WorldWideScience

Sample records for bubble column reactor

  1. Hydrodynamic models for slurry bubble column reactors

    Energy Technology Data Exchange (ETDEWEB)

    Gidaspow, D. [IIT Center, Chicago, IL (United States)

    1995-12-31

    The objective of this investigation is to convert a {open_quotes}learning gas-solid-liquid{close_quotes} fluidization model into a predictive design model. This model is capable of predicting local gas, liquid and solids hold-ups and the basic flow regimes: the uniform bubbling, the industrially practical churn-turbulent (bubble coalescence) and the slugging regimes. Current reactor models incorrectly assume that the gas and the particle hold-ups (volume fractions) are uniform in the reactor. They must be given in terms of empirical correlations determined under conditions that radically differ from reactor operation. In the proposed hydrodynamic approach these hold-ups are computed from separate phase momentum balances. Furthermore, the kinetic theory approach computes the high slurry viscosities from collisions of the catalyst particles. Thus particle rheology is not an input into the model.

  2. Engineering Development of Slurry Bubble Column Reactor (SBCR) Technology

    Energy Technology Data Exchange (ETDEWEB)

    Toseland, B.A.

    1998-10-29

    The major technical objectives of this program are threefold: (1) to develop the design tools and a fundamental understanding of the fluid dynamics of a slurry bubble column reactor to maximize reactor productivity, (2) to develop the mathematical reactor design models and gain an understanding of the hydrodynamic fundamentals under industrially relevant process conditions, and (3) to develop an understanding of the hydrodynamics and their interaction with the chemistries occurring in the bubble column reactor. Successful completion of these objectives will permit more efficient usage of the reactor column and tighter design criteria, increase overall reactor efficiency, and ensure a design that leads to stable reactor behavior when scaling up to large diameter reactors.

  3. ENGINEERING DEVELOPMENT OF SLURRY BUBBLE COLUMN REACTOR (SBCR) TECHNOLOGY

    Energy Technology Data Exchange (ETDEWEB)

    Bernard A. Toseland, Ph.D.

    2002-01-01

    The major technical objectives of this program are threefold: (1) to develop the design tools and a fundamental understanding of the fluid dynamics of a slurry bubble column reactor to maximize reactor productivity, (2) to develop the mathematical reactor design models and gain an understanding of the hydrodynamic fundamentals under industrially relevant process conditions, and (3) to develop an understanding of the hydrodynamics and their interaction with the chemistries occurring in the bubble column reactor. Successful completion of these objectives will permit more efficient usage of the reactor column and tighter design criteria, increase overall reactor efficiency, and ensure a design that leads to stable reactor behavior when scaling up to large diameter reactors.

  4. ENGINEERING DEVELOPMENT OF SLURRY BUBBLE COLUMN REACTOR (SBCR) TECHNOLOGY

    Energy Technology Data Exchange (ETDEWEB)

    Bernard A. Toseland

    2002-09-30

    The major technical objectives of this program are threefold: (1) to develop the design tools and a fundamental understanding of the fluid dynamics of a slurry bubble column reactor to maximize reactor productivity, (2) to develop the mathematical reactor design models and gain an understanding of the hydrodynamic fundamentals under industrially relevant process conditions, and (3) to develop an understanding of the hydrodynamics and their interaction with the chemistries occurring in the bubble column reactor. Successful completion of these objectives will permit more efficient usage of the reactor column and tighter design criteria, increase overall reactor efficiency, and ensure a design that leads to stable reactor behavior when scaling up to large diameter reactors.

  5. Axial and Radial Gas Holdup in Bubble Column Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Wagh, Sameer M.; Ansari, Mohashin E Alan; Kene, Pragati T. [RTMNU Nagpur, Nagpur (India)

    2014-06-15

    Bubble column reactors are considered the reactor of choice for numerous applications including oxidation, hydrogenation, waste water treatment, and Fischer-Tropsch (FT) synthesis. They are widely used in a variety of industrial applications for carrying out gas-liquid and gas-liquid-solid reactions. In this paper, the computational fluid dynamics (CFD) model is used for predicting the gas holdup and its distribution along radial and axial direction are presented. Gas holdup increases linearly with increase in gas velocity. Gas bubbles tends to concentrate more towards the center of the column and follows a wavy path.

  6. ENGINEERING DEVELOPMENT OF SLURRY BUBBLE COLUMN REACTOR (SBCR) TECHNOLOGY

    Energy Technology Data Exchange (ETDEWEB)

    Bernard A. Toseland

    2000-12-31

    The major technical objectives of this program are threefold: (1) to develop the design tools and a fundamental understanding of the fluid dynamics of a slurry bubble column reactor to maximize reactor productivity, (2) to develop the mathematical reactor design models and gain an understanding of the hydrodynamic fundamentals under industrially relevant process conditions, and (3) to develop an understanding of the hydrodynamics and their interaction with the chemistries occurring in the bubble column reactor. Successful completion of these objectives will permit more efficient usage of the reactor column and tighter design criteria, increase overall reactor efficiency, and ensure a design that leads to stable reactor behavior when scaling up to large-diameter reactors. Washington University's work during the reporting period involved the implementation of the automated calibration device, which will provide an advanced method of determining liquid and slurry velocities at high pressures. This new calibration device is intended to replace the original calibration setup, which depended on fishing lines and hooks to position the radioactive particle. The report submitted by Washington University contains a complete description of the new calibration device and its operation. Improvements to the calibration program are also discussed. Iowa State University utilized air-water bubble column simulations in an effort to determine the domain size needed to represent all of the flow scales in a gas-liquid column at a high superficial velocity. Ohio State's report summarizes conclusions drawn from the completion of gas injection phenomena studies, specifically with respect to the characteristics of bubbling-jetting at submerged single orifices in liquid-solid suspensions.

  7. An Axial Dispersion Model for Evaporating Bubble Column Reactor

    Institute of Scientific and Technical Information of China (English)

    谢刚; 李希

    2004-01-01

    Evaporating bubble column reactor (EBCR) is a kind of aerated reactor in which the reaction heat is removed by the evaporation of volatile reaction mixture. In this paper, a mathematical model that accounts for the gas-liquid exothermic reaction and axial dispersions of both gas and liquid phase is employed to study the performance of EBCR for the process of p-xylene(PX) oxidation. The computational results show that there are remarkable concentration and temperature gradients in EBCR for high ratio of height to diameter (H/DT). The temperature is lower at the bottom of column and higher at the top, due to rapid evaporation induced by the feed gas near the bottom. The concentration profiles in the gas phase are more nonuniform than those (except PX) in the liquid phase, which causes more solvent burning consumption at high H/DT ratio. For p-xylene oxidation, theo ptimal H/DT is around 5.

  8. COMPUTATIONAL AND EXPERIMENTAL MODELING OF SLURRY BUBBLE COLUMN REACTORS

    Energy Technology Data Exchange (ETDEWEB)

    Paul C.K. Lam; Isaac K. Gamwo; Dimitri Gidaspow

    2002-05-01

    The objective of this study was to develop a predictive experimentally verified computational fluid dynamics (CFD) model for gas-liquid-solid flow. A three dimensional transient computer code for the coupled Navier-Stokes equations for each phase was developed and is appended in this report. The principal input into the model is the viscosity of the particulate phase which was determined from a measurement of the random kinetic energy of the 800 micron glass beads and a Brookfield viscometer. The details are presented in the attached paper titled ''CFD Simulation of Flow and Turbulence in a Slurry Bubble Column''. This phase of the work is in press in a referred journal (AIChE Journal, 2002) and was presented at the Fourth International Conference on Multiphase Flow (ICMF 2001) in New Orleans, May 27-June 1, 2001 (Paper No. 909). The computed time averaged particle velocities and concentrations agree with Particle Image Velocimetry (PIV) measurements of velocities and concentrations, obtained using a combination of gamma-ray and X-ray densitometers, in a slurry bubble column, operated in the bubbly-coalesced fluidization regime with continuous flow of water. Both the experiment and the simulation show a down-flow of particles in the center of the column and up-flow near the walls and nearly uniform particle concentration. Normal and shear Reynolds stresses were constructed from the computed instantaneous particle velocities. The PIV measurement and the simulation produced instantaneous particle velocities. The PIV measurement and the simulation produced similar nearly flat horizontal profiles of turbulent kinetic energy of particles. To better understand turbulence we studied fluidization in a liquid-solid bed. This work was also presented at the Fourth International Conference on Multiphase Flow (ICMF 2001, Paper No. 910). To understand turbulence in risers, measurements were done in the IIT riser with 530 micron glass beads using a PIV

  9. COMPUTATIONAL AND EXPERIMENTAL MODELING OF SLURRY BUBBLE COLUMN REACTORS

    Energy Technology Data Exchange (ETDEWEB)

    Paul Lam; Dimitri Gidaspow

    2000-09-01

    The objective if this study was to develop a predictive experimentally verified computational fluid dynamics (CFD) model for gas-liquid-solid flow. A three dimensional transient computer code for the coupled Navier-Stokes equations for each phase was developed. The principal input into the model is the viscosity of the particulate phase which was determined from a measurement of the random kinetic energy of the 800 micron glass beads and a Brookfield viscometer. The computed time averaged particle velocities and concentrations agree with PIV measurements of velocities and concentrations, obtained using a combination of gamma-ray and X-ray densitometers, in a slurry bubble column, operated in the bubbly-coalesced fluidization regime with continuous flow of water. Both the experiment and the simulation show a down-flow of particles in the center of the column and up-flow near the walls and nearly uniform particle concentration. Normal and shear Reynolds stresses were constructed from the computed instantaneous particle velocities. The PIV measurement and the simulation produced instantaneous particle velocities. The PIV measurement and the simulation produced similar nearly flat horizontal profiles of turbulent kinetic energy of particles. This phase of the work was presented at the Chemical Reaction Engineering VIII: Computational Fluid Dynamics, August 6-11, 2000 in Quebec City, Canada. To understand turbulence in risers, measurements were done in the IIT riser with 530 micron glass beads using a PIV technique. The results together with simulations will be presented at the annual meeting of AIChE in November 2000.

  10. Gas-Liquid Mass Transfer in a Slurry Bubble Column Reactor under High Temperature and

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    The gas-liquid mass transfer of H2 and CO in a high temperature and high-pressure three-phase slurry bubble column reactor is studied. The gas-liquid volumetric mass transfer coefficients κLα are obtained by measuring the dissolution rate of H2 and CO. The influences of the main operation conditions, such as temperature, pressure, superficial gas velocity and solid concentration, are studied systematically. Two empirical correlations are proposed to predict κLα values for H2 and CO in liquid paraffin/solid particles slurry bubble column reactors.

  11. COMPUTATIONAL AND EXPERIMENTAL MODELING OF THREE-PHASE SLURRY-BUBBLE COLUMN REACTOR

    Energy Technology Data Exchange (ETDEWEB)

    Isaac K. Gamwo; Dimitri Gidaspow

    1999-09-01

    Considerable progress has been achieved in understanding three-phase reactors from the point of view of kinetic theory. In a paper in press for publication in Chemical Engineering Science (Wu and Gidaspow, 1999) we have obtained a complete numerical solution of bubble column reactors. In view of the complexity of the simulation a better understanding of the processes using simplified analytical solutions is required. Such analytical solutions are presented in the attached paper, Large Scale Oscillations or Gravity Waves in Risers and Bubbling Beds. This paper presents analytical solutions for bubbling frequencies and standing wave flow patterns. The flow patterns in operating slurry bubble column reactors are not optimum. They involve upflow in the center and downflow at the walls. It may be possible to control flow patterns by proper redistribution of heat exchangers in slurry bubble column reactors. We also believe that the catalyst size in operating slurry bubble column reactors is not optimum. To obtain an optimum size we are following up on the observation of George Cody of Exxon who reported a maximum granular temperature (random particle kinetic energy) for a particle size of 90 microns. The attached paper, Turbulence of Particles in a CFB and Slurry Bubble Columns Using Kinetic Theory, supports George Cody's observations. However, our explanation for the existence of the maximum in granular temperature differs from that proposed by George Cody. Further computer simulations and experiments involving measurements of granular temperature are needed to obtain a sound theoretical explanation for the possible existence of an optimum catalyst size.

  12. Modeling of a slurry bubble column reactor for Fischer-Tropsch synthesis

    Institute of Scientific and Technical Information of China (English)

    QIAN Wei-xin; MA Hong-fang; LI Tao; YING Wei-yong; FANG Ding-ye

    2012-01-01

    On the basis of the global CO consumption rate model,the lumped product distribution model and the sedimentation-dispersion model of a catalyst,a steady-state,one-dimensional mathematical model of the slurry bubble column reactor for Fischer-Tropsch synthesis were established.The mathematical simulation of the slurry bubble column reactor for Fischer-Tropsch synthesis was carried out under the following typical industrial operating conditions:temperature 230 ℃,pressure 3.0 MPa,gas flow 5× 105 m3/h,catalyst content in slurry phase 30%,reactor diameter 5.0 m and the composition of feed gas:y(H2)=0.60,y(CO)=0.30,y(N2)=0.10.The influences of operating pressure,temperature and m(H2)/m(CO) in feed gas on the reactor's reaction performance were simulated.

  13. Modeling of Bubble Column Slurry Reactor for Dimethyl Ether Synthesis from Syngas

    Institute of Scientific and Technical Information of China (English)

    张海涛; 应卫勇; 房鼎业

    2005-01-01

    A mathematical model for a bubble column slurry reactor is presented for dimethyl ether synthesis from syngas. Methanol synthesis from carbon monoxide and carbon dioxide by hydrogenation and the methanol dehydration are considered as independent reactions, in which methanol, dimethyl ether and carbon dioxide are the key components. In this model, the gas phase is considered to be in plug flow and the liquid phase to be in partly back mixing with axial distribution of solid catalyst. The simulation results show that the axial dispersion of solid catalysts, the operational height of the slurry phase in the bubble column slurry reactor, and the reaction results are influenced by the reaction temperature and pressure, which are the basic data for the scale-up of reactor.

  14. Bubble column reactor fluid dynamic study at pilot plant scale for residue and extra heavy crude oil upgrading technology

    Energy Technology Data Exchange (ETDEWEB)

    Sardella, R.; Medina, H. [Infrastructure and Upgrading Department PDVSA-Intevep (Venezuela); Zacarias, L.; Paiva, M. [Refining Department. PDVSA-Intevep (Venezuela)

    2011-07-01

    Bubble column reactors are used in several applications because of their simplicity and low cost; a new technology was developed to convert extra heavy crude oil into upgraded crude using a bubble column reactor. To design this kind of reactor, a lot of parameters like flow regime, gas hold up and dispersion coefficient have to be taken into account. This study aimed at determining the fluid dynamic behaviour of a bubble column working under Aquaconversion operating conditions. Experiments were undertaken on air-tap water and air-light oil systems under atmospheric conditions with various gas superficial velocities and liquid flowrates. Results showed that gas hold up increases with superficial gas velocity but is independent of liquid flowrate and that both systems tested work at the same flow regimes. This paper showed that under the experimental conditions used, this reactor tends to be a complete mixing reactor.

  15. Performance of a slurry bubble column reactor for Fischer-Tropsch synthesis: Determination of optimum condition

    Energy Technology Data Exchange (ETDEWEB)

    Woo, Kwang-Jae; Kang, Suk-Hwan; Kim, Seung-Moon; Bae, Jong-Wook; Jun, Ki-Won [Advanced Chemical Technology Division, Korea Research Institute of Chemical Technology (KRICT), P.O. Box 107, Yuseong, Daejeon 305-600 (Korea)

    2010-04-15

    The CO conversion and selectivity to C{sub 1}+ and C{sub 11}+ wax products over Co/Al{sub 2}O{sub 3} as well as Ru/Co/Al{sub 2}O{sub 3} Fischer-Tropsch (F-T)catalysts were investigated by varying reaction temperature (210-250 C), system pressure (1.0-3.0 MPa), GHSV (1000-6000 L/kg/h), superficial gas velocity (1.7-13.6 cm/s) and slurry concentration (9.09-26.67 wt.%) in a slurry bubble column reactor (0.05 m diameter x 1.5 m height) to determine the optimum operating conditions. Squalane or paraffin wax was used as initial liquid media. The overall CO conversion increased with increasing reaction temperature, system pressure and catalyst concentration. However, the local maximum CO conversion was exhibited at GHSV of 1500-2000 L/kg/h and superficial gas velocity of 3.4-5.0 cm/s. The CO conversion in the case of Ru/Co/Al{sub 2}O{sub 3} was much higher and stable than that in the case of Co/Al{sub 2}O{sub 3}. The selectivity to C{sub 11}+ wax products increased slightly with increasing GHSV; on the other hand, it decreased with increasing reaction temperature, system pressure, and solid concentration in a slurry bubble column reactor. It could be concluded that the optimum operating conditions based on the yield of hydrocarbons and wax products were; U{sub G} 6.8-10 cm/s, Cs = 15 wt.%, T = 220-230 C, P = 2.0 MPa in a slurry bubble column reactor for F-T synthesis. (author)

  16. Flow patterns in a slurry-bubble-column reactor under reaction conditions

    Energy Technology Data Exchange (ETDEWEB)

    Toselane, B.A.; Brown, D.M.; Zou, B.S.; Dudukovic, M.P. [Washington Univ., St. Louis, MO (United States)

    1995-12-31

    The gas and liquid radioactive tracer response curves obtained in an industrial bubble column reactor of height to diameter ratio of 10 are analyzed and the suitability of the axial dispersion model for interpretation of the results is discussed. The relationship between the tracer concentration distribution and measured detector response of the soluble gas tracer (Ar-41) is possibly dominated by the dissolved gas. The one dimensional axial dispersion model cannot match all the experimental observations well and the flow pattern of the undissolved gas cannot be determined with certainty.

  17. ADVANCED DIAGNOSTIC TECHNIQUES FOR THREE-PHASE SLURRY BUBBLE COLUMN REACTORS(SBCR)

    Energy Technology Data Exchange (ETDEWEB)

    M.H. Al-Dahhan; L.S. Fan; M.P. Dudukovic

    2002-07-25

    This report summarizes the accomplishment made during the third year of this cooperative research effort between Washington University, Ohio State University and Air Products and Chemicals. Data processing of the performed Computer Automated Radioactive Particle Tracking (CARPT) experiments in 6 inch column using air-water-glass beads (150 {micro}m) system has been completed. Experimental investigation of time averaged three phases distribution in air-Therminol LT-glass beads (150 {micro}m) system in 6 inch column has been executed. Data processing and analysis of all the performed Computed Tomography (CT) experiments have been completed, using the newly proposed CT/Overall gas holdup methodology. The hydrodynamics of air-Norpar 15-glass beads (150 {micro}m) have been investigated in 2 inch slurry bubble column using Dynamic Gas Disengagement (DGD), Pressure Drop fluctuations, and Fiber Optic Probe. To improve the design and scale-up of bubble column reactors, a correlation for overall gas holdup has been proposed based on Artificial Neural Network and Dimensional Analysis.

  18. Slurry bubble column hydrodynamics

    Science.gov (United States)

    Rados, Novica

    Slurry bubble column reactors are presently used for a wide range of reactions in both chemical and biochemical industry. The successful design and scale up of slurry bubble column reactors require a complete understanding of multiphase fluid dynamics, i.e. phase mixing, heat and mass transport characteristics. The primary objective of this thesis is to improve presently limited understanding of the gas-liquid-solid slurry bubble column hydrodynamics. The effect of superficial gas velocity (8 to 45 cm/s), pressure (0.1 to 1.0 MPa) and solids loading (20 and 35 wt.%) on the time-averaged solids velocity and turbulent parameter profiles has been studied using Computer Automated Radioactive Particle Tracking (CARPT). To accomplish this, CARPT technique has been significantly improved for the measurements in highly attenuating systems, such as high pressure, high solids loading stainless steel slurry bubble column. At a similar set of operational conditions time-averaged gas and solids holdup profiles have been evaluated using the developed Computed Tomography (CT)/Overall gas holdup procedure. This procedure is based on the combination of the CT scans and the overall gas holdup measurements. The procedure assumes constant solids loading in the radial direction and axially invariant cross-sectionally averaged gas holdup. The obtained experimental holdup, velocity and turbulent parameters data are correlated and compared with the existing low superficial gas velocities and atmospheric pressure CARPT/CT gas-liquid and gas-liquid-solid slurry data. The obtained solids axial velocity radial profiles are compared with the predictions of the one dimensional (1-D) liquid/slurry recirculation phenomenological model. The obtained solids loading axial profiles are compared with the predictions of the Sedimentation and Dispersion Model (SDM). The overall gas holdup values, gas holdup radial profiles, solids loading axial profiles, solids axial velocity radial profiles and solids

  19. Precipitation of CuS and ZnS in a bubble column reactor

    NARCIS (Netherlands)

    Al-Tarazi, M.; Heesink, A. Bert M.; Versteeg, G. F.; Azzam, M. O. J.; Azzam, K.

    2005-01-01

    This work presents an experimental study into the precipitation of CuS and ZnS in a semibatch-wise operated bubble column. First the applied bubble column was characterized with respect to mass transfer phenomena. The influences of ionic strength and superficial gas velocity on volumetric mass trans

  20. Gas-Liquid Mass Transfer in a Slurry Bubble Column Reactor under High Temperature andHigh Pressure

    Institute of Scientific and Technical Information of China (English)

    杨卫国; 王金福; 金涌

    2001-01-01

    The gas-liquid mass transfer of H2 and CO in a high temperature and high-pressure three-phase slurry bubble column reactor is studied. The gas-liquid volumetric mass transfer coefficients kLa are obtained by measuring the dissolution rate of H2 and CO. The influences of the main operation conditions, such as temperature, pressure,superficial gas velocity and solid concentration, are studied systematically. Two empirical correlations are proposed to predict kLa values for H2 and CO in liquid paraffln/solid particles slurry bubble column reactors.

  1. PROGRESS TOWARDS MODELING OF FISCHER TROPSCH SYNTHESIS IN A SLURRY BUBBLE COLUMN REACTOR

    Energy Technology Data Exchange (ETDEWEB)

    Donna Post Guillen; Tami Grimmett; Anastasia M. Gandrik; Steven P. Antal

    2010-11-01

    The Hybrid Energy Systems Testing (HYTEST) Laboratory is being established at the Idaho National Laboratory to develop and test hybrid energy systems with the principal objective to safeguard U.S. Energy Security by reducing dependence on foreign petroleum. A central component of the HYTEST is the slurry bubble column reactor (SBCR) in which the gas-to-liquid reactions will be performed to synthesize transportation fuels using the Fischer Tropsch (FT) process. SBCRs are cylindrical vessels in which gaseous reactants (for example, synthesis gas or syngas) is sparged into a slurry of liquid reaction products and finely dispersed catalyst particles. The catalyst particles are suspended in the slurry by the rising gas bubbles and serve to promote the chemical reaction that converts syngas to a spectrum of longer chain hydrocarbon products, which can be upgraded to gasoline, diesel or jet fuel. These SBCRs operate in the churn-turbulent flow regime which is characterized by complex hydrodynamics, coupled with reacting flow chemistry and heat transfer, that effect reactor performance. The purpose of this work is to develop a computational multiphase fluid dynamic (CMFD) model to aid in understanding the physico-chemical processes occurring in the SBCR. Our team is developing a robust methodology to couple reaction kinetics and mass transfer into a four-field model (consisting of the bulk liquid, small bubbles, large bubbles and solid catalyst particles) that includes twelve species: (1) CO reactant, (2) H2 reactant, (3) hydrocarbon product, and (4) H2O product in small bubbles, large bubbles, and the bulk fluid. Properties of the hydrocarbon product were specified by vapor liquid equilibrium calculations. The absorption and kinetic models, specifically changes in species concentrations, have been incorporated into the mass continuity equation. The reaction rate is determined based on the macrokinetic model for a cobalt catalyst developed by Yates and Satterfield [1]. The

  2. Ozonation kinetics of winery wastewater in a pilot-scale bubble column reactor.

    Science.gov (United States)

    Lucas, Marco S; Peres, José A; Lan, Bing Yan; Li Puma, Gianluca

    2009-04-01

    The degradation of organic substances present in winery wastewater was studied in a pilot-scale, bubble column ozonation reactor. A steady reduction of chemical oxygen demand (COD) was observed under the action of ozone at the natural pH of the wastewater (pH 4). At alkaline and neutral pH the degradation rate was accelerated by the formation of radical species from the decomposition of ozone. Furthermore, the reaction of hydrogen peroxide (formed from natural organic matter in the wastewater) and ozone enhances the oxidation capacity of the ozonation process. The monitoring of pH, redox potential (ORP), UV absorbance (254 nm), polyphenol content and ozone consumption was correlated with the oxidation of the organic species in the water. The ozonation of winery wastewater in the bubble column was analysed in terms of a mole balance coupled with ozonation kinetics modeled by the two-film theory of mass transfer and chemical reaction. It was determined that the ozonation reaction can develop both in and across different kinetic regimes: fast, moderate and slow, depending on the experimental conditions. The dynamic change of the rate coefficient estimated by the model was correlated with changes in the water composition and oxidant species.

  3. Effect of hydrodynamics on kinetics of gluconic acid enzymatic production in bubble column reactor

    Directory of Open Access Journals (Sweden)

    Ramezani Mohammad

    2013-01-01

    Full Text Available Oxidation of glucose by homogeneous glucose oxidase was performed in rectangular bubble column reactor at 40°C, ambient pressure and pH of 5.5 while superficial gas (oxygen velocity was varied in the homogeneous and transition regime in the range of 0.0014 - 0.0112 m s-1. Effect of superficial gas (oxygen velocity on the apparent reaction rate and its parameters was determined and it was observed that the apparent reaction rate on the basis of volume of the liquid increased with increasing the superficial gas (oxygen velocity. The apparent reaction rate was assumed to be in the form of Michaelis-Menten equation and its apparent kinetic parameters were evaluated by the nonlinear regression method.

  4. Hydrodynamic models for slurry bubble column reactors. Seventh technical progress report, January--March 1996

    Energy Technology Data Exchange (ETDEWEB)

    Gidaspow, D.

    1996-04-01

    The objective of this investigation is to convert our ``learning gas solid-liquid`` fluidization model into a predictive design model. The IIT hydrodynamic model computes the phase velocities and the volume fractions of gas, liquid and particulate phase. Model verification involves a comparison of these computed velocities and volume fractions to experimental values. A hydrodynamic model for multiphase flows, based on the principles of mass, momentum and energy conservation for each phase, was developed and applied to model gas-liquid, gas-liquid-solid fluidization and gas-solid-solid separation. To simulate the industrial slurry bubble column reactors, a computer program based on the hydrodynamic model was written with modules for chemical reactions (e.g. the synthesis of methanol), phase changes and heat exchangers. In the simulations of gas-liquid two phases flow system, the gas hold-ups, computed with a variety of operating conditions such as temperature, pressure, gas and liquid velocities, agree well with the measurements obtained at Air Products` pilot plant. The hydrodynamic model has more flexible features than the previous empirical correlations in predicting the gas hold-up of gas-liquid two-phase flow systems. In the simulations of gas-liquid-solid bubble column reactors with and without slurry circulation, the code computes volume fractions, temperatures and velocity distributions for the gas, the liquid and the solid phases, as well as concentration distributions for the species (CO, H{sub 2}, CH{sub 3}0H, ... ), after startup from a certain initial state. A kinetic theory approach is used to compute a solid viscosity due to particle collisions. Solid motion and gas-liquid-solid mixing are observed on a color PCSHOW movie made from computed time series data. The steady state and time average catalyst concentration profiles, the slurry height and the rates of methanol production agree well with the measurements obtained at an Air Products` pilot plant.

  5. Non-catalytic alcoholysis process for production of biodiesel fuel by using bubble column reactor

    Science.gov (United States)

    Hagiwara, S.; Nabetani, H.; Nakajima, M.

    2015-04-01

    -edible lipids by use of the SMV reactor has not been examined yet. Therefore, this study aims to investigate the productivity of biodiesel produced from waste vegetable oils using the SMV reactor. Biodiesel fuel is a replacement for diesel as a fuel produced from biomass resources. It is generally produced as a FAME derived from vegetable oil by using alkaline catalyzed alcoholysis process. This alkaline method requires deacidification process prior to the reaction process and the alkaline catalyst removal process after the reaction. Those process increases the total cost of biodiesel fuel production. In order to solve the problems in the conventional alkaline catalyzed alcoholysis process, the authors proposed a non-catalytic alcoholysis process called the Superheated Methanol Vapor (SMV) method with bubble column reactor. So, this study aims to investigate the productivity of biodiesel produced from vegetable oils and other lipids using the SMV method with bubble column reactor.

  6. Design of slurry bubble column reactors: novel technique for optimum catalyst size selection contractual origin of the invention

    Science.gov (United States)

    Gamwo, Isaac K.; Gidaspow, Dimitri; Jung, Jonghwun

    2009-11-17

    A method for determining optimum catalyst particle size for a gas-solid, liquid-solid, or gas-liquid-solid fluidized bed reactor such as a slurry bubble column reactor (SBCR) for converting synthesis gas into liquid fuels considers the complete granular temperature balance based on the kinetic theory of granular flow, the effect of a volumetric mass transfer coefficient between the liquid and the gas, and the water gas shift reaction. The granular temperature of the catalyst particles representing the kinetic energy of the catalyst particles is measured and the volumetric mass transfer coefficient between the gas and liquid phases is calculated using the granular temperature. Catalyst particle size is varied from 20 .mu.m to 120 .mu.m and a maximum mass transfer coefficient corresponding to optimum liquid hydrocarbon fuel production is determined. Optimum catalyst particle size for maximum methanol production in a SBCR was determined to be in the range of 60-70 .mu.m.

  7. Modeling of mass transfer characteristics of bubble column reactor with surfactant present

    Institute of Scientific and Technical Information of China (English)

    赵伟荣; 史惠祥; 汪大翚

    2004-01-01

    Danckwert's method was used to determine the specific interfacial area, a, and the individual mass transfer coefficient, kL, during absorption of CO2 in a bubble column with an anionic surfactant in the carbonate-bicarbonate buffer solution and NaAsO2 as catalyst, the presence of which decreases the specific interfacial area and the individual mass transfer coefficient. The specific interfacial area and the individual mass transfer coefficient increase with increasing superficial gas velocity. The specific interfacial area decreases whereas the individual mass transfer coefficient increases with increasing temperature. The results of experiments were used to determine the dependence of a, kL, and kLa on the surface tension, the temperature of the absorption phase, and the superficial velocity of the gas. The calculated results from the correlation were found to be within 10% deviation from the actual experimental results.

  8. Modeling of mass transfer characteristics of bubble column reactor with surfactant present

    Institute of Scientific and Technical Information of China (English)

    赵伟荣; 史惠祥; 汪大翚

    2004-01-01

    Danckwert's method was used to determine the specific interfacial area, a, and the individual mass transfer coefficient, κL, during absorption of CO2 in a bubble column with an anionic surfactant in the carbonate-bicarbonate buffer solution and NaAsO2 as catalyst, the presence of which decreases the specific interracial area and the individual mass transfer coefficient. The specific interfacial area and the individual mass transfer coefficient increase with increasing superficial gas velocity. The specific interfacial area decreases whereas the individual mass transfer coefficient increases with increasing temperature. The results of experiments were used to determine the dependence of a, κL, and κLa on the surface tension, the temperature of the absorption phase, and the superficial velocity of the gas. The calculated results from the correlation were found to be within 10% deviation from the actual experimental results.

  9. Mathematical Simulation and Design of Three-Phase Bubble Column Reactor for Direct Synthesis of Dimethyl Ether from Syngas

    Institute of Scientific and Technical Information of China (English)

    Dianhua Liu; Xing Hua; Dingye Fang

    2007-01-01

    A three-phase reactor mathematical model was set up to simulate and design a three-phase bubble column reactor for direct synthesis of dimethyl ether (DME) from syngas, considering both the influence of part inert carrier backmixing on transfer and the influence of catalyst grain sedimentation on reaction. On the basis of this model, the influences of the size and reaction conditions of a 100000 t/a DME reactor on capacity were investigated. The optimized size of the 10000 t/a DME synthesis reactor was proposed as follows: diameter 3.2 m, height 20 m, built-in 400 tube heat exchanger (φ 38×2 mm),and inert heat carrier paraffin oil 68 t and catalyst 34.46 t. Reaction temperature and pressure were important factors influencing the reaction conversion for different size reactors. Under the condition of uniform catalyst concentration distribution, higher pressure and temperature were proposed to achieve a higher production capacity of DME. The best ratio of fresh syngas for DME synthesis was 2.04.

  10. DEVELOPMENT OF A COMPUTATIONAL MULTIPHASE FLOW MODEL FOR FISCHER TROPSCH SYNTHESIS IN A SLURRY BUBBLE COLUMN REACTOR

    Energy Technology Data Exchange (ETDEWEB)

    Donna Post Guillen; Tami Grimmett; Anastasia M. Gribik; Steven P. Antal

    2010-09-01

    The Hybrid Energy Systems Testing (HYTEST) Laboratory is being established at the Idaho National Laboratory to develop and test hybrid energy systems with the principal objective to safeguard U.S. Energy Security by reducing dependence on foreign petroleum. A central component of the HYTEST is the slurry bubble column reactor (SBCR) in which the gas-to-liquid reactions will be performed to synthesize transportation fuels using the Fischer Tropsch (FT) process. SBCRs are cylindrical vessels in which gaseous reactants (for example, synthesis gas or syngas) is sparged into a slurry of liquid reaction products and finely dispersed catalyst particles. The catalyst particles are suspended in the slurry by the rising gas bubbles and serve to promote the chemical reaction that converts syngas to a spectrum of longer chain hydrocarbon products, which can be upgraded to gasoline, diesel or jet fuel. These SBCRs operate in the churn-turbulent flow regime which is characterized by complex hydrodynamics, coupled with reacting flow chemistry and heat transfer, that effect reactor performance. The purpose of this work is to develop a computational multiphase fluid dynamic (CMFD) model to aid in understanding the physico-chemical processes occurring in the SBCR. Our team is developing a robust methodology to couple reaction kinetics and mass transfer into a four-field model (consisting of the bulk liquid, small bubbles, large bubbles and solid catalyst particles) that includes twelve species: (1) CO reactant, (2) H2 reactant, (3) hydrocarbon product, and (4) H2O product in small bubbles, large bubbles, and the bulk fluid. Properties of the hydrocarbon product were specified by vapor liquid equilibrium calculations. The absorption and kinetic models, specifically changes in species concentrations, have been incorporated into the mass continuity equation. The reaction rate is determined based on the macrokinetic model for a cobalt catalyst developed by Yates and Satterfield [1]. The

  11. Incorporation of Reaction Kinetics into a Multiphase, Hydrodynamic Model of a Fischer Tropsch Slurry Bubble Column Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Donna Guillen, PhD; Anastasia Gribik; Daniel Ginosar, PhD; Steven P. Antal, PhD

    2008-11-01

    This paper describes the development of a computational multiphase fluid dynamics (CMFD) model of the Fischer Tropsch (FT) process in a Slurry Bubble Column Reactor (SBCR). The CMFD model is fundamentally based which allows it to be applied to different industrial processes and reactor geometries. The NPHASE CMFD solver [1] is used as the robust computational platform. Results from the CMFD model include gas distribution, species concentration profiles, and local temperatures within the SBCR. This type of model can provide valuable information for process design, operations and troubleshooting of FT plants. An ensemble-averaged, turbulent, multi-fluid solution algorithm for the multiphase, reacting flow with heat transfer was employed. Mechanistic models applicable to churn turbulent flow have been developed to provide a fundamentally based closure set for the equations. In this four-field model formulation, two of the fields are used to track the gas phase (i.e., small spherical and large slug/cap bubbles), and the other two fields are used for the liquid and catalyst particles. Reaction kinetics for a cobalt catalyst is based upon values reported in the published literature. An initial, reaction kinetics model has been developed and exercised to demonstrate viability of the overall solution scheme. The model will continue to be developed with improved physics added in stages.

  12. A new efficient empirical correlation for filtrate flux in slurry bubble column reactor of a gas-to-liquid process

    Energy Technology Data Exchange (ETDEWEB)

    Hemmati, Mohammad Reza [Entekhab Petrochemical Co., Tehran (Iran, Islamic Republic of); Khodagholi, Mohammad Ali [Research Institute of Petroleum Industry, Tehran (Iran, Islamic Republic of)

    2015-12-15

    Gas to Liquid has recently become of great interest. In this technology slurry bubble column reactors are favored for many reasons. Separation of liquid wax from the slurry is still a major problem that may be done by internal or external filtration. A system of sintered metal candle filters are designed and operated to collect experimental data of internal filtration. Data for 4 and 8 micron filter elements with different pressure differences and kinematic viscosity were collected. Data analysis revealed that these data could be correlated as a simple function of time, pressure drop and kinematic viscosity. This new and efficient correlation shows excellent ability to reproduce original data at moderate filtration conditions, but it is less precious in severe conditions. It was understood that main reason for this behavior is different filtrate flux regimes through filter media pores, led to inability of a single correlation to fit both regimes properly.

  13. Bioleaching of chalcopyrite concentrate using Leptospirillum ferriphilum, Acidithiobacillus ferrooxidans and Acidithiobacillus thiooxidans in a continuous bubble column reactor.

    Science.gov (United States)

    Xia, Lexian; Yin, Chu; Dai, Songlin; Qiu, Guanzhou; Chen, Xinhua; Liu, Jianshe

    2010-03-01

    To estimate the bioleaching performance of chalcopyrite for various hydraulic residence times (HRTs), laboratory-scale bioleaching of chalcopyrite concentrate was carried out in a continuous bubble column reactor with three different HRTs of 120, 80 and 40 h, respectively. An extraction rate and ratio of 0.578 g Cu l(-1) h(-1) and 39.7%, respectively, were achieved for an HRT of 80 h at a solids concentration of 10% (w/v). Lower bioleaching performances than this were obtained for a longer HRT of 120 h and a shorter HRT of 40 h. In addition, there was obvious competition between Leptospirillum ferriphilum and Acidithiobacillus ferrooxidans to oxidize ferrous iron, causing large compositional differences between the microbial communities obtained for the different HRTs. Leptospirillum ferriphilum and Acidithiobacillus thiooxidans were found to be the dominant microbes for the longer HRT (120 h). Acidithiobacillus ferrooxidans became the dominant species when the HRT was decreased. The proportion of Acidithiobacillus thiooxidans was comparatively constant in the microbial community throughout the three process stages.

  14. Regeneration of barium carbonate from barium sulphide in a pilot-scale bubbling column reactor and utilization for acid mine drainage.

    Science.gov (United States)

    Mulopo, J; Zvimba, J N; Swanepoel, H; Bologo, L T; Maree, J

    2012-01-01

    Batch regeneration of barium carbonate (BaCO(3)) from barium sulphide (BaS) slurries by passing CO(2) gas into a pilot-scale bubbling column reactor under ambient conditions was used to assess the technical feasibility of BaCO(3) recovery in the Alkali Barium Calcium (ABC) desalination process and its use for sulphate removal from high sulphate Acid Mine Drainage (AMD). The effect of key process parameters, such as BaS slurry concentration and CO(2) flow rate on the carbonation, as well as the extent of sulphate removal from AMD using the recovered BaCO(3) were investigated. It was observed that the carbonation reaction rate for BaCO(3) regeneration in a bubbling column reactor significantly increased with increase in carbon dioxide (CO(2)) flow rate whereas the BaS slurry content within the range 5-10% slurry content did not significantly affect the carbonation rate. The CO(2) flow rate also had an impact on the BaCO(3) morphology. The BaCO(3) recovered from the pilot-scale bubbling column reactor demonstrated effective sulphate removal ability during AMD treatment compared with commercial BaCO(3).

  15. Hydrodynamic models for slurry bubble column reactors. Fourth technical progress report

    Energy Technology Data Exchange (ETDEWEB)

    Gidaspow, D.

    1995-07-01

    The objective of this investigation is to convert our ``learning gas-solid-liquid`` fluidization model into a predictive design model. The IIT hydrodynamic model computes the phase velocities and volume fractions of gas, liquid and particulate phases. Model verification involves a comparison of these computed velocities and volume fractions to experimental values. The simulation of Air Product methanol reactors described in this paper are continuing. Granular temperatures and viscosities have been computed. Preliminary measurements of granular temperatures using the Air Product catalysts were obtained using our CCD camera.

  16. Catalytic Wet Air Oxidation of Oxalic Acid using Platinum Catalysts in Bubble Column Reactor: A Review

    Directory of Open Access Journals (Sweden)

    A. K. Saroha

    2010-01-01

    Full Text Available Wastewater treatment and re-use of industrial process water are critical issue for the development of human activities andenvironment conservation. Catalytic wet air oxidation (CWAO is an attractive and useful technique for treatment of effluentswhere the concentrations of organic pollutants are too low, for the incineration and other pollution control techniquesto be economically feasible and when biological treatments are ineffective, e.g. in the case of toxic effluents. In CWAO,combustion takes place on a Pt/Al2O3 catalysts usually at temperatures several degrees below those required forthermal incineration. In CWAO process, the organic contaminants dissolved in water are either partially degraded by meansof an oxidizing agent into biodegradable intermediates or mineralized into innocuous inorganic compounds such as CO2,H2O and inorganic salts, which remain in the aqueous phase. In contrast to other thermal processes CWAO produces no NOx,SO2, HCl, dioxins, furans, fly ash, etc. This review paper presents the application of platinum catalysts in bubble columnreactor for CWAO of oxalic acid.

  17. An Axial Dispersion Model for Evaporating Bubble Column Reactor%蒸发鼓泡塔反应器的轴向分散模型

    Institute of Scientific and Technical Information of China (English)

    谢刚; 李希

    2004-01-01

    Evaporating bubble column reactor (EBCR) is a kind of aerated reactor in which the reaction heat is removed by the evaporation of volatile reaction mixture. In this paper, a mathematical model that accounts for the gas-liquid exothermic reaction and axial dispersions of both gas and liquid phase is employed to study the performance of EBCR for the process of p-xylene(PX) oxidation. The computational results show that there are remarkable concentration and temperature gradients in EBCR for high ratio of height to diameter (H/DT). The temperature is lower at the bottom of column and higher at the top, due to rapid evaporation induced by the feed gas near the bottom. The concentration profiles in the gas phase are more nonuniform than those (except PX) in the liquid phase, which causes more solvent burning consumption at high H/DT ratio. For p-xylene oxidation, the optimal H/DT is around 5.

  18. REVIEW OF EXPERIMENTAL CAPABILITIES AND HYDRODYNAMIC DATA FOR VALIDATION OF CFD BASED PREDICTIONS FOR SLURRY BUBBLE COLUMN REACTORS

    Energy Technology Data Exchange (ETDEWEB)

    Donna Post Guillen; Daniel S. Wendt

    2007-11-01

    The purpose of this paper is to document the review of several open-literature sources of both experimental capabilities and published hydrodynamic data to aid in the validation of a Computational Fluid Dynamics (CFD) based model of a slurry bubble column (SBC). The review included searching the Web of Science, ISI Proceedings, and Inspec databases, internet searches as well as other open literature sources. The goal of this study was to identify available experimental facilities and relevant data. Integral (i.e., pertaining to the SBC system), as well as fundamental (i.e., separate effects are considered), data are included in the scope of this effort. The fundamental data is needed to validate the individual mechanistic models or closure laws used in a Computational Multiphase Fluid Dynamics (CMFD) simulation of a SBC. The fundamental data is generally focused on simple geometries (i.e., flow between parallel plates or cylindrical pipes) or custom-designed tests to focus on selected interfacial phenomena. Integral data covers the operation of a SBC as a system with coupled effects. This work highlights selected experimental capabilities and data for the purpose of SBC model validation, and is not meant to be an exhaustive summary.

  19. REVIEW OF EXPERIMENTAL CAPABILITIES AND HYDRODYNAMIC DATA FOR VALIDATION OF CFD-BASED PREDICTIONS FOR SLURRY BUBBLE COLUMN REACTORS

    Energy Technology Data Exchange (ETDEWEB)

    Donna Post Guillen; Daniel S. Wendt; Steven P. Antal; Michael Z. Podowski

    2007-11-01

    The purpose of this paper is to document the review of several open-literature sources of both experimental capabilities and published hydrodynamic data to aid in the validation of a Computational Fluid Dynamics (CFD) based model of a slurry bubble column (SBC). The review included searching the Web of Science, ISI Proceedings, and Inspec databases, internet searches as well as other open literature sources. The goal of this study was to identify available experimental facilities and relevant data. Integral (i.e., pertaining to the SBC system), as well as fundamental (i.e., separate effects are considered), data are included in the scope of this effort. The fundamental data is needed to validate the individual mechanistic models or closure laws used in a Computational Multiphase Fluid Dynamics (CMFD) simulation of a SBC. The fundamental data is generally focused on simple geometries (i.e., flow between parallel plates or cylindrical pipes) or custom-designed tests to focus on selected interfacial phenomena. Integral data covers the operation of a SBC as a system with coupled effects. This work highlights selected experimental capabilities and data for the purpose of SBC model validation, and is not meant to be an exhaustive summary.

  20. Bubble Size Distribution in a Vibrating Bubble Column

    Science.gov (United States)

    Mohagheghian, Shahrouz; Wilson, Trevor; Valenzuela, Bret; Hinds, Tyler; Moseni, Kevin; Elbing, Brian

    2016-11-01

    While vibrating bubble columns have increased the mass transfer between phases, a universal scaling law remains elusive. Attempts to predict mass transfer rates in large industrial scale applications by extrapolating laboratory scale models have failed. In a stationary bubble column, mass transfer is a function of phase interfacial area (PIA), while PIA is determined based on the bubble size distribution (BSD). On the other hand, BSD is influenced by the injection characteristics and liquid phase dynamics and properties. Vibration modifies the BSD by impacting the gas and gas-liquid dynamics. This work uses a vibrating cylindrical bubble column to investigate the effect of gas injection and vibration characteristics on the BSD. The bubble column has a 10 cm diameter and was filled with water to a depth of 90 cm above the tip of the orifice tube injector. BSD was measured using high-speed imaging to determine the projected area of individual bubbles, which the nominal bubble diameter was then calculated assuming spherical bubbles. The BSD dependence on the distance from the injector, injector design (1.6 and 0.8 mm ID), air flow rates (0.5 to 5 lit/min), and vibration conditions (stationary and vibration conditions varying amplitude and frequency) will be presented. In addition to mean data, higher order statistics will also be provided.

  1. KINETIC MODELING OF A FISCHER-TROPSCH REACTION OVER A COBALT CATALYST IN A SLURRY BUBBLE COLUMN REACTOR FOR INCORPORATION INTO A COMPUTATIONAL MULTIPHASE FLUID DYNAMICS MODEL

    Energy Technology Data Exchange (ETDEWEB)

    Anastasia Gribik; Doona Guillen, PhD; Daniel Ginosar, PhD

    2008-09-01

    Currently multi-tubular fixed bed reactors, fluidized bed reactors, and slurry bubble column reactors (SBCRs) are used in commercial Fischer Tropsch (FT) synthesis. There are a number of advantages of the SBCR compared to fixed and fluidized bed reactors. The main advantage of the SBCR is that temperature control and heat recovery are more easily achieved. The SBCR is a multiphase chemical reactor where a synthesis gas, comprised mainly of H2 and CO, is bubbled through a liquid hydrocarbon wax containing solid catalyst particles to produce specialty chemicals, lubricants, or fuels. The FT synthesis reaction is the polymerization of methylene groups [-(CH2)-] forming mainly linear alkanes and alkenes, ranging from methane to high molecular weight waxes. The Idaho National Laboratory is developing a computational multiphase fluid dynamics (CMFD) model of the FT process in a SBCR. This paper discusses the incorporation of absorption and reaction kinetics into the current hydrodynamic model. A phased approach for incorporation of the reaction kinetics into a CMFD model is presented here. Initially, a simple kinetic model is coupled to the hydrodynamic model, with increasing levels of complexity added in stages. The first phase of the model includes incorporation of the absorption of gas species from both large and small bubbles into the bulk liquid phase. The driving force for the gas across the gas liquid interface into the bulk liquid is dependent upon the interfacial gas concentration in both small and large bubbles. However, because it is difficult to measure the concentration at the gas-liquid interface, coefficients for convective mass transfer have been developed for the overall driving force between the bulk concentrations in the gas and liquid phases. It is assumed that there are no temperature effects from mass transfer of the gas phases to the bulk liquid phase, since there are only small amounts of dissolved gas in the liquid phase. The product from the

  2. Modeling of Bubble Column Slurry Reactor for Dimethyl Ether Synthesis from Syngas%合成气制二甲醚三相淤浆床反应器的数学模型研究

    Institute of Scientific and Technical Information of China (English)

    张海涛; 应卫勇; 房鼎业

    2005-01-01

    A mathematical model for a bubble column slurry reactor is presented for dimethyl ether synthesis from syngas. Methanol synthesis from carbon monoxide and carbon dioxide by hydrogenation and the methanol dehydration are considered as independent reactions, in which methanol, dimethyl ether and carbon dioxide are the key components. In this model, the gas phase is considered to be in plug flow and the liquid phase to be in partly back mixing with axial distribution of solid catalyst. The simulation results show that the axial dispersion of solid catalysts, the operational height of the slurry phase in the bubble column slurry reactor, and the reaction results are influenced by the reaction temperature and pressure, which are the basic data for the scale-up of reactor.

  3. Production of Diacylglycerol-enriched Oil by Glycerolysis of Soybean Oil using a Bubble Column Reactor in a Solvent-free System.

    Science.gov (United States)

    Zhang, Ning; Yang, Xue; Fu, Junning; Chen, Qiong; Song, Ziliang; Wang, Yong

    2016-01-01

    In this study, diacylglycerol-enriched soybean oil (DESO) was synthesized through Lipozyme 435-catalyzed glycerolysis of soybean oil (SO) in a solvent-free system using a modified bubble column reactor. The effects of enzyme load, mole ratio of glycerol to soybean oil, reaction temperature, gas flow and reaction time on DAG production were investigated. The selected conditions were established as being enzyme load of 4 wt% (mass of substrates), glycerol/soybean oil mole ratio of 20:1, reaction temperature of 80°C, gas flow of 10.6 cm/min, and a reaction time of 2.5 h, obtaining the DAG content of 49.4±0.5 wt%. The reusability of Lipozyme 435 was evaluated by monitoring the contents of DAG, monoacylglycerol (MAG) and triacylglycerol (TAG) in 10 consecutive runs. After purified by one-step molecular distillation, the DAG content of 63.5±0.3 wt% was achieved in DESO. The mole ratio of 1, 3-DAG to 1, 2-DAG was 2:1 and the fatty acid composition had no significant difference from that of soybean oil. However, the thermal properties of DESO and SO had considerable differences. Polymorphic form of DESO were mainly the β form and minor amounts of the β' form. Granular aggregation and round-shaped crystals were detected in DESO.

  4. Multi-scale and multi-fractal analysis of pressure fluctuation in slurry bubble column bed reactor

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    The Daubechies second order wavelet was applied to decompose pressure fluctuation signals with the gas flux varying from 0.18 to 0.90 m3/h and the solid mass fraction from 0 to 20% and scales 1-9 detail signals and the 9th scale approximation signals. The pressure signals were studied by multi-scale and R/S analysis method. Hurst analysis method was applied to analyze multi-fractal characteristics of different scale signals. The results show that the characteristics of mono-fractal under scale 1 and scale 2, and bi-fractal under scale 3-9 are effective in deducing the hydrodynamics in slurry bubbling flow system. The measured pressure signals are decomposed to micro-scale signals, meso-scale signals and macro-scale signals. Micro-scale and macro-scale signals are of mono-fractal characteristics, and meso-scale signals are of bi-fractal characteristics. By analyzing energy distribution of different scale signals, it is shown that pressure fluctuations mainly reflects meso-scale interaction between the particles and the bubble.

  5. Novel techniques for slurry bubble column hydrodynamics

    Energy Technology Data Exchange (ETDEWEB)

    Dudukovic, M.P.

    1999-05-14

    The objective of this cooperative research effort between Washington University, Ohio State University and Exxon Research Engineering Company was to improve the knowledge base for scale-up and operation of slurry bubble column reactors for syngas conversion and other coal conversion processes by increased reliance on experimentally verified hydrodynamic models. During the first year (July 1, 1995--June 30, 1996) of this three year program novel experimental tools (computer aided radioactive particle tracking (CARPT), particle image velocimetry (PIV), heat probe, optical fiber probe and gamma ray tomography) were developed and tuned for measurement of pertinent hydrodynamic quantities, such as velocity field, holdup distribution, heat transfer and bubble size. The accomplishments were delineated in the First Technical Annual Report. The second year (July, 1996--June 30, 1997) was spent on further development and tuning of the novel experimental tools (e.g., development of Monte Carlo calibration for CARPT, optical probe development), building up the hydrodynamic data base using these tools and comparison of the two techniques (PIV and CARPT) for determination of liquid velocities. A phenomenological model for gas and liquid backmixing was also developed. All accomplishments were summarized in the Second Annual Technical Report. During the third and final year of the program (July 1, 1997--June 30, 1998) and during the nine months no cost extension, the high pressure facility was completed and a set of data was taken at high pressure conditions. Both PIV, CT and CARPT were used. More fundamental hydrodynamic modeling was also undertaken and model predictions were compared to data. The accomplishments for this period are summarized in this report.

  6. Bubble properties of heterogeneous bubbly flows in a square bubble column: draft

    NARCIS (Netherlands)

    Bai, Wei; Deen, Niels G.; Kuipers, J.A.M.

    2009-01-01

    The present work focuses on the measurements of bubble properties in heterogeneous bubbly flows in a square bubble column. A four-point optical fibre probe was used for this purpose. The accuracy and intrusive effect of the optical probe was investigated first. The results show that the optical prob

  7. Optimization of C/N Ratio and Inducers for Wastewater Paper Industry Treatment Using Trametes versicolor Immobilized in Bubble Column Reactor

    Directory of Open Access Journals (Sweden)

    Aura M. Pedroza-Rodríguez

    2013-01-01

    Full Text Available C/N ratio and MnSO4 and CuSO4 concentrations were optimized for decolorization and chemical oxygen demand (COD removal of bleached Kraft pulp mill effluent by Trametes versicolor immobilized in polyurethane foam. Statistical differences (P<0.0001 at high C/N ratios (169, 2 mM CuSO4, and 0.071 mM MnSO4 were determined. Decolorization of 60.5%, COD removal of 55%, laccase (LAC 60 U/L, and manganese peroxidase (MnP 8.4 U/L were obtained. Maximum of decolorization (82%, COD removal (83%, LAC (443.5 U/L, and MnP (18 U/L activities at C/N ratio of 405 (6.75 mM CuSO4 and 0.22 mM MnSO4 was achieved in step 7 at 4 d. Positive correlation between the decolorization, COD removal, and enzymatic activity was found (P<0.0001. T. versicolor bioremediation capacity was evaluated in bubble column reactor during 8 d. Effluent was adjusted according to optimized parameters and treated at 25°C and air flow of 800 mL/min. Heterotrophic bacteria growth was not inhibited by fungus. After 4 d, 82% of COD reduction and 80% decolorization were recorded. Additionally, enzymatic activity of LAC (345 U/L and MnP (78 U/L was observed. The COD reduction and decolorization correlated positively (P<0.0001 with enzymatic activity. Chlorophenol removal was 98% of pentachlorophenol (PCP, 92% of 2,4,5-trichlorophenol (2,4,5-TCP, 90% of 3,4-dichlorophenol (3,4-DCP, and 99% of 4-chlorophenols (4CP.

  8. Computational analysis of ozonation in bubble columns

    Energy Technology Data Exchange (ETDEWEB)

    Quinones-Bolanos, E. [Univ. of Guelph, School of Engineering, Guelph, Ontario (Canada)]|[Univ. de Cartagena, Facultad de Ciencias e Ingenieria, Cartagena de Indias (Colombia); Zhou, H.; Otten, L. [Univ. of Guelph, School of Engineering, Guelph, Ontario (Canada)]. E-mail: hzhou@uoguelph.ca

    2002-06-15

    This paper presents a new computational ozonation model based on the principle of computational fluid dynamics along with the kinetics of ozone decay and microbial inactivation to predict the performance of ozone disinfection in fine bubble columns. The model can be represented using a mixture two-phase flow model to simulate the hydrodynamics of the water flow and using two transport equations to track the concentration profiles of ozone and microorganisms along the height of the column, respectively. The applicability of this model was then demonstrated by comparing the simulated ozone concentrations with experimental measurements obtained from a pilot scale fine bubble column. One distinct advantage of this approach is that it does not require the prerequisite assumptions such as plug flow condition, perfect mixing, tanks-in-series, uniform radial or longitudinal dispersion in predicting the performance of disinfection contactors without carrying out expensive and tedious tracer studies. (author)

  9. The cultivation of Anabaena variabilis in a bubble column operating under bubbly and slug flows.

    Science.gov (United States)

    Yoon, Jong Hyun; Choi, Shin Sik; Park, Tai Hyun

    2012-04-01

    In a bubble column reactor with an inner diameter of 6cm and a height of 63cm for the culture of cyanobacteria two different shapes of bubbles can be generated, resulting in bubbly flow or slug flow. Growth of Anabaena variabilis under slug flow (1.9g/l/day) was 1.73 times higher than that under bubbly flow (1.1g/l/day) when the specific irradiation rate was maintained above 10μmol/s/g dry cell. Although a stepwise increase in superficial gas velocity enhanced the average cell growth rate under bubbly flow by 1.57 times, the average cell growth rate during the deceleration phase under bubbly flow (1.98g/l/day) was 0.61 times smaller than that under slug flow (3.22g/l/day). These results demonstrate that the bubble shape in the slug flow was advantageous in regards to the radial circulation of cells.

  10. Liquid-Phase Back mixing in Bubble Columns

    Directory of Open Access Journals (Sweden)

    Burhan S. Abdulrazak

    2013-05-01

    Full Text Available Liquid-phase axial dispersion coefficients have been measured for air-water system in bubble columns of 10, 15 and 30 cm diameter. The experiments are carried out using a transient method (the tracer response method.  Dispersion coefficient is obtained by adjusting the experimental profiles of tracer concentration with the predictions of the model. The experimental results show that one-dimensional axial dispersion coefficient, Dax,L, reveal strong scale dependence. Backmixing of liquid phase increases with the increase of reactor diameter and superficial gas velocity.  Axial dispersion coefficient for large column reactors can be easily predicted from the developed relation . Comparison of calculated with the experimental data and with the published data of other authors shows good agreement which ensure the reliability and confusability of the adopted correlations to be used in further design and scale-up purposes. 

  11. Fluid mixing performance of bubble column reactor enhanced by tilted porous baffle%斜插穿流式挡板强化鼓泡塔内流体混合的研究

    Institute of Scientific and Technical Information of China (English)

    刘作华; 孙瑞祥; 宁伟征; 刘仁龙; 陶长元; 王运东

    2013-01-01

    乙炔二聚反应制备乙烯基乙炔是氯丁橡胶生产等工艺中的重要操作单元,通常在全混式鼓泡塔反应器中进行.但塔内流体混合模式单一、流场对称性强、液相轴向返混较高,乙烯基乙炔容易滞留在催化剂中,并与乙炔进一步反应生成二乙烯基乙炔和高聚物.强化乙炔二聚鼓泡塔内的反应,提高乙炔单程转化率和选择性,有助于氯丁橡胶生产实现节能减排.应用FLUENT软件模拟,计算了鼓泡塔内流场结构及变化规律,发现斜插穿流式挡板可有效地调控乙炔二聚鼓泡塔内流场结构,减小漩涡尺寸,降低液相湍流流速,减小液相返混区域,强化鼓泡塔内乙炔二聚反应.%Acetylene dimerization for preparation of monovinyl-acetylene is the key process for production of neoprene, which is usually operated in a full mixed bubble column reactor. But it has disadvantages of single mixing mode, symmetric flow field structure, serious liquid axial back mixing, and long residue time for monovinyl-acetylene in the catalyst leads to further reaction with acetylene, which results in formation of the divinyl-acetylene and byproduct polymers. Increasing conversion rate and selectivity contributes to energy saving and consumption reduction by the enhancement of bubble column reaction. The FLUENT software was used to simulate the flow field in the bubble column reactor. It shows that the tilted porous baffle can change the flow field structure effectively, reduce the vortex size. It can also reduce liquid back-mixing area and the turbulence intensity in the whole bubble column reactor, which can enhance the dimerization reaction of acetylene.

  12. Studies on modelling of bubble driven flows in chemical reactors

    Energy Technology Data Exchange (ETDEWEB)

    Grevskott, Sverre

    1997-12-31

    Multiphase reactors are widely used in the process industry, especially in the petrochemical industry. They very often are characterized by very good thermal control and high heat transfer coefficients against heating and cooling surfaces. This thesis first reviews recent advances in bubble column modelling, focusing on the fundamental flow equations, drag forces, transversal forces and added mass forces. The mathematical equations for the bubble column reactor are developed, using an Eulerian description for the continuous and dispersed phase in tensor notation. Conservation equations for mass, momentum, energy and chemical species are given, and the k-{epsilon} and Rice-Geary models for turbulence are described. The different algebraic solvers used in the model are described, as are relaxation procedures. Simulation results are presented and compared with experimental values. Attention is focused on the modelling of void fractions and gas velocities in the column. The energy conservation equation has been included in the bubble column model in order to model temperature distributions in a heated reactor. The conservation equation of chemical species has been included to simulate absorption of CO{sub 2}. Simulated axial and radial mass fraction profiles for CO{sub 2} in the gas phase are compared with measured values. Simulations of the dynamic behaviour of the column are also presented. 189 refs., 124 figs., 1 tab.

  13. Characterization of gas transfer and mixing in a bubble column equipped with a rubber membrane diffuser

    Science.gov (United States)

    Poulsen; Iversen

    1998-06-20

    Gas transfer and mixing were characterized in a 32-L bubble column reactor equipped with a commercially available rubber membrane diffuser. The performance of the membrane diffuser indicates that the slits in the membrane are best described as holes with elastic lids, acting as valves cutting off bubbles from the gas stream. The membrane diffuser thus functions as a one-way valve preventing backflow of liquid. Our design of the bottom plate of the reactor enabled us to optimize the aeration by changing the tension of the membrane. We thereby achieved mass transfer coefficients higher than those previously reported in bubble columns. A strong dependence of mass transfer on gas holdup and bubble size was indicated by estimates based on these two variables. The microalga, Rhodomonas sp. , sensitive to chemical and physical stress, was maintained for 8 months in continuous culture with a productivity identical to cultures grown in stirred tank reactors. Copyright 1998 John Wiley & Sons, Inc.

  14. Determination of size distribution of bubbles in a bubbly column two phase flows by ultrasound and neural networks

    Energy Technology Data Exchange (ETDEWEB)

    Baroni, Douglas B.; Lamy, Carlos A.; Bittencourt, Marcelo S.Q.; Pereira, Claudio M.N.A., E-mail: douglasbaroni@ien.gov.b, E-mail: lamy@ien.gov.b, E-mail: bittenc@ien.gov.b, E-mail: cmnap@ien.gov.b [Instituto de Engenharia Nuclear (IEN/CNEN-RJ), Rio de Janeiro, RJ (Brazil); Cunha Filho, Jurandyr S. [Escola Tecnica Estadual Visconde de Maua (ETEVM/RJ), Rio de Janeiro, RJ (Brazil); Motta, Mauricio S., E-mail: mmotta@cefet-rj.b [Centro Federal de Educacao Tecnologica Celso Suckow da Fonseca (CEFET/RJ), Rio de Janeiro, RJ (Brazil)

    2011-07-01

    The development of advanced nuclear reactor conceptions depends largely on the amount of available data to the designer. Non invasive ultrasonic techniques can contribute to the evaluation of gas-liquid two-phase regimes in the nuclear thermo-hydraulic circuits. A key-point for success of those techniques is the interpretation of the ultrasonic signal. In this work, a methodology based in artificial neural networks (ANN) is proposed to predict size distribution of bubbles in a bubbly flow. To accomplish that, an air feed system control was used to obtain specific bubbly flows in an experimental system utilizing a Plexiglas vertical bubbly column. Four different size distribution of bubbles were generated. The bubbles were photographed and measured. To evaluate the different size distribution of bubbles it was used the ultrasonic reflected echo on the opposite wall of the column. Then, an ANN has been developed for predicting size distribution of bubbles by using the frequency spectra of the ultrasonic signal as input. A trained artificial neural network using ultrasonic signal in the frequency domain can evaluate with a good precision the size distribution of bubbles generated in this system. (author)

  15. Applicability and hydrodynamics of a slurry bubble column reactor for oxygen-heating calcium carbide production%氧热法电石合成淤浆鼓泡床反应器的流动特性

    Institute of Scientific and Technical Information of China (English)

    杨鹏远; 刘陆; 刘辉

    2012-01-01

    With a particular focus on the oxygen-heating calcium carbide synthesis process, where the endothermic calcium carbide synthesis is coupled with exothermic coke combustion, this work investigated experimentally the applicability and hydrodynamics of a suitably designed slurry bubble column reactor for the process. Average gas holdup, axial solid concentration and bubble size distribution in an air-water-chlorinated poly (vinyl chloride) (CPVC) three-phase system were measured. The results show that the average gas holdup increased with increasing superficial gas velocity, whilst addition of solid particles significantly reduced the average gas holdup in the reactor. The axial distribution of solid holdup remained uniform with increasing superficial gas velocity in the range Uf = 0.136 -0. 196 m/s and with decreasing solid particle feed velocity. The small bubble holdup increased but the large bubble holdup decreased with increasing superficial gas velocity. The large bubble holdup initially increased and then decreased with increasing liquid bed height. Our results indicate that the slurry bubble column reactor can be used in oxygen-heating calcium carbide production.%针对氧热法电石合成的电石吸热反应和炭燃烧放热耦合特点,本文设计并研究了适用该过程的三相淤浆鼓泡床反应器.采用空气-水-氯化聚氯乙烯(CPVC)模拟物系,实测了不同表观气速、固体颗粒进料量和静液高度下淤浆鼓泡床床层中局部平均气含率、固含率轴向分布和大、小两类气泡的分布.结果表明表观气速越大,局部平均气含率越大;固体颗粒的加入减小了床层局部平均气含率.当U(g)在0.136 ~0.196 m/s之间时,固含率轴向分布随表观气速增大趋于均匀;固体颗粒进料量越小则固含率沿轴向分布越均匀.随着表观气速的增加,小气泡含量逐渐增加,大气泡含量逐渐减小;随着静液高度的增加,大气泡含量均是先增大后减小.

