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Sample records for bridge minneapolis mn

  1. Demonstration Assessment of Light-Emitting Diode (LED) Roadway Lighting at the I-35W Bridge, Minneapolis, MN

    Energy Technology Data Exchange (ETDEWEB)

    Kinzey, Bruce R.; Myer, Michael

    2009-08-31

    This report describes the process and results of a demonstration of solid-state lighting (SSL) technology conducted in 2009 at the recently reconstructed I-35W bridge in Minneapolis, MN. The project was supported under the U.S. Department of Energy (DOE) Solid-State Lighting GATEWAY Technology Demonstration Program. Other participants in the demonstration project included the Minnesota Department of Transportation (Mn/DOT), Federal Highways Administration (FHWA), and BetaLED™ (a division of Ruud Lighting). Pacific Northwest National Laboratory (PNNL) conducted the measurements and analysis of the results. DOE has implemented a three-year evaluation of the LED luminaires in this installation in order to develop new longitudinal field data on LED performance in a challenging, real-world environment. This document provides information through the initial phase of the I-35W bridge project, up to and including the opening of the bridge to the public and the initial feedback received on the LED lighting installation from bridge users. Initial findings of the evaluation are favorable, with minimum energy savings level of 13% for the LED installation relative to the simulated base case using 250W high-pressure sodium (HPS) fixtures. The LEDs had an average illuminance level of 0.91 foot candles compared to 1.29 fc for the HPS lamps. The LED luminaires cost $38,000 more than HPS lamps, yielding a lengthy payback period, however the bridge contractor had offered to include the LED luminaires as part of the construction package at no additional cost. One potentially significant benefit of the LEDs in this installation is avoiding rolling lane closures on the heavily-traveled interstate bridge for the purpose of relamping the HPS fixtures. Rolling lane closures involve multiple crew members and various maintenance and safety vehicles, diversion of traffic, as well as related administrative tasks (e.g., approvals, scheduling, etc.). Mn/DOT records show an average cost of

  2. 78 FR 31628 - Environmental Impact Statement for the Milwaukee, WI to Minneapolis, MN Rail Corridor

    Science.gov (United States)

    2013-05-24

    ... Procedures for Considering Environmental Impacts (64 FR 28545; May 26, 1999). FRA and MnDOT will use a tiered... Federal Railroad Administration Environmental Impact Statement for the Milwaukee, WI to Minneapolis, MN... be prepared for the Milwaukee, WI to Minneapolis-St. Paul, MN (Milwaukee-Twin Cities) High-Speed...

  3. EnviroAtlas - Minneapolis/St. Paul, MN - EnviroAtlas Community Boundary

    Data.gov (United States)

    U.S. Environmental Protection Agency — This EnviroAtlas dataset shows the boundary of the Minneapolis/St. Paul, MN EnviroAtlas Community. It represents the outside edge of all the block groups included in...

  4. Long-term Testing Results for the 2008 Installation of LED Luminaires at the I-35 West Bridge in Minneapolis

    Energy Technology Data Exchange (ETDEWEB)

    Kinzey, Bruce R.; Davis, Robert G.

    2014-09-30

    This document reports the long-term testing results from an extended GATEWAY project that was first reported in “Demonstration Assessment of Light-Emitting Diode (LED) Roadway Lighting at the I-35W Bridge, in Minneapolis, MN,” August 2009. That original report presented the results of lighting the newly reconstructed I 35W Bridge using LEDs in place of conventional high-pressure sodium (HPS) roadway luminaires, comparing energy use and illuminance levels with a simulated baseline condition. That installation was an early stage implementation of LED lighting and remains one of the oldest installations in continued operation today. This document provides an update of the LED system’s performance since its installation in September 2008.

  5. EnviroAtlas - Minneapolis/St. Paul, MN - One Meter Resolution Urban Area Land Cover Map (MULC) (2010)

    Data.gov (United States)

    U.S. Environmental Protection Agency — The Minneapolis-St. Paul, MN EnviroAtlas Meter-scale Urban Land Cover (MULC) data were generated from four-band (red, green, blue, and near infrared) aerial...

  6. Demonstration Assessment of Light-Emitting Diode (LED) Roadway Lighting, I-35W Bridge, Minneapolis, Minnesota, Phase I Report

    Energy Technology Data Exchange (ETDEWEB)

    Kinzey, B. R. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Myer, M. A. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2009-08-01

    On the I-35W Bridge in Minneapolis, Minnesota, the GATEWAY program conducted a two-phase demonstration of LED roadway lighting on the main span, which is one of the country's oldest continuously operated exterior LED lighting installations. The Phase I report provides an overview of initial project results including lighting performance, economic performance, and potential energy savings.

  7. Demonstration Assessment of Light-Emitting Diode (LED) Roadway Lighting, I-35W Bridge, Minneapolis, Minnesota, Phase II Report

    Energy Technology Data Exchange (ETDEWEB)

    Kinzey, B. R. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Davis, R. G. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2014-09-30

    On the I-35W Bridge in Minneapolis, Minnesota, the GATEWAY program conducted a two-phase demonstration of LED roadway lighting on the main span, which is one of the country's oldest continuously operated exterior LED lighting installations. The Phase II report documents longer-term performance of the LED lighting system that was installed in 2008, and is the first report on the longer-term performance of LED lighting in the field.

  8. EnviroAtlas - Minneapolis/St. Paul, MN - BenMAP Results by Block Group

    Data.gov (United States)

    U.S. Environmental Protection Agency — This EnviroAtlas dataset demonstrates the effect of changes in pollution concentration on local populations in 1,772 block groups in Minneapolis/St. Paul, Minnesota....

  9. EnviroAtlas - Minneapolis/St. Paul, MN - Ecosystem Services by Block Group

    Data.gov (United States)

    U.S. Environmental Protection Agency — This EnviroAtlas dataset presents environmental benefits of the urban forest in 1,772 block groups in Minneapolis/St. Paul, Minnesota. Carbon attributes, temperature...

  10. The I-35W bridge Project Website

    DEFF Research Database (Denmark)

    Kampf, Constance

    How can websites be used to rebuild trust?  In August 2007, the Interstate Highway 35-W bridge in Minneapolis, MN collapsed during rush hour.  Although many people were rescued and casualties were as limited as could be expected due to quick and effective intervention, the image of a major bridge...... collapsing during rush hour damaged the Minnesota Department of Transportation's reputation and resulted in the loss of public trust for the organization.  The ensuing bridge reconstruction project included a project website intended to rebuild this trust through transparency, community involvement......, and the use of multimodal features.  This paper looks at the I35-W bridge reconstruction project in Minneapolis through web-based communication by the Minnesota Department of Transportation (MnDOT) about the project. The MnDOT bridge reconstruction website will be examined using a combination of 1). Weick...

  11. Minneapolis and Saint Paul, Minnesota: Solar in Action (Brochure)

    Energy Technology Data Exchange (ETDEWEB)

    2011-10-01

    This brochure provides an overview of the challenges and successes of Minneapolis, MN, a 2008 Solar America City awardee, on the path toward becoming a solar-powered community. Accomplishments, case studies, key lessons learned, and local resource information are given.

  12. New 4-carboxylphthalhydrazidate-bridged Mn2+/In3+ coordination polymers

    Science.gov (United States)

    Jin, Juan; Yan, Wen-Fu; Yu, Xiao-Yang; Yang, Qing-Feng; Liu, Bing; Xu, Ji-Qing; Gao, Shan-Min; Li, Chuan-Zhao; Lin, Chen

    2017-04-01

    Based on the hydrothermal in situ acylation reaction of benzene-1,2,4-tricarboxylic acid (btca) with N2H4·H2O, two containing-4-carboxylphthalhydrazidate Mn2+/In3+ coordination polymers, [Mn(cpth)(phen)] 1 and [In(cpth)(ox)0.5(phen)]·H2O 2 (cpth = 4-carboxylphthalhydrazidate, phen = 1,10-phenanthroline, ox = oxalate), were obtained and characterized by elemental analysis, IR spectroscopy, X-ray powder diffraction (XRD), thermogravimetric analysis (TGA), and single-crystal X-ray diffraction. In compound 1, the cpth ligands exhibit a μ4-bridging mode, which link Mn(II) centers into a 2-D layer structure with ancillary phen molecules. In compound 2, the cpth ligands exhibit a μ2-bridging mode, which link In(III) centers into a binuclear unit. Ox ligands act as the second linkers, extending binuclear unit into a 1-D chain with ancillary phen molecules. Via Nsbnd H⋯O interactions, compound 2 self-assembles into a 2-D supramolecular layer. The magnetic analysis indicates that there exists antiferromagnetic interactions between magnetic centers in compound 1. The photoluminescence properties of compounds 1 and 2 were also investigated in an aqueous solution.

  13. Cyanide- and phenoxo-bridged heterobimetallic Fe(III)-Mn(III) complexes: Synthesis, crystal structures and magnetic properties

    Indian Academy of Sciences (India)

    Daopeng Zhang; Ping Wang; Kexun Chen; Xia Chen

    2014-11-01

    By employing two -tricyanidoiron(III) precursors [Ph4P][FeIII(pcq)(CN)3] and [Ph4P][FeIII (pzq)(CN)3] as building blocks and a salen-tpye Schiff-basemanganese (III) compound as assembling segment, two tetranuclear cyanide- and phenoxo- bridged heterobimetallic Fe(III)-Mn(III) complexes {[Mn(saltmen)] [Fe(pcq)(CN)3]}2·2CH3OH (1) and {[Mn(saltmen)] [Fe(pzq)(CN)3]}2·2CH3OH (2) (pcq = 8-(pyridine-2-carboxamido, pzq = 8-(pyrazine-2-carboxamido, saltmen2− = N,N′-(1,1,2,2-tetramethylethylene)bis(salicylideneaminato) dianion) have been synthesized and characterized by elemental analysis, IR spectroscopy and X-ray structure determination. Single x-ray analysis reveals their isostructural cyanide-bridged Fe(III)-Mn(III) binuclear structure. The binuclear entity is self-complementary through phenoxo oxygen from the neighbouring complex, giving cyanide- and phenoxo- bridged tetranuclear structure. Furthermore, under the help of the intermolecular - interaction, these two complexes can be constructed into 1D infinite chain supramolecular structure. Investigation over magnetic susceptibilities reveals the overall ferromagnetic coupling between the adjacent Fe(III) and Mn(III) ions bridged by cyanide group with = 5.34 cm-1 and 5.55 cm-1 for complexes 1 and 2, respectively.

  14. Cyanido-bridged Fe(III)-Mn(III) heterobimetallic materials built from Mn(III) Schiff base complexes and di- or tri-cyanido Fe(III) precursors.

    Science.gov (United States)

    Senapati, Tapas; Pichon, Céline; Ababei, Rodica; Mathonière, Corine; Clérac, Rodolphe

    2012-03-19

    The reaction of [Fe(III)L(CN)(3)](-) (L being bpca = bis(2-pyridylcarbonyl)amidate, pcq = 8-(pyridine-2-carboxamido)quinoline) or [Fe(III)(bpb)(CN)(2)](-) (bpb = 1,2-bis(pyridine-2-carboxamido)benzenate) ferric complexes with Mn(III) salen type complexes afforded seven new bimetallic cyanido-bridged Mn(III)-Fe(III) systems: [Fe(pcq)(CN)(3)Mn(saltmen)(CH(3)OH)]·CH(3)OH (1), [Fe(bpca)(CN)(3)Mn(3-MeO-salen)(OH(2))]·CH(3)OH·H(2)O (2), [Fe(bpca)(CN)(3)Mn(salpen)] (3), [Fe(bpca)(CN)(3)Mn(saltmen)] (4), [Fe(bpca)(CN)(3)Mn(5-Me-saltmen)]·2CHCl(3) (5), [Fe(pcq)(CN)(3)Mn(5-Me-saltmen)]·2CH(3)OH·0.75H(2)O (6), and [Fe(bpb)(CN)(2)Mn(saltmen)]·2CH(3)OH (7) (with saltmen(2-) = N,N'-(1,1,2,2-tetramethylethylene)bis(salicylideneiminato) dianion, salpen(2-) = N,N'-propylenebis(salicylideneiminato) dianion, salen(2-) = N,N'-ethylenebis(salicylideneiminato) dianion). Single crystal X-ray diffraction studies were carried out for all these compounds indicating that compounds 1 and 2 are discrete dinuclear [Fe(III)-CN-Mn(III)] complexes while systems 3-7 are heterometallic chains with {-NC-Fe(III)-CN-Mn(III)} repeating units. These chains are connected through π-π and short contact interactions to form extended supramolecular networks. Investigation of the magnetic properties revealed the occurrence of antiferromagnetic Mn(III)···Fe(III) interactions in 1-4 while ferromagnetic Mn(III)···Fe(III) interactions were detected in 5-7. The nature of these Mn(III)···Fe(III) magnetic interactions mediated by a CN bridge appeared to be dependent on the Schiff base substituent. The packing is also strongly affected by the nature of the substituent and the presence of solvent molecules, resulting in additional antiferromagnetic interdinuclear/interchain interactions. Thus the crystal packing and the supramolecular interactions induce different magnetic properties for these systems. The dinuclear complexes 1 and 2, which possess a paramagnetic S(T) = 3/2 ground state, interact

  15. STUDY ON THE SURFACE CRACK GROWTH BEHAVIOR IN 14MnNbq BRIDGE STEEL

    Institute of Scientific and Technical Information of China (English)

    Yanping Liu; Chuanyao Chen; Guoqing Li

    2010-01-01

    Three-dimensional crack closure correction methods are investigated in this paper.The fatigue crack growth tests of surface cracks in 14MnNbq steel for bridge plate subjected to tensile and bending loadings are systematically conducted.The experimentally measured fatigue crack growth rates of surface cracks are compared with those of through-thickness cracks in detail.It is found that the crack growth rates of surface cracks are lower than those of through-thickness cracks.In order to correct their differences in fatigue crack growth rates,a dimensionless crack closure correction model is proposed.Although this correction model is determined only by the experimental data of surface cracks under tensile loading with a constant ratio R=0.05,it can correlate the surface crack growth rates with reasonable accuracy under tensile and bending loadings with various stress ratios ranging from 0 to 0.5.Furthermore,predictions of fatigue life and crack aspect ratio for surface cracks are discussed,and the predicted results are also compared with those obtained from other prediction approaches.Comparison results show that the proposed crack closure correction model gives better prediction of fatigue life than other models.

  16. An experimental investigation of innovative bridge columns with engineered cementitious composites and Cu-Al-Mn super-elastic alloys

    Science.gov (United States)

    Hosseini, F.; Gencturk, B.; Lahpour, S.; Ibague Gil, D.

    2015-08-01

    Recent strong earthquakes have shown that reinforced concrete (RC) bridge columns constructed using conventional materials and techniques suffer from major damage and permanent deformations. The yielding of the longitudinal reinforcement as the main source of energy absorption, and cracking and spalling of concrete results in a dysfunctional bridge structure that does not support the post-disaster recovery efforts. This paper investigates the use of engineered cementitious composites (ECCs) and Cu-Al-Mn super-elastic alloys (SEAs) to improve the performance of bridge columns under seismic loads. A new column design is proposed, which is composed of a pre-fabricated ECC tube that encompasses the longitudinal and transverse steel reinforcement (rebar). The rebar in the plastic hinge region of the cantilever columns was totally or partially replaced with Cu-Al-Mn SEA bars. The tube was filled with conventional concrete after it was placed inside the rebar cage of the foundation. ECC exhibits superior tensile ductility, bonding with steel, energy absorption and shear resistance, in addition to lower permeability and reduced crack widths compared to conventional concrete. Cu-Al-Mn SEA bars are capable of recovering large inelastic deformations exceeding 12% strain. The proposed approach capitalizes on the deformability of ECC with reduced damage, and the energy absorption capacity of Cu-Al-Mn SEA bars without permanent deformation. A total of six column specimens were constructed and tested under simulated seismic loading. The number of rebars replaced with Cu-Al-Mn SEA bars, ECC mixture design, and the ratio of the concrete core area to total column cross-sectional area were the variables investigated in the test program. A comparison of the results indicated that the proposed concept with no Cu-Al-Mn SEA bars provides higher lateral strength, similar energy absorption and reduced damage compared to conventional RC columns; however, similar to a conventional column, it

  17. Arsenic-bridged magnetic interactions in an emerging two-dimensional FeAs nanostructure on MnAs

    Science.gov (United States)

    Helman, Christian; Ferrari, Valeria; Llois, Ana Maria

    2015-08-01

    The extreme case of an Fe monolayer deposited onto a manganese arsenide (MnAs) substrate is analyzed using density functional theory. We find that an FeAs quasi-two-dimensional antiferromagnetic surface nanostructure emerges. This nanostructure, which is magnetically nearly decoupled from the substrate, is due to bonding effects arising from the arsenic atoms bridging the Fe magnetic interactions. These interactions are studied and modeled using a Heisenberg-type Hamiltonian. They display an angular dependence which is characteristic of superexchange-like interactions, which are of the same order of magnitude as those appearing in Fe-based pnictides.

  18. Heteronuclear, mixed-metal Ag(I)-Mn(II) coordination polymers with bridging N-pyridinylisonicotinohydrazide ligands: synthesis, crystal structures, magnetic and photoluminescence properties.

    Science.gov (United States)

    Bikas, Rahman; Hosseini-Monfared, Hassan; Vasylyeva, Vera; Sanchiz, Joaquín; Alonso, Javier; Barandiaran, Jose Manuel; Janiak, Christoph

    2014-08-21

    Mixed-metal dicyanoargentate-bridged coordination polymers of Ag(i)-Mn(ii) have been prepared and their structure and magnetic properties were determined. Reaction of manganese(ii) chloride and potassium dicyanoargentate(i) with (X)(pyridin-2-ylmethylene)isonicotinohydrazide ligands (HL(1) X = Ph, HL(2) X = Me, HL(3) X = H) produced the coordination polymer 2D-[Mn(μ-L(1))(Cl)(μ-NCAgCN)Mn0.5(CH3OH)]n (), 1D-{[Mn(L(2))(Cl)(μ-NCAgCN)Mn0.5(CH3OH)]CH3OH}n () and [Mn(L(3))(Cl)(μ-NCAgCN)Mn0.5(CH3OH)]n () in good yields. Trinuclear {Mn(μ-L(1))Mn(μ-L(1))Mn} and [Ag(CN)2](-) building units form a two-dimensional slab in and 1D strands in . Variable temperature magnetic susceptibility measurements showed that despite the long distance among the high spin Mn(ii) ions [10.4676(12) Å and 10.522(1) Å, for and , respectively], weak antiferromagnetic coupling takes place through the long NC-Ag-CN bridge. The best fit parameters to the model led to the magnetic coupling constant of J = -0.1 and J = -0.47 cm(-1) for and , respectively. The photoluminescence behaviour of compounds and was studied. The spectrum of compound shows a broad emission centered at about 450 nm and two excitation maxima at 270 and 310 nm.

  19. Pentacoordinate and Hexacoordinate Mn(III Complexes of Tetradentate Schiff-Base Ligands Containing Tetracyanidoplatinate(II Bridges and Revealing Uniaxial Magnetic Anisotropy

    Directory of Open Access Journals (Sweden)

    Ivan Nemec

    2016-12-01

    Full Text Available Crystal structures and magnetic properties of polymeric and trinuclear heterobimetallic MnIII···PtII···MnIII coordination compounds, prepared from the Ba[Pt(CN4] and [Mn(L4A/B(Cl] (1a/b precursor complexes, are reported. The polymeric complex [{Mn(L4A}2{μ4-Pt(CN4}]n (2a, where H2L4A = N,N’-ethylene-bis(salicylideneiminate, comprises the {Mn(L4A} moieties covalently connected through the [Pt(CN4]2− bridges, thus forming a square-grid polymeric structure with the hexacoordinate MnIII atoms. The trinuclear complex [{Mn(L4B}2{μ-Pt(CN4}] (2b, where H2L4B = N,N’-benzene-bis(4-aminodiethylene-salicylideneiminate, consists of two [{Mn(L4B} moieties, involving pentacoordinate MnIII atoms, bridged through the tetracyanidoplatinate (II bridges to which they are coordinated in a trans fashion. Both complexes possess uniaxial type of magnetic anisotropy, with D (the axial parameter of zero-field splitting = −3.7(1 in 2a and −2.2(1 cm−1 in 2b. Furthermore, the parameters of magnetic anisotropy 2a and 2b were also thoroughly studied by theoretical complete active space self-consistent field (CASSCF methods, which revealed that the former is much more sensitive to the ligand field strength of the axial ligands.

  20. Oximato bridged Rh$^{\\text{III}}_2$MII and RhIIIMI species (MII = Mn, Co, Ni; MI = Cu, Ag)

    Indian Academy of Sciences (India)

    Indranil Bhattacharyya; Sanjib Ganguly; Bikash Kumar Panda; Animesh Chakravorty

    2008-01-01

    The reaction of [RhCl2(HPhL)(PhL)] with MII(ClO4)2.6H2O in presence of alkali has furnished trinuclear [RhCl2(PhL)2]2M(H2O)2.H2O (HPhL is phenylazobenzaldoxime; M = Mn, Co, Ni). A similar reaction with MI(PPh3)2NO3 yielded binuclear [RhCl2(PhL)2]M(PPh3)2 (M = Cu, Ag). In these molecules the oximato group acts as a bridge between RhIII (bonded at N) and MII or MI (bonded at O). In structurally characterized [RhIIICl2(PhL)2]2Mn(H2O)2.H2O the centrosymmetric distorted octahedral MnO6 coordination sphere is spanned by four oximato oxygen atoms and two water molecules lying in trans position. In the lattice the neighbouring molecules are held together by H2O$\\cdots$H2O$\\cdots$H2O hydrogen bonds generating infinite zigzag chains. The manganese atoms lie parallel to the C-axis, the shortest Mn…Mn distance being 7.992 Å. Magnetic exchange interactions if any are small as seen in room temperature magnetic moments. The manganese system displays a strong EPR signal near = 2.00. In the complex [RhCl2(PhL)2]Cu(PPh3)2 the copper atom is coordinated to two oximato oxygen atoms and the two phosphorus atoms in a distorted tetrahedral geometry. The softness of the phosphine ligand is believed to sustain the stable coordination of hard oximato oxygen to soft CuI. The coordination sphere of the RhIII atom in both the complexes is uniformly trans-RhN4Cl2.

  1. Synthesis, characterization, and reactivity studies of a water-soluble bis(alkoxo)(carboxylato)-bridged diMn(III) complex modeling the active site in catalase.

    Science.gov (United States)

    Palopoli, Claudia; Duhayon, Carine; Tuchagues, Jean-Pierre; Signorella, Sandra

    2014-12-07

    A new diMn(III) complex, Na[Mn2(5-SO3-salpentO)(μ-OAc)(μ-OMe)(H2O)]·4H2O, where 5-SO3-salpentOH = 1,5-bis(5-sulphonatosalicylidenamino)pentan-3-ol, has been prepared and characterized. ESI-mass spectrometry, paramagnetic (1)H NMR, EPR and UV-visible spectroscopic studies on freshly prepared solutions of the complex in methanol and 9 : 1 methanol-water mixtures showed that the compound retains the triply bridged bis(μ-alkoxo)(μ-acetato)Mn2(3+) core in solution. In the 9 : 1 methanol-water mixture, slow substitution of acetate by water molecules took place, and after one month, the doubly bridged diMn(III) complex, [Mn2(5-SO3-salpentO)(μ-OMe)(H2O)3]·5H2O, formed and could be characterized by X-ray diffraction analysis. In methanolic or aqueous basic media, acetate shifts from a bridging to a terminal coordination mode, affording the highly stable [Mn2(5-SO3-salpentO)(μ-OMe)(OAc)](-) anion. The efficiency of the complex in disproportionating H2O2 depends on the solvent and correlates with the stability of the complex (towards metal dissociation) in each medium: basic buffer > aqueous base > water. The buffer preserves the integrity of the catalyst and the rate of O2 evolution remains essentially constant after successive additions of excess of H2O2. Turnovers as high as 3000 mol H2O2 per mol of catalyst, without significant decomposition and with an efficiency of k(cat)/K(M) = 1028 M(-1) s(-1), were measured for the complex in aqueous buffers of pH 11. Kinetic and spectroscopic results suggest a catalytic cycle that runs between Mn(III)2 and Mn(IV)2 oxidation states, which is consistent with the low redox potential observed for the Mn(III)2/Mn(III)Mn(IV) couple of the catalyst in basic medium.

  2. EnviroAtlas - Metrics for Minneapolis/St. Paul, MN

    Data.gov (United States)

    U.S. Environmental Protection Agency — This EnviroAtlas web service supports research and online mapping activities related to EnviroAtlas (https://enviroatlas.epa.gov/EnviroAtlas). The layers in this web...

  3. 78 FR 63861 - Modification of Class B Airspace; Minneapolis, MN

    Science.gov (United States)

    2013-10-25

    ... modifications would impact the Minnesota Soaring Club and Stanton Sport Aviation operations and provided six... updating of materials outside the normal update cycle. Therefore, the expected outcome will be a...

  4. Student Attendance and Mobility in Minneapolis Public Schools.

    Science.gov (United States)

    Hinz, Elizabeth; Kapp, Lucy; Snapp, Sarah

    2003-01-01

    Describes how the Minneapolis Public Schools, Minnesota, identified system-wide standards and practices to help all students achieve the goal of 95 percent attendance, an especially difficult goal for highly mobile students. The Kids Mobility Study in Minneapolis documents the connection between residential mobility and student achievement and…

  5. The Minneapolis Accountability Project: 1972-1976. Final Report.

    Science.gov (United States)

    Faunce, R.W.; Walen, Tracey

    The Minneapolis Accountability Project was an effort of the Minneapolis Public Schools to provide greater accountability to the public by helping citizens evaluate school programs. Citizens' study groups were provided with staff to help them in a year-long study of a topic selected by a citizen's advisory board. Study committees met weekly…

  6. Synthesis and Crystal Structure of a Three-dimensional Mn(Ⅱ) Coordination Polymer with 3-(Pyrazin-2-yloxy)-pyridine and Azide Anion as Mixed Bridge Ligand

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    A three-dimensional coordination polymer [Mn2((1,3-N3)4(μ-PP)2]n (PP = 3-(pyra- zin-2-yloxy)-pyridine) has been synthesized with 3-(pyrazin-2-yloxy)-pyridine and azide anion as mixed bridge ligand, and its crystal structure was determined by X-ray crystallography. The crystal data: triclinic system, space group P, with a = 6.794(4), b = 9.885(6), c = 9.947(6)A, α = 64.170(6),β = 84.190(8),γ = 85.319(8)°, V = 597.7(6)(A)3, Z = 1, C18H14Mn2N18O2, Mr = 624.35, Dc = 1.735 g/cm3, F(000) = 314 andμ= 1.117 mm-1. In the crystal, the azide anion acts as a bridge ligand and makes adjacent Mn(Ⅱ) ions connect into a two-dimensional sheet on the ab plane, then 3-(pyrazin-2-yloxy)-pyridine serves as a bidentate bridge ligand to connect neighboring sheets along the c axis, and finally a three-dimensional structure is formed.

  7. Magnetic exchange interaction via HF 2--bridges? Structure and magnetism of pipzH 2[MnF 4(HF 2)

    Science.gov (United States)

    Bentrup, U.; Harms, K.; Massa, W.; Pebler, J.

    2000-05-01

    pipzH 2[MnF 4(HF 2)] (pipz=piperazine) has been prepared from an aqueous hydrofluoric acid solution of Mn(III) acetate and its crystal structure was determined by single-crystal X-ray analysis: triclinic, space group Poverline11¯, Z=1, a=5.636(1), b=6.151(1), c=6.498(1) Å, α=99.52(1), β=90.62(1), γ=107.43(1)°, wR2=0.063, R=0.023. The structure consists of hitherto unique anionic chains where [MnF 4] units are bridged by HF 2- anions. The resulting [MnF 6] octahedra are strongly elongated, mainly due to the Jahn-Teller effect ( 1.84 Å, MnF ax 2.19 Å). The geometry of the centrosymmetrical bifluoride anion is close to that of KHF 2 (HF 1.14 Å), the angles at the angular bridge MnFH are 111.7°. Surprisingly, magnetic investigations revealed pure paramagnetic behavior. Thus, in contrast to several examples where antiferromagnetic coupling was observed via OH⋯F hydrogen bonds, the very strong hydrogen bonds in the symmetric F⋯H⋯F - anion are obviously not able to mediate magnetic exchange interactions.

  8. Integrated solid waste management of Minneapolis, Minnesota

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-11-01

    The subject document reports the results of an in-depth investigation of the fiscal year 1992 cost of the City of Minneapolis, Minnesota (Hennepin County) integrated municipal solid waste management (IMSWM) system, the energy consumed to operate the system, and the environmental performance requirements for each of the system`s waste-processing and disposal facilities. Actual data from records kept by participants is reported in this document. Every effort was made to minimize the use of assumptions, and no attempt is made to interpret the data reported. Analytical approaches are documented so that interested analysts may perform manipulation or further analysis of the data. As such, the report is a reference document for municipal solid waste (MSW) management professionals who are interested in the actual costs and energy consumption for a one-year period, of an operating IMSWM system.

  9. Synthesis and Crystal Structure of a Spiral-chain Manganese(Ⅲ) Complex Containing Azide Bridge, [Mn(bzan)N3]n

    Institute of Scientific and Technical Information of China (English)

    冯云龙

    2002-01-01

    The title complex, C22H22MnN5O2, crystallizes in orthorhombic system, space group P212121 with a = 6.887(1), b = 11.718(2), c = 25.721(5) (A。), V = 2075.7(7) (A。)3, Z = 4, Mr = 443.39, F(000) = 920, Dc = 1.419 g/cm3 and ( = 0.665mm(1 (MoK(). The structure was refined to R = 0.0593 and wR = 0.1427 for 3576 observed reflections with I ≥ 2((I). The Mn(Ⅲ) atom is coordinated to one bzan2-[bzan2- = N,N-ethylenebis(benzoylacetoneiminato)] ligand binding in the equatorial mode and two N3- ions in the axial positions. The azide acts as a trans-μ-(1, 3) bridge, resulting in an infinite helical chain propagating along the b axis.

  10. Experimental and computational X-ray emission spectroscopy as a direct probe of protonation states in oxo-bridged Mn(IV) dimers relevant to redox-active metalloproteins.

    Science.gov (United States)

    Lassalle-Kaiser, Benedikt; Boron, Thaddeus T; Krewald, Vera; Kern, Jan; Beckwith, Martha A; Delgado-Jaime, Mario U; Schroeder, Henning; Alonso-Mori, Roberto; Nordlund, Dennis; Weng, Tsu-Chien; Sokaras, Dimosthenis; Neese, Frank; Bergmann, Uwe; Yachandra, Vittal K; DeBeer, Serena; Pecoraro, Vincent L; Yano, Junko

    2013-11-18

    The protonation state of oxo bridges in nature is of profound importance for a variety of enzymes, including the Mn4CaO5 cluster of photosystem II and the Mn2O2 cluster in Mn catalase. A set of dinuclear bis-μ-oxo-bridged Mn(IV) complexes in different protonation states was studied by Kβ emission spectroscopy to form the foundation for unraveling the protonation states in the native complex. The valence-to-core regions (valence-to-core XES) of the spectra show significant changes in intensity and peak position upon protonation. DFT calculations were performed to simulate the valence-to-core XES spectra and to assign the spectral features to specific transitions. The Kβ(2,5) peaks arise primarily from the ligand 2p to Mn 1s transitions, with a characteristic low energy shoulder appearing upon oxo-bridge protonation. The satellite Kβ" peak provides a more direct signature of the protonation state change, since the transitions originating from the 2s orbitals of protonated and unprotonated μ-oxo bridges dominate this spectral region. The energies of the Kβ" features differ by ~3 eV and thus are well resolved in the experimental spectra. Additionally, our work explores the chemical resolution limits of the method, namely, whether a mixed (μ-O)(μ-OH2) motif can be distinguished from a symmetric (μ-OH)2 one. The results reported here highlight the sensitivity of Kβ valence-to-core XES to single protonation state changes of bridging ligands, and form the basis for further studies of oxo-bridged polymetallic complexes and metalloenzyme active sites. In a complementary paper, the results from X-ray absorption spectroscopy of the same Mn(IV) dimer series are discussed.

  11. Self-assembly of linear [Mn II 2 Mn III ] units with end-on azido bridges: the construction of a ferromagnetic chain using S T = 7 high-spin trimers

    KAUST Repository

    Jiang, Yuan

    2015-01-01

    © The Royal Society of Chemistry 2015. The controlled organization of high-spin complexes into 1D coordination polymers is a challenge in molecular magnetism. In this work, we report a ferromagnetic Mn trimer Mn3(HL)2(CH3OH)6(Br)4·Br·(CH3OH)21 (H2L = 2-[(9H-fluoren-9-yl)amino]propane-1,3-diol) with the ground spin state of ST = 7 that can be assembled into a one-dimensional coordination chain [Mn3(HL)2(CH3OH)2(Br)4(N3)(H2O)·CH3OH]2 using azido bridging ligands. Interestingly, the ferromagnetic nature of 1 is well retained in 2. However, due to the negligible magnetic anisotropy in 1, both 1 and 2 do not show slow-relaxation of magnetization, which indicates that during the process of molecular assembly not only the intratrimer magnetic interaction but also the magnetic anisotropy of the trimer can be reserved.

  12. Minneapolis Multi-Ethnic Curriculum Project--Migration Unit.

    Science.gov (United States)

    Minneapolis Public Schools, Minn. Dept. of Intergroup Education.

    The student booklet presents short chapters illustrating the migration unit of the Minneapolis Multi-Ethnic Curriculum Project for secondary schools. Sixteen brief chapters describe migration, immigration, and emigration in the United States. The first six chapters offer first person accounts of immigrants from Norway, Korea, Egypt, Hitler's…

  13. Heterobimetallic oxalato-bridged M(II)Re(IV) complexes (M = Mn, Fe, Co, Ni): synthesis, crystal structure, and magnetic properties.

    Science.gov (United States)

    Chiozzone, Raúl; González, Ricardo; Kremer, Carlos; De Munno, Giovanni; Armentano, Donatella; Lloret, Francesc; Julve, Miguel; Faus, Juan

    2003-02-24

    Four rhenium(IV)-M(II) bimetallic complexes of formula [ReCl(4)(mu-ox)M(dmphen)(2)].CH(3)CN with M = Mn (1), Fe (2), Co (3), and Ni (4) (ox = oxalate anion, dmphen = 2,9-dimethyl-1,10-phenanthroline) have been synthesized and the crystal structures of 1 and 3 determined by single-crystal X-ray diffraction. 1 and 3 are isostructural and crystallize in the monoclinic system, space group P2(1)/c, with a = 16.008(4) A, b = 12.729(2) A, c = 18.909(5) A, beta = 112.70(2) degrees, and Z = 4 for 1 and a = 15.998(4) A, b = 12.665(2) A, c = 18.693(5) A, beta = 112.33(2) degrees, and Z = 4, for 3. The structure of 1 and 3 is made up of neutral [ReCl(4)(mu-ox)M(dmphen)(2)] bimetallic units (M = Mn (1), Co (3)) and acetonitrile molecules of crystallization. M(II) and Re(IV) metal ions exhibit distorted octahedral coordination geometries being bridged by a bis(bidentate) oxalato ligand. The magnetic behavior of 1-4 has been investigated over the temperature range 2.0-300 K. A very weak antiferromagnetic coupling between Re(IV) and Mn(II) occurs in 1 (J = -0.1 cm(-)(1)), whereas a significant ferromagnetic interaction between Re(IV) and M(II) is observed in 2-4 [J = +2.8 (2), +5.2 (3), and +5.9 cm(-)(1) (4)].

  14. Synthesis, crystal structure and magnetic properties of novel heterobimetallic malonate-bridged MIIReIV complexes (M = Mn, Fe, Co and Ni).

    Science.gov (United States)

    Cuevas, Alicia; Kremer, Carlos; Suescun, Leopoldo; Russi, Silvia; Mombrú, Alvaro W; Lloret, Francesc; Julve, Miguel; Faus, Juan

    2007-12-07

    Five novel ReIV-MII bimetallic complexes of formula [ReCl4(mu-mal)M(dmphen)2].MeCN [M = Co (1), Fe (2) and Ni (3)], [ReCl4(mu-mal)Ni(dmphen)(MeCN)2(H2O)].(MeCN)0.5(H2O)0.5 (4), and [ReCl4(mu-mal)Mn(dmphen)(H2O)2].dmphen.MeCN.H2O (5) (mal = malonate dianion, dmphen = 2,9-dimethyl-1,10-phenanthroline) have been synthesized, and the structures of 1, 2, 4, and 5 determined by single-crystal X-ray diffraction. The structures of 1 and 2 consist of neutral [ReCl4(mu-mal)M(dmphen)2] dinuclear units where the metal ions are linked through a malonate ligand which adopts simultaneously the bidentate (at ReIV) and monodentate (at MII) coordination modes. The bridging carboxylate-malonate group in them exhibits the anti-syn conformation. The rhenium atom is six-coordinated with four chloro atoms and two carboxylate-oxygens from a bidentate malonate group in a distorted octahedral environment. The M atom is five-coordinated being surrounded by four nitrogen atoms of two bidentate dmphen ligands and one oxygen atom of the malonato ligand. There are also ReIV(mu-mal)NiII dinuclear units in 4 with the same type of bridge, but the nickel atom is six-coordinated with one bidentate dmphen, two molecules of acetonitrile and one water molecule as peripheral ligands. Compound 5 is a neutral chain compound with regular alternating rhenium(IV) and manganese(II) ions. The [ReCl4(mal)]2- units in each chain act as bismonodenate ligands through two carboxylate-oxygen atoms toward [Mn(dmphen)(H2O)2]2+ entities. Variable-temperature magnetic measurements of 1-5 in the temperature range 2.0-300 K show the occurrence of weak antiferromagnetic interactions which are rationalized on the basis of the structural knowledge and simple orbital considerations. Very noticeable is compound 5, a ferrimagnetic chain with regular alternating ReIV and MnII cations.

  15. mer-[Fe(pcq)(CN)3]-: a novel cyanide-containing building block and its application to assembling cyanide-bridged trinuclear FeIII2MnII complexes [pcq- = 8-(pyridine-2-carboxamido)quinoline anion].

    Science.gov (United States)

    Ni, Zhong-Hai; Kou, Hui-Zhong; Zhang, Li-Fang; Ni, Wei-Wei; Jiang, Yun-Bo; Cui, Ai-Li; Ribas, Joan; Sato, Osamu

    2005-12-26

    A new cyanide-containing building block K[Fe(pcq)(CN)(3)] [1; pcq(-) = 8-(pyridine-2-carboxamido)quinoline anion] containing a low-spin Fe(III) center with three cyanide groups in a meridional arrangement has been successfully designed and synthesized. Three cyanide-bridged trinuclear Fe(III)(2)Mn(II) complexes, [Fe(pcq)(CN)(3)](2)[Mn(CH(3)OH)(2)(H(2)O)(2)].2H(2)O (2), [Fe(pcq)(CN)(3)](2)[Mn(bipy)(2)].CH(3)OH.2H(2)O (3), and [Fe(pcq)(CN)(3)](2)[Mn(phen)(2)].CH(3)OH.2H(2)O (4), have been synthesized and structurally characterized. The magnetic susceptibilities of the three heterometallic complexes have been investigated.

  16. New family of thiocyanate-bridged Re(IV)-SCN-M(II) (M = Ni, Co, Fe, and Mn) heterobimetallic compounds: synthesis, crystal structure, and magnetic properties.

    Science.gov (United States)

    González, Ricardo; Acosta, Alvaro; Chiozzone, Raúl; Kremer, Carlos; Armentano, Donatella; De Munno, Giovanni; Julve, Miguel; Lloret, Francesc; Faus, Juan

    2012-05-21

    The heterobimetallic complexes of formula [(Me(2)phen)(2)M(μ-NCS)Re(NCS)(5)]·CH(3)CN [Me(2)phen = 2,9-dimethyl-1,10-phenanthroline and M = Ni (1), Co (2), Fe (3), and Mn (4)] have been prepared, and their crystal structures have been determined by X-ray diffraction on single crystals. Compounds 1-4 crystallize in the monoclinic C2/c space group, and their structure consists of neutral [(Me(2)phen)(2)M(μ-NCS)Re(NCS)(5)] heterodinuclear units with a Re-SCN-M bridge. Each Re(IV) ion in this series is six-coordinated with one sulfur and five nitrogen atoms from six thiocyanate groups building a somewhat distorted octahedral environment, whereas the M(II) metal ions are five-coordinated with four nitrogen atoms from two bidentate Me(2)phen molecules and a nitrogen atom from the bridging thiocyanate describing distorted trigonal bipyramidal surroundings. The values of the Re···M separation through the thiocyanate bridge in 1-4 vary in the range 5.903(1)-6.117(3) Å. The magnetic properties of 1-4 as well as those of the parent mononuclear Re(IV) compounds (NBu(4))(2)[Re(NCS)(6)] (A1) (NBu(4)(+) = tetra-n-butylammonium cation) and [Zn(NO(3))(Me(2)phen)(2)](2)[Re(NCS)(5)(SCN)] (A2) were investigated in the temperature range 1.9-300 K. Weak antiferromagnetic interactions between the Re(IV) and M(II) ions across the bridging thiocyanate were found in 1-4 [J = -4.3 (1), -2.4 (2), -1.8 (3), and -1.2 cm(-1) (4), the Hamiltonian being defined as Ĥ = -JŜ(Re)·Ŝ(M)]. The magnetic behavior of A2 is that of a magnetically diluted Re(IV) complex with a large and positive value of the zero-field splitting for the ground level (D(Re) = +37.0 cm(-1)). In the case of A1, although its magnetic behavior is similar to that of A2 in the high-temperature range (D(Re) being +19.0 cm(-1)), it exhibits a weak ferromagnetism below 3.0 K with a canting angle of 1.3°.

  17. Synthesis and Crystal Structure of a One-dimensional Azido-bridged Manganese (II) Compound [Mn(N3)2(H2O)3·C6H12N4]n

    Institute of Scientific and Technical Information of China (English)

    CHEN Hui; WANG Wen-Guo; ZHANG Xiao-Feng; CHEN Chang-Neng; LIU Qiu-Tian

    2006-01-01

    A new one-dimensional azido-bridged manganese compound has been prepared and structurally characterized by X-ray diffraction. The complex [Mn(N3)2(H2O)3·C6H12N4]n crystallizes in space group Pnma with a = 6.5252 (5), b = 9.3226(7), c = 22.2070(15)(A), V = 1350.89(17)(A)3, Z = 4, Mr = 333.24, Dc = 1.639 g/cm3, μ= 1.005 mm-1 and F(000) = 692. The final refinement gave R = 0.0328 and wR = 0.0777 for 1085 observed reflections with I > 2σ(I). The structure contains [Mn- (N3)2(H2O)3]n polymeric chains and uncoordinated hexamethylenetetramine (HMTA) molecules with Mn/HMTA molar ratio of 1:1. The Mn atoms are bridged by end-to-end azido ligands to construct one-dimensional zig-zag infinite chains. Each Mn atom is six-coordinated by three N atoms of three azido ligands and three water O atoms, resulting in an octahedral geometry. Extending hydrogen- bonding interactions involving water O atoms, azido and HMTA N atoms link the chains and HMTA molecules into a three-dimensional network.

  18. Planar Hall effect bridge sensors with NiFe/Cu/IrMn stack optimized for self-field magnetic bead detection

    DEFF Research Database (Denmark)

    Henriksen, Anders Dahl; Rizzi, Giovanni; Hansen, Mikkel Fougt

    2016-01-01

    The stack composition in trilayer Planar Hall effect bridge sensors is investigated experimentally to identify the optimal stack for magnetic bead detection using the sensor self-field. The sensors were fabricated using exchange-biased stacks Ni80Fe20(tFM)/Cu(tCu)/Mn80Ir20(10 nm) with tFM = 10, 20......, and 30 nm, and 0 ≤ tCu ≤ 0.6 nm. The sensors were characterized by magnetic hysteresis measurements, by measurements of the sensor response vs. applied field, and by measurements of the sensor response to a suspension of magnetic beads magnetized by the sensor self-field due to the sensor bias current...... of the sensors and, thus, that the magnetic stacks should be compared at constant power consumption. For a fixed sensor geometry, the figure of merit for this comparison is the magnetic field sensitivity normalized by the sensor bias voltage. In this regard, we found that sensors with tFM = 20 nm or 30 nm...

  19. Crystal structure and spectroscopic analysis of a new oxalate-bridged MnII compound: catena-poly[guanidinium [[aquachloridomanganese(II]-μ2-oxalato-κ4O1,O2:O1′,O2′] monohydrate

    Directory of Open Access Journals (Sweden)

    Hiba Sehimi

    2016-05-01

    Full Text Available As part of our studies on the synthesis and the characterization of oxalate-bridged compounds M–ox–M (ox = oxalate dianion and M = transition metal ion, we report the crystal structure of a new oxalate-bridged MnII phase, {(CH6N3[Mn(C2O4Cl(H2O]·H2O}n. In the compound, a succession of MnII ions (situated on inversion centers adopting a distorted octahedral coordination and bridged by oxalate ligands forms parallel zigzag chains running along the c axis. These chains are interconnected through O—H...O hydrogen-bonding interactions to form anionic layers parallel to (010. Individual layers are held together via strong hydrogen bonds involving the guanidinium cations (N—H...O and N—H...Cl and the disordered non-coordinating water molecule (O—H...O and O—H...Cl, as well as by guanidinium π–π stacking. The structural data were confirmed by IR and UV–Visible spectroscopic analysis.

  20. Planar Hall effect bridge sensors with NiFe/Cu/IrMn stack optimized for self-field magnetic bead detection

    Science.gov (United States)

    Henriksen, Anders Dahl; Rizzi, Giovanni; Hansen, Mikkel Fougt

    2016-03-01

    The stack composition in trilayer Planar Hall effect bridge sensors is investigated experimentally to identify the optimal stack for magnetic bead detection using the sensor self-field. The sensors were fabricated using exchange-biased stacks Ni80Fe20(tFM)/Cu(tCu)/Mn80Ir20(10 nm) with tFM = 10, 20, and 30 nm, and 0 ≤ tCu ≤ 0.6 nm. The sensors were characterized by magnetic hysteresis measurements, by measurements of the sensor response vs. applied field, and by measurements of the sensor response to a suspension of magnetic beads magnetized by the sensor self-field due to the sensor bias current. The exchange bias field was found to decay exponentially with tCu and inversely with tFM. The reduced exchange field for larger values of tFM and tCu resulted in higher sensitivities to both magnetic fields and magnetic beads. We argue that the maximum magnetic bead signal is limited by Joule heating of the sensors and, thus, that the magnetic stacks should be compared at constant power consumption. For a fixed sensor geometry, the figure of merit for this comparison is the magnetic field sensitivity normalized by the sensor bias voltage. In this regard, we found that sensors with tFM = 20 nm or 30 nm outperformed those with tFM = 10 nm by a factor of approximately two, because the latter have a reduced AMR ratio. Further, the optimum layer thicknesses, tCu ≈ 0.6 nm and tFM = 20-30 nm, gave a 90% higher signal compared to the corresponding sensors with tCu = 0 nm.

  1. Building America Case Study: Demonstration House of Cold-Climate Solutions for Affordable Housing, Minneapolis, Minnesota

    Energy Technology Data Exchange (ETDEWEB)

    2016-05-01

    Single family homes in urban areas that are available for renovation by nonprofit developers are often in rough shape (1MM to 2MM nationally). Budgeting has historically focused on improving homes to meet basic housing standards. A rising interest in the long-term impact of homeownership has introduced the need to balance basic needs with home performance. This demonstration project aims to help nonprofit affordable housing developers become familiar with three Building America performance measures, the installation processes, and impacts and benefits of each. A story and a half home in North Minneapolis, MN was presented by Urban Homeworks our local nonprofit partner. The team helped them install three researched upgrade measures: exterior roof insulation or 'overcoat,' exterior foundation insulation, or 'excavationless', and a combined space and water heating HVAC system or 'combi'. To maximize efficiency of application and to address budget issues, the Team worked with Urban Homeworks to identify ways to use volunteers and construction training programs to install the measures. An open invitation to visit the job site was extended to other nonprofit developers and industry partners to encourage dialog about the systems during live installation.

  2. Visible Light-Induced Electron Transfer from Di-mu-oxo Bridged Dinuclear Mn Complexes to Cr Centers in Silica Nanopores

    Energy Technology Data Exchange (ETDEWEB)

    Frei, Heinz; Weare, Walter W.; Pushkar, Yulia; Yachandra, Vittal K.; Frei, Heinz

    2008-06-03

    The compound (bpy)2MnIII(mu-O)2MnIV(bpy)2, a structural model relevant for the photosynthetic water oxidation complex, was coupled to single CrVI charge-transfer chromophores in the channels of the nanoporous oxide AlMCM-41. Mn K-edge EXAFS spectroscopy confirmed that the di-mu-oxo dinuclear Mn core of the complex is unaffected when loaded into the nanoscale pores. Observation of the 16-line EPR signal characteristic of MnIII(mu-O)2MnIV demonstrates that the majority of the loaded complexes retained their nascent oxidation state in the presence or absence of CrVI centers. The FT-Raman spectrum upon visible light excitation of the CrVI-OII --> CrV-OI ligand-to-metal charge-transfer reveals electron transfer from MnIII(mu-O)2MnIV (Mn-O stretch at 700 cm-1) to CrVI, resulting in the formation of CrV and MnIV(mu-O)2MnIV (Mn-O stretch at 645 cm-1). All initial and final states are directly observed by FT-Raman or EPR spectroscopy, and the assignments corroborated by X-ray absorption spectroscopy measurements. The endoergic charge separation products (DELTA Eo = -0.6 V) remain after several minutes, which points to spatial separation of CrV and MnIV(mu-O)2MnIV as a consequence of hole (OI) hopping as a major contributing mechanism. This is the first observation of visible light-induced oxidation of a potential water oxidation complex by a metal charge-transfer pump in a nanoporous environment. These findings will allow for the assembly and photochemical characterization of well defined transition metal molecular units, with the ultimate goal of performing endothermic, multi-electron transformations that are coupled to visible light electron pumps in nanostructured scaffolds.

  3. Walker Community Library: building underground to serve neighborhood needs. [Minneapolis

    Energy Technology Data Exchange (ETDEWEB)

    Bennett, D.J.

    1980-09-01

    A branch library in Minneapolis was constructed underground in order to meet community needs for public open areas and affordable library space. A review of the site selection and building-design processes reveals a long-standing interaction between the library board, residents of the neighborhood, and consultants to develop a consensus. The money saved by reducing the land area needed for a single-story building more than offset the higher construction costs of roof-top parking. Energy savings are estimated at a 40 percent reduction of the present above-ground facility. The pedestrian terrace connects with an existing mall and provides a setting for neighborhood activities. 6 figures. (DCK)

  4. EnviroAtlas - Minneapolis/St. Paul, MN - 15m Riparian Buffer Vegetated Cover

    Data.gov (United States)

    U.S. Environmental Protection Agency — This EnviroAtlas dataset describes the percentage of a 15-m riparian buffer that is vegetated. In this community, vegetated cover is defined as Trees and Forest,...

  5. 78 FR 10564 - Proposed Modification of Class B Airspace; Minneapolis, MN

    Science.gov (United States)

    2013-02-14

    ... indicate the proposed modifications would impact the Minnesota Soaring Club and Stanton Sport Aviation... about the proposed design. The Ad Hoc Committee was chaired by the Minnesota Soaring Club representative... that the proposed modifications near the Stanton Airfield (SYN) would impact the Minnesota Soaring...

  6. EnviroAtlas - Minneapolis/St. Paul, MN - Near Road Tree Buffer

    Data.gov (United States)

    U.S. Environmental Protection Agency — This EnviroAtlas dataset addresses the tree buffer along heavily traveled roads. The roads are interstates, arterials, and collectors within the EnviroAtlas...

  7. EnviroAtlas - Minneapolis/St. Paul, MN - 51m Riparian Buffer Forest Cover

    Data.gov (United States)

    U.S. Environmental Protection Agency — This EnviroAtlas dataset describes the percentage of a 51-m riparian buffer that is forested. In this community, forest is defined as Trees and Forest and Woody...

  8. EnviroAtlas - Minneapolis/St. Paul, MN - Land Cover by Block Group

    Data.gov (United States)

    U.S. Environmental Protection Agency — This EnviroAtlas dataset describes the percentage of each block group that is classified as impervious, forest, green space, agriculture, and wetlands. In this...

  9. EnviroAtlas - Minneapolis/St. Paul, MN - Estimated Intersection Density of Walkable Roads

    Data.gov (United States)

    U.S. Environmental Protection Agency — This EnviroAtlas dataset estimates the intersection density of walkable roads within a 750 meter radius of any given 10 meter pixel in the community. Intersections...

  10. EnviroAtlas - Minneapolis/St. Paul, MN - Riparian Buffer Land Cover by Block Group

    Data.gov (United States)

    U.S. Environmental Protection Agency — This EnviroAtlas dataset describes the percentage of forested, vegetated, and impervious land within 15- and 50-meters of hydrologically connected streams, rivers,...

  11. EnviroAtlas - Minneapolis/St. Paul, MN - Potential Window Views of Water by Block Group

    Data.gov (United States)

    U.S. Environmental Protection Agency — This EnviroAtlas dataset describes the block group population and the percentage of the block group population that has potential views of water bodies. A potential...

  12. EnviroAtlas - Minneapolis/St. Paul, MN - Demographics by Block Group Web Service

    Data.gov (United States)

    U.S. Environmental Protection Agency — This EnviroAtlas web service supports research and online mapping activities related to EnviroAtlas (https://enviroatlas.epa.gov/EnviroAtlas). This EnviroAtlas...

  13. EnviroAtlas - Minneapolis/St. Paul, MN - Estimated Percent Green Space Along Walkable Roads

    Data.gov (United States)

    U.S. Environmental Protection Agency — This EnviroAtlas dataset estimates green space along walkable roads. Green space within 25 meters of the road centerline is included and the percentage is based on...

  14. EnviroAtlas - Minneapolis/St. Paul, MN - Tree Cover Configuration and Connectivity

    Data.gov (United States)

    U.S. Environmental Protection Agency — This EnviroAtlas dataset categorizes forest land cover into structural elements (e.g. core, edge, connector, etc.). In this community, forest is defined as Trees and...

  15. EnviroAtlas - Minneapolis/St. Paul, MN - Estimated Percent Tree Cover Along Walkable Roads

    Data.gov (United States)

    U.S. Environmental Protection Agency — This EnviroAtlas dataset estimates tree cover along walkable roads. The road width is estimated for each road and percent tree cover is calculated in a 8.5 meter...

  16. EnviroAtlas - Minneapolis/St. Paul, MN - Historic Places by Census Block Group

    Data.gov (United States)

    U.S. Environmental Protection Agency — This EnviroAtlas dataset portrays the total number of historic places located within each Census Block Group (CBG). The historic places data were compiled from the...

  17. EnviroAtlas - Minneapolis/St. Paul, MN - Near Road Block Group Summary

    Data.gov (United States)

    U.S. Environmental Protection Agency — This EnviroAtlas dataset addresses the tree buffer along heavily traveled roads. The roads are interstates, arterials, and collectors within the EnviroAtlas...

  18. EnviroAtlas - Minneapolis/St. Paul, MN - Proximity to Parks

    Data.gov (United States)

    U.S. Environmental Protection Agency — This EnviroAtlas dataset shows the approximate walking distance from a park entrance at any given location within the EnviroAtlas community boundary. The zones are...

  19. EnviroAtlas - Minneapolis/St. Paul, MN - Greenspace Around Schools by Block Group

    Data.gov (United States)

    U.S. Environmental Protection Agency — This EnviroAtlas data set shows the number of schools in each block group in the EnviroAtlas community boundary as well as the number of schools where less than 25%...

  20. EnviroAtlas - Minneapolis/St. Paul, MN - 51m Riparian Buffer Vegetated Cover

    Data.gov (United States)

    U.S. Environmental Protection Agency — This EnviroAtlas dataset describes the percentage of a 51-m riparian buffer that is vegetated. In this community, vegetated cover is defined as Trees and Forest,...

  1. EnviroAtlas - Minneapolis/St. Paul, MN - Green Space Proximity Gradient

    Data.gov (United States)

    U.S. Environmental Protection Agency — In any given 1-square meter point in this EnviroAtlas dataset, the value shown gives the percentage of square meters of greenspace within 1/4 square kilometer...

  2. EnviroAtlas - Minneapolis/St. Paul, MN - Demographics by Block Group

    Data.gov (United States)

    U.S. Environmental Protection Agency — This EnviroAtlas dataset is a summary of key demographic groups for the EnviroAtlas community. This dataset was produced by the US EPA to support research and online...

  3. Rational enantioselective design of chiral heterobimetallic single-chain magnets: synthesis, crystal structures and magnetic properties of oxamato-bridged M(II)Cu(II) chains (M=Mn, Co).

    Science.gov (United States)

    Ferrando-Soria, Jesús; Cangussu, Danielle; Eslava, Mercedes; Journaux, Yves; Lescouëzec, Rodrigue; Julve, Miguel; Lloret, Francesc; Pasán, Jorge; Ruiz-Pérez, Catalina; Lhotel, Elsa; Paulsen, Carley; Pardo, Emilio

    2011-10-24

    A new series of neutral oxamato-bridged M(II)Cu(II) chiral chains of general formula [MCuL(x)(S)(m)(H(2)O)(n)]·aS·bH(2)O [L(1)=(M)-1,1'-binaphthalene-2,2'-bis(oxamate) with M=Mn (1a) and Co (1b); L(2)=(P)-1,1'-binaphthalene-2,2'-bis(oxamate) with M=Mn (2a) and Co (2b)] and the analogous racemic chains of formula [MCuL(3)(S)(m)(H(2)O)(n)]·aS·bH(2)O [L(3)=1,1'-binaphthalene-2,2'-bis(oxamate) with M=Mn (3a) and Co (3b)] have been prepared by reaction of the corresponding dianionic oxamatocopper(II) complex [Cu(L(x))](2-) with Mn(2+) or Co(2+) cations in either dimethylformamide (DMF) or dimethyl sulfoxide (DMSO). Solid circular dichroism (CD) spectra of the bimetallic chain compounds were recorded to establish their chiral and enantiomeric nature. They exhibit maximum positive and negative Cotton effects, each pair of enantiomeric chains being non-superimposable mirror images. The crystal structures of the Mn(II)Cu(II) (1a-3a) and the Co(II)Cu(II) (1b and 2b) chain compounds were solved by single-crystal X-ray diffraction methods. Our attempts to obtain X-ray quality crystals of 3b were unsuccessful. The values of the shortest interchain Mn···Mn and Co···Co distances are indicative of a good isolation of neighbouring chains in the crystal lattice, which is caused by the bulky aromatic ligand. Although all the Mn(II)Cu(II) and Co(II)Cu(II) chains exhibit ferrimagnetic behaviour (-J(MnCu)=18.9-26.6 cm(-1) and -J(CoCu)=19.5-32.5 cm(-1)), only the enantiopure Co(II)Cu(II) chains (1b and 2b) show slow magnetic relaxation at low temperatures (T(B)=0.6-1.8 K), which is a characteristic of single-chain magnets (SCMs) and is related to the magnetic anisotropy of the high-spin Co(II) ion. Analysis of the SCM behaviour of 1b and 2b, based on Glauber's theory for an Ising one-dimensional system, shows a thermally activated mechanism for the magnetic relaxation (Arrhenius law dependence). The energy barriers (E(a)) to reverse the magnetisation direction are 8.2 (1b) and

  4. Single-ion anisotropy and exchange interactions in the cyano-bridged trimers MnIII2MIII(CN)6 (MIII = Co, Cr, Fe) species incorporating [Mn(5-Brsalen)]+ units: an inelastic neutron scattering and magnetic susceptibility study

    DEFF Research Database (Denmark)

    Tregenna-Piggott, Philip L W; Sheptyakov, Denis; Keller, Lukas;

    2009-01-01

    expectations based on the unquenched orbital angular momentum of the [Fe(CN)(6)](3-) anion, giving rise to an M(s) approximately +/-9/2 ground state, isolated by approximately 11.5 cm(-1) from the higher-lying levels. The reported INS and magnetic data should now serve as a benchmark against which theoretical......The electronic structures of the compounds K[(5-Brsalen)(2)(H(2)O)(2)-Mn(2)M(III)(CN)(6)].2H(2)O (M(III) = Co(III), Cr(III), Fe(III)) have been determined by inelastic neutron scattering (INS) and magnetic susceptibility studies, revealing the manganese(III) single-ion anisotropy and exchange...... interactions that define the low-lying states of the Mn-M(III)-Mn trimeric units. Despite the presence of an antiferromagnetic intertrimer interaction, the experimental evidence supports the classification of both the Cr(III) and Fe(III) compounds as single-molecule magnets. The value of 17(2) cm(-1...

