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Sample records for bulk formed micro

  1. Production Equipment and Processes for Bulk Formed Micro Components

    Science.gov (United States)

    Paldan, N. A.; Arentoft, M.; Eriksen, R. S.

    2007-04-01

    Manufacturing techniques for production of small precise metallic parts has gained interest during recent years, an interest led by an industrial demand for components for integrated products like mobile phones, personal digital assistants (PDAs), mp3-players and in the future for spare parts for the human body. Micro components have also found several applications within the medical, audiological and dental industry, applications that impose increased demands for biocompatible and corrosion-resistant materials and cleanness. So far these micro components have mainly been manufactured by traditional machining techniques or chemical etching. However, these traditional machining and etching techniques are generally not well suited for mass production of advanced micro components, due to handling problems, waste of expensive material and long machining times. This calls for development of a novel production system that can meet the demands for high productivity, high reliability, low cost, while being environmental acceptable. Bulk metal forming meets these demands to a great extent, but the technology cannot directly be transferred to the micro scale. A flexible machine system for bulk micro forming has been developed and used to form a number of industrial micro parts in aluminium and silver, with ongoing work on forming of titanium. Manufacture of billets by cropping has been examined using a simple test rig and an automatic cropping device has been designed, manufactured and tested.

  2. Towards the first generation micro bulk forming system

    DEFF Research Database (Denmark)

    Arentoft, Mogens; Eriksen, Rasmus Solmer; Hansen, Hans Nørgaard;

    2011-01-01

    work describes a number of prototype system units, which collectively form a desktop sized micro forming production system. The system includes a billet preparation module, an integrated transfer system, a temperature controlled forming tool, including process simulation, and a dedicated micro forming...

  3. Bulk forming of industrial micro components in conventional metals and bulk metallic glasses

    DEFF Research Database (Denmark)

    Arentoft, Mogens; Paldan, Nikolas Aulin; Eriksen, Rasmus Solmer; Gastaldi, T.; Wert, John A.; Eldrup, Morten Mostgaard

    2007-01-01

    glasses will at elevated temperatures behave like a highly viscous liquid, which can easily form even complicated geometries in 1 step. The strengths and limitations of forming the 2 materials are analyzed for a micro 3D component in a silver alloy and an Mg-Cu-Y BMG. ©2007 American Institute of Physics......For production of micro components in large numbers, forging is an interesting and challenging process. The conventional metals like silver, steel and aluminum often require multi-step processes, but high productivity and increased strength justify the investment. As an alternative, bulk metallic...

  4. Production Equipment and Processes for Bulk Formed Micro Components

    DEFF Research Database (Denmark)

    Paldan, Nikolas Aulin; Arentoft, Mogens; Eriksen, Rasmus Solmer

    2007-01-01

    traditional machining techniques or chemical etching. However, these traditional machining and etching techniques are generally not well suited for mass production of advanced micro components, due to handling problems, waste of expensive material and long machining times. This calls for development of a...... micro forming has been developed and used to form a number of industrial micro parts in aluminium and silver, with ongoing work on forming of titanium. Manufacture of billets by cropping has been examined using a simple test rig and an automatic cropping device has been designed, manufactured and tested....... the human body. Micro components have also found several applications within the medical, audiological and dental industry, applications that impose increased demands for biocompatible and corrosion-resistant materials and cleanness. So far these micro components have mainly been manufactured by...

  5. Precision analysis in billet preparation for micro bulk metal forming

    DEFF Research Database (Denmark)

    Mahshid, Rasoul; Hansen, Hans N.

    2015-01-01

    press. When using a vertical mechanical press, the material is fed as billets into the forming zone. Therefore, a large number of highly uniform billets are required to run mass production in such a setup. Shearing technique was used for manufacturing the billets. The efficiency of the shearing tool is......The purpose of this research is to fabricate billets for an automated transfer press for micro forming. High performance transfer presses are wellknown in conventional metal forming and distinguished from their automation and mass production. The press used in this research is a vertical mechanical...

  6. Bulk forming of industrial micro components in conventional metals and bulk metallic glasses

    DEFF Research Database (Denmark)

    Arentoft, Mogens; Paldan, Nikolas Aulin; Eriksen, Rasmus Solmer;

    2007-01-01

    For production of micro components in large numbers, forging is an interesting and challenging process. The conventional metals like silver, steel and aluminum often require multi-step processes, but high productivity and increased strength justify the investment. As an alternative, bulk metallic...

  7. Production Equipment and Processes for Bulk Formed Micro Components

    DEFF Research Database (Denmark)

    Paldan, Nikolas Aulin; Arentoft, Mogens; Eriksen, Rasmus Solmer

    2007-01-01

    Manufacturing techniques for production of small precise metallic parts has gained interest during recent years, an interest led by an industrial demand for components for integrated products like mobile phones, personal digital assistants (PDAs), mp3-players and in the future for spare parts for...... the human body. Micro components have also found several applications within the medical, audiological and dental industry, applications that impose increased demands for biocompatible and corrosion-resistant materials and cleanness. So far these micro components have mainly been manufactured by...

  8. Towards Mass Production by High Performance Transfer Press in Micro Bulk Forming

    DEFF Research Database (Denmark)

    Mahshid, Rasoul; Hansen, Hans Nørgaard; Arentoft, Mogens

    Multi-step micro bulk forming is characterized by complex processes and high precision requirements. Several process parameters influence on accuracy of micro forged parts where small tolerances in the order of few μm are in demand. The paper introduces a high performance transfer press for micro...... cold bulk forming. A methodology for selection of linear motors on the bases of the process parameters was obtained. In order to examine the effectiveness of the machine, specific geometry was investigated for production. Kinematic parameters were found for a production rate of 200 strokes per minute...

  9. A New Approach for Handling of Micro Parts in Bulk Metal Forming

    DEFF Research Database (Denmark)

    Mahshid, Rasoul; Hansen, Hans Nørgaard; Arentoft, M.

    2012-01-01

    During last 10 years a lot of research has been done in micro forming processes. In spite of the challenges micro forming has in process, material properties, tooling technology and machines, micro forming technology yields remarkable accuracy and good mechanical properties with high rate of...... production [1]. This can fulfill the demands for mass production and miniaturization in industries and academic communities. According to the recent studies, topics related to materials, process and simulation have been investigated intensively and well documented. Machines, forming tools and handling...... systems are critical elements to complete micro forming technology for transferring knowledge to industries and toward miniature manufacturing systems (micro factory) [2]. Since most metal forming processes are multi stage, making a new handling system with high reliability on accuracy and speed is...

  10. Micro metal forming

    CERN Document Server

    2013-01-01

    Micro Metal Forming, i. e. forming of parts and features with dimensions below 1 mm, is a young area of research in the wide field of metal forming technologies, expanding the limits for applying metal forming towards micro technology. The essential challenges arise from the reduced geometrical size and the increased lot size. In order to enable potential users to apply micro metal forming in production, information about the following topics are given: tribological behavior: friction between tool and work piece as well as tool wear mechanical behavior: strength and formability of the work piece material, durability of the work pieces size effects: basic description of effects occurring due to the fact, that the quantitative relation between different features changes with decreasing size process windows and limits for forming processes tool making methods numerical modeling of processes and process chains quality assurance and metrology All topics are discussed with respect to the questions relevant to micro...

  11. Micro benchtop optics by bulk silicon micromachining

    Science.gov (United States)

    Lee, Abraham P.; Pocha, Michael D.; McConaghy, Charles F.; Deri, Robert J.

    2000-01-01

    Micromachining of bulk silicon utilizing the parallel etching characteristics of bulk silicon and integrating the parallel etch planes of silicon with silicon wafer bonding and impurity doping, enables the fabrication of on-chip optics with in situ aligned etched grooves for optical fibers, micro-lenses, photodiodes, and laser diodes. Other optical components that can be microfabricated and integrated include semi-transparent beam splitters, micro-optical scanners, pinholes, optical gratings, micro-optical filters, etc. Micromachining of bulk silicon utilizing the parallel etching characteristics thereof can be utilized to develop miniaturization of bio-instrumentation such as wavelength monitoring by fluorescence spectrometers, and other miniaturized optical systems such as Fabry-Perot interferometry for filtering of wavelengths, tunable cavity lasers, micro-holography modules, and wavelength splitters for optical communication systems.

  12. Influence of the micro-addition of Mo on glass forming ability and corrosion resistance of Cu-based bulk metallic glasses

    International Nuclear Information System (INIS)

    (Cu47Zr11Ti34Ni8)100-xMo x bulk metallic glasses (BMGs) with x = 0, 1 and 2 at.% and a bulk metallic glass matrix composite with x = 5 at.% were successfully prepared by water-cooled copper mold casting. The effect of the addition of a small amount of Mo on the glass forming ability (GFA), thermal properties of the base alloy (i.e. x = 0) were investigated by X-ray diffraction (XRD), differential scanning calorimetry (DSC) and differential thermal analyzer (DTA). It is found that the addition of appropriate amount of Mo can enhance the GFA of the Cu-based BMG, as indicated by the increase in the reduced glass transition temperature T rg (=T g/T l) and the parameter γ (=T x/(T g + T l)) with the increase of Mo. On the other hand, the corrosion resistance of the Cu-based BMGs with different Mo contents was examined by electrochemical polarization and weight loss measurement in 1 mol/L H2SO4 and 1 mol/L NaOH solutions, respectively. It is found that the corrosion resistance of Cu-based BMGs increased with increasing Mo content with the lowest corrosion rate of (0.9 ± 0.2) x 10-3 mm/year in 1 mol/L H2SO4 solution and (0.3 ± 0.1) x 10-3 mm/year in 1 mol/L NaOH solution, respectively, for the BMG containing 2 at.% Mo. X-ray photoelectron spectroscopy (XPS) results revealed that the improvement of corrosion resistance of Cu-based BMG containing appropriate amount of Mo originated from the enrichment of ZrO2 and TiO2, but depletion in Cu- or Ni-oxides in the passive films formed during electrochemical polarization. Finally, the galvanostatic-step measurement was performed to investigate the kinetics of the formation of passive films on the BMG surfaces. It is demonstrated that the addition of an appropriate amount of Mo can effectively improve the stability and uniformity of the passive film. The role of Mo addition on the glass forming ability and corrosion behavior is discussed

  13. Forming of bulk metallic glass microcomponents

    DEFF Research Database (Denmark)

    Wert, John A.; Thomsen, Christian; Jensen, Rune Debel;

    2009-01-01

    The present article considers forward extrusion, closed-die forging and backward extrusion processes for fabrication of individual microcomponents from two bulk metallic glass (BMG) compositions: Mg60Cu30Y10 and Zr44Cu40Ag8Al8. Two types of tooling were used in the present work: relatively massive...... die sets characteristic of cold forming operations for crystalline metals and lightweight die sets adapted to the special characteristics of BMGs. In addition to demonstrating that microcomponents of several geometries can be readily fabricated from BMGs, rheological properties are combined with...

  14. Advanced and new developments in bulk metal forming

    DEFF Research Database (Denmark)

    Bay, Niels; Wanheim, Tarras; Ravn, Bjarne Gottlieb; Arentoft, Mogens

    Increasing demands to manufacturing industry of faster, better and cheaper production has intensified the research and development of bulk metal forming. The present paper gives examples on European industrial research on secondary bulk metal forming processes. The R&D follows three lines of appr...

  15. Laser based micro forming and assembly.

    Energy Technology Data Exchange (ETDEWEB)

    MacCallum, Danny O' Neill; Wong, Chung-Nin Channy; Knorovsky, Gerald Albert; Steyskal, Michele D.; Lehecka, Tom (Pennsylvania State University, Freeport, PA); Scherzinger, William Mark; Palmer, Jeremy Andrew

    2006-11-01

    It has been shown that thermal energy imparted to a metallic substrate by laser heating induces a transient temperature gradient through the thickness of the sample. In favorable conditions of laser fluence and absorptivity, the resulting inhomogeneous thermal strain leads to a measurable permanent deflection. This project established parameters for laser micro forming of thin materials that are relevant to MESA generation weapon system components and confirmed methods for producing micrometer displacements with repeatable bend direction and magnitude. Precise micro forming vectors were realized through computational finite element analysis (FEA) of laser-induced transient heating that indicated the optimal combination of laser heat input relative to the material being heated and its thermal mass. Precise laser micro forming was demonstrated in two practical manufacturing operations of importance to the DOE complex: micrometer gap adjustments of precious metal alloy contacts and forming of meso scale cones.

  16. Forming of Polymeric Tubular Micro-components

    DEFF Research Database (Denmark)

    Qin, Yi; Zhao, Jie; Anyasodor, Gerald; Schütt Hansen, Klaus; Calderon, Ivan; Konrad, Konstantin; Hartl, Christoph; Arentoft, Mogens; Chronakis, Ioannis S.

    2015-01-01

    This chapter is intended to provide an overview of three nontraditional shaping technologies for the forming of polymeric micro-tubes, which are hot embossing, blow molding, and cross rolling, as well as realization of a process chain and the integration of a modular machine-based manufacturing p...

  17. Micro and bulk analysis of prostate tissues classified as hyperplasia

    Science.gov (United States)

    Kwiatek, W. M.; Banaś, A.; Banaś, K.; Cinque, G.; Dyduch, G.; Falkenberg, G.; Kisiel, A.; Marcelli, A.; Podgórczyk, M.

    2007-07-01

    BPH (Benign Prostatic Hyperplasia) is the most common benign neoplasm (non cancerous enlargement of the prostate gland), whose prevalence increases with age. The gland, when increased in size, exerts pressure on the urethra, causing obstruction to urine flow. The latter may result in severe urinary tract and kidney conditions. In this work prostate samples from patients diagnosed with BPH were analyzed using synchrotron radiation. Micro-analysis of the hyperplastic samples was carried out on the L-beam line at HASYLAB, DESY (Germany), while bulk analysis on selected samples was performed at the DRX2 beamline at LNF, Frascati (Italy). Microanalysis with a mono-energetic beam 15 μm in diameter confirmed that concentrations of certain elements, such as S, Mn, Cu, Fe and Zn, are good indicators of pathological disorders in prostate tissue that may be considered effective tracers of developing compliant. The concentrations of Mn, Cu, Fe and Zn are higher in hyperplastic tissues, as compared to normal ones, while for sulphur the opposite is observed. Additionally, Fe and S K-edge XANES (X-ray Absorption Near Edge Structure) spectroscopy experiments were carried out in order to determine the chemical speciation of these elements in our samples.

  18. Ductile damage prediction in sheet and bulk metal forming

    Science.gov (United States)

    Badreddine, Houssem; Labergère, Carl; Saanouni, Khemais

    2016-04-01

    This paper is dedicated to the presentation of an advanced 3D numerical methodology for virtual sheet and/or bulk metal forming simulation to predict the anisotropic ductile defects occurrence. First, the detailed formulation of thermodynamically-consistent fully coupled and fully anisotropic constitutive equations is given. The proposed constitutive equations account for the main material nonlinearities as the anisotropic plastic flow, the mixed isotropic and kinematic hardening and the anisotropic ductile damage under large inelastic strains. Second, the related numerical aspects required to solve the initial and boundary value problem (IBVP) are very briefly presented in the framework of the 3D finite element method. The global resolution schemes as well as the local integration schemes of the fully coupled constitutive equations are briefly discussed. Finally, some typical examples of sheet and bulk metal forming processes are numerically simulated using the proposed numerical methodology.

  19. SPECTROPHOTOMETRIC ESTIMATION OF GEMFIBROZIL IN BULK AND PHARMACEUTICAL DOSAGE FORMS

    Directory of Open Access Journals (Sweden)

    Parikh Vikas C.

    2011-06-01

    Full Text Available A simple, sensitive and accurate UV spectrophotometric method has been developed for the determination of Gemfibrozil in bulk and pharmaceutical tablet dosage formulation. This method obeys Beer’s law in the concentration range of 30-90 µg/ml. with correlation coefficient of 0.9993 and exhibiting maximum absorption at 276 nm with apparent molar absorptivity of 0.1703 × 104 L mole-1 cm-1. The method is accurate and precise and is extended to pharmaceutical tablet dosage forms and there was no interference from any common pharmaceutical additives and excipients. The results of analysis were validated statistically and by recovery studies.

  20. SPECTROPHOTOMETRIC ESTIMATION OF GEMFIBROZIL IN BULK AND PHARMACEUTICAL DOSAGE FORMS

    OpenAIRE

    Parikh Vikas C.; Karkhanis V.V

    2011-01-01

    A simple, sensitive and accurate UV spectrophotometric method has been developed for the determination of Gemfibrozil in bulk and pharmaceutical tablet dosage formulation. This method obeys Beer’s law in the concentration range of 30-90 µg/ml. with correlation coefficient of 0.9993 and exhibiting maximum absorption at 276 nm with apparent molar absorptivity of 0.1703 × 104 L mole-1 cm-1. The method is accurate and precise and is extended to pharmaceutical tablet dosage forms and there was no ...

  1. Sheet-bulk metal formingforming of functional components from sheet metals

    Directory of Open Access Journals (Sweden)

    Merklein Marion

    2015-01-01

    Full Text Available The paper gives an overview on the application of sheet-bulk metal forming operations in both scientific and industrial environment. Beginning with the need for an innovative forming technology, the definition of this new process class is introduced. The rising challenges of the application of bulk metal forming operations on sheet metals are presented and the demand on a holistic investigation of this topic is motivated. With the help of examples from established production processes, the latest state of technology and the lack on fundamental knowledge is shown. Furthermore, perspectives regarding new research topics within sheet-bulk metal forming are presented. These focus on processing strategies to improve the quality of functional components by the application of process-adapted semi-finished products as well as the local adaption of the tribological system.

  2. Spectrophotometric determination of nateglinide in bulk and tablet dosage forms

    Directory of Open Access Journals (Sweden)

    Jain Suresh

    2009-01-01

    Full Text Available Nateglinide (NTG is available as tablet dosage form in 60 mg and 120 mg strength. In the present study, two simple, reproducible and efficient UV spectrophotometric methods for the estimation of this drug in bulk and pharmaceutical dosage forms have been developed. In method I, methanol-AR was used as solvent, while in method II, Methanol-AR + 10% V/V 3N NaOH was used as reference solvent. In method I, nateglinide shows λmax at 216 nm, which is then shifted to 225.4 nm on increasing the basicity of the reference solvent in method II. The linearity for nateglinide was observed to be statistically in the range of 10-100 μg/ml in method I and 100-1000 μg/ml in method II. Both the methods were validated using ANOVA. The recovery studies confirmed the accuracy of the proposed methods.

  3. Exploring the bulk of tidal charged micro-black holes

    International Nuclear Information System (INIS)

    We study the bulk corresponding to tidal charged brane-world black holes. We employ a propagating algorithm which makes use of the three-dimensional multipole expansion and analytically yields the metric elements as functions of the five-dimensional coordinates and of the Adler-Deser-Misner mass, tidal charge, and brane tension. Since the projected brane equations cannot determine how the charge depends on the mass, our main purpose is to select the combinations of these parameters for which black holes of microscopic size possess a regular bulk. Our results could, in particular, be relevant for a better understanding of TeV-scale black holes.

  4. Micro-optical structures formed by a mask moving method

    Institute of Scientific and Technical Information of China (English)

    DU Chun-lei; DONG Xiao-chun; DENG Qi-ling; LUO Xian-gang

    2007-01-01

    An unique mask moving method is developed for forming effective micro-optical structures with continuous profile. The mechanism for forming different micro-optical profiles is disclosed, and the designed approach for binary moving mask is described. Finally some concrete micro-optical components with typical microstructures are presented for demonstrating the validity of the method.

  5. Micro-beam and pulsed laser beam techniques for the micro-fabrication of diamond surface and bulk structures

    International Nuclear Information System (INIS)

    Micro-fabrication in diamond is applicable in a wide set of emerging technologies, exploiting the exceptional characteristics of diamond for application in bio-physics, photonics and radiation detection. Micro ion-beam irradiation and pulsed laser irradiation are complementary techniques, which permit the implementation of complex geometries, by modification and functionalization of surface and/or bulk material, modifying the optical, electrical and mechanical characteristics of the material. In this article we summarize the work done in Florence (Italy), concerning ion beam and pulsed laser beam micro-fabrication in diamond

  6. Advanced free-form micro tooling

    DEFF Research Database (Denmark)

    Tosello, Guido; Gavillet, J.

    2011-01-01

    -beam lithography and nano imprinting lithography [Che05][Che09] have high manufacturing cost and a low throughput. The aim was obtain large tool area with nano structures patterning without using energy intensive nano machining (e.g. focus ion beam, X-ray lithography, etc) but, instead, by exploiting the advantage......The present deliverable contains the report of the work and results achieved within the framework of WP 2.2 in Tasks 2.2.4 “Advanced free-form micro tooling” in experimental research done regarding practical applications of methods of applying nano structures to tooling solutions. As part of Task 2.......2.4, tests based on three different chemical-based-batch techniques to establish surface nano (i.e. sub-μm) structures on large tools area were performed. The three approached regarded: o Scheme 1  The use of Ø500nm nanobeads deposition for direct patterning of a Ø4inch. silicon wafer and subsequent nickel...

  7. An all-silicon single-wafer micro-g accelerometer with a combined surface and bulk micromachining process

    Science.gov (United States)

    Yazdi, N.; Najafi, K.

    2000-01-01

    This paper reports an all-silicon fully symmetrical z-axis micro-g accelerometer that is fabricated on a single-silicon wafer using a combined surface and bulk fabrication process. The microaccelerometer has high device sensitivity, low noise, and low/controllable damping that are the key factors for attaining micro g and sub-micro g resolution in capacitive accelerometers. The microfabrication process produces a large proof mass by using the whole wafer thickness and a large sense capacitance by utilizing a thin sacrificial layer. The sense/feedback electrodes are formed by a deposited 2-3 microns polysilicon film with embedded 25-35 microns-thick vertical stiffeners. These electrodes, while thin, are made very stiff by the thick embedded stiffeners so that force rebalancing of the proof mass becomes possible. The polysilicon electrodes are patterned to create damping holes. The microaccelerometers are batch-fabricated, packaged, and tested successfully. A device with a 2-mm x 1-mm proof mass and a full bridge support has a measured sensitivity of 2 pF/g. The measured sensitivity of a 4-mm x 1-mm accelerometer with a cantilever support is 19.4 pF/g. The calculated noise floor of these devices at atmosphere are 0.23 micro g/sqrt(Hz) and 0.16 micro g/sqrt(Hz), respectively.

  8. Micro-lateral extrusion of Zr55Cu30Al10Ni5 bulk metallic glass under low-frequency vibration loading

    Directory of Open Access Journals (Sweden)

    Li Jinyang

    2015-01-01

    Full Text Available The effect of vibration on the micro-forming ability of Zr55Cu30Al10Ni5 bulk metallic glass in its supercooled liquid region was studied. The experiment of micro-extrusion was carried out under different amplitude (38 ∼ 760 N and different frequency (0.1 ∼ 2.0 Hz at a fixed temperature of 723 K. The extrusion length was taken as a measure to characterize the micro-forming ability. Results reveal that the extrusion length of bulk metallic glass is effectively improved under vibration loading, and increases with increasing loading frequency and amplitude, whereas the frequency dependence is stronger. The viscosity of bulk metallic glass declines under vibration loading because of a larger free volume concentration and surface effect caused by vibration. This research indicates that the vibration forming is an effective method to enhance the micro-forming ability of bulk metallic glasses.

  9. Replication of micro/nano-scale features by micro injection molding with a bulk metallic glass mold insert

    International Nuclear Information System (INIS)

    The development of MEMS and microsystems needs a reliable mass production process to fabricate micro components with micro/nano-scale features. In our study, we used the micro injection molding process to replicate micro/nano-scale channels and ridges from a bulk metallic glass (BMG) cavity insert. High-density polyethylene was used as the molding material and the design of experiment approach was adopted to systematically and statistically investigate the relationship between machine parameters, real process conditions and replication quality. The peak cavity pressure and temperature were selected as process characteristic values to describe the real process conditions that the material experienced during the filling process. The experiments revealed that the replication of ridges, including feature edge, profile and filling height, was sensitive to the flow direction; cavity pressure and temperature both increased with holding pressure and mold temperature; replication quality can be improved by increasing cavity pressure and temperature within a certain range. The replication quality of micro/nano features is tightly related to the thermomechanical history of material experienced during the molding process. In addition, the longevity and roughness of the BMG insert were also evaluated based on the number of injection molding cycles. (paper)

  10. Design and Application of Quadrature Compensation Patterns in Bulk Silicon Micro-Gyroscopes

    OpenAIRE

    Yunfang Ni; Hongsheng Li; Libin Huang

    2014-01-01

    This paper focuses on the detailed design issues of a peculiar quadrature reduction method named system stiffness matrix diagonalization, whose key technology is the design and application of quadrature compensation patterns. For bulk silicon micro-gyroscopes, a complete design and application case was presented. The compensation principle was described first. In the mechanical design, four types of basic structure units were presented to obtain the basic compensation function. A novel layout...

  11. Micro-forming of Al-Si foil

    Directory of Open Access Journals (Sweden)

    T. Haga

    2010-06-01

    Full Text Available Purpose: of this paper is as below. The investigation of the ability of the cold micro-forming of non-metallic glass was purpose. The grain of the rapidly solidified aluminium alloy became fine. The aluminium alloy foil with fine grain was used, and the investigation of the micro-formability of this alloy was investigated. Moreover, increase of the forming speed was investigated. The increase of the forming speed was purpose of this study, too.Design/methodology/approach: The nozzle pressing melt spinning method was used to attain the rapid solidification of the non-metallic grass. The Al-14mass%Si, which is hyper eutectic but is close to eutectic, was used. The roll contact surface was formed by V-groove. The cold rolling was adopted for forming. The V-groove was machined at the roll surface. The micro-forming was operated at the cold work. Findings: Micro-forming of the crystal aluminium alloy was able by the cold work. The forming speed was 0.04S to form 10 μm height. The forming speed could be drastically increased. Research limitations/implications: The angle of the V-groove, which was used in the present study, was only 60 degrees. The effect of the groove angle on the protrusion-height was not clear. The used material was only the Al-14mass%Si. Relationship between the material and protrusion-height was not clear.Practical implications: The die for the micro-forming of the resin could be made from economy material by the conventional cold rolling process at short time. Therefore, the mass production of the economy die for resin may be obtained.Originality/value: The micro-forming of the rapidly solidified non-metallic glass by cold work was original.

  12. Nickel silicide thin films as masking and structural layers for silicon bulk micro-machining by potassium hydroxide wet etching

    International Nuclear Information System (INIS)

    This paper studies the feasibility of using titanium and nickel silicide thin films as mask materials for silicon bulk micro-machining. Thin films of nickel silicide were found to be more resistant to wet etching in potassium hydroxide. The use of nickel silicide as a structural material, by fabricating micro-beams of varying dimensions, is demonstrated. The micro-structures were realized using these thin films with wet etching using potassium hydroxide solution on (1 0 0) and (1 1 0) silicon substrates. These results show that nickel silicide is a suitable alternative to silicon nitride for silicon bulk micro-machining

  13. Spectrophotometric estimation of famciclovir in bulk and tablet dosage form

    Directory of Open Access Journals (Sweden)

    Nizamuddin S

    2007-01-01

    Full Text Available Two, simple, accurate, rapid and sensitive methods have been developed for the estimation of famciclovir in tablet dosage forms. Method A is based on the nucleophillic substitution product with Folin′s reagent to form colored chromogen exhibiting absorption maximum at 454 nm with apparent molar absorptivity of 3.99x10 4 l/mol.cm and obeyed Beer′s law in the concentration range of 2-10 µg/ml. Method B is based on diazotisation and coupling reaction with resorcinol to form colored chromogen exhibiting absorbance maximum at 386 nm with apparent molar absorptivity of 3.15x10 4 l/mol.cm and obeyed Beer′s law in the concentration range of 7-21 µg/ml.

  14. Micro-forming of Al-Si foil

    OpenAIRE

    T. Haga; Inoue, K.; H. Watari

    2010-01-01

    Purpose: of this paper is as below. The investigation of the ability of the cold micro-forming of non-metallic glass was purpose. The grain of the rapidly solidified aluminium alloy became fine. The aluminium alloy foil with fine grain was used, and the investigation of the micro-formability of this alloy was investigated. Moreover, increase of the forming speed was investigated. The increase of the forming speed was purpose of this study, too.Design/methodology/approach: The nozzle pressing ...

  15. Endoscopic fringe projection for in-situ inspection of a sheet-bulk metal forming process

    Science.gov (United States)

    Matthias, Steffen; Kästner, Markus; Reithmeier, Eduard

    2015-05-01

    Sheet-bulk metal forming is a new production process capable of performing deep-drawing and massive forming steps in a single operation. However, due to the high forming forces of the forming process, continuous process control is required in order to detect wear on the forming tool before production quality is impacted. To be able to measure the geometry of the forming tool in the limited space of forming presses, a new inspection system is being developed within the SFB/TR 73 collaborative research center. In addition to the limited space, the process restricts the amount of time available for inspection. Existing areal optical measurement systems suffer from shadowing when measuring the tool's inner elements, as they cannot be placed in the limited space next to the tool, while tactile measurement systems cannot meet the time restrictions for measuring the areal geometries. The new inspection system uses the fringe projection optical measurement principle to capture areal geometry data from relevant parts of the forming tool in short time. Highresolution image fibers are used to connect the system's compact sensor head to a base unit containing both camera and projector of the fringe projection system, which can be positioned outside of the moving parts of the press. To enable short measurement times, a high intensity laser source is used in the projector in combination with a digital micro-mirror device. Gradient index lenses are featured in the sensor head to allow for a very compact design that can be used in the narrow space above the forming tool inside the press. The sensor head is attached to an extended arm, which also guides the image fibers to the base unit. A rotation stage offers the possibility to capture measurements of different functional elements on the circular forming tool by changing the orientation of the sensor head next to the forming tool. During operation of the press, the arm can be travelled out of the moving parts of the forming press

  16. Micro thermal shear stress sensor based on vacuum anodic bonding and bulk-micromachining

    Institute of Scientific and Technical Information of China (English)

    Yi Liang; Ou Yi; Shi Sha-Li; Ma Jin; Chen Da-Peng; Ye Tian-Chun

    2008-01-01

    This paper describes a micro thermal shear stress sensor with a cavity underneath, based on vacuum anodic bonding and bulk micromachined technology. A Ti/Pt alloy strip, 2μmx100μm, is deposited on the top of a thin silicon nitride diaphragm and functioned as the thermal sensor element. By using vacuum anodic bonding and bulk-si anisotropic wet etching process instead of the sacrificial-layer technique, a cavity, functioned as the adiabatic vacuum chamber, 200μm×200μm×400μm, is placed between the silicon nitride diaphragm and glass (Corning 7740). This method totally avoid adhesion problem which is a major issue of the sacrificial-layer technique.

  17. Numerical simulation of the bulk forming processes for 1345 aluminum alloy billets

    Directory of Open Access Journals (Sweden)

    Fakhreddine. KHEROUF

    2015-08-01

    Full Text Available This paper presents an improved numerical simulation of bulk metal forming processes. It takes into the account the advanced formalism of large displacements and large deformations. Also, the interface workpiece formalism in considered. Metallographic studies are conducted to determine the evolution of the micro hardness as a function of annealing time and that to characterize accurately the plastic range of aluminum alloy for a range of plasticity 120%. The obtained results of metallographic studies are used to simulate a hot upsetting under the friction law of the plastic wave. Several simulations of forging operations of an axisymmetric billet by a rigid axisymmetric conical tool are performed with ABAQUS/standard computer code and that for preheated billets from 20 °C to 500 °C. The numerical study of the evolution of the normal stress at the interface has shown that the latter is independent of the tool roughness for a temperature close to 500 °C. The numerical study also allowed us to define the three areas of forging whatever cold; warm and hot forging. The effects of friction coefficient on the metal flow and contact pressure are numerically explored.

  18. Design and Application of Quadrature Compensation Patterns in Bulk Silicon Micro-Gyroscopes

    Directory of Open Access Journals (Sweden)

    Yunfang Ni

    2014-10-01

    Full Text Available This paper focuses on the detailed design issues of a peculiar quadrature reduction method named system stiffness matrix diagonalization, whose key technology is the design and application of quadrature compensation patterns. For bulk silicon micro-gyroscopes, a complete design and application case was presented. The compensation principle was described first. In the mechanical design, four types of basic structure units were presented to obtain the basic compensation function. A novel layout design was proposed to eliminate the additional disturbing static forces and torques. Parameter optimization was carried out to maximize the available compensation capability in a limited layout area. Two types of voltage loading methods were presented. Their influences on the sense mode dynamics were analyzed. The proposed design was applied on a dual-mass silicon micro-gyroscope developed in our laboratory. The theoretical compensation capability of a quadrature equivalent angular rate no more than 412 °/s was designed. In experiments, an actual quadrature equivalent angular rate of 357 °/s was compensated successfully. The actual compensation voltages were a little larger than the theoretical ones. The correctness of the design and the theoretical analyses was verified. They can be commonly used in planar linear vibratory silicon micro-gyroscopes for quadrature compensation purpose.

  19. Uranium speciation as a function of depth in contaminated hanford sediments--a micro-XRF, micro-XRD, and micro- and bulk-XAFS study.

    Science.gov (United States)

    Singer, David M; Zachara, John M; Brown, Gordon E

    2009-02-01

    The distribution and speciation of U and Cu in contaminated vadose zone and aquifer sediments from the U.S. DOE Hanford site (300 Area) were determined using a combination of synchrotron-based micro-X-ray fluorescence (microXRF) imaging, micro-X-ray absorption near edge structure (microXANES) spectroscopy, and micro-X-ray diffraction (microXRD) techniques combined with bulk U LIII-edge X-ray absorption fine structure (XAFS) spectroscopy. Samples were collected from within the inactive North Process Pond (NPP2) at 8 ft (2.4 m, NPP2-8) depth and 12 ft (3.7 m, NPP2-12) depth in the vadose zone, and fines were isolated from turbid groundwater just below the water Table (12-14 ft, approximately 4 m, NPP2-GW). microXRF imaging, microXRD, and microXANES spectroscopy revealed two major U occurrences within the vadose and groundwater zones: (1) low to moderate concentrations of U(VI) associated with fine-textured grain coatings that were consistently found to contain clinochlore (referred to here as chlorite) observed in all three samples, and (2) U(VI)-Cu(II) hotspots consisting of micrometer-sized particles associated with surface coatings on grains of muscovite and chlorite observed in samples NPP2-8' and NPP2-GW. In the aquifer fines (NPP2-GW), these particles were identified as cuprosklodowskite (cps: Cu[(UO2)(SiO2OH)]2 x 6H2O) and metatorbernite (mtb: Cu(UO2)2(PO4)2 x 8H2O). In contrast, the U-Cu-containing particles in the vadose zone were X-ray amorphous. Analyses of U LIII-edge XAFS spectra by linear-combination fitting indicated that U speciation consisted of (1) approximately 75% uranyl sorbed to chlorite and approximately 25% mtb-like X-ray amorphous U-Cu-phosphates (8 ft depth), (2) nearly 100% sorbed uranyl (12 ft depth), and (3) approximately 70% uranyl sorbed to chlorite and approximately 30% cps/mtb (groundwater zone). These findings suggest that dissolution of U(VI)-Cu(II)-bearing solids as well as desorption of U(VI), mainly from phyllosilicates, are

  20. Elastic deflection and tilting effect in a multi-stage micro bulk former

    DEFF Research Database (Denmark)

    Mahshid, R.; Hansen, H. N.

    Previous studies have described a high performance transfer press for the application in micro forming. This research extends this finding by conducting a two-stage forming process for the machine tool in order to examine the efficiency of the machine in a real multi-stage process. In particular...... the analysis focuses on quantifying the effect the forming force has on the elastic deflection of the machine and the tools by examining the displacement of the moving plate under loaded and unloaded conditions. The results of the measurements were used to describe the tilting effect due to the off...

  1. Micro-Raman spectroscopy studies of bulk and thin films of CuInTe2

    International Nuclear Information System (INIS)

    Micro-Raman spectroscopy measurements were made on polycrystalline and amorphous thin films of CuInTe2 as well as bulk polycrystalline CuInTe2. Various vibrational modes exhibited by the bulk and polycrystalline thin films were attributed to those expected for single crystal CuInTe2. Raman spectra of amorphous films presented a broad spectrum, decomposition of which revealed the presence of elemental tellurium on the film surface. Laser-induced changes on CuInTe2 thin films were studied by acquiring spectra with higher laser beam power. Modes due to tellurium appeared when the spectra were acquired during laser–sample interaction, indicating tellurium segregation. The Raman spectra measured from polycrystalline films during high laser power irradiation did not show decrease in the intensity of the A1 mode of CuInTe2 in spite of loss of tellurium from the lattice. This has been interpreted as related to an increased contribution from the undistorted subsurface CuInTe2 region at higher excitation power

  2. Linking structure to fragility in bulk metallic glass-forming liquids

    Energy Technology Data Exchange (ETDEWEB)

    Wei, Shuai, E-mail: shuai.wei@asu.edu, E-mail: m.stolpe@mx.uni-saarland.de [Department of Materials Science and Engineering, Saarland University, Campus C63, 66123 Saarbrücken (Germany); Department of Chemistry and Biochemistry, Arizona State University, Tempe, Arizona 85287 (United States); Stolpe, Moritz, E-mail: shuai.wei@asu.edu, E-mail: m.stolpe@mx.uni-saarland.de; Gross, Oliver; Gallino, Isabella; Hembree, William; Busch, Ralf [Department of Materials Science and Engineering, Saarland University, Campus C63, 66123 Saarbrücken (Germany); Evenson, Zach [Department of Materials Science and Engineering, Saarland University, Campus C63, 66123 Saarbrücken (Germany); Institut für Materialphysik im Weltraum, Deutsches Zentrum für Luft- und Raumfahrt (DLR), 51170 Köln (Germany); Bednarcik, Jozef [Deutsches Elektronen-Synchrotron DESY, Notkestrasse 85, D-22603 Hamburg (Germany); Kruzic, Jamie J. [Material Science, School of Mechanical, Industrial, and Manufacturing Engineering, Oregon State University, Corvallis, Oregon 97331 (United States)

    2015-05-04

    Using in-situ synchrotron X-ray scattering, we show that the structural evolution of various bulk metallic glass-forming liquids can be quantitatively connected to their viscosity behavior in the supercooled liquid near T{sub g}. The structural signature of fragility is identified as the temperature dependence of local dilatation on distinct key atomic length scales. A more fragile behavior results from a more pronounced thermally induced dilatation of the structure on a length scale of about 3 to 4 atomic diameters, coupled with shallower temperature dependence of structural changes in the nearest neighbor environment. These findings shed light on the structural origin of viscous slowdown during undercooling of bulk metallic glass-forming liquids and demonstrate the promise of predicting the properties of bulk metallic glasses from the atomic scale structure.

  3. Linking structure to fragility in bulk metallic glass-forming liquids

    International Nuclear Information System (INIS)

    Using in-situ synchrotron X-ray scattering, we show that the structural evolution of various bulk metallic glass-forming liquids can be quantitatively connected to their viscosity behavior in the supercooled liquid near Tg. The structural signature of fragility is identified as the temperature dependence of local dilatation on distinct key atomic length scales. A more fragile behavior results from a more pronounced thermally induced dilatation of the structure on a length scale of about 3 to 4 atomic diameters, coupled with shallower temperature dependence of structural changes in the nearest neighbor environment. These findings shed light on the structural origin of viscous slowdown during undercooling of bulk metallic glass-forming liquids and demonstrate the promise of predicting the properties of bulk metallic glasses from the atomic scale structure

  4. DIFFERENCE SPECTROPHOTOMETRIC ESTIMATION OF PRASUGREL HYDROCHLORIDE IN BULK AND TABLET DOSAGE FORM

    OpenAIRE

    Desai Darshali Satishkumar; Barmecha Bharati Subhash; Walode Sanjay Gomaji

    2012-01-01

    A simple, precise and accurate difference spectroscopic method has been developed for the estimation of prasugrel hydrochloride in bulk and in pharmaceutical dosage form. The proposed method is based on the principle that prasugrel hydrochloride exhibits in two different chemical forms that differs in the absorption spectra in basic and acidic medium. The absorbances were measured in acidic and basic solution separately against reagent blank. Prasugrel hydrochlo...

  5. Micro analysis of fringe field formed inside LDA measuring volume

    Science.gov (United States)

    Ghosh, Abhijit; Nirala, A. K.

    2016-05-01

    In the present study we propose a technique for micro analysis of fringe field formed inside laser Doppler anemometry (LDA) measuring volume. Detailed knowledge of the fringe field obtained by this technique allows beam quality, alignment and fringe uniformity to be evaluated with greater precision and may be helpful for selection of an appropriate optical element for LDA system operation. A complete characterization of fringes formed at the measurement volume using conventional, as well as holographic optical elements, is presented. Results indicate the qualitative, as well as quantitative, improvement of fringes formed at the measurement volume by holographic optical elements. Hence, use of holographic optical elements in LDA systems may be advantageous for improving accuracy in the measurement.

  6. Spray-Formed Tooling with Micro-Scale Features

    Energy Technology Data Exchange (ETDEWEB)

    Kevin McHugh

    2010-06-01

    Molds, dies, and related tooling are used to shape many of the plastic and metal components we use every day at home and work. Traditional mold-making practices are labor and capital equipment intensive, involving multiple machining, benching and heat treatment operations. Spray forming is an alternative method to manufacture molds and dies. The general concept is to atomize and deposit droplets of a tooling alloy onto a pattern to form a thick deposit while imaging the pattern’s shape, surface texture and details. Unlike conventional machining, this approach can be used to fabricate tooling with micro-scale surface features. This paper describes a research effort to spray form molds and dies that are used to image micro-scale surface textures into polymers. The goal of the study is to replicate textures that give rise to superhydrophobic behavior by mimicking the surface structure of highly water repellent biological materials such as the lotus leaf. Spray conditions leading to high transfer fidelity of features into the surface of molded polymers will be described. Improvements in water repellency of these materials was quantified by measuring the static contact angle of water droplets on flat and textured surfaces.

  7. Microscopic insight into the origin of enhanced glass-forming ability of metallic melts on micro-alloying

    International Nuclear Information System (INIS)

    Extensive efforts have been made to develop metallic-glasses with large casting diameter. Such efforts were hindered by the poor understanding of glass formation mechanisms and the origin of the glass-forming ability (GFA) in metallic glass-forming systems. In this work, we have investigated relaxation dynamics of a model bulk glass-forming alloy system that shows the enhanced at first and then diminished GFA on increasing the percentage of micro-alloying. The micro-alloying did not have any significant impact on the thermodynamic properties. The GFA increasing on micro-alloying in this system cannot be explained by the present theoretical knowledge. Our results indicate that atomic caging is the primary factor that influences the GFA. The composition dependence of the atomic caging time or residence time is found to be well correlated with GFA of the system

  8. VALIDATED SPECTROPHOTMETRIC METHOD FOR THE DETERMINATION OF SALBUTAMOL SULPHATE IN BULK AND PHARMACEUTICAL DOSAGE FORMS

    Directory of Open Access Journals (Sweden)

    Eswarudu.M.M

    2012-04-01

    Full Text Available A new, simple, accurate and sensitive spectrophotometric method has been developed for the estimation of Salbutamol sulphate in bulk and in pharmaceutical formulations. Salbutamol sulphate shows ʎ max at 292 nm. The drug follows the beer’s lambert’s law in the concentration range of 20-100µ ml. the method was validated by following the analytical performance parameters as suggested by the international conference on harmonization which included accuracy, precision, linearity. All validation parameters were with in the acceptable range. The developed method was successfully applied to estimate the amount of Salbutamol sulphate in bulk and pharmaceutical dosage forms.

  9. Preparation and characterization of Zr-based bulk metallic glasses in form of plate

    International Nuclear Information System (INIS)

    Highlights: • Zr-based BMGs in form of plate was successful produced by die pressure casting method. • Many techniques have been used to characterize the structure of Zr55Cu30Ni5Al10 alloy. • The calculated GFA parameters show that the alloy exhibits satisfactory GFA. • The studies reveal that tested as-cast Zr-based alloy is in amorphous state. - Abstract: Zr-based bulk metallic glasses present an interesting combination of physical, chemical and mechanical properties. During the last decade, intensive progress has been made and a number of applications have been suggested for these materials. In order to successfully apply these materials, it is necessary to accurately characterize their structure, thermal stability and other properties accurately. The aim of the presented work is the manufacturing, examination of the structure of selected Zr-based bulk metallic alloys and confirmation of an amorphous structure using X-ray analysis, microscopic observation and thermal analysis. In this work, the Zr-based bulk metallic glasses in form of plate was successful produced by die pressure casting method. Designed scientific station for casting zirconium based amorphous alloys in the form of plates and rods with selected dimensions is in our university a comprehensive method for achieving amorphous materials which enables us to maintain repeatability of as-cast samples with the amorphous structure and the assumed dimensions range. The diffraction pattern and exothermic reaction as well as the fracture surface morphology reveal that studied as-cast Zr-based alloy is in amorphous state. The calculated GFA parameters show that the alloy exhibits satisfactory glass-forming ability in form of studied plate. These obtained values can suggest that studied alloys are suitable materials for further planned practical application at welding process. The success of Zr-based bulk metallic glasses production in form of plate with obtained sizes is important for future progress

  10. An overview of micro-optical components and system technology: bulk, planar, and thin-film for laser initiated devices

    Science.gov (United States)

    Lizotte, Todd

    2010-08-01

    There are a number of attractive micro optical elements or combinations of elements that are currently used or could be employed in optically initiated ordnance systems. When taking a broad-spectrum examination of optically initiated devices, the required key parameters become obviously straightforward for micro optics. Plainly stated, micro optics need to be simple, inexpensive, reliable, robust and compatible within their operational environment. This presentation focuses on the variety of optical elements and components available in the market place today that could be used to realize micro-optical beam shaping and delivery systems for optically initiated devices. A number of micro optical elements will be presented with specific bulk, planar optical and thin film optical devices, such as diffractive optics, micro prisms, axicons, waveguides, micro lenses, beam splitters and gratings. Further descriptions will be presented on the subject of coupling light from a laser beam into a multimode optical fiber. The use of micro optics for collimation of the laser source and conditioning of the laser beam to achieve the highest efficiency and matching the optical fiber NA will be explained. An emphasis on making these optical assemblies compact and rugged will be highlighted.

  11. COLORIMETRIC DETERMINATION OF CEFQUINOME SULPHATE IN BULK AND DOSAGE FORM USING AMMONIUM MOLYBDATE

    OpenAIRE

    Shaza Wageialla Shantier; Elrasheed Ahmed Gadkariem

    2014-01-01

    This study was designed to develop two colorimetric methods for the determination of Cefquinome Sulphate (CS) in bulk and dosage forms using two different concentrations of molybdenum solution. The developed methods were based on the oxidation of CS with 2% ammonium molybdate, in the presence of sulphuric acid, producing a green colored product with λmax at 409 nm (Method I) and the oxidation of CS with 10% ammonium molybdate in acidic media to produce a blue col...

  12. Thermal and elastic properties of Cu–Zr–Be bulk metallic glass forming alloys

    OpenAIRE

    Duan, Gang; Lind, Mary Laura; De Blauwe, Katrien; Wiest, Aaron; Johnson, William L.

    2007-01-01

    The compositional dependence of thermal and elastic properties of Cu–Zr–Be ternary bulk metallic glass forming alloys was systematically studied. There exists a linear relationship between the glass transition temperature Tg and the total Zr concentration. G decreases linearly with increasing Zr concentration as well. The results also show that Tg, shear modulus G, and Poisson's ratio nu are very sensitive to changes in compositions. Low Tg, low G, and relatively high nu can be achieved with ...

  13. Forming and disintegration kinetics of nickel micro inclusions in silicon monocrystal

    International Nuclear Information System (INIS)

    By the method of electron-probe microanalysis a phase structure of nickel micro inclusions in silicon monocrystals has been investigated. Also sequence of micro inclusion disintegration under influence of all-round hydrostatic pressure has been studied. The phase structures and forms of nickel micro inclusions are revealed. It is established, that forms of formed micro inclusions depend on temperature of diffusional annealing of samples and have the character by stages. (authors)

  14. New developments in bulk forming of power train components of enhanced performance characteristics

    Energy Technology Data Exchange (ETDEWEB)

    Lorenz, B.; Glass, R.; Hartwig, H. [Fraunhofer-Institut Werkzeugmaschinen und Umformtechnik, Chemnitz (Germany)

    2005-07-01

    Highly loaded car components will be manufactured of steels by bulk forming also in future because optimal performance characteristics can be obtained by those techniques. Research and development is aimed at the production of still more complex components of high-strength steels using highly productive forming processes. In this paper, new process developments in warm extrusion, spin extrusion and cross rolling are described, which can contribute to reduced production time and are directed towards enhanced in-service safety of power train components and their weight reduction. (orig.)

  15. Study on the effect of humidity and dust on leakage current of bulk micro-MEGAS detector

    CERN Document Server

    Wang, Bo; Qi, Hui-Rong; Liu, Jing; Zhang, Xin-Shuai; Zhang, Tian-Chong; Yi, Fu-Ting; Ou-Yang, Qun; Chen, Yuan-Bo

    2013-01-01

    In this paper, the effect of humidity and dust trapped in avalanche region on leakage current of bulk micro-MEGAS detector is studied. Pyralux PC1025 layers of DuPont are introduced in bulk technique and micro-MEGAS detector with pillars of 300{\\mu}m in diameter is fabricated. Leakage current is tested in air with different humidity. Silicon carbide powder and PMMA (polymethyl methacrylate) powder are added as dust to avalanche region. Leakage current with and without powder is tested in air and results are depicted in the same figure. Test results indicate that leakage current increases with both storage humidity and test humidity, and also increases when powder is introduced in avalanche region.

  16. Method Development and Validation of Montelukast in Bulk and Pharmaceutical Dosage form by RP-HPLC

    OpenAIRE

    Minaketan Sahoo

    2012-01-01

    The present work describes a simple, precise and accurate HPLC method for estimation of montelukast sodium in bulk and in tablet dosage form. Montelukast sodium is a selective and orally active leukotriene receptor antagonist that inhibits the cysteinyl leukotriene (CysLT1) receptor. The separation was achieved by using Waters symmetry shield RP-C8 column and acetonitrile: sodium di-hydrogen Phosphate dehydrate (pH 3.7) in proportion of 70:30 v/v as mobile phase, at a flow rate of 1.5 ml/min....

  17. HPLC METHOD DEVELOPMENT OF AMLODIPINE BY RP-HPLC IN ITS BULK DOSAGE FORMS

    OpenAIRE

    V. Naveen Kumar, K. Kiran kumar, P. Ramesh Babu, K. Anilkumar

    2012-01-01

    A new, simple, precise, sensitive, accurate and reproducible Reverse phase HPLC method was developed and validated for the analysis of amlodipine in bulk dosage forms. The separation was conducted by using c-18 RP-HPLC coloumn, which was maintained at ambient temperature. The mobile phase consisting of Phosphate buffer and Acetonitrile (90:10v/v) was delivered at a rate of 1.5 ml/min. The analysis was detected by using UV detector at the wave length of 225nm.The method is validated for its ...

  18. Cu-based bulk amorphous alloy with larger glass-forming ability and supercooled liquid region

    Energy Technology Data Exchange (ETDEWEB)

    Fu, H.M. [Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016 (China); School of Engineering, University of Queensland, St. Lucia, Qld 4072 (Australia)], E-mail: waterdrophmfu@hotmail.com; Zhang, H.F. [Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016 (China); Wang, H. [Faculty of Engineering and Surveying, University of Southern Queensland, Toowoomba, Qld 4350 (Australia); Hu, Z.Q. [Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016 (China)

    2008-06-30

    The glassy rod with a maximum sample thickness of 11 mm and larger supercooled liquid region of 108 K was successfully fabricated when substituting Cu with minor amount of Ag in the Cu-Zr-Al-Gd alloy system. The value of {gamma} reaches a maximum of 0.418 for the Cu{sub 45.5}Zr{sub 45}Al{sub 7}Gd{sub 2}Ag{sub 0.5} bulk metallic glass (BMG) alloy. The high glass-forming ability (GFA) and larger supercooled liquid region are discussed from atomic size, negative mixing heat among constituent elements and thermodynamics.

  19. Method Development and Validation of Montelukast in Bulk and Pharmaceutical Dosage form by RP-HPLC

    Directory of Open Access Journals (Sweden)

    Minaketan Sahoo

    2012-09-01

    Full Text Available The present work describes a simple, precise and accurate HPLC method for estimation of montelukast sodium in bulk and in tablet dosage form. Montelukast sodium is a selective and orally active leukotriene receptor antagonist that inhibits the cysteinyl leukotriene (CysLT1 receptor. The separation was achieved by using Waters symmetry shield RP-C8 column and acetonitrile: sodium di-hydrogen Phosphate dehydrate (pH 3.7 in proportion of 70:30 v/v as mobile phase, at a flow rate of 1.5 ml/min. Detection was carried out at 225 nm. The retention time of montelukast sodium was found to be 3.721 min. The limit of detection was found 0.1357 µg/ml and limit of quantification 0.4111 µg/ml. The accuracy and reliability of the proposed method was ascertained by evaluating various validation parameters like linearity (1-30 µg/ml, accuracy, precision, robustness and specificity according to ICH guidelines. The method was statistically validated and RSD was found to be less than 2% indicating high degree of accuracy and precision of the proposed HPLC method. Due to its simplicity, rapidness, high precision and accuracy, the proposed HPLC method may be used for determining Montelukast in bulk or in pharmaceutical dosage forms.

  20. HPTLC DETERMINATION OF SORAFENIB TOSYLATE IN BULK DRUG AND PHARMACEUTICAL DOSAGE FORM

    Directory of Open Access Journals (Sweden)

    Powar Amol Shivaji

    2012-02-01

    Full Text Available A simple and sensitive HPTLC method has been developed for the quantitative estimation of Sorafenib Tosylate in bulk and Pharmaceutical dosage form. Sorafenib Tosylate was chromatographed on silica Gel 60 F254 TLC plate using n-Hexane : isopropanol (8:2 v/v as mobile phase. Sorafenib Tosylate showed Rf value 0.34±0.05 and scanned at 254 nm using Camag TLC Scanner 3. The method was validated in terms of linearity (100–500 ng/spot, precision (intra-day % RSD variation 0.07 to 0.39%, inter-day % RSD variation 0.5 to 1.2%, accuracy (98.88 to 100.815% specificity, ruggedness, sensitivity and reproducibility. The limit of detection and limit of quantitation for Sorafenib Tosylate were found to be 1.57 ng/spot and 4.75 ng/spot, respectively. The developed method was successfully used for the assay of Sorafenib Tosylate in bulk and Pharmaceutical dosage form.. it can be used for the routine quality control testing of marketed formulations.

  1. Spectrophotometric Determination of drugs in bulk and pharmaceutical dosage forms by using Tetracyanoethylene

    Directory of Open Access Journals (Sweden)

    Bathini.Srinivas

    2015-06-01

    Full Text Available A selective ,sensitive ,accurate UV-Visible spectrophotometric methods have been developed for the estimation of drugs viz.,Diflunisal (DFL,Febuxostat(FBT,Metaxalone(MTX,Fexofenadine methyl ester(FME and Linezolid(LZD in bulk and their pharmaceutical dosage forms using Tetracyanoethylene (TCNE as analytical reagent. These method are based on the formation of charge transfer complexes of drugs as n-electron donor with TCNE as π-acceptor .The selected drugs turned the colorless solution of TCNE in Acetonytrile to yellow and exhibited a doublet at 400 & 420nm due to the formation of Complex of drugs with TCNE.Under the optimized experimental conditions ,Beer, s law is obeyed over the concentration ranges of 10-50 μg/ml ,5- 25 μg/ml,15-75 μg/ml,5-25 μg/ml and 5-25 μg/ml for DFL,FBT,MTX,FME and LZD respectively. The effect of reagent concentrations, polarity of solvents and effect of reaction time have been studied and optimized. These methods have been validated in terms of ICH guidelines and applied to the quantification of selected drugs in bulk and dosage forms.

  2. The choice of nuclear material measurement strategy in bulk-form in material balance area

    International Nuclear Information System (INIS)

    Concepts have been defined such as Shipment batch, Technological batch, and Accounting batch, it has been found that Shipment and Technological batches should be formed through the arrangement of group of measured Accounting batches. The strategy for nuclear material (NM) measurement based on the Accounting batch is shown to give a possibility to use the advantages for the accounting purposes: ensure safeguards of non-diversion of NM at quantitative (numerical) level, which is a higher grade of safeguards compared to the systems of accounting and control now in force of the US and EURATOM; ensure a guaranteed accuracy and reliability (confidence level) when making up NM balance in Material Balance Area (MBA) and at Federal level, which has been realized only in part in the NM control and accounting systems. Strategy of NM measurement for MBAs counting NM in bulk form has been proposed

  3. Steady-state tensile viscous flow forming of bulk metallic glass

    International Nuclear Information System (INIS)

    Highlights: ► A simple setup is demonstrated for tensile viscous flow forming of bulk metallic glass to large aspect ratio. ► The flow stress of the part of the material to be deformed is lowered thermally, by local induction heating. ► Applying the mechanical load to the less-softened ends, via attached wires, is straight forward. ► An asymmetric configuration allows to form rods into wire by a steady-state process. ► For this asymmetric configuration, preparing the preform and attaching the wires requires no machining. - Abstract: Tensile viscous flow is explored as a forming method for metallic glasses in their supercooled liquid temperature region. Bulk amorphous preforms with nominal alloy composition Zr55Cu30Al10Ni5 were produced by arc melting and tilt- and suction casting into a copper mould. A simple loading rig, in which the preform is suspended from a wire, combined with selective heating of the section to be deformed, avoids the need for complicated loading grips. Different strategies are evaluated to attach the sample to the rig and to selectively heat the central part of the specimen. Finite element models were compared with experiments to verify the design of the induction heating coil and optimize process parameters. Differential scanning calorimetry and X-ray diffraction measurements show that the material is glassy before and after deformation. The rapid decrease of flow stress with increasing temperature means that the process can be controlled thermally at constant load instead of mechanically at constant temperature. An asymmetric configuration, where the selective heating zone is moved relative to the specimen during the deformation, allows to form rods into wire by a steady-state process. The effect of deformation on induction heating under constant tension was found to be inherently self-stabilizing, reducing the need for precise process control.

  4. Replication of nano/micro-scale features using bulk metallic glass mold prepared by femtosecond laser and imprint processes

    International Nuclear Information System (INIS)

    This study describes the replication of nano/micro-scale features using a Pd40Ni40P20 bulk metallic glass (BMG) mold prepared using a femtosecond laser and nanoimprinting process. The use of the beam shaper feature of the femtosecond laser enabled the rapid fabrication of periodic nanostripes over an area of ∼5 × 4 mm2 on the BMG mold following a single pulse of irradiation. The ablation pitch of the nanostructure irradiated with 100 mW of femtosecond laser power was determined to be 175.8 nm. The imprinting results demonstrate the applicability of Pd-based BMG in the replication of mold features ranging from 100 µm to 90 nm. Additionally, Pd-based BMG can itself be used as a mold to transfer features onto Au-based BMG and polydimethylsiloxane, where the results could be used to ascertain the workability of BMG for molding in a nano/micro-imprint process. (paper)

  5. HPLC METHOD DEVELOPMENT OF AMLODIPINE BY RP-HPLC IN ITS BULK DOSAGE FORMS

    Directory of Open Access Journals (Sweden)

    V. Naveen Kumar, K. Kiran kumar, P. Ramesh Babu, K. Anilkumar

    2012-06-01

    Full Text Available A new, simple, precise, sensitive, accurate and reproducible Reverse phase HPLC method was developed and validated for the analysis of amlodipine in bulk dosage forms. The separation was conducted by using c-18 RP-HPLC coloumn, which was maintained at ambient temperature. The mobile phase consisting of Phosphate buffer and Acetonitrile (90:10v/v was delivered at a rate of 1.5 ml/min. The analysis was detected by using UV detector at the wave length of 225nm.The method is validated for its specificity, precision, accuracy, linearity and robustness. The method was found to be linear over the concentration range 10-100 g/ml (r2 =0.999. The retention time for amlodipine was found to be 3.34min. Limit of quantification of the method is 0.179g/ml and limit of detection is 0.054 g/ml.

  6. On the origin of bulk glass forming ability in Cu-Hf, Zr alloys

    Science.gov (United States)

    Ristić, Ramir; Zadro, Krešo; Pajić, Damir; Figueroa, Ignacio A.; Babić, Emil

    2016-04-01

    Understanding the formation of bulk metallic glasses (BMG) in metallic systems and finding a reliable criterion for selection of BMG compositions are among the most important issues in condensed-matter physics and material science. Using the results of magnetic susceptibility measurements performed on both amorphous and crystallized Cu-Hf alloys (30–70 at% Cu) we find a correlation between the difference in magnetic susceptibilities of corresponding glassy and crystalline alloys and the variation in the glass forming ability (GFA) in these alloys. Since the same correlation can be inferred from data for the properties associated with the electronic structure of Cu-Zr alloys, it seems quite general and may apply to other glassy alloys based on early and late transition metals. This correlation is plausible from the free-energy considerations and provides a simple way to select the compositions with high GFA.

  7. UV Spectrophotometric Method for Estimation of Polypeptide-K in Bulk and Tablet Dosage Forms

    Science.gov (United States)

    Kaur, P.; Singh, S. Kumar; Gulati, M.; Vaidya, Y.

    2016-01-01

    An analytical method for estimation of polypeptide-k using UV spectrophotometry has been developed and validated for bulk as well as tablet dosage form. The developed method was validated for linearity, precision, accuracy, specificity, robustness, detection, and quantitation limits. The method has shown good linearity over the range from 100.0 to 300.0 μg/ml with a correlation coefficient of 0.9943. The percentage recovery of 99.88% showed that the method was highly accurate. The precision demonstrated relative standard deviation of less than 2.0%. The LOD and LOQ of the method were found to be 4.4 and 13.33, respectively. The study established that the proposed method is reliable, specific, reproducible, and cost-effective for the determination of polypeptide-k.

  8. RP-HPLC Method Development and Validation of Abacavir Sulphate in Bulk and Tablet Dosage Form

    Directory of Open Access Journals (Sweden)

    S. LAVANYA

    2014-11-01

    Full Text Available RP-HPLC method was developed for the estimation of abacavir sulphate in bulk and pharmaceutical dosage form (tablets by using INERTSIL ODS 3V column, C18 (250x4.6 ID mobile phase consisting of a mixture of 10mM phosphate buffer: ACN (60:40 v/v % PH: 4.0 with detection of 287 nm. The retention time was found to be 2.430min and linearity was observed in the range 60-140μg /ml. Still now there were a number of analytical methods were developed for the estimation of abacavir in pharmaceutical dosage form and also in biological samples like spectroscopic methods, chromatographic methods, etc. But the present method was met the validation parameters according ICH guidelines like accuracy, precision, linearity, range, robustness, ruggedness, limit of detection and limit of quantitation, etc. with a short around time. The method was found to be precise as indicated by the repeatability analysis, showing %RSD less than 2.

  9. New Simple UV Spectrophotometric Method for Determination of Mirtazapine in Bulk and pharmaceutical dosage forms

    Directory of Open Access Journals (Sweden)

    Sk. Benajeer

    2012-10-01

    Full Text Available Mirtazapine is chemically a tetratetracyclic (pyridodibenzazepine derivative which is classified as a noradrenergic and specific serotonergic antidepressant (NaSSA. Mirtazapine acts as an antagonist at central pre-synaptic α2-receptors, inhibiting negative feedback to the presynaptic nerve and causing an increase in NErelease. It is also used for the treatment of Posttraumatic stress disorder. In present work, simple, sensitive, accurate and economical spectroscopic method has been developed for the estimation of mirtazapine in bulk and its pharmaceutical dosage forms. An absorption maximum was found to be at 232nm with the solvent systemphosphate buffer (pH 6.8. The drug follows beer’s law in the range of 5-30μg/ml with correlation coefficient of 0.999. The percentage recovery of mirtazapine ranged from 99.57-100.26% in pharmaceutical dosage form. Results of the analysis were validated for accuracy, precision, LOD, LOQ and were found to be satisfactory. The proposed method is simple, rapid and suitable for the routine quality control analysis.

  10. Thermoluminescence Dynamics During Destructions of Porous Structures Formed by Nitrogen Nanoclusters in Bulk Superfluid Helium

    Science.gov (United States)

    Meraki, Adil; Mao, Shun; McColgan, Patrick T.; Boltnev, Roman E.; Lee, David M.; Khmelenko, Vladimir V.