  16. Optimization of bubble column performance for nanoparticle collection.

    Science.gov (United States)

    Cadavid-Rodriguez, M C; Charvet, A; Bemer, D; Thomas, D

    2014-04-30

    Fibrous media embody the most effective and widely used method of separating ultrafine particles from a carrier fluid. The main problem associated with them is filter clogging, which induces an increasingly marked pressure drop with time and thus imposes regular media cleaning or replacement. This context has prompted the idea of investigating bubble columns, which operate at constant pressure drop, as alternatives to fibrous filters. This study examines the influence of different operating conditions, such as liquid height, air flow rate, bubble size and presence of granular beds on ultrafine particle collection. Experimental results show that bubble columns are characterised by high collection efficiency, when they feature a large liquid height and small diameter bubbling orifices, while their efficiencies remain lower than those of fibrous filters. Gas velocity does not greatly influence collection efficiency, but the inclusion of a granular bed, composed of beads, increases the bubble residence time in the column, thereby increasing the column collection efficiency.

  17. Numerical modeling and simulation on dimethyl ether synthesis in a bubble column slurry reactor%浆态床法合成二甲醚的模拟研究

    Institute of Scientific and Technical Information of China (English)

    洪若瑜; 庄银枪; 杨伟

    2004-01-01

    对于直接以合成气作为原料,使用Cu-Zn-Al和γ-Al2O3构成的双重催化剂、采用浆态床法合成二甲醚的反应体系,使用全混流反应器模型结合化学反应动力学进行模拟.组分方程使用超松弛迭代方法并结合C++编程进行求解,编制了计算机程序.通过模拟计算,讨论了压力、温度、空速、催化剂配比、反应气中不同氢碳比以及CO2含量对反应收率、DME选择性的影响,并讨论了在不同氢碳比下对CO转化率和CO与H2总转化率的影响,从而寻找合适的反应条件,为工业化生产提供参考.%A complete-mixing-flow-reactor model together with detailed chemical reaction kinetics was used to simulate the synthesis of dimethyl ether (DME) in a bubble column slurry reactor using syngas directly. The derived non-linear equations were solved using under-relaxation iteration method. The programming language C + + was employed to implement the numerical algorithm. The influences of pressure, temperature and superficial gas velocity in the reactor, catalyst ratio, CO/H2 ratio and CO2 content of the feed gas on the conversion, yield and DME selectivity were studied. The influences of different CO/H2 ratio on CO conversion and total conversion were also studied. The optimal reaction conditions were found, which can be used as a worthwhile reference for engineering scale-up and design.

  18. Gas Holdups of Small and Large Bubbles in a Large-scale Bubble Column with Elevated Pressure

    Institute of Scientific and Technical Information of China (English)

    JIN Hai-bo; YANG Suo-he; ZHANG Tong-wang; TONG Ze-min

    2004-01-01

    Gas holdups of large bubbles and small bubbles were measured by means of dynamic gas disengagement approach in the pressured bubble column with a diameter of 0. 3 m and a height of 6. 6 m. The effects of superficial gas velocity, liquid surface tension, liquid viscosity andsystem pressure on gas holdups of small bubbles and large bubbles were investigated. The holdup of large bubbles increases and the holdup of small bubbles decreases with an increase of liquid viscosity. Meanwhile, the holdup of large bubbles decreases with increasing the system pressure. A correlation for the holdup of small bubbles was obtained from the experimental data.

  19. Heat transfer from a tube bundle in a bubble column

    Energy Technology Data Exchange (ETDEWEB)

    Saxena, S.C.; Vadivel, R.

    1988-09-01

    Heat transfer coefficient for an immersed five tube bundle in a two-phase (air-water) bubble column is measured as a function of air velocity and other relevant parameters. Average and local air holdup are also measured under identical conditions to characterize the system uniquely.

  20. Phenol biodegradation using a repeated batch culture of Candida tropicalis in a multistage bubble column.

    Science.gov (United States)

    Ruiz-Ordaz, N; Ruiz-Lagunez, J C; Castañon-González, J H; Hernández-Manzano, E; Cristiani-Urbina, E; Galíndez-Mayer, J

    2001-01-01

    As in many other microorganisms, the growth rate of C. tropicalis is affected by phenol. Besides, when the yeast is aerobically cultivated in a medium containing phenol, using a bubble column, the yeast cell flotation phenomenon occurs, which makes the continuous operation of this type of reactor difficult. Therefore, a system of phenol degradation, which recycles the biomass separated by flotation, was devised in this work. In order to reduce the substrate toxicity observed at high phenol concentrations, the bubble column used in the biodegradation studies was fed in a semibatch mode. So, a semicontinuous system was implemented to treat effluents with relatively high concentrations (> 9,000 ppm) of phenol, by replacing periodically about 22% of the bioreactor operational volume. The phenol removal efficiencies obtained with this system were higher than 98.7%.

  1. Effect of Solid Loading on Carbon Dioxide Absorptionin Bubble Column

    Directory of Open Access Journals (Sweden)

    Alyaa Khadhier Mageed

    2011-01-01

    Full Text Available In the present work experiments were conducted to study the effect of solid loading (1,5 and 9 vol.% on the enhancement of carbon dioxide absorption in bubble column at various volumetric gas flow rate (0.75, 1 and 1.5 m3/h and absorbent concentration (caustic soda( 0.1,0.5 and 1 M . Activated carbon and alumina oxide (Al2O3 are used as solid particles. The Danckwerts method was used to calculate interfacial area and individual mass transfer coefficients during absorption of carbon dioxide in a bubble column. The results show that the absorption rate was increased with increasing volumetric gas flow rate, caustic soda concentration and solid loading. Mass transfer coefficient and interfacial area were increased with increasing volumetric gas flow rate, and solid loading.

  2. Xanthane production in the bubble column bioreactor; Xanthanproduktion im Blasensaeulen-Bioreaktor

    Energy Technology Data Exchange (ETDEWEB)

    II-Soon Suh

    1992-05-14

    The industrial production of xanthane occurs in batch operation in stirred boiler reactors. The enrichment of the product in the culture medium causes an extreme increase of viscosity during strongly pseudoplastic flow behavior. Because of inhomogeneous distribution of the shear gradient in the stirred boiler, local deviations from the optimal fermentation conditions can occur (temperature, pH, oxygen supply); even stagnant regions may form at the walls. The suitability of tower reactors for xanthane production was investigated in the dissertation. The bubble column is by far superior to other reactor types (airlift, three-phase fluidized bed, stirred boiler, immersion-type beam reactor) with regard to good mixing of highly viscous culture broths of Xanthomonas campestris. The rise of the large bubbles which fill almost the entire column cross-section practically leads to intensive mixing. This not only makes the bubble column suitable for production but allow also the establishment of dependable fundamentals for model formation. (orig./EF). [Deutsch] Die industrielle Herstellung von Xanthan erfolgt satzweise in Ruehrkesselreaktoren. Die Anreicherung des Produkts im Kulturmedium bewirkt einen extremen Anstieg der Viskositaet bei einem stark pseudoplastischen Fliessverhalten. Wegen der inhomogenen Verteilung des Schergefaelles im Ruehrkessel koennen lokale Abweichungen von den optimalen Fermentationsbedingungen (Temperatur, pH-Wert, Sauerstoffversorgung) auftreten; schliesslich bilden sich an den Waenden sogar stagnante Zonen aus. In dieser Arbeit sollte die Eignung von Turmreaktoren zur Xanthanproduktion untersucht werden. Die Blasensaeule erwies sich gegenueber anderen Reaktortypen (Airlift, Dreiphasenfliessbett, Ruehrkessel, Tauchstrahlreaktor) hinsichtlich der guten Vermischung hochviskoser Kulturbruehen von Xanthomonas campestris als deutlich ueberlegen. Der Aufstieg der Grossblasen, die praktisch den gesamten Saeulenquerschnitt erfassen, fuehrt zu einer

  3. Comparative analysis of the outdoor culture of Haematococcus pluvialis in tubular and bubble column photobioreactors.

    Science.gov (United States)

    López, M C García-Malea; Sánchez, E Del Río; López, J L Casas; Fernández, F G Acién; Sevilla, J M Fernández; Rivas, J; Guerrero, M G; Grima, E Molina

    2006-05-29

    The present paper makes a comparative analysis of the outdoor culture of H. pluvialis in a tubular photobioreactor and a bubble column. Both reactors had the same volume and were operated in the same way, thus allowing the influence of the reactor design to be analyzed. Due to the large changes in cell morphology and biochemical composition of H. pluvialis during outdoor culture, a new, faster methodology has been developed for their evaluation. Characterisation of the cultures is carried out on a macroscopic scale using a colorimetric method that allows the simultaneous determination of biomass concentration, and the chlorophyll, carotenoid and astaxanthin content of the biomass. On the microscopic scale, a method was developed based on the computer analysis of digital microscopic images. This method allows the quantification of cell population, average cell size and population homogeneity. The accuracy of the methods was verified during the operation of outdoor photobioreactors on a pilot plant scale. Data from the reactors showed tubular reactors to be more suitable for the production of H. pluvialis biomass and/or astaxanthin, due to their higher light availability. In the tubular photobioreactor biomass concentrations of 7.0 g/L (d.wt.) were reached after 16 days, with an overall biomass productivity of 0.41 g/L day. In the bubble column photobioreactor, on the other hand, the maximum biomass concentration reached was 1.4 g/L, with an overall biomass productivity of 0.06 g/L day. The maximum daily biomass productivity, 0.55 g/L day, was reached in the tubular photobioreactor for an average irradiance inside the culture of 130 microE/m2s. In addition, the carotenoid content of biomass from tubular photobioreactor increased up to 2.0%d.wt., whereas that of the biomass from the bubble column remained roughly constant at values of 0.5%d.wt. It should be noted that in the tubular photobioreactor under conditions of nitrate saturation, there was an accumulation of

  4. Airlift column photobioreactors for Porphyridium sp. culturing: part I. effects of hydrodynamics and reactor geometry.

    Science.gov (United States)

    Luo, Hu-Ping; Al-Dahhan, Muthanna H

    2012-04-01

    Photosynthetic microorganisms have been attracting world attention for their great potential as renewable energy sources in recent years. Cost effective production in large scale, however, remains a major challenge to overcome. It is known to the field that turbulence could help improving the performance of photobioreactors due to the so-called flashing light effects. Better understanding of the multiphase fluid dynamics and the irradiance distribution inside the reactor that cause the flashing light effects, as well as quantifying their impacts on the reactor performance, thus, are crucial for successful design and scale-up of photobioreactors. In this study, a species of red marine microalgae, Porphyridium sp., was grown in three airlift column photobioreactors (i.e., draft tube column, bubble column, and split column). The physical properties of the culture medium, the local fluid dynamics and the photobioreactor performances were investigated and are reported in this part of the manuscript. Results indicate that the presence of microalgae considerably affected the local multiphase flow dynamics in the studied draft tube column. Results also show that the split column reactor works slightly better than the draft tube and the bubble columns due to the spiral flow pattern inside the reactor.

  5. Eulerian modeling of reactive gas-liquid flow in a bubble column

    NARCIS (Netherlands)

    Zhang, Dongsheng

    2007-01-01

    Despite the widespread application of bubble columns and intensive research efforts devoted to understand their complex behavior, detailed knowledge on the fluid flow, mass transfer and chemical reactions as well as their interactions is currently very limited. Gas-liquid flow in bubble column react

  6. Growth characteristics of Chlorella sorokiniana in airlift and bubble column photobioreactors.

    Science.gov (United States)

    Kumar, Kanhaiya; Das, Debabrata

    2012-07-01

    The present study investigated the feasibility of bioCO(2) sequestration using Chlorella sorokiniana. It was found that 5% CO(2) (v/v) in air was the most suitable concentration for the growth of this organism. At this concentration, the maximum rate of CO(2) sequestered and the biomass obtained were found to be 1.21 g L(-1)d(-1) and 4.4 g L(-1) respectively. Modeling and simulation of the growth profile was obtained using the logistic equation. Further, at higher CO(2) concentrations, pH drop in the growth media, TAP [-acetate], was prevented by replacing NH(4)Cl by NaNO(3.) Additionally, the study evaluated the performance of two reactors namely: bubble column and airlift reactor based on their growth profile and transport properties like K(L)a and mixing time. The growth profile was better in airlift reactor and it provides cyclic axial mixing of media. K(L)a of downcomer was significantly lower than the riser in airlift reactor.

  7. The Bubble Transport Mechanism: Indications for a bubble-mediated transfer of microorganisms from the sediment into the water column

    Science.gov (United States)

    Schmale, Oliver; Stolle, Christian; Schneider von Deimling, Jens; Leifer, Ira; Kießlich, Katrin; Krause, Stefan; Frahm, Andreas; Treude, Tina

    2015-04-01

    Gas releasing seep areas are known to impact the methane biogeochemistry in the surrounding sediment and water column. Due to microbial processes most of the methane is oxidized under anaerobic and aerobic conditions before the greenhouse gas can escape into the atmosphere. However, methane gas bubbles can largely bypass this microbial filter mechanism, enabling highly efficient transport of methane from the sediment towards the sea surface. Studies in the water column surrounding hydrocarbon seeps indicated an elevated abundance of methanotrophic microorganism in the near field of gas bubble plumes. The enhanced methane concentration in the seep-affected water column stimulates the activity of methane oxidizers and leads to a rapid rise in the abundance of methane-oxidizing microorganisms in the aging plume water. In our study we hypothesized that a bubble-mediated transport mechanisms between the benthic and pelagic habitats represents an exchange process, which transfers methanotrophic microorganisms from the sediment into the water column, a process we termed the "Bubble Transport Mechanism". This mechanism could eventually influence the pelagic methanotrophic community, thereby indirectly providing feedback mechanisms for dissolved methane concentrations in the water column and thus impacting the sea/atmosphere methane flux. To test our hypothesis, field studies were conducted at the "Rostocker Seep" site (Coal Oil Point seep area, California, USA). Catalyzed Reporter Deposition Fluorescence In Situ Hybridization (CARD-FISH) analyzes were performed to determine the abundance of aerobic and anaerobic methanotrophic microorganisms. Aerobic methane oxidizing bacteria were detected in the sediment and the water column, whereas anaerobic methanotrophs were detected exclusively in the sediment. The key device of the project was a newly developed "Bubble Catcher" used to collect naturally emanating gas bubbles at the sea floor together with particles attached to the

  8. Production of tropane alkaloids in Hyoscyamus niger (black henbane) hairy roots grown in bubble-column and spray bioreactors.

    Science.gov (United States)

    Jaremicz, Zbigniew; Luczkiewicz, Maria; Kokotkiewicz, Adam; Krolicka, Aleksandra; Sowinski, Pawel

    2014-04-01

    Hairy root cultures of Hyoscyamus niger were cultivated in shake-flasks, a bubble-column bioreactor and a hybrid bubble-column/spray bioreactor and evaluated for alkaloid production. The latter gave the highest anisodamine content (0.67 mg/g dry wt) whereas scopolamine, hyoscyamine and cuscohygrine concentrations were highest in the bubble-column reactor (5.3, 1.6 and 26.5 mg/g dry wt, respectively). Both bioreactors gave similar productivities of scopolamine (1 and 0.98 mg/l day) and cuscohygrine (5 and 5.4 mg/l day), but anisodamine productivity was 3.5-fold higher in the hybrid bioreactor (HB) (0.02 and 0.07 mg/l day, respectively). Elicitation with methyl jasmonate increased scopolamine productivity by 146 % in roots grown in the HB whereas their permeabilization with DMSO caused 4-, 5-, 25- and 28-fold increase in scopolamine, hyoscyamine, anisodamine and cuscohygrine concentrations in the growth medium. In situ extraction with Amberlite XAD-2 doubled scopolamine productivity in the hybrid reactor after 50 days.

  9. Rise characteristics of gas bubbles in a 2D rectangular column: VOF simulations vs experiments

    Energy Technology Data Exchange (ETDEWEB)

    Krishna, R.; Baten, J.M. van

    1999-10-01

    About five centuries ago, Leonardo da Vinci described the sinuous motion of gas bubbles rising in water. The authors have attempted to simulate the rise trajectories of bubbles of 4, 5, 7, 8, 9, 12, and 20 mm in diameter rising in a 2D rectangular column filled with water. The simulations were carried out using the volume-of-fluid (VOF) technique developed by Hirt and Nichols (J. Computational Physics, 39, 201--225 (1981)). To solve the Navier-Stokes equations of motion the authors used a commercial solver, CFX 4.1c of AEA Technology, UK. They developed their own bubble-tracking algorithm to capture sinuous bubble motions. The 4 and 5 mm bubbles show large lateral motions observed by Da Vinci. The 7, 8 and 9 mm bubble behave like jellyfish. The 12 mm bubble flaps its wings like a bird. The extent of lateral motion of the bubbles decreases with increasing bubble size. Bubbles larger than 20 mm in size assume a spherical cap form and simulations of the rise characteristics match experiments exactly. VOF simulations are powerful tools for a priori determination of the morphology and rise characteristics of bubbles rising in a liquid. Bubble-bubble interactions are also properly modeled by the VOF technique.

  10. Euler-Euler Modeling of Flow, Mass Transfer, and Chemical Reaction in a Bubble Column

    NARCIS (Netherlands)

    Zhang, Dongsheng; Deen, Niels G.; Kuipers, J.A.M.

    2009-01-01

    Physical and chemical absorption of pure CO2 bubbles in water and an aqueous sodium hydroxide (NaOH) solution has been studied in a square cross-sectioned bubble column using the commercial software package CFX-4.4. The subgrid-scale turbulence model of Vreman [Phys. Fluids 2004, 16, 3670-3681] was

  11. Experiments on turbulent diffusion of the gaseous phase in rectangular bubble column using image processing

    Energy Technology Data Exchange (ETDEWEB)

    Alexander Zaruba; Eckhard Krepper; Horst-Michael Prasser [Forschungszentrum Rossendorf e.V., P.O.Box 510119, 01314 Dresden (Germany)

    2005-07-01

    Full text of publication follows: The paper describes the application of high-speed video observation combined with digital image processing techniques to measure the turbulent diffusion coefficient of the gaseous phase in a bubble column. The test channel is a rectangular bubble column with a cross-section of 100 x 20 mm and a height of 1500 mm. Sequences of the images were taken at different heights of the column with a high-speed video system. A diffuse illumination from the backside of the column was found to produce bubble images with a characteristic bright spot in the center. This bright spot was used for a bubble tracking that tolerates some overlapping of the bubbles. This allows to enhance the applicability of the bubble tracking to higher gas fractions compared to the tracking of the entire bubble shadows. After the bubble trajectories were extracted from the image sequence, the lateral displacement of bubbles between two virtual horizontal measuring planes was calculated for each bubble that crosses both planes. This lateral displacement is caused by the turbulent fluctuations of the bubble velocity. It is analyzed statistically by constructing probability density functions of the lateral displacement, which can be well described by Gaussian standard distributions. The dispersion coefficient of the standard distributions that were fitted to the experimental data shows a linear dependency from the square-root of the vertical distance between the two control planes, which supports the assumption of a diffusion model for the lateral displacement. Deviations from the linear dependency were identified to be the result of deterministic oscillatory motions of the rising bubbles. This effect is typical for low-viscosity liquids, while the bubble oscillations are damped at higher viscosities. Results are presented for different gas flow rates (superficial gas velocity ranged from 0.5 to 4 mm/s), different primary bubble sizes produced by a variation of the

  12. More rational design of bubble columns; Kihoto sekkei no genjo to kadai

    Energy Technology Data Exchange (ETDEWEB)

    Kawase, Y.; Shimizu, K. [Toyo University, Saitama (Japan)

    1998-04-05

    Design and scale-up of bubble columns are not easy even at present. For not the conventional empirical design and scale-up by 1-D dispersion model or vessel line model but more rational approach, simulation is essential. This paper outlines approaches to design and scale-up of bubble columns from the viewpoints of gas dispersion as an important factor for design of bubble columns, and flow analysis of bubble columns. A large part of the design and scale-up of bubble columns is dependent on previous experiences. However, for more precise design and scale-up of bubble columns, those should be conducted through simulation. More precise simulation should be based on simultaneous solution of a motion equation on flow in gas-liquid two-phase system, a diffusion equation of mass transfer including a reaction term, and a heat transmission equation on heat transfer, reducing participation of an empirical correlation equation as much as possible. The importance of simulation will surely increase in the future. 14 refs., 5 figs.

  13. Effects of Swirl Bubble Injection on Mass Transfer and Hydrodynamics for Bubbly Flow Reactors: A Concept Paper

    Directory of Open Access Journals (Sweden)

    Farooqi Ahmad Salam

    2017-01-01

    Full Text Available Bubble flow reactors (BFR are commonly used for various industrial processes in the field of oil and gas production, pharmaceutical industries, biochemical and environmental engineering etc. The operation and performance of these reactors rely heavily on a range of hydrodynamic parameters; prominent among them are geometric configurations including gas injection geometry, operating conditions, mass transfer etc. A huge body of literature is available to describe the optimum design and performance of bubbly flow reactors with conventional bubble injection. Attempts were made to modify gas injection for improved efficiency of BFR’s. However, here instead of modifying the geometry of the gas injection, an attempt has been made to generate swirl bubbles for gaining larger mass transfer between gas and liquid. Here an exceptionally well thought strategies have been used in our numerical simulations towards the design of swirl injection mechanism, whose paramount aspect is to inhibit the rotary liquid motion but facilitates the swirl movement for bubbles in nearly stationary liquid. Our comprehension here is that the swirl motion can strongly affect the performance of bubbly reactor by identifying the changes in hydrodynamic parameters as compared to the conventional bubbly flows. In order to achieve this bubbly flow, an experimental setup has been designed as well as computational fluid dynamic (CFD code was used with to highlight a provision of swirl bubble injection by rotating the sparger plate.

  14. The influence of polymeric membrane gas spargers on hydrodynamics and mass transfer in bubble column bioreactors

    DEFF Research Database (Denmark)

    Tirunehe, Gossay; Norddahl, B.

    2016-01-01

    Gas sparging performances of a flat sheet and tubular polymeric membranes were investigated in 3.1 m bubble column bioreactor operated in a semi batch mode. Air–water and air–CMC (Carboxymethyl cellulose) solutions of 0.5, 0.75 and 1.0 % w/w were used as interacting gas–liquid mediums. CMC...... solutions were employed in the study to simulate rheological properties of bioreactor broth. Gas holdup, bubble size distribution, interfacial area and gas–liquid mass transfer were studied in the homogeneous bubbly flow hydrodynamic regime with superficial gas velocity (UG) range of 0.0004–0.0025 m....../s. The study indicated that the tubular membrane sparger produced the highest gas holdup and densely populated fine bubbles with narrow size distribution. An increase in liquid viscosity promoted a shift in bubble size distribution to large stable bubbles and smaller specific interfacial area. The tubular...

  15. VELOCITY AND CONCENTRATION OF BUBBLES IN OZONIZATION COLUMNS WITH CROSS SECTIONS OF DIFFERENT SIZES

    OpenAIRE

    Salla, Marcio Ricardo; Vieira Soares,Leonardo; Alamy Filho,José Eduardo; Daniel,Luiz Antonio; Schulz, Harry Edmar

    2008-01-01

    The size of the cross section of an ozonization column influences its hydrodynamic characteristics, which, on its turn, has effects on phenomena that depend on the relative movement between gas bubbles and liquid. To observe the influence of the cross sectional area on gas concentration and bubbles velocity, two columns were used. The first column had a square cross section with side of 0.19m and the second had a circular cross section with diameter of 0.10 m. The ascendant velocities of the ...

  16. Dependence of the characteristics of bubbles on types of sonochemical reactors.

    Science.gov (United States)

    Yasui, Kyuichi; Tuziuti, Toru; Iida, Yasuo

    2005-01-01

    Computer simulations of bubble oscillations in liquid water irradiated by an ultrasonic wave have revealed that the characteristic of bubbles depends on types of sonochemical reactors: a horn-type reactor and a standing-wave type reactor. When the acoustic amplitude is large at 20 kHz, the bubble content is mostly water vapor even at the end of the bubble collapse and the temperature inside a bubble at the collapse is relatively low. On the other hand, when the acoustic amplitude is relatively low, the bubble content is mostly noncondensable gas at the end of the bubble collapse and the bubble temperature is relatively high. In a horn-type sonochemical reactor, the former type of bubbles are dominant because many bubbles exist near the horn-tip where the acoustic amplitude is large, while in a standing-wave type reactor the latter type of bubbles are dominant because the Bjerknes force gathers bubbles at a region where acoustic amplitude is relatively low.

  17. A novel methodology to measure methane bubble sizes in the water column

    Science.gov (United States)

    Hemond, H.; Delwiche, K.; Senft-Grupp, S.; Manganello, T.

    2014-12-01

    The fate of methane ebullition from lake sediments is dependent on initial bubble size. Rising bubbles are subject to dissolution, reducing the fraction of methane that ultimately enters the atmosphere while increasing concentrations of aqueous methane. Smaller bubbles not only rise more slowly, but dissolve more rapidly larger bubbles. Thus, understanding methane bubble size distributions in the water column is critical to predicting atmospheric methane emissions from ebullition. However, current methods of measuring methane bubble sizes in-situ are resource-intensive, typically requiring divers, video equipment, sonar, or hydroacoustic instruments. The complexity and cost of these techniques points to the strong need for a simple, autonomous device that can measure bubble size distributions and be deployed unattended over long periods of time. We describe a bubble sizing device that can be moored in the subsurface and can intercept and measure the size of bubbles as they rise. The instrument uses a novel optical measurement technique with infrared LEDs and IR-sensitive photodetectors combined with a custom-designed printed circuit board. An on-board microcomputer handles raw optical signals and stores the relevant information needed to calculate bubble volume. The electronics are housed within a pressure case fabricated from standard PVC fittings and are powered by size C alkaline batteries. The bill of materials cost is less than $200, allowing us to deploy multiple sensors at various locations within Upper Mystic Lake, MA. This novel device will provide information on how methane bubble sizes may vary both spatially and temporally. We present data from tests under controlled laboratory conditions and from deployments in Upper Mystic Lake.

  18. A novel closed system bubble column photobioreactor for detailed characterisation of micro and macroalgal growth

    DEFF Research Database (Denmark)

    Holdt, Susan Løvstad; Christensen, L.; Iversen, J. J.L.

    produced oxygen was catalytically removed from the closed system by addition of hydrogen over a palladium catalyst to avoid photorespiration and to quantify oxygen production. In addition, the bubble column photobioreactor was well suited for cultivation of algae due to fast gas to liquid mass transfer (k...

  19. Prediction of Gas Holdup in Bubble Columns Using Artificial Neural Network

    Institute of Scientific and Technical Information of China (English)

    吴元欣; 罗湘华; 陈启明; 李定或; 李世荣; M.H.Al-Dahhan; M.P.Dudukovic

    2003-01-01

    A new correlation for the prediction of gas hod up in bubble columns was proposed based on an extensive experimental database set up from the literature published over last 30 years .The updated estimation method relying on artificial neural network,dimensional analysis and phenomenological approaches was used and the model prediction agreed with the experimental data with average relative error less than 10%.

  20. A New Statistical Parameter for Identifying the Main Transition Velocities in Bubble Columns.

    Science.gov (United States)

    Nedeltchev, Stoyan; Rabha, Swapna; Hampel, Uwe; Schubert, Markus

    2015-11-01

    The identification of the main flow regime boundaries in bubble columns is essential since the degrees of mixing and mass and heat transfer vary with the flow regime. In this work, a new statistical parameter was extracted from the time series of the cross-sectional averaged gas holdup. The measurements were performed in bubble columns by means of conductivity wire-mesh sensors at very high sampling frequency. The columns were operated with an air/deionized water system under ambient conditions. As a flow regime indicator, a new dimensionless statistical parameter called "relative maximum number of visits in a region" was introduced. This new parameter is a function of the difference between the maximum numbers of visits in a region, calculated from two different division schemes of the signal range.

  1. Gas-Liquid Mass Transfer Characteristics in a Gas-Liquid-Solid Bubble Column under Elevated Pressure and Temperature

    Institute of Scientific and Technical Information of China (English)

    Haibo Jin; Suohe Yang; Guangxiang He; Delin Liu; Zemin Tong; Jianhua Zhu

    2014-01-01

    abstract The volumetric mass transfer coefficient kLa of gases (H2, CO, CO2) and mass transfer coefficient kL on liquid par-affin side were studied using the dynamic absorption method in slurry bubble column reactors under elevated temperature and elevated pressure. Meanwhile, gas-holdup and gas-liquid interfacial area a were obtained. The effects of temperature, pressure, superficial gas velocity and solid concentration on the mass transfer coeffi-cient were discussed. Experimental results show that the gas-liquid volumetric mass transfer coefficient kLa and interfacial area a increased with the increase of pressure, temperature, and superficial gas velocity, and decreased with the slurry concentration. The mass transfer coefficient kL increased with increasing superficial gas velocity and temperature and decreased with higher slurry concentration, while it changed slightly with pressure. Ac-cording to analysis of experimental data, an empirical correlation is obtained to calculate the values of kLa for H2 (CO, CO2) in the gas-paraffin-quartz system in a bubble column under elevated temperature and elevated pressure.

  2. Comparison of a Full Second-Order Moment Model and an Algebraic Stress Two-Phase Turbulence Model for Simulating Bubble-Liquid Flows in a Bubble Column

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    A full second-order moment (FSM) model and an algebraic stress (ASM) two-phase turbulence modelare proposed and applied to predict turbulent bubble-liquid flows in a 2D rectangular bubble column. Predictiongives the bubble and liquid velocities, bubble volume fraction, bubble and liquid Reynolds stresses and bubble-liquidvelocity correlation. For predicted two-phase velocities and bubble volume fraction there is only slight differencebetween these two models, and the simulation results using both two models are in good agreement with the particleimage velocimetry (PIV) measurements. Although the predicted two-phase Reynolds stresses using the FSM are insomewhat better agreement with the PIV measurements than those predicted using the ASM, the Reynolds stressespredicted using both two models are in general agreement with the experiments. Therefore, it is suggested to usethe ASM two-phase turbulence model in engineering application for saving the computation time.

  3. The influence of polymeric membrane gas spargers on hydrodynamics and mass transfer in bubble column bioreactors.

    Science.gov (United States)

    Tirunehe, Gossaye; Norddahl, B

    2016-04-01

    Gas sparging performances of a flat sheet and tubular polymeric membranes were investigated in 3.1 m bubble column bioreactor operated in a semi batch mode. Air-water and air-CMC (Carboxymethyl cellulose) solutions of 0.5, 0.75 and 1.0 % w/w were used as interacting gas-liquid mediums. CMC solutions were employed in the study to simulate rheological properties of bioreactor broth. Gas holdup, bubble size distribution, interfacial area and gas-liquid mass transfer were studied in the homogeneous bubbly flow hydrodynamic regime with superficial gas velocity (U(G)) range of 0.0004-0.0025 m/s. The study indicated that the tubular membrane sparger produced the highest gas holdup and densely populated fine bubbles with narrow size distribution. An increase in liquid viscosity promoted a shift in bubble size distribution to large stable bubbles and smaller specific interfacial area. The tubular membrane sparger achieved greater interfacial area and an enhanced overall mass transfer coefficient (K(L)a) by a factor of 1.2-1.9 compared to the flat sheet membrane.

  4. ANALYSIS OF TRICKLE BED AND PACKED BUBBLE COLUMN BIOREACTORS FOR COMBINED CARBON OXIDATION AND NITRIFICATION

    Directory of Open Access Journals (Sweden)

    Iliuta I.

    2002-01-01

    Full Text Available Biological removal of nitrogen and carbon by combined nitrification-oxidation in gas-liquid trickle-bed reactors (TBRs and packed bubble columns (PBCs was analyzed theoretically using a transient two-dimensional model. The model describes TBR and PBC performances at steady state as well as their transient response to a pulse or step increase in inlet methanol and NH4+-nitrogen concentrations. The hydrodynamic parameters were determined from residence time distribution measurements, using an imperfect pulse method for time-domain analysis of nonideal pulse tracer response. A transient diffusion model of the tracer in the porous particle coupled with the piston-dispersion-exchange model was used to interpret the residence time distribution curves obtained. Gas-liquid mass transfer parameters were determined by a stationary method based on the least-squares fit of the calculated concentration profiles in gas phase to the experimental values. Analysis of steady-state performances showed that under like operating conditions, the TBR outperforms the PBC in terms of conversions. A pulse change in the inlet methanol or NH4+-nitrogen concentration causes a negligible transient change in the outlet methanol concentration and a negligible or high transient change in the outlet NH4+-nitrogen concentration. A step change in the inlet methanol concentration causes the negligible transient change in the methanol outlet concentration and a relatively important transient change in the NH4+-nitrogen outlet concentration. A step increase in the NH4+-nitrogen inlet concentration induces a drastic transient change in the NH4+-nitrogen outlet concentration but a negligible transient change in the methanol outlet concentration.

  5. Technical Note: Detection of gas bubble leakage via correlation of water column multibeam images

    Directory of Open Access Journals (Sweden)

    J. Schneider von Deimling

    2012-03-01

    Full Text Available Hydroacoustic detection of natural gas release from the seafloor has been conducted in the past by using singlebeam echosounders. In contrast, modern multibeam swath mapping systems allow much wider coverage, higher resolution, and offer 3-D spatial correlation. Up to the present, the extremely high data rate hampers water column backscatter investigations and more sophisticated visualization and processing techniques are needed. Here, we present water column backscatter data acquired with a 50 kHz prototype multibeam system over a period of 75 seconds. Display types are of swath-images as well as of a "re-sorted" singlebeam presentation. Thus, individual and/or groups of gas bubbles rising from the 24 m deep seafloor clearly emerge in the acoustic images, making it possible to estimate rise velocities. A sophisticated processing scheme is introduced to identify those rising gas bubbles in the hydroacoustic data. We apply a cross-correlation technique adapted from particle imaging velocimetry (PIV to the acoustic backscatter images. Temporal and spatial drift patterns of the bubbles are assessed and are shown to match very well to measured and theoretical rise patterns. The application of this processing to our field data gives clear results with respect to unambiguous bubble detection and remote bubble rise velocimetry. The method can identify and exclude the main source of misinterpretations, i.e. fish-mediated echoes. Although image-based cross-correlation techniques are well known in the field of fluid mechanics for high resolution and non-inversive current flow field analysis, we present the first application of this technique as an acoustic bubble detector.

  6. Influence of structured packing on gas holdup in a three-phase bubble column

    DEFF Research Database (Denmark)

    Monsalvo, Matias Alfonso; Böhm, Ursula

    2007-01-01

    In this work, the influence of structured packing on gas holdup in gas-liquid-solid dispersions has been studied. The experiments were carried out in an empty column and in column containing structured packing operating under identical conditions. Glass beads and silicon carbide particles were used....... The influence of structured packing on the total gas holdup for different superficial gas velocities was found to be similar with and without suspended solids. Therefore, the results obtained in this work were analysed on the basis of correlations derived earlier for gas-liquid dispersions. Excepting...... as the solid material and the volumetric fraction of solids was varied from 0% to around 10%. The liquid viscosity was strongly modified using water, CMC solution and glycerol. The experimental results obtained with both columns were compared with previous results obtained in two-phase bubble columns...

  7. Bubble Shuttle: A newly discovered transport mechanism, which transfers microorganisms from the sediment into the water column

    Science.gov (United States)

    Schmale, O.; Stolle, C.; Leifer, I.; Schneider von Deimling, J.; Kiesslich, K.; Krause, S.; Frahm, A.; Treude, T.

    2013-12-01

    The diversity and abundance of methanotrophic microorganisms is well studied in the aquatic environment, indicating their importance in biogeochemical cycling of methane in the sediment and the water column. However, whether methanotrophs are distinct populations in these habitats or are exchanged between benthic and pelagic environments, remains an open question. Therefore, field studies were conducted at the 'Rostocker Seep' site (Coal Oil Point seep area, California, USA) to test our hypothesis that methane-oxidizing microorganisms can be transported by gas bubbles from the sediment into the water column. The natural methane emanating location 'Rostocker Seep' showed a strong surface water oversaturation in methane with respect to the atmospheric equilibrium. Catalyzed Reporter Deposition Fluorescence In Situ Hybridization (CARD-FISH) analyzes were performed to determine the abundance of aerobic and anaerobic methanotrophic microorganisms. Aerobic methane oxidizing bacteria were detected in the sediment and the water column, whereas anaerobic methanotrophs were detected exclusively in the sediment. The key device of the project was the newly developed "Bubble Catcher" used to collect naturally emanating gas bubbles at the sea floor together with particles attached to the bubble surface rim. Bubble Catcher experiments were carried out directly above a natural bubble release spot and on a reference site at which artificially released gas bubbles were caught, which had no contact with the sediment. CARD-FISH analyzes showed that aerobic methane oxidizing bacteria were transported by gas bubbles from the sediment into the water column. In contrast anaerobic methanotrophs were not detected in the bubble catcher. Further results indicate that this newly discovered Bubble Shuttle transport mechanism might influence the distribution pattern of methanotrophic microorganisms in the water column and even at the air-sea interface. Methane seep areas are often characterized

  8. Heat Transfer in Bubble Columns with High Viscous and Low Surface Tension Media

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Wan Tae; Lim, Dae Ho; Kang, Yong [Chungnam National University, Daejeon (Korea, Republic of)

    2014-08-15

    Axial and overall heat transfer coefficients were investigated in a bubble column with relatively high viscous and low surface tension media. Effects of superficial gas velocity (0.02-0.1 m/s), liquid viscosity (0.1-3 Pa·s) and surface tension (66.1-72.9x10{sup -3} N/m) on the local and overall heat transfer coefficients were examined. The heat transfer field was composed of the immersed heater and the bubble column; a vertical heater was installed at the center of the column coaxially. The heat transfer coefficient was determined by measuring the temperature differences continuously between the heater surface and the column which was bubbling in a given operating condition, with the knowledge of heat supply to the heater. The local heat transfer coefficient increased with increasing superficial gas velocity but decreased with increasing axial distance from the gas distributor and liquid surface tension. The overall heat transfer coefficient increased with increasing superficial gas velocity but decreased with increasing liquid viscosity or surface tension. The overall heat transfer coefficient was well correlated in terms of operating variables such as superficial gas velocity, liquid surface tension and liquid viscosity with a correlation coefficient of 0.91, and in terms of dimensionless groups such as Nusselt, Reynolds, Prandtl and Weber numbers with a correlation of 0.92; h=2502U{sub G}{sup 0.236}{sub L}{sup -0.250}{sub L}{sup -}0{sup .028} Nu=3.25Re{sup 0.180}Pr{sup -0.067}We{sup 0.028}.

  9. Hydrolysis of Olive Oil with Immobilized Lipase in a Tapered Column Reactor

    Institute of Scientific and Technical Information of China (English)

    杨伯伦; 赵国胜; 林宏业

    2003-01-01

    Lipase was immobilized in ion exchange resin and then used in the hydrolysis of olive oil to produce fatty acids and glycerol. The time course of hydrolysis of olive oil was investigated in a stirred tank reactor using both of the free and immobilized lipases to find the yield of activity of immobilized enzyme. Continuous hydrolysis of olive oil was also carried out in a tapered column reactor and a cylindrical column reactor with a bottom ID of 10 mm at different upward flow rates. It can be known from experimental results that the degree of hydrolysis of olive oil in the tapered column reactor is moderately better than that in the cylindrical column reactor, the pressure drop in the tapered column reactor is much smaller than that in the cylindrical column reactor.

  10. Two-Phase Flow in Packed Columns and Generation of Bubbly Suspensions for Chemical Processing in Space

    Science.gov (United States)

    Motil, Brian J.; Green, R. D.; Nahra, H. K.; Sridhar, K. R.

    2000-01-01

    For long-duration space missions, the life support and In-Situ Resource Utilization (ISRU) systems necessary to lower the mass and volume of consumables carried from Earth will require more sophisticated chemical processing technologies involving gas-liquid two-phase flows. This paper discusses some preliminary two-phase flow work in packed columns and generation of bubbly suspensions, two types of flow systems that can exist in a number of chemical processing devices. The experimental hardware for a co-current flow, packed column operated in two ground-based low gravity facilities (two-second drop tower and KC- 135 low-gravity aircraft) is described. The preliminary results of this experimental work are discussed. The flow regimes observed and the conditions under which these flow regimes occur are compared with the available co-current packed column experimental work performed in normal gravity. For bubbly suspensions, the experimental hardware for generation of uniformly sized bubbles in Couette flow in microgravity conditions is described. Experimental work was performed on a number of bubbler designs, and the capillary bubble tube was found to produce the most consistent size bubbles. Low air flow rates and low Couette flow produce consistent 2-3 mm bubbles, the size of interest for the "Behavior of Rapidly Sheared Bubbly Suspension" flight experiment. Finally the mass transfer implications of these two-phase flows is qualitatively discussed.

  11. Pico-nano bubble column flotation using static mixer-venturi tube for Pittsburgh No. 8 coal seam

    Institute of Scientific and Technical Information of China (English)

    Peng Felicia F.; Yu Xiong

    2015-01-01

    The flotation process is a particle-hydrophobic surface-based separation technique. To improve the essential flotation steps of collision and attachment probabilities, and reduce the step of detachment probabilities between air bubbles and hydrophobic particles, a selectively designed cavitation venturi tube combined with a static mixer can be used to generate very high numbers of pico and nano bubbles in a flotation column. Fully embraced by those high numbers of tiny bubbles, hydrophobic particles readily attract the tiny bubbles to their surfaces. The results of column flotation of Pittsburgh No. 8 seam coal are obtained in a 5.08 cm ID and 162 cm height flotation column equipped with a static mixer and cavitation venturi tube, using kerosene as collector and MIBC as frother. Design of the experimental procedure is combined with a statistical two-stepwise analysis to determine the optimal operating conditions for maximum recovery at a specified grade. The effect of independent variables on the responses has been explained. Combustible material recovery of 85–90% at clean coal product of 10–11%ash is obtained from feed of 29.6%ash, with a much-reduced amount of frother and collector than that used in conventional column flotation. The column flotation process utilizing pico and nano bubbles can also be extended to the lower limit and upper limit of particle size ranges, minus 75 lm and 300–600 lm, respectively, for better recovery.

  12. A bubble column evaporator with basic flat-plate condenser for brackish and seawater desalination.

    Science.gov (United States)

    Schmack, Mario; Ho, Goen; Anda, Martin

    2016-01-01

    This paper describes the development and experimental evaluation of a novel bubble column-based humidification-dehumidification system, for small-scale desalination of saline groundwater or seawater in remote regions. A bubble evaporator prototype was built and matched with a simple flat-plate type condenser for concept assessment. Consistent bubble evaporation rates of between 80 and 88 ml per hour were demonstrated. Particular focus was on the performance of the simple condenser prototype, manufactured from rectangular polyvinylchlorid plastic pipe and copper sheet, a material with a high thermal conductivity that quickly allows for conduction of the heat energy. Under laboratory conditions, a long narrow condenser model of 1500 mm length and 100 mm width achieved condensate recovery rates of around 73%, without the need for external cooling. The condenser prototype was assessed under a range of different physical conditions, that is, external water cooling, partial insulation and aspects of air circulation, via implementing an internal honeycomb screen structure. Estimated by extrapolation, an up-scaled bubble desalination system with a 1 m2 condenser may produce around 19 l of distilled water per day. Sodium chloride salt removal was found to be highly effective with condensate salt concentrations between 70 and 135 µS. Based on findings and with the intent to reduce material cost of the system, a shorter condenser length of 750 mm for the non-cooled (passive) condenser and of 500 mm for the water-cooled condenser was considered to be equally efficient as the experimentally evaluated prototype of 1500 mm length.

  13. 鼓泡塔中水合物法分离混合气体的数值模拟%Numerical Simulation of Separating Gas Mixtures via Hydrate Formation in Bubble Column

    Institute of Scientific and Technical Information of China (English)

    罗艳托; 朱建华; 陈光进

    2007-01-01

    To develop a new technique for separating gas mixtures via hydrate formation, a set of medium-sized experimental bubble column reactor equipment was constructed.On the basis of the structure parameters of the experimental bubble column reactor, assuming that the liquid phase was in the axial dispersion regime and the gas phase was in the plug flow regime, in the presence of hydrate promoter tetrahydrofuran (THF), the rate of hydrogen enrichment for CH4+H2 gas mixtures at different operational conditions (such as temperature, pressure, concentration of gas components, gas flow rate, liquid flow rate) were simulated.The heat product of the hydrate reaction and its axial distribution under different operational conditions were also calculated.The results would be helpful not only to setting and optimizing operation conditions and design of multi-refrigeration equipment, but also to hydrate separation technique industrialization.

  14. Bubbles

    DEFF Research Database (Denmark)

    Dholakia, Nikhilesh; Turcan, Romeo V.

    2013-01-01

    A goal of our ongoing research stream is to develop a multidisciplinary metatheory of bubbles. In this viewpoint paper we put forward a typology of bubbles by comparing four types of assets – entertainment, commodities, financial securities (stocks), and housing properties – where bubbles could a...

  15. The effect of bubble plume on oxygen transfer for moving bed biofilm reactor

    Institute of Scientific and Technical Information of China (English)

    CHENG Wen; LIU Hu; WANG Meng; WANG Min

    2014-01-01

    The movement of the bubble plume plays an important role in the operation of a moving bed biofilm reactor (MBBR), and it directly affects the contact and the mixture of the gas-liquid-solid phases in the aeration tank and also the oxygen transfer from the gas phase to the liquid phase. In this study, the velocity field is determined by a 4-frame PTV as well as the time-averaged and time- dependent velocity distributions. The velocity distribution of the bubble plume is analyzed to evaluate the operating efficiency of the MBBR. The results show that the aeration rate is one of the main factors that sway the velocity distribution of the bubble plumes and affect the operating efficiency of the reactor.

  16. Control of CO₂ input conditions during outdoor culture of Chlorella vulgaris in bubble column photobioreactors.

    Science.gov (United States)

    Guo, Zhi; Phooi, Wei Boon Alfred; Lim, Zi Jian; Tong, Yen Wah

    2015-06-01

    A study on the optimization of CO2 usage during outdoor microalgae cultivation in order to further maximize the CO2 to biomass conversion efficiency is presented. A constant supply of CO2 was found to be non-essential for culturing microalgae outdoors in 80 L (8 L×10 sets) bubble columns. Among the different CO2 input conditions that were studied, 2% CO2 with intermittent supply and 2%+4% CO2 alternation did not affect the algal growth as compared to having a constant supply of 2% CO2. However, during both input conditions, the CO2 to biomass conversion efficiency was doubled while the amount of CO2 used was reduced by 50%. The algal biomass obtained was found to have a higher carbohydrate yield but a lower protein yield as compared to previously published studies. The findings from this study could be applied for large-scale microalgae production so as to minimize cultivation and energy costs.

  17. Thienamycin production by immobilized cells of Streptomyces cattleya in a bubble column.

    Science.gov (United States)

    Arcuri, E J; Nichols, J R; Brix, T S; Santamarina, V G; Buckland, B C; Drew, S W

    1983-10-01

    A novel 2.0-L columnar reactor has been developed for the production of thienamycin by cells of Streptomyces cattleya attached to celite particles. Successful immobilization of cells was achieved by operating the column continuously at a high dilution rate during the growth phase. Scanning electron micrographs of the celite particles indicate the involvement of subcellular fibrils in the attachment of cells to the solid surfaces. Reactor operation was divided into two distinct phases-a growth phase and a production phase. The kinetics of attached growth and thienamycin production were found to be strongly influenced by nutrient concentrations. The influences of nutrient concentration on CO(2) production and thienamycin production during both the growth phase and the production phase are discussed.

  18. Air-bubbling, hollow-fiber reactor with cell bleeding and cross-flow filtration.

    Science.gov (United States)

    Nishii, K; Sode, K; Karube, I

    1990-05-01

    Continuous asymmetric reduction of dyhydrooxoisophorone (DOIP) to 4-hydroxy-2,2,6-trimethylcyclo-hexanone (4-HTMCH) was achieved by a thermophilic bacterium Bacillus stearothermophilus NK86-0151. Three reactors were used: an air-bubbling hollow-fiber reactor with cell bleeding and cross-flow filtration, an air-lift reactor, and a CSTR with PAA immobilized cells. The maximum cell concentration of 11.1 g dry wt L(-1) was obtained in an air-bubbling hollow-fiber reactor, while in the other reactors the cell densities were between 3.5 and 4.1 g dry wt L(-1) The optimum bleed ratio was 0.1 at the dilution rate 0.3 h(-1) in the hollow-fiber reactor. The highest viable cell concentration was maintained in the dilution range of 0.4-0.7 h(-1) by a combination of proper cell bleeding and cross-flow filtration. The maximum volumetric productivity of 4-HTMCH reached 826 mg L(-1) h(-1) at the dilution rate 0.54 h(-1). This value was 4 and 2 times higher than those in the air-lift reactor and CSTR, respectively. The increasing viable cell concentration increased the volumetric productivity of 4-HTMCH. A cell free product solution was continuously obtained by cross-flow filtration.

  19. Determining the Enthalpy of Vaporization of Salt Solutions Using the Cooling Effect of a Bubble Column Evaporator

    Science.gov (United States)

    Fan, Chao; Pashley, Richard M.

    2016-01-01

    The enthalpy of vaporization (?H[subscript vap]) of salt solutions is not easily measured, as a certain quantity of pure water has to be evaporated from a solution, at constant composition, and at a fixed temperature and pressure; then the corresponding heat input has to be measured. However, a simple bubble column evaporator (BCE) was used as a…

  20. Bioleaching of low grade nickel sulfide mineral in column reactor

    Institute of Scientific and Technical Information of China (English)

    ZHEN Shi-jie; QIN Wen-qing; YAN Zhong-qiang; ZHANG Yan-sheng; WANG Jun; REN Liu-yi

    2008-01-01

    Jinchuan low grade nickel (0.4%-0.6% Ni,mass fraction) sulfide mineral ore contains a remarkably high content of magnesia (30%-35% MgO,mass fraction) present in the main gangue minerals.Bioleaching was performed to investigate the feasibility to process the mineral due to its relative simplicity,eco-friendly operation and low capital cost requirements.The mixed mesophiles were enriched from acid mine drainage samples collected from several acid mines in China.Considering that the magnesia is easily extracted by acid solution and the excessive Mg2+ will exceed the tolerance of the mixed mesophiles,three effective means were used to reduce the disadvantage of magnesia during the bioleaching operation.They were adaptation of the mixed mesophiles to improve the tolerance; pre-leaching to remove most leachable magnesia and periodic bleeds of a portion of the pregnant leaching solution to control the level of Mg2+ based on the tolerance of the mixed mesophiles.An extraction of nickel (90.3%) and cobalt (88.6%) was successfully achieved within a 300 d leaching process from the Jinchuan low grade nickel sulfide mineral ore using a column reactor at ambient temperature.

  1. Study of a Novel Method for the Thermolysis of Solutes in Aqueous Solution Using a Low Temperature Bubble Column Evaporator.

    Science.gov (United States)

    Shahid, Muhammad; Xue, Xinkai; Fan, Chao; Ninham, Barry W; Pashley, Richard M

    2015-06-25

    An enhanced thermal decomposition of chemical compounds in aqueous solution has been achieved at reduced solution temperatures. The technique exploits hitherto unrecognized properties of a bubble column evaporator (BCE). It offers better heat transfer efficiency than conventional heat transfer equipment. This is obtained via a continuous flow of hot, dry air bubbles of optimal (1-3 mm) size. Optimal bubble size is maintained by using the bubble coalescence inhibition property of some salts. This novel method is illustrated by a study of thermal decomposition of ammonium bicarbonate (NH4HCO3) and potassium persulfate (K2S2O8) in aqueous solutions. The decomposition occurs at significantly lower temperatures than those needed in bulk solution. The process appears to work via the continuous production of hot (e.g., 150 °C) dry air bubbles, which do not heat the solution significantly but produce a transient hot surface layer around each rising bubble. This causes the thermal decomposition of the solute. The decomposition occurs due to the effective collision of the solute with the surface of the hot bubbles. The new process could, for example, be applied to the regeneration of the ammonium bicarbonate draw solution used in forward osmosis.

  2. Effect of Solid Properties on Axial Liquid Dispersion in Bubble Column

    Directory of Open Access Journals (Sweden)

    Ali Raad Mohammed Jawad

    2012-01-01

    Full Text Available Experiments were conducted to study axial liquid dispersion coefficient in slurry bubble column of 0.15 m inside diameter and 1.6 m height using perforated plate gas distributor of 54 holes of a size equal to 1 mm diameter and with a 0.24 free area of holes to the cross sectional area of the column. The three phase system consists of air, water and PVC used as the solid phase. The effect of solid loading (0, 30 and 60 kg/m3 and solid diameter (0.7, 1.5 and 3 mm on the axial liquid dispersion coefficient at different axial location (25, 50 and 75 cm and superficial gas velocity covered homogeneous-heterogeneous flow regime (1-10 cm/s were studied in the present work. The results show that the axial liquid dispersion coefficient increases with increasing superficial gas velocity, axial distance, solid concentration and an inverse relationship with particles diameter

  3. An Euler-Lagrange method considering bubble radial dynamics for modeling sonochemical reactors.

    Science.gov (United States)

    Jamshidi, Rashid; Brenner, Gunther

    2014-01-01

    Unsteady numerical computations are performed to investigate the flow field, wave propagation and the structure of bubbles in sonochemical reactors. The turbulent flow field is simulated using a two-equation Reynolds-Averaged Navier-Stokes (RANS) model. The distribution of the acoustic pressure is solved based on the Helmholtz equation using a finite volume method (FVM). The radial dynamics of a single bubble are considered by applying the Keller-Miksis equation to consider the compressibility of the liquid to the first order of acoustical Mach number. To investigate the structure of bubbles, a one-way coupling Euler-Lagrange approach is used to simulate the bulk medium and the bubbles as the dispersed phase. Drag, gravity, buoyancy, added mass, volume change and first Bjerknes forces are considered and their orders of magnitude are compared. To verify the implemented numerical algorithms, results for one- and two-dimensional simplified test cases are compared with analytical solutions. The results show good agreement with experimental results for the relationship between the acoustic pressure amplitude and the volume fraction of the bubbles. The two-dimensional axi-symmetric results are in good agreement with experimentally observed structure of bubbles close to sonotrode.

  4. Characterization of oxygen transfer in miniature and lab-scale bubble column bioreactors and comparison of microbial growth performance based on constant k(L)a.

    Science.gov (United States)

    Doig, Steven D; Ortiz-Ochoa, Kenny; Ward, John M; Baganz, Frank

    2005-01-01

    This work describes the engineering characterization of miniature (2 mL) and laboratory-scale (100 mL) bubble column bioreactors useful for the cultivation of microbial cells. These bioreactors were constructed of glass and used a range of sintered glass gas diffusers with differently sized pores to disperse humidified air within the liquid biomedium. The effect of the pressure of this supplied air on the breakthrough point for gas diffusers with different pore sizes was examined and could be predicted using the Laplace-Young equation. The influence of the superficial gas velocity (u(g)) on the volumetric mass transfer coefficient (k(L)a) was determined, and values of up to 0.09 s(-1) were observed in this work. Two modeling approaches were considered in order to predict and provide comparison criteria. The first related the volumetric power consumption (P/V) to the k(L)a and a good correlation was obtained for differently sized reactors with a given pore size, but this correlation was not satisfactory for bubble columns with different gas diffusers. Values for P/V ranged from about 10 to 400 W.m(-3). Second, a model was developed predicting bubble size (d(b)), bubble rising velocity (u(b)), gas hold-up (phi), liquid side mass transfer coefficient (k(L)), and thus the k(L)a using established theory and empirical correlations. Good agreement was found with our experimental data at different scales and pore sizes. Values for d(b) varied from 0.1 to 0.6 mm, and k(L) values between 1.7 and 9.8 x 10(-4) m.s(-1) were determined. Several E. coli cultivations were performed in the miniature bubble column at low and high k(L)a values, and the results were compared to those from a conventional stirred tank operated under identical k(L)a values. Results from the two systems were similar in terms of biomass growth rate and carbon source utilization.

  5. Evaluation of a subsurface oxygenation technique using colloidal gas aphron injections into packed column reactors

    Energy Technology Data Exchange (ETDEWEB)

    Wills, R.A.; Coles, P.

    1991-11-01

    Bioremediation may be a remedial technology capable of decontaminating subsurface environments. The objective of this research was to evaluate the use of colloidal gas aphron (CGA) injection, which is the injection of micrometer-size air bubbles in an aqueous surfactant solution, as a subsurface oxygenation technique to create optimal growth conditions for aerobic bacteria. Along with this, the capability of CGAs to act as a soil-washing agent and free organic components from a coal tar-contaminated matrix was examined. Injection of CGAs may be useful for remediation of underground coal gasification (UCG) sites. Because of this, bacteria and solid material from a UCG site located in northeastern Wyoming were used in this research. Colloidal gas aphrons were generated and pumped through packed column reactors (PCRS) containing post-burn core materials. For comparison, PCRs containing sand were also studied. Bacteria from this site were tested for their capability to degrade phenol, a major contaminant at the UCG site, and were also used to bioaugment the PCR systems. In this study we examined: (1) the effect of CGA injection on dissolved oxygen concentrations in the PCR effluents, (2) the effect of CGA, H[sub 2]O[sub 2], and phenol injections on bacterial populations, (3) the stability and transport of CGAs over distance, and (4) CGA injection versus H[sub 2]O[sub 2] injection as an oxygenation technique.

  6. Evaluation of a subsurface oxygenation technique using colloidal gas aphron injections into packed column reactors

    Energy Technology Data Exchange (ETDEWEB)

    Wills, R.A.; Coles, P.

    1991-11-01

    Bioremediation may be a remedial technology capable of decontaminating subsurface environments. The objective of this research was to evaluate the use of colloidal gas aphron (CGA) injection, which is the injection of micrometer-size air bubbles in an aqueous surfactant solution, as a subsurface oxygenation technique to create optimal growth conditions for aerobic bacteria. Along with this, the capability of CGAs to act as a soil-washing agent and free organic components from a coal tar-contaminated matrix was examined. Injection of CGAs may be useful for remediation of underground coal gasification (UCG) sites. Because of this, bacteria and solid material from a UCG site located in northeastern Wyoming were used in this research. Colloidal gas aphrons were generated and pumped through packed column reactors (PCRS) containing post-burn core materials. For comparison, PCRs containing sand were also studied. Bacteria from this site were tested for their capability to degrade phenol, a major contaminant at the UCG site, and were also used to bioaugment the PCR systems. In this study we examined: (1) the effect of CGA injection on dissolved oxygen concentrations in the PCR effluents, (2) the effect of CGA, H{sub 2}O{sub 2}, and phenol injections on bacterial populations, (3) the stability and transport of CGAs over distance, and (4) CGA injection versus H{sub 2}O{sub 2} injection as an oxygenation technique.

  7. Study of the reactivity effect of bubble collapse in molten liquid metal cooled reactors

    Energy Technology Data Exchange (ETDEWEB)

    Munno, F.J.; Sheaks, O.J.

    1977-08-01

    The reactivity effect of void collapse on a Core Disruptive Accident in a sodium free fast reactor core was studied. A two-dimensional transport theory computer code was employed to obtain a reactivity model which incorporated random distributions of voids in spatial location and bubble size. This model was implemented into VENUS-II and several excursions were investigated for the purpose of assessing the effect of bubble collapse reactivity on excursion energy. In addition, comparisons were made between the VENUS-II results obtained using the transport reactivity model and those obtained using a reactivity model developed from the Behrens' formulation of the leakage effects due to the presence of bubbles. The results indicate that excursion energy is sensitive to the shape of the reactivity versus void fraction function and that reactivity models based strictly on leakage effects are probably conservative compared to models which include both self-multiplication and leakage.

  8. Quantitative calculation of reaction performance in sonochemical reactor by bubble dynamics

    Science.gov (United States)

    Xu, Zheng; Yasuda, Keiji; Liu, Xiao-Jun

    2015-10-01

    In order to design a sonochemical reactor with high reaction efficiency, it is important to clarify the size and intensity of the sonochemical reaction field. In this study, the reaction field in a sonochemical reactor is estimated from the distribution of pressure above the threshold for cavitation. The quantitation of hydroxide radical in a sonochemical reactor is obtained from the calculation of bubble dynamics and reaction equations. The distribution of the reaction field of the numerical simulation is consistent with that of the sonochemical luminescence. The sound absorption coefficient of liquid in the sonochemical reactor is much larger than that attributed to classical contributions which are heat conduction and shear viscosity. Under the dual irradiation, the reaction field becomes extensive and intensive because the acoustic pressure amplitude is intensified by the interference of two ultrasonic waves. Project supported by the National Natural Science Foundation of China (Grant Nos. 11404245, 11204129, and 11211140039).

  9. Quantitative calculation of reaction performance in sonochemical reactor by bubble dynamics

    Institute of Scientific and Technical Information of China (English)

    徐峥; 安田启司; 刘晓峻

    2015-01-01

    In order to design a sonochemical reactor with high reaction efficiency, it is important to clarify the size and intensity of the sonochemical reaction field. In this study, the reaction field in a sonochemical reactor is estimated from the distribution of pressure above the threshold for cavitation. The quantitation of hydroxide radical in a sonochemical reactor is obtained from the calculation of bubble dynamics and reaction equations. The distribution of the reaction field of the numerical simulation is consistent with that of the sonochemical luminescence. The sound absorption coefficient of liquid in the sonochemical reactor is much larger than that attributed to classical contributions which are heat conduction and shear viscosity. Under the dual irradiation, the reaction field becomes extensive and intensive because the acoustic pressure amplitude is intensified by the interference of two ultrasonic waves.

  10. Benchmarking of the construct of dimensionless correlations regarding batch bubble columns with suspended solids: Performance of the Pressure Transform Approach

    CERN Document Server

    Hristov, Jordan

    2010-01-01

    Benchmark of dimensionless data correlations pertinent to batch bubble columns (BC) with suspended solids has been performed by the pressure transform approach (PTA). The main efforts have addressed the correct definition of dimensionless groups referring to the fact that solids dynamics and the bubble dynamics have different velocity and length scales. The correct definition of the initial set of variable in the classical dimensional analysis depends mainly on the experience of the investigator while the pressure transform approach (PTA) avoids errors at this initial stage. PTA addresses the physics of the phenomena occurring in complex systems involving many phases and allows straightforward definitions of dimensionless numbers.

  11. Mixing Characteristics and Bubble Behavior in an Airlift Internal Loop Reactor with Low Aspect Ratio

    Institute of Scientific and Technical Information of China (English)

    张伟鹏; 雍玉梅; 张广积; 杨超; 毛在砂

    2014-01-01

    The present study summarizes the results of macro-and micro-mixing characteristics in an airlift inter-nal loop reactor with low aspect ratio (H/D≤5) using the electrolytic tracer response technique and the method of parallel competing reactions respectively. The micro-mixing has never been investigated in airlift loop reactors. The dual-tip electrical conductivity probe technique is used for measurement of local bubble behavior in the reactor. The effects of several operating parameters and geometric variables are investigated. It is found that the increase in su-perficial gas velocity corresponds to the increase in energy input, liquid circulation velocity and shear rate, decreas-ing the macro-mixing time and segregation index. Moreover, it is shown that top clearance and draft diameter affect flow resistance. However, the bubble redistribution with a screen mesh on the perforated plate distributor for macro-mixing is insignificant. The top region with a high energy dissipation rate is a suitable location for feeding reactants. The analysis of present experimental data provides a valuable insight into the interaction between gas and liquid phases for mixing and improves the understanding of intrinsic roles of hydrodynamics upon the reactor de-sign and operating parameter selection.