  5. 33 CFR 207.320 - Mississippi River, Twin City Locks and Dam, St. Paul and Minneapolis, Minn.; pool level.

    Science.gov (United States)

    2010-07-01

    ... Locks and Dam, St. Paul and Minneapolis, Minn.; pool level. 207.320 Section 207.320 Navigation and... § 207.320 Mississippi River, Twin City Locks and Dam, St. Paul and Minneapolis, Minn.; pool level. In.... 362-Minn., Ford Motor Co.), this section is prescribed for the control of the pool level created...

  6. Air conditioning versus heating: climate control is more energy demanding in Minneapolis than in Miami

    Science.gov (United States)

    Sivak, Michael

    2013-03-01

    Energy demand for climate control was analyzed for Miami (the warmest large metropolitan area in the US) and Minneapolis (the coldest large metropolitan area). The following relevant parameters were included in the analysis: (1) climatological deviations from the desired indoor temperature as expressed in heating and cooling degree days, (2) efficiencies of heating and cooling appliances, and (3) efficiencies of power-generating plants. The results indicate that climate control in Minneapolis is about 3.5 times as energy demanding as in Miami. This finding suggests that, in the US, living in cold climates is more energy demanding than living in hot climates.

  7. Magnetic Interactions through Fluoride: Magnetic and Spectroscopic Characterization of Discrete, Linearly Bridged Mn-2(III)(mu-F)F-4(Me(3)tacn)(2) (PF6)

    DEFF Research Database (Denmark)

    Pedersen, K. S.; Sigrist, M.; Weihe, H.;

    2014-01-01

    The nature of the magnetic interaction through fluoride in a simple, dinuclear manganese(III) complex (1), bridged by a single fluoride ion in a perfectly linear fashion, is established by experiment and density functional theory. The magnitude of the antiferromagnetic exchange interaction...... and the manganese(III) zero-field-splitting parameters are unambiguously determined by inelastic neutron scattering to yield J = 33.0(2) cm(-1) ((H) over cap = J (S-1) over cap.(S-2) over cap Hamiltonian definition) and single-ion D = -4.0(1) cm(-1). Additionally, high-field, high-frequency electron paramagnetic...... resonance and magnetic measurements support the parameter values and resolve vertical bar E vertical bar approximate to 0.04 cm(-1). The exchange coupling constant (J) is 1 order of magnitude smaller than that found in comparable systems with linear oxide bridging but comparable to typical magnitudes...

  8. A Fiscal Analysis of Proposed Education Access Grants in Minneapolis. School Choice Issues in the State

    Science.gov (United States)

    Maas, Ericca

    2005-01-01

    This study examines the fiscal impact of model legislation that would create Education Access Grants in Minnesota. The legislation would provide grants for low-income students to attend private schools. Specifically, this study examines the effect of implementing Education Access Grants in Minneapolis, the state's largest metropolitan area. It…

  9. "Romeo and Juliet" in the Minneapolis Public Schools: Accurate Text or Bowdlerized Text?

    Science.gov (United States)

    Reed, Margaret A.

    In 1984, parents of a Minneapolis, Minnesota, ninth grader came before the school district's "Students' Right to Learn Committee" to object to what they described as a bowdlerized version of "Romeo and Juliet" in the Scott, Foresman text, and the publisher's failure to acknowledge in the text that the play was abridged. The committee concurred…

  10. Railroad Bridges

    Data.gov (United States)

    Department of Homeland Security — Bridges-Rail in the United States According to The National Bridge Inspection Standards published in the Code of Federal Regulations (23 CFR 650.3), a bridge isA...

  11. Heterotetranuclear oxalato-bridged Re(IV)3M(II) (M = Mn, Fe, Co, Ni, Cu) complexes: a new example of a single-molecule magnet (M = Ni).

    Science.gov (United States)

    Martínez-Lillo, José; Armentano, Donatella; De Munno, Giovanni; Wernsdorfer, Wolfgang; Clemente-Juan, Juan Modesto; Krzystek, J; Lloret, Francesc; Julve, Miguel; Faus, Juan

    2009-04-01

    The use of the mononuclear species (NBu(4))(2)[Re(IV)Cl(4)(ox)] (NBu(4)(+) = tetra-n-butylammonium cation; ox = oxalate dianion) as a ligand toward fully solvated divalent first-row transition-metal ions affords the tetranuclear complexes (NBu(4))(4)[{Re(IV)Cl(4)(mu-ox)}(3)M(II)] with M = Mn (1), Fe (2), Co (3), Ni (4), and Cu (5). Their structure is made up of discrete [{ReCl(4)(mu-ox)}(3)M](4-) anions and bulky NBu(4)(+) cations. The complexes 2-5 crystallize in the triclinic system with space group P1; 2 and 5 as well as 3 and 4 are isostructural. The Re and M atoms exhibit somewhat distorted ReCl(4)O(2) and MO(6) octahedral surroundings, with the oxalate groups adopting the bis-bidentate bridging mode. Magnetic susceptibility measurements on polycrystalline samples of 1-5 in the temperature range 1.9-300 K show the occurrence of intramolecular antiferromagnetic [J = -1.30 cm(-1) (1)] and ferromagnetic couplings [J = +1.62 (2), +3.0 (3), +16.3 (4), and +4.64 cm(-1) (5)], with the Hamiltonian being defined as H = -J[S(M)(S(Re1) + S(Re2) + S(Re3))]. Compound 4 is the first example of an oxalato-bridged heterometallic species that behaves as a single-molecule magnet with a ground-state spin S = (11)/(2) and D = -0.8(1) cm(-1), as shown by the study of its static and dynamic magnetic properties and a high-frequency electron paramagnetic resonance study on polycrystalline samples together with detailed micro-SQUID measurements on single crystals.

  12. Practical Stabilization Through Real-Time Optimal Control, ACC (2006; Minneapolis, Minnesota)

    OpenAIRE

    Ross, I. Michael; Gong, Qi; Fahroo, Fariba; Kang,Wei

    2006-01-01

    The article of record as published may be located at http://ieeexplore.ieee.org Approved for public display, distribution unlimited Proceedings of the 2006 American Control Conference ; Minneapolis, Minnesota, USA, June 14-16, 2006. Infinite-horizon, nonlinear, optimal, feedback control is one of the fundamental problems in control theory. In this paper we propose a solution for this problem based on recent progress in real-time optimal control. The basic idea is to perform feedback ...

  13. Synthesis and magneticproperties of one-dimensional Mn(Ⅱ) complexes linked bydithiooxalato

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    Three dithiooxalato (Dto) bridging one-dimensional Mn(Ⅱ) complexes [Mn(L)Dto](L = Phen (1), Bpy (2) and en (3)) were synthesized. All of the complexes have the similar one-dimensional structure through Dto bridge. The measurement of the variable temperature magnetic susceptibility of complex 1 showed that there are weak antiferromag- netic interactions between the Mn(Ⅱ) ions.

  14. Community exposure to asbestos from a vermiculite exfoliation plant in NE Minneapolis.

    Science.gov (United States)

    Kelly, James; Pratt, Gregory C; Johnson, Jean; Messing, Rita B

    2006-11-01

    Western Mineral Products/W. R. Grace operated a vermiculite plant in a mixed industrial/residential area of northeast Minneapolis from 1936 to 1989. The plant processed vermiculite ore contaminated with amphibole asbestos from a mine in Libby, MT. Air monitoring in the early 1970s found fiber concentrations in excess of 10 fibers per cubic centimeter of air (f/cc), indicating that worker exposure to asbestos was occasionally 100 times the current occupational standard. Residents of the surrounding community also had direct contact with vermiculite processing wastes (containing up to 10% amphibole asbestos) that were made freely available. Children played on waste piles and neighborhood residents hauled the wastes away for home use. In total, 259 contaminated residential properties have been found to date. Reported emission factors and plant process data were used as inputs to model airborne emissions from the plant over several operating scenarios using the U.S. Environmental Protection Agency (EPA) ISC-Prime model. Results estimate short-term air concentrations of asbestos fibers in residential areas nearest the plant may have at times exceeded current occupational standards. Exposure estimates for other pathways were derived primarily from assessments done in Libby by the U.S. EPA. The Northeast Minneapolis Community Vermiculite Investigation (NMCVI) was conducted by the Minnesota Department of Health to identify and characterize the exposures of a cohort of over 6000 people who live or lived in Northeast Minneapolis and may have been exposed to asbestos. This cohort is now being investigated in a respiratory health screening study conducted by the University of Minnesota and the Minnesota Department of Health.

  15. Water resources outlook for the Minneapolis-Saint Paul Metropolitan Area, Minnesota

    Science.gov (United States)

    Norvitch, R.F.; Ross, T.G.; Brietkrietz, Alex

    1973-01-01

    The water resources were studied within an area whose natural ground-water flow is largely towards the center of the metropolitan area. This area coincides with the extent of the Hinckley Sandstone aquifer. Thus, the general geohydrology of the area bounded by the extent of the Hinckley Sandstone (about 6,000 square miles) as it relates to the hydrology of the Minneapolis-St. Paul metropolitan area is described. Greater emphasis is placed on the area underlain by the Prairie du Chien-Jordan aquifer (about 2,000 square miles), from which approximately 75 percent of the ground-water for the metropolitan area is pumped.

  16. Myocardial Bridging

    Directory of Open Access Journals (Sweden)

    Shi-Min Yuan

    2016-02-01

    Full Text Available Abstract Myocardial bridging is rare. Myocardial bridges are most commonly localized in the middle segment of the left anterior descending coronary artery. The anatomic features of the bridges vary significantly. Alterations of the endothelial morphology and the vasoactive agents impact on the progression of atherosclerosis of myocardial bridging. Patients may present with chest pain, myocardial infarction, arrhythmia and even sudden death. Patients who respond poorly to the medical treatment with β-blockers warrant a surgical intervention. Myotomy is a preferred surgical procedure for the symptomatic patients. Coronary stent deployment has been in limited use due to the unsatisfactory long-term results.

  17. Enhancing the magnetic coupling of oxalato-bridged Re(IV)2M(II) (M=Mn, Co, Ni, and Cu) trinuclear complexes via peripheral halide ligand effects.

    Science.gov (United States)

    Martínez-Lillo, José; Mastropietro, Teresa F; De Munno, Giovanni; Lloret, Francesc; Julve, Miguel; Faus, Juan

    2011-06-20

    Four heterotrinuclear Re(IV)(2)M(II) compounds of general formula (NBu(4))(2)[{Re(IV)Br(4)(μ-ox)}(2)M(II)(Him)(2)] [NBu(4)(+) = tetra-n-butylammonium cation, ox = oxalate, Him = imidazole; M = Mn (1), Co (2), Ni (3), and Cu (4)] have been synthesized by using the novel mononuclear complex [Re(IV)Br(4)(ox)](2-) as a ligand toward divalent first-row transition metal ions in the presence of imidazole. Compounds 1-4 are isostructural complexes whose structure contains discrete trinuclear [{Re(IV)Br(4)(μ-ox)}(2)M(II)(Him)(2)](2-) anions and bulky NBu(4)(+) cations. The Re and M atoms are six-coordinated: four peripheral bromo and two oxalate-oxygens (at Re), and two cis-coordinated imidazole molecules and four oxygen atoms from two oxalate ligands (at M), build distorted octahedral surroundings. Two peripheral [ReBr(4)(ox)](2-) units act as bidentate ligands through the oxalate group toward the central [M(II)(Him)(2)] fragment affording the trinuclear entities. The values of the intramolecular Re···M separation are 5.62(1) (1), 5.51(1) (2), 5.46(1) (3), and 5.55(1) Å (4). Magnetic susceptibility measurements on polycrystalline samples of 1-4 in the temperature range of 1.9-300 K show the occurrence of intramolecular antiferro- [J = -1.1 cm(-1) (1)] and ferromagnetic interactions [J = +3.9 (2), +19.7 (3), and +14.4 cm(-1) (4)], the Hamiltonian being defined as Ĥ = -J [Ŝ(M)(Ŝ(Re1) + Ŝ(Re2))]. The larger spin delocalization on the oxalato bridge in 1-4 when compared to the trinuclear Re(IV)(2)M(II) complexes with chloro instead of bromo as peripheral ligands (1'-4') accounts for the strengthening of the magnetic interactions in 1-4 [J = -0.35 (1'), +14.2 (3'), and +7.7 cm(-1) (4')]. An incipient frequency dependence of the out-of-phase ac signals of 3 at very low temperatures is reminiscent of a system with slow relaxation of the magnetization, a phenomenon characteristic of single-molecule magnet behavior.

  18. Bridge Management Systems

    DEFF Research Database (Denmark)

    Thoft-Christensen, Palle

    In this paper bridge management systems are discussed with special emphasis on management systems for reinforced concrete bridges. Management systems for prestressed concrete bridges, steel bridges, or composite bridges can be developed in a similar way....

  19. 78 FR 29612 - Prevailing Rate Systems; Redefinition of the Minneapolis-St. Paul, MN, and Southwestern Wisconsin...

    Science.gov (United States)

    2013-05-21

    ... this change by consensus. FPRAC recommended no other changes in the geographic definitions of the... number of small entities because they will affect only Federal agencies and employees. List of Subjects..., Reporting and recordkeeping requirements, Wages. U.S. Office of Personnel Management. Elaine Kaplan,...

  20. EnviroAtlas - Minneapolis/St Paul, MN - Domestic Water Use per Day by U.S. Census Block Group

    Data.gov (United States)

    U.S. Environmental Protection Agency — As included in this EnviroAtlas dataset, the community level domestic water use is calculated using locally available water use data per capita in gallons of water...

  1. EnviroAtlas - Minneapolis/St. Paul, MN - Residents with Minimal Potential Window Views of Trees by Block Group

    Data.gov (United States)

    U.S. Environmental Protection Agency — This EnviroAtlas dataset shows the total block group population and the percentage of the block group population that has little access to potential window views of...

  2. 76 FR 38975 - Safety Zone; Upper Mississippi River, Mile 856.0 to 855.0, Minneapolis, MN

    Science.gov (United States)

    2011-07-05

    ... needed to protect participants and event personnel during the U.S. Wakeboard Nationals occurring on the... rulemaking (NPRM) process. The Coast Guard received notice of the U.S. Wakeboard Nationals event on May 11... safety hazards associated with a wakeboard competition. Basis and Purpose From July 20 through July...

  3. National Bridge Inventory (NBI) Bridges

    Data.gov (United States)

    Department of Homeland Security — The NBI is a collection of information (database) describing the more than 600,000 of the Nation's bridges located on public roads, including Interstate Highways,...

  4. Bridged graphite oxide materials

    Science.gov (United States)

    Herrera-Alonso, Margarita (Inventor); McAllister, Michael J. (Inventor); Aksay, Ilhan A. (Inventor); Prud'homme, Robert K. (Inventor)

    2010-01-01

    Bridged graphite oxide material comprising graphite sheets bridged by at least one diamine bridging group. The bridged graphite oxide material may be incorporated in polymer composites or used in adsorption media.

  5. Building Bridges

    DEFF Research Database (Denmark)

    The report Building Bridges adresses the questions why, how and for whom academic audience research has public value, from the different points of view of the four working groups in the COST Action IS0906 Transforming Audiences, Transforming Societies – “New Media Genres, Media Literacy and Trust...... in the Media”, “Audience Interactivity and Participation”, “The Role of Media and ICT Use for Evolving Social Relationships” and “Audience Transformations and Social Integration”. Building Bridges is the result of an ongoing dialogue between the Action and non-academic stakeholders in the field of audience...... Belgrade), Leo Pekkala (Finnish Centre for Media Education and Audiovisual Media/MEKU), Julie Uldam (Network on Civic Engagement and Social Innovation) and Gabriella Velics (Community Media Forum Europe)....

  6. Mathematical bridges

    CERN Document Server

    Andreescu, Titu; Tetiva, Marian

    2017-01-01

    Building bridges between classical results and contemporary nonstandard problems, Mathematical Bridges embraces important topics in analysis and algebra from a problem-solving perspective. Blending old and new techniques, tactics and strategies used in solving challenging mathematical problems, readers will discover numerous genuine mathematical gems throughout that will heighten their appreciation of the inherent beauty of mathematics. Most of the problems are original to the authors and are intertwined in a well-motivated exposition driven by representative examples. The book is structured to assist the reader in formulating and proving conjectures, as well as devising solutions to important mathematical problems by making connections between various concepts and ideas from different areas of mathematics. Instructors and educators teaching problem-solving courses or organizing mathematics clubs, as well as motivated mathematics students from high school juniors to college seniors, will find Mathematical Bri...

  7. Plastic Bridge

    Institute of Scientific and Technical Information of China (English)

    履之

    1994-01-01

    Already ubiquitous in homes and cars, plastic is now appearing inbridges. An academic-industrial consortium based at the University ofCalifornia in San Diego is launching a three-year research program aimed atdeveloping the world’s first plastic highway bridge, a 450-foot span madeentirely from glass-,carbon,and polymer-fiber-reinforced composite mate-rials, the stuff of military aircraft. It will cross Interstate 5 to connect thetwo sides of the school’s campus.

  8. Structure of the Mn complex in photosystem II: Insights from x-ray spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Yachandra, Vittal K.

    2002-04-02

    We have used Mn K-edge absorption and Kb emission spectroscopies to determine the oxidation states of the Mn complex in the various S-states. We have started exploring the new technique of resonant inelastic X-ray scattering spectroscopy (RIXS); this technique can be characterized as a Raman process that uses K-edge energies (1s to 4p, {approx}6550 eV) to obtain L-edge-like spectra (2p to 3d, {approx}650 eV). The relevance of these data to the oxidation states and structure of the Mn complex is presented. We have obtained EXAFS data from the S0 and S3 states and observed heterogeneity in the Mn-Mn distances, leading us to conclude that there may be three rather than two di-(mu)-oxo bridged units present per tetranuclear Mn cluster. In addition, we have obtained data using Ca/Sr X-ray spectroscopy that provide evidence for a heteronuclear Mn/Ca cluster. The possibility of three di-(mu)-oxo-bridged Mn Mn moieties and the proximity of Ca is incorporated into developing structural models for the Mn cluster. The involvement of bridging and terminal O ligands of Mn in the mechanism of oxygen evolution is discussed in the context of our X-ray spectroscopy results.

  9. Cable Supported Bridges

    DEFF Research Database (Denmark)

    Gimsing, Niels Jørgen

    Cable supported bridges in the form of suspension bridges and cable-stayed bridges are distinguished by their ability to overcome large spans.The book concentrates on the synthesis of cable supported bridges, covering both design and construction aspects. The analytical part covers simple methods...

  10. Bridges in Complex Networks

    CERN Document Server

    Wu, Ang-Kun; Liu, Yang-Yu

    2016-01-01

    A bridge in a graph is an edge whose removal disconnects the graph and increases the number of connected components. We calculate the fraction of bridges in a wide range of real-world networks and their randomized counterparts. We find that real networks typically have more bridges than their completely randomized counterparts, but very similar fraction of bridges as their degree-preserving randomizations. We define a new edge centrality measure, called bridgeness, to differentiate the importance of a bridge in damaging a network. We find that certain real networks have very large average and variance of bridgeness compared to their degree-preserving randomizations and other real networks. Finally, we offer an analytical framework to calculate the bridge fraction and average bridgeness for uncorrelated random networks with arbitrary degree distributions.

  11. Structures of Mn clusters

    Indian Academy of Sciences (India)

    Tina M Briere; Marcel H F Sluiter; Vijay Kumar; Yoshiyuki Kawazoe

    2003-01-01

    The geometries of several Mn clusters in the size range Mn13–Mn23 are studied via the generalized gradient approximation to density functional theory. For the 13- and 19-atom clusters, the icosahedral structures are found to be most stable, while for the 15-atom cluster, the bcc structure is more favoured. The clusters show ferrimagnetic spin configurations.

  12. Taizhou Yangtze River Bridge

    Institute of Scientific and Technical Information of China (English)

    2012-01-01

    Taizhou Bridge lies between Taizhou, Zhenjiang and Changzhou City in Jiangsu Province. The total length of Taizhou Bridge is 62.088 kin. The whole line is designed by freeway codes with six lanes in two directions. The wholeinvestment is 9.37 billion RMB and the planned construction duration is 5.5 years. The main bridge crossing the Yangtze River is a continuous three-pylon two-span suspension bridge with the main span of 1 080 m. The bridge system is realized for the first time and ranks first in the world until now.

  13. Peer review of the National Transportation Safety Board structural analysis of the I-35W bridge collapse.

    Energy Technology Data Exchange (ETDEWEB)

    Gwinn, Kenneth West; Redmond, James Michael; Wellman, Gerald William

    2008-10-01

    The Engineering Sciences Center at Sandia National Laboratories provided an independent peer review of the structural analysis supporting the National Transportation Safety Board investigation of the August 1, 2007 collapse of the I-35W Bridge in Minneapolis. The purpose of the review was to provide an impartial critique of the analysis approach, assumptions, solution techniques, and conclusions. Subsequent to reviewing numerous supporting documents, a SNL team of staff and management visited NTSB to participate in analysis briefings, discussions with investigators, and examination of critical elements of the bridge wreckage. This report summarizes the opinion of the review team that the NTSB analysis effort was appropriate and provides compelling supporting evidence for the NTSB probable cause conclusion.

  14. Sustainable Bridge Infrastructure Procurement

    DEFF Research Database (Denmark)

    Safi, Mohammed; Du, Guangli; Simonsson, Peter

    2016-01-01

    The lack of a flexible but systematic approach for integrating lifecycle aspects into bridge investment decisions is a major obstacle hindering the procurement of sustainable bridge infrastructures. This paper addresses this obstacle by introducing a holistic approach that agencies could use...... to procure the most “sustainable” (lifecycle-efficient) bridge through a fair design-build (D-B) tendering process, considering all the main aspects: life-cycle cost (LCC), service life-span, aesthetic demands and environmental impacts (LCA)....

  15. Bridge Crossing Simulator

    Science.gov (United States)

    2014-10-07

    Requirement BCS Computer-controlled hydraulic actuation system to impart simulated crossing loads on an entire bridge structure undergoing fatigue test ...structure. Bridge test site with prepared embankments corresponding to the span and bank condition requirements of the bridge under test Conduct real...Center (AEC). (5) Sample size and number of crossings required. The number of required simulated crossings to conduct fatigue testing per the

  16. Bridging the Gap

    OpenAIRE

    Kramer Overgaard, Majken; Broeng, Jes; Jensen, Monika Luniewska; Murdock, Karen; Schmidt, Iben Julie

    2015-01-01

    Bridging the Gap (BtG) is a 2-year project funded by The Danish Industry Foundation. The goal of Bridging the Gap has been to create a new innovation model which will increase the rate at which Danish universities can spinout new technology ventures. Bridging the Gap (BtG) is a 2-year project funded by The Danish Industry Foundation. The goal of Bridging the Gap has been to create a new innovation model which will increase the rate at which Danish universities can spinout new technology ve...

  17. Bridging the Gap

    DEFF Research Database (Denmark)

    Kramer Overgaard, Majken; Broeng, Jes; Jensen, Monika Luniewska;

    Bridging the Gap (BtG) is a 2-year project funded by The Danish Industry Foundation. The goal of Bridging the Gap has been to create a new innovation model which will increase the rate at which Danish universities can spinout new technology ventures.......Bridging the Gap (BtG) is a 2-year project funded by The Danish Industry Foundation. The goal of Bridging the Gap has been to create a new innovation model which will increase the rate at which Danish universities can spinout new technology ventures....

  18. Semiconductor bridge (SCB) detonator

    Science.gov (United States)

    Bickes, Jr., Robert W.; Grubelich, Mark C.

    1999-01-01

    The present invention is a low-energy detonator for high-density secondary-explosive materials initiated by a semiconductor bridge igniter that comprises a pair of electrically conductive lands connected by a semiconductor bridge. The semiconductor bridge is in operational or direct contact with the explosive material, whereby current flowing through the semiconductor bridge causes initiation of the explosive material. Header wires connected to the electrically-conductive lands and electrical feed-throughs of the header posts of explosive devices, are substantially coaxial to the direction of current flow through the SCB, i.e., substantially coaxial to the SCB length.

  19. Principles of Bridge Reliability

    DEFF Research Database (Denmark)

    Thoft-Christensen, Palle; Nowak, Andrzej S.

    The paper gives a brief introduction to the basic principles of structural reliability theory and its application to bridge engineering. Fundamental concepts like failure probability and reliability index are introduced. Ultimate as well as serviceability limit states for bridges are formulated...

  20. Unsaturated Mn complex decorated hybrid thioarsenates: Syntheses, crystal structures and physical properties

    Science.gov (United States)

    Yue, Cheng-Yang; Lei, Xiao-Wu; Tian, Ya-Wei; Xu, Jing; Bai, Yi-Qun; Wang, Fei; Zhou, Peng-Fei; Liu, Xiao-Fan; Yi, Fei-Yan

    2016-03-01

    The incorporation of unsaturated [Mn(1,2-dap)]2+, [Mn(1,2-dap)2]2+, [Mn(2,2-bipy)]2+ (1,2-dap=1,2-diaminopropane) complex cations with thioarsenate anions of [AsIIIS3]3- and [AsVS4]3- led to three new hybrid manganese thioarsenates, namely, [Mn(1,2-dap)]2MnAs2S6 (1), [Mn(1,2-dap)2]{[Mn(1,2-dap)]2As2S8} (2) and (NH4)[Mn(2,2-bipy)2]AsS4 (3). In compound 1, the unsaturated [Mn(1,2-dap)]2+ complexes, [MnS4]6- tetrahedra and [AsIIIS3]3- trigonal-pyramids are condensed to form the 1D [Mn(1,2-dap)]2MnAs2S6 chain, whereas compound 2 features 2D layer composed of [Mn(1,2-dap)]2+ and [Mn(1,2-dap)2]2+ complexes as well as [AsVS4]3- tetrahedral units. For compound 3, two [AsVS4]3- anions bridge two [Mn(2,2-bipy)]2+ complex cations into a butterfly like {[Mn(2,2-bipy)]2As2S8}2- anionic unit. Magnetic measurements indicate the ferrimagnetic behavior for compound 1 and antiferromagnetic (AF) behaviors for compounds 2-3. The UV-vis diffuse-reflectance measurements and electronic structural calculations based on density functional theory (DFT) revealed the title compounds belong to semiconductors with band gaps of 2.63, 2.21, and 1.97 eV, respectively. The narrow band-gap of compound 3 led to the efficient and stable photocatalytic degradation activity over organic pollutant than N-doped P25 under visible light irradiation.

  1. The supramolecular interaction mediated chiral 1D cyanide-bridged metamagnet: synthesis, crystal structures and magnetic properties.

    Science.gov (United States)

    Zhang, Daopeng; Bian, Yongzhong; Qin, Jie; Wang, Ping; Chen, Xia

    2014-01-21

    Two cyanide-bridged enantiopure one-dimensional single chain complexes, [Mn((R,R)-Salcy)Fe(pcq)(CN)3]2n·1.5nDMF (1) and [Mn((S,S)-Salcy)Fe(pcq)(CN)3]2n·1.5nDMF (2), have been synthesized and structurally characterized. Systematically magnetic investigations show the antiferromagnetic coupling between the cyanide-bridged Mn(III)-Fe(III) centers and the interesting metamagnetic behavior at about 5.0 K resulted from the intermolecular π-π interaction.

  2. Bridge technology report

    CERN Document Server

    2013-01-01

    Please note this is a Short Discount publication. As LANs have proliferated, new technologies and system concepts have come to the fore. One of the key issues is how to interconnect networks. One means of interconnection is to use a 'bridge'. Other competing technologies are repeaters, routers, and gateways. Bridges permit traffic isolation, connect network segments together and operate at the MAC layer. Further, because they operate at the MAC layer, they can handle a variety of protocols such as TCP/IP, SNA, and X.25. This report focuses on the specific technology of bridging two netw

  3. 1,1,1-Tris(hydroxymethyl)propane in manganese carboxylate chemistry: synthesis, structure and magnetic properties of a mixed-valence [MnIII4MnII4] cluster featuring the novel [MnIII4MnII4(mu3-OR)6(mu2-OR)8]6+ core.

    Science.gov (United States)

    Milios, Constantinos J; Fabbiani, Francesca P A; Parsons, Simon; Murugesu, Muralee; Christou, George; Brechin, Euan K

    2006-01-14

    The reaction between MnBr(2).4H(2)O with H(3)tmp (1,1,1-tris(hydroxymethyl)propane) in MeCN in the presence of Na(O(2)CCMe(3)) and NBu(4)Br produces the complex [Mn(8)(O(2)CCMe(3))(2)(tmp)(2)(Htmp)(4)Br(4)(H(2)O)(2)].2MeCN (1.2MeCN) in good yield. The centrosymmetric octanuclear molecule consists of four Mn(III) and four Mn(II) ions assembled together by fourteen alkoxo bridges to give a [Mn(III)(4)Mn(II)(4)(mu(3)-OR)(6)(mu(2)-OR)(8)](6+) rod-like core in which the metal centres are arranged in a planar zigzag fashion. Peripheral ligation is provided by a combination of bridging pivalate ions, terminal bromides and water molecules. Dc magnetic susceptibility measurements reveal the presence of dominant antiferromagnetic interactions leading to a spin ground state of S = 0. A rationalization of this result is attempted by structural comparison with previously reported tetranuclear manganese complexes containing the [Mn(III)(2)Mn(II)(2)(mu(3)-OR)(2)(mu(2)-OR)(4)] core in which the magnetic interactions are ferromagnetic.

  4. Bridged Race Population Estimates

    Data.gov (United States)

    U.S. Department of Health & Human Services — Population estimates from "bridging" the 31 race categories used in Census 2000, as specified in the 1997 Office of Management and Budget (OMB) race and ethnicity...

  5. Bridging Humanism and Behaviorism.

    Science.gov (United States)

    Chu, Lily

    1980-01-01

    Humanistic behaviorism may provide the necessary bridge between behaviorism and humanism. Perhaps the most humanistic approach to teaching is to learn how certain changes will help students and how these changes can be accomplished. (Author/MLF)

  6. Germ Cell Intercellular Bridges

    Science.gov (United States)

    Greenbaum, Michael P.; Iwamori, Tokuko; Buchold, Gregory M.; Matzuk, Martin M.

    2011-01-01

    Stable intercellular bridges are a conserved feature of gametogenesis in multicellular animals observed more than 100 years ago, but their function was unknown. Many of the components necessary for this structure have been identified through the study of cytokinesis in Drosophila; however, mammalian intercellular bridges have distinct properties from those of insects. Mammalian germ cell intercellular bridges are composed of general cytokinesis components with additional germ cell–specific factors including TEX14. TEX14 is an inactive kinase essential for the maintenance of stable intercellular bridges in gametes of both sexes but whose loss specifically impairs male meiosis. TEX14 acts to impede the terminal steps of abscission by competing for essential component CEP55, blocking its interaction in nongerm cells with ALIX and TSG101. Additionally, TEX14-interacting protein RBM44, whose localization in stabile intercellular bridges is limited to pachytene and secondary spermatocytes, may participate in processes such as RNA transport but is nonessential to the maintenance of intercellular bridge stability. PMID:21669984

  7. Long Span Bridges in Scandinavia

    DEFF Research Database (Denmark)

    Gimsing, Niels Jørgen

    1998-01-01

    The first Scandinavian bridge with a span of more than 500 m was the Lillebælt Suspension Bridge opened to traffic in 1970.Art the end of the 20th century the longest span of any European bridge is found in the Storebælt East Bridge with a main span of 1624 m. Also the third longest span in Europe...... is found in Scandinavia - the 1210 m span of the Höga Kusten Bridge in Sweden.The Kvarnsund Bridge in Norway was at the completion in 1991 the longest cable-stayed bridge in the world, and the span of 530 m is still thge longest for cable-stayed bridges in concrete. The Øresund Bridge with its sapn of 490...... m is the longest among cable-stayed bridges for both road and railway traffic....

  8. One-pot synthesis of an Mn(III)-Cu(II)-Mn(III) trinuclear heterometallic compound formed by Mn$\\cdots$S-Cu-S$\\cdots$Mn supramolecular interactions: Crystal structure of [{MnIII(salph)(H2O)}2{CuII(mnt)2}]$\\cdot$4DMF

    Indian Academy of Sciences (India)

    Vedichi Madhu; Samar K Das

    2006-11-01

    A one-pot synthesis, that includes CuCl2$\\cdot$2H2O, Na2mnt, H2salph and Mn(CH3COO)3$\\cdot$H2O, leads to the isolation of a trinuclear heterometallic compound [{MnIII(salph)(H2O)}2{CuII(mnt)2}]$\\cdot$4DMF (1) formed by Mn$\\cdots$S-Cu-S$\\cdots$Mn supramolecular interactions. Compound 1 crystallizes in the monoclinic space group 21/ with = 13.433(4), = 16.283(5), = 15.072(4) Å, = 107.785(4)°, = 2. In the crystal structure, the complex anion [CuII(mnt)2]2- bridges two [MnIII(salph)(H2O)]1+ cations through Mn$\\cdots$S contacts. The non-covalent hydrogen bonding and - interactions among the trinuclear [{MnIII(salph)(H2O)}2{CuII(mnt)2}] complexes lead to an extended chain-like arrangement of [MnIII(salph) (H2O)]1+ cations with [CuII(mnt)2]2- anions embedded in between these chains.

  9. The aesthetic composite bridge.

    Science.gov (United States)

    Feinman, R A

    1997-01-01

    New developments are constantly introduced in the search for the optimal treatment modality to restore a single anterior tooth. The patient attention has shifted to aesthetics of the restoration, biocompatibility of the dental materials utilized, conservative preparation of the teeth to be restored, and the retention of intact adjacent dentition. The learning objective of this article is to review the methods currently utilized and to present a recently introduced treatment modality--the two-component bridge, which combines the strength and resiliency of composite resin with the aesthetic advantages of porcelain. The technology of the material is reviewed, the predominantly lingual tooth preparation procedures are outlined, and the bridge try-in is described. The advantages of the two-component bridge are presented along with the contraindications and suggestions of careful case selection. Three cases with congenitally missing maxillary lateral incisors in youthful patients are presented to supplement the theoretical outline and to describe and illustrate the clinical procedure.

  10. Istanbul Bridge Conference 2014

    CERN Document Server

    Gülkan, Polat; Mahmoud, Khaled

    2016-01-01

      The book includes peer-reviewed contributions selected from presentations given at the Istanbul Bridge Conference 2014, held from August 11 – 13 in Istanbul, Turkey. It reports on the current challenges in bridge engineering faced by professionals around the globe, giving a special emphasis to recently developed techniques, innovations and opportunities. The book covers key topics in the field, including modeling and analysis methods; construction and erection techniques; design for extreme events and condition assessment and structural health monitoring. There is a balanced presentation of theory, research and practice. This book, which provides the readers with a comprehensive and timely reference guide on current practices in bridge engineering, is intended for professionals, academic researchers and students alike.

  11. Active Control of Suspension Bridges

    DEFF Research Database (Denmark)

    Thoft-Christensen, Palle

    In this paper some recent research on active control of very long suspension bridges, is presented. The presentation is based on research work at Aalborg University, Denmark. The active control system is based on movable flaps attached to the bridge girder. Wind load on bridges with or without...... flaps attached to the girder is briefly presented. A simple active control system is discussed. Results from wind tunnel experiments with a bridge section show that flaps can be used effectively to control bridge girder vibrations. Flutter conditions for suspension bridges with and without flaps...

  12. Structural stability, half-metallicity and magnetism of the CoFeMnSi/GaAs(0 0 1) interface

    Energy Technology Data Exchange (ETDEWEB)

    Feng, Yu; Chen, Xiaorui; Zhou, Ting; Yuan, Hongkuan; Chen, Hong, E-mail: chenh@swu.edu.cn

    2015-08-15

    Highlights: • CoFeMnSi is one of LiMgPbSb-type Heusler alloy. • The phase diagram of various investigated interfaces is calculated. • Top-type MnMn-terminated interface preserves perfect 100% spin polarization. - Abstract: The ferromagnet/semiconductor interface plays a crucial role in the performance of advanced magnetic tunnel junctions (MTJs) built of ferromagnetic electrodes and semiconductor as a spacer. We investigate the interface character between LiMgPbSb-type Heusler alloy CoFeMnSi and semiconductor GaAs by using the first-principles density functional simulations. In our calculations, we build two kinds of interface structures, namely the top-type and the bridge-type structure by connecting the termination of nine CoFeMnSi layers to the top of the As-terminated GaAs layer and the bridge site between interface As atoms, respectively. The calculated phase diagram indicated that the CoFe-terminated interface is more stable in the bridge-type structure than in the top-type structure, and a favored MnMn- or MnSi-terminated interface will appear in the top-type structure instead of the bridge-type structure under Fe-rich conditions. Besides, our calculation reveals that interface Mn and interface Fe atoms prefer to extend outward and their atom-resolved spin magnetic moments are enhanced due to the rehybridization caused by the symmetry breaking at the interface, while interface Co atoms shrink inward and their moments are decreased compared with the bulk value. Further analysis on DOS and PDOS indicates that owing to the interface effect, the half metallicity of CoFe-, MnSi-, and SiSi-terminated interfaces is completely destroyed. However, the MnMn-terminated interface in the top-type structure preserves 100% spin polarization, indicating that the CoFeMnSi/GaAs heterostructure with the top-type MnMn-terminated interface has more advantages than other atomic terminations in spintronics applications.

  13. A possible evolutionary origin for the Mn4 cluster of the photosynthetic water oxidation complex from natural MnO2 precipitates in the early ocean

    Energy Technology Data Exchange (ETDEWEB)

    Sauer, Kenneth; Yachandra, Vittal K.

    2002-04-30

    The photosynthetic water oxidation complex consists of a cluster of 4 Mn atoms bridged by O atoms, associated with Ca2+ and Cl- and incorporated into protein. The structure is similar in higher plants and algae, as well as in cyanobacteria of more ancient lineage, dating back more than 2.5 Ga on Earth. It has been proposed that the proto-enzyme derived from a component of a natural early marine manganese precipitate that contained a CaMn4O9 cluster. A variety of MnO2 minerals is found in nature. Three major classes are spinels, sheet-like layered structures and 3-dimensional networks that contain parallel tunnels. These relatively open structures readily incorporate cations (Na+, Li+, Mg2+, Ca2+, Ba2+, H+ and even Mn2+) and water. The minerals have different ratios of Mn(III) and Mn(IV) octahedrally coordinated to oxygens. Using X-ray spectroscopy we compare the chemical structures of Mn in the minerals with what is known about the arrangement in the water-oxidation complex to define the parameters of a structural model for the photosynthetic catalytic site. This comparison provides for the structural model a set of candidate Mn4 clusters -- some previously proposed and considered and others entirely novel.

  14. High-Resolution Mn EXAFS of the Oxygen-Evolving Complex inPhotosystem II: Structural Implications for the Mn4Ca Cluster

    Energy Technology Data Exchange (ETDEWEB)

    Yano, Junko; Pushkar, Yulia; Glatzel, Pieter; Lewis, Azul; Sauer,Kenneth; Messinger, Johannes; Bergmann, Uwe; Yachandra, Vittal

    2005-09-06

    The biological generation of oxygen by the oxygen-evolving complex in photosystem II (PS II) is one of natures most important reactions. The recent X-ray crystal structures, while limited by resolutions of 3.2 to 3.5 A, have located the electron density associated with the Mn4Ca complex within the multi-protein PS II complex. Detailed structures critically depend on input from spectroscopic techniques such as EXAFS and EPR/ENDOR, as the XRD resolution does not allow for accurate determination of the position of Mn/Ca or the bridging and terminal ligand atoms. The number and distances of Mn-Mn/Ca/ligand interactions determined from EXAFS provide important constraints for the structure of the Mn cluster. Here we present data from a high-resolution EXAFS method using a novel multi-crystal monochromator that show three short Mn-Mn distances between 2.7 and 2.8 A and hence the presence of three di-mu-oxobridged units in the Mn4Ca cluster. This result imposes clear limitations on the proposed structures based on spectroscopic and diffraction data and provides input for refining such structures.

  15. BUILDING "BRIDGES" WITH QUALITY ASSURANCE

    Science.gov (United States)

    The papr describes how, rather than building "bridges" across centuries, quality assurance (QA) personnel have the opportunity to build bridges across technical disciplines, between public and private organizations, and between different QA groups. As reviewers and auditors of a...

  16. Existing Steel Railway Bridges Evaluation

    Science.gov (United States)

    Vičan, Josef; Gocál, Jozef; Odrobiňák, Jaroslav; Koteš, Peter

    2016-12-01

    The article describes general principles and basis of evaluation of existing railway bridges based on the concept of load-carrying capacity determination. Compared to the design of a new bridge, the modified reliability level for existing bridges evaluation should be considered due to implementation of the additional data related to bridge condition and behaviour obtained from regular inspections. Based on those data respecting the bridge remaining lifetime, a modification of partial safety factors for actions and materials could be respected in the bridge evaluation process. A great attention is also paid to the specific problems of determination of load-caring capacity of steel railway bridges in service. Recommendation for global analysis and methodology for existing steel bridge superstructure load-carrying capacity determination are described too.

  17. DOE Information Bridge

    CERN Document Server

    United States. Department of Energy. Office of Scientific and Technical Information

    DOE Information Bridge, a component of EnergyFiles, provides free, convenient, and quick access to full-text DOE research and development reports in physics, chemistry, materials, biology, environmental sciences, energy technologies, engineering, computer and information science, renewable energy, and other topics. This vast collection includes over 43,000 reports that have been received and processed by OSTI since January 1995.

  18. Bridging the Technological Gap.

    Science.gov (United States)

    Lazow, Robert; And Others

    The aim of "Bridging the Technological Gap" (BTG), a federally funded demonstration project, is to use microcomputer technology in the rehabilitation of the psychiatrically disabled. Through the use of a custom designed microcomputer software package, clients receive remediation in areas of specific cognitive and behavioral deficits. The project…

  19. Bridging a Cultural Gap

    Science.gov (United States)

    Leviatan, Talma

    2008-01-01

    There has been a broad wave of change in tertiary calculus courses in the past decade. However, the much-needed change in tertiary pre-calculus programmes--aimed at bridging the gap between high-school mathematics and tertiary mathematics--is happening at a far slower pace. Following a discussion on the nature of the gap and the objectives of a…

  20. Bridge over troubled water?

    DEFF Research Database (Denmark)

    Svendsen, Gunnar Lind Haase; Nannestad, Peter; Svendsen, Gert Tinggaard

    2008-01-01

    The problem of integrating non-Western immigrants into Western welfare states is the focus of this paper. To address this issue, we suggest a social capital approach in which we apply the conceptual pair of bridging social capital (BR), which connects an individual to the broader social structure...

  1. Building a Straw Bridge

    Science.gov (United States)

    Teaching Science, 2015

    2015-01-01

    This project is for a team of students (groups of two or three are ideal) to design and construct a model of a single-span bridge, using plastic drinking straws as the building material. All steps of the design, construction, testing and critiquing stages should be recorded by students in a journal. Students may like to include labelled diagrams,…

  2. Building Bridges to China.

    Science.gov (United States)

    Wasta, Stephanie; Scott, Margaret

    1998-01-01

    Describes a theme cycle called "Building Bridges to China" developed for third grade students that focuses on the similarities between the lives of children and families in China and the United States. Explains that the theme cycle addresses the National Geography Standards and three of the National Council for the Social Studies standards. (CMK)

  3. The Bridges of Taishun County

    Institute of Scientific and Technical Information of China (English)

    MaJianhe

    2003-01-01

    The American film The Bridges of Madison County captured the imagination of many Chinese moviegoers with its bittersweet love story and scenes of rustic covered bridges. But the U.S. can't lay sole claim to such spectacular rural sights:China has its own county worldrenowned for unforgettable bridges.

  4. Revised Rules for Concrete Bridges

    DEFF Research Database (Denmark)

    Thoft-Christensen, Palle; Jensen, F. M.; Middleton, C.;

    This paper is based on research performed for the Highway Agency, London, UK under the project DPU/9/44 "Revision of Bridge Assessment Rules Based on Whole Life Performance: Concrete Bridges" It contains details of a methodology which can be used to generate Whole Life (WL) reliability profiles....... These WL reliability profiles may be used to establish revised rules for Concrete Bridges....

  5. Carboxylate-bridged helical chains based on an azo carboxylate oximate ligand

    Institute of Scientific and Technical Information of China (English)

    KOU HuiZhong; ZHANG YanDong; CUI AiLi

    2012-01-01

    Two helical one-dimensional complexes[MnⅡ(MeOH)4][MnⅣ(L·)2]· 2MeOH(1)and[MnⅢ(salen)][MnⅢ(L)2](2)(H2L =HON=C(Ph)N=NC6H4CO2H)contain the noninnocent ligand[Mn(L·)2]2- and innocent low-spin[Mn(L)2]-.Intrachain anfiferromagnetic interaction between adjacent manganese ions via the syn-anti carboxylate bridges in complex 1.Alternate syn-anti and anti-anti carboxylate bridges have been found to transmit ferro- and antiferromagnetic coupling between high-spin and low-spin Mn(Ⅲ)ions in complex 2.

  6. Energy levels of 56Mn

    DEFF Research Database (Denmark)

    Van Assche, P. H. M.; Baader, H. A.; Koch, H. R.

    1971-01-01

    The low-energy spectrum of the 55Mn(n,γ)56 Mn reaction has been studied with a γ-diffraction spectrometer. These data allowed the construction of a level scheme for 56Mn with two previously unobserved doublets. High-energy γ-transitions to the low-energy states have been measured for different...

  7. Dynamic Bridge Response for a Bridge-friendly Truck

    Directory of Open Access Journals (Sweden)

    V. Šmilauer

    2004-01-01

    Full Text Available A truck with controlled semi-active suspensions traversing a bridge is examined for benefits to the bridge structure. The original concept of a road-friendly truck was extended to a bridge-friendly vehicle, using the same optimization tools. A half-car model with two independently driven axles is coupled with simply supported bridges (beam, slab model with the span range from 5 m to 50 m. Surface profile of the bridge deck is either stochastic or in the shape of a bump or a pot in the mid-span. Numerical integration in the MATLAB/SIMULINK environment solves coupled dynamic equations of motion with optimized truck suspensions. The rear axle generates the prevailing load and to a great extent determines the bridge response. A significant decrease in contact road-tire forces is observed and the mid-span bridge deflections are on average smaller, when compared to commercial passive suspensions. 

  8. Interface characteristics in Co{sub 2}MnSi/Ag/Co{sub 2}MnSi trilayer

    Energy Technology Data Exchange (ETDEWEB)

    Li, Yang [School of Physical Science and Technology, Southwest University, Chongqing 400715 (China); Department of Physics, Chongqing University of Arts and Sciences, Chongqing 402160 (China); Chen, Hong, E-mail: chenh@swu.edu.cn [School of Physical Science and Technology, Southwest University, Chongqing 400715 (China); Wang, Guangzhao; Yuan, Hongkuan [School of Physical Science and Technology, Southwest University, Chongqing 400715 (China)

    2016-05-15

    Highlights: • Inferface DO{sub 3} disorder is most favorable in Co{sub 2}MnSi/Ag/Co{sub 2}MnSi trilayer. • Interface itself and inferface DO{sub 3} disorder destroy the half-metallicity of interface layers. • Magnetoresistance is reduced by the interface itself and interface disorder. • Magnetotransport coefficient is largely reduced by the interface itself and interface disorder. - Abstract: Interface characteristics of Co{sub 2}MnSi/Ag/Co{sub 2}MnSi trilayer have been investigated by means of first-principles. The most likely interface is formed by connecting MnSi-termination to the bridge site between two Ag atoms. As annealed at high temperature, the formation of interface DO{sub 3} disorder is most energetically favorable. The spin polarization is reduced by both the interface itself and interface disorder due to the interface state occurs in the minority-spin gap. As a result, the magneto-resistance ratio has a sharp drop based on the estimation of a simplified modeling.

  9. Structural Changes in the Mn4Ca Cluster and the Mechanism of Photosynthetic Water Splitting

    Energy Technology Data Exchange (ETDEWEB)

    Pushkar, Y.; Yano, J.; Sauer, K.; Boussac, A.; Yachandra, V.K.

    2007-10-25

    Photosynthetic water oxidation, where water is oxidized to dioxygen, is a fundamental chemical reaction that sustains the biosphere. This reaction is catalyzed by a Mn4Ca complex in the photosystem II (PS II) oxygen-evolving complex (OEC): a multiproteinassembly embedded in the thylakoid membranes of green plants, cyanobacteria, and algae. The mechanism of photosynthetic water oxidation by the Mn4Ca cluster in photosystem II is the subject of much debate, although lacking structural characterization of the catalytic intermediates. Biosynthetically exchanged Ca/Sr-PS II preparations and x-ray spectroscopy, including extended x-ray absorption fine structure (EXAFS), allowed us to monitor Mn-Mn and Ca(Sr)-Mn distances in the four intermediate S states, S0 through S3, of the catalytic cycle that couples the one-electron photochemistry occurring at the PS II reaction center with the four-electron water-oxidation chemistry taking place at the Mn4Ca(Sr) cluster. We have detected significant changes in the structure of the complex, especially in the Mn-Mn and Ca(Sr)-Mn distances, on the S2-to-S3 and S3-to-S0 transitions. These results implicate the involvement of at least one common bridging oxygen atom between the Mn-Mn and Mn-Ca(Sr) atoms in the O-O bond formation. Because PS II cannot advance beyond the S2 state in preparations that lack Ca(Sr), these results show that Ca(Sr) is one of the critical components in the mechanism of the enzyme. The results also show that Ca is not just a spectator atom involved in providing a structural framework, but is actively involved in the mechanism of water oxidation and represents a rare example of a catalytically active Ca cofactor.

  10. Simulation of multivariate diffusion bridges

    DEFF Research Database (Denmark)

    Bladt, Mogens; Finch, Samuel; Sørensen, Michael

    We propose simple methods for multivariate diffusion bridge simulation, which plays a fundamental role in simulation-based likelihood and Bayesian inference for stochastic differential equations. By a novel application of classical coupling methods, the new approach generalizes a previously...... proposed simulation method for one-dimensional bridges to the mulit-variate setting. First a method of simulating approzimate, but often very accurate, diffusion bridges is proposed. These approximate bridges are used as proposal for easily implementable MCMC algorithms that produce exact diffusion bridges...

  11. Bridging Classroom Language Ethnography

    OpenAIRE

    GRENFELL, MICHAEL JAMES

    2012-01-01

    PUBLISHED Paper #5: Bridging Classroom Language Ethnography, New Literacy Studies and Bourdieu?s Social Philosophy: Principles and Practice The purpose of this paper is to analyze and synthesize the various ways that classroom language ethnography, NLS, and Bourdieu?s social philosophy, were integrated. The goal of the analysis and synthesis is to provide a fresh perspective and fruitful insights on literacy in all its manifestations that provides the foundations for a more robust...

  12. Bridging as Coercive Accommodation

    CERN Document Server

    Bos, J W; Mineur, A M; Bos, Johan; Buitelaar, Paul; Mineur, Anne-Marie

    1995-01-01

    In this paper we discuss the notion of "bridging" in Discourse Representation Theory as a tool to account for discourse referents that have only been established implicitly, through the lexical semantics of other referents. In doing so, we use ideas from Generative Lexicon theory, to introduce antecedents for anaphoric expressions that cannot be "linked" to a proper antecedent, but that do not need to be "accommodated" because they have some connection to the network of discourse referents that is already established.

  13. An intramolecular antiferromagnetically coupled pentanuclear Mn(II) cluster containing acetate and tetracarboxylate linkers: Synthesis, structure and magnetism

    Science.gov (United States)

    Wu, Jian; Liu, Wei-Cong; Wu, Xi-Ren; Liu, Jian-Qiang; Sakiyama, Hiroshi; Yadav, Reena; Kumar, Abhinav

    2016-06-01

    A new Mn(II) complex {[Mn5(CH3COO)2(L)2(DMF)8](DMF)}n (1), (H4L = 3,5-bis(3‧,5‧-dicarboxylphenyl)-1H-1,2,3-triazole), has been synthesized and structurally characterized. The complex 1 have pentanuclear Mn(II) core, where the two sides of metal centers (Mn2 and Mn3) have trigonal bipyramidal arrangement and the middle metal center (Mn1) have octahedral environment utilizing two O atoms from adjacent bridging bidentate carboxylate groups and four O atoms from four coordinated DMF molecules. The planar arrangement of pentanuclear Mn(II) atoms are linked by L linkage to generate two dimensional sheet. The magnetic property of the compound indicates χMT value for the five Mn(II) unit to be 21.3 cm3 K mol-1 at 300 K, which is close to the spin-only value (21.9 cm3 K mol-1) for the pentamer having S = 5/2. Also, the Hirshfeld surface analyses have been performed which indicated the absence of weak Mn···Mn interaction thereby corroborating the results of observed magnetic properties.

  14. Mn bioavailability by polarized Caco-2 cells: comparison between Mn gluconate and Mn oxyprolinate

    Directory of Open Access Journals (Sweden)

    Fulgenzi Alessandro

    2011-07-01

    Full Text Available Abstract Background Micronutrient inadequate intake is responsible of pathological deficiencies and there is a need of assessing the effectiveness of metal supplementation, frequently proposed to rebalance poor diets. Manganese (Mn is present in many enzymatic intracellular systems crucial for the regulation of cell metabolism, and is contained in commercially available metal supplements. Methods We compared the effects of two different commercial Mn forms, gluconate (MnGluc and oxyprolinate (MnOxP. For this purpose we used the polarized Caco-2 cells cultured on transwell filters, an established in vitro model of intestinal epithelium. Since micronutrient deficiency may accelerate mitochondrial efficiency, the mitochondrial response of these cells, in the presence of MnGluc and MnOxP, by microscopy methods and by ATP luminescence assay was used. Results In the presence of both MnOxP and MnGluc a sustained mitochondrial activity was shown by mitoTraker labeling (indicative of mitochondrial respiration, but ATP intracellular content remained comparable to untreated cells only in the presence of MnOxP. In addition MnOxP transiently up-regulated the antioxidant enzyme Mn superoxide dismutase more efficiently than MnGluc. Both metal treatments preserved NADH and βNADPH diaphorase oxidative activity, avoided mitochondrial dysfunction, as assessed by the absence of a sustained phosphoERK activation, and were able to maintain cell viability. Conclusions Collectively, our data indicate that MnOxP and MnGluc, and primarily the former, produce a moderate and safe modification of Caco-2 cell metabolism, by activating positive enzymatic mechanisms, thus could contribute to long-term maintenance of cell homeostasis.

  15. Vulnerability of bridges to fire

    DEFF Research Database (Denmark)

    Giuliani, Luisa; Crosti, C.; Gentili, F.

    2012-01-01

    Even if recent effort in developing methodology and measures for design structures against fire and explosions has been mostly focused on buildings, bridges can also be very sensitive to those actions, as witnesses by some recent bridge accidents, which caused major economic losses and also...... endangered people safety in few cases. Purpose of this paper is making a focus on the state of the art of the research and current regulations concerning the response of bridges to fire. Several cases of bridge fires are reported and a focus is made on the occurrence and consequence of bridge fires......, considering both the costs deriving by structural damages and by limited serviceability and other indirect societal aspects. Few cases of recent bridge fire are reviewed in detail and structural consequences are highlighted, distinguishing between damages directly induced by fire and damages induced by local...

  16. Unsaturated Mn complex decorated hybrid thioarsenates: Syntheses, crystal structures and physical properties

    Energy Technology Data Exchange (ETDEWEB)

    Yue, Cheng-Yang [Key Laboratory of Inorganic Chemistry in Universities of Shandong, Department of Chemistry and Chemical Engineering, Jining University, Qufu, Shandong 273155 (China); State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002 (China); Lei, Xiao-Wu, E-mail: xwlei_jnu@163.com [Key Laboratory of Inorganic Chemistry in Universities of Shandong, Department of Chemistry and Chemical Engineering, Jining University, Qufu, Shandong 273155 (China); Tian, Ya-Wei; Xu, Jing; Bai, Yi-Qun; Wang, Fei; Zhou, Peng-Fei; Liu, Xiao-Fan [Key Laboratory of Inorganic Chemistry in Universities of Shandong, Department of Chemistry and Chemical Engineering, Jining University, Qufu, Shandong 273155 (China); Yi, Fei-Yan, E-mail: yifeiyan@nbu.edu.cn [Faculty of Materials Science & Chemical Engineering, Ningbo University, Ningbo, Zhejiang 315211 (China)

    2016-03-15

    The incorporation of unsaturated [Mn(1,2-dap)]{sup 2+}, [Mn(1,2-dap){sub 2}]{sup 2+}, [Mn(2,2-bipy)]{sup 2+} (1,2-dap=1,2-diaminopropane) complex cations with thioarsenate anions of [As{sup III}S{sub 3}]{sup 3−} and [As{sup V}S{sub 4}]{sup 3−} led to three new hybrid manganese thioarsenates, namely, [Mn(1,2-dap)]{sub 2}MnAs{sub 2}S{sub 6} (1), [Mn(1,2-dap){sub 2}]{[Mn(1,2-dap)]_2As_2S_8} (2) and (NH{sub 4})[Mn(2,2-bipy){sub 2}]AsS{sub 4} (3). In compound 1, the unsaturated [Mn(1,2-dap)]{sup 2+} complexes, [MnS{sub 4}]{sup 6−} tetrahedra and [As{sup III}S{sub 3}]{sup 3−} trigonal-pyramids are condensed to form the 1D [Mn(1,2-dap)]{sub 2}MnAs{sub 2}S{sub 6} chain, whereas compound 2 features 2D layer composed of [Mn(1,2-dap)]{sup 2+} and [Mn(1,2-dap){sub 2}]{sup 2+} complexes as well as [As{sup V}S{sub 4}]{sup 3−} tetrahedral units. For compound 3, two [As{sup V}S{sub 4}]{sup 3−} anions bridge two [Mn(2,2-bipy)]{sup 2+} complex cations into a butterfly like {[Mn(2,2-bipy)]_2As_2S_8}{sup 2−} anionic unit. Magnetic measurements indicate the ferrimagnetic behavior for compound 1 and antiferromagnetic (AF) behaviors for compounds 2–3. The UV–vis diffuse-reflectance measurements and electronic structural calculations based on density functional theory (DFT) revealed the title compounds belong to semiconductors with band gaps of 2.63, 2.21, and 1.97 eV, respectively. The narrow band-gap of compound 3 led to the efficient and stable photocatalytic degradation activity over organic pollutant than N-doped P25 under visible light irradiation. - Highlights: Three new hybrid manganese thioarsenates have been prepared and structurally characterized. These hybrid phases feature interesting magnetic and visible light responding photocatalytic properties.