    2016-03-01

    We studied the dynamics of thermoluminescence during destruction of porous structures formed by nanoclusters of nitrogen molecules containing high concentrations of stabilized nitrogen atoms. The porous structures were formed in bulk superfluid helium by injection of the products of discharges in nitrogen-helium gas mixtures through the liquid helium surface. Fast recombination of nitrogen atoms during warming-up led to explosive destruction of the porous structures accompanied by bright flashes. Intense emissions from the α -group of nitrogen atoms, the β -group of oxygen atoms and the Vegard-Kaplan bands of N_2 molecules were observed at the beginning of destruction. At the end of destruction the M- and β -bands of NO molecules as well as bands of O_2 molecules were also observed. Observation of the emissions from NO molecules at the end of destruction was explained by processes of accumulation of NO molecules in the system due to the large van der Waals interaction of NO molecules. For the first time, we observed the emission of the O_2 molecules at the end of destruction of the porous nitrogen structures as a result of the (NO)_2 dimer formation in solid nitrogen and subsequent processes leading to the appearance of excited O_2 molecules.

  11. COLORIMETRIC DETERMINATION OF CEFQUINOME SULPHATE IN BULK AND DOSAGE FORM USING AMMONIUM MOLYBDATE

    Directory of Open Access Journals (Sweden)

    Shaza Wageialla Shantier

    2014-01-01

    Full Text Available This study was designed to develop two colorimetric methods for the determination of Cefquinome Sulphate (CS in bulk and dosage forms using two different concentrations of molybdenum solution. The developed methods were based on the oxidation of CS with 2% ammonium molybdate, in the presence of sulphuric acid, producing a green colored product with λmax at 409 nm (Method I and the oxidation of CS with 10% ammonium molybdate in acidic media to produce a blue colored product with λmax at 673 nm (Method II. The factors affecting the color development and stability were optimized and incorporated in the procedure. Beer’s law was obeyed over the concentration range 16-80 µg mL-1 (Method I and 40-80 µg mL-1 (Method II with a correlation coefficient not less than 0.999. The limit of detection and limit of quantification were 5.7 and 18.9 µg mL-1 for Method I, 4.25 µg mL-1 and 14.2 µg mL-1 for Method II respectively. The average recovery for the dosage form (suspension 2.5% was 100.30% ±0.59; n = 3, which reflected no interference by the suspension excipients. The results obtained by the developed methods for the suspension dosage form were statistically compared with those of a developed HPLC method and evaluated at 95% confidence limits. The developed methods were proved to be accurate and simple. The methods involved in the study covered, Colorimetric spectrophotometry, High Performance Liquid Chromatography. The molar ratio method is recommended to be conducted in order to determine the reaction stoichiometry.

  12. A new parameter to evaluate the glass-forming ability of bulk metallic glasses

    International Nuclear Information System (INIS)

    Research highlights: → Develop a new criterion, i.e., Q=((Tg+Tx)/Tl).(ΔE/ΔH). → The reliability and benefits of the new criterion have been demonstrated in a wide range of BMG alloys. → It corresponds well with the critical diameter of BMGs investigated up to now. - Abstract: Based on the consideration of the liquid phase stability, the resistance to crystallization and the glass transition enthalpy, a new criterion Q, defined as ((Tg + Tx)/Tl).(ΔE/ΔH), where the Tg, Tx, Tl, ΔE and ΔH are the glass transition temperature, the onset crystallization temperature, the liquidus temperature, the crystalline enthalpy and the fusion enthalpy, respectively, has been proposed for evaluating the glass-forming ability of bulk metallic glasses. The new criterion Q exhibits better correlation with the maximum cross section thickness (Dm) for glass formation compared with γ (=Tx/(Tl + Tg)), Trg (=Tg/Tl) and ΔTx (=Tx - Tg) respectively. The available data from literatures and experiments have confirmed the effectiveness of the newly developed criterion.

  13. AC Calorimetry and Thermophysical Properties of Bulk Glass-Forming Metallic Liquids

    Science.gov (United States)

    Johnson, William L.

    2000-01-01

    Thermo-physical properties of two bulk metallic glass forming alloys, Ti34Zr11Cu47Ni8 (VIT 101) and Zr57Nb5Ni12.6Al10CU15.4 (VIT 106), were investigated in the stable and undercooled melt. Our investigation focused on measurements of the specific heat in the stable and undercooled liquid using the method of AC modulation calorimetry. The VIT 106 exhibited a maximum undercooling of 140 K in free radiative cooling. Specific heat measurements could be performed in stable melt down to an undercooling of 80 K. Analysis of the specific heat data indicate an anomaly near the equilibrium liquidus temperature. This anomaly is also observed in y the temperature dependencies of the external relaxation time, the specific volume, and the surface tension; it is tentatively attributed to a phase separation in the liquid state. The VIT 101 specimen exhibited a small undercooling of about 50 K. Specific heat measurements were performed in the stable and undercooled melt. These various results will be combined with ground based work such as the measurement of T-T-T curves in the electrostatic levitator and low temperature viscosity and specific heat measurements for modeling the nucleation kinetics of these alloys.

  14. Micro-PIC. A Simple Form of the Profile of Interaction in the Classroom.

    Science.gov (United States)

    Forbes, Joan

    The Profile of Interaction in the Classroom (PIC) is a feedback method of interaction analysis, based on the Flanders System, created for supervisors of pre-service and in-service teacher education. The Micro-PIC is an abbreviated simplified form for analysis of shorter periods of interaction, particularly in microteaching. The Micro-PIC…

  15. Bulk refractive-index sensitivities of the THz-range plasmon resonances on a micro-size graphene strip

    International Nuclear Information System (INIS)

    We studied numerically the potential use of a micro-size graphene strip as a surface plasmon (SP) resonance-based bulk refractive-index sensor in the THz frequency regime. Our accurate computational instrument was an in-house algorithm based on integral equations (IEs) and Nystrom discretization. The refractive-index sensitivities and figure-of-merit (FOM) values of the associated plasmon resonances were calculated. It was found that the primary plasmon mode P 1 is more sensitive to the refractive-index changes than plasmons of higher orders, although the latter demonstrated much larger FOM values explained by the higher Q-factors. The FOM values of the higher-order resonances on a graphene strip in the THz range are at a level similar to the FOM values of the localized SP resonances on a noble-metal strip in the optical range. (paper)

  16. Ductile Damage and Fatigue Behavior of Semi-Finished Tailored Blanks for Sheet-Bulk Metal Forming Processes

    Science.gov (United States)

    Besserer, Hans-Bernward; Hildenbrand, Philipp; Gerstein, Gregory; Rodman, Dmytro; Nürnberger, Florian; Merklein, Marion; Maier, Hans Jürgen

    2016-03-01

    To produce parts from sheet metal with thickened functional elements, bulk forming operations can be employed. For this new process class, the term sheet-bulk metal forming has been established recently. Since sheet-bulk metal forming processes such as orbital forming generates triaxial stress and strain states, ductile damage is induced in the form of voids in the microstructure. Typical parts will experience cyclic loads during service, and thus, the influence of ductile damage on the fatigue life of parts manufactured by orbital forming is of interest. Both the formation and growth of voids were characterized following this forming process and then compared to the as-received condition of the ferritic deep drawing steel DC04 chosen for this study. Subsequent to the forming operation, the specimens were fatigued and the evolution of ductile damage and the rearrangement of the dislocation networks occurring during cyclic loading were determined. It was shown, that despite an increased ductile damage due to the forming process, the induced strain hardening has a positive effect on the fatigue life of the material. However, by analyzing the fatigued specimens a development of the ductile damage by an increasing number of voids and a change in the void shape were detected.

  17. A Flexible Ultrasound Transducer Array with Micro-Machined Bulk PZT

    Directory of Open Access Journals (Sweden)

    Zhe Wang

    2015-01-01

    Full Text Available This paper proposes a novel flexible piezoelectric micro-machined ultrasound transducer, which is based on PZT and a polyimide substrate. The transducer is made on the polyimide substrate and packaged with medical polydimethylsiloxane. Instead of etching the PZT ceramic, this paper proposes a method of putting diced PZT blocks into holes on the polyimide which are pre-etched. The device works in d31 mode and the electromechanical coupling factor is 22.25%. Its flexibility, good conformal contacting with skin surfaces and proper resonant frequency make the device suitable for heart imaging. The flexible packaging ultrasound transducer also has a good waterproof performance after hundreds of ultrasonic electric tests in water. It is a promising ultrasound transducer and will be an effective supplementary ultrasound imaging method in the practical applications.

  18. UV-SPECTROPHOTOMETRIC ESTIMATION OF ACYCLOVIR IN BULK AND PHARMACEUTICAL DOSAGE FORMS

    Directory of Open Access Journals (Sweden)

    Narayana Raju Padala

    2013-08-01

    Full Text Available Analytical method development being a vital part of pre formulation-formulation research and development obviates the need to develop reliable, effective, eco friendly and cost effective methodologies for routine analysis of active pharmaceutical ingredients. UV spectroscopy is one of the earliest, yet of wide applications in drug analysis in different stages of formulations and quality control; despite the availabilities of sophisticated chromatographic techniques and other hyphenated techniques. Current research attempts to develop simple, sensitive, accurate, precise and economical UV spectrophotometric methods for the routine analysis of acyclovir in bulk and pharmaceutical dosage forms using two separate alkaline media, 0.1N NaOH (method A and 0.1N KOH (method B and validate them as per ICH guidelines. In both the methods maximum absorbance was observed at 264 nm. Beer’s law was obeyed in the concentration of 2.5-40 µg / mL in method A and 2.5-30 µg / mL in method B with correlation coefficient of 0.999. The % recovery carried out by adding known amount of standard drug to pre-analyzed tablet solutions was 98.75 ± 0.52 % to 99.78 ± 0.69 % (method A and 98.55 ± 0.31 % to 99.78 ± 0.22 % (method B. Intra and interday precision expressed in % RSD were 0.38 ± 0.01 and 0.27 ± 0.02 - 0.44 ± 0.01 respectively and the percent purity was 99.85 ± 0.05 %. The methods were validated statistically as per ICH guidelines and the results obtained were within the acceptance criteria for the parameters relating to linearity, accuracy, precision.

  19. Bulk micro-machined wide-band aero-acoustic microphone and its application to acoustic ranging

    International Nuclear Information System (INIS)

    A wide-band aero-acoustic microphone was realized using a bulk micro-machining process based on the deep reactive-ion etching of silicon. The sensing diaphragm is completely sealed, thus eliminating the loss of low-frequency response resulting from pressure equalization through the release etch-holes present on the diaphragm of a previously reported microphone implemented using a surface-micro-machining process. A dynamic sensitivity of ∼0.33 µV/V/Pa was estimated using an acoustic shockwave (‘N-wave’) generated using a custom-built high-voltage electrical spark-discharge system. This value is comparable to the effective static sensitivity of ∼0.28 µV/V/Pa measured using a commercial nano-indenter system. The response of the microphone is relatively flat from 6 to 500 kHz, with a resonance frequency of ∼715 kHz. An array of three microphones was also constructed and tested to demonstrate the application of these microphones to the localization of high frequency and short duration acoustic sources. (paper)

  20. Bulk Metallic Glass Multiscale Tooling for Molding of Polymers with Micro to Nano Features: A Review

    Science.gov (United States)

    Browne, David J.; Stratton, Dermot; Gilchrist, Michael D.; Byrne, Cormac J.

    2013-05-01

    There is a growing demand for single-use disposable polymer devices with features at submicron scales. This requires resilient tooling which can be patterned to scales of the order of hundreds of nanometers. The requisite topology can be imparted to silicon, but it is too brittle to be of use in a die to mold thousands of plastic parts. The polycrystalline nature of tool steel means that it cannot be patterned with submicron detail. Some bulk amorphous alloys have the requisite mechanical properties to be viable as materials for such dies, and can be patterned— e.g., via embossing as a supercooled liquid into MEMS silicon or using focused ion beam (FIB)—with submicron features which may persevere over many thousands of molding cycles. The composition of the amorphous alloy must be carefully selected to suit the particular molding application (polymer/process). The state-of-the-art methodology is presented, along with results of our recent experimental investigations.

  1. Studies on micro plasto hydrodymic lubrication in metal forming

    DEFF Research Database (Denmark)

    Bay, Niels; Bech, Jakob Ilsted; Andreasen, Jan Lasson; Shimizu, I

    The influence of work piece surface topography on friction and lubrication and final surface quality in metal forming operations is well known and has been pointed out by many researchers, see Schey (1983) and Bay and Wanheim (1990). This is especially the case when liquid lubrication is applied,......, friction and pocket geometry and establishing a mathematical model predicting the onset of lubricant escape. The present paper presents an overview of these studies on MPHDL in metal forming carried out at the Technical University of Denmark....

  2. Influence of Kinetic and Thermodynamic Factors on the Glass-Forming Ability of Zirconium-Based Bulk Amorphous Alloys

    OpenAIRE

    Mukherjee, S.; Schroers, J.; Johnson, W. L.; Rhim, W. K.

    2005-01-01

    The time-temperature-transformation curves for three zirconium-based bulk amorphous alloys are measured to identify the primary factors influencing their glass-forming ability. The melt viscosity is found to have the most pronounced influence on the glass-forming ability compared to other thermodynamic factors. Surprisingly, it is found that the better glass former has a lower crystal-melt interfacial tension. This contradictory finding is explained by the icosahedral short-range order of the...

  3. Deposited Micro Porous Layer as Lubricant Carrier in Metal Forming

    DEFF Research Database (Denmark)

    Arentoft, Mogens; Bay, Niels; Tang, Peter Torben;

    2008-01-01

    A new porous coating for carrying lubricant in metal forming processes is developed. The coating is established by simultaneous electrochemical deposition of two pure metals. One of them is subsequently etched away leaving a porous surface layer. Lubricant can be trapped in the pores acting as lu...

  4. Deposited Micro Porous Layer as Lubricant Carrier in Metal Forming

    DEFF Research Database (Denmark)

    Arentoft, Mogens; Bay, Niels; Tang, Peter Torben; Jensen, Jørgen Dai; Paldan, Nikolas Aulin; Mizushima, Io; Eriksen, Rasmus Solmer

    lubricant reservoirs. Conventional friction tests for cold forming; ring compression and double cup extrusion tests are carried out with Molykote DX paste and mineral oil as lubricant. Both lubricants act as intended for the ring compressions test whereas only the low viscosity oil perform successfully in...

  5. Laser-assisted micro-forming process with miniaturised structures in sapphire dies

    International Nuclear Information System (INIS)

    Current results will be presented on developing and miniaturising a novel laser-assisted forming process to manufacture microstructures in metals such as stainless steel and aluminum. Due to its mechanical and optical properties, sapphire is a well-suited material for the micro-forming tool. Because of its high band gap, radiation with small wavelengths in the UV range is required to reach the ablation threshold. Thus, excimer lasers are used for manufacturing the microstructures. On the other hand, its high transmittance for higher wavelengths allows heating of the work-piece through the sapphire die during the micro-forming process, which allows a better form filling. The main goal of these investigations is to identify the scaling effects on micro-formed structures that result from miniaturising microstructures on dies for the development of strategies to overcome obstacles caused by these miniaturisation effects.

  6. Spectrophotometric methods for the simultaneous estimation of ofloxacin and tinidazole in bulk and pharmaceutical dosage form

    Directory of Open Access Journals (Sweden)

    Kareti Srinivasa Rao

    2011-01-01

    Full Text Available Aim: This work deals with the simultaneous estimation of Ofloxacin (OFL and Tinidazole (TNZ in in bulk and pharmaceutical dosage form, without prior separation, by three different techniques (Simultaneous equation, Absorbance ratio method and First order derivative method. Materials and Methods: The present work was carried out on Shimadzu electron UV1800 double beam UV-Visible spectrophotometer. The absorption spectra of reference and test solutions were carried out in 1 cm matched quartz cell over the range of 200 - 400 nm. Standard gift sample of OFL and TNZ obtain from Torrent pharmaceuticals Ltd., Baddi, Himachal Pradesh. Combined OFL and TNZ tablets were purchased from local market. Methanol from Merck Ltd and distilled water are used as solvent. Results: The first method is the application of simultaneous equation. Where the linearity ranges for OFL and TNZ were 5-30 μg/ml and 10-50 μg/ml respectively. The second method is the determination of ratio of absorbance at 278nm, the maximum absorption of TNZ and isobestic wavelength 283 nm, the linearity ranges for OFL and TNZ were 5-30 μg/ml and 10-50μg/ml respectively. The third method is the first order derivative method, where the linearity ranges for OFL and TNZ were 5-30 μg/ml and 10-50 μg/ml respectively. The results of the analysis have been validated statistically and by recovery studies, where the percentage recovery was found to be 100.9±0.49 and 97.30±0.20 using the simultaneous equation method, 98±0.45 and 100.4±0.48 using the graphical absorbance ratio method and 99.10±0.40 and 84.70±0.70 using first derivative method, for OFL and TNZ respectively. Conclusions: The proposed procedures are rapid, simple, require no preliminary separation steps and can be used for routine analysis of both drugs in quality control laboratories.

  7. Optimization of ISOCS Parameters for Quantitative Non-Destructive Analysis of Uranium in Bulk Form

    Science.gov (United States)

    Kutniy, D.; Vanzha, S.; Mikhaylov, V.; Belkin, F.

    2011-12-01

    and chemical composition of the matrix of the specimen. Obviously, not all parameters can be characterized when measuring samples of unknown composition or uranium in bulk form. Because of this, and especially for uranium materials, the IAEA developed an ISOCS optimization procedure. The target values for the optimization are Μmatrixfixed, the matrix mass determined by weighing with a known mass container, and Εfixed, the 235U enrichment, determined by MGAU. Target values are fitted by varying the matrix density (ρ), and the concentration of uranium in the matrix of the unknown (w). For each (ρi, wi), an efficiency curve is generated, and the masses of uranium isotopes, Μ235Ui and Μ238Ui, determined using spectral activity data and known specific activities for U. Finally, fitted parameters are obtained for Μmatrixi = Μmatrixfixed ± 1σ, Εi = Εfixed ± 1σ, as well as important parameters (ρi, wi, Μ235Ui, Μ238Ui, ΜUi). We examined multiple forms of uranium (powdered, pressed, and scrap UO2 and U3O8) to test this method for its utility in accurately identifying the mass and enrichment of uranium materials, and will present the results of this research.

  8. Precision formed micro magnets: LDRD project summary report

    Energy Technology Data Exchange (ETDEWEB)

    CHRISTENSON,TODD R.; GARINO,TERRY J.; VENTURINI,EUGENE L.

    2000-02-01

    A microfabrication process is described that provides for the batch realization of miniature rare earth based permanent magnets. Prismatic geometry with features as small as 5 microns, thicknesses up through several hundred microns and with submicron tolerances may be accommodated. The processing is based on a molding technique using deep x-ray lithography as a means to generate high aspect-ratio precision molds from PMMA (poly methyl methacrylate) used as an x-ray photoresist. Subsequent molding of rare-earth permanent magnet (REPM) powder combined with a thermosetting plastic binder may take place directly in the PMMA mold. Further approaches generate an alumina form replicated from the PMMA mold that becomes an intermediate mold for pressing higher density REPM material and allows for higher process temperatures. Maximum energy products of 3--8 MGOe (Mega Gauss Oersted, 1 MGOe = 100/4{pi} kJ/m{sup 3}) are obtained for bonded isotropic forms of REPM with dimensions on the scale of 100 microns and up to 23 MGOe for more dense anisotropic REPM material using higher temperature processing. The utility of miniature precision REPMs is revealed by the demonstration of a miniature multipole brushless DC motor that possesses a pole-anisotropic rotor with dimensions that would otherwise prohibit multipole magnetization using a multipole magnetizing fixture at this scale. Subsequent multipole assembly also leads to miniaturized Halbach arrays, efficient magnetic microactuators, and mechanical spring-like elements which can offset miniaturized mechanical scaling behavior.

  9. Determination of azathioprine in bulk and pharmaceutical dosage form by HPTLC

    OpenAIRE

    Jain, Pritam S.; Pradip Thakre; Chaudhari, Amar J.; Chavhan, Manish L.; Surana, Sanjay J.

    2012-01-01

    Introduction: An HPTLC method for analysis of Azathioprine in bulk and pharmaceutical formulation has been established and validated. Materials and Methods: The analyte was separated on aluminium plates precoated with silica gel 60 F254. The mobile phase was Ethyl acetate: Methanol: Triethylamine (4:1:0.5v/v). Quantification was done by densitometric scanning at 300nm. Results: Response was a linear function of Azathioprine concentration in the range of 200-1200 ng/band. The limit of detectio...

  10. Development of micro rotary swaging tools of graded tool steel via co-spray forming

    Directory of Open Access Journals (Sweden)

    Cui Chengsong

    2015-01-01

    Full Text Available In order to meet the requirements of micro rotary swaging, the local properties of the tools should be adjusted properly with respect to abrasive and adhesive wear, compressive strength, and toughness. These properties can be optimally combined by using different materials in specific regions of the tools, with a gradual transition in between to reduce critical stresses at the interface during heat treatment and in the rotary swaging process. In this study, a newly developed co-spray forming process was used to produce graded tool materials in the form of a flat product. The graded deposits were subsequently hot rolled and heat treated to achieve an optimal microstructure and advanced properties. Micro plunge rotary swaging tools with fine geometrical structures were machined from the hot rolled materials. The new forming tools were successfully applied in the micro plunge rotary swaging of wires of stainless steel.

  11. DEVELOPMENT AND VALIDATION OF UV SPECTROPHOTOMETRIC ESTIMATION OF EBASTINE IN BULK AND TABLET DOSAGE FORM USING AREA UNDER CURVE METHOD

    Directory of Open Access Journals (Sweden)

    Dahivadkar Manish Sudhakar

    2013-06-01

    Full Text Available The aim of this work is to develop a simple, accurate, reproducible and cost effective spectrophotometric method for determination of Ebastine in bulk and pharmaceutical dosage form. This method is basedon area under curve (AUC in wavelength range of 247-257nm and method has followed linearity in the concentration range of 5-30μg/ml. Methanol was used as a solvent. The developed analytical method was validated as per International Conference on Harmonization (ICH guidelines. The value of correlation coefficient (R2 was 0.999. Limit of Detection and Limit of Quantitation were calculated as 0.78µg/ml and 2.37µg/ml, respectively. Results of the recovery studies showed good accuracy of the method. Validation results suggest that the developed method can be used for routine quality control studies for assay of Ebastine in bulk and tablet dosage form.

  12. Preparation, glass forming ability, crystallization and deformation of (zirconium, hafnium)-copper-nickel-aluminum-titanium-based bulk metallic glasses

    Science.gov (United States)

    Gu, Xiaofeng

    Multicomponent Zr-based bulk metallic glasses are the most promising metallic glass forming systems. They exhibit great glass forming ability and fascinating mechanical properties, and thus are considered as potential structural materials. One potential application is that they could be replacements of the depleted uranium for making kinetic energy armor-piercing projectiles, but the density of existing Zr-based alloys is too low for this application. Based on the chemical and crystallographic similarities between Zr and Hf, we have developed two series of bulk metallic glasses with compositions of (HfxZr1-x) 52.5Cu17.9Ni14.6Al10Ti5 and (HfxZr1-x) 57Cu20Ni8Al10Ti5 ( x = 0--1) by gradually replacing Zr by Hf. Remarkably increased density and improved mechanical properties have been achieved in these alloys. In these glasses, Hf and Zr play an interchangeable role in determining the short range order. Although the glass forming ability decreases continuously with Hf addition, most of these alloys remain bulk glass-forming. Recently, nanocomposites produced from bulk metallic glasses have attracted wide attention due to improved mechanical properties. However, their crystalline microstructure (the grain size and the crystalline volume fraction) has to be optimized. We have investigated crystallization of (Zr, Hf)-based bulk metallic glasses, including the composition dependence of crystallization paths and crystallization mechanisms. Our results indicate that the formation of high number density nanocomposites from bulk metallic glasses can be attributed to easy nucleation and slowing-down growth processes, while the multistage crystallization behavior makes it more convenient to control the microstructure evolution. Metallic glasses are known to exhibit unique plastic deformation behavior. At low temperature and high stress, plastic flow is localized in narrow shear bands. Macroscopic investigations of shear bands (e.g., chemical etching) suggest that the internal

  13. Enhancement of glass-forming ability and mechanical behavior of zirconium–lanthanide two-phase bulk metallic glasses

    International Nuclear Information System (INIS)

    Highlights: • This work provides a new concept for design of two-phase BMGs. • The formation of two-glass structure in two-liquid systems is analyzed. • A strategy for improving GFA of two-phase metallic glasses is proposed. • A family of two-phase metallic glasses in bulk form is developed. • The mechanical behavior of two-phase BMGs is studied for the first time. - Abstract: Development of the two-phase bulk metallic glasses (BMGs) is essentially retarded due to difficulties in finding of phase-separated (immiscible) alloys with high glass-forming ability (GFA) of coexistent phases. Referring to the concept of solute partitioning and minimization of free energy, in this work we present an idea that a metallic liquid system containing two liquids with individual self-assembled eutectic composition may yield two-phase BMGs upon casting. The formation of the two-glass structure is discussed and a strategy of partial substitution of chemically similar elements for overcoming the drawback of low GFA is proposed. A family of two-phase zirconium–lanthanide based metallic glasses in bulk form is developed. The mechanical behavior of the two-phase BMGs with different ratio of zirconium-rich to lanthanide-rich glassy phase is studied for the first time. This work provides a new concept for fabrication of two-phase BMGs and reveals the role of constituent phases in determining the mechanical properties of the whole glass

  14. Crystallization behavior of Fe- and Co-based bulk metallic glasses and their glass-forming ability

    International Nuclear Information System (INIS)

    In the present work we study and compare the crystallization behavior of Fe- and Co-based good bulk glass formers with an exceptionally high glass-forming ability leading to the critical thickness of cast samples reaching 1 cm. For Fe-based alloys we also investigate the effect of opposite C/B content ratio on the glass-forming ability and the crystallization behavior. The structure and phase composition of the glassy samples were examined by conventional X-ray diffractometry and transmission electron microscopy while thermal stability and phase transformations were studied by differential scanning calorimetry. The reasons for high glass-forming ability are discussed. The glass-forming ability of the studied alloys depends on both factors: the type of crystallization reaction and characteristic temperatures. - Highlights: • Crystallization of Fe-based and Co-based bulk glass-forming alloys. • The reasons for enhanced glass-forming ability of these alloys are discussed. • Low growth rate of χ-Fe36Cr12Mo10 phase. • Reduced liquidus temperature of Fe48Cr15Mo14C6B15RE2 alloys

  15. SPECTROPHOTOMETRIC ESTIMATION OF MONTELUKAST FROM BULK DRUG AND TABLET DOSAGE FORM

    Directory of Open Access Journals (Sweden)

    S.R. Bhagade

    2013-11-01

    Full Text Available Two Simple, accurate, precise and sensitive spectrophotometric methods for estimation of Montelukast sodium (MON have been developed and validated. The zero order spectroscopic method (Method I and area under curve method (Method II have developed. The proposed methods are validated according to ICH Q2B guidelines. The Montelukast sodium gives maximum absorbance at 241nm in chloroform and observed linearity 2-20 μg/ml for zero order method and 4-20 μg/ml for area under curve method. The stability of drug in chloroform has been studied and drug shows good stability in Chloroform. The recovery by method I and method II are 99.52 ± 0.069, 101.93± 0.11 respectively. The both spectrophotometric methods can be applied for routine analysis of Montelukast sodium in tablet formulation and in bulk drug.

  16. Influence of Si on glass forming ability and properties of the bulk amorphous alloy Mg60Cu30Y10

    International Nuclear Information System (INIS)

    Research highlights: → The partial substitution of Cu by the right amount of Si increases the glass forming ability of the bulk amorphous alloy Mg60Cu30Y10. → The serrations size of Mg60Cu30-xY10Six is dependent on the content of Si. → The creep displacement of Mg60Cu30-xY10Six alloys decrease with increasing Si content. → The elastic modulus and nano-hardness of Mg60Cu30-xY10Six are dependent on the Si content. - Abstract: We studied the influence of partially replacing Cu by Si in the bulk amorphous alloy Mg30Cu30Y10. Glass forming ability (GFA), examined using X-ray diffraction and a differential scanning calorimeter, was increased at 1% Si, but decreased for larger Si concentrations. Nano-indentation measured nano-hardness, elastic modulus and load-displacement curves. The elastic modulus and nano-hardness increased with increasing Si content to a maximum at 2.5%. The load-displacement curves during nano-indentation revealed displacement serrations. These increased with decreasing loading rates, decreased with increasing Si content. The load-displacement curves also indicated that these bulk amorphous alloys exhibited primary creep at room temperature just like other high strength alloys. The creep displacement decreased with increasing Si content.

  17. Environmental correlates of cycling: Evaluating urban form and location effects based on Danish micro-data

    DEFF Research Database (Denmark)

    Nielsen, Thomas Alexander Sick; Olafsson, Anton Stahl; Carstensen, Trine Agervig;

    2013-01-01

    The paper analyses the environmental correlates of cycling based on Danish transportation and urban form micro-data. The results show that established walkability factors such as density, connectivity and diversity are related to cycling, but access to retail concentrations/centres, public transp...

  18. An automatic form error evaluation method for characterizing micro-structured surfaces

    Science.gov (United States)

    Yu, D. P.; Zhong, X.; Wong, Y. S.; Hong, G. S.; Lu, W. F.; Cheng, H. L.

    2011-01-01

    Ultra-precision micro-structured surfaces are becoming increasingly important in a range of application areas, including engineering optics, biological products, metrology artifacts, data storage, etc. However, there is a lack of surface characterization methods for the micro-structured surfaces with sub-nanometer accuracy. Although some research studies have been conducted on 3D surface characterization, most of them are on freeform surfaces, which are difficult to be applied on the micro-structured surfaces because of their limited characterization accuracy and the repeated surface feature patterns in the micro-structured surfaces. In this paper, an automatic form error evaluation method (AFEEM) is presented to characterize the form accuracy of the micro-structured surfaces. The machined micro-structured surface can be measured by any 3D high resolution measurement instrument. The measurement data are converted and pre-processed for the AFEEM, which mainly consists of a coarse registration and a fine registration process. The coarse registration estimates an initial position of the measured surface for the fine registration by extracting the most perceptually salient points in the surfaces, computing the integral volume descriptor for each salient point, searching for the best triplet-point correspondence and calculating the coarse registration matrix. The fine registration aligns the measured surface to the designed surface by a proposed adaptive iterative closest point algorithm to guarantee sub-nanometer accuracy for surface characterization. A series of computer simulations and experimental studies were conducted to verify the AFEEM. Results demonstrate the accuracy and effectiveness of the AFEEM for characterizing the micro-structured surfaces.

  19. An automatic form error evaluation method for characterizing micro-structured surfaces

    International Nuclear Information System (INIS)

    Ultra-precision micro-structured surfaces are becoming increasingly important in a range of application areas, including engineering optics, biological products, metrology artifacts, data storage, etc. However, there is a lack of surface characterization methods for the micro-structured surfaces with sub-nanometer accuracy. Although some research studies have been conducted on 3D surface characterization, most of them are on freeform surfaces, which are difficult to be applied on the micro-structured surfaces because of their limited characterization accuracy and the repeated surface feature patterns in the micro-structured surfaces. In this paper, an automatic form error evaluation method (AFEEM) is presented to characterize the form accuracy of the micro-structured surfaces. The machined micro-structured surface can be measured by any 3D high resolution measurement instrument. The measurement data are converted and pre-processed for the AFEEM, which mainly consists of a coarse registration and a fine registration process. The coarse registration estimates an initial position of the measured surface for the fine registration by extracting the most perceptually salient points in the surfaces, computing the integral volume descriptor for each salient point, searching for the best triplet-point correspondence and calculating the coarse registration matrix. The fine registration aligns the measured surface to the designed surface by a proposed adaptive iterative closest point algorithm to guarantee sub-nanometer accuracy for surface characterization. A series of computer simulations and experimental studies were conducted to verify the AFEEM. Results demonstrate the accuracy and effectiveness of the AFEEM for characterizing the micro-structured surfaces

  20. Co-based soft magnetic bulk glassy alloys optimized for glass-forming ability and plasticity

    Indian Academy of Sciences (India)

    LI LI; HUAIJUN SUN; YUNZHANG FANG; JIANLONG ZHENG

    2016-06-01

    Co-based bulk glassy alloys (BGAs) have become more and more important because of their nearly zero magnetostriction and high giant magneto-impedance effect. Here, we report the improvement of glass-formingability (GFA), soft-magnetic properties and plasticity by a small addition of Mo atoms in CoFeBSiNbMo BGAs.(Co$_{0.6}$Fe$_{0.4}$)$_{69}$B$_{20.8}$Si$_{5.2}$Nb$_{5−x}$Mo$_{x}$ ferromagnetic BGA cylindrical glassy rods were fabricated successfully with adiameter of 5 mm by conventional copper mould casting method. It reveals that the substitution of a small amount of Mo for Nb makes the composition to approach a eutectic point and effectively enhances the GFA of alloy. Inaddition to high GFA and superhigh strength, the compressive test shows that the Mo addition can improve the plasticity for the obtained BGAs. The combination of high GFA, excellent soft-magnetic properties and good plasticitydemonstrated in our alloys is promising for the future applications as functional materials.

  1. Structure and properties of cerium oxides in bulk and nanoparticulate forms

    Energy Technology Data Exchange (ETDEWEB)

    Gangopadhyay, Shruba [NanoScience Technology Center, University of Central Florida, 12424 Research Parkway, Suite 400, Orlando, FL 32826 (United States); Department of Chemistry, University of Central Florida, 4111 Libra Drive, PS 255, Orlando, FL 32826 (United States); Frolov, Dmitry D. [NanoScience Technology Center, University of Central Florida, 12424 Research Parkway, Suite 400, Orlando, FL 32826 (United States); Department of Chemistry, Moscow M.V. Lomonosov State University, Leninskiye Gory, Moscow 119991 (Russian Federation); Masunov, Artëm E., E-mail: amasunov@ucf.edu [NanoScience Technology Center, University of Central Florida, 12424 Research Parkway, Suite 400, Orlando, FL 32826 (United States); Department of Chemistry, University of Central Florida, 4111 Libra Drive, PS 255, Orlando, FL 32826 (United States); Department of Physics, University of Central Florida, 4111 Libra Drive, PS 430, Orlando, FL 32826 (United States); Seal, Sudipta [Advanced Materials Processing and Analysis Center, University of Central Florida, 12760 Pegasus Drive, ENG1 381, Orlando, FL 32816 (United States); Department of Materials Science and Engineering, University of Central Florida, 12760 Pegasus Drive, ENG1 207, FL 32816 (United States); College of Medicine, University of Central Florida, 6850 Lake Nona Blvd, Orlando, FL 32827 (United States); NanoScience Technology Center, University of Central Florida, 12424 Research Parkway, Suite 400, Orlando, FL 32826 (United States)

    2014-01-25

    The experimental and computational studies on the cerium oxide nanoparticles, as well as stoichiometric phases of bulk ceria are reviewed. Based on structural similarities of these phases in hexagonal aspect, electroneutral and non-polar pentalayers are identified as building blocks of type A sesquioxide structure. The idealized core/shell structure of the ceria nanoparticles is described as dioxide core covered by a single pentalayer of sesquioxide, which explains the exceptional stability of subsurface vacancies in nanoceria. The density functional theory (DFT) predictions of the lattice parameters and elastic moduli for the Ce(IV) and Ce(III) oxides at the hybrid DFT level are also presented. The calculated values for both compounds agree with available experimental data and allow predicting changes in the lattice parameter with decreasing size of the nanoparticles. The lattice parameter is calculated as equilibrium between contraction of sesquioxide structure in the core, and expansion of dioxide structure in the shell of the nanoparticle. This is consistent with available XRD data on ceria NPs obtained in mild aqueous conditions. The core/shell model, however, breaks down when applied to the size dependence of lattice parameter in NPs obtained by the laser ablation techniques.

  2. Structure and properties of cerium oxides in bulk and nanoparticulate forms

    International Nuclear Information System (INIS)

    The experimental and computational studies on the cerium oxide nanoparticles, as well as stoichiometric phases of bulk ceria are reviewed. Based on structural similarities of these phases in hexagonal aspect, electroneutral and non-polar pentalayers are identified as building blocks of type A sesquioxide structure. The idealized core/shell structure of the ceria nanoparticles is described as dioxide core covered by a single pentalayer of sesquioxide, which explains the exceptional stability of subsurface vacancies in nanoceria. The density functional theory (DFT) predictions of the lattice parameters and elastic moduli for the Ce(IV) and Ce(III) oxides at the hybrid DFT level are also presented. The calculated values for both compounds agree with available experimental data and allow predicting changes in the lattice parameter with decreasing size of the nanoparticles. The lattice parameter is calculated as equilibrium between contraction of sesquioxide structure in the core, and expansion of dioxide structure in the shell of the nanoparticle. This is consistent with available XRD data on ceria NPs obtained in mild aqueous conditions. The core/shell model, however, breaks down when applied to the size dependence of lattice parameter in NPs obtained by the laser ablation techniques

  3. Poincare-Einstein Holography for Forms via Conformal Geometry in the Bulk

    CERN Document Server

    Latini, Emanuele; Waldron, Andrew

    2012-01-01

    We study higher form Proca equations on Einstein manifolds with boundary data along conformal infinity. We solve these Laplace-type boundary problems formally, and to all orders, by constructing an operator which projects arbitrary forms to solutions. We also develop a product formula for solving these asymptotic problems in general. The central tools of our approach are (i) the conformal geometry of differential forms and the associated exterior tractor calculus, and (ii) a generalised notion of scale which encodes the connection between the underlying geometry and its boundary. The latter also controls the breaking of conformal invariance in a very strict way by coupling conformally invariant equations to the scale tractor associated with the generalised scale. From this, we obtain a map from existing solutions to new ones that exchanges Dirichlet and Neumann boundary conditions. Together, the scale tractor and exterior structure extend the solution generating algebra of [31] to a conformally invariant, Poi...

  4. Influence of carbonization conditions on micro-pore structure of foundry formed coke produced with char

    Energy Technology Data Exchange (ETDEWEB)

    Jun Qiao; Jianjun Wu; Jingru Zu; Zhiyuan Gao; Guoli Zhou

    2009-07-01

    There are few studies on coke's micro-pore structure in recent years, however, micro-pore structure of foundry coke determines its macroscopically quality index and reactivity in cupola furnace. Effect of such factors on micro-pore structure were investigated under different carbonization conditions with certain ratio of raw materials and material forming process in this article as charging temperature (A); braised furnace time (B); heating rate of the first stage (C)and the second stage (D) and holding time of ultimate temperature (E). Research showed that charging temperature was the most influential factor on the coke porosity, pore volume, pore size and specific surface area. It is suggested that formation of plastic mass and releasing rate of volatile during carbonization period are two main factors on microstructure of foundry coke while charging temperature contributes most to the above factors. 6 refs., 4 figs., 9 tabs.

  5. Novel LC Method Development and Validation for Simultaneous Determination of Montelukast and Doxofylline in Bulk and Pharmaceutical Dosage Forms

    OpenAIRE

    Gadapa Nirupa; A Siva Kumar; Upendra M. Tripathi

    2013-01-01

    A novel rapid HPLC method was developed for simultaneous determination of montelukast and doxofylline in bulk and pharmaceutical dosage forms. Development of an analytical method for simultaneous estimation of drugs requires a lot of efforts and of course it is a challenging task. The method was developed by using C18 (150 mm×4.6 mm, 5 μm) column; mobile phase consisting of methanol and phosphate buffer at pH 4.5; the flow rate of 1.0 mL/min and ultraviolet detection at 280 nm. Both drugs wer...

  6. STABILITY INDICATING RP-LC METHOD FOR DETERMINATION OF RASAGILINE MESYLATE IN BULK AND PHARMACEUTICAL DOSAGE FORMS

    OpenAIRE

    R. Narendra Kumar; G. Nageswara Rao; P.Y. Naidu

    2010-01-01

    An isocratic stability indicating liquid chromatographic method has been developed and validated for the determination of Rasagiline in bulk drug and its pharmaceutical dosage forms. Separation of the drug with degradation products was achieved using Puroshere Star, C18, 150 x 4.6mm; 5μm column as stationary phase and pH 7.0(±0.05) buffer: Acetonitrile (40:60,v/v) as mobile phase at a flow rate of 1.0 mL/min. UV detection was performed at 210 nm. The method is linear over the range of 4.8 – 1...

  7. Simultaneous Estimation of Ibuprofen and Phenylephrine Hydrochloride in Bulk and Combined Dosage Form by First Derivative UV Spectrophotometry Method

    OpenAIRE

    Mehul Patel; Bhavna Patel; Shraddha Parmar

    2013-01-01

    A simple, precise, rapid, and economic method was developed for the simultaneous determination of Ibuprofen and Phenylephrine HCl in bulk and combined dosage form. This method involves first-order derivative spectroscopy using 248 nm and 237 nm as zero crossing points for Ibuprofen and Phenylephrine HCl, respectively. For spectrophotometric method 0.1 N NaOH was used as a solvent. The linearity was established over the concentration range of 12–72 μg/mL and 1.5–22 μg/mL for Ibuprofen and Phen...

  8. Simple and sensitive spectrophotometric methods for the analysis of mesalamine in bulk and tablet dosage forms

    Directory of Open Access Journals (Sweden)

    Bala Sekaran Chandra

    2011-01-01

    Full Text Available Three simple, sensitive, economical and reproducible spectrophotometric methods (A, B and C are described for determination of mesalamine in pure drug as well as in tablet dosage forms. Method A is based on the reduction of tungstate and/or molybdate in Folin Ciocalteu's reagent; method B describes the reaction between the diazotized drug and α-naphthol and method C is based on the reaction of the drug with vanillin, in acidic medium. Under optimum conditions, mesalamine could be quantified in the concentration ranges, 1-30, 1-15 and 2-30 µg mL-1 by method A, B and C, respectively. All the methods have been applied to the determination of mesalamine in tablet dosage forms. Results of analysis are validated statistically.

  9. Molecular dynamics study of the ternary Cu50Ti25Zr25 bulk glass forming alloy

    Directory of Open Access Journals (Sweden)

    Celtek M.

    2011-05-01

    Full Text Available The structure and thermodynamic properties of a ternary Cu50Ti25Zr25 metallic glass forming alloy in solid-liquid to glass phases were studied using molecular dynamics (MD method based on tight-binding (TB potentials. An atomic description of the melting, glass formation and crystallization process has been analyzed using different heating and cooling rates. The computed Glass Forming Ability (GFA parameters are in good agreement with experimental data. The structure analysis of the Cu50Ti25Zr25 based on molecular dynamics simulation will be also presented and compared with available MD results. We have also discussed the crystallization transition with two different interatomic potentials used in this work

  10. A Stability Indicating U-HPLC Method for Milnacipran in Bulk Drugs and Pharmaceutical Dosage Forms

    OpenAIRE

    K.V. Surendranath; Shakil S. Sait; Naresh Tondepu; Ravi Kiran Kaja; Suresh Kumar

    2012-01-01

    The objective of the current study was to develop a validated, specific and stability-indicating reverse phase UHPLC method for the quantitative determination of Milnacipran and its related substances. The determination was done for active pharmaceutical ingredient and its pharmaceutical dosage forms in the presence of degradation products, and its process-related impurities. The drug was subjected to stress conditions of hydrolysis (acid and base), oxidation, pho- tolysis and thermal degrada...

  11. Visible Spectrophotometric Estimation of Diacerein in Bulk and Pharmaceutical Dosage Forms

    OpenAIRE

    R. Sivakumar; Nallasivan, PK; Saranya, KC; Sam, Solomon WD; T Akelesh; Venkatnarayanan, R.

    2010-01-01

    Two simple, sensitive, accurate, rapid, and economical spectrophotometric methods have been developed for the estimation of diacerein in Pharmaceutical dosage forms. Method A is based on the reaction of diacerein with Folin-Ciocalteu reagent, in the presence of 0.5 N sodium hydroxide solution, giving a pink-colored chromogen, which shows maximum absorbance at 512 nm against reagent blank, while method B is based on the oxidation of diacerein with potassium permanganate in an alkaline medium g...

  12. STABILITY INDICATING RP-LC METHOD FOR DETERMINATION OF RASAGILINE MESYLATE IN BULK AND PHARMACEUTICAL DOSAGE FORMS

    Directory of Open Access Journals (Sweden)

    R. Narendra Kumar

    2010-10-01

    Full Text Available An isocratic stability indicating liquid chromatographic method has been developed and validated for the determination of Rasagiline in bulk drug and its pharmaceutical dosage forms. Separation of the drug with degradation products was achieved using Puroshere Star, C18, 150 x 4.6mm; 5μm column as stationary phase and pH 7.0(±0.05 buffer: Acetonitrile (40:60,v/v as mobile phase at a flow rate of 1.0 mL/min. UV detection was performed at 210 nm. The method is linear over the range of 4.8 – 150.5 μg/mL. The percent recovery of drug in dosage forms was ranged from 98.0 to 102.1. The method is simple, rapid, precise, selective and stability indicating and can be used for the assay in quality control and stability studies samples.

  13. MicroRNAs Form Triplexes with Double Stranded DNA at Sequence-Specific Binding Sites; a Eukaryotic Mechanism via which microRNAs Could Directly Alter Gene Expression.

    Directory of Open Access Journals (Sweden)

    Steven W Paugh

    2016-02-01

    Full Text Available MicroRNAs are important regulators of gene expression, acting primarily by binding to sequence-specific locations on already transcribed messenger RNAs (mRNA and typically down-regulating their stability or translation. Recent studies indicate that microRNAs may also play a role in up-regulating mRNA transcription levels, although a definitive mechanism has not been established. Double-helical DNA is capable of forming triple-helical structures through Hoogsteen and reverse Hoogsteen interactions in the major groove of the duplex, and we show physical evidence (i.e., NMR, FRET, SPR that purine or pyrimidine-rich microRNAs of appropriate length and sequence form triple-helical structures with purine-rich sequences of duplex DNA, and identify microRNA sequences that favor triplex formation. We developed an algorithm (Trident to search genome-wide for potential triplex-forming sites and show that several mammalian and non-mammalian genomes are enriched for strong microRNA triplex binding sites. We show that those genes containing sequences favoring microRNA triplex formation are markedly enriched (3.3 fold, p<2.2 × 10(-16 for genes whose expression is positively correlated with expression of microRNAs targeting triplex binding sequences. This work has thus revealed a new mechanism by which microRNAs could interact with gene promoter regions to modify gene transcription.

  14. Visible spectrophotometric estimation of diacerein in bulk and pharmaceutical dosage forms.

    Science.gov (United States)

    Sivakumar, R; Nallasivan, Pk; Saranya, Kc; Sam, Solomon Wd; Akelesh, T; Venkatnarayanan, R

    2010-10-01

    Two simple, sensitive, accurate, rapid, and economical spectrophotometric methods have been developed for the estimation of diacerein in Pharmaceutical dosage forms. Method A is based on the reaction of diacerein with Folin-Ciocalteu reagent, in the presence of 0.5 N sodium hydroxide solution, giving a pink-colored chromogen, which shows maximum absorbance at 512 nm against reagent blank, while method B is based on the oxidation of diacerein with potassium permanganate in an alkaline medium giving a pink-colored chromogen, which shows maximum absorption at 497.5 nm. Beer's law was obeyed in the concentration range of 4 - 20 µg/ml for both methods A and B. Results of the analysis were validated statistically, and by recovery studies. PMID:21264105

  15. Numerical determination of micro-forming limit diagrams: introduction of the effect of grain size heterogeneity

    International Nuclear Information System (INIS)

    This paper presents the determination of virtual micro-forming limit diagrams by a behaviour law adapted to thin materials introducing the effect of microstructure heterogeneity. The observed size effect, i.e. the decrease in flow stress when the grain size increased, was modelled by a specific phenomenological behaviour law. A reduced numerical simulation by a finite element method rendered it possible to carry out very fast simulations of the different modes of deformation and to determine the virtual micro-forming limit diagrams from the onset of necking. This methodology was compared with experimental results on aluminium 1050A (99.5%) of thickness 0.2 mm. The comparison of the experimental and numerical data demonstrated good agreement between the real and virtual results obtained by such a methodology. (paper)

  16. Super-plastic forming process of Zr-based bulk metallic glass%Zr基非晶合金超塑性成形工艺研究

    Institute of Scientific and Technical Information of China (English)

    廖广兰; 王俊; 喻强; 朱志靖

    2011-01-01

    采用感应耦合等离子体刻蚀工艺制备了微型硅模具,基于硅模具研究了非晶合金Zr41.25Ti13.75Ni10Cu12.5Be22.5的超塑性微零件成形工艺.采用差示扫描量热仪测定了Zr41.25Ti13.75Ni10Cu12.5Be22.5的过冷液相区间为360~440℃,在过冷液相区间热压成形非晶合金微零件、机械研磨去除零件飞边和采用40%的KOH溶液腐蚀去除硅模具,得到非晶合金微型零件.自主研制了成形设备,仿真分析与实验相结合,解决了成形过程中设备的温度控制问题,比较分析了不同温度下的成形结果,实验与仿真结果符合较好.在410℃条件下成功制备出模数0.03、齿数66和厚度500μm的微型内齿轮,齿形轮廓清晰,X射线衍射仪扫描结果显示该微齿轮为非晶结构,从而验证了采用该工艺制备微型零件的可行性.%Super-plastic micro-forming process of bulk metallic glasses Zr41.25Ti13.75Ni10Cu12.5Be22.5 utilizing micro silicon molds was investigated,where the micro silicon molds were fabricated by inductively coupled plasma etching.The super-cooled liquid region,360~440 ℃,was measured by differential scanning calorimeter.Micro components were thermoformed in the super-cooled liquid region.The flash of micro components was removed by mechanical grinding,and the silicon molds were resolved with 40% KOH.Forming equipment was developed on the basis of the super-plastic process,and the temperature-control was solved by simulation analysis and experiments.Subsequently,the forming results in different temperatures were analyzed,which confirmed the simulation results.Finally,an internal gear with 0.03 module,66 teeth and 500 μm thickness was obtained with good dimensional accuracy at 410 ℃.The gear had a relatively good profile with an amorphous structure proved by X-ray diffraction scanning,which substantiated the feasibility of the process.

  17. Development of micro rotary swaging tools of graded tool steel via co-spray forming

    OpenAIRE

    Cui Chengsong; Schulz Alwin; Moumi Eric; Kuhfuss Bernd; Böhmermann Florian; Riemer Oltmann

    2015-01-01

    In order to meet the requirements of micro rotary swaging, the local properties of the tools should be adjusted properly with respect to abrasive and adhesive wear, compressive strength, and toughness. These properties can be optimally combined by using different materials in specific regions of the tools, with a gradual transition in between to reduce critical stresses at the interface during heat treatment and in the rotary swaging process. In this study, a newly developed co-spray forming ...

  18. Evaluating urban form and location effects on cycling based on Danish micro-data.

    OpenAIRE

    Nielsen, Thomas Alexander Sick; Olafsson, Anton Stahl; Carstensen, Trine Agervig; Skov-Petersen, Hans

    2012-01-01

    Extended abstract The paper analyses the environmental correlates of cycling based on Danish transportation and urban form micro-data. Established walkability factors such as density, connectivity and diversity are related to cycling, but access to retail concentrations/centers, public transportation level-of-service, as well a competition between walking and cycling depending on environmental features can be added Attractive conditions for using public transportation or walking relate to les...

  19. Exploring the Micro-Structure of the Proton from Form Factors to DVCS

    CERN Document Server

    Ralston, J P; Ralston, John P.; Jain, Pankaj

    2002-01-01

    For a long time people made the mistake of thinking the proton was understood. New experiments, ranging from form factors to deeply virtual Compton scattering, promise a new era of highly informative studies. Among the controversial topics of the future may be such basic features as the physical size of the proton, the role of quark orbital angular momentum, and the possibility of making "femto-photographic" images of hadronic micro-structure.

  20. Exploring the Micro-Structure of the Proton: from Form Factors to DVCS

    OpenAIRE

    Ralston, John P.; Jain, Pankaj

    2002-01-01

    For a long time people made the mistake of thinking the proton was understood. New experiments, ranging from form factors to deeply virtual Compton scattering, promise a new era of highly informative studies. Among the controversial topics of the future may be such basic features as the physical size of the proton, the role of quark orbital angular momentum, and the possibility of making "femto-photographic" images of hadronic micro-structure.

  1. Exploring the Micro-Structure of the Proton:. from Form Factors to Dvcs

    Science.gov (United States)

    Ralston, John P.; Jain, Pankaj

    2003-01-01

    For a long time people made the mistake of thinking the proton was understood. New experiments, ranging from form factors to deeply virtual Compton scattering, promise a new era of highly informative studies. Among the controversial topics of the future may be such basic features as the physical size of the proton, the role of quark orbital angular momentum, and the possibility of making "femto-photographic" images of hadronic micro-structure.

  2. Mechanical and physical simulation of complex 3-D bulk forming processes with Forge3

    International Nuclear Information System (INIS)

    To-day there is a growing need to predict numerically not only the mechanical parameters, but also the final microstructure of the work-piece. On the other hand, the use of simulation codes to analyze complex laboratory experiments can be viewed as a powerful way to improve the analysis of physical data. We outline basic methods for developing a finite element model of unsteady metal forming processes. At first the thermal and mechanical equations are recalled with several integral formulations. The most important issues are discussed, including time integration, evolving contact with rigid or deformable tools, meshing, remeshing, and parallel computing. Physical coupling is presented with the two possible approaches: introduction of internal parameters describing the evolution of microstructure and coupling with constitutive equations; multi-scale computation illustrated by the texture prediction. Finally it is shown that the inverse approach can be successfully applied to improve parameters identification from data acquisition of laboratory tests, or possibly from industrial experiments. This methodology can be utilized for: constitutive modeling, friction behavior, or even for internal parameters laws describing physical evolution. (author)

  3. Preparation and characterization of Fe-based bulk metallic glasses in plate form

    International Nuclear Information System (INIS)

    Amorphous alloys with composition (at%) Fe48Cr15Mo14C15B6Gd2 (alloy A) and Fe48Cr15Mo14C15B6Y2 (alloy B) were prepared either using pure elements (A and B1) and a commercial AISI430 steel as a base material (B2). When prepared from pure elements both alloys (A and B1) could be cast in plate form with a fixed thickness of 2 mm and variable lengths between 10 and 20 mm by means of copper-mold injection in air atmosphere. In the case of alloy B2, prepared using commercial grade raw materials, rods of 2 mm diameter were obtained. X-ray diffraction and scanning electron microscopy observations confirmed that an amorphous structure was obtained in all the as-cast samples. A minor fraction of crystalline phases (oxides and carbides) was detected on the as-cast surface. Differential scanning calorimetry measurements showed a glass transition temperature at 856 K for alloy A and 841 K for alloy B1, and an onset crystallization temperature of 887 K for alloy A and 885 K for alloy B1. In the case of alloy B2 a slightly different crystallization sequence was observed. Values of hardness (∼13 GPa) and the Young modulus (∼180 GPa) were measured by nanoindentation for both the alloys. The effects of adverse casting conditions (such as air atmosphere, non-conventional injection copper mold casting and partial replacement of pure elements with commercial grade raw materials) on the glass formation and properties of the alloy are discussed.

  4. Preparation and characterization of Fe-based bulk metallic glasses in plate form

    Science.gov (United States)

    Lavorato, G. C.; Fiore, G.; Castellero, A.; Baricco, M.; Moya, J. A.

    2012-08-01

    Amorphous alloys with composition (at%) Fe48Cr15Mo14C15B6Gd2 (alloy A) and Fe48Cr15Mo14C15B6Y2 (alloy B) were prepared either using pure elements (A and B1) and a commercial AISI430 steel as a base material (B2). When prepared from pure elements both alloys (A and B1) could be cast in plate form with a fixed thickness of 2 mm and variable lengths between 10 and 20 mm by means of copper-mold injection in air atmosphere. In the case of alloy B2, prepared using commercial grade raw materials, rods of 2 mm diameter were obtained. X-ray diffraction and scanning electron microscopy observations confirmed that an amorphous structure was obtained in all the as-cast samples. A minor fraction of crystalline phases (oxides and carbides) was detected on the as-cast surface. Differential scanning calorimetry measurements showed a glass transition temperature at 856 K for alloy A and 841 K for alloy B1, and an onset crystallization temperature of 887 K for alloy A and 885 K for alloy B1. In the case of alloy B2 a slightly different crystallization sequence was observed. Values of hardness (∼13 GPa) and the Young modulus (∼180 GPa) were measured by nanoindentation for both the alloys. The effects of adverse casting conditions (such as air atmosphere, non-conventional injection copper mold casting and partial replacement of pure elements with commercial grade raw materials) on the glass formation and properties of the alloy are discussed.

  5. Preparation and characterization of Fe-based bulk metallic glasses in plate form

    Energy Technology Data Exchange (ETDEWEB)

    Lavorato, G.C. [INTECIN (FIUBA-CONICET), Paseo Colon 850, Capital Federal (Argentina); Dipartimento di Chimica IFM and NIS, Universita di Torino, Torino (Italy); Fiore, G.; Castellero, A.; Baricco, M. [Dipartimento di Chimica IFM and NIS, Universita di Torino, Torino (Italy); Moya, J.A., E-mail: jmoya.fi.uba@gmail.com [IESIING, Facultad de Ingenieria e Informatica, UCASAL, Salta (Argentina); CONICET (Argentina)

    2012-08-15

    Amorphous alloys with composition (at%) Fe{sub 48}Cr{sub 15}Mo{sub 14}C{sub 15}B{sub 6}Gd{sub 2} (alloy A) and Fe{sub 48}Cr{sub 15}Mo{sub 14}C{sub 15}B{sub 6}Y{sub 2} (alloy B) were prepared either using pure elements (A and B1) and a commercial AISI430 steel as a base material (B2). When prepared from pure elements both alloys (A and B1) could be cast in plate form with a fixed thickness of 2 mm and variable lengths between 10 and 20 mm by means of copper-mold injection in air atmosphere. In the case of alloy B2, prepared using commercial grade raw materials, rods of 2 mm diameter were obtained. X-ray diffraction and scanning electron microscopy observations confirmed that an amorphous structure was obtained in all the as-cast samples. A minor fraction of crystalline phases (oxides and carbides) was detected on the as-cast surface. Differential scanning calorimetry measurements showed a glass transition temperature at 856 K for alloy A and 841 K for alloy B1, and an onset crystallization temperature of 887 K for alloy A and 885 K for alloy B1. In the case of alloy B2 a slightly different crystallization sequence was observed. Values of hardness ({approx}13 GPa) and the Young modulus ({approx}180 GPa) were measured by nanoindentation for both the alloys. The effects of adverse casting conditions (such as air atmosphere, non-conventional injection copper mold casting and partial replacement of pure elements with commercial grade raw materials) on the glass formation and properties of the alloy are discussed.

  6. Viscosity properties and strong liquid behavior of Pr60Ni25Al15 bulk metallic glass-forming liquids

    Institute of Scientific and Technical Information of China (English)

    WANG Dan; ZHANG Di; WANG ShuYing; NING QianYan; ZHENG CaiPing; YAN Yuan; LIU Jia; SUN MinHua

    2008-01-01

    Pr60Ni25Al15 bulk metallic glass in a cuboid form with dimensions of 2 mm×2 mm×55 mm by copper mold casting method was cast.The dynamic viscosity near the glass transition region for Pr60Ni25Al15 was measured by three-point beam bending methods.The fragility parameter m and activation energy for viscous flow of the liquid sample were calculated to be: m = 31.66, E= 10689.17 K, respectively.It was shown that the supercooled liquid of Pr60Ni25Al15 alloy behaved much closer to strong glasses.The variation of active energy with temperature in supercooled liquid was analyzed.It was found that Kivelson's super-Arrhenius equation is not suitable for description of the activation energy in a supercooled region of Bulk metallic glass, and there is a direct proportion between activation energy crystal-lization and activation energy of viscous flow.

  7. MicroRNAs Form Triplexes with Double Stranded DNA at Sequence-Specific Binding Sites; a Eukaryotic Mechanism via which microRNAs Could Directly Alter Gene Expression.

    Science.gov (United States)

    Paugh, Steven W; Coss, David R; Bao, Ju; Laudermilk, Lucas T; Grace, Christy R; Ferreira, Antonio M; Waddell, M Brett; Ridout, Granger; Naeve, Deanna; Leuze, Michael; LoCascio, Philip F; Panetta, John C; Wilkinson, Mark R; Pui, Ching-Hon; Naeve, Clayton W; Uberbacher, Edward C; Bonten, Erik J; Evans, William E

    2016-02-01

    MicroRNAs are important regulators of gene expression, acting primarily by binding to sequence-specific locations on already transcribed messenger RNAs (mRNA) and typically down-regulating their stability or translation. Recent studies indicate that microRNAs may also play a role in up-regulating mRNA transcription levels, although a definitive mechanism has not been established. Double-helical DNA is capable of forming triple-helical structures through Hoogsteen and reverse Hoogsteen interactions in the major groove of the duplex, and we show physical evidence (i.e., NMR, FRET, SPR) that purine or pyrimidine-rich microRNAs of appropriate length and sequence form triple-helical structures with purine-rich sequences of duplex DNA, and identify microRNA sequences that favor triplex formation. We developed an algorithm (Trident) to search genome-wide for potential triplex-forming sites and show that several mammalian and non-mammalian genomes are enriched for strong microRNA triplex binding sites. We show that those genes containing sequences favoring microRNA triplex formation are markedly enriched (3.3 fold, ptriplex binding sequences. This work has thus revealed a new mechanism by which microRNAs could interact with gene promoter regions to modify gene transcription. PMID:26844769

  8. A NEW RP-HPLC METHOD DEVELOPMENT AND VALIDATION OF ORLISTAT IN BULK AND PHARMACEUTICAL DOSAGE FORMS

    Directory of Open Access Journals (Sweden)

    N.Sreekanth,

    2010-07-01

    Full Text Available A simple, accurate and rapid RP-HPLC method has been developed for the estimation of Orlistat (ORL in bulk and pharmaceutical dosage forms using a C 18 column 150 x 4.6 mm i.d, 3.5m particle sizein isocratic mode, with mobile phase comprising of acetonitrile, water and phosphoric acid in the ratio of 85:15:0.5 (v/v/v. The flow rate was 1ml/min and detection was carried out by UV detector at 205nm. The retention time for ORL was found to be 3.79 min. The proposed method has permitted the quantification of ORL over linearity in the range of 6-60μg/ml and its percentage recovery was found to be 99.78-100.27%. The % RSD of intra day and inter day precision were found 0.49% and 0.57%, respectively.

  9. Bioactive calcium phosphate coating formed on micro-arc oxidized magnesium by chemical deposition

    Energy Technology Data Exchange (ETDEWEB)

    Liu, G.Y. [School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001 (China); Hu, J., E-mail: hujin@hit.edu.cn [School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001 (China); Ding, Z.K.; Wang, C. [School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001 (China)

    2011-01-01

    In order to improve the bioactivity of the micro-arc oxidized magnesium, a calcium phosphate coating was formed on the surface of micro-arc oxidized magnesium using a chemical method. The microstructures of the substrate and the calcium phosphate coating before and after the simulated body fluids (SBF) incubation were characterized by X-ray diffraction, Fourier-transformed infrared spectroscopy and scanning electron microscopy. The results showed that the calcified coating was composed of calcium deficient hydroxyapatite (HA) and dicalcium phosphate dihydrate (DCPD). After SBF incubation, some new apatite formation on the calcified coating surface from SBF could be found. The corrosion behaviours of the samples in SBF were also investigated by potentiodynamic polarization curves and immersion tests. The results showed that calcium phosphate coating increased the corrosion potential, and decreased the hydrogen gas release.

  10. Experimental Investigation on Strengthening Effect of Cu2O Film in Micro Sheet Forming of Copper

    Science.gov (United States)

    Zheng, Wei; Lin, Xiaojuan; Tang, Bingtao; Wang, Guangchun

    2016-05-01

    Materials processed using micro-manufacturing technologies exhibit significantly different properties compared to those produced using conventional macro-manufacturing techniques. In this paper, the uniaxial tensile tests were performed on the thin sheet specimens of pure copper to investigate how the sheet thickness impacts the flow stress. The experimental results show a continuous decrease of flow stress as the sheet thickness reduces from 200 to 100 μm, but an increase of flow stress with further reduction in thickness. Firstly, by introducing the ratio of surface grains, the decrease trend of flow stress was explained on the basis of surface layer model. Secondly, the strengthening effect of Cu2O film was clearly demonstrated by the x-ray diffraction and electrodeposition process. Finally, considering the effects of Cu2O film and free surface layer, the mechanical properties of Cu2O film was studied, which is helpful to explain the material behavior in micro sheet forming.