  12. Steady Thermal Field Simulation of Forced Air-cooled Column-type Air-core Reactor

    Institute of Scientific and Technical Information of China (English)

    DENG Qiu; LI Zhenbiao; YIN Xiaogen; YUAN Zhao

    2013-01-01

    Modeling the steady thermal field of the column-type air-core reactor,and further analyzing its distribution regularity,will help optimizing reactor design as well as improving its quality.The operation mechanism and inner insulation structure of a novel current limiting column-type air-core reactor is introduced in this paper.The finite element model of five encapsulation forced air-cooled column type air-core reactor is constructed using Fluent.Most importantly,this paper present a new method that,the steady thermal field of reactor working under forced air-cooled condition is simulated without arbitrarily defining the convection heat transfer coefficient for the initial condition; The result of the thermal field distribution shows that,the maximum steady temperature rise of forced air-cooled columntype air-core reactor happens approximately 5% to its top.The law of temperature distribution indicates:In the 1/3part of the reactor to its bottom,the temperature will rise rapidly to the increasing of height,yet the gradient rate is gradually decreasing; In the 5 % part of the reactor to its top,the temperature will drop rapidly to the increasing of height; In the part between,the temperature will rise slowly to the increasing of height.The conclusion draws that more thermal withstand capacity should be considered at the 5 % part of the reactor to its top to achieve optimal design solution.

  13. Modeling of reaction kinetics in bubbling fluidized bed biomass gasification reactor

    Energy Technology Data Exchange (ETDEWEB)

    Thapa, R.K.; Halvorsen, B.M. [Telemark University College, Kjolnes ring 56, P.O. Box 203, 3901 Porsgrunn (Norway); Pfeifer, C. [University of Natural Resources and Life Sciences, Vienna (Austria)

    2013-07-01

    Bubbling fluidized beds are widely used as biomass gasification reactors as at the biomass gasification plant in Gussing, Austria. The reactor in the plant is a dual circulating bubbling fluidized bed gasification reactor. The plant produces 2MW electricity and 4.5MW heat from the gasification of biomass. Wood chips as biomass and olivine particles as hot bed materials are fluidized with high temperature steam in the reactor. As a result, biomass undergoes endothermic chemical reaction to produce a mixture of combustible gases in addition to some carbon-dioxide (CO2). The combustible gases are mainly hydrogen (H2), carbon monoxide (CO) and methane (CH4). The gas is used to produce electricity and heat via utilization in a gas engine. Alternatively, the gas is further processed for gaseous or liquid fuels, but still on the process of development level. Composition and quality of the gas determine the efficiency of the reactor. A computational model has been developed for the study of reaction kinetics in the gasification rector. The simulation is performed using commercial software Barracuda virtual reactor, VR15. Eulerian-Lagrangian approach in coupling of gas-solid flow has been implemented. Fluid phase is treated with an Eulerian formulation. Discrete phase is treated with a Lagrangian formulation. Particle-particle and particle-wall interactions and inter-phase heat and mass transfer have been taken into account. Series of simulations have been performed to study model prediction of the gas composition. The composition is compared with data from the gasifier at the CHP plant in Güssing, Austria. The model prediction of the composition of gases has good agreements with the result of the operating plant.

  14. Modeling of reaction kinetics in bubbling fluidized bed biomass gasification reactor

    Directory of Open Access Journals (Sweden)

    R.K. Thapa, C. Pfeifer, B. M. Halvorsen

    2014-01-01

    Full Text Available Bubbling fluidized beds are widely used as biomass gasification reactors as at the biomass gasification plant in Güssing, Austria. The reactor in the plant is a dual circulating bubbling fluidized bed gasification reactor. The plant produces 2MW electricity and 4.5MW heat from the gasification of biomass. Wood chips as biomass and olivine particles as hot bed materials are fluidized with high temperature steam in the reactor. As a result, biomass undergoes endothermic chemical reaction to produce a mixture of combustible gases in addition to some carbon-dioxide (CO2. The combustible gases are mainly hydrogen (H2, carbon monoxide (CO and methane (CH4. The gas is used to produce electricity and heat via utilization in a gas engine. Alternatively, the gas is further processed for gaseous or liquid fuels, but still on the process of development level. Composition and quality of the gas determine the efficiency of the reactor. A computational model has been developed for the study of reaction kinetics in the gasification rector. The simulation is performed using commercial software Barracuda virtual reactor, VR15. Eulerian-Lagrangian approach in coupling of gas-solid flow has been implemented. Fluid phase is treated with an Eulerian formulation. Discrete phase is treated with a Lagrangian formulation. Particle-particle and particle-wall interactions and inter-phase heat and mass transfer have been taken into account. Series of simulations have been performed to study model prediction of the gas composition. The composition is compared with data from the gasifier at the CHP plant in Güssing, Austria. The model prediction of the composition of gases has good agreements with the result of the operating plant.

  15. A model to estimate volume change due to radiolytic gas bubbles and thermal expansion in solution reactors

    Energy Technology Data Exchange (ETDEWEB)

    Souto, F.J. [NIS-6: Advanced Nuclear Technology, Los Alamos National Lab., Los Alamos, NM (United States); Heger, A.S. [ESA-EA: Engineering Sciences and Application, Los Alamos National Lab., Los Alamos, NM (United States)

    2001-07-01

    To investigate the effects of radiolytic gas bubbles and thermal expansion on the steady-state operation of solution reactors at the power level required for the production of medical isotopes, a calculational model has been developed. To validate this model, including its principal hypotheses, specific experiments at the Los Alamos National Laboratory SHEBA uranyl fluoride solution reactor were conducted. The following sections describe radiolytic gas generation in solution reactors, the equations to estimate the fuel solution volume change due to radiolytic gas bubbles and thermal expansion, the experiments conducted at SHEBA, and the comparison of experimental results and model calculations. (author)

  16. Quantifying Methane Flux from a Prominent Seafloor Crater with Water Column Imagery Filtering and Bubble Quantification Techniques

    Science.gov (United States)

    Mitchell, G. A.; Gharib, J. J.; Doolittle, D. F.

    2015-12-01

    Methane gas flux from the seafloor to atmosphere is an important variable for global carbon cycle and climate models, yet is poorly constrained. Methodologies used to estimate seafloor gas flux commonly employ a combination of acoustic and optical techniques. These techniques often use hull-mounted multibeam echosounders (MBES) to quickly ensonify large volumes of the water column for acoustic backscatter anomalies indicative of gas bubble plumes. Detection of these water column anomalies with a MBES provides information on the lateral distribution of the plumes, the midwater dimensions of the plumes, and their positions on the seafloor. Seafloor plume locations are targeted for visual investigations using a remotely operated vehicle (ROV) to determine bubble emission rates, venting behaviors, bubble sizes, and ascent velocities. Once these variables are measured in-situ, an extrapolation of gas flux is made over the survey area using the number of remotely-mapped flares. This methodology was applied to a geophysical survey conducted in 2013 over a large seafloor crater that developed in response to an oil well blowout in 1983 offshore Papua New Guinea. The site was investigated by multibeam and sidescan mapping, sub-bottom profiling, 2-D high-resolution multi-channel seismic reflection, and ROV video and coring operations. Numerous water column plumes were detected in the data suggesting vigorously active vents within and near the seafloor crater (Figure 1). This study uses dual-frequency MBES datasets (Reson 7125, 200/400 kHz) and ROV video imagery of the active hydrocarbon seeps to estimate total gas flux from the crater. Plumes of bubbles were extracted from the water column data using threshold filtering techniques. Analysis of video images of the seep emission sites within the crater provided estimates on bubble size, expulsion frequency, and ascent velocity. The average gas flux characteristics made from ROV video observations is extrapolated over the number

  17. A MODEL TO ESTIMATE VOLUME CHANGE DUE TO RADIOLYTIC GAS BUBBLES AND THERMAL EXPANSION IN SOLUTION REACTORS

    Energy Technology Data Exchange (ETDEWEB)

    F. SOUTO; A HEGER

    2001-02-01

    Aqueous homogeneous solution reactors have been proposed for the production of medical isotopes. However, the reactivity effects of fuel solution volume change, due to formation of radiolytic gas bubbles and thermal expansion, have to be mitigated to allow steady-state operation of solution reactors. The results of the free run experiments analyzed indicate that the proposed model to estimate the void volume due to radiolytic gas bubbles and thermal expansion in solution reactors can accurately describe the observed behavior during the experiments. This void volume due to radiolytic gas bubbles and fuel solution thermal expansion can then be used in the investigation of reactivity effects in fissile solutions. In addition, these experiments confirm that the radiolytic gas bubbles are formed at a higher temperature than the fuel solution temperature. These experiments also indicate that the mole-weighted average for the radiolytic gas bubbles in uranyl fluoride solutions is about 1 {micro}m. Finally, it should be noted that another model, currently under development, would simulate the power behavior during the transient given the initial fuel solution level and density. The model is based on Monte Carlo simulation with the MCNP computer code [Briesmeister, 1997] to obtain the reactor reactivity as a function of the fuel solution density, which, in turn, changes due to thermal expansion and radiolytic gas bubble formation.

  18. Gas-Liquid flow characterization in bubble columns with various gas-liquid using electrical resistance tomography

    Science.gov (United States)

    Jin, Haibo; Yuhuan, Han; Suohe, Yang

    2009-02-01

    Electrical resistance tomography (ERT) is an advanced and new detecting technique that can measure and monitor the parameters of two-phase flow on line, such as gas-liquid bubble column. It is fit for the industrial process where the conductible medium serves as the disperse phase to present the key bubble flow characteristics in multi-phase medium. Radial variation of the gas holdup and mean holdups are investigated in a 0.160 m i. d. bubble column using ERT with two axial locations (Plane 1 and Plane 2). In all the experiments, air was used as the gas phase, tap water as liquid phase, and a series of experiments were done by adding KCl, ethanol, oil sodium, and glycerol to change liquid conductivity, liquid surface tension and viscosity. The superficial gas velocity was varied from 0.02 to 0.2 m/s. The effect of conductivity, surface tension, viscosity on the mean holdups and radial gas holdup distribution is discussed. The results showed that the gas holdup decrease with the increase of surface tension and increase with the increase of viscosity. Meanwhile, the settings of initial liquid conductivity slightly influence the gas holdup values, and the experimental data increases with the increase of the initial setting values in the same conditions.

  19. A new post-column reactor-laser induced fluorescence detector for capillary electrophoresis

    Energy Technology Data Exchange (ETDEWEB)

    Zhang Liling

    1996-01-02

    Capillary zone electrophoresis (CZE), a powerful separation method based on the differential migration of charged species under the influence of an electric field, has been widely used for separations covering from small ions to big biomolecules. Chapter 1 describes the method, then discusses detection of the separated analytes by laser induced fluorescence and by chemical derivatization, and the use of O-phthaldialdehyde (OPA) as a post-column reagent. Chapter 2 describes a post-column reactor which uses two narrow bore capillaries connected coaxially. This reactor differs from other coaxial reactors in terms of capillary dimensions, reagent flow control, ease of construction and most importantly, better limits of detection. The derivatization reagent is electroosmotically driven into the reaction capillary and the reagent flow rate is independently controlled by a high voltage power supply. Amino acids, amines and proteins, derivatized by OPA/2-mercaptoethanol using this post-column reactor coupled with LIF detection, show low attomole mass limits of detection, and for the first time, the authors demonstrate single cell capability with a post-column derivatization scheme. The single cell capability shows that this reactor could find applications in assaying non-fluorescent or electrochemically inactive components in individual biological cells in the future.

  20. Thermal neutron flux distribution in ET-RR-2 reactor thermal column

    Directory of Open Access Journals (Sweden)

    Imam Mahmoud M.

    2002-01-01

    Full Text Available The thermal column in the ET-RR-2 reactor is intended to promote a thermal neutron field of high intensity and purity to be used for following tasks: (a to provide a thermal neutron flux in the neutron transmutation silicon doping, (b to provide a thermal flux in the neutron activation analysis position, and (c to provide a thermal neutron flux of high intensity to the head of one of the beam tubes leading to the room specified for boron thermal neutron capture therapy. It was, therefore, necessary to determine the thermal neutron flux at above mentioned positions. In the present work, the neutron flux in the ET-RR-2 reactor system was calculated by applying the three dimensional diffusion depletion code TRITON. According to these calculations, the reactor system is composed of the core, surrounding external irradiation grid, beryllium block, thermal column and the water reflector in the reactor tank next to the tank wall. As a result of these calculations, the thermal neutron fluxes within the thermal column and at irradiation positions within the thermal column were obtained. Apart from this, the burn up results for the start up core calculated according to the TRITION code were compared with those given by the reactor designer.

  1. A single-phase turbulent flow numerical simulation of a cyclonic-static micro bubble flotation column

    Institute of Scientific and Technical Information of China (English)

    Yan Xiaokang; Liu Jiongtian; Cao Yijun; Wang Lijun

    2012-01-01

    Improved fluid dynamics can enhance the separation efficiency of flotation methods.A Computational Fluid Dynamics simulation using FLUENT was performed to model the fluid environment of a cyclonic-static micro bubble flotation column.The simulation results visually show the interior flow and illustrate mixing of the different flows within the apparatus.An analysis of the distribution in velocity and vorticity was used to analyze the separation mechanism and the synergism of the component parts and to strengthen the design of each unit.The conclusions are that axial back mixing and vortexes still exist in the separation unit even in the presence of packing media.The inverted cone structure near the tangential inlet (cone 1 ) within the cyclonic unit is the main reason for this.The cone 1 structure enhances swirling and focuses energy within the inner area of the cone where there are abundant bubbles.As a result slowly floating minerals are forcibly recovered and tailings are effectively separated within this unit.However,cone 1 also reduces the vorticity downstream from it,which reduces the efficiency of tailings separation within this part.Therefore,the design of cone 1 should be based on the principles of lessening disturbances to the column unit while strengthening the separation effect of the cyclonic unit.Also,the axial distance between the paired cyclonic structures at the bottom of the column (cone 2) and cone 1 poses tough requirements because of an interaction between separation of the middlings and tailings.

  2. A computational fluid dynamics study of hydrogen bubbles in an electrochemical reactor

    Directory of Open Access Journals (Sweden)

    Renata da Silva Cavalcanti

    2005-06-01

    Full Text Available Most electrochemical reactors present reactions with the growth and departure of gas bubbles which influence on the reactor hydrodynamics and this study is usually complex, representing a vast field for research. The present paper had as objective to study a bi-phase (gas-liquid system aiming to foresee the influence of departure of hydrogen bubbles generated on effective electrode surface situated on cathodic semi-cell. Nevertheless, it was idealized that the gas was injected into the semi cell, through the effective electrode surface With this hypothesis, it was possible to study, and numerically analyze, the hydrodynamic behavior of the hydrogen bubbles in the interior of the study domain, applying concepts of computational fluid dynamics by using the computational applicative CFX-4 for the application of the MUSIG ("MUltiple-SIze-Group" model, taking into consideration the phenomena of coalescence and the distribution of the diameter of the bubbles.A maioria dos reatores eletroquímicos apresenta reações com crescimento e desprendimento de bolhas de gás influenciando na hidrodinâmica dos reatores e seu estudo é, geralmente, complexo representando um campo amplo para pesquisas. O presente artigo teve por objetivo estudar um sistema bifásico (gás-líquido visando prever a influência do desprendimento das bolhas de hidrogênio geradas na superfície específica do eletrodo localizada na semicélula catódica. No entanto, foi idealizado que o gás fora injetado no interior da semicélula através da superfície específica do eletrodo. Com esta hipótese, foi possível estudar e analisar numericamente o comportamento hidrodinâmico das bolhas de hidrogênio no interior do domínio de estudo, aplicando-se os conceitos de fluidodinâmica computacional usando o aplicativo computacional CFX-4 para aplicação do modelo MUSIG ("Multiple-size-group" levando em consideração os fenômenos da coalescência e da distribuição do diâmetro das

  3. An analysis of the hydrogen bubble concerns in the three-mile island unit-2 reactor vessel

    Science.gov (United States)

    Gordon, S.; Schmidt, K. H.; Honekamp, J. R.

    On 30 March 1979, two days after the accident at the Three-Mile Island Reactor near Harrisburg, Pennsylvania, press reports appeared about a non-condensable bubble in the reactor vessel. This bubble was said to consist mainly of hydrogen, and to grow rapidly, possibly due to the development of oxygen. Danger of explosion was reported to be imminent. We analyzed all possible sources of non-condensable gases, including radiolysis, and determined that a continuing growth of the bubble during several days after the accident was not possible. Our main conclusions were the following: (1) Most of the initial hydrogen in the bubble was produced by the reaction of the Zircalloy cladding with the super-heated water. (2) During the first 16 hr after shutdown, when boiling of the primary coolant water took place, in the worst case stoichiometric amounts of hydrogen and oxygen could have been produced by radiolysis, leading to a maximum amount of oxygen in the bubble, of 0.7% of the hydrogen, which is well below the explosion limit. (3) After this 16 hr period, when boiling had totally ceased, no further oxygen could have been produced by radiolysis of the primary cooling water. On the contrary, oxygen was recombined with hydrogen due to radiolysis at such a rate that the oxygen in the water was completely removed in less than five minutes. The subsequent rate of removal of oxygen from the bubble by dissolution and radiolysis depended essentially on the rate of dissolution.

  4. Experimental investigation of a pilot-scale jet bubbling reactor for wet flue gas desulphurisation

    DEFF Research Database (Denmark)

    Zheng, Yuanjing; Kiil, Søren; Johnsson, Jan Erik

    2003-01-01

    In the present work, an experimental parameter study was conducted in a pilot-scale jet bubbling reactor for wet flue gas desulphurisation (FGD). The pilot plant is downscaled from a limestone-based, gypsum producing full-scale wet FGD plant. Important process parameters, such as slurry pH, inlet...... flue gas concentration of SO2, reactor temperature, and slurry concentration of Cl- have been varied. The degree of desulphurisation, residual limestone content of the gypsum, liquid phase concentrations, and solids content of the slurry were measured during the experimental series. The SO2 removal...... efficiency increased from 66.1% to 71.5% when the reactor slurry pH was changed from 3.5 to 5.5. Addition of Cl(in the form of CaCl2 . 2H(2)O) to the slurry (25 g Cl-/l) increased the degree of desulphurisation to above 99%, due to the onset of extensive foaming, which substantially increased the gas...

  5. Flow injection spectrophotometry coupled with a crushed barium sulfate reactor column for the determination of sulfate ion in water samples

    OpenAIRE

    Burakham,Rodjana; Higuchi, Keiro; Oshima, Mitsuko; Grudpan, Kate; Motomizu, Shoji

    2004-01-01

    A new type of a reactor column, a crushed BaSO4 reactor column used for the flow injection spectrophotometric determination of sulfate ion using the exchange reaction of sulfate ion and barium-dimethylsulfonazo III is proposed. The column is very simple and economical. It can be continuously used for 8 h before washing with water for repeated usage of at least 1 month. The procedure is sensitive. Application to various water samples was demonstrated.

  6. Voronoi analysis of bubbly flows via ultrafast X-ray tomographic imaging

    Energy Technology Data Exchange (ETDEWEB)

    Lau, Yuk Man; Mueller, Karolin; Azizi, Salar; Schubert, Markus [Helmholtz-Zentrum Dresden-Rossendorf e.V., Institute of Fluid Dynamics, Dresden (Germany)

    2016-03-15

    Although clustering of bubbles plays a significant role in bubble column reactors regarding the heat and mass transfer due to bubble-bubble and flow field interactions, it has yet to be fully understood. Contrary to flows in bubble columns, most literature studies on clustering report numerical and experimental results on dilute or micro-bubbly flows. In this paper, clustering of bubbles in a cylindrical bubble column of 100 mm diameter is experimentally investigated. Ultrafast X-ray tomographic imaging is used to obtain the bubble positions within a hybrid Eulerian framework. By means of Voronoi analysis, the clustering behavior of bubbles is investigated. Experiments are performed with different superficial gas velocities, where Voronoi diagrams are constructed at several column heights. From the PDFs of the Voronoi diagrams, it is shown that the bubble structuring in terms of Voronoi cell volumes develops slower than the bubble size distribution. The latter reaches a steady state earlier with increasing column height. The measured PDFs are compared with the PDF of randomly distributed points, which showed that the amount of bubbles as part of clusters (Voronoi cells < V/ anti V{sub cluster}) as well as bubbles as part of voids (Voronoi cells > V/ anti V{sub void}) increases with the superficial gas velocity. It is found that all experiments have an approximate cluster limit V/ anti V{sub cluster} of 0.63, while the void limit V/ anti V{sub void} varies between 1.5 and 3.0. (orig.)

  7. Chemisorptive removal of carbon dioxide from process streams using a reactive bubble column with simultaneous production of usable materials

    Energy Technology Data Exchange (ETDEWEB)

    Petrov, P.; Ewert, G.; Roehm, H.J. [Department of Process and Environmental Engineering, Ruhr-University, Bochum (Germany)

    2006-09-15

    In the context of attempts to improve the protection of the environment, a novel process where the carbon dioxide reacts rapidly with almost 100 % conversion under mild conditions, is proposed. The chemisorptive process takes place in a slurry bubble column which operates with countercurrent flow, utilizing special solutions of primary long chain amines in a nonaqueous media. The product obtained is insoluble and separated by filtration. Because of its molecular structure, this product possesses tenside properties and can be used as an industrial additive. Typically the liquid phase consists of a mixture of hexadecylamine (C{sub 16}H{sub 33}NH{sub 2}) or dodecylamine (C{sub 12}H{sub 25}NH{sub 2}) in various concentrations with methanol or other alcohols as the solvent. Numerous parameters have been studied including different column heights, gas inlet compositions, gas flow rates and solvent type. Efficiencies of up to 99 % are achievable for CO{sub 2} absorption with methanol as the solvent. The second solvent examined, isopropanol, shows lower CO{sub 2} conversion rates. This can be attributed to its physical properties, mainly higher viscosity and hence, smaller mass transfer coefficient. In order to simulate real gas conditions, the influence of other sour gases, e.g., SO{sub 2} was also investigated experimentally. Because of coabsorption of the two gases, the CO{sub 2} efficiency was lower in this instance. In both solvents, the absorption efficiency with respect to SO{sub 2} is more than 99 % due to its high solubility and reactivity. A complex mathematical model has been developed and applied to describe the mass and enthalpy transport in the reactive bubble column. (Abstract Copyright [2006], Wiley Periodicals, Inc.)

  8. Velocity distribution of the flow field in the cyclonic zone of cyclone-static micro-bubble flotation column

    Institute of Scientific and Technical Information of China (English)

    Deng Xiao-wei; Liu Jiong-tian; Wang Yong-tian; Cao Yi-jun

    2013-01-01

    Laboratory experiments have been conducted to study the flow field in a cyclone static micro-bubble flotation column.The method of Particle Image Velocimetry (PIV) was used.The flow field velocity distribution in both cross section and longitudinal section within cyclonic zone was studied for different circulating volumes.The cross sectional vortex was also analyzed.The results show that in cross section as the circulating volume increases from 0.187 to 0.350 m3/h,the flow velocity ranges from 0 to 0.68 m/s.The flow field is mainly a non-vortex potential flow that forms a free vortex without outside energy input.In the cyclonic region the vortex deviates from the center of the flotation column because a single tangential opening introduces circulating fluid into the column.The tangential component of the velocity plays a defining role in the cross section.In the longitudinal section the velocity ranges from 0 to 0.08 m/s.The flow velocity increases as does the circulating volume.Advantageous mineral separation conditions arise from the combined effects of cyclonic flow in cross and longitudinal section.

  9. Hydrodynamic and absorption studies of carbon dioxide absorption in aqueous amide solutions using a bubble column contactor

    Directory of Open Access Journals (Sweden)

    A. Blanco

    2013-12-01

    Full Text Available The present work analyses the carbon dioxide absorption process in aqueous n-alkylpyrrolidones solutions, from the point of view of hydrodynamic studies as well as mass transfer, using a bubble column contactor. An analysis of the influence of solute concentration and gas flow-rate is complemented by the study of the effect caused by the alkyl group on the hydrodynamics and mass transfer. The presence of this kind of substance produces a decrease in mass transfer rate, but on the basis of interfacial area and mass transfer coefficient values, ethyl-2-pyrrolidine (EP shows suitable characteristics to replace methyl-2-pyrrolidine (MP in gas separation processes due to its lower safety problems.

  10. Process mineralogy of copper-nickel sulphide flotation by cyclonic-static micro-bubble flotation column

    Institute of Scientific and Technical Information of China (English)

    CAO Yi-jun; GUI Xia-hui; MA Zi-long; YU Xiao-xia; CHEN Xiao-dong; ZHANG Xiu-pin

    2009-01-01

    In our study we investigated a refractory copper-nickel sulfide ore separation by using a cyclonic-static micro-bubble flotation column (FCSMC). The process mineralogy of the main products was studied. Using a scanning electron micro-scope-energy dispersive system (SEM-EDS) and an X-ray spectrometer the mineral category and content of samples were analyzed. By using a mineral liberation analyzer (MLA) the mineral liberation characteristics were revealed. It is shown that in roughing feed the monomers liberation degree of nickel pyrite and chalcopyrite take up 84.11% and 88.82%, respectively. In tailings, the lost nickel pyrite and chalcopyrite are mainly monomers. Therefore, strengthening the micro-fine particle recovery capacity is the key to increase recovery.

  11. An optimisation approach for culturing shear-sensitive dinoflagellate microalgae in bench-scale bubble column photobioreactors.

    Science.gov (United States)

    López-Rosales, L; García-Camacho, F; Sánchez-Mirón, A; Contreras-Gómez, A; Molina-Grima, E

    2015-12-01

    The dinoflagellate Karlodinium veneficum was grown in bubble column photobioreactors and a genetic algorithm-based stochastic search strategy used to find optimal values for the culture parameters gas flow rate, culture height, and nozzle sparger diameter. Cell production, concentration of reactive oxygen species (ROS), membrane fluidity and photosynthetic efficiency were studied throughout the culture period. Gas-flow rates below 0.26Lmin(-1), culture heights over 1.25m and a nozzle diameter of 1.5mm were found to provide the optimal conditions for cell growth, with an increase of 60% in cell production with respect to the control culture. Non-optimal conditions produced a sufficiently high shear stress to negatively affect cell growth and even produce cell death. Cell physiology was also severely affected in stressed cultures. The production of ROS increased by up to 200%, whereas cell membrane fluidity decreased by 60% relative to control cultures. Photosynthetic efficiency decreased concomitantly with membrane fluidity.

  12. The Design and Control of Distillation Column with Side Reactors for Chlorobenzene Production

    Institute of Scientific and Technical Information of China (English)

    薄翠梅; 汤吉海; 柏杨进; 乔旭; 丁良辉; 张湜

    2012-01-01

    The distillation column with side reactors (SRC) can overcome the temperature/pressure mismatch in the traditional reactive distillation, the column operates at temperature/pressure favorable for vapor-liquid separation, while the reactors operate at temperatures/pressures favorable for reaction kinetics. According to the smooth operation and automatic control problem of the distillation column with side reactors (SRC), the design, simulation calculation and dynamic control of the SCR process for chlorobenzene production are discussed in the paper. Firstly, the mechanism models, the integrated structure optimal design and process simulation systems are established, respectively. And then multivariable control schemes are designed, the controllability of SRC process based on the optimal steady-state integrated structure is explored. The dynamic response performances of closed-loop system against several disturbances are discussed to verify the effectiveness of control schemes for the SRC process. The simulating results show that the control structure using conventional control strategies can effectively overcome feeding disturbances in a specific range.

  13. Prediction of Gas Holdup in Bubble Columns Using Artificial Neural Network%用人工神经网络方法预测鼓泡塔气含率

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    A new correlation for the prediction of gas hold up in bubble columns was proposed based on an extensive experimental database set up from the literature published over last 30 years. The updated estimation method relying on artificial neural network, dimensional analysis and phenomenological approaches was used and the model prediction agreed with the experimental data with average relative error less than 10%.

  14. Three-phase gas-liquid-solid foaming bubble reactors and self-lubricated transport of bitumen froth

    Science.gov (United States)

    Mata, Clara E.

    Two distinct topics in multi-phase flow of interest of the oil industry are considered in this thesis. Studies of three-phase gas-liquid-solid foaming bubble reactors and self-lubricated transport of bitumen froth are reported. Applications of foams and foaming are found in many industrial processes such as flotation of minerals, enhanced oil recovery, drilling in oil reservoirs, and refining processes. However the physics of foaming and defoaming are not fully understood. Foams trap gas and are not desirable in some processes such as oil refining. Previously, it has been found that foaming may be strongly suppressed in a cold slit bubble reactor by fluidizing hydrophilic particles in the bubbly mixture below the foam. In this work, we fluidized hydrophobic and hydrophilic versions of two different sands in a cold slit foaming bubble reactor. We found that the hydrophobic sands suppress the foam substantially better than their hydrophilic counterparts. To study the capacity of foams to carry particles, we built a new slit foaming bubble reactor, which can be continuously fed with solid particles. Global gas, liquid, and solid holdups were measured for given gas and liquid velocities and solid flow rates. This research provides the fundamental ground work for the identification of flow types in a slit three-phase foaming bubble reactor with continuous injection of particles. Bitumen froth is produced from the oil sands of Athabasca, Canada. When transported in a pipeline, water present in the froth is released in regions of high shear (at the pipe wall). This results in a lubricating layer of water that allows bitumen froth pumping at greatly reduced pressures and hence the potential for savings in pumping energy consumption. Experimental results establishing the features of this self lubrication phenomenon are presented. The pressure gradient of lubricated flows closely follow the empirical law of Blasius for turbulent pipe flow with a constant of proportionality

  15. Physical Characteristics of Coffee Beans from Steaming Processin Single Column Reactor

    Directory of Open Access Journals (Sweden)

    Sukrisno Widyotomo

    2010-05-01

    Full Text Available One of important steps in decaffeination process is steaming. The aim of steaming is to expand coffee beans porosity in order to obtain optimal condition for decaffeination process. Steaming can be done in single column reactor using saturated water vapour as media. The objective of this research is to study physical characteristics of coffee beans after steaming process using single column reactor. Material tested was Robusta coffee with 13—14% moisture content after dry processing. Reactor capacity is 6 kg dried coffee beans and 30 l water to produce water vapour. Dried coffee beans classified in 4 grades, i.e. diameter size (d d>7,5 mm; 6,5column reactor, decaffeination.

  16. A pilot-scale jet bubbling reactor for wet flue gas desulfurization with pyrolusite

    Institute of Scientific and Technical Information of China (English)

    SU Shi-jun; ZHU Xiao-fan; LIU Yong-jun; JIANG Wen-ju; JIN Yan

    2005-01-01

    MnO2 in pyrolusite can react with SO2 in flue gas and obtain by-product MnSO4· H2 O. A pilot scale jet bubbling reactor was applied in this work. Different factors affecting both SO2 absorption efficiency and Mn2+ extraction rate have been investigated, these factors include temperature of inlet gas flue, ration of liquid/solid mass flow rate(L/S), pyrolusite grade, and SO2 concentration in the inlet flue gas. In the meantime, the procedure of purification of absorption liquid was also discussed. Experiment results indicated that the increase of temperature from 30 to 70 K caused the increase of SO2 absorption efficiency from 81.4% to 91.2%. And when SO2 concentration in the inlet flue gas increased from 500 to 3000 ppm, SO2 absorption efficiency and Mn2+ extraction rate decreased from 98.1% to 82.2% and from 82.8% to 61.7%, respectively. The content of MnO2 in pyrolusite had a neglectable effect on SO2 absorption efficiency. Low L/S was good for both removal of SO2 and Mn2+ extraction. The absorption liquid was filtrated and purified to remove Si,standards.

  17. Modeling and simulation of a pseudo-two-phase gas-liquid column reactor for thermal hydrocracking of petroleum heavy fractions

    Directory of Open Access Journals (Sweden)

    E.M. Matos

    2002-07-01

    Full Text Available This work presents a model to predict the behavior of velocity, gas holdup and local concentration fields in a pseudo-two-phase gas-liquid column reactor applied for thermal hydrocracking of petroleum heavy fractions. The model is based on the momentum and mass balances for the system, using an Eulerian-Eulerian approach. Using the k-epsilon model,fluid dynamics accounts for both laminar and turbulent flows, with discrete small bubbles (hydrogen flowing in a continuous pseudohomogeneous liquid phase (oil and catalyst particles. The petroleum is assumed to be a mixture of pseudocomponents, grouped by similar chemical structural properties, and the thermal hydrocracking is taken into account using a kinetic network based on these pseudocomponents.

  18. Safety Evaluation for Packaging for onsite Transfer of plutonium recycle test reactor ion exchange columns

    Energy Technology Data Exchange (ETDEWEB)

    Smith, R.J.

    1995-09-11

    The purpose of this Safety Evaluation for Packaging (SEP) is to authorize the use of three U.S. Department of Transportation (DOT) 7A, Type A metal boxes (Capital Industries Part No. S 0600-0600-1080- 0104) to package 12 Plutonium Recycle Test Reactor (PRTR) ion exchange columns as low-level waste (LLW). The packages will be transferred from the 309 Building in the 300 Area to low level waste burial in the 200 West Area. Revision 1 of WHC-SD-TP-SEP-035 (per ECN No. 621467) documents that the boxes containing ion exchange columns and grout will maintain the payload under normal conditions of transport if transferred without the box lids

  19. Process development of continuous hydrogen production by Enterobacter aerogenes in a packed column reactor

    Energy Technology Data Exchange (ETDEWEB)

    Palazzi, E.; Fabiano, B.; Perego, P. [DICheP Chemical and Process Engineering Department ' ' G.B. Bonino' ' , University of Genoa, Genoa (Italy)

    2000-03-01

    Hydrogen bioproduction from agro-industrial residues by Enterobacter aerogenes in a continuous packed column has been investigated and a complete reactor characterization is presented. Experimental runs carried out at different residence time, liable of interest for industrial application, showed hydrogen yields ranging from 1.36 to 3.02 mmol{sub H2}mmol{sup -1}{sub glucose} or, in other words, from 37.5% to 75% of the theoretical hydrogen yield. A simple kinetic model of cell growth, validated by experimental results and allowing the prediction of biomass concentration profile along the reactor and the optimization of superficial velocity, is suggested. By applying the developed approach to the selected operative conditions, the identification of the optimum superficial velocity v{sub 0,opt} of about 2.2 cm h{sup -1} corresponding to the maximum hydrogen evolution rate H{sub 2g,max}, was performed. (orig.)

  20. Thermal neutron flux distribution in ET-RR-2 reactor thermal column

    OpenAIRE

    Imam Mahmoud M.; Roushdy Hassan

    2002-01-01

    The thermal column in the ET-RR-2 reactor is intended to promote a thermal neutron field of high intensity and purity to be used for following tasks: (a) to provide a thermal neutron flux in the neutron transmutation silicon doping, (b) to provide a thermal flux in the neutron activation analysis position, and (c) to provide a thermal neutron flux of high intensity to the head of one of the beam tubes leading to the room specified for boron thermal neutron capture therapy. It was, therefore, ...

  1. New irradiation facility for biomedical applications at the RA-3 reactor thermal column.

    Science.gov (United States)

    Miller, M; Quintana, J; Ojeda, J; Langan, S; Thorp, S; Pozzi, E; Sztejnberg, M; Estryk, G; Nosal, R; Saire, E; Agrazar, H; Graiño, F

    2009-07-01

    A new irradiation facility has been developed in the RA-3 reactor in order to perform trials for the treatment of liver metastases using boron neutron capture therapy (BNCT). RA-3 is a production research reactor that works continuously five days a week. It had a thermal column with a small cross section access tunnel that was not accessible during operation. The objective of the work was to perform the necessary modifications to obtain a facility for irradiating a portion of the human liver. This irradiation facility must be operated without disrupting the normal reactor schedule and requires a highly thermalized neutron spectrum, a thermal flux of around 10(10) n cm(-2)s(-1) that is as isotropic and uniform as possible, as well as on-line instrumentation. The main modifications consist of enlarging the access tunnel inside the thermal column to the suitable dimensions, reducing the gamma dose rate at the irradiation position, and constructing properly shielded entrance gates enabled by logical control to safely irradiate and withdraw samples with the reactor at full power. Activation foils and a neutron shielded graphite ionization chamber were used for a preliminary in-air characterization of the irradiation site. The constructed facility is very practical and easy to use. Operational authorization was obtained from radioprotection personnel after confirming radiation levels did not significantly increase after the modification. A highly thermalized and homogenous irradiation field was obtained. Measurements in the empty cavity showed a thermal flux near 10(10) n cm(-2)s(-1), a cadmium ratio of 4100 for gold foils and a gamma dose rate of approximately 5 Gy h(-1).

  2. Gas Hold-Up, Mixing Time and Circulation Time in Internal Loop Airlift Bubble Column

    Directory of Open Access Journals (Sweden)

    Ali Abdul Rahman–Al Ezzi

    2014-01-01

    Full Text Available The effects of superficial gas in the riser (Vgr and liquid phase properties on the gas hold-up(ɛg , mixing time (Tm and circulation time (TC were studied in 8 liter internal air lift loop reactor (down comer-to-riser crosssectional area ratio = 0.249. Air was used as a gas phase. Water and four aqueous solutions of 10% concentration methanol, ethanol, (were used to simulate the behavior of non-coalescing organic liquids 50% glycerol and 2% Carboxy Methyl Cellulose (CMC were used to simulate the behavior of coalescing viscous liquids. Polyethylene-non-porous-solid particles with a concentration of (50 Kg/m3 were used as solid phase. Superficial gas velocity varied from 0.01 m/s to 0.1 m/s and air dispersed into the center of the draught tube by using a porous gas distributor. The results showed that (εg increased with increasing gas velocity and coalescence inhibition of liquid, while Tm and Tc decrease with increasing gas velocity. It was found that increasing liquid viscosity and coalescence reduces (εg but increases (Tm and (Tc. The gas holdup was correlated with dimensionless groups and independent parameter with correlation coefficient is 0.967, the following correlation is obtained.

  3. Hydrodynamic models for slurry bubble column reactors. Fifth technical progress report

    Energy Technology Data Exchange (ETDEWEB)

    Gidaspow, D.

    1995-10-01

    The objective of this work is to convert our `learning gas-solid-liquid` fluidization model into a predictive design model. The IIT hydrodynamic model computes the phase velocities and the volume fractions of gas, liquid, and particulate phases. Model verification involves a comparison of these computed velocities and volume fractions to experimental values.

  4. Characterization of factors influencing the growth of Anabaena variabilis in a bubble column reactor.

    Science.gov (United States)

    Yoon, Jong Hyun; Shin, Jong-Hwan; Park, Tai Hyun

    2008-03-01

    The combined effect of superficial gas velocity, pH, initial phosphate concentration, and light intensity on cell growth was investigated for the mass production of cyanobacterial cells. The light intensity was manipulated to maintain a specific irradiation rate (q(i)) at a constant level for high cell density culture. The optimum condition for the batch culture was achieved at a superficial gas velocity of 2.0 cm/s, pH 7.0, and an initial phosphate concentration of 55 mg/l when the specific irradiation rate was controlled above 11.5 micromol/s/g dry cell. In this condition, the specific growth rate and cell productivity were 1.47 day(-1) and 0.98 g dry cell/l/day, respectively.

  5. Decaffeination process characteristic of Robusta coffee in single column reactor using ethyl acetate solvent

    Directory of Open Access Journals (Sweden)

    Sukrisno Widyotomo

    2009-08-01

    Full Text Available Consumers drink coffee not as nutrition source, but as refreshment drink. For coffee consumers who have high tolerance for caffeine, coffee may warm up and refresh their bodies. High caffeine content in coffee beans may cause several complaints to consumers who are susceptible to caffeine. One of the efforts, for coffee market expansion is product diversification to decaffeinated coffee. Decaffeination process is one of process to reduce caffeine content from agricultural products. Indonesian Coffee and Cocoa Research Institute in collaboration with Bogor Agricultural University has developed a single column reactor for coffee beans decaffeination. The aim of this research is to study process characteristic of coffee decaffeination in single column reactor using ethyl acetate (C4H8O2 solvent. Treatments applicated in the research were time and temperature process. Temperature treatment were 50—60OC, 60—70OC, 70—80OC, 80—90OC and 90—100OC. Time treatment were 2 h, 4 h, 6 h, 8 h, 10 h, and 12 h Size of Robusta coffee beans used were less than 5.5 mm (A4, between 5.5 mm and 6.5 mm (A3, between 6.5 mm and 7.5 mm (A2, and more than 7.5 mm (A1. The result showed that decaffeination process with ethyl acetate solvent will be faster when its temperature was higher and smaller bean size. For bean size less than 5,5 mm, decaffeination process by 10% ethyl acetat can be done 8—10 hours in 90—100OC solvent temperature or 12 hours in 60—70OC solvent temperature for 0.3% caffein content. Organoleptic test showed that 90—100OC temperature solvent treatment decreased coffee flavor, which aroma, bitterness and body values were 1.9 each . Key words : Coffee, caffeine, decaffeination, quality, single column.

  6. Effect of liquid flow on culture of red beet hairy roots in single column reactor

    Energy Technology Data Exchange (ETDEWEB)

    Hitaka, Y.; Kino-oka, M.; Taya, M.; Tone, S. [Osaka University, Osaka (Japan). Department of Chemical Science and Engineering, Graduate School of Engineering Science

    1997-12-01

    The influence of liquid flow on the growth of red beet hairy roots is investigated by using a single column reactor operated at 25degC under a fixed value of superficial velocity of medium. In the cultures of the hairy roots for 172 - 190 h, average growth rates of 2.8 times 10{sup -2}, 1.6 times 10{sup -2} and 0.98 times 10{sup -2} kg/(m{sup 3}{center_dot}h) are obtained at superficial velocities of 4.2 times 10{sup -3}, 7.8 times 10{sup -3} and 11.1 times 10{sup -3} m/s, respectively. Using the packed column with the hairy roots at void fractions of 0.49 to 0.71, it is found that pressure drop through the root bed increases with an increase in superficial velocity of medium elevated up to about 14 times 10{sup -3} m/s. The effective diameter of the hairy roots is estimated at 1.5 times 10{sup -4}m, considering the root hairs found on the surfaces of the main roots. Pressure drop through the root bed in the column can be correlated with superficial velocity of the medium by using an extended Ergun`s equation expressed in terms of effective diameter of the hairy roots and void fraction in the bed. When the hairy roots are kept for 50 h in the column under pressure drop values of 8.4 times 10{sup 3} to 3.1 times 10{sup 4} Pa/m, the reduction in viability of growing points at the hairy root tips is observed with increasing pressure drop in the range. 18 refs., 7 figs., 1 tab.

  7. Blowing bubbles

    Energy Technology Data Exchange (ETDEWEB)

    Casteel, K.

    1999-04-01

    The article, based on a series of interviews with column flotation equipment suppliers, reviews and comments on the progress of bubble generator design. Developments mentioned include the Air/Water sparger from Cominco, the SparJet and SlamJet from CPT, the CISA sparger from Sevala CISA, Microcel flotation columns from Birtley Engineering, Flotaire column flotation cells from LMC International, and the Variable Gap Sparger from MinnovEX. 1 fig., 2 photo.

  8. Numerical simulation of the nonlinear ultrasonic pressure wave propagation in a cavitating bubbly liquid inside a sonochemical reactor.

    Science.gov (United States)

    Dogan, Hakan; Popov, Viktor

    2016-05-01

    We investigate the acoustic wave propagation in bubbly liquid inside a pilot sonochemical reactor which aims to produce antibacterial medical textile fabrics by coating the textile with ZnO or CuO nanoparticles. Computational models on acoustic propagation are developed in order to aid the design procedures. The acoustic pressure wave propagation in the sonoreactor is simulated by solving the Helmholtz equation using a meshless numerical method. The paper implements both the state-of-the-art linear model and a nonlinear wave propagation model recently introduced by Louisnard (2012), and presents a novel iterative solution procedure for the nonlinear propagation model which can be implemented using any numerical method and/or programming tool. Comparative results regarding both the linear and the nonlinear wave propagation are shown. Effects of bubble size distribution and bubble volume fraction on the acoustic wave propagation are discussed in detail. The simulations demonstrate that the nonlinear model successfully captures the realistic spatial distribution of the cavitation zones and the associated acoustic pressure amplitudes.

  9. Study on bubbly flow behavior in natural circulation reactor by thermal-hydraulic simulation tests with SF6-Gas and ethanol liquid

    Science.gov (United States)

    Kondo, Yoshiyuki; Suga, Keishi; Hibi, Koki; Okazaki, Toshihiko; Komeno, Toshihiro; Kunugi, Tomoaki; Serizawa, Akimi; Yoneda, Kimitoshi; Arai, Takahiro

    2009-02-01

    An advanced experimental technique has been developed to simulate two-phase flow behavior in a light water reactor (LWR). The technique applies three kinds of methods; (1) use of sulfur-hexafluoride (SF6) gas and ethanol (C2H5OH) liquid at atmospheric temperature and a pressure less than 1.0MPa, where the fluid properties are similar to steam-water ones in the LWR, (2) generation of bubble with a sintering tube, which simulates bubble generation on heated surface in the LWR, (3) measurement of detailed bubble distribution data with a bi-optical probe (BOP), (4) and measurement of liquid velocities with the tracer liquid. This experimental technique provides easy visualization of flows by using a large scale experimental apparatus, which gives three-dimensional flows, and measurement of detailed spatial distributions of two-phase flow. With this technique, we have carried out experiments simulating two-phase flow behavior in a single-channel geometry, a multi-rod-bundle one, and a horizontal-tube-bundle one on a typical natural circulation reactor system. Those experiments have clarified a) a flow regime map in a rod bundle on the transient region between bubbly and churn flow, b) three-dimensional flow behaviour in rod-bundles where inter-subassembly cross-flow occurs, c) bubble-separation behavior with consideration of reactor internal structures. The data have given analysis models for the natural circulation reactor design with good extrapolation.

  10. Energy Efficient Operation of Distillation Columns and a Reactor Applying Irreversible Thermodynamics

    Energy Technology Data Exchange (ETDEWEB)

    Koeijer, Gelein M. de

    2002-05-01

    minimisation. A method that can provide the chemical industry the thermodynamically optimum operation of distillation columns and reactors was constructed and exemplified. Once the system and its boundaries are determined, the objective function with its constraints and variables are set up. Several suitable minimisation procedures can be used. Finally, the design of the thermodynamically optimum system is obtained from the state of minimum entropy production rate. (author)

  11. Design of Mixed Batch Reactor and Column Studies at Oak Ridge National Laboratory

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Weimin [Stanford Univ., CA (United States); Criddle, Craig S. [Stanford Univ., CA (United States)

    2015-11-16

    We (the Stanford research team) were invited as external collaborators to contribute expertise in environmental engineering and field research at the ORNL IFRC, Oak Ridge, TN, for projects carried out at the Argonne National Laboratory and funded by US DOE. Specifically, we assisted in the design of batch and column reactors using ORNL IFRC materials to ensure the experiments were relevant to field conditions. During the funded research period, we characterized ORNL IFRC groundwater and sediments in batch microcosm and column experiments conducted at ANL, and we communicated with ANL team members through email and conference calls and face-to-face meetings at the annual ERSP PI meeting and national meetings. Microcosm test results demonstrated that U(VI) in sediments was reduced to U(IV) when amended with ethanol. The reduced products were not uraninite but unknown U(IV) complexes associated with Fe. Fe(III) in solid phase was only partially reduced. Due to budget reductions at ANL, Stanford contributions ended in 2011.

  12. Hydrocarbon-oil encapsulated bubble flotation of fine coal using 3-in. ID flotation column. Technical progress report for the eleventh quarter, April 1--June 30, 1993

    Energy Technology Data Exchange (ETDEWEB)

    Peng, F.F.

    1996-05-01

    There are four modes of the collector dispersion techniques. They are (1) direct liquid additions and stirring, (2) ultrasonic energy collector dispersion, (3) atomized collector dispersion, and (4) gasified collector transported in air stream. Among those collector dispersion techniques, the technique using the gasified collector transported in air phase can be used to enhance the flotation performance with substantial reduction in collector usage and selectivity, compared to the flotation using direct liquid addition (and mechanical agitation) technique. In this phase of study, two modes of collector addition techniques including gasified collector transported in gas phase and direct collector addition techniques were applied in the column flotation to demonstrate the selectivity of utilizing the hydrocarbon-oil encapsulated air bubbles in the fine coal flotation process. The 1-in. ID flotation column was used to scale-up to 3-in. ID flotation column. The initial starting point to operate the 3-in ID flotation column were determined using both 1-in. and 3-in. flotation columns based on the three phases of work plans and experiment design. A 3-in. flotation column was used to evaluate two modes of collector dispersion and addition techniques on the recovery and grade of fine coals using various ranks of coal.

  13. Treatment of Copper Contaminated Municipal Wastewater by Using UASB Reactor and Sand-Chemically Carbonized Rubber Wood Sawdust Column.

    Science.gov (United States)

    Biswas, Swarup; Mishra, Umesh

    2016-01-01

    The performance of a laboratory scale upflow anaerobic sludge blanket (UASB) reactor and its posttreatment unit of sand-chemically carbonized rubber wood sawdust (CCRWSD) column system for the treatment of a metal contaminated municipal wastewater was investigated. Copper ion contaminated municipal wastewater was introduced to a laboratory scale UASB reactor and the effluent from UASB reactor was then followed by treatment with sand-CCRWSD column system. The laboratory scale UASB reactor and column system were observed for a period of 121 days. After the posttreatment column the average removal of monitoring parameters such as copper ion concentration (91.37%), biochemical oxygen demand (BODT) (93.98%), chemical oxygen demand (COD) (95.59%), total suspended solid (TSS) (95.98%), ammonia (80.68%), nitrite (79.71%), nitrate (71.16%), phosphorous (44.77%), total coliform (TC) (99.9%), and fecal coliform (FC) (99.9%) was measured. The characterization of the chemically carbonized rubber wood sawdust was done by scanning electron microscope (SEM), X-ray fluorescence spectrum (XRF), and Fourier transforms infrared spectroscopy (FTIR). Overall the system was found to be an efficient and economical process for the treatment of copper contaminated municipal wastewater.

  14. Study on Bubble Size Measurement in Deinked Pulp Flotation Column%脱墨浆渣浮选柱气泡尺寸测量的研究

    Institute of Scientific and Technical Information of China (English)

    孙丽英; 田野; 李琼砚; 宋雪洁

    2011-01-01

    Bubble size plays an important role in wiping off ink particles and other contamination particles during the operation of deinked pulp flotation column. But bubble size measurement is a complicated problem because of multiple causes. In this paper, the dynamic bubble images are acquired from outside when the deinked pulp flotation column is working under existing experimental conditions. In order to improve the quality of the images, camera parameters and background lights are careful selected, and then graying, filtering, extracting edges and morphological processing are used to process the images. Finally, binary image is gotten, the bubble characteristics are extracted.The real area and equivalent diameter of the bubbles can be calculated through camera calibration, afterwards a basic statistical analysis on the distribution of bubble size is also done.%废纸脱墨浮选柱中的气泡大小对脱除废纸浆中的油墨颗粒和其他杂质颗粒的效率起着相当重要的作用,但是由于多种原因,浮选柱中气泡大小的测量是一个相当复杂的问题。本研究根据现有的试验条件,采用外部摄像的方法对浮选柱工作状态下的气泡进行了图像采集。由于气泡成像的特点,为提高图像的成像质量,对相机参数和背景光源进行了对比试验,并在此基础上对气泡的图像进行了灰度化、滤波、边缘提取以及数学形态学等处理,最后提取到具有气泡特征的二值图像。计算出了气泡的面积及当量直径,并对浮选柱中的气泡分布特征进行了初步的统计分析。

  15. Exploration of remediation of acid rock drainage with clinoptilolite as sorbent in a slurry bubble column for both heavy metal capture and regeneration.

    Science.gov (United States)

    Cui, Heping; Li, Loretta Y; Grace, John R

    2006-10-01

    Preliminary work was carried out to explore a novel process for high-efficiency high-capacity remediation of acid rock drainage. Zn and other metal ions were adsorbed and desorbed in a laboratory Plexiglas slurry bubble column with natural clinoptilolite particles as sorbent. The results indicate that both adsorption and desorption in this medium have considerable advantages over those in the packed beds and rotating columns, leading to faster batch adsorption and desorption, as well as greater uptake of zinc. The adsorption order of clinoptilolite particles to different metal ions appeared to be Fe>Al>Cu>Zn>Mg>Mn on the basis of normalized concentrations. Smaller particles had significantly higher capacity and rates of the adsorption than larger particles for the same operating conditions.

  16. A novel potential source of β-carotene: Eustigmatos cf. polyphem (Eustigmatophyceae) and pilot β-carotene production in bubble column and flat panel photobioreactors.

    Science.gov (United States)

    Li, Zhen; Ma, Xiaoqin; Li, Aifen; Zhang, Chengwu

    2012-08-01

    Carotenoids profile of the unicellular Eustigmatos cf. polyphem (Eustigmatophyceae) and β-carotene production of the microalga in bubble column and large flat panel bioreactors were studied. The microalga which contained β-carotene, violaxanthin and vaucheriaxanthin as the major carotenoids accumulated large amount of β-carotene. The β-carotene production of this microalga in the bubble column bioreactor was considerable, with the maximum intracellular β-carotene content reaching 60.76 mg g(-1), biomass reaching 9.2 g L(-1), and β-carotene yield up to 470.2 mg L(-1). The β-carotene productions in two large flat panel bioreactors were relatively lower, whereas over 100 mg β-carotene L(-1) was achieved. Besides, high light intensity helped to accumulate intracellular β-carotene and biomass. Deficient nitrate supply inhibited biomass growth, though it helped to accumulate β-carotene. Our results first proved that E. cf. polyphem was a potential source and producer of β-carotene, making it an interesting subject for further β-carotene study or commercial exploration.

  17. Co-Fuelling of Peat with Meat and Bone Meal in a Pilot Scale Bubbling Bed Reactor

    Directory of Open Access Journals (Sweden)

    Markku Orjala

    2010-07-01

    Full Text Available Co-combustion performance trials of Meat and Bone Meal (MBM and peat were conducted using a bubbling fluidized bed (BFB reactor. In the combustion performance trials the effects of the co-combustion of MBM and peat on flue gas emissions, bed fluidization, ash agglomeration tendency in the bed and the composition and quality of the ash were studied. MBM was mixed with peat at 6 levels between 15% and 100%. Emissions were predominantly below regulatory limits. CO concentrations in the flue gas only exceeded the 100 mg/m3 limit upon combustion of pure MBM. SO2 emissions were found to be over the limit of 50 mg/m3, while in all trials NOx emissions were below the limit of 300 mg/m3. The HCl content of the flue gases was found to vary near the limit of 30 mg/m3. VOCs however were within their limits. The problem of bed agglomeration was avoided when the bed temperature was about 850 °C and only 20% MBM was co-combusted. This study indicates that a pilot scale BFB reactor can, under optimum conditions, be operated within emission limits when MBM is used as a co-fuel with peat. This can provide a basis for further scale-up development work in industrial scale BFB applications.

  18. Removal of SO2 with particles of dolomite limestone powder in a binary fluidized bed reactor with bubbling fluidization

    Directory of Open Access Journals (Sweden)

    R. Pisani Jr.

    2003-06-01

    Full Text Available In this work, SO2 was treated by reaction with dolomite limestone (24 µm in a fluidized bed reactor composed of 500-590 µm sand particles. The influence of operating temperature (500, 600, 700 and 800ºC, superficial gas velocity (0.8, 1.0 and 1.2 m/s and Ca/S molar ratio (1, 2 and 3 on SO2 removal efficiency for an inlet concentration of 1000 ppm was examined. Removal of the pollutant was found to be dependent on temperature and Ca/S molar ratio, particularly at 700 and 800ºC. A maximum removal of 76% was achieved at a velocity of 0.8 m/s, a temperature of 800°C and a Ca/S of 3. The main residence time of the powder particles was determined by integrating normalized gas concentration curves as a function of time; the values found ranged from 4.1 to 14.4 min. It was concluded that the reactor operated in bubbling fluidization under every operational condition.

  19. Co-Fuelling of peat with meat and bone meal in a pilot scale bubbling bed reactor

    Energy Technology Data Exchange (ETDEWEB)

    McDonnell, K.; Cummins, E. J.; Fagan, C. C. [Biosystems Engineering, Bioresources Research Centre, UCD School of Agriculture, Food Science and Veterinary Medicine, Belfield, University College Dublin, Dublin 4 (Iran, Islamic Republic of); Orjala, M. [VTT Bioenergy, Koivurannantie, P.O. Box 1603, FIN- 40101 Jyvaeskylae (Finland)

    2010-07-15

    Co-combustion performance trials of Meat and Bone Meal (MBM) and peat were conducted using a bubbling fluidized bed (BFB) reactor. In the combustion performance trials the effects of the co-combustion of MBM and peat on flue gas emissions, bed fluidization, ash agglomeration tendency in the bed and the composition and quality of the ash were studied. MBM was mixed with peat at 6 levels between 15% and 100%. Emissions were predominantly below regulatory limits. CO concentrations in the flue gas only exceeded the 100 mg/m{sup 3} limit upon combustion of pure MBM. SO{sub 2} emissions were found to be over the limit of 50 mg/m{sup 3}, while in all trials NO{sub x} emissions were below the limit of 300 mg/m{sup 3}. The HCl content of the flue gases was found to vary near the limit of 30 mg/m{sup 3}. VOCs however were within their limits. The problem of bed agglomeration was avoided when the bed temperature was about 850 {sup o}C and only 20% MBM was co-combusted. This study indicates that a pilot scale BFB reactor can, under optimum conditions, be operated within emission limits when MBM is used as a co-fuel with peat. This can provide a basis for further scale-up development work in industrial scale BFB applications. (authors)

  20. Calibration of the borated ion chamber at NIST reactor thermal column.

    Science.gov (United States)

    Wang, Z; Hertel, N E; Lennox, A

    2007-01-01

    In boron neutron capture therapy and boron neutron capture enhanced fast neutron therapy, the absorbed dose of tissue due to the boron neutron capture reaction is difficult to measure directly. This dose can be computed from the measured thermal neutron fluence rate and the (10)B concentration at the site of interest. A borated tissue-equivalent (TE) ion chamber can be used to directly measure the boron dose in a phantom under irradiation by a neutron beam. Fermilab has two Exradin 0.5 cm(3) Spokas thimble TE ion chambers, one loaded with boron, available for such measurements. At the Fermilab Neutron Therapy Facility, these ion chambers are generally used with air as the filling gas. Since alpha particles and lithium ions from the (10)B(n,alpha)(7)Li reactions have very short ranges in air, the Bragg-Gray principle may not be satisfied for the borated TE ion chamber. A calibration method is described in this paper for the determination of boron capture dose using paired ion chambers. The two TE ion chambers were calibrated in the thermal column of the National Institute of Standards and Technology (NIST) research reactor. The borated TE ion chamber is loaded with 1,000 ppm of natural boron (184 ppm of (10)B). The NIST thermal column has a cadmium ratio of greater than 400 as determined by gold activation. The thermal neutron fluence rate during the calibration was determined using a NIST fission chamber to an accuracy of 5.1%. The chambers were calibrated at two different thermal neutron fluence rates: 5.11 x 10(6) and 4.46 x 10(7)n cm(-2) s(-1). The non-borated ion chamber reading was used to subtract collected charge not due to boron neutron capture reactions. An optically thick lithium slab was used to attenuate the thermal neutrons from the neutron beam port so the responses of the chambers could be corrected for fast neutrons and gamma rays in the beam. The calibration factor of the borated ion chamber was determined to be 1.83 x 10(9) +/- 5.5% (+/- 1sigma) n

  1. A composite reactor with wetted-wall column for mineral carbonation study in three-phase systems

    Science.gov (United States)

    Zhu, Chen; Yao, Xizhi; Zhao, Liang; Teng, H. Henry

    2016-11-01

    Despite the availability of various reactors designed to study gas-liquid reactions, no appropriate devices are available to accurately investigate triple-phased mineral carbonation reactions involving CO2 gas, aqueous solutions (containing divalent cations), and carbonate minerals. This report presents a composite reactor that combines a modified conventional wetted-wall column, a pH control module, and an attachment to monitor precipitation reactions. Our test and calibration experiments show that the absorption column behaved largely in agreement with theoretical predictions and previous observations. Experimental confirmation of CO2 absorption in NaOH and ethanolamine supported the effectiveness of the column for gas-liquid interaction. A test run in the CO2-NH3-MgCl2 system carried out for real time investigation of the relevant carbonation reactions shows that the reactor's performance closely followed the expected reaction path reflected in pH change, the occurrence of precipitation, and the rate of NH3 addition, indicating the appropriateness of the composite device in studying triple-phase carbonation process.

  2. Influence of ultrasound power on acoustic streaming and micro-bubbles formations in a low frequency sono-reactor: mathematical and 3D computational simulation.

    Science.gov (United States)

    Sajjadi, Baharak; Raman, Abdul Aziz Abdul; Ibrahim, Shaliza

    2015-05-01

    This paper aims at investigating the influence of ultrasound power amplitude on liquid behaviour in a low-frequency (24 kHz) sono-reactor. Three types of analysis were employed: (i) mechanical analysis of micro-bubbles formation and their activities/characteristics using mathematical modelling. (ii) Numerical analysis of acoustic streaming, fluid flow pattern, volume fraction of micro-bubbles and turbulence using 3D CFD simulation. (iii) Practical analysis of fluid flow pattern and acoustic streaming under ultrasound irradiation using Particle Image Velocimetry (PIV). In mathematical modelling, a lone micro bubble generated under power ultrasound irradiation was mechanistically analysed. Its characteristics were illustrated as a function of bubble radius, internal temperature and pressure (hot spot conditions) and oscillation (pulsation) velocity. The results showed that ultrasound power significantly affected the conditions of hotspots and bubbles oscillation velocity. From the CFD results, it was observed that the total volume of the micro-bubbles increased by about 4.95% with each 100 W-increase in power amplitude. Furthermore, velocity of acoustic streaming increased from 29 to 119 cm/s as power increased, which was in good agreement with the PIV analysis.

  3. Reliability of gas holdup measurements using the differential pressure method in a cyclone-static micro-bubble flotation column

    Institute of Scientific and Technical Information of China (English)

    Xia Wencheng; Yang Jianguo; Wang Yuling

    2011-01-01

    Gas holdup iS one of the Key parameters in flotation process.Gas holclup as measured by a differential pressure method was investigated and the relative errors compared to the average gas holdup from the volume expansion method.The errors were used to establish optimum measurement positions.The results show that the measurement position should be in the middle of the column and in the region half way from the center to the wall (the half-radius).The gas holdup along the axial direction is lower at the bottom and higher at the top of the floatation column.The gas holdup along the radial direction is lower near the wall and higher near the center of the flotation column.The average gas holdup measurement can be replaced bv regional gas holdup values.

  4. Catalytic wet air oxidation of coke-plant wastewater on ruthenium-based eggshell catalysts in a bubbling bed reactor.

    Science.gov (United States)

    Yang, M; Sun, Y; Xu, A H; Lu, X Y; Du, H Z; Sun, C L; Li, C

    2007-07-01

    Catalytic wet air of coke-plant wastewater was studied in a bubbling bed reactor. Two types of supported Ru-based catalysts, eggshell and uniform catalysts, were employed. Compared with the results in the wet air oxidation of coke-plant wastewater, supported Ru uniform catalysts showed high activity for chemical oxygen demand (COD) and ammonia/ammonium compounds (NH3-N) removal at temperature of 250 degrees C and pressure of 4.8 MPa, and it has been demonstrated that the catalytic activity of uniform catalyst depended strongly on the distribution of active sites of Ru on catalyst. Compared to the corresponding uniform catalysts with the same Ru loading (0.25 wt.% and 0.1 wt.%, respectively), the eggshell catalysts showed higher activities for CODcr removal and much higher activities for NH3-N degradation. The high activity of eggshell catalyst for treatment of coke-plant wastewater can be attributed to the higher density of active Ru sites in the shell layer than that of the corresponding uniform catalyst with the same Ru loading. It has been also evidenced that the active Ru sites in the internal core of uniform catalyst have very little or no contribution to CODcr and NH3-N removal in the total oxidation of coke-plant wastewater.

