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Sample records for boiling point fuels

  1. Basic research and industrialization of CANDU advanced fuel - Effect of transverse convex curvature on boiling heat transfer and ONB point of nucleate fuel rods

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Kyung Chun; Lee, Young; Lee, Sung Hong [Pusan National University, Pusan (Korea)

    2000-04-01

    Recently, the effect of convex curvature on heat transfer should not be ignored when the radius of curvature tends to be small and/or associated with high heat transfer rate cases. Both analytical and experimental studies were performed to prove the effect of transverse convex curvature on the boiling heat transfer in concentric annuli flows. The effect of the transverse convex surface curvature on ONB are studied analytically in the case of reactor and evaporator. It is seen that the inner wall heat flux depends on R/sub i/, Rc, Re, Pr, {alpha}, and the {theta} of working fluid. An experimental study on the incipience of nucleate boiling is performed as a verification ad extension of previous analyses. Through flow visualization, the results show that the most dominant parameter to affect the heat flux at ONB is found to be the surface curvature. The heat flux data at ONB increases with the Re and the subcooling, and the effect of subcooling on ONB becomes smaller with decreasing Re. The heat flux at ONB increases rapidly as increase in {alpha} due to higher convective motion of bulk flow. Comparison between both results are accomplished with respect to the relative enhancement due to the convex curvature. The relative heat transfer enhancement ratio shows a good agreement between theory and experiment qualitatively and quantitatively. In conclusion, the obtained results suggest that the effect transverse convex curvature appears significantly in the boiling heat transfer. Therefore, it can be clearly expected that the effect should be more strong at the case of critical heat flux condition which is the most important design goal of the advanced nuclear fuel rods. 30 refs., 78 figs. (Author)

  2. Development of Lubricity Evaluation Bench for Low-boiling Point Dimethyl Ether Fuel%低沸点燃料二甲醚润滑性评估实验台的研制

    Institute of Scientific and Technical Information of China (English)

    宋磊; 陈晓玲; 张武高; 浦耿强

    2012-01-01

    二甲醚在常温常压下为气态,不能用传统方法评估其润滑性能.根据低沸点燃油的物理特性和高频往复机(HFRR)的基本原理,设计可加压的高频往复机,初步搭建用于低沸点燃油的摩擦磨损试验台架,并采用常规燃油进行油品的可分辨性试验.结果表明,该台架可以用于评价不同油品的润滑性,为二甲醚等低沸点燃油润滑性能评估方法的建立奠定了基础.%Because dimethyl ether (DME) is gaseous at normal temperature and pressure, it is impossible to evaluate the lubricity of DME by using traditional methods. According to the principle of High Frequency Reciprocating Rig (HFRR)and the physical properties of low-boiling point fuel,a HFRR with pressure control was designed, and a wear test device for low-boiling point fuel was constructed. A preliminary resolution test with some regular fuels was done. The results show that the lubricity of different fuels can be evaluated by this rig, and it lays a solid foundation for the establishment of lubricity evaluation method about low-boiling point fuel like DME.

  3. 46 CFR 154.706 - Cargo boil-off as fuel: Fuel lines.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 5 2010-10-01 2010-10-01 false Cargo boil-off as fuel: Fuel lines. 154.706 Section 154... Equipment Cargo Pressure and Temperature Control § 154.706 Cargo boil-off as fuel: Fuel lines. (a) Gas fuel lines must not pass through accommodation, service, or control spaces. Each gas fuel line...

  4. Boiling point: government neglect, corporate abuse, and Canada's water crisis

    National Research Council Canada - National Science Library

    Barlow, Maude

    2016-01-01

    "In Boiling Point, bestselling author and activist Maude Barlow lays bare the issues facing Canada's water reserves, including long-outdated water laws, unmapped and unprotected groundwater reserves...

  5. Correlations estimate volume distilled using gravity, boiling point

    Energy Technology Data Exchange (ETDEWEB)

    Moreno, A.; Consuelo Perez de Alba, M. del; Manriquez, L.; Guardia Mendoz, P. de la [Inst. Mexicano del Petroleo, Mexico City (Mexico)

    1995-10-23

    Mathematical nd graphic correlations have been developed for estimating cumulative volume distilled as a function of crude API gravity and true boiling point (TBP). The correlations can be used for crudes with gravities of 21--34{degree} API and boiling points of 150--540 C. In distillation predictions for several mexican and Iraqi crude oils, the correlations have exhibited accuracy comparable to that of laboratory measurements. The paper discusses the need for such a correlation and the testing of the correlation.

  6. Investigation Status of Heat Exchange while Boiling Hydrocarbon Fuel

    Directory of Open Access Journals (Sweden)

    D. S. Obukhov

    2006-01-01

    Full Text Available The paper contains analysis of heat exchange investigations while boiling hydrocarbon fuel. The obtained data are within the limits of the S.S. Kutateladze dependence proposed in 1939. Heat exchange at non-stationary heat release has not been investigated. The data for hydrocarbon fuel with respect to critical density of heat flow are not available even for stationary conditions.

  7. An Analytical Approach for Relating Boiling Points of Monofunctional Organic Compounds to Intermolecular Forces

    Science.gov (United States)

    Struyf, Jef

    2011-01-01

    The boiling point of a monofunctional organic compound is expressed as the sum of two parts: a contribution to the boiling point due to the R group and a contribution due to the functional group. The boiling point in absolute temperature of the corresponding RH hydrocarbon is chosen for the contribution to the boiling point of the R group and is a…

  8. An Analytical Approach for Relating Boiling Points of Monofunctional Organic Compounds to Intermolecular Forces

    Science.gov (United States)

    Struyf, Jef

    2011-01-01

    The boiling point of a monofunctional organic compound is expressed as the sum of two parts: a contribution to the boiling point due to the R group and a contribution due to the functional group. The boiling point in absolute temperature of the corresponding RH hydrocarbon is chosen for the contribution to the boiling point of the R group and is a…

  9. High freezing point fuels used for aviation turbine engines

    Science.gov (United States)

    Friedman, R.

    1979-01-01

    Broadened-specification aviation fuels could be produced from a greater fraction of crude source material with improvements in fuel supply and price. These fuels, particularly those with increased final boiling temperatures, would have higher freezing temperatures than current aviation turbine fuels. For the small but significant fraction of commercial flights where low fuel temperatures make higher freezing-point fuel use unacceptable, adaptations to the fuel or fuel system may be made to accommodate this fuel. Several techniques are discussed. Fuel heating is the most promising concept. One simple design uses existing heat rejection from the fuel-lubricating oil cooler, another uses an engine-driven generator for electrical heating.

  10. Prediction of boiling points of organic compounds by QSPR tools.

    Science.gov (United States)

    Dai, Yi-min; Zhu, Zhi-ping; Cao, Zhong; Zhang, Yue-fei; Zeng, Ju-lan; Li, Xun

    2013-07-01

    The novel electro-negativity topological descriptors of YC, WC were derived from molecular structure by equilibrium electro-negativity of atom and relative bond length of molecule. The quantitative structure-property relationships (QSPR) between descriptors of YC, WC as well as path number parameter P3 and the normal boiling points of 80 alkanes, 65 unsaturated hydrocarbons and 70 alcohols were obtained separately. The high-quality prediction models were evidenced by coefficient of determination (R(2)), the standard error (S), average absolute errors (AAE) and predictive parameters (Qext(2),RCV(2),Rm(2)). According to the regression equations, the influences of the length of carbon backbone, the size, the degree of branching of a molecule and the role of functional groups on the normal boiling point were analyzed. Comparison results with reference models demonstrated that novel topological descriptors based on the equilibrium electro-negativity of atom and the relative bond length were useful molecular descriptors for predicting the normal boiling points of organic compounds. Copyright © 2013 Elsevier Inc. All rights reserved.

  11. Size-exclusion chromatography for the determination of the boiling point distribution of high-boiling petroleum fractions.

    Science.gov (United States)

    Boczkaj, Grzegorz; Przyjazny, Andrzej; Kamiński, Marian

    2015-03-01

    The paper describes a new procedure for the determination of boiling point distribution of high-boiling petroleum fractions using size-exclusion chromatography with refractive index detection. Thus far, the determination of boiling range distribution by chromatography has been accomplished using simulated distillation with gas chromatography with flame ionization detection. This study revealed that in spite of substantial differences in the separation mechanism and the detection mode, the size-exclusion chromatography technique yields similar results for the determination of boiling point distribution compared with simulated distillation and novel empty column gas chromatography. The developed procedure using size-exclusion chromatography has a substantial applicability, especially for the determination of exact final boiling point values for high-boiling mixtures, for which a standard high-temperature simulated distillation would have to be used. In this case, the precision of final boiling point determination is low due to the high final temperatures of the gas chromatograph oven and an insufficient thermal stability of both the gas chromatography stationary phase and the sample. Additionally, the use of high-performance liquid chromatography detectors more sensitive than refractive index detection allows a lower detection limit for high-molar-mass aromatic compounds, and thus increases the sensitivity of final boiling point determination. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  12. High-freezing-point fuels used for aviation turbine engines

    Science.gov (United States)

    Friedman, R.

    1979-01-01

    Broadened-specification aviation fuels could be produced from a greater fraction of crude source material with improvements in fuel supply and price. These fuels, particularly those with increased final boiling temperatures, would have higher freezing temperatures than current aviation turbine fuels. The higher-freezing-point fuels can be substituted in the majority of present commercial flights, since temperature data indicate that in-flight fuel temperatures are relatively mild. For the small but significant fraction of commercial flights where low fuel temperatures make higher freezing-point fuel use unacceptable, adaptations to the fuel or fuel system may be made to accommodate this fuel. Several techniques are discussed. Fuel heating is the most promising concept. One simple system design uses existing heat rejection from the fuel-lubricating oil cooler, another uses an engine-driven generator for electrical heating. Both systems offer advantages that outweigh the obvious penalties.

  13. Chemical Gradients in Crud on Boiling Water Reactor Fuel Elements

    Energy Technology Data Exchange (ETDEWEB)

    D. L. Porter; D. E. Janney

    2007-04-01

    Crud (radioactive corrosion products formed inside nuclear reactors is a major problem in commercial power-producing nuclear reactors. Although there are numerous studies of simulated (non-radioactive) crud, characteristics of crud from actual reactors are rarely studied. This study reports scanning electron microscope (SEM) studies of fragments of crud from a commercially operating boiling water reactor. Chemical analyses in the SEM indicated that the crud closest to the outer surfaces of the fuel pins in some areas had Fe:Zn ratios close to 2:1, which decreased away from the fuel pin in some of the fragments. In combination with transmission electron microsope analyses (published elsewhere), these results suggest that the innermost layer of crud in some areas may consist of franklinite (ZnFe2O4, also called zinc spinel), while outer layers in these areas may be predominantly iron oxides.

  14. Detection of the Departure from Nucleate Boiling in Nuclear Fuel Rod Simulators

    Directory of Open Access Journals (Sweden)

    Amir Zacarias Mesquita

    2013-01-01

    Full Text Available In the thermal hydraulic experiments to determin parameters of heat transfer where fuel rod simulators are heated by electric current, the preservation of the simulators is essential when the heat flux goes to the critical point. One of the most important limits in the design of cooling water reactors is the condition in which the heat transfer coefficient by boiling in the core deteriorates itself. The heat flux just before deterioration is denominated critical heat flux (CHF. At this time, the small increase in heat flux or in the refrigerant inlet temperature at the core, or the small decrease in the inlet flux of cooling, results in changes in the heat transfer mechanism. This causes increases in the surface temperature of the fuel elements causing failures at the fuel (burnout. This paper describes the experiments conducted to detect critical heat flux in nuclear fuel element simulators carried out in the thermal-hydraulic laboratory of Nuclear Technology Development Centre (CDTN. It is concluded that the use of displacement transducer is the most efficient technique for detecting critical heat flux in nuclear simulators heated by electric current in open pool.

  15. Estimation of boiling points using density functional theory with polarized continuum model solvent corrections.

    Science.gov (United States)

    Chan, Poh Yin; Tong, Chi Ming; Durrant, Marcus C

    2011-09-01

    An empirical method for estimation of the boiling points of organic molecules based on density functional theory (DFT) calculations with polarized continuum model (PCM) solvent corrections has been developed. The boiling points are calculated as the sum of three contributions. The first term is calculated directly from the structural formula of the molecule, and is related to its effective surface area. The second is a measure of the electronic interactions between molecules, based on the DFT-PCM solvation energy, and the third is employed only for planar aromatic molecules. The method is applicable to a very diverse range of organic molecules, with normal boiling points in the range of -50 to 500 °C, and includes ten different elements (C, H, Br, Cl, F, N, O, P, S and Si). Plots of observed versus calculated boiling points gave R²=0.980 for a training set of 317 molecules, and R²=0.979 for a test set of 74 molecules. The role of intramolecular hydrogen bonding in lowering the boiling points of certain molecules is quantitatively discussed. Crown Copyright © 2011. Published by Elsevier Inc. All rights reserved.

  16. What Is the Boiling Point and Heat of Vaporization of Sulfuric Acid?

    Science.gov (United States)

    Myers, R. Thomas

    1983-01-01

    Discusses the values presented in various handbooks for the boiling point and heat of vaporization of sulfuric acid, noting discrepencies. Analyzes various approaches to data presentation, discussing the data on sulfuric acid in light of the Trouton constant. Points out the need for a more critical use of tables. (JM)

  17. Modeling and measurement of boiling point elevation during water vaporization from aqueous urea for SCR applications

    Energy Technology Data Exchange (ETDEWEB)

    Dan, Ho Jin; Lee, Joon Sik [Seoul National University, Seoul (Korea, Republic of)

    2016-03-15

    Understanding of water vaporization is the first step to anticipate the conversion process of urea into ammonia in the exhaust stream. As aqueous urea is a mixture and the urea in the mixture acts as a non-volatile solute, its colligative properties should be considered during water vaporization. The elevation of boiling point for urea water solution is measured with respect to urea mole fraction. With the boiling-point elevation relation, a model for water vaporization is proposed underlining the correction of the heat of vaporization of water in the urea water mixture due to the enthalpy of urea dissolution in water. The model is verified by the experiments of water vaporization as well. Finally, the water vaporization model is applied to the water vaporization of aqueous urea droplets. It is shown that urea decomposition can begin before water evaporation finishes due to the boiling-point elevation.

