Bogoliubov Excited States and the Lyth Bound
Aravind, Aditya; Paban, Sonia
2014-01-01
We show that Bogoliubov excited scalar and tensor modes do not alleviate Planckian evolution during inflation if one assumes that $r$ and the Bogoliubov coefficients are approximately scale invariant. We constrain the excitation parameter for the scalar fluctuations, $\\beta$, and tensor perturbations, $\\tilde{\\beta}$, by requiring that there be at least three decades of scale invariance in the scalar and tensor power spectrum. For the scalar fluctuations this is motivated by the observed nearly scale invariant scalar power spectrum. For the tensor fluctuations this assumption may be shown to be valid or invalid by future experiments.
Spinon and bound-state excitation light cones in Heisenberg XXZ chains
de Paula, A. L.; Bragança, H.; Pereira, R. G.; Drumond, R. C.; Aguiar, M. C. O.
2017-01-01
We investigate the out-of-equilibrium dynamics after a local quench that connects two spin-1/2 XXZ chains prepared in the ground state of the Hamiltonian in different phases, one in the ferromagnetic phase and the other in the critical phase. We analyze the time evolution of the on-site magnetization and bipartite entanglement entropy via adaptive time-dependent density matrix renormalization group. In systems with short-range interactions, such as the one we consider, the velocity of information transfer is expected to be bounded, giving rise to a light-cone effect. Interestingly, our results show that, when the anisotropy parameter of the critical chain is sufficiently close to that of the isotropic ferromagnet, the light cone is determined by the velocity of spin-wave bound states that propagate faster than single-particle ("spinon") excitations. Furthermore, we investigate how the system approaches equilibrium in the inhomogeneous ground state of the connected system, in which the ferromagnetic chain induces a nonzero magnetization in the critical chain in the vicinity of the interface.
Foley, M S; Beeby, A; Parker, A W; Bishop, S M; Phillips, D
1997-03-01
The binding of the sulphonated aluminum phthalocyanines to human serum albumin (HSA) in aqueous phosphate buffer solution at 25 degrees C has been studied by measuring the properties of the triplet excited states of these dyes. The triplet lifetimes were measured by triplet-triplet absorption flash photolysis. The triplet lifetime of the disulphonated AlS2Pc (2.5 microM) varies from 500 +/- 30 microseconds in the absence of protein to 1.100 microseconds and longer with HSA concentrations above 100 microM. Under identical conditions, the maximum triplet lifetimes of the mono-, tri- and tetrasulphonated compounds bound to HSA are shorter than those for the disulphonated species. The increase in the triplet state lifetimes is attributed to the ability of the bulk aqueous phase to interact with the sensitizer at the site of binding; the site of binding being dependent on the degree of sulphonation. For AlS2Pc and AlS3Pc at all HSA concentrations, and regardless of the degree of sulphonation, all the triplet state decay profiles follow simple pseudo-first-order kinetics. The exponential decay of the triplet phthalocyanine at all HSA concentrations is ascribed to the rapid association and dissociation of the phthalocyanine-HSA complex on the time-scales of the triplet state lifetimes. A simplified one-step binding model is utilized to describe the results. The association of AlS1Pc with HSA results in substantial quenching of the triplet state quantum yield, and a more complex model is required to analyze the results. The tetrasulphonated compound (AlS4Pc) binds to the protein at a site where it experiences some protection from the aqueous phase.
Modelling excited states of weakly bound complexes with density functional theory.
Briggs, Edward A; Besley, Nicholas A
2014-07-28
The binding within the ethene-argon and formaldehyde-methane complexes in the ground and electronically excited states is studied with equation of motion coupled cluster theory (EOM-CCSD), second-order Møller-Plesset perturbation theory (MP2) and density functional theory with dispersion corrections (DFT-D). Electronically excited states are studied within MP2 and Kohn-Sham DFT formalisms by exploiting a procedure called the maximum overlap method that allows convergence of the relevant self-consistent field equations to higher energy (or excited state) solutions. Potential energy curves computed using MP2 are in good agreement with the EOM-CCSD calculations for both the valence and Rydberg excited states studied. For the DFT-D approach, B3LYP-D3/aug-cc-pVTZ calculations are found to be in agreement with EOM-CCSD for the ground and valence excited states. However, for the π3s Rydberg state of ethene-argon and the n3s Rydberg state of formaldehyde-methane significant deviation is observed, and this disagreement with EOM-CCSD is present for a variety of DFT-D based approaches. Variation of the parameters within the D2 dispersion correction results in closer agreement with EOM-CCSD for the Rydberg states but demonstrates that a different parameterisation from the ground state is required for these states. This indicates that time-dependent density functional theory calculations based upon a DFT-D reference may be satisfactory for excitations to valence states, but will potentially be inaccurate for excitations to Rydberg states, or more generally states where the nature of the electron density is significantly different from the ground state.
Population of bound excited states in intermediate-energy fragmentation reactions
Obertelli, A; Bazin, D; Campbell, C M; Cook, J M; Cottle, P D; Davies, A D; Dinca, D C; Glasmacher, T; Hansen, P G; Hoagland, T; Kemper, K W; Lecouey, J L; Müller, W F; Reynolds, R R; Roeder, B T; Terry, J R; Tostevin, J A; Yoneda, K; Zwahlen, H
2006-01-01
Fragmentation reactions with intermediate-energy heavy-ion beams exhibit a wide range of reaction mechanisms, ranging from direct reactions to statistical processes. We examine this transition by measuring the relative population of excited states in several sd-shell nuclei produced by fragmentation with the number of removed nucleons ranging from two to sixteen. The two-nucleon removal is consistent with a non-dissipative process whereas the removal of more than five nucleons appears to be mainly statistical.
Lim, Edward C
1974-01-01
Excited States, Volume I reviews radiationless transitions, phosphorescence microwave double resonance through optical spectra in molecular solids, dipole moments in excited states, luminescence of polar molecules, and the problem of interstate interaction in aromatic carbonyl compounds. The book discusses the molecular electronic radiationless transitions; the double resonance techniques and the relaxation mechanisms involving the lowest triplet state of aromatic compounds; as well as the optical spectra and relaxation in molecular solids. The text also describes dipole moments and polarizab
Wilkinson, Iain; Boguslavskiy, Andrey E; Mikosch, Jochen; Bertrand, Julien B; Wörner, Hans Jakob; Villeneuve, David M; Spanner, Michael; Patchkovskii, Serguei; Stolow, Albert
2014-05-28
The excited state dynamics of isolated sulfur dioxide molecules have been investigated using the time-resolved photoelectron spectroscopy and time-resolved photoelectron-photoion coincidence techniques. Excited state wavepackets were prepared in the spectroscopically complex, electronically mixed (B̃)(1)B1/(Ã)(1)A2, Clements manifold following broadband excitation at a range of photon energies between 4.03 eV and 4.28 eV (308 nm and 290 nm, respectively). The resulting wavepacket dynamics were monitored using a multiphoton ionisation probe. The extensive literature associated with the Clements bands has been summarised and a detailed time domain description of the ultrafast relaxation pathways occurring from the optically bright (B̃)(1)B1 diabatic state is presented. Signatures of the oscillatory motion on the (B̃)(1)B1/(Ã)(1)A2 lower adiabatic surface responsible for the Clements band structure were observed. The recorded spectra also indicate that a component of the excited state wavepacket undergoes intersystem crossing from the Clements manifold to the underlying triplet states on a sub-picosecond time scale. Photoelectron signal growth time constants have been predominantly associated with intersystem crossing to the (c̃)(3)B2 state and were measured to vary between 750 and 150 fs over the implemented pump photon energy range. Additionally, pump beam intensity studies were performed. These experiments highlighted parallel relaxation processes that occurred at the one- and two-pump-photon levels of excitation on similar time scales, obscuring the Clements band dynamics when high pump beam intensities were implemented. Hence, the Clements band dynamics may be difficult to disentangle from higher order processes when ultrashort laser pulses and less-differential probe techniques are implemented.
Prediction of a weakly bound excited state of Efimov character in a 7LiHe42 system
Wu, Meng-Shan; Han, Hui-Li; Li, Cheng-Bin; Shi, Ting-Yun
2014-12-01
We carry out calculations on the van der Waals trimer 7LiHe42 using the mapping method within the frame of hyperspherical coordinates, which allows us to give accurate binding energies and wave functions for both the ground and excited state of the system. When the realistic two-body potentials are adopted, the system presents an excited state which shows Efimov character. We study the range of the interaction strength in which the excited state could exist and find that the state persists within the experiment error band for binding energy of LiHe molecule. We also study the three-body parameter (3BP) of 7LiHe42 system and its relationship with the background scattering length aHeHe. Our calculations demonstrate that the 3BP of 7LiHe42 system is dependent on the value of the scattering length aHeHe, independent of the short-range details of the He-He interaction. The results confirm the prediction of Wang et al. [Phys. Rev. Lett. 109, 243201 (2012), 10.1103/PhysRevLett.109.243201] that the 3BP for a heteronuclear atomic system is universally determined from the van der Waals lengths and the homonuclear scattering length.
Hoyer, Paul
2016-01-01
Even a first approximation of bound states requires contributions of all powers in the coupling. This means that the concept of "lowest order bound state" needs to be defined. In these lectures I discuss the "Born" (no loop, lowest order in $\\hbar$) approximation. Born level states are bound by gauge fields which satisfy the classical field equations. As a check of the method, Positronium states of any momentum are determined as eigenstates of the QED Hamiltonian, quantized at equal time. Analogously, states bound by a strong external field $A^\\mu(\\xv)$ are found as eigenstates of the Dirac Hamiltonian. Their Fock states have dynamically created $e^+e^-$ pairs, whose distribution is determined by the Dirac wave function. The linear potential of $D=1+1$ dimensions confines electrons but repels positrons. As a result, the mass spectrum is continuous and the wave functions have features of both bound states and plane waves. The classical solutions of Gauss' law are explored for hadrons in QCD. A non-vanishing bo...
Szybisz, Leszek
1996-03-01
Elementary excitations in rather thick symmetric films of liquid 4He at T=0 K are investigated. They are characterized by a momentum ħq parallel to the surface and may be described by bound or continuum states, which are obtained by solving a Bogoliubov-type equation formulated within the framework of the paired-phonon analysis and the hypernetted-chain approximation. Films of coverages nc=0.3 and 0.4 Å-2 confined by simple Gaussian potentials are studied. The excitation spectrum is numerically evaluated by discretizing the associated eigenvalue problem in a finite box. The evolution of the energy levels as a function of the box size is explored. Examples of the calculated energies and wave functions are displayed in a series of figures. Two differing sorts of continuum states may be distinguished. Depending on the behavior of their excitation energies as a function of the box size on the one hand, and the spatial distribution of their wave functions inside the film and in the asymptotic region far apart from the interface layer on the other, the continuum solutions can be separated into two classes of excitations: (a) the ``regular'' continuum states and (b) the ``resonant modes.'' The matrix elements of the particle-hole potential and the penetration factors of the most important states are examined. The lowest-lying branch of states is always bound and for q~qR the structure factor is determined by the contributions originated from the three lowest-lying even states. At q~=qR there is a dramatic transfer of strength from the bound continuation of the hardest ``resonant mode'' to the ripplon excitation. Experimental data of the inelastic structure factor S(q,ħω) may be satisfactorily interpreted on the basis of our calculation. On the other hand, it is shown that for 2.9<=q<=3.9 Å-1 the lowest-lying excitations become surface modes again.
Energy Technology Data Exchange (ETDEWEB)
Szybisz, L. [Laboratorio Tandem Argentino, Departamento de Fisica, Comision Nacional de Energia Atomica, Av. del Libertador 8250, RA-1429 Buenos Aires (Argentina)]|[Departamento de Fisica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, RA-1428 Buenos Aires (Argentina)
1996-03-01
Elementary excitations in rather thick symmetric films of liquid {sup 4}He at {ital T}=0 K are investigated. They are characterized by a momentum {h_bar}{ital q} parallel to the surface and may be described by bound or continuum states, which are obtained by solving a Bogoliubov-type equation formulated within the framework of the paired-phonon analysis and the hypernetted-chain approximation. Films of coverages {ital n}{sub {ital c}}=0.3 and 0.4 A{sup {minus}2} confined by simple Gaussian potentials are studied. The excitation spectrum is numerically evaluated by discretizing the associated eigenvalue problem in a finite box. The evolution of the energy levels as a function of the box size is explored. Examples of the calculated energies and wave functions are displayed in a series of figures. Two differing sorts of continuum states may be distinguished. Depending on the behavior of their excitation energies as a function of the box size on the one hand, and the spatial distribution of their wave functions inside the film and in the asymptotic region far apart from the interface layer on the other, the continuum solutions can be separated into two classes of excitations: (a) the {open_quote}{open_quote}regular{close_quote}{close_quote} continuum states and (b) the {open_quote}{open_quote}resonant modes.{close_quote}{close_quote} The matrix elements of the particle-hole potential and the penetration factors of the most important states are examined. The lowest-lying branch of states is always bound and for {ital q}{lt}{ital q}{sub {ital R}} ({ital q}{sub {ital R}}{approx_equal}1.9 A{sup {minus}1} being the momentum at the roton minimum) it describes surface ripplon excitations. In the atomic scale regime, 1.1 A{sup {minus}1}{lt}{ital q}{lt}{ital q}{sub {ital R}}, the hardest {open_quote}{open_quote}resonant mode{close_quote}{close_quote} can be interpreted as a roton trapped at the center of the film and therefore associated with bulk excitations of the system.
Lim, Edward C
1982-01-01
Excited States, Volume 6 is a collection of papers that discusses the excited states of molecules. The first paper discusses the linear polyene electronic structure and potential surfaces, considering both the theoretical and experimental approaches in such electronic states. This paper also reviews the theory of electronic structure and cites some experimental techniques on polyene excitations, polyene spectroscopic phenomenology, and those involving higher states of polyenes and their triplet states. Examples of these experimental studies of excited states involve the high-resolution one-pho
Lim, Edward C
2013-01-01
Excited States, Volume 2 is a collection of papers that deals with molecules in the excited states. The book describes the geometries of molecules in the excited electronic states. One paper describes the geometries of a diatomic molecule and of polyatomic molecules; it also discusses the determination of the many excited state geometries of molecules with two, three, or four atoms by techniques similar to diatomic spectroscopy. Another paper introduces an ordered theory related to excitons in pure and mixed molecular crystals. This paper also presents some experimental data such as those invo
Lim, Edward C
2013-01-01
Excited States, Volume 4 is a collection of papers that deals with the excited states of molecular activity. One paper investigates the resonance Raman spectroscopy as the key to vibrational-electronic coupling. This paper reviews the basic theory of Raman scattering; it also explains the derivation of the Raman spectra, excitation profiles, and depolarization ratios for simple resonance systems. Another paper reviews the magnetic properties of triplet states, including the zero-field resonance techniques, the high-field experiments, and the spin Hamiltonian. This paper focuses on the magnetic
Schulz, Marc Daniel; Dusuel, Sébastien; Vidal, Julien
2016-11-01
We discuss the emergence of bound states in the low-energy spectrum of the string-net Hamiltonian in the presence of a string tension. In the ladder geometry, we show that a single bound state arises either for a finite tension or in the zero-tension limit depending on the theory considered. In the latter case, we perturbatively compute the binding energy as a function of the total quantum dimension. We also address this issue in the honeycomb lattice where the number of bound states in the topological phase depends on the total quantum dimension. Finally, the internal structure of these bound states is analyzed in the zero-tension limit.
Schulz, M D; Vidal, J
2016-01-01
We discuss the emergence of bound states in the low-energy spectrum of the string-net Hamiltonian in the presence of a string tension. In the ladder geometry, we show that a single bound state arises either for a finite tension or in the zero-tension limit depending on the theory considered. In the latter case, we perturbatively compute the binding energy as a function of the total quantum dimension. We also address this issue in the honeycomb lattice where the number of bound states in the topological phase depends on the total quantum dimension. Finally, the internal structure of these bound states is analyzed in the zero-tension limit.
Eta nuclear bound states revisited
Friedman, E; Mareš, J
2013-01-01
The strong energy dependence of the s-wave eta-N scattering amplitude at and below threshold, as evident in coupled-channels K-matrix fits and chiral models that incorporate the S11 N*(1535) resonance, is included self consistently in eta-nuclear bound state calculations. This approach, applied recently in calculations of kaonic atoms and Kbar-nuclear bound states, is found to impose stronger constraints than ever on the onset of eta-nuclear binding, with a minimum value of Re a_{eta N} approximately 0.9 fm required to accommodate an eta-4He bound state. Binding energies and widths of eta-nuclear states are calculated within several underlying eta-N models for nuclei across the periodic table, including eta-25Mg for which some evidence was proposed in a recent COSY experiment.
Topological magnon bound-states in quantum Heisenberg chains
Qin, Xizhou; Ke, Yongguan; Zhang, Li; Lee, Chaohong
2016-01-01
It is still an outstanding challenge to characterize and understand the topological features of strongly correlated states such as bound-states in interacting multi-particle quantum systems. Recently, bound states of elementary spin waves (magnons) in quantum magnets have been experimentally observed in quantum Heisenberg chains comprising ultracold Bose atoms in optical lattices. Here, we explore an unprecedented topological state called topological magnon bound-state in the quantum Heisenberg chain under cotranslational symmetry. We find that the cotranslational symmetry allows us to formulate a direct topological invariant for the multi-particle quantum states, which can be used to characterize the topological features of multi-magnon excitations. We calculate energy spectra, density distributions, correlations and topological invariants of the two-magnon bound-states and show the existence of topological magnon bound-states. Our study not only opens a new prospect to pursue topological bound-states, but a...
Hydrogen Bonds in Excited State Proton Transfer
Horke, D. A.; Watts, H. M.; Smith, A. D.; Jager, E.; Springate, E.; Alexander, O.; Cacho, C.; Chapman, R. T.; Minns, R. S.
2016-10-01
Hydrogen bonding interactions between biological chromophores and their surrounding protein and solvent environment significantly affect the photochemical pathways of the chromophore and its biological function. A common first step in the dynamics of these systems is excited state proton transfer between the noncovalently bound molecules, which stabilizes the system against dissociation and principally alters relaxation pathways. Despite such fundamental importance, studying excited state proton transfer across a hydrogen bond has proven difficult, leaving uncertainties about the mechanism. Through time-resolved photoelectron imaging measurements, we demonstrate how the addition of a single hydrogen bond and the opening of an excited state proton transfer channel dramatically changes the outcome of a photochemical reaction, from rapid dissociation in the isolated chromophore to efficient stabilization and ground state recovery in the hydrogen bonded case, and uncover the mechanism of excited state proton transfer at a hydrogen bond, which follows sequential hydrogen and charge transfer processes.
Ultrarelativistic bound states in the shallow spherical well
Zaba, Mariusz
2016-01-01
We determine approximate eigenvalues and eigenfunctions shapes for bound states in the $3D$ shallow spherical ultrarelativistic well. Existence thresholds for the ground state and first excited states are identified, both in the purely radial and orbitally nontrivial cases. This contributes to an understanding of how energy may be stored or accumulated in the form of bound states of Schr\\"odinger - type quantum systems that are devoid of any mass.
Novel Bound States in Graphene with Impurities
Gupta, Kumar S
2008-01-01
We obtain a novel bound state spectrum of the low energy excitations near the Fermi points of graphene in the presence of a charge impurity. The effects of possible short range interactions induced by the impurity are modelled by suitable boundary conditions. The spectrum in the subcritical region of the effective Coulomb coupling is labelled by a parameter which characterizes the boundary conditions and determines the inequivalent quantizations of the system. In the supercritical region we obtain a renormalization group flow for the effective Coulomb coupling.
Bound entangled states invariant under Ux
Institute of Scientific and Technical Information of China (English)
Wang Zhen; Wang Zhi-Xi
2008-01-01
This paper obtains an entangled condition for isotropic-like states by using an atomic map. It constructs a class of bound entangled states from the entangled condition and shows that the partial transposition of the state from the constructed bound entangled class is an edge bound entangled state by using range criterion.
Boosting equal time bound states
Dietrich, Dennis D; Jarvinen, Matti
2012-01-01
We present an explicit and exact boost of a relativistic bound state defined at equal time of the constituents in the Born approximation (lowest order in hbar). To this end, we construct the Poincar\\'e generators of QED and QCD in D=1+1 dimensions, using Gauss' law to express A^0 in terms of the fermion fields in A^1=0 gauge. We determine the fermion-antifermion bound states in the Born approximation as eigenstates of the time and space translation generators P^0 and P^1. The boost operator is combined with a gauge transformation so as to maintain the gauge condition A^1=0 in the new frame. We verify that the boosted state remains an eigenstate of P^0 and P^1 with appropriately transformed eigenvalues and determine the transformation law of the equal-time, relativistic wave function. The shape of the wave function is independent of the CM momentum when expressed in terms of a variable, which is quadratically related to the distance x between the fermions. As a consequence, the Lorentz contraction of the wave ...
Asymmetric dark matter bound state
Bi, Xiao-Jun; Kang, Zhaofeng; Ko, P.; Li, Jinmian; Li, Tianjun
2017-02-01
We propose an interesting framework for asymmetric scalar dark matter (ADM), which has novel collider phenomenology in terms of an unstable ADM bound state (ADMonium) produced via Higgs portals. ADMonium is a natural consequence of the basic features of ADM: the (complex scalar) ADM is charged under a dark local U (1 )d symmetry which is broken at a low scale and provides a light gauge boson X . The dark gauge coupling is strong and then ADM can annihilate away into X -pair effectively. Therefore, the ADM can form a bound state due to its large self-interaction via X mediation. To explore the collider signature of ADMonium, we propose that ADM has a two-Higgs doublet portal. The ADMonium can have a sizable mixing with the heavier Higgs boson, which admits a large cross section of ADMonium production associated with b b ¯. The resulting signature at the LHC depends on the decays of X . In this paper we consider a case of particular interest: p p →b b ¯ +ADMonium followed by ADMonium→2 X →2 e+e- where the electrons are identified as (un)converted photons. It may provide a competitive explanation to heavy di-photon resonance searches at the LHC.
Hsu, Chia Wei; Zhen, Bo; Stone, A. Douglas; Joannopoulos, John D.; Soljačić, Marin
2016-09-01
Bound states in the continuum (BICs) are waves that remain localized even though they coexist with a continuous spectrum of radiating waves that can carry energy away. Their very existence defies conventional wisdom. Although BICs were first proposed in quantum mechanics, they are a general wave phenomenon and have since been identified in electromagnetic waves, acoustic waves in air, water waves and elastic waves in solids. These states have been studied in a wide range of material systems, such as piezoelectric materials, dielectric photonic crystals, optical waveguides and fibres, quantum dots, graphene and topological insulators. In this Review, we describe recent developments in this field with an emphasis on the physical mechanisms that lead to BICs across seemingly very different materials and types of waves. We also discuss experimental realizations, existing applications and directions for future work.
Bound anionic states of adenine
Energy Technology Data Exchange (ETDEWEB)
Haranczyk, Maciej; Gutowski, Maciej S; Li, Xiang; Bowen, Kit H
2007-03-20
Anionic states of nucleic acid bases are involved in DNA damage by low-energy electrons and in charge transfer through DNA. Previous gas phase studies of free, unsolvated nucleic acid base parent anions probed only dipole-bound states, which are not present in condensed phase environments, but did not observe valence anionic states, which for purine bases, are thought to be adiabatically unbound. Contrary to this expectation, we have demonstrated that some thus far ignored tautomers of adenine, which result from enamine-imine transformations, support valence anionic states with electron vertical detachment energies as large as 2.2 eV, and at least one of these anionic tautomers is adiabatically bound. Moreover, we predict that the new anionic tautomers should also dominate in solutions and should be characterized by larger values of electron vertical detachment energy than the canonical valence anion. All of the new-found anionic tautomers might be formed in the course of dissociative electron attachment followed by a hydrogen atom attachment to a carbon atom, and they might affect the structure and properties of DNA and RNA exposed to low-energy electrons. The discovery of these valence anionic states of adenine was facilitated by the development of: (i) a new experimental method for preparing parent anions of nucleic acid bases for photoelectron experiments, and (ii) a new combinatorial/ quantum chemical approach for identification of the most stable tautomers of organic molecules. The computational portion of this work was supported by the: (i) Polish State Committee for Scientific Research (KBN) Grants: DS/8000-4-0140-7 (M.G.) and N204 127 31/2963 (M.H.), (ii) European Social Funds (EFS) ZPORR/2.22/II/2.6/ARP/U/2/05 (M.H.), and (iii) US DOE Office of Biological and Environmental Research, Low Dose Radiation Research Program (M.G.). M.H. holds the Foundation for Polish Science (FNP) award for young scientists. The calculations were performed at the Academic
Mass spectrum bound state systems with relativistic corrections
Energy Technology Data Exchange (ETDEWEB)
Dineykhan, M; Zhaugasheva, S A [Bogoliubov Laboratory of Theoretical Physics, Joint Institute for Nuclear Research, Dubna (Russian Federation); Toinbaeva, N Sh; Jakhanshir, A [al-Farabi Kazak National University, 480012 Almaty (Kazakhstan)
2009-07-28
Based on the investigation of the asymptotic behaviour of the polarization loop function for charged n scalar particles in an external gauge field, we determine the interaction Hamiltonian including relativistic corrections. The mass spectrum of the bound state is analytically derived. The mechanism for arising of the constituent mass of the relativistic bound-state forming particles is explained. The mass and the constituent mass of the two-, three- and n-body relativistic bound states are calculated taking into account relativistic corrections. The corrections arising due to the one- and two-loop electron polarization to the energy spectrum of muonic hydrogen with orbital and radial excitations are calculated.
Excited, bound and resonant positron-atom systems
Energy Technology Data Exchange (ETDEWEB)
Bromley, M W J [Department of Physics and Computational Science Research Center, San Diego State University, San Diego CA 92182 (United States); Mitroy, J, E-mail: mbromley@physics.sdsu.ed [ARC Centre for Antimatter-Matter Studies and Faculty of Education, Health and Science, Charles Darwin University, Darwin NT 0909 (Australia)
2010-01-01
Calculations have demonstrated that eleven neutral atoms can bind positrons, while many more can bind positronium. This is a short review of recent progress made in understanding some of the underlying mechanisms. The emphasis here being on configuration interaction calculations with excited state configurations. These have demonstrated the existence of a {sup 2}P{sup o} excited state of e{sup +}Ca, which consists predominantly of a positronium cluster orbiting the Ca{sup +} ion in the L = 1 partial wave. Preliminary results are presented of excited state positron binding to a model alkali atom, where the excited {sup 1}P{sup o} states are stable over a limited region. Implications for the unnatural parity, {sup 2,4}S{sup o}, states of PsH, LiPs, NaPs and KPs are also discussed. The e{sup +}Mg, e{sup +}Cu, e{sup +}Zn and e{sup +}Cd systems show a lack of a {sup 2}P{sup o} excited state, each instead possessing a low-energy p-wave shape resonance of varying strength.
Internal conversion to bound final states in 125Te
Harston, M. R.; Carreyre, T.; Chemin, J. F.; Karpeshin, F.; Trzhaskovskaya, M. B.
2000-08-01
Theoretical results are presented for rate of decay of the 3/2+ isomeric nuclear state of 125Te by excitation of atomic electrons to bound states in the ions Te 45+ and Te 46+. In these ions the nuclear transition energy lies just below the threshold for emission of a K-shell electron to the continuum with the result that normal K-shell internal conversion is energetically forbidden. However recent experimental results indicate that excitation of K-shell electrons is still significant in these ions. The theoretical results presented here for internal conversion to bound final states are in quantitative agreement with experiment and thereby confirm the contribution of near-resonant electron-nucleus transitions involving a bound final state.
Instanton bound states in ABJM theory
Energy Technology Data Exchange (ETDEWEB)
Hatsuda, Yasuyuki [DESY Hamburg (Germany). Theory Group; Tokyo Institute of Technology (Japan). Dept. of Physics; Moriyama, Sanefumi [Nagoya Univ. (Japan). Kobayashi Maskawa Inst. and Graduate School of Mathematics; Okuyama, Kazumi [Shinshu Univ., Matsumoto, Nagano (Japan). Dept. of Physics
2013-06-15
The partition function of the ABJM theory receives non-perturbative corrections due to instanton effects. We study these non-perturbative corrections, including bound states of worldsheet instantons and membrane instantons, in the Fermi-gas approach. We require that the total non-perturbative correction should be always finite for arbitrary Chern-Simons level. This finiteness is realized quite non-trivially because each bound state contribution naively diverges at some levels. The poles of each contribution should be canceled out in total. We use this pole cancellation mechanism to find unknown bound state corrections from known ones. We conjecture a general expression of the bound state contribution. Summing up all the bound state contributions, we find that the effect of bound states is simply incorporated into the worldsheet instanton correction by a redefinition of the chemical potential in the Fermi-gas system. Analytic expressions of the 3- and 4-membrane instanton corrections are also proposed.
On the reflection of magnon bound states
MacKay, Niall
2010-01-01
We investigate the reflection of two-particle bound states of a free open string in the light-cone AdS_5 x S^5 string sigma model, for large angular momentum J=J_56 and ending on a D7 brane which wraps the entire AdS_5 and a maximal S^3 of S^5. We use the superspace formalism to analyse fundamental and two-particle bound states in the cases of supersymmetry-preserving and broken-supersymmetry boundaries. We find the boundary S-matrices corresponding to bound states both in the bulk and on the boundary.
Lower Bounds of Concurrence for Multipartite States
Zhu, Xue-Na; Fei, Shao-Ming
2012-01-01
We study the entanglement of multipartite quantum states. Some lower bounds of the multipartite concurrence are reviewed. We further present more effective lower bounds for detecting and qualifying entanglement, by establishing functional relations between the concurrence and the generalized partial transpositions of the multipartite systems.
Parity lifetime of bound states in a proximitized semiconductor nanowire
DEFF Research Database (Denmark)
Higginbotham, Andrew Patrick; Albrecht, Sven Marian; Kirsanskas, Gediminas
2015-01-01
superconductors but remain relatively unexplored in semiconductor-superconductor structures, which are now being intensely pursued in the context of topological superconductivity. To this end, we introduce a new physical system comprised of a gate-confined semiconductor nanowire with an epitaxially grown...... superconductor layer, yielding an isolated, proximitized nanowire segment. We identify Andreev-like bound states in the semiconductor via bias spectroscopy, determine the characteristic temperatures and magnetic fields for quasiparticle excitations, and extract a parity lifetime (poisoning time) of the bound...... state in the semiconductor exceeding 10 ms....
Irreversibility for all bound entangled states
Yang, D; Horodecki, R; Synak-Radtke, B; Yang, Dong; Horodecki, Michal; Horodecki, Ryszard; Synak-Radtke, Barbara
2005-01-01
We derive a new inequality for entanglement for a mixed four-partite state. Employing this inequality, we present a one-shot lower bound for entanglement cost and prove that entanglement cost is strictly larger than zero for any entangled state. We demonstrate that irreversibility occurs in the process of formation for all non-distillable entangled states. In this way we solve a long standing problem, of how "real" is entanglement of bound entangled states. Using the new inequality we also prove impossibility of local-cloning and local-deleting of a known entangled state.
First direct proof of internal conversion between bound states
Carreyre, T.; Harston, M. R.; Aiche, M.; Bourgine, F.; Chemin, J. F.; Claverie, G.; Goudour, J. P.; Scheurer, J. N.; Attallah, F.; Bogaert, G.; Kiener, J.; Lefebvre, A.; Durell, J.; Grandin, J. P.; Meyerhof, W. E.; Phillips, W.
2000-08-01
We present direct evidence for the process of internal conversion between bound atomic states (BIC) when the binding energy of the converted electron becomes larger than the nuclear transition energy. This process has been proposed as an explanation of the measured, unexpectedly short lifetime of the first excited state of 125Te with charge state larger than 44+. We have detected the Kα x rays emitted in flight which follow the filling of the K-shell vacancy created by the bound internal conversion process, together with γ rays from Te ions in charge states ranging between 44+ and 48+. For Te45+ and Te46+, the comparison of the x-ray to γ-ray ratios with the theoretical calculations of the internal conversion coefficients including decay to bound atomic states, assuming Te ions in their ground electronic state, show poor agreement. The agreement becomes good if account is taken of BIC decay of excited initial states with different occupancies of the 2p1/2 and 2p3/2 subshells. In this situation, the half-life becomes sensitive to the precise initial state and simple specification of the charge state alone is no longer appropriate.
Chirped-frequency excitation of gravitationally bound ultracold neutrons
Manfredi, Giovanni; Morandi, Omar; Friedland, Lazar; Jenke, Tobias; Abele, Hartmut
2017-01-01
Ultracold neutrons confined in the Earth's gravitational field display quantized energy levels that have been observed for over a decade. In recent resonance spectroscopy experiments [T. Jenke et al., Nat. Phys. 7, 468 (2011), 10.1038/nphys1970], the transition between two such gravitational quantum states was driven by the mechanical oscillation of the plates that confine the neutrons. Here we show that by applying a sinusoidal modulation with slowly varying frequency (chirp), the neutrons can be brought to higher excited states by climbing the energy levels one by one. The proposed experiment should make it possible to observe the quantum-classical transition that occurs at high neutron energies. Furthermore, it provides a technique to realize superpositions of gravitational quantum states, to be used for precision tests of gravity at short distances.
Bound States in Boson Impurity Models
Shi, Tao; Wu, Ying-Hai; González-Tudela, A.; Cirac, J. I.
2016-04-01
The formation of bound states involving multiple particles underlies many interesting quantum physical phenomena, such as Efimov physics or superconductivity. In this work, we show the existence of an infinite number of such states for some boson impurity models. They describe free bosons coupled to an impurity and include some of the most representative models in quantum optics. We also propose a family of wave functions to describe the bound states and verify that it accurately characterizes all parameter regimes by comparing its predictions with exact numerical calculations for a one-dimensional tight-binding Hamiltonian. For that model, we also analyze the nature of the bound states by studying the scaling relations of physical quantities, such as the ground-state energy and localization length, and find a nonanalytical behavior as a function of the coupling strength. Finally, we discuss how to test our theoretical predictions in experimental platforms, such as photonic crystal structures and cold atoms in optical lattices.
Parity lifetime of bound states in a proximitized semiconductor nanowire
Higginbotham, A. P.; Albrecht, S. M.; Kiršanskas, G.; Chang, W.; Kuemmeth, F.; Krogstrup, P.; Jespersen, T. S.; Nygård, J.; Flensberg, K.; Marcus, C. M.
2015-12-01
Quasiparticle excitations can compromise the performance of superconducting devices, causing high-frequency dissipation, decoherence in Josephson qubits, and braiding errors in proposed Majorana-based topological quantum computers. Quasiparticle dynamics have been studied in detail in metallic superconductors but remain relatively unexplored in semiconductor-superconductor structures, which are now being intensely pursued in the context of topological superconductivity. To this end, we use a system comprising a gate-confined semiconductor nanowire with an epitaxially grown superconductor layer, yielding an isolated, proximitized nanowire segment. We identify bound states in the semiconductor by means of bias spectroscopy, determine the characteristic temperatures and magnetic fields for quasiparticle excitations, and extract a parity lifetime (poisoning time) of the bound state in the semiconductor exceeding 10 ms.
Family of nonlocal bound entangled states
Yu, Sixia; Oh, C. H.
2017-03-01
Bound entanglement, being entangled yet not distillable, is essential to our understanding of the relations between nonlocality and entanglement besides its applications in certain quantum information tasks. Recently, bound entangled states that violate a Bell inequality have been constructed for a two-qutrit system, disproving a conjecture by Peres that bound entanglement is local. Here we construct this kind of nonlocal bound entangled state for all finite dimensions larger than two, making possible their experimental demonstration in most general systems. We propose a Bell inequality, based on a Hardy-type argument for nonlocality, and a steering inequality to identify their nonlocality. We also provide a family of entanglement witnesses to detect their entanglement beyond the Bell inequality and the steering inequality.
η-nuclear bound states revisited
Friedman, E.; Gal, A.; Mareš, J.
2013-10-01
The strong energy dependence of the s-wave ηN scattering amplitude at and below threshold, as evident in coupled-channels K-matrix fits and chiral models that incorporate the S11N* (1535) resonance, is included self-consistently in η-nuclear bound-state calculations. This approach, applied recently in calculations of kaonic atoms and Kbar-nuclear bound states, is found to impose stronger constraints than ever on the onset of η-nuclear binding, with a minimum value of ReaηN ≈ 0.9 fm required to accommodate an η-4He bound state. Binding energies and widths of η-nuclear states are calculated within several underlying ηN models for nuclei across the periodic table, including Mg25η for which some evidence was proposed in a recent COSY experiment.
Narrow deeply bound K- atomic states
Friedman, E.; Gal, A.
1999-07-01
Using optical potentials fitted to a comprehensive set of strong interaction level shifts and widths in K- atoms, we predict that the K- atomic levels which are inaccessible in the atomic cascade process are generally narrow, spanning a range of widths about 50-1500 keV over the entire periodic table. The mechanism for this narrowing is different from the mechanism for narrowing of pionic atom levels. Examples of such `deeply bound' K- atomic states are given, showing that in many cases these states should be reasonably well resolved. Several reactions which could be used to form these `deeply bound' states are mentioned. Narrow deeply bound states are expected also in overlinep atoms.
Chirped-Frequency Excitation of Gravitationally Bound Ultracold Neutrons
Manfredi, Giovanni; Friedland, Lazar
2015-01-01
Ultracold neutrons confined in the Earth's gravitational field display quantized energy levels that have been observed for over a decade. In recent resonance spectroscopy experiments [T. Jenke et al., Nature Phys. 7, 468 (2011)], the transition between two such gravitational quantum states was driven by the mechanical modulation of one of the plates that confines the neutrons. Here we show that, by applying a sinusoidal modulation with slowly varying frequency (chirp), the neutrons can be brought to any excited state, however large its energy, by climbing the energy levels one by one. This technique should make it possible to observe the quantum-classical transition that occurs at high energies. The proposed experiment is realizable using current technology and could significantly improve the sensitivity of future tests of gravitational physics.
Introduction to QCD - a bound state perspective
Hoyer, Paul
2011-01-01
These lecture notes focus on the bound state sector of QCD. Motivated by data which suggests that the strong coupling \\alpha_s(Q) freezes at low Q, and by similarities between the spectra of hadrons and atoms, I discuss if and how QCD bound states may be treated perturbatively. I recall the basic principles of perturbative gauge theory bound states at lowest order in the \\hbar expansion. Born level amplitudes are insensitive to the i\\epsilon prescription of propagators, which allows to eliminate the Z-diagrams of relativistic, time-ordered Coulomb interactions. The Dirac wave function thus describes a single electron which propagates forward in time only, even though the bound state has any number of pair constituents when Feynman propagators are used. In the absence of an external potential, states that are bound by the Coulomb attraction of their constituents can be analogously described using only their valence degrees of freedom. The instantaneous A^0 field is determined by Gauss' law for each wave functi...
Interplay of projectile breakup and target excitation in reactions induced by weakly bound nuclei
Gómez-Ramos, M.; Moro, A. M.
2017-03-01
Background: Reactions involving weakly bound nuclei require formalisms able to deal with continuum states. The majority of these formalisms struggle to treat collective excitations of the systems involved. For continuum-discretized coupled channels (CDCC), extensions to include target excitation have been developed but have only been applied to a small number of cases. Purpose: In this work, we reexamine the extension of the CDCC formalism to include target excitation and apply it to a variety of reactions to study the effect of breakup on inelastic cross sections. Methods: We use a transformed oscillator basis to discretize the continuum of the projectiles in the different reactions and use the extended CDCC method developed in this work to solve the resulting coupled differential equations. A new code has been developed to perform the calculations. Results: Reactions 58Ni(d ,d )*58Ni , 24Mg(d ,d )*24Mg , 144Sm(6Li,6Li)*144Sm , and 9Be(6Li,6Li)*9Be are studied. Satisfactory agreement is found between experimental data and extended CDCC calculations. Conclusions: The studied CDCC method has proven to be an accurate tool to describe target excitation in reactions with weakly bound nuclei. Moderate effects of breakup on inelastic observables are found for the reactions studied. Cross-section magnitudes are not modified much, but angular distributions present smoothing when opposed to calculations without breakup.
Population of highly excited intermediate resonance states by electron transfer and excitation
Energy Technology Data Exchange (ETDEWEB)
Schuch, R. (Manne Siegbahn Institute of Physics, S-104 05 Stockholm, Sweden (SE)); Justiniano, E. (Department of Physics, East Carolina University, Greenville, North Carolina 27858-4353 (USA)); Schulz, M.; Datz, S.; Dittner, P.F.; Giese, J.P.; Krause, H.F.; Schoene, H.; Vane, R. (Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831-6377 (USA)); Shafroth, S. (Department of Physics, North Carolina University, Chapel Hill, North Carolina 27599-3255 (USA))
1991-05-01
Coincidences between two sulfur {ital K} x rays were detected from collisions of hydrogenlike S ions with H{sub 2} gas in the projectile energy range between 150 and 225 MeV. These {ital K} x rays are emitted in the decay of doubly excited states formed in the collisions via transfer and excitation. The excitation function for two coincident {ital K}{beta} transitions peaks at about 175 MeV, slightly above the expected {ital KMM} resonance energy for resonant transfer and excitation (RTE). This demonstrates the occurrence of {Delta}{ital N}{ge}2 transitions (i.e., {ital KMM} and higher resonances) in the RTE process. The cross sections for the population of the very highly excited states are higher than those predicted by theoretical calculations that use dielectronic recombination rates folded with the Compton profile for the bound electrons.
Two-body bound states & the Bethe-Salpeter equation
Energy Technology Data Exchange (ETDEWEB)
Pichowsky, M. [Argonne National Lab., IL (United States); Kennedy, M. [Univ. of New Hampshire, Durham, NH (United States). Physics Dept.; Strickland, M. [Duke Univ., Durham, NC (United States)
1995-01-18
The Bethe-Salpeter formalism is used to study two-body bound states within a scalar theory: two scalar fields interacting via the exchange of a third massless scalar field. The Schwinger-Dyson equation is derived using functional and diagrammatic techniques, and the Bethe-Salpeter equation is obtained in an analogous way, showing it to be a two-particle generalization of the Schwinger-Dyson equation. The authors also present a numerical method for solving the Bethe-Salpeter equation without three-dimensional reduction. The ground and first excited state masses and wavefunctions are computed within the ladder approximation and space-like form factors are calculated.
Role of nuclear couplings in the inelastic excitation of weakly-bound neutron-rich nuclei
Energy Technology Data Exchange (ETDEWEB)
Dasso, C.H. [Niels Bohr Institute, Copenhagen (Denmark); Lenzi, S.M.; Vitturi, A. [Universita di Padova (Italy)
1996-12-31
Much effort is presently devoted to the study of nuclear systems far from the stability line. Particular emphasis has been placed in light systems such as {sup 11}Li, {sup 8}B and others, where the very small binding energy of the last particles causes their density distribution to extend considerably outside of the remaining nuclear core. Some of the properties associated with this feature are expected to characterize also heavier systems in the vicinity of the proton or neutron drip lines. It is by now well established that low-lying concentrations of multipole strength arise from pure configurations in which a peculiar matching between the wavelength of the continuum wavefunction of the particles and the range of the weakly-bound hole states occurs. To this end the authors consider the break-up of a weakly-bound system in a heavy-ion collision and focus attention in the inelastic excitation of the low-lying part of the continuum. They make use of the fact that previous investigations have shown that the multipole response in this region is not of a collective nature and describe their excited states as pure particle-hole configurations. Since the relevant parameter determining the strength distributions is the binding energy of the last bound orbital they find it most convenient to use single-particle wavefunctions generated by a sperical square-well potential with characteristic nuclear dimensions and whose depth has been adjusted to give rise to a situation in which the last occupied neutron orbital is loosely-bound. Spin-orbit couplings are, for the present purpose, ignored. The results of this investigation clearly indicate that nuclear couplings have the predominant role in causing projectile dissociation in many circumstances, even at bombarding energies remarkably below the Coulomb barrier.
Nuclear internal conversion between bound atomic states
Chemin, J. F.; Harston, M. R.; Karpeshin, F. F.; Carreyre, J.; Attallah, F.; Aleonard, M. M.; Scheurer, J. N.; Boggaert, G.; Grandin, J. R.; Trzhaskovskaya, M. B.
2003-01-01
We present experimental and theoretical results for rate of decay of the (3/2)+ isomeric state in 125Te versus the ionic charge state. For charge state larger than 44 the nuclear transition lies below the threshold for emission of a K-shell electron into the continuum with the result that normal internal conversion is energetically forbiden. Rather surprisingly, for the charge 45 and 46 the lifetime of the level was found to have a value close to that in neutral atoms. We present direct evidence that the nuclear transition could still be converted but without the emission of the electron into the continuum, the electron being promoted from the K-shell to an other empty bound state lying close to the continuum. We called this process BIC. The experimental results agree whith theoretical calculations if BIC resonances are taken into account. This leads to a nuclear decay constant that is extremely sensitive to the precise initial state and simple specification of the charge state is no longer appropriate. The contribution to decay of the nucleus of BIC has recently been extended to the situation in which the electron is promoted to an intermediate filled bound state (PFBIC) with an apparent violation of the Pauli principle. Numerical results of the expected dependence of PFBIC on the charge state will be presented for the decay of the 77.351 keV level in 197Au.
Analytic continuation of bound states to solve resonance states
Energy Technology Data Exchange (ETDEWEB)
Tanaka, Norimichi; Arai, Koji [Niigata Univ. (Japan); Suzuki, Yoshiyuki; Varga, K.
1997-05-01
As a method to determine the parameters of the resonance state, a method is proposed using analytic continuation on bound constants of correlation. The characteristics of this method consists in probability of prediction of the parameters of the resonance state only by calculation of the bound state. Owing to conducting the analytic continuation on square root of energy in the bound state as a function relating to the bound constant, energy and width in the bound state was determined. Here was reported on a result of application of this method to three systems. Some partial wave on two systems showing correlation at a simple potential and a resonance state of zero of all orbital angular motion quality in three boson system were determined using the analytic continuation method. These results agreed well with one used a method of integrating Schroedinger equation directly and one used the complex scaling method, and this method was found to be much efficient for the study of the resonance state. Under a background of becoming applicable to the method of analytic continuation, there was development of calculating method for the recent small number multi system. As the characteristics of the analytic continuation method is used for only calculation of the bound state, it is convenient at a point applicable to the method to obtain conventional bound state and then is much efficient in a point of applicability of calculus of variations. However, in order to obtain coefficient of Pade approximation correctly, the bound state must be solved correctly, which is difficult for more complex system and is not always applicable to every systems. (G.K.)
Excited state Intramolecular Proton Transfer in Anthralin
DEFF Research Database (Denmark)
Møller, Søren; Andersen, Kristine B.; Spanget-Larsen, Jens
1998-01-01
Quantum chemical calculations performed on anthralin (1,8-dihydroxy-9(10H)-anthracenone) predict the possibility of an excited-state intramolecular proton transfer process. Fluorescence excitation and emission spectra of the compound dissolved in n-hexane at ambient temperature results in an unus......Quantum chemical calculations performed on anthralin (1,8-dihydroxy-9(10H)-anthracenone) predict the possibility of an excited-state intramolecular proton transfer process. Fluorescence excitation and emission spectra of the compound dissolved in n-hexane at ambient temperature results......, associated with an excited-state intramolecular proton transfer process....
A Neutron Halo in 12B Excited State
Institute of Scientific and Technical Information of China (English)
2001-01-01
Nonlinear relativistic mean field(RMF) theory with a new effective interaction NL3 has been used to investigate the bulk properties of 12B nucleus and its daughter nuclei. The results obtained in RMF indicate one neutron halo in 12B nucleus at an excited state. The density distribution of neutrons in the excited state of 12B has a long tail and the nucleon in 2s1/2 state has very small separation energy. The rms radius of halo neutron is about twice larger than that of matter. Meanwhile, it becomes more apparent that nuclear halo is a general feature of loosely bound nuclei. As the binding energy becomes smaller, to form a bound state the nucleon tends to occupy a state with a low angular momentum. It
Multimode optical fibers: steady state mode exciter.
Ikeda, M; Sugimura, A; Ikegami, T
1976-09-01
The steady state mode power distribution of the multimode graded index fiber was measured. A simple and effective steady state mode exciter was fabricated by an etching technique. Its insertion loss was 0.5 dB for an injection laser. Deviation in transmission characteristics of multimode graded index fibers can be avoided by using the steady state mode exciter.
Andreev bound states. Some quasiclassical reflections
Energy Technology Data Exchange (ETDEWEB)
Lin, Y., E-mail: yiriolin@illinois.edu; Leggett, A. J. [University of Illinois at Urhana-Champaign, Dept. of Physics (United States)
2014-12-15
We discuss a very simple and essentially exactly solvable model problem which illustrates some nice features of Andreev bound states, namely, the trapping of a single Bogoliubov quasiparticle in a neutral s-wave BCS superfluid by a wide and shallow Zeeman trap. In the quasiclassical limit, the ground state is a doublet with a splitting which is proportional to the exponentially small amplitude for “normal” reflection by the edges of the trap. We comment briefly on a prima facie paradox concerning the continuity equation and conjecture a resolution to it.
Nuclear dynamics of K¯ bound states
Mareš, J.; Friedman, E.; Gal, A.
2006-07-01
K¯ nuclear bound states were generated dynamically within a relativistic mean field (RMF) model. Substantial polarization of the core nucleus was found for light nuclei. The behavior of the dynamically calculated width ΓK¯ as function of the K¯ binding energy was studied. A lower limit of ΓK¯ ˜ 35 - 45 MeV for 1s K¯ nuclear states in light nuclei such as 12C was placed on the width expected for deep binding in the range B K¯ ˜ 100 - 200 MeV.
The mechanisms of Excited states in enzymes
DEFF Research Database (Denmark)
Petersen, Frederic Nicolas Rønne; Bohr, Henrik
2010-01-01
Enzyme catalysis is studied on the basis of excited state processes, which are of electronic, vibrational and thermal nature. The ways of achieving the excited state, such as photo-absorption and ligand binding, are discussed and exemplified by various cases of enzymes.......Enzyme catalysis is studied on the basis of excited state processes, which are of electronic, vibrational and thermal nature. The ways of achieving the excited state, such as photo-absorption and ligand binding, are discussed and exemplified by various cases of enzymes....
Excited states rotational effects on the behavior of excited molecules
Lim, Edward C
2013-01-01
Excited States, Volume 7 is a collection of papers that discusses the excited states of molecules. The first paper reviews the rotational involvement in intra-molecular in vibrational redistribution. This paper analyzes the vibrational Hamiltonian as to its efficacy in detecting the manifestations of intra-molecular state-mixing in time-resolved and time-averaged spectroscopic measurements. The next paper examines the temporal behavior of intra-molecular vibration-rotation energy transfer (IVRET) and the effects of IVRET on collision, reaction, and the decomposition processes. This paper also
Resonantly Trapped Bound State in the Continuum Laser
Lepetit, Thomas; Kodigala, Ashok; Bahari, Babak; Fainman, Yeshaiahu; Kanté, Boubacar
2015-01-01
Cavities play a fundamental role in wave phenomena from quantum mechanics to electromagnetism and dictate the spatiotemporal physics of lasers. In general, they are constructed by closing all "doors" through which waves can escape. We report, at room temperature, a bound state in the continuum laser that harnesses optical modes residing in the radiation continuum but nonetheless may possess arbitrarily high quality factors. These counterintuitive cavities are based on resonantly trapped symmetry-compatible modes that destructively interfere. Our experimental demonstration opens exciting avenues towards coherent sources with intriguing topological properties for optical trapping, biological imaging, and quantum communication.
Excited State Properties of Hybrid Perovskites.
Saba, Michele; Quochi, Francesco; Mura, Andrea; Bongiovanni, Giovanni
2016-01-19
Metal halide perovskites have come to the attention of the scientific community for the progress achieved in solar light conversion. Energy sustainability is one of the priorities of our society, and materials advancements resulting in low-cost but efficient solar cells and large-area lighting devices represent a major goal for applied research. From a basic point of view, perovskites are an exotic class of hybrid materials combining some merits of organic and inorganic semiconductors: large optical absorption, large mobilities, and tunable band gap together with the possibility to be processed in solution. When a novel class of promising semiconductors comes into the limelight, lively discussions ensue on the photophysics of band-edge excitations, because just the states close to the band edge are entailed in energy/charge transport and light emission. This was the case several decades ago for III-V semiconductors, it has been up to 10 years ago for organics, and it is currently the case for perovskites. Our aim in this Account is to rationalize the body of experimental evidence on perovskite photophysics in a coherent theoretical framework, borrowing from the knowledge acquired over the years in materials optoelectronics. A crucial question is whether photon absorption leads to a population of unbound, conductive free charges or instead excitons, neutral and insulating bound states created by Coulomb interaction just below the energy of the band gap. We first focus on the experimental estimates of the exciton binding energy (Eb): at room temperature, Eb is comparable to the thermal energy kBT in MAPbI3 and increases up to values 2-3kBT in wide band gap MAPbBr3 and MAPbCl3. Statistical considerations predict that these values, even though comparable to or larger than thermal energy, let free carriers prevail over bound excitons for all levels of excitation densities relevant for devices. The analysis of photophysics evidence confirms that all hybrid halide
Modelling Ca2+ bound Troponin in Excitation Contraction Coupling
Directory of Open Access Journals (Sweden)
Henry G. Zot
2016-09-01
Full Text Available To explain disparate decay rates of cytosolic Ca2+ and structural changes in the thin filaments during a twitch, we model the time course of Ca2+ bound troponin (Tn resulting from the free Ca2+ transient of fast skeletal muscle. In fibers stretched beyond overlap, the decay of Ca2+ as measured by a change in fluo 3 fluorescence is significantly slower than the intensity decay of the meridional 1/38.5 nm-1 reflection of Tn; this is not simply explained by considering only the Ca2+ binding properties of Tn alone (Matsuo, T., Iwamoto, H., and Yagi, N. (2010. Biophys. J. 99, 193-200. We apply a comprehensive model that includes the known Ca2+ binding properties of Tn in the context of the thin filament with and without cycling crossbridges. Calculations based on the model predict that the transient of Ca2+ bound Tn correlates with either the fluo 3 time course in muscle with overlapping thin and thick filaments or the intensity of the meridional 1/38.5 nm-1 reflection in overstretched muscle. Hence, cycling crossbridges delay the dissociation of Ca2+ from Tn. Correlation with the fluo 3 fluorescence change is not causal given that the transient of Ca2+ bound Tn depends on sarcomere length, whereas the fluo-3 fluorescence change does not. Transient positions of tropomyosin calculated from the time course of Ca2+ bound Tn are in reasonable agreement with the transient of measured perturbations of the Tn repeat in overlap and non-overlap muscle preparations.