  17. Morphological aspects of myocardial bridges.

    Science.gov (United States)

    Lujinović, Almira; Kulenović, Amela; Kapur, Eldan; Gojak, Refet

    2013-11-01

    Although some myocardial bridges can be asymptomatic, their presence often causes coronary disease either through direct compression of the "tunnel" segment or through stimulation and accelerated development of atherosclerosis in the segment proximally to the myocardial bridge. The studied material contained 30 human hearts received from the Department of Anatomy. The hearts were preserved 3 to 5 days in 10% formalin solution. Thereafter, the fatty tissue was removed and arterial blood vessels prepared by careful dissection with special reference to the presence of the myocardial bridges. Length and thickness of the bridges were measured by the precise electronic caliper. The angle between the myocardial bridge fibre axis and other axis of the crossed blood vessel was measured by a goniometer. The presence of the bridges was confirmed in 53.33% of the researched material, most frequently (43.33%) above the anterior interventricular branch. The mean length of the bridges was 14.64 ± 9.03 mm and the mean thickness was 1.23 ± 1.32 mm. Myocardial bridge fibres pass over the descending blood vessel at the angle of 10-90 degrees. The results obtained on a limited sample suggest that the muscular index of myocardial bridge is the highest for bridges located on RIA, but that the difference is not significant in relation to bridges located on other branches. The results obtained suggest that bridges located on other branches, not only those on RIA, could have a great contractive power and, consequently, a great compressive force, which would be exerted on the wall of a crossed blood vessel.

  18. Modular FRP Composite Bridge Deck

    OpenAIRE

    ECT Team, Purdue

    2007-01-01

    The bridge infrastructure of the United States is in constant need of repair and rehabilitation. It is reported that 43% of the bridges in the USA have been identified as being structurally deficient or functionally obsolete due to corrosion. SuperdeckTM, a non-corrosive fiber reinforced polymer (FRP) composite bridge deck. The Deck is designed and engineered into a lightweight, strong and rigid structure that will not corrode. The deck sections, composed of hexagon and double-trapezoid profi...

  19. Synthesis and Magnetic Studies of Copper ( Ⅱ )-Manganese (Ⅱ)Heterobinuclear Complexes with an Oxamido Bridge

    Institute of Scientific and Technical Information of China (English)

    LI, Yan-Tuan; YAN, Cui-Wei; LIAO, Dai-Zheng

    2001-01-01

    Four new copper ( Ⅱ )-manganese ( Ⅱ ) beterobinuclear complexes bridged by N, N' -bis[ 2- (dimethylamino) ethyl) ] oxamido dianion (dmoxae) and end-capped with 1,10-phenanthroline (phen), 5-methyl-1, l0-phenanthroline (Mephen), diaminoethane (en) or 1,3-di-aminopropane (pn), respectively, namely, [Cu(dmoxae)MnL2](CO4)2 (L= phen, Mephen, en, pn), have been synthesized and characterized by elemental analyses, IR, electronic spectral studies, and molar conductivity measurements. The electronic reflectance spectrum indicates the presence of spin exchange-coupling interaction between bridged copper (Ⅱ) and manganese (Ⅱ) ions.The cryomagnetic measurements (4.2-300 K) of [ Cu(dmoxae)Mn(phen)2](ClO4)2 ( 1 ) and [Cu(dmoxae)Mn(Mephen)2](ClO4)2(2) complexes demonstrated an antiferromagnetic interaction between the adjacent manganese(Ⅱ) and copper (Ⅱ) ions through the oxamido-bridge within each molecule. On the basis of spin Hamiltonian, H^ = - 2JS^1·S^2,the magnetic analysis was carried out for the two complexes and the spin-coupling constant (J) was evaluated as - 35.9cm-1 for 1 and - 32.6 cm-1 for 2. The influence of methyl substitutions in the amine groups of the bridging ligand on magnetic interactions between the metal ions of this kind of complexes is also discussed.

  20. Modelling railway bridge asset management

    OpenAIRE

    Le, Bryant Linh Hai

    2014-01-01

    The UK has a long history in the railway industry with a large number of railway assets. Railway bridges form one of the major asset groups with more than 35,000 bridges. The majority of the bridge population are old being constructed over 100 years ago. Many of the bridges were not designed to meet the current network demand. With an expected increasing rate of deterioration due to the increasing traffic loads and intensities, the management authorities are faced with the difficult task of k...

  1. Synthesis and Reaction of [MnRe(CO)6(μ-SH)(μ-SC(H)PPri3)(PPh3)

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    The synthesis, the crystal structure and the reaction of the hetero-binuclear complex [MnRe(CO)6(μ-SH)(μ-SC(H)PPri3)(PPh3)] are reported. The results of single crystal X-ray structure analysis showed that the fragments Mn(CO)3 and Re(CO)3 were bridged by SH and SC(H)PPri3. The title complexes can react with BunLi and RX forming complexes MnRe(CO)6(μ-SR)(μ-SC(H)PPri3)(PPh3) (R = Me, CH2CH=CH2, SnBu3n).

  2. A Mn-54 Radiotracer Study of Mn Isotope Solid-Liquid Exchange during Reductive Transformation of Vernadite (δ-MnO₂) by Aqueous Mn(II)

    Energy Technology Data Exchange (ETDEWEB)

    Elzinga, Evert J.; Kustka, Adam B. [Rutgers

    2015-04-09

    We employed Mn-54 radiotracers to characterize the extent and dynamics of Mn atom exchange between aqueous Mn(II) and vernadite (δ-Mn(IV)O2) at pH 7.5 under anoxic conditions. Exchange of Mn atoms between the solid and liquid phase is rapid, reaching dynamic equilibrium in 2–4 days. We propose that during the initial stages of reaction, Mn atom exchange occurs through consecutive comproportionation-disproportionation reactions where interfacial electron transfer from adsorbed Mn(II) to lattice Mn(IV) generates labile Mn(III) cations that rapidly disproportionate to reform aqueous Mn(II) and solid-phase Mn(IV). Following nucleation of Mn(III)OOH phases, additional exchange likely occurs through electron transfer from aqueous Mn(II) to solid-phase Mn(III). Our results provide evidence for the fast and extensive production of transient Mn(III) species at the vernadite surface upon contact of this substrate with dissolved Mn(II). We further show that HEPES buffer is a reductant of lattice Mn(IV) in the vernadite structure in our experiments. The methods and results presented here introduce application of Mn-54 tracers as a facile tool to further investigate the formation kinetics of labile Mn(III) surface species and their impacts on Mn-oxide structure and reactivity over a range of environmentally relevant geochemical conditions.

  3. London Bridge Is Shaking Funny

    Institute of Scientific and Technical Information of China (English)

    1995-01-01

    Bridges generally don’t fall down without warning;they crack first. Searching for cracks is a tedious business,though, and bridge inspectors bave been known to miss them. Charles Farrar,a civil engineer at Los Alamos Na-

  4. Fatigue tests on aluminium bridges

    NARCIS (Netherlands)

    Maljaars, J.; Soetens, F.; Straalen, IJ.J. van

    2004-01-01

    Traffic bridges are subjected to variable loads and should therefore be checked on fatigue. Especially low weight materials, like aluminium, are sensitive to fatigue, because the variable load is a substantial part of the total load. This paper shows the structural design of an aluminium bridge load

  5. Fatigue tests on aluminium bridges

    NARCIS (Netherlands)

    Maljaars, J.; Soetens, F.; Straalen, IJ.J. van

    2005-01-01

    Traffic bridges are subjected to variable loads and should therefore be checked on fatigue. Especially low weight materials, like aluminium, are sensitive to fatigue, because the variable load is a substantial part of the total load. This paper shows the structural design of an aluminium bridge load

  6. Syntheses, structures and magnetic properties of four-spin Mn-Imino nitroxide radical complexes

    Science.gov (United States)

    Lv, Xue-Hui; Yang, Shuai-Liang; Li, Yuan-Xia; Zhang, Chen-Xi; Wang, Qing-Lun

    2017-04-01

    Based on the nitroxide radicals, four-spin complexes [Mn(hfac)2(IMpPhCl)]2·NITpPhCl (1) and [Mn(hfac)2(IMmPhCl)]2·NITmPhCl (2) (IMpPhCl = 2-(4'-chlorophenyl)-4,4,5,5-tetramethylimidazoline-1-oxyl, IMmPhCl = 2-(3'-chlorophenyl)-4,4,5,5-tetramethylimidazoline-1-oxyl, hfac = hexafluoroacetylacetonate) have been synthesized and characterized by single-crystal X-ray diffraction. The X-ray crystal structure analyses show that the structures of the two compounds are similar and the imino nitroxide radical ligand acts as a bridge ligand linking two Mn(II) ions through the oxygen atom of the N-O group to form a four-spin system. Two kinds of nitroxide radicals: nitronyl nitroxide and imino nitroxide radicals coexist in the cyclic Mn(II) complexes. The magnetic studies show that there exists an antiferromagnetic interaction between Mn(II) ions and the imino nitroxide radical ligands, which is explained by spin polarization mechanism. The antiferromagnetic interaction of Mn-Rad in complex 2 (J1 = -9.36 cm-1) is stronger than that in complex 1 (J1 = -9.19 cm-1), which is consistent with crystal structure of complexes (The bond length of the shortest Mn-O in complex 2 (2.1625 Å) is smaller than complex 1 (2.1898 Å)).

  7. Development of cooperative system bridges

    Institute of Scientific and Technical Information of China (English)

    ZHANG Zhe; WAN Qi-bai; SHI Lei

    2008-01-01

    Cooperative system bridges comprise several basic structures that act jointly to improve structural characteristics. We delved into the historical development of cooperative system bridges. Cooperative systems are classified as different-load cooperative systems and same-load cooperative systems by distinguishing the modes of load distribution. For different-load cooperation, individual basic structures are at different positions in the direction along bridge axis and carry the loads separately. While for same-load cooperation, all basic structures overlap in geometrical locations and support the entire loads conjointly. The choosing of span ratios between basic structures, the design of connections of different-load cooperative systems were discussed as well as optimizations of relative rigidity for same-load cooperative systems which greatly influence structural characteristics. The general situation and several structural measurements of several cooperative bridges were demonstrated. This information can assist engineers in developing their concepts in cooperative systems and can lead to more efficient and economical cooperative bridges.

  8. Magnetocaloric effect and slow magnetic relaxation in two only azido bridged ferromagnetic tetranuclear metal clusters.

    Science.gov (United States)

    Zhao, Jiong-Peng; Zhao, Ran; Yang, Qian; Hu, Bo-Wen; Liu, Fu-Chen; Bu, Xian-He

    2013-10-28

    Two M(II) tetranuclear complexes bridged only by azido, Mn4(N3)(7.3)Cl(0.7)L4 (1) and Co4(N3)8L4 (2) in which the four M(II) ions are precisely coplanar bridged only by six azido anions, were obtained by using 4,5-diazafluoren-9-one (L) as a corner ligand. Magnetic studies indicate that ferromagnetic coupling was conducted by the azido anions between M(II) ions. At low temperature, 1 exhibits a large magnetocaloric effect and 2 shows field-induced multiple magnetic relaxations.

  9. Linguistic Barriers and Bridges

    DEFF Research Database (Denmark)

    Thuesen, Frederik

    2016-01-01

    and intercultural communication, this article analyses interviews with 31 employees from two highly ethnically diverse Danish workplaces. The article shows how linguistic barriers such as different levels of majority language competence and their consequent misunderstandings breed mistrust and hostility, whilst......The influence of language on social capital in low-skill and ethnically diverse workplaces has thus far received very limited attention within the sociology of work. As the ethnically diverse workplace is an important social space for the construction of social relations bridging different social...... groups, the sociology of work needs to develop a better understanding of the way in which linguistic diversity influences the formation of social capital, i.e. resources such as the trust and reciprocity inherent in social relations in such workplaces. Drawing on theories about intergroup contact...

  10. Looking Beyond the Bridge

    DEFF Research Database (Denmark)

    Jahn, Elke; Rosholm, Michael

    We perform a comprehensive analysis of the stepping-stone effect of temporary agency employment on unemployed workers. Using the timing-of-events approach, we not only investigate whether agency employment is a bridge into regular employment but also analyze its effect on post-unemployment wages ...... is even more effective in tight labor markets, where firms use agency employment primarily to screen po-tential candidates for permanent posts. Finally, our results suggest that agency employment may improve subsequent match quality in terms of wages and job duration....... and job stability for unemployed Danish workers. We find evidence of large positive treatment effects, particularly for immigrants. There is also some indication that higher treatment intensity increases the likelihood of leav-ing unemployment for regular jobs. Our results show that agency employment...

  11. Cascaded resonant bridge converters

    Science.gov (United States)

    Stuart, Thomas A. (Inventor)

    1989-01-01

    A converter for converting a low voltage direct current power source to a higher voltage, high frequency alternating current output for use in an electrical system where it is desired to use low weight cables and other circuit elements. The converter has a first stage series resonant (Schwarz) converter which converts the direct current power source to an alternating current by means of switching elements that are operated by a variable frequency voltage regulator, a transformer to step up the voltage of the alternating current, and a rectifier bridge to convert the alternating current to a direct current first stage output. The converter further has a second stage series resonant (Schwarz) converter which is connected in series to the first stage converter to receive its direct current output and convert it to a second stage high frequency alternating current output by means of switching elements that are operated by a fixed frequency oscillator. The voltage of the second stage output is controlled at a relatively constant value by controlling the first stage output voltage, which is accomplished by controlling the frequency of the first stage variable frequency voltage controller in response to second stage voltage. Fault tolerance in the event of a load short circuit is provided by making the operation of the first stage variable frequency voltage controller responsive to first and second stage current limiting devices. The second stage output is connected to a rectifier bridge whose output is connected to the input of the second stage to provide good regulation of output voltage wave form at low system loads.

  12. Cubane-type Cu(II)4 and Mn(II)2Mn(III)2 complexes based on pyridoxine: a versatile ligand for metal assembling.

    Science.gov (United States)

    Marino, Nadia; Armentano, Donatella; Mastropietro, Teresa F; Julve, Miguel; De Munno, Giovanni; Martínez-Lillo, José

    2013-10-21

    By using Vitamin B6 in its monodeprotonated pyridoxine form (PN-H) [PN = 3-hydroxy-4,5-bis(hydroxymethyl)-2-methylpyridine], two tetranuclear compounds of formula [Mn4(PN-H)4(CH3CO2)3Cl2]Cl·2CH3OH·2H2O (1) and [Cu4(PN-H)4Cl2(H2O)2]Cl2 (2) have been synthesized and magneto-structurally characterized. 1 crystallizes in the triclinic system with space group P1 whereas 2 crystallizes in the orthorhombic system with Fdd2 as space group. They exhibit Mn(II)2Mn(III)2 (1) and Cu(II)4 (2) cubane cores containing four monodeprotonated pyridoxine groups simultaneously acting as chelating and bridging ligands (1 and 2), three bridging acetate ligands in the syn-syn conformation (1), and two terminally bound chloride anions (1 and 2) plus two coordinated water molecules (2). The electroneutrality is achieved by the presence of chloride counterions in both compounds. Tri- [Mn(1) and Mn(3)] and divalent [Mn(2) and Mn(4)] manganese centers coexist in 1, all being six-coordinate with distorted Mn(1/3)O6 and Mn(2/4)O5Cl octahedral surroundings, respectively, the equatorial Mn-O bonds being about 0.2 Å shorter at the former ones. The two crystallographically independent copper(II) ions in 2 are five-coordinate in somewhat distorted CuO5 [Cu(1)] and CuO4Cl [Cu(2)] square pyramidal geometries. The values of the intracore metal-metal separation cover the ranges 3.144(1)-3.535(1) (1) and 2.922(6)-3.376(1) Å (2). The magnetic properties of 1 and 2 were investigated in the temperature range 1.9-300 K, and they correspond to an overall antiferromagnetic behavior with susceptibility maxima at 5.0 (1) and 65.0 K (2). The analysis of the magnetic susceptibility data showed the coexistence of intracore antiferro- and ferromagnetic interactions in the two compounds. Their values compare well with those existing in the literature for the parent systems.

  13. Torsional instability in suspension bridges: The Tacoma Narrows Bridge case

    Science.gov (United States)

    Arioli, Gianni; Gazzola, Filippo

    2017-01-01

    All attempts of aeroelastic explanations for the torsional instability of suspension bridges have been somehow criticised and none of them is unanimously accepted by the scientific community. We suggest a new nonlinear model for a suspension bridge and we perform numerical experiments with the parameters corresponding to the collapsed Tacoma Narrows Bridge. We show that the thresholds of instability are in line with those observed the day of the collapse. Our analysis enables us to give a new explanation for the torsional instability, only based on the nonlinear behavior of the structure.

  14. Chiral cyanide-bridged 1D FeⅢ-MnⅢ heterobimetallic chains: Synthesis,structures and magnetic properties%Chiral cyanide-bridged 1D FeⅢ-MnⅢ heterobimetallic chains:Synthesis,structures and magnetic properties

    Institute of Scientific and Technical Information of China (English)

    YAO MinXia; ZHENG Qi; GAO Feng; LI YiZhi; ZUO JingLin

    2012-01-01

    Two couples of enantiomerically pure chiral cyano-bridged heterobimetallic one-dimensional(1D)chain complexes:[Mn((R,R)-Salphen)Fe(Tp)(CN)3]n(1)and[Mn((S,S)-Salphen)Te(Tp)(CN)3]n(2)(Salphen =N,N1-I,2-diphenyl ethylenebis(salicylideneiminato)dianion,Tp =tris(pyrazolyl)hydroborate),[Mn((R,R)-Salphen)Fe(Tp*)(CN)3·2H2O]n(3)and[Mn((S,S)-Salphen)Fe(Tp*)(CN)3.2H2O]n(4)(Tp* =hydridotris(3,5-dimethylpyrazol- l-yl)borate),have been successfully synthesized by the reactions of MnⅢ schiff-base complexes with the tricyanometalate building block,[(LTp)Fe(CN)3]-(LTp =Tp or Tp*).All complexes are made up of neutral cyano-bridged zigzag double chains with(-Fe-C≡ N-Mn-N≡C-)n as the repeating unit.Circular dichroism(CD)spectra confirm the enantiomeric nature of the optically active complexes.Magnetic studies demonstrate that ferromagnetic interactions are operative in these complexes.The ferromagnetic couplings become weak in the chains with the bending of the Mn-N ≡C angles.

  15. National Bridge Inventory - National Geospatial Data Asset (NGDA) Bridges

    Data.gov (United States)

    Department of Transportation — The NBI (NTAD 2015) is a collection of information (database) describing the more than 610,000 of the Nation's bridges located on public roads, including Interstate...

  16. Bridge Creek IMW database - Bridge Creek Restoration and Monitoring Project

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The incised and degraded habitat of Bridge Creek is thought to be limiting a population of ESA-listed steelhead (Oncorhynchus mykiss). A logical restoration approach...

  17. General design of Sutong Bridge

    Institute of Scientific and Technical Information of China (English)

    Zhang Xigang; Yuan Hong; Pei Minshan; Dai Jie; Xu Lin

    2009-01-01

    The main span of Sutong Bridge is a double-pylon, double-plane cable-stayed bridge with steel box girder, which has the world's longest central span of 1 088 m within cable-stayed bridges. To overcome problems caused by severe meteorological conditions, perplexing hydrological conditions, deep buried bedrock and higher navigation level, many new technics and methods were created. Keys including structural system, steel box girder, stayed cable, tower, pier, tower foundation, collision avoidance system, wind-resistance, seismic-resistance, structural nonlinear response and structural static stability were presented individually in this paper.

  18. Reliability Assessment of Concrete Bridges

    DEFF Research Database (Denmark)

    Thoft-Christensen, Palle; Middleton, C. R.

    This paper is partly based on research performed for the Highways Agency, London, UK under the project DPU/9/44 "Revision of Bridge Assessment Rules Based on Whole Life Performance: concrete bridges". It contains the details of a methodology which can be used to generate Whole Life (WL) reliability...... profiles. These WL reliability profiles may be used to establish revised rules for concrete bridges. This paper is to some extend based on Thoft-Christensen et. al. [1996], Thoft-Christensen [1996] et. al. and Thoft-Christensen [1996]....

  19. Increased micronucleus, nucleoplasmic bridge, and nuclear bud frequencies in the peripheral blood lymphocytes of diesel engine exhaust-exposed workers.

    Science.gov (United States)

    Zhang, Xiao; Duan, Huawei; Gao, Feng; Li, Yuanyuan; Huang, Chuanfeng; Niu, Yong; Gao, Weimin; Yu, Shanfa; Zheng, Yuxin

    2015-02-01

    The International Agency for Research on Cancer has recently reclassified diesel engine exhaust (DEE) as a Group 1 carcinogen. Micronucleus (MN), nucleoplasmic bridge (NPB), and nuclear bud (NBUD) frequencies in peripheral blood lymphocytes (PBLs) are associated with cancer risk. However, the impact of DEE exposure on MN frequency has not been thoroughly elucidated due to mixed exposure and its impact on NPB and NBUD frequencies has never been explored in humans. We recruited 117 diesel engine testing workers with exclusive exposure to DEE and 112 non-DEE-exposed workers, and then we measured urinary levels of 4 mono-hydroxylated polycyclic aromatic hydrocarbons (OH-PAHs) using high-performance liquid chromatography-mass spectrometry as well as MN, NPB, and NBUD frequencies in PBLs using cytokinesis-block MN assay. The DEE-exposed workers exhibited significantly higher MN, NPB, and NBUD frequencies than the non-DEE-exposed workers (P frequencies (all P frequencies persisted in DEE-exposed workers (P = 0.001). The percent of MN frequencies increased, on average, by 23.99% (95% confidential interval, 9.64-39.93) per 1-unit increase in ln-transformed 9-OHPh. Our results clearly show that exposure to DEE can induce increases in MN, NPB, and NBUD frequencies in PBLs and suggest that DEE exposure level is associated with MN frequencies.

  20. The Higgs Bridge

    CERN Document Server

    Allen, Roland E

    2013-01-01

    The particle recently discovered at the Large Hadron Collider near Geneva is almost certainly a Higgs boson, the long-sought completion of the Standard Model of particle physics. But this discovery, an achievement by more than six thousand scientists (including students), is actually much more than a mere capstone of the Standard Model. It instead represents a bridge from the Standard Model to exciting discoveries of the future, at higher energies or in other experiments, and to the properties of matter at very low temperatures. The mere existence of a particle with zero spin implies a need for new physics, with the most likely candidate being supersymmetry, which requires that every known particle has a superpartner yet to be discovered. And phenomena similar to the Higgs are seen in superconducting metals and superfluid gases at low temperatures, which extend down to a millionth or even a billionth of a degree Kelvin. So the discovery of a Higgs boson has a central place in our attempts both to achieve a tr...

  1. Mineral bridges in nacre revisited

    CERN Document Server

    Checa, Antonio G; Willinger, Marc-Georg

    2012-01-01

    We confirm with high-resolution techniques the existence of mineral bridges between superposed nacre tablets. In the towered nacre of both gastropods and the cephalopod Nautilus there are large bridges aligned along the tower axes, corresponding to gaps (150-200 nm) in the interlamellar membranes. Gaps are produced by the interaction of the nascent tablets with a surface membrane that covers the nacre compartment. In the terraced nacre of bivalves bridges associated with elongated gaps in the interlamellar membrane (> 100 nm) have mainly been found at or close to the edges of superposed parental tablets. To explain this placement, we hypothesize that the interlamellar membrane breaks due to differences in osmotic pressure across it when the interlamellar space below becomes reduced at an advanced stage of calcification. In no cases are the minor connections between superimposed tablets (< 60 nm), earlier reported to be mineral bridges, found to be such.

  2. The stories of two bridges in Ghana

    DEFF Research Database (Denmark)

    Andreasen, Jørgen

    2004-01-01

    Public participation in bridge building was promoted by un habitat in the village of Mankrong. The neighbouring village did not participate in the construction of their bridge. The first flooding washed the second bridge down while the "participative bridge" stood up....

  3. Pre-edge features in X-ray absorption structure of Mn in GaMnN, GaMnAs and GeMn

    Energy Technology Data Exchange (ETDEWEB)

    Titov, A. [A.M. Prokhorov General Physics Institute, Russian Academy of Sciences, Vavilov str. 38, 119991 Moscow (Russian Federation) and ' Nanophysique et Semiconducteurs' , CEA-CNRS-Universite Joseph Fourier Grenoble, Laboratoire de Spectrometrie Physique, BP 87, 38402 St Martin d' Heres cedex (France)]. E-mail: titov@nsc.gpi.ru; Kulatov, E. [A.M. Prokhorov General Physics Institute, Russian Academy of Sciences, Vavilov str. 38, 119991 Moscow (Russian Federation); Uspenskii, Yu.A. [Lebedev Physical Institute, Russian Academy of Sciences, Leninskii prosp. 53, 119991 Moscow (Russian Federation); Biquard, X. [DRFMC-SP2M, CEA Grenoble-38054 Grenoble cedex 9 (France); Halley, D. [' Nanophysique et Semiconducteurs' , CEA-CNRS-Universite Joseph Fourier Grenoble, Laboratoire de Spectrometrie Physique, BP 87, 38402 St Martin d' Heres cedex (France); Kuroda, S. [' Nanophysique et Semiconducteurs' , CEA-CNRS-Universite Joseph Fourier Grenoble, Laboratoire de Spectrometrie Physique, BP 87, 38402 St Martin d' Heres cedex (France); Bellet-Amalric, E. [' Nanophysique et Semiconducteurs' , CEA-CNRS-Universite Joseph Fourier Grenoble, Laboratoire de Spectrometrie Physique, BP 87, 38402 St Martin d' Heres cedex (France); DRFMC-SP2M, CEA Grenoble-38054 Grenoble cedex 9 (France); Mariette, H. [' Nanophysique et Semiconducteurs' , CEA-CNRS-Universite Joseph Fourier Grenoble, Laboratoire de Spectrometrie Physique, BP 87, 38402 St Martin d' Heres cedex (France); Cibert, J. [Laboratoire Louis Neel, CNRS, BP 166, 38042 Grenoble cedex 9 (France)

    2006-05-15

    Ga{sub 1-x}Mn{sub x}N samples with a wide range of concentrations, from x=0.003 to 0.057, were grown by molecular beam epitaxy. X-ray diffraction and the simulation of the extended X-ray absorption fine structure (EXAFS) confirmed the wurtzite structure of the samples, without any secondary phase, and the location of Mn in the gallium sublattice of GaN. The valence state of Mn was studied using the X-ray absorption near-edge structure (XANES) at the K-edge of Mn. The shape of the measured XANES spectra does not depend on the Mn concentration: that implies the same valence state and local atomic structure around the Mn atom in all samples. A calculation of the electronic band structure of GaMnN, GaMnAs, GeMn and the XANES spectra of Mn in GaMnN was performed using the linearized augmented plane wave (LAPW) method. The calculated spectra fit well our experimental data. In particular, the comparison demonstrates that a peak in the pre-edge structure is directly related to the 3+ valence state of Mn. This was confirmed experimentally by measurements of the Mn K-edge in GaMn{sup 2+}As and ZnMn{sup 2+}Te. An application of proposed interpretation for GeMn is discussed.

  4. SrMnII2MnIII(PO43

    Directory of Open Access Journals (Sweden)

    Ghaleb Alhakmi

    2013-09-01

    Full Text Available The title compound, strontium trimanganese tris(orthophosphate, was synthesized under hydrothermal conditions. Its structure is isotypic to that of the lead analogue PbMnII2MnIII(PO43. Two O atoms are in general positions, whereas all others atoms are in special positions. The Sr and one P atom exhibit mm2 symmetry, the MnII atom 2/m symmetry, the MnIII atom and the other P atom .2. symmetry and two O atoms are located on mirror planes. The three-dimensional network of the crystal structure is made up of two types of chains running parallel to [010]. One chain is linear and is composed of alternating MnIIIO6 octahedra and PO4 tetrahedra sharing vertices; the other chain has a zigzag arrangement and is built up from two edge-sharing MnIIO6 octahedra connected to PO4 tetrahedra by edges and vertices. The two types of chains are linked through PO4 tetrahedra, leading to the formation of channels parallel to [100] and [010] in which the SrII ions are located. They are surrounded by eight O atoms in the form of a slightly distorted bicapped trigonal prism.

  5. Redundancy Evaluation of Fracture Critical Bridges

    OpenAIRE

    Bapat, Amey Vivek

    2014-01-01

    Cases of brittle fractures in major bridges prompted AASHTO to publish its first fracture control plan in 1978. It focused on material and fabrication standards, and required periodic 24-month hands-on inspection of bridges with fracture critical members. The practical result of this plan was to significantly increase the life cycle cost of these bridges, rendering them uneconomical. Apart from the Point Pleasant Bridge that failed in 1967, no other bridge has collapsed in the USA following a...

  6. Environmental life cycle assessment comparison between two bridge types: reinforced concrete bridge and steel composite bridge

    DEFF Research Database (Denmark)

    Du, Guangli; Karoumi, Raid

    2013-01-01

    not been integrated into the decision-making process. This paper presents a systematic LCA method for quantifying the environmental impacts for bridges. The comparison study is performed between a reinforced concrete bridge and a steel bridge as an alternative design, with several key maintenance and EOL...... scenarios outlined. LCA study is performed with the ReCiPe methodology with life cycle inventories data from public database. Five selected mid-point level impact categories and the energy consumption are presented. The result shows that the steel bridge has a better environmental performance due...... to the recycling strategy, while the initial material manufacture is the most dominant phase that contributes large environmental impact in both design solutions....

  7. Effects of disorder in the Heusler alloy Co{sub 2}MnSi and properties of the Co{sub 2}MnSi(100)/MgO interface; Effekte von Unordnung in der Heusler-Legierung Co{sub 2}MnSi und Eigenschaften der Co{sub 2}MnSi (100)/MgO-Grenzflaeche

    Energy Technology Data Exchange (ETDEWEB)

    Huelsen, Bjoern

    2009-02-13

    Mn{sub 3}Si at room temperature. In the third part of this work structural, magnetic and electronic properties of the Co{sub 2}MnSi(100)/MgO interface are investigated. The stability of different terminations (CoCo, MnSi, MnMn and SiSi) at different registries with respect to MgO (O-top, Mg-top, bridge and hollow site) are estimated with the method of ab initio thermodynamics. In thermodynamic equilibrium the CoCo/O and the MnSi/O heterojunctions are stable. They show interface states at the Fermi energy in the spin down channel and therefore have reduced spin polarization. The metastable MnMn terminated interface has a band gap. (orig.)

  8. Pre-edge features in X-ray absorption structure of Mn in GaMnN, GaMnAs and GeMn

    Science.gov (United States)

    Titov, A.; Kulatov, E.; Uspenskii, Yu. A.; Biquard, X.; Halley, D.; Kuroda, S.; Bellet-Amalric, E.; Mariette, H.; Cibert, J.

    2006-05-01

    Ga1-xMnxN samples with a wide range of concentrations, from x=0.003 to 0.057, were grown by molecular beam epitaxy. X-ray diffraction and the simulation of the extended X-ray absorption fine structure (EXAFS) confirmed the wurtzite structure of the samples, without any secondary phase, and the location of Mn in the gallium sublattice of GaN. The valence state of Mn was studied using the X-ray absorption near-edge structure (XANES) at the K-edge of Mn. The shape of the measured XANES spectra does not depend on the Mn concentration: that implies the same valence state and local atomic structure around the Mn atom in all samples. A calculation of the electronic band structure of GaMnN, GaMnAs, GeMn and the XANES spectra of Mn in GaMnN was performed using the linearized augmented plane wave (LAPW) method. The calculated spectra fit well our experimental data. In particular, the comparison demonstrates that a peak in the pre-edge structure is directly related to the 3+ valence state of Mn. This was confirmed experimentally by measurements of the Mn K-edge in GaMnAs and ZnMnTe. An application of proposed interpretation for GeMn is discussed.

  9. High-spin Mn wheels.

    Science.gov (United States)

    Manoli, Maria; Prescimone, Alessandro; Bagai, Rashmi; Mishra, Abhudaya; Murugesu, Muralee; Parsons, Simon; Wernsdorfer, Wolfgang; Christou, George; Brechin, Euan K

    2007-08-20

    The syntheses, structures, and magnetic properties of the complexes [MnIV4MnIII10MnII2O2(OCH3)12(tmp)8(O2CCH3)10].3Et2O (1.3Et2O), [MnIV2MnIII18MnII2O6(OCH3)14(O2CCH3)16(tmp)8(HIm)2].2CH3OH (2.2CH3OH), and [MnIV2MnIII18MnII2O6(OCH3)14(O2CCH3)16(Br-mp)8(HIm)2].2C6H14.5CH3OH (3.2C6H14.5CH3OH) are reported. The unusual wheel-like complexes were prepared by the treatment of [Mn3O(O2CCH3)6(HIm)3](O2CCH3) (HIm = imidazole) with 1,1,1-tris-(hydroxymethyl)propane (H3tmp) (1 and 2) or 2-(bromomethyl)-2-(hydroxymethyl)-1,3-propanediol (Br-mpH3) (3) in the presence of sodium methoxide (NaOCH3, 2, and 3) in CH3OH. Complex 1.3Et2O crystallizes in the triclinic space group P, while complexes 2.2CH3OH and 3.2C6H14.5CH3OH crystallize in the orthorhombic space group Pbca. Direct current magnetic susceptibility data, collected for 1-3 in the respective 1.8-300 K and 0.1-7 T temperature and magnetic-field ranges, afford spin ground-state values of S = 14 +/- 1 for complex 1 and S = 9 +/- 1 for complexes 2 and 3. Alternating current susceptibility measurements performed on all three complexes in the 1.8-10 K temperature range in a 3.5 G oscillating field at frequencies between 50 and 1000 Hz reveal out-of-phase chi"M signals below approximately 3 K. Single-crystal hysteresis loop and relaxation measurements confirm single-molecule magnetism behavior.

  10. Characterization of Danio rerio Mn2+-dependent ADP-ribose/CDP-alcohol diphosphatase, the structural prototype of the ADPRibase-Mn-like protein family.

    Directory of Open Access Journals (Sweden)

    Joaquim Rui Rodrigues

    Full Text Available The ADPRibase-Mn-like protein family, that belongs to the metallo-dependent phosphatase superfamily, has different functional and structural prototypes. The functional one is the Mn(2+-dependent ADP-ribose/CDP-alcohol diphosphatase from Rattus norvegicus, which is essentially inactive with Mg(2+ and active with low micromolar Mn(2+ in the hydrolysis of the phosphoanhydride linkages of ADP-ribose, CDP-alcohols and cyclic ADP-ribose (cADPR in order of decreasing efficiency. The structural prototype of the family is a Danio rerio protein with a known crystallographic structure but functionally uncharacterized. To estimate the structure-function correlation with the same protein, the activities of zebrafish ADPRibase-Mn were studied. Differences between zebrafish and rat enzymes are highlighted. The former showed a complex activity dependence on Mn(2+, significant (≈25% Mg(2+-dependent activity, but was almost inactive on cADPR (150-fold less efficient than the rat counterpart. The low cADPR hydrolase activity agreed with the zebrafish genome lacking genes coding for proteins with significant homology with cADPR-forming enzymes. Substrate-docking to zebrafish wild-type protein, and characterization of the ADPRibase-Mn H97A mutant pointed to a role of His-97 in catalysis by orientation, and to a bidentate water bridging the dinuclear metal center as the potential nucleophile. Finally, three structural elements that delimit the active site entrance in the zebrafish protein were identified as unique to the ADPRibase-Mn-like family within the metallo-dependent phosphatase superfamily.

  11. Characterization of Danio rerio Mn2+-Dependent ADP-Ribose/CDP-Alcohol Diphosphatase, the Structural Prototype of the ADPRibase-Mn-Like Protein Family

    Science.gov (United States)

    Rodrigues, Joaquim Rui; Fernández, Ascensión; Canales, José; Cabezas, Alicia; Ribeiro, João Meireles; Costas, María Jesús; Cameselle, José Carlos

    2012-01-01

    The ADPRibase-Mn-like protein family, that belongs to the metallo-dependent phosphatase superfamily, has different functional and structural prototypes. The functional one is the Mn2+-dependent ADP-ribose/CDP-alcohol diphosphatase from Rattus norvegicus, which is essentially inactive with Mg2+ and active with low micromolar Mn2+ in the hydrolysis of the phosphoanhydride linkages of ADP-ribose, CDP-alcohols and cyclic ADP-ribose (cADPR) in order of decreasing efficiency. The structural prototype of the family is a Danio rerio protein with a known crystallographic structure but functionally uncharacterized. To estimate the structure-function correlation with the same protein, the activities of zebrafish ADPRibase-Mn were studied. Differences between zebrafish and rat enzymes are highlighted. The former showed a complex activity dependence on Mn2+, significant (≈25%) Mg2+-dependent activity, but was almost inactive on cADPR (150-fold less efficient than the rat counterpart). The low cADPR hydrolase activity agreed with the zebrafish genome lacking genes coding for proteins with significant homology with cADPR-forming enzymes. Substrate-docking to zebrafish wild-type protein, and characterization of the ADPRibase-Mn H97A mutant pointed to a role of His-97 in catalysis by orientation, and to a bidentate water bridging the dinuclear metal center as the potential nucleophile. Finally, three structural elements that delimit the active site entrance in the zebrafish protein were identified as unique to the ADPRibase-Mn-like family within the metallo-dependent phosphatase superfamily. PMID:22848751

  12. The Akashi Kaikyo Bridge and the Storebælt Bridge

    DEFF Research Database (Denmark)

    Gimsing, Niels Jørgen

    1999-01-01

    With the completion of the Akashi Kaikyo Bridge and the Storebælt East Bridge the development of the suspension bridge technology in the 20th century has manifested itself in two impressive structures. With the present echnology may bridges of similar (and also more modest) dimensions...... will undoubtedly be built far into the next century. For bridges going beyond the spans of existing bridges it is, however, likely that new concepts will be developed....

  13. River ice jams at bridges

    Energy Technology Data Exchange (ETDEWEB)

    Sullivan, D. [New Brunswick Dept. of Transportation, Fredericton, NB (Canada); Beltaos, S. [National Water Research Institute, Burlington, ON (Canada)

    2000-12-01

    Ice jamming, known to cause high water levels at even moderate river flows, is described as both the main and least understood source of ice-related bridge damages. This paper describes a joint study by the New Brunswick Department of Transportation, the Department of the Environment, local governments, and the National Water Research Institute, designed to address problems associated with the interaction of ice jams and bridges. The study consists of collecting information at each of four sites in New Brunswick including: historical data on ice jam locations, causes, and water levels; channel bathymetry, width and slope within each study centred at the respective bridge; and documentation of ice conditions throughout the ice season, including measurement of ice cover thickness, observation of breakup mechanisms, times, causes, characteristics and possible impacts of ice jam release. Data analysis will include determination of high stages due to ice jams or surges caused by upstream ice jam releases, scour potential of surges, and quantification of the structure's capacity to restrain ice movement and to cause jams. The principal objective of the study is to advance beyond empiricism and to develop rational design criteria for bridges by anticipating the effects of climate changes and by incorporating local meteorological and hydrometric records into bridge design for added safety.

  14. Floating liquid bridge charge dynamics

    Science.gov (United States)

    Teschke, Omar; Soares, David Mendez; Gomes, Whyllerson Evaristo; Valente Filho, Juracyr Ferraz

    2016-01-01

    The interaction of liquid with electric fields is investigated in a configuration where up to 13 kV are applied between electrodes resulting in a 106 V/m electric field in the capillaries and where there is the formation of a free-standing fluid bridge in the interelectrode gap. The Mott-Gurney equation was fitted to the measured ionization current vs applied voltage curve which indicates that the ionization rate at the high-voltage anode electrode dimethylsulfoxide (DMSO) interface and space charging in the interelectrode gap determine the floating liquid bridge current for a given cathode-to-anode voltage. Space charge effects were measured in the cathode becker and also at the liquid bridge since the ionized charges at the anode migrate to the bridge outer surface and decrease the interfacial tension from 43 mJ/m2 to 29 mJ/m2. Two distinct structural regions then form the bridge, a charged plastic (bulk modulus ˜100 MPa) conducting outer layer with a surface conductivity of ˜10-9 Ω-1, which shapes and supports the floating fluid structure, and an inner liquid cylinder, where DMSO molecules flow.

  15. A strange bridge by Leonardo

    CERN Document Server

    Huylebrouck, Dirk

    2013-01-01

    On folio 855 recto of the Codex Atlanticus, Leonardo da Vinci drew three 'easily movable' bridges, but one of them is enigmatic: all 'replicas' in Leonardo museums and exhibitions come as a surprise, to say the least, to any engineer or architect whose attention is drawn to it. This is the case for models in Amboise (France), Chicago and Portland (USA), Florence (Italy) and for the one of the traveling exhibition by the Australian company 'Grande Exhibitions' that already visited 40 major cities in the world. All 'replicas' of the bridge model attributed to Leonardo have pillars standing on the deck of the bridge, while the deck is suspended by cables attached on these pillars. At first sight this problem does not catch the attention of the observer, as the bridge seems to be a mixed form of a beam and a suspension bridge, but it was not overlooked by my colleague architect-engineer Dr. Laurens Luyten (Gent, Belgium). Yet, after a TV-interview in Brussels so much pressure was exerted by some of the museum col...

  16. Synthesis,Crystal Structure and Magnetic Properties of Novel Three-dimensional Frameworks [Mn(PDC)H2O]n

    Institute of Scientific and Technical Information of China (English)

    GAO En-Jun; GU Xiao-Fu; SUN Ya-Guang; YIN Hong-Xi; WU Qiong; LIU Lei; ZHU Ming-Chang; ZHANG Wan-Zhong

    2008-01-01

    A novel coordination polymer,[Mn(PDC)H2O]n(1)(H2PDC=pyridine-2,3-dicarboxylic acid),has been hydrothermally synthesized and characterized by elemental analysis,IR and single crystal X-ray diffraction.X-ray single crystal structural analyses revealed that two-dimensional frameworks were formed,and further assembled into a three-dimensional supramolecular structure bridged by PDC ligands.Moreover,the magnetic study of complex 1 shows weak antiferromagnetic interaction between the neighboring Mn(Ⅱ)centers within the chains and even weak ferromagnetic interactions between the Mn(Ⅱ)centers in different chains.

  17. A large cryogenic magnetocaloric effect exhibited at low field by a 3D ferromagnetically coupled Mn(II)-Gd(III) framework material.

    Science.gov (United States)

    Guo, Fu-Sheng; Chen, Yan-Cong; Liu, Jun-Liang; Leng, Ji-Dong; Meng, Zhao-Sha; Vrábel, Peter; Orendáč, Martin; Tong, Ming-Liang

    2012-12-28

    The large cryogenic magnetocaloric effect of a 3D oxydiacetate-bridged gadolinium-manganese MOF material, [Mn(H(2)O)(6)][MnGd(oda)(3)](2)·6H(2)O (1), was evaluated by magnetization and heat capacity measurements. A maximum -ΔS(m) of 50.1 J kg(-1) K(-1) for ΔH = 70 kG along with significant entropy change at lower field was found on account of the weak Mn···Gd ferromagnetic interactions and the small molecular mass. This suggests that 1 could be considered as a potential coolant for liquid helium temperature applications.

  18. Thermal bridges of modern windows

    DEFF Research Database (Denmark)

    Hansen, Ernst Jan de Place; Møller, Eva B.; Nielsen, Anker

    2013-01-01

    With its focus on reduced energy consumption, contemporary housing construction requires a highly insulated and airtight building envelope with as few thermal bridges as possible.Windows must be carefully designed, as thermal bridges can lead to surface condensation or mold growth, even...... if the window has an U-factor of 1 W/(m2·K) or lower. This paper describes the development of modern, energy efficient Danish windows with reduced thermal bridges. It focuses on materials, geometry, and sealing of window panes based on a literature review. Examples of modern windows are presented. Experience...... with the minimum acceptable surface temperature regarding surface condensation or mold growth, implemented in the Danish Building Regulations in 2010, and the calculation method for this temperature based on international standards is discussed. The introduction of the minimum acceptable surface temperature has...

  19. An Expert System for Concrete Bridge Management

    DEFF Research Database (Denmark)

    Brito, J. de; Branco, F. A.; Thoft-Christensen, Palle

    1997-01-01

    management systems are presently being implemented by bridge authorities in several countries. The prototype of an expert system for concrete bridge management is presented in this paper, with its functionality relying on two modules. The inspection module relies on a periodic acquisition of field......The importance of bridge repair versus new bridge construction has risen in recent decades due to high deterioration rates that have been observed in these structures. Budgets both for building new bridges and keeping the existing ones are always limited. To help rational decision-making, bridge...

  20. Self-assembled decanuclear Na(I)2Mn(II)4Mn(III)4 complexes: from discrete clusters to 1-D and 2-D structures, with the Mn(II)4Mn(III)4 unit displaying a large spin ground state and probable SMM behaviour.

    Science.gov (United States)

    Langley, Stuart K; Chilton, Nicholas F; Moubaraki, Boujemaa; Murray, Keith S

    2011-12-07

    The synthesis, magnetic characterization and X-ray crystal structures are reported for five new manganese compounds, [Mn(III)(teaH(2))(sal)]·(1/2)H(2)O (1), [Na(I)(2)Mn(II)(4)Mn(III)(4)(teaH)(6)(sal)(4)(N(3))(2)(MeOH)(4)]·6MeOH (2), [Na(I)(2)Mn(II)(4)Mn(III)(4)(teaH)(6)(sal)(4)(N(3))(2)(MeOH)(2)](n)·7MeOH (3), [Na(I)(2)Mn(II)(4)Mn(III)(4)(teaH)(6)(sal)(4)(N(3))(2)(MeOH)(2)](n)·2MeOH·Et(2)O (4) and [K(I)(2)Mn(II)(4)Mn(III)(4)(teaH)(6)(sal)(4)(N(3))(2)(H(2)O)(2)](n)·5MeOH (5). Complex 1 is a mononuclear compound, formed via the reaction of Mn(NO(3))(2)·4H(2)O, triethanolamine (teaH(3)) and salicylic acid (salH(2)) in a basic methanolic solution. Compound 2 is a mixed-valent hetero-metallic cluster made up of a Mn(8)Na(2) decanuclear core and is formed via the reaction of sodium azide (NaN(3)) with 1. Compounds 3-5 are isolated as 1- or 2-D coordination polymers, each containing the decanuclear Mn(8)M(2) (M = Na(+) or K(+)) core building block as the repeating unit. Compound 3 is isolated when 1 is reacted with NaN(3) over a very short reaction time and forms a 1-D coordination polymer. Each unit displays inter-cluster bridges via the O-atoms of teaH(2-) ligands bonding to the sodium ions of an adjacent cluster. Increasing the reaction time appears to drive the formation of 4 which forms 2-D polymeric sheets and is a packing polymorph of 3. The addition of KMnO(4) and NaN(3) to 1 resulted in compound 5, which also forms a 1-D coordination polymer of the decanuclear core unit. The 1-D chains are now linked via inter-cluster potassium and salicylate bridges. Solid state DC susceptibility measurements were performed on compounds 1-5. The data for 1 are as expected for an S = 2 Mn(III) ion, with the isothermal M vs. H data being fitted by matrix diagonalization methods to give values of g and the axial (D) and rhombic (E) zero field splitting parameters of 2.02, -2.70 cm(-1) and 0.36 cm(-1) respectively. The data for 2-5, each with an identical Mn(II)(4)Mn(III)(4

  1. Excitation Methods for Bridge Structures

    Energy Technology Data Exchange (ETDEWEB)

    Farrar, C.R.; Duffy, T.A.; Cornwell, P.J.; Doebling, S.W.

    1999-02-08

    This paper summarizes the various methods that have been used to excited bridge structures during dynamic testing. The excitation methods fall into the general categories of ambient excitation methods and measured-input excitation methods. During ambient excitation the input to the bridge is not directly measured. In contrast, as the category label implies, measured-input excitations are usually applied at a single location where the force input to the structure can be monitored. Issues associated with using these various types of measurements are discussed along with a general description of the various excitation methods.

  2. Balanced bridge feedback control system

    Science.gov (United States)

    Lurie, Boris J. (Inventor)

    1990-01-01

    In a system having a driver, a motor, and a mechanical plant, a multiloop feedback control apparatus for controlling the movement and/or positioning of a mechanical plant, the control apparatus has a first local bridge feedback loop for feeding back a signal representative of a selected ratio of voltage and current at the output driver, and a second bridge feedback loop for feeding back a signal representative of a selected ratio of force and velocity at the output of the motor. The control apparatus may further include an outer loop for feeding back a signal representing the angular velocity and/or position of the mechanical plant.

  3. Optimum selection on bridge erection with floating crane in East China Sea Bridge and Hangzhou Bay Bridge

    Institute of Scientific and Technical Information of China (English)

    Shunquan Qin; Pu Zhou; Youheng Hua

    2004-01-01

    @@ Introduction With the rapid development of China′s economy, many bridges will be built over the Chinese coastal waters of Pacific Ocean. Among them, construction of East China Sea Bridge has been commenced in June 2001, and will be completed at the end of 2005, Hangzhou Bay Bridge was also started to construct in June 2003(Fig. 1). These two ultralong bridges are designed as twin expressway bridges standing side by side each carries a 3-lane one-way carriageway. The total width is 31.5m and 33.0m respectively. East China Sea Bridge starts from Nanhui District, Shanghai and extends to the Yangshan Deep Water Port Area, which is located at one of the Qiqu Islands. The total length of the bridge is about 31.0 km, in which 25 km are on the sea, and 22 km is in the unnavigable region. Hangzhou Bay Bridge across the mouth of Qiantang River.

  4. Is myocardial bridging a bridge connecting to cardiovascular events?

    Institute of Scientific and Technical Information of China (English)

    LI Jian-jun

    2010-01-01

    @@ Coronary arteries and their major branches usually course on the surface of the heart in the subepicardial tissue. However, a muscle hber overlying the intramyocardial segment of an epicardial coronary artery was defined as myocardial bridging (MB), and subsequently the artery coursing within the myocardium is called a tunneled artery.

  5. Radiation and chemotherapy bystander effects induce early genomic instability events: telomere shortening and bridge formation coupled with mitochondrial dysfunction.

    LENUS (Irish Health Repository)

    Gorman, Sheeona

    2012-02-01

    The bridge breakage fusion cycle is a chromosomal instability mechanism responsible for genomic changes. Radiation bystander effects induce genomic instability; however, the mechanism driving this instability is unknown. We examined if radiation and chemotherapy bystander effects induce early genomic instability events such as telomere shortening and bridge formation using a human colon cancer explant model. We assessed telomere lengths, bridge formations, mitochondrial membrane potential and levels of reactive oxygen species in bystander cells exposed to medium from irradiated and chemotherapy-treated explant tissues. Bystander cells exposed to media from 2Gy, 5Gy, FOLFOX treated tumor and matching normal tissue showed a significant reduction in telomere lengths (all p values <0.018) and an increase in bridge formations (all p values <0.017) compared to bystander cells treated with media from unirradiated tissue (0Gy) at 24h. There was no significant difference between 2Gy and 5Gy treatments, or between effects elicited by tumor versus matched normal tissue. Bystander cells exposed to media from 2Gy irradiated tumor tissue showed significant depolarisation of the mitochondrial membrane potential (p=0.012) and an increase in reactive oxygen species levels. We also used bystander cells overexpressing a mitochondrial antioxidant manganese superoxide dismutase (MnSOD) to examine if this antioxidant could rescue the mitochondrial changes and subsequently influence nuclear instability events. In MnSOD cells, ROS levels were reduced (p=0.02) and mitochondrial membrane potential increased (p=0.04). These events were coupled with a decrease in percentage of cells with anaphase bridges and a decrease in the number of cells undergoing telomere length shortening (p values 0.01 and 0.028 respectively). We demonstrate that radiation and chemotherapy bystander responses induce early genomic instability coupled with defects in mitochondrial function. Restoring mitochondrial

  6. Radiation and chemotherapy bystander effects induce early genomic instability events: Telomere shortening and bridge formation coupled with mitochondrial dysfunction

    Energy Technology Data Exchange (ETDEWEB)

    Gorman, Sheeona; Tosetto, Miriam [Centre for Colorectal Disease, St. Vincent' s University Hospital, Elm Park, Dublin 4 (Ireland); Lyng, Fiona; Howe, Orla [Radiation and Environmental Science Centre, Dublin Institute of Technology and St. Luke' s Hospital, Dublin (Ireland); Sheahan, Kieran; O' Donoghue, Diarmuid; Hyland, John; Mulcahy, Hugh [Centre for Colorectal Disease, St. Vincent' s University Hospital, Elm Park, Dublin 4 (Ireland); O' Sullivan, Jacintha, E-mail: jacintha.osullivan@ucd.ie [Centre for Colorectal Disease, St. Vincent' s University Hospital, Elm Park, Dublin 4 (Ireland)

    2009-10-02

    The bridge breakage fusion cycle is a chromosomal instability mechanism responsible for genomic changes. Radiation bystander effects induce genomic instability; however, the mechanism driving this instability is unknown. We examined if radiation and chemotherapy bystander effects induce early genomic instability events such as telomere shortening and bridge formation using a human colon cancer explant model. We assessed telomere lengths, bridge formations, mitochondrial membrane potential and levels of reactive oxygen species in bystander cells exposed to medium from irradiated and chemotherapy-treated explant tissues. Bystander cells exposed to media from 2 Gy, 5 Gy, FOLFOX treated tumor and matching normal tissue showed a significant reduction in telomere lengths (all p values <0.018) and an increase in bridge formations (all p values <0.017) compared to bystander cells treated with media from unirradiated tissue (0 Gy) at 24 h. There was no significant difference between 2 Gy and 5 Gy treatments, or between effects elicited by tumor versus matched normal tissue. Bystander cells exposed to media from 2 Gy irradiated tumor tissue showed significant depolarisation of the mitochondrial membrane potential (p = 0.012) and an increase in reactive oxygen species levels. We also used bystander cells overexpressing a mitochondrial antioxidant manganese superoxide dismutase (MnSOD) to examine if this antioxidant could rescue the mitochondrial changes and subsequently influence nuclear instability events. In MnSOD cells, ROS levels were reduced (p = 0.02) and mitochondrial membrane potential increased (p = 0.04). These events were coupled with a decrease in percentage of cells with anaphase bridges and a decrease in the number of cells undergoing telomere length shortening (p values 0.01 and 0.028 respectively). We demonstrate that radiation and chemotherapy bystander responses induce early genomic instability coupled with defects in mitochondrial function. Restoring

  7. Trinuclear manganese complexes of unsymmetrical polypodal diamino N3O3 ligands with an unusual [Mn3(μ-OR)4]5+ triangular core: synthesis, characterization, and catalase activity.

    Science.gov (United States)

    Ledesma, Gabriela N; Anxolabéhère-Mallart, Elodie; Rivière, Eric; Mallet-Ladeira, Sonia; Hureau, Christelle; Signorella, Sandra R

    2014-03-01

    Two new tri-Mn(III) complexes of general formula [Mn3L2(μ-OH)(OAc)]ClO4 (H3L = 1-[N-(2-pyridylmethyl),N-(2-hydroxybenzyl)amino]-3-[N'-(2-hydroxybenzyl),N'-(4-X-benzyl)amino]propan-2-ol; 1ClO4, X = Me; 2ClO4, X = H) have been prepared and characterized. X-ray diffraction analysis of 1ClO4 reveals that the complex cation possesses a Mn3(μ-alkoxo)2(μ-hydroxo)(μ-phenoxo)(4+) core, with the three Mn atoms bound to two fully deprotonated N3O3 chelating L(3-), one exogenous acetato ligand, and one hydroxo bridge, the structure of which is retained upon dissolution in acetonitrile or methanol. The three Mn atoms occupy the vertices of a nearly isosceles triangle (Mn1···Mn3 = 3.6374(12) Å, Mn2···Mn3 3.5583(13) Å, and Mn1···Mn2 3.2400(12) Å), with one substitution-labile site on the apical Mn ion occupied by terminally bound monodentate acetate. Temperature-dependent magnetic susceptibility studies indicate the presence of predominant antiferromagnetic intramolecular interactions between Mn(III) ions in 1ClO4. Complexes 1ClO4 and 2ClO4 decompose H2O2 at comparable rates upon initial binding of peroxide through acetate substitution, with retention of core structure during catalysis. Kinetic and spectroscopic studies suggest that these complexes employ the [Mn-(μ-oxo/aquo)-Mn](4+) moiety to activate peroxide, with the additional (μ-alkoxo)(μ-phenoxo)Mn(μ-alkoxo) metallobridge carrying out a structural function.

  8. Synthesis, structure, and magnetic properties of a [Mn22] wheel-like single-molecule magnet.

    Science.gov (United States)

    Murugesu, Muralee; Raftery, James; Wernsdorfer, Wolfgang; Christou, George; Brechin, Euan K

    2004-07-12

    The synthesis and magnetic properties of the compound [Mn(22)O(6)(OMe)(14)(O(2)CMe)(16)(tmp)(8)(HIm)(2)] 1 are reported. Complex 1 was prepared by treatment of [Mn(3)O(MeCO(2))(6)(HIm)(3)](MeCO(2)) (HIm = imidazole) with 1,1,1-tris(hydroxymethyl)propane (H(3)tmp) in MeOH. Complex 1.2MeOH crystallizes in the orthorhombic space group Pbca. The molecule consists of a metallic core of 2 Mn(IV), 18 Mn(III), and 2 Mn(II) ions linked by a combination of 6 micro(3)-bridging O(2)(-) ions, 14 micro(3)- and micro(2)-bridging MeO(-) ions, 16 micro-MeCO(2)(-) ligands, and 8 tmp(3)(-) ligands, which use their alkoxide arms to bridge in a variety of ways. The metal-oxygen core is best described as a wheel made from [Mn(3)O(4)] partial cubes and [Mn(3)O] triangles. Variable-temperature direct current (dc) magnetic susceptibility data were collected for complex 1 in the 1.8-300 K temperature range in a 1 T applied field. The chi(M)T value steadily decreases from 56 cm(3) K mol(-)(1) at 300 K to 48.3 cm(3) K mol(-)(1) at 30 K and then increases slightly to reach a maximum value of 48.6 cm(3) K mol(-)(1) at 15 K before dropping rapidly to 40.3 cm(3) K mol(-)(1) at 5 K. The ground-state spin of complex 1 was established by magnetization measurements in the 0.1-2.0 T and 1.80-4.00 K ranges. Fitting of the data by a matrix-diagonalization method to a model that assumes only the ground state is populated and incorporating only axial zero-field splitting (DS(z)()(2)), gave a best fit of S = 10, g = 1.96 and D = -0.10 cm(-)(1). The ac magnetization measurements performed on complex 1 in the 1.8-8 K range in a 3.5 G ac field oscillating at 50-1000 Hz showed frequency-dependent ac susceptibility signals below 3 K. Single-crystal hysteresis loop and relaxation measurements indicate loops whose coercivities are strongly temperature and time dependent, increasing with decreasing temperature and increasing field sweep rate, as expected for the superparamagnetic-like behavior of a single

  9. Architectural engineering of FRP bridges

    OpenAIRE

    Smits, J.E.P.

    2014-01-01

    This paper deals with the use of Fibre Reinforced Polymers (FRP's) in architectural and structural bridge design. The challenges and opportunities that come with this relatively new material are discussed. An inventory is made of recent engineers' solutions in FRP, followed by a discussion on architectural application of FRP's derived from the authors architectural practice.

  10. Bridge Aesthetics and Structural Honesty

    DEFF Research Database (Denmark)

    Gimsing, Niels Jørgen

    1999-01-01

    In bridges the overall form must be chosen with due respect to the transmission of forces if efficient structures shall be created, The design must therefore be governed by experienced structural engineers - in some cases assisted by aesthetic advisers on specific issues. Some basic requirements...