  5. Removal of NO from flue gas by aqueous chlorine-dioxide scrubbing solution in a lab-scale bubbling reactor

    Energy Technology Data Exchange (ETDEWEB)

    Deshwal, Bal Raj [Department of Chemistry, A.I.J.H.M. College, Rohtak 124001, Haryana (India); Jin, Dong Seop; Lee, Si Hyun; Moon, Seung Hyun [Korea Institute of Energy Research, Daejon 305 600 (Korea, Republic of); Jung, Jong Hyeon [Department of Environmental Engineering, Sorabol College, Kyungbuk - 780 711 (Korea, Republic of); Lee, Hyung Keun [Korea Institute of Energy Research, Daejon 305 600 (Korea, Republic of)], E-mail: hklee@kier.re.kr

    2008-02-11

    The present study attempts to clean up nitric oxide from the simulated flue gas using aqueous chlorine-dioxide solution in the bubbling reactor. Chlorine-dioxide is generated by chloride-chlorate process. Experiments are carried out to examine the effect of various operating variables like input NO concentration, presence of SO{sub 2}, pH of the solution and NaCl feeding rate on the NO{sub x} removal efficiency at 45 deg. C. Complete oxidation of nitric oxide into nitrogen dioxide occurred on passing sufficient ClO{sub 2} gas into the scrubbing solution. NO is finally converted into nitrate and ClO{sub 2} is reduced into chloride ions. A plausible reaction mechanism concerning NO{sub x} removal by ClO{sub 2} is suggested. DeNO{sub x} efficiency increased slightly with the increasing input NO concentration. The presence of SO{sub 2} improved the NO{sub 2} absorption but pH of solution showed marginal effect on NO{sub 2} absorption. NO{sub x} removal mechanism changed when medium of solution changed from acidic to alkaline. A constant NO{sub x} removal efficiency of about 60% has been achieved in the wide pH range of 3-11 under optimized conditions.

  6. A Laboratory Experiment To Measure Henry's Law Constants of Volatile Organic Compounds with a Bubble Column and a Gas Chromatography Flame Ionization Detector (GC-FID)

    Science.gov (United States)

    Lee, Shan-Hu; Mukherjee, Souptik; Brewer, Brittany; Ryan, Raphael; Yu, Huan; Gangoda, Mahinda

    2013-01-01

    An undergraduate laboratory experiment is described to measure Henry's law constants of organic compounds using a bubble column and gas chromatography flame ionization detector (GC-FID). This experiment is designed for upper-division undergraduate laboratory courses and can be implemented in conjunction with physical chemistry, analytical…

  7. Determination of Imidacloprid and metabolites by liquid chromatography with an electrochemical detector and post column photochemical reactor

    Energy Technology Data Exchange (ETDEWEB)

    Rancan, M. [Consiglio per la Ricerca e la Sperimentazione in Agricoltura (CRA), Istituto Nazionale di Apicoltura, Via di Saliceto 80, I-40128 Bologna (Italy)]. E-mail: mrancan@inapicoltura.org; Sabatini, A.G. [Consiglio per la Ricerca e la Sperimentazione in Agricoltura (CRA), Istituto Nazionale di Apicoltura, Via di Saliceto 80, I-40128 Bologna (Italy); Achilli, G. [Euroservice s.r.l., Piazza Maggiolini 3A, I-20015 Parabiago, Milan (Italy); Galletti, G.C. [Dipartimento di Chimica ' G.Ciamician' , University of Bologna, Via F. Selmi 2, I-40126 Bologna (Italy)

    2006-01-05

    A procedure for the determination of Imidacloprid and its main metabolites was set up by means of liquid chromatography with an electrochemical detector and post-column photochemical reactor (LC-h{nu}-ED). Sample clean-up was developed for bees, filter paper and maize leaves. Chromatographic conditions were based on a reversed-phase C-18 column operated by phosphate buffer 50 mM/CH{sub 3}CN (80/20, v/v) at pH 2.9. Detection of Imidacloprid and its metabolites was performed at a potential of 800 mV after photoactivation at 254 nm. Compared to conventional techniques such as gas chromatography/mass spectrometry (GC/MS) or LC coupled to other detectors, the present method allows simultaneous trace-level determination of both Imidacloprid (0.6 ng ml{sup -1}) and its main metabolites (2.4 ng ml{sup -1})

  8. Parameters measurement for the thermal neutron beam in the thermal column hole of Xi’an pulse reactor

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    The distribution of the neutron spectra in the thermal column hole of Xi’an pulse reactor was measured with the time-of-flight method.Compared with the thermal Maxwellian theory neutron spectra,the thermal neutron spectra measured is a little softer,and the average neutron energy of the experimental spectra is about 0.042±0.01 eV.The thermal neutron fluence rate at the front end of thermal column hole,measured with gold foil activation techniques,is about 1.18×105 cm-2 s-1.The standard uncertainty of the measured thermal neutron fluence is about 3%.The spectra-averaged cross section of 197Au(n,γ) determined by the experimental thermal neutron spectra is(92.8±0.93) ×10-24 cm2.

  9. Reactors

    CERN Document Server

    International Electrotechnical Commission. Geneva

    1988-01-01

    This standard applies to the following types of reactors: shunt reactors, current-limiting reactors including neutral-earthing reactors, damping reactors, tuning (filter) reactors, earthing transformers (neutral couplers), arc-suppression reactors, smoothing reactors, with the exception of the following reactors: small reactors with a rating generally less than 2 kvar single-phase and 10 kvar three-phase, reactors for special purposes such as high-frequency line traps or reactors mounted on rolling stock.

  10. Nonlinear analysis and prediction of time series in multiphase reactors

    CERN Document Server

    Liu, Mingyan

    2014-01-01

    This book reports on important nonlinear aspects or deterministic chaos issues in the systems of multi-phase reactors. The reactors treated in the book include gas-liquid bubble columns, gas-liquid-solid fluidized beds and gas-liquid-solid magnetized fluidized beds. The authors take pressure fluctuations in the bubble columns  as time series for nonlinear analysis, modeling and forecasting. They present qualitative and quantitative non-linear analysis tools which include attractor phase plane plot, correlation dimension, Kolmogorov entropy and largest Lyapunov exponent calculations and local non-linear short-term prediction.

  11. Microbial culture dynamics and chromium (VI) removal in packed-column microcosm reactors.

    Science.gov (United States)

    Molokwane, Pulane E; Nkhalambayausi-Chirwa, Evans M

    2009-01-01

    Microbial Cr(VI) reduction in groundwater aquifer media was investigated in microcosm reactors extracted from Cr(VI) contaminated sites in South Africa. The reactors were operated under an influent Cr(VI) concentration of 40 mg/L to simulate the current Cr(VI) level at the contaminated site. Near complete Cr(VI) removal was observed in microcosm reactors inoculated with Cr(VI) reducing bacteria from dried activated sludge collected from a treatment plant receiving periodic loadings of Cr(VI). The best performance was observed under low hydraulic loading (flow rate, Q=0.310 cm(3)/hr). Microbial culture characterisation results showed a change in culture composition after 17 days of reactor operation, indicating Bacillus and Lysinibacillus species as the most dominant organisms in reactors that reduced Cr(VI). The predominance of Bacillus and Lysinibacillus species was either due to resilience against toxicity or adaptation to the changing conditions in the reactor. This research was the initial step towards the development of an in situ bioremediation process to contain the spread of a Cr(VI) plume in a groundwater aquifer at contaminated site in Brits, South Africa. South Africa holds about 72% percent of the world's chromium resources, the majority of which is mined in the North Eastern region of the country formally known as Transvaal.

  12. 文丘里管反应器空化泡的动力学特性%Bubble dynamical behaviors in the Venturi cavitation reactor

    Institute of Scientific and Technical Information of China (English)

    沈壮志; 柳楠

    2012-01-01

    Numerical simulation on dynamical behaviors of the growth and collapse of bubble in Venturi cavitation reactor is obtained by the fourth Rung-Kutta method.The effect of turbulence,initial radius of cavitation bubble and upstream pressure on the cavitation bubble dynamics and the pressure pulse caused by collapse of cavitation bubble are analysed.The results show that pressure pulse amplitude is more bigger with turbulence than that to without turbulence;the smaller initial radius,the bigger pressure pulse is;and the inlet pressure variation on pressure pulse influence has a optimal value.%应用四阶Runge-Kutta法,对空泡径向非线性方程进行数值模拟,分析了文丘里管反应器内空泡的成长与溃灭特性以及湍流作用、空化泡初始半径、入口压力对空化泡运动特性与形成压力脉冲的影响规律.结果表明:在湍流作用下,气泡崩溃时压力脉冲远大于非湍流的效果,初始半径越小,压力脉冲越大,入口压力变化对压力脉冲影响有一最佳值.

  13. 射流鼓泡反应器的混合特性%Mixing characteristics in jet bubbling reactor

    Institute of Scientific and Technical Information of China (English)

    郭天琪; 黄正梁; 王靖岱; 蒋斌波; 阳永荣

    2015-01-01

    射流鼓泡反应器以液体射流代替搅拌实现液相混合,具有结构简单、制造及维护费用低等诸多优点,研究其混合特性对于反应器的设计、优化及放大具有重要意义。以空气-水作为模拟介质,采用KCl电解质溶液为示踪剂考察了表观气速和射流Reynolds数的大小对液相宏观混合时间的影响,并从能量输入的角度对射流鼓泡反应器的混合机制进行分析。研究发现,在实验条件下(表观气速变化范围为0.0006~0.0343 m·s−1,射流Reynolds数的变化范围为1.75×104~7.00×104),鼓泡的加入使得均相射流反应器内的液相混合得到改善;随着表观气速增大,液相宏观混合时间先缩短后延长;当气体输入功率或液体输入功率不变时,混合时间随总输入功率的增大而缩短。通过对多组实验数据的回归分析,提出了液相宏观混合时间与液体输入功率和气体输入功率的经验关联式,计算值与实际值吻合较好。最后基于提出的关联式,发现当总输入功率一定时,混合时间随气体输入功率的增加先缩短后延长,临界转变点在气体输入功率为总功率的61%处,此时气液两相协同作用最强。%The jet bubbling reactor uses liquid jet to achieve the liquid mixing instead of mechanical stirring, which brings several advantages such as simple structure and low cost of maintenance and manufacturing. The research of its mixing characteristics plays a significant role in the design, optimization and scaling up of the reactor. Based on the air-water system, the electrolyte tracer (KCl solution) method was applied to investigate the influences of gas velocity and jet Reynolds number on the liquid mixing time with the cold model experimental apparatus. The mixing mechanism in jet bubbling reactor had also been analyzed from the perspective of power input. The results showed that within the experimental range (ugfrom 0

  14. Use of a pulsed column contactor as a continuous oxalate precipitation reactor

    Energy Technology Data Exchange (ETDEWEB)

    Borda, Gilles, E-mail: gilles.borda@cea.f [Commissariat a l' Energie Atomique, Nuclear Energy Division, Fuel Cycle Technology Department, BP17171, F 30207 Bagnols sur Ceze Cedex (France); Brackx, Emmanuelle; Boisset, Laurence; Duhamet, Jean [Commissariat a l' Energie Atomique, Nuclear Energy Division, Fuel Cycle Technology Department, BP17171, F 30207 Bagnols sur Ceze Cedex (France); Ode, Denis, E-mail: denis.ode@cea.f [Commissariat a l' Energie Atomique, Nuclear Energy Division, Fuel Cycle Technology Department, BP17171, F 30207 Bagnols sur Ceze Cedex (France)

    2011-03-15

    Research highlights: {yields} A new type of continuous precipitating device was patented by CEA and tested with reaction between a surrogate nitrate cerium(III) or neodymium(III) and oxalate complexing agent. {yields} Precipitate is confined in aqueous phase emulsion in tetrapropylene hydrogen and does not form deposit on the vessel walls. {yields} Measure size of the precipitate ranges from 20 to 40 {mu}m, it meets the process requirements to filter, and the precipitation reaction is complete. {yields} The laboratory design can be extrapolated to an industrial uranium(IV) and minor actinide(III) coprecipitating column. - Abstract: The current objective of coprecipitating uranium, and minor actinides in order to fabricate a new nuclear fuel by direct (co)precipitation for further transmutation, requires to develop specific technology in order to meet the following requirements: nuclear maintenance, criticity, and potentially high flowrates due to global coprecipitation. A new type of device designed and patented by the CEA was then tested in 2007 under inactive conditions and with uranium. The patent is for organic confinement in a pulsed column (PC). Actually, pulsed columns have been working for a long time in a nuclear environment, as they allow high capacity, sub-critical design (annular geometry) and easy high activity maintenance. The precipitation reaction between the oxalate complexing agent and a surrogate nitrate - cerium(III) or neodymium(III) alone, or coprecipitated uranium(IV) and cerium(III) - occurs within an emulsion created in the device by these two phases flowing with a counter-current chemically inert organic phase (for example tetrapropylene hydrogen-TPH) produced by the stirring action of the column pulsator. The precipitate is confined and thus does not form deposits on the vessel walls (which are also water-repellent); it flows downward by gravity and exits the column continuously into a settling tank. The results obtained for precipitation

  15. Dynamic Modeling and Control Studies of a Two-Stage Bubbling Fluidized Bed Adsorber-Reactor for Solid-Sorbent CO{sub 2} Capture

    Energy Technology Data Exchange (ETDEWEB)

    Modekurti, Srinivasarao; Bhattacharyya, Debangsu; Zitney, Stephen E.

    2013-07-31

    A one-dimensional, non-isothermal, pressure-driven dynamic model has been developed for a two-stage bubbling fluidized bed (BFB) adsorber-reactor for solid-sorbent carbon dioxide (CO{sub 2}) capture using Aspen Custom Modeler® (ACM). The BFB model for the flow of gas through a continuous phase of downward moving solids considers three regions: emulsion, bubble, and cloud-wake. Both the upper and lower reactor stages are of overflow-type configuration, i.e., the solids leave from the top of each stage. In addition, dynamic models have been developed for the downcomer that transfers solids between the stages and the exit hopper that removes solids from the bottom of the bed. The models of all auxiliary equipment such as valves and gas distributor have been integrated with the main model of the two-stage adsorber reactor. Using the developed dynamic model, the transient responses of various process variables such as CO{sub 2} capture rate and flue gas outlet temperatures have been studied by simulating typical disturbances such as change in the temperature, flowrate, and composition of the incoming flue gas from pulverized coal-fired power plants. In control studies, the performance of a proportional-integral-derivative (PID) controller, feedback-augmented feedforward controller, and linear model predictive controller (LMPC) are evaluated for maintaining the overall CO{sub 2} capture rate at a desired level in the face of typical disturbances.

  16. Studies on hydrodynamics of turbulent slurry bubble column ( Ⅴ )Modeling of bubble column with multi-layer screens%湍动浆态床流体力学研究(Ⅴ)带多层水平网格构件的浆态床流体力学模型

    Institute of Scientific and Technical Information of China (English)

    张煜; 李兆奇; 李红波; 王丽军; 李希

    2012-01-01

    Screen is one of the simplest resistance internals for improving the radial profile of axial velocity in a bubble column. In this paper the profiles of axial liquid velocity and gas hold up along the radius of φ500 mm X 5000 mm bubble column with multi-layer screens were measured by Pavlov tube and conductivity probe respectively. The experimental observations showed that the lateral screen internals could remarkably reduce the ascending liquid velocity in the core region, resulting in improvement of flow profiles. The smaller the screen hole, the more remarkable the resistance effect, and the higher the average gas hold up. A one dimensional CFD model similar to that of pipe bundle internals was developed, and the damping effect of screen internals on the liquid was regarded as the volumetric source of momentum, turbulent kinetic energy and dissipation. The values of parameters in the turbulent energy dissipation equation were different from the model of pipe bundle internals, and they were estimated as c3 =2. 0, c4 = 1. 3 by comparison with experimental data. The present model provided an effective tool in simulation of damping effect of multi-layer screens internals in bubble columns.%水平布置的多层筛网是最简单的阻尼型内构件,用于改善流动分布.在安装多层筛网的(φ)500 mm×5000mm鼓泡塔冷模装置中进行了流速分布与气含率分布测定.实验表明,网格型内构件可以有效抑制塔中心区过快上升的流速,改善其分布.网孔越小,流动阻尼效果越明显,同时平均气含率也会有所增大.提出了与列管内构件相似的一维流体力学模型,将网格型内构件对流体的阻尼效果作为体积源来考虑,湍流耗散方程中的参数值c3=2.0、c4 =1.3,与列管束内构件略有不同.模型计算与实验数据符合良好,能够定量描述网格型阻尼内构件对流场的影响.

  17. Energy efficient electrocoagulation using a new flow column reactor to remove nitrate from drinking water - Experimental, statistical, and economic approach.

    Science.gov (United States)

    Hashim, Khalid S; Shaw, Andy; Al Khaddar, Rafid; Pedrola, Montserrat Ortoneda; Phipps, David

    2017-03-09

    In this investigation, a new bench-scale electrocoagulation reactor (FCER) has been applied for drinking water denitrification. FCER utilises the concepts of flow column to mix and aerate the water. The water being treated flows through the perforated aluminium disks electrodes, thereby efficiently mixing and aerating the water. As a result, FCER reduces the need for external stirring and aerating devices, which until now have been widely used in the electrocoagulation reactors. Therefore, FCER could be a promising cost-effective alternative to the traditional lab-scale EC reactors. A comprehensive study has been commenced to investigate the performance of the new reactor. This includes the application of FCER to remove nitrate from drinking water. Estimation of the produced amount of H2 gas and the yieldable energy from it, an estimation of its preliminary operating cost, and a SEM (scanning electron microscope) investigation of the influence of the EC process on the morphology of the surface of electrodes. Additionally, an empirical model was developed to reproduce the nitrate removal performance of the FCER. The results obtained indicated that the FCER reduced the nitrate concentration from 100 to 15 mg/L (World Health Organization limitations for infants) after 55 min of electrolysing at initial pH of 7, GBE of 5 mm, CD of 2 mA/cm(2), and at operating cost of 0.455 US $/m(3). Additionally, it was found that FCER emits H2 gas enough to generate a power of 1.36 kW/m(3). Statistically, the relationship between the operating parameters and nitrate removal could be modelled with R(2) of 0.848. The obtained SEM images showed a large number dents on anode's surface due to the production of aluminium hydroxides.

  18. The role of acid incubation in rapid immobilization of hydrogen-producing culture in anaerobic upflow column reactors

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Zhen-Peng; Tay, Joo-Hwa [School of Civil and Environmental Engineering, Nanyang Technological University (Singapore); Institute of Environmental Science and Engineering, Nanyang Technological University (Singapore); Show, Kuan-Yeow [Faculty of Science, Engineering and Technology, University Tunku Abdul Rahman, 31900 Kampar, Perak (Malaysia); Liang, David Tee [Institute of Environmental Science and Engineering, Nanyang Technological University (Singapore); Lee, Duu-Jong [Department of Chemical Engineering, National Taiwan University, Taipei 10617 (China); Su, Ay [Department of Mechanical Engineering, Fuel Cell Center, Yuan-Ze University, Taoyuan 320 (China)

    2008-10-15

    An approach of acidification was examined on formation of hydrogen-producing granules and biofilms in upflow column-shaped reactors. The reactors were fed with synthetic glucose wastewater and operated at 37 C and pH 5.5. The acclimated anaerobic culture was inoculated in four reactors designated R1, R2, R3 and R4, with R3 and R4 filled with granular activated carbon as support medium. To unveil the roles of acidification, microbial culture in R2 and R3 was subject to an acid incubation for 24 h by shifting the culture pH from 5.5 to 2.0. The experimental results suggested that the acidification substantially accelerated microbial granulation, but not biofilm formation. Microbial activities were inhibited by the acid incubation for about 78 h, resulting in the retarded formation of biofilms of the acidified culture. Reducing culture pH resulted in improvement in cell surface physicochemical properties favoring microbial adhesion and immobilization. Zeta potential increased from -25.3 mV to 11.9 mV, hydrophobicity in terms of contact angle improved from 31 to 38 and production of extracellular polymers increased from 66 mg/g-VSS to 136 mg/g-VSS. As a result of the formation of granules and biofilms, high hydrogen production rates of 6.98 and 7.49 L/L h were achieved in granule-based and biofilm-based reactors, respectively. It is concluded that acid incubation is an efficient means to initiate the rapid formation of granules by regulating the surface characteristics of microbial culture. The use of support media as starting nuclei may result in rapid formation of biofilms without the acidification. (author)

  19. Aluminum colloid formation and its effect on co-precipitation of zinc during acid rock drainage remediation with clinoptilolite in a slurry bubble column

    Science.gov (United States)

    Xu, W.; Li, L. Y.; Grace, J. R.

    2012-04-01

    Zinc and other metal ions were adsorbed in a laboratory slurry bubble column (SBC) by natural clinoptilolite sorbent particles. During the remediation process, significant white precipitates were sometimes observed. Both zinc and aluminum were detected in the colloidal mixtures. It is shown that Al leached from clinoptilolite during the agitation, contributing to the precipitate. As a result of the Al leaching and increase of pH during the remediation process, the formation of an Al colloid and zinc adsorption onto it could significantly improve ARD remediation, given the high adsorption capacity of the colloid. Sorption of cations increased with increasing colloid formation. Various conditions were tested to investigate their impact on (a) dealumination of clinoptilolite; (b) Al hydrolysis/colloid formation; and (c) adsorption onto the colloidal mixture. The test results indicate that dealumination contributes to the excess aluminum in the aqueous phase and to precipitates. The excess dealumination varies with pH and agitation time. Al hydrolysis occurs with increasing pH due to the neutralization effect of clinoptilolite. A significant proportion of zinc adsorbed onto the collectible aluminum precipitates.

  20. Contactless measurement of phase and concentration distributions in bubble columns using positron emitting radionuclides; Beruehrungslose Messung von Phasen- und Konzentrationsverteilungen in Blasensaeulen mit positronenemittierenden Radionukliden

    Energy Technology Data Exchange (ETDEWEB)

    Zippe, C.; Hoppe, D.; Fietz, J.; Hampel, U.; Hensel, F.; Maeding, P.; Prasser, H.M.; Zippe, W.

    2003-09-01

    Positron emission tomography (PET) is a well-established method for studying metabolic processes in humans and in use as a medical diagnostic procedure (metabolism, blood perfusion, metastasis detection). The present project was dedicated to a nonmedical application of this imaging method, namely to the development and use of a PET tomograph for studying the behaviour of foam in bubble columns on the ''SchaumPET'' test stand. This paper deals in particular with the technical realisation of the project and the image acquisition methods used. The capacity of positron emission tomography to detect the accumulation of a surfactant in a foam layer is demonstrated for the example of sodium capronate. [German] Die Positronen-Emissions-Tomographie (PET) ist eine etablierte Untersuchungsmethode zur Untersuchung von Stoffwechselvorgaengen im Menschen und wird als medizinisches Diagnoseverfahren (Stoffwechsel, Durchblutung, Metastasenerkennung) eingesetzt. Dieses Projekt beschaeftigt sich mit einer nichtmedizinischen Anwendung dieses bildgebenden Verfahrens - dem Aufbau und der Anwendung eines PET-Tomographen zur Untersuchung des Verhaltens von Schaum in Blasensaeulen, dem Versuchsstand SchaumPET. Insbesondere wird auf die technische Realisierung des Projektes und die angewendeten Verfahren zur Bildgewinnung eingegangen. Am Beispiel von Natriumcapronat wird gezeigt, dass sich die Anreicherung eines Tensids in einer Schaumschicht mit der Positronen-Emissions-Tomographie nachweisen laesst. (orig.)

  1. Performance of Inclined Baffle Column for Pectin Continuous Extraction Process from Cocoa Peel (Theobromacacao

    Directory of Open Access Journals (Sweden)

    Soemargono

    2016-01-01

    Full Text Available Pectin from cocoa peel was successfully prepared by extraction method in the bubble column reactor. The process could be carried out in batch and continuous, with co-current or counter current flow. Bubble pipe reactor with inclined baffle is expected to reduce the problem from gas flow patterns, jagged sloping bulkhead serves as a bubble breaker that could replace mechanical stirrer. In this study the reactor column sloping bulkhead was used as extractor to recover pectin in the cocoa peel by citric acid (1 N solvent. Cocoa peel paste and citric acid were entered to the top of the column at 1 : 1 rate ratio by streamed using dosing pump. Nitrogen gas as a medium stirrer flowed counter current from the bottom of the column. Once extraction was completed, the liquid then precipitated by acid alcohol. Pectin solids were washed with alcohol (96%. The temperature of extraction process is maintained at 70° C. The residence time in the column material was determined by feed flow rate (cocoa paste and citric acid, and the volume of suspension that remains in the reactor (V. Residence time equation obtained is: t = (7045.86G-0.1275/L. The yield of yellowish white precipitate reached up to 5.2973% and methoxyl concentration reached 5,21% for 72 minutes. The experiment shows that the continuous extraction process of pectin in baffle columns is better than batch process.

  2. Hydrodynamic causes and effects of air bubbles rising in very viscous media

    CERN Document Server

    Ravinuthala, Sharad Chand

    2013-01-01

    Detailed understanding of two-phase gas liquid flows is imperative for developing efficient multi-phase reactors through precise control of mixing and reaction kinetics. The bubble column is a good apparatus for elementary studies of such flows. In the current study experiments are conducted to assess the effect of liquid viscosity on flow dynamics inside a bubble column. Corn oil and water are used as the continuous media, and air was the dispersed media. The objective of this effort is to use the results for a qualitative validation of the numerical simulations.

  3. Effects of reactor type and mass transfer on the morphology of CuS and ZnS crystals

    NARCIS (Netherlands)

    Al-Tarazi, Mousa; Heesink, A. Bert M.; Versteeg, Geert F.

    2005-01-01

    For the precipitation of CuS and ZnS, the effects of the reactor/precipitator type, mass transfer and process conditions on crystal morphology were studied. Either H2S gas or a S2- solution were applied. Three different types of reactors have been tested, namely a laminar jet, a bubble column and an

  4. Iron removal, energy consumption and operating cost of electrocoagulation of drinking water using a new flow column reactor.

    Science.gov (United States)

    Hashim, Khalid S; Shaw, Andy; Al Khaddar, Rafid; Pedrola, Montserrat Ortoneda; Phipps, David

    2017-03-15

    The goal of this project was to remove iron from drinking water using a new electrocoagulation (EC) cell. In this research, a flow column has been employed in the designing of a new electrocoagulation reactor (FCER) to achieve the planned target. Where, the water being treated flows through the perforated disc electrodes, thereby effectively mixing and aerating the water being treated. As a result, the stirring and aerating devices that until now have been widely used in the electrocoagulation reactors are unnecessary. The obtained results indicated that FCER reduced the iron concentration from 20 to 0.3 mg/L within 20 min of electrolysis at initial pH of 6, inter-electrode distance (ID) of 5 mm, current density (CD) of 1.5 mA/cm(2), and minimum operating cost of 0.22 US $/m(3). Additionally, it was found that FCER produces H2 gas enough to generate energy of 10.14 kW/m(3). Statistically, it was found that the relationship between iron removal and operating parameters could be modelled with R(2) of 0.86, and the influence of operating parameters on iron removal followed the order: C0>t>CD>pH. Finally, the SEM (scanning electron microscopy) images showed a large number of irregularities on the surface of anode due to the generation of aluminium hydroxides.

  5. On the interaction of Taylor bubbles rising in two-phase co-current slug flow in vertical columns: turbulent wakes

    Energy Technology Data Exchange (ETDEWEB)

    Pinto, A.M.F.R.; Campos, J.B.L. [Centro de Estudos de Fenomenos de Transporte, Universidade do Porto Rua (Portugal); Coelho Pinheiro, M.N. [Dept. de Engenharia Quimica, Politecnico de Coimbra (Portugal)

    2001-12-01

    An experimental study on the interaction between Taylor bubbles rising through a co-current flowing liquid in a vertical tube with 32 mm of internal diameter is reported. The flow pattern in the bubble's wake was turbulent and the flow regime in the liquid slug was either turbulent or laminar. When the flow regime in the liquid slug is turbulent (i) the minimum distance between bubbles above which there is no interaction is 5D-6D; (ii) the bubble's rising velocity is in excellent agreement with the Nicklin relation; (iii) the experimental values of the bubble length compare well with theoretical predictions (Barnea 1990); (iv) the distance between consecutive bubbles varied from 13D to 16D and is insensitive to the liquid Reynolds number. When the flow regime in the liquid slug is laminar (i) the wake length is about 5D-6D; (ii) the minimum distance between bubbles above which there is no interaction is higher than 25D; (iii) the bubble's rising velocity is significantly smaller than theoretical predictions. These results were explained in the light of the findings of Pinto et al. (1998) on coalescence of two Taylor bubbles rising through a co-current liquid. (orig.)

  6. VELOCITY AND CONCENTRATION OF BUBBLES IN OZONIZATION COLUMNS WITH CROSS SECTIONS OF DIFFERENT SIZES VELOCIDAD Y CONCENTRACIÓN DE BURBUJAS EN COLUMNAS DE OZONIZACIÓN CON SECCIÓN TRANSVERSAL DE TAMAÑOS DIVERSOS

    Directory of Open Access Journals (Sweden)

    Marcio Ricardo Salla

    2008-12-01

    Full Text Available The size of the cross section of an ozonization column influences its hydrodynamic characteristics, which, on its turn, has effects on phenomena that depend on the relative movement between gas bubbles and liquid. To observe the influence of the cross sectional area on gas concentration and bubbles velocity, two columns were used. The first column had a square cross section with side of 0.19m and the second had a circular cross section with diameter of 0.10 m. The ascendant velocities of the bubbles and their concentration were measured in both columns and compared. The transversal spread of the plumes of bubbles was also quantified. The results show that the increase of the cross section of the column, in the proportion studied here, does not result in a similar increase of the cross section of the ascending plume of bubbles. Furthermore, the results of average velocities and concentrations obtained for the smallest cross section resulted independent of the liquid level in the column, while the results for the largest cross section showed to be dependent of this level. The ratio between the cross sectional areas of the larger and the smaller plumes of bubbles decreases for higher distances to the bottom of the columns.La sección transversal de una columna de ozonización posee influencia directa sobre las características hidrodinámicas de esa columna, lo que se refleja en los fenómenos que dependen de la transferencia de masa en la interfase gas-líquido. En este estudio se utilizaron dos columnas con secciones transversales diferentes cuanto a la forma y al tamaño. La primera con sección transversal cuadrada de 0,19m y la segunda con sección transversal circular de 0,10 m de diámetro. Se midieron las velocidades ascensionales de las burbujas y su concentración. Los resultados obtenidos muestran que el aumento de la sección transversal en la proporción aquí estudiada no conlleva un aumento semejante de la sección transversal de la

  7. Simultaneous measurement of local particle movement, solids concentrations and bubble properties in fluidized bed reactors using a novel fiber optical technique

    Energy Technology Data Exchange (ETDEWEB)

    Tayebi, Davoud

    1998-12-31

    This thesis develops a new method for simultaneous measurements of local flow properties in highly concentrated multiphase flow systems such as gas-solid fluidized bed reactors. The method is based on fiber optical technique and tracer particles. A particle present in the measuring volume in front of the probe is marked with a fluorescent dye. A light source illuminates the particles and the detecting fibres receive reflected light from uncoated particles and fluorescent light from the tracer particle. Using optical filters, the fluorescent light can be distinguished and together with a small fraction of background light from uncoated particles can be used for determination of local flow properties. Using this method, one can simultaneously measure the local movement of a single tracer particle, local bubble properties and the local solids volume fractions in different positions in the bed. The method is independent of the physical properties of the tracer particles. It is also independent of the local solids concentrations in the range of 0 to 60 vol.-%, but is mainly designed for highly concentrated flow systems. A computer programme that uses good signals from at least three sensors simultaneously to calculate the tracer particle velocity in two dimensions have been developed. It also calculates the bubble properties and local solids volume fractions from the same time series. 251 refs., 150 figs., 5 tabs.

  8. Mathematical modeling of a slurry reactor for DME direct synthesis from syngas

    Institute of Scientific and Technical Information of China (English)

    Sadegh Papari; Mohammad Kazemeini; Moslem Fattahi

    2012-01-01

    In this paper,an axial dispersion mathematical model is developed to simulate a three-phase slurry bubble column reactor for direct synthesis of dimethyl ether (DME) from syngas.This large-scale reactor is modeled using mass and energy balances,catalyst sedimentation and single-bubble as well as two-bubbles class flow hydrodynamics.A comparison between the two hydrodynamic models through pilot plant experimental data from the literature shows that heterogeneous two-bubbles flow model is in better agreement with the experimental data than homogeneous single-bubble gas flow model.Also,by investigating the heterogeneous gas flow and axial dispersion model for small bubbles as well as the large bubbles and slurry (i.e.including paraffins and the catalyst) phase,the temperature profile along the reactor is obtained.A comparison between isothermal and non-isothermal reactors reveals no obvious performance difference between them.The optimum values of reactor diameter and height were obtained at 7 m and 50 m,respectively.The effects of operating variables on the axial catalyst distribution,DME productivity and CO conversion are also investigated in this research.

  9. Study on pilot experiment of selective copper flotation by cyclone static micro- bubble flotation column%旋流-静态微泡浮选柱部分优先选铜半工业试验研究

    Institute of Scientific and Technical Information of China (English)

    邓小伟; 李延峰; 王永田; 程敢

    2011-01-01

    The cyclone static micro-bubble flotation column is a kind of new facility for mineral separation. In order to improve the productivity of a high silver-content metallic ore and reduce the pressure of posterior operation, the pilot experiment of selective copper flotation is carried out by using the cyclone static micro- bubble flotation column. Through the process of single-stage roughing and two-stage cleaning, the grade of copper, gold, sliver reach 18%, 60 g/t, 6 000 g/t, and the recovery rate reaches above 50%. It provides foundations for the production and the technical improvement in enterprises.%旋流-静态微泡浮选柱是一种新型选矿设备,为了提高某银多金属矿生产效率,减小后续作业压力,采用该浮选柱进行了部分优先选铜半工业试验。通过一粗两精闭路流程试验研究,可得到铜、金、银品位分别为18%、60g/t、6000g/t,回收率50%以上的结果,为企业生产和技术改造提供了依据。

  10. Study on size upper limit of grain processed by hydrocyclone micro-bubble flotation column%旋流微泡浮选柱浮选粒度上限研究

    Institute of Scientific and Technical Information of China (English)

    郭柱; 谢广元; 董玉蛟; 许光前

    2011-01-01

    简要介绍了选煤厂存在的浮选入料粒度过粗的问题,分析了旋流微泡浮选柱的分选原理,开创性地采用小于0.7 mm煤泥作为入料,通过浮选试验、正交试验分析了各个因素对粗粒回收效果的影响,为指导旋流微泡浮选柱现场生产应用提供理论支持.%The problem that oversize grain size is fed into the flotation process is introduced, and the separa tion principle of the hydrocyclone micro-bubble notation column is analyzed. The coal slime whose size is less than 0.7 mm is creatively taken to serve as feeding material to carry out flotation tests and orthogonal tests, and the influence of each factor on recovery of coarse grains is analyzed, which offers theoretical support for guid ing the field operation of the hydrocyclone micro-bubble flotation column.

  11. Bubbling bed catalytic hydropyrolysis process utilizing larger catalyst particles and smaller biomass particles featuring an anti-slugging reactor

    Science.gov (United States)

    Marker, Terry L; Felix, Larry G; Linck, Martin B; Roberts, Michael J

    2014-09-23

    This invention relates to a process for thermochemically transforming biomass or other oxygenated feedstocks into high quality liquid hydrocarbon fuels. In particular, a catalytic hydropyrolysis reactor, containing a deep bed of fluidized catalyst particles is utilized to accept particles of biomass or other oxygenated feedstocks that are significantly smaller than the particles of catalyst in the fluidized bed. The reactor features an insert or other structure disposed within the reactor vessel that inhibits slugging of the bed and thereby minimizes attrition of the catalyst. Within the bed, the biomass feedstock is converted into a vapor-phase product, containing hydrocarbon molecules and other process vapors, and an entrained solid char product, which is separated from the vapor stream after the vapor stream has been exhausted from the top of the reactor. When the product vapor stream is cooled to ambient temperatures, a significant proportion of the hydrocarbons in the product vapor stream can be recovered as a liquid stream of hydrophobic hydrocarbons, with properties consistent with those of gasoline, kerosene, and diesel fuel. Separate streams of gasoline, kerosene, and diesel fuel may also be obtained, either via selective condensation of each type of fuel, or via later distillation of the combined hydrocarbon liquid.

  12. Bubbling bed catalytic hydropyrolysis process utilizinig larger catalyst particles and small biomass particles featuring an anti-slugging reactor

    Energy Technology Data Exchange (ETDEWEB)

    Marker, Terry L.; Felix, Larry G.; Linck, Martin B.; Roberts, Michael J.

    2016-12-06

    This invention relates to a process for thermochemically transforming biomass or other oxygenated feedstocks into high quality liquid hydrocarbon fuels. In particular, a catalytic hydropyrolysis reactor, containing a deep bed of fluidized catalyst particles is utilized to accept particles of biomass or other oxygenated feedstocks that are significantly smaller than the particles of catalyst in the fluidized bed. The reactor features an insert or other structure disposed within the reactor vessel that inhibits slugging of the bed and thereby minimizes attrition of the catalyst. Within the bed, the biomass feedstock is converted into a vapor-phase product, containing hydrocarbon molecules and other process vapors, and an entrained solid char product, which is separated from the vapor stream after the vapor stream has been exhausted from the top of the reactor. When the product vapor stream is cooled to ambient temperatures, a significant proportion of the hydrocarbons in the product vapor stream can be recovered as a liquid stream of hydrophobic hydrocarbons, with properties consistent with those of gasoline, kerosene, and diesel fuel. Separate streams of gasoline, kerosene, and diesel fuel may also be obtained, either via selective condensation of each type of fuel, or via later distillation of the combined hydrocarbon liquid.

  13. Wavelet Transform of Velocity-Time Data for the Analysis of Turbulent Structures in a Trayed Bubble Column%通过速度-时间数据的小波变换研究筛板式鼓泡塔中的湍流结构

    Institute of Scientific and Technical Information of China (English)

    闻建平; 贾晓强; 周怀; 刘宝谈; 李瑞

    2004-01-01

    Hydrodynamic and turbulent structures in the trayed bubble column with 1.2 m inner diameter have been characterized from liquid-phase velocity-time series data obtained by the hot-film anemometer. Wavelet transform analysis was used for denoising the measured data and also for evaluating quantifiers of turbulence, viz., local intermittency measure, intermittency index and flatness factor. These quantifiers help in detecting the passage of bubbles and reveal the hidden structures and patterns in data. Also, the wavelet scalewise analysis of the turbulence at various locations in the column and under different operating conditions could be used to build a direct relationship between the local gas holdup and flatness factor. The methodology is therefore suitable for online evaluation of the trayed bubble column performance and shows promise for developing strategies for improving process performance.

  14. Science Bubbles

    DEFF Research Database (Denmark)

    Hendricks, Vincent Fella; Pedersen, David Budtz

    2013-01-01

    Much like the trade and trait sof bubbles in financial markets,similar bubbles appear on the science market. When economic bubbles burst, the drop in prices causes the crash of unsustainable investments leading to an investor confidence crisis possibly followed by a financial panic. But when...... bubbles appear in science, truth and reliability are the first victims. This paper explores how fashions in research funding and research management may turn science into something like a bubble economy....

  15. Ex-situ biogas upgrading and enhancement in different reactor systems

    DEFF Research Database (Denmark)

    Kougias, Panagiotis; Treu, Laura; Benavente, Daniela Peñailillo;

    2017-01-01

    Biogas upgrading is envisioned as a key process for clean energy production. The current study evaluates the efficiency of different reactor configurations for ex-situ biogas upgrading and enhancement, in which externally provided hydrogen and carbon dioxide were biologically converted to methane...... and Methanoculleus genera. Methanothermobacter thermautotrophicus was the predominant methanogen in the biofilm formed on top of the diffuser surface in the bubble column reactor....

  16. Vapor Bubbles

    Science.gov (United States)

    Prosperetti, Andrea

    2017-01-01

    This article reviews the fundamental physics of vapor bubbles in liquids. Work on bubble growth and condensation for stationary and translating bubbles is summarized and the differences with bubbles containing a permanent gas stressed. In particular, it is shown that the natural frequency of a vapor bubble is proportional not to the inverse radius, as for a gas bubble, but to the inverse radius raised to the power 2/3. Permanent gas dissolved in the liquid diffuses into the bubble with strong effects on its dynamics. The effects of the diffusion of heat and mass on the propagation of pressure waves in a vaporous bubbly liquid are discussed. Other topics briefly touched on include thermocapillary flow, plasmonic nanobubbles, and vapor bubbles in an immiscible liquid.

  17. 利用微泡浮选柱分选中低品位铝土矿的试验研究%Beneficiation of Middle-low Grade Bauxite with Micro-bubble Flotation Column

    Institute of Scientific and Technical Information of China (English)

    欧乐明; 王立军; 冯其明; 万丽; 叶家笋

    2011-01-01

    在研究矿石性质的基础上,利用新型微泡浮选柱对河南某中低铝硅比铝土矿进行了实验室分选研究,考察了捕收剂、抑制剂、充气量和淋洗水对分选结果的影响.闭路试验结果表明,在优化条件下,采用新型微泡浮选柱可得到精矿铝硅比为10.26,氧化铝回收率87.24%的实验指标.试验证明新型微泡浮选柱对细粒铝土矿分选有良好的应用前景.%Based on the analysis of mineral properties, a new type of micro-bubble flotation column was used in a laboratory study on beneficiation of a middle-low grade bauxite from Henan Province. The influence of collector, depressant, aeration rate and eluent flow rate on the separation effect was investigated. The results of the close-circuit test show that, under the optimized conditions, the A/S ratio for the concentrate can be enhanced to 10.26 and the aluminum recovery can be increased to 87. 24% , which testifies that this new type of micro-bubble flotation column may have promising application potential in bauxite separation.

  18. Design of an Extractive Distillation Column for the Environmentally Benign Separation of Zirconium and Hafnium Tetrachloride for Nuclear Power Reactor Applications

    Directory of Open Access Journals (Sweden)

    Le Quang Minh

    2015-09-01

    Full Text Available Nuclear power with strengthened safety regulations continues to be used as an important resource in the world for managing atmospheric greenhouse gases and associated climate change. This study examined the environmentally benign separation of zirconium tetrachloride (ZrCl4 and hafnium tetrachloride (HfCl4 for nuclear power reactor applications through extractive distillation using a NaCl-KCl molten salt mixture. The vapor–liquid equilibrium behavior of ZrCl4 and HfCl4 over the molten salt system was correlated with Raoult’s law. The molten salt-based extractive distillation column was designed optimally using a rigorous commercial simulator for the feasible separation of ZrCl4 and HfCl4. The molten salt-based extractive distillation approach has many potential advantages for the commercial separation of ZrCl4 and HfCl4 compared to the conventional distillation because of its milder temperatures and pressure conditions, smaller number of required separation trays in the column, and lower energy requirement for separation, while still taking the advantage of environmentally benign feature by distillation. A heat-pump-assisted configuration was also explored to improve the energy efficiency of the extractive distillation process. The proposed enhanced configuration reduced the energy requirement drastically. Extractive distillation can be a promising option competing with the existing extraction-based separation process for zirconium purification for nuclear power reactor applications.

  19. Characterization of the neutron flux in the Hohlraum of the thermal column of the TRIGA Mark III reactor of the ININ; Caracterizacion del flujo neutronico en el Hohlraum de la columna termica del reactor TRIGA Mark III del ININ

    Energy Technology Data Exchange (ETDEWEB)

    Delfin L, A.; Palacios, J.C.; Alonso, G. [ININ, 52045 Ocoyoacac, Estado de Mexico (Mexico)]. e-mail: adl@nuclear.inin.mx

    2006-07-01

    Knowing the magnitude of the neutron flux in the reactor irradiation facilities, is so much importance for the operation of the same one, like for the investigation developing. Particularly, knowing with certain precision the spectrum and the neutron flux in the different positions of irradiation of a reactor, it is essential for the evaluation of the results obtained for a certain irradiation experiment. The TRIGA Mark III reactor account with irradiation facilities designed to carry out experimentation, where the reactor is used like an intense neutron source and gamma radiation, what allows to make irradiations of samples or equipment in radiation fields with components and diverse levels in the different facilities, one of these irradiation facilities is the Thermal Column where the Hohlraum is. In this work it was carried out a characterization of the neutron flux inside the 'Hohlraum' of the irradiation facility Thermal Column of the TRIGA Mark III reactor of the Nuclear Center of Mexico to 1 MW of power. It was determined the sub cadmic neutron flux and the epi cadmic by means of the neutron activation technique of thin sheets of gold. The maps of the distribution of the neutron flux for both energy groups in three different positions inside the 'Hohlraum' are presented, these maps were obtained by means of the irradiation of undressed thin activation sheets of gold and covered with cadmium in arrangements of 10 x 12, located parallel to 11.5 cm, 40.5 cm and 70.5 cm to the internal wall of graphite of the installation in inverse address to the position of the reactor core. Starting from the obtained values of neutron flux it was found that, for the same position of the surface of irradiation of the experimental arrangement, the relative differences among the values of neutron flux can be of 80%, and that the differences among different positions of the irradiation surfaces can vary until in a one order of magnitude. (Author)

  20. Bubble rupture in bubble electrospinning

    Directory of Open Access Journals (Sweden)

    Chen Rouxi

    2015-01-01

    Full Text Available As the distinctive properties and different applications of nanofibers, the demand of nanofibers increased sharply in recently years. Bubble electrospinning is one of the most effective and industrialized methods for nanofiber production. To optimize the set-up of bubble electrospinning and improve its mass production, the dynamic properties of un-charged and charged bubbles are studied experimentally, the growth and rupture process of a bubble are also discussed in this paper.

  1. Industrial test on cyclonic-static micro-bubble floatation column in a certain gold mine%旋流-静态微泡浮选柱在某金矿的工业试验

    Institute of Scientific and Technical Information of China (English)

    孙永峰; 曹亦俊; 刘洋; 董洁; 廖寅飞; 邹文杰

    2011-01-01

    通过工业分流条件试验,研究了旋流-静态微泡浮选柱在山东某金矿应用的最佳工艺条件参数.试验结果表明:用浮选柱的一次粗选、一次精选工艺流程与生产中用浮选机的一次粗选、二次精选、二次扫选的工艺流程相比,在尾矿品位接近的情况下,精矿品位可提高12.69g/t.%In industrial condition test, the optimal processing condition parameters for cyclonic-static micro-bubble flotation column are studied in a certain gold mine in Shandong. Tests results show that with the flotation column flowsheet of once roughing flotation, once cleaning floatation, and the floatation machine flowsheet of once roughing flotation, twice cleaning floatation and twice scavenging floatation, the concentrate grade of the former one is 12. 69g/ t higher, when the grades of tailings are similar.

  2. A Bubble Detection Algorithm Based on Sparse and Redundant Image Processing

    Directory of Open Access Journals (Sweden)

    Ye Tian

    2013-06-01

    Full Text Available Deinked pulp flotation column has been applied in wastepaper recycling. Bubble size in deinked pulp flotation column is very important during the flotation process. In this paper, bubble images of deinked pulp flotation column were first caught by digital camera, and then the bubbles were detected by using a detection algorithm based on sparse and redundant image processing. The results show the algorithms are very practical and effective on bubble detection in deinked pulp flotation column.

  3. Fischer-Tropsch Slurry Reactor modeling

    Energy Technology Data Exchange (ETDEWEB)

    Soong, Y.; Gamwo, I.K.; Harke, F.W. [Pittsburgh Energy Technology Center, PA (United States)] [and others

    1995-12-31

    This paper reports experimental and theoretical results on hydrodynamic studies. The experiments were conducted in a hot-pressurized Slurry-Bubble Column Reactor (SBCR). It includes experimental results of Drakeol-10 oil/nitrogen/glass beads hydrodynamic study and the development of an ultrasonic technique for measuring solids concentration. A model to describe the flow behavior in reactors was developed. The hydrodynamic properties in a 10.16 cm diameter bubble column with a perforated-plate gas distributor were studied at pressures ranging from 0.1 to 1.36 MPa, and at temperatures from 20 to 200{degrees}C, using a dual hot-wire probe with nitrogen, glass beads, and Drakeol-10 oil as the gas, solid, and liquid phase, respectively. It was found that the addition of 20 oil wt% glass beads in the system has a slight effect on the average gas holdup and bubble size. A well-posed three-dimensional model for bed dynamics was developed from an ill-posed model. The new model has computed solid holdup distributions consistent with experimental observations with no artificial {open_quotes}fountain{close_quotes} as predicted by the earlier model. The model can be applied to a variety of multiphase flows of practical interest. An ultrasonic technique is being developed to measure solids concentration in a three-phase slurry reactor. Preliminary measurements have been made on slurries consisting of molten paraffin wax, glass beads, and nitrogen bubbles at 180 {degrees}C and 0.1 MPa. The data show that both the sound speed and attenuation are well-defined functions of both the solid and gas concentrations in the slurries. The results suggest possibilities to directly measure solids concentration during the operation of an autoclave reactor containing molten wax.

  4. 基于BP神经网络的旋流-静态微泡浮选柱气含率预测%Prediction of gas holdup in cyclonic-static micro-bubble flotation column based on BP neural networks

    Institute of Scientific and Technical Information of China (English)

    廖寅飞; 刘炯天; 王永田; 曹亦俊

    2011-01-01

    分析了影响旋流-静态微泡浮选柱气含率的因素,选取循环压力、进气量和起泡剂浓度3个主控因素作为BP神经网络模型的基本特征量,建立了浮选柱气含率与主控因素之间的相关关系和BP神经网络预测模型,并对气含率进行了预测分析.结果表明:BP神经网络能合理地表达浮选柱气含率与其主控因素之间的非线性映射关系,预测结果与实测值之间的相对误差一般小于5%,达到了较高的预测精度.%The factors that affect the gas holdup in cyclonic-static micro-bubble flotation column were analyzed. Taking the main controlling factors, including pressure of circulating pump, air flow and frother concentration, as the basic characteristic quantity of BP neural networks models, the correlation between the gas holdup, the factors, and the BP neural networks prediction model were proposed for prediction of the gas holdup in flotation column. The results show that the BP neural networks model can actually reflect the nonlinear relationship between the gas holdup in flotation column and main controlling factors. A better accurate prediction in which the errors between the predicted values and measured values are less than 5 % is achieved.

  5. 某硫铁矿矿泥柱浮选半工业试验%Pilot Test of a Pyrite Slime Flotation by Cyclone-Static Micro-bubble Flotation Column

    Institute of Scientific and Technical Information of China (English)

    黄根; 岳双凌; 文涵睿

    2012-01-01

    order to effectively utilize the slime produced in the course of producing - 3 mm production in a pyrite concentrator from Guangdong province,carried out the pilot test of once roughing once cleaning column flotation by two Φ400 mm ×4 000 mm cyclone static micro-bubble flotation columns. Suitable handling capacity,reagent system and circu-lating pump pressure of flotation column were determined by conditions test After 72 h continous production,the S concentrate with 48. 46% grade,93. 71% recovery was achineved,comparing to the spot flotation machine,the S recovery increased by 13 percentage ponits.%为使广东某硫铁矿生产-3 mm产品过程中产生的矿泥得到高效利用,采用2台Φ400 mm×4 000 mm旋流-静态微泡浮选柱在现场对该矿泥进行了1粗1精柱式浮选半工业试验.首先通过条件试验确定了合适的处理量、药剂制度以及浮选柱中矿循环泵压力,然后进行72 h连续运转,获得了硫精矿硫品位为48.46%、硫回收率为93.71%的良好指标.与现场采用浮选机的选别指标相比,硫回收率提高了约13个百分点.

  6. Continuous enzymatic biodiesel production from coconut oil in two-stage packed-bed reactor incorporating an extracting column to remove glycerol formed as by-product.

    Science.gov (United States)

    Costa E Silva, William; Freitas, Larissa; Oliveira, Pedro C; de Castro, Heizir F

    2016-10-01

    The transesterification of coconut oil with ethanol catalyzed by Burkholderia cepacia lipase immobilized on polysiloxane-polyvinyl alcohol was performed in a continuous flow. The experimental design consisted of a two-stage packed-bed reactor incorporating a column with cationic resin (Lewatit GF 202) to remove the glycerol formed as by-product and the reactor performance was quantified for three different flow rates corresponding to space-times from 10 to 14 h. The influence of space-time on the ethyl ester (FAEE) concentrations, yields and productivities was determined. The reactor operation was demonstrated for space-time of 14 h attaining FAEE concentrations of 58.5 ± 0.87 wt%, FAEE yields of 97.3 ± 1.9 % and productivities of 41.6  ± 1.0 mgester g medium (-1)  h(-1). Biodiesel purified samples showed average kinematic viscosity values of 5.5 ± 0.3 mm(2) s(-1) that meet the criteria established by the American National Standard ASTM (D6751). The immobilized lipase was found to be stable regarding its morphological and catalytic characteristics, showing half-life time (t 1/2) around 1540 h. The continuous packed-bed reactor connected in series with simultaneous glycerol removal has a great potential to attain high level of transesterification yields, raising biodiesel productivity.

  7. Interfacial area between gases and liquid in a valve plate column and a bubble cap tray; Barubu danto oyobi hosho danto ni okeru kieki sesshoku menseki

    Energy Technology Data Exchange (ETDEWEB)

    Nakoua, M.; Dribika, M.; Besher, E

    1999-03-05

    A mathematical model has been developed for absorption accompanied by chemical reaction of H{sub 2}S and CO{sub 2} in alkanolamine solutions encountered in plants for natural gas sweetening in Libya. The model has been used to calculate actual number of plates in industrial columns. The model results errors in number of trays predictions due to the lack of procedures for estimating interfacial area for the in between flow regime that prevailed in two industrial plants. The developed correlation for interfacial area estimation for the in between flow regime gives zero error in number of trays prediction. (author)

  8. Bubble systems

    CERN Document Server

    Avdeev, Alexander A

    2016-01-01

    This monograph presents a systematic analysis of bubble system mathematics, using the mechanics of two-phase systems in non-equilibrium as the scope of analysis. The author introduces the thermodynamic foundations of bubble systems, ranging from the fundamental starting points to current research challenges. This book addresses a range of topics, including description methods of multi-phase systems, boundary and initial conditions as well as coupling requirements at the phase boundary. Moreover, it presents a detailed study of the basic problems of bubble dynamics in a liquid mass: growth (dynamically and thermally controlled), collapse, bubble pulsations, bubble rise and breakup. Special emphasis is placed on bubble dynamics in turbulent flows. The analysis results are used to write integral equations governing the rate of vapor generation (condensation) in non-equilibrium flows, thus creating a basis for solving a number of practical problems. This book is the first to present a comprehensive theory of boil...

  9. Characterization of the Bnct Epithermal Column of the Fast Reactor Tapiro (enea) and Dose Measurements in Phantom Utilising Not-Conventional Detection

    Science.gov (United States)

    Gambarini, G.; Colombi, C.; Lietti, B.; Prestini, P.; Fiorani, O.; Perrone, A.; Rosi, G.; Agosteo, S.; Riva, A.

    2002-11-01

    The epithermal column of TAPIRO reactor has been characterized and in-phantom dose has been imaged, with the purpose of determining parameters and data whose knowledge will be of main importance for future experimentation regarding boron neutron capture therapy (BNCT). In-phantom measurements have been carried out mainly utilizing a recently developed method for absorbed dose imaging, based on gel-dosimeters. Gel-dosimeters have revealed to give significant support to thermal or epithermal neutron dosimetry: in fact, the modality of energy release in gel-dosimeters is very similar to that in tissue, and with proper adjustment of the isotopic composition of gel matrix, the various dose components are separated.

  10. The Effect of Aeration on the Growth and Lipid Content on Chlorella vulgaris LICME002 in the Applied Alumina Gas Distributor Bubbling Column Photobioreactor%氧化铝气体分布器应用小球藻培养的研究

    Institute of Scientific and Technical Information of China (English)

    张齐; 高振; 黄和; 梁西海; 纪晓俊; 郑洪立; 尹丰伟

    2011-01-01

    In the study of photobioreactor, gas distributor has great influence to the growth of microalgae,especially in the bubbling column reactor. The effect of the gas-flow rate and CO2 concentration on the biomass,chlorophyll a, and lipid accumulation of Chlorella vulgaris LICME002 in the 5L bubbling photobioreactor with a alumina gas distributor. The results showed that the 3% CO2 is the optimum condition for biomass, chlorophyll a, oil accumulation. When the CO2 concentration exceeded 6% , the algae's parameters decreased significantly.With the analysis of the algae's parameters at 0. lvvm ,0. 4vvm ,0. 7vvm , 1. Ovvm , and the gas-flow rate 0. 4vvm is the best one. Results showed that the optimum gas-flow rate and CO2 concentration, the microalgae biomass can achieve 1. 52 g/L , oil content achieved 31. 5% .%光生物反应器设计中,气体分布器对微藻生长有较大的影响,尤其是在鼓泡式光生物反应器中更为显著.实验考察了采用氧化铝烧制的多孔气体分布器的5L鼓泡式光生物反应器中通气速率、CO2浓度对小球藻HCME002生物量、叶绿素含量、油脂积累的影响.对该气体分布器下的CO2浓度和通气速率对小球藻的作用机理进行了初步的探讨.结果表明,CO2浓度为3%时,该株微藻生物量、叶绿素、油脂积累的最佳;CO2浓度超过6%时各项指标显著下降.通过对0.1vvm,0.4vvm,0.7vvm、1.0vvm的通气速条件下的各项指标的分析,确定最佳通气条件为0.4vvm.结论显示,在最佳通气速率和CO2浓度下,微藻生物量能达到1.52g/L,油脂含量达到31.5%.

  11. Attachment of Acidithiobacillus ferrooxidans and Leptospirillum ferriphilum cultured under varying conditions to pyrite, chalcopyrite, low-grade ore and quartz in a packed column reactor.

    Science.gov (United States)

    Africa, Cindy-Jade; van Hille, Robert P; Harrison, Susan T L

    2013-02-01

    The attachment of Acidithiobacillus ferrooxidans and Leptospirillum ferriphilum spp. grown on ferrous medium or adapted to a pyrite mineral concentrate to four mineral substrata, namely, chalcopyrite and pyrite concentrates, a low-grade chalcopyrite ore (0.5 wt%) and quartzite, was investigated. The quartzite represented a typical gangue mineral and served as a control. The attachment studies were carried out in a novel particle-coated column reactor. The saturated reactor containing glass beads, which were coated with fine mineral concentrates, provided a quantifiable surface area of mineral concentrate and maintained good fluid flow. A. ferrooxidans and Leptospirillum spp. had similar attachment characteristics. Enhanced attachment efficiency occurred with bacteria grown on sulphide minerals relative to those grown on ferrous sulphate in an ore-free environment. Selective attachment to sulphide minerals relative to gangue materials occurred, with mineral adapted cultures attaching to the minerals more efficiently than ferrous grown cultures. Mineral-adapted cultures showed highest levels of attachment to pyrite (74% and 79% attachment for A. ferrooxidans and L. ferriphilum, respectively). This was followed by attachment of mineral-adapted cultures to chalcopyrite (63% and 58% for A. ferrooxidans and L. ferriphilum, respectively). A. ferrooxidans and L. ferriphilum exhibited lower levels of attachment to low-grade ore and quartz relative to the sulphide minerals.

  12. Intensification and forecasting of low-pour-point diesel fuel production via modelling reactor and stabilizer column at industrial unit

    Science.gov (United States)

    Belinskaya, N. S.; Frantsina, E. V.; Ivanchina, E. D.; Popova, N. V.; Zyryanova, I. V.; Averyanova, E. V.

    2016-09-01

    In this work forecast calculation of stabilizer column in the technology of low-pour- point diesel fuel production was modelled. The results of forecast calculation were proved by full-scale experiment at diesel fuel catalytic dewaxing unit. The forecast calculation and full- scale experiment made it possible to determine the ways of mass transfer intensification, as well as to increase the degree of hydrogen sulphide removal in the column, and thereby to decrease corrosiveness of the product stream. It was found out that maintenance of the reflux rate in the range of 80-90 m3/h and injection of additional vapourizing streams, such as stable naphtha from distillation unit (in the volume of 10-22 m3/h) and hydrogen-containing gas (in the volume of 100-300 m3/h), ensure complete elimination of corrosive hydrogen sulphide from the product stream. Reduction of stream corrosive activity due to suggested solutions extends service life of equipment and pipelines at industrial catalytic dewaxing unit.

  13. Use of PTFE coils in post-column photochemical reactors for liquid chromatography--application to pharmaceuticals.

    Science.gov (United States)

    Scholten, A H; Welling, P L; Brinkman, U A; Frei, R W

    1980-10-31

    The advantages and the performance of PTFE reaction coils in photochemical reaction detectors for high-performance liquid chromatography (HPLC) are discussed. The excellent performance of these materials at irradiation wavelengths below 300 nm is based on a diffuse radiation transfer and an internal reflectance (light-tube) effect. Optimal coil designs can be obtained from signal vs. flow-rate curves for a particular application. Lamp performance has to be tested periodically and the reactor should be equipped with an efficient cooling system. Application of the principle to the fluorimetric detection of clobazam and phenothiazines after HPLC separation is discussed. The sensitive detection of these pharmaceuticals and their metabolites in serum with a minimum of sample handling demonstrates the potential of photochemical reaction detectors.

  14. Maximization of organic acids production by Aspergillus niger in a bubble column bioreactor for V and Ni recovery enhancement from power plant residual ash in spent-medium bioleaching experiments.

    Science.gov (United States)

    Rasoulnia, P; Mousavi, S M

    2016-09-01

    Spent-medium bioleaching of V and Ni from a power plant residual ash (PPR ash) was conducted using organic acids produced by Aspergillus niger. The production of organic acids in a bubble column bioreactor was optimized through selecting three most influencing factors. Under optimum condition of aeration rate of 762.5(ml/min), sucrose concentration of 101.9(g/l) and inoculum size of 40(ml/l), respectively 17,185, 4539, 1042 and 502(ppm) of oxalic, gluconic, citric and malic acids were produced. Leaching experiments were carried out using biogenic produced organic acids under leaching environment temperature of 60°C and rotary shaking speed of 135rpm, with various pulp densities of 1, 2, 3, 5, 7 and 9(%w/v). The results showed that biogenic produced organic acids leached V much more efficiently than Ni so that even at high pulp density of 9(%w/v), 83% of V was recovered while Ni recovery yield was 30%.

  15. Reactor

    Science.gov (United States)

    Evans, Robert M.

    1976-10-05

    1. A neutronic reactor having a moderator, coolant tubes traversing the moderator from an inlet end to an outlet end, bodies of material fissionable by neutrons of thermal energy disposed within the coolant tubes, and means for circulating water through said coolant tubes characterized by the improved construction wherein the coolant tubes are constructed of aluminum having an outer diameter of 1.729 inches and a wall thickness of 0.059 inch, and the means for circulating a liquid coolant through the tubes includes a source of water at a pressure of approximately 350 pounds per square inch connected to the inlet end of the tubes, and said construction including a pressure reducing orifice disposed at the inlet ends of the tubes reducing the pressure of the water by approximately 150 pounds per square inch.

  16. Adhesion of solid particles to gas bubbles. Part 2: Experimental

    NARCIS (Netherlands)

    Omota, Florin; Dimian, Alexandre C.; Bliek, Alfred

    2006-01-01

    In slurry bubble columns, the adhesion of solid catalyst particles to bubbles may significantly affect the G–L mass transfer and bubble size distribution. This feature may be exploited in design by modifying the hydrophilic or hydrophobic nature of the particles used. Previously we have proposed a g

  17. Exploring Bubbles

    Science.gov (United States)

    O'Geary, Melissa A.

    Bubbles provide an enjoyable and festive medium through which to teach many concepts within the science topics of light, color, chemistry, force, air pressure, electricity, buoyancy, floating, density, among many others. In order to determine the nature of children's engagement within a museum setting and the learning opportunities of playing with bubbles, I went to a children's interactive museum located in a metropolitan city in the Northeastern part of the United States.

  18. Antigravitating bubbles

    CERN Document Server

    Barnaveli, A T; Barnaveli, Andro; Gogberashvili, Merab

    1995-01-01

    We investigate the gravitational behavior of spherical domain walls (bubbles) arising during the phase transitions in the early Universe. In the thin-wall approximation we show the existence of the new solution of Einstein equations with negative gravitational mass of bubbles and the reversed direction of time flow on the shell. This walls exhibit gravitational repulsion just as the planar walls are assumed to do. The equilibrium radius and critical mass of such objects are found for realistic models.

  19. Bubble diagnostics

    Science.gov (United States)

    Visuri, Steven R.; Mammini, Beth M.; Da Silva, Luiz B.; Celliers, Peter M.

    2003-01-01

    The present invention is intended as a means of diagnosing the presence of a gas bubble and incorporating the information into a feedback system for opto-acoustic thrombolysis. In opto-acoustic thrombolysis, pulsed laser radiation at ultrasonic frequencies is delivered intraluminally down an optical fiber and directed toward a thrombus or otherwise occluded vessel. Dissolution of the occlusion is therefore mediated through ultrasonic action of propagating pressure or shock waves. A vapor bubble in the fluid surrounding the occlusion may form as a result of laser irradiation. This vapor bubble may be used to directly disrupt the occlusion or as a means of producing a pressure wave. It is desirable to detect the formation and follow the lifetime of the vapor bubble. Knowledge of the bubble formation and lifetime yields critical information as to the maximum size of the bubble, density of the absorbed radiation, and properties of the absorbing material. This information can then be used in a feedback system to alter the irradiation conditions.