  11. Effect of Nb on glass forming ability and plasticity of (Ti-Cu)-based bulk metallic glasses

    International Nuclear Information System (INIS)

    A Ti33Cu47Zr9Ni6Sn2Si1Nb2 bulk metallic glass has been developed by Nb partial substitution for Zr in Ti33Cu47Zr11Ni6Sn2Si1 alloy. The glass forming ability Ti33Cu47Zr9Ni6Sn2Si1Nb2 alloy has been investigated using differential scanning calorimetry and X-ray diffractometry. Partial Nb substitutes for Zr promote the glass forming ability. Ti33Cu47Zr9Ni6Sn2Si1Nb2 BMG with diameter of 3 mm can be fabricated by Cu-mold injection casting method. The glass forming ability of Ti33Cu47Zr9Ni6Sn2Si1Nb2 alloy is enhanced by stabilizing the undercooled liquid against crystallization. The plastic strain up to 2.5% was obtained for Ti33Cu47Zr9Ni6Sn2Si1Nb2 BMG compared to 0.15% for Ti33Cu47Zr11Ni6Sn2Si1 BMG, which demonstrates that small amount of Nb addition can have a dramatic effect on plasticity enhancement in Ti-Cu-based BMG. The intersection and branching of the shear bands are observed. The plastic strain of the Ti33Cu47Zr9Ni6Sn2Si1Nb2 BMG can be improved by the generation of nanocrystalline particles, which lead to multiple shear bands.

  12. Method development, validation and stability study of ritonavir in bulk and pharmaceutical dosage form by spectrophotometric method

    Directory of Open Access Journals (Sweden)

    Anindita Behera

    2011-01-01

    Full Text Available Background: Ritonavir is a protease inhibitor and mostly used as a booster for increasing the bioavailability of other protease inhibitors like Atazanavir Sulfate and Lopinavir. Aims: Quality assessment of the new dosage form of Ritonavir i.e. tablets is very essential, so two sensitive, simple and precise methods are developed for quantification of Ritonavir in bulk and tablet dosage forms. Materials and Methods: The first method is based on first order derivative method and the second is based on area under curve method. Both the methods are validated according to international conference of harmonization (ICH guidelines. A stability study of Ritonavir is done in UV - Visible Spectrophotometer under different stress conditions recommended by ICH guidelines. Results: The absorption maximum is found to be 239nm in methanol. The absorption maximum in first method is chosen at 253.2nm, and the linearity is found between 4 - 20 ΅g/ml with coefficient of correlation value 0.9981. In the second method, the range for area under curve selected is 237 - 242nm. The linearity is found between 4 -20 ΅g/ml with coefficient of correlation value 0.9992. Conclusion: The developed methods are validated and found to be simple, rapid, precise and cost-effective. The degradation study in tablet dosage form can be used as a stability indicating assay method.

  13. A novel vector-based method for exclusive overexpression of star-form microRNAs.

    Directory of Open Access Journals (Sweden)

    Bo Qu

    Full Text Available The roles of microRNAs (miRNAs as important regulators of gene expression have been studied intensively. Although most of these investigations have involved the highly expressed form of the two mature miRNA species, increasing evidence points to essential roles for star-form microRNAs (miRNA*, which are usually expressed at much lower levels. Owing to the nature of miRNA biogenesis, it is challenging to use plasmids containing miRNA coding sequences for gain-of-function experiments concerning the roles of microRNA* species. Synthetic microRNA mimics could introduce specific miRNA* species into cells, but this transient overexpression system has many shortcomings. Here, we report that specific miRNA* species can be overexpressed by introducing artificially designed stem-loop sequences into short hairpin RNA (shRNA overexpression vectors. By our prototypic plasmid, designed to overexpress hsa-miR-146b-3p, we successfully expressed high levels of hsa-miR-146b-3p without detectable change of hsa-miR-146b-5p. Functional analysis involving luciferase reporter assays showed that, like natural miRNAs, the overexpressed hsa-miR-146b-3p inhibited target gene expression by 3'UTR seed pairing. Our demonstration that this method could overexpress two other miRNAs suggests that the approach should be broadly applicable. Our novel strategy opens the way for exclusively stable overexpression of miRNA* species and analyzing their unique functions both in vitro and in vivo.

  14. Forming process of cross-connected finned micro-grooves in copper strips

    Institute of Scientific and Technical Information of China (English)

    CHI Yong; TANG Yong; CHEN Jin-chang; DENG Xue-xiong; LIU Lin; WAN Zhen-ping; LIU Xiao-qing

    2007-01-01

    Using ploughing-extrusion method, a cross-connected finned micro-grooves structure was formed on the surface of copper strips with thickness of 0.4 mm. The structure was fabricated by making 'V'-grooves in copper strips and perpendicular 'V'-grooves on the opposite side that intersect the first set of grooves. Micro pores appear at the intersection of these cross-connected grooves, and micro fins appear on the groove fringes. So it can be defined as 'pore-groove-fin' structure. The preferable 'pore-groove-fin' structure can be obtained under the condition that the tool edge inclination angle (χγ) is 45°, both the major extrusion angle (γo) and the minor extrusion angle (γ'o) are 30°, both the major formation angle (β) and the minor formation angle (β') are 10°, the ploughing-extrusion depth (fd) is 0.32 mm and the groove pitch is 0.4 mm on surfaces A and B. The formed included angle of groove A is 70°, and the groove depth is 0.3 mm, while the included angle of opposite perpendicular groove B is 20° with the groove depth of 0.35 mm. The obtained fin height is 0.15 mm, the elliptical pore length is 0.2 mm and the width is 0.05 mm. Experiments show that fd has the greatest influence on the formation of micro pores. Bulges appear on the opposite surface B when the ploughing-extrusion depth on surface A (fdA) reaches a critical value. The ploughing-extrusion depth on surface B (fdB) has great influence on the re-growth of fin structure.

  15. A Novel Approach using Hydrotropic Solubalization Technique for Quantitative Estimation of Entacapone in Bulk Drug and Dosage Form

    Directory of Open Access Journals (Sweden)

    Ruchi Jain

    2013-08-01

    Full Text Available Purpose: Analysis of drug utilized the organic solvent which are costlier, toxic and causing environment pollution. Hydrotropic solution may be a proper choice to preclude the use of organic solvents so that a simple, accurate, novel, safe and precise method has been developed for estimation of poorly water soluble drug Entacapone (Water Solubility-7.97e-02 g/l. Methods: Solubility of entacapone is increased by using 8M Urea as hydrotropic agent. There was more than 67 fold solubility enhanced in hydrotropic solution as compare with distilled water. The entacapone (ENT shows the maximum absorbance at 378 nm. At this wavelength hydrotropic agent and other tablet excipients do not shows any significant interference in the spectrophotometric assay. Results: The developed method was found to be linear in the range of 4-20 μg/ml with correlation coefficient (r2 of 0.9998. The mean percent label claims of tablets of ENT in tablet dosage form estimated by the proposed method were found to be 99.17±0.63. The developed methods were validated according to ICH guidelines and values of accuracy, precision and other statistical analysis were found to be in good accordance with the prescribed values. Conclusion: As hydrotropic agent used in the proposed method so this method is Ecofriendly and it can be used in routine quantitative analysis of drug in bulk drug and dosage form in industries.

  16. Novel LC Method Development and Validation for Simultaneous Determination of Montelukast and Doxofylline in Bulk and Pharmaceutical Dosage Forms

    Directory of Open Access Journals (Sweden)

    Gadapa Nirupa

    2013-01-01

    Full Text Available A novel rapid HPLC method was developed for simultaneous determination of montelukast and doxofylline in bulk and pharmaceutical dosage forms. Development of an analytical method for simultaneous estimation of drugs requires a lot of efforts and of course it is a challenging task. The method was developed by using C18 (150 mm×4.6 mm, 5 μm column; mobile phase consisting of methanol and phosphate buffer at pH 4.5; the flow rate of 1.0 mL/min and ultraviolet detection at 280 nm. Both drugs were sufficiently resolved having retention time of 4.7 min and 1.9 min for montelukast and doxofylline, respectively. The method was validated as per ICH Guidelines for various parameters like precision, linearity, accuracy, ruggedness, and robustness. The validated method was applied to the commercially available pharmaceutical dosage form and obtained the desired result.

  17. Development of Stability Indicating LC Method for the Estimation of Tolperisone in Bulk and Pharmaceutical Dosage Form

    Directory of Open Access Journals (Sweden)

    U. K. Chhalotiya

    2013-01-01

    Full Text Available A rapid, specific, and sensitive reverse phase high performance liquid chromatographic method has been developed and validated for analysis of tolperisone in both bulk and pharmaceutical dosage form. The HPLC method was performed with a reversed phase C18 SunFire column (250 mm × 4.6 mm i.d., 5 mm particle size, detection at 261 nm and a mixture of methanol, water and pH 7.5 adjusted by use of 1% solution of triethylamine (60 : 40 as mobile phase. The flow rate was 1.0 mL min−1 and effluents were monitored at 261 nm. The retention time of tolperisone was 4.8 min. Tolperisone was subjected to acid and alkali hydrolysis, chemical oxidation, wet hydrolysis, dry heat degradation, and sunlight degradation. The degraded product peaks were well resolved from the pure drug peak with significant difference in their retention time values. Stressed samples were assayed using developed LC method. The proposed method was validated with respect to linearity, accuracy, precision, and robustness. The method was successfully applied to the estimation of tolperisone in tablet dosage forms.

  18. TLC-densitometric analysis of α-escin in bulk drug substance and in pharmaceutical dosage forms

    Directory of Open Access Journals (Sweden)

    Dolowy Malgorzata

    2015-09-01

    Full Text Available A quite simple and rapid TLC-densitometric method for the identification of α-escin (Aescin in bulk drug substances was developed. In so doing, different chromatographic conditions, including various mobile and stationary phases, were tested. A TLC densitometric determination of the examined compound was performed without using visualizing reagent, yet with the use of appropriate dipping reagents, in order to obtain reliable UV-densitometric measurements of α-escin - a substance which has weak chromophore groups. Herein, the application of a mobile phase containing n-butanolacetic acid-water in volume composition 30:7:13, the use of silica gel 60F254 plates with concentrating zone, and subsequent application of 10% sulphuric acid in ethanol or 5% vanillin in methanol/sulphuric acid, respectively, provided the best results in a TLCdensitometric study of α-escin. The described method was successfully employed to identify α-escin in commercial samples that were in an oral dosage form (tablets and also in the form of gel containing 20 mg of α-escin.

  19. Effect of Ni addition on glass forming ability and thermal stability of Nd-Fe-Al-Ni bulk metallic glasses

    International Nuclear Information System (INIS)

    (Nd60Fe30Al10)100-xNi x (where x = 0, 3, 5, 8 and 10 at%) alloy cylinders with a diameter of 3 mm and a length of 55 mm were prepared by copper mold casting. The effect of Ni addition on glass forming ability (GFA) and thermal stability of Nd-based alloy was investigated using X-ray diffraction (XRD), scanning electron microscopy (SEM) and differential scanning calorimetry (DSC). It was found that a bulk metallic glass (BMG) composite with a small amount of primary crystallites in the amorphous matrix is formed without Ni addition, and the proportion of crystallites decreases with an increase in the amount of Ni. The (Nd60Fe30Al10)92Ni8 alloy exhibits the best GFA even though there is no apparent glass transition and supercooled liquid region. It is interesting to note that the main melting temperature of the (Nd60Fe30Al10)92Ni8 alloy is lower than its crystallization temperature, resulting in the value of the nominal reduced crystallization temperature T r (=T x/T m) being larger than 1.0. The separation of amorphous phases with different thermal stabilities is believed to be one of the reasons for the anomalous phenomenon. The high GFA of the alloy may be explained in terms of valence concentration and structural stability of the amorphous phase

  20. Account of a line form and luminosity developed for a spectrometer based on cylindrical curved multilayer mirror for a bulk source of X-ray radiation

    International Nuclear Information System (INIS)

    The procedure of calculation of the line form and aperture ratio developed for a spectrometer based on cylindrical curved multilayer mirror is presented. This approach is applicable for account of aperture ratio and line form for a bulk isotropic X-ray source. The calculation results for several geometries measurements are represented

  1. Forming method of micro heat pipe with compound structure of sintered wick on grooved substrate

    Science.gov (United States)

    Li, Xibing; Li, Mingjian; Li, Ming; Wu, Ruchen; Wan, Yingsi; Cheng, Tian

    2016-03-01

    Micro heat pipes (MHPs) with excellent heat transfer performance have been the ideal radiating components to meet increasingly higher requirements posed by high heat-flux products. Based on MHPs' working principle, this study deduced capillary limit of a novel MHP with compound structure of sintered wick on grooved substrate, and probed into its forming mechanism: first, high-speed oil-filled spinning was applied to fabricating micro grooves, with optimal spinning and drawing speeds determined; then a mini-type vibration machine was used to help fill copper powders fast and uniformly, with appropriate sintering temperature and time fixed; the manufacturing method that integrates vacuum-pumping-cold-welding with secondary-degassing-cold-welding to increase vacuumizing efficiency. The results of experiments on its heat transfer performance show that the MHPs with sintered-wick-on-grooved-substrate structure fabricated through the proposed forming method can not only acquire much better heat transfer performance, but have advantages such as higher productivity and lower cost.

  2. Evaluating urban form and location effects on cycling based on Danish micro-data

    DEFF Research Database (Denmark)

    Nielsen, Thomas Alexander Sick; Olafsson, Anton Stahl; Carstensen, Trine Agervig;

    Extended abstract The paper analyses the environmental correlates of cycling based on Danish transportation and urban form micro-data. Established walkability factors such as density, connectivity and diversity are related to cycling, but access to retail concentrations/centers, public...... access variables in the analysis – suggesting the strongest effect of density when controlling for mode access. Although direct inclusion of residential self selection issues in the analysis has not been possible based on the available data, this result indicate that the inclusion of preferences will not...... cycling in Denmark. Important questions related to this, and of particular interest from a cycling promotion and urban planning perspective, is the significance of urban form and location factors and which trade-offs between cycling and other transport provisions that appear from the results. The paper is...

  3. Simultaneous Estimation of Ibuprofen and Phenylephrine Hydrochloride in Bulk and Combined Dosage Form by First Derivative UV Spectrophotometry Method

    Directory of Open Access Journals (Sweden)

    Mehul Patel

    2013-01-01

    Full Text Available A simple, precise, rapid, and economic method was developed for the simultaneous determination of Ibuprofen and Phenylephrine HCl in bulk and combined dosage form. This method involves first-order derivative spectroscopy using 248 nm and 237 nm as zero crossing points for Ibuprofen and Phenylephrine HCl, respectively. For spectrophotometric method 0.1 N NaOH was used as a solvent. The linearity was established over the concentration range of 12–72 μg/mL and 1.5–22 μg/mL for Ibuprofen and Phenylephrine HCl with correlation coefficient (r2 of 0.9972 and 0.9981, respectively. The mean % recoveries were found to be in the range of 98.88% and 98.54% for Ibuprofen and Phenylephrine HCl, respectively. Interday and intraday studies showed repeatability of the method. The method was found to be specific and robust. The method was successfully applied to pharmaceutical formulation, with no interference from excipients as indicated by the recovery study. Results of analysis were validated statistically and by recovery studies.

  4. A Combinatorial Approach to the Investigation of Metal Systems that Form Both Bulk Metallic Glasses and High Entropy Alloys

    Science.gov (United States)

    Welk, Brian A.; Gibson, Mark A.; Fraser, Hamish L.

    2016-03-01

    In this work, compositionally graded specimens were deposited using the laser engineered net-shaping (LENS™) additive manufacturing technique to study the glass-forming ability of two bulk metallic glass (BMG) and high entropy alloy (HEA) composite systems. The first graded specimen varied from Zr57Ti5Al10Cu20Ni8 (BMG) to CoCrFeNiCu0.5 (HEA) and the second graded specimen varied from TiZrCuNb (BMG) to (TiZrCuNb)65Ni35 (HEA). After deposition, laser surface melting experiments were performed parallel to the gradient to remelt and rapidly solidify the specimen. Scanning electron microscopy and energy dispersive x-ray spectroscopy were used to determine the morphology and composition variations in the as-deposited and laser surface melted phases. Selected area diffraction of the melt pool regions confirmed an almost fully amorphous region in the first gradient and an amorphous matrix/crystalline dendrite composite structure in the second gradient.

  5. Micellar high performance liquid chromatographic determination of flunixin meglumine in bulk, pharmaceutical dosage forms, bovine liver and kidney

    Directory of Open Access Journals (Sweden)

    Fathalla F. Belal

    2015-03-01

    Full Text Available A simple, sensitive and rapid liquid chromatographic method was developed and validated for the analysis of flunixin meglumine (flunixin-M in bulk, pharmaceutical dosage forms, bovine liver and kidney. Analytical separation was performed in less than 4 min using a C18 column with UV detection at 284 nm. A micellar solution composed of 0.15 M sodium dodecyl sulphate, 8% n-butanol and 0.3% triethylamine in 0.02 M phosphoric acid buffered at pH 7.0 was used as the mobile phase. The method was fully validated in accordance with the International Conference on Harmonization (ICH guidelines. The limit of detection and the limit of quantitation were 0.02 and 0.06 μg mL−1, respectively. The recoveries obtained were in range of 95.58–106.94% for bovine liver and kidney. High extraction efficiency was obtained without matrix interference in the extraction process and in the subsequent chromatographic determination. The method showed good repeatability, linearity and sensitivity according to the evaluation of the validation parameters.

  6. Laboratory Testing of Bulk Vitrified Low-Activity Waste Forms to Support the 2005 Integrated Disposal Facility Performance Assessment

    International Nuclear Information System (INIS)

    The purpose of this report is to document the results from laboratory testing of the bulk vitrified (BV) waste form that was conducted in support of the 2005 integrated disposal facility (IDF) performance assessment (PA). Laboratory testing provides a majority of the key input data required to assess the long-term performance of the BV waste package with the STORM code. Test data from three principal methods, as described by McGrail et al. (2000a; 2003a), are discussed in this testing report including the single-pass flow-through test (SPFT) and product consistency test (PCT). Each of these test methods focuses on different aspects of the glass corrosion process. See McGrail et al. (2000a; 2003a) for additional details regarding these test methods and their use in evaluating long-term glass performance. In addition to evaluating the long-term glass performance, this report discusses the results and methods used to provided a recommended best estimate of the soluble fraction of 99Tc that can be leached from the engineering-scale BV waste package. These laboratory tests are part of a continuum of testing that is aimed at improving the performance of the BV waste package.

  7. Bulk-form TiCx/Ti nanocomposites with controlled nanostructure prepared by a new method: selective laser melting

    International Nuclear Information System (INIS)

    A novel selective laser melting method was applied to consolidate the high-energy ball-milled nanostructured TiCP/Ti composite powder to prepare TiCx/Ti nanocomposites in bulk form. The substoichiometric TiC0.625 with a hexagonal crystal structure acted as the reinforcing phase, having a lamellar nanostructure with an average thickness of ∼48 nm. The nanostructure of TiC0.625 was coarsened and finally disappeared on decreasing the applied linear laser energy density. Reasonable physical mechanisms and conditions for the formation of nanostructured TiCx during laser processing were proposed. It was revealed that the formation of nanoscale hexagonal structured TiC0.625 was due to the action of microscopic pressure induced by evaporative recoil and surface tension on (1 1 1) plane of the lamellar TiCx crystals. The disappearance of nanostructure of TiC0.625 at a lower laser energy input was ascribed to a decreased microscopic pressure and an elevated carbon activity in the molten pool.

  8. Crystalline Precipitate in a Bulk Glass Forming Zr-Based Alloy and Its Effect on Mechanical Properties

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    Cylindrical and sheet samples of bulk metallic glass with a nominal composition of Zr52.5Ni14.6Al10Cu17.9Ti5 (at. pct) were prepared by melt injection casting. The crystalline precipitates formed during the casting were studied by metallographic observations and selected-area electron diffractions. The effect of crystalline precipitates on the mechanical properties were investigated by tensile and compressive tests at room temperature. Oxygen contents and the sample sizes (or cooling rates) strongly affect the formation of the crystalline precipitates. Overheating the alloy melt up to 200 K above its melting temperature can effectively prevent the formation of the crystalline precipitates to get fully glass samples with diameters up to 2 mm for cylinders and thickness up to 1 mm for sheets even the oxygen content is as higher as 0.08 wt pct.With increasing the sample sizes, the crystalline precipitates increase in volume fraction and size. The formation of the precipitates experienced two stages, i.e., initially nucleation and isotropic growth, and then anisotropic growth, finally forming faceted morphologies. Fully glassy Zr52.5Ni14.6Al10Cu17.9Ti5 alloy exhibits excellent tensile and compressive properties at room temperature. The presence of crystalline precipitates significantly decreases the tensile and compressive properties. With increasing the crystalline precipitates, the area of vein patterns on the fracture surface decreases, but the fracture steps increase, and the fracture mode changes from ductile to brittle resulting from the larger stress concentration caused by the larger sizes and faceted shapes of the crystalline precipitates.

  9. Stability-Indicating RP-HPLC Method for Determination of Guanfacine Hydrochloride in Bulk Drugs and in Pharmaceutical Dosage Form

    Directory of Open Access Journals (Sweden)

    Vinod K. Ahirrao

    2011-04-01

    Full Text Available A novel stability-indicating RP-HPLC method was developed and validated for quantitative determination of guanfacine hydrochloride in bulk drug and in pharmaceutical dosage form. An isocratic, reversed phase HPLC method was developed to separate the drug from the degradation products, using Apollo, C18 (250mm x 4.6mm, 5µm column with mobile phase of 50mM Ammonium acetate (volatile buffer and acetonitrile (65:35, v/v. UV detection has been done at wavelength 220 nm. The guanfacine hydrochloride was subjected to the stress conditions of hydrolysis (acid, base, oxidation, photolysis and thermal degradation. The stressed samples were analyzed by the proposed method. The analyte peak shape was excellent. The described method shows excellent linearity over a range of 30 – 450 µg/mL. The correlation coefficient for guanfacine hydrochloride was 0.999. The limit of detection for Guanfacine hydrochloride is 0.011 µg/mL and the limit of quantification is 0.038 µg/mL respectively.Degradation was observed for guanfacine hydrochloride in base, thermal and in 30% H2O2 conditions. The drug was found to be stable in the other stress conditions attempted. The degradation products were well resolved from main peak. The percentage recovery of guanfacine hydrochloride was ranged from (99.2% to 100.5% in pharmaceutical dosage form. The developed method was validated with respect to the linearity, accuracy (recovery, precision, specificity and robustness. The forced degradation studies prove the stability indicating power of the method.

  10. Effects of Zn addition on the glass forming ability and mechanical properties of Mg–Cu–Gd bulk metallic glasses

    International Nuclear Information System (INIS)

    Highlights: • Mg-Zn-Cu-Gd BMGs with 2 mm diameter are fabricated by copper mold casting method. • The σf and Hv of the Mg60Zn5Cu25Gd10 reach up to 754 MPa and 286 Hv, respectively. • The Mg60Zn5Cu25Gd10 alloy exhibits plastic deformation characteristic at micro-level. -- Abstract: The effects of Zn addition on the glass forming ability (GFA) and mechanical properties are investigated in Mg65−xZnxCu25Gd10 (x = 0, 3, 5, 8 at.%) alloys by X-ray diffractometer (XRD), differential scanning calorimeter (DSC) and mechanical property tests. Thermal analysis shows that with the increasing of Zn content from 0 to 8 at.%, the supercooled liquid regions of Mg65−xZnxCu25Gd10 alloys decrease from 68 K to 31 K, indicating the obvious deterioration in their GFA. On the other hand, however, the mechanical property tests demonstrate that the appropriate addition of Zn (5 at.%) in Mg65−xZnxCu25Gd10 alloys greatly improves the mechanical strength, increases their compressive fracture strength and Vickers hardness from 648 MPa and 257 Hv to 754 MPa and 286 Hv, respectively. In addition, the fracture surface morphologies have been characterized by scanning electron microscopy (SEM) and the dominant fracture behaviors of the as-cast alloys have been explained as well

  11. Fully front-side bulk-micromachined single-chip micro flow sensors for bare-chip SMT (surface mounting technology) packaging

    International Nuclear Information System (INIS)

    This paper reports novel single-wafer-based piezoresistive micro flow sensors, which are bulk micromachined only from the front side of the silicon wafer to facilitate the sensor-bare chips directly packaged into micro-fluidic systems with low-cost surface mounting technology (SMT). With neither double-sided micromachining nor multiwafer bonding needed, two structural types of the piezoresistive flow sensors are designed and fabricated in (1 1 1) wafers, where ‘type A’ sensor has a smaller channel cross section area compared to ‘type B’ sensor. After the bare sensor chip directly attached on a printed circuit board (PCB), wire bonded between the pads and the PCB for electric interconnection and the inlet/outlet front side connected, deionized water is flowed into the both types of flow sensors to characterize piezoresistive output of the differential pressure sensing elements in terms of the flow rate. For ‘type A’ and ‘type B’ sensors that are both power supplied with DC 5 V, the sensitivities are sequentially measured as 766.80 mV (µL s−1)−1 and 19.12 mV (µL s−1)−1, with the nonlinearities as 0.4% FS and 0.9% FS, respectively. Compared with traditionally fabricated micro flow sensors, the single-chip fabricated differential-pressure flow sensors can be low-cost volume manufactured. Moreover, the bare sensor chips can be simply SMT packaged for low-cost micro-system applications. (paper)

  12. Micro and nano indentation studies on Zr60Cu10Al15Ni15 bulk metallic glass

    International Nuclear Information System (INIS)

    Highlights: • Highest hardness is observed in the fully crystalline regions. • Large atomic misfit between intermetallic phases provides additional hardening. • A unique case of ISE is observed in both glassy as well as crystalline regions. - Abstract: Partially vitrified Zr60Cu10Al15Ni15 bulk metallic glass has been synthesized using water cooled copper mold drop casting technique. Kinetically favorable microstructures having different morphologies are observed throughout the volume of the bulk metallic glass sample. X-ray diffraction studies indicate formation of hard intermetallic compounds such as Zr3Al2 and Zr2Ni in certain regions along with amorphous structures. Microindentation studies carried out in different regions of the sample reveal microstructure dependent deformation behavior. Highest hardness is observed in the fully crystallized regions compared to pure glassy regions in the same sample. Further nanoindentation in the same sample is used to understand dynamic mechanical properties of microstructures in different regions. The pile-up morphologies around the indent and differences in load–displacement curves provide vital information on deformation behavior of sample in different microstructure sensitive regions

  13. Effect of Si addition on glass-forming ability and mechanical properties of Cu-Zr-Al bulk metallic glass

    International Nuclear Information System (INIS)

    Research highlights: The Cu50Zr43Al7 alloy has a surprising GFA, and the glassy rods with diameter of 10 mm have been produced in this research. It has not been reported that the Cu-based glassy rods (Cu ≥ 50 at.%) to be produced with the critical diameter greater than 10 mm. The novelty of this research is that the glass formation has been improved and the critical diameter increased to 12 mm for the alloy having x = 1 with the addition of Si. Different criteria are used to evaluate the influence of Si content on the GFA, and the possible mechanisms involved in the achievement of this GFA are also discussed. - Abstract: The effect of Si addition on the glass-forming ability (GFA) and mechanical properties of (Cu50Zr43Al7)100-xSix (x = 0, 0.5, 1, 1.5 and 2 at.%) alloys were investigated. The GFA of Cu50Zr43Al7 alloy is improved by addition of a small amount of Si, and the critical diameter for glass formation increases from 10 mm for the alloy with x = 0-12 mm for the alloy with x = 1 when prepared using copper mold casting. Different criteria are used to evaluate the influence of Si content on the GFA, and the possible mechanisms involved in the achievement of this GFA are also discussed. In the uniaxial compression, the bulk glassy alloys exhibit a limited plastic strain of less than 1%, but the compressive fracture strength and Young's modulus were obtained in high values of 1969-2129 MPa and 101-144 GPa, respectively. Fracture surface and shear bands of samples were studied by using scanning electron microscopy (SEM).

  14. Mosses Like It Rough—Growth Form Specific Responses of Mosses, Herbaceous and Woody Plants to Micro-Relief Heterogeneity

    OpenAIRE

    Carl Beierkuhnlein; Anke Jentsch; Severin Irl; Andrea J. Früh; Müller, Carina M.; Manuel J. Steinbauer; Leutner, Benjamin F.

    2012-01-01

    Micro-relief heterogeneity can lead to substantial variability in microclimate and hence niche opportunities on a small scale. We explored the relationship between plant species richness and small-scale heterogeneity of micro-relief on the subtropical island of La Palma, Canary Islands. Overall, we sampled 40 plots in laurel and pine forests at four altitudinal bands. Species richness was recorded separately for various growth forms (i.e., mosses, herbaceous and woody plants). Site conditions...

  15. An overview of nuclear micro-beam analysis of surface and bulk fuel retention in carbon-fibre composites from Tore Supra

    International Nuclear Information System (INIS)

    Surface and bulk retention of deuterium in tiles of the pump limiter from Tore Supra was examined with nuclear reaction analysis using both standard and micro-beam techniques. The aim was to determine the variations in the content and distribution of fuel species in carbon-fibre composites. On plasma-facing surfaces from the deposition zone, the D content reaches 2.5 x 1019 cm-2 in about 8 μm thick top layer, but lateral differences reach even more than one order of magnitude. This is also measured in the erosion zone: 6.6 x 1017 cm-2 to 7.7 x 1018 cm-2 D atoms. Bulk content was examined on cross-sections opened by fracturing the tiles. Fuel is detected up to the depth of 1-1.5 mm beneath the plasma-facing surface in tiles from both the erosion and deposition zones. It occurs in bands, about 100 μm wide and several mm long, roughly parallel to the original plasma-facing surface.

  16. Noncontact measurement of high-temperature surface tension and viscosity of bulk metallic glass-forming alloys using the drop oscillation technique

    OpenAIRE

    Mukherjee, S.; Johnson, W. L.; Rhim, W. K.

    2005-01-01

    High-temperature surface tension and viscosities for five bulk metallic glass-forming alloys with widely different glass-forming abilities are measured. The measurements are carried out in a high-vacuum electrostatic levitator using the drop oscillation technique. The surface tension follows proportional mathematical addition of pure components' surface tension except when some of the constituent elements have much lower surface tension. In such cases, there is surface segregation of the low ...

  17. Biodegradation behavior of micro-arc oxidized AZ31 magnesium alloys formed in two different electrolytes

    International Nuclear Information System (INIS)

    Highlights: ► Phosphate coating has lesser degradation rate than silicate coating in r-SBF solution. ► Farringtonite phase is chemically more stable than forsterite phase in SBF solution. ► Apatite forming ability of forsterite containing coating is better than farringtonite containing film. ► The hydrophilisity nature of silicate film on magnesium alloy with respect to its roughness, is greater than phosphate film. - Abstract: Degradation behavior of coated magnesium alloys is among most prominent factors for their biomedical applications. In this study, bio-corrosion behavior of micro-arc oxidized magnesium AZ31 alloys formed in silicate and phosphate baths was investigated in r-SBF medium. For this purpose polarization behavior and open circuit profile of the coated samples were achieved by electrochemical and immersion tests, respectively. Moreover, the morphology and composition of the coatings were evaluated before and after immersion test using scanning electron microscopy, X-ray diffraction and energy dispersive spectroscopy. The results showed that the phosphate film had better corrosion resistance and greater thickness than silicate film and, in turn, the lesser degradability in SBF solution, so that Ca2+ and PO43− containing compounds were more abundant on silicate film than phosphate film. Moreover phosphate film had greater surface roughness and lesser hydrophilic nature.

  18. Mosses like it rough-growth form specific responses of mosses, herbaceous and woody plants to micro-relief heterogeneity

    DEFF Research Database (Denmark)

    Leutner, Benjamin F.; Steinbauer, Manuel; Müller, Carina M.; Früh, Andrea J.; Irl, Severin; Jentsch, Anke; Beierkuhnlein, Carl

    2012-01-01

    sampled 40 plots in laurel and pine forests at four altitudinal bands. Species richness was recorded separately for various growth forms (i.e., mosses, herbaceous and woody plants). Site conditions such as altitude, slope, aspect, and tree density were measured. Micro-relief heterogeneity was...... between growth forms. While moss richness was affected significantly by micro-relief heterogeneity, herbaceous and woody plants richness responded mainly to larger-scale site conditions such as aspect and tree density. Our results stress the importance of small-scale relief heterogeneity for the...

  19. Micro scanning probes

    CERN Document Server

    Niblock, T

    2001-01-01

    This thesis covers the design methodology, theory, modelling, fabrication and evaluation of a Micro-Scanning-Probe. The device is a thermally actuated bimorph quadrapod fabricated using Micro Electro Mechanical Systems technology. A quadrapod is a structure with four arms, in this case a planar structure with the four arms forming a cross which is dry etched out of a silicon diaphragm. Each arm has a layer of aluminium deposited on it forming a bimorph. Through heating each arm actuation is achieved in the plane of the quadrapod and the direction normal to it. Fabrication of the device has required the development of bulk micromachining techniques to handle post CMOS fabricated wafers and the patterning of thickly sputtered aluminium in bulk micro machined cavities. CMOS fabrication techniques were used to incorporate diodes onto the quadrapod arms for temperature measurement of the arms. Fine tungsten and silicon tips have also been fabricated to allow tunnelling between the tip and the platform at the centr...

  20. The influence of park size and form on micro climate and thermal comfort

    Science.gov (United States)

    Sodoudi, Sahar; Chi, Xiaoli; Müller, Felix; Zhang, Huiwen

    2016-04-01

    The population of urban areas will increase in the next decades and it leads to higher fraction of sealed areas, which will increase the urban heat island intensity. In addition, climate model projections also show that the frequency and the intensity of heat waves and the related heat stress will be higher in the future. Urban Parks are the best key to mitigate the urban heat island and to minimize the local climate change. Due to the lack of free spaces which can be converted to green spaces, this study investigates the influence of urban park forms on the micro climate and thermal comfort. In this study, a central big park has been compared to different numbers of small parks in terms of the cooling effect and thermal comfort. Five different park forms with the same total size have been considered. The results show that the park cooling effect depends not only on the park form, but also on the arrangement of the vegetation inside the park and wind speed and direction. Grassy areas (with 10 and 50 Cm grass), shrubs and hedges as well as trees with small and big canopies have been considered for the simulation. ENVI-MET and Rayman models have been used to simulate the cooling effect, cooled area size, PET and UTCI, respectively. The results for a hot day in Berlin on three different times during day and night will be shown and compared to each other. The effects of Sky view factor and soil humidity (irrigation) have also been discussed.

  1. New route to form micro-pores on 316L stainless steel surface

    Energy Technology Data Exchange (ETDEWEB)

    Ma Xinxin [School of Materials Science and Engineering, Harbin Institute of Technology, Harbin, 150001 (China)], E-mail: maxin@hit.edu.cn; Wang Yujiang; Tang Guangze [School of Materials Science and Engineering, Harbin Institute of Technology, Harbin, 150001 (China); Chen Qingfu [Jiangyin Fasten-PLT Materials Science Co., Ltd (Peier), 998 Changjiang Donglu, Jiangyin, 214434 (China)

    2008-11-15

    In order to seek an effective way for preventing restenosis after coronary stent implantation, a proposal of increasing the amount of loaded drug without changing the size of struts was given. Thereafter, a process of fabricating in-situ formed sub-micro-pores on 316L stainless steel (316L SS) was demonstrated. An aluminum thin film was deposited by magnetron sputtering on a 316L substrate. The aluminum film was then anodized in different acids (0.3 M oxalic and 10 vol.% sulfuric) by regulating direct current power supply. Through an appropriate chemical dissolution, the anodic alumina film was removed and the underlying porous 316L was obtained. The morphology of the porous 316L surface was examined by scanning electron microscope and the composition of the pores was investigated by energy dispersive X-ray analysis. The corrosion behavior of the porous 316L was evaluated by the polarization measurement. The results indicate that the shape and size of pores could be affected evidently by the acids used in anodization. The pores density is found to change with variation of the applied voltage in anodization. The corrosion current of the anodized specimens decrease and the corrosion voltage increase, compared with the untreated specimens.

  2. TLC-densitometric analysis of α-escin in bulk drug substance and in pharmaceutical dosage forms

    OpenAIRE

    Dolowy Malgorzata; Pyka-Pajak Alina; Filip Katarzyna; Zagrodzka Joanna

    2015-01-01

    A quite simple and rapid TLC-densitometric method for the identification of α-escin (Aescin) in bulk drug substances was developed. In so doing, different chromatographic conditions, including various mobile and stationary phases, were tested. A TLC densitometric determination of the examined compound was performed without using visualizing reagent, yet with the use of appropriate dipping reagents, in order to obtain reliable UV-densitometric measurements of α-escin - a substance which has we...

  3. Improvement of corrosion resistance in NaOH solution and glass forming ability of as-cast Mg-based bulk metallic glasses by microalloying

    Directory of Open Access Journals (Sweden)

    Peng Hao

    2011-02-01

    Full Text Available The influences of the addition of Ag on the glass forming ability (GFA and corrosion behavior were investigated in the Mg-Ni-based alloy system by X-ray diffraction (XRD and electrochemical polarization in 0.1 mol/L NaOH solution. Results shows that the GFA of the Mg-Ni-based BMGs can be improved dramatically by the addition of an appropriate amount of Ag; and the addition element Ag can improve the corrosion resistance of Mg-Ni-based bulk metallic glass. The large difference in atomic size and large negative mixing enthalpy in alloy system can contribute to the high GFA. The addition element Ag improves the forming speed and the stability of the passive film, which is helpful to decrease the passivation current density and to improve the corrosion resistance of Mg-Ni-based bulk metallic glass.

  4. Creating bulk nanocrystalline metal.

    Energy Technology Data Exchange (ETDEWEB)

    Fredenburg, D. Anthony (Georgia Institute of Technology, Atlanta, GA); Saldana, Christopher J. (Purdue University, West Lafayette, IN); Gill, David D.; Hall, Aaron Christopher; Roemer, Timothy John (Ktech Corporation, Albuquerque, NM); Vogler, Tracy John; Yang, Pin

    2008-10-01

    Nanocrystalline and nanostructured materials offer unique microstructure-dependent properties that are superior to coarse-grained materials. These materials have been shown to have very high hardness, strength, and wear resistance. However, most current methods of producing nanostructured materials in weapons-relevant materials create powdered metal that must be consolidated into bulk form to be useful. Conventional consolidation methods are not appropriate due to the need to maintain the nanocrystalline structure. This research investigated new ways of creating nanocrystalline material, new methods of consolidating nanocrystalline material, and an analysis of these different methods of creation and consolidation to evaluate their applicability to mesoscale weapons applications where part features are often under 100 {micro}m wide and the material's microstructure must be very small to give homogeneous properties across the feature.

  5. DEVELOPMENT AND VALIDATION OF RP-HPLC METHOD FOR SIMULTANEOUS ESTIMATION OF GLIPIZIDE AND METFORMIN IN BULK DRUGS AND TABLET DOSAGE FORM

    OpenAIRE

    D.Triveni; G.V.S Kumar; S B Puranik; N.Sateesh Kumar; K.A.Sridhar

    2012-01-01

    The present work describes development and validation of simple, precise and accurate reversed-phase liquid chromatographic method for simultaneous estimation of glipizide and metformin hydrochloride in both bulk drugs and pharmaceutical dosage forms. The chromatographic separation was achieved on (Enable, symmetry C18, 250mm x 4.6mm, 5μ) analytical column. A mobile phase consisting mixture of potassium dihydrogen phosphate (0.2M, pH 5.8 adjusted with dilute sodium hydroxide) and acetonitrile...

  6. On the Transition from Bulk to Ordered Form of Water: A Theoretical Model to Calculate Adhesion Force Due to Capillary and van der Waals Interaction

    OpenAIRE

    Yaqoob, M.A.; de, Rooij, R.; Schipper, D.J.

    2013-01-01

    The adhesion force due to capillary interaction between two hydrophilic surfaces is strongly dependent on the partial pressure of water and is often calculated using the Kelvin equation. The validity of the Kelvin equation is questionable at low relative humidity (RH) of water, like in high vacuum and dry nitrogen environments, where water is only present as layers of several molecules thick at the surfaces. A model from ordered to bulk form of water has been developed using the Brunauer, Emm...

  7. Integrative microRNA-gene expression network analysis in genetic hypercalciuric stone-forming rat kidney

    Science.gov (United States)

    Lu, Yuchao; Qin, Baolong; Hu, Henglong; Zhang, Jiaqiao; Wang, Yufeng; Wang, Qing

    2016-01-01

    Background. MicroRNAs (miRNAs) influence a variety of biological functions by regulating gene expression post-transcriptionally. Aberrant miRNA expression has been associated with many human diseases. Urolithiasis is a common disease, and idiopathic hypercalciuria (IH) is an important risk factor for calcium urolithiasis. However, miRNA expression patterns and their biological functions in urolithiasis remain unknown. Methods and Results. A multi-step approach combining microarray miRNA and mRNA expression profile and bioinformatics analysis was adopted to analyze dysregulated miRNAs and genes in genetic hypercalciuric stone-forming (GHS) rat kidneys, using normal Sprague-Dawley (SD) rats as controls. We identified 2418 mRNAs and 19 miRNAs as significantly differentially expressed, over 700 gene ontology (GO) terms and 83 KEGG pathways that were significantly enriched in GHS rats. In addition, we constructed an miRNA-gene network that suggested that rno-miR-674-5p, rno-miR-672-5p, rno-miR-138-5p and rno-miR-21-3p may play important roles in the regulatory network. Furthermore, signal-net analysis suggested that NF-kappa B likely plays a crucial role in hypercalciuria urolithiasis. Conclusions. This study presents a global view of mRNA and miRNA expression in GHS rat kidneys, and suggests that miRNAs may be important in the regulation of hypercalciuria. The data provide valuable insights for future research, which should aim at validating the role of the genes featured here in the pathophysiology of hypercalciuria. PMID:27069814

  8. Mechanism of forming defects in roll-to-roll hot embossing of micro-pyramid arrays I: experiments

    Science.gov (United States)

    Yi, Peiyun; Shu, Yunyi; Deng, Yujun; Peng, Linfa; Lai, Xinmin

    2015-10-01

    Roll-to-roll (R2R) hot embossing is a promising process for the continuous fabrication of micro-structures on polymers with high accuracy and high throughput. This paper presents an experimental investigation into forming defects for micro-pyramid arrays during the R2R hot embossing process, aiming at a comprehensive understanding of the mechanism of forming defects as well as providing effective guidance for large-area fabrication of micro-structures on polymers. Four defect modes, the platform-like defect, the collapse-like defect, the high-low defect, and the bubble-like defect, have been discovered so far and the corresponding assessment methods have also been preliminarily established using Polypropylene (PP) as an example. The influence of two key process parameters including mold temperature and feeding speed on forming defects have been systematically investigated as well. It is demonstrated that the forming defects change from a platform-like defect to a collapse-like defect, then to a high-low defect, and finally disappear as the mold temperature increases. In the meantime, a bubble-like defect may occur if the feeding speed exceeds 1.2 m min-1. Besides, the forming defects are also observed in the R2R hot embossing of other polymer materials, such as poly(vinyl chloride), polymethyl-methacrylate and polycarbonate. Analysis of the mechanism of forming defects is beneficial to the understanding of the flow behavior in the R2R hot embossing process and to the realization of process control for high-accuracy replication of large-area polymer films with micro-structures.

  9. Bulk undercooling

    Science.gov (United States)

    Kattamis, T. Z.

    1984-01-01

    Bulk undercooling methods and procedures will first be reviewed. Measurement of various parameters which are necessary to understand the solidification mechanism during and after recalescence will be discussed. During recalescence of levitated, glass-encased large droplets (5 to 8 mm diam) high speed temperature sensing devices coupled with a rapid response oscilloscope are now being used at MIT to measure local thermal behavior in hypoeutectic and eutectic binary Ni-Sn alloys. Dendrite tip velocities were measured by various investigators using thermal sensors or high speed cinematography. The confirmation of the validity of solidification models of bulk-undercooled melts is made difficult by the fineness of the final microstructure, the ultra-rapid evolution of the solidifying system which makes measurements very awkward, and the continuous modification of the microstructure which formed during recalescence because of precipitation, remelting and rapid coarsening.

  10. Brief exposure to nanosized and bulk titanium dioxide forms induces subtle changes in human D384 astrocytes.

    Science.gov (United States)

    De Simone, Uliana; Lonati, Davide; Ronchi, Anna; Coccini, Teresa

    2016-07-01

    Although nanosized-titanium dioxide particles (TiO2NPs)-containing products are constantly placed on the market, little is known about their possible impact on human health, even regarding to CNS effects. In this study, mechanistic pathways, by which TiO2NPs induce cellular damage and death, have been investigated in human (astrocytes-like) D384 cells and comparatively weighed against the effects produced by the bulk counterpart. Cellular signals evaluated by multiple set of in vitro tests after 24h exposure to TiO2NP concentrations (0.5-125μg/ml) were: ROS production, p-p53, p53, p21, Bax, Bcl-2 and caspase 3. TiO2 cellular uptake was also estimated by both light microscopy and ICP-MS. ROS were generated starting at 1.5μg/ml and further increased at the highest concentrations (≥31μg/ml). At the same low concentration, an increased expression of p-p53, p53, p21, Bax, and activated caspase3 were also observed. Parallely, Bcl-2 decreased along with TiO2NP concentration increase. Similar alterations were observed when testing TiO2 bulk: cellular checkpoint perturbations were associated with rising intracellular Ti. The present data demonstrated that low TiO2NP concentrations were capable, after 24h, to induce subtle cellular perturbation in D384 cells after a single cell treatment, supporting the evidence that both oxidative stress and apoptotic mechanisms may occur in this type of CNS cells. PMID:27153796

  11. Development and Validation of Chemometric Assisted Spectrophotometric Technique for Simultaneous Estimation of Cinitapride and Pantoprazole from Bulk and Combined Dosage Form

    Directory of Open Access Journals (Sweden)

    Jasmine Karanjia

    2015-03-01

    Full Text Available This paper describes two sensitive, accurate and precise chemometric spectrophotometric methods for the simultaneous determination of Cinitapride hydrogen tartarate (CNT and Pantoprazole sodium (PANTO in bulk powder and capsules without prior separation. Multivariate calibration chemometric methods are proposed for simultaneous determination of CNT and PANTO. The chemometric methods applied are Principal Component Regression (PCR and Partial Least Squares (PLS. These approaches are successfully applied to quantify both drugs using the information included in the absorption spectra of appropriate solutions. In these multivariate methods, calibration sets of standard samples composed of different mixtures of CNT and PANTO have been designed. The methods were validated according to The International Conference on Harmonization (ICH guidelines. The specificity of the proposed methods was tested using laboratory-prepared mixtures. The developed methods were successfully applied for the determination of CNT and PANTO in bulk powder and dosage form combination.

  12. Cascaded second-harmonic generation, summation of the wave vectors of the bulk defect-deformation waves, and generation of multimode micro- and nanostructures by laser irradiation of solids

    International Nuclear Information System (INIS)

    We consider for the first time three-wave interactions of bulk quasi-static defect-deformation (DD) waves (generation of the second DD harmonic and summation of the wave vectors), similar to three-wave interactions in nonlinear optics and acoustics, leading to cascaded broadening of the spectrum of spatial DD harmonics. Based on the theory developed, we interpret the recently observed effect of laser-induced generation of the bulk periodic structure of silver nanoparticles with a discrete spatial spectrum, extending from micro- to nanometres. (nonlinear optical phenomena)

  13. Cascaded second-harmonic generation, summation of the wave vectors of the bulk defect-deformation waves, and generation of multimode micro- and nanostructures by laser irradiation of solids

    Science.gov (United States)

    Emel'yanov, Vladimir I.

    2011-02-01

    We consider for the first time three-wave interactions of bulk quasi-static defect-deformation (DD) waves (generation of the second DD harmonic and summation of the wave vectors), similar to three-wave interactions in nonlinear optics and acoustics, leading to cascaded broadening of the spectrum of spatial DD harmonics. Based on the theory developed, we interpret the recently observed effect of laser-induced generation of the bulk periodic structure of silver nanoparticles with a discrete spatial spectrum, extending from micro- to nanometres.

  14. A New Technique for Superselective Catheterization of Arteries: Preshaping of a Micro-Guide Wire into a Shepherd's Hook Form

    International Nuclear Information System (INIS)

    We wanted to introduce a new technique for superselective catheterization of arteries with preshaping of a micro-guide wire into a shepherd's hook form, and this is useful for superselection of small arteries branching at an acute angle from a large parent artery for the treatment of tumors and hemorrhages. We developed a superselective catheterization technique by using preshaping of a micro-guide wire into a shepherd's hook form. We encountered six patients in our practice for whom we failed to catheterize the small tumor-feeding arteries that branched at an acute angle from wide parent arteries during chemoembolization of hepatocellular carcinoma; the parent arteries were the right inferior phrenic artery (n = 4) and the left gastric artery (n = 1) from the celiac axis with celiac stenosis due to compression by the median arcuate ligament and the proper hepatic artery from the gastroduodenal artery (n = 1) in a patient who had celiac axis occlusion with collateral circulation via the pancreaticoduodenal arcade from the superior mesenteric artery. In these consecutive six patients, we tested the usefulness of this new technique with employing preshaping of a micro-guide wire into a shepherd's hook form for superselective catheterization of targeted vessels. The target arteries were successfully catheterized and satisfactory transcatheter arterial chemoembolization was performed in all six patients. There were no significant complications such as arterial dissection. We developed a technique that is effective for superselection of vessels with preshaping of micro-guide wire into a shepherd's hook hook form, and we successfully applied it during chemoembolization of hepatocellular carcinoma. This technique can be useful for superselection of small arteries that branch from a large parent artery at acute angles for the treatment of tumors and hemorrhages

  15. Effects of Cu substitution for Fe on the glass-forming ability and soft magnetic properties for Fe-based bulk metallic glasses

    International Nuclear Information System (INIS)

    The effects of Cu substitution for Fe on the glass-forming ability (GFA) and soft magnetic properties for Fe72−xCuxB20Si4Nb4 (x=0.0, 0.2, 0.4, 0.6, 0.8, and 1.0) bulk metallic glasses (BMGs) are investigated. It is found that the investigated BMGs exhibit large GFA as well as excellent soft magnetic properties, and proper substitution of Fe by Cu improves the saturation magnetization, coercive force, and effective permeability without obvious deterioration of the GFA. - Highlights: • Fully glassy rods of Fe72−xCuxB20Si4Nb4 BMGs were produced above 1 mm in diameter. • Investigated BMGs exhibit large glass-forming ability and excellent soft magnetic properties. • Proper Cu substitution improves magnetic properties without obvious deterioration of glass-forming ability

  16. Development and Validation of UV Spectrophotometric method for estimation of Dapoxetine HCL in bulk and dosage Form

    Directory of Open Access Journals (Sweden)

    Kanani Vineeta V

    2013-03-01

    Full Text Available Dapoxetine HCl, a selective serotonin reuptake inhibitor is a novel drug for premature ejaculation and no spectrophotometric method for its estimation has been reported yet. The aim of present work is to develop and validate simple, accurate, sensitive, reproducible and specific spectrophotometric method for the determination of Dapoxetine HCl, in bulk and its pharmaceutical formulations, using methanol as a solvent. The optimum conditions for the analysis of the drug were established and the developed method was validated with respect to linearity, accuracy (recovery, precision, robustness, ruggedness, LOD, LOQ and specificity. The maximum wavelength (% max was found to be 291 nm and a good linearity was observed in the concentration range of 5-60 μg/mL having regression equation, y = 0.0164x – 0.0071 with correlation coefficient of 0.9998. The percentage recovery of Dapoxetine HCl was found to be 99.5489 ±0.1599 and % CV (0.16; n=9 indicated a good precision of the analytical method. The limit of detection (LOD and limit of quantitation (LOQ were 0.0239 μg/mL and 0.0724 μg/mL, respectively. Robustness and ruggedness of the method was performed by using different % max, instruments, apparatus and analysts. The method was found to be simple, accurate, precise, reproducible, economical and robust. Analytical method validation was found to be within an acceptance criteria according to ICH Q2 R1 guidelines. The proposed method can be applied for routine quality control analysis of Dapoxetine HCl.

  17. Application of a Validated Stability-Indicating LC Method for the Simultaneous Estimation of Tapentadol and Its Process-Related Impurities in Bulk and Its Dosage Form

    OpenAIRE

    Singaram Kathirvel; Suggala Venkata Satyanarayana; Garikapati Devalarao

    2013-01-01

    Described is a first reported, simple, rapid, selective, and isocratic stability-indicating RP-LC method for the quantitative determination of tapentadol and its related substances in bulk samples and pharmaceutical dosage forms in the presence of its two process-related impurities. Chromatographic separation was achieved on the reversed phase, Enable column (C18 (5-μm, 250 × 4.6 mm, i.d.)) at ambient temperature using a mobile phase consisting of 0.02 M potassium dihydrogen orthophosphate (a...

  18. DEVELOPMENT AND VALIDATION OF A RP- HPLC METHOD FOR SIMULTANEOUS ESTIMATION OF OMEPRAZOLE AND CINITAPRIDE IN BULK AND CAPSULE DOSAGE FORM

    OpenAIRE

    Nagarajan, G.; Nagesh, P.; Ramana, B.V.; N. Ratna Prasanna; C.Triveni

    2013-01-01

    A simple reversed-phase high-performance liquid chromatographic (RP-HPLC) method has been developed and validated for simultaneous determination of Omeprazole and Cinitapride in bulk and Capsule dosage form. Chromatographic analysis was performed on a Symmetry C8 column (150x 4.5 mm, 5μm) column ambient temperature with a mixture of mixed phosphate buffer and Acetonitrile in the ratio 50:50 (mixed phosphate buffer preparation; 1.625 gm of potassium Dihydrogen phosphate and 0.3 gm of Di potass...

  19. RP-HPLC METHOD DEVELOPMENT AND VALIDATION FOR THE ESTIMATION OF MONTELUKAST SODIUM IN BULK AND PHARMACEUTICAL DOSAGE FORMS

    Directory of Open Access Journals (Sweden)

    B.V.V Ravi kumar

    2012-11-01

    Full Text Available A simple, selective, linear, precise and accurate RP-HPLC method was developed and validated for rapid assay of Montelukast Sodium in pharmaceutical dosage form. Isocratic elution at a flow rate of 1.2 mL min -1 was employed on a symmetry C18 column at ambient temperature. The mobile phase consisted of acetonitrile: phosphate buffer 65:35 (v/v. The UV detection wavelength was at 234 nm. Linearity was observed in concentration range of 1-100 μg/mL. The retention time for Montelukast Sodium was 4.2 min. The method was validated as per the ICH guidelines. The proposed method can be successfully applied for the estimation of Montelukast Sodium in pharmaceutical dosage forms.

  20. Unusual glass-forming ability of new Zr-Cu-based bulk glassy alloys containing an immiscible element pair

    International Nuclear Information System (INIS)

    We herein report the unusual glass-forming ability (GFA) of a new series of quinary Zr48Cu36-xNixAg8Al8 (048Cu36Ag8Al8 alloy. By cooper mold casting, an as-cast glassy rod with a diameter of 30 mm can be easily obtained for the representative alloy Zr48Cu32Ni4Ag8Al8. The possible reasons for the excellent GFA of the new quinary alloys with an immiscible element pair are discussed based on the atomic size distribution, chemical compatibility among the components and atomic structure of glassy alloys. (author)

  1. A NOVEL VALIDATED RP-HPLC METHOD FOR THE DETERMINATION OF ITOPRIDE HYDROCHLORIDE IN BULK AND PHARMACEUTICAL TABLET DOSAGE FORMS

    Directory of Open Access Journals (Sweden)

    P.Ravisankar

    2013-04-01

    Full Text Available A simple, specific, accurate, rapid, inexpensive isocratic Reversed Phase-High Performance Liquid Chromatography (RP-HPLC method was developed and validated for the quantitative determination of Itopride HCl in pharmaceutical tablet dosage forms. RP-HPLC method was developed by using Welchrom C18Column (4.6 X 250mm, 5µm, Shimadzu LC-20AT Prominence Liquid Chromatograph. The mobile phase composed of 10mM Phosphate buffer (pH-3.0, adjusted with triethylamine: acetonitrile (50:50v/v. The flow rate was set to 1.0 mL.min-1 with the responses measured at 235nm using Shimadzu SPD-20A Prominence UV-Vis detector. The retention time of Itopride HCl was found to be 2.650 min. Linearity was established for Itopride HCl in the range of 2-10 µg.mL-1 with correlation coefficient 0.9999. The validation of the developed method was carried out for specificity, linearity, precision, accuracy, robustness, limit of detection, limit of quantitation. The developed method can be used for routine quality control analysis of Itopride HCl in pharmaceutical tablet dosage form.

  2. Gibbs Free Energy and Activation Energy of ZrTiAlNiCuSn Bulk Glass Forming Alloys

    Institute of Scientific and Technical Information of China (English)

    Jianfei SUN; Jun SHEN; Zhenye ZHU; Gang WANG; Dawei XING; Yulai GAO; Bide ZHOU

    2004-01-01

    The Gibbs free energy differences between the supercooled liquid and the crystalline mixture for the (Zr52.5Ti5Al10- Ni14.6Cu17.9)(100-x)/100Snx ·(x=0, 1, 2, 3, 4 and 5) glass forming alloys are estimated by introducing the equation proposed by Thompson, Spaepen and Turnbull. It can be seen that the Gibbs free energy differences decrease first as the increases of Sn addition smaller than 3, then followed by a decrease due to the successive addition of Sn larger than 3, indicating that the thermal stabilities of these glass forming alloys increase first and then followed by a decrease owing to the excessive addition of Sn. Furthermore, the activation energy of Zr52.5Ti5Al10Ni14.6Cu17.9 and (Zr5 2.5Ti5 Al10 Ni14.6 Cu 17.9)0.97Sn3 was evaluated by Kissinger equation. It is noted that the Sn addition increases the activation energies for glass transition and crystallization, implying that the higher thermal stability can be obtained by appropriate addition of Sn.

  3. A new Ti-Zr-Hf-Cu-Ni-Si-Sn bulk amorphous alloy with high glass-forming ability

    International Nuclear Information System (INIS)

    The effect of Sn substitution for Cu on the glass-forming ability was investigated in Ti41.5Zr2.5Hf5Cu42.5-xNi7.5Si1Sn x (x = 0, 1, 3, 5, 7) alloys by using differential scanning calorimetry (DSC) and X-ray diffractometry. The alloy containing 5% Sn shows the highest glass-forming ability (GFA) among the Ti-Zr-Hf-Cu-Ni-Si-Sn system. Fully amorphous rod sample with diameters up to 6 mm could be successfully fabricated by the copper mold casting Ti41.5Zr2.5Hf5Cu37.5Ni7.5Si1Sn5 alloy. The activation energies for glass transition and crystallization for Ti41.5Zr2.5Hf5Cu37.5Ni7.5Si1Sn5 amorphous alloy are both larger than those values for the Sn-free alloy. The enhancement in GFA and thermal stability after the partial replacement of Cu by Sn may be contributed to the strong atomic bonding nature between Ti and Sn and the increasing of atomic packing density. The amorphous Ti41.5Zr2.5Hf5Cu37.5Ni7.5Si1Sn5 alloy also possesses superior mechanical properties

  4. Liquid -to-glass transition in bulk glass-forming Cu55-xZr45Agx alloys using molecular dynamic simulations

    Directory of Open Access Journals (Sweden)

    Celtek M.

    2011-05-01

    Full Text Available We report results from molecular dynamics (MD studies concerning the microscopic structure of the ternary, bulk metallic glass-forming Cu55-x Zr45Agx (x=0,10,20 alloys using tight-binding potentials. Understanding of the nature of Glass Forming Ability (GFA of studied alloys, GFA parameters, glass transition temperature (T-g, melting temperature (T-m, reduced glass transition temperature (T-g/T-m, the supercooled liquid region and other parameters were simulated and compared with experiments. The computed pair distribution functions reproduce well experimental x-ray data of Inoue and co-workers. Structure analysis of the Cu-Zr-Ag alloy based on MD simulation will be also presented

  5. Application of micro X-ray diffraction to investigate the reaction products formed by the alkali silica reaction in concrete structures

    Energy Technology Data Exchange (ETDEWEB)

    Dähn, R.; Arakcheeva, A.; Schaub, Ph.; Pattison, P.; Chapuis, G.; Grolimund, D.; Wieland, E.; Leemann, A. (Ecole); (PSI); (Phase Solutions); (ESRF)

    2015-12-21

    Alkali–silica reaction (ASR) is one of the most important deterioration mechanisms in concrete leading to substantial damages of structures worldwide. Synchrotron-based micro-X-ray diffraction (micro-XRD) was employed to characterize the mineral phases formed in micro-cracks of concrete aggregates as a consequence of ASR. This particular high spatial resolution technique enables to directly gain structural information on ASR products formed in a 40-year old motorway bridge damaged due to ASR. Micro-X-ray-fluorescence was applied on thin sections to locate the reaction products formed in veins within concrete aggregates. Micro-XRD pattern were collected at selected points of interest along a vein by rotating the sample. Rietveld refinement determined the structure of the ASR product consisting of a new layered framework similar to mountainite and rhodesite. Furthermore, it is conceivable that understanding the structure of the ASR product may help developing new technical treatments inhibiting ASR.

  6. Mechanism of forming defects in roll-to-roll hot embossing of micro-pyramid arrays: II. Numerical study

    Science.gov (United States)

    Wang, Jin; Yi, Peiyun; Deng, Yujun; Peng, Linfa; Lai, Xinmin; Ni, Jun

    2015-11-01

    Roll-to-roll (R2R) hot embossing is a continuous imprinting technique for the replication of large-area microstructures. Polymer deformation and recovery behavior is more complicated in this process than in the traditional plate-to-plate mode, especially for the embossing of 3-dimensional (3D) structures, such as the micro-pyramid structure used for reflective film. As a result, forming defects of poor shape and dimensional accuracy are more likely to emerge and are of greater diversity, which may negatively influence product quality and must be eliminated. In our previous experimental study, we have defined several types of forming defects that are commonly seen in embossed micro-pyramid arrays and have discussed the influence of processing parameters on the forming defects systematically. What is presented in this article is devoted to the simulation analysis of the forming mechanism of three typical types of forming defect: the platform-like defect, the bubble-like defect and the collapse-like defect. A 3D finite element model is established for the simulation analysis, in which the polymer resist is treated as a viscoelastic material based on the general Maxwell model. The simulation results clearly reveal the correlation between the forming defects and the processing conditions, indicating that the platform-like defect and the bubble-like defect are caused by material transport problems while the collapse-like defect results from polymer recovery. The underlying mechanisms for the forming defects disclosed in this research can provide effective guidelines for better process control as well as for improved design of the R2R hot embossing system.

  7. Microstructure and hard magnetic properties in bulk rods of Nd60Fe30Al10 glass forming alloys

    International Nuclear Information System (INIS)

    The Nd60Fe30Al10 alloy exhibits a large glass forming ability which allows to obtain relatively thick cast rods containing large volume fractions of amorphous phases. In this work the microstructure and the hard magnetic properties of as-cast rods are characterized. The alloy is processed by suction casting into a chilled copper mould to obtain cylinders 5 mm diameter and 50 mm length. This diameter is selected because it is an upper limit for this processing route, beyond which the hard properties largely deteriorate. A room temperature coercivity of 0.34 T is obtained. The sample microstructure is heterogeneous, with very different size scales near the surface and along the central zone. However, in both regions a large fraction of an amorphous ferromagnetic phase is observed; it is found that paramagnetic nanocrystalline phases - mainly Nd or Nd-rich particles, embedded in the amorphous matrix - are somewhat coarser in the central zone. These larger nanocrystals, less efficient to pin domain walls, are proposed to be responsible for the lower coercive fields observed, as compared with those found in cylinders 1-3 mm diameter where no inhomogeneities are found. This conclusion is supported by microstructure, calorimetric and magnetic observations.