  11. Intercellular bridges in vertebrate gastrulation.

    Directory of Open Access Journals (Sweden)

    Luca Caneparo

    Full Text Available The developing zebrafish embryo has been the subject of many studies of regional patterning, stereotypical cell movements and changes in cell shape. To better study the morphological features of cells during gastrulation, we generated mosaic embryos expressing membrane attached Dendra2 to highlight cellular boundaries. We find that intercellular bridges join a significant fraction of epiblast cells in the zebrafish embryo, reaching several cell diameters in length and spanning across different regions of the developing embryos. These intercellular bridges are distinct from the cellular protrusions previously reported as extending from hypoblast cells (1-2 cellular diameters in length or epiblast cells (which were shorter. Most of the intercellular bridges were formed at pre-gastrula stages by the daughters of a dividing cell maintaining a membrane tether as they move apart after mitosis. These intercellular bridges persist during gastrulation and can mediate the transfer of proteins between distant cells. These findings reveal a surprising feature of the cellular landscape in zebrafish embryos and open new possibilities for cell-cell communication during gastrulation, with implications for modeling, cellular mechanics, and morphogenetic signaling.

  12. Noise Considerations in Resistance Bridges

    DEFF Research Database (Denmark)

    Diamond, Joseph M.

    1963-01-01

    A signal-to-noise analysis is made of the Wheatstone bridge, where the unknown and standard resistors may be at different temperatures, a situation which occurs in resistance thermometry. The limiting condition is assumed to be dissipation in the unknown resistor. It is shown that the ratio arms ...

  13. The Wien Bridge Oscillator Family

    DEFF Research Database (Denmark)

    Lindberg, Erik

    2006-01-01

    A tutorial in which the Wien bridge family of oscillators is defined and investigated. Oscillators which do not fit into the Barkhausen criterion topology may be designed. A design procedure based on initial complex pole quality factor is reported. The dynamic transfer characteristic...

  14. Architectural engineering of FRP bridges

    NARCIS (Netherlands)

    Smits, J.E.P.

    2014-01-01

    This paper deals with the use of Fibre Reinforced Polymers (FRP's) in architectural and structural bridge design. The challenges and opportunities that come with this relatively new material are discussed. An inventory is made of recent engineers' solutions in FRP, followed by a discussion on archit

  15. MnS clusters in natural zeolites

    Energy Technology Data Exchange (ETDEWEB)

    Iacomi, Felicia; Vasile, Aurelia; Polychroniadis, E.K

    2003-08-15

    FTIR, ESR, optical absorption, photoconductivity, and luminescence measurements are used to evidence the nature of MnS clusters, synthesized by treating the Mn{sup 2+} forms of natural zeolites with Na{sub 2}S.

  16. History of cable-stayed bridges

    DEFF Research Database (Denmark)

    Gimsing, Niels Jørgen

    1999-01-01

    The principle of supporting a bridge deck by inclined tension members leading to towers on either side of the span has been known for centuries. However, the real development of cable-stayed bridges did not begin before the 1950s. Since then the free span has been increased from 183 m...... in the Strömsund Bridge (from 1955) to 890 m in the Tatara Bridge (from 1999)....

  17. Mn-based nanostructured building blocks: Synthesis, characterization and applications

    Science.gov (United States)

    Beltran Huarac, Juan

    -up approaches towards the fabrication of different types of functional MBNs. Likewise, strategic procedures that advance the facile integration of these self-assembled nanostructures with carbon-based and magnetic/optical materials, chalcogenides, oxides, and ferroics are widely analyzed and discussed. Furthermore, we present the attractive peculiarities of three versatile MBN systems (bridging the gap between their advantageous properties and the lack of methods for their fabrication): single-crystal saw-like MnS NRs, and single-crystal MnS NWs conformally coated with carbon; doped rare-earth manganite NCs, and carbon NTs conformally coated with doped rare-earth manganite; and ZnS:Mn NPs, and Fe3O4/ZnS:Mn NCs. Concerning the applicative significance, the main features of these three systems obtained by our method are suitable to advance direct applications in nanotechnology. In this regard, this work represents a step ahead in the following areas: i) alternative anode materials to enhance the capacity and cycling performance of low-drain, long-life, low-cost, high-energy density light-weight and safer lithium-ion batteries; ii) promising luminescent materials to improve the optoelectronic performance of visible light emitters; iii) new elements for field-effect transistors that outperform the transport properties of conventional carbon-based channels; iv) bifunctional materials exhibiting optical response sensitive to external magnetic fields vital for DMS; v) novel types of nanocantilevers useful for nanosensors and nanotweezers; vi) unique multiferroics materials that exhibit magnetoelectric coupling at room temperature for spintronics; vii) potential core-shell materials showing stress-free and protective carbon shells for shock-resistance semiconductors; and viii) high-quality ceramics useful as starting materials to deposit films by pulsed laser deposition, sputtering and thermal evaporation techniques.

  18. Calix[4]arene supported clusters: a dimer of [Mn(III)Mn(II)] dimers

    DEFF Research Database (Denmark)

    Taylor, Stephanie M; McIntosh, Ruaraidh D; Beavers, Christine M;

    2011-01-01

    Phosphinate ligands allow for the transformation of a calix[4]arene supported [Mn(III)(2)Mn(II)(2)] tetramer cluster motif into an unusual [Mn(III)Mn(II)](2) dimer of dimers; the clusters self-assemble in the crystal to form bi-layer arrays reminiscent of the typical packing of calixarene solvates....

  19. Mn8 and Mn16 clusters from the use of 2-(hydroxymethyl)pyridine, and comparison with the products from bulkier chelates: a new high nuclearity single-molecule magnet.

    Science.gov (United States)

    Taguchi, Taketo; Wernsdorfer, Wolfgang; Abboud, Khalil A; Christou, George

    2010-11-15

    The synthesis, crystal structures, and magnetochemical characterization of two new Mn clusters [Mn(8)O(2)(O(2)CPh)(10)(hmp)(4)(MeOH)(2)] (1; 6Mn(II), 2Mn(III)) and [Mn(16)O(8)(OH)(2)(O(2)CPh)(12)(hmp)(10)(H(2)O)(2)](O(2)CPh)(2) (2; 6Mn(II), 10Mn(III)) are reported. They were obtained from the use of 2-(hydroxymethyl)pyridine (hmpH) under the same reaction conditions but differing in the presence or absence of added base. Thus, the reaction of hmpH with Mn(O(2)CPh)(2) in CH(2)Cl(2)/MeOH led to isolation of octanuclear complex 1, whereas the analogous reaction in the presence of NEt(3) gave hexadecanuclear complex 2. Complexes 1 and 2 possess either very rare or unprecedented core structures that are related to each other: that of 1 can be described as a linked pair of incomplete [Mn(4)O(3)] cubanes, while that of 2 consists of a linked pair of complete [Mn(4)O(4)] cubanes, on either side of which is attached a tetrahedral [Mn(4)(μ(4)-O)] unit. Solid-state direct current (dc) and alternating current (ac) magnetic susceptibility measurements on 1 and 2 establish that they possess S = 5 and 8 ground states, respectively. Complex 2 exhibits frequency-dependent out-of-phase (χ(M)") ac susceptibility signals at temperatures below 3 K suggestive of a single-molecule magnet (SMM). Magnetization versus applied dc field sweeps on single crystals of 2·10MeOH down to 0.04 K exhibited hysteresis, confirming 2 to be a new SMM. Comparison of the structure of 2 (Mn(16)) with Mn(12) or Mn(6) clusters previously obtained under the same reaction conditions but with two Me or two Ph groups, respectively, added next to the alkoxide O atom of hmp(-) indicate their influence on the nuclearity and structure of the products as being due to the overall bulk of the chelate plus the decreased ability of the O atom to bridge.

  20. Building Bridges One Line at a Time

    Science.gov (United States)

    Grigsby, Cathy Murray

    2012-01-01

    In this article, first-grade students were taught the different kinds of lines that were part of the construction of various bridges--the curved lines of the arches of stone bridges, straight lines connecting the cables of a suspension bridge, vertical lines, horizontal lines, and so on. They gained practice in drawing structures and in fine brush…

  1. Identification of the interstitial Mn site in ferromagnetic (Ga,Mn)As

    CERN Document Server

    AUTHOR|(CDS)2093111; Wahl, Ulrich; Augustyns, Valerie; Silva, Daniel; Granadeiro Costa, Angelo Rafael; Houben, K; Edmonds, Kevin W; Gallagher, BL; Campion, RP; Van Bael, MJ; Castro Ribeiro Da Silva, Manuel; Martins Correia, Joao; Esteves De Araujo, Araujo Joao Pedro; Temst, Kristiaan; Vantomme, André; Da Costa Pereira, Lino Miguel

    2015-01-01

    We determined the lattice location of Mn in ferromagnetic (Ga,Mn)As using the electron emission channeling technique. We show that interstitial Mn occupies the tetrahedral site with As nearest neighbors (TAs) both before and after thermal annealing at 200 °C, whereas the occupancy of the tetrahedral site with Ga nearest neighbors (TGa) is negligible. TAs is therefore the energetically favorable site for interstitial Mn in isolated form as well as when forming complexes with substitutional Mn. These results shed new light on the long standing controversy regarding TAs versus TGa occupancy of interstitial Mn in (Ga,Mn)As.

  2. Comparison between Modern Violin Bridge and Baroque Violin Bridge by Photoelastic Observation and Frequency Analysis

    Science.gov (United States)

    Matsutani, Akihiro

    2004-05-01

    A comparison between the modern bridge and the baroque bridge of the violin by photoelastic observation was carried out. The relationship between the stress part and the hole is symmetric in the modern and baroque bridges. The measured spectral envelopes of baroque bridges are similar to those of modern bridges in D- or G-strings, and have peaks at a frequency higher than those of modern bridges in E-string. The visualization method as used in this study may provide hints for the design of violin bridges.

  3. Novel thioarsenates {[Mn(2,2'-bipy)2(SCN)][Mn(2,2'-bipy)](As(V)S4)}2 and {[Mn(2,2'-bipy)2(SCN)]2[As(III)2(S2)2S2]}: introducing an anionic second ligand to modify MnII complex cations of 2,2'-bipyridine.

    Science.gov (United States)

    Liu, Guang-Ning; Guo, Guo-Cong; Wang, Ming-Sheng; Huang, Jin-Shun

    2014-03-14

    Two novel manganese thioarsenates, {[Mn(2,2'-bipy)2(SCN)][Mn(2,2'-bipy)](As(V)S4)}2 (1, 2,2'-bipy = 2,2'-bipyridine) and {[Mn(2,2'-bipy)2(SCN)]2[As(III)2(S2)2S2]} (2), containing thiocyanate-modified Mn-2,2'-bipy complex cations were synthesized. They feature two terminal [Mn(2,2'-bipy)2(SCN)](+) complex cations bridged by a polyanion {[Mn(2,2'-bipy)]2(As(V)S4)2}(2-) for 1 and a cyclic thioarsenate anion (As(III)2S6)(2-) for 2. In 2, the [As(III)2(S2)2S2](2-) anion can be described as two (As(III)S3)(3-) trigonal-pyramids interlinked through S-S bonds. The method to obtain new metal complex cations shown here, introducing an anionic second ligand to modify the number of coordination sites and the charges of the metal complex cations simultaneously, is different from the traditional methods, varying either the TM center or the organic ligand or employing mixed neutral organic ligands, and may open up a new route for preparing novel chalcogenidometalates. Compounds 1 and 2 exhibit wide optical gaps of 2.20 and 2.67 eV, respectively, and photoluminescence with the emission maxima occurring around 440 nm. Magnetic measurements show the presence of antiferromagnetic interactions between Mn(II) centers in the two compounds.

  4. Beginning Course Surveys: Bridges for Knowing and Bridges for Being

    Directory of Open Access Journals (Sweden)

    David Starr-Glass

    2011-06-01

    Full Text Available The use of a participant survey, administered at the outset of an online course, can provide information useful in the management of the learning environment and in its subsequent redesign. Such information can clarify participants’ prior experience, expectations, and demographics. But the very act of enquiring about the learner also signals the instructor’s social presence, relational interest, and desire to enter into an authentic dialogue. This study examines the use of participant surveys in online management courses. The first section discusses the informational bridges that this instrument provides. The second section considers survey responses to open-ended questions dealing with student sentiments. This analysis suggests that the survey plays a valuable part in accentuating social presence and in initiating relational bridges with participants.

  5. ESTIMATION OF ECONOMIC EXPEDIENCY OF «BRIDGE-PRE-BRIDGE TERRITORY» SYSTEM

    Directory of Open Access Journals (Sweden)

    A. A. Lapko

    2008-01-01

    Full Text Available The paper considers principles that form «Bridge-Pre-Bridge Territory» system. The method is proposed for calculation of expenses on technical research for development of projects on usage of pre-bridge territories. Usage of site class number for natural conditions makes it possible to estimate investment attractiveness of «Bridge-Pre-Bridge Territory» system.

  6. 33 CFR 115.70 - Advance approval of bridges.

    Science.gov (United States)

    2010-07-01

    ... 33 Navigation and Navigable Waters 1 2010-07-01 2010-07-01 false Advance approval of bridges. 115... BRIDGES BRIDGE LOCATIONS AND CLEARANCES; ADMINISTRATIVE PROCEDURES § 115.70 Advance approval of bridges. (a) The General Bridge Act of 1946 requires the approval of the location and plans of bridges...

  7. Performance analysis of LAN bridges and routers

    Science.gov (United States)

    Hajare, Ankur R.

    1991-01-01

    Bridges and routers are used to interconnect Local Area Networks (LANs). The performance of these devices is important since they can become bottlenecks in large multi-segment networks. Performance metrics and test methodology for bridges and routers were not standardized. Performance data reported by vendors is not applicable to the actual scenarios encountered in an operational network. However, vendor-provided data can be used to calibrate models of bridges and routers that, along with other models, yield performance data for a network. Several tools are available for modeling bridges and routers - Network II.5 was used. The results of the analysis of some bridges and routers are presented.

  8. Problems associated with nondestructive evaluation of bridges

    Science.gov (United States)

    Prine, David W.

    1995-05-01

    The US has 542,000 bridges that consume billions of dollars per year in construction, rehabilitation, and maintenance funds and which are the lifelines of US commerce. The 1992 ISTEA (Intermodal Surface Transportation Efficiency Act) mandates the implementation of a quantitative computerized bridge management system by 1996. A prime need of such a system are quantitative bridge inspection methods to feed accurate reliable condition information to the huge database of bridges. Nondestructive evaluation (NDE) will fill a critical need in the implementation of effective bridge management. However, many serious barriers exist to the widespread routine application of this technology to bridges. This paper provides an overview of the typical problems associated with applying NDE to bridges.

  9. A polyoxometalate-based single-molecule magnet with a mixed-valent {Mn(IV)2Mn(III)6Mn(II)4} core.

    Science.gov (United States)

    Zhang, Zhi-Ming; Yao, Shuang; Li, Yang-Guang; Wu, Hai-Hong; Wang, Yong-Hui; Rouzières, Mathieu; Clérac, Rodolphe; Su, Zhong-Min; Wang, En-Bo

    2013-03-28

    A polyoxometalate (POM)-based {Mn(IV)2Mn(III)6Mn(II)4} complex with single-molecule magnet (SMM) behaviour was prepared, exhibiting the largest known Mn nuclearity and the most Mn valence states in the POM-based SMM family.

  10. Formation process and superparamagnetic properties of (Mn,Ga)As nanocrystals in GaAs fabricated by annealing of (Ga,Mn)As layers with low Mn content

    DEFF Research Database (Denmark)

    Sadowski, Janusz; Domagala, Jaroslaw Z.; Mathieu, Roland;

    2011-01-01

    °C) annealing of (Ga,Mn)As layers with Mn concentrations between 0.1% and 2%, grown by molecular beam epitaxy at 270°C. Decomposition of (Ga,Mn)As is already observed at the lowest annealing temperature of 400°C for layers with initial Mn content of 1% and 2%. Both cubic and hexagonal (Mn...

  11. Parabolic metamaterials and Dirac bridges

    Science.gov (United States)

    Colquitt, D. J.; Movchan, N. V.; Movchan, A. B.

    2016-10-01

    A new class of multi-scale structures, referred to as `parabolic metamaterials' is introduced and studied in this paper. For an elastic two-dimensional triangular lattice, we identify dynamic regimes, which corresponds to so-called `Dirac Bridges' on the dispersion surfaces. Such regimes lead to a highly localised and focussed unidirectional beam when the lattice is excited. We also show that the flexural rigidities of elastic ligaments are essential in establishing the `parabolic metamaterial' regimes.

  12. Severe ASR damaged concrete bridges

    DEFF Research Database (Denmark)

    Antonio Barbosa, Ricardo; Gustenhoff Hansen, Søren

    2015-01-01

    Technical University of Denmark (DTU) and University of Southern Denmark (SDU) have conducted several full-scale experiments with severe ASR deteriorated bridges. This paper presents few and preliminary results from both the shear tests and the measuring of the material properties. The shear test...... show that the shear capacity is almost unaffected of ASR despite significant reduction in compressive concrete strength. Furthermore, measurements show a significant tensile reinforcement strain developed due to ASR expansion....

  13. Inspection Strategies for Concrete Bridges

    DEFF Research Database (Denmark)

    Sørensen, John Dalsgaard; Thoft-Christensen, Palle

    1989-01-01

    In this paper an optimal inspection strategy for concrete bridges based on periodic routine and detailed inspections is presented. The failure mode considered is corrosion of the reinforcement due to chlorides. A simple modelling of the corrosion and of the inspection strategy is presented....... The optimal inspection strategy is determined from an optimization problem, where the design variables are time intervals between detailed inspections and the concrete cover. The strategy is illustrated on a simple structure, namely a reinforced concrete beam....

  14. Structural Analysis of the Mn(IV)/Fe(III) Cofactor of Chlamydia Trachomatis Ribonucleotide Reductase By Extended X-Ray Absorption Fine Structure Spectroscopy And Density Functional Theory Calculations

    Energy Technology Data Exchange (ETDEWEB)

    Younker, J.M.; Krest, C.M.; Jiang, W.; Krebs, C.; Bollinger, J.M.Jr.; Green, M.T.

    2009-05-28

    The class Ic ribonucleotide reductase from Chlamydia trachomatis (C{bar A}) uses a stable Mn(lV)/ Fe(lll) cofactor to initiate nucleotide reduction by a free-radical mechanism. Extended X-ray absorption fine structure (EXAFS) spectroscopy and density functional theory (DFT) calculations are used to postulate a structure for this cofactor. Fe and Mn K-edge EXAFS data yield an intermetallic distance of -2.92 {angstrom}. The Mn data also suggest the presence of a short 1.74 {angstrom} Mn-O bond. These metrics are compared to the results of DFT calculations on 12 cofactor models derived from the crystal structure of the inactive Fe2(lll/ III) form of the protein. Models are differentiated by the protonation states of their bridging and terminal OH{sub x} ligands as well as the location of the Mn(lV) ion (site 1 or 2). The models that agree best with experimental observation feature a{mu}-1, 3-carboxylate bridge (E120), terminal solvent (H{sub 2}O/OH) to site 1, one {mu}-O bridge, and one {mu}-OH bridge. The site-placement of the metal ions cannot be discerned from the available data.

  15. Cochleates bridged by drug molecules.

    Science.gov (United States)

    Syed, Uwais M; Woo, Amy F; Plakogiannis, Fotios; Jin, Tuo; Zhu, Hua

    2008-11-03

    A new type of cochleate, able to microencapsulate water-soluble cationic drugs or peptides into its inter-lipid bi-layer space, was formed through interaction between negatively charged lipids and drugs or peptides acting as the inter-bi-layer bridges instead of multi-cationic metal ions. This new type of cochleate opened up to form large liposomes when treated with EDTA, suggesting that cationic organic molecules can be extracted from these cochleates in a way similar to multivalent metal ions from metal ion-bridged cochleates. Cochleates can be produced in sub-micron size using a method known as "hydrogel isolated cochleation" or simply by increasing the ratio of multivalent cationic peptides over negatively charged liposomes. When nanometer-sized cochleates and liposomes containing the same fluorescent labeled lipid component were incubated with human fibroblasts cells under identical conditions, cells exposed to cochleates showed bright fluorescent cell surfaces, whereas those incubated with liposomes did not. This result suggests that cochleates' edges made them fuse with the cell surfaces as compared to edge free liposomes. This mechanism of cochleates' fusion with cell membrane was supported by a bactericidal activity assay using tobramycin cochleates, which act by inhibiting intracellular ribosomes. Tobramycin bridged cochleates in nanometer size showed improved antibacterial activity than the drug's solution.

  16. Synthesis and Structure Characterization of Mn2(CO)6(μ-S2CPiPr3)

    Institute of Scientific and Technical Information of China (English)

    马永强; 陈晓; 李靖; 谢庆兰; 王宏根

    2003-01-01

    The homobinuclear compound Mn2(CO)6(u-S2CPiPr3) has been prepared by the reaction of BrMn(CO)3(u-S2CPiPr3) with NaMn(CO)5 in refluxing THF, and its structure was determined by single-crystal X-ray diffraction. Crystallographic data: C16H21Mn2O6PS2, Mr = 514.30, triclinic, space group Pīwith a = 9.293(3), b = 9.443(3), c = 12.977(4) A。, a = 83.633(5), b= 83.719(5), c= 73.399(5) V = 1081.1(6) A。3, Z = 2, Dc = 1.580 g/cm3, a = 1.463 mm-1, F(000) = 524, the final R = 0.0330 and wR = 0.0729 for 2945 observed reflections with I > 2o(I). The crystal structure determination shows that the ligand can be described as a η2(S, S') chelate to one manganese and a η3(S, C, S') pseudoallyl to the other manganese bridging the Mn-Mn bond asymmetrically.

  17. Manganese-induced reactive oxygen species: comparison between Mn+2 and Mn+3.

    Science.gov (United States)

    Ali, S F; Duhart, H M; Newport, G D; Lipe, G W; Slikker, W

    1995-09-01

    Manganese (Mn) is an essential element, the deficiency or excess of which is known to cause neurotoxicity in experimental animals and man. The mechanism of action of Mn neurotoxicity is still unclear. The present study was designed to evaluate whether in vitro or in vivo exposure to Mn produced reactive oxygen species (ROS). We also sought to determine if a single injection of Mn produces changes in monoamines concentration in different regions of rat brain. Adult Sprague-Dawley rats were dosed with 0, 50 or 100 mg/kg, ip with either MnCl2 (Mn+2) or MnOAc (Mn+3) and were sacrificed 1 h after the dose was administered. Brains were quickly removed and dissected for neurochemical analysis. ROS were measured by a molecular probe, 2',7'-dichlorofluorescein diacetate (DCFH-DA), and monoamines and their metabolites were measured by HPLC/EC. In vitro exposure to MnCl2 (1-1000 microM) produced dose-dependent increases of ROS in striatum whereas MnOAc produced similar increases at much lower concentrations (1-100 microM). In vivo exposure to MnOAc (Mn+3) produced significant increases of ROS in caudate nucleus and hippocampus, whereas MnCl2 (Mn+2) produced significant effects only in hippocampus. Concentrations of dopamine, serotonin and their metabolites (DOPAC, HVA and 5-HIAA) were not altered with acute injections of either MnCl2 or MnOAc. These data suggest that both divalent and trivalent manganese induce ROS, however, Mn+3 is an order of magnitude more potent than Mn+2.

  18. Salt bridges: geometrically specific, designable interactions.

    Science.gov (United States)

    Donald, Jason E; Kulp, Daniel W; DeGrado, William F

    2011-03-01

    Salt bridges occur frequently in proteins, providing conformational specificity and contributing to molecular recognition and catalysis. We present a comprehensive analysis of these interactions in protein structures by surveying a large database of protein structures. Salt bridges between Asp or Glu and His, Arg, or Lys display extremely well-defined geometric preferences. Several previously observed preferences are confirmed, and others that were previously unrecognized are discovered. Salt bridges are explored for their preferences for different separations in sequence and in space, geometric preferences within proteins and at protein-protein interfaces, co-operativity in networked salt bridges, inclusion within metal-binding sites, preference for acidic electrons, apparent conformational side chain entropy reduction on formation, and degree of burial. Salt bridges occur far more frequently between residues at close than distant sequence separations, but, at close distances, there remain strong preferences for salt bridges at specific separations. Specific types of complex salt bridges, involving three or more members, are also discovered. As we observe a strong relationship between the propensity to form a salt bridge and the placement of salt-bridging residues in protein sequences, we discuss the role that salt bridges might play in kinetically influencing protein folding and thermodynamically stabilizing the native conformation. We also develop a quantitative method to select appropriate crystal structure resolution and B-factor cutoffs. Detailed knowledge of these geometric and sequence dependences should aid de novo design and prediction algorithms.

  19. Thermodynamics of the Mn-P system

    Science.gov (United States)

    Lee, Y. E.

    1986-12-01

    The free energy of mixing in the Mn-P melts in the composition range of X p = 0.0 to 0.333 was estimated by coupling the phase boundary information with reliable Δ G° formation for the Mn2P phase. This information was used to obtain the dilute solution properties of P in Mn. P( l,pure) = P( l,Henrian, Mn) Δ G °(Joules) = -203,611.39 + 41.003 T The free energy is shown to be more negative than in the Fe system, reflecting a stronger interaction between Mn and P atoms than between Fe and P atoms. Presenting the activity coefficient of P with the expression used by Lupis and Elliott, the first and second interaction coefficients are obtained as follows: ɛ{P/P}(Mn) = 10.538 + 9728.14/ T ρ{P/P}(Mn) = 28.148 + 9101.83/ T The Gibbs free energy of formation for Mn3P was estimated in the temperature range of {dy1233} to {dy1378} K to be 3Mn l + P( l = Mn3P( s Δ G °(Joules) = -241,461.65 + 65.031 T

  20. Mn(ii) mediated degradation of artemisinin based on Fe3O4@MnSiO3-FA nanospheres for cancer therapy in vivo

    Science.gov (United States)

    Chen, Jian; Zhang, Weijie; Zhang, Min; Guo, Zhen; Wang, Haibao; He, Mengni; Xu, Pengping; Zhou, Jiajia; Liu, Zhenbang; Chen, Qianwang

    2015-07-01

    Artemisinin (ART) is a natural drug with potent anticancer activities related with Fe2+ mediated cleavage of the endoperoxide bridge in ART. Herein, we reported that Mn2+ could substitute for Fe2+ to react with ART and generate toxic products, inducing a much higher anticancer efficiency. On this basis, we prepared pH-responsive Fe3O4@MnSiO3-FA nanospheres which can efficiently deliver hydrophobic ART into tumors in mice models. Mn2+ was released in acidic tumor environments and intracellular lysosomes, interacting with ART to kill cancer cells. The ART-loaded nanocarriers could suppress tumor growth more efficiently than free ART, which could be further illustrated by magnetic resonance imaging (MRI). Histological analysis revealed that the drug delivery system had no obvious effect on the major organs of mice. ART has been reported to have lower toxicity than chemotherapeutics. The ART-loaded nanocarriers are promising to be used in improving the survival of chemotherapy patients, providing a novel method for clinical tumor therapy.Artemisinin (ART) is a natural drug with potent anticancer activities related with Fe2+ mediated cleavage of the endoperoxide bridge in ART. Herein, we reported that Mn2+ could substitute for Fe2+ to react with ART and generate toxic products, inducing a much higher anticancer efficiency. On this basis, we prepared pH-responsive Fe3O4@MnSiO3-FA nanospheres which can efficiently deliver hydrophobic ART into tumors in mice models. Mn2+ was released in acidic tumor environments and intracellular lysosomes, interacting with ART to kill cancer cells. The ART-loaded nanocarriers could suppress tumor growth more efficiently than free ART, which could be further illustrated by magnetic resonance imaging (MRI). Histological analysis revealed that the drug delivery system had no obvious effect on the major organs of mice. ART has been reported to have lower toxicity than chemotherapeutics. The ART-loaded nanocarriers are promising to be used in

  1. XPS Determination of Mn Oxidation States in Mn (Hydr)oxides

    Energy Technology Data Exchange (ETDEWEB)

    Ilton, Eugene S.; Post, Jeffrey E.; Heaney, Peter J.; Ling, Florence T.; Kerisit, Sebastien N.

    2016-03-15

    Hydrous manganese oxides are an important class of minerals that help regulate the geochemical redox cycle in near-surface environments and are also considered to be promising catalysts for energy applications such as the oxidation of water. A complete characterization of these minerals is required to better understand their catalytic activity. In this contribution an empirical methodology using X-ray photoelectron spectroscopy (XPS) is developed to quantify the oxidation state of hydrous multivalent manganese oxides with an emphasis on birnessite, a common layered structure that occurs readily in Nature but is also the oxidized endmember in biomimetic water-oxidation catalysts. The Mn2p3/2, Mn3p, and Mn3s lines of near monovalent Mn(II), Mn(III), and Mn(IV) oxides were fit with component peaks; after the best fit was obtained the relative widths, heights and binding energies of the components were fixed. Unknown multivalent samples were fit such that binding energies, intensities, and widths of each oxidation state, composed of a packet of correlated component peaks, were allowed vary. whereas widths were constrained to maintain the difference between the standards. Both average and individual mole fraction oxidation states for all three energy levels were strongly correlated with close agreement between Mn3s and Mn3p, whereas Mn2p3/2 gave systematically more reduced results. Limited stoichiometric analyses were consistent with Mn3p and Mn3s. Further, evidence indicates the shape of the Mn3p line was less sensitive to the bonding environment than Mn2p. Consequently, fitting the Mn3p and Mn3s lines yields robust quantification of oxidation states over a range of hydrous Mn oxide polytypes and compositions. In contrast, a common method for determining oxidation states that utilizes the multiplet splitting of the Mn3s line is not appropriate for birnessites.

  2. Oxygen Isotope Evidence for Mn(II)-Catalyzed Recrystallization of Manganite (γ-MnOOH).

    Science.gov (United States)

    Frierdich, Andrew J; Spicuzza, Michael J; Scherer, Michelle M

    2016-06-21

    Manganese is biogeochemically cycled between aqueous Mn(II) and Mn(IV) oxides. Aqueous Mn(II) often coexists with Mn(IV) oxides, and redox reactions between the two (e.g., comproportionation) are well known to result in the formation of Mn(III) minerals. It is unknown, however, whether aqueous Mn(II) exchanges with structural Mn(III) in manganese oxides in the absence of any mineral transformation (similar to what has been reported for aqueous Fe(II) and some Fe(III) minerals). To probe whether atoms exchange between a Mn(III) oxide and water, we use a (17)O tracer to measure oxygen isotope exchange between structural oxygen in manganite (γ-MnOOH) and water. In the absence of aqueous Mn(II), about 18% of the oxygen atoms in manganite exchange with the aqueous phase, which is close to the estimated surface oxygen atoms (∼11%). In the presence of aqueous Mn(II), an additional 10% (for a total of 28%) of the oxygen atoms exchange with water, suggesting that some of the bulk manganite mineral (i.e., beyond surface) is exchanging with the fluid. Exchange of manganite oxygen with water occurs without any observable change in mineral phase and appears to be independent of the rapid Mn(II) sorption kinetics. These experiments suggest that Mn(II) catalyzes manganese oxide recrystallization and illustrate a new pathway by which these ubiquitous minerals interact with their surrounding fluid.

  3. Evaluation method research on prestressed concrete bridges

    Institute of Scientific and Technical Information of China (English)

    HUANG Qiao; LIN Yang-zi; REN Yuan

    2008-01-01

    Considering the construction features of prestressed concrete bridge, the comprehensive evaluation method about the bridge damage conditions are studied. Particular attentions are paid on establishing a multi-level evaluation model for damaged prestressed concrete bridge, and the evaluation indices of the model as well as the rating standards are defined in the model. A normal relative function about the evaluation indices of each element is developed to calculate the relative degree, and for each element which is no sub-level elements. When evaluating the elements in sub-item level or index level of the model, the weights of elements that are pertained to one element are adopted, taking account of their deterioration degree. At the same time, the dam-age conditions of bridge are characterized by relative degree, element evaluation scale and structural technology mark of bridge ,so it agrees with Code for Maintenance of Highway Bridges and Culvers.

  4. Study on structural system of Sutong Bridge

    Institute of Scientific and Technical Information of China (English)

    Zhang Xigang; Pei Minshan; Yuan Hong; Xu Liping; Zhu Bin

    2009-01-01

    Sutong Bridge, whose layout is [ (100 + 100 + 300) + 1 088 + ( 300 + 100 + 100) ] m, marks the largest span of cable-stayed bridges in the world. The complex natural condition at the bridge site and the strict requirements for resistance of wind and seismic action make it crucial to choose a favorable structural system to assure the function and safety of the bridge. The comparison among several optional structural systems for Sutong Bridge is illustrated. After detailed analysis is carried out for viscous damper and hydraulic buffer, super liquid viscous damper with additional displacement limitation is designed for the first application in bridge engineering. The parameters for the damper is analyzed and studied and the dampers are installed suecessfuUy after quality tests.

  5. Bridge engineering handbook construction and maintenance

    CERN Document Server

    Chen, Wai-Fah

    2014-01-01

    Over 140 experts, 14 countries, and 89 chapters are represented in the second edition of the Bridge Engineering Handbook. This extensive collection highlights bridge engineering specimens from around the world, contains detailed information on bridge engineering, and thoroughly explains the concepts and practical applications surrounding the subject.Published in five books: Fundamentals, Superstructure Design, Substructure Design, Seismic Design, and Construction and Maintenance, this new edition provides numerous worked-out examples that give readers step-by-step design procedures, includes c

  6. Analysis of liquid bridge between spherical particles

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    A pair of central moving spherical particles connected by a pendular liquid bridge with interstitial Newtonian fluid is often encountered in pariculate coalescence process. In this paper, by assuming perfect-wet condition, the effects of liquid volume and separation distance on static liquid bridge are analyzed, and the relation between rupture energy and liquid bridge volume is also studied. These points would be of significance in industrial processes related to adhesive particles.

  7. Bridge Engineering-Oriented Parametric Model

    Institute of Scientific and Technical Information of China (English)

    周凌远; 李乔

    2004-01-01

    A new model is proposed to improve the efficiency of structural modeling. In this model, the bridge structural components are expressed with component description, parametric description and geometric description in a software system. This model provides both convenience and flexibility for users in structural modeling process. The object-oriented method is applied in the model implementation. A bridge analysis preprocessor is developed on the basis of this model. It provides an effective way for bridge modeling.

  8. Dynamics and Statics of Nonaxisymmetric Liquid Bridges

    Science.gov (United States)

    Alexander, J. Iwan D.; Resnick, Andrew H.; Slobozhanin, L. A.

    1996-01-01

    Theoretical and experimental investigation of the stability of nonaxisymmetric and nonaxisymmetric bridges contained between equal and unequal radii disks as a function of Bond and Weber number with emphasis on the transition from unstable axisymmetric to stable nonaxisymmetric shapes, are conducted. Numerical analysis of the stability of nonaxisymmetric bridges between unequal disks for various orientations of the gravity vector is performed. Experimental and theoretical investigation of large (nonaxisymmetric) oscillations and breaking of liquid bridges are also conducted.

  9. Mathematical Modelling of Bridges with SAP2000

    OpenAIRE

    Maraž, Miha

    2006-01-01

    The present work describes a relatively new programme module, which is enhanced in the recently released versions of SAP2000 software. The new module, called Bridge Modeler, is intended for simple, parametric mathematical modelling of bridges. The modelling procedure is explained on a test case through the steps of a user-friendly Bridge Wizard. For each step, we described the basic principles and the application possibilities as well as some limitations. We also explained two types of analys...

  10. GaAs-MnAs nanowires

    Energy Technology Data Exchange (ETDEWEB)

    Sadowski, Janusz [MAX-Lab, Lund University, P.O. Box 118, 221 00 Lund (Sweden); Institute of Physics, Polish Academy of Sciences, al. Lotnikow 32/46, 02-668 Warszawa (Poland); Siusys, Aloyzas; Wojciechowski, Tomasz; Reszka, Anna; Kowalski, Bogdan [Institute of Physics, Polish Academy of Sciences, al. Lotnikow 32/46, 02-668 Warszawa (Poland); Kovacs, Andras; Kasama, Takeshi [Center for Electron Nanoscopy, Technical University of Denmark, Kgs. Lyngby 2800 (Denmark); Dunin-Borkowski, Rafal E. [Center for Electron Nanoscopy, Technical University of Denmark, Kgs. Lyngby 2800 (Denmark); Institute for Microstructure Research, Peter Gruenberg Institute, Forschungszentrum Juelich, 52425 Juelich (Germany)

    2011-07-15

    Different strategies for obtaining nanowires (NWs) with ferromagnetic properties using the molecular beam epitaxy (MBE) grown nanostructures combining GaAs and Mn were investigated. Four types of structures have been studied: (i) self-catalyzed GaAs:Mn NWs grown at low temperatures on GaAs(100) substrates; (ii) GaAs:Mn NWs grown at high temperatures on Si(100) substrates; (iii) GaAs-GaMnAs core-shell NW structures; (iv) GaAs-MnAs core-shell NW structures grown on Si(100). Structures of types (i), (iii), and (iv) exhibit ferromagnetic properties. Right: Scanning electron microscopy image of Mn doped GaAs NWs with Ga droplets at the tops, grown by MBE on oxidized Si(100) substrate in the autocatalytic growth mode. (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  11. Buddha and the bridging relations.

    Science.gov (United States)

    Banerjee, Rahul

    2008-01-01

    The chapter reviews a classical Indian model of consciousness found in the Abhidhamma, a collection of seven treatises in the Pali Canon Tipitaka. The model was based on observations made during advanced vipassana practice, a first-person method taught by the Buddha. The climax of the model consists in the elucidation of 24 'Bridging Relations' causally linking the stream of consciousness, its contents and associated physical events. Review of such a model based on a specialized first-person technique could prove to be a resource of useful ideas providing directions for further research.

  12. Family Medicine: Bridge to Life.

    Science.gov (United States)

    Luz, Clare

    2016-01-01

    Reflecting on the suicide of a close friend, this essay explores what comprises, and inspires a will to live, and how those in Family Medicine can address suicide risk even in the face of debilitating or terminal illness. Research indicates that the will to live is a measurable indicator of general well-being, distinct from depression, and an important predictor of a person's motivation to "hold on to life". As such, understanding what is at the heart of a desire to live should alter clinical practice. This essay offers ideas for ways in which to create bridges for patients that could help sustain life.

  13. Nanoclusters a bridge across disciplines

    CERN Document Server

    Jena, Purusottam

    2010-01-01

    This comprehensive book on Nanoclusters comprises sixteen authoritative chapters written by leading researchers in the field. It provides insight into topics that are currently at the cutting edge of cluster science, with the main focus on metal and metal compound systems that are of particular interest in materials science, and also on aspects related to biology and medicine. While there are numerous books on clusters, the focus on clusters as a bridge across disciplines sets this book apart from others. Delivers cutting edge coverage of cluster science Covers a broad range of topics in

  14. A bridge to advanced mathematics

    CERN Document Server

    Sentilles, Dennis

    2011-01-01

    This helpful workbook-style ""bridge"" book introduces students to the foundations of advanced mathematics, spanning the gap between a practically oriented calculus sequence and subsequent courses in algebra and analysis with a more theoretical slant. Part 1 focuses on logic and number systems, providing the most basic tools, examples, and motivation for the manner, method, and concerns of higher mathematics. Part 2 covers sets, relations, functions, infinite sets, and mathematical proofs and reasoning. Author Dennis Sentilles also discusses the history and development of mathematics as well a

  15. Two bimetallic W(Ⅳ)-Mn(Ⅱ) complexes based on octacyanometallates:structures and magnetic properties

    Institute of Scientific and Technical Information of China (English)

    LIU BaoLin; XIAO HongPing; SONG You; YOU XiaoZeng

    2009-01-01

    Two cyano-bridged heterobimetallic coordination polymers,[{Mn(dpa)_2}_2W(CN)_8·CH_3GN·4H_2O]_n(1) (dpa =2,2'-dipyridylamine) and[Mn_2(H_2O)_4{W(CN)_8}·3H_2O]_n (2),have been synthesized and characterized structurally and magnetically.X-ray analysis shows that complex 1 is a one-dimensional (1-D) polymer of W_2(CN)_4Mn_2 square units in which adjacent square fragments are interlinked by sharing[W(CN)_8]~(4-)moieties to form an infinite chain.Complex 2 is a three-dimensional (3-D) polymer,which shows an unforeseen structure,exhibiting a 3-D open network with a 1-D channel (ca.13.21 (A) ×11.82 (A)).Fitting of the magnetic properties indicates that both polymers exhibit weakly antiferromagnetic interactions between the adjacent Mn ions.

  16. Review of Energy Harvesters Utilizing Bridge Vibrations

    Directory of Open Access Journals (Sweden)

    Farid Ullah Khan

    2016-01-01

    Full Text Available For health monitoring of bridges, wireless acceleration sensor nodes (WASNs are normally used. In bridge environment, several forms of energy are available for operating WASNs that include wind, solar, acoustic, and vibration energy. However, only bridge vibration has the tendency to be utilized for embedded WASNs application in bridge structures. This paper reports on the recent advancements in the area of vibration energy harvesters (VEHs utilizing bridge oscillations. The bridge vibration is narrowband (1 to 40 Hz with low acceleration levels (0.01 to 3.8 g. For utilization of bridge vibration, electromagnetic based vibration energy harvesters (EM-VEHs and piezoelectric based vibration energy harvesters (PE-VEHs have been developed. The power generation of the reported EM-VEHs is in the range from 0.7 to 1450000 μW. However, the power production by the developed PE-VEHs ranges from 0.6 to 7700 μW. The overall size of most of the bridge VEHs is quite comparable and is in mesoscale. The resonant frequencies of EM-VEHs are on the lower side (0.13 to 27 Hz in comparison to PE-VEHs (1 to 120 Hz. The power densities reported for these bridge VEHs range from 0.01 to 9539.5 μW/cm3 and are quite enough to operate most of the commercial WASNs.

  17. CONDITION RATING SYSTEM FOR THAILAND'S CONCRETE BRIDGES

    Directory of Open Access Journals (Sweden)

    Bonaventure H.W. Hadikusumo

    2010-06-01

    Full Text Available The Bridge Management System is designed to maximise use of available data and determine the optimal strategy to perform necessary improvements to bridges in the most cost-effective manner. This paper provides a condition rating system to meet the requirements of Thailand’s Department of Highways (DOH. A rating system to assess the existing condition of bridges is proposed. Segmental inspection is developed to execute efficient element-level evaluations and collect data that demonstrate deterioration patterns in bridge elements. The paper also describes inspection procedures for field survey execution, which enables observed distresses at the level of sub-elements or members to be allocated. Recommendations from bridge experts reveal that the proposed rating system is robust, implementable in actual practice, and suitable for efficient application in evaluating the nation’s concrete highway bridges. Although the bridge condition rating was developed in response to the specific characteristics of Thailand’s bridges, the proposed methodology can easily be extended to other bridge agencies.

  18. A data management infrastructure for bridge monitoring

    Science.gov (United States)

    Jeong, Seongwoon; Byun, Jaewook; Kim, Daeyoung; Sohn, Hoon; Bae, In Hwan; Law, Kincho H.

    2015-04-01

    This paper discusses a data management infrastructure framework for bridge monitoring applications. As sensor technologies mature and become economically affordable, their deployment for bridge monitoring will continue to grow. Data management becomes a critical issue not only for storing the sensor data but also for integrating with the bridge model to support other functions, such as management, maintenance and inspection. The focus of this study is on the effective data management of bridge information and sensor data, which is crucial to structural health monitoring and life cycle management of bridge structures. We review the state-of-the-art of bridge information modeling and sensor data management, and propose a data management framework for bridge monitoring based on NoSQL database technologies that have been shown useful in handling high volume, time-series data and to flexibly deal with unstructured data schema. Specifically, Apache Cassandra and Mongo DB are deployed for the prototype implementation of the framework. This paper describes the database design for an XML-based Bridge Information Modeling (BrIM) schema, and the representation of sensor data using Sensor Model Language (SensorML). The proposed prototype data management framework is validated using data collected from the Yeongjong Bridge in Incheon, Korea.

  19. Assessment of the Reliability of Concrete Bridges

    DEFF Research Database (Denmark)

    Middleton, C. R.; Thoft-Christensen, Palle

    a significant shift in emphasis for the highways authorities around the world away from the design of new structures over to maintaining the existing infrastructure. As a result, bridge owners are seeking improved ways of inspecting, assessing, maintaining and repairing their existing stock of bridges...... in the wake of ever increasing traffic loads and volumes, and an ageing population of bridges subject to various mechanisms of deterioration. The goal is to optimise the allocation of limited resources whilst maintaining their bridges in a safe and serviceable condition. Reliability analysis is one tool being...

  20. Thermodynamic Properties of Mn-C Melts

    Institute of Scientific and Technical Information of China (English)

    CHEN Er-bao; WANG Shi-jun

    2008-01-01

    Carbon solubility in Mn-Fe melts (xMn=0.161-0.706, xFe=0.034-0.633) was measured experimentally at various temperatures. By thermodynamic derivation and calculation, the relationship between activity coefficient of carbon in infinite dilute solution of manganese in Mn-C system and temperature was obtained. Using Gibbs-Duhem relationship, the experimental results of this study, and experimental data reported in references, the relationship between other thermodynamic properties in Mn-C system and temperature were obtained by thermodynamic derivation and calculation.

  1. A method for making Mn02 electrodes

    Energy Technology Data Exchange (ETDEWEB)

    Ikeda, M.; Nisino, A.

    1983-03-30

    A layer of Mn02, produced during thermal breakdown of manganese salts, is applied to a metallic current outlead. Then a mixture of granulated Mn02 and an electricity conducting additive and a binder is applied to this layer. The electrode contains 1 to 5 percent by mass epoxide resin, 5 to 15 percent by mass carbon powder, 0.1 to 10 percent by mass beta-Mn02 and 70 to 90 percent by mass gamma-Mn02. The electrode has high mechanical strength and good discharge characteristics.

  2. 23 CFR 650.409 - Evaluation of bridge inventory.

    Science.gov (United States)

    2010-04-01

    ... 23 Highways 1 2010-04-01 2010-04-01 false Evaluation of bridge inventory. 650.409 Section 650.409... Evaluation of bridge inventory. (a) Sufficiency rating of bridges. Upon receipt and evaluation of the bridge inventory, a sufficiency rating will be assigned to each bridge by the Secretary in accordance with...

  3. 23 CFR 650.807 - Bridges requiring a USCG permit.

    Science.gov (United States)

    2010-04-01

    ... 23 Highways 1 2010-04-01 2010-04-01 false Bridges requiring a USCG permit. 650.807 Section 650.807... BRIDGES, STRUCTURES, AND HYDRAULICS Navigational Clearances for Bridges § 650.807 Bridges requiring a USCG... improvement or construction of a bridge over navigable waters except for the exemption exercised by FHWA...

  4. 33 CFR 118.65 - Lights on fixed bridges.

    Science.gov (United States)

    2010-07-01

    ... 33 Navigation and Navigable Waters 1 2010-07-01 2010-07-01 false Lights on fixed bridges. 118.65 Section 118.65 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY BRIDGES BRIDGE LIGHTING AND OTHER SIGNALS § 118.65 Lights on fixed bridges. (a) Each fixed bridge span over a...

  5. 33 CFR 118.70 - Lights on swing bridges.

    Science.gov (United States)

    2010-07-01

    ... 33 Navigation and Navigable Waters 1 2010-07-01 2010-07-01 false Lights on swing bridges. 118.70 Section 118.70 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY BRIDGES BRIDGE LIGHTING AND OTHER SIGNALS § 118.70 Lights on swing bridges. (a) Swing span lights on through bridges....

  6. 33 CFR 118.85 - Lights on vertical lift bridges.

    Science.gov (United States)

    2010-07-01

    ... 33 Navigation and Navigable Waters 1 2010-07-01 2010-07-01 false Lights on vertical lift bridges... BRIDGES BRIDGE LIGHTING AND OTHER SIGNALS § 118.85 Lights on vertical lift bridges. (a) Lift span lights. The vertical lift span of every vertical lift bridge shall be lighted so that the center of...

  7. Finite element of multilayer surfacing systems on orthotropic steel bridges

    NARCIS (Netherlands)

    Li, J.; Liu, X.; Scarpas, A.; Tzimiris, G.

    2013-01-01

    Light weight orthotropic steel bridge decks have been widely utilized for bridges in seismic zones, movable bridges and long span bridges. In the last three decades, severe problems were reported in relation to asphaltic surfacing materials on orthotropic steel deck bridges. Earlier investigations h

  8. Light-weight aluminium bridges and bridge decks. An overview of recent applications

    NARCIS (Netherlands)

    Maljaars, J.; Soetens, F.; Kluyver, D. de

    2008-01-01

    The last decades have shown a large increase in the application of aluminium alloys for light-weight bridges. For bridge construction, aluminium alloys have some specific advantages, but also some points of attention. This paper deals with some recent projects of aluminium bridges, and for these pro

  9. The Bridge of Mandolin County

    Science.gov (United States)

    Lantz, Juliette M.; Feindt, Jenny E.; Lewellyn, Eric P. B.; Walczak, Mary M.

    1999-12-01

    The Bridge of Mandolin County is a case designed to teach the general chemistry principles of molar mass, ions and aqueous reactions, solubility rules, and inorganic nomenclature. Through the instructor-facilitated class discussion, students consider the options before the Mandolin Town Council regarding deicing the newly constructed bridge connecting Mandolin with a large nearby city. The students must decipher contradictory claims made on behalf of sodium chloride, the traditional deicer, and calcium magnesium acetate, a new environmentally friendly deicer, to arrive at the most cost-effective and environmentally appropriate deicing product. As they work through the analysis they raise questions that can be addressed in a laboratory setting. Four optional role-playing experiments are included, which can be used by the students to gather information helpful to resolution of the case. The case is intended to be used over two class periods, with a laboratory period in between, though suggestions for other models are provided. Laboratory procedures include an EDTA titration for Ca2+ and Mg2+, a gravimetric analysis, a qualitative examination of ions and solubility, an introduction to freezing point depression and measurement, and an experimental design activity. This case can also successfully be used without alteration in non-majors chemistry or environmental chemistry courses, or upper-level analytical or environmental chemistry courses.

  10. Global monitoring concept for bridges

    Science.gov (United States)

    Bergmeister, Konrad; Santa, Ulrich

    2000-06-01

    Knowledge of the integrity of in-service structures on a continuous time basis is an ultimate objective for owners and maintenance authorities. The development of a life extension and/or replacement strategy for highway structures is a crucial point in an effective bridge management system. A key component of such a bridge management system is a means of surveillance techniques and determining the condition of an existing structure within the normative and budgetary constraints. Recent advances in sensing technologies and material/structure damage characterization combined with current developments in computations and communications have resulted in a significant interest in developing diagnostic technologies for monitoring the integrity of and for the detection of damages of structures. To identify anomalies and deterioration processes, it is essential to understand the relationships between the signal measurements and the real occurred phenomena. Therefore, the comparison of measured and calculated data in order to tune and validate the mechanical and numerical model assumptions is an integral part of any system analysis. Finally, the interpreted results of all measurements should be the basis for the condition assessment and the safety evaluation of a structure to facilitate replacement and repair decisions.

  11. Bridging history and social psychology

    DEFF Research Database (Denmark)

    Glaveanu, Vlad Petre; Yamamoto, Koji

    2012-01-01

    This special issue aims to bridge history and social psychology by bringing together historians and social psychologists in an exercise of reading and learning from each other’s work. This interdisciplinary exercise is not only timely but of great importance for both disciplines. Social psycholog......This special issue aims to bridge history and social psychology by bringing together historians and social psychologists in an exercise of reading and learning from each other’s work. This interdisciplinary exercise is not only timely but of great importance for both disciplines. Social...... psychologists can benefit from engaging with historical sources by being able to contextualise their findings and enrich their theoretical models. It is not only that all social and psychological phenomena have a history but this history is very much part of present-day and future developments. On the other...... hand historians can enhance their analysis of historical sources by drawing upon the conceptual tools developed in social psychology. They can “test” these tools and contribute to their validation and enrichment from completely different perspectives. Most important, as contributions to this special...

  12. The rhetoric of communicating knowledge through the project website

    DEFF Research Database (Denmark)

    Kampf, Constance

    of rhetoric.  This paper looks at the I35 W bridge reconstruction project in Minneapolis through web-based communication by the Minnesota Department of Transportation (MnDOT) about the project. The MnDOT bridge reconstruction website will be examined using a combination of 1). Weick's notion of sensemaking...... and 2). Kress and VanLeeuwan's notions of multimodal discourse.  These concepts are combined to examine the project website as a site for knowledge communication processes between MnDOT and the Twin Cities community about the bridge reconstruction project. Results lead to an understanding...... of the rhetorical processes operating via the project website as an element in the socio-technical design of the bridge....

  13. Tuning of Exchange Coupling and Switchable Magnetization Dynamics by Displacing the Bridging Ligands Observed in Two Dimeric Manganese(III) Compounds

    Science.gov (United States)

    Liu, Xiang-Yu; Cen, Pei-Pei; Wu, Li-Zhou; Li, Fei-Fei; Song, Wei-Ming; Xie, Gang; Chen, San-Ping

    2017-03-01

    Two Mn(III)-based dimers, [Mn2(bpad)2(CH3O)4]n (1) and [Mn2(bpad)2(pa)2]n·2H2O (2) (Hbpad = N3-benzoylpyridine-2-carboxamidrazone, H2pa = phthalic acid), have been assembled from a tridentate Schiff-base chelator and various anionic coligands. Noteworthily, compound 1 could be identified as a reaction precursor to transform to 2 in the presence of phthalic acid, resulting in a rarely structural conversion process in which the bridges between intradimer Mn(III) ions alter from methanol oxygen atom with μ2-O mode in 1 (Mn Mn distance of 3.046 Å) to syn-anti carboxylate in 2 (Mn Mn distance of 4.043 Å), while the Mn(III) centers retain hexa-coordinated geometries with independently distorted octahedrons in two compounds. The dc magnetic determinations reveal that ferromagnetic coupling between two metal centers with J = 1.31 cm‑1 exists in 1, whereas 2 displays weak antiferromagnetic interactions with the coupling constant J of ‑0.56 cm‑1. Frequency-dependent ac susceptibilities in the absence of dc field for 1 suggest slow relaxation of the magnetization with an energy barrier of 13.9 K, signifying that 1 features single-molecule magnet (SMM) behavior. This work presents a rational strategy to fine-tune the magnetic interactions and further magnetization dynamics of the Mn(III)-containing dinuclear units through small structural variations driven by the ingenious chemistry.

  14. Salt-bridge energetics in halophilic proteins.

    Directory of Open Access Journals (Sweden)

    Arnab Nayek

    Full Text Available Halophilic proteins have greater abundance of acidic over basic and very low bulky hydrophobic residues. Classical electrostatic stabilization was suggested as the key determinant for halophilic adaptation of protein. However, contribution of specific electrostatic interactions (i.e. salt-bridges to overall stability of halophilic proteins is yet to be understood. To understand this, we use Adaptive-Poison-Boltzmann-Solver Methods along with our home-built automation to workout net as well as associated component energy terms such as desolvation energy, bridge energy and background energy for 275 salt-bridges from 20 extremely halophilic proteins. We then perform extensive statistical analysis on general and energetic attributes on these salt-bridges. On average, 8 salt-bridges per 150 residues protein were observed which is almost twice than earlier report. Overall contributions of salt-bridges are -3.0 kcal mol-1. Majority (78% of salt-bridges in our dataset are stable and conserved in nature. Although, average contributions of component energy terms are equal, their individual details vary greatly from one another indicating their sensitivity to local micro-environment. Notably, 35% of salt-bridges in our database are buried and stable. Greater desolvation penalty of these buried salt-bridges are counteracted by stable network salt-bridges apart from favorable equal contributions of bridge and background terms. Recruitment of extensive network salt-bridges (46% with a net contribution of -5.0 kcal mol-1 per salt-bridge, seems to be a halophilic design wherein favorable average contribution of background term (-10 kcal mol-1 exceeds than that of bridge term (-7 kcal mol-1. Interiors of proteins from halophiles are seen to possess relatively higher abundance of charge and polar side chains than that of mesophiles which seems to be satisfied by cooperative network salt-bridges. Overall, our theoretical analyses provide insight into halophilic

  15. Structural, electronic and magnetic properties of Co{sub 2}MnSi/Ag(1 0 0) interface

    Energy Technology Data Exchange (ETDEWEB)

    Feng, Yu [School of Physical Science and Technology, Southwest University, Chongqing 400715 (China); Wu, Bo [Department of Physics, Zunyi Normal College, Zunyi 563002 (China); Yuan, Hongkuan [School of Physical Science and Technology, Southwest University, Chongqing 400715 (China); Chen, Hong, E-mail: chenh@swu.edu.cn [School of Physical Science and Technology, Southwest University, Chongqing 400715 (China)

    2015-02-25

    Highlights: • Interfacial MnSi atoms prefer to locate in the bridge sites between two Ag atoms. • A2 disorder of Co{sub 2}MnSi layers near the interface is most likely to occur. • Spin polarization is reduced by interface itself and interfacial disorder. - Abstract: The performance of advanced current-perpendicular-to-plane giant magnetoresistance (MR) built of ferromagnetic (FM) electrodes and nonmagnetic metals as a spacer depends decisively on the properties of the FM/metal interface. Here we investigate the interface character between Co{sub 2}MnSi and Ag by using the first-principles density functional simulations. To simulate the actual cases, we build two types of interfaces, namely {sub t}O and {sub b}O interfaces by connecting the most favorable MnSi-termination of nine ordered Co{sub 2}MnSi layers to the top of Ag and the bridge site between two Ag atoms of seven atomic layers, respectively. Our calculations indicate that the {sub b}O interface is more probable to form in the growth than the {sub t}O interface due to the lower formation energy and interface free energy, and the interface states occur in the minority-spin gap, leading to the destruction of half-metallicity of the ordered Co{sub 2}MnSi. Further, taking into account the atomic disorder of the Co{sub 2}MnSi layers near the interface, we show that the A2 disorder is most likely to occur in the layers close to the interface due to the lower formation energy and interface free energy, and the interface states occurring in the spin-minority gap are strengthened and the spin polarization is further degraded by the A2 disorder of Co{sub 2}MnSi layers. Therefore, the spin-polarization reduction induced by interface itself and the disorder of Co{sub 2}MnSi layers close to the interface, together with the interface roughness indicated by the calculations, may be main causes of very low MR ratio.

  16. Pulse electron paramagnetic resonance studies of the interaction of methanol with the S2 state of the Mn4O5Ca cluster of photosystem II.

    Science.gov (United States)

    Oyala, Paul H; Stich, Troy A; Stull, Jamie A; Yu, Fangting; Pecoraro, Vincent L; Britt, R David

    2014-12-23

    The binding of the substrate analogue methanol to the catalytic Mn4CaO5 cluster of the water-oxidizing enzyme photosystem II is known to alter the electronic structure properties of the oxygen-evolving complex without retarding O2-evolution under steady-state illumination conditions. We report the binding mode of (13)C-labeled methanol determined using 9.4 GHz (X-band) hyperfine sublevel-correlation (HYSCORE) and 34 GHz (Q-band) electron spin-echo electron nuclear double resonance (ESE-ENDOR) spectroscopies. These results are compared to analogous experiments on a mixed-valence Mn(III)Mn(IV) complex (2-OH-3,5-Cl2-salpn)2Mn(III)Mn(IV) (salpn = N,N'-bis(3,5-dichlorosalicylidene)-1,3-diamino-2-hydroxypropane) in which methanol ligates to the Mn(III) ion ( Larson et al. (1992) J. Am. Chem. Soc. , 114 , 6263 ). In the mixed-valence Mn(III,IV) complex, the hyperfine coupling to the (13)C of the bound methanol (Aiso = 0.65 MHz, T = 1.25 MHz) is appreciably larger than that observed for (13)C methanol associated with the Mn4CaO5 cluster poised in the S2 state, where only a weak dipolar hyperfine interaction (Aiso = 0.05 MHz, T = 0.27 MHz) is observed. An evaluation of the (13)C hyperfine interaction using the X-ray structure coordinates of the Mn4CaO5 cluster indicates that methanol does not bind as a terminal ligand to any of the manganese ions in the oxygen-evolving complex. We favor methanol binding in place of a water ligand to the Ca(2+) in the Mn4CaO5 cluster or in place of one of the waters that form hydrogen bonds with the oxygen bridges of the cluster.

