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Sample records for c-o vibrational frequencies

  1. Fermi resonance and solvent dependence of the vC=O frequency shifts of Raman spectra: cyclohexanone and 2-cyclohexene-1-one

    CERN Document Server

    Nam, S I; Lee, M S; Jung, Y M

    2001-01-01

    The carbonyl stretching vibration, vC=O of 2-cyclohexene-1-one , is in Fermi resonance with a combination tone. The amount of Fermi resonance interaction between these two modes is dependent upon the amount of solute/solvent interaction due to hydrogen bonding between the carbonyl oxygen and the solvent proton. The corrected vC=O frequency of 2-cyclohexene-1-one occurs at a lower frequency than the observed vC=O mode of cyclohexanone, possibly caused by expanded conjugation effects. The carbonyl stretching modes of cyclic ketones were also affected by interaction with the ROH/CCl sub 4 mixed solvent system.

  2. Solvent effects on C=O stretching frequencies of some 1-substituted 2-pyrrolidinones

    NARCIS (Netherlands)

    Engberts, J.B.F.N.; Famini, G.R.; Perjéssy, A.; Wilson, L.Y.

    1998-01-01

    In an effort to model solute–solvent interactions, the C=O stretching frequencies of five 1-substituted 2-pyrrolidinones and four other carbonyl-containing compounds were measured for 30 common solvents. These were then correlated with four empirical parameter sets and one theoretical (computational

  3. Frequency adjustable MEMS vibration energy harvester

    Science.gov (United States)

    Podder, P.; Constantinou, P.; Amann, A.; Roy, S.

    2016-10-01

    Ambient mechanical vibrations offer an attractive solution for powering the wireless sensor nodes of the emerging “Internet-of-Things”. However, the wide-ranging variability of the ambient vibration frequencies pose a significant challenge to the efficient transduction of vibration into usable electrical energy. This work reports the development of a MEMS electromagnetic vibration energy harvester where the resonance frequency of the oscillator can be adjusted or tuned to adapt to the ambient vibrational frequency. Micro-fabricated silicon spring and double layer planar micro-coils along with sintered NdFeB micro-magnets are used to construct the electromagnetic transduction mechanism. Furthermore, another NdFeB magnet is adjustably assembled to induce variable magnetic interaction with the transducing magnet, leading to significant change in the spring stiffness and resonance frequency. Finite element analysis and numerical simulations exhibit substantial frequency tuning range (25% of natural resonance frequency) by appropriate adjustment of the repulsive magnetic interaction between the tuning and transducing magnet pair. This demonstrated method of frequency adjustment or tuning have potential applications in other MEMS vibration energy harvesters and micromechanical oscillators.

  4. Structures and vibrational frequencies of CO adlayers on Rh(111) surface

    Institute of Scientific and Technical Information of China (English)

    XIAO; Haiyan(肖海燕); LAI; Wenzhen(赖文珍); XIE; Daiqian(谢代前); YAN; Guosen(鄢国森)

    2003-01-01

    Density functional theory calculations within the generalized gradient approximation (GGA) have been carried out to study the structural and vibrational properties of carbon monoxide adsorption on Rh(111) surface. The optimized geometries, adsorption energies and vibrational frequencies have been obtained and the preferred binding sites have been determined. The results show that at low coverage CO prefers to adsorb at top site and at high coverage one molecule occupies top site while the two other molecules occupy hcp and fcc hollow sites respectively. The investigation of the vibrational properties of CO chemisorption on Rh(111) shows that the top C-O stretching frequency increases along with the increase of the coverage. The site assignments, optimized geometries and calculated vibrational frequencies are found to be in good agreement with the experimental results.

  5. Low-frequency characteristics extension for vibration sensors

    Institute of Scientific and Technical Information of China (English)

    杨学山; 高峰; 候兴民

    2004-01-01

    Traditional magneto-electric vibration sensors and servo accelerometers have severe shortcomings when used to measure vibration where low frequency components predominate. A low frequency characteristic extension for velocity vibration sensors is presented in this paper. The passive circuit technology, active compensation technology and the closedcycle pole compensation technology are used to extend the measurable range and to improve low frequency characteristics of sensors. Thses three types of low frequency velocity vibration sensors have been developed and widely adopted in China.

  6. Nonlinear frequency response analysis of structural vibrations

    Science.gov (United States)

    Weeger, Oliver; Wever, Utz; Simeon, Bernd

    2014-12-01

    In this paper we present a method for nonlinear frequency response analysis of mechanical vibrations of 3-dimensional solid structures. For computing nonlinear frequency response to periodic excitations, we employ the well-established harmonic balance method. A fundamental aspect for allowing a large-scale application of the method is model order reduction of the discretized equation of motion. Therefore we propose the utilization of a modal projection method enhanced with modal derivatives, providing second-order information. For an efficient spatial discretization of continuum mechanics nonlinear partial differential equations, including large deformations and hyperelastic material laws, we employ the concept of isogeometric analysis. Isogeometric finite element methods have already been shown to possess advantages over classical finite element discretizations in terms of higher accuracy of numerical approximations in the fields of linear vibration and static large deformation analysis. With several computational examples, we demonstrate the applicability and accuracy of the modal derivative reduction method for nonlinear static computations and vibration analysis. Thus, the presented method opens a promising perspective on application of nonlinear frequency analysis to large-scale industrial problems.

  7. Investigation on upsetting assisted by low-frequency vibration

    Directory of Open Access Journals (Sweden)

    Zhang M.

    2015-01-01

    Full Text Available The application of vibration load in metal forming processes has been demonstrated to be effective in reducing the forming load. In this paper, upsetting processes assisted by low-frequency vibration at room temperature was investigated based on finite element simulations. The vibration load was applied by the reciprocating movement of the upsetting punch. The influence of vibration frequency and feeding rate were analysed. It was revealed that low-frequency vibration was effective to reduce the mean forming load and increase the friction between billets and tools.

  8. Frequency-Dependent Attenuation of Blasting Vibration Waves

    Science.gov (United States)

    Zhou, Junru; Lu, Wenbo; Yan, Peng; Chen, Ming; Wang, Gaohui

    2016-10-01

    The dominant frequency, in addition to the peak particle velocity, is a critical factor for assessing adverse effects of the blasting vibration on surrounding structures; however, it has not been fully considered in blasting design. Therefore, the dominant frequency-dependent attenuation mechanism of blast-induced vibration is investigated in the present research. Starting with blasting vibration induced by a spherical charge propagating in an infinite viscoelastic medium, a modified expression of the vibration amplitude spectrum was derived to reveal the frequency dependency of attenuation. Then, ground vibration induced by more complex and more commonly used cylindrical charge that propagates in a semi-infinite viscoelastic medium was analyzed by numerical simulation. Results demonstrate that the absorptive property of the medium results in the frequency attenuation versus distance, whereas a rapid drop or fluctuation occurs during the attenuation of ground vibration. Fluctuation usually appears at moderate to far field, and the dominant frequency generally decreases to half the original value when rapid drop occurs. The decay rate discrepancy between different frequency components and the multimodal structure of vibration spectrum lead to the unsmooth frequency-dependent attenuation. The above research is verified by two field experiments. Furthermore, according to frequency-based vibration standards, frequency drop and fluctuation should be considered when evaluating blast safety. An optimized piecewise assessment is proposed for more accurate evaluation: With the frequency drop point as the breakpoint, the assessment is divided into two independent sections along the propagating path.

  9. Musculoskeletal modelling of low-frequency whole-body vibrations

    DEFF Research Database (Denmark)

    Rasmussen, John; Andersen, Michael Skipper

    2012-01-01

    This paper presents a musculoskeletal model for assessment of the effect of low-frequency whole-body vibrations on the human body. It is a basic assumption behind the model that the vibrations are slow enough to allow the central nervous system to respond to them in terms of muscle activations...

  10. Vibration velocity and frequency of underwater short-hole blasting

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    Based on the measuring data of underwater blasting vibrationand the regression analysis results of these data, two formulae usually used of blasting vibration velocity were compared. Factors that canaffect blasting vibration and frequency were summarized and analyzed.It is thought that the effect of the number of freedom face and burden direction on blasting vibration should be considered during blastingdesign. Based on the relevant research results and the regression results of these data, a formula to calculate under water blasting frequency was put forward.

  11. Size-Dependent Elastic Modulus and Vibration Frequency of Nanocrystals

    Directory of Open Access Journals (Sweden)

    Lihong Liang

    2011-01-01

    Full Text Available The elastic properties and the vibration characterization are important for the stability of materials and devices, especially for nanomaterials with potential and broad application. Nanomaterials show different properties from the corresponding bulk materials; the valid theoretical model about the size effect of the elastic modulus and the vibration frequency is significant to guide the application of nanomaterials. In this paper, a unified analytical model about the size-dependent elastic modulus and vibration frequency of nanocrystalline metals, ceramics and semiconductors is established based on the inherent lattice strain and the binding energy change of nanocrystals compared with the bulk crystals, and the intrinsic correlation between the elasticity and the vibration properties is discussed. The theoretical predictions for Cu, Ag, Si thin films, nanoparticles, and TiO2 nanoparticles agree with the experimental results, the computational simulations, and the other theoretical models.

  12. Theory Study on Structures and Vibrational Frequencies of Pyruvic acid

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    Density functional theory BLYP (using Becke's and Lee-Yang-Parr's correlation functionals ), ab initio Hartree-Fock (HF) and hybrid DFT/HF B3LYP calculations were carried out to study the structure and vibrational spectra of pyruvic acid. The scaled B3LYP/6-31G* frequencies correspond well with available experimental assignment of the functional vibrational modes and the mean absolut devation is only 12.3cm-1.

  13. Direct observation of the cyclic dimer in liquid acetic acid by probing the C=O vibration with ultrafast coherent Raman spectroscopy.

    Science.gov (United States)

    Lütgens, Matthias; Friedriszik, Frank; Lochbrunner, Stefan

    2014-09-01

    We present a comparison of spontaneous Raman and ultrafast coherent anti-Stokes Raman scattering (CARS) spectra of the C=O vibration of liquid acetic acid. The former technique cannot clearly reveal the number of contributions in the spectrum. However, the additional time and spectrally resolved CARS experiment supports strictly the existence of four modes, which proves the coexistence of more than one H-bonded configuration in liquid acetic acid. A comparably slowly dephasing mode which is obscured by a broad band in the linear Raman spectrum is assigned to the cyclic dimer and can be observed freed from all other contributions by ultrafast CARS.

  14. Capacitance-Based Frequency Adjustment of Micro Piezoelectric Vibration Generator

    Directory of Open Access Journals (Sweden)

    Xinhua Mao

    2014-01-01

    Full Text Available Micro piezoelectric vibration generator has a wide application in the field of microelectronics. Its natural frequency is unchanged after being manufactured. However, resonance cannot occur when the natural frequencies of a piezoelectric generator and the source of vibration frequency are not consistent. Output voltage of the piezoelectric generator will sharply decline. It cannot normally supply power for electronic devices. In order to make the natural frequency of the generator approach the frequency of vibration source, the capacitance FM technology is adopted in this paper. Different capacitance FM schemes are designed by different locations of the adjustment layer. The corresponding capacitance FM models have been established. Characteristic and effect of the capacitance FM have been simulated by the FM model. Experimental results show that the natural frequency of the generator could vary from 46.5 Hz to 42.4 Hz when the bypass capacitance value increases from 0 nF to 30 nF. The natural frequency of a piezoelectric vibration generator could be continuously adjusted by this method.

  15. Perceptual Space of Superimposed Dual-Frequency Vibrations in the Hands

    Science.gov (United States)

    Seo, Jeongil; Choi, Seungmoon

    2017-01-01

    The use of distinguishable complex vibrations that have multiple spectral components can improve the transfer of information by vibrotactile interfaces. We investigated the qualitative characteristics of dual-frequency vibrations as the simplest complex vibrations compared to single-frequency vibrations. Two psychophysical experiments were conducted to elucidate the perceptual characteristics of these vibrations by measuring the perceptual distances among single-frequency and dual-frequency vibrations. The perceptual distances of dual-frequency vibrations between their two frequency components along their relative intensity ratio were measured in Experiment I. The estimated perceptual spaces for three frequency conditions showed non-linear perceptual differences between the dual-frequency and single-frequency vibrations. A perceptual space was estimated from the measured perceptual distances among ten dual-frequency compositions and five single-frequency vibrations in Experiment II. The effect of the component frequency and the frequency ratio was revealed in the perceptual space. In a percept of dual-frequency vibration, the lower frequency component showed a dominant effect. Additionally, the perceptual difference among single-frequency and dual-frequency vibrations were increased with a low relative difference between two frequencies of a dual-frequency vibration. These results are expected to provide a fundamental understanding about the perception of complex vibrations to enrich the transfer of information using vibrotactile stimuli. PMID:28081187

  16. Gearbox Vibration Signal Amplitude and Frequency Modulation

    Directory of Open Access Journals (Sweden)

    Fakher Chaari

    2012-01-01

    Full Text Available Gearboxes usually run under fluctuating load conditions during service, however most of papers available in the literature describe models of gearboxes under stationary load conditions. Main task of published papers is fault modeling for their detection. Considering real situation from industry, the assumption of stationarity of load conditions cannot be longer kept. Vibration signals issued from monitoring in maintenance operations differ from mentioned models (due to load non-stationarity and may be difficult to analyze which lead to erroneous diagnosis of the system. The objective of this paper is to study the influence of time varying load conditions on a gearbox dynamic behavior. To investigate this, a simple spur gear system without defects is modeled. It is subjected to a time varying load. The speed-torque characteristic of the driving motor is considered. The load variation induces speed variation, which causes a variation in the gearmesh stiffness period. Computer simulation shows deep amplitude modulations with sidebands that don't differ from those obtained when there is a defective tooth. In order to put in evidence the time varying load effects, Short Time Fourier Transform and then Smoothed Wigner-Ville distribution are used. Results show that the last one is well suited for the studied case.

  17. Parameter Identification of Weakly Nonlinear Vibration System in Frequency Domain

    Directory of Open Access Journals (Sweden)

    Jiehua Peng

    2004-01-01

    Full Text Available A new method of identifying parameters of nonlinearly vibrating system in frequency domain is presented in this paper. The problems of parameter identification of the nonlinear dynamic system with nonlinear elastic force or nonlinear damping force are discussed. In the method, the mathematic model of parameter identification is frequency response function. Firstly, by means of perturbation method the frequency response function of weakly nonlinear vibration system is derived. Next, a parameter transformation is made and the frequency response function becomes a linear function of the new parameters. Then, based on this function and with the least square method, physical parameters of the system are identified. Finally, the applicability of the proposed technique is confirmed by numerical simulation.

  18. Vibration amplitude sonoelastography lesion imaging using low-frequency audible vibration

    Science.gov (United States)

    Taylor, Lawrence; Parker, Kevin

    2003-04-01

    Sonoelastography or vibration amplitude imaging is an ultrasound imaging technique in which low-amplitude, low-frequency shear waves, less than 0.1-mm displacement and 1-kHz frequency, are propagated deep into tissue, while real time Doppler techniques are used to image the resulting vibration pattern. Finite-element studies and experiments on tissue-mimicking phantoms verify that a discrete hard inhomogeneity present within a larger region of soft tissue will cause a decrease in the vibration field at its location. This forms the basis for tumor detection using sonoelastography. Real time relative imaging of the vibration field is possible because a vibrating particle will phase modulate an ultrasound signal. The particle's amplitude is directly proportional to the spectral spread of the reflected Doppler echo. Real time estimation of the variance of the Doppler power spectrum at each pixel allows the vibration field to be imaged. Results are shown for phantom lesions, thermal lesions, and 3-D in vitro and 2-D in vivo prostate cancer. MRI and whole mount histology is used to validate the system accuracy.

  19. Collagen and component polypeptides: Low frequency and amide vibrations

    Science.gov (United States)

    Fontaine-Vive, F.; Merzel, F.; Johnson, M. R.; Kearley, G. J.

    2009-01-01

    Collagen is a fibrous protein, which exists widely in the human body. The biomechanical properties of collagen depend on its triple helix structure and the corresponding low frequency vibrations. We use first-principles, density functional theory methods and analytical force fields to investigate the molecular vibrations of a model collagen compound, the results being validated by comparison with published, inelastic neutron scattering data. The results from these atomistic simulations are used at higher frequency to study the Amide I and V vibrations and therefore the vibrational signature of secondary and tertiary structure formation. In addition to collagen, its component homopolymers, poly-glycine and poly-proline are also studied. The Amide V vibration of glycine is strongly modified in going from the single helix of poly-glycine II to the triple helix of collagen. The collagen models are hydrated and this work allows us to discuss the relative merits of density functional theory and force field methods when tackling complex, partially crystalline systems.

  20. Band Width of Acoustic Resonance Frequency Relatively Natural Frequency of Fuel Rod Vibration

    Energy Technology Data Exchange (ETDEWEB)

    Proskuryakov, Konstantin Nicolaevich; Moukhine, V.S.; Novikov, K.S.; Galivets, E.Yu. [MPEI - TU, 14, Krasnokazarmennaya str., Moscow, 111250 (Russian Federation)

    2009-06-15

    In flow induced vibrations the fluid flow is the energy source that causes vibration. Acoustic resonance in piping may lead to severe problems due to over-stressing of components or significant losses of efficiency. Steady oscillatory flow in NPP primary loop can be induced by the pulsating flow introduced by reactor circulating pump or may be set up by self-excitation. Dynamic forces generated by the turbulent flow of coolant in reactor cores cause fuel rods (FR) and fuel assembly (FA) to vibrate. Flow-induced FR and FA vibrations can generally be broken into three groups: large amplitude 'resonance type' vibrations, which can cause immediate rod failure or severe damage to the rod and its support structure, middle amplitude 'within bandwidth of resonance frequency type' vibrations responsible for more gradual wear and fatigue at the contact surface between the fuel cladding and rod support and small amplitude vibrations, 'out of bandwidth of resonance frequency type' responsible for permissible wear and fatigue at the contact surface between the fuel cladding and rod support. Ultimately, these vibration types can result in a cladding breach, and therefore must be accounted for in the thermal hydraulic design of FR and FA and reactor internals. In paper the technique of definition of quality factor (Q) of acoustic contour of the coolant is presented. The value of Q defines a range of frequencies of acoustic fluctuations of the coolant within which the resonance of oscillations of the structure and the coolant is realized. Method of evaluation of so called band width (BW) of acoustic resonance frequency is worked out and presented in the paper. BW characterises the range of the frequency of coolant pressure oscillations within which the frequency of coolant pressure oscillations matches the fuel assembly's natural frequency of vibration (its resonance frequency). Paper show the way of detuning acoustic resonance from natural

  1. Frequency Identification of Vibration Signals Using Video Camera Image Data

    Directory of Open Access Journals (Sweden)

    Chia-Hung Wu

    2012-10-01

    Full Text Available This study showed that an image data acquisition system connecting a high-speed camera or webcam to a notebook or personal computer (PC can precisely capture most dominant modes of vibration signal, but may involve the non-physical modes induced by the insufficient frame rates. Using a simple model, frequencies of these modes are properly predicted and excluded. Two experimental designs, which involve using an LED light source and a vibration exciter, are proposed to demonstrate the performance. First, the original gray-level resolution of a video camera from, for instance, 0 to 256 levels, was enhanced by summing gray-level data of all pixels in a small region around the point of interest. The image signal was further enhanced by attaching a white paper sheet marked with a black line on the surface of the vibration system in operation to increase the gray-level resolution. Experimental results showed that the Prosilica CV640C CMOS high-speed camera has the critical frequency of inducing the false mode at 60 Hz, whereas that of the webcam is 7.8 Hz. Several factors were proven to have the effect of partially suppressing the non-physical modes, but they cannot eliminate them completely. Two examples, the prominent vibration modes of which are less than the associated critical frequencies, are examined to demonstrate the performances of the proposed systems. In general, the experimental data show that the non-contact type image data acquisition systems are potential tools for collecting the low-frequency vibration signal of a system.

  2. Frequency identification of vibration signals using video camera image data.

    Science.gov (United States)

    Jeng, Yih-Nen; Wu, Chia-Hung

    2012-10-16

    This study showed that an image data acquisition system connecting a high-speed camera or webcam to a notebook or personal computer (PC) can precisely capture most dominant modes of vibration signal, but may involve the non-physical modes induced by the insufficient frame rates. Using a simple model, frequencies of these modes are properly predicted and excluded. Two experimental designs, which involve using an LED light source and a vibration exciter, are proposed to demonstrate the performance. First, the original gray-level resolution of a video camera from, for instance, 0 to 256 levels, was enhanced by summing gray-level data of all pixels in a small region around the point of interest. The image signal was further enhanced by attaching a white paper sheet marked with a black line on the surface of the vibration system in operation to increase the gray-level resolution. Experimental results showed that the Prosilica CV640C CMOS high-speed camera has the critical frequency of inducing the false mode at 60 Hz, whereas that of the webcam is 7.8 Hz. Several factors were proven to have the effect of partially suppressing the non-physical modes, but they cannot eliminate them completely. Two examples, the prominent vibration modes of which are less than the associated critical frequencies, are examined to demonstrate the performances of the proposed systems. In general, the experimental data show that the non-contact type image data acquisition systems are potential tools for collecting the low-frequency vibration signal of a system.

  3. Two-dimensional optical coherence vibration tomography for low-frequency vibration measurement and response-only modal analysis

    Science.gov (United States)

    Zhong, Jianfeng; Zhong, Shuncong; Zhang, Qiukun

    2016-10-01

    A high-speed camera-based two-dimensional optical coherence vibration tomography (2DOCVT) system with a subnanometre displacement resolution was developed and employed for low-frequency vibration measurement and modal analysis. Experimental results demonstrated the ability of low-frequency absolute displacement measurement of structural line vibrations without scanning. Three-dimensional (3D) surface displacement of a vibrating structure could also be obtained using the developed 2DOCVT by scanning the structure. The scanning 2DOCVT system acted like a 3D optical coherence vibration tomography system. The developed 2DOCVT system could capture structural modal parameters without vibration excitation input information, and therefore, it is a response-only method. The 2DOCVT could be recommended in the application of low-frequency vibration measurement and modal analysis of beam and plate structures, especially when the vibration amplitude is at nanometre or micrometre scale.

  4. Vibration frequency measurement using a local multithreshold technique.

    Science.gov (United States)

    Ferrer, Belen; Espinosa, Julian; Roig, Ana B; Perez, J; Mas, D

    2013-11-01

    In this paper, we demonstrate the use of a video camera for measuring the frequency of small-amplitude vibration movements. The method is based on image acquisition and multilevel thresholding and it only requires a video camera with high enough acquisition rate, not being necessary the use of targets or auxiliary laser beams. Our proposal is accurate and robust. We demonstrate the technique with a pocket camera recording low-resolution videos with AVI-JPEG compression and measuring different objects that vibrate in parallel or perpendicular direction to the optical sensor. Despite the low resolution and the noise, we are able to measure the main vibration modes of a tuning fork, a loudspeaker and a bridge. Results are successfully compared with design parameters and measurements with alternative devices.

  5. Peroxyacetyl radical: Electronic excitation energies, fundamental vibrational frequencies, and symmetry breaking in the first excited state

    Energy Technology Data Exchange (ETDEWEB)

    Copan, Andreas V.; Wiens, Avery E.; Nowara, Ewa M.; Schaefer, Henry F.; Agarwal, Jay, E-mail: jagarwal@uga.edu [Center for Computational Quantum Chemistry, University of Georgia, Athens, Georgia 30602 (United States)

    2015-02-07

    Peroxyacetyl radical [CH{sub 3}C(O)O{sub 2}] is among the most abundant peroxy radicals in the atmosphere and is involved in OH-radical recycling along with peroxyacetyl nitrate formation. Herein, the ground (X{sup ~}) and first (A{sup ~}) excited state surfaces of cis and trans peroxyacetyl radical are characterized using high-level ab initio methods. Geometries, anharmonic vibrational frequencies, and adiabatic excitation energies extrapolated to the complete basis-set limit are reported from computations with coupled-cluster theory. Excitation of the trans conformer is found to induce a symmetry-breaking conformational change due to second-order Jahn-Teller interactions with higher-lying excited states. Additional benchmark computations are provided to aid future theoretical work on peroxy radicals.

  6. Low Frequency Vibration Energy Harvesting using Diamagnetically Stabilized Magnet Levitation

    Science.gov (United States)

    Palagummi, Sri Vikram

    Over the last decade, vibration-based energy harvesting has provided a technology push on the feasibility of self-powered portable small electronic devices and wireless sensor nodes. Vibration energy harvesters in general transduce energy by damping out the environmentally induced relative emotion through either a cantilever beam or an equivalent suspension mechanism with one of the transduction mechanisms, like, piezoelectric, electrostatic, electromagnetic or magnetostrictive. Two major challenges face the present harvesters in literature, one, they suffer from the unavoidable mechanical damping due to internal friction present in the systems, second, they cannot operate efficiently in the low frequency range (magnet levitation mechanisms which can work efficiently as a vibration energy harvester in the low frequency range are discussed in this work. First, a mono-stable vertical diamagnetic levitation (VDL) based vibration energy harvester (VEH) is discussed. The harvester consists of a lifting magnet (LM), a floating magnet (FM) and two diamagnetic plates (DPs). The LM balances out the weight of the FM and stability is brought about by the repulsive effect of the DPs, made of pyrolytic graphite. Two thick cylindrical coils, placed in grooves which are engraved in the DPs, are used to convert the mechanical energy into electrical energy. Experimental frequency response of the system is validated by the theoretical analysis which showed that the VEH works in a low frequency range but sufficient levitation gap was not achieved and the frequency response characteristic of the system was effectively linear. To overcome these challenges, the influence of the geometry of the FM, the LM, and the DP were parametrically studied to assess their effects on the levitation gap, size of the system and the natural frequency. For efficient vibration energy harvesting using the VDL system, ways to mitigate eddy current damping and a coil geometry for transduction were critically

  7. Time frequency analyses of vibrations of wind turbine towers

    Science.gov (United States)

    Chiang, Chih-Hung; Huang, Chi-Luen; Hsu, Keng-Tseng; Cheng, Chia-Chi; Yu, Chih-Peng; Lai, Jiunnren

    2015-04-01

    Transient vibrations of the tower supporting a horizontal-axis wind turbine were recorded using a microwave interferometer. Variations in dominant frequencies have been reported in the previous study. Signal analyses aiming to uncouple different frequency components were performed using reassigned spectrogram, a time-frequency representation based on time-corrected short time Fourier transform. Optimal resolutions in both time and frequency domains were first investigated using synthetic signals. The goal was to seek out the favorable combinations of window size and overlapping portions of adjacent windows for a data sequence at a given sampling rate. The dominant frequency found in reassigned spectrogram agrees with that obtained using Fourier spectrum of the same transient measurements of the wind turbine tower under investigation.

  8. Configurations of high-frequency ultrasonics complex vibration systems for packaging in microelectronics.

    Science.gov (United States)

    Tsujino, Jiromaru; Harada, Yoshiki; Ihara, Shigeru; Kasahara, Kohei; Shimizu, Masanori; Ueoka, Tetsugi

    2004-04-01

    Ultrasonic high-frequency complex vibrations are effective for various ultrasonic high-power applications. Three types of ultrasonic complex vibration system with a welding tip vibrating elliptical to circular locus for packaging in microelectronics were studied. The complex vibration sources are using (1) a longitudinal-torsional vibration converter with diagonal slits that is driven only by a longitudinal vibration source, (2) a complex transverse vibration rod with several stepped parts that is driven by two longitudinal vibration source crossed at a right angle and (3) a longitudinal vibration circular disk and three longitudinal transducers that are installed at the circumference of the disk.

  9. Simulation applied to working frequency selection in large-scale vibrating screen's design

    Institute of Scientific and Technical Information of China (English)

    PENG Chen-yu; SU Rong-hua

    2011-01-01

    The working frequency selection of the ZK30525 vibrating screen was studied using ANSYS.Integrating the dynamic performance simulation analysis of the vibrating screen structure,the variation laws of beams' vibration displacements changing with different exciting frequencies were researched.These beams include six beams,with one discharging beam and one in-material beam.Results indicate that vibration displacements in the middle of these beams increase with the augmentation of exciting frequency.When exciting frequency exceeds a certain value,there exists a flat change region for vibration displacement.According to vibrator characteristics,the vibrating screen's working frequency should be selected in the flat change region,and be far away from modal frequencies.The study provides theoretical guidance for the reasonable working frequency selection of the large-scale vibrating screen.

  10. Low-frequency meandering piezoelectric vibration energy harvester.

    Science.gov (United States)

    Berdy, David F; Srisungsitthisunti, Pornsak; Jung, Byunghoo; Xu, Xianfan; Rhoads, Jeffrey F; Peroulis, Dimitrios

    2012-05-01

    The design, fabrication, and characterization of a novel low-frequency meandering piezoelectric vibration energy harvester is presented. The energy harvester is designed for sensor node applications where the node targets a width-to-length aspect ratio close to 1:1 while simultaneously achieving a low resonant frequency. The measured power output and normalized power density are 118 μW and 5.02 μW/mm(3)/g(2), respectively, when excited by an acceleration magnitude of 0.2 g at 49.7 Hz. The energy harvester consists of a laser-machined meandering PZT bimorph. Two methods, strain-matched electrode (SME) and strain-matched polarization (SMP), are utilized to mitigate the voltage cancellation caused by having both positive and negative strains in the piezoelectric layer during operation at the meander's first resonant frequency. We have performed finite element analysis and experimentally demonstrated a prototype harvester with a footprint of 27 x 23 mm and a height of 6.5 mm including the tip mass. The device achieves a low resonant frequency while maintaining a form factor suitable for sensor node applications. The meandering design enables energy harvesters to harvest energy from vibration sources with frequencies less than 100 Hz within a compact footprint.

  11. Cross-Propagation Sum-Frequency Generation Vibrational Spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Fu, Li; Chen, Shunli; Gan, Wei; Wang, Hongfei

    2016-02-01

    Here we report the theory formulation and the experiment realization of sum-frequency generation vibrational spectroscopy (SFG-VS) in the cross-propagation (XP) geometry or configuration. In the XP geometry, the visible and the infrared (IR) beams in the SFG experiment are delivered to the same location on the surface from visible and IR incident planes perpendicular to each other, avoiding the requirement to have windows or optics to be transparent to both the visible and IR frequencies. Therefore, the XP geometry is applicable to study surfaces in the enclosed vacuum or high pressure chambers with far infrared (FIR) frequencies that can directly access the metal oxide and other lower frequency surface modes, with much broader selection of visible and IR transparent window materials.

  12. Experimental Study on External Low Frequency Vibration Influence on SPM

    Institute of Scientific and Technical Information of China (English)

    CHEN Jinping; GUO Tong; HU Xiaodong; HU Xiaotang

    2007-01-01

    The influence of external Iow frequency (0-100 Hz) vibration on the tip-sample interaction in SPM is the main concern of this paper. A concept, vibration rejection ratio (VRR) proposed by Thompson et al, was investigated theoretically and experimentally. A concise theoretical background was introduced, a vibration stimulating and measuring system for SPM was built up, and an experimental research of the influence on SPM VRR was carried out with different SPM probes, samples, tip pre-loads and open/close loops of tip-sample interaction. It was proved both in theory and experiment that SPM VRR had correlations with the spring constant, the air damping constant, the effective mass of the cantilever, the contact spring constant and the contact damping constant between tip and sample. SPM's vibration rejecting ability can be improved by longer cantilever probe, softer sample surface, greater tip pre-load, and close-loop control for tip-sample interaction. More attention should be paid to a proper combination of the above parameters.

  13. Microscale capillary wave turbulence excited by high frequency vibration.

    Science.gov (United States)

    Blamey, Jeremy; Yeo, Leslie Y; Friend, James R

    2013-03-19

    Low frequency (O(10 Hz-10 kHz)) vibration excitation of capillary waves has been extensively studied for nearly two centuries. Such waves appear at the excitation frequency or at rational multiples of the excitation frequency through nonlinear coupling as a result of the finite displacement of the wave, most often at one-half the excitation frequency in so-called Faraday waves and twice this frequency in superharmonic waves. Less understood, however, are the dynamics of capillary waves driven by high-frequency vibration (>O(100 kHz)) and small interface length scales, an arrangement ideal for a broad variety of applications, from nebulizers for pulmonary drug delivery to complex nanoparticle synthesis. In the few studies conducted to date, a marked departure from the predictions of classical Faraday wave theory has been shown, with the appearance of broadband capillary wave generation from 100 Hz to the excitation frequency and beyond, without a clear explanation. We show that weak wave turbulence is the dominant mechanism in the behavior of the system, as evident from wave height frequency spectra that closely follow the Rayleigh-Jeans spectral response η ≈ ω(-17/12) as a consequence of a period-halving, weakly turbulent cascade that appears within a 1 mm water drop whether driven by thickness-mode or surface acoustic Rayleigh wave excitation. However, such a cascade is one-way, from low to high frequencies. The mechanism of exciting the cascade with high-frequency acoustic waves is an acoustic streaming-driven turbulent jet in the fluid bulk, driving the fundamental capillary wave resonance through the well-known coupling between bulk flow and surface waves. Unlike capillary waves, turbulent acoustic streaming can exhibit subharmonic cascades from high to low frequencies; here it appears from the excitation frequency all the way to the fundamental modes of the capillary wave at some four orders of magnitude in frequency less than the excitation frequency

  14. Long-range vibration sensor based on correlation analysis of optical frequency-domain reflectometry signals.

    Science.gov (United States)

    Ding, Zhenyang; Yao, X Steve; Liu, Tiegen; Du, Yang; Liu, Kun; Han, Qun; Meng, Zhuo; Chen, Hongxin

    2012-12-17

    We present a novel method to achieve a space-resolved long- range vibration detection system based on the correlation analysis of the optical frequency-domain reflectometry (OFDR) signals. By performing two separate measurements of the vibrated and non-vibrated states on a test fiber, the vibration frequency and position of a vibration event can be obtained by analyzing the cross-correlation between beat signals of the vibrated and non-vibrated states in a spatial domain, where the beat signals are generated from interferences between local Rayleigh backscattering signals of the test fiber and local light oscillator. Using the proposed technique, we constructed a standard single-mode fiber based vibration sensor that can have a dynamic range of 12 km and a measurable vibration frequency up to 2 kHz with a spatial resolution of 5 m. Moreover, preliminarily investigation results of two vibration events located at different positions along the test fiber are also reported.

  15. Nature of the Frequency Shift of Hydrogen Valence Vibrations

    CERN Document Server

    Zhyganiuk, I V

    2015-01-01

    The physical nature of a frequency shift of hydrogen valence vibrations in a water molecule due to its interaction with neighbor molecules has been studied. Electrostatic forces connected with the multipole moments of molecules are supposed to give a dominating contribution to the intermolecular interaction. The frequency shift was calculated in the case where two neighbor molecules form a dimer. The obtained result is in qualitative agreement with the frequency shifts observed for water vapor, hexagonal ice, and liquid water, as well as for aqueous solutions of alcohols. This fact testifies to the electrostatic nature of H-bonds used to describe both the specific features of the intermolecular interaction in water and the macroscopic properties of the latter.

  16. High force vibration testing with wide frequency range

    Energy Technology Data Exchange (ETDEWEB)

    Romero, Edward F.; Jepsen, Richard A.; Gregory, Danny Lynn

    2013-04-02

    A shaker assembly for vibration testing includes first and second shakers, where the first shaker includes a piezo-electric material for generating vibration. A support structure permits a test object to be supported for vibration of the test object by both shakers. An input permits an external vibration controller to control vibration of the shakers.

  17. DESIGN AND DYNAMICAL SIMULATION TO NEW VIBRATING CENTRIFUGE WITH WIDER FREQUENCY RANGE

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    A new type of vibrating centrifuge with wider frequency range is designed instead of the traditional one with a single frequency to improve the vibrating effect. With the aid of a new dynamical model, one simulation without considering the visco-elasticity of basis is presented, then the dynamical responses of time and frequency in different scheme are given. The computational results show that the improved vibrating centrifuge possesses a remarkably widened frequency range.

  18. Spectroscopic and theoretical investigations of vibrational frequencies in binary unsaturated transition-metal carbonyl cations, neutrals, and anions.

    Science.gov (United States)

    Zhou, M; Andrews, L; Bauschlicher, C W

    2001-07-01

    Figure 18 presents the C-O stretching vibrational frequencies of the first-row transition-metal monocarbonyl cations, neutrals, and anions in solid neon; similar diagrams have been reported for neutral MCO species in solid argon, but three of the early assignments have been changed by recent work and one new assignment added. The laser-ablation method produces mostly neutral atoms with a few percent cations and electrons for capture to make anions; in contrast, thermal evaporation gives only neutral species. Hence, the very recent neon matrix investigations in our laboratory provide carbonyl cations and anions for comparison to neutrals on a level playing field. Several trends are very interesting. First, for all metals, the C-O stretching frequencies follow the order cations > neutrals > anions with large diagnostic 100-200 cm-1 separations, which is consistent with the magnitude of the metal d to CO pi * donation. Second, for a given charge, there is a general increase in C-O stretching vibrational frequencies with increasing metal atomic number, which demonstrates the expected decrease in the metal to CO pi * donation with increasing metal ionization potential. Some of the structure in this plot arises from the extra stability of the filled and half-filled d shell and from the electron pairing that occurs at the middle of the TM row; the plot resembles the "double-humped" graph found for the variation in properties across a row of transition metals. For the anions, the variation with metal atom is the smallest since all of the metals can easily donate charge to the CO ligand. Third, for the early transition-metal Ti, V, and Cr families, the C-O stretching frequencies decrease when going down the family, but the reverse relationship is observed for the late transition-metal Fe, Co, and Ni families. In most of the present discussion, we have referred to neon matrix frequencies; however, the argon matrix frequencies are complementary, and useful information can be

  19. Smart nanocoated structure for energy harvesting at low frequency vibration

    Science.gov (United States)

    Sharma, Sudhanshu

    Increasing demands of energy which is cleaner and has an unlimited supply has led development in the field of energy harvesting. Piezoelectric materials can be used as a means of transforming ambient vibrations into electrical energy that can be stored and used to power other devices. With the recent surge of micro scale devices, piezoelectric power generation can provide a convenient alternative to traditional power sources. In this research, a piezoelectric power generator composite prototype was developed to maximize the power output of the system. A lead zirconate titanate (PZT) composite structure was formed and mounted on a cantilever bar and was studied to convert vibration energy of the low range vibrations at 30 Hz--1000 Hz. To improve the performance of the PZT, different coatings were made using different percentage of Ferrofluid (FNP) and Zinc Oxide nanoparticles (ZnO) and binder resin. The optimal coating mixture constituent percentage was based on the performance of the composite structure formed by applying the coating on the PZT. The fabricated PZT power generator composite with an effective volume of 0.062 cm3 produced a maximum of 44.5 μW, or 0.717mW/cm3 at its resonant frequency of 90 Hz. The optimal coating mixture had the composition of 59.9%FNP + 40% ZnO + 1% Resin Binder. The coating utilizes the opto-magneto-electrical properties of ZnO and Magnetic properties of FNP. To further enhance the output, the magneto-electric (ME) effect was increased by subjecting the composite to magnetic field where coating acts as a magnetostrictive material. For the effective volume of 0.0062 cm 3, the composite produced a maximum of 68.5 μW, or 1.11mW/cm 3 at its resonant frequency of 90 Hz at 160 gauss. The optimal coating mixture had the composition of 59.9% FNP + 40% ZnO + 1% Resin Binder. This research also focused on improving the efficiency of solar cells by utilizing the magnetic effect along with gas plasma etching to improve the internal reflection

  20. Characteristics of coated copper wire specimens using high frequency ultrasonic complex vibration welding equipments.

    Science.gov (United States)

    Tsujino, J; Ihara, S; Harada, Y; Kasahara, K; Sakamaki, N

    2004-04-01

    Welding characteristic of thin coated copper wires were studied using 40, 60, 100 kHz ultrasonic complex vibration welding equipments with elliptical to circular vibration locus. The complex vibration systems consisted of a longitudinal-torsional vibration converter and a driving longitudinal vibration system. Polyurethane coated copper wires of 0.036 mm outer diameter and copper plates of 0.3 mm thickness and the other dimension wires were used as welding specimens. The copper wire part is completely welded on the copper substrate and the insulated coating material is driven from welded area to outsides of the wire specimens by high frequency complex vibration.

  1. Comparative analysis of internal friction and natural frequency measured by free decay and forced vibration.

    Science.gov (United States)

    Wang, Y Z; Ding, X D; Xiong, X M; Zhang, J X

    2007-10-01

    Relations between various values of the internal friction (tgdelta, Q(-1), Q(-1*), and Lambda/pi) measured by free decay and forced vibration are analyzed systemically based on a fundamental mechanical model in this paper. Additionally, relations between various natural frequencies, such as vibration frequency of free decay omega(FD), displacement-resonant frequency of forced vibration omega(d), and velocity-resonant frequency of forced vibration omega(0) are calculated. Moreover, measurement of natural frequencies of a copper specimen of 99.9% purity has been made to demonstrate the relation between the measured natural frequencies of the system by forced vibration and free decay. These results are of importance for not only more accurate measurement of the elastic modulus of materials but also the data conversion between different internal friction measurements.

  2. Vibration frequency and lock-in bandwidth of tensioned, flexible cylinders experiencing vortex shedding

    Science.gov (United States)

    Lee, L.; Allen, D.

    2010-05-01

    In-water vortex-induced vibration (VIV) tests of top-tensioned, flexible cylindrical structures were conducted at Shell Westhollow Technology Center current tank. These tests revealed that the top tension and structural stiffness (both lateral and axial) can have a significant impact on vibration frequencies. During lock-in between the vortex-shedding frequency and the structure's natural frequency, the increase of the vibration frequency with flow speeds is strongly related to the rise of the axial tension. After an initial abrupt rise, the vibration frequency of a bending-stiffness-dominated structure only increased slightly during lock-in. Alternative explanations are provided on why the vibration frequency does not rise significantly but there can still exist a broad lock-in band, and why a more massive structure has a narrower lock-in bandwidth.

  3. Micro-scale piezoelectric vibration energy harvesting: From fixed-frequency to adaptable-frequency devices

    Science.gov (United States)

    Miller, Lindsay Margaret

    hundred milliwatts and are falling steadily as improvements are made, it is feasible to use energy harvesting to power WSNs. This research begins by presenting the results of a thorough survey of ambient vibrations in the machine room of a large campus building, which found that ambient vibrations are low frequency, low amplitude, time varying, and multi-frequency. The modeling and design of fixed-frequency micro scale energy harvesters are then presented. The model is able to take into account rotational inertia of the harvester's proof mass and it accepts arbitrary measured acceleration input, calculating the energy harvester's voltage as an output. The fabrication of the micro electromechanical system (MEMS) energy harvesters is discussed and results of the devices harvesting energy from ambient vibrations are presented. The harvesters had resonance frequencies ranging from 31 - 232 Hz, which was the lowest reported in literature for a MEMS device, and produced 24 pW/g2 - 10 nW/g2 of harvested power from ambient vibrations. A novel method for frequency modification of the released harvester devices using a dispenser printed mass is then presented, demonstrating a frequency shift of 20 Hz. Optimization of the MEMS energy harvester connected to a resistive load is then presented, finding that the harvested power output can be increased to several microwatts with the optimized design as long as the driving frequency matches the harvester's resonance frequency. A framework is then presented to allow a similar optimization to be conducted with the harvester connected to a synchronously switched pre-bias circuit. With the realization that the optimized energy harvester only produces usable amounts of power if the resonance frequency and driving frequency match, which is an unrealistic situation in the case of ambient vibrations which change over time and are not always known a priori, an adaptable-frequency energy harvester was designed. The adaptable-frequency harvester

  4. Frequencies in the Vibration Induced by the Rotor Stator Interaction in a Centrifugal Pump Turbine

    DEFF Research Database (Denmark)

    Rodriguez, Cristian; Egusquiza, Eduard; Santos, Ilmar

    2007-01-01

    The highest vibration levels in large pump turbines are, in general, originated in the rotor stator interaction (RSI). This vibration has specific characteristics that can be clearly observed in the frequency domain: harmonics of the moving blade passing frequency and a particular relationship am...

  5. Predictions of the bond length and vibrational frequency of Ge/sub 2/

    Energy Technology Data Exchange (ETDEWEB)

    Northrup, J.E.; Cohen, M.L.

    1983-12-02

    A pseudopotential local spin density calculation of the bond length, vibrational frequency, and binding energy for the ..sigma../sub g//sup -/ state of the germanium dimer is presented. Predictions for the equilibrium bond length and vibrational frequency are given. An overestimate of the binding energy is obtained; this is consistent with other local density calculations for sp bonded diatomic molecules.

  6. Predictions of the bond length and vibrational frequency of Ge 2

    Science.gov (United States)

    Northrup, John E.; Cohen, Marvin L.

    1983-12-01

    We present a pseudopotential local spin density calculation of the bond length, vibrational frequency, and binding energy for the 3Σ g- state of the germanium dimer. Predictions for the equilibrium bond length and vibrational frequency are given. An overestimate of the binding energy is obtained; this is consistent with other local spin density calculations for sp bonded diatomic molecules.

  7. Low frequency vibration tests on a floating slab track in an underground laboratory

    Institute of Scientific and Technical Information of China (English)

    De-yun DING; Wei-ning LIU; Ke-fei LI; Xiao-jing SUN; Wei-feng LIU

    2011-01-01

    Low frequency vibrations induced by underground railways have attracted increasing attention in recent years. To obtain the characteristics of low frequency vibrations and the low frequency performance of a floating slab track (FST), low frequency vibration tests on an FST in an underground laboratory at Beijing Jiaotong University were carried out. The FST and an unbalanced shaker SBZ30 for dynamic simulation were designed for use in low frequency vibration experiments. Vibration measurements were performed on the bogie of the unbalanced shaker, the rail, the slab, the tunnel invert, the tunnel wall, the tunnel apex, and on the ground surface at distances varying from 0 to 80 m from the track. Measurements were also made on several floors of an adjacent building. Detailed results of low frequency vibration tests were reported. The attenuation of low frequency vibrations with the distance from the track was presented, as well as the responses of different floors of the building. The experimental results could be regarded as a reference for developing methods to control low frequency vibrations and for adopting countermeasures.

  8. Welding Characteristics of Ultrasonic Wire Bonding Using High-Frequency Vibration Systems

    Science.gov (United States)

    Tsujino, Jiromaru; Mori, Takahiro; Hasegawa, Koichi

    1994-05-01

    Welding characteristics of ultrasonic wire bonding using 60 kHz, 90 kHz and 120 kHz complex vibration as well as 190 kHz linear vibration welding systems are studied. The locus shapes of the complex vibration welding tip are controlled from linear to elliptical or circular. Aluminum wire specimens of 0.1 mm diameter are welded successfully using complex and high-frequency welding equipment. The required vibration amplitudes of these complex vibration systems are about one-half to one-third and required weld time is shorter than those of a conventional system of linear vibration. The required vibration velocity of a high-frequency system is lower than that of a low-frequency system. The deformations of the welded specimens under adequate welding conditions are almost the same, even if the welding tip vibration locus is altered from linear to elliptical or circular, or the vibration frequency used is changed from 60 kHz to 190 kHz in the case where the same wire specimens are used. Using these methods, the weld strength of wire bonding becomes independent of the difference in the directions of the welding tip vibration and wire length.

  9. Examining the impact of harmonic correlation on vibrational frequencies calculated in localized coordinates

    Energy Technology Data Exchange (ETDEWEB)

    Hanson-Heine, Magnus W. D., E-mail: magnus.hansonheine@nottingham.ac.uk [School of Chemistry, University of Nottingham, University Park, Nottingham NG7 2RD (United Kingdom)

    2015-10-28

    Carefully choosing a set of optimized coordinates for performing vibrational frequency calculations can significantly reduce the anharmonic correlation energy from the self-consistent field treatment of molecular vibrations. However, moving away from normal coordinates also introduces an additional source of correlation energy arising from mode-coupling at the harmonic level. The impact of this new component of the vibrational energy is examined for a range of molecules, and a method is proposed for correcting the resulting self-consistent field frequencies by adding the full coupling energy from connected pairs of harmonic and pseudoharmonic modes, termed vibrational self-consistent field (harmonic correlation). This approach is found to lift the vibrational degeneracies arising from coordinate optimization and provides better agreement with experimental and benchmark frequencies than uncorrected vibrational self-consistent field theory without relying on traditional correlated methods.

  10. The effect of vibrational molecular excitation on the chirping of the pulsed single-frequency CO2 laser radiation frequency

    Energy Technology Data Exchange (ETDEWEB)

    Kozolupenko, V.P.; Kuntsevich, B.F.; Maliuta, D.D.; Mezhevov, V.S.; Strel' tsov, A.P. (Institut Atomnoi Energii, Moscow (USSR))

    1989-03-01

    The dependence of the nonresonant part of the refractive index on vibrational molecular excitation is shown to be one of the possible mechanisms responsible for the chirping of the radiation frequency of pulsed single-frequency CO{sub 2} lasers. A heterodyning method was used to record the radiation frequency variation with two receivers utilizing HgCdTe. 12 refs.

  11. Time-frequency characteristics of blasting vibration signals measured in milliseconds

    Institute of Scientific and Technical Information of China (English)

    Zhao Mingsheng; Zhang Jianhua; Yi Changping

    2011-01-01

    In order to study the time-frequency characteristics of blasting vibration signals,measured in milliseconds,we carried out site blasting vibration tests at an open pit of the Jinduicheng Mine.Based on recorded field data and applying a combination of RSPWVD and wavelet,.we analyzed the time-frequency characteristics of recorded field data.summarized the time-frequency characteristics of blasting vibration signals in different frequency bands and present detailed information of blasting vibration signals in milliseconds of high time-frequency resolutions.Because RSPWVD can be seen as of definite physical significance to signal energy distribution in time and frequency domains,we studied the energy distribution of blasting vibration signals for various milliseconds intervals from a perspective of energy distribution.The results indicate that the effect of milliseconds intervals on time-frequency characteristics of blasting vibration signals is significant:the length of delay time directly affects the energy distribution of blasting vibration signals as well as the duration of energy in frequency bands.

  12. Active low-frequency vertical vibration isolation system for precision measurements

    Science.gov (United States)

    Wu, Kang; Li, Gang; Hu, Hua; Wang, Lijun

    2017-01-01

    Low-frequency vertical vibration isolation systems play important roles in precision measurements to reduce seismic and environmental vibration noise. Several types of active vibration isolation systems have been developed. However, few researches focus on how to optimize the test mass install position in order to improve the vibration transmissibility. An active low-frequency vertical vibration isolation system based on an earlier instrument, the Super Spring, is designed and implemented. The system, which is simple and compact, consists of two stages: a parallelogram-shaped linkage to ensure vertical motion, and a simple spring-mass system. The theoretical analysis of the vibration isolation system is presented, including terms erroneously ignored before. By carefully choosing the mechanical parameters according to the above analysis and using feedback control, the resonance frequency of the system is reduced from 2.3 to 0.03 Hz, a reduction by a factor of more than 75. The vibration isolation system is installed as an inertial reference in an absolute gravimeter, where it improved the scatter of the absolute gravity values by a factor of 5. The experimental results verifies the improved performance of the isolation system, making it particularly suitable for precision experiments. The improved vertical vibration isolation system can be used as a prototype for designing high-performance active vertical isolation systems. An improved theoretical model of this active vibration isolation system with beam-pivot configuration is proposed, providing fundamental guidelines for vibration isolator design and assembling.

  13. Effects of Frequency and Acceleration Amplitude on Osteoblast Mechanical Vibration Responses: A Finite Element Study

    Directory of Open Access Journals (Sweden)

    Liping Wang

    2016-01-01

    Full Text Available Bone cells are deformed according to mechanical stimulation they receive and their mechanical characteristics. However, how osteoblasts are affected by mechanical vibration frequency and acceleration amplitude remains unclear. By developing 3D osteoblast finite element (FE models, this study investigated the effect of cell shapes on vibration characteristics and effect of acceleration (vibration intensity on vibrational responses of cultured osteoblasts. Firstly, the developed FE models predicted natural frequencies of osteoblasts within 6.85–48.69 Hz. Then, three different levels of acceleration of base excitation were selected (0.5, 1, and 2 g to simulate vibrational responses, and acceleration of base excitation was found to have no influence on natural frequencies of osteoblasts. However, vibration response values of displacement, stress, and strain increased with the increase of acceleration. Finally, stress and stress distributions of osteoblast models under 0.5 g acceleration in Z-direction were investigated further. It was revealed that resonance frequencies can be a monotonic function of cell height or bottom area when cell volumes and material properties were assumed as constants. These findings will be useful in understanding how forces are transferred and influence osteoblast mechanical responses during vibrations and in providing guidance for cell culture and external vibration loading in experimental and clinical osteogenesis studies.

  14. Investigation into high-frequency-vibration assisted micro-blanking of pure copper foils

    Directory of Open Access Journals (Sweden)

    Wang Chunju

    2015-01-01

    Full Text Available The difficulties encountered during the manufacture of microparts are often associated with size effects relating to material, process and tooling. Utilizing acoustoplastic softening, achieved through a high-frequency vibration assisted micro-blanking process, was introduced to improve the surface finish in micro-blanking. A frequency of 1.0 kHz was chosen to activate the longitudinal vibration mode of the horn tip, using a piezoelectric actuator. A square hole with dimensions of 0.5 mm × 0.5 mm was made, successfully, from a commercial rolled T2 copper foil with 100 μm in thickness. It was found that the maximum blanking force could be reduced by 5% through utilizing the high-frequency vibration. Proportion of the smooth, burnished area in the cut cross-section increases with an increase of the plasticity to fracture, under the high-frequency vibration, which suggests that the vibration introduced is helpful for inhibiting evolution of the crack due to its acoustoplastic softening effect. During blanking, roughness of the burnished surface could be reduced by increasing the vibration amplitude of the punch, which played a role as surface polishing. The results obtained suggest that the high-frequency vibration can be adopted in micro-blanking in order to improve quality of the microparts.

  15. Co-Assignment of the Molecular Vibrational Frequencies in Different Electronic States

    Science.gov (United States)

    Panchenko, Yurii; Abramenkov, Alexander

    2016-06-01

    Ultrafast electron diffraction experimental data for the structural parameters of molecules in excited electronic states are comparatively uncommon, hence these parameters are largely unknown. However, because differences between the molecular geometries of excited and ground electronic states cause differences in their experimental vibrational spectra it is important to establish a correspondence between the molecular vibrational frequencies in the ground state and those of the excited state of interest. The correct co-assignment of the experimental vibrational frequencies between two different electronic states of a molecule may be determined by the analog of the Duschinsky matrix D. This matrix D is defined as D = (LI)-1LII where LI and LII are the matrices of the vibrational modes of the two states of the molecule under investigation. They are obtained by solving the vibrational problems in the I and II electronic states, respectively. Choosing the dominant elements in columns of the D matrix and permuting these columns to arrange these elements along the diagonal of the transformed matrix Dast makes it possible to establish the correct co-assignment of the calculated frequencies in the two electronic states. The rows of Dast are for the vibrations in the I electronic state, whereas the columns are for vibrations in the II electronic state. The results obtained may be tested by analogous calculations of Dast for isotopologues. The feasibility of co-assignments of the vibrational frequencies in the ground and T_1 and S_1 excited electronic states are demonstrated for trans-C_2O_2F_2. The analogs of the Duschinsky matrix Dast were used to juxtapose the vibrational frequencies of this molecule calculated at the CASPT2/cc-pVTZ level in the S_0, T_1 and S_1 states. F. Duschinsky, Acta Physicochim. URSS, 7(4), 551-566 (1937). Yu. N. Panchenko, Vibrational spectroscopy, 68, 236-240 (2013).

  16. Structure-borne sound structural vibrations and sound radiation at audio frequencies

    CERN Document Server

    Cremer, L; Petersson, Björn AT

    2005-01-01

    Structure-Borne Sound"" is a thorough introduction to structural vibrations with emphasis on audio frequencies and the associated radiation of sound. The book presents in-depth discussions of fundamental principles and basic problems, in order to enable the reader to understand and solve his own problems. It includes chapters dealing with measurement and generation of vibrations and sound, various types of structural wave motion, structural damping and its effects, impedances and vibration responses of the important types of structures, as well as with attenuation of vibrations, and sound radi

  17. Electrostatic energy harvesting device with dual resonant structure for wideband random vibration sources at low frequency

    Science.gov (United States)

    Zhang, Yulong; Wang, Tianyang; Zhang, Ai; Peng, Zhuoteng; Luo, Dan; Chen, Rui; Wang, Fei

    2016-12-01

    In this paper, we present design and test of a broadband electrostatic energy harvester with a dual resonant structure, which consists of two cantilever-mass subsystems each with a mass attached at the free edge of a cantilever. Comparing to traditional devices with single resonant frequency, the proposed device with dual resonant structure can resonate at two frequencies. Furthermore, when one of the cantilever-masses is oscillating at resonance, the vibration amplitude is large enough to make it collide with the other mass, which provides strong mechanical coupling between the two subsystems. Therefore, this device can harvest a decent power output from vibration sources at a broad frequency range. During the measurement, continuous power output up to 6.2-9.8 μW can be achieved under external vibration amplitude of 9.3 m/s2 at a frequency range from 36.3 Hz to 48.3 Hz, which means the bandwidth of the device is about 30% of the central frequency. The broad bandwidth of the device provides a promising application for energy harvesting from the scenarios with random vibration sources. The experimental results indicate that with the dual resonant structure, the vibration-to-electricity energy conversion efficiency can be improved by 97% when an external random vibration with a low frequency filter is applied.

  18. Detection of two identical frequency vibrations by phase discrimination in polarization-OTDR

    Science.gov (United States)

    Wang, Feng; Pan, Yun; Zhang, MingJiang; Cao, Chunqi; Zhang, Xuping

    2017-04-01

    In this paper, a new detection method for two identical frequency vibrations along optic fiber is proposed, by discrimination of their phase relationship in polarization optical time-domain reflectometer (POTDR). A vibration on fiber would modulate its index and birefringence, then it can consequently change the state of polarization (SOP) of the scattering signal. However, multiple simultaneous vibrations at different positions would result in random fluctuating SOP of the scattering signal, which make them very difficult to be identified. In our proposed method, the phase of the vibration signal along the fiber is obtained by Fast Fourier Transform. Therefore, two vibration events with the same frequency could be distinguished effectively by using the pattern of the phase distribution. The principle of the method is analyzed in detail. Both simulation and experiment results are presented to demonstrate the validity and limitation of this method. It could be widely used for safety monitoring of long distance perimeters, electrical transmission line, and so on.

  19. Enhancement to Non-Contacting Stress Measurement of Blade Vibration Frequency

    Science.gov (United States)

    Platt, Michael; Jagodnik, John

    2011-01-01

    A system for turbo machinery blade vibration has been developed that combines time-of-arrival sensors for blade vibration amplitude measurement and radar sensors for vibration frequency and mode identification. The enabling technology for this continuous blade monitoring system is the radar sensor, which provides a continuous time series of blade displacement over a portion of a revolution. This allows the data reduction algorithms to directly calculate the blade vibration frequency and to correctly identify the active modes of vibration. The work in this project represents a significant enhancement in the mode identification and stress calculation accuracy in non-contacting stress measurement system (NSMS) technology when compared to time-of-arrival measurements alone.

  20. The Possible Interstellar Anion CH2CN-: Spectroscopic Constants, Vibrational Frequencies, and Other Considerations

    Science.gov (United States)

    Fortenberry, Ryan C.; Crawford, T. Daniel; Lee, Timothy J.

    2012-01-01

    The A 1B1 anion (CH2CN??) has been hypothesized as the carrier for one di use interstellar band. However, this particular molecular system has not been detected in the interstellar medium even though the related cyanomethyl radical and the isoelectronic ketenimine molecule have been found. In this study we are employing the use of proven quartic force elds and second-order vibrational perturbation theory to compute accurate spectroscopic constants and fundamental vibrational frequencies for X 1A0 CH2CN?? in order to assist in laboratory studies and astronomical observations. Keywords: Astrochemistry, ISM: molecular anions, Quartic force elds, Rotational constants, Vibrational frequencies

  1. Coarse-fine adaptive tuned vibration absorber with high frequency resolution

    Science.gov (United States)

    Wang, Xi; Yang, Bintang; You, Jiaxin; Gao, Zhe

    2016-11-01

    The speed fluctuation of satellite-rotary-mechanisms causes vibration of slightly different frequencies. The critical requirements of satellites need a vibration control device with high frequency resolution to suppress the vibration. This paper presents a coarse-fine adaptive tuned vibration absorber (ATVA) with high frequency resolution. The coarse-fine ATVA which simultaneously satisfies the requirements of high resolution and relatively wide effective bandwidth is capable of tracking the variable exciting frequency adaptively to suppress the vibration of the primary system. The coarse-fine ATVA is divided into a coarse tuning segment and a fine tuning segment. The coarse tuning segment is used to tune the required natural frequency in a relatively wide effective bandwidth and the fine tuning segment can achieve precise tune in a tiny-scale bandwidth. The mathematical model of the coarse tuning and the fine tuning is proposed to design the parameters of the coarse-fine ATVA. The experimental test results indicate the coarse tuning bandwidth of the coarse-fine ATVA is 8.7 Hz to 29 Hz and the minimum resolution of the fine tuning is 0.05 Hz. Moreover, a significant vibration attenuation of 15dB is verified in the effective bandwidth.

  2. DIAGNOSIS SHAFT BEARINGS NODE KNIFE CUTTER FOR LOW-FREQUENCY VIBRATION

    Directory of Open Access Journals (Sweden)

    S. T. Antipov

    2015-01-01

    Full Text Available The currently used system of preventive maintenance is not effective enough. Vibration diagnostics is one of the modern methods of non-destructive testing equipment components, allowing to define the appearance of defects in the early stages. The paper identifies the main areas of research, as well as selected research object, selected non-destructive testing method for efficiently determining the actual state of dynamically operating equipment. Is a schematic of vibration sensors. Measuring point vibration parameters were determined experimentally based on the conditions for obtaining the most informative vibroacoustic signal. Determine the behavior of the cutter under which minimizes the occurrence of a wide range of fluctuations that affects the accuracy of the measurements. For vibration analysis method was chosen direct spectral analysis, which involves the detection of repetitive vibrations. Presented graphically vibration spectra and spectra of vibration signals. Analysis of a wide range of vibration spectrum allowed to allocate land on which showed a significant increase in the values of vibration. Processing of the selected portion of the spectrum has led to the conclusion that in the bearing, shock pulses are in contact with each rolling body shell, and as a result, a number of harmonics in the individual frequencies. Was made a comparative analysis of the spectra of working with a defective bearing bearing on the same frequencies and determine the average increase in the values of vibration. Spectral analysis is an effective method to determine not only the extent of the defect and its location, but also allows you to effectively predict its development. The results may be useful for specialists involved in vibration diagnostics, calculation and design of rotary machines.

  3. Frequency characteristics of human muscle and cortical responses evoked by noisy Achilles tendon vibration.

    Science.gov (United States)

    Mildren, Robyn Lynne; Peters, Ryan M; Hill, Aimee J; Blouin, Jean-Sebastien; Carpenter, Mark Gregory; Inglis, J Timothy

    2017-02-16

    Noisy stimuli, along with linear systems analysis, have proven to be effective for mapping functional neural connections. We explored the use of noisy (10-115 Hz) Achilles tendon vibration to examine proprioceptive reflexes in the triceps surae muscles in standing healthy young adults (n = 8). We also examined the association between noisy vibration and electrical activity recorded over the sensorimotor cortex using electroencephalography. We applied two-minutes of vibration and recorded ongoing muscle activity of the soleus and gastrocnemii using surface electromyography (EMG). Vibration amplitude was varied to characterize reflex scaling and to examine how different stimulus levels affected postural sway. Muscle activity from the soleus and gastrocnemii were significantly correlated with the tendon vibration across a broad frequency range (~10-80 Hz), with a peak located at ~40 Hz. Vibration-EMG coherence positively scaled with stimulus amplitude in all three muscles, with soleus displaying the strongest coupling and steepest scaling. EMG responses lagged the vibration by ~38 ms, a delay that paralleled observed response latencies to tendon taps. Vibration-evoked cortical oscillations were observed at frequencies ~40-70 Hz (peak ~54 Hz) in most subjects, a finding in line with previous reports of sensory evoked γ-band oscillations. Further examination of the method revealed a) accurate reflex estimates could be obtained with <60 s of low-level (RMS=10 m/s(2)) vibration, b) responses did not habituate over two-minutes of exposure, and importantly c) noisy vibration had a minimal influence on standing balance. Our findings suggest noisy tendon vibration is an effective novel approach to characterize proprioceptive reflexes.

  4. Electrostatics determine vibrational frequency shifts in hydrogen bonded complexes.

    Science.gov (United States)

    Dey, Arghya; Mondal, Sohidul Islam; Sen, Saumik; Ghosh, Debashree; Patwari, G Naresh

    2014-12-14

    The red-shifts in the acetylenic C-H stretching vibration of C-H∙∙∙X (X = O, N) hydrogen-bonded complexes increase with an increase in the basicity of the Lewis base. Analysis of various components of stabilization energy suggests that the observed red-shifts are correlated with the electrostatic component of the stabilization energy, while the dispersion modulates the stabilization energy.

  5. The effects of low-frequency vibrations on hepatic profile of blood

    Science.gov (United States)

    Damijan, Z.

    2008-02-01

    Body vibrations training has become popular in sports training, fitness activity, it is still a rare form of physical rehabilitation.. Vibrations are transmitted onto the whole body or some body parts of an exercising person via a vibration platform subjected to mechanical vertical vibrations. During the training session a participant has to maintain his body position or do exercises that engage specific muscles whilst vibrations of the platform are transmitted onto the person's body. This paper is the continuation of the earlier study covering the effects of low-frequency vibrations on selected physiological parameters of the human body. The experiments were conducted to find the answer to the question if vibration exposure (total duration of training sessions 6 hours 20 min) should produce any changes in hepatic profile of blood. Therefore a research program was undertaken at the University of Science and Technology AGH UST to investigate the effects of low-frequency vibration on selected parameters of hepatic profile of human blood. Cyclic fluctuations of bone loading were induced by the applied harmonic vibration 3.5 Hz and amplitude 0.004 m. The experiments utilizing two vibrating platforms were performed in the Laboratory of Structural Acoustics and Biomedical Engineering AGH-UST. The applied vibrations were harmless and not annoying, in accordance with the standard PN-EN ISO 130901-1, 1998. 23 women volunteers had 19 sessions on subsequent working days, at the same time of day. during the tests the participants remained in the standing position, passive. The main hypothesis has it that short-term low-frequency vibration exposure might bring about the changes of the hepatic profile of blood, including: bilirubin (BILIRUBIN), alkaline phosphatase (Alp), alanine aminotransferase (ALT), aspartate aminotransferase (AST) and albumin (ALBUMIN) levels. Research data indicate the low-frequency vibrations exposure produces statistically significant decrease of

  6. An extension of command shaping methods for controlling residual vibration using frequency sampling

    Science.gov (United States)

    Singer, Neil C.; Seering, Warren P.

    1992-01-01

    The authors present an extension to the impulse shaping technique for commanding machines to move with reduced residual vibration. The extension, called frequency sampling, is a method for generating constraints that are used to obtain shaping sequences which minimize residual vibration in systems such as robots whose resonant frequencies change during motion. The authors present a review of impulse shaping methods, a development of the proposed extension, and a comparison of results of tests conducted on a simple model of the space shuttle robot arm. Frequency shaping provides a method for minimizing the impulse sequence duration required to give the desired insensitivity.

  7. The correction of vibration in frequency scanning interferometry based absolute distance measurement system for dynamic measurements

    Science.gov (United States)

    Lu, Cheng; Liu, Guodong; Liu, Bingguo; Chen, Fengdong; Zhuang, Zhitao; Xu, Xinke; Gan, Yu

    2015-10-01

    Absolute distance measurement systems are of significant interest in the field of metrology, which could improve the manufacturing efficiency and accuracy of large assemblies in fields such as aircraft construction, automotive engineering, and the production of modern windmill blades. Frequency scanning interferometry demonstrates noticeable advantages as an absolute distance measurement system which has a high precision and doesn't depend on a cooperative target. In this paper , the influence of inevitable vibration in the frequency scanning interferometry based absolute distance measurement system is analyzed. The distance spectrum is broadened as the existence of Doppler effect caused by vibration, which will bring in a measurement error more than 103 times bigger than the changes of optical path difference. In order to decrease the influence of vibration, the changes of the optical path difference are monitored by a frequency stabilized laser, which runs parallel to the frequency scanning interferometry. The experiment has verified the effectiveness of this method.

  8. Development and application of a low-frequency FBG vibration sensor

    Science.gov (United States)

    Nan, Qiu-ming

    2010-10-01

    Dynamic monitoring is part of bridge structural health monitoring. Real-time and online monitoring for bridge's dynamic performance is an important technology means for model updating, damage detection of structure and security evaluation of bridge. Nowadays dynamic monitoring system is generally installed on new long-span bridges. Vibration sensor is key part of the technology means. Vibration of a large-scale bridge belongs to low frequency one, but traditional electromagnetic vibration sensors are restricted for use in the field due to such defects as signal unable to long distance transmission, hard to measure ultra-low frequency vibration, so it is inevitable and imminent to develop a novel-type vibration sensor instead of them. Aiming at the above-mentioned problems, the author in the paper develops a low-frequency vibration sensor with double-cantilever beam structure, based on fiber Bragg grating (FBG) and matching filtering demodulation. Some experiments are done to study its sensing properties and the results indicate that it has good temperature compensation, its natural frequency is about 35Hz, measurement bandwidth from 0.1Hz to 20Hz, sensitivity is 1000mv/g or so, linearity degree is over 0.9992, repeatability is superior to 2.4%, acceleration measurement range is 1g, and cross anti-interference is 5.6%. Such sensors have been successfully used on Wuhan Tianxingzhou Yangtze River Bridge(WTYRB). The most transmission distance of measurement signal is 10km or so and the lowest measurement frequency is 0.24 Hz. The application results show it can detect accurately dynamic properties of vital areas of the bridge and can meet the demands for dynamic measurement. To sum up, the sensor developed in the paper can overcome the shortcomings of electromagnetic sensors and has very good sensing properties, so it is very suitable to be used for low-frequency vibration measurement.

  9. Low frequency vibrations induce malformations in two aquatic species in a frequency-, waveform-, and direction-specific manner.

    Directory of Open Access Journals (Sweden)

    Laura N Vandenberg

    Full Text Available Environmental toxicants such as industrial wastes, air particulates from machinery and transportation vehicles, and pesticide run-offs, as well as many chemicals, have been widely studied for their effects on human and wildlife populations. Yet other potentially harmful environmental pollutants such as electromagnetic pulses, noise and vibrations have remained incompletely understood. Because developing embryos undergo complex morphological changes that can be affected detrimentally by alterations in physical forces, they may be particularly susceptible to exposure to these types of pollutants. We investigated the effects of low frequency vibrations on early embryonic development of two aquatic species, Xenopus laevis (frogs and Danio rerio (zebrafish, specifically focusing on the effects of varying frequencies, waveforms, and applied direction. We observed treatment-specific effects on the incidence of neural tube defects, left-right patterning defects and abnormal tail morphogenesis in Xenopus tadpoles. Additionally, we found that low frequency vibrations altered left-right patterning and tail morphogenesis, but did not induce neural tube defects, in zebrafish. The results of this study support the conclusion that low frequency vibrations are toxic to aquatic vertebrates, with detrimental effects observed in two important model species with very different embryonic architectures.