  20. Hydrogen Production with High Evolution Rate and High Yield by Immobilized Cells of Hydrogen-producing Bacteria Strain B49 in a Column Reactor

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    To improve the hydrogen evolution rate in continuous hydrogen production of a novel fermentative hydrogen-producing bacteria strain B49 (AF481148 in EMBL), 4 % immobilized cells by polyvinyl alcohol-boric acid method, with the addition of a small amount of calcium alginate in a column reactor obtain hydrogen yield of 2.31 mol H2/mol glucose and hydrogen evolution rate of 1435.4 ml/L culture*h respectively at medium retention time of 2.0 h with a medium containing 10g glucose/L. Moreover, as the cell density in gel beads is increased to 8%, hydrogen yield and hydrogen evolution rate for 10g glucose/L are 2.34 mol H2/mol glucose and 2912.4 ml/L culture*h respectively at medium retention time of 1.0 h, and for molasses wastewater COD of 7505.9 mg/L hydrogen production potential of 205.6 ml/g COD and hydrogen evolution rate of 2057.7 ml/L culture*h at hydraulic retention time of 0.75 h are observed. In the continuous culture pH value keeps around 3.9 by self-regulating.

  1. Experimental Study on the Cyclonic Static Micro-bubble Flotation Column for a Copper ore%某铜矿旋流-静态微泡浮选柱试验研究

    Institute of Scientific and Technical Information of China (English)

    孔令同; 曹亦俊; 徐宏祥; 孙永峰

    2011-01-01

    就某地微细粒含量高、易泥化的难选铜矿石,提出部分优先浮选新工艺,即原矿经破碎磨矿后采用高效、节能的微细粒分选设备旋流-静态微泡浮选柱进行分选,直接得到部分最终合格精矿,解决了该铜矿中微细粒级浮选机回收能力差造成金属流失的问题.在最优参数条件下进行了连选试验.研究结果表明,采用该工艺流程可以优先得到铜品位21.46%,回收率30.04%的铜精矿.%For a refractory copper ore with feature of fine particle and ease-to-slime, a new flow-sheet of partially preferential flotation was proposed, that is, raw ores are separated after crushing and grinding by the high efficiency and energy-saying micro-fine separator with cyclonic-static micro-bubble flotation column to directly get some final qualified concentrate. By this way, the problem of low recovery capacity by micro-fine flotation machine for a copper mine which result in metal loss are resolved. And the pilot experiments are carried out by adopting the optimum conditions. The results show that the high quality copper concentrates are obtained by this flow-sheet, which contain Cu of 21.46% with a 30.04% of recovery rate.

  2. Bubbling Threat

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    The shift of China’s monetary policy stance from "moderately loose" to "prudent" in 2011 indicates curbing inflation and asset bubbles have become the Central Government’s top priority. But is China’s bubble problem short-term or long-term? Is it only monetary or related to economic structure? Is it the cause of China’s economic imbalance or the result? And what kind of deep-rooted problems in the macro economy does it reflect? All these questions call for deep thought,said Zhang Monan,a

  3. Leverage bubble

    Science.gov (United States)

    Yan, Wanfeng; Woodard, Ryan; Sornette, Didier

    2012-01-01

    Leverage is strongly related to liquidity in a market and lack of liquidity is considered a cause and/or consequence of the recent financial crisis. A repurchase agreement is a financial instrument where a security is sold simultaneously with an agreement to buy it back at a later date. Repurchase agreement (repo) market size is a very important element in calculating the overall leverage in a financial market. Therefore, studying the behavior of repo market size can help to understand a process that can contribute to the birth of a financial crisis. We hypothesize that herding behavior among large investors led to massive over-leveraging through the use of repos, resulting in a bubble (built up over the previous years) and subsequent crash in this market in early 2008. We use the Johansen-Ledoit-Sornette (JLS) model of rational expectation bubbles and behavioral finance to study the dynamics of the repo market that led to the crash. The JLS model qualifies a bubble by the presence of characteristic patterns in the price dynamics, called log-periodic power law (LPPL) behavior. We show that there was significant LPPL behavior in the market before that crash and that the predicted range of times predicted by the model for the end of the bubble is consistent with the observations.

  4. Design development of an electrocoagulation reactor for molasses process wastewater treatment.

    Science.gov (United States)

    Gadd, A S; Ryan, D R; Kavanagh, J M; Barton, G W

    2010-01-01

    The impact of electrode corrosion behaviour, reactor geometry and current density on electrocoagulation efficiency were investigated for the treatment of molasses process wastewater. Two laboratory-scale vertical plate electrocoagulation reactors were used for this investigation: the first being a low aspect ratio bath reactor with a low specific electrode area, while the other was a high aspect ratio column reactor with a high specific electrode area. Anomalous anodic dissolution and cathodic corrosion of the aluminium electrodes both contributed significantly to overall metal consumption. Increasing specific electrode area and aspect ratio each led to improved treatment efficiency, whereas the impact of current density was more complicated involving the combined influences of several competing effects. The space-time yields of coagulant and bubbles (both functions of specific electrode area, current density and current efficiency) were found to influence mixing within the reactor and thus treatment efficiency.

  5. An immobilized cell reactor with simultaneous product separation. II. Experimental reactor performance.

    Science.gov (United States)

    Dale, M C; Okos, M R; Wankat, P C

    1985-07-01

    The simultaneous separation of volatile fermentation products from product-inhibited fermentations can greatly increase the productivity of a bioreactor by reducing the product concentration in the bioreactor, as well as concentrating the product in an output stream free of cells, substrate, or other feed impurities. The Immobilized Cell Reactor-Separator (ICRS) consists of two column reactors: a cocurrent gas-liquid "enricher" followed by a countercurrent "stripper" The columns are four-phase tubular reactors consisting of (1) an inert gas phase, (2) the liquid fermentation broth, (3) the solid column internal packing, and (4) the immobilized biological catalyst or cells. The application of the ICRS to the ethanol-from-whey-lactose fermentation system has been investigated. Operation in the liquid continuous or bubble flow regime allows a high liquid holdup in the reactor and consequent long and controllable liquid residence time but results in a high gas phase pressure drop over the length of the reactor and low gas flow rates. Operation in the gas continuous regime gives high gas flow rates and low pressure drop but also results in short liquid residence time and incomplete column wetting at low liquid loading rates using conventional gas-liquid column packings. Using cells absorbed to conventional ceramic column packing (0.25-in. Intalox saddles), it was found that a good reaction could be obtained in the liquid continuous mode, but little separation, while in the gas continuous mode there was little reaction but good separation. Using cells sorbed to an absorbant matrix allowed operation in the gas continuous regime with a liquid holdup of up to 30% of the total reactor volume. Good reaction rates and product separation were obtained using this matrix. High reaction rates were obtained due to high density cell loading in the reactor. A dry cell density of up to 92 g/L reactor was obtained in the enricher. The enricher ethanol productivity ranged from 50 to 160

  6. Bubble drag reduction requires large bubbles

    CERN Document Server

    Verschoof, Ruben A; Sun, Chao; Lohse, Detlef

    2016-01-01

    In the maritime industry, the injection of air bubbles into the turbulent boundary layer under the ship hull is seen as one of the most promising techniques to reduce the overall fuel consumption. However, the exact mechanism behind bubble drag reduction is unknown. Here we show that bubble drag reduction in turbulent flow dramatically depends on the bubble size. By adding minute concentrations (6 ppm) of the surfactant Triton X-100 into otherwise completely unchanged strongly turbulent Taylor-Couette flow containing bubbles, we dramatically reduce the drag reduction from more than 40% to about 4%, corresponding to the trivial effect of the bubbles on the density and viscosity of the liquid. The reason for this striking behavior is that the addition of surfactants prevents bubble coalescence, leading to much smaller bubbles. Our result demonstrates that bubble deformability is crucial for bubble drag reduction in turbulent flow and opens the door for an optimization of the process.

  7. Bubble Drag Reduction Requires Large Bubbles

    Science.gov (United States)

    Verschoof, Ruben A.; van der Veen, Roeland C. A.; Sun, Chao; Lohse, Detlef

    2016-09-01

    In the maritime industry, the injection of air bubbles into the turbulent boundary layer under the ship hull is seen as one of the most promising techniques to reduce the overall fuel consumption. However, the exact mechanism behind bubble drag reduction is unknown. Here we show that bubble drag reduction in turbulent flow dramatically depends on the bubble size. By adding minute concentrations (6 ppm) of the surfactant Triton X-100 into otherwise completely unchanged strongly turbulent Taylor-Couette flow containing bubbles, we dramatically reduce the drag reduction from more than 40% to about 4%, corresponding to the trivial effect of the bubbles on the density and viscosity of the liquid. The reason for this striking behavior is that the addition of surfactants prevents bubble coalescence, leading to much smaller bubbles. Our result demonstrates that bubble deformability is crucial for bubble drag reduction in turbulent flow and opens the door for an optimization of the process.

  8. Free Surface Lattice Boltzmann with Enhanced Bubble Model

    CERN Document Server

    Anderl, Daniela; Rauh, Cornelia; Rüde, Ulrich; Delgado, Antonio

    2016-01-01

    This paper presents an enhancement to the free surface lattice Boltzmann method (FSLBM) for the simulation of bubbly flows including rupture and breakup of bubbles. The FSLBM uses a volume of fluid approach to reduce the problem of a liquid-gas two-phase flow to a single-phase free surface simulation. In bubbly flows compression effects leading to an increase or decrease of pressure in the suspended bubbles cannot be neglected. Therefore, the free surface simulation is augmented by a bubble model that supplies the missing information by tracking the topological changes of the free surface in the flow. The new model presented here is capable of handling the effects of bubble breakup and coalesce without causing a significant computational overhead. Thus, the enhanced bubble model extends the applicability of the FSLBM to a new range of practically relevant problems, like bubble formation and development in chemical reactors or foaming processes.

  9. A CONCEPTUAL DESIGN OF NEUTRON COLLIMATOR IN THE THERMAL COLUMN OF KARTINI RESEARCH REACTOR FOR IN VITRO AND IN VIVO TEST OF BORON NEUTRON CAPTURE THERAPY

    Directory of Open Access Journals (Sweden)

    Nina Fauziah

    2015-03-01

    Full Text Available Studies were carried out to design a collimator which results in epithermal neutron beam for IN VITRO and IN VIVO of Boron Neutron Capture Therapy (BNCT at the Kartini research reactor by means of Monte Carlo N-Particle (MCNP codes. Reactor within 100 kW of thermal power was used as the neutron source. The design criteria were based on recommendation from the International Atomic Energy Agency (IAEA. All materials used were varied in size, according to the value of mean free path for each material. MCNP simulations indicated that by using 5 cm thick of Ni as collimator wall, 60 cm thick of Al as moderator, 15 cm thick of 60Ni as filter, 2 cm thick of Bi as γ-ray shielding, 3 cm thick of 6Li2CO3-polyethylene as beam delimiter, with 1 to 5 cm varied aperture size, epithermal neutron beam with maximum flux of 7.65 x 108 n.cm-2.s-1 could be produced. The beam has minimum fast neutron and γ-ray components of, respectively, 1.76 x 10-13 Gy.cm2.n-1 and 1.32 x 10-13 Gy.cm2.n-1, minimum thermal neutron per epithermal neutron ratio of 0.008, and maximum directionality of 0.73. It did not fully pass the IAEA’s criteria, since the epithermal neutron flux was below the recommended value, 1.0 x 109 n.cm-2.s-1. Nonetheless, it was still usable with epithermal neutron flux exceeding 5.0 x 108 n.cm-2.s-1. When it was assumed that the graphite inside the thermal column was not discharged but only the part which was going to be replaced by the collimator, the performance of the collimator became better within the positive effect from the surrounding graphite that the beam resulted passed all criteria with epithermal neutron flux up to 1.68 x 109 n.cm-2.s-1. Keywords: design, collimator, epithermal neutron beam, BNCT, MCNP, criteria   Telah dilakukan penelitian tentang desain kolimator yang menghasilkan radiasi netron epitermal untuk uji in vitro dan in vivo pada Boron Neutron Capture Therapy (BNCT di Reaktor Riset Kartini dengan menggunakan program Monte

  10. Interacting bubble clouds and their sonochemical production

    CERN Document Server

    Stricker, Laura; Rivas, David Fernandez; Lohse, Detlef

    2013-01-01

    Acoustically driven air pockets trapped in artificial crevices on a sur- face can emit bubbles which organize in (interacting) bubble clusters. With increasing driving power Fernandez Rivas et al. [Angew. Chem. Int. Ed., 2010] observed three different behaviors: clusters close to the very pits out of which they had been created, clusters pointing toward each other, and merging clusters. The latter behavior is highly undesired for technological purposes as it is associated with a reduction of the radical production and an enhancement of the erosion of the reactor walls. The dependence on the control parameters such as the distance of the pits and the conditions for cluster-merging are examined. The underlying mechanism, governed by the secondary Bjerknes forces, turns out to be strongly influenced by the nonlinearity of the bubble oscillations and not directly by the number of nucleated bubbles. The Bjerknes forces are found to dampen the bubble oscillations, thus reducing the radical production. Therefore, th...

  11. Simultaneous biosorption of chromium(VI) and copper(II) on Rhizopus arrhizus in packed column reactor: Application of the competitive Freundlich model

    Energy Technology Data Exchange (ETDEWEB)

    Sag, Y.; Atacoglu, I.; Kutsal, T.

    1999-12-01

    The simultaneous biosorption of Cr(VI) and Cu(II) on free Rhizopus arrhizus in a packed column operated in the continuous mode was investigated and compared to the single metal ion situation. The breakthrough curves were measured as a function of feed flow rate, feed pH, and different combinations of metal ion concentrations in the feed solutions. Column competitive biosorption data were evaluated in terms of the maximum (equilibrium) capacity in the column, the amount of metal loading on the R. arrhizus surface, the adsorption yield, and the total adsorption yield. In the single-ion situation the adsorption isotherms were developed for optimum conditions, and it was seen that the adsorption equilibrium data fit the noncompetitive Freundlich model. For the multicomponent adsorption equilibrium the competitive adsorption isotherms were also developed. The competitive Freundlich model for binary metal mixtures represented most the column adsorption equilibrium data of Cr(VI) and Cu(II) on R. arrhizus satisfactorily.

  12. Accuracy of bubble velocity measurement with a four-point optical fibre probe

    NARCIS (Netherlands)

    Bai, Wei; Deen, Niels G.; Mudde, Robert F.; Kuipers, J.A.M.

    2008-01-01

    For the operation of high void fraction bubbly flows in bubble columns, insight in primary parameters such as bubble size, shape and velocity as well as gas volume fraction is essential. At high gas volume fractions the flow system becomes opaque, ruling out non-intrusive optical techniques. As an a

  13. Fama on Bubbles

    DEFF Research Database (Denmark)

    Engsted, Tom

    2016-01-01

    While Eugene Fama has repeatedly expressed his discontent with the notion of an “irrational bubble,” he has never publicly expressed his opinion on “rational bubbles.” On empirical grounds Fama rejects bubbles by referring to the lack of reliable evidence that price declines are predictable. Howe...... component in stock market valuation ratios, consistent with a rational bubble....

  14. Column flotation

    Energy Technology Data Exchange (ETDEWEB)

    Kohmuench, J.N.; Norrgran, D.A.; Luttrell, E.; Luttrell, G.H. [Virginia Tech. (United States)

    2008-04-15

    Over the last decade, column flotation has been recognised in the industry to be most efficient and economical means of recovering fine coal while maximizing product grade. When designed properly, flotation columns provide a high combustible recovery while maintaining a low product ash. The paper looks at the benefits of using column flotation for fine coal recovery. 2 refs., 5 figs.

  15. A CONCEPTUAL DESIGN OF NEUTRON COLLIMATOR IN THE THERMAL COLUMN OF KARTINI RESEARCH REACTOR FOR IN VITRO AND IN VIVO TEST OF BORON NEUTRON CAPTURE THERAPY

    OpenAIRE

    Nina Fauziah; Andang Widiharto; Yohannes Sardjono

    2015-01-01

    Studies were carried out to design a collimator which results in epithermal neutron beam for IN VITRO and IN VIVO of Boron Neutron Capture Therapy (BNCT) at the Kartini research reactor by means of Monte Carlo N-Particle (MCNP) codes. Reactor within 100 kW of thermal power was used as the neutron source. The design criteria were based on recommendation from the International Atomic Energy Agency (IAEA). All materials used were varied in size, according to the value of mean free path for each ...

  16. 无传动微泡浮选槽在高海拔地区某锂辉石矿的工业试验%Industrial Test Research of No Drive Micro Bubble Flotation Column for Spodumene Separation in High Attitude Area

    Institute of Scientific and Technical Information of China (English)

    马智敏; 李思; 陈兴华

    2016-01-01

    This article systematically studied equipment performance , technical parameters , flota-tion technical index and their changing trends of no drive micro bubble flotation column in spodu-mene separation .Through industrial test study , it was found no drive micro bubble flotation column could adapt to spodumene flotation .Comparing with traditional flotation machine , the recovery of spodumene was improved by more than 2 .1%, and unit process energy consumption was saved by more than 20 .6%.Due to the advantages of high processing ability , low energy consumption , high degree of automation and stable equipment operation , it was of important guiding function for indus-trial application and popularization of no drive micro bubble flotation column in spodumene separa -tion, which also provided a good reference for solving flotation efficiency problems in high attitude regions.%研究了无传动微泡浮选槽在分选锂辉石矿时的设备性能、主要技术参数、分选技术指标及其变化趋势,通过工业试验研究发现无传动浮选槽能够较好的适应锂辉石浮选,与传统浮选机比较,锂辉石回收率提高至少2.1%,单位处理能耗节能20.6%以上。同时具有处理能力高、能耗低、自动化程度高、设备运行稳定等优点,本研究对无传动微泡浮选槽在锂辉石矿工业应用和推广具有重要的指导作用,并对解决高海拔地区浮选效率问题有着较好的示范作用。

  17. Bubble Growth and Detachment from a Needle

    Science.gov (United States)

    Shusser, Michael; Rambod, Edmond; Gharib, Morteza

    1999-11-01

    The release of bubbles from an underwater nozzle or orifice occurs in large number of applications, such as perforated plate columns, blood oxygenators and various methods of water treatment. It is also a widely used method in laboratory research on multiphase flow and acoustics for generating small bubbles in a controlled fashion. We studied experimentally the growth and pinch-off of air bubbles released from a submerged needle into a quiescent liquid or a liquid flowing parallel to the needle. Micron-sized bubbles were generated by an air-liquid dispenser. High-speed imaging was performed to study the formation and detachment of bubbles from the tip of the needle. The impact of the needle diameter was investigated and the size and number of produced bubbles were assessed for different flow rates of air and for different velocities of the imposed upward liquid flow. The results were compared with available theoretical models and numerical computations. The existence of a critical gas flow rate and two regimes of bubble growth were verified.

  18. Condensation-Induced Steam Bubble Collapse in a Pipeline

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    Steam bubbles often occur in pipelines due to the pipeline structure or operational errors. The water hammer force induced by the steam bubble collapse is a hidden safety concern. This paper experimentally and numerically investigates the conditions for steam bubble formation and collapse. A series of video pictures taken in the laboratory show that steam bubbles form and collapse over several cycles. The pressure history of the steam bubbles is measured in conjunction with the pictures. In the experiment, the liquid column cavitated at the low pressures and then the cavities collapsed due to condensation causing high pressure pulses. The process was also simulated numerically. The results suggest that coolant pipeline design and operation must include procedures to avoid steam bubble formation.

  19. Fama on bubbles

    DEFF Research Database (Denmark)

    Engsted, Tom

    Eugene Fama has repeatedly expressed his discontent with the notion of an irrational bubble. However, he has never publicly expressed his opinion on rational bubbles. This is peculiar since such bubbles build naturally from the rational efficient markets paradigm that Fama strongly adheres to...

  20. Application of cyclonic-static micro-bubble flotation column in direct-reverse flotation technology of phosphate rock%旋流-静态微泡浮选柱在胶磷矿浮选工艺中的应用

    Institute of Scientific and Technical Information of China (English)

    王大鹏; 刘炯天; 刘江林; 熊明金; 宋永胜

    2011-01-01

    采用旋流-静态微泡浮选柱对某胶磷矿进行了半工业试验研究,在原矿品位为23.73% P2O5的情况下通过正-反浮选流程获得了精矿P2O5品位29.78%、MgO品位0.29%,回收率82.69%的良好指标,缩短了流程结构.为浮选柱技术的工业应用进行了积极探索.%This study makes a semi-industrial experimental investigation on the phosphate rock by using cyclonic-static micro-bubble flotation column. With the application of direct-reverse flotation process flow, it carries out a good indicator with content of P2O5 concentrate 29.78%, content of MgO 0.29%,recovery rate 82.69% when raw mine grade is 23.73%. It shortens the process structure and makes an active exploration on the industrial application of flotation column technology.

  1. TiO2 Solar Photocatalytic Reactor Systems: Selection of Reactor Design for Scale-up and Commercialization—Analytical Review

    Directory of Open Access Journals (Sweden)

    Yasmine Abdel-Maksoud

    2016-09-01

    Full Text Available For the last four decades, viability of photocatalytic degradation of organic compounds in water streams has been demonstrated. Different configurations for solar TiO2 photocatalytic reactors have been used, however pilot and demonstration plants are still countable. Degradation efficiency reported as a function of treatment time does not answer the question: which of these reactor configurations is the most suitable for photocatalytic process and optimum for scale-up and commercialization? Degradation efficiency expressed as a function of the reactor throughput and ease of catalyst removal from treated effluent are used for comparing performance of different reactor configurations to select the optimum for scale-up. Comparison included parabolic trough, flat plate, double skin sheet, shallow ponds, shallow tanks, thin-film fixed-bed, thin film cascade, step, compound parabolic concentrators, fountain, slurry bubble column, pebble bed and packed bed reactors. Degradation efficiency as a function of system throughput is a powerful indicator for comparing the performance of photocatalytic reactors of different types and geometries, at different development scales. Shallow ponds, shallow tanks and fountain reactors have the potential of meeting all the process requirements and a relatively high throughput are suitable for developing into continuous industrial-scale treatment units given that an efficient immobilized or supported photocatalyst is used.

  2. Particle-bubble aggregate stability on static bubble generated by single nozzle on flotation process

    Science.gov (United States)

    Warjito, Harinaldi, Setyantono, Manus; Siregar, Sahala D.

    2016-06-01

    There are three sub-processes on flotation. These processes are intervening liquid film into critical thickness, rupture of liquid film forming three phase contact line, and expansion three phase contact line forming aggregate stability. Aggregate stability factor contribute to determine flotation efficiency. Aggregate stability has some important factors such as reagent and particle geometry. This research focussed on to understand effect of particle geometry to aggregate stability. Experimental setup consists of 9 x 9 x26 cm flotation column made of glass, bubble generator, particle feeding system, and high speed video camera. Bubble generator made from single nozzle with 0.3 mm diameter attached to programmable syringe pump. Particle feeding system made of pipette. Particle used in this research is taken from open pit Grasberg in Timika, Papua. Particle has sub-angular geometry and its size varies from 38 to 300 µm. Bubble-particle interaction are recorded using high speed video camera. Recordings from high speed video camera analyzed using image processing software. Experiment result shows that aggregate particle-bubble and induction time depends on particle size. Small particle (38-106 µm) has long induction time and able to rupture liquid film and also forming three phase contact line. Big particle (150-300 µm) has short induction time, so it unable to attach with bubble easily. This phenomenon is caused by apparent gravity work on particle-bubble interaction. Apparent gravity worked during particle sliding on bubble surface experience increase and reached its maximum magnitude at bubble equator. After particle passed bubble equator, apparent gravity force experience decrease. In conclusion particle size from 38-300 µm can form stable aggregate if particle attached with bubble in certain condition.

  3. Solids mixing in bubbling fluidized beds: CFD-based analysis of Bubble Dynamics and Time Scales

    Science.gov (United States)

    Bakshi, Akhilesh; Altantzis, Christos; Ghoniem, Ahmed

    2016-11-01

    In bubbling fluidized bed reactors, solids mixing is critical because it directly affects fuel segregation and residence time. However, there continues to be a lack of understanding because (a) most diagnostic techniques are only feasible in lab-scale setups and (b) the dynamics are sensitive to the operating conditions. Thus, quantitative estimates of mixing (e.g., dispersion coefficient, mixing indices) often span orders of magnitude although it is well accepted that the micro-mixing and gross circulation of solid particles is driven by bubble motion. To quantify this dependence, solids mixing is investigated using fine-grid 3D CFD simulations of a large 50 cm diameter fluidized bed. Detailed diagnostics of the computed flow-field data are performed using MS3DATA, a tool that we developed to detect and track bubbles, and the solids motion is correlated with the spatial and size distribution of bubbles. This study will be useful for quantifying mixing at commercial scales.

  4. Reading Columns

    OpenAIRE

    Coutts, Marion

    2008-01-01

    Reading Columns are twin permanent public sculptures commissioned as part of a £245m scheme for the redevelopment of the Chatham Place area in Reading. Dimensions: 3.5m high x 1.3m diameter each Field of knowledge: The work consists of twin bespoke columns of stainless steel and glass over digital colour transparencies. The piece revisits and reworks the idea of the Morris Column, a 19th C feature characteristic of major European metropolitan centres. A wraparound image on each of ...

  5. Estimation of the lifetime of small helium bubbles near tungsten surfaces - A methodological study

    Science.gov (United States)

    Cui, Jiechao; Wu, Zhangwen; Hou, Qing

    2016-09-01

    Under low energy and high flux/fluence irradiation of helium (He) atoms, the formation and bursting of He bubbles on tungsten (W) surfaces play important roles in the morphological evolution of component surfaces in fusion reactors. Microscopically, the bursting of He bubbles is a stochastic process, and He bubbles have statistically average lifetimes. In the present paper, a molecular dynamics-based method was developed to extract, for the first time, the lifetime of He bubbles near tungsten surfaces. It was found that He bubble bursting can be treated as an activated event. Its frequency or, equivalently, the average lifetime of bubbles follows the Arrhenius equation. For a given bubble size, the activation energy exhibits a good linear dependence with the depth, and the pre-exponential factor obeys the Meyer-Neldle rule. These results are useful for establishing a model in multi-scale simulations of the morphological evolution of component surfaces in fusion reactors.

  6. Fuzzy Based composition Control of Distillation Column

    Directory of Open Access Journals (Sweden)

    Guru.R

    2013-04-01

    Full Text Available This paper proposed a control scheme based on fuzzy logic for a methanol - water system of bubble cap distillation column. Fuzzy rule base and Inference System of fuzzy (FIS is planned to regulatethe reflux ratio (manipulated variable to obtain the preferred product composition (methanol for a distillation column. Comparisons are made with conventional controller and the results confirmed the potentials of the proposed strategy of fuzzy control.

  7. Separation of Oil from Wastewater by Column Flotation

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    A new type of device, a dissolved-air flotation column, was developed for separation of oily wastewater.The unique design idea of the dissolved-air flotation column is the combined use of dissolved-air flotation and column flotation.The dissolved air release occurred within the column separation system.As a potential application the column was investigated for its performance in separating emulsified oil droplets in oily wastewater.A high separation efficiency was obtained in a series of tests.The aeration performance of the bubble generator used in the dissolved-air flotation column was also studied in particular.

  8. Nanoemulsions obtained via bubble bursting at a compound interface

    CERN Document Server

    Feng, Jie; Vigolo, Daniele; Arnaudov, Luben N; Stoyanov, Simeon D; Gurkov, Theodor D; Tsutsumanova, Gichka G; Stone, Howard A

    2013-01-01

    The bursting of bubbles at an air/liquid interface is a familiar occurrence important to foam stability, cell cultures in bioreactors and mass transfer between the sea and atmosphere. Here we document the hitherto unreported formation and dispersal into the water column of submicrometre oil droplets following bubble bursting at a compound air/oil/water-with-surfactant interface. We show that dispersal results from the detachment of an oil spray from the bottom of the bubble towards water during bubble collapse. We provide evidence that droplet size is selected by physicochemical interactions between oil molecules and the surfactants rather than by hydrodynamic effects. We illustrate the unrecognized role that this dispersal mechanism may play in the fate of the sea surface micro-layer and of pollutant spills by dispersing petroleum in the water column. Finally, our system provides an energy-efficient route, with potential upscalability and wide applicability, for applications in drug delivery, food production...

  9. The jet flotation column control system

    Energy Technology Data Exchange (ETDEWEB)

    Xu Zhiqiang; Ming Shangzhi; Liu Lijian; Huangfu Jinghua; Huo Sen; Zhang Rongzeng [China Univ. of Mining and Technology, Beijing (China). Mineral Processing Dept.; Yang Hongjun [Hebi Coal Mine Administrative (China)

    1998-12-31

    Compared with the conventional mechanical flotation column, the jet flotation column has the advantages of high selectivity of separation, low investment and production cost, low floor space requirement, low dosage of reagent, easy control; it is more suitable to process fine particles. Recently, many new types of flotation columns have been developed with new methods. Mineral Processing Dept., China University of Mining and Technology (Beijing) designed an aerated, double-jet flotation column in the lab and the industrial trial will be put into operation. One of the significant characteristics of the new type of flotation column is high selectivity of separation, fast bubble mineralization speed. As it is sensitive to various factors, a control system for flotation column has been developed to stabilize the working condition, and this set of control system has been operated in the lab experiment.

  10. Simultaneous determination of imidacloprid and carbendazim in water samples by ion chromatography with fluorescence detector and post-column photochemical reactor.

    Science.gov (United States)

    Subhani, Qamar; Huang, Zhongping; Zhu, Zuoyi; Zhu, Yan

    2013-11-15

    A new analytical method has been developed and validated for the simultaneous determination of pesticides from different classes using ion chromatography-online photochemical derivatisation-fluorescence detector (IC-hv-FD). Fluorimetric detection was performed at λex/λem=332 nm/367 nm for imidacloprid and then detector was set at λex/λem=247 nm/470 nm for carbendazim. The two pesticides imidacloprid and carbendazim were successfully separated isocratically on an IonPac(®) AS11 (250 mm × 4 mm i.d; 13 µm particle size, Dionex) anion-exchange column using 40 mM KOH with 10% (v/v) acetonitrile and pumped at a flow rate of 1.0 mL min(-1). Under the optimized conditions, the limit of detection (LOD, S/N=3) of imidacloprid and carbendazim were 7.8 µg L(-1) and 67 µg L(-1), respectively. The experimental results showed that there was good linearity with a correlation coefficient (r)≥0.9966 over the range of 0.05-10 mg L(-1) for imidacloprid and 0.2-15 mg L(-1) for carbendazim. Good reproducibility with a relative standard deviation (RSD, n=7) less than 4.5%. Finally, the proposed method was applied with satisfactory results to the analysis of these pesticides in ground water, lake water and river water without any pre-treatment of samples. The average spiked recoveries were in the range of 90-104%.

  11. Bubble motion measurements during foam drainage and coarsening.

    Science.gov (United States)

    Maurdev, G; Saint-Jalmes, A; Langevin, D

    2006-08-15

    We have studied bubble motion within a column of foam allowed to undergo free drainage. We have measured bubble motion upward with time and as a function of their initial positions. Depending on the gas used, which sets the coarsening and drainage rates, different bubble upward motion types have been identified (constant speed, acceleration or deceleration) and explained in relation with liquid downward flows. The proofs of the consistency between bubble upward motion and liquid downward flow are obtained both by comparing the bubble motion curves to the liquid drainage ones, and by comparing the time variations of the liquid fraction extracted from bubble motion to direct liquid fraction measurements by electrical conductimetry. The agreement between bubble position tracking and electrical conductivity shows in particular that it is possible to determine the drainage regime from such simple bubble motion measurements. This work also allowed us to demonstrate a special case of foam coarsening and expansion, occurring when the foam gas is less soluble than the outside one, caused by diffusion of this external gas into the foam. All these results allow us to build a picture of drainage and coarsening seen from the bubble point of view.

  12. Effects of surface orientation on lifetime of near-surface nanoscale He bubble in tungsten

    Science.gov (United States)

    Cui, Jiechao; Fu, Baoqin; Wu, Zhangwen; Hou, Qing

    2017-02-01

    In multiscale modeling of the morphological evolution of plasma facing materials in nuclear fusion reactors, the knowledge of the timescales of the involved physical processes is important. In the present study, a new method based on molecular dynamics simulations was developed to extract the lifetime of helium bubbles near tungsten surfaces. It was found that the lifetime of a helium bubble can be described by the Arrhenius equation. However, the lifetime of a helium bubble depends on the thickness of tungsten film above the helium bubble in the substrate and the bubble size. The influence of surface orientations on the lifetime of helium bubbles was also observed, and the performance of helium bubbles on the (1 1 1) surface is very different from on the (0 0 1) and (0 1 1) surfaces. The role of the helium bubble lifetime in other simulation techniques, such as in kinetic Monte Carlo methods and rate theory, is discussed.

  13. 旋流微泡浮选柱在涡北选煤厂的应用%Application of cyclon micro bubble flotation column in Wobei coal preparation plant

    Institute of Scientific and Technical Information of China (English)

    冯立品; 周孟颖; 徐晓琦

    2011-01-01

    According to analysis of the size composition of coal slime, find that coal gangue pelitization, high content of high-ash fine mud are bad for Rotating. Single facter flotation tests of flotation machine, two factors and three levels orthogonal tests, substep releasing tests with the optimal mixture of flotation reagents have been taken. The results show that,while the mass concentration of coal slime pulp is 45 g/L and mixture flotation reagents is 1. 10 kg/t,clean coal ash could reaches 10. 97% productivity of clean coal is 72. 62% ,improved flotation index is up to 53. 43% and the flotation machine works best. The flotation column could separate all kinds of fine coal,fine coal ash could be adjusted in wide range in order to meet the requirements. The comprehensive contrast tests of flotation machine and flotation column are taken at last, disposing the same clean coal ash, the results show that flotation column could highly improve clean coal recovery and flotation index compared with the flotation machine.%分析了涡北选煤厂煤泥粒度组成,发现煤样矸石存在泥化现象,高灰细泥含量较高,对浮选不利.进行了浮选机的单因素浮选试验、两因素三水平正交试验以及最优药剂条件下的分步释放试验,同时进行了浮选柱的煤泥浮选试验.结果表明,当煤泥矿浆质量浓度为45 g/L,复合药剂为1.10 kg/t时,精煤灰分为10.97%,精煤产率为72.62%,浮选完善指标最高为53.43%,浮选机煤泥浮选效果最好;浮选柱可以分选出各种质量的精煤,精煤灰分可调性大,可以适应市场变化.最后进行了浮选机和浮选柱的综合对比试验,在精煤灰分相近的情况下,浮选柱不同程度地提高了精煤回收率和浮选完善指标,具有明显优势.

  14. Luminescence from Tube-Arrest Bubbles in Pure Glycerin

    Institute of Scientific and Technical Information of China (English)

    陈岐岱; 王龙

    2004-01-01

    Single transient cavitation bubble with luminescence has been generated in pure glycerin by using the ‘tube arrest'method. The analyses of high-speed photograph and light emission data suggest that the light emission would be a single bubble sonoluminescence. The luminescence pulse width is observed to wry from sub-nanosecond to about 30 ns. The width and intensity of luminescence pulses increases with the height of the liquid column height and decreases with the liquid temperature.

  15. Tribonucleation of bubbles

    CERN Document Server

    Wildeman, Sander; Sun, Chao; Lohse, Detlef; Prosperetti, Andrea

    2016-01-01

    We report on the nucleation of bubbles on solids that are gently rubbed against each other in a liquid. The phenomenon is found to depend strongly on the material and roughness of the solid surfaces. For a given surface, temperature, and gas content, a trail of growing bubbles is observed if the rubbing force and velocity exceed a certain threshold. Direct observation through a transparent solid shows that each bubble in the trail results from the early coalescence of several microscopic bubbles, themselves detaching from microscopic gas pockets forming between the solids. From a detailed study of the wear tracks, with atomic force and scanning electron microscopy imaging, we conclude that these microscopic gas pockets originate from a local fracturing of the surface asperities, possibly enhanced by chemical reactions at the freshly created surfaces. Our findings will be useful either for preventing undesired bubble formation or, on the contrary, for "writing with bubbles," i.e., creating controlled patterns ...

  16. PULSE COLUMN

    Science.gov (United States)

    Grimmett, E.S.

    1964-01-01

    This patent covers a continuous countercurrent liquidsolids contactor column having a number of contactor states each comprising a perforated plate, a layer of balls, and a downcomer tube; a liquid-pulsing piston; and a solids discharger formed of a conical section at the bottom of the column, and a tubular extension on the lowest downcomer terminating in the conical section. Between the conical section and the downcomer extension is formed a small annular opening, through which solids fall coming through the perforated plate of the lowest contactor stage. This annular opening is small enough that the pressure drop thereacross is greater than the pressure drop upward through the lowest contactor stage. (AEC)

  17. Bubble-sweeping mechanisms

    Institute of Scientific and Technical Information of China (English)

    WANG; Hao; (王; 昊); PENG; Xiaofeng; (彭晓峰); WANG; Buxuan; (王补宣); LEE; Duzhong; (李笃中)

    2003-01-01

    A series of subcooled boiling experiments was conducted on very small platinum wires having diameters of 0.1 and 0.025 mm. Vapor bubbles were visually observed to sweep back and forth along the wires in the experiments. The dynamic characteristics of bubble-sweeping phenomenon are described, and the induced bubble interaction and nonlinear growth are investigated to understand the boiling heat transfer mechanisms. An unsymmetrical temperature model is proposed to explain the physical mechanism.

  18. Bubbles and market crashes

    CERN Document Server

    Youssefmir, M; Hogg, T; Youssefmir, Michael; Huberman, Bernardo; Hogg, Tad

    1994-01-01

    We present a dynamical theory of asset price bubbles that exhibits the appearance of bubbles and their subsequent crashes. We show that when speculative trends dominate over fundamental beliefs, bubbles form, leading to the growth of asset prices away from their fundamental value. This growth makes the system increasingly susceptible to any exogenous shock, thus eventually precipitating a crash. We also present computer experiments which in their aggregate behavior confirm the predictions of the theory.

  19. A Better Method for Filling Pasteur Pipet Chromatography Columns

    Science.gov (United States)

    Ruekberg, Ben

    2006-01-01

    An alternative method for the preparation of Pasteur pipet chromatography columns is presented that allows the column to be filled with solvent without bubbles and allows greater control of fluid flow while the materials to be separated are added. Students are required to wear gloves and goggles and caution should be used while handling glass…

  20. Physics of bubble oscillations

    Energy Technology Data Exchange (ETDEWEB)

    Lauterborn, Werner; Kurz, Thomas [Third Physical Institute, University of Goettingen (Germany)

    2010-10-01

    Bubbles in liquids, soft and squeezy objects made of gas and vapour, yet so strong as to destroy any material and so mysterious as at times turning into tiny light bulbs, are the topic of the present report. Bubbles respond to pressure forces and reveal their full potential when periodically driven by sound waves. The basic equations for nonlinear bubble oscillation in sound fields are given, together with a survey of typical solutions. A bubble in a liquid can be considered as a representative example from nonlinear dynamical systems theory with its resonances, multiple attractors with their basins, bifurcations to chaos and not yet fully describable behaviour due to infinite complexity. Three stability conditions are treated for stable trapping of bubbles in standing sound fields: positional, spherical and diffusional stability. Chemical reactions may become important in that respect, when reacting gases fill the bubble, but the chemistry of bubbles is just touched upon and is beyond the scope of the present report. Bubble collapse, the runaway shrinking of a bubble, is presented in its current state of knowledge. Pressures and temperatures that are reached at this occasion are discussed, as well as the light emission in the form of short flashes. Aspherical bubble collapse, as for instance enforced by boundaries nearby, mitigates most of the phenomena encountered in spherical collapse, but introduces a new effect: jet formation, the self-piercing of a bubble with a high velocity liquid jet. Examples of this phenomenon are given from light induced bubbles. Two oscillating bubbles attract or repel each other, depending on their oscillations and their distance. Upon approaching, attraction may change to repulsion and vice versa. When being close, they also shoot self-piercing jets at each other. Systems of bubbles are treated as they appear after shock wave passage through a liquid and with their branched filaments that they attain in standing sound fields. The N-bubble

  1. Bubble and drop interfaces

    CERN Document Server

    Miller

    2011-01-01

    The book aims at describing the most important experimental methods for characterizing liquid interfaces, such as drop profile analysis, bubble pressure and drop volume tensiometry, capillary pressure technique, and oscillating drops and bubbles. Besides the details of experimental set ups, also the underlying theoretical basis is presented in detail. In addition, a number of applications based on drops and bubbles is discussed, such as rising bubbles and the very complex process of flotation. Also wetting, characterized by the dynamics of advancing contact angles is discussed critically. Spec

  2. Column: lef

    NARCIS (Netherlands)

    Reep, Frans van der

    2012-01-01

    1e alinea column: Ook in je beleggingsbeslissingen is het voor echte performance wellicht tijd om eens voorbij best practices (dan word je namelijk hoogstens tweede) te kijken naar next practices. Als je op zeker speelt, verdien je weinig geld. Want anderen gingen je al voor. Maar kun je nog meer op

  3. Fluctuations of the Solitary Bubble at the Separation from the Air Cavity, Compressed by the Magnetic Field in Magnetic Liquid

    Directory of Open Access Journals (Sweden)

    M.L. Boev

    2013-12-01

    Full Text Available In the article, on the basis of the concept of "display" of geometry of a free surface of the "low-magnetic" environment by the topography of isolines of the module of intensity of a magnetic field, it is studied a form of a free surface of magnetic fluid in a static condition at the initial stage of rapprochement of a ring magnet with a surface of a column of magnetic fluid in a tube and at a stage of pressing of a cavity to a bottom. It is shown that the separation of bubbles from an air cavity occurs in close proximity to the plane of symmetry of a ring magnet on its axis. It is described the method and experimental installation for studying the possibility of electromagnetic indication of sizes of the air bubbles, being in magnetic fluid. It is discussed the results of experimental research on process of a separation of solitary air bubble from a cavity, contained in magnetic fluid and squeezed by ponderomotive forces of a magnetic field which are of interest for creation of essentially new technique of the dosed supply of small amount of gas in the reactor.

  4. Effects of surfactant on bubble hydrodynamic behavior under flotation-related conditions in wastewater.

    Science.gov (United States)

    Li, Yanpeng; Zhu, Tingting; Liu, Yanyan; Tian, Ye; Wang, Huanran

    2012-01-01

    Bubble behavior is fundamental to the performance of froth flotation operations used in wastewater treatment processes. To fully understand and characterize bubble behavior under flotation-related conditions in wastewater, the high-speed photographic method has been employed to examine the motion of single bubbles and size distribution of bubble swarms with intermediate sizes ranging from 1 to 4 mm in the presence of surfactants in a laboratory scale flotation column. Both distilled water and synthetic municipal wastewater have been used to make solutions as well as two types of common surfactants. The instantaneous bubble motion has been recorded by a high speed camera. Subsequently, bubble trajectory, dimensions, velocity and distribution have been determined from the recorded frames using the image analysis software. The experimental results show that the addition of surfactant into wastewater has similar effects on bubble hydrodynamic behavior as in pure water (e.g., improving trajectory stabilization, dampening bubble deformation, slowing down terminal velocity, reducing bubble size and increasing the specific surface area of bubble swarm) due to the Marangoni effect. However, it is interesting to note that surfactant effects on single bubble hydrodynamics in wastewater are slightly stronger than those in pure water while surfactant effects on size parameters of bubble swarms in wastewater are significantly stronger than those in pure water. This finding suggests that besides surfactant, inorganic salts present in synthetic wastewater have an important influence on bubble dispersion.

  5. Prospects for bubble fusion

    Energy Technology Data Exchange (ETDEWEB)

    Nigmatulin, R.I. [Tyumen Institute of Mechanics of Multiphase Systems (TIMMS), Marx (Russian Federation); Lahey, R.T. Jr. [Rensselaer Polytechnic Institute, Troy, NY (United States)

    1995-09-01

    In this paper a new method for the realization of fusion energy is presented. This method is based on the superhigh compression of a gas bubble (deuterium or deuterium/thritium) in heavy water or another liquid. The superhigh compression of a gas bubble in a liquid is achieved through forced non-linear, non-periodic resonance oscillations using moderate amplitudes of forcing pressure. The key feature of this new method is a coordination of the forced liquid pressure change with the change of bubble volume. The corresponding regime of the bubble oscillation has been called {open_quotes}basketball dribbling (BD) regime{close_quotes}. The analytical solution describing this process for spherically symmetric bubble oscillations, neglecting dissipation and compressibility of the liquid, has been obtained. This solution shown no limitation on the supercompression of the bubble and the corresponding maximum temperature. The various dissipation mechanisms, including viscous, conductive and radiation heat losses have been considered. It is shown that in spite of these losses it is possible to achieve very high gas bubble temperatures. This because the time duration of the gas bubble supercompression becomes very short when increasing the intensity of compression, thus limiting the energy losses. Significantly, the calculated maximum gas temperatures have shown that nuclear fusion may be possible. First estimations of the affect of liquid compressibility have been made to determine possible limitations on gas bubble compression. The next step will be to investigate the role of interfacial instability and breaking down of the bubble, shock wave phenomena around and in the bubble and mutual diffusion of the gas and the liquid.

  6. Nuclear Reactors

    Energy Technology Data Exchange (ETDEWEB)

    Hogerton, John

    1964-01-01

    This pamphlet describes how reactors work; discusses reactor design; describes research, teaching, and materials testing reactors; production reactors; reactors for electric power generation; reactors for supply heat; reactors for propulsion; reactors for space; reactor safety; and reactors of tomorrow. The appendix discusses characteristics of U.S. civilian power reactor concepts and lists some of the U.S. reactor power projects, with location, type, capacity, owner, and startup date.

  7. Evaporation, Boiling and Bubbles

    Science.gov (United States)

    Goodwin, Alan

    2012-01-01

    Evaporation and boiling are both terms applied to the change of a liquid to the vapour/gaseous state. This article argues that it is the formation of bubbles of vapour within the liquid that most clearly differentiates boiling from evaporation although only a minority of chemistry textbooks seems to mention bubble formation in this context. The…

  8. Turbulence, bubbles and drops

    NARCIS (Netherlands)

    Veen, van der Roeland Cornelis Adriaan

    2016-01-01

    In this thesis, several questions related to drop impact and Taylor-Couette turbulence are answered. The deformation of a drop just before impact can cause a bubble to be entrapped. For many applications, such as inkjet printing, it is crucial to control the size of this entrapped bubble. To study t

  9. Bubbles in graphene

    DEFF Research Database (Denmark)

    Settnes, Mikkel; Power, Stephen; Lin, Jun

    2015-01-01

    Strain-induced deformations in graphene are predicted to give rise to large pseudomagnetic fields. We examine theoretically the case of gas-inflated bubbles to determine whether signatures of such fields are present in the local density of states. Sharp-edged bubbles are found to induce Friedel...

  10. Single bubble sonoluminescence

    NARCIS (Netherlands)

    Brenner, Michael P.; Hilgenfeldt, Sascha; Lohse, Detlef

    2002-01-01

    Single-bubble sonoluminescence occurs when an acoustically trapped and periodically driven gas bubble collapses so strongly that the energy focusing at collapse leads to light emission. Detailed experiments have demonstrated the unique properties of this system: the spectrum of the emitted light ten

  11. Bubble collision with gravitation

    CERN Document Server

    Hwang, Dong-il; Lee, Wonwoo; Yeom, Dong-han

    2012-01-01

    In this paper, we study vacuum bubble collisions with various potentials including gravitation, assuming spherical, planar, and hyperbolic symmetry. We use numerical calculations from double-null formalism. Spherical symmetry can mimic the formation of a black hole via multiple bubble collisions. Planar and especially hyperbolic symmetry describes two bubble collisions. We study both cases, when two true vacuum regions have the same field value or different field values, by varying tensions. For the latter case, we also test symmetric and asymmetric bubble collisions, and see details of causal structures. If the colliding energy is sufficient, then the vacuum can be destabilized, and it is also demonstrated. This double-null formalism can be a complementary approach in the context of bubble collisions.

  12. On 3D reconstruction of bubbles in volcanic ash particles

    Science.gov (United States)

    Proussevitch, A.; Sahagian, D.; Mulukutla, G.; Kiely, C.

    2007-12-01

    Bubbles in volcanic ash particles are primarily represented by the remnants of films and plateau borders from disrupting foam. Without preservation of complete bubbles, measuring bubble size distributions a challenging task, but one for which we have taken a novel approach. Concavities in ash particles retain a record of bubble sizes in the curvature of their concave surfaces that resulted from bubble fragmentation and quenching during energetic magma eruptions. We have used two methods to measure bubble fragment curvature on the basis of 3D reconstruction of ash particle surfaces. One is based on High Resolution X-Ray Tomography (HRXRT) and the second one is based on stereo images from tilting Scattered Electron Microscopy (SEM). Both methods allow the creation of Digital Elevation Model (DEM) datasets of the ash particle surfaces which in turn are used to identify and measure vertical cross-sectional profiles of the individual bubble fragments ("craters"). Function fit analysis for circular or elliptical functions are applied to each bubble cross sectional profile in two orthogonal directions to reconstruct sizes of the original, complete bubbles. The method allows measurement of submicron (SEM; XUM), micron or larger (HRXRT) bubbles in ash particles. The bubble size distributions so obtained can provide valuable insights regarding magma dynamics and vesiculation that lead to explosive eruptions, as well as the processes of fragmentation in eruption columns. There are no previous systematic information/databases of vesiculation metrics for explosive silicic eruptions, but this new method can be used to produce these and thus provide better insights into prehistoric eruption styles for volcanic hazard assessment.

  13. Production of large size single transient cavitation bubbles with tube arrest method

    Institute of Scientific and Technical Information of China (English)

    Chen Qi-Dai; Wang Long

    2004-01-01

    Large size single transient cavitation bubbles of maximum diameter up to 3 cm with sonoluminescence have been column motion is proposed. The results of numerical simulation are compared with the experimental data of the bubble size and oscillation period as the key parameters.

  14. Electric-field enhanced fluidized beds : a low-energy bubble control method

    NARCIS (Netherlands)

    Kleijn van Willigen, F.

    2006-01-01

    Reducing the size of gas bubbles can significantly improve the performance of gas-solid fluidized beds one of the most common reactor types in the chemical industry applied for such diverse systems as gasoline and plastics production to foods processing. However, a control of bubbles in these reac

  15. Effect of bubble size on nanofiber diameter in bubble electrospinning

    Directory of Open Access Journals (Sweden)

    Ren Zhong-Fu

    2016-01-01

    Full Text Available Polymer bubbles are widely used for fabrication of nanofibers. Bubble size affects not only bubble's surface tension, but also fiber's morphology. A mathematical model is established to reveal the effect of bubble size on the spinning process, and the experiment verification shows the theoretical analysis is reliable.

  16. EXPERIMENTAL BUBBLE FORMATION IN A LARGE SCALE SYSTEM FOR NEWTONIAN AND NONNEWTONIAN FLUIDS

    Energy Technology Data Exchange (ETDEWEB)

    Leishear, R; Michael Restivo, M

    2008-06-26

    The complexities of bubble formation in liquids increase as the system size increases, and a photographic study is presented here to provide some insight into the dynamics of bubble formation for large systems. Air was injected at the bottom of a 28 feet tall by 30 inch diameter column. Different fluids were subjected to different air flow rates at different fluid depths. The fluids were water and non-Newtonian, Bingham plastic fluids, which have yield stresses requiring an applied force to initiate movement, or shearing, of the fluid. Tests showed that bubble formation was significantly different in the two types of fluids. In water, a field of bubbles was formed, which consisted of numerous, distributed, 1/4 to 3/8 inch diameter bubbles. In the Bingham fluid, large bubbles of 6 to 12 inches in diameter were formed, which depended on the air flow rate. This paper provides comprehensive photographic results related to bubble formation in these fluids.

  17. Atomistic simulation of He bubble in Fe as obstacle to dislocation

    Science.gov (United States)

    Hafez Haghighat, S. M.; Lucas, G.; Schäublin, R.

    2009-07-01

    Degradation of mechanical properties due to nanometric irradiation induced defects is one of the challenging issues in designing materials for future fusion reactors. Various types of defects such as voids and He bubbles may be produced due to high dose of neutron irradiation due to fusion reaction. We study the influence of He bubble on the mobility of an edge dislocation in pure bcc-Fe using molecular dynamics simulation as a function of bubble size, He density and temperature. It appears that low contents He bubbles are penetrable defects, which size and temperature rise make them harder and softer, respectively. At high He contents a size dependent loop punching is observed, which at larger bubble sizes leads to a multistep dislocation-defect interaction. It also appears that the bubble surface curvature and temperature are the main parameters in the screw segments annihilation needed for the release of the dislocation from the bubble.

  18. Ex-situ biogas upgrading and enhancement in different reactor systems.

    Science.gov (United States)

    Kougias, Panagiotis G; Treu, Laura; Benavente, Daniela Peñailillo; Boe, Kanokwan; Campanaro, Stefano; Angelidaki, Irini

    2017-02-01

    Biogas upgrading is envisioned as a key process for clean energy production. The current study evaluates the efficiency of different reactor configurations for ex-situ biogas upgrading and enhancement, in which externally provided hydrogen and carbon dioxide were biologically converted to methane by the action of hydrogenotrophic methanogens. The methane content in the output gas of the most efficient configuration was >98%, allowing its exploitation as substitute to natural gas. Additionally, use of digestate from biogas plants as a cost efficient method to provide all the necessary nutrients for microbial growth was successful. High-throughput 16S rRNA sequencing revealed that the microbial community was resided by novel phylotypes belonging to the uncultured order MBA08 and to Bacteroidales. Moreover, only hydrogenotrophic methanogens were identified belonging to Methanothermobacter and Methanoculleus genera. Methanothermobacter thermautotrophicus was the predominant methanogen in the biofilm formed on top of the diffuser surface in the bubble column reactor.

  19. CENTRAL COMPOSITE STATISTICAL ASSESSMENT OF GAS-LIQUID MASS TR ANSFER IN SLURRY BUBBLE COLUMN REACTOR%中心复合设计法研究浆液床反应器的气液传质特性

    Institute of Scientific and Technical Information of China (English)

    门卓武; Arsam,B

    2000-01-01

    Central composite statistical design approach was employ ed to study the effects of pressure (P),superficial gas velocity (UG) and solid concentration (Cv) on the volumetric gas-liquid mass transfer c oefficient (kLa).The kLa values were found to increase with the increase of superficial gas velocity and pressure,on the other hand,it decre ased with the increase of solid concentration.In the pressure range of 0.1~1.5 MPa,the equilibrium solubility of CH4 appears to follow Henry's Law.%采用中心复合设计法研究系统压力(P)、气体表观气速(UG)以及固体颗粒体积浓度(Cv)对浆液床中体积气液传质系数(kLa)的影响。在实验中发现,体积气液传质系数随系统压力和气体表观气速的增加而增加,当增加固体颗粒体积浓度时反而下降。在0.1~1.5 MPa的压力范围内,甲烷的饱和溶解度遵守亨利定律。

  20. Drift flux modelling for a two-phase system in a flotation column

    Energy Technology Data Exchange (ETDEWEB)

    Vandenberghe, J.; Choung, J.; Xu, Z.; Masliyah, J. [Alberta Univ., Edmonton, AB (Canada). Dept. of Chemical and Materials Engineering

    2005-04-01

    Mineral and coal industries use flotation columns to improve recovery, upgrade products, save energy and reduce scale. Flotation columns are a proven process equipment that are adaptable to computer process control and offer flexible operation. Once gas is introduced to the bottom of the flotation column, bubbles form and rise throughout the pulp. Hydrophobic particles in the pulp attache to the bubbles, making the density of the bubble particle aggregates less than that of the medium. The bubble zone and the froth zone are the 2 main zones of a flotation column. This study applied the drift flux analysis to a wide range of operating conditions of a two-phase system column in order develop a better empirical relation that can predict the bubbly and froth zone characteristics. Tests were performed with process water taken from a bitumen extraction process at Syncrude Canada Limited with aqueous solutions having low concentrations of methyl isobutyl carbinol at 7.8 or 15.5 ppm. A new correlation for the drift flux system characteristic curve was discovered in this study. The new correlation is applicable for a bubble Reynolds number range of 5 to 70. The numerical equation for this correlation was presented. The bubble and froth zones have different hydrodynamics. Therefore, the method for calculating the Reynolds number in the bubble zone may not be suitable for the froth zone. Therefore, a new equation was proposed to accommodate a wider operating range. 16 refs., 1 tab., 13 figs.

  1. Visualization of cavitation bubbles; Visualisation de bulles de cavitation

    Energy Technology Data Exchange (ETDEWEB)

    Chouvellon, M.; Fournel, Th.; Ducottet, Ch. [Universite Jean Monnet, 31 Saint-Etienne (France). Laboratoire Traitement du Signal et Instrumentation-UMR CNRS 5516

    1999-07-01

    A high frequency ultrasonic reactor allows the degradation of some organic compounds which are not or poorly biodegradable by usual methods in industrial flows. The propagation of an ultrasonic wave in a liquid induces cavitation phenomena. The implosion of cavitation bubble locally causes a temperature of about several thousand Kelvins and a pressure of about several hundred bars. Such conditions allow the creation of the hydroxyl radicals and then the oxidation of organic compounds. The aim of this paper is to describe the method used to visualize cavitation bubbles in an ultrasonic reactor at a frequency of 500 kHz. The experimental set-up and the measurement of both the bubble radius and the fringe separation are presented. (authors)

  2. Popping the Bubble

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    Government adopts regulations to control real estate prices A mid concerns surrounding the presence of housing bubbles across China,the Chinese Government is taking action to secure and stabilize the real

  3. Chemistry in Soap Bubbles.

    Science.gov (United States)

    Lee, Albert W. M.; Wong, A.; Lee, H. W.; Lee, H. Y.; Zhou, Ning-Huai

    2002-01-01

    Describes a laboratory experiment in which common chemical gases are trapped inside soap bubbles. Examines the physical and chemical properties of the gases such as relative density and combustion. (Author/MM)

  4. Bubbling Out of Control

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    Jim Chanos,founder of the U.S. hedge fund Kynikos Associates,characterized the prop-erty bubble in China as "Dubai times 1,000-or worse." Many Chinese economists agree. Yi Xianrong,a senior researcher at the Institute of Finance and Banking under the Chinese Academy of Social Sciences,said the property bubble in China was far worse than the Dubai crisis in an interview with the Beijing-based International Herald Leader. Edited excerpts follow:

  5. Bubble chamber: antiproton annihilation

    CERN Multimedia

    1971-01-01

    These images show real particle tracks from the annihilation of an antiproton in the 80 cm Saclay liquid hydrogen bubble chamber. A negative kaon and a neutral kaon are produced in this process, as well as a positive pion. The invention of bubble chambers in 1952 revolutionized the field of particle physics, allowing real tracks left by particles to be seen and photographed by expanding liquid that had been heated to boiling point.

  6. Artificial neural network for bubbles pattern recognition on the images

    Science.gov (United States)

    Poletaev, I. E.; Pervunin, K. S.; Tokarev, M. P.

    2016-10-01

    Two-phase bubble flows have been used in many technological and energy processes as processing oil, chemical and nuclear reactors. This explains large interest to experimental and numerical studies of such flows last several decades. Exploiting of optical diagnostics for analysis of the bubble flows allows researchers obtaining of instantaneous velocity fields and gaseous phase distribution with the high spatial resolution non-intrusively. Behavior of light rays exhibits an intricate manner when they cross interphase boundaries of gaseous bubbles hence the identification of the bubbles images is a complicated problem. This work presents a method of bubbles images identification based on a modern technology of deep learning called convolutional neural networks (CNN). Neural networks are able to determine overlapping, blurred, and non-spherical bubble images. They can increase accuracy of the bubble image recognition, reduce the number of outliers, lower data processing time, and significantly decrease the number of settings for the identification in comparison with standard recognition methods developed before. In addition, usage of GPUs speeds up the learning process of CNN owning to the modern adaptive subgradient optimization techniques.

  7. Methane gas seepage - Disregard of significant water column filter processes?

    Science.gov (United States)

    Schneider von Deimling, Jens; Schmale, Oliver

    2016-04-01

    Marine methane seepage represents a potential contributor for greenhouse gas in the atmosphere and is discussed as a driver for climate change. The ultimate question is how much methane is released from the seafloor on a global scale and what fraction may reach the atmosphere? Dissolved fluxes from methane seepage sites on the seabed were found to be very efficiently reduced by benthic microbial oxidation, whereas transport of free gas bubbles from the seabed is considered to bypass the effective benthic methane filter. Numerical models are available today to predict the fate of such methane gas bubble release to the water column in regard to gas exchange with the ambient water column, respective bubble lifetime and rise height. However, the fate of rising gas bubbles and dissolved methane in the water column is not only governed by dissolution, but is also affected by lateral oceanographic currents and vertical bubble-induced upwelling, microbial oxidation, and physico-chemical processes that remain poorly understood so far. According to this gap of knowledge we present data from two study sites - the anthropogenic North Sea 22/4b Blowout and the natural Coal Oil point seeps - to shed light into two new processes gathered with hydro-acoustic multibeam water column imaging and microbial investigations. The newly discovered processes are hereafter termed Spiral Vortex and Bubble Transport Mechanism. Spiral Vortex describes the evolution of a complex vortical fluid motion of a bubble plume in the wake of an intense gas release site (Blowout, North Sea). It appears very likely that it dramatically changes the dissolution kinetics of the seep gas bubbles. Bubble Transport Mechanism prescribes the transport of sediment-hosted bacteria into the water column via rising gas bubbles. Both processes act as filter mechanisms in regard to vertical transport of seep related methane, but have not been considered before. Spiral Vortex and Bubble Transport Mechanism represent the

  8. The Milky Way Project and ATLASGAL: The distribution and physical properties of cold clumps near infrared bubbles

    CERN Document Server

    Kendrew, S; Simpson, R; Csengeri, T; Wienen, M; Lintott, C J; Povich, M S; Beaumont, C; Schuller, F

    2016-01-01

    We present a statistical study of the distribution and physical properties of cold dense material in and around the inner Galactic Plane near infrared bubbles as catalogued by the Milky Way Project citizen scientists. Using data from the ATLASGAL 870 um survey, we show that 48 +/- 2% of all cold clumps in the studied survey region (|l| <= 65 degrees, |b| <= 1 degree) are found in close proximity to a bubble, and 25 +/- 2% appear directly projected towards a bubble rim. A two-point correlation analysis confirms the strong correlation of massive cold clumps with expanding bubbles. It shows an overdensity of clumps along bubble rims that grows with increasing bubble size, which shows how interstellar medium material is reordered on large scales by bubble expansion around regions of massive star formation. The highest column density clumps appear resistent to the expansion, remaining overdense towards the bubbles' interior rather than being swept up by the expanding edge. Spectroscopic observations in ammon...

  9. Plasma spark discharge reactor and durable electrode

    Energy Technology Data Exchange (ETDEWEB)

    Cho, Young I.; Cho, Daniel J.; Fridman, Alexander; Kim, Hyoungsup

    2017-01-10

    A plasma spark discharge reactor for treating water. The plasma spark discharge reactor comprises a HV electrode with a head and ground electrode that surrounds at least a portion of the HV electrode. A passage for gas may pass through the reactor to a location proximate to the head to provide controlled formation of gas bubbles in order to facilitate the plasma spark discharge in a liquid environment.

  10. Sonoluminescence and multi-bubble cavitation phenomena for selected research and industrial applications

    Science.gov (United States)

    Greenwood, Larry; Olsen, Khris; Good, Morris; Bond, Leonard; Posakony, Gerald; Peters, Timothy; Baldwin, David; Wester, Dennis; Ahmed, Salahuddin

    2003-04-01

    Single bubble sonoluminescence (SBSL), multi-bubble sonoluminescence (MBSL), multi-bubble sonochemiluminescence (MBSCL) and other high power ultrasound cavitation and noncavitating ultrasound process stream interaction phenomena are known to produce a wide range of both physical and chemical effects that depend upon the system and operating conditions employed. Three interacting regimes are under investigation (a) high power and high frequency (including noncavitating systems), (b) single bubble resonance/sonoluminescence and (c) multi-bubble high power sonochemical processing. In all cases these involve various reactors, including possible schemes for continuous material feeding and processing for selected chemical, nonaqueous fluids and biological research and industrial applications. High power sonochemical and noncavitating ultrasound processing applications and a review of literature pertaining to the potential of high power processing, including fusion are discussed. Work includes the investigation of acoustic fields in reactors, characterization of sonoluminescence spectra, the investigation of system parameters to control maximum bubble temperature and pressure, and acoustic energy partition into light and acoustic emission/shock waves. Effects of various chemical systems on multi-bubble luminescence are being investigated and will be reported. Work to date has emphasized the evaluation of both single and multi-bubble sonoluminescence, spectral measurements, acoustic emission measurements and the observation of a continuous bubble feed phenomenon.