  18. An electrical simulator of a nuclear fuel rod cooled by nucleate boiling

    Energy Technology Data Exchange (ETDEWEB)

    Costa, Antonio Carlos Lopes da [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN/CNEN-MG), Belo Horizonte, MG (Brazil)], e-mail: aclc@cdtn.br; Machado, Luiz; Koury, Ricardo Nicolau Nassar [Universidade Federal de Minas Gerais (UFMG), Belo Horizonte, MG (Brazil). Dept. de Engenharia Mecanica], e-mail: luizm@demec.ufmg.br; Bonjour, Jocelyn [CETHIL, UMR5008, CNRS, INSA-Lyon (France)], e-mail: jocelyn.bonjour@insa-lyon.fr; Passos, Julio Cesar [Universidade Federal de Santa Catarina (UFSC), Florianopolis, SC (Brazil). Dept. de Engenharia Mecanica. LEPTEN/Boiling], e-mail: jpassos@emc.ufsc.br

    2009-07-01

    This study investigates an electrical heated test section designed to simulate a nuclear fuel rod. This simulator comprises a stainless steel vertical tube, with length and outside diameter of 600 mm and 10 mm, respectively, inside which there is a high power electrical resistor. The heat generated is removed by means of enhanced confined subcooled nucleate boiling of water in an annular space containing 153 small metal inclined discs. The tests were performed under electrical power and pressure up to 48 kW and 40 bar, respectively. The results show that the experimental boiling heat transfer coefficients are in good agreement with those calculated using the Jens-Lottes correlation. (author)

  19. Improving the neutronic characteristics of a boiling water reactor by using uranium zirconium hydride fuel instead of uranium dioxide fuel

    Energy Technology Data Exchange (ETDEWEB)

    Galahom, Ahmed Abdelghafar [Higher Technological Institute, Ramadan (Egypt)

    2016-06-15

    The present work discusses two different models of boiling water reactor (BWR) bundle to compare the neutronic characteristics of uranium dioxide (UO{sub 2}) and uranium zirconium hydride (UZrH{sub 1.6}) fuel. Each bundle consists of four assemblies. The BWR assembly fueled with UO{sub 2} contains 8 × 8 fuel rods while that fueled with UZrH{sub 1.6} contains 9 × 9 fuel rods. The Monte Carlo N-Particle Transport code, based on the Mont Carlo method, is used to design three dimensional models for BWR fuel bundles at typical operating temperatures and pressure conditions. These models are used to determine the multiplication factor, pin-by-pin power distribution, axial power distribution, thermal neutron flux distribution, and axial thermal neutron flux. The moderator and coolant (water) are permitted to boil within the BWR core forming steam bubbles, so it is important to calculate the reactivity effect of voiding at different values. It is found that the hydride fuel bundle design can be simplified by eliminating water rods and replacing the control blade with control rods. UZrH{sub 1.6} fuel improves the performance of the BWR in different ways such as increasing the energy extracted per fuel assembly, reducing the uranium ore, and reducing the plutonium accumulated in the BWR through burnup.

  20. Explaining Melting and Evaporation below Boiling Point. Can Software Help with Particle Ideas?

    Science.gov (United States)

    Papageorgiou, George; Johnson, Philip; Fotiades, Fotis

    2008-01-01

    This paper reports the findings of a study exploring the use of a software package to help pupils understand particulate explanations for melting and evaporation below boiling point. Two matched classes in a primary school in Greece (ages 11-12, n = 16 and 19) were involved in a short intervention of six one hour lessons. Covering the same…

  1. Explaining Melting and Evaporation below Boiling Point. Can Software Help with Particle Ideas?

    Science.gov (United States)

    Papageorgiou, George; Johnson, Philip; Fotiades, Fotis

    2008-01-01

    This paper reports the findings of a study exploring the use of a software package to help pupils understand particulate explanations for melting and evaporation below boiling point. Two matched classes in a primary school in Greece (ages 11-12, n = 16 and 19) were involved in a short intervention of six one hour lessons. Covering the same…

  2. Students' Understanding of Boiling Points and Intermolecular Forces

    Science.gov (United States)

    Schmidt, Hans-Jurgen; Kaufmann, Birgit; Treagust, David F.

    2009-01-01

    In introductory chemistry courses students are presented with the model that matter is composed of particles, and that weak forces of attraction exist between them. This model is used to interpret phenomena such as solubility and melting points, and aids in understanding the changes in states of matter as opposed to chemical reactions. We…

  3. Students' Understanding of Boiling Points and Intermolecular Forces

    Science.gov (United States)

    Schmidt, Hans-Jurgen; Kaufmann, Birgit; Treagust, David F.

    2009-01-01

    In introductory chemistry courses students are presented with the model that matter is composed of particles, and that weak forces of attraction exist between them. This model is used to interpret phenomena such as solubility and melting points, and aids in understanding the changes in states of matter as opposed to chemical reactions. We…

  4. Global reaction mechanism for the auto-ignition of full boiling range gasoline and kerosene fuels

    Science.gov (United States)

    Vandersickel, A.; Wright, Y. M.; Boulouchos, K.

    2013-12-01

    Compact reaction schemes capable of predicting auto-ignition are a prerequisite for the development of strategies to control and optimise homogeneous charge compression ignition (HCCI) engines. In particular for full boiling range fuels exhibiting two stage ignition a tremendous demand exists in the engine development community. The present paper therefore meticulously assesses a previous 7-step reaction scheme developed to predict auto-ignition for four hydrocarbon blends and proposes an important extension of the model constant optimisation procedure, allowing for the model to capture not only ignition delays, but also the evolutions of representative intermediates and heat release rates for a variety of full boiling range fuels. Additionally, an extensive validation of the later evolutions by means of various detailed n-heptane reaction mechanisms from literature has been presented; both for perfectly homogeneous, as well as non-premixed/stratified HCCI conditions. Finally, the models potential to simulate the auto-ignition of various full boiling range fuels is demonstrated by means of experimental shock tube data for six strongly differing fuels, containing e.g. up to 46.7% cyclo-alkanes, 20% napthalenes or complex branched aromatics such as methyl- or ethyl-napthalene. The good predictive capability observed for each of the validation cases as well as the successful parameterisation for each of the six fuels, indicate that the model could, in principle, be applied to any hydrocarbon fuel, providing suitable adjustments to the model parameters are carried out. Combined with the optimisation strategy presented, the model therefore constitutes a major step towards the inclusion of real fuel kinetics into full scale HCCI engine simulations.

  5. Two dimensional, two fluid model for sodium boiling in LMFBR fuel assemblies

    Energy Technology Data Exchange (ETDEWEB)

    Granziera, M.R.; Kazimi, M.S.

    1980-05-01

    A two dimensional numerical model for the simulation of sodium boiling transient was developed using the two fluid set of conservation equations. A semiimplicit numerical differencing scheme capable of handling the problems associated with the ill-posedness implied by the complex characteristic roots of the two fluid problems was used, which took advantage of the dumping effect of the exchange terms. Of particular interest in the development of the model was the identification of the numerical problems caused by the strong disparity between the axial and radial dimensions of fuel assemblies. A solution to this problem was found which uses the particular geometry of fuel assemblies to accelerate the convergence of the iterative technique used in the model. Three sodium boiling experiments were simulated with the model, with good agreement between the experimental results and the model predictions.

  6. Estimating the physicochemical properties of polyhalogenated aromatic and aliphatic compounds using UPPER: part 1. Boiling point and melting point.

    Science.gov (United States)

    Admire, Brittany; Lian, Bo; Yalkowsky, Samuel H

    2015-01-01

    The UPPER (Unified Physicochemical Property Estimation Relationships) model uses enthalpic and entropic parameters to estimate 20 biologically relevant properties of organic compounds. The model has been validated by Lian and Yalkowsky on a data set of 700 hydrocarbons. The aim of this work is to expand the UPPER model to estimate the boiling and melting points of polyhalogenated compounds. In this work, 19 new group descriptors are defined and used to predict the transition temperatures of an additional 1288 compounds. The boiling points of 808 and the melting points of 742 polyhalogenated compounds are predicted with average absolute errors of 13.56 K and 25.85 K, respectively. Copyright © 2014 Elsevier Ltd. All rights reserved.

  7. Study of the radiotoxicity of actinides recycling in boiling water reactors fuel

    Energy Technology Data Exchange (ETDEWEB)

    Francois, J.L. [Departamento de Sistemas Energeticos, Facultad de Ingenieria, Universidad Nacional Autonoma de Mexico, Paseo Cuauhnahuac 8532, Jiutepec, Mor., 62550 (Mexico)], E-mail: juan.luis.francois@gmail.com; Guzman, J.R. [Division de Ciencias Basicas e Ingenieria, Universidad Autonoma Metropolitana-Iztapalapa, Av. San Rafael Atlixco 186 Col. Vicentina, Mexico, D.F., 09340 (Mexico)], E-mail: maestro_juan_rafael@hotmail.com; Martin-del-Campo, C. [Departamento de Sistemas Energeticos, Facultad de Ingenieria, Universidad Nacional Autonoma de Mexico, Paseo Cuauhnahuac 8532, Jiutepec, Mor., 62550 (Mexico)], E-mail: cecilia.martin.del.campo@gmail.com

    2009-10-15

    In this paper the production and destruction, as well as the radiotoxicity of plutonium and minor actinides (MA) obtained from the multi-recycling of boiling water reactors (BWR) fuel are analyzed. A BWR MOX fuel assembly, with uranium (from enrichment tails), plutonium and minor actinides is designed and studied using the HELIOS code. The actinides mass and the radiotoxicity of the spent fuel are compared with those of the once-through or direct cycle. Other type of fuel assembly is also analyzed: an assembly with enriched uranium and minor actinides; without plutonium. For this study, the fuel remains in the reactor for four cycles, where each cycle is 18 months length, with a discharge burnup of 48 MWd/kg. After this time, the fuel is placed in the spent fuel pool to be cooled during 5 years. Afterwards, the fuel is recycled for the next fuel cycle; 2 years are considered for recycle and fuel fabrication. Two recycles are taken into account in this study. Regarding radiotoxicity, results show that in the period from the spent fuel discharge until 1000 years, the highest reduction in the radiotoxicity related to the direct cycle is obtained with a fuel composed of MA and enriched uranium. However, in the period after few thousands of years, the lowest radiotoxicity is obtained using the fuel with plutonium and MA. The reduction in the radiotoxicity of the spent fuel after one or two recycling in a BWR is however very small for the studied MOX assemblies, reaching a maximum reduction factor of 2.

  8. Boiling Point

    Science.gov (United States)

    Jansen, Michael C.

    2002-01-01

    The author recounts his experiences he helped to investigate the accident which destroyed the Space Shuttle Challenger. The focus was on how he used novel approaches to investigate heat transfer in the shuttle's hydrogen tank, after an expert he sought for advice proved unhelpful.

  9. Structural Vector Description and Estimation of Normal Boiling Points for 66 Aromatic Hydrocarbons

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    A molecular vector-type descriptor containing 6 variables is used to describe the structure of aromatic hydrocarbons (AHs) and relate to normal boiling points (bp) of AHs. The correlation coefficient (R) between the estimated bp and experimental bp is 0.9988 and the root mean square error (RMS) is 7.907° C for 66 AHs. The RMS obtained by cross-validation is 9.131° C, which implies the relationship model having good prediction ability.

  10. Prediction on dielectric strength and boiling point of gaseous molecules for replacement of SF6.

    Science.gov (United States)

    Yu, Xiaojuan; Hou, Hua; Wang, Baoshan

    2017-04-15

    Developing the environment-friendly insulation gases to replace sulfur hexafluoride (SF6 ) has attracted considerable experimental and theoretical attentions but without success. A computational methodology was presented herein for prediction on dielectric strength and boiling point of arbitrary gaseous molecules in the purpose of molecular design and screening. New structure-activity relationship (SAR) models have been established by combining the density-dependent properties of the electrostatic potential surface, including surface area and the statistical variance of the surface potentials, with the molecular properties including polarizability, electronegativity, and hardness. All the descriptors in the SAR models were calculated using density functional theory. The substitution effect of SF6 by various functional groups was studied systematically. It was found that CF3 is the most effective functional group to improve the dielectric strength due to the large surface area and polarizability. However, all the substitutes exhibit higher boiling points than SF6 because the molecular hardness decreases. The balance between Er and Tb could be achieved by minimizing the local polarity of the molecules. SF5 CN and SF5 CFO were found to be the potent candidates to replace SF6 in view of their large dielectric strengths and low boiling points. © 2017 Wiley Periodicals, Inc. © 2017 Wiley Periodicals, Inc.

  11. Physical concept and calculation of boiling point in a pulsating heat pipe

    Directory of Open Access Journals (Sweden)

    Naumova A. N.

    2014-06-01

    Full Text Available LED development is accompanied by the need to ensure a constructive solution for the thermal conditions problem. For this purpose one can use pulsating heat pipes (PHP, that operate more efficiently after the start of heat carrier boiling. This article describes the physical representation and formula that allows determining the boiling point, which is a lower bound of the PHP effective operating range. It is shown that the main factors influencing the required heat flow are driving capillary pressure and velocity of the vapor bubble. The formula was obtained for the closed PHP made of the copper with water as a heat carrier. Information about this heat flux can be used for further design of cooling systems for heat-sensitive elements, such as LED for promising lighting devices.

  12. Experimental investigation of sodium boiling heat exchange in fuel subassembly mockup for perspective fast reactor safety substantiation

    Directory of Open Access Journals (Sweden)

    R.R. Khafizov

    2015-10-01

    Full Text Available Numerical modeling of ULOF-type accident development in sodium-cooled fast reactor carried out using the COREMELT code indicate the development and spreading of sodium boiling in the core accompanied with fluctuations of reactor technological parameters lasting over a period of several tens of a seconds. Significant influence on the calculation results is produced by two-phase coolant flow regime so the code boiling models requiring experimental confirmation. Design solution that includes the “sodium cavity” above the reactor core was suggested in order to exclude reactor accidents resulting in the destruction of reactor core elements. As the result of experimental studies on heat exchange during sodium boiling in the fast reactor fuel subassembly mockup with “sodium cavity” conducted on the AR-1 test facility under natural circulation conditions it was demonstrated possibility of long-term fuel pins simulators stable cooling. Schematic map of two-phase liquid metal flow regimes in fuel pin bundles is presented, data on the heat transfer during liquid metal coolant boiling in the fuel assembly are presented and analyzed. The obtained experimental data are used for further elaboration of the calculation model of sodium boiling in the fuel assembly and for COREMELT computer code verification.

  13. Investigation of water films on fuel rods in boiling water reactors using neutron tomography

    Energy Technology Data Exchange (ETDEWEB)

    Lanthen, Jonas

    2006-09-15

    In a boiling water reactor, thin films of liquid water around the fuel rods play a very important role in cooling the fuel, and evaporation of the film can lead to fuel damage. If the thickness of the water film could be measured accurately the reactor operation could be both safer and more economical. In this thesis, the possibility to use neutron tomography, to study thin water films on fuel rods in an experimental nuclear fuel set-up, has been investigated. The main tool for this has been a computer simulation software. The simulations have shown that very thin water films, down to around 20 pm, can be seen on fuel rods in an experimental set-up using neutron tomography. The spatial resolution needed to obtain this result is around 300 pm. A suitable detector system for this kind of experiment would be plastic fiber scintillators combined with a CCD camera. As a neutron source it would be possible to use a D-D neutron generator, which generates neutrons with energies of 2.5 MeV. Using a neutron generator with a high enough neutron yield and a detector with high enough detection efficiency, a neutron tomography to measure thin water films should take no longer than 25 - 30 minutes.