  10. S-shape spring sensor: Sensing specific low-frequency vibration by energy harvesting

    Science.gov (United States)

    Zhang, Lan; Lu, Jian; Takei, Ryohei; Makimoto, Natsumi; Itoh, Toshihiro; Kobayashi, Takeshi

    2016-08-01

    We have developed a Si-based microelectromechanical systems sensor with high sensitivity for specific low-frequency vibration-sensing and energy-harvesting applications. The low-frequency vibration sensor contains a disk proof mass attached to two or three lead zirconate titanate (PZT) S-shape spring flexures. To obtain a faster and less expensive prototype, the design and optimization of the sensor structure are studied via finite-element method analysis. To validate the sensor structure to detect low-frequency vibration, the effects of geometrical dimensions, including the width and diameter of the S-shape spring of the proof mass, were analyzed and measured. The functional features, including the mechanical property and electrical performance of the vibration sensor, were evaluated. The results demonstrated that a very low resonant frequency of 0.2g can be typically achieved. Given a low-frequency vibration sensor with ideal performance and mass fabrication, many advanced civilian and industrial applications can be possibly realized.

  11. S-shape spring sensor: Sensing specific low-frequency vibration by energy harvesting.

    Science.gov (United States)

    Zhang, Lan; Lu, Jian; Takei, Ryohei; Makimoto, Natsumi; Itoh, Toshihiro; Kobayashi, Takeshi

    2016-08-01

    We have developed a Si-based microelectromechanical systems sensor with high sensitivity for specific low-frequency vibration-sensing and energy-harvesting applications. The low-frequency vibration sensor contains a disk proof mass attached to two or three lead zirconate titanate (PZT) S-shape spring flexures. To obtain a faster and less expensive prototype, the design and optimization of the sensor structure are studied via finite-element method analysis. To validate the sensor structure to detect low-frequency vibration, the effects of geometrical dimensions, including the width and diameter of the S-shape spring of the proof mass, were analyzed and measured. The functional features, including the mechanical property and electrical performance of the vibration sensor, were evaluated. The results demonstrated that a very low resonant frequency of 0.2g can be typically achieved. Given a low-frequency vibration sensor with ideal performance and mass fabrication, many advanced civilian and industrial applications can be possibly realized.

  12. Measurement of Mechatronic Property of Biological Gel with Micro-Vibrating Electrode at Ultrasonic Frequency

    Directory of Open Access Journals (Sweden)

    Shigehiro Hashimoto

    2008-10-01

    Full Text Available A measurement system has been designed with a micro-vibrating electrode at ultrasonic frequency to measure local impedance of biological gel in vitro. The designed system consists of two electrodes, where one of the electrodes vibrates with a piezoelectric actuator. The component of variation at impedance between two electrodes with vibration of one electrode is analyzed at the corresponding spectrum. The manufactured system was applied to measure impedance of a physiological saline solution, a potassium chloride solution, a dextran aqueous solution, and an egg. The experimental results show that the designed system is effective to measure local mechatronic property of biological gel.

  13. One Atomic Beam as a Detector of Classical Harmonic Vibrations with Micro Amplitudes and Low Frequencies

    CERN Document Server

    Wong, Werner

    2013-01-01

    We propose a simplest detector of harmonic vibrations with micro amplitudes and low frequencies, i.e. the detector consisting of one atomic beam. Here the atomic beam is induced by a plane harmonic wave and has a classical collective harmonic vibrations, which vibrant directions are perpendicular to the wave vectors of atomic beam. Compared with the detector consisting of atomic Mach-Zehnder interferometer, the new detector has two advantages: (1) it is suitable for the detection of the harmonic vibrations induced either by a longitudinal plane harmonic wave or by a transverse plane harmonic wave; (2) the quantum noise fluctuation of the atomic beam is exactly zero.

  14. A magnetic-spring-based, low-frequency-vibration energy harvester comprising a dual Halbach array

    Science.gov (United States)

    Salauddin, M.; Halim, M. A.; Park, J. Y.

    2016-09-01

    Energy harvesting that uses low-frequency vibrations is attractive due to the availability of such vibrations throughout the ambient environment. Significant power generation at low-frequency vibrations, however, is challenging because the power flow decreases as the frequency decreases; moreover, designing a spring-mass system that is suitable for low-frequency-vibration energy harvesting is difficult. In this work, our proposed device overcomes both of these challenges by using a dual Halbach array and magnetic springs. Each Halbach array concentrates the magnetic-flux lines on one side of the array while suppressing the flux lines on the other side; therefore, a dual Halbach array allows for an interaction between the concentrated magnetic-flux lines and the same coil so that the maximum flux linkage occurs. During the experiment, vibration was applied in a horizontal direction to reduce the gravity effect on the Halbach-array structure. To achieve an increased power generation at low-amplitude and low-frequency vibrations, the magnetic structure of the dual Halbach array and the magnetic springs were optimized in terms of the operating frequency and the power density; subsequently, a prototype was fabricated and tested. The prototype device offers a normalized power density of 133.45 μW cm-3 g-2 that is much higher than those of recently reported electromagnetic energy harvesters; furthermore, it is capable of delivering a maximum average power of 1093 μW to a 44 Ω optimum load, at an 11 Hz resonant frequency and under a 0.5 g acceleration.

  15. Study of the solvent effects on the molecular structure and Cdbnd O stretching vibrations of flurbiprofen

    Science.gov (United States)

    Tekin, Nalan; Pir, Hacer; Sagdinc, Seda

    2012-12-01

    The effects of 15 solvents on the C=O stretching vibrational frequency of flurbiprofen (FBF) were determined to investigate solvent-solute interactions. Solvent effects on the geometry and C=O stretching vibrational frequency, ν(C=O), of FBF were studied theoretically at the DFT/B3LYP and HF level in combination with the polarizable continuum model and experimentally using attenuated total reflection infrared spectroscopy (ATR-IR). The calculated C=O stretching frequencies in the liquid phase are in agreement with experimental values. Moreover, the wavenumbers of ν(C=O) of FBF in different solvents have been obtained and correlated with the Kirkwood-Bauer-Magat equation (KBM), the solvent acceptor numbers (ANs), and the linear solvation energy relationships (LSERs). The solvent-induced stretching vibrational frequency shifts displayed a better correlation with the LSERs than with the ANs and KBM.

  16. Application of coupled analysis methods for prediction of blast-induced dominant vibration frequency

    Science.gov (United States)

    Li, Haibo; Li, Xiaofeng; Li, Jianchun; Xia, Xiang; Wang, Xiaowei

    2016-03-01

    Blast-induced dominant vibration frequency (DVF) involves a complex, nonlinear and small sample system considering rock properties, blasting parameters and topography. In this study, a combination of grey relational analysis and dimensional analysis procedures for prediction of dominant vibration frequency are presented. Six factors are selected from extensive effect factor sequences based on grey relational analysis, and then a novel blast-induced dominant vibration frequency prediction is obtained by dimensional analysis. In addition, the prediction is simplified by sensitivity analysis with 195 experimental blast records. Validation is carried out for the proposed formula based on the site test database of the firstperiod blasting excavation in the Guangdong Lufeng Nuclear Power Plant (GLNPP). The results show the proposed approach has a higher fitting degree and smaller mean error when compared with traditional predictions.

  17. An analytical model for a piezoelectric vibration energy harvester with resonance frequency tunability

    Directory of Open Access Journals (Sweden)

    Yun Wang

    2015-06-01

    Full Text Available This article conceptually proposes a new method to tune the resonance frequency of piezoelectric vibration energy harvesters, in which the supporting position of the vibrator can be adjusted for frequency tuning. The corresponding analytical model is established to predict the performances of the harvester based on the principles of energy. First, the equivalent stiffness and mass of the vibrator in bending mode are derived explicitly for the different supporting positions. A simple analysis method is then established for the frequency, output voltage, and output power. Finally, some numerical examples are given to demonstrate the presented method. The results are also compared with those by finite element method and good agreement is observed.

  18. Conformal analysis of fundamental frequency of vibration of elastic clamped plates

    Institute of Scientific and Technical Information of China (English)

    QI Hongyuan; ZHU Hengjun

    2007-01-01

    To calculate the fundamental frequency of vibration of special-shaped and elastic clamped plates, the conformal mapping theory is adopted to separate the interpolating points of a complicated boundary into odd and even sequences,both of which can be mutually iterated, so that the conformal mapping function between the complicated region and the unit dish region is established. Trigonometric interpolation and convergence along the normal direction methods are provided, and the complex coefficients of the conformal mapping function are calculated. Galerkin method is used to obtain the solution of fundamental frequency in the vibrating differential function of the complicated vibrating region.Finally, taking ellipse elastic clamped plates as an example,the effects on fundamental frequency coefficient caused by eccentric ratio e and area size are analyzed.

  19. Calculations of the vibrational frequency and isotopic shift of UF6 and U2F6

    Institute of Scientific and Technical Information of China (English)

    Zhang Yun-Guang; Zha Xin-Wei

    2012-01-01

    Molecular structure,vibrational frequency and infrared intensity of UF6 are investigated by using the revised Perdew-Burke-Enzerhof function with the triple-zeta polarized basis set.The calculation results are in good agreement with the experimental values and indicate the existence of a stable U2F6 molecule with a multiple bonded U2 unit.The calculation results also predict that the D3d symmetry of U2F6 is more stable than D3h.The optimized geometries,vibrational frequencies,and infrared intensities are also reported for U2F6 molecules in D3d symmetry.In addition,the isotopic shift of vibrational frequencies of the two molecules under isotopic substitution of uranium atom are also investigated with the same method.The U2F6 molecule is predicted to be better than UF6 for laser uranic isotope separation.

  20. Peculiarities of the Third Natural Frequency Vibrations of a Cantilever for the Improvement of Energy Harvesting

    Directory of Open Access Journals (Sweden)

    Vytautas Ostasevicius

    2015-05-01

    Full Text Available This paper focuses on several aspects extending the dynamical efficiency of a cantilever beam vibrating in the third mode. A few ways of producing this mode stimulation, namely vibro-impact or forced excitation, as well as its application for energy harvesting devices are proposed. The paper presents numerical and experimental analyses of novel structural dynamics effects along with an optimal configuration of the cantilever beam. The peculiarities of a cantilever beam vibrating in the third mode are related to the significant increase of the level of deformations capable of extracting significant additional amounts of energy compared to the conventional harvester vibrating in the first mode. Two types of a piezoelectric vibrating energy harvester (PVEH prototype are analysed in this paper: the first one without electrode segmentation, while the second is segmented using electrode segmentation at the strain nodes of the third vibration mode to achieve effective operation at the third resonant frequency. The results of this research revealed that the voltage generated by any segment of the segmented PVEH prototype excited at the third resonant frequency demonstrated a 3.4–4.8-fold increase in comparison with the non-segmented prototype. Simultaneously, the efficiency of the energy harvester prototype also increased at lower resonant frequencies from 16% to 90%. The insights presented in the paper may serve for the development and fabrication of advanced piezoelectric energy harvesters which would be able to generate a considerably increased amount of electrical energy independently of the frequency of kinematical excitation.

  1. Peculiarities of the third natural frequency vibrations of a cantilever for the improvement of energy harvesting.

    Science.gov (United States)

    Ostasevicius, Vytautas; Janusas, Giedrius; Milasauskaite, Ieva; Zilys, Mindaugas; Kizauskiene, Laura

    2015-05-28

    This paper focuses on several aspects extending the dynamical efficiency of a cantilever beam vibrating in the third mode. A few ways of producing this mode stimulation, namely vibro-impact or forced excitation, as well as its application for energy harvesting devices are proposed. The paper presents numerical and experimental analyses of novel structural dynamics effects along with an optimal configuration of the cantilever beam. The peculiarities of a cantilever beam vibrating in the third mode are related to the significant increase of the level of deformations capable of extracting significant additional amounts of energy compared to the conventional harvester vibrating in the first mode. Two types of a piezoelectric vibrating energy harvester (PVEH) prototype are analysed in this paper: the first one without electrode segmentation, while the second is segmented using electrode segmentation at the strain nodes of the third vibration mode to achieve effective operation at the third resonant frequency. The results of this research revealed that the voltage generated by any segment of the segmented PVEH prototype excited at the third resonant frequency demonstrated a 3.4-4.8-fold increase in comparison with the non-segmented prototype. Simultaneously, the efficiency of the energy harvester prototype also increased at lower resonant frequencies from 16% to 90%. The insights presented in the paper may serve for the development and fabrication of advanced piezoelectric energy harvesters which would be able to generate a considerably increased amount of electrical energy independently of the frequency of kinematical excitation.

  2. A small-form-factor piezoelectric vibration energy harvester using a resonant frequency-down conversion

    Energy Technology Data Exchange (ETDEWEB)

    Sun, Kyung Ho; Kim, Young-Cheol [Department of System Dynamics, Korea Institute of Machinery and Materials, 156 Gajeongbuk-Ro, Yuseong-Gu, Daejeon 305-343 (Korea, Republic of); Kim, Jae Eun, E-mail: jekim@cu.ac.kr [School of Mechanical and Automotive Engineering, Catholic University of Daegu, 13-13 Hayang-Ro, Hayang-Eup, Gyeongsan-Si, Gyeongsangbuk-Do 712-702 (Korea, Republic of)

    2014-10-15

    While environmental vibrations are usually in the range of a few hundred Hertz, small-form-factor piezoelectric vibration energy harvesters will have higher resonant frequencies due to the structural size effect. To address this issue, we propose a resonant frequency-down conversion based on the theory of dynamic vibration absorber for the design of a small-form-factor piezoelectric vibration energy harvester. The proposed energy harvester consists of two frequency-tuned elastic components for lowering the first resonant frequency of an integrated system but is so configured that an energy harvesting beam component is inverted with respect to the other supporting beam component for a small form factor. Furthermore, in order to change the unwanted modal characteristic of small separation of resonant frequencies, as is the case with an inverted configuration, a proof mass on the supporting beam component is slightly shifted toward a second proof mass on the tip of the energy harvesting beam component. The proposed small-form-factor design capability was experimentally verified using a fabricated prototype with an occupation volume of 20 × 39 × 6.9 mm{sup 3}, which was designed for a target frequency of as low as 100 Hz.

  3. A small-form-factor piezoelectric vibration energy harvester using a resonant frequency-down conversion

    Directory of Open Access Journals (Sweden)

    Kyung Ho Sun

    2014-10-01

    Full Text Available While environmental vibrations are usually in the range of a few hundred Hertz, small-form-factor piezoelectric vibration energy harvesters will have higher resonant frequencies due to the structural size effect. To address this issue, we propose a resonant frequency-down conversion based on the theory of dynamic vibration absorber for the design of a small-form-factor piezoelectric vibration energy harvester. The proposed energy harvester consists of two frequency-tuned elastic components for lowering the first resonant frequency of an integrated system but is so configured that an energy harvesting beam component is inverted with respect to the other supporting beam component for a small form factor. Furthermore, in order to change the unwanted modal characteristic of small separation of resonant frequencies, as is the case with an inverted configuration, a proof mass on the supporting beam component is slightly shifted toward a second proof mass on the tip of the energy harvesting beam component. The proposed small-form-factor design capability was experimentally verified using a fabricated prototype with an occupation volume of 20 × 39 × 6.9 mm3, which was designed for a target frequency of as low as 100 Hz.

  4. Broadband electromagnetic power harvester from vibrations via frequency conversion by impact oscillations

    Energy Technology Data Exchange (ETDEWEB)

    Yuksek, N. S.; Almasri, M. [Electrical and Computer Engineering, University of Missouri, Columbia, Missouri 65211 (United States); Feng, Z. C. [Mechanical and Aerospace Engineering, University of Missouri, Columbia, Missouri 65211 (United States)

    2014-09-15

    In this paper, we propose an electromagnetic power harvester that uses a transformative multi-impact approach to achieve a wide bandwidth response from low frequency vibration sources through frequency-up conversion. The device consists of a pick-up coil, fixed at the free edge of a cantilever beam with high resonant frequency, and two cantilever beams with low excitation frequencies, each with an impact mass attached at its free edge. One of the two cantilevers is designed to resonate at 25 Hz, while the other resonates at 50 Hz within the range of ambient vibration frequency. When the device is subjected to a low frequency vibration, the two low-frequency cantilevers responded by vibrating at low frequencies, and thus their thick metallic masses made impacts with the high resonance frequency cantilever repeatedly at two locations. This has caused it along with the pick-up coil to oscillate, relative to the permanent magnet, with decaying amplitude at its resonance frequency, and results in a wide bandwidth response from 10 to 63 Hz at 2 g. A wide bandwidth response between 10–51 Hz and 10–58 Hz at acceleration values of 0.5 g and 2 g, respectively, were achieved by adjusting the impact cantilever frequencies closer to each other (25 Hz and 45 Hz). A maximum output power of 85 μW was achieved at 5 g at 30 Hz across a load resistor, 2.68 Ω.

  5. The influence of Exciting Frequency on N2 and N+2 Vibrational Temperature of Nitrogen Capacitively Coupled Plasma

    Institute of Scientific and Technical Information of China (English)

    HUANG Xiao-Jiang; XIN Yu; ZHANG Jie; NING Zhao-Yuan

    2009-01-01

    By using optical emission spectroscopy (OES), N2 and N+2 vibrational temperatures in capacitively coupled plasma discharges with different exciting frequencies are investigated. The vibrational temperatures are acquired by comparing the measured and calculated spectra of selected transitions with a least-square procedure. It is found that 512 and N+2 vibrational temperatures almost increase linearly with increasing exciting frequency up to 23 MHz, then increase slowly or even decrease. The pressure corresponding to the maximum point of N2 vibrational temperature decreases with the increasing exciting frequency. These experimental phenomena are attributed to the increasing electron density, whereas the electron temperature decreases with exciting frequency rising.

  6. Effect of Frequency and Vibration Time on Shaker Performance for Mechanized Harvesting of Orange (Thomson cultivar)

    OpenAIRE

    H Ghorbanpour; M.H Khoshtaghaza; M.R Mostofi Sarkari

    2012-01-01

    Manual citrus harvesting is commonly performing hard, expensive and time consuming. In this study, a factorial experiment with a completely randomized design in three replications was performed to find out the effect of frequency (three levels of 5, 7.5 and 10 Hz), vibration time (three levels of 10, 15 and 20 seconds) on harvesting capacity and losses of Thomson cultivar of orange. The results indicated that the effect of frequency and vibration time was significant (P≤0.01) on the harvestin...

  7. Experimental study on vibration frequency response of micro-bend optic-fiber sensor

    Institute of Scientific and Technical Information of China (English)

    Fuxiang Qin; Honggang Li; Wande Fan; Qiuqin Sheng

    2009-01-01

    We make an experimental study on vibration frequency response of micro-bend optic-fiber sensor, and single-mode fibers and multi-mode fibers are used as the sensitive optic-fibers. Contrast between the two sensitive fibers is presented. Result shows that the micro-bend optic-fiber sensor has good frequency response characteristics and strong ability to restore the waveform. With the frequency varying in the range of 500 - 4762 Hz, the vibration sensors using multi-mode optic-fiber as the sensitive fiber is more sensitive than that using single-mode optic-fiber. And the former has better frequency response characteristics and stronger capacity of waveform revivification. But with the frequency in the range of 287 - 500 Hz, the latter is better.

  8. Vibration Mode Observation of Piezoelectric Disk-type Resonator by High Frequency Laser Doppler Vibrometer

    Science.gov (United States)

    Matsumura, Takeshi; Esashi, Masayoshi; Harada, Hiroshi; Tanaka, Shuji

    For future mobile phones based on cognitive radio technology, a compact multi-band RF front-end architecture is strongly required and an integrated multi-band RF filter bank is a key component in it. Contour-mode resonators are receiving increased attention for a multi-band filter solution, because its resonant frequency is mainly determined by its size and shape, which are defined by lithography. However, spurious responses including flexural vibration are also excited due to its thin structure. To improve resonator performance and suppress spurious modes, visual observation with a laser probe system is very effective. In this paper, we have prototyped a mechanically-coupled disk-array filter, which consists of a Si disk and 2 disk-type resonators of higher-order wine-glass mode, and observed its vibration modes using a high-frequency laser-Doppler vibrometer (UHF-120, Polytec, Inc.). As a result, it was confirmed that higher order wine-glass mode vibration included a compound displacement, and that its out-of-plane vibration amplitude was much smaller than other flexural spurious modes. The observed vibration modes were compared with FEM (Finite Element Method) simulation results. In addition, it was also confirmed that the fabrication error, e.g. miss-alignment, induced asymmetric vibration.

  9. Flextensional fiber Bragg grating-based accelerometer for low frequency vibration measurement

    Institute of Scientific and Technical Information of China (English)

    Jinghua Zhang; Xueguang Qiao; Manli Hu; Zhongyao Feng; Hong Gao; Yang Yang; Rui Zhou

    2011-01-01

    @@ The intelligent structural health monitoring method,which uses a fiber Bragg grating(FBG)sensor,is a new approach in the field of civil engineering.However,it lacks a reliable FBG-based accelerometer for taking structural low frequency vibration measurements.In this letter,a flextensional FBG-based accelerometer is proposed and demonstrated.The experimental results indicate that the natural frequency of the developed accelerometer is 16.7 Hz,with a high sensitivity of 410.7 pm/g.In addition,it has a broad and flat response over low frequencies ranging from 1 to 10 Hz.The natural frequency and sensitivity of the accelerometer can be tuned by adding mass to tailor the sensor performance to specific applications.Experimental results are presented to demonstrate the good performance of the proposed FBG-based accelerometer.These results show that the proposed accelerometer is satisfactory for low frequency vibration measurements.%The intelligent structural health monitoring method, which uses a fiber Bragg grating {FBG} sensor, ie a new approach in the field of civil engineering. However, it lacks a reliable FBG-based accelerometer for taking structural low frequency vibration measurements. In this letter, a flextensional FBG-based accelerometer is proposed and demonstrated. The experimental results indicate that the natural frequency of the developed accelerometer is 16.7 Hz, with a high sensitivity of 410.7 pm/g. In addition, it has a broad and flat response over low frequencies ranging from 1 to 10 Hz. The natural frequency and sensitivity of the accelerometer can be tuned by adding mass to tailor the sensor performance to specific applications. Experimental results are presented to demonstrate the good performance of the proposed FBG-based accelerometer. These results show that the proposed accelerometer is satisfactory for low frequency vibration measurements.

  10. Method in calculating own vibration frequencies of open sections bars with thin walls

    Science.gov (United States)

    Mihuț, N.

    2016-08-01

    Dynamic stability of thin-walled bars of open sections, as well as the stability of elastic systems dynamics in general, is studying closely with their vibrations. This, because, areas of dynamics instability is around twice the frequency of free vibration of the bar or elastic system in all cases excitation parametric, on the one hand, and on the other hand matrices involved in the matrix equation of free vibration are matrices of matrix equation of dynamic stability. In this paper we settled differential equations of parametric vibrations of thin-walled straight bars open sections constant as a system with a triple infinity of second order differential equations, linear coefficients homogeneous and periodicals. In the end of work, by customizing differential equations of forced vibration parameters have been obtained differential equations of own vibration of bars with thin wall and open sections as a system with a triple infinity of differential equations of second order, linear, homogeneous with constant coefficients and, using it, the algebraic equation of own vibrations pulsations.

  11. DESIGN AND ANALYSIS OF NOVEL ACTIVE ACTUATOR TO CONTROL LOW FREQUENCY VIBRATIONS OF SHAFT SYSTEM

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    Aiming at providing with high-load capability in active vibration control of large-scale rotor system, a new type of active actuator to simultaneously reduce the dangers of low frequency flexural and torsional vibrations is designed. The actuator employs electro-hydraulic system and can provide a high and circumferential load. To initialize new research, the characteristics of various kinds of active actuators to control rotor shaft vibration are briefly introduced. The purpose of this paper is to introduce the preliminary results via presenting the structure, functions and operating principles, in particular, the working process of the electro-hydraulic system of the new actuator which includes a set of high speed electromagnetic valves and a series of sloping cone-shaped openings, and presenting the transmission relationships among the control parameters from control signals into the valves to active load onto shaft. The course of the work is dynamic, and a series of spatial forces and moments are put on the shaft to get an external resultant force to reduce excitations that induce vibration of shafts. By checking states of vibration, the actuator can control the impulse width and the interval of injection time for applying different control force to a vibration shaft in two circumference directions through the regulating action of a set of combination directional control valves. The results from simulating analysis and experiment show evidence of that this design can satisfy the case of active process of decreasing of flexural and torsional vibrations.

  12. Study of vibrational and magnetic excitations in Ni sub c Mg sub 1 sub - sub c O solid solutions by Raman spectroscopy

    CERN Document Server

    Cazzanelli, E; Mariotto, G; Mironova-Ulmane, N

    2003-01-01

    The Raman scattering by phonons and magnons was studied for the first time in the polycrystalline solid solutions Ni sub c Mg sub 1 sub - sub c O. The experimental Raman spectrum for c = 0.9 is similar to that of NiO and consists of six well resolved bands, whose origins are the disorder-induced one-phonon scattering (bands at 400 and 500 cm sup - sup 1), two-phonon scattering (bands at 750, 900, and 1100 cm sup - sup 1), and two-magnon scattering (the broad band at approx 1400 cm sup - sup 1). We found that the dependence of the two-magnon band in solid solutions on the composition and temperature is consistent with their magnetic phase diagram. We also observed that the relative contribution of two-phonon scattering decreases strongly upon dilution with magnesium ions and disappears completely at c < 0.5. Such behaviour is explained in terms of a disorder-induced effect, which increases the probability of the one-phonon scattering processes.

  13. ORIENTATION AND POSITION EFFECTS OF A LOCAL HETEROGENEITY ON FLEXURAL VIBRATION FREQUENCIES IN WOODEN BEAMS

    Directory of Open Access Journals (Sweden)

    Mehran Roohnia

    2015-06-01

    Full Text Available Studying the influence of defect on the dynamic behavior of wood in order to detect the local heterogeneities is of great importance in non-destructive testing of wood. The natural heterogeneities in wood are oriented in a volume. However, onedimensional models are still used in dynamic characterization of wooden beams. The aim of this study was to experimentally investigate the effects of the orientation and position of an artificial defect on the flexural vibration frequencies. Different batches of Fagus orientalis specimens were drilled in the radial direction at five positions along the specimen. Dynamic tests in free flexural vibration were performed on the specimens before and after drilling both in the longitudinal-radial (LR and longitudinal-tangential (LT bending plan. The behavior in free flexural vibration was found to be different depending on the position and orientation of heterogeneity. When the drilling axis lies in the bending plane (LR, the weakening of frequency was maximal at the location of an antinode of vibration. On the contrary, the frequency offset was maximal in the place of a vibration node when the drilling axis was orthogonal to the bending plane (LT.

  14. Vibrational dephasing and frequency shifts of hydrogen-bonded pyridine-water complexes.

    Science.gov (United States)

    Kalampounias, A G; Tsilomelekis, G; Boghosian, S

    2015-01-25

    In this paper we present the picosecond vibrational dynamics and Raman shifts of hydrogen-bonded pyridine-water complexes present in aqueous solutions in a wide concentration range from dense to extreme dilute solutions. We studied the vibrational dephasing and vibrational frequency modulation by calculating time correlation functions of vibrational relaxation by fits in the frequency domain. The concentration induced variations in bandwidths, band frequencies and characteristic dephasing times have been estimated and interpreted as effects due to solute-solvent interactions. The time-correlation functions of vibrational dephasing were obtained for the ring breathing mode of both "free" and hydrogen-bonded pyridine molecules and it was found that sufficiently deviate from the Kubo model. There is a general agreement in the whole concentration range with the modeling proposed by the Rothschild approach, which applies to complex liquids. The results have shown that the reorientation of pyridine aqueous solutions is very slow and hence in both scattering geometries only vibrational dephasing is probed. It is proposed that the spectral changes depend on the perturbations induced by the dynamics of the water molecules in the first hydration cell and water in bulk, while at extreme dilution conditions, the number of bulk water molecules increases and the interchange between molecules belonging to the first hydration cell may not be the predominant modulation mechanism. The evolution of several parameters, such as the characteristic times, the percentage of Gaussian character in the peak shape and the a parameter are indicative of drastic variations at extreme dilution revealing changes in the vibrational relaxation of the pyridine complexes in the aqueous environment. The higher dilution is correlated to diffusion of water molecules into the reference pyridine system in agreement with the jump diffusion model, while at extreme dilutions, almost all pyridine molecules are

  15. Calculation of the vibrational frequencies of carbon clusters and fullerenes with empirical potentials.

    Science.gov (United States)

    Do, Hainam; Besley, Nicholas A

    2015-02-07

    Vibrational frequencies for carbon clusters, fullerenes and nanotubes evaluated using empirical carbon-carbon potentials are presented. For linear and cyclic clusters, frequencies evaluated with the reactive empirical bond order (REBO) potential provide the closest agreement with experiment. The mean absolute deviation (MAD) between experiment and the calculated harmonic frequencies is 79 cm(-1) for the bending modes and 76 cm(-1) for the stretching modes. The effects of anharmonicity are included via second order vibrational perturbation theory and tend to increase the frequency of the bending modes while the stretching modes have negative shifts in the region of 20-60 cm(-1), with larger shifts for the higher frequency modes. This results in MADs for the bending and stretching modes of 84 cm(-1) and 58 cm(-1), respectively. For the fullerene molecule C60, the high frequency modes are predicted to have harmonic frequencies that are significantly higher than experiment, and this is not corrected by accounting for anharmonicity. This overestimation of experimental observed frequencies is also evident in the calculated frequencies of the G band in nanotubes. This suggests that the REBO potential is not optimal for these larger systems and it is shown that adjustment of the parameters within the potential leads to closer agreement with experiment, particularly if higher and lower frequency modes are considered separately.

  16. A New Ultra-low Frequency Passive Vertical Vibration Isolation System

    Institute of Scientific and Technical Information of China (English)

    赵鹏飞; 黄玉盈; 唐孟希

    2002-01-01

    A new ultra-low frequency passive vertical vibration isolation system is constructed by connecting the torsion spring isolator with a reverse pendulum. The theoretical analysis shows that the new system can achieve a much longer resonant period and have a smaller size than the current torsion spring isolators with the same geometric parameters.

  17. A New Ultra-low Frequency Passive Vertical Vibration Isolation System

    Science.gov (United States)

    Zhao, Peng-Fei; Huang, Yu-Ying; Tang, Meng-Xi

    2002-02-01

    A new ultra-low frequency passive vertical vibration isolation system is constructed by connecting the torsion spring isolator with a reverse pendulum. The theoretical analysis shows that the new system can achieve a much longer resonant period and have a smaller size than the current torsion spring isolators with the same geometric parameters.

  18. Research on a new type of precision cropping method with variable frequency vibration

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    Aiming at the cropping operations widely applied in practical industry production, a new method of bar cropping is presented. The rotational speeds of actuating motor of eccentric blocks are controlled by a frequency-changer, and the shearing die provides the bar with the controllable force, frequency and amplitude of vibration. By utilizing the stress concentration at the bottom of V shape groove on the bar, the low stress bar cropping is realized. The bar cropping experiments of duralumin alloy and steel ...

  19. Eulerian frequency analysis of structural vibrations from high-speed video

    Science.gov (United States)

    Venanzoni, Andrea; De Ryck, Laurent; Cuenca, Jacques

    2016-06-01

    An approach for the analysis of the frequency content of structural vibrations from high-speed video recordings is proposed. The techniques and tools proposed rely on an Eulerian approach, that is, using the time history of pixels independently to analyse structural motion, as opposed to Lagrangian approaches, where the motion of the structure is tracked in time. The starting point is an existing Eulerian motion magnification method, which consists in decomposing the video frames into a set of spatial scales through a so-called Laplacian pyramid [1]. Each scale - or level - can be amplified independently to reconstruct a magnified motion of the observed structure. The approach proposed here provides two analysis tools or pre-amplification steps. The first tool provides a representation of the global frequency content of a video per pyramid level. This may be further enhanced by applying an angular filter in the spatial frequency domain to each frame of the video before the Laplacian pyramid decomposition, which allows for the identification of the frequency content of the structural vibrations in a particular direction of space. This proposed tool complements the existing Eulerian magnification method by amplifying selectively the levels containing relevant motion information with respect to their frequency content. This magnifies the displacement while limiting the noise contribution. The second tool is a holographic representation of the frequency content of a vibrating structure, yielding a map of the predominant frequency components across the structure. In contrast to the global frequency content representation of the video, this tool provides a local analysis of the periodic gray scale intensity changes of the frame in order to identify the vibrating parts of the structure and their main frequencies. Validation cases are provided and the advantages and limits of the approaches are discussed. The first validation case consists of the frequency content

  20. Comparison of different techniques for time-frequency analysis of internal combustion engine vibration signals

    Institute of Scientific and Technical Information of China (English)

    Yang JIN; Zhi-yong HAO; Xu ZHENG

    2011-01-01

    In this study,we report an analysis of cylinder head vibration signals at a steady engine speed using short-time Fourier transform (STFT).Three popular time-frequency analysis techniques,i.e.,STFT,analytic wavelet transform (AWT) and S transform (ST),have been examined.AWT and ST are often applied in engine signal analyses.In particular,an AWT expression in terms of the quality factor Q and an analytical relationship between ST and AWT have been derived.The time-frequency resolution of a Gaussian function windowed STFT was studied via numerical simulation.Based on the simulation,the empirical limits for the lowest distinguishable frequency as well as the time and frequency resolutions were determined.These can provide insights for window width selection,spectrogram interpretation and artifact identification.Gaussian function windowed STFTs were applied to some cylinder head vibration signals.The spectrograms of the same signals from ST and AWT were also determined for comparison.The results indicate that the uniform resolution feature of STFT is not necessarily a disadvantage for time-frequency analysis of vibration signals when the engine is in stationary state because it can more accurately localize the frequency components excited by transient excitations without much loss of time resolution.

  1. Harvesting Ambient Vibration Energy over a Wide Frequency Range for Self-Powered Electronics.

    Science.gov (United States)

    Wang, Xiaofeng; Niu, Simiao; Yi, Fang; Yin, Yajiang; Hao, Chenglong; Dai, Keren; Zhang, Yue; You, Zheng; Wang, Zhong Lin

    2017-02-28

    Vibration is one of the most common energy sources in ambient environment. Harvesting vibration energy is a promising route to sustainably drive small electronics. This work introduces an approach to scavenge vibrational energy over a wide frequency range as an exclusive power source for continuous operation of electronics. An elastic multiunit triboelectric nanogenerator (TENG) is rationally designed to efficiently harvest low-frequency vibration energy, which can provide a maximum instantaneous output power density of 102 W·m(-3) at as low as 7 Hz and maintain its stable current outputs from 5 to 25 Hz. A self-charging power unit (SCPU) combining the TENG and a 10 mF supercapacitor gives a continuous direct current (DC) power delivery of 1.14 mW at a power management efficiency of 45.6% at 20 Hz. The performance of the SCPU can be further enhanced by a specially designed power management circuit, with a continuous DC power of 2 mW and power management efficiency of 60% at 7 Hz. Electronics such as a thermometer, hygrometer, and speedometer can be sustainably powered solely by the harvested vibration energy from a machine or riding bicycle. This approach has potential applications in self-powered systems for environment monitoring, machine safety, and transportation.

  2. Vibrational Spectral Signatures of Crystalline Cellulose Using High Resolution Broadband Sum Frequency Generation Vibrational Spectroscopy (HR-BB-SFG-VS)

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Libing; Lu, Zhou; Velarde Ruiz Esparza, Luis A.; Fu, Li; Pu, Yunqiao; Ding, Shi-You; Ragauskas, Art J.; Wang, Hongfei; Yang, Bin

    2015-03-03

    Here we reported the first sub-wavenumber high-resolution broadband sum frequency generation vibrational spectroscopy (HR-BB-SFG-VS) study on both the C-H and O-H region spectra of crystalline cellulose. HR-BB-SFG-VS has about 10 times better resolution than the conventional scanning SFG-VS and is known to be able to measure the intrinsic spectral lineshape and to resolve much more spectral details. With HR-BB-SFG-VS, we found that in cellulose from different sources, including Avicel and cellulose crystals isolated from algae Valonia (Iα) and tunicates (Iβ), the spectral signatures in the OH regions were unique for different allomorphs, i.e. Iα and Iβ, while the spectral signatures in the C-H regions varied in all samples examined. Even though the origin of the different behaviors of the crystalline cellulose in the O-H and C-H vibrational frequency regions is yet to be correlated to the structure of cellulose, these results provided new spectroscopic methods and opportunities to classify and understand the basic crystalline structure, as well as variations, in polymorphism of the crystalline cellulose structure.

  3. [Pulsed low-frequency electrotherapy of vibration disease associated with osteoarthrosis].

    Science.gov (United States)

    Chudinova, O A; Fedorov, A A; Venediktov, D L; Samokhvalova, G N; Il'ina, M I; Budlianskaia, S V

    2010-01-01

    The study involving 185 patients with vibration disease and concomitant osteoarthrosis has demonstrated the positive influence of pulsed low-frequency currents in combination with hydrogen sulphide baths on the clinical course of the disease. This combined therapy produced good immediate and late post-treatment results. The data obtained suggest high efficiency of differential application of complex-modulated pulsed and fluctuating currents in patients with vibration disease. It is concluded that amplipulse therapy is the method of choice for the management of this pathology in the absence of apparatuses emitting pulsed currents in the running way regime.

  4. Frequency Equations for the In-Plane Vibration of Circular Annular Disks

    OpenAIRE

    S. Bashmal; Bhat, R; S. Rakheja

    2010-01-01

    This paper deals with the in-plane vibration of circular annular disks under combinations of different boundary conditions at the inner and outer edges. The in-plane free vibration of an elastic and isotropic disk is studied on the basis of the two-dimensional linear plane stress theory of elasticity. The exact solution of the in-plane equation of equilibrium of annular disk is attainable, in terms of Bessel functions, for uniform boundary conditions. The frequency equations for different mod...

  5. Non-linear Vibration of Oscillation Systems using Frequency-Amplitude Formulation

    DEFF Research Database (Denmark)

    Fereidoon, A.; Ghadimi, M.; Barari, Amin;

    2012-01-01

    In this paper we study the periodic solutions of free vibration of mechanical systems with third and fifthorder nonlinearity for two examples using He’s Frequency Amplitude Formulation (HFAF).The effectiveness and convenience of the method is illustrated in these examples. It will be shown...... that the solutions obtained with current method have a fabulous conformity with those achieved from time marching solution. HFAF is easy with powerful concepts and the high accuracy, so it can be found widely applicable in vibrations, especially strong nonlinearity oscillatory problems....

  6. Resonant frequency of mass-loaded membranes for vibration energy harvesting applications

    Directory of Open Access Journals (Sweden)

    Lin Dong

    2015-08-01

    Full Text Available Vibration based energy harvesting has been widely investigated to target ambient vibration sources as a means to generate small amounts of electrical energy. While cantilever-based geometries have been pursued frequently in the literature, here membrane-based geometries for the energy harvesting device is considered, with the effects of an added mass and tension on the effective resonant frequency of the membranes studied. An analytical model is developed to describe the vibration response for a circular membrane with added mass structure, with the results closely agreeing with finite element simulation in ANSYS. A complementary study of square membranes loaded with a central mass shows analogous behavior. The analytical model is then used to interpret the experimentally observed shift in resonance frequency of a circular membrane with a proof mass. The impact of membrane tension and central proof mass on the resonant frequency of the membrane suggests that this approach may be used as a tuning method to optimize the response of membrane-based designs for maximum power output for vibration energy harvesting applications.

  7. Modeling structures and vibrational frequencies for dinitrosyl iron complexes (DNICs) with density functional theory.

    Science.gov (United States)

    Brothers, Scott M; Darensbourg, Marcetta Y; Hall, Michael B

    2011-09-05

    The biochemical and physiological importance of nitric oxide (NO) in signaling and vasodilation has been studied for several decades. The discovery of both protein-bound and free low molecular weight dinitrosyl iron complexes (DNICs) suggests that such compounds might play roles in biological NO storage and transport. These complexes have important distinguishing spectroscopic features, including EPR and Mössbauer spectra, and NO vibrational frequencies (ν((NO))). The latter are particularly sensitive to modifications of the ligand environment and metal oxidation states. Examinations of functionals and basis sets delineate their effect on the NO vibrational frequencies and allow development of a methodology to calculate these frequencies in other DNICs. Three complexes of the form (L)(CO)Fe(NO)(2) (L = CO, N,N'-dimethyl-imidazol-2-ylidene (IMe) or 1-methylimidazole (MeImid)), where {Fe(NO)(2)}(10) is in its reduced form, have been used to calibrate the vibrational frequencies. The functional BP86 paired with a basis set of SDD/ECP on the metal and 6-311++G(d,p) on the ligand atoms exhibits the most accurate results, with deviations from experimental vibrational frequencies of no more than ±40 cm(-1). Subsequent investigations were performed on a series of diiron trinitrosyl complexes of the form {Fe(NO)}(7)-{Fe(NO)(2)}(9) bridged by sulfurs, namely, [(ON)Fe(μ-S,S-C(6)H(4))(2)Fe(NO)(2)](-), [Fe(NO)(2){Fe(NS(3))(NO)}-μ-S,S'], and [(ON)Fe(bme-dach)Fe(NO)(2)-μ-S,S'](+), with the ideal functional/basis set pair determined via the aforementioned test set. The ground state energetics (singlet/triplet/singlet, respectively), geometric parameters, and nitrosyl vibrational frequencies were calculated. The results for the former two complexes correlated well with the experimental work, and in contrast with what was reported in an earlier computational study, a stable triplet ground state structure was optimized for [Fe(NO)(2){Fe(NS(3))(NO)}-μ-S,S']. For [(ON

  8. Vibrational frequency scale factors for density functional theory and the polarization consistent basis sets.

    Science.gov (United States)

    Laury, Marie L; Carlson, Matthew J; Wilson, Angela K

    2012-11-15

    Calculated harmonic vibrational frequencies systematically deviate from experimental vibrational frequencies. The observed deviation can be corrected by applying a scale factor. Scale factors for: (i) harmonic vibrational frequencies [categorized into low (1000 cm(-1))], (ii) vibrational contributions to enthalpy and entropy, and (iii) zero-point vibrational energies (ZPVEs) have been determined for widely used density functionals in combination with polarization consistent basis sets (pc-n, n = 0,1,2,3,4). The density functionals include pure functionals (BP86, BPW91, BLYP, HCTH93, PBEPBE), hybrid functionals with Hartree-Fock exchange (B3LYP, B3P86, B3PW91, PBE1PBE, mPW1K, BH&HLYP), hybrid meta functionals with the kinetic energy density gradient (M05, M06, M05-2X, M06-2X), a double hybrid functional with Møller-Plesset correlation (B2GP-PLYP), and a dispersion corrected functional (B97-D). The experimental frequencies for calibration were from 41 organic molecules and the ZPVEs for comparison were from 24 small molecules (diatomics, triatomics). For this family of basis sets, the scale factors for each property are more dependent on the functional selection than on basis set level, and thus allow for a suggested scale factor for each density functional when employing polarization consistent basis sets (pc-n, n = 1,2,3,4). A separate scale factor is recommended when the un-polarized basis set, pc-0, is used in combination with the density functionals.

  9. THE EFFECT OF WHOLE-BODY VIBRATION FREQUENCY AND AMPLITUDE ON THE MYOELECTRIC ACTIVITY OF VASTUS MEDIALIS AND VASTUS LATERALIS

    Directory of Open Access Journals (Sweden)

    Piotr Krol

    2011-03-01

    Full Text Available The aim of this study was to evaluate the efficiency of training protocols for whole body vibration (WBV training through the modulation of the frequency and amplitude of vibration. Despite the large number of studies regarding effects of such training, there is still lack of knowledge regarding optimum training protocols. The study analyzed the influence of whole-body vibration parameters (i.e., the frequency and amplitude on the myoelectric activity of vastus lateralis and vastus medialis in 29 females with the use of electromyography (EMG. The first and second of the eight consecutive trials were performed without vibrations; the remaining six trials were performed in a randomized order on a platform vibrating at different amplitude (2mm and 4mm and frequency (20 Hz, 40 Hz and 60 Hz combinations. The results revealed significantly higher EMG amplitude of both muscles during the vibration as compared with the non- vibrated trials (trial 1 and 2. Furthermore, the EMG activity significantly increased both with the amplitude and frequency, being the highest when the frequency and amplitude of reached 60 Hz and 4 mm, respectively. The study aims to determine the optimal vibration parameters in the aspect of purposeful stimulation of chosen leg muscles. Based on the results of the presented investigation, sports trainers and physiotherapists may be able to optimize training programs involving vibration platforms.

  10. Theory and experiment research for ultra-low frequency maglev vibration sensor

    Energy Technology Data Exchange (ETDEWEB)

    Zheng, Dezhi; Liu, Yixuan, E-mail: xuan61x@163.com; Guo, Zhanshe; Fan, Shangchun [School of Instrument Science and Opto-electronics Engineering, Beihang University, Beijing 100191 (China); Zhao, Xiaomeng [Laser Medicine Laboratory, Institute of Biomedical Engineering, Chinese Academy of medical Sciences and Peking Union Medical College, Tianjin 300192 (China)

    2015-10-15

    A new maglev sensor is proposed to measure ultra-low frequency (ULF) vibration, which uses hybrid-magnet levitation structure with electromagnets and permanent magnets as the supporting component, rather than the conventional spring structure of magnetoelectric vibration sensor. Since the lower measurement limit needs to be reduced, the equivalent bearing stiffness coefficient and the equivalent damping coefficient are adjusted by the sensitivity unit structure of the sensor and the closed-loop control system, which realizes both the closed-loop control and the solving algorithms. A simple sensor experimental platform is then assembled based on a digital hardware system, and experimental results demonstrate that the lower measurement limit of the sensor is increased to 0.2 Hz under these experimental conditions, indicating promising results of the maglev sensor for ULF vibration measurements.

  11. Theory and experiment research for ultra-low frequency maglev vibration sensor.

    Science.gov (United States)

    Zheng, Dezhi; Liu, Yixuan; Guo, Zhanshe; Zhao, Xiaomeng; Fan, Shangchun

    2015-10-01

    A new maglev sensor is proposed to measure ultra-low frequency (ULF) vibration, which uses hybrid-magnet levitation structure with electromagnets and permanent magnets as the supporting component, rather than the conventional spring structure of magnetoelectric vibration sensor. Since the lower measurement limit needs to be reduced, the equivalent bearing stiffness coefficient and the equivalent damping coefficient are adjusted by the sensitivity unit structure of the sensor and the closed-loop control system, which realizes both the closed-loop control and the solving algorithms. A simple sensor experimental platform is then assembled based on a digital hardware system, and experimental results demonstrate that the lower measurement limit of the sensor is increased to 0.2 Hz under these experimental conditions, indicating promising results of the maglev sensor for ULF vibration measurements.

  12. Electric-field effects on the OH vibrational frequency and infrared absorption intensity for water

    Science.gov (United States)

    Hermansson, Kersti

    1993-07-01

    The variations of the anharmonic OH frequency and the infrared absorption intensity with field strength have been calculated for the uncoupled OH stretching vibration of a water molecule in a static, homogeneous electric field using ab initio methods at the MP4 level with a nearly saturated basis set. The OH frequency is found to be virtually independent of the field components perpendicular to the vibrating OH bond. For the parallel component, the frequency vs field curve is close to quadratic, with a maximum for a slightly negative (directed from H to O) field strength. The external field perturbation, defined as Vext(E∥,rOH)=Vtot(E∥, rOH)-Vfree(rOH), is found to be closely linear in rOH, except when the field strength E∥ is both large and negative. The linear external force constant is almost perfectly accounted for by the sum of two terms, -E∥ṡdμ∥free/drOH and -1/2ṡE∥ṡ∂μ∥induced/∂rOH. These derivatives are quite insensitive to the choice of basis-set. The ∂μ∥induced/∂rOH derivative is approximately proportional to E∥, and gives rise to the arclike shape of the frequency vs field curve. The frequency maximum occurs where ∂μ∥tot/∂rOH≊0. It is the sign of dμ∥free/drOH which determines that the frequency maximum occurs at a negative field strength for water (but at a positive field strength for OH-, for example), i.e., that a frequency red-shift (blue-shift for OH-) occurs when the molecule is bound. The linear relationship between the infrared absorption intensity and frequency of the water OH vibration is derived.

  13. Wide operation frequency band magnetostrictive vibration power generator using nonlinear spring constant by permanent magnet

    Science.gov (United States)

    Furumachi, S.; Ueno, T.

    2016-04-01

    We study magnetostrictive vibration based power generator using iron-gallium alloy (Galfenol). The generator is advantages over conventional, such as piezoelectric material in the point of high efficiency highly robust and low electrical impedance. Generally, the generator exhibits maximum power when its resonant frequency matches the frequency of ambient vibration. In other words, the mismatch of these frequencies results in significant decrease of the output. One solution is making the spring characteristics nonlinear using magnetic force, which distorts the resonant peak toward higher or lower frequency side. In this paper, vibrational generator consisting of Galfenol plate of 6 by 0.5 by 13 mm wound with coil and U shape-frame accompanied with plates and pair of permanent magnets was investigated. The experimental results show that lean of resonant peak appears attributed on the non-linear spring characteristics, and half bandwidth with magnets is 1.2 times larger than that without. It was also demonstrated that the addition of proof mass is effective to increase the sensitivity but also the bandwidth. The generator with generating power of sub mW order is useful for power source of wireless heath monitoring for bridge and factory machine.

  14. Effect of High-Frequency Vertical Vibration of Track on Formation and Evolution of Corrugations

    Institute of Scientific and Technical Information of China (English)

    金学松; 温泽峰; 王开云; 张卫华

    2004-01-01

    The effect of high-frequency curved track vibrations in the vertical direction on the formation and development of rail corrugation was analyzed.Kalker's non-Hertzian rolling contact theory was modified and used to calculate the frictional work density on the contact area of the wheel and rail in rolling when a wheelset is steadily curving.The material loss unit area was assumed to be proportional to the frictional work density to determine the wear depth of the contact surface of the rail.The combined influences of the corrugation and the coupled dynamics of the railway vehicle and track were taken into consideration in the numerical simulation.For simplicity, the model considered one fourth of freight car without lateral motion, namely, a wheelset and the equivalent one fourth freight car body above it.The Euler beam was used to model the rails with the track structure under the rails replaced with equivalent springs, dumpers, and mass bodies.The numerical results show that the high-frequency track vibration causes formation of the initial corrugation on the smooth contact surface of the rail when a wheelset is steadily curving.The corrugation wave length depends on the frequencies and the rolling speed of the wheelset.The vibration frequencies also affect the depth and increase the corrugation.

  15. Time frequency characterization of hand-transmitted, impulsive vibrations using analytic wavelet transform

    Science.gov (United States)

    Kim, Jay; Welcome, Daniel E.; Dong, Ren G.; Joon Song, Won; Hayden, Charles

    2007-11-01

    Current guidelines to assess health risk of hand-arm vibration are based on the frequency-weighted rms acceleration level, therefore do not fully consider the effect of temporal variations of the spectral energy. Time averaging effect involved with the frequency analysis may severely underestimate the risk of impact tools. A time-frequency ( T- F) analysis is necessary to characterize a highly transient signal whose spectral characteristics change rapidly in time. The analytic wavelet transform (AWT) is an ideal T- F analysis tool as it possesses the advantages of both the Fourier and wavelet transforms. The AWT is applied to acceleration signals measured from six tools, five impact type tools and one relatively steady-type tool, to explore possible improvements of the current risk assessment method of hand-arm vibration exposure. Based on the unique capability of the AWT, several new concepts including frequency-weighted time history, cumulative injury function, and cumulative injury index are defined in this study. Possible applications of these new concepts to hand-arm vibration research are described. Based on the results from this study, needs for future research are discussed.

  16. Control of fluid flow during Bridgman crystal growth using low-frequency vibrational stirring

    Science.gov (United States)

    Zawilski, Kevin Thomas

    The goal of this research program was to develop an in depth understanding of a promising new method for stirring crystal growth melts called coupled vibrational stirring (CVS). CVS is a mixing technique that can be used in sealed systems and produces rapid mixing through vortex flows. Under normal operating conditions, CVS uses low-frequency vibrations to move the growth crucible along a circular path, producing a surface wave and convection in the melt. This research focused on the application of CVS to the vertical Bridgman technique. CVS generated flows were directly studied using a physical modeling system containing water/glycerin solutions. Sodium nitrate was chosen as a model growth system because the growth process could be directly observed using a transparent furnace. Lead magnesium niobate-lead titanate (PMNT) was chosen as the third system because of its potential application for high performance solid state transducers and actuators. In this study, the critical parameters for controlling CVS flows in cylindrical Bridgman systems were established. One of the most important results obtained was the dependence of an axial velocity gradient on the vibrational frequency. By changing the frequency, the intensity of fluid flow at a given depth can be easily manipulated. The intensity of CVS flows near the crystal-melt interface was found to be important. When flow intensity near the interface increased during growth, large growth rate fluctuations and significant changes in interface shape were observed. To eliminate such fluctuations, a constant flow rate near the crystal-melt interface was maintained by decreasing the vibrational frequency. A continuous frequency ramp was found to be essential to grow crystals of good quality under strong CVS flows. CVS generated flows were also useful in controlling the shape of the growth interface. In the sodium nitrate system without stirring, high growth rates produced a very concave interface. By adjusting the flow

  17. Effect of vehicle weight on natural frequencies of bridges measured from traffic-induced vibration

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    Recently, ambient vibration test (AVT) is widely used to estimate dynamic characteristics of large civil structures. Dynamic characteristics can be affected by various environmental factors such as humidity, intensity of wind, and temperature. Besides these environmental conditions, the mass of vehicles may change the measured values when traffic-induced vibration is used as a source of AVT for bridges. The effect of vehicle mass on dynamic characteristics is investigated through traffic-induced vibration tests on three bridges; (1) three-span suspension bridge (128m+404m+128m), (2) five-span continuous steel box girder bridge (59m+3@95m+59m), (3) simply supported plate girder bridge (46m). Acceleration histories of each measurement location under normal traffic are recorded for 30 minutes at field. These recorded histories are divided into individual vibrations and are combined into two groups according to the level of vibration; one by heavy vehicles such as trucks and buses and the other by light vehicles such as passenger cars. Separate processing of the two groups of signals shows that, for the middle and long-span bridges, the difference can be hardly detected, but, for the short span bridges whose mass is relatively small, the measured natural frequencies can change up to 5.4%.

  18. Time-frequency vibration analysis for the detection of motor damages caused by bearing currents

    Science.gov (United States)

    Prudhom, Aurelien; Antonino-Daviu, Jose; Razik, Hubert; Climente-Alarcon, Vicente

    2017-02-01

    Motor failure due to bearing currents is an issue that has drawn an increasing industrial interest over recent years. Bearing currents usually appear in motors operated by variable frequency drives (VFD); these drives may lead to common voltage modes which cause currents induced in the motor shaft that are discharged through the bearings. The presence of these currents may lead to the motor bearing failure only few months after system startup. Vibration monitoring is one of the most common ways for detecting bearing damages caused by circulating currents; the evaluation of the amplitudes of well-known characteristic components in the vibration Fourier spectrum that are associated with race, ball or cage defects enables to evaluate the bearing condition and, hence, to identify an eventual damage due to bearing currents. However, the inherent constraints of the Fourier transform may complicate the detection of the progressive bearing degradation; for instance, in some cases, other frequency components may mask or be confused with bearing defect-related while, in other cases, the analysis may not be suitable due to the eventual non-stationary nature of the captured vibration signals. Moreover, the fact that this analysis implies to lose the time-dimension limits the amount of information obtained from this technique. This work proposes the use of time-frequency (T-F) transforms to analyse vibration data in motors affected by bearing currents. The experimental results obtained in real machines show that the vibration analysis via T-F tools may provide significant advantages for the detection of bearing current damages; among other, these techniques enable to visualise the progressive degradation of the bearing while providing an effective discrimination versus other components that are not related with the fault. Moreover, their application is valid regardless of the operation regime of the machine. Both factors confirm the robustness and reliability of these tools

  19. Three-dimensional piezoelectric vibration energy harvester using spiral-shaped beam with triple operating frequencies.

    Science.gov (United States)

    Zhao, Nian; Yang, Jin; Yu, Qiangmo; Zhao, Jiangxin; Liu, Jun; Wen, Yumei; Li, Ping

    2016-01-01

    This work has demonstrated a novel piezoelectric energy harvester without a complex structure and appended component that is capable of scavenging vibration energy from arbitrary directions with multiple resonant frequencies. In this harvester, a spiral-shaped elastic thin beam instead of a traditional thin cantilever beam was adopted to absorb external vibration with arbitrary direction in three-dimensional (3D) spaces owing to its ability to bend flexibly and stretch along arbitrary direction. Furthermore, multiple modes in the elastic thin beam contribute to a possibility to widen the working bandwidth with multiple resonant frequencies. The experimental results show that the harvester was capable of scavenging the vibration energy in 3D arbitrary directions; they also exhibited triple power peaks at about 16 Hz, 21 Hz, and 28 Hz with the powers of 330 μW, 313 μW, and 6 μW, respectively. In addition, human walking and water wave energies were successfully converted into electricity, proving that our harvester was practical to scavenge the time-variant or multi-directional vibration energies in our daily life.

  20. Three-dimensional piezoelectric vibration energy harvester using spiral-shaped beam with triple operating frequencies

    Energy Technology Data Exchange (ETDEWEB)

    Zhao, Nian; Yang, Jin, E-mail: yangjin@cqu.edu.cn; Yu, Qiangmo; Zhao, Jiangxin; Liu, Jun; Wen, Yumei; Li, Ping [Department of Optoelectronic Engineering, Chongqing University, Chongqing 400044 (China)

    2016-01-15

    This work has demonstrated a novel piezoelectric energy harvester without a complex structure and appended component that is capable of scavenging vibration energy from arbitrary directions with multiple resonant frequencies. In this harvester, a spiral-shaped elastic thin beam instead of a traditional thin cantilever beam was adopted to absorb external vibration with arbitrary direction in three-dimensional (3D) spaces owing to its ability to bend flexibly and stretch along arbitrary direction. Furthermore, multiple modes in the elastic thin beam contribute to a possibility to widen the working bandwidth with multiple resonant frequencies. The experimental results show that the harvester was capable of scavenging the vibration energy in 3D arbitrary directions; they also exhibited triple power peaks at about 16 Hz, 21 Hz, and 28 Hz with the powers of 330 μW, 313 μW, and 6 μW, respectively. In addition, human walking and water wave energies were successfully converted into electricity, proving that our harvester was practical to scavenge the time-variant or multi-directional vibration energies in our daily life.

  1. Analytical Method for Reduction of Residual Stress Using Low Frequency and Ultrasonic Vibrations

    Science.gov (United States)

    Aoki, Shigeru; Kurita, Katsumi; Koshimizu, Shigeomi; Nishimura, Tadashi; Hiroi, Tetsumaro; Hirai, Seiji

    Welding is widely used for construction of many structures. It is well known that residual stress is generated near the bead because of locally given heat. Tensile residual stress on the surface degrades fatigue strength. On the other hand, welding is used for repair of mold and die. In this case, reduction of residual stress is required because of protection from crack of welded part in mold and die. In this paper, a new method for reduction of residual stress of welded joint is proposed for repair welding of mold and die. In this method, low frequency and ultrasonic vibrations are used during welding. Thick plates are used as specimens of mold and die. Residual stresses are reduced when low frequency and ultrasonic vibrations are used during welding. Experimental results are examined by simulation method using an analytical model. One mass model considering plastic deformation is used as an analytical model. Experimental results are demonstrated by simulation method.

  2. Anharmonic Vibrational Frequency Calculations Are Not Worthwhile for Small Basis Sets.

    Science.gov (United States)

    Jacobsen, Ruth L; Johnson, Russell D; Irikura, Karl K; Kacker, Raghu N

    2013-02-12

    Anharmonic calculations using vibrational perturbation theory are known to provide near-spectroscopic accuracy when combined with high-level ab initio potential energy functions. However, performance with economical, popular electronic structure methods is less well characterized. We compare the accuracy of harmonic and anharmonic predictions from Hartree-Fock, second-order perturbation, and density functional theories combined with 6-31G(d) and 6-31+G(d,p) basis sets. As expected, anharmonic frequencies are closer than harmonic frequencies to experimental fundamentals. However, common practice is to correct harmonic predictions using multiplicative scaling. The surprising conclusion is that scaled anharmonic calculations are no more accurate than scaled harmonic calculations for the basis sets we used. The data used are from the Computational Chemistry Comparison and Benchmark Database (CCCBDB), maintained by the National Institute of Standards and Technology, which includes more than 3939 independent vibrations for 358 molecules.

  3. Low-frequency vibration isolation in sandwich plates by piezoelectric shunting arrays

    Science.gov (United States)

    Chen, Shengbing; Wang, Gang; Song, Yubao

    2016-12-01

    Piezoelectric shunting arrays are proposed to isolate low-frequency vibrations transmitted in sandwich plates. The performance is characterized through application of finite element method. The numerical result shows that a complete band gap, whose width is about 20 Hz, is produced in the desired low-frequency ranges. The band gap is induced by local resonances of the shunting circuits, whose location is strongly related to the inductance, while the resistance can broaden the band gap to some extent. Vibration experiments are conducted on a 1200 × 1000 × 15 mm aluminum honeycomb plate with two arrays of 5 × 5 shunted piezoelectric patches bonded on the surface panels. Significant attenuation is found in the experimental results, which agree well with the theoretical predictions. Consequently, the proposed idea is feasible and effective.

  4. Vibrational frequency of a strong-coupling polaron in a quantum rod at finite temperatures

    Institute of Scientific and Technical Information of China (English)

    Ding Zhao-Hua; Xiao Jing-Lin

    2011-01-01

    The Hamiltonian of a quantum rod with a boundary is presented after a coordinate transformation that changes the original ellipsoidal boundary into a spherical one. We then study the effect of temperature on the vibrational frequency and the ground state binding energy of the strong-coupling polaron in the rod. The two quantities are expressed as functions of the aspect ratio of the ellipsoid,the transverse and the longitudinal effective confinement lengths,the temperature and the electron-phonon coupling strength by linear combination operator and unitary transformation methods. It is found that the vibrational frequency and the ground state binding energy will increase rapidly with decreasing transverse and longitudinal effective confinement lengths. They are increasing functions of the electronphonon coupling strength but become decreasing ones of the temperature and the aspect ratio.

  5. Novel Euler-LaCoste linkage as a very low frequency vertical vibration isolator.

    Science.gov (United States)

    Hosain, M A; Sirr, A; Ju, L; Blair, D G

    2012-08-01

    LaCoste linkage vibration isolators have shown excellent performance for ultra-low frequency vertical vibration isolation. However, such isolators depend on the use of conventional pre-stressed coil springs, which suffer from creep. Here, we show that compressional Euler springs can be configured to create a stable tension unit for use in a LaCoste structure. In a proof of concept experiment, we demonstrate a vertical resonance frequency of 0.15 Hz in an Euler-LaCoste configuration with 200 mm height. The system enables the use of very low creep maraging steel as spring elements to eliminate the creep while minimising spring mass and reducing the effect of parasitic resonances. Larger scale systems with optimized Euler spring boundary conditions should achieve performance suitable for applications on third generation gravitational wave detectors such as the proposed Einstein telescope.

  6. Frequency Equations for the In-Plane Vibration of Circular Annular Disks

    Directory of Open Access Journals (Sweden)

    S. Bashmal

    2010-01-01

    Full Text Available This paper deals with the in-plane vibration of circular annular disks under combinations of different boundary conditions at the inner and outer edges. The in-plane free vibration of an elastic and isotropic disk is studied on the basis of the two-dimensional linear plane stress theory of elasticity. The exact solution of the in-plane equation of equilibrium of annular disk is attainable, in terms of Bessel functions, for uniform boundary conditions. The frequency equations for different modes can be obtained from the general solutions by applying the appropriate boundary conditions at the inner and outer edges. The presented frequency equations provide the frequency parameters for the required number of modes for a wide range of radius ratios and Poisson's ratios of annular disks under clamped, free, or flexible boundary conditions. Simplified forms of frequency equations are presented for solid disks and axisymmetric modes of annular disks. Frequency parameters are computed and compared with those available in literature. The frequency equations can be used as a reference to assess the accuracy of approximate methods.

  7. Vapor-solvent shift of the lowest frequency vibration of p-benzoquinone and toluquinone and the consequences for the vibrational and electronic spectral assignments

    NARCIS (Netherlands)

    Trommsdorff, H.P.; Zelsmann, H.R.

    1985-01-01

    Far-infrared (20–230 cm–1) absorption spectra of p-benzoquinone-h4,-d4 and of toluquinone have been measured. In the vapor phase, the lowest frequency vibration of these three compounds is found at 88.9, 87.5, and 82.3 cm–1, respectively. In the condensed phase the frequency increases by approximate

  8. Effects of vibration frequency on vibration-assisted nano-scratch process of mono-crystalline copper via molecular dynamics simulation

    Science.gov (United States)

    Zhu, Bo; Zhao, Hongwei; Zhao, Dan; Zhang, Peng; Yang, Yihan; Han, Lei; Kui, Hailin

    2016-03-01

    It has always been a critical issue to understand the material removal behavior of Vibration-Assisted Machining (VAM), especially on atomic level. To find out the effects of vibration frequency on material removal response, a three-dimensional molecular dynamics (MD) model has been established in this research to investigate the effects of scratched groove, crystal defects on the surface quality, comparing with the Von Mises shear strain and tangential force in simulations during nano-scratching process. Comparisons are made among the results of simulations from different vibration frequency with the same scratching feed, depth, amplitude and crystal orientation. Copper potential in this simulation is Embedded-Atom Method (EAM) potential. Interaction between copper and carbon atoms is Morse potential. Simulational results show that higher frequency can make groove smoother. Simulation with high frequency creates more dislocations to improve the machinability of copper specimen. The changing frequency does not have evident effects on Von Mises shear strain. Higher frequency can decrease the tangential force to reduce the consumption of cutting energy and tool wear. In conclusion, higher vibration frequency in VAM on mono-crystalline copper has positive effects on surface finish, machinablility and tool wear reduction.

  9. Effects of vibration frequency on vibration-assisted nano-scratch process of mono-crystalline copper via molecular dynamics simulation

    Directory of Open Access Journals (Sweden)

    Bo Zhu

    2016-03-01

    Full Text Available It has always been a critical issue to understand the material removal behavior of Vibration-Assisted Machining (VAM, especially on atomic level. To find out the effects of vibration frequency on material removal response, a three-dimensional molecular dynamics (MD model has been established in this research to investigate the effects of scratched groove, crystal defects on the surface quality, comparing with the Von Mises shear strain and tangential force in simulations during nano-scratching process. Comparisons are made among the results of simulations from different vibration frequency with the same scratching feed, depth, amplitude and crystal orientation. Copper potential in this simulation is Embedded-Atom Method (EAM potential. Interaction between copper and carbon atoms is Morse potential. Simulational results show that higher frequency can make groove smoother. Simulation with high frequency creates more dislocations to improve the machinability of copper specimen. The changing frequency does not have evident effects on Von Mises shear strain. Higher frequency can decrease the tangential force to reduce the consumption of cutting energy and tool wear. In conclusion, higher vibration frequency in VAM on mono-crystalline copper has positive effects on surface finish, machinablility and tool wear reduction.

  10. Whole Body Vibration at Different Exposure Frequencies: Infrared Thermography and Physiological Effects

    Directory of Open Access Journals (Sweden)

    Anelise Sonza

    2015-01-01

    Full Text Available The aim of this study was to investigate the effects of whole body vibration (WBV on physiological parameters, cutaneous temperature, tactile sensitivity, and balance. Twenty-four healthy adults (25.3±2.6 years participated in four WBV sessions. They spent 15 minutes on a vibration platform in the vertical mode at four different frequencies (31, 35, 40, and 44 Hz with 1 mm of amplitude. All variables were measured before and after WBV exposure. Pressure sensation in five anatomical regions and both feet was determined using Von Frey monofilaments. Postural sway was measured using a force plate. Cutaneous temperature was obtained with an infrared camera. WBV influences the discharge of the skin touch-pressure receptors, decreasing sensitivity at all measured frequencies and foot regions (P≤0.05. Regarding balance, no differences were found after 20 minutes of WBV at frequencies of 31 and 35 Hz. At 40 and 44 Hz, participants showed higher anterior-posterior center of pressure (COP velocity and length. The cutaneous temperature of the lower limbs decreased during and 10 minutes after WBV. WBV decreases touch-pressure sensitivity at all measured frequencies 10 min after exposure. This may be related to the impaired balance at higher frequencies since these variables have a role in maintaining postural stability. Vasoconstriction might explain the decreased lower limb temperature.

  11. Vibration Frequencies Extraction of the Forth Road Bridge Using High Sampling GPS Data

    Directory of Open Access Journals (Sweden)

    Jian Wang

    2016-01-01

    Full Text Available This paper proposes a scheme for vibration frequencies extraction of the Forth Road Bridge in Scotland from high sampling GPS data. The interaction between the dynamic response and the ambient loadings is carefully analysed. A bilinear Chebyshev high-pass filter is designed to isolate the quasistatic movements, the FFT algorithm and peak-picking approach are applied to extract the vibration frequencies, and a GPS data accumulation counter is suggested for real-time monitoring applications. To understand the change in the structural characteristics under different loadings, the deformation results from three different loading conditions are presented, that is, the ambient circulation loading, the strong wind under abrupt wind speed change, and the specific trial with two 40 t lorries passing the bridge. The results show that GPS not only can capture absolute 3D deflections reliably, but also can be used to extract the frequency response accurately. It is evident that the frequencies detected using the filtered deflection time series in different direction show quite different characteristics, and more stable results can be obtained from the height displacement time series. The frequency responses of 0.105 and 0.269 Hz extracted from the lateral displacement time series correlate well with the data using height displacement time series.

  12. Whole body vibration at different exposure frequencies: infrared thermography and physiological effects.

    Science.gov (United States)

    Sonza, Anelise; Robinson, Caroline C; Achaval, Matilde; Zaro, Milton A

    2015-01-01

    The aim of this study was to investigate the effects of whole body vibration (WBV) on physiological parameters, cutaneous temperature, tactile sensitivity, and balance. Twenty-four healthy adults (25.3 ± 2.6 years) participated in four WBV sessions. They spent 15 minutes on a vibration platform in the vertical mode at four different frequencies (31, 35, 40, and 44 Hz) with 1 mm of amplitude. All variables were measured before and after WBV exposure. Pressure sensation in five anatomical regions and both feet was determined using Von Frey monofilaments. Postural sway was measured using a force plate. Cutaneous temperature was obtained with an infrared camera. WBV influences the discharge of the skin touch-pressure receptors, decreasing sensitivity at all measured frequencies and foot regions (P ≤ 0.05). Regarding balance, no differences were found after 20 minutes of WBV at frequencies of 31 and 35 Hz. At 40 and 44 Hz, participants showed higher anterior-posterior center of pressure (COP) velocity and length. The cutaneous temperature of the lower limbs decreased during and 10 minutes after WBV. WBV decreases touch-pressure sensitivity at all measured frequencies 10 min after exposure. This may be related to the impaired balance at higher frequencies since these variables have a role in maintaining postural stability. Vasoconstriction might explain the decreased lower limb temperature.