  17. A Statistical Observation of Crowns and Bridges in 1988 Part 2 : Bridge

    OpenAIRE

    小林, 賢一; 小坂, 茂; 柳田, 史城; 稲生, 衡樹; 大島, 俊明; 高橋, 喜博; 岩井, 啓三; 甘利, 光治; 中根, 卓

    1991-01-01

    A study was made of 207 bridges which had been fabricated for patients at the Prosthodontic Clinic of Matsumoto Dental College during 1988. Some of results were as follows; 1) 47.3% of the patients were males and 52.7% were females. 2) 92.8% of the patients were between 20 and 69 years old. 3) 65.2%of the bridges were fabricated as 3-unit bridges. 4) 77.8% were fabricated as 1-pontic bridges. 5) There were fewer bridge retainers for the lower anterior segment than for other segments. 6) 52.3%...

  18. Heavy Vehicles on Minor Highway Bridges

    DEFF Research Database (Denmark)

    Kirkegaard, Poul Henning; Nielsen, Søren R. K.; Enevoldsen, I.

    the results obtained using the numerical models given in details in "Heavy Vehicles on Minor Highway Bridges : dynamic modelling of vehicles and bridges". The models are established using a ordinary vehicle which consists of a 48 t Scania with a 3 axle tractor and a 3 axle trailer, joined in a flexible hinge...

  19. Passing the Einstein-Rosen bridge

    CERN Document Server

    Katanaev, M O

    2013-01-01

    We relax the requirement of geodesic completeness of a space-time. Instead, we require test particles trajectories to be smooth only in the physical sector. Test particles trajectories for Einstein--Rosen bridge are proved to be smooth in the physical sector, and particles can freely penetrate the bridge in both directions.

  20. COUPLING VIBRATION OF VEHICLE-BRIDGE SYSTEM

    Institute of Scientific and Technical Information of China (English)

    陈炎; 黄小清; 马友发

    2004-01-01

    By applying the sinusoidal wave mode to simulate the rugged surface of bridge deck,accounting for vehicle-bridge interaction and using Euler-Bernoulli beam theory, a coupling vibration model of vehicle-bridge system was developed. The model was solved by mode analyzing method and Runge-Kutta method, and the dynamic response and the resonance curve of the bridge were obtained. It is found that there are two resonance regions, one represents the main resonance while the other the minor resonance, in the resonance curve. The influence due to the rugged surface, the vibration mode of bridge, and the interaction between vehicle and bridge on vibration of the system were discussed. Numerical results show that the influence due to these parameters is so significant that the effect of roughness of the bridge deck and the mode shape of the bridge can't be ignored and the vehicle velocity should be kept away from the critical speed of the vehicle.

  1. Active aerodynamic stabilisation of long suspension bridges

    DEFF Research Database (Denmark)

    Nissen, Henrik Ditlev; Sørensen, Paul Haase; Jannerup, Ole Erik

    2004-01-01

    The paper describes the addition of actively controlled appendages (flaps) attached along the length of the bridge deck to dampen wind-induced oscillations in long suppension bridges. A novel approach using control systems methods for the analysis of dynamic stability is presented. In order to ma...

  2. General framework for bridge life cycle design

    Institute of Scientific and Technical Information of China (English)

    Junhai MA; Airong CHEN; Jun HE

    2009-01-01

    Based on a detailed illustration for bridge life cycle design which comprises the processes of service life design, aesthetics design, performance design, environ-mental and ecological design, inspection, maintenance and repair design as well as cost analysis, this paper presented a general framework for bridge life cycle design comprising three design phases and six design processes.

  3. Re-Assessment of Concrete Bridges

    DEFF Research Database (Denmark)

    Thoft-Christensen, Palle

    In this paper two aspects of re-assessment of the reliability of concrete bridges are discussed namely modelling of the corrosion of reinforcement and updating of uncertain variables. The main reason for deterioration of concrete bridges is corrosion of the reinforcement. Therefore, modelling...

  4. Lifetime Reliability Assessment of Concrete Slab Bridges

    DEFF Research Database (Denmark)

    Thoft-Christensen, Palle

    A procedure for lifetime assesment of the reliability of short concrete slab bridges is presented in the paper. Corrosion of the reinforcement is the deterioration mechanism used for estimating the reliability profiles for such bridges. The importance of using sensitivity measures is stressed. Fi...

  5. Precast Pearl-Chain concrete arch bridges

    DEFF Research Database (Denmark)

    Halding, Philip Skov; Hertz, Kristian Dahl; Schmidt, Jacob Wittrup

    2015-01-01

    A Pearl-Chain Bridge is a closed-spandrel arch bridge consisting of a number of straight pre-fabricated so called Super-Light Deck elements put together in an arch shape by post-tensioning cables. Several Pearl-Chain arches can be positioned adjacent to each other by a crane to achieve a bridge...... the technology was used. We also study other important components and details in the Pearl-Chain Bridge concept and review the effects of different types of loads. A theoretical case study of a circular 30 m span Pearl-Chain Bridge is presented showing the influence of a number of parameters: The number of post-tensioning......, and gives a large positive bending moment below the load and a smaller negative bending moment in the unloaded side. When the Pearl-Chain Bridge concept is compared to other pre-fabricated arch bridge solutions we find a number of advantages when using Pearl-Chain Bridges: Straight elements, combination...

  6. Thermal diffusion of Mn through GaAs overlayers on (Ga, Mn)As.

    Science.gov (United States)

    Adell, J; Ulfat, I; Ilver, L; Sadowski, J; Karlsson, K; Kanski, J

    2011-03-02

    Thermally stimulated diffusion of Mn through thin layers of GaAs has been studied by x-ray photoemission. (Ga, Mn)As samples with 5 at% Mn were capped with 4, 6 and 8 monolayer (ML) GaAs, and Mn diffusing through the GaAs was trapped on the surface by means of amorphous As. It was found that the out-diffusion is completely suppressed for an 8 ML thick GaAs film. The short diffusion length is attributed to an electrostatic barrier formed at the (Ga, Mn)As/GaAs interface.

  7. Thermal diffusion of Mn through GaAs overlayers on (Ga, Mn)As

    Energy Technology Data Exchange (ETDEWEB)

    Adell, J; Ulfat, I; Ilver, L; Kanski, J [Department of Applied Physics, Chalmers University of Technology, SE-412 96 Gothenburg (Sweden); Sadowski, J [Institute of Physics, Polish Academy of Sciences, PL-02-668 Warsaw (Poland); Karlsson, K [Department of Life Sciences, University of Skoevde, SE-541 28 Skoevde (Sweden)

    2011-03-02

    Thermally stimulated diffusion of Mn through thin layers of GaAs has been studied by x-ray photoemission. (Ga, Mn)As samples with 5 at% Mn were capped with 4, 6 and 8 monolayer (ML) GaAs, and Mn diffusing through the GaAs was trapped on the surface by means of amorphous As. It was found that the out-diffusion is completely suppressed for an 8 ML thick GaAs film. The short diffusion length is attributed to an electrostatic barrier formed at the (Ga, Mn)As/GaAs interface.

  8. Mechanical alloying of Fe-Mn and Fe-Mn-Si

    Institute of Scientific and Technical Information of China (English)

    1999-01-01

    The ball milling of Fe-24Mn and Fe-24Mn-6Si mixed powders has been performed by the high energy ball milling technique.By employing X-ray diffraction and Moessbauer measurements.The ccmposition evolution during the milling process has been investigated.The results indicate the formation of paramagnetic Fe-Mn or Fe-Mn-Si alloys with a metastable fcc phase as final products.which imply that the Fe and Mn proceed a co-diffusion meenanism through the surface of fragmented powders.The thermal stability and composition evolution of the as-milled alloys were discussed comparing with the bulk alloy,.

  9. Seismic response of steel suspension bridge

    Energy Technology Data Exchange (ETDEWEB)

    McCallen, D.B. [Lawrence Livermore National Lab., CA (United States); Astaneh-Asl, A. [California Univ., Berkeley, CA (United States). Dept. of Civil and Environmental Engineering

    1996-11-01

    Performing accurate, realistic numerical simulations of the seismic response of long-span bridges presents a significant challenge to the fields of earthquake engineering and seismology. Suspension bridges in particular represent some of the largest and most important man-made structures and ensuring the seismic integrity of these mega-structures is contingent on accurate estimations of earthquake ground motions and accurate computational simulations of the structure/foundation system response. A cooperative, multi-year research project between the Univ. of California and LLNL was recently initiated to study engineering and seismological issues essential for simulating the response of major structures. Part of this research project is focused on the response of the long-span bridges with the San Francisco-Oakland Bay Bridge serving as a case study. This paper reports on the status of this multi-disciplinary research project with emphasis on the numerical simulation of the transient seismic response of the Bay Bridge.

  10. Optimum Maintenance Strategies for Highway Bridges

    DEFF Research Database (Denmark)

    Frangopol, Dan M.; Thoft-Christensen, Palle; Das, Parag C.;

    As bridges become older and maintenance costs become higher, transportation agencies are facing challenges related to implementation of optimal bridge management programs based on life cycle cost considerations. A reliability-based approach is necessary to find optimal solutions based on minimum...... expected life-cycle costs or maximum life-cycle benefits. This is because many maintenance activities can be associated with significant costs, but their effects on bridge safety can be minor. In this paper, the program of an investigation on optimum maintenance strategies for different bridge types...... is described. The end result of this investigation will be a general reliability-based framework to be used by the UK Highways Agency in order to plan optimal strategies for the maintenance of its bridge network so as to optimize whole-life costs....

  11. Valence state of Mn in Ca-doped LaMnO3 studied by high-resolution Mn K ß emission spectroscopy

    NARCIS (Netherlands)

    Tyson, T.A.; Qian, Q.; Kao, C.-C.; Rueff, J.-P.; Groot, F.M.F. de; Croft, M.; Cheong, S.-W.; Greenblatt, M.; Subramanian, M.A.

    2001-01-01

    Mn K ß x-ray emission spectra provide a direct method to probe the effective spin state and charge density on the Mn atom and is used in an experimental study of a class of Mn oxides. Specifically, the Mn K ß line positions and detailed spectral shapes depend on the oxidation and the spin state of t

  12. Building bridges … and accelerators

    CERN Multimedia

    2009-01-01

    Lyn Evans, the LHC project leader, was awarded an honorary doctorate from the University of Geneva (UNIGE) to celebrate his role not just in building accelerators, but also in building bridges between nations. He was one of four notables honoured at the event on Friday 5 June, coinciding with the University’s 450th Anniversary. Lyn Evans arriving at the ceremony with Archbishop Desmond Tutu. "It was a big surprise when I found out I’d been nominated," recounts Evans, "but it was an even bigger surprise to find out with whom I’d been nominated". At the ceremony Evans was awarded the honorary doctorate along with three others: Archbishop Desmond Tutu, who was acclaimed for his fight against apartheid in South Africa, Mary Robinson, first woman president of Ireland and former United Nations’ high commissioner of human rights, and Pascal Lamy, Director-General of the World Trade Organization. The award ceremony, known as the �...

  13. Identification of the interstitial Mn site in ferromagnetic (Ga,Mn)As

    Energy Technology Data Exchange (ETDEWEB)

    Lima, T. A. L.; Augustyns, V.; Temst, K.; Vantomme, A.; Pereira, L. M. C., E-mail: lino.pereira@fys.kuleuven.be [KU Leuven, Instituut voor Kern- en Stralingsfysica, 3001 Leuven (Belgium); Wahl, U.; Costa, A.; Correia, J. G. [Centro de Ciências e Tecnologias Nucleares, Instituto Superior Técnico, Universidade de Lisboa, 2686-953 Sacavém (Portugal); Silva, D. J.; Araújo, J. P. [IFIMUP and IN-Institute of Nanoscience and Nanotechnology, Universidade do Porto, 4169-007 Porto (Portugal); Houben, K.; Van Bael, M. J. [Laboratory of Solid-State Physics and Magnetism, KU Leuven, 3001 Leuven (Belgium); Edmonds, K. W.; Gallagher, B. L.; Campion, R. P. [School of Physics and Astronomy, University of Nottingham, Nottingham NG7 2RD (United Kingdom); Silva, M. R. da [Centro de Física Nuclear, Universidade de Lisboa, Lisboa 1649-003 (Portugal)

    2015-01-05

    We determined the lattice location of Mn in ferromagnetic (Ga,Mn)As using the electron emission channeling technique. We show that interstitial Mn occupies the tetrahedral site with As nearest neighbors (T{sub As}) both before and after thermal annealing at 200 °C, whereas the occupancy of the tetrahedral site with Ga nearest neighbors (T{sub Ga}) is negligible. T{sub As} is therefore the energetically favorable site for interstitial Mn in isolated form as well as when forming complexes with substitutional Mn. These results shed new light on the long standing controversy regarding T{sub As} versus T{sub Ga} occupancy of interstitial Mn in (Ga,Mn)As.

  14. Effect of Mn and MnS on corrosion properties of domestic pipeline steels and welds

    Institute of Scientific and Technical Information of China (English)

    李云涛; 杜则裕; 陶勇寅; 李建军

    2004-01-01

    Base metals of domestic pipeline steels were used to study the effect of Mn on corrosion properties of SSCC(Sulfide Stress Corrosion Cracking), and welds were carried out to study the effect of MnS on corrosion properties of HIC (Hydrogen Induced Cracking) both in solutions with wet hydrogen sulfide(H2S). They were respectively conducted by referring to the standards of SSCC and HIC. Testing results revealed that with the increase of content Mn, the resistance of SSCC will be decreased, from the point of metallurgic view, and it is Mn element not C element to lead to the testing results of SSCC. Meanwhile, even under the condition without inclusions MnS, HIC in welds still occurred. That is to say, MnS is not necessary for HIC, the presence of local banded structures in which Mn and P are inclined to aggregate cause to the phenomena of HIC.

  15. Redetermination of brackebuschite, Pb2Mn3+(VO4)2(OH)

    Science.gov (United States)

    Lafuente, Barbara; Downs, Robert T.

    2016-01-01

    The crystal structure of brackebuschite, ideally Pb2Mn3+(VO4)2(OH) [dilead(II) manganese(III) vanadate(V) hydroxide], was redetermined based on single-crystal X-ray diffraction data of a natural sample from the type locality Sierra de Cordoba, Argentina. Improving on previous results, anisotropic displacement parameters for all non-H atoms were refined and the H atom located, obtaining a significant improvement of accuracy and an unambiguous hydrogen-bonding scheme. Brackebuschite belongs to the brackebuschite group of minerals with general formula A 2 M(T1O4)(T2O4)(OH, H2O), with A = Pb2+, Ba, Ca, Sr; M = Cu2+, Zn, Fe2+, Fe3+, Mn3+, Al; T1 = As5+, P, V5+; and T2 = As5+, P, V5+, S6+. The crystal structure of brackebuschite is based on a cubic closest-packed array of O and Pb atoms with infinite chains of edge-sharing [Mn3+O6] octa­hedra located about inversion centres and decorated by two unique VO4 tetra­hedra (each located on a special position 2e, site symmetry m). One type of VO4 tetra­hedra is linked with the 1 ∞[MnO4/2O2/1] chain by one common vertex, alternating with H atoms along the chain, while the other type of VO4 tetra­hedra link two adjacent octa­hedra by sharing two vertices with them and thereby participating in the formation of a three-membered Mn2V ring between the central atoms. The 1 ∞[Mn3+(VO4)2OH] chains run parallel to [010] and are held together by two types of irregular [PbOx] polyhedra (x = 8, 11), both located on special position 2e (site symmetry m). The magnitude of the libration component of the O atoms of the 1 ∞[Mn3+(VO4)2OH] chain increases linearly with the distance from the centerline of the chain, indicating a significant twisting to and fro of the chain along [010]. The hy­droxy group bridges one Pb2+ cation with two Mn3+ cations and forms an almost linear hydrogen bond with a vanadate group of a neighbouring chain. The O⋯O distance of this inter­action determined from the structure refinement agrees well with

  16. Redetermination of brackebuschite, Pb2Mn(3+)(VO4)2(OH).

    Science.gov (United States)

    Lafuente, Barbara; Downs, Robert T

    2016-03-01

    The crystal structure of brackebuschite, ideally Pb2Mn(3+)(VO4)2(OH) [dilead(II) manganese(III) vanadate(V) hydroxide], was redetermined based on single-crystal X-ray diffraction data of a natural sample from the type locality Sierra de Cordoba, Argentina. Improving on previous results, anisotropic displacement parameters for all non-H atoms were refined and the H atom located, obtaining a significant improvement of accuracy and an unambiguous hydrogen-bonding scheme. Brackebuschite belongs to the brackebuschite group of minerals with general formula A 2 M(T1O4)(T2O4)(OH, H2O), with A = Pb(2+), Ba, Ca, Sr; M = Cu(2+), Zn, Fe(2+), Fe(3+), Mn(3+), Al; T1 = As(5+), P, V(5+); and T2 = As(5+), P, V(5+), S(6+). The crystal structure of brackebuschite is based on a cubic closest-packed array of O and Pb atoms with infinite chains of edge-sharing [Mn(3+)O6] octa-hedra located about inversion centres and decorated by two unique VO4 tetra-hedra (each located on a special position 2e, site symmetry m). One type of VO4 tetra-hedra is linked with the (1) ∞[MnO4/2O2/1] chain by one common vertex, alternating with H atoms along the chain, while the other type of VO4 tetra-hedra link two adjacent octa-hedra by sharing two vertices with them and thereby participating in the formation of a three-membered Mn2V ring between the central atoms. The (1) ∞[Mn(3+)(VO4)2OH] chains run parallel to [010] and are held together by two types of irregular [PbO x ] polyhedra (x = 8, 11), both located on special position 2e (site symmetry m). The magnitude of the libration component of the O atoms of the (1) ∞[Mn(3+)(VO4)2OH] chain increases linearly with the distance from the centerline of the chain, indicating a significant twisting to and fro of the chain along [010]. The hy-droxy group bridges one Pb(2+) cation with two Mn(3+) cations and forms an almost linear hydrogen bond with a vanadate group of a neighbouring chain. The O⋯O distance of this inter-action determined from the

  17. Oscillations in a sunspot with light bridges

    CERN Document Server

    Yuan, Ding; Huang, Zhenghua; Li, Bo; Su, Jiangtao; Yan, Yihua; Tan, Baolin

    2014-01-01

    Solar Optical Telescope onboard Hinode observed a sunspot (AR 11836) with two light bridges (LBs) on 31 Aug 2013. We analysed a 2-hour \\ion{Ca}{2} H emission intensity data set and detected strong 5-min oscillation power on both LBs and in the inner penumbra. The time-distance plot reveals that 5-min oscillation phase does not vary significantly along the thin bridge, indicating that the oscillations are likely to originate from the underneath. The slit taken along the central axis of the wide light bridge exhibits a standing wave feature. However, at the centre of the wide bridge, the 5-min oscillation power is found to be stronger than at its sides. Moreover, the time-distance plot across the wide bridge exhibits a herringbone pattern that indicates a counter-stream of two running waves originated at the bridge sides. Thus, the 5-min oscillations on the wide bridge also resemble the properties of running penumbral waves. The 5-min oscillations are suppressed in the umbra, while the 3-min oscillations occupy...

  18. Signal and noise in bridging PCR

    Directory of Open Access Journals (Sweden)

    Thaler David S

    2002-07-01

    Full Text Available Abstract Background In a variant of the standard PCR reaction termed bridging, or jumping, PCR the primer-bound sequences are originally on separate template molecules. Bridging can occur if, and only if, the templates contain a region of sequence similarity. A 3' end of synthesis in one round of synthesis that terminates in this region of similarity can prime on the other. In principle, Bridging PCR (BPCR can detect a subpopulation of one template that terminates synthesis in the region of sequence shared by the other template. This study considers the sensitivity and noise of BPCR as a quantitative assay for backbone interruptions. Bridging synthesis is also important to some methods for computing with DNA. Results In this study, BPCR was tested over a 328 base pair segment of the E. coli lac operon and a signal to noise ratio (S/N of approximately 10 was obtained under normal PCR conditions with Taq polymerase. With special precautions in the case of Taq or by using the Stoffel fragment the S/N was improved to 100, i.e. 1 part of cut input DNA yielded the same output as 100 parts of intact input DNA. Conclusions In the E. coli lac operator region studied here, depending on details of protocol, between 3 and 30% per kilobase of final PCR product resulted from bridging. Other systems are expected to differ in the proportion of product that is bridged consequent to PCR protocol and the sequence analyzed. In many cases physical bridging during PCR will have no informational consequence because the bridged templates are of identical sequence, but in a number of special cases bridging creates, or, destroys, information.

  19. Building the clinical bridge: an Australian success.

    Science.gov (United States)

    Wallis, Marianne; Chaboyer, Wendy

    2012-01-01

    Nursing effectiveness science includes primary, secondary, and translational, clinically focused research activities which aim to improve patient or client outcomes. It is imperative, for the successful conduct of a program of nursing effectiveness science, that a clinical bridge is established between academic and healthcare service facilities. An Australian example of the development of a robust clinical bridge through the use of jointly funded positions at the professorial level is outlined. In addition, an analysis of the practical application of Lewin's model of change management and the contribution of both servant and transformational leadership styles to the bridge building process is provided.

  20. Building the Clinical Bridge: An Australian Success

    Directory of Open Access Journals (Sweden)

    Marianne Wallis

    2012-01-01

    Full Text Available Nursing effectiveness science includes primary, secondary, and translational, clinically focused research activities which aim to improve patient or client outcomes. It is imperative, for the successful conduct of a program of nursing effectiveness science, that a clinical bridge is established between academic and healthcare service facilities. An Australian example of the development of a robust clinical bridge through the use of jointly funded positions at the professorial level is outlined. In addition, an analysis of the practical application of Lewin’s model of change management and the contribution of both servant and transformational leadership styles to the bridge building process is provided.

  1. Asymptotics of a horizontal liquid bridge

    Science.gov (United States)

    Haynes, M.; O'Brien, S. B. G.; Benilov, E. S.

    2016-04-01

    This paper uses asymptotic techniques to find the shape of a two dimensional liquid bridge suspended between two vertical walls. We model the equilibrium bridge shape using the Laplace-Young equation. We use the Bond number as a small parameter to deduce an asymptotic solution which is then compared with numerical solutions. The perturbation approach demonstrates that equilibrium is only possible if the contact angle lies within a hysteresis interval and the analysis relates the width of this interval to the Bond number. This result is verified by comparison with a global force balance. In addition, we examine the quasi-static evolution of such a two dimensional bridge.

  2. Calculations in bridge aeroelasticity via CFD

    Energy Technology Data Exchange (ETDEWEB)

    Brar, P.S.; Raul, R.; Scanlan, R.H. [Johns Hopkins Univ., Baltimore, MD (United States)

    1996-12-31

    The central focus of the present study is the numerical calculation of flutter derivatives. These aeroelastic coefficients play an important role in determining the stability or instability of long, flexible structures under ambient wind loading. A class of Civil Engineering structures most susceptible to such an instability are long-span bridges of the cable-stayed or suspended-span variety. The disastrous collapse of the Tacoma Narrows suspension bridge in the recent past, due to a flutter instability, has been a big impetus in motivating studies in flutter of bridge decks.

  3. Gust loading on streamlined bridge decks

    DEFF Research Database (Denmark)

    Larose, Guy; Mann, Jakob

    1998-01-01

    The current analytical description of the buffeting action of wind on long-span bridges is based on the strip assumption. However, recent experiments on closed-box girder bridge decks have shown that this assumption is not valid and is the source of an important part of the error margin...... of the analytical prediction methods. In this paper, an analytical model that departs from the strip assumption is used to describe the gust loading on a thin airfoil. A parallel is drawn between the analytical model and direct measurements of gust loading on motionless closed-box girder bridge decks. Empirical...

  4. Transformation of the bridge during drop separation

    Science.gov (United States)

    Chashechkin, Yu. D.; Prokhorov, V. E.

    2016-05-01

    The geometry of flows during separation of pendant drops of liquids with significantly different physical properties (alcohol, water, glycerin, oil) has been studied by high-speed video recording. The dynamics of the processes involving the formation of bridges of two characteristic shapes—slightly nonuniform in thickness and with thinning of the upper and lower ends—has been investigated. It has been shown that the shape change of the separated bridge has a number of stages determined by the properties of the liquid. As a result, the bridge is transformed into a small drop—a satellite drop.

  5. Closure technique for the hybrid girder cable stayed bridge of Edong Bridge

    Institute of Scientific and Technical Information of China (English)

    Liu Minghu; Tan Hao; Xu GuoPing; Zhao Canhui

    2012-01-01

    Based on Edong Yangtze River Bridge, which is the second longest hybrid girder cable stayed bridge with 926 m long main span, the influencing factors and crucial techniques of the main span closure method for long span hybrid girder cable stayed bridge are studied. After theoretical analysis, numerical evaluation and practical test, the loading assistant closure method is employed in Edong Yangtze River Bridge. The loading assistant closure method, with better thermal adaptability and less influence on bridge line and the forced status, can meet the requirements of the unstressed state control method. Based on the mentioned advantages, the loading assistant closure method is applicable to long span hybrid girder cable stayed bridges. The conclusion can provide a reference for the further design of the similar brid~es.

  6. Charge, orbital and spin ordering phenomena in the mixed valence manganite (NaMn3+3)(Mn3+2Mn4+2)O12

    Science.gov (United States)

    Prodi, A.; Gilioli, E.; Gauzzi, A.; Licci, F.; Marezio, M.; Bolzoni, F.; Huang, Q.; Santoro, A.; Lynn, J. W.

    2004-01-01

    Mixed-valence manganites with the ABO3 perovskite structure display a variety of magnetic and structural transitions, dramatic changes of electrical conductivity and magnetoresistance effects. The physical properties vary with the relative concentration of Mn3+ and Mn4+ in the octahedral corner-sharing network, and the proportion of these two cations is usually changed by doping the trivalent large A cation (for example, La3+) with divalent cations. As the dopant and the original cation have, in general, different sizes, and as they are distributed randomly in the structure, such systems are characterized by local distortions that make it difficult to obtain direct information about their crystallographic and physical properties. On the other hand, the double oxides of formula AA'3Mn4O12 contain a perovskite-like network of oxygen octahedra centred on the Mn cations, coupled with an ordered arrangement of the A and A' cations, whose valences control the proportion of Mn3+ and Mn4+ in the structure. The compound investigated in this work, (NaMn3+3)(Mn3+2Mn4+2)O12, contains an equal number of Mn3+ and Mn4+ in the octahedral sites. We show that the absence of disorder enables the unambiguous determination of symmetry, the direct observation of full, or nearly full, charge ordering of Mn3+ and Mn4+ in distinct crystallographic sites, and a nearly perfect orbital ordering of the Mn3+ octahedra.

  7. Mn vacancy defects, grain boundaries, and A-phase stability of helimagnet MnSi.

    Science.gov (United States)

    Ou-Yang, T Y; Shu, G J; Lin, J-Y; Hu, C D; Chou, F C

    2016-01-20

    Mn vacancy defect and grain size are shown to modify the magnetic phase diagram of MnSi significantly, especially near the critical regime of A-phase (skyrmion lattice) formation and the helimagnetic phase transition. Crystals grown using controlled nonstoichiometric initial precursors creates both grain boundaries and intrinsic Mn vacancy defect of various levels in MnSi. The results of combined transport, specific heat, and AC spin susceptibility measurements are compared for MnSi single crystal samples of various manganese deficiency levels and grain sizes. The finite-size effect and Mn vacancy level dependent helical phase transition temperature T(c) have been identified and verified. The stability of A-phase in H-T phase space has been examined through AC spin susceptibility data analysis.

  8. Mn vacancy defects, grain boundaries, and A-phase stability of helimagnet MnSi

    Science.gov (United States)

    Ou-Yang, T. Y.; Shu, G. J.; Lin, J.-Y.; Hu, C. D.; Chou, F. C.

    2016-01-01

    Mn vacancy defect and grain size are shown to modify the magnetic phase diagram of MnSi significantly, especially near the critical regime of A-phase (skyrmion lattice) formation and the helimagnetic phase transition. Crystals grown using controlled nonstoichiometric initial precursors creates both grain boundaries and intrinsic Mn vacancy defect of various levels in MnSi. The results of combined transport, specific heat, and AC spin susceptibility measurements are compared for MnSi single crystal samples of various manganese deficiency levels and grain sizes. The finite-size effect and Mn vacancy level dependent helical phase transition temperature {{T}\\text{c}} have been identified and verified. The stability of A-phase in H-T phase space has been examined through AC spin susceptibility data analysis.

  9. Diode-quad bridge circuit means

    Science.gov (United States)

    Harrison, D. R.; Dimeff, J. (Inventor)

    1975-01-01

    A transducer and frequency discriminator circuit is described including a four-terminal circulating diode bridge, a first pair of capacitors connected in series across two terminals of the bridge, and a second pair of capacitors, or other impedance elements, connected in series across the other two terminals of the bridge. A source of balanced alternating electrical energy for energizing the circuit is coupled between the commonly connected plates of the first pair of capacitors and the commonly connected plates of the second pair of capacitors. Due to the operation of the diode bridge, the sum of the resultant charges developed on the first pair of capacitors is proportional to the relationship between the respective capacitors of the second pair, and consequently, an output voltage taken across the first pair of capacitors will be proportional to that relationship.

  10. Allegheny County-Owned Bridges Points

    Data.gov (United States)

    Allegheny County / City of Pittsburgh / Western PA Regional Data Center — This dataset shows the location of bridges owned by Allegheny County as centroids. If viewing this description on the Western Pennsylvania Regional Data Center’s...

  11. Allegheny County-Owned Bridges Centerlines

    Data.gov (United States)

    Allegheny County / City of Pittsburgh / Western PA Regional Data Center — This dataset shows the bridges owned by Allegheny County. If viewing this description on the Western Pennsylvania Regional Data Center’s open data portal...

  12. Relaxation of liquid bridge after droplets coalescence

    Directory of Open Access Journals (Sweden)

    Jiangen Zheng

    2016-11-01

    Full Text Available We investigate the relaxation of liquid bridge after the coalescence of two sessile droplets resting on an organic glass substrate both experimentally and theoretically. The liquid bridge is found to relax to its equilibrium shape via two distinct approaches: damped oscillation relaxation and underdamped relaxation. When the viscosity is low, damped oscillation shows up, in this approach, the liquid bridge undergoes a damped oscillation process until it reaches its stable shape. However, if the viscous effects become significant, underdamped relaxation occurs. In this case, the liquid bridge relaxes to its equilibrium state in a non-periodic decay mode. In depth analysis indicates that the damping rate and oscillation period of damped oscillation are related to an inertial-capillary time scale τc. These experimental results are also testified by our numerical simulations with COMSOL Multiphysics.

  13. Wheatstone bridge technique for magnetostriction measurements.

    Science.gov (United States)

    Sullivan, M

    1980-03-01

    A basic Wheatstone bridge, with additional electronic instrumentation, has been used in the measurement of magnetostriction. This method allows a resolution of approximately 10% on measurements of magnetostrictions less than 0.75 parts per million.

  14. VT Short Structures - Bridges and Culverts

    Data.gov (United States)

    Vermont Center for Geographic Information — Inspection data for structures (bridge and culvert) between 6 feet and 20 feet in length inspected on State road system. Stewards: Information Technology, Data...

  15. VT Long Structures - Bridges and Culverts

    Data.gov (United States)

    Vermont Center for Geographic Information — Inspection data for structures (bridge and culvert) greater than 20 feet in length inspected on both State and local road systems. Stewards: Information Technology,...

  16. Active Control of Long Bridges Using Flaps

    DEFF Research Database (Denmark)

    Hansen, H. I.; Thoft-Christensen, Palle

    The main problem in designing ultra-long span suspension bridges is flutter. A solution to this problem might be to introduce an active flap control system to increase the flutter wind velocity. The investigated flap control system consists of flaps integrated in the bridge girder so each flap...... is the streamlined part of the edge of the girder. Additional aerodynamic derivatives are shown for the flaps and it is shown how methods already developed can be used to estimate the flutter wind velocity for a bridge section with flaps. As an example, the flutter wind velocity is calculated for different flap...... configurations for a bridge section model by using aerodynamic derivatives for a flat plate. The example shows that different flap configurations can either increase or decrease the flutter wind velocity. for optimal flap configurations flutter will not occur....

  17. Pilot testing of a hydraulic bridge exciter

    Directory of Open Access Journals (Sweden)

    Andersson Andreas

    2015-01-01

    Full Text Available This paper describes the development of a hydraulic bridge exciter and its first pilot testing on a full scale railway bridge in service. The exciter is based on a hydraulic load cylinder with a capacity of 50 kN and is intended for controlled dynamic loading up to at least 50 Hz. The load is applied from underneath the bridge, enabling testing while the railway line is in service. The system is shown to produce constant load amplitude even at resonance. The exciter is used to experimentally determine frequency response functions at all sensor locations, which serve as valuable input for model updating and verification. An FE-model of the case study bridge has been developed that is in good agreement with the experimental results.

  18. Practical Approach to Fragility Analysis of Bridges

    Directory of Open Access Journals (Sweden)

    Yasamin Rafie Nazari

    2012-12-01

    Full Text Available Damages during past earthquakes reveal seismic vulnerability of bridge structures and the necessity of probabilistic approach toward seismic performance evaluation of bridges and its interpretation in terms of decision variables such as repair cost, downtime and life loss. This Procedure involves hazard analysis, structural analysis, damage analysis and loss analysis. The purpose of present study is reviewing different methods developed to derive fragility curves for damage analysis of bridges and demonstrating a simple procedure for fragility analysis using Microsoft Office Excel worksheet to reach probability of occurring predefined level of damage due to different levels of seismic demand parameters. The input of this procedure is the intensity of ground motion and the output is an appropriate estimate of the expected damage. Different observed damages of the bridges are discussed and compared the practical definition of damage states. Different methods of fragility analyses are discussed and a practical step by step example is illustrated.

  19. Magnetic Properties of AIIBIVCV2 Compounds Doped with Mn

    Directory of Open Access Journals (Sweden)

    A.V. Kochura

    2013-12-01

    Full Text Available Mn-doped AIIBIVCV2 semiconductors bulk crystals were grown by direct melting of base components with fast cooling. Structural and magnetic properties of samples were investigated. Analysis of the temperature dependence of the magnetization reveals three types of magnetic species: the substitutional Mn ions making Mn complexes (especially dimers, the MnAs micro- and nanosize precepitates.

  20. Effect of Mn and Fe on the Formation of Fe- and Mn-Rich Intermetallics in Al–5Mg–Mn Alloys Solidified Under Near-Rapid Cooling

    Directory of Open Access Journals (Sweden)

    Yulin Liu

    2016-01-01

    Full Text Available Mn was an important alloying element used in Al–Mg–Mn alloys. However, it had to be limited to a low level (<1.0 wt % to avoid the formation of coarse intermetallics. In order to take full advantage of the benefits of Mn, research was carried out to investigate the possibility of increasing the content of Mn by studying the effect of cooling rate on the formation of Fe- and Mn-rich intermetallics at different content levels of Mn and Fe. The results indicated that in Al–5Mg–Mn alloy with low Fe content (<0.1 wt %, intermetallic Al6(Fe,Mn was small in size and amount. With increasing Mn content, intermetallic Al6(Fe,Mn increased, but in limited amount. In high-Fe-containing Al–5Mg–Mn alloys (0.5 wt % Fe, intermetallic Al6(Fe,Mn became the dominant phase, even in the alloy with low Mn content (0.39 wt %. Cooling rate played a critical role in the refinement of the intermetallics. Under near-rapid cooling, intermetallic Al6(Fe,Mn was extremely refined. Even in the high Mn and/or high-Fe-containing alloys, it still demonstrated fine Chinese script structures. However, once the alloy composition passed beyond the eutectic point, the primary intermetallic Al6(Fe,Mn phase displayed extremely coarse platelet-like morphology. Increasing the content of Fe caused intermetallic Al6(Fe,Mn to become the primary phase at a lower Mn content.

  1. An anti-ferromagnetic terephthalate-bridged trigonal prismatic dinuclear manganese(II) complex: Synthon of rare anion $^{\\ldots}$ interaction promoting dimensionality

    Indian Academy of Sciences (India)

    Somnath Choubey; Soumi Chattopadhayay; Kishalay Bhar; Subhasis Roy; Sumitava Khan; Joan Ribas; Barindra Kumar Ghosh

    2014-11-01

    A dinuclear compound [Mn2(L)2(-tp)](PF6)2·3.57H2O (1) [L = N,N′-(bis(pyridin-2-yl)benzylidene)-1,3-propanediamine and tp = terephthalate dianion] has been isolated and characterized on the basis of microanalytical, spectroscopic and other physicochemical properties. X-ray structural study showed interesting bis(bidentate) bridging motif of tp in the dicationic dinuclear unit [Mn2(-tp)]2+. Each manganese(II) centre adopts a rare distorted trigonal prismatic geometry with an MnN4O2 chromophore.Chelation of the tetradentate Schiff base (L) along with bis(bidentate) bridging of two O atoms of tp complete hexacoordination around each manganese(II) centre. The dinuclear units of 1 are associated through cooperative C-H$\\cdots$F hydrogen bonds and $^{\\cdot}$ , C-H$^{\\cdots}$ and rare anion$^{\\cdots}$ interactions to promote the dimensionality in a graded manner. Variable temperature magnetic susceptibility measurement of 1 in the 2-300 K temperature range revealed weak antiferromagnetic interaction presumably due to long bridging arm of tp.

  2. Synthesis, structural studies, and oxidation catalysis of the late-first-row-transition-metal complexes of a 2-pyridylmethyl pendant-armed ethylene cross-bridged cyclam.

    Science.gov (United States)

    Jones, Donald G; Wilson, Kevin R; Cannon-Smith, Desiray J; Shircliff, Anthony D; Zhang, Zhan; Chen, Zhuqi; Prior, Timothy J; Yin, Guochuan; Hubin, Timothy J

    2015-03-02

    The first 2-pyridylmethyl pendant-armed ethylene cross-bridged cyclam ligand has been synthesized and successfully complexed to Mn(2+), Fe(2+), Co(2+), Ni(2+), Cu(2+), and Zn(2+) cations. X-ray crystal structures were obtained for all six complexes and demonstrate pentadentate binding of the ligand with the requisite cis-V configuration of the cross-bridged cyclam ring in all cases, leaving a potential labile binding site cis to the pyridine donor for interaction of the complex with oxidants and/or substrates. The electronic properties of the complexes were evaluated using solid-state magnetic moment determination and acetonitrile solution electronic spectroscopy, which both agree with the crystal structure determination of high-spin divalent metal complexes in all cases. Cyclic voltammetry in acetonitrile revealed reversible redox processes in all but the Ni(2+) complex, suggesting that catalytic reactivity involving electron-transfer processes is possible for complexes of this ligand. Kinetic studies of the dissociation of the ligand from the copper(II) complex under strongly acidic conditions and elevated temperatures revealed that the pyridine pendant arm actually destabilizes the complex compared to the parent cross-bridged cyclam complex. Screening for oxidation catalysis using hydrogen peroxide as the terminal oxidant for the most biologically relevant Mn(2+), Fe(2+), and Cu(2+) complexes identified the Mn(2+) complex as a potential mild oxidation catalyst worthy of continued development.

  3. Identifying hidden sexual bridging communities in Chicago.

    Science.gov (United States)

    Youm, Yoosik; Mackesy-Amiti, Mary Ellen; Williams, Chyvette T; Ouellet, Lawrence J

    2009-07-01

    Bridge populations can play a central role in the spread of human immunodeficiency virus (HIV) by providing transmission links between higher and lower prevalence populations. While social network methods are well suited to the study of bridge populations, analyses tend to focus on dyads (i.e., risk between drug and/or sex partners) and ignore bridges between distinct subpopulations. This study takes initial steps toward moving the analysis of sexual network linkages beyond individual and risk group levels to a community level in which Chicago's 77 community areas are examined as subpopulations for the purpose of identifying potential bridging communities. Of particular interest are "hidden" bridging communities; that is, areas with above-average levels of sexual ties with other areas but whose below-average AIDS prevalence may hide their potential importance for HIV prevention. Data for this analysis came from the first wave of recruiting at the Chicago Sexual Acquisition and Transmission of HIV Cooperative Agreement Program site. Between August 2005 through October 2006, respondent-driven sampling was used to recruit users of heroin, cocaine, or methamphetamine, men who have sex with men regardless of drug use, the sex partners of these two groups, and sex partners of the sex partners. In this cross-sectional study of the sexual transmission of HIV, participants completed a network-focused computer-assisted self-administered interview, which included questions about the geographic locations of sexual contacts with up to six recent partners. Bridging scores for each area were determined using a matrix representing Chicago's 77 community areas and were assessed using two measures: non-redundant ties and flow betweenness. Bridging measures and acquired immunodeficiency syndrome (AIDS) case prevalence rates were plotted for each community area on charts representing four conditions: below-average bridging and AIDS prevalence, below-average bridging and above

  4. 49 CFR 237.33 - Content of bridge management programs.

    Science.gov (United States)

    2010-10-01

    ... 49 Transportation 4 2010-10-01 2010-10-01 false Content of bridge management programs. 237.33... Content of bridge management programs. Each bridge management program adopted in compliance with this part... spans, span lengths, and all other information necessary to provide for the management of bridge...

  5. 23 CFR 650.705 - Application for discretionary bridge funds.

    Science.gov (United States)

    2010-04-01

    ... TRAFFIC OPERATIONS BRIDGES, STRUCTURES, AND HYDRAULICS Discretionary Bridge Candidate Rating Factor § 650... cost, current average daily truck traffic and a narrative describing the existing bridge, the proposed new or rehabilitated bridge and other relevant factors which the State believes may warrant...

  6. 33 CFR 118.80 - Lights on bascule bridges.

    Science.gov (United States)

    2010-07-01

    ... 33 Navigation and Navigable Waters 1 2010-07-01 2010-07-01 false Lights on bascule bridges. 118.80 Section 118.80 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY BRIDGES BRIDGE LIGHTING AND OTHER SIGNALS § 118.80 Lights on bascule bridges. (a) Lift span lights. Each lift span...

  7. 33 CFR 118.90 - Bridges crossing channel obliquely.

    Science.gov (United States)

    2010-07-01

    ... 33 Navigation and Navigable Waters 1 2010-07-01 2010-07-01 false Bridges crossing channel obliquely. 118.90 Section 118.90 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY BRIDGES BRIDGE LIGHTING AND OTHER SIGNALS § 118.90 Bridges crossing channel obliquely....

  8. 23 CFR 650.809 - Movable span bridges.

    Science.gov (United States)

    2010-04-01

    ... 23 Highways 1 2010-04-01 2010-04-01 false Movable span bridges. 650.809 Section 650.809 Highways FEDERAL HIGHWAY ADMINISTRATION, DEPARTMENT OF TRANSPORTATION ENGINEERING AND TRAFFIC OPERATIONS BRIDGES, STRUCTURES, AND HYDRAULICS Navigational Clearances for Bridges § 650.809 Movable span bridges. A fixed...

  9. Detection of salt bridges to lysines in solution in barnase

    DEFF Research Database (Denmark)

    Hansen, Poul Erik; Williamson, Michael P.; Hounslow, Andrea M.

    2013-01-01

    We show that salt bridges involving lysines can be detected by deuterium isotope effects on NMR chemical shifts of the sidechain amine. Lys27 in the ribonuclease barnase is salt bridged, and mutation of Arg69 to Lys retains a partially buried salt bridge. The salt bridges are functionally important....

  10. Inspection Based Evaluation of a Danish Road Bridge

    DEFF Research Database (Denmark)

    Thoft-Christensen, Palle

    In this paper it is shown how an inspection-based evaluation of a Danish road bridge may be performed using the BRIDGE1 and BRIDGE2 bridge management systems produced within the EC-supported research programme "Assessment of Performance and Optimal Strategies for Inspection and Maintenance...

  11. Micromechanical model of cross-over fibre bridging - Prediction of mixed mode bridging laws

    DEFF Research Database (Denmark)

    Sørensen, Bent F.; Gamstedt, E.K.; Østergaard, Rasmus Christian;

    2008-01-01

    on the observed bridging mechanism, a micromechanical model is developed for the prediction of macroscopic mixed mode bridging laws (stress-opening laws). The model predicts a high normal stress for very small openings, decreasing rapidly with increasing normal and tangential crack opening displacements......The fracture resistance of fibre composites can be greatly enhanced by crack bridging. In situ observations of mixed mode crack growth in a unidirectional carbon-fibre/epoxy composite reveal crack bridging by single fibres and by beam-like ligaments consisting of several fibres. Based...

  12. Thermal Bridge Effects in Walls Separating Rowhouses

    DEFF Research Database (Denmark)

    Rose, Jørgen

    1997-01-01

    In this report the thermal bridge effects at internal wall/roof junctions in rowhouses are evaluated. The analysis is performed using a numerical calculation programme, and different solutions are evaluated with respect to extra heat loss and internal surface temperatures.......In this report the thermal bridge effects at internal wall/roof junctions in rowhouses are evaluated. The analysis is performed using a numerical calculation programme, and different solutions are evaluated with respect to extra heat loss and internal surface temperatures....

  13. Heavy Vehicles on Minor Highway Bridges

    DEFF Research Database (Denmark)

    Nielsen, Søren R. K.; Kirkegaard, Poul Henning; Enevoldsen, I.

    The present paper worked out as a part of a research project on "Dynamic amplification factor of vehicle loadings on smaller bridges" establishes a two-dimensional spectral description of the road roughness surface based on measurements from a Danish road using so-called Profilograph used by Danish...... to the bridge and the stochastic nature of the surface roughness are included into the model....

  14. Earthquake Resistance of Integral Abutment Bridges

    OpenAIRE

    2009-01-01

    intermediate length bridges. Integral abutment construction eliminates joints and bearings which reduce long-term maintenance costs. However, in the absence of joints and bearings, the bridge abutments and foundations must be able to accommodate lateral movements from thermal expansion and contraction of the superstructure and from seismic events. Previous research has focused on the response to thermal expansion and contraction. The current research examines the response of integral abutment...

  15. Arch bridges – unlocking their potential

    OpenAIRE

    Long, Adrian; Nanukuttan, Sreejith

    2016-01-01

    Arch bridges are strong, durable, aesthetically pleasing and require little maintenance but very few have been built since the early 1900s. However, this trend has changed as more than 60 FlexiArch bridges have been installed since the system was launched in 2007. The FlexiArch uses precast concrete voussoirs, requires neither corrodible reinforcement, nor centring, can be installed in hours and is contractor friendly. Details of this innovative method of construction and installation of arch...

  16. External Prestressing Bridge Reinforcement Technology Review

    Directory of Open Access Journals (Sweden)

    Zhu Hanbing

    2015-01-01

    Full Text Available Externally prestressed bridge can not only limit and reduce the cracks and deformation of the structure, improve the rigidity and bearing capacity of structure, improve the stress state of structure, but also have less interference for bridge operation when it is operating and have the good economic efficiency. This paper introduces the advantages and disadvantages of external prestressed strengthening technique, its calculation theory and construction technology described in detail, and finally the paper discusses the deficiency of existing research.

  17. Synthesis of nanosize MnO2 and its performence

    Institute of Scientific and Technical Information of China (English)

    顾大明; 魏杰

    2003-01-01

    Sol sol-gel method and solid phase redox reaction were respectively applied in preparation of Nanos-ize MnO2 powders. The experiments showed that only Mn2O3 could be obtained from ignition of Mn( Ⅱ ) in themuffle furnace in air, and Mn2O3 had to be disproportionated in acids to gain MnO2. The analysis of XRD andTEM technique revealed that the diameters of nanosize MnO2 obtained by sol-gel method was 35 ~45 nm andthe x in MnOx was 1.9; the particle size of MnO2 produced from solid phase redox reaction was 10 ~ 20 nm andthe x in MnOx equaled 1.94. The test results have proved that the discharge property of alkaline-manganese bat-tery could be improved by nanosize MnO2.

  18. Framework for Bridges Maintenance in Egypt

    Directory of Open Access Journals (Sweden)

    Hesham Abd Elkhalek

    2016-01-01

    Full Text Available The traditional approaches for bridges maintenance is proven to be inefficient as they lead to random way of spending maintenance budget and deteriorating bridge conditions. In many cases, maintenance activities are performed due to user complaints. The objective of this paper is to develop a practical and reliable framework to manage the maintenance and repair activities of Bridges network in Egypt considering performance and budget limits. The model solves an optimization problem that maximizes the average condition of the network given the limited budget using Genetic Algorithm (GA. The main tasks of the system are bridge inventory, condition assessment, deterioration using markov model, and maintenance optimization. The developed model takes into account multiple parameters including serviceability requirements, budget allocation, element importance on structural safety and serviceability, bridge impact on network, and traffic. A questionnaire is conducted to complete the research scope. The proposed model is implemented in software, which provides a friendly user interface. The results of the framework are multi – year maintenance plan for the entire network for up to five years. A case study is presented for validating and testing the model with Data collected from “General Authority for Roads, Bridges and Land Transport” in Egypt.

  19. I-5/Gilman advanced technology bridge project

    Science.gov (United States)

    Lanza di Scalea, Francesco; Karbhari, Vistasp M.; Seible, Frieder

    2000-04-01

    The UCSD led I-5/Gilman Advanced Technology Bridge Project will design and construct a fully functional traffic bridge of advanced composite materials across Interstate 5 in La Jolla, California. Its objective is to demonstrate the use of advanced composite technologies developed by the aerospace industry in commercial applications to increase the life expectancy of new structures and for the rehabilitation of aging infrastructure components. The structure will be a 450 ft long, 60 ft wide cable-stayed bridge supported by a 150 ft A-frame pylon with two vehicular lanes, two bicycle lanes, pedestrian walkways and utility tunnels. The longitudinal girders and pylon will be carbon fiber shells filled with concrete. The transverse deck system will consist of hollow glass/carbon hybrid tubes and a polypropylene fiber reinforced concrete deck with an arch action. Selected cables will be composite. The bridge's structural behavior will be monitored to determine how advanced composite materials perform in civil infrastructure applications. The bridge will be instrumented to obtain performance and structural health data in real time and, where possible, in a remote fashion. The sensors applied to the bridge will include electrical resistance strain gages, fiberoptic Bragg gratings and accelerometers.

  20. Magnetic coupling in ferromagnetic semiconductor (Ga,Mn)As/(Al,Ga,Mn)As bilayers

    Energy Technology Data Exchange (ETDEWEB)

    Wang, M.; Wadley, P.; Campion, R. P.; Rushforth, A. W.; Edmonds, K. W.; Gallagher, B. L. [School of Physics and Astronomy, University of Nottingham, University Park, Nottingham NG7 2RD (United Kingdom); Charlton, T. R.; Kinane, C. J.; Langridge, S. [ISIS, Rutherford Appleton Laboratory, Harwell Science and Innovation Campus, Science and Technology Facilities Council, Oxon OX11 0QX (United Kingdom)

    2015-08-07

    We report on a study of ferromagnetic semiconductor (Ga,Mn)As/(Al,Ga,Mn)As bilayers using magnetometry and polarized neutron reflectivity (PNR). From depth-resolved characterization of the magnetic structure obtained by PNR, we concluded that the (Ga,Mn)As and (Al,Ga,Mn)As layers have in-plane and perpendicular-to-plane magnetic easy axes, respectively, with weak interlayer coupling. Therefore, the layer magnetizations align perpendicular to each other under low magnetic fields and parallel at high fields.

  1. Topological Weyl semimetals in the chiral antiferromagnetic materials Mn3Ge and Mn3Sn

    Science.gov (United States)

    Yang, Hao; Sun, Yan; Zhang, Yang; Shi, Wu-Jun; Parkin, Stuart S. P.; Yan, Binghai

    2017-01-01

    Recent experiments revealed that Mn3Sn and Mn3Ge exhibit a strong anomalous Hall effect at room temperature, provoking us to explore their electronic structures for topological properties. By ab initio band structure calculations, we have observed the existence of multiple Weyl points in the bulk and corresponding Fermi arcs on the surface, predicting antiferromagnetic Weyl semimetals in Mn3Ge and Mn3Sn. Here the chiral antiferromagnetism in the Kagome-type lattice structure is essential to determine the positions and numbers of Weyl points. Our work further reveals a new guiding principle to search for magnetic Weyl semimetals among materials that exhibit a strong anomalous Hall effect.

  2. Magnetic depth profile in GaMnAs layers with vertically graded Mn concentrations

    Energy Technology Data Exchange (ETDEWEB)

    Leiner, J., E-mail: leinerjc@ornl.gov [Oak Ridge National Laboratory, Oak Ridge, TN 37831 (United States); Kirby, B.J. [Center for Neutron Research, NIST, Gaithersburg, MD 20899 (United States); Fitzsimmons, M.R. [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Tivakornsasithorn, K. [Department of Physics, Faculty of Science, Mahidol Univeristy, Bangkok 10400 (Thailand); Liu, X.; Furdyna, J.K.; Dobrowolska, M. [Department of Physics, University of Notre Dame, Notre Dame, IN 46556 (United States)

    2014-01-15

    Controlled vertical grading of magnetization of the ferromagnetic semiconductor GaMnAs represents a significant step toward optimizing its magnetic properties for device applications. Quantitative control of such grading is difficult due to various competing effects, such as Mn diffusion, self-annealing, and diffusion of charge carriers. Furthermore, there are also several surface effects that can influence the magnetization profile, which should be considered in designing and fabricating graded GaMnAs specimens. However, we show that vertical magnetization gradients in GaMnAs layers can be readily achieved by appropriate growth strategies. In this paper we describe the preparation, magnetization measurements, and polarized neutron reflectometry studies of vertically graded GaMnAs layers, which provide direct evidence that vertical grading of Mn concentration has been successfully achieved in our GaMnAs samples. Our measurements also indicate that these graded samples exhibit magnetic “hardening” near the surface. - Highlights: • Controlled vertical grading of the magnetization ferromagnetic semiconductors represents a significant step toward optimizing its magnetic properties for device applications. • Quantitative control of such grading is difficult due to various competing effects, such as Mn diffusion, self-annealing, and diffusion of charge carriers. • We show (via SQUID and Polarized Neutron Scattering) that vertical magnetization gradients in GaMnAs layers can be readily achieved by appropriate MBE growth strategies. • Our measurements also indicate that these graded samples exhibit magnetic “hardening” near the surface.

  3. Studies on Spinel LiMn2O4 Cathode Material Synthesized from Different Mn Sources

    Institute of Scientific and Technical Information of China (English)

    唐致远; 冯季军; 彭亚宁

    2004-01-01

    The spinel LiMn2O4 cathode material was synthesized with the solid-state reaction method. Four manganese compounds including electrolytic manganese dioxide (EMD), MnCO3, Mn3O4 and nano-EMD were used as Mn sources while LiOH·H2O was used as the uniform Li source. The crystal structure characteristics of these samples produced were investigated by means of XRD, SEM, particle size distribution analysis and specific surface area testing. Their electrochemical properties were also studied by comparing their specific capacity, charge and discharge efficiency and cycle performance.

  4. Biota - 2011 Vegetation Inventory - Marsh Lake, MN

    Data.gov (United States)

    Army Corps of Engineers, Department of the Army, Department of Defense — 2011 Vegetation Classification for Marsh Lake, MN Vegetation Project Report, OMBIL Environmental Stewardship - Level 1 Inventory. Marsh Lake is located on the...

  5. Magnetic fields of HgMn stars

    DEFF Research Database (Denmark)

    Hubrig, S.; Gonzalez, J. F.; Ilyin, I.

    2012-01-01

    Context. The frequent presence of weak magnetic fields on the surface of spotted late-B stars with HgMn peculiarity in binary systems has been controversial during the two last decades. Recent studies of magnetic fields in these stars using the least-squares deconvolution (LSD) technique have...... by applying the moment technique on spectral lines of inhomogeneously distributed elements separately. Furthermore, we present new determinations of the mean longitudinal magnetic field for the HgMn star HD 65949 and the hotter analog of HgMn stars, the PGa star HD 19400, using FORS 2 installed at the VLT. We...... also give new measurements of the eclipsing system ARAur with a primary star of HgMn peculiarity, which were obtained with the SOFIN spectropolarimeter installed at the Nordic Optical Telescope. Methods. We downloaded from the European Southern Observatory (ESO) archive the publically available HARPS...

  6. Spin polarization effect for Mn2 molecule

    Institute of Scientific and Technical Information of China (English)

    Yan Shi-Ying; Xu Guo-Liang

    2007-01-01

    The density functional theory method (DFT) (b3p86) of Gaussian 03 has been used to optimize the structure of the Mn2 molecule.The result shows that the ground state of the Mn2 molecule is an 11-multiple state,indicating a spin polarization effect in the Mn2 molecule,a transition metal element molecule.Meanwhile,we have not found any spin pollution because the wavefunction of the ground state does not mingle with wavefunctions of higher-energy states.So the ground state for Mn2 molecule being of an 11-multiple state is the indicative of spin polarization effect of the Mn2 molecule among those in the transition metal elements:that is,there are 10 parallel spin electrons in a Mn2 molecule.The number of non-conjugated electrons is the greatest.These electrons occupy different spacious orbitals so that the energy of the Mn2 molecule is minimized.It can be concluded that the effect of parallel spin in the Mn2 molecule is larger than the effect of the conjugated molecule,which is obviously related to the effect of electron d delocalization.In addition,the Murrell-Sorbie potential functions with the parameters for the ground state and other states of the Mn2 molecule are derived.The dissociation energy De for the ground state of the Mn2 molecule is 1.4477eV,equilibrium bond length Re is 0.2506 nm,vibration frequency ωe is 211.51 cm-1.Its force constants,f2,f3,and f4 are 0.7240 aJ·nm-2,-3.35574 aJ·nm-3,11.4813 aJ·nm-4 respectively. The other spectroscopic data for the ground state of the Mn2 molecule ωeχe,Be,αe are 1.5301 cm-1,0.0978 cm-1,7.7825×10-4 cm-1 respectively.

  7. Knowledge Communication Through Visualizations in Project Management Documents

    DEFF Research Database (Denmark)

    Kampf, Constance

    in Internet based communication.  To examine online trust from a knowledge communication perspective, this paper looks at the I35W bridge reconstruction project in Minneapolis through web-based communication by the Minnesota Department of Transportation (MnDOT) about the project. The MnDOT bridge...... reconstruction website will be examined using a combination of 1). Nonaka et al's notion of knowledge assets, 2). Weick's notion of sensemaking, and 3). Kress and Van Leeuwan's notions of multimodal discourse.  These concepts are combined to examine the project website as a site for knowledge communication...... between MnDOT and the Twin Cities community about the bridge reconstruction project.  Results lead to an understanding of the knowledge communication processes operationg via the project website as a form of share experience....

  8. Single-molecule magnet behavior in heterometallic M(II)-Mn(III)(2)-M(II) tetramers (M(II) = Cu, Ni) containing Mn(III) salen-type dinuclear core.