Is there an quasi-bound state?
Wilkin, C; Chiladze, D; Dymov, S; Hanhart, C; Hartmann, M; Hejny, V; Kacharava, A K; Keshelashvili, I; Khoukaz, A; Maeda, Y; Mersmann, T; Mielke, M; Mikirtychiants, S; Papenbrock, M; Rathmann, F; Rausmann, T; Schleichert, R; Ströher, H; Täschner, A; Valdau, Yu; Wronska, A
2007-01-01
The observed variation of the total cross section for the dp -> 3He eta reaction near threshold means that the magnitude of the s--wave amplitude falls very rapidly with the eta centre--of--mass momentum. It is shown here that recent measurements of the momentum dependence of the angular distribution imply a strong variation also in the phase of this amplitude. Such a behaviour is that expected from a quasi--bound or virtual eta-3He state. The interpretation can be investigated further through measurements of the deuteron or proton analysing powers and/or spin--correlations.
A balance for Dark Matter bound states
Nozzoli, F
2016-01-01
Massive particles with self interactions of the order of 0.2 barn/GeV are intriguing Dark Matter candidates from an astrophysical point of view. Direct detection searches for very massive particles, with relatively high cross sections with ordinary matter, cannot rule out $\\sigma/M > 0.01$ barn/GeV, due to atmosphere and material shielding. Here, the possibility of the existence of bound states with ordinary matter, for Dark Matter candidates with not negligible interactions, is considered. The existence of bound states, with binding energy larger than $\\sim$1 meV, would offer the possibility to test in laboratory capture cross sections of the order of a barn (or larger). The signature of the detection of a mass increasing of cryogenic samples, due to the possible Dark Matter accumulation, would allow the investigation of Dark Matter particles with mass up to the GUT scale. A proof of concept for a possible detection set-up and the evaluation of some noise sources are described.
ADMonium: Asymmetric Dark Matter Bound State
Bi, Xiao-Jun; Ko, P; Li, Jinmian; Li, Tianjun
2016-01-01
We propose a novel framework for asymmetric scalar dark matter (ADM), which has interesting collider phenomenology in terms of an unstable ADM bound state (ADMonium) produced via Higgs portals. ADMonium is a natural consequence of the basic features of ADM: the (complex scalar) ADM is charged under a dark local $U(1)_d$ symmetry which is broken at a low scale and provides a light gauge boson $X$. The dark gauge coupling is strong and then ADM can annihilate away into $X$-pair effectively. Therefore, the ADM can form bound state due to its large self-interaction via $X$ mediation. To explore the collider signature of ADMonium, we propose that ADM has a two-Higgs doublet portal. The ADMonium can have a sizable mixing with the heavier Higgs boson, which admits a large cross section of ADMonium production associated with $b\\bar b$. Of particular interest, our setup nicely explains the recent di-photon anomaly at 750 GeV via the events from ${\\rm ADMonium}\\ra 2X(\\ra e^+e^-)$, where the electrons are identified as ...
On Aharonov-Casher bound states
Silva, E. O.; Andrade, F. M.; Filgueiras, C.; Belich, H.
2013-04-01
In this work bound states for the Aharonov-Casher problem are considered. According to Hagen's work on the exact equivalence between spin-1/2 Aharonov-Bohm and Aharonov-Casher effects, is known that the ∇ṡ E term cannot be neglected in the Hamiltonian if the spin of particle is considered. This term leads to the existence of a singular potential at the origin. By modeling the problem by boundary conditions at the origin which arises by the self-adjoint extension of the Hamiltonian, we derive for the first time an expression for the bound state energy of the Aharonov-Casher problem. As an application, we consider the Aharonov-Casher plus a two-dimensional harmonic oscillator. We derive the expression for the harmonic oscillator energies and compare it with the expression obtained in the case without singularity. At the end, an approach for determination of the self-adjoint extension parameter is given. In our approach, the parameter is obtained essentially in terms of physics of the problem.
On Aharonov-Casher bound states
Energy Technology Data Exchange (ETDEWEB)
Silva, E.O. [Universidade Federal do Maranhao, Departamento de Fisica, Sao Luis, MA (Brazil); Andrade, F.M. [Universidade Estadual de Ponta Grossa, Departamento de Matematica e Estatistica, Ponta Grossa, PR (Brazil); Filgueiras, C. [Universidade Federal de Campina Grande, Departamento de Fisica, Caixa Postal 10071, Campina Grande, PB (Brazil); Belich, H. [Universidade Federal do Espirito Santo, Departamento de Fisica e Quimica, Vitoria, ES (Brazil)
2013-04-15
In this work bound states for the Aharonov-Casher problem are considered. According to Hagen's work on the exact equivalence between spin-1/2 Aharonov-Bohm and Aharonov-Casher effects, is known that the {nabla}.E term cannot be neglected in the Hamiltonian if the spin of particle is considered. This term leads to the existence of a singular potential at the origin. By modeling the problem by boundary conditions at the origin which arises by the self-adjoint extension of the Hamiltonian, we derive for the first time an expression for the bound state energy of the Aharonov-Casher problem. As an application, we consider the Aharonov-Casher plus a two-dimensional harmonic oscillator. We derive the expression for the harmonic oscillator energies and compare it with the expression obtained in the case without singularity. At the end, an approach for determination of the self-adjoint extension parameter is given. In our approach, the parameter is obtained essentially in terms of physics of the problem. (orig.)
Bound states -- from QED to QCD
Hoyer, Paul
2014-01-01
These lectures are divided into two parts. In Part 1 I discuss bound state topics at the level of a basic course in field theory: The derivation of the Schr\\"odinger and Dirac equations from the QED Lagrangian, by summing Feynman diagrams and in a Hamiltonian framework. Less well known topics include the equal-time wave function of Positronium in motion and the properties of the Dirac wave function for a linear potential. The presentation emphasizes physical aspects and provides the framework for Part 2, which discusses the derivation of relativistic bound states at Born level in QED and QCD. A central aspect is the maintenance of Poincar\\'e invariance. The transformation of the wave function under boosts is studied in detail in D=1+1 dimensions, and its generalization to D=3+1 is indicated. Solving Gauss' law for $A^0$ with a non-vanishing boundary condition leads to a linear potential for QCD mesons, and an analogous confining potential for baryons.
Local pair natural orbitals for excited states
Helmich, Benjamin; Hättig, Christof
2011-12-01
We explore how in response calculations for excitation energies with wavefunction based (e.g., coupled cluster) methods the number of double excitation amplitudes can be reduced by means of truncated pair natural orbital (PNO) expansions and localized occupied orbitals. Using the CIS(D) approximation as a test model, we find that the number of double excitation amplitudes can be reduced dramatically with minor impact on the accuracy if the excited state wavefunction is expanded in state-specific PNOs generated from an approximate first-order guess wavefunction. As for ground states, the PNO truncation error can also for excitation energies be controlled by a single threshold related to generalized natural occupation numbers. The best performance is found with occupied orbitals which are localized by the Pipek-Mezey localization. For a large test set of excited states we find with this localization that already a PNO threshold of 10-8-10-7, corresponding to an average of only 40-80 PNOs per pair, is sufficient to keep the PNO truncation error for vertical excitation energies below 0.01 eV. This is a significantly more rapid convergence with the number doubles amplitudes than in domain-based local response approaches. We demonstrate that the number of significant excited state PNOs scales asymptotically linearly with the system size in the worst case of completely delocalized excitations and sub-linearly whenever the chromophore does not increase with the system size. Moreover, we observe that the flexibility of state-specific PNOs to adapt to the character of an excitation allows for an almost unbiased treatment of local, delocalized and charge transfer excited states.
Local pair natural orbitals for excited states.
Helmich, Benjamin; Hättig, Christof
2011-12-07
We explore how in response calculations for excitation energies with wavefunction based (e.g., coupled cluster) methods the number of double excitation amplitudes can be reduced by means of truncated pair natural orbital (PNO) expansions and localized occupied orbitals. Using the CIS(D) approximation as a test model, we find that the number of double excitation amplitudes can be reduced dramatically with minor impact on the accuracy if the excited state wavefunction is expanded in state-specific PNOs generated from an approximate first-order guess wavefunction. As for ground states, the PNO truncation error can also for excitation energies be controlled by a single threshold related to generalized natural occupation numbers. The best performance is found with occupied orbitals which are localized by the Pipek-Mezey localization. For a large test set of excited states we find with this localization that already a PNO threshold of 10(-8)-10(-7), corresponding to an average of only 40-80 PNOs per pair, is sufficient to keep the PNO truncation error for vertical excitation energies below 0.01 eV. This is a significantly more rapid convergence with the number doubles amplitudes than in domain-based local response approaches. We demonstrate that the number of significant excited state PNOs scales asymptotically linearly with the system size in the worst case of completely delocalized excitations and sub-linearly whenever the chromophore does not increase with the system size. Moreover, we observe that the flexibility of state-specific PNOs to adapt to the character of an excitation allows for an almost unbiased treatment of local, delocalized and charge transfer excited states.
Coexistence of bound and virtual-bound states in shallow-core to valence x-ray spectroscopies
Sen Gupta, Subhra; Bradley, J. A.; Haverkort, M. W.; Seidler, G. T.; Tanaka, A.; Sawatzky, G. A.
2011-08-01
With the example of the non-resonant inelastic x-ray scattering (NIXS) at the O45 edges (5d→5f) of the actinides, we develop the theory for shallow-core to valence excitations, where the multiplet spread is larger than the core-hole attraction, such as if the core and valence orbitals have the same principal quantum number. This involves very strong final state configuration interaction (CI), which manifests itself as huge reductions in the Slater-Condon integrals, needed to explain the spectral shapes within a simple renormalized atomic multiplet theory. But more importantly, this results in a cross-over from bound (excitonic) to virtual-bound excited states with increasing energy, within the same core-valance multiplet structure, and in large differences between the dipole and high-order multipole transitions, as observed in NIXS. While the bound states (often higher multipole allowed) can still be modeled using local cluster-like models, the virtual-bound resonances (often dipole-allowed) cannot be interpreted within such local approaches. This is in stark contrast to the more familiar core-valence transitions between different principal quantum number shells, where all the final excited states almost invariably form bound core-hole excitons and can be modeled using local approaches. The possibility of observing giant multipole resonances for systems with high angular momentum ground states is also predicted. The theory is important to obtain ground state information from core-level x-ray spectroscopies of strongly correlated transition metal, rare-earth, and actinide systems.
Excited States in Staggered Meson Propagators
Bernard, C; De Tar, C; Gottlieb, Steven; Gregory, E B; Heller, U M; Osborn, J; Sugar, R; Toussaint, D; Louis, St; Gottlieb, Steven
2003-01-01
We report on preliminary results from multi-particle fits to meson propagators with three flavors of light dynamical quarks. We are able to measure excited states in propagators with pion quantum numbers, which we interpret as the pion 2S state, and is evidence of locality of the action. In the a_0 (0^{++}) propagators we find evidence for excited states which are probably the expected decay channels, pi+eta and K+Kbar.
Hyperquarks and bosonic preon bound states
Schmid, Michael L.; Buchmann, Alfons J.
2009-11-01
In a model in which leptons, quarks, and the recently introduced hyperquarks are built up from two fundamental spin-(1)/(2) preons, the standard model weak gauge bosons emerge as preon bound states. In addition, the model predicts a host of new composite gauge bosons, in particular, those responsible for hyperquark and proton decay. Their presence entails a left-right symmetric extension of the standard model weak interactions and a scheme for a partial and grand unification of nongravitational interactions based on, respectively, the effective gauge groups SU(6)P and SU(9)G. This leads to a prediction of the Weinberg angle at low energies in good agreement with experiment. Furthermore, using evolution equations for the effective coupling strengths, we calculate the partial and grand unification scales, the hyperquark mass scale, as well as the mass and decay rate of the lightest hyperhadron.
Hyperquarks and bosonic preon bound states
Schmid, Michael L
2013-01-01
In a model in which leptons, quarks, and the recently introduced hyperquarks are built up from two fundamental spin 1/2 preons, the standard model weak gauge bosons emerge as preon bound states. In addition, the model predicts a host of new composite gauge bosons, in particular those responsible for hyperquark and proton decay. Their presence entails a left-right symmetric extension of the standard model weak interactions and a scheme for a partial and grand unification of nongravitational interactions based on respectively the effective gauge groups SU(6)_P and SU(9)_G. This leads to a prediction of the Weinberg angle at low energies in good agreement with experiment. Furthermore, using evolution equations for the effective coupling strengths, we calculate the partial and grand unification scales, the hyperquark mass scale, as well as the mass and decay rate of the lightest hyperhadron.
Direct excitation of butterfly states in Rydberg molecules
Lippe, Carsten; Niederpruem, Thomas; Thomas, Oliver; Eichert, Tanita; Ott, Herwig
2016-05-01
Since their first theoretical prediction Rydberg molecules have become an increasing field of research. These exotic states originate from the binding of a ground state atom in the electronic wave function of a highly-excited Rydberg atom mediated by a Fermi contact type interaction. A special class of long-range molecular states, the butterfly states, were first proposed by Greene et al.. These states arise from a shape resonance in the p-wave scattering channel of a ground state atom and a Rydberg electron and are characterized by an electron wavefunction whose density distribution resembles the shape of a butterfly. We report on the direct observation of deeply bound butterfly states of Rydberg molecules of 87 Rb. The butterfly states are studied by high resolution spectroscopy of UV-excited Rydberg molecules. We find states bound up to - 50 GHz from the 25 P1/2 , F = 1 state, corresponding to binding lengths of 50a0 to 500a0 and with permanent electric dipole moments of up to 500 Debye. This distinguishes the observed butterfly states from the previously observed long range Rydberg molecules in rubidium.
Proton Halo or Skin in the Excited States of Light Nuclei
Institute of Scientific and Technical Information of China (English)
陈金根; 蔡翔舟; 张虎勇; 沈文庆; 任中洲; 蒋维洲; 马余刚; 钟晨; 魏义彬; 郭威; 周星飞; 马国亮; 王鲲
2003-01-01
Properties of nuclei 13,15N and 9B are investigated in the relativistic mean-field theory with NLZ and NL3 force parameters. The calculated binding energies are very close to the experimental ones. The calculations show that the first excited state (1p1/2) in 9B, the first excited state (2s1/2) in 13N and the second excited state (2s1/2) in 15N are weakly bound. In particular, for 13N and 15N, the proton density distributions in the two above excited states have a long tail and the rms radii of the last proton are greatly larger compared with their respective matter radii. It is predicted that a proton halo exists in the first excited state of 13N and in the second excited state of 15N, respectively. It also indicates that the first excited state in 9B is a proton skin state.
Rearrangements in ground and excited states
de Mayo, Paul
1980-01-01
Rearrangements in Ground and Excited States, Volume 3 presents essays on the chemical generation of excited states; the cis-trans isomerization of olefins; and the photochemical rearrangements in trienes. The book also includes essays on the zimmerman rearrangements; the photochemical rearrangements of enones; the photochemical rearrangements of conjugated cyclic dienones; and the rearrangements of the benzene ring. Essays on the photo rearrangements via biradicals of simple carbonyl compounds; the photochemical rearrangements involving three-membered rings or five-membered ring heterocycles;
Baryons as relativistic three-quark bound states
Eichmann, Gernot; Williams, Richard; Alkofer, Reinhard; Fischer, Christian S
2016-01-01
We review the spectrum and electromagnetic properties of baryons described as relativistic three-quark bound states within QCD. The composite nature of baryons results in a rich excitation spectrum, whilst leading to highly non-trivial structural properties explored by the coupling to external (electromagnetic and other) currents. Both present many unsolved problems despite decades of experimental and theoretical research. We discuss the progress in these fields from a theoretical perspective, focusing on nonperturbative QCD as encoded in the functional approach via Dyson-Schwinger and Bethe-Salpeter equations. We give a systematic overview as to how results are obtained in this framework and explain technical connections to lattice QCD. We also discuss the mutual relations to the quark model, which still serves as a reference to distinguish 'expected' from 'unexpected' physics. We confront recent results on the spectrum of non-strange and strange baryons, their form factors and the issues of two-photon proce...
Real weights, bound states and duality orbits
Marrani, Alessio; Romano, Luca
2015-01-01
We show that the duality orbits of extremal black holes in supergravity theories with symmetric scalar manifolds can be derived by studying the stabilizing subalgebras of suitable representatives, realized as bound states of specific weight vectors of the corresponding representation of the duality symmetry group. The weight vectors always correspond to weights that are real, where the reality properties are derived from the Tits-Satake diagram that identifies the real form of the Lie algebra of the duality symmetry group. Both N=2 magic Maxwell-Einstein supergravities and the semisimple infinite sequences of N=2 and N=4 theories in D=4 and 5 are considered, and various results, obtained over the years in the literature using different methods, are retrieved. In particular, we show that the stratification of the orbits of these theories occurs because of very specific properties of the representations: in the case of the theory based on the real numbers, whose symmetry group is maximally non-compact and there...
Bounds on the electromagnetic interactions of excited spin-3/2 leptons
Walsh, R
1999-01-01
We discuss possible deviations from QED produced by a virtual excited spin-3/2 lepton in the reaction $e^+e^- \\longrightarrow 2\\gamma$. Data recorded by the OPAL Collaboration at a c.m. energy $\\sqrt{s} = 183 GeV$ are used to establish bounds on the nonstandard-lepton mass and coupling strengths.
Manipulation of Squeezed Two-Phonon Bound States using Femtosecond Laser Pulses
Directory of Open Access Journals (Sweden)
Nakamura Kazutaka G.
2013-03-01
Full Text Available Two-phonon bound states have been excited exclusively in ZnTe(110 via impulsive stimulated second-order Raman scattering, essentially being squeezed states due to phase coherent excitation of two identical components anticorrelated in the wave vector. By using coherent control technique with a pair of femtosecond laser pulses, the manipulation of squeezed states has been demonstrated in which both the amplitude and lifetime of coherent oscillations of squeezed states are modulated, indicating the feasibility to control the quantum noise and the quantum nature of phonon squeezed states, respectively.
Review of the N-quantum Approach to Bound States
Greenberg, O W
2010-01-01
We describe a method of solving quantum field theories using operator techniques based on the expansion of interacting fields in terms of asymptotic fields. For bound states, we introduce an asymptotic field for each (stable) bound state. We choose the nonrelativistic hydrogen atom as an example to illustrate the method. Future work will apply this N-quantum approach to relativistic theories that include bound states in motion.
Precision Study of Positronium: Testing Bound State QED Theory
Karshenboim, Savely G.
2003-01-01
As an unstable light pure leptonic system, positronium is a very specific probe atom to test bound state QED. In contrast to ordinary QED for free leptons, the bound state QED theory is not so well understood and bound state approaches deserve highly accurate tests. We present a brief overview of precision studies of positronium paying special attention to uncertainties of theory as well as comparison of theory and experiment. We also consider in detail advantages and disadvantages of positro...
Electronic excited states and relaxation dynamics in polymer heterojunction systems
Ramon, John Glenn Santos
The potential for using conducting polymers as the active material in optoelectronic devices has come to fruition in the past few years. Understanding the fundamental photophysics behind their operations points to the significant role played by the polymer interface in their performance. Current device architectures involve the use of bulk heterojunctions which intimately blend the donor and acceptor polymers to significantly increase not only their interfacial surface area but also the probability of exciton formation within the vicinity of the interface. In this dissertation, we detail the role played by the interface on the behavior and performance of bulk heterojunction systems. First, we explore the relation between the exciton binding energy to the band offset in determining device characteristics. As a general rule, when the exciton binding energy is greater than the band offset, the exciton remains the lowest energy excited state leading to efficient light-emitting properties. On the other hand, if the offset is greater than the binding energy, charge separation becomes favorable leading to better photovoltaic behavior. Here, we use a Wannier function, configuration interaction based approach to examine the essential excited states and predict the vibronic absorption and emission spectra of the PPV/BBL, TFB/F8BT and PFB/F8BT heterojunctions. Our results underscore the role of vibrational relaxation in the formation of charge-transfer states following photoexcitation. In addition, we look at the relaxation dynamics that occur upon photoexcitation. For this, we adopt the Marcus-Hush semiclassical method to account for lattice reorganization in the calculation of the interconversion rates in TFB/F8BT and PFB/F8BT. We find that, while a tightly bound charge-transfer state (exciplex) remains the lowest excited state, a regeneration pathway to the optically active lowest excitonic state in TFB/F8BT is possible via thermal repopulation from the exciplex. Finally
On the nature of an excited state
Blossier, Benoit
2016-01-01
In many lattice simulations with dynamical quarks, radial or orbital excitations of hadrons lie near multihadron thresholds: it makes the extraction of excited states properties more challenging and can introduce some systematics difficult to estimate without an explicit computation of correlators using interpolating fields strongly coupled to multihadronic states. In a recent study of the strong decay of the first radial excitation of the $B^*$ meson, this issue has been investigated and we have clues that a diquark interpolating field $\\bar{b} \\gamma^i q$ is very weakly coupled to a $B \\pi$ $P$-wave state while the situation is quite different if we consider an interpolating field of the kind $\\bar{b} \
Nodal Variational Principle for Excited States
Zahariev, Federico; Levy, Mel
2016-01-01
It is proven that the exact excited-state wavefunction and energy may be obtained by minimizing the energy expectation value of a trial wave function that is constrained only to have the correct nodes of the state of interest. This excited-state nodal minimum principle has the advantage that it requires neither minimization with the con- straint of wavefunction orthogonality to all lower eigenstates nor the antisymmetry of the trial wavefunctions. It is also found that the minimization over the entire space can be partitioned into several in- terconnected minimizations within the individual nodal regions, and the exact excited-state energy may be obtained by a minimization in just one or several of these nodal regions. For the proofs of the the- orem, it is observed that the many-electron eigenfunction, restricted to a nodal region, is equivalent to a ground state wavefunction of one electron in a higher dimensional space; and an explicit excited-state energy variational expression is obtained by generalizing...
Electronic Excited States of Tungsten(0) Arylisocyanides
2015-01-01
W(CNAryl)_6 complexes containing 2,6-diisopropylphenyl isocyanide (CNdipp) are powerful photoreductants with strongly emissive long-lived excited states. These properties are enhanced upon appending another aryl ring, e.g., W(CNdippPh^(OMe)_2)_6; CNdippPh^(OMe)_2 = 4-(3,5-dimethoxyphenyl)-2,6-diisopropylphenylisocyanide (Sattler et al. J. Am. Chem. Soc. 2015, 137, 1198−1205). Electronic transitions and low-lying excited states of these complexes were investigated by time-dependent density fun...
Computing Correct Truncated Excited State Wavefunctions
Bacalis, N C; Zang, J; Karaoulanis, D
2016-01-01
We demonstrate that, if a truncated expansion of a wave function is small, then the standard excited states computational method, of optimizing one root of a secular equation, may lead to an incorrect wave function - despite the correct energy according to the theorem of Hylleraas, Undheim and McDonald - whereas our proposed method [J. Comput. Meth. Sci. Eng. 8, 277 (2008)] (independent of orthogonality to lower lying approximants) leads to correct reliable small truncated wave functions. The demonstration is done in He excited states, using truncated series expansions in Hylleraas coordinates, as well as standard configuration-interaction truncated expansions.
Relativistic bound-state equations for fermions with instantaneous interactions
Suttorp, L.G.
1979-01-01
Three types of relativistic bound-state equations for a fermion pair with instantaneous interaction are studied, viz., the instantaneous Bethe-Salpeter equation, the quasi-potential equation, and the two-particle Dirac equation. General forms for the equations describing bound states with arbitrary
Bound states in a hyperbolic asymmetric double-well
Energy Technology Data Exchange (ETDEWEB)
Hartmann, R. R., E-mail: richard.hartmann@dlsu.edu.ph [Physics Department, De La Salle University, 2401 Taft Avenue, Manila (Philippines)
2014-01-15
We report a new class of hyperbolic asymmetric double-well whose bound state wavefunctions can be expressed in terms of confluent Heun functions. An analytic procedure is used to obtain the energy eigenvalues and the criterion for the potential to support bound states is discussed.
Embedding potentials for excited states of embedded species.
Wesolowski, Tomasz A
2014-05-14
Frozen-Density-Embedding Theory (FDET) is a formalism to obtain the upper bound of the ground-state energy of the total system and the corresponding embedded wavefunction by means of Euler-Lagrange equations [T. A. Wesolowski, Phys. Rev. A 77(1), 012504 (2008)]. FDET provides the expression for the embedding potential as a functional of the electron density of the embedded species, electron density of the environment, and the field generated by other charges in the environment. Under certain conditions, FDET leads to the exact ground-state energy and density of the whole system. Following Perdew-Levy theorem on stationary states of the ground-state energy functional, the other-than-ground-state stationary states of the FDET energy functional correspond to excited states. In the present work, we analyze such use of other-than-ground-state embedded wavefunctions obtained in practical calculations, i.e., when the FDET embedding potential is approximated. Three computational approaches based on FDET, that assure self-consistent excitation energy and embedded wavefunction dealing with the issue of orthogonality of embedded wavefunctions for different states in a different manner, are proposed and discussed.
Paramagnetic excited vortex states in superconductors
Gomes, Rodolpho Ribeiro; Doria, Mauro M.; Romaguera, Antonio R. de C.
2016-06-01
We consider excited vortex states, which are vortex states left inside a superconductor once the external applied magnetic field is switched off and whose energy is lower than of the normal state. We show that this state is paramagnetic and develop here a general method to obtain its Gibbs free energy through conformal mapping. The solution for any number of vortices in any cross-section geometry can be read off from the Schwarz-Christoffel mapping. The method is based on the first-order equations used by Abrikosov to discover vortices.
Excited singlet states of "hairpin" polyenes
Froelich, Wolfgang; Dewey, Harry J.; Deger, Hans; Dick, Bernhard; Klingensmith, Kenneth A.; Puettmann, Wilhelm; Vogel, Emanuel; Hohlneicher, Georg; Michl, Josef
1983-01-01
The synthesis and UV-visible, polarized-fluorescence and MCD spectra of 6 U-shaped hairpin polyenes (e.g., I) are reported. Qual. arguments and results of p-electron calcns. permit the identification of 4 excited singlet states and their assignment to mixts. of singly and doubly excited configurations. The hairpin polyenes represent a link between the all-trans-polyenes on the 1 hand and the annulenes and acenes on the other; they have the topol. of the former and a geometry near that of the ...
Formation of deeply bound LiRb molecules via photoassociation to near asymptotic states
Lorenz, John D.
We present the results of a spectroscopic study LiRb molecules created via photoassociation (PA) to vibration levels of the 4(1) potential. Atoms are first cooled and trapped in a dual species 7Li/ 85Rb magneto-optical trap (MOT) at temperatures of ≈ 1 mK or less. In a cold sample of sufficient density, PA occurs when a resonant laser field induces a free-bound transition to create molecules in an excited electronic potential. After spontaneous emission the molecules decay to a mixture of free atoms and bound molecules depending on the Franck-Condon factors (FCFs) of the excited and ground state vibrational wavefunctions. While excited LiRb * has been previously detected by trap loss fluorescence detection, ionization spectroscopy is required to determine the population of ground state levels after decay. We detect ground state molecules via resonantly enhanced multiphoton ionization (REMPI) where a two photon ionization transition is enhanced by an intermediate resonance. The intermediate resonances match progressions from the D1pi and possibly B1Π potentials, many of which have known energies obtained from previous heat pipe experiments. This is contrary to the expectation that weakly bound LiRb * should primarily decay to weakly bound levels of the ground state and could point to a possible path for creating molecules in the rovibronic ground state.
STIRAP on helium: Excitation to Rydberg states
Yuan, Deqian
Research in optically induced transitions between dierent atomic levels has a long history. For transitions between states driven by a coherent optical eld, the theoretical eciency could be ideally high as 100% but there could be many factors preventing this. In the three state helium atom excitation process, i.e. 23S→33P→nL , the stimulated emission from intermediate state makes it hard to achieve ecient population transfer to the nal state through an intuitive excitation order. One technique to achieve a higher eciency is Stimulated Raman Adiabatic Passage (STIRAP) which is being studied and under research in our lab. Unlike traditional three level excitation processes, STIRAP actually uses a counter intuitive pulsed laser beams timing arrangement. The excitation objects are metastable helium atoms traveling in a vacuum system with a longitudinal velocity of ~ 1070 m/s. We are using a 389 nm UV laser to connect the 23S and the 33P state and a frequency tunable ~790 nm IR laser to connect the 33P state and the dierent Rydberg states. A third 1083 nm wavelength laser beam drives the 23S → 23P transition to transversely separate the residual metastable atoms and the Rydberg atoms for eciency measurements. The data is taken by a stainless steel detector in the vacuum system. As the Rydberg atoms will get ionized by blackbody radiation under room temperature, we can utilize this for their detection. An ion detector sitting on the eld plate is capable to collect the ion signals of the Rydberg atoms for detection. So far the whole system has not been ready for data collection and measurement, so here we are using data and results from previous theses for discussions. The highest transition frequency that has ever been achieved in our lab is around 70% after corrections.
Bound state spectra of the 3D rational potential
Roy, Amlan K; Proynov, Emil I
2010-01-01
We present bound state spectra of the 3D rational potential, $V(r)=r^2 + \\lambda r^2/(1+gr^2)$, $g>0$, by means of the generalized pseudospectral method. All the thirty states corresponding to $n$=0--9 are considered for the first time for a broad range of coupling parameters. These results surpass the accuracy of \\emph{all} other existing calculations published so far except the finite-difference method, which yields similar accuracy as ours. Variation of energies and radial distribution functions is followed with respect to the interaction parameters. Special emphasis has been laid on \\emph{higher} excitations and \\emph{negative} values of the interaction, where relatively less work has been reported. The energy sequence is found to be different for positive and negative interaction; numerically following a mirror-image relationship \\emph{usually}, if not always. Additionally, twenty energy splittings arising from certain levels belonging to $n$=0--9 are systematically studied as functions of the potential ...
Second Bound State of Biexcitons in Quantum Dots
Institute of Scientific and Technical Information of China (English)
XIE Wen-Eang
2003-01-01
The second bound state of the biexcitons in a quantum dot, with orbital angular momentum L = 1, is reported. By using the method of few-body physics, the binding energy spectra of the second bound state of a biexciton in a GaAs quantum dot with a parabolic confinement have been calculated as a function of the electron-to-hole mass ratio and the quantum dot size. The fact that the biexcitons have a second bound state may aid in the better understanding of their binding mechanism.
Excited-state relaxation of some aminoquinolines
Directory of Open Access Journals (Sweden)
2006-01-01
Full Text Available The absorption and fluorescence spectra, fluorescence quantum yields and lifetimes, and fluorescence rate constants ( k f of 2-amino-3-( 2 ′ -benzoxazolylquinoline (I, 2-amino-3-( 2 ′ -benzothiazolylquinoline (II, 2-amino-3-( 2 ′ -methoxybenzothiazolyl-quinoline (III, 2-amino-3-( 2 ′ -benzothiazolylbenzoquinoline (IV at different temperatures have been measured. The shortwavelength shift of fluorescence spectra of compounds studied (23–49 nm in ethanol as the temperature decreases (the solvent viscosity increases points out that the excited-state relaxation process takes place. The rate of this process depends essentially on the solvent viscosity, but not the solvent polarity. The essential increasing of fluorescence rate constant k f (up to about 7 times as the solvent viscosity increases proves the existence of excited-state structural relaxation consisting in the mutual internal rotation of molecular fragments of aminoquinolines studied, followed by the solvent orientational relaxation.
Rearrangements in ground and excited states
de Mayo, Paul
1980-01-01
Rearrangements in Ground and Excited States, Volume 2 covers essays on the theoretical approach of rearrangements; the rearrangements involving boron; and the molecular rearrangements of organosilicon compounds. The book also includes essays on the polytopal rearrangement at phosphorus; the rearrangement in coordination complexes; and the reversible thermal intramolecular rearrangements of metal carbonyls. Chemists and people involved in the study of rearrangements will find the book invaluable.
D. A. Horke; Roberts, G.M.; Verlet, J. R. R.
2011-01-01
The spectroscopy and ultrafast relaxation dynamics of excited states of the radical anion of a representative charge-transfer acceptor molecule, 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane, have been studied in the gas phase using time-resolved photoelectron spectroscopy. The photoelectron spectra reveal that at least two anion excited states are bound. Time-resolved studies show that both excited states are very short-lived and internally convert to the anion ground state, with the ...
Entanglement bounds for squeezed non-symmetric thermal state
Jiang, L
2003-01-01
I study the three parameters bipartite quantum Gaussian state called squeezed asymmetric thermal state, calculate Gaussian entanglement of formation analytically and the up bound of relative entropy of entanglement, compare them with coherent information of the state. Based on the result obtained, it is anticipated that hashing inequality is not violated for squeezed non-symmetric thermal state.
Quasi-bound states in strained graphene
Bahamon, Dario; Qi, Zenan; Park, Harold; Pareira, Vitor; Campbell, David
In this work, we explore the possibility of manipulating electronic states in graphene nanostructures by mechanical means. Specifically, we use molecular dynamics and tight-binding models to access the electronic and transport properties of strained graphene nanobubbles and graphene kirigami. We establish that low energy electrons can be confined in the arms of the kirigami and within the nanobubbles; under different load conditions the coupling between confined states and continuous states is modified creating different conductance line-shapes.
Metastable states in parametrically excited multimode Hamiltonian systems
Kirr, E
2003-01-01
Consider a linear autonomous Hamiltonian system with time periodic bound state solutions. In this paper we study their dynamics under time almost periodic perturbations which are small, localized and Hamiltonian. The analysis proceeds through a reduction of the original infinite dimensional dynamical system to the dynamics of two coupled subsystems: a dominant m-dimensional system of ordinary differential equations (normal form), governing the projections onto the bound states and an infinite dimensional dispersive wave equation. The present work generalizes previous work of the authors, where the case of a single bound state is considered. Here, the interaction picture is considerably more complicated and requires deeper analysis, due to a multiplicity of bound states and the very general nature of the perturbation's time dependence. Parametric forcing induces coupling of bound states to continuum radiation modes, bound states directly to bound states, as well as coupling among bound states, which is mediate...
Baryons as relativistic three-quark bound states
Eichmann, Gernot; Sanchis-Alepuz, Hèlios; Williams, Richard; Alkofer, Reinhard; Fischer, Christian S.
2016-11-01
We review the spectrum and electromagnetic properties of baryons described as relativistic three-quark bound states within QCD. The composite nature of baryons results in a rich excitation spectrum, whilst leading to highly non-trivial structural properties explored by the coupling to external (electromagnetic and other) currents. Both present many unsolved problems despite decades of experimental and theoretical research. We discuss the progress in these fields from a theoretical perspective, focusing on nonperturbative QCD as encoded in the functional approach via Dyson-Schwinger and Bethe-Salpeter equations. We give a systematic overview as to how results are obtained in this framework and explain technical connections to lattice QCD. We also discuss the mutual relations to the quark model, which still serves as a reference to distinguish 'expected' from 'unexpected' physics. We confront recent results on the spectrum of non-strange and strange baryons, their form factors and the issues of two-photon processes and Compton scattering determined in the Dyson-Schwinger framework with those of lattice QCD and the available experimental data. The general aim is to identify the underlying physical mechanisms behind the plethora of observable phenomena in terms of the underlying quark and gluon degrees of freedom.
Bound states of two-dimensional relativistic harmonic oscillators
Institute of Scientific and Technical Information of China (English)
Qiang Wen-Chao
2004-01-01
We give the exact normalized bound state wavefunctions and energy expressions of the Klein-Gordon and Dirac equations with equal scalar and vector harmonic oscillator potentials in the two-dimensional space.
On the bound states for the Aharonov-Casher systems
Silva, E O; Belich, H; Filgueiras, C
2012-01-01
The bound states for the Aharonov-Casher problem is considered. According to the Hagen's work on the exact equivalence between spin-1/2 Aharonov-Bohm and Aharonov-Casher effects, is known that the $\\boldsymbol{\
Higgs interchange and bound states of superheavy fermions
Indian Academy of Sciences (India)
M De Sanctis
2013-09-01
Hypothetical superheavy fourth-generation fermions with a very small coupling with the rest of the Standard Model can give rise to long enough lived bound states. The production and the detection of these bound states would be experimentally feasible at the LHC. Extending, in the present study, the analysis of other authors, a semirelativistic wave equation is solved using an accurate numerical method to determine the binding energies of these possible superheavy fermion-bound states. The interaction given by the Yukawa potential of the Higgs boson exchange is considered; the corresponding relativistic corrections are calculated by means of a model based on the covariance properties of the Hamiltonian. We study the effects given by the Coulomb force. Moreover, we calculate the contributions given by the Coulombic and confining terms of the strong interaction in the case of superheavy quark bound states. The results of the model are critically analysed.
Identification of excited states in conjugated polymers
Hartwell, L J
2003-01-01
This thesis reports quasi steady state photoinduced absorption measurements from three conjugated polymers: polypyridine (PPy), polyfluorene (PFO) and the emeraldine base (EB) form of polyaniline. The aim of these experiments was to determine the nature of the photoexcited states existing in these materials in the millisecond time domain, as this has important consequences for the operation of real devices manufactured using these materials. The results from the photoinduced absorption experiments are closely compared with published results from pulse radiolysis experiments. In all cases there is very good correspondence between the two data sets, which has enabled the photoexcited states to be assigned with a high degree of confidence. Quasi steady-state photoinduced absorption involves the measurement of the change in absorption of a material in response to optical excitation with a laser beam. The changes in absorption are small, so a instrument was developed and optimised for each different sample. Lock-i...
Holographic Construction of Excited CFT States
Christodoulou, Ariana
2016-01-01
We present a systematic construction of bulk solutions that are dual to CFT excited states. The bulk solution is constructed perturbatively in bulk fields. The linearised solution is universal and depends only on the conformal dimension of the primary operator that is associated with the state via the operator-state correspondence, while higher order terms depend on detailed properties of the operator, such as its OPE with itself and generally involve many bulk fields. We illustrate the discussion with the holographic construction of the universal part of the solution for states of two dimensional CFTs, either on $R \\times S^1$ or on $R^{1,1}$. We compute the 1-point function both in the CFT and in the bulk, finding exact agreement. We comment on the relation with other reconstruction approaches.
Narrow deeply bound K- and p atomic states
Friedman, E.; Gal, A.
2000-01-01
Examples of recently predicted narrow `deeply bound' K- and p atomic states are shown. The saturation of widths for strong absorptive potentials due to the induced repulsion, and the resulting suppression of atomic wave functions within the nucleus, are demonstrated. Production reactions for K- atomic states using φ(1020) decay, and the (p,p) reaction for p atomic states, are discussed.
Bicudo, P.; Cardoso, M.
2016-11-01
We address q q Q ¯Q ¯ exotic tetraquark bound states and resonances with a fully unitarized and microscopic quark model. We propose a triple string flip-flop potential, inspired by lattice QCD tetraquark static potentials and flux tubes, combining meson-meson and double Y potentials. Our model includes the color excited potential, but neglects the spin-tensor potentials, as well as all the other relativistic effects. To search for bound states and resonances, we first solve the two-body mesonic problem. Then we develop fully unitary techniques to address the four-body tetraquark problem. We fold the four-body Schrödinger equation with the mesonic wave functions, transforming it into a two-body meson-meson problem with nonlocal potentials. We find bound states for some quark masses, including the one reported in lattice QCD. Moreover, we also find resonances and calculate their masses and widths, by computing the T matrix and finding its pole positions in the complex energy plane, for some quantum numbers. However, a detailed analysis of the quantum numbers where binding exists shows a discrepancy with recent lattice QCD results for the l l b ¯ b ¯ tetraquark bound states. We conclude that the string flip-flop models need further improvement.
NOON states via a quantum walk of bound particles
Compagno, Enrico; Banchi, Leonardo; Gross, Christian; Bose, Sougato
2017-01-01
Tight-binding lattice models allow the creation of bound composite objects which, in the strong-interacting regime, are protected against dissociation. We show that a local impurity in the lattice potential can generate a coherent split of an incoming bound particle wave packet which consequently produces a NOON state between the endpoints. This is nontrivial because, when finite lattices are involved, edge-localization effects render challenging their use for nonclassical state generation and information transfer. We derive an effective model to describe the propagation of bound particles in a Bose-Hubbard chain. We introduce local impurities in the lattice potential to inhibit localization effects and to split the propagating bound particle, thus enabling the generation of distant NOON states. We analyze how minimal engineering transfer schemes improve the transfer fidelity and we quantify the robustness to typical decoherence effects in optical lattice implementations. Our scheme potentially has an impact on quantum-enhanced atomic interferometry in a lattice.
Effects of QCD bound states on dark matter relic abundance
Liew, Seng Pei; Luo, Feng
2017-02-01
We study scenarios where there exists an exotic massive particle charged under QCD in the early Universe. We calculate the formation and dissociation rates of bound states formed by pairs of these particles, and apply the results in dark matter (DM) coannihilation scenarios, including also the Sommerfeld effect. We find that on top of the Sommerfeld enhancement, bound-state effects can further significantly increase the largest possible DM masses which can give the observed DM relic abundance, by ˜ 30-100% with respect to values obtained by considering the Sommerfeld effect only, for the color triplet or octet exotic particles we consider. In particular, it indicates that the Bino DM mass in the right-handed stop-Bino coannihilation scenario in the Minimal Supersymmetric extension of the Standard Model (MSSM) can reach ˜ 2.5 TeV, even though the potential between the stop and antistop prior to forming a bound state is repulsive. We also apply the bound-state effects in the calculations of relic abundance of long-lived or metastable massive colored particles, and discuss the implications on the BBN constraints and the abundance of a super-weakly interacting DM. The corrections for the bound-state effect when the exotic massive colored particles also carry electric charges, and the collider bounds are also discussed.
PROPENSITY RULES IN Ar—IMPACT EXCITATION OF H— IN DOUBLY EXCITED STATES
Institute of Scientific and Technical Information of China (English)
NaotoKoyama; MotoiMaeda; 等
1990-01-01
We have theoretically investigated excitation processes of H- ions in the doubly excited states by Ar-impact,using the impulse approximation and employing the hyperspherical wavefunctions.We have found that the H- ion in the double excited states tends to conserve its initial states as a “floppy linear triatomic molecule” during excitation processes except for the restriction arising from the Pauli exclusion principle for two atomic electrons.
Bound and continuum vibrational states of the bifluoride anion
Špirko, V.; Šindelka, M.; Shirsat, R. N.; Leszczynski, J.
2003-07-01
The energies of the bound vibrational states and energy density spectra of the continuum vibrational states of FHF - are calculated, 'exactly' and 'adiabatically', using a new ab initio (CCSD(T)) potential energy surface. Statistical properties of the bound states are probed in terms of the density of states and nearest neighbor level spacing distributions (NNSD). Importantly, the approximate 'adiabatic' densities coincide nearly quantitatively with their 'exact' counterparts. A quantitative fitting of the NNSDs is achieved with a new empirical modification of the Wigner distribution.
Floquet bound states around defects and adatoms in graphene
Lovey, D. A.; Usaj, Gonzalo; Foa Torres, L. E. F.; Balseiro, C. A.
2016-06-01
Recent studies have focused on laser-induced gaps in graphene which have been shown to have a topological origin, thereby hosting robust states at the sample edges. While the focus has remained mainly on these topological chiral edge states, the Floquet bound states around defects lack a detailed study. In this paper we present such a study covering large defects of different shape and also vacancy-like defects and adatoms at the dynamical gap at ℏ Ω /2 (ℏ Ω being the photon energy). Our results, based on analytical calculations as well as numerics for full tight-binding models, show that the bound states are chiral and appear in a number which grows with the defect size. Furthermore, while the bound states exist regardless of the type of the defect's edge termination (zigzag, armchair, mixed), the spectrum is strongly dependent on it. In the case of top adatoms, the bound state quasienergies depend on the adatoms energy. The appearance of such bound states might open the door to the presence of topological effects on the bulk transport properties of dirty graphene.
Bound States of a Ferromagnetic Wire in a Superconductor.
Sau, Jay D; Brydon, P M R
2015-09-18
We consider the problem of bound states in strongly anisotropic ferromagnetic impurities in a superconductor, motivated by recent experiments that claim to observe Majorana modes at the ends of ferromagnetic wires on a superconducting substrate [S. Nadj-Perge et al., Science 346, 602 (2014)]. Generalizing the successful theory of bound states of spherically symmetric impurities, we consider a wirelike potential using both analytical and numerical approaches. We find that away from the ends of the wire the bound states form bands with pronounced van Hove singularities, giving rise to subgap peaks in the local density of states. For sufficiently strong magnetization of the wire, we show that this process generically produces a sharp peak at zero energy in the local density of states near the ends of the wire. This zero-energy peak has qualitative similarities to the claimed signature of a Majorana mode observed in the aforementioned experiment.
Excited states of muonium in atomic hydrogen
Indian Academy of Sciences (India)
V S Kulhar
2006-06-01
Muonium formation in excited states in muon-hydrogen charge-exchange collision is investigated using a method developed in a previous paper. Differential cross-section results are found to resemble positronium formation cross-section results of positron-hydrogen charge-exchange problem. Forward differential and integrated cross-sections are computed for muon energy of 2 keV and higher. Total muonium formation cross-sections are computed using Jackson and Schiff scaling rules. Muonium formation cross-section results obtained from proton-hydrogen charge-exchange cross-section results, using velocity scaling are compared with the results of the present calculation.
Metastable excited states of OBr2- and OCl2- dianions
Noorisafa, Zeinab; Sabzyan, Hassan; Keshavarz, Elham
2014-11-01
Electronic stabilities, structures, properties, and spectroscopic constants of the halogen oxide dianions OBr2- and OCl2- and their singly charged anions which are of astrophysical and laboratory interests have been studied. The X2Σ states of OBr2- and OCl2- are metastable with PECs having smooth wells with minima located at R = 1.859 Å and 1.776 Å, and Coulomb barriers of 40402.54987 cm-1 and 43746.63462 cm-1 heights located at RRCB = 2.100 Å and 1.922 Å, respectively, both without any vibrational states. While, the B2Σ state of OBr2- and the A2Σ state of OCl2- are metastable with PECs having wells deep enough to suite several bound states, with minima located at Re = 1.773 Å and 1.6430 Å, and Coulomb barriers of 191437.45813 cm-1 and 180550.70294 cm-1 heights located at RRCB = 2.658 Å and 2.4480 Å, with De = 1.26470 eV and 1.60837 eV, respectively. The OBr- and OCl- singly charged anions are stable in their ground states. Based on the calculated Frank-Condon factors, it is concluded that metastable excited state OBr2- and OCl2- dianions and ground state OBr- and OCl- singly charged anions can be formed via electron capture processes.
The polaron: Ground state, excited states, and far from equilibrium
Energy Technology Data Exchange (ETDEWEB)
Trugman, S.A. [Los Alamos National Lab., NM (United States). Theory Div.; Bonca, J. [Univ. of Ljubljana (Slovenia)]|[Jozef Stefan Inst., Ljubljana (Slovenia)
1998-12-01
The authors describe a variational approach for solving the Holstein polaron model with dynamical quantum phonons on an infinite lattice. The method is simple, fast, extremely accurate, and gives ground and excited state energies and wavefunctions at any momentum k. The method can also be used to calculate coherent quantum dynamics for inelastic tunneling and for strongly driven polarons far from equilibrium.
Boson bound states in the -Fermi–Pasta–Ulam model
Indian Academy of Sciences (India)
Xin-Guang Hu; Ju Xiang; Zheng Jiao; Yang Liu; Guo-Qiu Xie; Ke Hu
2013-11-01
The bound states of four bosons in the quantum -Fermi–Pasta–Ulam model are investigated and some interesting results are presented using the number conserving approximation combined with the number state method. We find that the relative magnitude of anharmonic coefficient has a significant effect on forming localized energy in the model, and the wave number plays an important role in forming different bound states. The signature of the quantum breather is also set up by the square of the amplitudes of the corresponding eigenvectors in real space.
Bound States of the q-Deformed AdS5 x S5 Superstring S-matrix
Hoare, Ben; Miramontes, J Luis
2012-01-01
The investigation of the q deformation of the S-matrix for excitations on the string world sheet in AdS5 x S5 is continued. We argue that due to the lack of Lorentz invariance the situation is more subtle than in a relativistic theory in that the nature of bound states depends on their momentum. At low enough momentum |p|1. This subtlety fixes a problem involving the consistency of crossing symmetry with the relativistic limit found in earlier work. With mirror kinematics, obtained after a double Wick rotation, the bound state structure is simpler and there are no marginally unstable bound states.
Relaxed excited states of color centers
Energy Technology Data Exchange (ETDEWEB)
Baldacchini, G.
1992-12-31
Color centers in alkali halides display an optical cycle which has been, and it is still today, a model case for similar processes in other materials. Moreover, the luminescence of some color centers is so efficient that it has been used in laser applications. However, the quantum state from which the emission of light is originated, the so called relaxed excited state (RES), is not very well known. Indeed, in spite of the wealth of experimental results collected and of the theoretical approaches attempted, an exact description of the RES is still missing. This paper, confined mainly to F centers which are the simplest point defects in crystals, contains a review of the main experimental evidences which has some light on the nature of the RES, with special emphasis on the latest magneto-optical experiments. Also, a description of the theoretical models is attempted whenever required by a particular argument.
The dispersed fluorescence spectrum of NaAr - Ground and excited state potential curves
Tellinghuisen, J.; Ragone, A.; Kim, M. S.; Auerbach, D. J.; Smalley, R. E.; Wharton, L.; Levy, D. H.
1979-01-01
Potential curves for the ground state and the first excited state of NaAr were determined. The van der Waals molecule NaAr was prepared by supersonic free jet expansion of a mixture of sodium, argon, and helium. The electronic transition from the ground state to the first excited state A2pi was excited by a tunable dye laser and the resulting fluorescence was studied. The dispersed fluorescence spectra show discrete and diffuse features, corresponding to transitions from excited vibrational levels of the A state to bound and unbound levels of the x state. The characteristic reflection structure in the bound-free spectra permits an unambiguous assignment of the vibrational numbering in the A state, and this assignment together with previously measured spectroscopic constants are used to calculate the potential curve of the A state. The discrete structure in the fluorescence spectra is used to determine the potential curve of the x state in the well region, and the repulsive part of the X curve is then deduced through trial-and-error simulation of the bound-free spectra.
Conformation-Selective Resonant Photoelectron Spectroscopy via Dipole-Bound States of Cold Anions.
Huang, Dao-Ling; Liu, Hong-Tao; Ning, Chuan-Gang; Wang, Lai-Sheng
2015-06-18
Molecular conformation is important in chemistry and biochemistry. Conformers connected by low energy barriers can only be observed at low temperatures and are difficult to be separated. Here we report a new method to obtain conformation-selective spectroscopic information about dipolar molecular radicals via dipole-bound excited states of the corresponding anions cooled in a cryogenic ion trap. We observed two conformers of cold 3-hydroxyphenoxide anions [m-HO(C6H4)O(-)] in high-resolution photoelectron spectroscopy and measured different electron affinities, 18,850(8) and 18,917(5) cm(-1), for the syn and anti 3-hydroxyphenoxy radicals, respectively. We also observed dipole-bound excited states for m-HO(C6H4)O(-) with different binding energies for the two conformers due to the different dipole moments of the corresponding 3-hydroxyphenoxy radicals. Excitations to selected vibrational levels of the dipole-bound states result in conformation-selective photoelectron spectra. This method should be applicable to conformation-selective spectroscopic studies of any anions with dipolar neutral cores.
Two-body bound state problem and nonsingular scattering equations
Energy Technology Data Exchange (ETDEWEB)
Bartnik, E.A.; Haberzettl, H.; Sandhas, W.
1986-11-01
We present a new momentum space approach to the two-body problem in partial waves. In contrast to the usual momentum space approaches, we treat the bound state case with the help of an inhomogeneous integral equation which possesses solutions for all (negative) energies. The bound state energies and corresponding wave functions are identified by an additional condition. This procedure straightforwardly leads to a nonsingular formulation of the scattering problem in terms of essentially the same equation and thus unifies the descriptions of both energy regimes. We show that the properties of our momentum-space approach can be understood in terms of the so-called regular solution of the Schroedinger equation in position space. The unified description of the bound state and scattering energy regimes in terms of one single, real, and manifestly nonsingular equation allows us to construct an exact representation of the two-body off-shell T matrix in which all the bound state pole and scattering cut information is contained in one single separable term, the remainder being real, nonsingular, and vanishing half on-shell. Such a representation may be of considerable advantage as input in three-body Faddeev-type integral equations. We demonstrate the applicability of our method by calculating bound state and scattering data for the two-nucleon system with the s-wave Malfliet--Tjon III potential.
Bound states in open coupled asymmetrical waveguides and quantum wires
Amore, Paolo; Terrero-Escalante, Cesar A
2011-01-01
The behavior of bound states in asymmetric cross, T and L shaped configurations is considered. Because of the symmetries of the wavefunctions, the analysis can be reduced to the case of an electron localized at the intersection of two orthogonal crossed wires of different width. Numerical calculations show that the fundamental mode of this system remains bound for the widths that we have been able to study directly; moreover, the extrapolation of the results obtained for finite widths suggests that this state remains bound even when the width of one arm becomes infinitesimal. We provide a qualitative argument which explains this behavior and that can be generalized to the lowest energy states in each symmetry class. In the case of odd-odd states of the cross we find that the lowest mode is bounded when the width of the two arms is the same and stays bound up to a critical value of the ratio between the widths; in the case of the even-odd states we find that the lowest mode is unbound up to a critical value of...
Search for bound-state electron+positron pair decay
Bosch, F.; Hagmann, S.; Hillenbrand, P.-M.; Lane, G. J.; Litvinov, Yu. A.; Reed, M. W.; Sanjari, M. S.; Stöhlker, Th.; Torilov, S. Yu.; Tu, X. L.; Walke, P. M.
2016-09-01
The heavy ion storage rings coupled to in-flight radioactive-ion beam facilities, namely the ability to produce and store for extended periods of time radioactive nuclides in high atomic charge states, for the searchof yet unobserved decay mode - bound-state electron-positron pair decay.
Photodisintegration of a Bound State on the Torus
Meyer, Harvey B
2012-01-01
In this article the cross-section for the photodisintegration of a bound state is expressed, order by order in the multipole expansion, in terms of matrix elements between states living on the three-dimensional torus. The motivation is to make the process amenable to Monte-Carlo simulations. The case of the deuteron is discussed.