  8. Development and Validation of RP-HPLC Method for the Simultaneous Estimation of Telmisartan and Hydrochlorothiazide in Bulk and Pharmaceutical Dosage Form

    Directory of Open Access Journals (Sweden)

    N. Mukuntha Kumar

    2014-10-01

    Full Text Available A simple, accurate, precise and rapid RP-HPLC method has been developed and validated for the simultaneous estimation of Telmisartan and Hydrochlorothiazide in bulk and fixed-dosage formulation. The separation was achieved on ACE 5 C18 (Length 150 mm × Diameter 4.6 mm Particle size 5 μm column with gradient flow. The mobile phase at a flow rate of 1.5 mL/min consisted of Water: Acetonitrile: Orthophospharic acid (95:5:1 Mobile Phase A and Water: Acetonitrile: Orthophospharic acid (5:95:1 Mobile Phase B (Gradient ratio. The UV detection was carried out at 280 nm. The retention time of Hydrochlorothiazide and Telmisartan was found to be 4.19 and 9.12 min. respectively. The method has been validated for Specificity, Linearity, Accuracy, Precision and Robustness. The calibration curve for Telmisartan and Hydrochlorothiazide were linear from the range of 160.1-480.4 μg/mL and 25.2 - 75.7 μg/mL respectively. The mean recoveries obtained for Telmisartan and Hydrochlorothiazide were 100.1% and 99.8% respectively. The developed method was found to be Specific, accurate, Precise, Robust and rapid for the simultaneous estimation of Telmisartan and Hydrochlorothiazide in bulk Pharmaceutical Dosage Form.

  9. Light extraction from 2D materials using liquid formed micro-lenses

    CERN Document Server

    Woodhead, Christopher S; Noori, Yasir J; Cao, Yameng; Bernardo-Gavito, Ramón; Tovee, Peter; Kozikov, Aleksey; Novoselov, Konstantin; Young, Robert J

    2016-01-01

    The recent discovery of semiconducting two-dimensional materials has led to the prediction of a revolution in the field of optoelectronics, driven by the introduction of a series of new components that are just a few atoms thick. Key remaining challenges for producing practical devices from these materials lie in improving the coupling of light into and out of single atomic layers, and in making these layers robust to the influence of their surrounding environment. We present a solution to tackle both of these problems simultaneously, by deterministically placing a micro-lens directly onto the surface of these materials. These lenses are dynamically tuned to increase the coupling of light, whilst controlling chromatic aberration, before being set in place with UV light. We show that this approach enhances photoluminescence of tungsten diselenide (WSe2) monolayers by up to 300%, and nearly doubles the imaging resolution of the system. Furthermore, this solution fully encapsulates the monolayer, preventing it f...

  10. Effect of Yttrium Addition on Glass-Forming Ability and Magnetic Properties of Fe–Co–B–Si–Nb Bulk Metallic Glass

    Directory of Open Access Journals (Sweden)

    Teruo Bitoh

    2015-06-01

    Full Text Available The glass-forming ability (GFA and the magnetic properties of the [(Fe0.5Co0.50.75B0.20Si0.05]96Nb4−xYx bulk metallic glasses (BMGs have been studied. The partial replacement of Nb by Y improves the thermal stability of the glass against crystallization. The saturation mass magnetization (σs exhibits a maximum around 2 at. % Y, and the value of σs of the alloy with 2 at. % Y is 6.5% larger than that of the Y-free alloy. The coercivity shows a tendency to decrease with increasing Y content. These results indicate that the partial replacement of Nb by Y in the Fe–Co–B–Si–Nb BMGs is useful to simultaneous achievement of high GFA, high σs, and good soft magnetic properties.

  11. DEVELOPMENT AND VALIDATION OF A RP- HPLC METHOD FOR SIMULTANEOUS ESTIMATION OF OMEPRAZOLE AND CINITAPRIDE IN BULK AND CAPSULE DOSAGE FORM

    Directory of Open Access Journals (Sweden)

    G. Nagarajan

    2013-02-01

    Full Text Available A simple reversed-phase high-performance liquid chromatographic (RP-HPLC method has been developed and validated for simultaneous determination of Omeprazole and Cinitapride in bulk and Capsule dosage form. Chromatographic analysis was performed on a Symmetry C8 column (150x 4.5 mm, 5μm column ambient temperature with a mixture of mixed phosphate buffer and Acetonitrile in the ratio 50:50 (mixed phosphate buffer preparation; 1.625 gm of potassium Dihydrogen phosphate and 0.3 gm of Di potassium hydrogen phosphate in 550 mL HPLC grade water, pH= 6.0 adjust with phosphoric acid as mobile phase, at a flow rate of 1.0 mL min-1. UV detection was performed at 287 nm. The method was validated for accuracy, precision, specificity, linearity and sensitivity. The retention times of Omeprazole and Cinitapride were 2.49 and 3.650 min, respectively. Calibration plots were linear over the concentration ranges 5–30 μg mL-1 and 0.75-4.5 μg mL-1 for Omeprazole and Cinitapride, respectively. The Limit of detection was 1.43570 and 0.086 µg mL-1 and the quantification limit was 4.35 µg mL-1 and 0.26 µg mL-1 for Omeprazole and Cinitapride, respectively. The accuracy of the proposed method was determined by recovery studies and found to be 98.62% to 100.37%. Commercial capsule formulation was successfully analyzed using the developed method and the proposed method is applicable to routine analysis of determination of Omeprazole and Cinitapride in bulk and capsule dosage form.

  12. Bulk synthesis by spray forming of Al–Cu–Fe and Al–Cu–Fe–Sn alloys containing a quasicrystalline phase

    International Nuclear Information System (INIS)

    Highlights: • 40 kg Bulk material spray formed based on Al–Cu–Fe and Al–Cu–Fe + Sn. • Deposited Al–Cu–Fe alloy showed single phase bulk quasicrystals(QC). • DSC, XRD and microscopic analyses were done to ascertain the QC nature. • Sn does not help in single phase quasicrystal formation in the deposit. • The possible structural evolution mechanisms have been discussed in detail. - Abstract: In this study, Al–Cu–Fe alloys without and with the addition of Sn and containing a quasicrystalline phase were spray deposited. The spray-deposited bulk materials were characterized in terms of microstructure and hardness. The results showed that the Al62.5Cu25Fe12.5 alloy contains the icosahedral quasicrystalline phase (i-phase) along with the minor λ-Al13Fe4 phase, whereas the Al62.5Cu25Fe12.5 + Sn alloy contains five phases: the major i-phase and the crystalline phases of Sn, θ-Al2Cu, λ-Al13Fe4 and β-AlFe(Cu) phases. These results have been corroborated by X-ray diffraction (XRD), scanning and transmission electron microscopies (SEM and TEM) and differential scanning calorimetry (DSC). The hardness value of the Al–Cu–Fe alloy reached 10.5 GPa at 50 g load and then decreased steadily with increase in the applied load, while that for Al–Cu–Fe–Sn alloy it was originally somewhat lower, then decreased dramatically with slight increase in the applied load but stayed constant with further load increase. The hardness indentations in Al–Cu–Fe alloy introduced cracking in the material, whereas in the case of Al–Cu–Fe–Sn alloy the Sn-rich areas inhibited the crack growth. The present study provides an insight into the mechanism of phase and microstructural evolutions during spray forming of the studied alloys. Furthermore, the role of Sn in terms of microstructure and properties is highlighted

  13. Enhancement of glass-forming ability and bio-corrosion resistance of Zr-Co-Al bulk metallic glasses by the addition of Ag

    International Nuclear Information System (INIS)

    A novel Ni and Cu-free Zr-based bulk metallic glass (BMG) system with enhancement of glass-forming ability (GFA) and bio-corrosion resistance was prepared by copper mold casting by the addition of Ag. It was found that the addition of Ag can considerably enhance the glass-forming ability, as indicated by the increase of the critical glass dimension from 3 mm diameter of the ternary system to over 10 mm in the alloy of Zr53Co18.5Al23.5Ag5. The bio-corrosion behaviors of the Zr-based BMGs in phosphate buffered solution (PBS) were investigated by electrochemical polarization at 310 K. It was found that the addition of appropriate amount of Ag can enhance the corrosion resistance of the BMGs. The X-ray photoelectron spectroscopy (XPS) indicated that the formation of an Al2O3-enriched passive film is mainly responsible for the high corrosion resistance of Ag-bearing alloy in phosphate buffered solution.

  14. Determination of the pore size distribution of micro porous layer in PEMFC using pore forming agents under various drying conditions

    Energy Technology Data Exchange (ETDEWEB)

    Chun, Jeong Hwan; Park, Ki Tae; Jo, Dong Hyun; Lee, Ji Young; Kim, Sang Gon; Kim, Sung Hyun [Department of Chemical and Biological Engineering, Korea University, 1 Anam-Dong, Seongbuk-Ku, Seoul 136-713 (Korea); Lee, Eun Sook; Jyoung, Jy-Young [Energy Research Center, HyupJin I and C Co., LTD, 143-1 Gwelang-Ri, Jungnam-Myun, Hwasung-Si, Kyunggi-Do (Korea)

    2010-10-15

    In this paper, the effect of the pore size distribution of a micro-porous layer (MPL) on the performance of polymer electrolyte membrane fuel cells (PEMFC) was investigated using self-made gas diffusion layers (GDLs) with different MPLs for which the pore size distribution was modified using pore forming agents under different drying conditions. When MPL dried at high temperature, more macro pores, approximately 1,000-20,000 nm in diameter, and less micro pores, below 100 nm, were observed relative to when MPL was dried at low temperature. Self-made GDLs were characterized by a field-emission scanning electron microscope (FE-SEM), mercury porosimetry and self-made gas permeability measurement equipment. The performance of the single cells was measured under two different humidification conditions. The results demonstrate that the optimum pore size distribution of MPL depended on the cell operating humidification condition. The MPL dried at high temperature performed better than the MPL dried at low temperature under a low humidification condition; however, MPL dried at low temperature performed better under a high humidification condition. (author)

  15. Ceramic Films Containing Ca,P and Al Formed on Surface of TC4 Alloy by Micro-Arc Oxidation

    Institute of Scientific and Technical Information of China (English)

    FU Lian-chun; JIANG Zhao-hua; YAO Zhong-ping; SUN Xue-tong

    2004-01-01

    Ceramic films containing Ca, P and Al were prepared on surface of TC4 alloy by micro-arc oxidation using direct current supply to enhance its seawater and plankton corrosion resistance. XRD, EDS, SEM and EPMA were employed to characterize the microstructure and the phase composition. The results showed that 15 μm-ceramic films which was uniform and compact were formed on TC4 . The mass proportion of Ca, P and Al is about 2 : 3 : 4. There was AlPO4 crystal but Ca was not crystal. Cyclic Volt-Ampere test showed that the corrosion resistance of theceramic films was much better than that of the TC4 substrate.

  16. Printing medicines as orodispersible dosage forms: Effect of substrate on the printed micro-structure.

    Science.gov (United States)

    Planchette, C; Pichler, H; Wimmer-Teubenbacher, M; Gruber, M; Gruber-Woelfler, H; Mohr, S; Tetyczka, C; Hsiao, W-K; Paudel, A; Roblegg, E; Khinast, J

    2016-07-25

    We present our recent advancements in developing a viable manufacturing process for printed medicine. Our approach involves using a non-contact printing system that incorporates both piezoelectric- and solenoid valve-based inkjet printing technologies, to deliver both active and inactive pharmaceutical materials onto medical-graded orodispersible films. By using two complimentary inkjet technologies, we were able to dispense an extensive range of fluids, from aqueous drug solutions to viscous polymer coating materials. Essentially, we demonstrate printing of a wide range of formulations for patient-ready, orodispersible drug dosage forms, without the risk of drug degradation by ink heating and of substrate damages (by contact printing). In addition, our printing process has been optimized to ensure that the drug doses can be loaded onto the orally dissolvable films without introducing defects, such as holes or tears, while retaining a smooth surface texture that promotes patient adherence and allows for uniform post-coatings. Results show that our platform technology can address key issues in manufacturing orodispersible drug dosage forms and bring us closer to delivering personalized and precision medicine to targeted patient populations. PMID:26541301

  17. Recent developments in micro- and nanofabrication techniques for the preparation of amorphous pharmaceutical dosage forms.

    Science.gov (United States)

    Qi, Sheng; Craig, Duncan

    2016-05-01

    Nano- and microfabrication techniques have been widely explored in the textile, polymer and biomedical arenas, although more recently these systems have attracted considerable interest as drug delivery vehicles with concomitant considerations of physical characterization, scalability, stability and drug release. In this review, the current thinking with regards to the manufacture of solid amorphous pharmaceutical materials using electrohydrodynamic and gyration-based approaches, melt-spinning approaches, thermal moulding, inkjet printing and 3D printing will be examined in the context of their potential and actual viability as dosage forms. A series of practical examples will be discussed as to how these approaches have been used as means of producing drug delivery systems for a range of delivery systems and treatments. PMID:26776230

  18. Exosomes from bulk and stem cells from human prostate cancer have a differential microRNA content that contributes cooperatively over local and pre-metastatic niche

    Science.gov (United States)

    Sánchez, Catherine A.; Andahur, Eliana I.; Valenzuela, Rodrigo; Castellón, Enrique A.; Fullá, Juan A.; Ramos, Christian G.; Triviño, Juan C.

    2016-01-01

    The different prostate cancer (PCa) cell populations (bulk and cancer stem cells, CSCs) release exosomes that contain miRNAs that could modify the local or premetastatic niche. The analysis of the differential expression of miRNAs in exosomes allows evaluating the differential biological effect of both populations on the niche, and the identification of potential biomarkers and therapeutic targets. Five PCa primary cell cultures were established to originate bulk and CSCs cultures. From them, exosomes were purified by precipitation for miRNAs extraction to perform a comparative profile of miRNAs by next generation sequencing in an Illumina platform. 1839 miRNAs were identified in the exosomes. Of these 990 were known miRNAs, from which only 19 were significantly differentially expressed: 6 were overexpressed in CSCs and 13 in bulk cells exosomes. miR-100-5p and miR-21-5p were the most abundant miRNAs. Bioinformatics analysis indicated that differentially expressed miRNAs are highly related with PCa carcinogenesis, fibroblast proliferation, differentiation and migration, and angiogenesis. Besides, miRNAs from bulk cells affects osteoblast differentiation. Later, their effect was evaluated in normal prostate fibroblasts (WPMY-1) where transfection with miR-100-5p, miR-21-5p and miR-139-5p increased the expression of metalloproteinases (MMPs) -2, -9 and -13 and RANKL and fibroblast migration. The higher effect was achieved with miR21 transfection. As conclusion, miRNAs have a differential pattern between PCa bulk and CSCs exosomes that act collaboratively in PCa progression and metastasis. The most abundant miRNAs in PCa exosomes are interesting potential biomarkers and therapeutic targets. PMID:26675257

  19. 用体硅微加工工艺实现的微纳电械系统%Micro-nano electromechanical system by bulk silicon micromachining

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    @@ 1 Introduction MEMS (Micro ElectroMechanical System) based on semiconductor microfabrication plays important roles for example in the periphery of IT systems. NEMS (Nano ElectroMechanical System) contains nano-scale structures. Sophisticated and high performance systems based on the MEMS and the NEMS have been developed. Packaging and electrical interconnection play an important role in realizing practically applicable systems[1].

  20. DEVELOPMENT AND VALIDATION OF RP-HPLC METHOD FOR SIMULTANEOUS ESTIMATION OF GLIPIZIDE AND METFORMIN IN BULK DRUGS AND TABLET DOSAGE FORM

    Directory of Open Access Journals (Sweden)

    D.Triveni

    2012-09-01

    Full Text Available The present work describes development and validation of simple, precise and accurate reversed-phase liquid chromatographic method for simultaneous estimation of glipizide and metformin hydrochloride in both bulk drugs and pharmaceutical dosage forms. The chromatographic separation was achieved on (Enable, symmetry C18, 250mm x 4.6mm, 5μ analytical column. A mobile phase consisting mixture of potassium dihydrogen phosphate (0.2M, pH 5.8 adjusted with dilute sodium hydroxide and acetonitrile in ratio (60:40 v/v at flow rate of 1.0ml/min and UV detector wavelength 258 nm. The retention time of glipizide and metformin Hcl was found to be 7.9 and 2.5 minutes respectively.The method was successfully validated in accordance to ICH guidelines for accuracy, precision, specificity, linearity, ruggedness and robustness. The linear regression analysis data for calibration plots showed good linear relationship in the concentration range 60-140 μg/mL for both glipizide and metformin hydrochloride.

  1. Application of a Validated Stability-Indicating LC Method for the Simultaneous Estimation of Tapentadol and Its Process-Related Impurities in Bulk and Its Dosage Form

    Directory of Open Access Journals (Sweden)

    Singaram Kathirvel

    2013-01-01

    Full Text Available Described is a first reported, simple, rapid, selective, and isocratic stability-indicating RP-LC method for the quantitative determination of tapentadol and its related substances in bulk samples and pharmaceutical dosage forms in the presence of its two process-related impurities. Chromatographic separation was achieved on the reversed phase, Enable column (C18 (5-μm, 250 × 4.6 mm, i.d. at ambient temperature using a mobile phase consisting of 0.02 M potassium dihydrogen orthophosphate (adjusted to pH 6 with 1 M KOH and acetonitrile (80 : 20, v/v. Flow rate was 1 mL/min and retention time was found to be 7.7 ± 0.05 min. Quantitation was achieved with UV detection at 215 nm based on peak area with linear calibration curves at concentration range 75–300 μg/mL. Forced degradation studies were performed, in accordance with ICH guidelines, using acidic, alkaline, oxidative, neutral, photolytic, and thermal conditions. The drug was found to be stable under all the conditions. The developed method was validated in terms of precision, robustness, recovery, and limits of detection and quantitation. Regression analysis shows an “r” value (correlation coefficient of greater than 0.999 for tapentadol and two potential impurities.

  2. Effect of Cr addition on the glass-forming ability, magnetic properties, and corrosion resistance in FeMoGaPCBSi bulk glassy alloys

    International Nuclear Information System (INIS)

    The effect of Cr addition on the glass-forming ability (GFA), the magnetic properties, and corrosion resistance in Fe-Mo-Ga-P-C-B-Si glassy alloys was investigated. In addition to a slight increase of supercooled liquid region from 50 to 55 K, the substitution of a small amount of Fe with Cr was found to be effective for approaching alloy to a eutectic point, resulting in an increase in GFA. By copper mold casting, bulk glassy alloy rods with diameters up to 3 mm were produced. These glassy alloys exhibit a rather high saturation magnetization of 0.84-1.11 T with good soft-magnetic properties, i.e., low coercive force of 2.3-2.9 A/m, and high effective permeability of 13 360-15 960 at 1 kHz under a field of 1 A/m. The passive current density of the glassy alloy rod in 3 mass % NaCl solution decreased significantly from 1x102 to 3x10-1 A/m2 with an increase in Cr content, indicating that the addition of Cr is effective in enhancing the corrosion resistance

  3. A Stability Indicating RP-HPLC for the Simultaneous Estimation of Hydrochlorothiazide, Amlodipine Besylate and Telemisartan in Bulk and Pharmaceutical Dosage form

    Directory of Open Access Journals (Sweden)

    K. Kalyani

    2016-06-01

    Full Text Available A stability indicating RP-HPLC method was developed for the simultaneous estimation of the anti hypertensive drugs Hydrochlorothiazide, Amlodipine Besylate and Telemisartan. These drugs were subjected to stress studies under different conditions as per ICH guidelines. The separations were carried out using C18 reverse phase column (Agilent ODS UG 5 column, 250mm x 4.5mm,5µm employing Acetonitrile and Acetate buffer (60:40 v/v as mobile phase and pH adjusted to 5 at flow rate of 1ml/min was used for separation, deteced at 333 nm. The drugs were exposed to acidic, alkaline, oxidative, thermal and photolytic conditions and the stressed samples were analyzed by the proposed method. Degradation studies showed that all the three drugs were degraded under oxidative, thermal and photolytic conditions, negligible degradation observed under acidic, alkaline conditions. Analytical validation parameters such as specificity, linearity, accuracy, precision, Ruggedness and Robustness were determined and relative standard deviation of all the parameters were found to be less than 2%. Hence this method was found to be stable indicator that can be used for the routine analysis of these drugs in the bulk and combined tablet dosage form.

  4. In vitro responses of bone-forming MC3T3-E1 pre-osteoblasts to biodegradable Mg-based bulk metallic glasses.

    Science.gov (United States)

    Li, Haifei; He, Wei; Pang, Shujie; Liaw, Peter K; Zhang, Tao

    2016-11-01

    In light of the superior property profile of favorable biocompatibility, proper corrosion/degradation behavior and good mechanical properties, Mg-based bulk metallic glasses (BMGs) are considered as potential biodegradable biomaterials. In the present study, in vitro responses of bone-forming MC3T3-E1 pre-osteoblasts to Mg-Zn-Ca-Sr BMGs were studied in order to assess their feasibility to serve as orthopedic implants. The Mg-Zn-Ca-Sr BMGs were much more capable of supporting cell adhesion and spreading in comparison with crystalline AZ31B Mg alloy. The Mg-Zn-Ca-Sr BMG extracts showed no cytotoxicity to and slightly stimulated the proliferation of pre-osteoblasts. The cells cultured in 100% BMG extracts exhibited lower alkaline phosphatase activity as compared with that in negative control, which could be mainly ascribed to the inhibition of high concentrations of Zn ions on cell differentiation. With decreasing the extract concentration, the inhibitory effect was diminished and the 5% BMG extract exhibited slight stimulation in cell differentiation and mineralization. The high corrosion resistance of BMGs contributed to smaller environmental variations, compared with AZ31B alloy, thus lowering the unfavorable influences on cellular responses. A comparison among the biodegradable Mg-, Ca- and Sr-based BMGs for their biomedical applications is presented. PMID:27524063

  5. The effect of Hf substitution for Zr on glass forming ability and magnetic property of FeCoZrMoBAlY bulk metallic glasses

    International Nuclear Information System (INIS)

    Bulk metallic glasses (BMGs) Fe61Co6Zr8-xHfxMo7B15Al1Y2 (x = 0-8) have been produced by copper mold casting technique using industrial raw materials. The effect of substitution of Hf for Zr on the glass forming ability (GFA) and the magnetic property has been studied by X-ray diffraction (XRD), differential scanning calorimetry (DSC) and superconducting quantum interference device (SQUID). It was found that the substitution of an appropriate amount of Hf for Zr can improve the GFA of the base alloy Fe61Co6Zr8Mo7B15Al1Y2, as demonstrated by the increase in reduced glass transition temperature Trg (=Tg/Tl) and GFA parameters of γ (=Tx/Tg + Tl) and δ (=Tx/Tl - Tg). The Fe61Co6Zr5Hf3Mo7B15Al1Y2 alloy exhibits the highest GFA with the largest Trg (0.612) and δ (1.633), and can cast a fully amorphous rod in 3 mm diameter. The substitution of Hf for Zr also enhances the magnetic properties, as verified by the increase in saturation magnetization (Ms) in the alloy of Fe61Co6Zr3Hf5Mo7B15Al1Y2, whose Ms is approximately 1.5 times higher than that of the base alloy (x = 0) at room temperature. Finally, the effect of the substitution of Hf for Zr on glass forming ability and magnetic properties is discussed

  6. Nano/micro/meso scale interactions in mechanics of pharmaceutical solid dosage forms

    Science.gov (United States)

    Akseli, Ilgaz

    Oral administration in form tablets has been the most common method for delivering drug to the human systemic blood circulation accurately and reproducibly due to its established manufacturing methods and reliability as well as cost. The mechanical criteria for a successful powder-to-tablet processing are good flowability, compressibility and compactibility that are closely related to the mechanical and adhesion properties of the particles and particle strength. In this thesis, air-coupled acoustic and ultrasonic techniques are presented and demonstrated as noncontact and nondestructive methods for physical (mechanical) integrity monitoring and mechanical characterization of tablets. A testing and characterization experimental platform for defect detection, coating thickness and mechanical property determination of tablets was also developed. The presented air-coupled technique was based on the analysis of the transient vibrational responses of a tablet in both temporal and spectral domains. The contact ultrasonic technique was based on the analysis of the propagation speed of an acoustic pulse launched into a tablet and its reflection from the coat-core interface of the tablet. In defect monitoring, the ultimate objective is to separate defective tablets from nominal ones. In the case of characterization, to extract the coating layer thicknesses and mechanical properties of the tablets from a subset of the measured resonance frequencies, an iterative computational procedure was demonstrated. In the compaction monitoring experiments, an instrumented punch and a cylindrical die were employed to extract the elasticity properties of tablets during compaction. To study the effect of compaction kinetics on tablet properties and defect, finite element analyses of single layer and bilayer tablets were performed. A noncontact work-of-adhesion technique was also demonstrated to determine the work-of-adhesion of pharmaceutical powder particles.

  7. Thermal Behavior of Ag Micro/Nano Wires Formed by Low-Temperature Sintering of Ag Nanoparticles

    Science.gov (United States)

    Wang, Wen; Zhong, Yinghui; Li, Dongxue; Wang, Pan; Cai, Yuwei; Duan, Zhiyong

    2015-12-01

    Ag nanoparticles of 30 nm size were deposited onto a Si substrate to form Ag microwires. The nanoparticles were transformed into continuous Ag wires with low-temperature heat treatment at temperatures not higher than 200°C. The morphology, electrical properties, and interface of the sintered Ag nanoparticle wires are described. It is shown that the neck between the nanoparticles begins to form at 150°C, and obvious metallization was found at 170°C. The changes of the crystal structure of the Ag wires at different sintering temperatures were analyzed by x-ray diffractometry. The grain boundary resistance decreased as the crystal grain size increased above 130 nm. The corresponding resistivity of the microstructure is close to that of the bulk. Through the comparison between the Mayadas-Shatzkes's model and experimental data, the range of the grain boundary reflection coefficient C at different temperatures is obtained. This research lays the foundation for the study of nanoimprint lithography with a pseudoplastic metal nanoparticle fluid.

  8. Nano/micro structure fabrication of metal surfaces using the combination of nano plastic forming, coating and roller imprinting processes

    International Nuclear Information System (INIS)

    The fabrication technique using the combination of nano plastic forming, coating and roller imprinting processes to transfer nano/micro patterns onto the surface of metallic materials is developed. In this process, nano plastic forming (NPF) of pure aluminum (Al 99%) using a diamond tool is combined with a coating technique to produce a nickel die. The nickel die is then used for the double plate roller imprinting process to transfer the pattern onto the surface of metallic material. Experimental works with 0.1 N to 1.0 N indentation load variations and 2.5 µm to 7.5 µm pitch variations using a knife edge diamond tool are conducted to study the feasibility of this technique. Comparisons between the master mold, nickel die and rolling result in terms of geometries show good agreement, thus validating the proposed approach for high throughput, low cost, low emission and flexible fabrication technique. The capability of the proposed method is demonstrated in the fabrication of cross, net and brick patterns

  9. Microstructure and elemental composition of electrochemically formed dendrites on lead-free micro-alloyed low Ag solder alloys used in electronics

    International Nuclear Information System (INIS)

    Highlights: • The electrochemical migration is investigated on micro-alloyed low Ag solders. • Transmission electron microscopy is applied to investigate dendrites. • Antimony (micro-alloy) takes part during electrochemical migration processes. • The electrochemical migration model of antimony is established. - Abstract: The Electrochemical Migration (ECM) behaviour of lead-free, micro-alloyed, low Ag solder alloys was investigated using Scanning Transmission Electron Microscopy (STEM), Energy Disperse X-ray Spectroscopy (EDS) and electron diffraction methods. Different solder alloys were investigated by Water Drop (WD) tests to stimulate ECM failure mechanism. After WD tests, differently structured dendrites were formed depending on the solder alloy types. The results showed that micro-alloying components (e.g. Sb) also played role during the ECM processes. The novelty of this study is the demonstration that Sb can take part in the ECM process; the ECM model of Sb is also discussed

  10. Development and validation of UV-spectrophotometric methods for the determination of sumatriptan succinate in bulk and pharmaceutical dosage form and its degradation behavior under varied stress conditions

    Directory of Open Access Journals (Sweden)

    Kudige Nagaraj Prashanth

    2014-04-01

    Full Text Available The aim of the present work is to develop sensitive, simple, accurate, precise and cost effective UV-spectrophotometric methods for the determination of sumatriptan succinate (STS, an anti-migraine drug, in bulk and pharmaceutical dosage form; and also to monitor the degradation behavior of the drug under different ICH prescribed stress conditions. Two methods were developed using different solvents, 0.1 M HCl (method A and acetonitrile (method B. The calibration graphs are linear over the range of 0.2–6.0 μg ml−1 in both the methods with a correlation coefficient (r of 0.9999. The apparent molar absorptivity values are 7.59 × 104 and 7.81 × 104 l mol−1 cm−1, for method A and method B, respectively. The other optical characteristics such as Sandell’s sensitivity, limit of detection (LOD and limit of quantification (LOQ values are also reported. The accuracy and precision of the methods were evaluated based on intra-day and inter-day variations. The accuracy of the methods was further confirmed by standard addition procedure. The degradation behavior of the drug was studied by subjecting STS to an acid and alkaline hydrolysis, oxidative, thermal and UV degradation. This study indicated that STS was degraded in alkaline medium and in oxidative condition. The proposed methods were successfully applied to the determination of STS in tablets and the results obtained are comparable with the official method.

  11. DEVELOPMENT AND VALIDATION OF FIRST ORDER DERIVATIVE UV SPECTROPHOTOMETRIC METHOD FOR SIMULTANEOUS ESTIMATION OF PROPRANOLOL HYDROCHLORIDE AND FLUNARIZINE DIHYDROCHLORIDE IN BULK AND COMBINED DOSAGE FORM

    Directory of Open Access Journals (Sweden)

    Wagh Dipmala Dilip

    2013-06-01

    Full Text Available The first order derivative of UV spectrometry method for simultaneous determination of Propranolol hydrochloride (PRO and Flunarizine dihydrochloride (FLU in pure bulk drug and combined dosage form was found to be simple, accurate, fast, precise and reproducible. The first derivative values measured at 289nm for PRO and 253nm for FLU. The linearity for zero order derivative method was carried out by using the concentration range 4-28µg/ml for PRO and 3-7µg/ml for FLU. The coefficient correlation of PRO and FLU for zero order was found to be 0.9995 and 0.9991 respectively. At zero crossing point of PRO (289nm FLU showed a measurable derivative absorbance where as at the zero crossing point of FLU (253nm, PRO showed appreciable derivative absorbance value. The coefficient correlation of PRO and FLU for first order derivative was found to be 0.9991 and 0.9995 respectively. Precision study showed that % RSD was within the range of acceptable limits (<2. The % recovery for PRO and FLU was found to be in the range of 98-102% and 100-101% respectively. The percentage assay was found to be as 99.5 and 100.12% for PRO and FLU. The results of analysis have been validated as per ICH Q2 (R1 guidelines. This method has applied successfully for the determination of PRO and FLU in its combination with a high percentage of recovery good accuracy and precision.

  12. Simultaneous assessment of phase chemistry, phase abundance and bulk chemistry with statistical electron probe micro-analyses: Application to cement clinkers

    International Nuclear Information System (INIS)

    According to recent developments in cement clinker engineering, the optimization of chemical substitutions in the main clinker phases offers a promising approach to improve both reactivity and grindability of clinkers. Thus, monitoring the chemistry of the phases may become part of the quality control at the cement plants, along with the usual measurements of the abundance of the mineralogical phases (quantitative X-ray diffraction) and the bulk chemistry (X-ray fluorescence). This paper presents a new method to assess these three complementary quantities with a single experiment. The method is based on electron microprobe spot analyses, performed over a grid located on a representative surface of the sample and interpreted with advanced statistical tools. This paper describes the method and the experimental program performed on industrial clinkers to establish the accuracy in comparison to conventional methods. -- Highlights: •A new method of clinker characterization •Combination of electron probe technique with cluster analysis •Simultaneous assessment of phase abundance, composition and bulk chemistry •Experimental validation performed on industrial clinkers

  13. Preparation technology and anti-corrosion performances of black ceramic coatings formed by micro-arc oxidation on aluminum alloys

    Institute of Scientific and Technical Information of China (English)

    CHEN Ling; HAN Jing; YU Shengxue

    2006-01-01

    In order to prepare ornamental and anti-corrosive coating on aluminum alloys, preparation technology of black micro-arc ceramic coatings on Al alloys in silicate based electrolyte was studied.The influence of content of Na2WO4 and combination additive in solution on the performance of black ceramic coatings was studied; the anticorrosion performances of black ceramic coatings were evaluated through whole-immersion test and electrochemical method in 3.5% NaCl solution at different pH value; SEM and XRD were used to analyze the surface morphology and phase constitutes of the black ceramic coatings.Experimental results indicated that, without combination additives, with the increasing of Na2WO4 content in the electrolyte, ceramic coating became darker and thicker, but the color was not black; after adding combination additive, the coating turned to be black; the black ceramic coating was multi-hole form in surface.There was a small quantity of tungsten existing in the black ceramic coating beside α-Al2O3 phase and β-Al2O3 phase.And aluminum alloy with black ceramic coating exhibited excellent anti-corrosion property in acid, basic and neutral 3.5% NaCl solution.

  14. Zn/Ag micro-galvanic couples formed on titanium and osseointegration effects in the presence of S. aureus.

    Science.gov (United States)

    Jin, Guodong; Qin, Hui; Cao, Huiliang; Qiao, Yuqin; Zhao, Yaochao; Peng, Xiaochun; Zhang, Xianlong; Liu, Xuanyong; Chu, Paul K

    2015-10-01

    Titanium implants possessing simultaneous osseointegration and antibacterial ability are desirable. In this work, three types of Zn/Ag micro-galvanic couples are fabricated on titanium by plasma immersion ion implantation to investigate the osseointegration and antibacterial effects as well as the involved mechanisms. The in vitro findings disclose enhanced proliferation, osteogenic differentiation, and gene expressions of the rat bone mesenchymal stem cells (rBMSCs), as well as good antibacterial ability on all three micro-galvanic couples. Excellent antimicrobial ability is also observed in vivo and the micro-CT and histological results reveal notable osseointegration in vivo despite the presence of bacteria. The Zn/Ag micro-galvanic couple formed on Zn/Ag dual-ion co-implanted titanium shows the best osseointegration as well as good antibacterial properties in vivo obtained from a rabbit tibia model. The difference among the three Zn/Ag micro-galvanic couples can be ascribed to the contact between the Ag NPs and Zn film, which affects the corrosion process. Our results indicate that the biological behavior can be controlled by the corrosion process of the Zn/Ag micro-galvanic couples. PMID:26141835

  15. Hunting liquid micro-pockets in snow and ice: Phase transition in salt solutions at the bulk and interface with X-ray photoelectron spectroscopy.

    Science.gov (United States)

    Bartels-Rausch, Thorsten; Orlando, Fabrizio; Kong, Xiangrui; Waldner, Astrid; Artiglia, Luca; Ammann, Markus; Huthwelker, Thomas

    2016-04-01

    Sea salt, and in particular chloride, is an important reactant in the atmosphere. Chloride in air-borne sea salt aerosol is - once chemically converted to a molecular halogen (Cl2, BrCl) and released to the atmosphere - well known as important atmospheric reactant, driving large-scale changes to the atmospheric composition and in particular to ozone levels in remote areas, but also in coastal mega cities. Similar chemistry has been proposed for sea salt deposits in polar snow covers. A crucial factor determining the overall reactivity is the local physical environment of the chloride ion. For example, the reactivity of liquid aerosols decreases significantly upon crystallization. Surprisingly, the phases of NaCl-containing systems are still under debate, partially due to the limited availability of in situ measurements directly probing the local environment at the surface of frozen NaCl-water binary systems. Using core electron spectroscopy of the oxygen atoms in water, we previously showed that these systems follow the phase rules at the air-ice interface. This finding contrasts some earlier observations, where the presence of liquid below the eutectic point of bulk solutions was postulated. In the present study, we present new electron yield near-edge X-ray absorption fine structure spectroscopy (NEXAFS) data obtained at near-ambient pressures up to 20 mbar of NaCl frozen solutions. The method is sensitive to small changes in the local environment of the chlorine atom. The measurements were performed at the PHOENIX beamline at SLS. The study indicates frapant differences in the phases of NaCl - water mixtures at temperatures blow the freezing point for the surface of the ice vs. the bulk. This has significant impact on modelling chemical reactions in snow or ice and it's environmental consequences.

  16. SIMULTANEOUS ESTIMATION AND VALIDATION OF PARACETAMOL, CHLORPHENIRAMINE MALEATE AND PHENYLEPHRINE HYDROCHLORIDE IN BULK AND TABLET DOSAGE FORM BY USING DIFFERENT SPECTROPHOTOMETRIC METHOD

    Directory of Open Access Journals (Sweden)

    Hapse Sandip Appasaheb

    2013-10-01

    Full Text Available A simple, precise, accurate and economic simultaneous UV spectrophotometric method has been developed for the estimation of Paracetamol, Chlorpheniramine Maleate and Phenylephrine Hydrochloride in combination in bulk mixture and tablet. The estimation was based upon measurement of absorbance at absorbance maxima of 258 nm, 262 nm and 239 nm for Paracetamol, Chlorpheniramine Maleate and Phenylephrine Hydrochloride in methanol, respectively in bulk mixture and tablet. The Beer Lambert's law obeyed in the concentration range 4-24 μg/ml, for Paracetamol, Chlorpheniramine Maleate and Phenylephrine Hydrochloride respectively. The estimation of bulk mixture and tablet was carried out by simultaneous equation, Q-analysis and area under curve method for estimation of Paracetamol, Chlorpheniramine Maleate and Phenylephrine Hydrochloride. Recovery study was performed to confirm the accuracy of the methods. The methods were validated as per ICH guidelines.

  17. Mechanical spectra of glass-forming liquids. I. Low-frequency bulk and shear moduli of DC704 and 5-PPE measured by piezoceramic transducers

    DEFF Research Database (Denmark)

    Hecksher, Tina; Olsen, Niels Boye; Nelson, Keith Adam;

    2013-01-01

    We present dynamic shear and bulk modulus measurements of supercooled tetraphenyl-tetramethyl-trisiloxane (DC704) and 5-phenyl-4-ether over a range of temperatures close to their glass transition. The data are analyzed and compared in terms of time-temperature superposition (TTS), the relaxation ...

  18. Development and Validation of Chemometric Assisted Spectrophotometric Technique for Simultaneous Estimation of Cinitapride and Pantoprazole from Bulk and Combined Dosage Form

    OpenAIRE

    Jasmine Karanjia

    2015-01-01

    This paper describes two sensitive, accurate and precise chemometric spectrophotometric methods for the simultaneous determination of Cinitapride hydrogen tartarate (CNT) and Pantoprazole sodium (PANTO) in bulk powder and capsules without prior separation. Multivariate calibration chemometric methods are proposed for simultaneous determination of CNT and PANTO. The chemometric methods applied are Principal Component Regression (PCR) and Partial Least Squares (PLS). These approaches are succes...

  19. Coextrusion forming characteristics of novel Cu alloy/bulk metallic glass composite%新型铜合金/非晶复合材料的挤压成形特性

    Institute of Scientific and Technical Information of China (English)

    刘勇; 张丽; 郭洪民; 杨湘杰

    2011-01-01

    A novel Cu alloy/bulk metallic glass (BMG) composite was fabricated through the coextrusion process, based on the excellent thermoplastic forming characteristics of BMG in the supercooled liquid region (SLR). The Cu-based amorphous Cu40Zr44Ag8Al8 and pure Cu alloy were selected as components. The Cu alloy/BMG composite bar was easily fabricated at extrusion temperature of 703 K and extrusion speed of 0.4 mm/min. The morphology and structure of the core BMG before and after the coextrusion with Cu were characterized by optical microscopy (OM), X-ray diffractometry (XRD), differential scanning calorimetry(DSC) and microhardness(HV). The results indicate that the core BMG can reach the approximately uniform distribution of the dimension after suffering the shortly inhomogeneous distribution of the dimension in the initial stages of coextrusion. Combining the analysis of XRD, DSC and micro hardness (HV), it can be concluded that the crystallization of core BMG does not occur after the coextrusion with Cu at 703 K.%基于大块非晶在过冷液相区间具有较好的热塑性成形特点,选择铜基非晶Cu40Zr44Ag8Al8和铜合金,通过挤压成形工艺,制备出一种新型的铜合金/非晶复合材料;在703 K和挤压速度为0.4 mm/min下对该复合材料进行挤压,获得铜合金、非晶复合材料棒材.通过光学金相(OM)、X射线衍射(XRD)、示差扫描量热分析(DSC)和维氏硬度测试(HV)对挤压变形前、后芯部非晶进行形貌观察和结构分析.结果表明:芯部非晶在挤压前期呈不均匀分布,而后分布非常均匀;结合XRD、DSC和硬度的结果分析,在703 K下挤压后,芯部非晶没有发生晶化.

  20. Perubahan Lingkungan Mikro pada Berbagai Penutupan Lahan Hasil Revegetasi (Micro Environmental Change in Various Form Land Cover Revegetation)

    OpenAIRE

    Dadan Mulyana; Sri Wilarso Budi R; Basuki Wasis; Arum Sekar Wulandari

    2011-01-01

    Evaluation of land rehabilitation (revegetation) activities is necessary for measuring the extent of success of the ongoing activities in rehabilitating and recovering degraded lands. One way for evaluating the success of land rehabilitation (revegetation) is by determining the changes of micro enviroment.  The objective of this research was to study the changes of micro environment in  various types of revegetated land cover, including scrub/bush land (SB), agricultural land (TP), monocultur...

  1. DEVELOPMENT AND VALIDATION OF STABILITY-INDICATING TLC-DENSITOMETRY METHOD FOR THE SIMULTANEOUS DETERMINATION OF EPERISONE HYDROCHLORIDE AND PARACETAMOL IN BULK AND TABLET DOSAGE FORM

    Directory of Open Access Journals (Sweden)

    Pritam S. Jain

    2013-08-01

    Full Text Available A rapid and reproducible stability indicating TLC-densitometric method was developed for the determination of eperisone hydrochloride and paracetamol in presence of their degraded products in bulk drugs and pharmaceutical formulations. Uniform degradation conditions were maintained by refluxing reaction mixtures for 8 h at 60°C including acidic, alkaline hydrolysis. Oxidation at room temperature, photochemical and dry heating degradation studies were also carried out. A sensitive and robust stability indicating TLC-densitometric method for simultaneous quantification of eperisone hydrochloride and paracetamol in bulk drugs and pharmaceutical formulations has been developed and validated. Separation was done on TLC aluminum sheets, pre-coated with silica gel 60F-254 using ethyl acetate: toluene: methanol (2:2:1 v/v/v. Spots at Rf 0.42 ± 0.04 and Rf 0.60 ± 0.02 were recognized as paracetamol and eperisone hydrochloride, respectively. Densitometric analysis of chromatoplates was carried out in absorbance mode at isobastic point 260 nm. The developed method was optimized and validated as per ICH guidelines. Method was found linear over the concentration range of 100-350 ng / spot for eperisone hydrochloride and 600-2100 ng / spot for paracetamol with the correlation coefficient (r2 of 0.999 and 0.999 for eperisone hydrochloride and paracetamol, respectively. The developed TLC method can be applied for routine analysis of eperisone hydrochloride and paracetamol in presence of their degraded products in their combined pharmaceutical formulations.

  2. Perubahan Lingkungan Mikro pada Berbagai Penutupan Lahan Hasil Revegetasi (Micro Environmental Change in Various Form Land Cover Revegetation

    Directory of Open Access Journals (Sweden)

    Dadan Mulyana

    2011-07-01

    Full Text Available Evaluation of land rehabilitation (revegetation activities is necessary for measuring the extent of success of the ongoing activities in rehabilitating and recovering degraded lands. One way for evaluating the success of land rehabilitation (revegetation is by determining the changes of micro enviroment.  The objective of this research was to study the changes of micro environment in  various types of revegetated land cover, including scrub/bush land (SB, agricultural land (TP, monoculture teak (JM and mixed crops (TC in Ciliwung upper watershed. Research results showed that the highest air temperature and soil temperature were  obtained at SB, respectively at 32.8 0C and 26.5 0C, and the lowest at TC, respectively at 28.1 0C and 20.7 0C. Relative humidity and soil moisture were highest at TC (72.3% and 96% and lowest at SB (60.8%, and the lowest soil moisture occurred at JM (45%.  The highest infiltration rate occurred on TP (475.5 mm h-1, very rapid, followed by JM (117 mmh-1, fast and TC (80 mm h-1, and the lowest at SB (17.65 mm h-1, medium slow.  Erosion reductions occurred after 6 years of the revegetation activities with the following  results:TC  (96,676.1 ton year-1 ha-1, JM (10,790 ton year-1 ha-1, TP and SB (52,867.9 ton year-1 ha-1 and 24,612.6 ton year-1 ha-1.  The micro environments for all land cover types were better after revegetation activities.Keywords: micro environment, land cover, erosion, infiltration, upper watershed

  3. Enhanced glass-forming ability of FeCoBSiNb bulk glassy alloys prepared using commercial raw materials through the optimization of Nb content

    International Nuclear Information System (INIS)

    We optimized the alloy compositions by modifying the Nb content in [(Fe0.5Co0.5)0.75B0.20Si0.05]100-xNbx(x=3.6-4.4) alloy system. As a result, it was found that the Nb content of 4.3 at. % was effective for approaching alloy to a eutectic point. By copper mold casting, [(Fe0.5Co0.5)0.75B0.20Si0.05]95.7Nb4.3 bulk glassy alloy rods with diameters up to 4 mm were successfully synthesized even using commercial raw materials. These glassy alloys exhibit a rather high saturation magnetization of 0.77 T and low coercive force of 2.5 A/m.

  4. Ferromagnetic bulk glassy alloys

    International Nuclear Information System (INIS)

    This paper deals with the review on the formation, thermal stability and magnetic properties of the Fe-based bulk glassy alloys in as-cast bulk and melt-spun ribbon forms. A large supercooled liquid region over 50 K before crystallization was obtained in Fe-(Al, Ga)-(P, C, B, Si), Fe-(Cr, Mo, Nb)-(Al, Ga)-(P, C, B) and (Fe, Co, Ni)-Zr-M-B (M=Ti, Hf, V, Nb, Ta, Cr, Mo and W) systems and bulk glassy alloys were produced in a thickness range below 2 mm for the Fe-(Al, Ga)-(P, C, B, Si) system and 6 mm for the Fe-Co-(Zr, Nb, Ta)-(Mo, W)-B system by copper-mold casting. The ring-shaped glassy Fe-(Al, Ga)-(P, C, B, Si) alloys exhibit much better soft magnetic properties as compared with the ring-shaped alloy made from the melt-spun ribbon because of the formation of the unique domain structure. The good combination of high glass-forming ability and good soft magnetic properties indicates the possibility of future development as a new bulk glassy magnetic material

  5. 微热弯成形的微位移计算机视觉测量方法%Micro-displacement measurement of computer vision for micro-bending forming

    Institute of Scientific and Technical Information of China (English)

    孙林林; 李伯全; 蔡孝燕; 许桢英

    2011-01-01

    The focus of the work is to build a micro-displacement measurement of computer vision for micro-bending forming with high measuring accuracy. Matlab was utilized to write camera calibration program, and the internal and external parameters of the camera was calculated. The method made use of OpenCV to conduct gray level transformation , image binary, Canny edge extraction, and adopted sequential similarity detection algorithm to carry out template matching. Results indicate that the measurement method of micro-displacement is simple in operation with high efficiency.%为实现微热弯成形系统中微位移的高精度测量,构建了微位移计算机视觉测量系统.应用Matlab编写摄像机标定程序并计算摄像机的内外参数,利用OpenCV对被测对象的图像进行灰度化、二值化和Canny边缘提取,采用序贯相似性检测算法(SSDA)进行模板匹配,实现了热弯曲成形过程中模具与工件位置微位移的实时在线检测.实验结果表明,该系统对微位移的测量具有操作简单、高效的特点.

  6. Closed-form expressions correlating exciton transport and interfacial charge carrier generation with the donor/acceptor morphology in organic bulk heterojunction solar cells

    International Nuclear Information System (INIS)

    Organic bulk heterojunction (BHJ) solar cells are frequently modeled with effective-medium device models; these models, however, do not resolve the relation between excitonic processes in the donor/acceptor (D/A) blend and the D/A morphology. In this context, we derive a simple analytical model to relate the interfacial exciton flux and the volumetric generation rate of interfacial electron–hole pairs with the morphological characteristics of a D/A blend. Our approach does not require explicit morphological information of the D/A blend, except for the specific interfacial area and the blending ratio between donor and acceptor materials, both of which can be assessed experimentally. The expressions are verified with numerical simulations based on randomly generated three-dimensional D/A morphologies – overall, good agreement is found. The analytical expressions developed in this paper can easily be integrated into existing effective-medium device models, allowing them to capture the effect of exciton transport and morphology on free charge carrier generation in more detail. These expressions potentially allow morphological features in a D/A blend to be optimized within a fast, 1D computational framework

  7. Micro-scale truss structures with three-fold and six-fold symmetry formed from self-propagating polymer waveguides

    International Nuclear Information System (INIS)

    A process for interconnecting a three-dimensional pattern of self-propagating polymer waveguides was used to form micro-truss structures with two new unit cell architectures. The structures were formed using a two-dimensional mask with a hexagonal pattern of apertures. Distinct unit cell architectures were possible by exposing the mask to a different number of incident UV exposure beams, which are used to form the waveguides. One unit cell design featured three intersecting waveguides per node, resulting in a structure with three-fold symmetry. The second unit cell design had six-fold symmetry and was characterized by primary nodes with six intersecting waveguides and secondary nodes with two intersecting waveguides. Compression loading experiments were conducted on micro-truss samples with comparable relative density values (ρ/ρs = 6.5%), but different unit cell architectures. The addition of secondary nodes in the structures based on the second design led to an increase in compressive modulus of up to 70% and an average increase in peak strength of 42%. The increase in compressive strength and modulus was attributed to a reduction in the truss-member slenderness ratio achieved through increased waveguide connectivity

  8. Superparamagnetic iron oxide nanoparticle attachment on array of micro test tubes and microbeakers formed on p-type silicon substrate for biosensor applications

    Directory of Open Access Journals (Sweden)

    Raja Sufi

    2011-01-01

    Full Text Available Abstract A uniformly distributed array of micro test tubes and microbeakers is formed on a p-type silicon substrate with tunable cross-section and distance of separation by anodic etching of the silicon wafer in N, N-dimethylformamide and hydrofluoric acid, which essentially leads to the formation of macroporous silicon templates. A reasonable control over the dimensions of the structures could be achieved by tailoring the formation parameters, primarily the wafer resistivity. For a micro test tube, the cross-section (i.e., the pore size as well as the distance of separation between two adjacent test tubes (i.e., inter-pore distance is typically approximately 1 μm, whereas, for a microbeaker the pore size exceeds 1.5 μm and the inter-pore distance could be less than 100 nm. We successfully synthesized superparamagnetic iron oxide nanoparticles (SPIONs, with average particle size approximately 20 nm and attached them on the porous silicon chip surface as well as on the pore walls. Such SPION-coated arrays of micro test tubes and microbeakers are potential candidates for biosensors because of the biocompatibility of both silicon and SPIONs. As acquisition of data via microarray is an essential attribute of high throughput bio-sensing, the proposed nanostructured array may be a promising step in this direction.

  9. The effect of nitrogen on the glass-forming ability and micro-hardness of Fe-Cr-Mn-N amorphous alloys prepared by mechanical alloying

    International Nuclear Information System (INIS)

    In this research, the effect of nitrogen on the thermal behavior and micro-hardness of Fe-Cr-Mn-N amorphous alloys synthesized by mechanical alloying under a nitrogen atmosphere has been considered. The characterization of the as-milled powders by X-ray diffraction, scanning and transmission electron microscopy showed that a fully amorphous structure has been developed by the mechanical alloying process. Differential scanning calorimetry results revealed that the glass transition temperatures and onset crystallization temperatures are in the ranges of 764-766 K and 855-861 K, respectively, for the alloys containing 3.45-3.95 wt.% nitrogen, giving considerable supercooled liquid regions of 91-95 K. The amorphous alloys exhibited an increase in the glass-forming ability by increasing the nitrogen amount. Furthermore, the as-milled amorphous powders showed high micro-hardness values of nearly 1015-1070 HV with an elastic-plastic deformation feature during the indentations. A decrease in the micro-hardness values was found by increasing the nitrogen content.

  10. Modeling of contact theories for the manipulation of biological micro/nanoparticles in the form of circular crowned rollers based on the atomic force microscope

    International Nuclear Information System (INIS)

    cylindrical and circular crowned roller shaped micro/nanoparticles. The results of models indicate that the contact model of Hertz achieves the largest amount of deformation for the DNA nanoparticle in cylindrical form and the contact model of Heoprich achieves the largest deformation for the circular crowned roller shaped DNA. Of course, this finding is not always true for the other nanoparticles; and considering the mechanical and environmental characteristics, different results can be obtained. Also, by comparing the deformations of different types of nanoparticles, it was determined that the platelet type nanoparticles display the highest degree of deformation in all the considered models, due to their particular mechanical characteristics

  11. Modeling of contact theories for the manipulation of biological micro/nanoparticles in the form of circular crowned rollers based on the atomic force microscope

    Science.gov (United States)

    Korayem, M. H.; Khaksar, H.; Taheri, M.

    2013-11-01

    cylindrical and circular crowned roller shaped micro/nanoparticles. The results of models indicate that the contact model of Hertz achieves the largest amount of deformation for the DNA nanoparticle in cylindrical form and the contact model of Heoprich achieves the largest deformation for the circular crowned roller shaped DNA. Of course, this finding is not always true for the other nanoparticles; and considering the mechanical and environmental characteristics, different results can be obtained. Also, by comparing the deformations of different types of nanoparticles, it was determined that the platelet type nanoparticles display the highest degree of deformation in all the considered models, due to their particular mechanical characteristics.

  12. Non-isothermal crystallization kinetics and glass-forming ability of Ti41Zr25Be28Fe6 bulk metallic glass investigated by differential scanning calorimetry

    Science.gov (United States)

    Gong, Pan; Zhao, Shaofan; Wang, Xin; Yao, Kefu

    2015-07-01

    The non-isothermal crystallization kinetics and glass-forming ability of Ti41Zr25Be28Fe6 glassy alloy were investigated by differential scanning calorimetry. The activation energies corresponding to the characteristic temperatures have been calculated by Kissinger and Ozawa equations. Based on Kissinger-Akahira-Sunose and Ozawa-Flynn-Wall models, it has been found that the local activation energy is higher at the beginning of the crystallization process for the first exothermic peak. The local Avrami exponent indicates that the first-step crystallization is mainly a high-dimensional nucleation and growth with an increasing nucleation rate. According to the calculated fragility index, Ti41Zr25Be28Fe6 alloy can be classified as "strong glass former." The studied alloy also possesses a critical size up to centimeter order, and the high glass-forming ability is probably related to the relatively low Gibbs energy difference between the liquid and crystalline states. The critical cooling rate of Ti41Zr25Be28Fe6 glassy alloy has also been determined using Barandiaran-Colmenero's method.

  13. Equilibrium viscosity of the Zr41.2Ti13.8Cu12.5Ni10Be22.5 bulk metallic glass-forming liquid and viscous flow during relaxation, phase separation, and primary crystallization

    International Nuclear Information System (INIS)

    The flow behavior of the supercooled Zr41.2Ti13.8Cu12.5Ni10Be22.5 bulk metallic glass-forming liquid is studied in isothermal three-point beam-bending experiments. The experiments lead to the determination of the equilibrium viscosity as a function of temperature. Comparison with other glass-forming liquids shows that the Zr41.2Ti13.8Cu12.5Ni10Be22.5, alloy is a strong liquid, similar to sodium silicate liquids. Flow measurements during phase separation and subsequent formation of crystals embedded in a non-crystalline matrix reveal a dramatic slowdown of the kinetics of the matrix that is expressed in an increase of the viscosity by several orders of magnitude

  14. Investigation of rare earth sealing of porous micro-arc oxidation coating formed on AZ91D magnesium alloy

    Institute of Scientific and Technical Information of China (English)

    M.Laleh; Farzad Kargar; A.Sabour Rouhaghdam

    2012-01-01

    Magnesium and its alloys have been used in many industries,but they are reactive and require protection against aggressive environments.In this study,oxide coatings were applied on AZ91D magnesium alloy using micro-arc oxidation (MAO) process.Then,in order to seal the pores of the MAO coatings,the samples were immersed in cerium bath for different times.The surface morphologies and compositions of the coatings were analyzed by scanning electron microscopy (SEM) and X-ray energy dispersive spectroscopy (EDS),respectively.The corrosion behavior of the coatings was investigated with electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization tests in 3.5 wt.% NaCl solution.The amount of the porosity of the coating was measured by electrochemical method.It was found that the sealing treatments by immersion in cerium bath successfully sealed the pores of the MAO coatings.The results of the corrosion tests showed that the MAO coating which was sealed in Ce bath for 10 min enhanced the corrosion resistance of the substrate significantly.Furthermore,this coating had the lowest amount of the porosity among the coatings.

  15. Stability-indicating UHPLC method for determination of nevirapine in its bulk form and tablets: identification of impurities and degradation kinetic study.

    Science.gov (United States)

    Reis, Naialy Fernandes Araújo; de Assis, Jéssica Camille; Fialho, Sílvia Ligório; Pianetti, Gerson Antônio; Fernandes, Christian

    2016-07-15

    Nevirapine (NVP), a non-nucleoside reverse transcriptase inhibitor, is a drug widely used in the treatment of Acquired Immunodeficiency Syndrome (AIDS). The evaluation of NVP stability is of fundamental importance in order to guarantee drug product efficacy, safety and quality. In this study, NVP active pharmaceutical ingredient (API) and tablets were subjected to a detailed study of forced degradation, employing several degrading agents (acid, alkaline, water, metal ions, humidity, heat, light and oxidation agents). In order to determine NVP and the degradation products formed, a stability-indicating UHPLC method using fused core column was developed and validated. The separation was carried out using a Poroshell 120C18 column (100×2.1mm i.d.; 2.7μm particle size) and the mobile phase was composed of acetonitrile and water in a gradient elution, at a flow rate of 0.2ml/min. Chemical structures and mechanisms for the formation of three degradation products were proposed by means of LC/MS-MS. Also, NVP degradation kinetic was studied and its order of degradation evaluated. NVP was degraded in acidic and oxidative conditions and the degradation profile for NVP tablets and API were similar. The stability-indicating method proved to be selective for NVP and its degradation products. Calibration curve was linear in the range of 8-48μg/ml and the method showed to be precise, accurate and robust for both NVP API and tablets, with detection and quantification limits of 0.092μg/ml and 0.174μg/ml, respectively. PMID:27179642

  16. Characterization of Zeolite in Zeolite-Geopolymer Hybrid Bulk Materials Derived from Kaolinitic Clays

    Directory of Open Access Journals (Sweden)

    Hayami Takeda

    2013-05-01

    Full Text Available Zeolite-geopolymer hybrid materials have been formed when kaolin was used as a starting material. Their characteristics are of interest because they can have a wide pore size distribution with micro- and meso-pores due to the zeolite and geopolymer, respectively. In this study, Zeolite-geopolymer hybrid bulk materials were fabricated using four kinds of kaolinitic clays (a halloysite and three kinds of kaolinite. The kaolinitic clays were first calcined at 700 °C for 3 h to transform into the amorphous aluminosilicate phases. Alkali-activation treatment of the metakaolin yielded bulk materials with different amounts and types of zeolite and different compressive strength. This study investigated the effects of the initial kaolinitic clays on the amount and types of zeolite in the resultant geopolymers as well as the strength of the bulk materials. The kaolinitic clays and their metakaolin were characterized by XRD analysis, chemical composition, crystallite size, 29Si and 27Al MAS NMR analysis, and specific surface area measurements. The correlation between the amount of zeolite formed and the compressive strength of the resultant hybrid bulk materials, previously reported by other researchers was not positively observed. In the studied systems, the effects of Si/Al and crystalline size were observed. When the atomic ratio of Si/Al in the starting kaolinitic clays increased, the compressive strength of the hybrid bulk materials increased. The crystallite size of the zeolite in the hybrid bulk materials increased with decreasing compressive strength of the hybrid bulk materials.

  17. (Ba1-xKx)(Cu2-xMnx)Se2: A copper-based bulk form diluted magnetic semiconductor with orthorhombic BaCu2S2-type structure

    Science.gov (United States)

    Guo, Shengli; Man, Huiyuan; Gong, Xin; Ding, Cui; Zhao, Yao; Chen, Bin; Guo, Yang; Wang, Hangdong; Ning, F. L.

    2016-02-01

    A new copper-based bulk form diluted magnetic semiconductor (DMS) (Ba1-xKx)(Cu2-xMnx)Se2 (x=0.075, 0.10, 0.125, and 0.15) with TC ∼18 K has been synthesized. K substitution for Ba introduces hole-type carriers, while Mn substitution for Cu provides local spins. Different from previous reported DMSs, this material crystallizes into orthorhombic BaCu2S2-type crystal structure. No ferromagnetism is observed when only doping Mn, and clear ferromagnetic transition and hysteresis loop have been observed as K and Mn are codoped into the parent compound BaCu2Se2.

  18. Research progress of forming process of bipolar plate for micro fuel cell%微型燃料电池双极板成形工艺的研究进展

    Institute of Scientific and Technical Information of China (English)

    许桢英; 张园园; 王匀; 丁盛; 尹必峰

    2015-01-01

    The micro fuel cellis the mainstream of the future mobile power, but the forming process of bipolar plate hinders the application of fuel cell. The forming process of bipolar plates for micro fuel cellwas introduced, including regular plastic deformation means based on micro stamping and so on,micro processing technology based on MEMS and non-traditional machining process. The development trend of forming technology of future micro fuel cellbipolar plate was looked forward.%微型燃料电池是未来可移动电源的主流,但是其双极板成形工艺成为燃料电池推广应用的主要制约之一。介绍了微型燃料电池双极板的成形工艺,包括基于微冲压等常规的塑性变形手段,基于MEMS(Micro-Electro-Mechanical Systems)的微加工技术和非传统加工工艺,展望了未来微型燃料电池双极板成形工艺的发展趋势。

  19. Explosive bulk charge

    Science.gov (United States)

    Miller, Jacob Lee

    2015-04-21

    An explosive bulk charge, including: a first contact surface configured to be selectively disposed substantially adjacent to a structure or material; a second end surface configured to selectively receive a detonator; and a curvilinear side surface joining the first contact surface and the second end surface. The first contact surface, the second end surface, and the curvilinear side surface form a bi-truncated hemispherical structure. The first contact surface, the second end surface, and the curvilinear side surface are formed from an explosive material. Optionally, the first contact surface and the second end surface each have a substantially circular shape. Optionally, the first contact surface and the second end surface consist of planar structures that are aligned substantially parallel or slightly tilted with respect to one another. The curvilinear side surface has one of a smooth curved geometry, an elliptical geometry, and a parabolic geometry.

  20. Beyond packing of hard spheres: The effects of core softness, non-additivity, intermediate-range repulsion, and many-body interactions on the glass-forming ability of bulk metallic glasses.

    Science.gov (United States)

    Zhang, Kai; Fan, Meng; Liu, Yanhui; Schroers, Jan; Shattuck, Mark D; O'Hern, Corey S

    2015-11-14

    When a liquid is cooled well below its melting temperature at a rate that exceeds the critical cooling rate Rc, the crystalline state is bypassed and a metastable, amorphous glassy state forms instead. Rc (or the corresponding critical casting thickness dc) characterizes the glass-forming ability (GFA) of each material. While silica is an excellent glass-former with small Rc metals and most alloys are typically poor glass-formers with large Rc > 10(10) K/s. Only in the past thirty years have bulk metallic glasses (BMGs) been identified with Rc approaching that for silica. Recent simulations have shown that simple, hard-sphere models are able to identify the atomic size ratio and number fraction regime where BMGs exist with critical cooling rates more than 13 orders of magnitude smaller than those for pure metals. However, there are a number of other features of interatomic potentials beyond hard-core interactions. How do these other features affect the glass-forming ability of BMGs? In this manuscript, we perform molecular dynamics simulations to determine how variations in the softness and non-additivity of the repulsive core and form of the interatomic pair potential at intermediate distances affect the GFA of binary alloys. These variations in the interatomic pair potential allow us to introduce geometric frustration and change the crystal phases that compete with glass formation. We also investigate the effect of tuning the strength of the many-body interactions from zero to the full embedded atom model on the GFA for pure metals. We then employ the full embedded atom model for binary BMGs and show that hard-core interactions play the dominant role in setting the GFA of alloys, while other features of the interatomic potential only change the GFA by one to two orders of magnitude. Despite their perturbative effect, understanding the detailed form of the intermetallic potential is important for designing BMGs with cm or greater casting thickness. PMID:26567672

  1. Micro Elector Mechanical Systems

    International Nuclear Information System (INIS)

    This book consists of seven chapters, which are the flow of the age from macro world to micro world, what is MEMS, semiconductor, micro machining and MEMS, where do MEMS goes to?, How to make MEMS, MEMS in the future and knowing about MEMS more than. This book is written to explain in ease and fun. It deals with MEMS in IT, BT, NT, ST, micro robot technology, basic process for making MEMS such as Bulk micromachining, surface micromachining LGA technology, DARPA and organization in domestic and overseas and academy and journal related MEMS.