    Science.gov (United States)

    Kachi-Terajima, Chihiro; Miyasaka, Hitoshi; Saitoh, Ayumi; Shirakawa, Naoki; Yamashita, Masahiro; Clérac, Rodolphe

    2007-07-23

    The linear-type heterometallic tetramers, [Mn(III)(2)(5-MeOsaltmen)(2)M(II)(2)(L)(2)](CF(3)SO(3))(2) x 2H(2)O (MII = Cu, 1a; Ni, 2a), where 5-MeOsaltmen(2-) = N,N'-(1,1,2,2-tetramethylethylene) bis(5-methoxysalicylideneiminate), and H(2)L = 3-{2-[(2-hydroxy-benzylidene)-amino]-2-methyl-propylimino}-butan-2-one oxime, have been synthesized and characterized from structural and magnetic points of view. These two compounds are isostructural and crystallize in the same monoclinic P2(1)/n space group. The structure has a [M(II)-NO-Mn(III)-(O)(2)-Mn(III)-ON-M(II)] skeleton, where -NO- is a linking oximato group derived from the non-symmetrical Schiff-base complex [M(II)(L)] and -(O)(2)- is a biphenolato bridge in the out-of-plane [Mn(2)(5-MeOsaltmen)(2)](2+) dimer. The solvent-free compounds, 1b and 2b, have also been prepared by drying of the parent compounds, 1a and 2a, respectively, at 100 degrees C under dried nitrogen. After this treatment, the crystallinity is preserved, and 1b and 2b crystallize in a monoclinic P2(1)/c space group without significant changes in their structures in comparison to 1a and 2a. Magnetic measurements on 1a and 1b revealed antiferromagnetic Mn(III)---Cu(II) interactions via the oximato group and weak ferromagnetic Mn(III)---Mn(III) interactions via the biphenolato bridge leading to an S(T) = 3 ground state. On the other hand, the diamagnetic nature of the square planar Ni(II) center generates an S(T) = 4 ground state for 2a and 2b. At low temperature, these solvated (a) and desolvated (b) compounds display single-molecule magnet behavior modulated by their spin ground state.

  9. High Mn austenitic stainless steel

    Science.gov (United States)

    Yamamoto, Yukinori [Oak Ridge, TN; Santella, Michael L [Knoxville, TN; Brady, Michael P [Oak Ridge, TN; Maziasz, Philip J [Oak Ridge, TN; Liu, Chain-tsuan [Knoxville, TN

    2010-07-13

    An austenitic stainless steel alloy includes, in weight percent: >4 to 15 Mn; 8 to 15 Ni; 14 to 16 Cr; 2.4 to 3 Al; 0.4 to 1 total of at least one of Nb and Ta; 0.05 to 0.2 C; 0.01 to 0.02 B; no more than 0.3 of combined Ti+V; up to 3 Mo; up to 3 Co; up to 1W; up to 3 Cu; up to 1 Si; up to 0.05 P; up to 1 total of at least one of Y, La, Ce, Hf, and Zr; less than 0.05 N; and base Fe, wherein the weight percent Fe is greater than the weight percent Ni, and wherein the alloy forms an external continuous scale including alumina, nanometer scale sized particles distributed throughout the microstructure, the particles including at least one of NbC and TaC, and a stable essentially single phase FCC austenitic matrix microstructure that is essentially delta-ferrite-free and essentially BCC-phase-free.

  10. Correlation of Mn charge state with the electrical resistivity of Mn doped indium tin oxide thin films

    KAUST Repository

    Kumar, S. R. Sarath

    2010-09-15

    Correlation of charge state of Mn with the increase in resistivity with Mn concentration is demonstrated in Mn-doped indium tin oxide films. Bonding analysis shows that Mn 2p3/2 core level can be deconvoluted into three components corresponding to Mn2+ and Mn4+ with binding energies 640.8 eV and 642.7 eV, respectively, and a Mn2+ satellite at ∼5.4 eV away from the Mn2+ peak. The presence of the satellite peak unambiguously proves that Mn exists in the +2 charge state. The ratio of concentration of Mn2+ to Mn4+ of ∼4:1 suggests that charge compensation occurs in the n-type films causing the resistivity increase.

  11. Tetramerization reinforces the dimer interface of MnSOD.

    Directory of Open Access Journals (Sweden)

    Yuewei Sheng

    Full Text Available Two yeast manganese superoxide dismutases (MnSOD, one from Saccharomyces cerevisiae mitochondria (ScMnSOD and the other from Candida albicans cytosol (CaMnSODc, have most biochemical and biophysical properties in common, yet ScMnSOD is a tetramer and CaMnSODc is a dimer or "loose tetramer" in solution. Although CaMnSODc was found to crystallize as a tetramer, there is no indication from the solution properties that the functionality of CaMnSODc in vivo depends upon the formation of the tetrameric structure. To elucidate further the functional significance of MnSOD quaternary structure, wild-type and mutant forms of ScMnSOD (K182R, A183P mutant and CaMnSODc (K184R, L185P mutant with the substitutions at dimer interfaces were analyzed with respect to their oligomeric states and resistance to pH, heat, and denaturant. Dimeric CaMnSODc was found to be significantly more subject to thermal or denaturant-induced unfolding than tetrameric ScMnSOD. The residue substitutions at dimer interfaces caused dimeric CaMnSODc but not tetrameric ScMnSOD to dissociate into monomers. We conclude that the tetrameric assembly strongly reinforces the dimer interface, which is critical for MnSOD activity.

  12. Synthesis and characterization of Mn intercalated Mg-Al hydrotalcite.

    Science.gov (United States)

    Yang, Chengxue; Liao, Libing; Lv, Guocheng; Wu, Limei; Mei, Lefu; Li, Zhaohui

    2016-10-01

    Mn intercalated hydrotalcite was prepared using a reconstruction method. And Mn intercalation was confirmed by XRD, FTIR, and thermal analyses. The different valences of Mn were present as determined by XPS. Calcination slightly promoted the isomorphic replacement of Mn(2+) and Mn(3+) for Mg(2+) and Al(3+), especially the replacement of Mn(2+) for Mg(2+) and Al(3+), and to some extent, reduced Mn intercalation. Ultrasonic treatment significantly increased Mn intercalation in permanganate form (Mn(7+)), and promoted the replacement of Mn(2+) for Mg(2+) and Al(3+). XRF analysis showed that ultrasonic treatment decreased the unbalanced layer charge of Mn intercalated hydrotalcite, while prolonged calcination increased it. These results may provide guidance on the preparation and application of Mn intercalated hydrotalcite. Extended calcination time and ultrasonic vibration increased the interlayer spacing of hydrotalcite, as a result of reduction in layer charge. As the layer charge was not completely balanced after Mn intercalation, a certain amount of CO3(2-) was re-adsorbed into the interlayer space. Mn-hydrotalcites with different layer charges, different contents of Mn with varying valences are expected to have different performances in the process of adsorption, degradation, and catalysis.

  13. New routes to polymetallic clusters: fluoride-based tri-, deca-, and hexaicosametallic MnIII clusters and their magnetic properties.

    Science.gov (United States)

    Jones, Leigh F; Rajaraman, Gopalan; Brockman, Jonathon; Murugesu, Muralee; Sanudo, E Carolina; Raftery, Jim; Teat, Simon J; Wernsdorfer, Wolfgang; Christou, George; Brechin, Euan K; Collison, David

    2004-10-11

    The syntheses, structures and magnetic properties of three new MnIII clusters, [Mn26O17(OH)8(OMe)4F10(bta)22(MeOH)14(H2O)2] (1), [Mn(0O6(OH)2(bta)8(py)8F8] (2) and [NHEt3]2[Mn3O(bta)6F3] (3), are reported (bta=anion of benzotriazole), thereby demonstrating the utility of MnF3 as a new synthon in Mn cluster chemistry. The "melt" reaction (100 degrees C) between MnF(3) and benzotriazole (btaH, C6H5N3) under an inert atmosphere, followed by dissolution in MeOH produces the cluster [Mn26O17(OH)8(OMe)4F10(bta)22(MeOH)14(H2O)2] (1) after two weeks. Complex 1 crystallizes in the triclinic space group P1, and consists of a complicated array of metal tetrahedra linked by mu3-O2- ions, mu3- and mu2-OH- ions, mu2-MeO- ions and mu2-bta- ligands. The "simpler" reaction between MnF3 and btaH in boiling MeOH (50 degrees C) also produces complex 1. If this reaction is repeated in the presence of pyridine, the decametallic complex [Mn10O6(OH)2(bta)8(py)8F8] (2) is produced. Complex 2 crystallizes in the triclinic space group P1 and consists of a "supertetrahedral" [Mn(III)10] core bridged by six mu3-O2- ions, two mu3-OH- ions, four mu2-F- ions and eight mu2-bta- ions. The replacement of pyridine by triethylamine in the same reaction scheme produces the trimetallic species [NHEt3]2[Mn3O(bta)6F3] (3). Complex 3 crystallises in the monoclinic space group P2(1)/c and has a structure analogous to that of the basic metal carboxylates of general formula [M3O(RCO2)6L3]0/+, which consists of an oxo-centred metal triangle with mu2-bta- ligands bridging each edge of the triangle and the fluoride ions acting as the terminal ligands. DC magnetic susceptibility measurements in the 300-1.8 K and 0.1-7 T ranges were investigated for all three complexes. For each, the value of chi(M)T decreases with decreasing temperatures; this indicates the presence of dominant antiferromagnetic exchange interactions in 1-3. For complex 1, the low-temperature value of chi(M)T is 10 cm(3) K mol(-1) and fitting of

  14. A one-dimensional double-chain coordination polymer: [Mn(C12H13NO6S)(C10H8N2)]n.

    Science.gov (United States)

    Liang, Fu-Pei; Chen, Man-Sheng; Hu, Rui-Xiang; Chen, Zi-Lu

    2004-06-01

    In the title compound, poly[[(2,2'-bipyridine-kappa(2)N,N')manganese(II)]-micro(3)-N-tosyl-L-glutamato-kappa(4)O,O':O":O"'], [Mn(tsgluo)(bipy)](n), where tsgluo is N-tosyl-L-glutamate (C(12)H(13)NO(6)S) and bipy is 2,2'-bipyridine (C(10)H(8)N(2)), the Mn atoms are octahedrally coordinated by two N atoms of one bipy ligand and by four O atoms of three tsgluo(2-) anions. The gamma-carboxyl group coordinates to the Mn(II) atom in a chelating mode, while the alpha-carboxyl group coordinates in a bidentate-bridging mode. The complex displays a one-dimensional double-chain structure.

  15. Composition dependence on the martensitic structures of the Mn-rich NiMnGa alloys

    Energy Technology Data Exchange (ETDEWEB)

    Jiang Chengbao; Muhammad, Yousaf; Deng Lifeng; Wu Wei; Xu Huibin

    2004-05-17

    The Mn-rich Ni{sub 50}Mn{sub 25+x}Ga{sub 25-x} (x=0-5) alloys were developed to investigate the structural transitions and magnetic properties. Structural transitions from austenite to 5M, 7M, and non-modulated martensite were observed with the increase of Mn content. The lattice parameter a elongates, as where b and c contract, and the unit cell volume reduces with increasing Mn content. The martensitic transformation start temperatures M{sub s} increase monotonically from 10.7 deg. C for x=2 to 102.7 deg. C for x=5. The saturation magnetization was measured at 5 K, where all the samples exhibit a martensitic structure. The average magnetic moments per Mn atom vary from 4.38 {mu}{sub B} to 2.93 {mu}{sub B} for x=0 to x=5. The negative effect of excess Mn atoms changes from -3.00 {mu}{sub B} for x=2 to -7.25 {mu}{sub B} for x=5. The excess Mn atoms modify the electronic structures of the unsubstituted Mn atoms, resulting in the sharp decrease of the magnetic moments of the unsubstituted Mn atoms with increasing Mn content. Structural incommensurability was observed with 7M for powder and non-modulated for bulk samper in a specific range of compositions and proved to be reversible when performing martensitic transformation. The 7M and non-modulated martensites Ni{sub 50}Mn{sub 30}Ga{sub 20} possess similar saturation magnetizations and Curie temperatures. The non-modulated martensite was estimated to have a lower free energy than 7M, and should be more stable for a reverse martensitic transformation, leading to a higher austenite start temperature A{sub s}, which is consistent with the experimental result.

  16. Influence of calcium(II) and chloride on the oxidative reactivity of a manganese(II) complex of a cross-bridged cyclen ligand.

    Science.gov (United States)

    Zhang, Zhan; Coats, Katherine L; Chen, Zhuqi; Hubin, Timothy J; Yin, Guochuan

    2014-11-17

    Available data from different laboratories have confirmed that both Ca(2+) and Cl(-) are crucial for water oxidation in Photosystem II. However, their roles are still elusive. Using a manganese(II) complex having a cross-bridged cyclen ligand as a model, the influence of Ca(2+) on the oxidative reactivity of the manganese(II) complex and its corresponding manganese(IV) analogue were investigated. It has been found that adding Ca(2+) can significantly improve the oxygenation efficiency of the manganese(II) complex in sulfide oxidation and further accelerate the oxidation of sulfoxide to sulfone. Similar improvements have also been observed for Mg(2+), Sr(2+), and Ba(2+). A new monomeric manganese(IV) complex having two cis-hydroxide ligands has also been isolated through oxidation of the corresponding manganese(II) complex with H2O2 in the presence of NH4PF6. This rare cis-dihydroxomanganese(IV) species has been well characterized by X-ray crystallography, electrochemistry, electron paramagnetic resonance, and UV-vis spectroscopy. Notably, using the manganese(IV) complex as a catalyst demonstrates higher activity than the corresponding manganese(II) complex, and adding Ca(2+) further improves its catalytic efficiency. However, adding Cl(-) decreases its catalytic activity. In electrochemical studies of manganese(IV) complexes with no chloride ligand present, adding Ca(2+) positively shifted the redox potential of the Mn(IV)/Mn(III) couple but negatively shifted its Mn(V)/Mn(IV) couple. In the manganese(II) complex having a chloride ligand, adding Ca(2+) shifted both the Mn(IV)/Mn(III) and Mn(V)/Mn(IV) couples in the negative direction. The revealed oxidative reactivity and redox properties of the manganese species affected by Ca(2+) and Cl(-) may provide new clues to understanding their roles in the water oxidation process of Photosystem II.

  17. A hierarchical nanostructure consisting of amorphous MnO 2, Mn 3O 4 nanocrystallites, and single-crystalline MnOOH nanowires for supercapacitors

    Science.gov (United States)

    Hu, Chi-Chang; Hung, Ching-Yun; Chang, Kuo-Hsin; Yang, Yi-Lin

    In this communication, a porous hierarchical nanostructure consisting of amorphous MnO 2 (a-MnO 2), Mn 3O 4 nanocrystals, and single-crystalline MnOOH nanowires is designed for the supercapacitor application, which is prepared by a simple two-step electrochemical deposition process. Because of the gradual co-transformation of Mn 3O 4 nanocrystals and a-MnO 2 nanorods into an amorphous manganese oxide, the cycle stability of a-MnO 2 is obviously enhanced by adding Mn 3O 4. This unique ternary oxide nanocomposite with 100-cycle CV activation exhibits excellent capacitive performances, i.e., excellent reversibility, high specific capacitances (470 F g -1 in CaCl 2), high power property, and outstanding cycle stability. The highly porous microstructures of this composite before and after the 10,000-cycle CV test are examined by means of scanning electron microscopy (SEM) and transmission electron microscopy (TEM).

  18. A Tale of Five Bridges; the use of GNSS for Monitoring the Deflections of Bridges

    Science.gov (United States)

    Roberts, Gethin Wyn; Brown, Christopher J.; Tang, Xu; Meng, Xiaolin; Ogundipe, Oluropo

    2014-11-01

    The first Bridge Monitoring surveying was carried out in 1996 by the authors, through attaching Ashtech ZXII GPS receivers onto the Humber Bridge' parapet, and gathering and further analysing the resulting 1 Hz RTK GPS data. Various surveys have subsequently been conducted on the Humber Bridge, the Millennium Bridge, the Forth Road Bridge, the Severn Suspension Bridge and the Avonmouth Viaduct. These were all carried out using survey grade carrier phase/pseudorange GPS and later GNSS receivers. These receivers were primarily dual frequency receivers, but the work has also investigated the use of single frequency receivers, gathering data at 1 Hz, 10 Hz, 20 Hz and even 100 Hz. Various aspects of the research conducted are reported here, as well as the historical approach. Conclusions are shown in the paper, as well as lessons learnt during the development of this work. The results are compared to various models that exist of the bridges' movements, and compare well. The results also illustrate that calculating the frequencies of the movements, as well as looking at the magnitudes of the movements, is an important aspect of this work. It is also shown that in instances where the magnitudes of the movements of the bridge under investigation are small, it is still possible to derive very accurate frequencies of the movements, in comparison to the existing models.

  19. Role of multiprotein bridging factor 1 in archaea: bridging the domains?

    NARCIS (Netherlands)

    Koning, de B.; Blombach, F.; Wu Hao,; Brouns, S.J.J.; Oost, van der J.

    2009-01-01

    MBF1 (multiprotein bridging factor 1) is a highly conserved protein in archaea and eukaryotes. It was originally identified as a mediator of the eukaryotic transcription regulator BmFTZ-F1 (Bombyx mori regulator of fushi tarazu). MBF1 was demonstrated to enhance transcription by forming a bridge bet

  20. Crystal Structure and Characterization of a New Mixed-valence Manganese(Ⅲ/Ⅳ) Complex: [Mn2(cyclen)2(μ-O)2](ClO4)3-4H2O

    Institute of Scientific and Technical Information of China (English)

    任颜卫; 李珺; 张逢星; 张金花; 郭惠

    2005-01-01

    The mixed-valence manganese(Ⅲ/Ⅳ) complex [Mn2(cyclen)2(μ-O)2](ClO4)3-4H2O (1) (cyclen=1,4,7,10-tetraazacyclododecan) with chemical formula C16H48Cl3Mn2N8O18 has been synthesized and characterized by single crystal X-ray diffraction analysis, elemental analysis, IR and electronic spectra. The results showed that the manganese(Ⅲ/Ⅳ) ions were six-coordinated by four nitrogen atoms from cyclen and two oxygen atoms from the oxygen bridge, forming a distorted octahedron geometry. There were two very strong peaks in the range of 400-700 nm in electronic spectrum, which was similar to Mn catalase and Mn ribonucleotide reductase extracted from organisms.Electrochemical study indicated that the complex underwent a quasi-reversible one-electron reduction and oxidation at E1/2=0.827 V in acetonitrile.

  1. New quantum tunneling steps in Mn11Cr/Mn12 mixed crystal

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    Magnetic properties of Mn11Cr and Mn12 mixed crystal at low temperature are studied.A new set of quantum tunneling steps discovered in magnetization curves suggests that there may exist another kind of single molecular magnet in this mixed crystal.

  2. Natural vibration dynamics of Rainbow Bridge, Utah

    Science.gov (United States)

    Moore, J. R.; Thorne, M. S.; Wood, J. R.; Doyle, S.; Stanfield, E.; White, B.

    2015-12-01

    We measured resonant frequencies of Rainbow Bridge, Utah, one of the world's longest rock spans, during a field experiment recording ambient vibration data. Measurements were generated over 20 hours on March 23-24, 2015 using two broadband three-component seismometers placed on the bridge, and compared to concurrent data from nearby reference stations 20 and 220 m distant. We identified seven distinct modes of vibration for Rainbow Bridge between 1 and 6 Hz. Data for each resonant frequency was then analyzed to determine the frequency-dependent polarization vector in an attempt to clarify mode shapes; e.g. the fundamental mode represents out-of-plane horizontal flexure. We compared experimental data to results of 3D numerical modal analysis, using a new photogrammetric model of Rainbow Bridge generated in this study imported into COMSOL Multiphysics. Results compare well with measured data for seven of the first eight modeled modes, matching vibrational frequencies and polarization orientations generally within 10%. Only predicted mode 6 was not explicitly apparent in our experimental data. Large site-to-reference spectral ratios resolved from experimental data indicate high amplification on the bridge as compared to nearby bedrock.

  3. A probabilistic bridge safety evaluation against floods.

    Science.gov (United States)

    Liao, Kuo-Wei; Muto, Yasunori; Chen, Wei-Lun; Wu, Bang-Ho

    2016-01-01

    To further capture the influences of uncertain factors on river bridge safety evaluation, a probabilistic approach is adopted. Because this is a systematic and nonlinear problem, MPP-based reliability analyses are not suitable. A sampling approach such as a Monte Carlo simulation (MCS) or importance sampling is often adopted. To enhance the efficiency of the sampling approach, this study utilizes Bayesian least squares support vector machines to construct a response surface followed by an MCS, providing a more precise safety index. Although there are several factors impacting the flood-resistant reliability of a bridge, previous experiences and studies show that the reliability of the bridge itself plays a key role. Thus, the goal of this study is to analyze the system reliability of a selected bridge that includes five limit states. The random variables considered here include the water surface elevation, water velocity, local scour depth, soil property and wind load. Because the first three variables are deeply affected by river hydraulics, a probabilistic HEC-RAS-based simulation is performed to capture the uncertainties in those random variables. The accuracy and variation of our solutions are confirmed by a direct MCS to ensure the applicability of the proposed approach. The results of a numerical example indicate that the proposed approach can efficiently provide an accurate bridge safety evaluation and maintain satisfactory variation.

  4. Using rotating liquid bridges as accelerometers

    Energy Technology Data Exchange (ETDEWEB)

    Montanero, J.M. [Universidad de Extremadura, Badajoz (Spain). Dept. de Electronica e Ingenieria Electromecanica; Cabezas, G.; Acero, J.; Zayas, F.

    1999-07-01

    Liquid bridges have recently been proposed as fluid accelerometers that could be used to measure very small inertial forces under microgravity conditions [Meseguer et al., microgravity sci. technol. IX/2 (1996)]. The essential idea is to infer the values of such inertial forces from the liquid bridge interface contour, whose shape obviously depends on the values of such forces (apart from the bridge volume and the geometry of the supporting disks). Following a similar procedure, in this paper we explore the use of rotating axisymmetric liquid bridges to measure the residual axial gravity and the rotation rate of the liquid bridge regarded as a solid body. In light off the difficulties involved in performing experiments on Earth, the role of empirical data is played by an accurate numerical solution of the Young-Laplace equation. The values of both the axial gravity and angular speed are obtained by fitting the approximate analytical expressions derived in this paper to the numerical solution of the Young-Laplace equation. The comparison between the predicted and actual values of the variables of interest shows a satisfactory agreement, supporting the suitability of the procedure. (orig.)

  5. Influence of Mn Content and Hot Deformation on Transformation Behavior of C-Mn Steels

    Institute of Scientific and Technical Information of China (English)

    LI Long; DING Hua; DU Lin-xiu; WEN Jing-lin; SONG Hong-mei; ZHANG Pi-jun

    2008-01-01

    The hot deformation behaviors and the microstructural evolution of plain C-Mn steels with similar contents of C and Si but different contents of Mn have been investigated by compressive processing using Gleeble-1500 mechanical simulator. Influence of Mn and hot deformation on continuous cooling transformation of steels has been studied. The experimental results showed that deformation in austenite region accelerated transformation process, and the extent is dependent on the hot deformation and cooling conditions. The hot deformation would promote transformation process, but the increase of transformation temperature is dependent on Mn contents. The results have also shown that the effect of deformation on ferrite transformation becomes more obvious with the increase of Mn content at relatively low cooling rate.

  6. Mn(II,III) oxidation and MnO2 mineralization by an expressed bacterial multicopper oxidase

    Science.gov (United States)

    Butterfield, Cristina N.; Soldatova, Alexandra V.; Lee, Sung-Woo; Spiro, Thomas G.; Tebo, Bradley M.

    2013-07-01

    Reactive Mn(IV) oxide minerals are ubiquitous in the environment and control the bioavailability and distribution of many toxic and essential elements and organic compounds. Their formation is thought to be dependent on microbial enzymes, because spontaneous Mn(II) to Mn(IV) oxidation is slow. Several species of marine Bacillus spores oxidize Mn(II) on their exosporium, the outermost layer of the spore, encrusting them with Mn(IV) oxides. Molecular studies have identified the mnx (Mn oxidation) genes, including mnxG, encoding a putative multicopper oxidase (MCO), as responsible for this two-electron oxidation, a surprising finding because MCOs only catalyze single-electron transfer reactions. Characterization of the enzymatic mechanism has been hindered by the lack of purified protein. By purifying active protein from the mnxDEFG expression construct, we found that the resulting enzyme is a blue (absorption maximum 590 nm) complex containing MnxE, MnxF, and MnxG proteins. Further, by analyzing the Mn(II)- and (III)-oxidizing activity in the presence of a Mn(III) chelator, pyrophosphate, we found that the complex facilitates both electron transfers from Mn(II) to Mn(III) and from Mn(III) to Mn(IV). X-ray absorption spectroscopy of the Mn mineral product confirmed its similarity to Mn(IV) oxides generated by whole spores. Our results demonstrate that Mn oxidation from soluble Mn(II) to Mn(IV) oxides is a two-step reaction catalyzed by an MCO-containing complex. With the purification of active Mn oxidase, we will be able to uncover its mechanism, broadening our understanding of Mn mineral formation and the bioinorganic capabilities of MCOs.

  7. Heavy Vehicles on Minor Highway Bridges

    DEFF Research Database (Denmark)

    Kirkegaard, Poul Henning; Nielsen, Søren R. K.; Enevoldsen, I.

    of heavier trucks moving at larger speeds, and partly because the authorities want to permit transportation of special heavy goods at a larger part of the road net. These needs will in many cases cause the strengthening of the bridges becomes necessary. In order to keep the expenses of such strengthening...... projects at a minimum, it is necessary to perform accurate estimates of the dynamic amplification factor (defined as the dynamic load effect divided by the static load effect from the vehicles), so this quantity is neither over- nor underestimated. The principal aims of the present paper are to establish...... the numerical models for the mathematical models of the vehicles and the bridge from which the load amplification factors can be estimated assuming that the dynamic parameters of the vehicles and the modal parameters of the bridge are known....

  8. Ergonomic aspects of automation in navigation bridges.

    Science.gov (United States)

    Lazet, A; Walraven, P L

    1971-06-01

    New ergonomic questions arise from the tendency toward increasing automation in maritime operations. Direct control of engines and rudder from the bridge promises improved ship control, provided that the operator can really exploit the technical improvements. To make such direct control most efficient, good ergonomic design is essential. A series of designs of navigation bridges is used to illustrate typical problems and situations. The building of full scale mock-ups of complete bridges is essential in order to handle the design as an integrated problem and to simulate the work situation. Such static mock-ups have been shown to be extremely useful in the discussion between builder, future user and adviser. An extension to dynamic simulation is necessary in order to study the actual work conditions in a new design.

  9. Influence of Icing on Bridge Cable Aerodynamics

    DEFF Research Database (Denmark)

    Koss, Holger; Frej Henningsen, Jesper; Olsen, Idar

    2013-01-01

    In recent years the relevance of ice accretion for wind-induced vibration of structural bridge cables has been recognised and became a subject of research in bridge engineering. Full-scale monitoring and observation indicate that light precipitation at moderate low temperatures between zero and -5......°C may lead to large amplitude vibrations of bridge cables under wind action. For the prediction of aerodynamic instability quasi-steady models have been developed estimating the cable response magnitude based on structural properties and aerodynamic force coefficients for drag, lift and torsion....... The determination of these force coefficients require a proper simulation of the ice layer occurring under the specific climatic conditions, favouring real ice accretion over simplified artificial reproduction. The work presented in this paper was performed to study the influence of ice accretion on the aerodynamic...

  10. Stability of dynamic response of suspension bridges

    Science.gov (United States)

    Capsoni, Antonio; Ardito, Raffaele; Guerrieri, Andrea

    2017-04-01

    The potential occurrence of internal parametric resonance phenomena has been recently indicated as a potential contributory cause of the appearance of critical dynamic states in long-span suspension bridges. At the same time, suspension bridges, in view of their flexibility, are prone to aeroelastic response, such as vortex shedding, torsional divergence and flutter. In this paper, a non-linear dynamic model of a suspension bridge is devised, with the purpose of providing a first attempt toward a unified framework for the study of aeroelastic and internal resonance instabilities. Inspired by the pioneering work of Herrmann and Hauger, the analyses have been based on a linearized formulation that is able to represent the main structural non-linear effects and the coupling given by aerodynamic forces. The results confirm that the interaction between aeroelastic effects and non-linear internal resonance leads to unstable conditions for wind speeds which can be lower than the critical threshold for standard aeroelastic predictions.

  11. Building bridges within the bacterial chromosome.

    Science.gov (United States)

    Song, Dan; Loparo, Joseph J

    2015-03-01

    All organisms must dramatically compact their genomes to accommodate DNA within the cell. Bacteria use a set of DNA-binding proteins with low sequence specificity called nucleoid-associated proteins (NAPs) to assist in chromosome condensation and organization. By bending or bridging DNA, NAPs also facilitate chromosome segregation and regulate gene expression. Over the past decade, emerging single-molecule and chromosome conformation capture techniques have investigated the molecular mechanisms by which NAPs remodel and organize the bacterial chromosome. In this review we describe how such approaches reveal the biochemical mechanisms of three NAPs that are believed to facilitate DNA bridging: histone-like nucleoid structuring protein (H-NS), ParB, and structural maintenance of chromosomes (SMC). These three proteins form qualitatively different DNA bridges, leading to varied effects on transcription and chromosome segregation.

  12. Fast Hough transform for automatic bridge extraction

    Science.gov (United States)

    Hao, Qiwei; Chen, Xiaomei; Ni, Guoqiang; Zhang, Huaili

    2008-03-01

    In this paper, a new method to recognize bridge in the complicated background is presented. The algorithm takes full advantages of the characteristics of the bridge image. Firstly, the image is preprocessed and the object edges are extracted. Then according to the limitations of traditional Hough transform (HT), the extraction method of the image line segment characteristic of HT is improved, which eliminates spurious peaks on the basis of global and local thresholds, discriminates the position relation between two straight line segments, and merges segments with near endpoints, etc. Experiments show that this algorithm is more precise and efficient than traditional HT, moreover it can provide a complete description of the bridge in a complicated background.

  13. MINERAL BRIDGES OF NACRE AND ITS EFFECTS

    Institute of Scientific and Technical Information of China (English)

    宋凡; 白以龙

    2001-01-01

    Nacre, or mother-of-pearl, is a kind of composites of aragonite platelets sandwiched between organic materials. Its excellent mechanical properties are thought to stem from the microarchitecture that is traditionally described as a "brick and mortar" arrangement. In this paper, a new microstructure, referred to as mineral bridge in the biomineralization, is directly observed in the organic matrix layers (mortar) of nacre. This is an indication that the organic matrix layer of nacre should be treated as a three-dimensional interface and the microarchitecture of nacre ought to be considered as a "brick-bridge-mortar" structure rather than the traditional one. Experiments and analyses show that the mineral bridges not only improve the mechanical properties of the organic matrix layers but also play an important role in the pattern of the crack extension in nacre.

  14. Composition-structure-property-performance relationship inMn-substituted LiMn2O4

    Energy Technology Data Exchange (ETDEWEB)

    Horne, Craig R.; Richardson, Thomas J.; Gee, B.; Tucker, Mike; Grush, Melissa M.; Bergmann, Uwe; Striebel, Kathryn A.; Cramer, StephenP.; Reimer, Jeffrey A.; Cairns, Elton J.

    2001-03-09

    The spinel LiMn{sub 2}O{sub 4} has been extensively studied as a positive electrode active material in lithium rechargeable batteries. Partial substitution of Mn by another metal has also been the subject of recent study in an effort to improve the cycling performance. In general, the literature has shown that Mn substitution results in improved cycling stability at the expense of capacity (1,2). Resistance to the formation of tetragonal phase upon lithiation of the starting spinel (via a higher nominal Mn oxidation state in the substituted spinel) has been suggested as a mechanism for the improved performance. The degree of substitution is an important factor to optimize in order to minimize capacity loss and costs. The spectroscopic investigations on LiMn{sub 2}O{sub 4} described in the previous paper (LixMn2O4) confirmed that the cooperative Jahn-Teller effect (CJTE) from the [Mn{sup 3+}O{sub 6}] octahedra is the mechanism for the cubic to tetragonal phase transformation. The driving force for the CJTE is based upon the electronic structure, therefore changes in electronic structure should lead to changes in the phase behavior. The fact that the LiMn{sub 1.5}Ni{sub 0.5}O{sub 4} does not form tetragonal phase upon discharging (FUJI3, MUCK?), unlike the 100% Mn{sup 4+} spinel Li{sub 4}Mn{sub 5}O{sub 12} (THAC5), led to the hypothesis that an increased degree of covalency as a source for the behavior. An increased covalence would remove the driving force for the transformation, the increased electronic stability achieved in tetragonally-distorted [Mn{sup 3+}O{sub 6}] octahedra, due to a change in electron density and widening of the Mn 3d bands. The STH field is dependent upon the amount of unpaired spin density transferred between the magnetic (transition-metal) and diamagnetic ions through an intermittent oxygen ion, attributable to overlap and electron transfer effects. Therefore, the magnitude of the STH coupling constant reflects the degree of covalency (GESC

  15. Operational modal analysis of road-rail bridge

    OpenAIRE

    Cardoso M.; Sampaio R. A. C.; de Souza R. M.; Silva E.

    2015-01-01

    In this paper, we describe an Operational Modal Analysis (OMA) of the Bridge over the Tocantins River, a composite road-rail bridge located in the city of Marabá, state of Pará, northern Brazil. The bridge is part of the Carajás Railway, which is used by VALE Company to transport iron ore from “Serra dos Carajás”, the largest mineral reserve of the planet. The bridge has a length of 2310m, being the second longest road-rail bridge in Brazil. The study focused on the bridge central span (with ...

  16. Dragon bridge - the world largest dragon-shaped (ARCH steel bridge as element of smart city

    Directory of Open Access Journals (Sweden)

    Chinh Luong Minh

    2016-01-01

    Full Text Available Dragon Bridge - The world’s largest dragon-shaped steel bridge, with an installation cost of $85 million USD, features 6 lanes for two separate directions, 666 meters of undulating steel in the shape of a dragon in the Ly Dynasty, the symbol of prosperity in Vietnamese culture. This unique and beautifully lit bridge, which also breathes fire and sprays water. It’s the purposeful integration of the lighting hardware articulates the dragon’s form, and the fire-breathing dragon head. This project transcends the notion of monumental bridge with dynamic colour-changing lighting, creating an iconic sculpture in the skyline that is both reverent and whimsical. The signature feature of the bridge was the massive undulating support structure resembling a dragon flying over the river. The dragon is prominent in Vietnamese culture as a symbol of power and nobility. Dragon Bridge stands out as a model of innovation. It has received worldwide attention in the design community and from the global media for its unique arch support system. Dragon Bridge serves as an example of how aesthetic quality of a design can serve cultural, economic and functional purposes. The article presents design solutions of the object and the evaluation of the technical condition before putting the facility into service.

  17. The seismic response of concrete arch bridges (with focus on the Bixby Creek bridge Carmel, California)

    Energy Technology Data Exchange (ETDEWEB)

    Hoehler, M; McCallen, D; Noble, C

    1999-06-01

    The analysis, and subsequent retrofit, of concrete arch bridges during recent years has relied heavily on the use of computational simulation. For seismic analysis in particular, computer simulation, typically utilizing linear approximations of structural behavior, has become standard practice. This report presents the results of a comprehensive study of the significance of model sophistication (i.e. linear vs. nonlinear) and pertinent modeling assumptions on the dynamic response of concrete arch bridges. The study uses the Bixby Creek Bridge, located in California, as a case study. In addition to presenting general recommendations for analysis of this class of structures, this report provides an independent evaluation of the proposed seismic retrofit for the Bixby Creek Bridge. Results from the study clearly illustrate a reduction of displacement drifts and redistribution of member forces brought on by the inclusion of material nonlinearity. The analyses demonstrate that accurate modeling of expansion joints, for the Bixby Creek Bridge in particular, is critical to achieve representative modal and transient behavior. The inclusion of near-field displacement pulses in ground motion records was shown to significantly increase demand on the relatively softer, longer period Bixby Creek Bridge arch. Stiffer, shorter period arches, however, are more likely susceptible to variable support motions arising from the canyon topography typical for this class of bridges.

  18. Extracorporeal Life Support Bridge to Ventricular Assist Device: The Double Bridge Strategy.

    Science.gov (United States)

    Marasco, Silvana F; Lo, Casey; Murphy, Deirdre; Summerhayes, Robyn; Quayle, Margaret; Zimmet, Adam; Bailey, Michael

    2016-01-01

    In patients requiring left ventricular assist device (LVAD) support, it can be difficult to ascertain suitability for long-term mechanical support with LVAD and eventual transplantation. LVAD implantation in a shocked patient is associated with increased morbidity and mortality. Interest is growing in the utilization of extracorporeal life support (ECLS) as a bridge-to-bridge support for these critically unwell patients. Here, we reviewed our experience with ECLS double bridging. We hypothesized that ECLS double bridging would stabilize end-organ dysfunction and reduce ventricular assist device (VAD) implant perioperative mortality. We conducted a retrospective review of prospectively collected data for 58 consecutive patients implanted with a continuous-flow LVAD between January 2010 and December 2013 at The Alfred Hospital, Melbourne, Victoria, Australia. Twenty-three patients required ECLS support pre-LVAD while 35 patients underwent LVAD implantation without an ECLS bridge. Preoperative morbidity in the ECLS bridge group was reflected by increased postoperative intensive care duration, blood loss, blood product use, and postoperative renal failure, but without negative impact upon survival when compared with the no ECLS group. ECLS stabilization improved end-organ function pre-VAD implant with significant improvements in hepatic and renal dysfunction. This series demonstrates that the use of ECLS bridge to VAD stabilizes end-organ dysfunction and reduces VAD implant perioperative mortality from that traditionally reported in these "crash and burn" patients.

  19. Stability of a liquid bridge under vibration

    Science.gov (United States)

    Benilov, E. S.

    2016-06-01

    We examine the stability of a vertical liquid bridge between two vertically vibrating, coaxial disks. Assuming that the vibration amplitude and period are much smaller than the mean distance between the disks and the global timescale, respectively, we employ the method of multiple scales to derive a set of asymptotic equations. The set is then used to examine the stability of a bridge of an almost cylindrical shape. It is shown that, if acting alone, gravity is a destabilizing influence, whereas vibration can weaken it or even eliminate altogether. Thus, counter-intuitively, vibration can stabilize an otherwise unstable capillary structure.

  20. A Bridge Deflection Monitoring with GPS

    Science.gov (United States)

    Figurski, M.; Gałuszkiewicz, M.; Wrona, M.

    2007-01-01

    This paper introduces results of investigation carried on by The Applied Geomatics Section in Military University of Technology. Research includes possibilities of monitoring dynamic behavior of a bridge using high rate GPS data. Whole event was executed with collaboration of The Road and Bridge Management and The Warsaw Geodesy Company. Interdisciplinary approach with this project allows authors to get reliable information about investigating constructions and their respond for true traffic loading detected by GPS receivers. Way of compute data and used software (TRACK) are also shown in this paper.

  1. Planar Hall effect bridge magnetic field sensors

    DEFF Research Database (Denmark)

    Henriksen, A.D.; Dalslet, Bjarke Thomas; Skieller, D.H.

    2010-01-01

    Until now, the planar Hall effect has been studied in samples with cross-shaped Hall geometry. We demonstrate theoretically and experimentally that the planar Hall effect can be observed for an exchange-biased ferromagnetic material in a Wheatstone bridge topology and that the sensor signal can...... be significantly enhanced by a geometric factor. For the samples in the present study, we demonstrate an enhancement of the sensor output by a factor of about 100 compared to cross-shaped sensors. The presented construction opens a new design and application area of the planar Hall effect, which we term planar...... Hall effect bridge sensors....

  2. Analysis of Biaxially Stressed Bridge Deck Plates

    DEFF Research Database (Denmark)

    Jönsson, Jeppe; Bondum, Tommi Højer

    2012-01-01

    The ultimate state analysis of bridge deck plates at the intersection zone between main girders and transverse beams is complicated by biaxial membrane stresses, which may be in compression or tension in either direction depending on the bridge configuration and the specific location. This paper...... presents a detailed investigation of the ultimate capacity of simply supported plates subjected to biaxial loads. The full interaction domain of combinations of compressive and tensile loads has been investigated including a large number of imperfections. It was found that non-standard imperfection modes...

  3. Construction Technology of Long Span Bridges

    DEFF Research Database (Denmark)

    Gimsing, Niels Jørgen

    2000-01-01

    A large variety of construction methods are used during construction of major bridges, and in many cases the final structural system must be chosen with due respect to the construction process. Today the preferred construction methods are: the free-cantilever method, the launching method and the ......A large variety of construction methods are used during construction of major bridges, and in many cases the final structural system must be chosen with due respect to the construction process. Today the preferred construction methods are: the free-cantilever method, the launching method...

  4. Ambient Vibration Test on Reinforced Concrete Bridges

    Directory of Open Access Journals (Sweden)

    Idris Nurul Shazwin

    2016-01-01

    Full Text Available An investigation was carried out to determine dynamic characteristic of reinforced concrete (RC bridges by using ambient vibration test (AVT. The ambient vibration sources on bridges may come from traffic, wind, wave motion and seismic events. AVT describes the dynamic characteristics of the bridge and ground by measuring the natural frequencies using highly sensitive seismometer sensor. This test is beneficial due to light weight equipment and smaller number of operator required, cheap and easy to be handled. It is able to give a true picture of the bridge dynamic behavior without any artificial force excitation when vibration data is recorded. A three-span reinforced concrete bridge located in Sri Medan, Batu Pahat, Johor was measured by using microtremor equipment consist of three units of 1 Hz eigenfrequency passive sensors used in this test was performed in normal operating condition without excitation required from any active sources or short period noise perturbations. Ten measurements were conducted on the bridge deck and ten measurements on the ground surface in order to identify the natural frequencies of the bridge. Several peak frequencies were identified from three components of Fourier Amplitude Spectra (FAS in transverse (North-South, longitudinal (East-West and vertical (Up-Down direction as well as squared average Horizontal to Vertical Spectral Ratio (HVSR of ground response, computed by using Geopsy software. From the result, it was expected the bridge have five vibration modes frequencies in the range of 1.0 Hz and 7.0 Hz with the first two modes in the transverse and longitudinal direction having a frequency 1.0 Hz, the third mode is 2.2 Hz in transverse direction, fourth and fifth mode is 5.8 Hz and 7.0 Hz. For ground natural frequencies are in range 1.0 Hz to 1.3 Hz for North-South direction and 1.0 Hz to 1.6 Hz for East-West direction. Finally the results are compared with several empirical formulas for simple

  5. V. Tormis: "Bridge of Song / Brian Hunt

    Index Scriptorium Estoniae

    Hunt, Brian

    1997-01-01

    Uuest heliplaadist "V. Tormis: "Bridge of Song" - Bridge of Song; Singing aboard ship; Brides Farewell; Kihnu Island Wedding Songs; 17 Estonian Wedding Songs; Three Estonian Game Songs; Four Estonian Lullabies. Estonian Radio Choir / Toomas Kapten. Finlandia 4509 96937-2; 56:52 DDD; "People of Kalevala" - God protect us from war; Vespian Winter; Eagle Flew From the North East; Plague Memory; Vainamoinen's Words of Wisdom; The Seventeenth Rune of Kalevala. National Male Choir of Estonia. Finlandia 0630 12245-2; 56:52 DDD

  6. Composite timber-concrete road bridge structure

    Directory of Open Access Journals (Sweden)

    Stojić Dragoslav

    2007-01-01

    Full Text Available This work presents preliminary design of the road bridge made of laminated timber. The supporting system of the main bearing elements is made of the laminated timber in the system of arch with three joints; the bridge slab is designed as continuous slab, made of nine equal fields; each pair is made as composite timber-concrete beam, where the road slab is made of concrete and the needle pieces are made of timber. Fundament is based on HW piles. All the elements are designed to Eurocode.

  7. Planar Hall effect bridge magnetic field sensors

    Science.gov (United States)

    Henriksen, A. D.; Dalslet, B. T.; Skieller, D. H.; Lee, K. H.; Okkels, F.; Hansen, M. F.

    2010-07-01

    Until now, the planar Hall effect has been studied in samples with cross-shaped Hall geometry. We demonstrate theoretically and experimentally that the planar Hall effect can be observed for an exchange-biased ferromagnetic material in a Wheatstone bridge topology and that the sensor signal can be significantly enhanced by a geometric factor. For the samples in the present study, we demonstrate an enhancement of the sensor output by a factor of about 100 compared to cross-shaped sensors. The presented construction opens a new design and application area of the planar Hall effect, which we term planar Hall effect bridge sensors.

  8. Ca3Mn2O7.

    Science.gov (United States)

    Guiblin, Nicolas; Grebille, Dominique; Leligny, Henri; Martin, Christine

    2002-01-01

    The tricalcium dimanganese heptaoxide (Ca3Mn2O7) member of the Ruddlesden-Popper series Ca(n+1)Mn(n)O(3n+1), i.e. with n = 2, was previously reported with an I-centred tetragonal lattice [a(t) = 3.68 and c(t) = 19.57 A] by Fawcett, Sunstrom, Greenblatt, Croft & Ramanujachary [Chem. Mater. (1998), 10, 3643-3651]. It is now found to be orthorhombic, with an A-centred lattice [a = 5.2347 (6), b = 5.2421 (2) and c = 19.4177 (19) A]. The structure has been refined in space group A2(1)am using X-ray single-crystal diffraction data and assuming the existence of twin domains related by the (1-10) plane. A comparison with the basic perovskite structure CaMnO3 (n = infinity) is proposed.

  9. BSA与α-MnO2及δ-MnO2间的界面吸附作用%The adsorption of BSA on the surfaces of α-MnO2 and δ-MnO2

    Institute of Scientific and Technical Information of China (English)

    蔡爱军; 马子川; 刘敬泽

    2007-01-01

    比较研究了牛血清白蛋白(BSA)与α-MnO2和δ-MnO2的界面吸附作用及其影响因素.结果表明,BSA在两种MnO2颗粒物表面有明显的吸附,且δ-MnO2比α-MnO2对BSA的吸附能力略强.pH3.8~8.0范围内,BSA在α-MnO2和δ-MnO2上的吸附率随pH的升高而减小,pH3.8条件下,α-MnO2上的吸附率为88.2%,δ-MnO2上的吸附率为94.0%.BSA在α-MnO2和δ-MnO2上的吸附量均随BSA浓度的增加而增大,吸附率随NaCl浓度的增加而减小.BSA在α-MnO2上的吸附具有很高的不可逆性,δ-MnO2上的吸附完全不可逆.吸附过程中BSA发生解螺旋作用,引起结构熵增大.

  10. Mn-induced modifications of Ga 3d photoemission from (Ga, Mn)As: evidence for long range effects.

    Science.gov (United States)

    Kanski, J; Ulfat, I; Ilver, L; Leandersson, M; Sadowski, J; Karlsson, K; Pal, P

    2012-10-31

    Using synchrotron based photoemission, we have investigated the Mn-induced changes in Ga 3d core level spectra from as-grown Ga(1-x)Mn(x)As. Although Mn is located in Ga substitutional sites, and therefore does not have any Ga nearest neighbors, the impact of Mn on the Ga core level spectra is pronounced even at Mn concentrations in the region of 0.5%. The analysis shows that each Mn atom affects a volume corresponding to a sphere with around 1.4 nm diameter.

  11. The preferred orientation of Mn3 spins in magnetic multiferroic CaMn7O12

    Science.gov (United States)

    Dai, Jian-Qing; Zhang, Hu; Song, Yu-Min

    2015-12-01

    The remarkable ferroelectricity in CaMn7O12 originates from the helicoidal spin spiral, in which the Mn3 (3b Wyckoff position) spin direction remains controversial. In this paper, the total energy, phase transition path, and spontaneous polarization of CaMn7O12 are investigated by using first-principle methods. We show that, in order to account for the giant electric polarization and the correct phase transition sequence, the relative orientation between the spins of Mn3 and Mn2 (9d Wyckoff position) sites with the same coordinate along the hexagonal c-axis can not be antiparallel, i.e. their relative orientation angle should be ϕ≈0.84π instead of ϕ=π. The most likely reason for the observation of ϕ=π can be attributed to the withdrawal of spin-orbital coupling between the Mn2 and Mn3 spins, which is caused by doping Cu2+ in the samples for neutron powder diffraction measurements.

  12. Magnetism of carbon doped Mn5Si3 and Mn5Ge3 films

    Indian Academy of Sciences (India)

    C Sürgers; K Potzger; G Fischer

    2009-03-01

    The magnetic properties of Mn5Si3C and Mn5Ge3C films prepared by magnetron cosputtering or C+-ion implantation are studied. The carbon-doped films exhibit ferromagnetic properties with Curie temperatures C well above room temperature and metallic conductivity, making them possible candidates for future magnetic semiconductor-based devices. In Mn5Si3C, the carbon gives rise to a lattice expansion and a concomitant change of the magnetic order from antiferromagnetic Mn5Si3 to ferromagnetic Mn5Si3C0.8 with C = 350 K. Likewise, C of ferromagnetic Mn5Ge3 is strongly enhanced in Mn5Ge3C0.8. However, in this case the lattice is slightly compressed by carbon. This demonstrates that the effect of carbon on the magnetic behaviour in these compounds is not simply due to a change of the various interatomic distances by carbon but also due to a modification of the electronic band structure.

  13. Experimental investigation of different fill materials in arch bridges with particular focus on Pearl-Chain Bridges

    DEFF Research Database (Denmark)

    Lund, Mia Schou Møller; Hansen, Kurt Kielsgaard; Hertz, Kristian Dahl

    2016-01-01

    Pearl-Chain Bridge technology is a recently developed prefabricated arch solution for road and railway bridges allowing faster, more environmentally friendly, and cheaper bridge construction. This study compared the strength and durability properties of three different types of fill material...... to find the most optimal fill for Pearl-Chain Bridges. Sub-base gravel, cement-stabilized gravel, and pervious concrete were tested with respect to compressive strength, stiffness, splitting tensile strength, permeability, freeze–thaw durability, and shrinkage. This paper summarizes the advantages...... and disadvantages of implementing the different types of fill material in arch bridges, particularly in Pearl-Chain Bridges....

  14. Synthesis and Structure of a Mn(II)-triazolyl Coordination Polymer Consisting of Dinuclear Units%Synthesis and Structure of a Mn(II)-triazolyl Coordination Polymer Consisting of Dinuclear Units

    Institute of Scientific and Technical Information of China (English)

    WU Tao; XU Hong-Yan; KONG Fan-Zhen; YU Zhang-Yu; WANG Rui-Hu

    2012-01-01

    The reaction of bis(1,2,4-triazolyl-4-yl) (btr) and MnClO4-6H20 gave rise to a Mn(II) complex comprised of unprecedented dinuclear Mn(II) units, {[Mn2(btr)s(H20)5]- (ClO4)4(H20)2]n (1). Single-crystal X-ray diffraction analysis revealed that 1 crystallizes in the monoclinic space group C2/c. btr adopts two types of bridging modes. One serves as μ-N1 :N2 bridge through one triazolyl ring of btr forming a dinuclear Mn(II) unit, and the other adopts an exo-bidentate mode using two nitrogen atoms from each triazolyl ring and links the dinuclear units into a 2D cationic layer. ClO4 acts as a counter anion and does not take part in coordination. Interestingly, 2D layers are packed in an ABCABC mode. ClO4- and uncoordinated water molecules locate between the adjacent layers, and extensive hydrogen bonds further stabilize the whole framework.

  15. Bridge Influence Line Estimation for Bridge Weigh-in-Motion System

    OpenAIRE

    Ieng, Sio Song

    2015-01-01

    This paper presents an algorithm that estimates the influence line (IL) of a bridge using data collected when trucks pass over the sensors installed in the bridge. The algorithm is tested with data collected from the Millau Viaduct in France using a bridge weigh-in-motion (B-WIM) device. The algorithm uses the maximum likelihood estimation (MLE) and is compared with an old algorithm. The algorithm is more robust because it takes into account many signals for the estimation of the IL.

  16. Room Temperature Ferromagnetic Mn:Ge(001

    Directory of Open Access Journals (Sweden)

    George Adrian Lungu

    2013-12-01

    Full Text Available We report the synthesis of a room temperature ferromagnetic Mn-Ge system obtained by simple deposition of manganese on Ge(001, heated at relatively high temperature (starting with 250 °C. The samples were characterized by low energy electron diffraction (LEED, scanning tunneling microscopy (STM, high resolution transmission electron microscopy (HRTEM, X-ray photoelectron spectroscopy (XPS, superconducting quantum interference device (SQUID, and magneto-optical Kerr effect (MOKE. Samples deposited at relatively elevated temperature (350 °C exhibited the formation of ~5–8 nm diameter Mn5Ge3 and Mn11Ge8 agglomerates by HRTEM, while XPS identified at least two Mn-containing phases: the agglomerates, together with a Ge-rich MnGe~2.5 phase, or manganese diluted into the Ge(001 crystal. LEED revealed the persistence of long range order after a relatively high amount of Mn (100 nm deposited on the single crystal substrate. STM probed the existence of dimer rows on the surface, slightly elongated as compared with Ge–Ge dimers on Ge(001. The films exhibited a clear ferromagnetism at room temperature, opening the possibility of forming a magnetic phase behind a nearly ideally terminated Ge surface, which could find applications in integration of magnetic functionalities on semiconductor bases. SQUID probed the co-existence of a superparamagnetic phase, with one phase which may be attributed to a diluted magnetic semiconductor. The hypothesis that the room temperature ferromagnetic phase might be the one with manganese diluted into the Ge crystal is formulated and discussed.

  17. Helimagnetic order in bulk MnSi and CoSi/MnSi superlattices

    Science.gov (United States)

    Loh, G. C.; Khoo, K. H.; Gan, C. K.

    2017-01-01

    Skyrmions are nanoscopic whirls of spins that reside in chiral magnets. It is only fairly recent that a plethora of applications for these quasiparticles emerges, especially in data storage. On the other hand, spin spirals are the periodic analogs of skyrmions, and are equally imperative in the course of exploration to enhance our understanding of helimagnetism. In this study, a new infrastructure based on the B20 compound, MnSi is propounded as a hosting material for spin spirals; alternating thin layers of CoSi and MnSi in the superlattice form provides a facile way of varying the properties of the spin spirals across a continuum. Using first-principles calculations based on full-potential linearized augmented plane-wave (FLAPW)-based density functional theory (DFT), the spin order of bulk MnSi, MnSi film, and the CoSi/MnSi superlattice is investigated. Spin dispersion plots as a function of propagation vectors show that the spiral size changes in the presence of CoSi - we find that the size of the spiral is reduced in the superlattice with thin CoSi layers (CoSi:MnSi=1:1 thickness ratio), whilst at a larger CoSi:MnSi=2:1 thickness ratio, the material behaves as a ferromagnet. In a similar fashion, the spin moment and orbital occupancy depend significantly on the thickness of the CoSi layers. However, the exchange interaction between Mn atoms appears to be generally impervious to the presence of CoSi. Succinctly, the CoSi/MnSi superlattice could be an excellent functional material in data storage applications.

  18. Shape memory effect in Fe-Mn-Ni-Si-C alloys with low Mn contents

    Energy Technology Data Exchange (ETDEWEB)

    Min, X.H., E-mail: MIN.Xiaohua@nims.go.jp [National Institute for Materials Science, Tsukuba 305-0047 (Japan); Sawaguchi, T.; Ogawa, K. [National Institute for Materials Science, Tsukuba 305-0047 (Japan); Maruyama, T. [Awaji Materia Co., Ltd. 2-3-13, Kanda ogawamachi, Chiyoda, Tokyo 101-0052 (Japan); Yin, F.X. [National Institute for Materials Science, Tsukuba 305-0047 (Japan); Tsuzaki, K. [National Institute for Materials Science, Tsukuba 305-0047 (Japan); Graduate School of Pure and Applied Sciences, University of Tsukuba, Ibaraki 305-0047 (Japan)

    2011-06-15

    Highlights: {yields} A class of new Fe-Mn-Ni-Si-C shape memory alloys with low Mn contents has been designed. {yields} A Mn content for the onset of the {alpha}' martensite is less than 13 mass%, and the {epsilon} martensite still exists in the alloy with a 9 mass% Mn. {yields} The shape recovery strain decreases considerably when the Mn content is reduced from 13 to 11 mass%. {yields} The sudden decrease in the shape recovery strain is mainly caused by the formation of {alpha}' martensite. - Abstract: An attempt was made to develop a new Fe-Mn-Si-based shape memory alloy from a Fe-17Mn-6Si-0.3C (mass%) shape memory alloy, which was previously reported to show a superior shape memory effect without any costly training treatment, by lowering its Mn content. The shape memory effect and the phase transformation behavior were investigated for the as-solution treated Fe-(17-2x)Mn-6Si-0.3C-xNi (x = 0, 1, 2, 3, 4) polycrystalline alloys. The shape recovery strain exceeded 2% in the alloys with x = 0-2, which is sufficient for an industrially applicable shape memory effect; however, it suddenly decreased in the alloys between x = 2 and 3 although the significant shape recovery strain still exceeded 1%. In the alloys with x = 3 and 4, X-ray diffraction analysis and transmission electron microscope observation revealed the existence of {alpha}' martensite, which forms at the intersection of the {epsilon} martensite plates and suppresses the crystallographic reversibility of the {gamma} austenite to {epsilon} martensitic transformation.

  19. Detailed magnetic study on the formato-bridged MOFs with anion-tunable magnetic properties

    Institute of Scientific and Technical Information of China (English)

    WANG XinYi; WANG ZheMing; GAO Song

    2012-01-01

    Detailed studies of the structures,magnetic properties and photodimerization of a series of formato-bridged MOFs with the general formula M2(HCOO)3(4,4'-bpe)3(H20)3(X)(4,4'-bpe =4,4'-bipyridylethylene,M =Mn(l-X-),X- =CIO-4,NO-3,BF-4,I-,Br-; M =Co(2-X-),X- =CIO-4,NO-3; M =Zn(3-X-),X- =NO-3)were reported.Careful magnetic measurements on an oriented single crystal of 1-ClO-4 determined the spin-flop magnetic phase diagram and some intrinsic parameters,such as the intralayer coupling J,the anisotropy field HA and the exchange field HE.Different anions can remarkably tune the magnetic properties of l-X-,especially the critical fields of the spin-flop transition.Compound 2-ClO-4 remained paramagnetic down to 2 K.

  20. Mn based olivine electrode material with high power and energy.

    Science.gov (United States)

    Kim, Jongsoon; Seo, Dong-Hwa; Kim, Sung-Wook; Park, Young-Uk; Kang, Kisuk

    2010-02-28

    We report the Mn based olivine electrode material with high power and energy. Easier and more frequent nucleation by Fe and Co in Mn-based olivines significantly enhanced the rate capability as evidenced by the electrochemical results.

  1. Malonate-containing manganese(III) complexes: synthesis, crystal structure, and magnetic properties of AsPh4[Mn(mal)2(H2O)2].

    Science.gov (United States)

    Delgado, Fernando S; Kerbellec, Nicolas; Ruiz-Pérez, Catalina; Cano, Joan; Lloret, Francesc; Julve, Miguel

    2006-02-06

    The novel manganese(III) complexes PPh4[Mn(mal)2(H2O)2] (1) and AsPh4[Mn(mal)2(H2O)2] (2) (PPh4+ = tetraphenylphosphonium cation, AsPh4+ = tetraphenylarsonium cation, and H2mal = malonic acid) have been prepared, and the structure of 2 was determined by X-ray diffraction analysis. 2 is a mononuclear complex whose structure is made up of trans-diaquabis(malonato)manganate(III) units and tetraphenylarsonium cations. Two crystallographically independent manganese(III) ions (Mn(1) and Mn(2)) occur in 2 that exhibit elongated octahedral surroundings with four oxygen atoms from two bidentate malonate groups in equatorial positions (Mn(1)-O = 1.923(6) and 1.9328(6) A and Mn(2)-O = 1.894(6) and 1.925(6) A) and two trans-coordinated water molecules in the axial sites (Mn(1)-Ow = 2.245(6) A and Mn(2)-Ow = 2.268(6) A). The [Mn(mal)2(H2O)2]- units are linked through hydrogen bonds involving the free malonate-oxygen atoms and the coordinated water molecules to yield a quasi-square-type anionic layer growing in the ab plane. The shortest intralayer metal-metal separations are 7.1557(7) and 7.1526(7) A (through the edges of the square). The anionic sheets are separated from each other by layers of AsPh4+ where sextuple- and double-phenyl embraces occur. The magnetic behavior of 1 and 2 in the temperature range 1.9-290 K reveals the occurrence of weak intralayer ferromagnetic interactions (J = +0.081(1) (1) and +0.072(2) cm(-1) (2)). These values are compared to those of the weak antiferromagnetic coupling [J = -0.19(1) cm(-1)], which is observed in the chain compound K2[Mn(mal)2(MeOH)2][Mn(mal)2] (3), where the exchange pathway involves the carboxyate-malonate bridge in the anti-syn conformation. The structure of 3 was reported elsewhere. Theoretical calculations on fragment models of 2 and 3 were performed to analyze and substantiate both the nature and magnitude of the magnetic couplings observed.