  14. Morphological control in polymer solar cells using low-boiling-point solvent additives

    Science.gov (United States)

    Mahadevapuram, Rakesh C.

    In the global search for clean, renewable energy sources, organic photovoltaics (OPVs) have recently been given much attention. Popular modern-day OPVs are made from solution-processible, carbon-based polymers (e.g. the model poly(3-hexylthiophene) that are intimately blended with fullerene derivatives (e.g. [6,6]-phenyl-C71-butyric acid methyl ester) to form what is known as the dispersed bulk-heterojunction (BHJ). This BHJ architecture has produced some of the most efficient OPVs to date, with reports closing in on 10% power conversion efficiency. To push efficiencies further into double digits, many groups have identified the BHJ nanomorphology---that is, the phase separations and grain sizes within the polymer: fullerene composite---as a key aspect in need of control and improvement. As a result, many methods, including thermal annealing, slow-drying (solvent) annealing, vapor annealing, and solvent additives, have been developed and studied to promote BHJ self-organization. Processing organic photovoltaic (OPV) blend solutions with high-boiling-point solvent additives has recently been used for morphological control in BHJ OPV cells. Here we show that even low-boiling-point solvents can be effective additives. When P3HT:PCBM OPV cells were processed with a low-boiling-point solvent tetrahydrafuran as an additive in parent solvent o-dichlorobenzene, charge extraction increased leading to fill factors as high as 69.5%, without low work-function cathodes, electrode buffer layers or thermal treatment. This was attributed to PCBM demixing from P3HT domains and better vertical phase separation, as indicated by photoluminescence lifetimes, hole mobilities, and shunt leakage currents. Dependence on solvent parameters and applicability beyond P3HT system was also investigated.

  15. SYNTHESIS OF POLYMER-STABILIZED RUTHENIUM COLLOIDS BY LOW BOILING POINT ALCOHOL REDUCTION

    Institute of Scientific and Technical Information of China (English)

    Ya-li Su; Xiu-ru Li; Yue-jin Tong; Yue-sheng Li

    2003-01-01

    Stable and well-dispersed poly(N-vinyl-2-pyrrolidone) (PVP)-stabilized ruthenium colloidal clusters were prepared via the reduction of ruthenium(Ⅲ) chloride by refluxing with low boiling point alcohols. Investigation of the size of Ru colloids by transmission electron microscopy (TEM) indicated that the average diameters could be controlled in the range of 1.2-1.6 nm with relative standard deviations of less than 0.33 by changing the molar ratio of PVP to Ru. The X-ray photoelectron spectroscopy (XPS) characterization verified the formation of elemental ruthenium colloids.

  16. A QSPR STUDY OF NORMAL BOILING POINT OF ORGANIC COMPOUNDS (ALIPHATIC ALKANES USING MOLECULAR DESCRIPTORS

    Directory of Open Access Journals (Sweden)

    B. Souyei

    2013-12-01

    Full Text Available A quantitative structure–property relationship (QSPR study is carried out to develop correlations that relate the molecular structures of organic compounds (Aliphatic Alkanes to their normal boiling point (NBP and two correlations were proposed for constitutionals and connectivity indices Models. The correlations are simple in application with good accuracy, which provide an easy, direct and relatively accurate way to calculate NBP. Such calculation gives us a model that gives results in remarkable correlations with the descriptors of blokes constitutionals (CON, and connectivity indices (CI (R2 = 0.950, δ = 0.766 (R2 = 0.969, δ = 0.782 respectively.

  17. Feasibility study of boiling water reactor core based on thorium-uranium fuel concept

    Energy Technology Data Exchange (ETDEWEB)

    Nunez-Carrera, Alejandro [Comision Nacional de Seguridad Nuclear y Salvaguardias, Dr. Barragan 779, Col Narvarte, 03020 Mexico D.F. (Mexico); Francois Lacouture, Juan Luis; Martin del Campo, Cecilia [Universidad Nacional Autonoma de Mexico, Facultad de Ingenieria, Paseo Cuauhnahuac 8532, Jiutepec, Mor. (Mexico); Espinosa-Paredes, Gilberto [Area de Ingenieria en Recursos Energeticos, Universidad Autonoma Metropolitana Iztapalapa, Apartado Postal 55-534, Mexico D.F. 09340 (Mexico)], E-mail: gepe@xanum.uam.mx

    2008-01-15

    The design of a boiling water reactor (BWR) equilibrium core using the thorium-uranium (blanket-seed) concept in the same integrated fuel assembly is presented in this paper. The lattice design uses the thorium conversion capability to {sup 233}U in a BWR spectrum. A core design was developed to achieve an equilibrium cycle of one effective full power year in a standard BWR with a reload of 104 fuel assemblies designed with an average {sup 235}U enrichment of 7.5 w/o in the seed sub-lattice. The main core operating parameters were obtained. It was observed that the analyzed parameters behave like those obtained in a standard BWR. The economic analysis shows that the fuel cycle cost of the proposed core design can be competitive with a standard uranium core design. Finally, a comparison of the toxicity of the spent fuel showed that the toxicity is lower in the thorium cycle than in other fuel cycles (UO{sub 2} and MOX uranium and plutonium) in the case of the once through cycle for light water reactors (LWR)

  18. Investigation of Minimum Film boiling Phenomena on Fuel Rods Under Blowdown Cooling Conditions

    Energy Technology Data Exchange (ETDEWEB)

    Stephen M. Bajorek; Michael Gawron; Timothy Etzel; Lucas Peterson

    2003-06-30

    Blowdon cooling heat transfer is an important process that occurs early in a hypothetical large break loss-of-coolant accident (LOCA) in a pressurized water reactor. During blowdown, the flow through the hot assembly is a post-critical heat flux dispersed droplet flow. The heat transfer mechanisms that occur in blowdown cooling are complex and depend on droplet and heated surface interaction. In a safety analysis, it is of considerable importance to determine the thermal-hydraulic conditions leading to the minimum film boiling temperature, Tmin. A flow boiling rig for measurement of blowdown cooling heat transfer and quench phenomena on a nuclear fuel rod simulator was designed and constructed for operation at up to 12.4 MPa. The test section consisted of a concentric annulus, with a 9.5 mm OD nuclear fuel rod simulator at the center. The rod was contained within a 0.85 mm thick, 19 mm OD 316 stainless steel tube, forming the flow channel. Two types of rods were tested; one type was sheathed with Inconel 600 while the other was clad with Zircaloy-2. Water was injected into the test section at the top of the heated length through an injection header. This header was an annular sign that fit around the fuel rod simulator and within the stainless steel tube. Small spacers aligned the injection header and prevented contract with either the heater rod or the tube. A series of small diameter holes at the bottom of the header caused the formation of droplets that became entrained with the steam flow. The test section design was such that quench would take place on the rod, and not along the channel outer annulus.

  19. Measurement of Nucleate Pool Boiling Heat Transfer Limit using Fuel Cladding Material

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Chi Young; Shin, Chang Hwan; Oh, Dong Seok; Chun, Tae Hyun; In, Wang Kee [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2013-10-15

    Zircaloy has been widely used as a fuel cladding material of light water reactor for more than three decades because it has a lower neutron absorption cross section and cracking rate. Recently, HANA-6 has been developed in KAERI (Korea Atomic Energy Research Institute) as the advanced fuel cladding for high burn-up fuel. Generally, under the normal and accident operating conditions of a nuclear reactor, the nuclear fuel cladding of zirconium based alloys undergoes the surface change, and the oxide layer can be formed. In such a case, the previous CHF correlations should be assessed and examined using the experimental results for not a fresh zircaloy surface but an oxidized one, to predict and examine the thermal margin and safety of a nuclear reactor core. Therefore, the experimental data using the oxidized zircaloy surface need to be provided quantitatively. In this paper, the CHF in saturated water pool boiling is measured and discussed using the specimens of zircaloy-4, HANA-6, and oxidized zircaloy-4 in high temperature air environment. The CHF of zircaloy-4, HANA-6, and oxidized surface was tested. Zircaloy-4 and HANA-6 had a similar CHF performance. This is because both are the zirconium based alloys, and appear the almost same water contact angle. On the other hands, the oxidized specimen became to be higher CHF than plain zircaloy-4 and HANA-6 specimens, due to smaller water contact angle (i. e., good hydrophilicity of specimen). The Kandlikar's (2001) correlation reasonably predicted the present experimental data.

  20. Boiling performance and material robustness of modified surfaces with multi scale structures for fuel cladding development

    Energy Technology Data Exchange (ETDEWEB)

    Jo, HangJin; Kim, Jin Man [Division of Advanced Nuclear Engineering, POSTECH, Pohang 790-784, Gyungbuk (Korea, Republic of); Yeom, Hwasung [Department of Nuclear Engineering and Engineering physics, UW-Madison, Madison, WI 53706, Unities States (United States); Lee, Gi Cheol [Department of Mechanical Engineering, POSTECH, Pohang 790-784, Gyungbuk (Korea, Republic of); Park, Hyun Sun, E-mail: hejsunny@postech.ac.kr [Division of Advanced Nuclear Engineering, POSTECH, Pohang 790-784, Gyungbuk (Korea, Republic of); Kiyofumi, Moriyama; Kim, Moo Hwan [Division of Advanced Nuclear Engineering, POSTECH, Pohang 790-784, Gyungbuk (Korea, Republic of); Sridharan, Kumar; Corradini, Michael [Department of Nuclear Engineering and Engineering physics, UW-Madison, Madison, WI 53706, Unities States (United States)

    2015-09-15

    Highlights: • We improved boiling performance and material robustness using surface modification. • We combined micro/millimeter post structures and nanoparticles with heat treatments. • Compactly-arranged micrometer posts had improved boiling performance. • CHF increased significantly due to capillary pumping by the deposited NP layers. • Sintering procedure increased mechanical strength of the NP coating surface. - Abstract: By regulating the geometrical characteristics of multi-scale structures and by adopting heat treatment for protective layer of nanoparticles (NPs), we improved critical heat flux (CHF), boiling heat transfer (BHT), and mechanical robustness of the modified surface. We fabricated 1-mm and 100-μm post structures and deposited NPs on the structured surface as a nano-scale structured layer and protective layer at the same time, then evaluated the CHF and BHT and material robustness of the modified surfaces. On the structured surfaces without NPs, the surface with compactly-arranged micrometer posts had improved CHF (118%) and BHT (41%). On the surface with structures on which NPs had been deposited, CHF increased significantly (172%) due to capillary pumping by the deposited NP layers. The heat treatment improved robustness of coating layer in comparison to the one of before heat treatment. In particular, low-temperature sintering increased the hardness of the modified surface by 140%. The increased mechanical strength of the NP coating is attributed to reduction in coating porosity during sintering. The combination of micrometer posts structures and sintered NP coating can increase the safety, efficiency and reliability of advanced nuclear fuel cladding.

  1. Experimental research on dryout point of flow boiling in narrow annular channels

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    An experimental research on the dryout point of flow boiling in narrow annular channels under low mass flux with 1.55 mm and 1.05 mm annular gap, respectively, is conducted. Distilled water is used as working fluid and the range of pressure is limited within 2.0~4.0 MPa and that of mass flux is 26.0~69.0 kg·m-2·s-1. The relation of critical heat flux (CHF) and critical qualities with mass flux and pressure are revealed. It is found that the critical qualities decrease with the increasing mass flux and increase with the increasing inlet qualities in externally heated annuli.Under the same conditions, critical qualities in the outer tube are always larger than those in the inner tube. The appearance of dryout point in bilaterally heated narrow annuli can be judged according to the ratio of qo/qi.

  2. Full evaporation headspace gas chromatography for sensitive determination of high boiling point volatile organic compounds in low boiling matrices.

    Science.gov (United States)

    Mana Kialengila, Didi; Wolfs, Kris; Bugalama, John; Van Schepdael, Ann; Adams, Erwin

    2013-11-08

    Determination of volatile organic components (VOC's) is often done by static headspace gas chromatography as this technique is very robust and combines easy sample preparation with good selectivity and low detection limits. This technique is used nowadays in different applications which have in common that they have a dirty matrix which would be problematic in direct injection approaches. Headspace by nature favors the most volatile compounds, avoiding the less volatile to reach the injector and column. As a consequence, determination of a high boiling solvent in a lower boiling matrix becomes challenging. Determination of VOCs like: xylenes, cumene, N,N-dimethylformamide (DMF), dimethyl sulfoxide (DMSO), N,N-dimethylacetamide (DMA), N-methyl-2-pyrrolidone (NMP), 1,3-dimethyl-2-imidazolidinone (DMI), benzyl alcohol (BA) and anisole in water or water soluble products are an interesting example of the arising problems. In this work, a headspace variant called full evaporation technique is worked out and validated for the mentioned solvents. Detection limits below 0.1 μg/vial are reached with RSD values below 10%. Mean recovery values ranged from 92.5 to 110%. The optimized method was applied to determine residual DMSO in a water based cell culture and DMSO and DMA in tetracycline hydrochloride (a water soluble sample). Copyright © 2013 Elsevier B.V. All rights reserved.

  3. Correlation of normal boiling points of dialkylalkyl phosphonates with topological indices on the gas chromatographic retention data

    Energy Technology Data Exchange (ETDEWEB)

    Panneerselvam, K., E-mail: kpselvam@igcar.gov.in; Rao, C.V.S. Brahmmananda; Antony, M.P.

    2015-01-20

    Highlights: • Normal boiling points of dialkylalkyl phosphonates measured by using GC technique. • Retention times have been determined by using temperature programmed technique. • Topological indices derived to encode the structural aspects of phosphonates. • QSPR discipline have been developed for predicting normal boiling points. • Statistical characteristics were used for validity of the QSPR discipline. - Abstract: The normal boiling point of twelve dialkylalkyl phosphonates has been determined using gas chromatographic technique. Dibutylhydrogen phosphonate has been used as reference for computing normal boiling point of dialkylalkyl phosphonates. Retention times of dialkylalkyl phosphonates have been measured by using temperature programmed technique. The topological indices namely, odd–even index, atom type index and steric effect index have been designed to capture surface interaction parameters. It was found to exhibit excellent correlation of the topological indices to the normal boiling point of dialkylalkyl phosphonates. Multiple linear regression analysis has been performed for development of quantitative structure property relationships discipline. It exhibited good predictive power (R{sup 2} = 0.998)

  4. Nickel Catalyzed Conversion of Cyclohexanol into Cyclohexylamine in Water and Low Boiling Point Solvents

    Directory of Open Access Journals (Sweden)

    Yunfei Qi

    2016-04-01

    Full Text Available Nickel is found to demonstrate high performance in the amination of cyclohexanol into cyclohexylamine in water and two solvents with low boiling points: tetrahydrofuran and cyclohexane. Three catalysts, Raney Ni, Ni/Al2O3 and Ni/C, were investigated and it is found that the base, hydrogen, the solvents and the support will affect the activity of the catalyst. In water, all the three catalysts achieved over 85% conversion and 90% cyclohexylamine selectivity in the presence of base and hydrogen at a high temperature. In tetrahydrofuran and cyclohexane, Ni/Al2O3 exhibits better activity than Ni/C under optimal conditions. Ni/C was stable during recycling in aqueous ammonia, while Ni/Al2O3 was not due to the formation of AlO(OH.