  2. Multilayer Integrated Film Bulk Acoustic Resonators

    CERN Document Server

    Zhang, Yafei

    2013-01-01

    Multilayer Integrated Film Bulk Acoustic Resonators mainly introduces the theory, design, fabrication technology and application of a recently developed new type of device, multilayer integrated film bulk acoustic resonators, at the micro and nano scale involving microelectronic devices, integrated circuits, optical devices, sensors and actuators, acoustic resonators, micro-nano manufacturing, multilayer integration, device theory and design principles, etc. These devices can work at very high frequencies by using the newly developed theory, design, and fabrication technology of nano and micro devices. Readers in fields of IC, electronic devices, sensors, materials, and films etc. will benefit from this book by learning the detailed fundamentals and potential applications of these advanced devices. Prof. Yafei Zhang is the director of the Ministry of Education’s Key Laboratory for Thin Films and Microfabrication Technology, PRC; Dr. Da Chen was a PhD student in Prof. Yafei Zhang’s research group.

  3. Formation of amorphous sapphire by a femtosecond laser pulse induced micro-explosion

    International Nuclear Information System (INIS)

    We report on structural characterization of void-structures created by a micro-explosion at the locus of a tightly focused femtosecond laser pulse inside the crystalline phase of Al2O3 (R3c space group). The transmission electron microscopy (TEM), micro-X-ray diffraction (XRD) analysis, and Raman scattering revealed a presence of strongly structurally modified amorphous regions around the void-structures. We discuss issues of achieving the required resolution for structural characterization and assignment of newly formed phases of nano-crystallites by TEM, XRD, and Raman scattering from micro-volumes of modified materials enclosed inside the bulk of the host phase.

  4. Beyond packing of hard spheres: The effects of core softness, non-additivity, intermediate-range repulsion, and many-body interactions on the glass-forming ability of bulk metallic glasses

    International Nuclear Information System (INIS)

    When a liquid is cooled well below its melting temperature at a rate that exceeds the critical cooling rate Rc, the crystalline state is bypassed and a metastable, amorphous glassy state forms instead. Rc (or the corresponding critical casting thickness dc) characterizes the glass-forming ability (GFA) of each material. While silica is an excellent glass-former with small Rc < 10−2 K/s, pure metals and most alloys are typically poor glass-formers with large Rc > 1010 K/s. Only in the past thirty years have bulk metallic glasses (BMGs) been identified with Rc approaching that for silica. Recent simulations have shown that simple, hard-sphere models are able to identify the atomic size ratio and number fraction regime where BMGs exist with critical cooling rates more than 13 orders of magnitude smaller than those for pure metals. However, there are a number of other features of interatomic potentials beyond hard-core interactions. How do these other features affect the glass-forming ability of BMGs? In this manuscript, we perform molecular dynamics simulations to determine how variations in the softness and non-additivity of the repulsive core and form of the interatomic pair potential at intermediate distances affect the GFA of binary alloys. These variations in the interatomic pair potential allow us to introduce geometric frustration and change the crystal phases that compete with glass formation. We also investigate the effect of tuning the strength of the many-body interactions from zero to the full embedded atom model on the GFA for pure metals. We then employ the full embedded atom model for binary BMGs and show that hard-core interactions play the dominant role in setting the GFA of alloys, while other features of the interatomic potential only change the GFA by one to two orders of magnitude. Despite their perturbative effect, understanding the detailed form of the intermetallic potential is important for designing BMGs with cm or greater casting thickness

  5. Beyond packing of hard spheres: The effects of core softness, non-additivity, intermediate-range repulsion, and many-body interactions on the glass-forming ability of bulk metallic glasses

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Kai; Fan, Meng; Liu, Yanhui; Schroers, Jan [Department of Mechanical Engineering and Materials Science, Yale University, New Haven, Connecticut 06520 (United States); Center for Research on Interface Structures and Phenomena, Yale University, New Haven, Connecticut 06520 (United States); Shattuck, Mark D. [Department of Mechanical Engineering and Materials Science, Yale University, New Haven, Connecticut 06520 (United States); Department of Physics and Benjamin Levich Institute, The City College of the City University of New York, New York, New York 10031 (United States); O’Hern, Corey S. [Department of Mechanical Engineering and Materials Science, Yale University, New Haven, Connecticut 06520 (United States); Center for Research on Interface Structures and Phenomena, Yale University, New Haven, Connecticut 06520 (United States); Department of Physics, Yale University, New Haven, Connecticut 06520 (United States); Department of Applied Physics, Yale University, New Haven, Connecticut 06520 (United States)

    2015-11-14

    When a liquid is cooled well below its melting temperature at a rate that exceeds the critical cooling rate R{sub c}, the crystalline state is bypassed and a metastable, amorphous glassy state forms instead. R{sub c} (or the corresponding critical casting thickness d{sub c}) characterizes the glass-forming ability (GFA) of each material. While silica is an excellent glass-former with small R{sub c} < 10{sup −2} K/s, pure metals and most alloys are typically poor glass-formers with large R{sub c} > 10{sup 10} K/s. Only in the past thirty years have bulk metallic glasses (BMGs) been identified with R{sub c} approaching that for silica. Recent simulations have shown that simple, hard-sphere models are able to identify the atomic size ratio and number fraction regime where BMGs exist with critical cooling rates more than 13 orders of magnitude smaller than those for pure metals. However, there are a number of other features of interatomic potentials beyond hard-core interactions. How do these other features affect the glass-forming ability of BMGs? In this manuscript, we perform molecular dynamics simulations to determine how variations in the softness and non-additivity of the repulsive core and form of the interatomic pair potential at intermediate distances affect the GFA of binary alloys. These variations in the interatomic pair potential allow us to introduce geometric frustration and change the crystal phases that compete with glass formation. We also investigate the effect of tuning the strength of the many-body interactions from zero to the full embedded atom model on the GFA for pure metals. We then employ the full embedded atom model for binary BMGs and show that hard-core interactions play the dominant role in setting the GFA of alloys, while other features of the interatomic potential only change the GFA by one to two orders of magnitude. Despite their perturbative effect, understanding the detailed form of the intermetallic potential is important for

  6. Novel artificial hip joint: A layer of alumina on Ti-6Al-4V alloy formed by micro-arc oxidation.

    Science.gov (United States)

    Khanna, Rohit; Kokubo, Tadashi; Matsushita, Tomiharu; Nomura, Yuuji; Nose, Norihiro; Oomori, Yoshiyuki; Yoshida, Takuya; Wakita, Koichi; Takadama, Hiroaki

    2015-10-01

    In many hip replacement surgeries, monolithic alumina is used as a femoral head due to its high wear resistance. However, it is liable to fracture under load bearing operations in artificial joints. We propose a promising way to overcome this limitation by forming a dense alumina layer onto a relatively tough substrate such as Ti-6Al-4V alloy to obtain high wear resistance on a material that can sustain relatively high toughness. For this purpose, Al metal powders were deposited onto Ti-6Al-4V alloy by cold spraying in N2 atmosphere. Interfacial adhesion between Al and the Ti alloy was improved by the formation of a reaction layer of Al3Ti between them by heating at 640 °C for 1h in air. Subsequently, micro-arc oxidation treatment was performed to oxidize Al. The oxidized layer was composed of an outer porous layer of γ-alumina and inner-most dense layer of α-alumina. The α-alumina layer was almost fully densified and exhibited high Vickers hardness almost equal to that of alumina ceramics used as the femoral head. Thus, the newly developed dense alumina/Ti alloy can be potentially used to produce the reliable bearing surfaces of artificial hip joint. PMID:26117770

  7. Use of micro-Raman spectrometry coupled with scanning electron microscopy to determine the chemical form of uranium compounds in micrometer-size particles

    International Nuclear Information System (INIS)

    In the frame of nuclear safeguards, knowledge of the chemical form (stoichiometry) of the uranium compounds present in the micrometric particulate material sampled by wiping surfaces in an inspected nuclear facility may point out the industrial process implemented in the installation. Micro-Raman spectroscopy (MRS) coupled with scanning electron microscopy (SEM) has been used for the first time to analyze micrometer-size particles of various uranium oxides [UO2, U3O8, UO3, and UO4.4(H2O)] deposited on carbon disks. Uranium particles are detected by means of SEM, and Raman analysis is then directly carried out inside the SEM measurement chamber without moving the carbon disk from SEM to MRS. When particles are deposited on appropriate carbon disks (sticky carbon tapes), despite a loss of signal-to-noise ratio of about an order of magnitude with regard to the stand-alone MRS, all uranium oxides are successfully identified in particles by in-SEM Raman analysis, obtaining similar characteristic bands as the ones obtained with the stand-alone MRS. Moreover, with the SEM-MRS coupling, particles as small as 1 μm can be analyzed, whereas, without the SEM-MRS coupling, only particles larger than ∼5 μm are efficiently analyzed, after localization inside the SEM, transfer of the sample holder into the MRS, and relocation of the particles inside the MRS. (authors)

  8. Solvent extraction technology of 99Mo-99mTc system re-visited : re-engineering of the technology for the faster preparation of a purer form of bulk 99mTcO-4 in the hospital radiopharmacy

    International Nuclear Information System (INIS)

    Full text: The liquid-liquid (MEK-aqueous alkali) method of separation and purification of 99mTc from 99Mo, though unpopular worldwide because of its relative complexity, has been the work-horse of Indian nuclear medicine since 1971, owing to its cheapness and ready availability of low specific activity 99Mo. The main issues to be considered while perfecting this technology are: simplicity of operation, yield, purity, radiation health and safety of operator and environment, time element to obtain the product and cost. Any modifications in process technology that help to improve these are welcome. In the past we had made many alternations in the process and process design and these have been incorporated into the relevant technology (IAEA 1984). In keeping with our objectives we have systematically introduced a few more innovations/improvisations in the process chemistry and technology viz. (i) substitution of dil (1.0 M) NaOH for conc. 5.0 M as the aqueous alkaline liquid phase, (ii) use of excess (∼40 ml) MEK as the extractant, (iii) total elimination of the back extraction (stripping) step, and (iv) effecting multiple (∼3) aerations + removal of liquid MEK at interphase (0.1-0.3 ml after each aeration) subsequent to the initial separation. The characteristics of the bulk 99mTcO4- were closely monitored for yield and purity while studying each of these parameters. It was found that the alterations did not affect these features. These changes have resulted in simplifying the process technology while ensuring optimum yields and purity even when performed by novices. (The assurance of purity is an important pharmacopoeial requirement for guaranteeing the quality of derived 99mTc- radiodiagnostics). It also reduced the time element involved to an extent, as well as the radiation exposures to operators. Some of these procedures have the potential for reducing operating costs. Presently all these are tried and tested methodologies and form a part of the standard

  9. Drastic influence of minor Fe or Co additions on the glass forming ability, martensitic transformations and mechanical properties of shape memory Zr–Cu–Al bulk metallic glass composites

    International Nuclear Information System (INIS)

    The microstructure and mechanical properties of Zr48Cu48 − xAl4M x (M ≡ Fe or Co, x = 0, 0.5, 1 at.%) metallic glass (MG) composites are highly dependent on the amount of Fe or Co added as microalloying elements in the parent Zr48Cu48Al4 material. Addition of Fe and Co promotes the transformation from austenite to martensite during the course of nanoindentation or compression experiments, resulting in an enhancement of plasticity. However, the presence of Fe or Co also reduces the glass forming ability, ultimately causing a worsening of the mechanical properties. Owing to the interplay between these two effects, the compressive plasticity for alloys with x = 0.5 (5.5% in Zr48Cu47.5Al4Co0.5 and 6.2% in Zr48Cu47.5Al4Fe0.5) is considerably larger than for Zr48Cu48Al4 or the alloys with x = 1. Slight variations in the Young’s modulus (around 5–10%) and significant changes in the yield stress (up to 25%) are also observed depending on the composition. The different microstructural factors that have an influence on the mechanical behavior of these composites are investigated in detail: (i) co-existence of amorphous and crystalline phases in the as-cast state, (ii) nature of the crystalline phases (austenite versus martensite content), and (iii) propensity for the austenite to undergo a mechanically-driven martensitic transformation during plastic deformation. Evidence for intragranular nanotwins likely generated in the course of the austenite–martensite transformation is provided by transmission electron microscopy. Our results reveal that fine-tuning of the composition of the Zr–Cu–Al–(Fe,Co) system is crucial in order to optimize the mechanical performance of these bulk MG composites, to make them suitable materials for structural applications. (paper)

  10. Manufacturing processes 4 forming

    CERN Document Server

    Klocke, Fritz

    2013-01-01

    This book provides essential information on metal forming, utilizing a practical distinction between bulk and sheet metal forming. In the field of bulk forming, it examines processes of cold, warm and hot bulk forming, as well as rolling and a new addition, the process of thixoforming. As for the field of sheet metal working, on the one hand it deals with sheet metal forming processes (deep drawing, flange forming, stretch drawing, metal spinning and bending). In terms of special processes, the chapters on internal high-pressure forming and high rate forming have been revised and refined. On the other, the book elucidates and presents the state of the art in sheet metal separation processes (shearing and fineblanking). Furthermore, joining by forming has been added to the new edition as a new chapter describing mechanical methods for joining sheet metals. The new chapter “Basic Principles” addresses both sheet metal and bulk forming, in addition to metal physics, plastomechanics and computational basics; ...

  11. Effect of Microstructure of Al-Si-alloy on the Quality of the Layer Formed with Micro-Arc Oxidation Method

    Directory of Open Access Journals (Sweden)

    Kiseleva S.K.

    2015-09-01

    Full Text Available This investigation is on the properties of hardened layers, developed with the micro-arc oxidation method (MAO on the surface of the ingots from an Al-Si alloy. It has been established that the properties (microhardness, thickness, porosity of the generated surfaces depend on the structure of the alloy.

  12. Micro Engineering

    DEFF Research Database (Denmark)

    Alting, Leo; Kimura, F.; Hansen, Hans Nørgaard;

    2003-01-01

    The paper addresses the questions of how micro products are designed and how they are manufactured. Definitions of micro products and micro engineering are discussed and the presentation is aimed at describing typical issues, possibilities and tools regarding design of micro products. The...

  13. Fe60CoxZr10Mo5W2B23-x(x=1,3,5,7,9)块状金属玻璃的非晶形成能力%Glass forming ability of Fe60 Cox Zr10Mo5 W2B23-x (x = 1,3,5,7,9) bulk metallic glasses

    Institute of Scientific and Technical Information of China (English)

    刘冬艳; 张海峰; 邓胜涛; 胡壮麒

    2005-01-01

    The bulk Fe60CoxZr10Mo5W2B23-x (x= 1, 3, 5, 7, 9) amorphous rods with diameters of1.5 mm were successfully prepared by copper mold casting method with the low purity raw materials.The amorphous and crystalline states, and thermal parameters, such as the glass transition temperature (Tg), the initial crystallization temperature (Tx), the supercooled liquid region (ΔTx = TxTg), the reduced glass transition temperature Trg (Tg/Tm, Tm: the onset temperature of melting of the alloy, and Tg/T1, T1 : the finished temperature of melting of the alloy) were investigated by X-ray diffractometry (XRD) and differential scanning calorimetry (DSC) analysis. Glass forming ability of Fe60CoxZr10Mo5W2B23-x (x=1, 3, 5, 7, 9)bulk metallic glasses has been studied. According to the results, the alloy (x=7) with the highest Trg (Tg/T1 =0. 607, Tg/T1 =0.590) value, has the strongest glass forming ability among these alloys because its composition is near eutectic composition.The wide supercooled liquid region over 72 K indicates the high thermal stability for this alloy system.This bulk metallic glass exhibits quite high strength (Hv 1020). The success of production of the Febased bulk metallic glass with industrial materials is of great significance for the future progress of basic research and practical application.

  14. Effects of Loading Type And Cavity Position On The Pattern Height In Micro-manufacturing of Al5083 Superplastic Alloy And Zr62Cu17Ni13Al8 Metallic Glass

    Science.gov (United States)

    Na, Young-Sang; Son, Seon-Cheon; Park, Kyu-Yeol; Lee, Jong-Hoon

    2009-11-01

    Vibrational micro-forming of pyramidal shape patterns was conducted for an Al superplastic alloy, Al 5083 and a Zr-based bulk metallic glass, Zr62Cu17Ni13Al8. A vibrational micro-forming system was specially designed for generating vibrational load by combining a PZT actuator with a signal generator. Si micro dies with wet-etched pyramidal patterns were used as master dies for vibrational micro-forming. The micro-formed pattern height was increasing with increasing the frequency of the vibrational load. In particular, the vibrationally-microformed pattern height is similar or even higher than the statically-microformed pattern height when the load frequency exceeded about 125 kHz. It was also observed that the crystal grains affect the surface quality of the microformed pattern and the distribution of the pattern height in the die cavity array.

  15. Micro-machining.

    Science.gov (United States)

    Brinksmeier, Ekkard; Preuss, Werner

    2012-08-28

    Manipulating bulk material at the atomic level is considered to be the domain of physics, chemistry and nanotechnology. However, precision engineering, especially micro-machining, has become a powerful tool for controlling the surface properties and sub-surface integrity of the optical, electronic and mechanical functional parts in a regime where continuum mechanics is left behind and the quantum nature of matter comes into play. The surprising subtlety of micro-machining results from the extraordinary precision of tools, machines and controls expanding into the nanometre range-a hundred times more precise than the wavelength of light. In this paper, we will outline the development of precision engineering, highlight modern achievements of ultra-precision machining and discuss the necessity of a deeper physical understanding of micro-machining. PMID:22802498

  16. Uniform superhydrophobic surfaces using micro/nano complex structures formed spontaneously by a simple and cost-effective nonlithographic process based on anodic aluminum oxide technology

    International Nuclear Information System (INIS)

    This paper presents a uniform micro/nano double-roughened superhydrophobic surface with a high static contact angle (CA) and low contact angle hysteresis (CAH). The proposed micro/nano complex structured surfaces were self-fabricated simply and efficiently using a very simple and low-cost nonlithographic sequential process, which consists of aluminum (Al) sputtering, anodization of the Al layer and pore widening, without specific equipment and additional subsequent processes. The wetting properties of the fabricated surfaces were characterized by measuring the static CAs and the CAHs after plasma polymerized fluorocarbon coating with a low surface energy. The measured static CA and CAH were 154 ± 2.3° and 5.7 ± 0.8°, respectively, showing that the fabricated double-roughened surfaces exhibit superhydrophobic behaviors clearly. In addition, the proposed double-scaled surfaces at a wafer-level exhibited uniform superhydrophobic behaviors across the wafer with an apparent CA and CAH of 153.9 ± 0.8° and 4.9 ± 1.3°, respectively.

  17. Bulk chemicals from biomass

    NARCIS (Netherlands)

    Haveren, van J.; Scott, E.L.; Sanders, J.P.M.

    2008-01-01

    Given the current robust forces driving sustainable production, and available biomass conversion technologies, biomass-based routes are expected to make a significant impact on the production of bulk chemicals within 10 years, and a huge impact within 20-30 years. In the Port of Rotterdam there is a

  18. Heat transport in bulk/nanoporous/bulk silicon devices

    Energy Technology Data Exchange (ETDEWEB)

    Criado-Sancho, M. [Departamento de Ciencias y Técnicas Físicoquimicas, Facultad de Ciencias, UNED, Senda del Rey 9, 20040 Madrid (Spain); Jou, D., E-mail: David.Jou@uab.cat [Departament de Física, Universitat Autònoma de Barcelona, 08193 Bellaterra, Catalonia (Spain); Institut d' Estudis Catalans, Carme 47, 08001 Barcelona, Catalonia (Spain)

    2013-02-04

    We study heat transport in bulk/nanoporous/bulk silicon devices; we show that, despite bulk/nanoporous devices may act as thermal rectifiers, the non-linear aspects of their joint thermal conductance are not strong enough to lead to a negative differential thermal resistance, necessary to allow bulk/nanoporous/bulk Si devices to act as thermal transistors. Furthermore, we explicitly study the effective thermal conductivity of the mentioned devices for several temperatures, geometries, porosities, and pore size.

  19. Comparative evaluation of hydroxyapatite and nano-bioglass in two forms of conventional micro- and nano-particles in repairing bone defects (an animal study

    Directory of Open Access Journals (Sweden)

    Saied Nosouhian

    2015-01-01

    Results: After 15 days, the bone formation percentage showed a significant difference between HA and nano-HA and between HA and bioglass (P < 0.001. The nano-HA group showed the highest rate of bone formation after 15 days. Nano-bioglass and bioglass and nano-HA and nano-bioglass groups represented a significant difference and nano-bioglass showed the highest rate of bone formation after 30 days (P = 0.01. After 45 days, the bone formation percentage showed a significant difference between nano-bioglass and bioglass and between nano-HA and nano-bioglass groups (P = 0.01. Conclusions: Nano-HA and nano-bioglass biomaterials showed promising results when compared to conventional micro-particles in the repair of bone defects.

  20. A size-dependent constitutive model of bulk metallic glasses in the supercooled liquid region

    Science.gov (United States)

    Yao, Di; Deng, Lei; Zhang, Mao; Wang, Xinyun; Tang, Na; Li, Jianjun

    2015-01-01

    Size effect is of great importance in micro forming processes. In this paper, micro cylinder compression was conducted to investigate the deformation behavior of bulk metallic glasses (BMGs) in supercooled liquid region with different deformation variables including sample size, temperature and strain rate. It was found that the elastic and plastic behaviors of BMGs have a strong dependence on the sample size. The free volume and defect concentration were introduced to explain the size effect. In order to demonstrate the influence of deformation variables on steady stress, elastic modulus and overshoot phenomenon, four size-dependent factors were proposed to construct a size-dependent constitutive model based on the Maxwell-pulse type model previously presented by the authors according to viscosity theory and free volume model. The proposed constitutive model was then adopted in finite element method simulations, and validated by comparing the micro cylinder compression and micro double cup extrusion experimental data with the numerical results. Furthermore, the model provides a new approach to understanding the size-dependent plastic deformation behavior of BMGs.

  1. Iron - based bulk amorphous alloys

    Directory of Open Access Journals (Sweden)

    R. Babilas

    2010-07-01

    Full Text Available Purpose: The paper presents a structure characterization, thermal and soft magnetic properties analysis of Fe-based bulk amorphous materials in as-cast state and after crystallization process. In addition, the paper gives some brief review about achieving, formation and structure of bulk metallic glasses as a special group of amorphous materials.Design/methodology/approach: The studies were performed on Fe72B20Si4Nb4 metallic glass in form of ribbons and rods. The amorphous structure of tested samples was examined by X-ray diffraction (XRD, transmission electron microscopy (TEM and scanning electron microscopy (SEM methods. The thermal properties of the glassy samples were measured using differential thermal analysis (DTA and differential scanning calorimetry (DSC. The magnetic properties contained initial and maximum magnetic permeability, coercive force and magnetic after-effects measurements were determined by the Maxwell-Wien bridge and VSM methods.Findings: The X-ray diffraction and transmission electron microscopy investigations revealed that the studied as-cast bulk metallic glasses in form of ribbons and rods were amorphous. Two stage crystallization process was observed for studied bulk amorphous alloy. The differences of crystallization temperature between ribbons and rods with chosen thickness are probably caused by different amorphous structures as a result of the different cooling rates in casting process. The SEM images showed that studied fractures could be classified as mixed fractures with indicated two zones contained “river” and “smooth” areas. The changing of chosen soft magnetic properties (μr, Bs, Hc obtained for samples with different thickness is a result of the non-homogenous amorphous structure of tested metallic glasses. The annealing process in temperature range from 373 to 773 K causes structural relaxation of tested amorphous materials, which leads to changes in their physical properties. The qualitative

  2. Molecular dynamics and quasidynamics simulations of the annealing of bulk and near-surface interstitials formed in molecular-beam epitaxial Si due to low-energy particle bombardment during deposition

    Science.gov (United States)

    Kitabatake, M.; Fons, P.; Greene, J. E.

    1991-01-01

    The relaxation, diffusion, and annihilation of split and hexagonal interstitials resulting from 10 eV Si irradiation of (2x1)-terminated Si(100) are investigated. Molecular dynamics and quasidynamics simulations, utilizing the Tersoff many-body potential are used in the investigation. The interstitials are created in layers two through six, and stable atomic configurations and total potential energies are derived as a function of site symmetry and layer depth. The interstitial Si atoms are allowed to diffuse, and the total potential energy changes are calculated. Lattice configurations along each path, as well as the starting configurations, are relaxed, and minimum energy diffusion paths are derived. The results show that the minimum energy paths are toward the surface and generally involved tetrahedral sites. The calculated interstitial migration activation energies are always less than 1.4 eV and are much lower in the near-surface region than in the bulk.

  3. Application of the penetration theory for gas - Liquid mass transfer without liquid bulk: Differences with system with a bulk

    OpenAIRE

    van Elk, E. P.; Knaap, M. C.; Versteeg, G. F.

    2007-01-01

    Frequently applied micro models for gas-liquid mass transfer all assume the presence of a liquid bulk. However, some systems are characterized by the absence of a liquid bulk, a very thin layer of liquid flows over a solid surface. An example of such a process is absorption in a column equipped with sructured packing elements. The penetration model was slightly modified, so that it can describe systems without liquid bulk. A comparison is made between the results obtained with the modified mo...

  4. Bulk materials handling review

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2007-02-15

    The paper provides details of some of the most important coal handling projects and technologies worldwide. It describes development by Aubema Crushing Technology GmbH, Bedeschi, Cimbria Moduflex, DBT, Dynamic Air Conveying Systems, E & F Services, InBulk Technologies, Nord-Sen Metal Industries Ltd., Pebco Inc, Primasonics International Ltd., R.J.S. Silo Clean (International) Ltd., Takraf GmbH, and The ACT Group. 17 photos.

  5. Impacts of Press Amount on Forming Property of Micro Fuel Cell Bipolar Plate%下压量对微型燃料电池双极板成形性能的影响

    Institute of Scientific and Technical Information of China (English)

    王匀; 丁盛; 许桢英; 张园园; 尹必峰

    2012-01-01

    The bipolar plate is a key component of micro fuel cell. It is difficult to form the high precision flow channel of bipolar plate under the micro scale. Herein,an accumulative forming method for the characteristics of bipolar plate was presented. On the basis of introducing the principles of micro- accumulation forming, we set up the corresponding experimental apparatus, selecting 9mm× 9mm ×0. 165mm and 9mm×9mm×0. 27mm aluminum plate as the bipolar plate blanks to do the accumulated forming test. We analyzed the shaping law and the influence of different amount of under-draught on the forming force,comparing the maximum forming force under different amount of under-draught. The results show that the piates with different thickness present the same law of forming force,the forming force reaches maximum at the starting point as increasing the amount of under-draught,then the forming force decreases firstly and then increases,at last reaches the vicinity of the maximum forming force at the end of flow channel. The bigger the amount of underdraught and the thickness of plates,the greater the maximum forming force. The maximum forming force of 0. 27mm sheet plate with the underdraught of 0. 5 times thickness is greater than that of 0. 165mm sheet plate with the underdraught of 2 times thickness.%双极板是微型燃料电池关键部件之一,微尺度下的高精度极板流道给其成形带来了难度,针对双极板这一特点提出了累积成形方法.在介绍微累积成形工作原理的基础上搭建了相应的实验装置,分别选取0.165mm和0.27mm板厚的成形区域9mm×9mm铝合金板作为双极板毛坯,进行了累积成形实验,分析双极板成形规律,研究了不同下压量对成形力的影响,并且比较了不同下压量时的最大成形力.结果显示,不同厚度的板科随着下压量的增加,成形力在累积成形起始点达到最大,然后成形力先减小后增大,在终点处接近最大成形力;最大成形力

  6. Bulk metallic glass tube casting

    International Nuclear Information System (INIS)

    Research highlights: → Tubular specimens of Zr55Cu30Al10Ni5 cast in custom arc-melting furnace. → Tilt casting supplemented by suction casting. → Bulk metallic glass formed only with optimized processing parameters. → Fully amorphous tubes with 1.8 mm wall thickness and 25 mm diameter. - Abstract: Tubular bulk metallic glass specimens were produced, using a custom-built combined arc-melting tilt-casting furnace. Zr55Cu30Al10Ni5 tubes with outer diameter of 25 mm and 0.8-3 mm wall thicknesses were cast, with both tilt and suction casting to ensure mold filling. Tilt casting was found to fill one side of the tube mold first, with the rest of the tube circumference filled subsequently by suction casting. Optimized casting parameters were required to fully fill the mold and ensure glass formation. Too small melt mass and too low arc power filled the mold only partially. However, too large melt mass and higher arc power which lead to the best mold filling also lead to partial crystallization. Variations in processing parameters were explored, until a glassy ring with 1.8 mm thickness was produced. Different sections of the as-cast ring were investigated by X-ray diffraction (XRD), differential scanning calorimetry (DSC), and instrumented indentation to ensure amorphous microstructure. Atomic force microscopy (AFM) was used to compare the surface qualities of the first- and last-filled sections. These measurements confirmed the glassy structure of the cast ring, and that, the tilt cast tube section consistently showed better surface quality than the suction cast section. Optimized casting parameters are required to fully realize the potential of directly manufacturing complex shapes out of high-purity bulk metallic glasses by tilt casting.

  7. Micro Embossing of Ceramic Green Substrates for Micro Devices

    CERN Document Server

    Shan, X -C; Maw, H P; Lu, C W; Lam, Y C

    2008-01-01

    Multilayered ceramic substrates with embedded micro patterns are becoming increasingly important, for example, in harsh environment electronics and microfluidic devices. Fabrication of these embedded micro patterns, such as micro channels, cavities and vias, is a challenge. This study focuses on the process of patterning micro features on ceramic green substrates using micro embossing. A ceramic green tape that possessed near-zero shrinkage in the x-y plane was used, six layers of which were laminated as the embossing substrate. The process parameters that impact on the pattern fidelity were investigated and optimized in this study. Micro features with line-width as small as several micrometers were formed on the ceramic green substrates. The dynamic thermo-mechanical analysis indicated that extending the holding time at certain temperature range would harden the green substrates with little effect on improving the embossing fidelity. Ceramic substrates with embossed micro patterns were obtain d after co-firi...

  8. Integration of bulk piezoelectric materials into microsystems

    Science.gov (United States)

    Aktakka, Ethem Erkan

    Bulk piezoelectric ceramics, compared to deposited piezoelectric thin-films, provide greater electromechanical coupling and charge capacity, which are highly desirable in many MEMS applications. In this thesis, a technology platform is developed for wafer-level integration of bulk piezoelectric substrates on silicon, with a final film thickness of 5-100microm. The characterized processes include reliable low-temperature (200°C) AuIn diffusion bonding and parylene bonding of bulk-PZT on silicon, wafer-level lapping of bulk-PZT with high-uniformity (+/-0.5microm), and low-damage micro-machining of PZT films via dicing-saw patterning, laser ablation, and wet-etching. Preservation of ferroelectric and piezoelectric properties is confirmed with hysteresis and piezo-response measurements. The introduced technology offers higher material quality and unique advantages in fabrication flexibility over existing piezoelectric film deposition methods. In order to confirm the preserved bulk properties in the final film, diaphragm and cantilever beam actuators operating in the transverse-mode are designed, fabricated and tested. The diaphragm structure and electrode shapes/sizes are optimized for maximum deflection through finite-element simulations. During tests of fabricated devices, greater than 12microm PP displacement is obtained by actuation of a 1mm2 diaphragm at 111kHz with properties of bulk-PZT5A are mostly preserved without any necessity of repolarization. Three generations of resonant vibration energy harvesters are designed, simulated and fabricated to demonstrate the competitive performance of the new fabrication process over traditional piezoelectric deposition systems. An unpackaged PZT/Si unimorph harvester with 27mm3 active device volume produces up to 205microW at 1.5g/154Hz. The prototypes have achieved the highest figure-of-merits (normalized-power-density x bandwidth) amongst previously reported inertial energy harvesters. The fabricated energy harvester is

  9. Marked dependence on carrier-ligand bulk but not on carrier-ligand chirality of the duplex versus single-strand forms of a DNA oligonucleotide with a series of G-Pt(II)-G intrastrand cross-links modeling cisplatin-DNA adducts.

    Science.gov (United States)

    Beljanski, Vladimir; Villanueva, Julie M; Doetsch, Paul W; Natile, Giovanni; Marzilli, Luigi G

    2005-11-16

    The N7-Pt-N7 adjacent G,G intrastrand DNA cross-link responsible for cisplatin anticancer activity is dynamic, promotes local "melting" in long DNA, and converts many oligomer duplexes to single strands. For 5'-d(A1T2G3G4G5T6A7C8C9C10A11T12)-3' (G3), treatment of the (G3)2 duplex with five pairs of [LPt(H2O)2]2+ enantiomers (L = an asymmetric diamine) formed mixtures of LPt-G3 products (1 Pt per strand) cross-linked at G3,G4 or at G4,G5 in all cases. L chirality exerted little influence. For primary diamines L with bulk on chelate ring carbons (e.g., 1,2-diaminocyclohexane), the duplex was converted completely into single strands (G3,G4 coils and G4,G5 hairpins), exactly mirroring results for cisplatin, which lacks bulk. In sharp contrast, for secondary diamines L with bulk on chelate ring nitrogens (e.g., 2,2'-bipiperidine, Bip), unexpectedly stable duplexes having two platinated strands (even a unique G3,G4/G4,G5 heteroduplex) were formed. After enzymatic digestion of BipPt-G3 duplexes, the conformation of the relatively nondynamic G,G units was shown to be head-to-head (HH) by HPLC/mass spectrometric characterization. Because the HH conformation dominates at the G,G lesion in duplex DNA and in the BipPt-G3 duplexes, the stabilization of the duplex form only when the L nitrogen adducts possess bulk suggests that H-bonding interactions of the Pt-NH groups with the flanking DNA lead to local melting and to destabilization of oligomer duplexes. The marked dependence of adduct properties on L bulk and the minimal dependence on L chirality underscore the need for future exploration of the roles of the L periphery in affecting anticancer activity. PMID:16277526

  10. Fiscal 1998 research report on micro-particle control process technology; 1998 nendo micro ryushi seigyo process gijutsu no chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    For establishment of process technology realizing control of forms and structures of micro-particles on practical equipment, research was made on related elementary technologies and current technologies. The research was promoted aiming at synthesis of micro-particles from nanometer to micrometer in size and their application to functional materials, establishment of the methodology for correlating the microstructure and function of micro-particle materials with fabrication process, and establishment of a common-base technology system in chemical technology aiming at fabrication of functional materials. As for the common- base technology, to clarify its importance, research was made on the fabrication method and dispersion mechanism of nano- particles, particle arraying method by coating, device fabrication technique by coating, and one-step synthesis and coating of nano-particles. As for the project research, synthesis of monodispersed nano-particles at large production rates, fabrication of thin films and bulk materials by arraying and coating. (NEDO)

  11. 选区激光熔化制备块体TiC/Ti纳米复合材料的成形工艺及性能%Forming Process and Properties of TiC/Ti Bulk-Form Nanocomposites Prepared by Selective Laser Melting

    Institute of Scientific and Technical Information of China (English)

    孟广斌; 顾冬冬; 李闯; 沈以赴; 李玉芳

    2011-01-01

    The TiC (mass fraction of 30 % ) reinforced Ti matrix bulk-form nanocomposites are successfully prepared by selective laser melting (SLM) process.The influence of the applied laser linear energy density η (the ratio of laser power to scan speed) on surface morphology, densification level, microstructure, and mechanical performance of SLM-processed parts is studied.It shows that when ηis 400 J/m, the SLM-processed part has a relatively smooth surface.A high relative density of 95.5 % and an average microhardness of 750 HV are obtained.The TiC reinforcing phase is dispersed uniformly in the Ti matrix, exhibiting an ultrafine lamellar nanostructure.The dry sliding wear tests reveal that the TiC/Ti nanocomposites possess a considerably low friction coefficient of 0.2, which is much lower than SLM-processed pure titanium parts of 1.2.The densification rate, microhardness, and wear performance decrease at a higher laser energy density of 800 J/m due to the formation of thermal cracks and the coarsening of TiC dendritic reinforcing phase.%利用选区激光熔化(SLM)工艺成功制备了TiC增强Ti基纳米复合块体材料,其中TiC质量分数为30%.研究了激光线能量密度η(激光功率与扫描速率之比)对SLM成形试件的表面形貌、致密度、微观组织及力学性能的影响.结果表明,在η=400 J/m时,SLM成形试件表面较为光滑,成形致密度达到95.5%.平均显微硬度为750 HV,增强体TiC以细小层片状纳米结构均匀分布于Ti基体中.摩擦磨损试验表明,激光成形复合材料的摩擦系数为0.2,远低于SLM纯钛成形件(摩擦系数为1.2).在较高激光线能量密度下(800 J/m),因热裂纹产生和增强体TiC枝晶粗化,致使复合材料致密度、显微硬度及磨损性能下降.

  12. Carbon nanotubes grown on bulk materials and methods for fabrication

    Science.gov (United States)

    Menchhofer, Paul A.; Montgomery, Frederick C.; Baker, Frederick S.

    2011-11-08

    Disclosed are structures formed as bulk support media having carbon nanotubes formed therewith. The bulk support media may comprise fibers or particles and the fibers or particles may be formed from such materials as quartz, carbon, or activated carbon. Metal catalyst species are formed adjacent the surfaces of the bulk support material, and carbon nanotubes are grown adjacent the surfaces of the metal catalyst species. Methods employ metal salt solutions that may comprise iron salts such as iron chloride, aluminum salts such as aluminum chloride, or nickel salts such as nickel chloride. Carbon nanotubes may be separated from the carbon-based bulk support media and the metal catalyst species by using concentrated acids to oxidize the carbon-based bulk support media and the metal catalyst species.

  13. A novel capsule-like structure of micro-sized particles formed by phytosterol ester and γ-cyclodextrin in water.

    Science.gov (United States)

    Sasako, Hiroshi; Kihara, Fukashi; Koyama, Kazuo; Higashi, Kenjirou; Yamamoto, Keiji; Moribe, Kunikazu

    2016-11-01

    The composite material formed by phytosterol ester (PSE) and γ-cyclodextrin (γ-CD) disperses readily in water and has been used to mask undesirable flavours. This paper elucidates the structure of the PSE/γ-CD particle. Cryogenic scanning electron microscopy and contact angle measurements showed that the PSE/γ-CD particles formed a capsule-like structure with a hydrophilic surface. A phase-solubility study using cholesteryl oleate (ChO), one of the components of PSE, showed that ChO formed a hydrophilic and stoichiometric inclusion complex with γ-CD at a molar ratio of 2:5. The structure of the PSE/γ-CD inclusion complex was similar to that of ChO/γ-CD, based on differential scanning calorimetry and powder X-ray diffractometry results. Thus, we propose that the PSE/γ-CD particle has a capsule-like structure wherein a hydrophobic PSE droplet is surrounded by an outer layer of the hydrophilic PSE/γ-CD inclusion complex. PMID:27211647

  14. Form finding and analysis of extensible membranes attached to 2-D and 3-D frames intended for micro air vehicles via experimentally validated finite element methods

    Science.gov (United States)

    Abudaram, Yaakov Jack

    This work is concerned with a new method to apply consistent and known pretension to silicone rubber membranes intended for micro air vehicles as well as an understanding in the science of developed pre-tension in membranes constrained by 2- D and 3-D frames and structures. Pre-tension has a marked effect on the static and dynamic response of membrane wings and controls the overall deflections, as such control and measurement of the membrane pre-tension is important. Two different 2-D frame geometries were fabricated to evaluate the technique. For open-cell frames, the pretension was not uniform, whereas it was for closed-cell frames. Results show developed full-field stress and strain fields as a function of membrane attachment temperature and frame geometry along with experimental iterations to prove repeatability. The membranes can be stretched to a specific pretension according to the temperature at which it adheres to frames. Strain fields in membranes attached to 3-D frames at various temperatures are modeled through FEA utilizing Abaqus to be able to predict the developed membrane deformations, stresses, and strains. Rigid frames with various curvatures are built via appropriate molds and then adhered to silicone rubber membranes and elevated to various temperatures to achieve different pre-strains for experimental validation. Additional experiments are conducted for more complex frame geometries involving both convex and concave topologies embedded within frames. Results are then compared with the Abaqus outputs to validate the accuracy of the FEA model. Highly compliant wings have been used for MAV platforms, where the wing structure is determined by some combination of carbon fiber composites and a membrane skin, adhered in between the layers of composite material. Another new technique of attaching membranes firmly on wing structures is introduced, which involves the application of a technology known as corona treatment coupled with another method of

  15. Wormholes in Bulk Viscous Cosmology

    OpenAIRE

    Jamil, Mubasher

    2008-01-01

    We investigate the effects of the accretion of phantom energy with non-zero bulk viscosity onto a Morris-Thorne wormhole. We have found that if the bulk viscosity is large then the mass of wormhole increases rapidly as compared to small or zero bulk viscosity.

  16. Experiment and simulation of hot embossing of a bulk metallic glass with low pressure and temperature

    International Nuclear Information System (INIS)

    The thermoplastic forming process of a bulk metallic glass (BMG) is simulated using commercial software DEFORM 3D and verified by hot-embossing experiment in this study. The fabrication process of micro-electro-mechanical systems (MEMS) includes a photoresist reflow technique, and Nickle–Cobalt (Ni–Co) electroplating to fabricate a first mold. Then, this mold is applied to hot emboss on an Mg–Cu–Y amorphous alloy to form a secondary mold. The thermal properties of the BMG material such as the glass transition temperature (Tg) and the onset temperature (Tonset) for the viscous flow are investigated using a differential scanning calorimetry (DSC) and a thermomechanical analyzer (TMA). The Tg of BMG is around 413 K (140 °C). The hot-embossing temperature is set at 423 K (150 °C). The supercooled liquid region ΔT between the Tg and the crystallization temperature (Tx) is the working temperature for the microforming study. This embossing process shows that the thermoplastic forming ability of the BMG material is better than polymethylmethacrylate (PMMA) which requires high hot-embossing pressure and temperature. BMG is not only a good material for the hot-embossing process to fabricate micro-structure directly, but also a fast-forming material for mold (or die) fabrication

  17. Can local bulk effects explain the galactic dark matter?

    Energy Technology Data Exchange (ETDEWEB)

    Heydari-Fard, Malihe; Sepangi, Hamid R, E-mail: m.heydarifard@mail.sbu.ac.ir, E-mail: hr-sepangi@sbu.ac.ir [Department of Physics, Shahid Beheshti University, Evin, Tehran 19839 (Iran, Islamic Republic of)

    2008-08-15

    We obtain the virial theorem within the context of a brane-world model without mirror symmetry or any form of junction condition. Taking a constant curvature bulk (neglecting non-local bulk effects), the local bulk effects generate a geometrical mass, contributing to the gravitational energy which may be used to explain the virial mass discrepancy in clusters of galaxies. We fix the parameters of this model in agreement with observational data.

  18. Can local bulk effects explain the galactic dark matter?

    OpenAIRE

    Heydari-Fard, Malihe; Sepangi, Hamid R.

    2008-01-01

    We obtain the virial theorem within the context of a brane-world model without mirror symmetry or any form of junction condition. Taking a constant curvature bulk (neglecting non-local bulk effects), the local bulk effects generate a geometrical mass, contributing to the gravitational energy which may be used to explain the virial mass discrepancy in clusters of galaxies. We fix the parameter of this model in agreement with observational data.

  19. The Incredible Bulk

    CERN Document Server

    Fukushima, Keita; Kumar, Jason; Sandick, Pearl; Yamamoto, Takahiro

    2014-01-01

    Recent experimental results from the LHC have placed strong constraints on the masses of colored superpartners. The MSSM parameter space is also constrained by the measurement of the Higgs boson mass, and the requirement that the relic density of lightest neutralinos be consistent with observations. Although large regions of the MSSM parameter space can be excluded by these combined bounds, leptophilic versions of the MSSM can survive these constraints. In this paper we consider a scenario in which the requirements of minimal flavor violation, vanishing $CP$-violation, and mass universality are relaxed, specifically focusing on scenarios with light sleptons. We find a large region of parameter space, analogous to the original bulk region, for which the lightest neutralino is a thermal relic with an abundance consistent with that of dark matter. We find that these leptophilic models are constrained by measurements of the magnetic and electric dipole moments of the electron and muon, and that these models have ...

  20. Bulk muscles, loose cables.

    Science.gov (United States)

    Liyanage, Chamari R D G; Kodali, Venkata

    2014-01-01

    The accessibility and usage of body building supplements is on the rise with stronger internet marketing strategies by the industry. The dangers posed by the ingredients in them are underestimated. A healthy young man came to the emergency room with palpitations and feeling unwell. Initial history and clinical examination were non-contributory to find the cause. ECG showed atrial fibrillation. A detailed history for any over the counter or herbal medicine use confirmed that he was taking supplements to bulk muscle. One of the components in these supplements is yohimbine; the onset of symptoms coincided with the ingestion of this product and the patient is symptom free after stopping it. This report highlights the dangers to the public of consuming over the counter products with unknown ingredients and the consequential detrimental impact on health. PMID:25326558

  1. On the surface characteristics of a Zr-based bulk metallic glass processed by microelectrical discharge machining

    Science.gov (United States)

    Huang, Hu; Yan, Jiwang

    2015-11-01

    Microelectrical discharge machining (micro-EDM) performance of a Zr-based bulk metallic glass was investigated experimentally. Various discharge voltages and capacitances were used to study their effects on the material removal rate, cross-sectional profile, surface morphology and roughness, carbonization, and crystallization. Experimental results indicated that many randomly overlapped craters were formed on the EDMed surfaces, and their size and distribution were strongly dependent of the applied voltage and capacitance as well as their positions (center region or outer region), which further affected the surface roughness. Raman spectra and energy dispersive X-ray spectroscopy demonstrated that amorphous carbons originating from the decomposition of the EDM oil were deposited on the EDMed surface. Although some small sharp peaks appeared in the X-ray diffraction patterns of the micro-EDMed surfaces, a broad hump was maintained in all patterns, suggesting a dominant amorphous characteristic. Furthermore, crystallization was also affected by experimental conditions and machining positions. Results in this study indicate that micro-EDM under low discharge energy is useful for fabricating bulk metallic glass microstructures or components because of the ability to retain an amorphous structure.

  2. Social norms, trust and control of power theft in Uganda: Does bulk metering work for MSEs?

    International Nuclear Information System (INIS)

    Power theft is still rampant in many developing countries. Governments and utility providers tend to favor technical solutions, neglecting the socio-economic dimension. This article analyzes the interaction between the socio-economic factors trust, informal social norms, awareness and electricity pricing effect and technical control measures in Uganda. After reforming its power sector, Uganda introduced two technical innovations: bulk metering for micro and small enterprises (MSE) and prepaid metering for households. The bulk metering system imposes a strong form of social control among MSEs. Drawing on semi-structured interviews with 29 MSEs and 16 experts in Uganda, this article shows how well bulk metering works in practice. It finds that trust is key in the relations between electricity user and utility provider, between citizens and government overseeing the energy sector as well as within bulk metering groups of MSEs. The electricity price impacts MSEs' ability to pay and to some extent also their willingness to pay. Finally, power theft used to be accepted as an informal social norm. Change is happening, but is currently undermined by corruption and patronage networks in the energy sector and the political system, impacting people's attitude to compliance – regardless of the privatization of the electricity sector. -- Highlights: •Socio-economic factors impact the control of power theft. •Bulk metering works well for those MSE groups with high trust and information. •Sub-meters need to be available and energy recordings possible. •Prepaid metering more suitable for areas with a lot of social tension. •Long-term norm change and social acceptance depends on perceptions of political economy

  3. Bulk amorphous Mg-based alloys

    DEFF Research Database (Denmark)

    Pryds, Nini

    The present paper describes the preparation and properties of bulk amorphous quarternary Mg-based alloys and the influence of additional elements on the ability of the alloy to form bulk amorphous. The main goal is to find a Mg-based alloy system which shows both high strength to weight ratio and a...... low glass transition temperature. The alloys were prepared by using a relatively simple technique, i.e. rapid cooling of the melt in a copper wedge mould. The essential structural changes that are achieved by going from the amorphous to the crystalline state through the supercooled liquid state are...... discussed in this paper. On the basis of these measurements phase diagrams of the different systems were constructed. Finally, it is demonstrated that when pressing the bulk amorphous alloy onto a metallic dies at temperatures within the supercooled liquid region, the alloy faithfully replicates the surface...

  4. Development of superconductor bulk for superconductor bearing

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Chan Joong; Jun, Byung Hyuk; Park, Soon Dong (and others)

    2008-08-15

    Current carrying capacity is one of the most important issues in the consideration of superconductor bulk materials for engineering applications. There are numerous applications of Y-Ba-Cu-O (YBCO) bulk superconductors e.g. magnetic levitation train, flywheel energy storage system, levitation transportation, lunar telescope, centrifugal device, magnetic shielding materials, bulk magnets etc. Accordingly, to obtain YBCO materials in the form of large, single crystals without weak-link problem is necessary. A top seeded melt growth (TSMG) process was used to fabricate single crystal YBCO bulk superconductors. The seeded and infiltration growth (IG) technique was also very promising method for the synthesis of large, single-grain YBCO bulk superconductors with good superconducting properties. 5 wt.% Ag doped Y211 green compacts were sintered at 900 .deg. C {approx} 1200 .deg.C and then a single crystal YBCO was fabricated by an infiltration method. A refinement and uniform distribution of the Y211 particles in the Y123 matrix were achieved by sintering the Ag-doped samples. This enhancement of the critical current density was ascribable to a fine dispersion of the Y211 particles, a low porosity and the presence of Ag particles. In addition, we have designed and manufactured large YBCO single domain with levitation force of 10-13 kg/cm{sup 2} using TSMG processing technique.

  5. Non-isothermal crystallization kinetics and glass-forming ability of Ti{sub 41}Zr{sub 25}Be{sub 28}Fe{sub 6} bulk metallic glass investigated by differential scanning calorimetry

    Energy Technology Data Exchange (ETDEWEB)

    Gong, Pan; Zhao, Shaofan; Yao, Kefu [Tsinghua University, School of Materials Science and Engineering, Beijing (China); Wang, Xin [Hebei University of Technology, School of Materials Science and Engineering, Tianjin (China)

    2015-07-15

    The non-isothermal crystallization kinetics and glass-forming ability of Ti{sub 41}Zr{sub 25}Be{sub 28}Fe{sub 6} glassy alloy were investigated by differential scanning calorimetry. The activation energies corresponding to the characteristic temperatures have been calculated by Kissinger and Ozawa equations. Based on Kissinger-Akahira-Sunose and Ozawa-Flynn-Wall models, it has been found that the local activation energy is higher at the beginning of the crystallization process for the first exothermic peak. The local Avrami exponent indicates that the first-step crystallization is mainly a high-dimensional nucleation and growth with an increasing nucleation rate. According to the calculated fragility index, Ti{sub 41}Zr{sub 25}Be{sub 28}Fe{sub 6} alloy can be classified as ''strong glass former.'' The studied alloy also possesses a critical size up to centimeter order, and the high glass-forming ability is probably related to the relatively low Gibbs energy difference between the liquid and crystalline states. The critical cooling rate of Ti{sub 41}Zr{sub 25}Be{sub 28}Fe{sub 6} glassy alloy has also been determined using Barandiaran-Colmenero's method. (orig.)

  6. Micro manufacturing techniques and applications

    CERN Document Server

    Du, Ruxu; Li, Zifu

    2013-01-01

    Micro/meso-scale manufacturing has been developed in research fields of machining, forming, materials and others, but its potential to industries are yet to be fully realized. The theme of the current volume was to build a bridge joining academic research and industrial needs in micro manufacturing. Among the 12 papers selected for publication are three keynote addresses onmicro and desktop factories for micro/meso-scale manufacturing applicationsand future visions, tissue cutting mechanics and applications for needlecore biopsy and guidance, and micro-texturing onto amorphous carbonmaterials

  7. Zr基大块非晶合金在过冷液相区超塑性成形的摩擦行为及机理研究%Study on the Friction Behavior and Mechanism of Zr-based Bulk Metallic Glass Superplastic Forming in the Supercooled Liquid Region

    Institute of Scientific and Technical Information of China (English)

    郑志镇; 成蛟; 王新云; 李建军

    2009-01-01

    The friction behavior of Zr_(55) Al_(10)Ni_5Cu_(30) bulk metallic glass in the supercooled liquid region was investigated. The influence of forming temperature and velocity on friction factor was established by double cup extrusion test. The calibration curves of friction factor were evaluated by FE simulation and Kawamura's constitutive equation was adopted. Constant parameters in the constitutive equation were acquired by fitting the data from compression test. The results indicate that the friction factor of bulk metallic glass forming in the supercooled liquid region is between 0. 2 and 0. 7. With the temperature rising, the friction factor decreases in general under a low forming velocity. However, the friction factor increases slightly and then decreases abruptly under a high forming velocity. In low temperature area of supercooled liquid region, the friction factor increases abruptly with increasing of the forming velocity. While in high temperature area of supercooled liquid region, the friction factor decreases slightly with increasing of the forming velocity. The friction mechanism of bulk metallic glass forming in supercooled liquid region was analyzed by modern tribology theory. Adhesion is the dominant factor contributing to the friction of bulk metallic glass.%采用双杯挤压方法研究了成形温度、应变速率等工艺参数对Zr_(55) Al_(10) Ni_5 Cu_(30)块体非晶合金在过冷液相区塑性成形时模具和零件之间的摩擦行为的影响.采用有限元模拟方法获得大块非晶合金双杯挤压的摩擦因数标定曲线,有限元模拟中非晶合金的变形采用Kawamura的本构模型,将高温压缩实验的数据拟合,获得本构模型中的参数,结果表明非晶合金在过冷液相区内变形的摩擦因数在0.2~0.7之间.当应变速率较低时,随着温度的升高,摩擦因数总体上降低;而当应变速率较高时,随着温度的升高,摩擦因数先略有上升,然后急剧下降.当温度较低

  8. Inflation from bulk viscosity

    CERN Document Server

    Bamba, Kazuharu

    2015-01-01

    We explore the perfect fluid description of the inflationary universe. In particular, we investigate a fluid model with the bulk-viscosity term. We find that the three observables of inflationary cosmology: the spectral index of the curvature perturbations, the tensor-to-scalar ratio of the density perturbations, and the running of the spectral index, can be consistent with the recent Planck results. We also reconstruct the explicit equation of state (EoS) of the viscous fluid from the spectral index of the curvature perturbations compatible with the Planck analysis. In the reconstructed models of the viscous fluid, the tensor-to-scalar ratio of the density perturbations can satisfy the constraints obtained from the Planck satellite. The running of the spectral index can explain the Planck data. In addition, it is demonstrated that in the reconstructed models of the viscous fluid, the graceful exit from inflation can be realized. Furthermore, we show that the singular inflation can occur in the viscous fluid ...

  9. Bulk-Fill Resin Composites

    DEFF Research Database (Denmark)

    Benetti, Ana Raquel; Havndrup-Pedersen, Cæcilie; Honoré, Daniel;

    2015-01-01

    restorative procedure. The aim of this study, therefore, was to compare the depth of cure, polymerization contraction, and gap formation in bulk-fill resin composites with those of a conventional resin composite. To achieve this, the depth of cure was assessed in accordance with the International Organization...... for Standardization 4049 standard, and the polymerization contraction was determined using the bonded-disc method. The gap formation was measured at the dentin margin of Class II cavities. Five bulk-fill resin composites were investigated: two high-viscosity (Tetric EvoCeram Bulk Fill, SonicFill) and...... three low-viscosity (x-tra base, Venus Bulk Fill, SDR) materials. Compared with the conventional resin composite, the high-viscosity bulk-fill materials exhibited only a small increase (but significant for Tetric EvoCeram Bulk Fill) in depth of cure and polymerization contraction, whereas the low...

  10. Locality, bulk equations of motion and the conformal bootstrap

    CERN Document Server

    Kabat, Daniel

    2016-01-01

    We develop an approach to construct local bulk operators in a CFT to order 1/N^2. Since 4-point functions are not fixed by conformal invariance we use the OPE to categorize possible forms for a bulk operator. Using previous results on 3-point functions we construct a local bulk operator in each OPE channel. We then impose the condition that the bulk operators constructed in different channels agree, and hence give rise to a well-defined bulk operator. We refer to this condition as the "bulk bootstrap." We argue and explicitly show in some examples that the bulk bootstrap leads to some of the same results as the regular conformal bootstrap. In fact the bulk bootstrap provides an easier way to determine some CFT data, since it does not require knowing the form of the conformal blocks. This analysis clarifies previous results on the relation between bulk locality and the bootstrap for theories with a 1/N expansion, and it identifies a simple and direct way in which OPE coefficients and anomalous dimensions deter...

  11. A Coupled Cavity Micro Fluidic Dye Ring Laser

    OpenAIRE

    Gersborg-Hansen, M.; Balslev, S.; Mortensen, N. A.; Kristensen, A.

    2004-01-01

    We present a laterally emitting, coupled cavity micro fluidic dye ring laser, suitable for integration into lab-on-a-chip micro systems. The micro-fluidic laser has been successfully designed, fabricated, characterized and modelled. The resonator is formed by a micro-fluidic channel bounded by two isosceles triangle mirrors. The micro-fluidic laser structure is defined using photo lithography in 10 microns thick SU-8 polymer on a glass substrate. The micro fluidic channel is sealed by a glass...

  12. Micro Mobility Marketing

    DEFF Research Database (Denmark)

    Hosbond, Jens Henrik; Skov, Mikael B.

    2008-01-01

    Mobile marketing refers to marketing of services or goods using mobile technology and mobile marketing holds potentially great economical opportunities. Traditionally, mobile marketing has been viewed as mobility in the large taking place virtually anywhere, anytime. Further, research shows...... similarities and differences between micro mobility marketing and the traditional mobile marketing in the large. Finally, we suggest areas for further study.Journal of Targeting, Measurement and Analysis for Marketing (2007) 16, 68-77. doi:10.1057/palgrave.jt.5750058; published online 24 December 2007...... considerable number of studies on push-based SMS mobile marketing campaigns. This paper explores a related yet different form of mobile marketing namely micro mobility marketing. Micro mobility marketing denotes mobility in the small, meaning that promotion of goods takes place within a circumscribed location...

  13. Contribution at the study of stress release mechanism in chromia scales formed on Ni-30Cr and Fe-47Cr: multi-scale approach by Raman spectroscopy and Synchrotron micro-diffraction

    International Nuclear Information System (INIS)

    Chromia-former alloy are mainly used for high temperature applications. Their ability to form a protective thermal oxide scale allows reducing oxidation kinetics of the materials. In particular, Ni-Cr and Fe-Cr alloy forms a α-Cr2O3 scale at the surface. Durability of the metal/ceramic system depends on the mechanical integrity of this scale, and also of the scale damage which could appear during oxidation or cooling. These scale damages are closely correlated to the residual stress magnitude in the oxide and to the microstructure. In this work, Ni-30Cr and Fe-47Cr alloys oxidized in air at 800, 900 and 1000 C and a multi-scale approach is proposed to a analyse with accuracy residual stress magnitude both at macroscopic scale in the adherent oxide and at local scale through delaminated area. At macroscopic scale, residual stress magnitudes are determined thanks to conventional X-Ray diffraction and Raman spectroscopy. Delamination rate in the oxide scale and diffusional creep phenomena are quantified in function of metallurgical parameters leading to different microstructural state of the system. The influence of competition between these two stress release modes on scale damage is discussed. At microscopic scale, residual stress map through different types of delamination are performed thanks to Raman microspectroscopy and Synchrotron micro-diffraction. Raman microspectroscopy is particularly appropriated to analyze delamination locally formed, due to its lateral resolution. Observations by atomic force microscopy have been performed to describe the different delamination type (dimension, height). These morphological information and associated residual stresses allows confrontation to buckling mechanic and calculation of the interface toughness. Diagrams and maps concerning the scale damages have been done thanks to these analyses. (author)

  14. STUDY ON OCCURENCE FORM OF PLATINUM IN XINJIE Cu—Pt DEPOSIT BY NAA AND SCANNING PROTON MICROPROBE

    Institute of Scientific and Technical Information of China (English)

    李晓林; 童纯菡; 等

    1995-01-01

    A combination of NAA and micro-PIXE was used to study concentrations and distributions of platinum group elements (PGE) in ores from Xinjie Cu-Pt deposit.The NAA results of the bulk indicate that the ores belong to the enriched Pt-Pd type.The element concentration maps of scanning micro-PIXE for the ores show that the occurence form of Pt is independent arsenide minerals.No PGE were detected in chalcopyrite of Xinjie Cu-Pt deposit.These information are economically beneficial to the mineral smelting process.

  15. The in vitro and in vivo performance of a strontium-containing coating on the low-modulus Ti35Nb2Ta3Zr alloy formed by micro-arc oxidation.

    Science.gov (United States)

    Liu, Wei; Cheng, Mengqi; Wahafu, Tuerhongjiang; Zhao, Yaochao; Qin, Hui; Wang, Jiaxing; Zhang, Xianlong; Wang, Liqiang

    2015-07-01

    The β-titanium alloy is thought to be a promising alloy using as orthopedic or dental implants owing to its characteristics, which contains low elastic modulus, high corrosion resistance and well biocompatibility. Our previous study has reported that a new β-titanium alloy Ti35Nb2Ta3Zr showed low modulus close to human bone, equal tissue compatibility to a traditional implant alloy Ti6Al4V. In this study, micro-arc oxidation (MAO) was applied on the Ti35Nb2Ta3Zr alloy to enhance its surface characteristics and biocompatibility and osseointegration ability. Two different coatings were formed, TiO2 doped with calcium-phosphate coating (Ca-P) and calcium-phosphate-strontium coating (Ca-P-Sr). Then we evaluated the effects of the MAO coatings on the Ti35Nb2Ta3Zr alloy through in vitro and in vivo tests. As to the characteristics of the coatings, the morphology, chemical composition, surface roughness and contact angle of MAO coatings were tested by scanning electron microscopy, energy dispersive spectroscopy, atomic force microscopy, and video contact-angle measurement system respectively. Besides, we performed MTT assay, ALP test and cell morphology-adhesion test on materials to evaluate the MAOed coating materials' biocompatibility in vitro. The in vivo experiment was performed through rabbit model. Alloys were implanted into rabbits' femur shafts, then we performed micro-CT, histological and sequential fluorescent labeling analysis to evaluate implants' osseointegration ability in vivo. Finally, the Ca-P specimens and Ca-P-Sr specimens exhibited a significant enhancement in surface roughness, hydrophilicity, cell proliferation, cell adhesion. More new bone was found around the Ca-P-Sr coated alloy than Ca-P coated alloy and Ti35Nb2Ta3Zr alloy. In conclusion, the MAO treatment improved in vitro and in vivo performance of Ti35Nb2Ta3Zr alloy. The Ca-P-Sr coating may be a promising modified surface formed by MAO for the novel β-titanium alloy Ti35Nb2Ta3Zr. PMID

  16. Micro Manufacturing

    DEFF Research Database (Denmark)

    Hansen, Hans Nørgaard

    2003-01-01

    micro manufacturing system isn’t designed rationally and correctly, it will be high-cost, unreliable, and not robust. For micro products and systems it is a continuously increasing challenge to create the operational basis for an industrial production. As the products through product development......Manufacturing deals with systems that include products, processes, materials and production systems. These systems have functional requirements, constraints, design parameters and process variables. They must be decomposed in a systematic manner to achieve the best possible system performance. If a...... processes are made applicable to a large number of customers, the pressure in regard to developing production technologies that make it possible to produce the products at a reasonable price and in large numbers is growing. The micro/nano manufacturing programme at the Department of Manufacturing...

  17. High-dielectric-constant ferroelectric thin film and bulk ceramic capacitors for power electronics.

    Energy Technology Data Exchange (ETDEWEB)

    Auciello, O. H.; Baldo, P.; Baumann, P.; Erck, R. A.; Giumarra, J.; Im, J.; Kaufman, D. Y.; Lanagan, M. T.; Pan, M. J.; Streiffer, S. K.; Zebrowski, J.