  13. Vibration Sensor Data Denoising Using a Time-Frequency Manifold for Machinery Fault Diagnosis

    Directory of Open Access Journals (Sweden)

    Qingbo He

    2013-12-01

    Full Text Available Vibration sensor data from a mechanical system are often associated with important measurement information useful for machinery fault diagnosis. However, in practice the existence of background noise makes it difficult to identify the fault signature from the sensing data. This paper introduces the time-frequency manifold (TFM concept into sensor data denoising and proposes a novel denoising method for reliable machinery fault diagnosis. The TFM signature reflects the intrinsic time-frequency structure of a non-stationary signal. The proposed method intends to realize data denoising by synthesizing the TFM using time-frequency synthesis and phase space reconstruction (PSR synthesis. Due to the merits of the TFM in noise suppression and resolution enhancement, the denoised signal would have satisfactory denoising effects, as well as inherent time-frequency structure keeping. Moreover, this paper presents a clustering-based statistical parameter to evaluate the proposed method, and also presents a new diagnostic approach, called frequency probability time series (FPTS spectral analysis, to show its effectiveness in fault diagnosis. The proposed TFM-based data denoising method has been employed to deal with a set of vibration sensor data from defective bearings, and the results verify that for machinery fault diagnosis the method is superior to two traditional denoising methods.

  14. Vibration sensor data denoising using a time-frequency manifold for machinery fault diagnosis.

    Science.gov (United States)

    He, Qingbo; Wang, Xiangxiang; Zhou, Qiang

    2013-12-27

    Vibration sensor data from a mechanical system are often associated with important measurement information useful for machinery fault diagnosis. However, in practice the existence of background noise makes it difficult to identify the fault signature from the sensing data. This paper introduces the time-frequency manifold (TFM) concept into sensor data denoising and proposes a novel denoising method for reliable machinery fault diagnosis. The TFM signature reflects the intrinsic time-frequency structure of a non-stationary signal. The proposed method intends to realize data denoising by synthesizing the TFM using time-frequency synthesis and phase space reconstruction (PSR) synthesis. Due to the merits of the TFM in noise suppression and resolution enhancement, the denoised signal would have satisfactory denoising effects, as well as inherent time-frequency structure keeping. Moreover, this paper presents a clustering-based statistical parameter to evaluate the proposed method, and also presents a new diagnostic approach, called frequency probability time series (FPTS) spectral analysis, to show its effectiveness in fault diagnosis. The proposed TFM-based data denoising method has been employed to deal with a set of vibration sensor data from defective bearings, and the results verify that for machinery fault diagnosis the method is superior to two traditional denoising methods.

  15. Effect of vibration frequency on microstructure and performance of high chromium cast iron prepared by lost foam casting

    Directory of Open Access Journals (Sweden)

    Wen-qi Zou

    2016-07-01

    Full Text Available In the present research, high chromium cast irons (HCCIs were prepared using the lost foam casting (LFC process. To improve the wear resistance of the high chromium cast irons (HCCIs, mechanical vibration was employed during the solidification of the HCCIs. The effects of vibration frequency on the microstructure and performance of the HCCIs under as-cast, as-quenched and as-tempered conditions were investigated. The results indicated that the microstructures of the LFC-produced HCCIs were refined due to the introduction of mechanical vibration, and the hardness was improved compared to that of the alloy without vibration. However, only a slight improvement in hardness was found in spite of the increase of vibration frequency. In contrast, the impact toughness of the as-tempered HCCIs increased with an increase in the vibration frequency. In addition, the wear resistance of the HCCIs was improved as a result of the introduction of vibration and increased with an increase in the vibration frequency.

  16. Dual-wavelength speckle-based SI-POF sensor for frequency detection and localization of remote vibrations

    Science.gov (United States)

    Pinzón, P. J.; Montero, D. S.; Tapetado, A.; Torres, J. C.; Vázquez, C.

    2016-05-01

    A novel speckle-based method for sensing frequency vibration is demonstrated in a reflective configuration. By employing a visible dual-wavelength approach it is also possible to determine the relative spatial location of the vibrations along a plastic optical fiber lead of 8 m in a distributed scheme.

  17. Effect of vibration frequency on microstructure and performance of high chromium cast iron prepared by lost foam casting

    Institute of Scientific and Technical Information of China (English)

    Wen-qi Zou; Zhi-guo Zhang; Hao Yang; Wei Li

    2016-01-01

    In the present research, high chromium cast irons (HCCIs) were prepared using the lost foam casting (LFC) process. To improve the wear resistance of the high chromium cast irons (HCCIs), mechanical vibration was employed during the solidiifcation of the HCCIs. The effects of vibration frequency on the microstructure and performance of the HCCIs under as-cast, as-quenched and as-tempered conditions were investigated. The results indicated that the microstructures of the LFC-produced HCCIs were reifned due to the introduction of mechanical vibration, and the hardness was improved compared to that of the aloy without vibration. However, only a slight improvement in hardness was found in spite of the increase of vibration frequency. In contrast, the impact toughness of the as-tempered HCCIs increased with an increase in the vibration frequency. In addition, the wear resistance of the HCCIs was improved as a result of the introduction of vibration and increased with an increase in the vibration frequency.

  18. Electrostatic MEMS vibration energy harvester for HVAC applications with impact-based frequency up-conversion

    Science.gov (United States)

    Oxaal, J.; Hella, M.; Borca-Tasciuc, D.-A.

    2016-12-01

    This paper reports on electrostatic MEMS vibration energy harvesters with gap-closing interdigitated electrodes, designed for and tested on HVAC air ducts. The harvesters were fabricated on SOI wafers with 200 µm device layer using a custom microfabrication process. Designs with aspects ratio (electrodes’ gap versus depth) of 10 and 20 were implemented, while the overall footprint was approximately 1 cm  ×  1 cm in both cases. In order to enhance the power output, a dual-level physical stopper system was designed to control the minimum gap between the electrodes, which is a key parameter in the conversion process. The dual-level stopper utilizes cantilever beams to absorb a portion of the impact energy as the electrodes approach the impact point, and a film of parylene with nanometer thickness deposited on the electrode sidewalls. The parylene layer defines the absolute minimum gap and provides electrical insulation. The fabricated devices were first tested on a vibration shaker to characterize the resonant behavior. Devices with aspect ratio 10 were found to exhibit frequency up-conversion, which enhances the amount of converted power. Devices with both aspect ratios were found to exhibits spring hardening due to impact with the stoppers and spring softening behavior at increasing voltage bias. The highest power measured on shaker table for sinusoidal vibrations was 3.13 µW (includes enhancement due to frequency up-conversion driven by impact) for aspect ratio 10, and 0.166 µW for aspect ratio 20. The corresponding dimensional figure-of-merit, defined as the power output normalized to vibration acceleration and frequency, squared voltage and device mass, was in the range of 10 · 10-8 m V-2 for both devices, about an order of magnitude higher than state-of-the-art. Testing was carried out on HVAC air duct vibrating with an RMS acceleration of 155 mg RMS, a primary frequency of 60 Hz and a PSD of 7.15 · 10-2 g2 Hz-1. The peak power measured was

  19. The vibrating reed frequency meter: digital investigation of an early cochlear model

    Directory of Open Access Journals (Sweden)

    Andrew Bell

    2015-10-01

    Full Text Available The vibrating reed frequency meter, originally employed by Békésy and later by Wilson as a cochlear model, uses a set of tuned reeds to represent the cochlea’s graded bank of resonant elements and an elastic band threaded between them to provide nearest-neighbour coupling. Here the system, constructed of 21 reeds progressively tuned from 45 to 55 Hz, is simulated numerically as an elastically coupled bank of passive harmonic oscillators driven simultaneously by an external sinusoidal force. To uncover more detail, simulations were extended to 201 oscillators covering the range 1–2 kHz. Calculations mirror the results reported by Wilson and show expected characteristics such as traveling waves, phase plateaus, and a response with a broad peak at a forcing frequency just above the natural frequency. The system also displays additional fine-grain features that resemble those which have only recently been recognised in the cochlea. Thus, detailed analysis brings to light a secondary peak beyond the main peak, a set of closely spaced low-amplitude ripples, rapid rotation of phase as the driving frequency is swept, frequency plateaus, clustering, and waxing and waning of impulse responses. Further investigation shows that each reed’s vibrations are strongly localised, with small energy flow along the chain. The distinctive set of equally spaced ripples is an inherent feature which is found to be largely independent of boundary conditions. Although the vibrating reed model is functionally different to the standard transmission line, its cochlea-like properties make it an intriguing local oscillator model whose relevance to cochlear mechanics needs further investigation.

  20. Vibration Powered RF-Transponder for Sensing Low Frequency Motion Events

    Science.gov (United States)

    Gupta, S. K.; Pinrod, V.; Nadig, S.; Davaji, B.; Lal, A.

    2016-11-01

    Vibration energy harvesting offers a pathway to developing battery-less sensing solutions to be deployed in wireless sensor network nodes. The integration of the energy harvesters require regulation by power conditioning and control circuitry that consume some of the energy generated, reducing the effective energy available for node function. By designing a unique 3D-printed plastic structure for low frequency sensitivity and mechanical switching, and a lateral PZT bimorph for capturing energy from environmental vibrations, we report a zero-power consumption RF-transponder capable of detecting and reporting motion events without a battery. We have successfully picked up wireless transmissions on an external receiver placed ∼25cm away from the transponder, shaken at 0.75 g and 20 Hz. We have additionally demonstrated the ability to harvest energy from 5 Hz vibrations up to just under 150 Hz. When placed on an oil-based electric generator, which vibrates when operating, the RF-transponder has successfully picked up the differing harmonics to identify the mode of operation as the economy or regular power setting.

  1. a Hamiltonian to Obtain a Global Frequency Analysis of all the Vibrational Bands of Ethane

    Science.gov (United States)

    Moazzen-Ahmadi, Nasser; Norooz Oliaee, Jalal

    2016-06-01

    The interest in laboratory spectroscopy of ethane stems from the desire to understand the methane cycle in the atmospheres of planets and their moons and from the importance of ethane as a trace species in the terrestrial atmosphere. Solar decomposition of methane in the upper part of these atmospheres followed by a series of reactions leads to a variety of hydrocarbon compounds among which ethane is often the second most abundant species. Because of its high abundance, ethane spectra have been measured by Voyager and Cassini in the regions around 30, 12, 7, and 3 μm. Therefore, a complete knowledge of line parameters of ethane is crucial for spectroscopic remote sensing of planetary atmospheres. Experimental characterization of torsion-vibration states of ethane lying below 1400 cm-1 have been made previously, but extension of the Hamiltonian model for treatment of the strongly perturbed νb{8} fundamental and the complex band system of ethane in the 3 micron region requires careful examination of the operators for many new torsionally mediated vibration-rotation interactions. Following the procedures outlined by Hougen, we have re-examined the transformation properties of the total angular momentum, the translational and vibrational coordinates and momenta of ethane, and for vibration-torsion-rotation interaction terms constructed by taking products of these basic operators. It is found that for certain choices of phase, the doubly degenerate vibrational coordinates with and symmetry can be made to transform under the group elements in such a way as to yield real matrix elements for the torsion-vibration-rotation couplings whereas other choices of phase may require complex algebra. In this talk, I will discuss the construction of a very general torsion-vibration-rotation Hamiltonian for ethane, as well as the prospect for using such a Hamiltonian to obtain a global frequency analysis (based in large part on an extension of earlier programs and ethane fits^a from

  2. On the efficacy of the wavelet decomposition for high frequency vibration analyses

    Science.gov (United States)

    Zhang, S.; Cheng, L.

    2016-10-01

    This paper reports the extraordinary ability of the wavelet decomposition for vibration analyses under the framework of Rayleigh-Ritz method. Using a beam as an example, Daubechies wavelet scale functions are used as admissible functions for decomposing the flexural displacement of the structure, along with the artificial springs at the boundary, to predict vibration of an Euler-Bernoulli beam in an extremely large frequency range. It is shown that the use of wavelet basis allows reaching very high frequencies, typically covering more than 1000 modes using conventional computational facility within the available numerical dynamics of the computers with no particular care needed for round-off errors. As a side benefit, the use of spring boundary also allows handling any elastic boundary conditions through a dynamic contribution in the Hamiltonian of the beam. The wavelet decomposed approach combines the flexibility of the global methods and the accuracy of local methods by inheriting the versatility of the Rayleigh-Ritz approach and the superior fitting ability of the wavelets. Numerical results on both free and forced vibrations are given, in excellent agreement with predictions of classical methods.

  3. Design of piezoelectric MEMS cantilever for low-frequency vibration energy harvester

    Science.gov (United States)

    Takei, Ryohei; Makimoto, Natsumi; Okada, Hironao; Itoh, Toshihiro; Kobayashi, Takeshi

    2016-06-01

    We report the design of piezoelectric MEMS cantilevers formed on a silicon-on-insulator wafer to efficiently harvest electrical power from harmonic vibration with a frequency of approximately 30 Hz. Numerical simulation indicates that a >4-µm-thick top silicon layer and >3-µm-thick piezoelectric film are preferable to maximize the output electrical power. An in-plane structure of the cantilever is also designed retaining the footprint of the cantilever. The simulation results indicate that the output power is maximized when the length ratio of the proof mass to the cantilever beam is 1.5. To ensure the accuracy of the simulation, we fabricated and characterized cantilevers with a 10-µm-thick top silicon layer and a 1.8-µm-thick piezoelectric film, resulting in 0.21 µW at a vibration of 0.5 m/s2 and 25.1 Hz. The measured output power is in agreement with the simulated value, meaning that the design is significantly reliable for low-frequency vibration energy harvesters.

  4. The effect of lubricant supply and frequency upon the behaviour of EHD films subjected to vibrations

    Science.gov (United States)

    Glovnea, R.; Zhang, X.; Sugimura, J.

    2017-02-01

    Machine elements such as rolling element bearings or gears often experience vibrations due to for example geometrical inaccuracies, shock loading, rotating unbalanced masses, and others. These machine elements rely on a very thin lubricant film to protect the metallic surfaces from direct contact and eventual damage. During rapid variation of load the elastohydrodynamic contact is influenced by the so-called squeeze film effect, however, when both entrainment and squeeze are present, the conditions of film formation are more complex. It is expected that the lubricant film thickness is influenced by the amplitude and frequency of the vibrations. At the same time, as it is known that the film thickness is established in the inlet of the contact, it is equally important to evaluate what is the role played by the supply of lubricant to the contact under oscillatory conditions. To date there are not many studies on the effect of the oscillatory motion parameters upon the behaviour of the lubricant film. In this study the focus is on the effect of the frequency of vibrations and the supply of lubricant upon the film thickness.

  5. Composite 3D-printed metastructures for low-frequency and broadband vibration absorption

    Science.gov (United States)

    Matlack, Kathryn H.; Bauhofer, Anton; Krödel, Sebastian; Palermo, Antonio; Daraio, Chiara

    2016-07-01

    Architected materials that control elastic wave propagation are essential in vibration mitigation and sound attenuation. Phononic crystals and acoustic metamaterials use band-gap engineering to forbid certain frequencies from propagating through a material. However, existing solutions are limited in the low-frequency regimes and in their bandwidth of operation because they require impractical sizes and masses. Here, we present a class of materials (labeled elastic metastructures) that supports the formation of wide and low-frequency band gaps, while simultaneously reducing their global mass. To achieve these properties, the metastructures combine local resonances with structural modes of a periodic architected lattice. Whereas the band gaps in these metastructures are induced by Bragg scattering mechanisms, their key feature is that the band-gap size and frequency range can be controlled and broadened through local resonances, which are linked to changes in the lattice geometry. We demonstrate these principles experimentally, using advanced additive manufacturing methods, and inform our designs using finite-element simulations. This design strategy has a broad range of applications, including control of structural vibrations, noise, and shock mitigation.

  6. Diffusion regime for high-frequency vibrations of randomly heterogeneous structures.

    Science.gov (United States)

    Savin, Eric

    2008-12-01

    The evolution of the high-frequency vibrational energy density of slender heterogeneous structures such as Timoshenko beams or thick shells is depicted by transport equations or radiative transfer equations (RTEs) in the presence of random heterogeneities. A diffusive regime arises when their correlation lengths are comparable to the wavelength, among other possible situations, and waves are multiply scattered. The purpose of this paper is to expound how diffusion approximations of the RTEs for elastic structures can be derived and to discuss the relevance of the vibrational conductivity analogy invoked in the structural acoustics literature. Its main contribution is the consideration of a heterogeneous background medium with varying parameters and the effects of polarization of elastic waves. The paper also outlines some of the remarkable features of the diffusive regime: depolarization of waves, energy equipartition, and asymptotic Fick's law.

  7. Fuzzy control on automatic frequency tracking of ultrasonic vibration system with high power and high quality factor Q

    Institute of Scientific and Technical Information of China (English)

    ZHU Wu; ZHANG Jia-min; LIU Hong-li; MENG Feng-feng; ZHANG Zhi-ming

    2009-01-01

    In order to realize automatic tracking drift of resonance frequency of ultrasonic vibration system with high power and high quality factor Q, adaptive fuzzy control was studied with a self-fabricated ultrasonic plastic welding machine. At first, relations between amplitude of vibration and frequency as well as main loop current and amplitude of vibration were analyzed. From this analysis, we deduced that frequency tracking process of the vibration system can be concluded as an optimizing problem of one dimensional fluctuant extremum of main loop current in vibration system. Then a method of self-optimizing fuzzy control, used for the realization of automatic frequency tracking in vibration system, is presented on the basis of self-optimizing adaptive control approach and fuzzy control approach. The result of experiments shows that the fuzzy self-optimizing method can solve the problem of tracking frequency drift very well. Response time of tracking in the system is less than 50 ms, which basically meets the requirements of frequency tracking in ultrasonic plastic welding machine.

  8. Bi-resonant structure with piezoelectric PVDF films for energy harvesting from random vibration sources at low frequency

    DEFF Research Database (Denmark)

    Liang, Shanshan; Crovetto, Andrea; Peng, Zhuoteng

    2016-01-01

    This paper reports on a bi-resonant structure of piezoelectric PVDF films energy harvester (PPEH), which consists of two cantilevers with resonant frequencies of 15 Hz and 22 Hz. With increased acceleration, the vibration amplitudes of the two cantilever-mass structures are increased and collision...... and experiments with piezoelectric elements show that the energy harvesting device with the bi-resonant structure can generate higher power output than that of the sum of the two separate devices from random vibration sources at low frequency, and hence significantly improves the vibration-to- electricity...

  9. Research on a new type of precision cropping method with variable frequency vibration

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    Aiming at the cropping operations widely applied in practical industry production, a new method of bar cropping is presented. The rotational speeds of actuating motor of eccentric blocks are controlled by a frequency-changer, and the shearing die provides the bar with the controllable force, frequency and amplitude of vibration. By utilizing the stress concentration at the bottom of V shape groove on the bar, the low stress bar cropping is realized. The bar cropping experiments of duralumin alloy and steel show that the shear surface has no radial distortion and deviation angle, the cutting force is lower and the die life is longer compared with the common bar cropping method. According to the special feature of cutting surface obtained by the new method, a new method of measurement is proposed and applied to assess the cutting surfaces obtained by the different control curves of frequency. The results show that the linear decrease control method is the best.

  10. Modal identification using the frequency-scale domain decomposition technique of ambient vibration responses

    Science.gov (United States)

    Le, Thien-Phu; Argoul, Pierre

    2016-12-01

    This paper proposes a new modal identification method of ambient vibration responses. The application of the singular value decomposition to continuous wavelet transform of power spectral density matrix gives singular values and singular vectors in frequency-scale domain. Analytical development shows a direct relation between local maxima in frequency-scale representation of singular values and modal parameters. This relation is then carried on for the identification of modal parameters via a complete practical procedure. The main novelties of this work involve the new formulation in frequency-scale domain and the capacity for the identification of modal parameters without the step of ridges extraction in comparison with previous wavelet-based modal identification methods.

  11. A vibration isolation system in low frequency excitation region using negative stiffness structure for vehicle seat

    Science.gov (United States)

    Le, Thanh Danh; Ahn, Kyoung Kwan

    2011-12-01

    This paper designs and fabricates a vibration isolation model for improving vibration isolation effectiveness of the vehicle seat under low excitation frequencies. The feature of the proposed system is to use two symmetric negative stiffness structures (NSS) in parallel to a positive stiffness structure. Here, theoretical analysis of the proposed system is clearly presented. Then, the design procedure is derived so that the resonance peak of frequency-response curve drifts to the left, the load support capacity of the system is maintained, the total size of the system is reduced for easy practical application and especially, the bending of the frequency-response curve is minimized. Next the dynamic equation of the proposed system is set up. Then, the harmonic balance (HB) method is employed to seek the characteristic of the motion transmissibility of the proposed system at the steady state for each of the excitation frequency. From this characteristic, the curves of the motion transmission are predicted according to the various values of the configurative parameters of the system. Then, the time responses to the sinusoidal, multi frequency and random excitations are also investigated by simulation and experiment. In addition, the isolation performance comparison between the system with NSS and system without NSS is realized. The simulation results reveal that the proposed system has larger frequency region of isolation than that of the system without NSS. The experimental results confirm also that with a random excitation mainly spreading from 0.1 to 10 Hz, the isolation performance of the system with NSS is greatly improved, where the RMS values of the mass displacement may be reduced to 67.2%, whereas the isolation performance of the system without NSS is bad. Besides, the stability of the steady-state response is also studied. Finally, some conclusions are given.

  12. Analytical Expressions for Frequency and Buckling of Large Amplitude Vibration of Multilayered Composite Beams

    Directory of Open Access Journals (Sweden)

    R. A. Jafari-Talookolaei

    2011-01-01

    Full Text Available The aim of this paper is to present analytical and exact expressions for the frequency and buckling of large amplitude vibration of the symmetrical laminated composite beam (LCB with simple and clamped end conditions. The equations of motion are derived by using Hamilton's principle. The influences of axial force, Poisson effect, shear deformation, and rotary inertia are taken into account in the formulation. First, the geometric nonlinearity based on the von Karman's assumptions is incorporated in the formulation while retaining the linear behavior for the material. Then, the displacement fields used for the analysis are coupled using the equilibrium equations of the composite beam. Substituting this coupled displacement fields in the potential and kinetic energies and using harmonic balance method, we obtain the ordinary differential equation in time domain. Finally, applying first order of homotopy analysis method (HAM, we get the closed form solutions for the natural frequency and deflection of the LCB. A detailed numerical study is carried out to highlight the influences of amplitude of vibration, shear deformation and rotary inertia, slenderness ratios, and layup in the case of laminates on the natural frequency and buckling load.

  13. PARALLEL FINITE ELEMENT ANALYSIS OF HIGH FREQUENCY VIBRATIONS OF QUARTZ CRYSTAL RESONATORS ON LINUX CLUSTER

    Institute of Scientific and Technical Information of China (English)

    Ji Wang; Yu Wang; Wenke Hu; Wenhua Zhao; Jianke Du; Dejin Huang

    2008-01-01

    Quartz crystal resonators are typical piezoelectric acoustic wave devices for frequency control applications with mechanical vibration frequency at the radio-frequency (RF) range. Precise analyses of the vibration and deformation are generally required in the resonator design and improvement process. The considerations include the presence of electrodes, mountings, bias fields such as temperature, initial stresses, and acceleration. Naturally, the finite element method is the only effective tool for such a coupled problem with multi-physics nature. The main challenge is the extremely large size of resulted linear equations. For this reason, we have been employing the Mindlin plate equations to reduce the computational difficulty. In addition, we have to utilize the parallel computing techniques on Linux clusters, which are widely available for academic and industrial applications nowadays, to improve the computing efficiency. The general principle of our research is to use open source software components and public domain technology to reduce cost for developers and users on a Linux cluster. We start with a mesh generator specifically for quartz crystal resonators of rectangular and circular types, and the Mindlin plate equations are implemented for the finite element analysis. Computing techniques like parallel processing, sparse matrix handling, and the latest eigenvalue extraction package are integrated into the program. It is clear from our computation that the combination of these algorithms and methods on a cluster can meet the memory requirement and reduce computing time significantly.

  14. Multiscale wireless sensor node for impedance-based SHM and low-frequency vibration data acquisition

    Energy Technology Data Exchange (ETDEWEB)

    Taylor, Stuart G [Los Alamos National Laboratory; Farinholt, Kevin M [Los Alamos National Laboratory; Park, Gyuhae [Los Alamos National Laboratory; Farrar, Charles R [Los Alamos National Laboratory; Todd, Michael D [UCSD

    2009-01-01

    This paper presents recent developments in an extremely compact, wireless impedance sensor node (WID3, Wireless Impedance Device) at Los Alamos National Laboratory for use in impedance-based structural health monitoring (SHM), Sensor diagnostics and low-frequency vibrational data acquisition. The current generation WID3 is equipped with an Analog Devices AD5933 impedance chip that can resolve measurements up to 100 kHz, a frequency range ideal for many SHM applications. An integrated set of multiplexers allows the end user to monitor seven piezoelectric sensors from a single sensor node. The WID3 combines on-board processing using an Atmega1281 microcontroller, data storage using flash memory, wireless communications capabilities, and a series of internal and external triggering options into a single package to realize a truly comprehensive, self-contained wireless active-sensor node for SHM applications. Furthermore, we recently extended the capability of this device by implementing low-frequency analog to digital and digital and analog converters so that the same device can measure structural vibration data. The WID3 requires less than 70 mW of power to operate, and it can operate in various wireless network paradigms. The performance of this miniaturized and portable device is compared to our previous results and its broader capabilities are demonstrated.

  15. Energy Expenditure and Substrate Oxidation in Response to Side-Alternating Whole Body Vibration across Three Commonly-Used Vibration Frequencies.

    Directory of Open Access Journals (Sweden)

    Elie-Jacques Fares

    Full Text Available There is increasing recognition about the importance of enhancing energy expenditure (EE for weight control through increases in low-intensity physical activities comparable with daily life (1.5-4 METS. Whole-body vibration (WBV increases EE modestly and could present both a useful adjuvant for obesity management and tool for metabolic phenotyping. However, it is unclear whether a "dose-response" exists between commonly-used vibration frequencies (VF and EE, nor if WBV influences respiratory quotient (RQ, and hence substrate oxidation. We aimed to investigate the EE-VF and RQ-VF relationships across three different frequencies (30, 40, and 50Hz.EE and RQ were measured in 8 healthy young adults by indirect calorimetry at rest, and subsequently during side-alternating WBV at one of 3 VFs (30, 40, and 50 Hz. Each frequency was assessed over 5 cycles of intermittent WBV (30s vibration/30s rest, separated by 5 min seated rest. During the WBV participants stood on the platform with knees flexed sufficiently to maintain comfort, prevent transmission of vibration to the upper body, and minimise voluntary physical exertion. Repeatability was assessed across 3 separate days in a subset of 4 individuals. In order to assess any sequence/habituation effect, an additional group of 6 men underwent 5 cycles of intermittent WBV (30s vibration/30s rest at 40 Hz, separated by 5 min seated rest.Side-alternating WBV increased EE relative to standing, non-vibration levels (+36%, p<0.001. However, no differences in EE were observed across VFs. Similarly, no effect of VF on RQ was found, nor did WBV alter RQ relative to standing without vibration.No relationship could be demonstrated between EE and VF in the range of 30-50Hz, and substrate oxidation did not change in response to WBV. Furthermore, the thermogenic effect of intermittent WBV, whilst robust, was quantitatively small (<2 METS.

  16. INFLUENCE OF HOUSING RIBBING MODIFICATION ON FREQUENCIES AND SHAPES OF VIBRATIONS

    Directory of Open Access Journals (Sweden)

    Piotr FOLĘGA

    2014-03-01

    Full Text Available In article an experimental and theoretical modal analysis of selected structural solutions of housings gear was carried out. Results of the examinations enabled to determine a rate of FEM modal parameters conformity with parameters of actual objects by determination of MAC ratio value. Basing on obtained results of the experimental modal analysis, the numerical models of housings were fine tuned. The obtained conformity of the results of experimental and theoretical modal analysis of examined housings’ solutions enabled to ascertain the correctness of prepared FEM models. The executed modal analysis of various housing versions enabled to estimate influence of made ribbing modifications on form and frequency of its own vibrations.

  17. Efficient Procedures of Sensitivity Analysis for Structural Vibration Systems with Repeated Frequencies

    Directory of Open Access Journals (Sweden)

    Shijia Zhao

    2013-01-01

    Full Text Available Derivatives of eigenvectors with respect to structural parameters play an important role in structural design, identification, and optimization. Particularly, calculation of eigenvector sensitivity is considered when the eigenvalues are repeated. A relaxation factor embedded in the combined approximations (CA method makes it effective to the structural response at various modified designs. The proposed method is feasible after overcoming the defection of irreversibility of the characteristic matrix. Numerical examples show that it is easy to implement the computational procedure, and the method presented in this paper is efficient for the general linear vibration damped systems with repeated frequencies.

  18. Li2MoO4 crystal growth from solution activated by low-frequency vibrations

    Science.gov (United States)

    Barinova, Olga; Sadovskiy, Andrey; Ermochenkov, Ivan; Kirsanova, Svetlana; Sukhanova, Ekaterina; Kostikov, Vladimir; Belov, Stanislav; Mozhevitina, Elena; Khomyakov, Andrew; Kuchuk, Zhanna; Zharikov, Eugeny; Avetissov, Igor

    2017-01-01

    The possibility of Li2MoO4 crystal growth from aqueous solutions activated by axial vibrational control (AVC) technique was investigated. It was found out that a low-frequency mechanical activation of the solution led to an increase of Li2MoO4 equilibrium solubility in aqueous solution for 11 rel% in the 25-29 °C temperature range. The changes in solution structure were analyzed in situ by Raman study of the solution. The AVC activation of solution resulted in a re-faceting of growing crystals, a smoothing of a face surface morphology and reduction of water content in the crystal.

  19. Comparison of DFT with Traditional Methods for the Calculation of Vibrational Frequencies and Bond Energies

    Science.gov (United States)

    Bauschlicher, Charles W.; Arnold, James O. (Technical Monitor)

    1997-01-01

    The vibrational frequencies of MO2 are computed at many levels of theory, including HF, B3LYP, BP86, CASSCF, MP2, and CCSD(T). The computed results are compared with the available experimental results. Most of the methods fail for at least one state of the systems considered. The accuracy of the results and the origin of the observed failures are discussed. The B3LYP bond energies are compared with traditional methods for a variety of systems, ranging from FeCOn+ to SiCln and its positive ions. The cases where B3LYP differs from the traditional methods are discussed.

  20. Theoretical Analysis of Vibration Frequency of Graphene Sheets Used as Nanomechanical Mass Sensor

    Directory of Open Access Journals (Sweden)

    Toshiaki Natsuki

    2015-09-01

    Full Text Available Nanoelectromechanical resonator sensors based on graphene sheets (GS show ultrahigh sensitivity to vibration. However, many factors such as the layer number and dimension of the GSs will affect the sensor characteristics. In this study, an analytical model is proposed to investigate the vibration behavior of double-layered graphene sheets (DLGSs with attached nanoparticles. Based on nonlocal continuum mechanics, the influences of the layer number, dimensions of the GSs, and of the mass and position of nanoparticles attached to the GSs on the vibration response of GS resonators are discussed in detail. The results indicate that nanomasses can easily be detected by GS resonators, which can be used as a highly sensitive nanomechanical element in sensor systems. A logarithmically linear relationship exists between the frequency shift and the attached mass when the total mass attached to GS is less than about 1.0 zg. Accordingly, it is convenient to use a linear calibration for the calculation and determination of attached nanomasses. The simulation approach and the parametric investigation are useful tools for the design of graphene-based nanomass sensors and devices.

  1. Ultra-low frequency vertical vibration isolator based on LaCoste spring linkage

    Science.gov (United States)

    Li, G.; Hu, H.; Wu, K.; Wang, G.; Wang, L. J.

    2014-10-01

    For the applications in precision measurement such as absolute gravimeter, we have designed and built an ultra-low frequency vertical vibration isolator based on LaCoste spring linkage. In the system, an arm with test mass is suspended by a mechanical extension spring, and one end of the arm is connected to the frame with flexible pivots. The displacement of the arm is detected by an optical reflection method. With the displacement signal, a feedback control force is exerted on the arm to keep it at the balance position. This method can also correct the systematic drift caused by temperature change. In order to study the vibration isolation performance of the system, we analyze the dynamic characteristics of the spring linkage in the general case, and present key methods to adjust the natural oscillating period of the system. With careful adjustment, the system can achieve a steady oscillation with a natural period up to 32 s. This isolator has been tested based on the T-1 absolute gravimeter. A statistical uncertainty of 2 μGal has been achieved within a typical 12 h measurement. The experimental results verify that the isolator has significant vibration isolation performance, and it is very suitable for applications in high precision absolute gravity measurement.

  2. Postural responses to various frequencies of vibration of the triceps surae and forefoot sole during quiet standing.

    Science.gov (United States)

    Naka, Masami; Fujiwara, Katsuo; Kiyota, Naoe

    2015-01-01

    The purpose of this study was to determine the role of somatosensory input to the sensory reference system in quiet standing. We applied vibration (0.5 mm amplitude, 1-60 Hz) to the triceps surae and the forefoot sole to stimulate the muscle spindles and the mechanoreceptors, respectively, and evaluated postural responses. Thirteen young healthy adults who showed backward-lean and forward-lean responses to vibration at high and low frequencies, respectively, participated in the full experiment. The lowest vibration frequencies inducing backward-lean responses (B-LF) were 15-55 Hz for the triceps surae and 16-60 Hz for the forefoot sole. The highest frequencies inducing forward-lean responses (F-HF) were 3-18 Hz for the triceps surae and 1-20 Hz for the forefoot sole. When vibration was simultaneously applied to the triceps surae and forefoot sole at F-HF, no response was induced in 70% of trials. A forward-lean response was induced in the remaining 30% of trials. Simultaneous vibration of the triceps surae and forefoot sole at B-LF induced backward-lean responses in all trials. All postural responses occurred 0.5-4.3 s after vibration onset. Postural responses to high-frequency vibration conceivably occur as a compensatory movement to the illusionary perception that standing position is deviating forward from quiet standing, which must be a reference position. Postural responses to low-frequency vibration possibly occur to equalize the positional information that is received from the triceps surae and the forefoot sole. Both postural responses are likely to involve the sensory reference system, which is located in the supraspinal nervous system.

  3. Comparative Study of Time-Frequency Decomposition Techniques for Fault Detection in Induction Motors Using Vibration Analysis during Startup Transient

    Directory of Open Access Journals (Sweden)

    Paulo Antonio Delgado-Arredondo

    2015-01-01

    Full Text Available Induction motors are critical components for most industries and the condition monitoring has become necessary to detect faults. There are several techniques for fault diagnosis of induction motors and analyzing the startup transient vibration signals is not as widely used as other techniques like motor current signature analysis. Vibration analysis gives a fault diagnosis focused on the location of spectral components associated with faults. Therefore, this paper presents a comparative study of different time-frequency analysis methodologies that can be used for detecting faults in induction motors analyzing vibration signals during the startup transient. The studied methodologies are the time-frequency distribution of Gabor (TFDG, the time-frequency Morlet scalogram (TFMS, multiple signal classification (MUSIC, and fast Fourier transform (FFT. The analyzed vibration signals are one broken rotor bar, two broken bars, unbalance, and bearing defects. The obtained results have shown the feasibility of detecting faults in induction motors using the time-frequency spectral analysis applied to vibration signals, and the proposed methodology is applicable when it does not have current signals and only has vibration signals. Also, the methodology has applications in motors that are not fed directly to the supply line, in such cases the analysis of current signals is not recommended due to poor current signal quality.

  4. Lattice vibration frequencies in Raman spectra of manganese and rhenium decacarbonyls

    Energy Technology Data Exchange (ETDEWEB)

    Volkov, V.E.; Danilov, I.Yu.; Zhidkov, L.L.; Kovalev, Yu.G.; Ioganson, A.A. (AN SSSR, Krasnoyarsk. Inst. Khimii i Khimicheskoj Tekhnologii)

    1983-06-01

    Raman spectra (RS) in the 170-10 cm/sup -1/ region of Mn/sub 2/(CO)/sub 10/, Re/sub 2/(CO)/sub 10/ polycrystal samples and their mixed crystals with different component percentage were obtained in the 296-123 K range. Investigations at low temperatures enabled to obtain most complete spectra in the given region. The spectra were separated to intramolecular and lattice ones on the basis of both comparing the spectra of pure components with those of mixed crystals, and studying the temperature behaviour of frequencies in the spectra. It was established that frequencies, placed below 60 cm/sup -1/ as well as in the region of 130-150 cm/sup -1/ in the spectra of manganese- and rhenium decacarbonyls are determined by the lattice vibrations of molecules in crystals.

  5. Low-frequency and wideband vibration energy harvester with flexible frame and interdigital structure

    Energy Technology Data Exchange (ETDEWEB)

    Li, Pengwei, E-mail: lipengwei@tyut.edu.cn; Wang, Yanfen; Luo, Cuixian; Li, Gang; Hu, Jie; Zhang, Wendong [MicroNano System Research Center of College of Information Engineering and Key Lab of Advanced Transducers and Intelligent Control System of the Ministry of Education, Taiyuan University of Technology, Taiyuan 030024, Shanxi (China); Liu, Ying [MicroNano System Research Center of College of Information Engineering and Key Lab of Advanced Transducers and Intelligent Control System of the Ministry of Education, Taiyuan University of Technology, Taiyuan 030024, Shanxi (China); Baicheng Ordnance Test Center of China, Baicheng 137000, Jilin (China); Liu, Wei [Baicheng Ordnance Test Center of China, Baicheng 137000, Jilin (China)

    2015-04-15

    As an alternative to traditional cantilever beam structures and their evolutions, a flexible beam based, interdigital structure, vibration energy harvester has been presented and investigated. The proposed interdigital-shaped oscillator consists of a rectangular flexible frame and series of cantilever beams interdigitally bonded to it. In order to achieve low frequency and wide-bandwidth harvesting, Young’s modulus of materials, frame size and the amount of the cantilevers have been studied systematically. The measured frequency responses of the designed device (PDMS frame, quintuple piezoelectric cantilever beams) show a 460% increase in bandwidth below 80Hz. When excited at an acceleration of 1.0 g, the energy harvester achieves to a maximum open-circuit voltage of 65V, and the maximum output power 4.5 mW.

  6. Low-frequency and wideband vibration energy harvester with flexible frame and interdigital structure

    Directory of Open Access Journals (Sweden)

    Pengwei Li

    2015-04-01

    Full Text Available As an alternative to traditional cantilever beam structures and their evolutions, a flexible beam based, interdigital structure, vibration energy harvester has been presented and investigated. The proposed interdigital-shaped oscillator consists of a rectangular flexible frame and series of cantilever beams interdigitally bonded to it. In order to achieve low frequency and wide-bandwidth harvesting, Young’s modulus of materials, frame size and the amount of the cantilevers have been studied systematically. The measured frequency responses of the designed device (PDMS frame, quintuple piezoelectric cantilever beams show a 460% increase in bandwidth below 80Hz. When excited at an acceleration of 1.0 g, the energy harvester achieves to a maximum open-circuit voltage of 65V, and the maximum output power 4.5 mW.

  7. Investigation of Microstructure, Natural Frequencies and Vibration Modes of Dragonfly Wing

    Institute of Scientific and Technical Information of China (English)

    H. Rajabi; M. Moghadami; A. Darvizeh

    2011-01-01

    In the present work, a thorough investigation on the microstructural and morphological aspects of dragonfly wings was carried out using scanning electron microscope. Then, based on this study and the previous reports, a precise three-dimensional numerical model was developed and natural frequencies and vibration modes of dragonfly forewing were determined by finite element method. The results shown that dragonfly wings are made of a series of adaptive materials, which form a very complex composite structure. This bio-composite fabrication has some unique features and potential benefits. Furthermore, the numerical results show that the first natural frequency of dragonfly wings is about 168 Hz and bending is the predominant deformation mode in this stage. The accuracy of the present analysis is verified by comparison of calculated results with experimental data.This paper may be helpful for micro aerial vehicle design concerning dynamic response.

  8. Delays of stimulus-frequency otoacoustic emissions and cochlear vibrations contradict the theory of coherent reflection filtering

    NARCIS (Netherlands)

    Siegel, JH; Cerka, AJ; Recio-Spinoso, A; Temchin, AN; van Dijk, P; Ruggero, MA

    2005-01-01

    When stimulated by tones, the ear appears to emit tones of its own, stimulus-frequency otoacoustic emissions (SFOAEs). SFOAEs were measured in 17 chinchillas and their group delays were compared with a place map of basilar-membrane vibration group delays measured at the characteristic frequency. The

  9. The dispersion correction and weak-hydrogen-bond network in low-frequency vibration of solid-state salicylic acid

    Science.gov (United States)

    Takahashi, Masae; Ishikawa, Yoichi; Ito, Hiromasa

    2012-04-01

    We perform the dispersion-corrected first-principles calculations of vibrational absorption and the far-infrared (terahertz) spectroscopic experiments at different temperature to examine the effect of weak-hydrogen-bond network on the low-frequency vibrations of solid-state salicylic acid. By dispersion correction, calculated frequencies improve especially in the intermonomer torsion and interdimer translational modes which are closely related to the weak hydrogen bonds. The calculated frequencies and their relative intensities reproduce the observed spectrum in the accuracy of 10 cm-1 or less. Weak-hydrogen-bond network causes a large frequency shift of out-of-plane intermonomer modes and enhances interdimer translational modes accompanied by the O⋯H stretching vibrations.

  10. Theoretical equilibrium geometry, vibrational frequencies and the first electronic transition energy of HCC

    Science.gov (United States)

    Fogarasi, Géza; Boggs, James E.; Pulay, Péter

    Ab initio calculations with the 6-311 G** basis set and all single and double excitations in the CI treatment have been carried out to determine the structure of the HCC radical. The theoretical geometry of R(CC) = 1·209, r(CH) = 1·067 Å (or 1·205 and 1·063, respectively, if corrected for residual errors) is in excellent accordance with the experimental rotational constant. The calculated harmonic vibrational frequencies are v1 ⋍ 3450, v2 ⋍ 540 and v3 ⋍ 2040 cm-1. An extremely low energy around 2000 cm-1 is obtained for the first electronic transition A2II ← X 2∑. Results for the excited state are also given. The theoretical vibrational frequencies, with all possible errors taken into account, are inconsistent with the accepted interpretations of the few experimental results. It is shown, however, that a complete reinterpretation of the spectroscopic observations is possible, by which the present calculations fit with the recent gas phase infrared laser spectroscopic data but remain in definite contradiction with the infrared matrix results.

  11. Low-frequency vibration modulation of guided waves to image nonlinear scatterers for structural health monitoring

    Science.gov (United States)

    Jiao, J. P.; Drinkwater, B. W.; Neild, S. A.; Wilcox, P. D.

    2009-06-01

    Guided wave structural health monitoring offers the prospect of continuous interrogation of large plate-like structures with a sparse network of permanently attached sensors. Currently, the most common approach is to monitor changes in the received signals by subtraction from a reference signal obtained when the structure was known to be defect-free. In this paper a comparison is made between this defect-free subtraction approach and a technique in which low-frequency vibration modulation of guided wave signals is used to detect nonlinear scatterers. The modulation technique potentially overcomes the need for the defect-free reference measurement as the subtraction is now made between different parts of an externally applied low-frequency vibration. Linear defects were simulated by masses bonded onto a plate and nonlinear scatterers were simulated by loading a similar mass against the plate. The experimental results show that the defect-free subtraction technique performs well in detecting the bonded mass whereas the modulation technique is able to discriminate between the bonded and loaded masses. Furthermore, because the modulation technique does not require a defect-free reference, it is shown to be relatively independent of temperature effects, a significant problem for reference based subtraction techniques.

  12. Time-dependent wave packet averaged vibrational frequencies from femtosecond stimulated Raman spectra

    Science.gov (United States)

    Wu, Yue-Chao; Zhao, Bin; Lee, Soo-Y.

    2016-02-01

    Femtosecond stimulated Raman spectroscopy (FSRS) on the Stokes side arises from a third order polarization, P(3)(t), which is given by an overlap of a first order wave packet, |" separators=" Ψ2 ( 1 ) ( p u , t ) > , prepared by a narrow band (ps) Raman pump pulse, Epu(t), on the upper electronic e2 potential energy surface (PES), with a second order wave packet, resembles the zeroth order wave packet |" separators=" Ψ1 ( 0 ) ( t ) > on the lower PES spatially, but with a force on |" separators=" Ψ2 ( 1 ) ( p u , t ) > along the coordinates of the reporter modes due to displacements in the equilibrium position, so that . The observable FSRS Raman gain is related to the imaginary part of P(3)(ω). The imaginary and real parts of P(3)(ω) are related by the Kramers-Kronig relation. Hence, from the FSRS Raman gain, we can obtain the complex P(3)(ω), whose Fourier transform then gives us the complex P(3)(t) to analyze for ω ¯ j ( t ) . We apply the theory, first, to a two-dimensional model system with one conformational mode of low frequency and one reporter vibrational mode of higher frequency with good results, and then we apply it to the time-resolved FSRS spectra of the cis-trans isomerization of retinal in rhodopsin [P. Kukura et al., Science 310, 1006 (2005)]. We obtain the vibrational frequency up-shift time constants for the C12-H wagging mode at 216 fs and for the C10-H wagging mode at 161 fs which are larger than for the C11-H wagging mode at 127 fs, i.e., the C11-H wagging mode arrives at its final frequency while the C12-H and C10-H wagging modes are still up-shifting to their final values, agreeing with the findings of Yan et al. [Biochemistry 43, 10867 (2004)].

  13. Time-frequency analysis of DC bias vibration of transformer core on the basis of Hilbert–Huang transform

    Directory of Open Access Journals (Sweden)

    Xingmou Liu

    2016-04-01

    Full Text Available This paper presents a time–frequency analysis of the vibration of transformer under direct current (DC bias through Hilbert–Huang transform (HHT. First, the theory of DC bias for the transformer was analyzed. Next, the empirical mode decomposition (EMD process, which is the key in HHT, was introduced. The results of EMD, namely, intrinsic mode functions (IMFs, were calculated and summed by Hilbert transform(HT to obtain time-dependent series in a 2D time–frequency domain. Lastly, a test system of vibration measurement for the transformer was set up. Three direction (x, y, and z axes components of core vibration were measured. Decomposition of EMD and HHT spectra showed that vibration strength increased, and odd harmonics were produced with DC bias. Results indicated that HHT is a viable signal processing tool for transformer health monitoring.

  14. Effect of higher frequency components and duration of vibration on bone tissue alterations in the rat-tail model.

    Science.gov (United States)

    Peelukhana, Srikara V; Goenka, Shilpi; Kim, Brian; Kim, Jay; Bhattacharya, Amit; Stringer, Keith F; Banerjee, Rupak K

    2015-01-01

    To formulate more accurate guidelines for musculoskeletal disorders (MSD) linked to Hand-Arm Vibration Syndrome (HAVS), delineation of the response of bone tissue under different frequencies and duration of vibration needs elucidation. Rat-tails were vibrated at 125 Hz (9 rats) and 250 Hz (9 rats), at 49 m/s(2), for 1D (6 rats), 5D (6 rats) and 20D (6 rats); D=days (4 h/d). Rats in the control group (6 rats for the vibration groups; 2 each for 1D, 5D, and 20D) were left in their cages, without being subjected to any vibration. Structural and biochemical damages were quantified using empty lacunae count and nitrotyrosine signal-intensity, respectively. One-way repeated-measure mixed-model ANOVA at pbone, structural damage quantified through empty lacunae count was significant (pbone while the trabecular bone showed significant (pbone tissue are dependent upon higher vibration frequencies of 125 Hz, 250 Hz and the duration of vibration (5D, 20D).

  15. Optical multi-frequency swept sensing for wide-field vibration measurement of interior surfaces in biological tissue

    Science.gov (United States)

    Choi, S.; Nin, F.; Hibino, H.; Suzuki, T.

    2015-12-01

    Multifrequency sensing technique adopting the wide field heterodyne detection technique is demonstrated for interior surface vibration measurements in thick biological tissue. These arrangements allow obtaining not only 3D tomographic images but also various vibration parameters such as spatial amplitude, phase, and frequency, with high temporal and transverse resolutions over a wide field. The axial resolution and the accuracy of vibration amplitude measurement were estimated to be 2.5 μm and 3 nm, respectively. This wide-field tomographic sensing method can be applied for measuring microdynamics of a variety of biological samples, thus contributing to the progress in life sciences research.

  16. Focusing vibrating targets in frequency-modulation continuous-wave-synthetic aperture radar with Doppler keystone transform

    Science.gov (United States)

    Hu, Yuxin; Zhang, Yuan; Sun, Jinping; Lei, Peng

    2016-04-01

    Vibrating targets generally induce sinusoidal micro-Doppler modulation in high resolution synthetic aperture radar (SAR). They could cause defocused and ghost results by conventional imaging algorithms. This paper proposes a method on vibrating target imaging in frequency-modulation continuous-wave (FMCW) SAR systems. The continuous motion of sensor platform during pulse time is considered in the signal model. Based on Bessel series expansion of the signal in the azimuth direction, the influence of platform motion on the azimuth frequency is eliminated after dechirp and deskew. In addition, the range walk is compensated in the two-dimensional frequency domain by Doppler keystone transform. Next, using range cell migration correction, the azimuth quadratic phase compensation and the range curvature correction are made in range-Doppler domain for the focus of paired echoes. The residual video phase of paired echoes is eliminated, and vibration parameters are estimated to compensate in the sinusoidal modulation phase. Then the deghosted image of vibrating targets can be obtained. The proposed method is applicable to multiple targets with various vibrating states due to no need of a priori knowledge of targets. Finally, simulations are carried out to validate the effectiveness of the method in FMCW-SAR imaging of vibrating targets.

  17. Communication: Quantitative multi-site frequency maps for amide I vibrational spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Reppert, Mike [Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States); Department of Chemistry, University of Chicago, Chicago, Illinois 60637 (United States); Tokmakoff, Andrei, E-mail: tokmakoff@uchicago.edu [Department of Chemistry, University of Chicago, Chicago, Illinois 60637 (United States)

    2015-08-14

    An accurate method for predicting the amide I vibrational spectrum of a given protein structure has been sought for many years. Significant progress has been made recently by sampling structures from molecular dynamics simulations and mapping local electrostatic variables onto the frequencies of individual amide bonds. Agreement with experiment, however, has remained largely qualitative. Previously, we used dipeptide fragments and isotope-labeled constructs of the protein G mimic NuG2b as experimental standards for developing and testing amide I frequency maps. Here, we combine these datasets to test different frequency-map models and develop a novel method to produce an optimized four-site potential (4P) map based on the CHARMM27 force field. Together with a charge correction for glycine residues, the optimized map accurately describes both experimental datasets, with average frequency errors of 2–3 cm{sup −1}. This 4P map is shown to be convertible to a three-site field map which provides equivalent performance, highlighting the viability of both field- and potential-based maps for amide I spectral modeling. The use of multiple sampling points for local electrostatics is found to be essential for accurate map performance.

  18. Solvation Reaction Field at the Interface Measured by Vibrational Sum Frequency Generation Spectroscopy.

    Science.gov (United States)

    Sorenson, Shayne A; Patrow, Joel G; Dawlaty, Jahan M

    2017-02-15

    Interfacial electric fields are important in several areas of chemistry, materials sciences, and device physics. However, they are poorly understood, partly because they are difficult to measure directly and model accurately. We present both a spectroscopic experimental investigation and a theoretical model for the interfacial field at the junction of a conductor and a dielectric. First, we present vibrational sum frequency generation (VSFG) results of the nitrile (CN) stretch of 4-mercaptobenzonitrile (4-MBN) covalently attached to a gold surface and in contact with a variety of liquid dielectrics. It is found that the CN stretch frequency red-shifts with increasing dielectric constant. Second, we build a model in direct analogy to the well-known Onsager reaction field theory, which has been successful in predicting vibrational frequency shifts in bulk dielectric media. Clearly, due to the asymmetric environment, with metal on one side and a dielectric on the other, the bulk Onsager model is not applicable at the interface. To address this, we apply the Onsager model to the interface accounting for the asymmetry. The model successfully explains the red-shift of the CN stretch as a function of the dielectric constant and is used to estimate the reaction field near the interface. We show the similarities and differences between the conventional bulk Onsager model and the interfacial reaction field model. In particular, the model emphasizes the importance of the metal as part of the solvation environment of the tethered molecules. We anticipate that our work will be of fundamental value to understand the crucial and often elusive electric fields at interfaces.

  19. Vibration signal analysis using parameterized time-frequency method for features extraction of varying-speed rotary machinery

    Science.gov (United States)

    Yang, Y.; Dong, X. J.; Peng, Z. K.; Zhang, W. M.; Meng, G.

    2015-01-01

    In real application, when rotary machinery frequently involves variable-speed, unsteady load and defect, it will produce non-stationary vibration signal. Such signal can be characterized by mono- or multi-component frequency modulation (FM) and its internal instantaneous patterns are closely related to operation condition of the rotary machinery. For example, instantaneous frequency (IF) and instantaneous amplitude (IA) of a non-stationary signal are two important time-frequency features to be inspected. For vibration signal analysis of the rotary machinery, time-frequency analysis (TFA), known for analyzing the signal in the time and frequency domain simultaneously, has been accepted as a key signal processing tool. Particularly, parameterized TFA, among various TFAs, has shown great potential to investigate time-frequency features of non-stationary signals. It attracts more attention for improving time-frequency representation (TFR) with signal-dependent transform parameters. However, the parameter estimation and component separation are two problems to tackle with while using the parameterized TFA to extract time-frequency features from non-stationary vibration signal of varying-speed rotary machinery. In this paper, we propose a procedure for the parameterized TFA to analyze the non-stationary vibration signal of varying-speed rotary machinery. It basically includes four steps: initialization, estimation of transform parameter, component separation and parameterized TFA, as well as feature extraction. To demonstrate the effectiveness of the proposed method in analyzing mono- and multi-component signals, it is first used to analyze the vibration response of a laboratory rotor during a speed-up and run-down process, and then extract the instantaneous time-frequency signatures of a hydro-turbine rotor in a hydroelectric power station during a shut-down stage. In addition, the results are compared with several traditional TFAs and the proposed method outperforms

  20. Conformal analysis of fundamental frequency of vibration of simple-supported elastic ellipse-plates with concentrated substance

    Institute of Scientific and Technical Information of China (English)

    QI Hong-yuan; ZHU Heng-jun

    2005-01-01

    Aimed at calculating the fundamental frequency of vibration of special-shaped, simple-supported elasticplates, Conformal Mapping theory is applied, and the mathematical method of trigonometric interpolation with interpolation points mutual iterative between odd and even sequences in boundary region is provided, as well as the conformal mapping function which can be described by real number region between complicated region and unit dish region is carried out. Furthermore, in the in-plane state of constant stress, vibrating function is completed by unit dish region method for simple-supported elastic plates with concentrated substance of complicated vibrating region, and the coefficient of fundamental frequency of the plate is analyzed. Meanwhile, taking simple-supported elastic ellipseplates as an example, the effects on fundamental frequency caused by eccentric ratio, the coefficient of constant inplane stress, as well as the concentrated substance mass and positions are analyzed respectively.

  1. Observation of the low frequency vibrational modes of bacteriophage M13 in water by Raman spectroscopy

    Directory of Open Access Journals (Sweden)

    Tsen Shaw-Wei D

    2006-09-01

    Full Text Available Abstract Background Recently, a technique which departs radically from conventional approaches has been proposed. This novel technique utilizes biological objects such as viruses as nano-templates for the fabrication of nanostructure elements. For example, rod-shaped viruses such as the M13 phage and tobacco mosaic virus have been successfully used as biological templates for the synthesis of semiconductor and metallic nanowires. Results and discussion Low wave number (≤ 20 cm-1 acoustic vibrations of the M13 phage have been studied using Raman spectroscopy. The experimental results are compared with theoretical calculations based on an elastic continuum model and appropriate Raman selection rules derived from a bond polarizability model. The observed Raman mode has been shown to belong to one of the Raman-active axial torsion modes of the M13 phage protein coat. Conclusion It is expected that the detection and characterization of this low frequency vibrational mode can be used for applications in nanotechnology such as for monitoring the process of virus functionalization and self-assembly. For example, the differences in Raman spectra can be used to monitor the coating of virus with some other materials and nano-assembly process, such as attaching a carbon nanotube or quantum dots.

  2. Sum Frequency Generation Vibrational Spectroscopy of Colloidal Platinum Nanoparticle Catalysts: Disordering versus Removal of Organic Capping

    KAUST Repository

    Krier, James M.

    2012-08-23

    Recent work with nanoparticle catalysts shows that size and shape control on the nanometer scale influences reaction rate and selectivity. Sum frequency generation (SFG) vibrational spectroscopy is a powerful tool for studying heterogeneous catalysis because it enables the observation of surface intermediates during catalytic reactions. To control the size and shape of catalytic nanoparticles, an organic ligand was used as a capping agent to stabilize nanoparticles during synthesis. However, the presence of an organic capping agent presents two major challenges in SFG and catalytic reaction studies: it blocks a significant fraction of active surface sites and produces a strong signal that prevents the detection of reaction intermediates with SFG. Two methods for cleaning Pt nanoparticles capped with poly (vinylpyrrolidone) (PVP) are examined in this study: solvent cleaning and UV cleaning. Solvent cleaning leaves more PVP intact and relies on disordering with hydrogen gas to reduce the SFG signal of PVP. In contrast, UV cleaning depends on nearly complete removal of PVP to reduce SFG signal. Both UV and solvent cleaning enable the detection of reaction intermediates by SFG. However, solvent cleaning also yields nanoparticles that are stable under reaction conditions, whereas UV cleaning results in aggregation during reaction. The results of this study indicate that solvent cleaning is more advantageous for studying the effects of nanoparticle size and shape on catalytic selectivity by SFG vibrational spectroscopy. © 2012 American Chemical Society.

  3. Low-frequency vibration sensors based on a cascaded gapped cantilever

    Science.gov (United States)

    Hu, Y.; Tu, H.; Xu, Y.

    2016-09-01

    This paper reports the development of low-cost high-performance vibration sensors based on a cascaded asymmetric-gapped cantilever for low-frequency sensing. The cascaded structure is implemented to reduce the spring constant for a high sensitivity and simultaneously avoid the undesirable shear bending. A prototype with a proof mass of 40 g and an overall size of 124 mm × 39 mm × 5.1 mm (l × w × t) has been successfully constructed. The sensor body was made of aluminum and two lead zirconate titanate sheets were implemented as the sensing element. Based on a coherence method, a noise equivalent acceleration close to the theoretical value has been achieved at 35 Hz (~3 ng/√Hz). Finally, the prototype has been successfully demonstrated for ballistocardiogaph monitoring for both sitting and lying positions.

  4. Substituent Effects on the Low-Frequency Vibrational Modes of Benzoic Acid and Related Compounds

    Institute of Scientific and Technical Information of China (English)

    GE Min; ZHAO Hong-Wei; WANG Wen-Feng; YU Xiao-Han; LI Wen-Xin

    2007-01-01

    Well-resolved absorption spectra of benzoic acid and its derivatives with one hydrogen atom replaced by a substituent group CH3, OH, NH2 or NO2 were reported in the frequency region between 6 and 67 cm-1 at room temperature with terahertz time-domain spectroscopy (THz-TDS). These substances can be distinguished easily based on the terahertz absorption spectra. The measurements suggested that even minor changes in the molecular configuration and chemical composition lead to distinct differences in THz spectrum. Density functional theory (DFT)method was used to assist the analysis and assignment of the individual THz absorption spectra of benzoic acid and its methyl derivatives. Observed THz responses of samples can be assigned to the collective vibrations associated with intermolecular hydrogen bonds.

  5. Two-dimensional concentrated-stress low-frequency piezoelectric vibration energy harvesters

    Science.gov (United States)

    Sharpes, Nathan; Abdelkefi, Abdessattar; Priya, Shashank

    2015-08-01

    Vibration-based energy harvesters using piezoelectric materials have long made use of the cantilever beam structure. Surmounting the deficiencies in one-dimensional cantilever-based energy harvesters has been a major focus in the literature. In this work, we demonstrate a strategy of using two-dimensional beam shapes to harvest energy from low frequency excitations. A characteristic Zigzag-shaped beam is created to compare against the two proposed two-dimensional beam shapes, all of which occupy a 25.4 × 25.4 mm2 area. In addition to maintaining the low-resonance bending frequency, the proposed beam shapes are designed with the goal of realizing a concentrated stress structure, whereby stress in the beam is concentrated in a single area where a piezoelectric layer may be placed, rather than being distributed throughout the beam. It is shown analytically, numerically, and experimentally that one of the proposed harvesters is able to provide significant increase in power production, when the base acceleration is set equal to 0.1 g, with only a minimal change in the resonant frequency compared to the current state-of-the-art Zigzag shape. This is accomplished by eliminating torsional effects, producing a more pure bending motion that is necessary for high electromechanical coupling. In addition, the proposed harvesters have a large effective beam tip whereby large tip mass may be placed while retaining a low-profile, resulting in a low volume harvester and subsequently large power density.

  6. The effects of whole-body vibration on the Wingate test for anaerobic power when applying individualized frequencies.

    Science.gov (United States)

    Surowiec, Rachel K; Wang, Henry; Nagelkirk, Paul R; Frame, Jeffrey W; Dickin, D Clark

    2014-07-01

    Recently, individualized frequency (I-Freq) has been introduced with the notion that athletes may elicit a greater reflex response at differing levels (Hz) of vibration. The aim of the study was to evaluate acute whole-body vibration as a feasible intervention to increase power in trained cyclists and evaluate the efficacy of using I-Freq as an alternative to 30Hz, a common frequency seen in the literature. Twelve highly trained, competitive male cyclists (age, 29.9 ± 10.0 years; body height, 175.4 ± 7.8 cm; body mass, 77.3 ± 13.9 kg) participated in the study. A Wingate test for anaerobic power was administered on 3 occasions: following a control of no vibration, 30 Hz, or I-freq. Measures of peak power, average power (AP), and the rate of fatigue were recorded and compared with the vibration conditions using separate repeated measures analysis of variance. Peak power, AP, and the rate of fatigue were not significantly impacted by either the 30 Hz or I-Freq vibration interventions (p > 0.05). Given the trained status of the individuals in this study, the ability to elicit an acute response may have been muted. Future studies should further refine the vibration parameters used and assess changes in untrained or recreationally trained populations.

  7. ZERO MODE NATURAL FREQUENCY AND NONLINEAR VIBRATION OF COUPLED LATERAL AND TORSION OF A LARGE TURBINE GENERATOR

    Institute of Scientific and Technical Information of China (English)

    Ta Na; Qiu Jiajun; Cai Ganhua

    2005-01-01

    Zero mode natural frequency (ZMNF) is found during experiments. The ZMNF and vibrations resulted by it are studied. First, calculating method of the ZMNF excited by electromagnetic in vibrational system of coupled mechanics and electrics are given from the view of magnetic energy.Laws that the ZMNF varies with active power and exciting current are obtained and are verified by experiments. Then, coupled lateral and torsional vibration of rotor shaft system is studied by considering rest eccentricity, rotating eccentricity and swing eccentricity. Using Largrange-Maxwell equation when three phases are asymmetric derives differential equation of the coupled vibration. With energy method of nonlinear vibration, amplitude-frequency characteristics of resonance are studied when rotating speed of rotor equals to ZMNF. The results show that ZMNF will occur in turbine generators by the action of electromagnetic. Because ZMNF varies with electromagnetic parameters,resonance can occur when exciting frequency of the rotor speed is fixed whereas exciting current change. And also find that a generator is in the state of large amplitude in rated exciting current.

  8. Fin whale sound reception mechanisms: skull vibration enables low-frequency hearing.

    Directory of Open Access Journals (Sweden)

    Ted W Cranford

    Full Text Available Hearing mechanisms in baleen whales (Mysticeti are essentially unknown but their vocalization frequencies overlap with anthropogenic sound sources. Synthetic audiograms were generated for a fin whale by applying finite element modeling tools to X-ray computed tomography (CT scans. We CT scanned the head of a small fin whale (Balaenoptera physalus in a scanner designed for solid-fuel rocket motors. Our computer (finite element modeling toolkit allowed us to visualize what occurs when sounds interact with the anatomic geometry of the whale's head. Simulations reveal two mechanisms that excite both bony ear complexes, (1 the skull-vibration enabled bone conduction mechanism and (2 a pressure mechanism transmitted through soft tissues. Bone conduction is the predominant mechanism. The mass density of the bony ear complexes and their firmly embedded attachments to the skull are universal across the Mysticeti, suggesting that sound reception mechanisms are similar in all baleen whales. Interactions between incident sound waves and the skull cause deformations that induce motion in each bony ear complex, resulting in best hearing sensitivity for low-frequency sounds. This predominant low-frequency sensitivity has significant implications for assessing mysticete exposure levels to anthropogenic sounds. The din of man-made ocean noise has increased steadily over the past half century. Our results provide valuable data for U.S. regulatory agencies and concerned large-scale industrial users of the ocean environment. This study transforms our understanding of baleen whale hearing and provides a means to predict auditory sensitivity across a broad spectrum of sound frequencies.

  9. Efficient procedure for the numerical calculation of harmonic vibrational frequencies based on internal coordinates.

    Science.gov (United States)

    Miliordos, Evangelos; Xantheas, Sotiris S

    2013-08-15

    We propose a general procedure for the numerical calculation of the harmonic vibrational frequencies that is based on internal coordinates and Wilson's GF methodology via double differentiation of the energy. The internal coordinates are defined as the geometrical parameters of a Z-matrix structure, thus avoiding issues related to their redundancy. Linear arrangements of atoms are described using a dummy atom of infinite mass. The procedure has been automated in FORTRAN90 and its main advantage lies in the nontrivial reduction of the number of single-point energy calculations needed for the construction of the Hessian matrix when compared to the corresponding number using double differentiation in Cartesian coordinates. For molecules of C1 symmetry the computational savings in the energy calculations amount to 36N - 30, where N is the number of atoms, with additional savings when symmetry is present. Typical applications for small and medium size molecules in their minimum and transition state geometries as well as hydrogen bonded clusters (water dimer and trimer) are presented. In all cases the frequencies based on internal coordinates differ on average by coordinates.

  10. Gray bootstrap method for estimating frequency-varying random vibration signals with small samples

    Directory of Open Access Journals (Sweden)

    Wang Yanqing

    2014-04-01

    Full Text Available During environment testing, the estimation of random vibration signals (RVS is an important technique for the airborne platform safety and reliability. However, the available methods including extreme value envelope method (EVEM, statistical tolerances method (STM and improved statistical tolerance method (ISTM require large samples and typical probability distribution. Moreover, the frequency-varying characteristic of RVS is usually not taken into account. Gray bootstrap method (GBM is proposed to solve the problem of estimating frequency-varying RVS with small samples. Firstly, the estimated indexes are obtained including the estimated interval, the estimated uncertainty, the estimated value, the estimated error and estimated reliability. In addition, GBM is applied to estimating the single flight testing of certain aircraft. At last, in order to evaluate the estimated performance, GBM is compared with bootstrap method (BM and gray method (GM in testing analysis. The result shows that GBM has superiority for estimating dynamic signals with small samples and estimated reliability is proved to be 100% at the given confidence level.

  11. A Frequency Model of Vibrational Processes in Gas-Turbine Drives of Compressor Stations of Main Gas Pipelines

    Science.gov (United States)

    Chekardovskiy, M. N.; Chekardovskiy, S. M.; Razboynikov, A. A.; Ponomareva, T. G.

    2016-10-01

    At compressor stations, systematic measurements of noise and vibration of power equipment - gas compressor units - are carried out. The article presents basic equations for calculating natural and forced frequencies at which the main defects appear. According to the studied dependences, results of calculations are obtained on the following types of drives for gas-compressor units GTK-10-4, Avon-1534, DG-90.

  12. Hydrogenation of the alpha,beta-Unsaturated Aldehydes Acrolein, Crotonaldehyde, and Prenal over Pt Single Crystals: A Kinetic and Sum-Frequency Generation Vibrational Spectroscopy Study

    Energy Technology Data Exchange (ETDEWEB)

    Kliewer, C.J.; Somorjai, G.A.

    2008-11-26

    Sum-frequency generation vibrational spectroscopy (SFG-VS) and kinetic measurements using gas chromatography have been used to study the surface reaction intermediates during the hydrogenation of three {alpha},{beta}-unsaturated aldehydes, acrolein, crotonaldehyde, and prenal, over Pt(111) at Torr pressures (1 Torr aldehyde, 100 Torr hydrogen) in the temperature range of 295K to 415K. SFG-VS data showed that acrolein has mixed adsorption species of {eta}{sub 2}-di-{sigma}(CC)-trans, {eta}{sub 2}-di-{sigma}(CC)-cis as well as highly coordinated {eta}{sub 3} or {eta}{sub 4} species. Crotonaldehyde adsorbed to Pt(111) as {eta}{sub 2} surface intermediates. SFG-VS during prenal hydrogenation also suggested the presence of the {eta}{sub 2} adsorption species, and became more highly coordinated as the temperature was raised to 415K, in agreement with its enhanced C=O hydrogenation. The effect of catalyst surface structure was clarified by carrying out the hydrogenation of crotonaldehyde over both Pt(111) and Pt(100) single crystals while acquiring the SFG-VS spectra in situ. Both the kinetics and SFG-VS showed little structure sensitivity. Pt(100) generated more decarbonylation 'cracking' product while Pt(111) had a higher selectivity for the formation of the desired unsaturated alcohol, crotylalcohol.

  13. Hydrogenation of the alpha,beta-unsaturated aldehydes acrolein, crotonaldehyde, and prenal over Pt single crystals: a kinetic and sum-frequency generation vibrational spectroscopy study.

    Science.gov (United States)

    Kliewer, Christopher J; Bieri, Marco; Somorjai, Gabor A

    2009-07-29

    Sum-frequency generation vibrational spectroscopy (SFG-VS) and kinetic measurements using gas chromatography have been used to study the surface reaction intermediates during the hydrogenation of three alpha,beta-unsaturated aldehydes, acrolein, crotonaldehyde, and prenal, over Pt(111) at Torr pressures (1 Torr of aldehyde, 100 Torr of hydrogen) in the temperature range of 295-415 K. SFG-VS data showed that acrolein has mixed adsorption species of eta(2)-di-sigma(CC)-trans, eta(2)-di-sigma(CC)-cis as well as highly coordinated eta(3) or eta(4) species. Crotonaldehyde adsorbed to Pt(111) as eta(2) surface intermediates. SFG-VS during prenal hydrogenation also suggested the presence of the eta(2) adsorption species and became more highly coordinated as the temperature was raised to 415 K, in agreement with its enhanced C=O hydrogenation. The effect of catalyst surface structure was clarified by carrying out the hydrogenation of crotonaldehyde over both Pt(111) and Pt(100) single crystals while acquiring the SFG-VS spectra in situ. Both the kinetics and SFG-VS showed little structure sensitivity. Pt(100) generated more decarbonylation "cracking" product while Pt(111) had a higher selectivity for the formation of the desired unsaturated alcohol, crotyl alcohol.