  5. Design and analysis of 19 pin annular fuel rod cluster for pressure tube type boiling water reactor

    Energy Technology Data Exchange (ETDEWEB)

    Deokule, A.P., E-mail: abhijit.deokule1986@gmail.com [Homi Bhabha National Institute, Trombay 400 085, Mumbai (India); Vishnoi, A.K.; Dasgupta, A.; Umasankari, K.; Chandraker, D.K.; Vijayan, P.K. [Bhabha Atomic Research Centre, Trombay 400 085, Mumbai (India)

    2014-09-15

    Highlights: • Development of 19 pin annular fuel rod cluster. • Reactor physics study of designed annular fuel rod cluster. • Thermal hydraulic study of annular fuel rod cluster. - Abstract: An assessment of 33 pin annular fuel rod cluster has been carried out previously for possible use in a pressure tube type boiling water reactor. Despite the benefits such as negative coolant void reactivity and larger heat transfer area, the 33 pin annular fuel rod cluster is having lower discharge burn up as compared to solid fuel rod cluster when all other parameters are kept the same. The power rating of this design cannot be increased beyond 20% of the corresponding solid fuel rod cluster. The limitation on the power is not due to physics parameters rather it comes from the thermal hydraulics side. In order to increase power rating of the annular fuel cluster, keeping same pressure tube diameter, the pin diameter was increased, achieving larger inside flow area. However, this reduces the number of annular fuel rods. In spite of this, the power of the annular fuel cluster can be increased by 30% compared to the solid fuel rod cluster. This makes the nineteen pin annular fuel rod cluster a suitable option to extract more power without any major changes in the existing design of the fuel. In the present study reactor physics and thermal hydraulic analysis carried out with different annular fuel rod cluster geometry is reported in detail.

  6. Fuel lattice design in a boiling water reactor using an ant-colony-based system

    Energy Technology Data Exchange (ETDEWEB)

    Montes, Jose Luis, E-mail: joseluis.montes@inin.gob.mx [Instituto Nacional de Investigaciones Nucleares, Carr. Mexico-Toluca S/N, La Marquesa, Ocoyoacac, Estado de Mexico, CP 52750 (Mexico); Facultad de Ciencias, Universidad Autonoma del Estado de Mexico (Mexico); Francois, Juan-Luis, E-mail: juan.luis.francois@gmail.com [Departamento de Sistemas Energeticos, Facultad de Ingenieria, Universidad Nacional Autonoma de Mexico, Paseo Cuauhnahuac 8532, Jiutepec, Mor., CP 62550 (Mexico); Ortiz, Juan Jose, E-mail: juanjose.ortiz@inin.gob.mx [Instituto Nacional de Investigaciones Nucleares, Carr. Mexico-Toluca S/N, La Marquesa, Ocoyoacac, Estado de Mexico, CP 52750 (Mexico); Martin-del-Campo, Cecilia, E-mail: cecilia.martin.del.campo@gmail.com [Departamento de Sistemas Energeticos, Facultad de Ingenieria, Universidad Nacional Autonoma de Mexico, Paseo Cuauhnahuac 8532, Jiutepec, Mor., CP 62550 (Mexico); Perusquia, Raul, E-mail: raul.perusquia@inin.gob.mx [Instituto Nacional de Investigaciones Nucleares, Carr. Mexico-Toluca S/N, La Marquesa, Ocoyoacac, Estado de Mexico, CP 52750 (Mexico)

    2011-06-15

    Research highlights: > We present an ant-colony-based system for BWR fuel lattice design and optimization. > Assessment of candidate solutions at 0.0 MWd/kg {sup 235}U seems to have a limited scope. > Suitable heuristic rules enable more realistic fuel lattice designs. > The election of the objective has a large impact in CPU time. > ACS enables an important decrease of the initial average U-235 enrichment. - Abstract: This paper presents a new approach to deal with the boiling water reactor radial fuel lattice design. The goal is to optimize the distribution of both, the fissionable material, and the reactivity control poison material inside the fuel lattice at the beginning of its life. An ant-colony-based system was used to search for either: the optimum location of the poisoned pin inside the lattice, or the U{sup 235} enrichment and Gd{sub 2}O{sub 3} concentrations. In the optimization process, in order to know the parameters of the candidate solutions, the neutronic simulator CASMO-4 transport code was used. A typical 10 x 10 BWR fuel lattice with an initial average U{sup 235} enrichment of 4.1%, used in the current operation of Laguna Verde Nuclear Power Plant was taken as a reference. With respect to that reference lattice, it was possible to decrease the average U{sup 235} enrichment up to 3.949%, this obtained value represents a decrease of 3.84% with respect to the reference U{sup 235} enrichment; whereas, the k-infinity was inside the {+-}100 pcm's range, and there was a difference of 0.94% between the local power peaking factor and the lattice reference value. Particular emphasis was made on defining the objective function which is used for making the assessment of candidate solutions. In a typical desktop personal computer, about four hours of CPU time were necessary for the algorithm to fulfill the goals of the optimization process. The results obtained with the application of the implemented system showed that the proposed approach represents a

  7. Enhanced mobility of poly(3-hexylthiophene) transistors by spin-coating from high-boiling-point solvents

    DEFF Research Database (Denmark)

    Chang, J.F.; Sun, B.Q.; Breiby, Dag Werner

    2004-01-01

    Chloroform is a general solvent for poly(3-hexylthiophene) (P3HT) active layers in field-effect transistors. However, its low boiling point and rapid evaporation limit the time for crystallization during the spin-coating process, and field-effect mobilities achieved for P3HT films spin-coated from...

  8. CADASTER QSPR Models for Predictions of Melting and Boiling Points of Perfluorinated Chemicals.

    Science.gov (United States)

    Bhhatarai, Barun; Teetz, Wolfram; Liu, Tao; Öberg, Tomas; Jeliazkova, Nina; Kochev, Nikolay; Pukalov, Ognyan; Tetko, Igor V; Kovarich, Simona; Papa, Ester; Gramatica, Paola

    2011-03-14

    Quantitative structure property relationship (QSPR) studies on per- and polyfluorinated chemicals (PFCs) on melting point (MP) and boiling point (BP) are presented. The training and prediction chemicals used for developing and validating the models were selected from Syracuse PhysProp database and literatures. The available experimental data sets were split in two different ways: a) random selection on response value, and b) structural similarity verified by self-organizing-map (SOM), in order to propose reliable predictive models, developed only on the training sets and externally verified on the prediction sets. Individual linear and non-linear approaches based models developed by different CADASTER partners on 0D-2D Dragon descriptors, E-state descriptors and fragment based descriptors as well as consensus model and their predictions are presented. In addition, the predictive performance of the developed models was verified on a blind external validation set (EV-set) prepared using PERFORCE database on 15 MP and 25 BP data respectively. This database contains only long chain perfluoro-alkylated chemicals, particularly monitored by regulatory agencies like US-EPA and EU-REACH. QSPR models with internal and external validation on two different external prediction/validation sets and study of applicability-domain highlighting the robustness and high accuracy of the models are discussed. Finally, MPs for additional 303 PFCs and BPs for 271 PFCs were predicted for which experimental measurements are unknown. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  9. Design of a boiling water reactor equilibrium core using thorium-uranium fuel

    Energy Technology Data Exchange (ETDEWEB)

    Francois, J-L.; Nunez-Carrera, A.; Espinosa-Paredes, G.; Martin-del-Campo, C.

    2004-10-06

    In this paper the design of a Boiling Water Reactor (BWR) equilibrium core using thorium is presented; a heterogeneous blanket-seed core arrangement concept was adopted. The design was developed in three steps: in the first step two different assemblies were designed based on the integrated blanket-seed concept, they are the blanket-dummy assembly and the blanket-seed assembly. The integrated blanketseed concept comes from the fact that the blanket and the seed rods are located in the same assembly, and are burned-out in a once-through cycle. In the second step, a core design was developed to achieve an equilibrium cycle of 365 effective full power days in a standard BWR with a reload of 104 fuel assemblies designed with an average 235U enrichment of 7.5 w/o in the seed sub-lattice. The main operating parameters, like power, linear heat generation rate and void distributions were obtained as well as the shutdown margin. It was observed that the analyzed parameters behave like those obtained in a standard BWR. The shutdown margin design criterion was fulfilled by addition of a burnable poison region in the assembly. In the third step an in-house code was developed to evaluate the thorium equilibrium core under transient conditions. A stability analysis was also performed. Regarding the stability analysis, five operational states were analyzed; four of them define the traditional instability region corner of the power-flow map and the fifth one is the operational state for the full power condition. The frequency and the boiling length were calculated for each operational state. The frequency of the analyzed operational states was similar to that reported for BWRs; these are close to the unstable region that occurs due to the density wave oscillation phenomena in some nuclear power plants. Four transient analyses were also performed: manual SCRAM, recirculation pumps trip, main steam isolation valves closure and loss of feed water. The results of these transients are

  10. Design of a boiling water reactor equilibrium core using thorium-uranium fuel

    Energy Technology Data Exchange (ETDEWEB)

    Francois, J-L.; Nunez-Carrera, A.; Espinosa-Paredes, G.; Martin-del-Campo, C.

    2004-10-06

    In this paper the design of a Boiling Water Reactor (BWR) equilibrium core using thorium is presented; a heterogeneous blanket-seed core arrangement concept was adopted. The design was developed in three steps: in the first step two different assemblies were designed based on the integrated blanket-seed concept, they are the blanket-dummy assembly and the blanket-seed assembly. The integrated blanketseed concept comes from the fact that the blanket and the seed rods are located in the same assembly, and are burned-out in a once-through cycle. In the second step, a core design was developed to achieve an equilibrium cycle of 365 effective full power days in a standard BWR with a reload of 104 fuel assemblies designed with an average 235U enrichment of 7.5 w/o in the seed sub-lattice. The main operating parameters, like power, linear heat generation rate and void distributions were obtained as well as the shutdown margin. It was observed that the analyzed parameters behave like those obtained in a standard BWR. The shutdown margin design criterion was fulfilled by addition of a burnable poison region in the assembly. In the third step an in-house code was developed to evaluate the thorium equilibrium core under transient conditions. A stability analysis was also performed. Regarding the stability analysis, five operational states were analyzed; four of them define the traditional instability region corner of the power-flow map and the fifth one is the operational state for the full power condition. The frequency and the boiling length were calculated for each operational state. The frequency of the analyzed operational states was similar to that reported for BWRs; these are close to the unstable region that occurs due to the density wave oscillation phenomena in some nuclear power plants. Four transient analyses were also performed: manual SCRAM, recirculation pumps trip, main steam isolation valves closure and loss of feed water. The results of these transients are

  11. Experimental studies of heat exchange for sodium boiling in the fuel assembly model: Safety substantiation of a promising fast reactor

    Science.gov (United States)

    Khafizov, R. R.; Poplavskii, V. M.; Rachkov, V. I.; Sorokin, A. P.; Trufanov, A. A.; Ashurko, Yu. M.; Volkov, A. V.; Ivanov, E. F.; Privezentsev, V. V.

    2017-01-01

    Numerical simulation of the ULOF-type accident development in a fast reactor with sodium coolant performed using the COREMELT code indicates that sodium boiling in the active core takes place. The boiling is accompanied by oscillations of the technological parameters of the reactor installation; these oscillations can go on during several tens of seconds. In this case, it is possible that a stable regime of removal of heat from residual energy release is implemented. The model of the two-phase coolant flow applied in the code has an important effect on the numerical results; that is why this model needs experimental verification. For eliminating the development of an accident resulting in destruction of the active core elements, a structural solution is proposed; the essence of it is the application of the sodium void above the reactor active core. The experimental installation was developed and the heat exchange at sodium boiling in the model fuel assembly of the fast reactor in the regimes of natural and forced circulation in the presence of the sodium void and the top end shield was studied. It was demonstrated that, in the presence of the sodium void, it is possible to provide long-term cooling of the fuel assembly for a thermal flux density on the fuel element simulator surface of up to 140 and 170 kW/m2 in the natural and forced circulation modes, respectively. The obtained data are used for more precise determination of the numerical model of sodium boiling in the fuel assembly and verification of the COREMELT code.

  12. Design and Analysis of Thorium-fueled Reduced Moderation Boiling Water Reactors

    Science.gov (United States)

    Gorman, Phillip Michael

    The Resource-renewable Boiling Water Reactors (RBWRs) are a set of light water reactors (LWRs) proposed by Hitachi which use a triangular lattice and high void fraction to incinerate fuel with an epithermal spectrum, which is highly atypical of LWRs. The RBWRs operate on a closed fuel cycle, which is impossible with a typical thermal spectrum reactor, in order to accomplish missions normally reserved for sodium fast reactors (SFRs)--either fuel self-sufficiency or waste incineration. The RBWRs also axially segregate the fuel into alternating fissile "seed" regions and fertile "blanket" regions in order to enhance breeding and leakage probability upon coolant voiding. This dissertation focuses on thorium design variants of the RBWR: the self-sufficient RBWR-SS and the RBWR-TR, which consumes reprocessed transuranic (TRU) waste from PWR used nuclear fuel. These designs were based off of the Hitachi-designed RBWR-AC and the RBWR-TB2, respectively, which use depleted uranium (DU) as the primary fertile fuel. The DU-fueled RBWRs use a pair of axially segregated seed sections in order to achieve a negative void coefficient; however, several concerns were raised with this multi-seed approach, including difficulty with controlling the reactor and unacceptably high axial power peaking. Since thorium-uranium fuel tends to have much more negative void feedback than uranium-plutonium fuels, the thorium RBWRs were designed to use a single elongated seed to avoid these issues. A series of parametric studies were performed in order to find the design space for the thorium RBWRs, and optimize the designs while meeting the required safety constraints. The RBWR-SS was optimized to maximize the discharge burnup, while the RBWR-TR was optimized to maximize the TRU transmutation rate. These parametric studies were performed on an assembly level model using the MocDown simulator, which calculates an equilibrium fuel composition with a specified reprocessing scheme. A full core model was

  13. A Closer Look at Trends in Boiling Points of Hydrides: Using an Inquiry-Based Approach to Teach Intermolecular Forces of Attraction

    Science.gov (United States)

    Glazier, Samantha; Marano, Nadia; Eisen, Laura

    2010-01-01

    We describe how we use boiling-point trends of group IV-VII hydrides to introduce intermolecular forces in our first-year general chemistry classes. Starting with the idea that molecules in the liquid state are held together by some kind of force that must be overcome for boiling to take place, students use data analysis and critical reasoning to…

  14. A Closer Look at Trends in Boiling Points of Hydrides: Using an Inquiry-Based Approach to Teach Intermolecular Forces of Attraction

    Science.gov (United States)

    Glazier, Samantha; Marano, Nadia; Eisen, Laura

    2010-01-01

    We describe how we use boiling-point trends of group IV-VII hydrides to introduce intermolecular forces in our first-year general chemistry classes. Starting with the idea that molecules in the liquid state are held together by some kind of force that must be overcome for boiling to take place, students use data analysis and critical reasoning to…

  15. Spent fuel assembly hardware: Characterization and 10 CFR 61 classification for waste disposal: Volume 3, Calculated activity profiles of spent nuclear fuel assembly hardware for boiling water reactors

    Energy Technology Data Exchange (ETDEWEB)

    Short, S.M.; Luksic, A.T.; Schutz, M.E.

