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Sample records for bridge minneapolis mn

  1. Demonstration Assessment of Light-Emitting Diode (LED) Roadway Lighting at the I-35W Bridge, Minneapolis, MN

    Energy Technology Data Exchange (ETDEWEB)

    Kinzey, Bruce R.; Myer, Michael

    2009-08-31

    This report describes the process and results of a demonstration of solid-state lighting (SSL) technology conducted in 2009 at the recently reconstructed I-35W bridge in Minneapolis, MN. The project was supported under the U.S. Department of Energy (DOE) Solid-State Lighting GATEWAY Technology Demonstration Program. Other participants in the demonstration project included the Minnesota Department of Transportation (Mn/DOT), Federal Highways Administration (FHWA), and BetaLED™ (a division of Ruud Lighting). Pacific Northwest National Laboratory (PNNL) conducted the measurements and analysis of the results. DOE has implemented a three-year evaluation of the LED luminaires in this installation in order to develop new longitudinal field data on LED performance in a challenging, real-world environment. This document provides information through the initial phase of the I-35W bridge project, up to and including the opening of the bridge to the public and the initial feedback received on the LED lighting installation from bridge users. Initial findings of the evaluation are favorable, with minimum energy savings level of 13% for the LED installation relative to the simulated base case using 250W high-pressure sodium (HPS) fixtures. The LEDs had an average illuminance level of 0.91 foot candles compared to 1.29 fc for the HPS lamps. The LED luminaires cost $38,000 more than HPS lamps, yielding a lengthy payback period, however the bridge contractor had offered to include the LED luminaires as part of the construction package at no additional cost. One potentially significant benefit of the LEDs in this installation is avoiding rolling lane closures on the heavily-traveled interstate bridge for the purpose of relamping the HPS fixtures. Rolling lane closures involve multiple crew members and various maintenance and safety vehicles, diversion of traffic, as well as related administrative tasks (e.g., approvals, scheduling, etc.). Mn/DOT records show an average cost of

  2. 78 FR 31628 - Environmental Impact Statement for the Milwaukee, WI to Minneapolis, MN Rail Corridor

    Science.gov (United States)

    2013-05-24

    ... Procedures for Considering Environmental Impacts (64 FR 28545; May 26, 1999). FRA and MnDOT will use a tiered... Federal Railroad Administration Environmental Impact Statement for the Milwaukee, WI to Minneapolis, MN... be prepared for the Milwaukee, WI to Minneapolis-St. Paul, MN (Milwaukee-Twin Cities) High-Speed...

  3. Long-term Testing Results for the 2008 Installation of LED Luminaires at the I-35 West Bridge in Minneapolis

    Energy Technology Data Exchange (ETDEWEB)

    Kinzey, Bruce R.; Davis, Robert G.

    2014-09-30

    This document reports the long-term testing results from an extended GATEWAY project that was first reported in “Demonstration Assessment of Light-Emitting Diode (LED) Roadway Lighting at the I-35W Bridge, in Minneapolis, MN,” August 2009. That original report presented the results of lighting the newly reconstructed I 35W Bridge using LEDs in place of conventional high-pressure sodium (HPS) roadway luminaires, comparing energy use and illuminance levels with a simulated baseline condition. That installation was an early stage implementation of LED lighting and remains one of the oldest installations in continued operation today. This document provides an update of the LED system’s performance since its installation in September 2008.

  4. Demonstration Assessment of Light-Emitting Diode (LED) Roadway Lighting, I-35W Bridge, Minneapolis, Minnesota, Phase I Report

    Energy Technology Data Exchange (ETDEWEB)

    Kinzey, B. R. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Myer, M. A. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2009-08-01

    On the I-35W Bridge in Minneapolis, Minnesota, the GATEWAY program conducted a two-phase demonstration of LED roadway lighting on the main span, which is one of the country's oldest continuously operated exterior LED lighting installations. The Phase I report provides an overview of initial project results including lighting performance, economic performance, and potential energy savings.

  5. Demonstration Assessment of Light-Emitting Diode (LED) Roadway Lighting, I-35W Bridge, Minneapolis, Minnesota, Phase II Report

    Energy Technology Data Exchange (ETDEWEB)

    Kinzey, B. R. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Davis, R. G. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2014-09-30

    On the I-35W Bridge in Minneapolis, Minnesota, the GATEWAY program conducted a two-phase demonstration of LED roadway lighting on the main span, which is one of the country's oldest continuously operated exterior LED lighting installations. The Phase II report documents longer-term performance of the LED lighting system that was installed in 2008, and is the first report on the longer-term performance of LED lighting in the field.

  6. The I-35W bridge Project Website

    DEFF Research Database (Denmark)

    Kampf, Constance

    How can websites be used to rebuild trust?  In August 2007, the Interstate Highway 35-W bridge in Minneapolis, MN collapsed during rush hour.  Although many people were rescued and casualties were as limited as could be expected due to quick and effective intervention, the image of a major bridge...... collapsing during rush hour damaged the Minnesota Department of Transportation's reputation and resulted in the loss of public trust for the organization.  The ensuing bridge reconstruction project included a project website intended to rebuild this trust through transparency, community involvement......, and the use of multimodal features.  This paper looks at the I35-W bridge reconstruction project in Minneapolis through web-based communication by the Minnesota Department of Transportation (MnDOT) about the project. The MnDOT bridge reconstruction website will be examined using a combination of 1). Weick...

  7. Ferromagnetic exchange in a twisted, oxime-bridged [MnIII2] dimer

    DEFF Research Database (Denmark)

    Houton, Edel; Taylor, Stephanie M.; Beedle, Christopher C.;

    2012-01-01

    The dimeric complex [Mn(III)(2)(Naphth-sao)(2)(Naphth-saoH)(2)(MeOH)(2)]·4MeOH (1·4MeOH), acts as a simple model complex with which to examine the magneto-structural relationship in polymetallic, oxime-bridged Mn(III) complexes. Dc magnetic susceptibility studies reveal that ferromagnetic exchange...

  8. Temporal and spatial variability in water quality of wetlands in the Minneapolis/St. Paul, MN metropolitan area: Implications for monitoring strategies and designs.

    Science.gov (United States)

    Detenbeck, N E; Taylor, D L; Lima, A; Hagley, C

    1996-03-01

    Temporal and spatial variability in wetland water-quality variables were examined for twenty-one wetlands in the Minneapolis/St. Paul metropolitan area and eighteen wetlands in adjacent Wright County. Wetland water quality was significantly affected by contact with the sediment (surface water vs. groundwater), season, degree of hydrologic isolation, wetland class, and predominant land-use in the surrounding watershed (pedaphic factors>detritivory>land-use factors>biotic-redox or other multiple factors.For two wetlands sampled intensively, soluble reactive phosphate and total dissolved phosphorus were the most spatially variable (c.v.=76-249%), while temperature, color, dissolved organic carbon, and DO were least variable (c.v.=6-43%). Geostatistical analyses demonstrated that the average distance across which water-quality variables were spatially correlated (variogram range) was 61-112% of the mean radius of each wetland. Within the shallower of the two wetlands, nitrogen speciation was explained as a function of dissolved oxygen, while deeper marsh water-quality variables were explained as a function of water depth or distance from the wetland edge. Compositing water-quality samples produced unbiased estimates of individual sample means for all water quality variables examined except for ammonium. PMID:24198069

  9. Minneapolis and Saint Paul, Minnesota: Solar in Action (Brochure)

    Energy Technology Data Exchange (ETDEWEB)

    2011-10-01

    This brochure provides an overview of the challenges and successes of Minneapolis, MN, a 2008 Solar America City awardee, on the path toward becoming a solar-powered community. Accomplishments, case studies, key lessons learned, and local resource information are given.

  10. Cyanide- and phenoxo-bridged heterobimetallic Fe(III)-Mn(III) complexes: Synthesis, crystal structures and magnetic properties

    Indian Academy of Sciences (India)

    Daopeng Zhang; Ping Wang; Kexun Chen; Xia Chen

    2014-11-01

    By employing two -tricyanidoiron(III) precursors [Ph4P][FeIII(pcq)(CN)3] and [Ph4P][FeIII (pzq)(CN)3] as building blocks and a salen-tpye Schiff-basemanganese (III) compound as assembling segment, two tetranuclear cyanide- and phenoxo- bridged heterobimetallic Fe(III)-Mn(III) complexes {[Mn(saltmen)] [Fe(pcq)(CN)3]}2·2CH3OH (1) and {[Mn(saltmen)] [Fe(pzq)(CN)3]}2·2CH3OH (2) (pcq = 8-(pyridine-2-carboxamido, pzq = 8-(pyrazine-2-carboxamido, saltmen2− = N,N′-(1,1,2,2-tetramethylethylene)bis(salicylideneaminato) dianion) have been synthesized and characterized by elemental analysis, IR spectroscopy and X-ray structure determination. Single x-ray analysis reveals their isostructural cyanide-bridged Fe(III)-Mn(III) binuclear structure. The binuclear entity is self-complementary through phenoxo oxygen from the neighbouring complex, giving cyanide- and phenoxo- bridged tetranuclear structure. Furthermore, under the help of the intermolecular - interaction, these two complexes can be constructed into 1D infinite chain supramolecular structure. Investigation over magnetic susceptibilities reveals the overall ferromagnetic coupling between the adjacent Fe(III) and Mn(III) ions bridged by cyanide group with = 5.34 cm-1 and 5.55 cm-1 for complexes 1 and 2, respectively.

  11. Minneapolis district-heating options

    Science.gov (United States)

    Stovall, T. K.; Borkowski, R. J.; Karnitz, M. A.; Strom, S.; Linwick, K.

    1981-10-01

    The feasibility of a large-scale district heating system for the Minneapolis central city area was investigated. The analysis was based on a previous city of St. Paul Hot-water district heating study and other studies done by a Swedish engineering firm. Capital costs such as building and heat source conversion, pipeline construction, and equipment were used in comparing the projected expenses of various district heating scenarios. Options such as coal, refuse-derived fuel burning, and cogeneration at the Riverside Power Station were discussed as energy supplies for a cost-effective district heating system.

  12. STUDY ON THE SURFACE CRACK GROWTH BEHAVIOR IN 14MnNbq BRIDGE STEEL

    Institute of Scientific and Technical Information of China (English)

    Yanping Liu; Chuanyao Chen; Guoqing Li

    2010-01-01

    Three-dimensional crack closure correction methods are investigated in this paper.The fatigue crack growth tests of surface cracks in 14MnNbq steel for bridge plate subjected to tensile and bending loadings are systematically conducted.The experimentally measured fatigue crack growth rates of surface cracks are compared with those of through-thickness cracks in detail.It is found that the crack growth rates of surface cracks are lower than those of through-thickness cracks.In order to correct their differences in fatigue crack growth rates,a dimensionless crack closure correction model is proposed.Although this correction model is determined only by the experimental data of surface cracks under tensile loading with a constant ratio R=0.05,it can correlate the surface crack growth rates with reasonable accuracy under tensile and bending loadings with various stress ratios ranging from 0 to 0.5.Furthermore,predictions of fatigue life and crack aspect ratio for surface cracks are discussed,and the predicted results are also compared with those obtained from other prediction approaches.Comparison results show that the proposed crack closure correction model gives better prediction of fatigue life than other models.

  13. Arsenic-bridged magnetic interactions in an emerging two-dimensional FeAs nanostructure on MnAs

    Science.gov (United States)

    Helman, Christian; Ferrari, Valeria; Llois, Ana Maria

    2015-08-01

    The extreme case of an Fe monolayer deposited onto a manganese arsenide (MnAs) substrate is analyzed using density functional theory. We find that an FeAs quasi-two-dimensional antiferromagnetic surface nanostructure emerges. This nanostructure, which is magnetically nearly decoupled from the substrate, is due to bonding effects arising from the arsenic atoms bridging the Fe magnetic interactions. These interactions are studied and modeled using a Heisenberg-type Hamiltonian. They display an angular dependence which is characteristic of superexchange-like interactions, which are of the same order of magnitude as those appearing in Fe-based pnictides.

  14. Tuning of exchange coupling by the Mn-O distance and phenoxido bridging angle: an experimental and theoretical study of the family of Mn(iii) dimers with salen type ligands.

    Science.gov (United States)

    Seth, Piya; Giri, Sanjib; Ghosh, Ashutosh

    2015-07-28

    Three new Mn(III) complexes [Mn2L2(ClO4)2] (1), [Mn2L2(NCS)2] (2) and [Mn2L2N(CN)2]ClO4·CH3CN (3) have been synthesized from the Schiff base ligand H2L (where H2L = N,N′-bis(2-hydroxypropiophenone)-1,2- ethanediamine) and various anionic coligands e.g. perchlorate, thiocyanate and dicyanamide. X-ray crystal structure analysis reveals that 1 and 2 are dinuclear complexes, joined together by Mn⋯O (phenoxido) interactions. Whereas 3 consists of an alternating phenoxido and μ1,5 dicyanamido bridge, resulting in a 1D chain. In 1 and 2 ferromagnetic coupling exists between the Mn(III) centres within the dimer but 3 possesses antiferromagnetic interaction. This difference in magnetic exchange interactions has been rationalized on the basis of structural parameters like longer bridging Mn-O distance and Mn-O-Mn angle in these complexes with the help of DFT calculations. PMID:26102087

  15. Oximato bridged Rh$^{\\text{III}}_2$MII and RhIIIMI species (MII = Mn, Co, Ni; MI = Cu, Ag)

    Indian Academy of Sciences (India)

    Indranil Bhattacharyya; Sanjib Ganguly; Bikash Kumar Panda; Animesh Chakravorty

    2008-01-01

    The reaction of [RhCl2(HPhL)(PhL)] with MII(ClO4)2.6H2O in presence of alkali has furnished trinuclear [RhCl2(PhL)2]2M(H2O)2.H2O (HPhL is phenylazobenzaldoxime; M = Mn, Co, Ni). A similar reaction with MI(PPh3)2NO3 yielded binuclear [RhCl2(PhL)2]M(PPh3)2 (M = Cu, Ag). In these molecules the oximato group acts as a bridge between RhIII (bonded at N) and MII or MI (bonded at O). In structurally characterized [RhIIICl2(PhL)2]2Mn(H2O)2.H2O the centrosymmetric distorted octahedral MnO6 coordination sphere is spanned by four oximato oxygen atoms and two water molecules lying in trans position. In the lattice the neighbouring molecules are held together by H2O$\\cdots$H2O$\\cdots$H2O hydrogen bonds generating infinite zigzag chains. The manganese atoms lie parallel to the C-axis, the shortest Mn…Mn distance being 7.992 Å. Magnetic exchange interactions if any are small as seen in room temperature magnetic moments. The manganese system displays a strong EPR signal near = 2.00. In the complex [RhCl2(PhL)2]Cu(PPh3)2 the copper atom is coordinated to two oximato oxygen atoms and the two phosphorus atoms in a distorted tetrahedral geometry. The softness of the phosphine ligand is believed to sustain the stable coordination of hard oximato oxygen to soft CuI. The coordination sphere of the RhIII atom in both the complexes is uniformly trans-RhN4Cl2.

  16. Synthesis, characterization, and reactivity studies of a water-soluble bis(alkoxo)(carboxylato)-bridged diMn(III) complex modeling the active site in catalase.

    Science.gov (United States)

    Palopoli, Claudia; Duhayon, Carine; Tuchagues, Jean-Pierre; Signorella, Sandra

    2014-12-01

    A new diMn(III) complex, Na[Mn2(5-SO3-salpentO)(μ-OAc)(μ-OMe)(H2O)]·4H2O, where 5-SO3-salpentOH = 1,5-bis(5-sulphonatosalicylidenamino)pentan-3-ol, has been prepared and characterized. ESI-mass spectrometry, paramagnetic (1)H NMR, EPR and UV-visible spectroscopic studies on freshly prepared solutions of the complex in methanol and 9 : 1 methanol-water mixtures showed that the compound retains the triply bridged bis(μ-alkoxo)(μ-acetato)Mn2(3+) core in solution. In the 9 : 1 methanol-water mixture, slow substitution of acetate by water molecules took place, and after one month, the doubly bridged diMn(III) complex, [Mn2(5-SO3-salpentO)(μ-OMe)(H2O)3]·5H2O, formed and could be characterized by X-ray diffraction analysis. In methanolic or aqueous basic media, acetate shifts from a bridging to a terminal coordination mode, affording the highly stable [Mn2(5-SO3-salpentO)(μ-OMe)(OAc)](-) anion. The efficiency of the complex in disproportionating H2O2 depends on the solvent and correlates with the stability of the complex (towards metal dissociation) in each medium: basic buffer > aqueous base > water. The buffer preserves the integrity of the catalyst and the rate of O2 evolution remains essentially constant after successive additions of excess of H2O2. Turnovers as high as 3000 mol H2O2 per mol of catalyst, without significant decomposition and with an efficiency of k(cat)/K(M) = 1028 M(-1) s(-1), were measured for the complex in aqueous buffers of pH 11. Kinetic and spectroscopic results suggest a catalytic cycle that runs between Mn(III)2 and Mn(IV)2 oxidation states, which is consistent with the low redox potential observed for the Mn(III)2/Mn(III)Mn(IV) couple of the catalyst in basic medium.

  17. 78 FR 63861 - Modification of Class B Airspace; Minneapolis, MN

    Science.gov (United States)

    2013-10-25

    ...., Washington, DC 20591; telephone: (202) 267-8783. SUPPLEMENTARY INFORMATION: History On February 14, 2013, the... Class B airspace area (78 FR 10564). This action proposed to expand the lateral boundaries and lower... modifications would impact the Minnesota Soaring Club and Stanton Sport Aviation operations and provided...

  18. The Minneapolis Accountability Project: 1972-1976. Final Report.

    Science.gov (United States)

    Faunce, R.W.; Walen, Tracey

    The Minneapolis Accountability Project was an effort of the Minneapolis Public Schools to provide greater accountability to the public by helping citizens evaluate school programs. Citizens' study groups were provided with staff to help them in a year-long study of a topic selected by a citizen's advisory board. Study committees met weekly…

  19. Integrated solid waste management of Minneapolis, Minnesota

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-11-01

    The subject document reports the results of an in-depth investigation of the fiscal year 1992 cost of the City of Minneapolis, Minnesota (Hennepin County) integrated municipal solid waste management (IMSWM) system, the energy consumed to operate the system, and the environmental performance requirements for each of the system`s waste-processing and disposal facilities. Actual data from records kept by participants is reported in this document. Every effort was made to minimize the use of assumptions, and no attempt is made to interpret the data reported. Analytical approaches are documented so that interested analysts may perform manipulation or further analysis of the data. As such, the report is a reference document for municipal solid waste (MSW) management professionals who are interested in the actual costs and energy consumption for a one-year period, of an operating IMSWM system.

  20. Magnetic exchange interaction via HF 2--bridges? Structure and magnetism of pipzH 2[MnF 4(HF 2)

    Science.gov (United States)

    Bentrup, U.; Harms, K.; Massa, W.; Pebler, J.

    2000-05-01

    pipzH 2[MnF 4(HF 2)] (pipz=piperazine) has been prepared from an aqueous hydrofluoric acid solution of Mn(III) acetate and its crystal structure was determined by single-crystal X-ray analysis: triclinic, space group Poverline11¯, Z=1, a=5.636(1), b=6.151(1), c=6.498(1) Å, α=99.52(1), β=90.62(1), γ=107.43(1)°, wR2=0.063, R=0.023. The structure consists of hitherto unique anionic chains where [MnF 4] units are bridged by HF 2- anions. The resulting [MnF 6] octahedra are strongly elongated, mainly due to the Jahn-Teller effect ( 1.84 Å, MnF ax 2.19 Å). The geometry of the centrosymmetrical bifluoride anion is close to that of KHF 2 (HF 1.14 Å), the angles at the angular bridge MnFH are 111.7°. Surprisingly, magnetic investigations revealed pure paramagnetic behavior. Thus, in contrast to several examples where antiferromagnetic coupling was observed via OH⋯F hydrogen bonds, the very strong hydrogen bonds in the symmetric F⋯H⋯F - anion are obviously not able to mediate magnetic exchange interactions.

  1. X-ray characterization and magnetic properties of dioxygen-bridged Cu(II) and Mn(III) Schiff base complexes.

    Science.gov (United States)

    Yahsi, Yasemin

    2016-07-01

    The coordination chemistry of multinuclear metal compounds is important because of their relevance to the multi-metal active sites of various metalloproteins and metalloenzymes. Multinuclear Cu(II) and Mn(III) compounds are of interest due to their various properties in the fields of coordination chemistry, inorganic biochemistry, catalysis, and optical and magnetic materials. Oxygen-bridged binuclear Mn(III) complexes generally exhibit antiferromagnetic interactions and a few examples of ferromagnetic interactions have also been reported. Binuclear Cu(II) complexes are important due to the fact that they provide examples of the simplest case of magnetic interaction involving only two unpaired electrons. Two novel dioxygen-bridged copper(II) and manganese(III) Schiff base complexes, namely bis(μ-4-bromo-2-{[(3-oxidopropyl)imino]methyl}phenolato)dicopper(II), [Cu2(C10H10BrNO2)2], (1), and bis(diaqua{4,4'-dichloro-2,2'-[(1,1-dimethylethane-1,2-diyl)bis(nitrilomethanylylidene)]diphenolato}manganese(III)) bis{μ-4,4'-dichloro-2,2'-[(1,1-dimethylethane-1,2-diyl)bis(nitrilomethanylylidene)]diphenolato}bis[aquamanganese(III)] tetrakis(perchlorate) ethanol disolvate, [Mn(C18H16Cl2N2O2)(H2O)2]2[Mn2(C18H16Cl2N2O2)2(H2O)2](ClO4)4·2C2H5OH, (2), have been synthesized and single-crystal X-ray diffraction has been used to analyze their crystal structures. The structure analyses of (1) and (2) show that each Cu(II) atom is four-coordinated, with long weak Cu...O interactions of 2.8631 (13) Å linking the dinuclear halves of the centrosymmetric tetranucelar molecules, while each Mn(III) atom is six-coordinated. The shortest intra- and intermolecular nonbonding Mn...Mn separations are 3.3277 (16) and 5.1763 (19) Å for (2), while the Cu...Cu separations are 3.0237 (3) and 3.4846 (3) Å for (1). The magnetic susceptibilities of (1) and (2) in the solid state were measured in the temperature range 2-300 K and reveal the presence of antiferromagnetic spin

  2. Self-assembly of linear [Mn II 2 Mn III ] units with end-on azido bridges: the construction of a ferromagnetic chain using S T = 7 high-spin trimers

    KAUST Repository

    Jiang, Yuan

    2015-01-01

    © The Royal Society of Chemistry 2015. The controlled organization of high-spin complexes into 1D coordination polymers is a challenge in molecular magnetism. In this work, we report a ferromagnetic Mn trimer Mn3(HL)2(CH3OH)6(Br)4·Br·(CH3OH)21 (H2L = 2-[(9H-fluoren-9-yl)amino]propane-1,3-diol) with the ground spin state of ST = 7 that can be assembled into a one-dimensional coordination chain [Mn3(HL)2(CH3OH)2(Br)4(N3)(H2O)·CH3OH]2 using azido bridging ligands. Interestingly, the ferromagnetic nature of 1 is well retained in 2. However, due to the negligible magnetic anisotropy in 1, both 1 and 2 do not show slow-relaxation of magnetization, which indicates that during the process of molecular assembly not only the intratrimer magnetic interaction but also the magnetic anisotropy of the trimer can be reserved.

  3. Minneapolis Multi-Ethnic Curriculum Project--Migration Unit.

    Science.gov (United States)

    Minneapolis Public Schools, Minn. Dept. of Intergroup Education.

    The student booklet presents short chapters illustrating the migration unit of the Minneapolis Multi-Ethnic Curriculum Project for secondary schools. Sixteen brief chapters describe migration, immigration, and emigration in the United States. The first six chapters offer first person accounts of immigrants from Norway, Korea, Egypt, Hitler's…

  4. City of Minneapolis Park & Recreation Summer Youth Report, 1999.

    Science.gov (United States)

    Minnesota State Dept. of Economic Security, St. Paul.

    This report describes youth employment and training programs run by the Minneapolis Park and Recreation Board (MPRB) in summer 1999. The MPRB operates the Teen Teamworks program, which helps teens acquire appreciation for connections between academic, social, judgment, and job skills. MPRB has identified changing social and economic needs as a…

  5. Heterobimetallic oxalato-bridged M(II)Re(IV) complexes (M = Mn, Fe, Co, Ni): synthesis, crystal structure, and magnetic properties.

    Science.gov (United States)

    Chiozzone, Raúl; González, Ricardo; Kremer, Carlos; De Munno, Giovanni; Armentano, Donatella; Lloret, Francesc; Julve, Miguel; Faus, Juan

    2003-02-24

    Four rhenium(IV)-M(II) bimetallic complexes of formula [ReCl(4)(mu-ox)M(dmphen)(2)].CH(3)CN with M = Mn (1), Fe (2), Co (3), and Ni (4) (ox = oxalate anion, dmphen = 2,9-dimethyl-1,10-phenanthroline) have been synthesized and the crystal structures of 1 and 3 determined by single-crystal X-ray diffraction. 1 and 3 are isostructural and crystallize in the monoclinic system, space group P2(1)/c, with a = 16.008(4) A, b = 12.729(2) A, c = 18.909(5) A, beta = 112.70(2) degrees, and Z = 4 for 1 and a = 15.998(4) A, b = 12.665(2) A, c = 18.693(5) A, beta = 112.33(2) degrees, and Z = 4, for 3. The structure of 1 and 3 is made up of neutral [ReCl(4)(mu-ox)M(dmphen)(2)] bimetallic units (M = Mn (1), Co (3)) and acetonitrile molecules of crystallization. M(II) and Re(IV) metal ions exhibit distorted octahedral coordination geometries being bridged by a bis(bidentate) oxalato ligand. The magnetic behavior of 1-4 has been investigated over the temperature range 2.0-300 K. A very weak antiferromagnetic coupling between Re(IV) and Mn(II) occurs in 1 (J = -0.1 cm(-)(1)), whereas a significant ferromagnetic interaction between Re(IV) and M(II) is observed in 2-4 [J = +2.8 (2), +5.2 (3), and +5.9 cm(-)(1) (4)].

  6. Study of Pilot-scale Filtration at Minneapolis Water Works

    OpenAIRE

    Seip, Nils Darre

    2014-01-01

    Minneapolis Water Works (MWW) in Minnesota, United States, have experienced occasional taste and odor episodes with their river water source. This thesis investigates the potential benefits of installing granular activated carbon (GAC) filters at MWW, replacing existing anthracite medium filters and eliminating the need for powdered activated carbon as taste and odor protection. Pilot scale filters of GAC and anthracite media have been studied and batch reactor tests have been performed –...

  7. New family of thiocyanate-bridged Re(IV)-SCN-M(II) (M = Ni, Co, Fe, and Mn) heterobimetallic compounds: synthesis, crystal structure, and magnetic properties.

    Science.gov (United States)

    González, Ricardo; Acosta, Alvaro; Chiozzone, Raúl; Kremer, Carlos; Armentano, Donatella; De Munno, Giovanni; Julve, Miguel; Lloret, Francesc; Faus, Juan

    2012-05-21

    The heterobimetallic complexes of formula [(Me(2)phen)(2)M(μ-NCS)Re(NCS)(5)]·CH(3)CN [Me(2)phen = 2,9-dimethyl-1,10-phenanthroline and M = Ni (1), Co (2), Fe (3), and Mn (4)] have been prepared, and their crystal structures have been determined by X-ray diffraction on single crystals. Compounds 1-4 crystallize in the monoclinic C2/c space group, and their structure consists of neutral [(Me(2)phen)(2)M(μ-NCS)Re(NCS)(5)] heterodinuclear units with a Re-SCN-M bridge. Each Re(IV) ion in this series is six-coordinated with one sulfur and five nitrogen atoms from six thiocyanate groups building a somewhat distorted octahedral environment, whereas the M(II) metal ions are five-coordinated with four nitrogen atoms from two bidentate Me(2)phen molecules and a nitrogen atom from the bridging thiocyanate describing distorted trigonal bipyramidal surroundings. The values of the Re···M separation through the thiocyanate bridge in 1-4 vary in the range 5.903(1)-6.117(3) Å. The magnetic properties of 1-4 as well as those of the parent mononuclear Re(IV) compounds (NBu(4))(2)[Re(NCS)(6)] (A1) (NBu(4)(+) = tetra-n-butylammonium cation) and [Zn(NO(3))(Me(2)phen)(2)](2)[Re(NCS)(5)(SCN)] (A2) were investigated in the temperature range 1.9-300 K. Weak antiferromagnetic interactions between the Re(IV) and M(II) ions across the bridging thiocyanate were found in 1-4 [J = -4.3 (1), -2.4 (2), -1.8 (3), and -1.2 cm(-1) (4), the Hamiltonian being defined as Ĥ = -JŜ(Re)·Ŝ(M)]. The magnetic behavior of A2 is that of a magnetically diluted Re(IV) complex with a large and positive value of the zero-field splitting for the ground level (D(Re) = +37.0 cm(-1)). In the case of A1, although its magnetic behavior is similar to that of A2 in the high-temperature range (D(Re) being +19.0 cm(-1)), it exhibits a weak ferromagnetism below 3.0 K with a canting angle of 1.3°. PMID:22574893

  8. New family of thiocyanate-bridged Re(IV)-SCN-M(II) (M = Ni, Co, Fe, and Mn) heterobimetallic compounds: synthesis, crystal structure, and magnetic properties.

    Science.gov (United States)

    González, Ricardo; Acosta, Alvaro; Chiozzone, Raúl; Kremer, Carlos; Armentano, Donatella; De Munno, Giovanni; Julve, Miguel; Lloret, Francesc; Faus, Juan

    2012-05-21

    The heterobimetallic complexes of formula [(Me(2)phen)(2)M(μ-NCS)Re(NCS)(5)]·CH(3)CN [Me(2)phen = 2,9-dimethyl-1,10-phenanthroline and M = Ni (1), Co (2), Fe (3), and Mn (4)] have been prepared, and their crystal structures have been determined by X-ray diffraction on single crystals. Compounds 1-4 crystallize in the monoclinic C2/c space group, and their structure consists of neutral [(Me(2)phen)(2)M(μ-NCS)Re(NCS)(5)] heterodinuclear units with a Re-SCN-M bridge. Each Re(IV) ion in this series is six-coordinated with one sulfur and five nitrogen atoms from six thiocyanate groups building a somewhat distorted octahedral environment, whereas the M(II) metal ions are five-coordinated with four nitrogen atoms from two bidentate Me(2)phen molecules and a nitrogen atom from the bridging thiocyanate describing distorted trigonal bipyramidal surroundings. The values of the Re···M separation through the thiocyanate bridge in 1-4 vary in the range 5.903(1)-6.117(3) Å. The magnetic properties of 1-4 as well as those of the parent mononuclear Re(IV) compounds (NBu(4))(2)[Re(NCS)(6)] (A1) (NBu(4)(+) = tetra-n-butylammonium cation) and [Zn(NO(3))(Me(2)phen)(2)](2)[Re(NCS)(5)(SCN)] (A2) were investigated in the temperature range 1.9-300 K. Weak antiferromagnetic interactions between the Re(IV) and M(II) ions across the bridging thiocyanate were found in 1-4 [J = -4.3 (1), -2.4 (2), -1.8 (3), and -1.2 cm(-1) (4), the Hamiltonian being defined as Ĥ = -JŜ(Re)·Ŝ(M)]. The magnetic behavior of A2 is that of a magnetically diluted Re(IV) complex with a large and positive value of the zero-field splitting for the ground level (D(Re) = +37.0 cm(-1)). In the case of A1, although its magnetic behavior is similar to that of A2 in the high-temperature range (D(Re) being +19.0 cm(-1)), it exhibits a weak ferromagnetism below 3.0 K with a canting angle of 1.3°.

  9. Crystal structure and spectroscopic analysis of a new oxalate-bridged MnII compound: catena-poly[guanidinium [[aquachloridomanganese(II]-μ2-oxalato-κ4O1,O2:O1′,O2′] monohydrate

    Directory of Open Access Journals (Sweden)

    Hiba Sehimi

    2016-05-01

    Full Text Available As part of our studies on the synthesis and the characterization of oxalate-bridged compounds M–ox–M (ox = oxalate dianion and M = transition metal ion, we report the crystal structure of a new oxalate-bridged MnII phase, {(CH6N3[Mn(C2O4Cl(H2O]·H2O}n. In the compound, a succession of MnII ions (situated on inversion centers adopting a distorted octahedral coordination and bridged by oxalate ligands forms parallel zigzag chains running along the c axis. These chains are interconnected through O—H...O hydrogen-bonding interactions to form anionic layers parallel to (010. Individual layers are held together via strong hydrogen bonds involving the guanidinium cations (N—H...O and N—H...Cl and the disordered non-coordinating water molecule (O—H...O and O—H...Cl, as well as by guanidinium π–π stacking. The structural data were confirmed by IR and UV–Visible spectroscopic analysis.

  10. Crystal structure and spectroscopic analysis of a new oxalate-bridged Mn(II) compound: catena-poly[guanidinium [[aqua-chlorido-manganese(II)]-μ2-oxalato-κ(4) O (1),O (2):O (1'),O (2')] monohydrate].

    Science.gov (United States)

    Sehimi, Hiba; Chérif, Ichraf; Zid, Mohamed Faouzi

    2016-05-01

    As part of our studies on the synthesis and the characterization of oxalate-bridged compounds M-ox-M (ox = oxalate dianion and M = transition metal ion), we report the crystal structure of a new oxalate-bridged Mn(II) phase, {(CH6N3)[Mn(C2O4)Cl(H2O)]·H2O} n . In the compound, a succession of Mn(II) ions (situated on inversion centers) adopting a distorted octa-hedral coordination and bridged by oxalate ligands forms parallel zigzag chains running along the c axis. These chains are inter-connected through O-H⋯O hydrogen-bonding inter-actions to form anionic layers parallel to (010). Individual layers are held together via strong hydrogen bonds involving the guanidinium cations (N-H⋯O and N-H⋯Cl) and the disordered non-coordinating water mol-ecule (O-H⋯O and O-H⋯Cl), as well as by guanidinium π-π stacking. The structural data were confirmed by IR and UV-Visible spectroscopic analysis. PMID:27308028

  11. Synthesis, Crystal Structure and Magnetic Properties of an Oxalato- and Oxamido-bridged One-dimensional Mn( Ⅱ )-Cu( Ⅱ ) Complex%草酸-草酰胺混合桥联Mn(Ⅱ)-Cu(Ⅱ)一维配合物的合成、晶体结构与磁性

    Institute of Scientific and Technical Information of China (English)

    胡孔球; 寇会忠

    2012-01-01

    A new complex, [Cu(L) (H2O)Mn(C2O4) ] ·4H2O(H2L=1,4,8,11-tetraazacyclotetradecane-2,3-dione), was synthesized and structurally characterized by X-ray diffraction. The complex crystallizes in monoclinic space group P21/n with a = 0. 97471(5) run, b = 0.89316(5) ran, c = 2. 35635( 11) nm, β= 92.441(2) ° , V=2.04951(18) run3, Dc = 1.691 Mg/m3, Z=4, R1, =0.0607, wR2=0. 1915(based on F2). The complex consists of [CuL(H2O) ], Mn( Ⅱ ) , oxalate and lattice H2O molecules. Through the alternate oxalate bridges, the Mn( Ⅱ) ions form a zig-zag one-dimensional chain, while the other two coordination sites of the Mn( Ⅱ ) ion are occupied by two oxygen atoms from L2- of [ CuL( H2O) ], giving rise to a mixed oxalate- and oxamido-bridged one-dimensional bimetallic complex. Magnetic studies show the presence of anti-ferromagnetic interaction between the Cu( Ⅱ) and Mn( Ⅱ ) ions and between the adjacent Mn( Ⅱ ) ions. Best fit to the experimental data by means of MAGPACK software gives the magnetic coupling constant of JCu-Mn = -13. 1 cm-1 and /mn-mn= -0. 87 cm-1.%合成了1个草酸-草酰胺混合桥联的双异金属配合物[ Cu(L) (H2O) Mn( C2O4)]·4H2O(H2L为1,4,8,11-四氮杂环十四烷-2,3-二酮).配合物由[Cu(Ⅱ)L(H2O)]、Mn(Ⅱ)、草酸根和晶格水分子构成.Mn(Ⅱ)通过草酸根的交替桥联作用形成弯折的中性一维链状骨架[Mn(C2O4)]n,而Mn(Ⅱ)剩余的2个配位点则由[ CuL]上的2个草酰胺氧原子占据,形成了草酸-草酰胺混合桥联一维双金属配合物.而Cu(Ⅱ)为五配位,轴向上由1个水分子占据.磁研究表明,配合物中Cu(Ⅱ)-Mn(Ⅱ)间通过草酰胺传递反铁磁相互作用,而Mn(Ⅱ)-Mn(Ⅱ)间亦通过草酸根离子存在反铁磁耦合.通过MAGPACK软件对变温磁化率进行拟合,得到JCu-Mn=-13.1 cm-1,JMn-Mn=-0.87 cm-1,g=2.01.

  12. Building America Case Study: Demonstration House of Cold-Climate Solutions for Affordable Housing, Minneapolis, Minnesota

    Energy Technology Data Exchange (ETDEWEB)

    2016-05-01

    Single family homes in urban areas that are available for renovation by nonprofit developers are often in rough shape (1MM to 2MM nationally). Budgeting has historically focused on improving homes to meet basic housing standards. A rising interest in the long-term impact of homeownership has introduced the need to balance basic needs with home performance. This demonstration project aims to help nonprofit affordable housing developers become familiar with three Building America performance measures, the installation processes, and impacts and benefits of each. A story and a half home in North Minneapolis, MN was presented by Urban Homeworks our local nonprofit partner. The team helped them install three researched upgrade measures: exterior roof insulation or 'overcoat,' exterior foundation insulation, or 'excavationless', and a combined space and water heating HVAC system or 'combi'. To maximize efficiency of application and to address budget issues, the Team worked with Urban Homeworks to identify ways to use volunteers and construction training programs to install the measures. An open invitation to visit the job site was extended to other nonprofit developers and industry partners to encourage dialog about the systems during live installation.

  13. Planar Hall effect bridge sensors with NiFe/Cu/IrMn stack optimized for self-field magnetic bead detection

    Science.gov (United States)

    Henriksen, Anders Dahl; Rizzi, Giovanni; Hansen, Mikkel Fougt

    2016-03-01

    The stack composition in trilayer Planar Hall effect bridge sensors is investigated experimentally to identify the optimal stack for magnetic bead detection using the sensor self-field. The sensors were fabricated using exchange-biased stacks Ni80Fe20(tFM)/Cu(tCu)/Mn80Ir20(10 nm) with tFM = 10, 20, and 30 nm, and 0 ≤ tCu ≤ 0.6 nm. The sensors were characterized by magnetic hysteresis measurements, by measurements of the sensor response vs. applied field, and by measurements of the sensor response to a suspension of magnetic beads magnetized by the sensor self-field due to the sensor bias current. The exchange bias field was found to decay exponentially with tCu and inversely with tFM. The reduced exchange field for larger values of tFM and tCu resulted in higher sensitivities to both magnetic fields and magnetic beads. We argue that the maximum magnetic bead signal is limited by Joule heating of the sensors and, thus, that the magnetic stacks should be compared at constant power consumption. For a fixed sensor geometry, the figure of merit for this comparison is the magnetic field sensitivity normalized by the sensor bias voltage. In this regard, we found that sensors with tFM = 20 nm or 30 nm outperformed those with tFM = 10 nm by a factor of approximately two, because the latter have a reduced AMR ratio. Further, the optimum layer thicknesses, tCu ≈ 0.6 nm and tFM = 20-30 nm, gave a 90% higher signal compared to the corresponding sensors with tCu = 0 nm.

  14. Walker Community Library: building underground to serve neighborhood needs. [Minneapolis

    Energy Technology Data Exchange (ETDEWEB)

    Bennett, D.J.

    1980-09-01

    A branch library in Minneapolis was constructed underground in order to meet community needs for public open areas and affordable library space. A review of the site selection and building-design processes reveals a long-standing interaction between the library board, residents of the neighborhood, and consultants to develop a consensus. The money saved by reducing the land area needed for a single-story building more than offset the higher construction costs of roof-top parking. Energy savings are estimated at a 40 percent reduction of the present above-ground facility. The pedestrian terrace connects with an existing mall and provides a setting for neighborhood activities. 6 figures. (DCK)

  15. Visible Light-Induced Electron Transfer from Di-mu-oxo Bridged Dinuclear Mn Complexes to Cr Centers in Silica Nanopores

    Energy Technology Data Exchange (ETDEWEB)

    Frei, Heinz; Weare, Walter W.; Pushkar, Yulia; Yachandra, Vittal K.; Frei, Heinz

    2008-06-03

    The compound (bpy)2MnIII(mu-O)2MnIV(bpy)2, a structural model relevant for the photosynthetic water oxidation complex, was coupled to single CrVI charge-transfer chromophores in the channels of the nanoporous oxide AlMCM-41. Mn K-edge EXAFS spectroscopy confirmed that the di-mu-oxo dinuclear Mn core of the complex is unaffected when loaded into the nanoscale pores. Observation of the 16-line EPR signal characteristic of MnIII(mu-O)2MnIV demonstrates that the majority of the loaded complexes retained their nascent oxidation state in the presence or absence of CrVI centers. The FT-Raman spectrum upon visible light excitation of the CrVI-OII --> CrV-OI ligand-to-metal charge-transfer reveals electron transfer from MnIII(mu-O)2MnIV (Mn-O stretch at 700 cm-1) to CrVI, resulting in the formation of CrV and MnIV(mu-O)2MnIV (Mn-O stretch at 645 cm-1). All initial and final states are directly observed by FT-Raman or EPR spectroscopy, and the assignments corroborated by X-ray absorption spectroscopy measurements. The endoergic charge separation products (DELTA Eo = -0.6 V) remain after several minutes, which points to spatial separation of CrV and MnIV(mu-O)2MnIV as a consequence of hole (OI) hopping as a major contributing mechanism. This is the first observation of visible light-induced oxidation of a potential water oxidation complex by a metal charge-transfer pump in a nanoporous environment. These findings will allow for the assembly and photochemical characterization of well defined transition metal molecular units, with the ultimate goal of performing endothermic, multi-electron transformations that are coupled to visible light electron pumps in nanostructured scaffolds.

  16. Building a municipal food policy regime in Minneapolis: implications for urban climate governance

    OpenAIRE

    Jane E Shey; David Belis

    2013-01-01

    With this paper we analyze Minneapolis’s urban food policy regime and attempt to make a case for applying urban regime theory (URT) to study climate change governance at the municipal level. In 2008 Minneapolis launched Homegrown Minneapolis, a multiple stakeholder initiative bringing together local government actors, businesses, and NGOs to build a sustainable and local food system. As the link between food systems and climate change is increasingly acknowledged in the literature, the analys...

  17. EnviroAtlas - Minneapolis/St. Paul, MN - Estimated Percent Green Space Along Walkable Roads

    Data.gov (United States)

    U.S. Environmental Protection Agency — This EnviroAtlas dataset estimates green space along walkable roads. Green space within 25 meters of the road centerline is included and the percentage is based on...

  18. EnviroAtlas - Minneapolis/St. Paul, MN - Estimated Percent Tree Cover Along Walkable Roads

    Data.gov (United States)

    U.S. Environmental Protection Agency — This EnviroAtlas dataset estimates tree cover along walkable roads. The road width is estimated for each road and percent tree cover is calculated in a 8.5 meter...

  19. 78 FR 10564 - Proposed Modification of Class B Airspace; Minneapolis, MN

    Science.gov (United States)

    2013-02-14

    ... altogether. It felt that flight track data shown to it indicated that the floor at the 25 NM line over SYN... (TCA) (38 FR 34991). As a result of the Airspace Reclassification final rule (56 FR 65638), which..., 2010. In addition, as announced in the Federal Register of January 5, 2011 (76 FR 489), four...

  20. Single-ion anisotropy and exchange interactions in the cyano-bridged trimers MnIII2MIII(CN)6 (MIII = Co, Cr, Fe) species incorporating [Mn(5-Brsalen)]+ units: an inelastic neutron scattering and magnetic susceptibility study.

    Science.gov (United States)

    Tregenna-Piggott, Philip L W; Sheptyakov, Denis; Keller, Lukas; Klokishner, Sophia I; Ostrovsky, Sergei M; Palii, Andrei V; Reu, Oleg S; Bendix, Jesper; Brock-Nannestad, Theis; Pedersen, Kasper; Weihe, Høgni; Mutka, Hannu

    2009-01-01

    The electronic structures of the compounds K[(5-Brsalen)(2)(H(2)O)(2)-Mn(2)M(III)(CN)(6)].2H(2)O (M(III) = Co(III), Cr(III), Fe(III)) have been determined by inelastic neutron scattering (INS) and magnetic susceptibility studies, revealing the manganese(III) single-ion anisotropy and exchange interactions that define the low-lying states of the Mn-M(III)-Mn trimeric units. Despite the presence of an antiferromagnetic intertrimer interaction, the experimental evidence supports the classification of both the Cr(III) and Fe(III) compounds as single-molecule magnets. The value of 17(2) cm(-1) established from AC susceptibility measurements for a spin-reversal barrier of K[(5-Brsalen)(2)(H(2)O)(2)-Mn(2)Cr(CN)(6)].2H(2)O may be readily rationalized in terms of the energy level diagram determined directly by INS. AC susceptibility measurements on samples of K[(5-Brsalen)(2)(H(2)O)(2)-Mn(2)Fe(CN)(6)].2H(2)O are contrary to those previously reported, exhibiting but the onset of peaks below temperatures of 1.8 K at oscillating frequencies in the range of 100-800 Hz. INS measurements reveal an anisotropic ferromagnetic manganese(III)-iron(III) exchange interaction, in accordance with theoretical expectations based on the unquenched orbital angular momentum of the [Fe(CN)(6)](3-) anion, giving rise to an M(s) approximately +/-9/2 ground state, isolated by approximately 11.5 cm(-1) from the higher-lying levels. The reported INS and magnetic data should now serve as a benchmark against which theoretical models that aim to inter-relate the electronic and molecular structure of molecular magnets should be tested. PMID:19035636

  1. 33 CFR 207.320 - Mississippi River, Twin City Locks and Dam, St. Paul and Minneapolis, Minn.; pool level.

    Science.gov (United States)

    2010-07-01

    ... Locks and Dam, St. Paul and Minneapolis, Minn.; pool level. 207.320 Section 207.320 Navigation and... § 207.320 Mississippi River, Twin City Locks and Dam, St. Paul and Minneapolis, Minn.; pool level. In.... 362-Minn., Ford Motor Co.), this section is prescribed for the control of the pool level created...

  2. Single-ion anisotropy and exchange interactions in the cyano-bridged trimers MnIII2MIII(CN)6 (MIII = Co, Cr, Fe) species incorporating [Mn(5-Brsalen)]+ units: an inelastic neutron scattering and magnetic susceptibility study

    DEFF Research Database (Denmark)

    Tregenna-Piggott, Philip L W; Sheptyakov, Denis; Keller, Lukas;

    2009-01-01

    expectations based on the unquenched orbital angular momentum of the [Fe(CN)(6)](3-) anion, giving rise to an M(s) approximately +/-9/2 ground state, isolated by approximately 11.5 cm(-1) from the higher-lying levels. The reported INS and magnetic data should now serve as a benchmark against which theoretical......The electronic structures of the compounds K[(5-Brsalen)(2)(H(2)O)(2)-Mn(2)M(III)(CN)(6)].2H(2)O (M(III) = Co(III), Cr(III), Fe(III)) have been determined by inelastic neutron scattering (INS) and magnetic susceptibility studies, revealing the manganese(III) single-ion anisotropy and exchange...... interactions that define the low-lying states of the Mn-M(III)-Mn trimeric units. Despite the presence of an antiferromagnetic intertrimer interaction, the experimental evidence supports the classification of both the Cr(III) and Fe(III) compounds as single-molecule magnets. The value of 17(2) cm(-1...

  3. 75 FR 34097 - Expansion of Foreign-Trade Zone 119; Minneapolis-St. Paul Area

    Science.gov (United States)

    2010-06-16

    .../21/09); Whereas, notice inviting public comment was given in the Federal Register (74 FR 26652, 6/3... From the Federal Register Online via the Government Publishing Office ] DEPARTMENT OF COMMERCE Foreign-Trade Zones Board Expansion of Foreign-Trade Zone 119; Minneapolis-St. Paul Area Pursuant to...

  4. "Romeo and Juliet" in the Minneapolis Public Schools: Accurate Text or Bowdlerized Text?

    Science.gov (United States)

    Reed, Margaret A.

    In 1984, parents of a Minneapolis, Minnesota, ninth grader came before the school district's "Students' Right to Learn Committee" to object to what they described as a bowdlerized version of "Romeo and Juliet" in the Scott, Foresman text, and the publisher's failure to acknowledge in the text that the play was abridged. The committee concurred…

  5. A Fiscal Analysis of Proposed Education Access Grants in Minneapolis. School Choice Issues in the State

    Science.gov (United States)

    Maas, Ericca

    2005-01-01

    This study examines the fiscal impact of model legislation that would create Education Access Grants in Minnesota. The legislation would provide grants for low-income students to attend private schools. Specifically, this study examines the effect of implementing Education Access Grants in Minneapolis, the state's largest metropolitan area. It…

  6. Screening for Asthma in an Inner-City Elementary School in Minneapolis, Minnesota.

    Science.gov (United States)

    Bauer, Ellen Jones; Lurie, Nicole; Yeh, Carol; Grant, Evalyn N.

    1999-01-01

    Describes schoolwide asthma screening in an inner-city Minneapolis elementary school, discussing the effectiveness and feasibility of the screening efforts. Screening methodology resulted in a simple, noninvasive, efficient approach for identifying children with current asthma in a school setting. The paper proposes how such a screening program…

  7. Music at Lincoln Junior High (Minneapolis) and the Lincoln Junior High Girls' Band: 1923-1940

    Science.gov (United States)

    Hamann, Keitha Lucas

    2010-01-01

    Examination of the music opportunities available to students in the junior high schools of the early twentieth century lends historical perspective to current challenges facing middle level music educators. This article describes the specific music offerings at Lincoln Junior High School in Minneapolis, Minnesota, from the school opening in 1923…

  8. Railroad Bridges

    Data.gov (United States)

    Department of Homeland Security — Bridges-Rail in the United States According to The National Bridge Inspection Standards published in the Code of Federal Regulations (23 CFR 650.3), a bridge isA...

  9. Heterotetranuclear oxalato-bridged Re(IV)3M(II) (M = Mn, Fe, Co, Ni, Cu) complexes: a new example of a single-molecule magnet (M = Ni).

    Science.gov (United States)

    Martínez-Lillo, José; Armentano, Donatella; De Munno, Giovanni; Wernsdorfer, Wolfgang; Clemente-Juan, Juan Modesto; Krzystek, J; Lloret, Francesc; Julve, Miguel; Faus, Juan

    2009-04-01

    The use of the mononuclear species (NBu(4))(2)[Re(IV)Cl(4)(ox)] (NBu(4)(+) = tetra-n-butylammonium cation; ox = oxalate dianion) as a ligand toward fully solvated divalent first-row transition-metal ions affords the tetranuclear complexes (NBu(4))(4)[{Re(IV)Cl(4)(mu-ox)}(3)M(II)] with M = Mn (1), Fe (2), Co (3), Ni (4), and Cu (5). Their structure is made up of discrete [{ReCl(4)(mu-ox)}(3)M](4-) anions and bulky NBu(4)(+) cations. The complexes 2-5 crystallize in the triclinic system with space group P1; 2 and 5 as well as 3 and 4 are isostructural. The Re and M atoms exhibit somewhat distorted ReCl(4)O(2) and MO(6) octahedral surroundings, with the oxalate groups adopting the bis-bidentate bridging mode. Magnetic susceptibility measurements on polycrystalline samples of 1-5 in the temperature range 1.9-300 K show the occurrence of intramolecular antiferromagnetic [J = -1.30 cm(-1) (1)] and ferromagnetic couplings [J = +1.62 (2), +3.0 (3), +16.3 (4), and +4.64 cm(-1) (5)], with the Hamiltonian being defined as H = -J[S(M)(S(Re1) + S(Re2) + S(Re3))]. Compound 4 is the first example of an oxalato-bridged heterometallic species that behaves as a single-molecule magnet with a ground-state spin S = (11)/(2) and D = -0.8(1) cm(-1), as shown by the study of its static and dynamic magnetic properties and a high-frequency electron paramagnetic resonance study on polycrystalline samples together with detailed micro-SQUID measurements on single crystals.

  10. Evaluating the Effects of I-35W Bridge Collapse on Road-Users in the Twin Cities Metropolitan Region

    OpenAIRE

    Feng Xie; David Levinson

    2008-01-01

    This study evaluates the effects of I-35W bridge collapse on road-users in the Minneapolis-St. Paul Metropolitan area. We adopted the seven-County travel demand model developed in previous research, re-calibrated it against July 2007 loop detector traffic data, and used this model to carry out an evaluation of economic loss incurred by increased travel delay in alternative scenarios before and after the bridge collapse. We concluded that the failure of the I-35W bridge resulted in an economic...

  11. Myocardial Bridging

    Directory of Open Access Journals (Sweden)

    Shi-Min Yuan

    2016-02-01

    Full Text Available Abstract Myocardial bridging is rare. Myocardial bridges are most commonly localized in the middle segment of the left anterior descending coronary artery. The anatomic features of the bridges vary significantly. Alterations of the endothelial morphology and the vasoactive agents impact on the progression of atherosclerosis of myocardial bridging. Patients may present with chest pain, myocardial infarction, arrhythmia and even sudden death. Patients who respond poorly to the medical treatment with β-blockers warrant a surgical intervention. Myotomy is a preferred surgical procedure for the symptomatic patients. Coronary stent deployment has been in limited use due to the unsatisfactory long-term results.

  12. Enhancing the magnetic coupling of oxalato-bridged Re(IV)2M(II) (M=Mn, Co, Ni, and Cu) trinuclear complexes via peripheral halide ligand effects.

    Science.gov (United States)

    Martínez-Lillo, José; Mastropietro, Teresa F; De Munno, Giovanni; Lloret, Francesc; Julve, Miguel; Faus, Juan

    2011-06-20

    Four heterotrinuclear Re(IV)(2)M(II) compounds of general formula (NBu(4))(2)[{Re(IV)Br(4)(μ-ox)}(2)M(II)(Him)(2)] [NBu(4)(+) = tetra-n-butylammonium cation, ox = oxalate, Him = imidazole; M = Mn (1), Co (2), Ni (3), and Cu (4)] have been synthesized by using the novel mononuclear complex [Re(IV)Br(4)(ox)](2-) as a ligand toward divalent first-row transition metal ions in the presence of imidazole. Compounds 1-4 are isostructural complexes whose structure contains discrete trinuclear [{Re(IV)Br(4)(μ-ox)}(2)M(II)(Him)(2)](2-) anions and bulky NBu(4)(+) cations. The Re and M atoms are six-coordinated: four peripheral bromo and two oxalate-oxygens (at Re), and two cis-coordinated imidazole molecules and four oxygen atoms from two oxalate ligands (at M), build distorted octahedral surroundings. Two peripheral [ReBr(4)(ox)](2-) units act as bidentate ligands through the oxalate group toward the central [M(II)(Him)(2)] fragment affording the trinuclear entities. The values of the intramolecular Re···M separation are 5.62(1) (1), 5.51(1) (2), 5.46(1) (3), and 5.55(1) Å (4). Magnetic susceptibility measurements on polycrystalline samples of 1-4 in the temperature range of 1.9-300 K show the occurrence of intramolecular antiferro- [J = -1.1 cm(-1) (1)] and ferromagnetic interactions [J = +3.9 (2), +19.7 (3), and +14.4 cm(-1) (4)], the Hamiltonian being defined as Ĥ = -J [Ŝ(M)(Ŝ(Re1) + Ŝ(Re2))]. The larger spin delocalization on the oxalato bridge in 1-4 when compared to the trinuclear Re(IV)(2)M(II) complexes with chloro instead of bromo as peripheral ligands (1'-4') accounts for the strengthening of the magnetic interactions in 1-4 [J = -0.35 (1'), +14.2 (3'), and +7.7 cm(-1) (4')]. An incipient frequency dependence of the out-of-phase ac signals of 3 at very low temperatures is reminiscent of a system with slow relaxation of the magnetization, a phenomenon characteristic of single-molecule magnet behavior.

  13. 76 FR 38975 - Safety Zone; Upper Mississippi River, Mile 856.0 to 855.0, Minneapolis, MN

    Science.gov (United States)

    2011-07-05

    ..., 2011, World Sports and Marketing will sponsor the U.S. Wakeboard Nationals between Mile 856.0 and 855.0... more Indian tribes, on the relationship between the Federal Government and Indian tribes, or on...

  14. 78 FR 29612 - Prevailing Rate Systems; Redefinition of the Minneapolis-St. Paul, MN, and Southwestern Wisconsin...

    Science.gov (United States)

    2013-05-21

    ... Management (OPM) issued a proposed rule (77 FR 75589) to redefine the geographic boundaries of the... Grant Isanti Kanabec Kandiyohi Lac Qui Parle Le Sueur McLeod Martin Meeker Mille Lacs Morrison Mower... Shawano Taylor Vernon Vilas Waupaca Wood * * * * * BILLING CODE 6325-39-P...