  2. Violin bridge mobility analysis under in-plane excitation.

    Science.gov (United States)

    Zhang, Cheng-Zhong; Zhang, Guang-Ming; Ye, Bang-Yan; Liang, Li-Dong

    2013-11-08

    The vibration of a violin bridge is a dynamic contact vibration with two interfaces: strings-bridge, and bridge feet-top plate. In this paper, the mobility of an isolated bridge under in-plane excitation is explored using finite element modeling based on the contact vibration model. Numerical results show that the dynamic contact stiffness in the two contact interfaces has a great impact on the bridge mobility. A main resonance peak is observed in the frequency range of 2-3 kHz in the frequency response of the isolated bridge when the contact stiffness is smaller than a critical threshold. The main resonance peak frequency is affected by the contact stiffness as well. In order to verify the numerical findings, a novel experimental system is then designed on the basis of a piezoelectric dynamometer for bridge mobility analysis. Experimental results confirm the impact of the dynamic contact stiffness on the bridge mobility.

  3. Foot force models of crowd dynamics on a wobbly bridge

    CERN Document Server

    Belykh, Igor; Belykh, Vladamir

    2016-01-01

    Modern pedestrian and suspension bridges are designed using industry-standard packages, yet disastrous resonant vibrations are observed, necessitating multi-million dollar repairs. Recent examples include pedestrian induced vibrations during the openings of the Solf\\'erino Bridge in Paris in 1999 and the increased bouncing of the Squibb Park Bridge in Brooklyn in 2014. The most prominent example of an unstable lively bridge is the London Millennium Bridge which started wobbling as a result of pedestrian-bridge interactions. Pedestrian phase-locking due to footstep phase adjustment, is suspected to be the main cause of its large lateral vibrations; however, its role in the initiation of wobbling was debated. In this paper, we develop foot force models of pedestrians' response to bridge motion and detailed, yet analytically tractable models of crowd phase-locking. We use bio-mechanically inspired models of crowd lateral movement to investigate to what degree pedestrian synchrony must be present for a bridge to ...

  4. CDC WONDER: Population - Bridged-Race July 1st Estimates

    Data.gov (United States)

    U.S. Department of Health & Human Services — The Population - Bridged-Race July 1st Estimates online databases report bridged-race population estimates of the July 1st resident population of the United States,...

  5. MnGa-based fully perpendicular magnetic tunnel junctions with ultrathin Co2MnSi interlayers.

    Science.gov (United States)

    Mao, Siwei; Lu, Jun; Zhao, Xupeng; Wang, Xiaolei; Wei, Dahai; Liu, Jian; Xia, Jianbai; Zhao, Jianhua

    2017-02-24

    Because tetragonal structured MnGa alloy has intrinsic (not interface induced) giant perpendicular magnetic anisotropy (PMA), ultra-low damping constant and high spin polarization, it is predicted to be a kind of suitable magnetic electrode candidate in the perpendicular magnetic tunnel junction (p-MTJ) for high density spin transfer torque magnetic random access memory (STT-MRAM) applications. However, p-MTJs with both bottom and top MnGa electrodes have not been achieved yet, since high quality perpendicular magnetic MnGa films can hardly be obtained on the MgO barrier due to large lattice mismatch and surface energy difference between them. Here, a MnGa-based fully p-MTJ with the structure of MnGa/Co2MnSi/MgO/Co2MnSi/MnGa is investigated. As a result, the multilayer is with high crystalline quality, and both the top and bottom MnGa electrodes show well PMA. Meanwhile, a distinct tunneling magnetoresistance (TMR) ratio of 65% at 10 K is achieved. Ultrathin Co2MnSi films are used to optimize the interface quality between MnGa and MgO barrier. A strong antiferromagnetic coupling in MnGa/Co2MnSi bilayer is confirmed with the interfacial exchange coupling constant of -5erg/cm(2). This work proposes a novel p-MTJ structure for the future STT-MRAM progress.

  6. MnGa-based fully perpendicular magnetic tunnel junctions with ultrathin Co2MnSi interlayers

    Science.gov (United States)

    Mao, Siwei; Lu, Jun; Zhao, Xupeng; Wang, Xiaolei; Wei, Dahai; Liu, Jian; Xia, Jianbai; Zhao, Jianhua

    2017-01-01

    Because tetragonal structured MnGa alloy has intrinsic (not interface induced) giant perpendicular magnetic anisotropy (PMA), ultra-low damping constant and high spin polarization, it is predicted to be a kind of suitable magnetic electrode candidate in the perpendicular magnetic tunnel junction (p-MTJ) for high density spin transfer torque magnetic random access memory (STT-MRAM) applications. However, p-MTJs with both bottom and top MnGa electrodes have not been achieved yet, since high quality perpendicular magnetic MnGa films can hardly be obtained on the MgO barrier due to large lattice mismatch and surface energy difference between them. Here, a MnGa-based fully p-MTJ with the structure of MnGa/Co2MnSi/MgO/Co2MnSi/MnGa is investigated. As a result, the multilayer is with high crystalline quality, and both the top and bottom MnGa electrodes show well PMA. Meanwhile, a distinct tunneling magnetoresistance (TMR) ratio of 65% at 10 K is achieved. Ultrathin Co2MnSi films are used to optimize the interface quality between MnGa and MgO barrier. A strong antiferromagnetic coupling in MnGa/Co2MnSi bilayer is confirmed with the interfacial exchange coupling constant of −5erg/cm2. This work proposes a novel p-MTJ structure for the future STT-MRAM progress. PMID:28233780

  7. Hydraulic bridges in unsaturated coarse granular media: Influence of bridge size and conductivity on flow through clasts

    Science.gov (United States)

    Jayakody, Jeevan A.; Nicholl, Michael J.

    2016-10-01

    Unsaturated flow in coarse granular media must pass through hydraulic bridges (e.g., pendular water, porous connections) that form a physical connection between adjoining clasts. Previous studies suggest that volumetric flow through a porous clast (Q) will be linearly dependent on the cross-sectional area of the hydraulic bridges, and understate the importance of bridge conductivity. Numerical simulations were performed to explore steady-state flow through a spherical clast with identical bridges located at the top and bottom. The cross-sectional area of the bridges relative to that of the clast (Ar) was varied across six orders of magnitude. The ratio of hydraulic conductivity between bridges and clasts (Kb/Kc) was varied across 12 orders of magnitude to consider resistive, neutral, and conductive bridges. Results show that hydraulic bridges place a primary control on both Q and flux distribution within the clast. For neutral and conductive bridges (Kb/Kc ≥1), Ar is the dominant factor in determining Q, while Kb/Kc is the primary control for resistive bridges (Kb/Kc < 1). For all bridges, Q shows a non-linear dependency on both Ar and Kb/Kc. The intra-clast flow distribution shifts outwards as Ar increases. Conductive bridges promote this process and resistive bridges impede it.

  8. Steel plate reinforcement of orthotropic bridge decks

    NARCIS (Netherlands)

    Teixeira de Freitas, S.

    2012-01-01

    The PhD research is focused on the reinforcement of fatigue cracked orthotropic steel bridge decks (OBD) by adding a second steel plate to the existing deck. The main idea is to stiffen the existing deck plate, which will reduce the stresses at the fatigue sensitive details and extend the fatigue li

  9. LPN/ADN Bridge Course. Instructor's Guide.

    Science.gov (United States)

    Barrett, Jan; And Others

    This curriculum guide has been constructed in order to bridge the skills gap between licensed practical nursing (LPN) programs and associate degree nursing (ADN) programs in Missouri. The curriculum was developed through a cooperative effort by persons from both sectors. The curriculum contains four major units, each consisting of several lessons,…

  10. Images Bridging Home and Academic Cultures.

    Science.gov (United States)

    Andres, Sophia

    Often students are unable to draw upon their personal worlds and individual experiences to enrich their writing, suggesting a disparity between home and academic cultures. In light of this apparent disparity, teachers must try to bridge the gap, a task that is possible when the teacher focuses on the germinal, emotional, and unifying qualities of…

  11. The mechanics of ship impacts against bridges

    DEFF Research Database (Denmark)

    Pedersen, Preben Terndrup; Zhang, Shengming

    1998-01-01

    a glancing blow between the ship and the bridge structure. This model is based on rigid body mechanics and well suited for inclusion in a probabilistic analysis procedure. Finally, some empirical expressions are presented which relate the energy absorbed by crushing of ship structures to the maximum impact...

  12. Bridging the digital divide with mobile services

    CERN Document Server

    Yelton, Andromeda

    2013-01-01

    In this issue of Library Technology Reports, Andromeda Yelton shows how libraries can build on the breadth of this population to help bridge the digital divide and provide even greater access to information. Yelton breaks down the demographics of mobile internet users, provides examples of how different libraries are reaching out to these populations, and suggests what the future may hold for this trend.

  13. New Program Builds Bridges for Hearing Impaired.

    Science.gov (United States)

    Johnson, Jeannie

    1998-01-01

    Describes a new approach to teaching English-as-a-Second-Language to New Mexico elementary school students who have hearing impairments and whose dominant language is American Sign Language (ASL). These students must first acquire ASL as a bridge to learning English. Then, using the bilingual approach, they are able to focus on English literacy.…

  14. Ergonomic aspects of automation in navigation bridges

    NARCIS (Netherlands)

    Lazet, A.; Walraven, P.L.

    1971-01-01

    New ergonomic questions arise from the tendency toward increasing automation in maritime operations. Direct control of engines and rudder from the bridge promises improved ship control, provided that the operator can really exploit the technical improvements. To make such direct control most efficie

  15. Fiber reinforced polymer composites for bridge structures

    Directory of Open Access Journals (Sweden)

    Alexandra CANTORIU

    2013-12-01

    Full Text Available Rapid advances in construction materials technology have led to the emergence of new materials with special properties, aiming at safety, economy and functionality of bridges structures. A class of structural materials which was originally developed many years ago, but recently caught the attention of engineers involved in the construction of bridges is fiber reinforced polymer composites. This paper provides an overview of fiber reinforced polymer composites used in bridge structures including types, properties, applications and future trends. The results of this study have revealed that this class of materials presents outstanding properties such as high specific strength, high fatigue and environmental resistance, lightweight, stiffness, magnetic transparency, highly cost-effective, and quick assembly, but in the same time high initial costs, lack of data on long-term field performance, low fire resistance. Fiber reinforced polymer composites were widely used in construction of different bridge structures such as: deck and tower, I-beams, tendons, cable stands and proved to be materials for future in this field.

  16. Aeroelastic Stability of Suspension Bridges using CFD

    DEFF Research Database (Denmark)

    Stærdahl, Jesper Winther; Sørensen, Niels; Nielsen, Søren R.K.

    2007-01-01

    In recent years large span suspension bridges with very thin and slender profiles have been built without proportional increasing torsional and bending stiffness. As a consequence large deformations at the mid-span can occur with risk of aeroelastic instability and structural failure. Analysis...

  17. Bridge monitoring using heterogeneous wireless sensor network

    Science.gov (United States)

    Haran, Shivan; Kher, Shubhalaxmi; Mehndiratta, Vandana

    2010-03-01

    Wireless sensor networks (WSN) are proving to be a good fit where real time monitoring of multiple physical parameters is required. In many applications such as structural health monitoring, patient data monitoring, traffic accident monitoring and analysis, sensor networks may involve interface with conventional P2P systems and it is challenging to handle heterogeneous network systems. Heterogeneous deployments will become increasingly prevalent as it allows for systems to seamlessly integrate and interoperate especially when it comes to applications involving monitoring of large infrastructures. Such networks may have wireless sensor network overlaid on a conventional computer network to pick up data from one distant location and carry out the analysis after relaying it over to another distant location. This paper discusses monitoring of bridges using WSN. As a test bed, a heterogeneous network of WSN and conventional P2P together with a combination of sensing devices (including vibration and strain) is to be used on a bridge model. Issues related to condition assessment of the bridge for situations including faults, overloads, etc., as well as analysis of network and system performance will be discussed. When conducted under controlled conditions, this is an important step towards fine tuning the monitoring system for recommendation of permanent mounting of sensors and collecting data that can help in the development of new methods for inspection and evaluation of bridges. The proposed model, design, and issues therein will be discussed, along with its implementation and results.

  18. Circuit bridging of components by smoke

    Energy Technology Data Exchange (ETDEWEB)

    Tanaka, T.J.; Nowlen, S.P.; Anderson, D.J. [Sandia National Labs., Albuquerque, NM (United States)

    1996-10-01

    Smoke can adversely affect digital electronics; in the short term, it can lead to circuit bridging and in the long term to corrosion of metal parts. This report is a summary of the work to date and component-level tests by Sandia National Laboratories for the Nuclear Regulatory Commission to determine the impact of smoke on digital instrumentation and control equipment. The component tests focused on short-term effects such as circuit bridging in typical components and the factors that can influence how much the smoke will affect them. These factors include the component technology and packaging, physical board protection, and environmental conditions such as the amount of smoke, temperature of burn, and humidity level. The likelihood of circuit bridging was tested by measuring leakage currents and converting those currents to resistance in ohms. Hermetically sealed ceramic packages were more resistant to smoke than plastic packages. Coating the boards with an acrylic spray provided some protection against circuit bridging. The smoke generation factors that affect the resistance the most are humidity, fuel level, and burn temperature. The use of CO{sub 2} as a fire suppressant, the presence of galvanic metal, and the presence of PVC did not significantly affect the outcome of these results.

  19. Thermal Bridge Effects in Window Grooves

    DEFF Research Database (Denmark)

    Rose, Jørgen

    1997-01-01

    In this report thermal bridge effects in window grooves are analyzed. The analysis is performed using different thicknesses of the window groove insulation, to evaluate what the optimal solution is.All analysis in the report is performed using both 2- and 3-dimensional numerical analysis....

  20. Section 3: Optimization of a 550/690-MPa high-performance bridge steel

    Energy Technology Data Exchange (ETDEWEB)

    Magee, A.B.; Gross, J.H.; Stout, R.D. [and others

    1997-04-01

    This project to develop a high-performance bridge steel was intended to avoid susceptibility of the steel to weld heat-affected-zone cracking and therefore minimize the requirement for preheat, and to increase its fracture toughness at service temperatures. Previous studies by the Lehigh University Center for Advanced Technology for Large Structural Systems have suggested that a Cu-Ni steels with the following composition was an excellent candidate for such a bridge steel: C/0.070; Mn/1.50; P/0.009; S/0.005; Si/0.25; Cu/1.00; Ni/0.75; Cr/0.50; Mo/0.50; V/0.06; Cb/0.010. To confirm that observation, 227-kg heats of the candidate steel were melted and processed to 25- and 50-mm-thick plate by various thermomechanical practices, and the weldability and mechanical properties determined. To evaluate the feasibility of reduced alloy content, two 227-kg heats of a lower hardenability steel were melted with C reduced to 0.06, Mn to 1.25, and Mo to 0.25 and similarly processed and tested. The results indicate that the steels were not susceptible to hydrogen-induced weld-heat-affected-zone cracking when welded without preheat. Jominy end-quench tests of the higher-hardenability steel indicate that a minimum yield-strength of 690 MPa should be readily attainable in thicknesses through 50 mm and marginally at 100 mm. The toughness of the steel readily met AASHTO specifications for Zone 3 in all conditions and thicknesses, and may be sufficiently tough so that the critical crack size will minimize fatigue-crack-extension problems.

  1. XANES evidence for sulphur speciation in Mn-, Ni- and W-bearing silicate melts

    Science.gov (United States)

    Evans, K. A.; O'Neill, H. St. C.; Mavrogenes, J. A.; Keller, N. S.; Jang, L.-Y.; Lee, J.-F.

    2009-11-01

    spectra of the component element monosulphides. Mn-, W- and Ni-XANES and EXAFS for synthetic glasses without sulphide exsolution did not show any sensitivity to the presence of sulphur, which is unsurprising as S:O ratios were sufficiently low that metals would be mostly co-ordinated by O. Mn EXAFS spectra were consistent with divalent Mn in 5 co-ordinated Mn-O melt species. W spectra were consistent with tetrahedrally co-ordinated hexavalent W, most likely in scheelite-like melt species, and Ni spectra were consistent with [4] co-ordinated divalent Ni. These results indicate lower co-ordinations for both W and Ni than those inferred by some previous workers. Cation co-ordination may reflect the proportion of non-bridging oxygens, which is lower in the Ca-rich and Al-poor samples investigated here than for previous studies.

  2. RISK LEVEL ANALYSIS ON THE PREVENTIVE EROSION CAPACITY OF BRIDGES

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    Deficiency of the Preventive Erosion Capacity (PEC) of a bridge pier is the main factor leading to bridge failures. In this paper, the PEC of bridge piers was analyzed using the stochastic analysis method. The definitions of the reliability and risk level of a bridge pier subjected to water erosion were proposed and a computational model for erosion depth and risk level in was suggested.

  3. Nondestructive evaluation inspection of the Arlington Memorial Bridge using a robotic assisted bridge inspection tool (RABIT)

    Science.gov (United States)

    Gucunski, Nenad; Boone, Shane D.; Zobel, Rob; Ghasemi, Hamid; Parvardeh, Hooman; Kee, Seong-Hoon

    2014-04-01

    The information presented in this report provides a detailed assessment of the condition of the Arlington Memorial Bridge (AMB) deck. The field-data collection was obtained by both the RABIT™ Bridge Inspection Tool and a number of semi-automated non-destructive evaluation (NDE) tools. The deployment of the semi-automated NDE tools was performed to inspect the AMB deck condition and also to validate data obtained by the RABIT™ Bridge Inspection Tool. Data mining and analysis were accomplished through enhanced data interpretation and visualization capabilities using advanced data integration, fusion, and 2D rendering. One of the major challenges that the research team had to overcome in assessing the condition of the AMB deck was the presence of an asphalt overlay on the entire bridge deck.

  4. Railroad Bridges in Louisiana, Geographic NAD83, FEMA (1997) [railroad_bridges_FEMA_1997

    Data.gov (United States)

    Louisiana Geographic Information Center — This is is a point dataset for the locations and attributes of 32 Louisiana railroad bridges. The attributes include city (nearest?), county (sic), routefrom (city),...

  5. Performance Assessment of Bridges Using GPS: The Juarez Bridge in Culiacan, Mexico

    Science.gov (United States)

    Vazquez, G. E.; Gaxiola-Camacho, J. R.; Trejo, M.; Echagaray, J.; Guzman, G. M.

    2015-12-01

    Performance assessment of bridges has become very important during recent years. Bridges around the world are aging, leading to the incorporation of efficient, reliable, and economic evaluation procedures. These techniques must assess properly the performance of bridges under several loading conditions in a real manner, representing the physics of the problem. Among several approaches, Global Positioning System (GPS) can be intelligently used for the performance evaluation of bridges. We focused on GPS, since it naturally produces position estimates as compared to seismic instruments that record either velocity or acceleration, and thus require an integration. There are several reasons that make the Juarez Bridge a case of study for evaluation: it is approximately 45 years old, it is a reinforced concrete structure, it connects two significant zones of the city, and its spans is closely to 200 meters long. In addition, thousands of vehicles and pedestrians use the Juarez Bridge every day, which make feasible the GPS performance assessment. Hence, in order to produce optimal position estimates, GPS data were collected during two consecutive hours at three different periods of the day for a whole week (Monday through Sunday), to represent three critical limit states of the bridge (mid-span and end-spans). GPS data were processed using the GAMIT/GLOBK software, considering 1-second sampling rate, 15-degree cutoff angle, ionosphere-free double-differenced (DD) carrier phase method, and precise final orbits disseminated by IGS (International GNSS Service). The displacements obtained from the above discussed procedure are compared with allowable values documented in bridge construction manuals. Reliability theory was used to evaluate the probability of failure of the bridge for the three periods of the day. In addition, a conclusion was made about the most risky day of the week for the use of the Juarez Bridge. It is expected that the results from the proposed research

  6. Magnetoresistance effect in (La, Sr)MnO{sub 3} bicrystalline films

    Energy Technology Data Exchange (ETDEWEB)

    Alejandro, G; Pastoriza, H; Granada, M; Rojas Sanchez, J C; Sirena, M; Alascio, B [Centro Atomico Bariloche (CNEA), Av. Bustillo 9500, 8400 San Carlos de Bariloche, Pcia. de Rio Negro (Argentina); Steren, L B; Vega, D, E-mail: galejand@cab.cnea.gov.a [Centro Atomico Constituyentes (CNEA), 1650 San MartIn, Pcia. de Buenos Aires (Argentina)

    2010-09-01

    The angular dependence of the magnetoresistance effect has been measured on bicrystalline La{sub 0.75}Sr{sub 0.25}MnO{sub 3} films. The measurements have been performed on an electronically lithographed Wheatstone bridge. The study of the angular dependence of both the magnetoresistance and the resistance of single-crystalline and grain-boundary regions of the samples allowed us to isolate two contributions of low-field magnetoresistance in manganites. One of them is associated with the spin-orbit effect, i.e. the anisotropic magnetoresistance of ferromagnetic compounds, and the other one is related to spin-disorder regions at the grain boundary. Complementary x-ray diffraction, ferromagnetic resonance and low temperature magnetization experiments contribute to the characterization of the magnetic anisotropy of the samples and the general comprehension of the problem.

  7. Magnetoresistance effect in (La, Sr)MnO3 bicrystalline films.

    Science.gov (United States)

    Alejandro, G; Steren, L B; Pastoriza, H; Vega, D; Granada, M; Sánchez, J C Rojas; Sirena, M; Alascio, B

    2010-09-01

    The angular dependence of the magnetoresistance effect has been measured on bicrystalline La(0.75)Sr(0.25)MnO(3) films. The measurements have been performed on an electronically lithographed Wheatstone bridge. The study of the angular dependence of both the magnetoresistance and the resistance of single-crystalline and grain-boundary regions of the samples allowed us to isolate two contributions of low-field magnetoresistance in manganites. One of them is associated with the spin-orbit effect, i.e. the anisotropic magnetoresistance of ferromagnetic compounds, and the other one is related to spin-disorder regions at the grain boundary. Complementary x-ray diffraction, ferromagnetic resonance and low temperature magnetization experiments contribute to the characterization of the magnetic anisotropy of the samples and the general comprehension of the problem.

  8. Ambient Response Analysis of the Great Belt Bridge

    DEFF Research Database (Denmark)

    Brincker, Rune; Frandsen, J. B.; Andersen, P.

    2000-01-01

    In this paper an ambient response analysis of the Great Belt Bridge is presented. The Great Belt Bridge is one of the largest suspension bridges in the world, and the analysis was carried out in order to investigate the possibilities of estimating reliable damping values from the ambient response...

  9. Resin-Bonded Bridges in vitro and in vivo

    NARCIS (Netherlands)

    Veen, Johannes Hilbrandt van der

    1988-01-01

    In this thesis in vitro and in vivo studies on the clinical application of resin-bonded bridges are described and discussed. The development of different types of resin-bonded bridges is described in chapter 1. The bridges are often made by boding a cast metal retainer fitted with and artificial too

  10. Renovation techniques for fatigue cracked orthotropic steel bridge decks

    NARCIS (Netherlands)

    de Jong, F.B.P.

    2007-01-01

    This dissertation presents the research into renovation techniques for orthotropic steel bridge decks. These techniques are needed to solve fatigue problems in the decks of these bridges, as several fatigue cracks have been detected in the deck structure of these bridges the last decade. A well-know

  11. A calculation model for the noise from steel railway bridges

    NARCIS (Netherlands)

    Janssens, M.H.A.; Thompson, D.J.

    1996-01-01

    The sound level of a train crossing a steel railway bridge is usually about 10 dB higher than on plain track. In the Netherlands there are many such bridges which, for practical reasons, cannot be replaced by more intrinsically quiet concrete bridges. A computational model is described for the estim

  12. Dynamic Vehicle Impact for Safety Assessment of Bridges

    DEFF Research Database (Denmark)

    Kirkegaard, Poul Henning; Nielsen, Søren R. K.; Enevoldsen, I.

    In this paper the dynamic amplification of vehicle load at minor highway bridges is considered for safety assessment of the load carrying capacity of bridges. The considered case is the most critical for bridges, i.e. the simultaneous passage of two heavy trucks. A short description...

  13. 33 CFR 115.50 - Application for bridge permits.

    Science.gov (United States)

    2010-07-01

    ... authority not necessary. Coast Guard approval of the location and plans for construction or modification of a bridge or causeway is not required for any bridge or causeway over waters which are not subject to... (historic use). This provision does not apply to bridges which connect the United States with any...

  14. Future Trends in Reliability-Based Bridge Management

    DEFF Research Database (Denmark)

    Thoft-Christensen, Palle

    Future bridge management systems will be based on simple stochastic models predicting the residual strength of structural elements. The current deterministic management systems are not effective in optimizing e.g. the life cycle cost of a bridge or a system of bridges. A number of important factors...

  15. 21 CFR 872.3770 - Temporary crown and bridge resin.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Temporary crown and bridge resin. 872.3770 Section... (CONTINUED) MEDICAL DEVICES DENTAL DEVICES Prosthetic Devices § 872.3770 Temporary crown and bridge resin. (a) Identification. A temporary crown and bridge resin is a device composed of a material, such...

  16. Seismic Performance of Multi-Span RC Railway Bridges

    DEFF Research Database (Denmark)

    Georgakis, Christos; Barrau, Xavier

    2008-01-01

    Presently, there is no clear method for determining the optimal railway bridge design for a particular ground type and expected seismic intensity. Four main types of RC bridge dominate the current multi-span railway bridge design trends – the Simply Supported Beam, Continuous Box-Girder (CBG), CBG...

  17. Reduction of Impact Noise of Trams on a Major Bridge

    NARCIS (Netherlands)

    Dittrich, M.G.; Bosshaart, C.; Wessels, P.W.

    2015-01-01

    As part of a recent renovation of the Erasmus bridge in Rotterdam, improvements were made to reduce impact noise caused by trams passing a series of rai! joints. The bridge inciudes several different sections inciuding a bascule bridge and is in an inner city tocation with new adjacent apartment bui

  18. Improving the Dynamics of Suspension Bridges using Active Control Systems

    DEFF Research Database (Denmark)

    Thoft-Christensen, Palle

    Improving the dynamics of suspension bridge using active control is discussed in this paper. The main dynamic problem with long suspension bridges is the aeroelastic phenomenon called flutter. Flutter oscillations of a bridge girder is a stability problem and the oscillations are perpendicular...

  19. Reliability-Based Optimization for Maintenance Management in Bridge Networks

    OpenAIRE

    Hu, Xiaofei

    2014-01-01

    This dissertation addresses the problem of optimizing maintenance, repair and reconstruction decisions for bridge networks. Incorporating network topologies into bridge management problems is computationally difficult. Because of the interdependencies among networked bridges, they have to be analyzed together. Simulation-based numerical optimization techniques adopted in past research are limited to networks of moderate sizes. In this dissertation, novel approaches are developed to dete...

  20. Highly Sensitive AMS Measurement of 53Mn at CIAE

    Institute of Scientific and Technical Information of China (English)

    DONG; Ke-jun; HU; Hao; LIU; Guang-shan; HE; Ming; LI; Zhen-yu; DOU; Liang; XIE; Lin-bo; LIU; Jian-cheng; WANG; Xiang-gao; SHEN; Hong-tao; LIN; De-yu; ZHENG; Guo-wen; WANG; Xiao-bo; LI; Heng; LI; Chao-li; WU; Shao-yong; YOU; Qu-bo; JIN; Chun-sheng; CHEN; Zhi-gang; YUAN; Jian; JIANG; Shan

    2013-01-01

    Methods for highly sensitive AMS measurement of 53Mn were explored by extracting different Mn-containing molecular ions in ion source and using different chemical forms of sample materials.Preliminary results indicate that a method for AMS measurement of 53Mn has been established and a-155355

  1. The research progress on layered LixMnO2

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    The structural characteristics, preparation methods and electrochemical properties of LixMnO2 were introduced in this paper, and many problems of the research status of LixMnO2 at present were pointet out, meanwhile the developmental direction of layered LixMnO2 in the future was put forward.

  2. τ-MnAl with high coercivity and saturation magnetization

    Directory of Open Access Journals (Sweden)

    J. Z. Wei

    2014-12-01

    Full Text Available In this paper, high purity τ-Mn54Al46 and Mn54−xAl46Cxalloys were successfully prepared using conventional arc-melting, melt-spinning, and heat treatment process. The magnetic and the structural properties were examined using x-ray diffraction (XRD, powder neutron diffraction and magnetic measurements. A room temperature saturation magnetization of 650.5 kAm-1, coercivity of 0.5 T, and a maximum energy product of (BHmax = 24.7 kJm-3 were achieved for the pure Mn54Al46 powders without carbon doping. The carbon substituted Mn54−xAl46Cx, however, reveals a lower Curie temperature but similar saturation magnetization as compared to the carbon-free sample. The electronic structure of MnAl shows that the Mn atom possesses a magnetic moment of 2.454 μB which results from strong hybridization between Mn-Al and Mn-Mn. We also investigated the volume and c/a ratio dependence of the magnetic moments of Mn and Al. The results indicate that an increase in the intra-atomic exchange splitting due to the cell volume expansion, leads to a large magnetic moment for the Mn atom. The Mn magnetic moment can reach a value of 2.9 μB at a volume expansion rate of ΔV/V ≈ 20%.

  3. Of Variability, or its Absence, in HgMn Stars

    CERN Document Server

    Turcotte, S

    2003-01-01

    Current models and observations of variability in HgMn stars disagree. We present here the models that argue for pulsating HgMn stars with properties similar to those of Slowly Pulsating B Stars. The lack of observed variable HgMn stars suggests that some physical process is missing from the models. Some possibilities are discussed.

  4. Road Bridges and Culverts, Bridges layers located in GIS and Transportation database., Published in unknown, City of Roswell, GA.

    Data.gov (United States)

    NSGIC GIS Inventory (aka Ramona) — This Road Bridges and Culverts dataset as of unknown. It is described as 'Bridges layers located in GIS and Transportation database.'. Data by this publisher are...

  5. Magnetism and transport properties of α-Mn structure Mn3Ge thin film

    Science.gov (United States)

    Dung, Dang Duc; Feng, Wuwei; Shin, Yooleemi; Cho, Sunglae

    2011-04-01

    We have newly synthesized the α-Mn structured Mn3Ge thin films on GaAs(001) substrate. The single phase Mn3Ge film was grown at a growth temperature of 150 °C, while the secondary phase was observed above a growth temperature of 250 °C. The Mn3Ge films exhibited ferrimagnetism with a Curie temperature of 334 K. The saturation magnetizations were 255.9 and 313.8 emu/cm3 and the corresponding coercive fields were 453 and 1166 Oe at 10 K for the samples grown at 150 and 300 °C, respectively. The ferrimagnetism was confirmed by the anomalous Hall effect data.

  6. TMR study of GaMnAs/AlGaAs:Be/GaMnAs trilayers

    Science.gov (United States)

    Hagmann, Joseph; Liu, Xinyu; Dobrowolska, Malgorzata; Furdyna, Jacek; Yoo, Taehee; Khym, Sungwon; Lee, Sanghoon

    2011-03-01

    GaMnAs/GaAs:Be/GaMnAs trilayers have recently demonstrated antiferromagnetic (AFM) coupling between the two ferromagnetic (FM) layers, mediated by holes in the spacer layer. In this work, GaMnAs/ Al x Ga 1-x :Be/GaMnAs trilayer samples with varying Al concentrations were fabricated into magnetic tunnel junction (MTJ) devices with range of pillar diameters to measure tunneling magnetoresistance (TMR) under various conditions. SQUID measurements were use to measure the magnetization of the samples, including switching fields for parallel and antiparallel magnetization alignments of the FM layers. TMR was observed in the sample with Al 0.22 Ga 0.78 As:Be spacer, but was massively suppressed in the samples with lower Al content. The presence of holes in the spacer layer is shown to suppress TMR. This illustrates the difference in conditions for TMR and for AFM interlayer coupling. Supported by NSF Grant DMR-1005851 and OISE-1015458.

  7. Thermodynamic Properties of Carbon and Manganese in Mn-C and Mn-Fe-C Melts

    Institute of Scientific and Technical Information of China (English)

    CHEN Er-bao; WANG Shi-jun

    2008-01-01

    Carbon solubility in Mn-Fe melts (xMn=0.083-0.706,xFe=0.034-0.715) was measured experimentally at various temperatures.By thermodynamic derivation and calculation,the relationship between activity coefficient of carbon in infinite dilute solution of manganese in Mn-C system and temperature was obtained.Using Gibbs-Duhem relationship,the experimental results of this study,and experimental data obtained by strict thermodynamic derivation and calculation in references,the relationships between other thermodynamic properties (εCC,εCCC,εCFe,eεCCFe,and εCFeCFe) in Mn-Fe-C system and temperature were obtained.

  8. 77 FR 51101 - Minnesota Disaster #MN-00037

    Science.gov (United States)

    2012-08-23

    ... From the Federal Register Online via the Government Publishing Office SMALL BUSINESS ADMINISTRATION Minnesota Disaster MN-00037 AGENCY: U.S. Small Business Administration. ACTION: Notice. SUMMARY... INFORMATION CONTACT: A. Escobar, Office of Disaster Assistance, U.S. Small Business Administration, 409...

  9. Na Deposition on MnO(100)

    Science.gov (United States)

    Feng, Xu; Cox, David F.

    2016-03-01

    Na deposition on the MnO(100) surface was investigated by temperature programmed desorption (TPD), X-ray photoelectron spectroscopy (XPS) and low energy electron diffraction (LEED). Na TPD and XPS results indicate that adsorbed Na interacts strongly with the MnO substrate to form an irreversibly-adsorbed, oxidic Na compound on the surface for coverages up to 1 monolayer (ML). This strongly-bound Na diffuses into the MnO subsurface and bulk at elevated temperatures above 500 K. For Na coverages above 1 ML, metallic Na is present and desorbs from the surface below 500 K. The deposition of Na on MnO(100) follows a Stranski-Krastanov (SK) growth mode, with the formation of metallic Na islands following completion of the first Na monolayer. After Na deposition, the surface exhibits a diffuse (1 × 1) LEED pattern, suggesting the formation of disordered Na overlayers. After heating to 1000 K, the surface presents a (2 × 2) LEED pattern indicating that a surface reconstruction is induced by the diffusion of Na into the near surface region. CO2 can be used as a probe molecule in TPD to distinguish between metallic Na islands and oxidic Na in the first ML, and to indicate when Na that is still observable by XPS goes subsurface.

  10. 78 FR 28939 - Minnesota Disaster #MN-00049

    Science.gov (United States)

    2013-05-16

    ... Counties: Cottonwood, Jackson, Murray, Nobles, Rock. The Interest Rates are: Percent For Physical Damage... ADMINISTRATION Minnesota Disaster MN-00049 AGENCY: U.S. Small Business Administration. ACTION: Notice. SUMMARY... State of Minnesota (FEMA- 4113-DR), dated 05/03/2013. Incident: Severe Winter Storm. Incident Period:...

  11. XPS and EELS characterization of Mn2SiO4, MnSiO3 and MnAl2O4

    Science.gov (United States)

    Grosvenor, A. P.; Bellhouse, E. M.; Korinek, A.; Bugnet, M.; McDermid, J. R.

    2016-08-01

    X-ray Photoelectron Spectroscopy (XPS) and Electron Energy Loss Spectroscopy (EELS) are strong candidate techniques for characterizing steel surfaces and substrate-coating interfaces when investigating the selective oxidation and reactive wetting of advanced high strength steels (AHSS) during the continuous galvanizing process. However, unambiguous identification of ternary oxides such as Mn2SiO4, MnSiO3, and MnAl2O4 by XPS or EELS, which can play a significant role in substrate reactive wetting, is difficult due to the lack of fully characterized standards in the literature. To resolve this issue, samples of Mn2SiO4, MnSiO3 and MnAl2O4 were synthesized and characterized by XPS and EELS. The unique features of the XPS and EELS spectra for the Mn2SiO4, MnSiO3 and MnAl2O4 standards were successfully derived, thereby allowing investigators to fully differentiate and identify these oxides at the surface and subsurface of Mn, Si and Al alloyed AHSS using these techniques.

  12. Frustrated pyrochlore oxides, Y2Mn2O7, Ho2Mn2O7, and Yb2Mn2O7: Bulk magnetism and magnetic microstructure

    DEFF Research Database (Denmark)

    Greedan, J.E.; Raju, N.P.; Maignan, A.

    1996-01-01

    The bulk magnetic properties, including de and ac susceptibilities and heat capacity, of the pyrochlore oxides Ho2Mn2O7 and Yb2Mn2O7 are reported and compared with those of the previously studied Y2Mn2O7. In the latter case the magnetic Mn4+ ions occupy the 16c sites in Fd3m which define...... a potentially frustrated three-dimensional array of corner sharing tetrahedra. For Ho2Mn2O7 and Yb2Mn2O7 magnetic rare earth ions occupy the 16d sites, as shown by powder neutron diffraction, which are topologically equivalent to the 16c sites but displaced by a vector (1/2 1/2 1/2). Ho2Mn2O7 and Yb2Mn2O7....... Surprisingly, neutron diffraction data for both Ho2Mn2O7 and Yb2Mn2O7 show resolution limited reflections of magnetic origin in contrast to the heat capacity results. The resolution of the neutron diffraction data places a minimum on the correlation length of 100 Angstrom. Small angle neutron scattering data...

  13. Synthesis of an S T = 7 [Mn 3 ] Mixed-Valence Complex Based on 1,3-Propanediol Ligand Derivatives and Its One-Dimensional Assemblies

    KAUST Repository

    Huang, Jian

    2013-10-07

    Controlled organization of high-spin complexes and single-molecule magnets is a great challenge in molecular magnetism in order to study the effect of the intercomplex magnetic interactions on the intrinsic properties of a given magnetic object. In this work, a new ST = 7 trinuclear mixed-valence Mn complex, [MnIIIMnII 2(LA) 2(Br)4(CH3OH)6] ·Br· (CH3OH)1.5·(H2O)0.5 (1), is reported using a pyridinium-functionalized 1,3-propanediol ligand (H 2LABr = 1-(3-bromo-2,2-bis(hydroxymethyl)propyl)pyridinium bromide). Using azido anions as bridging ligands and different pyridinium-functionalized 1,3-propanediol ligands (H2LBBr = 1-(3-bromo-2,2-bis(hydroxymethyl)propyl)-4-picolinium bromide; H 2LCBr = 1-(3-bromo-2,2-bis(hydroxymethyl)propyl)-3,5- lutidinium bromide), the linear [MnIIIMnII 2L2X4]+ building block has been assembled into one-dimensional coordination networks: [MnIIIMn II 2(LA)2(Br)4(CH 3OH)4(N3)]·((C2H 5)2O)1.25 (2∞), [MnIIIMn II 2(LB)2(Br)4(C 2H5OH)(CH3OH)(H2O) 2(N3)]·(H2O)0.25 (3∞), and [MnIIIMnII 2(LC) 2(Cl)3.8(Br)0.2(C2H 5OH)3(CH3OH)(N3)] (4∞). The syntheses, characterization, crystal structures, and magnetic properties of these new [Mn3]-based materials are reported. © 2013 American Chemical Society.

  14. Catalytic Oxidation of NO over MnOx-CeO₂ and MnOx-TiO₂ Catalysts.

    Science.gov (United States)

    Zeng, Xiaolan; Huo, Xiaoyue; Zhu, Tianle; Hong, Xiaowei; Sun, Ye

    2016-11-14

    A series of MnOx-CeO₂ and MnOx-TiO₂ catalysts were prepared by a homogeneous precipitation method and their catalytic activities for the NO oxidation in the absence or presence of SO₂ were evaluated. Results show that the optimal molar ratio of Mn/Ce and Mn/Ti are 0.7 and 0.5, respectively. The MnOx-CeO₂ catalyst exhibits higher catalytic activity and better resistance to SO₂ poisoning than the MnOx-TiO₂ catalyst. On the basis of Brunauer-Emmett-Teller (BET), X-ray diffraction (XRD), and scanning transmission electron microscope with mapping (STEM-mapping) analyses, it is seen that the MnOx-CeO₂ catalyst possesses higher BET surface area and better dispersion of MnOx over the catalyst than MnOx-TiO₂ catalyst. X-ray photoelectron spectroscopy (XPS) measurements reveal that MnOx-CeO₂ catalyst provides the abundance of Mn(3+) and more surface adsorbed oxygen, and SO₂ might be preferentially adsorbed to the surface of CeO₂ to form sulfate species, which provides a protection of MnOx active sites from being poisoned. In contrast, MnOx active sites over the MnOx-TiO₂ catalyst are easily and quickly sulfated, leading to rapid deactivation of the catalyst for NO oxidation. Furthermore, temperature programmed desorption with NO and O₂ (NO + O₂-TPD) and in situ diffuse reflectance infrared transform spectroscopy (in situ DRIFTS) characterizations results show that the MnOx-CeO₂ catalyst displays much stronger ability to adsorb NOx than the MnOx-TiO₂ catalyst, especially after SO₂ poisoning.

  15. Preparation of Mn 2O 3 and Mn 3O 4 nanofibers via an electrospinning technique

    Science.gov (United States)

    Shao, Changlu; Guan, Hongyu; Liu, Yichun; Li, Xiliang; Yang, Xinghua

    2004-07-01

    Thin PVA/manganese acetate composite fibers were prepared by using sol-gel processing and electrospinning technique. After calcinations of the above precursor fibers, Mn 2O 3 and Mn 3O 4 nanofibers with a diameter of 50-200 nm could be successfully obtained. The fibers were characterized by TG-DTA, Scanning electron microscopy, FT-IR, WAXD, respectively. The results showed that the crystalline phase and morphology of nanofibers were largely influenced by the calcination temperature.

  16. CaMn2Al10 : Itinerant Mn magnetism on the verge of magnetic order

    Science.gov (United States)

    Steinke, L.; Simonson, J. W.; Yin, W.-G.; Smith, G. J.; Kistner-Morris, J. J.; Zellman, S.; Puri, A.; Aronson, M. C.

    2015-07-01

    We report the discovery of CaMn2Al10 , a metal with strong magnetic anisotropy and moderate electronic correlations. Magnetization measurements find a Curie-Weiss moment of 0.83 μB/Mn , significantly reduced from the Hund's rule value, and the magnetic entropy obtained from specific heat measurements is correspondingly small, only ≈9 % of R ln 2 . These results imply that the Mn magnetism is highly itinerant, a conclusion supported by density functional theory calculations that find strong Mn-Al hybridization. Consistent with the layered nature of the crystal structure, the magnetic susceptibility χ is anisotropic below 20 K, with a maximum ratio of χ[010 ]/χ[001 ]≈3.5 . A strong power-law divergence χ (T ) ˜T-1.2 below 20 K implies incipient ferromagnetic order with a low Curie temperature TC<2 K . Our experiments indicate that CaMn2Al10 is a rare example of a system where the weak and itinerant Mn-based magnetism is poised on the verge of order.

  17. Suppression of superconductivity in Nb by IrMn in IrMn/Nb bilayers

    KAUST Repository

    Wu, B. L.

    2013-10-10

    Effect of antiferromagnet on superconductivity has been investigated in IrMn/Nb bilayers. Significant suppression of both transition temperature (Tc) and lower critical field (Hc1) of Nb is found in IrMn/Nb bilayers as compared to a single layer Nb of same thickness; the suppression effect is even stronger than that of a ferromagnet in NiFe/Nb bilayers. The addition of an insulating MgO layer at the IrMn-Nb interface nearly restores Tc to that of the single layer Nb, but Hc1 still remains suppressed. These results suggest that, in addition to proximity effect and magnetic impurity scattering, magnetostatic interaction also plays a role in suppressing superconductivity of Nb in IrMn/Nb bilayers. In addition to reduced Tc and Hc1, the IrMn layer also induces broadening in the transition temperature of Nb, which can be accounted for by a finite distribution of stray field from IrMn.

  18. On Reductive Monoid Mn(K)%既约么半群Mn(K)

    Institute of Scientific and Technical Information of China (English)

    曹佑安; 李卓

    2004-01-01

    主要介绍Renner得到的重要结果代数么半群的Bruhat分解.这一结果是Putcha-Renner理论系统发展的一个里程碑.当保留首先被Renner发现时,它甚至对Mn(K)也是新的.该文利用线性代数知识对Mn(K)的Bruhat分解给出一个初等描述,并且给出所有秩2,半单秩1的既约么半群.作者用初等方法证明了Mn(K)的Bruhat分解,最后介绍了与Renner么半群密切相关的Hecke代数.%This article serves as an introduction to one of the amazing results established by Renner which is the analogue of the Bruhat decomposition of algebraic monoids. This result is a milestone in the system development of Putcha-Renner theory. It was even new to Mn(K) when it was first found by Renner. In this article we give an elementary description to Mn(K) using linear algebra knowledge and list all rank two, semisimple rank one reductive monoids. We prove the analogue of Bruhat decomposition for Mn(K) in an elementary way. Finally we pose some open problems on Hecke algebras related to Renner monoids.

  19. Reversing ferroelectric polarization in multiferroic DyMn2O5 by nonmagnetic Al substitution of Mn

    Science.gov (United States)

    Zhao, Z. Y.; Liu, M. F.; Li, X.; Wang, J. X.; Yan, Z. B.; Wang, K. F.; Liu, J.-M.

    2014-08-01

    The multiferroic RMn2O5 family, where R is rare-earth ion or Y, exhibits rich physics of multiferroicity which has not yet well understood. DyMn2O5 is a representative member of this family. The ferroelectric polarization of DyMn2O5 is claimed to be magnetically relevant and have more than one component. Therefore, the polarization reversal upon the sequent magnetic transitions is expected. We investigate the evolution of the ferroelectric polarization upon a partial substitution of Mn3+ by nonmagnetic Al3+ in order to tailor the Mn3+-Mn4+ interactions and then to modulate the polarization in DyMn2-x/2Alx/2O5. It is revealed that the polarization can be successfully reversed by Al-substitution via substantially suppressing the Mn3+-Mn4+ interactions, while the Dy3+-Mn4+ interactions can sustain against the substitution until a level as high as x = 0.2. In addition, the independent Dy spin ordering is shifted remarkably down to an extremely low temperature due to the Al3+ substitution. The present work unveils the possibility of tailoring the Mn3+-Mn4+ and Dy3+-Mn4+ interactions independently, and thus reversing the ferroelectric polarization.

  20. Rational serendipity: "undirected" synthesis of a large {MnCu} complex from pre-formed Mn(II) building blocks.

    Science.gov (United States)

    Frost, Jamie M; Kettles, Fraser J; Wilson, Claire; Murrie, Mark

    2016-11-15

    Use of an aminopolyalcohol-based Mn(II) complex in solvothermal Cu(II) chemistry leads to a rare example of a high nuclearity heterometallic {MnCu} system, in which four Cu(II)(H1Edte) units trap an inner {MnCu(II)} oxide core.

  1. Dissolved Mn Speciation and Ligand Characteristics in a Coastal Waterway

    Science.gov (United States)

    Oldham, V.; Jensen, L.; Luther, G. W., III

    2014-12-01

    Soluble manganese speciation (Mn(II) and Mn(III); 0.2 μm filtered) was measured along a salinity gradient in the Broadkill River, a coastal waterway bordered by wetlands and salt marshes in Delaware. We modified an established method of porphyrin (T-4(CP)P) addition, by incorporating a heating step and coupling a 100-cm cell to a UV/Vis detector, to achieve a 4.0 nM sample DL. Surface waters were collected from June to August, 2014 and total dissolved Mn (0.23 - 1.92 μM) first increased then decreased along the salinity gradient (31 ppt to freshwater). However, Mn speciation was highly variable; Mn(III) made up 0-49 % of the total dissolved Mn, where the highest Mn(III) values occurred at sites with high salt-marsh runoff. Mn(III) was not recoverable without the addition of a strong reducing agent, indicating that little or no weak ligand was present, and that a strong ligand was responsible for complexing Mn(III). An assessment of potential strong ligand character was made by precipitating humic matter, by acidifying subsamples to pHyellow color. Upon the addition of 500 μM desferrioxamine-B (DFOB) to the same sample, a peak at 310 nm appeared, indicating the formation of Mn(III)-DFOB. In acidified samples, the Mn(III)-pyrophosphate peak did not change. Humic matter, therefore, may be acting as an Mn(III) binding ligand, outcompeting pyrophosphate for Mn(III), however this natural ligand is outcompeted by a large excess of DFOB. The humic matter and increased Mn likely come from the salt marsh runoff during tidal exchange, and we observed that as salinity increased, the amount of humic binding decreased. These results present the first Mn speciation measurements along a salinity gradient in oxygenated waters.

  2. Scale-bridging analysis on deformation behavior of high-nitrogen austenitic steels.

    Science.gov (United States)

    Lee, Tae-Ho; Ha, Heon-Young; Hwang, Byoungchul; Kim, Sung-Joon; Shin, Eunjoo; Lee, Jong Wook

    2013-08-01

    Scale-bridging analysis on deformation behavior of high-nitrogen austenitic Fe-18Cr-10Mn-(0.39 and 0.69)N steels was performed by neutron diffraction, electron backscattered diffraction (EBSD), and transmission electron microscopy (TEM). Two important modes of deformation were identified depending on the nitrogen content: deformation twinning in the 0.69 N alloy and strain-induced martensitic transformation in the 0.39 N alloy. The phase fraction and deformation faulting probabilities were evaluated based on analyses of peak shift and asymmetry of neutron diffraction profiles. Semi in situ EBSD measurement was performed to investigate the orientation dependence of deformation microstructure and it showed that the variants of ε martensite as well as twin showed strong orientation dependence with respect to tensile axis. TEM observation showed that deformation twin with a {111} mathematical left angle bracket 112 mathematical right angle bracket crystallographic component was predominant in the 0.69 N alloy whereas two types of strain-induced martensites (ε and α' martensites) were observed in the 0.39 N alloy. It can be concluded that scale-bridging analysis using neutron diffraction, EBSD, and TEM can yield a comprehensive understanding of the deformation mechanism of nitrogen-alloyed austenitic steels.

  3. Dynamic analysis of rail transit elevated bridge with ladder track

    Institute of Scientific and Technical Information of China (English)

    He XIA; Yushu DENG; Yongwei ZOU; Guido DE ROECK; Geert DEGRANDE

    2009-01-01

    In this paper, a dynamic analysis model of an elevated bridge with ladder tracks under moving train load is established. The whole process of a train running through an elevated bridge at different speeds is simulated.The dynamic responses of the elevated bridge with ladder track and the running safety and comfort index of train vehicles are evaluated. Compared with the dynamic responses of an elevated bridge with ordinary non-ballasted slab track, the ladder track's effect on reducing the vibration of an elevated bridge is analyzed. The analysis results show that the ladder track has good vibration reduction characteristics as compared to ordinary non-ballasted track.

  4. Seismic Passive Control of Cable-Stayed Bridges

    Directory of Open Access Journals (Sweden)

    Hosam-Eddin M. Ali

    1995-01-01

    Full Text Available A three-dimensional modeling procedure is proposed for cable-stayed bridges with rubber, steel, and lead energy dissipation devices. The passive control technique is investigated by considering the response of bridge models with and without energy dissipation devices. The impact of various design parameters on the seismic response of current and future bridge designs is studied. Appropriate locations and properties of the passive devices can achieve better performance for cable-stayed bridges by balancing the significant reduction in earthquake-induced forces against tolerable displacements. Proper design of passive systems can help provide solutions for retro-fitting some existing bridges.

  5. An effective Handling of Thermal Bridges in the EPBD Context

    DEFF Research Database (Denmark)

    Erhorn, Hans; Erhorn-Kluttig, Heike; Thomsen, Kirsten Engelund;

    The ASIEPI project has collected and analysed international and national information from up to 17 EU Member States plus Norway on the topic of thermal bridges in buildings. Seven different aspects have been addressed, ranging from EU Member States’ approaches in regulations to quantification...... of thermal bridge effects to the energy balance, used software tools and thermal bridge atlases, available good practice guidance and promotion of good building practice to the execution quality and advanced thermal bridge driven technical developments. This report presents the gathered knowledge, draws...... junctions and other building parts with possible thermal bridges....

  6. Suspension Bridge Flutter for Girder with Separate Control Flaps

    DEFF Research Database (Denmark)

    Huynh, T.; Thoft-Christensen, Palle

    Active vibration control of long span suspension bridge flutter using separated control flaps (SFSC) has shown to increase effectively the critical wind speed of bridges. In this paper, an SFSC calculation based on modal equations of the vertical and torsional motions of the bridge girder including...... the flaps is presented. The length of the flaps attached to the girder, the flap configuration and the flap rotational angles are parameters used to increase the critical wind speed of the bridge. To illustrate the theory a numerical example is shown for a suspension bridge of 1000m+2500m+1000m span based...

  7. Dynamics and statics of nonaxisymmetric and symmetric liquid bridges

    Science.gov (United States)

    Alexander, J. Iwan D.; Resnick, Andrew H.; Kaukler, William F.; Zhang, Yiqiang

    1994-01-01

    This program of theoretical and experimental ground-based research focuses on the understanding of the dynamics and stability limits of nonaxisymmetric and symmetric liquid bridges. There are three basic objectives: First, to determine the stability limits of nonaxisymmetric liquid bridges held between non-coaxial parallel disks, Second, to examine the dynamics of nonaxisymmetric bridges and nonaxisymmetric oscillations of initially axisymmetric bridges. The third objective is to experimentally investigate the vibration sensitivity of liquid bridges under terrestrial and low gravity conditions. Some of these experiments will require a low gravity environment and the ground-based research will culminate in a definitive flight experiment.

  8. Magnetic anisotropy of [Mo(CN)7]4- anions and fragments of cyano-bridged magnetic networks.

    Science.gov (United States)

    Chibotaru, Liviu F; Hendrickx, Marc F A; Clima, Sergiu; Larionova, Joulia; Ceulemans, Arnout

    2005-08-18

    Quantum chemistry calculations of CASSCF/CASPT2 level together with ligand field analysis are used for the investigation of magnetic anisotropy of [Mo(CN)7]4- complexes. We have considered three types of heptacyano environments: two ideal geometries, a pentagonal bipyramid and a capped trigonal prism, and the heptacyanomolybdate fragment of the cyano-bridged magnetic network K2[Mn(H2O)2]3[Mo(CN)7]2.6H2O. At all geometries the first excited Kramers doublet is found remarkably close to the ground one due to a small orbital energy gap in the ligand field spectrum, which ranges between a maximal value in the capped trigonal prism (800 cm(-1)) and zero in the pentagonal bipyramid. The small value of this gap explains (i) the axial form of the g tensor and (ii) the strong magnetic anisotropy even in strongly distorted complexes. Comparison with available experimental data for the g tensor of the mononuclear precursors reveals good agreement with the present calculations for the capped trigonal prismatic complex and a significant discrepancy for the pentagonal bipyramidal one. The calculations for the heptacyanomolybdate fragment of K2[Mn(H2O)2]3[Mo(CN)7]2.6H2O give g(perpendicular)/g(parallel) approximately 0.5 and the orientation of the local anisotropy axis close to the symmetry axis of an idealized pentagonal bipyramid. These findings are expected to be important for the understanding of the magnetism of anisotropic Mo(III)-Mn(II) cyano-bridged networks based on the [Mo(CN)7]4- building block.

  9. High pressure effects on a trimetallic Mn(II/III) SMM.

    Science.gov (United States)

    Prescimone, Alessandro; Sanchez-Benitez, Javier; Kamenev, Konstantin V; Moggach, Stephen A; Lennie, Alistair R; Warren, John E; Murrie, Mark; Parsons, Simon; Brechin, Euan K

    2009-09-28

    A combined study of the high pressure crystallography and high pressure magnetism of the complex [Mn3(Hcht)2(bpy)4](ClO4)3.Et2O.2MeCN (1.Et2O.2MeCN) (H3cht is cis,cis-1,3,5-cyclohexanetriol) is presented in an attempt to observe and correlate pressure induced changes in its structural and physical properties. At 0.16 GPa the complex 1.Et2O.2MeCN loses all associated solvent in the crystal lattice, becoming 1. At higher pressures structural distortions occur changing the distances between the metal centres and the bridging oxygen atoms making the magnetic exchange between the manganese ions weaker. No significant variations are observed in the Jahn-Teller axis of the only Mn(III) present in the structure. High pressure dc chiMT plots display a gradual decrease in both the low temperature value and slope. Simulations show a decrease in J with increasing pressure although the ground state is preserved. Magnetisation data do not show any change in |D|.

  10. A Review of Indirect Bridge Monitoring Using Passing Vehicles

    Directory of Open Access Journals (Sweden)

    Abdollah Malekjafarian

    2015-01-01

    Full Text Available Indirect bridge monitoring methods, using the responses measured from vehicles passing over bridges, are under development for about a decade. A major advantage of these methods is that they use sensors mounted on the vehicle, no sensors or data acquisition system needs to be installed on the bridge. Most of the proposed methods are based on the identification of dynamic characteristics of the bridge from responses measured on the vehicle, such as natural frequency, mode shapes, and damping. In addition, some of the methods seek to directly detect bridge damage based on the interaction between the vehicle and bridge. This paper presents a critical review of indirect methods for bridge monitoring and provides discussion and recommendations on the challenges to be overcome for successful implementation in practice.

  11. Polymeric salt bridges for conducting electric current in microfluidic devices

    Science.gov (United States)

    Shepodd, Timothy J.; Tichenor, Mark S.; Artau, Alexander

    2009-11-17

    A "cast-in-place" monolithic microporous polymer salt bridge for conducting electrical current in microfluidic devices, and methods for manufacture thereof is disclosed. Polymeric salt bridges are formed in place in capillaries or microchannels. Formulations are prepared with monomer, suitable cross-linkers, solvent, and a thermal or radiation responsive initiator. The formulation is placed in a desired location and then suitable radiation such as UV light is used to polymerize the salt bridge within a desired structural location. Embodiments are provided wherein the polymeric salt bridges have sufficient porosity to allow ionic migration without bulk flow of solvents therethrough. The salt bridges form barriers that seal against fluid pressures in excess of 5000 pounds per square inch. The salt bridges can be formulated for carriage of suitable amperage at a desired voltage, and thus microfluidic devices using such salt bridges can be specifically constructed to meet selected analytical requirements.

  12. Evaluating the life cycle environmental impact of short span bridges

    DEFF Research Database (Denmark)

    Du, Guangli; Pettersson, Lars; Karoumi, Raid

    2016-01-01

    Bridge infrastructure consumes large amount of energy and raw materials, leading to considerable environmental burdens. The traditional infrastructure construction prioritizes its technical and economic viability. In recent years, the society devotes an ever-increased attention to the environmental...... impact of the construction sector. Life cycle assessment (LCA) is a systematic method for assessing the environmental impact of products and systems, but its application in bridges is scarce. In Swede, most of the bridges are short spans and the type of concrete slab-frame bridge (CFB) accounts...... for a large share. Soil steel composite bridge (SSCB) is a functional equivalent solution for CFB. In order to mitigate the environmental burdens of short span bridges, this paper performed a comparative LCA study between these two types of bridge. The results indicate that the initial material consumption...