Bound state techniques to solve the multiparticle scattering problem
Carbonell, J; Fonseca, A C; Lazauskas, R
2013-01-01
Solution of the scattering problem turns to be very difficult task both from the formal as well as from the computational point of view. If the last two decades have witnessed decisive progress in ab initio bound state calculations, rigorous solution of the scattering problem remains limited to A$\\leq$4 case. Therefore there is a rising interest to apply bound-state-like methods to handle non-relativistic scattering problems. In this article the latest theoretical developments in this field are reviewed. Five fully rigorous methods will be discussed, which address the problem of nuclear collisions in full extent (including the break-up problem) at the same time avoiding treatment of the complicate boundary conditions or integral kernel singularities. These new developments allows to use modern bound-state techniques to advance significantly rigorous solution of the scattering problem.
Relativistic bound state approach to fundamental forces including gravitation
Directory of Open Access Journals (Sweden)
Morsch H.P.
2012-06-01
Full Text Available To describe the structure of particle bound states of nature, a relativistic bound state formalism is presented, which requires a Lagrangian including scalar coupling of two boson fields. The underlying mechanisms are quite complex and require an interplay of overlapping boson fields and fermion-antifermion production. This gives rise to two potentials, a boson-exchange potential and one identified with the long sought confinement potential in hadrons. With minimal requirements, two elementary massless fermions (quantons - with and without charge - and one gauge boson, hadrons and leptons but also atoms and gravitational systems are described by bound states with electric and magnetic coupling between the charges and spins of quantons. No need is found for colour, Higgs-coupling and supersymmetry.
VISCO-ELASTIC SYSTEMS UNDER BOTH DETERMINISTIC AND BOUND RANDOM PARAMETRIC EXCITATION
Institute of Scientific and Technical Information of China (English)
徐伟; 戎海武; 方同
2003-01-01
The principal resonance of a visco-elastic systems under both deterministic and random parametric excitation was investigated. The method of multiple scales was used to determine the equations of modulation of amplitude and phase. The behavior, stability and bifurcation of steady state response were studied by means of qualitative analysis. The contributions from the visco-elastic force to both damping and stiffness can be taken into account. The effects of damping, detuning, bandwidth, and magnitudes of deterministic and random excitations were analyzed. The theoretical analysis is verified by numerical results.
Bounding the persistency of the nonlocality of W states
Diviánszky, Péter; Trencsényi, Réka; Bene, Erika; Vértesi, Tamás
2016-04-01
The nonlocal properties of the W states are investigated under particle loss. By removing all but two particles from an N -qubit W state, the resulting two-qubit state is still entangled. Hence, the W state has high persistency of entanglement. We ask an analogous question regarding the persistency of nonlocality [see N. Brunner and T. Vértesi, Phys. Rev. A 86, 042113 (2012), 10.1103/PhysRevA.86.042113]. Namely, we inquire what is the minimal number of particles that must be removed from the W state so that the resulting state becomes local. We bound this value in function of N qubits by considering Bell nonlocality tests with two alternative settings per site. In particular, we find that this value is between 2 N /5 and N /2 for large N . We also develop a framework to establish bounds for more than two settings per site.
Force-producing ADP state of myosin bound to actin.
Wulf, Sarah F; Ropars, Virginie; Fujita-Becker, Setsuko; Oster, Marco; Hofhaus, Goetz; Trabuco, Leonardo G; Pylypenko, Olena; Sweeney, H Lee; Houdusse, Anne M; Schröder, Rasmus R
2016-03-29
Molecular motors produce force when they interact with their cellular tracks. For myosin motors, the primary force-generating state has MgADP tightly bound, whereas myosin is strongly bound to actin. We have generated an 8-Å cryoEM reconstruction of this state for myosin V and used molecular dynamics flexed fitting for model building. We compare this state to the subsequent state on actin (Rigor). The ADP-bound structure reveals that the actin-binding cleft is closed, even though MgADP is tightly bound. This state is accomplished by a previously unseen conformation of the β-sheet underlying the nucleotide pocket. The transition from the force-generating ADP state to Rigor requires a 9.5° rotation of the myosin lever arm, coupled to a β-sheet rearrangement. Thus, the structure reveals the detailed rearrangements underlying myosin force generation as well as the basis of strain-dependent ADP release that is essential for processive myosins, such as myosin V.
A Density Matrix Renormalization Group Approach to an Asymptotically Free Model with Bound States
Martín-Delgado, M A
1999-01-01
We apply the DMRG method to the 2 dimensional delta function potential which is a simple quantum mechanical model with asymptotic freedom and formation of bound states. The system block and the environment block of the DMRG contain the low energy and high energy degrees of freedom, respectively. The ground state energy and the lowest excited states are obtained with an unprecedent accuracy. We compare the DMRG method with the Similarity RG method and propose its generalization to field theoretical models in high energy physics.
Flow Equations for N Point Functions and Bound States
Ellwanger, Ulrich
1994-01-01
We discuss the exact renormalization group or flow equation for the effective action and its decomposition into one particle irreducible N point functions. With the help of a truncated flow equation for the four point function we study the bound state problem for scalar fields. A combination of analytic and numerical methods is proposed, which is applied to the Wick-Cutkosky model and a QCD-motivated interaction. We present results for the bound state masses and the Bethe-Salpeter wave function. (Figs. 1-4 attached as separate uuencoded post-script files.)
How much double excitation character do the lowest excited states of linear polyenes have?
Starcke, Jan Hendrik; Wormit, Michael; Schirmer, Jochen; Dreuw, Andreas
2006-10-01
Doubly excited states play important roles in the low-energy region of the optical spectra of polyenes and their investigation has been subject of theoretical and experimental studies for more than 30 years now and still is in the focus of ongoing research. In this work, we address the question why doubly excited states play a role in the low-energy region of the optical spectrum of molecular systems at all, since from a naive point of view one would expect their excitation energy approximately twice as large as the one of the corresponding single excitation. Furthermore, we show that extended-ADC(2) is well suited for the balanced calculation of the low-lying excited 21Ag-, 11Bu- and 11Bu+ states of long all- trans polyenes, which are known to possess substantial double excitation character. A careful re-investigation of the performance of TDDFT calculations for these states reveals that the previously reported good performance for the 21Ag- state relies heavily on fortuitous cancellation of errors. Finally, the title question is answered such that for short polyenes the lowest excited 21Ag- and 11Bu- states can clearly be classified as doubly excited, whereas the 11Ag- ground state is essentially represented by the (ground-state) HF determinant. For longer polyenes, in addition to increasing double excitation contributions in the 21Ag- and 11Bu- states, the ground state itself aquires substantial double excitation character (45% in C 22H 24), so that the transition from the ground state to these excited states should not be addressed as the excitation of two electrons relative to the 11Ag- ground state.
Helical bound states in the continuum of the edge states in two dimensional topological insulators
Energy Technology Data Exchange (ETDEWEB)
Sablikov, Vladimir A., E-mail: sablikov@gmail.com; Sukhanov, Aleksei A.
2015-09-04
We study bound states embedded into the continuum of edge states in two-dimensional topological insulators. These states emerge in the presence of a short-range potential of a structural defect coupled to the boundary. In this case the edge states flow around the defect and have two resonances in the local density of states. The bound state in continuum (BIC) arises due to an interference of the resonances when they are close to the degeneracy. We find the condition under which the BIC appears, study the spacial distribution of the electron density, and show that the BIC has a helical structure with an electron current circulating around the defect. - Highlights: • We find bound states in the continuum of edge states in 2D topological insulators. • The bound states are induced by an impurity potential and topological order. • The bound state in the continuum has a helical structure of spin and current density.
Horke, Daniel A; Roberts, Gareth M; Verlet, Jan R R
2011-08-04
The spectroscopy and ultrafast relaxation dynamics of excited states of the radical anion of a representative charge-transfer acceptor molecule, 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane, have been studied in the gas phase using time-resolved photoelectron spectroscopy. The photoelectron spectra reveal that at least two anion excited states are bound. Time-resolved studies show that both excited states are very short-lived and internally convert to the anion ground state, with the lower energy state relaxing within 200 fs and a near-threshold valence-excited state relaxing on a 60 fs time scale. These excited states, and in particular the valence-excited state, present efficient pathways for electron-transfer reactions in the highly exergonic inverted region which commonly displays rates exceeding predictions from electron-transfer theory.
Directional detection of dark matter in universal bound states
Laha, Ranjan
2015-01-01
It has been suggested that several small-scale structure anomalies in $\\Lambda$CDM cosmology can be solved by strong self-interaction between dark matter particles. It was shown by Braaten and Hammer that the presence of a near threshold S-wave resonance can make the scattering cross section at nonrelativistic speeds come close to saturating the unitarity bound. This can result in the formation of a stable bound state of two asymmetric dark matter particles (which we call darkonium). Laha and Braaten studied the nuclear recoil energy spectrum in dark matter direct detection experiments due to this incident bound state. Here we study the angular recoil spectrum, and show that it is uniquely determined up to normalization by the S-wave scattering length. Observing this angular recoil spectrum in a dark matter directional detection experiment will uniquely determine many of the low-energy properties of dark matter independent of the underlying dark matter microphysics.
Excitation and ionization of hydrogen Rydberg states in a plasma
Energy Technology Data Exchange (ETDEWEB)
Glab, W.; Nayfeh, M.H.
1982-08-01
Hydrogen Rydberg states in a hydrogen plasma are optically excited from the plasma-excited n = 2 state. Photoionization and optogalvanic, which are due to electron-impact ionization and other collisional processes, are used to monitor the Rydberg states. This process may be used to study collisional ionization of the Rydberg states.
Excitation and ionization of hydrogen Rydberg states in a plasma.
Glab, W; Nayfeh, M H
1982-08-01
Hydrogen Rydberg states in a hydrogen plasma are optically excited from the plasma-excited n = 2 state. Photoionization and optogalvanic ionization, which is due to electron-impact ionization and other collisional processes, are used to monitor the Rydberg states. This process may be used to study collisional ionization of the Rydberg states.
ɛ-bounded state estimation for time-delay systems with bounded disturbances
Nam, P. T.; Pathirana, P. N.; Trinh, H.
2014-09-01
A new problem on ε-bounded functional state estimation for time-delay systems with unknown bounded disturbances is studied in this paper. In the presence of unknown bounded disturbances, the common assumption regarding the observer's matching condition is no longer required. In this regard, instead of achieving asymptotic convergence for the observer error, the error is now required to converge exponentially within a ball with a small radius ε > 0. This means that the estimate converges exponentially within an ε-bound of the true value. A general observer that utilises multiple-delayed output and input information is proposed. Sufficient conditions for the existence of the proposed observer are first given. We then employ an extended Lyapunov-Krasovskii functional which combines the delay-decomposition technique with a triple-integral term to study the ε-convergence problem of the observer error system. Moreover, the obtained results are shown to be more effective than the existing results for the cases with no disturbances and/or no time delay. Three numerical examples are given to illustrate the obtained results.
A Lorentz covariant approach to the bound state problem
Micu, L
2000-01-01
The relativistic equivalent of the Schr\\"odinger equation for a two particle bound state having the total angular momentum $S$ is written in the form of a Lorentz covariant set of equations (p_1^mu+p_2^mu+Omega^mu)Psi(p_1,p_2;P) chi_S(\\vec{p}_1,\\vec{p}_2)=P^mu Psi(p_1,p_2;P) chi_S(\\vec{p}_1,\\vec{p}_2) where the operators Omega^mu are the components of a 4-vector quasipotential. The solution of this set is a stationary function representing the distribution of spins and internal momenta in a reference frame where the momentum of the bound system is P^\\mu. The contribution of the operators Omega^mu to the bound state momentum is assumed to be the 4-momentum of a vacuum-like effective field entering the bound system as an independent component. It is shown that a state made of free quarks and of the effective field has definite mass and can be normalized like a single particle state. The generalization to the case of three or more particles is immediate.
The S-matrix of String Bound States
Arutyunov, Gleb
2008-01-01
We find the S-matrix which describes the scattering of two-particle bound states of the light-cone string sigma model on AdS5xS5. We realize the M-particle bound state representation of the centrally extended su(2|2) algebra on the space of homogeneous (super)symmetric polynomials of degree M depending on two bosonic and two fermionic variables. The scattering matrix S^{MN} of M- and N-particle bound states is a differential operator of degree M+N acting on the product of the corresponding polynomials. We require this operator to obey the invariance condition and the Yang-Baxter equation, and we determine it for the two cases M=1,N=2 and M=N=2. We show that the S-matrices found satisfy generalized physical unitarity, CPT invariance, parity transformation rule and crossing symmetry. Although the dressing factor as a function of four parameters x_1^+,x_1^-,x_2^+,x_2^- is universal for scattering of any bound states, it obeys a crossing symmetry equation which depends on M and N.
Towards flavored bound states beyond rainbows and ladders
El-Bennich, B; Paracha, M A; de Melo, J P B C
2013-01-01
We give a snapshot of recent progress in solving the Dyson-Schwinger equation with a beyond rainbow-ladder ansatz for the dressed quark-gluon vertex which includes ghost contributions. We discuss the motivations for this approach with regard to heavy-flavored bound states and form factors and briefly describe future steps to be taken.
The S-matrix of string bound states
Energy Technology Data Exchange (ETDEWEB)
Arutyunov, Gleb [Institute for Theoretical Physics and Spinoza Institute, Utrecht University, 3508 TD Utrecht (Netherlands)], E-mail: g.arutyunov@phys.uu.nl; Frolov, Sergey [School of Mathematics, Trinity College, Dublin 2 (Ireland)], E-mail: frolovs@maths.tcd.ie
2008-11-21
We find the S-matrix which describes the scattering of two-particle bound states of the light-cone string sigma model on AdS{sub 5}xS{sup 5}. We realize the M-particle bound state representation of the centrally extended su(2|2) algebra on the space of homogeneous (super)symmetric polynomials of degree M depending on two bosonic and two fermionic variables. The scattering matrix S{sup MN} of M- and N-particle bound states is a differential operator of degree M+N acting on the product of the corresponding polynomials. We require this operator to obey the invariance condition and the Yang-Baxter equation, and we determine it for the two cases M=1,N=2 and M=N=2. We show that the S-matrices found satisfy generalized physical unitarity, CPT invariance, parity transformation rule and crossing symmetry. Although the dressing factor as a function of four parameters x{sub 1}{sup +},x{sub 1}{sup -},x{sub 2}{sup +},x{sub 2}{sup -} is universal for scattering of any bound states, it obeys a crossing symmetry equation which depends on M and N.
In-medium K̄ interactions and bound states
Directory of Open Access Journals (Sweden)
Gal Avraham
2014-01-01
Full Text Available Correct treatment of subthreshold K̄ N dynamics is mandatory in K− -atom and K̄ -nuclear bound-state calculations, as demonstrated by using in-medium chirally-based models of K̄ N interactions. Recent studies of kaonic atom data reveal appreciable multi-nucleon contributions. K̄ -nuclear widths larger than 50 MeV are anticipated.
Calculation of size for bound-state constituents
Glazek, Stanislaw D
2014-01-01
Elements are given of a calculation that identifies the size of a proton in the Schroedinger equation for lepton-proton bound states, using the renormalization group procedure for effective particles (RGPEP) in quantum field theory, executed only up to the second order of expansion in powers of the coupling constant. Already in this crude approximation, the extraction of size of a proton from bound-state observables is found to depend on the lepton mass, so that the smaller the lepton mass the larger the proton size extracted from the same observable bound-state energy splitting. In comparison of Hydrogen and muon-proton bound-state dynamics, the crude calculation suggests that the difference between extracted proton sizes in these two cases can be a few percent. Such values would match the order of magnitude of currently discussed proton-size differences in leptonic atoms. Calculations using the RGPEP of higher order than second are required for a precise interpretation of the energy splittings in terms of t...
The local characteristics of the bound states of muonic molecules
Energy Technology Data Exchange (ETDEWEB)
Abramov, D.I. [Sankt Peterburgskij Univ., St. Petersburg (Russian Federation); Bogdanova, L.N. [Institute of Theoretical and Experimental Physics, Moscow (Russian Federation); Gusev, V.V. [Institut Fiziki Vysokikh Ehnergij, Protvino (Russian Federation); Ponomarev, L.I. [Rossijskij Nauchnyj Tsentr ``Kurchatovskij Inst.``, Moscow (Russian Federation)
1996-10-01
The sticking probabilities {omega}{sup Jv}, G- and {gamma}-factors for all bound states of mesic molecules HH{mu}, HD{mu}, HT{mu}, DD{mu}, DT{mu}, and TT{mu} with J = 0 and v = 0, 1 have been calculated in the adiabatic hyperspherical approach (AHSA). (orig.). 6 refs.
Excited State Dynamics in Carbon Nanotubes
Miyamoto, Yoshiyuki
2004-03-01
Carbon nanotube, one of the most promising materials for nano-technology, still suffers from its imperfection in crystalline structure that will make performance of nanotube behind theoretical limit. From the first-principles simulations, I propose efficient methods to overcome the imperfection. I show that photo-induced ion dynamics can (1) identify defects in nanotubes, (2) stabilize defected nanotubes, and (3) purify contaminated nanotubes. All of these methods can be alternative to conventional heat treatments and will be important techniques for realizing nanotube-devices. Ion dynamics under electronic excitation has been simulated with use of the computer code FPSEID (First-Principles Simulation tool for Electron Ion Dynamics) [1], which combines the time-dependent density functional method [2] to classical molecular dynamics. This very challenging approach is time-consuming but can automatically treat the level alternation of differently occupied states, and can observe initiation of non-adiabatic decay of excitation. The time-dependent Kohn-Sham equation has been solved by using the Suzuki-Trotter split operator method [3], which is a numerically stable method being suitable for plane wave basis, non-local pseudopotentials, and parallel computing. This work has been done in collaboration with Prof. Angel Rubio, Prof. David Tomanek, Dr. Savas Berber and Mina Yoon. Most of present calculations have been done by using the SX5 Vector-Parallel system in the NEC Fuchu-plant, and the Earth Simulator in Yokohama Japan. [1] O. Sugino and Y. Miyamoto, Phys. Rev. B59, 2579 (1999); ibid, B66 089901(E) (2001) [2] E. Runge and E. K. U. Gross, Phys. Rev. Lett. 52, 997 (1984). [3] M. Suzuki, J. Phys. Soc. Jpn. 61, L3015 (1992).
Interplay of projectile breakup and target excitation in reactions induced by weakly-bound nuclei
Gomez-Ramos, M
2016-01-01
In this work, we reexamine the extension of the CDCC formalism to include target excitation and apply it to a variety of reactions to study the effect of breakup on inelastic cross sections. We use a transformed oscillator basis to discretize the continuum of the projectiles in the different reactions and use the extended CDCC method developed in this work to solve the resulting coupled differential equations. A new code has been developed to perform the calculations. Reactions 58Ni(d, d) 58Ni*, 24Mg(d, d) 24Mg* , 144Sm( 6Li, 6Li) 144Sm* and 9Be( 6Li, 6Li) 9Be* are studied. Satisfactory agreement is found between experimental data and extended CDCC calculations. The studied CDCC method is proved to be an accurate tool to describe target excitation in reactions with weakly-bound nuclei. Moderate effects of breakup on inelastic observables are found for the reactions studied. Cross section magnitudes are not modified much, but angular distributions present smoothing when opposed to calculations without breakup.
Nonradiative formation of the positron-helium triplet bound state
di Rienzi, Joseph; Drachman, Richard J.
2007-02-01
We have previously calculated the cross section for radiative formation of the interesting bound state consisting of a positron bound to helium, where the atomic electrons are in the triplet spin state. That process uses the metastable triplet helium system as target, and, as expected, it has a very small cross section. In this paper we examine a more probable process in which the state of interest is produced in an exchange rearrangement collision between a positronium atom and the singlet helium ground state: Ps+He(Se1)→PsHe+(Se3)+e- . The present calculation is done in the plane-wave Born approximation, using simple initial and final wave functions and compares post and prior forms.
Excited State Spectra and Dynamics of Phenyl-Substituted Butadienes
DEFF Research Database (Denmark)
Wallace-Williams, Stacie E.; Schwartz, Benjamin J.; Møller, Søren
1994-01-01
A combination of steady-state and dynamic spectral measurements are used to provide new insights into the nature of the excited-state processes of all-trans-1,4-diphenyl-1,3-butadiene and several analogs: 1,4-diphenyl- 1,3-cyclopentadiene, 1,1,4,4-tetraphenylbutadiene, 1,2,3,4-tetraphenyl-1,3-cyc...... indicate that phenyl torsional motion is not important to the excited-state dynamics and reveal alternative excited-state reaction pathways. The results demonstrate how molecular systems that are structually similar can exhibit different electronic properties and excited-state dynamics....
Probing Andreev bound states in one-atom superconducting contacts
Energy Technology Data Exchange (ETDEWEB)
Pothier, Hugues; Janvier, Camille; Tosi, Leandro; Girit, Caglar; Goffman, Marcelo; Esteve, Daniel; Urbina, Cristian [Quantronics Group, SPEC, CEA-Saclay (France)
2015-07-01
Superconductors are characterized by a dissipationless current. Since the work of Josephson 50 years ago, it is known that a supercurrent can even flow through tunnel junctions between superconductors. This Josephson effect also occurs through any type of ''weak links'' between superconductors: non-superconducting materials, constrictions,.. A unified understanding of the Josephson effect has emerged from a mesoscopic description of weak links. It relies on the existence of doublets of localized states that have energies below the superconducting gap: the Andreev bound states. I will present experiments performed on the simplest conductor possible, a single-atom contact between superconductors, that illustrate these concepts. The most recent work demonstrates time-domain manipulation of quantum superpositions of Andreev bound states.
Excited states in DNA strands investigated by ultrafast laser spectroscopy.
Chen, Jinquan; Zhang, Yuyuan; Kohler, Bern
2015-01-01
Ultrafast laser experiments on carefully selected DNA model compounds probe the effects of base stacking, base pairing, and structural disorder on excited electronic states formed by UV absorption in single and double DNA strands. Direct π-orbital overlap between two stacked bases in a dinucleotide or in a longer single strand creates new excited states that decay orders of magnitude more slowly than the generally subpicosecond excited states of monomeric bases. Half or more of all excited states in single strands decay in this manner. Ultrafast mid-IR transient absorption experiments reveal that the long-lived excited states in a number of model compounds are charge transfer states formed by interbase electron transfer, which subsequently decay by charge recombination. The lifetimes of the charge transfer states are surprisingly independent of how the stacked bases are oriented, but disruption of π-stacking, either by elevating temperature or by adding a denaturing co-solvent, completely eliminates this decay channel. Time-resolved emission measurements support the conclusion that these states are populated very rapidly from initial excitons. These experiments also reveal the existence of populations of emissive excited states that decay on the nanosecond time scale. The quantum yield of these states is very small for UVB/UVC excitation, but increases at UVA wavelengths. In double strands, hydrogen bonding between bases perturbs, but does not quench, the long-lived excited states. Kinetic isotope effects on the excited-state dynamics suggest that intrastrand electron transfer may couple to interstrand proton transfer. By revealing how structure and non-covalent interactions affect excited-state dynamics, on-going experimental and theoretical studies of excited states in DNA strands can advance understanding of fundamental photophysics in other nanoscale systems.
Excited-State Effective Masses in Lattice QCD
Energy Technology Data Exchange (ETDEWEB)
George Fleming, Saul Cohen, Huey-Wen Lin
2009-10-01
We apply black-box methods, i.e. where the performance of the method does not depend upon initial guesses, to extract excited-state energies from Euclidean-time hadron correlation functions. In particular, we extend the widely used effective-mass method to incorporate multiple correlation functions and produce effective mass estimates for multiple excited states. In general, these excited-state effective masses will be determined by finding the roots of some polynomial. We demonstrate the method using sample lattice data to determine excited-state energies of the nucleon and compare the results to other energy-level finding techniques.
Systematics of α -decay transitions to excited states
Delion, D. S.; Dumitrescu, A.
2015-08-01
We systematize the available experimental material concerning α -decay transitions to low-lying excited states in even-even and odd-mass emitters. We generalize our previous theoretical prediction concerning the linear dependence between hindrance factors and the excitation energy for transitions in even-even α emitters. Thus, we show that α intensities for transitions to excited states depend linearly upon the excitation energy for all known even-even and odd-mass α emitters. It turns out that the well-known Viola-Seaborg law for α -decay transitions between ground states can be generalized for transitions to excited states. This rule can be used to predict any α -decay half-life to a low-lying excited state.
Radially Excited States of 1P Charmonium and X(3872)
Chen, Y; Liu, Y; Ma, J; Zhang, J; Chen, Ying; Liu, Chuan; Liu, Yubin; Ma, Jianping; Zhang, Jianbo
2007-01-01
The first excited states of charmonium in $0^{++}$, $1^{++}$, $1^{+-}$ channels are numerically investigated with lattice QCD of improved gauge and Wilson fermion actions, formulated on anisotropic lattices. Having determined the mass of ground states, the masses of excited states can be extracted by a constrained curve fitting algorithm which gives the masses 3.825(88) GeV, 3.853(57) GeV, and 3.858(70) Gev for the first excited states in $0^{++}$, $1^{++}$, $1^{+-}$ channels, respectively. A node structure is also observed in the Bethe-Salpeter wave-function of the $1^{++}$ state. The mass of the radically excited $1^{++}$ state is close to the mass of the newly observed X(3872). It indicates that X(3872) can be the first excited state of $\\chi_{c1}$.
How quantum bound states bounce and the structure it reveals
Lee, Dean
2010-01-01
We investigate how quantum bound states bounce from a hard surface. Our analysis has applications to ab initio calculations of nuclear structure and elastic deformation, energy levels of excitons in semiconductor quantum dots and wells, and cold atomic few-body systems on optical lattices with sharp boundaries. We develop the general theory of elastic reflection for a composite body from a hard wall. On the numerical side we present universal results for two-body states and discuss ab initio calculations for general few-body systems. On the analytical side we derive a universal effective potential that gives the reflection scattering length for shallow two-body states.
Bound states and critical behavior of the Yukawa potential
Institute of Scientific and Technical Information of China (English)
LI; Yongyao
2006-01-01
[1]Yukawa,H.,On the interaction of elementary particles,Proc.Phys.Math Soc.Jap.,1935,17:48-57.[2]Sachs,R.,Goeppert-Mayer,M.,Calculations on a new neutron-proton interaction potential,Phys.Rev.,1938,53:991-993.[3]Harris,G.,Attractive two-body interactions in partially ionized plasmas,Phys.Rev.,1962,125:1131-1140.[4]Schey,H.,Schwartz,J.,Counting the bound states in short-range central potentials,Phys.Rev.B,1965,139:1428-1432.[5]Rogers,J.,Graboske,H.,Harwood,E.,Bound eigenstates of the static screened Coulomb poten-tial,Phys.Rev.A,1970,1:1577-1586.[6]McEnnan,J.,Kissel,L.,Pratt,R.,Analytic perturbation theory for screened Coulomb potentials:non-relativistic case,Phys.Rev.A,1976,13:532-559.[7]Gerry,C.,Estimates of the ground states of the Yukawa potential from the Bogoliubov inequality,J.Phys.A,1984,17:L313-L315.[8]Kr(o)ger,H.,Girard,R.,Dufour,G.,Direct calculation of the S matrix in coordinate space,Phys.Rev.C,1988,37:486-496.[9]Girard,R.,Kr(o)ger,H.,Labelle,P.et al.,Computation of a long time evolution in a Schr(o)dinger system,Phys.Rev.A,1988,37:3195-3200.[10]Garavelli,S.,Oliveira,F.,Analytical solution for a Yukawa-type potential,Phys.Rev.Lett.,1991,66:1310-1313.[11]Gomes,O.,Chacham,H.,Mohallem,J.,Variational calculations for the bound-unbound transition of the Yukawa potential,Phys.Rev.A,1994,50:228-231.[12]Yukalov,V.,Yukalova,E.,Oliveira,F.,Renormalization-group solutions for Yukawa potential,J.Phys.A,1998,31:4337-4348.[13]Brau,F.,Necessary and sufficient conditions for existence of bound states in a central potential,J.Phys.A,2003,36:9907-9913.[14]Bertini,L.,Mella,M.,Bressanini,D.et al.,Borromean binding in H-2 with Yukawa potential:a nonadiabatic quantum Monte Carlo study,Phys.Rev.A,2004,69:042504.[15]Dean,D.,Drummond,I.,Horgan,R.,Effective diffusion constant in a two-dimensional medium of charged point scatterers,J.Phys.A,2004,37:2039-2046.[16]De-Leo,S.,Rotelli,P.,Amplification of coupling for Yukawa potentials,Phys.Rev.D,2004,69:034006.[17]Khrapak
Excited electronic states and spectroscopy of unsymmetrically substituted polyenes
Itoh, Takao
2013-09-01
α-Methyl-ω-phenylpolyenes, Me-(CH=CH)N-Ph, (MPPNs) with N = 2, 3, and 4 were synthesized. Fluorescence, absorption, and excitation spectra of MPPNs have been measured under different conditions along with those of β-methylstyrene. It is shown that there is a forbidden singlet (π, π*) excited state located at energies below the absorbing state for MPPNs with N = 3 and 4. Excitation energies of these polyenes are determined as a function of N. Quantitative analysis of the temperature dependence of the relative intensity of the fluorescence spectrum and its solvent shift behavior extract estimates of the various physical parameters that characterize excitation energies and excited-state dynamical behavior of MPPN with N = 3. The singlet excited states of the MPPNs were compared with those of the α,ω-diphenylpolyenes and α,ω-dimethylpolyenes.
Observation of Andreev bound states at spin-active interfaces
Energy Technology Data Exchange (ETDEWEB)
Beckmann, Detlef; Wolf, Michael Johannes [KIT, Institut fuer Nanotechnologie (Germany); Huebler, Florian [KIT, Institut fuer Nanotechnologie (Germany); KIT, Institut fuer Festkoerperphysik (Germany); Loehneysen, Hilbert von [KIT, Institut fuer Festkoerperphysik (Germany); KIT, Physikalisches Institut (Germany)
2013-07-01
We report on high-resolution differential conductance experiments on nanoscale superconductor/ferromagnet tunnel junctions with ultra-thin oxide tunnel barriers. We observe subgap conductance features which are symmetric with respect to bias, and shift according to the Zeeman energy with an applied magnetic field. These features can be explained by resonant transport via Andreev bound states induced by spin-active scattering at the interface. From the energy and the Zeeman shift of the bound states, both the magnitude and sign of the spin-dependent interfacial phase shifts between spin-up and spin-down electrons can be determined. These results contribute to the microscopic insight into the triplet proximity effect at spin-active interfaces.
Radial sensitivity of kaonic atoms and strongly bound K¯ states
Barnea, N.; Friedman, E.
2007-02-01
The strength of the low-energy K--nucleus real potential has recently received renewed attention in view of experimental evidence for the possible existence of strongly bound K- states. Previous fits to kaonic atom data led to either “shallow” or “deep” potentials, where only the former are in agreement with chiral approaches but only the latter can produce strongly bound states. Here we explore the uncertainties of the K--nucleus optical potentials, obtained from fits to kaonic atom data, using the functional derivatives of the best-fit χ2 values with respect to the potential. We find that only the deep type of potential provides information that is applicable to the K- interaction in the nuclear interior.
Understanding the nucleon as a Borromean bound-state
Directory of Open Access Journals (Sweden)
Jorge Segovia
2015-11-01
Full Text Available Analyses of the three valence-quark bound-state problem in relativistic quantum field theory predict that the nucleon may be understood primarily as a Borromean bound-state, in which binding arises mainly from two separate effects. One originates in non-Abelian facets of QCD that are expressed in the strong running coupling and generate confined but strongly-correlated colour-antitriplet diquark clusters in both the scalar–isoscalar and pseudovector–isotriplet channels. That attraction is magnified by quark exchange associated with diquark breakup and reformation. Diquark clustering is driven by the same mechanism which dynamically breaks chiral symmetry in the Standard Model. It has numerous observable consequences, the complete elucidation of which requires a framework that also simultaneously expresses the running of the coupling and masses in the strong interaction. Planned experiments are capable of validating this picture.
R-matrix calculations for few-quark bound states
Energy Technology Data Exchange (ETDEWEB)
Shalchi, M.A. [Instituto de Fisica Teorica, UNESP, Sao Paulo, SP (Brazil); Hadizadeh, M.R. [Ohio University, Institute of Nuclear and Particle Physics and Department of Physics and Astronomy, Athens, OH (United States); Central State University, College of Science and Engineering, Wilberforce, OH (United States)
2016-10-15
The R-matrix method is implemented to study the heavy charm and bottom diquark, triquark, tetraquark, and pentaquarks in configuration space, as the bound states of quark-antiquark, diquark-quark, diquark-antidiquark, and diquark-antitriquark systems, respectively. The mass spectrum and the size of these systems are calculated for different partial wave channels. The calculated masses are compared with recent theoretical results obtained by other methods in momentum and configuration spaces and also by available experimental data. (orig.)
Fermion Bound States Around Skyrmions in Doped Antiferromagnets
Institute of Scientific and Technical Information of China (English)
寇谡鹏
2003-01-01
We show the skyrmion effects in doped antiferromagnets for the uniform flux phase. The low-energy effective theory of the t′-J model can be mapped onto the massive quantum electrodynamics. There exist Fermion bound states around skyrmions. For each sublattice, there exist induced fractional fermion numbers around the skyrmions. The total induced fermion number is zero due to the "cancelling effect" between two sublattices with opposite charges.
R-matrix calculations for few-quark bound states
Shalchi, M. A.; Hadizadeh, M. R.
2016-10-01
The R-matrix method is implemented to study the heavy charm and bottom diquark, triquark, tetraquark, and pentaquarks in configuration space, as the bound states of quark-antiquark, diquark-quark, diquark-antidiquark, and diquark-antitriquark systems, respectively. The mass spectrum and the size of these systems are calculated for different partial wave channels. The calculated masses are compared with recent theoretical results obtained by other methods in momentum and configuration spaces and also by available experimental data.
SWKB Quantization Rules for Bound States in Quantum Wells
Sinha, A K; Sinha, Anjana; Roychoudhury, Rajkumar
2000-01-01
In a recent paper by Gomes and Adhikari (J.Phys B30 5987(1997)) a matrix formulation of the Bohr-Sommerfield quantization rule has been applied to the study of bound states in one dimension quantum wells. Here we study these potentials in the frame work of supersymmetric WKB (SWKB) quantization approximation and find that SWKB quantization rule is superior to the modified Bohr-Sommerfield or WKB rules as it exactly reproduces the eigenenergies.
Hyperons in the bound state approach with vector mesons
Schat, C L
1994-01-01
We investigate a model for hyperons based on the bound state approach in which vector mesons are explicitly incorporated. We show that for empirical values of the mesonic parameters the strange hyperon spectrum is well reproduced. We also discuss the extension of the model to heavier flavors. We show that the explicit presence of the heavy vectors leads to good predictions for the heavy baryon masses.
Lambda(1405) in the bound state soliton model
Schat, C L; Gobbi, C; Schat, C L; Scoccola, N N; Gobbi, C
1994-01-01
The strong and electromagnetic properties of the Lambda(1405) hyperon are studied in the framework of the bound state soliton model. We explicitly evaluate the strong coupling constant g(Lambda^*-N-K), the Lambda^* magnetic moment, mean square radii and radiative decay amplitudes. The results are shown to be in general agreement with available empirical data. A comparison with results of other models is also presented.
K¯ nuclear bound states in a dynamical model
Mareš, J.; Friedman, E.; Gal, A.
2006-05-01
A comprehensive data base of K-atom level shifts and widths is re-analyzed in order to study the density dependence of the K¯-nuclear optical potential. Significant departure from a tρ form is found only for ρ(r)/ρ ≲ 0.2 and extrapolation to nuclear-matter density ρ yields an attractive potential, about 170 MeV deep. Partial restoration of chiral symmetry compatible with pionic atoms and low-energy pion-nuclear data plays no role at the relevant low-density regime, but this effect is not ruled out at densities of order ρ and beyond. K¯-nuclear bound states are generated across the periodic table self consistently, using a relativistic mean-field model Lagrangian which couples the K¯ to the scalar and vector meson fields mediating the nuclear interactions. The reduced phase space available for K¯ absorption from these bound states is taken into account by adding an energy-dependent imaginary term which underlies the corresponding K¯-nuclear level widths, with a strength required by fits to the atomic data. Substantial polarization of the core nucleus is found for light nuclei, and the binding energies and widths calculated in this dynamical model differ appreciably from those calculated for a static nucleus. A wide range of binding energies is spanned by varying the K¯ couplings to the meson fields. Our calculations provide a lower limit of Γ=50±10 MeV on the width of nuclear bound states for K¯-binding energy in the range B˜100-200 MeV. Comments are made on the interpretation of the FINUDA experiment at DAΦNE which claimed evidence for deeply bound Kpp states in light nuclei.
Rapid thermal co-annihilation through bound states in QCD
Kim, Seyong; Laine, M.
2016-07-01
The co-annihilation rate of heavy particles close to thermal equilibrium, which plays a role in many classic dark matter scenarios, can be "simulated" in QCD by considering the pair annihilation rate of a heavy quark and antiquark at a temperature of a few hundred MeV. We show that the so-called Sommerfeld factors, parameterizing the rate, can be defined and measured non-perturbatively within the NRQCD framework. Lattice measurements indicate a modest suppression in the octet channel, in reasonable agreement with perturbation theory, and a large enhancement in the singlet channel, much above the perturbative prediction. The additional enhancement is suggested to originate from bound state formation and subsequent decay. Making use of a Green's function based method to incorporate thermal corrections in perturbative co-annihilation rate computations, we show that qualitative agreement with lattice data can be found once thermally broadened bound states are accounted for. We suggest that our formalism may also be applicable to specific dark matter models which have complicated bound state structures.
Matrix algorithms for solving (in)homogeneous bound state equations.
Blank, M; Krassnigg, A
2011-07-01
In the functional approach to quantum chromodynamics, the properties of hadronic bound states are accessible via covariant integral equations, e.g. the Bethe-Salpeter equation for mesons. In particular, one has to deal with linear, homogeneous integral equations which, in sophisticated model setups, use numerical representations of the solutions of other integral equations as part of their input. Analogously, inhomogeneous equations can be constructed to obtain off-shell information in addition to bound-state masses and other properties obtained from the covariant analogue to a wave function of the bound state. These can be solved very efficiently using well-known matrix algorithms for eigenvalues (in the homogeneous case) and the solution of linear systems (in the inhomogeneous case). We demonstrate this by solving the homogeneous and inhomogeneous Bethe-Salpeter equations and find, e.g. that for the calculation of the mass spectrum it is as efficient or even advantageous to use the inhomogeneous equation as compared to the homogeneous. This is valuable insight, in particular for the study of baryons in a three-quark setup and more involved systems.
Search for a bound state of kaon and pion
Kishimoto, T; Hayakawa, T; Ajimura, S; Itabashi, T; Matsuoka, K; Minami, S; Mitoma, Y; Sakaguchi, A; Shimizu, Y; Terai, K; Sato, T; Noumi, H; Sekimoto, M; Takahashi, H; Fukuda, T; Imoto, W; Mizoi, Y
2012-01-01
We have searched for a bound state of kaon and pion denoted by $X$. The $X$ was conjectured to explain the so-called $\\Theta^+$ resonance as a bound state of kaon, pion and nucleon. This model explains almost all properties of the $\\Theta^+$, however, the model works only if the $K \\pi$ interaction is strongly attractive. It is so strong that it could make a bound state $X$. Here we report a result of the search for the $X$ by using the $K^+ + N \\rightarrow X^+ + N$ reaction at P$_K\\sim$ 1.2 GeV/c. The $X^+ \\rightarrow K^+ \\gamma \\gamma$ decay produces $K^+$ in momentum region where other processes cannot fill. We observed signature of the $X^+$ with statistical significance of 2 $\\sigma$. Production cross section of $X$ with respect to that of $\\pi^0$ is 1$\\pm$0.5% if we take it as an evidence and 1.5% if we set an upper limit.
Effects of QCD bound states on dark matter relic abundance
Liew, Seng Pei
2016-01-01
We study scenarios where there exists an exotic massive particle charged under QCD in the early Universe. We calculate the formation and dissociation rates of bound states formed by pairs of these particles, and apply the results in dark matter (DM) coannihilation scenarios, including also the Sommerfeld effect. We find that on top of the Sommerfeld enhancement, bound-state effects can further significantly increase the largest possible DM masses which can give the observed DM relic abundance, by $\\sim 30 - 100\\%$ with respect to values obtained by considering the Sommerfeld effect only, for the color triplet or octet exotic particles we consider. In particular, it indicates that the Bino DM mass in the right-handed stop-Bino coannihilation scenario in the Minimal Supersymmetric extension of the Standard Model (MSSM) can reach $\\sim 2.5$ TeV. We also apply the bound-state effects in the calculations of relic abundance of long-lived or metastable massive colored particles, and discuss the implications on the B...
Bounds for State Degeneracies in 2D Conformal Field Theory
Hellerman, Simeon
2010-01-01
In this note we explore the application of modular invariance in 2-dimensional CFT to derive universal bounds for quantities describing certain state degeneracies, such as the thermodynamic entropy, or the number of marginal operators. We show that the entropy at inverse temperature 2 pi satisfies a universal lower bound, and we enumerate the principal obstacles to deriving upper bounds on entropies or quantum mechanical degeneracies for fully general CFTs. We then restrict our attention to infrared stable CFT with moderately low central charge, in addition to the usual assumptions of modular invariance, unitarity and discrete operator spectrum. For CFT in the range c_left + c_right < 48 with no relevant operators, we are able to prove an upper bound on the thermodynamic entropy at inverse temperature 2 pi. Under the same conditions we also prove that a CFT can have a number of marginal deformations no greater than ((c_left + c_right) / (48 - c_left - c_right)) e^(4 Pi) - 2.
Three-photon excitation of hydrogen Rydberg states.
Glab, W L; Nayfeh, M H
1983-01-01
A three-photon process using radiation at 2430 and 3660 A and with a 1s-2s two-photon resonance is used to excite atomic hydrogen from the ground state to Rydberg states of high principal quantum number. Collision-induced ionization is used to monitor the excitation.
Three-photon excitation of hydrogen Rydberg states
Energy Technology Data Exchange (ETDEWEB)
Glab, W.L.; Nayfeh, M.H.
1983-01-01
A three-photon process using radiation at 2430 and 3660 A and with a 1s-2s two-photon resonance is used to excite atomic hydrogen from the ground state to Rydberg states of high principal quantum number. Collision-induced ionization is used to monitor the excitation.
DILEPTON YIELD FROM THE DECAY OF EXCITED SI-28 STATES
BACELAR, JC; BUDA, A; BALANDA, A; KRASZNAHORKAY, A; VANDERPLOEG, H; SUJKOWSKI, Z; VANDERWOUDE, A
1994-01-01
The first dilepton yield measurements from excited nuclear states obtained with a new Positron-Electron Pair Spectroscopic Instrument (PEPSI) are reported. Nuclear states in Si-28, with an initial excitation energy E* = 50 MeV, were populated via the isospin T = 0 reaction He-4 + Mg-24 and the mixed
Exact ensemble density-functional theory for excited states
Yang, Zeng-hui; Pribram-Jones, Aurora; Burke, Kieron; Needs, Richard J; Ullrich, Carsten A
2014-01-01
We construct exact Kohn-Sham potentials for the ensemble density-functional theory (EDFT) of excited states from the ground and excited states of helium. The exchange-correlation potential is compared with current approximations, which miss prominent features. The ensemble derivative discontinuity is tested, and the virial theorem is proven and illustrated.
Experimental Investigation of Excited-State Lifetimes in Atomic Ytterbium
Energy Technology Data Exchange (ETDEWEB)
Bowers, C.J.; Budker, D.; Commins, E.D.; DeMille, D.; Freedman, S.J.; Nguyen, A.-T.; Shang, S.-Q.; /UC, Berkeley; Zolotorev, M.; /SLAC
2011-11-15
Lifetimes of 21 excited states in atomic Yb were measured using time-resolved fluorescence detection following pulsed laser excitation. The lifetime of the 4f{sup 14}5d6s {sup 3}D{sub 1} state, which is of particular importance for a proposed study of parity nonconservation in atoms, was measured to be 380(30) ns.
Role of Excited States In High-order Harmonic Generation
Beaulieu, S.; Camp, S.; Descamps, D.; Comby, A.; Wanie, V.; Petit, S.; Légaré, F.; Schafer, K. J.; Gaarde, M. B.; Catoire, F.; Mairesse, Y.
2016-11-01
We investigate the role of excited states in high-order harmonic generation by studying the spectral, spatial, and temporal characteristics of the radiation produced near the ionization threshold of argon by few-cycle laser pulses. We show that the population of excited states can lead either to direct extreme ultraviolet emission through free induction decay or to the generation of high-order harmonics through ionization from these states and recombination to the ground state. By using the attosecond lighthouse technique, we demonstrate that the high-harmonic emission from excited states is temporally delayed by a few femtoseconds compared to the usual harmonics, leading to a strong nonadiabatic spectral redshift.
Computational approach for calculating bound states in quantum field theory
Lv, Q. Z.; Norris, S.; Brennan, R.; Stefanovich, E.; Su, Q.; Grobe, R.
2016-09-01
We propose a nonperturbative approach to calculate bound-state energies and wave functions for quantum field theoretical models. It is based on the direct diagonalization of the corresponding quantum field theoretical Hamiltonian in an effectively discretized and truncated Hilbert space. We illustrate this approach for a Yukawa-like interaction between fermions and bosons in one spatial dimension and show where it agrees with the traditional method based on the potential picture and where it deviates due to recoil and radiative corrections. This method permits us also to obtain some insight into the spatial characteristics of the distribution of the fermions in the ground state, such as the bremsstrahlung-induced widening.
Nonadiabatic excited-state molecular dynamics: On-the-fly limiting of essential excited states
Nelson, Tammie; Naumov, Artem; Fernandez-Alberti, Sebastian; Tretiak, Sergei
2016-12-01
The simulation of nonadiabatic dynamics in extended molecular systems involving hundreds of atoms and large densities of states is particularly challenging. Nonadiabatic coupling terms (NACTs) represent a significant numerical bottleneck in surface hopping approaches. Rather than using unreliable NACT cutting schemes, here we develop "on-the-fly" state limiting methods to eliminate states that are no longer essential for the non-radiative relaxation dynamics as a trajectory proceeds. We propose a state number criteria and an energy-based state limit. The latter is more physically relevant by requiring a user-imposed energy threshold. For this purpose, we introduce a local kinetic energy gauge by summing contributions from atoms within the spatial localization of the electronic wavefunction to define the energy available for upward hops. The proposed state limiting schemes are implemented within the nonadiabatic excited-state molecular dynamics framework to simulate photoinduced relaxation in poly-phenylene vinylene (PPV) and branched poly-phenylene ethynylene (PPE) oligomers for benchmark evaluation.
Ultrafast excited state relaxation in long-chain polyenes
Energy Technology Data Exchange (ETDEWEB)
Antognazza, Maria Rosa, E-mail: mariarosa.antognazza@polimi.it [Center for Nano Science and Technology of IIT-PoliMI, via Pascoli 70/3, 20133 Milano (Italy); Lueer, Larry [National Laboratory for Ultrafast and Ultraintense Optical Science, CNR-INFM, Dipartimento di Fisica, Politecnico di Milano, P.za L. da Vinci 32, 20133 Milano (Italy); Madrid Institute of Advanced Studies, IMDEA Nanociencia, Faculdad de Ciencias, Av. Tomas y Valiente 7, 28049 Madrid (Spain); Polli, Dario [National Laboratory for Ultrafast and Ultraintense Optical Science, CNR-INFM, Dipartimento di Fisica, Politecnico di Milano, P.za L. da Vinci 32, 20133 Milano (Italy); Christensen, Ronald L. [Department of Chemistry, Bowdoin College, Brunswick, ME 04011 (United States); Schrock, Richard R. [Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA 02139 (United States); Lanzani, Guglielmo [Center for Nano Science and Technology of IIT-PoliMI, via Pascoli 70/3, 20133 Milano (Italy); National Laboratory for Ultrafast and Ultraintense Optical Science, CNR-INFM, Dipartimento di Fisica, Politecnico di Milano, P.za L. da Vinci 32, 20133 Milano (Italy); Cerullo, Giulio [National Laboratory for Ultrafast and Ultraintense Optical Science, CNR-INFM, Dipartimento di Fisica, Politecnico di Milano, P.za L. da Vinci 32, 20133 Milano (Italy)
2010-07-19
Graphical abstract: Excited state dynamics of a long-chain polyene studied by femtosecond pump-probe spectroscopy. - Abstract: We present a comprehensive study, by femtosecond pump-probe spectroscopy, of excited state dynamics in a polyene that approaches the infinite chain limit. By excitation with sub-10-fs pulses resonant with the 0-0 S{sub 0} {yields} S{sub 2} transition, we observe rapid loss of stimulated emission from the bright excited state S{sub 2}, followed by population of the hot S{sub 1} state within 150 fs. Vibrational cooling of S{sub 1} takes place within 500 fs and is followed by decay back to S{sub 0} with 1 ps time constant. By excitation with excess vibrational energy we also observe the ultrafast formation of a long-living absorption, that is assigned to the triplet state generated by singlet fission.
Search for the eta-mesic Helium bound state with the WASA-at-COSY facility
Skurzok, M; Rundel, O; Moskal, P
2015-01-01
We performed a search for 4He-eta bound state with high statistics and high acceptance with the WASA-at-COSY facility using a ramped beam technique. The signature of eta-mesic nuclei is searched for in dd -> 3Henpi0 and dd -> 3Heppi- reactions by the measurement of the excitation functions in the vicinity of the {\\eta} production threshold. This paper presents the experimental method and the preliminary results of the data analysis for dd -> 3Henpi0 process.
Primary optical excitations and excited-state interaction energies in sexithiophene
Loi, MA; Martin, C; Chandrasekhar, HR; Chandrasekhar, M; Graupner, W; Garnier, F; Mura, A; Bongiovanni, G
2002-01-01
Based on a unique combination of angle-resolved transmission spectroscopy and transmission data at high pressure, we identify the primary photoexcitations and the relevant excited-state interaction energies in a sexithiophene crystal. Optical excitations include charge-transfer excitons and Davydov
Inelastic scattering of {sup 9}Li and excitation mechanism of its first excited state
Energy Technology Data Exchange (ETDEWEB)
Al Falou, H. [Astronomy and Physics Department, Saint Mary' s University, Halifax, Nova Scotia B3H 3C3 (Canada); TRIUMF, Vancouver, British Columbia V6T 2A3 (Canada); Kanungo, R., E-mail: ritu@triumf.ca [Astronomy and Physics Department, Saint Mary' s University, Halifax, Nova Scotia B3H 3C3 (Canada); Andreoiu, C.; Cross, D.S. [Department of Chemistry, Simon Fraser University, Burnaby, British Columbia V5A 1S6 (Canada); Davids, B.; Djongolov, M. [TRIUMF, Vancouver, British Columbia V6T 2A3 (Canada); Gallant, A.T. [TRIUMF, Vancouver, British Columbia V6T 2A3 (Canada); Department of Physics, University of British Columbia, British Columbia V6T 1Z4 (Canada); Galinski, N.; Howell, D. [TRIUMF, Vancouver, British Columbia V6T 2A3 (Canada); Department of Physics, Simon Fraser University, Burnaby, British Columbia V5A 1S6 (Canada); Kshetri, R.; Niamir, D. [TRIUMF, Vancouver, British Columbia V6T 2A3 (Canada); Orce, J.N. [TRIUMF, Vancouver, British Columbia V6T 2A3 (Canada); Department of Physics, University of the Western Cape, P/B X17, Bellville, ZA-7535 (South Africa); Shotter, A.C. [Department of Physics and Astronomy, University of Edinburgh, Edinburgh (United Kingdom); Sjue, S. [TRIUMF, Vancouver, British Columbia V6T 2A3 (Canada); Tanihata, I. [Research Center for Nuclear Physics, Osaka University, Mihogaoka, Ibaraki, Osaka 567 0047 (Japan); Thompson, I.J. [Lawrence Livermore National Laboratory, Livermore, CA 94551 (United States); Triambak, S. [TRIUMF, Vancouver, British Columbia V6T 2A3 (Canada); Uchida, M. [Astronomy and Physics Department, Saint Mary' s University, Halifax, Nova Scotia B3H 3C3 (Canada); Walden, P. [TRIUMF, Vancouver, British Columbia V6T 2A3 (Canada); Wiringa, R.B. [Physics Division, Argonne National Laboratory, Argonne, IL 60439 (United States)
2013-04-25
The first measurement of inelastic scattering of {sup 9}Li from deuterons at the ISAC facility is reported. The measured angular distribution for the first excited state confirms the nature of excitation to be an E2 transition. The quadrupole deformation parameter is extracted from an analysis of the angular distribution.
Photo-production of Bound States with Hidden Charms
Wu, Jia-Jun
2012-01-01
The photo-production of $J/\\Psi$-$^3He$ bound state ($[^3He]_{J/\\Psi}$) on a $^4He$ target has been investigated using the impulse approximation. The calculations have been performed using several $\\gamma+N \\rightarrow J/\\Psi +N$ models based on the Pomeron-exchange and accounting for the pion-exchange mechanism at low energies. The $J/\\Psi$ wavefunctions in $[^3He]_{J/\\Psi}$ are generated from various $J/\\Psi$-nucleus potentials which are constructed by either using a procedure based on the Pomeron-quark coupling mechanism or folding a $J/\\Psi$-N potential ($v_{J/\\Psi,N}$) into the nuclear densities. We consider $v_{J/\\Psi,N}$ derived from the effective field theory approach, Lattice QCD, and Pomeron-quark coupling mechanism. The upper bound of the predicted total cross sections is about $0.1 - 0.3$ pico-barn. We also consider the possibility of photo-production of a six quark-$J/\\Psi$ bound state ($[q^6]_{J/\\Psi})$ on the $^3He$ target. The Compound Bag Model of $NN$ scattering and the quark cluster model o...
Charge-displacement analysis for excited states
Energy Technology Data Exchange (ETDEWEB)
Ronca, Enrico, E-mail: enrico@thch.unipg.it; Tarantelli, Francesco, E-mail: francesco.tarantelli@unipg.it [Istituto CNR di Scienze e Tecnologie Molecolari, via Elce di Sotto 8, I-06123 Perugia (Italy); Dipartimento di Chimica, Biologia e Biotecnologie, Università degli Studi di Perugia, via Elce di Sotto 8, I-06123 Perugia (Italy); Pastore, Mariachiara, E-mail: chiara@thch.unipg.it; Belpassi, Leonardo; De Angelis, Filippo [Istituto CNR di Scienze e Tecnologie Molecolari, via Elce di Sotto 8, I-06123 Perugia (Italy); Angeli, Celestino; Cimiraglia, Renzo [Dipartimento di Scienze Chimiche e Farmaceutiche, Università degli Studi di Ferrara, via Borsari 46, I-44100 Ferrara (Italy)
2014-02-07
We extend the Charge-Displacement (CD) analysis, already successfully employed to describe the nature of intermolecular interactions [L. Belpassi et al., J. Am. Chem. Soc. 132, 13046 (2010)] and various types of controversial chemical bonds [L. Belpassi et al., J. Am. Chem. Soc. 130, 1048 (2008); N. Salvi et al., Chem. Eur. J. 16, 7231 (2010)], to study the charge fluxes accompanying electron excitations, and in particular the all-important charge-transfer (CT) phenomena. We demonstrate the usefulness of the new approach through applications to exemplary excitations in a series of molecules, encompassing various typical situations from valence, to Rydberg, to CT excitations. The CD functions defined along various spatial directions provide a detailed and insightful quantitative picture of the electron displacements taking place.