  15. Nocturnal Propagating Thunderstorms May Favor Urban "Hot-Spots": A Model-Based Study over Minneapolis

    Science.gov (United States)

    Ganeshan, Manisha; Murtugudde, Raghu

    2015-01-01

    High-resolution WRF model sensitivity experiments are carried out (with and without urban land cover) to study urban impacts on nocturnal propagating thunderstorms over the city of Minneapolis. It is found that the storm spatial characteristics, especially the position of the storm cell, are appreciably altered by the presence of urban land cover. The most robust urban instability during stormy conditions is the enhanced surface convergence due to increased frictional drag. No urban impact is visible on the rainfall intensity simulated by the model. The frictional convergence, aided by the nocturnal Urban Heat Island (UHI), appears to be responsible for attracting propagating storms towards the urban center. Advanced modeling experiments are needed to quantify the mechanical and thermal influence along with similar studies in other cities to further investigate the urban impact on the frequency and trajectory of nocturnal propagating storms.

  16. Bridge Management Systems

    DEFF Research Database (Denmark)

    Thoft-Christensen, Palle

    In this paper bridge management systems are discussed with special emphasis on management systems for reinforced concrete bridges. Management systems for prestressed concrete bridges, steel bridges, or composite bridges can be developed in a similar way.......In this paper bridge management systems are discussed with special emphasis on management systems for reinforced concrete bridges. Management systems for prestressed concrete bridges, steel bridges, or composite bridges can be developed in a similar way....

  17. Programmevaluierung Bridge

    OpenAIRE

    Warta, Katharina; Good, Barbara; Geyer, Anton

    2009-01-01

    BRIDGE is an initiative funded by the Ministry for Transport, Innovation and Technology (BMVIT) that aims to close the “funding gap” between basic and applied research in stand-alone projects with the primary objective of jointly developing the potential of basic and applied research. BRIDGE acts as an  umbrella structure under which the Austrian Science Fund (FWF) and the  Austrian Research Promotion Agency (FFG) coordinate two thematically open funding programmes: The ...

  18. National Bridge Inventory (NBI) Bridges

    Data.gov (United States)

    Department of Homeland Security — The NBI is a collection of information (database) describing the more than 600,000 of the Nation's bridges located on public roads, including Interstate Highways,...

  19. Building Bridges

    DEFF Research Database (Denmark)

    The report Building Bridges adresses the questions why, how and for whom academic audience research has public value, from the different points of view of the four working groups in the COST Action IS0906 Transforming Audiences, Transforming Societies – “New Media Genres, Media Literacy and Trust...... in the Media”, “Audience Interactivity and Participation”, “The Role of Media and ICT Use for Evolving Social Relationships” and “Audience Transformations and Social Integration”. Building Bridges is the result of an ongoing dialogue between the Action and non-academic stakeholders in the field of audience...

  20. Building Bridges

    DEFF Research Database (Denmark)

    The report Building Bridges adresses the questions why, how and for whom academic audience research has public value, from the different points of view of the four working groups in the COST Action IS0906 Transforming Audiences, Transforming Societies – “New Media Genres, Media Literacy and Trust...

  1. Bridged graphite oxide materials

    Science.gov (United States)

    Herrera-Alonso, Margarita (Inventor); McAllister, Michael J. (Inventor); Aksay, Ilhan A. (Inventor); Prud'homme, Robert K. (Inventor)

    2010-01-01

    Bridged graphite oxide material comprising graphite sheets bridged by at least one diamine bridging group. The bridged graphite oxide material may be incorporated in polymer composites or used in adsorption media.

  2. Structure of the Mn complex in photosystem II: Insights from x-ray spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Yachandra, Vittal K.

    2002-04-02

    We have used Mn K-edge absorption and Kb emission spectroscopies to determine the oxidation states of the Mn complex in the various S-states. We have started exploring the new technique of resonant inelastic X-ray scattering spectroscopy (RIXS); this technique can be characterized as a Raman process that uses K-edge energies (1s to 4p, {approx}6550 eV) to obtain L-edge-like spectra (2p to 3d, {approx}650 eV). The relevance of these data to the oxidation states and structure of the Mn complex is presented. We have obtained EXAFS data from the S0 and S3 states and observed heterogeneity in the Mn-Mn distances, leading us to conclude that there may be three rather than two di-(mu)-oxo bridged units present per tetranuclear Mn cluster. In addition, we have obtained data using Ca/Sr X-ray spectroscopy that provide evidence for a heteronuclear Mn/Ca cluster. The possibility of three di-(mu)-oxo-bridged Mn Mn moieties and the proximity of Ca is incorporated into developing structural models for the Mn cluster. The involvement of bridging and terminal O ligands of Mn in the mechanism of oxygen evolution is discussed in the context of our X-ray spectroscopy results.

  3. A rational design for imidazolate-bridged linear trinuclear compounds from mononuclear copper(II) complexes with 2-[((imidazol-2-ylmethylidene)amino)ethyl]pyridine (HL): syntheses, structures, and magnetic properties of [Cu(L)(hfac)M(hfac)2Cu(hfac)(L)] (M = ZnII, CuII, MnII).

    Science.gov (United States)

    Colacio, E; Ghazi, M; Kivekäs, R; Klinga, M; Lloret, F; Moreno, J M

    2000-06-26

    Two mononuclear copper(II) complexes with the unsymmetrical tridentate ligand 2-[((imidazol-2-ylmethylidene)amino)ethyl]pyridine (HL), [Cu(HL)(H2O)](ClO4)2.2H2O (1) and [Cu(HL)Cl2] (2), have been prepared and characterized. The X-ray analysis of 2 revealed that the copper(II) ion assumes a pentacoordinated square pyramidal geometry with an N3Cl2 donor set. When 1 and 2 are treated with an equimolecular amount of potassium hydroxide, the deprotonation of the imidazole moiety promotes a self-assembled process, by coordination of the imidazolate nitrogen atom to a Cu(II) center of an adjacent unit, leading to the polynuclear complexes [[Cu(L)(H2O)](ClO4)]n (3) and [[Cu(L)Cl].2H2O]n (4). Variable-temperature magnetic data are well reproduced for one-dimensional infinite regular chain systems with J = -60.3 cm(-1) and g = 2.02 for 3 and J = -69.5 cm(-1) and g = 2.06, for 4. When 1 is used as a "ligand complex" for [M(hfac)2] (M = Cu(II), Ni(II), Mn(II), Zn(II)) in a basic medium, only the imidazolate-bridged trinuclear complexes [Cu(L)(hfac)M(hfac)2Cu(hfac)(L)] (M = Zn(II), Cu(II)) (5, 6) can be isolated. Nevertheless, the analogous complex containing Mn(II) as the central metal (7) can be prepared from the precursor [Cu(HL)Cl2] (2). All the trinuclear complexes are isostructural. The structures of 5 and 6 have been solved by X-ray crystallographic methods and consist of well-isolated molecules with Ci symmetry, the center of symmetry being located at the central metal. Thus, the copper(II) fragments are in trans positions, leading to a linear conformation. The magnetic susceptibility data (2-300 K), which reveal the occurrence of antiferromagnetic interactions between copper(II) ions and the central metal, were quantitatively analyzed for symmetrical three-spin systems to give the coupling parameters JCuCu = -37.2 and JCuMn = -3.7 cm(-1) with D = +/-0.4 cm(-1) for 6 and 7, respectively. These magnetic behaviors are compared with those for analogous systems and

  4. Enhanced Mn2+ emission in ZnS:Mn nanoparticles by surface plasmon resonance of gold nanoparticles

    Science.gov (United States)

    Zhou, Shuyao; Chu, Xueying; Li, Jinhua; Fang, Fang; Fang, Xuan; Wei, Zhipeng; Chen, Feng; Wang, Xiaohua

    2014-07-01

    The Mn2+ emission of ZnS:Mn nanoparticles was enhanced by a simple procedure. 3-Mercaptopropionic acid was used as a complexing agent in the synthesis of ZnS:Mn nanoparticles. Sulfydryl groups of 3-mercaptopropionic acid acted as bridging groups, to form composites of ZnS:Mn and Au nanoparticles. The peak wavelength of Au surface plasmons was red-shifted by 5 nm upon compositing. The intensity of Mn2+ emission at 590 nm because of the 4T1-6A1 transition was enhanced by 469% from the effects of the surface plasmon resonance. The enhancement was greatly influenced by the ratio of ZnS:Mn and Au. Enhancement was primarily attributed to localized surface plasmon resonance on the Au nanoparticle surface.

  5. Colloid particle sizes in the Mississippi River and some of its tributaries, from Minneapolis to below New Orleans

    Science.gov (United States)

    Rostad, C.E.; Rees, T.F.; Daniel, S.R.

    1998-01-01

    An on-board technique was developed that combined discharge-weighted pumping to a high-speed continuous-flow centrifuge for isolation of the particulate-sized material with ultrafiltration for isolation of colloid-sized material. In order to address whether these processes changed the particle sizes during isolation, samples of particles in suspension were collected at various steps in the isolation process to evaluate changes in particle size. Particle sizes were determined using laser light-scattering photon correlation spectroscopy and indicated no change in size during the colloid isolation process. Mississippi River colloid particle sizes from twelve sites from Minneapolis to below New Orleans were compared with sizes from four tributaries and three seasons, and from predominantly autochthonous sources upstream to more allochthonous sources downstream. ?? 1998 John Wiley Sons, Ltd.

  6. Cable Supported Bridges

    DEFF Research Database (Denmark)

    Gimsing, Niels Jørgen

    Cable supported bridges in the form of suspension bridges and cable-stayed bridges are distinguished by their ability to overcome large spans.The book concentrates on the synthesis of cable supported bridges, covering both design and construction aspects. The analytical part covers simple methods...... to quantify the different structural configurations and allows a preliminary optimization of the main structure.Included are the most recent advances in structural design, corrosion protection of cables, aerodynamic safety, and erection procedures....

  7. Structures of Mn clusters

    Indian Academy of Sciences (India)

    Tina M Briere; Marcel H F Sluiter; Vijay Kumar; Yoshiyuki Kawazoe

    2003-01-01

    The geometries of several Mn clusters in the size range Mn13–Mn23 are studied via the generalized gradient approximation to density functional theory. For the 13- and 19-atom clusters, the icosahedral structures are found to be most stable, while for the 15-atom cluster, the bcc structure is more favoured. The clusters show ferrimagnetic spin configurations.

  8. Photomagnetism in cyano-bridged bimetal assemblies.

    Science.gov (United States)

    Ohkoshi, Shin-ichi; Tokoro, Hiroko

    2012-10-16

    The study of photoinduced phase-transition materials has implications for the fields of inorganic chemistry, solid-state chemistry, and materials science. Cyano-bridged bimetal assemblies are promising photomagnetic materials. Because cyano-bridged bimetal assemblies possess various absorption bands in the visible light region, their electronic and spin states can be controlled by visible light irradiation. Moreover, the selection of magnetic metal ions and organic ligands provide a way of controlling spin-spin interactions through a cyano bridge. In this Account, we describe cyano-bridged bimetal assemblies developed in our laboratory. Cu(II)(2)[Mo(IV)(CN)(8)]·8H(2)O (CuMo), Rb(I)Mn(II)[Fe(III)(CN)(6)] (RbMnFe), and Co(II)(3)[W(V)(CN)(8)](2)·(pyrimidine)(4)·6H(2)O (CoW) induce photomagnetism via photoinduced metal-to-metal charge transfers (MM'CT), while Fe(II)(2)[Nb(IV)(CN)(8)]·(4-pyridinealdoxime)(8)·2H(2)O (FeNb) exhibits a photoinduced magnetization via a photoinduced spin crossover. Irradiation with 473 nm light causes the CuMo system to exhibit a spontaneous magnetization with a Curie temperature (T(C)) of 25 K, but irradiation with 532, 785, and 840 nm light reduces the magnetization. In this reversible photomagnetic process, excitation of the MM'CT from Mo(IV) to Cu(II) produces a ferromagnetic mixed-valence isomer of Cu(I)Cu(II)[Mo(V)(CN)(8)]·8H(2)O (CuMo'). CuMo' returns to CuMo upon irradiation in the reverse-M'MCT band. RbMnFe shows a charge transfer (CT)-induced phase transition from the Mn(II)-Fe(III) phase to the Mn(III)-Fe(II) phase. Irradiation with 532 nm light converts the Mn(III)-Fe(II) phase into the Mn(II)-Fe(III) phase, and we observe photodemagnetization. In contrast, irradiation of the Mn(II)-Fe(III) phase with 410 nm light causes the reverse phase transition. A CT-induced Jahn-Teller distortion is responsible for this visible light-induced reversible photomagnetic effect. In the CoW system, a CT-induced spin transition causes the

  9. Taizhou Yangtze River Bridge

    Institute of Scientific and Technical Information of China (English)

    2012-01-01

    Taizhou Bridge lies between Taizhou, Zhenjiang and Changzhou City in Jiangsu Province. The total length of Taizhou Bridge is 62.088 kin. The whole line is designed by freeway codes with six lanes in two directions. The wholeinvestment is 9.37 billion RMB and the planned construction duration is 5.5 years. The main bridge crossing the Yangtze River is a continuous three-pylon two-span suspension bridge with the main span of 1 080 m. The bridge system is realized for the first time and ranks first in the world until now.

  10. Concrete bridge prioritization system

    OpenAIRE

    Kesselring, Debbie Anne

    1995-01-01

    An alternative method of prioritization for concrete bridge maintenance, repair, and rehabilitation activities is required due to the inability of the current system to manage the increasing nmnber of aging concrete bridges. The Concrete Bridge Prioritization System was proposed because of its ability to address the critical technical parameters of safety and cost benefit in prioritization of funding and work allocation. The analysis includes four parts, service life assessment, s...

  11. Bridging the Gap

    DEFF Research Database (Denmark)

    Kramer Overgaard, Majken; Broeng, Jes; Jensen, Monika Luniewska;

    Bridging the Gap (BtG) is a 2-year project funded by The Danish Industry Foundation. The goal of Bridging the Gap has been to create a new innovation model which will increase the rate at which Danish universities can spinout new technology ventures.......Bridging the Gap (BtG) is a 2-year project funded by The Danish Industry Foundation. The goal of Bridging the Gap has been to create a new innovation model which will increase the rate at which Danish universities can spinout new technology ventures....

  12. Bridging the Gap

    OpenAIRE

    Kramer Overgaard, Majken; Broeng, Jes; Jensen, Monika Luniewska; Murdock, Karen; Schmidt, Iben Julie

    2015-01-01

    Bridging the Gap (BtG) is a 2-year project funded by The Danish Industry Foundation. The goal of Bridging the Gap has been to create a new innovation model which will increase the rate at which Danish universities can spinout new technology ventures. Bridging the Gap (BtG) is a 2-year project funded by The Danish Industry Foundation. The goal of Bridging the Gap has been to create a new innovation model which will increase the rate at which Danish universities can spinout new technology ve...

  13. Semiconductor bridge (SCB) detonator

    Science.gov (United States)

    Bickes, Jr., Robert W.; Grubelich, Mark C.

    1999-01-01

    The present invention is a low-energy detonator for high-density secondary-explosive materials initiated by a semiconductor bridge igniter that comprises a pair of electrically conductive lands connected by a semiconductor bridge. The semiconductor bridge is in operational or direct contact with the explosive material, whereby current flowing through the semiconductor bridge causes initiation of the explosive material. Header wires connected to the electrically-conductive lands and electrical feed-throughs of the header posts of explosive devices, are substantially coaxial to the direction of current flow through the SCB, i.e., substantially coaxial to the SCB length.

  14. Principles of Bridge Reliability

    DEFF Research Database (Denmark)

    Thoft-Christensen, Palle; Nowak, Andrzej S.

    The paper gives a brief introduction to the basic principles of structural reliability theory and its application to bridge engineering. Fundamental concepts like failure probability and reliability index are introduced. Ultimate as well as serviceability limit states for bridges are formulated...

  15. The floating water bridge

    International Nuclear Information System (INIS)

    When high voltage is applied to distilled water filled in two glass beakers which are in contact, a stable water connection forms spontaneously, giving the impression of a floating water bridge. A detailed experimental analysis reveals static and dynamic structures as well as heat and mass transfer through this bridge

  16. Bridge technology report

    CERN Document Server

    2013-01-01

    Please note this is a Short Discount publication. As LANs have proliferated, new technologies and system concepts have come to the fore. One of the key issues is how to interconnect networks. One means of interconnection is to use a 'bridge'. Other competing technologies are repeaters, routers, and gateways. Bridges permit traffic isolation, connect network segments together and operate at the MAC layer. Further, because they operate at the MAC layer, they can handle a variety of protocols such as TCP/IP, SNA, and X.25. This report focuses on the specific technology of bridging two netw

  17. Bridged Race Population Estimates

    Data.gov (United States)

    U.S. Department of Health & Human Services — Population estimates from "bridging" the 31 race categories used in Census 2000, as specified in the 1997 Office of Management and Budget (OMB) race and ethnicity...

  18. Long Span Bridges in Scandinavia

    DEFF Research Database (Denmark)

    Gimsing, Niels Jørgen

    1998-01-01

    The first Scandinavian bridge with a span of more than 500 m was the Lillebælt Suspension Bridge opened to traffic in 1970.Art the end of the 20th century the longest span of any European bridge is found in the Storebælt East Bridge with a main span of 1624 m. Also the third longest span in Europ...

  19. Integral Abutment and Jointless Bridges

    OpenAIRE

    Cristian-Claudiu Comisu

    2005-01-01

    Integral bridges, or integral abutment and jointless bridges, as they are more commonly known in the USA, are constructed without any movement joints between spans or between spans and abutments. Typically these bridges have stub-type abutments supported on piles and continuous bridge deck from one embankment to the other. Foundations are usually designed to be small and flexible to facilitate horizontal movement or rocking of the support. Integrally bridges are simple or multiple span ones t...

  20. One-pot synthesis of an Mn(III)-Cu(II)-Mn(III) trinuclear heterometallic compound formed by Mn$\\cdots$S-Cu-S$\\cdots$Mn supramolecular interactions: Crystal structure of [{MnIII(salph)(H2O)}2{CuII(mnt)2}]$\\cdot$4DMF

    Indian Academy of Sciences (India)

    Vedichi Madhu; Samar K Das

    2006-11-01

    A one-pot synthesis, that includes CuCl2$\\cdot$2H2O, Na2mnt, H2salph and Mn(CH3COO)3$\\cdot$H2O, leads to the isolation of a trinuclear heterometallic compound [{MnIII(salph)(H2O)}2{CuII(mnt)2}]$\\cdot$4DMF (1) formed by Mn$\\cdots$S-Cu-S$\\cdots$Mn supramolecular interactions. Compound 1 crystallizes in the monoclinic space group 21/ with = 13.433(4), = 16.283(5), = 15.072(4) Å, = 107.785(4)°, = 2. In the crystal structure, the complex anion [CuII(mnt)2]2- bridges two [MnIII(salph)(H2O)]1+ cations through Mn$\\cdots$S contacts. The non-covalent hydrogen bonding and - interactions among the trinuclear [{MnIII(salph)(H2O)}2{CuII(mnt)2}] complexes lead to an extended chain-like arrangement of [MnIII(salph) (H2O)]1+ cations with [CuII(mnt)2]2- anions embedded in between these chains.

  1. Istanbul Bridge Conference 2014

    CERN Document Server

    Gülkan, Polat; Mahmoud, Khaled

    2016-01-01

      The book includes peer-reviewed contributions selected from presentations given at the Istanbul Bridge Conference 2014, held from August 11 – 13 in Istanbul, Turkey. It reports on the current challenges in bridge engineering faced by professionals around the globe, giving a special emphasis to recently developed techniques, innovations and opportunities. The book covers key topics in the field, including modeling and analysis methods; construction and erection techniques; design for extreme events and condition assessment and structural health monitoring. There is a balanced presentation of theory, research and practice. This book, which provides the readers with a comprehensive and timely reference guide on current practices in bridge engineering, is intended for professionals, academic researchers and students alike.

  2. Active Control of Suspension Bridges

    DEFF Research Database (Denmark)

    Thoft-Christensen, Palle

    In this paper some recent research on active control of very long suspension bridges, is presented. The presentation is based on research work at Aalborg University, Denmark. The active control system is based on movable flaps attached to the bridge girder. Wind load on bridges with or without...... flaps attached to the girder is briefly presented. A simple active control system is discussed. Results from wind tunnel experiments with a bridge section show that flaps can be used effectively to control bridge girder vibrations. Flutter conditions for suspension bridges with and without flaps...

  3. Structural stability, half-metallicity and magnetism of the CoFeMnSi/GaAs(0 0 1) interface

    Energy Technology Data Exchange (ETDEWEB)

    Feng, Yu; Chen, Xiaorui; Zhou, Ting; Yuan, Hongkuan; Chen, Hong, E-mail: chenh@swu.edu.cn

    2015-08-15

    Highlights: • CoFeMnSi is one of LiMgPbSb-type Heusler alloy. • The phase diagram of various investigated interfaces is calculated. • Top-type MnMn-terminated interface preserves perfect 100% spin polarization. - Abstract: The ferromagnet/semiconductor interface plays a crucial role in the performance of advanced magnetic tunnel junctions (MTJs) built of ferromagnetic electrodes and semiconductor as a spacer. We investigate the interface character between LiMgPbSb-type Heusler alloy CoFeMnSi and semiconductor GaAs by using the first-principles density functional simulations. In our calculations, we build two kinds of interface structures, namely the top-type and the bridge-type structure by connecting the termination of nine CoFeMnSi layers to the top of the As-terminated GaAs layer and the bridge site between interface As atoms, respectively. The calculated phase diagram indicated that the CoFe-terminated interface is more stable in the bridge-type structure than in the top-type structure, and a favored MnMn- or MnSi-terminated interface will appear in the top-type structure instead of the bridge-type structure under Fe-rich conditions. Besides, our calculation reveals that interface Mn and interface Fe atoms prefer to extend outward and their atom-resolved spin magnetic moments are enhanced due to the rehybridization caused by the symmetry breaking at the interface, while interface Co atoms shrink inward and their moments are decreased compared with the bulk value. Further analysis on DOS and PDOS indicates that owing to the interface effect, the half metallicity of CoFe-, MnSi-, and SiSi-terminated interfaces is completely destroyed. However, the MnMn-terminated interface in the top-type structure preserves 100% spin polarization, indicating that the CoFeMnSi/GaAs heterostructure with the top-type MnMn-terminated interface has more advantages than other atomic terminations in spintronics applications.

  4. High-Resolution Mn EXAFS of the Oxygen-Evolving Complex inPhotosystem II: Structural Implications for the Mn4Ca Cluster

    Energy Technology Data Exchange (ETDEWEB)

    Yano, Junko; Pushkar, Yulia; Glatzel, Pieter; Lewis, Azul; Sauer,Kenneth; Messinger, Johannes; Bergmann, Uwe; Yachandra, Vittal

    2005-09-06

    The biological generation of oxygen by the oxygen-evolving complex in photosystem II (PS II) is one of natures most important reactions. The recent X-ray crystal structures, while limited by resolutions of 3.2 to 3.5 A, have located the electron density associated with the Mn4Ca complex within the multi-protein PS II complex. Detailed structures critically depend on input from spectroscopic techniques such as EXAFS and EPR/ENDOR, as the XRD resolution does not allow for accurate determination of the position of Mn/Ca or the bridging and terminal ligand atoms. The number and distances of Mn-Mn/Ca/ligand interactions determined from EXAFS provide important constraints for the structure of the Mn cluster. Here we present data from a high-resolution EXAFS method using a novel multi-crystal monochromator that show three short Mn-Mn distances between 2.7 and 2.8 A and hence the presence of three di-mu-oxobridged units in the Mn4Ca cluster. This result imposes clear limitations on the proposed structures based on spectroscopic and diffraction data and provides input for refining such structures.

  5. A possible evolutionary origin for the Mn4 cluster of the photosynthetic water oxidation complex from natural MnO2 precipitates in the early ocean

    Energy Technology Data Exchange (ETDEWEB)

    Sauer, Kenneth; Yachandra, Vittal K.

    2002-04-30

    The photosynthetic water oxidation complex consists of a cluster of 4 Mn atoms bridged by O atoms, associated with Ca2+ and Cl- and incorporated into protein. The structure is similar in higher plants and algae, as well as in cyanobacteria of more ancient lineage, dating back more than 2.5 Ga on Earth. It has been proposed that the proto-enzyme derived from a component of a natural early marine manganese precipitate that contained a CaMn4O9 cluster. A variety of MnO2 minerals is found in nature. Three major classes are spinels, sheet-like layered structures and 3-dimensional networks that contain parallel tunnels. These relatively open structures readily incorporate cations (Na+, Li+, Mg2+, Ca2+, Ba2+, H+ and even Mn2+) and water. The minerals have different ratios of Mn(III) and Mn(IV) octahedrally coordinated to oxygens. Using X-ray spectroscopy we compare the chemical structures of Mn in the minerals with what is known about the arrangement in the water-oxidation complex to define the parameters of a structural model for the photosynthetic catalytic site. This comparison provides for the structural model a set of candidate Mn4 clusters -- some previously proposed and considered and others entirely novel.

  6. Quantum Bidding in Bridge

    Science.gov (United States)

    Muhammad, Sadiq; Tavakoli, Armin; Kurant, Maciej; Pawłowski, Marcin; Żukowski, Marek; Bourennane, Mohamed

    2014-04-01

    Quantum methods allow us to reduce communication complexity of some computational tasks, with several separated partners, beyond classical constraints. Nevertheless, experimental demonstrations of this have thus far been limited to some abstract problems, far away from real-life tasks. We show here, and demonstrate experimentally, that the power of reduction of communication complexity can be harnessed to gain an advantage in a famous, immensely popular, card game—bridge. The essence of a winning strategy in bridge is efficient communication between the partners. The rules of the game allow only a specific form of communication, of very low complexity (effectively, one has strong limitations on the number of exchanged bits). Surprisingly, our quantum technique does not violate the existing rules of the game (as there is no increase in information flow). We show that our quantum bridge auction corresponds to a biased nonlocal Clauser-Horne-Shimony-Holt game, which is equivalent to a 2→1 quantum random access code. Thus, our experiment is also a realization of such protocols. However, this correspondence is not complete, which enables the bridge players to have efficient strategies regardless of the quality of their detectors.

  7. Bridge of Light

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    Lying gleaming white under a brooding sky,the Lhasa River Railway Bridge forms a gate to Lhasa City.Built as a part of Qinghai-Tibet Railway,on July 1,2011, the highest altitude railway in the world has been in service for five years. Lhasa,Tibet

  8. Bridge over troubled water?

    DEFF Research Database (Denmark)

    Svendsen, Gunnar Lind Haase; Nannestad, Peter; Svendsen, Gert Tinggaard

    2008-01-01

    The problem of integrating non-Western immigrants into Western welfare states is the focus of this paper. To address this issue, we suggest a social capital approach in which we apply the conceptual pair of bridging social capital (BR), which connects an individual to the broader social structure...

  9. Building Bridges to China.

    Science.gov (United States)

    Wasta, Stephanie; Scott, Margaret

    1998-01-01

    Describes a theme cycle called "Building Bridges to China" developed for third grade students that focuses on the similarities between the lives of children and families in China and the United States. Explains that the theme cycle addresses the National Geography Standards and three of the National Council for the Social Studies standards. (CMK)

  10. A low-noise ac-bridge amplifier for ballistocardiogram measurement on an electronic weighing scale

    International Nuclear Information System (INIS)

    Ballistocardiography is a non-invasive technique for evaluating cardiovascular health. This note presents an ac-bridge amplifier for low-noise ballistocardiogram (BCG) recording from a modified weighing scale. The strain gauges in a commercial scale were excited by an ac source—square or sine wave—and the differential output voltage resulting from the BCG was amplified and demodulated synchronously with the excitation waveform. A standard BCG amplifier, with a simple dc-bridge excitation, was also built and the performance was compared to both the square- and sine-wave excited ac-bridge amplifiers. The total input-referred voltage noise (rms) integrated over the relevant BCG bandwidth of 0.3–10 Hz was found to be 30 nV (square wave source) or 25 nV (sine-wave source) for the ac-bridge amplifier and 52 nV for the standard amplifier: an improvement of 4.8 dB or 6 dB, respectively. These correspond to input-referred force noise (rms) values of 5 mN, 4 mN and 8.3 mN. The improvement in SNR was also observed in recorded waveforms from a seated subject whose BCG signal was measured with both dc- and ac-bridge circuits. (note)

  11. Revised Rules for Concrete Bridges

    DEFF Research Database (Denmark)

    Thoft-Christensen, Palle; Jensen, F. M.; Middleton, C.;

    This paper is based on research performed for the Highway Agency, London, UK under the project DPU/9/44 "Revision of Bridge Assessment Rules Based on Whole Life Performance: Concrete Bridges" It contains details of a methodology which can be used to generate Whole Life (WL) reliability profiles....... These WL reliability profiles may be used to establish revised rules for Concrete Bridges....

  12. Energy levels of 56Mn

    DEFF Research Database (Denmark)

    Van Assche, P. H. M.; Baader, H. A.; Koch, H. R.;

    1971-01-01

    The low-energy spectrum of the 55Mn(n,γ)56 Mn reaction has been studied with a γ-diffraction spectrometer. These data allowed the construction of a level scheme for 56Mn with two previously unobserved doublets. High-energy γ-transitions to the low-energy states have been measured for different...

  13. Dynamic Bridge Response for a Bridge-friendly Truck

    Directory of Open Access Journals (Sweden)

    V. Šmilauer

    2004-01-01

    Full Text Available A truck with controlled semi-active suspensions traversing a bridge is examined for benefits to the bridge structure. The original concept of a road-friendly truck was extended to a bridge-friendly vehicle, using the same optimization tools. A half-car model with two independently driven axles is coupled with simply supported bridges (beam, slab model with the span range from 5 m to 50 m. Surface profile of the bridge deck is either stochastic or in the shape of a bump or a pot in the mid-span. Numerical integration in the MATLAB/SIMULINK environment solves coupled dynamic equations of motion with optimized truck suspensions. The rear axle generates the prevailing load and to a great extent determines the bridge response. A significant decrease in contact road-tire forces is observed and the mid-span bridge deflections are on average smaller, when compared to commercial passive suspensions. 

  14. MnBr2/18-crown-6 coordination complexes showing high room temperature luminescence and quantum yield.

    Science.gov (United States)

    Hausmann, David; Kuzmanoski, Ana; Feldmann, Claus

    2016-04-12

    The reaction of manganese(ii) bromide and the crown ether 18-crown-6 in the ionic liquid [(n-Bu)3MeN][N(Tf)2] under mild conditions (80-130 °C) resulted in the formation of three different coordination compounds: MnBr2(18-crown-6) (), Mn3Br6(18-crown-6)2 () and Mn3Br6(18-crown-6) (). In general, the local coordination and the crystal structure of all compounds are driven by the mismatch between the small radius of the Mn(2+) cation (83 pm) and the ring opening of 18-crown-6 as a chelating ligand (about 300 pm). This improper situation leads to different types of coordination and bonding. MnBr2(18-crown-6) represents a molecular compound with Mn(2+) coordinated by two bromine atoms and only five oxygen atoms of 18-crown-6. Mn3Br6(18-crown-6)2 falls into a [MnBr(18-crown-6)](+) cation - with Mn(2+) coordinated by six oxygen atoms and Br - and a [MnBr(18-crown-6)MnBr4](-) anion. In this anion, Mn(2+) is coordinated by five oxygen atoms of the crown ether as well as by two bromine atoms, one of them bridging to an isolated (MnBr4) tetrahedron. Mn3Br6(18-crown-6), finally, forms an infinite, non-charged [Mn2(18-crown-6)(MnBr6)] chain. Herein, 18-crown-6 is exocyclically coordinated by two Mn(2+) cations. All compounds show intense luminescence in the yellow to red spectral range and exhibit remarkable quantum yields of 70% (Mn3Br6(18-crown-6)) and 98% (Mn3Br6(18-crown-6)2). The excellent quantum yield of Mn3Br6(18-crown-6)2 and its differentiation from MnBr2(18-crown-6) and Mn3Br6(18-crown-6) can be directly correlated to the local coordination. PMID:26956783

  15. Structural Changes in the Mn4Ca Cluster and the Mechanism of Photosynthetic Water Splitting

    Energy Technology Data Exchange (ETDEWEB)

    Pushkar, Y.; Yano, J.; Sauer, K.; Boussac, A.; Yachandra, V.K.

    2007-10-25

    Photosynthetic water oxidation, where water is oxidized to dioxygen, is a fundamental chemical reaction that sustains the biosphere. This reaction is catalyzed by a Mn4Ca complex in the photosystem II (PS II) oxygen-evolving complex (OEC): a multiproteinassembly embedded in the thylakoid membranes of green plants, cyanobacteria, and algae. The mechanism of photosynthetic water oxidation by the Mn4Ca cluster in photosystem II is the subject of much debate, although lacking structural characterization of the catalytic intermediates. Biosynthetically exchanged Ca/Sr-PS II preparations and x-ray spectroscopy, including extended x-ray absorption fine structure (EXAFS), allowed us to monitor Mn-Mn and Ca(Sr)-Mn distances in the four intermediate S states, S0 through S3, of the catalytic cycle that couples the one-electron photochemistry occurring at the PS II reaction center with the four-electron water-oxidation chemistry taking place at the Mn4Ca(Sr) cluster. We have detected significant changes in the structure of the complex, especially in the Mn-Mn and Ca(Sr)-Mn distances, on the S2-to-S3 and S3-to-S0 transitions. These results implicate the involvement of at least one common bridging oxygen atom between the Mn-Mn and Mn-Ca(Sr) atoms in the O-O bond formation. Because PS II cannot advance beyond the S2 state in preparations that lack Ca(Sr), these results show that Ca(Sr) is one of the critical components in the mechanism of the enzyme. The results also show that Ca is not just a spectator atom involved in providing a structural framework, but is actively involved in the mechanism of water oxidation and represents a rare example of a catalytically active Ca cofactor.

  16. [Retention of adhesive bridges].

    Science.gov (United States)

    Raes, F; De Boever, J

    1994-04-01

    Since the development of adhesive bridges in the early seventies, the retention and therefore the durability of these bridges has been tremendously improved. Conditioning of the non-precious metal by silanisation, careful acid etching of the enamel and the use of the appropriate composite resin are of prime importance. Furthermore, the meticulous preparation with enough interproximal embrace, occlusal rests, interocclusal clearance and cingulum stops is equally important. Including more teeth in the design does not necessarily lead to an improved retention. Besides the material and technical aspects, the whole clinical procedure needs much attention. The retention does not depend on one single factor, but on the precision of all the necessary clinical steps and on a well-defined selection of the material. In this way a five-year survival rate of close to 80% can be obtained. PMID:11830965

  17. BRIDGING SERVICE QUALITY GAPS

    OpenAIRE

    BARKATH UNISSA

    2012-01-01

    Bridging the Service quality gaps is one of the foremost areas of concern for amarketer. Service marketing is inherently different from product or goods marketing.Services are distinctively characterized by their intangible, heterogeneous, inseparableand perishable nature. The importance of the service sector in today's world is a verywidely accepted and renowned idea. “We are already experiencing a service society“services do have some basic characteristics which make them fundamentally diff...

  18. Bridging as Coercive Accommodation

    CERN Document Server

    Bos, J W; Mineur, A M; Bos, Johan; Buitelaar, Paul; Mineur, Anne-Marie

    1995-01-01

    In this paper we discuss the notion of "bridging" in Discourse Representation Theory as a tool to account for discourse referents that have only been established implicitly, through the lexical semantics of other referents. In doing so, we use ideas from Generative Lexicon theory, to introduce antecedents for anaphoric expressions that cannot be "linked" to a proper antecedent, but that do not need to be "accommodated" because they have some connection to the network of discourse referents that is already established.

  19. Nematic liquid crystal bridges

    Science.gov (United States)

    Doss, Susannah; Ellis, Perry; Vallamkondu, Jayalakshmi; Danemiller, Edward; Vernon, Mark; Fernandez-Nieves, Alberto

    We study the effects of confining a nematic liquid crystal between two parallel glass plates with homeotropic boundary conditions for the director at all bounding surfaces. We find that the free surface of the nematic bridge is a surface of constant mean curvature. In addition, by changing the distance between the plates and the contact angle with the glass plates, we transition between loops and hedgehogs that can be either radial or hyperbolic.

  20. Environmental life cycle assessment comparison between two bridge types: reinforced concrete bridge and steel composite bridge

    DEFF Research Database (Denmark)

    Du, Guangli; Karoumi, Raid

    2013-01-01

    not been integrated into the decision-making process. This paper presents a systematic LCA method for quantifying the environmental impacts for bridges. The comparison study is performed between a reinforced concrete bridge and a steel bridge as an alternative design, with several key maintenance and EOL......The concept of sustainable construction has attracted an increased attention. Bridge infrastructures and their belonged construction activities consume considerable material and energy, which is responsible for large environmental burdens. However, the environmental assessment of bridges has...

  1. Mn bioavailability by polarized Caco-2 cells: comparison between Mn gluconate and Mn oxyprolinate

    Directory of Open Access Journals (Sweden)

    Fulgenzi Alessandro

    2011-07-01

    Full Text Available Abstract Background Micronutrient inadequate intake is responsible of pathological deficiencies and there is a need of assessing the effectiveness of metal supplementation, frequently proposed to rebalance poor diets. Manganese (Mn is present in many enzymatic intracellular systems crucial for the regulation of cell metabolism, and is contained in commercially available metal supplements. Methods We compared the effects of two different commercial Mn forms, gluconate (MnGluc and oxyprolinate (MnOxP. For this purpose we used the polarized Caco-2 cells cultured on transwell filters, an established in vitro model of intestinal epithelium. Since micronutrient deficiency may accelerate mitochondrial efficiency, the mitochondrial response of these cells, in the presence of MnGluc and MnOxP, by microscopy methods and by ATP luminescence assay was used. Results In the presence of both MnOxP and MnGluc a sustained mitochondrial activity was shown by mitoTraker labeling (indicative of mitochondrial respiration, but ATP intracellular content remained comparable to untreated cells only in the presence of MnOxP. In addition MnOxP transiently up-regulated the antioxidant enzyme Mn superoxide dismutase more efficiently than MnGluc. Both metal treatments preserved NADH and βNADPH diaphorase oxidative activity, avoided mitochondrial dysfunction, as assessed by the absence of a sustained phosphoERK activation, and were able to maintain cell viability. Conclusions Collectively, our data indicate that MnOxP and MnGluc, and primarily the former, produce a moderate and safe modification of Caco-2 cell metabolism, by activating positive enzymatic mechanisms, thus could contribute to long-term maintenance of cell homeostasis.

  2. Vulnerability of bridges to fire

    DEFF Research Database (Denmark)

    Giuliani, Luisa; Crosti, C.; Gentili, F.

    2012-01-01

    Even if recent effort in developing methodology and measures for design structures against fire and explosions has been mostly focused on buildings, bridges can also be very sensitive to those actions, as witnesses by some recent bridge accidents, which caused major economic losses and also...... endangered people safety in few cases. Purpose of this paper is making a focus on the state of the art of the research and current regulations concerning the response of bridges to fire. Several cases of bridge fires are reported and a focus is made on the occurrence and consequence of bridge fires......, considering both the costs deriving by structural damages and by limited serviceability and other indirect societal aspects. Few cases of recent bridge fire are reviewed in detail and structural consequences are highlighted, distinguishing between damages directly induced by fire and damages induced by local...

  3. Theory of bridge aerodynamics

    CERN Document Server

    Strømmen, Einar

    2006-01-01

    This text book is intended for studies in wind engineering, with focus on the stochastic theory of wind induced dynamic response calculations for slender bridges or other line ?like civil engineering type of structures. It contains the background assumptions and hypothesis as well as the development of the computational theory that is necessary for the prediction of wind induced fluctuating displacements and cross sectional forces. The simple cases of static and quasi-static structural response calculations are for the sake of completeness also included. The text is at an advanced level in the

  4. Modelling railway bridge asset management

    OpenAIRE

    Le, Bryant Linh Hai

    2014-01-01

    The UK has a long history in the railway industry with a large number of railway assets. Railway bridges form one of the major asset groups with more than 35,000 bridges. The majority of the bridge population are old being constructed over 100 years ago. Many of the bridges were not designed to meet the current network demand. With an expected increasing rate of deterioration due to the increasing traffic loads and intensities, the management authorities are faced with the difficult task of k...

  5. Synthesis and Reaction of [MnRe(CO)6(μ-SH)(μ-SC(H)PPri3)(PPh3)

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    The synthesis, the crystal structure and the reaction of the hetero-binuclear complex [MnRe(CO)6(μ-SH)(μ-SC(H)PPri3)(PPh3)] are reported. The results of single crystal X-ray structure analysis showed that the fragments Mn(CO)3 and Re(CO)3 were bridged by SH and SC(H)PPri3. The title complexes can react with BunLi and RX forming complexes MnRe(CO)6(μ-SR)(μ-SC(H)PPri3)(PPh3) (R = Me, CH2CH=CH2, SnBu3n).

  6. Association Between Food Opportunities During the School Day and Selected Dietary Behaviors of Alternative High School Students, Minneapolis/Saint Paul, Minnesota, 2006

    Directory of Open Access Journals (Sweden)

    Chrisa Arcan, PhD, MHS, MBA

    2011-01-01

    Full Text Available IntroductionAvailability of competitive foods in schools has been linked to unhealthful dietary behaviors of students. Little is known about the food environment of alternative high schools, schools that enroll students at risk of academic failure. We examined correlations between food opportunities during the school day and selected dietary behaviors of students attending alternative high schools.MethodsBaseline data were collected in fall 2006 as part of the Team COOL (Controlling Overweight and Obesity for Life pilot study, a group randomized obesity prevention trial. Students (n = 145 attending 6 alternative high schools in Minneapolis/Saint Paul, Minnesota, completed a survey on food opportunities during the school day and selected dietary behaviors. We used mixed-model multivariate cross-sectional analysis and adjusted for demographic characteristics to examine associations of interest.ResultsFood opportunities during the school day were positively associated with overall consumption of sugar-sweetened beverages, high-fat foods, and fast-food restaurant use.ConclusionsHaving many food opportunities during the school day at alternative high schools was linked to the consumption of foods and beverages high in sugar and fat and low in nutrients. School-based interventions should focus on changing the food environment in alternative high schools to decrease less healthful eating opportunities and to increase the availability of healthful foods and beverages.

  7. Fatigue tests on aluminium bridges

    NARCIS (Netherlands)

    Maljaars, J.; Soetens, F.; Straalen, IJ.J. van

    2005-01-01

    Traffic bridges are subjected to variable loads and should therefore be checked on fatigue. Especially low weight materials, like aluminium, are sensitive to fatigue, because the variable load is a substantial part of the total load. This paper shows the structural design of an aluminium bridge load

  8. Fatigue tests on aluminium bridges

    NARCIS (Netherlands)

    Maljaars, J.; Soetens, F.; Straalen, IJ.J. van

    2004-01-01

    Traffic bridges are subjected to variable loads and should therefore be checked on fatigue. Especially low weight materials, like aluminium, are sensitive to fatigue, because the variable load is a substantial part of the total load. This paper shows the structural design of an aluminium bridge load

  9. Development of cooperative system bridges

    Institute of Scientific and Technical Information of China (English)

    ZHANG Zhe; WAN Qi-bai; SHI Lei

    2008-01-01

    Cooperative system bridges comprise several basic structures that act jointly to improve structural characteristics. We delved into the historical development of cooperative system bridges. Cooperative systems are classified as different-load cooperative systems and same-load cooperative systems by distinguishing the modes of load distribution. For different-load cooperation, individual basic structures are at different positions in the direction along bridge axis and carry the loads separately. While for same-load cooperation, all basic structures overlap in geometrical locations and support the entire loads conjointly. The choosing of span ratios between basic structures, the design of connections of different-load cooperative systems were discussed as well as optimizations of relative rigidity for same-load cooperative systems which greatly influence structural characteristics. The general situation and several structural measurements of several cooperative bridges were demonstrated. This information can assist engineers in developing their concepts in cooperative systems and can lead to more efficient and economical cooperative bridges.

  10. Cascaded resonant bridge converters

    Science.gov (United States)

    Stuart, Thomas A. (Inventor)

    1989-01-01

    A converter for converting a low voltage direct current power source to a higher voltage, high frequency alternating current output for use in an electrical system where it is desired to use low weight cables and other circuit elements. The converter has a first stage series resonant (Schwarz) converter which converts the direct current power source to an alternating current by means of switching elements that are operated by a variable frequency voltage regulator, a transformer to step up the voltage of the alternating current, and a rectifier bridge to convert the alternating current to a direct current first stage output. The converter further has a second stage series resonant (Schwarz) converter which is connected in series to the first stage converter to receive its direct current output and convert it to a second stage high frequency alternating current output by means of switching elements that are operated by a fixed frequency oscillator. The voltage of the second stage output is controlled at a relatively constant value by controlling the first stage output voltage, which is accomplished by controlling the frequency of the first stage variable frequency voltage controller in response to second stage voltage. Fault tolerance in the event of a load short circuit is provided by making the operation of the first stage variable frequency voltage controller responsive to first and second stage current limiting devices. The second stage output is connected to a rectifier bridge whose output is connected to the input of the second stage to provide good regulation of output voltage wave form at low system loads.

  11. Cubane-type Cu(II)4 and Mn(II)2Mn(III)2 complexes based on pyridoxine: a versatile ligand for metal assembling.

    Science.gov (United States)

    Marino, Nadia; Armentano, Donatella; Mastropietro, Teresa F; Julve, Miguel; De Munno, Giovanni; Martínez-Lillo, José

    2013-10-21

    By using Vitamin B6 in its monodeprotonated pyridoxine form (PN-H) [PN = 3-hydroxy-4,5-bis(hydroxymethyl)-2-methylpyridine], two tetranuclear compounds of formula [Mn4(PN-H)4(CH3CO2)3Cl2]Cl·2CH3OH·2H2O (1) and [Cu4(PN-H)4Cl2(H2O)2]Cl2 (2) have been synthesized and magneto-structurally characterized. 1 crystallizes in the triclinic system with space group P1 whereas 2 crystallizes in the orthorhombic system with Fdd2 as space group. They exhibit Mn(II)2Mn(III)2 (1) and Cu(II)4 (2) cubane cores containing four monodeprotonated pyridoxine groups simultaneously acting as chelating and bridging ligands (1 and 2), three bridging acetate ligands in the syn-syn conformation (1), and two terminally bound chloride anions (1 and 2) plus two coordinated water molecules (2). The electroneutrality is achieved by the presence of chloride counterions in both compounds. Tri- [Mn(1) and Mn(3)] and divalent [Mn(2) and Mn(4)] manganese centers coexist in 1, all being six-coordinate with distorted Mn(1/3)O6 and Mn(2/4)O5Cl octahedral surroundings, respectively, the equatorial Mn-O bonds being about 0.2 Å shorter at the former ones. The two crystallographically independent copper(II) ions in 2 are five-coordinate in somewhat distorted CuO5 [Cu(1)] and CuO4Cl [Cu(2)] square pyramidal geometries. The values of the intracore metal-metal separation cover the ranges 3.144(1)-3.535(1) (1) and 2.922(6)-3.376(1) Å (2). The magnetic properties of 1 and 2 were investigated in the temperature range 1.9-300 K, and they correspond to an overall antiferromagnetic behavior with susceptibility maxima at 5.0 (1) and 65.0 K (2). The analysis of the magnetic susceptibility data showed the coexistence of intracore antiferro- and ferromagnetic interactions in the two compounds. Their values compare well with those existing in the literature for the parent systems.

  12. Lithium and oxygen adsorption at the b-MnO2 (110) surface

    OpenAIRE

    Mellan, Thomas A.; Maenetja, Khomotso P.; Ngoepe, Phuti E.; Woodley, Scott M.; Catlow , C Richard A; Grau-Crespo, Ricardo

    2013-01-01

    The adsorption and co-adsorption of lithium and oxygen at the surface of rutile-like manganese dioxide(b-MnO2), which are important in the context of Li–air batteries, are investigated using density functional theory. In the absence of lithium, the most stable surface of b-MnO2, the (110), adsorbs oxygen in the form of peroxo groups bridging between two manganese cations. Conversely, in the absence of excess oxygen, lithium atoms adsorb on the (110) surface at two different sites, which ar...

  13. Lithium and oxygen adsorption at the beta-MnO2 (110) surface

    OpenAIRE

    Mellan, T. A.; Maenetja, K. P.; Ngoepe, P.E.; Woodley, S. M.; Catlow, C. R. A.; Grau-Crespo, R.

    2013-01-01

    The adsorption and co-adsorption of lithium and oxygen at the surface of rutile-like manganese dioxide (β-MnO2), which are important in the context of Li–air batteries, are investigated using density functional theory. In the absence of lithium, the most stable surface of β-MnO2, the (110), adsorbs oxygen in the form of peroxo groups bridging between two manganese cations. Conversely, in the absence of excess oxygen, lithium atoms adsorb on the (110) surface at two different sites, which are ...

  14. Electronic structure of MnSb

    OpenAIRE

    Coehoorn, R.; Haas, C.; de Groot, R. A.

    1985-01-01

    Self-consistent, spin-polarized energy-band calculations have been performed for MnSb, for both ferromagnetic and antiferromagnetic spin alignments. For ferromagnetic MnSb we find a 3d5.5 configuration on the Mn atom, with a magnetic moment of 3.3μB on the Mn sites, and –0.06μB on the Sb sites. The charge transfer of Mn to Sb is very small. A detailed analysis is made of the strong covalent Mn-Mn and Mn-Sb interactions. The coupling between the moments is described in terms of covalent intera...

  15. Liquid-Bridge Breaking Limits

    Science.gov (United States)

    Macner, Ashley; Steen, Paul

    2011-11-01

    Wet adhesion by liquid bridges in large arrays shows promise for use in lightweight, controllable on-demand devices. Applications include grab/release of wafer substrates, transport of micron-sized tiles for use in 3D printing and micro-dosing of personalized pharmaceutical drugs. By wetting and spreading, a drop can form a bridge and thereby ``grab'' a nearby solid substrate. By volume decrease or extension, the bridge can break. The breaking limit corresponds to bridge instability which can be predicted, knowing the static mechanical response of the bridge. Mechanical behaviors include force-volume (FV), pressure-volume (pV) and force-length (FL) responses. Instability crucially depends on the mode of failure - failure under constant-force or constant length are typical cases. We study single bridge equilibria for their breaking limits. FV diagrams for the pin-pin equal and pin-pin unequal radii boundary conditions for different bridge heights are measured in the laboratory. The FL response in the case of pin-pin equal radii is also measured. Results are compared to predictions of static theory. Static results are then used to compare to dynamical sequences where volume is driven quasistatically by syringe or an electro-osmotic pump. As the breaking limit is approached, the shape deformation accelerates leading to non-equilibrium shapes not captured by the static analysis.

  16. Bridge Creek IMW database - Bridge Creek Restoration and Monitoring Project

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The incised and degraded habitat of Bridge Creek is thought to be limiting a population of ESA-listed steelhead (Oncorhynchus mykiss). A logical restoration...

  17. National Bridge Inventory - National Geospatial Data Asset (NGDA) Bridges

    Data.gov (United States)

    Department of Transportation — The NBI (NTAD 2015) is a collection of information (database) describing the more than 610,000 of the Nation's bridges located on public roads, including Interstate...

  18. Complex Testing of the Bridges

    Directory of Open Access Journals (Sweden)

    Savić Adrijana

    2016-01-01

    Full Text Available This article describes the process of examining bridges. AB road bridge, founded on the columns by the Karpoš system and damaged due to erosive action of the river, is given as an example. The first tests of the bridge are conducted on the impact load of V 300, because of the appearance of longitudinal cracks. The results of the columns testing are presented in this paper, as well as the rehabilitation measures thus increasing the load capacity of the column.

  19. General design of Sutong Bridge

    Institute of Scientific and Technical Information of China (English)

    Zhang Xigang; Yuan Hong; Pei Minshan; Dai Jie; Xu Lin

    2009-01-01

    The main span of Sutong Bridge is a double-pylon, double-plane cable-stayed bridge with steel box girder, which has the world's longest central span of 1 088 m within cable-stayed bridges. To overcome problems caused by severe meteorological conditions, perplexing hydrological conditions, deep buried bedrock and higher navigation level, many new technics and methods were created. Keys including structural system, steel box girder, stayed cable, tower, pier, tower foundation, collision avoidance system, wind-resistance, seismic-resistance, structural nonlinear response and structural static stability were presented individually in this paper.

  20. Thermal bridges of modern windows

    DEFF Research Database (Denmark)

    Hansen, Ernst Jan de Place; Møller, Eva B.; Nielsen, Anker;

    2013-01-01

    With its focus on reduced energy consumption, contemporary housing construction requires a highly insulated and airtight building envelope with as few thermal bridges as possible.Windows must be carefully designed, as thermal bridges can lead to surface condensation or mold growth, even...... if the window has an U-factor of 1 W/(m2·K) or lower. This paper describes the development of modern, energy efficient Danish windows with reduced thermal bridges. It focuses on materials, geometry, and sealing of window panes based on a literature review. Examples of modern windows are presented. Experience...

  1. Reliability Assessment of Concrete Bridges

    DEFF Research Database (Denmark)

    Thoft-Christensen, Palle; Middleton, C. R.

    This paper is partly based on research performed for the Highways Agency, London, UK under the project DPU/9/44 "Revision of Bridge Assessment Rules Based on Whole Life Performance: concrete bridges". It contains the details of a methodology which can be used to generate Whole Life (WL) reliability...... profiles. These WL reliability profiles may be used to establish revised rules for concrete bridges. This paper is to some extend based on Thoft-Christensen et. al. [1996], Thoft-Christensen [1996] et. al. and Thoft-Christensen [1996]....

  2. Major differences between the binuclear manganese boronyl carbonyl Mn2(BO)2(CO)9 and its isoelectronic chromium carbonyl analogue Cr2(CO)11.

    Science.gov (United States)

    Chang, Yu; Li, Qian-Shu; Xie, Yaoming; King, R Bruce

    2013-03-14

    The lowest energy structures of the manganese boronyl carbonyl Mn2(BO)2(CO)9 by more than 8 kcal/mol are found to have a single end-to-end bridging BO group bonding to one manganese atom through its boron atom and to the other manganese atom through its oxygen atom. The long Mn···Mn distances in these structures indicate the lack of direct manganese-manganese bonding as confirmed by essentially zero Wiberg bond indices. These Mn2(BO)2(CO)9 structures are favored thermochemically by more than 25 kcal/mol over dissociation into mononuclear fragments and thus appear to be viable synthetic objectives. This contrasts with the isoelectronic Cr2(CO)11 system, which is predicted to be disfavored relative to the mononuclear fragments Cr(CO)6 + Cr(CO)5. Analogous Mn2(BO)2(CO)9 structures with an end-to-end bridging CO group lie ∼17 kcal/mol in energy above the corresponding structures with end-to-end bridging BO groups. The lowest energy Mn2(BO)2(CO)9 structures without an end-to-end bridging BO group provide unprecedented examples of the coupling of two terminal BO groups to form a terminal dioxodiborene (B2O2) ligand with a B-B distance of ∼1.9 Å. Still higher energy Mn2(BO)2(CO)9 structures include singly bridged and doubly semibridged structures analogous to the previously optimized lowest energy Cr2(CO)11 structures. PMID:23402266

  3. The Higgs Bridge

    CERN Document Server

    Allen, Roland E

    2013-01-01

    The particle recently discovered at the Large Hadron Collider near Geneva is almost certainly a Higgs boson, the long-sought completion of the Standard Model of particle physics. But this discovery, an achievement by more than six thousand scientists (including students), is actually much more than a mere capstone of the Standard Model. It instead represents a bridge from the Standard Model to exciting discoveries of the future, at higher energies or in other experiments, and to the properties of matter at very low temperatures. The mere existence of a particle with zero spin implies a need for new physics, with the most likely candidate being supersymmetry, which requires that every known particle has a superpartner yet to be discovered. And phenomena similar to the Higgs are seen in superconducting metals and superfluid gases at low temperatures, which extend down to a millionth or even a billionth of a degree Kelvin. So the discovery of a Higgs boson has a central place in our attempts both to achieve a tr...

  4. Mineral bridges in nacre revisited

    CERN Document Server

    Checa, Antonio G; Willinger, Marc-Georg

    2012-01-01

    We confirm with high-resolution techniques the existence of mineral bridges between superposed nacre tablets. In the towered nacre of both gastropods and the cephalopod Nautilus there are large bridges aligned along the tower axes, corresponding to gaps (150-200 nm) in the interlamellar membranes. Gaps are produced by the interaction of the nascent tablets with a surface membrane that covers the nacre compartment. In the terraced nacre of bivalves bridges associated with elongated gaps in the interlamellar membrane (> 100 nm) have mainly been found at or close to the edges of superposed parental tablets. To explain this placement, we hypothesize that the interlamellar membrane breaks due to differences in osmotic pressure across it when the interlamellar space below becomes reduced at an advanced stage of calcification. In no cases are the minor connections between superimposed tablets (< 60 nm), earlier reported to be mineral bridges, found to be such.