  14. Dictums for problem solving and approximation in mathematical acoustics: examples involving low-frequency vibration and radiation.

    Science.gov (United States)

    Pierce, Allan D; Thiam, Amadou G

    2012-03-01

    A sequence of dictums for mathematical acoustics is given representing opinions intended to be regarded as authoritative, but not necessarily universally agreed upon. The dictums are presented in the context of the detailed solution for a class of problems involving the forced vibration of a long cylinder protruding half-way into a half-space bounded by a compliant surface (impedance boundary) characterized by a spring constant. One limiting case corresponds to a cylinder vibrating within an infinite rigid baffle, and another limiting case corresponds to a vibrating cylinder on the compliant surface of an incompressible fluid. The second limiting case is identified as analogous to that of a floating half-submerged cylinder whose vibrations cause water waves to propagate over the surface. Attention is focused on vibrations at very low frequencies. Difficulties with insuring a causal solution are pointed out and dictums are given as to how one overcomes such difficulties. Various approximation techniques are described. The derivations involve application of the theory of complex variables and the method of matched asymptotic expansions, and the results include the apparent entrained mass in the near field of the cylinder and the radiation resistance per unit length experienced by the vibrating cylinder.

  15. Two-dimensional concentrated-stress low-frequency piezoelectric vibration energy harvesters

    Energy Technology Data Exchange (ETDEWEB)

    Sharpes, Nathan [Center for Energy Harvesting Materials and Systems (CEHMS), Virginia Tech, Blacksburg, Virginia 24061 (United States); Abdelkefi, Abdessattar [Department of Mechanical and Aerospace Engineering, New Mexico State University, Las Cruces, New Mexico 88003 (United States); Priya, Shashank [Center for Energy Harvesting Materials and Systems (CEHMS), Virginia Tech, Blacksburg, Virginia 24061 (United States); Bio-Inspired Materials and Devices Laboratory (BMDL), Virginia Tech, Blacksburg, Virginia 24061 (United States)

    2015-08-31

    Vibration-based energy harvesters using piezoelectric materials have long made use of the cantilever beam structure. Surmounting the deficiencies in one-dimensional cantilever-based energy harvesters has been a major focus in the literature. In this work, we demonstrate a strategy of using two-dimensional beam shapes to harvest energy from low frequency excitations. A characteristic Zigzag-shaped beam is created to compare against the two proposed two-dimensional beam shapes, all of which occupy a 25.4 × 25.4 mm{sup 2} area. In addition to maintaining the low-resonance bending frequency, the proposed beam shapes are designed with the goal of realizing a concentrated stress structure, whereby stress in the beam is concentrated in a single area where a piezoelectric layer may be placed, rather than being distributed throughout the beam. It is shown analytically, numerically, and experimentally that one of the proposed harvesters is able to provide significant increase in power production, when the base acceleration is set equal to 0.1 g, with only a minimal change in the resonant frequency compared to the current state-of-the-art Zigzag shape. This is accomplished by eliminating torsional effects, producing a more pure bending motion that is necessary for high electromechanical coupling. In addition, the proposed harvesters have a large effective beam tip whereby large tip mass may be placed while retaining a low-profile, resulting in a low volume harvester and subsequently large power density.

  16. [The effect of betahistine on histological changes in rabbit brain in model of whole body wide-frequency vibration].

    Science.gov (United States)

    Shimkus, Iu Iu; Sapegin, I D

    2013-01-01

    In acute experiments in conscious rabbits was studied protective action of selective blocker of histamine H3-receptor betahistine (2mg/kg i/v) against histological changes in precentral and postcentral gyrus, as well as in temporal lobe of cerebral cortex, thalamus, hypothalamus, and cerebellum, arising in case of modeling of whole body wide-frequency vibration. Betahistine attenuates edematous and degenerative changes in neurons and reciprocal glial reaction, caused by vibration, but does not eliminate edema in perivascular spaces. This effect may be related to the improvement of blood supply as a result of of vasodilatory action and decrease of oxygen consumption via vestibuloprotective effect.

  17. Time-frequency analysis of nonstationary vibration signals for deployable structures by using the constant-Q nonstationary gabor transform

    Science.gov (United States)

    Liu, Tao; Yan, Shaoze; Zhang, Wei

    2016-06-01

    Deployable structures have been widely used in on-orbit servicing spacecrafts, and the vibration properties of such structures have become increasingly important in the aerospace industry. The constant-Q nonstationary Gabor transform (CQ-NSGT) is introduced in this paper to accurately evaluate the variation in the frequency and amplitude of vibration signals along with time. First, an example signal is constructed on the basis of the vibration properties of deployable structures and is processed by the short-time Fourier transform, Wigner-Ville distribution, Hilbert-Huang transform, and CQ-NSGT. Results show that time and frequency resolutions are simultaneously fine only by employing CQ-NSGT. Subsequently, a zero padding operation is conducted to correct the calculation error at the end of the transform results. Finally, a set of experimental devices is constructed. The vibration signal of the experimental mode is processed by CQ-NSGT. On this basis, the experimental signal properties are discussed. This time-frequency method may be useful for formulating the dynamics for complex deployable structures.

  18. Highly Accurate Quartic Force Fields, Vibrational Frequencies, and Spectroscopic Constants for Cyclic and Linear C3H3(+)

    Science.gov (United States)

    Huang, Xinchuan; Taylor, Peter R.; Lee, Timothy J.

    2011-01-01

    High levels of theory have been used to compute quartic force fields (QFFs) for the cyclic and linear forms of the C H + molecular cation, referred to as c-C H + and I-C H +. Specifically the 33 3333 singles and doubles coupled-cluster method that includes a perturbational estimate of connected triple excitations, CCSD(T), has been used in conjunction with extrapolation to the one-particle basis set limit and corrections for scalar relativity and core correlation have been included. The QFFs have been used to compute highly accurate fundamental vibrational frequencies and other spectroscopic constants using both vibrational 2nd-order perturbation theory and variational methods to solve the nuclear Schroedinger equation. Agreement between our best computed fundamental vibrational frequencies and recent infrared photodissociation experiments is reasonable for most bands, but there are a few exceptions. Possible sources for the discrepancies are discussed. We determine the energy difference between the cyclic and linear forms of C H +, 33 obtaining 27.9 kcal/mol at 0 K, which should be the most reliable available. It is expected that the fundamental vibrational frequencies and spectroscopic constants presented here for c-C H + 33 and I-C H + are the most reliable available for the free gas-phase species and it is hoped that 33 these will be useful in the assignment of future high-resolution laboratory experiments or astronomical observations.

  19. A hybrid single-end-access MZI and Φ-OTDR vibration sensing system with high frequency response

    Science.gov (United States)

    Zhang, Yixin; Xia, Lan; Cao, Chunqi; Sun, Zhenhong; Li, Yanting; Zhang, Xuping

    2017-01-01

    A hybrid single-end-access Mach-Zehnder interferometer (MZI) and phase sensitive OTDR (Φ-OTDR) vibration sensing system is proposed and demonstrated experimentally. In our system, the narrow optical pulses and the continuous wave are injected into the fiber through the front end of the fiber at the same time. And at the rear end of the fiber, a frequency-shift-mirror (FSM) is designed to back propagate the continuous wave modulated by the external vibration. Thus the Rayleigh backscattering signals (RBS) and the back propagated continuous wave interfere with the reference light at the same end of the sensing fiber and a single-end-access configuration is achieved. The RBS can be successfully separated from the interference signal (IS) through digital signal process due to their different intermediate frequency based on frequency division multiplexing technique. There is no influence between these two schemes. The experimental results show 10 m spatial resolution and up to 1.2 MHz frequency response along a 6.35 km long fiber. This newly designed single-end-access setup can achieve vibration events locating and high frequency events response, which can be widely used in health monitoring for civil infrastructures and transportation.

  20. Mapping analysis of vibrating fundamental frequency for simple-supported elastic rectangle-plates with concentrated mass

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    By conformal mapping theory, a trigonometric interpolation method between odd and even sequences in rectangle boundary region was provided, and the conformal mapping function of rectangle-plate with arc radius between complicated region and unite dish region was carried out. Aiming at calculating the vibrating fundamental frequency of special-shaped, elastic simple-supported rectangle-plates, in the in-plane state of constant stress, the vibration function of this complicated plate was depicted by unit dish region. The coefficient of fundamental frequency was calculated. Whilst, taking simple-supported elastic rectangle-plates with arc radius as an example, the effects on fundamental frequency caused by the concentrated mass and position, the ratio of the length to width of rectangle, as well as the coefficient of constant in-plane stress were analyzed respectively.

  1. Theoretical vibrational sum-frequency generation spectroscopy of water near lipid and surfactant monolayer interfaces

    Energy Technology Data Exchange (ETDEWEB)

    Roy, S.; Gruenbaum, S. M.; Skinner, J. L. [Theoretical Chemistry Institute and Department of Chemistry, 1101 University Ave., University of Wisconsin-Madison, Madison, Wisconsin 53706 (United States)

    2014-11-14

    Understanding the structure of water near cell membranes is crucial for characterizing water-mediated events such as molecular transport. To obtain structural information of water near a membrane, it is useful to have a surface-selective technique that can probe only interfacial water molecules. One such technique is vibrational sum-frequency generation (VSFG) spectroscopy. As model systems for studying membrane headgroup/water interactions, in this paper we consider lipid and surfactant monolayers on water. We adopt a theoretical approach combining molecular dynamics simulations and phase-sensitive VSFG to investigate water structure near these interfaces. Our simulated spectra are in qualitative agreement with experiments and reveal orientational ordering of interfacial water molecules near cationic, anionic, and zwitterionic interfaces. OH bonds of water molecules point toward an anionic interface leading to a positive VSFG peak, whereas the water hydrogen atoms point away from a cationic interface leading to a negative VSFG peak. Coexistence of these two interfacial water species is observed near interfaces between water and mixtures of cationic and anionic lipids, as indicated by the presence of both negative and positive peaks in their VSFG spectra. In the case of a zwitterionic interface, OH orientation is toward the interface on the average, resulting in a positive VSFG peak.

  2. Cardiac reflections and natural vibrations: Force-frequency relation recording system in the stress echo lab

    Directory of Open Access Journals (Sweden)

    Pianelli Mascia

    2007-11-01

    Full Text Available Abstract Background The inherent ability of ventricular myocardium to increase its force of contraction in response to an increase in contraction frequency is known as the cardiac force-frequency relation (FFR. This relation can be easily obtained in the stress echo lab, where the force is computed as the systolic pressure/end-systolic volume index ratio, and measured for increasing heart rates during stress. Ideally, the noninvasive, imaging independent, objective assessment of FFR would greatly enhance its practical appeal. Objectives 1 – To evaluate the feasibility of the cardiac force measurement by a precordial cutaneous sensor. 2 – To build the curve of force variation as a function of the heart rate. 3 – To compare the standard stress echo results vs. this sensor operator-independent built FFR. Methods The transcutaneous force sensor was positioned in the precordial region in 88 consecutive patients referred for exercise, dipyridamole, or pacing stress. The force was measured as the myocardial vibrations amplitude in the isovolumic contraction period. FFR was computed as the curve of force variation as a function of heart rate. Standard echocardiographic FFR measurements were performed. Results A consistent FFR was obtained in all patients. Both the sensor built and the echo built FFR identifiy pts with normal or abnormal contractile reserve. The best cut-off value of the sensor built FFR was 15.5 g * 10-3 (Sensitivity = 0.85, Specificity = 0.77. Sensor built FFR slope and shape mirror pressure/volume relation during stress. This approach is extendable to daily physiological exercise and could be potentially attractive in home monitoring systems.

  3. Vibration-induced drop atomization and the numerical simulation of low-frequency single-droplet ejection

    Science.gov (United States)

    James, Ashley J.; Smith, Marc K.; Glezer, Ari

    2003-02-01

    Vibration-induced droplet ejection is a novel way to create a spray. In this method, a liquid drop is placed on a vertically vibrating solid surface. The vibration leads to the formation of waves on the free surface. Secondary droplets break off from the wave crests when the forcing amplitude is above a critical value. When the forcing frequency is small, only low-order axisymmetric wave modes are excited, and a single secondary droplet is ejected from the tip of the primary drop. When the forcing frequency is high, many high-order non-axisymmetric modes are excited, the motion is chaotic, and numerous small secondary droplets are ejected simultaneously from across the surface of the primary drop. In both frequency regimes a crater may form that collapses to create a liquid spike from which droplet ejection occurs. An axisymmetric, incompressible, Navier Stokes solver was developed to simulate the low-frequency ejection process. A volume-of-fluid method was used to track the free surface, with surface tension incorporated using the continuum-surface-force method. A time sequence of the simulated interface shape compared favourably with an experimental sequence. The dynamics of the droplet ejection process was investigated, and the conditions under which ejection occurs and the effect of the system parameters on the process were determined.

  4. Ultra-low-frequency vertical vibration isolator based on a two-stage beam structure for absolute gravimetry

    Science.gov (United States)

    Wang, G.; Wu, K.; Hu, H.; Li, G.; Wang, L. J.

    2016-10-01

    To reduce seismic and environmental vibration noise, ultra-low-frequency vertical vibration isolation systems play an important role in absolute gravimetry. For this purpose, an isolator based on a two-stage beam structure is proposed and demonstrated. The isolator has a simpler and more robust structure than the present ultra-low-frequency vertical active vibration isolators. In the system, two beams are connected to a frame using flexural pivots. The upper beam is suspended from the frame with a normal hex spring and the lower beam is suspended from the upper one using a zero-length spring. The pivot of the upper beam is not vertically above the pivot of the lower beam. With this special design, the attachment points of the zero-length spring to the beams can be moved to adjust the effective stiffness. A photoelectric detector is used to detect the angle between the two beams, and a voice coil actuator attached to the upper beam is controlled by a feedback circuit to keep the angle at a fixed value. The system can achieve a natural period of 100 s by carefully moving the attachment points of the zero-length spring to the beams and tuning the feedback parameters. The system has been used as an inertial reference in the T-1 absolute gravimeter. The experiment results demonstrate that the system has significant vibration isolation performance that holds promise in applications such as absolute gravimeters.

  5. Low-frequency vibration isolation in six degrees of freedom: the Hummingbird

    NARCIS (Netherlands)

    Rijnveld, N.; Braber, R. van den; Fraanje, P.R.; Dool, T.C. van den

    2010-01-01

    TNO Science and Industry and MECAL have developed a six degree of freedom vibration isolation system that suppresses both floor vibrations and direct forces on a table top. The achieved reduction of transmissibility and compliance is 40 dB between 1 and 50 Hz in vertical direction, and 30 dB between

  6. Therapeutic impact of low amplitude high frequency whole body vibrations on the osteogenesis imperfecta mouse bone.

    Science.gov (United States)

    Vanleene, Maximilien; Shefelbine, Sandra J

    2013-04-01

    Osteogenesis imperfecta (OI) is characterized by extremely brittle bone. Currently, bisphosphonate drugs allow a decrease of fracture by inhibiting bone resorption and increasing bone mass but with possible long term side effects. Whole body mechanical vibrations (WBV) treatment may offer a promising route to stimulate bone formation in OI patients as it has exhibited health benefits on both muscle and bone mass in human and animal models. The present study has investigated the effects of WBV (45Hz, 0.3g, 15minutes/days, 5days/week) in young OI (oim) and wild type female mice from 3 to 8weeks of age. Vibration therapy resulted in a significant increase in the cortical bone area and cortical thickness in the femur and tibia diaphysis of both vibrated oim and wild type mice compared to sham controls. Trabecular bone was not affected by vibration in the wild type mice; vibrated oim mice, however, exhibited significantly higher trabecular bone volume fraction in the proximal tibia. Femoral stiffness and yield load in three point bending were greater in the vibrated wild type mice than in sham controls, most likely attributed to the increase in femur cortical cross sectional area observed in the μCT morphology analyses. The vibrated oim mice showed a trend toward improved mechanical properties, but bending data had large standard deviations and there was no significant difference between vibrated and non-vibrated oim mice. No significant difference of the bone apposition was observed in the tibial metaphyseal trabecular bone for both the oim and wild type vibrated mice by histomorphometry analyses of calcein labels. At the mid diaphysis, the cortical bone apposition was not significantly influenced by the WBV treatment in both the endosteum and periosteum of the oim vibrated mice while a significant change is observed in the endosteum of the vibrated wild type mice. As only a weak impact in bone apposition between the vibrated and sham groups is observed in the

  7. Control of the low-frequency vibrations of elastic metamaterial shafts with discretized arc-rubber layers

    Science.gov (United States)

    Lixia, Li; Anjiang, Cai

    2016-06-01

    We propose a new kind of elastic metamaterial (EM) shaft with discretized arc-shaped rubber layers, which shows excellent low-frequency vibration properties. The band gaps of the shaft structure were analyzed by employing the finite element method. The proposed EM shaft exhibits much lower band gaps than the corresponding structures with the whole rubber ring. Furthermore, the band gaps can be modulated by tuning the arc angle and the number of the arc-shaped rubbers. Additionally, we observed that the first complete band gap tends to disappear when the arc angle of each arc-shaped rubber section is decreased but the arc number remains fixed because the arc angle more strongly affects the rotational stiffness than the transverse stiffness of the rubber layers. This new type of EM shafts could find potential application as a means to control the low-frequency vibrations of rotor shafts in mechanical engineering.

  8. Time-frequency representation based on time-varying autoregressive model with applications to non-stationary rotor vibration analysis

    Indian Academy of Sciences (India)

    Long Zhang; Guoliang Xiong; Hesheng Liu; Huijun Zou; Weizhong Guo

    2010-04-01

    A parametric time-frequency representation is presented based on timevarying autoregressive model (TVAR), followed by applications to non-stationary vibration signal processing. The identification of time-varying model coefficients and the determination of model order, are addressed by means of neural networks and genetic algorithms, respectively. Firstly, a simulated signal which mimic the rotor vibration during run-up stages was processed for a comparative study on TVAR and other non-parametric time-frequency representations such as Short Time Fourier Transform, Continuous Wavelet Transform, Empirical Mode Decomposition, Wigner–Ville Distribution and Choi–Williams Distribution, in terms of their resolutions, accuracy, cross term suppression as well as noise resistance. Secondly, TVAR was applied to analyse non-stationary vibration signals collected from a rotor test rig during run-up stages, with an aim to extract fault symptoms under non-stationary operating conditions. Simulation and experimental results demonstrate that TVAR is an effective solution to non-stationary signal analysis and has strong capability in signal time-frequency feature extraction.

  9. Layer-number dependent high-frequency vibration modes in few-layer transition metal dichalcogenides induced by interlayer couplings

    Science.gov (United States)

    Tan, Qing-Hai; Zhang, Xin; Luo, Xiang-Dong; Zhang, Jun; Tan, Ping-Heng

    2017-03-01

    Two-dimensional transition metal dichalcogenides (TMDs) have attracted extensive attention due to their many novel properties. The atoms within each layer in two-dimensional TMDs are joined together by covalent bonds, while van der Waals interactions combine the layers together. This makes its lattice dynamics layer-number dependent. The evolutions of ultralow frequency ( 50 cm‑1) vibration modes in few-layer TMDs and demonstrate how the interlayer coupling leads to the splitting of high-frequency vibration modes, known as Davydov splitting. Such Davydov splitting can be well described by a van der Waals model, which directly links the splitting with the interlayer coupling. Our review expands the understanding on the effect of interlayer coupling on the high-frequency vibration modes in TMDs and other two-dimensional materials. Project supported by the National Basic Research Program of China (No. 2016YFA0301200), the National Natural Science Foundation of China (Nos. 11225421, 11474277, 11434010, 61474067, 11604326, 11574305 and 51527901), and the National Young 1000 Talent Plan of China.

  10. Balancing Vibrations at Harmonic Frequencies by Injecting Harmonic Balancing Signals into the Armature of a Linear Motor/Alternator Coupled to a Stirling Machine

    Science.gov (United States)

    Holliday, Ezekiel S. (Inventor)

    2014-01-01

    Vibrations at harmonic frequencies are reduced by injecting harmonic balancing signals into the armature of a linear motor/alternator coupled to a Stirling machine. The vibrations are sensed to provide a signal representing the mechanical vibrations. A harmonic balancing signal is generated for selected harmonics of the operating frequency by processing the sensed vibration signal with adaptive filter algorithms of adaptive filters for each harmonic. Reference inputs for each harmonic are applied to the adaptive filter algorithms at the frequency of the selected harmonic. The harmonic balancing signals for all of the harmonics are summed with a principal control signal. The harmonic balancing signals modify the principal electrical drive voltage and drive the motor/alternator with a drive voltage component in opposition to the vibration at each harmonic.

  11. A MEMS-Based Piezoelectric Power Generator for Low Frequency Vibration Energy Harvesting

    Institute of Scientific and Technical Information of China (English)

    FANG Hua-Bin; LIU Jing-Quan; XU Zheng-Yi; DONG Lu; CHEN Di; CAI Bing-Chu; LIU Yue

    2006-01-01

    @@ A novel power generator has been achieved to convert vibration to electrical energy via the piezoelectric effect. The generator obtained by micro fabrication process mainly consists of silicon based frame and composite cantilever.The prototype tested at resonant vibration generates 1.15 μ W of effective power to a 20.4-kΩ resistance load. The potential of this work is to offer miniaturization solutions for power generators, and with the proposed method the ambient ubiquitous vibration can be harvested effectively as endless energy source to form an integrated self-powering system.

  12. The Utilization of Low Frequency Raman Spectra of Gases for the Study of Molecules with Large Amplitude Vibration

    Institute of Scientific and Technical Information of China (English)

    James R. Durig; Sarah Xiao-hua Zhou; Joshua Klaassen; Arindam Ganguly

    2009-01-01

    The utilization of the Raman spectra of the low frequency bending mode for three quasi-linear molecules, disiloxane, (SiH3)2 O; methylisocyanate, CH3NCO; and dimethy lisocyanate, (CH3)2SiHNCO for observing the low frequency anharmonic bending vibration is demonstrated which is superior to the corresponding far infrared spectra. From the observed frequencies from the Raman spectra the potential function governing the heavy atom motion to linearity has been obtained from which the barrier has been determined. These experimental values are compared to the ab ini-tio predicted values. Also low frequency Raman spectra of the ring puckering vibration of chlorocy-clobutane, c-C4H7Cl, bromocyclobutane, c-C4H7Br, and aminocyclobutane, c-C4H7NH2, have been utilized to obtain the potential function governing the ring inversion for these molecules. The deter-mined barriers to planarity are compared to those obtained from MP2 (full) ab initio and density functional theory B3LYP calculations by utilizing a variety of basis sets. For all of these studies it is shown that the Raman spectra are superior to the infrared spectra for determining the frequencies of the excited state transitions.

  13. Three-Dimensional Vibration Isolator for Suppressing High-Frequency Responses for Sage III Contamination Monitoring Package (CMP)

    Science.gov (United States)

    Li, Y.; Cutright, S.; Dyke, R.; Templeton, J.; Gasbarre, J.; Novak, F.

    2015-01-01

    The Stratospheric Aerosol and Gas Experiment (SAGE) III - International Space Station (ISS) instrument will be used to study ozone, providing global, long-term measurements of key components of the Earth's atmosphere for the continued health of Earth and its inhabitants. SAGE III is launched into orbit in an inverted configuration on SpaceX;s Falcon 9 launch vehicle. As one of its four supporting elements, a Contamination Monitoring Package (CMP) mounted to the top panel of the Interface Adapter Module (IAM) box experiences high-frequency response due to structural coupling between the two structures during the SpaceX launch. These vibrations, which were initially observed in the IAM Engineering Development Unit (EDU) test and later verified through finite element analysis (FEA) for the SpaceX launch loads, may damage the internal electronic cards and the Thermoelectric Quartz Crystal Microbalance (TQCM) sensors mounted on the CMP. Three-dimensional (3D) vibration isolators were required to be inserted between the CMP and IAM interface in order to attenuate the high frequency vibrations without resulting in any major changes to the existing system. Wire rope isolators were proposed as the isolation system between the CMP and IAM due to the low impact to design. Most 3D isolation systems are designed for compression and roll, therefore little dynamic data was available for using wire rope isolators in an inverted or tension configuration. From the isolator FEA and test results, it is shown that by using the 3D wire rope isolators, the CMP high-frequency responses have been suppressed by several orders of magnitude over a wide excitation frequency range. Consequently, the TQCM sensor responses are well below their qualification environments. It is indicated that these high-frequency responses due to the typical instrument structural coupling can be significantly suppressed by a vibration passive control using the 3D vibration isolator. Thermal and contamination

  14. On the correction of calculated vibrational frequencies for the effects of the counterions - α,ω-diamine dihydrochlorides.

    Science.gov (United States)

    Fiuza, S M; Silva, T M; Marques, M P M; de Carvalho, L A E Batista; Amado, A M

    2015-10-01

    The present work provides sets of correction factors to adjust the calculated vibrational frequencies of a series of α,ω-diamines hydrochloride salts to account for the intermolecular interactions with the counterion. The study was performed using different theory levels for predicting the vibrational data of isolated dicationic α,ω-diamines and their hydrochloride forms, with and without the explicit account of the interactions with the chloride counterions. Different sets of correction factors were determined for each theory level considering the four smallest elements for the α,ω-diamines series, while their transferability and reliability was evaluated considering the larger elements of the series. The theory level simplification was also evaluated and was found to neither compromise the vibrational frequencies estimates nor the magnitude and accuracy of the pre-defined scaling factors. This suggests that transferability of the correction factors is possible not only for different diamines but also between different levels of theory with the averaged group correction factor, ζ g (a) , being the best choice to account for the effects of the N-H · · · Cl interactions. The possibility of simplifying the theory level without compromising efficiency and accuracy is additionally of utmost importance. This computational approach can constitute a valuable tool in the future for studying the hydrochloride forms of larger and more complex diamine systems. Graphical Abstract A computational approach that may constitute a valuable tool for studying the hydrochloride forms of large and complex diamine systems. Correction factors to adjust the vibrational frequencies calculated for isolated dicationic primary diamines for the effects of the interactions with chloride counterions, without their explicit account in the calculations, are presented and evaluated for eficiency.

  15. The effects of photobiomodulation and low-amplitude high-frequency vibration on bone healing process: a comparative study.

    Science.gov (United States)

    Rajaei Jafarabadi, M; Rouhi, G; Kaka, G; Sadraie, S H; Arum, J

    2016-12-01

    This study aimed at investigating the effects of photobiomodulation (PBM) and low-amplitude high-frequency (LAHF) whole body mechanical vibration on bone fracture healing process when metallic plates are implanted in rats' femurs. Forty male rats weighing between 250 and 350 g, 12 weeks old, were employed in this study. A transverse critical size defect (CSD) was made in their right femurs that were fixed by stainless steel plates. After the surgery, the rats were divided equally into four groups: low-level laser therapy group (GaAlAs laser, 830 nm, 40 mW, 4 J/cm(2), 0.35 cm beam diameter, LLLT), whole body vibration group (60 Hz, 0.1 mm amplitude, 1.5 g, WBV), a combination of laser and vibration group (LV), and the control group (C). Each group was divided into two subgroups based on sacrifice dates. The rats were sacrificed at intervals of 3 and 6 weeks after the surgery to extract their right femurs for radiography and biomechanical and histological analyses, and the results were analyzed using standard statistical methods. Radiographic analyses showed greater callus formation in the LLLT and WBV groups than in control group at both 3 (P low-amplitude high-frequency WBV both had a positive impact on bone healing process, for critical size defects in the presence of a stainless steel implant. But their combination, i.e., low-level laser therapy and low-amplitude high-frequency whole body vibration (LV), interestingly did not accelerate the fractured bone healing process.

  16. Raman scattering studies of the low-frequency vibrational modes of bacteriophage M13 in water—observation of an axial torsion mode

    Science.gov (United States)

    Tsen, K. T.; Dykeman, Eric C.; Sankey, Otto F.; Tsen, Shaw-Wei D.; Lin, Nien-Tsung; Kiang, Juliann G.

    2006-11-01

    Low-wavenumber (detection and characterization of this low-frequency vibrational mode can be used for applications in nanotechnology such as for monitoring the process of virus functionalization and self-assembly.

  17. Effects of Plant Cell Wall Matrix Polysaccharides on Bacterial Cellulose Structure Studied with Vibrational Sum Frequency Generation Spectroscopy and X-ray Diffraction

    Energy Technology Data Exchange (ETDEWEB)

    Park, Yong Bum; Lee, Christopher M; Kafle, Kabindra; Park, Sunkyu; Cosgrove, Daniel; Kim, Seong H

    2014-07-14

    The crystallinity, allomorph content, and mesoscale ordering of cellulose produced by Gluconacetobacter xylinus cultured with different plant cell wall matrix polysaccharides were studied with vibrational sum frequency generation (SFG) spectroscopy and X-ray diffraction (XRD).

  18. Elucidating low-frequency vibrational dynamics in calcite and water with time-resolved third-harmonic generation spectroscopy.

    Science.gov (United States)

    Wang, Liang; Liu, Weimin; Fang, Chong

    2015-07-14

    Low-frequency vibrations are foundational for material properties including thermal conductivity and chemical reactivity. To resolve the intrinsic molecular conformational dynamics in condensed phase, we implement time-resolved third-harmonic generation (TRTHG) spectroscopy to unravel collective skeletal motions in calcite, water, and aqueous salt solution in situ. The lifetime of three Raman-active modes in polycrystalline calcite at 155, 282 and 703 cm(-1) is found to be ca. 1.6 ps, 1.3 ps and 250 fs, respectively. The lifetime difference is due to crystallographic defects and anharmonic effects. By incorporating a home-built wire-guided liquid jet, we apply TRTHG to investigate pure water and ZnCl2 aqueous solution, revealing ultrafast dynamics of water intermolecular stretching and librational bands below 500 cm(-1) and a characteristic 280 cm(-1) vibrational mode in the ZnCl4(H2O)2(2-) complex. TRTHG proves to be a compact and versatile technique that directly uses the 800 nm fundamental laser pulse output to capture ultrafast low-frequency vibrational motion snapshots in condensed-phase materials including the omnipresent water, which provides the important time dimension to spectral characterization of molecular structure-function relationships.

  19. Impact of acoustic airflow on intrasinus drug deposition: New insights into the vibrating mode and the optimal acoustic frequency to enhance the delivery of nebulized antibiotic

    OpenAIRE

    2015-01-01

    International audience; Aim: We investigated the impact of vibrating acoustic airflow, the high frequency (f ≥ 100 Hz) and the low frequency (f ≤ 45 Hz) sound waves, on the enhancement of intrasinus drug deposition.Methods: 81mKr-gas ventilation study was performed in a plastinated human cast with and without the addition of vibrating acoustic airflow. Similarly, intrasinus drug deposition in a nasal replica using gentamicin as a marker was studied with and without the superposition of differ...

  20. Optimization of linear zigzag insert metastructures for low-frequency vibration attenuation using genetic algorithms

    Science.gov (United States)

    Abdeljaber, Osama; Avci, Onur; Kiranyaz, Serkan; Inman, Daniel J.

    2017-02-01

    Vibration suppression remains a crucial issue in the design of structures and machines. Recent studies have shown that with the use of metamaterial inspired structures (or metastructures), considerable vibration attenuation can be achieved. Optimization of the internal geometry of metastructures maximizes the suppression performance. Zigzag inserts have been reported to be efficient for vibration attenuation. It has also been reported that the geometric parameters of the inserts affect the vibration suppression performance in a complex manner. In an attempt to find out the most efficient parameters, an optimization study has been conducted on the linear zigzag inserts and is presented here. The research reported in this paper aims at developing an automated method for determining the geometry of zigzag inserts through optimization. This genetic algorithm based optimization process searches for optimal zigzag designs which are properly tuned to suppress vibrations when inserted in a specific host structure (cantilever beam). The inserts adopted in this study consist of a cantilever zigzag structure with a mass attached to its unsupported tip. Numerical simulations are carried out to demonstrate the efficiency of the proposed zigzag optimization approach.

  1. Collective excitations in liquid DMSO : FIR spectrum, Low frequency vibrational density of states and ultrafast dipolar solvation dynamics

    CERN Document Server

    Hazra, Milan

    2016-01-01

    Valuable dynamical and structural information about neat liquid DMSO at ambient conditions can be obtained through study of low frequency vibrations in the far infrared (FIR), that is, terahertz regime. For DMSO, collective excitations as well as single molecule stretches and bends have been measured by different kinds of experiments such as OHD-RIKES and terahertz spectroscopy. In the present work we investigate the intermolecular vibrational spectrum of DMSO through three different computational techniques namely (i) the far-infra red spectrum obtained through Fourier transform of total dipole moment auto time correlation function, (ii) from Fourier transform of the translational and angular velocity time autocorrelation functions and a (iii) quenched normal mode analysis of the parent liquid at 300K. The three spectrum, although exhibit differences among each other, reveal similar features which are in good, semi-quantitative, agreement with experimental results. Study of participation ratio of the density...

  2. Analiza niskofrekventnog spektra vibracija na elementima strukture helikoptera 'Gazela' / Analysis of low frequency vibrations on the structural connection elements of the Gazelle helicopter

    Directory of Open Access Journals (Sweden)

    Miroslav M. Jovanović

    2010-10-01

    Full Text Available U radu je prikazan postupak i metodologija ispitivanja vibracija na helikopteru 'gazela' radi definisanja efikasnosti prigušenja vibracija na vezi struktura - sedište pilota. Posebna pažnja posvećena je teorijskim osnovama vibracija na helikopteru, određivanju radnih frekvencija, definisanju režima rada i profila leta helikoptera u toku ispitivanja. Na kraju rada prikazani su rezultati merenja vibracija u frekventnom domenu. / In this paper the procedure and methodology of vibration testing on a Gazelle helicopter are presented with the aim to define efficiency of vibration damping at the structure-pilot seat connection. A particular attention is paid to the theoretical basis of helicopter vibrations, definition of working frequency, regime and profile of flight during the test. The results of the vibration measurement are shown in the frequency domain. Introduction Nowadays, possibility of defining loads and vibrations is one of the most important requests in the design and modification of processes on helicopters. The loads occuring on the main rotor during flight are the basic source of vibrations on the helicopter. Possibilities to satisfy international standards in the area of structural and human vibrations are based on continuous and adequate measurement and analysis of the vibration levels on all elements of helicopters. This paper shows the procedures of vibration measuring and analyzing in order to define efficiency of vibration damping using a modern acquisition system NetdB 12 and its software dBFA Suite. Theoretical analysis of vibration sources on the helicopter main rotor The helicopter rotor operates in a complex aerodynamic flow field. The aerodynamic loads on the rotor blade vary considerably as it moves around the rotor disc, and in steady flight these loads are periodic. A particular attention is paid to a theoretical basis of vibration sources on a helicopter. A complex aerodynamic field in the plane of the helicopter

  3. Effects of surface finish and treatment on the fatigue behaviour of vibrating cylinder block using frequency response approach

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    This paper presents the effects of surface finish and treatment on the high cycle fatigue behaviour of vibrating cylinder block of a new two-stroke free piston engine at complex variable amplitude loading conditions using frequency response approach,Finite element modelling and frequency response analysis was conducted using finite element analysis software Package MSC.PATRAN/MSC.NASTRAN and fatigue life prediction was carried out using MSC.FATIGUE software. Based on the finite element results, different frequency response approach was applied to predict the cylinder block fatigue life. Results for different load histories and material combinations are also discussed. Results indicated great effects for all surface finish and treatment. It is concluded that polished and cast surface finish conditions give the highest and lowest cylinder block lives, respectively; and that Nitrided treatment leads to longest cylinder block life. The results were used to draw contour plots of fatigue life and damage in the worst or most damaging case.

  4. Electron-phonon metamaterial featuring nonlinear tri-interleaved piezoelectric topologies and its application in low-frequency vibration control

    Science.gov (United States)

    Bao, Bin; Guyomar, Daniel; Lallart, Mickaël

    2016-09-01

    This article proposes a nonlinear tri-interleaved piezoelectric topology based on the synchronized switch damping on inductor (SSDI) technique, which can be applied to phononic metamaterials for elastic wave control and effective low-frequency vibration reduction. A comparison of the attenuation performance is made between piezoelectric phononic metamaterial with distributed SSDI topology (each SSDI shunt being independently connected to a single piezoelectric element) and piezoelectric phononic metamaterial with the proposed electronic topology. Theoretical results show excellent band gap hybridization (near-coupling between Bragg scattering mechanism and wideband resonance mechanism induced by synchronized switch damping networks in piezoelectric phononic metamaterials) with the proposed electronic topology over the investigated frequency domain. Furthermore, piezoelectric phononic metamaterials with proposed electronic topology generated a better low-frequency broadband gap, which is experimentally validated by measuring the harmonic response of a piezoelectric phononic metamaterial beam under clamped-clamped boundary conditions.

  5. Observations of earth eigen vibrations possibly excited by low frequency gravity waves

    Science.gov (United States)

    Tuman, V. S.

    1971-01-01

    A cryogenic gravity meter made of two parts, a magnetic suspension unit and a detection module, was used to monitor earth eigen vibrations. The magnetic field and field gradient are generated by energizing a set of superconducting coils made of niobium-zirconium alloy wire. The detection module is a double Josephson junction magnetometer. The output is printed on a chart recorder and later digitized using a computer; a Fourier transformation is performed on the accumulated data. The measurements of eigen vibrations are summarized in tabular and graphical representations.

  6. Molecular structures and vibrational frequencies of xanthine and its methyl derivatives (caffeine and theobromine) by ab initio Hartree-Fock and density functional theory calculations

    Science.gov (United States)

    Ucun, Fatih; Sağlam, Adnan; Güçlü, Vesile

    2007-06-01

    The molecular structures, vibrational frequencies and corresponding vibrational assignments of xanthine and its methyl derivatives (caffeine and theobromine) have been calculated using ab initio Hartree-Fock (HF) and density functional theory (B3LYP) methods with 6-31G(d, p) basis set level. The calculations were utilized to the CS symmetries of the molecules. The obtained vibrational frequencies and optimised geometric parameters (bond lengths and bond angles) were seen to be well agreement with the experimental data. The used scale factors which have been obtained the ratio of the frequency values of the strongest peaks in the calculated and experimental spectra seem to cause the gained vibrations well corresponding to the experimental ones. Theoretical infrared intensities and Raman activities are also reported.

  7. Natural Frequencies and Modal Damping Ratios Identification of Civil Structures from Ambient Vibration Data

    Directory of Open Access Journals (Sweden)

    Minh-Nghi Ta

    2006-01-01

    Full Text Available Damping is a mechanism that dissipates vibration energy in dynamic systems and plays a key role in dynamic response prediction, vibration control as well as in structural health monitoring during service. In this paper a time domain and a time-scale domain approaches are used for damping estimation of engineering structures, using ambient response data only. The use of tests under ambient vibration is increasingly popular today because they allow to measure the structural response in service. In this paper we consider two engineering structures excited by ambient forces. The first structure is the 310 m tall TV tower recently constructed in the city of Nanjing in China. The second example concerns the Jinma cable-stayed bridge that connects Guangzhou and Zhaoqing in China. It is a single tower, double row cable-stayed bridge supported by 112 stay cables. Ambient vibration of each cable is carried out using accelerometers. From output data only, the modal parameter are extracted using a subspace method and the wavelet transform method.

  8. Vibration-induced displacement using high-frequency resonators and friction layers

    DEFF Research Database (Denmark)

    Thomsen, Jon Juel

    1998-01-01

    A mathematical model is set up to quantify vibration-induced motions of a slider with an imbedded resonator. A simple approximate expression is presented for predicting average velocities of the slider, agreeing fairly well with numerical integration of the full equations of motion. The simple...... expression can be used to the estimate influence of system parameters, and to plan and interpret laboratory experiments....

  9. Molecular order at polymer interfaces measured by broad-bandwidth vibrationally-resolved sum frequency generation spectroscopy.

    Science.gov (United States)

    Wilson, Philip T.; Briggman, Kimberly A.; Stephenson, John C.; Wallace, William E.; Richter, Lee J.

    2001-03-01

    Broad-bandwidth vibrationally-resolved sum frequency generation (VR-SFG)spectroscopy has been used to measure the molecular orientation distribution at polymer/dielectric interfaces. A novel three layer microcavity structure of polystyrene (i.e.,PS)/spin-on hydrogen silsesquioxane dielectric (i.e.,spin-on glass)/Au has been developed in which manipulation of Fresnel factors through the variation of dielectric thickness allows unique spectroscopic study of either the free or buried polymer interface. Chemically specific VR-SFG spectroscopy of the phenyl groups of PS reveals opposite absolute orientations of these groups for the two interfaces, each directed away from the bulk of the PS film.

  10. Binding of Na+ and K+ to the Headgroup of Palmitic Acid Monolayers Studied by Vibrational Sum Frequency Generation Spectroscopy

    Science.gov (United States)

    Huang, Zishuai; Allen, Heather C.

    2012-06-01

    Alkali cations are critical in biological systems due to their electrical interaction with cell membranes. While Na+ and K+ share similar chemical and physical properties, they can exhibit differences when interacting with biological membranes. These phenomena may be modeled using a Langmuir monolayer of surfactant on alkali chloride solutions. Vibrational sum frequency generation (VSFG) spectroscopy is an interface specific technique that is widely employed to study molecular organization at surfaces and interfaces. VSFG spectroscopy was used to probe the CO2- vibrational mode for the carboxylic acid headgroup of palmitic acid (PA) spread on the surface of NaCl and KCl solutions in the vibrational region between 1400 and 1500 cm-1. The ability of Na+ and K+ to bind with the carboxylic headgroup of PA is revealed by observing peak positions (˜1410 cm-1 and ˜1470 cm-1) and relative intensity for the CO2- peaks. These results are compared and discussed with perspective toward elucidating interfacial PA headgroup organization. The time evolution for the PA CO2- peaks is also monitored after monolayer spreading via VSFG and these results are presented as well.

  11. Getting down to the Fundamentals of Hydrogen Bonding: Anharmonic Vibrational Frequencies of (HF)2 and (H2O)2 from Ab Initio Electronic Structure Computations.

    Science.gov (United States)

    Howard, J Coleman; Gray, Jessica L; Hardwick, Amanda J; Nguyen, Linh T; Tschumper, Gregory S

    2014-12-09

    This work presents a systematic investigation into the basis set convergence of harmonic vibrational frequencies of (H2O)2 and (HF)2 computed with second-order Møller-Plesset perturbation theory (MP2) and the coupled-cluster singles and doubles method with perturbative connected triples, CCSD(T), while employing correlation-consistent basis sets as large as aug-cc-pV6Z. The harmonic vibrational frequencies presented here are expected to lie within a few cm(-1) of the complete basis set (CBS) limit. For these important hydrogen-bonding prototype systems, a basis set of at least quadruple-ζ quality augmented with diffuse functions is required to obtain harmonic vibrational frequencies within 10 cm(-1) of the CBS limit. In addition, second-order vibrational perturbation theory (VPT2) anharmonic corrections yield CCSD(T) vibrational frequencies in excellent agreement with experimental spectra, differing by no more than a few cm(-1) for the intramonomer fundamental vibrations. D0 values predicted by CCSD(T) VPT2 computations with a quadruple-ζ basis set reproduce the experimental values of (HF)2 and (H2O)2 to within 2 and 21 cm(-1), respectively.

  12. Quasi-localized low-frequency vibrational modes of disordered solids II. Study by single-molecule spectroscopy

    Science.gov (United States)

    Naumov, A. V.; Vainer, Yu. G.; Bauer, M.; Kador, L.

    2004-12-01

    By means of single molecule (SM) spectroscopy we investigated elementary matrix excitations in a disordered solid, i.e., quasi-localized low-frequency vibrational modes (LFMs). To this end we recorded the spectra of single tetra-tert-butylterrylene molecules embedded in an amorphous polyisobutylene matrix in a temperature region, where the LFM contribution to line broadening dominates. The individual param- eters of LFMs in a polymer glass can be determined from the temperature-dependent linewidths of single molecules. The magnitude of the LFM contribution to SM spectra was obtained by the statistical analysis of the distribution of linewidths of SMs. Pronounced distributions of LFM frequencies and SM-LFM coupling constants were found. This result can be regarded as the first direct experimental proof of the localized nature of LFMs.

  13. Low-Frequency MEMS Electrostatic Vibration Energy Harvester With Corona-Charged Vertical Electrets and Nonlinear Stoppers

    Science.gov (United States)

    Lu, Y.; Cottone, F.; Boisseau, S.; Galayko, D.; Marty, F.; Basset, P.

    2015-12-01

    This paper reports for the first time a MEMS electrostatic vibration energy harvester (e-VEH) with corona-charged vertical electrets on its electrodes. The bandwidth of the 1-cm2 device is extended in low and high frequencies by nonlinear elastic stoppers. With a bias voltage of 46 V (electret@21 V + DC external source@25 V) between the electrodes, the RMS power of the device reaches 0.89 μW at 33 Hz and 6.6 μW at 428 Hz. The -3dB frequency band including the hysteresis is 223∼432 Hz, the one excluding the hysteresis 88∼166 Hz. We also demonstrate the charging of a 47 μF capacitor used for powering a wireless and autonomous temperature sensor node with a data transmission beyond 10 m at 868 MHz.

  14. N-H stretching modes around 3300 wavenumber from peptide backbones observed by chiral sum frequency generation vibrational spectroscopy.

    Science.gov (United States)

    Fu, Li; Wang, Zhuguang; Yan, Elsa C Y

    2014-09-01

    We present a detailed analysis of the molecular origin of the chiral sum frequency generation (SFG) signals of proteins and peptides at interfaces in the N-H stretching vibrational region. The N-H stretching can be a probe for investigating structural and functional properties of proteins, but remains technically difficult to analyze due to the overlapping with the O-H stretching of water molecules. Chiral SFG spectroscopy offers unique tools to study the N-H stretching from proteins at interfaces without interference from the water background. However, the molecular origin of the N-H stretching signals of proteins is still unclear. This work provides a justification of the origin of chiral N-H signals by analyzing the vibrational frequencies, examining chiral SFG theory, studying proton (hydrogen/deuterium) exchange kinetics, and performing optical control experiments. The results demonstrate that the chiral N-H stretching signals at ~3300 cm(-1) originate from the amide group of the protein backbones. This chiral N-H stretching signal offers an in situ, real-time, and background-free probe for interrogating the protein structures and dynamics at interfaces at the molecular level.

  15. High-frequency vibration energy harvesting from impulsive excitation utilizing intentional dynamic instability caused by strong nonlinearity

    Science.gov (United States)

    Remick, Kevin; Dane Quinn, D.; Michael McFarland, D.; Bergman, Lawrence; Vakakis, Alexander

    2016-05-01

    The authors investigate a vibration-based energy harvesting system utilizing essential (nonlinearizable) nonlinearities and electromagnetic coupling elements. The system consists of a grounded, weakly damped linear oscillator (primary system) subjected to a single impulsive load. This primary system is coupled to a lightweight, damped oscillating attachment (denoted as nonlinear energy sink, NES) via a neodymium magnet and an inductance coil, and a piano wire, which generates an essential geometric cubic stiffness nonlinearity. Under impulsive input, the transient damped dynamics of this system exhibit transient resonance captures (TRCs) causing intentional large-amplitude and high-frequency instabilities in the response of the NES. These TRCs result in strong energy transfer from the directly excited primary system to the light-weight attachment. The energy is harvested by the electromagnetic elements in the coupling and, in the present case, dissipated in a resistive element in the electrical circuit. The primary goal of this work is to numerically, analytically, and experimentally demonstrate the efficacy of employing this type of intentional high-frequency dynamic instability to achieve enhanced vibration energy harvesting under impulsive excitation.

  16. Myocardial contractile depression from high-frequency vibration is not due to increased cross-bridge breakage.

    Science.gov (United States)

    Campbell, K B; Wu, Y; Kirkpatrick, R D; Slinker, B K

    1998-04-01

    Experiments were conducted in 10 isolated rabbit hearts at 25 degrees C to test the hypothesis that vibration-induced depression of myocardial contractile function was the result of increased cross-bridge breakage. Small-amplitude sinusoidal changes in left ventricular volume were administered at frequencies of 25, 50, and 76.9 Hz. The resulting pressure response consisted of a depressive response [delta Pd(t), a sustained decrease in pressure that was not at the perturbation frequency] and an infrequency response [delta Pf(t), that part at the perturbation frequency]. delta Pd(t) represented the effects of contractile depression. A cross-bridge model was applied to delta Pf(t) to estimate cross-bridge cycling parameters. Responses were obtained during Ca2+ activation and during Sr2+ activation when the time course of pressure development was slowed by a factor of 3. delta Pd(t) was strongly affected by whether the responses were activated by Ca2+ or by Sr2+. In the Sr(2+)-activated state, delta Pd(t) declined while pressure was rising and relaxation rate decreased. During Ca2+ and Sr2+ activation, velocity of myofilament sliding was insignificant as a predictor of delta Pd(t) or, when it was significant, participated by reducing delta Pd(t) rather than contributing to its magnitude. Furthermore, there was no difference in cross-bridge cycling rate constants when the Ca(2+)-activated state was compared with the Sr(2+)-activated state. An increase in cross-bridge detachment rate constant with volume-induced change in cross-bridge distortion could not be detected. Finally, processes responsible for delta Pd(t) occurred at slower frequencies than those of cross-bridge detachment. Collectively, these results argue against a cross-bridge detachment basis for vibration-induced myocardial depression.

  17. Research of automatic control system for uitralow frequency vibration calibration%超低频振动校准自动控制系统的研究

    Institute of Scientific and Technical Information of China (English)

    王志鹏; 何闻; 于梅; 沈润杰

    2011-01-01

    针对超低频振动校准过程中测试时间长且效率较低的问题,设计了一种基于个人计算机及虚拟仪器技术开发的超低频振动校准自动控制系统.该系统由超低频标准振动台、功率放大器、激光测振仪、位移传感器、信号发生器、频比计数器、数据采集卡、计算机与测控软件等组成.通过线性逼近与逐步移频相结合的算法,精确控制振动台在超低频时迅速到达设定振级.试验结果证明该系统满足超低频振动校准要求,提高了超低频振动传感器的测试精度和自动化程度.%Aiming at the demerits of time-consuming and low efficiency during the process of ultralow frequency vibration calibration, an automatic ultralow frequency vibration calibration system based on personal computer and virtual instrument was presented.The system was consisted of ultralow frequency standard vibrator, power amplifier, laser vibrometer, displacement transducer, signal generator, universal counter, data acquisition card, computer, control software, etc..The strategy which via combining the method of linear approximation and stepby-step frequency shift could make the vibrator reach the pre-set vibration level quickly and precisely.The experiment results show that the system is suitable for the calibrating ultralow frequency vibration transducers very well and improves the automation of ultralow frequency calibrating vibration.

  18. Relationship between the shape and density distribution of the femur and its natural frequencies of vibration.

    Science.gov (United States)

    Campoli, G; Baka, N; Kaptein, B L; Valstar, E R; Zachow, S; Weinans, H; Zadpoor, A A

    2014-10-17

    It has been recently suggested that mechanical loads applied at frequencies close to the natural frequencies of bone could enhance bone apposition due to the resonance phenomenon. Other applications of bone modal analysis are also suggested. For the above-mentioned applications, it is important to understand how patient-specific bone shape and density distribution influence the natural frequencies of bones. We used finite element models to study the effects of bone shape and density distribution on the natural frequencies of the femur in free boundary conditions. A statistical shape and appearance model that describes shape and density distribution independently was created, based on a training set of 27 femora. The natural frequencies were then calculated for different shape modes varied around the mean shape while keeping the mean density distribution, for different appearance modes around the mean density distribution while keeping the mean bone shape, and for the 27 training femora. Single shape or appearance modes could cause up to 15% variations in the natural frequencies with certain modes having the greatest impact. For the actual femora, shape and density distribution changed the natural frequencies by up to 38%. First appearance mode that describes the general cortical bone thickness and trabecular bone density had one of the strongest impacts. The first appearance mode could therefore provide a sensitive measure of general bone health and disease progression. Since shape and density could cause large variations in the calculated natural frequencies, patient-specific FE models are needed for accurate estimation of bone natural frequencies.

  19. A study on the contribution of body vibrations to the vibratory sensation induced by high-level, complex low-frequency noise

    Directory of Open Access Journals (Sweden)

    Yukio Takahashi

    2011-01-01

    Full Text Available To investigate the contribution of body vibrations to the vibratory sensation induced by high-level, complex low-frequency noise, we conducted two experiments. In Experiment 1, eight male subjects were exposed to seven types of low-frequency noise stimuli: two pure tones [a 31.5-Hz, 100-dB(SPL tone and a 50-Hz, 100-dB(SPL tone] and five complex noises composed of the pure tones. For the complex noise stimuli, the sound pressure level of one tonal component was 100 dB(SPL and that of another one was either 90, 95, or 100 dB(SPL. Vibration induced on the body surface was measured at five locations, and the correlation with the subjective rating of the vibratory sensation at each site of measurement was examined. In Experiment 2, the correlation between the body surface vibration and the vibratory sensation was similarly examined using seven types of noise stimuli composed of a 25-Hz tone and a 50-Hz tone. In both the experiments, we found that at the chest and the abdomen, the rating of the vibratory sensation was in close correlation with the vibration acceleration level (VAL of the body surface vibration measured at each corresponding location. This was consistent with our previous results and suggested that at the trunk of the body (the chest and the abdomen, the mechanoreception of body vibrations plays an important role in the experience of the vibratory sensation in persons exposed to high-level low-frequency noise. At the head, however, no close correlation was found between the rating of the vibratory sensation and the VAL of body surface vibration. This suggested that at the head, the perceptual mechanisms of vibration induced by high-level low-frequency noise were different from those in the trunk of the body.

  20. Low-amplitude high frequency vibration down-regulates myostatin and atrogin-1 expression, two components of the atrophy pathway in muscle cells.

    Science.gov (United States)

    Ceccarelli, Gabriele; Benedetti, Laura; Galli, Daniela; Prè, Deborah; Silvani, Giulia; Crosetto, Nicola; Magenes, Giovanni; Cusella De Angelis, Maria Gabriella

    2014-05-01

    Whole body vibration (WBV) is a very widespread mechanical stimulus used in physical therapy, rehabilitation and fitness centres. It has been demonstrated that vibration induces improvements in muscular strength and performance and increases bone density. We investigated the effects of low-amplitude, high frequency vibration (HFV) at the cellular and tissue levels in muscle. We developed a system to produce vibrations adapted to test several parameters in vitro and in vivo. For in vivo experiments, we used newborn CD1 wild-type mice, for in vitro experiments, we isolated satellite cells from 6-day-old CD1 mice, while for proliferation studies, we used murine cell lines. Animals and cells were treated with high frequency vibration at 30 Hz. We analyzed the effects of mechanical stimulation on muscle hypertrophy/atrophy pathways, fusion enhancement of myoblast cells and modifications in the proliferation rate of cells. Results demonstrated that mechanical vibration strongly down-regulates atrophy genes both in vivo and in vitro. The in vitro experiments indicated that mechanical stimulation promotes fusion of satellite cells treated directly in culture compared to controls. Finally, proliferation experiments indicated that stimulated cells had a decreased growth rate compared to controls. We concluded that vibration treatment at 30 Hz is effective in suppressing the atrophy pathway both in vivo and in vitro and enhances fusion of satellite muscle cells.

  1. Natural vibration frequency and damping of slender structures founded on monopiles

    DEFF Research Database (Denmark)

    Zania, Varvara

    2014-01-01

    Offshore wind turbine (OWT) is a typical example of a slender engineering structure founded on large diameter rigid piles (monopiles). The natural vibration characteristics of these structures are of primary interest since the dominant loading conditions are dynamic. A rigorous analytical solution...... of the modified SSI eigenfrequency and damping is presented, which accounts for the cross coupling stiffness and damping terms of the soil–pile system and is applicable but not restrictive to OWTs. A parametric study was performed to illustrate the sensitivity of the eigenfrequency and damping on the foundation...

  2. The Effects of Vibration Frequencies on Physical, Perceptual and Cognitive Performance

    Science.gov (United States)

    2006-10-01

    vibratoire à partir de laquelle le rendement commence à décroître. Notre examen des études de rendement s’intéresse principalement à l’incidence des...performance on simple mental tasks. Studies that involved only mental addition as the task and only vibration as the stressor did not show any...performance decrement; however, performance decrements were shown in studies that used a combined task (e.g., mental addition and memory) or a combined

  3. Studies of pressure oscillations in a research dump combustor. [low frequency vibration effect

    Science.gov (United States)

    Schadow, K. C.; Crump, J. E.; Derr, R. L.; Heaser, J. S.

    1980-01-01

    A coaxial research dump combustor was used to investigate the acoustic modes structure and its effect on the inlet shock system. Acoustic wave structure was determined including the amplitude, frequency, and phase as a function of position. Inlet shock position, shock displacement, shock displacement frequency, and phase relative to acoustic wave structure were also defined. All results were compared to with one dimensional modeling.

  4. Ultra-low vibration pulse-tube cryocooler stabilized cryogenic sapphire oscillator with 10^-16 fractional frequency stability

    CERN Document Server

    Hartnett, John G

    2010-01-01

    A low maintenance long-term operational cryogenic sapphire oscillator has been implemented at 11.2 GHz using an ultra-low-vibration cryostat and pulse-tube cryocooler. It is currently the world's most stable microwave oscillator employing a cryocooler. Its performance is explained in terms of temperature and frequency stability. The phase noise and the Allan deviation of frequency fluctuations have been evaluated by comparing it to an ultra-stable liquid-helium cooled cryogenic sapphire oscillator in the same laboratory. Assuming both contribute equally, the Allan deviation evaluated for the cryocooled oscillator is sigma_y = 1 x 10^-15 tau^-1/2 for integration times 1 < tau < 10 s with a minimum sigma_y = 3.9 x 10^-16 at tau = 20 s. The long term frequency drift is less than 5 x 10^-14/day. From the measured power spectral density of phase fluctuations the single side band phase noise can be represented by L_phi(f) = 10^-14.0/f^4+10^-11.6/f^3+10^-10.0/f^2+10^-10.2/f+ 10^-11.0 for Fourier frequencies 10...

  5. Matrix effect on vibrational frequencies: experiments and simulations for HCl and HNgCl (Ng = Kr and Xe).

    Science.gov (United States)

    Kalinowski, Jaroslaw; Gerber, R Benny; Räsänen, Markku; Lignell, Antti; Khriachtchev, Leonid

    2014-03-01

    We study the environmental effect on molecules embedded in noble-gas (Ng) matrices. The experimental data on HXeCl and HKrCl in Ng matrices is enriched. As a result, the H-Xe stretching bands of HXeCl are now known in four Ng matrices (Ne, Ar, Kr, and Xe), and HKrCl is now known in Ar and Kr matrices. The order of the H-Xe stretching frequencies of HXeCl in different matrices is ν(Ne) Kr) Kr) Kr stretching frequencies of HKrCl is consistently ν(Kr) < ν(Ar). These matrix effects are analyzed theoretically by using a number of quantum chemical methods. The calculations on these molecules (HCl, HXeCl, and HKrCl) embedded in single Ng(') layer cages lead to very satisfactory results with respect to the relative matrix shifts in the case of the MP4(SDQ) method whereas the B3LYP-D and MP2 methods fail to fully reproduce these experimental results. The obtained order of frequencies is discussed in terms of the size available for the Ng hydrides in the cages, probably leading to different stresses on the embedded molecule. Taking into account vibrational anharmonicity produces a good agreement of the MP4(SDQ) frequencies of HCl and HXeCl with the experimental values in different matrices. This work also highlights a number of open questions in the field.

  6. Design, Simulation, and Optimization of a Frequency-Tunable Vibration Energy Harvester That Uses a Magnetorheological Elastomer

    Directory of Open Access Journals (Sweden)

    Wan Sun

    2015-01-01

    Full Text Available This study focuses on the design, simulation, and load power optimization for the development of a novel frequency-tunable electromagnetic vibrational energy harvester. The unique characteristic of a magnetorheological elastomer (MRE is utilized, that the shear modulus can be varied by changing the strength of an applied magnetic field. The electromagnetic energy harvester is fabricated, the external electric circuit is connected, and the performance is evaluated through a series of experiments. The resonant frequencies and the parasitic damping constant are measured experimentally for different tuning magnet gap distances, which validate the application of the MRE to the development of a frequency-tunable energy harvesting system. The harvested energy of the system is measured by the voltage across the load resistor. The maximum load power is attained by optimizing the external circuit connected to the coil system. The analysis results are presented for harvesting the maximum load power in terms of the coil parameters and external circuit resistance. The optimality of the load resistance is validated by comparing the analytical results with experimental results. The optimal load resistances under various resonance frequencies are also found for the design and composition of the optimal energy harvesting circuit of the energy harvester system.

  7. [Characteristic vibration analysis of M-RNA nucleic acid bases complexes (M = Ca+ and Mg+) by DFT].

    Science.gov (United States)

    Zhang, Xing-Chu; Hu, Yi-Hua; Wang, Xiao-Juan

    2009-01-01

    A density functional investigation of the interaction between calcium and magnesium univalent cations and RNA pyrimidine base (cytosine, thymine and uracil) was performed to determine geometric coordinates and free energies for all possible stable isomers at B3LYP/6-311 + G (2df, 2p) level. The most stable isomers C1M, T1M and U1M (M = Ca+ and Mg+) with the lowest free energy among the same pyrimidine base tautomers were calculated to determine the characters of infrared vibrations. According to the results, two characteristic infrared vibrations at wave numbers 1,684 and 1,765 cm(-1) were found for single pyrimidine base C1, at 1,747 and 1,792 cm(-1) for T1, 1,763 and at 1,796 cm(-1) for U1. In addition, spectrum shifts were found when the cations interact with the pyrimidine base tautomers. For deeper analysis, we found that when the stable complexes are formed, the cations are prone to act on the oxygen atoms, and cause the vibrational frequencies to change, the spectral lines belonging to the vibration of C--O--M turn out to redshift and the others turn out to blueshift. When the stable complex C1M is formed, the characteristic infrared vibration at 1,684 cm(-1) mainly caused by the ring's vibration turns out to blueshift about 10 cm(-1), and the another characteristic vibration of 1,765 cm(-1) caused by vibration of bond C--O with oxygen atom acting on cations directly turns out to redshift by 112 cm(-1) for complex C1Ca+ and by 110 cm(-1) for C1Mg+. When the stable complexes T1M are formed, the characteristic vibration of bond C--O--M turns out to redshift about 130 cm(-1) and the vibration of bond C--O turns out to blueshift about 55 cm(-1). When the stable complexes U1M are formed, the vibration of bond C--O--M turns out to redshift about 90 cm(-1) and about 50 cm(-1) for another C--O. The characteristic infrared vibration frequencies are changed obviously when tautomers act on the cations, which is mainly because cations take part in molecule's vibrations

  8. Relationship of the vibrational frequency of the uranyl ion with the uranium electronegativity; Relacion de la frecuencia vibracional del ion uranilo con la electronegatividad del uranio

    Energy Technology Data Exchange (ETDEWEB)

    Rodriguez S, A.; Martinez Q, E

    1990-07-15

    It has been demonstrated that the vibrational asymmetric frequency of the uranyl ion, it experiences a consistent spectrochemical displacement with the variations of electronegativity of the uranium in their complexes. The values of the electronegativity of the uranium they were dear by means of calculations that it involves measures of those lengths of the connection uranium-oxygen, obtained by vibrational spectroscopy, effective nuclear charges and the Allred and Rochow equation. The results show the evidence of a natural order that relates to the vibrational frequency with the electronegativity of the uranium atom; settling down that if the electronegativity is graph against it bond length to the oxygen or to it frequency value, a simple relationship is obtained as a form to obtain clear responses in absence of complementary information. (Author)

  9. O modelo AM1 na previsão de frequências vibracionais The vibration frequencies predicted by the AM1 model

    Directory of Open Access Journals (Sweden)

    João Carlos Silva Ramos

    1999-09-01

    Full Text Available We analyse vibrational frequencies of 168 compounds with the AM1 model concerning its experimentally observed gaseous frequencies. Stretching of CH, NH, OH and CO bonds, its related bending frequencies, and the CC frame movements are the studied vibrations. The results show problems with the AM1 vibrational splittings. Often symmetric stretching frequencies, like in CH3, CH2 and NH3, appear switched with the corresponding antisymmetrical ones. Among the studied vibrations many stretchings are overestimated, while bendings oscillate around experimental values. Fluorine stretchings, NN, OO, CH, double and triples CC bonds and cyclic hydrocarbon breathing modes are always overestimated while torsions, umbrella modes and OH/SH stretching are, in average, underestimated. Graphical analysis show that compounds with the lowest molecular masses are the ones with the largest difference to the experimental values. From our results it is not possible to fit confortably the calculated frequencies by a simple linear relationship of the type, n(obs=a*n(AM1. Better aggreement is obtained when different curves are adjusted for the stretching and bending modes, and when a complete linear function is used. Among our studies the best obtained statistical results are for CH, NH and OH. The conclusions obtained in this work will improve the AM1 calculated frequencies leading to accurate results for these properties.

  10. Effect of frequency and amplitude of vibration and role of a surfactant on void formation in models poured from polyvinyl siloxane impressions

    Directory of Open Access Journals (Sweden)

    N Kulashekar Reddy

    2011-01-01

    Full Text Available Aims : To determine whether the frequency and amplitude of vibration and the use of surfactant has any effect on the formation of voids on the cast surface, poured from a polyvinyl siloxane impression material, using a mechanical model vibrator. Materials and Methods : A total of 100 impressions of a master die were made using Reprosil, Type 1, Medium Viscosity, Regular body, and Dentsply Caulk. The test group was subdivided into a surfactant and non-surfactant group, 50 impressions each. The impressions were poured in a dental stone with a mechanical model vibrator that was set at a vibration frequency of 3000 cycles / minute (low and 6000 cycles / minute (high with the help of a knob. The resultant casts were examined with a Stereomicroscope (LABOMED CZM4 under x10 magnifications. Results : For the low and high frequencies, when surfactant and non-surfactant groups were compared, for all the amplitudes and for both the material groups, the surfactant groups resulted in fewer void formations and showed very high statistical significance (P-value = 0.001. Conclusions : The lowest mean voids were obtained for high frequency surfactant groups. Reprosil: High frequency amplitude 2 being the most prominent, produced the least mean voids (mean = 23.2000, P = 0.001, very highly significant. In comparison, the surfactant groups produced the least voids for both frequencies.

  11. Analysis of methods for calculating the transition frequencies of the torsional vibration of acrolein isomers in the ground ( S 0) electronic state

    Science.gov (United States)

    Koroleva, L. A.; Tyulin, V. I.; Matveev, V. K.; Pentin, Yu. A.

    2013-05-01

    B3LYP, MP2, CCSD(T), and MP4/MP2 in the 6-311G( d, p), 6-311++G( d, p), cc-pVTZ, aug-cc-pVTZ bases used to calculate the transition frequencies of torsional vibration of trans- and cis-isomers of acrolein in the ground electronic state ( S 0) are analyzed. It is found that for trans-isomers, all methods of calculation except for B3LYP in the cc-pVTZ basis yield good agreement between the calculated and experimental values. It is noted that for the cis-isomer of acrolein, no method of calculation confirms the experimental value of the frequency of torsional vibration (138 cm-1). It is shown that the calculated and experimental values for obertones at 273.0 cm-1 and other transitions of torsional vibration are different for this isomer in particular. However, it is established that in some calculation methods (B3LYP, MP2), the frequency of the torsional vibration of the cis-isomer coincides with another experimental value of this frequency (166.5 cm-1). It is concluded that in analyzing the vibrational structure of the UV spectrum, the calculated and experimental values of its obertone (331.3 cm-1) coincide, along with its frequency. It is also noted that the frequency of torsional vibration for the cis-isomer (166.5 cm-1) can also be found in other experimental works if we change the allocation of torsional transition 18{1/1}.

  12. Sum Frequency Generation Vibrational Spectroscopy of Adsorbed Amino Acids, Peptides and Proteins of Hydrophilic and Hydrophobic Solid-Water Interfaces

    Energy Technology Data Exchange (ETDEWEB)

    Holinga IV, George Joseph [Univ. of California, Berkeley, CA (United States)

    2010-09-01

    Sum frequency generation (SFG) vibrational spectroscopy was used to investigate the interfacial properties of several amino acids, peptides, and proteins adsorbed at the hydrophilic polystyrene solid-liquid and the hydrophobic silica solid-liquid interfaces. The influence of experimental geometry on the sensitivity and resolution of the SFG vibrational spectroscopy technique was investigated both theoretically and experimentally. SFG was implemented to investigate the adsorption and organization of eight individual amino acids at model hydrophilic and hydrophobic surfaces under physiological conditions. Biointerface studies were conducted using a combination of SFG and quartz crystal microbalance (QCM) comparing the interfacial structure and concentration of two amino acids and their corresponding homopeptides at two model liquid-solid interfaces as a function of their concentration in aqueous solutions. The influence of temperature, concentration, equilibration time, and electrical bias on the extent of adsorption and interfacial structure of biomolecules were explored at the liquid-solid interface via QCM and SFG. QCM was utilized to quantify the biological activity of heparin functionalized surfaces. A novel optical parametric amplifier was developed and utilized in SFG experiments to investigate the secondary structure of an adsorbed model peptide at the solid-liquid interface.

  13. Effect of magnet/slot combination on triple-frequency magnetic force and vibration of permanent magnet motors

    Science.gov (United States)

    Huo, Mina; Wang, Shiyu; Xiu, Jie; Cao, Shuqian

    2013-10-01

    The relationship between magnet/slot combination and magnetic forces including unbalanced magnetic force (UMF) and cogging torque (CT) of permanent magnet (PM) motors is investigated by using superposition principle and mechanical and magnetic symmetries. The results show that magnetic force can be produced by all magnets passing a single slot, by all slots passing a single magnet, or by eccentricity, which respectively correspond to three frequency components. The results further show that net force/torque can be classified into three typical cases: UMF is suppressed and CT is excited, UMF excited and CT suppressed, and UMF and CT both suppressed, and consequently possible vibrations include three unique groups: rotational modes, translational modes, and balanced modes. The conclusion that combinations with the greatest common divisor (GCD) greater than unity can avoid UMF is mathematically verified, and at the same time lower CT harmonics are preliminarily addressed by the typical excitations. The above findings can create simple guidelines for the suppression of certain UMF and/or CT by using suitable combinations, which in turn can present approach to yield a more desirable response in high performance applications. The superposition effect and predicted relationship are verified by the transient magnetic Finite Element method. Since this work is motivated by symmetries, comparisons are made in order to give further insight into the inner force and vibration behaviors of general rotary power-transmission systems.