  11. Colliding with a crunching bubble

    Energy Technology Data Exchange (ETDEWEB)

    Freivogel, Ben; Freivogel, Ben; Horowitz, Gary T.; Shenker, Stephen

    2007-03-26

    In the context of eternal inflation we discuss the fate of Lambda = 0 bubbles when they collide with Lambda< 0 crunching bubbles. When the Lambda = 0 bubble is supersymmetric, it is not completely destroyed by collisions. If the domain wall separating the bubbles has higher tension than the BPS bound, it is expelled from the Lambda = 0 bubble and does not alter its long time behavior. If the domain wall saturates the BPS bound, then it stays inside the Lambda = 0 bubble and removes a finite fraction of future infinity. In this case, the crunch singularity is hidden behind the horizon of a stable hyperbolic black hole.

  12. Hydrodynamic Characteristics in an External Loop Airlift Slurry Reactor

    Institute of Scientific and Technical Information of China (English)

    Bian Qing; Tang Xiaojin; Hu Lifeng; Wang Shaobing; Zhang Zhanzhu

    2016-01-01

    Three different types of gas distributors were used in an external loop airlift slurry reactor to investigate the hydrodynamic characteristics. To predict the important hydrodynamic parameters, such as the total gas holdup, the slurry circulating velocity, the bubble size distribution, and the slip velocity between the gas phase and the slurry phase, the cor-relations are developed. The calculated results fit the experimental data very well. According to the influence of the solid holdup on the bubble size, the fluid flow in the reactor can be divided into two regimes, while a 10% value is regarded as the critical solid holdup value. Whenεs is≤10%, the bubble size is determined by both the gas phase and the slurry phase. Whenεs is ≥10%, the bubble size is determined mainly by the slurry phase. By analyzing the relationship between the slip velocity and the gas holdup, the bubble coalescence plays a key role in the slurry reactor.

  13. Investigation of bubble-bubble interaction effect during the collapse of multi-bubble system

    Science.gov (United States)

    Shao, Xueming; Zhang, Lingxin; Wang, Wenfeng

    2014-11-01

    Bubble collapse is not only an important subject among bubble dynamics, but also a key consequence of cavitation. It has been demonstrated that the structural damage is associated with the rapid change in flow fields during bubble collapse. How to model and simulate the behavior of the bubble collapse is now of great interest. In the present study, both theoretical analysis and a direct numerical simulation on the basis of VOF are performed to investigate the collapses of single bubble and bubble cluster. The effect of bubble-bubble interaction on the collapse of multi-bubble system is presented. The work was supported by the National Natural Science Foundation of China (11272284, 11332009).

  14. MEASUREMENT OF BUBBLE-BUBBLE INTERACTION DEPENDED ON REYNOLDS NUMBER USING STEREOSCOPIC BUBBLE-TRACKING TECHNIQUE

    Institute of Scientific and Technical Information of China (English)

    QU Jian-wu; MURAI Yuichi; YAMAMOTO Fujio

    2005-01-01

    Bubble-bubble interaction in free rising bubbly flows is experimentally investigated in the present study.The velocity vectors of the bubbles are measured by a stereoscopic bubble-tracking technique and then the relative velocity vectors of two nearest-neighbor bubbles are calculated with high statistical reliability.With the measurement data at Reynolds number ranging from 5 to 75, the vertical attraction and the horizontal repulsion are confirmed for Re<10 as known by the past study based on Navier-Stokes simulation.The new finding of the present measurement is that the bubbles of Re>30 have repulsive velocity bothin the horizontal and the vertical directions as those rise closely.Moreover, the three-dimensional structure of the bubble-bubble interaction is discussed with the data analysis of the interaction vector fields.

  15. Bubble nuclei; Noyaux Bulles

    Energy Technology Data Exchange (ETDEWEB)

    Legoll, F. [Service de Physique Theorique, CEA Centre d`Etudes de Saclay, 91 - Gif-sur-Yvette (France)

    1998-07-22

    For nuclei with very high electrical charge, the Coulomb field is expected to drive the protons away from the centre to the surface of the nucleus. Such a nucleus would be no more compact but look like a bubble. The goal of this work is to confirm this idea. We are interested in only the ground state of spherical nuclei. We use the Skyrme potential with the Sly4 parametrization to calculate the mean-field Hamiltonian. Paring correlations are described by a surface-active delta paring interaction. In its ground state the nucleus {sup A=900} X{sub Z=274} is shown to be a bubble. Another stable state is found with a little higher energy: it is also a bubble. (author) 11 refs., 18 figs., 33 tabs.

  16. Experimantal Study on the Bubble Clustering in Bubbly Flows

    Science.gov (United States)

    Takagi, Shu; Fujiwara, Akiko; Ogasawara, Toshiyuki; Matsumoto, Yoichiro

    2003-11-01

    The statistical properties of bubbly flows and the near-wall bubble-clustering behaviors are investigated for upward flow in a rectangular channel. Bubble size, turbulent properties of liquid phase and the bubble clustering motion were measured using image-processing technique, Laser Doppler Velocimetry (LDV) and Particle Image Velocimetry (PIV), respectively. Using 3-pentanol as a surfactant, the mono-dispersed 1mm-bubbles are generated. The mono-dispersed bubbles in upward flows accumulate near the wall and construct bubble clusters. These bubble clusters were investigated. Experimental observation showed that the size of bubble cluster can be much larger than that of the coherent structure in single phase turbulence. The clusters change their shape in time and space and these bubble motions accelerate the mean streamwise velocity near the wall due to the buoyancy effect. Thus the mean velocity profile of the liquid phase becomes flattened. It is suggested that the highly accumulated bubbles in the vicinity of the wall disturb the transport of turbulence energy produced in the wall shear layer from the central region of the channel flow. Furthermore, in the middle of channel, the fluctuations of the liquid phase are mainly generated by the bubble motions.

  17. Multivariate bubbles and antibubbles

    Science.gov (United States)

    Fry, John

    2014-08-01

    In this paper we develop models for multivariate financial bubbles and antibubbles based on statistical physics. In particular, we extend a rich set of univariate models to higher dimensions. Changes in market regime can be explicitly shown to represent a phase transition from random to deterministic behaviour in prices. Moreover, our multivariate models are able to capture some of the contagious effects that occur during such episodes. We are able to show that declining lending quality helped fuel a bubble in the US stock market prior to 2008. Further, our approach offers interesting insights into the spatial development of UK house prices.

  18. Column flotation of bitumen at Fort Hills

    Energy Technology Data Exchange (ETDEWEB)

    Lizama, H.M. [Teck Cominco, Vancouver, BC (Canada); Romero, D. [UTS Energy Corp., Calgary, AB (Canada); Armour, M. [Petro-Canada, Calgary, AB (Canada)

    2008-05-15

    Flotation columns are used by mineral processors to separate mineral species. The separation is based on the premise that different mineral particles have different surface hydrophobicities. There are 2 carrier phases, notably air bubbles moving up and aqueous pulp moving down. Hydrophobic particles predominantly adhere to rising air bubbles and form a froth, while hydrophilic particles remain in aqueous suspension and flow down and out the bottom of the column. This paper described a demonstration plant near Fort McMurray where bitumen extraction was tested. The plant included 2 columns for bitumen flotation. Oil sands material was passed through a roll sizer and fed to a countercurrent drum separator, where it was mixed with water at 75 degrees C. Column data from the demonstration plant provided the opportunity to examine the separation behaviour during flotation of bitumen. The bitumen grade was described only in terms of bitumen content and solids content in order to simplify the interpretation of the bitumen flotation data. Bitumen/solids separation in the first column was successful at 50 to 60 degrees C, with feeds having bitumen grades between 1 and 19 per cent, and where the solids had about 60 per cent fines. Bitumen/solids separation did not occur in the second column at 50 to 60 degrees C, with feeds having bitumen grades between 8 and 63 per cent, and where the solids had about 90 per cent fines. The lack of separation was probably due to high solids entrainment in the flotation froth. It was concluded that bitumen column flotation data can be analyzed and interpreted by adopting mineral processing principles. Bitumen/solids separation can be evaluated and predicted by plotting solids recovery as a function of bitumen recovery. 7 refs., 1 tab., 6 figs.

  19. The Early Years: Blowing Bubbles

    Science.gov (United States)

    Ashbrook, Peggy

    2016-01-01

    Blowing bubbles is not only a favorite summer activity for young children. Studying bubbles that are grouped together, or "foam," is fun for children and fascinating to many real-world scientists. Foam is widely used--from the bedroom (mattresses) to outer space (insulating panels on spacecraft). Bubble foam can provide children a…

  20. Probing the Southern Fermi Bubble in Ultraviolet Absorption

    Science.gov (United States)

    Karim, Md. Tanveer; Fox, Andrew; Jenkins, Edward B.

    2017-01-01

    The Fermi Bubbles are two giant gamma-ray emitting lobes, extending 55° below and above the Galactic Center, that were discovered in 2010. While the Northern Bubble has been extensively studied in ultraviolet (UV) absorption, little is known about the UV properties of the Southern Bubble. We use UV absorption-line spectra from the Hubble Space Telescope Cosmic Origins Spectrograph (HST/COS) to probe the Southern Fermi Bubble using two sightlines to background AGN, one passing inside the Bubble (RBS 1768) and one passing just outside (RBS 2000). We used VPFIT, a Voigt profile fitting program to detect the existence of high-velocity absorption components and to measure the column density of different metal ions. We detected two high-velocity absorption components in both sightlines; one at vLSR = -150 km s-1 and one at vLSR = 160 km s-1. We determined that the component at vLSR = 160 km s-1 is due to the Magellanic Stream. Absorption is seen in ions of silicon, carbon and aluminium. The discovery that the high-velocity component is present in both sightlines shows that cool gas can extend further from the Galactic plane than the gamma-ray emitting regions. This could indicate past outflow activity prior to the creation of the Southern Bubble. This project was supported in part by the NSF REU grant AST-1358980 and by the Nantucket Maria Mitchell Association.

  1. THE FLOW PATTERNS OF BUBBLE PLUME IN AN MBBR

    Institute of Scientific and Technical Information of China (English)

    LI Shi-rong; CHENG Wen; WANG Meng; CHEN Chen

    2011-01-01

    The flow patterns of the gas-liquid two-phase flow in a Moving-Bed Biofilm Reactor(MBBR)have a critical effect upon the mass transfer by the convection.Bubble plumes promote unsteadily fluctuating two-phase flows during the aeration.This article studies the unsteady structure of bubble plumes through experiments.The time-serial bubble plume images in various cases of the tank are analyzed.The Recursive Cross Correlation-Particle Image Velocimetry(RCC-PIV)is used to calculate the velocities in those cases,and then the time-serial vortex,the total turbulence intensity,the time-serial streamline are obtained.It is shown that the aspect ratio and the void fraction are the dominant factors influencing the unsteady structure of bubble plumes.When the aspect ratio is unity and the void fraction is high,the bubble plumes see a symmetrical vortex structure with a long residence time,which is beneficial for optimizing the aeration system and enhancing the applied range of bubble plumes.

  2. The Liberal Arts Bubble

    Science.gov (United States)

    Agresto, John

    2011-01-01

    The author expresses his doubt that the general higher education bubble will burst anytime soon. Although tuition, student housing, and book costs have all increased substantially, he believes it is still likely that the federal government will continue to pour billions into higher education, largely because Americans have been persuaded that it…

  3. Popping the Bubble

    Institute of Scientific and Technical Information of China (English)

    LAN XINZHEN

    2010-01-01

    @@ Amid concerns surrounding the presence of housing bubbles across China,the Chinese Government is taking action to secure and stabilize the real estate market.In the past month,the government launched a series of regulatory policies aimed at cooling the overheated market.

  4. Scanning bubble chamber pictures

    CERN Multimedia

    1974-01-01

    These were taken at the 2 m hydrogen bubble chamber. The photo shows an early Shiva system where the pre-measurements needed to qualify the event were done manually (cf photo 7408136X). The scanning tables were located in bld. 12. Gilberte Saulmier sits on foreground, Inge Arents at centre.

  5. BEBC bubble chamber

    CERN Multimedia

    1972-01-01

    Looking up into the interior of BEBC bubble chamber from the expansion cylinder. At the top of the chamber two fish-eye lenses are installed and three other fish-eye ports are blanked off. In the centre is a heat exchanger.

  6. Understanding the bubbles

    DEFF Research Database (Denmark)

    Turcan, Romeo V.

    that are identified to exist between the Internet and housing market bubbles: uncertainty and sentiments. The iteration between uncertainty and sentiments leads to the emergence of the third commonality: residue. The residue is the difference between the actors’ overall sentiment about exaggerated future prospects...

  7. Heavy liquid bubble chamber

    CERN Multimedia

    1965-01-01

    The CERN Heavy liquid bubble chamber being installed in the north experimental hall at the PS. On the left, the 1180 litre body; in the centre the magnet, which can produce a field of 26 800 gauss; on the right the expansion mechanism.

  8. Microfluidic "blinking" bubble pump

    NARCIS (Netherlands)

    Yin, Zhizhong; Prosperetti, Andrea

    2005-01-01

    The paper reports data obtained on a simple micropump, suitable for electrolytes, based on the periodic growth and collapse of a single vapor bubble in a microchannel. With a channel diameter of the order of 100 µm, pumping rates of several tens of µl/min and pressure differences of several kPa are

  9. BURST OF STAR FORMATION DRIVES BUBBLE IN GALAXY'S CORE

    Science.gov (United States)

    2002-01-01

    These NASA Hubble Space Telescope snapshots reveal dramatic activities within the core of the galaxy NGC 3079, where a lumpy bubble of hot gas is rising from a cauldron of glowing matter. The picture at left shows the bubble in the center of the galaxy's disk. The structure is more than 3,000 light-years wide and rises 3,500 light-years above the galaxy's disk. The smaller photo at right is a close-up view of the bubble. Astronomers suspect that the bubble is being blown by 'winds' (high-speed streams of particles) released during a burst of star formation. Gaseous filaments at the top of the bubble are whirling around in a vortex and are being expelled into space. Eventually, this gas will rain down upon the galaxy's disk where it may collide with gas clouds, compress them, and form a new generation of stars. The two white dots just above the bubble are probably stars in the galaxy. The close-up reveals that the bubble's surface is lumpy, consisting of four columns of gaseous filaments that tower above the galaxy's disk. The filaments disperse at a height of 2,000 light-years. Each filament is about 75 light-years wide. Velocity measurements taken by the Canada-France-Hawaii Telescope in Hawaii show that the gaseous filaments are ascending at more than 4 million miles an hour (6 million kilometers an hour). According to theoretical models, the bubble formed when ongoing winds from hot stars mixed with small bubbles of very hot gas from supernova explosions. Observations of the core's structure by radio telescopes indicate that those processes are still active. The models suggest that this outflow began about a million years ago. They occur about every 10 million years. Eventually, the hot stars will die, and the bubble's energy source will fade away. Astronomers have seen evidence of previous outbursts from radio and X-ray observations. Those studies show rings of dust and gas and long plumes of material, all of which are larger than the bubble. NGC 3079 is 50

  10. Characteristics of bubble plumes, bubble-plume bubbles and waves from wind-steepened wave breaking

    NARCIS (Netherlands)

    Leifer, I.; Caulliez, G.; Leeuw, G. de

    2007-01-01

    Observations of breaking waves, associated bubble plumes and bubble-plume size distributions were used to explore the coupled evolution of wave-breaking, wave properties and bubble-plume characteristics. Experiments were made in a large, freshwater, wind-wave channel with mechanical wind-steepened w

  11. Bubble dynamics and bubble-induced turbulence of a single-bubble chain

    Science.gov (United States)

    Lee, Joohyoung; Park, Hyungmin

    2016-11-01

    In the present study, the bubble dynamics and liquid-phase turbulence induced by a chain of bubbles injected from a single nozzle have been experimentally investigated. Using a high-speed two-phase particle image velociemtry, measurements on the bubbles and liquid-phase velocity field are conducted in a transparent tank filled with water, while varying the bubble release frequency from 0.1 to 35 Hz. The tested bubble size ranges between 2.0-3.2 mm, and the corresponding bubble Reynolds number is 590-1100, indicating that it belongs to the regime of path instability. As the release frequency increases, it is found that the global shape of bubble dispersion can be classified into two regimes: from asymmetric (regular) to axisymmetric (irregular). In particular, at higher frequency, the wake vortices of leading bubbles cause an irregular behaviour of the following bubble. For the liquid phase, it is found that a specific trend on the bubble-induced turbulence appears in a strong relation to the above bubble dynamics. Considering this, we try to provide a theoretical model to estimate the liquid-phase turbulence induced by a chain of bubbles. Supported by a Grant funded by Samsung Electronics, Korea.

  12. Bubbles generated from wind-steepened breaking waves: 1. Bubble plume bubbles

    NARCIS (Netherlands)

    Leifer, I.; Leeuw, G. de

    2006-01-01

    Measurements of bubble plumes from paddle-amplified, wind stress breaking waves were made in a large wind-wave channel during the LUMINY experiment in fresh (but not clean) water. Bubble plumes exhibited considerable variability with respect to dynamics, bubble size distribution, and physical extent

  13. ADVANCED COMPUTATIONAL MODEL FOR THREE-PHASE SLURRY REACTORS

    Energy Technology Data Exchange (ETDEWEB)

    Goodarz Ahmadi

    2004-10-01

    In this project, an Eulerian-Lagrangian formulation for analyzing three-phase slurry flows in a bubble column was developed. The approach used an Eulerian analysis of liquid flows in the bubble column, and made use of the Lagrangian trajectory analysis for the bubbles and particle motions. The bubble-bubble and particle-particle collisions are included the model. The model predictions are compared with the experimental data and good agreement was found An experimental setup for studying two-dimensional bubble columns was developed. The multiphase flow conditions in the bubble column were measured using optical image processing and Particle Image Velocimetry techniques (PIV). A simple shear flow device for bubble motion in a constant shear flow field was also developed. The flow conditions in simple shear flow device were studied using PIV method. Concentration and velocity of particles of different sizes near a wall in a duct flow was also measured. The technique of Phase-Doppler anemometry was used in these studies. An Eulerian volume of fluid (VOF) computational model for the flow condition in the two-dimensional bubble column was also developed. The liquid and bubble motions were analyzed and the results were compared with observed flow patterns in the experimental setup. Solid-fluid mixture flows in ducts and passages at different angle of orientations were also analyzed. The model predictions were compared with the experimental data and good agreement was found. Gravity chute flows of solid-liquid mixtures were also studied. The simulation results were compared with the experimental data and discussed A thermodynamically consistent model for multiphase slurry flows with and without chemical reaction in a state of turbulent motion was developed. The balance laws were obtained and the constitutive laws established.

  14. Bubble Dynamics and Shock Waves

    CERN Document Server

    2013-01-01

    This volume of the Shock Wave Science and Technology Reference Library is concerned with the interplay between bubble dynamics and shock waves. It is divided into four parts containing twelve chapters written by eminent scientists. Topics discussed include shock wave emission by laser generated bubbles (W Lauterborn, A Vogel), pulsating bubbles near boundaries (DM Leppinen, QX Wang, JR Blake), interaction of shock waves with bubble clouds (CD Ohl, SW Ohl), shock propagation in polydispersed bubbly liquids by model equations (K Ando, T Colonius, CE Brennen. T Yano, T Kanagawa,  M Watanabe, S Fujikawa) and by DNS (G Tryggvason, S Dabiri), shocks in cavitating flows (NA Adams, SJ Schmidt, CF Delale, GH Schnerr, S Pasinlioglu) together with applications involving encapsulated bubble dynamics in imaging (AA Doinikov, A Novell, JM Escoffre, A Bouakaz),  shock wave lithotripsy (P Zhong), sterilization of ships’ ballast water (A Abe, H Mimura) and bubbly flow model of volcano eruptions ((VK Kedrinskii, K Takayama...

  15. Flow mixing model of liquid phase in an internal airlift loop reactor%气升式内环流反应器的液相流动混合模型

    Institute of Scientific and Technical Information of China (English)

    聂大仕; 沈文豪; 刘群姣; 张震宇; 王欣

    2006-01-01

    Residence time distribution (RTD) analysis of liquid phase was conducted in an internal airlift loop reactor (AL) and a bubble column (BC) with the tracer response technique. These data were simulated and compared through several flow mixing models. The modeling results of two-parameter model indicated that there were higher ratio of full mixing zones and lower ratio of bypass flow in AL than in BC. Then a completely mixed-plug flow parallel combined (four-parameter) model was established. Modeling results show that it is more precise and more obvious than two-parameter model.

  16. Automated Composite Column Wrapping

    OpenAIRE

    ECT Team, Purdue

    2007-01-01

    The Automated Composite Column Wrapping is performed by a patented machine known as Robo-Wrapper. Currently there are three versions of the machine available for bridge retrofit work depending on the size of the columns being wrapped. Composite column retrofit jacket systems can be structurally just as effective as conventional steel jacketing in improving the seismic response characteristics of substandard reinforced concrete columns.

  17. CRISIS FOCUS Blowing Bubbles

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    The Chinese stock and property markets have been outperforming expectations, fueled by an unprecedented surge in bank lending. Xie Guozhong, an economist and board member of Rosetta Stone Advisors, argues the robust Chinese economic figures are only propped up by bubbles, whose bursting will lead to a hard landing for the economy. Xie published his opinion in a related article in Caijing Magazine. Edited excerpts follow:

  18. Bubble colloidal AFM probes formed from ultrasonically generated bubbles.

    Science.gov (United States)

    Vakarelski, Ivan U; Lee, Judy; Dagastine, Raymond R; Chan, Derek Y C; Stevens, Geoffrey W; Grieser, Franz

    2008-02-05

    Here we introduce a simple and effective experimental approach to measuring the interaction forces between two small bubbles (approximately 80-140 microm) in aqueous solution during controlled collisions on the scale of micrometers to nanometers. The colloidal probe technique using atomic force microscopy (AFM) was extended to measure interaction forces between a cantilever-attached bubble and surface-attached bubbles of various sizes. By using an ultrasonic source, we generated numerous small bubbles on a mildly hydrophobic surface of a glass slide. A single bubble picked up with a strongly hydrophobized V-shaped cantilever was used as the colloidal probe. Sample force measurements were used to evaluate the pure water bubble cleanliness and the general consistency of the measurements.

  19. H Reactor

    Data.gov (United States)

    Federal Laboratory Consortium — The H Reactor was the first reactor to be built at Hanford after World War II.It became operational in October of 1949, and represented the fourth nuclear reactor on...

  20. Electrowetting of a soap bubble

    CERN Document Server

    Arscott, Steve

    2013-01-01

    A proof-of-concept demonstration of the electrowetting-on-dielectric of a sessile soap bubble is reported here. The bubbles are generated using a commercial soap bubble mixture - the surfaces are composed of highly doped, commercial silicon wafers covered with nanometre thick films of Teflon. Voltages less than 40V are sufficient to observe the modification of the bubble shape and the apparent bubble contact angle. Such observations open the way to inter alia the possibility of bubble-transport, as opposed to droplet-transport, in fluidic microsystems (e.g. laboratory-on-a-chip) - the potential gains in terms of volume, speed and surface/volume ratio are non-negligible.

  1. Investigation of a Bubble Detector based on Active Electrolocation of Weakly Electric Fish

    Science.gov (United States)

    Mohan, M.; Mayekar, K.; Zhou, R.; von der Emde, G.; Bousack, H.

    2013-04-01

    Weakly electric fish employ active electrolocation for navigation and object detection. They emit an electric signal with their electric organ in the tail and sense the electric field with electroreceptors that are distributed over their skin. We adopted this principle to design a bubble detector that can detect gas bubbles in a fluid or, in principle, objects with different electric conductivity than the surrounding fluid. The evaluation of the influence of electrode diameter on detecting a given bubble size showed that the signal increases with electrode diameter. Therefore it appears that this detector will be more appropriate for large sized applications such as bubble columns than small sized applications such as bubble detectors in dialysis.

  2. Observation of bubble formation in water during microwave irradiation by dynamic light scattering

    Science.gov (United States)

    Asakuma, Yusuke; Munenaga, Takuya; Nakata, Ryosuke

    2016-09-01

    A microwave reactor was designed for in situ observation of nano- and micro-bubbles, and size profiles during and after irradiation were measured with respect to irradiation power and time. Bubble formation in water during irradiation was observed even at temperatures below the boiling point of water. The maximum size strongly depended on radiation power and time, even at a given temperature. Nano-particles in the dispersion medium were found to play an important role in achieving more stable nucleation of bubbles around particles, and stable size distributions were obtained from clear autocorrelation by a dynamic light scattering system. Moreover, a combination of microwave induction heating and the addition of nano-particles to the dispersion medium can prevent heterogeneous nucleation of bubbles on the cell wall. Quantitative nano-bubble size profiles obtained by in situ observation provide useful information regarding microwave-based industrial processes for nano-particle production.

  3. Bubble Formation in Basalt-like Melts

    DEFF Research Database (Denmark)

    Jensen, Martin; Keding, Ralf; Yue, Yuanzheng

    2011-01-01

    The effect of the melting temperature on bubble size and bubble formation in an iron bearing calcium aluminosilicate melt is studied by means of in-depth images acquired by optical microscopy. The bubble size distribution and the total bubble volume are determined by counting the number of bubble...

  4. Bubble Formation in Basalt-like Melts

    DEFF Research Database (Denmark)

    Jensen, Martin; Keding, Ralf; Yue, Yuanzheng

    2011-01-01

    The effect of the melting temperature on bubble size and bubble formation in an iron bearing calcium aluminosilicate melt is studied by means of in-depth images acquired by optical microscopy. The bubble size distribution and the total bubble volume are determined by counting the number of bubbles...

  5. Electrical Capacitance Volume Tomography for the Packed Bed Reactor ISS Flight Experiment

    Science.gov (United States)

    Marashdeh, Qussai; Motil, Brian; Wang, Aining; Liang-Shih, Fan

    2013-01-01

    Fixed packed bed reactors are compact, require minimum power and maintenance to operate, and are highly reliable. These features make this technology a highly desirable unit operation for long duration life support systems in space. NASA is developing an ISS experiment to address this technology with particular focus on water reclamation and air revitalization. Earlier research and development efforts funded by NASA have resulted in two hydrodynamic models which require validation with appropriate instrumentation in an extended microgravity environment. To validate these models, the instantaneous distribution of the gas and liquid phases must be measured.Electrical Capacitance Volume Tomography (ECVT) is a non-invasive imaging technology recently developed for multi-phase flow applications. It is based on distributing flexible capacitance plates on the peripheral of a flow column and collecting real-time measurements of inter-electrode capacitances. Capacitance measurements here are directly related to dielectric constant distribution, a physical property that is also related to material distribution in the imaging domain. Reconstruction algorithms are employed to map volume images of dielectric distribution in the imaging domain, which is in turn related to phase distribution. ECVT is suitable for imaging interacting materials of different dielectric constants, typical in multi-phase flow systems. ECVT is being used extensively for measuring flow variables in various gas-liquid and gas-solid flow systems. Recent application of ECVT include flows in risers and exit regions of circulating fluidized beds, gas-liquid and gas-solid bubble columns, trickle beds, and slurry bubble columns. ECVT is also used to validate flow models and CFD simulations. The technology is uniquely qualified for imaging phase concentrations in packed bed reactors for the ISS flight experiments as it exhibits favorable features of compact size, low profile sensors, high imaging speed, and

  6. Scale translation from shaken to diffused bubble aerated systems for lycopene production by Blakeslea trispora under stimulated conditions.

    Science.gov (United States)

    Mantzouridou, Fani Th; Naziri, Eleni

    2017-03-01

    This study deals with the scale up of Blakeslea trispora culture from the successful surface-aerated shake flasks to dispersed-bubble aerated column reactor for lycopene production in the presence of lycopene cyclase inhibitor 2-methyl imidazole. Controlling the initial volumetric oxygen mass transfer coefficient (kLa) via airflow rate contributes to increasing cell mass and lycopene accumulation. Inhibitor effectiveness seems to decrease in conditions of high cell mass. Optimization of crude soybean oil (CSO), airflow rate, and 2-methyl imidazole was arranged according to central composite statistical design. The optimized levels of factors were 110.5 g/L, 2.3 vvm, and 29.5 mg/L, respectively. At this optimum setting, maximum lycopene yield (256 mg/L) was comparable or even higher to those reported in shake flasks and stirred tank reactor. 2-Methyl imidazole use at levels significantly lower than those reported for other inhibitors in the literature was successful in terms of process selectivity. CSO provides economic benefits to the process through its ability to stimulate lycopene synthesis, as an inexpensive carbon source and oxygen vector at the same time.

  7. Interactions of the Infrared bubble N4 with the surroundings

    CERN Document Server

    Liu, Hong-Li; Wu, Yuefang; Yuan, Jing-Hua; Liu, Tie; Dubner, G; Paron, S; Ortega, M E; Molinari, Sergio; Huang, Maohai; Zavagno, Annie; Samal, Manash R; Huang, Ya-Fang; Zhang, Si-Ju

    2016-01-01

    The physical mechanisms that induce the transformation of a certain mass of gas in new stars are far from being well understood. Infrared bubbles associated with HII regions have been considered to be a good sample to investigate triggered star formation. In this paper we report on the investigation of the dust properties of the infrared bubble N4 around the HII region G11.898+0.747, analyzing its interaction with the surroundings and star formation histories therein, aiming at determining the possibility of star formation triggered by the expansion of the bubble. Using Herschel PACS and SPIRE images with a wide wavelength coverage, we reveal the dust properties over the entire bubble. Meanwhile, we are able to identify six dust clumps surrounding the bubble, with a mean size of 0.50 pc, temperature of about 22 K, mean column density of 1.7 $\\times10^{22}$ cm$^{-2}$, mean volume density of about 4.4 $\\times10^{4}$ cm$^{-3}$, and a mean mass of 320 $M_{\\odot}$. In addition, from PAH emission seen at 8 $\\mu$m, ...

  8. Dynamic behaviors of cavitation bubble for the steady cavitating flow

    Institute of Scientific and Technical Information of China (English)

    Jun CAI; Xiulan HUAI; Xunfeng LI

    2009-01-01

    In this paper, by introducing the flow velocity item into the classical Rayleigh-Plesset dynamic equation, a new equation, which does not involve the time term and can describe the motion of cavitation bubble in the steady cavitating flow, has been obtained. By solving the new motion equation using Runge-Kutta fourth order method with adaptive step size control, the dynamic behaviors of cavitation bubble driven by the varying pressure field downstream of a venturi cavitation reactor are numerically simulated. The effects of liquid temperature (corre-sponding to the saturated vapor pressure of liquid), cavitation number and inlet pressure of venturi on radial mo-tion of bubble and pressure pulse due to the radial motion are analyzed and discussed in detail. Some dynamic behaviors of bubble different from those in previous papers are displayed. In addition, the internal relationship between bubble dynamics and process intensification is also discussed. The simulation results reported in this work reveal the variation laws of cavitation intensity with the flow conditions of liquid, and will lay a foundation for the practical application of hydrodynamic cavitation technology.

  9. Droplets, Bubbles and Ultrasound Interactions.

    Science.gov (United States)

    Shpak, Oleksandr; Verweij, Martin; de Jong, Nico; Versluis, Michel

    2016-01-01

    The interaction of droplets and bubbles with ultrasound has been studied extensively in the last 25 years. Microbubbles are broadly used in diagnostic and therapeutic medical applications, for instance, as ultrasound contrast agents. They have a similar size as red blood cells, and thus are able to circulate within blood vessels. Perfluorocarbon liquid droplets can be a potential new generation of microbubble agents as ultrasound can trigger their conversion into gas bubbles. Prior to activation, they are at least five times smaller in diameter than the resulting bubbles. Together with the violent nature of the phase-transition, the droplets can be used for local drug delivery, embolotherapy, HIFU enhancement and tumor imaging. Here we explain the basics of bubble dynamics, described by the Rayleigh-Plesset equation, bubble resonance frequency, damping and quality factor. We show the elegant calculation of the above characteristics for the case of small amplitude oscillations by linearizing the equations. The effect and importance of a bubble coating and effective surface tension are also discussed. We give the main characteristics of the power spectrum of bubble oscillations. Preceding bubble dynamics, ultrasound propagation is introduced. We explain the speed of sound, nonlinearity and attenuation terms. We examine bubble ultrasound scattering and how it depends on the wave-shape of the incident wave. Finally, we introduce droplet interaction with ultrasound. We elucidate the ultrasound-focusing concept within a droplets sphere, droplet shaking due to media compressibility and droplet phase-conversion dynamics.

  10. Optimization of cavitation venturi tube design for pico and nano bubbles generation

    Institute of Scientific and Technical Information of China (English)

    Xiong Yu; Peng Felicia⇑

    2015-01-01

    Hydrodynamic cavitaion venturi tube technique is used for pico and nano bubble generations in coal column flotation. In order to determine the optimal design of hydrodynamic cavitation venture tube for pico and nano bubble generation, a four-factor three-level Central Composite Design of Experimental was conducted for investigating four important design parameters of cavitation venturi tube governing the median size and the volume of pico and nano bubbles. The test results showed that maximum volume of pico and nano bubbles, 65–75%, and minimum mean pico and nano bubble size, 150–240 nm, were achieved at the medium ratio of the diameter of outlet of the venturi-tube and diam-eter of throat (3–4), medium outlet angle (11–13?), high inlet angle (26–27?) and high ratio of the length of the throat and the diameter of throat (2.3–3). Study the effects of the producing pico and nano bubbles on fine coal flotation was performed in a 5 cm diameter 260 cm height flotation column. The optimal percentage of pico and nano bubbles was about 70%, which produced maximum combustible material recovery of 86%with clean coal ash content of 11.7%.

  11. Nanosecond Discharge in Bubbled Liquid n-Heptane: Effects of Gas Composition and Water Addition

    KAUST Repository

    Hamdan, Ahmad

    2016-08-30

    Recently, an aqueous discharge reactor was developed to facilitate reformation of liquid fuels by in-liquid plasma. To gain a microscopic understanding of the physical elements behind this aqueous reactor, we investigate nanosecond discharges in liquid n-heptane with single and double gaseous bubbles in the gap between electrodes. We introduce discharge probability (DP) to characterize the stochastic nature of the discharges, and we investigate the dependence of DP on the gap distance, applied voltage, gaseous bubble composition, and the water content in n-heptane/distilled-water emulsified mixtures. Propagation of a streamer through the bubbles indicates no discharges in the liquids. DP is controlled by the properties of the gaseous bubble rather than by the composition of the liquid mixture in the gap with a single bubble; meanwhile, DP is determined by the dielectric permittivity of the liquid mixture in the gap with double bubbles, results that are supported by static electric field simulations. We found that a physical mechanism of increasing DP is caused by an interaction between bubbles and an importance of the dielectric permittivity of a liquid mixture on the local enhancement of field intensity. We also discuss detailed physical characteristics, such as plasma lifetime and electron density within the discharge channel, by estimating from measured emissions with a gated-intensified charge-coupled device and by using spectroscopic images, respectively. © 1973-2012 IEEE.

  12. Flotation of high-grade fluorite in a short column under negative bias regime

    OpenAIRE

    2006-01-01

    RESTRITO This paper presents flotation results carried out on fluorite ore using a relatively short column, operated under negative bias regime and without wash water. The term short column is used from a kinetic point of view from which collection zone comes out to be around 8 m tall (the relation height/diameter appears valid for industrial size columns). Negative bias was achieved making tailing flow smaller than feed flow. Hence, part of the water is carried up within bubbles wakes. No...

  13. Dynamic Bubble Behaviour during Microscale Subcooled Boiling

    Institute of Scientific and Technical Information of China (English)

    WANG Hao; PENG Xiao-Feng; David M.Christopher

    2005-01-01

    @@ Bubble cycles, including initiation, growth and departure, are the physical basis of nucleate boiling. The presentinvestigation, however, reveals unusual bubble motions during subcooled nucleate boiling on microwires 25 orl00μm in diameter. Two types of bubble motions, bubble sweeping and bubble return, are observed in theexperiments. Bubble sweeping describes a bubble moving back and forth along the wire, which is motion parallelto the wire. Bubble return is the bubble moving back to the wire after it has detached or leaping above thewire. Theoretical analyses and numerical simulations are conducted to investigate the driving mechanisms forboth bubble sweeping and return. Marangoni flow from warm to cool regions along the bubble interface is foundto produce the shear stresses needed to drive these unusual bubble movements.

  14. Stable tridimensional bubble clusters in multi-bubble sonoluminescence (MBSL).

    Science.gov (United States)

    Rosselló, J M; Dellavale, D; Bonetto, F J

    2015-01-01

    In the present work, stable clusters made of multiple sonoluminescent bubbles are experimentally and theoretically studied. Argon bubbles were acoustically generated and trapped using bi-frequency driving within a cylindrical chamber filled with a sulfuric acid aqueous solution (SA85w/w). The intensity of the acoustic pressure field was strong enough to sustain, during several minutes, a large number of positionally and spatially fixed (without pseudo-orbits) sonoluminescent bubbles over an ellipsoidally-shaped tridimensional array. The dimensions of the ellipsoids were studied as a function of the amplitude of the applied low-frequency acoustic pressure (PAc(LF)) and the static pressure in the fluid (P0). In order to explain the size and shape of the bubble clusters, we performed a series of numerical simulations of the hydrodynamic forces acting over the bubbles. In both cases the observed experimental behavior was in excellent agreement with the numerical results. The simulations revealed that the positionally stable region, mainly determined by the null primary Bjerknes force (F→Bj), is defined as the outer perimeter of an axisymmetric ellipsoidal cluster centered in the acoustic field antinode. The role of the high-frequency component of the pressure field and the influence of the secondary Bjerknes force are discussed. We also investigate the effect of a change in the concentration of dissolved gas on the positional and spatial instabilities through the cluster dimensions. The experimental and numerical results presented in this paper are potentially useful for further understanding and modeling numerous current research topics regarding multi-bubble phenomena, e.g. forces acting on the bubbles in multi-frequency acoustic fields, transient acoustic cavitation, bubble interactions, structure formation processes, atomic and molecular emissions of equal bubbles and nonlinear or unsteady acoustic pressure fields in bubbly media.

  15. WATER BOILER REACTOR

    Science.gov (United States)

    King, L.D.P.

    1960-11-22

    As its name implies, this reactor utilizes an aqueous solution of a fissionable element salt, and is also conventional in that it contains a heat exchanger cooling coil immersed in the fuel. Its novelty lies in the utilization of a cylindrical reactor vessel to provide a critical region having a large and constant interface with a supernatant vapor region, and the use of a hollow sleeve coolant member suspended from the cover assembly in coaxial relation with the reactor vessel. Cool water is circulated inside this hollow coolant member, and a gap between its outer wall and the reactor vessel is used to carry off radiolytic gases for recombination in an external catalyst chamber. The central passage of the coolant member defines a reflux condenser passage into which the externally recombined gases are returned and condensed. The large and constant interface between fuel solution and vapor region prevents the formation of large bubbles and minimizes the amount of fuel salt carried off by water vapor, thus making possible higher flux densities, specific powers and power densities.

  16. Triangular bubble spline surfaces.

    Science.gov (United States)

    Kapl, Mario; Byrtus, Marek; Jüttler, Bert

    2011-11-01

    We present a new method for generating a [Formula: see text]-surface from a triangular network of compatible surface strips. The compatible surface strips are given by a network of polynomial curves with an associated implicitly defined surface, which fulfill certain compatibility conditions. Our construction is based on a new concept, called bubble patches, to represent the single surface patches. The compatible surface strips provide a simple [Formula: see text]-condition between two neighboring bubble patches, which are used to construct surface patches, connected with [Formula: see text]-continuity. For [Formula: see text], we describe the obtained [Formula: see text]-condition in detail. It can be generalized to any [Formula: see text]. The construction of a single surface patch is based on Gordon-Coons interpolation for triangles.Our method is a simple local construction scheme, which works uniformly for vertices of arbitrary valency. The resulting surface is a piecewise rational surface, which interpolates the given network of polynomial curves. Several examples of [Formula: see text], [Formula: see text] and [Formula: see text]-surfaces are presented, which have been generated by using our method. The obtained surfaces are visualized with reflection lines to demonstrate the order of smoothness.

  17. Tuning bubbly structures in microchannels.

    Science.gov (United States)

    Vuong, Sharon M; Anna, Shelley L

    2012-06-01

    Foams have many useful applications that arise from the structure and size distribution of the bubbles within them. Microfluidics allows for the rapid formation of uniform bubbles, where bubble size and volume fraction are functions of the input gas pressure, liquid flow rate, and device geometry. After formation, the microchannel confines the bubbles and determines the resulting foam structure. Bubbly structures can vary from a single row ("dripping"), to multiple rows ("alternating"), to densely packed bubbles ("bamboo" and dry foams). We show that each configuration arises in a distinct region of the operating space defined by bubble volume and volume fraction. We describe the boundaries between these regions using geometric arguments and show that the boundaries are functions of the channel aspect ratio. We compare these geometric arguments with foam structures observed in experiments using flow-focusing, T-junction, and co-flow designs to generate stable nitrogen bubbles in aqueous surfactant solution and stable droplets in oil containing dissolved surfactant. The outcome of this work is a set of design parameters that can be used to achieve desired foam structures as a function of device geometry and experimental control parameters.

  18. Bubble chamber: colour enhanced tracks

    CERN Multimedia

    1998-01-01

    This artistically-enhanced image of real particle tracks was produced in the Big European Bubble Chamber (BEBC). Liquid hydrogen is used to create bubbles along the paths of the particles as a piston expands the medium. A magnetic field is produced in the detector causing the particles to travel in spirals, allowing charge and momentum to be measured.

  19. Explosive micro-bubble actuator

    NARCIS (Netherlands)

    Broek, van den D.M.; Elwenspoek, M.

    2008-01-01

    Explosive evaporation occurs when a liquid is exposed to extremely high heat-fluxes. Within a few microseconds a bubble in the form vapour film is generated, followed by rapid growth due to the pressure impulse and finally the bubbles collapse. This effect, which already has proven its use in curren

  20. Bubble coalescence in breathing DNA

    DEFF Research Database (Denmark)

    Novotný, Tomas; Pedersen, Jonas Nyvold; Ambjörnsson, Tobias;

    2007-01-01

    We investigate the coalescence of two DNA bubbles initially located at weak segments and separated by a more stable barrier region in a designed construct of double-stranded DNA. The characteristic time for bubble coalescence and the corresponding distribution are derived, as well as the distribu...

  1. Column Liquid Chromatography.

    Science.gov (United States)

    Majors, Ronald E.; And Others

    1984-01-01

    Reviews literature covering developments of column liquid chromatography during 1982-83. Areas considered include: books and reviews; general theory; columns; instrumentation; detectors; automation and data handling; multidimensional chromatographic and column switching techniques; liquid-solid chromatography; normal bonded-phase, reversed-phase,…

  2. Growing bubbles rising in line

    Directory of Open Access Journals (Sweden)

    John F. Harper

    2001-01-01

    Full Text Available Over many years the author and others have given theories for bubbles rising in line in a liquid. Theory has usually suggested that the bubbles will tend towards a stable distance apart, but experiments have often showed them pairing off and sometimes coalescing. However, existing theory seems not to deal adequately with the case of bubbles growing as they rise, which they do if the liquid is boiling, or is a supersaturated solution of a gas, or simply because the pressure decreases with height. That omission is now addressed, for spherical bubbles rising at high Reynolds numbers. As the flow is then nearly irrotational, Lagrange's equations can be used with Rayleigh's dissipation function. The theory also works for bubbles shrinking as they rise because they dissolve.

  3. Unsteady State Simulation and Process Design of a Batch Reactive Distillation Column with Multiple Side Reactors for Benzyl Chloride Production%带多台侧反应器的间歇反应精馏生产氯化苄非稳态模拟与过程设计

    Institute of Scientific and Technical Information of China (English)

    孙玉玉; 汤吉海; 陈献; 崔咪芬; 费兆阳; 乔旭

    2015-01-01

    建立了带多台侧反应器的间歇反应精馏过程,采用Aspen Plus模拟软件构建该过程的非稳态模拟方法。以甲苯氯化生产氯化苄为对象,研究了侧反应器台数、侧线采出率和采出位置、氯气分配、反应精馏时间及再沸器蒸发量等设计参数对间歇反应精馏过程的影响规律。模拟结果表明反应能力和分离达到最佳匹配的最优设计参数为:精馏塔塔板数8块、侧反应器2台、氯气分配7:3、从第3块塔板侧线采出、采出率85%、再沸器蒸发量25 kmol⋅h−1。在此结构参数和操作条件下完成50 kmol甲苯氯化所需时间为9 h,甲苯的转化率和氯化苄的选择性均可达到98.0%以上。%A batch distillation column coupled with multiple side reactors was established to produce benzyl chloride through toluene chlorination, and its unsteady state process was simulated using Aspen Plus. The influences of reactor number, extraction ratio, extraction position, chlorine distribution, distillation time and boil-up ratio on the performance of batch reactive distillation were investigated. The simulation results indicate that the best match between reaction and separation can be achieved, and the optimal parameters are as follows: column tray 8, side reactor number 2, chlorine distribution 7:3, 85% of the liquid flow extracted from the 3 rd stage into the 2nd reactor and boil-up ratio 25 kmol⋅h−1. Under the optimum conditions, 50 kmol toluene can be converted to benzyl chloride in 9 h with both conversion and selectivity up to 98.0%.

  4. Assessment of the CO2 fixation capacity of Anabaena sp. ATCC 33047 outdoor cultures in vertical flat-panel reactors.

    Science.gov (United States)

    Clares, Marta E; Moreno, José; Guerrero, Miguel G; García-González, Mercedes

    2014-10-10

    The extent of biological CO2 fixation was evaluated for outdoor cultures of the cyanobacterium Anabaena sp. ATCC 33047. Culture conditions were optimized indoors in bubble-column photochemostats operating in continuous mode, subjected to irradiance cycles mimicking the light regime outdoors. Highest values achieved for CO2 fixation rate and biomass productivity were 1 and 0.6 g L(-1) day(-1), respectively. The comparison among different reactors operating simultaneously - open pond, horizontal tubular reactor and vertical flat-panel - allowed to assess their relative efficiency for the outdoor development of Anabaena cultures. Despite the higher volumetric CO2 fixation capacity (and biomass productivity) exhibited by the tubular photobioreactor, yield of the flat-panel reactor was 50% higher than that of the tubular option on a per area basis, reaching values over 35 g CO2 fixed m(-2) d(-1). The flat-panel reactor actually represents a most suitable system for CO2 capture coupled to the generation of valuable biomass by Anabaena cultures.

  5. Reactor Physics

    Energy Technology Data Exchange (ETDEWEB)

    Ait Abderrahim, A

    2001-04-01

    The Reactor Physics and MYRRHA Department of SCK-CEN offers expertise in various areas of reactor physics, in particular in neutronics calculations, reactor dosimetry, reactor operation, reactor safety and control and non-destructive analysis of reactor fuel. This expertise is applied in the Department's own research projects in the VENUS critical facility, in the BR1 reactor and in the MYRRHA project (this project aims at designing a prototype Accelerator Driven System). Available expertise is also used in programmes external to the Department such as the reactor pressure steel vessel programme, the BR2 reactor dosimetry, and the preparation and interpretation of irradiation experiments by means of neutron and gamma calculations. The activities of the Fuzzy Logic and Intelligent Technologies in Nuclear Science programme cover several domains outside the department. Progress and achievements in these topical areas in 2000 are summarised.

  6. Energy spectra in bubbly turbulence

    CERN Document Server

    Prakash, Vivek N; Ramos, Fabio Ernesto Mancilla; Tagawa, Yoshiyuki; Lohse, Detlef; Sun, Chao

    2013-01-01

    We conduct experiments in a turbulent bubbly flow to study the unknown nature of the transition between the classical -5/3 energy spectrum scaling for a single-phase turbulent flow and the -3 scaling for a swarm of bubbles rising in a quiescent liquid and of bubble-dominated turbulence. The bubblance parameter, b, which measures the ratio of the bubble-induced kinetic energy to the kinetic energy induced by the turbulent liquid fluctuations before bubble injection, is used to characterise the bubbly flow. We vary b from $b = \\infty$ (pseudo-turbulence) to b = 0 (single-phase flow) over 2-3 orders of magnitude: ~O(0.01, 0.1, 5) to study its effect on the turbulent energy spectrum and liquid velocity fluctuations. The experiments are conducted in a multi-phase turbulent water tunnel with air bubbles of diameters 2-4 mm and 3-5 mm. An active-grid is used to generate nearly homogeneous and isotropic turbulence in the liquid flow. The liquid speeds and gas void fractions are varied to achieve the above mentioned b...

  7. Doughnut-shaped soap bubbles

    Science.gov (United States)

    Préve, Deison; Saa, Alberto

    2015-10-01

    Soap bubbles are thin liquid films enclosing a fixed volume of air. Since the surface tension is typically assumed to be the only factor responsible for conforming the soap bubble shape, the realized bubble surfaces are always minimal area ones. Here, we consider the problem of finding the axisymmetric minimal area surface enclosing a fixed volume V and with a fixed equatorial perimeter L . It is well known that the sphere is the solution for V =L3/6 π2 , and this is indeed the case of a free soap bubble, for instance. Surprisingly, we show that for V <α L3/6 π2 , with α ≈0.21 , such a surface cannot be the usual lens-shaped surface formed by the juxtaposition of two spherical caps, but is rather a toroidal surface. Practically, a doughnut-shaped bubble is known to be ultimately unstable and, hence, it will eventually lose its axisymmetry by breaking apart in smaller bubbles. Indisputably, however, the topological transition from spherical to toroidal surfaces is mandatory here for obtaining the global solution for this axisymmetric isoperimetric problem. Our result suggests that deformed bubbles with V <α L3/6 π2 cannot be stable and should not exist in foams, for instance.

  8. Dynamic morphology of gas hydrate on a methane bubble in water: Observations and new insights for hydrate film models

    Science.gov (United States)

    Warzinski, Robert P.; Lynn, Ronald; Haljasmaa, Igor; Leifer, Ira; Shaffer, Frank; Anderson, Brian J.; Levine, Jonathan S.

    2014-10-01

    Predicting the fate of subsea hydrocarbon gases escaping into seawater is complicated by potential formation of hydrate on rising bubbles that can enhance their survival in the water column, allowing gas to reach shallower depths and the atmosphere. The precise nature and influence of hydrate coatings on bubble hydrodynamics and dissolution is largely unknown. Here we present high-definition, experimental observations of complex surficial mechanisms governing methane bubble hydrate formation and dissociation during transit of a simulated oceanic water column that reveal a temporal progression of deep-sea controlling mechanisms. Synergistic feedbacks between bubble hydrodynamics, hydrate morphology, and coverage characteristics were discovered. Morphological changes on the bubble surface appear analogous to macroscale, sea ice processes, presenting new mechanistic insights. An inverse linear relationship between hydrate coverage and bubble dissolution rate is indicated. Understanding and incorporating these phenomena into bubble and bubble plume models will be necessary to accurately predict global greenhouse gas budgets for warming ocean scenarios and hydrocarbon transport from anthropogenic or natural deep-sea eruptions.

  9. Hydrodynamic Behavior of Three-Phase Airlift Loop Slurry Reactor

    Institute of Scientific and Technical Information of China (English)

    任飞; 王金福; 王铁峰; 金涌

    2002-01-01

    A novel fiber optic probe system and a set of commercial ultrasonic Doppler velocimeters have been used to study the hydrodynamic behavior of a three-phase airlift loop (TPAL) slurry reactor. Experiments have been carried out in a loop reactor with 100 mm inner diameter and 2.5 m height, in which air, tap water and silica gel particles are used as the gas, liquid and solid phase, respectively. The radial profile of gas holdup, bubble size, bubble rising velocity, liquid circulating velocity, and the influence of the main operating conditions such as superficial gas velocity and solids concentration have been studied experimentally in the TPAL slurry reactor. The experimental results show that the bubble characteristics are different in various flow regimes and the radial profiles of some hydrodynamic parameters in the TPAL slurry reactor are more uniform than those in traditional three-phase reactors. The distribution of the bubble size and bubble rising velocity can be described by a lognormal function. The influence of superficial gas velocity on the hydrodynamic parameters is more remarkable than that of the solids concentration.

  10. Reactor safeguards

    CERN Document Server

    Russell, Charles R

    1962-01-01

    Reactor Safeguards provides information for all who are interested in the subject of reactor safeguards. Much of the material is descriptive although some sections are written for the engineer or physicist directly concerned with hazards analysis or site selection problems. The book opens with an introductory chapter on radiation hazards, the construction of nuclear reactors, safety issues, and the operation of nuclear reactors. This is followed by separate chapters that discuss radioactive materials, reactor kinetics, control and safety systems, containment, safety features for water reactor

  11. Reactor operation

    CERN Document Server

    Shaw, J

    2013-01-01

    Reactor Operation covers the theoretical aspects and design information of nuclear reactors. This book is composed of nine chapters that also consider their control, calibration, and experimentation.The opening chapters present the general problems of reactor operation and the principles of reactor control and operation. The succeeding chapters deal with the instrumentation, start-up, pre-commissioning, and physical experiments of nuclear reactors. The remaining chapters are devoted to the control rod calibrations and temperature coefficient measurements in the reactor. These chapters also exp

  12. Bubble video experiments in the marine waters off Panarea Island (Italy): real-world data for modelling CO2 bubble dissolution and evolution

    Science.gov (United States)

    Beaubien, Stan; De Vittor, Cinzia; McGinnis, Dan; Bigi, Sabina; Comici, Cinzia; Ingrosso, Gianmarco; Lombardi, Salvatore; Ruggiero, Livio

    2014-05-01

    Carbon capture and storage is expected to provide an important, short-term contribution to mitigate global climate change due to anthropogenic emissions of CO2. Offshore reservoirs are particularly favourable, however concerns exist regarding the potential for CO2 leakage into the water column (with possible ecosystem impacts) and the atmosphere. Although laboratory experiments and modelling can examine these issues, the study of natural systems can provide a more complete and realistic understanding. For this reason the natural CO2 emission site off the coast of Panarea Island (Italy) was chosen for study within the EC-funded ECO2 project. The present paper discusses the results of field experiments conducted at this site to better understand the fate of CO2 gas bubbles as they rise through the water column, and to use this real-world data as input to test the predictive capabilities of a bubble model. Experiments were conducted using a 1m wide x 1m deep x 3m tall, hollow-tube structure equipped with a vertical guide on the front face and a dark, graduated cloth for contrast and depth reference on the back. A Plexiglas box was filled with the naturally emitted gas and fixed on the seafloor inside the structure. Tubes exit the top of the box to make bubbles of different diameters, while valves on each tube control bubble release rate. Bubble rise velocity was measured by tracking each bubble with a HD video camera mounted in the guide and calculating values over 20 cm intervals. Bubble diameter was measured by filming the bubbles as they collide with a graduated Plexiglas sheet deployed horizontally at the measurement height. Bubble gas was collected at different heights using a funnel and analysed in the laboratory for CO2, O2+Ar, N2, and CH4. Water parameters were measured by performing a CTD cast beside the structure and collecting water samples at four depths using a Niskin bottle; samples were analysed in the laboratory for all carbonate system species, DO

  13. Partial coalescence of soap bubbles

    Science.gov (United States)

    Harris, Daniel M.; Pucci, Giuseppe; Bush, John W. M.

    2015-11-01

    We present the results of an experimental investigation of the merger of a soap bubble with a planar soap film. When gently deposited onto a horizontal film, a bubble may interact with the underlying film in such a way as to decrease in size, leaving behind a smaller daughter bubble with approximately half the radius of its progenitor. The process repeats up to three times, with each partial coalescence event occurring over a time scale comparable to the inertial-capillary time. Our results are compared to the recent numerical simulations of Martin and Blanchette and to the coalescence cascade of droplets on a fluid bath.

  14. Bubble Growth in Lunar Basalts

    Science.gov (United States)

    Zhang, Y.

    2009-05-01

    Although Moon is usually said to be volatile-"free", lunar basalts are often vesicular with mm-size bubbles. The vesicular nature of the lunar basalts suggests that they contained some initial gas concentration. A recent publication estimated volatile concentrations in lunar basalts (Saal et al. 2008). This report investigates bubble growth on Moon and compares with that on Earth. Under conditions relevant to lunar basalts, bubble growth in a finite melt shell (i.e., growth of multiple regularly-spaced bubbles) is calculated following Proussevitch and Sahagian (1998) and Liu and Zhang (2000). Initial H2O content of 700 ppm (Saal et al. 2008) or lower is used and the effect of other volatiles (such as carbon dioxide, halogens, and sulfur) is ignored. H2O solubility at low pressures (Liu et al. 2005), concentration-dependent diffusivity in basalt (Zhang and Stolper 1991), and lunar basalt viscosity (Murase and McBirney 1970) are used. Because lunar atmospheric pressure is essentially zero, the confining pressure on bubbles is completely supplied by the overlying magma. Due to low H2O content in lunar basaltic melt (700 ppm H2O corresponds to a saturation pressure of 75 kPa), H2O bubbles only grow in the upper 16 m of a basalt flow or lake. A depth of 20 mm corresponds to a confining pressure of 100 Pa. Hence, vesicular lunar rocks come from very shallow depth. Some findings from the modeling are as follows. (a) Due to low confining pressure as well as low viscosity, even though volatile concentration is very low, bubble growth rate is extremely high, much higher than typical bubble growth rates in terrestrial melts. Hence, mm-size bubbles in lunar basalts are not strange. (b) Because the pertinent pressures are so low, bubble pressure due to surface tension plays a main role in lunar bubble growth, contrary to terrestrial cases. (c) Time scale to reach equilibrium bubble size increases as the confining pressure increases. References: (1) Liu Y, Zhang YX (2000) Earth

  15. Sonochemistry and the acoustic bubble

    CERN Document Server

    Grieser, Franz; Enomoto, Naoya; Harada, Hisashi; Okitsu, Kenji; Yasui, Kyuichi

    2015-01-01

    Sonochemistry and the Acoustic Bubble provides an introduction to the way ultrasound acts on bubbles in a liquid to cause bubbles to collapse violently, leading to localized 'hot spots' in the liquid with temperatures of 5000° celcius and under pressures of several hundred atmospheres. These extreme conditions produce events such as the emission of light, sonoluminescence, with a lifetime of less than a nanosecond, and free radicals that can initiate a host of varied chemical reactions (sonochemistry) in the liquid, all at room temperature. The physics and chemistry behind the p

  16. Thermal Phase in Bubbling Geometries

    Institute of Scientific and Technical Information of China (English)

    LIU Chang-Yong

    2008-01-01

    We use matrix model to study thermal phase in bubbling half-BPS type IIB geometries with SO(4)×SO(4) symmetry.Near the horizon limit,we find that thermal vacua of bubbling geometries have disjoint parts,and each part is one kind of phase of the thermal system.We connect the thermal dynamics of bubbling geometries with one-dimensional fermions thermal system.Finally,we try to give a new possible way to resolve information loss puzzle.

  17. Reducing axial mixing in flotation columns

    Energy Technology Data Exchange (ETDEWEB)

    Al Taweel, A.M.; Ramadan, A.M. [Technical Univ. of Nova Scotia, Halifax (Canada). Chemical Engineering Dept.; Moharam, M.R.; Hassan, T.A. [Al Azhar Univ., Cairo (Egypt); El Mofty, S.M. [Cairo Univ., Giza (Egypt)

    1995-10-01

    The axial mixing characteristics of a pilot-scale flotation column were investigated with the objective of identifying means to mitigate the extent of axial mixing that adversely affects its grade/recovery performance. A wide range of design and operating conditions wa investigated and the experimental results, obtained using the dynamic response method, were analyzed using three axial mixing models. The dynamic response of the column can best be described using the axial dispersion model. The results obtained suggest that the value of the axial dispersion coefficient, E{sub L}, can be significantly reduced by judicial selection of hydrodynamic conditions and/or the use of column inserts that suppress the onset of hydrodynamic instabilities inherent to the operation of conventional flotation columns. Up to 40% reduction in the value of E{sub L} was thus obtained by using spargers that produce more uniform bubble sizes, while up to 30% reductions were obtained by controlling the residual frother concentration. 33 refs., 7 figs.

  18. Bubble stimulation efficiency of dinoflagellate bioluminescence.

    Science.gov (United States)

    Deane, Grant B; Stokes, M Dale; Latz, Michael I

    2016-02-01

    Dinoflagellate bioluminescence, a common source of bioluminescence in coastal waters, is stimulated by flow agitation. Although bubbles are anecdotally known to be stimulatory, the process has never been experimentally investigated. This study quantified the flash response of the bioluminescent dinoflagellate Lingulodinium polyedrum to stimulation by bubbles rising through still seawater. Cells were stimulated by isolated bubbles of 0.3-3 mm radii rising at their terminal velocity, and also by bubble clouds containing bubbles of 0.06-10 mm radii for different air flow rates. Stimulation efficiency, the proportion of cells producing a flash within the volume of water swept out by a rising bubble, decreased with decreasing bubble radius for radii less than approximately 1 mm. Bubbles smaller than a critical radius in the range 0.275-0.325 mm did not stimulate a flash response. The fraction of cells stimulated by bubble clouds was proportional to the volume of air in the bubble cloud, with lower stimulation levels observed for clouds with smaller bubbles. An empirical model for bubble cloud stimulation based on the isolated bubble observations successfully reproduced the observed stimulation by bubble clouds for low air flow rates. High air flow rates stimulated more light emission than expected, presumably because of additional fluid shear stress associated with collective buoyancy effects generated by the high air fraction bubble cloud. These results are relevant to bioluminescence stimulation by bubbles in two-phase flows, such as in ship wakes, breaking waves, and sparged bioreactors.

  19. Bubble Dynamics and Resulting Noise from Traveling Bubble Cavitation.

    Science.gov (United States)

    1982-04-13

    has resulted in models which aqree well with bubble dynamics recorded by high speed film . Chahine, et. al. (23) incorporated asymmetric bubble...recording on the tape soundtrack . 3.8 Measurement of Gas Nuclei in Water The role of nuclei density and size in cavitation inception has been the subject...interference between the coherent background and the particle-diffracted radiation exooses photographic film in the far-field of the nuclei. This

  20. Towards advanced aeration modelling: from blower to bubbles to bulk.

    Science.gov (United States)

    Amaral, Andreia; Schraa, Oliver; Rieger, Leiv; Gillot, Sylvie; Fayolle, Yannick; Bellandi, Giacomo; Amerlinck, Youri; Mortier, Séverine T F C; Gori, Riccardo; Neves, Ramiro; Nopens, Ingmar

    2017-02-01

    Aeration is an essential component of aerobic biological wastewater treatment and is the largest energy consumer at most water resource recovery facilities. Most modelling studies neglect the inherent complexity of the aeration systems used. Typically, the blowers, air piping, and diffusers are not modelled in detail, completely mixed reactors in a series are used to represent plug-flow reactors, and empirical correlations are used to describe the impact of operating conditions on bubble formation and transport, and oxygen transfer from the bubbles to the bulk liquid. However, the mechanisms involved are very complex in nature and require significant research efforts. This contribution highlights why and where there is a need for more detail in the different aspects of the aeration system and compiles recent efforts to develop physical models of the entire aeration system (blower, valves, air piping and diffusers), as well as adding rigour to the oxygen transfer efficiency modelling (impact of viscosity, bubble size distribution, shear and hydrodynamics). As a result of these model extensions, more realistic predictions of dissolved oxygen profiles and energy consumption have been achieved. Finally, the current needs for further model development are highlighted.

  1. Spiral multicapillary columns

    Science.gov (United States)

    Efimenko, A. P.; Naumenko, I. I.; Soboleva, V. K.

    2008-08-01

    It was shown in a theoretical study and confirmed by experiment that a spiral multicapillary column had maximum efficiency if the bunch of capillaries was additionally coiled around its longitudinal axis to produce an integral number of coils. This technique made it possible to manufacture gas-chromatographic columns with performance as high as 12 to 16 thousand theoretical plates. These columns can find various applications, especially if quick separation is required.