  5. Simulation of multivariate diffusion bridges

    DEFF Research Database (Denmark)

    Bladt, Mogens; Finch, Samuel; Sørensen, Michael

    We propose simple methods for multivariate diffusion bridge simulation, which plays a fundamental role in simulation-based likelihood and Bayesian inference for stochastic differential equations. By a novel application of classical coupling methods, the new approach generalizes a previously...

  6. Applications of overburden conveyor bridges

    Energy Technology Data Exchange (ETDEWEB)

    Schachtschneider, H.

    1987-06-01

    In large scale surface mines of the capacities required today, a cross-pit operation with overburden conveyor bridges is the most economical method of overburden removal and disposal. In order to provide the production capacity required in surface mining equipment by the GDR brown coal industry, VEB Schwermaschinenbau Lauchhammerwerk undertook the design and manufacture of standard overburden conveyor bridges for cut heights of 34 m, 45 m and 60 m. All three base types may be equipped to match the site specific geological and geotechnical conditions, and to meet customer's demands. Specifications of the bridges are given as well as details of conveyor belt speeds, modifications to the standards, and number manufactured. Design problems faced with the 60 m bridge are discussed, together with details of the superstructure, method of operation, transportation rates, structural steel used, assembly and power supply. 5 refs.

  7. Bridge Culture of Langde Village

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    Langde, a village in Leishan County ofsouthwestern Guizhou province, is known for itslarge number of unique bridges bearing the distinctdesign style of the Miao ethnic group. Animpressive variety of well-preserved ancient

  8. SrMnII2MnIII(PO43

    Directory of Open Access Journals (Sweden)

    Ghaleb Alhakmi

    2013-09-01

    Full Text Available The title compound, strontium trimanganese tris(orthophosphate, was synthesized under hydrothermal conditions. Its structure is isotypic to that of the lead analogue PbMnII2MnIII(PO43. Two O atoms are in general positions, whereas all others atoms are in special positions. The Sr and one P atom exhibit mm2 symmetry, the MnII atom 2/m symmetry, the MnIII atom and the other P atom .2. symmetry and two O atoms are located on mirror planes. The three-dimensional network of the crystal structure is made up of two types of chains running parallel to [010]. One chain is linear and is composed of alternating MnIIIO6 octahedra and PO4 tetrahedra sharing vertices; the other chain has a zigzag arrangement and is built up from two edge-sharing MnIIO6 octahedra connected to PO4 tetrahedra by edges and vertices. The two types of chains are linked through PO4 tetrahedra, leading to the formation of channels parallel to [100] and [010] in which the SrII ions are located. They are surrounded by eight O atoms in the form of a slightly distorted bicapped trigonal prism.

  9. ANGIOGRAPHIC ASPECTS OF MYOCARDIAL BRIDGES

    Directory of Open Access Journals (Sweden)

    Sujatha. M

    2015-12-01

    Full Text Available Introduction: The segment of epicardial coronary artery that traverses intramurally through the myocardium and bridged by a bunch of cardiac muscle fibers is called tunneled artery or intramural artery. The band of cardiac muscle fibers passing over the tunneled artery segment is named as myocardial bridge. During angiography milking effect is observed during systole due to the external pressure of muscle fibers on the tunneled artery that leads to narrowing of vessel lumen and further ischemia. Materials & Methods: It is a prospective study performed from 2012- 2015 in cardiac centers available around Tirupati, Andhra Pradesh, South India. A total number of 2015 adult patients who underwent diagnostic coronary angiography were evaluated to detect myocardial bridges. With the informed consent the relevant data was collected from the patients and analyzed. Results: The prevalence of myocardial bridges was 3.17%. Among the 2015 patients 70.7% are males and 29.2% are females. Among 64 myocardial bridge positive cases 62.5% were male and 37.5% were female patients. Regarding coronary dominance 84% were right dominant and 14.4% were left dominant and 1.6% are balanced. The percentage incidence of myocardial bridging according to dominance was 3.01% for right dominant patients, 4.12% for left dominant patients and 3.1% for balanced dominant patients. In all the myocardial bridge positive cases they were located on the left anterior descending artery (LAD. According to diagnosis the patients with normal coronaries were 22.6%, patients with MILD CAD were 17.9%, patients with single vessel disease were 23.4%, patients with two vessel disease were 14.7% and the patients with triple vessel disease were 21.3%. The 64 myocardial bridging cases were grouped in to three groups according to their age. Incidence of double bridges was observed in 3 cases of which 66.7% males & 33.3% in females. Conclusion: These results show that Andhra Pradesh population are

  10. The stories of two bridges in Ghana

    DEFF Research Database (Denmark)

    Andreasen, Jørgen

    2004-01-01

    Public participation in bridge building was promoted by un habitat in the village of Mankrong. The neighbouring village did not participate in the construction of their bridge. The first flooding washed the second bridge down while the "participative bridge" stood up....

  11. An Expert System for Concrete Bridge Management

    DEFF Research Database (Denmark)

    Brito, J. de; Branco, F. A.; Thoft-Christensen, Palle;

    1997-01-01

    The importance of bridge repair versus new bridge construction has risen in recent decades due to high deterioration rates that have been observed in these structures. Budgets both for building new bridges and keeping the existing ones are always limited. To help rational decision-making, bridge...

  12. Stability of liquid crystalline bridges

    Science.gov (United States)

    Mahajan, Milind P.; Tsige, Mesfin; Taylor, P. L.; Rosenblatt, Charles

    1999-02-01

    The stability of cylindrical bridges of the liquid crystal octylcyanobiphenyl in an immiscible liquid bath was investigated in the nematic and smectic A phases. In the nematic phase the bridge was found to destabilize at a length-to-diameter (slenderness) ratio R similar to that of ordinary Newtonian fluids. On the other hand, the Bingham behavior of the smectic A phase, i.e., an apparent yield stress, enabled the formation of stable columns with R well in excess of π.

  13. Growth and properties of (Ga,Mn)As films with high Mn concentration

    Science.gov (United States)

    Takamura, K.; Matsukura, F.; Ohno, Y.; Ohno, H.

    2001-06-01

    (Ga, Mn)As films with high nominal Mn concentration (00.1, which turn to polycrystalline features when x>0.3. X-ray diffraction shows the formation of MnAs together with the growth of (Ga, Mn)As. The lattice constant of the layers suggests that (Ga, Mn)As with high Mn composition as high as 17% can be grown by LT-MBE.

  14. Characterization of Danio rerio Mn2+-dependent ADP-ribose/CDP-alcohol diphosphatase, the structural prototype of the ADPRibase-Mn-like protein family.

    Directory of Open Access Journals (Sweden)

    Joaquim Rui Rodrigues

    Full Text Available The ADPRibase-Mn-like protein family, that belongs to the metallo-dependent phosphatase superfamily, has different functional and structural prototypes. The functional one is the Mn(2+-dependent ADP-ribose/CDP-alcohol diphosphatase from Rattus norvegicus, which is essentially inactive with Mg(2+ and active with low micromolar Mn(2+ in the hydrolysis of the phosphoanhydride linkages of ADP-ribose, CDP-alcohols and cyclic ADP-ribose (cADPR in order of decreasing efficiency. The structural prototype of the family is a Danio rerio protein with a known crystallographic structure but functionally uncharacterized. To estimate the structure-function correlation with the same protein, the activities of zebrafish ADPRibase-Mn were studied. Differences between zebrafish and rat enzymes are highlighted. The former showed a complex activity dependence on Mn(2+, significant (≈25% Mg(2+-dependent activity, but was almost inactive on cADPR (150-fold less efficient than the rat counterpart. The low cADPR hydrolase activity agreed with the zebrafish genome lacking genes coding for proteins with significant homology with cADPR-forming enzymes. Substrate-docking to zebrafish wild-type protein, and characterization of the ADPRibase-Mn H97A mutant pointed to a role of His-97 in catalysis by orientation, and to a bidentate water bridging the dinuclear metal center as the potential nucleophile. Finally, three structural elements that delimit the active site entrance in the zebrafish protein were identified as unique to the ADPRibase-Mn-like family within the metallo-dependent phosphatase superfamily.

  15. Floating liquid bridge charge dynamics

    Science.gov (United States)

    Teschke, Omar; Soares, David Mendez; Gomes, Whyllerson Evaristo; Valente Filho, Juracyr Ferraz

    2016-01-01

    The interaction of liquid with electric fields is investigated in a configuration where up to 13 kV are applied between electrodes resulting in a 106 V/m electric field in the capillaries and where there is the formation of a free-standing fluid bridge in the interelectrode gap. The Mott-Gurney equation was fitted to the measured ionization current vs applied voltage curve which indicates that the ionization rate at the high-voltage anode electrode dimethylsulfoxide (DMSO) interface and space charging in the interelectrode gap determine the floating liquid bridge current for a given cathode-to-anode voltage. Space charge effects were measured in the cathode becker and also at the liquid bridge since the ionized charges at the anode migrate to the bridge outer surface and decrease the interfacial tension from 43 mJ/m2 to 29 mJ/m2. Two distinct structural regions then form the bridge, a charged plastic (bulk modulus ˜100 MPa) conducting outer layer with a surface conductivity of ˜10-9 Ω-1, which shapes and supports the floating fluid structure, and an inner liquid cylinder, where DMSO molecules flow.

  16. A strange bridge by Leonardo

    CERN Document Server

    Huylebrouck, Dirk

    2013-01-01

    On folio 855 recto of the Codex Atlanticus, Leonardo da Vinci drew three 'easily movable' bridges, but one of them is enigmatic: all 'replicas' in Leonardo museums and exhibitions come as a surprise, to say the least, to any engineer or architect whose attention is drawn to it. This is the case for models in Amboise (France), Chicago and Portland (USA), Florence (Italy) and for the one of the traveling exhibition by the Australian company 'Grande Exhibitions' that already visited 40 major cities in the world. All 'replicas' of the bridge model attributed to Leonardo have pillars standing on the deck of the bridge, while the deck is suspended by cables attached on these pillars. At first sight this problem does not catch the attention of the observer, as the bridge seems to be a mixed form of a beam and a suspension bridge, but it was not overlooked by my colleague architect-engineer Dr. Laurens Luyten (Gent, Belgium). Yet, after a TV-interview in Brussels so much pressure was exerted by some of the museum col...

  17. Synthesis,Crystal Structure and Magnetic Properties of Novel Three-dimensional Frameworks [Mn(PDC)H2O]n

    Institute of Scientific and Technical Information of China (English)

    GAO En-Jun; GU Xiao-Fu; SUN Ya-Guang; YIN Hong-Xi; WU Qiong; LIU Lei; ZHU Ming-Chang; ZHANG Wan-Zhong

    2008-01-01

    A novel coordination polymer,[Mn(PDC)H2O]n(1)(H2PDC=pyridine-2,3-dicarboxylic acid),has been hydrothermally synthesized and characterized by elemental analysis,IR and single crystal X-ray diffraction.X-ray single crystal structural analyses revealed that two-dimensional frameworks were formed,and further assembled into a three-dimensional supramolecular structure bridged by PDC ligands.Moreover,the magnetic study of complex 1 shows weak antiferromagnetic interaction between the neighboring Mn(Ⅱ)centers within the chains and even weak ferromagnetic interactions between the Mn(Ⅱ)centers in different chains.

  18. Paramagnetic Liquid Bridge in a Gravity-Compensating Magnetic Field

    Science.gov (United States)

    Mahajan, Milind P.; Tsige, Mesfin; Taylor, P. L.; Rosenblatt, Charles

    1999-01-01

    Magnetic levitation was used to stabilize cylindrical columns of a paramagnetic liquid in air between two solid supports. The maximum achievable length to diameter ratio R(sub max) was approx. (3.10 +/- 0.07), very close to the Rayleigh-Plateau limit of pi. For smaller R, the stability of the column was measured as a function of the Bond number, which could be continuously varied by adjusting the strength of the magnetic field. Liquid bridges supported by two solid surfaces have been attracting scientific attention since the time of Rayleigh and Plateau. For a cylindrical bridge of length L and diameter d, it was shown theoretically that in zero gravity the maximum slenderness ratio R (identically = L/d) is pi. The stability and ultimate collapse of such bridges is of interest because of their importance in a number of industrial processes and their potential for low gravity applications. In the presence of gravity, however, the cylindrical shape of an axisymmetric bridge tends to deform, limiting its stability and decreasing the maximum achievable value of R. Theoretical studies have discussed the stability and possible shapes of axisymmetric bridges. Experiments typically are performed in either a Plateau tank, in which the bridge is surrounded by a density-matched immiscible fluid, or in a space-borne microgravity environment. It has been shown, for example, that the stability limit R can be pushed beyond pi by using flow stabilization, by acoustic radiation pressure, or by forming columns in the presence of an axial electric field. In this work, magnetic levitation was used to simulate a low gravity environment and create quasi-cylindrical liquid columns in air. Use of a magnetic field permits us to continuously vary the Bond number B identically equal to (g)(rho)d(exp 2)/4(sigma), where g is the gravitational acceleration, rho is the density of the liquid, and sigma is the surface tension of the liquid in air. The dimensionless Bond number represents the

  19. Bridging history and social psychology

    DEFF Research Database (Denmark)

    Glaveanu, Vlad Petre; Yamamoto, Koji

    2012-01-01

    This special issue aims to bridge history and social psychology by bringing together historians and social psychologists in an exercise of reading and learning from each other’s work. This interdisciplinary exercise is not only timely but of great importance for both disciplines. Social...... hand historians can enhance their analysis of historical sources by drawing upon the conceptual tools developed in social psychology. They can “test” these tools and contribute to their validation and enrichment from completely different perspectives. Most important, as contributions to this special......-traditionalized societies—a distinction that lies at the heart of many social psychology accounts of the world we live in. The present editorial will introduce and consider this act of bridging history and social psychology by focusing on three main questions: What is the bridge made of? How can the two disciplines...

  20. Excitation Methods for Bridge Structures

    Energy Technology Data Exchange (ETDEWEB)

    Farrar, C.R.; Duffy, T.A.; Cornwell, P.J.; Doebling, S.W.

    1999-02-08

    This paper summarizes the various methods that have been used to excited bridge structures during dynamic testing. The excitation methods fall into the general categories of ambient excitation methods and measured-input excitation methods. During ambient excitation the input to the bridge is not directly measured. In contrast, as the category label implies, measured-input excitations are usually applied at a single location where the force input to the structure can be monitored. Issues associated with using these various types of measurements are discussed along with a general description of the various excitation methods.

  1. Bridge Number and Conway Products

    OpenAIRE

    Blair, Ryan C.

    2007-01-01

    Schubert proved that, given a composite link $K$ with summands $K_{1}$ and $K_{2}$, the bridge number of $K$ satisfies the following equation: $$\\beta(K)=\\beta(K_{1})+\\beta(K_{2})-1.$$ In ``Conway Produts and Links with Multiple Bridge Surfaces", Scharlemann and Tomova proved that, given links $K_{1}$ and $K_{2}$, there is a Conway product $K_{1}\\times_{c}K_{2}$ such that $$\\beta(K_{1}\\times_{c} K_{2}) \\leq \\beta(K_{1}) + \\beta(K_{2}) - 1$$ In this paper, we define the generalized Conway prod...

  2. Optimum selection on bridge erection with floating crane in East China Sea Bridge and Hangzhou Bay Bridge

    Institute of Scientific and Technical Information of China (English)

    Shunquan Qin; Pu Zhou; Youheng Hua

    2004-01-01

    @@ Introduction With the rapid development of China′s economy, many bridges will be built over the Chinese coastal waters of Pacific Ocean. Among them, construction of East China Sea Bridge has been commenced in June 2001, and will be completed at the end of 2005, Hangzhou Bay Bridge was also started to construct in June 2003(Fig. 1). These two ultralong bridges are designed as twin expressway bridges standing side by side each carries a 3-lane one-way carriageway. The total width is 31.5m and 33.0m respectively. East China Sea Bridge starts from Nanhui District, Shanghai and extends to the Yangshan Deep Water Port Area, which is located at one of the Qiqu Islands. The total length of the bridge is about 31.0 km, in which 25 km are on the sea, and 22 km is in the unnavigable region. Hangzhou Bay Bridge across the mouth of Qiantang River.

  3. Is myocardial bridging a bridge connecting to cardiovascular events?

    Institute of Scientific and Technical Information of China (English)

    LI Jian-jun

    2010-01-01

    @@ Coronary arteries and their major branches usually course on the surface of the heart in the subepicardial tissue. However, a muscle hber overlying the intramyocardial segment of an epicardial coronary artery was defined as myocardial bridging (MB), and subsequently the artery coursing within the myocardium is called a tunneled artery.

  4. Radiation and chemotherapy bystander effects induce early genomic instability events: telomere shortening and bridge formation coupled with mitochondrial dysfunction.

    LENUS (Irish Health Repository)

    Gorman, Sheeona

    2012-02-01

    The bridge breakage fusion cycle is a chromosomal instability mechanism responsible for genomic changes. Radiation bystander effects induce genomic instability; however, the mechanism driving this instability is unknown. We examined if radiation and chemotherapy bystander effects induce early genomic instability events such as telomere shortening and bridge formation using a human colon cancer explant model. We assessed telomere lengths, bridge formations, mitochondrial membrane potential and levels of reactive oxygen species in bystander cells exposed to medium from irradiated and chemotherapy-treated explant tissues. Bystander cells exposed to media from 2Gy, 5Gy, FOLFOX treated tumor and matching normal tissue showed a significant reduction in telomere lengths (all p values <0.018) and an increase in bridge formations (all p values <0.017) compared to bystander cells treated with media from unirradiated tissue (0Gy) at 24h. There was no significant difference between 2Gy and 5Gy treatments, or between effects elicited by tumor versus matched normal tissue. Bystander cells exposed to media from 2Gy irradiated tumor tissue showed significant depolarisation of the mitochondrial membrane potential (p=0.012) and an increase in reactive oxygen species levels. We also used bystander cells overexpressing a mitochondrial antioxidant manganese superoxide dismutase (MnSOD) to examine if this antioxidant could rescue the mitochondrial changes and subsequently influence nuclear instability events. In MnSOD cells, ROS levels were reduced (p=0.02) and mitochondrial membrane potential increased (p=0.04). These events were coupled with a decrease in percentage of cells with anaphase bridges and a decrease in the number of cells undergoing telomere length shortening (p values 0.01 and 0.028 respectively). We demonstrate that radiation and chemotherapy bystander responses induce early genomic instability coupled with defects in mitochondrial function. Restoring mitochondrial

  5. Radiation and chemotherapy bystander effects induce early genomic instability events: Telomere shortening and bridge formation coupled with mitochondrial dysfunction

    Energy Technology Data Exchange (ETDEWEB)

    Gorman, Sheeona; Tosetto, Miriam [Centre for Colorectal Disease, St. Vincent' s University Hospital, Elm Park, Dublin 4 (Ireland); Lyng, Fiona; Howe, Orla [Radiation and Environmental Science Centre, Dublin Institute of Technology and St. Luke' s Hospital, Dublin (Ireland); Sheahan, Kieran; O' Donoghue, Diarmuid; Hyland, John; Mulcahy, Hugh [Centre for Colorectal Disease, St. Vincent' s University Hospital, Elm Park, Dublin 4 (Ireland); O' Sullivan, Jacintha, E-mail: jacintha.osullivan@ucd.ie [Centre for Colorectal Disease, St. Vincent' s University Hospital, Elm Park, Dublin 4 (Ireland)

    2009-10-02

    The bridge breakage fusion cycle is a chromosomal instability mechanism responsible for genomic changes. Radiation bystander effects induce genomic instability; however, the mechanism driving this instability is unknown. We examined if radiation and chemotherapy bystander effects induce early genomic instability events such as telomere shortening and bridge formation using a human colon cancer explant model. We assessed telomere lengths, bridge formations, mitochondrial membrane potential and levels of reactive oxygen species in bystander cells exposed to medium from irradiated and chemotherapy-treated explant tissues. Bystander cells exposed to media from 2 Gy, 5 Gy, FOLFOX treated tumor and matching normal tissue showed a significant reduction in telomere lengths (all p values <0.018) and an increase in bridge formations (all p values <0.017) compared to bystander cells treated with media from unirradiated tissue (0 Gy) at 24 h. There was no significant difference between 2 Gy and 5 Gy treatments, or between effects elicited by tumor versus matched normal tissue. Bystander cells exposed to media from 2 Gy irradiated tumor tissue showed significant depolarisation of the mitochondrial membrane potential (p = 0.012) and an increase in reactive oxygen species levels. We also used bystander cells overexpressing a mitochondrial antioxidant manganese superoxide dismutase (MnSOD) to examine if this antioxidant could rescue the mitochondrial changes and subsequently influence nuclear instability events. In MnSOD cells, ROS levels were reduced (p = 0.02) and mitochondrial membrane potential increased (p = 0.04). These events were coupled with a decrease in percentage of cells with anaphase bridges and a decrease in the number of cells undergoing telomere length shortening (p values 0.01 and 0.028 respectively). We demonstrate that radiation and chemotherapy bystander responses induce early genomic instability coupled with defects in mitochondrial function. Restoring

  6. Manganese (Mn oxidation increases intracellular Mn in Pseudomonas putida GB-1.

    Directory of Open Access Journals (Sweden)

    Andy Banh

    Full Text Available Bacterial manganese (Mn oxidation plays an important role in the global biogeochemical cycling of Mn and other compounds, and the diversity and prevalence of Mn oxidizers have been well established. Despite many hypotheses of why these bacteria may oxidize Mn, the physiological reasons remain elusive. Intracellular Mn levels were determined for Pseudomonas putida GB-1 grown in the presence or absence of Mn by inductively coupled plasma mass spectrometry (ICP-MS. Mn oxidizing wild type P. putida GB-1 had higher intracellular Mn than non Mn oxidizing mutants grown under the same conditions. P. putida GB-1 had a 5 fold increase in intracellular Mn compared to the non Mn oxidizing mutant P. putida GB-1-007 and a 59 fold increase in intracellular Mn compared to P. putida GB-1 ∆2665 ∆2447. The intracellular Mn is primarily associated with the less than 3 kDa fraction, suggesting it is not bound to protein. Protein oxidation levels in Mn oxidizing and non oxidizing cultures were relatively similar, yet Mn oxidation did increase survival of P. putida GB-1 when oxidatively stressed. This study is the first to link Mn oxidation to Mn homeostasis and oxidative stress protection.

  7. Trinuclear manganese complexes of unsymmetrical polypodal diamino N3O3 ligands with an unusual [Mn3(μ-OR)4]5+ triangular core: synthesis, characterization, and catalase activity.

    Science.gov (United States)

    Ledesma, Gabriela N; Anxolabéhère-Mallart, Elodie; Rivière, Eric; Mallet-Ladeira, Sonia; Hureau, Christelle; Signorella, Sandra R

    2014-03-01

    Two new tri-Mn(III) complexes of general formula [Mn3L2(μ-OH)(OAc)]ClO4 (H3L = 1-[N-(2-pyridylmethyl),N-(2-hydroxybenzyl)amino]-3-[N'-(2-hydroxybenzyl),N'-(4-X-benzyl)amino]propan-2-ol; 1ClO4, X = Me; 2ClO4, X = H) have been prepared and characterized. X-ray diffraction analysis of 1ClO4 reveals that the complex cation possesses a Mn3(μ-alkoxo)2(μ-hydroxo)(μ-phenoxo)(4+) core, with the three Mn atoms bound to two fully deprotonated N3O3 chelating L(3-), one exogenous acetato ligand, and one hydroxo bridge, the structure of which is retained upon dissolution in acetonitrile or methanol. The three Mn atoms occupy the vertices of a nearly isosceles triangle (Mn1···Mn3 = 3.6374(12) Å, Mn2···Mn3 3.5583(13) Å, and Mn1···Mn2 3.2400(12) Å), with one substitution-labile site on the apical Mn ion occupied by terminally bound monodentate acetate. Temperature-dependent magnetic susceptibility studies indicate the presence of predominant antiferromagnetic intramolecular interactions between Mn(III) ions in 1ClO4. Complexes 1ClO4 and 2ClO4 decompose H2O2 at comparable rates upon initial binding of peroxide through acetate substitution, with retention of core structure during catalysis. Kinetic and spectroscopic studies suggest that these complexes employ the [Mn-(μ-oxo/aquo)-Mn](4+) moiety to activate peroxide, with the additional (μ-alkoxo)(μ-phenoxo)Mn(μ-alkoxo) metallobridge carrying out a structural function.

  8. Architectural engineering of FRP bridges

    OpenAIRE

    Smits, J.E.P.

    2014-01-01

    This paper deals with the use of Fibre Reinforced Polymers (FRP's) in architectural and structural bridge design. The challenges and opportunities that come with this relatively new material are discussed. An inventory is made of recent engineers' solutions in FRP, followed by a discussion on architectural application of FRP's derived from the authors architectural practice.

  9. Instability of the capillary bridge

    Science.gov (United States)

    Pare, Gounseti; Hoepffner, Jerome

    2014-11-01

    Capillary adhesion is a physical mechanism that maintains two bodies in contact by capillarity through a liquid ligament. The capillary bridge is an idealization of this capillary adhesion. In this study we first focus on the classical case of the stability of the capillary bridge. Secondly we study a slightly more complex configuration, imagining a flow in the capillary bridge as in the case of the dynamics of the neck of a liquid ligament, in its withdrawal under the effect of capillarity. Inspired by the experiments on soap films of Plateau, the configuration analyzed consists of an initially axisymmetric, mass of fluid held by surface tension forces between two parallel, coaxial, solid pipes of the same diameter. The results presented are obtained by numerical simulations using the free software, Gerris Flow Solver. We first focus on the capillary Venturi. In the static configuration the stability diagram of the capillary bridge obtained is in perfect agreement with the results of Lev A. Slobozhanin. In the dynamic case we develop a matlab code based on the one dimensional equations of Eggers and Dupont. The comparison of the bifurcation diagram obtained and the numerical simulations shows a good agreement.

  10. Bridge Aesthetics and Structural Honesty

    DEFF Research Database (Denmark)

    Gimsing, Niels Jørgen

    1999-01-01

    In bridges the overall form must be chosen with due respect to the transmission of forces if efficient structures shall be created, The design must therefore be governed by experienced structural engineers - in some cases assisted by aesthetic advisers on specific issues. Some basic requirements...

  11. The Wien Bridge Oscillator Family

    DEFF Research Database (Denmark)

    Lindberg, Erik

    2006-01-01

    A tutorial in which the Wien bridge family of oscillators is defined and investigated. Oscillators which do not fit into the Barkhausen criterion topology may be designed. A design procedure based on initial complex pole quality factor is reported. The dynamic transfer characteristic...

  12. Architectural engineering of FRP bridges

    NARCIS (Netherlands)

    Smits, J.E.P.

    2014-01-01

    This paper deals with the use of Fibre Reinforced Polymers (FRP's) in architectural and structural bridge design. The challenges and opportunities that come with this relatively new material are discussed. An inventory is made of recent engineers' solutions in FRP, followed by a discussion on archit

  13. Intercellular bridges in vertebrate gastrulation.

    Directory of Open Access Journals (Sweden)

    Luca Caneparo

    Full Text Available The developing zebrafish embryo has been the subject of many studies of regional patterning, stereotypical cell movements and changes in cell shape. To better study the morphological features of cells during gastrulation, we generated mosaic embryos expressing membrane attached Dendra2 to highlight cellular boundaries. We find that intercellular bridges join a significant fraction of epiblast cells in the zebrafish embryo, reaching several cell diameters in length and spanning across different regions of the developing embryos. These intercellular bridges are distinct from the cellular protrusions previously reported as extending from hypoblast cells (1-2 cellular diameters in length or epiblast cells (which were shorter. Most of the intercellular bridges were formed at pre-gastrula stages by the daughters of a dividing cell maintaining a membrane tether as they move apart after mitosis. These intercellular bridges persist during gastrulation and can mediate the transfer of proteins between distant cells. These findings reveal a surprising feature of the cellular landscape in zebrafish embryos and open new possibilities for cell-cell communication during gastrulation, with implications for modeling, cellular mechanics, and morphogenetic signaling.

  14. Dynamic identification of paradela historic railway bridge

    OpenAIRE

    Ramos, Luís F.; Valente, Isabel; Guimarães, Paulo; Vazquez, Kevin; Lourenço, Paulo B.

    2013-01-01

    Paradela Bridge is a metallic bridge located along the bank of the Tua River in northern Portugal. While the bridge is not currently in service, its structure is representative of many metallic truss structures built across the country between the 19th and the 20th century. The construction of the Paradela Bridge was completed in 1886 and served for about 120 years connecting northern Portugal. Tua Line belongs to the Douro area that UNESCO recently declared as world heritage. This work acqui...

  15. Transition Slabs of Integral Abutment Bridges

    OpenAIRE

    Dreier, Damien; Muttoni, Aurelio; BURDET, Olivier

    2011-01-01

    Over the past decades, an increasing number of bridges with integral abutment have been built in Switzerland. This type of bridge offers various advantages over standard bridges with abutments, equipped with expansion joints and bearings that require regular inspection and maintenance. One main concern of integral abutment bridges is related to the soil-structure interaction, in particular between the transition slab and the embankment. To avoid any expansion joints, transition slabs are dire...

  16. Path transformations of first passage bridges

    OpenAIRE

    Bertoin, Jean

    2003-01-01

    We define the first passage bridge from 0 to $\\lambda$ as the Brownian motion on the time interval $[0,1]$ conditioned to first hit $\\lambda$ at time 1. We show that this process may be related to the Brownian bridge, the Bessel bridge or the Brownian excursion via some path transformations, the main one being an extension of Vervaat's transformation. We also propose an extension of these results to certain bridges with cyclically exchangeable increments.

  17. Mn-based nanostructured building blocks: Synthesis, characterization and applications

    Science.gov (United States)

    Beltran Huarac, Juan

    -up approaches towards the fabrication of different types of functional MBNs. Likewise, strategic procedures that advance the facile integration of these self-assembled nanostructures with carbon-based and magnetic/optical materials, chalcogenides, oxides, and ferroics are widely analyzed and discussed. Furthermore, we present the attractive peculiarities of three versatile MBN systems (bridging the gap between their advantageous properties and the lack of methods for their fabrication): single-crystal saw-like MnS NRs, and single-crystal MnS NWs conformally coated with carbon; doped rare-earth manganite NCs, and carbon NTs conformally coated with doped rare-earth manganite; and ZnS:Mn NPs, and Fe3O4/ZnS:Mn NCs. Concerning the applicative significance, the main features of these three systems obtained by our method are suitable to advance direct applications in nanotechnology. In this regard, this work represents a step ahead in the following areas: i) alternative anode materials to enhance the capacity and cycling performance of low-drain, long-life, low-cost, high-energy density light-weight and safer lithium-ion batteries; ii) promising luminescent materials to improve the optoelectronic performance of visible light emitters; iii) new elements for field-effect transistors that outperform the transport properties of conventional carbon-based channels; iv) bifunctional materials exhibiting optical response sensitive to external magnetic fields vital for DMS; v) novel types of nanocantilevers useful for nanosensors and nanotweezers; vi) unique multiferroics materials that exhibit magnetoelectric coupling at room temperature for spintronics; vii) potential core-shell materials showing stress-free and protective carbon shells for shock-resistance semiconductors; and viii) high-quality ceramics useful as starting materials to deposit films by pulsed laser deposition, sputtering and thermal evaporation techniques.

  18. 三维异核Mn-Na配合物[MnNa(N3)4(C5H5N)4]的合成与表征%Synthesis and Characterization of a Three-dimensional Heteronuclear Mn-Na Complex[MnNa(N3)4(C5H5N)4

    Institute of Scientific and Technical Information of China (English)

    马运声; 王君袁; 袁荣鑫

    2008-01-01

    Azide-containing coordination polymers have received considerable attention for the construction of new molecule-based magnets.A three dimensional heteronuclear Mn-Na compound[MnNa(N3)4(C5H5N)4]was obtained by reaction of[Mn3O(O2CCH3)6(py)3]ClO4 and NaN3 in pyndine solvents.The title compound crystallizes in monoclinic space group C2/c,a=1.536 6(2),b=1.045 3(2),c=1.576 3(2)nm,β=90.309(3).,V=2.531 8(6)nm3,Z=4.In the structure,each Mn3+and Na+ion coordinated with four N atoms from four N3-and two N atoms from two pyridine molecules.Each pair of Mn3+and Na+ion are linked by N3-bridges into a 3D polymer with PtS topology.CCDC:706250.

  19. Calix[4]arene supported clusters: a dimer of [Mn(III)Mn(II)] dimers

    DEFF Research Database (Denmark)

    Taylor, Stephanie M; McIntosh, Ruaraidh D; Beavers, Christine M;

    2011-01-01

    Phosphinate ligands allow for the transformation of a calix[4]arene supported [Mn(III)(2)Mn(II)(2)] tetramer cluster motif into an unusual [Mn(III)Mn(II)](2) dimer of dimers; the clusters self-assemble in the crystal to form bi-layer arrays reminiscent of the typical packing of calixarene solvates....

  20. 47 CFR 80.331 - Bridge-to-bridge communication procedure.

    Science.gov (United States)

    2010-10-01

    ... 47 Telecommunication 5 2010-10-01 2010-10-01 false Bridge-to-bridge communication procedure. 80..., Alarm, Urgency and Safety Procedures § 80.331 Bridge-to-bridge communication procedure. (a) Vessels... position). I plan to (give proposed course of action). Over. (3) (Coast station), this is (vessel's...

  1. Development of bioinspired Mn4O4-cubane water oxidation catalysts: lessons from photosynthesis.

    Science.gov (United States)

    Dismukes, G Charles; Brimblecombe, Robin; Felton, Greg A N; Pryadun, Ruslan S; Sheats, John E; Spiccia, Leone; Swiegers, Gerhard F

    2009-12-21

    Hydrogen is the most promising fuel of the future owing to its carbon-free, high-energy content and potential to be efficiently converted into either electrical or thermal energy. The greatest technical barrier to accessing this renewable resource remains the inability to create inexpensive catalysts for the solar-driven oxidation of water. To date, the most efficient system that uses solar energy to oxidize water is the photosystem II water-oxidizing complex (PSII-WOC), which is found within naturally occurring photosynthetic organisms. The catalytic core of this enzyme is a CaMn(4)O(x) cluster, which is present in all known species of oxygenic phototrophs and has been conserved since the emergence of this type of photosynthesis about 2.5 billion years ago. The key features that facilitate the catalytic success of the PSII-WOC offer important lessons for the design of abiological water oxidation catalysts. In this Account, we examine the chemical principles that may govern the PSII-WOC by comparing the water oxidation capabilities of structurally related synthetic manganese-oxo complexes, particularly those with a cubical Mn(4)O(4) core ("cubanes"). We summarize this research, from the self-assembly of the first such clusters, through the elucidation of their mechanism of photoinduced rearrangement to release O(2), to recent advances highlighting their capability to catalyze sustained light-activated electrolysis of water. The [Mn(4)O(4)](6+) cubane core assembles spontaneously in solution from monomeric precursors or from [Mn(2)O(2)](3+) core complexes in the presence of metrically appropriate bidentate chelates, for example, diarylphosphinates (ligands of Ph(2)PO(2)(-) and 4-phenyl-substituted derivatives), which bridge pairs of Mn atoms on each cube face (Mn(4)O(4)L(6)). The [Mn(4)O(4)](6+) core is enlarged relative to the [Mn(2)O(2)](3+) core, resulting in considerably weaker Mn-O bonds. Cubanes are ferocious oxidizing agents, stronger than analogous complexes

  2. Removal of failed crown and bridge.

    Science.gov (United States)

    Sharma, Ashu; Rahul, G R; Poduval, Soorya T; Shetty, Karunakar

    2012-07-01

    Crown and bridge have life span of many years but they fail for a number of reasons. Over the years, many devices have been designed to remove crowns and bridges from abutment teeth. While the removal of temporary crowns and bridges is usually very straightforward, the removal of a definitive cast crown with unknown cement is more challenging. Removal is often by destructive means. There are a number of circumstances, however, in which conservative disassembly would aid the practitioner in completing restorative/endodontic procedures. There are different mechanisms available to remove a failed crown or bridge. But there is no information published about the classification of available systems for crown and bridge removal. So it is logical to classify these systems into different groups which can help a clinician in choosing a particular type of system depending upon the clinical situation. The aim of this article is to provide a classification for various crown and bridge removal systems; describe how a number of systems work; and when and why they might be used. A PubMed search of English literature was conducted up to January 2010 using the terms: Crown and bridge removal, Crown and bridge disassembly, Crown and bridge failure. Additionally, the bibliographies of 3 previous reviews, their cross references as well as articles published in various journals like International Endodontic Journal, Journal of Endodontics and were manually searched. Key words:Crown and bridge removal, Crown and bridge disassembly, Crown and bridge failure. PMID:24558549

  3. Remediation: Higher Education's Bridge to Nowhere

    Science.gov (United States)

    Complete College America, 2012

    2012-01-01

    The intentions were noble. It was hoped that remediation programs would be an academic bridge from poor high school preparation to college readiness. Sadly, remediation has become instead higher education's "Bridge to Nowhere." This broken remedial bridge is travelled by some 1.7 million beginning students each year, most of whom will…

  4. Ferromagnetic resonance study of MnAs /(Ga,Mn)As bilayers

    Science.gov (United States)

    Cubukcu, M.; von Bardeleben, H. J.; Khazen, Kh.; Cantin, J. L.; Zhu, M.; Wilson, M. J.; Schiffer, P.; Samarth, N.

    2009-04-01

    We report the investigation of the static and dynamic magnetic properties of type-A MnAs /Ga0.945Mn0.055As (001) bilayers. Static magnetization measurements show them to be ferromagnetically coupled with an exchange bias field of ˜340Oe. The magnetocrystalline anisotropy constants of the (Ga,Mn)As layer were determined by X-band ferromagnetic resonance (FMR) spectroscopy. The (Ga,Mn)As layers are magnetically inhomogeneous as evidenced by a strong broadening of the (Ga,Mn)As uniform mode linewidth. The MnAs FMR spectra reveal the presence of a small MnAs fraction with a different orientation.

  5. Development of a parent version of the Manchester-Minneapolis quality of life survey for use by parents and carers of UK children: MMQL-UK (PF

    Directory of Open Access Journals (Sweden)

    Williams John G

    2008-02-01

    Full Text Available Abstract Background Although it is now widely endorsed that children should as far as possible rate their own health related quality of life (HRQL, there are situations where proxy information on child HRQL may be useful, especially where a child is too ill or young to provide their own HRQL assessment. There is limited availability of generic HRQL scales that have a parallel child and parent version and that are reliable, valid, brief, comprehensible and suitable for use in UK populations. The aims of this study were therefore to develop and validate a parent version of the anglicised Manchester-Minneapolis Quality of Life child form (MMQL-UK (CF and to determine the level of association between the child and parent versions of this form. Methods This study was undertaken concurrently with the anglicisation and validation of the MMQL, a measure of HRQL developed for use with children in North America. At that time, no parent version existed, so the MMQL form for children (MMQL-UK (CF was used as the basis for the development of the MMQL-UK parent form (PF. The sample included a control group of healthy children and their parents and five exemplar groups; children diagnosed with asthma, diabetes or inflammatory bowel disease and their parents, children in remission from cancer and their parents and children in public care and their carers. Consistency of the MMQL-UK (PF components were assessed by calculating Cronbach's alpha. Validation of the parent questionnaire was undertaken by comparing MMQL-UK (PF component scores with comparable components on the proxy PedsQL™ quality of life scales, comparing MMQL-UK (PF component scores between parents of healthy and chronic disease children and by comparison of component scores from children and their parents or carers. Reproducibility and responsiveness were assessed by retesting parents by follow-up questionnaires. Results A total of 874 children (completing MMQL-UK (CF and 572 parents or carers

  6. Tetranuclear polybipyridyl complexes of Ru(II) and Mn(II), their electro- and photo-induced transformation into di-mu-oxo Mn(III)Mn(IV) hexanuclear complexes.

    Science.gov (United States)

    Romain, Sophie; Baffert, Carole; Dumas, Stéphane; Chauvin, Jérôme; Leprêtre, Jean-Claude; Daveloose, Denis; Deronzier, Alain; Collomb, Marie-Noëlle

    2006-12-28

    Three heterotetranuclear complexes, [{Ru(II)(bpy)(2)(L(n))}(3)Mn(II)](8+) (bpy = 2,2'-bipyridine, n = 2, 4, 6), in which a Mn(II)-tris-bipyridine-like centre is covalently linked to three Ru(II)-tris-bipyridine-like moieties using bridging bis-bipyridine L(n) ligands, have been synthesised and characterised. The electrochemical, photophysical and photochemical properties of these complexes have been investigated in CH(3)CN. The cyclic voltammograms of the three complexes exhibit two successive very close one-electron metal-centred oxidation processes in the positive potential region. The first, which is irreversible, corresponds to the Mn(II)/Mn(III) redox system (E(pa) approximately 0.82 V vs Ag/Ag(+) 0.01 M in CH(3)CN-0.1 M Bu(4)NClO(4)), whereas the second which is, reversible, is associated with the Ru(II)/Ru(III) redox couple (E(1/2) approximately 0.91 V). In the negative potential region, three successive reversible four electron systems are observed, corresponding to ligand-based reduction processes. The three stable dimeric oxidized forms of the complexes, [Mn(2)(III,IV)O(2){Ru(II)(bpy)(2)(L(n))}(4)](11+), [Mn(2)(IV,IV)O(2){Ru(II)(bpy)(2)(L(n))}(4)](12+) and [Mn(2)(IV,IV)O(2){Ru(III)(bpy)(2)(L(n))}(4)](16+) are obtained in fairly good yields by sequential electrolyses after consumption of respectively 1.5, 0.5 and 3 electrons per molecule of initial tetranuclear complexes. The formation of the di-micro-oxo binuclear complexes are the result of the instability of the {[Ru(II)(bpy)(2)(L(n))](3)Mn(III)}(9+) species, which react with residual water, via a disproportionation reaction and the release of one ligand, [Ru(II)(bpy)(2)(L(n))](2+). A quantitative yield can be obtained for these reactions if the electrochemical oxidations are performed in the presence of an added external base like 2,6-dimethylpyridine. Photophysical properties of these compounds have been investigated showing that the luminescence of the Ru(II)-tris-bipyridine-like moieties is little

  7. Comparison between Modern Violin Bridge and Baroque Violin Bridge by Photoelastic Observation and Frequency Analysis

    Science.gov (United States)

    Matsutani, Akihiro

    2004-05-01

    A comparison between the modern bridge and the baroque bridge of the violin by photoelastic observation was carried out. The relationship between the stress part and the hole is symmetric in the modern and baroque bridges. The measured spectral envelopes of baroque bridges are similar to those of modern bridges in D- or G-strings, and have peaks at a frequency higher than those of modern bridges in E-string. The visualization method as used in this study may provide hints for the design of violin bridges.

  8. Novel thioarsenates {[Mn(2,2'-bipy)2(SCN)][Mn(2,2'-bipy)](As(V)S4)}2 and {[Mn(2,2'-bipy)2(SCN)]2[As(III)2(S2)2S2]}: introducing an anionic second ligand to modify MnII complex cations of 2,2'-bipyridine.

    Science.gov (United States)

    Liu, Guang-Ning; Guo, Guo-Cong; Wang, Ming-Sheng; Huang, Jin-Shun

    2014-03-14

    Two novel manganese thioarsenates, {[Mn(2,2'-bipy)2(SCN)][Mn(2,2'-bipy)](As(V)S4)}2 (1, 2,2'-bipy = 2,2'-bipyridine) and {[Mn(2,2'-bipy)2(SCN)]2[As(III)2(S2)2S2]} (2), containing thiocyanate-modified Mn-2,2'-bipy complex cations were synthesized. They feature two terminal [Mn(2,2'-bipy)2(SCN)](+) complex cations bridged by a polyanion {[Mn(2,2'-bipy)]2(As(V)S4)2}(2-) for 1 and a cyclic thioarsenate anion (As(III)2S6)(2-) for 2. In 2, the [As(III)2(S2)2S2](2-) anion can be described as two (As(III)S3)(3-) trigonal-pyramids interlinked through S-S bonds. The method to obtain new metal complex cations shown here, introducing an anionic second ligand to modify the number of coordination sites and the charges of the metal complex cations simultaneously, is different from the traditional methods, varying either the TM center or the organic ligand or employing mixed neutral organic ligands, and may open up a new route for preparing novel chalcogenidometalates. Compounds 1 and 2 exhibit wide optical gaps of 2.20 and 2.67 eV, respectively, and photoluminescence with the emission maxima occurring around 440 nm. Magnetic measurements show the presence of antiferromagnetic interactions between Mn(II) centers in the two compounds.

  9. Public Forum Before the Committee on Urban Indians in L.A., Calif. (Dec. 16-17, 1968); Dallas, Tex. (Feb. 13-14, 1969); Minneapolis-St. Paul, Minn. (Mar. 18-19, 1969); San Francisco, Calif. (Apr. 11-12, 1968); Phoenix, Ariz. (Apr. 17-18, 1969).

    Science.gov (United States)

    National Council on Indian Opportunity, Washington, DC.

    The proceedings of public forums of the National Council of Indian Opportunity are recorded in these 5 documents. These forums were designed to gain information on the condition of urban American Indians living in Los Angeles, Minneapolis-St. Paul, San Francisco, Dallas, and Phoenix. Included in each of the documents are discussions on such…

  10. Comprehensive Real-Time Bridge Health Monitoring System of Tongtai Bridge

    OpenAIRE

    Lei Su-su; Gao Yong-tao; Pan Dan-guang

    2015-01-01

    Tongtai Bridge is the world’s largest suspension curve-girder-skew-arch bridge, which is located in Zhangjiakou, China. The understanding of mechanics characteristics is limited to such complex bridges, so it is necessary to establish reliable health monitoring system to investigate the static and dynamic responses and monitor the safety of the bridge. A comprehensive real-time bridge health monitoring system is establish, which includes four aspects: sensor system, data acquisition and trans...

  11. New Concept for Durable Concrete Bridges

    OpenAIRE

    Damek, Marek

    2015-01-01

    This master’s thesis covers the design of a post-tensioned concrete bridge in Trondheim municipality in Norway, in collaboration with Statens vegvesen (SVV). The concept of the bridge is inspired by Egg-Graben-Brücke in Austria, which was designed and built without steel reinforcement in the bridge deck. The idea is to eliminate steel reinforcement which can corrode in the bridge deck. The total length of the bridge is 73 meters and it is divided into 3 spans. The crosssection ...

  12. Heavy Vehicles on Minor Highway Bridges

    DEFF Research Database (Denmark)

    Kirkegaard, Poul Henning; Nielsen, Søren R. K.; Enevoldsen, I.

    Vibration of a bridge structure due to the passage of vehicles is an important consideration in the design of bridges. Further, a common problem in bridge engineering practice in these years is the upgrading of minor highway bridges (=5-20 m) to carry heavier loads partly due to a tendency...... of heavier trucks moving at larger speeds, and partly because the authorities want to permit transportation of special heavy goods at a larger part of the road net. These needs will in many cases cause the strengthening of the bridges becomes necessary. In order to keep the expenses of such strengthening...... the results obtained using the numerical models given in details in "Heavy Vehicles on Minor Highway Bridges : dynamic modelling of vehicles and bridges". The models are established using a ordinary vehicle which consists of a 48 t Scania with a 3 axle tractor and a 3 axle trailer, joined in a flexible hinge...

  13. Heavy Vehicles on Minor Highway Bridges

    DEFF Research Database (Denmark)

    Kirkegaard, Poul Henning; Nielsen, Søren R. K.; Enevoldsen, I.

    Vibration of a bridge structure due to the passage of vehicles is an important consideration in the design of bridges. Further, a common problem in bridge engineering practice in these years is the upgrading of minor highway bridges (=5-20 m) to carry heavier loads partly due to a tendency...... of heavier trucks moving at larger speeds, and partly because the authorities want to permit transportation of special heavy goods at a larger part of the road net. These needs will in many cases cause the strengthening of the bridges becomes necessary. In order to keep the expenses of such strengthening...... the numerical models for the mathematical models of the vehicles and the bridge from which the load amplification factors can be estimated assuming that the dynamic parameters of the vehicles and the modal parameters of the bridge are known....

  14. Scandium phosphate alloyed with Mn4+

    International Nuclear Information System (INIS)

    Interaction of manganese dioxide with ScPO4 matrix with xynothyme structure is investigated by X ray diffraction, IR spectroscopy, ESR and luminescent spectroscopy method. It is ascertained that the manganese ions (up to 1.5 mas. %) are incorporated into ScPO4 crystal lattice without changing its structure. Being disproportionate according to Mn4+ → Mn2+ + Mn5+ scheme manganese is present in ScPO4 crystal lattice in the form of Mn2+ (Sc3+ → Mn2+) and MnO43- ion similar to PO43- one. Isovalent substitution Sc3+ → Mn3+ cannot be excluded either. Manganese ions are rigidly fixed inside ScPO4 structure positions

  15. Full-bridge capacitive extensometer

    Science.gov (United States)

    Peters, Randall D.

    1993-08-01

    Capacitive transducers have proven to be very effective sensors of small displacements, because of inherent stability and noninvasive high resolution. The most versatile ones have been those of a differential type, in which two elements are altered in opposite directions in response to change of the system parameter being monitored. Oftentimes, this differential pair has been incorporated into a bridge circuit, which is a useful means for employing synchronous detection to improve signal to noise ratios. Unlike previous differential capacitive dilatometers which used only two active capacitors, the present sensor is a full-bridge type, which is well suited to measuring low-level thermal expansions. This analog sensor is capable of 0.1 μm resolution anywhere within a range of several centimeters, with a linearity of 0.1%. Its user friendly output can be put on a strip chart recorder or directed to a computer for sophisticated data analysis.

  16. Noise Considerations in Resistance Bridges

    DEFF Research Database (Denmark)

    Diamond, Joseph M.

    1963-01-01

    thermometry, where the noise in the unknown resistor will predominate strongly. An impedance step-up device (transformer or tuned circuit) is valuable in raising the bridge signal and noise level above the noise of the first amplifier tube. However, as the step-up ratio is increased, two counterfactors appear......, namely, noise in the loss resistance of the step-up device, and grid current noise. There is therefore an optimum step-up ratio, which has been found. The step-up device is permitted to have a different temperature from the unknown and standard resistors, to evaluate the advantage of cooling it....... With certain assumptions about the noise and grid current of the first tube it is found that the equivalent temperature of a unity ratio (Mueller) bridge used for liquid helium measurements may be 400°K....

  17. Stability of Axisymmetric Liquid Bridges

    CERN Document Server

    Rubinstein, Boris

    2016-01-01

    We study stability of axisymmetric liquid bridges between two axisymmetric solid bodies in the absence of gravity under arbitrary asymmetric perturbations which are expanded into a set of angular Fourier modes. We determine the stability region boundary for every angular mode in case of both fixed and free contact lines. Application of this approach allows us to demonstrate existence of stable convex nodoid menisci between two spheres.

  18. 2015 Bridge Inspection ERC Training

    OpenAIRE

    Dougherty, Merril

    2015-01-01

    This presentation will discuss recent changes to the County Bridge Inspection Program from the perspective of both the FHWA and INDOT. We will also discuss the responsibilities of the local public agency’s (LPA’s) employee in responsible charge (ERC) with respect to managing this program. As this course is a yearly requirement, all county ERCs are encouraged to attend. Pre-registering is strongly encouraged by e-mailing your contact information to .

  19. The Bridge Program - Participant Perspectives

    OpenAIRE

    Rönnqvist, Riitta; Hakonen, Anu; Vartiainen, Matti

    2015-01-01

    The Nokia Bridge Program was established in summer 2011 in order to "make the best of the restructuring: create meaningful opportunities for individuals and local economies impacted by workforce reductions" and to "assist individuals in re-employment". This document reports whether and how the program helped individuals avoid the known negative effects of job loss and find meaningful re-employment. The document also reports how affected employees formed perceptions about Nokia´s fairness and ...

  20. Inspection Strategies for Concrete Bridges

    DEFF Research Database (Denmark)

    Sørensen, John Dalsgaard; Thoft-Christensen, Palle

    1989-01-01

    In this paper an optimal inspection strategy for concrete bridges based on periodic routine and detailed inspections is presented. The failure mode considered is corrosion of the reinforcement due to chlorides. A simple modelling of the corrosion and of the inspection strategy is presented....... The optimal inspection strategy is determined from an optimization problem, where the design variables are time intervals between detailed inspections and the concrete cover. The strategy is illustrated on a simple structure, namely a reinforced concrete beam....

  1. Parabolic metamaterials and Dirac bridges

    Science.gov (United States)

    Colquitt, D. J.; Movchan, N. V.; Movchan, A. B.

    2016-10-01

    A new class of multi-scale structures, referred to as `parabolic metamaterials' is introduced and studied in this paper. For an elastic two-dimensional triangular lattice, we identify dynamic regimes, which corresponds to so-called `Dirac Bridges' on the dispersion surfaces. Such regimes lead to a highly localised and focussed unidirectional beam when the lattice is excited. We also show that the flexural rigidities of elastic ligaments are essential in establishing the `parabolic metamaterial' regimes.

  2. Severe ASR damaged concrete bridges

    DEFF Research Database (Denmark)

    Antonio Barbosa, Ricardo; Gustenhoff Hansen, Søren

    2015-01-01

    Technical University of Denmark (DTU) and University of Southern Denmark (SDU) have conducted several full-scale experiments with severe ASR deteriorated bridges. This paper presents few and preliminary results from both the shear tests and the measuring of the material properties. The shear test...... show that the shear capacity is almost unaffected of ASR despite significant reduction in compressive concrete strength. Furthermore, measurements show a significant tensile reinforcement strain developed due to ASR expansion....

  3. Halliburton Composite Bridge Plug Assembly

    Energy Technology Data Exchange (ETDEWEB)

    Starbuck, J.M.; Luttrell, C.R.; Aramayo, G.

    2005-01-15

    The overall objectives of this CRADA were to assist Halliburton in analyzing a composite bridge plug and to determine why their original design was failing in the field. In Phase 1, finite element analyses were done on the original composite slip design and several alternative designs. The composite slip was the component in the bridge plug that was failing. The finite element code ABAQUS was used for these calculations and I-DEAS was used as the pre- and post-processor in the analyses. Several different designs and materials were analyzed and recommendations were made towards improving the design. In Phase 2, the objective was to develop finite element models that would accurately represent the deformations in the entire all-composite 4-1/2' diameter bridge plug assembly. The finite element code LS-DYNA was used and the results from this effort were intended to expand Halliburton's composite design and analysis capabilities with regard to developing future composite components for downhole tools. In addition to the finite element modeling, this effort involved the utilization of micromechanics to determine the necessary composite material properties that were needed as input for finite element codes.

  4. Effects of bonding type and interface geometry on coherent transport through the single-molecule magnet Mn12

    OpenAIRE

    Park, Kyungwha; Barraza-Lopez, Salvador; García-Suárez, Víctor M.; Ferrer, Jaime

    2010-01-01

    We examine theoretically coherent electron transport through the single-molecule magnet Mn-12, bridged between Au(111) electrodes, using the nonequilibrium Green's function method and the density-functional theory. We analyze the effects of bonding type, molecular orientation, and geometry relaxation on the electronic properties and charge and spin transport across the single-molecule junction. We consider nine interface geometries leading to five bonding mechanisms and two molecular orientat...

  5. Large magnetoresistance of MnBi/Bi/MnBi spin valve

    Energy Technology Data Exchange (ETDEWEB)

    Tarawneh, Khaldoun, E-mail: Khaldoun@psut.edu.jo [Princess Sumaya University for Technology, Amman 11941 (Jordan); Al-Aqtash, Nabil; Sabirianov, Renat [University of Nebraska at Omaha, Omaha, NE 68182 (United States)

    2014-08-01

    A transport magetoresistance (MR) of MnBi/Bi/MnBi spin valve device was calculated using density functional theory coupled with nonequilibrium Green's function method. The calculated transmission MR of the MnBi/Bi/MnBi spin valve device is around 750%, Obtained MR is very large compared with MR observed experimentally in MnBi junctions at room temperature (MR∼70%). Large MR is consistent with a large transport spin polarization was demonstrated in MnBi films by the point contact Andreev reflection spectroscopy. MR of experimental point contacts is observed to be low is probably due to the rough interfaces that increased scattering and contact resistance. Consequently, a spin-valve MnBi/Bi/MnBi device could potentially have large MR that could be controlled by varying the thickness of the Bi spacer. Thus, MnBi is a promising candidate for high MR devices with tunable spacer properties. - Highlights: • We calculate the transport magetoresistance (MR) of MnBi/Bi/MnBi spin valve device. • The calculated transmission MR of the MnBi/Bi/MnBi spin valve device is around 750%. • MR depend on the thickness of Bi layer. • MnBi is a promising candidate for high MR devices using spin polarizing current.