    1989-06-01

    Consolidation of spent fuel is under active consideration as the US Department of Energy plans to dispose of spent fuel as required by the Nuclear Waste Policy Act of 1982. During consolidation, the fuel pins are removed from an intact fuel assembly and repackaged into a more compact configuration. After repackaging, approximately 30 kg of residual spent fuel assembly hardware per assembly that is also radioactive and required disposal. Understanding the nature of this secondary waste stream is critical to designing a system that will properly handle, package, store, and dispose of the waste. This report presents a methodology for estimating the radionuclide inventory in irradiated spent fuel hardware. Ratios are developed that allow the use of ORIGEN2 computer code calculations to be applied to regions that are outside the fueled region. The ratios are based on the analysis of samples of irradiated hardware from spent fuel assemblies. The results of this research are presented in three volumes. In Volume 1, the development of scaling factors that can be used with ORIGEN2 calculations to estimate activation of spent fuel assembly hardware is documented. The results from laboratory analysis of irradiated spent-fuel hardware samples are also presented in Volume 1. In Volume 2 and 3, the calculated flux profiles of spent nuclear fuel assemblies are presented for pressurized water reactors and boiling water reactors, respectively. The results presented in Volumes 2 and 3 were used to develop the scaling factors documented in Volume 1.

  16. Boiling Point Distribution of Hydrocarbon Types in Diesel Using Solid-Phase Extraction Followed by GC/FID-EIMS

    Institute of Scientific and Technical Information of China (English)

    Li Chengwei; Tian Songbai; Liu Zelong; Zhu Xinyi

    2008-01-01

    In this paper, a method was established to determine the boiling point distribution of hydro-carbon types in diesel. The diesel sample was separated into the saturate and aromatic fractions by means of solid-phase extraction (SPE), and each fraction was analyzed by GC/FID-EIMS. According to the relationship between boiling point and retention time of n-paraffins in the chromatogram, the percent-ages of saturates and aromatics at each temperature interval were calculated. According to the average mass spectra of the saturate and aromatic fractions at each temperature interval, the hydrocarbon types of the sample were identified through summation of characteristic mass fragments. Using this method,the changes in composition of diesel during hydrotreating process were studied. The results showed that hydrogenation of aromatics is the main reaction during the hydrotreating process. The more rings the aromatics have, the easier the hydrogenation reactions would take place. The aromatics were converted into cycloparaffins via the hydrogenation and saturation process, leading to an increase in low boiling point fractions in the hydrotreated oil.

  17. Azcaxalli: A system based on Ant Colony Optimization algorithms, applied to fuel reloads design in a Boiling Water Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Esquivel-Estrada, Jaime, E-mail: jaime.esquivel@fi.uaemex.m [Facultad de Ingenieria, Universidad Autonoma del Estado de Mexico, Cerro de Coatepec S/N, Toluca de Lerdo, Estado de Mexico 50000 (Mexico); Instituto Nacional de Investigaciones Nucleares, Carr. Mexico Toluca S/N, Ocoyoacac, Estado de Mexico 52750 (Mexico); Ortiz-Servin, Juan Jose, E-mail: juanjose.ortiz@inin.gob.m [Instituto Nacional de Investigaciones Nucleares, Carr. Mexico Toluca S/N, Ocoyoacac, Estado de Mexico 52750 (Mexico); Castillo, Jose Alejandro; Perusquia, Raul [Instituto Nacional de Investigaciones Nucleares, Carr. Mexico Toluca S/N, Ocoyoacac, Estado de Mexico 52750 (Mexico)

    2011-01-15

    This paper presents some results of the implementation of several optimization algorithms based on ant colonies, applied to the fuel reload design in a Boiling Water Reactor. The system called Azcaxalli is constructed with the following algorithms: Ant Colony System, Ant System, Best-Worst Ant System and MAX-MIN Ant System. Azcaxalli starts with a random fuel reload. Ants move into reactor core channels according to the State Transition Rule in order to select two fuel assemblies into a 1/8 part of the reactor core and change positions between them. This rule takes into account pheromone trails and acquired knowledge. Acquired knowledge is obtained from load cycle values of fuel assemblies. Azcaxalli claim is to work in order to maximize the cycle length taking into account several safety parameters. Azcaxalli's objective function involves thermal limits at the end of the cycle, cold shutdown margin at the beginning of the cycle and the neutron effective multiplication factor for a given cycle exposure. Those parameters are calculated by CM-PRESTO code. Through the Haling Principle is possible to calculate the end of the cycle. This system was applied to an equilibrium cycle of 18 months of Laguna Verde Nuclear Power Plant in Mexico. The results show that the system obtains fuel reloads with higher cycle lengths than the original fuel reload. Azcaxalli results are compared with genetic algorithms, tabu search and neural networks results.

  18. In-situ Observation of Boiling Dynamics on Fuel Cladding Surface in Non-pressurized Water Using Acoustic Emission Method

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Kaige; Baek, Seung Heon; Shim, Hee-Sang; Hur, Do Haeng; Lee, Deok Hyun [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2015-10-15

    In the PWR primary coolant system, a phenomenon of axial offset anomaly (AOA) can be caused due to accumulated boron hide out in porous CRUD deposition on the fuel cladding surface. Up to now, the CRUD deposition has been well known to be driven by subcooled nucleate boiling (SNB) on the cladding surface based on large scale experimental work. Therefore, monitoring and evaluation of the SNB-phenomenon is an important approach to study the CRUD deposition. Many attempts have been made to study the SNB and CRUD deposition using thermal hydraulic or model calculation. However, a comprehensive understanding of the SNB during CRUD deposition is still far from being realized. Acoustic emission (AE) technique, as an in-situ nondestructive evaluation (NDE) method, has been widely used to monitor the boiling activity in containers and pipes. Accordingly, this work aimed to investigate the exact AE characteristics of SNB-phenomenon on the fuel cladding surface at atmospheric pressure, with the purpose of providing an experimental groundwork for the AE investigation on SNB in high-temperature pressurized coolant system. In this study, we conducted an in-situ experimental observation of the bubble dynamic of SNB in non-pressurized water at atmospheric pressure using AE method. The AE of heater noise was confirmed to cluster between 8 and 26 khz. Three AE groups were detected during the boiling process in the Snob zones. AE group 1 and 3 seemed to be the results of bubble growth and collapse, while bubble departure from the cladding surface was reasonably associated with an isolated AE group 2.

  19. Indoor Particulate Matter Concentration, Water Boiling Time, and Fuel Use of Selected Alternative Cookstoves in a Home-Like Setting in Rural Nepal.

    Science.gov (United States)

    Ojo, Kristen D; Soneja, Sutyajeet I; Scrafford, Carolyn G; Khatry, Subarna K; LeClerq, Steven C; Checkley, William; Katz, Joanne; Breysse, Patrick N; Tielsch, James M

    2015-07-07

    Alternative cookstoves are designed to improve biomass fuel combustion efficiency to reduce the amount of fuel used and lower emission of air pollutants. The Nepal Cookstove Trial (NCT) studies effects of alternative cookstoves on family health. Our study measured indoor particulate matter concentration (PM2.5), boiling time, and fuel use of cookstoves during a water-boiling test in a house-like setting in rural Nepal. Study I was designed to select a stove to be used in the NCT; Study II evaluated stoves used in the NCT. In Study I, mean indoor PM2.5 using wood fuel was 4584 μg/m3, 1657 μg/m3, and 2414 μg/m3 for the traditional, alternative mud brick stove (AMBS-I) and Envirofit G-series, respectively. The AMBS-I reduced PM2.5 concentration but increased boiling time compared to the traditional stove (p-values Boiling times for alternative stoves in Study I were significantly longer than the traditional stove--a trade-off that may have implications for acceptability of the stoves among end users. These extended cooking times may increase cumulative exposure during cooking events where emission rates are lower; these differences must be carefully considered in the evaluation of alternative stove designs.

  20. Evaluation of Particle Counter Technology for Detection of Fuel Contamination Detection Utilizing Fuel System Supply Point

    Science.gov (United States)

    2014-06-19

    utilizing Fuel System Supply Point Joel Schmitigal U S Army Tank Automotive Research DISTRIBUTION STATEMENT A. Approved for public release; distribution...UNCLASSIFIED 6 UNCLASSIFIED Receipt Vehicle Fuel Tank Fuel Injector Aviation Fuel DEF (AUST) 5695B 18/16/13 Parker 18...Test Center while AMRDEC was conducting Alcohol to Jet (ATJ) fuel flight tests (17). The test results indicated that on-line particle counters

  1. Fuel lattice design in a boiling water reactor using a knowledge-based automation system

    Energy Technology Data Exchange (ETDEWEB)

    Tung, Wu-Hsiung, E-mail: wstong@iner.gov.tw; Lee, Tien-Tso; Kuo, Weng-Sheng; Yaur, Shung-Jung

    2015-11-15

    Highlights: • An automation system was developed for the fuel lattice radial design of BWRs. • An enrichment group peaking equalizing method is applied to optimize the design. • Several heuristic rules and restrictions are incorporated to facilitate the design. • The CPU time for the system to design a 10x10 lattice was less than 1.2 h. • The beginning-of-life LPF was improved from 1.319 to 1.272 for one of the cases. - Abstract: A knowledge-based fuel lattice design automation system for BWRs is developed and applied to the design of 10 × 10 fuel lattices. The knowledge implemented in this fuel lattice design automation system includes the determination of gadolinium fuel pin location, the determination of fuel pin enrichment and enrichment distribution. The optimization process starts by determining the gadolinium distribution based on the pin power distribution of a flat enrichment lattice and some heuristic rules. Next, a pin power distribution flattening and an enrichment grouping process are introduced to determine the enrichment of each fuel pin enrichment type and the initial enrichment distribution of a fuel lattice design. Finally, enrichment group peaking equalizing processes are performed to achieve lower lattice peaking. Several fuel lattice design constraints are also incorporated in the automation system such that the system can accomplish a design which meets the requirements of practical use. Depending on the axial position of the lattice, a different method is applied in the design of the fuel lattice. Two typical fuel lattices with U{sup 235} enrichment of 4.471% and 4.386% were taken as references. Application of the method demonstrates that improved lattice designs can be achieved through the enrichment grouping and the enrichment group peaking equalizing method. It takes about 11 min and 1 h 11 min of CPU time for the automation system to accomplish two design cases on an HP-8000 workstation, including the execution of CASMO-4

  2. Direct production of fractionated and upgraded hydrocarbon fuels from biomass

    Science.gov (United States)

    Felix, Larry G.; Linck, Martin B.; Marker, Terry L.; Roberts, Michael J.

    2014-08-26

    Multistage processing of biomass to produce at least two separate fungible fuel streams, one dominated by gasoline boiling-point range liquids and the other by diesel boiling-point range liquids. The processing involves hydrotreating the biomass to produce a hydrotreatment product including a deoxygenated hydrocarbon product of gasoline and diesel boiling materials, followed by separating each of the gasoline and diesel boiling materials from the hydrotreatment product and each other.

  3. Identification of polybrominated diphenyl ether metabolites based on calculated boiling points from COSMO-RS, experimental retention times, and mass spectral fragmentation patterns.

    Science.gov (United States)

    Simpson, Scott; Gross, Michael S; Olson, James R; Zurek, Eva; Aga, Diana S

    2015-02-17

    The COnductor-like Screening MOdel for Realistic Solvents (COSMO-RS) was used to predict the boiling points of several polybrominated diphenyl ethers (PBDEs) and methylated derivatives (MeO-BDEs) of monohydroxylated BDE (OH-BDE) metabolites. The linear correlation obtained by plotting theoretical boiling points calculated by COSMO-RS against experimentally determined retention times from gas chromatography-mass spectrometry facilitated the identification of PBDEs and OH-BDEs. This paper demonstrates the applicability of COSMO-RS in identifying unknown PBDE metabolites of 2,2',4,4'-tetrabromodiphenyl ether (BDE-47) and 2,2',4,4',6-pentabromodiphenyl ether (BDE-100). Metabolites of BDE-47 and BDE-100 were formed through individual incubations of each PBDE with recombinant cytochrome P450 2B6. Using calculated boiling points and characteristic mass spectral fragmentation patterns of the MeO-BDE positional isomers, the identities of the unknown monohydroxylated metabolites were proposed to be 2'-hydroxy-2,3',4,4'-tetrabromodiphenyl ether (2'-OH-BDE-66) from BDE-47, and 2'-hydroxy-2,3',4,4',6-pentabromodiphenyl ether (2'-OH-BDE-119) and 4-hydroxy-2,2',3,4',6-pentabromodiphenyl ether (4-OH-BDE-91) from BDE-100. The collective use of boiling points predicted with COSMO-RS, and characteristic mass spectral fragmentation patterns provided a valuable tool toward the identification of isobaric compounds.

  4. A low viscosity, low boiling point, clean solvent system for the rapid crystallisation of highly specular perovskite films

    Energy Technology Data Exchange (ETDEWEB)

    Noel, Nakita K.; Habisreutinger, Severin N.; Wenger, Bernard; Klug, Matthew T.; Hörantner, Maximilian T.; Johnston, Michael B.; Nicholas, Robin J.; Moore, David T.; Snaith, Henry J.

    2017-01-01

    Perovskite-based photovoltaics have, in recent years, become poised to revolutionise the solar industry. While there have been many approaches taken to the deposition of this material, one-step spin-coating remains the simplest and most widely used method in research laboratories. Although spin-coating is not recognised as the ideal manufacturing methodology, it represents a starting point from which more scalable deposition methods, such as slot-dye coating or ink-jet printing can be developed. Here, we introduce a new, low-boiling point, low viscosity solvent system that enables rapid, room temperature crystallisation of methylammonium lead triiodide perovskite films, without the use of strongly coordinating aprotic solvents. Through the use of this solvent, we produce dense, pinhole free films with uniform coverage, high specularity, and enhanced optoelectronic properties. We fabricate devices and achieve stabilised power conversion efficiencies of over 18% for films which have been annealed at 100 degrees C, and over 17% for films which have been dried under vacuum and have undergone no thermal processing. This deposition technique allows uniform coating on substrate areas of up to 125 cm2, showing tremendous promise for the fabrication of large area, high efficiency, solution processed devices, and represents a critical step towards industrial upscaling and large area printing of perovskite solar cells.