    1999-08-10

    Significant effort is presently focused on reducing the size and weight of power electronic modules. To achieve these goals in high-power capacitors, alternative materials and fabrication processes are needed. Thin film (<0.5 {micro}m) and bulk capacitors that use perovskite-based ferroelectric dielectrics are promising alternative technologies. Ferroelectrics possess high dielectric constants, thus offering substantial increases in volumetric capacitance. In thin film form, these materials display low loss and high breakdown strength. The unique properties of some of these materials, such as a nonlinear dielectric response or a high energy-storage capacity accompanying a phase change, can be exploited for power electronic capacitors. Prototype capacitors of two such materials, (Ba,Sr)TiO{sub 3} and PbZrO{sub 3}, have been fabricated in both thin film and bulk ceramic form. The influence of fabrication conditions on dielectric properties has been studied. Initial studies have demonstrated the viability of perovskite ferroelectrics for next-generation capacitor components.

  18. Mining the bulk positron lifetime

    Energy Technology Data Exchange (ETDEWEB)

    Aourag, H.; Guittom, A. [Centre de Recherche Nucleaire d' Alger (CRNA), Alger Gare - Algiers (Algeria)

    2009-02-15

    We introduce a new approach to investigate the bulk positron lifetimes of new systems based on data-mining techniques. Through data mining of bulk positron lifetimes, we demonstrate the ability to predict the positron lifetimes of new semiconductors on the basis of available semiconductor data already studied. Informatics techniques have been applied to bulk positron lifetimes for different tetrahedrally bounded semiconductors in order to discover computational design rules. (copyright 2009 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  19. Mining the bulk positron lifetime

    International Nuclear Information System (INIS)

    We introduce a new approach to investigate the bulk positron lifetimes of new systems based on data-mining techniques. Through data mining of bulk positron lifetimes, we demonstrate the ability to predict the positron lifetimes of new semiconductors on the basis of available semiconductor data already studied. Informatics techniques have been applied to bulk positron lifetimes for different tetrahedrally bounded semiconductors in order to discover computational design rules. (copyright 2009 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  20. Advances in bulk port development

    Energy Technology Data Exchange (ETDEWEB)

    Soros, P. (Soros Associates Consulting Engineers, New York, NY (USA))

    1991-03-01

    The article features several recently developed bulk ports which illustrate aspects of new technology or concepts in maritime transport. Low handling capacity bulk terminals at Ponta da Madeira, Brazil and Kooragang Island, Australia and the low-cost bulk port at Port of Corpus Christi, Texas are described. Operations at the ports of Pecket and Tocopilla in Chile, which had special technical problems, are mentioned. Coal terminals at Port Kembla, Australia and St. Johns River in Florid Jacksonville, Florida are featured as examples of terminals which had to be designed to meet high environmental standards. 13 refs., 2 figs., 14 photos.

  1. High numerical aperture all-dielectric metasurface micro-lenses

    NARCIS (Netherlands)

    Silvestri, F.; Gerini, G.; Pisano, E.; Galdi, V.

    2015-01-01

    In this paper, the design principles and the sensitivity analysis needed for the realization of a high numerical aperture metasurface micro-lens are presented. The metasurface micro-lens is realized defining a surface with spatially-variant dielectric resonators embedded in a dielectric bulk. The de

  2. A multi-scale friction model framework for full scale sheet forming simulations

    Science.gov (United States)

    Hol, J.; Meinders, T.; Huétink, J.

    2011-05-01

    In this paper a numerical framework is proposed which accounts for the most important friction mechanisms. Static flattening and flattening due to bulk strain are accounted for by theoretical models on a microscale. Based on statistical parameters a fast and efficient translation from micro- to macro modeling is included. A general overview of the friction model is presented and the translation from micro to macro modeling is outlined. The development of real area of contact is described by the flattening models and the effect of ploughing and adhesion on the coefficient of friction is described by a micro-scale friction model. A brief theoretical background of these models is given. The flattening models are validated by means of FE simulations on microscale and the feasibility of the advanced macroscopic friction model is proven by a full scale sheet metal forming simulation.

  3. Teaching Form as Form

    DEFF Research Database (Denmark)

    Keiding, Tina Bering

    2012-01-01

    understanding of form per se, or, to use an expression from this text, of form as form. This challenge can be reduced to one question: how can design teaching support students in achieving not only the ability to recognize and describe different form-related concepts in existing design (i.e. analytical and...

  4. Bulk viscous cosmology with causal transport theory

    International Nuclear Information System (INIS)

    We consider cosmological scenarios originating from a single imperfect fluid with bulk viscosity and apply Eckart's and both the full and the truncated Müller-Israel-Stewart's theories as descriptions of the non-equilibrium processes. Our principal objective is to investigate if the dynamical properties of Dark Matter and Dark Energy can be described by a single viscous fluid and how such description changes when a causal theory (Müller-Israel-Stewart's, both in its full and truncated forms) is taken into account instead of Eckart's non-causal one. To this purpose, we find numerical solutions for the gravitational potential and compare its behaviour with the corresponding ΛCDM case. Eckart's and the full causal theory seem to be disfavoured, whereas the truncated theory leads to results similar to those of the ΛCDM model for a bulk viscous speed in the interval 10−11 || cb2 ∼−8

  5. Brane plus Bulk Supersymmetry in Ten Dimensions

    CERN Document Server

    Bergshoeff, E A; Ortín, Tomas; Roest, D; Van Proeyen, A

    2001-01-01

    We discuss a generalized form of IIA/IIB supergravity depending on all R-R potentials C^(p) (p=0,1,...,9) as the effective field theory of Type IIA/IIB superstring theory. For the IIA case we explicitly break this R-R democracy to either p=5 which allows us to write a new bulk action that can be coupled to N=1 supersymmetric brane actions. The case of 8-branes is studied in detail using the new bulk & brane action. The supersymmetric negative tension branes without matter excitations can be viewed as orientifolds in the effective action. These D8-branes and O8-planes are fundamental in Type I' string theory. A BPS 8-brane solution is given which satisfies the jump conditions on the wall. As an application of our results we derive a quantization of the mass parameter and the cosmological constant in string units.

  6. Bulk Nuclear Properties from Reactions

    OpenAIRE

    Danielewicz, P.

    2002-01-01

    Extraction of bulk nuclear properties by comparing reaction observables to results from semiclassical transport-model simulations is discussed. Specific properties include the nuclear viscosity, incompressibility and constraints on the nuclear pressure at supranormal densities.

  7. Bulk charges in eleven dimensions

    CERN Document Server

    Hawking, Stephen William

    1998-01-01

    Eleven dimensional supergravity has electric type currents arising from the Chern-Simon and anomaly terms in the action. However the bulk charge integrates to zero for asymptotically flat solutions with topological trivial spatial sections. We show that by relaxing the boundary conditions to generalisations of the ALE and ALF boundary conditions in four dimensions one can obtain static solutions with a bulk charge preserving between 1/16 and 1/4 of the supersymmetries. One can introduce membranes with the same sign of charge into these backgrounds. This raises the possibility that these generalized membranes might decay quantum mechanically to leave just a bulk distribution of charge. Alternatively and more probably, a bulk distribution of charge can decay into a collection of singlely charged membranes. Dimensional reductions of these solutions lead to novel representations of extreme black holes in four dimensions with up to four charges. We discuss how the eleven-dimensional Kaluza-Klein monopole wrapped a...

  8. Development of 3d micro-nano hybrid patterns using anodized aluminum and micro-indentation

    International Nuclear Information System (INIS)

    We developed a simple and cost-effective method of fabricating 3D micro-nano hybrid patterns in which micro-indentation is applied on the anodized aluminum substrate. Nano-patterns were formed first on the aluminum substrate, and then micro-patterns were fabricated by deforming the nano-patterned aluminum substrate. Hemispherical nano-patterns with a 150 nm-diameter on an aluminum substrate were fabricated by anodizing and alumina removing process. Then, micro-pyramid patterns with a side-length of 50 μm were formed on the nano-patterns using micro-indentation. To verify 3D micro-nano hybrid patterns, we replicated 3D micro-nano hybrid patterns by a hot-embossing process. 3D micro-nano hybrid patterns may be used in nano-photonic devices and nano-biochips applications

  9. Development of 3d micro-nano hybrid patterns using anodized aluminum and micro-indentation

    Energy Technology Data Exchange (ETDEWEB)

    Shin, Hong Gue; Kwon, Jong Tae [Division of Mechanical Engineering and Mechatronics, Kangwon National University, 1 Kangwondaehakgil, Chunchon, Gangwon-do, 200-701 (Korea, Republic of); Seo, Young Ho [Division of Mechanical Engineering and Mechatronics, Kangwon National University, 1 Kangwondaehakgil, Chunchon, Gangwon-do, 200-701 (Korea, Republic of)], E-mail: mems@kangwon.ac.kr; Kim, Byeong Hee [Division of Mechanical Engineering and Mechatronics, Kangwon National University, 1 Kangwondaehakgil, Chunchon, Gangwon-do, 200-701 (Korea, Republic of)

    2008-07-31

    We developed a simple and cost-effective method of fabricating 3D micro-nano hybrid patterns in which micro-indentation is applied on the anodized aluminum substrate. Nano-patterns were formed first on the aluminum substrate, and then micro-patterns were fabricated by deforming the nano-patterned aluminum substrate. Hemispherical nano-patterns with a 150 nm-diameter on an aluminum substrate were fabricated by anodizing and alumina removing process. Then, micro-pyramid patterns with a side-length of 50 {mu}m were formed on the nano-patterns using micro-indentation. To verify 3D micro-nano hybrid patterns, we replicated 3D micro-nano hybrid patterns by a hot-embossing process. 3D micro-nano hybrid patterns may be used in nano-photonic devices and nano-biochips applications.

  10. An experimental approach of milli-structure sheet metal forming

    International Nuclear Information System (INIS)

    Milli-structure components are classified as a component group whose size is between macro and micro scales, that is, about less than 20mm and larger than 1mm. The forming of these components has a typical phenomenon of bulk deformation with thin sheets because of the forming size. In this study, milli-structure rectangular cup drawing is analyzed and measured using the finite element method and experiment. Generally, milli-structure containers or cases like cellular phone vibrator consist of rectangular-shaped drawing to save installation space. A systematic approach is established for the design and the experiment of the forming processes for rectangular milli-structure cases. To verify the simulation results, the experimental investigations were also carried out on a real industrial product. The numerical analysis by FEM shows good agreement with the experimental results in view of the deformation shape of the product

  11. Infrared micro-optics technologies

    Science.gov (United States)

    Krogmann, Dirk; Tholl, Hans D.

    2004-08-01

    Bodenseewerk GmbH generally works on challenging projects comprising Microsystems, e.g. micro-optics (micro-lenses, micro-mirrors). We utilize state-of-the-art laboratory equipment and simulation software (e.g. optical design with ZEMAX, ASAP and GLAD). Our recent activities on the development of several infrared micro-optical devices focus on high speed imaging of scenes with high angular resolution including the analysis of physical properties of the detected light (e.g. spectral content, polarization) utilizing staring IR sensors with focal-plane-arrays operating in a snap shot mode at high frame rates. We report about the development of so called micro-optical multiplexers which: (a) comprise micro-optical arrays and electro-mechanical micro-actuators, (b) image several fields of view with high resolution onto a single focal-plane-array, (c) image several fields of view with enhanced spatial resolution [by the factor of four compared to (b)] in a modified realization onto one focal-plane-array and (d) analyze the spectral content of an image using a single-band photon detector-array and multi-frame processing. The micro-opto-electro-mechanical multiplexer (MOEM) systems all consist of a primary objective, a MOEM image-steering respectively image coding device and a secondary objective. The primary objective images one or more suitable formed individual fields of view onto a common intermediate image plane. The MOEM devices comprise combinations of focusing and defocusing micro-lens-arrays, micro-shutter-arrays and micro-filter-arrays which are mounted parallel to each other near the intermediate image plane. The MOEM devices exhibit their above mentioned function modes by laterally displacing the micro-arrays with the help of modern micro-actuators. The secondary objective is utilized as relay optical stage. A modern common focal-plane-array is used as detector device. The micro-actuators responsible for the relative displacement of the micro-arrays are highly

  12. Magnetism and homogenization of micro-resonators

    CERN Document Server

    Kohn, Robert V

    2007-01-01

    Arrays of cylindrical metal micro-resonators embedded in a dielectric matrix were proposed by Pendry, et. al., in 1999 as a means of creating a microscopic structure that exhibits strong bulk magnetic behavior at frequencies not realized in nature. This behavior arises for H-polarized fields in the quasi-static regime, in which the scale of the micro-structure is much smaller than the free-space wavelength of the fields. We carry out both formal and rigorous two-scale homogenization analyses, paying special attention to the appropriate method of averaging, which does not involve the usual cell averages. We show that the effective magnetic and dielectric coefficients obtained by means of such averaging characterize a bulk medium that, to leading order, produces the same scattering data as the micro-structured composite.

  13. Plasma cermet WC-Co coatings hardened by micro- and nanosized carbides

    International Nuclear Information System (INIS)

    Significant changes of the structure and phase composition of formed cermet WC-Co coatings are possible under plasma spraying of mechanically alloyed nano- and micro-sized powders. WC carbide content can be lowered from 43.9% in initial powder to 3.8% in coating. During deposition process, intense formation of non-equilibrium phases takes place which are fixed in the coating at quenching from a liquid state at cooling rate of 108 K/s. In spite of the changes of phase composition of WC-Co hard alloy, inner bulk of sprayed particles has a high (15-23 GPa) value of microhardness

  14. Bulk metallic glasses: A new class of engineering materials

    Indian Academy of Sciences (India)

    Joysurya Basu; S Ranganathan

    2003-06-01

    Bulk glass-forming alloys have emerged over the past fifteen years with attractive properties and technological promise. A number of alloy systems based on lanthanum, magnesium, zirconium, palladium, iron, cobalt and nickel have been discovered. Glass-forming ability depends on various factors like enthalpy of mixing, atomic size and multicomponent alloying. A number of processes is available to synthesise bulk metallic glasses. The crystallisation behaviour and mechanical properties of these alloys pose interesting scientific questions. Upon crystallisation many of these glasses transform to bulk nanocrystals and nanoquasicrystals. A detailed study of the structure and the crystallisation behaviour of glasses has enabled the elucidation of the possible atomic configuration in liquid alloys. Their crystallisation behaviour can be exploited to synthesise novel nanocomposite microstructures and their mechanical properties can be enhanced. A broad overview of the present status of the science and technology of bulk metallic glasses and their potential technological uses is presented.

  15. Evolution of bulk damage initiation in DKDP

    Science.gov (United States)

    Carr, Christopher W.; McMillian, T. H.; Staggs, Mike C.; Radousky, Harry B.; Demos, Stavros G.

    2003-05-01

    We investigate the evolution of laser-induced damage initiated in the bulk of DKDP crystals using in-situ microscopy. Experimental results indicate that at peek fluences greater than 10 J/cm2, damage sites are formed with increasing number as a function of the laser fluence. Following plasma formation, cracks are observed which grow in size for tens of seconds after the termination of the laser pulse. Subsequent irradiation leads to modest increase in size only during the initial 2-5 pulses. Experimental results suggest that there is also relaxation of the stresses adjacent to a damage site for several hours after initial damage.

  16. Looking for a bulk point

    CERN Document Server

    Maldacena, Juan; Zhiboedov, Alexander

    2015-01-01

    We consider Lorentzian correlators of local operators. In perturbation theory, singularities occur when we can draw a position-space Landau diagram with null lines. In theories with gravity duals, we can also draw Landau diagrams in the bulk. We argue that certain singularities can arise only from bulk diagrams, not from boundary diagrams. As has been previously observed, these singularities are a clear diagnostic of bulk locality. We analyze some properties of these perturbative singularities and discuss their relation to the OPE and the dimensions of double-trace operators. In the exact nonperturbative theory, we expect no singularity at these locations. We prove this statement in 1+1 dimensions by CFT methods.

  17. Gamma probe dry bulk densities

    International Nuclear Information System (INIS)

    The gamma density probe is a useful instrument for measuring water content in small volumes of soil. Essentially, the gamma probe measures the density of the soil and water between a source and a detector. To transpose the gamma densities into water content, the dry bulk density of the soil is needed. A nondestructive method for estimating dry bulk densities for use with the gamma probe is proposed. The procedure is based on the assumption that water content values in a field dry condition were more stable than the dry bulk density values and could be transferred from one point to another. The procedure was successfully used on three areas in Reynolds Creek Experimental Watershed in southwest Idaho. (U.S.)

  18. Bulk Viscosity of Interacting Hadrons

    OpenAIRE

    Wiranata, A.; M. Prakash

    2009-01-01

    We show that first approximations to the bulk viscosity $\\eta_v$ are expressible in terms of factors that depend on the sound speed $v_s$, the enthalpy, and the interaction (elastic and inelastic) cross section. The explicit dependence of $\\eta_v$ on the factor $(\\frac 13 - v_s^2)$ is demonstrated in the Chapman-Enskog approximation as well as the variational and relaxation time approaches. The interesting feature of bulk viscosity is that the dominant contributions at a given temperature ari...

  19. Bulk Viscosity of Interacting Hadrons

    CERN Document Server

    Wiranata, A

    2009-01-01

    We show that first approximations to the bulk viscosity $\\eta_v$ are expressible in terms of factors that depend on the sound speed $v_s$, the enthalpy, and the interaction (elastic and inelastic) cross section. The explicit dependence of $\\eta_v$ on the factor $(\\frac 13 - v_s^2)$ is demonstrated in the Chapman-Enskog approximation as well as the variational and relaxation time approaches. The interesting feature of bulk viscosity is that the dominant contributions at a given temperature arise from particles which are neither extremely nonrelativistic nor extremely relativistic. Numerical results for a model binary mixture are reported.

  20. Cavitation instability in bulk metallic glasses

    Directory of Open Access Journals (Sweden)

    Dai L.H.

    2015-01-01

    Full Text Available Recent experiments have shown that fracture surfaces of bulk metallic glasses (BMGs usually exhibit an intriguing nanoscale corrugation like fractographic feature mediated by nanoscale void formation. We attribute the onset of this nanoscale corrugation to TTZs (tension transformation zones mediated cavitation. In our recent study, the spall experiments of Zr-based BMG using a single-stage light gas gun were performed. To uncover the mechanisms of the spallation damage nucleation and evolution, the samples were designed to be subjected to dynamic tensile loadings of identical amplitude but with different durations by making use of the multi-stress pulse and the double-flyer techniques. It is clearly revealed that the macroscopic spall fracture in BMGs originates from the nucleation, growth and coalescence of micro-voids. Then, a microvoid nucleation model of BMGs based on free volume theory is proposed, which indicates that the nucleation of microvoids at the early stage of spallation in BMGs is resulted from diffusion and coalescence of free volume. Furthermore, a theoretical model of void growth in BMGs undergoing remote dynamic hydrostatic tension is developed. The critical condition of cavitation instability is obtained. It is found that dynamic void growth in BMGs can be well controlled by a dimensionless inertial number characterizing the competition between intrinsic and extrinsic time scales. To unveil the atomic-level mechanism of cavitation, a systematic molecular dynamics (MD simulation of spallation behaviour of a binary metallic glass with different impact velocities was performed. It is found that micro-void nucleation is determined TTZs while the growth is controlled by shear transformation zones (STZs at atomic scale.

  1. Cavitation instability in bulk metallic glasses

    Science.gov (United States)

    Dai, L. H.; Huang, X.; Ling, Z.

    2015-09-01

    Recent experiments have shown that fracture surfaces of bulk metallic glasses (BMGs) usually exhibit an intriguing nanoscale corrugation like fractographic feature mediated by nanoscale void formation. We attribute the onset of this nanoscale corrugation to TTZs (tension transformation zones) mediated cavitation. In our recent study, the spall experiments of Zr-based BMG using a single-stage light gas gun were performed. To uncover the mechanisms of the spallation damage nucleation and evolution, the samples were designed to be subjected to dynamic tensile loadings of identical amplitude but with different durations by making use of the multi-stress pulse and the double-flyer techniques. It is clearly revealed that the macroscopic spall fracture in BMGs originates from the nucleation, growth and coalescence of micro-voids. Then, a microvoid nucleation model of BMGs based on free volume theory is proposed, which indicates that the nucleation of microvoids at the early stage of spallation in BMGs is resulted from diffusion and coalescence of free volume. Furthermore, a theoretical model of void growth in BMGs undergoing remote dynamic hydrostatic tension is developed. The critical condition of cavitation instability is obtained. It is found that dynamic void growth in BMGs can be well controlled by a dimensionless inertial number characterizing the competition between intrinsic and extrinsic time scales. To unveil the atomic-level mechanism of cavitation, a systematic molecular dynamics (MD) simulation of spallation behaviour of a binary metallic glass with different impact velocities was performed. It is found that micro-void nucleation is determined TTZs while the growth is controlled by shear transformation zones (STZs) at atomic scale.

  2. Influence of bulk pre-straining on the size effect in nickel compression pillars

    Energy Technology Data Exchange (ETDEWEB)

    Schneider, A.S., E-mail: Andreas.schneider@inm-gmbh.de [INM-Leibniz Institute for New Materials, Campus D2 2, 66123 Saarbruecken (Germany); Kiener, D. [University of Leoben, Department of Materials Physics, Jahnstr. 12, 8700 Leoben (Austria); Yakacki, C.M. [Department of Mechanical Engineering, University of Colorado Denver, Denver 80217 (United States); Maier, H.J. [University of Paderborn, Lehrstuhl fuer Werkstoffkunde (Materials Science), 33098 Paderborn (Germany); Gruber, P.A. [Karlsruhe Institute of Technology, Institute for Applied Materials, Kaiserstr. 12, 76131 Karlsruhe (Germany); Tamura, N.; Kunz, M. [Advanced Light Source (ALS), Lawrence Berkeley National Laboratory (LBNL), 1 Cyclotron Road, Berkeley, CA 94720 (United States); Minor, A.M. [Department of Materials Science and Engineering, University of California, Berkeley, and National Center for Electron Microscopy, Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States); Frick, C.P. [University of Wyoming, Mechanical Engineering Department, 1000 East University Avenue, Laramie, WY 82071 (United States)

    2013-01-01

    Micro-compression tests were performed on pre-strained nickel (Ni) single crystals in order to investigate the influence of the initial dislocation arrangement on the size dependence of small-scale metal structures. A bulk Ni sample was grown using the Czochralski method and sectioned into four compression samples, which were then pre-strained to nominal strains of 5, 10, 15 and 20%. Bulk samples were then characterized using transmission electron microscopy (TEM), micro-Laue diffraction, and electron backscatter diffraction. TEM results show that a dislocation cell structure was present for all deformed samples, and Laue diffraction demonstrated that the internal strain increased with increased amount of pre-straining. Small-scale pillars with diameters from 200 nm to 5 {mu}m were focused ion beam (FIB) machined from each of the four deformed bulk samples and further compressed via a nanoindenter equipped with a flat diamond punch. Results demonstrate that bulk pre-straining inhibits the sample size effect. For heavily pre-strained bulk samples, the deformation history does not affect the stress-strain behavior, as the pillars demonstrated elevated strength and rather low strain hardening over the whole investigated size range. In situ TEM and micro-Laue diffraction measurements of pillars confirmed little change in dislocation density during pillar compression. Thus, the dislocation cell walls created by heavy bulk pre-straining become the relevant internal material structure controlling the mechanical properties, dominating the sample size effect observed in the low dislocation density regime.

  3. Pre-stressed piezoelectric bimorph micro-actuators based on machined 40 µm PZT thick films: batch scale fabrication and integration with MEMS

    International Nuclear Information System (INIS)

    The projected force–displacement capability of piezoelectric ceramic films in the 20–50 µm thickness range suggests that they are well suited to many micro-fluidic and micro-pneumatic applications. Furthermore when they are configured as bending actuators and operated at ∼ 1 V µm−1 they do not necessarily conform to the high-voltage, very low-displacement piezoelectric stereotype. Even so they are rarely found today in commercial micro-electromechanical devices, such as micro-pumps and micro-valves, and the main barriers to making them much more widely available would appear to be processing incompatibilities rather than commercial desirability. In particular, the issues associated with integration of these devices into MEMS at the production level are highly significant and they have perhaps received less attention in the mainstream than they deserve. This paper describes a fabrication route based on ultra-precision ceramic machining and full-wafer bonding for cost-effective batch scale production of thick film PZT bimorph micro-actuators and their integration with MEMS. The resulting actuators are pre-stressed (ceramic in compression) which gives them added performance, they are true bimorphs with bi-directional capability and they exhibit full bulk piezoelectric ceramic properties. The devices are designed to integrate with ancillary systems components using transfer-bonding techniques. The work forms part of the European Framework 6 Project 'Q2M—Quality to Micro'

  4. Bulk charges in eleven dimensions

    Science.gov (United States)

    Hawking, S. W.; Taylor-Robinson, M. M.

    1998-07-01

    Eleven dimensional supergravity has electric type currents arising from the Chern-Simon and anomaly terms in the action. However the bulk charge integrates to zero for asymptotically flat solutions with topological trivial spatial sections. We show that by relaxing the boundary conditions to generalisations of the ALE and ALF boundary conditions in four dimensions one can obtain static solutions with a bulk charge. Solutions involving anomaly terms preserve between 1/16 and 1/4 of the supersymmetries but Chern-Simons fluxes generally break all of the remaining supersymmetry. One can introduce membranes with the same sign of charge into these backgrounds. This raises the possibility that these generalized membranes might decay quantum mechanically to leave just a bulk distribution of charge. Alternatively and more probably, a bulk distribution of charge can decay into a collection of singly charged membranes. Dimensional reductions of these solutions lead to novel representations of extreme black holes in four dimensions with up to four charges. We discuss how the eleven-dimensional Kaluza-Klein monopole wrapped around a space with non-zero first Pontryagin class picks up an electric charge proportional to the Pontryagin number.

  5. Bulk viscosity and deflationary universes

    CERN Document Server

    Lima, J A S; Waga, I

    2007-01-01

    We analyze the conditions that make possible the description of entropy generation in the new inflationary model by means of a nearequilibrium process. We show that there are situations in which the bulk viscosity cannot describe particle production during the coherent field oscillations phase.

  6. Longitudinal bulk acoustic mass sensor

    DEFF Research Database (Denmark)

    Hales, Jan Harry; Teva, Jordi; Boisen, Anja;

    2009-01-01

    A polycrystalline silicon longitudinal bulk acoustic cantilever is fabricated and operated in air at 51 MHz. A mass sensitivity of 100 Hz/fg (1 fg=10(-15) g) is obtained from the preliminary experiments where a minute mass is deposited on the device by means of focused ion beam. The total noise i...

  7. Cosmic no hair for braneworlds with a bulk dilaton field

    Science.gov (United States)

    Lidsey, James E.; Seery, David

    2005-11-01

    Braneworld cosmology supported by a bulk scalar field with an exponential potential is developed. A general class of separable backgrounds for both single and two-brane systems is derived, where the bulk metric components are given by products of world volume and bulk coordinates and the world-volumes represent any anisotropic and inhomogeneous solution to an effective four-dimensional Brans-Dicke theory of gravity. We deduce a cosmic no hair theorem for all ever-expanding, spatially homogeneous Bianchi world volumes and find that the spatially flat and isotropic inflationary scaling solution represents a late-time attractor when the bulk potential is sufficiently flat. The dependence of this result on the separable nature of the bulk metric is investigated by applying the techniques of Hamilton-Jacobi theory to five-dimensional Einstein gravity. We employ the spatial gradient expansion method to determine the asymptotic form of the bulk metric up to third-order in spatial gradients. It is found that the condition for the separable form of the metric to represent the attractor of the system is precisely the same as that for the four-dimensional world-volume to isotropize. We also derive the fourth-order contribution to the Hamilton-Jacobi generating functional. Finally, we conclude by placing our results within the context of the holographic approach to braneworld cosmology.

  8. Polymerisationseigenschaften von Bulk-Fill Kompositen

    OpenAIRE

    Maier, Eva

    2015-01-01

    Hintergrund und Ziele: Untersuchung der Polymerisationseigenschaften von Bulk-Fill Kompositen bzgl. Konversionsrate (degree of conversion = DC), Vickers-Härte (HV), Polymerisationsschrumpfungsstress (PSS) und Polymerisationsvolumenschrumpfung (PVS) im Vergleich zu konventionellen Kompositen. Material und Methode: Untersucht wurden die Bulk-Fill Komposite Filtek Bulk Fill Flowable (FBF, 3M ESPE, Seefeld), Surefil Smart Dentin Replacement (SDR, Dentsply, Konstanz), Tetric EvoCeram Bulk Fill...

  9. Crack evolution in bulk metallic glasses

    International Nuclear Information System (INIS)

    In the present study, the mechanisms underlying plastic deformation of a Ni-based bulk metallic glass (BMG) are explored. Based on the microstructural investigations, a model is proposed how fracture emerges in BMGs. After deformation, the glass is macroscopically more fragile indicating a decrease in the viscosity within the shear bands due to shear softening. These fluctuations of viscosity and therefore Poisson ratio between the deformed and undeformed regions appear to be the initiation sites for nanometer-scale cracks, which are aligned parallel to the applied force. Coalescence of voids is believed to form these small cracks, which eventually interconnect along the interface between the sheared and unsheared regions to form a detrimental defect resulting in fracture.

  10. DEPLOYMENT OF THE BULK TRITIUM SHIPPING PACKAGE

    Energy Technology Data Exchange (ETDEWEB)

    Blanton, P.

    2013-10-10

    A new Bulk Tritium Shipping Package (BTSP) was designed by the Savannah River National Laboratory to be a replacement for a package that has been used to ship tritium in a variety of content configurations and forms since the early 1970s. The BTSP was certified by the National Nuclear Safety Administration in 2011 for shipments of up to 150 grams of Tritium. Thirty packages were procured and are being delivered to various DOE sites for operational use. This paper summarizes the design features of the BTSP, as well as associated engineered material improvements. Fabrication challenges encountered during production are discussed as well as fielding requirements. Current approved tritium content forms (gas and tritium hydrides), are reviewed, as well as, a new content, tritium contaminated water on molecular sieves. Issues associated with gas generation will also be discussed.

  11. Tuneable film bulk acoustic wave resonators

    CERN Document Server

    Gevorgian, Spartak Sh; Vorobiev, Andrei K

    2013-01-01

    To handle many standards and ever increasing bandwidth requirements, large number of filters and switches are used in transceivers of modern wireless communications systems. It makes the cost, performance, form factor, and power consumption of these systems, including cellular phones, critical issues. At present, the fixed frequency filter banks based on Film Bulk Acoustic Resonators (FBAR) are regarded as one of the most promising technologies to address performance -form factor-cost issues. Even though the FBARs improve the overall performances the complexity of these systems remains high.  Attempts are being made to exclude some of the filters by bringing the digital signal processing (including channel selection) as close to the antennas as possible. However handling the increased interference levels is unrealistic for low-cost battery operated radios. Replacing fixed frequency filter banks by one tuneable filter is the most desired and widely considered scenario. As an example, development of the softwa...

  12. Fabrication, Micro-structural Analysis, and Mechanical Testing of High Density Polymeric Foam

    Science.gov (United States)

    Marks, Trevor Gustov

    Foams, or what are often called cellular solids, are some of the most widely used materials in the modern era. In general, foam is a porous substance formed by the introduction of gas filled pores into condensed matter; the result is typically a light weight substance with properties related to the base (non-porous) medium. Applications of foams include: vibration dampening, energy mitigation (such as packaging and bike helmets), insulation, filtration, and flotation. The focus of this work is on the properties of flexible elastomeric foam of high relative-density. The bulk of existing literature on elastomeric foam is concerned with foam of low relative-density (ratio of the foam density to the density of the material from which the foam is formed ≤ 0.1). The relationship between the micro-structure of high relative-density foam and its mechanical response has, in large part, not been subjected to systematic investigation heretofore. The present work examines how the micro-structural features of pore shape, size, and location affect the macro-structural response of relative high density foam to compressive loading. In order to carry out this study, methods were developed and employed to control a foam's micro-structure, and hence its mechanical response, with the use of temporary pore forming particles and micron scale inclusions. Advanced microscopy techniques were used to observe, in situ, the evolution of a foam's micro-structure under compressive loading, and the results were correlated with the evolution of the foam's stress - strain response. Additionally, quantitative methods were developed and employed to describe numerically the foam's micro-structural features, such as: (i), pore shape, (ii), pore size, and (iii), the arrangement of the pores with respect to each other. Numerous foams were produced, tested, and subjected to the methodology developed for this study.

  13. MicroED data collection and processing

    Energy Technology Data Exchange (ETDEWEB)

    Hattne, Johan; Reyes, Francis E.; Nannenga, Brent L.; Shi, Dan; Cruz, M. Jason de la [Janelia Research Campus, Howard Hughes Medical Institute, Ashburn, VA 20147 (United States); Leslie, Andrew G. W. [Medical Research Council Laboratory of Molecular Biology, Cambridge (United Kingdom); Gonen, Tamir, E-mail: gonent@janelia.hhmi.org [Janelia Research Campus, Howard Hughes Medical Institute, Ashburn, VA 20147 (United States)

    2015-07-01

    The collection and processing of MicroED data are presented. MicroED, a method at the intersection of X-ray crystallography and electron cryo-microscopy, has rapidly progressed by exploiting advances in both fields and has already been successfully employed to determine the atomic structures of several proteins from sub-micron-sized, three-dimensional crystals. A major limiting factor in X-ray crystallography is the requirement for large and well ordered crystals. By permitting electron diffraction patterns to be collected from much smaller crystals, or even single well ordered domains of large crystals composed of several small mosaic blocks, MicroED has the potential to overcome the limiting size requirement and enable structural studies on difficult-to-crystallize samples. This communication details the steps for sample preparation, data collection and reduction necessary to obtain refined, high-resolution, three-dimensional models by MicroED, and presents some of its unique challenges.

  14. Investigation of Ion Backflow in Bulk Micromegas Detectors

    CERN Document Server

    Bhattacharya, Purba; Mukhopadhyay, Supratik; Bhattacharya, Sudeb; Majumdar, Nayana; Sarkar, Sandip; Colas, Paul; Attie, David

    2016-01-01

    The operation of gas detectors is often limited by secondary effects, originating from avalanche-induced photons and ions. Ion backflow is one of the effects limiting the operation of a gas detector at high flux, by giving rise to space charge which disturbs the electric field locally. For the Micromegas detector, a large fraction of the secondary positive ions created in the avalanche can be stopped at the micro-mesh. The present work involves measurements of the ion backflow fraction (using an experimental setup comprising of two drift planes) in bulk Micromegas detectors as a function of detector design parameters. These measured characteristics have also been compared in detail to numerical simulations using the Garfield framework that combines packages such as neBEM, Magboltz and Heed. Further, the effect of using a second micro-mesh on ion backflow and other parameters has been studied numerically.

  15. BEHAVIORS OF BULK METALLIC GLASS UNDER SHOCK LOADING

    OpenAIRE

    ATROSHENKO S.A.

    2016-01-01

    The high-strain-rate method of materials for dynamic strength investigations under micro and sub-microsecond durations of shock loads on the base of electrical explosion of conductors was developed. The experimental investigations of dynamic properties for bulk metallic glass on the base of Ti and Zr under shock loads of sub-microsecond duration (~0.5-0.7 μs) in the pressure range up to 12 GPa were carried out. The values of Hugoniot elastic limit (HEL) and spall strength for these amorphous ...

  16. Coulombic Fluids Bulk and Interfaces

    CERN Document Server

    Freyland, Werner

    2011-01-01

    Ionic liquids have attracted considerable interest in recent years. In this book the bulk and interfacial physico-chemical characteristics of various fluid systems dominated by Coulomb interactions are treated which includes molten salts, ionic liquids as well as metal-molten salt mixtures and expanded fluid metals. Of particular interest is the comparison of the different systems. Topics in the bulk phase concern the microscopic structure, the phase behaviour and critical phenomena, and the metal-nonmetal transition. Interfacial phenomena include wetting transitions, electrowetting, surface freezing, and the electrified ionic liquid/ electrode interface. With regard to the latter 2D and 3D electrochemical phase formation of metals and semi-conductors on the nanometer scale is described for a number of selected examples. The basic concepts and various experimental methods are introduced making the book suitable for both graduate students and researchers interested in Coulombic fluids.

  17. Pronounced ductility in CuZrAl ternary bulk metallic glass composites with optimized microstructure through melt adjustment

    Directory of Open Access Journals (Sweden)

    Zengqian Liu

    2012-09-01

    Full Text Available Microstructures and mechanical properties of as-cast Cu47.5Zr47.5Al5 bulk metallic glass composites are optimized by appropriate remelting treatment of master alloys. With increasing remelting time, the alloys exhibit homogenized size and distribution of in situ formed B2 CuZr crystals. Pronounced tensile ductility of ∼13.6% and work-hardening ability are obtained for the composite with optimized microstructure. The effect of remelting treatment is attributed to the suppressed heterogeneous nucleation and growth of the crystalline phase from undercooled liquid, which may originate from the dissolution of oxides and nitrides as well as from the micro-scale homogenization of the melt.

  18. Identification of New Lithic Clasts in Lunar Breccia 14305 by Micro-CT and Micro-XRF Analysis

    Science.gov (United States)

    Zeigler, Ryan A.; Carpenter, Paul K.; Jolliff, Bradley L.

    2014-01-01

    From 1969 to 1972, Apollo astronauts collected 382 kg of rocks, soils, and core samples from six locations on the surface of the Moon. The samples were initially characterized, largely by binocular examination, in a custom-built facility at Johnson Space Center (JSC), and the samples have been curated at JSC ever since. Despite over 40 years of study, demand for samples remains high (500 subsamples per year are allocated to scientists around the world), particularly for plutonic (e.g., anorthosites, norites, etc.) and evolved (e.g., granites, KREEP basalts) lithologies. The reason for the prolonged interest is that as new scientists and new techniques examine the samples, our understanding of how the Moon, Earth, and other inner Solar System bodies formed and evolved continues to grow. Scientists continually clamor for new samples to test their emerging hypotheses. Although all of the large Apollo samples that are igneous rocks have been classified, many Apollo samples are complex polymict breccias that have previously yielded large (cm-sized) igneous clasts. In this work we present the initial efforts to use the non-destructive techniques of micro-computed tomography (micro-CT) and micro x-ray fluorescence (micro-XRF) to identify large lithic clasts in Apollo 14 polymict breccia sample 14305. The sample in this study is 14305,483, a 150 g slab of regolith breccia 14305 measuring 10x6x2 cm (Figure 1a). The sample was scanned at the University of Texas High-Resolution X-ray CT Facility on an Xradia MicroXCT scanner. Two adjacent overlapping volumes were acquired at 49.2 micrometer resolution and stitched together, resulting in 1766 slices. Each volume was acquired at 100 kV accelerating voltage and 98 mA beam current with a 1 mm CaF2 filter, with 2161 views gathered over 360deg at 3 seconds acquisition time per view. Micro-XRF analyses were done at Washington University in St. Louis, Missouri on an EDAX Orbis PC micro-XRF instrument. Multiple scans were made at 40 k

  19. Pulse mode readout of MEMS bulk disk resonator based mass sensor

    DEFF Research Database (Denmark)

    Tang, Meng; Cagliani, Alberto; Davis, Zachary James

    2011-01-01

    We propose a pulse excitation setup applied on a Micro-Electro-Mechanical bulk disk resonator aimed for mass detection. This scheme offers measuring not only the resonant frequency, which defines the mass change, but also the quality factor and the feedthrough/parasitic capacitance of the disk wh...

  20. A high energy microscope for local strain measurements within bulk materials

    DEFF Research Database (Denmark)

    Lienert, U.; Poulsen, H.F.; Martins, R.V.; Kvick, Å.

    A novel diffraction technique for local, three dimensional strain scanning within bulk materials is presented. The technique utilizes high energy, micro-focussed synchrotron radiation which can penetrate several millimeters into typical metals. The spatial resolution can be as narrow as 1 mum in...

  1. Micro Machining Enhances Precision Fabrication

    Science.gov (United States)

    2007-01-01

    Advanced thermal systems developed for the Space Station Freedom project are now in use on the International Space Station. These thermal systems employ evaporative ammonia as their coolant, and though they employ the same series of chemical reactions as terrestrial refrigerators, the space-bound coolers are significantly smaller. Two Small Business Innovation Research (SBIR) contracts between Creare Inc. of Hanover, NH and Johnson Space Center developed an ammonia evaporator for thermal management systems aboard Freedom. The principal investigator for Creare Inc., formed Mikros Technologies Inc. to commercialize the work. Mikros Technologies then developed an advanced form of micro-electrical discharge machining (micro-EDM) to make tiny holes in the ammonia evaporator. Mikros Technologies has had great success applying this method to the fabrication of micro-nozzle array systems for industrial ink jet printing systems. The company is currently the world leader in fabrication of stainless steel micro-nozzles for this market, and in 2001 the company was awarded two SBIR research contracts from Goddard Space Flight Center to advance micro-fabrication and high-performance thermal management technologies.

  2. Micro club

    CERN Multimedia

    Micro Club

    2014-01-01

    Jeudi 18 septembre 2014 à 18h30 au Bât. 567 R-029 Le CERN MICRO CLUB organise un Atelier sur la sécurité informatique. La Cyber-sécurité : Ce qui se passe vraiment, comment ne pas en être victime ! Orateur : Sebastian Lopienski Adjoint au Computer Security Officer du Département IT. Sujet : Cet exposé vous présentera les modes de sécurité actuels et les problèmes touchants les applications logicielles des ordinateurs, les réseaux ainsi que leurs utilisateurs. Cela inclus des informations sur les nouveaux types de vulnérabilité, les vecteurs d'attaque récents et une vue d'ensemble sur le monde de la cyber-sécurité en 2014. Biographie : Sebastian Lopienski travaille au CERN depuis 2001. Il est actuellement adjoint au Computer Security Officer et s'occupe de la protection de...

  3. Micro club

    CERN Multimedia

    Micro club

    2014-01-01

    Opération NEMO   Pour finir en beauté les activités spéciales que le CMC a réalisé pendant cette année 2014, pour commémorer le 60ème anniversaire du CERN, et le 30ème du Micro Club, l’ Opération NEMO aura cette année un caractère très particulier. Nous allons proposer 6 fabricants de premier ordre qui offriront chacun deux ou trois produits à des prix exceptionnels. L’opération débute le lundi 17 novembre 2014. Elle se poursuivra  jusqu’au samedi 6 décembre inclus. Les délais de livraison seront de deux à trois semaines, selon les fabricants. Donc les commandes faites la dernière semaine, du 1 au 6 décembre, risquent d’arriver qu'au début du mois de janvier 2015. Liste de fabricants part...

  4. Microstructure and mechanical properties of ceramic coatings formed on 6063 aluminium alloy by micro-arc oxidation%6063铝合金微弧氧化陶瓷涂层的显微组织和力学性能

    Institute of Scientific and Technical Information of China (English)

    项南; 宋仁国; 赵坚; 李海; 王超; 王芝秀

    2015-01-01

    以硅酸盐、硼酸盐和铝酸盐为主要溶液,分别在这3种溶液中添加纳米添加剂Al2O3和TiO2以及不添加纳米添加剂,制备6063铝合金的微弧氧化陶瓷涂层。利用扫描电镜(SEM)、电子能谱分析(EDS)、X射线衍射、硬度和摩擦磨损测试研究这些涂层的显微组织和力学性能。SEM结果显示,含纳米添加剂涂层的孔洞比不含添加剂涂层的孔洞少。X射线衍射结果表明,在每种溶液中含添加剂的涂层比不含添加剂的涂层含有更多的氧化物成分,这与EDS的分析结果是一致的。力学性能测试结果表明,含纳米添加剂Al2O3的涂层较其他各种情况下在硅酸盐、硼酸盐和铝酸盐中制备出的涂层具有更高的硬度;纳米添加剂在这3种溶液中都能够提高微弧氧化涂层的耐磨性能。此外,无论是否含有纳米添加剂,硼酸盐微弧氧化涂层相对于硅酸盐和铝酸盐涂层都表现出较差的耐磨性能。%The microstructure and mechanical properties of ceramic coatings formed on 6063 aluminium alloy obtained in silicate-, borate-and aluminate-based electrolyte without and with nanoadditive Al2O3 and TiO2 by micro-arc oxidation (MAO) were studied by scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD), microhardness and friction−abrasion tests, respectively. SEM results show that coatings with nanoadditive have less porosities than those without nanoadditive. XRD results reveal that nanoadditive-containing coatings contain more oxides compared with nanoadditive-free coatings in all cases, which are consistent with the EDS analysis. Mechanical properties tests show that nanoadditive Al2O3-containing coatings have higher microhardness values compared with the other coatings obtained in silicate-, borate- and aluminate-based electrolyte. On the other hand, nanoadditive has a positive effect on improving the wearing-resistance of MAO coatings

  5. Thin layers elaborated from new anodic and cathodic materials for lithium-ions micro-batteries; Nouveaux materiaux d'electrodes elabores sous forme de couches minces pour batteries lithium-ion

    Energy Technology Data Exchange (ETDEWEB)

    Benjelloun, N.

    2002-12-01

    Thin layers elaborated by R.F. sputtering from new anodic and cathodic materials were investigated as electrodes for lithium-ion micro-batteries. Anodic thin films based on the Tin Composite Oxides (TCOs) were found to exhibit interesting electrochemical characteristics. However, the irreversible capacity loss occurring during the first charge and due to the reduction of tin oxide remains a drawback. According to the gold collector contribution to the faradic yield, electrochemical behavior of metallic thin films (Au, Ag, Cu, Zn, etc...) was studied. AuCuAg and Ag based thin films were associated via an aprotic or solid electrolyte (LiPON) to Li{sub 1+x}Mn{sub 1,5}Ni{sub 0,5}O{sub 4} thin layers in order to build up mini or micro batteries with an average voltage close to 4,7 V. However, all solid state micro-batteries were found to present high ohmic drop. (author)

  6. Fabrication of bulk metallic glasses by centrifugal casting method

    Directory of Open Access Journals (Sweden)

    R. Nowosielski

    2007-01-01

    Full Text Available Purpose: The aim of the present work is characterization of the centrifugal casting method, apparatus andproduced amorphous materials, which are also known as bulk metallic glassesDesign/methodology/approach: The studied centrifugal casting system consists of two main parts: castingapparatus and injection system of molten alloy. The described centrifugal casting method was presented bypreparing a casting apparatus “CentriCast – 5”. The apparatus includes a cylindrical copper mold, which isrotated by a motor. The transmission allows to changing the speed of rotating mold.Findings: Bulk metallic glasses are a novel class of engineering materials, which exhibit excelent mechanical,thermal, magnetic and corrosion properties. Centrifugal casting is a useful method to produce bulk amorphousmaterials in form of rings, tubes or cylindrical parts. Presented centrifugal casting method and casting apparatushas been prepared to fabricate the samples of bulk metallic glass in form of rings with an outer diameter of 25mm and controlled thicknesses by changing the weight of the molten alloy.Research limitations/implications: Studied centrifugal casting method and casting apparatus has beenprepared to fabricate the samples of bulk metallic glass. For future research a characterization of microstructureand properties of prepared material will be performed.Practical implications: The centrifugal casting is a useful process to produce bulk amorphous materials in formof rings, tubes or graded amorphous matrix composites. It seems to be a very simple method, which allows toobtain BMG materials.Originality/value: The centrifugal casting method allows to produce bulk amorphous rings with thicknessabove 1-mm.

  7. Bulk Moisture and Salinity Sensor

    Science.gov (United States)

    Nurge, Mark; Monje, Oscar; Prenger, Jessica; Catechis, John

    2013-01-01

    Measurement and feedback control of nutrient solutions in plant root zones is critical to the development of healthy plants in both terrestrial and reduced-gravity environments. In addition to the water content, the amount of fertilizer in the nutrient solution is important to plant health. This typically requires a separate set of sensors to accomplish. A combination bulk moisture and salinity sensor has been designed, built, and tested with different nutrient solutions in several substrates. The substrates include glass beads, a clay-like substrate, and a nutrient-enriched substrate with the presence of plant roots. By measuring two key parameters, the sensor is able to monitor both the volumetric water content and salinity of the nutrient solution in bulk media. Many commercially available moisture sensors are point sensors, making localized measurements over a small volume at the point of insertion. Consequently, they are more prone to suffer from interferences with air bubbles, contact area of media, and root growth. This makes it difficult to get an accurate representation of true moisture content and distribution in the bulk media. Additionally, a network of point sensors is required, increasing the cabling, data acquisition, and calibration requirements. measure the dielectric properties of a material in the annular space of the vessel. Because the pore water in the media often has high salinity, a method to measure the media moisture content and salinity simultaneously was devised. Characterization of the frequency response for capacitance and conductance across the electrodes was completed for 2-mm glass bead media, 1- to 2-mm Turface (a clay like media), and 1- to 2-mm fertilized Turface with the presence of root mass. These measurements were then used to find empirical relationships among capacitance (C), the dissipation factor (D), the volumetric water content, and the pore water salinity.

  8. Nanomechanical characterization of clay micro flocs

    OpenAIRE

    Zhang, Guoping; Yin, Hang; Reed, Allen

    2014-01-01

    Clay flocs are abundant in natural soils (a particulate material) and water-borne sediments. As the basic microscale, loading-bearing fundamental units, their mechanical properties control the macroscopic response of bulk soils and sediment transport. Owing to their tiny size and extremely soft consistency (especially for suspended water-borne flocs), significant difficulties and challenges exist for mechanical characterization of clay micro flocs. A novel nanomechanical characterization tech...

  9. Gold based bulk metallic glass

    OpenAIRE

    Schroers, Jan; Lohwongwatana, Boonrat; Johnson, William L.; Peker, Atakan

    2005-01-01

    Gold-based bulk metallic glass alloys based on Au-Cu-Si are introduced. The alloys exhibit a gold content comparable to 18-karat gold. They show very low liquidus temperature, large supercooled liquid region, and good processibility. The maximum casting thickness exceeds 5 mm in the best glassformer. Au49Ag5.5Pd2.3Cu26.9Si16.3 has a liquidus temperature of 644 K, a glass transition temperature of 401 K, and a supercooled liquid region of 58 K. The Vickers hardness of the alloys in this system...

  10. Collaborative form(s)

    DEFF Research Database (Denmark)

    Gunn, Wendy

    Gunn asks us to consider beauty as collaborative forms of action generated by moving between design by means of anthropology and anthropology by means of design. Specifically, she gives focus to play-like reflexions on practices of designing energy products, systems and infrastructure. Design...... anthropology engages groups of people within collaborative, interdisciplinary, inter-organizational design processes and co-analytic activities vs. the individual anthropologist conducting studies of people. In doing anthropology by means of design as Gatt and Ingold (2013) have shown, design is considered the...... premise designing as a social process and can be understood as a material engagement and constructive critique involving participant observation....

  11. A regression-based approach to tolerance values forecasting in micro/meso-scale for micro non-monolithic components

    Science.gov (United States)

    Liu, Xiaoyu; Wei, Xingping; Li, Jun; Zhao, Shiping

    2013-10-01

    Compared to the function-oriented tolerancing rules for micro monolithic components, the lack of specific tolerancing rules for micro non-monolithic ones results in difficulties in bulk production and quality assurance. In order to regulate micro non-monolithic components in micro/meso-scale, a mathematical model of power function is adopted to forecast the tolerance values of nominal sizes in 10~10,000 microns by the linearized regression analysis. The goodness-of-fit qualifies the regression with the power function model and the forecasting results are reasonable in the view of relative accuracy. It is hoped that the improved numerical value table of tolerance can provide some beneficial proposals for the establishment of new tolerancing rules for micro non-monolithic components in micro/meso-scale.

  12. Femtosecond micromachining in transparent bulk materials using an anamorphic lens.

    Science.gov (United States)

    Desautels, G Logan; Brewer, Chris D; Walker, Mark A; Juhl, Shane B; Finet, Marc A; Powers, Peter E

    2007-10-01

    A unique anamorphic lens design was applied to a circular 780nm femtosecond laser pulse to transform it into an elliptically shaped beam at focus. This lens was developed to give an alternative method of micromachining bulk transparent materials. The challenge for femtosecond laser processing is to control the nonlinear affect of self-focusing, which can occur when using a fast f-number lens. Once the focused spot is dominated by self-focusing the predicted focused beam becomes a filament inside the bulk, which is an undesirable effect. The anamorphic lens resolves this self-focusing by increasing the numerical aperture (NA) and employing an elliptical beam shape. The anamorphic lens was designed to furnish a 2.5mum by 190mum line at focus. Provided the pulse energy is high enough, transparent bulk material will be damaged with a single femtosecond laser pulse. Damage in this text refers to visual change in the index of refraction as observed under an optical microscope. Using this elliptical shape (or line), grating structures were micro-machined on the surface of SiC bulk transparent substrate. SiC was chosen because it is known for its micromachining difficulty and its crystalline structure. From the lack of self-focusing and using energy that is just above the damage threshold the focused line beam generated from the anamorphic lens grating structures produced a line shape nearly identical to the geometrical approximation. In this paper we discuss a new method of writing gratings (or other types of structures) in bulk transparent materials using a single femtosecond laser pulse. We will investigate the grating structures visually (inspected under an optical microscope) and also by use of an atomic force microscopy (AFM). In addition, we test the grating diffraction efficiency (DE) as a function of grating spacing, d. PMID:19550582

  13. Assessment of bioburden encapsulated in bulk materials

    Science.gov (United States)

    Schubert, Wayne W.; Newlin, Laura; Chung, Shirley Y.; Ellyin, Raymond

    2016-05-01

    The National Aeronautics and Space Administration (NASA) imposes bioburden limitations on all spacecraft destined for solar system bodies that might harbor evidence of extant or extinct life. The subset of microorganisms trapped within solid materials during manufacture and assembly is referred to as encapsulated bioburden. In the absence of spacecraft-specific data, NASA relies on specification values to estimate total spacecraft encapsulated bioburden, typically 30 endospores/cm3 or 300 viable cells/cm3 in non-electronic materials. Specification values for endospores have been established conservatively, and represent no less than an order of magnitude greater abundance than that derived from empirical assessments of actual spacecraft materials. The goal of this study was to generate data germane to determining whether revised bulk encapsulated material values (lower than those estimated by historical specifications) tailored specifically to the materials designated in modern-day spacecraft design could be used, on a case-by-case basis, to comply with planetary protection requirements. Organic materials having distinctly different chemical properties and configurations were selected. This required more than one experimental and analytical approach. Filtration was employed for liquid electrolytes, lubricants were suspended in an aqueous solution and solids (wire and epoxy sealant) were cryogenically milled. The final data characteristic for all bioburden estimates was microbial colony formation in rich agar growth medium. To assess survival potential, three non-spore-forming bacterial cell lines were systematically encapsulated in an epoxy matrix, liberated via cryogenic grinding, and cultured. Results suggest that bulk solid materials harbor significantly fewer encapsulated microorganisms than are estimated by specification values. Lithium-ion battery electrolyte reagents housed fewer than 1 CFU/cm3. Results also demonstrated that non-spore-forming microorganisms

  14. Bulk micromachining of Si by metal-assisted chemical etching.

    Science.gov (United States)

    Kim, Sang-Mi; Khang, Dahl-Young

    2014-09-24

    Bulk micromachining of Si is demonstrated by the well-known metal-assisted chemical etching (MaCE). Si microstructures, having lateral dimension from 5 μm up to millimeters, are successfully sculpted deeply into Si substrate, as deep as >100 μm. The key ingredient of this success is found to be the optimizations of catalyst metal type and its morphology. Combining the respective advantages of Ag and Au in the MaCE as a Ag/Au bilayer configuration leads to quite stable etch reaction upon a prolonged etch duration up to >5 h. Further, the permeable nature of the optimized Ag/Au bilayer metal catalyst enables the etching of pattern features having very large lateral dimension. Problems such as the generation of micro/nanostructures and chemical attacks on the top of pattern surface are successfully overcome by process optimizations such as post-partum sonication treatment and etchant formulation control. The method can also be successful to vertical micromachining of Si substrate having other crystal orientations than Si(100), such as Si(110) and Si(111). The simple, easy, and low-cost nature of present approach may be a great help in bulk micromachining of Si for various applications such as microelectromechanical system (MEMS), micro total analysis system (μTAS), and so forth. PMID:24820931

  15. X-Ray Micro-Computed Tomography Imaging of the Buzzard Coulee Chondrite

    Science.gov (United States)

    Melanson, D.; Samson, C.; Herd, R. K.; Fry, C.; McCausland, P. J. A.; Umoh, J.; Holdsworth, D. W.

    2012-03-01

    This abstract outlines research and some results of X-ray micro-computed tomography imaging of the Buzzard Coulee H4 chondrite. A comparison of bulk density results and an analysis of radio-density profile curves are discussed.

  16. Bulk dynamics for interfacial growth models

    OpenAIRE

    López, Cristóbal; Santos, Fernando; Garrido, P. L.

    2000-01-01

    We study the influence of the bulk dynamics of a growing cluster of particles on the properties of its interface. First, we define a general bulk growth model by means of a continuum Master equation for the evolution of the bulk density field. This general model just considers an arbitrary addition of particles (though it can be easily generalized to consider subtraction) with no other physical restriction. The corresponding Langevin equation for this bulk density field is derived where the i...

  17. MicroPRIS user's guide

    International Nuclear Information System (INIS)

    MicroPRIS is a new service of the IAEA Power Reactor Information System (PRIS) for the Member States of IAEA. MicroPRIS makes the IAEA database on nuclear power plants and their operating experience available to Member States on computer diskettes in a form readily accessible by standard commercially available personal computer packages. The aim of this publication is to provide the users of the PC version of PRIS data with description of the subset of the full PRIS database contained in MicroPRIS (release 1990), description of files and file structures, field descriptions and definitions, extraction and selection guide and with the method of calculation of a number of important performance indicators used by the IAEA

  18. Silicon bulk micromachined hybrid dimensional artifact.

    Energy Technology Data Exchange (ETDEWEB)

    Claudet, Andre A.; Tran, Hy D.; Bauer, Todd Marks; Shilling, Katherine Meghan; Oliver, Andrew David

    2010-03-01

    A mesoscale dimensional artifact based on silicon bulk micromachining fabrication has been developed and manufactured with the intention of evaluating the artifact both on a high precision coordinate measuring machine (CMM) and video-probe based measuring systems. This hybrid artifact has features that can be located by both a touch probe and a video probe system with a k=2 uncertainty of 0.4 {micro}m, more than twice as good as a glass reference artifact. We also present evidence that this uncertainty could be lowered to as little as 50 nm (k=2). While video-probe based systems are commonly used to inspect mesoscale mechanical components, a video-probe system's certified accuracy is generally much worse than its repeatability. To solve this problem, an artifact has been developed which can be calibrated using a commercially available high-accuracy tactile system and then be used to calibrate typical production vision-based measurement systems. This allows for error mapping to a higher degree of accuracy than is possible with a glass reference artifact. Details of the designed features and manufacturing process of the hybrid dimensional artifact are given and a comparison of the designed features to the measured features of the manufactured artifact is presented and discussed. Measurement results from vision and touch probe systems are compared and evaluated to determine the capability of the manufactured artifact to serve as a calibration tool for video-probe systems. An uncertainty analysis for calibration of the artifact using a CMM is presented.

  19. Design of $Cu_{8}Zr_{5}$-based bulk metallic glasses

    OpenAIRE

    Yang, L.; Xia, J H; Wang, Q; Dong, C; Chen, L. Y.; Ou, X; Liu, J. F.; Jiang, J. Z.; Klementiev, K.; Saksl, K.; Franz, H.; Schneider, J. R.; L. Gerward

    2006-01-01

    Basic polyhedral clusters have been derived from intermetallic compounds at near-eutectic composition by considering a dense packing and random arrangement of atoms at shell sites. Using such building units, bulk metallic glasses can be formed. This strategy was verified in the Cu-Zr binary system, where we have demonstrated the existence of Cu8Zr5 icosahedral clusters in Cu61.8Zr38.2, Cu64Zr36, and Cu64.5Zr35.5 amorphous alloys. Furthermore, ternary bulk metallic glasses can be developed by ...

  20. Experimental and numerical study of micro deep drawing

    Directory of Open Access Journals (Sweden)

    Luo Liang

    2015-01-01

    Full Text Available Micro forming is a key technology for an industrial miniaturisation trend, and micro deep drawing (MDD is a typical micro forming method. It has great advantages comparing to other micro manufacturing methods, such as net forming ability, mass production potential, high product quality and complex 3D metal products fabrication capacity. Meanwhile, it is facing difficulties, for example the so-called size effects, once scaled down to micro scale. To investigate and to solve the problems in MDD, a combined micro blanking-drawing machine is employed and an explicit-implicit micro deep drawing model with a voronoi blank model is developed. Through heat treatment different grain sizes can be obtained, which affect material's properties and, consequently, the drawing process parameters, as well as produced cups' quality. Further, a voronoi model can provide detailed material information in simulation, and numerical simulation results are in accordance with experimental results.

  1. QCD phase transition with a power law chameleon scalar field in the bulk

    OpenAIRE

    Golanbari, T.; Mohammadi, A.; Saaidi, Kh.

    2014-01-01

    In this work, a brane world model with a perfect fluid on brane and a scalar field on bulk has been used to study quark-hadron phase transition. The bulk scalar field has an interaction with brane matter. This interaction comes into non-conservation relation which describe an energy transfer between bulk and brane. Since quark-hadron transition curly depends on the form of evolution equations therefore modification of energy conservation equation and Friedmann equation comes into some interes...

  2. Handling of bulk solids theory and practice

    CERN Document Server

    Shamlou, P A

    1990-01-01

    Handling of Bulk Solids provides a comprehensive discussion of the field of solids flow and handling in the process industries. Presentation of the subject follows classical lines of separate discussions for each topic, so each chapter is self-contained and can be read on its own. Topics discussed include bulk solids flow and handling properties; pressure profiles in bulk solids storage vessels; the design of storage silos for reliable discharge of bulk materials; gravity flow of particulate materials from storage vessels; pneumatic transportation of bulk solids; and the hazards of solid-mater

  3. Gold based bulk metallic glass

    Science.gov (United States)

    Schroers, Jan; Lohwongwatana, Boonrat; Johnson, William L.; Peker, Atakan

    2005-08-01

    Gold-based bulk metallic glass alloys based on Au-Cu-Si are introduced. The alloys exhibit a gold content comparable to 18-karat gold. They show very low liquidus temperature, large supercooled liquid region, and good processibility. The maximum casting thickness exceeds 5mm in the best glassformer. Au49Ag5.5Pd2.3Cu26.9Si16.3 has a liquidus temperature of 644K, a glass transition temperature of 401K, and a supercooled liquid region of 58K. The Vickers hardness of the alloys in this system is ˜350Hv, twice that of conventional 18-karat crystalline gold alloys. This combination of properties makes the alloys attractive for many applications including electronic, medical, dental, surface coating, and jewelry.

  4. Gold based bulk metallic glass

    International Nuclear Information System (INIS)

    Gold-based bulk metallic glass alloys based on Au-Cu-Si are introduced. The alloys exhibit a gold content comparable to 18-karat gold. They show very low liquidus temperature, large supercooled liquid region, and good processibility. The maximum casting thickness exceeds 5 mm in the best glassformer. Au49Ag5.5Pd2.3Cu26.9Si16.3 has a liquidus temperature of 644 K, a glass transition temperature of 401 K, and a supercooled liquid region of 58 K. The Vickers hardness of the alloys in this system is ∼350 Hv, twice that of conventional 18-karat crystalline gold alloys. This combination of properties makes the alloys attractive for many applications including electronic, medical, dental, surface coating, and jewelry

  5. Bulk analysis using nuclear techniques

    International Nuclear Information System (INIS)

    Bulk analysis techniques developed for the mining industry are reviewed. Using penetrating neutron and #betta#-radiations, measurements are obtained directly from a large volume of sample (3-30 kg) #betta#-techniques were used to determine the grade of iron ore and to detect shale on conveyor belts. Thermal neutron irradiation was developed for the simultaneous determination of iron and aluminium in iron ore on a conveyor belt. Thermal-neutron activation analysis includes the determination of alumina in bauxite, and manganese and alumina in manganese ore. Fast neutron activation analysis is used to determine silicon in iron ores, and alumina and silica in bauxite. Fast and thermal neutron activation has been used to determine the soil in shredded sugar cane. (U.K.)