  13. Noncollinear magnetism of Mn nanowires on Fe(1 1 0)

    Science.gov (United States)

    Igarashi, R. N.; Miranda, I. P.; Eleno, L. T. F.; Klautau, A. B.; Petrilli, H. M.

    2016-08-01

    Magnetic properties of Mn linear nanochains on a bcc Fe(1 1 0) surface have been studied using the first-principles real space-linear muffin-tin orbital atomic sphere approximation (RS-LMTO-ASA) method. We have considered up to nine Mn atoms deposited on bcc Fe(1 1 0). Our ab initio calculations reveal the competition between the antiferromagnetic Mn-Mn and Mn-Fe couplings, presenting a behavior which is very different from Mn nanowires on Fe(0 0 1), as shown in a previous publication. Due to this competition and non-negligible Dzyaloshinskii-Moriya interaction, noncollinear magnetic structures are stabilized as ground states for the Mn nanochains on Fe(1 1 0).

  14. Effect of the Mn Oxidation State on Single-Molecule-Magnet Properties: Mn(III) vs Mn(IV) in Biologically Inspired DyMn3O4 Cubanes.

    Science.gov (United States)

    Lin, Po-Heng; Tsui, Emily Y; Habib, Fatemah; Murugesu, Muralee; Agapie, Theodor

    2016-06-20

    Inspired by the ferromagnetic coupling in the cubane model CaMn(IV)3O4 of the oxygen-evolving complex of photosystem II, 3d-4f mixed-metal DyMn3O4 clusters were prepared for investigation of the magnetic properties. For comparison, YMn(IV)3O4 and YMn(IV)2Mn(III)O4 clusters were investigated as well and showed ferromagnetic interactions, like the calcium analogue. DyMn(IV)3O4 displays single-molecule-magnet properties, while the one-electron-reduced species (DyMn(IV)2Mn(III)O4) does not, despite the presence of a Mn(III) center with higher spin and single-ion anisotropy.

  15. Martensitic Transformation in Ni-Mn-Sn-Co Heusler Alloys

    Directory of Open Access Journals (Sweden)

    Alexandre Deltell

    2015-04-01

    Full Text Available Thermal and structural austenite to martensite reversible transition was studied in melt spun ribbons of Ni50Mn40Sn5Co5, Ni50Mn37.5Sn7.5Co5 and Ni50Mn35Sn10Co5 (at. % alloys. Analysis of X-ray diffraction patterns confirms that all alloys have martensitic structure at room temperature: four layered orthorhombic 4O for Ni50Mn40Sn5Co5, four layered orthorhombic 4O and seven-layered monoclinic 14M for Ni50Mn37.5Sn7.5Co5 and seven-layered monoclinic 14M for Ni50Mn35Sn5Co5. Analysis of differential scanning calorimetry scans shows that higher enthalpy and entropy changes are obtained for alloy Ni50Mn37.5Sn7.5Co5, whereas transition temperatures increases as increasing valence electron density.

  16. Online Bridge Crack Monitoring with Smart Film

    Directory of Open Access Journals (Sweden)

    Benniu Zhang

    2013-01-01

    Full Text Available Smart film crack monitoring method, which can be used for detecting initiation, length, width, shape, location, and propagation of cracks on real bridges, is proposed. Firstly, the fabrication of the smart film is developed. Then the feasibility of the method is analyzed and verified by the mechanical sensing character of the smart film under the two conditions of normal strain and crack initiation. Meanwhile, the coupling interference between parallel enameled wires of the smart film is discussed, and then low-frequency detecting signal and the custom communication protocol are used to decrease interference. On this basis, crack monitoring system with smart film is designed, where the collected crack data is sent to the remote monitoring center and the cracks are simulated and recurred. Finally, the monitoring system is applied to six bridges, and the effects are discussed.

  17. Fatigue-Prone Details in Steel Bridges

    Directory of Open Access Journals (Sweden)

    Mohsen Heshmati

    2012-11-01

    Full Text Available This paper reviews the results of a comprehensive investigation including more than 100 fatigue damage cases, reported for steel and composite bridges. The damage cases are categorized according to types of detail. The mechanisms behind fatigue damage in each category are identified and studied. It was found that more than 90% of all reported damage cases are of deformation-induced type and generated by some kind of unintentional or otherwise overlooked interaction between different load-carrying members or systems in the bridge. Poor detailing, with unstiffened gaps and abrupt changes in stiffness at the connections between different members were also found to contribute to fatigue cracking in many details.

  18. Accelerated aging of polymer composite bridge materials

    Science.gov (United States)

    Carlson, Nancy M.; Blackwood, Larry G.; Torres, Lucinda L.; Rodriguez, Julio G.; Yoder, Timothy S.

    1999-05-01

    Accelerated aging research on samples of composite materials and candidate UV protective coatings is determining the effects of six environmental factors on material durability. Candidate fastener materials are being evaluated to determine corrosion rates and crevice corrosion effects at load-bearing joints. This work supports field testing of a 30-ft long, 18-ft wide polymer matrix composite (PMC) bridge at the Idaho National Engineering and Environmental Laboratory. Durability results and sensor data form test with live loads provide information required for determining the cost/benefit measures to use in life-cycle planning, determining a maintenance strategy, establishing applicable inspection techniques, and establishing guidelines, standards and acceptance criteria for PMC bridges for use in the transportation infrastructure.

  19. Skin bridging secondary to ingrown toenail.

    Science.gov (United States)

    Dadaci, Mehmet; Ince, Bilsev; Altuntas, Zeynep; Kamburoglu, Haldun Onuralp; Bitik, Ozan

    2014-01-01

    Ingrown toenails are painful conditions that especially affect young people and may become chronic if not treated. We describe a case of chronically inflamed ingrown toenail left untreated for three years. In the physical examination, skin bridging and epithelialization was observed in midline secondary to soft tissue hypertrophy of the lateral nail matrixes. Epithelized fibrous tissue was cut across the lateral nail matrix and left for secondary healing. Partial matrixectomy was applied and the remnants were cauterized in compliance with the Winograd procedure after removal of the nail. Our case is an advanced condition which is the second report in the literature. Skin bridging secondary to excess soft tissue hypertrophy can be observed in untreated bilateral Heinfert or Frost stage 3 ingrown nails. This rare case can be classified as advanced stage 3 disease or stage 4.

  20. Accelerated Aging of Polymer Composite Bridge Materials

    Energy Technology Data Exchange (ETDEWEB)

    Carlson, Nancy Margaret; Blackwood, Larry Gene; Torres, Lucinda Laine; Rodriguez, Julio Gallardo; Yoder, Timothy Scott

    1999-03-01

    Accelerated aging research on samples of composite material and candidate ultraviolet (UV) protective coatings is determining the effects of six environmental factors on material durability. Candidate fastener materials are being evaluated to determine corrosion rates and crevice corrosion effects at load-bearing joints. This work supports field testing of a 30-ft long, 18-ft wide polymer matrix composite (PMC) bridge at the Idaho National Engineering and Environmental Laboratory (INEEL). Durability results and sensor data from tests with live loads provide information required for determining the cost/benefit measures to use in life-cycle planning, determining a maintenance strategy, establishing applicable inspection techniques, and establishing guidelines, standards, and acceptance criteria for PMC bridges for use in the transportation infrastructure.

  1. A liquid bridge connecting moving porous surfaces

    Science.gov (United States)

    Gharib, Morteza; Gat, Amir; Navaz, Homayun

    2011-11-01

    We study the coupled problem of a liquid bridge connecting two porous surfaces where the gap between the surfaces is an externally controlled function of time. The relative motion between the surfaces affects the geometry and the pressure distribution of the liquid bridge, thus influencing the diffusion speed and penetration topology within the porous material. Utilizing the lubrication approximation and Darcy's phenomenological law we obtain a relation between the diffusion into the porous surface and the relative motion between the surfaces. A scheme to control the diffusion topology is presented and illustrated for the case of conical penetration topology with an arbitrary cone opening angle. Analytic expressions describing the penetration topology for the case of constant speed of the surfaces and the relative motion between the surfaces required to create a conical penetration topology are obtained and compared to experimental and numerical data. This project was supported by the Defense Threat Reduction Agency (DTRA), Award Number: 330233-A.

  2. Molecules at the Quantum-Classical Nanoparticle Interface: Giant Mn70 Single-Molecule Magnets of ∼4 nm Diameter.

    Science.gov (United States)

    Vinslava, Alina; Tasiopoulos, Anastasios J; Wernsdorfer, Wolfgang; Abboud, Khalil A; Christou, George

    2016-04-01

    Two Mn70 torus-like molecules have been obtained from the alcoholysis in EtOH and 2-ClC2H4OH of [Mn12O12(O2CMe)16(H2O)4]·4H2O·2MeCO2H (1) in the presence of NBu(n)4MnO4 and an excess of MeCO2H. The reaction in EtOH afforded [Mn70O60(O2CMe)70(OEt)20(EtOH)16(H2O)22] (2), whereas the reaction in ClC2H4OH gave [Mn70O60(O2CMe)70(OC2H4Cl)20(ClC2H4OH)18(H2O)22] (3). The complexes are nearly isostructural, each possessing a Mn70 torus structure consisting of alternating near-linear [Mn3(μ3-O)4] and cubic [Mn4(μ3-O)2(μ3-OR)2] (R = OEt, 2; R = OC2H4Cl, 3) subunits, linked together via syn,syn-μ-bridging MeCO2(-) and μ3-bridging O(2-) groups. 2 and 3 have an overall diameter of ∼4 nm and crystallize as highly ordered supramolecular nanotubes. Alternating current (ac) magnetic susceptibility measurements, performed on microcrystalline samples in the 1.8-10 K range and a 3.5 G ac field with oscillation frequencies in the 5-1500 Hz range, revealed frequency-dependent out-of-phase signals below ∼2.4 K for both molecules indicative of the slow magnetization relaxation of single-molecule magnets (SMMs). Single-crystal, magnetization vs field studies on both complexes revealed hysteresis loops below 1.5 K, thus confirming 2 and 3 to be new SMMs. The hysteresis loops do not show the steps that are characteristic of quantum tunneling of magnetization (QTM). However, low-temperature studies revealed temperature-independent relaxation rates below ∼0.2 K for both compounds, the signature of ground state QTM. Fitting of relaxation data to the Arrhenius equation gave effective barriers for magnetization reversal (Ueff) of 23 and 18 K for 2 and 3, respectively. Because the Mn70 molecule is close to the classical limit, it was also studied using a method based on the Néel-Brown model of thermally activated magnetization reversal in a classical single-domain magnetic nanoparticle. The field and sweep-rate dependence of the coercive field was investigated and yielded the energy

  3. Impact Coefficient Analysis of Long-Span Railway Cable-Stayed Bridge Based on Coupled Vehicle-Bridge Vibration

    OpenAIRE

    Yongle Li; Shifu Dong; Yulong Bao; Kejian Chen; Shizhong Qiang

    2015-01-01

    Compared with medium and small span bridges, very limited attention has been paid on the research of the impact coefficient of long-span railway bridges. To estimate the impact effects of long-span railway bridges subjected to moving vehicles, a real long-span railway cable-stayed bridge is regarded as the research object in this study, and a coupled model of vehicle-bridge system is established. The track irregularities are taken as the system excitation and the dynamic responses of the vehi...

  4. Magnetocaloric effect in M-pyrazole-[Nb(CN)(8)] (M = Ni, Mn) molecular compounds.

    Science.gov (United States)

    Fitta, Magdalena; Bałanda, Maria; Mihalik, Marian; Pełka, Robert; Pinkowicz, Dawid; Sieklucka, Barbara; Zentkova, Maria

    2012-12-19

    We report a study of magnetocaloric effect (MCE) in cyanido-bridged {[M(II)(pyrazole)(4)](2)[Nb(IV)(CN)(8)]·4H(2)O}(n) molecular compounds where M = Ni, Mn, pyrazole = C(3)H(4)N(2). The substances show a sharp phase transition to a long range magnetically ordered state, with ferromagnetic coupling between M and Nb sublattices in the case of the Ni-based sample 1 (T(c) = 13.4 K) and ferrimagnetic coupling for the Mn-based sample 2 (T(c) = 23.8 K). The magnetic entropy change ΔS due to applied field change ΔH as a function of temperature was determined by the magnetization and heat capacity measurements. The maximum value of ΔS at μ(0)ΔH = 5 T is 6.1 J mol(-1) K(-1) (5.9 J kg(-1) K(-1)) for 1 at T = 14 K and 6.7 J mol(-1) K(-1) (6.5 J kg(-1) K(-1)) for 2 at T = 25 K. MCE data at different applied fields have been presented as one universal curve, which confirms magnetic transitions in 1 and 2 to be of second order. The temperature dependences of the n exponent characterizing the dependence of ΔS on ΔH have been obtained. The n(T(c)) values, consistent with the shape of the magnetization curves, pointed to the 3D Heisenberg behaviour for 2 and some anisotropy, probably of the XY type, for 1. The (H/T(c))(2/3) dependence of the maximum entropy change has been tested in the ferrimagnetic Mn(2)-L-[Nb(CN)(8)] (L = C(3)H(4)N(2), C(4)H(4)N(2)) series.

  5. Skin bridging secondary to ingrown toenail

    OpenAIRE

    Dadaci, Mehmet; Ince, Bilsev; Altuntas, Zeynep; Kamburoglu, Haldun Onuralp; Bitik, Ozan

    2014-01-01

    Ingrown toenails are painful conditions that especially affect young people and may become chronic if not treated. We describe a case of chronically inflamed ingrown toenail left untreated for three years. In the physical examination, skin bridging and epithelialization was observed in midline secondary to soft tissue hypertrophy of the lateral nail matrixes. Epithelized fibrous tissue was cut across the lateral nail matrix and left for secondary healing. Partial matrixectomy was applied and ...

  6. Bridging the Gap: Linking Simulation and Testing

    Energy Technology Data Exchange (ETDEWEB)

    Krajewski, Paul E.; Carsley, John; Stoudt, Mark R.; Hovanski, Yuri

    2012-09-01

    The Materials Genome Initiative (MGI) which is a key enabler for the Advanced Manufacturing Partnership, announced in 2011 by U.S. President Barack Obama, was established to accelerate the development and deployment of advanced materials. The MGI is driven by the need to "bridge the gap" between (I) experimental results and computational analysis to enable the rapid development and validation of new mateirals, and (II) the processes required to convert these materials into useable goods.

  7. COLLISIONS OF ROAD VEHICLES WITH BRIDGE COLUMNS

    OpenAIRE

    2015-01-01

    As speed limits and traffic on city roads continue to increase, collisions between road vehicles and bridge columns are becoming more common. Current regulations analyze collision with one major simplification: replacing dynamic action with the equivalent static force. In the present paper, we develop a numerical model of a typical Croatian overpass and loaded it with an equivalent static load according to the EN1991-7 and ASSHTO LRFD provisions, analyzing the differences in overpass behavior...

  8. Golgi localized barley MTP8 proteins facilitate Mn transport.

    Science.gov (United States)

    Pedas, Pai; Schiller Stokholm, Michaela; Hegelund, Josefine Nymark; Ladegård, Anne Hald; Schjoerring, Jan Kofod; Husted, Søren

    2014-01-01

    Many metabolic processes in plants are regulated by manganese (Mn) but limited information is available on the molecular mechanisms controlling cellular Mn homeostasis. In this study, a yeast assay was used to isolate and characterize two genes, MTP8.1 and MTP8.2, which encode membrane-bound proteins belonging to the cation diffusion facilitator (CDF) family in the cereal species barley (Hordeum vulgare). Transient expression in onion epidermal cells showed that MTP8.1 and MTP8.2 proteins fused to the green fluorescent protein (GFP) are localized to Golgi. When heterologously expressed in yeast, MTP8.1 and MTP8.2 were found to be Mn transporters catalysing Mn efflux in a similar manner as the Golgi localized endogenous yeast protein Pmr1p. The level of MTP8.1 transcripts in barley roots increased with external Mn supply ranging from deficiency to toxicity, while MTP8.2 transcripts decreased under the same conditions, indicating non-overlapping functions for the two genes. In barley leaves, the expression of both MTP8 genes declined in response to toxic Mn additions to the roots suggesting a role in ensuring proper delivery of Mn to Golgi. Based on the above we suggest that barley MTP8 proteins are involved in Mn loading to the Golgi apparatus and play a role in Mn homeostasis by delivering Mn to Mn-dependent enzymes and/or by facilitating Mn efflux via secretory vesicles. This study highlights the importance of MTP transporters in Mn homeostasis and is the first report of Golgi localized Mn2+ transport proteins in a monocot plant species.

  9. Bridging Redox Species-Coated Graphene Oxide Sheets to Electrode for Extending Battery Life Using Nanocomposite Electrolyte.

    Science.gov (United States)

    Huang, Yi Fu; Ruan, Wen Hong; Lin, Dong Ling; Zhang, Ming Qiu

    2017-01-11

    Substituting conventional electrolyte for redox electrolyte has provided a new intriguing method for extending battery life. The efficiency of utilizing the contained redox species (RS) in the redox electrolyte can benefit from increasing the specific surface area of battery electrodes from the electrode side of the electrode-electrolyte interface, but is not limited to that. Herein, a new strategy using nanocomposite electrolyte is proposed to enlarge the interface with the aid of nanoinclusions from the electrolyte side. To do this, graphene oxide (GO) sheets are first dispersed in the electrolyte solution of tungstosilicic salt/lithium sulfate/poly(vinyl alcohol) (SiWLi/Li2SO4/PVA), and then the sheets are bridged to electrode, after casting and evaporating the solution on the electrode surface. By applying in situ conductive atomic force microscopy and Raman spectra, it is confirmed that the GO sheets doped with RS of SiWLi/Li2SO4 can be bridged and electrically reduced as an extended electrode-electrolyte interface. As a result, the RS-coated GO sheets bridged to LiTi2(PO4)3//LiMn2O4 battery electrodes are found to deliver extra energy capacity (∼30 mAh/g) with excellent electrochemical cycling stability, which successfully extends the battery life by over 50%.

  10. Structural characterization of thioether-bridged bacteriocins.

    Science.gov (United States)

    Lohans, Christopher T; Vederas, John C

    2014-01-01

    Bacteriocins are a group of ribosomally synthesized antimicrobial peptides produced by bacteria, some of which are extensively post-translationally modified. Some bacteriocins, namely the lantibiotics and sactibiotics, contain one or more thioether bridges. However, these modifications complicate the structural elucidation of these bacteriocins using conventional techniques. This review will discuss the techniques and strategies that have been applied to determine the primary structures of lantibiotics and sactibiotics. A major challenge is to identify the topology of thioether bridges in these peptides (i.e., which amino-acid residues are involved in which bridges). Edman degradation, NMR spectroscopy and tandem MS have all been commonly applied to characterize these bacteriocins, but can be incompatible with the post-translational modifications present. Chemical modifications to the modified residues, such as desulfurization and reduction, make the treated bacteriocins more compatible to analysis by these standard peptide analytical techniques. Despite their differences in structure, similar strategies have proved useful to study the structures of both lantibiotics and sactibiotics.

  11. Core-shell Mn3O4/birnessite-MnO2 hierachical structure with enhanced adsorption towards methylene blue

    Science.gov (United States)

    Huang, Feifan; Zhou, Bowen; Xiao, Han; Xiao, Wei

    2016-01-01

    The core-shell Mn3O4/birnessite-MnO2 (Mn3O4/MnO2) was successfully established by assembly of birnessite-type MnO2 over Mn3O4 backbones. The product was characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM), as well as UV-vis absorption spectra (UV-vis) to assess its adsorption of methylene blue (MB) from neutral aqueous solutions. Compared to the individual Mn3O4, the prepared Mn3O4/MnO2 shows enhanced adsorption capability towards MB. Such enhancement is due to the higher surface area and the unique nanosheet shells. The adsorption of MB on the surface of Mn3O4/MnO2 was studied in terms of pseudo-first-order and the pseudo-second-order kinetic models, and the latter was found better. The present study indicates that hierarchically structured core-shell manganese oxides are promising adsorbents for wastewater treatment.

  12. Effect of MnO2 morphology on the catalytic oxidation of toluene over Ag/MnO2 catalysts

    Science.gov (United States)

    Li, Jiamin; Qu, Zhenping; Qin, Yuan; Wang, Hui

    2016-11-01

    The Ag/MnO2 catalysts with different morphologies (wire-like, rod-like and tube-like) are used as toluene oxidation catalysts in an attempt to investigate how the structures of support affect the interaction of Ag and MnO2, and thus the toluene catalytic activity. Analysis by TEM, H2-TPR and XPS measurements reveals that the structures of MnO2 influence the particle size and dispersion of silver particles and the combination of silver particles with MnO2. Meanwhile, the addition of Ag regulates the performance of MnO2. The small particle size and hemispherically shaped Ag particles are easily to form and homogeneously dispersed on the surface of wire-like MnO2. And this specific form of Ag shows the strongest interaction with MnO2, which promotes the low-temperature reducibility of support and generated more lattice oxygen in metal oxides. The Ag/MnO2 nanowires sample exhibits the highest reactivity for toluene oxidation with a complete conversion at 220 °C. Therefore, the excellent catalytic performance of Ag/MnO2 nanowires catalyst for toluene oxidation is clearly connected with the interaction between the Ag and MnO2, which is determined by the morphology of MnO2 support.

  13. Ionic Strength-Controlled Mn (Hydr)oxide Nanoparticle Nucleation on Quartz: Effect of Aqueous Mn(OH)2.

    Science.gov (United States)

    Jung, Haesung; Jun, Young-Shin

    2016-01-05

    The early formation of manganese (hydr)oxide nanoparticles at mineral-water interfaces is crucial in understanding how Mn oxides control the fate and transport of heavy metals and the cycling of nutrients. Using atomic force microscopy, we investigated the heterogeneous nucleation and growth of Mn (hydr)oxide under varied ionic strengths (IS; 1-100 mM NaNO3). Experimental conditions (i.e., 0.1 mM Mn(2+) (aq) concentration and pH 10.1) were chosen to be relevant to Mn remediation sites. We found that IS controls Mn(OH)2 (aq) formation, and that the controlled Mn(OH)2 (aq) formation can affect the system's saturation and subsequent Mn(OH)2 (s) and further Mn3O4 (s) nanoparticle formation. In 100 mM IS system, nucleated Mn (hydr)oxide particles had more coverage on the quartz substrate than those in 1 mM and 10 mM IS systems. This high IS also resulted in low supersaturation ratio and thus favor heterogeneous nucleation, having better structural matching between nucleating Mn (hydr)oxides and quartz. The unique information obtained in this work improves our understanding of Mn (hydr)oxide formation in natural as well as engineered aqueous environments, such as groundwater contaminated by natural leachate and acid mine drainage remediation.

  14. The structural and magnetic properties of MnBi and exchange coupled MnBi/Fe films

    Energy Technology Data Exchange (ETDEWEB)

    Li, B. [Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016 (China); Liu, W., E-mail: wliu@imr.ac.cn [Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016 (China); Zhao, X.G.; Gong, W.J.; Zhao, X.T.; Wang, H.L. [Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016 (China); Kim, D.; Choi, C.J. [Functional Materials Division, Korea Institute of Materials Science, 531 Changwon-daero, Changwon 631-831 (Korea, Republic of); Zhang, Z.D. [Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016 (China)

    2014-12-15

    The structural and magnetic properties of MnBi and MnBi/Fe films prepared by magnetron sputtering and in situ vacuum annealing are investigated. MnBi film is highly c-axis textured with perpendicular anisotropy. The out-of-plane coercivity increases with temperature, which reaches to 15 kOe and 21 kOe at 300 K and 400 K, respectively. For exchange coupled MnBi/Fe films, when the thickness of Fe layer is thin, the hysteresis loops show single-phase-like reversal behavior due to the effective interfacial exchange coupling. In comparison with MnBi film, the remanent magnetization enhances. The maximum energy product also improves from 7.6 MGOe to 8.0 MGOe at 300 K, and from 5.7 MGOe to 6.1 MGOe at 400 K. As the thickness of Fe layer exceeds the critical dimension, the two-step reversal behavior is observed, indicating the decoupling of soft Fe layer and neighboring hard MnBi layer. - Highlights: • MnBi film shows perpendicular anisotropy with highly c-axis textured. • At 400 K, MnBi film shows a higher (BH){sub max} than MnBi magnet due to perpendicular anisotropy. • (BH){sub max} of MnBi/Fe film is enhanced due to exchange coupling. • A step emerges on the demagnetization curve of MnBi/Fe film as temperature goes up.

  15. Communication through molecular bridges: different bridge orbital trends result in common property trends.

    Science.gov (United States)

    Proppe, Jonny; Herrmann, Carmen

    2015-02-05

    Common trends in communication through molecular bridges are ubiquitous in chemistry, such as the frequently observed exponential decay of conductance/electron transport and of exchange spin coupling with increasing bridge length, or the increased communication through a bridge upon closing a diarylethene photoswitch. For antiferromagnetically coupled diradicals in which two equivalent spin centers are connected by a closed-shell bridge, the molecular orbitals (MOs) whose energy splitting dominates the coupling strength are similar in shape to the MOs of the dithiolated bridges, which in turn can be used to rationalize conductance. Therefore, it appears reasonable to expect the observed common property trends to result from common orbital trends. We illustrate based on a set of model compounds that this assumption is not true, and that common property trends result from either different pairs of orbitals being involved, or from orbital energies not being the dominant contribution to property trends. For substituent effects, an effective modification of the π system can make a comparison difficult.

  16. Development of bridge management system (BMS); Bridge Management System (BMS) no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Miyamoto, A.; Kushida, M. [Yamaguchi University, Yamaguchi (Japan). Faculty of Engineering; Adachi, Y. [Hanshin Expressway Public Corp., Osaka (Japan); Matsumoto, M. [Kobe University, Kobe (Japan)

    1997-03-20

    With an objective to develop a bridge management system (BMS) which can execute overall management of road networks, discussions were given on the subject taking advantage of a result of the output from a concrete bridge diagnosis expert system. As its first step, a certain bridge was noticed to discuss an optimal maintenance and management measure which takes into consideration the safety, economic efficiency, functionality, and environmentality. The system has made it possible to estimate deterioration of the bridge after repair and reinforcement by proposing a deterioration curve and setting different hypotheses as a method to forecast performance deterioration of bridge members. Necessity of repair and reinforcement at the time of checking was determined from the result of an output from the expert system to select a construction method. A scheduled number of service years is set, all of the combinations of maintenance and management measures which satisfy the scheduled service life were retrieved, and an optimal maintenance and management measure was indicated, whose total cost is minimum among the proposed measures. Applying this MBS is capable to some extent of evaluating the effect of executing different measures and making economical optimization. 15 refs., 12 figs., 18 tabs.

  17. Building water bridges in air: Electrohydrodynamics of the Floating Water Bridge

    CERN Document Server

    Marin, Alvaro G

    2010-01-01

    The interaction of electrical fields and liquids can lead to phenomena that defies intuition. Some famous examples can be found in Electrohydrodynamics as Taylor cones, whipping jets or non-coalescing drops. A less famous example is the Floating Water Bridge: a slender thread of water held between two glass beakers in which a high voltage difference is applied. Surprisingly, the water bridge defies gravity even when the beakers are separated at distances up to 2 cm. In the presentation, experimental measurements and simple models are proposed and discussed for the stability of the bridge and the source of the flow, revealing an important role of polarization forces on the stability of the water bridge. On the other hand, the observed flow can only be explained due to the non negligible free charge present in the surface. In this sense, the Floating Water Bridge can be considered as an extreme case of a leaky dielectric liquid (J. R. Melcher and G. I. Taylor, Annu. Rev. Fluid Mech., 1:111, 1969).

  18. MnO nanoparticles as the cause of ferromagnetism in bulk dilute Mn-doped ZnO

    Science.gov (United States)

    Lançon, Diane; Nilsen, Gøran J.; Wildes, Andrew R.; Nemkovski, Kirill; Huang, Ping; Fejes, Dóra; Rønnow, Henrik M.; Magrez, Arnaud

    2016-12-01

    We show that the observed ferromagnetic behavior of ZnO lightly doped with Mn coincides with the presence of MnO nanoparticles, whereas cluster-free Mn doped ZnO behaves paramagnetically. This conclusion is reached by a study of the structural and magnetic properties of powdered samples of (Mnx,Zn1-x)O with x ≤ 0.033 using polarized neutron scattering. Two types of samples were synthesized via, respectively, a solid state method and the decomposition of hydrozincite. Further characterization has been performed using standard X-ray diffraction and magnetization measurements. The results show evidence for the formation of MnO nanoparticles in the highest doped samples for both synthesis methods, with a ferromagnetic behavior attributed to uncompensated Mn2+ in the MnO nanoparticles. The lower Mn-doped samples showed no evidence for structural segregation or magnetic correlations and showed only a paramagnetic behaviour.

  19. The Internet Inter-Orb Protocol Security Bridge

    Directory of Open Access Journals (Sweden)

    Pawel Slowikowski

    1999-01-01

    Full Text Available In this paper, we present a security bridge for the Internet protocol of interoperability amongst CORBA objects and the Internet inter-ORB Protocol (IIOP. The bridge helps in making accessible objects in the Internet and makes possible the access control to them. The bridge was realized in the popular request broker the Visigenic's VisiBroker under Windows 95/NT and Solaris 2.X operating systems. We describe two ways of locating the bridge in the request broker. The first means uses one name domain of broker and is not transparent for client. The second one uses two name domains and provides objects protection on the level of the Naming Service and is transparent lor the client. We also describe the variant ofthe second means with using GateKeeper server to support IIOP tunneling within HTTP. We emphasize the importance of a firewall, cooperating with a bridge. which is required for the purpose of providing object protection. The paper presents an original conception of security managing, basing on the ideas of users, groups and resources defined using the standard terms of CORBA, IIOP and TCP/IP, that allows to control positively and negatively the access to classes (interfaces, objects and also to their individual methods. This conception was effectively implemented in a functioning bridge. Further chapters describe the foundations and some details of the bridge implementation sueli as the use ofthe Interface Repository, cache memory application, thread synchronization and the way of synchronization of the configuration applet with the bridge's objects. We discuss the influence of these solutions on the efficiency ofthe bridge and its source code portability. We also present the general structure of the component objects ofthe bridge with a scheme. ln the next part we characterize the implementation foundations ofthe bridge manager, realized as an applet in Java, with the stress on the possibility of the bridge configuration through the

  20. Mechanism of a strongly anisotropic MoIII-CN-MnII spin-spin coupling in molecular magnets based on the [Mo(CN)(7)](4-) heptacyanometalate: a new strategy for single-molecule magnets with high blocking temperatures.

    Science.gov (United States)

    Mironov, Vladimir S; Chibotaru, Liviu F; Ceulemans, Arnout

    2003-08-13

    Unusual spin coupling between Mo(III) and Mn(II) cyano-bridged ions in bimetallic molecular magnets based on the [Mo(III)(CN)(7)](4-) heptacyanometalate is analyzed in terms of the superexchange theory. Due to the orbital degeneracy and strong spin-orbit coupling on Mo(III), the ground state of the pentagonal-bipyramidal [Mo(III)(CN)(7)](4-) complex corresponds to an anisotropic Kramers doublet. Using a specially adapted kinetic exchange model we have shown that the Mo(III)-CN-Mn(II) superexchange interaction is extremely anisotropic: it is described by an Ising-like spin Hamiltonian JS(z)(Mo) S(z)(Mn) for the apical pairs and by the J(z)S(z)(Mo) S(z)(Mn) + J(xy)(Sx(Mo) Sx(Mn) + Sy(Mo) Sy(Mn)) spin Hamiltonian for the equatorial pairs (in the latter case J(z) and J(xy) can have opposite signs). This anisotropy resulted from an interplay of several Ising-like (Sz(Mo) Sz(Mn)) and isotropic (S(Mo)S(Mn)) ferro- and antiferromagnetic contributions originating from metal-to-metal electron transfers through the pi and sigma orbitals of the cyano bridges. The Mo(III)-CN-Mn(II) exchange anisotropy is distinct from the anisotropy of the g-tensor of [Mo(III)(CN)(7)](4-); moreover, there is no correlation between the exchange anisotropy and g-tensor anisotropy. We indicate that highly anisotropic spin-spin couplings (such as the Ising-like JS(z)(Mo) S(z)(Mn)) combined with large exchange parameters represent a very important source of the global magnetic anisotropy of polyatomic molecular magnetic clusters. Since the total spin of such clusters is no longer a good quantum number, the spin spectrum pattern can differ considerably from the conventional scheme described by the zero-field splitting of the isotropic spin of the ground state. As a result, the spin reorientation barrier of the magnetic cluster may be considerably larger. This finding opens a new way in the strategy of designing single-molecule magnets (SMM) with unusually high blocking temperatures. The use of

  1. Disulfide Bridges: Bringing Together Frustrated Structure in a Bioactive Peptide.

    Science.gov (United States)

    Zhang, Yi; Schulten, Klaus; Gruebele, Martin; Bansal, Paramjit S; Wilson, David; Daly, Norelle L

    2016-04-26

    Disulfide bridges are commonly found covalent bonds that are usually believed to maintain structural stability of proteins. Here, we investigate the influence of disulfide bridges on protein dynamics through molecular dynamics simulations on the cysteine-rich trypsin inhibitor MCoTI-II with three disulfide bridges. Correlation analysis of the reduced cyclic peptide shows that two of the three disulfide distances (Cys(11)-Cys(23) and Cys(17)-Cys(29)) are anticorrelated within ∼1 μs of bridge formation or dissolution: when the peptide is in nativelike structures and one of the distances shortens to allow bond formation, the other tends to lengthen. Simulations over longer timescales, when the denatured state is less structured, do not show the anticorrelation. We propose that the native state contains structural elements that frustrate one another's folding, and that the two bridges are critical for snapping the frustrated native structure into place. In contrast, the Cys(4)-Cys(21) bridge is predicted to form together with either of the other two bridges. Indeed, experimental chromatography and nuclear magnetic resonance data show that an engineered peptide with the Cys(4)-Cys(21) bridge deleted can still fold into its near-native structure even in its noncyclic form, confirming the lesser role of the Cys(4)-Cys(21) bridge. The results highlight the importance of disulfide bridges in a small bioactive peptide to bring together frustrated structure in addition to maintaining protein structural stability.

  2. Aerodynamic stability of cable-supported bridges using CFRP cables

    Institute of Scientific and Technical Information of China (English)

    ZHANG Xin-jun; YING Lei-dong

    2007-01-01

    To gain understanding of the applicability of carbon fiber reinforced polymer (CFRP) cable in cable-supported bridges, based on the Runyang Bridge and Jinsha Bridge, a suspension bridge using CFRP cables and a cable-stayed bridge using CFRP stay cables are designed, in which the cable's cross-sectional area is determined by the principle of equivalent axial stiffness.Numerical investigations on the aerodynamic stability of the two bridges are conducted by 3D nonlinear aerodynamic stability analysis. The results showed that as CFRP cables are used in cable-supported bridges, for suspension bridge, its aerodynamic stability is superior to that of the case using steel cables due to the great increase of the torsional frequency; for cable-stayed bridge,its aerodynamic stability is basically the same as that of the case using steel stay cables. Therefore as far as the wind stability is considered, the use of CFRP cables in cable-supported bridges is feasible, and the cable's cross-sectional area should be determined by the principle of equivalent axial stiffness.

  3. Field Tests and Simulation of Lion-Head River Bridge

    Directory of Open Access Journals (Sweden)

    Yao-Min Fang

    2007-01-01

    Full Text Available Lion-Head River Bridge is a twin bridge in parallel position. The east-bounded was designed and constructed as a traditional prestress concrete box girder bridge with pot bearings; and the west-bounded was installed with seismic isolation devices of lead rubber bearings. The behavior of the isolated bridge is compared with that of the traditional bridge through several field tests including the ambient vibration test, the force vibration test induced by shakers, the free vibration test induced by a push and fast release system, and the truck test. The bridges suffered from various extents of damage due to the Chi-Chi and the Chi-I earthquakes of great strength during the construction and had been retrofitted. The damage was reflected by the change of the bridges' natural frequencies obtained from the ambient vibration tests. The models of the two bridges are simulated by the finite element method based on the original design drawings. Soil-structure interaction was also scrutinized in this study. The simulation was then modified based on the results from the field tests. Dynamic parameters of bridges are identified and compared with those from theoretical simulation. The efficiency is also verified to be better for an isolated bridge.

  4. Bridges analysis, design, structural health monitoring, and rehabilitation

    CERN Document Server

    Bakht, Baidar

    2015-01-01

    This book offers a valuable guide for practicing bridge engineers and graduate students in structural engineering; its main purpose is to present the latest concepts in bridge engineering in fairly easy-to-follow terms. The book provides details of easy-to-use computer programs for: ·      Analysing slab-on-girder bridges for live load distribution. ·      Analysing slab and other solid bridge components for live load distribution. ·      Analysing and designing concrete deck slab overhangs of girder bridges under vehicular loads. ·      Determining the failure loads of concrete deck slabs of girder bridges under concentrated wheel loads. In addition, the book includes extensive chapters dealing with the design of wood bridges and soil-steel bridges. Further, a unique chapter on structural health monitoring (SHM) will help bridge engineers determine the actual load carrying capacities of bridges, as opposed to their perceived analytical capacities. The chapter addressing structures...

  5. A cloud-based information repository for bridge monitoring applications

    Science.gov (United States)

    Jeong, Seongwoon; Zhang, Yilan; Hou, Rui; Lynch, Jerome P.; Sohn, Hoon; Law, Kincho H.

    2016-04-01

    This paper describes an information repository to support bridge monitoring applications on a cloud computing platform. Bridge monitoring, with instrumentation of sensors in particular, collects significant amount of data. In addition to sensor data, a wide variety of information such as bridge geometry, analysis model and sensor description need to be stored. Data management plays an important role to facilitate data utilization and data sharing. While bridge information modeling (BrIM) technologies and standards have been proposed and they provide a means to enable integration and facilitate interoperability, current BrIM standards support mostly the information about bridge geometry. In this study, we extend the BrIM schema to include analysis models and sensor information. Specifically, using the OpenBrIM standards as the base, we draw on CSI Bridge, a commercial software widely used for bridge analysis and design, and SensorML, a standard schema for sensor definition, to define the data entities necessary for bridge monitoring applications. NoSQL database systems are employed for data repository. Cloud service infrastructure is deployed to enhance scalability, flexibility and accessibility of the data management system. The data model and systems are tested using the bridge model and the sensor data collected at the Telegraph Road Bridge, Monroe, Michigan.

  6. Construction and control technology of the main bridge superstructure of Sutong Bridge

    Institute of Scientific and Technical Information of China (English)

    Zhang Hong; Luo Chenbin; Zhang Yongtao; You Xinpeng

    2009-01-01

    The Sutong Yangtze River Bridge (short as Sutong Bridge) is now the largest span cable-stayed bridge in the world. The construction of the superstructure of the middle bridge covered several stages including erection of the big block girders for the side span, assistant span and tower area, erection of standard girders and closure of the middle span. The big block girders were hoisted by a floating crane, and the standard girders were hoisted by a double crane system on the deck. The pushing assistant method was adopted for the middle span closure construction. Furthermore, key technologies and innovative methods used in the processes of girder erection and cable assemblage in all stages were expatiated systematically. An all-stage self- adaptive geometry control method was used in the construction process. By accurately controlling the unstressed dimensions and shape of all structural components in each step, and realization that the control system and the controlled system adapt to each other, the goal was to make control of the final line shape and inner force of the bridge structure achievable. Two solutions, including GPS based and total station based dynamic geometry monitoring systems, were used to resolve the measure problem under the wide-range of wind-induced vibrations in the long cantilever state. Finally, research on the wind-induced vibration of the superstructure during the construction period was executed. Buffeting response analysis to the longest single and double cantilever states were carried out. The analysis and evaluation of wind resistance safety of the main girders under the longest single cantilever state was made, and corresponding wind resistance measures were suggested. The as-built geometric error and cable force error were controlled in a required design range, and this whole technological achievement can be a benchmark for construction of other large span cable-stayed bridges in the future.

  7. Magnetic and electrical properties of epitaxial GeMn

    Energy Technology Data Exchange (ETDEWEB)

    Ahlers, Stefan

    2009-01-15

    In this work, GeMn magnetic semiconductors will be investigated. The fabrication of GeMn thin films with Mn contents up to 11.7% was realised with molecular beam epitaxy. At a fabrication temperature of 60 C, the suppression of Mn{sub x}Ge{sub y} phases could reproducibly be obtained. Dislocation free epitaxy of diamond-lattice type GeMn thin films was observed. In all fabrication conditions where Mn{sub x}Ge{sub y} suppression was feasible, an inhomogeneous dispersion of Mn was observed in form of a self-assembly of nanometre sized, Mn rich regions in a Ge rich matrix. Each Mn rich region exhibits ferromagnetic coupling with high Curie temperatures exceeding, in part, room temperature. The local ferromagnetic ordering leads to the formation of large, spatially separated magnetic moments, which induce a superparamagnetic behaviour of the GeMn thin films. At low temperatures {<=} 20 K, remanent behaviour was found to emerge. X-ray absorption experiments revealed a similarity of the Mn incorporation in diamond-lattice type GeMn thin films and in the hexagonal lattice of the intermetallic Mn{sub 5}Ge{sub 3} phase, respectively. These tetrahedra represent building blocks of the Mn{sub 5}Ge{sub 3} unit cell. The incorporation of Mn{sub 5}Ge{sub 3} building blocks was found to be accompanied by local structural disorder. The electrical properties of GeMn thin films were addressed by transport measurements. It was shown that by using a n-type Ge substrate, a pn energy barrier between epilayers and substrate to suppress parallel substrate conduction paths can be introduced. With the pn barrier concept, first results on the magnetotransport behaviour of GeMn thin films were obtained. GeMn was found to be p-type, but of high resistivity. a series of GeMn thin films was fabricated, where intermetallic Mn{sub x}Ge{sub y} phase separation was supported in a controlled manner. Phase separation was found to result in the formation of partially coherent, nanometre sized Mn{sub 5

  8. GaAs:Mn nanowires grown by molecular beam epitaxy of (Ga,Mn)as at MnAs segregation conditions.

    Science.gov (United States)

    Sadowski, Janusz; Dłuzewski, Piotr; Kret, Sławomir; Janik, Elzbieta; Lusakowska, Elzbieta; Kanski, Janusz; Presz, Adam; Terki, Ferial; Charar, Salam; Tang, Dong

    2007-09-01

    GaAs:Mn nanowires were obtained on GaAs(001) and GaAs(111)B substrates by molecular beam epitaxial growth of (Ga,Mn)As at conditions leading to MnAs phase separation. Their density is proportional to the density of catalyzing MnAs nanoislands, which can be controlled by the Mn flux and/or the substrate temperature. After deposition corresponding to a 200 nm thick (Ga,Mn)As layer the nanowires are around 700 nm long. Their shapes are tapered, with typical diameters around 30 nm at the base and 7 nm at the tip. The wires grow along the 111 direction, i.e., along the surface normal on GaAs(111)B and inclined on GaAs(001). In the latter case they tend to form branches. Being rooted in the ferromagnetic semiconductor (Ga,Mn)As, the nanowires combine one-dimensional properties with the magnetic properties of (Ga,Mn)As and provide natural, self-assembled structures for nanospintronics.

  9. Increased micronucleus, nucleoplasmic bridge, nuclear bud frequency and oxidative DNA damage associated with prolactin levels and pituitary adenoma diameters in patients with prolactinoma.

    Science.gov (United States)

    Bitgen, N; Donmez-Altuntas, H; Bayram, F; Cakir, I; Hamurcu, Z; Diri, H; Baskol, G; Senol, S; Durak, A C

    2016-01-01

    Prolactinoma is the most common pituitary tumor. Most pituitary tumors are benign, but they often are clinically significant. We investigated cytokinesis-block micronucleus cytome (CBMN cyt) assay parameters and oxidative DNA damage in patients with prolactinoma to assess the relations among age, prolactin level, pituitary adenoma diameter and 8-hydroxy-2'-deoxyguanosine (8-OHdG) level in patients with prolactinoma. We investigated 27 patients diagnosed with prolactinoma and 20 age- and sex-matched healthy controls. We measured CBMN cyt parameters and plasma 8-OHdG levels in peripheral blood lymphocytes of patients with prolactinoma and controls. The frequencies of micronucleus (MN), nucleoplasmic bridge, nuclear bud, apoptotic and necrotic cells, and plasma 8-OHdG levels in patients with prolactinoma were significantly greater than controls. MN frequency was correlated positively with age, prolactin levels and pituitary adenoma diameters in patients with prolactinoma. The increased chromosomal and oxidative DNA damage, and the positive correlation between MN frequency, prolactin levels and pituitary adenoma diameters may be associated with increased risk of cancer in patients with prolactinoma, because increased MN frequency is a predictor of cancer risk.

  10. Optical properties of Mn doped ZnO films and wires synthesized by thermal oxidation of ZnMn alloy

    Energy Technology Data Exchange (ETDEWEB)

    Sima, M., E-mail: msima@infim.ro [National Institute of Materials Physics, 105bis Atomistilor Street, 077125 Magurele (Romania); Mihut, L. [National Institute of Materials Physics, 105bis Atomistilor Street, 077125 Magurele (Romania); Vasile, E. [University “Politehnica”of Bucharest, Faculty of Applied Chemistry and Material Science, Department of Oxide Materials and Nanomaterials, No. 1-7 Gh. Polizu Street, 011061 Bucharest (Romania); Sima, Ma.; Logofatu, C. [National Institute of Materials Physics, 105bis Atomistilor Street, 077125 Magurele (Romania)

    2015-09-01

    Mn doped ZnO films and wires, having different manganese concentrations were synthesized by thermal oxidation of the corresponding ZnMn alloy films and wires electrodeposited on a gold substrate. Structural and optical properties were addressed with scanning electron microscopy, X-ray diffraction (XRD), Raman scattering and photoluminescence (PL). To estimate the manganese concentration in Mn doped ZnO films, X-ray photoelectron spectroscopy was used. XRD patterns indicate that the incorporation of Mn{sup 2+} ions into the Zn{sup 2+} site of ZnO lattice takes place. Quenching of the ZnO PL appears due to Mn{sup 2+} ions in the ZnO lattice. Moreover, a significant decrease in the green emission of ZnO is reported in the case of the Mn doped ZnO wire array with a Mn concentration of 1.45%. The wurtzite ZnO has a total of 12 phonon modes, namely, one longitudinal acoustic (LA), two transverse acoustic (TA), three longitudinal optical (LO), and six transverse optical branches. Compared to the undoped ZnO, a gradual up-shift of the Raman lines assigned to the 2LA and A{sub 1} (LO) vibrational modes, from 482 and 567 cm{sup −1} to 532 and 580 cm{sup −1}, respectively, takes place for the Mn doped ZnO films having a Mn concentration between 2 and 15%. Additionally, in the case of the Mn doped ZnO films with 7 and 15% Mn concentration, Raman spectra show the appearance and increase in the relative intensity of the ZnO Raman line assigned to the TA + LO vibrational mode in the 600–750 cm{sup −1} spectral range. For the Mn-doped ZnO wires, the presence of the Raman line peaking at 527 cm{sup −1} confirms the insertion of Mn{sup 2+} ions in ZnO lattice. - Highlights: • Mn doped ZnO films and wires grown by thermal oxidation of ZnMn alloy • Incorporation of Mn{sup 2+} ions into Zn{sup 2+} site of ZnO lattice • Appearance of a strong Raman line in the spectral range 600–800 cm{sup −1} at high Mn concentration • Compensation of the oxygen vacancy at higher

  11. Investigation of Aerodynamic Interference of Double Deck Bridges

    Energy Technology Data Exchange (ETDEWEB)

    Sitek, M. A. [Argonne National Lab. (ANL), Argonne, IL (United States). Energy Systems Division. Transportation Research and Analysis Computing Center (TRACC); Bojanowski, C. [Argonne National Lab. (ANL), Argonne, IL (United States). Energy Systems Division. Transportation Research and Analysis Computing Center (TRACC); Lottes, S. A. [Argonne National Lab. (ANL), Argonne, IL (United States). Energy Systems Division. Transportation Research and Analysis Computing Center (TRACC)

    2016-05-01

    Construction of a twin bridge can be a cost effective and minimally disruptive way to increase capacity when an existing bridge is not near the end of its service life. With ever growing vehicular traffic, when demand approaches the capacity of many existing roads and bridges. Remodeling a structure with an insufficient number of lanes can be a good solution in case of smaller and less busy bridges. Closing down or reducing traffic on crossings of greater importance for the construction period, however, can result in major delays and revenue loss for commerce and transportation as well as increasing the traffic load on alternate route bridges. Multiple-deck bridges may be the answer to this issue. A parallel deck can be built next to the existing one, without reducing the flow. Additionally, a new bridge can be designed as a twin or multi-deck structure. Several such structures have been built throughout the United States, among them: - The New NY Bridge Project - the Tappan Zee Hudson River Crossing, - SR-182 Columbia River Bridge, - The Thaddeus Kosciusko Bridge (I-87), - The Allegheny River Bridge, Pennsylvania, which carries I76, - Fred Hartman Bridge, TX, see Figure 1.2. With a growing number of double deck bridges, additional, more detailed, studies on the interaction of such bridge pairs in windy conditions appears appropriate. Aerodynamic interference effects should be examined to assure the aerodynamic stability of both bridges. There are many studies on aerodynamic response of single deck bridges, but the literature on double-deck structures is not extensive. The experimental results from wind tunnels are still limited in number, as a parametric study is required, they can be very time consuming. Literature review shows that some investigation of the effects of gap-width and angle of wind incidence has been done. Most of the CFD computational studies that have been done were limited to 2D simulations. Therefore, it is desirable to investigate twin decks

  12. C-Mn segregation and its effect on phase transformation and deformation in Fe-Mn-C alloys

    Institute of Scientific and Technical Information of China (English)

    朱瑞富; 吕宇鹏; 魏涛

    1997-01-01

    C-Mn segregation and its effect on phase transformation and plastic deformation in Fe-Mn-C alloys were studied through the calculation of valence electron structure, the microregion composition detection and TEM in-situ dynamic tensile deformation test The experimental results show that in Fe-8Mn-1.2C alloyed austenite, nA of units with C Mn involved is 3 98 times that of units without C involved and 1.4 times that of units with C involved; aCD of units with C-Mn involved is 2 21 times that of units with C involved. In Fe-Mn-C alloyed austenites, there exists microsegrcgation of C-Mn, forming the randomly distributed Fe-Mn-C atomic cluster segregation zone linked with the -C-Mn-C-Mn- strong bond network, which will effectively slow down the motion of atoms and retard the initiation of the slip system and the movement of dislocation, and thus will severely influence the phase transformation and deformation of the alloy

  13. Electrochemical properties of MnS-C and MnO-C composite powders prepared via spray drying process

    Science.gov (United States)

    Jeon, Kyung Min; Cho, Jung Sang; Kang, Yun Chan

    2015-11-01

    Spherical micron-sized MnS-C and MnO-C composite powders are successfully prepared by post-treating the spray-dried precursor powders. Dextrin, which is used as the carbon source material, plays a key role in the preparation of the composite powders with regular morphologies; the bare MnS and MnO powders prepared from the spray solution without dextrin have irregular morphologies. The MnS-C composite powders prepared from the spray solution containing 17 g L-1 of dextrin have mixed crystal structures of α- and γ-MnS phases. These powders exhibit superior electrochemical properties compared with those of their MnS and MnO-C counterparts. For example, at a current density of 0.5 A g-1, the MnO-C powders have a 100th-cycle discharge capacity of 321 mA h g-1; the corresponding discharge capacities of the MnS powders prepared from spray solutions containing 0, 17, and 50 g L-1 of dextrin are 501, 786, and 636 mA h g-1, respectively.

  14. Comparison of the magnetic properties of GeMn thin films through Mn L-edge x-ray absorption

    Energy Technology Data Exchange (ETDEWEB)

    Ahlers, S.; Stone, P.R.; Sircar, N.; Arenholz, E.; Dubon, O. D.; Bougeard, D.

    2009-08-04

    X-ray absorption spectroscopy of epitaxial GeMn thin films reveals an experimentally indistinguishable electronic configuration of Mn atoms incorporated in Ge{sub 1?x}Mn{sub x} nanoclusters and in precipitates of the intermetallic compound Mn{sub 5}Ge{sub 3}, respectively. However, the average magnetic response of thin films containing Ge{sub 1?x}Mn{sub x} nanoclusters is lower than the response of films containing Mn{sub 5}Ge{sub 3} precipitates. This reduced magnetic response of Ge{sub 1?x}Mn{sub x} nanoclusters is explained in terms of a fraction of Mn atoms being magnetically inactive due to antiferromagnetic coupling or the presence of structural disorder. A determination of the role of magnetically inactive Mn atoms in the self-assembly of the thermodynamically metastable Ge{sub 1?x}Mn{sub x} nanoclusters seems to be an essential ingredient for an enhanced control of this promising high Curie temperature magnetic semiconductor.

  15. Tridecanuclear [Mn(III)5Ln(III)8] complexes derived from N-(t)butyl-diethanolamine: synthesis, structures, and magnetic properties.

    Science.gov (United States)

    Ako, Ayuk M; Mereacre, Valeriu; Clérac, Rodolphe; Hewitt, Ian J; Lan, Yanhua; Buth, Gernot; Anson, Christopher E; Powell, Annie K

    2009-07-20

    The synthesis, structures and magnetic properties of a family of heterometallic [Mn(III)(5)Ln(III)(8)(mu(3)-OH)(12)(L(2))(4)(piv)(12)(NO(3))(4)(OAc)(4)](-) (Ln = Pr, 2; Nd, 3; Sm, 4; Gd, 5; Tb, 6) aggregates are reported. The complexes were obtained from the direct reaction of N-(t)butyldiethanolamine (H(2)L(2)) with Mn(OAc)(2) x 4 H(2)O and Ln(NO(3))(3) x 6 H(2)O in the presence of pivalic acid (pivH) in MeCN under ambient conditions. Compounds 2-6 are isomorphous and crystallize in the monoclinic space group P2(1)/n with four molecules in the unit cell. The complexes have a centrosymmetric tridecanuclear anionic core consisting of two distorted inner heterometallic [Mn(III)Ln(III)(3)(mu(3)-OH)(4)](8+) cubane subunits sharing a common Mn vertex flanked by four edge-sharing heterometallic [Mn(III)Ln(III)(2)(mu(3)-OH)(4)](5+) defect cubane units. Complexes 2-6 are the first high-nuclearity 3d-4f aggregates reported to date using (t)Bu-deaH(2) as ligand. These compounds show no evidence of slow relaxation behavior above 1.8 K, which appears to be the consequence of the very weak or non-existent magnetic interactions between the Mn(III) and Ln(III) ions resulting from the particular angles at the bridging oxygens.

  16. X-ray absorption near-edge structure and valence state of Mn in (Ga,Mn)N

    Science.gov (United States)

    Titov, A.; Biquard, X.; Halley, D.; Kuroda, S.; Bellet-Amalric, E.; Mariette, H.; Cibert, J.; Merad, A. E.; Merad, G.; Kanoun, M. B.; Kulatov, E.; Uspenskii, Yu. A.

    2005-09-01

    The band structure of the diluted magnetic semiconductor (Ga,Mn)N, and the x-ray absorption near-edge structure (XANES) at the K edge of Mn, were calculated using the linearized augmented plane wave method. The calculated K-edge spectra fit well with experimental data obtained on samples of Ga1-xMnxN with a wide range of Mn content, from x=0.3% to 5.7%. These samples were grown by molecular beam epitaxy. X-ray diffraction measurements and extended x-ray absorption fine structure studies were used to confirm the wurtzite structure of the samples, the absence of any secondary phase, and the substitutional position of Mn in the gallium sublattice of GaN. The shape of the measured XANES spectra does not depend on the Mn content, implying the same valence state and local atomic structure around the Mn atom in all samples. The comparison between the measured spectra and the results of the ab initio calculation offers a clear interpretation of the preedge structure: It is mainly due to dipolar transitions, with a single peak in the case of Mn2+ and an additional peak for Mn3+ . Such a behavior of the XANES preedge of Mn2+ was confirmed experimentally on (Ga,Mn)As and (Zn,Mn)Te. We conclude that the valence state of Mn in wurtzite (Ga,Mn)N is 3+ , a conclusion which is also supported by infrared optical transmission and magnetization data obtained on the same samples.

  17. H-BONDING SELF-ASSEMBLED TEMPLATE-CONTROLLED SYNTHESIS OF A NOVEL SOLUBLE AND REACTIVE AMIDE-BRIDGED LADDERLIKE POLYHYDROSILOXANE

    Institute of Scientific and Technical Information of China (English)

    Guan-qun Zhong; Qing-hua Duan; Kui-lin Deng; Ai-qin Zhang; Ping Xie; Hai-liang Zhang; Rong-ben Zhang

    2006-01-01

    A novel soluble and reactive amide-bridged ladderlike polyhydrosiloxane (ALPHS) was first synthesized by an amido H-bonding self-assembled template. ALPHS with molecular weight M-n = 18300 has very highly ordered ladderlike structure, which was confirmed by a sharp resonance absorption peak of [-Si(H)O2/2 ] moiety with the half peak width A1/2 < 0.5 in 29Si-NMR spectrum. Presence of the reactive Si-H groups gives ALPHS an opportunity to further derive a variety of functional polymers by versatile Si-H reactions such as hydrosilylation, condensation, and so on.

  18. Wind Tunnel Experiments with Active Control of Bridge Section Model

    DEFF Research Database (Denmark)

    Hansen, Henriette I.; Thoft-Christensen, Palle

    the flutter wind velocity for future ultra-long span suspension bridges. The purpose of the wind tunnel experiments is to investigate the principle to use this active flap control system. The bridge section model used in the experiments is therefore not a model of a specific bridge but it is realistic......This paper describes results of wind tunnel experiments with a bridge section model where movable flaps are integrated in the bridge girder so each flap is the streamlined part of the edge of the girder. This active control flap system is patented by COWIconsult and may be used to increase...... compared with a real bridge. Five flap configurations are investigated during the wind tunnel experiments and depending on the actual flap configuration it is possible to decrease or increase the flutter wind velocity for the model....

  19. Measurements of bridges' vibration characteristics using a mobile phone

    Directory of Open Access Journals (Sweden)

    Z. M. C. Pravia

    Full Text Available ABSTRACTThis research presents an alternative way to perform a bridge inspection, which considers the dynamics parameters from the structure. It shows an experimental phase with use of a mobile phone to extract the accelerations answers from two concrete bridges, from those records is feasible to obtain natural frequencies using the Fast Fourier Transform (FFT.Numerical models with uses finite element model (FEM allow to determine the natural frequencies from the two concrete bridges and compare with the experimental phase of each one. The final results shows it's possible to use mobiles phones to extract vibration answers from concrete bridges and define the structural behavior of bridges from natural frequencies, this procedure could be used to evaluate bridges with lower costs.

  20. Detection of Subsurface Defects in Concrete Bridge Deck Joints

    Directory of Open Access Journals (Sweden)

    Wonchang Choi

    2011-01-01

    Full Text Available Problem statement: The integrity of deck joints in highway bridges plays a major role to determine overall performance of bridge system. As the bridge maintenance program, the defects in deck joints have historically been detected by conventional non-destructive testing and evaluation methods such as visual inspection, chain-dragging and by the detecting sounds under the traffic. Future bridge maintenance challenges will demand the development of techniques and procedures to detect and monitor such defects before they become apparent. Approach: Two non-destructive methods; namely Ground Penetration Radar (GPR and Seismic Properties Analyzer (SPA were employed to assess the integrity of deck joins installed in North Carolina bridges. Results: The results obtained with the GPR and SPA allows to quantify the subsurface defects in bridge deck joints. Conclusion: The practical application and limitations of each method are discussed in this study.