Energy Technology Data Exchange (ETDEWEB)
Goble, J.H. Jr.
1982-05-01
Three variations on the Dunham series expansion function of the potential of a diatomic molecule are compared. The differences among these expansions lie in the choice of the expansion variable, lambda. The functional form of these variables are lambda/sub s/ = l-r/sub e//r for the Simon-Parr-Finlan version, lambda/sub T/ - 1-(r/sub e//r)/sup p/ for that of Thakkar, and lambda/sub H/ = 1-exp(-rho(r/r/sub e/-1) for that of Huffaker. A wide selection of molecular systems are examined. It is found that, for potentials in excess of thirty kcal/mole, the Huffaker expansion provides the best description of the three, extrapolating at large internuclear separation to a value within 10% of the true dissociation energy. For potentials that result from the interaction of excited states, all series expansions show poor behavior away from the equilibrium internuclear separation of the molecule. The series representation of the potentials of weakly bound molecules are examined in more detail. The ground states of BeAr/sup +/, HeNe/sup +/, NaAr, and Ar/sub 2/ and the excited states of HeNe+, NaNe, and NaAr are best described by the Thakkar expansion. Finally, the observation of laser-assisted excitive Penning ionization in a flowing afterglow is reported. The reaction Ar(/sup 3/P/sub 2/) + Ca + h nu ..-->.. Ar + Ca/sup +/(5p /sup 2/P/sub J/) + e/sup -/ occurs when the photon energy, h nu, is approximately equal to the energy difference between the metastable argon and one of the fine structure levels of the ion's doublet. By monitoring the cascade fluorescence of the above reaction and comparing it to the flourescence from the field-free process Ar(/sup 3/P/sub 2/) + Ca ..-->.. Ar + Ca/sup +/(4p /sup 2/P/sub J/) + e/sup -/ a surprisingly large cross section of 6.7 x 10/sup 3/ A/sup 2/ is estimated.
K- and p¯ deeply bound atomic states
Friedman, E.; Gal, A.
1999-12-01
The strongly absorptive optical potentials Vopt which have been deduced from the strong-interaction level shifts and widths in X-ray spectra of K- and p¯ atoms produce effective repulsion leading to substantial suppression of the atomic wave functions within the nucleus. The width of atomic levels then saturates as function of the strength of Im Vopt. We find that `deeply bound' atomic states, which are inaccessible in the atomic cascade process, are generally narrow, due to this mechanism, over the entire periodic table and should be reasonably well resolved. These predictions are insensitive to Vopt, provided it was fitted to the observed X-ray spectra. In contrast, the nuclear states bound by Vopt are very broad and their spectrum depends sensitively on details of Vopt. We discuss production reactions for K- atomic states using slow K- mesons from the decay of the φ(1020) vector meson, and the ( p¯,p ) reaction for p¯ atomic states. Rough cross section estimates are given.
Origin of ultrafast excited state dynamics of 1-nitropyrene.
Murudkar, Sushant; Mora, Aruna K; Singh, Prabhat K; Nath, Sukhendu
2011-10-01
Time-resolved emission measurements in subpicosecond time domain have been carried out for 1-nitropyrene in different solvents to understand the mechanism for the observed ultrafast decay of its first excited singlet state. Excited-state dynamics of 1-nitropyrene is found to be independent of the solvent viscosity. This result contradicts the proposition in the literature (J. Phys. Chem. A 2007, 111, 552) that the ultrafast decay in 1-nitropyrene is due to the large amplitude torsional motion of the nitro group around the pyrene moiety. Excited-state dynamics of 1-nitropyrene in solvents with different dielectric constants shows that excited-state lifetime suddenly increases after a certain value of the dielectric constant. Detailed quantum chemical calculations have been carried out to understand the process that is responsible for the observed effect of the dielectric constant on the excited-state dynamics of 1-nitropyrene. It is seen that the excited-state lifetime and the singlet-triplet energy gap follow similar variation with the dielectric constant of the medium. Such a correlation between the excited-state lifetime and the singlet-triplet energy gap supports the fact that the observed ultrafast decay for 1-nitropyrene is due to an efficient intersystem crossing rather than to the torsional motion of the nitro group as proposed in the literature.
Photoionization of excited states of neon-like Mg III
Indian Academy of Sciences (India)
Narendra Singh; Man Mohan
2002-04-01
The close coupling -matrix method is used to calculate cross-sections for photoionization of Mg III from its ﬁrst three excited states. Conﬁguration interaction wave functions are used to represent two target states of Mg III retained in the -matrix expansion. The positions and effective quantum numbers for the Rydberg series converging to the excited state 2226 \\ 2 of the residual ion, are predicted.
A Simple Hubbard Model for the Excited States of Dibenzoterrylene
Sadeq, Z S
2016-01-01
We use a simple Hubbard model to characterize the electronic excited states of the dibenzoterrylene (DBT) molecule; we compute the excited state transition energies and oscillator strengths from the ground state to several singlet excited states. We consider the lowest singlet and triplet states of the molecule, examine their wavefunctions, and compute the density correlation functions that describe these states. We find that the DBT ground state is mostly a closed shell singlet with very slight radical character. We predict a relatively small singlet-triplet splitting of 0.75 eV, which is less than the mid-sized -acenes but larger than literature predictions for this state; this is because the Hubbard interaction makes a very small correction to the singlet and triplet states.
Static and dynamic properties of QCD bound states
Energy Technology Data Exchange (ETDEWEB)
Kubrak, Stanislav
2015-07-01
The QCD phenomenology can be faced with the framework of the coupled quark DSE, meson BSE and baryon Faddeev equation, providing non-perturbative, continuum and Poincare invariant scientific approach. The research performed throughout this thesis is twofold. From one perspective we focus on the investigation of mass spectra for mesons with total spin quantum number J=3 and arising Regge-trajectory for natural parity states J{sup PC}=1{sup --},2{sup ++},3{sup --} within rainbow-ladder single gluon exchange model. The other findings are concerning the impact of the pion cloud effect on J>2 meson states, baryon masses, namely on Nucleon and Delta three-body bound states and meson dynamical properties like the pion form factor.
Exotic Hadron Bound State Production at Hadronic Colliders
Jin, Yi; Liu, Yan-Rui; Meng, Lu; Si, Zon-Guo; Zhang, Xiao-Feng
2016-01-01
The non-relativistic wave function framework is applied to study the production and decay of the exotic hadrons which can be effectively described as bound states of other hadrons. The ingredient hadron production can be calculated by event generators. We investigate the production of exotic hadrons in the multiproduction processes at high energy hadronic colliders with the help of the event generators. We illustrate the crucial information such as their momentum distributions and production rate for the measurements at the large hadron collider. This study provides crucial information for the measurements of the relevant exotic hadrons.
Scattering and Bound States of a Deformed Quantum Mechanics
Ching, Chee-Leong
2012-01-01
We construct the exact position representation of a deformed quantum mechanics which exhibits an intrinsic maximum momentum and use it to study problems such as a particle in a box and scattering from a step potential, among others. In particular, we show that unlike usual quantum mechanics, the present deformed case delays the formation of bound states in a finite potential well. In the process we also highlight some limitations and pit-falls of low-momentum or perturbative treatments and thus resolve two puzzles occurring in the literature.
Diquark bound states at far beyond ladder truncation
Jinno, Ryusuke; Mishima, Go
2015-01-01
The Bethe-Salpeter equation in the diquark channel is investigated by employing the Dyson-Schwinger method together with the Munczek-Nemirovsky model. The novelty of our study is a resummation of completely-crossed ladder diagrams in the Bethe-Salpeter kernel. These diagrams are enhanced due to their color factors in the diquark channel, but not in the meson channel. As a result of our analysis, it is suggested that diquark bound-state solutions exist in the Bethe-Salpeter equation, which have been thought to be absent.
Are $\\eta$- and $\\omega$-nuclear states bound ?
Tsushima, K; Thomas, A W; Saitô, K
1998-01-01
We investigate theoretically whether it is feasible to detect $\\eta$- and $^{40}$Ca, $^{90}$Zr and $^{208}$Pb, we also investigate $^6$He, $^{11}$B and $^{26}$Mg, which are the final nuclei in the proposed experiment involving the (d,$^3$He) reaction at GSI. Potentials for the $\\eta$ and $\\omega$ mesons in these nuclei are calculated in local density approximation, embedding the mesons in the nucleus described by solving the mean-field equations of motion in the QMC model. Our results suggest that one should expect to find $\\eta$- and $\\omega$-nucleus bound states in all these nuclei.
R-Matrix Calculations for Few-Quark Bound States
Shalchi, M A
2016-01-01
The R-matrix method is implemented to study the heavy charm and bottom diquark, triquark, tetraquark and pentaquarks in configuration space, as the bound states of quark-antiquark, diquark-quark, diquark-antidiquark and diquark-antitriquark systems, respectively. The mass spectrum and the size of these systems are calculated for different partial wave channels. The calculated masses are compared with recent theoretical results obtained by %the solution of Lippmann-Schwinger equation other methods in momentum and configuration spaces and also by available experimental data.
Quarkonium-nucleus bound states from lattice QCD
Energy Technology Data Exchange (ETDEWEB)
Beane, S. R. [Univ. of Washington, Seattle, WA (United States); Chang, E. [Univ. of Washington, Seattle, WA (United States); Cohen, S. D. [Univ. of Washington, Seattle, WA (United States); Detmold, W. [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Lin, H. -W. [Univ. of Washington, Seattle, WA (United States); Orginos, K. [College of William and Mary, Williamsburg, VA (United States); Thomas Jefferson National Accelerator Facility (TJNAF), Newport News, VA (United States); Parreño, A. [Univ., de Barcelona, Marti Franques (Spain); Savage, M. J. [Univ. of Washington, Seattle, WA (United States)
2015-06-11
Quarkonium-nucleus systems are composed of two interacting hadronic states without common valence quarks, which interact primarily through multi-gluon exchanges, realizing a color van der Waals force. We present lattice QCD calculations of the interactions of strange and charm quarkonia with light nuclei. Both the strangeonium-nucleus and charmonium-nucleus systems are found to be relatively deeply bound when the masses of the three light quarks are set equal to that of the physical strange quark. Extrapolation of these results to the physical light-quark masses suggests that the binding energy of charmonium to nuclear matter is B < 40 MeV.
Stieltjes electrostatic model interpretation for bound state problems
Indian Academy of Sciences (India)
K V S Shiv Chaitanya
2014-07-01
In this paper, it is shown that Stieltjes electrostatic model and quantum Hamilton Jacobi formalism are analogous to each other. This analogy allows the bound state problem to mimic as unit moving imaginary charges $i\\hbar$, which are placed in between the two fixed imaginary charges arising due to the classical turning points of the potential. The interaction potential between unit moving imaginary charges $i\\hbar$ is given by the logarithm of the wave function. For an exactly solvable potential, this system attains stable equilibrium position at the zeros of the orthogonal polynomials depending upon the interval of the classical turning points.
Study of excited nucleon states at EBAC: status and plans
Energy Technology Data Exchange (ETDEWEB)
Hiroyuki Kamano
2009-12-01
We present an overview of a research program for the excited nucleon states in Excited Baryon Analysis Center (EBAC) at Jefferson Lab. Current status of our analysis of the meson production reactions based on the unitary dynamical coupled-channels model is summarized, and the N* pole positions extracted from the constructed scattering amplitudes are presented. Our plans for future developments are also discussed.
Fingerprints of Majorana Bound States in Aharonov-Bohm Geometry
Tripathi, Krashna Mohan; Das, Sourin; Rao, Sumathi
2016-04-01
We study a ring geometry, coupled to two normal metallic leads, which has a Majorana bound state (MBS) embedded in one of its arms and is threaded by Aharonov-Bohm (A B ) flux ϕ . We show that by varying the A B flux, the two leads go through resonance in an anticorrelated fashion while the resonance conductance is quantized to 2 e2/h . We further show that such anticorrelation is completely absent when the MBS is replaced by an Andreev bound state (ABS). Hence this anti-correlation in conductance when studied as a function of ϕ provides a unique signature of the MBS which cannot be faked by an ABS. We contrast the phase sensitivity of the MBS and ABS in terms of tunneling conductances. We argue that the relative phase between the tunneling amplitude of the electrons and holes from either lead to the level (MBS or ABS), which is constrained to 0 ,π for the MBS and unconstrained for the ABS, is responsible for this interesting contrast in the A B effect between the MBS and ABS.
Vibronic coupling in the excited-states of carotenoids.
Miki, Takeshi; Buckup, Tiago; Krause, Marie S; Southall, June; Cogdell, Richard J; Motzkus, Marcus
2016-04-28
The ultrafast femtochemistry of carotenoids is governed by the interaction between electronic excited states, which has been explained by the relaxation dynamics within a few hundred femtoseconds from the lowest optically allowed excited state S2 to the optically dark state S1. Extending this picture, some additional dark states (3A(g)(-) and 1B(u)(-)) and their interaction with the S2 state have also been suggested to play a major role in the ultrafast deactivation of carotenoids and their properties. Here, we investigate the interaction between such dark and bright electronic excited states of open chain carotenoids, particularly its dependence on the number of conjugated double bonds (N). We focus on the ultrafast wave packet motion on the excited potential surface, which is modified by the interaction between bright and dark electronic states. Such a coupling between electronic states leads to a shift of the vibrational frequency during the excited-state evolution. In this regard, pump-degenerate four-wave mixing (pump-DFWM) is applied to a series of carotenoids with different numbers of conjugated double bonds N = 9, 10, 11 and 13 (neurosporene, spheroidene, lycopene and spirilloxanthin, respectively). Moreover, we demonstrate in a closed-chain carotenoid (lutein) that the coupling strength and therefore the vibrational shift can be tailored by changing the energy degeneracy between the 1B(u)(+) and 1B(u)(-) states via solvent interaction.
Three-nucleon bound states using realistic potential models
Nogga, A.; Kievsky, A.; Kamada, H.; Glöckle, W.; Marcucci, L. E.; Rosati, S.; Viviani, M.
2003-03-01
The bound states of 3H and 3He have been calculated by using the Argonne v18 plus the Urbana IX three-nucleon potential. The isospin T=3/2 state have been included in the calculations as well as the n-p mass difference. The 3H-3He mass difference has been evaluated through the charge-dependent terms explicitly included in the two-body potential. The calculations have been performed using two different methods: the solution of the Faddeev equations in momentum space and the expansion on the correlated hyperspherical harmonic basis. The results are in agreement within 0.1% and can be used as benchmark tests. Results for the charge-dependent Bonn interaction in conjunction with the Tucson-Melbourne three-nucleon force are also presented. It is shown that the 3H and 3He binding energy difference can be predicted model independently.
The three-nucleon bound state using realistic potential models
Nogga, A; Kamada, H; Glöckle, W; Marcucci, L E; Rosati, S; Viviani, M
2003-01-01
The bound states of $^3$H and $^3$He have been calculated using the Argonne $v_{18}$ plus the Urbana three-nucleon potential. The isospin $T=3/2$ state have been included in the calculations as well as the $n$-$p$ mass difference. The $^3$H-$^3$He mass difference has been evaluated through the charge dependent terms explicitly included in the two-body potential. The calculations have been performed using two different methods: the solution of the Faddeev equations in momentum space and the expansion on the correlated hyperspherical harmonic basis. The results are in agreement within 0.1% and can be used as benchmark tests. Results for the CD-Bonn interaction are also presented. It is shown that the $^3$H and $^3$He binding energy difference can be predicted model independently.
Lower Bound for entanglement cost of antisymmetric states
Shimono, T
2002-01-01
This report gives a lower bound of entanglement cost for antisymmetric states of bipartite d-level systems to be log_2 (d/(d-1)) ebit (for d=3, E_c >= 0.585...). The paper quant-ph/0112131 claims that the value is equal to one ebit for d=3, since all of the eigenvalues of reduced matrix of any pure states living in N times tensor product of antisymmetric space is not greater than 2^(-N) thus the von Neumann entropy is not less than N, but the proof is not true. Hence whether the value is equal to or less than one ebit is not clear at this moment.
Bound states for non-symmetric evolution Schroedinger potentials
Energy Technology Data Exchange (ETDEWEB)
Corona, Gulmaro Corona [Area de Analisis Matematico y sus Aplicaciones, Universidad Autonoma Metropolitana-Azcapotalco, Atzcapotzalco, DF (Mexico)). E-mail: ccg@correo.azc.uam.mx
2001-09-14
We consider the spectral problem associated with the evolution Schroedinger equation, (D{sup 2}+ k{sup 2}){phi}=u{phi}, where u is a matrix-square-valued function, with entries in the Schwartz class defined on the real line. The solution {phi}, called the wavefunction, consists of a function of one real variable, matrix-square-valued with entries in the Schwartz class. This problem has been dealt for symmetric potentials u. We found for the present case that the bound states are localized similarly to the scalar and symmetric cases, but by the zeroes of an analytic matrix-valued function. If we add an extra condition to the potential u, we can determine these states by an analytic scalar function. We do this by generalizing the scalar and symmetric cases but without using the fact that the Wronskian of a pair of wavefunction is constant. (author)
Ultrafast excited state relaxation in long-chain polyenes
Antognazza, Maria Rosa; Lüer, Larry; Polli, Dario; Christensen, Ronald L.; Schrock, Richard R.; Lanzani, Guglielmo; Cerullo, Giulio
2010-07-01
We present a comprehensive study, by femtosecond pump-probe spectroscopy, of excited state dynamics in a polyene that approaches the infinite chain limit. By excitation with sub-10-fs pulses resonant with the 0-0 S 0 → S 2 transition, we observe rapid loss of stimulated emission from the bright excited state S 2, followed by population of the hot S 1 state within 150 fs. Vibrational cooling of S 1 takes place within 500 fs and is followed by decay back to S 0 with 1 ps time constant. By excitation with excess vibrational energy we also observe the ultrafast formation of a long-living absorption, that is assigned to the triplet state generated by singlet fission.
The examination of berberine excited state by laser flash photolysis
Cheng, Lingli; Wang, Mei; Zhao, Ping; Zhu, Hui; Zhu, Rongrong; Sun, Xiaoyu; Yao, Side; Wang, Shilong
2009-07-01
The property of the excited triplet state of berberine (BBR) was investigated by using time-resolved laser flash photolysis of 355 nm in acetonitrile. The transient absorption spectra of the excited triplet BBR were obtained in acetonitrile, which have an absorption maximum at 420 nm. And the ratio of excitation to ionization of BBR in acetonitrile solvent was calculated. The self-decay and self-quenching rate constants, and the absorption coefficient of 3BBR* were investigated and the excited state quantum yield was determined. Furthermore utilizing the benzophenone (BEN) as a triplet sensitizer, and the β-carotene (Car) as an excited energy transfer acceptor, the assignment of 3BBR* was further confirmed and the related energy transfer rate constants were also determined.
Energy Technology Data Exchange (ETDEWEB)
Copan, Andreas V.; Wiens, Avery E.; Nowara, Ewa M.; Schaefer, Henry F.; Agarwal, Jay, E-mail: jagarwal@uga.edu [Center for Computational Quantum Chemistry, University of Georgia, Athens, Georgia 30602 (United States)
2015-02-07
Peroxyacetyl radical [CH{sub 3}C(O)O{sub 2}] is among the most abundant peroxy radicals in the atmosphere and is involved in OH-radical recycling along with peroxyacetyl nitrate formation. Herein, the ground (X{sup ~}) and first (A{sup ~}) excited state surfaces of cis and trans peroxyacetyl radical are characterized using high-level ab initio methods. Geometries, anharmonic vibrational frequencies, and adiabatic excitation energies extrapolated to the complete basis-set limit are reported from computations with coupled-cluster theory. Excitation of the trans conformer is found to induce a symmetry-breaking conformational change due to second-order Jahn-Teller interactions with higher-lying excited states. Additional benchmark computations are provided to aid future theoretical work on peroxy radicals.
Quantum state discrimination bounds for finite sample size
Audenaert, Koenraad M R; Verstraete, Frank
2012-01-01
In the problem of quantum state discrimination, one has to determine by measurements the state of a quantum system, based on the a priori side information that the true state is one of two given and completely known states, rho or sigma. In general, it is not possible to decide the identity of the true state with certainty, and the optimal measurement strategy depends on whether the two possible errors (mistaking rho for sigma, or the other way around) are treated as of equal importance or not. Recent results on the quantum Chernoff and Hoeffding bounds show that, if several copies of the system are available then the optimal error probabilities decay exponentially in the number of copies, and the decay rate is given by a certain statistical distance between rho and sigma (the Chernoff distance and the Hoeffding distances, respectively). While these results provide a complete solution for the asymptotic problem, they are not completely satisfying from a practical point of view. Indeed, in realistic scenarios ...
Investigation into chromophore excited-state coupling in allophycocyanin
Zheng, Xiguang; Zhao, Fuli; Wang, He Z.; Gao, Zhaolan; Yu, Zhenxin; Zhu, Jinchang; Xia, Andong; Jiang, Lijin
1994-08-01
Both theoretical and experimental studies are presented on chromophore excited-state coupling in linker-free allophycocyanin (APC), one of the antenna phycobiliproteins in algal photosynthesis. A three-site-coupling model has been introduced to describe the exciton interaction mechanism amoung the excited (beta) chromophore in APC, and the exciton energy splitting is estimated. Picosecond polarized fluorescence experiments both on monomeric and trimeric APC isolated from alga Spirulina platensis have been performed. The experimental results show that APC monomer and trimer exhibit remarkedly different spectropic characteristics, and satisfy the suggestion of strong excited- state coupling among chromophores in APC.
Bethe-Salpeter bound-state structure in Minkowski space
Gutierrez, C; Frederico, T; Salmè, G; Viviani, M; Tomio, Lauro
2016-01-01
The quantitative investigation of the scalar Bethe-Salpeter equation in Minkowski space, within the ladder-approximation framework, is extended to include the excited states. This study has been carried out for an interacting system composed by two massive bosons exchanging a massive scalar, by adopting (i) the Nakanishi integral representation of the Bethe-Salpeter amplitude, and (ii) the formally exact projection onto the null plane. Our analysis, on one hand, confirms the reliability of the method already applied to the ground state and, on the other one, extends the investigation from the valence distribution in momentum space to the corresponding quantity in the impact-parameter space, pointing out some relevant features, like (i) the equivalence between Minkowski and Euclidean transverse-momentum amplitudes, and (ii) the leading exponential fall-off of the valence wave function in the impact-parameter space.
Bethe–Salpeter bound-state structure in Minkowski space
Energy Technology Data Exchange (ETDEWEB)
Gutierrez, C. [Instituto de Física Teórica, Universidade Estadual Paulista, 01156-970 São Paulo, SP (Brazil); Gigante, V.; Frederico, T. [Instituto Tecnológico de Aeronáutica, DCTA, 12.228-900 São José dos Campos, SP (Brazil); Salmè, G. [Istituto Nazionale di Fisica Nucleare, Sezione di Roma, P.le A. Moro 2, 00185 Roma (Italy); Viviani, M. [Istituto Nazionale di Fisica Nucleare, Sezione di Pisa, Largo Pontecorvo 3, 56100 Pisa (Italy); Tomio, Lauro, E-mail: tomio@ift.unesp.br [Instituto de Física Teórica, Universidade Estadual Paulista, 01156-970 São Paulo, SP (Brazil); Instituto Tecnológico de Aeronáutica, DCTA, 12.228-900 São José dos Campos, SP (Brazil)
2016-08-10
The quantitative investigation of the scalar Bethe–Salpeter equation in Minkowski space, within the ladder-approximation framework, is extended to include the excited states. This study has been carried out for an interacting system composed by two massive bosons exchanging a massive scalar, by adopting (i) the Nakanishi integral representation of the Bethe–Salpeter amplitude, and (ii) the formally exact projection onto the null plane. Our analysis, on one hand, confirms the reliability of the method already applied to the ground state and, on the other one, extends the investigation from the valence distribution in momentum space to the corresponding quantity in the impact-parameter space, pointing out some relevant features, like (i) the equivalence between Minkowski and Euclidean transverse-momentum amplitudes, and (ii) the leading exponential fall-off of the valence wave function in the impact-parameter space.
Excited States of the divacancy in SiC
Bockstedte, Michel; Garratt, Thomas; Ivady, Viktor; Gali, Adam
2014-03-01
The divacancy in SiC - a technologically mature material that fulfills the necessary requirements for hosting defect based quantum computing - is a good candidate for implementing a solid state quantum bit. Its ground state is isovalent to the NV center in diamond as demonstrated by density functional theory (DFT). Furthermore, coherent manipulation of divacancy spins in SiC has been demonstrated. The similarities to NV might indicate that the same inter system crossing (ICS) from the high to the low spin state is responsible for its spin-dependent fluorescent signal. By DFT and a DFT-based multi-reference hamiltonian we analyze the excited state spectrum of the defects. In contrast to the current picture of the spin dynamics of the NV center, we predict that a static Jahn-Teller effect in the first excited triplet states governs an ICS both with the excited and ground state of the divacancy.
Microwave spectroscopy of furfural in vibrationally excited states
Motiyenko, R. A.; Alekseev, E. A.; Dyubko, S. F.
2007-07-01
The results of microwave spectrum investigation of the excited vibrational states of furfural in the frequency range between 49 and 149 GHz are reported. In total 15 excited vibrational states (9 for trans-furfural and 6 for cis-furfural) were assigned and analyzed. Six of the 15 investigated states were assigned for the first time. Accurate values of rigid rotor and quartic centrifugal distortion constants of asymmetric top Hamiltonian have been determined for 13 excited states. Also for some states several sextic and octic level constants were needed in order to fit the data within experimental accuracy. The vt = 3 and vs = 1, va = 1 states of trans-furfural were found to be strongly perturbed and only rotational transitions with low Ka values can be reliably identified in this study.
Characterizing RNA Excited States using NMR Relaxation Dispersion
Xue, Yi; Kellogg, Dawn; Kimsey, Isaac J; Sathyamoorthy, Bharathwaj; Stein, Zachary W; McBrairty, Mitchell; Al-Hashimi, Hashim M.
2016-01-01
Changes in RNA secondary structure play fundamental roles in the cellular functions of a growing number of non-coding RNAs. This chapter describes NMR-based approaches for characterizing microsecond-to-millisecond changes in RNA secondary structure that are directed toward short-lived and low-populated species often referred to as “excited states”. Compared to larger-scale changes in RNA secondary structure, transitions towards excited states do not require assistance from chaperones, are often orders of magnitude faster, and are localized to a small number of nearby base pairs in and around non-canonical motifs. Here we describe a procedure for characterizing RNA excited states using off-resonance R1ρ NMR relaxation dispersion utilizing low-to-high spin-lock fields (25–3000 Hz). R1ρ NMR relaxation dispersion experiments are used to measure carbon and nitrogen chemical shifts in base and sugar moieties of the excited state. The chemical shift data is then interpreted with the aid of secondary structure prediction to infer potential excited states that feature alternative secondary structures. Candidate structures are then tested by using mutations, single-atom substitutions, or by changing physiochemical conditions, such as pH and temperature, to either stabilize or destabilize the candidate excited state. The resulting chemical shifts of the mutants or under different physiochemical conditions are then compared to those of the ground and excited state. Application is illustrated with a focus on the transactivation response element (TAR) from the human immune deficiency virus type 1 (HIV-1), which exists in dynamic equilibrium with at least two distinct excited states. PMID:26068737
Lasing action from photonic bound states in continuum
Kodigala, Ashok; Lepetit, Thomas; Gu, Qing; Bahari, Babak; Fainman, Yeshaiahu; Kanté, Boubacar
2017-01-01
In 1929, only three years after the advent of quantum mechanics, von Neumann and Wigner showed that Schrödinger’s equation can have bound states above the continuum threshold. These peculiar states, called bound states in the continuum (BICs), manifest themselves as resonances that do not decay. For several decades afterwards the idea lay dormant, regarded primarily as a mathematical curiosity. In 1977, Herrick and Stillinger revived interest in BICs when they suggested that BICs could be observed in semiconductor superlattices. BICs arise naturally from Feshbach’s quantum mechanical theory of resonances, as explained by Friedrich and Wintgen, and are thus more physical than initially realized. Recently, it was realized that BICs are intrinsically a wave phenomenon and are thus not restricted to the realm of quantum mechanics. They have since been shown to occur in many different fields of wave physics including acoustics, microwaves and nanophotonics. However, experimental observations of BICs have been limited to passive systems and the realization of BIC lasers has remained elusive. Here we report, at room temperature, lasing action from an optically pumped BIC cavity. Our results show that the lasing wavelength of the fabricated BIC cavities, each made of an array of cylindrical nanoresonators suspended in air, scales with the radii of the nanoresonators according to the theoretical prediction for the BIC mode. Moreover, lasing action from the designed BIC cavity persists even after scaling down the array to as few as 8-by-8 nanoresonators. BIC lasers open up new avenues in the study of light-matter interaction because they are intrinsically connected to topological charges and represent natural vector beam sources (that is, there are several possible beam shapes), which are highly sought after in the fields of optical trapping, biological sensing and quantum information.
Institute of Scientific and Technical Information of China (English)
2002-01-01
Neutron capture processes on carbon isotope play an important role in astrophysics ranging fromnucleosynthesis in the stellar helium and carbon burning stages to possibly inhomogeneous big bangmodels. The capture rate in astrophysical environments strongly depends on the structure of these carbonnuclei. For example, the first 1/2+ state in 13C is a neutron halo state, and these results in an enormous
2νββ decay of 76Ge into excited states with GERDA phase I
GERDA Collaboration; Agostini, M.; Allardt, M.; Bakalyarov, A. M.; Balata, M.; Barabanov, I.; Barros, N.; Baudis, L.; Bauer, C.; Becerici-Schmidt, N.; Bellotti, E.; Belogurov, S.; Belyaev, S. T.; Benato, G.; Bettini, A.; Bezrukov, L.; Bode, T.; Borowicz, D.; Brudanin, V.; Brugnera, R.; Budjáš, D.; Caldwell, A.; Cattadori, C.; Chernogorov, A.; D'Andrea, V.; Demidova, E. V.; di Vacri, A.; Domula, A.; Doroshkevich, E.; Egorov, V.; Falkenstein, R.; Fedorova, O.; Freund, K.; Frodyma, N.; Gangapshev, A.; Garfagnini, A.; Gooch, C.; Grabmayr, P.; Gurentsov, V.; Gusev, K.; Hegai, A.; Heisel, M.; Hemmer, S.; Heusser, G.; Hofmann, W.; Hult, M.; Inzhechik, L. V.; Janicskó Csáthy, J.; Jochum, J.; Junker, M.; Kazalov, V.; Kihm, T.; Kirpichnikov, I. V.; Kirsch, A.; Klimenko, A.; Knöpfle, K. T.; Kochetov, O.; Kornoukhov, V. N.; Kuzminov, V. V.; Laubenstein, M.; Lazzaro, A.; Lebedev, V. I.; Lehnert, B.; Liao, H. Y.; Lindner, M.; Lippi, I.; Lubashevskiy, A.; Lubsandorzhiev, B.; Lutter, G.; Macolino, C.; Majorovits, B.; Maneschg, W.; Medinaceli, E.; Mi, Y.; Misiaszek, M.; Moseev, P.; Nemchenok, I.; Palioselitis, D.; Panas, K.; Pandola, L.; Pelczar, K.; Pullia, A.; Riboldi, S.; Rumyantseva, N.; Sada, C.; Salathe, M.; Schmitt, C.; Schneider, B.; Schreiner, J.; Schulz, O.; Schwingenheuer, B.; Schönert, S.; Schütz, A.-K.; Selivanenko, O.; Shirchenko, M.; Simgen, H.; Smolnikov, A.; Stanco, L.; Stepaniuk, M.; Ur, C. A.; Vanhoefer, L.; Vasenko, A. A.; Veresnikova, A.; von Sturm, K.; Wagner, V.; Walter, M.; Wegmann, A.; Wester, T.; Wilsenach, H.; Wojcik, M.; Yanovich, E.; Zavarise, P.; Zhitnikov, I.; Zhukov, S. V.; Zinatulina, D.; Zuber, K.; Zuzel, G.
2015-11-01
Two neutrino double beta decay of {}76{Ge} to excited states of {}76{Se} has been studied using data from Phase I of the GERDA experiment. An array composed of up to 14 germanium detectors including detectors that have been isotopically enriched in {}76{Ge} was deployed in liquid argon. The analysis of various possible transitions to excited final states is based on coincidence events between pairs of detectors where a de-excitation γ ray is detected in one detector and the two electrons in the other. No signal has been observed and an event counting profile likelihood analysis has been used to determine Frequentist 90% C.L. bounds for three transitions: {0}{{g}.{{s}}.}+-{2}1+: {T}1/22ν \\gt 1.6× {10}23 yr, {0}{{g}.{{s}}.}+-{0}1+: {T}1/22ν \\gt 3.7× {10}23 yr and {0}{{g}.{{s}}.}+-{2}2+: {T}1/22ν \\gt 2.3× {10}23 yr. These bounds are more than two orders of magnitude larger than those reported previously. Bayesian 90% credibility bounds were extracted and used to exclude several models for the {0}{{g}.{{s}}.}+-{0}1+ transition.
Targeting excited states in all-trans polyenes with electron-pair states
Boguslawski, Katharina
2016-12-01
Wavefunctions restricted to electron pair states are promising models for strongly correlated systems. Specifically, the pair Coupled Cluster Doubles (pCCD) ansatz allows us to accurately describe bond dissociation processes and heavy-element containing compounds with multiple quasi-degenerate single-particle states. Here, we extend the pCCD method to model excited states using the equation of motion (EOM) formalism. As the cluster operator of pCCD is restricted to electron-pair excitations, EOM-pCCD allows us to target excited electron-pair states only. To model singly excited states within EOM-pCCD, we modify the configuration interaction ansatz of EOM-pCCD to contain also single excitations. Our proposed model represents a simple and cost-effective alternative to conventional EOM-CC methods to study singly excited electronic states. The performance of the excited state models is assessed against the lowest-lying excited states of the uranyl cation and the two lowest-lying excited states of all-trans polyenes. Our numerical results suggest that EOM-pCCD including single excitations is a good starting point to target singly excited states.
Impact of Electric Fields on Highly Excited Rovibrational States of Polar Dimers
Gonzalez-Ferez, Rosario
2008-01-01
We study the effect of a strong static homogeneous electric field on the highly excited rovibrational levels of the LiCs dimer in its electronic ground state. Our full rovibrational investigation of the system includes the interaction with the field due to the permanent electric dipole moment and the polarizability of the molecule. We explore the evolution of the states next to the dissociation threshold as the field strength is increased. The rotational and vibrational dynamics are influenced by the field; effects such as orientation, angular motion hybridization and squeezing of the vibrational motion are demonstrated and analyzed. The field also induces avoided crossings causing a strong mixing of the electrically dressed rovibrational states. Importantly, we show how some of these highly excited levels can be shifted to the continuum as the field strength is increased, and reversely how two atoms in the continuum can be brought into a bound state by lowering the electric field strength.
Universal Bounds on Charged States in 2d CFT and 3d Gravity
Benjamin, Nathan; Fitzpatrick, A Liam; Kachru, Shamit
2016-01-01
We derive an explicit bound on the dimension of the lightest charged state in two dimensional conformal field theories with a global abelian symmetry. We find that the bound scales with $c$ and provide examples that parametrically saturate this bound. We also prove than any such theory must contain a state with charge-to-mass ratio above a minimal lower bound. We comment on the implications for charged states in three dimensional theories of gravity.
Bound states in the continuum in open acoustic resonators
Lyapina, A A; Pilipchuk, A S; Sadreev, A F
2015-01-01
We consider bound states in the continuum (BSC) or embedded trapped modes in two- and three-dimensional acoustic axisymmetric duct-cavity structures. We demonstrate numerically that under variation of the length of the cavity multiple BSCs occur due to the Friedrich-Wintgen two-mode full destructive interference mechanism. The BSCs are detected by tracing the resonant widths to the points of the collapse of Fano resonances where one of the two resonant modes acquires infinite life-time. It is shown that the approach of the acoustic coupled mode theory cast in the truncated form of a two-mode approximation allows us to analytically predict the BSC frequencies and shape functions to a good accuracy in both two and three dimensions.
Three-boson bound states in finite volume with EFT
Kreuzer, S.; Hammer, H.-W.
2010-04-01
The universal properties of a three-boson system with large scattering length are well understood within the framework of Effective Field Theory. They include a geometric spectrum of shallow three-body bound states called “Efimov states” and log-periodic dependence of scattering observables on the scattering length. We investigate the modification of this spectrum in a finite cubic box using a partial wave expansion. The dependence of the binding energies on the box size is calculated for systems with positive and negative two-body scattering length. We compare the full results to results obtained using an expansion around the infinite volume binding energy. The renormalization of the Effective Field Theory in the finite volume is verified explicitly.
Rapid thermal co-annihilation through bound states
Kim, Seyong
2016-01-01
The co-annihilation rate of heavy particles close to thermal equilibrium, which plays a role in many classic dark matter scenarios, can be "simulated" in QCD by considering the pair annihilation rate of a heavy quark and antiquark at a temperature of a few hundred MeV. We show that the so-called Sommerfeld factors, parameterizing the rate, can be defined and measured non-perturbatively within the NRQCD framework. Lattice measurements indicate a modest suppression in the octet channel, in reasonable agreement with perturbation theory, and a large enhancement in the singlet channel, much above the perturbative prediction. We suggest that the additional enhancement originates from bound state formation and subsequent decay, omitted in previous estimates of thermal Sommerfeld factors, which were based on Boltzmann equations governing single-particle phase space distributions.
Weakly bound states with spin-isospin symmetry
Kievsky, A.; Gattobigio, M.
2016-03-01
We discuss weakly bound states of a few-fermion system having spin-isospin symmetry. This corresponds to the nuclear physics case in which the singlet, a0, and triplet, a1, n - p scattering lengths are large with respect to the range of the nuclear interaction. The ratio of the two is about a0/a1 ≈ -4.31. This value defines a plane in which a0 and a1 can be varied up to the unitary limit, 1/a0 = 0 and 1/a1 = 0, maintaining its ratio fixed. Using a spin dependant potential model we estimate the three-nucleon binding energy along that plane. This analysis can be considered an extension of the Efimov plot for three bosons to the case of three 1/2-spin-isospin fermions.
Weakly bound states with spin-isospin symmetry
Kievsky, A
2015-01-01
We discuss weakly bound states of a few-fermion system having spin-isospin symmetry. This corresponds to the nuclear physics case in which the singlet, $a_0$, and triplet, $a_1$, $n-p$ scattering lengths are large with respect to the range of the nuclear interaction. The ratio of the two is about $a_0/a_1\\approx-4.31$. This value defines a plane in which $a_0$ and $a_1$ can be varied up to the unitary limit, $1/a_0=0$ and $1/a_1=0$, maintaining its ratio fixed. Using a spin dependant potential model we estimate the three-nucleon binding energy along that plane. This analysis can be considered an extension of the Efimov plot for three bosons to the case of three $1/2$-spin-isospin fermions.
Weakly bound states with spin-isospin symmetry
Directory of Open Access Journals (Sweden)
Kievsky A.
2016-01-01
Full Text Available We discuss weakly bound states of a few-fermion system having spin-isospin symmetry. This corresponds to the nuclear physics case in which the singlet, a0, and triplet, a1, n − p scattering lengths are large with respect to the range of the nuclear interaction. The ratio of the two is about a0/a1 ≈ −4.31. This value defines a plane in which a0 and a1 can be varied up to the unitary limit, 1/a0 = 0 and 1/a1 = 0, maintaining its ratio fixed. Using a spin dependant potential model we estimate the three-nucleon binding energy along that plane. This analysis can be considered an extension of the Efimov plot for three bosons to the case of three 1/2-spin-isospin fermions.
Excited state correlations of the finite Heisenberg chain
Pozsgay, Balázs
2017-02-01
We consider short range correlations in excited states of the finite XXZ and XXX Heisenberg spin chains. We conjecture that the known results for the factorized ground state correlations can be applied to the excited states too, if the so-called physical part of the construction is changed appropriately. For the ground state we derive simple algebraic expressions for the physical part; the formulas only use the ground state Bethe roots as an input. We conjecture that the same formulas can be applied to the excited states as well, if the exact Bethe roots of the excited states are used instead. In the XXZ chain the results are expected to be valid for all states (except certain singular cases where regularization is needed), whereas in the XXX case they only apply to singlet states or group invariant operators. Our conjectures are tested against numerical data from exact diagonalization and coordinate Bethe Ansatz calculations, and perfect agreement is found in all cases. In the XXX case we also derive a new result for the nearest-neighbour correlator , which is valid for non-singlet states as well. Our results build a bridge between the known theory of factorized correlations, and the recently conjectured TBA-like description for the building blocks of the construction.
Shape vibrations and quasiparticle excitations in the lowest 0+ excited state of the Erbium isotopes
Chen, Fang-Qi
2016-01-01
The ground and first excited 0+ states of the {156-172}Er isotopes are analyzed in the framework of the generator coordinate method. The shape parameter beta is used to generate wave functions with different deformations which together with the two-quasiparticle states built on them provide a set of states. An angular momentum and particle number projection of the latter spawn the basis states of the generator coordinate method. With this ansatz and using the separable pairing plus quadrupole interaction we obtain a good agreement with the experimental spectra and E2 transition rates up to moderate spin values. The structure of the wave functions suggests that the first excited 0+ states in the soft Er isotopes are dominated by shape fluctuations, while in the well deformed Er isotopes the two-quasiparticle states are more relevant. In between both degrees of freedom are necessary .
Even-parity states of the Sm atom with stepwise excitation
Institute of Scientific and Technical Information of China (English)
Li Ming; Dai Chang-Jian; Xie Jun
2011-01-01
Two-colour stepwise excitation and photoionization schemes are adopted to study the spectra of high-lying states of the Sm atom. These bound even-parity states are excited with three different excitation paths from the 4f66s6p7DJ (J = 1, 2, 3) intermediate states, respectively. They are probed by photoionization process with an extra photon driving them to the continuum states. In this experiment, 270 states are detected in an energy range from 36160 cm-1 to 42250 cm-1, 109 of which are newly discovered, while the rest of them are confirmed to be the energy levels reported previously. Furthermore, based on the J-momentum selection rules of three excitation paths, a unique assignment of J-momentum for all observed states is determined, eliminating all remaining ambiguities in the literature. Finally, 53 single-colour transitions originating from the scanning laser are also identified. For all the relevant transitions, the information about their relative intensities is also given in the paper.
Bound Polaron Pair Formation in Poly (phenylenevinylenes)
Rothberg, Lewis
The following sections are included: * INTRODUCTION * PHOTOGENERATED YIELD OF SINGLET EXCITONS * AGGREGRATION EFFECTS ON EXCITED STATE PHOTO-GENERATION * ASSIGNMENT TO BOUND POLARON PAIRS AND DISCUSSION * PROBLEMS WITH THE BOUND POLARON PAIR PICTURE AND CONCLUSION * REFERENCES
Probing the Dark Sector with Dark Matter Bound States.
An, Haipeng; Echenard, Bertrand; Pospelov, Maxim; Zhang, Yue
2016-04-15
A model of the dark sector where O(few GeV) mass dark matter particles χ couple to a lighter dark force mediator V, m_{V}≪m_{χ}, is motivated by the recently discovered mismatch between simulated and observed shapes of galactic halos. Such models, in general, provide a challenge for direct detection efforts and collider searches. We show that for a large range of coupling constants and masses, the production and decay of the bound states of χ, such as 0^{-+} and 1^{--} states, η_{D} and ϒ_{D}, is an important search channel. We show that e^{+}e^{-}→η_{D}+V or ϒ_{D}+γ production at B factories for α_{D}>0.1 is sufficiently strong to result in multiple pairs of charged leptons and pions via η_{D}→2V→2(l^{+}l^{-}) and ϒ_{D}→3V→3(l^{+}l^{-}) (l=e,μ,π). The absence of such final states in the existing searches performed at BABAR and Belle sets new constraints on the parameter space of the model. We also show that a search for multiple bremsstrahlung of dark force mediators, e^{+}e^{-}→χχ[over ¯]+nV, resulting in missing energy and multiple leptons, will further improve the sensitivity to self-interacting dark matter.
Johansen, J G; Borge, M J G; Cubero, M; Diriken, J; Elsevier, J; Fraile, L M; Fynbo, H O U; Gaffney, L P; Gernhäuser, R; Jonson, B; Koldste, G T; Konki, J; Kröll, T; Krücken, R; Mücher, D; Nilsson, T; Nowak, K; Pakarinen, J; Pesudo, V; Raabe, R; Riisager, K; Seidlitz, M; Tengblad, O; Törnqvist, H; Voulot, D; Warr, N; Wenander, F; Wimmer, K; De Witte, H
2013-01-01
The bound states of $^{12}$Be have been studied through a $^{11}$Be$(d,p)^{12}$Be transfer reaction experiment in inverse kinematics. A 2.8 MeV/u beam of $^{11}$Be was produced using the REX-ISOLDE facility at CERN. The outgoing protons were detected with the T-REX silicon detector array. The MINIBALL germanium array was used to detect $\\gamma$-rays from the excited states in $^{12}$Be. The $\\gamma$-ray detection enabled a clear identification of the four known bound states in $^{12}$Be, and each of the states has been studied individually. Differential cross sections over a large angular range have been extracted. Spectroscopic factors for each of the states have been determined from DWBA calculations and have been compared to previous experimental and theoretical results.
Bounds for entanglement of formation of two mode squeezed thermal states
Chen, X Y; Chen, Xiao-Yu; Qiu, Pei-liang
2003-01-01
The upper and lower bounds of entanglement of formation are given for two mode squeezed thermal state. The bounds are compared with other entanglement measure or bounds. The entanglement distillation and the relative entropy of entanglement of infinitive squeezed state are obtained at the postulation of hashing inequality.
Two-vibron bound states in the β-Fermi-Pasta-Ulam model
Institute of Scientific and Technical Information of China (English)
Hu Xin-Guang; Tang Yi
2008-01-01
This paper studies the two-vibron bound states in the β-Fermi-Pasta-Ulam model by means of the number conserving approximation combined with the number state method.The results indicate that on-site,adjacent-site and mixed two-vibron bound states may exist in the model.Specially,wave number has a significant effect on such bound states,which may be considered as the quantum effects of the localized states in quantum systems.
Neutron halos in the excited states for N=127 isotones
Institute of Scientific and Technical Information of China (English)
SUN Qin; GUO Jian-You
2009-01-01
Properties of the ground states and the excited states of N=127 isotones are investigated by using the nonlinear relativistic mean field theory with the interactions PK1. By analyzing the rms of proton and neutron, the single particle energies of valence nucleon and the density distributions of neutron, proton and the last neutron, it can be found that there exists a neutron halo in the excited states of 3d5/2, 4s1/2 and 3d3/2 in 209Pb. It is also predicted that there exists a neutron halo in the excited states of 3d5/2, 4s1/2 and 3d3/2 in 207Hg, 208Tl, 210Bi and 211Po.
Super-atom molecular orbital excited states of fullerenes.
Johansson, J Olof; Bohl, Elvira; Campbell, Eleanor E B
2016-09-13
Super-atom molecular orbitals are orbitals that form diffuse hydrogenic excited electronic states of fullerenes with their electron density centred at the centre of the hollow carbon cage and a significant electron density inside the cage. This is a consequence of the high symmetry and hollow structure of the molecules and distinguishes them from typical low-lying molecular Rydberg states. This review summarizes the current experimental and theoretical studies related to these exotic excited electronic states with emphasis on femtosecond photoelectron spectroscopy experiments on gas-phase fullerenes.This article is part of the themed issue 'Fullerenes: past, present and future, celebrating the 30th anniversary of Buckminster Fullerene'.
Excited states of Ne isoelectronic ions: SAC-CI study
Energy Technology Data Exchange (ETDEWEB)
Das, A.K.; Ehara, M.; Nakatsuji, H. [Kyoto Univ. (Japan). Faculty of Engineering
2001-02-01
Excited states of the s, p, and d symmetries up to principal quantum number n = 4 are studied for the first eight members of Ne isoelectronic sequence (Ne to Cl{sup 7+}) by the SAC-CI (symmetry-adapted-cluster configuration-interaction) method. The valence STO basis sets of Clementi et al. and the optimized excited STO are used by the STO-6G expansion method. The calculated transition energies agree well with the experimental values wherever available. (orig.)
Ultrafast excited-state intramolecular proton transfer of aloesaponarin I.
Nagaoka, Shin-ichi; Uno, Hidemitsu; Huppert, Dan
2013-04-25
Time-resolved emission of aloesaponarin I was studied with the fluorescence up-conversion and time-correlated single-photon-counting techniques. The rates of the excited-state intramolecular proton transfer, of the solvent and molecular rearrangements, and of the decay from the excited proton-transferred species were determined and interpreted in the light of time-dependent density functional calculations. These results were discussed in conjunction with UV protection and singlet-oxygen quenching activity of aloe.
Extended Eckart Theorem and New Variation Method for Excited States of Atoms
Xiong, Zhuang; Bacalis, N C; Zhou, Qin
2016-01-01
We extend the Eckart theorem, from the ground state to excited statew, which introduces an energy augmentation to the variation criterion for excited states. It is shown that the energy of a very good excited state trial function can be slightly lower than the exact eigenvalue. Further, the energy calculated by the trial excited state wave function, which is the closest to the exact eigenstate through Gram-Schmidt orthonormalization to a ground state approximant, is lower than the exact eigenvalue as well. In order to avoid the variation restrictions inherent in the upper bound variation theory based on Hylleraas, Undheim, and McDonald [HUM] and Eckart Theorem, we have proposed a new variation functional Omega-n and proved that it has a local minimum at the eigenstates, which allows approaching the eigenstate unlimitedly by variation of the trial wave function. As an example, we calculated the energy and the radial expectation values of Triplet-S(even) Helium atom by the new variation functional, and by HUM a...
Excited-state dynamics of astaxanthin aggregates
Fuciman, Marcel; Durchan, Milan; Šlouf, Václav; Keşan, Gürkan; Polívka, Tomáš
2013-05-01
Astaxanthin forms three types of aggregates in hydrated dimethyl sulfoxide (DMSO). In DMSO/water ratio of 1:1, a red-shifted J-aggregate with maximum at 570 nm is generated, while a ratio of 1:9 produces blue-shifted H-aggregates with peaks at 386 nm (H1) and 460 nm (H2). Monomeric astaxanthin in DMSO has an S1 lifetime of 5.3 ps, but a long-lived (33 ps) S∗ signal was also identified. Aggregation changes the S1 lifetimes to 17 ps (H1), 30 ps (H2), and 14 ps (J). Triplet state of astaxanthin, most likely generated via singlet homofission, was observed in H1 and H2 aggregates.
Full-potential multiple scattering theory with space-filling cells for bound and continuum states.
Hatada, Keisuke; Hayakawa, Kuniko; Benfatto, Maurizio; Natoli, Calogero R
2010-05-12
We present a rigorous derivation of a real-space full-potential multiple scattering theory (FP-MST) that is free from the drawbacks that up to now have impaired its development (in particular the need to expand cell shape functions in spherical harmonics and rectangular matrices), valid both for continuum and bound states, under conditions for space partitioning that are not excessively restrictive and easily implemented. In this connection we give a new scheme to generate local basis functions for the truncated potential cells that is simple, fast, efficient, valid for any shape of the cell and reduces to the minimum the number of spherical harmonics in the expansion of the scattering wavefunction. The method also avoids the need for saturating 'internal sums' due to the re-expansion of the spherical Hankel functions around another point in space (usually another cell center). Thus this approach provides a straightforward extension of MST in the muffin-tin (MT) approximation, with only one truncation parameter given by the classical relation l(max) = kR(b), where k is the electron wavevector (either in the excited or ground state of the system under consideration) and R(b) is the radius of the bounding sphere of the scattering cell. Moreover, the scattering path operator of the theory can be found in terms of an absolutely convergent procedure in the l(max) --> ∞ limit. Consequently, this feature provides a firm ground for the use of FP-MST as a viable method for electronic structure calculations and makes possible the computation of x-ray spectroscopies, notably photo-electron diffraction, absorption and anomalous scattering among others, with the ease and versatility of the corresponding MT theory. Some numerical applications of the theory are presented, both for continuum and bound states.
Energy Technology Data Exchange (ETDEWEB)
Shuai, Zhigang, E-mail: zgshuai@tsinghua.edu.cn [MOE Key Laboratory of Organic OptoElectronics and Molecular Engineering, Department of Chemistry, Tsinghua University, 100084 Beijing (China); Peng, Qian, E-mail: qpeng@iccas.ac.cn [Beijing National Laboratory for Molecular Science (BNLMS), Institute of Chemistry, Chinese Academy of Sciences, 100190 Beijing (China)
2014-04-01
Photo- or electro-excited states in polyatomic molecules, aggregates, and conjugated polymers are at the center of organic light-emitting diodes (OLEDs). These can decay radiatively or non-radiatively, determining the luminescence quantum efficiency of molecular materials. According to Kasha’s rule, light-emission is dictated by the lowest-lying excited state. For conjugated polymers, the electron correlation effect can lead the lowest-lying excited state to the even-parity 2A{sub g} state which is non-emissive. To understand the nature of the low-lying excited state structure, we developed the density matrix renormalization group (DMRG) theory and its symmetrization scheme for quantum chemistry applied to calculate the excited states structure. We found there are three types of 1B{sub u}/2A{sub g} crossover behaviors: with electron correlation strength U, with bond length alternation, and with conjugation length. These directly influence the light-emitting property. For the electro-excitation, carriers (electron and hole) are injected independently, forming both singlet and triplet excited bound states with statistically 25% and 75% portions, respectively. We found that the exciton formation rate can depend on spin manifold, and for conjugated polymers, the singlet exciton can have larger formation rate leading to the internal electroluminescence quantum efficiency larger than the 25% spin statistical limit. It is originated from the interchain electron correlation as well as intrachain lattice relaxation. For the dipole allowed emissive state, the radiative decay process via either spontaneous emission or stimulated emission can be computed from electronic structure plus vibronic couplings. The challenging issue lies in the non-radiative decay via non-adiabatic coupling and/or spin–orbit coupling. We developed a unified correlation function formalism for the excited state radiative and non-radiative decay rates. We emphasized the low-frequency mode mixing
State-Selective Excitation of Quantum Systems via Geometrical Optimization.