  6. Synthesis and Structure Characterization of Mn2(CO)6(μ-S2CPiPr3)

    Institute of Scientific and Technical Information of China (English)

    马永强; 陈晓; 李靖; 谢庆兰; 王宏根

    2003-01-01

    The homobinuclear compound Mn2(CO)6(u-S2CPiPr3) has been prepared by the reaction of BrMn(CO)3(u-S2CPiPr3) with NaMn(CO)5 in refluxing THF, and its structure was determined by single-crystal X-ray diffraction. Crystallographic data: C16H21Mn2O6PS2, Mr = 514.30, triclinic, space group Pīwith a = 9.293(3), b = 9.443(3), c = 12.977(4) A。, a = 83.633(5), b= 83.719(5), c= 73.399(5) V = 1081.1(6) A。3, Z = 2, Dc = 1.580 g/cm3, a = 1.463 mm-1, F(000) = 524, the final R = 0.0330 and wR = 0.0729 for 2945 observed reflections with I > 2o(I). The crystal structure determination shows that the ligand can be described as a η2(S, S') chelate to one manganese and a η3(S, C, S') pseudoallyl to the other manganese bridging the Mn-Mn bond asymmetrically.

  7. Nondestructive evaluation techniques for enhanced bridge inspection

    Energy Technology Data Exchange (ETDEWEB)

    Thomas, G.; Benson, S.; Durbin, P.; Del Grande, N.; Haskins, J.; Brown, A.; Schneberk, D.

    1993-10-01

    Nondestructive evaluation of bridges is a critical aspect in the US aging infrastructure problem. For example in California there are 26,000 bridges, 3000 are made of steel, and of the steel bridges, 1000 are fracture critical. California Department of Transportation (Caltrans), Federal Highway Administration, and Lawrence Livermore National Laboratory (LLNL) are collaborating to develop and field NDE techniques to improve bridge inspections. We have demonstrated our NDE technologies on several bridge inspection applications. An early collaboration was to ultrasonically evaluate the steel pins in the E-9 pier on the San Francisco Bay Bridge. Following the Loma-Prieta earthquake in 1989 and the road way collapse at the E-9 pier, a complete nondestructive evaluation was conducted by Caltrans inspectors and several ultrasonic indications were noted. LLNL worked with Caltrans to help identify the source of these reflections. Another project was to digitally enhance high energy radiographs of bridge components such as cable end caps. We demonstrated our ability to improve the detection of corrosion and fiber breakage inside the end cap. An extension of this technology is limited view computer tomography (CT). We implemented our limited view CT software and produced cross-sectional views of bridge cables from digitized radiographic films. Most recently, we are developing dual band infrared imaging techniques to assess bridge decks for delaminations. We have demonstrated the potential of our NDE technology for enhancing the inspection of the country`s aging bridges.

  8. Physical properties of Mn oxypnictide (LaO)MnPn; Pn = P, As, Sb

    Science.gov (United States)

    Onizawa, M.; Otsuka, S.; Takeda, R.; Kato, K.; Umeyama, N.; Ikeda, S.; Hiramoto, S.; Yoshida, F.; Moriyoshi, C.; Kuroiwa, Y.; Tobimatu, K.; Sato, H.; Sawada, M.; Namatame, H.; Taniguchi, M.; Watanabe, T.; Takano, Y.; Takase, K.

    2011-12-01

    We have investigated physical properties of the layered Mn oxypnictides (LaO)MnPn; Pn = P, As, Sb. Electrical resistivity of three samples, indicting semiconducting behaviors, drastically increases with lowering temperature. The optical band gaps estimated from the diffusive reflectance are about 1.6 eV and they don't depend on pnictogen atoms even though the lattice constants widely change. Magnetizations of (LaO)MnAs and (LaO)MnSb show very weak temperature dependence with positive slope against temperature. Some magnetic order is expected to exist at higher temperature than room temperature. Consequently, the Mn oxypnictides (LaO)MnPn are magnetic semiconductors.

  9. New insights into the comprehension of the magnetic properties of dinuclear Mn(III) compounds with the general formula [{MnL(NN)}2(μ-O)(μ-n-RC6H4COO)2]X2.

    Science.gov (United States)

    Escriche-Tur, Luis; Font-Bardia, Mercè; Albela, Belén; Corbella, Montserrat

    2016-07-19

    Five new dinuclear Mn(iii) compounds with benzoato derivative bridges [{Mn(bpy)L}2(μ-O)(μ-n-RC6H4COO)2]X2 (n-R = 3-MeO, 4-MeO and 4-tBu, X = NO3(-) and ClO4(-)) were synthesised and characterised. According to X-ray diffraction, the X anions tend to be coordinated to the Mn ions and may occupy the place of the monodentate ligand L. Two structural isomers that only differ in one of their monodentate ligands have been obtained with the 3-MeOC6H4COO(-) bridges. For all compounds, the Mn(iii) ions display elongated octahedra with a pronounced rhombic distortion. To quantify these distortions separately, the elongation and rhombicity parameters Δ and ρ have been defined. The magnetic study shows a good relationship between the distortion of the coordination polyhedra and the zero field splitting parameters (DMn and EMn). From the magnetic data of a powder sample, it is possible to determine the sign and magnitude of DMn for ferromagnetic systems or weak antiferromagnetic systems with DMn < 0. For this kind of dinuclear compound, the R group at the meta position, the rhombic distortion of the octahedra, and large torsion angles between the Jahn-Teller axes lead to ferromagnetic interactions. PMID:27295557

  10. (54)Mn Radiotracers Demonstrate Continuous Dissolution and Reprecipitation of Vernadite (δ-MnO2) during Interaction with Aqueous Mn(II).

    Science.gov (United States)

    Elzinga, Evert J

    2016-08-16

    (54)Mn radiotracers were used to assess Mn atom exchange between aqueous Mn(II) and vernadite (δ-MnO2) at pH 5.0. Continuous solid-liquid redistribution of (54)Mn atoms occurred, and systems are near isotopic equilibrium after reaction for 3 months. Despite this extensive exchange, X-ray diffraction and X-ray absorption spectroscopy data showed no major changes in vernadite bulk mineralogy. These results demonstrate that the vernadite-Mn(II) interface is dynamic, with the substrate undergoing continuous dissolution and reprecipitation mediated by aqueous Mn(II) without observable impacts on its mineralogy. Interfacial redox reactions between adsorbed Mn(II) and solid-phase Mn(IV) and Mn(III) are proposed as the main drivers of this process. Interaction between aqueous Mn(II) and structural Mn(III) likely involves interfacial electron transfer coupled with Mn atom exchange. The exchange of aqueous Mn(II) and solid-phase Mn(IV) is more complex and is proposed to result from coupled interfacial comproportionation-disproportionation reactions, where electron transfer from adsorbed Mn(II) to lattice Mn(IV) produces transient Mn(III) species that disproportionate to regenerate aqueous Mn(II) and structural Mn(IV). These findings provide further evidence of the importance of Mn(II)(aq)-MnO2(s) interactions and the attendant production of transient Mn(III) intermediates to the geochemical functioning of phyllomanganates in environments undergoing Mn redox cycling. PMID:27403960

  11. Mn(ii) mediated degradation of artemisinin based on Fe3O4@MnSiO3-FA nanospheres for cancer therapy in vivo

    Science.gov (United States)

    Chen, Jian; Zhang, Weijie; Zhang, Min; Guo, Zhen; Wang, Haibao; He, Mengni; Xu, Pengping; Zhou, Jiajia; Liu, Zhenbang; Chen, Qianwang

    2015-07-01

    Artemisinin (ART) is a natural drug with potent anticancer activities related with Fe2+ mediated cleavage of the endoperoxide bridge in ART. Herein, we reported that Mn2+ could substitute for Fe2+ to react with ART and generate toxic products, inducing a much higher anticancer efficiency. On this basis, we prepared pH-responsive Fe3O4@MnSiO3-FA nanospheres which can efficiently deliver hydrophobic ART into tumors in mice models. Mn2+ was released in acidic tumor environments and intracellular lysosomes, interacting with ART to kill cancer cells. The ART-loaded nanocarriers could suppress tumor growth more efficiently than free ART, which could be further illustrated by magnetic resonance imaging (MRI). Histological analysis revealed that the drug delivery system had no obvious effect on the major organs of mice. ART has been reported to have lower toxicity than chemotherapeutics. The ART-loaded nanocarriers are promising to be used in improving the survival of chemotherapy patients, providing a novel method for clinical tumor therapy.Artemisinin (ART) is a natural drug with potent anticancer activities related with Fe2+ mediated cleavage of the endoperoxide bridge in ART. Herein, we reported that Mn2+ could substitute for Fe2+ to react with ART and generate toxic products, inducing a much higher anticancer efficiency. On this basis, we prepared pH-responsive Fe3O4@MnSiO3-FA nanospheres which can efficiently deliver hydrophobic ART into tumors in mice models. Mn2+ was released in acidic tumor environments and intracellular lysosomes, interacting with ART to kill cancer cells. The ART-loaded nanocarriers could suppress tumor growth more efficiently than free ART, which could be further illustrated by magnetic resonance imaging (MRI). Histological analysis revealed that the drug delivery system had no obvious effect on the major organs of mice. ART has been reported to have lower toxicity than chemotherapeutics. The ART-loaded nanocarriers are promising to be used in

  12. XPS Determination of Mn Oxidation States in Mn (Hydr)oxides

    Energy Technology Data Exchange (ETDEWEB)

    Ilton, Eugene S.; Post, Jeffrey E.; Heaney, Peter J.; Ling, Florence T.; Kerisit, Sebastien N.

    2016-03-15

    Hydrous manganese oxides are an important class of minerals that help regulate the geochemical redox cycle in near-surface environments and are also considered to be promising catalysts for energy applications such as the oxidation of water. A complete characterization of these minerals is required to better understand their catalytic activity. In this contribution an empirical methodology using X-ray photoelectron spectroscopy (XPS) is developed to quantify the oxidation state of hydrous multivalent manganese oxides with an emphasis on birnessite, a common layered structure that occurs readily in Nature but is also the oxidized endmember in biomimetic water-oxidation catalysts. The Mn2p3/2, Mn3p, and Mn3s lines of near monovalent Mn(II), Mn(III), and Mn(IV) oxides were fit with component peaks; after the best fit was obtained the relative widths, heights and binding energies of the components were fixed. Unknown multivalent samples were fit such that binding energies, intensities, and widths of each oxidation state, composed of a packet of correlated component peaks, were allowed vary. whereas widths were constrained to maintain the difference between the standards. Both average and individual mole fraction oxidation states for all three energy levels were strongly correlated with close agreement between Mn3s and Mn3p, whereas Mn2p3/2 gave systematically more reduced results. Limited stoichiometric analyses were consistent with Mn3p and Mn3s. Further, evidence indicates the shape of the Mn3p line was less sensitive to the bonding environment than Mn2p. Consequently, fitting the Mn3p and Mn3s lines yields robust quantification of oxidation states over a range of hydrous Mn oxide polytypes and compositions. In contrast, a common method for determining oxidation states that utilizes the multiplet splitting of the Mn3s line is not appropriate for birnessites.

  13. Oxygen Isotope Evidence for Mn(II)-Catalyzed Recrystallization of Manganite (γ-MnOOH).

    Science.gov (United States)

    Frierdich, Andrew J; Spicuzza, Michael J; Scherer, Michelle M

    2016-06-21

    Manganese is biogeochemically cycled between aqueous Mn(II) and Mn(IV) oxides. Aqueous Mn(II) often coexists with Mn(IV) oxides, and redox reactions between the two (e.g., comproportionation) are well known to result in the formation of Mn(III) minerals. It is unknown, however, whether aqueous Mn(II) exchanges with structural Mn(III) in manganese oxides in the absence of any mineral transformation (similar to what has been reported for aqueous Fe(II) and some Fe(III) minerals). To probe whether atoms exchange between a Mn(III) oxide and water, we use a (17)O tracer to measure oxygen isotope exchange between structural oxygen in manganite (γ-MnOOH) and water. In the absence of aqueous Mn(II), about 18% of the oxygen atoms in manganite exchange with the aqueous phase, which is close to the estimated surface oxygen atoms (∼11%). In the presence of aqueous Mn(II), an additional 10% (for a total of 28%) of the oxygen atoms exchange with water, suggesting that some of the bulk manganite mineral (i.e., beyond surface) is exchanging with the fluid. Exchange of manganite oxygen with water occurs without any observable change in mineral phase and appears to be independent of the rapid Mn(II) sorption kinetics. These experiments suggest that Mn(II) catalyzes manganese oxide recrystallization and illustrate a new pathway by which these ubiquitous minerals interact with their surrounding fluid. PMID:27249316

  14. Oxygen Isotope Evidence for Mn(II)-Catalyzed Recrystallization of Manganite (γ-MnOOH).

    Science.gov (United States)

    Frierdich, Andrew J; Spicuzza, Michael J; Scherer, Michelle M

    2016-06-21

    Manganese is biogeochemically cycled between aqueous Mn(II) and Mn(IV) oxides. Aqueous Mn(II) often coexists with Mn(IV) oxides, and redox reactions between the two (e.g., comproportionation) are well known to result in the formation of Mn(III) minerals. It is unknown, however, whether aqueous Mn(II) exchanges with structural Mn(III) in manganese oxides in the absence of any mineral transformation (similar to what has been reported for aqueous Fe(II) and some Fe(III) minerals). To probe whether atoms exchange between a Mn(III) oxide and water, we use a (17)O tracer to measure oxygen isotope exchange between structural oxygen in manganite (γ-MnOOH) and water. In the absence of aqueous Mn(II), about 18% of the oxygen atoms in manganite exchange with the aqueous phase, which is close to the estimated surface oxygen atoms (∼11%). In the presence of aqueous Mn(II), an additional 10% (for a total of 28%) of the oxygen atoms exchange with water, suggesting that some of the bulk manganite mineral (i.e., beyond surface) is exchanging with the fluid. Exchange of manganite oxygen with water occurs without any observable change in mineral phase and appears to be independent of the rapid Mn(II) sorption kinetics. These experiments suggest that Mn(II) catalyzes manganese oxide recrystallization and illustrate a new pathway by which these ubiquitous minerals interact with their surrounding fluid.

  15. Study on structural system of Sutong Bridge

    Institute of Scientific and Technical Information of China (English)

    Zhang Xigang; Pei Minshan; Yuan Hong; Xu Liping; Zhu Bin

    2009-01-01

    Sutong Bridge, whose layout is [ (100 + 100 + 300) + 1 088 + ( 300 + 100 + 100) ] m, marks the largest span of cable-stayed bridges in the world. The complex natural condition at the bridge site and the strict requirements for resistance of wind and seismic action make it crucial to choose a favorable structural system to assure the function and safety of the bridge. The comparison among several optional structural systems for Sutong Bridge is illustrated. After detailed analysis is carried out for viscous damper and hydraulic buffer, super liquid viscous damper with additional displacement limitation is designed for the first application in bridge engineering. The parameters for the damper is analyzed and studied and the dampers are installed suecessfuUy after quality tests.

  16. Evaluation method research on prestressed concrete bridges

    Institute of Scientific and Technical Information of China (English)

    HUANG Qiao; LIN Yang-zi; REN Yuan

    2008-01-01

    Considering the construction features of prestressed concrete bridge, the comprehensive evaluation method about the bridge damage conditions are studied. Particular attentions are paid on establishing a multi-level evaluation model for damaged prestressed concrete bridge, and the evaluation indices of the model as well as the rating standards are defined in the model. A normal relative function about the evaluation indices of each element is developed to calculate the relative degree, and for each element which is no sub-level elements. When evaluating the elements in sub-item level or index level of the model, the weights of elements that are pertained to one element are adopted, taking account of their deterioration degree. At the same time, the dam-age conditions of bridge are characterized by relative degree, element evaluation scale and structural technology mark of bridge ,so it agrees with Code for Maintenance of Highway Bridges and Culvers.

  17. Porous Coordination Polymers Based on {Mn6} Single-Molecule Magnets.

    Science.gov (United States)

    Jiang, Xiang; Liu, Cai-Ming; Kou, Hui-Zhong

    2016-06-20

    In this paper, three isostructural porous coordination polymers, namely, [Mn6(μ3-O)2(sao)6(DMF)4(L(1))2/3]·4DMF·2H2O·2CH3OH (1), [Mn6(μ3-O)2(sao)6(DMF)4(L(2))2/3]·4DMF·2H2O·2CH3OH (2), and [Mn6(μ3-O)2(sao)6(DMF)4(L(3))2/3]·4DMF·4H2O·2CH3OH (3) (DMF = dimethylformamide, H2sao = salicylaldoxime, H3L(1) = benzene-1,3,5-trisbenzoic acid, H3L(2) = 4,4',4″-s-triazine-2,4,6-triyltribenzoic acid, and H3L(3) = 2,4,6-tris(4-carboxyphenoxy)-1,3,5-s-triazine), based on the oximato-bridged {Mn6} single-molecule magnet (SMM) and tricarboxylic acid ligands, were designed and synthesized. X-ray structural analysis shows that they possess a two-dimensional layered structure, where the {Mn6} moieties are linked by the corresponding (L(x))(3-) carboxylate ligands (x = 1, 2, 3) forming a huge honeycomb layer. These compounds not only show the SMM behavior as confirmed by alternative current susceptibility measurements but also show selectivity for CO2 over N2 at 273 K. On the basis of the magnetic fitting to the magnetic susceptibilities and the field dependence of magnetization for complexes 1-3, the spin ground states are S = 4. Compared with isolated {Mn6} SMMs with S = 4, the out-of-phase susceptibilities of 1-3 show obvious peaks only under the external direct-current field of 2 kOe. However, no peaks in χm″ are observed in the partially desolvated sample of compound 1. PMID:27258680

  18. Seismic Evaluation of Highway Bridges - Phase 1

    OpenAIRE

    Ramirez, J.A.; Pan, Austin D.; Mwakasisi, Frank Thompson

    1996-01-01

    The primary objective of the study was to establish the guidelines for screening, assessing, and ranking Indiana bridges for seismic upgrade. The outcome of the study is a complete strategy for the detailed structural assessment of Indiana highway bridges subjected to seismic forces. The structural evaluation is conducted using a nonlinear time-history analysis of the bridge for simulated or actual records. The specific soil conditions at the site are accounted in terms of the ground motio...

  19. REPORT: BioMedBridges standards workshop

    OpenAIRE

    Conte, Nathalie; Hancocks, Tom; Suhr, Stephanie

    2014-01-01

    This workshop, co-organized by BioMedBridges WP3 and 12, was held on 24-25 June and hosted by BioMedBridges partners at VUMC in Amsterdam. Attendees included BioMedBridges personnel, members from the ESFRI BMS research infrastructures and invited external experts from existing standards organisations. The following aspects of data standardisation were explored: Defining entity identifiers and identifiers best practice Development of a Meta models and Mappings Registry for bio...

  20. Analysis of liquid bridge between spherical particles

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    A pair of central moving spherical particles connected by a pendular liquid bridge with interstitial Newtonian fluid is often encountered in pariculate coalescence process. In this paper, by assuming perfect-wet condition, the effects of liquid volume and separation distance on static liquid bridge are analyzed, and the relation between rupture energy and liquid bridge volume is also studied. These points would be of significance in industrial processes related to adhesive particles.

  1. Bridge engineering handbook construction and maintenance

    CERN Document Server

    Chen, Wai-Fah

    2014-01-01

    Over 140 experts, 14 countries, and 89 chapters are represented in the second edition of the Bridge Engineering Handbook. This extensive collection highlights bridge engineering specimens from around the world, contains detailed information on bridge engineering, and thoroughly explains the concepts and practical applications surrounding the subject.Published in five books: Fundamentals, Superstructure Design, Substructure Design, Seismic Design, and Construction and Maintenance, this new edition provides numerous worked-out examples that give readers step-by-step design procedures, includes c

  2. Markovian Bridges: Weak continuity and pathwise constructions

    OpenAIRE

    Chaumont, Loïc; Uribe Bravo, Gerónimo

    2009-01-01

    A Markovian bridge is a probability measure taken from a disintegration of the law of an initial part of the path of a Markov process given its terminal value. As such, Markovian bridges admit a natural parameterization in terms of the state space of the process. In the context of Feller processes with continuous transition densities, we construct by weak convergence considerations the only versions of Markovian bridges which are weakly continuous with respect to their parameter. We use this ...

  3. Life Cycle Assessment of a Norwegian Bridge

    OpenAIRE

    Dequidt, Thomas Charles Edouard

    2012-01-01

    Life cycle assessment (LCA) methodology aims at evaluating the environmental impacts of a product or system from a holistic approach. In this methodology, all life cycle phases of the product are identified and assessed, from the raw material acquisition to the end-of-life phase. This master thesis is dealing with the LCA of a Norwegian bridge. First, a literature review is realized by going through 14 bridge LCA references. Then, a detailed description of bridge LCA methodology ...

  4. Bridge Engineering-Oriented Parametric Model

    Institute of Scientific and Technical Information of China (English)

    周凌远; 李乔

    2004-01-01

    A new model is proposed to improve the efficiency of structural modeling. In this model, the bridge structural components are expressed with component description, parametric description and geometric description in a software system. This model provides both convenience and flexibility for users in structural modeling process. The object-oriented method is applied in the model implementation. A bridge analysis preprocessor is developed on the basis of this model. It provides an effective way for bridge modeling.

  5. Dynamics and Statics of Nonaxisymmetric Liquid Bridges

    Science.gov (United States)

    Alexander, J. Iwan D.; Resnick, Andrew H.; Slobozhanin, L. A.

    1996-01-01

    Theoretical and experimental investigation of the stability of nonaxisymmetric and nonaxisymmetric bridges contained between equal and unequal radii disks as a function of Bond and Weber number with emphasis on the transition from unstable axisymmetric to stable nonaxisymmetric shapes, are conducted. Numerical analysis of the stability of nonaxisymmetric bridges between unequal disks for various orientations of the gravity vector is performed. Experimental and theoretical investigation of large (nonaxisymmetric) oscillations and breaking of liquid bridges are also conducted.

  6. Maximal liquid bridges between horizontal cylinders

    OpenAIRE

    Cooray, Himantha; Huppert, Herbert E.; Neufeld, Jerome A

    2016-01-01

    We investigate two-dimensional liquid bridges trapped between pairs of identical horizontal cylinders. The cylinders support forces due to surface tension and hydrostatic pressure which balance the weight of the liquid. The shape of the liquid bridge is determined by analytically solving the nonlinear Laplace-Young equation. Parameters that maximize the trapping capacity (defined as the cross-sectional area of the liquid bridge) are then determined. The results show that these parameters can ...

  7. Axisymmetric long liquid bridges stability and resonances

    OpenAIRE

    Meseguer Ruiz, José; Sanz Andres, Angel Pedro; Perales Perales, José Manuel

    1990-01-01

    In this paper mathematical expressions for minimum-volume stability limits and resonance frequencies of axisymmetric long liquid bridges are presented. These expressions are valid for a wide range of liquid bridge configurations, accounting for ef-fects like unequal disks and axial microgravity in the case of minimum-volume stability limits,and unequal disks, axial microgravity,non-zero viscosity and liquid bridge volume different from the cylindrical one in the case of resonance frequenc...

  8. Electronic structural flexibility of heterobimetallic Mn/Fe cofactors: R2lox and R2c proteins.

    Science.gov (United States)

    Shafaat, Hannah S; Griese, Julia J; Pantazis, Dimitrios A; Roos, Katarina; Andersson, Charlotta S; Popović-Bijelić, Ana; Gräslund, Astrid; Siegbahn, Per E M; Neese, Frank; Lubitz, Wolfgang; Högbom, Martin; Cox, Nicholas

    2014-09-24

    The electronic structure of the Mn/Fe cofactor identified in a new class of oxidases (R2lox) described by Andersson and Högbom [Proc. Natl. Acad. Sci. U.S.A. 2009, 106, 5633] is reported. The R2lox protein is homologous to the small subunit of class Ic ribonucleotide reductase (R2c) but has a completely different in vivo function. Using multifrequency EPR and related pulse techniques, it is shown that the cofactor of R2lox represents an antiferromagnetically coupled Mn(III)/Fe(III) dimer linked by a μ-hydroxo/bis-μ-carboxylato bridging network. The Mn(III) ion is coordinated by a single water ligand. The R2lox cofactor is photoactive, converting into a second form (R2loxPhoto) upon visible illumination at cryogenic temperatures (77 K) that completely decays upon warming. This second, unstable form of the cofactor more closely resembles the Mn(III)/Fe(III) cofactor seen in R2c. It is shown that the two forms of the R2lox cofactor differ primarily in terms of the local site geometry and electronic state of the Mn(III) ion, as best evidenced by a reorientation of its unique (55)Mn hyperfine axis. Analysis of the metal hyperfine tensors in combination with density functional theory (DFT) calculations suggests that this change is triggered by deprotonation of the μ-hydroxo bridge. These results have important consequences for the mixed-metal R2c cofactor and the divergent chemistry R2lox and R2c perform. PMID:25153930

  9. Further study on highly sensitive AMS measurement of 53Mn

    Science.gov (United States)

    Kejun, Dong; Hao, Hu; Xianggao, Wang; Chaoli, Li; Ming, He; Zhenyu, Li; Shaoyong, Wu; Jiancheng, Liu; Guowen, Zheng; Heng, Li; Zhigang, Chen; Guangshan, Liu; Jian, Yuan; Shan, Jiang

    2012-08-01

    The AMS facility at China Institute of Atomic Energy has been equipped with a ΔE-Q3D detection system for the measurements of 53Mn. While the sample material of MnO2 and the extraction ions of MnO- were used previously in AMS measurement of 53Mn with fairly good results, a method has recently been developed with the extraction of MnF- from ion source using MnF2 and MnO2 + PbF2 as sample materials. As a result, a sensitivity of 10-14 (53Mn/Mn) has been achieved. Compared with the original MnO-/MnO2 approach, the method of MnF- extraction, combined with ΔE-Q3D detection technique, demonstrated an improved sensitivity for AMS measurement of 53Mn.

  10. Crystal growth under bridge foundation

    OpenAIRE

    Ramon Tarragona, Anna; Alonso Pérez de Agreda, Eduardo

    2012-01-01

    W(H)YDOC PhD Prize 2012, durant el 4th International Workshop of Young Doctors in Geomechanics W(H)YDOC 2012. A high-speed railway viaduct experienced a sustained heave at high rates after its construction. The pillars of the bridge are founded on an Eocene hard anhydritic-gypsiferous claystone by means of massive foundations. Field investigations identified an active layer below the piles’ tips where expansions occur as a result of gypsum crystal growth in discontinuities from supersatura...

  11. Nanoclusters a bridge across disciplines

    CERN Document Server

    Jena, Purusottam

    2010-01-01

    This comprehensive book on Nanoclusters comprises sixteen authoritative chapters written by leading researchers in the field. It provides insight into topics that are currently at the cutting edge of cluster science, with the main focus on metal and metal compound systems that are of particular interest in materials science, and also on aspects related to biology and medicine. While there are numerous books on clusters, the focus on clusters as a bridge across disciplines sets this book apart from others. Delivers cutting edge coverage of cluster science Covers a broad range of topics in

  12. Family Medicine: Bridge to Life.

    Science.gov (United States)

    Luz, Clare

    2016-01-01

    Reflecting on the suicide of a close friend, this essay explores what comprises, and inspires a will to live, and how those in Family Medicine can address suicide risk even in the face of debilitating or terminal illness. Research indicates that the will to live is a measurable indicator of general well-being, distinct from depression, and an important predictor of a person's motivation to "hold on to life". As such, understanding what is at the heart of a desire to live should alter clinical practice. This essay offers ideas for ways in which to create bridges for patients that could help sustain life.

  13. A bridge to advanced mathematics

    CERN Document Server

    Sentilles, Dennis

    2011-01-01

    This helpful workbook-style ""bridge"" book introduces students to the foundations of advanced mathematics, spanning the gap between a practically oriented calculus sequence and subsequent courses in algebra and analysis with a more theoretical slant. Part 1 focuses on logic and number systems, providing the most basic tools, examples, and motivation for the manner, method, and concerns of higher mathematics. Part 2 covers sets, relations, functions, infinite sets, and mathematical proofs and reasoning. Author Dennis Sentilles also discusses the history and development of mathematics as well a

  14. 55Mn NMR study in Mn1-xTixAs

    Science.gov (United States)

    Amako, Yasushi; Nagai, Hiroyuki; Ido, Hideaki

    2004-05-01

    The nuclear magnetic resonance of 55Mn nuclei in Mn1-xTixAs has been measured at 4K. 55Mn resonance frequency in zero external field is 237MHz for MnAs of which the spontaneous magnetization at 4.2K is 3.4μB/f.u. Zero field 55Mn NMR spectra shift at the high-frequency side and they split in three signals by substituting Mn for Ti though the magnetic moment per Mn atom is constant for x less than 0.55. The transferred hyperfine field due to the nearest neighbor Mn moment is estimated to be +21kOe.

  15. Electron channelling enhanced microanalysis on Ni-Al-Mn and Al-Mn-Si

    International Nuclear Information System (INIS)

    Atom location by channelling enhanced microanalysis (ALCHEMI) was performed for Ni-Al-Mn compounds and Al-Mn-Si quasicrystals. For Ni75Al25-xMnx (x=5,9) with the L12-type structure, an occupation fraction of Mn atoms at the Ni site was quantitatively determined using planar channelling conditions. The occupation fraction increases with the Mn concentration or by quenching the compound from high temperature. In quasicrystals of Al74Mn20Si6 and Al68Mn20Ru8Si4, axial channelling conditions were used to locate Si and Ru, respectively. It was shown that Si atoms occupy the Al site in Al74Mn20Si6 whereas Ru atoms occupy the site different from that of Al in Al68Mn20Ru8Si4. (author)

  16. Two bimetallic W(Ⅳ)-Mn(Ⅱ) complexes based on octacyanometallates:structures and magnetic properties

    Institute of Scientific and Technical Information of China (English)

    LIU BaoLin; XIAO HongPing; SONG You; YOU XiaoZeng

    2009-01-01

    Two cyano-bridged heterobimetallic coordination polymers,[{Mn(dpa)_2}_2W(CN)_8·CH_3GN·4H_2O]_n(1) (dpa =2,2'-dipyridylamine) and[Mn_2(H_2O)_4{W(CN)_8}·3H_2O]_n (2),have been synthesized and characterized structurally and magnetically.X-ray analysis shows that complex 1 is a one-dimensional (1-D) polymer of W_2(CN)_4Mn_2 square units in which adjacent square fragments are interlinked by sharing[W(CN)_8]~(4-)moieties to form an infinite chain.Complex 2 is a three-dimensional (3-D) polymer,which shows an unforeseen structure,exhibiting a 3-D open network with a 1-D channel (ca.13.21 (A) ×11.82 (A)).Fitting of the magnetic properties indicates that both polymers exhibit weakly antiferromagnetic interactions between the adjacent Mn ions.

  17. Myocardial bridges: morphological and functional aspects.

    OpenAIRE

    A.G. Ferreira; Trotter, S E; König, B; Décourt, L V; Fox, K; Olsen, E G

    1991-01-01

    OBJECTIVE--To assess the arrangement of myocardial bridges. DESIGN--A necropsy study of 90 consecutive hearts (56 male, 34 female). RESULTS--Myocardial bridges, either single or multiple, were seen in 50 (55.6%) of the 90 hearts. The left anterior descending artery was the most commonly affected artery. Thirty five of the 50 hearts which contained in total 41 muscle bridges were dissected further with a magnifying glass. Two different types of muscle bridges could be identified. Thirty one of...

  18. A data management infrastructure for bridge monitoring

    Science.gov (United States)

    Jeong, Seongwoon; Byun, Jaewook; Kim, Daeyoung; Sohn, Hoon; Bae, In Hwan; Law, Kincho H.

    2015-04-01

    This paper discusses a data management infrastructure framework for bridge monitoring applications. As sensor technologies mature and become economically affordable, their deployment for bridge monitoring will continue to grow. Data management becomes a critical issue not only for storing the sensor data but also for integrating with the bridge model to support other functions, such as management, maintenance and inspection. The focus of this study is on the effective data management of bridge information and sensor data, which is crucial to structural health monitoring and life cycle management of bridge structures. We review the state-of-the-art of bridge information modeling and sensor data management, and propose a data management framework for bridge monitoring based on NoSQL database technologies that have been shown useful in handling high volume, time-series data and to flexibly deal with unstructured data schema. Specifically, Apache Cassandra and Mongo DB are deployed for the prototype implementation of the framework. This paper describes the database design for an XML-based Bridge Information Modeling (BrIM) schema, and the representation of sensor data using Sensor Model Language (SensorML). The proposed prototype data management framework is validated using data collected from the Yeongjong Bridge in Incheon, Korea.

  19. Review of Energy Harvesters Utilizing Bridge Vibrations

    Directory of Open Access Journals (Sweden)

    Farid Ullah Khan

    2016-01-01

    Full Text Available For health monitoring of bridges, wireless acceleration sensor nodes (WASNs are normally used. In bridge environment, several forms of energy are available for operating WASNs that include wind, solar, acoustic, and vibration energy. However, only bridge vibration has the tendency to be utilized for embedded WASNs application in bridge structures. This paper reports on the recent advancements in the area of vibration energy harvesters (VEHs utilizing bridge oscillations. The bridge vibration is narrowband (1 to 40 Hz with low acceleration levels (0.01 to 3.8 g. For utilization of bridge vibration, electromagnetic based vibration energy harvesters (EM-VEHs and piezoelectric based vibration energy harvesters (PE-VEHs have been developed. The power generation of the reported EM-VEHs is in the range from 0.7 to 1450000 μW. However, the power production by the developed PE-VEHs ranges from 0.6 to 7700 μW. The overall size of most of the bridge VEHs is quite comparable and is in mesoscale. The resonant frequencies of EM-VEHs are on the lower side (0.13 to 27 Hz in comparison to PE-VEHs (1 to 120 Hz. The power densities reported for these bridge VEHs range from 0.01 to 9539.5 μW/cm3 and are quite enough to operate most of the commercial WASNs.

  20. Gust loading on streamlined bridge decks

    DEFF Research Database (Denmark)

    Larose, Guy; Mann, Jakob

    1998-01-01

    The current analytical description of the buffeting action of wind on long-span bridges is based on the strip assumption. However, recent experiments on closed-box girder bridge decks have shown that this assumption is not valid and is the source of an important part of the error margin of the an......The current analytical description of the buffeting action of wind on long-span bridges is based on the strip assumption. However, recent experiments on closed-box girder bridge decks have shown that this assumption is not valid and is the source of an important part of the error margin...

  1. Thermodynamic Properties of Mn-C Melts

    Institute of Scientific and Technical Information of China (English)

    CHEN Er-bao; WANG Shi-jun

    2008-01-01

    Carbon solubility in Mn-Fe melts (xMn=0.161-0.706, xFe=0.034-0.633) was measured experimentally at various temperatures. By thermodynamic derivation and calculation, the relationship between activity coefficient of carbon in infinite dilute solution of manganese in Mn-C system and temperature was obtained. Using Gibbs-Duhem relationship, the experimental results of this study, and experimental data reported in references, the relationship between other thermodynamic properties in Mn-C system and temperature were obtained by thermodynamic derivation and calculation.

  2. Magnetic properties of MnPt

    Energy Technology Data Exchange (ETDEWEB)

    Severin, C. S.

    1977-06-01

    The magnetic properties of quenched and annealed powder specimens of MnPt were investigated using x-ray diffraction, magnetization measurements and neutron diffraction techniques. Thin films of MnPt were prepared by rf sputtering techniques and the films were investigated by x-ray diffraction and magnetization measurements. The powder specimens of MnPt were found to be typically antiferromagnetic in an L1/sub 0/ structure with Mn atoms occupying the (001) planes. The Mn moments were antiparallel to their nearest neighbors in the (001) planes. The atomic moment of Mn is (4.1 +- .2) ..mu../sub B/ for the annealed specimens and (3.9 +- .2) ..mu../sub B/ for the quenched specimens. Neutron data failed to determine whether or not Pt carries a moment. Assuming a moment associated with the Pt atoms, the maximum value is 0.2 ..mu../sub B/ per atom. The quenched specimens contained small ferromagnetic regions probably with a composition of 18-32 at. percent Mn. The sputtered films of MnPt were highly disordered in all but one specimen, which was amorphous. The films were ferromagnetic with the deduced Mn moment of (3.0 +- .3) ..mu../sub B/ per atom, which may not represent the true value because the films were not entirely ferromagnetic.

  3. Element spots in HgMn stars

    OpenAIRE

    Korhonen, Heidi

    2013-01-01

    A fraction of late B-type stars, the so-called HgMn stars, exhibit enhanced absorption lines of certain chemical elements, notably Hg and Mn, combined with an underabundance of He. For about a decade now the elements with anomalously high abundances in HgMn stars are known to be distributed inhomogeneously over the stellar surface. Temporal evolution of these elemental spots have been reported in a few HgMn stars, first secular evolution of the mercury spots in alpha And, and recently also a ...

  4. A method for making Mn02 electrodes

    Energy Technology Data Exchange (ETDEWEB)

    Ikeda, M.; Nisino, A.

    1983-03-30

    A layer of Mn02, produced during thermal breakdown of manganese salts, is applied to a metallic current outlead. Then a mixture of granulated Mn02 and an electricity conducting additive and a binder is applied to this layer. The electrode contains 1 to 5 percent by mass epoxide resin, 5 to 15 percent by mass carbon powder, 0.1 to 10 percent by mass beta-Mn02 and 70 to 90 percent by mass gamma-Mn02. The electrode has high mechanical strength and good discharge characteristics.

  5. 49 CFR 237.101 - Scheduling of bridge inspections.

    Science.gov (United States)

    2010-10-01

    ... 49 Transportation 4 2010-10-01 2010-10-01 false Scheduling of bridge inspections. 237.101 Section... ADMINISTRATION, DEPARTMENT OF TRANSPORTATION BRIDGE SAFETY STANDARDS Bridge Inspection § 237.101 Scheduling of bridge inspections. (a) Each bridge management program shall include a provision for scheduling...

  6. Finite element of multilayer surfacing systems on orthotropic steel bridges

    NARCIS (Netherlands)

    Li, J.; Liu, X.; Scarpas, A.; Tzimiris, G.

    2013-01-01

    Light weight orthotropic steel bridge decks have been widely utilized for bridges in seismic zones, movable bridges and long span bridges. In the last three decades, severe problems were reported in relation to asphaltic surfacing materials on orthotropic steel deck bridges. Earlier investigations h

  7. The Bridge of Mandolin County

    Science.gov (United States)

    Lantz, Juliette M.; Feindt, Jenny E.; Lewellyn, Eric P. B.; Walczak, Mary M.

    1999-12-01

    The Bridge of Mandolin County is a case designed to teach the general chemistry principles of molar mass, ions and aqueous reactions, solubility rules, and inorganic nomenclature. Through the instructor-facilitated class discussion, students consider the options before the Mandolin Town Council regarding deicing the newly constructed bridge connecting Mandolin with a large nearby city. The students must decipher contradictory claims made on behalf of sodium chloride, the traditional deicer, and calcium magnesium acetate, a new environmentally friendly deicer, to arrive at the most cost-effective and environmentally appropriate deicing product. As they work through the analysis they raise questions that can be addressed in a laboratory setting. Four optional role-playing experiments are included, which can be used by the students to gather information helpful to resolution of the case. The case is intended to be used over two class periods, with a laboratory period in between, though suggestions for other models are provided. Laboratory procedures include an EDTA titration for Ca2+ and Mg2+, a gravimetric analysis, a qualitative examination of ions and solubility, an introduction to freezing point depression and measurement, and an experimental design activity. This case can also successfully be used without alteration in non-majors chemistry or environmental chemistry courses, or upper-level analytical or environmental chemistry courses.

  8. Structural, electronic and magnetic properties of Co{sub 2}MnSi/Ag(1 0 0) interface

    Energy Technology Data Exchange (ETDEWEB)

    Feng, Yu [School of Physical Science and Technology, Southwest University, Chongqing 400715 (China); Wu, Bo [Department of Physics, Zunyi Normal College, Zunyi 563002 (China); Yuan, Hongkuan [School of Physical Science and Technology, Southwest University, Chongqing 400715 (China); Chen, Hong, E-mail: chenh@swu.edu.cn [School of Physical Science and Technology, Southwest University, Chongqing 400715 (China)

    2015-02-25

    Highlights: • Interfacial MnSi atoms prefer to locate in the bridge sites between two Ag atoms. • A2 disorder of Co{sub 2}MnSi layers near the interface is most likely to occur. • Spin polarization is reduced by interface itself and interfacial disorder. - Abstract: The performance of advanced current-perpendicular-to-plane giant magnetoresistance (MR) built of ferromagnetic (FM) electrodes and nonmagnetic metals as a spacer depends decisively on the properties of the FM/metal interface. Here we investigate the interface character between Co{sub 2}MnSi and Ag by using the first-principles density functional simulations. To simulate the actual cases, we build two types of interfaces, namely {sub t}O and {sub b}O interfaces by connecting the most favorable MnSi-termination of nine ordered Co{sub 2}MnSi layers to the top of Ag and the bridge site between two Ag atoms of seven atomic layers, respectively. Our calculations indicate that the {sub b}O interface is more probable to form in the growth than the {sub t}O interface due to the lower formation energy and interface free energy, and the interface states occur in the minority-spin gap, leading to the destruction of half-metallicity of the ordered Co{sub 2}MnSi. Further, taking into account the atomic disorder of the Co{sub 2}MnSi layers near the interface, we show that the A2 disorder is most likely to occur in the layers close to the interface due to the lower formation energy and interface free energy, and the interface states occurring in the spin-minority gap are strengthened and the spin polarization is further degraded by the A2 disorder of Co{sub 2}MnSi layers. Therefore, the spin-polarization reduction induced by interface itself and the disorder of Co{sub 2}MnSi layers close to the interface, together with the interface roughness indicated by the calculations, may be main causes of very low MR ratio.

  9. The rhetoric of communicating knowledge through the project website

    DEFF Research Database (Denmark)

    Kampf, Constance

    of rhetoric.  This paper looks at the I35 W bridge reconstruction project in Minneapolis through web-based communication by the Minnesota Department of Transportation (MnDOT) about the project. The MnDOT bridge reconstruction website will be examined using a combination of 1). Weick's notion of sensemaking...... and 2). Kress and VanLeeuwan's notions of multimodal discourse.  These concepts are combined to examine the project website as a site for knowledge communication processes between MnDOT and the Twin Cities community about the bridge reconstruction project. Results lead to an understanding...... of the rhetorical processes operating via the project website as an element in the socio-technical design of the bridge....

  10. Bridge Lock-up Device System

    OpenAIRE

    ECT Team, Purdue

    2007-01-01

    The Colebrand Lock-up Device (LUD) provides additional substructure strength to resist seismic forces as a structural shock transmission unit for highway bridges. This system can provide a temporary rigid link between bridge structural members under seismic, braking, or other fast-acting type loads, while permitting slow thermal movements.

  11. Paul Dirac:. Building Bridges of the Mind

    Science.gov (United States)

    Brown, Laurie M.

    2003-12-01

    Paul Dirac was a brilliant and original thinker. He used his physical intuition and his ideal of mathematical beauty to construct bridges between major areas of physics. This article discusses several such important works, including the bridge between quantum mechanics and relativity that led to his prediction of the existence of antimatter.

  12. History of cable-stayed bridges

    DEFF Research Database (Denmark)

    Gimsing, Niels Jørgen

    1999-01-01

    The principle of supporting a bridge deck by inclined tension members leading to towers on either side of the span has been known for centuries. However, the real development of cable-stayed bridges did not begin before the 1950s. Since then the free span has been increased from 183 m in the Strö...

  13. COUPLING VIBRATION OF VEHICLE-BRIDGE SYSTEM

    Institute of Scientific and Technical Information of China (English)

    陈炎; 黄小清; 马友发

    2004-01-01

    By applying the sinusoidal wave mode to simulate the rugged surface of bridge deck,accounting for vehicle-bridge interaction and using Euler-Bernoulli beam theory, a coupling vibration model of vehicle-bridge system was developed. The model was solved by mode analyzing method and Runge-Kutta method, and the dynamic response and the resonance curve of the bridge were obtained. It is found that there are two resonance regions, one represents the main resonance while the other the minor resonance, in the resonance curve. The influence due to the rugged surface, the vibration mode of bridge, and the interaction between vehicle and bridge on vibration of the system were discussed. Numerical results show that the influence due to these parameters is so significant that the effect of roughness of the bridge deck and the mode shape of the bridge can't be ignored and the vehicle velocity should be kept away from the critical speed of the vehicle.

  14. A STUDY OF BARRIERS IN BRIDGING COMMUNICATION

    OpenAIRE

    Niteen V. Dandekar

    2014-01-01

    The main objective of this paper is to make a thought provoking discussion on the role barriers in bridging communication. It focuses on the concept of communication, process and the role of language related barriers in bridging communication. It studies the significance of communication in modern human life.

  15. General framework for bridge life cycle design

    Institute of Scientific and Technical Information of China (English)

    Junhai MA; Airong CHEN; Jun HE

    2009-01-01

    Based on a detailed illustration for bridge life cycle design which comprises the processes of service life design, aesthetics design, performance design, environ-mental and ecological design, inspection, maintenance and repair design as well as cost analysis, this paper presented a general framework for bridge life cycle design comprising three design phases and six design processes.

  16. Active aerodynamic stabilisation of long suspension bridges

    DEFF Research Database (Denmark)

    Nissen, Henrik Ditlev; Sørensen, Paul Haase; Jannerup, Ole Erik

    2004-01-01

    The paper describes the addition of actively controlled appendages (flaps) attached along the length of the bridge deck to dampen wind-induced oscillations in long suppension bridges. A novel approach using control systems methods for the analysis of dynamic stability is presented. In order to ma...

  17. Lifetime Reliability Assessment of Concrete Slab Bridges

    DEFF Research Database (Denmark)

    Thoft-Christensen, Palle

    A procedure for lifetime assesment of the reliability of short concrete slab bridges is presented in the paper. Corrosion of the reinforcement is the deterioration mechanism used for estimating the reliability profiles for such bridges. The importance of using sensitivity measures is stressed...

  18. Re-Assessment of Concrete Bridges

    DEFF Research Database (Denmark)

    Thoft-Christensen, Palle

    In this paper two aspects of re-assessment of the reliability of concrete bridges are discussed namely modelling of the corrosion of reinforcement and updating of uncertain variables. The main reason for deterioration of concrete bridges is corrosion of the reinforcement. Therefore, modelling...

  19. Thermal diffusion of Mn through GaAs overlayers on (Ga, Mn)As.

    Science.gov (United States)

    Adell, J; Ulfat, I; Ilver, L; Sadowski, J; Karlsson, K; Kanski, J

    2011-03-01

    Thermally stimulated diffusion of Mn through thin layers of GaAs has been studied by x-ray photoemission. (Ga, Mn)As samples with 5 at% Mn were capped with 4, 6 and 8 monolayer (ML) GaAs, and Mn diffusing through the GaAs was trapped on the surface by means of amorphous As. It was found that the out-diffusion is completely suppressed for an 8 ML thick GaAs film. The short diffusion length is attributed to an electrostatic barrier formed at the (Ga, Mn)As/GaAs interface.

  20. Thermal diffusion of Mn through GaAs overlayers on (Ga, Mn)As

    Energy Technology Data Exchange (ETDEWEB)

    Adell, J; Ulfat, I; Ilver, L; Kanski, J [Department of Applied Physics, Chalmers University of Technology, SE-412 96 Gothenburg (Sweden); Sadowski, J [Institute of Physics, Polish Academy of Sciences, PL-02-668 Warsaw (Poland); Karlsson, K [Department of Life Sciences, University of Skoevde, SE-541 28 Skoevde (Sweden)

    2011-03-02

    Thermally stimulated diffusion of Mn through thin layers of GaAs has been studied by x-ray photoemission. (Ga, Mn)As samples with 5 at% Mn were capped with 4, 6 and 8 monolayer (ML) GaAs, and Mn diffusing through the GaAs was trapped on the surface by means of amorphous As. It was found that the out-diffusion is completely suppressed for an 8 ML thick GaAs film. The short diffusion length is attributed to an electrostatic barrier formed at the (Ga, Mn)As/GaAs interface.

  1. Valence state of Mn in Ca-doped LaMnO3 studied by high-resolution Mn K ß emission spectroscopy

    NARCIS (Netherlands)

    Tyson, T.A.; Qian, Q.; Kao, C.-C.; Rueff, J.-P.; Groot, F.M.F. de; Croft, M.; Cheong, S.-W.; Greenblatt, M.; Subramanian, M.A.

    2001-01-01

    Mn K ß x-ray emission spectra provide a direct method to probe the effective spin state and charge density on the Mn atom and is used in an experimental study of a class of Mn oxides. Specifically, the Mn K ß line positions and detailed spectral shapes depend on the oxidation and the spin state of t

  2. Optimum Maintenance Strategies for Highway Bridges

    DEFF Research Database (Denmark)

    Frangopol, Dan M.; Thoft-Christensen, Palle; Das, Parag C.;

    As bridges become older and maintenance costs become higher, transportation agencies are facing challenges related to implementation of optimal bridge management programs based on life cycle cost considerations. A reliability-based approach is necessary to find optimal solutions based on minimum ...... is described. The end result of this investigation will be a general reliability-based framework to be used by the UK Highways Agency in order to plan optimal strategies for the maintenance of its bridge network so as to optimize whole-life costs....... expected life-cycle costs or maximum life-cycle benefits. This is because many maintenance activities can be associated with significant costs, but their effects on bridge safety can be minor. In this paper, the program of an investigation on optimum maintenance strategies for different bridge types...

  3. The preferred orientation of Mn3 spins in magnetic multiferroic CaMn7O12

    International Nuclear Information System (INIS)

    The remarkable ferroelectricity in CaMn7O12 originates from the helicoidal spin spiral, in which the Mn3 (3b Wyckoff position) spin direction remains controversial. In this paper, the total energy, phase transition path, and spontaneous polarization of CaMn7O12 are investigated by using first-principle methods. We show that, in order to account for the giant electric polarization and the correct phase transition sequence, the relative orientation between the spins of Mn3 and Mn2 (9d Wyckoff position) sites with the same coordinate along the hexagonal c-axis can not be antiparallel, i.e. their relative orientation angle should be ϕ≈0.84π instead of ϕ=π. The most likely reason for the observation of ϕ=π can be attributed to the withdrawal of spin–orbital coupling between the Mn2 and Mn3 spins, which is caused by doping Cu2+ in the samples for neutron powder diffraction measurements. - Highlights: • In CaMn7O12, the preferred orientation angle of the Mn3 spins remains controversial. • The relative orientation angle between Mn3 and Mn2 spins should be 0.84π instead of π. • For ϕ=π, phase transition path and polarization are inconsistent with experiments. • The reason for observation of ϕ=π is due to Cu2+-doping in the experimental samples

  4. Effect of Mn and MnS on corrosion properties of domestic pipeline steels and welds

    Institute of Scientific and Technical Information of China (English)

    李云涛; 杜则裕; 陶勇寅; 李建军

    2004-01-01

    Base metals of domestic pipeline steels were used to study the effect of Mn on corrosion properties of SSCC(Sulfide Stress Corrosion Cracking), and welds were carried out to study the effect of MnS on corrosion properties of HIC (Hydrogen Induced Cracking) both in solutions with wet hydrogen sulfide(H2S). They were respectively conducted by referring to the standards of SSCC and HIC. Testing results revealed that with the increase of content Mn, the resistance of SSCC will be decreased, from the point of metallurgic view, and it is Mn element not C element to lead to the testing results of SSCC. Meanwhile, even under the condition without inclusions MnS, HIC in welds still occurred. That is to say, MnS is not necessary for HIC, the presence of local banded structures in which Mn and P are inclined to aggregate cause to the phenomena of HIC.

  5. Growth and properties of (Ga,Mn)As films with high Mn concentration

    Energy Technology Data Exchange (ETDEWEB)

    Takamura, K.; Matsukura, F.; Ohno, Y.; Ohno, H.

    2001-06-01

    (Ga, Mn)As films with high nominal Mn concentration (0{lt}x{lt}0.55) are grown by low temperature molecular beam epitaxy (LT-MBE), growth temperature T{sub s}=180{degree}C. Reflection high energy electron diffraction patterns indicate epitaxial growth of (Ga, Mn)As for x{lt}0.1, whereas they show spotty patterns for x{gt}0.1, which turn to polycrystalline features when x{gt}0.3. X-ray diffraction shows the formation of MnAs together with the growth of (Ga, Mn)As. The lattice constant of the layers suggests that (Ga, Mn)As with high Mn composition as high as 17% can be grown by LT-MBE. {copyright} 2001 American Institute of Physics.

  6. Modified Geometry of Transition Slabs for Integral Bridges

    OpenAIRE

    Dreier, Damien

    2010-01-01

    Over the past decades, an increasing number of integral bridges have been built. This type of bridge offers various advantages in comparison with standard bridges equipped with expansion joints and bearings. In particular, integral bridges require less maintenance since they require less mechanical elements. Transition slabs, which are used in integral bridges, are directly connected to the bridge deck and therefore they are subjected to large displacements caused by creep, shrinkage and temp...

  7. Building bridges … and accelerators

    CERN Multimedia

    2009-01-01

    Lyn Evans, the LHC project leader, was awarded an honorary doctorate from the University of Geneva (UNIGE) to celebrate his role not just in building accelerators, but also in building bridges between nations. He was one of four notables honoured at the event on Friday 5 June, coinciding with the University’s 450th Anniversary. Lyn Evans arriving at the ceremony with Archbishop Desmond Tutu. "It was a big surprise when I found out I’d been nominated," recounts Evans, "but it was an even bigger surprise to find out with whom I’d been nominated". At the ceremony Evans was awarded the honorary doctorate along with three others: Archbishop Desmond Tutu, who was acclaimed for his fight against apartheid in South Africa, Mary Robinson, first woman president of Ireland and former United Nations’ high commissioner of human rights, and Pascal Lamy, Director-General of the World Trade Organization. The award ceremony, known as the �...

  8. Root coverage with bridge flap

    Directory of Open Access Journals (Sweden)

    Pushpendra Kumar Verma

    2013-01-01

    Full Text Available Gingival recession in anterior teeth is a common concern due to esthetic reasons or root sensitivity. Gingival recession, especially in multiple anterior teeth, is of huge concern due to esthetic reasons. Various mucogingival surgeries are available for root coverage. This case report presents a new bridge flap technique, which allows the dentist not only to cover the previously denuded root surfaces but also to increase the zone of attached gingiva at a single step. In this case, a coronally advanced flap along with vestibular deepening technique was used as root coverage procedure for the treatment of multiple recession-type defect. Here, vestibular deepening technique is used to increase the width of the attached gingiva. The predictability of this procedure results in an esthetically healthy periodontium, along with gain in keratinized tissue and good patient′s acceptance.

  9. Element spots in HgMn stars

    Science.gov (United States)

    Korhonen, H.

    2014-11-01

    A fraction of late B-type stars, the so-called HgMn stars, exhibit enhanced absorption lines of certain chemical elements, notably Hg and Mn, combined with an underabundance of He. For about a decade it has been known that the elements with anomalously high abundances in HgMn stars are distributed inhomogeneously over the stellar surface. Observation of the temporal evolution of those spots has been reported in a few HgMn stars, first of a secular evolution of the mercury spots in α And, and more recently of a fast evolution of yttrium and strontium spots in HD 11753. The fast evolution of spots in HD 11753 is combined with a slower change in the overall abundance of the elements affected. In this paper I review what is known about these ``elemental spots'' in HgMn stars and their secular and fast temporal evolution.

  10. Element spots in HgMn stars

    CERN Document Server

    Korhonen, Heidi

    2013-01-01

    A fraction of late B-type stars, the so-called HgMn stars, exhibit enhanced absorption lines of certain chemical elements, notably Hg and Mn, combined with an underabundance of He. For about a decade now the elements with anomalously high abundances in HgMn stars are known to be distributed inhomogeneously over the stellar surface. Temporal evolution of these elemental spots have been reported in a few HgMn stars, first secular evolution of the mercury spots in alpha And, and recently also a fast evolution of yttrium and strontium spots in HD 11753. The fast evolution of spots in HD 11753 is combined with a slower change in the overall abundance of the affected elements. In this paper I review what is known of elemental spots in HgMn stars and their secular and fast temporal evolution.