  5. Indoor Particulate Matter Concentration, Water Boiling Time, and Fuel Use of Selected Alternative Cookstoves in a Home-Like Setting in Rural Nepal

    Directory of Open Access Journals (Sweden)

    Kristen D. Ojo

    2015-07-01

    Full Text Available Alternative cookstoves are designed to improve biomass fuel combustion efficiency to reduce the amount of fuel used and lower emission of air pollutants. The Nepal Cookstove Trial (NCT studies effects of alternative cookstoves on family health. Our study measured indoor particulate matter concentration (PM2.5, boiling time, and fuel use of cookstoves during a water-boiling test in a house-like setting in rural Nepal. Study I was designed to select a stove to be used in the NCT; Study II evaluated stoves used in the NCT. In Study I, mean indoor PM2.5 using wood fuel was 4584 μg/m3, 1657 μg/m3, and 2414 μg/m3 for the traditional, alternative mud brick stove (AMBS-I and Envirofit G-series, respectively. The AMBS-I reduced PM2.5 concentration but increased boiling time compared to the traditional stove (p-values < 0.001. Unlike AMBS-I, Envirofit G-series did not significantly increase overall fuel consumption. In Phase II, the manufacturer altered Envirofit stove (MAES and Nepal Nutrition Intervention Project Sarlahi (NNIPS altered Envirofit stove (NAES, produced lower mean PM2.5, 1573 μg/m3 and 1341 μg/m3, respectively, relative to AMBS-II 3488 μg/m3 for wood tests. The liquid propane gas stove had the lowest mean PM2.5 concentrations, with measurements indistinguishable from background levels. Results from Study I and II showed significant reduction in PM2.5 for all alternative stoves in a controlled setting. In study I, the AMBS-I stove required more fuel than the traditional stove. In contrast, in study II, the MAES and NAES stoves required statistically less fuel than the AMBS-II. Reductions and increases in fuel use should be interpreted with caution because the composition of fuels was not standardized—an issue which may have implications for generalizability of other findings as well. Boiling times for alternative stoves in Study I were significantly longer than the traditional stove—a trade-off that may have implications for

  6. Review of magnetic properties and magnetocaloric effect in the intermetallic compounds of rare earth with low boiling point metals

    Science.gov (United States)

    Ling-Wei, Li

    2016-03-01

    The magnetocaloric effect (MCE) in many rare earth (RE) based intermetallic compounds has been extensively investigated during the last two decades, not only due to their potential applications for magnetic refrigeration but also for better understanding of the fundamental problems of the materials. This paper reviews our recent progress on studying the magnetic properties and MCE in some binary or ternary intermetallic compounds of RE with low boiling point metal(s) (Zn, Mg, and Cd). Some of them exhibit promising MCE properties, which make them attractive for low temperature magnetic refrigeration. Characteristics of the magnetic transition, origin of large MCE, as well as the potential application of these compounds are thoroughly discussed. Additionally, a brief review of the magnetic and magnetocaloric properties in the quaternary rare earth nickel boroncarbides RENi2B2C superconductors is also presented. Project supported by the National Natural Science Foundation of China (Grant Nos. 11374081 and 11004044), the Fundamental Research Funds for the Central Universities, China (Grant Nos. N150905001, L1509006, and N140901001), the Japan Society for the Promotion of Science Postdoctoral Fellowships for Foreign Researchers (Grant No. P10060), and the Alexander von Humboldt (AvH) Foundation (Research stipend to L. Li).

  7. On Use of the Variable Zagreb vM2 Index in QSPR: Boiling Points of Benzenoid Hydrocarbons

    Directory of Open Access Journals (Sweden)

    Albin Jurić

    2004-12-01

    Full Text Available The variable Zagreb vM2 index is introduced and applied to the structure-boiling point modeling of benzenoid hydrocarbons. The linear model obtained (thestandard error of estimate for the fit model Sfit=6.8 oC is much better than thecorresponding model based on the original Zagreb M2 index (Sfit=16.4 oC. Surprisingly,the model based on the variable vertex-connectivity index (Sfit=6.8 oC is comparable tothe model based on vM2 index. A comparative study with models based on the vertex-connectivity index, edge-connectivity index and several distance indices favours modelsbased on the variable Zagreb vM2 index and variable vertex-connectivity index.However, the multivariate regression with two-, three- and four-descriptors givesimproved models, the best being the model with four-descriptors (but vM2 index is notamong them with Sfit=5 oC, though the four-descriptor model contaning vM2 index isonly slightly inferior (Sfit=5.3 oC.

  8. Development of a water boil-off spent-fuel calorimeter system. [To measure decay heat generation rate

    Energy Technology Data Exchange (ETDEWEB)

    Creer, J.M.; Shupe, J.W. Jr.

    1981-05-01

    A calorimeter system was developed to measure decay heat generation rates of unmodified spent fuel assemblies from commercial nuclear reactors. The system was designed, fabricated, and successfully tested using the following specifications: capacity of one BWR or PWR spent fuel assembly; decay heat generation range 0.1 to 2.5 kW; measurement time of < 12 h; and an accuracy of +-10% or better. The system was acceptance tested using a dc reference heater to simulate spent fuel assembly heat generation rates. Results of these tests indicated that the system could be used to measure heat generation rates between 0.5 and 2.5 kW within +- 5%. Measurements of heat generation rates of approx. 0.1 kW were obtained within +- 15%. The calorimeter system has the potential to permit measurements of heat generation rates of spent fuel assemblies and other devices in the 12- to 14-kW range. Results of calorimetry of a Turkey Point spent fuel assembly indicated that the assembly was generating approx. 1.55 kW.

  9. Uncertainty evaluation of brake fluid equilibrium reflux boiling point%制动液平衡回流沸点不确定度的评定

    Institute of Scientific and Technical Information of China (English)

    王静; 张志芳; 唐林

    2014-01-01

    ERBP is the basic indicator of brake fluid performance. Five aspects of the brake fluid equilibri-um reflux boiling point uncertainty are evaluated in this article and to determine which one contributes most. The conclusions have certain significance to guide the brake fluid boiling point test.%平衡回流沸点是衡量制动液产品性能优劣的最基本指标。本文从五个方面对制动液平衡回流沸点不确定度进行评定,以确定哪些分量对最终不确定贡献最大,所得结论对指导制动液沸点检测具有一定意义。

  10. Prediction of Boiling Point of Alkanes by Artificial Neural Network%利用人工神经网络法预测烷烃的沸点

    Institute of Scientific and Technical Information of China (English)

    李谦; 王黎; 李伟; 房晓敏

    2001-01-01

    有机物沸点是有机物的一种非常重要的性质. 采用人工神经网络模型,选用结构描述码作为输入特征参数对烷烃的沸点进行预测,得到了很高的预测精度. 该方法还可作为对有机化合物的其他性质进行预测的一种有效手段.%The boiling point is a very important property of organics. The paper uses the structural discribing code as input data to predict precisely the boiling point of alkanes by artificial neural network. This method proves effective on predicting other important properties of organics.

  11. Reorientational dynamics in molecular liquids as revealed by dynamic light scattering: From boiling point to glass transition temperature

    Science.gov (United States)

    Schmidtke, B.; Petzold, N.; Kahlau, R.; Rössler, E. A.

    2013-08-01

    We determine the reorientational correlation time τ of a series of molecular liquids by performing depolarized light scattering experiments (double monochromator, Fabry-Perot interferometry, and photon correlation spectroscopy). Correlation times in the range 10-12 s-100 s are compiled, i.e., the full temperature interval between the boiling point and the glass transition temperature Tg is covered. We focus on low-Tg liquids for which the high-temperature limit τ ≅ 10-12 s is easily accessed by standard spectroscopic equipment (up to 440 K). Regarding the temperature dependence three interpolation formulae of τ(T) with three parameters each are tested: (i) Vogel-Fulcher-Tammann equation, (ii) the approach recently discussed by Mauro et al. [Proc. Natl. Acad. Sci. U.S.A. 106, 19780 (2009)], and (iii) our approach decomposing the activation energy E(T) in a constant high temperature value E∞ and a "cooperative part" Ecoop(T) depending exponentially on temperature [Schmidtke et al., Phys. Rev. E 86, 041507 (2012)], 10.1103/PhysRevE.86.041507. On the basis of the present data, approaches (i) and (ii) are insufficient as they do not provide the correct crossover to the high-temperature Arrhenius law clearly identified in the experimental data while approach (iii) reproduces the salient features of τ(T). It allows to discuss the temperature dependence of the liquid's dynamics in terms of a Ecoop(T)/E∞ vs. T/E∞ plot and suggests that E∞ controls the energy scale of the glass transition phenomenon.

  12. Optimum structural properties for an anode current collector used in a polymer electrolyte membrane water electrolyzer operated at the boiling point of water

    Science.gov (United States)

    Li, Hua; Fujigaya, Tsuyohiko; Nakajima, Hironori; Inada, Akiko; Ito, Kohei

    2016-11-01

    This study attempts to optimize the properties of the anode current collector of a polymer electrolyte membrane water electrolyzer at high temperatures, particularly at the boiling point of water. Different titanium meshes (4 commercial ones and 4 modified ones) with various properties are experimentally examined by operating a cell with each mesh under different conditions. The average pore diameter, thickness, and contact angle of the anode current collector are controlled in the ranges of 10-35 μm, 0.2-0.3 mm, and 0-120°, respectively. These results showed that increasing the temperature from the conventional temperature of 80 °C to the boiling point could reduce both the open circuit voltage and the overvoltages to a large extent without notable dehydration of the membrane. These results also showed that decreasing the contact angle and the thickness suppresses the electrolysis overvoltage largely by decreasing the concentration overvoltage. The effect of the average pore diameter was not evident until the temperature reached the boiling point. Using operating conditions of 100 °C and 2 A/cm2, the electrolysis voltage is minimized to 1.69 V with a hydrophilic titanium mesh with an average pore diameter of 21 μm and a thickness of 0.2 mm.

  13. Influence Factor Analysis of FCC Heavy Gasoline End Boiling Point%催化重汽油干点的影响因素分析

    Institute of Scientific and Technical Information of China (English)

    庞春天; 张颖; 李雅华

    2014-01-01

    国内某石化公司1 Mt/a 的催化裂化装置出现了重汽油干点偏高的情况。通过分析装置现有操作数据并针对该数据进行了详细核算,找到了导致重汽油干点偏高的具体原因。分析讨论了重汽油干点的影响因素,并提出了降低重汽油干点的调整方案。%The heavy gasoline from 1 Mt/a FCC unit in a domestic petrochemical company has higher end boiling point. In this paper, through analyzing and calculating the existed operating data, specific reasons to cause higher end boiling point were determined. The influence factors of heavy gasoline end boiling point were discussed, and the solutions were put forward.

  14. Modeling and Thermal Performance Evaluation of Porous Curd Layers in Sub-Cooled Boiling Region of PWRs and Effects of Sub-Cooled Nucleate Boiling on Anomalous Porous Crud Deposition on Fuel Pin Surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Barclay Jones

    2005-06-27

    A significant number of current PWRs around the world are experiencing anomalous crud deposition in the sub-cooled region of the core, resulting in an axial power shift or Axial Offset Anomaly (AOA), a condition that continues to elude prediction of occurrence and thermal/neutronic performance. This creates an operational difficulty of not being able to accurately determine power safety margin. In some cases this condition has required power ''down rating'' by as much as thirty percent and the concomitant considerable loss of revenue for the utility. This study examines two aspects of the issue: thermal performance of crud layer and effect of sub-cooled nucleate boiling on the solute concentration and its influence on initiation of crud deposition/formation on fuel pin surface.

  15. Fuel and fuel blending components from biomass derived pyrolysis oil

    Science.gov (United States)

    McCall, Michael J.; Brandvold, Timothy A.; Elliott, Douglas C.

    2012-12-11

    A process for the conversion of biomass derived pyrolysis oil to liquid fuel components is presented. The process includes the production of diesel, aviation, and naphtha boiling point range fuels or fuel blending components by two-stage deoxygenation of the pyrolysis oil and separation of the products.

  16. Boiling water reactors with uranium-plutonium mixed oxide fuel. Report 5: Analysis of the reactivity coefficients and the stability of a BWR loaded with MOx fuel

    Energy Technology Data Exchange (ETDEWEB)

    Demaziere, C. [CEA Centre d' Etudes de Cadarache, 13 - Saint-Paul-lez-Durance (France). Direction des Reacteurs Nucleaires

    2000-01-01

    This report is a part of the project titled 'Boiling Water Reactors With Uranium-Plutonium Mixed Oxide (MOx) Fuel'. The aim of this study is to model the impact of a core loading pattern containing MOx bundles upon the main characteristics of a BWR (reactivity coefficients, stability, etc.). For this purpose, the Core Management System (CMS) codes of Studsvik Scandpower are used. This package is constituted by CASMO-4/TABLES-3/SIMULATE-3. It has been shown in previous reports that these codes are able to accurately represent and model MOx bundles. This report is thus devoted to the study of BWR cores loaded (partially or totally) with MOx bundles. The plutonium quality used is the Pu type 2016 (mostly Pu-239, 56 %, and Pu-240, 26 %), but a variation of the plutonium isotopic vector was also investigated, in case of a partial MOx loading. One notices that the reactivity coefficients do not present significant changes in comparison with a full UOx loading. Nevertheless, two main problems arise: the shutdown margin at BOC is lower than 1 % and the stability to in-phase oscillations is slightly decreased. (The SIMULATE-3 version used for this study does not contain the latest MOx enhancements described in literature, since these code developments have not been provided to the department. Nevertheless, as the nominal average enrichment of the MOx bundles is 5.41 % (total amount of plutonium), which can still be considered as a relatively low enrichment, the accuracy of the CMS codes is acceptable without the use of the MOx improvements for this level of Pu enrichment.