Chang, Bo Y; Shin, Seokmin; Sola, Ignacio R
2015-09-08
We lay out the foundations of a general method of quantum control via geometrical optimization. We apply the method to state-selective population transfer using ultrashort transform-limited pulses between manifolds of levels that may represent, e.g., state-selective transitions in molecules. Assuming that certain states can be prepared, we develop three implementations: (i) preoptimization, which implies engineering the initial state within the ground manifold or electronic state before the pulse is applied; (ii) postoptimization, which implies engineering the final state within the excited manifold or target electronic state, after the pulse; and (iii) double-time optimization, which uses both types of time-ordered manipulations. We apply the schemes to two important dynamical problems: To prepare arbitrary vibrational superposition states on the target electronic state and to select weakly coupled vibrational states. Whereas full population inversion between the electronic states only requires control at initial time in all of the ground vibrational levels, only very specific superposition states can be prepared with high fidelity by either pre- or postoptimization mechanisms. Full state-selective population inversion requires manipulating the vibrational coherences in the ground electronic state before the optical pulse is applied and in the excited electronic state afterward, but not during all times.
Two-Mode Excited Entangled Coherent State: Nonclassicality and Entanglement
Zhang, Hao-Liang; Wu, Jia-Ni; Liu, Cun-Jin; Hu, Yin-Quan; Hu, Li-Yun
2017-03-01
Two-mode excited entangled coherent states (TME-ECSs) are introduced by operating repeatedly the photon-excited operator on the ECSs. It is shown that the normalization constant is related to the product of two Laguerre polynomials. The influence of the operation on nonclassical behaviour of the ECSs is investigated in terms of cross-correlation function, anti-bunching effect and the negativity of Wigner function, which show that nonclassical properties can be enhanced. In addition, inseparability properties of the TME-ECSs are discussed by using Bell inequality and concurrence. It is found that the degree of quantum entanglement of even ECSs increases with the increase of the total excited photon number, and the violation of Bell inequality can be present for both even and odd case only when the total excited photon numbers are even and odd, respectively.
The Problem of Mass: Mesonic Bound States Above T_c
Park, H J; Brown, G E; Park, Hong-Jo; Lee, Chang-Hwan; Brown, Gerald E.
2005-01-01
We discuss the problem of mass, noting that meson masses decrease with increasing scale as the dynamically generated condensate of "soft glue" is melted (Brown/Rho scaling). We then extend the Bielefeld LGS color singlet interaction computed for heavy quarks in a model-dependent way by including the Ampere law velocity-velocity interaction. Parameterizing the resulting interaction in terms of effective strength of the potential and including screening, we find that the masses of pi, sigma, rho and A1 excitations, 32 degrees of freedom in all, go to zero (in the chiral limit) as T goes to Tc essentially independently of the input quark (thermal) masses in the range of 1-2 GeV, calculated also in Bielefeld. We discuss other LGS which show q-bar q bound states, which we interpret as our chirally restored mesons, for T > Tc.
First-principles Calculation of Excited State Spectra in QCD
Energy Technology Data Exchange (ETDEWEB)
Jozef Dudek,Robert Edwards,Michael Peardon,David Richards,Christopher Thomas
2011-05-01
Recent progress at understanding the excited state spectra of mesons and baryons is described. I begin by outlining the application of the variational method to compute the spectrum of QCD, and then present results for the excited meson spectrum, with continuum quantum numbers of the states clearly delineated. I emphasise the need to extend the calculation to encompass multi-hadron contributions, and describe a recent calculation of the I=2 pion-pion energy-dependent phase shifts as a precursor to the study of channels with resonant behavior. I conclude with recent results for the low lying baryon spectrum, and the prospects for future calculations.
Accurate Excited State Geometries within Reduced Subspace TDDFT/TDA.
Robinson, David
2014-12-09
A method for the calculation of TDDFT/TDA excited state geometries within a reduced subspace of Kohn-Sham orbitals has been implemented and tested. Accurate geometries are found for all of the fluorophore-like molecules tested, with at most all valence occupied orbitals and half of the virtual orbitals included but for some molecules even fewer orbitals. Efficiency gains of between 15 and 30% are found for essentially the same level of accuracy as a standard TDDFT/TDA excited state geometry optimization calculation.
Coherent excitation of a single atom to a Rydberg state
DEFF Research Database (Denmark)
Miroshnychenko, Yevhen; Gaëtan, Alpha; Evellin, Charles
2010-01-01
We present the coherent excitation of a single Rubidium atom to the Rydberg state 58d3/2 using a two-photon transition. The experimental setup is described in detail, as are experimental techniques and procedures. The coherence of the excitation is revealed by observing Rabi oscillations between...... ground and Rydberg states of the atom. We analyze the observed oscillations in detail and compare them to numerical simulations which include imperfections of our experimental system. Strategies for future improvements on the coherent manipulation of a single atom in our settings are given....
Multiple-Pulse Operation and Bound States of Solitons in Passive Mode-Locked Fiber Lasers
Directory of Open Access Journals (Sweden)
A. Komarov
2012-01-01
Full Text Available We present results of our research on a multiple-pulse operation of passive mode-locked fiber lasers. The research has been performed on basis of numerical simulation. Multihysteresis dependence of both an intracavity energy and peak intensities of intracavity ultrashort pulses on pump power is found. It is shown that the change of a number of ultrashort pulses in a laser cavity can be realized by hard as well as soft regimes of an excitation and an annihilation of new solitons. Bound steady states of interacting solitons are studied for various mechanisms of nonlinear losses shaping ultrashort pulses. Possibility of coding of information on basis of soliton trains with various bonds between neighboring pulses is discussed. The role of dispersive wave emitted by solitons because of lumped intracavity elements in a formation of powerful soliton wings is analyzed. It is found that such powerful wings result in large bounding energies of interacting solitons in steady states. Various problems of a soliton interaction in passive mode-locked fiber lasers are discussed.
Examination of experimental evidence of chaos in the bound states of 208Pb
Muñoz, L.; Molina, R. A.; Gómez, J. M. G.; Heusler, A.
2017-01-01
We study the spectral fluctuations of the 208Pb nucleus using the complete experimental spectrum of 151 states up to excitation energies of 6.20 MeV recently identified at the Maier-Leibnitz Laboratorium at Garching, Germany. For natural parity states the results are very close to the predictions of random matrix theory (RMT) for the nearest-neighbor spacing distribution. A quantitative estimate of the agreement is given by the Brody parameter ω , which takes the value ω =0 for regular systems and ω ≃1 for chaotic systems. We obtain ω =0.85 which is, to our knowledge, the closest value to chaos ever observed in experimental bound states of nuclei. By contrast, the results for unnatural parity states are far from RMT behavior. We interpret these results as a consequence of the strength of the residual interaction in 208Pb, which, according to experimental data, is much stronger for natural than for unnatural parity states. In addition, our results show that chaotic and nonchaotic nuclear states coexist in the same energy region of the spectrum.
Skobelev, N. K.
2016-07-01
Experimental data on the cross sections for channels of fusion and transfer reactions induced by beams of radioactive halo nuclei and clustered and stable loosely bound nuclei were analyzed, and the results of this analysis were summarized. The interplay of the excitation of single-particle states in reaction-product nuclei and direct reaction channels was established for transfer reactions. Respective experiments were performed in stable (6Li) and radioactive (6He) beams of the DRIBs accelerator complex at the Flerov Laboratory of Nuclear Reactions, Joint Institute for Nuclear Research, and in deuteron and 3He beams of the U-120M cyclotron at the Nuclear Physics Institute, Academy Sciences of Czech Republic (Řež and Prague, Czech Republic). Data on subbarrier and near-barrier fusion reactions involving clustered and loosely bound light nuclei (6Li and 3He) can be described quite reliably within simple evaporation models with allowance for different reaction Q-values and couple channels. In reactions involving halo nuclei, their structure manifests itself most strongly in the region of energies below the Coulomb barrier. Neutron transfer occurs with a high probability in the interactions of all loosely bound nuclei with light and heavy stable nuclei at positive Q-values. The cross sections for such reactions and the respective isomeric ratios differ drastically for nucleon stripping and nucleon pickup mechanisms. This is due to the difference in the population probabilities for excited single-particle states.
Octupole correlations in excited 0{sup +} states of the actinides
Energy Technology Data Exchange (ETDEWEB)
Spieker, Mark; Endres, Janis; Zilges, Andreas [Institute for Nuclear Physics, University of Cologne (Germany); Bucurescu, Dorel; Pascu, Sorin; Zamfir, Nicolae-Victor [Horia Hulubei National Institute of Physics and Nuclear Engineering, Bucharest (Romania); Faestermann, Thomas [Physik Department, Technische Universitaet Muenchen, Munich (Germany); Hertenberger, Ralf; Wirth, Hans-Friedrich [Fakultaet fuer Physik, Ludwig-Maximilians-Universitaet Muenchen, Munich (Germany)
2014-07-01
New experimental data has once again shown the importance of the octupole degree of freedom in the actinides. To further study possible admixtures of double-octupole structures to the wave function of positive-parity states, a high-resolution (p,t) experiment on {sup 242}Pu has been recently performed at the Q3D magnetic spectrograph in Munich. Excited 0{sup +} states were populated in {sup 240}Pu up to an excitation energy of 3 MeV. The new data allowed for a stringent test of the predictions of the spdf interacting boson model. In order to find possible double-octupole 0{sup +} candidates in the actinides, the signature of close-lying first and second excited 0{sup +} states has been proposed. It is found that the observation of this signature coincides with an E1 γ-decay of the first excited 0{sup +} state, while this state is strongly populated in the (p,t) reaction.
Electronically excited negative ion resonant states in chloroethylenes
Energy Technology Data Exchange (ETDEWEB)
Khvostenko, O.G., E-mail: khv@mail.ru; Lukin, V.G.; Tuimedov, G.M.; Khatymova, L.Z.; Kinzyabulatov, R.R.; Tseplin, E.E.
2015-02-15
Highlights: • Several novel dissociative negative ion channels were revealed in chloroethylenes. • The electronically excited resonant states were recorded in all chloroethylenes under study. • The states were assigned to the inter-shell types, but not to the core-excited Feshbach one. - Abstract: The negative ion mass spectra of the resonant electron capture by molecules of 1,1-dichloroethylene, 1,2-dichloroethylene-cis, 1,2-dichloroethylene-trans, trichloroethylene and tetrachloroethylene have been recorded in the 0–12 eV range of the captured electron energy using static magnetic sector mass spectrometer modified for operation in the resonant electron capture regime. As a result, several novel low-intensive dissociation channels were revealed in the compounds under study. Additionally, the negative ion resonant states were recorded at approximately 3–12 eV, mostly for the first time. These resonant states were assigned to the electronically excited resonances of the inter-shell type by comparing their energies with those of the parent neutral molecules triplet and singlet electronically excited states known from the energy-loss spectra obtained by previous studies.
Youker, Diane Greer
The research presented in this dissertation focuses on elucidating the parameters affecting dynamics and yield of electron transfer reactions in semiconducting nanoparticle assemblies through the use of time-resolved spectroscopy. In particular, the dissertation focuses on photoinduced electron injection in assemblies of CdSe, CdS, or PbS quantum dots covalently bound to either metal oxide films or each other through the use of bifunctional molecular linkers. Chapter 2 elucidates the influence of electronic coupling on excited-state electron transfer from CdS quantum dots to TiO2 nanoparticles via molecular linkers with phenylene bridges. We establish that the efficiency of electron injection from CdS quantum dots to TiO2 nanoparticle varies dramatically with electronic coupling, which can be controlled by tuning the properties of molecular linkers. Chapter 3 presents the role of excitation energy on interfacial electron transfer in tethered assemblies of CdSe quantum dots and TiO2 nanoparticles. Through this work, we determined that injection efficiency from band-edge states is independent of excitation energy. However, the efficiency of injection from trap-states decreases at lower-energy excitation. We attribute the decrease to a lower energy distribution of emissive trap-states from which injection is less efficient. Chapter 4 presents the observation of multiphasic electron injection dynamics from photoexcited PbS quantum dots to TiO2 nanoparticles. In this collaborative study with Dr. Masumoto from the University of Tsukuba we observed electron injection on multiple timescales. We determined that electron injection occurred in this system through two different mechanisms. The first involved injection from thermalized PbS excited states and the second through injection of hot electrons through Auger recombination of biexcitons that creates high lying excitonic states. Chapter 5 investigates charge transfer in covalently bound quantum dot assemblies. We utilize
Excited state tautomerization of 7-azaindole catalyzed by pyrazole
Karmakar, Shreetama; Mukherjee, Moitrayee; Chakraborty, Tapas
2013-03-01
Pyrazole, a five member cyclic azole, is reported here as an efficient catalyst for excited state tautomeric conversion of 7-azaindole. In hydrocarbon solution the two compounds efficiently form a doubly hydrogen-bonded 1:1 cyclic complex whose association constant value is found comparable with 7-azaindole dimerization constant, and according to B3LYP/6-311G++∗∗ calculation the binding energies of the complex and dimer are nearly same. In the excited state (S1), the TDDFT calculation predicts tautomer of the complex to be 13.4 kcal/mol more stable than normal form. Fluorescence spectra reveal that upon UV excitation the complex emits exclusively from the tautomeric form.
Diphoton decay of the Higgs boson and new bound states of top and anti-top quarks
Froggatt, C D; Laperashvili, L V; Nielsen, H B
2015-01-01
We consider the constraints, provided by the LHC results on Higgs boson decay into 2 photons and its production via gluon fusion, on the previously proposed Standard Model (SM) strongly bound state $S$ of 6 top quarks and 6 anti-top quarks. A correlation is predicted between the ratios $\\kappa_{\\gamma}$ and $\\kappa_g$ of the Higgs diphoton decay and gluon production amplitudes respectively to their SM values. We estimate the contribution to these amplitudes from one loop diagrams involving the 12 quark bound state $S$ and related excited states using an atomic physics based model. We find two regions of parameter space consistent with the ATLAS and CMS data on ($\\kappa_{\\gamma}$, $\\kappa_g$) at the 3 sigma level: a region close to the SM values ($\\kappa_{\\gamma}=1$, $\\kappa_g =1$) with the mass of the bound state $m_S > 400$ GeV and a region with ($\\kappa_{\\gamma} \\sim 3/2$, $\\kappa_g \\sim -3/4$) corresponding to a bound state mass of $m_S \\sim 220$ GeV.
First clear evidence of quantum chaos in the bound states of an atomic nucleus
Muñoz, L; Gómez, J M G; Heusler, A
2016-01-01
We study the spectral fluctuations of the $^{208}$Pb nucleus using the complete experimental spectrum of 151 states up to excitation energies of $6.20$ MeV recently identified at the Maier-Leibnitz-Laboratorium at Garching, Germany. For natural parity states the results are very close to the predictions of Random Matrix Theory (RMT) for the nearest-neighbor spacing distribution. A quantitative estimate of the agreement is given by the Brody parameter $\\omega$, which takes the value $\\omega=0$ for regular systems and $\\omega \\simeq 1$ for chaotic systems. We obtain $\\omega=0.85 \\pm 0.02$ which is, to our knowledge, the closest value to chaos ever observed in experimental bound states of nuclei. By contrast, the results for unnatural parity states are far from RMT behavior. We interpret these results as a consequence of the strength of the residual interaction in $^{208}$Pb, which, according to experimental data, is much stronger for natural than for unnatural parity states. In addition our results show that ch...
Estimation of correlation energy for excited-states of atoms
Hemanadhan, M
2014-01-01
The correlation energies of various atoms in their excited-states are estimated by modelling the Coulomb hole following the previous work by Chakravorty and Clementi. The parameter in the model is fixed by making the corresponding Coulomb hole to satisfy the exact constraint of charge neutrality.
Size dependent deactivation of the excited state of DHICA
DEFF Research Database (Denmark)
Gauden, Magdalena; Pezzella, Alessandro; Panzella, Lucia;
2008-01-01
Melanin is a natural pigment mainly responsible for the protection of skin and eyes from UV damage. 5,6- dihydroxyindole- 2 carboxylic acid (DHICA) is a key melanin building block. We have investigated the excited state dynamics of DHICA as well as its derivatives and oligomeric units using...
Lowest energy excited singlet state of isolated cis-hexatriene
Kohler, B.E.; Song, K.; Buma, W.J.
1991-01-01
In a previous letter [J. Chem. Phys. 92, 4622 (1990)] we reported the first observation of the 2 1Ag state of cis-hexatriene in a supersonic jet expansion by using resonance enhanced multiphoton ionization spectroscopy. Here, the vibrational analysis of the 1 1Ag2 1Ag excitation spectrum of cis-hexa
Excited-state quantum phase transition in the Rabi model
Puebla, Ricardo; Hwang, Myung-Joong; Plenio, Martin B.
2016-08-01
The Rabi model, a two-level atom coupled to a harmonic oscillator, can undergo a second-order quantum phase transition (QPT) [M.-J. Hwang et al., Phys. Rev. Lett. 115, 180404 (2015), 10.1103/PhysRevLett.115.180404]. Here we show that the Rabi QPT accompanies critical behavior in the higher-energy excited states, i.e., the excited-state QPT (ESQPT). We derive analytic expressions for the semiclassical density of states, which show a logarithmic divergence at a critical energy eigenvalue in the broken symmetry (superradiant) phase. Moreover, we find that the logarithmic singularities in the density of states lead to singularities in the relevant observables in the system such as photon number and atomic polarization. We corroborate our analytical semiclassical prediction of the ESQPT in the Rabi model with its numerically exact quantum mechanical solution.
Optimized resonating valence bond state in square lattice: correlations & excitations
Directory of Open Access Journals (Sweden)
Z Nourbakhsh
2009-09-01
Full Text Available We consider RVB state as a variational estimate for the ground state of Heisenberg antiferromagnet in square lattice. We present numerical calculation of energy, spin-spin correlation function and spin excitation spectrum. We show, that the quantum flactuations reduce of magnetization respect to Neel order. Our results are in good agreement with other methods such as spin-wave calculation and series expansions.
String Models for the Heavy Quark-Antiquark Bound States.
Tse, Sze-Man
1988-12-01
The heavy quark-antiquark bound state is examined in the phenomenological string models. Specifically, the Nambu-Goto model and the Polyakov's smooth string model are studied in the large-D limit, D being the number of transverse space-time dimensions. The static potential V(R) is extracted in both models in the large-D limit. In the former case, this amounts to the usual saddle point calculation. In the latter case, the renormalized, physical string tension is expressed in terms of the bare string tension and the extrinsic curvature coupling. A systematic loop expansion of V(R) is developed and carried out explicitly to one loop order, with the two loops result presented without detail. For large separations R, the potential is linear in R with corrections of order 1/R. The coefficient of the 1/R Luscher term has the universal value -piD/24 to any finite order in the loop expansion. For very small separations R, the potential V(R) is also proportional to 1/R with a coefficient twice that of Luscher's term. The corrections are logarithmically small. Polyakov's smooth string model is extended to the finite temperature situation. The temperature dependence of the string tension is investigated in the large-D limit. The effective string tension is calculated to the second order in the loop expansion. At low temperature, it differs from that of the Nambu-Goto model only by terms that fall exponentially with inverse temperature. Comparison of the potential V(R) in the smooth string model with lattice gauge calculation and hadron spectroscopy data yields a consistent result.
On the excited-state multi-dimensionality in cyanines
Dietzek, Benjamin; Brüggemann, Ben; Persson, Petter; Yartsev, Arkady
2008-03-01
Vibrational coherences in a photoexcited cyanine dye are preserved for the time-scale of diffusive torsional motion to the bottom of the excited-state potential. The coherently excited modes are virtually unaffected by solvent friction and thus distinct from the bond-twisting motion, which is strongly coupled to the surrounding solvent. We correlate the modes apparent in the resonance Raman and the four-wave mixing signal of 1,1'-diethyl-2,2'-cyanine with the understanding of optimal control of isomerization. In turn, the experimental results illustrate that optimal control might be used to obtain vibrational information complementary to conventional spectroscopic data.
Parity lifetime of bound states in a proximitized semiconductor nanowire
DEFF Research Database (Denmark)
Higginbotham, Andrew Patrick; Albrecht, Sven Marian; Kirsanskas, Gediminas;
2015-01-01
Quasiparticle excitations can compromise the performance of superconducting devices, causing high frequency dissipation, decoherence in Josephson qubits, and braiding errors in proposed Majorana-based topological quantum computers. Quasiparticle dynamics have been studied in detail in metallic...
Sub-50 fs excited state dynamics of 6-chloroguanine upon deep ultraviolet excitation.
Mondal, Sayan; Puranik, Mrinalini
2016-05-18
The photophysical properties of natural nucleobases and their respective nucleotides are ascribed to the sub-picosecond lifetime of their first singlet states in the UV-B region (260-350 nm). Electronic transitions of the ππ* type, which are stronger than those in the UV-B region, lie at the red edge of the UV-C range (100-260 nm) in all isolated nucleobases. The lowest energetic excited states in the UV-B region of nucleobases have been investigated using a plethora of experimental and theoretical methods in gas and solution phases. The sub-picosecond lifetime of these molecules is not a general attribute of all nucleobases but specific to the five primary nucleobases and a few xanthine and methylated derivatives. To determine the overall UV photostability, we aim to understand the effect of more energetic photons lying in the UV-C region on nucleobases. To determine the UV-C initiated photophysics of a nucleobase system, we chose a halogen substituted purine, 6-chloroguanine (6-ClG), that we had investigated previously using resonance Raman spectroscopy. We have performed quantitative measurements of the resonance Raman cross-section across the Bb absorption band (210-230 nm) and constructed the Raman excitation profiles. We modeled the excitation profiles using Lee and Heller's time-dependent theory of resonance Raman intensities to extract the initial excited state dynamics of 6-ClG within 30-50 fs after photoexcitation. We found that imidazole and pyrimidine rings of 6-ClG undergo expansion and contraction, respectively, following photoexcitation to the Bb state. The amount of distortions of the excited state structure from that of the ground state structure is reflected by the total internal reorganization energy that is determined at 112 cm(-1). The contribution of the inertial component of the solvent response towards the total reorganization energy was obtained at 1220 cm(-1). In addition, our simulation also yields an instantaneous response of the first
MULTIPLY CHARGED IONS COLLISIONS WITH ATOMS INTO EXCITED STATES
Institute of Scientific and Technical Information of China (English)
PanGuangyan
1990-01-01
The emission spectra in collisions between Ions and Atoms have been measured by an Optical Multichannel Analysis System (OMA).The experimental results demonstrate that there are two channels of excitation in collision between single charged ions and atoms and three channels of excitation in collision between double charged ions and atoms.Emission cross cestions and excitation cross sections have been obtained.K.Kadota et al and R.Shingal et al suggested that,under the appropriate conditions,the H42+-Li and He2++Na collision systems can be used efficiently to produce a laser of Lyman-α(30,4nm) and Lyman-β(25.6nm)lines via cascade to He+(2P)state.
Observation of the First Excited State in 23O
Frank, N; Baumann, T; Bazin, D; Brown, J; DeYoung, P A; Finck, J E; Gade, A; Hinnefeld, J; Howes, R; Lecouey, J -L; Luther, B; Peters, W A; Scheit, H; Thoennessen, M
2007-01-01
The first excited state in neutron-rich 23O was observed in a (2p1n) knock-out reaction from 26Ne on a beryllium target at a beam energy of 86 MeV/A. The state is unbound with respect to neutron emission and was reconstructed from the invariant mass from the 22O fragment and the neutron. It is unbound by 45(2) keV corresponding to an excitation energy of 2.8(1) MeV. The non-observation of further resonances implies a predominantly direct reaction mechanism of the employed three-nucleon-removal reaction which suggests the assignment of the observed resonance to be the 5/2+ hole state.
Optical nanoscopy with excited state saturation at liquid helium temperatures
Yang, B.; Trebbia, J.-B.; Baby, R.; Tamarat, Ph.; Lounis, B.
2015-10-01
Optical resolution of solid-state single quantum emitters at the nanometre scale is a challenging step towards the control of delocalized states formed by strongly and coherently interacting emitters. We have developed a simple super-resolution optical microscopy method operating at cryogenic temperatures, which is based on optical saturation of the excited state of single fluorescent molecules with a doughnut-shaped beam. Sub-10 nm resolution is achieved with extremely low excitation intensities, a million times lower than those used in room-temperature stimulated emission depletion microscopy. Compared with super-localization approaches, our technique offers a unique opportunity to super-resolve single molecules with overlapping optical resonance frequencies and paves the way to the study of coherent interactions between single emitters and to the manipulation of their degree of entanglement.
Controlling Excited-State Contamination in Nucleon Matrix Elements
Yoon, Boram; Bhattacharya, Tanmoy; Engelhardt, Michael; Green, Jeremy; Joó, Bálint; Lin, Huey-Wen; Negele, John; Orginos, Kostas; Pochinsky, Andrew; Richards, David; Syritsyn, Sergey; Winter, Frank
2016-01-01
We present a detailed analysis of methods to reduce statistical errors and excited-state contamination in the calculation of matrix elements of quark bilinear operators in nucleon states. All the calculations were done on a 2+1 flavor ensemble with lattices of size $32^3 \\times 64$ generated using the rational hybrid Monte Carlo algorithm at $a=0.081$~fm and with $M_\\pi=312$~MeV. The statistical precision of the data is improved using the all-mode-averaging method. We compare two methods for reducing excited-state contamination: a variational analysis and a two-state fit to data at multiple values of the source-sink separation $t_{\\rm sep}$. We show that both methods can be tuned to significantly reduce excited-state contamination and discuss their relative advantages and cost-effectiveness. A detailed analysis of the size of source smearing used in the calculation of quark propagators and the range of values of $t_{\\rm sep}$ needed to demonstrate convergence of the isovector charges of the nucleon to the $t_...
Controlling excited-state contamination in nucleon matrix elements
Energy Technology Data Exchange (ETDEWEB)
Yoon, Boram; Gupta, Rajan; Bhattacharya, Tanmoy; Engelhardt, Michael; Green, Jeremy; Joó, Bálint; Lin, Huey-Wen; Negele, John; Orginos, Kostas; Pochinsky, Andrew; Richards, David; Syritsyn, Sergey; Winter, Frank
2016-06-01
We present a detailed analysis of methods to reduce statistical errors and excited-state contamination in the calculation of matrix elements of quark bilinear operators in nucleon states. All the calculations were done on a 2+1 flavor ensemble with lattices of size $32^3 \\times 64$ generated using the rational hybrid Monte Carlo algorithm at $a=0.081$~fm and with $M_\\pi=312$~MeV. The statistical precision of the data is improved using the all-mode-averaging method. We compare two methods for reducing excited-state contamination: a variational analysis and a two-state fit to data at multiple values of the source-sink separation $t_{\\rm sep}$. We show that both methods can be tuned to significantly reduce excited-state contamination and discuss their relative advantages and cost-effectiveness. A detailed analysis of the size of source smearing used in the calculation of quark propagators and the range of values of $t_{\\rm sep}$ needed to demonstrate convergence of the isovector charges of the nucleon to the $t_{\\rm sep} \\to \\infty $ estimates is presented.
Excited state dynamics of the astaxanthin radical cation
Amarie, Sergiu; Förster, Ute; Gildenhoff, Nina; Dreuw, Andreas; Wachtveitl, Josef
2010-07-01
Femtosecond transient absorption spectroscopy in the visible and NIR and ultrafast fluorescence spectroscopy were used to examine the excited state dynamics of astaxanthin and its radical cation. For neutral astaxanthin, two kinetic components corresponding to time constants of 130 fs (decay of the S 2 excited state) and 5.2 ps (nonradiative decay of the S 1 excited state) were sufficient to describe the data. The dynamics of the radical cation proved to be more complex. The main absorption band was shifted to 880 nm (D 0 → D 3 transition), showing a weak additional band at 1320 nm (D 0 → D 1 transition). We found, that D 3 decays to the lower-lying D 2 within 100 fs, followed by a decay to D 1 with a time constant of 0.9 ps. The D 1 state itself exhibited a dual behavior, the majority of the population is transferred to the ground state in 4.9 ps, while a small population decays on a longer timescale of 40 ps. Both transitions from D 1 were found to be fluorescent.
Controlling excited-state contamination in nucleon matrix elements
Yoon, Boram; Gupta, Rajan; Bhattacharya, Tanmoy; Engelhardt, Michael; Green, Jeremy; Joó, Bálint; Lin, Huey-Wen; Negele, John; Orginos, Kostas; Pochinsky, Andrew; Richards, David; Syritsyn, Sergey; Winter, Frank; Nucleon Matrix Elements NME Collaboration
2016-06-01
We present a detailed analysis of methods to reduce statistical errors and excited-state contamination in the calculation of matrix elements of quark bilinear operators in nucleon states. All the calculations were done on a 2 +1 -flavor ensemble with lattices of size 323×64 generated using the rational hybrid Monte Carlo algorithm at a =0.081 fm and with Mπ=312 MeV . The statistical precision of the data is improved using the all-mode-averaging method. We compare two methods for reducing excited-state contamination: a variational analysis and a 2-state fit to data at multiple values of the source-sink separation tsep. We show that both methods can be tuned to significantly reduce excited-state contamination and discuss their relative advantages and cost effectiveness. A detailed analysis of the size of source smearing used in the calculation of quark propagators and the range of values of tsep needed to demonstrate convergence of the isovector charges of the nucleon to the tsep→∞ estimates is presented.
Reexamination of the excited states of C12
Freer, M.; Boztosun, I.; Bremner, C. A.; Chappell, S. P. G.; Cowin, R. L.; Dillon, G. K.; Fulton, B. R.; Greenhalgh, B. J.; Munoz-Britton, T.; Nicoli, M. P.; Rae, W. D. M.; Singer, S. M.; Sparks, N.; Watson, D. L.; Weisser, D. C.
2007-09-01
An analysis of the C12(C12,3α)C12 reaction was made at beam energies between 82 and 106 MeV. Decays to both the ground state and the excited states of Be8 were isolated, allowing states of different characters to be identified. In particular, evidence was found for a previously observed state at 11.16 MeV. An analysis of the angular distributions of the unnatural parity states at 11.83 and 13.35 MeV, previously assigned Jπ=2-, calls into question the validity of these assignments, suggesting that at least one of the states may correspond to Jπ=4-. Evidence is also found for 1- and 3- strengths associated with broad states between 11 and 14 MeV.
Photoactivated excited states of DNA repair photolyase: Dynamical and semiempircal identification
Zheng, Xuehe; Ly, Ngan M.; Stuchebrukhov, Alexei A.
DNA damage caused by UV light radiation is often naturally repaired in a process initiated by excited state electron transfer from the photoactivated photolyase enzyme to the DNA cyclobutane pyrimidine dimer lesion. The active cofactor in the excited state electron transfer in the photolyase is the two-electron fully reduced form of the flavin adenine dinucleotide (FADH-). To calculate electron tunneling matrix element and model the DNA binding with photolyase, the LUMO of the FADH- calculated using extended Huckel method was previously chosen from the SCF wavefunctions. Recently, the DNA-photolyase complex was crystallized in its bound form, in good agreement with our previous model in even minute details at the active site. Here we carry out molecular dynamics simulation of the entire complex using the new experimental structure of Anacystis nidulans and identify the low-lying photoactivated states of the enzyme for the dynamical confirmations. Our results from ZINDO/S CIS calculations are compared with experimental UV spectra, and their implications for excited state electron transfer and energy transfer are discussed.0
Negative-parity nucleon excited state in nuclear matter
Ohtani, Keisuke; Gubler, Philipp; Oka, Makoto
2016-10-01
Spectral functions of the nucleon and its negative-parity excited state in nuclear matter are studied by using QCD sum rules and the maximum entropy method (MEM). It is found that in-medium modifications of the spectral functions are attributed mainly to density dependencies of the and condensates. The MEM reproduces the lowest-energy peaks of both the positive- and negative-parity nucleon states at finite density up to ρ ˜ρN (normal nuclear matter density). As the density grows, the residue of the nucleon ground state decreases gradually while the residue of the lowest negative-parity excited state increases slightly. On the other hand, the positions of the peaks, which correspond to the total energies of these states, are almost density independent for both parity states. The density dependencies of the effective masses and vector self-energies are also extracted by assuming phenomenological mean-field-type propagators for the peak states. We find that, as the density increases, the nucleon effective mass decreases while the vector self-energy increases. The density dependence of these quantities for the negative-parity state on the other hand turns out to be relatively weak.
Lifetimes and structure of excited states of 115Sb
Lobach, Yu. N.; Bucurescu, D.
1998-06-01
Lifetimes of excited states of 115Sb were measured by the Doppler shift attenuation method in the (α,2nγ) reaction at Eα = 27.2 MeV. The experimental level scheme and the electromagnetic transition probabilities have been interpreted in terms of the interacting boson-fermion model. A reasonable agreement with the experiment was obtained for the positive-parity states. The experimental data also show the applicability of the cluster-vibrational model for the mixing of two 9/2+ states having different intrinsic configurations.
Controlling autoionization in strontium two-electron-excited states
Fields, Robert; Zhang, Xinyue; Dunning, F. Barry; Yoshida, Shuhei; Burgdörfer, Joachim
2016-05-01
One challenge in engineering long-lived two-electron-excited states, i.e., so-called planetary atoms, is autoionization. Autoionization, however, can be suppressed if the outermost electron is placed in a high- n, n ~ 300 - 600 , high- L state because such states have only a very small overlap with the inner electron, even when this is also excited to a state of relatively high n and hence of relatively long lifetime. Here the L-dependence of the autoionization rate for high- n strontium Rydberg atoms is examined during excitation of the core ion 5 s 2S1 / 2 - 5 p 2P3 / 2 transition. Measurements in which the angular momentum of the Rydberg electron is controlled using a pulsed electric field show that the autoionization rate decreases rapidly with increasing L and becomes very small for values larger than ~ 20 . The data are analyzed with the aid of calculations undertaken using complex scaling. Research supported by the NSF and Robert A. Welch Foundation.
Trilinear couplings and scalar bound states in supersymmetric extensions of the standard model
Hernández, Pilar; Sanz, V
2001-01-01
The trilinear terms in minimal supersymmetric extensions of the standard model can be responsible of forming a bound state of scalars. In this talk we outline our results on the study of this bound state using a non-perturbative method, the exact renormalization group. We focus on the trilinear term between the Higgs and stop fields. (4 refs).
The Bethe ansatz for AdS5 × S5 bound states
de Leeuw, M.
2009-01-01
We reformulate the nested coordinate Bethe ansatz in terms of coproducts of Yangian symmetry generators. This allows us to derive the nested Bethe equations for arbitrary bound state string S-matrices. The bound state number dependence in the Bethe equations appears through the parameters x± and the
Bound states for fermions in the gauge Aharonov-Bohm field
Energy Technology Data Exchange (ETDEWEB)
Voropaev, S.A.; Galtsov, D.V.; Spasov, D.A. (Dept. of Theoretical Physics, Moscow State Univ. (USSR))
1991-09-05
In this paper we discuss some interesting properties of the Aharonov-Bohm interaction for relativistic spin-one-half particles. We will show that the AB potential is powerful enough to create bound states. We will then discuss the wave function, spin-coefficients and the energy level for the bound states of the fermions in the gauge AB field. (orig.).
The bound state S-matrix for AdS5×S5 superstring
Arutyunov, G.E.; de Leeuw, M.; Torrielli, A.
2009-01-01
We determine the S-matrix that describes scattering of arbitrary bound states in the light-cone string theory in AdS5×S5. The corresponding construction relies on the Yangian symmetry and the superspace formalism for the bound state representations. The basic analytic structure supporting the S-matr
The electronic excited states of green fluorescent protein chromophore models
Olsen, Seth Carlton
We explore the properties of quantum chemical approximations to the excited states of model chromophores of the green fluorescent protein of A. victoria. We calculate several low-lying states by several methods of quantum chemical calculation, including state-averaged complete active space SCF (CASSCF) methods, time dependent density functional theory (TDDFT), equation-of motion coupled cluster (EOM-CCSD) and multireference perturbation theory (MRPT). Amongst the low-lying states we identify the optically bright pipi* state of the molecules and examine its properties. We demonstrate that the state is dominated by a single configuration function. We calculate zero-time approximations to the resonance Raman spectrum of GFP chromophore models, and assign published spectra based upon these.
Ensemble-based characterization of unbound and bound states on protein energy landscape
Ruvinsky, Anatoly M; Tuzikov, Alexander V; Vakser, Ilya A
2012-01-01
Characterization of protein energy landscape and conformational ensembles is important for understanding mechanisms of protein folding and function. We studied ensembles of bound and unbound conformations of six proteins to explore their binding mechanisms and characterize the energy landscapes in implicit solvent. First, results show that bound and unbound spectra often significantly overlap. Moreover, the larger the overlap the smaller the RMSD between bound and unbound conformational ensembles. Second, the analysis of the unbound-to-bound changes points to conformational selection as the binding mechanism for four of the proteins. Third, the center of the unbound spectrum has a higher energy than the center of the corresponding bound spectrum of the dimeric and multimeric states for most of the proteins. This suggests that the unbound states often have larger entropy than the bound states considered outside of the complex. Fourth, the exhaustively long minimization, making small intra-rotamer adjustments, ...
Negative-parity nucleon excited state in nuclear matter
Ohtani, Keisuke; Oka, Makoto
2016-01-01
Spectral functions of the nucleon and its negative parity excited state in nuclear matter are studied using QCD sum rules and the maximum entropy method (MEM). It is found that in-medium modifications of the spectral functions are attributed mainly to density dependencies of the $\\langle \\bar{q}q \\rangle $ and $\\langle q^{\\dagger}q \\rangle $ condensates. The MEM reproduces the lowest-energy peaks of both the positive and negative parity nucleon states at finite density up to $\\rho \\sim \\rho_N$ (normal nuclear matter density). As the density grows, the residue of the nucleon ground state decreases gradually while the residue of the lowest negative parity excited state increases slightly. On the other hand, the positions of the peaks, which correspond to the total energies of these states, are almost density independent for both parity states. The density dependencies of the effective masses and vector self-energies are also extracted by assuming the mean-field green functions for the peak states. We find that,...
On the nature of highly vibrationally excited states of Thiophosgene
Keshavamurthy, Srihari
2011-01-01
In this work an analysis of the highly vibrationally excited states of thiophosgene (SCCl$_{2}$) is made in order to gain insights into some of the experimental observations and spectral features. The states analyzed herein lie in a spectrally complex region where strong mode mixings are expected due to the overlap of several strong anharmonic Fermi resonances. Two recent techniques, a semiclassical angle space representation of the eigenstates and the parametric variation of the eigenvalues (level-velocities) are used to identify eigenstate sequences exhibiting common localization characteristics. Preliminary results on the influence of highly excited out-of-plane bending modes on the nature of the eigenstates suggest a possible bifurcation in the system.
On the nature of highly vibrationally excited states of thiophosgene
Indian Academy of Sciences (India)
Srihari Keshavamurthy
2012-01-01
In this work an analysis of the highly vibrationally excited states of thiophosgene (SCCl2) is made in order to gain insights into some of the experimental observations and spectral features. The states analysed here lie in a spectrally complex region where strong mode mixings are expected due to the overlap of several strong anharmonic Fermi resonances. Two recent techniques, a semiclassical angle space representation of the eigenstates and the parametric variation of the eigenvalues (level-velocities) are used to identify eigenstate sequences exhibiting common localization characteristics. Preliminary results on the influence of highly excited out-of-plane bending modes on the nature of the eigenstates suggest a possible bifurcation in the system.
Precision study of excited state effects in nucleon matrix elements
Energy Technology Data Exchange (ETDEWEB)
Dinter, Simon; Drach, Vincent; Jansen, Karl; Renner, Dru B. [Deutsches Elektronen-Synchrotron (DESY), Zeuthen (Germany). John von Neumann-Inst. fuer Computing NIC; Alexandrou, Constantia [Cyprus Univ., Nicosia (Cyprus). Dept. of Physics; The Cyprus Insitute, Nicosia (Cyprus). Computation-Based Science and Technology Research Center; Constantinou, Martha [Cyprus Univ., Nicosia (Cyprus). Dept. of Physics
2011-08-15
We present a dedicated analysis of the influence of excited states on the calculation of nucleon matrix elements. This calculation is performed at a fixed value of the lattice spacing, volume and pion mass that are typical of contemporary lattice computations. We focus on the nucleon axial charge, g{sub A}, for which we use about 7,500 measurements, and on the average momentum of the unpolarized isovector parton distribution, left angle x right angle {sub u-d}, for which we use about 23,000 measurements. All computations are done employing N{sub f}=2+1+1 maximally-twisted-mass Wilson fermions and using nonperturbatively calculated renormalization factors. Excited state e ects are shown to be negligible for g{sub A}, whereas they lead to an O(10%) downward shift for left angle x right angle {sub u-d}. (orig.)
The effects of doubly excited states on ionization balance
Institute of Scientific and Technical Information of China (English)
无
2006-01-01
The effects of highly doubly excited states on ionization balance are investigated. In the calculation, A Collisional-Radiative model in Detailed-Configuration-Accounting (DCA) is applied to population calculations for NLTE plasmas. Configuration-averaged rate coefficients that needed in the rate equations are obtained based on the first order perturbation theory. The Hatree-Fock-Slater self-consistent-field method is used to calculate the electron wave functions. The mean ionization stage of high-Z plasma Lu is presented. The comparison shows that the mean ionization stage increases more than 3 stages when doubly excited states 5l6l' and 5l5l' are not included in the population calculations.
Stark spectrum of barium in highly excited Rydberg states
Institute of Scientific and Technical Information of China (English)
Yang Hai-Feng; Gao Wei; Cheng Hong; Liu Xiao-Jun; Liu Hong-Ping
2013-01-01
We present observations of Stark spectra of barium in highly excited Rydberg states in the energy region around n =35.The one-photon excitation concerns the π transition.The observed Stark spectra at electric fields ranging from 0 to 60 V·cm-1 are well explained by the diagonalization of the Hamiltonian incorporating the core effects.From the Stark maps,the anti-crossings between energy levels are identified experimentally and theoretically.The time of flight spectra at the specified Stark states are recorded,where the deceleration and acceleration of barium atoms are observed.This is very consistent with the prediction derived from the Stark maps from the point of view of energy conservation.
Ndangali, Friends R
2010-01-01
Electromagnetic bound states in the radiation continuum are studied for periodic double arrays of subwavelength dielectric cylinders in TM polarization. They are similar to localized waveguide mode solutions of Maxwell's equations for metal cavities or defects of photonic crystals, but, in contrast to the latter, their spectrum lies in the radiation continuum. The phenomenon is identical to the existence of bound sates in the radiation continuum in quantum mechanics, discovered by von Neumann and Wigner. In the formal scattering theory, these states appear as resonances with the vanishing width. For the system studied, the bound states are shown to exist at specific distances between the arrays in the spectral region where one or two diffraction channels are open. Analytic solutions are obtained for all bound states (below the radiation continuum and in it) in the limit of thin cylinders (the cylinder radius is much smaller than the wavelength). The existence of bound states is also established in the spectra...
Nonlinear Optical Spectroscopy of Excited States in Polyfluorene
Tong, M; Vardeny, Z V
2006-01-01
We used a variety of nonlinear optical (NLO) spectroscopies to study the singlet excited states order, and primary photoexcitations in polyfluorene; an important blue emitting p-conjugated polymer. The polarized NLO spectroscopies include ultrafast pump-probe photomodulation, two-photon absorption, and electroabsorption. For completeness we also measured the linear absorption and photoluminescence spectra. We found that the primary photoexcitations in polyfluorene are singlet excitons.
Excited states in large molecular systems through polarizable embedding
DEFF Research Database (Denmark)
List, Nanna Holmgaard; Olsen, Jógvan Magnus Haugaard; Kongsted, Jacob
2016-01-01
In this perspective, we provide an overview of recent work within the polarizable embedding scheme to describe properties of molecules in realistic environments of increasing complexity. After an outline of the theoretical basis for the polarizable embedding model, we discuss the importance of us...... theory. We finally discuss aspects related to two recent extensions of the model (i) effective external field and (ii) polarizable density embedding emphasizing their importance for efficient yet accurate description of excited-state properties in complex environments....
First observation of excited states in 173Hg93
O'Donnell, D; Scholey, C; Bianco, L; Capponi, L; Carroll, R J; Darby, I G; Donosa, L; Drummond, M; Ertugral, F; Greenlees, P T; Grahn, T; Hauschild, K; Herzan, A; Jakobsson, U; Jones, P; Joss, D T; Julin, R; Juutinen, S; Ketelhut, S; Labiche, M; Leino, M; Lopez-Martens, A; Mullholland, K; Nieminen, P; Peura, P; Rahkila, P; Rinta-Antila, S; Ruotsalainen, P; Sandzelius, M; Saren, J; Saygi, B; Simpson, J; Sorri, J; Thornthwaite, A; Uusitalo, J
2012-01-01
The neutron-deficient nucleus 173Hg has been studied following fusion-evaporation reactions. The observation of gamma rays decaying from excited states are reported for the first time and a tentative level scheme is proposed. The proposed level scheme is discussed within the context of the systematics of neighbouring neutron-deficient Hg nuclei. In addition to the gamma-ray spectroscopy, the alpha decay of this nucleus has been measured yielding superior precision to earlier measurements.
Low-Lying ππ* States of Heteroaromatic Molecules: A Challenge for Excited State Methods.
Prlj, Antonio; Sandoval-Salinas, María Eugenia; Casanova, David; Jacquemin, Denis; Corminboeuf, Clémence
2016-06-14
The description of low-lying ππ* states of linear acenes by standard electronic structure methods is known to be challenging. Here, we broaden the framework of this problem by considering a set of fused heteroaromatic rings and demonstrate that standard electronic structure methods do not provide a balanced description of the two (typically) lowest singlet state (La and Lb) excitations. While the Lb state is highly sensitive to correlation effects, La suffers from the same drawbacks as charge transfer excitations. We show that the comparison between CIS/CIS(D) can serve as a diagnostic for detecting the two problematic excited states. Standard TD-DFT and even its spin-flip variant lead to inaccurate excitation energies and interstate gaps, with only a double hybrid functional performing somewhat better. The complication inherent to a balanced description of these states is so important that even CC2 and ADC(2) do not necessarily match the ADC(3) reference.
Interacting quantum walkers: two-body bosonic and fermionic bound states
Krapivsky, P. L.; Luck, J. M.; Mallick, K.
2015-11-01
We investigate the dynamics of bound states of two interacting particles, either bosons or fermions, performing a continuous-time quantum walk on a one-dimensional lattice. We consider the situation where the distance between both particles has a hard bound, and the richer situation where the particles are bound by a smooth confining potential. The main emphasis is on the velocity characterizing the ballistic spreading of these bound states, and on the structure of the asymptotic distribution profile of their center-of-mass coordinate. The latter profile generically exhibits many internal fronts.
Formation of bound states in expanded metal studied via path integral molecular dynamics
Deymier, P. A.; Oh, Ki-Dong
2004-03-01
The usefulness of the restricted path integral molecular dynamics method for the study of strongly correlated electrons is demonstrated by studying the formation of bound electronic states in a half-filled expanded three-dimensional hydrogenoid body-centred cubic lattice at finite temperature. Starting from a metallic state with one-component plasma character, we find that bound electrons form upon expansion of the lattice. The bound electrons are spatially localized with their centre for the motion of gyration located at ionic positions. The number of bound electrons increases monotonically with decreasing density.
Quasi-bound states, resonance tunnelling, and tunnelling times generated by twin symmetric barriers
Indian Academy of Sciences (India)
A Uma Maheswari; P Prema; S Mahadevan; C S Shastry
2009-12-01
In analogy with the definition of resonant or quasi-bound states used in three-dimensional quantal scattering, we define the quasi-bound states that occur in one-dimensional transmission generated by twin symmetric potential barriers and evaluate their energies and widths using two typical examples: (i) twin rectangular barrier and (ii) twin Gaussian-type barrier. The energies at which reflectionless transmission occurs correspond to these states and the widths of the transmission peaks are also the same as those of quasi-bound states. We compare the behaviour of the magnitude of wave functions of quasi-bound states with those for bound states and with the above-barrier state wave function. We deduce a Breit–Wigner-type resonance formula which neatly describes the variation of transmission coefficient as a function of energy at below-barrier energies. Similar formula with additional empirical term explains approximately the peaks of transmission coefficients at above-barrier energies as well. Further, we study the variation of tunnelling time as a function of energy and compare the same with transmission, reflection time and Breit–Wigner delay time around a quasi-bound state energy. We also find that tunnelling time is of the same order of magnitude as lifetime of the quasi-bound state, but somewhat larger.
The maximal Lyapunov exponent of a co-dimension two-bifurcation system excited by a bounded noise
Institute of Scientific and Technical Information of China (English)
Sheng-Hong Li; Xian-Bin Liu
2012-01-01
In the present paper,the maximal Lyapunov exponent is investigated for a co-dimension two bifurcation system that is on a three-dimensional central manifold and subjected to parametric excitation by a bounded noise.By using a perturbation method,the expressions of the invariant measure of a one-dimensional phase diffusion process are obtained for three cases,in which different forms of the matrix B,that is included in the noise excitation term,are assumed and then,as a result,all the three kinds of singular boundaries for one-dimensional phase diffusion process are analyzed.Via Monte-Carlo simulation,we find that the analytical expressions of the invariant measures meet well the numerical ones.And furthermore,the P-bifurcation behaviors are investigated for the one-dimensional phase diffusion process.Finally,for the three cases of singular boundaries for one-dimensional phase diffusion process,analytical expressions of the maximal Lyapunov exponent are presented for the stochastic bifurcation system.
Féraud, Géraldine; Broquier, Michel; Dedonder, Claude; Jouvet, Christophe; Grégoire, Gilles; Soorkia, Satchin
2015-06-11
The electronic spectroscopy and the electronic excited state properties of cold protonated phenylalanine and protonated tyrosine have been revisited on a large spectral domain and interpreted by comparison with ab initio calculations. The protonated species are stored in a cryogenically cooled Paul trap, maintained at ∼10 K, and the parent and all the photofragment ions are mass-analyzed in a time-of-flight mass spectrometer, which allows detecting the ionic species with an improved mass resolution compared to what is routinely achieved with a quadrupole mass spectrometer. These new results emphasize the competition around the band origin between two proton transfer reactions from the ammonium group toward either the aromatic chromophore or the carboxylic acid group. These reactions are initiated by the coupling of the locally excited ππ* state with higher charge transfer states, the positions and coupling of which depend on the conformation of the protonated molecules. Each of these reaction processes gives rise to specific fragmentation channels that supports the conformer selectivity observed in the photofragmentation spectra of protonated tyrosine and phenylalanine.
Unnatural parity resonance states in positron-excited hydrogen scattering
Institute of Scientific and Technical Information of China (English)
Ma Jia; Zhou Ya-Jun; Wang Yuan-Cheng
2012-01-01
The coupled-channels optical method for positron scattering has been applied to investigate resonance states with unnatural parities in a positron-excited hydrogen system.The positronium formation channels and continuum channel are included via a complex equivalent local potential.Resonance states with angular momenta L =1 to L =2 and parities (-1)L+1 are calculated.Resonance energies and widths are reported and compared with other theoretical calculations.We found that the opening positronium formation channels play an important role in forming nondipole Feshbach resonances.
Modular Hamiltonian for Excited States in Conformal Field Theory.
Lashkari, Nima
2016-07-22
We present a novel replica trick that computes the relative entropy of two arbitrary states in conformal field theory. Our replica trick is based on the analytic continuation of partition functions that break the Z_{n} replica symmetry. It provides a method for computing arbitrary matrix elements of the modular Hamiltonian corresponding to excited states in terms of correlation functions. We show that the quantum Fisher information in vacuum can be expressed in terms of two-point functions on the replica geometry. We perform sample calculations in two-dimensional conformal field theories.
Modular Hamiltonian of Excited States in Conformal Field Theory
Lashkari, Nima
2015-01-01
We present a novel replica trick that computes the relative entropy of two arbitrary states in conformal field theory. Our replica trick is based on the analytic continuation of partition functions that break the replica Z_n symmetry. It provides a method for computing arbitrary matrix elements of the modular Hamiltonian corresponding to excited states in terms of correlation functions. We show that the quantum Fisher information in vacuum can be expressed in terms of two-point functions on the replica geometry. We perform sample calculations in two-dimensional conformal field theories.
The investigation of interactions in the excited state of flavins using time-resolved spectroscopy
Visser, A.J.W.G.
1975-01-01
In paper I the results obtained with a very short (3 nsec) intense laser pulse as excitation source are described. This pulse excites such a large amount of flavin molecules into higher excited singlet and triplet states that changes in absorption of these higher excited states can be analyzed with
Indirect predissociation of highly excited singlet states of N2
Directory of Open Access Journals (Sweden)
Heays A.N.
2015-01-01
Full Text Available Indirect predissociation of the b′ 1Σu+(v = 20 level of N2 is studied experimentally by vacuum-ultraviolet photoabsorption employing synchrotron radiation and a Fourier-transform spectrometer, and interpreted with the aid of a quantitative model of interacting 1Πu and 1Σu+, bound and unbound states which solves the coupled Schrödinger equation. An observed rotationally-localised peak in the b′(20 predissociation linewidths is identified by the model as arising from an interaction with a strongly predissociated and unobserved bound level of the mixed c3 1Πu and o3 1Πu Rydberg states. This leads to the dissociation of b′(20 into the continuum of the b 1Πu valence state. The residual observed predissociation of b′ 1Σu+(v = 20 apart from the rotationally-localised peak cannot be explained by a mechanism of 1Πu and 1Σu+ interaction, and must involve states of higher multiplicity.