  2. A Summary of Shock/Soap Bubble Interactions Performed at the SWRC, Tohoku University

    Science.gov (United States)

    Yamamoto, H.; Igra, D.; Takayama, Kazuyoshi

    A summary of experiments of shock wave interactions with spherical soap bubbles and cylindrical soap columns filled with helium performed in the Shock Wave Research Center at Tohoku University is presented. Sequential holographic interferograms of soap bubbles impinged by small-scale blast waves created by explosion of 10 mg weight silver azide pellets are presented. The standoff distance between micro-explosives and the bubbles center is about 40 mm and the shock overpressure was about 2 MPa. Helium filled soap columns of 40 mm diameter and 60 mm in height were placed in a 60 mm x 150 mm shock tube. Their interaction with shock wave was intensively visualized by using holographic interferogram at atmospheric conditions. It is found that the irregular interfacial deformation observed are just three-dimensional vortices viewed from the side

  3. Reactor Neutrinos

    OpenAIRE

    Soo-Bong Kim; Thierry Lasserre; Yifang Wang

    2013-01-01

    We review the status and the results of reactor neutrino experiments. Short-baseline experiments have provided the measurement of the reactor neutrino spectrum, and their interest has been recently revived by the discovery of the reactor antineutrino anomaly, a discrepancy between the reactor neutrino flux state of the art prediction and the measurements at baselines shorter than one kilometer. Middle and long-baseline oscillation experiments at Daya Bay, Double Chooz, and RENO provided very ...

  4. The Housing Bubble Fact Sheet

    OpenAIRE

    Dean Baker

    2005-01-01

    This paper explains the basic facts about the current housing market. It lays out the evidence that the rise in housing prices constitutes a housing bubble - and explains what can be expected when it inevitably collapses.

  5. Bubble bean bags in shampoo

    CERN Document Server

    Kundu, Anup; Das, Gargi; Harikrishnan, G

    2011-01-01

    In these fluid dynamics videos, we, for the first time, show various interactions of a 'Taylor bubble' with their smaller and differently, shaped counterparts, in a shear thinning, non-Newtonian fluid, confined in a narrow channel.

  6. Mechanisms of single bubble cleaning.

    Science.gov (United States)

    Reuter, Fabian; Mettin, Robert

    2016-03-01

    The dynamics of collapsing bubbles close to a flat solid is investigated with respect to its potential for removal of surface attached particles. Individual bubbles are created by nanosecond Nd:YAG laser pulses focused into water close to glass plates contaminated with melamine resin micro-particles. The bubble dynamics is analysed by means of synchronous high-speed recordings. Due to the close solid boundary, the bubble collapses with the well-known liquid jet phenomenon. Subsequent microscopic inspection of the substrates reveals circular areas clean of particles after a single bubble generation and collapse event. The detailed bubble dynamics, as well as the cleaned area size, is characterised by the non-dimensional bubble stand-off γ=d/Rmax, with d: laser focus distance to the solid boundary, and Rmax: maximum bubble radius before collapse. We observe a maximum of clean area at γ≈0.7, a roughly linear decay of the cleaned circle radius for increasing γ, and no cleaning for γ>3.5. As the main mechanism for particle removal, rapid flows at the boundary are identified. Three different cleaning regimes are discussed in relation to γ: (I) For large stand-off, 1.8substrate and remove particles without significant contact of the gas phase. (II) For small distances, γsubstrate are driven by the jet impact with its subsequent radial spreading, and by the liquid following the motion of the collapsing and rebounding bubble wall. Both flows remove particles. Their relative timing, which depends sensitively on the exact γ, appears to determine the extension of the area with forces large enough to cause particle detachment. (III) At intermediate stand-off, 1.1substrate, but acts with cleaning mechanisms similar to an effective small γ collapse: particles are removed by the jet flow and the flow induced by the bubble wall oscillation. Furthermore, the observations reveal that the extent of direct bubble gas phase contact to the solid is partially smaller than the

  7. A study of gas bubbles in liquid mercury in a vertical Hele-Shaw cell

    Science.gov (United States)

    Klaasen, B.; Verhaeghe, F.; Blanpain, B.; Fransaer, J.

    2014-01-01

    High-quality observations of mesoscopic gas bubbles in liquid metal are vital for a further development of pyrometallurgical gas injection reactors. However, the opacity of metals enforces the use of indirect imaging techniques with limited temporal or spatial resolution. In addition, accurate interface tracking requires tomography which further complicates the design of a high-temperature experimental setup. In this paper, an alternative approach is suggested that circumvents these two main restrictions. By injecting gas in a thin layer of liquid metal entrapped between two flat and closely spaced plates, bubbles in a Hele-Shaw flow regime are generated. The resulting quasi-2D multiphase flow phenomena can be fully captured from a single point of view and, when using a non-wetted transparent plate material, the bubbles can be observed directly. The feasibility of this approach is demonstrated by observations on buoyancy-driven nitrogen bubbles in liquid mercury in a vertical Hele-Shaw cell. By using a moving high-speed camera to make continuous close up recordings of individual bubbles, the position and geometry of these bubbles are quantified with a high resolution along their entire path. After a thorough evaluation of the experimental accuracy, this information is used for a detailed analysis of the bubble expansion along the path. While the observed bubble growth is mainly caused by the hydrostatic pressure gradient, a careful assessment of the volume variations for smaller bubbles shows that an accurate bubble description should account for significant dynamic pressure variations that seem to be largely regime dependent.

  8. Bubble-Facilitated VOC Transport from LNAPL Smear Zones and Its Potential Effect on Vapor Intrusion.

    Science.gov (United States)

    Soucy, Nicole C; Mumford, Kevin G

    2017-02-10

    Most conceptual and mathematical models of soil vapor intrusion assume that the transport of volatile organic compounds (VOCs) from a source toward a building is limited by diffusion through the soil gas. Under conditions where advection occurs, transport rates are higher and can lead to higher indoor air concentrations. Advection-dominated conditions can be created by gas bubble flow in the saturated zone. A series of laboratory column experiments were conducted to measure mass flux due to bubble-facilitated VOC transport from light nonaqueous phase liquid (LNAPL) smear zones. Smear zones that contained both LNAPL residual and trapped gas, as well as those that contained only LNAPL residual, were investigated. Results showed that the VOC mass flux due to bubble-facilitated transport was orders-of-magnitude higher than under diffusion-limited conditions. Results also showed that the mass flux due to bubble-facilitated transport was intermittent, and increased with an increased supply of dissolved gases.

  9. Dual-beam irradiation of {alpha}-iron: Heterogeneous bubble formation on dislocation loops

    Energy Technology Data Exchange (ETDEWEB)

    Brimbal, Daniel, E-mail: Daniel.brimbal@cea.fr [Laboratoire d' Analyse Microstructurale des Materiaux (LA2M), CEA/Saclay, DEN/DMN/SRMA/LA2M, 91191 Gif-sur-Yvette Cedex (France); Decamps, Brigitte, E-mail: Brigitte.decamps@csnsm.in2p3.fr [Centre de Spectrometrie Nucleaire et de Spectrometrie de Masses (CSNSM/IN2P3/CNRS), Orsay University, Bat. 108, 91405 Orsay Campus (France); Barbu, Alain, E-mail: Alain.barbu@cea.fr [Service de Recherches de Metallurgie Physique (SRMP), CEA/Saclay, DEN/DMN/SRMP, 91191 Gif-sur-Yvette Cedex (France); Meslin, Estelle, E-mail: Estelle.Meslin@cea.fr [Service de Recherches de Metallurgie Physique (SRMP), CEA/Saclay, DEN/DMN/SRMP, 91191 Gif-sur-Yvette Cedex (France); Henry, Jean, E-mail: Jean.henry@cea.fr [Laboratoire d' Analyse Microstructurale des Materiaux (LA2M), CEA/Saclay, DEN/DMN/SRMA/LA2M, 91191 Gif-sur-Yvette Cedex (France)

    2011-11-15

    Highlights: > We have irradiated {alpha}-iron in situ with Fe{sup +} and He{sup +} ions at 500 deg. C. > Dislocation loops and helium bubbles are present at 1 dpa/540 appm He. > The helium bubbles are located heterogeneously on the dislocation loops. - Abstract: In order to understand the evolution of materials under irradiation conditions similar to those in future fusion reactors, we have irradiated high purity iron in situ in a transmission electron microscope with 1 MeV Fe{sup +} ions while simultaneously implanting 15 keV He{sup +} ions, at 500 deg. C. Once {approx}1 dpa/500 appm He were reached, helium bubbles and large dislocation loops were observed. The study reveals that helium bubbles nucleated heterogeneously: a majority of them were observed inside the large dislocation loops.

  10. Doughnut-shaped soap bubbles

    CERN Document Server

    Preve, Deison

    2015-01-01

    Soap bubbles are thin liquid films enclosing a fixed volume of air. Since the surface tension is typically assumed to be the only responsible for conforming the soap bubble shape, the realized bubble surfaces are always minimal area ones. Here, we consider the problem of finding the axisymmetric minimal area surface enclosing a fixed volume $V$ and with a fixed equatorial perimeter $L$. It is well known that the sphere is the solution for $V=L^3/6\\pi^2$, and this is indeed the case of a free soap bubble, for instance. Surprisingly, we show that for $V<\\alpha L^3/6\\pi^2$, with $\\alpha\\approx 0.21$, such a surface cannot be the usual lens-shaped surface formed by the juxtaposition of two spherical caps, but rather a toroidal surface. Practically, a doughnut-shaped bubble is known to be ultimately unstable and, hence, it will eventually lose its axisymmetry by breaking apart in smaller bubbles. Indisputably, however, the topological transition from spherical to toroidal surfaces is mandatory here for obtainin...

  11. Measuring online social bubbles

    Directory of Open Access Journals (Sweden)

    Dimitar Nikolov

    2015-12-01

    Full Text Available Social media have become a prevalent channel to access information, spread ideas, and influence opinions. However, it has been suggested that social and algorithmic filtering may cause exposure to less diverse points of view. Here we quantitatively measure this kind of social bias at the collective level by mining a massive datasets of web clicks. Our analysis shows that collectively, people access information from a significantly narrower spectrum of sources through social media and email, compared to a search baseline. The significance of this finding for individual exposure is revealed by investigating the relationship between the diversity of information sources experienced by users at both the collective and individual levels in two datasets where individual users can be analyzed—Twitter posts and search logs. There is a strong correlation between collective and individual diversity, supporting the notion that when we use social media we find ourselves inside “social bubbles.” Our results could lead to a deeper understanding of how technology biases our exposure to new information.

  12. Modeling the impediment of methane ebullition bubbles by seasonal lake ice

    Directory of Open Access Journals (Sweden)

    S. Greene

    2014-07-01

    Full Text Available Microbial methane (CH4 ebullition (bubbling from anoxic lake sediments comprises a globally significant flux to the atmosphere, but ebullition bubbles in temperate and polar lakes can be trapped by winter ice cover and later released during spring thaw. This "ice-bubble storage" (IBS constitutes a novel mode of CH4 emission. Before bubbles are encapsulated by downward-growing ice, some of their CH4 dissolves into the lake water, where it may be subject to oxidation. We present field characterization and a model of the annual CH4 cycle in Goldstream Lake, a thermokarst (thaw lake in interior Alaska. We find that summertime ebullition dominates annual CH4 emissions to the atmosphere. Eighty percent of CH4 in bubbles trapped by ice dissolves into the lake water column in winter, and about half of that is oxidized. The ice growth rate and the magnitude of the CH4 ebullition flux are important controlling factors of bubble dissolution. Seven percent of annual ebullition CH4 is trapped as IBS and later emitted as ice melts. In a future warmer climate, there will likely be less seasonal ice cover, less IBS, less CH4 dissolution from trapped bubbles, and greater CH4 emissions from northern lakes.

  13. Measuring and modeling the bubble population produced by an underwater explosion.

    Science.gov (United States)

    Holt, Fred D; Lee Culver, R

    2011-11-01

    Underwater explosions have been studied intensively in the United States since 1941 [e.g., R. H. Cole, Underwater Explosions (Princeton University Press, Princeton, NJ, 1945), pp. 3-13]. Research to date has primarily focused on the initial shock and subsequent pressure waves caused by the oscillations of the "gas-globe" resulting from charge detonation. These phenomena have relatively short timescales (typically less than 2 s). However, after the gas-globe rises through the water column and breaks the surface, there remains behind a cloud of bubbles and perhaps debris from the explosion container which has been markedly less studied. A recent experiment measured the spatial and temporal acoustic response of the bubble cloud resulting from a 13.6 kg PBXN-111 charge detonated at 15.2 m (50 ft) depth. A directional projector was used to propagate linear frequency-modulated (5-65 kHz) and 40 kHz tonal pulses through the bubble cloud. Two hydrophone arrays were positioned so as to measure the energy lost in propagating through the bubble cloud. Three methods have been utilized to invert measurements and estimate the bubble population. The bubble population estimates have been used to develop a model for the bubble population resulting from an underwater explosion.

  14. Rise of an argon bubble in liquid steel in the presence of a transverse magnetic field

    Science.gov (United States)

    Jin, K.; Kumar, P.; Vanka, S. P.; Thomas, B. G.

    2016-09-01

    The rise of gaseous bubbles in viscous liquids is a fundamental problem in fluid physics, and it is also a common phenomenon in many industrial applications such as materials processing, food processing, and fusion reactor cooling. In this work, the motion of a single argon gas bubble rising in quiescent liquid steel under an external magnetic field is studied numerically using a Volume-of-Fluid method. To mitigate spurious velocities normally generated during numerical simulation of multiphase flows with large density differences, an improved algorithm for surface tension modeling, originally proposed by Wang and Tong ["Deformation and oscillations of a single gas bubble rising in a narrow vertical tube," Int. J. Therm. Sci. 47, 221-228 (2008)] is implemented, validated and used in the present computations. The governing equations are integrated by a second-order space and time accurate numerical scheme, and implemented on multiple Graphics Processing Units with high parallel efficiency. The motion and terminal velocities of the rising bubble under different magnetic fields are compared and a reduction in rise velocity is seen in cases with the magnetic field applied. The shape deformation and the path of the bubble are discussed. An elongation of the bubble along the field direction is seen, and the physics behind these phenomena is discussed. The wake structures behind the bubble are visualized and effects of the magnetic field on the wake structures are presented. A modified drag coefficient is obtained to include the additional resistance force caused by adding a transverse magnetic field.

  15. Estimation of the lifetime of small helium bubbles near tungsten surfaces -- a methodological study

    CERN Document Server

    Cui, Jiechao; Hou, Qing

    2016-01-01

    Under low energy and high flux/fluence irradiation of helium (He) atoms, the formation and bursting of He bubbles on tungsten (W) surfaces play important roles in the morphological evolution of component surfaces and impurity production in fusion reactors. Microscopically, the bursting of He bubbles is a stochastic process, and He bubbles have statistically average lifetimes. In the present paper, a molecular dynamics-based method was developed to extract, for the first time, the lifetime of He bubbles near tungsten surfaces. It was found that He bubble bursting can be treated as an activated event. Its occurrence frequency or, equivalently, the average lifetime of bubbles follows the Arrhenius equation. For a given bubble size, the activation energy exhibits a good linear dependence with the depth, and the pre-exponential factor obeys the Meyer-Nedle rule. These results are useful for establishing a model in multi-scale simulations of impurity production in the fusion plasma and of the morphological evolutio...

  16. The effects of surfactants on the lateral migration of bubbles and the bubble clustering phenomenon in a bubbly channel flow

    Science.gov (United States)

    Takagi, Shu; Ogasawara, Toshiyuki; Matsumoto, Yoichiro

    2004-11-01

    The behaviors of bubbles in an upward channel flow are experimentally investigated. Two kinds of surfactant, 3-pentanol and Triton X-100 are added in the bubbly flow. Addition of surfactant prevents the bubble coalescence and mono-dispersed 1mm spherical bubbles were obtained, although these surfactants do not modify the single-phase turbulence statistics. At the condition of high Reynolds number (Re=8200) with 20-60ppm 3-Pentanol, bubbles migrated towards the wall. These bubbles highly accumulated near the wall and formed crescent like shaped horizontal bubble clusters of 10-40mm length. On the other hand, bubble clusters did not appear in the 2ppm Triton-X100 aqueous solution. By the addition of the small amount of Triton-X100, bubble coalescences were also preventable and the bubble size and its distribution became almost the same as in the case of 60ppm 3-Pentanol aqueous solution. However, the tendency of the lateral migration of bubbles towards the wall weakened and the bubbles did not accumulated near the wall. And this is the main reason of the disapperance of bubble cluster. We discuss this phenomenon, related to the lift force acting on bubbles and particles.

  17. A gold-immobilized microchannel flow reactor for oxidation of alcohols with molecular oxygen.

    Science.gov (United States)

    Wang, Naiwei; Matsumoto, Tsutomu; Ueno, Masaharu; Miyamura, Hiroyuki; Kobayashi, Shū

    2009-01-01

    Golden capillaries: A gold-immobilized capillary column reactor allows oxidation of alcohols to carbonyl compounds using molecular oxygen. These capillary columns (see picture) can be used for at least four days without loss of activity.

  18. FEASTING BLACK HOLE BLOWS BUBBLES

    Science.gov (United States)

    2002-01-01

    A monstrous black hole's rude table manners include blowing huge bubbles of hot gas into space. At least, that's the gustatory practice followed by the supermassive black hole residing in the hub of the nearby galaxy NGC 4438. Known as a peculiar galaxy because of its unusual shape, NGC 4438 is in the Virgo Cluster, 50 million light-years from Earth. These NASA Hubble Space Telescope images of the galaxy's central region clearly show one of the bubbles rising from a dark band of dust. The other bubble, emanating from below the dust band, is barely visible, appearing as dim red blobs in the close-up picture of the galaxy's hub (the colorful picture at right). The background image represents a wider view of the galaxy, with the central region defined by the white box. These extremely hot bubbles are caused by the black hole's voracious eating habits. The eating machine is engorging itself with a banquet of material swirling around it in an accretion disk (the white region below the bright bubble). Some of this material is spewed from the disk in opposite directions. Acting like high-powered garden hoses, these twin jets of matter sweep out material in their paths. The jets eventually slam into a wall of dense, slow-moving gas, which is traveling at less than 223,000 mph (360,000 kph). The collision produces the glowing material. The bubbles will continue to expand and will eventually dissipate. Compared with the life of the galaxy, this bubble-blowing phase is a short-lived event. The bubble is much brighter on one side of the galaxy's center because the jet smashed into a denser amount of gas. The brighter bubble is 800 light-years tall and 800 light-years across. The observations are being presented June 5 at the American Astronomical Society meeting in Rochester, N.Y. Both pictures were taken March 24, 1999 with the Wide Field and Planetary Camera 2. False colors were used to enhance the details of the bubbles. The red regions in the picture denote the hot gas

  19. JCE Feature Columns

    Science.gov (United States)

    Holmes, Jon L.

    1999-05-01

    The Features area of JCE Online is now readily accessible through a single click from our home page. In the Features area each column is linked to its own home page. These column home pages also have links to them from the online Journal Table of Contents pages or from any article published as part of that feature column. Using these links you can easily find abstracts of additional articles that are related by topic. Of course, JCE Online+ subscribers are then just one click away from the entire article. Finding related articles is easy because each feature column "site" contains links to the online abstracts of all the articles that have appeared in the column. In addition, you can find the mission statement for the column and the email link to the column editor that I mentioned above. At the discretion of its editor, a feature column site may contain additional resources. As an example, the Chemical Information Instructor column edited by Arleen Somerville will have a periodically updated bibliography of resources for teaching and using chemical information. Due to the increase in the number of these resources available on the WWW, it only makes sense to publish this information online so that you can get to these resources with a simple click of the mouse. We expect that there will soon be additional information and resources at several other feature column sites. Following in the footsteps of the Chemical Information Instructor, up-to-date bibliographies and links to related online resources can be made available. We hope to extend the online component of our feature columns with moderated online discussion forums. If you have a suggestion for an online resource you would like to see included, let the feature editor or JCE Online (jceonline@chem.wisc.edu) know about it. JCE Internet Features JCE Internet also has several feature columns: Chemical Education Resource Shelf, Conceptual Questions and Challenge Problems, Equipment Buyers Guide, Hal's Picks, Mathcad

  20. Hydrodynamics in a swarm of rising bubbles; Hydrodynamique d'un essaim de bulles en ascension

    Energy Technology Data Exchange (ETDEWEB)

    Riboux, G

    2007-04-15

    In many applications, bubbles are used to agitate a liquid in order to enhance mixing and transfer. This work is devoted to the study of the hydrodynamics in a stable bubble column. Experimentally, we have determined the properties of the velocity fluctuations inside and behind a homogeneous swarm of rising bubbles for different bubble sizes and gas volume fractions {alpha}: self-similarity in {alpha}{sup 0,4}, spectrum in k{sup -3} and integral length scale controlled by buoyancy. Numerically, we have reproduced these properties by means of large-scale simulations, the bubbles being modeled by volume-forces. This confirms that the dynamics is controlled by wake interactions. (author)

  1. Impact of nuclear irradiation on helium bubble nucleation at interfaces in liquid metals coupled to permeation through stainless steels

    CERN Document Server

    Fradera, Jorge

    2013-01-01

    The impact of nucleating gas bubbles in the form of a dispersed gas phase on hydrogen isotope permeation at interfaces between liquid metals, like LLE, and structural materials, like stainless steel, has been studied. Liquid metal to structural material interfaces involving surfaces, may lower the nucleation barrier promoting bubble nucleation at active sites. Hence, hydrogen isotope absorption into gas bubbles modelling and control at interfaces may have a capital importance regarding design, operation and safety. He bubbles as a permeation barrier principle is analysed showing a significant impact on hydrogen isotope permeation, which may have a significant effect on liquid metal systems, e.g., tritium extraction systems. Liquid metals like LLE under nuclear irradiation in, e.g., breeding blankets of a nuclear fusion reactor would generate tritium which is to be extracted and recirculated as fuel. At the same time that tritium is bred, helium is also generated and may precipitate in the form of nano bubbles...

  2. A numerical study on gas–liquid mass transfer in the rotor–stator spinning disc reactor

    NARCIS (Netherlands)

    Eeten, van K.M.P.; Verzicco, R.; Schaaf, van der J.; Heijst, van G.J.F.; Schouten, J.C.

    2015-01-01

    The gas–liquid mass transfer coefficient was investigated in a novel multiphase reactor: the rotor–stator spinning disc reactor. Direct Numerical Simulations of the flow field around a single bubble in the reactor showed that vortex stretching invoked the presence of turbulence inside the thin liqui

  3. INTERACTIONS OF THE INFRARED BUBBLE N4 WITH ITS SURROUNDINGS

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Hong-Li; Li, Jin-Zeng; Yuan, Jing-Hua; Huang, Maohai; Huang, Ya-Fang; Zhang, Si-Ju [National Astronomical Observatories, Chinese Academy of Sciences, 20A Datun Road, Chaoyang District, Beijing 100012 (China); Wu, Yuefang [Department of Astronomy, Peking University, 100871 Beijing (China); Liu, Tie [Korea Astronomy and Space Science Institute 776, Daedeokdae-ro, Yuseong-gu, Daejeon, 305-348 (Korea, Republic of); Dubner, G.; Paron, S.; Ortega, M. E. [1Instituto de Astronomía y Física del Espacio (IAFE, CONICET-UBA), CC 67, Suc. 28, 1428 Buenos Aires (Argentina); Molinari, Sergio [Istituto di Astrofisica e Planetologia Spaziali—IAPS, Istituto Nazionale di Astrofisica—INAF, via Fosso del Cavaliere 100, I-00133 Roma (Italy); Zavagno, Annie; Samal, Manash R., E-mail: hlliu@nao.cas.cn [Aix Marseille Universit, CNRS, LAM (Laboratoire d’Astrophysique de Marseille) UMR 7326, F-13388, Marseille (France)

    2016-02-10

    The physical mechanisms that induce the transformation of a certain mass of gas in new stars are far from being well understood. Infrared bubbles associated with H ii regions have been considered to be good samples for investigating triggered star formation. In this paper we report on the investigation of the dust properties of the infrared bubble N4 around the H ii region G11.898+0.747, analyzing its interaction with its surroundings and star formation histories therein, with the aim of determining the possibility of star formation triggered by the expansion of the bubble. Using Herschel PACS and SPIRE images with a wide wavelength coverage, we reveal the dust properties over the entire bubble. Meanwhile, we are able to identify six dust clumps surrounding the bubble, with a mean size of 0.50 pc, temperature of about 22 K, mean column density of 1.7 × 10{sup 22} cm{sup −2}, mean volume density of about 4.4 × 10{sup 4} cm{sup −3}, and a mean mass of 320 M{sub ⊙}. In addition, from PAH emission seen at 8 μm, free–free emission detected at 20 cm, and a probability density function in special regions, we could identify clear signatures of the influence of the H ii region on the surroundings. There are hints of star formation, though further investigation is required to demonstrate that N4 is the triggering source.

  4. Bubble-bubble interaction: A potential source of cavitation noise

    CERN Document Server

    Ida, Masato

    2009-01-01

    The interaction between microbubbles through pressure pulses has been studied to show that it can be a source of cavitation noise. A recent report demonstrated that the acoustic noise generated by a shrimp originates from the collapse of a cavitation bubble produced when the shrimp closes its snapper claw. The recorded acoustic signal contains a broadband noise that consists of positive and negative pulses, but a theoretical model for single bubbles fails to reproduce the negative ones. Using a nonlinear multibubble model we have shown here that the negative pulses can be explained by considering the interaction of microbubbles formed after the cavitation bubble has collapsed and fragmented: Positive pulses produced at the collapse of the microbubbles hit and impulsively compress neighboring microbubbles to generate reflected pulses whose amplitudes are negative. Discussing the details of the noise generation process, we have found that no negative pulses are generated if the internal pressure of the reflecti...

  5. Bubble-sort图和Modified Bubble-sort图的自同构群%Automorphism Groups of Bubble-sort Graphs and Modified Bubble-sort Graphs

    Institute of Scientific and Technical Information of China (English)

    张昭; 黄琼湘

    2005-01-01

    Bubble-sort graphs and modified bubble-sort graphs are two classes of Cayley graphs which are widely studied for their application in network construction. In this paper, we determine the full automorphism groups of bubble-sort graphs and modified bubble-sort graphs.%Bubble-Sort图和Modified Bubble-Sort图是两类特殊的Cayley图,由于其在网络构建中的应用而受到广泛关注.本文完全确定了这两类图的自同构群.

  6. Spherical Solutions of an Underwater Explosion Bubble

    Directory of Open Access Journals (Sweden)

    Andrew B. Wardlaw

    1998-01-01

    Full Text Available The evolution of the 1D explosion bubble flow field out to the first bubble minimum is examined in detail using four different models. The most detailed is based on the Euler equations and accounts for the internal bubble fluid motion, while the simplest links a potential water solution to a stationary, Isentropic bubble model. Comparison of the different models with experimental data provides insight into the influence of compressibility and internal bubble dynamics on the behavior of the explosion bubble.

  7. N131: A dust bubble was born from the disruption of a gas filament?

    Science.gov (United States)

    Zhang, Chuan-Peng

    2017-03-01

    N131 is an infrared dust bubble residing in a molecular filament. We aim to study the formation and fragmentation of this bubble with multi-wavelength dust and gas observations. Towards the bubble N131, we analyzed archival multi-wavelength observations including 3.6, 4.5, 5.8, 8.0, 24, 70, 160, 250, 350, 500 μm, 1.1 mm, and 21 cm. In addition, we performed new observations of CO (2-1), CO (1-0), and 13CO (1-0) with the IRAM 30-m telescope. Multi-wavelength dust and gas observations reveal a ringlike shell with compact fragments, two filamentary structures, and a secondary bubble N131-A. The bubble N131 is a rare object with a large hole at 24 μm and 21 cm in the direction of its center. The dust and gas clumps are compact and might have been compressed at the inner edge of the ringlike shell, while they are extended and might be pre-existing at the outer edge. The column density, excitation temperature, and velocity show a potentially hierarchical distribution from the inner to outer edge of the ringlike shell. We also detected the front and back sides of the secondary bubble N131-A in the direction of its center. The derived Lyman-continuum ionizing photon flux within N131-A is equivalent to an O9.5 star. Based on the above, we suggest that the bubble N131 might be triggered by the strong stellar winds from a group of massive stars inside the bubble. We propose a scenario in which the bubble N131 forms from the disruption of a gas filament by expansion of H II region, strong stellar winds, and fragments under self-gravity.

  8. Gas Line Pressure Fluctuation Analysis of a Gas-Liquid Reactor

    Institute of Scientific and Technical Information of China (English)

    J.J.J. CHEN; J.C. ZHAO

    2005-01-01

    To ensure efficient operation of metallurgical gas-liquid reactors, the gas bubbles must be uniformly distributed.For high temperature metallurgical reactors, it is impractical and unsafe to carry out visual observations.An air-water model was used to study the relationship between the bubble flow patterns and the pressure fluctuation signals.The fluctuation signals captured in the time domain were transformed into the frequency domain. Various parameters obtained from the transformed data were analysed for their suitability for delineating the bubble flow pqtterns observed.These parameters and the flow patterns were found to be well-correlated using the gas flow number.

  9. Bursting Bubbles and Bilayers

    Directory of Open Access Journals (Sweden)

    Steven P. Wrenn, Stephen M. Dicker, Eleanor F. Small, Nily R. Dan, Michał Mleczko, Georg Schmitz, Peter A. Lewin

    2012-01-01

    Full Text Available This paper discusses various interactions between ultrasound, phospholipid monolayer-coated gas bubbles, phospholipid bilayer vesicles, and cells. The paper begins with a review of microbubble physics models, developed to describe microbubble dynamic behavior in the presence of ultrasound, and follows this with a discussion of how such models can be used to predict inertial cavitation profiles. Predicted sensitivities of inertial cavitation to changes in the values of membrane properties, including surface tension, surface dilatational viscosity, and area expansion modulus, indicate that area expansion modulus exerts the greatest relative influence on inertial cavitation. Accordingly, the theoretical dependence of area expansion modulus on chemical composition - in particular, poly (ethylene glyclol (PEG - is reviewed, and predictions of inertial cavitation for different PEG molecular weights and compositions are compared with experiment. Noteworthy is the predicted dependence, or lack thereof, of inertial cavitation on PEG molecular weight and mole fraction. Specifically, inertial cavitation is predicted to be independent of PEG molecular weight and mole fraction in the so-called mushroom regime. In the “brush” regime, however, inertial cavitation is predicted to increase with PEG mole fraction but to decrease (to the inverse 3/5 power with PEG molecular weight. While excellent agreement between experiment and theory can be achieved, it is shown that the calculated inertial cavitation profiles depend strongly on the criterion used to predict inertial cavitation. This is followed by a discussion of nesting microbubbles inside the aqueous core of microcapsules and how this significantly increases the inertial cavitation threshold. Nesting thus offers a means for avoiding unwanted inertial cavitation and cell death during imaging and other applications such as sonoporation. A review of putative sonoporation mechanisms is then presented

  10. How safe is Bubble Soccer?

    Science.gov (United States)

    Halani, Sameer H; Riley, Jonathan P; Pradilla, Gustavo; Ahmad, Faiz U

    2016-12-01

    Traumatic neurologic injury in contact sports is a rare but serious consequence for its players. These injuries are most commonly associated with high-impact collisions, for example in football, but are found in a wide variety of sports. In an attempt to minimize these injuries, sports are trying to increase safety by adding protection for participants. Most recently is the seemingly 'safe' sport of Bubble Soccer, which attempts to protect its players with inflatable plastic bubbles. We report a case of a 16-year-old male sustaining a cervical spine burst fracture with incomplete spinal cord injury while playing Bubble Soccer. To our knowledge, this is the first serious neurological injury reported in the sport.

  11. CFD analysis of bubble microlayer and growth in subcooled flow boiling

    Energy Technology Data Exchange (ETDEWEB)

    Owoeye, Eyitayo James, E-mail: msgenius10@ufl.edu; Schubring, DuWanye, E-mail: dlschubring@ufl.edu

    2016-08-01

    Highlights: • A new LES-microlayer model is introduced. • Analogous to the unresolved SGS in LES, analysis of bubble microlayer was performed. • The thickness of bubble microlayer was computed at both steady and transient states. • The macroscale two-phase behavior was captured with VOF coupled with AMR. • Numerical validations were performed for both the micro- and macro-region analyses. - Abstract: A numerical study of single bubble growth in turbulent subcooled flow boiling was carried out. The macro- and micro-regions of the bubble were analyzed by introducing a LES-microlayer model. Analogous to the unresolved sub-grid scale (SGS) in LES, a microlayer analysis was performed to capture the unresolved thermal scales for the micro-region heat transfer by deriving equations for the microlayer thickness at steady and transient states. The phase change at the macro-region was based on Volume-of-Fluid (VOF) interface tracking method coupled with adaptive mesh refinement (AMR). Large Eddy Simulation (LES) was used to model the turbulence characteristics. The numerical model was validated with multiple experimental data from the open literature. This study includes parametric variations that cover the operating conditions of boiling water reactor (BWR) and pressurized water reactor (PWR). The numerical model was used to study the microlayer thickness, growth rate, dynamics, and distortion of the bubble.

  12. Fine bubble generator and method

    Energy Technology Data Exchange (ETDEWEB)

    Bhagat, P.M.; Koros, R.M.

    1990-10-09

    This patent describes a method of forming fine gaseous bubbles in a liquid ambient. It comprises: forcing a gas through orifices located in the liquid ambient while simultaneously forcing a liquid through liquid orifices at a velocity sufficient to form jet streams of liquid, the liquid orifices being equal in number to the gas orifices and so oriented that each jet stream of liquid intersects the gas forced through each gas orifice and creates sufficient turbulence where the gas and jet stream of liquid intersect, whereby fine gaseous bubbles are formed.

  13. Progress in the Development of Compressible, Multiphase Flow Modeling Capability for Nuclear Reactor Flow Applications

    Energy Technology Data Exchange (ETDEWEB)

    R. A. Berry; R. Saurel; F. Petitpas; E. Daniel; O. Le Metayer; S. Gavrilyuk; N. Dovetta

    2008-10-01

    In nuclear reactor safety and optimization there are key issues that rely on in-depth understanding of basic two-phase flow phenomena with heat and mass transfer. Within the context of multiphase flows, two bubble-dynamic phenomena – boiling (heterogeneous) and flashing or cavitation (homogeneous boiling), with bubble collapse, are technologically very important to nuclear reactor systems. The main difference between boiling and flashing is that bubble growth (and collapse) in boiling is inhibited by limitations on the heat transfer at the interface, whereas bubble growth (and collapse) in flashing is limited primarily by inertial effects in the surrounding liquid. The flashing process tends to be far more explosive (and implosive), and is more violent and damaging (at least in the near term) than the bubble dynamics of boiling. However, other problematic phenomena, such as crud deposition, appear to be intimately connecting with the boiling process. In reality, these two processes share many details.

  14. Bubble nucleation in an explosive micro-bubble actuator

    NARCIS (Netherlands)

    Broek, van den D.M.; Elwenspoek, M.C.

    2008-01-01

    Explosive evaporation occurs when a thin layer of liquid reaches a temperature close to the critical temperature in a very short time. At these temperatures spontaneous nucleation takes place. The nucleated bubbles instantly coalesce forming a vapour film followed by rapid growth due to the pressure

  15. Bubble Content in Air/Hydro System--Part 1:Measurement of Bubble Content

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    The mechanism of bubble formation in air/hydro systems is investigated. Results presented in this paper include further insight into the mechanism of bubble formation and the measurement of bubble content. The regularity of bubble transport in the system is found, with an idea for a new method for separating gas from oil. The method has been verified experimentally with favorable results.

  16. Single bubble sonoluminescence and stable cavitation

    Institute of Scientific and Technical Information of China (English)

    CHEN Qian; QIAN Menglu

    2004-01-01

    A single bubble trapped at an antinode of an acoustic standing wave field in water can emit 50ps-140ps light pulses, called "single bubble sonoluminescence" (SBSL). It arouses much interest in physical acoustics because of its highly non-linear characteristics, high concentration of energy, and stable cavitation behavior. In this paper, bubble stability, the dynamic behavior of bubbles, non-invasive measurement of driving acoustic pressure and Mie scattering method are introduced.

  17. Determination of Free Choline in Citicoline Sodium Injection by HPLC with Electrochemical Detection Combined with a Post-Column Immobilized Enzyme Reactor%HPLC-电化学法测定胞磷胆碱钠注射液中游离胆碱含量

    Institute of Scientific and Technical Information of China (English)

    黄晓舞; 刘俊; 徐江; 沈娟

    2012-01-01

    目的 建立胞磷胆碱钠注射液中游离胆碱含量测定方法.方法 采用高效液相色谱电化学检测法,专用色谱柱(ESA ACH-3,250 mm×3 mm ID)和固相胆碱氧化酶反应器(ESA ACH-SPR,3 cm),M5040分析电极和5300型电化学检测器,柱温:35C,流速:0.35 m-1 ·min-1.结果 游离胆碱在0.12 ~2.89 μg.ml-1范围内呈良好线性关系,r=0.9999,平均回收率为100.0%,RSD为2.7%(n=6).结论 该方法简便可行,重复性好,可用于胞磷胆碱钠注射剂中游离胆碱含量测定.%Objective To determine free choline in citicoline sodium injection. Methods HPLC was used together with electrochemical detection combined with a post-column immobilized enzyme reactor (IMER). This assay was based on the separation of choline on a polymer gel column(ESA ACH-3,250 mm×3 mm ID) followed by the passage of the effluent through an IMER (ESA ACH-SPR,3 cm) ,on which the separated choline reacted respectively to give each stoichiometric yield of hydrogen peroxide, which was detected electrochemically at an electrode ( ESA M5040, E1: + 300 mV). The flow rate was 0. 35 ml·min-1 ,and the column temperature was 35℃. Results The linear range of free choline was 0. 12-2. 89 μg·ml-1 ( r =0. 9999) ,The average recovery was 100. 0% and RSD was 1.6%. Conclusion This method can be used for quality control of free choline in citicoline sodium injection.

  18. Passive acoustic derived bubble flux and applications to natural gas seepage in the Mackenzie Delta, NWT, Canada and Coal Oil Point, CA

    Science.gov (United States)

    Culling, D.; Leifer, I.; Dallimore, S.; Alcala, K.

    2012-12-01

    Methane is a prominent greenhouse gas that escapes naturally from thermogenic reservoirs as seepage from marine and lacustrine biogenic sources as bubble ebullition. Geologic methane emissions are critically important contributors to the global methane budget however, few quantitative flux measurements are available for shallow waters. This gap in knowledge is critical as in these settings gas can easily transit as bubbles through the water column and directly influence global atmospheric budgets. Video and active acoustic (sonar) measurements of bubble flux have spatial limitations requiring predictable bubble emission location. Passive acoustics are less affected by these limitations, in addition, they can provide data in water too shallow for effective sonar bubble observations. Lab tests were undertaken to quantify the acoustic signature of bubbles formed in non-cohesive sediments. specifically focusing on mechanisms that complicate interpretation of acoustic data. Lab tests then were compared to field data to provide measurement calibration/validation. The principles behind the acoustic analysis method are based on the Minnaert equation, which relates a bubble radius and acoustic frequency. Bubble size and the resultant acoustic frequency from known flows and capillary tube diameters are well documented; however changing sediment pathways adds to the complexity of bubble formation and the resultant bubble acoustic signal. These complex signals were investigated in a lab tank with a thick, cohesive fine-grained sediment bed, through which bubbles produced by a syringe pump migrated to the sediment-water interface. Then, the resultant bubbles were diverted into clear water and measured from high speed, high definition video, while the acoustic signature of bubble formation was recorded concurrently by a hydrophone. Bubble formation is influenced by currents, which shifts the acoustical signal towards a higher frequency with a more complex pattern than the

  19. Bubble Formation in Silicon-Quartz Interface

    OpenAIRE

    Kakimoto, K.; EGUCHI, M.; Ozoe, H.

    1997-01-01

    Bubble formation at an interface between silicon melt and a quartz crucible was studied by thermodynamical calculation and visualization of bubble formation using X-ray radiography. A phase diagram of silicon-oxygen (Si-O) system is also calculated from the reported thermodynamical data. Critical temperature and radius of bubble formation at the interface was discussed.

  20. Radiation Damping at a Bubble Wall

    CERN Document Server

    Lee, J; Lee, C H; Jang, J; Lee, Jae-weon; Kim, Kyungsub; Lee, Chul H.; Jang, Ji-ho

    1999-01-01

    The first order phase transition proceeds via nucleation and growth of true vacuum bubbles. When charged particles collide with the bubble they could radiate electromagnetic wave. We show that, due to an energy loss of the particles by the radiation, the damping pressure acting on the bubble wall depends on the velocity of the wall even in a thermal equilibrium state.

  1. Multifunctional reactors

    NARCIS (Netherlands)

    Westerterp, K.R.

    1992-01-01

    Multifunctional reactors are single pieces of equipment in which, besides the reaction, other functions are carried out simultaneously. The other functions can be a heat, mass or momentum transfer operation and even another reaction. Multifunctional reactors are not new, but they have received much

  2. Particle Residence Time in Column Flotation Based on Cyclonic Separation

    Institute of Scientific and Technical Information of China (English)

    ZHOU Xiao-hua; LIU Jiong-tian

    2007-01-01

    The cyclonic static micro-bubble column flotation (FCSMC) is an effective separation device for fine particle treatment. The high mineralization rate and short flotation time of this equipment can be attributed to its unique cyclonic force field. It also has been observed that the presence of a cyclonic force field leads to a lower bottom separation size limit and a reduction of unselective entrainment. The collection zone of the column is considered to consist of two parts, a column separation zone and a cyclonic zone. Total recovery of the collection zone was developed. For our study, we analyzed the particle movement in the cyclonic zone. Particle residence time equations for the cyclonic zone were derived by force analysis. Results obtained in this study provide a theoretical foundation for the design and scale-up of the FCSMC.

  3. Dynamic behavior of gas bubble in single bubble sonoluminescence - vibrator model

    Institute of Scientific and Technical Information of China (English)

    QIAN Menglu; CHENG Qian; GE Caoyan

    2002-01-01

    Single bubble sonoluminescence is a process of energy transformation from soundto light. Therefore the motion equations of near spherical vibration of a gas bubble in anincompressible and viscous liquid can be deduced by Lagrangian Equation with dissipationfunction when the bubble is considered as a vibrator surrounded by liquid. The analyticalsolutions in the bubble expanding, collapsing and rebounding stages can be obtained by solvingthese motion equations when some approximations are adopted. And the dynamic behaviorsof the bubble in these three stages are discussed.

  4. "Financial Bubbles" and Monetary Policy

    Science.gov (United States)

    Tikhonov, Yuriy A.; Pudovkina, Olga E.; Permjakova, Juliana V.

    2016-01-01

    The relevance of this research is caused by the need of strengthening a role of monetary regulators to prevent financial bubbles in the financial markets. The aim of the article is the analysis of a problem of crisis phenomena in the markets of financial assets owing to an inadequate growth of their cost, owing to subjective reasons. The leading…

  5. Impurity bubbles in a BEC

    Science.gov (United States)

    Timmermans, Eddy; Blinova, Alina; Boshier, Malcolm

    2013-05-01

    Polarons (particles that interact with the self-consistent deformation of the host medium that contains them) self-localize when strongly coupled. Dilute Bose-Einstein condensates (BECs) doped with neutral distinguishable atoms (impurities) and armed with a Feshbach-tuned impurity-boson interaction provide a unique laboratory to study self-localized polarons. In nature, self-localized polarons come in two flavors that exhibit qualitatively different behavior: In lattice systems, the deformation is slight and the particle is accompanied by a cloud of collective excitations as in the case of the Landau-Pekar polarons of electrons in a dielectric lattice. In natural fluids and gases, the strongly coupled particle radically alters the medium, e.g. by expelling the host medium as in the case of the electron bubbles in superfluid helium. We show that BEC-impurities can self-localize in a bubble, as well as in a Landau-Pekar polaron state. The BEC-impurity system is fully characterized by only two dimensionless coupling constants. In the corresponding phase diagram the bubble and Landau-Pekar polaron limits correspond to large islands separated by a cross-over region. The same BEC-impurity species can be adiabatically Feshbach steered from the Landau-Pekar to the bubble regime. This work was funded by the Los Alamos LDRD program.

  6. Electrolysis Bubbles Make Waterflow Visible

    Science.gov (United States)

    Schultz, Donald F.

    1990-01-01

    Technique for visualization of three-dimensional flow uses tiny tracer bubbles of hydrogen and oxygen made by electrolysis of water. Strobe-light photography used to capture flow patterns, yielding permanent record that is measured to obtain velocities of particles. Used to measure simulated mixing turbulence in proposed gas-turbine combustor and also used in other water-table flow tests.

  7. The Big European Bubble Chamber

    CERN Multimedia

    1977-01-01

    The 3.70 metre Big European Bubble Chamber (BEBC), dismantled on 9 August 1984. During operation it was one of the biggest detectors in the world, producing direct visual recordings of particle tracks. 6.3 million photos of interactions were taken with the chamber in the course of its existence.

  8. Droplets, Bubbles and Ultrasound Interactions

    NARCIS (Netherlands)

    Shpak, O.; Verweij, M.; Jong, de N.; Versluis, M.; Escoffre, J.M.; Bouakaz, A.

    2016-01-01

    The interaction of droplets and bubbles with ultrasound has been studied extensively in the last 25 years. Microbubbles are broadly used in diagnostic and therapeutic medical applications, for instance, as ultrasound contrast agents. They have a similar size as red blood cells, and thus are able to

  9. Explosive micro-bubble actuator

    NARCIS (Netherlands)

    Broek, van den D.M.; Elwenspoek, M.C.

    2007-01-01

    Explosive evaporation occurs when a thin layer of liquid reaches a very high temperature in a very short time. At these temperatures homogeneous nucleation takes place. The nucleated bubbles almost instantly coalesce forming a vapour film followed by rapid growth due to the pressure impulse and fina

  10. Bubble-Driven Inertial Micropump

    CERN Document Server

    Torniainen, Erik D; Markel, David P; Kornilovitch, Pavel E

    2012-01-01

    The fundamental action of the bubble-driven inertial micropump is investigated. The pump has no moving parts and consists of a thermal resistor placed asymmetrically within a straight channel connecting two reservoirs. Using numerical simulations, the net flow is studied as a function of channel geometry, resistor location, vapor bubble strength, fluid viscosity, and surface tension. Two major regimes of behavior are identified: axial and non-axial. In the axial regime, the drive bubble either remains inside the channel or continues to grow axially when it reaches the reservoir. In the non-axial regime the bubble grows out of the channel and in all three dimensions while inside the reservoir. The net flow in the axial regime is parabolic with respect to the hydraulic diameter of the channel cross-section but in the non-axial regime it is not. From numerical modeling, it is determined that the net flow is maximal when the axial regime crosses over to the non-axial regime. To elucidate the basic physical princi...

  11. The effects of bubble-bubble interactions on pressures and temperatures produced by bubbles collapsing near a rigid surface

    Science.gov (United States)

    Alahyari Beig, Shahaboddin; Johnsen, Eric

    2016-11-01

    Cavitation occurs in a wide range of hydraulic applications, and one of its most important consequences is structural damage to neighboring surfaces following repeated bubble collapse. A number of studies have been conducted to predict the pressures produced by the collapse of a single bubble. However, the collapse of multiple bubbles is known to lead to enhanced collapse pressures. In this study, we quantify the effects of bubble-bubble interactions on the bubble dynamics and pressures/temperatures produced by the collapse of a pair of bubbles near a rigid surface. For this purpose, we use an in-house, high-order accurate shock- and interface-capturing method to solve the 3D compressible Navier-Stokes equations for gas/liquid flows. The non-spherical bubble dynamics are investigated and the subsequent pressure and temperature fields are characterized based on the relevant parameters entering the problem: stand-off distance, geometrical configuation, collapse strength. We demonstrate that bubble-bubble interactions amplify/reduce pressures and temperatures produced at the collapse, and increase the non-sphericity of the bubbles and the collapse time, depending on the flow parameters.

  12. Experimental study of the interaction between the spark-induced cavitation bubble and the air bubble

    Institute of Scientific and Technical Information of China (English)

    罗晶; 许唯临; 牛志攀; 罗书靖; 郑秋文

    2013-01-01

    Experiments are carried out by using high-speed photography to investigate the interaction between the spark-generated cavitation bubble and the air bubble in its surrounding fluid. Three problems are discussed in detail: the impact of the air bubble upon the development of the cavitation bubble, the evolution of the air bubble under the influence of the cavitation bubble, and the change of the fluid pressure during the development of a micro jet of the cavitation bubble. Based on the experimental results, under the condition of no air bubble present, the lifetime of the cavitation bubble from expansion to contraction increases with the increase of the maximum radius. On the other hand, when there is an air bubble present, different sized cavitation bubbles have similarity with one another generally in terms of the lifetime from expansion to contraction, which does not depend on the maximum radius. Also, with the presence of an air bubble, the lifetime of the smaller cavitation bubble is extended while that of the bigger ones reduced. Furthermore, it is shown in the experiment that the low pressure formed in the opposite direction to the cavitation bubble micro jet makes the air bubble in the low pressure area being stretched into a steplike shape.

  13. Eruption column physics

    Energy Technology Data Exchange (ETDEWEB)

    Valentine, G.A.

    1997-03-01

    In this paper the author focuses on the fluid dynamics of large-scale eruption columns. The dynamics of these columns are rooted in multiphase flow phenomena, so a major part of the paper sets up a foundation on that topic that allows one to quickly assess the inherent assumptions made in various theoretical and experimental approaches. The first part is centered on a set of complex differential equations that describe eruption columns, but the focus is on a general understanding of important physical processes rather than on the mathematics. The author discusses briefly the relative merits and weaknesses of different approaches, emphasizing that the largest advances in understanding are made by combining them. He then focuses on dynamics of steady eruption columns and then on transient phenomena. Finally he briefly reviews the effects of varying behavior of the ambient medium through which an eruption column moves. These final sections will emphasize concepts and a qualitative understanding of eruption dynamics. This paper relies on principles of continuum mechanics and transport processes but does not go into detail on the development of those principles. 36 refs., 36 figs., 3 tabs.

  14. Shell correction energy for bubble nuclei

    CERN Document Server

    Yu, Y; Magierski, P; Bulgac, Aurel; Magierski, Piotr

    2000-01-01

    The positioning of a bubble inside a many fermion system does not affect the volume, surface or curvature terms in the liquid drop expansion of the total energy. Besides possible Coulomb effects, the only other contribution to the ground state energy of such a system arises from shell effects. We show that the potential energy surface is a rather shallow function of the displacement of the bubble from the center and in most cases the preferential position of a bubble is off center. Systems with bubbles are expected to have bands of extremely low lying collective states, corresponding to various bubble displacements.

  15. Supercoiling induces denaturation bubbles in circular DNA.

    Science.gov (United States)

    Jeon, Jae-Hyung; Adamcik, Jozef; Dietler, Giovanni; Metzler, Ralf

    2010-11-12

    We present a theoretical framework for the thermodynamic properties of supercoiling-induced denaturation bubbles in circular double-stranded DNA molecules. We explore how DNA supercoiling, ambient salt concentration, and sequence heterogeneity impact on the bubble occurrence. An analytical derivation of the probability distribution to find multiple bubbles is derived and the relevance for supercoiled DNA discussed. We show that in vivo sustained DNA bubbles are likely to occur due to partial twist release in regions rich in weaker AT base pairs. Single DNA plasmid imaging experiments clearly demonstrate the existence of bubbles in free solution.

  16. Bubble Universe Dynamics After Free Passage

    CERN Document Server

    Ahlqvist, Pontus; Greene, Brian

    2013-01-01

    We consider bubble collisions in single scalar field theories with multiple vacua. Recent work has argued that at sufficiently high impact velocities, collisions between such bubble vacua are governed by 'free passage' dynamics in which field interactions can be ignored during the collision, providing a systematic process for populating local minima without quantum nucleation. We focus on the time period that follows the bubble collision and provide evidence that, for certain potentials, interactions can drive significant deviations from the free-passage bubble profile, thwarting the production of bubbles with different field values.

  17. Shock-induced collapse of a bubble inside a deformable vessel.

    Science.gov (United States)

    Coralic, Vedran; Colonius, Tim

    2013-07-01

    Shockwave lithotripsy repeatedly focuses shockwaves on kidney stones to induce their fracture, partially through cavitation erosion. A typical side effect of the procedure is hemorrhage, which is potentially the result of the growth and collapse of bubbles inside blood vessels. To identify the mechanisms by which shock-induced collapse could lead to the onset of injury, we study an idealized problem involving a preexisting bubble in a deformable vessel. We utilize a high-order accurate, shock- and interface-capturing, finite-volume scheme and simulate the three-dimensional shock-induced collapse of an air bubble immersed in a cylindrical water column which is embedded in a gelatin/water mixture. The mixture is a soft tissue simulant, 10% gelatin by weight, and is modeled by the stiffened gas equation of state. The bubble dynamics of this model configuration are characterized by the collapse of the bubble and its subsequent jetting in the direction of the propagation of the shockwave. The vessel wall, which is defined by the material interface between the water and gelatin/water mixture, is invaginated by the collapse and distended by the impact of the jet. The present results show that the highest measured pressures and deformations occur when the volumetric confinement of the bubble is strongest, the bubble is nearest the vessel wall and/or the angle of incidence of the shockwave reduces the distance between the jet tip and the nearest vessel surface. For a particular case considered, the 40 MPa shockwave utilized in this study to collapse the bubble generated a vessel wall pressure of almost 450 MPa and produced both an invagination and distention of nearly 50% of the initial vessel radius on a (10) ns timescale. These results are indicative of the significant potential of shock-induced collapse to contribute to the injury of blood vessels in shockwave lithotripsy.

  18. An equation of motion for bubble growth

    Energy Technology Data Exchange (ETDEWEB)

    Lesage, F.J. [College d' Enseignement General et Professionnel de L' Outaouais, Gatineau, Quebec (Canada). Dept. of Mathematics; Cotton, J.S. [McMaster University, Hamilton, ON (Canada). Dept. of Mechanical Engineering; Robinson, A.J. [Trinity College Dublin (Ireland). Dept. of Mechanical and Manufacturing Engineering

    2009-07-01

    A mathematical model is developed which describes asymmetric bubble growth, either during boiling or bubble injection from submerged orifices. The model is developed using the integral form of the continuity and momentum equations, resulting in a general expression for the acceleration of the bubble's centre of gravity. The proposed model highlights the need to include acceleration due to an asymmetric gain or loss of mass in order to accurately predict bubble motion. Some scenarios are posed by which the growth of bubbles, particularly idealized bubbles that remain a section of a sphere, must include the fact that bubble growth can be asymmetric. In particular, for approximately hemispherical bubble growth the sum of the forces acting on the bubble is negligible compared with the asymmetric term. Further, for bubble injection from a submerged needle this component in the equation of motion is very significant during the initial rapid growth phase as the bubble issues from the nozzle changing from a near hemisphere to truncated sphere geometry. (author)

  19. Bubbles generated from wind-steepened breaking waves: 2. Bubble plumes, bubbles, and wave characteristics

    NARCIS (Netherlands)

    Leifer, I.; Caulliez, G.; Leeuw, G.de

    2006-01-01

    Measurements of breaking-wave-generated bubble plumes were made in fresh (but not clean) water in a large wind-wave tunnel. To preserve diversity, a classification scheme was developed on the basis of plume dimensions and "optical density," or the plume's ability to obscure the background. Optically

  20. 臭氧气泡大小对分散染料废水氧化处理效果的影响%Influences of ozone bubble size on the treatment of disperse dyestuff wastewater

    Institute of Scientific and Technical Information of China (English)

    王璐; 冯玥; 韦彦斐; 谭德俊; 陈泉源

    2013-01-01

    采用臭氧氧化法处理实际分散染料废水,研究了初始pH、臭氧投加量、反应时间、臭氧气泡大小(气体洗瓶和自制的砂芯鼓泡反应柱分别作反应器)对处理效果的影响,采用动态显微高速摄影仪对反应器内的臭氧气泡进行了表征.结果表明,反应体系的初始pH、臭氧投加量越高,反应速率越快,染料废水的脱色及矿化效果越好;染料废水的臭氧氧化处理过程符合拟二级动力学方程;自制的砂芯鼓泡反应柱改善了臭氧分散效果,缩小了气泡直径,提高了臭氧传质速率和效率,强化了臭氧氧化能力.%The degradation of industrial disperse dyestuff wastewater was investigated using ozonation. The effect of initial solution pH, ozone dose, reaction time and size of ozone bubbles (a gas washing bottle and a self-made porous sintered glass sparger column were respectively served as ozonation reactor) on the degradation was studied. The high-speed microscopic camera was applied to characterize ozone bubbles in two reactors. It was found that the decolorization and mineralization of wastewater and the reaction rate increased as the initial pH value and ozone dose increased. The ozonation of wastewater was correctly modelled by a pseudo second-order kinetic model. Compared with the gas washing bottle, the self-made porous sintered glass sparger column significantly reduced bubble size, increased the mass transfer rate of ozone and enhanced the ozone oxidation of wastewater.

  1. Cosmological HII Bubble Growth During Reionization

    CERN Document Server

    Shin, Min-Su; Cen, Renyue

    2007-01-01

    We present general properties of ionized hydrogen (HII) bubbles and their growth based on a state-of-the-art large-scale (100 Mpc/h) cosmological radiative transfer simulation. The simulation resolves all halos with atomic cooling at the relevant redshifts and simultaneously performs radiative transfer and dynamical evolution of structure formation. Our major conclusions include: (1) for significant HII bubbles, the number distribution is peaked at a volume of ~ 0.6 Mpc^3/h^3 at all redshifts. But, at z 10 even the largest HII bubbles have a balanced ionizing photon contribution from Pop II and Pop III stars, while at z < 8 Pop II stars start to dominate the overall ionizing photon production for large bubbles, although Pop III stars continue to make a non-negligible contribution. (6) The relationship between halo number density and bubble size is complicated but a strong correlation is found between halo number density and bubble size for for large bubbles.

  2. Digital Microfluidics with Bubble Manipulations by Dielectrophoresis

    Directory of Open Access Journals (Sweden)

    Shih-Kang Fan

    2012-03-01

    Full Text Available This paper presents basic bubble manipulations, including transporting, splitting, and merging, by dielectrophoresis (DEP in an oil environment. In our presented method, bubbles are placed between parallel plates in an oil medium of a low vapor pressure, which eliminates the possibility of changing the gaseous composition of the bubble caused by evaporation of the medium. DEP has been previously investigated to actuate dielectric droplets and is adopted here to drive the oil environment as well as the immersed bubbles between parallel plates. In our experiment, air bubbles of 0.3 ml were successfully transported in a 20 cSt silicone oil medium between a 75 mm-high parallel plate gap. In addition, 0.6 ml air bubbles were successfully split into two 0.3 ml air bubbles, and then merged again by DEP. These successful manipulations make digital gaseous lab-on-a-chip a reality.

  3. Reactor vessel

    OpenAIRE

    Makkee, M.; Kapteijn, F.; Moulijn, J.A

    1999-01-01

    A reactor vessel (1) comprises a reactor body (2) through which channels (3) are provided whose surface comprises longitudinal inwardly directed parts (4) and is provided with a catalyst (6), as well as buffer bodies (8, 12) connected to the channels (3) on both sides of the reactor body (2) and comprising connections for supplying (9, 10, 11) and discharging (13, 14, 15) via the channels (3) gases and/or liquids entering into a reaction with each other and substances formed upon this reactio...

  4. Developed ‘laminar’ bubbly flow with non-uniform bubble sizes

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    Bubbles with different sizes have different dynamic and kineticbehavior in a two-phase bubbly flow. A common two-fluid model based on the uniform bubble size assumption is not suitable for a bubbly flow with non-uniform bubble sizes. To deal with non-uniform bubbly flows, a multi-fluid model is established, with which bubbles are divided into several groups according to their sizes and a set of basic equations is derived for each group of bubbles with almost the same size. Through analyzing the bubble-bubble and bubble-pipe wall interactions, two new constitutive laws for the wall-force and pressure difference between the liquid phase and interface are developed to close the averaged basic equations. The respective phase distributions for each group of bubbles measured by a specially designed three-dimensional photographic method are used to check the model. Comparison between model-predicted values and experimental data shows that the model can describe laminar bubbly flow with non-uniform bubble sizes.

  5. Bubble–bubble interaction effects on dynamics of multiple bubbles in a vortical flow field

    Directory of Open Access Journals (Sweden)

    Bing Cui

    2016-02-01

    Full Text Available Bubble–bubble interactions play important roles in the dynamic behaviours of multiple bubbles or bubble clouds in a vortical flow field. Based on the Rayleigh–Plesset equation and the modified Maxey–Riley equation of a single bubble, bubble–bubble interaction terms are derived and introduced for multiple bubbles. Thus, both the Rayleigh–Plesset and modified Maxey–Riley equations are improved by considering bubble–bubble interactions and then applied for the multiple bubbles entrainment into a stationary Gaussian vortex. Runge–Kutta fourth-order scheme is adopted to solve the coupled dynamic and kinematic equations and the convergence study has been conducted. Numerical result has also been compared and validated with the published experimental data. On this basis, the oscillation, trajectory and effects of different parameters of double-bubble and multi-bubble entrainment into Gaussian vortex have been studied and the results have been compared with those of the cases without bubble–bubble interactions. It indicates that bubble–bubble interactions influence the amplitudes and periods of bubble oscillations severely, but have small effects on bubble trajectories.

  6. Suppression of cavitation inception by gas bubble injection: a numerical study focusing on bubble-bubble interaction.

    Science.gov (United States)

    Ida, Masato; Naoe, Takashi; Futakawa, Masatoshi

    2007-10-01

    The dynamic behavior of cavitation and gas bubbles under negative pressure has been studied numerically to evaluate the effect of gas bubble injection into a liquid on the suppression of cavitation inception. In our previous studies, it was demonstrated by direct observation that cavitation occurs in liquid mercury when mechanical impacts are imposed, and this will cause cavitation damage in spallation neutron sources, in which liquid mercury is bombarded by a high-power proton beam. In the present paper, we describe numerical investigations of the dynamics of cavitation bubbles in liquid mercury using a multibubble model that takes into account the interaction of a cavitation bubble with preexisting gas bubbles through bubble-radiated pressure waves. The numerical results suggest that, if the mercury includes gas bubbles whose equilibrium radius is much larger than that of the cavitation bubble, the explosive expansion of the cavitation bubble (i.e., cavitation inception) is suppressed by the positive-pressure wave radiated by the injected bubbles, which decreases the magnitude of the negative pressure in the mercury.

  7. NUCLEAR REACTOR

    Science.gov (United States)

    Miller, H.I.; Smith, R.C.

    1958-01-21

    This patent relates to nuclear reactors of the type which use a liquid fuel, such as a solution of uranyl sulfate in ordinary water which acts as the moderator. The reactor is comprised of a spherical vessel having a diameter of about 12 inches substantially surrounded by a reflector of beryllium oxide. Conventionnl control rods and safety rods are operated in slots in the reflector outside the vessel to control the operation of the reactor. An additional means for increasing the safety factor of the reactor by raising the ratio of delayed neutrons to prompt neutrons, is provided and consists of a soluble sulfate salt of beryllium dissolved in the liquid fuel in the proper proportion to obtain the result desired.

  8. Reactor Neutrinos

    Directory of Open Access Journals (Sweden)

    Soo-Bong Kim

    2013-01-01

    Full Text Available We review the status and the results of reactor neutrino experiments. Short-baseline experiments have provided the measurement of the reactor neutrino spectrum, and their interest has been recently revived by the discovery of the reactor antineutrino anomaly, a discrepancy between the reactor neutrino flux state of the art prediction and the measurements at baselines shorter than one kilometer. Middle and long-baseline oscillation experiments at Daya Bay, Double Chooz, and RENO provided very recently the most precise determination of the neutrino mixing angle θ13. This paper provides an overview of the upcoming experiments and of the projects under development, including the determination of the neutrino mass hierarchy and the possible use of neutrinos for society, for nonproliferation of nuclear materials, and geophysics.

  9. Chemical Reactors.

    Science.gov (United States)

    Kenney, C. N.

    1980-01-01

    Describes a course, including content, reading list, and presentation on chemical reactors at Cambridge University, England. A brief comparison of chemical engineering education between the United States and England is also given. (JN)

  10. Slender CRC Columns

    DEFF Research Database (Denmark)

    Aarup, Bendt; Jensen, Lars Rom; Ellegaard, Peter

    2005-01-01

    CRC is a high-performance steel fibre reinforced concrete with a typical compressive strength of 150 MPa. Design methods for a number of structural elements have been developed since CRC was invented in 1986, but the current project set out to further investigate the range of columns for which...

  11. Columns in Clay

    Science.gov (United States)

    Leenhouts, Robin

    2010-01-01

    This article describes a clay project for students studying Greece and Rome. It provides a wonderful way to learn slab construction techniques by making small clay column capitols. With this lesson, students learn architectural vocabulary and history, understand the importance of classical architectural forms and their influence on today's…

  12. Reactor Neutrinos

    OpenAIRE

    Lasserre, T.; Sobel, H.W.

    2005-01-01

    We review the status and the results of reactor neutrino experiments, that toe the cutting edge of neutrino research. Short baseline experiments have provided the measurement of the reactor neutrino spectrum, and are still searching for important phenomena such as the neutrino magnetic moment. They could open the door to the measurement of coherent neutrino scattering in a near future. Middle and long baseline oscillation experiments at Chooz and KamLAND have played a relevant role in neutrin...