  14. Interfacial Water Structure in Langmuir Monolayer and Gibbs Layer Probed by Sum Frequency Generation Vibrational Spectroscopy

    Institute of Scientific and Technical Information of China (English)

    张贞; 郭源

    2012-01-01

    Langmuir monolayer and Gibbs layer exhibit surface-active properties and it can be used as simple model systems to investigate the physicochemical properties of biological membranes. In this report, we presented the OH stretching vibration of H2O in the 4"-n-pentyl-4-cyano-p-terphenyl (5CT), nonadecanenitrile (C18CN) Langmuir monolayer and compared them with CH3CN Gibbs layer at the air/water interface with polarization SFG-VS. This study demonstrated that the hydrogen bond network is different in the Langmuir monolayer of 5CT, C18CN from CH3CN Gibbs layer at the air/water interface which showed two different water structures on the different surface layer. The results provided a deeper insight into understanding the hydrogen bond on the interfaces.

  15. Variation of CH Stretch Frequencies with CH_4 Orientation in the CH_4 - F^- Complex: Multiple Resonances as Vibrational Conical Intersections

    Science.gov (United States)

    Thapaliya, Bishnu P.; Perry, David S.

    2016-06-01

    In the CH_4 - F^- complex, an adiabatic separation of the CH stretch frequencies from the CH_4 orientational coordinates allows the calculation of the four adiabatic CH stretch surfaces. These ab initio calculations reveal (i) a large variation of CH stretch frequencies (> 100 wn) in the orientational space and (ii) the existence of four symmetrically equivalent sets of vibrational conical intersections (CIs). Two sets of symmetry-allowed CIs are identified in addition to the symmetry-required CIs at the front- and back-side C3v geometries. These results have implications for the evolution of excited CH vibrations in methane during its approach to a potentially reactive surface.

  16. Benchmark Calculations on the Atomization Enthalpy,Geometry and Vibrational Frequencies of UF6 with Relativistic DFT Methods

    Institute of Scientific and Technical Information of China (English)

    XIAO Hai; LI Jun

    2008-01-01

    Benchmark calculations on the molar atomization enthalpy, geometry, and vibrational frequencies of uranium hexafluoride (UF6) have been performed by using relativistic density functional theory (DFT) with various levels of relativistic effects, different types of basis sets, and exchange-correlation functionals. Scalar relativistic effects are shown to be critical for the structural properties. The spin-orbit coupling effects are important for the calculated energies, but are much less important for other calculated ground-state properties of closed-shell UF6. We conclude through systematic investigations that ZORA- and RECP-based relativistic DFT methods are both appropriate for incorporating relativistic effects. Comparisons of different types of basis sets (Slater, Gaussian, and plane-wave types) and various levels of theoretical approximation of the exchange-correlation functionals were also made.

  17. Redshift and blueshift of the Ar-H vibrational stretching frequency in complexes of FArH and acetylene.

    Science.gov (United States)

    McDowell, Sean A C

    2005-05-22

    Two planar hydrogen-bonded complexes of FArH and acetylene were found to be stable using second-order Møller-Plesset perturbation theory (MP2) with 6-311++G(2d,2p) basis sets. The more stable complex involves bonding between the F atom of FArH and a H atom of acetylene, while the other isomer is a T-shaped complex with the H atom of FArH bonded to the center of the CC bond of acetylene; the zero-point energy corrected dissociation energies are 29 and 27 kJ mol(-1), respectively. Interestingly, the Ar-H harmonic vibrational stretching frequency is blueshifted in the more stable isomer and redshifted in the less stable form. The electron density rearrangement of FArH on complexation was investigated and used to explain these unusual findings.

  18. Using strong nonlinearity and high-frequency vibrations to control effective mechanical stiffness

    DEFF Research Database (Denmark)

    Thomsen, Jon Juel

    2008-01-01

    High-frequency excitation (HFE) can be used to change the effective stiffness of an elastic structure, and related quanti-ties such as resonance frequencies, wave speed, buckling loads, and equilibrium states. There are basically two ways to do this: By using parametrical HFE (with or without non...... the method of direct separation of motions with results of a modified multiple scales ap-proach, valid also for strong nonlinearity, the stiffening ef-fect is predicted for a generic 1-dof system, and results are tested against numerical simulation and ((it is planned)) laboratory experiments....

  19. Low-frequency, low-magnitude vibrations (LFLM enhances chondrogenic differentiation potential of human adipose derived mesenchymal stromal stem cells (hASCs

    Directory of Open Access Journals (Sweden)

    Krzysztof Marycz

    2016-02-01

    Full Text Available The aim of this study was to evaluate if low-frequency, low-magnitude vibrations (LFLM could enhance chondrogenic differentiation potential of human adipose derived mesenchymal stem cells (hASCs with simultaneous inhibition of their adipogenic properties for biomedical purposes. We developed a prototype device that induces low-magnitude (0.3 g low-frequency vibrations with the following frequencies: 25, 35 and 45 Hz. Afterwards, we used human adipose derived mesenchymal stem cell (hASCS, to investigate their cellular response to the mechanical signals. We have also evaluated hASCs morphological and proliferative activity changes in response to each frequency. Induction of chondrogenesis in hASCs, under the influence of a 35 Hz signal leads to most effective and stable cartilaginous tissue formation through highest secretion of Bone Morphogenetic Protein 2 (BMP-2, and Collagen type II, with low concentration of Collagen type I. These results correlated well with appropriate gene expression level. Simultaneously, we observed significant up-regulation of α3, α4, β1 and β3 integrins in chondroblast progenitor cells treated with 35 Hz vibrations, as well as Sox-9. Interestingly, we noticed that application of 35 Hz frequencies significantly inhibited adipogenesis of hASCs. The obtained results suggest that application of LFLM vibrations together with stem cell therapy might be a promising tool in cartilage regeneration.

  20. Topology Optimization of Distributed Mass Dampers for Low-frequency Vibration Suppression

    DEFF Research Database (Denmark)

    Jensen, Jakob Søndergaard; Lazarov, Boyan Stefanov

    2007-01-01

    In this paper the method of topology optimization is used to find optimized parameter distributions for a multiple mass damper system with the purpose of minimizing the low-frequency steady-state response of a carrier structure. An effective density model that describes the steady-state effect...

  1. Using strong nonlinearity and high-frequency vibrations to control effective properties of discrete elastic waveguides

    DEFF Research Database (Denmark)

    Lazarov, Boyan Stefanov; Thomsen, Jon Juel; Snaeland, Sveinn Orri

    2008-01-01

    The aim of this article is to investigate how highfrequency (HF) excitation, combined with strong nonlinear elastic material behavior, influences the effective material or structural properties for low-frequency excitation and wave propagation. The HF effects are demonstrated on discrete linear...

  2. Vibrational power flow and structural intensity: Measurements and limitations at low frequencies

    DEFF Research Database (Denmark)

    Ohlrich, Mogens

    1991-01-01

    The cross-spectral methods and their sensitivity to phase errors are investigated for the two and four-accelerometer arrays. From experiments on a beam structure it is attempted to verify the influence of phase errors and to determine the usable frequency ranges of the two methods. Measurements a...

  3. Analysis of the dominant vibration frequencies of rail bridges for structure-borne noise using a power flow method

    Science.gov (United States)

    Li, Q.; Wu, D. J.

    2013-09-01

    The use of concrete bridges in urban rail transit systems has raised many concerns regarding low-frequency (20-200 Hz) structure-borne noise due to the vibration of bridges when subjected to moving trains. Understanding the mechanism that determines the dominant frequencies of bridge vibrations is essential for both vibration and noise reduction. This paper presents a general procedure based on the force method to obtain the power flows within a coupled vehicle-track-bridge system, the point mobility of the system and the dynamic interaction forces connecting various components. The general coupling system consists of multi-rigid-bodies for the vehicles, infinite Euler beams representing the rails, two-dimensional or three-dimensional elements of the concrete bridges, and spring-dashpot pairs to model the wheel-rail contacts, the vehicle suspensions, the rail pads and the bridge bearings. The dynamic interaction of the coupled system is solved in the frequency domain by assuming the combined wheel-rail roughness moves forward relative to the stationary vehicles. The proposed procedure is first applied to a rail on discrete supports and then to a real urban rail transit U-shaped concrete bridge. The computed results show that the wheel-rail contact forces, the power flows to the rail/bridge subsystem and the accelerations of the bridge are primarily dominated by the contents around the natural frequency of a single wheel adhered to the elastically supported rail. If the ath node of the mth spring-dashpot pair and the bth node of the nth spring-dashpot pair are connected to the same rigid body, then δmnab(ω) can be expressed as δmnab(ω)=-{(}/{Mlω}, where Ml is the mass of the lth rigid body. If the ath node of the mth spring-dashpot pair and the bth node of the nth spring-dashpot pair are connected to the same infinite rail, δmnab(ω) can be expressed as [8] δmnab(ω)=-j{((e-je)}/{4EIk}, where xm and xn are the x-coordinates of the mth and nth spring

  4. Intramolecular interactions, isomerization and vibrational frequencies of two paracetamol analogues: A spectroscopic and a computational approach

    Science.gov (United States)

    Viana, Rommel B.; Ribeiro, Gabriela L. O.; Santos, Sinara F. F.; Quintero, David E.; Viana, Anderson B.; da Silva, Albérico B. F.; Moreno-Fuquen, Rodolfo

    2016-06-01

    The aim of this investigation was to determine the molecular properties and provide an interpretation of the vibrational mode couplings of these two paracetamol analogues: 2-bromo-2-methyl-N-(4-nitrophenyl)-propanamide and 2-bromo-2-methyl-N-p-tolyl-propanamide. E/Z isomers, keto/enol unimolecular rearrangement and prediction of the transition state structures in each mechanism were also assessed using the Density Functional Theory (DFT). The DFT estimates a high energy gap between E and Z isomers (9-11 kcal·mol- 1), with barrier heights ranging from 16 to 19 kcal·mol- 1. In contrast, the barrier energies on the keto/enol isomerization are almost 10 kcal·mol- 1 higher than those estimated for the E/Z rearrangement. The kinetic rate constant was also determined for each reaction mechanism. Natural bond orbital analysis and the quantum theory of atoms in molecules were used to interpret the intramolecular hydrogen bonds and to understand the most important interactions that govern the stabilization of each isomer. Furthermore, an analysis of the atomic charge distribution using different population methodologies was also performed.

  5. Linear- and nonlinear-electromyographic analysis of supracutaneous vibration stimuli of the forearm using diverse frequencies and considering skin physiological properties.

    Science.gov (United States)

    Ko, Chang-Yong; Chang, Yunhee; Kim, Sol-Bi; Kim, Shinki; Kim, Gyoosuk; Ryu, Jeicheong; Mun, Musung

    2014-01-01

    Numerous studies have reported the efficacy of vibration in sensory feedback or substitution devices for users of myoelectric hand prostheses. Although most myoelectric hand prostheses are presently manipulated by a surface electromyogram (sEMG), only a few studies have been conducted on the effect of vibration on an sEMG. This study aimed to determine whether vibration stimulation affects the linear and nonlinear properties of surface electromyography (sEMG) considering the skin properties. The vibration stimuli, with frequencies ranging from 37 to 258 Hz, were applied to the proximal part of the arms of the eight female and seven male subjects. The skinfold thickness, hardness, and vibration threshold at the stimuli loci were measured. The root mean square (rms) and fractal dimension (DF) of the sEMG were measured at a distance of 1 cm in the upward direction from the stimuli loci. Above 223 Hz there were no differences between the rms of the genders in between the vibration stimuli (p > 0.05). Moreover, no differences were observed between the DF of the genders for any frequency (p > 0.05). Above 149 Hz, there were correlations between the rms and the skin hardness in the females. Otherwise, no correlations were observed between the rms and DF and the skin properties in both genders for most of the frequencies (all p > 0.05). These results suggest that vibration stimuli affect the linear properties of the sEMG, but not the nonlinear properties.

  6. Vibrating Ground Target Detection and Feature Extraction of One-stationary Bistatic Frequency-modulated Continuous-wave Synthetic Aperture Radar

    Directory of Open Access Journals (Sweden)

    Liang Ying

    2015-12-01

    Full Text Available One of the unique characteristics of a ground target is its micro-motion, which can be used for target classification and identification. In this study, methods for vibrating ground target detection and feature extraction of the one-stationary bistatic frequency-modulated continuous-wave Synthetic Aperture Radar (SAR are studied. The Displaced Phase Center Antenna (DPCA technique is adopted to suppress the ground clutter, allowing the ground-vibrating targets to be detected. Analysis of the received signal indicates that the DPCA processing results in a slow time-varying envelope, known as the Slow Time Envelope (STE. The STE has a direct effect on the micro-Doppler time-frequency curve, which therefore cannot be obtained unbroken. Furthermore, vibrating features are extracted by utilizing their relationship with the STE term. Finally, some simulations are provided to validate the theoretical derivation and effectiveness of the proposed extraction method.

  7. Time-frequency analysis of railway bridge response in forced vibration

    OpenAIRE

    Cantero, Daniel; Ülker-Kaustell, Mahir; Karoumi, Raid

    2016-01-01

    This paper suggests the use of the Continuous Wavelet Transform in combination with the Modified Littlewood-Paley basis to analyse bridge responses exited by traversing trains. The analysis provides an energy distribution map in the time-frequency domain that offers a better resolution compared to previous published studies. This is demonstrated with recorded responses of the Skidträsk Bridge, a 36 m long composite bridge located in Sweden. It is shown to be particularly useful to understand ...

  8. Low-frequency vibrational modes of DL-homocysteic acid and related compounds

    Science.gov (United States)

    Yang, Limin; Zhao, Guozhong; Li, Weihong; Liu, Yufeng; Shi, Xiaoxi; Jia, Xinfeng; Zhao, Kui; Lu, Xiangyang; Xu, Yizhuang; Xie, Datao; Wu, Jinguang; Chen, Jia'er

    2009-09-01

    In this paper several polycrystalline molecules with sulfonate groups and some of their metal complexes, including DL-homocysteic acid (DLH) and its Sr- and Cu-complexes, pyridine-3-sulphonic acid and its Co- and Ni-complexes, sulfanilic acid and L-cysteic acid were investigated using THz time-domain methods at room temperature. The results of THz absorption spectra show that the molecules have characteristic bands in the region of 0.2-2.7 THz (6-90 cm -1). THz technique can be used to distinguish different molecules with sulfonate groups and to determine the bonding of metal ions and the changes of hydrogen bond networks. In the THz region DLH has three bands: 1.61, 1.93 and 2.02 THz; and 0.85, 1.23 and 1.73 THz for Sr-DLH complex, 1.94 THz for Cu-DLH complex, respectively. The absorption bands of pyridine-3-sulphonic acid are located at 0.81, 1.66 and 2.34 THz; the bands at 0.96, 1.70 and 2.38 THz for its Co-complex, 0.76, 1.26 and 1.87 THz for its Ni-complex. Sulphanilic acid has three bands: 0.97, 1.46 and 2.05 THz; and the absorption bands of L-cysteic acid are at 0.82, 1.62, 1.87 and 2.07 THz, respectively. The THz absorption spectra after complexation are different from the ligands, which indicate the bonding of metal ions and the changes of hydrogen bond networks. M-O and other vibrations appear in the FIR region for those metal-ligand complexes. The bands in the THz region were assigned to the rocking, torsion, rotation, wagging and other modes of different groups in the molecules. Preliminary assignments of the bands were carried out using Gaussian program calculation.

  9. Crack modelling and detection in Timoshenko FGM beam under transverse vibration using frequency contour and response surface model with GA

    Science.gov (United States)

    Banerjee, Amit; Panigrahi, Brajesh; Pohit, G.

    2016-04-01

    In the present work, dynamic response of cracked Timoshenko beam with functionally graded material properties are obtained by a numerical technique using Ritz approximation. In order to verify the applicability and performance of the formulation, comparisons of the present numerical method with three-dimensional FEM models are made. Crack is assumed to be transverse and open throughout the vibration cycle. Two different crack detection techniques have been proposed. Results obtained by the numerical technique are used in both of the crack detection techniques. In the first technique, the frequency contours with respect to crack location and size are plotted and the intersection of contours of different modes helps in the prediction of crack location and size. In the second technique, crack is modelled using response surface methodology (RSM). The sum of the squared errors between the numerical and RSM regression model natural frequencies is used as the objective function. This objective function is minimised using genetic algorithm optimisation technique. Both the crack detection techniques and the numerical analysis have shown good agreement with each other.

  10. (H2O)2(g): Monomer/dimer vibrational frequency shifts in Bopp-Jancsó-Heinzinger- and Matsuoka-Clementi-Yoshimine-Lie-type flexible potentials

    Science.gov (United States)

    Slanina, Zdeněk

    1991-01-01

    Harmonic vibrational analysis of the water dimer is reported for four BJH- and four MCYL-type flexible water-water potentials. The calculated monomer/dimer frequency shifts correspond reasonably well to the available observed terms, the BJH-type flexible potentials (with the gas-phase intramolecular potential) yielding a slightly better agreement.

  11. Atomization off thin water films generated by high-frequency substrate wave vibrations.

    Science.gov (United States)

    Collins, David J; Manor, Ofer; Winkler, Andreas; Schmidt, Hagen; Friend, James R; Yeo, Leslie Y

    2012-11-01

    Generating aerosol droplets via the atomization of thin aqueous films with high frequency surface acoustic waves (SAWs) offers several advantages over existing nebulization methods, particularly for pulmonary drug delivery, offering droplet sizes in the 1-5-μm range ideal for effective pulmonary therapy. Nevertheless, the physics underlying SAW atomization is not well understood, especially in the context of thin liquid film formation and spreading and how this affects the aerosol production. Here, we demonstrate that the film geometry, governed primarily by the applied power and frequency of the SAW, indeed plays a crucial role in the atomization process and, in particular, the size of the atomized droplets. In contrast to the continuous spreading of low surface energy liquids atop similar platforms, high surface energy liquids such as water, in the present case, are found to undergo transient spreading due to the SAW to form a quasisteady film whose height is determined by self-selection of the energy minimum state associated with the acoustic resonance in the film and whose length arises from a competition between acoustic streaming and capillary effects. This is elucidated from a fundamental model for the thin film spreading behavior under SAW excitation, from which we show good agreement between the experimentally measured and theoretically predicted droplet dimension, both of which consistently indicate a linear relationship between the droplet diameter and the mechanical power coupled into the liquid by the SAW (the latter captured by an acoustic Weber number to the two thirds power, and the reciprocal of the SAW frequency).

  12. Prediction model for fundamental frequency of low frequency bending vibration piezoelectric vibrator of ultrasonic atomizing nozzle%低频弯振超声雾化喷头压电振子基频的预测模型

    Institute of Scientific and Technical Information of China (English)

    高建民; 滕悦

    2015-01-01

    vibration frequency of this kind of actuator was mainly applying Rayleigh-Ritz theory based on the minimal energy principle to search an approximate value without considering electronic-mechanical coupling. Because Rayleigh-Ritz theory ignored the effect of t electronic-mechanical, the calculation result error was too bigger. At the same time, this method was so complicated that it’s not suitable for engineering calculation. So it’s necessary to find a simple calculation formulation for engineering application. In order to find out how key structural parameters of axial symmetry bending composite piezoelectric actuators influence on their fundamental frequencies, a virtual testing system based on finite element method was established. In this virtual testing system, element Solid 98, an tetrahedral coupled-field solid element in ANSYS software was used to mesh the prototype of axial symmetry bending composite piezoelectric actuator. Combined with an orthogonal experimental design method, an orthogonal protocol of four factors and five levels was proposed. Based on virtual test data, a regression model between fundamental frequency and key structural parameters of piezoelectric vibrators (significance levelα=0.05) was established. The regression model indicated that: i)P-valuesof outer diameters, inner diameters of nozzle’s piezoelectric discs and diameters of metal discs were 1.2×10-8、9.97×10-6、2.093×10-3respectively. It indicated that fundamental frequencies of axial symmetry bending composite piezoelectric actuator were affected by outer diameters, inner diameters of nozzle’s piezoelectric discs and diameters of metal discs highly significantly; ii)P-valueof piezoelectric disc thickness was 0.012813. It indicated that fundamental frequencies were influenced by piezoelectric disc thickness significantly; iii) outer diameter, inner diameter, thickness of nozzle’s piezoelectric ceramic and diameter of metal disc influence frequencies of those actuators in

  13. Time-frequency analysis of railway bridge response in forced vibration

    Science.gov (United States)

    Cantero, Daniel; Ülker-Kaustell, Mahir; Karoumi, Raid

    2016-08-01

    This paper suggests the use of the Continuous Wavelet Transform in combination with the Modified Littlewood-Paley basis to analyse bridge responses exited by traversing trains. The analysis provides an energy distribution map in the time-frequency domain that offers a better resolution compared to previous published studies. This is demonstrated with recorded responses of the Skidträsk Bridge, a 36 m long composite bridge located in Sweden. It is shown to be particularly useful to understand the evolution of the energy content during a vehicle crossing event. With this information it is possible to distinguish the effect of several of the governing factors involved in the dynamic response including vehicle's speed and axle configuration as well as non-linear behaviour of the structure.

  14. Raman and infrared vibrational frequencies and elastic properties of solid BaFCl calculated with various Hamiltonians: an ab initio study

    Energy Technology Data Exchange (ETDEWEB)

    Merawa, Mohammadou [Laboratoire de Chimie Theorique et de Physico-Chimie Moleculaire, UMR 5624, FR ' IPREM' 2606, BP 27540 IFR-rue Jules Ferry 64075 Pau-Cedex (France); Noel, Yves [Laboratoire de Petrologie et Modelisation des Materiaux et des Processus, Universite P and M Curie Paris 6, 4 place Jussieu 75252 Paris Cedex 05 (France); Civalleri, Bartolomeo [Dipartimento di Chimica IFM, University of Torino, Via Giuria 7, I-10125 Torino (Italy); Brown, Ross [Laboratoire de Chimie Theorique et de Physico-Chimie Moleculaire, UMR 5624, FR ' IPREM' 2606, BP 27540 IFR-rue Jules Ferry 64075 Pau-Cedex (France); Dovesi, Roberto [Dipartimento di Chimica IFM, University of Torino, Via Giuria 7, I-10125 Torino (Italy)

    2005-01-26

    The structural, elastic, vibrational and electronic properties of barium fluorochloride (BaFCl) have been investigated for the first time at the ab initio level, by using the periodic CRYSTAL program. Both Hartree-Fock (HF) and density functional theory (DFT) Hamiltonians have been used, with the latter in its local density (LV), gradient-corrected (PP), and hybrid (B3LYP) versions. All properties, and in particular the phonon frequencies and the elastic constants, are strongly Hamiltonian dependent. The structural features are in reasonable agreement with experiment, the percentage deviation being smaller than 5% in all cases. The B3LYP elastic constants are in good agreement with experiment, whereas LV systematically overestimates them. PP and B3LYP provide the best results for the vibrational frequencies, the mean percentage absolute difference with respect to experiment being 2.9 and 4.3%, for Raman and 4.8 and 6.3%, for infrared mode frequencies, respectively.

  15. Analysis of algorithms for detection of resonance frequencies in vibration measurements on super heater tubes; Analys av algoritmer foer detektering av resonansfrekvenser i vibrationsmaetningar paa oeverhettartuber

    Energy Technology Data Exchange (ETDEWEB)

    Eriksson, Daniel

    2010-07-01

    Combustion of fuel in thermal power plants emits particles which creates coatings on the super heater tubes. The coatings isolate the tubes and impairs the efficiency of the heat transfer. Cleaning the tubes occurs while the power plant is running but without any knowledge of the actual coating. A change in frequency corresponds to a change in mass of the coatings. This thesis has been focusing in estimating resonance frequencies in vibration measurements made by strain gauges on the tubes. To improve the estimations a target tracking algorithm had been added. The results indicates that it is possible to estimate the resonance frequencies but the algorithms need to be verified on more signals.

  16. Portable vibration exciter

    Science.gov (United States)

    Beecher, L. C.; Williams, F. T.

    1970-01-01

    Gas-driven vibration exciter produces a sinusoidal excitation function controllable in frequency and in amplitude. It allows direct vibration testing of components under normal loads, removing the possibility of component damage due to high static pressure.

  17. Vibrational spectroscopy [FTIR and FTRaman] investigation, computed vibrational frequency analysis and IR intensity and Raman activity peak resemblance analysis on 4-chloro 2-methylaniline using HF and DFT [LSDA, B3LYP and B3PW91] calculations.

    Science.gov (United States)

    Ramalingam, S; Periandy, S

    2011-03-01

    In the present study, the FT-IR and FT-Raman spectra of 4-chloro-2-methylaniline (4CH2MA) have been recorded in the range of 4000-100 cm(-1). The fundamental modes of vibrational frequencies of 4CH2MA are assigned. All the geometrical parameters have been calculated by HF and DFT (LSDA, B3LYP and B3PW91) methods with 6-31G (d, p) and 6-311G (d, p) basis sets. Optimized geometries of the molecule have been interpreted and compared with the reported experimental values for aniline and some substituted aniline. The harmonic and anharmonic vibrational wavenumbers, IR intensities and Raman activities are calculated at the same theory levels used in geometry optimization. The calculated frequencies are scaled and compared with experimental values. The scaled vibrational frequencies at LSDA/B3LYP/6-311G (d, p) seem to coincide with the experimentally observed values with acceptable deviations. The impact of substitutions on the benzene structure is investigated. The molecular interactions between the substitutions (Cl, CH(3) and NH(2)) are also analyzed.

  18. High-frequency vibration effects on hole entrance chipping in rotary ultrasonic drilling of BK7 glass.

    Science.gov (United States)

    Lv, Dongxi; Zhang, Yuanming; Peng, Yunfeng

    2016-12-01

    This present investigation exhibited some fundamental information about the influence of the high-frequency vibration on the hole entrance chipping formation involved in rotary ultrasonic drilling (RUD) of BK7 glass process. The entrance chipping morphologies, produced with and without ultrasonic, were observed and evaluated with respect to the fracture mechanics of brittle material. Giving consideration to the variation characteristics of the plastic deformation region in the interior material induced by the specific kinematics principles of the abrasive, the ultrasonic effects on the chipping formation mechanisms were investigated by assessing the groove morphologies obtained in the scratching experiment utilizing the formation mechanisms of the lateral cracking. Furthermore, the formal confirmatory tests with and without ultrasonic were performed to validate these chipping formation mechanisms. It was found that the plastic deformed region reached its maximum at the trajectory bottom. Moreover, the propagation of the lateral cracking initially nucleated at the bottom of the ductile deformation zone resulted in the formation of the entrance chipping in formal RUD process. The slight deformation of the material at the two terminals of each groove produced with ultrasonic would provide the inhibitory effects to the further extending of the lateral cracks, which would shrink with the increased spindle speed, and the inhibitory effect dominated in determining the improvement effects on the hole entrance quality. Additionally, a theoretical relationship between the nucleation depth and the propagation length of the lateral cracking was developed for the conventional drilling (CD) process.

  19. Vibrational Frequencies and Spectroscopic Constants for 1(sup 3)A' HNC and 1(sup 3)A' HOC+ from High-Accuracy Quartic Force Fields

    Science.gov (United States)

    Fortenberry, Ryan C.; Crawford, T. Daniel; Lee, Timothy J.

    2014-01-01

    The spectroscopic constants and vibrational frequencies for the 1(sup 3)A' states of HNC, DNC, HOC+, and DOC+ are computed and discussed in this work. The reliable CcCR quartic force field based on high-level coupled cluster ab initio quantum chemical computations is exclusively utilized to provide the anharmonic potential. Then, second order vibrational perturbation theory and vibrational configuration interaction methods are employed to treat the nuclear Schroedinger equation. Second-order perturbation theory is also employed to provide spectroscopic data for all molecules examined. The relationship between these molecules and the corresponding 1(sup 3)A' HCN and HCO+ isomers is further developed here. These data are applicable to laboratory studies involving formation of HNC and HOC+ as well as astronomical observations of chemically active astrophysical environments.

  20. Theoretical studies for the N{sub 2}–N{sub 2}O van der Waals complex: The potential energy surface, intermolecular vibrations, and rotational transition frequencies

    Energy Technology Data Exchange (ETDEWEB)

    Zheng, Rui [Key Laboratory of Magnetic Resonance in Biological Systems, State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Centre for Magnetic Resonance, Wuhan Institute of Physics and Mathematics, Chinese Academy of Sciences, Wuhan 430071 (China); School of Mathematics and Information Science, North China University of Water Resources and Electric Power, Zhengzhou 450011 (China); Zheng, Limin; Yang, Minghui, E-mail: yplu@ntu.edu.sg, E-mail: yangmh@wipm.ac.cn [Key Laboratory of Magnetic Resonance in Biological Systems, State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Centre for Magnetic Resonance, Wuhan Institute of Physics and Mathematics, Chinese Academy of Sciences, Wuhan 430071 (China); Lu, Yunpeng, E-mail: yplu@ntu.edu.sg, E-mail: yangmh@wipm.ac.cn [Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, Singapore 637371 (Singapore)

    2015-10-21

    Theoretical studies of the potential energy surface (PES) and bound states are performed for the N{sub 2}–N{sub 2}O van der Waals (vdW) complex. A four-dimensional intermolecular PES is constructed at the level of single and double excitation coupled-cluster method with a non-iterative perturbation treatment of triple excitations [CCSD(T)] with aug-cc-pVTZ basis set supplemented with bond functions. Two equivalent T-shaped global minima are located, in which the O atom of N{sub 2}O monomer is near the N{sub 2} monomer. The intermolecular fundamental vibrational states are assigned by inspecting the orientation of the nodal surface of the wavefunctions. The calculated frequency for intermolecular disrotation mode is 23.086 cm{sup −1}, which is in good agreement with the available experimental data of 22.334 cm{sup −1}. A negligible tunneling splitting with the value of 4.2 MHz is determined for the ground vibrational state and the tunneling splitting increases as the increment of the vibrational frequencies. Rotational levels and transition frequencies are calculated for both isotopomers {sup 14}N{sub 2}–N{sub 2}O and {sup 15}N{sub 2}–N{sub 2}O. The accuracy of the PES is validated by the good agreement between theoretical and experimental results for the transition frequencies and spectroscopic parameters.

  1. Experimental Investigation of the Effect of Radial Gap and Impeller Blade Exit on Flow-Induced Vibration at the Blade-Passing Frequency in a Centrifugal Pump

    Directory of Open Access Journals (Sweden)

    A. Al-Qutub

    2009-01-01

    Full Text Available It has been recognized that the pressure pulsation excited by rotor-stator interaction in large pumps is strongly influenced by the radial gap between impeller and volute diffusers/tongues and the geometry of impeller blade at exit. This fluid-structure interaction phenomenon, as manifested by the pressure pulsation, is the main cause of flow-induced vibrations at the blade-passing frequency. In the present investigation, the effects of the radial gap and flow rate on pressure fluctuations, vibration, and pump performance are investigated experimentally for two different impeller designs. One impeller has a V-shaped cut at the blade's exit, while the second has a straight exit (without the V-cut. The experimental findings showed that the high vibrations at the blade-passing frequency are primarily raised by high pressure pulsation due to improper gap design. The existence of V-cut at blades exit produces lower pressure fluctuations inside the pump while maintaining nearly the same performance. The selection of proper radial gap for a given impeller-volute combination results in an appreciable reduction in vibration levels.

  2. Theoretical Investigation on the Substituent Effect of Halogen Atoms at the C8 Position of Adenine: Relative Stability, Vibrational Frequencies, and Raman Spectra of Tautomers.

    Science.gov (United States)

    Chen, Yan-Li; Wu, De-Yin; Tian, Zhong-Qun

    2016-06-16

    We have theoretically investigated the substituent effect of adenine at the C8 position with a substituent X = H, F, Cl, and Br by using the density functional theory (DFT) at the B3LYP/6-311+G(d, p) level. The aim is to study the substituent effect of halogen atoms on the relative stability, vibrational frequencies, and solvation effect of tautomers. Our calculated results show that for substituted adenine molecules the N9H8X tautomer to be the most stable structure in gas phase at the present theoretical level. Here N9H8X denotes the hydrogen atom binds to the N9 position of imidazole ring and X denotes H, F, Cl, and Br atoms. The influence of the induced attraction of the fluorine substituent is significantly larger than chlorine and bromine ones. The halogen substituent effect has a significant influence on changes of vibrational frequencies and Raman intensities.

  3. Characterisation of the membrane affinity of an isoniazide peptide conjugate by tensiometry, atomic force microscopy and sum-frequency vibrational spectroscopy, using a phospholipid Langmuir monolayer model.

    Science.gov (United States)

    Hill, Katalin; Pénzes, Csanád Botond; Schnöller, Donát; Horváti, Kata; Bosze, Szilvia; Hudecz, Ferenc; Keszthelyi, Tamás; Kiss, Eva

    2010-10-07

    Tensiometry, sum-frequency vibrational spectroscopy, and atomic force microscopy were employed to assess the cell penetration ability of a peptide conjugate of the antituberculotic agent isoniazide. Isoniazide was conjugated to peptide (91)SEFAYGSFVRTVSLPV(106), a functional T-cell epitope of the immunodominant 16 kDa protein of Mycobacterium tuberculosis. As a simple but versatile model of the cell membrane a phospholipid Langmuir monolayer at the liquid/air interface was used. Changes induced in the structure of the phospholipid monolayer by injection of the peptide conjugate into the subphase were followed by tensiometry and sum-frequency vibrational spectroscopy. The drug penetrated lipid films were transferred to a solid support by the Langmuir-Blodgett technique, and their structures were characterized by atomic force microscopy. Peptide conjugation was found to strongly enhance the cell penetration ability of isoniazide.

  4. Frequency Spectrum and Treatment for Vibration of Large Booster Fans%大型增压风机振动的频谱特性及处理

    Institute of Scientific and Technical Information of China (English)

    梁勇

    2012-01-01

    The abnormal vibration of a booster fan for a 100O-MW unit during operation is introduced. Field measurement shows that the vibration has the characteristics of airflow pulsation. The frequency spectrum of (he vibration shows that the excitation of fan vibration mainly comes from the blade passing frequency with a large amount of impact energy in both axial and vertical directions. In addition, the fan is easy to fall into un-stable operation under low load conditions for the excessive margin design. As a result, fatigue fracture happens on the inlet support lateral plate of the fan after long-term vibration, which could cause bad damage to fan blades and the rear impeller. According lo the vibration characteristics and abnormal phenomena of the fan, by changing the natural frequency of the blades and installation angles and improving the resistance of the flue gas system and the rigidity of chassis supports,the vibration of the booster fan has been solved.%介绍了某1000MW机组增压风机运行中振动异常的情况.通过现场测量分析,振动具有气流脉动的特征,振动频谱显示风机振动的激励主要来自叶片通过频率,且轴向和垂直方向均有很大的冲击能量;另外,增压风机的裕量较大,在低负荷工况时风机容易落入不稳定工作区运行.由于长期的振动引起风机入口支撑侧板疲劳断裂,进而引起风机叶片和后导叶严重损坏.针对风机振动的特点和异常现象,通过改变叶片固有频率、叶片安装角、改善烟道系统阻力和机壳支撑刚性等措施,解决了增压风机振动大的问题.

  5. The giant frequency shift of intramolecular O-H vibration band in the raman spectra of water on the silver surface

    CERN Document Server

    Kompan, Mikhail

    2016-01-01

    The giant frequency shift was observed in Raman spectra for inramolecular O-H vibration band. The effect was observed in SERS-condition experiment, when exciting light was focused by short-focus objective on the Ag-surface, merged in water. The shift was detected relatively to the regularl position of band, measured from the bulk of water under the same other conditions.

  6. Nanoscale chemical and mechanical characterization of thin films:sum frequency generation (SFG) vibrational spectroscopy at buriedinterfaces

    Energy Technology Data Exchange (ETDEWEB)

    Kweskin, Sasha Joseph [Univ. of California, Berkeley, CA (United States)

    2006-01-01

    Sum frequency generation (SFG) surface vibrational spectroscopy was used to characterize interfaces pertinent to current surface engineering applications, such as thin film polymers and novel catalysts. An array of advanced surface science techniques like scanning probe microscopy (SPM), x-ray photoelectron spectroscopy (XPS), gas chromatography (GC) and electron microscopy were used to obtain experimental measurements complementary to SFG data elucidating polymer and catalyst surface composition, surface structure, and surface mechanical behavior. Experiments reported in this dissertation concentrate on three fundamental questions: (1) How does the interfacial molecular structure differ from that of the bulk in real world applications? (2) How do differences in chemical environment affect interface composition or conformation? (3) How do these changes correlate to properties such as mechanical or catalytic performance? The density, surface energy and bonding at a solid interface dramatically alter the polymer configuration, physics and mechanical properties such as surface glass transition, adhesion and hardness. The enhanced sensitivity of SFG at the buried interface is applied to three systems: a series of acrylates under compression, the compositions and segregation behavior of binary polymer polyolefin blends, and the changes in surface structure of a hydrogel as a function of hydration. In addition, a catalytically active thin film of polymer coated nanoparticles is investigated to evaluate the efficacy of SFG to provide in situ information for catalytic reactions involving small mass adsorption and/or product development. Through the use of SFG, in situ total internal reflection (TIR) was used to increase the sensitivity of SFG and provide the necessary specificity to investigate interfaces of thin polymer films and nanostructures previously considered unfeasible. The dynamic nature of thin film surfaces is examined and it is found that the non

  7. Influence of charge and coordination number on bond dissociation energies, distances, and vibrational frequencies for the phosphorus-phosphorus bond.

    Science.gov (United States)

    Chitnis, Saurabh S; Whalen, J Marc; Burford, Neil

    2014-09-01

    We report a comprehensive and systematic experimental and computational assessment of the P-P bond in prototypical molecules that represent a rare series of known compounds. The data presented complement the existing solid-state structural data and previous computational studies to provide a thorough thermodynamic and electronic understanding of the P-P bond. Comparison of homolytic and heterolytic bond dissociation for tricoordinate-tricoordinate, tricoordinate-tetracoordinate, and tetracoordinate-tetracoordinate P-P bonds in frameworks 1-6 provides fundamental insights into covalent bonding. For all types of P-P bond discussed, homolytic dissociation is favored over heterolytic dissociation, although the distinction is small for 2(1+) and 6(1+). The presence of a single cationic charge in a molecule substantially strengthens the P-P bond (relative to analogous neutral frameworks) such that it is comparable with the C-C bond in alkanes. Nevertheless, P-P distances are remarkably independent of molecular charge or coordination number, and trends in values of d(PC) and νsymm(PC) imply that a molecular cationic charge is distributed over the alkyl substituents. In the gas phase, the diphosphonium dication 3(2+) has similar energy to two [PMe3](+) radical cations, so that it is the lattice enthalpy of 3[OTf]2 in the solid-state that enables isolation, highlighting that values from gas-phase calculations are poor guides for synthetic planning for ionic compounds. There are no relationships or correlations between bond lengths, strengths, and vibrational frequencies.

  8. Surface and buried interfacial structures of epoxy resins used as underfills studied by sum frequency generation vibrational spectroscopy.

    Science.gov (United States)

    Vázquez, Anne V; Holden, Brad; Kristalyn, Cornelius; Fuller, Mike; Wilkerson, Brett; Chen, Zhan

    2011-05-01

    Flip chip technology has greatly improved the performance of semiconductor devices, but relies heavily on the performance of epoxy underfill adhesives. Because epoxy underfills are cured in situ in flip chip semiconductor devices, understanding their surface and interfacial structures is critical for understanding their adhesion to various substrates. Here, sum frequency generation (SFG) vibrational spectroscopy was used to study surface and buried interfacial structures of two model epoxy resins used as underfills in flip chip devices, bisphenol A digylcidyl ether (BADGE) and 1,4-butanediol diglycidyl ether (BDDGE). The surface structures of these epoxies were compared before and after cure, and the orientations of their surface functional groups were deduced to understand how surface structural changes during cure may affect adhesion properties. Further, the effect of moisture exposure, a known cause of adhesion failure, on surface structures was studied. It was found that the BADGE surface significantly restructured upon moisture exposure while the BDDGE surface did not, showing that BADGE adhesives may be more prone to moisture-induced delamination. Lastly, although surface structure can give some insight into adhesion, buried interfacial structures more directly correspond to adhesion properties of polymers. SFG was used to study buried interfaces between deuterated polystyrene (d-PS) and the epoxies before and after moisture exposure. It was shown that moisture exposure acted to disorder the buried interfaces, most likely due to swelling. These results correlated with lap shear adhesion testing showing a decrease in adhesion strength after moisture exposure. The presented work showed that surface and interfacial structures can be correlated to adhesive strength and may be helpful in understanding and designing optimized epoxy underfill adhesives.

  9. Heme carbonyls: environmental effects on nu(C-O) and Fe-C/C-O bond length correlations.

    Science.gov (United States)

    Silvernail, Nathan J; Roth, Arne; Schulz, Charles E; Noll, Bruce C; Scheidt, W Robert

    2005-10-19

    The synthesis and characterization of four low-spin (carbonyl)iron(II) tetraphenylporphyrinates, [Fe(TPP)(CO)(L)], where L = 1-methylimidazole, 2-methylimidazole, 1,2-dimethylimidazole (unsolvated), and 1,2-dimethylimidazole (toluene solvate) are reported. The complexes show nearly the same value of nu(C-O) in toluene solution (1969-72 cm(-1)) but a large range of CO stretching frequencies in the solid-state (1926-1968 cm(-1)). The large solid-state variation results from CO interactions in the solid state, as shown by an examination of the crystal structures of the four complexes. The high precision of the four structures obtained allows us to make a number of structural and spectroscopic correlations that describe the Fe-C-O and N(Im)-Fe-CO units. The values of nu(C-O) and the Fe-C and C-O bond distances are strongly correlated and provide a structural, as well as a spectroscopic, correlation of the pi back-bonding model. The interactions of CO described are closely related to the large range of CO stretching frequencies observed in heme proteins and specific interactions observed in carbonylmyoglobin (MbCO).

  10. The impact of low-magnitude high-frequency vibration on fracture healing is profoundly influenced by the oestrogen status in mice

    Directory of Open Access Journals (Sweden)

    Esther Wehrle

    2015-01-01

    Full Text Available Fracture healing is impaired in aged and osteoporotic individuals. Because adequate mechanical stimuli are able to increase bone formation, one therapeutical approach to treat poorly healing fractures could be the application of whole-body vibration, including low-magnitude high-frequency vibration (LMHFV. We investigated the effects of LMHFV on fracture healing in aged osteoporotic mice. Female C57BL/6NCrl mice (n=96 were either ovariectomised (OVX or sham operated (non-OVX at age 41 weeks. When aged to 49 weeks, all mice received a femur osteotomy that was stabilised using an external fixator. The mice received whole-body vibrations (20 minutes/day with 0.3 g peak-to-peak acceleration and a frequency of 45 Hz. After 10 and 21 days, the osteotomised femurs and intact bones (contra-lateral femurs, lumbar spine were evaluated using bending-testing, micro-computed tomography (μCT, histology and gene expression analyses. LMHFV disturbed fracture healing in aged non-OVX mice, with significantly reduced flexural rigidity (−81% and bone formation (−80% in the callus. Gene expression analyses demonstrated increased oestrogen receptor β (ERβ, encoded by Esr2 and Sost expression in the callus of the vibrated animals, but decreased β-catenin, suggesting that ERβ might mediate these negative effects through inhibition of osteoanabolic Wnt/β-catenin signalling. In contrast, in OVX mice, LMHFV significantly improved callus properties, with increased flexural rigidity (+1398% and bone formation (+637%, which could be abolished by subcutaneous oestrogen application (0.025 mg oestrogen administered in a 90-day-release pellet. On a molecular level, we found an upregulation of ERα in the callus of the vibrated OVX mice, whereas ERβ was unaffected, indicating that ERα might mediate the osteoanabolic response. Our results indicate a major role for oestrogen in the mechanostimulation of fracture healing and imply that LMHFV might only be safe and

  11. Homogeneous and inhomogeneous broadenings and the Voigt line shapes in the phase-resolved and intensity sum-frequency generation vibrational spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Shunli; Fu, Li; Gan, Wei; Wang, Hongfei

    2016-01-21

    In this report we show that the ability to measure the sub-1 cm-1 resolution phase-resolved and intensity high-resolution broadband sum frequency generation vibrational spectra (HR-BB-SFG-VS) of the –CN stretch vibration of the Langmuir-Blodgett (LB) monolayer of the 4-n-octyl-4’-cyanobiphenyl (8CB) on the z-cut α-quartz surface allows for the first time the direct comparison and understanding of the homogeneous and inhomogeneous broadenings in the imaginary and intensity SFG vibrational spectral lineshapes in detail. The difference of the full width at half maxima (FWHM) of the imaginary and intensity SFG-VS spectra of the same vibrational mode is the signature of the Voigt lineshape and it measures the relative contribution to the overall lineshape from the homogeneous and inhomogeneous broadenings in SFG vibrational spectra. From the phase-resolved and intensity spectra, we found that the FWHM of the 2238.00 ±0.02 cm-1 peak in the phase-resolved imaginary and intensity spectra is 19.2 ± 0.2 cm-1 and 21.6 ± 0.4 cm-1, respectively, for the –CN group of the 8CB LB monolayer on the z-cut α-quartz crystal surface. The FWHM width difference of 2.4 cm-1 agrees quantitatively with a Voigt lineshape with a homogeneous broadening half width of Γ = 5.29 ± 0.08 cm-1 and a inhomogeneous standard derivation width Δω = 5.42 ± 0.07 cm-1. These results shed new lights on the understanding and interpretation of the lineshapes of both the phase-resolved and the intensity SFG vibrational spectra, as well as other incoherent and coherent spectroscopic techniques in general.

  12. Vibrational properties of uracil

    Institute of Scientific and Technical Information of China (English)

    WANG Zhiping; ZHANG Fengshou; ZENG Xianghua; ZHOU Hongyu; GU Bin; CHENG Wei

    2006-01-01

    A semiempirical molecular dynamics model is developed to study the vibrational frequencies of uracil at very low kinetic temperature by using the Fourier transform of velocity autocorrelation function of trajectories of molecular dynamics simulations. The finite difference harmonic method is used to assign the vibrational frequency of each mode. The calculated frequencies are found to be in good agreement with experimental measurements. Moreover, we make up for the lost vibrational modes in experiments self-consistently. A total of 30 vibrational modes and their corresponding frequencies are reported.

  13. Energy Finite Element Analysis for Computing the High Frequency Vibration of the Aluminum Testbed Cylinder and Correlating the Results to Test Data

    Science.gov (United States)

    Vlahopoulos, Nickolas

    2005-01-01

    The Energy Finite Element Analysis (EFEA) is a finite element based computational method for high frequency vibration and acoustic analysis. The EFEA solves with finite elements governing differential equations for energy variables. These equations are developed from wave equations. Recently, an EFEA method for computing high frequency vibration of structures either in vacuum or in contact with a dense fluid has been presented. The presence of fluid loading has been considered through added mass and radiation damping. The EFEA developments were validated by comparing EFEA results to solutions obtained by very dense conventional finite element models and solutions from classical techniques such as statistical energy analysis (SEA) and the modal decomposition method for bodies of revolution. EFEA results have also been compared favorably with test data for the vibration and the radiated noise generated by a large scale submersible vehicle. The primary variable in EFEA is defined as the time averaged over a period and space averaged over a wavelength energy density. A joint matrix computed from the power transmission coefficients is utilized for coupling the energy density variables across any discontinuities, such as change of plate thickness, plate/stiffener junctions etc. When considering the high frequency vibration of a periodically stiffened plate or cylinder, the flexural wavelength is smaller than the interval length between two periodic stiffeners, therefore the stiffener stiffness can not be smeared by computing an equivalent rigidity for the plate or cylinder. The periodic stiffeners must be regarded as coupling components between periodic units. In this paper, Periodic Structure (PS) theory is utilized for computing the coupling joint matrix and for accounting for the periodicity characteristics.

  14. Combined IR/NIR and density functional theory calculations analysis of the solvent effects on frequencies and intensities of the fundamental and overtones of the C ═ O stretching vibrations of acetone and 2-hexanone.

    Science.gov (United States)

    Chen, Yujing; Morisawa, Yusuke; Futami, Yoshisuke; Czarnecki, Mirosław A; Wang, Hai-Shui; Ozaki, Yukihiro

    2014-04-10

    Vibrational overtone studies primarily focus on X-H stretching overtone transitions, where X is an atom like C, O, N, or S. In contrast, the studies on the C ═ O stretching overtones are very scattered. To advance the research in this field, we measured the fundamental, first, and second overtones of the C ═ O stretching vibration of acetone and 2-hexanone in n-hexane, CCl4, and CHCl3, as well as in the vapor phase using FT-IR/FT-NIR spectroscopy. Density functional theory (DFT) calculations have also been performed to help the assignment of the C ═ O stretching bands and to guide interpretation of the experimental results. It was found that the wavenumbers, absorption intensities, and oscillator strengths of the C ═ O stretching bands show marked solvent dependence. In the fundamental and the first overtone regions, the intensities of the C ═ O stretching vibration were found to be pronouncedly more intense than those of the C-H stretching vibration. In the second overtone region, the intensities of the C-H stretching vibration are comparable to those of the C ═ O stretching vibration. The theoretical and observed decrease in integrated intensity upon going from the fundamental to the first overtone of the C ═ O stretching vibration is around 50, which is significantly larger than those of the O-H, C-H, and S-H stretching vibration. Both the calculated and experimental results suggest that excessive weakness in the C ═ O stretching overtone was shown to be a result of both a low anharmonicity and a substantial reduction in the oscillator strength. These results provide new insight into our understanding of the C ═ O stretching vibration.

  15. Analysis of motion of inverted pendulum with vibrating suspension axis at low-frequency excitation as an illustration of a new approach for solving equations without explicit small parameter

    DEFF Research Database (Denmark)

    Sorokin, Vladislav

    2014-01-01

    In the classical papers (see, e.g. P.L. Kapitsa, Pendulum with vibrating axis of suspension. Usp. Fiz. Nauk 44 1 (1954) 7-20 (in Russian)) motion of pendulum with vibrating suspension axis was considered in the case when frequency of external loading is much higher than the natural frequency of t......; as an illustration, a damped Duffing equation is considered. © 2014 Elsevier Ltd....

  16. Vibration sensors

    Science.gov (United States)

    Gupta, Amita; Singh, Ranvir; Ahmad, Amir; Kumar, Mahesh

    2003-10-01

    Today, vibration sensors with low and medium sensitivities are in great demand. Their applications include robotics, navigation, machine vibration monitoring, isolation of precision equipment & activation of safety systems e.g. airbags in automobiles. Vibration sensors have been developed at SSPL, using silicon micromachining to sense vibrations in a system in the 30 - 200 Hz frequency band. The sensing element in the silicon vibration sensor is a seismic mass suspended by thin silicon hinges mounted on a metallized glass plate forming a parallel plate capacitor. The movement of the seismic mass along the vertical axis is monitored to sense vibrations. This is obtained by measuring the change in capacitance. The movable plate of the parallel plate capacitor is formed by a block connected to a surrounding frame by four cantilever beams located on sides or corners of the seismic mass. This element is fabricated by silicon micromachining. Several sensors in the chip sizes 1.6 cm x 1.6 cm, 1 cm x 1 cm and 0.7 cm x 0.7 cm have been fabricated. Work done on these sensors, techniques used in processing and silicon to glass bonding are presented in the paper. Performance evaluation of these sensors is also discussed.

  17. Dependence of the frequency spectrum of small amplitude vibrations superimposed on finite deformations of a nonlinear, cylindrical elastic body on residual stress

    KAUST Repository

    Gorb, Yuliya

    2010-11-01

    We model and analyze the response of nonlinear, residually stressed elastic bodies subjected to small amplitude vibrations superimposed upon large deformations. The problem derives from modeling the use of intravascular ultrasound (IVUS) imaging to interrogate atherosclerotic plaques in vivo in large arteries. The goal of this investigation is twofold: (i) introduce a modeling framework for residual stress that unlike traditional Fung type classical opening angle models may be used for a diseased artery, and (ii) investigate the sensitivity of the spectra of small amplitude high frequency time harmonic vibrations superimposed on a large deformation to the details of the residual stress stored in arteries through a numerical simulation using physiologic parameter values under both low and high blood pressure loadings. The modeling framework also points the way towards an inverse problem using IVUS techniques to estimate residual stress in healthy and diseased arteries. © 2010 Elsevier Ltd. All rights reserved.

  18. 国内外高频振动筛技术与设备现状及发展趋势%Current situation and development tendency of high-frequency vibration screen technology and equipments at home and abroad

    Institute of Scientific and Technical Information of China (English)

    赵环帅; 鲍玉新; 陈思元; 杨秀秀

    2011-01-01

    The paper introduces the main technical characteristics of the high-frequency vibration screen and analyzes the study situation of high-frequency vibration screen technology at home and abroad. It briefly introduces the main characteristics of commonly used high-frequency vibration screens at present, and proposes the future development tendency of the high-frequency vibration screen according to current issues about the development of the high-frequency vibration screen. The proposed development tendency includes the application of advanced analysis software and testing tools for optimization and analysis, study on manufacturing process of the high-frequency vibration screen as well as study on structure of rubber springs, sieving plates and vibration exciters, study on relationship between technical parameters and process parameters, developing towards large scale and fineness, decreasing operation noise of the high-frequency vibration screen.%介绍了高频振动筛的主要工艺特点,对国内外高频振动筛技术的研究现状进行了分析,对目前市场上常见的高频振动筛的主要特点进行了简单介绍。针对目前高频振动筛发展存在的问题,提出了未来高频振动筛的发展趋势:采用先进的分析软件与测试工具进行优化分析;高频振动筛加工工艺、橡胶弹簧、筛板、激振器结构的研究;技术参数与工艺参数之间关系的研究;向大型化和精细化发展;降低高频振动筛工作噪声的方法等。

  19. SIMULATION OF VIBRATION STRESS RELIEF AFTER WELDING BASED ON FEM

    Institute of Scientific and Technical Information of China (English)

    X.C.Zhao; Y.D.Zhang; H.W.Zhang; Q.Wu

    2008-01-01

    A finite element model is developed for the simulation of vibration stress relief (VSR) after welding.For the nonresonant vibration,the reduction in stress strongly depends on the amplitude of vibration.For the resonant vibration,the vibration frequency is the key for stress relief.The vibration frequency should be close to the structure natural frequency for the desired vibration mode.Only small vibration amplitude is required,which will be amplified during vibration.Vibration time does not have a major impact on vibration stress relief.When the amplitude of vibration stress relief is large,the treatment will be more effective.

  20. Infrared spectra of metal complexes with -x,5-dimethylpyrazole and 1,2,4-triazole in frequency range of valent vibrations of metal-ligand bond

    Energy Technology Data Exchange (ETDEWEB)

    Oglezneva, I.M.; Lavrenova, L.G.; Larionov, S.V. (AN SSSR, Novosibirsk. Inst. Neorganicheskoj Khimii)

    1984-06-01

    In the range 200-600 cm/sup -1/ IR absorption spectra of complexes of halides and nitrates of Cu/sup 2/, Ni/sup 2/, Co/sup 2/, Zn/sup 2/, Cd/sup 2/ with two heterocyclic nitrogen-containing ligands: 3,5-dimethylpyrazole and 1,2,4-triazole, have been investigated. Taking into account the structure of coordination polyhedron (according to the data of electron spectroscopy and magnetic measurements), the interpretation of frequencies of valent vibrations of metal-nitrogen and metal-helide bonds is made. Regularities of ..nu.. (MN) change depending on metal and ligand are pointed out.

  1. A batch-fabricated electret-biased wideband MEMS vibration energy harvester with frequency-up conversion behavior powering a UHF wireless sensor node

    Science.gov (United States)

    Lu, Y.; O'Riordan, E.; Cottone, F.; Boisseau, S.; Galayko, D.; Blokhina, E.; Marty, F.; Basset, P.

    2016-12-01

    This paper reports a batch-fabricated, low-frequency and wideband MEMS electrostatic vibration energy harvester (e-VEH), which implements corona-charged vertical electrets and nonlinear elastic stoppers. A numeric model is used to perform parametric study, where we observe a wideband bi-modality resulting from nonlinearity. The nonlinear stoppers improve the bandwidth and induce a frequency-up feature at low frequencies. When the e-VEH works with a bias of 45 V, the power reaches a maximum value of 6.6 μW at 428 Hz and 2.0 g rms, and is above 1 μW at 50 Hz. When the frequency drops below 60 Hz, a ‘frequency-up’ conversion behavior is observed with peaks of power at 34 Hz and 52 Hz. The  -3 dB bandwidth is more than 60% of its central frequency, both including and excluding the hysteresis introduced by the nonlinear stoppers. We also perform experiments with wideband Gaussian noise. The device is eventually tested with an RF data transmission setup, where a communication node with an internal temperature sensor is powered. Every 2 min, a data transmission at 868 MHz is performed by the sensor node supplied by the e-VEH, and received at a distance of up to 15 m.

  2. The Frequency Modification of Vibration for Multi-DOF Ultrasonic Motor%多自由度超声电机振动频率的修正

    Institute of Scientific and Technical Information of China (English)

    李小云; 张小凤; 郝君宇; 宋智广; 周方

    2012-01-01

    Multi-DOF ultrasonic motor is the combination of more than two ultrasonic vibration modes in accordance with a certain way. In this paper,the characteristics of the vibration of the complex pattern of vertical cylindrical curved multi-DOF ultrasonic motor are studied. The stator of the motor is composed of two groups of sandwich lamination oscillator. The motivation of one group of sandwich lamination piezoelectric voltage is to produce larger vertical vibration displacement; the other group of piezoelectric sandwich lamination, used to produce the two directions of the blending vibration, is composed of two longitudinal vibrations of piezoelectric patches and four bronze e-lectrodes. Referring to the calculated method of frequency of transducer, the frequency equation of motor longitudinal bending by the wave equation of the vertical bending vibration is derived. Considering the interactions of vertical bending vibration of the stator with multi-DOF, the frequency equation of motor longitudinal bending is modified. Comparing the theoretical results, the numerical simulation results and experimental results, the correctness of theoretical calculations is proved.%多自由度超声电机是将两种以上的超声振动模式按照一定的方式组合,通过在定子表面的椭圆运动实现转子的多自由度转动.该文对纵弯复合模式圆柱形多自由度超声电机的振动特性进行了研究,该电机的定子由两组夹心式振子组成:一组夹心式压电片在电压激励时能在纵向产生较大的振动位移;另一组夹心式压电片由2个纵向振动的压电片和4个铜电极组成,用于产生两个方向的弯曲振动.为了研究电机的工作特性,参照换能器频率的计算方法,通过纵弯振动的波动方程推导了电机纵弯振动频率方程,考虑多自由度工作时,电机定子纵弯振动的相互影响,对纵弯振动频率方程进行了修正,并将理论计算结果、数值仿真结果及实验测

  3. Effect of temperature on the low-frequency vibrational spectrum and relative structuring of hydration water around a single-stranded DNA.

    Science.gov (United States)

    Chakraborty, Kaushik; Bandyopadhyay, Sanjoy

    2015-01-07

    Molecular dynamics simulations of the single-stranded DNA oligomer (5'-CGCGAAT TCGCG-3') in aqueous solution have been carried out at different temperatures between 160 K and 300 K. The effects of temperature on the low-frequency vibrational spectrum and local structural arrangements of water molecules hydrating the DNA strand have been explored in detail. The low-frequency density of states distributions reveal that increasingly trapped transverse water motions play a dominant role in controlling the band corresponding to O⋯O⋯O bending or transverse oscillations of hydration water at supercooled temperatures. In addition, presence of a broad band around 260 (±20) cm(-1) under supercooled conditions indicates transformation from high density liquid-like structuring of hydration water at higher temperatures to that of a low density liquid at lower temperatures. It is found that long-range correlations between the supercooled hydration water molecules arise due to such local structural transition around the DNA oligomer.

  4. Shaping frequency response of a vibrating plate for passive and active control applications by simultaneous optimization of arrangement of additional masses and ribs. Part I: Modeling

    Science.gov (United States)

    Wrona, Stanislaw; Pawelczyk, Marek

    2016-03-01

    An ability to shape frequency response of a vibrating plate according to precisely defined demands has a very high practical potential. It can be applied to improve acoustic radiation of the plate for required frequencies or enhance acoustic isolation of noise barriers and device casings by using both passive and active control. The proposed method is based on mounting severaladditional ribs and masses (passive and/or active) to the plate surface at locations followed from an optimization process. This paper, Part I, concerns derivation of a mathematical model of the plate with attached elements in the function of their shape and placement. The model is validated by means of simulations and laboratory experiments, and compared with models known from the literature. This paper is followed by a companion paper, Part II, where the optimization process is described. It includes arrangement of passive elements as well as actuators and sensors to improve controllability and observability measures, if active control is concerned.

  5. Why fluorination of the polar heads reverses the positive sign of the dipole potential of Langmuir monolayers: a vibrational sum frequency spectroscopic study.

    Science.gov (United States)

    Karageorgiev, Peter; Petrov, Jordan G; Motschmann, Hubert; Moehwald, Helmuth

    2013-04-16

    Natural nonionic amphiphiles forming monolayers, bilayers, micelles, or biomembranes create a positive dipole potential at the boundary with water. In a series of papers we have reported on Langmuir monolayers with CF3 terminals of the polar heads, which show a negative surface dipole potential ΔV (Petrov , J. G.; Andreeva, T. D.; Kurt, D. K.; Möhwald, H. J. Phys. Chem. B 2005, 109, 14102). Here we use vibrational sum frequency spectroscopy (SF) to study the origin of the opposite ΔV signs of Langmuir films of CH3(CH2)20COCH2CH3 (ethyl ether, EE) and CH3(CH2)20COCH2CF3 (fluorinated ethyl ether, FEE). The vibrational sum frequency spectra are recorded at the same film density of the S-phase of the EE and FEE monolayers and analyzed in the spectral regions of OH, COC, CH3, and CF3 stretching vibrations because these functional groups could be responsible for the different dipole potentials. We compare the rearrangement of the pure water surface by EE and FEE monolayers and the conformations of EE and FEE polar heads. The analysis is performed according to the three-capacitor model of the dipole potential of Langmuir monolayers (Demchak, R. T.; Fort, T., Jr. J. Colloid Interface Sci. 1974, 46, 191). The results show that reversal of the ΔV sign caused by fluorination of the polar heads originates from the upward-oriented CF3 terminals of the FEE heads, whose negative normal dipole moment component determines the negative dipole potential of the FEE monolayer.

  6. Intrinsic chirality and prochirality at Air/R-(+)- and S-(-)-limonene interfaces: spectral signatures with interference chiral sum-frequency generation vibrational spectroscopy.

    Science.gov (United States)

    Fu, Li; Zhang, Yun; Wei, Zhe-Hao; Wang, Hong-Fei

    2014-09-01

    We report in this work detailed measurements of the chiral and achiral sum-frequency vibrational spectra in the C-H stretching vibration region (2800-3050 cm(-1)) of the air/liquid interfaces of R-(+)-limonene and S-(-)-limonene, using the recently developed high-resolution broadband sum-frequency generation vibrational spectroscopy (HR-BB-SFG-VS). The achiral SFG spectra of R-limonene and S-limonene, as well as the RS racemic mixture (50/50 equal amount mixture), show that the corresponding molecular groups of the R and S enantiomers are with the same interfacial orientations. The interference chiral SFG spectra of the limonene enantiomers exhibit a spectral signature from the chiral response of the Cα-H stretching mode, and a spectral signature from the prochiral response of the CH(2) asymmetric stretching mode, respectively. The chiral spectral feature of the Cα-H stretching mode changes sign from R-(+)-limonene to S-(-)-limonene surfaces, and disappears for the RS racemic mixture surface. While the prochiral spectral feature of the CH(2) asymmetric stretching mode is the same for R-(+)-limonene and S-(-)-limonene surfaces, and also surprisingly remains the same for the RS racemic mixture surface. Therefore, the structures of the R-(+)-limonene and the S-(-)-limonene at the liquid interfaces are nevertheless not mirror images to each other, even though the corresponding groups have the same tilt angle from the interfacial normal, i.e., the R-(+)-limonene and the S-(-)-limonene at the surface are diastereomeric instead of enantiomeric. These results provide detailed information in understanding the structure and chirality of molecular interfaces and demonstrate the sensitivity and potential of SFG-VS as a unique spectroscopic tool for chirality characterization and chiral recognition at the molecular interface.

  7. Solvent-induced red-shifts for the proton stretch vibrational frequency in a hydrogen-bonded complex. 1. A valence bond-based theoretical approach.

    Science.gov (United States)

    Kiefer, Philip M; Pines, Ehud; Pines, Dina; Hynes, James T

    2014-07-17

    A theory is presented for the proton stretch vibrational frequency νAH for hydrogen (H-) bonded complexes of the acid dissociation type, that is, AH···B ⇔ A(-)···HB(+)(but without complete proton transfer), in both polar and nonpolar solvents, with special attention given to the variation of νAH with the solvent's dielectric constant ε. The theory involves a valence bond (VB) model for the complex's electronic structure, quantization of the complex's proton and H-bond motions, and a solvent coordinate accounting for nonequilibrium solvation. A general prediction is that νAH decreases with increasing ε largely due to increased solvent stabilization of the ionic VB structure A(-)···HB(+) relative to the neutral VB structure AH···B. Theoretical νAH versus 1/ε slope expressions are derived; these differ for polar and nonpolar solvents and allow analysis of the solvent dependence of νAH. The theory predicts that both polar and nonpolar slopes are determined by (i) a structure factor reflecting the complex's size/geometry, (ii) the complex's dipole moment in the ground vibrational state, and (iii) the dipole moment change in the transition, which especially reflects charge transfer and the solution phase proton potential shapes. The experimental proton frequency solvent dependence for several OH···O H-bonded complexes is successfully accounted for and analyzed with the theory.

  8. Molecular structure, Normal Coordinate Analysis, harmonic vibrational frequencies, Natural Bond Orbital, TD-DFT calculations and biological activity analysis of antioxidant drug 7-hydroxycoumarin

    Science.gov (United States)

    Sebastian, S.; Sylvestre, S.; Jayarajan, D.; Amalanathan, M.; Oudayakumar, K.; Gnanapoongothai, T.; Jayavarthanan, T.

    2013-01-01

    In this work, we report harmonic vibrational frequencies, molecular structure, NBO and HOMO, LUMO analysis of Umbelliferone also known as 7-hydroxycoumarin (7HC). The optimized geometric bond lengths and bond angles obtained by computation (monomer and dimmer) shows good agreement with experimental XRD data. Harmonic frequencies of 7HC were determined and analyzed by DFT utilizing 6-311+G(d,p) as basis set. The assignments of the vibrational spectra have been carried out with the help of Normal Coordinate Analysis (NCA) following the Scaled Quantum Mechanical Force Field Methodology (SQMFF). The change in electron density (ED) in the σ* and π* antibonding orbitals and stabilization energies E(2) have been calculated by Natural Bond Orbital (NBO) analysis to give clear evidence of stabilization originating in the hyperconjugation of hydrogen-bonded interaction. The energy and oscillator strength calculated by Time-Dependent Density Functional Theory (TD-DFT) complements with the experimental findings. The simulated spectra satisfactorily coincides with the experimental spectra. Microbial activity of studied compounds was tested against Staphylococcus aureus, Streptococcus pyogenes, Bacillus subtilis, Escherichia coli, Psuedomonas aeruginosa, Klebsiella pneumoniae, Proteus mirabilis, Shigella flexneri, Salmonella typhi and Enterococcus faecalis.

  9. Using high-frequency vibrations and non-linear inclusions to create metamaterials with adjustable effective properties

    DEFF Research Database (Denmark)

    Lazarov, Boyan Stefanov; Thomsen, Jon Juel

    2009-01-01

    We investigate how high-frequency (HF) excitation combined with strongly non-linear elasticity may influence the effective properties for low-frequency wave propagation. The HF effects are demonstrated for linear spring-mass chains with embedded non-linear parts. The investigated mechanical systems...

  10. Orbital-optimized coupled-electron pair theory and its analytic gradients: accurate equilibrium geometries, harmonic vibrational frequencies, and hydrogen transfer reactions.

    Science.gov (United States)

    Bozkaya, Uğur; Sherrill, C David

    2013-08-07

    Orbital-optimized coupled-electron pair theory [or simply "optimized CEPA(0)," OCEPA(0), for short] and its analytic energy gradients are presented. For variational optimization of the molecular orbitals for the OCEPA(0) method, a Lagrangian-based approach is used along with an orbital direct inversion of the iterative subspace algorithm. The cost of the method is comparable to that of CCSD [O(N(6)) scaling] for energy computations. However, for analytic gradient computations the OCEPA(0) method is only half as expensive as CCSD since there is no need to solve the λ2-amplitude equation for OCEPA(0). The performance of the OCEPA(0) method is compared with that of the canonical MP2, CEPA(0), CCSD, and CCSD(T) methods, for equilibrium geometries, harmonic vibrational frequencies, and hydrogen transfer reactions between radicals. For bond lengths of both closed and open-shell molecules, the OCEPA(0) method improves upon CEPA(0) and CCSD by 25%-43% and 38%-53%, respectively, with Dunning's cc-pCVQZ basis set. Especially for the open-shell test set, the performance of OCEPA(0) is comparable with that of CCSD(T) (ΔR is 0.0003 Å on average). For harmonic vibrational frequencies of closed-shell molecules, the OCEPA(0) method again outperforms CEPA(0) and CCSD by 33%-79% and 53%-79%, respectively. For harmonic vibrational frequencies of open-shell molecules, the mean absolute error (MAE) of the OCEPA(0) method (39 cm(-1)) is fortuitously even better than that of CCSD(T) (50 cm(-1)), while the MAEs of CEPA(0) (184 cm(-1)) and CCSD (84 cm(-1)) are considerably higher. For complete basis set estimates of hydrogen transfer reaction energies, the OCEPA(0) method again exhibits a substantially better performance than CEPA(0), providing a mean absolute error of 0.7 kcal mol(-1), which is more than 6 times lower than that of CEPA(0) (4.6 kcal mol(-1)), and comparing to MP2 (7.7 kcal mol(-1)) there is a more than 10-fold reduction in errors. Whereas the MAE for the CCSD method is

  11. The effect of weight-bearing exercise with low frequency, whole body vibration on lumbosacral proprioception: a pilot study on normal subjects.

    Science.gov (United States)

    Fontana, Tania L; Richardson, Carolyn A; Stanton, Warren R

    2005-01-01

    Patients with low back pain (LBP) often present with impaired proprioception of the lumbopelvic region. For this reason, proprioception training usually forms part of the rehabilitation protocols. New exercise equipment that produces whole body, low frequency vibration (WBV) has been developed to improve muscle function, and reportedly improves proprioception. The aim of this pilot study was to investigate whether weightbearing exercise given in conjunction with WBV would affect lumbosacral position sense in healthy individuals. For this purpose, twenty-five young individuals with no LBP were assigned randomly to an experimental or control group. The experimental group received WBV for five minutes while holding a static, semi-squat position. The control group adopted the same weightbearing position for equal time but received no vibration. A two-dimensional motion analysis system measured the repositioning accuracy of pelvic tilting in standing. The experimental (WBV) group demonstrated a significant improvement in repositioning accuracy over time (mean 0.78 degrees) representing 39% improvement. It was concluded that WBV may induce improvements in lumbosacral repositioning accuracy when combined with a weightbearing exercise. Future studies with WBV should focus on evaluating its effects with different types of exercise, the exercise time needed for optimal outcomes, and the effects on proprioception deficits in LBP patients.