Electron-electron bound states in Maxwell-Chern-Simons-Proca QED{sub 3}
Energy Technology Data Exchange (ETDEWEB)
Belich, H.; Helayel-Neto, J.A. [Grupo de Fisica Teorica Jose Leite Lopes, Petropolis, RJ (Brazil)]|[Centro Brasileiro de Pesquisas Fisicas (CBPF), Rio de Janeiro, RJ (Brazil). Coordenacao de Teoria de Campos e Particulas]. E-mail: belich@cbpf.br; helayel@gft.ucp.br; Del Cima, O.M. [Grupo de Fisica Teorica Jose Leite Lopes, Petropolis, RJ (Brazil)]. E-mail: delcima@gft.ucp.br; Ferreira, M.M. Jr. [Grupo de Fisica Teorica Jose Leite Lopes, Petropolis, RJ (Brazil)]|[Maranhao Univ., Sao Luis, MA (Brazil). Dept. de Fisica]. E-mail: manojr@cbpf.br
2002-10-01
We start from a parity-breaking MCS QED{sub 3} model with spontaneous breaking of the gauge symmetry as a framework for evaluation of the electron-electron interaction potential and for attainment of numerical values for the e{sup -}e{sup -} - bound state. Three expressions (V{sub eff{down_arrow}}{sub {down_arrow}}, V{sub eff{down_arrow}}{sub {up_arrow}}, V{sub eff{down_arrow}}{sub {down_arrow}}) are obtained according to the polarization state of the scattered electrons. In an energy scale compatible with condensed matter electronic excitations, these potentials become degenerated. The resulting potential is implemented in the Schroedinger equation and the variational method is applied to carry out the electronic binding energy. The resulting binding energies in the scale of 10-100 meV and a correlation length in the scale of 10 - 30 Angstrom are possible indications that the MCS-QED{sub 3} model adopted may be suitable to address an eventual case of e{sup -}e{sup -} pairing in the presence of parity-symmetry breakdown. The data analyzed here suggest an energy scale of 10-100 meV to fix the breaking of the U(1)-symmetry. (author)
Quantum Entanglement of Locally Excited States in Maxwell Theory
Nozaki, Masahiro
2016-01-01
In 4 dimensional Maxwell gauge theory, we study the changes of (Renyi) entangle-ment entropy which are defined by subtracting the entropy for the ground state from the one for the locally excited states generated by acting with the gauge invariant local operators on the state. The changes for the operators which we consider in this paper reflect the electric-magnetic duality. The late-time value of changes can be interpreted in terms of electromagnetic quasi-particles. When the operator constructed of both electric and magnetic fields acts on the ground state, it shows that the operator acts on the late-time structure of quantum entanglement differently from free scalar fields.
Excited-State Properties of Molecular Solids from First Principles
Kronik, Leeor; Neaton, Jeffrey B.
2016-05-01
Molecular solids have attracted attention recently in the context of organic (opto)electronics. These materials exhibit unique charge carrier generation and transport phenomena that are distinct from those of conventional semiconductors. Understanding these phenomena is fundamental to optoelectronics and requires a detailed description of the excited-state properties of molecular solids. Recent advances in many-body perturbation theory (MBPT) and density functional theory (DFT) have made such description possible and have revealed many surprising electronic and optical properties of molecular crystals. Here, we review this progress. We summarize the salient aspects of MBPT and DFT as well as various properties that can be described by these methods. These properties include the fundamental gap and its renormalization, hybridization and band dispersion, singlet and triplet excitations, optical spectra, and excitonic properties. For each, we present concrete examples, a comparison to experiments, and a critical discussion.
Bound states of Dipolar Bosons in One-dimensional Systems
DEFF Research Database (Denmark)
G. Volosniev, A.; R. Armstrong, J.; V. Fedorov, D.;
2013-01-01
-body structures in this geometry are determined as function of polarization angles and dipole strength by using both essentially exact stochastic variational methods and the harmonic approximation. The main focus is on the three, four, and five-body problems in two or more tubes. Our results indicate...... that in the weakly-coupled limit the inter-tube interaction is similar to a zero-range term with a suitable rescaled strength. This allows us to address the corresponding many-body physics of the system by constructing a model where bound chains with one molecule in each tube are the effective degrees of freedom...
Photon-assisted tunneling through a topological superconductor with Majorana bound states
Energy Technology Data Exchange (ETDEWEB)
Tang, Han-Zhao; Zhang, Ying-Tao, E-mail: zhangyt@mail.hebtu.edu.cn [College of Physics, Hebei Normal University, Shijiazhuang 050024 (China); Liu, Jian-Jun, E-mail: liujj@mail.hebtu.edu.cn [College of Physics, Hebei Normal University, Shijiazhuang 050024 (China); Department of Physics, Shijiazhuang University, Shijiazhuang 050035 (China)
2015-12-15
Employing the Keldysh Nonequilibrium Green’s function method, we investigate time-dependent transport through a topological superconductor with Majorana bound states in the presence of a high frequency microwave field. It is found that Majorana bound states driven by photon-assisted tunneling can absorb(emit) photons and the resulting photon-assisted tunneling side band peaks can split the Majorana bound state that then appears at non-zero bias. This splitting breaks from the current opinion that Majorana bound states appear only at zero bias and thus provides a new experimental method for detecting Majorana bound states in the Non-zero-energy mode. We not only demonstrate that the photon-assisted tunneling side band peaks are due to Non-zero-energy Majorana bound states, but also that the height of the photon-assisted tunneling side band peaks is related to the intensity of the microwave field. It is further shown that the time-varying conductance induced by the Majorana bound states shows negative values for a certain period of time, which corresponds to a manifestation of the phase coherent time-varying behavior in mesoscopic systems.
Becis-Aubry, Yasmina; Boutayeb, Mohamed; Darouach, Mohamed
2006-01-01
International audience; This contribution proposes a recursive and easily implementable online algorithm for state estimation of multi-output discrete-time systems with nonlinear dynamics and linear measurements in presence of unknown but bounded disturbances corrupting both the state and measurement equations. The proposed algorithm is based on state bounding techniques and is decomposed into two steps : time update and observation update that uses a switching estimation Kalman-like gain mat...
Binding Energy of Quantum Bound States in X-shaped Nanowire Intersection
2014-01-01
that with non-zero magnetic field new structures are associated with virtual and resonant states located at the junction that becomes 2D Landau ...results of our model system (cross-wire intersecting at an arbitrary angle) not only supplement the theory of quantum bound state in a classically unbound...geometries has been a long standing problem in quantum theory . Knowledge of quantum bound states in crossed nanowire system is very important in
On accurate computations of bound state properties in three- and four-electron atomic systems
Frolov, Alexei M
2016-01-01
Results of accurate computations of bound states in three- and four-electron atomic systems are discussed. Bound state properties of the four-electron lithium ion Li$^{-}$ in its ground $2^{2}S-$state are determined from the results of accurate, variational computations. We also consider a closely related problem of accurate numerical evaluation of the half-life of the beryllium-7 isotope. This problem is of paramount importance for modern radiochemistry.
Initial state-resolved excited state absorption spectroscopy of ZBLAN:Ho3+ glass
Piatkowski, D.; Wisniewski, K.; Koepke, C.; Piramidowicz, R.; Klimczak, M.; Malinowski, M.
2008-12-01
Phase-sensitive and frequency-resolved detection techniques are used for the initial state-resolved excited state absorption (ESA) measurements in ZBLAN:Ho3+ glass. Both experimental techniques were applied simultaneously in a broad spectral range (550 1750 nm) for the first time. Estimated results are compared and discussed in detail. A simple kinetic model, used for qualitative considerations, is presented and successfully compared with the experimental data. The measured spectra will be useful for identifying new up-conversion excitation channels in the considered system, where ESA transitions originating from several excited levels are observed.
Application of spectroscopy and super-resolution microscopy: Excited state
Energy Technology Data Exchange (ETDEWEB)
Bhattacharjee, Ujjal [Iowa State Univ., Ames, IA (United States)
2016-02-19
Photophysics of inorganic materials and organic molecules in complex systems have been extensively studied with absorption and emission spectroscopy.1-4 Steady-state and time-resolved fluorescence studies are commonly carried out to characterize excited-state properties of fluorophores. Although steady-state fluorescence measurements are widely used for analytical applications, time-resolved fluorescence measurements provide more detailed information about excited-state properties and the environment in the vicinity of the fluorophore. Many photophysical processes, such as photoinduced electron transfer (PET), rotational reorientation, solvent relaxation, and energy transfer, occur on a nanosecond (10^{-9} s) timescale, thus affecting the lifetime of the fluorophores. Moreover, time-resolved microscopy methods, such as lifetimeimaging, combine the benefits of the microscopic measurement and information-rich, timeresolved data. Thus, time-resolved fluorescence spectroscopy combined with microscopy can be used to quantify these processes and to obtain a deeper understanding of the chemical surroundings of the fluorophore in a small area under investigation. This thesis discusses various photophysical and super-resolution microscopic studies of organic and inorganic materials, which have been outlined below.
The Problem of Mass: Mesonic Bound States Above Tc
Park, H J; Brown, G E; Rho, M
2006-01-01
By extending the Bielefeld LGS (Lattice Gauge Simulation) color singlet interaction, we find that the masses of pi, sigma, rho and a_1 excitations, 32 degrees of freedom in all, go to zero (in the chiral limit) as T -> T_c. This result indicates a smooth phase transition at T_c, at which from above the masses and couplings of mesons vanish `a la Brown-Rho scaling. We discuss that our scenario successfully explains the STAR (STAR Collaboration) rho^0/pi^- ratio in Au-Au peripheral collisions at RHIC.
Taming the Yukawa potential singularity: improved evaluation of bound states and resonance energies
Alhaidari, A D; Abdelmonem, M S
2007-01-01
Using the tools of the J-matrix method, we absorb the 1/r singularity of the Yukawa potential in the reference Hamiltonian, which is handled analytically. The remaining part, which is bound and regular everywhere, is treated by an efficient numerical scheme in a suitable basis using Gauss quadrature approximation. Analysis of resonance energies and bound states spectrum is performed using the complex scaling method, where we show their trajectories in the complex energy plane and demonstrate the remarkable fact that bound states cross over into resonance states by varying the potential parameters.
Excited-state proton transfer of firefly dehydroluciferin.
Presiado, Itay; Erez, Yuval; Simkovitch, Ron; Shomer, Shay; Gepshtein, Rinat; Pinto da Silva, Luís; Esteves da Silva, Joaquim C G; Huppert, Dan
2012-11-08
Steady-state and time-resolved emission techniques were used to study the protolytic processes in the excited state of dehydroluciferin, a nonbioluminescent product of the firefly enzyme luciferase. We found that the ESPT rate coefficient is only 1.1 × 10(10) s(-1), whereas those of d-luciferin and oxyluciferin are 3.7 × 10(10) and 2.1 × 10(10) s(-1), respectively. We measured the ESPT rate in water-methanol mixtures, and we found that the rate decreases nonlinearly as the methanol content in the mixture increases. The deprotonated form of dehydroluciferin has a bimodal decay with short- and long-time decay components, as was previously found for both D-luciferin and oxyluciferin. In weakly acidic aqueous solutions, the deprotonated form's emission is efficiently quenched. We attribute this observation to the ground-state protonation of the thiazole nitrogen, whose pK(a) value is ~3.
Energy Technology Data Exchange (ETDEWEB)
Adhikari, S.; Basu, C.; Thompson, I. J.; Sugathan, P.; Jhinghan, A.; Golda, K. S.; Babu, A.; Singh, D.; Ray, S.; Mitra, A. K. [Nuclear Physics Division, Saha Institute of Nuclear Physics, Kolkata-700064 (India); Lawrence Livermore National Laboratory, L-414, Livermore CA 94551 (United States); Inter University Accelerator Centre, New Delhi 110067 (India); Physics Department, Ramkrishna Vivekananda University, Belur, Howrah (India); Nuclear Physics Division, Saha Institute of Nuclear Physics, Kolkata-700064 (India)
2012-10-20
The deuteron angular distribution for the {sup 12}C({sup 6}Li,d){sup 16}O* has been measured at 20 MeV populating bound and unbound states of {sup 16}O. Analysis shows a dominance of breakup induced alpha transfer in comparison to a direct alpha transfer process for the bound states. The effect increases as the excitation energy of {sup 16}O decreases, maximizing at the ground state.
Excited states above the proton threshold in {sup 26}Si
Energy Technology Data Exchange (ETDEWEB)
Komatsubara, T. [Institute for Basic Science (IBS), Rare Isotope Science Project, Yuseong-gu Daejeon (Korea, Republic of); Kubono, S.; Ito, Y. [RIKEN, Saitama (Japan); Hayakawa, T.; Shizuma, T. [Japan Atomic Energy Agency, Tokai, Ibaraki (Japan); Ozawa, A.; Ishibashi, Y. [University of Tsukuba, Institute of Physics, Tsukuba, Ibaraki (Japan); Moriguchi, T. [National Cerebral and Cardiovascular Center Research Institute, Suita, Osaka (Japan); Yamaguchi, H.; Kahl, D. [University of Tokyo, Wako Branch, Center for Nuclear Study (CNS), Wako, Saitama (Japan); Hayakawa, S. [Laboratori Nazionali del Sud-INFN, Catania (Italy); Nguyen Binh, Dam [Vietnamese Academy for Science and Technology, Institute of Physics, Hanoi (Viet Nam); Chen, A.A.; Chen, J. [McMaster University, Hamilton, Ontario (Canada); Setoodehnia, K. [University of Notre Dame, Department of Physics, Notre Dame, Indiana (United States); Kajino, T. [National Astronomical Observatory, Tokyo (Japan); University of Tokyo, Department of Astronomy, Graduate School of Science, Tokyo (Japan)
2014-09-15
The level scheme above the proton threshold in {sup 26}Si is crucial for evaluating the {sup 25}Al(p, γ){sup 26}Si stellar reaction, which is important for understanding the astrophysical origin of the long-lived cosmic radioactivity {sup 26}Al(T{sub 1/2} = 7.17 x 10{sup 5} y) in the Galaxy. The excited states in {sup 26}Si have been studied using an in-beam γ-ray spectroscopy technique with the {sup 24}Mg({sup 3}He, nγ){sup 26}Si reaction. γ-rays with energies up to 4.6 MeV emitted from excited states in {sup 26}Si have been measured using large volume HPGe detectors. The spin-parity of one of the most important states reported recently at 5890.0keV has been assigned as 0{sup +} by γ-γ angular correlation measurements in this work. (orig.)
Excited-State Dynamics of Oxyluciferin in Firefly Luciferase
Snellenburg, Joris J.
2016-11-23
The color variations of light emitted by some natural and mutant luciferases are normally attributed to collective factors referred to as microenvironment effects; however, the exact nature of these interactions between the emitting molecule (oxyluciferin) and the active site remains elusive. Although model studies of noncomplexed oxyluciferin and its variants have greatly advanced the understanding of its photochemistry, extrapolation of the conclusions to the real system requires assumptions about the polarity and proticity of the active site. To decipher the intricate excited-state dynamics, global and target analysis is performed here for the first time on the steady-state and time-resolved spectra of firefly oxyluciferin complexed with luciferase from the Japanese firefly (Luciola cruciata). The experimental steady-state and time resolved luminescence spectra of the oxyluciferin/luciferase complex in solution are compared with the broadband time-resolved firefly bioluminescence recorded in vivo. The results demonstrate that de-excitation of the luminophore results in a complex cascade of photoinduced proton transfer processes and can be interpreted by the pH dependence of the emitted light. It is confirmed that proton transfer is the central event in the spectrochemistry of this system for which any assignment of the pH dependent emission to a single chemical species would be an oversimplification.
Radiative Decays of Low-Lying Excited-State Hyperons
Energy Technology Data Exchange (ETDEWEB)
Taylor, Simon [Rice Univ., Houston, TX (United States)
2000-05-01
The quark wave-functions of the lower-lying excited-state hyperons Lambda(1405), Sigma(1385), and Lambda(1520) are not well understood. For example, the Lambda(1405) may not be a regular three-quark state but a $\\bar{K}$N molecule. Several competing models have been proposed, but none have been convincingly eliminated. Measuring radiative decays provides a means of discriminating between the models. The radiative branching of ratios are predicted to be small (~1%), but the radiative widths vary by factors of 2-10 from model to model. The existing experimental data is sparse and inconsistent; moreover, the radiative decay of the Sigma(1385) has never been observed before (except for one event). These lower-lying excited state hypersons were produced in a tagged photon-beam experiment in the CLAS detector at TJNAF in the reaction gamma p → K^{+} Y* for photon energies from threshold to 2.4 GeV. The radiative branching ration for the Sigma^{0}(1385) relative to the Sigma^{0}(1385) → Lambda pi^{0} channel was measured to be 0.021 ± 0.008$+0.004\\atop{-0.007}$, corresponding to a partial width of 640 ± 270$+130\\atop{-220}$ keV.
Proton Decay from Excited States in Spherical Nuclei
Misicu, S; Talou, P
1998-01-01
Based on a single particle model which describes the time evolution of the wave function during tunneling across a one dimensional potential barrier we study the proton decay of $^{208}$Pb from excited states with non-vanishing angular momentum $\\ell$. Several quantities of interest in this process like the decay rate $\\lambda$, the period of oscillation $T_{osc}$, the transient time $t_{tr}$, the tunneling time $t_{tun}$ and the average value of the proton packet position $ r_{av} $ are computed and compared with the WKB results.
Triaxiality near the 110Ru ground state from Coulomb excitation
Doherty, D. T.; Allmond, J. M.; Janssens, R. V. F.; Korten, W.; Zhu, S.; Zielińska, M.; Radford, D. C.; Ayangeakaa, A. D.; Bucher, B.; Batchelder, J. C.; Beausang, C. W.; Campbell, C.; Carpenter, M. P.; Cline, D.; Crawford, H. L.; David, H. M.; Delaroche, J. P.; Dickerson, C.; Fallon, P.; Galindo-Uribarri, A.; Kondev, F. G.; Harker, J. L.; Hayes, A. B.; Hendricks, M.; Humby, P.; Girod, M.; Gross, C. J.; Klintefjord, M.; Kolos, K.; Lane, G. J.; Lauritsen, T.; Libert, J.; Macchiavelli, A. O.; Napiorkowski, P. J.; Padilla-Rodal, E.; Pardo, R. C.; Reviol, W.; Sarantites, D. G.; Savard, G.; Seweryniak, D.; Srebrny, J.; Varner, R.; Vondrasek, R.; Wiens, A.; Wilson, E.; Wood, J. L.; Wu, C. Y.
2017-03-01
A multi-step Coulomb excitation measurement with the GRETINA and CHICO2 detector arrays was carried out with a 430-MeV beam of the neutron-rich 110Ru (t1/2 = 12 s) isotope produced at the CARIBU facility. This represents the first successful measurement following the post-acceleration of an unstable isotope of a refractory element. The reduced transition probabilities obtained for levels near the ground state provide strong evidence for a triaxial shape; a conclusion confirmed by comparisons with the results of beyond-mean-field and triaxial rotor model calculations.
Averaging in Parametrically Excited Systems – A State Space Formulation
Directory of Open Access Journals (Sweden)
Pfau Bastian
2016-01-01
Full Text Available Parametric excitation can lead to instabilities as well as to an improved stability behavior, depending on whether a parametric resonance or anti-resonance is induced. In order to calculate the stability domains and boundaries, the method of averaging is applied. The problem is reformulated in state space representation, which allows a general handling of the averaging method especially for systems with non-symmetric system matrices. It is highlighted that this approach can enhance the first order approximation significantly. Two example systems are investigated: a generic mechanical system and a flexible rotor in journal bearings with adjustable geometry.
Excited-State Upconversion of Pr(0.5) Yb(1.5): ZB LAN under Two-Colour Excitation
Institute of Scientific and Technical Information of China (English)
CHEN Xiao-Bo; SONG Zeng-Fu
2005-01-01
@@ We report the excited-state upconversion in Pr(0.5)Yb(1.5):ZBLAN under two-colour excitation of 960nm laser and xenon lamp light.Three obvious upconversion excitation peaks around 856.0, 804.2 and 787.1 nm were observed and the involved mechanism has been explained.The measured upconversion excitation peak 856.0nm corresponds to the sum of theoretical values 852nm and 866nm owing to the 1G4(Pr3+)→ 1I6(Pr3+) and 1G4(Pr3+ )→ 3 P1 (Pr3+ ) excited state absorption transitions.The measured 804.2 and 787.1 nm upconversion excitation peaks originate from the excited state absorption transitions 3H6 (Pr3+ )→ 1 D2 (Pr3+) and 1G4 (Pr3+ )→ 3P2 (Pr3+), respectively.The excited state absorption upconversion 1 G4(Pr3+)→ 1 I6 (Pr3+) is strong because of its large oscillator strength f = 23.040 × 10-6.
DEFF Research Database (Denmark)
Bohr, Henrik; Malik, F. Bary
2013-01-01
The observed multiple de-excitation pathways of photo-absorbed electronic excited state in the peridinin–chlorophyll complex, involving both energy and charge transfers among its constituents, are analyzed using the bio-Auger (B-A) theory. It is also shown that the usually used F¨orster–Dexter th...
Excited-state relaxation in π-conjugated polymers
Frolov, S. V.; Bao, Z.; Wohlgenannt, M.; Vardeny, Z. V.
2002-05-01
We study ultrafast relaxation processes of odd- (Bu) and even-parity (Ag) exciton states in poly(p-phenylene vinylene) derivatives. The Bu states are studied using a regular two-beam pump-and-probe spectroscopy, which can monitor vibronic relaxation and exciton diffusion. In order to observe the Ag states, a three-beam femtosecond transient spectroscopy is developed, in which two different excitation pulses successively generate odd-parity (1Bu) excitons at 2.2 eV and then reexcite them to higher Ag states. We are able to distinguish two different classes of Ag states: one class (mAg) experiences ultrafast internal conversion back to the lowest singlet exciton, whereas the other class (kAg) in violation of the Vavilov-Kasha's rule undergoes a different relaxation pathway. The excitons subsequently dissociate into long-lived polaron pairs, which results in emission quenching with the action spectrum similar to that of the intrinsic photoconductivity. We conclude that the Ag states above 3.3 eV (kAg) are charge-transfer states, that mediate carrier photogeneration.
Photoionization spectroscopy of excited states of cold cesium dimers
Bouloufa, Nadia; Viteau, Matthieu; Chotia, Amodsen; Fioretti, Andrea; Gabbanini, Carlo; Allegrini, Maria; Aymar, Mireille; Comparat, Daniel; Dulieu, Olivier; Pillet, Pierre
2010-01-01
Photoionization spectroscopy of cold cesium dimers obtained by photoassociation of cold atoms in a magneto-optical trap is reported here. In particular, we report on the observation and on the spectroscopic analysis of all the excited states that have actually been used for efficient detection of cold molecules stabilized in the triplet a^3Sigma_u^+ ground state. They are: the (1)^3Sigma_g^+ state connected to the 6s+6p asymptote, the (2)^3Sigma_g^+ and (2)^3Pi_g states connected to the 6s+5d asymptote and finally the (3)^3Sigma_g^+ state connected to the 6s + 7s asymptote. The detection through these states spans a wide range of laser energies, from 8000 to 16500 cm-1, obtained with different laser dyes and techniques. Information on the initial distribution of cold molecules among the different vibrational levels of the a^3Sigma_u^+ ground state is also provided. This spectroscopic knowledge is important when conceiving schemes for quantum manipulation, population transfer and optical detection of cold cesi...
State-to-state kinetics and transport properties of electronically excited N and O atoms
Istomin, V. A.; Kustova, E. V.
2016-11-01
A theoretical model of transport properties in electronically excited atomic gases in the state-to-state approach is developed. Different models for the collision diameters of atoms in excited states are discussed, and it is shown that the Slater-like models can be applied for the state-resolved transport coefficient calculations. The influence of collision diameters of N and O atoms with electronic degrees of freedom on the transport properties is evaluated. Different distributions on the electronic energy are considered for the calculation of transport coefficients. For the Boltzmann-like distributions at temperatures greater than 15000 K, an important effect of electronic excitation on the thermal conductivity and viscosity coefficients is found; the coefficients decrease significantly when many electronic states are taken into account. It is shown that under hypersonic reentry conditions the impact of collision diameters on the transport properties is not really important since the populations of high levels behind the shock waves are low.
Huang, Dao-Ling; Zhu, Guo-Zhu; Wang, Lai-Sheng
2016-06-01
Deprotonated thymine can exist in two different forms, depending on which of its two N sites is deprotonated: N1[T-H]^- or N3[T-H]^-. Here we report a photodetachment study of the N1[T-H]^- isomer cooled in a cryogenic ion trap and the observation of an excited dipole-bound state. Eighteen vibrational levels of the dipole-bound state are observed, and its vibrational ground state is found to be 238 ± 5 wn below the detachment threshold of N1[T-H]^-. The electron affinity of the deprotonated thymine radical (N1[T-H]^.) is measured accruately to be 26 322 ± 5 wn (3.2635 ± 0.0006 eV). By tuning the detachment laser to the sixteen vibrational levels of the dipole-bound state that are above the detachment threshold, highly non-Franck-Condon resonant-enhanced photoelectron spectra are obtained due to state- and mode-selective vibrational autodetachment. Much richer vibrational information is obtained for the deprotonated thymine radical from the photodetachment and resonant-enhanced photoelectron spectroscopy. Eleven fundamental vibrational frequencies in the low-frequency regime are obtained for the N1[T-H]^. radical, including the two lowest-frequency internal rotational modes of the methyl group at 70 ± 8 wn and 92 ± 5 wn. D. L. Huang, H. T. Liu, C. G. Ning, G. Z. Zhu and L. S. Wang, Chem. Sci., 6, 3129-3138 (2015)
Atomic GHZ States Prepared in Two Directly Coupled Cavities with Virtual Excitations in One Step
Institute of Scientific and Technical Information of China (English)
杨榕灿; 黄志平; 郭强; 张鹏飞; 钟纯勇; 张天才
2011-01-01
A scheme for one-step preparation of atomic GHZ states in two directly coupled cavities via virtual excitations is proposed. In the whole procedure, the information is carried only in two ground states of A-type atoms, while the excited states of atoms and cavity modes are virtually excited, leading the system to be insensitive to atomic spontaneous emission and photon loss.
Optical Generation of Single- or Two-Mode Excited Entangled Coherent States
Institute of Scientific and Technical Information of China (English)
REN Zhen-Zhong; JING Hui; ZHANG Xian-Zhou
2008-01-01
With nonlinear Mach-Zehnder interferometer (NLMZI) and a type-Ⅰ beta-barium borate (BBO) crystal, we optically generate single-mode excited entangled coherent states. This scheme can be easily generalized to generate two-mode excited entangled coherent states. We simply analyse different influences of single- and two-mode photon excitations on entangled coherent states.
Cruising through molecular bound-state manifolds with radiofrequency
Lang, F.; van der Straten, P.; Brandstätter, B.; Thalhammer, G.; Winkler, K.; Julienne, P.S.; Grimm, R.; Hecker Denschlag, J.
2008-01-01
The production of ultracold molecules with their rich internal structure is currently attracting considerable interest1, 2, 3, 4. For future experiments, it will be important to efficiently transfer these molecules from their initial internal quantum state at production to other quantum states of in
An Improved Lower Bound Limit State Optimisation Algorithm
DEFF Research Database (Denmark)
Frier, Christian; Damkilde, Lars
2010-01-01
Limit State analysis has been used in manual design methods for decades e.g. the yield line theory for concrete slabs.......Limit State analysis has been used in manual design methods for decades e.g. the yield line theory for concrete slabs....
Quark-antiquark bound-state spectroscopy and QCD
Energy Technology Data Exchange (ETDEWEB)
Bloom, E.D.
1982-11-01
The discussion covers quarks as we know them, the classification of ordinary mesons in terms of constituent quarks, hidden charm states and charmed mesons, bottom quarks, positronium as a model for quarti q, quantum chromodynamics and its foundation in experiment, the charmonium model, the mass of states, fine structure and hyperfine structure, classification, widths of states, rate and multipolarity of gamma transitions, questions about bottom, leptonic widths and the determination of Q/sub b/, the mass splitting of the n/sup 3/S/sub 1/ states, the center of gravity of the masses of the n/sup 3/P; states, n/sup 3/ P; fine structure and classification, branching ratios for upsilon' ..-->.. tau chi/sub 6j/ and the tau cascade reactions, hyperfine splitting, and top. (GHT)
Breathing-like excited state of the Hoyle state in 12C
Zhou, Bo; Tohsaki, Akihiro; Horiuchi, Hisashi; Ren, Zhongzhou
2016-10-01
The existence of the 03+ and 04+ states around 10 MeV excitation energy in 12C is confirmed by a fully microscopic 3 α cluster model. Firstly, a generator coordinate method (GCM) calculation is performed by superposing optimized 2 α +α Tohsaki-Horiuchi-Schuck-Röpke (THSR) wave functions with the radius-constraint method. The obtained two excited 0+ states above the Hoyle state are consistent with the recently observed states by experiment. Secondly, a variational calculation using the single 2 α +α THSR wave function orthogonalized to the ground and Hoyle states is made and it also supports the existence of the 03+ state obtained by the GCM calculation. The analysis of the obtained 03+ state is made by studying its 2 α -α reduced width amplitude, its 2 α correlation function, and the large monopole matrix element between this state and the Hoyle state, which shows that this 03+ state is a breathing-like excited state of the Hoyle state. This character of the 03+ state is very different from the 04+ state which seems to have a bent-arm 3 α structure.
Dvornikov, Maxim
2011-01-01
I reply here to the comment of Dr Shmatov on my recent work and demonstrate the invalidity of his criticism of the classical physics description of the formation of bound states of electrons participating in spherically symmetric oscillations of plasma.
The dynamical gluon mass in the massless bound-state formalism
Ibanez, David
2014-01-01
We describe the phenomenon of dynamical gluon mass generation within the massless bound-state formalism, which constitutes the general framework for the systematic implementation of the Schwinger mechanism in non-Abelian gauge theories. The main ingredient of this formalism is the dynamical formation of bound states with vanishing mass, which gives rise to effective vertices containing massless poles; these vertices, in turn, trigger the Schwinger mechanism, and allow for the gauge-invariant generation of an effective gluon mass. In this particular approach, the gluon mass is directly related to quantities that are intrinsic to the bound-state formation itself, such as the "transition amplitude" and the corresponding "bound-state wave-function". Specifically, a set of powerful relations discussed in the text, allows one to determine the dynamical evolution of the gluon mass through a Bethe-Salpeter equation, which controls the dynamics of the relevant wave-function. In addition, it is possible to demonstrate ...
Electron-phonon interaction and excited states relaxation in carbon nanotubes
Perebeinos, Vasili
2008-03-01
We will discuss the role of electron-phonon interaction on excited states relaxation and phonon spectra in carbon nanotubes (CNTs). The electron-phonon interaction leads to the polaronic effects of the charge carriers, but it also renormalizes the energy and the lifetime of phonons. We present a theoretical model that predicts the changes induced in the phonon modes of CNTs as a function of the charge carrier doping, i.e. position of the Fermi level. In agreement with the predictions, our experiments show sharpening and blue shifts of the G-phonons of metallic CNTs, but only blue shifts for semiconducting CNTs, making the Raman scattering a useful probe of local doping of CNTs [1]. The non-equilibrium dynamics of charge carriers under external electric field is determined by the electron-phonon scattering. The hot carriers under unipolar transport conditions can be produced, leading to the strong impact excitation and light emission, which intensity is determined by electric field, phonon scattering, and impact excitation cross section [2, 3]. In the reverse process of photoconductivity, light is absorbed creating excited states. We will discuss electronic relaxation of high energy excited states leading to the free carriers, contributing to the photoconductivity, and phonon relaxation, leading to the bound excitons [4]. The later can contribute to the photocurrent only after ionization by the external field [5]. Finally, we will discuss the role of phonons in the long puzzling question regarding the nature of the dominant decay channel of the low energy excited states and the potential of optoelectronic applications of CNTs. [1] J.C. Tsang, M. Freitag, V. Perebeinos, J. Liu, and Ph. Avouris, Nature Nanotechnology 2, 725 (2007); [2] J. Chen, V. Perebeinos, M. Freitag, J. Tsang, Q. Fu, J. Liu, Ph. Avouris, Science 310, 1171 (2005); [3] V. Perebeinos and Ph. Avouris, Phys. Rev. B. 74, 121410(R), (2006); [4] T. Hertel, V. Perebeinos, J. Crochet, K. Arnold, M. Kappes
Impurity bound states in fully gapped d-wave superconductors with subdominant order parameters
Mashkoori, Mahdi; Björnson, Kristofer; Black-Schaffer, Annica M.
2017-01-01
Impurities in superconductors and their induced bound states are important both for engineering novel states such as Majorana zero-energy modes and for probing bulk properties of the superconducting state. The high-temperature cuprates offer a clear advantage in a much larger superconducting order parameter, but the nodal energy spectrum of a pure d-wave superconductor only allows virtual bound states. Fully gapped d-wave superconducting states have, however, been proposed in several cuprate systems thanks to subdominant order parameters producing d + is- or d + id′-wave superconducting states. Here we study both magnetic and potential impurities in these fully gapped d-wave superconductors. Using analytical T-matrix and complementary numerical tight-binding lattice calculations, we show that magnetic and potential impurities behave fundamentally different in d + is- and d + id′-wave superconductors. In a d + is-wave superconductor, there are no bound states for potential impurities, while a magnetic impurity produces one pair of bound states, with a zero-energy level crossing at a finite scattering strength. On the other hand, a d + id′-wave symmetry always gives rise to two pairs of bound states and only produce a reachable zero-energy level crossing if the normal state has a strong particle-hole asymmetry. PMID:28281570
Impurity bound states in fully gapped d-wave superconductors with subdominant order parameters.
Mashkoori, Mahdi; Björnson, Kristofer; Black-Schaffer, Annica M
2017-03-10
Impurities in superconductors and their induced bound states are important both for engineering novel states such as Majorana zero-energy modes and for probing bulk properties of the superconducting state. The high-temperature cuprates offer a clear advantage in a much larger superconducting order parameter, but the nodal energy spectrum of a pure d-wave superconductor only allows virtual bound states. Fully gapped d-wave superconducting states have, however, been proposed in several cuprate systems thanks to subdominant order parameters producing d + is- or d + id'-wave superconducting states. Here we study both magnetic and potential impurities in these fully gapped d-wave superconductors. Using analytical T-matrix and complementary numerical tight-binding lattice calculations, we show that magnetic and potential impurities behave fundamentally different in d + is- and d + id'-wave superconductors. In a d + is-wave superconductor, there are no bound states for potential impurities, while a magnetic impurity produces one pair of bound states, with a zero-energy level crossing at a finite scattering strength. On the other hand, a d + id'-wave symmetry always gives rise to two pairs of bound states and only produce a reachable zero-energy level crossing if the normal state has a strong particle-hole asymmetry.
The generalized pseudospectral approach to the bound states of the Hulthén and the Yukawa potentials
Indian Academy of Sciences (India)
Amlan K Roy
2005-07-01
The generalized pseudospectral (GPS) method is employed to calculate the bound states of the Hulthén and the Yukawa potentials in quantum mechanics, with special emphasis on higher excited states and stronger couplings. Accurate energy eigenvalues, expectation values and radial probability densities are obtained through a non-uniform and optimal spatial discretization of the radial Schrödinger equation. Results accurate up to thirteen to fourteen significant figures are reported for all the 55 eigenstates of both these potentials with ≤ 10 for arbitrary values of the screening parameters covering a wide range of interaction. Furthermore, excited states as high as = 17 have been computed with good accuracy for both these potentials. Excellent agreement with the available literature data has been observed in all cases. The > 6 states of the Yukawa potential has been considerably improved over all other existing results currently available, while the same for Hulthén potential are reported here for the first time. Excepting the 1 and 2 states of the Yukawa potential, the present method surpasses the accuracy of all other existing results in the stronger coupling region for all other states of both these systems. This offers a simple and efficient scheme for the accurate calculation of these and other screened Coulomb potentials.
Raman scattering from a superconductivity-induced bound state in MgB2.
Zeyher, R
2003-03-14
It is shown that the sharp peak in the E(2g) Raman spectrum of superconducting MgB2 is due to a bound state caused by the electron-phonon coupling. Our theory explains why this peak appears only in the spectra with E(2g) symmetry and only in the sigma but not the pi bands. The properties of the bound state and the Raman spectrum are investigated, also in the presence of impurity scattering.
Exact bound state solutions of the Klein-Gordon particle in Hulthén potential
Institute of Scientific and Technical Information of China (English)
Zhang Min-Cang
2008-01-01
In this paper,the Klein-Gordon equation with the spherical symmetric Hulthén potential is turned into a hypergeometric equation and is solved in the framework of function analysis exactly.The corresponding bound state solutions are expressed in terms of the hypergeometric function,and the energy spectrum of the bound states is obtained as a solution to a given equation by boundary constraints.
Institute of Scientific and Technical Information of China (English)
LIU Hui; HOU De-Fu; LI Jia-Rong
2009-01-01
We investigate the in-medium interparticle potential of hot gauge system with bound states by employing the QED and scalar QED coupling. At the finite temperature an oscillatory behavior of the potential has been found as well as its variation in terms of different free parameters. We expect the competition among the parameters will lead to an appropriate interparticle potential, which could be extended to discuss the fluid properties of QGP with scalar bound states.
Eta bound states in nuclei: a probe of flavour-singlet dynamics
Energy Technology Data Exchange (ETDEWEB)
Steven D. Bass; Anthony W. Thomas
2005-07-01
We argue that eta bound states in nuclei are sensitive to the singlet component in the eta. The bigger the singlet component, the more attraction and the greater the binding. Thus, measurements of eta bound states will yield new information about axial U(1) dynamics and glue in mesons. Eta - etaprime mixing plays an important role in understanding the value of the eta-nucleon scattering length.
Calculations of bar K-nuclear quasi-bound states using chiral bar KN amplitudes
Mareš, J.; Barnea, N.; Cieplý, A.; Friedman, E.; Gal, A.; Gazda, D.
2014-03-01
We review our recent calculations of K- quasi-bound states in nuclear systems using subthreshold energy dependent chiral bar KN amplitudes. Strong energy dependence of the scattering amplitudes requires self-consistent evaluation of the involved bar KN interactions. In view of sizable widths predicted by our calculations, an unambiguous identification of K--nuclear quasi-bound states in ongoing experimental searches would be difficult.
Lee, Timothy J.; Dateo, Christopher E.
2001-01-01
Vertical electronic excitation energies for single states have been computed for the high energy density material (HEDM) Td N4 in order to assess possible synthetic routes that originate from excited electronic states of N2 molecules. Several ab initio theoretical approaches have been used, including complete active space self-consistent field (CASSCF), state averaged CASSCF (SA-CASSCF), singles configuration interaction (CIS), CIS with second-order and third-order correlation corrections [CIS(D)) and CIS(3)], and linear response singles and doubles coupled-cluster (LRCCSD), which is the highest level of theory employed. Standard double zeta polarized (DZP) and triple zeta double polarized (TZ2P) one-particle basis sets were used. The CASSCF calculations are found to overestimate the excitation energies, while the SA-CASSCF approach rectifies this error to some extent, but not completely. The accuracy of the CIS calculations varied depending on the particular state, while the CIS(D), CIS(3), and LRCCSD results are in generally good agreement. Based on the LRCCSD calculations, the lowest six excited singlet states are 9.35(l(sup)T1), 10.01(l(sup)T2), 10.04(1(sup)A2), 10.07(1(sup)E), 10.12(2(sup)T1), and 10.42(2(sup)T2) eV above the ground state, respectively. Comparison of these excited state energies with the energies of possible excited states of N2+N2 fragments, leads us to propose that the most likely synthetic route for Td N4 involving this mechanism arises from combination of two bound quintet states of N2.
Probing the Locality of Excited States with Linear Algebra.
Etienne, Thibaud
2015-04-14
This article reports a novel theoretical approach related to the analysis of molecular excited states. The strategy introduced here involves gathering two pieces of physical information, coming from Hilbert and direct space operations, into a general, unique quantum mechanical descriptor of electronic transitions' locality. Moreover, the projection of Hilbert and direct space-derived indices in an Argand plane delivers a straightforward way to visually probe the ability of a dye to undergo a long- or short-range charge-transfer. This information can be applied, for instance, to the analysis of the electronic response of families of dyes to light absorption by unveiling the trend of a given push-pull chromophore to increase the electronic cloud polarization magnitude of its main transition with respect to the size extension of its conjugated spacer. We finally demonstrate that all the quantities reported in this article can be reliably approximated by a linear algebraic derivation, based on the contraction of detachment/attachment density matrices from canonical to atomic space. This alternative derivation has the remarkable advantage of a very low computational cost with respect to the previously used numerical integrations, making fast and accurate characterization of large molecular systems' excited states easily affordable.
Excited state mass spectra of singly charmed baryons
Energy Technology Data Exchange (ETDEWEB)
Shah, Zalak; Kumar Rai, Ajay [Sardar Vallabhbhai National Institute of Technology, Department of Applied Physics, Surat, Gujarat (India); Thakkar, Kaushal [GIDC Degree Engineering College, Department of Applied Sciences and Humanities, Abrama (India); Vinodkumar, P.C. [Sardar Patel University, Department of Physics, V.V. Nagar (India)
2016-10-15
Mass spectra of excited states of the singly charmed baryons are calculated using the hypercentral description of the three-body system. The baryons consist of a charm quark and light quarks (u, d and s) are studied in the framework of QCD motivated constituent quark model. The form of the confinement potential is hyper-Coloumb plus power potential with potential index ν, varying from 0.5 to 2.0. The first-order correction to the confinement potential is also incorporated in this approach. The radial as well as orbital excited state masses of Σ{sub c}{sup ++}, Σ{sub c}{sup +}, Σ{sub c}{sup 0}, Ξ{sub c}{sup +}, Ξ{sub c}{sup 0}, Λ{sub c}{sup +}, Ω{sub c}{sup 0} baryons, are reported in this paper. We have incorporated spin-spin, spin-orbit and tensor interactions perturbatively in the present study. The semi-electronic decay of Ω{sub c} and Ξ{sub c} are also calculated using the spectroscopic parameters of these baryons. The computed results are compared with other theoretical predictions as well as with the available experimental observations. We also construct the Regge trajectory in (n{sub r},M{sup 2}) and (J,M{sup 2}) planes for these baryons. (orig.)
Bound Electron States in Skew-symmetric Quantum Wire Intersections
2014-01-01
dots is that they lie far beneath the surface of the surround- ing material whose associated states are potentially meddlesome. Colloidal chemistry ... textbooks have posed problems dealing with these states, but the approaches used in these problems involved variational methods or limiting cases, which are...of the Introductory Quantum Mechanics textbook by D.J.Griffith (Pearson, 2005). My trial function that has been developed in this the- sis, has an
Scaling and universality in two dimensions: three-body bound states with short-ranged interactions
Energy Technology Data Exchange (ETDEWEB)
Bellotti, F F; Frederico, T [Instituto Tecnologico de Aeronautica, DCTA, 12.228-900 Sao Jose dos Campos, SP (Brazil); Yamashita, M T [Instituto de Fisica Teorica, UNESP-Univ Estadual Paulista, CP 70532-2, CEP 01156-970, Sao Paulo, SP (Brazil); Fedorov, D V; Jensen, A S; Zinner, N T, E-mail: zinner@phys.au.dk [Department of Physics and Astronomy-Aarhus University, Ny Munkegade, bygn. 1520, DK-8000 Arhus C (Denmark)
2011-10-28
The momentum space zero-range model is used to investigate universal properties of three interacting particles confined to two dimensions. The pertinent equations are first formulated for a system of two identical and one distinct particle and the two different two-body subsystems are characterized by two-body energies and masses. The three-body energy in units of one of the two-body energies is a universal function of the other two-body energy and the mass ratio. We derive convenient analytical formulae for calculations of the three-body energy as a function of these two independent parameters and exhibit the results as universal curves. In particular, we show that the three-body system can have any number of stable bound states. When the mass ratio of the distinct to identical particles is greater than 0.22, we find that at most two stable bound states exist, while for two heavy and one light mass an increasing number of bound states is possible. The specific number of stable bound states depends on the ratio of two-body bound state energies and on the mass ratio, and we map out an energy-mass phase diagram of the number of stable bound states. Realizable systems of both fermions and bosons are discussed in this framework.
Universal crossover from ground-state to excited-state quantum criticality
Kang, Byungmin; Potter, Andrew C.; Vasseur, Romain
2017-01-01
We study the nonequilibrium properties of a nonergodic random quantum chain in which highly excited eigenstates exhibit critical properties usually associated with quantum critical ground states. The ground state and excited states of this system belong to different universality classes, characterized by infinite-randomness quantum critical behavior. Using strong-disorder renormalization group techniques, we show that the crossover between the zero and finite energy density regimes is universal. We analytically derive a flow equation describing the unitary dynamics of this isolated system at finite energy density from which we obtain universal scaling functions along the crossover.
Photoexcited breathers in conjugated polyenes: an excited-state molecular dynamics study.
Tretiak, S; Saxena, A; Martin, R L; Bishop, A R
2003-03-04
pi-conjugated polymers have become an important class of materials for electronic devices. Design of these devices requires understanding such processes as photochemical reactions, spatial dynamics of photoexcitations, and energy and charge transport, which in turn involve complex coupled electron-vibrational dynamics. Here we study nonlinear photoexcitation dynamics in the polyene oligomers by using a quantum-chemical method suitable for the simulation of excited-state molecular dynamics in extended molecular systems with sizes up to hundreds of atoms. The method is based on the adiabatic propagation of the ground-state and transition single-electron density matrices along the trajectory. The simulations reveal formation of a self-localized vibronic excitation ("breather" or multiquanta bound state) with a typical period of 34 fs and allows us to identify specific slow and fast nuclear motions strongly coupled to the electronic degrees of freedom. The effect of chain imperfections and chemical defects on the dynamics is also investigated. A complementary two-dimensional analysis of corresponding transition density matrices provides an efficient way to monitor time-dependent real-space localization of the photoexcitation by identifying the underlying changes in charge densities and bond orders. Possible correlated electronic and vibrational spectroscopic signatures of photoexcited breathers are predicted, and generalizations to energy localization in complex macromolecules are discussed.
Excited state properties of the astaxanthin radical cation: A quantum chemical study
Dreuw, Andreas; Starcke, Jan Hendrik; Wachtveitl, Josef
2010-07-01
Using time-dependent density functional theory, the excited electronic states of the astaxanthin radical cation (AXT rad + ) are investigated. While the optically allowed excited D 1 and D 3 states are typical ππ∗ excited states, the D 2 and D 4 states are nπ∗ states. Special emphasis is put onto the influence of the carbonyl groups onto the excited states. For this objective, the excited states of four hypothetical carotenoids and zeaxanthin have been computed. Addition of a carbonyl group to a conjugated carbon double bond system does essentially not change the vertical excitation energies of the optically allowed ππ∗ states due to two counter-acting effects: the excitation energy should increase due to the -M-effect of the carbonyl group and at the same time decrease owing to the elongation of the conjugated double bond system by the carbonyl group itself.
Excited state properties of the astaxanthin radical cation: A quantum chemical study
Energy Technology Data Exchange (ETDEWEB)
Dreuw, Andreas, E-mail: andreas.dreuw@theochem.uni-frankfurt.de [Institute of Physical and Theoretical Chemistry, Goethe-University Frankfurt, Max von Laue-Str. 7, 60438 Frankfurt am Main (Germany); Starcke, Jan Hendrik; Wachtveitl, Josef [Institute of Physical and Theoretical Chemistry, Goethe-University Frankfurt, Max von Laue-Str. 7, 60438 Frankfurt am Main (Germany)
2010-07-19
Using time-dependent density functional theory, the excited electronic states of the astaxanthin radical cation (AXT{sup {center_dot}+}) are investigated. While the optically allowed excited D{sub 1} and D{sub 3} states are typical {pi}{pi}* excited states, the D{sub 2} and D{sub 4} states are n{pi}* states. Special emphasis is put onto the influence of the carbonyl groups onto the excited states. For this objective, the excited states of four hypothetical carotenoids and zeaxanthin have been computed. Addition of a carbonyl group to a conjugated carbon double bond system does essentially not change the vertical excitation energies of the optically allowed {pi}{pi}* states due to two counter-acting effects: the excitation energy should increase due to the -M-effect of the carbonyl group and at the same time decrease owing to the elongation of the conjugated double bond system by the carbonyl group itself.
Kondo, Jorge M; Guttridge, Alex; Wade, Christopher G; De Melo, Natalia R; Adams, Charles S; Weatherill, Kevin J
2015-01-01
We report on the observation of Electromagnetically Induced Transparency (EIT) and Absorption (EIA) of highly-excited Rydberg states in thermal Cs vapor using a 4-step excitation scheme. The advantage of this 4-step scheme is that the final transition to the Rydberg state has a large dipole moment and one can achieve similar Rabi frequencies to 2 or 3 step excitation schemes using two orders of magnitude less laser power. Consequently each step is driven by a relatively low power infra-red diode laser opening up the prospect for new applications. The observed lineshapes are in good agreement with simulations based on multilevel optical Bloch equations.
An Improved Lower Bound Limit State Optimisation Algorithm
DEFF Research Database (Denmark)
Frier, Christian; Damkilde, Lars
2010-01-01
Limit State analysis has been used in engineering practice for many years e.g. the yield-line method for concrete slabs and slip-line solutions in geotechnics. In the recent years there has been an increased interest in numerical Limit State analysis, and today algorithms take into account the non......-linear yield criteria. The aim of the paper is to refine an earlier presented effective method which reduces the number of optimisation variables considerably by eliminating the equilibrium equations a priori and improvements are made on the interior point optimisation algorithm....
Selective population and neutron decay of the first excited state of semi-magic O-23
Schiller, A; Bazin, D; Brown, B A; Brown, J; DeYoung, P A; Finck, J E; Frank, N; Gade, A; Hinnefeld, J; Howes, R; Lecouey, J L; Luther, B; Peters, W A; Scheit, H; Thoennessen, M; Tostevin, J A
2006-01-01
We have observed an excited state in the neutron-rich semi-magic nucleus O-23 for the first time. No such states have been found in previous searches using gamma-ray spectroscopy. The observation of a resonance in n-fragment coincidence measurements confirms the speculation in the literature that the lowest excited state is neutron unbound and establishes positive evidence for a 2.8(1) MeV excitation energy of the first excited state in O-23. The non-observation of a predicted second excited state is explained assuming selectivity of inner-shell knockout reactions.
QQqq Four-Quark Bound States in Chiral SU(3) Quark Model
Institute of Scientific and Technical Information of China (English)
ZHANG Ming; ZHANG Hai-Xia; ZHANG Zong-Ye
2008-01-01
The possibility of QQqq heavy-light four-quark bound states has been analyzed by means of the chiral SU(3) quark model, where Q is the heavy quark (c or b) and q is the light quark (u, d, or s). We obtain a bound state for the bbnn configuration with quantum number JP=1+, I=0 and for the ccnn (JP=1+, I=0) configuration, which is not bound but slightly above the D*D* threshold (n is u or d quark). Meanwhile, we also conclude that a weakly bound state in bbnn system can also be found without considering the chiral quark interactions between the two light quarks, yet its binding energy is weaker than that with the chiral quark interactions.
Breathing-like excited state of the Hoyle state in ${^{12}{\\rm C}}$
Zhou, Bo; Horiuchi, Hisashi; Ren, Zhongzhou
2016-01-01
The existence of the $0_3^+$ and $0_4^+$ states around 10 MeV excitation energy in ${^{12}{\\rm C}}$ is confirmed by a fully microscopic 3$\\alpha$ cluster model. Firstly, a GCM (generator coordinate method) calculation is performed by superposing optimized 2$\\alpha$+$\\alpha$ THSR (Tohsaki-Horiuchi-Schuck-R\\"{o}pke) wave functions with the radius-constraint method. The obtained two excited $0^+$ states above the Hoyle state are consistent with the recently observed states by experiment. Secondly, a variational calculation using the single 2$\\alpha$+$\\alpha$ THSR wave function orthogonalized to the ground and Hoyle states is made and it also supports the existence of the $0_3^+$ state obtained by the GCM calculation. The analysis of the obtained $0_3^+$ state is made by studying its 2$\\alpha$-$\\alpha$ reduced width amplitude, its 2$\\alpha$ correlation function, and the large monopole matrix element between this state and the Hoyle state, which shows that this $0_3^+$ state is a breathing-like excited state of th...
Andreev bound states for cake shape superconducting-normal systems
Energy Technology Data Exchange (ETDEWEB)
Cserti, J; Beri, B; Kormanyos, A; Pollner, P; Kaufmann, Z [Department of Physics of Complex Systems, Eoetvoes University, H-1117 Budapest, Pazmany Peter setany 1/A (Hungary)
2004-09-22
The energy spectrum of cake shape normal-superconducting systems is calculated by solving the Bogoliubov-de Gennes equation. We take into account the mismatch in the effective masses and Fermi energies of the normal and superconducting regions as well as the potential barrier at the interface. In the case of a perfect interface and without mismatch, the energy levels are treated by semi-classics. Analytical expressions for the density of states and its integral, the step function, are derived and compared with that obtained from exact numerics. We find a very good agreement between the two calculations. It is shown that the spectrum possesses an energy gap and the density of states is singular at the edge of the gap. The effect of the mismatch and the potential barrier on the gap is also investigated.
Is the exotic X(5568) a bound state?
Energy Technology Data Exchange (ETDEWEB)
Chen, Xiaoyun; Ping, Jialun [Nanjing Normal University, Department of Physics and Jiangsu Key Laboratory for Numerical Simulation of Large Scale Complex Systems, Nanjing (China)
2016-06-15
Stimulated by the recent observation of the exotic X(5568) state by the D0 Collaboration, we study the four-quark system us anti b anti d with quantum numbers J{sup P} = 0{sup +} in the framework of the chiral quark model. Two structures, diquark-antidiquark and meson-meson, with all possible color configurations are investigated by using the Gaussian expansion method. The results show that the energies of the tetraquark states with diquark-antiquark structure are too high to be candidates of X(5568), and no molecular structure can be formed in our calculations. The calculation is also extended to the four-quark system us anti c anti d and the same results as that of us anti b anti d are obtained. (orig.)
Andreev Spectra and Subgap Bound States in Multiband Superconductors
Golubov, A. A.; Brinkman, A.; Tanaka, Yukio; Mazin, I.I.; Dolgov, O. V.
2009-01-01
The theory of Andreev conductance is formulated for junctions involving normal metals (N) and multiband superconductors (S) and applied to the case of superconductors with nodeless extended $s_{\\pm}$-wave order parameter symmetry, as possibly realized in the recently discovered ferro pnictides. We find qualitative differences from tunneling into s-wave or d-wave superconductors that may help to identify such a state. First, interband interference leads to a suppression of Andreev reflection i...