  11. Redetermination of brackebuschite, Pb2Mn(3+)(VO4)2(OH).

    Science.gov (United States)

    Lafuente, Barbara; Downs, Robert T

    2016-03-01

    The crystal structure of brackebuschite, ideally Pb2Mn(3+)(VO4)2(OH) [dilead(II) manganese(III) vanadate(V) hydroxide], was redetermined based on single-crystal X-ray diffraction data of a natural sample from the type locality Sierra de Cordoba, Argentina. Improving on previous results, anisotropic displacement parameters for all non-H atoms were refined and the H atom located, obtaining a significant improvement of accuracy and an unambiguous hydrogen-bonding scheme. Brackebuschite belongs to the brackebuschite group of minerals with general formula A 2 M(T1O4)(T2O4)(OH, H2O), with A = Pb(2+), Ba, Ca, Sr; M = Cu(2+), Zn, Fe(2+), Fe(3+), Mn(3+), Al; T1 = As(5+), P, V(5+); and T2 = As(5+), P, V(5+), S(6+). The crystal structure of brackebuschite is based on a cubic closest-packed array of O and Pb atoms with infinite chains of edge-sharing [Mn(3+)O6] octa-hedra located about inversion centres and decorated by two unique VO4 tetra-hedra (each located on a special position 2e, site symmetry m). One type of VO4 tetra-hedra is linked with the (1) ∞[MnO4/2O2/1] chain by one common vertex, alternating with H atoms along the chain, while the other type of VO4 tetra-hedra link two adjacent octa-hedra by sharing two vertices with them and thereby participating in the formation of a three-membered Mn2V ring between the central atoms. The (1) ∞[Mn(3+)(VO4)2OH] chains run parallel to [010] and are held together by two types of irregular [PbO x ] polyhedra (x = 8, 11), both located on special position 2e (site symmetry m). The magnitude of the libration component of the O atoms of the (1) ∞[Mn(3+)(VO4)2OH] chain increases linearly with the distance from the centerline of the chain, indicating a significant twisting to and fro of the chain along [010]. The hy-droxy group bridges one Pb(2+) cation with two Mn(3+) cations and forms an almost linear hydrogen bond with a vanadate group of a neighbouring chain. The O⋯O distance of this inter-action determined from the

  12. ELECTRODEPOSITION BEHAVIOR OF Mn WITH Ni IN ACIDIC SULFATE SOLUTIONS

    OpenAIRE

    DAN JI; XIAWEN LE; QINGDONG ZHONG; QIONGYU ZHOU

    2014-01-01

    The influence of Mn2+/Ni2+ mole ratio in electrolytes on the Ni–Mn alloy deposits was studied. The electrodeposition mechanism of Mn with Ni is analyzed by the cyclic voltammogram (CV) and an "induced co-deposition" mechanism is proposed for Ni–Mn alloy electrodeposition. The results show that the Mn content in Ni–Mn alloy deposit and the hardness increased with the increase of Mn2+/Ni2+ mole ratio in electrolytes. When the Mn2+/Ni2+ mole ratio in bath was 2/1, the corrosion current density o...

  13. Oscillations in a sunspot with light bridges

    CERN Document Server

    Yuan, Ding; Huang, Zhenghua; Li, Bo; Su, Jiangtao; Yan, Yihua; Tan, Baolin

    2014-01-01

    Solar Optical Telescope onboard Hinode observed a sunspot (AR 11836) with two light bridges (LBs) on 31 Aug 2013. We analysed a 2-hour \\ion{Ca}{2} H emission intensity data set and detected strong 5-min oscillation power on both LBs and in the inner penumbra. The time-distance plot reveals that 5-min oscillation phase does not vary significantly along the thin bridge, indicating that the oscillations are likely to originate from the underneath. The slit taken along the central axis of the wide light bridge exhibits a standing wave feature. However, at the centre of the wide bridge, the 5-min oscillation power is found to be stronger than at its sides. Moreover, the time-distance plot across the wide bridge exhibits a herringbone pattern that indicates a counter-stream of two running waves originated at the bridge sides. Thus, the 5-min oscillations on the wide bridge also resemble the properties of running penumbral waves. The 5-min oscillations are suppressed in the umbra, while the 3-min oscillations occupy...

  14. Track-Bridge Longitudinal Interaction of Continuous Welded Rails on Arch Bridge

    Directory of Open Access Journals (Sweden)

    Rong Chen

    2013-01-01

    Full Text Available Taking arch bridges, including deck, half-through, and through arch bridges (short for DAB, HTAB, and TAB as examples, mechanics analysis models of longitudinal interaction between continuously welded rails (short for CWRs and arch bridges are established. Based on the finite element method (FEM, the longitudinal interaction calculation software of CWR on arch bridges has been developed. Focusing on an HTAB, the tension, compression, and deflection conditions are calculated and analyzed. The results show that the mechanics analysis models of three types of arch bridges can truly reflect the real state of the structure; the calculation software can be used for systematic research of the CWR on arch bridge; as for HTAB, temperature difference of arch rib has a small effect on rail tension/compression, and arch bridge can be simplified as a continuous beam for rail tension/compression additional force calculation; in calculation of deflection conditions of HTAB, it is suggested that train loads are arranged on half span and full span and take the direction of load entering bridge into account. Additionally, the deflection additional force variation of CFST basket handle arch bridge is different from that of ordinary bridge.

  15. Signal and noise in bridging PCR

    Directory of Open Access Journals (Sweden)

    Thaler David S

    2002-07-01

    Full Text Available Abstract Background In a variant of the standard PCR reaction termed bridging, or jumping, PCR the primer-bound sequences are originally on separate template molecules. Bridging can occur if, and only if, the templates contain a region of sequence similarity. A 3' end of synthesis in one round of synthesis that terminates in this region of similarity can prime on the other. In principle, Bridging PCR (BPCR can detect a subpopulation of one template that terminates synthesis in the region of sequence shared by the other template. This study considers the sensitivity and noise of BPCR as a quantitative assay for backbone interruptions. Bridging synthesis is also important to some methods for computing with DNA. Results In this study, BPCR was tested over a 328 base pair segment of the E. coli lac operon and a signal to noise ratio (S/N of approximately 10 was obtained under normal PCR conditions with Taq polymerase. With special precautions in the case of Taq or by using the Stoffel fragment the S/N was improved to 100, i.e. 1 part of cut input DNA yielded the same output as 100 parts of intact input DNA. Conclusions In the E. coli lac operator region studied here, depending on details of protocol, between 3 and 30% per kilobase of final PCR product resulted from bridging. Other systems are expected to differ in the proportion of product that is bridged consequent to PCR protocol and the sequence analyzed. In many cases physical bridging during PCR will have no informational consequence because the bridged templates are of identical sequence, but in a number of special cases bridging creates, or, destroys, information.

  16. Novel ferromagnetism in digital GaAs/Mn and GaSb/Mn alloys

    Science.gov (United States)

    McCombe, B. D.; Na, M.; Chen, X.; Cheon, M.; Wang, S.; Luo, H.; Liu, X.; Sasaki, Y.; Wojtowicz, T.; Furdyna, J. K.; Potashnik, S. J.; Schiffer, P.

    2003-01-01

    Ferromagnetic III-Mn-V semiconductors are under intensive investigation for spintronic applications. In the present work digital alloys of GaAs/Mn and GaSb/Mn were fabricated by a combination of molecular beam epitaxy and atomic layer epitaxy. The Mn fraction in the layers was varied at constant III-V spacer thickness, and the III-V spacer-layer thickness was varied at constant Mn fraction (0.5 monolayer). Transmission electron micrographs showed good crystal quality with no evidence of three-dimensional (3D) Mn-V precipitates. The GaAs/Mn samples have Curie temperatures in the vicinity of 40 K and exhibit an anomalous Hall effect (AHE) similar to that seen in GaMnAs random alloys. These samples all show thermally activated resistance at zero field, characteristic of hopping conduction with evidence of Coulomb-gap-like behavior. The GaSb/Mn samples exhibit ferromagnetism (with temperature dependent hysteresis loops) and a strong AHE up to 400 K. At low temperatures the remanent magnetization initially drops rapidly with increasing temperature, indicative of Curie temperatures between 10 and 50 K depending on the Mn concentration. However, a substantial remanent magnetization persists to high temperature, suggesting a second phase with a Curie temperature above 400 K. These samples all showed essentially metallic behavior and weak negative magnetoresistance at low temperatures. These results are discussed in the context of a model of quasi-2D MnSb islands (for which there is direct evidence) embedded in a matrix of GaMnSb in the Mn-containing layers.

  17. Human Errors and Bridge Management Systems

    DEFF Research Database (Denmark)

    Thoft-Christensen, Palle; Nowak, A. S.

    Human errors are divided in two groups. The first group contains human errors, which effect the reliability directly. The second group contains human errors, which will not directly effect the reliability of the structure. The methodology used to estimate so-called reliability distributions...... on basis of reliability profiles for bridges without human errors are extended to include bridges with human errors. The first rehabilitation distributions for bridges without and with human errors are combined into a joint first rehabilitation distribution. The methodology presented is illustrated...

  18. Building the Clinical Bridge: An Australian Success

    Directory of Open Access Journals (Sweden)

    Marianne Wallis

    2012-01-01

    Full Text Available Nursing effectiveness science includes primary, secondary, and translational, clinically focused research activities which aim to improve patient or client outcomes. It is imperative, for the successful conduct of a program of nursing effectiveness science, that a clinical bridge is established between academic and healthcare service facilities. An Australian example of the development of a robust clinical bridge through the use of jointly funded positions at the professorial level is outlined. In addition, an analysis of the practical application of Lewin’s model of change management and the contribution of both servant and transformational leadership styles to the bridge building process is provided.

  19. Building the clinical bridge: an Australian success.

    Science.gov (United States)

    Wallis, Marianne; Chaboyer, Wendy

    2012-01-01

    Nursing effectiveness science includes primary, secondary, and translational, clinically focused research activities which aim to improve patient or client outcomes. It is imperative, for the successful conduct of a program of nursing effectiveness science, that a clinical bridge is established between academic and healthcare service facilities. An Australian example of the development of a robust clinical bridge through the use of jointly funded positions at the professorial level is outlined. In addition, an analysis of the practical application of Lewin's model of change management and the contribution of both servant and transformational leadership styles to the bridge building process is provided.

  20. Maxwell Tension Supports the Water Bridge

    OpenAIRE

    Widom, A.; Srivastava, Y. N.; Swain, J.; Sivasubramanian, S.

    2008-01-01

    A cylindrical flexible cable made up of pure fluid water can be experimentally spanned across a spatial gap with cable endpoints fixed to the top edges of two glass beakers. The cable has been called a water bridge in close analogy to iron cables employed to build ordinary span bridges. A necessary condition for the construction of a water bridge is that a large electric field exists parallel to and located within the water cable. Presently, there is no accepted detailed theory which quantita...

  1. Pilot testing of a hydraulic bridge exciter

    OpenAIRE

    Andersson Andreas; Ülker-Kaustell Mahir; Borg Richard; Dymén Olivier; Carolin Anders; Karoumi Raid

    2015-01-01

    This paper describes the development of a hydraulic bridge exciter and its first pilot testing on a full scale railway bridge in service. The exciter is based on a hydraulic load cylinder with a capacity of 50 kN and is intended for controlled dynamic loading up to at least 50 Hz. The load is applied from underneath the bridge, enabling testing while the railway line is in service. The system is shown to produce constant load amplitude even at resonance. The exciter is used to experimentally ...

  2. Diphosphine- and CO-Induced Fragmentation of Chloride-bridged Dinuclear Complex and Cp*Ir(mu-Cl)(3)Re(CO)(3) and Attempted Synthesis of Cp*Ir(mu-Cl)(3)Mn(CO)(3): Spectroscopic Data and X-ray Diffraction Structures of the Pentamethylcyclopentadienyl Compounds [Cp*IrCl{(Z)-Ph2PCH = CHPPh2}][Cl]center dot 2CHCl(3) and Cp*Ir(CO)Cl-2

    Energy Technology Data Exchange (ETDEWEB)

    Hammons, Casey [University of North Texas; Wang, Xiaoping [ORNL; Nesterov, Vladimir [University of North Texas; Richmond, Michael G. [University of North Texas

    2010-01-01

    The confacial bioctahedral compound Cp*Ir(mu-Cl)(3)Re(CO)(3) (1) undergoes rapid fragmentation in the presence of the unsaturated diphosphine ligand (Z)-Ph2PCH = CHPPh2 to give the mononuclear compounds [Cp*IrCl {(Z)-Ph2PCH = CHPPh2}][Cl] (2) and fac-ClRe(CO)(3)[(Z)-Ph2PCH = CHPPh2] (3). 2 has been characterized by H-1 and P-31 NMR spectroscopy and X-ray diffraction analysis. 2 center dot 2CHCl(3) crystallizes in the monoclinic space group C2/c, a = 35.023 (8) angstrom, b = 10.189 (2) angstrom, c = 24.003 (6) angstrom, b = 103.340 (3), V = 8,335 (3) angstrom 3, Z = 8, and d(calc) = 1.647 Mg/m(3); R = 0.0383, R-w = 0.1135 for 8,178 reflections with I> 2 sigma(I). The Ir(III) center in 2 exhibits a six-coordinate geometry and displays a chelating diphosphine group. Compound 1 reacts with added CO with fragmentation to yield the known compounds Cp*Ir(CO)Cl-2 (4) and ClRe(CO)(5) (5) in near quantitative yield by IR spectroscopy. Using the protocol established by our groups for the synthesis of 1, we have explored the reaction of [Cp*IrCl2](2) with ClMn(CO)(5) as a potential route to Cp*Ir(mu-Cl)(3)Mn(CO)(3); unfortunately, 4 was the only product isolated from this reaction. The solid-state structure of 4 was determined by X-ray diffraction analysis. 4 crystallizes in the triclinic space group P-1, a = 7.4059 (4) angstrom, b = 7.8940 (4) angstrom, c = 11.8488 (7) angstrom, alpha = 80.020 (1), beta = 79.758 (1), gamma = 68.631 (1), V = 630.34 (6) angstrom(3), Z = 2, and d(calc) = 2.246 Mg/m(3); R = 0.0126, R-w = 0.0329 for 2,754 reflections with I> 2 sigma(I). The expected three-legged piano-stool geometry in 4 has been crystallographically confirmed.

  3. Mn vacancy defects, grain boundaries, and A-phase stability of helimagnet MnSi.

    Science.gov (United States)

    Ou-Yang, T Y; Shu, G J; Lin, J-Y; Hu, C D; Chou, F C

    2016-01-20

    Mn vacancy defect and grain size are shown to modify the magnetic phase diagram of MnSi significantly, especially near the critical regime of A-phase (skyrmion lattice) formation and the helimagnetic phase transition. Crystals grown using controlled nonstoichiometric initial precursors creates both grain boundaries and intrinsic Mn vacancy defect of various levels in MnSi. The results of combined transport, specific heat, and AC spin susceptibility measurements are compared for MnSi single crystal samples of various manganese deficiency levels and grain sizes. The finite-size effect and Mn vacancy level dependent helical phase transition temperature T(c) have been identified and verified. The stability of A-phase in H-T phase space has been examined through AC spin susceptibility data analysis.

  4. Mn vacancy defects, grain boundaries, and A-phase stability of helimagnet MnSi

    Science.gov (United States)

    Ou-Yang, T. Y.; Shu, G. J.; Lin, J.-Y.; Hu, C. D.; Chou, F. C.

    2016-01-01

    Mn vacancy defect and grain size are shown to modify the magnetic phase diagram of MnSi significantly, especially near the critical regime of A-phase (skyrmion lattice) formation and the helimagnetic phase transition. Crystals grown using controlled nonstoichiometric initial precursors creates both grain boundaries and intrinsic Mn vacancy defect of various levels in MnSi. The results of combined transport, specific heat, and AC spin susceptibility measurements are compared for MnSi single crystal samples of various manganese deficiency levels and grain sizes. The finite-size effect and Mn vacancy level dependent helical phase transition temperature {{T}\\text{c}} have been identified and verified. The stability of A-phase in H-T phase space has been examined through AC spin susceptibility data analysis.

  5. Emergent ferromagnetism in NdMnO3 /SrMnO3 superlattices

    Science.gov (United States)

    Glavic, Artur; Calder, Stuart; Cooper, Valentino; Dixit, Hemant

    2015-03-01

    The phenomenon of ferromagnetism evolving in digital superlattices of two antiferromagnets LaMnO3[2n]/SrMnO3[n] has been well established. We show that this interface effect can be observed in systems with different rare earth manganites as well, exemplified in the Nd system grown on LSAT and TbScO3 substrates. With polarized neutron reflectometry we prove that not only 2/1 unit cell samples become ferromagnetic but that interface ferromagnetism can be induced whenever a single layer of SrMnO3 is introduced in the NdMnO3 system. These results show that the strain state of the superlattice system is of much less importance for the induced magnetization then the Mn3+/Mn4+ electronic state.

  6. Effect of Mn and Fe on the Formation of Fe- and Mn-Rich Intermetallics in Al–5Mg–Mn Alloys Solidified Under Near-Rapid Cooling

    Directory of Open Access Journals (Sweden)

    Yulin Liu

    2016-01-01

    Full Text Available Mn was an important alloying element used in Al–Mg–Mn alloys. However, it had to be limited to a low level (<1.0 wt % to avoid the formation of coarse intermetallics. In order to take full advantage of the benefits of Mn, research was carried out to investigate the possibility of increasing the content of Mn by studying the effect of cooling rate on the formation of Fe- and Mn-rich intermetallics at different content levels of Mn and Fe. The results indicated that in Al–5Mg–Mn alloy with low Fe content (<0.1 wt %, intermetallic Al6(Fe,Mn was small in size and amount. With increasing Mn content, intermetallic Al6(Fe,Mn increased, but in limited amount. In high-Fe-containing Al–5Mg–Mn alloys (0.5 wt % Fe, intermetallic Al6(Fe,Mn became the dominant phase, even in the alloy with low Mn content (0.39 wt %. Cooling rate played a critical role in the refinement of the intermetallics. Under near-rapid cooling, intermetallic Al6(Fe,Mn was extremely refined. Even in the high Mn and/or high-Fe-containing alloys, it still demonstrated fine Chinese script structures. However, once the alloy composition passed beyond the eutectic point, the primary intermetallic Al6(Fe,Mn phase displayed extremely coarse platelet-like morphology. Increasing the content of Fe caused intermetallic Al6(Fe,Mn to become the primary phase at a lower Mn content.

  7. Allegheny County-Owned Bridges Points

    Data.gov (United States)

    Allegheny County / City of Pittsburgh / Western PA Regional Data Center — This dataset shows the location of bridges owned by Allegheny County as centroids. If viewing this description on the Western Pennsylvania Regional Data Center’s...

  8. Allegheny County-Owned Bridges Centerlines

    Data.gov (United States)

    Allegheny County / City of Pittsburgh / Western PA Regional Data Center — This dataset shows the bridges owned by Allegheny County. If viewing this description on the Western Pennsylvania Regional Data Center’s open data portal...

  9. Influence of Icing on Bridge Cable Aerodynamics

    DEFF Research Database (Denmark)

    Koss, Holger; Frej Henningsen, Jesper; Olsen, Idar

    2013-01-01

    In recent years the relevance of ice accretion for wind-induced vibration of structural bridge cables has been recognised and became a subject of research in bridge engineering. Full-scale monitoring and observation indicate that light precipitation at moderate low temperatures between zero and -5......°C may lead to large amplitude vibrations of bridge cables under wind action. For the prediction of aerodynamic instability quasi-steady models have been developed estimating the cable response magnitude based on structural properties and aerodynamic force coefficients for drag, lift and torsion...... forces of different bridge cables types. The experiments were conducted in a wind tunnel facility capable amongst others to simulate incloud icing conditions....

  10. Assessment of the Reliability of Concrete Bridges

    DEFF Research Database (Denmark)

    Middleton, C. R.; Thoft-Christensen, Palle

    in the wake of ever increasing traffic loads and volumes, and an ageing population of bridges subject to various mechanisms of deterioration. The goal is to optimise the allocation of limited resources whilst maintaining their bridges in a safe and serviceable condition. Reliability analysis is one tool being......Although there has been a considerable amount of research into different aspects of concrete bridge reliability, it has still not been widely adopted in professional practice other than in the development and calibration of codes. This situation appears to be changing as there has been...... adopted to assist in achieving this goal. Rather than review the specific research on this subject this paper examines a number of key issues related to the practical application of reliability analysis to the assessment of concrete bridges....

  11. Pilot testing of a hydraulic bridge exciter

    Directory of Open Access Journals (Sweden)

    Andersson Andreas

    2015-01-01

    Full Text Available This paper describes the development of a hydraulic bridge exciter and its first pilot testing on a full scale railway bridge in service. The exciter is based on a hydraulic load cylinder with a capacity of 50 kN and is intended for controlled dynamic loading up to at least 50 Hz. The load is applied from underneath the bridge, enabling testing while the railway line is in service. The system is shown to produce constant load amplitude even at resonance. The exciter is used to experimentally determine frequency response functions at all sensor locations, which serve as valuable input for model updating and verification. An FE-model of the case study bridge has been developed that is in good agreement with the experimental results.

  12. Practical Approach to Fragility Analysis of Bridges

    Directory of Open Access Journals (Sweden)

    Yasamin Rafie Nazari

    2012-12-01

    Full Text Available Damages during past earthquakes reveal seismic vulnerability of bridge structures and the necessity of probabilistic approach toward seismic performance evaluation of bridges and its interpretation in terms of decision variables such as repair cost, downtime and life loss. This Procedure involves hazard analysis, structural analysis, damage analysis and loss analysis. The purpose of present study is reviewing different methods developed to derive fragility curves for damage analysis of bridges and demonstrating a simple procedure for fragility analysis using Microsoft Office Excel worksheet to reach probability of occurring predefined level of damage due to different levels of seismic demand parameters. The input of this procedure is the intensity of ground motion and the output is an appropriate estimate of the expected damage. Different observed damages of the bridges are discussed and compared the practical definition of damage states. Different methods of fragility analyses are discussed and a practical step by step example is illustrated.

  13. Mn-Zn soft magnetic ferrite nanoparticles synthesized from spent alkaline Zn-Mn batteries

    International Nuclear Information System (INIS)

    Research highlights: → This manuscript reports for the first time to prepare Mn-Zn soft magnetic ferrite nanoparticles using spent alkaline Zn-Mn batteries as raw material by multi-step processes including acid leaching, chemical treatment of battery iron shells and citrate-nitrate precursor auto-combustion. → Synthesized Mn0.5Zn0.5Fe2O4 ferrite nanoparticles have pure ferrite phase, larger saturation magnetization and lower coercivity compared with the same composition ferrites prepared by other techniques due to better crystallinity. → Auto-combustion Mn-Zn ferrite nanoparticles synthesis method presents a viable alternative for alkaline Zn-Mn batteries recycling due to its target product is not a single metal or its oxide. → It is original and not currently submitted for review to any other journal and their intent is to publish the article in the Journal of Alloys and Compounds. - Abstract: Using spent alkaline Zn-Mn batteries as raw material, Mn-Zn soft magnetic ferrite nanoparticles are prepared by multi-step processes including acid leaching, chemical treatment of battery iron shells and citrate-nitrate precursor auto-combustion. Acid leaching and chemical treatment mechanisms are investigated. Dried gels thermal decomposition process, auto-combustion, phase composition, morphological and magnetic properties of as-prepared Mn-Zn ferrite nanoparticles are characterized by thermogravimetric and differential thermal analysis, X-ray powder diffraction, transmission electron microscopy and vibrating sample magnetometer. Synthesized Mn-Zn ferrite nanoparticles (Mn0.5Zn0.5Fe2O4) have pure ferrite phase, larger saturation magnetization (Ms = 60.62 emu g-1) and lower coercivity (Hc = 30 Oe) compared with the same composition ferrites prepared by other techniques due to better crystallinity. Mn-Zn ferrite nanoparticles synthesis method presents a viable alternative for alkaline Zn-Mn batteries recycling.

  14. Identifying hidden sexual bridging communities in Chicago.

    Science.gov (United States)

    Youm, Yoosik; Mackesy-Amiti, Mary Ellen; Williams, Chyvette T; Ouellet, Lawrence J

    2009-07-01

    Bridge populations can play a central role in the spread of human immunodeficiency virus (HIV) by providing transmission links between higher and lower prevalence populations. While social network methods are well suited to the study of bridge populations, analyses tend to focus on dyads (i.e., risk between drug and/or sex partners) and ignore bridges between distinct subpopulations. This study takes initial steps toward moving the analysis of sexual network linkages beyond individual and risk group levels to a community level in which Chicago's 77 community areas are examined as subpopulations for the purpose of identifying potential bridging communities. Of particular interest are "hidden" bridging communities; that is, areas with above-average levels of sexual ties with other areas but whose below-average AIDS prevalence may hide their potential importance for HIV prevention. Data for this analysis came from the first wave of recruiting at the Chicago Sexual Acquisition and Transmission of HIV Cooperative Agreement Program site. Between August 2005 through October 2006, respondent-driven sampling was used to recruit users of heroin, cocaine, or methamphetamine, men who have sex with men regardless of drug use, the sex partners of these two groups, and sex partners of the sex partners. In this cross-sectional study of the sexual transmission of HIV, participants completed a network-focused computer-assisted self-administered interview, which included questions about the geographic locations of sexual contacts with up to six recent partners. Bridging scores for each area were determined using a matrix representing Chicago's 77 community areas and were assessed using two measures: non-redundant ties and flow betweenness. Bridging measures and acquired immunodeficiency syndrome (AIDS) case prevalence rates were plotted for each community area on charts representing four conditions: below-average bridging and AIDS prevalence, below-average bridging and above

  15. Inspection Based Evaluation of a Danish Road Bridge

    DEFF Research Database (Denmark)

    Thoft-Christensen, Palle

    In this paper it is shown how an inspection-based evaluation of a Danish road bridge may be performed using the BRIDGE1 and BRIDGE2 bridge management systems produced within the EC-supported research programme "Assessment of Performance and Optimal Strategies for Inspection and Maintenance...

  16. TMACS test procedure TP012: Panalarm software bridge

    International Nuclear Information System (INIS)

    This Test Procedure addresses the testing of the functionality of the Tank Monitor and Control System (TMACS) Panalarm bridge software. The features to be tested are: Bridge Initialization Options; Bridge Communication; Bridge Performance; Testing Checksum Errors; and Testing Command Reject Errors. Only the first three could be tested; the last two have been deferred to a later date

  17. An anti-ferromagnetic terephthalate-bridged trigonal prismatic dinuclear manganese(II) complex: Synthon of rare anion $^{\\ldots}$ interaction promoting dimensionality

    Indian Academy of Sciences (India)

    Somnath Choubey; Soumi Chattopadhayay; Kishalay Bhar; Subhasis Roy; Sumitava Khan; Joan Ribas; Barindra Kumar Ghosh

    2014-11-01

    A dinuclear compound [Mn2(L)2(-tp)](PF6)2·3.57H2O (1) [L = N,N′-(bis(pyridin-2-yl)benzylidene)-1,3-propanediamine and tp = terephthalate dianion] has been isolated and characterized on the basis of microanalytical, spectroscopic and other physicochemical properties. X-ray structural study showed interesting bis(bidentate) bridging motif of tp in the dicationic dinuclear unit [Mn2(-tp)]2+. Each manganese(II) centre adopts a rare distorted trigonal prismatic geometry with an MnN4O2 chromophore.Chelation of the tetradentate Schiff base (L) along with bis(bidentate) bridging of two O atoms of tp complete hexacoordination around each manganese(II) centre. The dinuclear units of 1 are associated through cooperative C-H$\\cdots$F hydrogen bonds and $^{\\cdot}$ , C-H$^{\\cdots}$ and rare anion$^{\\cdots}$ interactions to promote the dimensionality in a graded manner. Variable temperature magnetic susceptibility measurement of 1 in the 2-300 K temperature range revealed weak antiferromagnetic interaction presumably due to long bridging arm of tp.

  18. Assessment of a Bridge WIM System on Integral Concrete Bridges and on Steel Orthotropic Decks

    OpenAIRE

    Ieng, Sio Song; SCHMIDT, Franziska; ROMBONI, Frédéric; Jacob, Bernard

    2011-01-01

    Bridge-Weigh-In-Motion uses bridges as a scale to weigh vehicles. Practically, this is done by measuring the strains in that bridge, and relating them to the weight and dimensions of a truck called “calibration trucks” whose shape and axle weights are well known. This article summarizes different B-WIM experiments the institute IFSTTAR (formerly called LCPC) realized and the lessons drawn from this experience. First, the system has been tested on frame-type bridges with integral s...

  19. Experimental study of single span railway bridges

    OpenAIRE

    Rigueiro, Constança; Rebelo, C.; Silva, L. Simões da

    2007-01-01

    The main purpose of this paper is to present some results concerning the investigation that has been done by the authors regarding the dynamic response of small to médium span railway bridges using response acceleration data colleted during the measurements carried out on single span bridges on the railway track Linz-Wels, in Austria. Using output-only methods in this experimental program, it was possible to have an estimation of the igenfrequencies, mode shapes and the corresponding viscous ...

  20. Active control of vibrations in pedestrian bridges

    OpenAIRE

    Álvaro Cunha; Carlos Moutinho

    1999-01-01

    This paper, apart from making a brief general reference to vibration problems in pedestrian bridges, as well as to the form of modelling of dynamic pedestrian loads, presents the use of a predictive control strategy for the numerical simulation of the dynamic response of actively controlled structures of this type. The consideration of this control strategy permitted the development of a computational model, which was applied to the study of a pedestrian cable-stayed bridge, in order to show ...

  1. Building Organic Bridges: Volume 1, Argentina - France

    OpenAIRE

    Rahmann, Gerold; Aksoy, Uygun

    2014-01-01

    [Foreword ...] The 18th IFOAM Organic World Congress held on 13-15 October, 2014 in Istanbul-Turkey targets to 'build organic bridges'. The Scientific track will contribute to bridging not only scientists but also institutions and disciplines, and to linking more developed and less developed, rural and urban, research to extension, plant to animal, farm practices to world-wide problems and producer and consumers. Organic is a management system that requires a diversity of inputs from differen...

  2. Building Organic Bridges: Volume 2, Germany - India

    OpenAIRE

    Rahmann, Gerold; Aksoy, Uygun

    2014-01-01

    [Foreword ...] The 18th IFOAM Organic World Congress held on 13-15 October, 2014 in Istanbul-Turkey targets to 'build organic bridges'. The Scientific track will contribute to bridging not only scientists but also institutions and disciplines, and to linking more developed and less developed, rural and urban, research to extension, plant to animal, farm practices to world-wide problems and producer and consumers. Organic is a management system that requires a diversity of inputs from differen...

  3. Thermal Bridge Effects in Walls Separating Rowhouses

    DEFF Research Database (Denmark)

    Rose, Jørgen

    1997-01-01

    In this report the thermal bridge effects at internal wall/roof junctions in rowhouses are evaluated. The analysis is performed using a numerical calculation programme, and different solutions are evaluated with respect to extra heat loss and internal surface temperatures.......In this report the thermal bridge effects at internal wall/roof junctions in rowhouses are evaluated. The analysis is performed using a numerical calculation programme, and different solutions are evaluated with respect to extra heat loss and internal surface temperatures....

  4. External Prestressing Bridge Reinforcement Technology Review

    Directory of Open Access Journals (Sweden)

    Zhu Hanbing

    2015-01-01

    Full Text Available Externally prestressed bridge can not only limit and reduce the cracks and deformation of the structure, improve the rigidity and bearing capacity of structure, improve the stress state of structure, but also have less interference for bridge operation when it is operating and have the good economic efficiency. This paper introduces the advantages and disadvantages of external prestressed strengthening technique, its calculation theory and construction technology described in detail, and finally the paper discusses the deficiency of existing research.

  5. Subscapularis Tendon Repair Using Suture Bridge Technique

    OpenAIRE

    Park, Yong Bok; Park, Young Eun; Koh, Kyoung Hwan; Lim, Tae Kang; Shon, Min Soo; Yoo, Jae Chul

    2015-01-01

    The subscapularis tendon plays an essential role in shoulder function. Although subscapularis tendon tears are less common than other rotator cuff tears, tears of the subscapularis tendon have increasingly been recognized with the advent of magnetic resonance imaging and arthroscopy. A suture bridge technique for the treatment of posterosuperior rotator cuff tears has provided the opportunity to improve the pressurized contact area and mean footprint pressure. However, suture bridge fixation ...

  6. Magnetic coupling in ferromagnetic semiconductor (Ga,Mn)As/(Al,Ga,Mn)As bilayers

    Energy Technology Data Exchange (ETDEWEB)

    Wang, M.; Wadley, P.; Campion, R. P.; Rushforth, A. W.; Edmonds, K. W.; Gallagher, B. L. [School of Physics and Astronomy, University of Nottingham, University Park, Nottingham NG7 2RD (United Kingdom); Charlton, T. R.; Kinane, C. J.; Langridge, S. [ISIS, Rutherford Appleton Laboratory, Harwell Science and Innovation Campus, Science and Technology Facilities Council, Oxon OX11 0QX (United Kingdom)

    2015-08-07

    We report on a study of ferromagnetic semiconductor (Ga,Mn)As/(Al,Ga,Mn)As bilayers using magnetometry and polarized neutron reflectivity (PNR). From depth-resolved characterization of the magnetic structure obtained by PNR, we concluded that the (Ga,Mn)As and (Al,Ga,Mn)As layers have in-plane and perpendicular-to-plane magnetic easy axes, respectively, with weak interlayer coupling. Therefore, the layer magnetizations align perpendicular to each other under low magnetic fields and parallel at high fields.

  7. Different origin of the ferromagnetic order in (Ga,Mn)As and (Ga,Mn)N

    OpenAIRE

    Wierzbowska, Malgorzata; Sanchez-Portal, Daniel; Sanvito, Stefano

    2004-01-01

    The mechanism for the ferromagnetic order of (Ga,Mn)As and (Ga,Mn)N is extensively studied over a vast range of Mn concentrations. We calculate the electronic structures of these materials using density functional theory in both the local spin density approximation and the LDA+U scheme, that we have now implemented in the code SIESTA. For (Ga,Mn)As, the LDA+U approach leads to a hole mediated picture of the ferromagnetism, with an exchange constant $N\\beta$ =~ -2.8 eV. This is smaller than th...

  8. Studies on Spinel LiMn2O4 Cathode Material Synthesized from Different Mn Sources

    Institute of Scientific and Technical Information of China (English)

    唐致远; 冯季军; 彭亚宁

    2004-01-01

    The spinel LiMn2O4 cathode material was synthesized with the solid-state reaction method. Four manganese compounds including electrolytic manganese dioxide (EMD), MnCO3, Mn3O4 and nano-EMD were used as Mn sources while LiOH·H2O was used as the uniform Li source. The crystal structure characteristics of these samples produced were investigated by means of XRD, SEM, particle size distribution analysis and specific surface area testing. Their electrochemical properties were also studied by comparing their specific capacity, charge and discharge efficiency and cycle performance.

  9. Magnetic fields of HgMn stars

    DEFF Research Database (Denmark)

    Hubrig, S.; Gonzalez, J. F.; Ilyin, I.;

    2012-01-01

    Context. The frequent presence of weak magnetic fields on the surface of spotted late-B stars with HgMn peculiarity in binary systems has been controversial during the two last decades. Recent studies of magnetic fields in these stars using the least-squares deconvolution (LSD) technique have...... by applying the moment technique on spectral lines of inhomogeneously distributed elements separately. Furthermore, we present new determinations of the mean longitudinal magnetic field for the HgMn star HD 65949 and the hotter analog of HgMn stars, the PGa star HD 19400, using FORS 2 installed at the VLT. We...... also give new measurements of the eclipsing system ARAur with a primary star of HgMn peculiarity, which were obtained with the SOFIN spectropolarimeter installed at the Nordic Optical Telescope. Methods. We downloaded from the European Southern Observatory (ESO) archive the publically available HARPS...

  10. Biota - 2011 Vegetation Inventory - Marsh Lake, MN

    Data.gov (United States)

    Army Corps of Engineers, Department of the Army, Department of Defense — 2011 Vegetation Classification for Marsh Lake, MN Vegetation Project Report, OMBIL Environmental Stewardship - Level 1 Inventory. Marsh Lake is located on the...

  11. Synthesis of nanosize MnO2 and its performence

    Institute of Scientific and Technical Information of China (English)

    顾大明; 魏杰

    2003-01-01

    Sol sol-gel method and solid phase redox reaction were respectively applied in preparation of Nanos-ize MnO2 powders. The experiments showed that only Mn2O3 could be obtained from ignition of Mn( Ⅱ ) in themuffle furnace in air, and Mn2O3 had to be disproportionated in acids to gain MnO2. The analysis of XRD andTEM technique revealed that the diameters of nanosize MnO2 obtained by sol-gel method was 35 ~45 nm andthe x in MnOx was 1.9; the particle size of MnO2 produced from solid phase redox reaction was 10 ~ 20 nm andthe x in MnOx equaled 1.94. The test results have proved that the discharge property of alkaline-manganese bat-tery could be improved by nanosize MnO2.

  12. Framework for Bridges Maintenance in Egypt

    Directory of Open Access Journals (Sweden)

    Hesham Abd Elkhalek

    2016-01-01

    Full Text Available The traditional approaches for bridges maintenance is proven to be inefficient as they lead to random way of spending maintenance budget and deteriorating bridge conditions. In many cases, maintenance activities are performed due to user complaints. The objective of this paper is to develop a practical and reliable framework to manage the maintenance and repair activities of Bridges network in Egypt considering performance and budget limits. The model solves an optimization problem that maximizes the average condition of the network given the limited budget using Genetic Algorithm (GA. The main tasks of the system are bridge inventory, condition assessment, deterioration using markov model, and maintenance optimization. The developed model takes into account multiple parameters including serviceability requirements, budget allocation, element importance on structural safety and serviceability, bridge impact on network, and traffic. A questionnaire is conducted to complete the research scope. The proposed model is implemented in software, which provides a friendly user interface. The results of the framework are multi – year maintenance plan for the entire network for up to five years. A case study is presented for validating and testing the model with Data collected from “General Authority for Roads, Bridges and Land Transport” in Egypt.

  13. Precast Pearl-Chain concrete arch bridges

    DEFF Research Database (Denmark)

    Halding, Philip Skov; Hertz, Kristian Dahl; Schmidt, Jacob Wittrup

    2015-01-01

    A Pearl-Chain Bridge is a closed-spandrel arch bridge consisting of a number of straight pre-fabricated so called Super-Light Deck elements put together in an arch shape by post-tensioning cables. Several Pearl-Chain arches can be positioned adjacent to each other by a crane to achieve a bridge...... the technology was used. We also study other important components and details in the Pearl-Chain Bridge concept and review the effects of different types of loads. A theoretical case study of a circular 30 m span Pearl-Chain Bridge is presented showing the influence of a number of parameters: The number of post......-tensioning cables, the rise to span ratio, the height of the filling, and the height of the Super-Light Decks. We find that Pearl-Chain Bridges can be adjusted to resist specific moment loads by changing the normal force in the arch cross section by altering the above parameters. It is also found that the negative...

  14. Spin polarization effect for Mn2 molecule

    Institute of Scientific and Technical Information of China (English)

    Yan Shi-Ying; Xu Guo-Liang

    2007-01-01

    The density functional theory method (DFT) (b3p86) of Gaussian 03 has been used to optimize the structure of the Mn2 molecule.The result shows that the ground state of the Mn2 molecule is an 11-multiple state,indicating a spin polarization effect in the Mn2 molecule,a transition metal element molecule.Meanwhile,we have not found any spin pollution because the wavefunction of the ground state does not mingle with wavefunctions of higher-energy states.So the ground state for Mn2 molecule being of an 11-multiple state is the indicative of spin polarization effect of the Mn2 molecule among those in the transition metal elements:that is,there are 10 parallel spin electrons in a Mn2 molecule.The number of non-conjugated electrons is the greatest.These electrons occupy different spacious orbitals so that the energy of the Mn2 molecule is minimized.It can be concluded that the effect of parallel spin in the Mn2 molecule is larger than the effect of the conjugated molecule,which is obviously related to the effect of electron d delocalization.In addition,the Murrell-Sorbie potential functions with the parameters for the ground state and other states of the Mn2 molecule are derived.The dissociation energy De for the ground state of the Mn2 molecule is 1.4477eV,equilibrium bond length Re is 0.2506 nm,vibration frequency ωe is 211.51 cm-1.Its force constants,f2,f3,and f4 are 0.7240 aJ·nm-2,-3.35574 aJ·nm-3,11.4813 aJ·nm-4 respectively. The other spectroscopic data for the ground state of the Mn2 molecule ωeχe,Be,αe are 1.5301 cm-1,0.0978 cm-1,7.7825×10-4 cm-1 respectively.

  15. High Mn austenitic stainless steel

    Science.gov (United States)

    Yamamoto, Yukinori [Oak Ridge, TN; Santella, Michael L [Knoxville, TN; Brady, Michael P [Oak Ridge, TN; Maziasz, Philip J [Oak Ridge, TN; Liu, Chain-tsuan [Knoxville, TN

    2010-07-13

    An austenitic stainless steel alloy includes, in weight percent: >4 to 15 Mn; 8 to 15 Ni; 14 to 16 Cr; 2.4 to 3 Al; 0.4 to 1 total of at least one of Nb and Ta; 0.05 to 0.2 C; 0.01 to 0.02 B; no more than 0.3 of combined Ti+V; up to 3 Mo; up to 3 Co; up to 1W; up to 3 Cu; up to 1 Si; up to 0.05 P; up to 1 total of at least one of Y, La, Ce, Hf, and Zr; less than 0.05 N; and base Fe, wherein the weight percent Fe is greater than the weight percent Ni, and wherein the alloy forms an external continuous scale including alumina, nanometer scale sized particles distributed throughout the microstructure, the particles including at least one of NbC and TaC, and a stable essentially single phase FCC austenitic matrix microstructure that is essentially delta-ferrite-free and essentially BCC-phase-free.

  16. Antiferromagnetic semiconductor LiMnAs

    Energy Technology Data Exchange (ETDEWEB)

    Novak, Vit; Jungwirth, Tomas; Cukr, Miroslav [Institute of Physics AS CR, Cukrovarnicka 10, Praha (Czech Republic); Svoboda, Stepan [Institute of Physics AS CR, Cukrovarnicka 10, Praha (Czech Republic); Charles University, Ke Karlovu 5, Praha (Czech Republic); Soban, Zbynek [Institute of Physics AS CR, Cukrovarnicka 10, Praha (Czech Republic); Czech Technical University, Technicka 2, Praha (Czech Republic); Marti, Xavier; Holy, Vaclav; Horodyska, Petra; Nemec, Petr [Charles University, Ke Karlovu 5, Praha (Czech Republic)

    2011-07-01

    LiMnAs belongs to the theoretically predicted class of I-Mn-V semiconductors with the antiferromagnetic ordering of Mn atoms. We report its first successful preparation in form of a thin film by molecular beam epitaxy. Structural properties of the material were examined in-situ by RHEED, and ex-situ by XPS and XRD, confirming the tetragonal crystal structure with its [100] direction oriented along the [110] direction of the InAs substrate. Transparency of LiMnAs in the spectral range of 870 to 1400 nm confirms the existence of an optical gap and indicates the band-gap energy above 1.4 eV. Magnetic properties measured by SQUID magnetometry show nearly compensated net magnetic moment in temperatures up to 400 K and magnetic fields up to 7 T, in a clear contrast to the ferromagnetic character of MnAs or to the paramagnetic behavior of the same amount of uncoupled Mn atoms.

  17. Response Modification Factors for Concrete Bridges in Europe

    OpenAIRE

    Kappos, A. J.; Paraskeva, T. S.; Moschonas, I. F.

    2013-01-01

    The paper presents a methodology for evaluating the actual response modification factors (q or R) of bridges and applies it to seven concrete bridges typical of the stock found in southern Europe. The usual procedure for analytically estimating the q-factor is through pushover curves derived for the bridge in (at least) its longitudinal and transverse directions. The shape of such curves depends on the seismic energy dissipation mechanism of the bridge; hence, bridges are assigned to two cate...

  18. Correlation of Mn charge state with the electrical resistivity of Mn doped indium tin oxide thin films

    KAUST Repository

    Kumar, S. R. Sarath

    2010-09-15

    Correlation of charge state of Mn with the increase in resistivity with Mn concentration is demonstrated in Mn-doped indium tin oxide films. Bonding analysis shows that Mn 2p3/2 core level can be deconvoluted into three components corresponding to Mn2+ and Mn4+ with binding energies 640.8 eV and 642.7 eV, respectively, and a Mn2+ satellite at ∼5.4 eV away from the Mn2+ peak. The presence of the satellite peak unambiguously proves that Mn exists in the +2 charge state. The ratio of concentration of Mn2+ to Mn4+ of ∼4:1 suggests that charge compensation occurs in the n-type films causing the resistivity increase.

  19. Synthesis and characterization of Mn intercalated Mg-Al hydrotalcite.

    Science.gov (United States)

    Yang, Chengxue; Liao, Libing; Lv, Guocheng; Wu, Limei; Mei, Lefu; Li, Zhaohui

    2016-10-01

    Mn intercalated hydrotalcite was prepared using a reconstruction method. And Mn intercalation was confirmed by XRD, FTIR, and thermal analyses. The different valences of Mn were present as determined by XPS. Calcination slightly promoted the isomorphic replacement of Mn(2+) and Mn(3+) for Mg(2+) and Al(3+), especially the replacement of Mn(2+) for Mg(2+) and Al(3+), and to some extent, reduced Mn intercalation. Ultrasonic treatment significantly increased Mn intercalation in permanganate form (Mn(7+)), and promoted the replacement of Mn(2+) for Mg(2+) and Al(3+). XRF analysis showed that ultrasonic treatment decreased the unbalanced layer charge of Mn intercalated hydrotalcite, while prolonged calcination increased it. These results may provide guidance on the preparation and application of Mn intercalated hydrotalcite. Extended calcination time and ultrasonic vibration increased the interlayer spacing of hydrotalcite, as a result of reduction in layer charge. As the layer charge was not completely balanced after Mn intercalation, a certain amount of CO3(2-) was re-adsorbed into the interlayer space. Mn-hydrotalcites with different layer charges, different contents of Mn with varying valences are expected to have different performances in the process of adsorption, degradation, and catalysis. PMID:27380016

  20. Composition dependence on the martensitic structures of the Mn-rich NiMnGa alloys

    Energy Technology Data Exchange (ETDEWEB)

    Jiang Chengbao; Muhammad, Yousaf; Deng Lifeng; Wu Wei; Xu Huibin

    2004-05-17

    The Mn-rich Ni{sub 50}Mn{sub 25+x}Ga{sub 25-x} (x=0-5) alloys were developed to investigate the structural transitions and magnetic properties. Structural transitions from austenite to 5M, 7M, and non-modulated martensite were observed with the increase of Mn content. The lattice parameter a elongates, as where b and c contract, and the unit cell volume reduces with increasing Mn content. The martensitic transformation start temperatures M{sub s} increase monotonically from 10.7 deg. C for x=2 to 102.7 deg. C for x=5. The saturation magnetization was measured at 5 K, where all the samples exhibit a martensitic structure. The average magnetic moments per Mn atom vary from 4.38 {mu}{sub B} to 2.93 {mu}{sub B} for x=0 to x=5. The negative effect of excess Mn atoms changes from -3.00 {mu}{sub B} for x=2 to -7.25 {mu}{sub B} for x=5. The excess Mn atoms modify the electronic structures of the unsubstituted Mn atoms, resulting in the sharp decrease of the magnetic moments of the unsubstituted Mn atoms with increasing Mn content. Structural incommensurability was observed with 7M for powder and non-modulated for bulk samper in a specific range of compositions and proved to be reversible when performing martensitic transformation. The 7M and non-modulated martensites Ni{sub 50}Mn{sub 30}Ga{sub 20} possess similar saturation magnetizations and Curie temperatures. The non-modulated martensite was estimated to have a lower free energy than 7M, and should be more stable for a reverse martensitic transformation, leading to a higher austenite start temperature A{sub s}, which is consistent with the experimental result.

  1. Diversity of Mn oxides produced by Mn(II)-oxidizing fungi

    Energy Technology Data Exchange (ETDEWEB)

    Santelli, Cara M.; Webb, Samuel M.; Dohnalkova, Alice; Hansel, Colleen M.

    2011-02-21

    Manganese (Mn) oxides are environmentally abundant, highly reactive mineral phases that mediate the biogeochemical cycling of nutrients, contaminants, carbon, and numerous other elements. Despite the belief that microorganisms (specifically bacteria and fungi) are responsible for the majority of Mn oxide formation in the environment, the impact of microbial species, physiology, and growth stage on Mn oxide formation is largely unresolved. Here, we couple microscopic and spectroscopic techniques to characterize the Mn oxides produced by four different species of Mn(II)-oxidizing Ascomycete fungi (Plectosphaerella cucumerina strain DS2psM2a2, Pyrenochaeta sp. DS3sAY3a, Stagonospora sp. SRC1lsM3a, and Acremonium strictum strain DS1bioAY4a) isolated from acid mine drainage treatment systems in central Pennsylvania. The site of Mn oxide formation varies greatly among the fungi, including deposition on hyphal surfaces, at the base of reproductive structures (e.g., fruiting bodies), and on envisaged extracellular polymers adjacent to the cell. The primary product of Mn(II) oxidation for all species growing under the same chemical and physical conditions is a nanoparticulate, poorly-crystalline hexagonal birnessite-like phase resembling synthetic d-MnO2. The phylogeny and growth conditions (planktonic versus surface-attached) of the fungi, however, impact the conversion of the initial phyllomanganate to more ordered phases, such as todorokite (A. strictum strain DS1bioAY4a) and triclinic birnessite (Stagonospora sp. SRC1lsM3a). Our findings reveal that the species of Mn(II)-oxidizing fungi impacts the size, morphology, and structure of Mn biooxides, which will likely translate to large differences in the reactivity of the Mn oxide phases.

  2. A hierarchical nanostructure consisting of amorphous MnO 2, Mn 3O 4 nanocrystallites, and single-crystalline MnOOH nanowires for supercapacitors

    Science.gov (United States)

    Hu, Chi-Chang; Hung, Ching-Yun; Chang, Kuo-Hsin; Yang, Yi-Lin

    In this communication, a porous hierarchical nanostructure consisting of amorphous MnO 2 (a-MnO 2), Mn 3O 4 nanocrystals, and single-crystalline MnOOH nanowires is designed for the supercapacitor application, which is prepared by a simple two-step electrochemical deposition process. Because of the gradual co-transformation of Mn 3O 4 nanocrystals and a-MnO 2 nanorods into an amorphous manganese oxide, the cycle stability of a-MnO 2 is obviously enhanced by adding Mn 3O 4. This unique ternary oxide nanocomposite with 100-cycle CV activation exhibits excellent capacitive performances, i.e., excellent reversibility, high specific capacitances (470 F g -1 in CaCl 2), high power property, and outstanding cycle stability. The highly porous microstructures of this composite before and after the 10,000-cycle CV test are examined by means of scanning electron microscopy (SEM) and transmission electron microscopy (TEM).

  3. Role of multiprotein bridging factor 1 in archaea: bridging the domains?

    NARCIS (Netherlands)

    Koning, de B.; Blombach, F.; Wu Hao,; Brouns, S.J.J.; Oost, van der J.

    2009-01-01

    MBF1 (multiprotein bridging factor 1) is a highly conserved protein in archaea and eukaryotes. It was originally identified as a mediator of the eukaryotic transcription regulator BmFTZ-F1 (Bombyx mori regulator of fushi tarazu). MBF1 was demonstrated to enhance transcription by forming a bridge bet

  4. Micromechanical model of cross-over fibre bridging - Prediction of mixed mode bridging laws

    DEFF Research Database (Denmark)

    Sørensen, Bent F.; Gamstedt, E.K.; Østergaard, Rasmus Christian;

    2008-01-01

    The fracture resistance of fibre composites can be greatly enhanced by crack bridging. In situ observations of mixed mode crack growth in a unidirectional carbon-fibre/epoxy composite reveal crack bridging by single fibres and by beam-like ligaments consisting of several fibres. Based on the obse...

  5. Crystal Structure and Characterization of a New Mixed-valence Manganese(Ⅲ/Ⅳ) Complex: [Mn2(cyclen)2(μ-O)2](ClO4)3-4H2O

    Institute of Scientific and Technical Information of China (English)

    任颜卫; 李珺; 张逢星; 张金花; 郭惠

    2005-01-01

    The mixed-valence manganese(Ⅲ/Ⅳ) complex [Mn2(cyclen)2(μ-O)2](ClO4)3-4H2O (1) (cyclen=1,4,7,10-tetraazacyclododecan) with chemical formula C16H48Cl3Mn2N8O18 has been synthesized and characterized by single crystal X-ray diffraction analysis, elemental analysis, IR and electronic spectra. The results showed that the manganese(Ⅲ/Ⅳ) ions were six-coordinated by four nitrogen atoms from cyclen and two oxygen atoms from the oxygen bridge, forming a distorted octahedron geometry. There were two very strong peaks in the range of 400-700 nm in electronic spectrum, which was similar to Mn catalase and Mn ribonucleotide reductase extracted from organisms.Electrochemical study indicated that the complex underwent a quasi-reversible one-electron reduction and oxidation at E1/2=0.827 V in acetonitrile.

  6. New quantum tunneling steps in Mn11Cr/Mn12 mixed crystal

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    Magnetic properties of Mn11Cr and Mn12 mixed crystal at low temperature are studied.A new set of quantum tunneling steps discovered in magnetization curves suggests that there may exist another kind of single molecular magnet in this mixed crystal.

  7. Comprehensive Real-Time Bridge Health Monitoring System of Tongtai Bridge

    Directory of Open Access Journals (Sweden)

    Lei Su-su

    2015-01-01

    Full Text Available Tongtai Bridge is the world’s largest suspension curve-girder-skew-arch bridge, which is located in Zhangjiakou, China. The understanding of mechanics characteristics is limited to such complex bridges, so it is necessary to establish reliable health monitoring system to investigate the static and dynamic responses and monitor the safety of the bridge. A comprehensive real-time bridge health monitoring system is establish, which includes four aspects: sensor system, data acquisition and transmission system, data processing and control system, structure early warning and security assessment system. The paper systematically describes the system design principles, sensor layout, and monitoring content, then expounds system integration and function of each subsystem.

  8. Influence of Mn Content and Hot Deformation on Transformation Behavior of C-Mn Steels

    Institute of Scientific and Technical Information of China (English)

    LI Long; DING Hua; DU Lin-xiu; WEN Jing-lin; SONG Hong-mei; ZHANG Pi-jun

    2008-01-01

    The hot deformation behaviors and the microstructural evolution of plain C-Mn steels with similar contents of C and Si but different contents of Mn have been investigated by compressive processing using Gleeble-1500 mechanical simulator. Influence of Mn and hot deformation on continuous cooling transformation of steels has been studied. The experimental results showed that deformation in austenite region accelerated transformation process, and the extent is dependent on the hot deformation and cooling conditions. The hot deformation would promote transformation process, but the increase of transformation temperature is dependent on Mn contents. The results have also shown that the effect of deformation on ferrite transformation becomes more obvious with the increase of Mn content at relatively low cooling rate.

  9. Application of Soliton Theory to the Construction of Isometric Immersions of Mn1(C1) × Mn2(c2) into Constant Curvature Spaces Mn(±1)

    Institute of Scientific and Technical Information of China (English)

    Jian Hua CHEN

    2002-01-01

    In this paper, we apply the soliton theory to the case of isometric immersion in differentialgeometry and obtain a family of isometric immersions from Mn1 (c1) × Mn2 (c2) to space forms Mn(c)by introducing 2-parameter loop algebra.

  10. A probabilistic bridge safety evaluation against floods.

    Science.gov (United States)

    Liao, Kuo-Wei; Muto, Yasunori; Chen, Wei-Lun; Wu, Bang-Ho

    2016-01-01

    To further capture the influences of uncertain factors on river bridge safety evaluation, a probabilistic approach is adopted. Because this is a systematic and nonlinear problem, MPP-based reliability analyses are not suitable. A sampling approach such as a Monte Carlo simulation (MCS) or importance sampling is often adopted. To enhance the efficiency of the sampling approach, this study utilizes Bayesian least squares support vector machines to construct a response surface followed by an MCS, providing a more precise safety index. Although there are several factors impacting the flood-resistant reliability of a bridge, previous experiences and studies show that the reliability of the bridge itself plays a key role. Thus, the goal of this study is to analyze the system reliability of a selected bridge that includes five limit states. The random variables considered here include the water surface elevation, water velocity, local scour depth, soil property and wind load. Because the first three variables are deeply affected by river hydraulics, a probabilistic HEC-RAS-based simulation is performed to capture the uncertainties in those random variables. The accuracy and variation of our solutions are confirmed by a direct MCS to ensure the applicability of the proposed approach. The results of a numerical example indicate that the proposed approach can efficiently provide an accurate bridge safety evaluation and maintain satisfactory variation. PMID:27386269

  11. Natural vibration dynamics of Rainbow Bridge, Utah

    Science.gov (United States)

    Moore, J. R.; Thorne, M. S.; Wood, J. R.; Doyle, S.; Stanfield, E.; White, B.

    2015-12-01

    We measured resonant frequencies of Rainbow Bridge, Utah, one of the world's longest rock spans, during a field experiment recording ambient vibration data. Measurements were generated over 20 hours on March 23-24, 2015 using two broadband three-component seismometers placed on the bridge, and compared to concurrent data from nearby reference stations 20 and 220 m distant. We identified seven distinct modes of vibration for Rainbow Bridge between 1 and 6 Hz. Data for each resonant frequency was then analyzed to determine the frequency-dependent polarization vector in an attempt to clarify mode shapes; e.g. the fundamental mode represents out-of-plane horizontal flexure. We compared experimental data to results of 3D numerical modal analysis, using a new photogrammetric model of Rainbow Bridge generated in this study imported into COMSOL Multiphysics. Results compare well with measured data for seven of the first eight modeled modes, matching vibrational frequencies and polarization orientations generally within 10%. Only predicted mode 6 was not explicitly apparent in our experimental data. Large site-to-reference spectral ratios resolved from experimental data indicate high amplification on the bridge as compared to nearby bedrock.