  17. Qualification of the Darwin code for the studies of the fuel cycle relative to the boiling water reactors; Qualification du formulaire Darwin pour les etudes du cycle du combustible pour les reacteurs a eau bouillante

    Energy Technology Data Exchange (ETDEWEB)

    Allais, V

    1998-03-01

    This thesis was carried out in the framework of fuel cycles studies in partnership with COGEMA; the aim is to determine physics parameters characterising Boiling Reactor Assemblies. Those reactors Firstly distinguish themselves from Pressurised Water Reactor by the boiling of the moderator in the core and secondary by the strong neutronics heterogeneity due to complex design. The diphasic mixture formed is characterised by the void fraction parameter. The loss of information, and neutronic studies characteristics of Boiling Water Reactors led us to make preliminary studies having in view to quantify the void fraction impact on the isotopics evolution. Studies on neutronics influence of assemblies and control rods from the immediate environment allows to define the cluster size to describe. The radial description optimisation with APOLLO-2 is necessary to improve the calculation performance and to reduce the errors coming from the modelization. The following points were studied: pellet radial discretization, clustering of cells characterized by a similar behaviour, options in flux spatial calculation (interface current formalism), self-shielding optimisation (specific to each isotopes). The three dimensional modelization with CRONOS-2 and the simplified accounting of the thermohydraulics / neutronics coupling done by a procedure developed and written during this thesis, allow an evaluation of axial distribution of void fraction, power and burn-up during the irradiation. The comparison with experimental analytic results of complete assembly and pin samples dissolutions allows the qualification of this procedure and confirms the necessity to take into account the void fraction axial variation during the evolution. The application of an automatic coupling with the DARWIN cycle code will allow a precise burnup calculation to be utilized in an industrial procedure. (author)

  18. Biomass to fuels : Upgrading of flash pyrolysis oil by reactive distillation using a high boiling alcohol and acid catalysts

    NARCIS (Netherlands)

    Mahfud, F.H.; Melian Cabrera, I.V.; Manurung, R.M.; Heeres, H.J.

    2007-01-01

    We here report our studies on the upgrading of flash pyrolysis oil using an improved alcohol treatment method. The method consists of treating pyrolysis oil with a high boiling alcohol like n-butanol in the presence of a (solid) acid catalyst at 323-353 K under reduced pressure (<10 kPa). Using this

  19. Changes of Petroleum Acid Distribution Characterized by FT-ICR MS in Heavy Acidic Crude Oil after True Boiling Point Distillation

    Institute of Scientific and Technical Information of China (English)

    Liu Yingrong; Zhang Qundan; Wang Wei; Liu Zelong; Zhu Xinyi; Tian Songbai

    2014-01-01

    The molecular transformations of carboxylic acids in heavy acidic SL crude before and after true boiling point distillation were examined by ultra-high resolution negative-ion electrospray ionization (ESI) Fourier transform ion cyclo-tron resonance mass spectrometry (FT-ICR MS). The acid class (heteroatom number), type (z numbers) and carbon number distributions were positively characterized. It was found out that the total acid number (TAN) of SL crude decreased after true boiling point distillation, and the abundance of O2 class in mass spectra was also found to be reduced from 67.6%to 34.5%in SL TBP mixed crude as measured by MS spectra, indicating to a potential carboxylic acid decomposition. However, it was interesting that the carboxylic acids type distribution in both oils was almost the same although their relative abundance in SL TBP mixed crude turned to be much lower, suggesting that various petroleum carboxylic acid types have the similar thermal decomposition reaction behavior. Furthermore, for each O2 type of acids in SL TBP mixed crude, the abundance of carboxylic acids with carbon number higher than 35 was reduced greatly, especially for those with carbon number higher than 60, the mass peaks of which were nearly totally removed, indicating that the large carboxylic acid molecules in heavy fractions decomposed more signiifcantly because of longer heating time during the true boiling point distillation process. As a result, the reduction of TAN may be caused by the thermal decomposition of carboxylic acids especially those with high carbon number, suggesting that quick distillation or much lower pressure is required to avoid the thermal decomposition.

  20. Micro distillation of crude oil to obtain TBP (True Boiling Points) curve; Micro destilacao de petroleo para obtencao da curva PEV (Ponto de Ebulicao Verdadeiro)

    Energy Technology Data Exchange (ETDEWEB)

    Marques, Maria de Lourdes S.P.; Mendes, Luana de Jesus [Fundacao Gorceix, Ouro Preto, MG (Brazil); Medina, Lilian Carmen [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil)

    2008-07-01

    PETROBRAS and others petroleum companies adopt the ASTM norms as reference method for oil distillation, ASTM D2892 (2005) that uses columns with 14 to 18 theoretical plates and the ASTM D 5236 (2003) , that distills mixture of heavy hydrocarbons with boiling point over 150 deg C. The result of these two distillations is the TBP (True Boiling Point) curve that is the main tool to define the yield of oil derivatives, the 'royalties' payment, the oil price for commercialization and the logistic support of oil location or in new plants projects of distillation and optimization studies. This procedure has some limitations as the volume sample, at least 1L, and the time of distillation, 2 to 4 days. The objective of this work is to propose a new alternative to attain de PEV curve, developing a new methodology using micro scale distillation that uses a more efficient column than the conventional method. Graphics of both methods were created and the results between the conventional and the micro distillation received statistical treatment to prove the equivalence between them. (author)

  1. Improving efficiency and color purity of poly(9,9-dioctylfluorene) through addition of a high boiling-point solvent of 1-chloronaphthalene

    Science.gov (United States)

    Liang, Junfei; Yu, Lei; Zhao, Sen; Ying, Lei; Liu, Feng; Yang, Wei; Peng, Junbiao; Cao, Yong

    2016-07-01

    In this work, the β-phase of poly(9,9-dioctylfluorene) (PFO) was used as a probe to study the effects of the addition of a high boiling-point solvent of 1-chloronaphthalene on the nanostructures and electroluminescence of PFO films. Both absorption and photoluminescence spectra showed that the content of the β-phase in PFO film was obviously enhanced as a result of the addition of a small amount of 1-chloronaphthalene into the processing solvent of p-xylenes. Apparently rougher morphology associated with the effectively enhanced ordering of polymer chains across the entire film was observed for films processed from p-xylene solutions consisting of a certain amount of 1-chloronaphthalene, as revealed by atomic force microscopy and grazing incidence x-ray diffraction measurements. In addition to the effects on the nanostructures of films, of particular interest is that the performance and color purity of polymer light-emitting devices can be noticeably enhanced upon the addition of 1-chloronaphthalene. These observations highlight the importance of controlling the nanostructures of the emissive layer, and demonstrate that the addition of a low volume ratio of high boiling-point additive can be a promising strategy to attain high-performance polymer light-emitting diodes.

  2. Variation of Boiling Point with Salting Effect in Vapor-Liquid Equilibrium%汽液平衡盐效应中的沸点变化

    Institute of Scientific and Technical Information of China (English)

    孙仁义; 朱元举; 冷春莉

    2003-01-01

    测定了在恒压(100.0kPa)条件下若干含盐双液系(甲醇-水,乙醇-水,正丙醇-水)的沸点变化.实验结果表明引起溶液沸点降低"反常现象"发生的必要条件是易挥发组分被盐析或难挥发组分被盐溶.经热力学分析表明上述实验结果是一个具有普遍意义的结论.%The influence of some nonvolatile salts on boiling point of methanol-water, ethanol-water andn-propanol-water systems was determined at fixed liquid composition and given pressure (100.0 kPa).The experimental results indicate that the requisite of boiling point depression is that the more volatilecomponent must be salted out, the less volatile component must be salted in. This conclusion, basedon thermodynamical consideration, can be taken as a universal rule that governs the variation of boilingpoint when a little nonvolatile salt dissolves in liquid mixture with constant composition.

  3. Alternative aviation turbine fuels

    Science.gov (United States)

    Grobman, J.

    1977-01-01

    The efficient utilization of fossil fuels by future jet aircraft may necessitate the broadening of current aviation turbine fuel specifications. The most significant changes in specifications would be an increased aromatics content and a higher final boiling point in order to minimize refinery energy consumption and costs. These changes would increase the freezing point and might lower the thermal stability of the fuel and could cause increased pollutant emissions, increased smoke and carbon formation, increased combustor liner temperatures, and poorer ignition characteristics. This paper discusses the effects that broadened specification fuels may have on present-day jet aircraft and engine components and the technology required to use fuels with broadened specifications.

  4. 打造英语课堂沸点培养学生学科兴趣%Creating a Boiling Point in English Class and Cultivating Students' Interest in the Subject

    Institute of Scientific and Technical Information of China (English)

    洪曼林

    2015-01-01

    要培养小学生英语兴趣,必须提高小学英语课堂质量,努力打造英语课堂的“沸点”,使学生在沸点中,感受英语魅力,收获学习英语的成果,享受学习英语的快乐。为此教师要置情于境,营造课堂沸点;突破教学重点、难点,形成课堂沸点;抓住师生互动,引爆课堂沸点;让课堂精彩到底,在教学结尾处设置教学沸点。%To cultivate the English interest of primary school stu-dents, the English class quality in primary school must be im-proved to strive to create a boiling point in class so that students are in their boiling point, feeling the charm of English and gain-ing English learning results and enjoying the learning happiness. For this purpose, teachers shall be in the actual atmosphere and create a boiling point in class, breaking through key teaching points and difficulties to form the boiling point, igniting the class-room boiling point in interactions between teachers and students to fully make the class exciting and set a boiling point at the end of teaching.

  5. Below and above boiling point comparison of microwave irradiation and conductive heating for municipal sludge digestion under identical heating/cooling profiles.

    Science.gov (United States)

    Hosseini Koupaie, E; Eskicioglu, C

    2015-01-01

    This research provides a comprehensive comparison between microwave (MW) and conductive heating (CH) sludge pretreatments under identical heating/cooling profiles at below and above boiling point temperatures. Previous comparison studies were constrained to an uncontrolled or a single heating rate due to lack of a CH equipment simulating MW under identical thermal profiles. In this research, a novel custom-built pressure-sealed vessel which could simulate MW pretreatment under identical heating/cooling profiles was used for CH pretreatment. No statistically significant difference was proven between MW and CH pretreatments in terms of sludge solubilization, anaerobic biogas yield and organics biodegradation rate (p-value>0.05), while statistically significant effects of temperature and heating rate were observed (p-valueheating/cooling rates) was controlled.

  6. Oscillate Boiling

    CERN Document Server

    Li, Fenfang; Nguyen, Dang Minh; Ohl, Claus-Dieter

    2016-01-01

    We report about an intriguing boiling regime occurring for small heaters embedded on the boundary in subcooled water. The microheater is realized by focusing a continuous wave laser beam to about $10\\,\\mu$m in diameter onto a 165\\,nm-thick layer of gold, which is submerged in water. After an initial vaporous explosion a single bubble oscillates continuously and repeatably at several $100\\,$kHz. The microbubble's oscillations are accompanied with bubble pinch-off leading to a stream of gaseous bubbles into the subcooled water. The self-driven bubble oscillation is explained with a thermally kicked oscillator caused by the non-spherical collapses and by surface pinning. Additionally, Marangoni stresses induce a recirculating streaming flow which transports cold liquid towards the microheater reducing diffusion of heat along the substrate and therefore stabilizing the phenomenon to many million cycles. We speculate that this oscillate boiling regime may allow to overcome the heat transfer thresholds observed dur...

  7. BOILING REACTORS

    Science.gov (United States)

    Untermyer, S.

    1962-04-10

    A boiling reactor having a reactivity which is reduced by an increase in the volume of vaporized coolant therein is described. In this system unvaporized liquid coolant is extracted from the reactor, heat is extracted therefrom, and it is returned to the reactor as sub-cooled liquid coolant. This reduces a portion of the coolant which includes vaporized coolant within the core assembly thereby enhancing the power output of the assembly and rendering the reactor substantially self-regulating. (AEC)

  8. 脂肪族含氧有机物沸点的定量构效关系%Quantitative structure-property relationship of normal boiling point of aliphatic oxygen-containing organic compounds

    Institute of Scientific and Technical Information of China (English)

    刘万强; 曹晨忠

    2012-01-01

    The descriptors of polarizability effect index (PEI),the number of effective carbon (Nc,e(f)> the differences in PEI and Nc,eff between the branching chain and straight chain isomers,SPEI and δ Nc,eff,are derived from molecular structure. The quantitative structure-property relationships (QSPRs) between these descriptors and boiling points of 520 aliphatic alcohols,ethers,aldehydes,ketones,acids,and esters were obtained separately. The QSPRs between these descriptors and boiling points were developed for 520 aliphatic oxygen-containing organic compounds by best subsets regression method. For the training set,the correlation coefficient R2 is 0. 9946 and the standard deviation GO is 6. 70 K. For the test set,R2 is 0. 9857 and s is 6. 10 K. The average relative error is 1. 19%. According to the regression equation,the influences of the number of effective carbon of alkyl,the role of functional groups and their interaction on the boiling point were analyzed. These results showed a good correlation between the boiling points of organic compounds and these descriptors derived from PEI for aliphatic alcohols,ethers,aldehydes,ketones,acids,and esters.

  9. 烃类及其衍生物闪点、沸点的定量构效关系%QSPR study for predicting flash points and boiling points of hydrocarbon and their derivatives

    Institute of Scientific and Technical Information of China (English)

    杨惠; 陈利平; 谢传欣; 石宁; 陈网桦

    2011-01-01

    The quantitative relationships existed between flash points, boiling points and molecular structures of hydrocarbon and their derivatives were investigated based on the quantitative structure-property relationship ( QSPR) study. 384 molecular descriptors of hydrocarbon and their derivatives were calculated by CODESSA, and these descriptors were pre-selected by best multilinear regression method. Then QSPR models about flash points and boiling points were built. As a result, the five-descriptor linear models were developed to describe the relationship between the molecular structures and the flash points or the boiling points. The non-linear regression models were built based on support vector machine using the five descriptors selected by best multilinear regression method. The compounds were divided into a training set and a test set. The squared correlation coefficient, cross-validation coefficient and mean squared error of each model were calculated. The test set was used to validate the prediction performance of the resulting models. The predicted results indicated that, the prediction results were in good agreement with the experimental values. The models of flash points had robustness, strong generative ability and small prediction error. The predicted results were satisfactory. But the predicted results of boiling points remained to be improved. Compared to the models of hydrocarbons, the performance of the models which added derivatives was decreased. It can be very helpful to expand the applied scope of QSPR study.%基于定量结构-性质相关性( QSPR)原理,研究了烃类及其衍生物闪点、沸点与其分子结构间的内在定量关系.应用CODESSA软件计算384种烃类及其衍生物的分子结构描述符,建立了闪点和沸点的QSPR模型.用最佳多元线性回归(B-MLR)方法筛选得到的分子描述符建立了线性回归模型.用B-MLR方法所选择的5个描述符作为支持向量机(SVM)的输入建立了非线性模型.

  10. 气相色谱法测定苯类的初馏点和干点%Determination of Initial Boiling Point and Dry Point of Benzenes by Gas Chromatography

    Institute of Scientific and Technical Information of China (English)

    陈志运; 李志勇

    2001-01-01

    在工业生产中,用气相色谱法测定纯苯和甲苯产品的初馏点、干点及焦炉煤气中的含苯量,该法与常规方法相比,不仅具有测定速度快、结果准确和操作简单等优点,而且还可做到一柱多用。%In the commercial production,the initial boiling point,dry point of pure benzene and toluene products as well as benzol content in COG are determined with gas chromatography.Compare with the conventional method,the gas chromatography not only has advantages of rapid measurement, accurate measurement and simple operation,but also one column can have more applications.