New excited states in the halo nucleus {sup 6}He
Energy Technology Data Exchange (ETDEWEB)
Mougeot, X. [CEA, Centre de Saclay, IRFU, Service de Physique Nucleaire, F-91191 Gif-sur-Yvette (France); Lapoux, V., E-mail: valerie.lapoux@cea.fr [CEA, Centre de Saclay, IRFU, Service de Physique Nucleaire, F-91191 Gif-sur-Yvette (France); Mittig, W. [GANIL, Bld. Henri Becquerel, BP 5027, F-14021 Caen Cedex (France); Alamanos, N.; Auger, F.; Avez, B. [CEA, Centre de Saclay, IRFU, Service de Physique Nucleaire, F-91191 Gif-sur-Yvette (France); Beaumel, D.; Blumenfeld, Y. [Institut de Physique Nucleaire, CNRS-IN2P3, F-91406 Orsay (France); Dayras, R.; Drouart, A. [CEA, Centre de Saclay, IRFU, Service de Physique Nucleaire, F-91191 Gif-sur-Yvette (France); Force, C. [GANIL, Bld. Henri Becquerel, BP 5027, F-14021 Caen Cedex (France); Gaudefroy, L. [CEA, DAM, DIF, F-91297 Arpajon (France); Gillibert, A. [CEA, Centre de Saclay, IRFU, Service de Physique Nucleaire, F-91191 Gif-sur-Yvette (France); Guillot, J. [Institut de Physique Nucleaire, CNRS-IN2P3, F-91406 Orsay (France); Iwasaki, H. [CEA, Centre de Saclay, IRFU, Service de Physique Nucleaire, F-91191 Gif-sur-Yvette (France); Al Kalanee, T. [GANIL, Bld. Henri Becquerel, BP 5027, F-14021 Caen Cedex (France); Keeley, N. [Department of Nuclear Reactions, National Centre for Nuclear Research, PL-00681, Warsaw (Poland); Nalpas, L.; Pollacco, E.C. [CEA, Centre de Saclay, IRFU, Service de Physique Nucleaire, F-91191 Gif-sur-Yvette (France); Roger, T. [GANIL, Bld. Henri Becquerel, BP 5027, F-14021 Caen Cedex (France); and others
2012-12-05
The low-lying spectroscopy of {sup 6}He was investigated via the 2-neutron transfer reaction p({sup 8}He,t) with the {sup 8}He beam delivered by the SPIRAL facility at 15.4 AMeV. The light charged particles produced by the direct reactions were measured using the MUST2 Si-strip telescope array. Above the known 2{sup +} state, two new resonances were observed: at E{sup Low-Asterisk }=2.6{+-}0.3 MeV (width {Gamma}=1.6{+-}0.4 MeV) and at 5.3{+-}0.3 MeV with {Gamma}=2{+-}1 MeV. Through the analysis of the angular distributions, they correspond to a 2{sup +} state and to an L=1 state, respectively. These new states, challenging the nuclear theories, could be used as benchmarks for checking the microscopic inputs of the newly improved structure models, and should trigger development of models including the treatments of both core excitation and continuum coupling effects.
Excited state effects in nucleon matrix element calculations
Energy Technology Data Exchange (ETDEWEB)
Alexandrou, Constantia [Cyprus Univ., Nicosia (Cyprus). Dept. of Physics; The Cyprus Institute, Nicosia (Cyprus). Computation-based Science and Technology Research Center; Constantinou, Martha [Cyprus Univ., Nicosia (Cyprus). Dept. of Physics; Dinter, Simon; Drach, Vincent; Jansen, Karl [Deutsches Elektronen-Synchrotron (DESY), Zeuthen (Germany). John von Neumann-Inst. fuer Computing NIC; Leontiou, Theodoros [Frederick Univ., Nicosia (Cyprus). General Dept.; Renner, Dru B. [Thomas Jefferson National Accelerator Facility, Newport News, VA (United States)
2011-12-15
We perform a high-statistics precision calculation of nucleon matrix elements using an open sink method allowing us to explore a wide range of sink-source time separations. In this way the influence of excited states of nucleon matrix elements can be studied. As particular examples we present results for the nucleon axial charge g{sub A} and for the first moment of the isovector unpolarized parton distribution left angle x right angle {sub u-d}. In addition, we report on preliminary results using the generalized eigenvalue method for nucleon matrix elements. All calculations are performed using N{sub f}=2+1+1 maximally twisted mass Wilson fermions. (orig.)
Alpha-particle decays from excited states in 24Mg
Institute of Scientific and Technical Information of China (English)
LIOTTA; R; J
2011-01-01
Using a cluster model based on the Woods-Saxon potential, alpha-particle decays from excited states in 24Mg have been system atically investigated. Calculations can in general reproduce experimental data, noticing the fact that the preformation factor P of alpha particle in alpha-decaying nuclei is of order from 100 to 10?2. This can be the evidence for the α+20Ne structure in 24Mg. Meanwhile, the results also show the existence of other configurations, such as 16O+2α. Since the calculated decay widths are very sensitive to the angular momentum carried by the outgoing cluster (α particle), our results could serve as a guide to experimental spin assignments.
Theoretical studies of excited state 1,3 dipolar cycloadditions
Belluccci, Michael A.
The 1,3 dipolar photocycloaddition reaction between 3-hydroxy-4',5,7-trimethoxyflavone (3-HTMF) and methyl cinnamate is investigated in this work. Since its inception in 2004 [JACS, 124, 13260 (2004)], this reaction remains at the forefront in the synthetic design of the rocaglamide natural products. The reaction is multi-faceted in that it involves multiple excited states and is contingent upon excited state intramolecular proton transfer (ESIPT) in 3-HTMF. Given the complexity of the reaction, there remain many questions regarding the underlying mechanism. Consequently, throughout this work we investigate the mechanism of the reaction along with a number of other properties that directly influence it. To investigate the photocycloaddition reaction, we began by studying the effects of different solvent environments on the ESIPT reaction in 3-hydroxyflavone since this underlying reaction is sensitive to the solvent environment and directly influences the cycloaddition. To study the ESIPT reaction, we developed a parallel multi-level genetic program to fit accurate empirical valence bond (EVB) potentials to ab initio data. We found that simulations with our EVB potentials accurately reproduced experimentally determined reaction rates, fluorescence spectra, and vibrational frequency spectra in all solvents. Furthermore, we found that the ultrafast ESIPT process results from a combination of ballistic transfer and intramolecular vibrational redistribution. To investigate the cycloaddition reaction mechanism, we utilized the string method to obtain minimum energy paths on the ab initio potential. These calculations demonstrated that the reaction can proceed through formation of an exciplex in the S1 state, followed by a non-adiabatic transition to the ground state. In addition, we investigated the enantioselective catalysis of the reaction using alpha,alpha,alpha',alpha'-tetraaryl-1,3-dioxolan-4,5-dimethanol alcohol (TADDOL). We found that TADDOL lowered the energy
Weatherford, Charles A.; Huo, Winifred M.
1990-01-01
The Chi 1Sigma - b 3Sigma(+) transition of CO is described using the Schwinger multichannel method in the two-state approximation, in an energy range from threshold to 20 eV. The resonance structure is analyzed by performing a partial-wave decomposition and the resonance positions are established based on the typical discontinuous behavior in the K-matrix elements as well as the pi radian change in the partial-wave eigenphases. The resonance behavior is related to the concept of core-excited resonances and the 'grandparent' model of resonances. The results are related to the formation of the negative ion by carrying out bound-state calculations on the (5 sigma)(3 s sigma)-squared core-excited Rydberg state of CO(-), and the position is found to agree well with the low-energy resonance positions.
Free energy barrier for melittin reorientation from a membrane-bound state to a transmembrane state
Irudayam, Sheeba J; Berkowitz, Max L
2013-01-01
An important step in a phospholipid membrane pore formation by melittin antimicrobial peptide is a reorientation of the peptide from a surface into a transmembrane conformation. In this work we perform umbrella sampling simulations to calculate the potential of mean force (PMF) for the reorientation of melittin from a surface-bound state to a transmembrane state and provide a molecular level insight into understanding peptide and lipid properties that influence the existence of the free energy barrier. The PMFs were calculated for a peptide to lipid (P/L) ratio of 1/128 and 4/128. We observe that the free energy barrier is reduced when the P/L ratio increased. In addition, we study the cooperative effect; specifically we investigate if the barrier is smaller for a second melittin reorientation, given that another neighboring melittin was already in the transmembrane state. We observe that indeed the barrier of the PMF curve is reduced in this case, thus confirming the presence of a cooperative effect.
Ultracold Heteronuclear Mixture of Ground and Excited State Atoms
Khramov, Alexander; Dowd, William; Roy, Richard; Makrides, Constantinos; Petrov, Alexander; Kotochigova, Svetlana; Gupta, Subhadeep
2014-01-01
We report on the realization of an ultracold mixture of lithium atoms in the ground state and ytterbium atoms in the excited metastable 3P2 state. Such a mixture can support broad magnetic Feshbach resonances which may be utilized for the production of ultracold molecules with an electronic spin degree of freedom, as well as novel Efimov trimers. We investigate the interaction properties of the mixture in the presence of an external magnetic field and find an upper limit for the background interspecies two-body inelastic decay coefficient of K'2 < 3e-12 cm^3/s for the 3P2 m_J=-1 substate. We calculate the dynamic polarizabilities of the Yb 3P2 magnetic substates for a range of wavelengths, and find good agreement with our measurements at 1064nm. Our calculations also allow the identification of magic frequencies where Yb ground and metastable states are identically trapped and the determination of the interspecies van der Waals coefficients.
Excited-State Wigner Crystals in One Dimension
Rogers, Fergus J M
2016-01-01
Wigner crystals (WC) are electronic phases peculiar to low-density systems, particularly in the uniform electron gas. Since its introduction in the early twentieth century, this model has remained essential to many aspects of electronic structure theory and condensed-matter physics. Although the (lowest-energy) ground-state WC (GSWC) has been thoroughly studied, the properties of excited-state WCs (ESWCs) are basically unknown. To bridge this gap, we present a well-defined procedure to obtain an entire family of ESWCs in a one-dimensional electron gas using a symmetry-broken mean-field approach. While the GSWC is a commensurate crystal (i.e.~the number of density maxima equals the number of electrons), these ESWCs are incommensurate crystals exhibiting more or less maxima. Interestingly, they are lower in energy than the (uniform) Fermi fluid state. For some of these ESWCs we have found asymmetrical band gaps, which would lead to anisotropic conductivity. These properties are associated to unusual characteris...
Transfer matrices and excitations with matrix product states
Zauner, V.; Draxler, D.; Vanderstraeten, L.; Degroote, M.; Haegeman, J.; Rams, M. M.; Stojevic, V.; Schuch, N.; Verstraete, F.
2015-05-01
We use the formalism of tensor network states to investigate the relation between static correlation functions in the ground state of local quantum many-body Hamiltonians and the dispersion relations of the corresponding low-energy excitations. In particular, we show that the matrix product state transfer matrix (MPS-TM)—a central object in the computation of static correlation functions—provides important information about the location and magnitude of the minima of the low-energy dispersion relation(s), and we present supporting numerical data for one-dimensional lattice and continuum models as well as two-dimensional lattice models on a cylinder. We elaborate on the peculiar structure of the MPS-TM’s eigenspectrum and give several arguments for the close relation between the structure of the low-energy spectrum of the system and the form of the static correlation functions. Finally, we discuss how the MPS-TM connects to the exact quantum transfer matrix of the model at zero temperature. We present a renormalization group argument for obtaining finite bond dimension approximations of the MPS, which allows one to reinterpret variational MPS techniques (such as the density matrix renormalization group) as an application of Wilson’s numerical renormalization group along the virtual (imaginary time) dimension of the system.
Fingerprint of topological Andreev bound states in phase-dependent heat transport
Sothmann, Björn; Hankiewicz, Ewelina M.
2016-08-01
We demonstrate that phase-dependent heat currents through superconductor-topological insulator Josephson junctions provide a useful tool to probe the existence of topological Andreev bound states, even for multichannel surface states. We predict that in the tunneling regime topological Andreev bound states lead to a minimum of the thermal conductance for a phase difference ϕ =π , in clear contrast to a maximum of the thermal conductance at ϕ =π that occurs for trivial Andreev bound states in superconductor-normal-metal tunnel junctions. This opens up the possibility that phase-dependent heat transport can distinguish between topologically trivial and nontrivial 4 π modes. Furthermore, we propose a superconducting quantum interference device geometry where phase-dependent heat currents can be measured using available experimental technology.
Tunable Plasmonic Reflection by Bound 1D Electron States in a 2D Dirac Metal.
Jiang, B-Y; Ni, G X; Pan, C; Fei, Z; Cheng, B; Lau, C N; Bockrath, M; Basov, D N; Fogler, M M
2016-08-19
We show that the surface plasmons of a two-dimensional Dirac metal such as graphene can be reflected by linelike perturbations hosting one-dimensional electron states. The reflection originates from a strong enhancement of the local optical conductivity caused by optical transitions involving these bound states. We propose that the bound states can be systematically created, controlled, and liquidated by an ultranarrow electrostatic gate. Using infrared nanoimaging, we obtain experimental evidence for the locally enhanced conductivity of graphene induced by a carbon nanotube gate, which supports this theoretical concept.
X(3872) and Bound State Problem of D~0(D)*~0((D)~0D*~0)
Institute of Scientific and Technical Information of China (English)
LIU Tan-rui; LIU Xiang; DENG Wei-zhen
2009-01-01
We have performed a dynamical calculation of the bound state problem of D~0(D)~(*0) by considering the pion and sigma meson exchange potential.Our preliminary analysis disfavors the molecular interpretation of X(3872) if we use the experimental D~* Dπ coupling constant g=0.59 and a reasonable cutoff around 1 GeV,which is the typical hadronic scale.In contrast,there probably exists a loosely bound S-wave B (-B)~* molecular state.Such a molecular state would be rather stable since its dominant decay mode is the radiative decay through B~*→Bγ.
Tunable Plasmonic Reflection by Bound 1D Electron States in a 2D Dirac Metal
Jiang, B.-Y.; Ni, G. X.; Pan, C.; Fei, Z.; Cheng, B.; Lau, C. N.; Bockrath, M.; Basov, D. N.; Fogler, M. M.
2016-08-01
We show that the surface plasmons of a two-dimensional Dirac metal such as graphene can be reflected by linelike perturbations hosting one-dimensional electron states. The reflection originates from a strong enhancement of the local optical conductivity caused by optical transitions involving these bound states. We propose that the bound states can be systematically created, controlled, and liquidated by an ultranarrow electrostatic gate. Using infrared nanoimaging, we obtain experimental evidence for the locally enhanced conductivity of graphene induced by a carbon nanotube gate, which supports this theoretical concept.
Study of BB ¯*/DD ¯* bound states in a Bethe-Salpeter approach
He, Jun
2014-10-01
In this work the BB ¯*/DD ¯* system is studied in the Bethe-Salpeter approach with quasipotential approximation. In our calculation both direct and cross diagrams are included in the one-boson-exchange potential. The numerical results indicate the existence of an isoscalar bound state DD ¯* with JPC=1++, which may be related to the X(3872). In the isovector sector, no bound state is produced from the interactions of DD ¯* and BB ¯*, which suggests the molecular state explanations for Zb(10610) and Zc(3900) are excluded.
In-medium mathaccent "7016relax K- and eta -meson Interactions and Bound States
Gal, A.; Friedman, E.; Barnea, N.; Cieplý, A.; Mareš, J.; Gazda, D.
The role played by subthreshold meson-baryon dynamics is demonstrated in kaonic-atom, Kbar-nuclear and eta-nuclear bound-state calculations within in-medium models of Kbar-N and eta-N interactions. New analyses of kaonic atom data reveal appreciable multi-nucleon contributions. Calculations of eta-nuclear bound states show, in particular, that the eta-N scattering length is not a useful indicator of whether or not eta mesons bind in nuclei nor of the widths anticipated for such states.
Ground-state and excited-state structures of tungsten-benzylidyne complexes
Energy Technology Data Exchange (ETDEWEB)
Lovaasen, B. M.; Lockard, J. V.; Cohen, B. W.; Yang, S.; Zhang, X.; Simpson, C. K.; Chen, L. X.; Hopkins, M. D. (Chemical Sciences and Engineering Division); ( XSD); (The Univ. of Chicago)
2012-01-01
The molecular structure of the tungsten-benzylidyne complex trans-W({triple_bond}CPh)(dppe){sub 2}Cl (1; dppe = 1,2-bis(diphenylphosphino)ethane) in the singlet (d{sub xy}){sup 2} ground state and luminescent triplet (d{sub xy}){sup 1}({pi}*(WCPh)){sup 1} excited state (1*) has been studied using X-ray transient absorption spectroscopy, X-ray crystallography, and density functional theory (DFT) calculations. Molecular-orbital considerations suggest that the W-C and W-P bond lengths should increase in the excited state because of the reduction of the formal W-C bond order and decrease in W {yields} P {pi}-backbonding, respectively, between 1 and 1*. This latter conclusion is supported by comparisons among the W-P bond lengths obtained from the X-ray crystal structures of 1, (d{sub xy}){sup 1}-configured 1{sup +}, and (d{sub xy}){sup 2} [W(CPh)(dppe){sub 2}(NCMe)]{sup +} (2{sup +}). X-ray transient absorption spectroscopic measurements of the excited-state structure of 1* reveal that the W-C bond length is the same (within experimental error) as that determined by X-ray crystallography for the ground state 1, while the average W-P/W-Cl distance increases by 0.04 {angstrom} in the excited state. The small excited-state elongation of the W-C bond relative to the M-E distortions found for M({triple_bond}E)L{sub n} (E = O, N) compounds with analogous (d{sub xy}){sup 1}({pi}*(ME)){sup 1} excited states is due to the {pi} conjugation within the WCPh unit, which lessens the local W-C {pi}-antibonding character of the {pi}*(WCPh) lowest unoccupied molecular orbital (LUMO). These conclusions are supported by DFT calculations on 1 and 1*. The similar core bond distances of 1, 1{sup +}, and 1* indicates that the inner-sphere reorganization energy associated with ground- and excited-state electron-transfer reactions is small.
Andreev and Majorana bound states in single and double quantum dot structures
Silva, Joelson F.; Vernek, E.
2016-11-01
We present a numerical study of the emergence of Majorana and Andreev bound states in a system composed of two quantum dots, one of which is coupled to a conventional superconductor, SC1, and the other connects to a topological superconductor, SC2. By controlling the interdot coupling we can drive the system from two single (uncoupled) quantum dots to double (coupled) dot system configurations. We employ a recursive Green’s function technique that provides us with numerically exact results for the local density of states of the system. We first show that in the uncoupled dot configuration (single dot behavior) the Majorana and the Andreev bound states appear in an individual dot in two completely distinct regimes. Therefore, they cannot coexist in the single quantum dot system. We then study the coexistence of these states in the coupled double dot configuration. In this situation we show that in the trivial phase of SC2, the Andreev states are bound to an individual quantum dot in the atomic regime (weak interdot coupling) or extended over the entire molecule in the molecular regime (strong interdot coupling). More interesting features are actually seen in the topological phase of SC2. In this case, in the atomic limit, the Andreev states appear bound to one of the quantum dots while a Majorana zero mode appears in the other one. In the molecular regime, on the other hand, the Andreev bound states take over the entire molecule while the Majorana state remains always bound to one of the quantum dots.
Search for $\\eta$'(958)-nucleus bound states by (p,d) reaction at GSI and FAIR
Fujioka, H; Benlliure, J; Brinkmann, K -T; Friedrich, S; Geissel, H; Gellanki, J; Guo, C; Gutz, E; Haettner, E; Harakeh, M N; Hayano, R S; Higashi, Y; Hirenzaki, S; Hornung, C; Igarashi, Y; Ikeno, N; Itahashi, K; Iwasaki, M; Jido, D; Kalantar-Nayestanaki, N; Kanungo, R; Knoebel, R; Kurz, N; Metag, V; Mukha, I; Nagae, T; Nagahiro, H; Nanova, M; Nishi, T; Ong, H J; Pietri, S; Prochazka, A; Rappold, C; Reiter, M P; Rodríguez-Sánchez, J L; Scheidenberger, C; Simon, H; Sitar, B; Strmen, P; Sun, B; Suzuki, K; Szarka, I; Takechi, M; Tanaka, Y K; Tanihata, I; Terashima, S; Watanabe, Y N; Weick, H; Widmann, E; Winfield, J S; Xu, X; Yamakami, H; Zhao, J
2015-01-01
The mass of the {\\eta}' meson is theoretically expected to be reduced at finite density, which indicates the existence of {\\eta}'-nucleus bound states. To investigate these states, we perform missing-mass spectroscopy for the (p, d) reaction near the {\\eta}' production threshold. The overview of the experimental situation is given and the current status is discussed.
Normalization and perturbation theory for tightly bound states of the spinor Bethe-Salpeter equation
L.G. Suttorp
1976-01-01
The normalisation integrals for the tightly-bound-state solutions of the spinor Bethe-Salpeter equation that have been derived recently are evaluated. Ghost states are found to appear when the continuous parameters characterising the type of fermion-boson interaction reach a critical value. Perturba
Rapisarda, P.; Trentelman, H.L.; Minh, H.B.
2013-01-01
We illustrate an algorithm that starting from the image representation of a strictly bounded-real system computes a minimal balanced state variable, from which a minimal balanced state realization is readily obtained. The algorithm stems from an iterative procedure to compute a storage function, bas
DEFF Research Database (Denmark)
Zhang, Wenkai; Kjær, Kasper Skov; Alonso-Mori, Roberto
2017-01-01
state lifetime of iron based complexes due to spin crossover-the extremely fast intersystem crossing and internal conversion to high spin metal-centered excited states. We revitalize a 30 year old synthetic strategy for extending the MLCT excited state lifetimes of iron complexes by making mixed ligand...... iron complexes with four cyanide (CN-;) ligands and one 2,2′-bipyridine (bpy) ligand. This enables MLCT excited state and metal-centered excited state energies to be manipulated with partial independence and provides a path to suppressing spin crossover. We have combined X-ray Free-Electron Laser (XFEL......-visible measurement probes allowed electronic transitions between valence states making it sensitive to ligand-centered electronic states such as MLCT states, whereas the Kβ fluorescence spectroscopy provides a sensitive measure of changes in the Fe spin state characteristic of metal-centered excited states. We...
Excited-State Dynamics in Colloidal Semiconductor Nanocrystals.
Rabouw, Freddy T; de Mello Donega, Celso
2016-10-01
Colloidal semiconductor nanocrystals have attracted continuous worldwide interest over the last three decades owing to their remarkable and unique size- and shape-, dependent properties. The colloidal nature of these nanomaterials allows one to take full advantage of nanoscale effects to tailor their optoelectronic and physical-chemical properties, yielding materials that combine size-, shape-, and composition-dependent properties with easy surface manipulation and solution processing. These features have turned the study of colloidal semiconductor nanocrystals into a dynamic and multidisciplinary research field, with fascinating fundamental challenges and dazzling application prospects. This review focuses on the excited-state dynamics in these intriguing nanomaterials, covering a range of different relaxation mechanisms that span over 15 orders of magnitude, from a few femtoseconds to a few seconds after photoexcitation. In addition to reviewing the state of the art and highlighting the essential concepts in the field, we also discuss the relevance of the different relaxation processes to a number of potential applications, such as photovoltaics and LEDs. The fundamental physical and chemical principles needed to control and understand the properties of colloidal semiconductor nanocrystals are also addressed.
Explicit formula for the Holevo bound for two-parameter qubit-state estimation problem
Suzuki, Jun
2016-04-01
The main contribution of this paper is to derive an explicit expression for the fundamental precision bound, the Holevo bound, for estimating any two-parameter family of qubit mixed-states in terms of quantum versions of Fisher information. The obtained formula depends solely on the symmetric logarithmic derivative (SLD), the right logarithmic derivative (RLD) Fisher information, and a given weight matrix. This result immediately provides necessary and sufficient conditions for the following two important classes of quantum statistical models; the Holevo bound coincides with the SLD Cramér-Rao bound and it does with the RLD Cramér-Rao bound. One of the important results of this paper is that a general model other than these two special cases exhibits an unexpected property: the structure of the Holevo bound changes smoothly when the weight matrix varies. In particular, it always coincides with the RLD Cramér-Rao bound for a certain choice of the weight matrix. Several examples illustrate these findings.
Ground States and Excited States in a Tunable Graphene Quantum Dot
Institute of Scientific and Technical Information of China (English)
WANG Lin-Jun; CAO Gang; TU Tao; LI Hai-Ou; ZHOU Cheng; HAO Xiao-Jie; GUO Guang-Can; GUO Guo-Ping
2011-01-01
We prepare an etched gate tunable quantum dot in single-layer graphene and present transport measurement in this system. We extract the information of the ground states and excited states of the graphene quantum dot, as denoted by the presence of characteristic Coulomb blockade diamond diagrams. The results demonstrate that the quantum dot in single-layer graphene bodes well in future quantum transport study and quantum computing applications.%@@ We prepare an etched gate tunable quantum dot in single-layer graphene and present transport measurement in this system.We extract the information of the ground states and excited states of the graphene quantum dot, as denoted by the presence of characteristic Coulomb blockade diamond diagrams.The results demonstrate that the quantum dot in single-layer graphene bodes well in future quantum transport study and quantum computing applications.
Short-lived two-soliton bound states in weakly perturbed nonlinear Schrodinger equation.
Dmitriev, Sergey V.; Shigenari, Takeshi
2002-06-01
Resonant soliton collisions in the weakly discrete nonlinear Schrodinger equation are studied numerically. The fractal nature of the soliton scattering, described in our previous works, is investigated in detail. We demonstrate that the fractal scattering pattern is related to the existence of the short-lived two-soliton bound states. The bound state can be regarded as a two-soliton quasiparticle of a new type, different from the breather. We establish that the probability P of a bound state with the lifetime L follows the law P approximately L(-3). In the frame of a simple two-particle model, we derive the nonlinear map, which generates the fractal pattern similar to that observed in the numerical study of soliton collisions. (c) 2002 American Institute of Physics.
Majorana bound state in a coupled quantum-dot hybrid-nanowire system
Deng, M. T.; Vaitiekėnas, S.; Hansen, E. B.; Danon, J.; Leijnse, M.; Flensberg, K.; Nygård, J.; Krogstrup, P.; Marcus, C. M.
2016-12-01
Hybrid nanowires combining semiconductor and superconductor materials appear well suited for the creation, detection, and control of Majorana bound states (MBSs). We demonstrate the emergence of MBSs from coalescing Andreev bound states (ABSs) in a hybrid InAs nanowire with epitaxial Al, using a quantum dot at the end of the nanowire as a spectrometer. Electrostatic gating tuned the nanowire density to a regime of one or a few ABSs. In an applied axial magnetic field, a topological phase emerges in which ABSs move to zero energy and remain there, forming MBSs. We observed hybridization of the MBS with the end-dot bound state, which is in agreement with a numerical model. The ABS/MBS spectra provide parameters that are useful for understanding topological superconductivity in this system.
Widths of K¯-nuclear deeply bound states in a dynamical model
Mareš, J.; Friedman, E.; Gal, A.
2005-01-01
The relativistic mean field (RMF) model is applied to a system of nucleons and a Kbar meson, interacting via scalar and vector boson fields. The model incorporates the standard RMF phenomenology for bound nucleons and, for the Kbar meson, it relates to low-energy Kbar N and K- atom phenomenology. Deeply bound Kbar nuclear states are generated dynamically across the periodic table and are exhibited for 12C and 16O over a wide range of binding energies. Substantial polarization of the core nucleus is found for these light nuclei. Absorption modes are also included dynamically, considering explicitly both the resulting compressed nuclear density and the reduced phase space for Kbar absorption from deeply bound states. The behavior of the calculated width as function of the Kbar binding energy is studied in order to explore limits on the possible existence of narrow Kbar nuclear states.
Bound states of two-dimensional Schr\\"{o}dinger-Newton equations
Stubbe, Joachim
2008-01-01
We prove an existence and uniqueness result for ground states and for purely angular excitations of two-dimensional Schr\\"{o}dinger-Newton equations. From the minimization problem for ground states we obtain a sharp version of a logarithmic Hardy-Littlewood-Sobolev type inequality.
Bound entanglement and entanglement bounds
Energy Technology Data Exchange (ETDEWEB)
Sauer, Simeon [Physikalisch-Astronomische Fakultaet, Friedrich-Schiller-Univesitaet Jena (Germany)]|[Physikalisches Institut, Albert-Ludwigs-Universitaet Freiburg, Hermann-Herder-Strasse 3, D-79104 Freiburg (Germany); Melo, Fernando de; Mintert, Florian; Buchleitner, Andreas [Physikalisches Institut, Albert-Ludwigs-Universitaet Freiburg, Hermann-Herder-Strasse 3, D-79104 Freiburg (Germany)]|[Max-Planck-Institut fuer Physik komplexer Systeme, Noethnitzer Str.38, D-01187 Dresden (Germany); Bae, Joonwoo [School of Computational Sciences, Korea Institute for Advanced Study, Seoul 130-012 (Korea); Hiesmayr, Beatrix [Faculty of Physics, University of Vienna, Boltzmanngasse 5, A-1090 Vienna (Austria)
2008-07-01
We investigate the separability of Bell-diagonal states of two qutrits. By using lower bounds to algebraically estimate concurrence, we find convex regions of bound entangled states. Some of these regions exactly coincide with the obtained results when employing optimal entanglement witnesses, what shows that the lower bound can serve as a precise detector of entanglement. Some hitherto unknown regions of bound entangled states were discovered with this approach, and delimited efficiently.
Gamiz-Hernandez, Ana P; Magomedov, Artiom; Hummer, Gerhard; Kaila, Ville R I
2015-02-12
Proton-coupled electron transfer (PCET) processes are elementary chemical reactions involved in a broad range of radical and redox reactions. Elucidating fundamental PCET reaction mechanisms are thus of central importance for chemical and biochemical research. Here we use quantum chemical density functional theory (DFT), time-dependent density functional theory (TDDFT), and the algebraic diagrammatic-construction through second-order (ADC(2)) to study the mechanism, thermodynamic driving force effects, and reaction barriers of both ground state proton transfer (pT) and photoinduced proton-coupled electron transfer (PCET) between nitrosylated phenyl-phenol compounds and hydrogen-bonded t-butylamine as an external base. We show that the obtained reaction barriers for the ground state pT reactions depend linearly on the thermodynamic driving force, with a Brønsted slope of 1 or 0. Photoexcitation leads to a PCET reaction, for which we find that the excited state reaction barrier depends on the thermodynamic driving force with a Brønsted slope of 1/2. To support the mechanistic picture arising from the static potential energy surfaces, we perform additional molecular dynamics simulations on the excited state energy surface, in which we observe a spontaneous PCET between the donor and the acceptor groups. Our findings suggest that a Brønsted analysis may distinguish the ground state pT and excited state PCET processes.
Lorentz contraction of bound states in 1+1 dimensional gauge theory
Järvinen, M.
2004-09-01
We consider the Lorentz contraction of a fermion-antifermion bound state in 1+1 dimensional QED. In 1+1 dimensions the absence of physical, propagating photons allows us to explicitly solve the weak coupling limit α≪m2 of the Bethe-Salpeter bound state equation in any Lorentz frame. In a time-ordered formalism it is seen that all pair production is suppressed in this limit. The wave function is shown to contract while the mass spectrum is invariant under boosts.
The Analogue of the Aharonov-Bohm Effect for Bound States for Neutral Particles
Bakke, Knut; Furtado, C.
We study the analogue of the Aharonov-Bohm effect for bound states for a neutral particle with a permanent magnetic dipole moment interacting with an external field. We consider a neutral particle confined to moving between two coaxial cylinders and show the dependence of the energy levels on the Aharonov-Casher quantum flux. Moreover, we show that the same flux dependence of the bound states can be found when the neutral particle is confined to a one-dimensional quantum ring and a quantum dot, and we also calculate the persistent currents in each case.
Bound states of the $\\phi^4$ model via the Non-Perturbative Renormalization Group
Rose, F; Leonard, F; Delamotte, B
2016-01-01
Using the nonperturbative renormalization group, we study the existence of bound states in the symmetry-broken phase of the scalar $\\phi^4$ theory in all dimensions between two and four and as a function of the temperature. The accurate description of the momentum dependence of the two-point function, required to get the spectrum of the theory, is provided by means of the Blaizot--M\\'endez-Galain--Wschebor approximation scheme. We confirm the existence of a bound state in dimension three, with a mass within 1% of previous Monte-Carlo and numerical diagonalization values.
The Relativistic Three-Body Bound State in Three-Dimensions
Directory of Open Access Journals (Sweden)
Hadizadeh M. R.
2016-01-01
Full Text Available Studying of the relativistic three-body bound state in a three-dimensional (3D approach is a necessary first step in a process to eventually perform scattering calculations at GeV energies, where partial-wave expansions are not useful. To this aim we recently studied relativistic effects in the binding energy and for the first time, obtained the relativistic 3B wave function [1]. The relativistic Faddeev integral equations for the bound state are formulated in terms of momentum vectors, and relativistic invariance is incorporated within the framework of Poincaré invariant quantum mechanics.
Nature of the lowest excited states of neutral polyenyl radicals and polyene radical cations
Starcke, Jan Hendrik; Wormit, Michael; Dreuw, Andreas
2009-10-01
Due to the close relation of the polyenyl radicals C2n+1H2n+3• and polyene radical cations C2nH2n+2•+ to the neutral linear polyenes, one may suspect their excited states to possess substantial double excitation character, similar to the famous S1 state of neutral polyenes and thus to be equally problematic for simple excited state theories. Using the recently developed unrestricted algebraic-diagrammatic construction scheme of second order perturbation theory and the equation-of-motion coupled-cluster method, the vertical excitation energies, their corresponding oscillator strengths, and the nature of the wave functions of the lowest excited electronic states of the radicals are calculated and analyzed in detail. For the polyenyl radicals two one-photon allowed states are found as D1 and D4 states, with two symmetry-forbidden D2 and D3 states in between, while in the polyene radical cations D1 and D2 are allowed and D3 is forbidden. The order of the states is conserved with increasing chain length. It is found that all low-lying excited states exhibit a significant but similar amount of doubly excited configuration in their wave functions of 15%-20%. Using extrapolation, predictions for the excitation energies of the five lowest excited states of the polyene radical cations are made for longer chain lengths.
Upper Bounds on the Degeneracy of the Ground State in Quantum Field Models
Directory of Open Access Journals (Sweden)
Asao Arai
2016-01-01
Full Text Available Axiomatic abstract formulations are presented to derive upper bounds on the degeneracy of the ground state in quantum field models including massless ones. In particular, given is a sufficient condition under which the degeneracy of the ground state of the perturbed Hamiltonian is less than or equal to the degeneracy of the ground state of the unperturbed one. Applications of the abstract theory to models in quantum field theory are outlined.
Study of hyperfine structure in simple atoms and precision tests of the bound state QED
Energy Technology Data Exchange (ETDEWEB)
Karshenboim, S.G. [Max-Planck-Institut fuer Quantenoptik, 85748 Garching (Germany); D.I. Mendeleev Institute for Metrology (VNIIM), St. Petersburg 190005 (Russian Federation); Eidelman, S.I. [Budker Institute for Nuclear Physics and Novosibirsk State University, Novosibirsk, 630090 (Russian Federation); Fendel, P. [Max-Planck-Institut fuer Quantenoptik, 85748 Garching (Germany); Ivanov, V.G. [Pulkovo Observatory, St. Petersburg 196140 (Russian Federation); Kolachevsky, N.N. [P.N. Lebedev Physics Institute, Moscow, 119991 (Russian Federation); Shelyuto, V.A. [D.I. Mendeleev Institute for Metrology (VNIIM), St. Petersburg 190005 (Russian Federation); Haensch, T.W. [Max-Planck-Institut fuer Quantenoptik, 85748 Garching (Germany)
2006-12-15
We consider the most accurate tests of bound state QED, precision theory of simple atoms, related to the hyperfine splitting in light hydrogen-like atoms. We discuss the HFS interval of the 1s state in muonium and positronium and of the 2s state in hydrogen, deuterium and helium-3 ion. We summarize their QED theory and pay attention to involved effects of strong interactions. We also consider recent optical measurements of the 2s HFS interval in hydrogen and deuterium.
Study of hyperfine structure in simple atoms and precision tests of the bound state QED
Karshenboim, S G; Fendel, P; Ivanov, V G; Kolachevsky, N N; Shelyuto, V A; Hänsch, T W
2006-01-01
We consider the most accurate tests of bound state QED, precision theory of simple atoms, related to the hyperfine splitting in light hydrogen-like atoms. We discuss the HFS interval of the 1s state in muonium and positronium and of the 2s state in hydrogen, deuterium and helium-3 ion. We summarize their QED theory and pay attention to involved effects of strong interactions. We also consider recent optical measurements of the 2s HFS interval in hydrogen and deuterium.
Ikot, A. N.; Obong, H. P.; Abbey, T. M.; Zare, S.; Ghafourian, M.; Hassanabadi, H.
2016-09-01
In this article we use supersymmetry quantum mechanics and factorization methods to study the bound and scattering state of Klein-Gordon equation with deformed Hulthen plus deformed hyperbolical potential for arbitrary state in D-dimensions. The analytic relativistic bound state eigenvalues and the scattering phase factor are found in closed form. We report on the numerical results for the bound state energy in D-dimensions.
Electron delocalization and aromaticity in low-lying excited states of archetypal organic compounds.
Feixas, Ferran; Vandenbussche, Jelle; Bultinck, Patrick; Matito, Eduard; Solà, Miquel
2011-12-14
Aromaticity is a property usually linked to the ground state of stable molecules. Although it is well-known that certain excited states are unquestionably aromatic, the aromaticity of excited states remains rather unexplored. To move one step forward in the comprehension of aromaticity in excited states, in this work we analyze the electron delocalization and aromaticity of a series of low-lying excited states of cyclobutadiene, benzene, and cyclooctatetraene with different multiplicities at the CASSCF level by means of electron delocalization measures. While our results are in agreement with Baird's rule for the aromaticity of the lowest-lying triplet excited state in annulenes having 4nπ-electrons, they do not support Soncini and Fowler's generalization of Baird's rule pointing out that the lowest-lying quintet state of benzene and septet state of cyclooctatetraene are not aromatic.
Investigation of the $nn\\Lambda$ bound state in pionless effective theory
Ando, Shung-Ichi; Oh, Yongseok
2015-01-01
The possibility of an $nn\\Lambda$ bound state is investigated in the framework of pionless effective field theory at leading order. A system of coupled integral equations are constructed in the spin-isospin basis, of which numerical solutions are investigated. In particular, we make use of the limit cycle behavior, i.e., cyclic singularities of coupled integral equations of the system, which would be associated with the formation of a three-body bound state, so-called the Efimov state, in the unitary limit. Furthermore, we find that, when the sharp momentum cutoff introduced in the integral equations is taken significantly larger than the hard scale of the effective theory, the coupling of a three-body contact interaction becomes cyclically singular indicating the onset of Efimov-like bound state formation. However, the paucity of empirical information to determine the parameters of the theory precludes a definitive conclusion on the existence of such a bound state. As a simple test of the feasibility of the ...
Energy Technology Data Exchange (ETDEWEB)
Li, Shihong [Department of Radiology, University of California, San Diego, California 92103-8226 (United States); Department of Radiology, Hua Dong Hospital, Fudan University, Shanghai 200040 (China); Yancheng Medical College, Jiangsu (China); The First People' s Hospital of Yancheng City, Jiangsu 224005 (China); Chang, Eric Y.; Chung, Christine B. [VA San Diego Healthcare System, San Diego, California 92161 and Department of Radiology, University of California, San Diego, California 92103-8226 (United States); Bae, Won C.; Du, Jiang, E-mail: jiangdu@ucsd.edu [Department of Radiology, University of California, San Diego, California 92103-8226 (United States); Hua, Yanqing [Department of Radiology, Hua Dong Hospital, Fudan University, Shanghai 200040 (China); Zhou, Yi [The First People' s Hospital of Yancheng City, Jiangsu 224005 (China)
2014-02-15
Purpose: The purpose of this study was to investigate the effect of excitation, fat saturation, long T2 saturation, and adiabatic inversion pulses on ultrashort echo time (UTE) imaging with bicomponent analysis of bound and free water in cortical bone for potential applications in osteoporosis. Methods: Six bovine cortical bones and six human tibial midshaft samples were harvested for this study. Each bone sample was imaged with eight sequences using 2D UTE imaging at 3T with half and hard excitation pulses, without and with fat saturation, long T2 saturation, and adiabatic inversion recovery (IR) preparation pulses. Single- and bicomponent signal models were utilized to calculate the T2{sup *}s and/or relative fractions of short and long T2{sup *}s. Results: For all bone samples UTE T2{sup *} signal decay showed bicomponent behavior. A higher short T2{sup *} fraction was observed on UTE images with hard pulse excitation compared with half pulse excitation (75.6% vs 68.8% in bovine bone, 79.9% vs 73.2% in human bone). Fat saturation pulses slightly reduced the short T2{sup *} fraction relative to regular UTE sequences (5.0% and 2.0% reduction, respectively, with half and hard excitation pulses for bovine bone, 6.3% and 8.2% reduction, respectively, with half and hard excitation pulses for human bone). Long T2 saturation pulses significantly reduced the long T2{sup *} fraction relative to regular UTE sequence (18.9% and 17.2% reduction, respectively, with half and hard excitation pulses for bovine bone, 26.4% and 27.7% reduction, respectively, with half and hard excitation pulses for human bone). With IR-UTE preparation the long T2{sup *} components were significantly reduced relative to regular UTE sequence (75.3% and 66.4% reduction, respectively, with half and hard excitation pulses for bovine bone, 87.7% and 90.3% reduction, respectively, with half and hard excitation pulses for human bone). Conclusions: Bound and free water T2{sup *}s and relative fractions can
State-selective high-energy excitation of nuclei by resonant positron annihilation
Directory of Open Access Journals (Sweden)
Nikolay A. Belov
2015-02-01
Full Text Available In the annihilation of a positron with a bound atomic electron, the virtual γ photon created may excite the atomic nucleus. We put forward this effect as a spectroscopic tool for an energy-selective excitation of nuclear transitions. This scheme can efficiently populate nuclear levels of arbitrary multipolarities in the MeV regime, including giant resonances and monopole transitions. In certain cases, it may have higher cross sections than the conventionally used Coulomb excitation and it can even occur with high probability when the latter is energetically forbidden.
DEFF Research Database (Denmark)
Wallace-Williams, Stacie E.; Møller, Søren; Goldbeck, Robert A.;
1993-01-01
The shapes of the fluorescence emission and lowest excited singlet-state absorption spectra of all-trans-1,4- diphenylbutadiene (DPB) in hydrocarbon solvents vary with excitation wavelength when exciting on the extreme red edge of the ground-state absorption spectrum. This contrasts with the wave......The shapes of the fluorescence emission and lowest excited singlet-state absorption spectra of all-trans-1,4- diphenylbutadiene (DPB) in hydrocarbon solvents vary with excitation wavelength when exciting on the extreme red edge of the ground-state absorption spectrum. This contrasts...... changes in DPB can be explained in terms of an excitation wavelength-dependent production of s-cis and s-trans rotamer populations in the excited state. The DPB fluorescence emission spectrum was resolved into s-cis and s-trans components. The vibronic structure of the s-cis fluorescence spectrum...
Cho, Dae Won; Kim, Yong Hee; Yoon, Minjoong; Jeoung, Sae Chae; Kim, Dongho
1994-08-01
The picosecond time-resolved fluorescence and transient absorption behavior of piroxicam at room temperature are reported. The keto tautomer in the excited singlet state ( 1K*) formed via the fast intramolecular proton transfer (≈ 20 ps) is observed. The short-lived (7.5 ns) triplet state of keto tauomer ( 3K*) is generated from 1K * in toluene whereas it is hardly observed in ethanol. Consequently, rapid reverse proton transfer takes place from 3K * to the enol triplet state ( 3E *.
Filatov, Mikhail A.
2015-10-13
The synthesis and photophysical characterization of a palladium(II) porphyrin – anthracene dyad bridged via short and conformationally rigid bicyclo[2.2.2]octadiene spacer were achieved. A spectroscopic investigation of the prepared molecule in solution has been undertaken to study electronic energy transfer in excited singlet and triplet states between the anthracene and porphyrin units. By using steady-state and time-resolved photoluminescence spectroscopy it was shown that excitation of the singlet excited state of the anthracene leads to energy transfer to the lower-lying singlet state of porphyrin. Alternatively, excitation of the porphyrin followed by intersystem crossing to the triplet state leads to very fast energy transfer to the triplet state of anthracene. The rate of this energy transfer has been determined by transient absorption spectroscopy. Comparative studies of the dynamics of triplet excited states of the dyad and reference palladium octaethylporphyrin (PdOEP) have been performed.
Aspects of Majorana Bound States in One-Dimensional Systems with and without Time-Reversal Symmetry
DEFF Research Database (Denmark)
Wölms, Konrad Udo Hannes
bound states in the measurement still has to be understood better. And example would be the frequently performed tunnel probe measurement on Majorana bound states [26, 40, 41]. A second reason why Majorana bound states are interesting is their potential application to a certain quantum computation...... scheme. This scheme, called topological quantum computation, relies on the braiding of so-called non-abelian anyons in order to perform computations [18]. Majorana bound states are the simplest example of such non-abelian anyons. No other non-abelian anyons have been realized experimentally yet, which...... puts further focus on the study of Majorana bound states. Additionally to probing Majorana bound states, their use in topological quantum computation also requires them to be manipulated. This also poses an interesting problem for both experimentalists and theorists [25, 27]. We can summarize...
Onyeaju, M. C.; Ikot, A. N.; Chukwuocha, E. O.; Obong, H. P.; Zare, S.; Hassanabadi, H.
2016-09-01
Scattering and bound states solution for the one-dimensional Klein-Gordon particle with Hylleraas potential is presented within the frame work of position dependent effective mass formalism. We calculate in detail the reflection and transmission coefficients using the properties of hypergeometric functions and the equation of continuity of the wave functions.
Bound States of the S-Wave Equation with Equal Scalar and Vector Standard Eckart Potential
Institute of Scientific and Technical Information of China (English)
Eser Ol(g)ar; Ramazan Ko(c); Hayriye Tütüncüler
2006-01-01
@@ A supersymmetric technique for the bound-state solutions of the s-wave Klein-Gordon equation with equal scalar and vector standard Eckart-type potential is proposed. Its exact solutions are obtained. Possible generalization of our approach is outlined.
Resonances from QCD bound states and the 750 GeV diphoton excess
Kats, Yevgeny
2016-01-01
Pair production of colored particles is in general accompanied by production of QCD bound states (onia) slightly below the pair-production threshold. Bound state annihilation leads to resonant signals, which in some cases are easier to see than the decays of the pair-produced constituents. In a previous paper (arXiv:1204.1119) we estimated the bound state signals, at leading order and in the Coulomb approximation, for particles with various spins, color representations and electric charges, and used 7 TeV ATLAS and CMS resonance searches to set rough limits. Here we update our results to include 8 and 13 TeV data. We find that the recently reported diphoton excesses near 750 GeV could indeed be due to a bound state of this kind. A narrow resonance of the correct size could be obtained for a color-triplet scalar with electric charge -4/3 and mass near 375 GeV, if (as a recent lattice computation suggests) the wave function at the origin is somewhat larger than anticipated. Pair production of this particle coul...
Spin(p+1, p+1) covariant Dp-brane bound states
Sundell, P
2001-01-01
We construct Spin(p + 1, p + 1) covariant Dp-brane bound states by using the fact that the potentials in the RR sector of toroidically compactified type Ii supergravity transform as a chiral spinor of the T duality group. As an application, we show the invariance of the zero-force condition for a pr
The Need for an Upward Bound Project at Bowie State College.
Gill, Wanda E.
Reasons that Bowie State College in Maryland should participate in the Upward Bound Project are discussed, with attention to geographic and demographic characteristics of the area, school characteristics, and needed services. The college historically has provided educational opportunities for black, disadvantaged students and has been successful…
Liu, H; Glöckle, W; Elster, Ch.
2002-01-01
The Faddeev equations for the three-body bound state are solved directly as thre e-dimensional integral equations without employing partial wave decomposition. Two-body forces of the Malfliet-Tjon type and simple spin independent genuine three-body forces are considered for the calculation of the three-body binding energy.
Precision study of positronium and precision tests of the bound state QED
Karshenboim, Savely G.
2002-01-01
Despite its very short lifetime positronium provides us with a number of accurate tests of the bound state QED. In this note a brief overview of QED theory and precision experiments on the spectrum and annihilation decay of the positronium atom is presented. Special attention is paid to the accuracy of theoretical predictions.
Bound State Solutions of Klein-Gordon Equation with the Kratzer Potential
Institute of Scientific and Technical Information of China (English)
M. Ko(c)ak
2007-01-01
The relativistic problem of spinless particle subject to a Kratzer potential is analysed. Bound state solutions for s-waves are found by separating the Klein-Gordon equation into two parts. Unlike the similar works in the literature, the separation make it possible to see explicitly the relativistic contributions, if any, to the solution in the non-relativistic limit.
Exact solutions of the spinor Bethe-Salpeter equation for tightly bound states
Suttorp, L.G.
1975-01-01
Exact solutions are obtained for the spinor Bethe-Salpeter equation that describes tightly bound states of spin-/sup 1///sub 2/ fermions with massless-boson exchange. The corresponding coupling constants form a discrete spectrum that depends continuously on the parameters characterizing the type of
Light Fermion Finite Mass Effects in Non-relativistic Bound States
Eiras, D; Eiras, Dolors; Soto, Joan
2000-01-01
We present analytic expressions for the vacuum polarization effects due to a light fermion with finite mass in the binding energy and in the wave function at the origin of QED and (weak coupling) QCD non-relativistic bound states. Applications to exotic atoms, \\Upsilon (1s) and t\\bar{t} production near threshold are briefly discussed.
Charmed mesic nuclei Bound D and over D states with 208Pb
Tsushima, K; Thomas, A W; Saitô, K; Landau, Rubin H
1999-01-01
We show that the $D^-$ meson will inevitably form narrow bound states with $^{208}$Pb. The experimental confirmation and comparison with the $\\bar{D}^0$ and $D^0$ will provide distinctive information on the nature of the interaction between the charmed meson and matter.
Bakke, K.
2010-10-01
We obtain the solutions of the Dirac equation when the noninertial effects of the Fermi-Walker reference frame break the relativistic Landau-Aharonov-Casher quantization, but they provide bound states in an analogous way to a Dirac neutral particle subject to Tan-Inkson quantum dot potential [W.-C. Tan, J.C. Inkson, Semicond. Sci. Technol. 11 (1996) 1635].
On the energy of bound states for magnetic Schrödinger operators
DEFF Research Database (Denmark)
Fournais, Søren; Kachmar, Ayman
2009-01-01
We provide a leading order semiclassical asymptotics of the energy of bound states for magnetic Neumann Schrödinger operators in two-dimensional (exterior) domains with smooth boundaries. The asymptotics is valid all the way up to the bottom of the essential spectrum. When the spectral parameter...
The Bound State S-matrix of the Deformed Hubbard Chain
de Leeuw, Marius; Matsumoto, Takuya
2011-01-01
In this work we use the q-oscillator formalism to construct the atypical (short) supersymmetric representations of the centrally extended Uq (su(2|2)) algebra. We then determine the S-matrix describing the scattering of arbitrary bound states. The crucial ingredient in this derivation is the affine extension of the aforementioned algebra.
Applying the relativistic quantization condition to a three-particle bound state in a periodic box
Hansen, Maxwell T
2016-01-01
Using our recently developed relativistic three-particle quantization condition, we study the finite-volume energy shift of a three-particle bound state. We reproduce the result obtained using non-relativistic quantum mechanics by Mei{\\ss}ner, R{\\'i}os and Rusetsky, and generalize the result to a moving frame.
Bound state transfer matrix for AdS5 × S5 superstring
Arutyunov, G.E.; de Leeuw, M.; Suzuki, R.; Torrielli, A.
2009-01-01
We apply the algebraic Bethe ansatz technique to compute the eigenvalues of the transfer matrix constructed from the general bound state S-matrix of the light-cone AdS5 × S5 superstring. This allows us to verify certain conjectures on the quantum characteristic function, and to extend them to the ge
Bound states of the Dirac equation with some physical potentials by the Nikiforov-Uvarov method
Energy Technology Data Exchange (ETDEWEB)
Setare, Mohammad R; Haidari, S [Department of Physics, University of Kurdistan, Pasdaran Avenue, Sanandaj (Iran, Islamic Republic of)], E-mail: rezakord@ipm.ir, E-mail: heidary.somayeh@gmail.com
2010-01-15
Exact analytical solutions for the s-wave Dirac equation with the reflectionless-type, Rosen-Morse and Manning-Rosen potentials are obtained, under the condition of spin symmetry. We obtained bound state energy eigenvalues and corresponding spinor wave function in the framework of the Nikiforov-Uvarov (NU) method.
Resonances from QCD bound states and the 750 GeV diphoton excess
Kats, Yevgeny; Strassler, Matthew J.
2016-05-01
Pair production of colored particles is in general accompanied by production of QCD bound states (onia) slightly below the pair-production threshold. Bound state annihilation leads to resonant signals, which in some cases are easier to see than the decays of the pair-produced constituents. In a previous paper ( arXiv:1204.1119 URL"/> ) we estimated the bound state signals, at leading order and in the Coulomb approximation, for particles with various spins, color representations and electric charges, and used 7 TeV ATLAS and CMS resonance searches to set rough limits. Here we update our results to include 8 and 13 TeV data. We find that the recently reported diphoton excesses near 750 GeV could indeed be due to a bound state of this kind. A narrow resonance of the correct size could be obtained for a color-triplet scalar with electric charge -4/3 and mass near 375GeV, if (as a recent lattice computation suggests) the wave function at the origin is somewhat larger than anticipated. Pair production of this particle could have evaded detection up to now. Other candidates may include a triplet scalar of charge 5/3, a triplet fermion of charge -4/3, and perhaps a sextet scalar of charge -2/3.
A new interpretation of the proton-neutron bound state The calculation of the binding energy
Mandache, N
1996-01-01
We treat the old problem of the proton-neutron bound state (the deuteron). Using a new concept of incomplete (partial) annihilation process we derive a formula for the binding energy of the deuteron, which does not contain any new constant. Some implications of this new approach are discussed.
ηN interactions in the nuclear medium. η-nuclear bound states
Mareš, J.; Barnea, N.; Cieplý, A.; Friedman, E.; Gal, A.
2016-11-01
We report on our recent study of in-medium ηN interactions and η-nuclear quasi-bound states. The ηN scattering amplitudes considered in the calculations are constructed within coupled-channel models that incorporate the S11 N*(1535) resonance. The implications of self-consistent treatment and the role played by subthreshold dynamics are discussed.
Hu, Weifeng
2015-01-01
We describe and extend the formalism of state-specific analytic density matrix renormalization group (DMRG) energy gradients, first used by Liu et al (J. Chem. Theor.Comput. 9, 4462 (2013)). We introduce a DMRG wavefunction maximum overlap following technique to facilitate state-specific DMRG excited state optimization. Using DMRG configuration interaction (DMRG-CI) gradients we relax the low-lying singlet states of a series of trans-polyenes up to C20H22. Using the relaxed excited state geometries as well as correlation functions, we elucidate the exciton, soliton, and bimagnon ("single-fission") character of the excited states, and find evidence for a planar conical intersection.