  6. Isotopic signatures by bulk analyses

    International Nuclear Information System (INIS)

    Los Alamos National Laboratory has developed a series of measurement techniques for identification of nuclear signatures by analyzing bulk samples. Two specific applications for isotopic fingerprinting to identify the origin of anthropogenic radioactivity in bulk samples are presented. The first example is the analyses of environmental samples collected in the US Arctic to determine the impact of dumping of radionuclides in this polar region. Analyses of sediment and biota samples indicate that for the areas sampled the anthropogenic radionuclide content of sediments was predominantly the result of the deposition of global fallout. The anthropogenic radionuclide concentrations in fish, birds and mammals were very low. It can be surmised that marine food chains are presently not significantly affected. The second example is isotopic fingerprinting of water and sediment samples from the Rocky Flats Facility (RFP). The largest source of anthropogenic radioactivity presently affecting surface-waters at RFP is the sediments that are currently residing in the holding ponds. One gram of sediment from a holding pond contains approximately 50 times more plutonium than 1 liter of water from the pond. Essentially 100% of the uranium in Ponds A-1 and A-2 originated as depleted uranium. The largest source of radioactivity in the terminal Ponds A-4, B-5 and C-2 was naturally occurring uranium and its decay product radium. The uranium concentrations in the waters collected from the terminal ponds contained 0.05% or less of the interim standard calculated derived concentration guide for uranium in waters available to the public. All of the radioactivity observed in soil, sediment and water samples collected at RFP was naturally occurring, the result of processes at RFP or the result of global fallout. No extraneous anthropogenic alpha, beta or gamma activities were detected. The plutonium concentrations in Pond C-2 appear to vary seasonally

  7. Guidelines for Measuring Bulk Density of Soil

    International Nuclear Information System (INIS)

    Bulk density is defined as the dry weight of soil per unit volume of undisturbed soil. • Bulk density can be used to give an indication of the porosity and structure of the soil influencing O2 and H2O movement in the soil. • Soils with a bulk density higher than 1.6 g/cm3 may restrict root development. • Bulk density is also a measurement of the degree of compaction of the soil. • Bulk density increases with compaction and tends to increase with soil depth. • Sandy soils tend to have higher bulk density (1.4-1.5 g/cm3) than clay soils (1.2-1/3g/cm3). The measurement of soil bulk density is carried out by collecting undisturbed soil samples through inserting metal rings (with a known volume) into the soil, and determining the weight of the collected soil after drying

  8. Fabrication of micro metallic valve and pump

    Science.gov (United States)

    Yang, Ming; Kabasawa, Yasunari; Ito, Kuniyoshi

    2010-03-01

    Fabrication of micro devices by using micro metal forming was proposed by the authors. We developed a desktop servo-press machine with precise tooling system. Precise press forming processes including micro forging and micro joining has been carried out in a progressive die. In this study, micro metallic valve and pump were fabricated by using the precise press forming. The components are made of sheet metals, and assembled in to a unit in the progressive die. A micro check-valve with a diameter of 3mm and a length of 3.2mm was fabricated, and the property of flow resistance was evaluated. The results show that the check valve has high property of leakage proof. Since the valve is a unit parts with dimensions of several millimeters, it has advantage to be adapted to various pump design. Here, two kinds of micro pumps with the check-valves were fabricated. One is diaphragm pump actuated by vibration of the diaphragm, and another is tube-shaped pump actuated by resonation. The flow quantities of the pumps were evaluated and the results show that both of the pumps have high pumping performance.

  9. Development of Integrated Electronics for Readout of High Frequency Micro/Nano-mechanical Resonator

    DEFF Research Database (Denmark)

    Tang, Meng

    Micro størrelse bulk type resonatorer er blevet udviklet gennern de sidste fem år til anvendelse inden for elektronikbranchen til lav strøm og billige alternativer til både passive og aktive komponenter. Dog kan denne type bulk resonator også bruges til bio/kemiske sensorer hvor, da på grund af d...

  10. Micro-Scale Regenerative Heat Exchanger

    Science.gov (United States)

    Moran, Matthew E.; Stelter, Stephan; Stelter, Manfred

    2004-01-01

    A micro-scale regenerative heat exchanger has been designed, optimized and fabricated for use in a micro-Stirling device. Novel design and fabrication techniques enabled the minimization of axial heat conduction losses and pressure drop, while maximizing thermal regenerative performance. The fabricated prototype is comprised of ten separate assembled layers of alternating metal-dielectric composite. Each layer is offset to minimize conduction losses and maximize heat transfer by boundary layer disruption. A grating pattern of 100 micron square non-contiguous flow passages were formed with a nominal 20 micron wall thickness, and an overall assembled ten-layer thickness of 900 microns. Application of the micro heat exchanger is envisioned in the areas of micro-refrigerators/coolers, micropower devices, and micro-fluidic devices.

  11. Characterization of small particles by micro X-ray fluorescence

    International Nuclear Information System (INIS)

    Micro X-ray fluorescence was used to study both homogeneous and heterogeneous particle systems. Specifically, homogeneous glass microspheres and heterogeneous soil particle samples were prepared by both bulk and single particle sample preparation methods for evaluation by micro X-ray fluorescence. Single particle sample preparation methods allow for single particles from a collected sample to be isolated and individually presented to the micro X-ray fluorescence instrument for analysis. Various particle dispersion methods, including immobilization onto Tacky DotTM slides, mounting onto double-sided sticky tape affixed to polypropylene film, or attachment to polypropylene film using 3M Artist's Adhesive, were used to separate the sample particles for single particle analysis. These methods were then compared and evaluated for their ability to disperse the particles into an array of single separated particles for optimal micro X-ray fluorescence characterization with minimal background contribution from the particle mounting surface. Bulk methods of particle sample preparation, which included pellet preparation and aerosol impaction, used a large quantity of collected single particles to make a single homogeneous specimen for presentation to the instrument for analysis. It was found that single particle elemental analysis by micro X-ray fluorescence can be performed if the particles are well separated (minimum separation distance = excitation source beam diameter) down to a particle mass of ∼ 0.04 ng and a mean particle diameter of ∼ 0.06 μm. Homogeneous particulates can be adequately characterized by micro X-ray fluorescence using either bulk or single particle analysis methods, with no loss of analytical information. Heterogeneous samples are much harder to characterize, and both single particle as well as bulk analyses must be performed on the sample to insure full elemental characterization by micro X-ray fluorescence

  12. Electrospinning of micro spiral fibers

    International Nuclear Information System (INIS)

    We describe an easy way to form micro spiral structures resulting from buckling instabilities of an electro jet of a nanoscale polymer fiber of polyvinglpyrrolidone-Cu(NO3)2 (PVP-Cu(NO3)2) sol) and discuss the formation process. We control the morphologies of the fibers into spiral fibers, and free-standing hollow cylinders by connecting an opposite high voltage supply (−5 to −10 kV) on the collector. The microstructured surfaces were observed by scanning electron microscope (SEM). SEM analysis revealed the presence of spirals with diameters of approximately 20 to 30 μm. The structures formed by the nanofibers could be used in diverse fields of nanotechnology, such as micro planar inductor and nanochannels. (papers)

  13. Bulk and track etching of PET studied by spectrophotometer

    International Nuclear Information System (INIS)

    UV-VIS spectra of poly(ethylene terephthalate) (PET) solutions formed by etching PET in NaOH solution were analyzed with respect to the etching time. A linear relationship between absorptions centered at 4.45 and 5.11 eV with weight loss of PET in NaOH solution was established. The relation was applied to study the influence of UV light illumination on bulk etching of PET and to evaluate pore size of etched-through tracks. It is found that bulk etching of PET can be greatly enhanced by UV illumination in air in the wavelength range around 313 nm. A surface area of about 350 nm in thickness shows a 23 times increase in bulk-etching rate after illuminated for 6 h. The phenomenon is attributed to the oxygen-assisted photo-degradation through generating of new photo-unstable species. The enhancement in bulk etching was immediately reduced as the etching proceeds below the surface with an exponential decay constant of about 1.5 μm-1. Etching of Xe ion irradiated PET films gives extra etching products with similar chemical structure as revealed by spectrophotometer measurements. Quantitative analysis of etching products from latent tracks implies that pores of about 14.6 nm in radius are formed after etching in 0.74 N NaOH at 40 deg. C for 35 min, which is in agreement with the conductometric measurement

  14. Study on the micro-replication of shark skin

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    Direct replication of creatural scarfskins to form biomimetic surfaces with relatively vivid morphology is a new attempt of the bio-replicated forming technology at animal body. Taking shark skins as the replication templates, and the micro-embossing and micro-molding as the material forming methods, the micro-replicating technology of the outward morphology on shark skins was demonstrated. The preliminary analysis on replication precision indicates that the bio-replicated forming technology can replicate the outward morphology of the shark scales with good precision, which validates the application of the bio-replicated forming technology in the direct morphology replication of the firm creatural scarfskins.

  15. A study on the analysis method of shape quality and the micro burr removal on a micro pyramid pattern using the micro MR fluid jet polishing system

    Science.gov (United States)

    Lee, J. W.; Ha, S. J.; Hong, K. P.; Cho, Y. K.; Kim, K. B.; Kim, B. C.; Cho, M. W.

    2016-04-01

    Recently, micro square pyramid patterns which can be obtained by a light diffusion effect have been widely studied and examined. However, micro pyramid patterns are difficult to fabricate, because of a deburring problem. Therefore, a micro machining technology for the fabrication of micro pyramid patterns has emerged as an essential element. Burr can almost be generated on the edge of the micro pattern when the micro square pyramid pattern is manufactured by a mechanical cutting process. The micro pyramid pattern shape is difficult to maintain as an original form when the burrs are removed. So various methods have been used in an attempt to remove the burrs. A micro magnetorheological (MR) fluid jet polishing process is one of various methods to remove burrs. The process can control shear force for material removing it by a controlled viscosity of the MR fluid due to magnetic-field adjusting. In this paper, magnetic analysis and the deburring process were carried out to fabricate a micro square pyramid pattern on brass (non-magnetic material) and nickel (ferromagnetic material) using a micro MR fluid jet polishing system. Finally, the deburring characteristics and the shape analysis of micro pyramid patterns were investigated by using a micro MR fluid jet polishing system.

  16. Low-cost formation of bulk and localized polymer-derived carbon nanodomains from polydimethylsiloxane.

    Science.gov (United States)

    Alcántara, Juan Carlos Castro; Cerda Zorrilla, Mariana; Cabriales, Lucia; Rossano, Luis Manuel León; Hautefeuille, Mathieu

    2015-01-01

    We present two simple alternative methods to form polymer-derived carbon nanodomains in a controlled fashion and at low cost, using custom-made chemical vapour deposition and selective laser ablation with a commercial CD-DVD platform. Both processes presented shiny and dark residual materials after the polymer combustion and according to micro-Raman spectroscopy of the domains, graphitic nanocrystals and carbon nanotubes have successfully been produced by the combustion of polydimethylsiloxane layers. The fabrication processes and characterization of the byproduct materials are reported. We demonstrate that CVD led to bulk production of graphitic nanocrystals and single-walled carbon nanotubes while direct laser ablation may be employed for the formation of localized fluorescent nanodots. In the latter case, graphitic nanodomains and multi-wall carbon nanotubes are left inside microchannels and preliminary results seem to indicate that laser ablation could offer a tuning control of the nature and optical properties of the nanodomains that are left inside micropatterns with on-demand geometries. These low-cost methods look particularly promising for the formation of carbon nanoresidues with controlled properties and in applications where high integration is desired. PMID:25977844

  17. Low-cost formation of bulk and localized polymer-derived carbon nanodomains from polydimethylsiloxane

    Directory of Open Access Journals (Sweden)

    Juan Carlos Castro Alcántara

    2015-03-01

    Full Text Available We present two simple alternative methods to form polymer-derived carbon nanodomains in a controlled fashion and at low cost, using custom-made chemical vapour deposition and selective laser ablation with a commercial CD-DVD platform. Both processes presented shiny and dark residual materials after the polymer combustion and according to micro-Raman spectroscopy of the domains, graphitic nanocrystals and carbon nanotubes have successfully been produced by the combustion of polydimethylsiloxane layers. The fabrication processes and characterization of the byproduct materials are reported. We demonstrate that CVD led to bulk production of graphitic nanocrystals and single-walled carbon nanotubes while direct laser ablation may be employed for the formation of localized fluorescent nanodots. In the latter case, graphitic nanodomains and multi-wall carbon nanotubes are left inside microchannels and preliminary results seem to indicate that laser ablation could offer a tuning control of the nature and optical properties of the nanodomains that are left inside micropatterns with on-demand geometries. These low-cost methods look particularly promising for the formation of carbon nanoresidues with controlled properties and in applications where high integration is desired.

  18. Bulk Nanostructured Materials Obtained by Shock Waves Compaction of Ultrafine Titanium and Aluminum

    Science.gov (United States)

    Chikhradze, Nikoloz M.; Politis, Constantin; Chikhradze, Mikheil; Oniashvili, George

    Theoretical and experimental Investigations of shock wave consolidation processes of Ti-Al nano sized and ultra-disperse powder compositions are discussed. For theoretical calculations of the shock wave loaded materials were used the hydrodynamic theory and experimental adiabatic of Ti and Al. The normal and tangential stresses in the cylindrical steel tube (containers of Ti-Al reaction mixtures) were estimated using the partial solutions of elasticity theory. The mixtures of ultra-disperse Ti and nano sized (≤ 50nm) Al powder compositions were consolidated to full or near-full density by explosive-compaction technology. The ammonium nitride based industrial explosives were used for generation of shock waves. To form ultra-fine grained bulk TiAl intermetallics with different compositions, ultra-disperse Ti particles were mixed with nano-crystalline Al. Each reaction mixture was placed in a sealed container and explosively compacted using a normal and cylindrical detonation set-up. Explosive compaction experiments were performed in range of pressure impulse (5-20) GPa. X-ray diffraction (XRD), structural investigations (SEM) and micro-hardness measurements were used to characterize the intermetallics phase composition and mechanical properties. The results of analysis revealing the effects of the compacting conditions and precursor particles sizes, affecting the consolidation and the properties of this new ultra high performance alloys are discussed.

  19. [Fate and balance of bulk blending controlled release fertilizer nitrogen under continuous cropping of mustard].

    Science.gov (United States)

    Zhang, Pan-Pan; Fan, Xiao-Lin

    2012-10-01

    Under the conditions of applying water soluble fertilizer and its bulk blending with controlled release fertilizer (BB-CRF), and by using micro-lysimeter, this paper quantitatively studied the nitrogen (N) uptake by mustard, the soil N losses from N2O emission, leaching and others, and the N residual in soil in three rotations of continuously cropped mustard. In the treatment of BB-CRF with 25% of controlled release nitrogen, the N uptake by mustard increased with rotations, and the yield by the end of the experiment was significantly higher than that in the treatment of water soluble fertilizer. The cumulated N2O emission loss and the N leaching loss were obviously higher in treatment water soluble fertilizer than in treatment BB-CRF. NO3(-)-N was the primary form of N in the leachate. In relative to water soluble fertilizer, BB-CRF altered the fates of fertilizer nitrogen, i.e., the N uptake by mustard and the N residual in soil increased by 75.4% and 76.0%, and the N leaching loss and other apparent N losses decreased by 27.1% and 66.3%, respectively. The application of BB-CRF could be an effective way to reduce the various losses of fertilizer N while increase the fertilizer N use efficiency, and the controlled release fertilizer is the environmentally friendly fertilizer with the property of high N use efficiency. PMID:23359937

  20. Effect of precipitation, geographical location and biosynthesis on New Zealand milk powder bulk and fatty acids D/H ratios

    Science.gov (United States)

    Frew, R.; Emad Ehtesham, R.; Van Hale, R.; Hayman, A.; Baisden, T.

    2012-04-01

    D/H ratio measurements provide useful information for the investigation of biogeochemical influences on natural and agricultural produce, particularly with application to food traceability and authentication. Numerous studies have shown that variation of a product's D/H ratio is influenced by both environmental factors and biological processes. This study investigates the D/H ratio of New Zealand milk powder and individual fatty acids, and causal determinants of isotopic variation. One of the key environmental factors is precipitation, and the D/H ratio "isoscaping" of NZ has been undertaken. New Zealand provides a unique geography for these kinds of study in terms of proximity to the ocean and natural geographical variability from sea level to elevations as high as 3700 m. Milk powder samples were collected from different geographical regions from milk processing units, which were supplied by producers in the immediate region. H/D ratios of bulk milk powder and of individual fatty acids were determined. Initial comparison of the precipitation and milk powder bulk D/H data show a very good differentiation from north to southernmost parts of New Zealand and a relation between rain and milk bulk D/H abundance ratio. Almost 98% of milk FAs are in the form of triglycerides that have been extracted and hydrolysed to free FAs. Free FAs were esterified and analyzed with GC-IRMS. Individual FAs show variation in D/H ratio, and all values are depleted relative to the precipitation data. The difference in D/H ratio amongst individual FAs reflects the geographical environment and biological processes i.e. micro-organisms activity in the rumen of the cow. Short chain FAs (less than 8 carbons), particularly C4 (Butyric acid), appear to be key determinants. The variation in the data can be rationalized using statistical multivariate analysis.

  1. Relative entropy equals bulk relative entropy

    CERN Document Server

    Jafferis, Daniel L; Maldacena, Juan; Suh, S Josephine

    2015-01-01

    We consider the gravity dual of the modular Hamiltonian associated to a general subregion of a boundary theory. We use it to argue that the relative entropy of nearby states is given by the relative entropy in the bulk, to leading order in the bulk gravitational coupling. We also argue that the boundary modular flow is dual to the bulk modular flow in the entanglement wedge, with implications for entanglement wedge reconstruction.

  2. Coupling brane fields to bulk supergravity

    International Nuclear Information System (INIS)

    In this note we present a simple, general prescription for coupling brane localized fields to bulk supergravity. We illustrate the procedure by considering 6D N=2 bulk supergravity on a 2D orbifold, with brane fields localized at the fixed points. The resulting action enjoys the full 6D N=2 symmetries in the bulk, and those of 4D N=1 supergravity at the brane positions. (orig.)

  3. Coupling brane fields to bulk supergravity

    Energy Technology Data Exchange (ETDEWEB)

    Parameswaran, Susha L. [Uppsala Univ. (Sweden). Theoretical Physics; Schmidt, Jonas [Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany)

    2010-12-15

    In this note we present a simple, general prescription for coupling brane localized fields to bulk supergravity. We illustrate the procedure by considering 6D N=2 bulk supergravity on a 2D orbifold, with brane fields localized at the fixed points. The resulting action enjoys the full 6D N=2 symmetries in the bulk, and those of 4D N=1 supergravity at the brane positions. (orig.)

  4. Micro Dot Patterning on the Light Guide Panel Using Powder Blasting

    OpenAIRE

    Dong Sam Park; Myeong Woo Cho; Ho Su Jang

    2008-01-01

    This study is to develop a micromachining technology for a light guide panel(LGP) mold, whereby micro dot patterns are formed on a LGP surface by a single injection process instead of existing screen printing processes. The micro powder blasting technique is applied to form micro dot patterns on the LGP mold surface. The optimal conditions for masking, laminating, exposure, and developing processes to form the micro dot patterns are first experimentally investigated. A LGP mold with masked mi...

  5. Review on progressive microforming of bulk metal parts directly using sheet metals (Keynote Paper

    Directory of Open Access Journals (Sweden)

    Fu M.W.

    2015-01-01

    Full Text Available Due to the ubiquitous trend of product miniaturization, energy saving and weight reduction, micro/meso-scale parts have been widely used in many industrial clusters. Micromanufacturing processes for production of such micro/meso-scale parts are thus critically needed. Microforming, as one of these micro manufacturing processes, is a promising process and thus got many explorations and researches. Compared with the research on size effect affected deformation behaviours, less attention has been paid to the process development for mass production of micro-parts. The product quality and fabrication productivity of micro-parts depend on the involved process chain. To address the difficulty in handling and transporting of the micro-sized workpiece, development of a progressive microforming process for directly fabricating bulk micro-parts using sheet metals seems quite promising as it avoids or facilitates billet handling, transportation, positioning, and ejection in the process chain. In this paper, an intensive review on the latest development of progressive microforming technologies is presented. First of all, the paper summarizes the characteristic of progressive microforming directly using sheet metal. The size effect-affected deformation behaviour and the dimensional accuracy, deformation load, ductile fracture, and the surface finish of the microformed parts by progressive microforming using sheet metals are then presented. Finally, some research issues from the implementation of mass production perspective are also discussed.

  6. Bulk scalar field in DGP braneworld cosmology

    CERN Document Server

    Ansari, Rizwan ul Haq

    2007-01-01

    We investigated the effects of bulk scalar field in the braneworld cosmological scenario. The Friedmann equations and acceleration condition in presence of the bulk scalar field for a zero tension brane and cosmological constant are studied. In DGP model the effective Einstein equation on the brane is obtained with bulk scalar field. The rescaled bulk scalar field on the brane in the DGP model behaves as an effective four dimensional field, thus standard type cosmology is recovered. In present study of the DGP model, the late-time accelerating phase of the universe can be explained .

  7. Effect of the presence of an ordered micro-pillar array on the formation of silica monoliths.

    Science.gov (United States)

    Detobel, Frederik; Eghbali, Hamed; De Bruyne, Selm; Terryn, Herman; Gardeniers, Han; Desmet, Gert

    2009-10-30

    We report on the synthesis of siloxane-based monoliths in the presence of a two-dimensional, perfectly ordered array of micro-pillars. Both methyltrimethoxysilane- and tetramethoxysilane-based monoliths were considered. The obtained structures were analyzed using scanning-electron microscopy and can be explained from the general theory of surface-directed phase separation in confined spaces. The formed structures are to a large extent nearly exclusively determined by the ratio between the bulk domain size of the monolith on the one hand and the distance between the micro-pillars on the other hand. When this ratio is small, the presence of the pillars has nearly no effect on the morphology of the produced monoliths. However, when the ratio approaches unity and ascends above it, some new types of monolith morphologies are induced, two of which appear to have interesting properties for use as novel chromatographic supports. One of these structures (obtained when the domain size/inter-pillar distance ratio is around unity) is a 3D network of linear interconnections between the pillars, organized such that all skeleton branches are oriented perpendicular to the micro-pillar surface. A second interesting structure is obtained at even higher values of the domain size/inter-pillar distance ratio. In this case, each individual micro-pillar is uniformly coated with a mesoporous shell. PMID:19321168

  8. Demonstration of a silicon photomultiplier with bulk integrated quenching resistors on epitaxial silicon

    International Nuclear Information System (INIS)

    In this paper we present the experimental results of a silicon photomultiplier (SiPM) with bulk integrated quenching resistors on epitaxial silicon. Compared with existing SiPM with polysilicon quenching resistors on the surface or with MRS structure, it has potential advantages of high photon detection efficiency (PDE) while retaining a large micro-cell density and the fabrication process is also simplified. The SiPM with the micro-cell density up to 104/mm2 and the PDE up to 25.6% is demonstrated. The characteristics of dark count rate, single photon detection capability, gain, optical crosstalk and PDE have been investigated and discussed.

  9. FORM development

    OpenAIRE

    Vermaseren, J. A. M.

    2011-01-01

    I give an overview of FORM development based on a few pilot projects, explaining how they have influenced the FORM capabilities. Next I explain what is happnening right now in the field of Open Sourcing and the FORM Forum.

  10. Phase transitions of bulk statistical copolymers studied by dynamic Monte Carlo simulations

    NARCIS (Netherlands)

    Hu, W.; Mathot, V.B.F.; Frenkel, D.

    2003-01-01

    We report a numerical study of crystallization and melting in bulk statistical homogeneous (random), homogeneous (slightly alternating), and heterogeneous (produced in a batch reaction) copolymers formed by crystallizable monomers and noncrystallizable comonomers. In our dynamic Monte Carlo simulati

  11. Accurate theoretical prediction on positron lifetime of bulk materials

    CERN Document Server

    Zhang, Wenshuai; Liu, Jiandang; Ye, Bangjiao

    2015-01-01

    Based on the first-principles calculations, we perform an initiatory statistical assessment on the reliability level of theoretical positron lifetime of bulk material. We found the original generalized gradient approximation (GGA) form of the enhancement factor and correlation potentials overestimates the effect of the gradient factor. Furthermore, an excellent agreement between model and data with the difference being the noise level of the data is found in this work. In addition, we suggest a new GGA form of the correlation scheme which gives the best performance. This work demonstrates that a brand-new reliability level is achieved for the theoretical prediction on positron lifetime of bulk material and the accuracy of the best theoretical scheme can be independent on the type of materials.

  12. Tilting the Primordial Power Spectrum with Bulk Viscosity

    OpenAIRE

    Lidsey, James E.

    1993-01-01

    Within the context of the cold dark matter model, current observations suggest that inflationary models which generate a tilted primordial power spectrum with negligible gravitational waves provide the most promising mechanism for explaining large scale clustering. The general form of the inflationary potential which produces such a spectrum is a hyperbolic function and is interpreted physically as a bulk viscous stress contribution to the energy-momentum of a perfect baryotropic fluid. This ...

  13. Surface and Bulk Nanostructuring of Polymers Using Ionizing Radiation

    International Nuclear Information System (INIS)

    Ionizing radiation has long been known tobe a powerful tool in modifying and controlled the properties, forms and eventually end-uses of polymeric materials for a variety of applications. Industrial applications are full of successful examples of macro scale, bulk property modifications by radiation. Extremely short wavelength of ionizing radiation however, makes it an important and useful tool in creating very small size structures in polymers

  14. Micro Machining of Injection Mold Inserts for Fluidic Channel of Polymeric Biochips

    Directory of Open Access Journals (Sweden)

    Myeong-Woo Cho

    2007-08-01

    Full Text Available Recently, the polymeric micro-fluidic biochip, often called LOC (lab-on-a-chip, has been focused as a cheap, rapid and simplified method to replace the existing biochemical laboratory works. It becomes possible to form miniaturized lab functionalities on a chip with the development of MEMS technologies. The micro-fluidic chips contain many micro-channels for the flow of sample and reagents, mixing, and detection tasks. Typical substrate materials for the chip are glass and polymers. Typical techniques for micro-fluidic chip fabrication are utilizing various micro pattern forming methods, such as wet-etching, micro-contact printing, and hot-embossing, micro injection molding, LIGA, and micro powder blasting processes, etc. In this study, to establish the basis of the micro pattern fabrication and mass production of polymeric micro-fluidic chips using injection molding process, micro machining method was applied to form micro-channels on the LOC molds. In the research, a series of machining experiments using micro end-mills were performed to determine optimum machining conditions to improve surface roughness and shape accuracy of designed simplified micro-channels. Obtained conditions were used to machine required mold inserts for micro-channels using micro end-mills. Test injection processes using machined molds and COC polymer were performed, and then the results were investigated.

  15. Comparative waste forms study

    International Nuclear Information System (INIS)

    A number of alternative process and waste form options exist for the immobilization of nuclear wastes. Although data exists on the characterization of these alternative waste forms, a straightforward comparison of product properties is difficult, due to the lack of standardized testing procedures. The characterization study described in this report involved the application of the same volatility, mechanical strength and leach tests to ten alternative waste forms, to assess product durability. Bulk property, phase analysis and microstructural examination of the simulated products, whose waste loading varied from 5% to 100% was also conducted. The specific waste forms investigated were as follows: Cold Pressed and Sintered PW-9 Calcine; Hot Pressed PW-9 Calcine; Hot Isostatic Pressed PW-9 Calcine; Cold Pressed and Sintered SPC-5B Supercalcine; Hot Isostatic pressed SPC-5B Supercalcine; Sintered PW-9 and 50% Glass Frit; Glass 76-68; Celsian Glass Ceramic; Type II Portland Cement and 10% PW-9 Calcine; and Type II Portland Cement and 10% SPC-5B Supercalcine. Bulk property data were used to calculate and compare the relative quantities of waste form volume produced at a spent fuel processing rate of 5 metric ton uranium/day. This quantity ranged from 3173 L/day (5280 Kg/day) for 10% SPC-5B supercalcine in cement to 83 L/day (294 Kg/day) for 100% calcine. Mechanical strength, volatility, and leach resistance tests provide data related to waste form durability. Glass, glass-ceramic and supercalcine ranked high in waste form durability where as the 100% PW-9 calcine ranked low. All other materials ranked between these two groupings

  16. Design of Cu8Zr5-based bulk metallic glasses

    DEFF Research Database (Denmark)

    Yang, L.; Xia, J.H.; Wang, Q.; Dong, C.; Chen, L.Y.; Ou, X.; Liu, J.F.; Jiang, J.Z.; Klementiev, K.; Saksl, K.; Franz, H.; Schneider, J.R.; Gerward, Leif

    2006-01-01

    Basic polyhedral clusters have been derived from intermetallic compounds at near-eutectic composition by considering a dense packing and random arrangement of atoms at shell sites. Using such building units, bulk metallic glasses can be formed. This strategy was verified in the Cu-Zr binary syste.......382)(100-x)Nb-x, where x=1.5 and 2.5 at. %, and (Cu0.618Zr0.382)(98)Sn-2. The present results may open a route to prepare amorphous alloys with improved glass forming ability.......Basic polyhedral clusters have been derived from intermetallic compounds at near-eutectic composition by considering a dense packing and random arrangement of atoms at shell sites. Using such building units, bulk metallic glasses can be formed. This strategy was verified in the Cu-Zr binary system......, where we have demonstrated the existence of Cu8Zr5 icosahedral clusters in Cu61.8Zr38.2, Cu64Zr36, and Cu64.5Zr35.5 amorphous alloys. Furthermore, ternary bulk metallic glasses can be developed by doping the basic Cu-Zr alloy with a minority element. This hypothesis was confirmed in systems (Cu0.618Zr0...

  17. Leachables evaluation for bulk drug substance.

    Science.gov (United States)

    Tsui, Victor; Somma, Maria S; Zitzner, Linda A

    2009-01-01

    This study describes a comprehensive analytical approach for evaluating potential leachables from product-contacting material surfaces in the manufacture of bulk drug substance (BDS) for use in parenteral products. A qualitative step-by-step evaluation of the process stream for the production, purification, and storage of the BDS was performed. The product-contact equipment surfaces were then grouped based on their materials of construction and prioritized according to the potential risk of contributing leachables to the BDS. Based on this evaluation, 13 potential leachable species were identified and classified either as volatile organic compounds (VOCs), semi-volatile organic compounds (SVOCs), anions, cations, or trace metals. The BDS was first screened for the presence of VOCs, SVOCs, anions, cations, and trace metals using analytical methods that were qualified for their application with the BDS. Thirteen potential leachables were then spiked in the BDS and in the water for injection for spike-recovery studies. The analysis of the BDS for potential leachables showed that the potential impurities were not present in the BDS except for a trace amount of silicon, and that the residual solvent concentrations were lower than the recommended limits established by the International Committee on Harmonisation. The spike-recovery studies confirmed that the analytical methods could effectively determine the leachable compounds in the BDS. Moreover, the 13 contaminants did not form a complex with the protein in the BDS and did not represent a potential risk to the BDS's safety and stability. PMID:19634355

  18. Bulk viscous cosmology: statefinder and entropy

    CERN Document Server

    He, X

    2006-01-01

    The statefinder diagnostic pair is adopted to differentiate viscous cosmology models and it is found that the trajectories of these viscous cosmology models on the statefinder pair $s-r$ plane are quite different from those of the corresponding non-viscous cases. Particularly for the quiessence model, the singular properties of state parameter $w=-1$ are obviously demonstrated on the statefinder diagnostic pair planes. We then discuss the entropy of the viscous / dissipative cosmology system which may be more practical to describe the present cosmic observations as the perfect fluid is just a global approximation to the complicated cosmic media in current universe evolution. When the bulk viscosity takes the form of $\\zeta=\\zeta_{1}\\dot{a}/a$($\\zeta_{1}$ is constant), the relationship between the entropy $S$ and the redshift $z$ is explicitly given out. We find that the entropy of the viscous cosmology is always increasing and consistent with the thermodynamics arrow of time for the universe evolution. With t...

  19. 27 CFR 20.191 - Bulk articles.

    Science.gov (United States)

    2010-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Bulk articles. 20.191... Users of Specially Denatured Spirits Operations by Users § 20.191 Bulk articles. Users who convey articles in containers exceeding one gallon may provide the recipient with a photocopy of subpart G of...

  20. Bulk equations of motion from CFT correlators

    CERN Document Server

    Kabat, Daniel

    2015-01-01

    To O(1/N) we derive, purely from CFT data, the bulk equations of motion for interacting scalar fields and for scalars coupled to gauge fields and gravity. We first uplift CFT operators to mimic local AdS fields by imposing bulk microcausality. This requires adding an infinite tower of smeared higher-dimension double-trace operators to the CFT definition of a bulk field, with coefficients that we explicitly compute. By summing the contribution of the higher-dimension operators we derive the equations of motion satisfied by these uplifted CFT operators and show that we precisely recover the expected bulk equations of motion. We exhibit the freedom in the CFT construction which corresponds to bulk field redefinitions.

  1. Microstructure evolution in Nd:YAG laser-welded (Zr53Cu30Ni9Al8)Si0.5 bulk metallic glass alloy

    International Nuclear Information System (INIS)

    To generate a rapid welding thermal cycle for a (Zr53Cu30Ni9Al8)Si0.5 bulk metallic glass (BMG) weld, the Nd:YAG pulse laser welding process with pre-selected welding variables is used in this study. The microstructure development and crystallization behavior in the weld fusion zone (WFZ) and the heat-affected zone (HAZ) are investigated by scanning electron microscopy (SEM), micro-area X-ray diffractometry (XRD) and transmission electron microscopy (TEM). From the results, it is observed that the HAZ is liable to crystallize, although no crystallization occurs within the WFZ. The spherical type crystalline phases (with a particle size of 20-200 nm) observed in the HAZ, which are rich in Zr, Cu and Ni, result in a change of chemical composition in this region. Furthermore, if the particle size in the crystallized area is greater than 50 nm, cracks may form.

  2. 'Age-hardened alloy' based on bulk polycrystalline oxide ceramic

    Science.gov (United States)

    Gurnani, Luv; Singh, Mahesh Kumar; Bhargava, Parag; Mukhopadhyay, Amartya

    2015-05-01

    We report here for the first time the development of 'age-hardened/toughened' ceramic alloy based on MgO in the bulk polycrystalline form. This route allows for the facile development of a 'near-ideal' microstructure characterized by the presence of nanosized and uniformly dispersed second-phase particles (MgFe2O4) within the matrix grains, as well as along the matrix grain boundaries, in a controlled manner. Furthermore, the intragranular second-phase particles are rendered coherent with the matrix (MgO). Development of such microstructural features for two-phase bulk polycrystalline ceramics is extremely challenging following the powder metallurgical route usually adopted for the development of bulk ceramic nanocomposites. Furthermore, unlike for the case of ceramic nanocomposites, the route adopted here does not necessitate the usage of nano-powder, pressure/electric field-assisted sintering techniques and inert/reducing atmosphere. The as-developed bulk polycrystalline MgO-MgFe2O4 alloys possess considerably improved hardness (by ~52%) and indentation toughness (by ~35%), as compared to phase pure MgO.

  3. Bulk and interfacial thermal transport in microstructural porous materials with application to fuel cells

    OpenAIRE

    Sadeghifar, Hamidreza

    2015-01-01

    The performance, reliability and durability of fuel cells are strongly influenced by the operating conditions, especially temperature and compression. Adequate thermal and water management of fuel cells requires knowledge of the thermal bulk and interfacial resistances of all involved components. The porous, brittle and anisotropic nature of most fuel cell components, together with the micro/nano-sized structures, has made it challenging to study their transport properties and thermal behavio...

  4. Bulk micromachining of silicon using electron-beam-induced carbonaceous nanomasking

    International Nuclear Information System (INIS)

    This paper reports on an alternative nanolithographic technique for bulk micromachining of silicon. We show how to selectively etch Si(110) in aqueous KOH solutions using electron-beam-induced nanomasking. Already nanometre thin carbonaceous films can completely suppress the wet anisotropic chemical etching of Si performed in alkaline solution (10 wt% KOH+5 wt% isopropanol). It is shown that under optimized conditions, this approach can be exploited for the fabrication of three-dimensional micro- and nanostructures

  5. Bulk micromachining of silicon using electron-beam-induced carbonaceous nanomasking

    Energy Technology Data Exchange (ETDEWEB)

    Djenizian, T [Laboratoire MADIREL (UMR 6121), Electrochemistry of Materials Group, Universite de Provence-CNRS Centre Saint Jerome, F-13397 Marseille Cedex 20 (France); Salhi, B [Institut de Recherche Interdisciplinaire (IRI), Avenue Poincare BP 60069, 59652 Villeneuve d' Ascq (France); Boukherroub, R [Institut de Recherche Interdisciplinaire (IRI), Avenue Poincare BP 60069, 59652 Villeneuve d' Ascq (France); Schmuki, P [Department of Materials Science, University of Erlangen-Nuremberg, WW4-LKO, Martensstrasse 7, D-91058 Erlangen (Germany)

    2006-11-14

    This paper reports on an alternative nanolithographic technique for bulk micromachining of silicon. We show how to selectively etch Si(110) in aqueous KOH solutions using electron-beam-induced nanomasking. Already nanometre thin carbonaceous films can completely suppress the wet anisotropic chemical etching of Si performed in alkaline solution (10 wt% KOH+5 wt% isopropanol). It is shown that under optimized conditions, this approach can be exploited for the fabrication of three-dimensional micro- and nanostructures.

  6. The effects of initial welding temperature and welding parameters on the crystallization behaviors of laser spot welded Zr-based bulk metallic glass

    International Nuclear Information System (INIS)

    This study investigated the effects of the initial welding temperature (IWT) and welding parameters on the crystallization behaviors of laser spot welded (Zr53Cu30Ni9Al8)Si0.5 bulk metallic glass (BMG). After the welding process, the microstructure evolution, glass-forming ability (GFA) and mechanical properties of the welded samples were determined by a combination of scanning electron microscopy (SEM), transmission electron microscopy (TEM), differential scanning calorimetry (DSC) and the Vicker's micro-hardness test. The results showed that the heat-affected zone (HAZ) crystallization seemed avoidable under the room temperature welding process. However, with a combination of a lower energy input (welding Condition C) and a lower IWT (at 0 deg. C), a crystallization-free HAZ was finally obtained. Using the above welding condition into the refined heat flow equation, a critical retention time of 79 ms for the crystallization temperature interval was estimated. Moreover, as the laser welded samples came to crystallization in the HAZ, it was observed that a higher content of spherical-type crystalline precipitates tended to result in a higher value of glass transition temperature, Tg. Therefore, the GFA indices, ΔTx, γ and γm, were reduced. Furthermore, it was found that the micro-hardness value in the HAZ crystallization area was decreased due to the massive cracks formed in most parts of the crystalline precipitates. For a crystallization-free HAZ, the hardness seemed unaffected.

  7. Fabrication of ternary Ca-Mg-Zn bulk metallic glasses

    Directory of Open Access Journals (Sweden)

    R. Nowosielski

    2013-02-01

    Full Text Available Purpose: The paper describes the preparation, structure and thermal properties of ternary Ca-Mg-Zn bulk metallic glass in form of as-cast rods.Design/methodology/approach: The investigations on the ternary Ca-Mg-Zn glassy rods were conducted by using X-ray diffraction (XRD, scanning electron microscopy (SEM which energy dispersive X-ray analysis (EDS.Findings: The X-ray diffraction investigations have revealed that the studied as-cast rod was amorphous. The fractures of studied alloy could be classified as mixed fracture with indicated “river” and “smooth” fractures. Both type of the fracture surfaces consist of weakly formed “river” and “shell” patterns and “smooth” regions. The “river” patterns are characteristic for metallic glassy alloys.Practical implications: The studied Ca-based bulk metallic glasses is a relatively new group of material. Ca-based bulk metallic glasses are applied for many applications in different elements. Ca-based bulk metallic glasses have many unique properties such as low density (~2.0 g/cm3, low Youn g’s modulus ( ~20 to 30 GPa. The elastic modulus of Ca-b ased BMGs is comparable to that of hum an bone s, and Ca, Mg, and Zn are biocompatible. These features make the Ca-Mg-Zn–based alloys attractive for use in biomedical applications.Originality/value: Fabrication of amorphous alloy in the form of rod ternary Ca-Mg-Zn alloy by pressure die casting method.

  8. X-ray fluorescence mapping and micro-XANES spectroscopic characterization of exhaust particulates emitted from auto engines burning MMT-added gasoline.

    Science.gov (United States)

    Mölders, N; Schilling, P J; Wong, J; Roos, J W; Smith, I L

    2001-08-01

    The elemental distribution and compositional homogeneity in auto exhaust particulates emitted from methylcyclopentadienyl manganese tricarbonyl-(MMT-)added gasoline engines have been investigated using a newly installed synchrotron X-ray microprobe. Two representative groups of exhaust particulate matter, as defined in a recent bulk X-ray absorption fine structure (XAFS) spectroscopic study at the Mn K-edge, were studied. The micro-X-ray absorption near-edge structure (XANES) spectra indicate a relatively homogeneous distribution of phases within a given particulate sample, down to a spatial extent of 40 microm (the resolution of microprobe). The micro-XANES also enabled analysis of several areas which displayed compositions different from the bulk sample, supporting the general theory describing manganese species formation in the exhaust. The ability to evaluate small regions also enabled direct verification of manganese sulfate from the S XANES despite the vast excess of sulfur present in other forms. The presence of a chloride compound, introduced through the sample dilution air and engine intake air, was also revealed. The study demonstrates the value of the combined X-ray microfluorescence with excitation by polychromatic radiation for elemental mapping and micro-XANES spectroscopy for chemical speciation in the study of dilute environmental materials containing low-Z constituents such as Cl, S, and P. PMID:11505987

  9. Fabrication of high aspect ratio micro electrode by using EDM

    Science.gov (United States)

    Mejid Elsiti, Nagwa; Noordin, M. Y.; Umar Alkali, Adam

    2016-02-01

    The electrical discharge machining (EDM) process inherits characteristics that make it a promising micro-machining technique. Micro electrical discharge machining (micro- EDM) is a derived form of EDM, which is commonly used to manufacture micro and miniature parts and components by using the conventional electrical discharge machining fundamentals. Moving block electro discharge grinding (Moving BEDG) is one of the processes that can be used to fabricate micro-electrode. In this study, a conventional die sinker EDM machine was used to fabricate the micro-electrode. Modifications are made to the moving BEDG, which include changing the direction of movements and control gap in one electrode. Consequently current was controlled due to the use of roughing, semi-finishing and finishing parameters. Finally, a high aspect ratio micro-electrode with a diameter of 110.49μm and length of 6000μm was fabricated.

  10. Micro-propulsion and micro-combustion; Micropropulsion microcombustion

    Energy Technology Data Exchange (ETDEWEB)

    Ribaud, Y.; Dessornes, O.

    2002-10-01

    The AAAF (french space and aeronautic association) organized at Paris a presentation on the micro-propulsion. The first part was devoted to the thermal micro-machines for micro drones, the second part to the micro-combustion applied to micro-turbines. (A.L.B.)

  11. Production of candidate natural matrix reference materials for micro-analytical techniques

    International Nuclear Information System (INIS)

    Homogeneity is considered to be the most vital prerequisite for a certified reference material (CRM); more stringent requirements exist for the analysis of small subsamples. Many of the natural matrix CRMs are prepared from bulk samples by grinding and milling them to a certain particle size, which is expected to provide a more homogenous material; however recommended sample sizes for biological and environmental reference materials are found to be more than 100 mg. Since the milling of materials is costly and has some drawbacks, natural materials that already occur as small particles such as air particulate matter, certain sediments, and cellular biological materials may form the basis of the required reference materials. The nature of these materials, i.e. naturally occurring particles, may provide ideal model reference material. We describe here the production of the materials and preliminary tests, the evaluation for the micro-analytical techniques

  12. Poly(hydridocarbyne as Highly Processable Insulating Polymer Precursor to Micro/Nanostructures and Graphite Conductors

    Directory of Open Access Journals (Sweden)

    Aaron M. Katzenmeyer

    2009-01-01

    Full Text Available Carbon-based electronic materials have received much attention since the discovery and elucidation of the properties of the nanotube, fullerene allotropes, and conducting polymers. Amorphous carbon, graphite, graphene, and diamond have also been the topics of intensive research. In accordance with this interest, we herein provide the details of a novel and facile method for synthesis of poly(hydridocarbyne (PHC, a preceramic carbon polymer reported to undergo a conversion to diamond-like carbon (DLC upon pyrolysis and also provide electrical characterization after low-temperature processing and pyrolysis of this material. The results indicate that the strongly insulating polymer becomes notably conductive in bulk form upon heating and contains interspersed micro- and nanostructures, which are the subject of ongoing research.

  13. A Stochastic Closure for Two-Moment Bulk Microphysics of Warm Clouds: Part I, Derivations

    CERN Document Server

    Collins, David

    2015-01-01

    We propose a mathematical methodology to derive a stochastic parameterization of bulk warm cloud micro-physics properties. Unlike previous bulk parameterizations, the stochastic parameterization does not assume any particular droplet size distribution, all parameters have physical meanings which are recoverable from data, and the resultant parameterization has the flexibility to utilize a variety of collision kernels. Our strategy is a new two-fold approach to modelling the kinetic collection equation. Partitioning the droplet spectrum into cloud and rain aggregates, we represent droplet densities as the sum of a mean and a random fluctuation. Moreover, we use a Taylor approximation for the collision kernel which allows the resulting parameterization to be independent of the collision kernel. To address the two-moment closure for bulk microphysical equations, we represent the higher (third) order terms as points in an Ornstein-Uhlenbeck-like stochastic process. These higher order terms are aggregate number co...

  14. Interaction of gas phase atomic hydrogen with Pt(111): Direct evidence for the formation of bulk hydrogen species

    Institute of Scientific and Technical Information of China (English)

    JIANG ZhiQuan; HUANG WeiXin; BAO XinHe

    2007-01-01

    Employing hot tungsten filament to thermal dissociate molecular hydrogen, we generated gas phase atomic hydrogen under ultra-high vacuum (UHV) conditions and investigated its interaction with Pt(111) surface. Thermal desorption spectroscopy (TDS) results demonstrate that adsorption of molecular hydrogen on Pt(111) forms surface Had species whereas adsorption of atomic hydrogen forms not only surface Had species but also bulk Had species. Bulk Had species is more thermal-unstable than surface Had species on Pt(111), suggesting that bulk Had species is more energetic. This kind of weakly- adsorbed bulk Had species might be the active hydrogen species in the Pt-catalyzed hydrogenation reactions.

  15. Micro Learning: A Modernized Education System

    Directory of Open Access Journals (Sweden)

    Omer Jomah

    2016-03-01

    Full Text Available Learning is an understanding of how the human brain is wired to learning rather than to an approach or a system. It is one of the best and most frequent approaches for the 21st century learners. Micro learning is more interesting due to its way of teaching and learning the content in a small, very specific burst. Here the learners decide what and when to learn. Content, time, curriculum, form, process, mediality, and learning type are the dimensions of micro learning. Our paper will discuss about micro learning and about the micro-content management system. The study will reflect the views of different users, and will analyze the collected data. Finally, it will be concluded with its pros and cons. 

  16. Tractor beam in micro-scale

    Science.gov (United States)

    Brzobohatý, O.; Karásek, V.; Šiler, M.; Chvátal, L.; Čižmár, T.; Zemánek, P.

    2014-12-01

    Following the Keplerian idea of radiative forces one would intuitively expect that an object illuminated by sunlight radiation or a laser beam is accelerated along the direction of the photon flow. Such radiation pressure forms the basis for the concept of solar sail, or laser acceleration of micro-particles. In contrast, a hypothetical optical field known from the realm of science-fiction as the "tractor" beam attracts the matter from large distances against the beam propagation. We present a geometry of such"tractor" beam in micro-scale and experimentally demonstrate how it acts upon spherical micro-particles of various sizes or optically self-arranged structures of micro-particles.

  17. Bulk Viscosity in Holographic Lifshitz Hydrodynamics

    CERN Document Server

    Hoyos, Carlos; Oz, Yaron

    2013-01-01

    We compute the bulk viscosity in holographic models dual to theories with Lifshitz scaling and/or hyperscaling violation, using a generalization of the bulk viscosity formula derived in arXiv:1103.1657 from the null focusing equation. We find that only a class of models with massive vector fields are truly Lifshitz scale invariant, and have a vanishing bulk viscosity. For other holographic models with scalars and/or massless vector fields we find a universal formula in terms of the dynamical exponent and the hyperscaling violation exponent.

  18. Bulk viscosity in holographic Lifshitz hydrodynamics

    OpenAIRE

    Carlos Hoyos; Bom Soo Kim; Yaron Oz

    2014-01-01

    We compute the bulk viscosity in holographic models dual to theories with Lifshitz scaling and/or hyperscaling violation, using a generalization of the bulk viscosity formula derived in arXiv:1103.1657 from the null focusing equation. We find that only a class of models with massive vector fields are truly Lifshitz scale invariant, and have a vanishing bulk viscosity. For other holographic models with scalars and/or massless vector fields we find a universal formula in terms of the dynamical ...

  19. Bulk viscosity in holographic Lifshitz hydrodynamics

    International Nuclear Information System (INIS)

    We compute the bulk viscosity in holographic models dual to theories with Lifshitz scaling and/or hyperscaling violation, using a generalization of the bulk viscosity formula derived in arXiv:1103.1657 from the null focusing equation. We find that only a class of models with massive vector fields are truly Lifshitz scale invariant, and have a vanishing bulk viscosity. For other holographic models with scalars and/or massless vector fields we find a universal formula in terms of the dynamical exponent and the hyperscaling violation exponent

  20. Bulk viscosity of hot and dense hadrons

    International Nuclear Information System (INIS)

    The bulk viscosity of hot and dense hadrons has been estimated within the framework of hadronic resonance gas model. We observe that the bulk viscosity to entropy ratio increases faster with temperature for higher μB. The magnitude of ζ is more at high μB. This results will have crucial importance for fire-ball produced at low energy nuclear collisions (FAIR, NICA). We note that the bulk to shear viscosity ratio remains above the bound set by AdS/CFT

  1. Formation of cerium-based bulk metallic glasses

    International Nuclear Information System (INIS)

    We report the formation and composition range of Ce-based bulk metallic glasses. Ternary Ce-Al-Cu(Co,Ni) glassy rods of 1-3 mm in diameter can be easily formed in a wide composition range by a conventional copper mold cast method. Substituting Ce with low-cost Ce-rich misch metal (MM), MM-Al-Cu bulk glasses with a similar high glass-forming ability (GFA) can be obtained. With minor addition of extra elements such as Fe, Co, Ni, Nb, Zn and Si, the critical diameter of the full glassy rods of the Ce-Al-Cu matrix can be markedly enhanced from 2 mm to at least 3-10 mm. It is found that the often-cited empirical criteria for bulk metallic glass formation cannot interpret the formation and the addition effect on GFA of the metallic glasses. The striking effect and mechanism of microalloying on the GFA of the metallic glasses are studied. These materials with extremely low glass transition temperatures (341-439 K, even below the boiling temperature of water) and excellent deformability at low temperatures could have potential applications

  2. Thermocline bulk shear analysis in the northern North Sea

    Science.gov (United States)

    Chen, Shengli; Polton, Jeff A.; Hu, Jianyu; Xing, Jiuxing

    2016-04-01

    Thermocline bulk shear is investigated in the northern North Sea using historical observations. The conventional bulk shear is modified to define a thermocline bulk shear (TBS), in order to better represent the shear across the thermocline. The TBS computed by observed currents is decomposed into components at different frequency bands. The near-inertial TBS is the largest component. Its dominance is significant during the period of high wind. It is formed by the wind-driven near-inertial current which has a distinct phase shift (˜180°) across the thermocline. A linear model is presented, which well simulates the observed near-inertial TBS, especially during the period of relatively strong wind. The semidiurnal TBS makes a secondary contribution to the total TBS. It is only slightly smaller than the near-inertial TBS when the wind is relatively weak. The large values of semidiurnal TBS are associated with semidiurnal currents which have a phase shift (˜30-40°) or a magnitude difference (˜5 cm/s) across the thermocline. The low-frequency (<0.7 cpd) TBS also makes an episodic contribution to the total. Its variation coincides with the Ekman transport during the period of relatively strong wind. The low-frequency TBS is mainly formed by an Ekman-like clockwise spiraling of velocity with depth or a distinct magnitude difference in velocities between upper and lower layers.

  3. Oxygen Behavior in Bulk Amorphous Zr-base Alloy

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    Bulk Zr55Al10Ni5Cu30 metallic glass plates with a dimension of 85 mm×35mm×4 mm and a complicated plate werefabricated by injecting casting method using spongy zirconium and industrial purity aluminum, nickel and copper asraw materials. It was shown that the holding time of liquid metals at elevated temperatures had a great influence onthe oxygen content of the plates due to the contamination resulting from the atmosphere. Increasing holding timeresulted in the increase of oxygen content in the injected alloy. The glass transition temperatures of the bulk metallicglass plates are higher than that reported in the literature and crystallization temperature is lower for the one withhigher oxygen content at the same heating rate. The extension of the undercooled liquid region △Tx reaching about87 K is 3 K higher than that previously reported and 26 K higher than that with oxygen content of 0.076 wt pct forthe one with oxygen content as high as 0.065 wt pct. Therefore the oxygen content of the alloy has a significantinfluence on the glass forming ability and thermal stability of bulk metal glass. It is suggested that direct correlationbetween high glass forming ability and large △Tx is only valid for a well-defined Iow oxygen concentration or has tobe reconsidered by incorporating oxygen as an additional alloying element.

  4. A COMPREHENSIVE TECHNICAL REVIEW OF THE DEMONSTRATION BULK VITRIFICATION SYSTEM

    International Nuclear Information System (INIS)

    In May 2006, CH2M Hill Hanford Group, Inc. chartered an Expert Review Panel (ERP) to review the current status of the Demonstration Bulk Vitrification System (DBVS). It is the consensus of the ERP that bulk vitrification is a technology that requires further development and evaluation to determine its potential for meeting the Hanford waste stabilization mission. No fatal flaws (issues that would jeopardize the overall DBVS mission that cannot be mitigated) were found, given the current state of the project. However, a number of technical issues were found that could significantly affect the project's ability to meet its overall mission as stated in the project ''Justification of Mission Need'' document, if not satisfactorily resolved. The ERP recognizes that the project has changed from an accelerated schedule demonstration project to a formally chartered project that must be in full compliance with DOE 413.3 requirements. The perspective of the ERP presented herein, is measured against the formally chartered project as stated in the approved Justification of Mission Need document. A justification of Mission Need document was approved in July 2006 which defined the objectives for the DBVS Project. In this document, DOE concluded that bulk vitrification is a viable technology that requires additional development to determine its potential applicability to treatment of a portion of the Hanford low activity waste. The DBVS mission need statement now includes the following primary objectives: (1) process approximately 190,000 gallons of Tank S-109 waste into fifty 100 metric ton boxes of vitrified product; (2) store and dispose of these boxes at Hanford's Integrated Disposal Facility (IDF); (3) evaluate the waste form characteristics; (4) gather pilot plant operability data, and (5) develop the overall life cycle system performance of bulk vitrification and produce a comparison of the bulk vitrification process to building a second LAW Immobilization facility or other

  5. A COMPREHENSIVE TECHNICAL REVIEW OF THE DEMONSTRATION BULK VITRIFICATION SYSTEM

    Energy Technology Data Exchange (ETDEWEB)

    SCHAUS, P.S.

    2006-09-29

    In May 2006, CH2M Hill Hanford Group, Inc. chartered an Expert Review Panel (ERP) to review the current status of the Demonstration Bulk Vitrification System (DBVS). It is the consensus of the ERP that bulk vitrification is a technology that requires further development and evaluation to determine its potential for meeting the Hanford waste stabilization mission. No fatal flaws (issues that would jeopardize the overall DBVS mission that cannot be mitigated) were found, given the current state of the project. However, a number of technical issues were found that could significantly affect the project's ability to meet its overall mission as stated in the project ''Justification of Mission Need'' document, if not satisfactorily resolved. The ERP recognizes that the project has changed from an accelerated schedule demonstration project to a formally chartered project that must be in full compliance with DOE 413.3 requirements. The perspective of the ERP presented herein, is measured against the formally chartered project as stated in the approved Justification of Mission Need document. A justification of Mission Need document was approved in July 2006 which defined the objectives for the DBVS Project. In this document, DOE concluded that bulk vitrification is a viable technology that requires additional development to determine its potential applicability to treatment of a portion of the Hanford low activity waste. The DBVS mission need statement now includes the following primary objectives: (1) process approximately 190,000 gallons of Tank S-109 waste into fifty 100 metric ton boxes of vitrified product; (2) store and dispose of these boxes at Hanford's Integrated Disposal Facility (IDF); (3) evaluate the waste form characteristics; (4) gather pilot plant operability data, and (5) develop the overall life cycle system performance of bulk vitrification and produce a comparison of the bulk vitrification process to building a second LAW

  6. Epitaxially Grown Layered MFI–Bulk MFI Hybrid Zeolitic Materials

    KAUST Repository

    Kim, Wun-gwi

    2012-11-27

    The synthesis of hybrid zeolitic materials with complex micropore-mesopore structures and morphologies is an expanding area of recent interest for a number of applications. Here we report a new type of hybrid zeolite material, composed of a layered zeolite material grown epitaxially on the surface of a bulk zeolite material. Specifically, layered (2-D) MFI sheets were grown on the surface of bulk MFI crystals of different sizes (300 nm and 10 μm), thereby resulting in a hybrid material containing a unique morphology of interconnected micropores (∼0.55 nm) and mesopores (∼3 nm). The structure and morphology of this material, referred to as a "bulk MFI-layered MFI" (BMLM) material, was elucidated by a combination of XRD, TEM, HRTEM, SEM, TGA, and N2 physisorption techniques. It is conclusively shown that epitaxial growth of the 2-D layered MFI sheets occurs in at least two principal crystallographic directions of the bulk MFI crystal and possibly in the third direction as well. The BMLM material combines the properties of bulk MFI (micropore network and mechanical support) and 2-D layered MFI (large surface roughness, external surface area, and mesoporosity). As an example of the uses of the BMLM material, it was incorporated into a polyimide and fabricated into a composite membrane with enhanced permeability for CO2 and good CO2/CH4 selectivity for gas separations. SEM-EDX imaging and composition analysis showed that the polyimide and the BMLM interpenetrate into each other, thereby forming a well-adhered polymer/particle microstructure, in contrast with the defective interfacial microstructure obtained using bare MFI particles. Analysis of the gas permeation data with the modified Maxwell model also allows the estimation of the effective volume of the BMLM particles, as well as the CO2 and CH4 gas permeabilities of the interpenetrated layer at the BMLM/polyimide interface. © 2012 American Chemical Society.

  7. 'Micro-8' micro-computer system

    International Nuclear Information System (INIS)

    The micro-computer Micro-8 system has been developed to organize a data exchange network between various instruments and a computer group including a large computer system. Used for packet exchangers and terminal controllers, the system consists of ten kinds of standard boards including a CPU board with INTEL-8080 one-chip-processor. CPU architecture, BUS architecture, interrupt control, and standard-boards function are explained in circuit block diagrams. Operations of the basic I/O device, digital I/O board and communication adapter are described with definitions of the interrupt ramp status, I/O command, I/O mask, data register, etc. In the appendixes are circuit drawings, INTEL-8080 micro-processor specifications, BUS connections, I/O address mappings, jumper connections of address selection, and interface connections. (author)

  8. Effect of radiation on bulk swelling of plutonium alloys

    International Nuclear Information System (INIS)

    Several studies show that plutonium alloys present bulk swelling. More precisely, length (as measured by dilatometry) and lattice parameter (as measured by X-ray diffraction) increase with time and seems to reach saturation after a few months for the microscopic scale. This bulk swelling can be correlated to self-induced radiation due to the decay of the different plutonium isotopes (238Pu, 239Pu, 241Pu and 242Pu) which also induce helium that tends to forms clusters, then bubbles. Many experimental and theoretical results have already been published on this topic. The goal of this paper is to review some of the results and to propose a strategy for both experiments and modelling to try to answer some of the remaining questions regarding swelling and more generally self-irradiation defects in plutonium alloys

  9. Bulk-edge correspondence for topological photonic continua

    CERN Document Server

    Silveirinha, Mario G

    2016-01-01

    Here, building on our previous work [Phys. Rev. B, 92, 125153, (2015)], it is shown that the propagation of unidirectional gapless edge states at an interface of two topologically distinct electromagnetic continua with a well-behaved asymptotic electromagnetic response is rigorously predicted by the bulk-edge correspondence principle. We work out detailed examples demonstrating that when the spatial-cut off of the nonreciprocal part of the material response is considered self-consistently in the solution of the relevant electromagnetic problem, the number of unidirectional gapless edge modes is identical to the difference of the Chern numbers of the bulk materials. Furthermore, it is shown how the role of the spatial cut-off can be imitated in realistic systems using a tiny air gap with a specific thickness. This theory provides a practical roadmap for the application of topological concepts to photonic platforms formed by nonreciprocal electromagnetic continua.

  10. Effects of stirring on the bulk etch rate of CR-39 detector

    International Nuclear Information System (INIS)

    It is well established that the bulk etch rates for solid state nuclear track detectors are affected by the concentration and the temperature of the etchant. Recently, we found that the bulk etch rate for the LR 115 detector to be affected by stirring during etching. In the present work, the effects of stirring on the bulk etch rate of the CR-39 detector is investigated. One set of sample was etched under continuous stirring by a magnetic stirrer at 70 deg. C in a 6.25 N NaOH solution, while the other set of samples was etched without the magnetic stirrer. After etching, the bulk etch thickness was measured using Form Talysurf PGI (Taylor Hobson, Leicester, England). It was found that magnetic stirring did not affect the bulk etch of the CR-39 detector, which was in contrast to the results for the LR 115 detector

  11. Structural Characterization of Carbon Nanomaterial Film In Situ Synthesized on Various Bulk Metals

    Directory of Open Access Journals (Sweden)

    J. Y. Xu

    2014-01-01

    Full Text Available Carbon nanofiber films were prepared via a simple chemical vapor deposition (CVD method on various bulk metal substrates including bulk 316 L stainless steel, pure cobalt, and pure nickel treated by surface mechanical attrition treatment (SMAT. The microstructures of the carbon nanomaterial film were studied by SEM, TEM, XRD, and Raman spectroscopy. In this paper, bulk metallic materials treated by SMAT served as substrates as well as catalysts for carbon nanomaterial film formation. The results indicate that the carbon nanofiber films are formed concerning the catalytic effects of the refined metallic particles during CVD on the surface of SMAT-treated bulk metal substrates. However, distinguished morphologies of carbon nanomaterial film are displayed in the case of the diverse bulk metal substrates.

  12. Technical specifications for the bulk shielding reactor

    International Nuclear Information System (INIS)

    This report provides information concerning the technical specifications for the Bulk Shielding Reactor. Areas covered include: safety limits and limiting safety settings; limiting conditions for operation; surveillance requirements; design features; administrative controls; and monitoring of airborne effluents. 10 refs

  13. The bulk radio expansion of Cassiopeia A

    International Nuclear Information System (INIS)

    Comparison, in the visibility plane, or radio observations of Cassiopeia A made at 151 MHz over a 2.3 yr interval indicates that the bulk of the radio emitting material has not been decelerated strongly

  14. Faecal bulking efficacy of Australasian breakfast cereals.

    Science.gov (United States)

    Monro, John A

    2002-01-01

    Faecal bulk may play an important role in preventing a range of disorders of the large bowel, but as yet there is little information available on the relative faecal bulking capacities of various foods. Breakfast cereals are often promoted as a good source of potential bulk for 'inner health' because they provide dietary fibre, but their relative abilities to provide faecal bulk per se have not been described. The faecal bulking efficacy of 28 representative Australasian breakfast cereals was therefore measured. A rat model developed for the purpose, and shown to give similar responses as humans to cereal fibres, was used to measure faecal bulking efficacy as increases in fully hydrated faecal weight/100 g diet, based on precise measurements of food intake, faecal dry matter output and faecal water-holding capacity (g water held without stress/g faecal dry matter). Compared to a baseline diet containing 50% sucrose, increments in hydrated faecal weight due to 50% breakfast cereal ranged from slightly negative (Cornflakes, -2 g/100 g diet) to about 80 g/100 g diet (San Bran). Most breakfast cereals increased hydrated faecal weight by between 10 and 20 g/100 g diet from a baseline of 21 +/- 1.5 g/100 g diet, but four products containing high levels of wheat bran had an exceptionally large impact on hydrated faecal weight (increment > 20 g/100 g diet), and the changes resulted more from relative changes in dry matter output than in faecal water retention/gram. However, as faecal water retention was about 2.5 g water/g faecal dry matter on average, increases in dry matter represented large increases in faecal water load. Faecal bulking indices (FBI) for most of the breakfast cereals were less than 20 (wheat bran = 100). The content of wheat bran equivalents for faecal bulk (WBE(fb)) in the breakfast cereals was calculated from FBI. Most breakfast cereals contributed, per serve, less than 10% of a theoretical daily reference value for faecal bulk (DRV(fb) = 63 WBE

  15. PHONON ECHOES IN BULK AND POWDERED MATERIALS

    OpenAIRE

    Kajimura, K.