  12. Vibrational Dynamics of Interfacial Water by Free Induction Decay Sum Frequency Generation (FID-SFG) at the Al2O3(1120)/H2O Interface.

    Science.gov (United States)

    Boulesbaa, Abdelaziz; Borguet, Eric

    2014-02-06

    The dephasing dynamics of a vibrational coherence may reveal the interactions of chemical functional groups with their environment. To investigate this process at a surface, we employ free induction decay sum frequency generation (FID-SFG) to measure the time that it takes for free OH stretch oscillators at the charged (pH ≈ 13, KOH) interface of alumina/water (Al2O3/H2O) to lose their collective coherence. By employing noncollinear optical parametric amplification (NOPA) technology and nonlinear vibrational spectroscopy, we showed that the single free OH peak actually corresponds to two distinct oscillators oriented opposite to each other and measured the total dephasing time, T2, of the free OH stretch modes at the Al2O3/H2O interface with a sub-40 fs temporal resolution. Our results suggested that the free OH oscillators associated with interfacial water dephase on the time scale of 89.4 ± 6.9 fs, whereas the homogeneous dephasing of interfacial alumina hydroxyls is an order of magnitude slower.

  13. Influence of PtMo Structure and Composition on the Adsorption Energies, Adsorption Site and Vibrational Frequency of Carbon Monoxide

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    Density functional theory periodic slab calculations were carried out for CO adsorption on a series of Mo modified Pt(111) surfaces to provide an insight into the interaction between CO and doped metal surface, an important issue in CO oxidation as well as in promotion and poisoning effects of catalysis. The modification of adsorption properties with respect to those of adsorption on the pure Mo(110) and Pt(111) is described in terms of changes in the adsorption energies, adsorption sites and vibrational properties occurring upon alloying. We believe that the present DFT calculations can provide important information into optimal alloy composition for CO-tolerance, which is not easily obtained by experimental methods.

  14. Predicting the structure and vibrational frequencies of ethylene using harmonic and anharmonic approaches at the Kohn-Sham complete basis set limit.

    Science.gov (United States)

    Buczek, Aneta; Kupka, Teobald; Broda, Małgorzata A; Żyła, Adriana

    2016-01-01

    In this work, regular convergence patterns of the structural, harmonic, and VPT2-calculated anharmonic vibrational parameters of ethylene towards the Kohn-Sham complete basis set (KS CBS) limit are demonstrated for the first time. The performance of the VPT2 scheme implemented using density functional theory (DFT-BLYP and DFT-B3LYP) in combination with two Pople basis sets (6-311++G** and 6-311++G(3df,2pd)), the polarization-consistent basis sets pc-n, aug-pc-n, and pcseg-n (n = 0, 1, 2, 3, 4), and the correlation-consistent basis sets cc-pVXZ and aug-cc-pVXZ (X = D, T, Q, 5, 6) was tested.The BLYP-calculated harmonic frequencies were found to be markedly closer than the B3LYP-calculated harmonic frequencies to the experimentally derived values, while the calculated anharmonic frequencies consistently underestimated the observed wavenumbers. The different basis set families gave very similar estimated values for the CBS parameters. The anharmonic frequencies calculated with B3LYP/aug-pc-3 were consistently significantly higher than those obtained with the pc-3 basis set; applying the aug-pcseg-n basis set family alleviated this problem. Utilization of B3LYP/aug-pcseg-n basis sets instead of B3LYP/aug-cc-pVXZ, which is computationally less expensive, is suggested for medium-sized molecules. Harmonic BLYP/pc-2 calculations produced fairly accurate ethylene frequencies. Graphical Abstract In this study, the performance of the VPT2 scheme implemented using density functional theory (DFT-BLYP and DFT-B3LYP) in combination with the polarization-consistent basis sets pc-n, aug-pc-n, and pcseg-n (n = 0, 1, 2, 3, 4), and the correlation-consistent basis sets cc-pVXZ and aug-cc-pVXZ (X = D, T, Q, 5, and 6) was tested. For the first time, we demonstrated regular convergence patterns of the structural, harmonic, and VPT2-calculated anharmonic vibrational parameters of ethylene towards the Kohn-Sham complete basis set (KS CBS) limit.

  15. Sum Frequency Generation Vibrational Spectroscopy and Kinetic Study of 2-Methylfuran and 2,5-Dimethylfuran Hydrogenation over 7 nm Platinum Cubic Nanoparticles

    KAUST Repository

    Aliaga, Cesar

    2011-04-28

    Sum frequency generation vibrational spectroscopy and kinetic measurements obtained from gas chromatography were used to study the adsorption and hydrogenation of 2-methylfuran (MF) and 2,5-dimethylfuran (DMF) over cubic Pt nanoparticles of 7 nm average size, synthesized by colloidal methods and cleaned by ultraviolet light and ozone treatment. Reactions carried out at atmospheric pressure in the temperature range of 20-120 °C produced dihydro and tetrahydro species, as well as ring-opening products (alcohols) and ring-cracking products, showing high selectivity toward ring opening throughout the entire temperature range. The aromatic rings (MF and DMF) adsorbed parallel to the nanoparticle surface. Results yield insight into various surface reaction intermediates and the reason for the significantly lower selectivity for ring cracking in DMF hydrogenation compared to MF hydrogenation. © 2011 American Chemical Society.

  16. Novel SiO2-deposited CaF2 substrate for vibrational sum-frequency generation (SFG) measurements of chemisorbed monolayers in an aqueous environment.

    Science.gov (United States)

    Padermshoke, Adchara; Konishi, Shouta; Ara, Masato; Tada, Hirokazu; Ishibashi, Taka-Aki

    2012-06-01

    A novel SiO(2)-deposited CaF(2) (SiO(2)/CaF(2)) substrate for measuring vibrational sum-frequency generation (SFG) spectra of silane-based chemisorbed monolayers in aqueous media has been developed. The substrate is suitable for silanization and transparent over a broad range of the infrared (IR) probe. The present work demonstrates the practical application of the SiO(2)/CaF(2) substrate and, to our knowledge, the first SFG spectrum at the solid/water interface of a silanized monolayer observed over the IR fingerprint region (1780-1400 cm(-1)) using a back-side probing geometry. This new substrate can be very useful for SFG studies of various chemisorbed organic molecules, particularly biological compounds, in aqueous environments.

  17. Sum frequency generation vibrational spectroscopy (SFG-VS) for complex molecular surfaces and interfaces: Spectral lineshape measurement and analysis plus some controversial issues

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Hong-Fei

    2016-12-01

    Sum-frequency generation vibrational spectroscopy (SFG-VS) was first developed in the 1980s and it has been proven a uniquely sensitive and surface/interface selective spectroscopic probe for characterization of the structure, conformation and dynamics of molecular surfaces and interfaces. In recent years, there has been significant progress in the development of methodology and instrumentation in the SFG-VS toolbox that has significantly broadened the application to complex molecular surfaces and interfaces. In this review, after presenting a unified view on the theory and methodology focusing on the SFG-VS spectral lineshape, as well as the new opportunities in SFG-VS applications with such developments, some of the controversial issues that have been puzzling the community are to be discussed. The aim of this review is to present to the researchers and students interested in molecular surfaces and interfacial sciences up-to-date perspectives complementary to the existing textbooks and reviews on SFG-VS.

  18. Investigation of analytical potential energy function, harmonic frequency and vibrational levels for the X2∑+ and A2∏ states of CN radical

    Institute of Scientific and Technical Information of China (English)

    Wang Jian-Kun; Wu Zhen-Sen

    2008-01-01

    This paper calculates the equilibrium structure and the potential energy functions of the ground state (X2∑+) and the low lying excited electronic state (A2∏) of CN radical are calculated by using CASSCF method. The potential energy curves are obtained by a least square fitting to the modified Murrell-Sorbie function. On the basis of physical theory of potential energy function, harmonic frequency (ωe) and other spectroscopic constants (ωeχe, βe and αe) are calculated by employing the Rydberg-Klein-Rees method. The theoretical calculation results are in excellent agreement with the experimental and other complicated theoretical calculation data. In addition, the eigenvalues of vibrational levels have been calculated by solving the radial one-dimensional Schrodinger equation of nuclear motion using the algebraic method based on the analytical potential energy function.

  19. Sum frequency generation vibrational spectroscopy (SFG-VS) for complex molecular surfaces and interfaces: Spectral lineshape measurement and analysis plus some controversial issues

    Science.gov (United States)

    Wang, Hong-Fei

    2016-12-01

    Sum-frequency generation vibrational spectroscopy (SFG-VS) was first developed in the 1980s and it has been proven a uniquely sensitive and surface/interface selective spectroscopic probe for characterization of the structure, conformation and dynamics of molecular surfaces and interfaces. In recent years, there have been many progresses in the development of methodology and instrumentation in the SFG-VS toolbox that have significantly broadened the application to complex molecular surfaces and interfaces. In this review, after presenting a unified view on the theory and methodology focusing on the SFG-VS spectral lineshape, as well as the new opportunities in SFG-VS applications with such developments, some of the controversial issues that have been puzzling the community are discussed. The aim of this review is to present to the researchers and students interested in molecular surfaces and interfacial sciences up-to-date perspectives complementary to the existing textbooks and reviews on SFG-VS.

  20. Harmonic Vibrational Frequencies: Approximate Global Scaling Factors for TPSS, M06, and M11 Functional Families Using Several Common Basis Sets.

    Science.gov (United States)

    Kashinski, D O; Chase, G M; Nelson, R G; Di Nallo, O E; Scales, A N; VanderLey, D L; Byrd, E F C

    2017-03-23

    We propose new approximate global multiplicative scaling factors for the DFT calculation of ground state harmonic vibrational frequencies using functionals from the TPSS, M06, and M11 functional families with standard correlation consistent cc-pVxZ and aug-cc-pVxZ (x = D, T, and Q), 6-311G split valence family, Sadlej and Sapporo polarized triple-ζ basis sets. Results for B3LYP, CAM-B3LYP, B3PW91, PBE, and PBE0 functionals with these basis sets are also reported. A total of 99 harmonic frequencies were calculated for 26 gas-phase organic and nonorganic molecules typically found in detonated solid propellant residue. Our proposed approximate multiplicative scaling factors are determined using a least-squares approach comparing the computed harmonic frequencies to experimental counterparts well established in the scientific literature. A comparison of our work to previously published global scaling factors is made to verify method reliability and the applicability of our molecular test set.

  1. Frequency and zero-point vibrational energy scale factors for double-hybrid density functionals (and other selected methods): can anharmonic force fields be avoided?

    Science.gov (United States)

    Kesharwani, Manoj K; Brauer, Brina; Martin, Jan M L

    2015-03-05

    We have obtained uniform frequency scaling factors λ(harm) (for harmonic frequencies), λ(fund) (for fundamentals), and λ(ZPVE) (for zero-point vibrational energies (ZPVEs)) for the Weigend-Ahlrichs and other selected basis sets for MP2, SCS-MP2, and a variety of DFT functionals including double hybrids. For selected levels of theory, we have also obtained scaling factors for true anharmonic fundamentals and ZPVEs obtained from quartic force fields. For harmonic frequencies, the double hybrids B2PLYP, B2GP-PLYP, and DSD-PBEP86 clearly yield the best performance at RMSD = 10-12 cm(-1) for def2-TZVP and larger basis sets, compared to 5 cm(-1) at the CCSD(T) basis set limit. For ZPVEs, again, the double hybrids are the best performers, reaching root-mean-square deviations (RMSDs) as low as 0.05 kcal/mol, but even mainstream functionals like B3LYP can get down to 0.10 kcal/mol. Explicitly anharmonic ZPVEs only are marginally more accurate. For fundamentals, however, simple uniform scaling is clearly inadequate.

  2. Catalyzed hydrogenation of nitrogen and ethylene on metal (Fe, Pt) single crystal surfaces and effects of coadsorption: A sum frequency generation vibrational spectroscopy study

    Energy Technology Data Exchange (ETDEWEB)

    Westerberg, Staffan Per Gustav [Univ. of California, Berkeley, CA (United States)

    2004-01-01

    High-pressure catalytic reactions and associated processes, such as adsorption have been studied on a molecular level on single crystal surfaces. Sum Frequency Generation (SFG) vibrational spectroscopy together with Auger Electron Spectroscopy (AES), Temperature Programmed Desorption (TPD) and Gas Chromatography (GC) were used to investigate the nature of species on catalytic surfaces and to measure the catalytic reaction rates. Special attention has been directed at studying high-pressure reactions and in particular, ammonia synthesis in order to identify reaction intermediates and the influence of adsorbates on the surface during reaction conditions. The adsorption of gases N2, H2, O2 and NH3 that play a role in ammonia synthesis have been studied on the Fe(111) crystal surface by sum frequency generation vibrational spectroscopy using an integrated Ultra-High Vacuum (UHV)/high-pressure system. SFG spectra are presented for the dissociation intermediates, NH2 (~3325 cm-1) and NH (~3235 cm-1) under high pressure of ammonia (200 Torr) on the clean Fe(111) surface. Addition of 0.5 Torr of oxygen to 200 Torr of ammonia does not significantly change the bonding of dissociation intermediates to the surface. However, it leads to a phase change of nearly 180° between the resonant and non-resonant second order non-linear susceptibility of the surface, demonstrated by the reversal of the SFG spectral features. Heating the surface in the presence of 200 Torr ammonia and 0.5 Torr oxygen reduces the oxygen coverage, which can be seen from the SFG spectra as another relative phase change of 180°. The reduction of the oxide is also supported by Auger electron spectroscopy. The result suggests that the phase change of the spectral features could serve as a sensitive indicator of the chemical environment of the adsorbates.

  3. Catalyzed hydrogenation of nitrogen and ethylene on metal (Fe, Pt) single crystal surfaces and effects of coadsorption: A sum frequency generation vibrational spectroscopy study

    Energy Technology Data Exchange (ETDEWEB)

    Westerberg, Staffan Per Gustav

    2004-12-15

    High-pressure catalytic reactions and associated processes, such as adsorption have been studied on a molecular level on single crystal surfaces. Sum Frequency Generation (SFG) vibrational spectroscopy together with Auger Electron Spectroscopy (AES), Temperature Programmed Desorption (TPD) and Gas Chromatography (GC) were used to investigate the nature of species on catalytic surfaces and to measure the catalytic reaction rates. Special attention has been directed at studying high-pressure reactions and in particular, ammonia synthesis in order to identify reaction intermediates and the influence of adsorbates on the surface during reaction conditions. The adsorption of gases N{sub 2}, H{sub 2}, O{sub 2} and NH{sub 3} that play a role in ammonia synthesis have been studied on the Fe(111) crystal surface by sum frequency generation vibrational spectroscopy using an integrated Ultra-High Vacuum (UHV)/high-pressure system. SFG spectra are presented for the dissociation intermediates, NH{sub 2} ({approx}3325 cm{sup -1}) and NH ({approx}3235 cm{sup -1}) under high pressure of ammonia (200 Torr) on the clean Fe(111) surface. Addition of 0.5 Torr of oxygen to 200 Torr of ammonia does not significantly change the bonding of dissociation intermediates to the surface. However, it leads to a phase change of nearly 180{sup o} between the resonant and non-resonant second order non-linear susceptibility of the surface, demonstrated by the reversal of the SFG spectral features. Heating the surface in the presence of 200 Torr ammonia and 0.5 Torr oxygen reduces the oxygen coverage, which can be seen from the SFG spectra as another relative phase change of 180{sup o}. The reduction of the oxide is also supported by Auger electron spectroscopy. The result suggests that the phase change of the spectral features could serve as a sensitive indicator of the chemical environment of the adsorbates.

  4. A Forced Vibration Non-Resonant Method for the Determination of Complex Modulus in the Audio Frequency Range

    Science.gov (United States)

    1992-01-01

    water -borne sound when used in anechoic coatings1 . The frequency and temperature dependence of the viscoelastic properties of polymers is essential...strain on the sample, 8: E t11=tan 8- E’ - tanq ) [8] In this case the measured phase angle, p, is identical with 8, the angle between stress and strain

  5. Acute and cumulative effects of focused high-frequency vibrations on the endocrine system and muscle strength.

    Science.gov (United States)

    Iodice, Pierpaolo; Bellomo, Rosa Grazia; Gialluca, Glaugo; Fanò, Giorgio; Saggini, Raoul

    2011-06-01

    The purpose of this study was to evaluate the acute and long-term effects of local high-intensity vibration (HLV, f = 300 Hz) on muscle performance and blood hormone concentrations in healthy young men. Totally 18 subjects (cV group) were studied in two sessions, either without (control) or with HLV treatment. The protocol was the same on both control and test days, except that, in the second session, subjects underwent HLV treatment. Counter-movement jumping (CMJ), maximal isometric voluntary contraction (MVC) test, and hormonal levels were measured before the procedure, immediately thereafter, and 1 h later. To assess the long-term effects of HLV, the cV group was subjected to HLV on the leg muscles for 4 weeks, and a second group (cR group, n = 18) embarked upon a resistance training program. All subjects underwent an MVC test and an isokinetic (100 deg/s) test before training, 4 weeks after training, and 2 months after the end of training. The HLV protocol significantly increased the serum level of growth hormone (GH, P neuromuscular performance. Our results indicate that HLV has a long-term beneficial effect comparable to that of resistance training.

  6. Palladium(II) and platinum(II) complexes containing benzimidazole ligands: Molecular structures, vibrational frequencies and cytotoxicity

    Science.gov (United States)

    Abdel Ghani, Nour T.; Mansour, Ahmed M.

    2011-04-01

    (1H-benzimidazol-2-ylmethyl)-(4-methoxyl-phenyl)-amine (L 1), (1H-benzimidazol-2-ylmethyl)-(4-methyl-phenyl)-amine (L 2) and their Pd(II) and Pt(II) complexes have been synthesized as potential anticancer compounds and their structures were elucidated using a variety of physico-chemical techniques. Theoretical calculations invoking geometry optimization, vibrational assignments, 1H NMR, charge distribution and molecular orbital description HOMO and LUMO were done using density functional theory. Natural bond orbital analysis (NBO) method was performed to provide details about the type of hybridization and the nature of bonding in the studied complexes. Strong coordination bonds (LP(1)N11 → σ *(M sbnd Cl22)) and (LP(1)N21 → σ *(M sbnd Cl23)) (M = Pd or Pt) result from donation of electron density from a lone pair orbital on the nitrogen atoms to the acceptor metal molecular orbitals. The experimental results and the calculated molecular parameters revealed square-planar geometries around the metallic centre through the pyridine-type nitrogen of the benzimidazole ring and secondary amino group and two chlorine atoms. The activation thermodynamic parameters were calculated using non-isothermal methods. The synthesized ligands, in comparison to their metal complexes were screened for their antibacterial activity. In addition, the studied complexes showed activity against three cell lines of different origin, breast cancer (MCF-7), Colon Carcinoma (HCT) and human heptacellular carcinoma (Hep-G2) comparable to cis-platin.

  7. VIBRATION ISOLATION SYSTEM PROBABILITY ANALYSIS

    Directory of Open Access Journals (Sweden)

    Smirnov Vladimir Alexandrovich

    2012-10-01

    Full Text Available The article deals with the probability analysis for a vibration isolation system of high-precision equipment, which is extremely sensitive to low-frequency oscillations even of submicron amplitude. The external sources of low-frequency vibrations may include the natural city background or internal low-frequency sources inside buildings (pedestrian activity, HVAC. Taking Gauss distribution into account, the author estimates the probability of the relative displacement of the isolated mass being still lower than the vibration criteria. This problem is being solved in the three dimensional space, evolved by the system parameters, including damping and natural frequency. According to this probability distribution, the chance of exceeding the vibration criteria for a vibration isolation system is evaluated. Optimal system parameters - damping and natural frequency - are being developed, thus the possibility of exceeding vibration criteria VC-E and VC-D is assumed to be less than 0.04.

  8. Specific features of low-frequency vibrational dynamics and low-temperature heat capacity of double-walled carbon nanotubes

    Science.gov (United States)

    Avramenko, M. V.; Roshal, S. B.

    2016-05-01

    A continuous model has been constructed for low-frequency dynamics of a double-walled carbon nanotube. The formation of the low-frequency part of the phonon spectrum of a double-walled nanotube from phonon spectra of its constituent single-walled nanotubes has been considered in the framework of the proposed approach. The influence of the environment on the phonon spectrum of a single double-walled carbon nanotube has been analyzed. A combined method has been proposed for estimating the coefficients of the van der Waals interaction between the walls of the nanotube from the spectroscopic data and the known values of the elastic moduli of graphite. The low-temperature specific heat has been calculated for doublewalled carbon nanotubes, which in the field of applicability of the model ( T nanotubes forming it.

  9. Understanding Chemical Sensitivity and Surface Response in Detecting Trace Levels of Explosives Using Vibrational Sum Frequency Spectroscopy

    Science.gov (United States)

    2013-11-04

    does not degrade contaminants on surfaces, a positive detection result leaves any explosives detected in place for subsequent forensic analysis...applications. Optical sum-frequency generation (SFG) has long been used for studying surface chemistry [Lambert et al., 2005; Shen, 2000]. SFG is...present on surfaces at low concentrations, surface selectivity and high sensitivity to surface chemistry are key advantages of VSFS in detecting HEs

  10. Direct comparison of phase-sensitive vibrational sum frequency generation with maximum entropy method: case study of water.

    Science.gov (United States)

    de Beer, Alex G F; Samson, Jean-Sebastièn; Hua, Wei; Huang, Zishuai; Chen, Xiangke; Allen, Heather C; Roke, Sylvie

    2011-12-14

    We present a direct comparison of phase sensitive sum-frequency generation experiments with phase reconstruction obtained by the maximum entropy method. We show that both methods lead to the same complex spectrum. Furthermore, we discuss the strengths and weaknesses of each of these methods, analyzing possible sources of experimental and analytical errors. A simulation program for maximum entropy phase reconstruction is available at: http://lbp.epfl.ch/.

  11. Multi-frequency Operation of a MEMS Vibration Energy Harvester by Accessing Five Orders of Parametric Resonance

    Science.gov (United States)

    Jia, Y.; Yan, J.; Soga, K.; Seshia, A. A.

    2013-12-01

    The mechanical amplification effect of parametric resonance has the potential to outperform direct resonance by over an order of magnitude in terms of power output. However, the excitation must first overcome the damping-dependent initiation threshold amplitude prior to accessing this more profitable region. In addition to activating the principal (1st order) parametric resonance at twice the natural frequency ω0, higher orders of parametric resonance may be accessed when the excitation frequency is in the vicinity of 2ω0/n for integer n. Together with the passive design approaches previously developed to reduce the initiation threshold to access the principal parametric resonance, vacuum packaging (< 10 torr) is employed to further reduce the threshold and unveil the higher orders. A vacuum packaged MEMS electrostatic harvester (0.278 mm3) exhibited 4 and 5 parametric resonance peaks at room pressure and vacuum respectively when scanned up to 10 g. At 5.1 ms-2, a peak power output of 20.8 nW and 166 nW is recorded for direct and principal parametric resonance respectively at atmospheric pressure; while a peak power output of 60.9 nW and 324 nW is observed for the respective resonant peaks in vacuum. Additionally, unlike direct resonance, the operational frequency bandwidth of parametric resonance broadens with lower damping.

  12. Effect of Solvent Dielectric Constant and Acidity on the OH Vibration Frequency in Hydrogen-Bonded Complexes of Fluorinated Ethanols.

    Science.gov (United States)

    Pines, Dina; Keinan, Sharon; Kiefer, Philip M; Hynes, James T; Pines, Ehud

    2015-07-23

    Infrared spectroscopy measurements were used to characterize the OH stretching vibrations in a series of similarly structured fluoroethanols, RCH2OH (R = CH3, CH2F, CHF2, CF3), a series which exhibits a systematic increase in the molecule acidity with increasing number of F atoms. This study, which expands our earlier efforts, was carried out in non-hydrogen-bonding solvents comprising molecules with and without a permanent dipole moment, with the former solvents being classified as polar solvents and the latter designated as nonpolar. The hydrogen bond interaction in donor-acceptor complexes formed in solution between the fluorinated ethanol H-donors and the H-acceptor base DMSO was investigated in relation to the solvent dielectric and to the differences ΔPA of the gas phase proton affinities (PAs) of the conjugate base of the fluorinated alcohols and DMSO. We have observed that νOH decreases as the acidity of the alcohol increases (ΔPA decreases) and that νOH varies inversely with ε, exhibiting different slopes for nonpolar and polar solvents. These 1/ε slopes tend to vary linearly with ΔPA, increasing with increasing acidity. These experimental findings, including the ΔPA trends, are described with our recently published two-state Valence Bond-based theory for acid-base H-bonded complexes. Lastly, the correlation of the alcohol's conjugate base PAs with Taft σ* values of the fluorinated ethyl groups CH(n)F(3-n)CH2- provides a connection of the inductive effects for these groups with the acidity parameter ΔPA associated with the H-bonded complexes.

  13. Anomalous effective polarity of an air/liquid-mixture interface: a heterodyne-detected electronic and vibrational sum frequency generation study.

    Science.gov (United States)

    Mondal, Sudip Kumar; Inoue, Ken-ichi; Yamaguchi, Shoichi; Tahara, Tahei

    2015-10-07

    We study the effective polarity of an air/liquid-mixture interface by using interface-selective heterodyne-detected electronic sum frequency generation (HD-ESFG) and vibrational sum frequency generation (HD-VSFG) spectroscopies. With water and N,N-dimethylformamide (DMF) chosen as two components of the liquid mixture, the bulk polarity of the mixture is controlled nearly arbitrarily by the mixing ratio. The effective polarity of the air/mixture interface is evaluated by HD-ESFG with a surface-active solvatochromic molecule used as a polarity indicator. Surprisingly, the interfacial effective polarity of the air/mixture interface increases significantly, when the bulk polarity of the mixture decreases (i.e. when the fraction of DMF increases). Judging from the hydrogen-bond structure at the air/mixture interface clarified by HD-VSFG, this anomalous change of the interfacial effective polarity is attributed to the interface-specific solvation structure around the indicator molecule at the air/mixture interface.

  14. Vibration Propagation in Spider Webs

    Science.gov (United States)

    Hatton, Ross; Otto, Andrew; Elias, Damian

    Due to their poor eyesight, spiders rely on web vibrations for situational awareness. Web-borne vibrations are used to determine the location of prey, predators, and potential mates. The influence of web geometry and composition on web vibrations is important for understanding spider's behavior and ecology. Past studies on web vibrations have experimentally measured the frequency response of web geometries by removing threads from existing webs. The full influence of web structure and tension distribution on vibration transmission; however, has not been addressed in prior work. We have constructed physical artificial webs and computer models to better understand the effect of web structure on vibration transmission. These models provide insight into the propagation of vibrations through the webs, the frequency response of the bare web, and the influence of the spider's mass and stiffness on the vibration transmission patterns. Funded by NSF-1504428.

  15. 高频电液振动台振动特性实验研究*%Experimental Research on Vibration Characteristics of High-frequency Electro-hydraulic Shaking Table

    Institute of Scientific and Technical Information of China (English)

    李伟荣; 阮健

    2013-01-01

    The vibration frequency of traditional electro-hydraulic shaking table is very difficult to rise a higher range due to restriction of working frequency of servo valve. Therefore the high-frequency electro-hydraulic shaking table based on 2D exciting valve was proposed. Because 2D exciting valve is a special rotating valve, the vibration fre-quency of electro-hydraulic shaking table can be enhanced largely through improving the rotating speed of spool of 2D exciting valve. The scheme of high-frequency electro-hydraulic shaking table was analyzed and the mathemati-cal model was built. In order to verify the theoretical analysis and the real vibration waveform of high-frequency electro-hydraulic shaking table, the high-frequency electro-hydraulic shaking table was designed and experimented. Experimental results show the high-frequency electro-hydraulic shaking table based on 2D exciting valve can im-prove the working frequency highly, and the vibration frequency of high-frequency electro-hydraulic shaking table can realize 1 000 Hz, far higher than the vibration frequency of traditional electro-hydraulic shaking table.%  传统电液振动台由于受伺服阀频响特性的限制,其工作频率难以提高到较高的水平。为此提出一种基于2D激振阀的高频电液振动台,由于2D激振阀是一种特殊结构的转阀,通过提高2D激振阀阀芯的转速可以使电液振动台的工作频率实现大幅提高。分析了高频电液振动台的工作原理,并建立了其数学模型,为了验证理论分析以及高频电液振动台工作时的实际输出振动波形,设计了高频电液振动台并进行了实验研究。实验结果表明:基于2D激振阀的电液振动台能大幅提高振动频率,振动台输出的振动频率达到800 Hz,远远高于现有传统电液振动台的振动频率。

  16. Thermal Vibrational Convection

    Science.gov (United States)

    Gershuni, G. Z.; Lyubimov, D. V.

    1998-08-01

    Recent increasing awareness of the ways in which vibrational effects can affect low-gravity experiments have renewed interest in the study of thermal vibrational convection across a wide range of fields. For example, in applications where vibrational effects are used to provide active control of heat and mass transfer, such as in heat exchangers, stirrers, mineral separators and crystal growth, a sound understanding of the fundamental theory is required. In Thermal Vibrational Convection, the authors present the theory of vibrational effects caused by a static gravity field, and of fluid flows which appear under vibration in fluid-filled cavities. The first part of the book discusses fluid-filled cavities where the fluid motion only appears in the presence of temperature non-uniformities, while the second considers those situations where the vibrational effects are caused by a non-uniform field. Throughout, the authors concentrate on consideration of high frequency vibrations, where averaging methods can be successfully applied in the study of the phenomena. Written by two of the pioneers in this field, Thermal Vibrational Convection will be of great interest to scientists and engineers working in the many areas that are concerned with vibration, and its effect on heat and mass transfer. These include hydrodynamics, hydro-mechanics, low gravity physics and mechanics, and geophysics. The rigorous approach adopted in presenting the theory of this fascinating and highly topical area will facilitate a greater understanding of the phenomena involved, and will lead to the development of more and better-designed experiments.

  17. Probing the structure and nano-scale mechanical properties of polymer surfaces with scanning force microscopy and sum frequency vibrational spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Gracias, David Hugo [Univ. of California, Berkeley, CA (United States)

    1999-05-01

    Scanning Force Microscopy (SFM) has been used to quantitatively measure the elastic modulus, friction and hardness of polymer surfaces with special emphasis on polyethylene and polypropylene. In the experiments, tips of different radii of curvature ranging from 20 nm to 1000 nm have been used and the high pressure applied by the SFM have been observed to affect the values obtained in the measurements. The contact of the SFM tip with the polymer surface is explained by fitting the experimental curves to theoretical predictions of contact mechanics. Sum Frequency Generation (SFG) Vibrational Spectroscopy has been used to measure vibrational spectra of polymer surfaces in the vibrational range of 2700 to 3100 cm-1. Strong correlations are established between surface chemistry and surface structure as probed by SFG and mechanical properties measured by SFM on the surfaces. In these studies segregation of low surface energy moieties, from the bulk of the polymer to the surface have been studied. It was found that surface segregation occurs in miscible polymer blends and a small concentration of surface active polymer can be used to totally modify the surface properties of the blend. A novel high vacuum SFM was built to do temperature dependent measurements of mechanical changes occurring at the surface of polypropylene during the glass transition of the polymer. Using this instrument the modulus and friction of polypropylene was measured in the range of room temperature to ˜-60°C. An increase in the ordering of the backbone of the polymer chains below the glass transition measured by SFG correlates well with the increase in modulus measured on the same surface with SFM. Friction measurements have been done on polyethylene with three different instruments by applying loads ranging from nN to sub newton i.e. over eight orders of magnitude. Pressure and contact area effects were observed to play a significant role in determining the frictional response of the polymer

  18. The effects of vibration-reducing gloves on finger vibration.

    Science.gov (United States)

    Welcome, Daniel E; Dong, Ren G; Xu, Xueyan S; Warren, Christopher; McDowell, Thomas W

    2014-01-01

    Vibration-reducing (VR) gloves have been used to reduce the hand-transmitted vibration exposures from machines and powered hand tools but their effectiveness remains unclear, especially for finger protection. The objectives of this study are to determine whether VR gloves can attenuate the vibration transmitted to the fingers and to enhance the understanding of the mechanisms of how these gloves work. Seven adult male subjects participated in the experiment. The fixed factors evaluated include hand force (four levels), glove condition (gel-filled, air bladder, no gloves), and location of the finger vibration measurement. A 3-D laser vibrometer was used to measure the vibrations on the fingers with and without wearing a glove on a 3-D hand-arm vibration test system. This study finds that the effect of VR gloves on the finger vibration depends on not only the gloves but also their influence on the distribution of the finger contact stiffness and the grip effort. As a result, the gloves increase the vibration in the fingertip area but marginally reduce the vibration in the proximal area at some frequencies below 100 Hz. On average, the gloves reduce the vibration of the entire fingers by less than 3% at frequencies below 80 Hz but increase at frequencies from 80 to 400 Hz. At higher frequencies, the gel-filled glove is more effective at reducing the finger vibration than the air bladder-filled glove. The implications of these findings are discussed.

  19. Analysis of the carbonyl group stretching vibrations in some structural fragments of poly-3-hydroxybutyrate

    CERN Document Server

    Pitsevich, George A; Doroshenko, Iryna

    2016-01-01

    The structure and the medium effects exerted on the spectral characteristics of the carbonyl group stretching vibrations in some structural fragments of poly-3-hydroxybutyrate have been analyzed. Calculations of the equilibrium configurations and IR spectra were carried out using the Gaussian program set in the approximation B3LYP/cc-pVDZ. It has been shown that typical bending of the poly-3-hydroxybutyrate chain is observed with an increase in the number of structural units. In order to explain the difference between the calculated and experimental frequencies of the C=O group stretching vibrations, the calculations of the potential energy curve associated with variations in the length of C=O bond and the subsequent numerical solution of a one-dimensional vibrational Schr\\"odinger equation have been performed. The medium effects have been taken into account within the scope of a polarizable continuum model. Owing to the inclusion of the above-mentioned factors, which affect frequencies of the carbonyl groups...

  20. 轮式拖拉机振动系统横向固有频率理论建模及验证%Lateral natural frequency modeling and verification for vibration systems of wheeled tractors

    Institute of Scientific and Technical Information of China (English)

    薛金林; 汪珍珍; 伊力达尔伊力亚斯; 聂信天; 朱思洪

    2016-01-01

    为了进一步研究拖拉机的振动特性,对拖拉机振动系统的横向固有频率进行研究,建立了无悬架拖拉机横向和侧倾2自由度振动模型,推导出拖拉机横向固有频率的理论计算公式。以江苏常发集团CF700型拖拉机为研究对象,用理论与试验相结合的方法进行了试验验证,试验分别在5、9、11、13和15 km/h的行驶速度下测得拖拉机的横向固有频率,并与其相应的横向固有频率理论计算值进行比较。结果表明,理论计算值与试验值最大相对误差为1.11%,验证了横向固有频率理论计算公式的准确性,该研究为拖拉机座椅横向减振系统的设计提供了重要参考。%In China, operators of off-road vehicles such as agricultural vehicles and mining vehicles are exposed to excessively high levels of vibrations in all of 3 translational modes - vertical, longitudinal and lateral mode, which can pose health risks to the drivers. According to international organization for standardization 2631-1:1997, the lateral vibration can be more hazardous to operators’ work performance, comfort and health than the vertical vibration when the vibration frequency is below 3 Hz, and meanwhile, some vibration systems of off-road vehicles can resonate in this frequency range. But seldom research was conducted on the lateral vibration characteristics of off-road vehicles. In this paper, a new theoretical vibration model including the lateral and roll directions of ride vibration in space was constructed for the unsuspended tractor with 2 degrees of freedom, and the theoretical formula was presented for calculating the lateral natural frequency of domestic tractors. In this lateral vibration model, the radical and lateral stiffness of tires was taken into account. By the use of a CF700 tractor without suspensions from Changfa Group in Jiangsu Province, the accuracy of the theoretical values of the lateral vibration model was improved

  1. CPR 1000技术核电机组高频振动故障诊断与处理%Fault Diagnosis and Processing on High Frequency Vibration of CPR1000 Nuclear Power Unit

    Institute of Scientific and Technical Information of China (English)

    杨毅; 高庆水; 张楚; 刘石; 杜胜磊; 李力

    2016-01-01

    针对 CPR1000技术半转速核电机组汽轮机在调试期间出现瓦振超标,存在大比例振动幅值波动的高频成分,通过大修前振动试验、大修中模态测试、高频激振力来源辨识等试验分析,判断该机组瓦振高频振动故障是3号进汽管道内的不稳定汽流激振力经进汽管道、汽缸传递至轴承箱引发轴承箱盖不稳定共振所致。根据振动故障诊断分析结果,通过优化调节汽门的开启程序和方式,改变管道内汽流的状态参数,使得瓦振大幅降低至优良水平;从阻隔高频激振力的传递路径、瓦振测点位置选择等方面对机组瓦振安全性进行评估,并提出了改进方案。%In allusion to the problem of superstandard bearing vibration of steam turbine of CPR1000 half-speed nuclear pow-er unit in commissioning period which may cause high frequency with high range vibration amplitude fluctuation,experimen-tal analysis on vibration experiment before overhaul,mode testing in overhaul,identification on high frequency exciting force source,and so on is carried out to judge reason for high frequency vibration fault of the unit bearing vibration is un-steady resonance of bearing box cover caused by unsteady steam exciting force in No.3 steam pipe flowing through steam pipe and cylinder stator to the bearing box.According to fault diagnosis analysis results,it is proved to be able to greatly re-duce bearing vibration to fine level by optimizing open program and mode of steam regulating valve and changing state pa-rameters of gas flow in the pipe.In terms of transferring path of obstructing high frequency exciting force and selection for testing point position of bearing vibration,security of unit bearing vibration is evaluated and improvement scheme is pro-posed.

  2. Vibrational sum-frequency generation spectroscopy of ionic liquid 1-butyl-3-methylimidazolium tris(pentafluoroethyl)trifluorophosphate at the air-water interface

    Science.gov (United States)

    Saha, Ankur; SenGupta, Sumana; Kumar, Awadhesh; Choudhury, Sipra; Naik, Prakash D.

    2016-08-01

    The structure and orientation of room temperature ionic liquid (RTIL) 1-butyl-3-methylimidazolium tris(pentafluoroethyl)trifluorophosphate [PF3(C2F5)3], commonly known as [bmim][fap], have been investigated at the air-[bmim][fap] and air-water interfaces, employing vibrational sum-frequency generation (VSFG) spectroscopy. The VSFG spectra in the CH stretch region suggest presence of the [bmim] cation at the interfaces. Studies reveal that the butyl chain protrudes out into air, and the imidazolium ring lies almost planar to the interface. The CH stretch intensities get enhanced at the air-water interface, mainly because of polar orientation of imidazolium cation induced by interfacial water molecules. The OH stretch intensities are also enhanced at the air-water interface due to polar orientation of interfacial water molecules induced by [bmim][fap]. The Brewster angle microscopy suggests self aggregation of [bmim][fap] in the presence of water, and the aggregation becomes extensive showing dense surface domains with time. However, the surface pressure is almost unaffected due to aggregation.

  3. Low energy electron diffraction (LEED) and sum frequency generation (SFG) vibrational spectroscopy studies of solid-vacuum, solid-air and solid-liquid interfaces

    Energy Technology Data Exchange (ETDEWEB)

    Hoffer, Saskia

    2002-08-19

    Electron based surface probing techniques can provide detailed information about surface structure or chemical composition in vacuum environments. The development of new surface techniques has made possible in situ molecular level studies of solid-gas interfaces and more recently, solid-liquid interfaces. The aim of this dissertation is two-fold. First, by using novel sample preparation, Low Energy Electron Diffraction (LEED) and other traditional ultra high vacuum (UHV) techniques are shown to provide new information on the insulator/vacuum interface. The surface structure of the classic insulator NaCl has been determined using these methods. Second, using sum frequency generation (SFG) surface specific vibrational spectroscopy studies were performed on both the biopolymer/air and electrode/electrolyte interfaces. The surface structure and composition of polyetherurethane-silicone copolymers were determined in air using SFG, atomic force microscopy (AFM), and X-ray photoelectron spectroscopy (XPS). SFG studies of the electrode (platinum, gold and copper)/electrolyte interface were performed as a function of applied potential in an electrochemical cell.

  4. Phase transition behaviors of the supported DPPC bilayer investigated by sum frequency generation (SFG) vibrational spectroscopy and atomic force microscopy (AFM).

    Science.gov (United States)

    Wu, Heng-Liang; Tong, Yujin; Peng, Qiling; Li, Na; Ye, Shen

    2016-01-21

    The phase transition behaviors of a supported bilayer of dipalmitoylphosphatidyl-choline (DPPC) have been systematically evaluated by in situ sum frequency generation (SFG) vibrational spectroscopy and atomic force microscopy (AFM). By using an asymmetric bilayer composed of per-deuterated and per-protonated monolayers, i.e., DPPC-d75/DPPC and a symmetric bilayer of DPPC/DPPC, we were able to probe the molecular structural changes during the phase transition process of the lipid bilayer by SFG spectroscopy. It was found that the DPPC bilayer is sequentially melted from the top (adjacent to the solution) to bottom leaflet (adjacent to the substrate) over a wide temperature range. The conformational ordering of the supported bilayer does not decrease (even slightly increases) during the phase transition process. The conformational defects in the bilayer can be removed after the complete melting process. The phase transition enthalpy for the bottom leaflet was found to be approximately three times greater than that for the top leaflet, indicating a strong interaction of the lipids with the substrate. The present SFG and AFM observations revealed similar temperature dependent profiles. Based on these results, the temperature-induced structural changes in the supported lipid bilayer during its phase transition process are discussed in comparison with previous studies.

  5. Structure of butanol and hexanol at aqueous, ammonium bisulfate, and sulfuric acid solution surfaces investigated by vibrational sum frequency generation spectroscopy.

    Science.gov (United States)

    Van Loon, Lisa L; Minor, Rena N; Allen, Heather C

    2007-08-09

    The organization of 1-butanol and 1-hexanol at the air-liquid interface of aqueous, aqueous ammonium bisulfate, and sulfuric acid solutions was investigated using vibrational broad bandwidth sum frequency generation spectroscopy. There is spectroscopic evidence supporting the formation of centrosymmetric structures at the surface of pure butanol and pure hexanol. At aqueous, ammonium bisulfate, and at most sulfuric acid solution surfaces, butanol molecules organize in all-trans conformations. This suggests that butanol self-aggregates. The spectrum for the 0.052 M butanol in 59.5 wt % sulfuric acid solution is different from the other butanol solution spectra, that is, the surface butanol molecules are observed to possess a significant number of gauche defects. Relative to surface butanol, surface hexanol chains are more disordered at the surface of their respective solutions. Statistically, an increase in the number of gauche defects is expected for hexanol relative to butanol, a six carbon chain vs a four carbon chain. Yet, self-aggregation of hexanol at its aqueous solution surfaces is not ruled out because the methylene spectral contribution is relatively small. The surface spectra for butanol and hexanol also show evidence for salting out from the ammonium bisulfate solutions.

  6. Low energy electron diffraction (LEED) and sum frequency generation (SFG) vibrational spectroscopy studies of solid-vacuum, solid-air and solid-liquid interfaces

    Energy Technology Data Exchange (ETDEWEB)

    Hoffer, Saskia [Univ. of California, Berkeley, CA (United States)

    2002-01-01

    Electron based surface probing techniques can provide detailed information about surface structure or chemical composition in vacuum environments. The development of new surface techniques has made possible in situ molecular level studies of solid-gas interfaces and more recently, solid-liquid interfaces. The aim of this dissertation is two-fold. First, by using novel sample preparation, Low Energy Electron Diffraction (LEED) and other traditional ultra high vacuum (UHV) techniques are shown to provide new information on the insulator/vacuum interface. The surface structure of the classic insulator NaCl has been determined using these methods. Second, using sum frequency generation (SFG) surface specific vibrational spectroscopy studies were performed on both the biopolymer/air and electrode/electrolyte interfaces. The surface structure and composition of polyetherurethane-silicone copolymers were determined in air using SFG, atomic force microscopy (AFM), and X-ray photoelectron spectroscopy (XPS). SFG studies of the electrode (platinum, gold and copper)/electrolyte interface were performed as a function of applied potential in an electrochemical cell.

  7. Experimental evidence for an optical interference model for vibrational sum frequency generation on multilayer organic thin film systems. II. Consideration for higher order terms.

    Science.gov (United States)

    O'Brien, Daniel B; Massari, Aaron M

    2015-01-14

    The generalized optical interference model for interfacial contributions to vibrational sum frequency generation (VSFG) spectroscopic signals from organic thin film systems is extended to include a description of optical interferences contained in the thin film bulk response. This is based on electric quadrupolar interactions with the input fields and includes a discussion on possible contribution from the electric quadrupolar polarization. VSFG data from the first of this two part report are analyzed and include effects from higher order responses, for both bulk and higher order interfacial terms. The results indicate that although it is capable of capturing many of the data features, the electric dipole treatment is likely not a complete description of the VSFG intensity data from this system. An analysis based on the signs of the resulting response amplitudes is used to deduce the relative magnitude of the electric dipole and higher order interfacial terms. It is found that the buried interface is closer to satisfying the electric dipole approximation, consistent with smaller field gradients due to closer index matching between the organic thin film and substrate relative to air. The procedure outlined in this work allows for the difficult task of deducing a physical picture of average molecular orientation at the buried interface of a multilayer organic thin film system while including higher order effects.

  8. Studies of Heterogeneously Catalyzed Liquid-Phase Alcohol Oxidation on Platinum bySum-frequency Generation Vibrational Spectroscopy and Reaction Rate Measurements

    Energy Technology Data Exchange (ETDEWEB)

    Thompson, Christopher [Univ. of California, Berkeley, CA (United States)

    2014-05-15

    Compared to many branches of chemistry, the molecular level study of catalytically active surfaces is young. Only with the invention of ultrahigh vacuum technology in the past half century has it been possible to carry out experiments that yield useful molecular information about the reactive occurrences at a surface. The reason is two-fold: low pressure is necessary to keep a surface clean for an amount of time long enough to perform an experiment, and most atomic scale techniques that are surface speci c (x-ray photoelectron spectroscopy, electron energy loss spectroscopy, Auger electron spectroscopy, etc.) cannot be used at ambient pressures, because electrons, which act as chemical probes in these techniques, are easily scattered by molecules. Sum-frequency generation (SFG) vibrational spectroscopy is one technique that can provide molecular level information from the surface without the necessity for high vacuum. Since the advent of SFG as a surface spectroscopic tool it has proved its worth in the studies of surface catalyzed reactions in the gas phase, with numerous reactions in the gas phase having been investigated on a multitude of surfaces. However, in situ SFG characterization of catalysis at the solid-liquid interface has yet to be thoroughly pursued despite the broad interest in the use of heterogeneous catalysts in the liquid phase as replacements for homogeneous counterparts. This work describes an attempt to move in that direction, applying SFG to study the solid-liquid interface under conditions of catalytic alcohol oxidation on platinum.

  9. On the influence of freight trains on humans: a laboratory investigation of the impact of nocturnal low frequency vibration and noise on sleep and heart rate.

    Directory of Open Access Journals (Sweden)

    Michael G Smith

    Full Text Available BACKGROUND: A substantial increase in transportation of goods on railway may be hindered by public fear of increased vibration and noise leading to annoyance and sleep disturbance. As the majority of freight trains run during night time, the impact upon sleep is expected to be the most serious adverse effect. The impact of nocturnal vibration on sleep is an area currently lacking in knowledge. We experimentally investigated sleep disturbance with the aim to ascertain the impact of increasing vibration amplitude. METHODOLOGY/PRINCIPAL FINDINGS: The impacts of various amplitudes of horizontal vibrations on sleep disturbance and heart rate were investigated in a laboratory study. Cardiac accelerations were assessed using a combination of polysomnography and ECG recordings. Sleep was assessed subjectively using questionnaires. Twelve young, healthy subjects slept for six nights in the sleep laboratory, with one habituation night, one control night and four nights with a variation of vibration exposures whilst maintaining the same noise exposure. With increasing vibration amplitude, we found a decrease in latency and increase in amplitude of heart rate as well as a reduction in sleep quality and increase in sleep disturbance. CONCLUSIONS/SIGNIFICANCE: We concluded that nocturnal vibration has a negative impact on sleep and that the impact increases with greater vibration amplitude. Sleep disturbance has short- and long-term health consequences. Therefore, it is necessary to define levels that protect residents against sleep disruptive vibrations that may arise from night time railway freight traffic.

  10. Vibration control in accelerators

    Energy Technology Data Exchange (ETDEWEB)

    Montag, C.

    2011-01-01

    In the vast majority of accelerator applications, ground vibration amplitudes are well below tolerable magnet jitter amplitudes. In these cases, it is necessary and sufficient to design a rigid magnet support structure that does not amplify ground vibration. Since accelerator beam lines are typically installed at an elevation of 1-2m above ground level, special care has to be taken in order to avoid designing a support structure that acts like an inverted pendulum with a low resonance frequency, resulting in untolerable lateral vibration amplitudes of the accelerator components when excited by either ambient ground motion or vibration sources within the accelerator itself, such as cooling water pumps or helium flow in superconducting magnets. In cases where ground motion amplitudes already exceed the required jiter tolerances, for instance in future linear colliders, passive vibration damping or active stabilization may be considered.

  11. Benchmark Structures and Harmonic Vibrational Frequencies Near the CCSD(T) Complete Basis Set Limit for Small Water Clusters: (H2O)n = 2, 3, 4, 5, 6.

    Science.gov (United States)

    Howard, J Coleman; Tschumper, Gregory S

    2015-05-12

    A series of (H2O)n clusters ranging from the dimer to the hexamer have been characterized with the CCSD(T) and the 2-body:Many-body CCSD(T):MP2 methods near the complete basis set (CBS) limit to generate benchmark-quality optimized structures and harmonic vibrational frequencies for these important systems. Quadruple-ζ correlation-consistent basis sets that augment the O atoms with diffuse functions have been employed in the analytic computation of harmonic vibrational frequencies for the global minima of the dimer, trimer, tetramer, and pentamer as well as the ring, book, cage, and prism isomers of the hexamer. Prior calibration [J. Chem. Phys. 2013, 139, 184113 and J. Chem. Theory Comput. 2014, 10, 5426] suggests that harmonic frequencies computed with this approach will lie within a few cm(-1) of the canonical CCSD(T) CBS limit. These data are used as reference values to gauge the performance of harmonic frequencies obtained with other ab initio methods (e.g., LCCSD(T) and MP2) and water potentials (e.g., TTM3-F and WHBB). This comparison reveals that it is far more challenging to converge harmonic vibrational frequencies for the bound OH stretching modes in these (H2O)n clusters to the CCSD(T) CBS limit than the free OH stretches, the n intramonomer HOH bending modes and even the 6n - 6 intermonomer modes. Deviations associated with the bound OH stretching harmonic frequencies increase rapidly with the size of the cluster for all methods and potentials examined, as do the corresponding frequency shifts relative to the monomer OH stretches.

  12. Study on Dual-Ultrasonic Vibrator Frequency Tracking Technology Based on FPGA%基于FPGA双超声振子频率跟踪技术的研究

    Institute of Scientific and Technical Information of China (English)

    杨军; 郭钟宁; 姚震; 温凯林

    2015-01-01

    为解决传统单超声、无超声生物质压缩技术的不足,提出了利用单个超声电源同时驱动两个超声振子的新方法,即双超声同步压缩生物质技术. 结合单超声振子谐振特性,在分析双超声振子谐振特性的基础上,得出双超声振子并联后的谐振特性可等效为单超声振子的谐振特性. 采用基于FPGA的最大电流法和相位差法相结合的方法实现频率自动跟踪功能,设计了电压电流相位采样电路和电流大小采样电路. 通过双超声同步压缩生物质实验,验证了该频率跟踪方式的有效性.%In order to solve the disadvantages of the technology of traditional single ultrasonic and non-ultrasonic vibration-assisted pelletizing of biomass ,a new method of dual-ultrasonic vibrator driven by a single power supply is presented ,which is named dual-ultrasonic synchronous vibration-assisted pelletizing of biomass technology. Through the analysis of the resonance characteristics of dual-ultrasonic vibrator compared with that of single ultrasonic vibrator ,it is concluded that the characteristics of dual-ultrasonic vibrator can be equivalent to the characteristics of single ultrasonic vibrator. The compound automatic frequency tracking method of combining the maximum current and the difference of current and voltage phase based on FPGA is realized. Voltage and current phase sampling circuit and current sampling circuit were designed. The effectiveness of the compound frequency tracking method is verified by the experiment of dual-ultrasonic synchronous vibration-assisted pelletizing of biomass.

  13. Time-frequency Analysis on Torsional Vibration of Turbo-generator Shafts%汽轮发电机组轴系扭振的时频特征分析

    Institute of Scientific and Technical Information of China (English)

    向玲; 杨世锡; 唐贵基; 甘春标

    2011-01-01

    针对电网动态模拟系统和汽轮发电机组轴系扭振模拟机,开展了典型工况及故障扰动下的汽轮发电机组轴系扭振试验研究,并利用非平稳信号的时频分析方法Hilbert-Huang变换(HHT)对轴系的扭振信号进行了分析.结果表明:在短路故障的冲击下,机组有机电互作用的扭振发生时,扭转振动的幅值大幅增加,扭振频率也发生了变化;三维时频图显示了扭振幅值开始增大然后逐渐减小,形成一个瓶颈状的峰谷对应曲线;三相短路故障引起的机电互作用的扭振时间大于两相短路故障引起的机电互作用的扭振时间;Hilbert谱图能获得时间、频率和幅值对应的关系,定量刻画了频率和幅值随时间的变化过程.%Based on dynamic simulation system of power grid and torsional vibration simulator of turbo-gen- erator shaft, an experimental test was conducted to study the torsional vibration under typical and dis- turbed working conditions, after which the non-stationary vibration signals were analyzed using Hilbert- Huang Transform (HHT) method. Results show that under short-circuit fault, when torsional vibration of the electrical-mechanical interaction kind exists, the amplitude of torsional vibration increases greatly while the stimulated frequency ehanges~ the 3D time-frequency graph indicates that the amplitude first ri- ses and then drops, forming a corresponding peak-to-valley curve of bottleneck like. The holding time of torsional vibration caused by electrical-mechanical interaction in the case of 3-phase short-circuit fault is longer than that of 2-phase short-circuit fault. Hilbert spectrum quantitatively describes the rapid process of vibration frequency and amplitude varying with the time under electrical disturbances.

  14. Predicting Statistical Distributions of Footbridge Vibrations

    DEFF Research Database (Denmark)

    Pedersen, Lars; Frier, Christian

    2009-01-01

    The paper considers vibration response of footbridges to pedestrian loading. Employing Newmark and Monte Carlo simulation methods, a statistical distribution of bridge vibration levels is calculated modelling walking parameters such as step frequency and stride length as random variables. The imp......The paper considers vibration response of footbridges to pedestrian loading. Employing Newmark and Monte Carlo simulation methods, a statistical distribution of bridge vibration levels is calculated modelling walking parameters such as step frequency and stride length as random variables...

  15. Research on the Gap Flow Field of Low Frequency Vibration Assisted EDM Milling Process%低频振动辅助电火花铣削加工间隙流场研究

    Institute of Scientific and Technical Information of China (English)

    王海蛟; 孔德政; 张敏; 张勤河

    2015-01-01

    通过仿真分析与实验验证相结合的方法,对低频振动辅助电火花铣削加工间隙流场进行了研究。利用Fluent有限元软件对低频振动辅助电火花铣削加工间隙流场进行了仿真分析,得到冲液压力、工具电极转速、振动频率对流场内压力、速度、蚀除颗粒分布规律的影响,并通过实验得到验证,同时得到其对加工效果的影响规律。%The simulation analysis and experimental validation methods are adopted to make the researches on the gap flow field of low frequency vibration assisted EDM machining process. The impacts of flushing pressure,rotation speed of the electrode and the frequency of vibration on the gap flow field pressure,velocity,distribution of molten particles have been found by simulation analysis using the finite element software Fluent and validated by experimental results. Effects of flushing pressure,rotation speed of the electrode and the frequency of vibration on machining effects are also obtained.

  16. 高频微振条件下激光焊接组织研究%Microstructure Characteristic of Laser Welded Joint under High Frequency Micro-vibration Condition

    Institute of Scientific and Technical Information of China (English)

    陈轩; 卢庆华; 张静; 张成; 蔡遵武

    2016-01-01

    为了研究振动工艺在激光焊接方面的应用,选用工业纯铁为研究对象,进行不同激光焊接参数与振动频率下的高频微振光纤激光焊接,达到优化接头成形,提高焊接质量的目的。利用超景深显微镜观察焊接接头宏观形貌,利用扫描电镜分析接头微观组织,利用显微硬度计测量焊接接头显微硬度分布。结果表明:在高频微振激光焊接中,施加振动可增加焊接接头熔深。焊缝晶粒细化,表现为振动频率越快,晶粒越细小。振动加速度可以作为振幅的替代参量;当振动频率与材料本身固有振动频率相近时,振动加速度越大,晶粒细化作用不明显。当激光功率为3000 W、离焦量为−10 mm、焊接速度为1.2 m/min、振动频率为118 Hz、振动加速度为36.1 m/s2时,焊接接头的整体平均显微硬度由无振动条件下的273.3 HV降低到244.6 HV,且组织晶粒细化最明显。%To study the application of vibratory process on laser welding, the industrial pure iron is selected in this research. Different laser welding parameters and vibratory frequency parameters are carried out to optimize the welding joint forming and to improve the welding quality. The cross-section morphology, microstructure and microhardness of the welding joint are studied by optical microscope, scanning electron microscope and microhardness tester respectively. The results indicate that the depth of fusion is increased by vibration. The grains in weld metal are dramatically refined at a higher vibration frequency. On the other hand, vibration acceleration can be used as an alternative parameter for vibratory amplitude. Under the condition that the applied vibration frequency is close to the inherent vibration frequency of the material, the grain refining effect is not obvious when the vibration acceleration becomes higher. The average value of welding joint microhardness is decreased from 273.3 HV without

  17. Investigation for parametric vibration of rolling mill

    Institute of Scientific and Technical Information of China (English)

    唐华平; 丁睿; 吴运新; 钟掘

    2002-01-01

    The vibration unsteady condition of rolling mill caused by flexural vibration of strip has been investigated. The parametric flexural vibration equation of rolled strip has been established. The parametric flexural vibration stability of rolled strip has been studied and the regions of stability and unstability have been determined based on Floquet theory and perturbation method. The flexural-vibration of strip is unstable when the frequency of variable tension is two times as the natural frequency of flexural-vibration strip. The characteristic of current in a temp driving motor's main loop has been studied and tested, it has been proved that there are 6 harmonic component and 12 harmonic component in main loop of driving motor electricity. The vertical vibration of working roller has been tested, the test result approves that the running unsteady is caused by parametric vibration. It attaches importance to the parametric vibration of rolling mill.

  18. 不同频率振动训练对膝关节位置觉影响的实验研究%Experimental Research on Impact of Knee Topesthesia by Vibration Training with Different Frequencies

    Institute of Scientific and Technical Information of China (English)

    黄鹏; 王安利

    2012-01-01

    目的:通过使用不同频率的振动训练方法,对以下肢为主的篮球专项运动员进行8周分组训练,观察比较振动训练方法对本体感觉的作用效果。方法:受试对象选取相同专项、身高体重年龄相近、训练水平及年限接近的成年男性篮球运动员共27名,分为对照组、次高频(45Hz)振动训练组、中低频(30Hz)振动训练组等三组,测定不同频率振动训练前后实际膝关节(右侧)角度位置与目标位置之间的差值,之后进行组间和组内比较。结果:训练组的本体感觉强化训练方案与正常空白对照组相比较,膝关节位置觉呈显著性差异,且8周后采用次高频振动训练组比中低频振动训练组在本体感觉提高方面呈显著性差异,尤其在45。角度差异更明显。结论:1)两组不同频率的振动训练都使受试者膝关节本体感觉(关节位置觉)出现增强的效果。2)次高频(45Hz)振动训练比中低频(30Hz)振动训练对膝关节本体感觉提高的效果更显著,尤其在45。差异更为明显。%Objective: Through the method of different frequencies of vibration training of lower limb, the researches conducted 8 - week group training of basketball players focused on lower limb to observe the function and effect of comparative vibration training method on the athletes proprioceptive sensory indexes. Methods: Select 27 adult athletes in the same sports events, with similar height, weight, age, training level. All of them were divided into three groups: the control group, the quasi-high frequency in (45 Hz) vibration training group, and the low and medium frequency in (30 Hz) vibration training group. The researchers measured different frequency vibra- tion training before and after the knee (right side) numerical value. Then they compared the angle position and the difference in value between target positions. Results: Comparing the proprioception

  19. 土-结构相互作用时地下车站自振频率分析%Analysis on Natural Vibration Frequency in Soil-Structure Interaction of Underground Stations

    Institute of Scientific and Technical Information of China (English)

    焦建林

    2013-01-01

    The paper discusses soil-structure interaction, qualitatively analyzes the natural vibration frequency in the soil-structure system of underground stations, and calculates station vibration characteristics under different site conditions. The paper works out the surrounding soil modulus ratios and different pairs of soft soil depth and their impact on soil-underground stations vibration frequency. The conclusion is conducive to the anti-seismic design of underground stations.%文章考虑土-结构相互作用影响,对土-地下车站结构系统的自振频率进行定量分析,计算了不同场地条件下车站的自振特性,得到了周围土体与车站结构的模量比和软土层埋深不同对土-地下车站结构系统自振频率的影响,得到的结果对于地下车站抗震设计具有指导意义。

  20. Vibration enhanced quantum transport

    CERN Document Server

    Semião, F L; Milburn, G J

    2009-01-01

    In this paper, we study the role of a collective vibrational motion in the phenomenon of electronic energy transfer (EET) between chromophores with different electronic transition frequencies. Previous experimental work on EET in conjugated polymer samples has suggested that the common structural framework of the macromolecule introduce correlations in the energy gap fluctuations which cause coherent EET. We present a simple model describing the coupling between the chromophores and a common vibrational mode, and find that vibration can indeed lead to an enhancement in the transport of excitations across the quantum network. Furthermore, in our model phase information is partially retained in the transfer process from a donor to an acceptor, as experimentally demonstrated in the conjugated polymer system. Consequently, this mechanism of vibration enhanced quantum transport might find applications in quantum information transfer of qubit states or entanglement.

  1. Vibrating wire alignment technique

    CERN Document Server

    Xiao-Long, Wang; lei, Wu; Chun-Hua, Li

    2013-01-01

    Vibrating wire alignment technique is a kind of method which through measuring the spatial distribution of magnetic field to do the alignment and it can achieve very high alignment accuracy. Vibrating wire alignment technique can be applied for magnet fiducialization and accelerator straight section components alignment, it is a necessary supplement for conventional alignment method. This article will systematically expound the international research achievements of vibrating wire alignment technique, including vibrating wire model analysis, system frequency calculation, wire sag calculation and the relation between wire amplitude and magnetic induction intensity. On the basis of model analysis this article will introduce the alignment method which based on magnetic field measurement and the alignment method which based on amplitude and phase measurement. Finally, some basic questions will be discussed and the solutions will be given.

  2. Vibration transmissibility characteristics of smart spring vibration isolation system

    Institute of Scientific and Technical Information of China (English)

    倪德; 朱如鹏; 陆凤霞; 鲍和云; 付秋菊

    2014-01-01

    The objective of this work was to study the vibration transmissibility characteristics of the undamped and damped smart spring systems. The frequency response characteristics of them were analyzed by using the equivalent linearization technique, and the possible types of the system motion were distinguished by using the starting and ending frequencies. The influences of system parameters on the vibration transmissibility characteristics were discussed. The following conclusions may be drawn from the analysis results. The undamped smart spring system may simultaneously have one starting frequency and one ending frequency or only have one starting frequency, and the damped system may simultaneously have two starting frequencies and one ending frequency. There is an optimal control parameter to make the peak value of the vibration transmissibility curve of the system be minimum. When the mass ratio is far away from the stiffness ratio, the vibration transmissibility is small. The effect of the damping ratio on the system vibration transmissibility is significant while the control parameter is less than its optimal value. But the influence of the relative damping ratio on the vibration transmissibility is small.

  3. Frequency domain coherence analysis and relationship recognition between gearbox vibration and input energy signal%齿轮箱振动与输入能量信号的频域相干分析与关系识别

    Institute of Scientific and Technical Information of China (English)

    李怀俊; 刘越琪; 谢小鹏

    2015-01-01

    energy data. Secondly, the model of gear transmission energy interact with vibration was proposed to analyze the stable I/O relationship between the input energy and vibration signal response using correlation function based on the probability statistics form. Results showed that the larger of correlation value in the key frequency point, the more obvious of vibration energy dissipation. Finally, the normal and fault gear contrast experiment was carried out in the energy monitoring experimental platform of gear transmission system. Analysis of the experimental power signal spectrum found it is similar to vibration signal that the side band also appeared with the rotating frequency as modulation frequency on the both side of the fault gear’s meshing frequencyand typical frequency point distribution with larger amplitude accords with the traditional gear fault characteristic spectrum. Thus the spectrum features of power signal was confirmed consistent with traditional gear fault vibration spectrum, which all could reflect rich frequency information. So, condition of gearbox could also be revealed obviously by using power signal spectrum Meanwhile, auto power spectrum and cross power spectrum of vibration and power signal were all analyzed by using coherent analysis method, and the forecast that they correlate highly was verified based on classical control theory. In conclusion, vibration excitation originated from in gear vibration mechanism analysis filed, and energy had a close relationship with vibration signal. The paper lays an effective foundation for the fault diagnosis technology based on energy signal analysis.

  4. 带锯条掉齿前后横向振动位移及主频率变化规律%Horizontal Vibration Displacement and Main Frequency Variation of Band Saw Blade before and after Dropping Tooth

    Institute of Scientific and Technical Information of China (English)

    高金贵; 张健; 李辉; 吴俊华; 赵洪刚; 齐华春; 姜兆方

    2016-01-01

    Based on MJ345A woodworking band saw machine as the research object, the transverse vibration displacement of the saw blade was tested by using vibration analyzer under no-load and vibration signal acquisition, processing, analysis software. The vibration displacement and main modal frequency of different blades under the different conditions were found out through transverse vibration displacement of the saw blade and analysis of the power spectrum. The orthogonal experiment analysis showed that saw wheel spindle speed is the most significant factor impacting on the saw blade transverse vibration displacement,followed by the tension of saw blade,belt tension is not obvious. Analysis of band saw blade before and after dropping teeth showed that if the measuring range of transverse vibration displacement of band saw blade is in 0. 56~0. 68μm microns,and the vibration in 450~465 Hz frequency range,the saw blade had at least two teeth,new band saw blade need to be replaced in a timely manner in order to ensure the safety and cutting sawing quality;Then horizontal vibration displacement and frequency variation of band saw blade before and after dropping tooth have been clear. Research results can provide preliminary research and criterion of preliminary basis for sufficient and reasonable using band saw blade in the process of production,processing quality serious decline and the occurrence of the phenomenon such as endangering the personal safety accident,timely replacement blade.%以MJ345A型木工带锯机为研究对象,在空载下利用振动分析仪和振动信号采集、处理、分析软件对带锯条的横向振动进行测试及信号采集,通过锯条横向振动位移、自功率谱分析,找出不同条件下锯条振动位移和主振型频率的变化规律.通过正交试验分析可知:锯轮主轴转速是对锯条横向振动位移影响最为显著的因素,其次为锯条张紧力,皮带张紧力为不明显因素.对带

  5. INFLUENCE OF ENVIRONMENTAL FACTORS UPON FUNDAMENTAL VIBRATION FREQUENCY OF CABLES FOR CABLE-STAYED BRIDGE%环境因素对斜拉桥拉索振动基频的影响

    Institute of Scientific and Technical Information of China (English)

    吉伯海; 程苗; 傅中秋; 赵端端; 孙媛媛

    2013-01-01

    基于斜拉桥拉索有限元模型,分析了考虑拉索工程参数时阻尼器、梁体振动和温度三种环境因素对拉索振动基频的影响。结果表明:当阻尼器安装位置一定时,阻尼器对长索的基频影响大于短索的基频;当索长和阻尼器位置一定时,阻尼器对截面直径大的拉索基频的影响小于截面直径小的拉索基频;由于车辆荷载导致斜拉桥梁体振动,使得拉索的基频存在动态波动,因此在索力测量时,应选择车辆较少的时段以获得更加准确的基频;高温和低温均影响拉索基频,即拉索温度越高,基频越小;拉索温度越低,基频越大。%Based on the finite element model of cable for cable-stayed bridge , it was analyzed the influence of three environmental factors including damper , beam vibration and temperature upon the cable ’ s vibration fundamental frequency when considering engineering parameters of cable .The results show that when the damper ’ s installation position is fixed , the influence of the damper upon the long cable ’ s fundamental frequency is greater than the influence upon the short cable’s.When the cable’s length and the damper’s position are fixed, the influence of the damper upon the fundamental frequency of the cable which has large section diameter is less than the one has small section diameter .The fundamental frequency of the cable has dynamic fluctuations because of the cable -stayed bridge’s beam vibration caused by the vehicle load .To make the fundamental frequency more accurate , the time with a few vehicles may be selected when measuring the cable force .Temperature variation also has influence upon the fundamental frequency of the cable.Namely, the higher of the cable’s temperature, the smaller of the fundamental frequency;the lower of the cable ’ s temperature , the bigger of the fundamental frequency .

  6. Note: High frequency vibration rejection using a linear shaft actuator-based image stabilizing device via vestibulo-ocular reflex adaptation control method

    Science.gov (United States)

    Koh, Doo-Yeol; Kim, Young-Kook; Kim, Kyung-Soo; Kim, Soohyun

    2013-08-01

    In mobile robotics, obtaining stable image of a mounted camera is crucial for operating a mobile system to complete given tasks. This note presents the development of a high-speed image stabilizing device using linear shaft actuator, and a new image stabilization method inspired by human gaze stabilization process known as vestibulo-ocular reflex (VOR). In the proposed control, the reference is adaptively adjusted by the VOR adaptation control to reject residual vibration of a camera as the VOR gain converges to optimal state. Through experiments on a pneumatic vibrator, it will be shown that the proposed system is capable of stabilizing 10 Hz platform vibration, which shows potential applicability of the device to a high-speed mobile robot.

  7. PREFACE: Vibrations at surfaces Vibrations at surfaces

    Science.gov (United States)

    Rahman, Talat S.