  13. APPLICATION OF γ-RAY ATTENUATION FOR AXIAL DISTRIBUTION OF HOLDUPS IN LARGE-SCALE BUBBLE COLUMN WITH EVALUATED PRESSURE%γ射线透射技术测量气液鼓泡塔内气含率的轴向分布

    Institute of Scientific and Technical Information of China (English)

    靳海波; 杨索和; 佟泽民

    2004-01-01

    The axial profile of gas holdups was measured using a γ-ray densitometry in the pressurizedb ubble column, 0. 3 m in diameter and 6.6 m in height. The principle of γ-ray measurement and data processing is discussed. The axial profile of gas holdups and its average value in two-phase system were obtained in the churn-turbulent flow regime with a gas velocity up to 0.40 m · s-1 and a system pressure up to 1.0 MPa, which are in agreement with results obtained by differential pressure method. The effects of superficial gas velocity, liquid surface tension, liquid viscosity and system pressure on the axial profile of gas holdups were investigated. It is shown that the gas holdup decreases with the increasing liquid viscosity and liquid surface tension, and increases with the increase of pressure and superficial gas velocity.

  14. Conformal gravity and "gravitational bubbles"

    CERN Document Server

    Berezin, V A; Eroshenko, Yu N

    2015-01-01

    We describe the general structure of the spherically symmetric solutions in the Weyl conformal gravity. The corresponding Bach equations are derived for the special type of metrics, which can be considered as the representative of the general class. The complete set of the pure vacuum solutions, consisting of two classes, is found. The first one contains the solutions with constant two-dimensional curvature scalar, and the representatives are the famous Robertson--Walker metrics. We called one of them the "gravitational bubbles", which is compact and with zero Weyl tensor. These "gravitational bubbles" are the pure vacuum curved space-times (without any material sources, including the cosmological constant), which are absolutely impossible in General Relativity. This phenomenon makes it easier to create the universe from "nothing". The second class consists of the solutions with varying curvature scalar. We found its representative as the one-parameter family, which can be conformally covered by the thee-para...

  15. Bubble entrapment through topological change

    KAUST Repository

    Thoroddsen, Sigurdur T.

    2010-05-03

    When a viscousdrop impacts onto a solid surface, it entraps a myriad of microbubbles at the interface between liquid and solid. We present direct high-speed video observations of this entrapment. For viscousdrops, the tip of the spreading lamella is separated from the surface and levitated on a cushion of air. We show that the primary mechanism for the bubble entrapment is contact between this precursor sheet of liquid with the solid and not air pulled directly through cusps in the contact line. The sheet makes contact with the solid surface,forming a wetted patch, which grows in size, but only entraps a bubble when it meets the advancing contact line. The leading front of this wet patch can also lead to the localized thinning and puncturing of the liquid film producing strong splashing of droplets.

  16. Research on Pressure Drop Performance of the Packing-Flotation Column

    Institute of Scientific and Technical Information of China (English)

    LIU Jiong-tian; ZHANG Min; LI Yan-feng; LU Yang

    2006-01-01

    A packing-flotation column was proposed to optimize the flotation environment A research system was established using a 100 mm diameter cyclonic micro-bubble flotation column to study fluid properties. Dry-plate and wet- plate pressure drops were studied and the corresponding pressure drop equations developed. The results show that the dry-plate pressure drop of the packing cyclonic micro-bubble flotation column is 10-15 times less than that of the chemical tower, which is principally shown in its relatively small resistance coefficient, 0.0207. The wet-plate pressure drop is 2-3 times higher than that of the chemical tower, which is largely caused by the separation materials and characteristics of the equipment. With flotation, the greater the pressure drop, the better the flotation environment.

  17. BEBC Big European Bubble Chamber

    CERN Multimedia

    1974-01-01

    A view of the dismantling of the magnet of BEBC, the 3.7 m European Bubble Chamber : iron magnetic shielding ; lower and upper parts of the vacuum enclosure of the magnet; turbo-molecular vacuum pumps for the "fish-eye" windows; the two superconducting coils; a handling platform; the two cryostats suspended from the bar of the travelling crane which has a 170 ton carrying capacity. The chamber proper, not dismantled, is inside the shielding.

  18. Photon Bubbles in Accretion Discs

    OpenAIRE

    Gammie, Charles F.

    1998-01-01

    We show that radiation dominated accretion discs are likely to suffer from a ``photon bubble'' instability similar to that described by Arons in the context of accretion onto neutron star polar caps. The instability requires a magnetic field for its existence. In an asymptotic regime appropriate to accretion discs, we find that the overstable modes obey the remarkably simple dispersion relation \\omega^2 = -i g k F(B,k). Here g is the vertical gravitational acceleration, B the magnetic field, ...

  19. Soap bubbles in paintings: Art and science

    Science.gov (United States)

    Behroozi, F.

    2008-12-01

    Soap bubbles became popular in 17th century paintings and prints primarily as a metaphor for the impermanence and fragility of life. The Dancing Couple (1663) by the Dutch painter Jan Steen is a good example which, among many other symbols, shows a young boy blowing soap bubbles. In the 18th century the French painter Jean-Simeon Chardin used soap bubbles not only as metaphor but also to express a sense of play and wonder. In his most famous painting, Soap Bubbles (1733/1734) a translucent and quavering soap bubble takes center stage. Chardin's contemporary Charles Van Loo painted his Soap Bubbles (1764) after seeing Chardin's work. In both paintings the soap bubbles have a hint of color and show two bright reflection spots. We discuss the physics involved and explain how keenly the painters have observed the interaction of light and soap bubbles. We show that the two reflection spots on the soap bubbles are images of the light source, one real and one virtual, formed by the curved surface of the bubble. The faint colors are due to thin film interference effects.

  20. Armoring confined bubbles in concentrated colloidal suspensions

    Science.gov (United States)

    Yu, Yingxian; Khodaparast, Sepideh; Stone, Howard

    2016-11-01

    Encapsulation of a bubble with microparticles is known to significantly improve the stability of the bubble. This phenomenon has recently gained increasing attention due to its application in a variety of technologies such as foam stabilization, drug encapsulation and colloidosomes. Nevertheless, the production of such colloidal armored bubble with controlled size and particle coverage ratio is still a great challenge industrially. We study the coating process of a long air bubble by microparticles in a circular tube filled with a concentrated microparticles colloidal suspension. As the bubble proceeds in the suspension of particles, a monolayer of micro-particles forms on the interface of the bubble, which eventually results in a fully armored bubble. We investigate the phenomenon that triggers and controls the evolution of the particle accumulation on the bubble interface. Moreover, we examine the effects of the mean flow velocity, the size of the colloids and concentration of the suspension on the dynamics of the armored bubble. The results of this study can potentially be applied to production of particle-encapsulated bubbles, surface-cleaning techniques, and gas-assisted injection molding.

  1. Use of a packed-bed airlift reactor with net draft tube to study kinetics of naphthalene degradation by Ralstonia eutropha.

    Science.gov (United States)

    Jalilnejad, Elham; Vahabzadeh, Farzaneh

    2014-03-01

    Biodegradation of naphthalene by Ralstonia eutropha (also known as Cupriavidus necator) in a packed-bed airlift reactor with net draft tube (PBALR-nd) was studied; the Kissiris pieces were the packing material. The reactor hydrodynamics has been characterized under abiotic conditions and the dependencies of the superficial gas velocity (U G) on the gas holdup (εG), liquid mixing time, and mass transfer coefficient were determined. The improving role of the net draft tube in this small column reactor (height 42 cm, ID 5 cm) was confirmed. The flow regime was described using the εG α U G (n) expression, and bubbly flow was observed in PBALR-nd at U G kinetics of biodegradation was modeled using the Haldane and Aiba equations. The fitting of the experimental results to the models were done according to the nonlinear least square regression technique. The biokinetic constants (q m, K s, and K i) were estimated and q m as the specific biodegradation rate was equaled to 0.415 and 0.24 mgnaph./mgcell h for the Haldane and Aiba equations, respectively. The goodness of fit reported as R (2) and root-mean-square error (RMSE) showed the adequate fitness of the Haldane and Aiba models in predicting naphthalene biodegradation kinetics. On the basis of the HPLC results, a hypothetical pathway for the biodegradation was presented.

  2. Turbulent Characteristic of Liquid Around a Chain of Bubbles in Non-Newtonian Fluid

    Institute of Scientific and Technical Information of China (English)

    李少白; 马友光; 朱春英; 付涛涛; 李怀志

    2012-01-01

    The turbulence behavior of gas-liquid two-phase flow plays an important role in heat transfer and mass transfer in many chemical processes. In this work, a 2D particle image velocimetry (PIV) was used to investigate the turbulent characteristic of fluid induced by a chain of bubbles rising in Newtonian and non-Newtonian fluids. The instantaneous flow field, turbulent kinetic energy (TKE) and TKE dissipation rate were measured. The results demonstrated that the TKE profiles were almost symmetrical along the column center and showed higher values in the central region of the column. The TKE was enhanced with the increase of gas flow and decrease of liquid viscosity. The maximum TKE dissipation rate appeared on both sides of the bubble chain, and increased with the increase of gas flow rate or liquid viscosity. These results provide an understanding for gas-liquid mass transfer in non-Newtonian fluids.

  3. Particle Dispersion Behaviors of Dense Gas-Particle Flows in Bubble Fluidized Bed

    Directory of Open Access Journals (Sweden)

    Sihao Lv

    2013-01-01

    Full Text Available An Euler-Euler two-fluid model incorporating a developed momentum transfer empirical coefficient is developed to study the particle dispersion behaviors of dense gas-particle flows in gas-fluidization reactor. In this model, the four-way couplings among gas-particles, particle-gas, and particle-particle collisions are fully considered based on kinetic theory of granular flows and an improved smooth continuous drag coefficient is utilized. Gas turbulent flow is solved by large eddy simulation. The particle fraction, the time-averaged axial particle velocity, the histogram of particle fluctuation velocity, and the wavelet analysis of pressure signals are obtained. The results are in good agreement with experimental measurements. The mean value and the variance of axial particle velocity are greater than those of radial particle velocities. Particle collision frequencies at bubble vibrant movement regions along axial direction are much higher than those of radial direction and attenuated along height increase. Low-frequency component of pressure signal indicating the bubble movement behaviors in the center of reactor is stronger than wall regions. Furthermore, the negative values represent the passed bubble and positive peak values disclose the continuous motion of single bubble.

  4. Simulation of bubbly flow in vertical pipes by coupling Lagrangian and Eulerian models with 3D random walks models: validation with experimental data using multi-sensor conductivity probes and laser doppler anemometry

    Energy Technology Data Exchange (ETDEWEB)

    Munoz-Cobo, J.L. [Univ. Politecnica de Valencia, Inst. de Ingenieria Energetica, Valencia (Spain); Chiva, S. [Univ. Jaume I, Dept. of Mechnical Engineering and Construction, Castellon (Spain); Abd El Aziz Essa, M. [Univ. Politecnica de Valencia, Inst. de Ingenieria Energetica, Valencia (Spain); Mendes, S. [Univ. Autonoma de Nuevo Leon, Facultad de Ingenieria Mecanica y Electrica (Mexico)

    2011-07-01

    A set of air-water experiments have been performed under isothermal upward concurrent flow in a vertical column. The interfacial velocity, interfacial area of the bubbles and the void fraction distributions was obtained. Numerical validation of these results for bubbly flow conditions were performed by coupling a Lagrangian code which tracks the 3D motion of the individual bubbles, with an Eulerian one. Both Lagrangian and Eulerian calculations were performed in parallel and iterative self-consistent method was developed. The bubbles-induced turbulence is an important issue considered, to obtain good predictions of experimental results. (author)

  5. An Eulerian-Lagrangian open source solver for bubbly flow in vertical pipes

    Energy Technology Data Exchange (ETDEWEB)

    Pena-Monferrer, C.; Munoz-Cobo, J. L.; Monros-Andreu, G.; Martinez-Cuenca, R.; Chiva, S.

    2014-07-01

    Air-water two-phase flow is present in natural and industrial processes of different nature as nuclear reactors. An accurate local prediction of the boiling flow could support safety and operation analyses of nuclear reactors. An Eulerian-Lagrangian approach is investigated in this contribution as it can be used as a virtual facility to investigate the two-phase flow phenomena. A solver based on the PISO algorithm coupled with the Lagrangian equation of motion have been implemented for computing incompressible bubbly flows. (Author)

  6. Manipulating bubbles with secondary Bjerknes forces

    Energy Technology Data Exchange (ETDEWEB)

    Lanoy, Maxime [Institut Langevin, ESPCI ParisTech, CNRS (UMR 7587), PSL Research University, 1 rue Jussieu, 75005 Paris (France); Laboratoire Matière et Systèmes Complexes, Université Paris-Diderot, CNRS (UMR 7057), 10 rue Alice Domon et Léonie Duquet, 75013 Paris (France); Derec, Caroline; Leroy, Valentin [Laboratoire Matière et Systèmes Complexes, Université Paris-Diderot, CNRS (UMR 7057), 10 rue Alice Domon et Léonie Duquet, 75013 Paris (France); Tourin, Arnaud [Institut Langevin, ESPCI ParisTech, CNRS (UMR 7587), PSL Research University, 1 rue Jussieu, 75005 Paris (France)

    2015-11-23

    Gas bubbles in a sound field are submitted to a radiative force, known as the secondary Bjerknes force. We propose an original experimental setup that allows us to investigate in detail this force between two bubbles, as a function of the sonication frequency, as well as the bubbles radii and distance. We report the observation of both attractive and, more interestingly, repulsive Bjerknes force, when the two bubbles are driven in antiphase. Our experiments show the importance of taking multiple scatterings into account, which leads to a strong acoustic coupling of the bubbles when their radii are similar. Our setup demonstrates the accuracy of secondary Bjerknes forces for attracting or repealing a bubble, and could lead to new acoustic tools for noncontact manipulation in microfluidic devices.

  7. Tube erosion in bubbling fluidized beds

    Energy Technology Data Exchange (ETDEWEB)

    Levy, E.K. [Lehigh Univ., Bethlehem, PA (United States). Energy Research Center; Stallings, J.W. [Electric Power Research Inst., Palo Alto, CA (United States)

    1991-12-31

    This paper reports on experimental and theoretical studies that were preformed of the interaction between bubbles and tubes and tube erosion in fluidized beds. The results are applicable to the erosion of horizontal tubes in the bottom row of a tube bundle in a bubbling bed. Cold model experimental data show that erosion is caused by the impact of bubble wakes on the tubes, with the rate of erosion increasing with the velocity of wake impact with the particle size. Wake impacts resulting from the vertical coalescence of pairs of bubbles directly beneath the tube result in particularly high rates of erosion damage. Theoretical results from a computer simulation of bubbling and erosion show very strong effects of the bed geometry and bubbling conditions on computed rates of erosion. These results show, for example, that the rate of erosion can be very sensitive to the vertical location of the bottom row of tubes with respect to the distributor.

  8. Bernoulli Suction Effect on Soap Bubble Blowing?

    Science.gov (United States)

    Davidson, John; Ryu, Sangjin

    2015-11-01

    As a model system for thin-film bubble with two gas-liquid interfaces, we experimentally investigated the pinch-off of soap bubble blowing. Using the lab-built bubble blower and high-speed videography, we have found that the scaling law exponent of soap bubble pinch-off is 2/3, which is similar to that of soap film bridge. Because air flowed through the decreasing neck of soap film tube, we studied possible Bernoulli suction effect on soap bubble pinch-off by evaluating the Reynolds number of airflow. Image processing was utilized to calculate approximate volume of growing soap film tube and the volume flow rate of the airflow, and the Reynolds number was estimated to be 800-3200. This result suggests that soap bubbling may involve the Bernoulli suction effect.

  9. Mechanism of bubble detachment from vibrating walls

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Dongjun; Park, Jun Kwon, E-mail: junkeun@postech.ac.kr; Kang, Kwan Hyoung [Department of Mechanical Engineering, Pohang University of Science and Technology (POSTECH), San 31, Hyoja-dong, Pohang 790-784 (Korea, Republic of); Kang, In Seok [Department of Chemical Engineering, Pohang University of Science and Technology (POSTECH), San 31, Hyoja-dong, Pohang 790-784 (Korea, Republic of)

    2013-11-15

    We discovered a previously unobserved mechanism by which air bubbles detach from vibrating walls in glasses containing water. Chaotic oscillation and subsequent water jets appeared when a wall vibrated at greater than a critical level. Wave forms were developed at water-air interface of the bubble by the wall vibration, and water jets were formed when sufficiently grown wave-curvatures were collapsing. Droplets were pinched off from the tip of jets and fell to the surface of the glass. When the solid-air interface at the bubble-wall attachment point was completely covered with water, the bubble detached from the wall. The water jets were mainly generated by subharmonic waves and were generated most vigorously when the wall vibrated at the volume resonant frequency of the bubble. Bubbles of specific size can be removed by adjusting the frequency of the wall's vibration.

  10. Bubbles Rising Through a Soft Granular Material

    Science.gov (United States)

    Le Mestre, Robin; MacMinn, Chris; Lee, Sungyon

    2016-11-01

    Bubble migration through a soft granular material involves a strong coupling between the bubble dynamics and the deformation of the material. This is relevant to a variety of natural processes such as gas venting from sediments and gas exsolution from magma. Here, we study this process experimentally by injecting air bubbles into a quasi-2D packing of soft hydrogel beads and measuring the size, speed, and morphology of the bubbles as they rise due to buoyancy. Whereas previous work has focused on deformation resisted by intergranular friction, we focus on the previously inaccessible regime of deformation resisted by elasticity. At low confining stress, the bubbles are irregular and rounded, migrating via local rearrangement. At high confining stress, the bubbles become unstable and branched, migrating via pathway opening. The authors thank The Royal Society for support (International Exchanges Ref IE150885).

  11. Simple improvements to classical bubble nucleation models

    CERN Document Server

    Tanaka, Kyoko K; Angélil, Raymond; Diemand, Jürg

    2015-01-01

    We revisit classical nucleation theory (CNT) for the homogeneous bubble nucleation rate and improve the classical formula using a new prefactor in the nucleation rate. Most of the previous theoretical studies have used the constant prefactor determined by the bubble growth due to the evaporation process from the bubble surface. However, the growth of bubbles is also regulated by the thermal conduction, the viscosity, and the inertia of liquid motion. These effects can decrease the prefactor significantly, especially when the liquid pressure is much smaller than the equilibrium one. The deviation in the nucleation rate between the improved formula and the CNT can be as large as several orders of magnitude. Our improved, accurate prefactor and recent advances in molecular dynamics simulations and laboratory experiments for argon bubble nucleation enable us to precisely constrain the free energy barrier for bubble nucleation. Assuming the correction to the CNT free energy is of the functional form suggested by T...

  12. Ostwald Ripening in Multiple-Bubble Nuclei

    CERN Document Server

    Watanabe, Hiroshi; Inaoka, Hajime; Ito, Nobuyasu

    2014-01-01

    The ostwald ripening of bubbles is studied by molecular dynamics simulations involving up to 679 million Lennard-Jones particles. Many bubbles appear after depressurizing a system that is initially maintained in the pure-liquid phase, and the coarsening of bubbles follows. The self-similarity of the bubble-size distribution function predicted by Lifshitz-Slyozov-Wagner theory is directly confirmed. The total number of bubbles decreases asymptotically as $t^{-x}$ with scaling exponent $x$. As the initial temperature increases, the exponent changes from $x=3/2$ to $1$, which implies that the growth of bubbles changes from interface-limited (the $t^{1/2}$ law) to diffusion-limited (the $t^{1/3}$ law) growth.

  13. Ostwald ripening in multiple-bubble nuclei.

    Science.gov (United States)

    Watanabe, Hiroshi; Suzuki, Masaru; Inaoka, Hajime; Ito, Nobuyasu

    2014-12-21

    The Ostwald ripening of bubbles is studied by molecular dynamics simulations involving up to 679 × 10(6) Lennard-Jones particles. Many bubbles appear after depressurizing a system that is initially maintained in the pure-liquid phase, and the coarsening of bubbles follows. The self-similarity of the bubble-size distribution function predicted by Lifshitz-Slyozov-Wagner theory is directly confirmed. The total number of bubbles decreases asymptotically as t(-x) with scaling exponent x. As the initial temperature increases, the exponent changes from x = 3/2 to 1, which implies that the growth of bubbles changes from interface-limited (the t(1/2) law) to diffusion-limited (the t(1/3) law) growth.

  14. Curvature and bubble convergence of harmonic maps

    CERN Document Server

    Kokarev, Gerasim

    2010-01-01

    We explore geometric aspects of bubble convergence for harmonic maps. More precisely, we show that the formation of bubbles is characterised by the local excess of curvature on the target manifold. We give a universal estimate for curvature concentration masses at each bubble point and show that there is no curvature loss in the necks. Our principal hypothesis is that the target manifold is Kaehler.

  15. ACOUSTIC MEASUREMENTS BUBBLES IN BIOLOGICAL TIESSURE

    Institute of Scientific and Technical Information of China (English)

    CHAHINE Georges L.; TANGUAY Michel; LORAINE Greg

    2009-01-01

    An acoustic based instrument,the ABS Acoustic Bubble Spectrometer(R)(C)(ABS),was investigated for the detection and quantification of bubbles in biological media.These include viscoelastic media(blood),materials of varying density(bone in tissue),non-homogenous distribution of bubbles(intravenous bubbly flow),and bubbles migrating in tissue(decompression sickness,DCS).The performance of the ABS was demonstrated in a series of laboratory experiments.Validation of the code was performed using a viscoelastic polymer solution,Polyox,in which the bubble size distribution and void fraction were determined by ABS measurements and with image analysis of high speed videos.These tests showed that the accuracy of the ABS was not significantly affected by viscoelasticity for bubbles smaller than 200 microns.The ABS detection and measurement of non-homogenous bubble distributions was demonstrated using a bubbly flow through a simulated vein surrounded by tissue.The scatter of acoustic signals due to bones in the acoustic pathway was also investigated.These in-vitro experiments were done using meat(beef)as a tissue simulant.Decompression experiments were done using beef meat which was held underwater at high pressure(9.9 atm)then rapidly decompressed.Bubble size distributions and void fraction calculations in these experiments were then validated using image analysis of high speed video.In addition,preliminary experiments were performed with the US Navy Medical Research Center,demonstrating the utility of the modified ABS system in detecting the evolution of bubbles in swine undergoing decompression sickness(DCS).These results indicate that the ABS may be used to detect and quantify the evolution of bubbles in-vivo and aid in the monitoring of DCS.

  16. Binary Schemes of Vapor Bubble Growth

    Science.gov (United States)

    Zudin, Yu. B.

    2015-05-01

    A problem on spherically symmetric growth of a vapor bubble in an infi nite volume of a uniformly superheated liquid is considered. A description of the limiting schemes of bubble growth is presented. A binary inertial-thermal bubble growth scheme characterized by such specifi c features as the "three quarters" growth law and the effect of "pressure blocking" in a vapor phase is considered.

  17. Finite-Amplitude Vibration of a Bubble

    Institute of Scientific and Technical Information of China (English)

    QIAN Zu-Wen; XIAO Ling

    2003-01-01

    The Rayleigh-Plesset equation for bubble vibration is modified. The numerical solution of new equation is obtained by means of the symbolic computation programme. The acceleration of the h'quid on the surface of the bubble, or pressure in the bubble, displays much intense 8-impulse with a very short duration from ns to ps. Suggestions for developing the measurements of sonoluminescence and cavitation fusion (if any) are presented.

  18. Shock propagation in polydisperse bubbly flows

    OpenAIRE

    Ando, Keita; Colonius, Tim; Brennen, Christopher E.

    2009-01-01

    The effect of distributed bubble size on shock propagation in homogeneous bubbly liquids is computed using a continuum two-phase model. An ensemble-averaging technique is employed to derive the statistically averaged equations and a finite-volume method is used to solve the model equations. The bubble dynamics are incorporated using a Rayleigh-Plesset-type equation which includes the effects of heat transfer, liquid viscosity and compressibility. For the case of monodispe...

  19. Repairing liner of the reactor; Reparacion del liner del reactor

    Energy Technology Data Exchange (ETDEWEB)

    Aguilar H, F. [ININ, 52045 Ocoyoacac, Estado de Mexico (Mexico)

    2001-07-15

    Due to the corrosion problems of the aluminum coating of the reactor pool, a periodic inspections program by ultrasound to evaluate the advance grade and the corrosion speed was settled down. This inspections have shown the necessity to repair some areas, in those that the slimming is significant, of not making it can arrive to the water escape of the reactor pool. The objective of the repair is to place patches of plates of 1/4 inch aluminum thickness in the areas of the reactor 'liner', in those that it has been detected by ultrasound a smaller thickness or similar to 3 mm. To carry out this the fuels are move (of the core and those that are decaying) to a temporary storage, the structure of the core is confined in a tank that this placed inside the pool of the reactor, a shield is placed in the thermal column and it is completely extracted the water for to leave uncover the 'liner' of the reactor. (Author)

  20. Treatment of Wastewater Containing Heavy Metals Using Dissolved Air Released Flotation Column

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    A new type of dissolved air released flotation column is developed to treat wastewater containing Cr(Ⅵ) based on advantages of both dissolved air floatation and column floatation. By using a column with a diameter of 50 mm and a specially made dissolved air releaser, micro-bubbles inside the column can be formed. N2H4.H2O was used as reductant, AlCl3 as flocculant, C12H25SO3Na(SDS) as surfactant in the experiment. The effects of pH of wastewater, pressure of dissolved air, ratio of return water, and concentration of flocculant and surfactant on the removal efficiency are studied. The results show that the efficiency of dissolved air released flotation column is much higher than that of other approaches after the operation parameters are optimized, with the reduction ratio of Cr(Ⅵ) in wastewater reaching 98%. So this technique can be widely used in wastewater treatment.

  1. The thermodynamic and kinetic interactions of He interstitial clusters with bubbles in W

    Science.gov (United States)

    Perez, Danny; Sandoval, Luis; Uberuaga, Blas P.; Voter, Arthur F.

    2016-05-01

    Due to its enviable properties, tungsten is a leading candidate plasma facing material in nuclear fusion reactors. However, like many other metals, tungsten is known to be affected by the high doses of helium atoms incoming from the plasma. Indeed, the implanted interstitial helium atoms cluster together and, upon reaching a critical cluster size, convert into substitutional nanoscale He bubbles. These bubbles then grow by absorbing further interstitial clusters from the matrix. This process can lead to deleterious changes in microstructure, degradation of mechanical properties, and contamination of the plasma. In order to better understand the growth process, we use traditional and accelerated molecular dynamics simulations to investigate the interactions between interstitial He clusters and pre-existing bubbles. These interactions are characterized in terms of thermodynamics and kinetics. We show that the proximity of the bubble leads to an enhancement of the trap mutation rate and, consequently, to the nucleation of satellite bubbles in the neighborhood of existing ones. We also uncover a number of mechanisms that can lead to the subsequent annihilation of such satellite nanobubbles.

  2. Bubble burst as jamming phase transition

    CERN Document Server

    Nishinari, Katsuhiro; Saito, Yukiko Umeno; Watanabe, Tsutomu

    2010-01-01

    Recently research on bubble and its burst attract much interest of researchers in various field such as economics and physics. Economists have been regarding bubble as a disorder in prices. However, this research strategy has overlooked an importance of the volume of transactions. In this paper, we have proposed a bubble burst model by focusing the transactions incorporating a traffic model that represents spontaneous traffic jam. We find that the phenomenon of bubble burst shares many similar properties with traffic jam formation by comparing data taken from US housing market. Our result suggests that the transaction could be a driving force of bursting phenomenon.

  3. Living Near de Sitter Bubble Walls

    OpenAIRE

    Cho, Jin-Ho; Nam, Soonkeon

    2006-01-01

    We study various bubble solutions in string/M theories obtained by double Wick rotations of (non-)extremal brane configurations. Typically, the geometry interpolates de Sitter space-time times non-compact extra-dimensional space in the near-bubble wall region and the asymptotic flat Minkowski space-time. These bubble solutions provide nice background geometries reconciling string/M theories with de Sitter space-time. For the application of these solutions to cosmology, we consider multi-bubbl...

  4. Spectroscopic characteristic of conical bubble luminescence

    Institute of Scientific and Technical Information of China (English)

    Chen Qi-Dai; Fu Li-Min; Ai Xi-Cheng; Zhang Jian-Ping; Wang Long

    2005-01-01

    The conical bubble sonoluminescence (CBSL) from the collapse of the bubble was observed in an improved Utube apparatus. The emitted light energy of a single CBSL flash was measured to be ~ 1.4mJ. The pulse width was about 100μs. The spectra of luminescence were continuum superimposed with the spectral bands from the excitedstate C2, CN and CH. The CBSL provides a link between the light emission of the single-bubble and the multi-bubble sonoluminescence (SBSL and MBSL).

  5. Behavior of Columns During Earthquakes

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The behavior of columns during earthquakes is very important since column failures may lead to additional structural failures and result in total building collapses....

  6. Determination of Two Columns Performance

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    When protein is analyzed by high performance liquid chromatography (HPLC), the selection of column is one of the most important factors. There are four quality control parameters for the column, which are theoretical plates n, capacity facto

  7. NMFS Water Column Sonar Database

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Water column sonar data are an important component of fishery independent surveys, habitat studies and other research. NMFS water column sonar data are archived here.

  8. Flow and Heat Flux Behavior of Micro-bubble Jet Flows Observed in Thin, Twisted-Wire, Subcooled Boiling in Microgravity

    Science.gov (United States)

    Munro, Troy R.; Ban, Heng

    2015-02-01

    Thin wire, subcooled boiling experiments were performed onboard an aircraft flying a parabolic trajectory to provide microgravity conditions for improved observation of jet flow phenomena and their behavior in the absence of buoyant forces. A new type of nucleation jet flow was observed in microgravity. This new micro-bubble jet flow is seen at medium to high heat fluxes and is characterized by a region of the wire that forms multiple jet columns which contain micro-bubbles. These columns flow together and penetrate tens of millimeters into the bulk fluid. Bubble behavior on the wire was observed to progress from a dominance of larger isolated bubbles on the wire to a dominance of micro-bubble jet flows on the wire as heat flux was increased. There was also a transient transition from a few large isolated bubbles to micro-bubble jet flow dominance for a set heat flux. A cross correlation calculation provided velocities of micro-bubbles in the flow, which were in the range of 4-14 mm/s. These velocities were used with convection correlations to show that fluid flows induced by jet flows are a significant contributor to the subcooled boiling heat transfer in microgravity, but are not the primary contributor. Additionally, a relative bubble area analysis approximates the direct contribution of these jet flows to the overall heat dissipation. These micro-bubble jet flows, which are only observed on thin wires (not flat surfaces), and the convection currents they induce, have the potential to allow for sustained fluid motion to occur in microgravity.

  9. Interaction of a bubble and a bubble cluster in an ultrasonic field

    Institute of Scientific and Technical Information of China (English)

    Wang Cheng-Hui; Cheng Jian-Chun

    2013-01-01

    Using an appropriate approximation,we have formulated the interacting equation of multi-bubble motion for a system of a single bubble and a spherical bubble cluster.The behavior of the bubbles is observed in coupled and uncoupled states.The oscillation of bubbles inside the cluster is in a coupled state.The numerical simulation demonstrates that the secondary Bjerknes force can be influenced by the number density,initial radius,distance,driving frequency,and amplitude of ultrasound.However,if a bubble approaches a bubble cluster of the same initial radii,coupled oscillation would be induced and a repulsive force is evoked,which may be the reason why the bubble cluster can exist steadily.With the increment of the number density of the bubble cluster,a secondary Bjerknes force acting on the bubbles inside the cluster decreases due to the strong suppression of the coupled bubbles.It is shown that there may be an optimal number density for a bubble cluster which can generate an optimal cavitation effect in liquid for a stable driving ultrasound.

  10. DGP with bubble of nothing

    CERN Document Server

    Izumi, Keisuke

    2014-01-01

    We construct exact solutions with the bubble of nothing in the Dvali-Gabadadze-Porrati(DGP) braneworld model. The configuration with a single brane can be constructed, unlike in the Randall-Sundrum braneworld model. The geometry on the single brane looks like the Einstein-Rosen bridge. We also discuss the junction of multi branes. Surprisingly, even without any artificial matter fields on the branes such as three dimensional tension of the codimension two objects, two branes can be connected in certain configurations. We investigate solutions of multi branes too. The presence of solutions may indicate the semiclassical instability of the models.

  11. Magma mixing enhanced by bubble segregation

    Directory of Open Access Journals (Sweden)

    S. Wiesmaier

    2015-04-01

    Full Text Available That rising bubbles may significantly affect magma mixing paths has already been demon strated by analogue experiments. Here, for the first time, bubble-advection experiments are performed employing volcanic melts at magmatic temperatures. Cylinders of basaltic glass were placed below cylinders of rhyolite glass. Upon melting, interstitial air formed bubbles that rose into the rhyolite melt, thereby entraining tails of basaltic liquid. The formation of plume-like filaments of advected basalt within the rhyolite was characterized by microCT and subsequent high-resolution EMP analyses. Melt entrainment by bubble ascent appears to be an efficient mechanism for mingling volcanic melts of highly contrasting compositions and properties. MicroCT imaging reveals bubbles trailing each other and multiple filaments coalescing into bigger ones. Rheological modelling of the filaments yields viscosities of up to 2 orders of magnitude lower than for the surrounding rhyolitic liquid. Such a viscosity contrast implies that bubbles rising successively are likely to follow this pathway of low resistance that previously ascending bubbles have generated. Filaments formed by multiple bubbles would thus experience episodic replenishment with mafic material. Inevitable implications for the concept of bubble advection in magma mixing include thereby both an acceleration of mixing because of decreased viscous resistance for bubbles inside filaments and non-conventional diffusion systematics because of intermittent supply of mafic material (instead of a single pulse inside a material. Inside the filaments, the mafic material was variably hybridised to andesitic through rhyolitic composition. Compositional profiles alone are ambiguous, however, to determine whether single or multiple bubbles were involved during formation of a filament. Statistical analysis, employing concentration variance as measure of homogenisation, demonstrates that also filaments appearing as single-bubble

  12. Neural basis of economic bubble behavior.

    Science.gov (United States)

    Ogawa, A; Onozaki, T; Mizuno, T; Asamizuya, T; Ueno, K; Cheng, K; Iriki, A

    2014-04-18

    Throughout human history, economic bubbles have formed and burst. As a bubble grows, microeconomic behavior ceases to be constrained by realistic predictions. This contradicts the basic assumption of economics that agents have rational expectations. To examine the neural basis of behavior during bubbles, we performed functional magnetic resonance imaging while participants traded shares in a virtual stock exchange with two non-bubble stocks and one bubble stock. The price was largely deflected from the fair price in one of the non-bubble stocks, but not in the other. Their fair prices were specified. The price of the bubble stock showed a large increase and battering, as based on a real stock-market bust. The imaging results revealed modulation of the brain circuits that regulate trade behavior under different market conditions. The premotor cortex was activated only under a market condition in which the price was largely deflected from the fair price specified. During the bubble, brain regions associated with the cognitive processing that supports order decisions were identified. The asset preference that might bias the decision was associated with the ventrolateral prefrontal cortex and the dorsolateral prefrontal cortex (DLPFC). The activity of the inferior parietal lobule (IPL) was correlated with the score of future time perspective, which would bias the estimation of future price. These regions were deemed to form a distinctive network during the bubble. A functional connectivity analysis showed that the connectivity between the DLPFC and the IPL was predominant compared with other connectivities only during the bubble. These findings indicate that uncertain and unstable market conditions changed brain modes in traders. These brain mechanisms might lead to a loss of control caused by wishful thinking, and to microeconomic bubbles that expand, on the macroscopic scale, toward bust.

  13. Sonochemical Reactors.

    Science.gov (United States)

    Gogate, Parag R; Patil, Pankaj N

    2016-10-01

    Sonochemical reactors are based on the generation of cavitational events using ultrasound and offer immense potential for the intensification of physical and chemical processing applications. The present work presents a critical analysis of the underlying mechanisms for intensification, available reactor configurations and overview of the different applications exploited successfully, though mostly at laboratory scales. Guidelines have also been presented for optimum selection of the important operating parameters (frequency and intensity of irradiation, temperature and liquid physicochemical properties) as well as the geometric parameters (type of reactor configuration and the number/position of the transducers) so as to maximize the process intensification benefits. The key areas for future work so as to transform the successful technique at laboratory/pilot scale into commercial technology have also been discussed. Overall, it has been established that there is immense potential for sonochemical reactors for process intensification leading to greener processing and economic benefits. Combined efforts from a wide range of disciplines such as material science, physics, chemistry and chemical engineers are required to harness the benefits at commercial scale operation.

  14. Micro-bubble emission boiling with the cavitation bubble blow pit

    Science.gov (United States)

    Inada, Shigeaki; Shinagawa, Kazuaki; Illias, Suhaimi Bin; Sumiya, Hiroyuki; Jalaludin, Helmisyah A.

    2016-09-01

    The miniaturization boiling (micro-bubble emission boiling [MEB]) phenomenon, with a high heat removal capacity that contributes considerably to the cooling of the divertor of the nuclear fusion reactor, was discovered in the early 1980s. Extensive research on MEB has been performed since its discovery. However, the progress of the application has been delayed because the generation mechanism of MEB remains unclear. Reasons for this lack of clarity include the complexity of the phenomenon itself and the high-speed phase change phenomenon in which boiling and condensation are rapidly generated. In addition, a more advanced thermal technique is required to realize the MEB phenomenon at the laboratory scale. To the authors’ knowledge, few studies have discussed the rush mechanism of subcooled liquid to the heating surface, which is critical to elucidating the mechanism behind MEB. This study used photographic images to verify that the cavitation phenomenon spreads to the inside of the superheated liquid on the heating surface and thus clarify the mechanism of MEB.

  15. Micro-bubble emission boiling with the cavitation bubble blow pit

    Science.gov (United States)

    Inada, Shigeaki; Shinagawa, Kazuaki; Illias, Suhaimi Bin; Sumiya, Hiroyuki; Jalaludin, Helmisyah A.

    2016-01-01

    The miniaturization boiling (micro-bubble emission boiling [MEB]) phenomenon, with a high heat removal capacity that contributes considerably to the cooling of the divertor of the nuclear fusion reactor, was discovered in the early 1980s. Extensive research on MEB has been performed since its discovery. However, the progress of the application has been delayed because the generation mechanism of MEB remains unclear. Reasons for this lack of clarity include the complexity of the phenomenon itself and the high-speed phase change phenomenon in which boiling and condensation are rapidly generated. In addition, a more advanced thermal technique is required to realize the MEB phenomenon at the laboratory scale. To the authors’ knowledge, few studies have discussed the rush mechanism of subcooled liquid to the heating surface, which is critical to elucidating the mechanism behind MEB. This study used photographic images to verify that the cavitation phenomenon spreads to the inside of the superheated liquid on the heating surface and thus clarify the mechanism of MEB. PMID:27628271

  16. Column: Every Last Byte

    Directory of Open Access Journals (Sweden)

    Simson Garfinkel

    2011-06-01

    Full Text Available Inheritance powder is the name that was given to poisons, especially arsenic, that were commonly used in the 17th and early 18th centuries to hasten the death of the elderly. For most of the 17th century, arsenic was deadly but undetectable, making it nearly impossible to prove that someone had been poisoned. The first arsenic test produced a gas—hardly something that a scientist could show to a judge. Faced with a growing epidemic of poisonings, doctors and chemists spent decades searching for something better.(see PDF for full column

  17. Modified Bubble Core Fields and Bubble Shape in Laser Driven Plasma

    Institute of Scientific and Technical Information of China (English)

    WU Hai-Cheng; XIE Bai-Song

    2013-01-01

    Bubble core fields as well bubble shape modification due to the nondepleted electrons inside the bubble is investigated theoretically.It is found that the slope of transverse fields are reduced significantly,however,the slope of longitudinal electric field,which plays a key role on electrons acceleration in bubble,changes little.Moreover a modified longitudinal compressed bubble shape leads to a shorter dephasing distance which makes the electrons acceleration energy reduced to some extent.As a comparison we perform particle-in-cell simulations whose results are consistent with that of our theoretical consideration.

  18. Nonlinear Bubble Dynamics And The Effects On Propagation Through Near-Surface Bubble Layers

    Science.gov (United States)

    Leighton, Timothy G.

    2004-11-01

    Nonlinear bubble dynamics are often viewed as the unfortunate consequence of having to use high acoustic pressure amplitudes when the void fraction in the near-surface oceanic bubble layer is great enough to cause severe attenuation (e.g. >50 dB/m). This is seen as unfortunate since existing models for acoustic propagation in bubbly liquids are based on linear bubble dynamics. However, the development of nonlinear models does more than just allow quantification of the errors associated with the use of linear models. It also offers the possibility of propagation modeling and acoustic inversions which appropriately incorporate the bubble nonlinearity. Furthermore, it allows exploration and quantification of possible nonlinear effects which may be exploited. As a result, high acoustic pressure amplitudes may be desirable even in low void fractions, because they offer opportunities to gain information about the bubble cloud from the nonlinearities, and options to exploit the nonlinearities to enhance communication and sonar in bubbly waters. This paper presents a method for calculating the nonlinear acoustic cross-sections, scatter, attenuations and sound speeds from bubble clouds which may be inhomogeneous. The method allows prediction of the time dependency of these quantities, both because the cloud may vary and because the incident acoustic pulse may have finite and arbitrary time history. The method can be readily adapted for bubbles in other environments (e.g. clouds of interacting bubbles, sediments, structures, in vivo, reverberant conditions etc.). The possible exploitation of bubble acoustics by marine mammals, and for sonar enhancement, is explored.

  19. Interaction of cavitation bubbles on a wall

    NARCIS (Netherlands)

    Bremond, Nicolas; Arora, Manish; Dammer, Stephan M.; Lohse, Detlef

    2006-01-01

    We report experimental and numerical investigations on the dynamics of the cavitation of bubbles on a solid surface and the interaction between them with the help of controlled cavitation nuclei: hemispherical bubbles are nucleated from hydrophobic microcavities that act as gas traps when the substr

  20. Structure of nanoscale gas bubbles in metals

    Energy Technology Data Exchange (ETDEWEB)

    Caro, A., E-mail: caro@lanl.gov; Schwen, D.; Martinez, E. [Materials Science and Technology Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87544 (United States)

    2013-11-18

    A usual way to estimate the amount of gas in a bubble inside a metal is to assume thermodynamic equilibrium, i.e., the gas pressure P equals the capillarity force 2γ/R, with γ the surface energy of the host material and R the bubble radius; under this condition there is no driving force for vacancies to be emitted or absorbed by the bubble. In contrast to the common assumption that pressure inside a gas or fluid bubble is constant, we show that at the nanoscale this picture is no longer valid. P and density can no longer be defined as global quantities determined by an equation of state (EOS), but they become functions of position because the bubble develops a core-shell structure. We focus on He in Fe and solve the problem using both continuum mechanics and empirical potentials to find a quantitative measure of this effect. We point to the need of redefining an EOS for nanoscale gas bubbles in metals, which can be obtained via an average pressure inside the bubble. The resulting EOS, which is now size dependent, gives pressures that differ by a factor of two or more from the original EOS for bubble diameters of 1 nm and below.

  1. The Physics of Foams, Droplets and Bubbles

    Science.gov (United States)

    Sarker, Dipak K.

    2013-01-01

    Foams or bubble dispersions are common to milkshakes, bread, champagne froth, shaving mousse, shampoo, crude oil extraction systems, upholstery packing and bubble wrap, whereas the term droplet is often synonymous with either a small drop of water or a drop of oil--a type of coarse dispersion. The latter are seen in butter and milk, household…

  2. Laminar separation bubbles: Dynamics and control

    Indian Academy of Sciences (India)

    Sourabh S Diwan; O N Ramesh

    2007-02-01

    This work is an experimental investigation of the dynamics and control of the laminar separation bubbles which are typically present on the suction surface of an aerofoil at a large angle of attack. A separation bubble is produced on the upper surface of a flat plate by appropriately contouring the top wall of the wind tunnel. First, a basic (unforced) separation bubble is obtained to set a benchmark for further experiments. Parametric study is done where the reference velocity is decreased to quantify its effect on the aspect ratio of the bubble. It is found that with decrease in Reynolds number, the height of the bubble increases at a greater rate than the length. This feature could be useful in characterising separation bubbles especially from the point of view of low Reynolds number aerofoil design. Artificial disturbance is introduced at two different initial amplitudes (infinitesimal and finite) upstream of separation location and hotwire anemometry is used to trace the wave packet as it is advected downstream. The evolution of wave packets is seen to take place in two distinct stages. Finite amplitude forcing causes periodic quenching of the bubble. Interestingly, even an infinitesimally small forcing is seen to modify and thereby control the separation bubble.

  3. Steady State Vapor Bubble in Pool Boiling

    Science.gov (United States)

    Zou, An; Chanana, Ashish; Agrawal, Amit; Wayner, Peter C.; Maroo, Shalabh C.

    2016-02-01

    Boiling, a dynamic and multiscale process, has been studied for several decades; however, a comprehensive understanding of the process is still lacking. The bubble ebullition cycle, which occurs over millisecond time-span, makes it extremely challenging to study near-surface interfacial characteristics of a single bubble. Here, we create a steady-state vapor bubble that can remain stable for hours in a pool of sub-cooled water using a femtosecond laser source. The stability of the bubble allows us to measure the contact-angle and perform in-situ imaging of the contact-line region and the microlayer, on hydrophilic and hydrophobic surfaces and in both degassed and regular (with dissolved air) water. The early growth stage of vapor bubble in degassed water shows a completely wetted bubble base with the microlayer, and the bubble does not depart from the surface due to reduced liquid pressure in the microlayer. Using experimental data and numerical simulations, we obtain permissible range of maximum heat transfer coefficient possible in nucleate boiling and the width of the evaporating layer in the contact-line region. This technique of creating and measuring fundamental characteristics of a stable vapor bubble will facilitate rational design of nanostructures for boiling enhancement and advance thermal management in electronics.

  4. Simple improvements to classical bubble nucleation models

    Science.gov (United States)

    Tanaka, Kyoko K.; Tanaka, Hidekazu; Angélil, Raymond; Diemand, Jürg

    2015-08-01

    We revisit classical nucleation theory (CNT) for the homogeneous bubble nucleation rate and improve the classical formula using a correct prefactor in the nucleation rate. Most of the previous theoretical studies have used the constant prefactor determined by the bubble growth due to the evaporation process from the bubble surface. However, the growth of bubbles is also regulated by the thermal conduction, the viscosity, and the inertia of liquid motion. These effects can decrease the prefactor significantly, especially when the liquid pressure is much smaller than the equilibrium one. The deviation in the nucleation rate between the improved formula and the CNT can be as large as several orders of magnitude. Our improved, accurate prefactor and recent advances in molecular dynamics simulations and laboratory experiments for argon bubble nucleation enable us to precisely constrain the free energy barrier for bubble nucleation. Assuming the correction to the CNT free energy is of the functional form suggested by Tolman, the precise evaluations of the free energy barriers suggest the Tolman length is ≃0.3 σ independently of the temperature for argon bubble nucleation, where σ is the unit length of the Lennard-Jones potential. With this Tolman correction and our prefactor one gets accurate bubble nucleation rate predictions in the parameter range probed by current experiments and molecular dynamics simulations.

  5. Interacting bubble clouds and their sonochemical production

    NARCIS (Netherlands)

    Stricker, L.; Dollet, B.; Fernandez Rivas, D.; Lohse, D.

    2013-01-01

    An acoustically driven air pocket trapped in a pit etched on a surface can emit a bubble cluster. When several pits are present, the resulting bubble clusters interact in a nontrivial way. Fernández Rivas et al. [Angew. Chem. Int. Ed. 49, 9699–9701 (2010)] observed three different behaviors at incre

  6. Probing luminescence from nonspherical bubble collapse

    NARCIS (Netherlands)

    Ohl, Claus-Dieter

    2002-01-01

    The luminescence from single laser produced cavitation bubbles for varying degrees of asphericity is investigated temporally, spatially, and spectrally. The degree of asphericity is controlled with an adjustable rigid boundary near the bubble. Temporally, single and multiple light emission events ha

  7. Galactic Teamwork Makes Distant Bubbles

    Science.gov (United States)

    Kohler, Susanna

    2016-03-01

    During the period of reionization that followed the dark ages of our universe, hydrogen was transformed from a neutral state, which is opaque to radiation, to an ionized one, which is transparent to radiation. But what generated the initial ionizing radiation? The recent discovery of multiple distant galaxies offers evidence for how this process occurred.Two Distant GalaxiesWe believe reionization occurred somewhere between a redshift of z = 6 and 7, because Ly-emitting galaxies drop out at roughly this redshift. Beyond this distance, were generally unable to see the light from these galaxies, because the universe is no longer transparent to their emission. This is not always the case, however: if a bubble of ionized gas exists around a distant galaxy, the radiation can escape, allowing us to see the galaxy.This is true of two recently-discovered Ly-emitting galaxies, confirmed to be at a redshift of z~7 and located near one another in a region known as the Bremer Deep Field. The fact that were able to see the radiation from these galaxies means that they are in an ionized HII region presumably one of the earlier regions to have become reionized in the universe.But on their own, neither of these galaxies is capable of generating an ionized bubble large enough for their light to escape. So what ionized the region around them, and what does this mean for our understanding of how reionization occurred in the universe?A Little Help From FriendsLocation in different filters of the objects in the Hubble Bremer Deep Field catalog. The z~7 selection region is outlined by the grey box. BDF-521 and BDF-3299 were the two originally discovered galaxies; the remaining red markers indicate the additional six galaxies discovered in the same region. [Castellano et al. 2016]A team of scientists led by Marco Castellano (Rome Observatory, INAF) investigated the possibility that there are other, faint galaxies near these two that have helped to ionize the region. Performing a survey

  8. Tensor Effect on Bubble Nuclei

    Institute of Scientific and Technical Information of China (English)

    WANG Yan-Zhao; GU Jian-Zhong; ZHANG Xi-Zhen; DONG Jian-Min

    2011-01-01

    In the framework of the Hartree-Fock-Bogoliubov (HFB) approach with Skyrme interactions SLy5+T, SLy5+Tw and several sets of TIJ parametrizations, I.e. The Skyrme interaction parametrizations including the tensor terms, the proton density distribution in 34Si and 46Ar nuclei is calculated with and without the tensor force. It is shown that the bubble effect in 34Si does not depend a great deal on the Skyrme parametrization and the proton density distribution in 34Si is hardly influenced by the tensor force. As to 46Ar, the SLy5+Tw parametrization favors the formation of the bubble structure due to the inversion between the 2s1/2 and 1d3/2 orbits (2s1/2-ld3/2 inversion). The inversion mechanism induced by the SLy5+Tw interaction is analyzed based on the proton single-particle spectra obtained from the SLy5 and SLy5+Tw interactions as well as the wave functions of the 2s1/2 and 1d3/2 states.%In the framework of the Hartree-Fock-Bogoliubov (HFB) approach with Skyrme interactions SLy5+ T,SLy5+ Tω and several sets of TIJ parametrizations,i.e.the Skyrme interaction pararmetrizations including the tensor terms,the proton density distribution in 34Si and 46 Ar nuclei is calculated with and without the tensor force.It is shown that the bubble effect in 34Si does not depend a great deal on the Skyrme parametrization and the proton density distribution in 34Si is hardly influenced by the tensor force.As to 46Ar,the SLy5+ Tω parametrization favors the formation of the bubble structure due to the inversion between the 2s1/2 and 1d3/2 orbits (2s1/2-1d3/2 inversion).The inversion mechanism induced by the SLy5+ Tω interaction is analyzed based on the proton single-particle spectra obtained from the SLy5 and SLy5+ Tω interactions as well as the wave functions of the 2s1/2 and 1d3/2 states.The study of exotic nuclear structures has been a hot topic in nuclear physics.[1-4] Exotic nuclei are unstabile,superheavy nuclei,halo nuclei and so forth,whose structures are quite different

  9. Single DNA denaturation and bubble dynamics

    DEFF Research Database (Denmark)

    Metzler, Ralf; Ambjörnsson, Tobias; Hanke, Andreas

    2009-01-01

    for situations below, at, and above the denaturation transition. We also propose a new single molecule setup based on DNA constructs with two bubble zones to measure the bubble coalescence and extract the physical parameters relevant to DNA breathing. Finally we consider the interplay between denaturation......While the Watson-Crick double-strand is the thermodynamically stable state of DNA in a wide range of temperature and salt conditions, even at physiological conditions local denaturation bubbles may open up spontaneously due to thermal activation. By raising the ambient temperature, titration......, or by external forces in single molecule setups bubbles proliferate until full denaturation of the DNA occurs. Based on the Poland-Scheraga model we investigate both the equilibrium transition of DNA denaturation and the dynamics of the denaturation bubbles with respect to recent single DNA chain experiments...

  10. Oscillation of large air bubble cloud

    Energy Technology Data Exchange (ETDEWEB)

    Bae, Y.Y.; Kim, H.Y.; Park, J.K. [Korea Atomic Energy Research Inst., Daejeon (Korea, Republic of)

    2001-07-01

    The behavior of a large air bubble cloud, which is generated by the air discharged from a perforated sparger, is analyzed by solving Rayleigh-Plesset equation, energy equations and energy balance equation. The equations are solved by Runge-Kutta integration and MacCormack finite difference method. Initial conditions such as driving pressure, air volume, and void fraction strongly affect the bubble pressure amplitude and oscillation frequency. The pool temperature has a strong effect on the oscillation frequency and a negligible effect on the pressure amplitude. The polytropic constant during the compression and expansion processes of individual bubbles ranges from 1.0 to 1.4, which may be attributed to the fact that small bubbles oscillated in frequencies different from their resonance. The temperature of the bubble cloud rapidly approaches the ambient temperature, as is expected from the polytropic constants being between 1.0 and 1.4. (authors)

  11. CO observation of the Galactic bubble N4

    CERN Document Server

    Li, Junyu; Liu, Yao; Wang, Yuan

    2013-01-01

    We presented a study on the Galactic bubble N4 using the 13.7 m millimeter telescope of Purple Mountain Observatory at the Qinghai Station. N4 is one of the science demonstration regions for the Milky Way Imaging Scroll Painting (WMISP). Simultaneous observations of $^{12}$CO (J = 1$-$0), $^{13}$CO (J = 1$-$0) and C$^{18}$O (J = 1$-$0) line emission towards N4 were carried out. We analyzed the spectral profile and the distribution of the molecular gas. Morphologically, the CO emissions correlate well with Spitzer IRAC 8.0 $\\mu$m emission. The channel map and velocity-position diagram shows that N4 is more likely an inclined expanding ring than a spherical bubble. We calculated the physical parameters of N4 including the mass, size, column density and optical depth. Some massive star candidates were discovered in the region of N4 using (J, J$-$H) color-magnitude diagram. We found an energy source candidate for the expansion of N4, a massive star with a mass of ${\\sim} 15\\,M_{\\odot}$ and an age of $\\sim$ 1 Myr....

  12. CFD simulation of bubbly turbulent Tayor-Couette flow☆

    Institute of Scientific and Technical Information of China (English)

    Xi Gao; Bo Kong; R. Dennis Vigil

    2016-01-01

    Bubbly gas–liquid Taylor–Couette vortex flow has been the subject of several recent investigations both because of interest in bubble-induced drag reduction and because such devices have potential applications to a variety of chemical and biochemical processing problems. In order to quantitatively describe the hydrodynamics of highly turbulent two phase Taylor–Couette flow, a rigorous two-fluid computational fluid dynamics (CFD) model was developed and compared with previously published experimental data. This model includes a comprehensive description of the constitutive closure for inter-phase forces and turbulence was simulated using both the k–εand k–ωmodels. In addition, the mechanism by which the dispersed fluid attains a non-uniform radial and axial distribution is analyzed and the relative importance of various interphase forces is discussed. Lastly the model was validated by comparison of simulation predictions with experimental data, and it is shown that the CFD model correctly predicts phase velocity, velocity fluctuation, and gas distribution, and may provide guidance for reactor design and scale-up.

  13. Generation and characterization of gas bubbles in liquid metals

    Energy Technology Data Exchange (ETDEWEB)

    Eckert, S.; Gerbeth, G.; Witke, W.

    1996-06-01

    There is an ongoing research performed in the RCR on local transport phenomena in turbulent liquid metal (LM) duct flows exposed to external magnetic fields. In this context so-called MHD flow phenomena can be observed, which are unknown in usual hydraulic engineering. The field of interest covers also the influence of magnetic fields on the behaviour of liquid metal - gas mixtures. Profound knowledge on these LMMHD two-phase flow plays an important role in a variety of technological applications, in particular, in the design of Liquid-Metal MHD generators or for several metallurgical processes employing gas-stirred reactors. However, the highly empirical nature of two-phase flow analysis gives little hope for the prediction of MHD two-phase flows without extensive experimental data. A summary is given about the authors research activities focussing on two directions: (a) Momentum transfer between gas and liquid metal in a bubbly flow regime to investigate the influence of the external magnetic field on the velocity slip ration S (b) Peculiarities of the MHD turbulence to use small gas bubbles as local tracers in order to study the turbulent mass transfer.

  14. Externally triggered renewed bubble nucleation in basaltic magma: the 12 October 2008 eruption at Halema‘uma‘u Overlook vent, Kīlauea, Hawai‘i, USA

    Science.gov (United States)

    Carey, Rebecca J.; Manga, Michael; Degruyter, Wim; Swanson, Donald; Houghton, Bruce; Orr, Tim R.; Patrick, Matthew R.

    2012-01-01

    From October 2008 until present, dozens of small impulsive explosive eruptions occurred from the Overlook vent on the southeast side of Halema‘uma‘u Crater, at Kīlauea volcano, USA. These eruptions were triggered by rockfalls from the walls of the volcanic vent and conduit onto the top of the lava column. Here we use microtextural observations and data from clasts erupted during the well-characterized 12 October 2008 explosive eruption at Halema‘uma‘u to extend existing models of eruption triggering. We present a potential mechanism for this eruption by combining microtextural observations with existing geophysical and visual data sets. We measure the size and number density of bubbles preserved in juvenile ejecta using 2D images and X-ray microtomography. Our data suggest that accumulations of large bubbles with diameters of >50μm to at least millimeters existed at shallow levels within the conduit prior to the 12 October 2008 explosion. Furthermore, a high number density of small bubbles <50 μm is measured in the clasts, implying very rapid nucleation of bubbles. Visual observations, combined with preexisting geophysical data, suggest that the impact of rockfalls onto the magma free surface induces pressure changes over short timescales that (1) nucleated new additional bubbles in the shallow conduit leading to high number densities of small bubbles and (2) expanded the preexisting bubbles driving upward acceleration. The trigger of eruption and bubble nucleation is thus external to the degassing system.

  15. Gas bubble dynamics in soft materials.

    Science.gov (United States)

    Solano-Altamirano, J M; Malcolm, John D; Goldman, Saul

    2015-01-01

    Epstein and Plesset's seminal work on the rate of gas bubble dissolution and growth in a simple liquid is generalized to render it applicable to a gas bubble embedded in a soft elastic solid. Both the underlying diffusion equation and the expression for the gas bubble pressure were modified to allow for the non-zero shear modulus of the medium. The extension of the diffusion equation results in a trivial shift (by an additive constant) in the value of the diffusion coefficient, and does not change the form of the rate equations. But the use of a generalized Young-Laplace equation for the bubble pressure resulted in significant differences on the dynamics of bubble dissolution and growth, relative to an inviscid liquid medium. Depending on whether the salient parameters (solute concentration, initial bubble radius, surface tension, and shear modulus) lead to bubble growth or dissolution, the effect of allowing for a non-zero shear modulus in the generalized Young-Laplace equation is to speed up the rate of bubble growth, or to reduce the rate of bubble dissolution, respectively. The relation to previous work on visco-elastic materials is discussed, as is the connection of this work to the problem of Decompression Sickness (specifically, "the bends"). Examples of tissues to which our expressions can be applied are provided. Also, a new phenomenon is predicted whereby, for some parameter values, a bubble can be metastable and persist for long times, or it may grow, when embedded in a homogeneous under-saturated soft elastic medium.

  16. Investigation of The Bubble Foam Separation Technique To Extract Protein From Whey

    Directory of Open Access Journals (Sweden)

    Mohammed Matouq

    2008-01-01

    Full Text Available Separation of proteins from whey; namely α- Lactoglobulin and β-Lactalbumin was obtained using the bubble foam column technique. Two types of whey were conducted in this study; yogurt whey and cheese whey. The effect of gas flow-rate and the height of the whey (liquid holdup inside the column were studied at room temperature and at constant pH of whey. Whey used here obtained from local dairy factory as waste, and was used to investigate the performance ability of bubble column to extract very low concentration portion from waste. Enrichment ratio showed that the possibility of extracting protein from whey was high. Results showed that enrichment ration was higher for yogurt whey from that of cheese whey. The results also showed that the efficiency of separation of these proteins increased with decreasing both the air flow-rate, and wheys volume inside the column. The maximum amount of protein obtained at air flow-rate = 0.2 Liter/ min at experimental condition.

  17. Doppler method leak detection for LMFBR steam generators. Pt. 1. Experimental results of bubble detection using small models

    Energy Technology Data Exchange (ETDEWEB)

    Kumagai, Hiromichi [Central Research Inst. of Electric Power Industry, Komae, Tokyo (Japan). Komae Research Lab

    1999-05-01

    To prevent the expansion of the tube damage and to maintain structural integrity in the steam generators (SGs) of fast breeder reactors (FBRs), it is necessary to detect precisely and immediately the leakage of water from heat transfer tubes. Therefore, an active acoustic method was developed. Previous studies have revealed that in practical steam generators the active acoustic method can detect bubbles of 10 l/s within 10 seconds. To prevent the expansion of damage to neighboring tubes, it is necessary to detect smaller leakages of water from the heat transfer tubes. The Doppler method is designed to detect small leakages and to find the source of the leak before damage spreads to neighboring tubes. To evaluate the relationship between the detection sensitivity of the Doppler method and the bubble volume and bubble size, the structural shapes and bubble flow conditions were investigated experimentally, using a small structural model. The results show that the Doppler method can detect the bubbles under bubble flow conditions, and it is sensitive enough to detect small leakages within a short time. The doppler method thus has strong potential for the detection of water leakage in SGs. (author)

  18. Method for enhancing selectivity and recovery in the fractional flotation of particles in a flotation column

    Energy Technology Data Exchange (ETDEWEB)

    Klunder, Edgar B. (Bethel Park, PA)

    2011-08-09

    The method relates to particle separation from a feed stream. The feed stream is injected directly into the froth zone of a vertical flotation column in the presence of a counter-current reflux stream. A froth breaker generates a reflux stream and a concentrate stream, and the reflux stream is injected into the froth zone to mix with the interstitial liquid between bubbles in the froth zone. Counter-current flow between the plurality of bubbles and the interstitial liquid facilitates the attachment of higher hydrophobicity particles to bubble surfaces as lower hydrophobicity particles detach. The height of the feed stream injection and the reflux ratio may be varied in order to optimize the concentrate or tailing stream recoveries desired based on existing operating conditions.

  19. European Analytical Column

    DEFF Research Database (Denmark)

    Karlberg, B.; Grasserbauer, M.; Andersen, Jens Enevold Thaulov

    2009-01-01

    The European Analytical Column has once more invited a guest columnist to give his views on various matters related to analytical chemistry in Europe. This year, we have invited Professor Manfred Grasserbauer of the Vienna University of Technology to present some of the current challenges...... for European analytical chemistry. During the period 2002–07, Professor Grasserbauer was Director of the Institute for Environment and Sustainability, Joint Research Centre of the European Commission (EC), Ispra, Italy. There is no doubt that many challenges exist at the present time for all of us representing...... a major branch of chemistry, namely analytical chemistry. The global financial crisis is affecting all branches of chemistry, but analytical chemistry, in particular, since our discipline by tradition has many close links to industry. We have already noticed decreased industrial commitment with respect...

  20. Column: File Cabinet Forensics

    Directory of Open Access Journals (Sweden)

    Simson Garfinkel

    2011-12-01

    Full Text Available Researchers can spend their time reverse engineering, performing reverse analysis, or making substantive contributions to digital forensics science. Although work in all of these areas is important, it is the scientific breakthroughs that are the most critical for addressing the challenges that we face.Reverse Engineering is the traditional bread-and-butter of digital forensics research. Companies like Microsoft and Apple deliver computational artifacts (operating systems, applications and phones to the commercial market. These artifacts are bought and used by billions. Some have evil intent, and (if society is lucky, the computers end up in the hands of law enforcement. Unfortunately the original vendors rarely provide digital forensics tools that make their systems amenable to analysis by law enforcement. Hence the need for reverse engineering.(see PDF for full column