  12. Bridges in the random-cluster model

    Directory of Open Access Journals (Sweden)

    Eren Metin Elçi

    2016-02-01

    Full Text Available The random-cluster model, a correlated bond percolation model, unifies a range of important models of statistical mechanics in one description, including independent bond percolation, the Potts model and uniform spanning trees. By introducing a classification of edges based on their relevance to the connectivity we study the stability of clusters in this model. We prove several exact relations for general graphs that allow us to derive unambiguously the finite-size scaling behavior of the density of bridges and non-bridges. For percolation, we are also able to characterize the point for which clusters become maximally fragile and show that it is connected to the concept of the bridge load. Combining our exact treatment with further results from conformal field theory, we uncover a surprising behavior of the (normalized variance of the number of (non-bridges, showing that it diverges in two dimensions below the value 4cos2⁡(π/3=0.2315891⋯ of the cluster coupling q. Finally, we show that a partial or complete pruning of bridges from clusters enables estimates of the backbone fractal dimension that are much less encumbered by finite-size corrections than more conventional approaches.

  13. Magnetic fields of HgMn stars

    CERN Document Server

    Hubrig, S; Ilyin, I; Korhonen, H; Schoeller, M; Savanov, I; Arlt, R; Castelli, F; Curto, G Lo; Briquet, M; Dall, T H

    2012-01-01

    The frequent presence of weak magnetic fields on the surface of spotted late-B stars with HgMn peculiarity in binary systems has been controversial during the two last decades. We re-analyse available spectropolarimetric material by applying the moment technique on spectral lines of inhomogeneously distributed elements separately. Furthermore, we present new determinations of the mean longitudinal magnetic field for the HgMn star HD65949 and the hotter analog of HgMn stars, the PGa star HD19400, using FORS2 installed at the VLT. We also give new measurements of the eclipsing system AR Aur with a primary star of HgMn peculiarity which were obtained with the SOFIN spectropolarimeter installed at the Nordic Optical Telescope. We downloaded from the ESO archive the publically available HARPS spectra for eight HgMn stars and one normal and one superficially normal B-type star obtained in 2010. The application of the moment technique to the HARPS and SOFIN spectra allowed us to study the presence of the longitudina...

  14. Unusual magnetic phases in MnCo ultrathin alloy films

    International Nuclear Information System (INIS)

    For over a quarter century the Mn : Co magnetic phase diagram has been controversial. We find that for Mn : Co ultrathin alloys with dilute Mn concentration, the Mn and Co moments are coupled parallel for dilute Mn concentrations using X-ray magnetic circular dichroism (XMCD), in contradistinction to the latest accepted bulk results using neutron scattering. To determine if the parallel coupling was the result of epitaxial strain, surface or interface effects, we also performed measurements on very thick films of the same compositions. XMCD shows that thick film Mn : Co alloys have identical magnetic coupling as ultrathin films. (Copyright (c) 1999 Elsevier Science B.V., Amsterdam. All rights reserved.)

  15. Fast Hough transform for automatic bridge extraction

    Science.gov (United States)

    Hao, Qiwei; Chen, Xiaomei; Ni, Guoqiang; Zhang, Huaili

    2008-03-01

    In this paper, a new method to recognize bridge in the complicated background is presented. The algorithm takes full advantages of the characteristics of the bridge image. Firstly, the image is preprocessed and the object edges are extracted. Then according to the limitations of traditional Hough transform (HT), the extraction method of the image line segment characteristic of HT is improved, which eliminates spurious peaks on the basis of global and local thresholds, discriminates the position relation between two straight line segments, and merges segments with near endpoints, etc. Experiments show that this algorithm is more precise and efficient than traditional HT, moreover it can provide a complete description of the bridge in a complicated background.

  16. MINERAL BRIDGES OF NACRE AND ITS EFFECTS

    Institute of Scientific and Technical Information of China (English)

    宋凡; 白以龙

    2001-01-01

    Nacre, or mother-of-pearl, is a kind of composites of aragonite platelets sandwiched between organic materials. Its excellent mechanical properties are thought to stem from the microarchitecture that is traditionally described as a "brick and mortar" arrangement. In this paper, a new microstructure, referred to as mineral bridge in the biomineralization, is directly observed in the organic matrix layers (mortar) of nacre. This is an indication that the organic matrix layer of nacre should be treated as a three-dimensional interface and the microarchitecture of nacre ought to be considered as a "brick-bridge-mortar" structure rather than the traditional one. Experiments and analyses show that the mineral bridges not only improve the mechanical properties of the organic matrix layers but also play an important role in the pattern of the crack extension in nacre.

  17. MULTIPHASE BLASTING OF THE BRIDGE ACROSS THE DRENICA RIVER

    OpenAIRE

    Branko Božić

    1989-01-01

    The construction of new bridges on the sites of the existing ones require demolition of the old bridge. Due to closeness of newly erected bridge elements the fundations of old bridges are demolished by multiphase blasting process. The blasting of the piers and anchorages of the bridge across 'the Drenica river carrying the Balačevac—Goleš industrial railway was done in four phases. The piers and anchorages of a new bridge and its construction elements have been erected before (the paper is pu...

  18. Bridging radiation policy and science

    International Nuclear Information System (INIS)

    Scientists, regulators, and policy makers from five continents and 20 countries reached consensus on a number of conclusions and recommendations regarding low-level ionizing radiation exposures at an international conference, 'Bridging Radiation Policy and Science,' at the Airlie Center in Warrenton, Virginia, 1-5 December 1999. The goal of the conference was to develop strategies for formulating national and international policy based on current scientific information in the context of economic, political, and social concerns. Specifically, attendees explored how to establish public policies with respect to radiation protection in view of the scientific uncertainties of the effects of low-level radiation [<100 millisievert (mSv)]. Conference participants agreed that science will not likely answer in the near future fundamental questions about the shape of the dose-response curve and mechanisms of effects of radiation at low doses. The conference endorsed the quest for a prudent and coherent radiation policy based on the International Atomic Energy Agency's (IAEA) 'evolving global framework'. The Conference participants agreed upon the following recommendations: Policy discussions on the regulation of radiation sources delivering low-level radiation should include references to natural background radiation. The conference supports the evolving global framework of the International Atomic Energy Agency (IAEA) for the safe use of radiation. The conference supports further development and evaluation of the ideas associated with the proposal on controllable dose. No radiation dose is below regulatory concern but certain levels should be below regulatory action, and appropriate dose levels should be established. Fundamental questions about the shape of the dose-response curve and mechanisms of effects of radiation at low doses are unlikely to be answered in the near future. Scientific research, including molecular and cellular radiobiology studies are critical in order

  19. Extracorporeal Life Support Bridge to Ventricular Assist Device: The Double Bridge Strategy.

    Science.gov (United States)

    Marasco, Silvana F; Lo, Casey; Murphy, Deirdre; Summerhayes, Robyn; Quayle, Margaret; Zimmet, Adam; Bailey, Michael

    2016-01-01

    In patients requiring left ventricular assist device (LVAD) support, it can be difficult to ascertain suitability for long-term mechanical support with LVAD and eventual transplantation. LVAD implantation in a shocked patient is associated with increased morbidity and mortality. Interest is growing in the utilization of extracorporeal life support (ECLS) as a bridge-to-bridge support for these critically unwell patients. Here, we reviewed our experience with ECLS double bridging. We hypothesized that ECLS double bridging would stabilize end-organ dysfunction and reduce ventricular assist device (VAD) implant perioperative mortality. We conducted a retrospective review of prospectively collected data for 58 consecutive patients implanted with a continuous-flow LVAD between January 2010 and December 2013 at The Alfred Hospital, Melbourne, Victoria, Australia. Twenty-three patients required ECLS support pre-LVAD while 35 patients underwent LVAD implantation without an ECLS bridge. Preoperative morbidity in the ECLS bridge group was reflected by increased postoperative intensive care duration, blood loss, blood product use, and postoperative renal failure, but without negative impact upon survival when compared with the no ECLS group. ECLS stabilization improved end-organ function pre-VAD implant with significant improvements in hepatic and renal dysfunction. This series demonstrates that the use of ECLS bridge to VAD stabilizes end-organ dysfunction and reduces VAD implant perioperative mortality from that traditionally reported in these "crash and burn" patients.

  20. The seismic response of concrete arch bridges (with focus on the Bixby Creek bridge Carmel, California)

    Energy Technology Data Exchange (ETDEWEB)

    Hoehler, M; McCallen, D; Noble, C

    1999-06-01

    The analysis, and subsequent retrofit, of concrete arch bridges during recent years has relied heavily on the use of computational simulation. For seismic analysis in particular, computer simulation, typically utilizing linear approximations of structural behavior, has become standard practice. This report presents the results of a comprehensive study of the significance of model sophistication (i.e. linear vs. nonlinear) and pertinent modeling assumptions on the dynamic response of concrete arch bridges. The study uses the Bixby Creek Bridge, located in California, as a case study. In addition to presenting general recommendations for analysis of this class of structures, this report provides an independent evaluation of the proposed seismic retrofit for the Bixby Creek Bridge. Results from the study clearly illustrate a reduction of displacement drifts and redistribution of member forces brought on by the inclusion of material nonlinearity. The analyses demonstrate that accurate modeling of expansion joints, for the Bixby Creek Bridge in particular, is critical to achieve representative modal and transient behavior. The inclusion of near-field displacement pulses in ground motion records was shown to significantly increase demand on the relatively softer, longer period Bixby Creek Bridge arch. Stiffer, shorter period arches, however, are more likely susceptible to variable support motions arising from the canyon topography typical for this class of bridges.

  1. V. Tormis: "Bridge of Song / Brian Hunt

    Index Scriptorium Estoniae

    Hunt, Brian

    1997-01-01

    Uuest heliplaadist "V. Tormis: "Bridge of Song" - Bridge of Song; Singing aboard ship; Brides Farewell; Kihnu Island Wedding Songs; 17 Estonian Wedding Songs; Three Estonian Game Songs; Four Estonian Lullabies. Estonian Radio Choir / Toomas Kapten. Finlandia 4509 96937-2; 56:52 DDD; "People of Kalevala" - God protect us from war; Vespian Winter; Eagle Flew From the North East; Plague Memory; Vainamoinen's Words of Wisdom; The Seventeenth Rune of Kalevala. National Male Choir of Estonia. Finlandia 0630 12245-2; 56:52 DDD

  2. Stability of a liquid bridge under vibration

    Science.gov (United States)

    Benilov, E. S.

    2016-06-01

    We examine the stability of a vertical liquid bridge between two vertically vibrating, coaxial disks. Assuming that the vibration amplitude and period are much smaller than the mean distance between the disks and the global timescale, respectively, we employ the method of multiple scales to derive a set of asymptotic equations. The set is then used to examine the stability of a bridge of an almost cylindrical shape. It is shown that, if acting alone, gravity is a destabilizing influence, whereas vibration can weaken it or even eliminate altogether. Thus, counter-intuitively, vibration can stabilize an otherwise unstable capillary structure.

  3. ParB spreading requires DNA bridging

    OpenAIRE

    Graham, Thomas G. W.; Wang, Xindan; Song, Dan; Etson, Candice M.; van Oijen, Antoine M.; Rudner, David Z.; Loparo, Joseph J.

    2014-01-01

    The bacterial parABS system is employed for plasmid partitioning and chromosome segregation. ParB binds to parS sites and associates with broad regions of adjacent DNA, a phenomenon known as spreading. However, the molecular basis for spreading is unknown. Using single-molecule approaches, Graham et al. demonstrate DNA bridging by B. subtilis ParB (Spo0J). Spo0J mutations that disrupt DNA bridging lead to defective spreading and SMC condensin complex recruitment. This study suggests a novel, ...

  4. Germanium-overcoated niobium Dayem bridges

    Science.gov (United States)

    Holdeman, L. B.; Peters, P. N.

    1976-01-01

    Overcoating constriction microbridges with semiconducting germanium provides additional thermal conductivity at liquid-helium temperatures to reduce the effects of self-heating in these Josephson junctions. Microwave-induced steps were observed in the I-V characteristics of an overcoated Dayem bridge fabricated in a 15-nm-thick niobium film; at least 20 steps could be counted at 4.2 K. No steps were observed in the I-V characteristics of the bridge prior to overcoating. In addition, the germanium overcoat can protect against electrical disturbances at room temperature.

  5. Ambient Vibration Test on Reinforced Concrete Bridges

    Directory of Open Access Journals (Sweden)

    Idris Nurul Shazwin

    2016-01-01

    Full Text Available An investigation was carried out to determine dynamic characteristic of reinforced concrete (RC bridges by using ambient vibration test (AVT. The ambient vibration sources on bridges may come from traffic, wind, wave motion and seismic events. AVT describes the dynamic characteristics of the bridge and ground by measuring the natural frequencies using highly sensitive seismometer sensor. This test is beneficial due to light weight equipment and smaller number of operator required, cheap and easy to be handled. It is able to give a true picture of the bridge dynamic behavior without any artificial force excitation when vibration data is recorded. A three-span reinforced concrete bridge located in Sri Medan, Batu Pahat, Johor was measured by using microtremor equipment consist of three units of 1 Hz eigenfrequency passive sensors used in this test was performed in normal operating condition without excitation required from any active sources or short period noise perturbations. Ten measurements were conducted on the bridge deck and ten measurements on the ground surface in order to identify the natural frequencies of the bridge. Several peak frequencies were identified from three components of Fourier Amplitude Spectra (FAS in transverse (North-South, longitudinal (East-West and vertical (Up-Down direction as well as squared average Horizontal to Vertical Spectral Ratio (HVSR of ground response, computed by using Geopsy software. From the result, it was expected the bridge have five vibration modes frequencies in the range of 1.0 Hz and 7.0 Hz with the first two modes in the transverse and longitudinal direction having a frequency 1.0 Hz, the third mode is 2.2 Hz in transverse direction, fourth and fifth mode is 5.8 Hz and 7.0 Hz. For ground natural frequencies are in range 1.0 Hz to 1.3 Hz for North-South direction and 1.0 Hz to 1.6 Hz for East-West direction. Finally the results are compared with several empirical formulas for simple

  6. A Bridge Deflection Monitoring with GPS

    Science.gov (United States)

    Figurski, M.; Gałuszkiewicz, M.; Wrona, M.

    2007-01-01

    This paper introduces results of investigation carried on by The Applied Geomatics Section in Military University of Technology. Research includes possibilities of monitoring dynamic behavior of a bridge using high rate GPS data. Whole event was executed with collaboration of The Road and Bridge Management and The Warsaw Geodesy Company. Interdisciplinary approach with this project allows authors to get reliable information about investigating constructions and their respond for true traffic loading detected by GPS receivers. Way of compute data and used software (TRACK) are also shown in this paper.

  7. Planar Hall effect bridge magnetic field sensors

    DEFF Research Database (Denmark)

    Henriksen, A.D.; Dalslet, Bjarke Thomas; Skieller, D.H.;

    2010-01-01

    Until now, the planar Hall effect has been studied in samples with cross-shaped Hall geometry. We demonstrate theoretically and experimentally that the planar Hall effect can be observed for an exchange-biased ferromagnetic material in a Wheatstone bridge topology and that the sensor signal can...... be significantly enhanced by a geometric factor. For the samples in the present study, we demonstrate an enhancement of the sensor output by a factor of about 100 compared to cross-shaped sensors. The presented construction opens a new design and application area of the planar Hall effect, which we term planar...... Hall effect bridge sensors....

  8. Planar Hall effect bridge magnetic field sensors

    Science.gov (United States)

    Henriksen, A. D.; Dalslet, B. T.; Skieller, D. H.; Lee, K. H.; Okkels, F.; Hansen, M. F.

    2010-07-01

    Until now, the planar Hall effect has been studied in samples with cross-shaped Hall geometry. We demonstrate theoretically and experimentally that the planar Hall effect can be observed for an exchange-biased ferromagnetic material in a Wheatstone bridge topology and that the sensor signal can be significantly enhanced by a geometric factor. For the samples in the present study, we demonstrate an enhancement of the sensor output by a factor of about 100 compared to cross-shaped sensors. The presented construction opens a new design and application area of the planar Hall effect, which we term planar Hall effect bridge sensors.

  9. “On a bridge in Berlin”

    DEFF Research Database (Denmark)

    Pihl, Ole Verner

    2013-01-01

    that jumps in time and place: it begins with Martin Heidegger´s quotation “The Bridge gathers to itself in its own way earth and sky, divinities and mortals”, and the bridge is a state of mind, a chronotope, a portal in time between past, present, and future. The methodological approach is based...... on Bachelard and Heidegger. This GN investigates how architecture changes our cities and cultural identity. It merges different narrative time layers as: childhood memories, dreams, hallucinations, fiction, past, present, and future. The findings of this paper explains why a cross disciplinary approach...

  10. Composite timber-concrete road bridge structure

    Directory of Open Access Journals (Sweden)

    Stojić Dragoslav

    2007-01-01

    Full Text Available This work presents preliminary design of the road bridge made of laminated timber. The supporting system of the main bearing elements is made of the laminated timber in the system of arch with three joints; the bridge slab is designed as continuous slab, made of nine equal fields; each pair is made as composite timber-concrete beam, where the road slab is made of concrete and the needle pieces are made of timber. Fundament is based on HW piles. All the elements are designed to Eurocode.

  11. Ca3Mn2O7.

    Science.gov (United States)

    Guiblin, Nicolas; Grebille, Dominique; Leligny, Henri; Martin, Christine

    2002-01-01

    The tricalcium dimanganese heptaoxide (Ca3Mn2O7) member of the Ruddlesden-Popper series Ca(n+1)Mn(n)O(3n+1), i.e. with n = 2, was previously reported with an I-centred tetragonal lattice [a(t) = 3.68 and c(t) = 19.57 A] by Fawcett, Sunstrom, Greenblatt, Croft & Ramanujachary [Chem. Mater. (1998), 10, 3643-3651]. It is now found to be orthorhombic, with an A-centred lattice [a = 5.2347 (6), b = 5.2421 (2) and c = 19.4177 (19) A]. The structure has been refined in space group A2(1)am using X-ray single-crystal diffraction data and assuming the existence of twin domains related by the (1-10) plane. A comparison with the basic perovskite structure CaMnO3 (n = infinity) is proposed.

  12. BSA与α-MnO2及δ-MnO2间的界面吸附作用%The adsorption of BSA on the surfaces of α-MnO2 and δ-MnO2

    Institute of Scientific and Technical Information of China (English)

    蔡爱军; 马子川; 刘敬泽

    2007-01-01

    比较研究了牛血清白蛋白(BSA)与α-MnO2和δ-MnO2的界面吸附作用及其影响因素.结果表明,BSA在两种MnO2颗粒物表面有明显的吸附,且δ-MnO2比α-MnO2对BSA的吸附能力略强.pH3.8~8.0范围内,BSA在α-MnO2和δ-MnO2上的吸附率随pH的升高而减小,pH3.8条件下,α-MnO2上的吸附率为88.2%,δ-MnO2上的吸附率为94.0%.BSA在α-MnO2和δ-MnO2上的吸附量均随BSA浓度的增加而增大,吸附率随NaCl浓度的增加而减小.BSA在α-MnO2上的吸附具有很高的不可逆性,δ-MnO2上的吸附完全不可逆.吸附过程中BSA发生解螺旋作用,引起结构熵增大.

  13. Mn-induced modifications of Ga 3d photoemission from (Ga, Mn)As: evidence for long range effects.

    Science.gov (United States)

    Kanski, J; Ulfat, I; Ilver, L; Leandersson, M; Sadowski, J; Karlsson, K; Pal, P

    2012-10-31

    Using synchrotron based photoemission, we have investigated the Mn-induced changes in Ga 3d core level spectra from as-grown Ga(1-x)Mn(x)As. Although Mn is located in Ga substitutional sites, and therefore does not have any Ga nearest neighbors, the impact of Mn on the Ga core level spectra is pronounced even at Mn concentrations in the region of 0.5%. The analysis shows that each Mn atom affects a volume corresponding to a sphere with around 1.4 nm diameter.

  14. Lattice Expansion of (Ga,Mn)As: The Role of Substitutional Mn and of the Compensating Defects

    OpenAIRE

    J. Masek; Maca, F.

    2005-01-01

    We apply the density-functional technique to determine the lattice constant of GaAs supercells containing Mn_Ga, Mn_int, and As_Ga impurities, and use a linear interpolation to describe the dependence of the lattice constant a of Ga_{1-x}Mn_xAs on the concentrations of these impurities. The results of the supercell calculations confirm that Mn_Ga does not contribute to the lattice expansion. The increase of a is due to both Mn_int and As_Ga, that are both created in the as-grown (Ga,Mn)As in ...

  15. The preferred orientation of Mn3 spins in magnetic multiferroic CaMn7O12

    Science.gov (United States)

    Dai, Jian-Qing; Zhang, Hu; Song, Yu-Min

    2015-12-01

    The remarkable ferroelectricity in CaMn7O12 originates from the helicoidal spin spiral, in which the Mn3 (3b Wyckoff position) spin direction remains controversial. In this paper, the total energy, phase transition path, and spontaneous polarization of CaMn7O12 are investigated by using first-principle methods. We show that, in order to account for the giant electric polarization and the correct phase transition sequence, the relative orientation between the spins of Mn3 and Mn2 (9d Wyckoff position) sites with the same coordinate along the hexagonal c-axis can not be antiparallel, i.e. their relative orientation angle should be ϕ≈0.84π instead of ϕ=π. The most likely reason for the observation of ϕ=π can be attributed to the withdrawal of spin-orbital coupling between the Mn2 and Mn3 spins, which is caused by doping Cu2+ in the samples for neutron powder diffraction measurements.

  16. Lattice expansion, stability, and Mn solubility in substitutionally Mn-doped GaAs

    Science.gov (United States)

    Nakamura, Kohji; Hatano, Keishi; Akiyama, Toru; Ito, Tomonori; Freeman, A. J.

    2007-05-01

    The structural properties and stability of zinc-blende GaxMn1-xAs over the whole Mn composition range are studied by means of the highly precise full-potential linearized augmented plane-wave method and the Connolly-Williams cluster expansion method, within the local-density approximation (LDA), generalized gradient approximation (GGA), and LDA+U . In contrast to LDA and GGA predictions, the calculated LDA+U lattice constant is found to increase when the Mn composition increases, even in the case that the Mn atoms substitutionally occupy cation sites, due to the correlation correction of the pd hybridization strength between the Mn3d bands and the As4p valence bands, which agrees with recent experimental findings. In addition, we confirm that the system has a tendency to segregate into GaAs and MnAs, and so inherently favors clustering. A temperature-composition phase diagram is obtained with the mean-field approximation for the entropy, in which the Mn solubility into GaAs is found to be very low at low temperatures (˜300°C) .

  17. Magnetism of carbon doped Mn5Si3 and Mn5Ge3 films

    Indian Academy of Sciences (India)

    C Sürgers; K Potzger; G Fischer

    2009-03-01

    The magnetic properties of Mn5Si3C and Mn5Ge3C films prepared by magnetron cosputtering or C+-ion implantation are studied. The carbon-doped films exhibit ferromagnetic properties with Curie temperatures C well above room temperature and metallic conductivity, making them possible candidates for future magnetic semiconductor-based devices. In Mn5Si3C, the carbon gives rise to a lattice expansion and a concomitant change of the magnetic order from antiferromagnetic Mn5Si3 to ferromagnetic Mn5Si3C0.8 with C = 350 K. Likewise, C of ferromagnetic Mn5Ge3 is strongly enhanced in Mn5Ge3C0.8. However, in this case the lattice is slightly compressed by carbon. This demonstrates that the effect of carbon on the magnetic behaviour in these compounds is not simply due to a change of the various interatomic distances by carbon but also due to a modification of the electronic band structure.

  18. Room Temperature Ferromagnetic Mn:Ge(001

    Directory of Open Access Journals (Sweden)

    George Adrian Lungu

    2013-12-01

    Full Text Available We report the synthesis of a room temperature ferromagnetic Mn-Ge system obtained by simple deposition of manganese on Ge(001, heated at relatively high temperature (starting with 250 °C. The samples were characterized by low energy electron diffraction (LEED, scanning tunneling microscopy (STM, high resolution transmission electron microscopy (HRTEM, X-ray photoelectron spectroscopy (XPS, superconducting quantum interference device (SQUID, and magneto-optical Kerr effect (MOKE. Samples deposited at relatively elevated temperature (350 °C exhibited the formation of ~5–8 nm diameter Mn5Ge3 and Mn11Ge8 agglomerates by HRTEM, while XPS identified at least two Mn-containing phases: the agglomerates, together with a Ge-rich MnGe~2.5 phase, or manganese diluted into the Ge(001 crystal. LEED revealed the persistence of long range order after a relatively high amount of Mn (100 nm deposited on the single crystal substrate. STM probed the existence of dimer rows on the surface, slightly elongated as compared with Ge–Ge dimers on Ge(001. The films exhibited a clear ferromagnetism at room temperature, opening the possibility of forming a magnetic phase behind a nearly ideally terminated Ge surface, which could find applications in integration of magnetic functionalities on semiconductor bases. SQUID probed the co-existence of a superparamagnetic phase, with one phase which may be attributed to a diluted magnetic semiconductor. The hypothesis that the room temperature ferromagnetic phase might be the one with manganese diluted into the Ge crystal is formulated and discussed.

  19. Magnetic properties of MnBi based alloys: First-principles calculations for MnBi-Co and MnBi-Co-Fe cases

    Directory of Open Access Journals (Sweden)

    Yang-Ki Hong

    2013-05-01

    Full Text Available First-principles calculations of fundamental magnetic properties were performed for ordered MnBi, MnBi-Co, and MnBi-Co-Fe alloys to evaluate maximum energy product (BHmax. Full potential linear-augmented plane wave (FLAPW and linear-muffin-tin-orbital (LMTO calculations using density functional theory (DFT within the local spin density approximation (LSDA were used and found to give a reasonable description of saturation magnetization (Ms, effective anisotropy constant (Keff, and Curie temperature (Tc for NiAs-structured MnBi crystal. We found that upon addition of Co, the Ms and Keff increased, while Tc reduced. The magnetic anisotropy changed from weak anisotropy easy plane for MnBi to the strong easy axis anisotropy for MnBi-Co and MnBi-Co-Fe.

  20. Cosmic ray half life of 54Mn

    International Nuclear Information System (INIS)

    A search for the β+ decay of 54Mn has established an upper limit of 4.4 x 10-8 for this branching ratio, and a lower limit of 13.3 for the log ft value for this second forbidden unique transition. Assuming that the β- decay branch has the same log ft value, then its partial half life must be greater than 4 x 104 years. Experiments to directly measure the β- decay rate of 54Mn are now in progress. 6 refs., 2 figs

  1. Characterization of Mn-resistant endophytic bacteria from Mn-hyperaccumulator Phytolacca americana and their impact on Mn accumulation of hybrid penisetum.

    Science.gov (United States)

    Zhang, Wen-Hui; Chen, Wei; He, Lin-Yan; Wang, Qi; Sheng, Xia-Fang

    2015-10-01

    Three hundred Mn-resistant endophytic bacteria were isolated from the Mn-hyperaccumulator, Phytolacca americana, grown at different levels of Mn (0, 1, and 10mM) stress. Under no Mn stress, 90%, 92%, and 11% of the bacteria produced indole acetic acid (IAA), siderophore, and 1-aminocyclopropane-1-carboxylate (ACC) deaminase, respectively. Under Mn stress, 68-94%, 91-92%, and 21-81% of the bacteria produced IAA, siderophore, and ACC deaminase, respectively. Greater percentages of ACC deaminase-producing bacteria were found in the Mn-treated P. americana. Furthermore, the ratios of IAA- and siderophore-producing bacteria were significantly higher in the Mn treated plant leaves, while the ratio of ACC deaminase-producing bacteria was significantly higher in the Mn treated-roots. Based on 16S rRNA gene sequence analysis, Mn-resistant bacteria were affiliated with 10 genera. In experiments involving hybrid penisetum grown in soils treated with 0 and 1000mgkg(-1) of Mn, inoculation with strain 1Y31 was found to increase the root (ranging from 6.4% to 18.3%) and above-ground tissue (ranging from 19.3% to 70.2%) mass and total Mn uptake of above-ground tissues (64%) compared to the control. Furthermore, inoculation with strain 1Y31 was found to increase the ratio of IAA-producing bacteria in the rhizosphere and bulk soils of hybrid penisetum grown in Mn-added soils. The results showed the effect of Mn stress on the ratio of the plant growth-promoting factor-producing endophytic bacteria of P. americana and highlighted the potential of endophytic bacterium as an inoculum for enhanced phytoremediation of Mn-polluted soils by hybrid penisetum plants. PMID:26114256

  2. Detailed magnetic study on the formato-bridged MOFs with anion-tunable magnetic properties

    Institute of Scientific and Technical Information of China (English)

    WANG XinYi; WANG ZheMing; GAO Song

    2012-01-01

    Detailed studies of the structures,magnetic properties and photodimerization of a series of formato-bridged MOFs with the general formula M2(HCOO)3(4,4'-bpe)3(H20)3(X)(4,4'-bpe =4,4'-bipyridylethylene,M =Mn(l-X-),X- =CIO-4,NO-3,BF-4,I-,Br-; M =Co(2-X-),X- =CIO-4,NO-3; M =Zn(3-X-),X- =NO-3)were reported.Careful magnetic measurements on an oriented single crystal of 1-ClO-4 determined the spin-flop magnetic phase diagram and some intrinsic parameters,such as the intralayer coupling J,the anisotropy field HA and the exchange field HE.Different anions can remarkably tune the magnetic properties of l-X-,especially the critical fields of the spin-flop transition.Compound 2-ClO-4 remained paramagnetic down to 2 K.

  3. Influence of Mn ions concentration on optical and magnetic properties of Mn-doped ZnS nanowires

    Science.gov (United States)

    Wei, Maobin; Yang, Jinghai; Yan, Yongsheng; Yang, Lili; Cao, Jian; Fu, Hao; Wang, Bingji; Fan, Lin

    2013-08-01

    We successfully synthesized the ZnS:Mn2+ nanowires (NWs) with different Mn2+ doping concentration by the simple hydrothermal method. The optical and magnetic properties can be well tuned by the Mn2+ doping concentration. The yellow-orange emission from the Mn2+ 4T1-6A1 transition can be observed in the PL spectra of ZnS:Mn2+ NWs and the intensity reaches a maximum when the concentration of Mn2+ is 3%. The room-temperature magnetic hysteresis loops of the ZnS:Mn2+ NWs indicate that when the Mn2+ doping concentration is smaller than 3% (x≤3%),the samples exhibit the ferromagnetism characteristics; meanwhile, once the Mn2+ doping concentration is higher than 3% (x>3%), the samples exhibited a ferromagnetism including part paramagnetic characteristics at room-temperature. This variation tendency can be well explained by the competition mechanism between two exchange interactions, i.e. the antiferromagnetic exchange interaction between the near neighbor Mn2+ and Mn2+ ions, and the ferromagnetic exchange interaction between the Mn2+ and Mn2+ ions mediated by their near neighbor S2- ions or native defects such as S vacancies.

  4. Diode-quad bridge for reactive transducers and FM discriminators

    Science.gov (United States)

    Harrison, D. R.; Dimeff, J.

    1972-01-01

    Diode-quad bridge circuit was developed for use with pressure-sensitive capacitive transducers, liquid-level measuring devices, proximity deflection sensors, and inductive displacement sensors. It may also be used as FM discriminator and as universal impedance bridge.

  5. Foot force models of crowd dynamics on a wobbly bridge

    CERN Document Server

    Belykh, Igor; Belykh, Vladamir

    2016-01-01

    Modern pedestrian and suspension bridges are designed using industry-standard packages, yet disastrous resonant vibrations are observed, necessitating multi-million dollar repairs. Recent examples include pedestrian induced vibrations during the openings of the Solf\\'erino Bridge in Paris in 1999 and the increased bouncing of the Squibb Park Bridge in Brooklyn in 2014. The most prominent example of an unstable lively bridge is the London Millennium Bridge which started wobbling as a result of pedestrian-bridge interactions. Pedestrian phase-locking due to footstep phase adjustment, is suspected to be the main cause of its large lateral vibrations; however, its role in the initiation of wobbling was debated. In this paper, we develop foot force models of pedestrians' response to bridge motion and detailed, yet analytically tractable models of crowd phase-locking. We use bio-mechanically inspired models of crowd lateral movement to investigate to what degree pedestrian synchrony must be present for a bridge to ...

  6. Violin bridge mobility analysis under in-plane excitation.

    Science.gov (United States)

    Zhang, Cheng-Zhong; Zhang, Guang-Ming; Ye, Bang-Yan; Liang, Li-Dong

    2013-11-08

    The vibration of a violin bridge is a dynamic contact vibration with two interfaces: strings-bridge, and bridge feet-top plate. In this paper, the mobility of an isolated bridge under in-plane excitation is explored using finite element modeling based on the contact vibration model. Numerical results show that the dynamic contact stiffness in the two contact interfaces has a great impact on the bridge mobility. A main resonance peak is observed in the frequency range of 2-3 kHz in the frequency response of the isolated bridge when the contact stiffness is smaller than a critical threshold. The main resonance peak frequency is affected by the contact stiffness as well. In order to verify the numerical findings, a novel experimental system is then designed on the basis of a piezoelectric dynamometer for bridge mobility analysis. Experimental results confirm the impact of the dynamic contact stiffness on the bridge mobility.

  7. CDC WONDER: Population - Bridged-Race July 1st Estimates

    Data.gov (United States)

    U.S. Department of Health & Human Services — The Population - Bridged-Race July 1st Estimates online databases report bridged-race population estimates of the July 1st resident population of the United States,...

  8. Violin Bridge Mobility Analysis under In-Plane Excitation

    Directory of Open Access Journals (Sweden)

    Cheng-Zhong Zhang

    2013-11-01

    Full Text Available The vibration of a violin bridge is a dynamic contact vibration with two interfaces: strings-bridge, and bridge feet-top plate. In this paper, the mobility of an isolated bridge under in-plane excitation is explored using finite element modeling based on the contact vibration model. Numerical results show that the dynamic contact stiffness in the two contact interfaces has a great impact on the bridge mobility. A main resonance peak is observed in the frequency range of 2–3 kHz in the frequency response of the isolated bridge when the contact stiffness is smaller than a critical threshold. The main resonance peak frequency is affected by the contact stiffness as well. In order to verify the numerical findings, a novel experimental system is then designed on the basis of a piezoelectric dynamometer for bridge mobility analysis. Experimental results confirm the impact of the dynamic contact stiffness on the bridge mobility.

  9. Hydraulic bridges in unsaturated coarse granular media: Influence of bridge size and conductivity on flow through clasts

    Science.gov (United States)

    Jayakody, Jeevan A.; Nicholl, Michael J.

    2016-10-01

    Unsaturated flow in coarse granular media must pass through hydraulic bridges (e.g., pendular water, porous connections) that form a physical connection between adjoining clasts. Previous studies suggest that volumetric flow through a porous clast (Q) will be linearly dependent on the cross-sectional area of the hydraulic bridges, and understate the importance of bridge conductivity. Numerical simulations were performed to explore steady-state flow through a spherical clast with identical bridges located at the top and bottom. The cross-sectional area of the bridges relative to that of the clast (Ar) was varied across six orders of magnitude. The ratio of hydraulic conductivity between bridges and clasts (Kb/Kc) was varied across 12 orders of magnitude to consider resistive, neutral, and conductive bridges. Results show that hydraulic bridges place a primary control on both Q and flux distribution within the clast. For neutral and conductive bridges (Kb/Kc ≥1), Ar is the dominant factor in determining Q, while Kb/Kc is the primary control for resistive bridges (Kb/Kc < 1). For all bridges, Q shows a non-linear dependency on both Ar and Kb/Kc. The intra-clast flow distribution shifts outwards as Ar increases. Conductive bridges promote this process and resistive bridges impede it.

  10. Bridging the digital divide with mobile services

    CERN Document Server

    Yelton, Andromeda

    2013-01-01

    In this issue of Library Technology Reports, Andromeda Yelton shows how libraries can build on the breadth of this population to help bridge the digital divide and provide even greater access to information. Yelton breaks down the demographics of mobile internet users, provides examples of how different libraries are reaching out to these populations, and suggests what the future may hold for this trend.

  11. Circuit bridging of components by smoke

    Energy Technology Data Exchange (ETDEWEB)

    Tanaka, T.J.; Nowlen, S.P.; Anderson, D.J. [Sandia National Labs., Albuquerque, NM (United States)

    1996-10-01

    Smoke can adversely affect digital electronics; in the short term, it can lead to circuit bridging and in the long term to corrosion of metal parts. This report is a summary of the work to date and component-level tests by Sandia National Laboratories for the Nuclear Regulatory Commission to determine the impact of smoke on digital instrumentation and control equipment. The component tests focused on short-term effects such as circuit bridging in typical components and the factors that can influence how much the smoke will affect them. These factors include the component technology and packaging, physical board protection, and environmental conditions such as the amount of smoke, temperature of burn, and humidity level. The likelihood of circuit bridging was tested by measuring leakage currents and converting those currents to resistance in ohms. Hermetically sealed ceramic packages were more resistant to smoke than plastic packages. Coating the boards with an acrylic spray provided some protection against circuit bridging. The smoke generation factors that affect the resistance the most are humidity, fuel level, and burn temperature. The use of CO{sub 2} as a fire suppressant, the presence of galvanic metal, and the presence of PVC did not significantly affect the outcome of these results.

  12. Bridges in Mathematics. WWC Intervention Report

    Science.gov (United States)

    What Works Clearinghouse, 2009

    2009-01-01

    "Bridges in Mathematics," published by the Math Learning Center (MLC), is an elementary school math curriculum covering kindergarten through fifth grade that focuses on problem solving and skill building, and applies a combination of whole-group, small-group, and independent activities. Lessons incorporate visual models, including manipulatives,…

  13. The Memory Bridge Initiative on Service Learners

    Science.gov (United States)

    Wescott, Amy; Healy, Tara C.

    2011-01-01

    This study evaluated the Memory Bridge Initiative (MBI), an educational, experiential program pairing high school students with older adults who have dementia. A qualitative, single group design with baseline and follow-up measures examined whether or not students would have a positive learning experience while gaining newfound appreciation and…

  14. Bridging the Gap: Pracademics in Foreign Policy

    Science.gov (United States)

    Murphy, Ann Marie; Fulda, Andreas

    2011-01-01

    In his seminal work "Bridging the Gap: Theory and Practice in Foreign Policy", Alexander George (1993) lamented the great divide between academia and the foreign policymaking community, arguing that greater interaction between scholars and policymakers would produce better policy. We share George's belief that scholars and practitioners each have…

  15. Ergonomic aspects of automation in navigation bridges

    NARCIS (Netherlands)

    Lazet, A.; Walraven, P.L.

    1971-01-01

    New ergonomic questions arise from the tendency toward increasing automation in maritime operations. Direct control of engines and rudder from the bridge promises improved ship control, provided that the operator can really exploit the technical improvements. To make such direct control most efficie

  16. LPN/ADN Bridge Course. Instructor's Guide.

    Science.gov (United States)

    Barrett, Jan; And Others

    This curriculum guide has been constructed in order to bridge the skills gap between licensed practical nursing (LPN) programs and associate degree nursing (ADN) programs in Missouri. The curriculum was developed through a cooperative effort by persons from both sectors. The curriculum contains four major units, each consisting of several lessons,…

  17. Journaling: A Bridge between School and Home

    Science.gov (United States)

    McGough, Julie

    2013-01-01

    This article describes how first-grade students create meaningful communication with families and help build the student-teacher-parent relationship through journaling. Journals are a useful tool to bridge school and home. A journal can communicate learning goals, develop scientific vocabulary, and create dialogue through oral and written…

  18. 75 FR 41281 - Bridge Safety Standards

    Science.gov (United States)

    2010-07-15

    ... Federal Register at 60 FR 20654, the interim statement included a request for comments to be submitted to... of Agency Policy on the Safety of Railroad Bridges (``policy statement''). See 65 FR 52667. With the... amendment. See 74 FR 157. All aspects of the policy statement that are not incorporated into the...

  19. Heavy Vehicles on Minor Highway Bridges

    DEFF Research Database (Denmark)

    Nielsen, Søren R. K.; Kirkegaard, Poul Henning; Enevoldsen, I.

    The present paper worked out as a part of a research project on "Dynamic amplification factor of vehicle loadings on smaller bridges" establishes a two-dimensional spectral description of the road roughness surface based on measurements from a Danish road using so-called Profilograph used by Dani...

  20. Bridging gaps : ten crosscurrents in media studies

    OpenAIRE

    Fornäs, Johan

    2008-01-01

    The final, definitive version of this paper has been published in: Media, Culture and Society, (30), 6, 895-905, 2008.Johan Fornäs, Bridging Gaps: Ten Crosscurrents in Media Studies.http://dx.doi.org/10.1177/0163443708096811. by SAGE Publications Ltd, All rights reserved. http://www.sagepub.com/

  1. Steel plate reinforcement of orthotropic bridge decks

    NARCIS (Netherlands)

    Teixeira de Freitas, S.

    2012-01-01

    The PhD research is focused on the reinforcement of fatigue cracked orthotropic steel bridge decks (OBD) by adding a second steel plate to the existing deck. The main idea is to stiffen the existing deck plate, which will reduce the stresses at the fatigue sensitive details and extend the fatigue li

  2. Aeroelastic Stability of Suspension Bridges using CFD

    DEFF Research Database (Denmark)

    Stærdahl, Jesper Winther; Sørensen, Niels; Nielsen, Søren R.K.

    2007-01-01

    In recent years large span suspension bridges with very thin and slender profiles have been built without proportional increasing torsional and bending stiffness. As a consequence large deformations at the mid-span can occur with risk of aeroelastic instability and structural failure. Analysis...

  3. The mechanics of ship impacts against bridges

    DEFF Research Database (Denmark)

    Pedersen, Preben Terndrup; Zhang, Shengming

    1998-01-01

    a glancing blow between the ship and the bridge structure. This model is based on rigid body mechanics and well suited for inclusion in a probabilistic analysis procedure. Finally, some empirical expressions are presented which relate the energy absorbed by crushing of ship structures to the maximum impact...

  4. Fiber reinforced polymer composites for bridge structures

    Directory of Open Access Journals (Sweden)

    Alexandra CANTORIU

    2013-12-01

    Full Text Available Rapid advances in construction materials technology have led to the emergence of new materials with special properties, aiming at safety, economy and functionality of bridges structures. A class of structural materials which was originally developed many years ago, but recently caught the attention of engineers involved in the construction of bridges is fiber reinforced polymer composites. This paper provides an overview of fiber reinforced polymer composites used in bridge structures including types, properties, applications and future trends. The results of this study have revealed that this class of materials presents outstanding properties such as high specific strength, high fatigue and environmental resistance, lightweight, stiffness, magnetic transparency, highly cost-effective, and quick assembly, but in the same time high initial costs, lack of data on long-term field performance, low fire resistance. Fiber reinforced polymer composites were widely used in construction of different bridge structures such as: deck and tower, I-beams, tendons, cable stands and proved to be materials for future in this field.

  5. Bridging the Gap Between Theory and Practice

    Directory of Open Access Journals (Sweden)

    Roy H.M. Sembel

    2015-05-01

    Full Text Available Some concerns in the field of Business Management regarding the gap between theory and practice have been raised by practitioners and academicians. This keynote speech describes some lessons learned from the academic literature regarding this gap (whether the gap really exists, and if it exists, whether it needs to be bridged or closed, and how to bridge or close this gap, and shares the author's personal and professional experiences of living as both an academician and a practitioner. The main findings of this article are: (1 Yes the gap exists, however, it has to be viewed in a wider perspective to really understand the situation; (2 The gap in a specific area is bad and should become our concern, but in other areas it should not; (3 There are some ways to bridge or close the negative gap; (4 There exists hybrid career opportunities to become professionals that work both as an academician and a practitioner; (5 This new breed of hybrid professionals has a huge potential to bridge the bad theory-practice gap.

  6. Thermal Bridge Effects in Window Grooves

    DEFF Research Database (Denmark)

    Rose, Jørgen

    1997-01-01

    In this report thermal bridge effects in window grooves are analyzed. The analysis is performed using different thicknesses of the window groove insulation, to evaluate what the optimal solution is.All analysis in the report is performed using both 2- and 3-dimensional numerical analysis....

  7. Charge Transfer and Orbital Reconstruction in Strain-Engineered (La,Sr)MnO3/LaNiO3 Heterostructures.

    Science.gov (United States)

    Peng, Jingjing; Song, Cheng; Li, Fan; Cui, Bin; Mao, Haijun; Wang, Yuyan; Wang, Guangyue; Pan, Feng

    2015-08-19

    We investigate charge transfer, orbital reconstruction, and the emergence of exchange bias in (La,Sr)MnO3/LaNiO3 heterostructures. We demonstrate that charge transfer from Mn(3+) ions to Ni(3+) ions is accompanied by the formation of hybridized Mn/Ni 3z(2) - r(2) orbits at the interface, instead of strain-stabilized Mn and Ni x(2) - y(2) orbits in the bulk films. In the heterostructures with ultrathin LaNiO3, orbital reconstruction induced by charge transfer results in magnetization frustration of (La,Sr)MnO3 at the interface. But the strain effect exerted by the growth of the LaNiO3 top layer plays a dominant role on orbital reconstruction in the heterostructures with thick LaNiO3, stabilizing 3z(2) - r(2) orbits. In this case, robust spin glass, associated with larger magnetization frustration, accounts for the exchange bias effect. Our work builds a bridge between the microscopic electronic structure and the macroscopic magnetic property, providing the possibility of manipulating the exotic states with the aid of strain engineering in oxide-based electronics. PMID:26214290

  8. Mn 3s exchange splitting in mixed-valence manganites.

    Energy Technology Data Exchange (ETDEWEB)

    Galakhov, V. R.; Demeter, M.; Bartkowski, S.; Neumann, M.; Ovechkina, N. A.; Kurmaev, E. Z.; Lobachevskaya, N. I.; Mukovskii, Ya. M.; Mitchell, J.; Ederer, D. L.; Russian Academy of Sciences; Univ. of Osnabruck; Moscow State Steel and Alloys Inst.; Tulane Univ.

    2002-03-15

    We present Mn 3s x-ray photoelectron spectra of manganese oxides with the Mn formal valency from 2+ to 4+. We found that the Sr{sup 2+} doping or cation deficiency in manganites do not change the Mn 3s splitting in manganites with the Mn formal valency from 3.0+ to 3.3+. We suggest that doping holes are localized in O 2p states.

  9. Section 3: Optimization of a 550/690-MPa high-performance bridge steel

    Energy Technology Data Exchange (ETDEWEB)

    Magee, A.B.; Gross, J.H.; Stout, R.D. [and others

    1997-04-01

    This project to develop a high-performance bridge steel was intended to avoid susceptibility of the steel to weld heat-affected-zone cracking and therefore minimize the requirement for preheat, and to increase its fracture toughness at service temperatures. Previous studies by the Lehigh University Center for Advanced Technology for Large Structural Systems have suggested that a Cu-Ni steels with the following composition was an excellent candidate for such a bridge steel: C/0.070; Mn/1.50; P/0.009; S/0.005; Si/0.25; Cu/1.00; Ni/0.75; Cr/0.50; Mo/0.50; V/0.06; Cb/0.010. To confirm that observation, 227-kg heats of the candidate steel were melted and processed to 25- and 50-mm-thick plate by various thermomechanical practices, and the weldability and mechanical properties determined. To evaluate the feasibility of reduced alloy content, two 227-kg heats of a lower hardenability steel were melted with C reduced to 0.06, Mn to 1.25, and Mo to 0.25 and similarly processed and tested. The results indicate that the steels were not susceptible to hydrogen-induced weld-heat-affected-zone cracking when welded without preheat. Jominy end-quench tests of the higher-hardenability steel indicate that a minimum yield-strength of 690 MPa should be readily attainable in thicknesses through 50 mm and marginally at 100 mm. The toughness of the steel readily met AASHTO specifications for Zone 3 in all conditions and thicknesses, and may be sufficiently tough so that the critical crack size will minimize fatigue-crack-extension problems.

  10. Noise Reduction of Fractional Source in Cryogenic Current Comparator Bridge

    OpenAIRE

    C. Jassadajin; Kurupakorn, C.; N. Khumthukthit; A. Pruksanubal

    2013-01-01

    In this work, a resistance measurement is done at both high accuracy and precision using Cryogenic Current Comparator (CCC) bridge system [1]. A CCC bridge circuit consists of three parts: coil, current source and detector parts. There are electronic components in the current source of the system. They generate thermal noise in the measurement system. This paper shows the noise reduction in a fractional source of CCC Bridge which is a ramp generator. The bridge receives the voltage signal, wh...

  11. Performance of damage detection methods in bridges through vibration monitoring

    OpenAIRE

    Cruz, Paulo J. S.; Salgado, R.

    2009-01-01

    The important advances achieved in the modal identification, sensors and structural monitoring of bridges have motivated the bridge engineering community to develop damage detection methods based on vibration monitoring. Some of these methods have already been demonstrated under certain conditions in bridges with deliberate damage (Farrar et al., 1998). However, the performance of these methods for damage detection in bridges has not been fully proven so far and more research n...

  12. RISK LEVEL ANALYSIS ON THE PREVENTIVE EROSION CAPACITY OF BRIDGES

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    Deficiency of the Preventive Erosion Capacity (PEC) of a bridge pier is the main factor leading to bridge failures. In this paper, the PEC of bridge piers was analyzed using the stochastic analysis method. The definitions of the reliability and risk level of a bridge pier subjected to water erosion were proposed and a computational model for erosion depth and risk level in was suggested.

  13. The detection of an older population in the Magellanic Bridge

    OpenAIRE

    Bagheri, Gemma; Cioni, Maria-Rosa; Napiwotzki, Ralf

    2012-01-01

    The Magellanic system comprises the Large Magellanic Cloud (LMC), the Small Magellanic Cloud (SMC), and the less frequently observed Magellanic Bridge and Magellanic Stream. The Bridge is traced by neutral gas and has an observed stellar component, while the Stream consists of gas only, with no observed stellar counterpart to date. This study uses catalogues created in the direction of the Bridge from 2MASS and WISE to investigate the stellar content of the Magellanic Bridge. Catalogues were ...

  14. Rupture of an Evaporating Liquid Bridge between Two Grains

    OpenAIRE

    Mielniczuk, Boleslaw; El Youssoufi, Moulay Saïd; Sabatier, Laurent; Hueckel, Tomasz

    2014-01-01

    The study examines rupture of evaporating liquid bridges between two glass spheres. Evolution of the bridge profile has been recorded with the use of high-speed camera. Geometrical characteristics of the bridge were then used to calculate evolution of the variables during the process: Laplace pressure, capillary force, and surface tension force. For the purpose of reference, the bridge evolution is followed also during kinematic extension. During both processes the diameter of the neck decrea...

  15. TorBricks: Blocking-Resistant Tor Bridge Distribution

    OpenAIRE

    Zamani, Mahdi; Saia, Jared; Crandall, Jedidiah

    2016-01-01

    Tor is currently the most popular network for anonymous Internet access. It critically relies on volunteer nodes called bridges for relaying Internet traffic when a user's ISP blocks connections to Tor. Unfortunately, current methods for distributing bridges are vulnerable to malicious users who obtain and block bridge addresses. In this paper, we propose TorBricks, a protocol for distributing Tor bridges to n users, even when an unknown number t < n of these users are controlled by a malicio...

  16. Railroad Bridges in Louisiana, Geographic NAD83, FEMA (1997) [railroad_bridges_FEMA_1997

    Data.gov (United States)

    Louisiana Geographic Information Center — This is is a point dataset for the locations and attributes of 32 Louisiana railroad bridges. The attributes include city (nearest?), county (sic), routefrom...

  17. Nondestructive evaluation inspection of the Arlington Memorial Bridge using a robotic assisted bridge inspection tool (RABIT)

    Science.gov (United States)

    Gucunski, Nenad; Boone, Shane D.; Zobel, Rob; Ghasemi, Hamid; Parvardeh, Hooman; Kee, Seong-Hoon

    2014-04-01

    The information presented in this report provides a detailed assessment of the condition of the Arlington Memorial Bridge (AMB) deck. The field-data collection was obtained by both the RABIT™ Bridge Inspection Tool and a number of semi-automated non-destructive evaluation (NDE) tools. The deployment of the semi-automated NDE tools was performed to inspect the AMB deck condition and also to validate data obtained by the RABIT™ Bridge Inspection Tool. Data mining and analysis were accomplished through enhanced data interpretation and visualization capabilities using advanced data integration, fusion, and 2D rendering. One of the major challenges that the research team had to overcome in assessing the condition of the AMB deck was the presence of an asphalt overlay on the entire bridge deck.

  18. Performance Assessment of Bridges Using GPS: The Juarez Bridge in Culiacan, Mexico

    Science.gov (United States)

    Vazquez, G. E.; Gaxiola-Camacho, J. R.; Trejo, M.; Echagaray, J.; Guzman, G. M.

    2015-12-01

    Performance assessment of bridges has become very important during recent years. Bridges around the world are aging, leading to the incorporation of efficient, reliable, and economic evaluation procedures. These techniques must assess properly the performance of bridges under several loading conditions in a real manner, representing the physics of the problem. Among several approaches, Global Positioning System (GPS) can be intelligently used for the performance evaluation of bridges. We focused on GPS, since it naturally produces position estimates as compared to seismic instruments that record either velocity or acceleration, and thus require an integration. There are several reasons that make the Juarez Bridge a case of study for evaluation: it is approximately 45 years old, it is a reinforced concrete structure, it connects two significant zones of the city, and its spans is closely to 200 meters long. In addition, thousands of vehicles and pedestrians use the Juarez Bridge every day, which make feasible the GPS performance assessment. Hence, in order to produce optimal position estimates, GPS data were collected during two consecutive hours at three different periods of the day for a whole week (Monday through Sunday), to represent three critical limit states of the bridge (mid-span and end-spans). GPS data were processed using the GAMIT/GLOBK software, considering 1-second sampling rate, 15-degree cutoff angle, ionosphere-free double-differenced (DD) carrier phase method, and precise final orbits disseminated by IGS (International GNSS Service). The displacements obtained from the above discussed procedure are compared with allowable values documented in bridge construction manuals. Reliability theory was used to evaluate the probability of failure of the bridge for the three periods of the day. In addition, a conclusion was made about the most risky day of the week for the use of the Juarez Bridge. It is expected that the results from the proposed research

  19. Magnetoresistance effect in (La, Sr)MnO{sub 3} bicrystalline films

    Energy Technology Data Exchange (ETDEWEB)

    Alejandro, G; Pastoriza, H; Granada, M; Rojas Sanchez, J C; Sirena, M; Alascio, B [Centro Atomico Bariloche (CNEA), Av. Bustillo 9500, 8400 San Carlos de Bariloche, Pcia. de Rio Negro (Argentina); Steren, L B; Vega, D, E-mail: galejand@cab.cnea.gov.a [Centro Atomico Constituyentes (CNEA), 1650 San MartIn, Pcia. de Buenos Aires (Argentina)

    2010-09-01

    The angular dependence of the magnetoresistance effect has been measured on bicrystalline La{sub 0.75}Sr{sub 0.25}MnO{sub 3} films. The measurements have been performed on an electronically lithographed Wheatstone bridge. The study of the angular dependence of both the magnetoresistance and the resistance of single-crystalline and grain-boundary regions of the samples allowed us to isolate two contributions of low-field magnetoresistance in manganites. One of them is associated with the spin-orbit effect, i.e. the anisotropic magnetoresistance of ferromagnetic compounds, and the other one is related to spin-disorder regions at the grain boundary. Complementary x-ray diffraction, ferromagnetic resonance and low temperature magnetization experiments contribute to the characterization of the magnetic anisotropy of the samples and the general comprehension of the problem.

  20. Magnetoresistance effect in (La, Sr)MnO3 bicrystalline films.

    Science.gov (United States)

    Alejandro, G; Steren, L B; Pastoriza, H; Vega, D; Granada, M; Sánchez, J C Rojas; Sirena, M; Alascio, B

    2010-09-01

    The angular dependence of the magnetoresistance effect has been measured on bicrystalline La(0.75)Sr(0.25)MnO(3) films. The measurements have been performed on an electronically lithographed Wheatstone bridge. The study of the angular dependence of both the magnetoresistance and the resistance of single-crystalline and grain-boundary regions of the samples allowed us to isolate two contributions of low-field magnetoresistance in manganites. One of them is associated with the spin-orbit effect, i.e. the anisotropic magnetoresistance of ferromagnetic compounds, and the other one is related to spin-disorder regions at the grain boundary. Complementary x-ray diffraction, ferromagnetic resonance and low temperature magnetization experiments contribute to the characterization of the magnetic anisotropy of the samples and the general comprehension of the problem.

  1. τ-MnAl with high coercivity and saturation magnetization

    Directory of Open Access Journals (Sweden)

    J. Z. Wei

    2014-12-01

    Full Text Available In this paper, high purity τ-Mn54Al46 and Mn54−xAl46Cxalloys were successfully prepared using conventional arc-melting, melt-spinning, and heat treatment process. The magnetic and the structural properties were examined using x-ray diffraction (XRD, powder neutron diffraction and magnetic measurements. A room temperature saturation magnetization of 650.5 kAm-1, coercivity of 0.5 T, and a maximum energy product of (BHmax = 24.7 kJm-3 were achieved for the pure Mn54Al46 powders without carbon doping. The carbon substituted Mn54−xAl46Cx, however, reveals a lower Curie temperature but similar saturation magnetization as compared to the carbon-free sample. The electronic structure of MnAl shows that the Mn atom possesses a magnetic moment of 2.454 μB which results from strong hybridization between Mn-Al and Mn-Mn. We also investigated the volume and c/a ratio dependence of the magnetic moments of Mn and Al. The results indicate that an increase in the intra-atomic exchange splitting due to the cell volume expansion, leads to a large magnetic moment for the Mn atom. The Mn magnetic moment can reach a value of 2.9 μB at a volume expansion rate of ΔV/V ≈ 20%.