    2011-12-01

    This special issue is dedicated to the phenomenon of vibrations at surfaces—a topic that was indispensible a couple of decades ago, since it was one of the few phenomena capable of revealing the nature of binding at solid surfaces. For clean surfaces, the frequencies of modes with characteristic displacement patterns revealed how surface geometry, as well as the nature of binding between atoms in the surface layers, could be different from that in the bulk solid. Dispersion of the surface phonons provided further measures of interatomic interactions. For chemisorbed molecules on surfaces, frequencies and dispersion of the vibrational modes were also critical for determining adsorption sites. In other words, vibrations at surfaces served as a reliable means of extracting information about surface structure, chemisorption and overlayer formation. Experimental techniques, such as electron energy loss spectroscopy and helium-atom-surface scattering, coupled with infra-red spectroscopy, were continually refined and their resolutions enhanced to capture subtleties in the dynamics of atoms and molecules at surfaces. Theoretical methods, whether based on empirical and semi-empirical interatomic potential or on ab initio electronic structure calculations, helped decipher experimental observations and provide deeper insights into the nature of the bond between atoms and molecules in regions of reduced symmetry, as encountered on solid surfaces. Vibrations at surfaces were thus an integral part of the set of phenomena that characterized surface science. Dedicated workshops and conferences were held to explore the variety of interesting and puzzling features revealed in experimental and theoretical investigations of surface vibrational modes and their dispersion. One such conference, Vibrations at Surfaces, first organized by Harald Ibach in Juelich in 1980, continues to this day. The 13th International Conference on Vibrations at Surfaces was held at the University of

  8. C/O and Mg/Si Ratios of Stars in the Solar Neighborhood

    CERN Document Server

    Brewer, John M

    2016-01-01

    The carbon to oxygen ratio in a protoplanetary disk can have a dramatic influence on the compositions of any terrestrial planets formed. In regions of high C/O, planets form primarily from carbonates and in regions of low C/O, the ratio of magnesium to silicon determines the types of silicates which dominate the compositions. We present C/O and Mg/Si ratios for 849 F, G, and K dwarfs in the solar neighborhood. We find that the frequency of carbon-rich dwarfs in the solar neighborhood is < 0.13% and that 156 known planet hosts in the sample follow a similar distribution as all of the stars as a whole. The cosmic distribution of Mg/Si for these same stars is broader than the C/O distribution and peaks near 1.0 with $\\sim 60$% of systems having $1 \\leq$ Mg/Si $< 2$, leading to rocky planet compositions similar to the Earth. This leaves 40% of systems that can have planets that are silicate rich and may have very different compositions than our own.

  9. Frequency and damping ratio assessment of high-rise buildings using an Automatic Model-Based Approach applied to real-world ambient vibration recordings

    Science.gov (United States)

    Nasser, Fatima; Li, Zhongyang; Gueguen, Philippe; Martin, Nadine

    2016-06-01

    This paper deals with the application of the Automatic Model-Based Approach (AMBA) over actual buildings subjected to real-world ambient vibrations. In a previous paper, AMBA was developed with the aim of automating the estimation process of the modal parameters and minimizing the estimation error, especially that of the damping ratio. It is applicable over a single-channel record, has no parameters to be set, and no manual initialization phase. The results presented in this paper should be regarded as further documentation of the approach over real-world ambient vibration signals.

  10. Vibrational relaxation and vibrational cooling in low temperature molecular crystals

    Science.gov (United States)

    Hill, Jeffrey R.; Chronister, Eric L.; Chang, Ta-Chau; Kim, Hackjin; Postlewaite, Jay C.; Dlott, Dana D.

    1988-01-01

    The processes of vibrational relaxation (VR) and vibrational cooling (VC) are investigated in low temperature crystals of complex molecules, specifically benzene, naphthalene, anthracene, and durene. In the VR process, a vibration is deexcited, while VC consists of many sequential and parallel VR steps which return the crystal to thermal equilibrium. A theoretical model is developed which relates the VR rate to the excess vibrational energy, the molecular structure, and the crystal structure. Specific relations are derived for the vibrational lifetime T1 in each of three regimes of excess vibrational energy. The regimes are the following: Low frequency regime I where VR occurs by emission of two phonons, intermediate frequency regime II where VR occurs by emission of one phonon and one vibration, and high frequency regime III where VR occurs by evolution into a dense bath of vibrational combinations. The VR rate in each regime depends on a particular multiphonon density of states and a few averaged anharmonic coefficients. The appropriate densities of states are calculated from spectroscopic data, and together with available VR data and new infrared and ps Raman data, the values of the anharmonic coefficients are determined for each material. The relationship between these parameters and the material properties is discussed. We then describe VC in a master equation formalism. The transition rate matrix for naphthalene is found using the empirically determined parameters of the above model, and the time dependent redistribution in each mode is calculated.

  11. Analysis of Vibration Specific and Natural Frequency of Axial-flow Compressor Blades%轴流式压缩机叶片振动特性及固有频率分析

    Institute of Scientific and Technical Information of China (English)

    白静

    2013-01-01

    The kinetic characteristics of blades of axial-flow compressor were researched by taking blades of axial-flow compressor as subjects. The static frequency, the dynamic frequency and vibration modes were calculated by the mode analysis of the blades. The difference between the dynamic frequency and the static frequency was small under each rotational speed. Because the pre-stress imposed by the centrifugal force was distributed in the groove, the centrifugal force has little influence on the vibration specific of the blades. The Campbell diagram which described the dynamic frequency under the rotational speed of 1000~3000 r/min is drew. Through an analysis of the Campbell diagram and the calculation of resonance safety ratio, it was found that there are two resonant peaks and frequency must be adjusted.%以轴流压缩机动叶片为研究对象,分析了轴流式压缩机叶片的动态特性.对叶片进行模态分析,计算得到其静频值、动频值及其相应振型.发现叶片在各个转速下的动频值与静频值相差很小,说明离心初应力对叶片的振动特性影响很小,这是因为离心力产生的预应力仅仅分布在叶根榫槽处.并将模态计算得到的转速1 000~3 000 r/min的动频绘制成Campbell图,通过对Campbell图进行分析及共振安全率的计算发现,叶片存在2个共振点,必须对其进行调频.

  12. NASDA's activities on vibration isolation technology

    Science.gov (United States)

    1992-01-01

    The National Space Development Agency's (NASDA) activities in providing various vibration isolation technologies for the Space Station Mission are covered in viewgraph form. Technologies covered include an active vibration isolation system for extra sensitive missions in the low frequency range, a passive damping system consisting of a damping rack for the reduction of resonance amplification, and an isolator for vibration isolation from low frequencies. Information is given in viewgraph form on the active vibration isolation concept, voice coil type electromagnetic suspension, a profile of an active vibration isolation system, a three degree of freedom ground experiment, and acceleration feedback.

  13. Research on cylindrical shell vibration reduction systems

    Institute of Scientific and Technical Information of China (English)

    XING Xiao-liang; WANG Min-qing

    2008-01-01

    Longitudinal and horizontal vibration must both be reduced in an effective vibration isolation system. We present a cylindrical shell vibration isolator as a dynamic system composed of four springs and dampers. Vibration is directly produced by the motion of machinery, and more is subsequently generated by harmonic frequencies within their structure. To test the effectiveness of our isolator, we first determined equations for the transmission of vibration from the machine to its cylindrical shell. Damping effects produced by the vibration parameters of our system are then analyzed.

  14. The origins of vibration theory

    Science.gov (United States)

    Dimarogonas, A. D.

    1990-07-01

    The Ionian School of natural philosophy introduced the scientific method of dealing with natural phenomena and the rigorous proofs for abstract propositions. Vibration theory was initiated by the Pythagoreans in the fifth century BC, in association with the theory of music and the theory of acoustics. They observed the natural frequency of vibrating systems and proved that it is a system property and that it does not depend on the excitation. Pythagoreans determined the fundamental natural frequencies of several simple systems, such as vibrating strings, pipes, vessels and circular plates. Aristoteles and the Peripatetic School founded mechanics and developed a fundamental understanding of statics and dynamics. In Alexandrian times there were substantial engineering developments in the field of vibration. The pendulum as a vibration, and probably time, measuring device was known in antiquity, and was further developed by the end of the first millennium AD.

  15. Magnetic damping of ski vibrations

    Energy Technology Data Exchange (ETDEWEB)

    Yonnet, J.-P. [CNRS, St. Martin d' Heres (France). Lab. d' Electrotech. de Grenoble; Patton, A.C.; Philippe; Arnould; Bressan, C. [CNRS, St. Martin d' Heres (France). Lab. d' Electrotech. de Grenoble]|[Skis Dynastar S.A., Sallanches (France)

    1998-07-01

    An original damping device has been developed to reduce ski vibrations. Ski movement is transmitted to a conductive sheet situated in a multipole magnetic field created by permanent magnets. The conductive sheet is simultaneously submitted to eddy current and friction forces, giving the damping effect. The eddy current damper is more efficient for high frequency than for low frequency vibrations and consequently is very well adapted to ski vibrations. Bench and snow tests show the positive effects of the damper, which will be commercially available before the end of this year. (orig.)

  16. Development of a metal annulus-based low frequency fiber Bragg grating vibration sensing system%金属环封装低频光纤布拉格光栅振动传感系统研制

    Institute of Scientific and Technical Information of China (English)

    王建飞; 于洋; 罗洪; 孟洲

    2012-01-01

    A metal annulus-based single cylinder mandrel structure fiber Bragg grating(FBG) vibration sensor and a phase generated carrier(PGC) demodulator based on an unbalanced Michelson interferometer are proposed in this paper.The high precision and real time signal detection are achieved for this FBG vibration sensor.Experimental results show that its resonance frequency is 388 Hz and its acceleration sensitivity is around 81 pm/g over the frequency range from 10 Hz to 200 Hz,with fluctuation at different frequencies less than 1 dB.This FBG vibration sensor is suitable for monitoring vibration signals below the frequency of 200Hz.The wavelength resolution of the demodulation system is 1.07×10-3 pm,and the acceleration resolution of the sensing system is 1.3×10-5 g.%研制了一种金属环封装的单柱体芯轴式光纤布拉格光栅(FBG)振动传感器,搭建了基于非平衡迈克耳逊干涉仪相位载波调制(PGC)解调技术的FBG振动传感器解调系统,实现了低频振动信号的高精度实时解调,并分析了各参数对传感器谐振频率和灵敏度等特性的影响。实验结果表明,研制的FBG振动传感器谐振频率为388Hz,在10~200Hz频率范围内,传感器的加速度灵敏度约为81pm/g,且加速度响应平坦,起伏小于1dB,与理论分析结果基本一致。研制的振动传感器可实现200Hz以下低频振动信号的实时检测,解调系统的波长检测精度为1.07×10-3 pm,最小可检测加速度为1.3×10-5 g。

  17. Study on the vibration band gap and vibration attenuation property of phononic crystals

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    Phononic crystals (PCs) are functional materials with periodic structures and elas- tic wave (vibration) band gaps, where propagation of vibrations with frequencies within band gaps is forbidden. PCs with finite periods can restrain the propagation of vibrations with frequencies in band gaps and thus has vibration attenuation property. Worldwide, many institutions and researchers are engaged in the re- search of PCs, however, studies on the vibration attenuation property of PCs are still limited. In this paper, we report our study of band gaps and vibration attenua- tion properties of 1) a simplified PC—periodic mass-spring structures, 2) longitu- dinal vibration of one-dimensional (1D-), 2D-, 3D-PCs, and 3) the flexural vibration of 1D- and 2D-PCs. These studies provide a foundation for the applications of PCs in vibration attenuation.

  18. Study on the vibration band gap and vibration attenuation property of phononic crystals

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    Phononic crystals (PCs) are functional materials with periodic structures and elastic wave (vibration) band gaps, where propagation of vibrations with frequencies within band gaps is forbidden. PCs with finite periods can restrain the propagation of vibrations with frequencies in band gaps and thus has vibration attenuation property. Worldwide, many institutions and researchers are engaged in the research of PCs, however, studies on the vibration attenuation property of PCs are still limited. In this paper, we report our study of band gaps and vibration attenuation properties of 1) a simplified PC-periodic mass-spring structures, 2) longitudinal vibration of one-dimensional (1D-), 2D-, 3D-PCs, and 3) the flexural vibration of 1D- and 2D-PCs. These studies provide a foundation for the applications of PCs in vibration attenuation.

  19. Vibration Compensation for Scanning Tunneling Microscope

    Institute of Scientific and Technical Information of China (English)

    LI Meng-chao; FU Xing; WEI Xiao-lei; HU Xiao-tang

    2003-01-01

    The influence of vibration is already one of main obstacles for improving the nano measuring accuracy.The techniques of anti-vibration,vibration isolation and vibration compensation become an important branch in nano measuring field.Starting with the research of sensitivity to vibration of scanning tunneling microscope(STM),the theory,techniques and realization methods of nano vibration sensor based on tunnel effect are initially investigated,followed by developing the experimental devices.The experiments of the vibration detection and vibration compensation are carried out.The experimental results show that vibration sensor based on tunnel effect is characterized by high sensitivity,good frequency characteristic and the same vibratory response characteristic consistent with STM.

  20. 铁道车辆过桥竖向振动加速度频域近似算法%Frequency Domain Approximate Algorithm for Vertical Vibration Acceleration of Railway Vehicle Passing Through Bridge

    Institute of Scientific and Technical Information of China (English)

    晋智斌; 强士中; 李小珍

    2012-01-01

    列车过桥时引起的桥梁挠曲会降低车辆乘坐舒适度,高速铁路桥梁设计时一般通过控制桥梁的挠度或进行车-桥耦合动力分析来保证车辆舒适度.为得到车辆过桥的振动规律,并提供一种便于工程应用的计算方法,基于频域分析,将桥梁变形假设为正弦半波并展开为傅里叶级数,输入车辆点头、沉浮频响函数,经过简化得出车辆竖向加速度的包络近似算式.通过实例计算结果与时域方法对比,验证了频域包络算法的准确性.频域包络解析公式还揭示了影响车辆过桥舒适度的主要因素,即桥梁最大挠度、设计车速和桥跨的比值、车辆自振频率、车辆频率响应函数等.%The defection of bridge caused by the railway vehicle passing through the bridge will decrease the riding comfort and in the design of a high-speed railway bridge, the riding comfort is guaranteed generally by way of control of the deflection of the bridge or analysis of the vehicle-bridge dynamic interaction. To acquire the vibration laws of the vehicle passing through the bridge and to provide an algorithm that is convenient for engineering application, on the basis of the frequency domain analysis, the deformation of the bridge is assumed to be a half sinusoidal wave function and the function is expanded as the Fourier's series. The frequency response functions of pitching and bouncing of the vehicle are then input and by simplifying, the envelope approximate formulae of the vehicle vertical vibration acceleration are obtained. The comparison of the calculations of practical examples with those according to the time-domain method proves the correctness of the frequency domain envelope algorithm. Besides, the analytic formulae in the frequency domain envelop algorithm also reveal the primary factors affecting the riding comfort, that is, the factors of the maximum deflection of the bridge, the ratio of designed vehicle speed to bridge spans and the

  1. Waves & vibrations

    OpenAIRE

    Nicolas, Maxime

    2016-01-01

    Engineering school; This course is designed for students of Polytech Marseille, engineering school. It covers first the physics of vibration of the harmonic oscillator with damping and forcing, coupled oscillators. After a presentation of the wave equation, the vibration of strings, beams and membranes are studied.

  2. Ab initio characterization of low-lying triplet state potential-energy surfaces and vibrational frequencies in the Wulf band of ozone

    Science.gov (United States)

    Xie, Daiqian; Guo, Hua; Peterson, Kirk A.

    2001-12-01

    Accurate ab initio potential-energy surfaces of the 3A2 and 3B1 states of ozone and their nonadiabatic coupling are reported near the ground-state equilibrium geometry using an internally contracted multireference configuration interaction method. These coupled three-dimensional potential-energy surfaces enable the first theoretical characterization of all three vibrational modes in the Wulf band. Reasonably good agreement with recent experimental observations is obtained.

  3. Model Catalysis of Ammonia Synthesis ad Iron-Water Interfaces - ASum Frequency Generation Vibrational Spectroscopic Study of Solid-GasInterfaces and Anion Photoelectron Spectroscopic Study of Selected Anionclusters

    Energy Technology Data Exchange (ETDEWEB)

    Ferguson, Michael James [Univ. of California, Berkeley, CA (United States)

    2005-01-01

    The ammonia synthesis reaction has been studied using single crystal model catalysis combined with sum frequency generation (SFG) vibrational spectroscopy. The adsorption of gases N2, H2, O2 and NH3 that play a role in ammonia synthesis have been studied on the Fe(111) crystal surface by sum frequency generation vibrational spectroscopy using an integrated Ultra-High Vacuum (UHV)/high-pressure system. SFG spectra are presented for the dissociation intermediates, NH2 (~3325 cm-1) and NH (~3235 cm-1) under high pressure of ammonia or equilibrium concentrations of reactants and products on Fe(111) surfaces. Special attention was paid to understand how potassium promotion of the iron catalyst affects the intermediates of ammonia synthesis. An Fe(111) surface promoted with 0.2 monolayers of potassium red shifts the vibrational frequencies of the reactive surface intermediates, NH and NH2, providing evidence for weakened the nitrogen-hydrogen bonds relative to clean Fe(111). Spectral features of these surface intermediates persisted to higher temperatures for promoted iron surfaces than for clean Fe(111) surfaces implying that nitrogen-iron bonds are stronger for the promoted surface. The ratio of the NH to NH2 signal changed for promoted surfaces in the presence of equilibrium concentrations of reactants and products. The order of adding oxygen and potassium to promoted surfaces does not alter the spectra indicating that ammonia induces surface reconstruction of the catalyst to produce the same surface morphology. When oxygen is co-adsorbed with nitrogen, hydrogen, ammonia or potassium on Fe(111), a relative phase shift of the spectra occurs as compared to the presence of adsorbates on clean iron surfaces. Water adsorption on iron was also probed using SFG vibrational spectroscopy. For both H2O and D2O, the only spectral feature was in the range of

  4. 悬臂压电叠层复合梁的弯曲振动固有频率%Natural frequency of flexural vibration of cantilever piezoelectric laminated composite beam

    Institute of Scientific and Technical Information of China (English)

    龚立娇; 王玉山

    2012-01-01

    压电叠层复合梁是一种三叠片对称结构.这里以压电陶瓷-金属-压电陶瓷复合结构为研究对象,给出了悬臂式对称压电复合结构的压电振子弯曲振动共振频率表达式,并建立了相应的有限元模型;计算分析了压电陶瓷-金属复合梁弯曲振动的固有频率值与几何尺寸之间的关系,并与相应的有限元模态分析结果进行了比较.结果表明,两种分析方法得到的压电振子的固有频率值基本符合,计算公式和模型是精确有效的;压电叠层复合梁愈细长则表达式的计算结果愈准确.%Piezoelectric laminated composite cantilever beam is a structure with three symmetrical laminate.With piezoelectric ceramic-metal-piezoelectric ceramic composite structure as research object, the bending vibration frequency expression of the piezoelectric ceramic -metal composite structure cantilever piezoelectric vibrator is derived and its finite-element model is established.The relationship between the natural frequency values and different dimension of piezoelectric ceramic-metal composite structure beams are calculated and analyzed, which are compared with the results from FEM analysis.The results show that the computing value of the peizoelectric vibrator obtained from two methods are fits. The results show that calculation formula and FEM model are accurate and effective.The longer piezoelectric laminated composite beam is the more accurate calculation results of expression is.

  5. Application of the multi-parameter SQM harmonic force field, and ESFF harmonic frequencies scaling procedures to the determination of the vibrational spectra of silicon- and sulfur(II)-containing compounds.

    Science.gov (United States)

    Borowski, Piotr; Ruiz, Tomas Peña; Barczak, Mariusz; Pilorz, Karol; Pasieczna-Patkowska, Sylwia

    2012-02-01

    Multi-parameter scaling techniques, such as Scaled Quantum Mechanical (SQM) force field [J. Am. Chem. Soc. 105 (1983) 7037-7047; J. Phys. Chem. A 102 (1998) 1412-1424] or Effective Scaling Frequency Factor (ESFF) [Chem. Phys. Lett. 446 (2007) 191-198; J. Mol. Spectrosc. 264 (2010) 66-74] techniques, are very powerful in the theoretical prediction of the vibrational spectra of complex molecules. In the present work sets of transferable SQM and ESFF scaling factors (within the valence coordinates based schemes) that can be applied to silicon- and sulfur(II)-containing compounds have been determined. A number of VDZ- and VTZ-quality basis sets were used in conjunction with the B3LYP density functional. Eight molecules typically used in the synthesis of silica-based materials were chosen, and theoretical modes were assigned to bands detected on their IR or Raman spectra. This set was augmented with a set of 10 auxiliary, sulfur(II)-containing molecules, for which only "pure" vibrations involving S-containing motifs were assigned. This led to the set of more than 600 individual vibrations. Five factors attributed to these motifs were optimized. Scaling factors attributed to the characteristic types of internal coordinates including the second-row atoms and chlorine, which are applicable to the present molecules were preset. Their values, optimized for Baker's training set of molecules [J. Phys. Chem. A 102 (1998) 1412-1424] for all basis sets considered in this work, were also found, extending thus the applicability of the multi-parameter scaling methods. New scaling factors exhibit low statistical uncertainties. Reasonable agreement between experimental and SQM- or ESFF-scaled frequencies was obtained even for the 6-31G* basis set (RMSSQM scaling factors were found to occasionally exhibit large deviations from unity, which is to be contrasted with ESFF scaling factors.

  6. Geometrical structures, vibrational frequencies, force constants and dissociation energies of isotopic water molecules (H2O, HDO, D2O, HTO, DTO, and T2O) under dipole electric field

    Institute of Scientific and Technical Information of China (English)

    Shi Shun-Ping; Zhang Quan; Zhang Li; Wang Rong; Zhu Zheng-He; Jiang Gang; Fu Yi-Bei

    2011-01-01

    The dissociation limits of isotopic water molecules are derived for the ground state. The equilibrium geometries,the vibrational frequencies, the force constants and the dissociation energies for the ground states of all isotopic water molecules under the dipole electric fields from -0.05 a.u. to 0.05 a.u. are calculated using B3P86/6-311++G(3df,3pf).The results show that when the dipole electric fields change from -0.05 a.u. to 0.05 a.u., the bond length of H-O increases whereas the bond angle of H-O-H decreases because of the charge transfer induced by the applied dipole electric field. The vibrational frequencies and the force constants of isotopic water molecules change under the influence of the strong external torque. The dissociation energies increase when the dipole electric fields change from -0.05 a.u.to 0.05 a.u. and the increased dissociation energies are in the order of H2O, HDO, HTO, D2O, DTO, and T2O under the same external electric fields.

  7. Kr对HF(X1Σ+)基频和泛频的影响%Influence of Kr Atoms on the Fundamental and Overtone Vibrational Frequency for HF(X1Σ+)

    Institute of Scientific and Technical Information of China (English)

    谢洪平; 陈泽琴; 蒋刚; 杨迎春; 朱正和

    2000-01-01

    运用Monte-Carlo轨迹法研究了Kr(1Sg)+HF(X1Σ+;ν=1,2,3;J=4)→Kr(1Sg)+HF(X1Σ+,ν',J')的碰撞过程,从而分析Kr原子对HF基频和泛频的影响。研究表明:在初始相对平动能Et≤251.0kJ/mol时,Kr原子能够减少产生基频的粒子数反转,增加产生泛频特别是ν'=2能级的粒子数反转,并且,Kr原子有较强的弛豫高转动态(J'≥4)的能力,因此,Kr原子对HF泛频激光在提高光强和增强大气传输能力方面均有 较大的改善。%The collision reaction that Kr(1Sg)+HF(X1Σ+;ν=1,2,3;J=4)→Kr(1Sg)+HF(X1Σ+;ν',J')has been studied using Monte-Carlo trajectory method,and it has been found that Kr atoms have in fluence on the fundamental and overtone vibrational frequency for HF(X1Σ+).The studying results show that,when the initial relative translational energy Et≤251.0kJ/mol,Kr atoms can reduce the particle number reversion of the fundamental vibrational frequency,and increase it of the overtone vibrational frequency,particularly in the energy level ν'=2,and Kr atoms are more strong on relaxing the higher rotational states(J'≥4).Thus,for hydrogen fluoride(HF)overtone frequency laser Kr atoms can obviously increase the strength of light and improve the transmission property in the air.

  8. 混流式水轮机顶盖振动信号的精细分频研究%Research on fine frequency division of vibration signal of head cover for francis turbine

    Institute of Scientific and Technical Information of China (English)

    王海军; 郑韩慈

    2015-01-01

    高水头长引水隧洞电站在水力过渡过程中具有振荡周期长、振幅大、波动衰减周期长等特点,水轮机顶盖振动可以较好地反映该规律。本文依据真机试验,采用小波和小波包联合分析方法,对一大型电站变负荷振动试验中顶盖的振动响应测试信号进行了精细分频分析。结果表明:高水头长引水隧洞电站的水流脉动、尾水涡带和水击波频率较为接近,三者共同作用,导致顶盖强烈的振动响应;其中,水流脉动和尾水涡带是引起顶盖振动的最主要原因;同时也证明了小波和小波包联合分析方法是处理水电站振动信号的一种较好的方法。%The hydropower stations with high water head and long diversion tunnel have some characteris-tics such as long period of oscillation , large oscillation range and slow -attenuation wave in the process of hydraulic transient .The vibration of Francis turbine's head cover can reflect these characteristics .Based on a hydropower station with high water head and long diversion tunnel , the paper described the vibration of its head cover with a combination method of wavelet and wavelet packet analysis .The results show that the strong vibration resonance of head cover results from the three factors such as flow pulsation , tail wa-ter vortex and water hammer ,for their frequencies are close in the hydropower station with high head and long diversion tunnel .Flow pulsation and tail water vortex are the most main factors which cause the vi-bration of head cover .This paper also proved that the method combing wavelet with wavelet packet is a better tool in the treatment of vibration signal of hydropower station .

  9. Characterization of the molecular structure and mechanical properties of polymer surfaces and protein/polymer interfaces by sum frequency generation vibrational spectroscopy and atomic force microscopy

    Energy Technology Data Exchange (ETDEWEB)

    Koffas, Telly Stelianos [Univ. of California, Berkeley, CA (United States)

    2004-01-01

    Sum frequency generation (SFG) vibrational spectroscopy, atomic force microscopy (AFM), and other complementary surface-sensitive techniques have been used to study the surface molecular structure and surface mechanical behavior of biologically-relevant polymer systems. SFG and AFM have emerged as powerful analytical tools to deduce structure/property relationships, in situ, for polymers at air, liquid and solid interfaces. The experiments described in this dissertation have been performed to understand how polymer surface properties are linked to polymer bulk composition, substrate hydrophobicity, changes in the ambient environment (e.g., humidity and temperature), or the adsorption of macromolecules. The correlation of spectroscopic and mechanical data by SFG and AFM can become a powerful methodology to study and engineer materials with tailored surface properties. The overarching theme of this research is the interrogation of systems of increasing structural complexity, which allows us to extend conclusions made on simpler model systems. We begin by systematically describing the surface molecular composition and mechanical properties of polymers, copolymers, and blends having simple linear architectures. Subsequent chapters focus on networked hydrogel materials used as soft contact lenses and the adsorption of protein and surfactant at the polymer/liquid interface. The power of SFG is immediately demonstrated in experiments which identify the chemical parameters that influence the molecular composition and ordering of a polymer chain's side groups at the polymer/air and polymer/liquid interfaces. In general, side groups with increasingly greater hydrophobic character will be more surface active in air. Larger side groups impose steric restrictions, thus they will tend to be more randomly ordered than smaller hydrophobic groups. If exposed to a hydrophilic environment, such as water, the polymer chain will attempt to orient more of its hydrophilic groups to

  10. Characterization of the molecular structure and mechanical properties of polymer surfaces and protein/polymer interfaces by sum frequency generation vibrational spectroscopy and atomic force microscopy

    Energy Technology Data Exchange (ETDEWEB)

    Koffas, Telly Stelianos

    2004-05-15

    Sum frequency generation (SFG) vibrational spectroscopy, atomic force microscopy (AFM), and other complementary surface-sensitive techniques have been used to study the surface molecular structure and surface mechanical behavior of biologically-relevant polymer systems. SFG and AFM have emerged as powerful analytical tools to deduce structure/property relationships, in situ, for polymers at air, liquid and solid interfaces. The experiments described in this dissertation have been performed to understand how polymer surface properties are linked to polymer bulk composition, substrate hydrophobicity, changes in the ambient environment (e.g., humidity and temperature), or the adsorption of macromolecules. The correlation of spectroscopic and mechanical data by SFG and AFM can become a powerful methodology to study and engineer materials with tailored surface properties. The overarching theme of this research is the interrogation of systems of increasing structural complexity, which allows us to extend conclusions made on simpler model systems. We begin by systematically describing the surface molecular composition and mechanical properties of polymers, copolymers, and blends having simple linear architectures. Subsequent chapters focus on networked hydrogel materials used as soft contact lenses and the adsorption of protein and surfactant at the polymer/liquid interface. The power of SFG is immediately demonstrated in experiments which identify the chemical parameters that influence the molecular composition and ordering of a polymer chain's side groups at the polymer/air and polymer/liquid interfaces. In general, side groups with increasingly greater hydrophobic character will be more surface active in air. Larger side groups impose steric restrictions, thus they will tend to be more randomly ordered than smaller hydrophobic groups. If exposed to a hydrophilic environment, such as water, the polymer chain will attempt to orient more of its hydrophilic groups to

  11. Analiza niskofrekventnog spektra vibracija na elementima strukture helikoptera 'Gazela' / Analysis of low frequency vibrations on the structural connection elements of the Gazelle helicopter

    OpenAIRE

    Jovanović, Miroslav M.

    2010-01-01

    U radu je prikazan postupak i metodologija ispitivanja vibracija na helikopteru 'gazela' radi definisanja efikasnosti prigušenja vibracija na vezi struktura - sedište pilota. Posebna pažnja posvećena je teorijskim osnovama vibracija na helikopteru, određivanju radnih frekvencija, definisanju režima rada i profila leta helikoptera u toku ispitivanja. Na kraju rada prikazani su rezultati merenja vibracija u frekventnom domenu. / In this paper the procedure and methodology of vibration testing o...

  12. The Origin of Vibration Redemption Effect for Shape Memory Alloys

    Directory of Open Access Journals (Sweden)

    Daniel Amariei

    2007-10-01

    Full Text Available Shape memory alloys (SMA components can affect through two mechanisms the vibrations of structures. The stresses from a SMA element that realize phase transformations, as a result of vibrations, have an effect on the frequency-amplitude characteristics. In addition, a dissipation of energy due to hysteresis in a SMA element can reduce the natural frequency and affect forced vibrations.

  13. Vibrational states on Pd surfaces

    Science.gov (United States)

    Sklyadneva, I. Yu.; Rusina, G. G.; Chulkov, E. V.

    1997-04-01

    We present the calculation of vibrational modes and lattice relaxation for the Pd(100), (110) and (111) surfaces. The surface phonon frequencies and polarizations are obtained using embedded-atom potentials. Comparison of the calculated frequency values with available experimental data gives agreement within 0.2 THz.

  14. Ultrasonic vibration for structural health monitoring

    Science.gov (United States)

    Liang, Y.; Yan, F.; Borigo, C.; Rose, J. L.

    2013-01-01

    Guided waves and vibration analysis are two useful techniques in Nondestructive Evaluation and Structural Health Monitoring. Bridging the gap between guided waves and vibration, a novel testing method ultrasonic vibration is demonstrated here. Ultrasonic vibration is capable to achieve defect detection sensitivity as ultrasonic guided waves, while maintaining the efficiency of traditional vibration in the way of adopting several sensors to cover the whole structure. In this new method, continuous guided wave energy will impinge into the structure to make the structure vibrate steadily. The steady state vibration is achieved after multiple boundary reflections of the continuous guided wave. In ultrasonic vibration experiments, annual array transducer is used as the actuator. The loading functions are tuned by the frequencies and phase delays among each transducer element. Experiments demonstrate good defect detection ability of by optimally selecting guided wave loadings.

  15. Characteristics of Vibration Induced by Cavitation

    Institute of Scientific and Technical Information of China (English)

    WANG Guo-yu; TAO Lei; LIU Shu-yan; QIAN Jian-jun

    2005-01-01

    Cavitation-induced vibration characteristics and the relations between the vibration and cavitation are studied. Cavitation vibrations are measured around a model hollow-jet valve by an accelerometer under cavitating and non-cavitating conditions. The measurement data is analyzed by FFT method. The corresponding cavitating flow patterns are photographed by a high-speed camera with an xenon flash lamp. The frequency band of the vibration induced by cavitation is determined. To compare the vibration intensities under different cavitation conditions, a definition of vibration acceleration level is introduced based on power spectral density of the vibration. By the analysis of vibration, the definitions of characteristic cavitation number are suggested. According to these cavitation numbers, the cavitation process is divided into three stages, that is, incipient cavitation, subcavitation and supercavitation.

  16. Research on Two Dimensional Normal Vibration Modes Resonance Frequency of MEMS Ultrasonic Separator%MEMS超声分离腔二维简正模式谐振频率的研究

    Institute of Scientific and Technical Information of China (English)

    华晨辉; 李彦彦

    2012-01-01

    以基于二维简正模式的微机电系统(MEMS)超声分离器的结构模型为研究对象,首先根据声电类比原理,得到超声分离腔的二维等效电路模型,通过该模型分析计算二维简正模式的谐振频率;接着通过Ansys软件对MEMS超声分离器进行有限元的仿真分析,验证了等效电路模型的可行性,并得到了最佳激发频率;最后在实验中分别采用单片PZT激发(2,1)阶和双片反相位PZT激发(1,1)阶的简正模式,均取得了一定分离的效果.%A structure model of Micro Electro Mechanical System (MEMS) ultrasonic separator which based on the two-dimensional normal vibration modes was chosen as the research object in this paper. Firstly, in accordance with the theory of electricity-sound analogy.a two-dimensional equivalent circuit model of the rectangular section of the fluid cavity was figured out. According to this model, the resonance frequencies of the two-dimensional normal mode were listed. Secondly.Simulations using finite-element method with ANSYS software was used to demonstrate the validity of the model and helped to select the best exciting frequencies; in the end the frequencies of two-dimensional normal vibration modes(2,l) and (1,1) were chosen in this paper to excite the ultrasonic. The results showed good separation.

  17. Good Vibrations

    OpenAIRE

    Panesar, Lucy

    2007-01-01

    Good Vibrations was a market research exercise conducted by Felicity (my alter-ego) and assistants to help develop marketing and packaging for an electro-therapeutic device (vibrator) used to treat hysteria and other female stress related disorders. It was a live art work commissioned by The Live Art Development Agency for East End Collaborations on 6th May 2007 and the South London Gallery for Bonkersfest on 2nd June 2007.

  18. 螺旋钻采煤机输送机构振动频率的计算与分析%Calculation and analysis of vibration frequency of spiral conveyor for coal auger

    Institute of Scientific and Technical Information of China (English)

    李晓豁; 郭继文; 王丽; 战林

    2011-01-01

    In order to study the vibration behavior of spiral conveyor of a coal auger during the work process, a dynamic model using Euler angles to describe the vibration according to Lyapunov theory was established, and ANSYS software was used to establish parameterization finite element simulation model based on APDL language. The vibration of a certain type of spiral conveyor for coal auger were calculated and simulated using the two methods, and the first fifth-order vibration frequency and maximum amplitude equivalent contour of spiral conveyor were obtained. The results of vibration analysis by ANSYS show that transverse resonance occurred in the X and Z directions, the maximum resonance amplitude occurred in the 500 Hz and 100 Hz, longitudinal resonance occurred in the Y direction, the maximum resonance amplitude occurred in the 500 Hz, and the amplitude of X direction is the largest and amplitude of Z direction is the minimum. The stress contour shows that the stress of spiral conveyor is minimum at the bottom, and the stress at the junction of spindle and helical vane is maximum. Because of the large stress at the top of spiral conveyor, the wear and deformation is serious. The results indicate that the Lyapunov theory model is straight forward and the calculation is simple; the ANSYS model is flexibility and the results are intuitively obvious although the accuracy is dependent on the selection of element type, meshing accuracy and the methods of vibration extraction. The maximum error obtained from both methods is 9. 9% , capable of reflecting the true vibration.%为了研究螺旋钻采煤机输送机构工作过程的振动,根据Lyapunov理论建立了用欧拉角描述的振动动力学方程,应用ANSYS软件建立了基于APDL语言的参数化有限元仿真模型,利用两种方法对某型螺旋钻采煤机输送机构的振动频率进行了计算和仿真,得到了输送机构前五阶的振动频率和最大振幅等效云图.其中通过ANSYS振动

  19. Experimental Research on Internal Thread Formation by Cold Extrusion Based on Low Frequency Vibration%内螺纹低频振动冷挤压试验研究

    Institute of Scientific and Technical Information of China (English)

    梁瑜轩; 黎向锋; 左敦稳; 黄小龙; 缪宏

    2013-01-01

    内螺纹低频振动冷挤压加工是通过挤压丝锥棱齿的振动挤压,将传统内螺纹冷挤压加工中的干摩擦状态转变为更有利的边界摩擦状态,从而改善传统内螺纹冷挤压加工过程中冷却润滑液不易进入挤压区的严重缺陷.通过试验可知:随着激振频率的不断增大,挤压扭矩呈不断增大趋势;随着激振力的不断增大,挤压扭矩呈现为先减小后增大的趋势;随着激振力臂长度的不断增大,挤压扭矩总体呈不断增大的趋势.在其他工艺参数相同条件下,低频振动冷挤压可以进一步提高传统内螺纹的牙高率和改善牙顶处凹陷的缺陷,从而提高冷挤压内螺纹的抗疲劳强度及获得更好的表面形貌.%Internal thread formation by cold extrusion based on low-frequency vibration can realize vibration extrusion by extruding tap. It can turn the process of dry friction into a more favorable state of boundary friction. Therefore it can overcome the defect of traditional cold extrusion that the coolant cannot easily enter the extrusion zone. The experimental study shows that: as the exciting frequency increases, so does the extrusion torque; as the exciting force increases, the extrusion torque decreases first, and then increases; as the exciting arm length increases, the extrusion torque also increases. Under the same conditions of the process parameters, the internal thread formation by cold extrusion based on low-frequency vibration exhibits a higher rate of thread teeth height and fewer defects of the teeth top than traditional methods, and the method can improve the fatigue strength and surface morphology of the thread so formed.

  20. Vibrational investigation on FT-IR and FT-Raman spectra, IR intensity, Raman activity, peak resemblance, ideal estimation, standard deviation of computed frequencies analyses and electronic structure on 3-methyl-1,2-butadiene using HF and DFT (LSDA/B3LYP/B3PW91) calculations.

    Science.gov (United States)

    Ramalingam, S; Jayaprakash, A; Mohan, S; Karabacak, M

    2011-11-01

    FT-IR and FT-Raman (4000-100 cm(-1)) spectral measurements of 3-methyl-1,2-butadiene (3M12B) have been attempted in the present work. Ab-initio HF and DFT (LSDA/B3LYP/B3PW91) calculations have been performed giving energies, optimized structures, harmonic vibrational frequencies, IR intensities and Raman activities. Complete vibrational assignments on the observed spectra are made with vibrational frequencies obtained by HF and DFT (LSDA/B3LYP/B3PW91) at 6-31G(d,p) and 6-311G(d,p) basis sets. The results of the calculations have been used to simulate IR and Raman spectra for the molecule that showed good agreement with the observed spectra. The potential energy distribution (PED) corresponding to each of the observed frequencies are calculated which confirms the reliability and precision of the assignment and analysis of the vibrational fundamentals modes. The oscillation of vibrational frequencies of butadiene due to the couple of methyl group is also discussed. A study on the electronic properties such as HOMO and LUMO energies, were performed by time-dependent DFT (TD-DFT) approach. The calculated HOMO and LUMO energies show that charge transfer occurs within the molecule. The thermodynamic properties of the title compound at different temperatures reveal the correlations between standard heat capacities (C) standard entropies (S), and standard enthalpy changes (H).

  1. 地下轨道交通结构噪声与振动频率特性分析%Structural Noise and Vibration Frequency Characteristics Caused by Underground Rail Transit

    Institute of Scientific and Technical Information of China (English)

    张中平; 郭建辉

    2014-01-01

    通过研究地下轨道交通现行国家标准与地方标准监测方法与评价量,探讨标准中存在的不足之处。并通过对受地下轨道交通运行过程影响的建筑物进行室内噪声与振动实地测试和数据分析,大胆提出了监测地下轨道交通排放的新思路。即采用1/3倍频程时间历程方法对列车通过全过程产生的结构传声排放与振动排放全时记录,借鉴声暴露级的方法,通过实测各频率数值变化截取列车通过时噪声事件的振动分频振级与结构传声1/3倍频程声压级。对此种方法的数据结果进行各频率噪声与振动相关性分析,得出地下轨道交通运行所产生结构传声污染排放的低频排放特性。通过研究和测量发现,轨道交通所引起的室内结构传声与振动污染能量主要集中于500 Hz 以下低频部分,其峰值出现于40~60 Hz 附近。将其与现行国家或地方标准进行比较,提出了采用特征频率作为事件判别的依据,并将各事件的最终测量结果以低频分频数据进行评价的方式,最终归纳总结了实际地下轨道交通排放频率特性并展望其测量方法。%By studying the underground rail transit existing national standards and local standards monitoring method and evaluation, we explored the deficiencies existing in the standard.Through the indoor noise and vibration test of the buildings affected by the un-derground rail transportation operation process,we put forward new ideas of the monitoring of the underground rail transport emis-sions.The method used a third octave to record full discharge and vibration of train through the whole process of the structure of the microphone.By taking example of the measured method of sound exposure and testing levels of each frequency numerical change e-vents,we intercepted train noise sound vibration frequency vibration level and structure and a third octave sound pressure level. Through various

  2. Pyrrole Hydrogenation over Rh(111) and Pt(111) Single-Crystal Surfaces and Hydrogenation Promotion Mediated by 1-Methylpyrrole: A Kinetic and Sum-Frequency Generation Vibrational Spectroscopy Study

    Energy Technology Data Exchange (ETDEWEB)

    Kliewer, Christopher J.; Bieri, Marco; Somorjai, Gabor A.

    2008-03-04

    Sum-frequency generation (SFG) surface vibrational spectroscopy and kinetic measurements using gas chromatography have been used to study the adsorption and hydrogenation of pyrrole over both Pt(111) and Rh(111) single-crystal surfaces at Torr pressures (3 Torr pyrrole, 30 Torr H{sub 2}) to form pyrrolidine and the minor product butylamine. Over Pt(111) at 298 K it was found that pyrrole adsorbs in an upright geometry cleaving the N-H bond to bind through the nitrogen evidenced by SFG data. Over Rh(111) at 298 K pyrrole adsorbs in a tilted geometry relative to the surface through the p-aromatic system. A pyrroline surface reaction intermediate, which was not detected in the gas phase, was seen by SFG during the hydrogenation over both surfaces. Significant enhancement of the reaction rate was achieved over both metal surfaces by adsorbing 1-methylpyrrole before reaction. SFG vibrational spectroscopic results indicate that reaction promotion is achieved by weakening the bonding between the N-containing products and the metal surface because of lateral interactions on the surface between 1-methylpyrrole and the reaction species, reducing the desorption energy of the products. It was found that the ring-opening product butylamine was a reaction poison over both surfaces, but this effect can be minimized by treating the catalyst surfaces with 1-methylpyrrole before reaction. The reaction rate was not enhanced with elevated temperatures, and SFG suggests desorption of pyrrole at elevated temperatures.

  3. Sum Frequency Generation Vibrational Spectroscopy of 1,3-Butadiene Hydrogenation on 4 nm Pt@SiO 2 , Pd@SiO 2 , and Rh@SiO 2 Core–Shell Catalysts

    KAUST Repository

    Krier, James M.

    2015-01-14

    © 2014 American Chemical Society. 1,3-Butadiene (1,3-BD) hydrogenation was performed on 4 nm Pt, Pd, and Rh nanoparticles (NPs) encapsulated in SiO2 shells at 20, 60, and 100 °C. The core-shells were grown around polyvinylpyrrolidone (PVP) coated NPs (Stöber encapsulation) prepared by colloidal synthesis. Sum frequency generation (SFG) vibrational spectroscopy was performed to correlate surface intermediates observed in situ with reaction selectivity. It is shown that calcination is effective in removing PVP, and the SFG signal can be generated from the metal surface. Using SFG, it is possible to compare the surface vibrational spectrum of Pt@SiO2 (1,3-BD is hydrogenated through multiple paths and produces butane, 1-butene, and cis/trans-2-butene) to Pd@SiO2 (1,3-BD favors one path and produces 1-butene and cis/trans-2-butene). In contrast to Pt@SiO2 and Pd@SiO2, SFG and kinetic experiments of Rh@SiO2 show a permanent accumulation of organic material.

  4. The b 1Sigma + --> X 3Sigma - transition in PH: A measurement of the term energy, bond length, and vibrational frequency of a phosphinidene metastable

    Science.gov (United States)

    Droege, A. T.; Engelking, P. C.

    1984-06-01

    The (0,0), (1,1), and (2,2) vibrational bands of the weak, spin forbidden b 1Σ+ → X 3Σ- transition of the PH radical have been observed in a flowing afterglow of PH3 in He. The spectra yield the following constants for the upper b state: Te =(14 325.5±0.1) cm-1, Be =(8.587±0.003) cm-1, we =(2403.0±0.1) cm-1, Dv =(4.0±0.05×10-4) cm-1, αe =(0.0253±0.003) cm-1, and re =(1.4178±0.0004) Å. The intensity distribution is consistent with the mixing of the b 1Σ+ state almost exclusively with the A 3Π state.

  5. Homolytic C-O cleavage in phosphates and sulfonates.

    Science.gov (United States)

    Ding, Lanlan; Zheng, Wenrui; Wang, Yingxing

    2015-04-09

    The C-O homolytic bond dissociation enthalpies(BDEs) were calculated by high-level ab initio including G4, G3B3, G3, CBS-QB3 and a series of density function theory (DFT) methods. It is found that the wB97 method gave the most reliable C-O BDEs and the root-mean-square deviation (RMSD) is 7.6 kJ/mol. Therefore, the C(sp(2))-O BDE predictions and the substituent effects of alkenyl phosphates/sulfonates and aryl phosphates/sulfonates were investigated in detail by using the wB97 method. Interestingly, there exist different substituent effects in α- and β-substituted alkenyl phosphates/sulfonates. Excellent linear relationships between the C-O BDEs of β-substituted alkenyl phosphates/sulfonates with substituent constant σp(+) were found. In addition, the NBO analysis further disclosed the essence of the substituent effects on C-O BDEs.

  6. Molecular docking, TG/DTA, molecular structure, harmonic vibrational frequencies, natural bond orbital and TD-DFT analysis of diphenyl carbonate by DFT approach

    Science.gov (United States)

    Xavier, S.; Periandy, S.; Carthigayan, K.; Sebastian, S.

    2016-12-01

    Vibrational spectral analysis of Diphenyl Carbonate (DPC) is carried out by using FT-IR and FT-Raman spectroscopic techniques. It is found that all vibrational modes are in the expected region. Gaussian computational calculations were performed using B3LYP method with 6-311++G (d, p) basis set. The computed geometric parameters are in good agreement with XRD data. The observation shows that the structure of the carbonate group is unsymmetrical by ∼5° due to the attachment of the two phenyl rings. The stability of the molecule arising from hyperconjugative interaction and charge delocalization are analyzed by Natural Bond Orbital (NBO) study and the results show the lone pair transition has higher stabilization energy compared to all other. The 1H and 13C NMR chemical shifts are calculated using the Gauge-Including Atomic Orbital (GIAO) method with B3LYP/6-311++G (d, p) method. The chemical shifts computed theoretically go very closer to the experimental results. A study on the electronic and optical properties; absorption wavelengths, excitation energy, dipole moment and frontier molecular orbital energies and Molecular electrostatic potential (MEP) exhibit the high reactivity nature of the molecule. The non-linear optical property of the DPC molecule predicted theoretically found to be good candidate for NLO material. TG/DTA analysis was made and decomposition of the molecule with respect to the temperature was studied. DPC having the anthelmintic activity is docked in the Hemoglobin of Fasciola hepatica protein. The DPC has been screened to antimicrobial activity and found to exhibit antibacterial effects.

  7. Application of Bridge Self- Vibration Frequency Inspection in TechnicalExamination and Determination of Harbour Bridge in Dalian Port%桥梁自振频率检测在大连港港湾桥技术检定中的应用

    Institute of Scientific and Technical Information of China (English)

    孙敬波; 杨艳; 谢大为; 周发凯

    2001-01-01

    It introduces the main contents and test procedure of technicalexamination and determination for the harbour bridge of Dalian Port, analyzes the application of self- vibration frequency inspection in examination and determination test, and emphasizes the significance of bridge self- vibration frequency inspection in technical examination and determination of bridge.%介绍大连港港湾桥技术检定的主要内容及试验过程;分析自振频率检测在本次检定试验中的应用,强调其在技术检定中的重要意义。

  8. Adaptive Piezoelectric Absorber for Active Vibration Control

    Directory of Open Access Journals (Sweden)

    Sven Herold

    2016-02-01

    Full Text Available Passive vibration control solutions are often limited to working reliably at one design point. Especially applied to lightweight structures, which tend to have unwanted vibration, active vibration control approaches can outperform passive solutions. To generate dynamic forces in a narrow frequency band, passive single-degree-of-freedom oscillators are frequently used as vibration absorbers and neutralizers. In order to respond to changes in system properties and/or the frequency of excitation forces, in this work, adaptive vibration compensation by a tunable piezoelectric vibration absorber is investigated. A special design containing piezoelectric stack actuators is used to cover a large tuning range for the natural frequency of the adaptive vibration absorber, while also the utilization as an active dynamic inertial mass actuator for active control concepts is possible, which can help to implement a broadband vibration control system. An analytical model is set up to derive general design rules for the system. An absorber prototype is set up and validated experimentally for both use cases of an adaptive vibration absorber and inertial mass actuator. Finally, the adaptive vibration control system is installed and tested with a basic truss structure in the laboratory, using both the possibility to adjust the properties of the absorber and active control.

  9. A new approach to electron diffraction analysis of symmetric triatomic molecules with large-amplitude bending motion : The equilibrium geometry, force field and vibrational frequencies of BaI2 as determined by electron diffraction

    Science.gov (United States)

    Spiridonov, V. P.; Gershikov, A. G.; Altman, A. B.; Romanov, G. V.; Ivanov, A. A.

    1981-01-01

    Diffraction data on BaI 2, analyzed by a new approach, indicate an anharmonic potential with a barrier of 71(12) cm -1 at a linear geometry. The structural and vibrational parameters were found to be reh(Ba-I o) = 3.150(7)Å, ∠ eIBaI = 148.0(9) °, fq = 0.69(8) mdyn/Å, fqq= 0.14(6) mdyn/Å, k2 = -0.0075(15) mdyn/Å, k4 = 0.0025(9) mdyn/Å 3, v1 = 106(12) cm -1 and v3 = 145(21) cm -1. The bending frequency v2 is predicted to be near 16 cm -1.

  10. 加权滤波在电梯振动测量中的应用研究%The Application of Frequency Weight Filtering in the Elevator Vibration Measurement

    Institute of Scientific and Technical Information of China (English)

    程耀华

    2013-01-01

    This paper introduces a measurement method of frequency weight filtering that correlates well with human response. In 2013, in the East Guangzhou elevator vibration sampling measurements, this method had been verified and got a well performance.%电梯运行振动可以反映电梯整体性能状况。介绍一种加权滤波测量方法,根据人体对不同频率振动的敏感程度,对电梯运行振动数据采用加权滤波方法衡量。该方法在广州东部地区乘客电梯实际测量中得到验证,取得良好效果。

  11. VIBRATION ANALYSIS OF TURBINE BASED ON FLUID-STRUCTURE COUPLING

    Institute of Scientific and Technical Information of China (English)

    LIU Demin; LIU Xiaobing

    2008-01-01

    The vibration of a Francis turbine is analyzed with the additional quality matrix method based on fluid-structure coupling (FSC). Firstly, the vibration frequency and mode of blade and runner in air and water are calculated. Secondly, the influences to runner frequency domain by large flow, small flow and design flow working conditions are compared. Finally the influences to runner modes by centrifugal forces under three rotating speeds of 400 r/min, 500 r/min and 600 r/min are compared. The centrifugal force and small flow working condition have greatly influence on the vibration of small runner. With the increase of centrifugal force, the vibration frequency of the runner is sharply increased. Some order frequencies are even close to the runner natural frequency in the air. Because the low frequency vibration will severely damage the stability of the turbine, low frequency vibration of units should be avoided as soon as possible.

  12. Surface acoustic wave (SAW) vibration sensors.

    Science.gov (United States)

    Filipiak, Jerzy; Solarz, Lech; Steczko, Grzegorz

    2011-01-01

    In the paper a feasibility study on the use of surface acoustic wave (SAW) vibration sensors for electronic warning systems is presented. The system is assembled from concatenated SAW vibration sensors based on a SAW delay line manufactured on a surface of a piezoelectric plate. Vibrations of the plate are transformed into electric signals that allow identification of the sensor and localization of a threat. The theoretical study of sensor vibrations leads us to the simple isotropic model with one degree of freedom. This model allowed an explicit description of the sensor plate movement and identification of the vibrating sensor. Analysis of frequency response of the ST-cut quartz sensor plate and a damping speed of its impulse response has been conducted. The analysis above was the basis to determine the ranges of parameters for vibrating plates to be useful in electronic warning systems. Generally, operation of electronic warning systems with SAW vibration sensors is based on the analysis of signal phase changes at the working frequency of delay line after being transmitted via two circuits of concatenated four-terminal networks. Frequencies of phase changes are equal to resonance frequencies of vibrating plates of sensors. The amplitude of these phase changes is proportional to the amplitude of vibrations of a sensor plate. Both pieces of information may be sent and recorded jointly by a simple electrical unit.

  13. Surface Acoustic Wave (SAW Vibration Sensors

    Directory of Open Access Journals (Sweden)

    Jerzy Filipiak

    2011-12-01

    Full Text Available In the paper a feasibility study on the use of surface acoustic wave (SAW vibration sensors for electronic warning systems is presented. The system is assembled from concatenated SAW vibration sensors based on a SAW delay line manufactured on a surface of a piezoelectric plate. Vibrations of the plate are transformed into electric signals that allow identification of the sensor and localization of a threat. The theoretical study of sensor vibrations leads us to the simple isotropic model with one degree of freedom. This model allowed an explicit description of the sensor plate movement and identification of the vibrating sensor. Analysis of frequency response of the ST-cut quartz sensor plate and a damping speed of its impulse response has been conducted. The analysis above was the basis to determine the ranges of parameters for vibrating plates to be useful in electronic warning systems. Generally, operation of electronic warning systems with SAW vibration sensors is based on the analysis of signal phase changes at the working frequency of delay line after being transmitted via two circuits of concatenated four-terminal networks. Frequencies of phase changes are equal to resonance frequencies of vibrating plates of sensors. The amplitude of these phase changes is proportional to the amplitude of vibrations of a sensor plate. Both pieces of information may be sent and recorded jointly by a simple electrical unit.

  14. Speed-Frequency Domain Method for the ResponseAnalysis of Vehicle Vibration Acceleration%车辆振动加速度响应分析的速度—频域方法

    Institute of Scientific and Technical Information of China (English)

    康熊; 曾宇清

    2012-01-01

    为直接从车辆振动加速度响应中提取车辆特性和车辆激励特性,引入车辆速度参量,构成系统响应—特性—激励关联方程组;由空间输入功率不变的物理特性得到并论证车辆激励特性随车辆速度变化的频域数值规律:激励频率与车辆速度成正比,随机激励加速度等效功率谱与车辆速度的3次方成正比,周期激励加速度等效功率谱与车辆速度的4次方成正比;车辆特性随车辆速度变化较小,即使发生蛇形,只要振动传递路径不发生变化,轮对以上部件间的振动传递关系也基本与车辆速度无关.据此,给出车辆加速度响应分析的速度—频域方法,通过对速度—频谱和速度—名义传递三维图中基本不随车辆速度变化、随车辆速度线性变化和高速低频区突变3类局部峰值的识别,实现对系统响应—特性—激励关联方程组的工程求解.运用结果表明:该方法有效实现了车辆特性与车辆激励的解耦及耦合分析.%To directly get both vehicle system and excitation characteristics from vehicle vibration acceleration response, system response-characteristics-excitation relevant equations were built through introducing vehicle speed parameter. The numerical correlation of vehicle excitation characteristics changed with vehicle speed in frequency domain was obtained and demonstrated through the physical characteristics of consistent space input power. Excitation frequency is linear to vehicle speed. The stochastic excitation acceleration equivalent power spectrum is linear to the third power of vehicle speed. The periodic excitation acceleration equivalent power spectrum is linear to the forth power of vehicle speed. Vehicle characteristics vary little with vehicle speed. The vibration transmission relationship between components above wheelset basically has nothing to do with vehicle speed as long as the path of vibration transmission remains unchanged even if

  15. Urban vibrations

    DEFF Research Database (Denmark)

    Morrison, Ann; Knudsen, L.; Andersen, Hans Jørgen

    2012-01-01

    In   this   paper   we   describe   a   field   study   conducted   with   a   wearable   vibration   belt   where   we   test   to   determine   the   vibration   intensity   sensitivity   ranges   on   a   large   diverse   group   of   participants   with   evenly   distributed  ages  and......   lab   studies   in   that   we   found   a   decreased   detection   rate   in   busy   environments.   Here   we   test   with   a   much   larger   sample   and   age   range,   and   contribute   with   the   first   vibration  sensitivity  testing  outside  the  lab  in  an  urban   public...

  16. Resonant frequency drift characteristics of straight-line vibration MEMS gyro under heavy load%大载荷下线振动微机械陀螺谐振频率漂移特性

    Institute of Scientific and Technical Information of China (English)

    王巍; 庄海涵; 邢朝洋

    2013-01-01

    The resonant frequencies of a straight line vibration gyro would generate drifts between drive axis and sense axis under heavy angular velocity load. The two frequencies are always designed to be close to get a high sensitivity. But when the angular velocity load is heavy, the resonant frequencies in two axes will drift apart from each other. The amount of the drift has no relationship with the centripetal acceleration, but be proportional to the square of the angular velocity load, and be more drastically when the two resonant frequencies are closer. In this paper, two-dimension vibration differential equations were derived to represent this phenomenon by considering the Coriolis influence, and it is indicated that the drift is caused by the Coriolis influence. The analysis results by the theory solution, simulation method, and the experiment data meet well with each other, and provide a theory basis for the optimization of the dimension parameters.%  线振动 MEMS 陀螺在大载荷条件下,驱动轴与检测轴的谐振频率会发生漂移,频差随载荷变大。这类型振动陀螺为了提高灵敏度往往将两个振动轴的谐振频率设计得尽量靠近,但当角速率载荷较大时,两个振动轴的谐振频率将发生分裂漂移,彼此互相远离。漂移量与向心加速度无关,近似与角速率载荷的平方成正比,且两轴的谐振频率越靠近漂移越剧烈。考虑到 Coriolis 效应的弹簧质量块二维振动数学模型可定量描述该现象,表明此现象为线振动陀螺 Coriolis 效应的一部分。理论分析、仿真研究和实验数据的不同角度对这种频率漂移特性的分析结果吻合良好,为进一步结构优化奠定了理论基础。

  17. Prediction and validation of high frequency vibration repsonses of NASA Mars Pathfinder spacecraft due to acoustic launch load using statistical energy analysis

    Science.gov (United States)

    Hwang, H. J.

    2002-01-01

    Mid and high frequency structural responses of a spacecraft during the launch condition are mainly dominated by the intense acoustic pressure field over the exterior of the launch vehicle. The prediction of structural responses due to the acoustic launch load is therefore an important analysis for engineers and scientists to correctly define various dynamics specifications of the spacecraft.

  18. C/O: Effects on Habitability of Stellar Exoplanet Systems

    Science.gov (United States)

    Johnson, Torrence V.; Sevin Peckmezci, Gül; Mousis, Olivier; Lunine, Jonathan I.; Madhusudhan, Nikku

    2015-11-01

    We assess how differences in the composition of exoplanet host stars might affect the availability of water in their systems, particularly the role of carbon and oxygen abundances. Water, one of the key chemical ingredients for habitability, may be in short supply in carbon-rich, oxygen-poor systems even if planets exist in the ‘habitable zone’. For the solar system, C/O = 0.55 is particularly important in determining the refractory (silicate and metal) to volatile ice ratio expected in material condensed beyond the snow line (Gaidos E. J. Icarus 145, 637, 2000; Wong M. H. et al. in Oxygen in the Solar System, G.J. MacPherson, Ed., 2008). Our analysis of published compositions for a set of exoplanet host stars (Johnson T. V. et al. ApJ. 757(2), 192, 2012) showed that the amount of condensed water ice in those systems might range from as much as 50% by mass for sub-solar C/O = 0.35 to less than a few percent for super-solar C/O = 0.7. A recent analysis using similar techniques (Pekmezci G. S., Dottorato di Ricerca in Astronomia, Università Degli Studi di Roma “Tor Vergata”, 2014) of a much larger stellar composition data set for 974 FGK stars (Petigura E. and Marcy G. Journal of Astrophysics 735, 2011), allows us to assess the possible range of water ice abundance in the circumstellar accretion disks of these ‘solar-type’ stars (of which 72 were known to have one or more planets as of 2011). Stellar C/O in a subset (457 stars) of this stellar database with reported C, O, Ni, and Fe abundances ranges from 0.3 to 1.4. The resulting computed water ice fractions and refractory (silicate + metal) fractions range from ~0 to 0.6 and 0.3 to 0.9 respectively. These results have implications for assessing the habitability of exoplanets since they constrain the amount of water available beyond the snow line for dynamical delivery to inner planets, depending on the host stars’ C/O in the circumstellar nebula. TVJ acknowledges government support at JPL

  19. Polarized and depolarized Raman spectra of liquid carbon disulfide in the pressure range 0-10 kbar. I. Vibration frequencies, C-S bond length, and Fermi resonance

    Science.gov (United States)

    Ikawa, S.; Whalley, Edward

    1986-09-01

    The effect of pressure on the polarized and depolarized Raman spectra of liquid carbon disulphide, i.e., the peak frequencies, bandwidths, and relative intensities of both the allowed ν1 and 2ν2 bands and the interaction-induced ν2 and ν3 bands, have been measured at 22 °C up to 10 kbar. This paper discusses the effect of pressure on the frequencies and on the relative isotropic intensity of the ν1 and 2ν2 bands. The frequency of the ν1 band increases linearly with pressure, within the experimental uncertainty, at the rate 0.16±0.01 cm-1 kbar-1, and the frequencies of the ν2, ν3, and 2ν2 bands decrease nonlinearly. The frequency shifts are described by second-order perturbation theory with the molecular anharmonicity and the intermolecular interaction as perturbations. The leading terms of the shifts consist of the same derivative of the interaction potential, multiplied by different anharmonicity constants, and the shifts of the ν1 and 2ν2 bands suggests that the C-S bond length decreases at the rate 2×10-4 Å kbar-1. The relative isotropic intensity of the 2ν2 and ν1 bands increases with pressure at the rate 0.050 kbar-1, whereas the anisotropic 2ν2 intensity relative to the isotropic ν1 intensity is independent of pressure to the experimental precision of ˜0.005. The effect of pressure on the second derivative of the isotropic and anisotropic parts of the polarizability with respect to the bend coordinate was estimated as 1.1×10-43 C m2 V-1 kbar-1 and ˜0, respectively, from these values.

  20. Nonlinear characteristic analyses of pneumatic vibration isolation system with a multi-frequency excitation%多频激励下气动隔振系统非线性特性分析

    Institute of Scientific and Technical Information of China (English)

    钟艳春; 杨庆俊; 包钢

    2011-01-01

    The nonlinear dynamics characteristic of pneumatic vibration isolation system with a multi-frequency excitation was studied with the method of nonlinear dynamics. First, relative load curve of an air spring under a certain initial pressure was obtained by test, and based on the test data, a cube polynomial equation was obtained by means of nonlinear polynomial curve fitting according to the equilibrium heights of the air spring. Then, the nonlinear model of pneumatic vibration isolation system with a multi-frequency excitation was built and nonlinear dynamics equation was obtained according to nonlinear restoring force of the air spring. Next, the method of multiple scales was used to solve the nonlinear dynamics equation. Finally, combination resonance of pneumatic vibration isolation system with a multi-frequency excitation was analyzed and influences of the nonlinear parameter to the system were discussed. The results show that when combination frequencies are near the linearized natural frequency, combination resonance becomes strong. Cube nonlinear parameter directly influences nonlinear characteristic of the system, the greater the excitation amplitude, the more obvious of the nonlinear characteristic.%运用非线性动力学的方法研究气动隔振系统在多个频率激励下的非线性动力学特性.通过试验的方法得到空气弹簧在一定初始压力下的相对载荷曲线,以空气弹簧工作高度为自变量,用三次多项式对该曲线进行非线性拟合,得到弹簧非线性恢复力与工作高度的三次多项式表达式.建立气动隔振系统在3个激励频率下的非线性模型,根据弹簧的非线性恢复力,得到系统的非线性动力学方程.运用多尺度法对该非线性动力学方程进行求解,分析3个频率共同作用下的组合共振,讨论各非线性参数对系统的影响.研究结果表明:当组合频率接近系统线性化固有频率时,系统具有很强的组合共振;三次非线性

  1. Localized vibrations of graphene nanoribbons

    Science.gov (United States)

    Savin, A. V.; Kivshar, Yu. S.

    2016-08-01

    Vibrational modes of graphene nanoribbons are studied. It is demonstrated that in an unstretched graphene nanoribbon, localized vibrations (in the form of breathers) can occur only at the edges. The largest number of localized edge oscillations is expected for the nanoribbons with the armchair structure. Stretching of a nanoribbon can lead to the appearance of new types of strongly localized oscillations. When a nanoribbon is stretched, in its oscillatory spectrum a frequency gap appears in which the frequencies of the localized modes are located. An armchair nanoribbon can support localized modes only at its edges, while a highly stretched zigzag nanoribbon can support them both at the edges and inside the nanoribbon.

  2. Parametric Vibration and Vibration Reduction of Cables in Cable-stayed Space Latticed Structure

    Institute of Scientific and Technical Information of China (English)

    BAO Yan; ZHOU Dai; LIU Jie

    2008-01-01

    Mechanical model and vibration equation of a cable in cable-stayed sparse latticed structure (CSLS) under external axial excitation were founded. Determination of the mass lumps and natural frequencies supplied by the space latticed structure (SLS) was analyzed. Multiple scales method (MSM) was introduced to analyze the characteristics of cable's parametric vibration, and the precise time-integration method (PTIM) was used to solve vibration equation. The vibration behavior of a cable is closely relative to the frequency ratio of the cable and SLS. The cable's parametric vibration caused by the external axial excitation easily occurs if the frequency ratio of the cable and SLS is in a certain range, and the cable's vibration amplitude varies greatly even if the initial disturbance supplied by SLS changes a little. Furthermore, the mechanical model and vibration equation of the composite cable system consisting of main cables and assistant cables were studied. The parametric analysis such as the pre-tension level and arrangement of the assistant cables was carried out. Due to the assistant cables, the single-cable vibration mode can be transferred to the global vibration mode, and the stiffness and damping of the cable system are enhanced. The natural frequencies of the composite cable system with the curve line arrangement of assistant cables are higher than those with the straight-line arrangement and the former is more effective than the latter on the cable's vibration suppression.

  3. Optimal geometries and harmonic vibrational frequencies of the global minima of water clusters (H2O)n, n = 2-6, and several hexamer local minima at the CCSD(T) level of theory.

    Science.gov (United States)

    Miliordos, Evangelos; Aprà, Edoardo; Xantheas, Sotiris S

    2013-09-21

    We report the first optimum geometries and harmonic vibrational frequencies for the ring pentamer and several water hexamer (prism, cage, cyclic and two book) at the coupled-cluster including single, double, and full perturbative triple excitations (CCSD(T))/aug-cc-pVDZ level of theory. All five examined hexamer isomer minima previously reported by Møller-Plesset perturbation theory (MP2) are also minima on the CCSD(T) potential energy surface (PES). In addition, all CCSD(T) minimum energy structures for the n = 2-6 cluster isomers are quite close to the ones previously obtained by MP2 on the respective PESs, as confirmed by a modified Procrustes analysis that quantifies the difference between any two cluster geometries. The CCSD(T) results confirm the cooperative effect of the homodromic ring networks (systematic contraction of the nearest-neighbor (nn) intermolecular separations with cluster size) previously reported by MP2, albeit with O-O distances shorter by ~0.02 Å, indicating that MP2 overcorrects this effect. The harmonic frequencies at the minimum geometries were obtained by the double differentiation of the CCSD(T) energy using an efficient scheme based on internal coordinates that reduces the number of required single point energy evaluations by ~15% when compared to the corresponding double differentiation using Cartesian coordinates. Negligible differences between MP2 and CCSD(T) frequencies are found for the librational modes, while uniform increases of ~15 and ~25 cm(-1) are observed for the bending and "free" OH harmonic frequencies. The largest differences between CCSD(T) and MP2 are observed for the harmonic hydrogen bonded frequencies, for which the former produces larger absolute values than the latter. Their CCSD(T) redshifts from the monomer values (Δω) are smaller than the MP2 ones, due to the fact that CCSD(T) produces shorter elongations (ΔR) of the respective hydrogen bonded OH lengths from the monomer value with respect to MP2. Both

  4. Damping of roll vibrations of vehicle suspension

    Science.gov (United States)

    Le, K. C.; Pieper, A.

    2014-04-01

    Small forced vibrations of an axle model of independent suspensions having four degrees of freedom are studied. The exact analytical solution of the generalised Lagrange equation enables one to produce 3D plots of the normalised amplitudes of forced vibrations versus frequency and excitation ratio or phase difference of the road inputs. The analysis of these plots exhibits some deficiency in damping of roll vibrations of conventional vehicle suspensions. The possibilities of improvement are discussed.

  5. Localization theory of distributed fiber vibration sensor

    Institute of Scientific and Technical Information of China (English)

    Weimin Chen; Yuanyuan Xie; Peng Zhang; Lei Lin

    2009-01-01

    Based on Sagnac interferometer, a simple distributed optical fiber sensing system with sub-loop is pre-sented to monitor the vibration applied on the sensing fiber. By introducing a sub-loop, three output beams of interference with different delay time are gotten. Location of the vibration is analyzed through mathematical-physical equations. The vibration frequency, amplitude, and location are theoretically sim-ulated. The results agree well with the previous experiments.

  6. Studies Of Residual Flexibility And Vibration Testing

    Science.gov (United States)

    Admire, John R.; Tinker, Michael L.; Bookout, Paul S.; Ivey, Edward W.

    1995-01-01

    Collection of reports presents theoretical and experimental studies in which concept of residual flexibility applied to modal vibration testing and verification of mathematical models of vibrations of flexible structure constrained by another structure. "Residual flexibility" denotes that part of interface flexibility due to mode shapes out of frequency range of test. Studies directed toward assessing residual-flexibility approach as substitute for fixed-base vibrational testing of payloads installed in spacecraft.