Delayed birth of distillable entanglement in the evolution of bound entangled states
Derkacz, Łukasz
2010-01-01
The dynamical creation of entanglement between three-level atoms coupled to the common vacuum is investigated. For the class of bound entangled initial states we show that the dynamics of closely separated atoms generates stationary distillable entanglement of asymptotic states. We also find that the effect of delayed sudden birth of distillable entanglement occurs in the case of atoms separated by a distance comparable with the radiation wavelength.
Reflection algebra, Yangian symmetry and bound-states in AdS/CFT
MacKay, Niall
2011-01-01
We present the `Heisenberg picture' of the reflection algebra by explicitly constructing the boundary Yangian symmetry of the AdS/CFT superstring ending on a boundary with degrees of freedom and preserving all of the bulk symmetry algebra. This enables us to present the bound-state reflection matrices in a more elegant, rapidity-difference form. We also consider the spectrum of bulk and boundary states and some automorphisms of the underlying algebras.
Bounds on probability of state transfer with respect to readout time and edge weight
Gordon, Whitney; Kirkland, Steve; Li, Chi-Kwong; Plosker, Sarah; Zhang, Xiaohong
2016-02-01
We analyze the sensitivity of a spin chain modeled by an undirected weighted connected graph exhibiting perfect state transfer to small perturbations in readout time and edge weight in order to obtain physically relevant bounds on the probability of state transfer. At the heart of our analysis is the concept of the numerical range of a matrix; our analysis of edge weight errors additionally makes use of the spectral and Frobenius norms.
Scattering resonances and two-particle bound states of the extended Hubbard model
Energy Technology Data Exchange (ETDEWEB)
Valiente, M; Petrosyan, D [Institute of Electronic Structure and Laser, FORTH, 71110 Heraklion, Crete (Greece)
2009-06-28
We present a complete derivation of two-particle states of the one-dimensional extended Bose-Hubbard model involving attractive or repulsive on-site and nearest-neighbour interactions. We find that this system possesses scattering resonances and two families of energy-dependent interaction-bound states which are not present in the Hubbard model with the on-site interaction alone. (fast track communication)
Reduced adiabatic hyperspherical basis in the Coulomb three-body bound state problem
Energy Technology Data Exchange (ETDEWEB)
Abramov, D.I. [Sankt Peterburgskij Univ., St. Petersburg (Russian Federation); Gusev, V.V. [Institut Fiziki Vysokikh Ehnergij, Protvino (Russian Federation); Ponomarev, L.I. [Rossijskij Nauchnyj Tsentr ``Kurchatovskij Inst.``, Moscow (Russian Federation)
1996-10-01
A new version of the adiabatic hyperspherical approach (AHSA) is suggested which has significant advantages for the calculation of three-body states with total angular momentum J > 0. The binding energies of all bound states of mesic molecules with normal parity are calculated by the suggested method. Comparison with results of variational calculations and the fast convergence of the method confirm its high efficiency. (orig.). 13 refs.
Two-mode excited entangled coherent states and their entanglement properties
Institute of Scientific and Technical Information of China (English)
Zhou Dong-Lin; Kuang Le-Man
2009-01-01
This paper introduces two types of two-mode excited entangled coherent states(TMEECSs)|Ψ±(α,m,n)>,studies their entanglement characteristics,and investigates the influence of photon excitations on quantum entanglement.It shows that for the state|Ψ+(α,m,m)>the two-mode photon excitations affect seriously entanglement character while the state |Ψ-(α,m,m)>is always a maximally entangled state,and shows how such states can be produced by using cavity quantum electrodynamics and quantum measurements.It finds that the entanglement amount of the TMEECSs is larger than that of the single-mode excited entangled coherent states with the same photon excitation number.
Excited-state lifetime of adenine near the first electronic band origin.
Kang, Hyuk; Chang, Jinyoung; Lee, Sang Hak; Ahn, Tae Kyu; Kim, Nam Joon; Kim, Seong Keun
2010-10-21
The excited-state lifetime of supersonically cooled adenine was measured in the gas phase by femtosecond pump-probe transient ionization as a function of excitation energy between 36 100 and 37 500cm(-1). The excited-state lifetime of adenine is ∼2ps around the 0-0 band of the (1)L(b) ππ(∗) state (36 105cm(-1)). The lifetime drops to ∼1ps when adenine is excited to the (1)L(a) ππ(∗) state with the pump energy at 36 800cm(-1) and above. The excited-state lifetimes of (1)L(a) and (1)L(b) ππ(∗) states are differentiated in accordance with previous frequency-resolved and computational studies.
Tight bound on coherent-state-based entanglement generation over lossy channels
Azuma, Koji; Koashi, Masato; Imoto, Nobuyuki
2009-01-01
The first stage of the hybrid quantum repeaters is entanglement generation based on transmission of pulses in coherent states over a lossy channel. Protocols to make entanglement with only one type of error are favorable for rendering subsequent entanglement distillation efficient. Here we provide the tight upper bound on performances of these protocols that is determined only by the channel loss. In addition, we show that this bound is achievable by utilizing a proposed protocol [arXiv:0811.3100] composed of a simple combination of linear optical elements and photon-number-resolving detectors.
Lower bounds for ballistic current and noise in non-equilibrium quantum steady states
Directory of Open Access Journals (Sweden)
Benjamin Doyon
2015-03-01
Full Text Available Let an infinite, homogeneous, many-body quantum system be unitarily evolved for a long time from a state where two halves are independently thermalized. One says that a non-equilibrium steady state emerges if there are nonzero steady currents in the central region. In particular, their presence is a signature of ballistic transport. We analyze the consequences of the current observable being a conserved density; near equilibrium this is known to give rise to linear wave propagation and a nonzero Drude peak. Using the Lieb–Robinson bound, we derive, under a certain regularity condition, a lower bound for the non-equilibrium steady-state current determined by equilibrium averages. This shows and quantifies the presence of ballistic transport far from equilibrium. The inequality suggests the definition of “nonlinear sound velocities”, which specialize to the sound velocity near equilibrium in non-integrable models, and “generalized sound velocities”, which encode generalized Gibbs thermalization in integrable models. These are bounded by the Lieb–Robinson velocity. The inequality also gives rise to a bound on the energy current noise in the case of pure energy transport. We show that the inequality is satisfied in many models where exact results are available, and that it is saturated at one-dimensional criticality.
Bound states of massive fermions in Aharonov-Bohm-like fields
Energy Technology Data Exchange (ETDEWEB)
Khalilov, V.R. [Moscow State University, Faculty of Physics, Moscow (Russian Federation)
2014-01-15
Bound states of massive fermions in Aharonov-Bohm (AB)-like fields have analytically been studied. The Hamiltonians with the (AB)-like potentials are essentially singular and therefore require specification of a one-parameter self-adjoint extension. We construct self-adjoint Dirac Hamiltonians with the AB potential in 2+1 dimensions that are specified by boundary conditions at the origin. It is of interest that for some range of the extension parameter the AB potential can bind relativistic charged massive fermions. The bound-state energy is determined by the AB magnetic flux and depends upon the fermion spin and extension parameter; it is a periodical function of the magnetic flux. We also construct self-adjoint Hamiltonians for the so-called Aharonov-Casher (AC) problem, show that nonrelativistic neutral massive fermions can be bound by the (AC) background, determine the range of the extension parameter in which fermion bound states exist, and find their energies as well as wave functions. (orig.)
Lower bounds for the ground-state degeneracies of frustrated systems on fractal lattices
Curado; Nobre
2000-12-01
The total number of ground states for nearest-neighbor-interaction Ising systems with frustrations, defined on hierarchical lattices, is investigated. A simple method is presented, which allows one to factorize the ground-state degeneracy, at a given hierarchy level n, in terms of contributions due to all hierarchy levels. Such a method may yield the exact ground-state degeneracy of uniformly frustrated systems, whereas it works as an approximation for randomly frustrated models. In the latter cases, it is demonstrated that such an approximation yields lower-bound estimates for the ground-state degeneracies.
Mai, Sebastian; Marquetand, Philipp; González, Leticia
2014-05-28
The importance of triplet states in the photorelaxation dynamics of SO2 is studied by mixed quantum-classical dynamics simulations. Using the SHARC method, standing for Surface Hopping including ARbitrary Couplings, intersystem crossing (ISC) processes caused by spin-orbit coupling are found occurring on an ultrafast time scale (few 100 fs) and thus competing with internal conversion. While in the singlet-only dynamics only oscillatory population transfer between the (1)B1 and (1)A2 states is observed, in the dynamics including singlet and triplet states we find additionally continuous ISC to the (3)B2 state and to a smaller extent to the (3)B1/(3)A2 coupled states. The populations obtained from the dynamics are discussed with respect to the overall nuclear motion and in the light of recent TRPEPICO studies [I. Wilkinson, A. E. Boguslavskiy, J. Mikosch, D. M. Villeneuve, H.-J. Wörner, M. Spanner, S. Patchkovskii, and A. Stolow, "Excited state dynamics in SO2. I. Bound state relaxation studied by time-resolved photoelectron-photoion coincidence spectroscopy," J. Chem. Phys. 140, 204301 (2014)].
Ionization and bound-state relativistic quantum dynamics in laser-driven multiply charged ions
Energy Technology Data Exchange (ETDEWEB)
Hetzheim, Henrik
2009-01-14
The interaction of ultra-strong laser fields with multiply charged hydrogen-like ions can be distinguished in an ionization and a bound dynamics regime. Both are investigated by means of numerically solving the Dirac equation in two dimensions and by a classical relativistic Monte-Carlo simulation. For a better understanding of highly nonlinear physical processes the development of a well characterized ultra-intense relativistic laser field strength has been driven forward, capable of studying e.g. the magnetic field effects of the laser resulting in an additional electron motion in the laser propagation direction. A novel method to sensitively measure these ultra-strong laser intensities is developed and employed from the optical via the UV towards the XUV frequency regime. In the bound dynamics field, the determination of multiphoton transition matrixelements has been investigated between different bound states via Rabi oscillations. (orig.)
Femtosecond Twisting and Coherent Vibrational Motion in the Excited State of Tetraphenylethylene
Lenderink, E; Duppen, K.; Wiersma, D. A.
1995-01-01
The initial dynamics after excitation to the S-1 state of tetraphenylethylene is studied using femtosecond pump-probe spectroscopy. From the rapid spectral changes during the first few hundred femtoseconds, we conclude that a fast ethylenic twisting motion occurs in the excited state within this tim
26Si excited states via one-neutron removal from a 27Si radioactive ion beam
Chen, J.; Chen, A. A.; Amthor, A. M.; Bazin, D.; Becerril, A. D.; Gade, A.; Galaviz, D.; Glasmacher, T.; Kahl, D.; Lorusso, G.; Matos, M.; Ouellet, C. V.; Pereira, J.; Schatz, H.; Smith, K.; Wales, B.; Weisshaar, D.; Zegers, R. G. T.
2012-04-01
A study of 26Si states by neutron removal from a fast radioactive beam of 27Si has been performed. A beam of 27Si of energy 84.3 MeV/nucleon impinged on a polypropylene foil (C3H6) of 180 mg/cm2 thickness. Deexcitation γ rays were detected with a highly segmented germanium detector array, in coincidence with the 26Si recoils, and the corresponding 26Si level energies were determined. In comparing our results to two previous γ-ray spectroscopic studies of 26Si level structures, we find good agreement with a recent measurement of the 12C(16O,2nγ)26Si reaction. Our results support the use of excitation energies from that study in helping determine the important resonance energies for the thermonuclear 25Al(p,γ)26Si reaction rate. We do not observe a bound state at 4093 keV reported in an earlier study of the 24Mg(3He,nγ)26Si reaction.
Impact of electron–vibron interaction on the bound states in the continuum
Energy Technology Data Exchange (ETDEWEB)
Álvarez, C. [GISC, Departamento de Física de Materiales, Universidad Complutense, E-28040 Madrid (Spain); Domínguez-Adame, F., E-mail: adame@fis.ucm.es [GISC, Departamento de Física de Materiales, Universidad Complutense, E-28040 Madrid (Spain); Department of Physics, University of Warwick, Coventry, CV4 7AL (United Kingdom); Orellana, P.A. [Departamento de Física, Universidad Técnica Federico Santa María, Casilla 110 V, Valparaíso (Chile); Díaz, E. [GISC, Departamento de Física de Materiales, Universidad Complutense, E-28040 Madrid (Spain)
2015-06-12
We investigate the nonequilibrium transport properties of a coupled quantum dot system connected in parallel to two leads, including electron–vibron interaction. It is known that in the absence of interaction the system supports a bound state in the continuum. This state is revealed as a Fano antiresonance in the transmission when the energy levels of the dots are detuned. Using the Keldysh nonequilibrium Green's function formalism, we find that the occurrence of the Fano antiresonance arises even if the electron–vibration interaction is taken into account. We also examine the impact of the coupling to the leads in the linear response of the system. We conclude that the existence of bound states in the continuum in coupled quantum dot systems is a robust phenomenon, opening the possibility of its observation in experiments.
Effect of bound-state dressing in laser-assisted radiative recombination
Müller, Robert A.; Seipt, Daniel; Fritzsche, Stephan; Surzhykov, Andrey
2015-11-01
We present a theoretical study on the recombination of a free electron into the ground state of a hydrogenlike ion in the presence of an external laser field. Emphasis is placed on the effects caused by the laser dressing of the residual ionic bound state. To investigate how this dressing affects the total and angle-differential cross section of laser-assisted radiative recombination (LARR) we apply first-order perturbation theory and the separable Coulomb-Volkov continuum ansatz. Using this approach, detailed calculations are performed for low-Z hydrogenlike ions and laser intensities in the range from IL=1012 to 1013W/cm2 . It is seen that the total cross section as a function of the laser intensity is remarkably affected by the bound-state dressing. Moreover, the laser dressing becomes manifest as asymmetries in the angular distribution and the (energy) spectrum of the emitted recombination photons.
Ghost-gluon and ghost-quark bound states and their role in BRST quartets
Alkofer, Natalia
2011-01-01
A non-perturbative version of the BRST quartet mechanism in infrared Landau gauge QCD is proposed for transverse gluons and quarks. Based on the positivity violation for transverse gluons the content of the respective non-perturbative BRST quartet is derived. To identify the gluon's BRST-daughter and second parent state, a truncated Bethe-Salpeter equation for the gluon-(anti-)ghost bound state is investigated. We comment shortly on several equivalent forms of this equation. Repeating the same construction for quarks leads to a truncated Bethe-Salpeter equation for a fundamentally charged quark-(anti-)ghost bound state. It turns out that a cardinal input to this equation is given by the fully dressed quark-gluon vertex, and that it is indispensable to dress the quark-gluon vertex in this equation in order to obtain a consistent truncation.
I(-)·(CH3I)2 photoexcitation: the influence of dipole bound states on detachment and fragmentation.
Van Duzor, Matthew; Mbaiwa, Foster; Lasinski, Joshua; Holtgrewe, Nicholas; Mabbs, Richard
2011-06-01
We present the results of a photoelectron imaging study of the I(-)·(CH(3)I)(2) cluster anion over excitation wavelengths 355-260 nm. The resulting spectra and photoelectron angular distributions (PADs) suggest extensive electron-molecule interaction following photoexcitation. Fragmentation channels are observed subsequent to excitation between 355 and 330 nm. The origin of these features, which begin 200 meV and peak 70 meV below the X band direct detachment threshold, is described in terms of a predissociative dipole bound state. The nature of the fragments detected and the energetics of the channel opening argue strongly in favor of an asymmetric, head to tail cluster anion geometry posited by Dessent et al. [Acc. Chem. Res. 31, 527 (1998)]. Above the direct detachment threshold, PADs display evidence of phenomena akin to electron-molecule scattering. The fragment anions disappear above the X band threshold but reappear some distance below the second (A) direct detachment band. At these energies there is also rapid variation of the X band PAD, an observation attributed to autodetachment via spin-orbit relaxation of the iodine core of the cluster.
I-.(CH3I)2 photoexcitation: The influence of dipole bound states on detachment and fragmentation
Van Duzor, Matthew; Mbaiwa, Foster; Lasinski, Joshua; Holtgrewe, Nicholas; Mabbs, Richard
2011-06-01
We present the results of a photoelectron imaging study of the I-.(CH3I)2 cluster anion over excitation wavelengths 355-260 nm. The resulting spectra and photoelectron angular distributions (PADs) suggest extensive electron-molecule interaction following photoexcitation. Fragmentation channels are observed subsequent to excitation between 355 and 330 nm. The origin of these features, which begin 200 meV and peak 70 meV below the X band direct detachment threshold, is described in terms of a predissociative dipole bound state. The nature of the fragments detected and the energetics of the channel opening argue strongly in favor of an asymmetric, head to tail cluster anion geometry posited by Dessent et al. [Acc. Chem. Res. 31, 527 (1998)], 10.1021/ar950061f. Above the direct detachment threshold, PADs display evidence of phenomena akin to electron-molecule scattering. The fragment anions disappear above the X band threshold but reappear some distance below the second (A) direct detachment band. At these energies there is also rapid variation of the X band PAD, an observation attributed to autodetachment via spin-orbit relaxation of the iodine core of the cluster.
Liu, Junzi; Zhang, Yong; Bao, Peng; Yi, Yuanping
2017-02-14
Electronic couplings of charge-transfer states with the ground state and localized excited states at the donor/acceptor interface are crucial parameters for controlling the dynamics of exciton dissociation and charge recombination processes in organic solar cells. Here we propose a quasi-adiabatic state approach to evaluate electronic couplings through combining maximum occupation method (mom)-ΔSCF and state diabatization schemes. Compared with time-dependent density functional theory (TDDFT) using global hybrid functional, mom-ΔSCF is superior to estimate the excitation energies of charge-transfer states; moreover it can also provide good excited electronic state for property calculation. Our approach is hence reliable to evaluate electronic couplings for excited state electron transfer processes, which is demonstrated by calculations on a typical organic photovoltaic system, oligothiophene/perylenediimide complex.
Afzal, Muhammad Imran; Lee, Yong Tak
2016-01-01
Von Neumann and Wigner theorized bounding of asymmetric eigenstates and anti-crossing of symmetric eigenstates. Experiments have shown that owing to anti-crossing and similar radiation rates, graphene-like resonance of inhomogeneously strained photonic eigenstates can generate pseudomagnetic field, bandgaps and Landau levels, while dissimilar rates induce non-Hermicity. Here, we showed experimentally higher-order supersymmetry and quantum phase transitions by resonance between similar one dimensional lattices. The lattices consisted of inhomgeneously strain-like phases of triangular solitons. The resonance created two dimensional inhomogeneously deformed photonic graphene. All parent eigenstates are annihilated. Where eigenstates of mildly strained solitons are annihilated with similar (power law) rates through one tail only and generated Hermitianally bounded eigenstates. The strongly strained solitons, positive defects are annihilated exponentially through both tails with dissimilar rates. Which bounded eig...
Roy, Khokan; Kayal, Surajit; Ariese, Freek; Beeby, Andrew; Umapathy, Siva
2017-02-01
Femtosecond transient absorption (fs-TA) and Ultrafast Raman Loss Spectroscopy (URLS) have been applied to reveal the excited state dynamics of bis(phenylethynyl)benzene (BPEB), a model system for one-dimensional molecular wires that have numerous applications in opto-electronics. It is known from the literature that in the ground state BPEB has a low torsional barrier, resulting in a mixed population of rotamers in solution at room temperature. For the excited state this torsional barrier had been calculated to be much higher. Our femtosecond TA measurements show a multi-exponential behaviour, related to the complex structural dynamics in the excited electronic state. Time-resolved, excited state URLS studies in different solvents reveal mode-dependent kinetics and picosecond vibrational relaxation dynamics of high frequency vibrations. After excitation, a gradual increase in intensity is observed for all Raman bands, which reflects the structural reorganization of Franck-Condon excited, non-planar rotamers to a planar conformation. It is argued that this excited state planarization is also responsible for its high fluorescence quantum yield. The time dependent peak positions of high frequency vibrations provide additional information: a rapid, sub-picosecond decrease in peak frequency, followed by a slower increase, indicates the extent of conjugation during different phases of excited state relaxation. The CC triple (-C≡C-) bond responds somewhat faster to structural reorganization than the CC double (>C=Cwires."
The double radiative annihilation of the heavy-light fermion bound states
Eeg, Jan O; Picek, I
2001-01-01
We consider the double-radiative decays of heavy-light QED and QCD atoms, $\\mu^+ e^- \\to \\gamma\\gamma$ and $\\bar{B}^{0}_s \\to \\gamma\\gamma$. Especially, we take under scrutiny contributions coming from operators that vanish on the free-quark mass shell. We show that by field redefinitions these operators are converted into contact terms attached to the bound state dynamics. A net off-shell contribution is suppressed with respect to the effect of the well known flavour-changing magnetic-moment operator by the bound-state binding factor. The negligible off-shellness of the weakly bound QED atoms becomes more relevant for strongly bound QCD atoms. We analyze this off-shellness in model-approaches to QCD, one of them enabling us to keep close contact to the related effect in QED. We also comment on the off-shell effect in the corresponding process $\\bar{B}_d \\to K^* \\gamma$, and discuss possible hindering of the claimed beyond-standard-model discovery in this decay mode.
Dereka, Bogdan; Rosspeintner, Arnulf; Li, Zhiquan; Liska, Robert; Vauthey, Eric
2016-04-01
Most symmetric quadrupolar molecules designed for two-photon absorption behave as dipolar molecules in the S1 electronic excited state. This is usually explained by a breakup of the symmetry in the excited state. However, the origin of this process and its dynamics are still not fully understood. Here, excited-state symmetry breaking in a quadrupolar molecule with a D-π-A-π-D motif, where D and A are electron donating and accepting units, is observed in real time using ultrafast transient infrared absorption spectroscopy. The nature of the relaxed S1 state was found to strongly depend on the solvent polarity: (1) in nonpolar solvents, it is symmetric and quadrupolar; (2) in weakly polar media, the quadrupolar state observed directly after excitation transforms to a symmetry broken S1 state with one arm bearing more excitation than the other; and (3) in highly polar solvents, the excited state evolves further to a purely dipolar S1 state with the excitation localized entirely on one arm. The time scales associated with the transitions between these states coincide with those of solvation dynamics, indicating that symmetry breaking is governed by solvent fluctuations.
Emergence of nontrivial magnetic excitations in a spin-liquid state of kagomé volborthite
Watanabe, Daiki; Sugii, Kaori; Shimozawa, Masaaki; Suzuki, Yoshitaka; Yajima, Takeshi; Ishikawa, Hajime; Hiroi, Zenji; Shibauchi, Takasada; Matsuda, Yuji; Yamashita, Minoru
2016-08-01
When quantum fluctuations destroy underlying long-range ordered states, novel quantum states emerge. Spin-liquid (SL) states of frustrated quantum antiferromagnets, in which highly correlated spins fluctuate down to very low temperatures, are prominent examples of such quantum states. SL states often exhibit exotic physical properties, but the precise nature of the elementary excitations behind such phenomena remains entirely elusive. Here, we use thermal Hall measurements that can capture the unexplored property of the elementary excitations in SL states, and report the observation of anomalous excitations that may unveil the unique features of the SL state. Our principal finding is a negative thermal Hall conductivity κxyκxy which the charge-neutral spin excitations in a gapless SL state of the 2D kagomé insulator volborthite Cu3V2O7(OH)2ṡṡ2H2O exhibit, in much the same way in which charged electrons show the conventional electric Hall effect. We find that κxyκxy is absent in the high-temperature paramagnetic state and develops upon entering the SL state in accordance with the growth of the short-range spin correlations, demonstrating that κxyκxy is a key signature of the elementary excitation formed in the SL state. These results suggest the emergence of nontrivial elementary excitations in the gapless SL state which feel the presence of fictitious magnetic flux, whose effective Lorentz force is found to be less than 1/100 of the force experienced by free electrons.
Methodological CASPT2 study of the valence excited states of an iron-porphyrin complex.
Ben Amor, Nadia; Soupart, Adrien; Heitz, Marie-Catherine
2017-02-01
The singlet valence excited states of an iron-porphyrin-pyrazine-carbonyl complex are investigated up to the Soret band (about 3 eV) using multi-state complete active space with perturbation at the second order (MS-CASPT2). This complex is a model for the active site of carboxy-hemoglobin/myoglobin. The spectrum of the excited states is rather dense, comprising states of different nature: d→π* transitions, d→d states, π→π* excitations of the porphyrin, and doubly excited states involving simultaneous intra-porphyrin π→π* and d→d transitions. Specific features of the MS-CASPT2 method are investigated. The effect of varying the number of roots in the state average calculation is quantified as well as the consequence of targeted modifications of the active space. The effect of inclusion of standard ionization potential-electron affinity (IPEA) shift in the perturbation treatment is also investigated.
Betowski, Leon D; Enlow, Mark; Riddick, Lee
2002-06-01
Investigators using models to determine the phototoxic effects of sunlight on polycyclic aromatic hydrocarbons (PAHs) have invoked the excited states of the molecule as important in elucidating the mechanism of these reactions. Energies of actual excited states were calculated for ten PAHs by several ab initio methods. The main method used for these calculations was the Configuration Interaction approach, modeling excited states as combinations of single substitutions out of the Hartree-Fock ground state. These calculations correlate well with both experimentally measured singlet and triplet state energies and also previous HOMO-LUMO gap energies that approximate the singlet state energies. The excited state calculations then correlate well with general models of photo-induced toxicity based for the PAHs.
Two qubits of a W state violate Bell's inequality beyond Cirel'son's bound
Cabello, A
2002-01-01
It is shown that the correlations between two qubits selected from a trio prepared in a W state violate the Clauser-Horne-Shimony-Holt inequality more than the correlations between two qubits in any quantum state. Such a violation beyond Cirel'son's bound is smaller than the one achieved by two qubits selected from a trio in a Greenberger-Horne-Zeilinger state [A. Cabello, Phys. Rev. Lett. 88, 060403 (2002)]. However, it has the advantage that all local observers can know from their own measurements whether their qubits belongs or not to the selected pair.
Spectrum of Andreev bound states in Josephson junctions with a ferromagnetic insulator
Energy Technology Data Exchange (ETDEWEB)
Kawabata, Shiro, E-mail: s-kawabata@aist.go.jp [Nanosystem Research Institute (NRI), National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Ibaraki 305-8568 (Japan); CREST, Japan Science and Technology Corporation (JST), Kawaguchi, Saitama 332-0012 (Japan); Tanaka, Yukio [Department of Applied Physics, Nagoya University, Nagoya 464-8603 (Japan); Golubov, Alexander A. [Faculty of Science and Technology, University of Twente, P.O. Box 217, 7500 AE Enschede (Netherlands); Vasenko, Andrey S. [Institut Laue-Langevin, 6 rue Jules Horowitz, BP 156, 38042 Grenoble (France); Asano, Yasuhiro [Department of Applied Physics, Hokkaido University, Sapporo 060-8628 (Japan)
2012-10-15
Ferromagnetic-insulator (FI) based Josephson junctions are promising candidates for a coherent superconducting quantum bit as well as a classical superconducting logic circuit. Recently the appearance of an intriguing atomic-scale 0-{pi} transition has been theoretically predicted. In order to uncover the mechanism of this phenomena, we numerically calculate the spectrum of Andreev bound states in a FI barrier by diagonalizing the Bogoliubov-de Gennes equation. We show that Andreev spectrum drastically depends on the parity of the FI-layer number L and accordingly the {pi}(0) state is always more stable than the 0 ({pi}) state if L is odd (even).
Choudhari, Tarun; Deo, Nivedita
2017-01-01
A superconductor-topological insulator-superconductor (S/TI/S) junction having normal region at angle θ is studied theoretically to investigate the junction angle dependency of the Andreev reflection and the formation of the Andreev bound states in the step and planar S/TI/S structures. It is found that the Andreev reflection becomes θ dependent only in the presence of the potential barrier at the TI/S interface. In particular, the step and planar TI/S junction have totally different conductive behavior with bias voltage and potential barrier in the regime of retro and specular Andreev reflection. Interestingly, we find that the elliptical cross section of Dirac cone, an important feature of topological insulator with step surface defect, affects the Fabry-Perot resonance of the Andreev reflection induced Andreev bound states (which become Majorana zero energy states at low chemical potential) in the step S/TI/S structure. Unlike the usual planar S/TI/S structures, we find these ellipticity affected Andreev bound states lead to non-monotonic Josephson super-current in the step S/TI/S structure whose non-monotonicity can be controlled with the use of the potential barrier, which may find applications in nanoelectronics.
Gauge invariant formulation of 3$\\gamma$ decay of particle-antiparticle bound states
Blankleider, B; Silagadze, Z K
2014-01-01
We construct the gauge invariant three-photon decay amplitude of particle-antiparticle bound states modeled by the Dyson-Schwinger and Bethe-Salpeter equations. Application to the quark-antiquark ($q\\bar{q}$) bound states is emphasized. An essential aspect of our approach is that photons are allowed to couple to the $q\\bar{q}$ system in any way allowed by the given model, i.e., not just via the dressed quark propagator as in exact QCD. In this way, applications to effective field theories and other QCD motivated models are envisioned. The three-photon decay amplitude is constructed by attaching currents to all possible places in the Feynman diagrams contributing to the dressed quark propagator. The gauge invariance of our construction is thus a direct consequence of respecting the underlying structure of the quantum field theory determining the dynamics. In the resultant expression for the three-photon decay amplitude, all the basic ingredients consisting of the bound state wave function, the final-state inte...
Vibron-polaron in alpha-helices. II. Two-vibron bound states
Falvo, C; Falvo, Cyril; Pouthier, Vincent
2005-01-01
The two-vibron dynamics associated to amide-I vibrations in a 3D $\\alpha$-helix is described according to a generalized Davydov model. The helix is modeled by three spines of hydrogen-bonded peptide units linked via covalent bonds. It is shown that the two-vibron energy spectrum supports both a two-vibron free states continuum and two kinds of bound states, called TVBS-I and TVBS-II, connected to the trapping of two vibrons onto the same amide-I mode and onto two nearest neighbor amide-I modes belonging to the same spine, respectively. At low temperature, non vanishing interspine hopping constants yield a three dimensional nature of both TVBS-I and TVBS-II which the wave functions extend over the three spines of the helix. At biological temperature, the pairs are confined in a given spine and exhibit the same features as the bound states described within a one-dimensional model. The interplay between the temperature and the 3D nature of the helix is also responsible for the occurrence of a third bound state c...
Zhang, Mingzhen; Yang, Dapeng; Ren, Baiping; Wang, Dandan
2013-07-01
One important issue of current interest is the excited-state equilibrium for some ESITP dyes. However, so far, the information about the driving forces for excited-state equilibrium is very limited. In this work, the time-dependent density functional theory (TDDFT) method was employed to investigate the nature of the excited-state intramolecular proton transfer (ESIPT). The geometric structures, vibrational frequencies, frontier molecular orbitals (MOs) and the potential-energy curves for 1-hydroxy-11H-benzo[b]fluoren-11-one (HHBF) in the ground and the first singlet excited state were calculated. Analysis of the results shows that the intramolecular hydrogen bond of HHBF is strengthened from E to E*. Moreover, it is found that electron density swing between the proton acceptor and donor provides the driving forces for the forward and backward ESIPT, enabling the excited-state equilibrium to be established. Furthermore, we proposed that the photoexcitation and the interchange of position for electron-donating and electron-withdrawing groups are the main reasons for the electron density swing. The potential-energy curves suggest that the forward ESIPT and backward ESIPT may happen on the similar timescale, which is faster than the fluorescence decay of both E* and K* forms.
Continuum excitations of $^{26}$O in a three-body model: $0^+$ and $2^+$ states
Grigorenko, L V
2015-01-01
The structure and decay dynamics for $0^+$ and $2^+$ continuum excitations of $^{26}$O are investigated in a three-body $^{24}$O+$n$+$n$ model. Validity of a simple approximation for the cross section profile for long-lived $2n$ emission is demonstrated. Sequence of three $0^+$ monopole ("breathing mode" type) excited states is predicted. These states could probably be interpreted as analogues of Efimov states pushed into continuum by insufficient binding. The possible energies of the $2^+$ states are related to excitation spectrum of $^{25}$O. We discuss possible connection of predicted $^{26}$O spectrum with observations.
Ground and Excited States of Bipolarons in Two and Three Dimensions
Institute of Scientific and Technical Information of China (English)
RUAN Yong-Hong; CHEN Qing-Hu
2007-01-01
The properties of large bipolarons in two and three dimensions are investigated by averaging over the relative wavefunction of the two electrons and using the Lee-Low-Pines-Huybrechts variational method. The groundstate (GS) and excited-state energies of the Fr(o)hlich bipolaron for the whole range of electron-phonon coupling constants can be obtained. The energies of the first relaxed excited state (RES) and Franck-Condon (FC) excited state of the bipolaron are also calculated. It is found that the first RES energy is lower than the FC state energy. The comparison of our GS and RES energies with those in literature is also given.
Ultrafast internal conversion of excited cytosine via the lowest pipi electronic singlet state.
Merchán, Manuela; Serrano-Andrés, Luis
2003-07-09
Computational evidence at the CASPT2 level supports that the lowest excited state pipi* contributes to the S1/S0 crossing responsible for the ultrafast decay of singlet excited cytosine. The computed radiative lifetime, 33 ns, is consistent with the experimentally derived value, 40 ns. The nOpi* state does not play a direct role in the rapid repopulation of the ground state; it is involved in a S2/S1 crossing. Alternative mechanisms through excited states pisigma* or nNpi* are not competitive in cytosine.
Electric field enhancement of depolarization of excited states
Energy Technology Data Exchange (ETDEWEB)
Nayfeh, M.H.; Hillard, G.B.; Glab, W.L.
1985-12-01
Our calculations show that an external dc electric field can enhance by many orders of magnitude the depolarization cross section of highly excited atoms by charged particles. The enhancement is due to the fact that the electric field extends and shifts the electronic charge distribution along its direction, thus effectively creating a giant electric dipole in the atom.
Szczepanik, Beata
2015-11-01
The excited state proton transfer (ESPT) has been extensively studied for hydroxyarenes, phenols, naphthols, hydroxystilbenes, etc., which undergo large enhancement of acidity upon electronic excitation, thus classified as photoacids. The changes of acidic character in the excited state of cyano-substituted derivatives of phenol, hydroxybiphenyl and naphthol are reviewed in this paper. The acidity constants pKa in the ground state (S0), pKa∗ in the first singlet excited state (S1) and the change of the acidity constant in the excited state ΔpKa for the discussed compounds are summarized and compared. The results of the acidity studies show, that the "electro-withdrawing" CN group in the molecules of naphthol, hydroxybiphenyl and phenol causes dramatic increase of their acidity in the excited state in comparison to the ground state. This effect is greatest for the cyanonaphthols (the doubly substituted CN derivatives are almost as strong as a mineral acid in the excited state), comparable for cyanobiphenyls, and smaller for phenol derivatives. The increase of acidity enables proton transfer to various organic solvents, and the investigation of ESPT can be extended to a variety of solvents besides water. The results of theoretical investigations were also presented and used for understanding the protolytic equilibria of cyano derivatives of naphthol, hydroxybiphenyl and phenol.
Excited state X-ray absorption spectroscopy: Probing both electronic and structural dynamics
Neville, Simon P.; Averbukh, Vitali; Ruberti, Marco; Yun, Renjie; Patchkovskii, Serguei; Chergui, Majed; Stolow, Albert; Schuurman, Michael S.
2016-10-01
We investigate the sensitivity of X-ray absorption spectra, simulated using a general method, to properties of molecular excited states. Recently, Averbukh and co-workers [M. Ruberti et al., J. Chem. Phys. 140, 184107 (2014)] introduced an efficient and accurate L 2 method for the calculation of excited state valence photoionization cross-sections based on the application of Stieltjes imaging to the Lanczos pseudo-spectrum of the algebraic diagrammatic construction (ADC) representation of the electronic Hamiltonian. In this paper, we report an extension of this method to the calculation of excited state core photoionization cross-sections. We demonstrate that, at the ADC(2)x level of theory, ground state X-ray absorption spectra may be accurately reproduced, validating the method. Significantly, the calculated X-ray absorption spectra of the excited states are found to be sensitive to both geometric distortions (structural dynamics) and the electronic character (electronic dynamics) of the initial state, suggesting that core excitation spectroscopies will be useful probes of excited state non-adiabatic dynamics. We anticipate that the method presented here can be combined with ab initio molecular dynamics calculations to simulate the time-resolved X-ray spectroscopy of excited state molecular wavepacket dynamics.
Bound-State Solution of s-Wave Klein-Gordon Equation for Woods-Saxon Potential
Directory of Open Access Journals (Sweden)
Eser Olğar
2015-01-01
Full Text Available The bound-state solution of s-wave Klein-Gordon equation is calculated for Woods-Saxon potential by using the asymptotic iteration method (AIM. The energy eigenvalues and eigenfunctions are obtained for the required condition of bound-state solutions.
The quark-gluon vertex in Landau gauge bound-state studies
Williams, Richard
2015-05-01
We present a practical method for the solution of the quark-gluon vertex for use in Bethe-Salpeter and Dyson-Schwinger calculations. The efficient decomposition into the necessary covariants is detailed, with the numerical algorithm outlined for both real and complex Euclidean momenta. A truncation of the quark-gluon vertex, that neglects explicit back-coupling to enable the application to bound-state calculations, is given together with results for the quark propagator and quark-gluon vertex for different quark flavours. The relative impact of the various components of the quark-gluon vertex is highlighted with the flavour dependence of the effective quark-gluon interaction obtained, thus providing insight for the construction of phenomenological models within the rainbow ladder. Finally, we solve the corresponding Green's functions for complex Euclidean momenta as required in future bound-state calculations.
Bound-state field theory approach to proton structure effects in muonic hydrogen
Mohr, Peter J; Sapirstein, J
2013-01-01
A bound-state field theory approach to muonic hydrogen is set up using a variant of the Furry representation in which the lowest-order Hamiltonian describes a muon in the presence of a point Coulomb field, but the origin of the binding field is taken to be three charged quarks in the proton which are modeled as Dirac particles that move freely within a spherical well. Bound-state field theory techniques are used to evaluate one- and two-photon effects. Particular attention is paid to two-photon exchange diagrams, which include the effect of proton polarizability. In addition the modification of the electromagnetic self energy of the proton by the electric field of the muon is examined. Finally, the model is used to carry out a calculation of the static electric polarizability of the proton.
The quark-gluon vertex in Landau gauge bound-state studies
Energy Technology Data Exchange (ETDEWEB)
Williams, Richard [Justus-Liebig University of Giessen, Institute of Theoretical Physics, Giessen (Germany)
2015-05-15
We present a practical method for the solution of the quark-gluon vertex for use in Bethe-Salpeter and Dyson-Schwinger calculations. The efficient decomposition into the necessary covariants is detailed, with the numerical algorithm outlined for both real and complex Euclidean momenta. A truncation of the quark-gluon vertex, that neglects explicit back-coupling to enable the application to bound-state calculations, is given together with results for the quark propagator and quark-gluon vertex for different quark flavours. The relative impact of the various components of the quark-gluon vertex is highlighted with the flavour dependence of the effective quark-gluon interaction obtained, thus providing insight for the construction of phenomenological models within the rainbow ladder. Finally, we solve the corresponding Green's functions for complex Euclidean momenta as required in future bound-state calculations. (orig.)
Vertical D4-D2-D0 bound states on K3 fibrations and modularity
DEFF Research Database (Denmark)
Bouchard, Vincent; Creutzig, Thomas; Diaconescu, Duiliu-Emanuel;
2016-01-01
An explicit formula is derived for the generating function of vertical D4-D2-D0 bound states on smooth K3 fibered Calabi-Yau threefolds, generalizing previous results of Gholampour and Sheshmani. It is also shown that this formula satisfies strong modularity properties, as predicted by string the...... theory. This leads to a new construction of vector valued modular forms which exhibits some of the features of a generalized Hecke transform.......An explicit formula is derived for the generating function of vertical D4-D2-D0 bound states on smooth K3 fibered Calabi-Yau threefolds, generalizing previous results of Gholampour and Sheshmani. It is also shown that this formula satisfies strong modularity properties, as predicted by string...
Baryon-baryon bound states in a (2+1)-dimensional lattice QCD model
Faria da Veiga, Paulo A.; O'Carroll, Michael; Schor, Ricardo
2003-08-01
We consider bound states of two baryons (antibaryons) in lattice QCD in a Euclidean formulation. For simplicity, we analyze an SU(3) theory with a single flavor in 2+1 dimensions and two-dimensional Dirac matrices. For a small hopping parameter 0<κ≪1 and large glueball mass, we recently showed the existence of a (anti)baryonlike particle, with an asymptotic mass of the order of -3 ln κ and with an isolated dispersion curve, i.e., an upper gap property persisting up to near the meson-baryon threshold, which is of order -5 ln κ. Here, we show that there is no baryon-baryon (or antibaryon-antibaryon) bound state solution to the Bethe-Salpeter equation up to the two-baryon threshold, which is approximately -6 ln κ.
Radiative bound-state-formation cross-sections for dark matter interacting via a Yukawa potential
Petraki, Kalliopi; de Vries, Jordy
2016-01-01
We calculate the cross-sections for the radiative formation of bound states by dark matter whose interactions are described in the non-relativistic regime by a Yukawa potential. These cross-sections are important for cosmological and phenomenological studies of dark matter with long-range interactions, residing in a hidden sector, as well as for TeV-scale WIMP dark matter. We provide the leading-order contributions to the cross-sections for the dominant capture processes occurring via emission of a vector or a scalar boson. We offer a detailed inspection of their features, including their velocity dependence within and outside the Coulomb regime, and their resonance structure. For pairs of annihilating particles, we compare bound-state formation with annihilation.
Institute of Scientific and Technical Information of China (English)
CHANG Chao-Hsi; CHEN Jiao-Kai; WANG Guo-Li
2006-01-01
We have precisely derived a "rigorous instantaneous formulation" for transitions between two bound states when the bound states are well-described by instantaneous Bethe-Salpeter (BS) equation (i.e. the kernel of the equation is instantaneous"occasionally"). The obtained rigorous instantaneous formulation, in fact, is expressed as an operator sandwiched by two "reduced BS wave functions" properly, while the reduced BS wave functions appearing in the formulation are the rigorous solutions of the instantaneous BS equation, and they may relate to Schr(o)dinger wave functions straightforwardly. We also show that the rigorous instantaneous formulation is gauge-invariant with respect to the Uem(1) transformation precisely, if the concerned transitions are radiative. Some applications of the formulation are outlined.
Differential dynamics of RAS isoforms in GDP- and GTP-bound states.
Kapoor, Abhijeet; Travesset, Alex
2015-06-01
RAS subfamily proteins regulates cell growth promoting signaling processes by cycling between active (GTP-bound) and inactive (GDP-bound) states. Different RAS isoforms, though structurally similar, exhibit functional specificity and are associated with different types of cancers and developmental disorders. Understanding the dynamical differences between the isoforms is crucial for the design of inhibitors that can selectively target a particular malfunctioning isoform. In this study, we provide a comprehensive comparison of the dynamics of all the three RAS isoforms (HRAS, KRAS, and NRAS) using extensive molecular dynamics simulations in both the GDP- (total of 3.06 μs) and GTP-bound (total of 2.4 μs) states. We observed significant differences in the dynamics of the isoforms, which rather interestingly, varied depending on the type of the nucleotide bound and the simulation temperature. Both SwitchI (Residues 25-40) and SwitchII (Residues 59-75) differ significantly in their flexibility in the three isoforms. Furthermore, Principal Component Analysis showed that there are differences in the conformational space sampled by the GTP-bound RAS isoforms. We also identified a previously unreported pocket, which opens transiently during MD simulations, and can be targeted to regulate nucleotide exchange reaction or possibly interfere with membrane localization. Further, we present the first simulation study showing GDP destabilization in the wild-type RAS protein. The destabilization of GDP/GTP occurred only in 1/50 simulations, emphasizing the need of guanine nucleotide exchange factors (GEFs) to accelerate such an extremely unfavorable process. This observation along with the other results presented in this article further support our previously hypothesized mechanism of GEF-assisted nucleotide exchange.
Lower Bounds on the Capacity of the Relay Channel with States at the Source
Directory of Open Access Journals (Sweden)
Abdellatif Zaidi
2009-01-01
Full Text Available We consider a state-dependent three-terminal full-duplex relay channel with the channel states noncausally available at only the source, that is, neither at the relay nor at the destination. This model has application to cooperation over certain wireless channels with asymmetric cognition capabilities and cognitive interference relay channels. We establish lower bounds on the channel capacity for both discrete memoryless (DM and Gaussian cases. For the DM case, the coding scheme for the lower bound uses techniques of rate-splitting at the source, decode-and-forward (DF relaying, and a Gel'fand-Pinsker-like binning scheme. In this coding scheme, the relay decodes only partially the information sent by the source. Due to the rate-splitting, this lower bound is better than the one obtained by assuming that the relay decodes all the information from the source, that is, full-DF. For the Gaussian case, we consider channel models in which each of the relay node and the destination node experiences on its link an additive Gaussian outside interference. We first focus on the case in which the links to the relay and to the destination are corrupted by the same interference; and then we focus on the case of independent interferences. We also discuss a model with correlated interferences. For each of the first two models, we establish a lower bound on the channel capacity. The coding schemes for the lower bounds use techniques of dirty paper coding or carbon copying onto dirty paper, interference reduction at the source and decode-and-forward relaying. The results reveal that, by opposition to carbon copying onto dirty paper and its root Costa's initial dirty paper coding (DPC, it may be beneficial in our setup that the informed source uses a part of its power to partially cancel the effect of the interference so that the uninformed relay benefits from this cancellation, and so the source benefits in turn.
State-Bound Estimation for Nonlinear Systems Using Randomized Mu-Analysis
2014-04-30
number of threads per block is 1024. The algorithms on the GPU is implemented using CUDA - GPU [27]. 2.3 Probabilistic Properties of the Algorithms A...between 0 and 1. As the size of the system is relatively large, the integration part is imple- mented over CUDA - GPU [27] and the programmes are shown in...delta.m . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 60 B ErbB Signalling Pathways: GPU Example 61 B.1 state bounds for many steps main.m
Vertical D4-D2-D0 bound states on K3 fibrations and modularity
Bouchard, Vincent; Diaconescu, Duiliu-Emanuel; Doran, Charles; Quigley, Callum; Sheshmani, Artan
2016-01-01
An explicit formula is derived for the generating function of vertical D4-D2-D0 bound states on smooth K3 fibered Calabi-Yau threefolds, generalizing previous results of Gholampour and Sheshmani. It is also shown that this formula satisfies strong modularity properties, as predicted by string theory. This leads to a new construction of vector valued modular forms which exhibits some of the features of a generalized Hecke transform.
Study of -nucleus interaction through the formation of -nucleus bound state
Indian Academy of Sciences (India)
V Jha; B J Roy; A Chatterjee; H Machner
2006-05-01
The question of possible existence of -mesic nuclei is quite intriguing. Answer to this question will deeply enrich our understanding of -nucleus interaction which is not so well-understood. We review the experimental efforts for the search of -mesic nuclei and describe the physics motivation behind it. We present the description of an experiment for the search of -nucleus bound state using the GeV proton beam, currently being performed at COSY.
Dissecting zero modes and bound states on BPS vortices in Ginzburg-Landau superconductors
Alonso-Izquierdo, Alberto; Guilarte, Juan Mateos
2016-01-01
In this paper the zero modes of fluctuation of cylindrically symmetric self-dual vortices are analyzed and described in full detail. These BPS topological defects arise at the critical point between Type II and Type I superconductors, or, equivalently, when the masses of the Higgs particle and the vector boson in the Abelian Higgs model are equal. In addition, novel bound states of Higss and vector bosons trapped by the self-dual vortices at their core are found and investigated.
Phonon dilatation, dressed vibrons and two-vibron bound states localization in an adsorbed nanowire
Pouthier, Vincent,
2006-01-01
A special attention is paid to characterize the two-vibron bound state dynamics of an anharmonic molecular nanostructure coupled with a set of optical phonons. It is shown that the vibron-phonon coupling is responsible for a new dressing mechanism. The vibrons are accompanied by virtual phonons which account for the scaling of each phonon coordinate and for the dilatation of the corresponding wave function. As a result, the dynamics of the dressed vibrons is governed by an effective Hamiltoni...
Vertical D4-D2-D0 bound states on K3 fibrations and modularity
DEFF Research Database (Denmark)
Bouchard, Vincent; Creutzig, Thomas; Diaconescu, Duiliu-Emanuel;
2016-01-01
An explicit formula is derived for the generating function of vertical D4-D2-D0 bound states on smooth K3 fibered Calabi-Yau threefolds, generalizing previous results of Gholampour and Sheshmani. It is also shown that this formula satisfies strong modularity properties, as predicted by string...... theory. This leads to a new construction of vector valued modular forms which exhibits some of the features of a generalized Hecke transform....
Vertical D4-D2-D0 Bound States on K3 Fibrations and Modularity
Bouchard, Vincent; Creutzig, Thomas; Diaconescu, Duiliu-Emanuel; Doran, Charles; Quigley, Callum; Sheshmani, Artan
2017-03-01
An explicit formula is derived for the generating function of vertical D4-D2-D0 bound states on smooth K3 fibered Calabi-Yau threefolds, generalizing previous results of Gholampour and Sheshmani. It is also shown that this formula satisfies strong modularity properties, as predicted by string theory. This leads to a new construction of vector valued modular forms which exhibit some of the features of a generalized Hecke transform.
Search for the He-{\\eta} bound states with the WASA-at-COSY facility
Skurzok, M; Moskal, P
2012-01-01
The eta-mesic nuclei in which the {\\eta} meson is bound with nucleus via strong interaction was postulated already in 1986, however till now no experiment confirmed empirically its existence. The discovery of this new kind of an exotic nuclear matter would be very important for better understanding of the {\\eta} meson structure and its interaction with nucleons. The search for {\\eta}-mesic helium is carried out with high statistic and high acceptance with the WASA-at-COSY detection setup in the Research Center Juelich. The search is conducted via the measurement of the excitation function for the chosen decay channels of the 4He-{\\eta} system. Till now two reactions dd --> (4He-{\\eta})_bs --> 3Hep\\pi- and dd --> (4He-{\\eta})_bs --> 3 Hen{\\pi}0 were measured with the beam momentum ramped around the eta production threshold. This report includes the description of experimental method and status of the analysis.
Robust State Feedback Control of Wind-Excited Tall Buildings
Institute of Scientific and Technical Information of China (English)
无
2001-01-01
The introduction of robust control theory into structure control, as well as design procedure of stabilizing controllers for structures with parameter uncertainty and model error is discussed. A stability bound is derived from the polar decomposition of the nominal system matrix. In addition, our study shows that application of Iow pass filters avoids spillover by eliminating the unconsidered high frequency compo nents. It is demonstrated, via an example, our approach leads to excellent control result and offers far better robustness than previous solutions.
F(750), We Miss You, as Bound State of 6 Top and 6 Anti top
Nielsen, Holger Frits Bech
2016-01-01
We collect and estimate support for our long speculated "multiple point principle" saying that there should be several vacua all having (compared to the scales of high energy physics) very low energy densities. In pure Standard Model we suggest there being three by "multiple point principle" low energy density vacua, "present", "condensate" and "high field" vacuum. We fit the mass of the in our picture since long speculated bound state of six top and six anti top quarks in three quite {\\em independent ways} and get remarkably within our crude accuracy the {\\em same} mass in all three fits! The new point of the present article is to estimate the bound state mass in what we could call a bag model estimation. The two other fits, which we review, obtain the mass of the bound state by fitting to the multiple point principle prediction of degenerate vacua. Our remarkable agreement of our three mass-fits can be interpreted to mean, that we have calculated at the end the energy densities of the two extra speculated v...
Quantization of the Closed Mini-Superspace Models as Bound States
Kung, J H
1995-01-01
Wheeler-DeWitt equation is applied to $k > 0$ Friedmann Robertson Walker metric with various types of matter. It is shown that if the Universe ends in the matter dominated era (e.g., radiation or pressureless gas) with zero cosmological constant, then the resulting Wheeler-DeWitt equation describes a bound state problem. As solutions of a non-degenerate bound state system, the eigen-wave functions are real (Hartle-Hawking) and the usual issue associated with the ambiguity in the boundary conditions for the wave functions is resolved. Furthermore, as a bound state problem, there exists a quantization condition that relates the curvature of the three space with the energy density of the Universe. Incorporating a cosmological constant in the early Universe (inflation) is given as a natural explanation for the large quantum number associated with our Universe, which resulted from the quantization condition. It is also shown that if there is a cosmological constant $\\Lambda > 0$ in our Universe that persists for a...
Gluon bound state and asymptotic freedom derived from the Bethe--Salpeter equation
Fukamachi, Hitoshi; Nishino, Shogo; Shinohara, Toru
2016-01-01
In this paper we study the two-body bound states for gluons and ghosts in a massive Yang-Mills theory which is obtained by generalizing the ordinary massless Yang-Mills theory in a manifestly Lorentz covariant gauge. First, we give a systematic derivation of the coupled Bethe-Salpeter equations for gluons and ghosts by using the Cornwall-Jackiw-Tomboulis effective action of the composite operators within the framework of the path integral quantization. Then, we obtain the numerical solutions for the Bethe-Salpeter amplitude representing the simultaneous bound states of gluons and ghosts by solving the homogeneous Bethe-Salpeter equation in the ladder approximation. We study how the inclusion of ghosts affects the two-gluon bound states in the cases of the standing and running gauge coupling constant. Moreover, we show explicitly that the approximate solutions obtained for the gluon-gluon amplitude are consistent with the ultraviolet asymptotic freedom signaled by the negative $\\beta$ function.
Meson-baryon bound states in a (2+1)-dimensional strongly coupled lattice QCD model
Neto, Antônio Francisco
2004-08-01
We consider bound states of a meson and a baryon (meson and antibaryon) in lattice QCD in a Euclidean formulation. For simplicity, considering the + parity sector we analyze an SU(3) theory with a single flavor in 2+1 dimensions and two-dimensional Dirac matrices. We work in the strong coupling regime, i.e., in a region of parameters such that the hopping parameter κ is sufficiently small and κ≫g-20, where g-20 is the pure gauge coupling. There is a meson (baryon) particle with asymptotic mass -2 ln κ (-3 ln κ) and an isolated dispersion curve. Here, in a ladder approximation, we show that there is no meson baryon (or meson-antibaryon) bound state solution to the Bethe-Salpeter equation up to the meson-baryon threshold (˜-5 ln κ). The absence of such a bound state is an effect of a spatial range-one repulsive potential that is local in space at order κ3, i.e., the leading order in the hopping parameter κ.