  2. The research progress on layered LixMnO2

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    The structural characteristics, preparation methods and electrochemical properties of LixMnO2 were introduced in this paper, and many problems of the research status of LixMnO2 at present were pointet out, meanwhile the developmental direction of layered LixMnO2 in the future was put forward.

  3. Crystalline and magnetic properties of MnAs under pressure

    Science.gov (United States)

    Maki, K.; Kaneko, T.; Hiroyoshi, H.; Kamigaki, K.

    1998-01-01

    Lattice constants and magnetization in MnAs were measured under pressures up to 24 kbar at room temperature and 10 kbar at 80 K, respectively. Compresibilities in the MnP-type phase was obtained at pressures from 8 to 24 kbar. Magnetic moment of Mn ion was about 1.6 μ B under 8—10 kbar.

  4. Building water bridges in air: Electrohydrodynamics of the Floating Water Bridge

    OpenAIRE

    Marin, Alvaro G.; Lohse, Detlef

    2010-01-01

    The interaction of electrical fields and liquids can lead to a phenomenon that defies intuition. Some famous examples can be found in electrohydrodynamics as Taylor cones, whipping jets, or noncoalescing drops. A less famous example is the floating water bridge: a slender thread of water held between two glass beakers in which a high voltage difference is applied. Surprisingly, the water bridge defies gravity even when the beakers are separated at distances up to 2 cm. In this paper, experime...

  5. Spectroscopic Studies of Bridge Contributions to Electronic Coupling in a Donor-Bridge-Acceptor Biradical System

    OpenAIRE

    Kirk, Martin L.; Shultz, David A.; Depperman, Ezra C.; Habel-Rodriguez, Diana; Schmidt, Robert D.

    2012-01-01

    Variable temperature electronic absorption and resonance Raman spectroscopies are used to probe the excited state electronic structure of TpCum,MeZn(SQ-Ph-NN) (1) – a donor-bridge-acceptor (D-B-A) biradical complex and a ground state analog of the charge-separated excited state formed in photoinduced electron transfer reactions. Strong ferromagnetic exchange coupling that is mediated by the para-phenylene bridge stabilizes the triplet ground state of this molecule. Detailed spectroscopic and ...

  6. Effects of Cu and Mn on mechanical properties and damping capacity of Mg-Cu-Mn alloy

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    The effects of Cu and Mn additions on mechanical properties and damping capacity of Mg-Cu-Mn alloy were investigated.The tensile properties and damping capacity at room temperature of as-cast Mg-Cu-Mn alloy were tested. The microstructure was model were used to explain the influences of Cu and Mn additions on the tensile properties and damping capacity of Mg-Cu-Mn alloy. The results show that Cu and Mn additions remarkably reduce the grain size of Mg-Cu-Mn alloy, but have little influence on phase composition and solute atoms concentration, the tensile properties increase obviously and the internal friction of Mg-Cu-Mn alloy decreases with grain refining.

  7. {sup 55}Mn NMR study in Mn{sub 1-x}Ti{sub x}As

    Energy Technology Data Exchange (ETDEWEB)

    Amako, Yasushi E-mail: tenjine@gipac.shinshu-u.ac.jp; Nagai, Hiroyuki; Ido, Hideaki

    2004-05-01

    The nuclear magnetic resonance of {sup 55}Mn nuclei in Mn{sub 1-x}Ti{sub x}As has been measured at 4 K. {sup 55}Mn resonance frequency in zero external field is 237 MHz for MnAs of which the spontaneous magnetization at 4.2 K is 3.4 {mu}{sub B}/f.u. Zero field {sup 55}Mn NMR spectra shift at the high-frequency side and they split in three signals by substituting Mn for Ti though the magnetic moment per Mn atom is constant for x less than 0.55. The transferred hyperfine field due to the nearest neighbor Mn moment is estimated to be +21 kOe.

  8. 49 CFR 237.31 - Adoption of bridge management programs.

    Science.gov (United States)

    2010-10-01

    ... 49 Transportation 4 2010-10-01 2010-10-01 false Adoption of bridge management programs. 237.31 Section 237.31 Transportation Other Regulations Relating to Transportation (Continued) FEDERAL RAILROAD... Adoption of bridge management programs. Each track owner shall adopt a bridge safety management program...

  9. Ambient Response Analysis of the Great Belt Bridge

    DEFF Research Database (Denmark)

    Brincker, Rune; Frandsen, J. B.; Andersen, P.

    2000-01-01

    In this paper an ambient response analysis of the Great Belt Bridge is presented. The Great Belt Bridge is one of the largest suspension bridges in the world, and the analysis was carried out in order to investigate the possibilities of estimating reliable damping values from the ambient response...

  10. 23 CFR 650.409 - Evaluation of bridge inventory.

    Science.gov (United States)

    2010-04-01

    ... BRIDGES, STRUCTURES, AND HYDRAULICS Highway Bridge Replacement and Rehabilitation Program § 650.409... establishing eligibility and priority for replacement or rehabilitation of bridges; in general the lower the... State program. After evaluation of the inventory and assignment of sufficiency ratings, the...

  11. Reduction of Impact Noise of Trams on a Major Bridge

    NARCIS (Netherlands)

    Dittrich, M.G.; Bosshaart, C.; Wessels, P.W.

    2015-01-01

    As part of a recent renovation of the Erasmus bridge in Rotterdam, improvements were made to reduce impact noise caused by trams passing a series of rai! joints. The bridge inciudes several different sections inciuding a bascule bridge and is in an inner city tocation with new adjacent apartment bui

  12. 21 CFR 872.3770 - Temporary crown and bridge resin.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Temporary crown and bridge resin. 872.3770 Section... (CONTINUED) MEDICAL DEVICES DENTAL DEVICES Prosthetic Devices § 872.3770 Temporary crown and bridge resin. (a) Identification. A temporary crown and bridge resin is a device composed of a material, such...

  13. Resin-Bonded Bridges in vitro and in vivo

    NARCIS (Netherlands)

    Veen, Johannes Hilbrandt van der

    1988-01-01

    In this thesis in vitro and in vivo studies on the clinical application of resin-bonded bridges are described and discussed. The development of different types of resin-bonded bridges is described in chapter 1. The bridges are often made by boding a cast metal retainer fitted with and artificial too

  14. Bridged Quaterphenyls as Flashlamp-Pumpable Laser Dyes

    OpenAIRE

    Kauffman, Joel M; Kelley, Charles J.; Ghiorghis, Alem; Neister, Edward; Armstrong, Lorne; Prause, Paul R.

    1987-01-01

    Partial bridging of the o,o′ positions of the aromatic rings in quaterphenyl gave superior flashlamp-pumpable laser dyes. Alkyl-substituted carbon bridges gave superior dyes to those containing oxygen or alkyl-substituted nitrogen or silicon bridges. Dyes lasing in the 365–390 nm region with improved energy output, lifetime and solubility were discovered.

  15. Improving the Dynamics of Suspension Bridges using Active Control Systems

    DEFF Research Database (Denmark)

    Thoft-Christensen, Palle

    Improving the dynamics of suspension bridge using active control is discussed in this paper. The main dynamic problem with long suspension bridges is the aeroelastic phenomenon called flutter. Flutter oscillations of a bridge girder is a stability problem and the oscillations are perpendicular...

  16. Renovation techniques for fatigue cracked orthotropic steel bridge decks

    NARCIS (Netherlands)

    de Jong, F.B.P.

    2007-01-01

    This dissertation presents the research into renovation techniques for orthotropic steel bridge decks. These techniques are needed to solve fatigue problems in the decks of these bridges, as several fatigue cracks have been detected in the deck structure of these bridges the last decade. A well-know

  17. Thermodynamic Properties of Carbon and Manganese in Mn-C and Mn-Fe-C Melts

    Institute of Scientific and Technical Information of China (English)

    CHEN Er-bao; WANG Shi-jun

    2008-01-01

    Carbon solubility in Mn-Fe melts (xMn=0.083-0.706,xFe=0.034-0.715) was measured experimentally at various temperatures.By thermodynamic derivation and calculation,the relationship between activity coefficient of carbon in infinite dilute solution of manganese in Mn-C system and temperature was obtained.Using Gibbs-Duhem relationship,the experimental results of this study,and experimental data obtained by strict thermodynamic derivation and calculation in references,the relationships between other thermodynamic properties (εCC,εCCC,εCFe,eεCCFe,and εCFeCFe) in Mn-Fe-C system and temperature were obtained.

  18. Magnetism and transport properties of α-Mn structure Mn3Ge thin film

    Science.gov (United States)

    Dung, Dang Duc; Feng, Wuwei; Shin, Yooleemi; Cho, Sunglae

    2011-04-01

    We have newly synthesized the α-Mn structured Mn3Ge thin films on GaAs(001) substrate. The single phase Mn3Ge film was grown at a growth temperature of 150 °C, while the secondary phase was observed above a growth temperature of 250 °C. The Mn3Ge films exhibited ferrimagnetism with a Curie temperature of 334 K. The saturation magnetizations were 255.9 and 313.8 emu/cm3 and the corresponding coercive fields were 453 and 1166 Oe at 10 K for the samples grown at 150 and 300 °C, respectively. The ferrimagnetism was confirmed by the anomalous Hall effect data.

  19. 78 FR 28939 - Minnesota Disaster #MN-00049

    Science.gov (United States)

    2013-05-16

    ... Counties: Cottonwood, Jackson, Murray, Nobles, Rock. The Interest Rates are: Percent For Physical Damage... ADMINISTRATION Minnesota Disaster MN-00049 AGENCY: U.S. Small Business Administration. ACTION: Notice. SUMMARY... State of Minnesota (FEMA- 4113-DR), dated 05/03/2013. Incident: Severe Winter Storm. Incident Period:...

  20. Na Deposition on MnO(100)

    Science.gov (United States)

    Feng, Xu; Cox, David F.

    2016-03-01

    Na deposition on the MnO(100) surface was investigated by temperature programmed desorption (TPD), X-ray photoelectron spectroscopy (XPS) and low energy electron diffraction (LEED). Na TPD and XPS results indicate that adsorbed Na interacts strongly with the MnO substrate to form an irreversibly-adsorbed, oxidic Na compound on the surface for coverages up to 1 monolayer (ML). This strongly-bound Na diffuses into the MnO subsurface and bulk at elevated temperatures above 500 K. For Na coverages above 1 ML, metallic Na is present and desorbs from the surface below 500 K. The deposition of Na on MnO(100) follows a Stranski-Krastanov (SK) growth mode, with the formation of metallic Na islands following completion of the first Na monolayer. After Na deposition, the surface exhibits a diffuse (1 × 1) LEED pattern, suggesting the formation of disordered Na overlayers. After heating to 1000 K, the surface presents a (2 × 2) LEED pattern indicating that a surface reconstruction is induced by the diffusion of Na into the near surface region. CO2 can be used as a probe molecule in TPD to distinguish between metallic Na islands and oxidic Na in the first ML, and to indicate when Na that is still observable by XPS goes subsurface.

  1. 77 FR 51101 - Minnesota Disaster #MN-00037

    Science.gov (United States)

    2012-08-23

    ... From the Federal Register Online via the Government Publishing Office SMALL BUSINESS ADMINISTRATION Minnesota Disaster MN-00037 AGENCY: U.S. Small Business Administration. ACTION: Notice. SUMMARY... Application Deadline Date: 05/16/2013. ADDRESSES: Submit completed loan applications to: U.S. Small...

  2. Road Bridges and Culverts, Bridges layers located in GIS and Transportation database., Published in unknown, City of Roswell, GA.

    Data.gov (United States)

    NSGIC GIS Inventory (aka Ramona) — This Road Bridges and Culverts dataset as of unknown. It is described as 'Bridges layers located in GIS and Transportation database.'. Data by this publisher are...

  3. Frustrated pyrochlore oxides, Y2Mn2O7, Ho2Mn2O7, and Yb2Mn2O7: Bulk magnetism and magnetic microstructure

    DEFF Research Database (Denmark)

    Greedan, J.E.; Raju, N.P.; Maignan, A.;

    1996-01-01

    The bulk magnetic properties, including de and ac susceptibilities and heat capacity, of the pyrochlore oxides Ho2Mn2O7 and Yb2Mn2O7 are reported and compared with those of the previously studied Y2Mn2O7. In the latter case the magnetic Mn4+ ions occupy the 16c sites in Fd3m which define...... a potentially frustrated three-dimensional array of corner sharing tetrahedra. For Ho2Mn2O7 and Yb2Mn2O7 magnetic rare earth ions occupy the 16d sites, as shown by powder neutron diffraction, which are topologically equivalent to the 16c sites but displaced by a vector (1/2 1/2 1/2). Ho2Mn2O7 and Yb2Mn2O7....... Surprisingly, neutron diffraction data for both Ho2Mn2O7 and Yb2Mn2O7 show resolution limited reflections of magnetic origin in contrast to the heat capacity results. The resolution of the neutron diffraction data places a minimum on the correlation length of 100 Angstrom. Small angle neutron scattering data...

  4. Synthesis of an S T = 7 [Mn 3 ] Mixed-Valence Complex Based on 1,3-Propanediol Ligand Derivatives and Its One-Dimensional Assemblies

    KAUST Repository

    Huang, Jian

    2013-10-07

    Controlled organization of high-spin complexes and single-molecule magnets is a great challenge in molecular magnetism in order to study the effect of the intercomplex magnetic interactions on the intrinsic properties of a given magnetic object. In this work, a new ST = 7 trinuclear mixed-valence Mn complex, [MnIIIMnII 2(LA) 2(Br)4(CH3OH)6] ·Br· (CH3OH)1.5·(H2O)0.5 (1), is reported using a pyridinium-functionalized 1,3-propanediol ligand (H 2LABr = 1-(3-bromo-2,2-bis(hydroxymethyl)propyl)pyridinium bromide). Using azido anions as bridging ligands and different pyridinium-functionalized 1,3-propanediol ligands (H2LBBr = 1-(3-bromo-2,2-bis(hydroxymethyl)propyl)-4-picolinium bromide; H 2LCBr = 1-(3-bromo-2,2-bis(hydroxymethyl)propyl)-3,5- lutidinium bromide), the linear [MnIIIMnII 2L2X4]+ building block has been assembled into one-dimensional coordination networks: [MnIIIMn II 2(LA)2(Br)4(CH 3OH)4(N3)]·((C2H 5)2O)1.25 (2∞), [MnIIIMn II 2(LB)2(Br)4(C 2H5OH)(CH3OH)(H2O) 2(N3)]·(H2O)0.25 (3∞), and [MnIIIMnII 2(LC) 2(Cl)3.8(Br)0.2(C2H 5OH)3(CH3OH)(N3)] (4∞). The syntheses, characterization, crystal structures, and magnetic properties of these new [Mn3]-based materials are reported. © 2013 American Chemical Society.

  5. On Reductive Monoid Mn(K)%既约么半群Mn(K)

    Institute of Scientific and Technical Information of China (English)

    曹佑安; 李卓

    2004-01-01

    主要介绍Renner得到的重要结果代数么半群的Bruhat分解.这一结果是Putcha-Renner理论系统发展的一个里程碑.当保留首先被Renner发现时,它甚至对Mn(K)也是新的.该文利用线性代数知识对Mn(K)的Bruhat分解给出一个初等描述,并且给出所有秩2,半单秩1的既约么半群.作者用初等方法证明了Mn(K)的Bruhat分解,最后介绍了与Renner么半群密切相关的Hecke代数.%This article serves as an introduction to one of the amazing results established by Renner which is the analogue of the Bruhat decomposition of algebraic monoids. This result is a milestone in the system development of Putcha-Renner theory. It was even new to Mn(K) when it was first found by Renner. In this article we give an elementary description to Mn(K) using linear algebra knowledge and list all rank two, semisimple rank one reductive monoids. We prove the analogue of Bruhat decomposition for Mn(K) in an elementary way. Finally we pose some open problems on Hecke algebras related to Renner monoids.

  6. Suppression of superconductivity in Nb by IrMn in IrMn/Nb bilayers

    KAUST Repository

    Wu, B. L.

    2013-10-10

    Effect of antiferromagnet on superconductivity has been investigated in IrMn/Nb bilayers. Significant suppression of both transition temperature (Tc) and lower critical field (Hc1) of Nb is found in IrMn/Nb bilayers as compared to a single layer Nb of same thickness; the suppression effect is even stronger than that of a ferromagnet in NiFe/Nb bilayers. The addition of an insulating MgO layer at the IrMn-Nb interface nearly restores Tc to that of the single layer Nb, but Hc1 still remains suppressed. These results suggest that, in addition to proximity effect and magnetic impurity scattering, magnetostatic interaction also plays a role in suppressing superconductivity of Nb in IrMn/Nb bilayers. In addition to reduced Tc and Hc1, the IrMn layer also induces broadening in the transition temperature of Nb, which can be accounted for by a finite distribution of stray field from IrMn.

  7. CaMn2Al10 : Itinerant Mn magnetism on the verge of magnetic order

    Science.gov (United States)

    Steinke, L.; Simonson, J. W.; Yin, W.-G.; Smith, G. J.; Kistner-Morris, J. J.; Zellman, S.; Puri, A.; Aronson, M. C.

    2015-07-01

    We report the discovery of CaMn2Al10 , a metal with strong magnetic anisotropy and moderate electronic correlations. Magnetization measurements find a Curie-Weiss moment of 0.83 μB/Mn , significantly reduced from the Hund's rule value, and the magnetic entropy obtained from specific heat measurements is correspondingly small, only ≈9 % of R ln 2 . These results imply that the Mn magnetism is highly itinerant, a conclusion supported by density functional theory calculations that find strong Mn-Al hybridization. Consistent with the layered nature of the crystal structure, the magnetic susceptibility χ is anisotropic below 20 K, with a maximum ratio of χ[010 ]/χ[001 ]≈3.5 . A strong power-law divergence χ (T ) ˜T-1.2 below 20 K implies incipient ferromagnetic order with a low Curie temperature TC<2 K . Our experiments indicate that CaMn2Al10 is a rare example of a system where the weak and itinerant Mn-based magnetism is poised on the verge of order.

  8. Growth and characterization of epitaxial NiMnSb/ZnTe/NiMnSb magnetic multilayers

    Science.gov (United States)

    Gerhard, F.; Naydenova, T.; Baussenwein, M.; Schumacher, C.; Gould, C.; Molenkamp, L. W.

    2016-02-01

    The half-metal ferromagnet NiMnSb, with its high spin polarization, low magnetic damping and tunable magnetic anisotropy, is a promising material for applications in spin torque devices. We develop the epitaxial growth of NiMnSb/ZnTe/NiMnSb heterostructures, aiming towards the realization of an all-NiMnSb based magnetic tunneling junction (MTJ). Layers are grown in situ by Molecular Beam Epitaxy (MBE) and Atomic Layer Epitaxy (ALE) methods. By tuning Mn content, the magnetic anisotropy of each of the two NiMnSb layers is adjusted in order to achieve mutually orthogonal uniaxial anisotropies. SQUID measurements of the magnetization along orthogonal crystal directions [110] and [ 1 1 bar 0] confirm that the two layers have mutually orthogonal anisotropy. High Resolution X-Ray Diffraction measurements and simulations confirm the nominal layer stack and demonstrate the high crystalline quality of the individual layers. Such layer stacks provide a potential basis for TMR-based spin-torque devices such as spin-torque oscillators.

  9. Reversing ferroelectric polarization in multiferroic DyMn2O5 by nonmagnetic Al substitution of Mn

    Science.gov (United States)

    Zhao, Z. Y.; Liu, M. F.; Li, X.; Wang, J. X.; Yan, Z. B.; Wang, K. F.; Liu, J.-M.

    2014-08-01

    The multiferroic RMn2O5 family, where R is rare-earth ion or Y, exhibits rich physics of multiferroicity which has not yet well understood. DyMn2O5 is a representative member of this family. The ferroelectric polarization of DyMn2O5 is claimed to be magnetically relevant and have more than one component. Therefore, the polarization reversal upon the sequent magnetic transitions is expected. We investigate the evolution of the ferroelectric polarization upon a partial substitution of Mn3+ by nonmagnetic Al3+ in order to tailor the Mn3+-Mn4+ interactions and then to modulate the polarization in DyMn2-x/2Alx/2O5. It is revealed that the polarization can be successfully reversed by Al-substitution via substantially suppressing the Mn3+-Mn4+ interactions, while the Dy3+-Mn4+ interactions can sustain against the substitution until a level as high as x = 0.2. In addition, the independent Dy spin ordering is shifted remarkably down to an extremely low temperature due to the Al3+ substitution. The present work unveils the possibility of tailoring the Mn3+-Mn4+ and Dy3+-Mn4+ interactions independently, and thus reversing the ferroelectric polarization.

  10. Scale-bridging analysis on deformation behavior of high-nitrogen austenitic steels.

    Science.gov (United States)

    Lee, Tae-Ho; Ha, Heon-Young; Hwang, Byoungchul; Kim, Sung-Joon; Shin, Eunjoo; Lee, Jong Wook

    2013-08-01

    Scale-bridging analysis on deformation behavior of high-nitrogen austenitic Fe-18Cr-10Mn-(0.39 and 0.69)N steels was performed by neutron diffraction, electron backscattered diffraction (EBSD), and transmission electron microscopy (TEM). Two important modes of deformation were identified depending on the nitrogen content: deformation twinning in the 0.69 N alloy and strain-induced martensitic transformation in the 0.39 N alloy. The phase fraction and deformation faulting probabilities were evaluated based on analyses of peak shift and asymmetry of neutron diffraction profiles. Semi in situ EBSD measurement was performed to investigate the orientation dependence of deformation microstructure and it showed that the variants of ε martensite as well as twin showed strong orientation dependence with respect to tensile axis. TEM observation showed that deformation twin with a {111} mathematical left angle bracket 112 mathematical right angle bracket crystallographic component was predominant in the 0.69 N alloy whereas two types of strain-induced martensites (ε and α' martensites) were observed in the 0.39 N alloy. It can be concluded that scale-bridging analysis using neutron diffraction, EBSD, and TEM can yield a comprehensive understanding of the deformation mechanism of nitrogen-alloyed austenitic steels.

  11. Cationic disorder and Mn3+/Mn4+ charge ordering in the B′ and B″ sites of Ca3Mn2NbO9 perovskite: a comparison with Ca3Mn2WO9

    International Nuclear Information System (INIS)

    We describe the preparation, crystal structure determination, magnetic and transport properties of two novel Mn-containing perovskites, with a different electronic configuration for Mn atoms located in B site. Ca3Mn3+2WO9 and Ca3Mn3+/4+2NbO9 were synthesized by standard ceramic procedures; the crystallographic structure was studied from X-ray powder diffraction (XRPD) and neutron powder diffraction (NPD). Both phases exhibit a monoclinic symmetry (S.G.: P21/n); Ca3Mn2WO9 presents a long-range ordering over the B sites, whereas Ca3Mn2NbO9 is strongly disordered. By “in-situ” NPD, the temperature evolution of the structure study presents an interesting evolution in the octahedral size (〈Mn–O〉) for Ca3Mn2NbO9, driven by a charge ordering effect between Mn3+ and Mn4+ atoms, related to the anomaly observed in the transport measurements at T≈160 K. Both materials present a magnetic order below TC=30 K and 40 K for W and Nb materials, respectively. The magneto-transport measurements display non-negligible magnetoresistance properties in the paramagnetic regime. - Graphical abstract: Comparison between the octahedron size and the magnetic behaviour for Ca3Mn2NbO9 in the temperature region where the charge and magnetic order occur. Display Omitted - Highlights: • Two novel Mn-containing double perovskites were obtained by solid-state reactions. • Both double perovskites are monoclinic (P21/n) determined by XRPD and NPD. • Ca3Mn2WO9 contains Mn3+ while Ca3Mn2NbO9 includes mixed-valence cations Mn3+/Mn4+. • Ca3Mn2NbO9 presents a charge-ordering effect between Mn3+ and Mn4+ evidenced by NPD. • The magnetic and transport studies evidenced the charge ordering in Ca3Mn2NbO9

  12. Observation of ferromagnetism in Mn doped KNbO3

    International Nuclear Information System (INIS)

    Pure and Mn doped KNbO3 have been prepared by ball milling assisted ceramic method. Mn ion had been doped at Nb site to induce ferromagnetism at room temperature. X-ray diffraction (XRD) patterns reveal the formation of orthorhombic phase. High resolution scanning electron micrograph (HR-SEM) of both pure and Mn doped samples show a mixture of spherical and plate like particles. Room temperature magnetic behavior of both the samples were analyzed using vibrating sample magnetometer (VSM). 5% Mn doped KNbO3 exhibits ferromagnetic behavior. Observed ferromagnetic feature has been explained by interactions between bound magnetic polarons which are created by Mn4+ ions

  13. Lithium intercalation into layered LiMnO2

    DEFF Research Database (Denmark)

    Vitins, G.; West, Keld

    1997-01-01

    Recently Armstrong and Bruce(1) reported a layered modification of lithium manganese oxide, LiMnO2, isostructural with LiCoO2. LiMnO2 obtained by ion exchange from alpha-NaMnO2 synthesized in air is characterized by x-ray diffraction and by electrochemical insertion and extraction of lithium...... to expectations based on thermodynamics, insertion of larger amounts of lithium leads to a more complete conversion. We suggest that a relatively high mobility of manganese leaves Li and Mn randomly distributed in the close-packed oxygen lattice after a deep discharge. This isotropic Mn distribution can...

  14. PARAMETRIC STUDY OF SKEW ANGLE ON BOX GIRDER BRIDGE DECK

    OpenAIRE

    Shrikant D. Bobade *, Dr. Valsson Varghese

    2016-01-01

    Box girder bridge deck, is the most common type of bridges in world and India, it consists of several Slab or girders. The span in the direction of the roadway and connected across their tops and bottoms by a thin continuous structural stab, the longitudinal box girders can be made of steel or concrete. The Simple supported single span concrete bridge deck is presented in present study. Skewed bridges are suitable in highway design when the geometry of straight bridges is not possible. The sk...

  15. Ambient Modal Testing of the Vestvej Bridge using Random Decrement

    DEFF Research Database (Denmark)

    Asmussen, J. C.; Brincker, Rune; Rytter, A.

    This paper presents an ambient vibration study of the Vestvej Bridge. The bridge is a typically Danish two-span concrete bridge which crosses a highway. The purpose of the study is to perform a pre-investigation of the dynamic behavior to obtain information for the design of a demonstration project...... concerning application of vibration based inspection of bridges. The data analysis process of ambient vribration testing of bridges has traditionally been based on auto and cross spectral densities estimated using an FFT algorithm. In the pre-analysis state the spectral densities are all averaged to obtain...

  16. Ambient Modal Testing of the Vestvej Bridge using Random Decrement

    DEFF Research Database (Denmark)

    Asmussen, J. C.; Brincker, Rune; Rytter, A.

    1998-01-01

    This paper presents an ambient vibration study of the Vestvej Bridge. The bridge is a typically Danish two-span concrete bridge which crosses a highway. The purpose of the study is to perform a pre-investigation of the dynamic behavior to obtain information for the design of a demonstration project...... concerning application of vibration based inspection of bridges. The data analysis process of ambient vribration testing of bridges has traditionally been based on auto and cross spectral densities estimated using an FFT algorithm. In the pre-analysis state the spectral densities are all averaged to obtain...

  17. Seismic Passive Control of Cable-Stayed Bridges

    Directory of Open Access Journals (Sweden)

    Hosam-Eddin M. Ali

    1995-01-01

    Full Text Available A three-dimensional modeling procedure is proposed for cable-stayed bridges with rubber, steel, and lead energy dissipation devices. The passive control technique is investigated by considering the response of bridge models with and without energy dissipation devices. The impact of various design parameters on the seismic response of current and future bridge designs is studied. Appropriate locations and properties of the passive devices can achieve better performance for cable-stayed bridges by balancing the significant reduction in earthquake-induced forces against tolerable displacements. Proper design of passive systems can help provide solutions for retro-fitting some existing bridges.

  18. Dynamic analysis of rail transit elevated bridge with ladder track

    Institute of Scientific and Technical Information of China (English)

    He XIA; Yushu DENG; Yongwei ZOU; Guido DE ROECK; Geert DEGRANDE

    2009-01-01

    In this paper, a dynamic analysis model of an elevated bridge with ladder tracks under moving train load is established. The whole process of a train running through an elevated bridge at different speeds is simulated.The dynamic responses of the elevated bridge with ladder track and the running safety and comfort index of train vehicles are evaluated. Compared with the dynamic responses of an elevated bridge with ordinary non-ballasted slab track, the ladder track's effect on reducing the vibration of an elevated bridge is analyzed. The analysis results show that the ladder track has good vibration reduction characteristics as compared to ordinary non-ballasted track.

  19. Suspension Bridge Flutter for Girder with Separate Control Flaps

    DEFF Research Database (Denmark)

    Huynh, T.; Thoft-Christensen, Palle

    Active vibration control of long span suspension bridge flutter using separated control flaps (SFSC) has shown to increase effectively the critical wind speed of bridges. In this paper, an SFSC calculation based on modal equations of the vertical and torsional motions of the bridge girder including...... the flaps is presented. The length of the flaps attached to the girder, the flap configuration and the flap rotational angles are parameters used to increase the critical wind speed of the bridge. To illustrate the theory a numerical example is shown for a suspension bridge of 1000m+2500m+1000m span based...

  20. Cross-bridge model of muscle contraction. Quantitative analysis.

    OpenAIRE

    Eisenberg, E.; Hill, T L; Chen, Y.

    1980-01-01

    We recently presented, in a qualitative manner, a cross-bridge model of muscle contraction which was based on a biochemical kinetic cycle for the actomyosin ATPase activity. This cross-bridge model consisted of two cross-bridge states detached from actin and two cross-bridge states attached to actin. In the present paper, we attempt to fit this model quantitatively to both biochemical and physiological data. We find that the resulting complete cross-bridge model is able to account reasonably ...

  1. Excitation of Arch and Suspension Bridges by Subwires

    Directory of Open Access Journals (Sweden)

    Noriaki Hiwatashi

    1993-01-01

    Full Text Available A force generation method using a subwire for arch and suspension bridges is proposed. The subwire is connected to the arch or the cable of the bridge through rollers. The uniform force produced by pulling and releasing the pretensioned subwires acts on the bridge as an externalforce. A new device called “the resonance force generator” is also developed to excite the bridges by applying a small force. To verify the proposed concept, a stress ribbon bridge was excited with the resonance force generator.

  2. Excitation of Arch and Suspension Bridges by Subwires

    OpenAIRE

    Noriaki Hiwatashi; Yoji Mizuta; Yutaka Ishihara; Itio Hirai

    1993-01-01

    A force generation method using a subwire for arch and suspension bridges is proposed. The subwire is connected to the arch or the cable of the bridge through rollers. The uniform force produced by pulling and releasing the pretensioned subwires acts on the bridge as an externalforce. A new device called “the resonance force generator” is also developed to excite the bridges by applying a small force. To verify the proposed concept, a stress ribbon bridge was excited with the resonance force ...

  3. Violin Bridge Mobility Analysis under In-Plane Excitation

    OpenAIRE

    Cheng-Zhong Zhang; Guang-Ming Zhang; Bang-Yan Ye; Li-Dong Liang

    2013-01-01

    The vibration of a violin bridge is a dynamic contact vibration with two interfaces: strings-bridge, and bridge feet-top plate. In this paper, the mobility of an isolated bridge under in-plane excitation is explored using finite element modeling based on the contact vibration model. Numerical results show that the dynamic contact stiffness in the two contact interfaces has a great impact on the bridge mobility. A main resonance peak is observed in the frequency range of 2–3 kHz in the frequen...

  4. Translating Climate Projections for Bridge Engineering

    Science.gov (United States)

    Anderson, C.; Takle, E. S.; Krajewski, W.; Mantilla, R.; Quintero, F.

    2015-12-01

    A bridge vulnerability pilot study was conducted by Iowa Department of Transportation (IADOT) as one of nineteen pilots supported by the Federal Highway Administration Climate Change Resilience Pilots. Our pilot study team consisted of the IADOT senior bridge engineer who is the preliminary design section leader as well as climate and hydrological scientists. The pilot project culminated in a visual graphic designed by the bridge engineer (Figure 1), and an evaluation framework for bridge engineering design. The framework has four stages. The first two stages evaluate the spatial and temporal resolution needed in climate projection data in order to be suitable for input to a hydrology model. The framework separates streamflow simulation error into errors from the streamflow model and from the coarseness of input weather data series. In the final two stages, the framework evaluates credibility of climate projection streamflow simulations. Using an empirically downscaled data set, projection streamflow is generated. Error is computed in two time frames: the training period of the empirical downscaling methodology, and an out-of-sample period. If large errors in projection streamflow were observed during the training period, it would indicate low accuracy and, therefore, low credibility. If large errors in streamflow were observed during the out-of-sample period, it would mean the approach may not include some causes of change and, therefore, the climate projections would have limited credibility for setting expectations for changes. We address uncertainty with confidence intervals on quantiles of streamflow discharge. The results show the 95% confidence intervals have significant overlap. Nevertheless, the use of confidence intervals enabled engineering judgement. In our discussions, we noted the consistency in direction of change across basins, though the flood mechanism was different across basins, and the high bound of bridge lifetime period quantiles exceeded

  5. Electrodeposition Behavior of Mn with Ni in Acidic Sulfate Solutions

    Science.gov (United States)

    Ji, Dan; Le, Xiawen; Zhong, Qingdong; Zhou, Qiongyu

    2014-09-01

    The influence of Mn2+/Ni2+ mole ratio in electrolytes on the Ni-Mn alloy deposits was studied. The electrodeposition mechanism of Mn with Ni is analyzed by the cyclic voltammogram (CV) and an "induced co-deposition" mechanism is proposed for Ni-Mn alloy electrodeposition. The results show that the Mn content in Ni-Mn alloy deposit and the hardness increased with the increase of Mn2+/Ni2+ mole ratio in electrolytes. When the Mn2+/Ni2+ mole ratio in bath was 2/1, the corrosion current density of the deposit coating was the lowest and the corresponding corrosion potential was higher, and under these conditions the coating with a Mn content of 1.20 wt.% showed good corrosion resistance. The scanning electron microscopy (SEM) of the alloy coatings exhibited that the morphology of Ni-Mn alloy coatings were different from Pure Ni coating, and when Mn2+/Ni2+ was 2/1, the surface was compact and homogeneous.

  6. Bridge health assessment system with fatigue analysis algorithm

    Science.gov (United States)

    Wang, Xuan; Wang, M. L.; Zhao, Yang

    2005-05-01

    A modern bridge is such a complicated system that is difficult to analyze by conventional mathematic tools. A rational bridge monitoring requires a good knowledge of the actual condition of various structural components. Fatigue analysis of concrete bridges is one of the most important problems. Concrete bridges are often undergoing a fatigue deterioration, starting with cracking and ending with large holes through the web. There is a need for the development of efficient health assessment system for fatigue evaluation and prediction of the remaining life. This information has clear economical consequences, as deficient bridges must be repaired or closed. The goal of this research is to provide a practical expert system in bridge health evaluation and improve the understanding of bridge behavior during their service. Efforts to develop a functional bridge monitoring system have mainly been concentrated upon successful implementation of experienced-based machine learning. The reliability of the techniques adopted for damage assessment is also important for bridge monitoring systems. By applying the system to an in-service PC bridge, it has been verified that this fuzzy logic expert system is effective and reliable for the bridge health evaluation.

  7. Inverse bottleneck in Eu2+-Mn2+ energy transfer

    International Nuclear Information System (INIS)

    The energy transfer (ET) between Eu2+ and Mn2+ in Ca5(PO4)3Cl has been investigated. At low intensities under 405 nm excitation, time-resolved experiments provide microscopic parameters for the energy transfer between adjacent Eu2+ and Mn2+ ions. At high intensities, we observe a non-linear component in the energy transfer process due to ground state depletion of the Mn2+ ions, leading not to a reduction, but to an increase in the energy transfer rate between Eu2+ and Mn2+ ions and also energy transfer between excited Mn2+ ions. This results in a sub-linear response of both Eu2+ and Mn2+ luminescence as a function of intensity. Our observations are quantitatively described by a model using energy transfer to Mn2+ ions in both the ground and the excited state.

  8. Noncollinear magnetism of Mn nanowires on Fe(1 1 0)

    Science.gov (United States)

    Igarashi, R. N.; Miranda, I. P.; Eleno, L. T. F.; Klautau, A. B.; Petrilli, H. M.

    2016-08-01

    Magnetic properties of Mn linear nanochains on a bcc Fe(1 1 0) surface have been studied using the first-principles real space-linear muffin-tin orbital atomic sphere approximation (RS-LMTO-ASA) method. We have considered up to nine Mn atoms deposited on bcc Fe(1 1 0). Our ab initio calculations reveal the competition between the antiferromagnetic Mn-Mn and Mn-Fe couplings, presenting a behavior which is very different from Mn nanowires on Fe(0 0 1), as shown in a previous publication. Due to this competition and non-negligible Dzyaloshinskii-Moriya interaction, noncollinear magnetic structures are stabilized as ground states for the Mn nanochains on Fe(1 1 0).

  9. Noncollinear magnetism of Mn nanowires on Fe(1 1 0).

    Science.gov (United States)

    Igarashi, R N; Miranda, I P; Eleno, L T F; Klautau, A B; Petrilli, H M

    2016-08-17

    Magnetic properties of Mn linear nanochains on a bcc Fe(1 1 0) surface have been studied using the first-principles real space-linear muffin-tin orbital atomic sphere approximation (RS-LMTO-ASA) method. We have considered up to nine Mn atoms deposited on bcc Fe(1 1 0). Our ab initio calculations reveal the competition between the antiferromagnetic Mn-Mn and Mn-Fe couplings, presenting a behavior which is very different from Mn nanowires on Fe(0 0 1), as shown in a previous publication. Due to this competition and non-negligible Dzyaloshinskii-Moriya interaction, noncollinear magnetic structures are stabilized as ground states for the Mn nanochains on Fe(1 1 0). PMID:27346457

  10. Martensitic Transformation in Ni-Mn-Sn-Co Heusler Alloys

    Directory of Open Access Journals (Sweden)

    Alexandre Deltell

    2015-04-01

    Full Text Available Thermal and structural austenite to martensite reversible transition was studied in melt spun ribbons of Ni50Mn40Sn5Co5, Ni50Mn37.5Sn7.5Co5 and Ni50Mn35Sn10Co5 (at. % alloys. Analysis of X-ray diffraction patterns confirms that all alloys have martensitic structure at room temperature: four layered orthorhombic 4O for Ni50Mn40Sn5Co5, four layered orthorhombic 4O and seven-layered monoclinic 14M for Ni50Mn37.5Sn7.5Co5 and seven-layered monoclinic 14M for Ni50Mn35Sn5Co5. Analysis of differential scanning calorimetry scans shows that higher enthalpy and entropy changes are obtained for alloy Ni50Mn37.5Sn7.5Co5, whereas transition temperatures increases as increasing valence electron density.

  11. A Review of Indirect Bridge Monitoring Using Passing Vehicles

    Directory of Open Access Journals (Sweden)

    Abdollah Malekjafarian

    2015-01-01

    Full Text Available Indirect bridge monitoring methods, using the responses measured from vehicles passing over bridges, are under development for about a decade. A major advantage of these methods is that they use sensors mounted on the vehicle, no sensors or data acquisition system needs to be installed on the bridge. Most of the proposed methods are based on the identification of dynamic characteristics of the bridge from responses measured on the vehicle, such as natural frequency, mode shapes, and damping. In addition, some of the methods seek to directly detect bridge damage based on the interaction between the vehicle and bridge. This paper presents a critical review of indirect methods for bridge monitoring and provides discussion and recommendations on the challenges to be overcome for successful implementation in practice.

  12. Evaluating the life cycle environmental impact of short span bridges

    DEFF Research Database (Denmark)

    Du, Guangli; Pettersson, Lars; Karoumi, Raid

    2016-01-01

    Bridge infrastructure consumes large amount of energy and raw materials, leading to considerable environmental burdens. The traditional infrastructure construction prioritizes its technical and economic viability. In recent years, the society devotes an ever-increased attention to the environmental...... impact of the construction sector. Life cycle assessment (LCA) is a systematic method for assessing the environmental impact of products and systems, but its application in bridges is scarce. In Swede, most of the bridges are short spans and the type of concrete slab-frame bridge (CFB) accounts...... for a large share. Soil steel composite bridge (SSCB) is a functional equivalent solution for CFB. In order to mitigate the environmental burdens of short span bridges, this paper performed a comparative LCA study between these two types of bridge. The results indicate that the initial material consumption...

  13. Molecules at the Quantum-Classical Nanoparticle Interface: Giant Mn70 Single-Molecule Magnets of ∼4 nm Diameter.

    Science.gov (United States)

    Vinslava, Alina; Tasiopoulos, Anastasios J; Wernsdorfer, Wolfgang; Abboud, Khalil A; Christou, George

    2016-04-01

    Two Mn70 torus-like molecules have been obtained from the alcoholysis in EtOH and 2-ClC2H4OH of [Mn12O12(O2CMe)16(H2O)4]·4H2O·2MeCO2H (1) in the presence of NBu(n)4MnO4 and an excess of MeCO2H. The reaction in EtOH afforded [Mn70O60(O2CMe)70(OEt)20(EtOH)16(H2O)22] (2), whereas the reaction in ClC2H4OH gave [Mn70O60(O2CMe)70(OC2H4Cl)20(ClC2H4OH)18(H2O)22] (3). The complexes are nearly isostructural, each possessing a Mn70 torus structure consisting of alternating near-linear [Mn3(μ3-O)4] and cubic [Mn4(μ3-O)2(μ3-OR)2] (R = OEt, 2; R = OC2H4Cl, 3) subunits, linked together via syn,syn-μ-bridging MeCO2(-) and μ3-bridging O(2-) groups. 2 and 3 have an overall diameter of ∼4 nm and crystallize as highly ordered supramolecular nanotubes. Alternating current (ac) magnetic susceptibility measurements, performed on microcrystalline samples in the 1.8-10 K range and a 3.5 G ac field with oscillation frequencies in the 5-1500 Hz range, revealed frequency-dependent out-of-phase signals below ∼2.4 K for both molecules indicative of the slow magnetization relaxation of single-molecule magnets (SMMs). Single-crystal, magnetization vs field studies on both complexes revealed hysteresis loops below 1.5 K, thus confirming 2 and 3 to be new SMMs. The hysteresis loops do not show the steps that are characteristic of quantum tunneling of magnetization (QTM). However, low-temperature studies revealed temperature-independent relaxation rates below ∼0.2 K for both compounds, the signature of ground state QTM. Fitting of relaxation data to the Arrhenius equation gave effective barriers for magnetization reversal (Ueff) of 23 and 18 K for 2 and 3, respectively. Because the Mn70 molecule is close to the classical limit, it was also studied using a method based on the Néel-Brown model of thermally activated magnetization reversal in a classical single-domain magnetic nanoparticle. The field and sweep-rate dependence of the coercive field was investigated and yielded the energy

  14. Molecules at the Quantum-Classical Nanoparticle Interface: Giant Mn70 Single-Molecule Magnets of ∼4 nm Diameter.

    Science.gov (United States)

    Vinslava, Alina; Tasiopoulos, Anastasios J; Wernsdorfer, Wolfgang; Abboud, Khalil A; Christou, George

    2016-04-01

    Two Mn70 torus-like molecules have been obtained from the alcoholysis in EtOH and 2-ClC2H4OH of [Mn12O12(O2CMe)16(H2O)4]·4H2O·2MeCO2H (1) in the presence of NBu(n)4MnO4 and an excess of MeCO2H. The reaction in EtOH afforded [Mn70O60(O2CMe)70(OEt)20(EtOH)16(H2O)22] (2), whereas the reaction in ClC2H4OH gave [Mn70O60(O2CMe)70(OC2H4Cl)20(ClC2H4OH)18(H2O)22] (3). The complexes are nearly isostructural, each possessing a Mn70 torus structure consisting of alternating near-linear [Mn3(μ3-O)4] and cubic [Mn4(μ3-O)2(μ3-OR)2] (R = OEt, 2; R = OC2H4Cl, 3) subunits, linked together via syn,syn-μ-bridging MeCO2(-) and μ3-bridging O(2-) groups. 2 and 3 have an overall diameter of ∼4 nm and crystallize as highly ordered supramolecular nanotubes. Alternating current (ac) magnetic susceptibility measurements, performed on microcrystalline samples in the 1.8-10 K range and a 3.5 G ac field with oscillation frequencies in the 5-1500 Hz range, revealed frequency-dependent out-of-phase signals below ∼2.4 K for both molecules indicative of the slow magnetization relaxation of single-molecule magnets (SMMs). Single-crystal, magnetization vs field studies on both complexes revealed hysteresis loops below 1.5 K, thus confirming 2 and 3 to be new SMMs. The hysteresis loops do not show the steps that are characteristic of quantum tunneling of magnetization (QTM). However, low-temperature studies revealed temperature-independent relaxation rates below ∼0.2 K for both compounds, the signature of ground state QTM. Fitting of relaxation data to the Arrhenius equation gave effective barriers for magnetization reversal (Ueff) of 23 and 18 K for 2 and 3, respectively. Because the Mn70 molecule is close to the classical limit, it was also studied using a method based on the Néel-Brown model of thermally activated magnetization reversal in a classical single-domain magnetic nanoparticle. The field and sweep-rate dependence of the coercive field was investigated and yielded the energy

  15. Online Bridge Crack Monitoring with Smart Film

    Directory of Open Access Journals (Sweden)

    Benniu Zhang

    2013-01-01

    Full Text Available Smart film crack monitoring method, which can be used for detecting initiation, length, width, shape, location, and propagation of cracks on real bridges, is proposed. Firstly, the fabrication of the smart film is developed. Then the feasibility of the method is analyzed and verified by the mechanical sensing character of the smart film under the two conditions of normal strain and crack initiation. Meanwhile, the coupling interference between parallel enameled wires of the smart film is discussed, and then low-frequency detecting signal and the custom communication protocol are used to decrease interference. On this basis, crack monitoring system with smart film is designed, where the collected crack data is sent to the remote monitoring center and the cracks are simulated and recurred. Finally, the monitoring system is applied to six bridges, and the effects are discussed.

  16. Bridge Condition Assessment Using D Numbers

    Directory of Open Access Journals (Sweden)

    Xinyang Deng

    2014-01-01

    Full Text Available Bridge condition assessment is a complex problem influenced by many factors. The uncertain environment increases more its complexity. Due to the uncertainty in the process of assessment, one of the key problems is the representation of assessment results. Though there exists many methods that can deal with uncertain information, however, they have more or less deficiencies. In this paper, a new representation of uncertain information, called D numbers, is presented. It extends the Dempster-Shafer theory. By using D numbers, a new method is developed for the bridge condition assessment. Compared to these existing methods, the proposed method is simpler and more effective. An illustrative case is given to show the effectiveness of the new method.

  17. Accelerated aging of polymer composite bridge materials

    Science.gov (United States)

    Carlson, Nancy M.; Blackwood, Larry G.; Torres, Lucinda L.; Rodriguez, Julio G.; Yoder, Timothy S.

    1999-05-01

    Accelerated aging research on samples of composite materials and candidate UV protective coatings is determining the effects of six environmental factors on material durability. Candidate fastener materials are being evaluated to determine corrosion rates and crevice corrosion effects at load-bearing joints. This work supports field testing of a 30-ft long, 18-ft wide polymer matrix composite (PMC) bridge at the Idaho National Engineering and Environmental Laboratory. Durability results and sensor data form test with live loads provide information required for determining the cost/benefit measures to use in life-cycle planning, determining a maintenance strategy, establishing applicable inspection techniques, and establishing guidelines, standards and acceptance criteria for PMC bridges for use in the transportation infrastructure.

  18. Tacoma Bridge Failure-- a Physical Model

    CERN Document Server

    Green, D; Green, Daniel; Unruh, William G.

    2004-01-01

    The cause of the collapse of the Tacoma Narrows Bridge has been a topic of much debate and confusion since the day it fell. Many mischaracterizations of the observed phenomena have limited the widespread understanding of the problem. Nevertheless, there has always been an abundance of evidence in favour of a negative damping model. Negative damping, or positive feedback, is responsible for many large amplitude oscillations observed in many applications. In this paper, we will explain some well-known examples of positive feedback. We will then present a feedback model, derived from fundamental physics, capable of explaining a number of features observed in the instabilities of many bridge decks. This model is supported by computational, experimental and historical data.

  19. Fatigue-Prone Details in Steel Bridges

    Directory of Open Access Journals (Sweden)

    Mohsen Heshmati

    2012-11-01

    Full Text Available This paper reviews the results of a comprehensive investigation including more than 100 fatigue damage cases, reported for steel and composite bridges. The damage cases are categorized according to types of detail. The mechanisms behind fatigue damage in each category are identified and studied. It was found that more than 90% of all reported damage cases are of deformation-induced type and generated by some kind of unintentional or otherwise overlooked interaction between different load-carrying members or systems in the bridge. Poor detailing, with unstiffened gaps and abrupt changes in stiffness at the connections between different members were also found to contribute to fatigue cracking in many details.

  20. A liquid bridge connecting moving porous surfaces

    Science.gov (United States)

    Gharib, Morteza; Gat, Amir; Navaz, Homayun

    2011-11-01

    We study the coupled problem of a liquid bridge connecting two porous surfaces where the gap between the surfaces is an externally controlled function of time. The relative motion between the surfaces affects the geometry and the pressure distribution of the liquid bridge, thus influencing the diffusion speed and penetration topology within the porous material. Utilizing the lubrication approximation and Darcy's phenomenological law we obtain a relation between the diffusion into the porous surface and the relative motion between the surfaces. A scheme to control the diffusion topology is presented and illustrated for the case of conical penetration topology with an arbitrary cone opening angle. Analytic expressions describing the penetration topology for the case of constant speed of the surfaces and the relative motion between the surfaces required to create a conical penetration topology are obtained and compared to experimental and numerical data. This project was supported by the Defense Threat Reduction Agency (DTRA), Award Number: 330233-A.

  1. Martensitic transition of Mn-rich Pd-Mn-Sn alloy

    Energy Technology Data Exchange (ETDEWEB)

    Kanomata, T. [Faculty of Engineering, Tohoku Gakuin University, Tagajo 985-8537 (Japan); Department of Materials Science, Graduate School of Engineering, Tohoku University, Sendai 980-8579 (Japan); Chieda, Y.; Okada, H. [Faculty of Engineering, Tohoku Gakuin University, Tagajo 985-8537 (Japan); Nishihara, H. [Faculty of Science and Technology, Ryukoku University, Otsu 520-2194 (Japan); Kimura, A. [Graduate School of Science, Hiroshima University, Higashi-Hiroshima 739-8526 (Japan); Nagasako, M. [Department of Materials Science, Graduate School of Engineering, Tohoku University, Sendai 980-8579 (Japan); Umetsu, R.Y., E-mail: rieume@imr.tohoku.ac.jp [Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan); Kainuma, R. [Department of Materials Science, Graduate School of Engineering, Tohoku University, Sendai 980-8579 (Japan); Ziebeck, K.R.A. [Department of Physics, Cavendish Laboratory, University of Cambridge, CB3 0HE (United Kingdom)

    2012-11-15

    Highlights: Black-Right-Pointing-Pointer This is the first report of clear evidence of the martensitic transition in Pd-Mn-Sn new material. Black-Right-Pointing-Pointer Pd{sub 2}Mn{sub 1.46}Sn{sub 0.54} exhibits martensitic transition from ferromagnetic L2{sub 1} phase to paramagnetic 4O phase. Black-Right-Pointing-Pointer A smaller magnetic moment of Pd than that of Ni for other Ni-based shape memory alloys is suggested. - Abstract: A new magnetic shape memory alloy Pd{sub 2}Mn{sub 1.46}Sn{sub 0.54} has been synthesized. It was found that in the austenite phase Pd{sub 2}Mn{sub 1.46}Sn{sub 0.54} crystallizes in the L2{sub 1} structure. It was confirmed from the low temperature X-ray diffraction measurements that the martensite phase of Pd{sub 2}Mn{sub 1.46}Sn{sub 0.56} has an orthorhombic four-layered structure. The magnetization versus temperature curve of Pd{sub 2}Mn{sub 1.46}Sn{sub 0.54} is very similar to those of the Ni-Mn-Z (Z = In, Sn and Sb) magnetic shape memory alloys; the paramagnetic-ferromagnetic transition appears in the austenite phase with decreasing temperature. With further decrease of temperature, the magnetization and permeability decrease abruptly at the martensitic transition temperature. The martensite phase remains ferromagnetic at low temperatures.

  2. Bridging the Divide between Science and Journalism

    OpenAIRE

    Marincola Francesco M; Van Eperen Laura; Strohm Jennifer

    2010-01-01

    Abstract There are countless reasons nearly every scientist should learn how to communicate effectively with the media, including increased understanding of critical research findings to attract or sustain funding and build new professional partnerships that will further propel forward research. But where do scientists begin? Bridging the Divide between Science and Journalism offers practical tips for any scientist looking to work with the media. Given the traditional and internet-based sourc...

  3. Fatigue-Prone Details in Steel Bridges

    OpenAIRE

    Mohsen Heshmati; Mohammad Al-Emrani; Reza Haghani

    2012-01-01

    This paper reviews the results of a comprehensive investigation including more than 100 fatigue damage cases, reported for steel and composite bridges. The damage cases are categorized according to types of detail. The mechanisms behind fatigue damage in each category are identified and studied. It was found that more than 90% of all reported damage cases are of deformation-induced type and generated by some kind of unintentional or otherwise overlooked interaction between different load-carr...

  4. Design of bridges against large tectonic deformation

    Institute of Scientific and Technical Information of China (English)

    I.Anastasopoulost; G.Gazetas; V.Drosos; T.Georgarakos; R.Kourkoulis

    2008-01-01

    The engineering community has devoted much effort to understanding the response of soil-structure systems to seismic ground motions,but little attention to the effects of an outcropping fault offset.The 1999 earthquakes of Turkey and Taiwan,offering a variety of case histories of structural damage due to faulting,have (re)fueled the interest on the subject.This paper presents a methodology for design of bridges against tectonic deformation.The problem is decoupled in two analysis steps:the first (at the local level) deals with the response of a single pier and its foundation to fault rupture propagating through the soil,and the superstructure is modeled in a simplified manner;and the second (at the global level)investigates detailed models of the superstructure subjected to the support (differential) displacements of Step 1.A parametric study investigates typical models of viaduct and overpass bridges,founded on piles or caissons.Fixed-head piled foundations are shown to be rather vulnerable to faulting-induced deformation.End-bearing piles in particular are unable to survive bedrock offsets exceeding 10 cm.Floating piles perform better,and if combined with hinged pile-to-cap connections,they could survive much larger offsets.Soil resilience is beneficial in reducing pile distress.Caisson foundations are almost invariably successful.Statically-indeterminate superstructures are quite vulnerable,while statically-determinate are insensitive (allowing differential displacements and rotations without suffering any distress).For large-span cantilever construction bridges,where a statically determinate system is hardly an option,inserting resilient seismic isolation bearings is advantageous as long as ample seating can prevent the deck from falling off the supports.An actual application of the developed method is presented for a major bridge,demonstrating the feasibility of design against tectonic deformation.

  5. Bridge Inspections and Being an ERC

    OpenAIRE

    Hoernschemeyer, Keith; Miller, Jessica

    2015-01-01

    This presentation will discuss recent changes to the County Bridge Inspection Program from the perspective of both the FHWA and INDOT. We will also discuss the responsibilities of the local public agency’s (LPA’s) employee in responsible charge (ERC) with respect to managing this program. As this course is a yearly requirement, all county ERCs are encouraged to attend. Pre-registering is strongly encouraged by e-mailing your contact information to .

  6. Liquid bridge simulations with OpenFOAM

    OpenAIRE

    Guirao Aguilar, Guillermo

    2011-01-01

    Any liquid-gas interface being under a temperature gradient is subject to a thermocapillary flow generated by the differences in the surface tension. In the particular case of liquid bridges, this flow can evolve into a oscillatory or travelling flow known as hydrothermal wave. This works aims to achieve a better understanding of the formation of this kind of flow by means of computational fluid dynamics techniques using a specific software package. For that, a simplified model of the liquid ...

  7. Legendrian framings for two-bridge links

    CERN Document Server

    Baader, Sebastian

    2009-01-01

    We define the Thurston-Bennequin polytope of a two-component link as the convex hull of all pairs of integers that arise as framings of a Legendrian representative. The main result of this paper is a description of the Thurston-Bennequin polytope for two-bridge links. As an application, we construct non-quasipositive surfaces in $\\R^3$ all whose sub-annuli are quasipositive.