  7. Vibration Powered Radiation of Quaking Magnetar

    CERN Document Server

    Bastrukov, S; Xu, R X; Molodtsova, I

    2011-01-01

    In juxtaposition with the standard model of rotation powered pulsar, the model of vibration powered magnetar undergoing quake-induced torsional Alfven vibrations in its own ultra strong magnetic field experiencing decay is considered. The presented line of argument shows that gradual decrease of frequencies (lengthening of periods) of long-periodic pulsed radiation detected from set of X-ray sources can be attributed to magnetic-field-induced energy conversion from seismic vibrations to magneto-dipole radiation of quaking magnetar.

  8. Design for Vibrator Field Experiment Based- on Vibrator- earth System

    Institute of Scientific and Technical Information of China (English)

    Chen Zubin; Lin Jun; Liang Tiecheng; Zhang Linhang

    2000-01-01

    Source- generated energy in seismic vibrator records high frequency harmonic behavior. Conventional vibratorearth coupling model was set up on the linear system. Some assumptions in the application of linear theory to the vibrator problem play an insignificant role in the overall coupling structure. Obviously, non- linear behaviors can be modeled using a "hard - spring" form of the Duffing equation. Model dedicates that a qualitatively similar harmonic component is present for a broad range of possible mathematical descriptions. After some qualitative analysis about the non- linear system, some conclusion can be drawn. Firstly, The design of the vibrator weight should be abided by two points as followed: In order to avoid decoupling for the vibrator to the earth, the weight should be greater than the peak of the driving force amplitude as to keep the resultant force pointing to the earth's core. On the other hand, for the limited energy output, the vibrator overweight may damage the system high - frequency ability. Secondly, as the driving force frequency approaching to the ground hard- spring inherent frequency, the energy transmission was found to climb its peak from the system energy absorbed curve. At last, due to the non- linear coupling model system, its load curve would come into unstable frequency range,which might limit the application of the Vibroseis conventional sweeping pattern - linear sweep. A new sweeping pattern was listed: the driving signal was the pseudo- random sequence modulated by a fixed frequency cosine signal satisfying with the exploration precision and absorbing efficiency. The synthesized signal was ready to be realized by the electromagnetic driven system. Even the side- lobes noise of its auto- correlation function was restrained well. The theory coming from the Vibrator- earth coupling model was applied to the design of the Portable High- frequency Vibrator System (PHVS), and the good result was obtained. By the analysis of the

  9. 面齿轮传动分扭系统扭转振动的固有频率分析%Research on Natural Frequency of Torsional Vibration of Torque-split Face Gear Transmission System

    Institute of Scientific and Technical Information of China (English)

    张乐; 朱如鹏; 李政民卿

    2012-01-01

    Based on the lumped mass method, the dynamic model of torque-split face gear transmission system is built, including the torsional vibration. The stiffness matrix and the mass matrix are performed, and the natural frequency of the system is solved. The influence of the torsional stiffness of the input shaft and the face gear shaft, and the meshing stiffness of the face gear on the system is studied. The result shows that the stiffness of the input shaft and the face gear shaft has great influence on the natural frequency of the system's high level natural frequency, and the meshing stiffness of the face gear has great influence on the system's low level natural frequency.%基于集中质量法,建立了面齿轮传动分扭系统的动力学模型,模型中考虑了系统的扭转振动自由度.列出了系统的刚度矩阵和质量矩阵,求出了系统的各阶固有频率,分析了输入轴和面齿轮轴的扭转刚度以及面齿轮啮合刚度对系统固有频率的影响.结果表明,输入轴和面齿轮轴的扭转刚度对系统的高阶固有频率有较大的影响,面齿轮平均啮合刚度对系统的低阶固有频率有较大的影响.

  10. Vibration Induced Microfluidic Atomization

    Science.gov (United States)

    Yeo, Leslie; Qi, Aisha; Friend, James

    2008-11-01

    We demonstrate rapid generation of micron aerosol droplets in a microfluidic device in which a fluid drop is exposed to surface vibration as it sits atop a piezoelectric substrate. Little, however, is understood about the processes by which these droplets form due to the complex hydrodynamic processes that occur across widely varying length and time scales. Through experiments, scaling theory and numerical modelling, we elucidate the interfacial destabilization mechanisms that lead to droplet formation. Droplets form due to the axisymmetric break-up of cylindrical liquid jets ejected as a consequence of interfacial destabilization. Their 10 μm size correlates with the jet radius and the instability wavelength, both determined from a viscous-capillary dominant force balance and confirmed through a numerical solution. With the exception of drops that spread into thin films with thicknesses on the order of the boundary layer dimension, the free surface is always observed to vibrate at the capillary-viscous resonance frequency despite the surface vibration frequency being several orders larger. This is contrary to common assumptions used in deriving subharmonic models resulting in a Mathieu equation, which has commonly led to spurious predictions in the droplet size.

  11. Vibrating minds

    CERN Multimedia

    2009-01-01

    Ed Witten is one of the leading scientists in the field of string theory, the theory that describes elementary particles as vibrating strings. This week he leaves CERN after having spent a few months here on sabbatical. His wish is that the LHC will unveil supersymmetry.

  12. 非简谐振动对石墨烯杨氏模量与声子频率的影响∗%Influence of the anharmonic vibration on the Young mo dulus and the phonon frequency of the graphene

    Institute of Scientific and Technical Information of China (English)

    程正富; 郑瑞伦

    2016-01-01

    在哈里森键联轨道法框架下,考虑到原子的短程相互作用和原子的非简谐振动,应用固体物理理论和方法,得到了石墨烯的力常数、杨氏模量、扭曲模量、泊松系数以及声子频率随温度的变化关系,探讨了非简谐振动对它们的影响.结果表明:1)杨氏模量与声子频率等随温度变化并遵从一定的规律,其中力常数、杨氏模量、扭曲模量随温度升高而增大,但变化较小;声子频率随温度升高而增大但变化较快;泊松系数随温度升高而较快地减小;2)石墨烯原子具有沿键长方向的纵振动和垂直键长方向的横振动,但以纵振动为主,纵振动的非简谐效应远大于横振动,横振动的简谐系数ε′0和第二非谐系数ε′2均小于纵振动的相应值ε0,ε2;比值为ε0/ε′0≈8.477,ε2/ε′2≈156;3)若不考虑非简谐振动项,则石墨烯的力常数、杨氏模量和扭曲模量、泊松系数、声子频率均为常量,与实验不符合;同时考虑到原子的第一、二非简谐振动项后,它们均随温度升高而变化,而且温度愈高,原子振动的非简谐效应愈显著.本文的结果与文献的实验结果符合较好.%In the frame of the Harrison bonded-orbital method, the variations of the force constant, the Young modulus, the torsional modulus and the phonon frequency with temperature are given through the relevant theory or method of the solid state physics with considering the non-harmonic effect and the short-range interaction of atoms. Results show that the force constant, the Young modulus, the torsional modulus, the phonon frequency and the Poisson’s coeffcient all vary with temperature. The results show that the first three quantities increase with temperature but not very much;the phonon frequency increases with temperature rapidly;the Poisson’s coeffcient decreases fast with the increase of temperature. There are transverse vibrations along the direction

  13. Molecular quantum mechanical gradients within the polarizable embedding approach—Application to the internal vibrational Stark shift of acetophenone

    Energy Technology Data Exchange (ETDEWEB)

    List, Nanna Holmgaard, E-mail: nhl@sdu.dk; Jensen, Hans Jørgen Aagaard; Kongsted, Jacob [Department of Physics, Chemistry and Pharmacy, University of Southern Denmark, Campusvej 55, Odense M, Odense DK-5230 Denmark (Denmark); Beerepoot, Maarten T. P.; Gao, Bin; Ruud, Kenneth [Centre for Theoretical and Computational Chemistry, Department of Chemistry, University of Tromsø–The Arctic University of Norway, N-9037 Tromsø (Norway); Olsen, Jógvan Magnus Haugaard [Department of Physics, Chemistry and Pharmacy, University of Southern Denmark, Campusvej 55, Odense M, Odense DK-5230 Denmark (Denmark); Laboratory of Computational Chemistry and Biochemistry, Ecole Polytechnique Fédérale de Lausanne, CH-1015 Lausanne (Switzerland)

    2015-01-21

    We present an implementation of analytical quantum mechanical molecular gradients within the polarizable embedding (PE) model to allow for efficient geometry optimizations and vibrational analysis of molecules embedded in large, geometrically frozen environments. We consider a variational ansatz for the quantum region, covering (multiconfigurational) self-consistent-field and Kohn–Sham density functional theory. As the first application of the implementation, we consider the internal vibrational Stark effect of the C=O group of acetophenone in different solvents and derive its vibrational linear Stark tuning rate using harmonic frequencies calculated from analytical gradients and computed local electric fields. Comparisons to PE calculations employing an enlarged quantum region as well as to a non-polarizable embedding scheme show that the inclusion of mutual polarization between acetophenone and water is essential in order to capture the structural modifications and the associated frequency shifts observed in water. For more apolar solvents, a proper description of dispersion and exchange–repulsion becomes increasingly important, and the quality of the optimized structures relies to a larger extent on the quality of the Lennard-Jones parameters.

  14. Molecular quantum mechanical gradients within the polarizable embedding approach--application to the internal vibrational Stark shift of acetophenone.

    Science.gov (United States)

    List, Nanna Holmgaard; Beerepoot, Maarten T P; Olsen, Jógvan Magnus Haugaard; Gao, Bin; Ruud, Kenneth; Jensen, Hans Jørgen Aagaard; Kongsted, Jacob

    2015-01-21

    We present an implementation of analytical quantum mechanical molecular gradients within the polarizable embedding (PE) model to allow for efficient geometry optimizations and vibrational analysis of molecules embedded in large, geometrically frozen environments. We consider a variational ansatz for the quantum region, covering (multiconfigurational) self-consistent-field and Kohn-Sham density functional theory. As the first application of the implementation, we consider the internal vibrational Stark effect of the C=O group of acetophenone in different solvents and derive its vibrational linear Stark tuning rate using harmonic frequencies calculated from analytical gradients and computed local electric fields. Comparisons to PE calculations employing an enlarged quantum region as well as to a non-polarizable embedding scheme show that the inclusion of mutual polarization between acetophenone and water is essential in order to capture the structural modifications and the associated frequency shifts observed in water. For more apolar solvents, a proper description of dispersion and exchange-repulsion becomes increasingly important, and the quality of the optimized structures relies to a larger extent on the quality of the Lennard-Jones parameters.

  15. Application of the Quartz-flexure Accelerometer to the Development of Ultra-low Frequency Vibration National Primary Standard Device%石英挠性加速度计在超低频振动国家基准研制中的应用研究

    Institute of Scientific and Technical Information of China (English)

    于梅; 刘爱东; 何闻; 杨丽峰; 胡红波; 左爱斌; 马明德

    2011-01-01

    The improved quartz-flexure accelerometer with independent developed condition-amplifier is adopted as the vibration pickup sensor in ultra-low frequency vibration feedback control, and as the standard implement for performance measuring of ultra-low frequency vibration primary standard device.The distortion of vibrator output acceleration waveform is decreased effectively, and the effect of environmental vibration is suppressed to some extent.The acceleration distortion is less than 1% above 0.002 Hz.It solves the measurement means problem caused by without measuring sensor below 1Hz.The stability and repeatability meet requirements of standard devices.It is considered that it can be used as the standard implement of calibration and the check standard for low frequency or ultra-low frequency vibration national primary standard and standard devices.%介绍了超低频振动国家基准装置.采用改进型石英挠性加速度计SA704和研发的适配器MSA-I组成的振动套组,作为超低频振动台负反馈控制的拾振器和装置性能测试的标准器,有效地降低了振动台台面输出加速度波形的失真度,抑制了环境振动的影响,实现了0.002 Hz以上加速度失真度小于1%;解决了1 Hz以下超低频段无测量传感器的问题.该套组可作为低频和超低频振动基标准装置量值传递的标准器和核查标准.

  16. Low-Frequency Vibrational Modes of Poly(glycolic acid) and Thermal Expansion of Crystal Lattice Assigned On the Basis of DFT-Spectral Simulation Aided with a Fragment Method.

    Science.gov (United States)

    Yamamoto, Shigeki; Miyada, Mai; Sato, Harumi; Hoshina, Hiromichi; Ozaki, Yukihiro

    2017-02-09

    Low-frequency vibrational modes of lamellar crystalline poly(glycolic acid) (PGA) were measured on Raman and far-infrared (FIR) spectra. Among the observed bands, an FIR band at ∼70 cm(-1) and a Raman band at 125 cm(-1) showed a gradual lower-frequency shift with increasing temperature from 20 °C to the melting point at ∼230 °C. Their polarization direction was perpendicular to the chain axis of PGA. Both spectra were quantum-mechanically simulated with the aid of a fragment method, the Cartesian-coordinate tensor transfer, which enabled an explicit consideration of molecular interactions between two adjacent polymer chains. Good agreement was achieved between the experiment and theory in both spectra. The temperature-sensitive bands at ∼70 cm(-1) in FIR and at 125 cm(-1) in Raman comprise the out-of-plane C═O bending motion. The temperature-dependent shifts of the low-frequency bands were successfully simulated by the DFT-spectral calculation, exploring that the main origin of the shifts is the thermal expansion of the crystal lattice. This result indicates that the thermally shifted bands may be used as an indicator of the lattice expansion of PGA. Possible changes in intermolecular interactions of PGA under temperature rising were ascribed on the basis of natural bond orbital theory. The steric repulsion between the carbonyl O atom in one chain and the H-C bond in the adjacent chain will be a dominant interaction in the lattice-expanding process, which would cause the observed thermal shifts of the bending modes. Comparisons of the spectral assignment for PGA obtained in this study and that for poly-(R)-3-hydroxybutyrate (PHB) reported by us suggest that crystalline polyesters give vibrational modes composed of out-of-plane bending motion of C═O groups between ∼70 and ∼125 cm(-1), the modes of which are sensitive to the thermal expansion of crystal lattice and its concomitant changes in their intermolecular interactions.

  17. Free vibration of membrane/bounded incompressible fluid

    Institute of Scientific and Technical Information of China (English)

    S.TARIVERDILO; J.MIRZAPOUR; M.SHAHMARDANI; G.REZAZADEH

    2012-01-01

    Vibration of a circular membrane in contact with a fluid has extensive applications in industry.The natural vibration frequencies for the asymmetric free vibration of a circular membrane in contact with a bounded incompressible fluid are derived in this paper.Considering small oscillations induced by the membrane vibration in an incompressible and inviscid fluid,the velocity potential function is used to describe the fluid field.Two approaches are used to derive the free vibration frequencies of the system,which include a variational formulation and an approximate solution employing the Rayleigh quotient method.A good correlation is found between free vibration frequencies evaluated by these methods.Finally,the effects of the fluid depth,the mass density,and the radial tension on the free vibration frequencies of the coupled system are investigated.

  18. An Abnormal Vibrational Mode of Torsion Pendulum

    Institute of Scientific and Technical Information of China (English)

    赵亮; 涂英; 顾邦明; 胡忠坤; 罗俊

    2003-01-01

    In the experiment for the determination of the gravitational constant G, we found an abnormal vibrational mode of the torsion pendulum. The abnormal mode disappeared as a magnetic damper was introduced to the torsion pendulum system. Our experimental results also show that the magnetic damper can be used to suppress the high frequency vibrational noises to torsion pendulums effectively.

  19. In Situ Adsorption Studies at the Solid/Liquid Interface:Characterization of Biological Surfaces and Interfaces Using SumFrequency Generation Vibrational Spectroscopy, Atomic Force Microscopy,and Quartz Crystal Microbalance

    Energy Technology Data Exchange (ETDEWEB)

    Phillips, Diana Christine [Univ. of California, Berkeley, CA (United States)

    2006-01-01

    Sum frequency generation (SFG) vibrational spectroscopy, atomic force microscopy (AFM), and quartz crystal microbalance (QCM) have been used to study the molecular surface structure, surface topography and mechanical properties, and quantitative adsorbed amount of biological molecules at the solid-liquid interface. The molecular-level behavior of designed peptides adsorbed on hydrophobic polystyrene and hydrophilic silica substrates has been examined as a model of protein adsorption on polymeric biomaterial surfaces. Proteins are such large and complex molecules that it is difficult to identify the features in their structure that lead to adsorption and interaction with solid surfaces. Designed peptides which possess secondary structure provide simple model systems for understanding protein adsorption. Depending on the amino acid sequence of a peptide, different secondary structures (α-helix and β-sheet) can be induced at apolar (air/liquid or air/solid) interfaces. Having a well-defined secondary structure allows experiments to be carried out under controlled conditions, where it is possible to investigate the affects of peptide amino acid sequence and chain length, concentration, buffering effects, etc. on adsorbed peptide structure. The experiments presented in this dissertation demonstrate that SFG vibrational spectroscopy can be used to directly probe the interaction of adsorbing biomolecules with a surface or interface. The use of well designed model systems aided in isolation of the SFG signal of the adsorbing species, and showed that surface functional groups of the substrate are sensitive to surface adsorbates. The complementary techniques of AFM and QCM allowed for deconvolution of the effects of surface topography and coverage from the observed SFG spectra. Initial studies of biologically relevant surfaces are also presented: SFG spectroscopy was used to study the surface composition of common soil bacteria for use in bioremediation of nuclear waste.

  20. Synchronization between excitation and response signals in frequency response function estimation for MIMO random vibration test%MIMO随机振动试验频响估计中激励和响应的同步方法

    Institute of Scientific and Technical Information of China (English)

    崔旭利; 陈怀海; 贺旭东; 姜双燕

    2012-01-01

    频响函数估计是多输入多输出随机振动试验控制算法中的必要环节.在振动环境试验中,通常不采集振动台的实际激励信号,而用实测的响应信号和计算机内存中的激励信号来进行系统频响函数估计.由于计算机内存中的激励信号与实际振动台上的激励信号之间在相位上存在着差异,从而导致实测的响应信号和计算机内存中的激励信号不同步.这给系统频响函数的估计带来了较大困难.为此,根据线性系统中激励和响应之间的关系,结合随机减量法,提出了一种二次相关法用于系统频响函数的估计,用该方法进行频响函数估计只需要采集响应信号.在三轴振动台上进行了对比试验,结果验证了所提出的二次相关法的正确性.%The estimation of frequency response functions ( FRFs) is unavoidable in MIMO ( multiple input and multiple output) random vibration test control. The actual excitation signals on the shaker tables are always not sampled during the vibration test. So, the FRFs are usually estimated by the response signals acturally measured and the excitation signals stored in the computer memory. Because there is a phase lag between the signal in the memory and the actual signal on the shaker table, the response signal is not synchronous with the memory excitation signal, which makes difficulty to estimat FRFs. Based on the relationship between the excitation and response in linear system and utilizing the random decrement technique, a dual correlation method ( DCM) was presented to estimate FRFs without measuring the actual driving force signals. A comparison test between DCM and the conventional method which needs to sample the excitation and response signals simultaneously was accomplished on a 3-axis vibration table. The result shows the correctness of the presented DCM.

  1. 一种应变式超低频微振动测试台%An ultra-low frequency micro-vibration testing platform based on strain-resistance effect

    Institute of Scientific and Technical Information of China (English)

    陈江攀; 程伟; 夏明一

    2014-01-01

    In order to measure micro-vibration of a SADA (solar array drive assembly ) in low and ultra-low frequency zone caused by electromechanical coupling,a six-component testing platform based on strain-resistance effect was developed.Its response characteristic in low frequency zone was outstanding and its installation interface was flexible. The working principle and dynamic calibration method of this platform were introduced in detail.In order to assess the performance of this testing platform,linearity examination,natural frequencies measurement and dynamic testing error examination for it were done.The results showed that linearity errors of eight force sensors are within 3.4% under the action of external force within 1 00N;there are no natural frequencies within 1 00Hz,so that the micro-vibration signals can not be modulated through structural coupling in frequency domain of (0 -1 00Hz );dynamic testing errors of six components are within ±9.6% in frequency domain of (0 -1 00Hz),testing resolutions of three forces and three moments can reach 0.0lN and 0.001 N.m,respectively.%为了测试卫星太阳翼驱动机构低频、超低频区由机电耦合产生的微振动,发明了一种应变式超低频微振动六分量测试台,该测试台低频响应特性好,安装接口灵活。介绍该测试台的工作原理和动态标定方法,并对该测试台进行了线性度检验、固有频率测试以及动态测试误差检验。通过线性度检验可得:在100 N范围内的外力作用下,组成该测试台的八个双孔梁应变式力传感器的线性度相对误差在±3.4%以内;通过固有频率测试可得:该测试台在100 Hz内没有固有频率,不会通过结构耦合对被测微振动信号进行调制;通过动态测试误差检验可得:在频域上0!100 Hz范围内,该测试台对六个分量动态测试的相对误差在±9.6%以内,同时还可以得出该测试台对三个力分量和三个力矩分量

  2. Vibrational and electronic spectroscopic studies of melatonin

    Science.gov (United States)

    Singh, Gurpreet; Abbas, J. M.; Dogra, Sukh Dev; Sachdeva, Ritika; Rai, Bimal; Tripathi, S. K.; Prakash, Satya; Sathe, Vasant; Saini, G. S. S.

    2014-01-01

    We report the infrared absorption and Raman spectra of melatonin recorded with 488 and 632.8 nm excitations in 3600-2700 and 1700-70 cm-1 regions. Further, we optimized molecular structure of the three conformers of melatonin within density functional theory calculations. Vibrational frequencies of all three conformers have also been calculated. Observed vibrational bands have been assigned to different vibrational motions of the molecules on the basis of potential energy distribution calculations and calculated vibrational frequencies. Observed band positions match well with the calculated values after scaling except Nsbnd H stretching mode frequencies. It is found that the observed and calculated frequencies mismatch of Nsbnd H stretching is due to intermolecular interactions between melatonin molecules.

  3. A study of internal rotations and vibrational spectra of oxiranemethanol ( glycidol)

    Science.gov (United States)

    Badawi, Hassan M.; Ali, Shaikh A.

    2009-10-01

    The conformational stability and the C-O and O-H internal rotations in oxiranemethanol were investigated at the DFT-B3LYP/6-311G**, MP2/6-311G** and MP4(SDQ)/6-311G** levels of theory. Three minima were predicted in the CCOH potential energy scans of the molecule to have relative energies of about 2 kcal/mol or less and all were calculated to have real frequencies upon full optimization of structural parameters at the DFT and the MP2 levels of calculations. The Cg1 ( H bond inner) conformation was predicted to be the lowest energy conformation for oxiranemethanol in excellent agreement with an earlier microwave study. The equilibrium mixture was calculated from Gibb's free-energy changes to be about 79% Cg1, 17 % G1g and 3% Gg1 at the B3LYP/6-311G** level and about 87% Cg1, 11 % G1g and 2% Gg1 at the MP2/6-311G** level for oxiranemethanol at 298.15 K. No conclusive evidence was obtained for the presence of high-energy form in the liquid phase of oxiranemethanol. The vibrational frequencies of oxiranemethanol in its three stable forms were computed at the B3LYP level and complete vibrational assignments were made for the lowest energy Cg1 form on basis of calculated and experimental data of the molecule.

  4. Moire interferometry for vibration analysis of plates

    Science.gov (United States)

    Asundi, A.; Cheung, M. T.

    1987-12-01

    Moire interferometry is used to locate nodal regions and measure vibration amplitudes of sinusoidally vibrating square plates. The high sensitivity afforded by this technique makes possible the study of plate vibrations at high frequencies and low amplitudes. The initial pattern is modulated by the zero-order Bessel function representing the vibratory motion. The fringe (or fringes) with best contrast indicate the nodal regions, while the higher order fringes, describing loci of points vibrating with the same amplitude, have decreasing contrast which is improved by spatial filtering.

  5. What is limiting low-temperature atomic layer deposition of Al{sub 2}O{sub 3}? A vibrational sum-frequency generation study

    Energy Technology Data Exchange (ETDEWEB)

    Vandalon, V., E-mail: v.vandalon@tue.nl, E-mail: w.m.m.kessels@tue.nl; Kessels, W. M. M., E-mail: v.vandalon@tue.nl, E-mail: w.m.m.kessels@tue.nl [Department of Applied Physics, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven (Netherlands)

    2016-01-04

    The surface reactions during atomic layer deposition (ALD) of Al{sub 2}O{sub 3} from Al(CH{sub 3}){sub 3} and H{sub 2}O have been studied with broadband sum-frequency generation to reveal what is limiting the growth at low temperatures. The –CH{sub 3} surface coverage was measured for temperatures between 100 and 300 °C and the absolute reaction cross sections, describing the reaction kinetics, were determined for both half-cycles. It was found that –CH{sub 3} groups persisted on the surface after saturation of the H{sub 2}O half-cycle. From a direct correlation with the growth per cycle, it was established that the reduced reactivity of H{sub 2}O towards –CH{sub 3} is the dominant factor limiting the ALD process at low temperatures.

  6. Helicopter crew/passenger vibration sensitivity -

    Science.gov (United States)

    Gabel, R.; Reed, D. A.

    1972-01-01

    Helicopter crew and passenger vibration sensitivity are presented. Pilot subjective ratings are established for discrete frequencies and the impact of combinations of harmonic frequencies is examined. A passenger long term comfort level and a short term limit are defined for discrete frequencies and compared with pilot ratings. The results show reasonable agreement between pilot and passenger. Subjective comfort levels obtained for mixed frequency environments clearly demonstrate the need for a multi-frequency criterion.

  7. Vibrational Modes of Trumpet Bells

    Science.gov (United States)

    MOORE, T. R.; KAPLON, J. D.; MCDOWALL, G. D.; MARTIN, K. A.

    2002-07-01

    We report on an investigation of the normal modes of vibration of the bells of several modern trumpets. We describe the results of experiments using electronic speckle-pattern interferometry to visualize the modal structure and we show that the mode frequencies follow a generalized version of Chladni's law.

  8. Chladni's law for vibrating plates

    Science.gov (United States)

    Rossing, Thomas D.

    1982-03-01

    The normal vibrational modes of free circular plates can be classified according to the number of nodal diameters m and the number of nodal circles n. Chladni observed that the addition of one nodal circle raised the frequency f about the same amount as adding two nodal diameters, and Rayleigh pointed out that f is proportional to (m+2n)2 for large f. Waller, however, concluded that the number of nodal diameters necessary to raise the frequency as much as a nodal circle varies from two to five. We have examined data on the vibrations of flat and non-flat circular plates and fitted their vibration frequencies to the relationship f = c(m+bn)k. By proper choice of c it is possible to satisfy Chladni's law (b = 2, k = 2) over quite a wide range of frequency in flat plates. Non-flat plates such as cymbals and bells, require different choices of b and k. A brief history of Chladni patterns, and suggestions for observing and demonstrating the vibrational modes of plates are included (AIP).

  9. Force transmissibility and vibration power flow behaviour of inerter-based vibration isolators

    Science.gov (United States)

    Yang, Jian

    2016-09-01

    This paper investigates the dynamics and performance of inerter-based vibration isolators. Force / displacement transmissibility and vibration power flow are obtained to evaluate the isolation performance. Both force and motion excitations are considered. It is demonstrated that the use of inerters can enhance vibration isolation performance by enlarging the frequency band of effective vibration isolation. It is found that adding inerters can introduce anti-resonances in the frequency-response curves and in the curves of the force and displacement transmissibility such that vibration transmission can be suppressed at interested excitation frequencies. It is found that the introduction of inerters enhances inertial coupling and thus have a large influence on the dynamic behaviour at high frequencies. It is shown that force and displacement transmissibility increases with the excitation frequency and tends to an asymptotic value as the excitation frequency increases. In the high-frequency range, it was shown that adding inerters can result in a lower level of input power. These findings provide a better understanding of the effects of introducing inerters to vibration isolation and demonstrate the performance benefits of inerter-based vibration isolators.

  10. THE POTENTIAL NEURAL MECHANISMS OF ACUTE INDIRECT VIBRATION

    Directory of Open Access Journals (Sweden)

    Darryl J. Cochrane

    2011-03-01

    Full Text Available There is strong evidence to suggest that acute indirect vibration acts on muscle to enhance force, power, flexibility, balance and proprioception suggesting neural enhancement. Nevertheless, the neural mechanism(s of vibration and its potentiating effect have received little attention. One proposal suggests that spinal reflexes enhance muscle contraction through a reflex activity known as tonic vibration stretch reflex (TVR, which increases muscle activation. However, TVR is based on direct, brief, and high frequency vibration (>100 Hz which differs to indirect vibration, which is applied to the whole body or body parts at lower vibration frequency (5-45 Hz. Likewise, muscle tuning and neuromuscular aspects are other candidate mechanisms used to explain the vibration phenomenon. But there is much debate in terms of identifying which neural mechanism(s are responsible for acute vibration; due to a number of studies using various vibration testing protocols. These protocols include: different methods of application, vibration variables, training duration, exercise types and a range of population groups. Therefore, the neural mechanism of acute vibration remain equivocal, but spinal reflexes, muscle tuning and neuromuscular aspects are all viable factors that may contribute in different ways to increasing muscular performance. Additional research is encouraged to determine which neural mechanism(s and their contributions are responsible for acute vibration. Testing variables and vibration applications need to be standardised before reaching a consensus on which neural mechanism(s occur during and post-vibration

  11. Lattice Vibrations in Chlorobenzenes:

    DEFF Research Database (Denmark)

    Reynolds, P. A.; Kjems, Jørgen; White, J. W.

    1974-01-01

    Lattice vibrational dispersion curves for the ``intermolecular'' modes in the triclinic, one molecule per unit cell β phase of p‐C6D4Cl2 and p‐C6H4Cl2 have been obtained by inelastic neutron scattering. The deuterated sample was investigated at 295 and at 90°K and a linear extrapolation to 0°K...... by consideration of electrostatic forces or by further anisotropy in the dispersion forces not described in the atom‐atom model. Anharmonic effects are shown to be large, but the dominant features in the temperature variation of frequencies are describable by a quasiharmonic model....

  12. Performance of a Piezoelectric Energy Harvester under Vibrations Taken from a Helicopter

    OpenAIRE

    Zhu, Dibin; Beeby, Steve; Tudor, John; Grabham, Neil; White, Neil; Harris, Nick

    2011-01-01

    This paper compares performance of a piezoelectric vibration energy harvester, in terms of output power, under different types of vibration. The most common method used to characterize a vibration energy harvester is to excite the energy harvester under a sinusoidal vibration of its resonant frequency and measure the voltage across certain electrical loads. However, in practical applications, the vibration spectrum usually contains multiple peaks at different frequencies. In this research, a ...

  13. Human response to vibration in residential environments.

    Science.gov (United States)

    Waddington, David C; Woodcock, James; Peris, Eulalia; Condie, Jenna; Sica, Gennaro; Moorhouse, Andrew T; Steele, Andy

    2014-01-01

    This paper presents the main findings of a field survey conducted in the United Kingdom into the human response to vibration in residential environments. The main aim of this study was to derive exposure-response relationships for annoyance due to vibration from environmental sources. The sources of vibration considered in this paper are railway and construction activity. Annoyance data were collected using questionnaires conducted face-to-face with residents in their own homes. Questionnaires were completed with residents exposed to railway induced vibration (N = 931) and vibration from the construction of a light rail system (N = 350). Measurements of vibration were conducted at internal and external positions from which estimates of 24-h vibration exposure were derived for 1073 of the case studies. Sixty different vibration exposure descriptors along with 6 different frequency weightings were assessed as potential predictors of annoyance. Of the exposure descriptors considered, none were found to be a better predictor of annoyance than any other. However, use of relevant frequency weightings was found to improve correlation between vibration exposure and annoyance. A unified exposure-response relationship could not be derived due to differences in response to the two sources so separate relationships are presented for each source.

  14. Vibration in metal and non-metal incubators.

    Science.gov (United States)

    Youngblut, J M; Lewandowski, W; Casper, G R; Youngblut, W R

    1994-01-01

    The purpose of this study was to determine the amount of vibration transmitted to the surface of an incubator mattress. Empty incubators with metal (n = 12) and non-metal (n = 12) bases were monitored for vibration levels when the incubators were turned "off" and when they were turned "on." High levels of low-frequency vibration were detected in both types of incubators in both conditions. The metal incubators transmitted significantly less vibration to the mattress than did the non-metal incubators at several frequencies in the "off," the "on," and the "adjusted" conditions. These results suggest that infants experience significant whole-body vibration while lying in incubators.

  15. Optimal active vibration absorber - Design and experimental results

    Science.gov (United States)

    Lee-Glauser, Gina; Juang, Jer-Nan; Sulla, Jeffrey L.

    1993-01-01

    An optimal active vibration absorber can provide guaranteed closed-loop stability and control for large flexible space structures with collocated sensors/actuators. The active vibration absorber is a second-order dynamic system which is designed to suppress any unwanted structural vibration. This can be designed with minimum knowledge of the controlled system. Two methods for optimizing the active vibration absorber parameters are illustrated: minimum resonant amplitude and frequency matched active controllers. The Controls-Structures Interaction Phase-1 Evolutionary Model at NASA LaRC is used to demonstrate the effectiveness of the active vibration absorber for vibration suppression. Performance is compared numerically and experimentally using acceleration feedback.

  16. Optimal active vibration absorber: Design and experimental results

    Science.gov (United States)

    Lee-Glauser, Gina; Juang, Jer-Nan; Sulla, Jeffrey L.

    1992-01-01

    An optimal active vibration absorber can provide guaranteed closed-loop stability and control for large flexible space structures with collocated sensors/actuators. The active vibration absorber is a second-order dynamic system which is designed to suppress any unwanted structural vibration. This can be designed with minimum knowledge of the controlled system. Two methods for optimizing the active vibration absorber parameters are illustrated: minimum resonant amplitude and frequency matched active controllers. The Controls-Structures Interaction Phase-1 Evolutionary Model at NASA LaRC is used to demonstrate the effectiveness of the active vibration absorber for vibration suppression. Performance is compared numerically and experimentally using acceleration feedback.

  17. Absolute Orientation of Molecules with Competing Hydrophilic Head Groups at the Air/Water Interface Probed with Sum Frequency Generation Vibrational Spectroscopy

    Institute of Scientific and Technical Information of China (English)

    Feng Wang; Zhi Huang; Zhifeng Cui; Hongfei Wang

    2009-01-01

    The constructive or destructive spectral interference between the molecular groups oriented up and down at the interface in the sum-frequency generation (SFG) spectra provides a direct measurement of the absolute orientation of these molecular groups. This simple approach can be employed to interrogate absolute molecular orientations other than using the complex absolute phase measurement in the SFG studies. We used the -CN group in the p-cyanophenol (PCP) molecule as the internal phase standard, and we measured the phases of the SFG fields of the -CN groups in the 3,5-dimethyl-4-hydroxy-benzonitrile (35DMHBN)and 2,6-dimethyl-4-hydroxy-benzonitrile (26DMHBN) at the air/water interface by measuring the SFG spectra of the aqueous surfaces of the mixtures of the PCP, 35DMHBN, and 26DMHBN solutions. The results showed that the 35DMHBN had its -CN group pointing into the aqueous phase; while the 26DMHBN, similar to the PCP, had its -CN group pointing away from the aqueous phase. The tilt angles of the -CN group for both the 35DMHBN and 26DMHBN molecules at the air/water interface were around 25°-45° from the interface normal. These results provided insights on the understanding of the detailed balance of the competing factors, such as solvation of the polar head groups, hydrogen bonding and hydrophobic effects, etc., on influencing the absolute molecular orientation at the air/water interface.

  18. Mechanism of bubble detachment from vibrating walls

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Dongjun; Park, Jun Kwon, E-mail: junkeun@postech.ac.kr; Kang, Kwan Hyoung [Department of Mechanical Engineering, Pohang University of Science and Technology (POSTECH), San 31, Hyoja-dong, Pohang 790-784 (Korea, Republic of); Kang, In Seok [Department of Chemical Engineering, Pohang University of Science and Technology (POSTECH), San 31, Hyoja-dong, Pohang 790-784 (Korea, Republic of)

    2013-11-15

    We discovered a previously unobserved mechanism by which air bubbles detach from vibrating walls in glasses containing water. Chaotic oscillation and subsequent water jets appeared when a wall vibrated at greater than a critical level. Wave forms were developed at water-air interface of the bubble by the wall vibration, and water jets were formed when sufficiently grown wave-curvatures were collapsing. Droplets were pinched off from the tip of jets and fell to the surface of the glass. When the solid-air interface at the bubble-wall attachment point was completely covered with water, the bubble detached from the wall. The water jets were mainly generated by subharmonic waves and were generated most vigorously when the wall vibrated at the volume resonant frequency of the bubble. Bubbles of specific size can be removed by adjusting the frequency of the wall's vibration.

  19. Low cost subpixel method for vibration measurement

    Science.gov (United States)

    Ferrer, Belen; Espinosa, Julian; Roig, Ana B.; Perez, Jorge; Acevedo, Pablo; Mas, David

    2014-05-01

    Traditional vibration measurement methods are based on devices that acquire local data by direct contact (accelerometers, GPS) or by laser beams (Doppler vibrometers). Our proposal uses video processing to obtain the vibration frequency directly from the scene, without the need of auxiliary targets or devices. Our video-vibrometer can obtain the vibration frequency at any point in the scene and can be implemented with low-cost devices, such as commercial cameras. Here we present the underlying theory and some experiments that support our technique.

  20. Low cost subpixel method for vibration measurement

    Energy Technology Data Exchange (ETDEWEB)

    Ferrer, Belen [Department of Civil Engineering, Univ. Alicante P.O. Box, 99, 03080 Alicante (Spain); Espinosa, Julian; Perez, Jorge; Acevedo, Pablo; Mas, David [Inst. of Physics Applied to the Sciences and Technologies, Univ. Alicante P.O. Box, 99, 03080 Alicante (Spain); Roig, Ana B. [Department of Optics, Univ. Alicante P.O. Box, 99, 03080 Alicante (Spain)

    2014-05-27

    Traditional vibration measurement methods are based on devices that acquire local data by direct contact (accelerometers, GPS) or by laser beams (Doppler vibrometers). Our proposal uses video processing to obtain the vibration frequency directly from the scene, without the need of auxiliary targets or devices. Our video-vibrometer can obtain the vibration frequency at any point in the scene and can be implemented with low-cost devices, such as commercial cameras. Here we present the underlying theory and some experiments that support our technique.

  1. Low vibration laboratory with a single-stage vibration isolation for microscopy applications

    Science.gov (United States)

    Voigtländer, Bert; Coenen, Peter; Cherepanov, Vasily; Borgens, Peter; Duden, Thomas; Tautz, F. Stefan

    2017-02-01

    The construction and the vibrational performance of a low vibration laboratory for microscopy applications comprising a 100 ton floating foundation supported by passive pneumatic isolators (air springs), which rest themselves on a 200 ton solid base plate, are discussed. The optimization of the air spring system leads to a vibration level on the floating floor below that induced by an acceleration of 10 ng for most frequencies. Additional acoustic and electromagnetic isolation is accomplished by a room-in-room concept.

  2. Physiology responses of Rhesus monkeys to vibration

    Science.gov (United States)

    Hajebrahimi, Zahra; Ebrahimi, Mohammad; Alidoust, Leila; Arabian Hosseinabadi, Maedeh

    Vibration is one of the important environmental factors in space vehicles that it can induce severe physiological responses in most of the body systems such as cardiovascular, respiratory, skeletal, endocrine, and etc. This investigation was to assess the effect of different vibration frequencies on heart rate variability (HRV), electrocardiograms (ECG) and respiratory rate in Rhesus monkeys. Methods: two groups of rhesus monkey (n=16 in each group) was selected as control and intervention groups. Monkeys were held in a sitting position within a specific fixture. The animals of this experiment were vibrated on a table which oscillated right and left with sinusoidal motion. Frequency and acceleration for intervention group were between the range of 1 to 2000 Hz and +0.5 to +3 G during 36 weeks (one per week for 15 min), respectively. All of the animals passed the clinical evaluation (echocardiography, sonography, radiography and blood analysis test) before vibration test and were considered healthy and these tests repeated during and at the end of experiments. Results and discussions: Our results showed that heart and respiratory rates increased significantly in response to increased frequency from 1 to 60 Hz (p monkeys passed vibration experiment successfully without any arrhythmic symptoms due to electrocardiography analysis. Conclusion: Our results indicate that vibration in low frequency can effect respiratory and cardiovascular function in rhesus monkey. Keywords: Vibration, rhesus monkey, heart rate, respiratory rate

  3. Bevel Gearbox Fault Diagnosis using Vibration Measurements

    Directory of Open Access Journals (Sweden)

    Hartono Dennis

    2016-01-01

    Full Text Available The use of vibration measurementanalysis has been proven to be effective for gearbox fault diagnosis. However, the complexity of vibration signals observed from a gearbox makes it difficult to accurately detectfaults in the gearbox. This work is based on a comparative studyof several time-frequency signal processing methods that can be used to extract information from transient vibration signals containing useful diagnostic information. Experiments were performed on a bevel gearbox test rig using vibration measurements obtained from accelerometers. Initially, thediscrete wavelet transform was implementedfor vibration signal analysis to extract the frequency content of signal from the relevant frequency region. Several time-frequency signal processing methods werethen incorporated to extract the fault features of vibration signals and their diagnostic performances were compared. It was shown thatthe Short Time Fourier Transform (STFT could not offer a good time resolution to detect the periodicity of the faulty gear tooth due the difficulty in choosing an appropriate window length to capture the impulse signal. The Continuous Wavelet Transform (CWT, on the other hand, was suitable to detection of vibration transients generated by localized fault from a gearbox due to its multi-scale property. However, both methods still require a thorough visual inspection. In contrast, it was shown from the experiments that the diagnostic method using the Cepstrumanalysis could provide a direct indication of the faulty tooth without the need of a thorough visual inspection as required by CWT and STFT.

  4. Stopping power of C, O and Cl in tantalum oxide

    Energy Technology Data Exchange (ETDEWEB)

    Barradas, Nuno P., E-mail: nunoni@ctn.ist.utl.pt [Centro de Ciências e Tecnologias Nucleares, Instituto Superior Técnico, Universidade de Lisboa, Estrada Nacional 10, ao km 139.7, 2695-066 Bobadela LRS (Portugal); Laboratório de Engenharia Nuclear, Instituto Superior Técnico, Universidade de Lisboa, Estrada Nacional 10, ao km 139.7, 2695-066 Bobadela LRS (Portugal); Alves, E. [Associação Euratom/IST, Instituto de Plasmas e Fusão Nuclear, Instituto Superior Técnico, Universidade Técnica de Lisboa, Av. Rovisco Pais, Lisboa 1049-001 (Portugal); Fonseca, M. [Dep. Física, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, 2829- 516 Caparica (Portugal); ISLA Campus Lisboa| Laureate International Universities, 1500-210 Lisboa (Portugal); Siketić, Z.; Bogdanović Radović, I. [Ruđer Bošković Institute, P.O. Box 180, 10002 Zagreb (Croatia)

    2014-08-01

    Highlights: •We measured the stopping power of C, O, and Cl in tantalum oxide. •A bulk sample method was used, with Bayesian inference data analysis. •Good agreement was found with SRIM2012 calculations. -- Abstract: Tantalum oxide is used in a variety of applications due to its high bandgap, high-K and high index of refraction. Unintentional impurities can change properties of tantalum oxide, and heavy ion elastic recoil detection is a method that can play a fundamental role in the quantification of those impurities. Furthermore, tantalum oxide is frequently part of the samples that also include other materials, which are often analysed with ion beam techniques. However, there are very few reported stopping power measurements for tantalum oxide, and data analysis relies not only on interpolation from a sparse data base but also on the Bragg rule. As is well known, the Bragg rule is often inaccurate for oxides, particularly when the difference in atomic numbers of the involved elements is very large as is case for Ta{sub 2}O{sub 5}. We have used a bulk method, previously developed by us and applied successfully to other systems, to determine experimentally the stopping power of tantalum oxide for three different ion types: C, O and Cl. In the present paper the results of our measurements and bulk method analysis are presented.

  5. 基于希尔伯特振动分解的低频振荡在线辨识%Online Identification for Low Frequency Oscillation Based on Hilbert Vibration Decomposition

    Institute of Scientific and Technical Information of China (English)

    孟洁; 李世明; 温伯坚

    2016-01-01

    On the basis of characteristic of Hilbert vibration decomposition (HVD)algorithm being suitable to deal with time-varying frequency signals,this paper proposes a kind of new algorithm combining with HVD for dealing with non-stationary oscillation signals named signal energy analysis method which is applied in online identification for low frequency oscillation of the power system. Firstly,it analyzes and filters analytic signals obtained from Hilbert conversion to get instantaneous frequency with the maximum component of amplitude as well as get relevant amplitude and initial phase by means of syn-chronous detection. Then,by iterative operation,it is able to detect out frequency,amplitude and phase of each component of non-stationary oscillation signals. Finally,the signal energy analysis method is used for identification and decomposition for the dominant oscillation mode of each stationary signal from HVD. This algorithm is compared with Prony algorithm and signal energy algorithm based on empirical mode decomposition (EMD),and results of simulating test and example anal-ysis indicate that this new algorithm is able to effectively extract the dominant mode of off-axis-symmetrical oscillation sig-nals which has strong noise proof ability and high computation efficiency.%利用希尔伯特振动分解(Hilbert vibration decomposition,HVD)算法适于处理时变频率信号的特性,提出一种处理非平稳振荡信号的新算法———结合 HVD 的信号能量分析法,并应用于电力系统低频振荡在线辨识中。首先,对通过 Hilbert变换获得的解析信号进行分析和滤波,得到幅值最大分量的瞬时频率,并由同步检测获得相应的幅值和初相位;然后,通过迭代运算检测出非平稳振荡信号各分量的频率、幅值、相位;最后,运用信号能量法对通过HVD得到的各平稳信号的主导振荡模式进行识别和分离。将该算法与Prony算法、基于经验模态分解(empirical mode

  6. Investigations of the Rg-BrCl (Rg = He, Ne, Ar, Kr, Xe) binary van der Waals complexes: ab initio intermolecular potential energy surfaces, vibrational states and predicted pure rotational transition frequencies

    Science.gov (United States)

    Li, Song; Zheng, Rui; Chen, Shan-Jun; Chen, Yan; Chen, Peng

    2017-03-01

    The intermolecular potential energy surfaces (PESs) of the ground electronic state for the Rg-BrCl (Rg = He, Ne, Ar, Kr, Xe) van der Waals complexes have been constructed by using the coupled-cluster method in combination with the augmented quadruple-zeta correlation-consistent basis sets supplemented with an additional set of bond functions. The features of the anisotropic PESs for these complexes are remarkably similar, which are characterized by three minima and two saddle points between them. The global minimum corresponds to a collinear Rg-Br-Cl configuration. Two local minima, correlate with an anti-linear Rg-Cl-Br geometry and a nearly T-shaped structure, can also be located on each PES. The quantum bound state calculations enable us to investigate intermolecular vibrational states and rotational energy levels of the complexes. The transition frequencies are predicted and are fitted to obtain their corresponding spectroscopic constants. In general, the periodic trends are observed for this complex family. Comparisons with available experimental data for the collinear isomer of Ar-BrCl demonstrate reliability of our theoretical predictions, and our results for the other two isomers of Ar-BrCl as well as for other members of the complex family are also anticipated to be trustable. Except for the collinear isomer of Ar-BrCl, the data presented in this paper would be beneficial to improve our knowledge for these experimentally unknown species.

  7. Investigations of the Rg-BrCl (Rg=He, Ne, Ar, Kr, Xe) binary van der Waals complexes: ab initio intermolecular potential energy surfaces, vibrational states and predicted pure rotational transition frequencies.

    Science.gov (United States)

    Li, Song; Zheng, Rui; Chen, Shan-Jun; Chen, Yan; Chen, Peng

    2017-03-05

    The intermolecular potential energy surfaces (PESs) of the ground electronic state for the Rg-BrCl (Rg=He, Ne, Ar, Kr, Xe) van der Waals complexes have been constructed by using the coupled-cluster method in combination with the augmented quadruple-zeta correlation-consistent basis sets supplemented with an additional set of bond functions. The features of the anisotropic PESs for these complexes are remarkably similar, which are characterized by three minima and two saddle points between them. The global minimum corresponds to a collinear Rg-Br-Cl configuration. Two local minima, correlate with an anti-linear Rg-Cl-Br geometry and a nearly T-shaped structure, can also be located on each PES. The quantum bound state calculations enable us to investigate intermolecular vibrational states and rotational energy levels of the complexes. The transition frequencies are predicted and are fitted to obtain their corresponding spectroscopic constants. In general, the periodic trends are observed for this complex family. Comparisons with available experimental data for the collinear isomer of Ar-BrCl demonstrate reliability of our theoretical predictions, and our results for the other two isomers of Ar-BrCl as well as for other members of the complex family are also anticipated to be trustable. Except for the collinear isomer of Ar-BrCl, the data presented in this paper would be beneficial to improve our knowledge for these experimentally unknown species.

  8. Monitoring Vibration of A Model of Rotating Machine

    Directory of Open Access Journals (Sweden)

    Arko Djajadi

    2012-03-01

    Full Text Available Mechanical movement or motion of a rotating machine normally causes additional vibration. A vibration sensing device must be added to constantly monitor vibration level of the system having a rotating machine, since the vibration frequency and amplitude cannot be measured quantitatively by only sight or touch. If the vibration signals from the machine have a lot of noise, there are possibilities that the rotating machine has defects that can lead to failure. In this experimental research project, a vibration structure is constructed in a scaled model to simulate vibration and to monitor system performance in term of vibration level in case of rotation with balanced and unbalanced condition. In this scaled model, the output signal of the vibration sensor is processed in a microcontroller and then transferred to a computer via a serial communication medium, and plotted on the screen with data plotter software developed using C language. The signal waveform of the vibration is displayed to allow further analysis of the vibration. Vibration level monitor can be set in the microcontroller to allow shutdown of the rotating machine in case of excessive vibration to protect the rotating machine from further damage. Experiment results show the agreement with theory that unbalance condition on a rotating machine can lead to larger vibration amplitude compared to balance condition. Adding and reducing the mass for balancing can be performed to obtain lower vibration level. 

  9. 一种多频局域共振型声子晶体板的低频带隙与减振特性∗%Low frequency band gaps and vibration reduction prop erties of a multi-frequency lo cally resonant phononic plate

    Institute of Scientific and Technical Information of China (English)

    吴健; 白晓春; 肖勇; 耿明昕; 郁殿龙; 温激鸿

    2016-01-01

    A multi-frequency locally resonant (LR) phononic plate is proposed in this paper. The phononic plate consists of periodic arrays of multiple double-cantilevered thin beams attached to a thin homogeneous plate. This proposed phononic plate is simplified and modeled using a plane wave expansion method to enable the calculation of flexural wave band structures. The band gap behavior of the phononic plate is analyzed comprehensively. In addition, an experimental specimen is fabricated using a square aluminum plate with a thickness of 0.9 mm and an area of 840 mm × 840 mm, and attached to the specimens as periodic arrays of two types of double-cantilevered thin beams made of the same material as the host plate. And the specimen is measured by using a scanning laser Doppler vibrometer to verify the theoretical predictions of band gaps. Investigations of this paper yield the following findings and conclusions. 1) Due to the interaction of low-frequency vibrational modes of attached multiple double-cantilevered beams and flexural vibration of the host plate, the proposed multi-frequency LR phononic plate can exhibit multiple low-frequency flexural wave band gaps (stop bands). It is also found that the band gaps of a multi-frequency LR phononic plate, especially those appearing in a lower frequency range, are generally narrower than that of a single-frequency LR phononic plate with the same type of double-cantilevered beams. 2) The frequency location of band gaps moves to higher frequency range when the thickness of the double-cantilevered beams is increased, or when the length of the double-cantilevered beams is decreased. It is also shown that a very small variation of the thickness (e.g., 0.1 mm) may lead to significant changes of frequency position of the band gaps. 3) When the width of the double-cantilevered beams is enlarged or the number of the double-cantilevered beams is increased, the lower band gap edge will move to a lower frequency range, while the upper band

  10. Magnetically levitated autoparametric broadband vibration energy harvesting

    Science.gov (United States)

    Kurmann, L.; Jia, Y.; Manoli, Y.; Woias, P.

    2016-11-01

    Some of the lingering challenges within the current paradigm of vibration energy harvesting (VEH) involve narrow operational frequency range and the inevitable non-resonant response from broadband noise excitations. Such VEHs are only suitable for limited applications with fixed sinusoidal vibration, and fail to capture a large spectrum of the real world vibration. Various arraying designs, frequency tuning schemes and nonlinear vibratory approaches have only yielded modest enhancements. To fundamentally address this, the paper proposes and explores the potentials in using highly nonlinear magnetic spring force to activate an autoparametric oscillator, in order to realize an inherently broadband resonant system. Analytical and numerical modelling illustrate that high spring nonlinearity derived from magnetic levitation helps to promote the 2:1 internal frequency matching required to activate parametric resonance. At the right internal parameters, the resulting system can intrinsically exhibit semi-resonant response regardless of the bandwidth of the input vibration, including broadband white noise excitation.

  11. Response of the seated human body to whole-body vertical vibration: discomfort caused by sinusoidal vibration.

    Science.gov (United States)

    Zhou, Zhen; Griffin, Michael J

    2014-01-01

    Frequency weightings for predicting vibration discomfort assume the same frequency-dependence at all magnitudes of vibration, whereas biodynamic studies show that the frequency-dependence of the human body depends on the magnitude of vibration. This study investigated how the frequency-dependence of vibration discomfort depends on the acceleration and the force at the subject-seat interface. Using magnitude estimation, 20 males and 20 females judged their discomfort caused by sinusoidal vertical acceleration at 13 frequencies (1-16 Hz) at magnitudes from 0.1 to 4.0 ms(-2) r.m.s. The frequency-dependence of their equivalent comfort contours depended on the magnitude of vibration, but was less dependent on the magnitude of dynamic force than the magnitude of acceleration, consistent with the biodynamic non-linearity of the body causing some of the magnitude-dependence of equivalent comfort contours. There were significant associations between the biodynamic responses and subjective responses at all frequencies in the range 1-16 Hz. Practitioner Summary: Vertical seat vibration causes discomfort in many forms of transport. This study provides the frequency-dependence of vibration discomfort over a range of vibration magnitudes and shows how the frequency weightings in the current standards can be improved.

  12. Integrated Passive and Active Vibration Control of Ultra-precision Lathe

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    In ultra-precision cutting process, vibration is one of the key factors affecting the machining quality. In this paper, the damping methods of HCM-I Ultra-precision Lathe are discussed in both complete machine and slide. It is pointed out that integrated passive and active vibration control (IPAVC) by combining passive vibration control (PVC) and active vibration control (AVC) can not only eliminate high frequency vibration but also improve the damping effect to low frequency vibration. Experiment results show the effectiveness of the integrated passive and active vibration control.

  13. Sound and vibration sensitivity of VIIIth nerve fibers in the grassfrog, Rana temporaria

    DEFF Research Database (Denmark)

    Christensen-Dalsgaard, J; Jørgensen, M B

    1996-01-01

    , the animals were stimulated with dorso-ventral vibrations, and the sound-induced vertical vibrations in the setup could be canceled by emitting vibrations in antiphase from the vibration exciter. All low-frequency fibers responded to both sound and vibration with sound thresholds from 23 dB SPL and vibration......We have studied the sound and vibration sensitivity of 164 amphibian papilla fibers in the VIIIth nerve of the grassfrog, Rana temporaria. The VIIIth nerve was exposed using a dorsal approach. The frogs were placed in a natural sitting posture and stimulated by free-field sound. Furthermore...... thresholds from 0.02 cm/s2. The sound and vibration sensitivity was compared for each fiber using the offset between the rate-level curves for sound and vibration stimulation as a measure of relative vibration sensitivity. When measured in this way relative vibration sensitivity decreases with frequency from...

  14. Analysis on Non-Resonance Standing Waves and Vibration Tracks of Strings

    Science.gov (United States)

    Fang, Tian-Shen

    2007-01-01

    This paper presents an experimental technique to observe the vibration tracks of string standing waves. From the vibration tracks, we can analyse the vibration directions of harmonic waves. For the harmonic wave vibrations of strings, when the driving frequency f[subscript s] = Nf[subscript n] (N = 1, 2, 3, 4,...), both resonance and non-resonance…

  15. Z-Damper: A New Paradigm for Attenuation of Vibrations

    Directory of Open Access Journals (Sweden)

    José Luis Pérez-Díaz

    2016-06-01

    Full Text Available Magnetic linear gear provides a new and unique opportunity for coupling mechanical impedances and optimizing vibration damping. In the present paper a new magneto-mechanical vibration damper (the so-called Z-damper is described. Its expected theoretical dynamic behavior shows a particularly high damping capability, a low frequency, as well as an optimal behavior for high frequencies.

  16. Vibrational spectra of corticosteroid hormones in the terahertz range

    Science.gov (United States)

    Cherkasova, O. P.; Nazarov, M. M.; Sapozhnikov, D. A.; Man'kova, A. A.; Fedulova, E. V.; Volodin, V. A.; Minaeva, V. A.; Minaev, B. F.; Baryshnikov, G. V.

    2010-11-01

    The terahertz time-domain and Raman spectra of corticosteroid hormones in the region of low-frequency infrared vibrations have been measured. On the ground of quantum chemical calculations of the frequencies and normal modes the assignments of vibrational bands in the THz-spectra are performed.

  17. Mechanical Vibrations Modeling and Measurement

    CERN Document Server

    Schmitz, Tony L

    2012-01-01

    Mechanical Vibrations:Modeling and Measurement describes essential concepts in vibration analysis of mechanical systems. It incorporates the required mathematics, experimental techniques, fundamentals of modal analysis, and beam theory into a unified framework that is written to be accessible to undergraduate students,researchers, and practicing engineers. To unify the various concepts, a single experimental platform is used throughout the text to provide experimental data and evaluation. Engineering drawings for the platform are included in an appendix. Additionally, MATLAB programming solutions are integrated into the content throughout the text. This book also: Discusses model development using frequency response function measurements Presents a clear connection between continuous beam models and finite degree of freedom models Includes MATLAB code to support numerical examples that are integrated into the text narrative Uses mathematics to support vibrations theory and emphasizes the practical significanc...

  18. Theory of vibration protection

    CERN Document Server

    Karnovsky, Igor A

    2016-01-01

    This text is an advancement of the theory of vibration protection of mechanical systems with lumped and distributed parameters. The book offers various concepts and methods of solving vibration protection problems, discusses the advantages and disadvantages of different methods, and the fields of their effective applications. Fundamental approaches of vibration protection, which are considered in this book, are the passive, parametric and optimal active vibration protection. The passive vibration protection is based on vibration isolation, vibration damping and dynamic absorbers. Parametric vibration protection theory is based on the Shchipanov-Luzin invariance principle. Optimal active vibration protection theory is based on the Pontryagin principle and the Krein moment method. The book also contains special topics such as suppression of vibrations at the source of their occurrence and the harmful influence of vibrations on humans. Numerous examples, which illustrate the theoretical ideas of each chapter, ar...

  19. [Study on Enhancing Characteristic Vibration of the Molecular Vibration Spectrum for BDE-15 Based on Solvent Effect].

    Science.gov (United States)

    Jiang, Long; Meng, Chong; Li, Yu

    2015-12-01

    In this paper, the molecular vibrational spectra (IR spectra and Raman spectra) of 4, 4'-dibrominated diphenyl ethers (BDE-15) in atmosphere and 24 kinds of solvents were calculated, at the B3LYP/6-31+G(d) level by density functional theory and self-consistent reaction field separately. Taking the spectra in atmosphere as benchmark, the spectra information of selected characteristic vibrations which were sensitive to the polarity of solvent were used to establish the solvent effect index system for BDE-15, evaluate the specific solvent effect on vibrational frequency, IR vibrational intensity, Raman vibrational intensity and comprehensive solvent effect of each solvent and search the organic solvent which significantly affected the frequency shift/intensity. From the view of molecular vibrational frequency, the characteristic vibrations sensitive to polarity of solvent (frequency shift > 1 cm⁻¹) are all correlated with stretching and out-surface bending vibrations, the solvent effect on the vibrational frequency of BDE-15 of 24 kinds of solvents are all insignificant, with the index values between 1.01-1.03, compared with standard index value 1 of atmosphere spectra. From the view of molecular vibrational intensity, 24 kinds of solvents have all strengthen the vibrational intensities of most of vibrations, locating at the high frequency region of Raman spectra and the middle/low frequency region of IR spectra. The solvents which enhance the vibrational intensities significantly (index value greater than 6 and 5 for IR and Raman intensity separately) include alcohols, acetonitrile, dimethyl sulfoxide, nitrobenzene, dimethyl sulfoxide. The solvent effect index values on Raman vibrational intensity of BDE-15 increase along with the dielectric constant of solvents from linear to logarithmic growth trend, while the solvent effect index values on IR vibrational intensity only leaving the linear relationship. The comprehensive solvent effect index values have presented

  20. Hybrid isolation of micro vibrations induced by reaction wheels

    Science.gov (United States)

    Lee, Dae-Oen; Park, Geeyong; Han, Jae-Hung

    2016-02-01

    As the technology for precision satellite payloads continues to advance, the requirements for the pointing stability of the satellites are becoming extremely high. In many situations, even small amplitude disturbances generated by the onboard components may cause serious degradation in the performance of high precision payloads. In such situations, vibration isolators can be installed to reduce the vibration transmission. In this work, a hybrid vibration isolator comprising passive and active components is proposed to provide an effective solution to the vibration problems caused by the reaction wheel disturbances. Firstly, mathematical modeling and experimental study of a single axis vibration isolator having high damping and high roll-off rate for the high frequency region and active components that enhance isolation performance for narrow frequency bands are presented. This concept is then extended to multi-axis by forming Stewart platform and the performance is experimentally verified. The tests on a flexible testbed show effective vibration isolation by the proposed vibration isolator.

  1. Vibrational Microspectroscopy for Cancer Screening

    Directory of Open Access Journals (Sweden)

    Fiona M. Lyng

    2015-02-01

    Full Text Available Vibrational spectroscopy analyses vibrations within a molecule and can be used to characterise a molecular structure. Raman spectroscopy is one of the vibrational spectroscopic techniques, in which incident radiation is used to induce vibrations in the molecules of a sample, and the scattered radiation may be used to characterise the sample in a rapid and non-destructive manner. Infrared (IR spectroscopy is a complementary vibrational spectroscopic technique based on the absorption of IR radiation by the sample. Molecules absorb specific frequencies of the incident light which are characteristic of their structure. IR and Raman spectroscopy are sensitive to subtle biochemical changes occurring at the molecular level allowing spectral variations corresponding to disease onset to be detected. Over the past 15 years, there have been numerous reports demonstrating the potential of IR and Raman spectroscopy together with multivariate statistical analysis techniques for the detection of a variety of cancers including, breast, lung, brain, colon, oral, oesophageal, prostate and cervical cancer. This paper discusses the recent advances and the future perspectives in relation to cancer screening applications, focussing on cervical and oral cancer.

  2. Statistical quality control through overall vibration analysis

    Science.gov (United States)

    Carnero, M. a. Carmen; González-Palma, Rafael; Almorza, David; Mayorga, Pedro; López-Escobar, Carlos

    2010-05-01

    The present study introduces the concept of statistical quality control in automotive wheel bearings manufacturing processes. Defects on products under analysis can have a direct influence on passengers' safety and comfort. At present, the use of vibration analysis on machine tools for quality control purposes is not very extensive in manufacturing facilities. Noise and vibration are common quality problems in bearings. These failure modes likely occur under certain operating conditions and do not require high vibration amplitudes but relate to certain vibration frequencies. The vibration frequencies are affected by the type of surface problems (chattering) of ball races that are generated through grinding processes. The purpose of this paper is to identify grinding process variables that affect the quality of bearings by using statistical principles in the field of machine tools. In addition, an evaluation of the quality results of the finished parts under different combinations of process variables is assessed. This paper intends to establish the foundations to predict the quality of the products through the analysis of self-induced vibrations during the contact between the grinding wheel and the parts. To achieve this goal, the overall self-induced vibration readings under different combinations of process variables are analysed using statistical tools. The analysis of data and design of experiments follows a classical approach, considering all potential interactions between variables. The analysis of data is conducted through analysis of variance (ANOVA) for data sets that meet normality and homoscedasticity criteria. This paper utilizes different statistical tools to support the conclusions such as chi squared, Shapiro-Wilks, symmetry, Kurtosis, Cochran, Hartlett, and Hartley and Krushal-Wallis. The analysis presented is the starting point to extend the use of predictive techniques (vibration analysis) for quality control. This paper demonstrates the existence

  3. Femtosecond nonlinear spectroscopy at surfaces: Second-harmonic probing of hole burning at the Si(111)7x7 surface and fourier-transform sum-frequency vibrational spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    McGuire, John Andrew [Univ. of California, Berkeley, CA (United States)

    2004-11-24

    The high temporal resolution and broad bandwidth of a femtosecond laser system are exploited in a pair of nonlinear optical studies of surfaces. The dephasing dynamics of resonances associated with the adatom dangling bonds of the Si(111)7 x 7 surface are explored by transient second-harmonic hole burning, a process that can be described as a fourth-order nonlinear optical process. Spectral holes produced by a 100 fs pump pulse at about 800 nm are probed by the second harmonic signal of a 100 fs pulse tunable around 800 nm. The measured spectral holes yield homogeneous dephasing times of a few tens of femtoseconds. Fits with a Lorentzian spectral hole centered at zero probe detuning show a linear dependence of the hole width on pump fluence, which suggests that charge carrier-carrier scattering dominates the dephasing dynamics at the measured excitation densities. Extrapolation of the deduced homogeneous dephasing times to zero excitation density yields an intrinsic dephasing time of {approx} 70 fs. The presence of a secondary spectral hole indicates that scattering of the surface electrons with surface optical phonons at 570 cm-1 occurs within the first 200 fs after excitation. The broad bandwidth of femtosecond IR pulses is used to perform IR-visible sum frequency vibrational spectroscopy. By implementing a Fourier-transform technique, we demonstrate the ability to obtain sub-laser-bandwidth spectral resolution. FT-SFG yields a greater signal when implemented with a stretched visible pulse than with a femtosecond visible pulse. However, when compared with multichannel spectroscopy using a femtosecond IR pulse but a narrowband visible pulse, Fourier-transform SFG is found to have an inferior signal-to-noise ratio. A mathematical analysis of the signal-to-noise ratio illustrates the constraints on the Fourier-transform approach.

  4. Bifurcation and Chaos on Frequencies the Excited Forces in Nonlinear Vibration Mechanism with Piece-Wise Linearity%分段线性振动机械关于外激振频率的分岔与混沌

    Institute of Scientific and Technical Information of China (English)

    文成秀; 赵长宽; 闻邦椿

    2001-01-01

    The characteristics of motion in nonlinear vibration mechanismwith piece-wise linearity were analyzed by means of computer simulation and Poincare method. Bifurcation of periodic motions and chaos in the system were studied when the angular frequencies increase from change 30rad/s to 100rad/s by steps 0.1rad/s. There are sudden changes from P-1 to P-3,inverse bifurcation from P-2 to P-1 and sudden change from P-3 to P-1 except that double-periodic bifurcation exist. The global and part bifurcation figure and Poincare mapping figure of chaos and the time-history curves of 3 periodic motions were given.%利用计算机仿真及Poincare映射方法研究不对称分段线性非线性机械系统的运动学特征.研究了外激振力角频率从30rad/s以步长0.1rad/s增加到100rad/s时,系统的周期运动分岔和混沌运动.发现其中除了存在倍周期分岔外,还存在P-1到P-3的突变、P-2到P-1的倒分岔和P-3到P-1的突变.给出了全局分岔图、局部分岔图、混沌运动的Poincare映射及3种周期运动的时间历程曲线和相平面图.对于设计此类机械系统具有指导意义.

  5. Effects of ramp vibrational states on flexural intrinsic vibrations in Besocke-style scanners

    Institute of Scientific and Technical Information of China (English)

    Zhang Hui; Jiang Guo-Zhu; Liu Zhao-Qun; Zhang Shu-Yi; Fan Li

    2013-01-01

    For both the vibrating and steady supporting surfaces of a scanning disk in a Besocke-style piezoelectric scanner,a theoretical model is given by considering the nonlinear lateral friction at the micro-contact interface between the positioning legs and the supporting surface.Numerical simulations demonstrate that unexpected flexural vibrations can arise from a vibrating ramp,and their frequencies are lower than the eigenfrequencies of the scanner in the linearly elastic regime.The vibrations essentially depend on 1) the vibrational states of the supporting ramp and the steel ball tips on the three piezoelectric positioning legs,and 2) the tribological characteristics of the contacts between the tips and the ramp.The results give an insight into the intrinsic vibrations of the scanners,and are applicable in designing and optimizing piezoelectric scanning systems.

  6. Vibrations in Magnet/Superconductor Levitation Systems

    Institute of Scientific and Technical Information of China (English)

    F. Y. Alzoubi; H. M. Al-khateeb; M. K. Alqadi; N. Y. Ayoub

    2006-01-01

    The problem of a small magnet levitating above a very thin superconducting disc in the Meissner state is analysed. The dipole-dipole interaction model is employed to derive analytical expressions for the interaction energy, levitation force, magnetic stiffness and frequency of small vibrations about the equilibrium position in two different configurations, i.e. with the magnetic moment parallel and perpendicular to the superconductor. The results show that the frequency of small vibrations decreases with the increasing levitation height for a particular radius of the superconducting disc, which is in good agreement with the experimental results. However, the frequency increases monotomcally up to saturation by increasing the radius of the disc for a particular height of the magnet. In addition, the frequency of vibrations is higher when the system is in the vertical configuration than that when the system is in the horizontal configuration.

  7. Analysis of vibration reduction level in an 8/6 switched reluctance machine by active vibration cancellation

    Institute of Scientific and Technical Information of China (English)

    Xu LIU; Zai-ping PAN; Z.Q. ZHU

    2010-01-01

    This paper proposes an analytical model for predicting the maximum vibration reduction level in a four-phase 8/6switched reluctance machine(SRM)by employing active vibration cancellation(AVC),one of the most effective and convenient methods for reducing the vibration and acoustic noise produced by SRMs.Based on the proposed method,the factors that influence the vibration reduction level are analyzed in detail.The relationships between vibration and noise reduction levels at resonance frequency and rotor speed are presented.Moreover,it is shown that a large damping factor will lead to smaller vibration reduction level with AVC while,in contrast,a large resonance frequency will increase the vibration reduction level.Both finite element analyses and experiments were carried out on a prototype 8/6 SRM to validate the proposed method.

  8. Multidimensional Time-Resolved Spectroscopy of Vibrational Coherence in Biopolyenes

    Science.gov (United States)

    Buckup, Tiago; Motzkus, Marcus

    2014-04-01

    Multidimensional femtosecond time-resolved vibrational coherence spectroscopy allows one to investigate the evolution of vibrational coherence in electronic excited states. Methods such as pump-degenerate four-wave mixing and pump-impulsive vibrational spectroscopy combine an initial ultrashort laser pulse with a nonlinear probing sequence