    1981-01-01

    Experimental and theoretical studies of phonon echoes in bulk and powdered materials are reviewed. Phonon echoes have been observed in many materials such as bulk piezoelectric crystals, paramagnets, glasses, doped semiconductors, and piezoelectric, magnetic, and metallic powders, etc. The echoes arise from a time reversal of the phase, like spin echoes, of a primary pulsed acoustic excitation due to a second acoustic or rf pulse. The phase reversal occurs through the nonlinear interactions o...

  16. Orbital magnetization in insulators: Bulk versus surface

    Science.gov (United States)

    Bianco, Raffaello; Resta, Raffaele

    2016-05-01

    The orbital magnetic moment of a finite piece of matter is expressed in terms of the one-body density matrix as a simple trace. We address a macroscopic system, insulating in the bulk, and we show that its orbital moment is the sum of a bulk term and a surface term, both extensive. The latter only occurs when the transverse conductivity is nonzero and it is due to conducting surface states. Simulations on a model Hamiltonian validate our theory.

  17. An intrinsic mobility ceiling of Si bulk

    OpenAIRE

    Garcia-Castello, Nuria; Prades, Joan Daniel; Cirera, Albert

    2011-01-01

    We compute by Density Functional Theory-Non Equilibrium Green Functions Formalism (DFT-NEGFF) the conductance of bulk Si along different crystallographic directions. We find a ceiling value for the intrinsic mobility of bulk silicon of $8.4\\cdot10^6 cm^2/V\\cdot s$. We suggest that this result is related to the lowest effective mass of the $$ direction.

  18. An electrochemical micro actuator

    NARCIS (Netherlands)

    Hamberg, M.W.; Neagu, C.R.; Gardeniers, J.G.E.; IJntema, D.J.; Elwenspoek, M.C.

    1995-01-01

    In this paper an investigation of the feasibility of a new electrochemical micro actuator is presented. The actuator is fabricated using silicon micro-machining techniques. A gas pressure is generated by electrolysis of an aqueous electrolyte solution. The build up pressure is used to change the def

  19. MicroCulture

    DEFF Research Database (Denmark)

    Marchetti, Emanuela

    2012-01-01

    This paper proposes a playful learning scenario, to enhance children’s museum experience, and the design of MicroCulture, a new learning platform. MicroCulture has been developed through a participatory design process, involving around 25 children. The perspective proposed in this paper is focused...

  20. Thermal Spectral Function and Deconfinement Temperature in Bulk Holographic AdS/QCD with Back Reaction of Bulk Vacuum

    CERN Document Server

    Cui, Ling-Xiao; Wu, Yue-Liang

    2014-01-01

    Based on the IR-improved bulk holographic AdS/QCD model which provides a consistent prediction for the mass spectra of resonance scalar, pseudoscalar, vector and axial vector mesons, we investigate its finite temperature behavior. By analyzing the spectral function of mesons and fitting it with a Breit-Wigner form, we perform an analysis for the critical temperature of mesons. The back-reaction effects of bulk vacuum are considered, the thermal mass spectral function of resonance mesons is calculated based on the back-reaction improved action. A reasonable melting temperature is found to be $T_c \\simeq 150 \\pm 7$ MeV, which is consistent with the recent results from lattice QCD simulations.

  1. Flow visualization of silicon-based micro pulsating heat pipes

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    Two sets of silicon-based micro pulsating heat pipes(SMPHPs) with trapezoidal cross section having hydraulic diameters of 352 μm(#1) and 394 μm(#2) respectively were fabricated for the first time using MEMS technology.With FC-72 as the working fluid,the start-up,steady operation state,as well as flow patterns were investigated using a CCD camera.It was found that the start-up process of these two SMPHPs was rather rapid.At the start-up period,no nucleation was observed,and the vapor plugs at the evaporator U-bends were formed mainly due to the breakup of liquid slugs.At the steady operation state,self-sustained oscillation with large amplitudes dominated the flow behavior when the inclination angle varied from 10° to 90°,but the nucleate boiling and bulk circulation were observed only in SMPHP #2.While bubbly,slug/plug,annular/semi-annular,and wavy-annular flows were observed in both two SMPHPs,the injection flow only appeared in SMPHP #2.

  2. Search for Bs0 --> micro+ micro- and B0 --> micro+ micro- decays with 2 fb-1 of pp collisions.

    Science.gov (United States)

    Aaltonen, T; Adelman, J; Akimoto, T; Albrow, M G; Alvarez González, B; Amerio, S; Amidei, D; Anastassov, A; Annovi, A; Antos, J; Aoki, M; Apollinari, G; Apresyan, A; Arisawa, T; Artikov, A; Ashmanskas, W; Attal, A; Aurisano, A; Azfar, F; Azzi-Bacchetta, P; Azzurri, P; Bacchetta, N; Badgett, W; Barbaro-Galtieri, A; Barnes, V E; Barnett, B A; Baroiant, S; Bartsch, V; Bauer, G; Beauchemin, P-H; Bedeschi, F; Bednar, P; Behari, S; Bellettini, G; Bellinger, J; Belloni, A; Benjamin, D; Beretvas, A; Beringer, J; Berry, T; Bhatti, A; Binkley, M; Bisello, D; Bizjak, I; Blair, R E; Blocker, C; Blumenfeld, B; Bocci, A; Bodek, A; Boisvert, V; Bolla, G; Bolshov, A; Bortoletto, D; Boudreau, J; Boveia, A; Brau, B; Bridgeman, A; Brigliadori, L; Bromberg, C; Brubaker, E; Budagov, J; Budd, H S; Budd, S; Burkett, K; Busetto, G; Bussey, P; Buzatu, A; Byrum, K L; Cabrera, S; Campanelli, M; Campbell, M; Canelli, F; Canepa, A; Carlsmith, D; Carosi, R; Carrillo, S; Carron, S; Casal, B; Casarsa, M; Castro, A; Catastini, P; Cauz, D; Cavalli-Sforza, M; Cerri, A; Cerrito, L; Chang, S H; Chen, Y C; Chertok, M; Chiarelli, G; Chlachidze, G; Chlebana, F; Cho, K; Chokheli, D; Chou, J P; Choudalakis, G; Chuang, S H; Chung, K; Chung, W H; Chung, Y S; Ciobanu, C I; Ciocci, M A; Clark, A; Clark, D; Compostella, G; Convery, M E; Conway, J; Cooper, B; Copic, K; Cordelli, M; Cortiana, G; Crescioli, F; Cuenca Almenar, C; Cuevas, J; Culbertson, R; Cully, J C; Dagenhart, D; Datta, M; Davies, T; de Barbaro, P; De Cecco, S; Deisher, A; De Lentdecker, G; De Lorenzo, G; Dell'orso, M; Demortier, L; Deng, J; Deninno, M; De Pedis, D; Derwent, P F; Di Giovanni, G P; Dionisi, C; Di Ruzza, B; Dittmann, J R; D'Onofrio, M; Donati, S; Dong, P; Donini, J; Dorigo, T; Dube, S; Efron, J; Erbacher, R; Errede, D; Errede, S; Eusebi, R; Fang, H C; Farrington, S; Fedorko, W T; Feild, R G; Feindt, M; Fernandez, J P; Ferrazza, C; Field, R; Flanagan, G; Forrest, R; Forrester, S; Franklin, M; Freeman, J C; Furic, I; Gallinaro, M; Galyardt, J; Garberson, F; Garcia, J E; Garfinkel, A F; Genser, K; Gerberich, H; Gerdes, D; Giagu, S; Giakoumopolou, V; Giannetti, P; Gibson, K; Gimmell, J L; Ginsburg, C M; Giokaris, N; Giordani, M; Giromini, P; Giunta, M; Glagolev, V; Glenzinski, D; Gold, M; Goldschmidt, N; Golossanov, A; Gomez, G; Gomez-Ceballos, G; Goncharov, M; González, O; Gorelov, I; Goshaw, A T; Goulianos, K; Gresele, A; Grinstein, S; Grosso-Pilcher, C; Grundler, U; Guimaraes da Costa, J; Gunay-Unalan, Z; Haber, C; Hahn, K; Hahn, S R; Halkiadakis, E; Hamilton, A; Han, B-Y; Han, J Y; Handler, R; Happacher, F; Hara, K; Hare, D; Hare, M; Harper, S; Harr, R F; Harris, R M; Hartz, M; Hatakeyama, K; Hauser, J; Hays, C; Heck, M; Heijboer, A; Heinemann, B; Heinrich, J; Henderson, C; Herndon, M; Heuser, J; Hewamanage, S; Hidas, D; Hill, C S; Hirschbuehl, D; Hocker, A; Hou, S; Houlden, M; Hsu, S-C; Huffman, B T; Hughes, R E; Husemann, U; Huston, J; Incandela, J; Introzzi, G; Iori, M; Ivanov, A; Iyutin, B; James, E; Jayatilaka, B; Jeans, D; Jeon, E J; Jindariani, S; Johnson, W; Jones, M; Joo, K K; Jun, S Y; Jung, J E; Junk, T R; Kamon, T; Kar, D; Karchin, P E; Kato, Y; Kephart, R; Kerzel, U; Khotilovich, V; Kilminster, B; Kim, D H; Kim, H S; Kim, J E; Kim, M J; Kim, S B; Kim, S H; Kim, Y K; Kimura, N; Kirsch, L; Klimenko, S; Klute, M; Knuteson, B; Ko, B R; Koay, S A; Kondo, K; Kong, D J; Konigsberg, J; Korytov, A; Kotwal, A V; Kraus, J; Kreps, M; Kroll, J; Krumnack, N; Kruse, M; Krutelyov, V; Kubo, T; Kuhlmann, S E; Kuhr, T; Kulkarni, N P; Kusakabe, Y; Kwang, S; Laasanen, A T; Lai, S; Lami, S; Lammel, S; Lancaster, M; Lander, R L; Lannon, K; Lath, A; Latino, G; Lazzizzera, I; Lecompte, T; Lee, J; Lee, J; Lee, Y J; Lee, S W; Lefèvre, R; Leonardo, N; Leone, S; Levy, S; Lewis, J D; Lin, C; Lin, C S; Linacre, J; Lindgren, M; Lipeles, E; Lister, A; Litvintsev, D O; Liu, T; Lockyer, N S; Loginov, A; Loreti, M; Lovas, L; Lu, R-S; Lucchesi, D; Lueck, J; Luci, C; Lujan, P; Lukens, P; Lungu, G; Lyons, L; Lys, J; Lysak, R; Lytken, E; Mack, P; Macqueen, D; Madrak, R; Maeshima, K; Makhoul, K; Maki, T; Maksimovic, P; Malde, S; Malik, S; Manca, G; Manousakis, A; Margaroli, F; Marino, C; Marino, C P; Martin, A; Martin, M; Martin, V; Martínez, M; Martínez-Ballarín, R; Maruyama, T; Mastrandrea, P; Masubuchi, T; Mattson, M E; Mazzanti, P; McFarland, K S; McIntyre, P; McNulty, R; Mehta, A; Mehtala, P; Menzemer, S; Menzione, A; Merkel, P; Mesropian, C; Messina, A; Miao, T; Miladinovic, N; Miles, J; Miller, R; Mills, C; Milnik, M; Mitra, A; Mitselmakher, G; Miyake, H; Moed, S; Moggi, N; Moon, C S; Moore, R; Morello, M; Movilla Fernandez, P; Mülmenstädt, J; Mukherjee, A; Muller, Th; Mumford, R; Murat, P; Mussini, M; Nachtman, J; Nagai, Y; Nagano, A; Naganoma, J; Nakamura, K; Nakano, I; Napier, A; Necula, V; Neu, C; Neubauer, M S; Nielsen, J; Nodulman, L; Norman, M; Norniella, O; Nurse, E; Oh, S H

    2008-03-14

    We have performed a search for B(s)(0) --> micro(+) micro(-) and B(0) --> micro(+) micro(-) decays in pp collisions at square root s = 1.96 TeV using 2 fb(-1) of integrated luminosity collected by the CDF II detector at the Fermilab Tevatron Collider. The observed number of B(s)(0) and B0 candidates is consistent with background expectations. The resulting upper limits on the branching fractions are B(B(s)0) --> micro(+) micro(-)) micro(+) micro(-))<1.8 x 10(-8) at 95% C.L. PMID:18352173

  3. Experimental observation of bulk and edge transport in photonic Lieb lattices

    CERN Document Server

    Guzman-Silva, D; Bandres, M A; Rechtsman, M C; Weimann, S; Nolte, S; Segev, M; Szameit, A; Vicencio, R A

    2014-01-01

    We analyze the transport of light in the bulk and at the edge of photonic Lieb lattices, whose unique feature is the existence of a flat band representing stationary states in the middle of the band structure that can form localized bulk states. We find that transport in bulk Lieb lattices is significantly affected by the particular excitation site within the unit cell, due to overlap with the flat band states. Additionally, we demonstrate the existence of new edge states in anisotropic Lieb lattices. These states arise due to a virtual defect at the lattice edges and are not described by the standard tight-binding model.

  4. [INVITED] Ultrafast laser micro-processing of transparent material

    Science.gov (United States)

    Watanabe, Wataru; Li, Yan; Itoh, Kazuyoshi

    2016-04-01

    Focusing ultrafast laser pulses inside a transparent material induces localized permanent structural modifications. Using these permanent structural modifications, one can produce photonic devices and micro-channels inside the bulk of a transparent material in three-dimensions. By virtue of localized melting and resolidification in materials, joining or welding is achieved between pieces of the same or different materials. This welding technique for transparent materials using ultrafast laser pulses is also reviewed along with applications to hermetic sealing. The mechanisms and applications of ultrafast laser micro-processing in transparent material are discussed.

  5. Process Chain for the Manufacture of Polymeric Tubular Micro-Components and “POLYTUBES Micro-Factory” Concept

    DEFF Research Database (Denmark)

    Qin, Yi; Perzon, Erik; Chronakis, Ioannis S.;

    The paper presents a process chain for the shaping of poly-meric tubular micro-components for the volume production as well as presents a concept for the integration of the developed processes and modular machines onto a platform to form a "POLYTUBES Micro-Factory", being resulting from the...

  6. Ordered Nanopillar Structured Electrodes for Depleted Bulk Heterojunction Colloidal Quantum Dot Solar Cells

    KAUST Repository

    Kramer, Illan J.

    2012-03-30

    A bulk heterojunction of ordered titania nanopillars and PbS colloidal quantum dots is developed. By using a pre-patterned template, an ordered titania nanopillar matrix with nearest neighbours 275 nm apart and height of 300 nm is fabricated and subsequently filled in with PbS colloidal quantum dots to form an ordered depleted bulk heterojunction exhibiting power conversion efficiency of 5.6%. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  7. Preparation of Aligned Polymer Micro/Nanofibres by Electrospinning

    Institute of Scientific and Technical Information of China (English)

    TAN Jin-Shan; LONG Yun-Ze; LI Meng-Meng

    2008-01-01

    @@ Polymer micro/nanofibres are prepared by typical and modified methods of electrospinning. The morphologies and microstructures of the electrospun micro/nanofibres are characterized by a scanning electron microscope (SEM). The micro/nanofibres prepared by the typical electrospinning are usually collected in the form of non-woven mats lacking of structural orientation. However, by modifying collector(s) of the electrospinning setup, the resulting polymer fibres show aligned structures to some extent. We analyse all the forces that the fibres experienced during electrospinning and find that the electrostatic force originating from the splitting electric field plays a key role in the alignment of the micro/nanofibres.

  8. MicroRNAs

    DEFF Research Database (Denmark)

    Devaux, Yvan; Stammet, Pascal; Friberg, Hans; Hassager, Christian; Kuiper, Michael A; Wise, Matt P; Nielsen, Niklas

    2015-01-01

    cardiac arrest would allow subsequent health care delivery to be tailored to individual patients. However, currently available predictive methods and biomarkers lack sufficient accuracy and therefore cannot be generally recommended in clinical practice. MicroRNAs have recently emerged as potential...... biomarkers of cardiovascular diseases. While the biomarker value of microRNAs for myocardial infarction or heart failure has been extensively studied, less attention has been devoted to their prognostic value after cardiac arrest. This review highlights the recent discoveries suggesting that microRNAs may be...

  9. Bulk viscous matter-dominated Universes: asymptotic properties

    International Nuclear Information System (INIS)

    By means of a combined use of the type Ia supernovae and H(z) data tests, together with the study of the asymptotic properties in the equivalent phase space — through the use of the dynamical systems tools — we demonstrate that the bulk viscous matter-dominated scenario is not a good model to explain the accepted cosmological paradigm, at least, under the parametrization of bulk viscosity considered in this paper. The main objection against such scenarios is the absence of conventional radiation and matter-dominated critical points in the phase space of the model. This entails that radiation and matter dominance are not generic solutions of the cosmological equations, so that these stages can be implemented only by means of unique and very specific initial conditions, i. e., of very unstable particular solutions. Such a behavior is in marked contradiction with the accepted cosmological paradigm which requires of an earlier stage dominated by relativistic species, followed by a period of conventional non-relativistic matter domination, during which the cosmic structure we see was formed. Also, we found that the bulk viscosity is positive just until very late times in the cosmic evolution, around z < 1. For earlier epochs it is negative, been in tension with the local second law of thermodynamics

  10. Module 13: Bulk Packaging Shipments by Highway

    International Nuclear Information System (INIS)

    The Hazardous Materials Modular Training Program provides participating United States Department of Energy (DOE) sites with a basic, yet comprehensive, hazardous materials transportation training program for use onsite. This program may be used to assist individual program entities to satisfy the general awareness, safety training, and function specific training requirements addressed in Code of Federal Regulation (CFR), Title 49, Part 172, Subpart H -- ''Training.'' Module 13 -- Bulk Packaging Shipments by Highway is a supplement to the Basic Hazardous Materials Workshop. Module 13 -- Bulk Packaging Shipments by Highway focuses on bulk shipments of hazardous materials by highway mode, which have additional or unique requirements beyond those addressed in the ten module core program. Attendance in this course of instruction should be limited to those individuals with work experience in transporting hazardous materials utilizing bulk packagings and who have completed the Basic Hazardous Materials Workshop or an equivalent. Participants will become familiar with the rules and regulations governing the transportation by highway of hazardous materials in bulk packagings and will demonstrate the application of these requirements through work projects and examination

  11. Observation of multiple flux quantum periodicities in V-Φ curves of single bulk bridge of Y-Ba-Cu-O superconductor

    International Nuclear Information System (INIS)

    This paper discusses a single bulk bridge carved out of a superconducting pellet of YBa2Cu3O7-x made by usual solid state reaction. The I-V curves show large maximum pair current followed by a quasi-particle tunneling regime. In spite of having single bridge geometry, application of external magnetic field leads to periodicites in V-φ curves at 77 K and at lower temperatures. The periodic behavior is akin to dc AQUID characteristics. The shape of individual lobes show large asymmetries indicating presence of parallel superconducting micro networks with several array of junctions with differing critical currents. The individual arm of this network further consists of small superconducting loops. The individual loop itself has been formed of a series of identical granular Josephson weaklings. This network imparts dc SQUID character to the bulk bridge. The proposed model is explained with the help of diagrams. Large periods correspond to large networks with large inductance, while small superposed oscillations pertain to smaller loops with extremely low inductance. This explains occurrence of V-φ curves with assorted flux periods equivalent to some integral multiple of flux quantum (φ0)

  12. Bulk compositions of the moon and earth, estimated from meteorites

    Science.gov (United States)

    Ganapathy, R.; Anders, E.

    1974-01-01

    The present work calculates the bulk compositions of the earth and moon, based on the assumption that these planets formed by the same processes as chondrites. In terms of the model presented, the earth contains 9.2% early condensate and 1.5% carbonaceous, volatile-rich silicate. For the moon these percentages are 30.1 and 0.04, respectively. When lunar and terrestrial basalt data are normalized to these model compositions, element abundance patterns based on the percentages (assuming that each component carried its cosmic complement of trace elements) demonstrate the essential identity of igneous processes on both celestial bodies.

  13. Applications and modelling of bulk HTSs in brushless ac machines

    International Nuclear Information System (INIS)

    The use of high temperature superconducting material in its bulk form for engineering applications is attractive due to the large power densities that can be achieved. In brushless electrical machines, there are essentially four properties that can be exploited; their hysteretic nature, their flux shielding properties, their ability to trap large flux densities and their ability to produce levitation. These properties translate to hysteresis machines, reluctance machines, trapped-field synchronous machines and linear motors respectively. Each one of these machines is addressed separately and computer simulations that reveal the current and field distributions within the machines are used to explain their operation. (author)

  14. Soliton interaction in quadratic and cubic bulk media

    DEFF Research Database (Denmark)

    Johansen, Steffen Kjær; Bang, Ole

    2000-01-01

    Summary form only given. The understanding of how and to what extend the cubic nonlinearity affects beam propagation and spatial soliton formation in quadratic media is of vital importance in fundamental and applied nonlinear physics. We consider beam propagation under type-I SHG conditions in...... lossless bulk second order nonlinear optical materials with a nonvanishing third order nonlinearity. It is known that in pure second order systems a single soliton can never collapse whereas in systems with both nonlinearities and that stable single soliton propagation can only in some circumstances be...

  15. Degree of Conversion and BisGMA, TEGDMA, UDMA Elution from Flowable Bulk Fill Composites

    Directory of Open Access Journals (Sweden)

    Edina Lempel

    2016-05-01

    Full Text Available The degree of conversion (DC and the released bisphenol A diglycidyl ether dimethacrylate (BisGMA, triethylene glycol dimethacrylate (TEGDMA and urethane dimethacrylate (UDMA monomers of bulk-fill composites compared to that of conventional flowable ones were assessed using micro-Raman spectroscopy and high performance liquid chromatography (HPLC. Four millimeter-thick samples were prepared from SureFil SDR Flow (SDR, X-tra Base (XB, Filtek Bulk Fill (FBF and two and four millimeter samples from Filtek Ultimate Flow (FUF. They were measured with micro-Raman spectroscopy to determine the DC% of the top and the bottom surfaces. The amount of released monomers in 75% ethanol extraction media was measured with HPLC. The differences between the top and bottom DC% were significant for each material. The mean DC values were in the following order for the bottom surfaces: SDR_4mm_20s > FUF_2mm_20s > XB_4mm_20s > FBF_4mm_20s > XB_4mm_10s > FBF_4mm_10s > FUF_4mm_20s. The highest rate in the amount of released BisGMA and TEGDMA was found from the 4 mm-thick conventional flowable FUF. Among bulk-fills, FBF showed a twenty times higher amount of eluted UDMA and twice more BisGMA; meanwhile, SDR released a significantly higher amount of TEGDMA. SDR bulk-fill showed significantly higher DC%; meanwhile XB, FBF did not reach the same level DC, as that of the 2 mm-thick conventional composite at the bottom surface. Conventional flowable composites showed a higher rate of monomer elution compared to the bulk-fills, except FBF, which showed a high amount of UDMA release.

  16. Degree of Conversion and BisGMA, TEGDMA, UDMA Elution from Flowable Bulk Fill Composites

    Science.gov (United States)

    Lempel, Edina; Czibulya, Zsuzsanna; Kovács, Bálint; Szalma, József; Tóth, Ákos; Kunsági-Máté, Sándor; Varga, Zoltán; Böddi, Katalin

    2016-01-01

    The degree of conversion (DC) and the released bisphenol A diglycidyl ether dimethacrylate (BisGMA), triethylene glycol dimethacrylate (TEGDMA) and urethane dimethacrylate (UDMA) monomers of bulk-fill composites compared to that of conventional flowable ones were assessed using micro-Raman spectroscopy and high performance liquid chromatography (HPLC). Four millimeter-thick samples were prepared from SureFil SDR Flow (SDR), X-tra Base (XB), Filtek Bulk Fill (FBF) and two and four millimeter samples from Filtek Ultimate Flow (FUF). They were measured with micro-Raman spectroscopy to determine the DC% of the top and the bottom surfaces. The amount of released monomers in 75% ethanol extraction media was measured with HPLC. The differences between the top and bottom DC% were significant for each material. The mean DC values were in the following order for the bottom surfaces: SDR_4mm_20s > FUF_2mm_20s > XB_4mm_20s > FBF_4mm_20s > XB_4mm_10s > FBF_4mm_10s > FUF_4mm_20s. The highest rate in the amount of released BisGMA and TEGDMA was found from the 4 mm-thick conventional flowable FUF. Among bulk-fills, FBF showed a twenty times higher amount of eluted UDMA and twice more BisGMA; meanwhile, SDR released a significantly higher amount of TEGDMA. SDR bulk-fill showed significantly higher DC%; meanwhile XB, FBF did not reach the same level DC, as that of the 2 mm-thick conventional composite at the bottom surface. Conventional flowable composites showed a higher rate of monomer elution compared to the bulk-fills, except FBF, which showed a high amount of UDMA release. PMID:27213361

  17. Bulk Laser Material Modification: Towards a Kerfless Laser Wafering Process

    Science.gov (United States)

    LeBeau, James

    Due to the ever increasing relevance of finer machining control as well as necessary reduction in material waste by large area semiconductor device manufacturers, a novel bulk laser machining method was investigated. Because the cost of silicon and sapphire substrates are limiting to the reduction in cost of devices in both the light emitting diode (LED) and solar industries, and the present substrate wafering process results in >50% waste, the need for an improved ingot wafering technique exists. The focus of this work is the design and understanding of a novel semiconductor wafering technique that utilizes the nonlinear absorption properties of band-gapped materials to achieve bulk (subsurface) morphological changes in matter using highly focused laser light. A method and tool was designed and developed to form controlled damage regions in the bulk of a crystalline sapphire wafer leaving the surfaces unaltered. The controllability of the subsurface damage geometry was investigated, and the effect of numerical aperture of the focusing optic, energy per pulse, wavelength, and number of pulses was characterized for a nanosecond pulse length variable wavelength Nd:YAG OPO laser. A novel model was developed to describe the geometry of laser induced morphological changes in the bulk of semiconducting materials for nanosecond pulse lengths. The beam propagation aspect of the model was based on ray-optics, and the full Keldysh multiphoton photoionization theory in conjuncture with Thornber's and Drude's models for impact ionization were used to describe high fluence laser light absorption and carrier generation ultimately resulting in permanent material modification though strong electron-plasma absorption and plasma melting. Although the electron-plasma description of laser damage formation is usually reserved for extremely short laser pulses (precision stage control.

  18. A diphoton resonance from bulk RS

    Science.gov (United States)

    Csáki, Csaba; Randall, Lisa

    2016-07-01

    Recent LHC data hinted at a 750 GeV mass resonance that decays into two photons. A significant feature of this resonance is that its decays to any other Standard Model particles would be too low to be detected so far. Such a state has a compelling explanation in terms of a scalar or a pseudoscalar that is strongly coupled to vector states charged under the Standard Model gauge groups. Such a scenario is readily accommodated in bulk RS with a scalar localized in the bulk away from but close to the Higgs. Turning this around, we argue that a good way to find the elusive bulk RS model might be the search for a resonance with prominent couplings to gauge bosons.

  19. Orchestrating Bulk Data Movement in Grid Environments

    Energy Technology Data Exchange (ETDEWEB)

    Vazhkudai, SS

    2005-01-25

    Data Grids provide a convenient environment for researchers to manage and access massively distributed bulk data by addressing several system and transfer challenges inherent to these environments. This work addresses issues involved in the efficient selection and access of replicated data in Grid environments in the context of the Globus Toolkit{trademark}, building middleware that (1) selects datasets in highly replicated environments, enabling efficient scheduling of data transfer requests; (2) predicts transfer times of bulk wide-area data transfers using extensive statistical analysis; and (3) co-allocates bulk data transfer requests, enabling parallel downloads from mirrored sites. These efforts have demonstrated a decentralized data scheduling architecture, a set of forecasting tools that predict bandwidth availability within 15% error and co-allocation architecture, and heuristics that expedites data downloads by up to 2 times.

  20. Bulk Comptonization by Turbulence in Accretion Disks

    CERN Document Server

    Kaufman, J

    2016-01-01

    Radiation pressure dominated accretion discs around compact objects may have turbulent velocities that greatly exceed the electron thermal velocities within the disc. Bulk Comptonization by the turbulence may therefore dominate over thermal Comptonization in determining the emergent spectrum. Bulk Comptonization by divergenceless turbulence is due to radiation viscous dissipation only. It can be treated as thermal Comptonization by solving the Kompaneets equation with an equivalent "wave" temperature, which is a weighted sum over the power present at each scale in the turbulent cascade. Bulk Comptonization by turbulence with non-zero divergence is due to both pressure work and radiation viscous dissipation. Pressure work has negligible effect on photon spectra in the limit of optically thin turbulence, and in this limit radiation viscous dissipation alone can be treated as thermal Comptonization with a temperature equivalent to the full turbulent power. In the limit of extremely optically thick turbulence, ra...

  1. Synthesis of Bulk Superconducting Magnesium Diboride

    Directory of Open Access Journals (Sweden)

    Margie Olbinado

    2002-06-01

    Full Text Available Bulk polycrystalline superconducting magnesium diboride, MgB2, samples were successfully prepared via a one-step sintering program at 750°C, in pre Argon with a pressure of 1atm. Both electrical resistivity and magnetic susceptibility measurements confirmed the superconductivity of the material at 39K, with a transition width of 5K. The polycrystalline nature, granular morphology, and composition of the sintered bulk material were confirmed using X-ray diffractometry (XRD, scanning electron microscopy (SEM, and energy dispersive X-ray analysis (EDX.

  2. Thermal relics in cosmology with bulk viscosity

    International Nuclear Information System (INIS)

    In this paper we discuss some consequences of cosmological models in which the primordial cosmic matter is described by a relativistic imperfect fluid. The latter takes into account the dissipative effects (bulk viscosity) arising from different cooling rates of the fluid components in the expanding Universe. We discuss, in particular, the effects of the bulk viscosity on Big Bang Nucleosynthesis and on the thermal relic abundance of particles, looking at recent results of PAMELA experiment. The latter has determined an anomalous excess of positron events, which cannot be explained by conventional cosmology and particle physics. (orig.)

  3. Remedial investigations for quarry bulk wastes

    International Nuclear Information System (INIS)

    The US Department of Energy proposes, as a separate operable unit of the Weldon Spring Site Remedial Action Project, to remove contaminated bulk wastes from the Weldon Spring quarry and transport them approximately four miles to the chemical plant portion of the raffinate pits and chemical plant area. The wastes will be held in temporary storage prior to the record of decision for the overall remedial action. The decision on the ultimate disposal of these bulk wastes will be included as part of the decision for management of the waste materials resulting from remedial action activities at the raffinate pits and chemical plant area. 86 refs., 71 figs., 83 tabs

  4. Radiation-hardened bulk CMOS technology

    International Nuclear Information System (INIS)

    The evolutionary development of a radiation-hardened bulk CMOS technology is reviewed. The metal gate hardened CMOS status is summarized, including both radiation and reliability data. The development of a radiation-hardened bulk silicon gate process which was successfully implemented to a commercial microprocessor family and applied to a new, radiation-hardened, LSI standard cell family is also discussed. The cell family is reviewed and preliminary characterization data is presented. Finally, a brief comparison of the various radiation-hardened technologies with regard to performance, reliability, and availability is made

  5. Thermal relics in cosmology with bulk viscosity

    Energy Technology Data Exchange (ETDEWEB)

    Iorio, A. [Charles University in Prague, Faculty of Mathematics and Physics, Prague (Czech Republic); Lambiase, G. [Universita di Salerno, Dipartimento di Fisica E.R. Caianiello, Fisciano (Italy); INFN, Gruppo Collegato di Salerno, Fisciano (Italy)

    2015-03-01

    In this paper we discuss some consequences of cosmological models in which the primordial cosmic matter is described by a relativistic imperfect fluid. The latter takes into account the dissipative effects (bulk viscosity) arising from different cooling rates of the fluid components in the expanding Universe. We discuss, in particular, the effects of the bulk viscosity on Big Bang Nucleosynthesis and on the thermal relic abundance of particles, looking at recent results of PAMELA experiment. The latter has determined an anomalous excess of positron events, which cannot be explained by conventional cosmology and particle physics. (orig.)

  6. Bulk Entropy in Loop Quantum Gravity

    OpenAIRE

    Livine, Etera R; Terno, Daniel R.

    2007-01-01

    In the framework of loop quantum gravity (LQG), having quantum black holes in mind, we generalize the previous boundary state counting (gr-qc/0508085) to a full bulk state counting. After a suitable gauge fixing we are able to compute the bulk entropy of a bounded region (the "black hole") with fixed boundary. This allows us to study the relationship between the entropy and the boundary area in details and we identify a holographic regime of LQG where the leading order of the entropy scales w...

  7. Bulk Entropy in Loop Quantum Gravity

    CERN Document Server

    Livine, Etera R

    2007-01-01

    In the framework of loop quantum gravity (LQG), having quantum black holes in mind, we generalize the previous boundary state counting (gr-qc/0508085) to a full bulk state counting. After a suitable gauge fixing we are able to compute the bulk entropy of a bounded region (the "black hole") with fixed boundary. This allows us to study the relationship between the entropy and the boundary area in details and we identify a holographic regime of LQG where the leading order of the entropy scales with the area. We show that in this regime we can fine tune the factor between entropy and area without changing the Immirzi parameter.

  8. An analytical model for force prediction in ball nose micro milling of inclined surfaces

    DEFF Research Database (Denmark)

    Bissacco, Giuliano; Hansen, Hans Nørgaard; De Chiffre, Leonardo

    2010-01-01

    Ball nose micro milling is a key process for the generation of free form surfaces and inclined surfaces often present in mould inserts for micro replication. This paper presents a new cutting force model for ball nose micro milling that is capable of taking into account the effect of the edge...

  9. Micro Gas Turbine – A Review

    OpenAIRE

    Tushar Shukla

    2013-01-01

    Turbomachines is a class of machines which comprise of turbines and compressors. These machines are widely used for power generation, aircraft propulsion and in a wide range of heavy and medium industries. When we scale down these large turbines, we get micro turbines, which are compact and miniaturized form of these large turbines. The process of scaling down a turbine is not as simple as it looks like, it is a very tedious job and researches are going on in this area. These micro gas turbin...

  10. Cold atoms in videotape micro-traps

    Science.gov (United States)

    Sinclair, C. D. J.; Retter, J. A.; Curtis, E. A.; Hall, B. V.; Llorente Garcia, I.; Eriksson, S.; Sauer, B. E.; Hinds, E. A.

    2005-08-01

    We describe an array of microscopic atom traps formed by a pattern of magnetisation on a piece of videotape. We describe the way in which cold atoms are loaded into one of these micro-traps and how the trapped atom cloud is used to explore the properties of the trap. Evaporative cooling in the micro-trap down to a temperature of 1~μK allows us to probe the smoothness of the trapping potential and reveals some inhomogeneity produced by the magnetic film. We discuss future prospects for atom chips based on microscopic permanent-magnet structures.

  11. Cold atoms in videotape micro-traps

    CERN Document Server

    Sinclair, C D J; Curtis, E A; Hall, B V; Garcia, I L; Eriksson, S; Sauer, B E; Hinds, E A

    2005-01-01

    We describe an array of microscopic atom traps formed by a pattern of magnetisation on a piece of videotape. We describe the way in which cold atoms are loaded into one of these micro-traps and how the trapped atom cloud is used to explore the properties of the trap. Evaporative cooling in the micro-trap down to a temperature of 1 microkelvin allows us to probe the smoothness of the trapping potential and reveals some inhomogeneity produced by the magnetic film. We discuss future prospects for atom chips based on microscopic permanent-magnet structures.

  12. A Micro Cylindrical Ion Trap (5-CIT) Micro Mass Spectrometer Instrument System (5MSIS) for NASA Planetary Exploration Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The project aims to develop a miniature packaging platform for the integration of MEMS mass spectrometer components to form the basis of a Micro Mass Spectrometer...

  13. A new approach to integrate PLZT thin films with micro-cantilevers

    Indian Academy of Sciences (India)

    Ravindra Singh; T C Goel; Sudhir Chandra

    2009-08-01

    In the present work, we report the preparation of PLZT thin films in pure perovskite phase by RF magnetron sputtering without external substrate heating and their integration with micro-cantilevers. The ‘lift-off’ process for patterning different layers of a micro-cantilever including PLZT, Pt/Ti and Au/Cr was employed. The basic requirement of lift-off process is that the deposition temperature should not exceed 200°C otherwise photoresist will burn out. Therefore, one of the aims of the present work was to prepare PLZT film at lower deposition temperatures, which can be subsequently annealed to form pure perovskite phase. This also strongly favours the incorporation of ‘lift-off’ process for patterning in the complete process flow. As no external substrate heating was required in the deposition of PLZT film, this objective has been successfully accomplished in the present work. The ‘lift-off’ process has been successfully adopted for patterning the composite layers of PLZT/Pt/Ti and Au/Cr using thick positive photo-resist (STR-1045). Different types of cantilever beams incorporating PLZT films have been successfully fabricated using ‘lift-off’ process and bulk micromachining technology. The proposed process can be advantageously applied for the fabrication of various MEMS devices.

  14. Three-dimensional fabrication of metallic micro/nanostructures by two-photon polymerization for metamaterials

    Science.gov (United States)

    Formanek, Florian; Takeyasu, Nobuyuki; Tanaka, Takuo; Chiyoda, Kenta; Ishikawa, Atsushi; Kawata, Satoshi

    2006-08-01

    We report on selective metal deposition over complex polymer structures formed by two-photon induced photopolymerization (TPP) technique. Periodic three-dimensional (3D) polymer micro/nanostructures are fabricated by means of a microlens array to produce multiple spots from a single-beam femtosecond laser amplified by a regenerative amplifier. The photopolymerizable resin and the glass substrate are chemically modified, and a pre-treatment with SnCl2 is applied before realizing a uniform silver coating by electroless plating. This preparation enables a selective deposition of small silver particles only on the polymer surface all over the sample and to avoid metal deposition on the substrate. Electrical measurements show the structures to be highly conductive with typical resistivities ρ approx. 10 -7 Ωm, only a few times larger than the value for bulk silver. By taking advantage of the high accuracy and arbitrary shape modeling of TPP fabrication, we can realize complex periodic and/or metallic micro-nanostructures which were so far out of reach. Thus, a straightforward application could be the realization of metamaterials. The processing efficiency of our technique is demonstrated with the fabrication of several large samples, created by more than 700 objects written in parallel and metallized with silver.

  15. THE OPTIMIZATION OF PLUSH YARNS BULKING PROCESS

    Directory of Open Access Journals (Sweden)

    VINEREANU Adam

    2014-05-01

    Full Text Available This paper presents the experiments that were conducted on the installation of continuous bulking and thermofixing “SUPERBA” type TVP-2S for optimization of the plush yarns bulking process. There were considered plush yarns Nm 6.5/2, made of the fibrous blend of 50% indigenous wool sort 41 and 50% PES. In the first stage, it performs a thermal treatment with a turboprevaporizer at a temperature lower than thermofixing temperature, at atmospheric pressure, such that the plush yarns - deposed in a freely state on a belt conveyor - are uniformly bulking and contracting. It was followed the mathematical modeling procedure, working with a factorial program, rotatable central composite type, and two independent variables. After analyzing the parameters that have a direct influence on the bulking degree, there were selected the pre-vaporization temperature (coded x1,oC and the velocity of belt inside pre-vaporizer (coded x 2, m/min. As for the dependent variable, it was chosen the plush yarn diameter (coded y, mm. There were found the coordinates of the optimal point, and then this pair of values was verified in practice. These coordinates are: x1optim= 90oC and x 2optim= 6.5 m/min. The conclusion is that the goal was accomplished: it was obtained a good cover degree f or double-plush carpets by reducing the number of tufts per unit surface.

  16. Determining the bulk strength of strata

    International Nuclear Information System (INIS)

    The bulk rock strength of strata is determined by logging a bore-hole with an instrument to obtain a neutron-neutron log of the hole and determining in conjunction with the lithology of the strata the strength by applying an inverse relation formula. (author)

  17. Realistic anomaly mediation with bulk gauge fields

    International Nuclear Information System (INIS)

    We present a simple general framework for realistic models of supersymmetry breaking driven by anomaly mediation. We consider a 5-dimensional 'brane universe' where the visible and hidden sectors are localized on different branes, and the standard model gauge bosons propagate in the bulk. In this framework there can be charged scalar messengers that have contact interactions with the hidden sector, either localized in the hidden sector or in the bulk. These scalars obtain soft masses that feed into visible sector scalar masses at two loop order via bulk gauge interactions. This contribution is automatically flavor-blind, and can be naturally positive. If the messengers are in the bulk this contribution is automatically the same order of magnitude as the anomaly mediated contribution, independent of the brane spacing. If the messengers are localized to a brane the two effects are of the same order for relatively small brane spacings. The gaugino masses and A terms are determined completely by anomaly mediation. In order for anomaly mediation to dominate over radion mediation the radion must be is stabilized in a manner that preserves supersymmetry, with supergravity effects included. We show that this occurs in simple models. We also show that the mu problem can be solved by the vacuum expectation value of a singlet in this framework. (author)

  18. Crevice chemistry estimation from bulk water chemistry

    International Nuclear Information System (INIS)

    Since the first PWR plant in Japan started commercial operation in 1970, 22 plants are running in Japan as of the end of 1994. The main purpose of secondary water chemistry control is to minimize the corrosion possibility of the secondary system equipment, especially steam generators (SG). To achieve this objective, much effort has been concentrated on improving secondary water chemistry control. As a result of this effort, the recent secondary water chemistry in Japanese plants is well maintained in every stage of operation. However, to ensure and improve the reliability of SG, it is necessary to control crevice environments, which are located at tube/tube support plate intersections and under the sludge pile on the tube sheet. According to recent crevice monitoring examination results, the concentration behavior impurities in SG bulk water at the crevice is different for each species, and SG bulk water and crevice chemical compositions are not always equal. From these results, to control the crevice chemistry, improving bulk water chemistry control methods and a new type of molar ratio control index is needed. This paper introduces a brief summary of a recent crevice chemistry evaluation technique and bulk water chemistry control method, which is employed for crevice chemistry control, based on crevice monitoring examination results

  19. A Stereoscopic Look into the Bulk

    CERN Document Server

    Czech, Bartlomiej; McCandlish, Samuel; Mosk, Benjamin; Sully, James

    2016-01-01

    We present the foundation for a holographic dictionary with depth perception. The dictionary consists of natural CFT operators whose duals are simple, diffeomorphism-invariant bulk operators. The CFT operators of interest are the "OPE blocks," contributions to the OPE from a single conformal family. In holographic theories, we show that the OPE blocks are dual at leading order in 1/N to integrals of effective bulk fields along geodesics or homogeneous minimal surfaces in anti-de Sitter space. One widely studied example of an OPE block is the modular Hamiltonian, which is dual to the fluctuation in the area of a minimal surface. Thus, our operators pave the way for generalizing the Ryu-Takayanagi relation to other bulk fields. Although the OPE blocks are non-local operators in the CFT, they admit a simple geometric description as fields in kinematic space--the space of pairs of CFT points. We develop the tools for constructing local bulk operators in terms of these non-local objects. The OPE blocks also allow ...

  20. Teaching Advanced SQL Skills: Text Bulk Loading

    Science.gov (United States)

    Olsen, David; Hauser, Karina

    2007-01-01

    Studies show that advanced database skills are important for students to be prepared for today's highly competitive job market. A common task for database administrators is to insert a large amount of data into a database. This paper illustrates how an up-to-date, advanced database topic, namely bulk insert, can be incorporated into a database…

  1. Longitudinal bulk a coustic mass sensor

    DEFF Research Database (Denmark)

    Hales, Jan Harry; Teva, Jordi; Boisen, Anja;

    2009-01-01

    Design, fabrication and characterization, in terms of mass sensitivity, is presented for a polycrystalline silicon longitudinal bulk acoustic cantilever. The device is operated in air at 51 MHz, resulting in a mass sensitivity of 100 HZ/fg (1 fg = 10{su−15 g). The initial characterization is cond...

  2. New Development in the Preparation of Micro/Nano-Wires of Molecular (Magnetic) Conductors

    OpenAIRE

    Lydie Valade; Hisashi Tanaka; Dominique de Caro; Toyonari Sugimoto

    2010-01-01

    A lot of molecular (magnetic) conductors are prepared largely using charge-transfer (CT) salts of donor molecules with acceptor molecules or nonmagnetic or magnetic anions such as metal halides and oxides; their CT salts are usually obtained as bulk crystals, which are used to elucidate the electrical conducting (magnetic) properties. In contrast, a small number of micro/nano-crystals of the molecular (magnetic) conductors, especially micro/nano-wires, are known, of which highly conducting na...

  3. Bulk sulfur (S) deposition in China

    Science.gov (United States)

    Liu, Lei; Zhang, Xiuying; Wang, Shanqian; Zhang, Wuting; Lu, Xuehe

    2016-06-01

    A systematic dataset of an observation network on a national scale has been organized to investigate the spatial distribution of bulk sulfur (S) deposition (Sdep) throughout China during 2000-2013, representing by far the most detailed data set to track the bulk sulfur deposition throughout China since 2000. Such a dataset is needed for ecosystem studies and for developing emission control policies. Bulk Sdep values showed great variations, ranging from 2.17 to 70.55 kg ha-1 y-1, with an average of 22.99 kg ha-1 y-1. The average rate of bulk Sdep located in East Coastal region (35.97 kg ha-1 y-1), Middle Yangtze region (57.90 kg ha-1 y-1), Middle Yellow River region (23.42 kg ha-1 y-1), North Coastal region (42.19 kg ha-1 y-1), Northeast region (34.28 kg ha-1 y-1), South Coastal region (36.97 kg S ha-1 y-1), Southwest region (33.85 kg ha-1 y-1) was 4.50, 7.24, 2.93, 5.28, 4.29, 4.63 and 4.24 times than that in Northwest region (7.99 kg ha-1 y-1). Bulk Sdep over China was mainly from fossil fuel combustion (76.96%), biomass burning (7.64%), crust (6.22%), aged sea salt (5.48%) and agriculture (3.68%). A systematic observation network on a national scale should be established to conduct a long-term monitoring atmospheric Sdep (including wet and dry deposition), based on exiting ecological stations administrated by different departments in China.

  4. Digestibility and bulking effect of ispaghula husks in healthy humans.

    Science.gov (United States)

    Marteau, P; Flourié, B; Cherbut, C; Corrèze, J L; Pellier, P; Seylaz, J; Rambaud, J C

    1994-12-01

    The digestibility of ispaghula, a mucilage from Plantago ovata composed mainly of arabinoxylans, and its faecal bulking effect were studied in seven healthy volunteers who ingested a low fibre controlled diet plus either placebo or 18 g/day of ispaghula for two 15 day periods. Whole gut transit time and gas excretion in breath and flatus were not different during the periods of ispaghula and placebo ingestion. Faecal wet and dry weights rose significantly, however, during ispaghula ingestion. Faecal short chain fatty acid concentrations and the molar proportions of propionic and acetic acids also increased. Most of the ispaghula had reached the caecum four hours after ingestion in an intact highly polymerised form. During ispaghula ingestion, the increase in the faecal output of neutral sugars was accounted for by the faecal excretion of arabinose and xylose in an intact highly polymerised form; the apparent digestibilities of these sugars were 24 (11) and 53% (6) respectively (mean (SEM)). In conclusion, ispaghula is more resistant to fermentation than previously reported in humans, and its bulking effect largely results from intact material. PMID:7829013

  5. 27 CFR 1.90 - Distilled spirits in bulk.

    Science.gov (United States)

    2010-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Distilled spirits in bulk..., NONINDUSTRIAL USE OF DISTILLED SPIRITS AND WINE, BULK SALES AND BOTTLING OF DISTILLED SPIRITS Bulk Sales and Bottling of Distilled Spirits Warehouse Receipts § 1.90 Distilled spirits in bulk. By the terms of the...

  6. Bulk and surface sensitivities of surface plasmon waveguides

    International Nuclear Information System (INIS)

    Kretschmann-Raether) configuration, despite the fact that they are at opposite ends of the confinement-attenuation trade-off. Preferred wavelengths for surface sensing were found to be near the short wavelength edge of the Drude region, where detection limits of about 0.1 pg mm-2 are predicted. With regard to bulk sensing, only the IMI offers an improvement over the single interface. The results are collected in a form that should be useful for investigating other sensor architectures implemented with these waveguides or variants thereof.

  7. Sustainable Micro-Manufacturing of Micro-Components via Micro Electrical Discharge Machining

    OpenAIRE

    Valeria Marrocco; Giacomo Copani; Irene Fassi; Francesco Modica

    2011-01-01

    Micro-manufacturing emerged in the last years as a new engineering area with the potential of increasing peoples’ quality of life through the production of innovative micro-devices to be used, for example, in the biomedical, micro-electronics or telecommunication sectors. The possibility to decrease the energy consumption makes the micro-manufacturing extremely appealing in terms of environmental protection. However, despite this common belief that the micro-scale implies a higher sustainab...

  8. Form Matters

    OpenAIRE

    Hedegaard Larsen, Morten

    2010-01-01

    This thesis investigates the reasons for our (in the Western World) preference for shopping (for food) in supermarkets? What social and performative historical developments might explain this preference? And what are the consequences of this preference? Historical descriptions of the performativity of the food market from the first Agora’s to the supermarkets of the 21st century as well as from theatre’s and Western performance spaces will form the comparative analytical basis, together wi...

  9. Bulk solitary waves in elastic solids

    Science.gov (United States)

    Samsonov, A. M.; Dreiden, G. V.; Semenova, I. V.; Shvartz, A. G.

    2015-10-01

    A short and object oriented conspectus of bulk solitary wave theory, numerical simulations and real experiments in condensed matter is given. Upon a brief description of the soliton history and development we focus on bulk solitary waves of strain, also known as waves of density and, sometimes, as elastic and/or acoustic solitons. We consider the problem of nonlinear bulk wave generation and detection in basic structural elements, rods, plates and shells, that are exhaustively studied and widely used in physics and engineering. However, it is mostly valid for linear elasticity, whereas dynamic nonlinear theory of these elements is still far from being completed. In order to show how the nonlinear waves can be used in various applications, we studied the solitary elastic wave propagation along lengthy wave guides, and remarkably small attenuation of elastic solitons was proven in physical experiments. Both theory and generation for strain soliton in a shell, however, remained unsolved problems until recently, and we consider in more details the nonlinear bulk wave propagation in a shell. We studied an axially symmetric deformation of an infinite nonlinearly elastic cylindrical shell without torsion. The problem for bulk longitudinal waves is shown to be reducible to the one equation, if a relation between transversal displacement and the longitudinal strain is found. It is found that both the 1+1D and even the 1+2D problems for long travelling waves in nonlinear solids can be reduced to the Weierstrass equation for elliptic functions, which provide the solitary wave solutions as appropriate limits. We show that the accuracy in the boundary conditions on free lateral surfaces is of crucial importance for solution, derive the only equation for longitudinal nonlinear strain wave and show, that the equation has, amongst others, a bidirectional solitary wave solution, which lead us to successful physical experiments. We observed first the compression solitary wave in the

  10. Micro-spectroscopic investigation of selenium-bearing minerals from the Western US Phosphate Resource Area

    Directory of Open Access Journals (Sweden)

    Gunter Mickey E

    2005-01-01

    Full Text Available Mining activities in the US Western Phosphate Resource Area (WPRA have released Se into the environment. Selenium has several different oxidation states and species, each having varying degrees of solubility, reactivity, and bioavailability. In this study we are investigating the speciation of Se in mine-waste rocks. Selenium speciation was determined using bulk and micro-x-ray absorption spectroscopy (XAS, as well as micro-x-ray fluorescence mapping. Rocks used for bulk-XAS were ground into fine powders. Shale used for micro-XAS was broken along depositional planes to expose unweathered surfaces. The near edge region of the XAS spectra (XANES for the bulk rock samples revealed multiple oxidation states, with peaks indicative of Se(-II, Se(IV, and Se(+VI species. Micro-XANES analysis of the shale indicated that three unique Se-bearing species were present. Using the XANES data together with ab initio fitting of the extended x-ray absorption fine structure region of the micro-XAS data (micro-EXAFS the three Se-bearing species were identified as dzharkenite, a di-selenide carbon compound, and Se-substituted pyrite. Results from this research will allow for a better understanding of the biogeochemical cycling of Se in the WPRA.

  11. Dimensional Effects in Micro- and Nanostructural Changes in Grain and Intragrained Structure of Steel 45 at Static-pulse Treatment

    Directory of Open Access Journals (Sweden)

    A.V. Kirichek

    2015-12-01

    Full Text Available Conducted macro-, micro- and nanostructured materials were investigated by the influence of sample sizes of steel 45 in the form of a parallelepiped, after intense static pulse processing in plastic deformation as in the single (150 J, and pulsed (25 J impact with a frequency of 23 Hz. When all modes of processing bulk samples found structuring self-organized formation of dislocations. With a single exposure revealed as filling pearlite grains periodic dislocations (200 nm, and the formation of dislocation-free regions. When a periodic pulse treatment of the samples with transverse dimensions fold speed of propagation of elastic waves and shock waves as well as the related transport velocity of dislocations turns shockwave mechanism causing the formation of alternating strips of ferritic and pearlite walls (25 microns, wherein the pearlite wall completely or partially filled with dislocations.

  12. What governs the fluidic behavior of water near single DNA molecules at the micro/nano scale

    CERN Document Server

    Zhang, Y; Lei, X; Lv, J; Ai, X; Jun, H; Zhang, Yi; Li, Huabing; Lei, Xiaoling; Lv, Junhong; Ai, Xiaobai; Jun, Hu

    2006-01-01

    The fluidic behavior of water at the micro/nano scale is studied by using of single DNA molecules as a model system. Stable curved DNA patterns with spans about one micron were generated by using of water flows, and observed by Atomic Force Microscopy. By rigorously comparing the numerical simulation results with these patterns, it is suggested that the form of the macroscopic hydrodynamic equation still works quantitatively well on the fluid flows at the nanoscale. The molecular effects, however, are still apparent that the effective viscosity of the adjacent water is considerably larger than its bulk value. Our observation is also helpful to understand of the dynamics of biomolecules in solutions from nanoscale to microscale.

  13. Numerical modelling and comparison of MgB2 bulks fabricated by HIP and infiltration growth

    Science.gov (United States)

    Zou, J.; Ainslie, M. D.; Fujishiro, H.; Bhagurkar, A. G.; Naito, T.; Babu, N. Hari; Fagnard, J.-F.; Vanderbemden, P.; Yamamoto, A.

    2015-07-01

    MgB2 in bulk form shows great promise as trapped field magnets (TFMs) as an alternative to bulk (RE)BCO materials to replace permanent magnets in applications such as rotating machines, magnetic bearings and magnetic separation, and the relative ease of fabrication of MgB2 materials has enabled a number of different processing techniques to be developed. In this paper, a comparison is made between bulk MgB2 samples fabricated by the hot isostatic pressing (HIP), with and without Ti-doping, and infiltration growth (IG) methods and the highest trapped field in an IG-processed bulk MgB2 sample, Bz = 2.12 at 5 K and 1.66 T at 15 K, is reported. Since bulk MgB2 has a more homogeneous Jc distribution than (RE)BCO bulks, studies on such systems are made somewhat easier because simplified assumptions regarding the geometry and Jc distribution can be made, and a numerical simulation technique based on the 2D axisymmetric H-formulation is introduced to model the complete process of field cooling (FC) magnetization. As input data for the model, the measured Jc(B,T) characteristics of a single, small specimen taken from each bulk sample are used, in addition to measured specific heat and thermal conductivity data for the materials. The results of the simulation reproduce the experimental results extremely well: (1) indicating the samples have excellent homogeneity, and (2) validating the numerical model as a fast, accurate and powerful tool to investigate the trapped field profile of bulk MgB2 discs of any size accurately, under any specific operating conditions. Finally, the paper is concluded with a numerical analysis of the influence of the dimensions of the bulk sample on the trapped field.

  14. Sub-picosecond ultraviolet laser filamentation-induced bulk modifications in fused silica

    Science.gov (United States)

    Papazoglou, D. G.; Zergioti, I.; Tzortzakis, S.; Sgouros, G.; Maravelias, G.; Christopoulos, S.; Fotakis, C.

    2005-07-01

    We present experiments with sub-picosecond ultraviolet laser pulses (248 nm, 450 fs) tightly focused in the bulk of fused-silica samples. The high laser intensities attained generate plasma through multi-photon absorption and electron avalanche processes in the bulk of the material. Depending on the initial experimental conditions three distinct types of structural changes in the material are observed, from small changes of the refractive index to birefringence, and even cracks and voids. We also observe the creation of micro-channels, up to 115 μm in length, inside the material due to self-guiding and filamentation of the laser pulses in the transparent material. The selective change of the refractive index is a promising method for the fabrication of photonic structures such as waveguides and three-dimensional integrated optical devices.

  15. Tunable micro-optics

    CERN Document Server

    Duppé, Claudia

    2015-01-01

    Presenting state-of-the-art research into the dynamic field of tunable micro-optics, this is the first book to provide a comprehensive survey covering a varied range of topics including novel materials, actuation concepts and new imaging systems in optics. Internationally renowned researchers present a diverse range of chapters on cutting-edge materials, devices and subsystems, including soft matter, artificial muscles, tunable lenses and apertures, photonic crystals, and complete tunable imagers. Special contributions also provide in-depth treatment of micro-optical characterisation, scanners, and the use of natural eye models as inspiration for new concepts in advanced optics. With applications extending from medical diagnosis to fibre telecommunications, Tunable Micro-optics equips readers with a solid understanding of the broader technical context through its interdisciplinary approach to the realisation of new types of optical systems. This is an essential resource for engineers in industry and academia,...

  16. Control and understanding of the formation of micro/nanostructured metal surfaces using femtosecond laser pulses

    Science.gov (United States)

    Zuhlke, Craig A.

    An application of femtosecond lasers that has developed, in recent years, is the functionalization of surfaces. With femtosecond laser ablation micro and nano-scale features can be created in a single step without affecting the bulk material. In this dissertation micro/nanostructuring of metal surfaces, specifically nickel and SS316, was carried out using femtosecond laser pulses. By varying the fluence (between 0.01 and 3.18 J/cm2), and pulse count (between 1 and 20,000 pulses) incident on the metal surface, a number of surface morphologies were produced. It was demonstrated that a number of these morphologies can be separated in regions based on fluence and shot number. The effects of other parameters were studied in less detail, including: polarization, stationary versus rastering pulses, atmosphere during processing (processing in nitrogen and oxygen), and lens aberrations. Two morphologies from femtosecond laser ablation of metals are demonstrated for the first time: spike shaped microstructures that have peaks above the original surface, and pyramid shaped structures (with a much lower aspect ratio than commonly published morphologies) covered in thick layers of nanoparticles. Similarities and differences are shown between the commonly published relief structures, with a blunt, round top (mounds) and the protruding spikes. This work shows that the morphologies are formed through a balance between fluid flow, nanoparticle/material redeposition and preferential etching. It can be observed by watching the development of individual microstructures with increasing pulse count, what role each of these processes plays in their development. Mounds, spikes, and pyramids each have a different balance of these processes, leading to the uniqueness of each morphology. As an application of these processes, studies were completed to utilize the high surface areas of these micro/nanostructures to produce ultracapacitor electrodes. This proved to be challenging, due to the

  17. Quasi-static and dynamic deformation behaviour of Zr-based bulk metallic glass

    International Nuclear Information System (INIS)

    Nano- and micro-indentation studies were carried out to characterise a plasticity mechanism through the evolution of localised shear bands that drive material's deformation at sub-micron length scale. Initial deformation of Zr-based bulk metallic glass (BMG) was investigated with nanoindentation tests using a spherical indenter. The indentation cycle reflects an elastic deformation with the yielding load of approx. 3 mN. For designed cycling indentation, hardening and softening phenomena were observed in nano- and micro-indentations, respectively. High-precision dynamic mechanical relaxation measurements were performed using a Dynamic Mechanical Analyzer (DMA), on decreasing frequency from 160 Hz to 0.1 Hz. A mechanical response of the BMG surface to a concentrated impact load was also studied. The obtained results indicated that the studied Zr-based BMG behaved as an elastic-perfectly plastic material at macroscale with discrete plasticity events at smaller length scales

  18. Micro-Doppler analysis of multiple frequency continuous wave radar signatures

    Science.gov (United States)

    Anderson, Michael G.; Rogers, Robert L.

    2007-04-01

    Micro-Doppler refers to Doppler scattering returns produced by non rigid-body motion. Micro-Doppler gives rise to many detailed radar image features in addition to those associated with bulk target motion. Targets of different classes (for example, humans, animals, and vehicles) produce micro-Doppler images that are often distinguishable even by nonexpert observers. Micro-Doppler features have great potential for use in automatic target classification algorithms. Although the potential benefit of using micro-Doppler in classification algorithms is high, relatively little experimental (non-synthetic) micro-Doppler data exists. Much of the existing experimental data comes from highly cooperative targets (human or vehicle targets directly approaching the radar). This research involved field data collection and analysis of micro-Doppler radar signatures from non-cooperative targets. The data was collected using a low cost Xband multiple frequency continuous wave (MFCW) radar with three transmit frequencies. The collected MFCW radar signatures contain data from humans, vehicles, and animals. The presented data includes micro-Doppler signatures previously unavailable in the literature such as crawling humans and various animal species. The animal micro-Doppler signatures include deer, dog, and goat datasets. This research focuses on the analysis of micro-Doppler from noncooperative targets approaching the radar at various angles, maneuvers, and postures.

  19. 磁控溅射Ni-0.5Y微晶涂层高温氧化行为研究%High temperature oxidation behavior of magnetically sputtered Ni-0.5Y micro-crystal coating

    Institute of Scientific and Technical Information of China (English)

    靳惠明; 陈荣发; 张林楠; 刘晓军

    2003-01-01

    研究了纯镍及其表面磁控溅射Ni-0.5Y微晶涂层在1 000 ℃空气中的恒温氧化和循环氧化行为.通过扫描电镜(SEM)和透射电镜(TEM)对涂层以及表面NiO氧化膜的形貌和结构进行了研究.此外,用激光拉曼(Raman)谱对2种样品表面NiO氧化膜内应力大小进行了测量,结果表明:Ni-0.5Y微晶涂层与基体镍相比有更低的氧化增重速率, 表面NiO氧化膜的晶粒尺寸明显减小, 膜的高温塑性得以改善.同时, 氧化膜内的压应力水平也有所降低, 因而改善了NiO氧化膜的粘附性和保护性.磁控溅射涂层的微晶结构以及稀土元素钇的存在均有助于提高涂层的抗高温氧化性能.%The isothermal and cyclic oxidation behaviors of bulk pure nickel and its magnetically sputtered Ni-0.5Y micro-crystal coating were studied at 1 000 ℃ in air. Scanning electronic microscopy (SEM) and transmission electronic microscopy (TEM) were used to examine structures of the coating and the NiO oxide films. Laser Raman spectrum was also used to measure the stress level in NiO films formed on bulk nickel and the coating. It was found that Ni-0.5Y micro-crystal coating had lower oxidation rate, and the grain-size of NiO formed on Ni-0.5Y coating was also relatively smaller than that formed on bulk nickel. Meanwhile, the compressive stress level of oxide film formed on Ni-0.5Y coating was lower than that formed on bulk nickel, and the oxide film's high temperature plasticity was improved in the coating case. The improvements of anti-oxidation properties of the sputtered Ni-0.5Y coating were due to the micro-crystal structure and the rare earth element Y.

  20. Quark-hadron phase transition in DGP brane gravity with bulk scalar field

    Science.gov (United States)

    Golanbari, T.; Mohammadi, A.; Ossoulian, Z.; Saaidi, K.

    2015-06-01

    A DGP brane-world framework is picked out to study quark-hadron phase transition problem. The model also includes a bulk scalar field in agreement with string theory prediction. The work is performed using two formalisms as: smooth crossover approach and first order approach, and the results are plotted for both branches of DGP model. General behavior of temperature is the same in these two approaches and it decrease with increasing time and expanding Universe. Phase transition occurs at about micro-second after the big bang. The results show that transition time depends on brane tension value in which larger brane tension comes to earlier transition time.