  8. Ether bridge formation in loline alkaloid biosynthesis

    OpenAIRE

    Pan, Juan; Bhardwaj, Minakshi; Faulkner, Jerome R.; Nagabhyru, Padmaja; Charlton, Nikki D.; Higashi, Richard M.; Miller, Anne-Frances; Young, Carolyn A; Grossman, Robert B.; Schardl, Christopher L

    2013-01-01

    Lolines are potent insecticidal agents produced by endophytic fungi of cool-season grasses. These alkaloids are composed of a pyrrolizidine ring system and an uncommon ether bridge linking carbons 2 and 7. Previous results indicated that 1-aminopyrrolizidine was a pathway intermediate. We used RNA interference to knock down expression of lolO, resulting in the accumulation of a novel alkaloid identified as exo-1-acetamidopyrrolizidine based on high-resolution MS and NMR. Genomes of endophytes...

  9. Bridging the Gap: Linking Simulation and Testing

    Energy Technology Data Exchange (ETDEWEB)

    Krajewski, Paul E.; Carsley, John; Stoudt, Mark R.; Hovanski, Yuri

    2012-09-01

    The Materials Genome Initiative (MGI) which is a key enabler for the Advanced Manufacturing Partnership, announced in 2011 by U.S. President Barack Obama, was established to accelerate the development and deployment of advanced materials. The MGI is driven by the need to "bridge the gap" between (I) experimental results and computational analysis to enable the rapid development and validation of new mateirals, and (II) the processes required to convert these materials into useable goods.

  10. Characterization of bottom sediment of Adam bridge for its mineral content by spectrochemical and ICP-OES techniques

    International Nuclear Information System (INIS)

    Adam's Bridge also known as Rama's Bridge or Rama Setu is a chain of limestone shoals, between Rameswaram Island, off the southeastern coast of Tamil Nadu, India, and Mannar Island, off the northwestern coast of Sri Lanka. Geological evidence suggests that this bridge is a former land connection between India and Sri Lanka. During this work mineral content in the sand sample collected from four different locations were evaluated by using spectrochemical techniques such as FAAS (Flame atomic absorption spectroscopy), FES(Florescence Emission Spectroscopy), ICP-OES (Inductive coupled plasma optical emission spectroscopy) and UV - Visible Spectrophotometry. Various major elements like SiO2 , Al2O3, Fe2O3, MgO, CaO , Na2O , K2O, minor elements like MnO, TiO2, P2O5 and trace elements like ZrO2; V2O5, PbO and U etc. Validation of analytical methodology and reliability of analytical results were carried out by the analysis of the standard reference material. Trace elements were estimated after the selective removal of silica using AAS and ICP-OES technique. (author)

  11. Bridge concrete deteriorating diagnosis by infrared thermography

    Science.gov (United States)

    Shibata, Hiroki; Fukuyama, Nobuhiro; Sakuma, Joji; Mochizuki, Jun; Kimura, Yukinori

    2006-04-01

    Bridge is indispensable as social overhead capital. In the past, concrete construction was believed to be semi-permanent. Actually, however, concrete is deteriorated by various factors including seawater damage, annual temperature change, etc. Therefore, it is now obvious that maintenance and management are essential to keep performance of the bridge. In Japan, we had many reports of using infrared thermography for diagnosis of building, mainly for delamination of tile and mortar used for surface of the building for more than 10 years. In recent years, infrared thermogrephy is more actively used for delamination of surface of the bridge. Passive method is usually used for open-air concrete structure diagnosis, which utilizes intraday environmental temperature change and/or radiation energy emitted from the sun which create delta-T of delamination portion of the concrete structure. It is very important to take thermal image at right conditions. Otherwise, you may easily fall onto false diagnosis. In our presentation, many case examples and study of thermal data will be shown, which are taken at the right condition.

  12. Effect of MnO2 morphology on the catalytic oxidation of toluene over Ag/MnO2 catalysts

    Science.gov (United States)

    Li, Jiamin; Qu, Zhenping; Qin, Yuan; Wang, Hui

    2016-11-01

    The Ag/MnO2 catalysts with different morphologies (wire-like, rod-like and tube-like) are used as toluene oxidation catalysts in an attempt to investigate how the structures of support affect the interaction of Ag and MnO2, and thus the toluene catalytic activity. Analysis by TEM, H2-TPR and XPS measurements reveals that the structures of MnO2 influence the particle size and dispersion of silver particles and the combination of silver particles with MnO2. Meanwhile, the addition of Ag regulates the performance of MnO2. The small particle size and hemispherically shaped Ag particles are easily to form and homogeneously dispersed on the surface of wire-like MnO2. And this specific form of Ag shows the strongest interaction with MnO2, which promotes the low-temperature reducibility of support and generated more lattice oxygen in metal oxides. The Ag/MnO2 nanowires sample exhibits the highest reactivity for toluene oxidation with a complete conversion at 220 °C. Therefore, the excellent catalytic performance of Ag/MnO2 nanowires catalyst for toluene oxidation is clearly connected with the interaction between the Ag and MnO2, which is determined by the morphology of MnO2 support.

  13. Core-shell Mn3O4/birnessite-MnO2 hierachical structure with enhanced adsorption towards methylene blue

    Science.gov (United States)

    Huang, Feifan; Zhou, Bowen; Xiao, Han; Xiao, Wei

    2016-01-01

    The core-shell Mn3O4/birnessite-MnO2 (Mn3O4/MnO2) was successfully established by assembly of birnessite-type MnO2 over Mn3O4 backbones. The product was characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM), as well as UV-vis absorption spectra (UV-vis) to assess its adsorption of methylene blue (MB) from neutral aqueous solutions. Compared to the individual Mn3O4, the prepared Mn3O4/MnO2 shows enhanced adsorption capability towards MB. Such enhancement is due to the higher surface area and the unique nanosheet shells. The adsorption of MB on the surface of Mn3O4/MnO2 was studied in terms of pseudo-first-order and the pseudo-second-order kinetic models, and the latter was found better. The present study indicates that hierarchically structured core-shell manganese oxides are promising adsorbents for wastewater treatment.

  14. Effect of MnSb clusters recharge on ferromagnetism in GaSb-MnSb thin films

    Science.gov (United States)

    Talantsev, A.; Koplak, O.; Morgunov, R.

    2016-07-01

    The concentration effect of charge carriers on the magnetic moment of ferromagnetic MnSb nanoclusters embedded in GaSbMn thin films is reported. High concentration of holes enhances the probability of their tunneling through the barrier between the semiconductor matrix and the MnSb nanocluster. Enrichment of the MnSb clusters by Mn2+ ions instead of Mn3+ enhances their ferromagnetism. Dynamics of magnetization relaxation of the MnSb clusters under applied magnetic field has been studied in the 8-300 K temperature range. Magnetic anisotropy constant ∼3.2·104 erg/cm3 has been determined. The fluctuation field HF = 7 Oe and the activation volume VA = 1.7·10-16 cm3 have been extracted from magnetic viscosity data.

  15. Building water bridges in air: Electrohydrodynamics of the Floating Water Bridge

    CERN Document Server

    Marin, Alvaro G

    2010-01-01

    The interaction of electrical fields and liquids can lead to phenomena that defies intuition. Some famous examples can be found in Electrohydrodynamics as Taylor cones, whipping jets or non-coalescing drops. A less famous example is the Floating Water Bridge: a slender thread of water held between two glass beakers in which a high voltage difference is applied. Surprisingly, the water bridge defies gravity even when the beakers are separated at distances up to 2 cm. In the presentation, experimental measurements and simple models are proposed and discussed for the stability of the bridge and the source of the flow, revealing an important role of polarization forces on the stability of the water bridge. On the other hand, the observed flow can only be explained due to the non negligible free charge present in the surface. In this sense, the Floating Water Bridge can be considered as an extreme case of a leaky dielectric liquid (J. R. Melcher and G. I. Taylor, Annu. Rev. Fluid Mech., 1:111, 1969).

  16. SMART BRIDGE: A tool for estimating the military load classification of bridges using varying levels of information

    Energy Technology Data Exchange (ETDEWEB)

    Van Groningen, C.N.; Paddock, R.A.

    1997-03-01

    A major consideration in planning and executing military deployments is determining the routes available for moving troops and equipment. Part of this planning ensures that all of the bridges along the routes can support the specialized equipment needed. Because few trained and experienced bridge analysts are available, and automated tool is required to help military engineers and planners quickly and accurately determine the capacity, or the military load classification, of bridges. However, because detailed information about each bridge may not always be available, the tool also needs to include alternative methods for estimating bridge capacities. SMART BRIDGE, developed by Argonne National Laboratory, provides this capacity. The tool consists of a collection of modules that interact with each other to accommodate various bridge types, analytical techniques, and database functions. 5 refs., 6 figs., 2 tabs.

  17. Hydrothermal Synthesis and Structure of a Novel 1-D Mn(Ⅱ) Compound with Carboxlyto and Imidazole Ligands

    Institute of Scientific and Technical Information of China (English)

    WANG Yu-De; WU Xing-Hui; ZENG Qing-Xin; YAO You-Wei

    2005-01-01

    A novel manganiferous polymeric complex [(imid)2(ta)Mn0.5]n (imid = imidazole, ta = terephthalato) was synthesized by the hydrothermal reaction of MnO2, terephthalic acid, imidazole, and H2O. Structure analysis indicates that the compound crystallizes in the triclinic system, space group P, with a = 8.1500(16), b = 8.5100(17), c = 9.0500(18) (A), α = 72.77(3), β = 65.50(3), γ = 77.22(3)°, V = 542.02(19) (A)3, Z = 2, Dc = 1.505 g/cm3, F(000) = 253, Mr = 245.69, μ(MoKα = 0.655 mm-1, R = 0.0733 and wR = 0.1703 for 1673 observed reflections (I > 2σ(I)). The compound is characteristic of a zigzag chain-like framework built up of ta bridge and (Imid)4Mn group. The 1-D frameworks are held together by H-bonds between the dangling N-H donors from imid and O acceptors from ta.

  18. Internal bremsstrahlung endpoint energy of 54Mn

    International Nuclear Information System (INIS)

    For 54Mn there is a discrepancy between the QEC obtained from the endpoint energy of the internal bremsstrahlung (IB) spectrum which accompanies the electron capture decay (QEC=1353±8 keV) and that obtained from the accepted mass differences (QEC=1377±1 keV). This Q value is needed to deduce the partial-half life of the astrophysically interesting β- decay of 54Mn from the recently measured β+ partial half-life. To resolve this discrepancy, we have remeasured the endpoint energy of the IB spectrum, by recording coincidences between the IB and the 835-keV γ ray, both detected in Compton-suppressed Ge detectors. The QEC we deduce is 1379±8 keV, in agreement with the accepted mass differences. (c) 2000 The American Physical Society

  19. The Internet Inter-Orb Protocol Security Bridge

    Directory of Open Access Journals (Sweden)

    Pawel Slowikowski

    1999-01-01

    Full Text Available In this paper, we present a security bridge for the Internet protocol of interoperability amongst CORBA objects and the Internet inter-ORB Protocol (IIOP. The bridge helps in making accessible objects in the Internet and makes possible the access control to them. The bridge was realized in the popular request broker the Visigenic's VisiBroker under Windows 95/NT and Solaris 2.X operating systems. We describe two ways of locating the bridge in the request broker. The first means uses one name domain of broker and is not transparent for client. The second one uses two name domains and provides objects protection on the level of the Naming Service and is transparent lor the client. We also describe the variant ofthe second means with using GateKeeper server to support IIOP tunneling within HTTP. We emphasize the importance of a firewall, cooperating with a bridge. which is required for the purpose of providing object protection. The paper presents an original conception of security managing, basing on the ideas of users, groups and resources defined using the standard terms of CORBA, IIOP and TCP/IP, that allows to control positively and negatively the access to classes (interfaces, objects and also to their individual methods. This conception was effectively implemented in a functioning bridge. Further chapters describe the foundations and some details of the bridge implementation sueli as the use ofthe Interface Repository, cache memory application, thread synchronization and the way of synchronization of the configuration applet with the bridge's objects. We discuss the influence of these solutions on the efficiency ofthe bridge and its source code portability. We also present the general structure of the component objects ofthe bridge with a scheme. ln the next part we characterize the implementation foundations ofthe bridge manager, realized as an applet in Java, with the stress on the possibility of the bridge configuration through the

  20. Bridges analysis, design, structural health monitoring, and rehabilitation

    CERN Document Server

    Bakht, Baidar

    2015-01-01

    This book offers a valuable guide for practicing bridge engineers and graduate students in structural engineering; its main purpose is to present the latest concepts in bridge engineering in fairly easy-to-follow terms. The book provides details of easy-to-use computer programs for: ·      Analysing slab-on-girder bridges for live load distribution. ·      Analysing slab and other solid bridge components for live load distribution. ·      Analysing and designing concrete deck slab overhangs of girder bridges under vehicular loads. ·      Determining the failure loads of concrete deck slabs of girder bridges under concentrated wheel loads. In addition, the book includes extensive chapters dealing with the design of wood bridges and soil-steel bridges. Further, a unique chapter on structural health monitoring (SHM) will help bridge engineers determine the actual load carrying capacities of bridges, as opposed to their perceived analytical capacities. The chapter addressing structures...

  1. Field Tests and Simulation of Lion-Head River Bridge

    Directory of Open Access Journals (Sweden)

    Yao-Min Fang

    2007-01-01

    Full Text Available Lion-Head River Bridge is a twin bridge in parallel position. The east-bounded was designed and constructed as a traditional prestress concrete box girder bridge with pot bearings; and the west-bounded was installed with seismic isolation devices of lead rubber bearings. The behavior of the isolated bridge is compared with that of the traditional bridge through several field tests including the ambient vibration test, the force vibration test induced by shakers, the free vibration test induced by a push and fast release system, and the truck test. The bridges suffered from various extents of damage due to the Chi-Chi and the Chi-I earthquakes of great strength during the construction and had been retrofitted. The damage was reflected by the change of the bridges' natural frequencies obtained from the ambient vibration tests. The models of the two bridges are simulated by the finite element method based on the original design drawings. Soil-structure interaction was also scrutinized in this study. The simulation was then modified based on the results from the field tests. Dynamic parameters of bridges are identified and compared with those from theoretical simulation. The efficiency is also verified to be better for an isolated bridge.

  2. Aerodynamic stability of cable-supported bridges using CFRP cables

    Institute of Scientific and Technical Information of China (English)

    ZHANG Xin-jun; YING Lei-dong

    2007-01-01

    To gain understanding of the applicability of carbon fiber reinforced polymer (CFRP) cable in cable-supported bridges, based on the Runyang Bridge and Jinsha Bridge, a suspension bridge using CFRP cables and a cable-stayed bridge using CFRP stay cables are designed, in which the cable's cross-sectional area is determined by the principle of equivalent axial stiffness.Numerical investigations on the aerodynamic stability of the two bridges are conducted by 3D nonlinear aerodynamic stability analysis. The results showed that as CFRP cables are used in cable-supported bridges, for suspension bridge, its aerodynamic stability is superior to that of the case using steel cables due to the great increase of the torsional frequency; for cable-stayed bridge,its aerodynamic stability is basically the same as that of the case using steel stay cables. Therefore as far as the wind stability is considered, the use of CFRP cables in cable-supported bridges is feasible, and the cable's cross-sectional area should be determined by the principle of equivalent axial stiffness.

  3. A cloud-based information repository for bridge monitoring applications

    Science.gov (United States)

    Jeong, Seongwoon; Zhang, Yilan; Hou, Rui; Lynch, Jerome P.; Sohn, Hoon; Law, Kincho H.

    2016-04-01

    This paper describes an information repository to support bridge monitoring applications on a cloud computing platform. Bridge monitoring, with instrumentation of sensors in particular, collects significant amount of data. In addition to sensor data, a wide variety of information such as bridge geometry, analysis model and sensor description need to be stored. Data management plays an important role to facilitate data utilization and data sharing. While bridge information modeling (BrIM) technologies and standards have been proposed and they provide a means to enable integration and facilitate interoperability, current BrIM standards support mostly the information about bridge geometry. In this study, we extend the BrIM schema to include analysis models and sensor information. Specifically, using the OpenBrIM standards as the base, we draw on CSI Bridge, a commercial software widely used for bridge analysis and design, and SensorML, a standard schema for sensor definition, to define the data entities necessary for bridge monitoring applications. NoSQL database systems are employed for data repository. Cloud service infrastructure is deployed to enhance scalability, flexibility and accessibility of the data management system. The data model and systems are tested using the bridge model and the sensor data collected at the Telegraph Road Bridge, Monroe, Michigan.

  4. Disulfide Bridges: Bringing Together Frustrated Structure in a Bioactive Peptide.

    Science.gov (United States)

    Zhang, Yi; Schulten, Klaus; Gruebele, Martin; Bansal, Paramjit S; Wilson, David; Daly, Norelle L

    2016-04-26

    Disulfide bridges are commonly found covalent bonds that are usually believed to maintain structural stability of proteins. Here, we investigate the influence of disulfide bridges on protein dynamics through molecular dynamics simulations on the cysteine-rich trypsin inhibitor MCoTI-II with three disulfide bridges. Correlation analysis of the reduced cyclic peptide shows that two of the three disulfide distances (Cys(11)-Cys(23) and Cys(17)-Cys(29)) are anticorrelated within ∼1 μs of bridge formation or dissolution: when the peptide is in nativelike structures and one of the distances shortens to allow bond formation, the other tends to lengthen. Simulations over longer timescales, when the denatured state is less structured, do not show the anticorrelation. We propose that the native state contains structural elements that frustrate one another's folding, and that the two bridges are critical for snapping the frustrated native structure into place. In contrast, the Cys(4)-Cys(21) bridge is predicted to form together with either of the other two bridges. Indeed, experimental chromatography and nuclear magnetic resonance data show that an engineered peptide with the Cys(4)-Cys(21) bridge deleted can still fold into its near-native structure even in its noncyclic form, confirming the lesser role of the Cys(4)-Cys(21) bridge. The results highlight the importance of disulfide bridges in a small bioactive peptide to bring together frustrated structure in addition to maintaining protein structural stability. PMID:27119635

  5. Construction and control technology of the main bridge superstructure of Sutong Bridge

    Institute of Scientific and Technical Information of China (English)

    Zhang Hong; Luo Chenbin; Zhang Yongtao; You Xinpeng

    2009-01-01

    The Sutong Yangtze River Bridge (short as Sutong Bridge) is now the largest span cable-stayed bridge in the world. The construction of the superstructure of the middle bridge covered several stages including erection of the big block girders for the side span, assistant span and tower area, erection of standard girders and closure of the middle span. The big block girders were hoisted by a floating crane, and the standard girders were hoisted by a double crane system on the deck. The pushing assistant method was adopted for the middle span closure construction. Furthermore, key technologies and innovative methods used in the processes of girder erection and cable assemblage in all stages were expatiated systematically. An all-stage self- adaptive geometry control method was used in the construction process. By accurately controlling the unstressed dimensions and shape of all structural components in each step, and realization that the control system and the controlled system adapt to each other, the goal was to make control of the final line shape and inner force of the bridge structure achievable. Two solutions, including GPS based and total station based dynamic geometry monitoring systems, were used to resolve the measure problem under the wide-range of wind-induced vibrations in the long cantilever state. Finally, research on the wind-induced vibration of the superstructure during the construction period was executed. Buffeting response analysis to the longest single and double cantilever states were carried out. The analysis and evaluation of wind resistance safety of the main girders under the longest single cantilever state was made, and corresponding wind resistance measures were suggested. The as-built geometric error and cable force error were controlled in a required design range, and this whole technological achievement can be a benchmark for construction of other large span cable-stayed bridges in the future.

  6. Magnetic and electrical properties of epitaxial GeMn

    Energy Technology Data Exchange (ETDEWEB)

    Ahlers, Stefan

    2009-01-15

    In this work, GeMn magnetic semiconductors will be investigated. The fabrication of GeMn thin films with Mn contents up to 11.7% was realised with molecular beam epitaxy. At a fabrication temperature of 60 C, the suppression of Mn{sub x}Ge{sub y} phases could reproducibly be obtained. Dislocation free epitaxy of diamond-lattice type GeMn thin films was observed. In all fabrication conditions where Mn{sub x}Ge{sub y} suppression was feasible, an inhomogeneous dispersion of Mn was observed in form of a self-assembly of nanometre sized, Mn rich regions in a Ge rich matrix. Each Mn rich region exhibits ferromagnetic coupling with high Curie temperatures exceeding, in part, room temperature. The local ferromagnetic ordering leads to the formation of large, spatially separated magnetic moments, which induce a superparamagnetic behaviour of the GeMn thin films. At low temperatures {<=} 20 K, remanent behaviour was found to emerge. X-ray absorption experiments revealed a similarity of the Mn incorporation in diamond-lattice type GeMn thin films and in the hexagonal lattice of the intermetallic Mn{sub 5}Ge{sub 3} phase, respectively. These tetrahedra represent building blocks of the Mn{sub 5}Ge{sub 3} unit cell. The incorporation of Mn{sub 5}Ge{sub 3} building blocks was found to be accompanied by local structural disorder. The electrical properties of GeMn thin films were addressed by transport measurements. It was shown that by using a n-type Ge substrate, a pn energy barrier between epilayers and substrate to suppress parallel substrate conduction paths can be introduced. With the pn barrier concept, first results on the magnetotransport behaviour of GeMn thin films were obtained. GeMn was found to be p-type, but of high resistivity. a series of GeMn thin films was fabricated, where intermetallic Mn{sub x}Ge{sub y} phase separation was supported in a controlled manner. Phase separation was found to result in the formation of partially coherent, nanometre sized Mn{sub 5

  7. ZnSe-ZnMnSe and CdTe-CdMnTe superlattices

    Science.gov (United States)

    Gunshor, R. L.; Kolodziejski, L. A.; Otsuka, N.; Datta, S.

    1986-08-01

    We report the growth and characterization of superiattices of a new wide-gap, zincblende material system, Zn 1 - xMn xSe. ZnSe exhibiting dominant free excitonic emission in photoluminescence (PL) is the well material, while wider-band-gap Zn 1 - xMn xSe (0.23 efficiency compared to films of the ZnSe well material, while transmission electron microscopy shows extremely abrupt interfaces by the presence of seventh-order satellite spots. Previously reported superiattices in the CdTe-CdMnTe material system were grown with the (111) orientation, and exhibit unique excitonic properties believed related to the (111) interfaces. Using various techniques to select (111) or (100) heteroepitaxy of CdTe on (100) GaAs, we report the first (100) superlattices of this material, and compare the optical properties to the previous (111) structures.

  8. GaAs:Mn nanowires grown by molecular beam epitaxy of (Ga,Mn)as at MnAs segregation conditions.

    Science.gov (United States)

    Sadowski, Janusz; Dłuzewski, Piotr; Kret, Sławomir; Janik, Elzbieta; Lusakowska, Elzbieta; Kanski, Janusz; Presz, Adam; Terki, Ferial; Charar, Salam; Tang, Dong

    2007-09-01

    GaAs:Mn nanowires were obtained on GaAs(001) and GaAs(111)B substrates by molecular beam epitaxial growth of (Ga,Mn)As at conditions leading to MnAs phase separation. Their density is proportional to the density of catalyzing MnAs nanoislands, which can be controlled by the Mn flux and/or the substrate temperature. After deposition corresponding to a 200 nm thick (Ga,Mn)As layer the nanowires are around 700 nm long. Their shapes are tapered, with typical diameters around 30 nm at the base and 7 nm at the tip. The wires grow along the 111 direction, i.e., along the surface normal on GaAs(111)B and inclined on GaAs(001). In the latter case they tend to form branches. Being rooted in the ferromagnetic semiconductor (Ga,Mn)As, the nanowires combine one-dimensional properties with the magnetic properties of (Ga,Mn)As and provide natural, self-assembled structures for nanospintronics.

  9. Optical properties of Mn doped ZnO films and wires synthesized by thermal oxidation of ZnMn alloy

    Energy Technology Data Exchange (ETDEWEB)

    Sima, M., E-mail: msima@infim.ro [National Institute of Materials Physics, 105bis Atomistilor Street, 077125 Magurele (Romania); Mihut, L. [National Institute of Materials Physics, 105bis Atomistilor Street, 077125 Magurele (Romania); Vasile, E. [University “Politehnica”of Bucharest, Faculty of Applied Chemistry and Material Science, Department of Oxide Materials and Nanomaterials, No. 1-7 Gh. Polizu Street, 011061 Bucharest (Romania); Sima, Ma.; Logofatu, C. [National Institute of Materials Physics, 105bis Atomistilor Street, 077125 Magurele (Romania)

    2015-09-01

    Mn doped ZnO films and wires, having different manganese concentrations were synthesized by thermal oxidation of the corresponding ZnMn alloy films and wires electrodeposited on a gold substrate. Structural and optical properties were addressed with scanning electron microscopy, X-ray diffraction (XRD), Raman scattering and photoluminescence (PL). To estimate the manganese concentration in Mn doped ZnO films, X-ray photoelectron spectroscopy was used. XRD patterns indicate that the incorporation of Mn{sup 2+} ions into the Zn{sup 2+} site of ZnO lattice takes place. Quenching of the ZnO PL appears due to Mn{sup 2+} ions in the ZnO lattice. Moreover, a significant decrease in the green emission of ZnO is reported in the case of the Mn doped ZnO wire array with a Mn concentration of 1.45%. The wurtzite ZnO has a total of 12 phonon modes, namely, one longitudinal acoustic (LA), two transverse acoustic (TA), three longitudinal optical (LO), and six transverse optical branches. Compared to the undoped ZnO, a gradual up-shift of the Raman lines assigned to the 2LA and A{sub 1} (LO) vibrational modes, from 482 and 567 cm{sup −1} to 532 and 580 cm{sup −1}, respectively, takes place for the Mn doped ZnO films having a Mn concentration between 2 and 15%. Additionally, in the case of the Mn doped ZnO films with 7 and 15% Mn concentration, Raman spectra show the appearance and increase in the relative intensity of the ZnO Raman line assigned to the TA + LO vibrational mode in the 600–750 cm{sup −1} spectral range. For the Mn-doped ZnO wires, the presence of the Raman line peaking at 527 cm{sup −1} confirms the insertion of Mn{sup 2+} ions in ZnO lattice. - Highlights: • Mn doped ZnO films and wires grown by thermal oxidation of ZnMn alloy • Incorporation of Mn{sup 2+} ions into Zn{sup 2+} site of ZnO lattice • Appearance of a strong Raman line in the spectral range 600–800 cm{sup −1} at high Mn concentration • Compensation of the oxygen vacancy at higher

  10. Investigation of Aerodynamic Interference of Double Deck Bridges

    Energy Technology Data Exchange (ETDEWEB)

    Sitek, M. A. [Argonne National Lab. (ANL), Argonne, IL (United States). Energy Systems Division. Transportation Research and Analysis Computing Center (TRACC); Bojanowski, C. [Argonne National Lab. (ANL), Argonne, IL (United States). Energy Systems Division. Transportation Research and Analysis Computing Center (TRACC); Lottes, S. A. [Argonne National Lab. (ANL), Argonne, IL (United States). Energy Systems Division. Transportation Research and Analysis Computing Center (TRACC)

    2016-05-01

    Construction of a twin bridge can be a cost effective and minimally disruptive way to increase capacity when an existing bridge is not near the end of its service life. With ever growing vehicular traffic, when demand approaches the capacity of many existing roads and bridges. Remodeling a structure with an insufficient number of lanes can be a good solution in case of smaller and less busy bridges. Closing down or reducing traffic on crossings of greater importance for the construction period, however, can result in major delays and revenue loss for commerce and transportation as well as increasing the traffic load on alternate route bridges. Multiple-deck bridges may be the answer to this issue. A parallel deck can be built next to the existing one, without reducing the flow. Additionally, a new bridge can be designed as a twin or multi-deck structure. Several such structures have been built throughout the United States, among them: - The New NY Bridge Project - the Tappan Zee Hudson River Crossing, - SR-182 Columbia River Bridge, - The Thaddeus Kosciusko Bridge (I-87), - The Allegheny River Bridge, Pennsylvania, which carries I76, - Fred Hartman Bridge, TX, see Figure 1.2. With a growing number of double deck bridges, additional, more detailed, studies on the interaction of such bridge pairs in windy conditions appears appropriate. Aerodynamic interference effects should be examined to assure the aerodynamic stability of both bridges. There are many studies on aerodynamic response of single deck bridges, but the literature on double-deck structures is not extensive. The experimental results from wind tunnels are still limited in number, as a parametric study is required, they can be very time consuming. Literature review shows that some investigation of the effects of gap-width and angle of wind incidence has been done. Most of the CFD computational studies that have been done were limited to 2D simulations. Therefore, it is desirable to investigate twin decks

  11. Increased micronucleus, nucleoplasmic bridge, nuclear bud frequency and oxidative DNA damage associated with prolactin levels and pituitary adenoma diameters in patients with prolactinoma.

    Science.gov (United States)

    Bitgen, N; Donmez-Altuntas, H; Bayram, F; Cakir, I; Hamurcu, Z; Diri, H; Baskol, G; Senol, S; Durak, A C

    2016-01-01

    Prolactinoma is the most common pituitary tumor. Most pituitary tumors are benign, but they often are clinically significant. We investigated cytokinesis-block micronucleus cytome (CBMN cyt) assay parameters and oxidative DNA damage in patients with prolactinoma to assess the relations among age, prolactin level, pituitary adenoma diameter and 8-hydroxy-2'-deoxyguanosine (8-OHdG) level in patients with prolactinoma. We investigated 27 patients diagnosed with prolactinoma and 20 age- and sex-matched healthy controls. We measured CBMN cyt parameters and plasma 8-OHdG levels in peripheral blood lymphocytes of patients with prolactinoma and controls. The frequencies of micronucleus (MN), nucleoplasmic bridge, nuclear bud, apoptotic and necrotic cells, and plasma 8-OHdG levels in patients with prolactinoma were significantly greater than controls. MN frequency was correlated positively with age, prolactin levels and pituitary adenoma diameters in patients with prolactinoma. The increased chromosomal and oxidative DNA damage, and the positive correlation between MN frequency, prolactin levels and pituitary adenoma diameters may be associated with increased risk of cancer in patients with prolactinoma, because increased MN frequency is a predictor of cancer risk. PMID:26720589

  12. C-Mn segregation and its effect on phase transformation and deformation in Fe-Mn-C alloys

    Institute of Scientific and Technical Information of China (English)

    朱瑞富; 吕宇鹏; 魏涛

    1997-01-01

    C-Mn segregation and its effect on phase transformation and plastic deformation in Fe-Mn-C alloys were studied through the calculation of valence electron structure, the microregion composition detection and TEM in-situ dynamic tensile deformation test The experimental results show that in Fe-8Mn-1.2C alloyed austenite, nA of units with C Mn involved is 3 98 times that of units without C involved and 1.4 times that of units with C involved; aCD of units with C-Mn involved is 2 21 times that of units with C involved. In Fe-Mn-C alloyed austenites, there exists microsegrcgation of C-Mn, forming the randomly distributed Fe-Mn-C atomic cluster segregation zone linked with the -C-Mn-C-Mn- strong bond network, which will effectively slow down the motion of atoms and retard the initiation of the slip system and the movement of dislocation, and thus will severely influence the phase transformation and deformation of the alloy

  13. Comparison of the magnetic properties of GeMn thin films through Mn L-edge x-ray absorption

    Energy Technology Data Exchange (ETDEWEB)

    Ahlers, S.; Stone, P.R.; Sircar, N.; Arenholz, E.; Dubon, O. D.; Bougeard, D.

    2009-08-04

    X-ray absorption spectroscopy of epitaxial GeMn thin films reveals an experimentally indistinguishable electronic configuration of Mn atoms incorporated in Ge{sub 1?x}Mn{sub x} nanoclusters and in precipitates of the intermetallic compound Mn{sub 5}Ge{sub 3}, respectively. However, the average magnetic response of thin films containing Ge{sub 1?x}Mn{sub x} nanoclusters is lower than the response of films containing Mn{sub 5}Ge{sub 3} precipitates. This reduced magnetic response of Ge{sub 1?x}Mn{sub x} nanoclusters is explained in terms of a fraction of Mn atoms being magnetically inactive due to antiferromagnetic coupling or the presence of structural disorder. A determination of the role of magnetically inactive Mn atoms in the self-assembly of the thermodynamically metastable Ge{sub 1?x}Mn{sub x} nanoclusters seems to be an essential ingredient for an enhanced control of this promising high Curie temperature magnetic semiconductor.

  14. Electrochemical properties of MnS-C and MnO-C composite powders prepared via spray drying process

    Science.gov (United States)

    Jeon, Kyung Min; Cho, Jung Sang; Kang, Yun Chan

    2015-11-01

    Spherical micron-sized MnS-C and MnO-C composite powders are successfully prepared by post-treating the spray-dried precursor powders. Dextrin, which is used as the carbon source material, plays a key role in the preparation of the composite powders with regular morphologies; the bare MnS and MnO powders prepared from the spray solution without dextrin have irregular morphologies. The MnS-C composite powders prepared from the spray solution containing 17 g L-1 of dextrin have mixed crystal structures of α- and γ-MnS phases. These powders exhibit superior electrochemical properties compared with those of their MnS and MnO-C counterparts. For example, at a current density of 0.5 A g-1, the MnO-C powders have a 100th-cycle discharge capacity of 321 mA h g-1; the corresponding discharge capacities of the MnS powders prepared from spray solutions containing 0, 17, and 50 g L-1 of dextrin are 501, 786, and 636 mA h g-1, respectively.

  15. Quantum tunnelling of magnetization in Mn12-ac studied by 55Mn NMR

    OpenAIRE

    Morello, A.; Bakharev, O. N.; Brom, H. B.; de Jongh, L.J.

    2002-01-01

    We present an ultra-low temperature study (down to T = 20 mK) of the nuclear spin-lattice relaxation (SLR) in the 55Mn nuclei of the molecular magnet Mn12-ac. The nuclear spins act as local probes for the electronic spin fluctuations, due to thermal excitations and to tunnelling events. In the quantum regime (below T = 0.75 K), the nuclear SLR becomes temperature-independent and is driven by fluctuations of the cluster's electronic spin due to the quantum tunnelling of magnetization in the gr...

  16. Grotrian diagrams for highly ionized manganese Mn VI through Mn XXV

    Energy Technology Data Exchange (ETDEWEB)

    Shirai, Toshizo [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment; Sugar, J.; Wiese, W.L.

    1997-07-01

    Grotrian diagrams are presented to provide graphical overviews for 1,535 spectral lines of highly ionized manganese, Mn VI through Mn XXV. In the usual diagram display such as that by Bashkin and Stoner (North-Holland, Amsterdam, 1975), the density of transitions is often too high to allow each transition to be drawn separately. Here in our modified diagrams, the transitions are also represented by lines connecting the upper and lower energy levels, but the lower energy levels are extended and repeated for successive configurations as needed. As a sequence, dense packing is avoided and all lines in a multiplet can be accommodated. (author)

  17. Direct injection of spin-polarized carriers across YBa2Cu3O7-–La0.3Ca0.7MnO3 interface at 77 K

    Indian Academy of Sciences (India)

    K V Upadhye; K Ganesh Kumara; S C Purandare; S P Pai; R Pinto

    2002-05-01

    We report here injection of spin-polarized carriers from a half-metallic La0.3-Ca0.7MnO3 (LCMO) colossal magnetoresistive (CMR) thin film into a high-temperature superconducting YBa2Cu3O7- (YBCO) thin film studied using a micro-bridge. The LCMO and YBCO films were grown on $\\langle 100\\rangle$ LaAlO3 (LAO) substrate sequentially using pulsed laser deposition (PLD). - measurements carried out at 77 K show that while normal critical current, $I^{n}_{c}$, of the micro-bridge is 80 mA, the critical current, $I^{p}_{c}$, through the micro-bridge when injected from the CMR layer is 38 mA. This clearly shows that spin-polarized quasiparticles injected from the CMR layer into the YBCO layer suppress the critical current of the superconductor via the pair-breaking phenomena.

  18. Structural safety monitoring for Nanjing Yangtze River Bridge

    Institute of Scientific and Technical Information of China (English)

    黄方林; 何旭辉; 陈政清; 曾储惠

    2004-01-01

    In order to evaluate objectively and accurately the integrity, safety and operating conditions in real time for the Nanjing Yangtze River Bridge, a large structural safety monitoring system was described. The monitoring system is composed of three parts: sensor system, signal sampling and processing system, and safety monitoring and assessment system. Combining theoretical analysis with measured data analysis, main monitoring contents and layout of measuring points were determined. The vibration response monitoring was significantly investigated. The main contents of safety monitoring on vibration response monitoring are vibration of the main body of the Nanjing Yangtze river bridge, collision avoidance of the bridge piers, vibration of girders on high piers for the bridge approach and earthquake. As a field laboratory, the safety monitorying system also provides information to investigate the unknown and indeterminate problems on bridge structures and specific environment around bridges.

  19. Development of a nondestructive evaluation method for FRP bridge decks

    Science.gov (United States)

    Brown, Jeff; Fox, Terra

    2010-05-01

    Open steel grids are typically used on bridges to minimize the weight of the bridge deck and wearing surface. These grids, however, require frequent maintenance and exhibit other durability concerns related to fatigue cracking and corrosion. Bridge decks constructed from composite materials, such as a Fiber-reinforced Polymer (FRP), are strong and lightweight; they also offer improved rideability, reduced noise levels, less maintenance, and are relatively easy to install compared to steel grids. This research is aimed at developing an inspection protocol for FRP bridge decks using Infrared thermography. The finite element method was used to simulate the heat transfer process and determine optimal heating and data acquisition parameters that will be used to inspect FRP bridge decks in the field. It was demonstrated that thermal imaging could successfully identify features of the FRP bridge deck to depths of 1.7 cm using a phase analysis process.

  20. Detection of Subsurface Defects in Concrete Bridge Deck Joints

    Directory of Open Access Journals (Sweden)

    Wonchang Choi

    2011-01-01

    Full Text Available Problem statement: The integrity of deck joints in highway bridges plays a major role to determine overall performance of bridge system. As the bridge maintenance program, the defects in deck joints have historically been detected by conventional non-destructive testing and evaluation methods such as visual inspection, chain-dragging and by the detecting sounds under the traffic. Future bridge maintenance challenges will demand the development of techniques and procedures to detect and monitor such defects before they become apparent. Approach: Two non-destructive methods; namely Ground Penetration Radar (GPR and Seismic Properties Analyzer (SPA were employed to assess the integrity of deck joins installed in North Carolina bridges. Results: The results obtained with the GPR and SPA allows to quantify the subsurface defects in bridge deck joints. Conclusion: The practical application and limitations of each method are discussed in this study.

  1. Dynamic Vehicle Impact for Safety Assessment of Bridges

    DEFF Research Database (Denmark)

    Kirkegaard, Poul Henning; Nielsen, Søren R. K.; Enevoldsen, I.

    In this paper the dynamic amplification of vehicle load at minor highway bridges is considered for safety assessment of the load carrying capacity of bridges. The considered case is the most critical for bridges, i.e. the simultaneous passage of two heavy trucks. A short description...... of the numerical modal parameters of the bridge are known, Only irregularities from imperfect expansion joints have been modelled as bumps at the entrance to the bridge. The results are obtained from a simulation study for different passage situations of the two heavy vehicles. Further, consequences for the safety...... assessment of the bridge are outlined. The results actually obtained show that the dynamic amplification factors used in Danish ans several other national regulations are too conservative....

  2. Wind Tunnel Experiments with Active Control of Bridge Section Model

    DEFF Research Database (Denmark)

    Hansen, Henriette I.; Thoft-Christensen, Palle

    This paper describes results of wind tunnel experiments with a bridge section model where movable flaps are integrated in the bridge girder so each flap is the streamlined part of the edge of the girder. This active control flap system is patented by COWIconsult and may be used to increase the...... flutter wind velocity for future ultra-long span suspension bridges. The purpose of the wind tunnel experiments is to investigate the principle to use this active flap control system. The bridge section model used in the experiments is therefore not a model of a specific bridge but it is realistic...... compared with a real bridge. Five flap configurations are investigated during the wind tunnel experiments and depending on the actual flap configuration it is possible to decrease or increase the flutter wind velocity for the model....

  3. Impact of environmental chemistry on mycogenic Mn oxide minerals

    Science.gov (United States)

    Santelli, C. M.; Farfan, G. A.; Post, A.; Post, J. E.

    2012-12-01

    Manganese (Mn) oxide minerals are ubiquitous in aquatic and terrestrial environments and their presence can have broad environmental consequences. In particular, Mn oxides scavenge nutrients and metals, degrade complex organics, and oxidize a variety of inorganic contaminants. The "reactivity" of Mn oxides, however, is highly dependent upon crystallite size, composition, and structure, which are largely determined by environmental factors such as solution chemistry. It is has been suggested that most Mn oxides in terrestrial and aquatic environments are formed by microbial activity; indeed, a diversity of Mn(II)-oxidizing bacteria and fungi have been isolated and their mineral byproducts are consistent with those observed in natural systems. Previous studies showed that Mn(II)-oxidizing Ascomycete fungi produce highly-disordered, nanocrystalline Mn oxides that are structurally similar to synthetic δ-MnO2 or natural vernadite. Unlike related studies with Mn-oxidizing bacteria, Mn oxides produced by these fungi did not "age" or transform to more crystalline mineral phases with time. We hypothesize that fungal growth conditions, in particular the low concentration of cations, are inhibiting secondary mineral formation. The overall goal of this research is to examine the structure and speciation of fungally-precipitated Mn oxides with respect to fungal species, time, and concentration of soluble Mn(II), Na, and Ca - three environmentally relevant cations that promote the transformation of δ-MnO2 to more crystalline mineral phases such as feitknechtite, birnessite, or ranciéite. For this study, we examined the Mn oxides formed by different species of Mn(II)-oxidizing fungi (Pyrenochaeta sp., Stagonospora sp., Plectosphaerella cucumerina., and Acremonium strictum). Isolates were grown for 8 or 16 days in a nutrient lean media consisting of yeast extract, trace elements and 0.2 mM MnCl2 supplemented with varying concentrations of Na, Ca, or Mn(II) compounds. The

  4. Electroanalysis of Mn(Ⅱ) to Mn(Ⅲ)on Pb-Sb-As electrode%Pb-Sb-As电极上Mn(Ⅱ)电解生成Mn(Ⅲ)的研究

    Institute of Scientific and Technical Information of China (English)

    李淑芹; 闫雷; 周定

    2002-01-01

    以Pb-Sb-As合金为电极,进行电解Mn(Ⅱ)生成/Mn(Ⅲ)的研究.探讨了温度、电流密度、电解时间、阴阳极面积比等对电流效率的影响.结果表明,室温下电流密度45~60 mA/cm2,电解时间为45~60 min,阴阳面积比为1∶1.5时,Mn(Ⅱ)电解生成/Mn(Ⅲ)的电流效率可达85%以上.为进一步利用Mn(Ⅲ)/Mn(Ⅱ)循环媒质间接电合成芳香醛奠定了基础.

  5. H-BONDING SELF-ASSEMBLED TEMPLATE-CONTROLLED SYNTHESIS OF A NOVEL SOLUBLE AND REACTIVE AMIDE-BRIDGED LADDERLIKE POLYHYDROSILOXANE

    Institute of Scientific and Technical Information of China (English)

    Guan-qun Zhong; Qing-hua Duan; Kui-lin Deng; Ai-qin Zhang; Ping Xie; Hai-liang Zhang; Rong-ben Zhang

    2006-01-01

    A novel soluble and reactive amide-bridged ladderlike polyhydrosiloxane (ALPHS) was first synthesized by an amido H-bonding self-assembled template. ALPHS with molecular weight M-n = 18300 has very highly ordered ladderlike structure, which was confirmed by a sharp resonance absorption peak of [-Si(H)O2/2 ] moiety with the half peak width A1/2 < 0.5 in 29Si-NMR spectrum. Presence of the reactive Si-H groups gives ALPHS an opportunity to further derive a variety of functional polymers by versatile Si-H reactions such as hydrosilylation, condensation, and so on.

  6. Salt bridge as a gatekeeper against partial unfolding.

    Science.gov (United States)

    Hinzman, Mark W; Essex, Morgan E; Park, Chiwook

    2016-05-01

    Salt bridges are frequently observed in protein structures. Because the energetic contribution of salt bridges is strongly dependent on the environmental context, salt bridges are believed to contribute to the structural specificity rather than the stability. To test the role of salt bridges in enhancing structural specificity, we investigated the contribution of a salt bridge to the energetics of native-state partial unfolding in a cysteine-free version of Escherichia coli ribonuclease H (RNase H*). Thermolysin cleaves a protruding loop of RNase H(*) through transient partial unfolding under native conditions. Lys86 and Asp108 in RNase H(*) form a partially buried salt bridge that tethers the protruding loop. Investigation of the global stability of K86Q/D108N RNase H(*) showed that the salt bridge does not significantly contribute to the global stability. However, K86Q/D108N RNase H(*) is greatly more susceptible to proteolysis by thermolysin than wild-type RNase H(*) is. The free energy for partial unfolding determined by native-state proteolysis indicates that the salt bridge significantly increases the energy for partial unfolding by destabilizing the partially unfolded form. Double mutant cycles with single and double mutations of the salt bridge suggest that the partially unfolded form is destabilized due to a significant decrease in the interaction energy between Lys86 and Asp108 upon partial unfolding. This study demonstrates that, even in the case that a salt bridge does not contribute to the global stability, the salt bridge may function as a gatekeeper against partial unfolding that disturbs the optimal geometry of the salt bridge. PMID:26916981

  7. Abutments influence in the dynamic response of bridges

    OpenAIRE

    Martínez Cutillas, Antonio; Gómez Lera, Sagrario; Alarcón Álvarez, Enrique

    1996-01-01

    A simplified analytical model of a short span bridge is proposed. The inertial interaction effects of pier foundations and abutments has been included in order to evaluate the response sensitivities to different soil-structure interaction variables. The modification of natural frequency and damping properties is shown for typical short span bridges of the integral deck-abutment type for longitudinal vibrations or general bridges for the transverse ones.

  8. Experiences with a two terminal-pair digital impedance bridge

    OpenAIRE

    Callegaro, Luca; D'Elia, Vincenzo; Kampik, Marian; Kim, Dan Bee; Ortolano, Massimo; Pourdanesh, Faranak

    2014-01-01

    This paper describes the realization of a two terminal-pair digital impedance bridge and the test measurements performed with it. The bridge, with a very simple architecture, is based on a commercial two-channel digital signal synthesizer and a synchronous detector. The bridge can perform comparisons between impedances having arbitrary phase and magnitude ratio: its balance is achieved automatically in less than a minute. $R$-$C$ comparisons with calibrated standards, at kHz frequency and 100...

  9. Force generated by actomyosin contraction builds bridges between adhesive contacts

    OpenAIRE

    Rossier, Olivier M.; Gauthier, Nils; Biais, Nicolas; Vonnegut, Wynn; Fardin, Marc-Antoine; Avigan, Philip; Heller, Evan R; Mathur, Anurag; Ghassemi, Saba; Koeckert, Michael S; Hone, James C.; Sheetz, Michael P.

    2010-01-01

    Extracellular matrices in vivo are heterogeneous structures containing gaps that cells bridge with an actomyosin network. To understand the basis of bridging, we plated cells on surfaces patterned with fibronectin (FN)-coated stripes separated by non-adhesive regions. Bridges developed large tensions where concave cell edges were anchored to FN by adhesion sites. Actomyosin complexes assembled near those sites (both actin and myosin filaments) and moved towards the centre of the non-adhesive ...

  10. Jointless and Smoother Bridges: Behavior and Design of Piles

    OpenAIRE

    Frosch, Robert J; Chovichien, Voraniti; Durbin, Katrinna; Fedroff, David

    2006-01-01

    Integral abutment bridges have been used in the United States for decades. By eliminating expensive expansion joints, the piles supporting the end bent accommodate the total thermal movement of the bridge. Currently, integral bridges are designed based upon experience, and a rational design specification has not been developed. Furthermore, the interaction of the abutment, pile, and soil remains uncertain. A better understanding regarding the behavior of this system is needed. The objective o...

  11. The number of capillary bridges in a wet granular medium

    OpenAIRE

    Geromichalos, Dimitrios; Kohonen, Mika M.; Scheel, Mario; Herminghaus, Stephan

    2003-01-01

    We observed the appearance of capillary bridges in a granular medium consisting of glass beads after adding small amounts of liquid. We found the initial bridge formation depending on the bead roughness. Furthermore we obtained a statistics for the average number of bridges for randomly packed beads in dependence of the liquid content and were able to find an explanation therefore based on recent models and former experimental data.

  12. Electron Transfer rate between a electrode and a bridged redox

    OpenAIRE

    Cruz, A. V. B.; Mishra, A. K.; Schmickler, W.

    2009-01-01

    We derive an explict bias dependent expression for electron transfer reaction rate from a solvated redox to a electrode through a bridged molecule of arbitrary length. The interaction of the solvated redox with the solvent is modelled as a classical harmonic oscillator bath. The effect of competing process, namely resonance tunneling between redox and bridge and the solvation of the redox is investigated. Plots were produced for the case of 5 atom bridge. Our analysis shows that for certain s...

  13. Magneto-Structural Correlations in [Mn3O]7+ Core SMMs and Selected 4d, 5d and 4f SMMs

    DEFF Research Database (Denmark)

    Sigrist, Marc

    in spite of that, peaks in the out-of-phase components of the Ac susceptibility χ can be observed if a small magnetic field is applied. Furthermore, chains with reoccurring motif M(viz)4[ReF6] (M = Zn, Ni) have been synthesized and the intra-chain exchange coupling parameter for the Ni(viz)4[ReF6] chain...... of enhancing the effective barrier height Ueff by alignment of the single center anisotropy axes were studied. The alignment was achieved by exchanging a bridging tripodal ligand ClO4 - with the larger analogue ReO4 . This has already been attempted once [2], but the effect could not be observed due to a lack...... by a combination of the single center anisotropies. Chapter 5 shows the results of other trinuclear compounds. Instead of the triangular Mn3 SMMs, the molecules are linear, heterometallic Mn(III)-M(III)-Mn(III) (M = Ir, Ru, Os). The SMMs of the form (NEt4)[Mn2(5-Brsalen)2(MeOH)2M(CN)6] has a Schiff-base ligand...

  14. X-ray Damage to the Mn4Ca Complex in Single Crystals ofPhotosystem II: A Case Study for Metalloprotein Crystallography

    Energy Technology Data Exchange (ETDEWEB)

    Yano, Junko; Kern, Jan; Irrgang, Klaus-Dieter; Latimer, Matthew; Bergmann, Uwe; Glatzel, Pieter; Pushkar, Yulia; Biesiadka, Jacek; Loll,Bernhard; Sauer, Kenneth; Messinger, Johannes; Zouni, Athina; Yachandra,Vittal K.

    2005-06-21

    X-ray absorption spectroscopy was used to measure the damage caused by exposure to X-rays to the Mn4Ca active site in single crystals of photosystem II, as a function of dose and energy of X-rays, temperature, and time. These studies reveal that the conditions used for structure determination by X-ray crystallography cause serious damage specifically to the metal-site structure. The X-ray absorption spectra show that the structure changes from one that is characteristic of a high-valent Mn4(III2,IV2) oxo-bridged Mn4Ca cluster, to that of Mn(II) in aqueous solution. This damage to the metal site occurs at a dose that is more than an order of magnitude lower than that resulting in loss of diffractivity, and commonly considered safe for protein crystallography. These results establish the first quantitative X-ray dose parameters applicable to redox-active metallo-proteins. This case study shows that a careful evaluation of the structural intactness of the active sites by spectroscopic techniques can validate structures derived from crystallography, and it can be a valuable complementary method before structure-function correlations of metallo-proteins can be made on the basis of high resolution X-ray crystal structures.

  15. X-ray damage to the Mn4Ca complex in single crystals of photosystem II: a case study for metalloprotein crystallography.

    Science.gov (United States)

    Yano, Junko; Kern, Jan; Irrgang, Klaus-Dieter; Latimer, Matthew J; Bergmann, Uwe; Glatzel, Pieter; Pushkar, Yulia; Biesiadka, Jacek; Loll, Bernhard; Sauer, Kenneth; Messinger, Johannes; Zouni, Athina; Yachandra, Vittal K

    2005-08-23

    X-ray absorption spectroscopy was used to measure the damage caused by exposure to x-rays to the Mn(4)Ca active site in single crystals of photosystem II as a function of dose and energy of x-rays, temperature, and time. These studies reveal that the conditions used for structure determination by x-ray crystallography cause serious damage specifically to the metal-site structure. The x-ray absorption spectra show that the structure changes from one that is characteristic of a high-valent Mn(4)(III(2),IV(2)) oxo-bridged Mn(4)Ca cluster to that of Mn(II) in aqueous solution. This damage to the metal site occurs at a dose that is more than one order of magnitude lower than the dose that results in loss of diffractivity and is commonly considered safe for protein crystallography. These results establish quantitative x-ray dose parameters that are applicable to redox-active metalloproteins. This case study shows that a careful evaluation of the structural intactness of the active site(s) by spectroscopic techniques can validate structures derived from crystallography and that it can be a valuable complementary method before structure-function correlations of metalloproteins can be made on the basis of high-resolution x-ray crystal structures.

  16. Lattice constant in diluted magnetic semiconductors (Ga,Mn)As

    OpenAIRE

    J. Masek; Kudrnovsky, J.; Maca, F.

    2003-01-01

    We use the density-functional calculations to investigate the compositional dependence of the lattice constant of (Ga,Mn)As containing various native defects. The lattice constant of perfect mixed crystals does not depend much on the concentration of Mn. The lattice parameter increases if some Mn atoms occupy interstitial positions. The same happens if As antisite defects are present. A quantitative agreement with the observed compositional dependence is obtained for materials close to a comp...

  17. Magnetic anisotropy in GaMnAs; Magnetische Anisotropie in GaMnAs

    Energy Technology Data Exchange (ETDEWEB)

    Daeubler, Joachim

    2009-07-02

    The goal of the present work was the detailed investigation of the impact of parameters like vertical strain, hole concentration, substrate orientation and patterning on the MA in GaMnAs. At first a method is introduced enabling us to determine the MA from angle-dependent magnetotransport measurements. This method was used to analyze the impact of vertical strain {epsilon}{sub zz} on the MA in a series of GaMnAs layers with a Mn content of 5% grown on relaxed InGaAs-templates. While hole concentration and Curie temperature were found to be unaffected by vertical strain, a significant dependence of the MA on {epsilon}{sub zz} was found. The most pronounced dependence was observed for the anisotropy parameter B{sub 2} {sub perpendicular} {sub to}, representing the intrinsic contribution to the MA perpendicular to the layer plane. For this parameter a linear dependence on {epsilon}{sub zz} was found, resulting in a strain-induced transition of the magnetic easy axis with increasing strain from in-plane to out-of-plane at {epsilon}{sub zz} {approx} -0.13%. Post-growth annealing of the samples leads to an outdiffusion and/or regrouping of the highly mobile Mn interstitial donor defects, resulting in an increase in both p and T{sub C}. For the annealed samples, the transition from in-plane to out-of-plane easy axis takes place at {epsilon}{sub zz} {approx} -0.07%. From a comparison of as-grown and annealed samples, B{sub 2} {sub perpendicular} {sub to} was found to be proportional to both p and {epsilon}{sub zz}, B{sub 2} {sub perpendicular} {sub to} {proportional_to} p .{epsilon}{sub zz}. To study the influence of substrate orientation on the magnetic properties of GaMnAs, a series of GaMnAs layers with Mn contents up to 5% was grown on (001)- and (113)A-oriented GaAs substrates. The hole densities and Curie temperatures, determined from magnetotransport measurements, are drastically reduced in the (113)A layers. The differences in the magnetic properties of (113)A- and

  18. Commutation Processes in Multiresonant ZVS Bridge Converter

    Directory of Open Access Journals (Sweden)

    Miroslaw Luft

    2008-01-01

    Full Text Available The analysis of the multiresonant ZVS DC/DC bridge converter is presented. The control system of the converter is basedon the method of frequency control at the constant time of transistor turn-off with a phase shift. The operation of the circuit is givenand the operating range of the converter is defined where ZVS switching operation is assured. Control characteristics are given andthe converter’s efficiency is defined. The circuit’s operation is analysed on the basis of results of the converter simulation tests using Simplorer programme.

  19. Bridge connection of quantum Hall elementary devices

    CERN Document Server

    Callegaro, Luca

    2013-01-01

    Multiple-series and multiple-parallel connections of quantum Hall elementary devices allow the realization of multiple or fractional values of the quantized Hall resistance, rejecting the effect of contact and wiring resistances. We introduce here the multiple-bridge connection, which maintains the properties of multiple-series and parallel connections and allows more freedom in the choice of the topology of networks composed of quantum Hall elements, and the design of more efficient quantum Hall array resistance standards (and other devices). As an example, a 5-element network is analyzed in detail.

  20. Fatigue Performance of Bridge Deck Pavement Materials

    Institute of Scientific and Technical Information of China (English)

    WU Shaopeng; ZHANG Guang; HAN Jun; LIU Gang; ZHOU Jie

    2009-01-01

    Three beam samplesof bridge deck pavementwere prepared, with gradationtypes of AC-13, and AC-16 and combined AC-13+AC-16. Four-point bending test was adopted to investigate the fatigue performance of these beam samples. The experimental results indicate that the initial bending stiffness is related to the type of beam sample and testing temperature. Fatigue life of these samples decreases as the increase of the controlled strain level. The AC-13 beam sample exhibits better fatigue resistance and bigger limiting bending strain at the given strain level and temperature. Com-pared with single beam sample, the fatigue performance of combining beam sample is relatively poor.