  11. 估算有机物正常沸点的基团贡献法的研究进展%Research Progress of Group - contribution Methods for Estimating Normal Boiling Point of Organic Compounds

    Institute of Scientific and Technical Information of China (English)

    王小艳; 司继林

    2012-01-01

    Normal boiling points are one of the most important properties for organic compounds. Although there are many experimental values of the normal boiling point of organic compounds in the literature, but there are a few normal boiling point of the material cannot be obtained by experiment. We can obtain the normal boiling points by establishing the mathematical model, the group contribution method is the most important research methods to obtain the normal boiling point. A variety of group - contribution methods for estimating normal boiling point of organic compounds have been summarized. It has discussed the principles, advantages and disadvantages, application ranges of Joback method, C - G method, Xu - Wen method, position group contribution method, elements and bonds. The difference of these methods and the development trend of the methods for estimating normal boiling point of organic compounds was discussed.%有机物的正常沸点是重要的物性数据之一。尽管文献中有很多化合物正常沸点的实验值,但一些物质的正常沸点不能由实验获得,可以通过建立数学模型来估算缺少的有机物正常沸点,其中基团贡献法是人们获得正常沸点的最重要研究方法。本文对估算有机物正常沸点的基团贡献法进行了综述。主要介绍了Joback法、C—G法、许文法、定位分布贡献法、元素和化学键法等方法的原理、优缺点及应用范围;并对这些方法进行简单的比较;最后指出了有机物正常沸点的基团贡献法的发展趋势。

  12. Relation between flash point of a emulsfied fuel and its internal phase ratio

    Energy Technology Data Exchange (ETDEWEB)

    Nakano, Yasuhide; Hirai, Eiji; Kawara, Nobuhiro; Nakagawa, Yoshihiro

    1988-04-15

    Flash points of emulsified fuels (O/W type) were measured changing volume blending ratio of oil (internal phase ratio). As a result the following facts were revealed. (1) The testing method for flash point of petroleum products by tag closed tester regulated by JIS is inadequate for a sample of poor thermal convection such as a creamy emulsified fuel. (2) Emulsified fuel becomes creamy, when its internal phase ratio becomes more than 60 to 70 %, Such a creamy emulsified fuel is possible to catch fire at lower temperature as a whole, for it tends to get high temperature locally by flame approaching etc. This fact is important from a standpoint of safety engineering. (3) Flash point of emulsified fuel does not depend on its internal phase ratio provided that it is measured at uniform temperature, it seems to be constant. And its constant flash point is higher than of the corresponding pure fuel by a little. (8 figs, 5 refs)

  13. Correlation of Boiling Points with Molecular Structure for Halogenated Propanes%卤代丙烷的沸点与分子结构的关联及预测

    Institute of Scientific and Technical Information of China (English)

    王克强; 孙献忠

    2000-01-01

    探讨了卤代丙烷沸点的变化规律,发展了一种直接根据分子结构信息计算和预测卤代丙烷沸点的方法.对53种卤代丙烷的计算结果表明,沸点计算值与实验值的一致性令人满意,平均误差1.18%.本文方法的提出,不仅在一定程度上揭示了卤代丙烷沸点与分子结构之间的定量关系,而且为工程上提供了一种预测卤代丙烷沸点的有效方法.%A correlation was investigated between the boiling points and molecular structure of halogenated propanes,and a method which can be used to calculate and predict the boiling points of halogenated propanes was developed.The results showed that the calculated boiling points are in good agreement with the experimental data,and the mean relative deviation was 1.18% for 53 halogenated propanes.The boiling points of 6 halogenated propanes were predicted for reference and testing in the future.Not only can the method be used to predict haloenated propance,but can help to understand the quantitative relation between boiling point and molecular structure of halogenated propanes as well.

  14. Analysis of Boiling of Water in a Fixed Container Volume--the reason of boiling and the condition without boiling for water in a container with unchangeable volume and the temperature higher than boiling point%关于固定容器中水沸腾的分析——固定容器中的水在温度高于沸点时发生沸腾的原因与不发生沸腾的物理条件

    Institute of Scientific and Technical Information of China (English)

    罗烛红

    2012-01-01

    In real life; the water in a container with fixed volume will boil, as the temperature of water is increased and reaches the boiling point, However, is there a physical conditioin, under which the water in the closed vessel never boils? It is very interesting for teachers and classmates to answer the above question. Motivated by this, in this paper, we do qualitative analysis of the principle on the ebullition of water in the closed vessel and further discuss the physical condition that makes the water still keep liquid state.%从对应态方程出发定性分析在固定体积和升高温度时水沸腾的原因,也探讨了固定体积和温度达到沸点时水不发生沸腾的物理条件.

  15. Boiling water reactors with Uranium-Plutonium mixed oxide fuel. Report 1: Accuracy of the nuclide concentrations calculated by CASMO-4

    Energy Technology Data Exchange (ETDEWEB)

    Demaziere, C. [CEA Centre d' Etudes de Cadarache, Saint-Paul-lez-Durance (France). Direction des Reacteurs Nucleaires

    1999-07-01

    This report is a part of the project titled 'Boiling Water Reactors With Uranium-Plutonium Mixed Oxide (MOx) Fuel'. The aim of this study is to model the impact of a core loading pattern containing MOx bundles upon the main characteristics of a BWR (reactivity coefficients, stability, etc.). The tools that are available to perform a modeling in the Department of Reactor Physics in Chalmers are CASMO-4/TABLES-3/SIMULATE-3 from Studsvik of America. These CMS (Core Management System) programs have been extensively compared with both measurements and reference codes. Nevertheless some data are proprietary in particular the comparison of the calculated nuclide concentrations versus experiments (because of the cost of this kind of experimental study). This is why this report describes such a comparative investigation carried out with a General Electric 7x7 BWR bundle. Unfortunately, since some core history parameters were unknown, a lot of hypotheses have been adopted. This invokes sometimes a significant discrepancy in the results without being able to determine the origin of the differences between calculations and experiments. Yet one can assess that, except for four nuclides - Plutonium-238, Curium-243, Curium-244 and Cesium-135 - for which the approximate power history (history effect) can be invoked, the accuracy of the calculated nuclide concentrations is rather good if one takes the numerous approximations into account.

  16. Boiling of the interface between two immiscible liquids below the bulk boiling temperatures of both components.

    Science.gov (United States)

    Pimenova, Anastasiya V; Goldobin, Denis S

    2014-11-01

    We consider the problem of boiling of the direct contact of two immiscible liquids. An intense vapour formation at such a direct contact is possible below the bulk boiling points of both components, meaning an effective decrease of the boiling temperature of the system. Although the phenomenon is known in science and widely employed in technology, the direct contact boiling process was thoroughly studied (both experimentally and theoretically) only for the case where one of liquids is becoming heated above its bulk boiling point. On the contrary, we address the case where both liquids remain below their bulk boiling points. In this paper we construct the theoretical description of the boiling process and discuss the actualisation of the case we consider for real systems.

  17. Assessing the microbiological performance and potential cost of boiling drinking water in urban Zambia.

    Science.gov (United States)

    Psutka, Rebecca; Peletz, Rachel; Michelo, Sandford; Kelly, Paul; Clasen, Thomas

    2011-07-15

    Boiling is the most common method of disinfecting water in the home and the benchmark against which other point-of-use water treatment is measured. In a six-week study in peri-urban Zambia, we assessed the microbiological effectiveness and potential cost of boiling among 49 households without a water connection who reported "always" or "almost always" boiling their water before drinking it. Source and household drinking water samples were compared weekly for thermotolerant coliforms (TTC), an indicator of fecal contamination. Demographics, costs, and other information were collected through surveys and structured observations. Drinking water samples taken at the household (geometric mean 7.2 TTC/100 mL, 95% CI, 5.4-9.7) were actually worse in microbiological quality than source water (geometric mean 4.0 TTC/100 mL, 95% CI, 3.1-5.1) (p boiled at the time of collection from the home, suggesting over-reporting and inconsistent compliance. However, these samples were of no higher microbiological quality. Evidence suggests that water quality deteriorated after boiling due to lack of residual protection and unsafe storage and handling. The potential cost of fuel or electricity for boiling was estimated at 5% and 7% of income, respectively. In this setting where microbiological water quality was relatively good at the source, safe-storage practices that minimize recontamination may be more effective in managing the risk of disease from drinking water at a fraction of the cost of boiling.

  18. A review of film boiling at cryogenic temperatures.

    Science.gov (United States)

    Hsu, Y. Y.

    1972-01-01

    Film boiling occurs in the quenching of metals, the chilling of biological species, the regenerative cooling of rockets, and the cooling down of a cryogenic fuel tank. Occasionally film boiling is also found in a nuclear reactor or in a cryomagnet. Aspects of film boiling involving an unconstrained liquid mass are considered, giving attention to the evaporation time, the Leidenfrost temperature, solid-liquid contacts, the thermal properties of the solid, effects of coating or scale, wettability, the metastable condition, and the velocity effect on drops. Developments discussed with regard to pool boiling are related to vertical surfaces, film boiling from horizontal surfaces, film boiling from a horizontal cylinder, film boiling from a sphere, and film boiling of helium. Processes of film boiling in a channel are also analyzed.

  19. Contrast-enhanced ultrasound imaging and in vivo circulatory kinetics with low-boiling-point nanoscale phase-change perfluorocarbon agents.

    Science.gov (United States)

    Sheeran, Paul S; Rojas, Juan D; Puett, Connor; Hjelmquist, Jordan; Arena, Christopher B; Dayton, Paul A

    2015-03-01

    Many studies have explored phase-change contrast agents (PCCAs) that can be vaporized by an ultrasonic pulse to form microbubbles for ultrasound imaging and therapy. However, few investigations have been published on the utility and characteristics of PCCAs as contrast agents in vivo. In this study, we examine the properties of low-boiling-point nanoscale PCCAs evaluated in vivo and compare data with those for conventional microbubbles with respect to contrast generation and circulation properties. To do this, we develop a custom pulse sequence to vaporize and image PCCAs using the Verasonics research platform and a clinical array transducer. Results indicate that droplets can produce contrast enhancement similar to that of microbubbles (7.29 to 18.24 dB over baseline, depending on formulation) and can be designed to circulate for as much as 3.3 times longer than microbubbles. This study also reports for the first time the ability to capture contrast washout kinetics of the target organ as a measure of vascular perfusion.

  20. PREDICTING THE BOILING POINT OF PCDD/Fs BY THE QSPR METHOD BASED ON THE MOLECULAR DISTANCE-EDGE VECTOR INDEX

    Directory of Open Access Journals (Sweden)

    Long Jiao

    2015-05-01

    Full Text Available The quantitative structure property relationship (QSPR for the boiling point (Tb of polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDD/Fs was investigated. The molecular distance-edge vector (MDEV index was used as the structural descriptor. The quantitative relationship between the MDEV index and Tb was modeled by using multivariate linear regression (MLR and artificial neural network (ANN, respectively. Leave-one-out cross validation and external validation were carried out to assess the prediction performance of the models developed. For the MLR method, the prediction root mean square relative error (RMSRE of leave-one-out cross validation and external validation was 1.77 and 1.23, respectively. For the ANN method, the prediction RMSRE of leave-one-out cross validation and external validation was 1.65 and 1.16, respectively. A quantitative relationship between the MDEV index and Tb of PCDD/Fs was demonstrated. Both MLR and ANN are practicable for modeling this relationship. The MLR model and ANN model developed can be used to predict the Tb of PCDD/Fs. Thus, the Tb of each PCDD/F was predicted by the developed models.

  1. Generation of standard gas mixtures of halogenated, aliphatic, and aromatic compounds and prediction of the individual output rates based on molecular formula and boiling point.

    Science.gov (United States)

    Thorenz, Ute R; Kundel, Michael; Müller, Lars; Hoffmann, Thorsten

    2012-11-01

    In this work, we describe a simple diffusion capillary device for the generation of various organic test gases. Using a set of basic equations the output rate of the test gas devices can easily be predicted only based on the molecular formula and the boiling point of the compounds of interest. Since these parameters are easily accessible for a large number of potential analytes, even for those compounds which are typically not listed in physico-chemical handbooks or internet databases, the adjustment of the test gas source to the concentration range required for the individual analytical application is straightforward. The agreement of the predicted and measured values is shown to be valid for different groups of chemicals, such as halocarbons, alkanes, alkenes, and aromatic compounds and for different dimensions of the diffusion capillaries. The limits of the predictability of the output rates are explored and observed to result in an underprediction of the output rates when very thin capillaries are used. It is demonstrated that pressure variations are responsible for the observed deviation of the output rates. To overcome the influence of pressure variations and at the same time to establish a suitable test gas source for highly volatile compounds, also the usability of permeation sources is explored, for example for the generation of molecular bromine test gases.

  2. THE RESULTS OF THE STUDY BOILING POINT OUT OZONE-SAFE REFRIGERANT R410A IN THE EVAPORATORS OF REFRIGERATING MACHINES

    Directory of Open Access Journals (Sweden)

    V. G. Bukin

    2012-01-01

    Full Text Available The results of experimental research boiling heat transfer of ozone-friendly R410A refrigerant in evaporators machines and the possibility of its use in place of the prohibited refrigerant R22.

  3. 过冷沸腾起始点和净蒸汽产生点的实验研究%EXPERIMENTAL STUDY ON ONSET OF SUBCOOLED BOILING AND POINT OF NET VAPOR GENERATION

    Institute of Scientific and Technical Information of China (English)

    杨瑞昌; 王彦武; 唐虹; 司徒荣

    2001-01-01

    This paper reports the experimental study of onset of subcooled boiling and point of net vapor generation in a natural circulation system with subcooled boiling. Freon-12 was used as the working medium. In the experiments the onset of subcooled boiling and the point of net vapor generation were determined byvisual observation. The influence of the system pressure, inlet subcooling of the working medium and the input power to the heated section on the onset of subcooled boiling and the point of net vapor generation were investigated in the experiments. Based on the data reduction, the calculation methods of the onset of subcooled boiling and the net vapor generation in the natural circulation system have been presented respectively.%本文报告了使用R-12作工质进行的自然循环过冷沸腾起始点和净蒸汽产生点的实验结果。实验过程中使用可视化方法观察确定过冷沸腾起始点和净蒸汽产生点. 在相当宽广的工质压力、入口过冷度及加热功率范围内研究了上述参数对过冷沸腾起始点和净蒸汽产生点的影响, 在此基础上提出了计算自然循环过冷沸腾起始点和净蒸汽产生点的计算方法。

  4. A Tentative Study on the Relationship Among External Pressure, Vapor Tension and Boiling Point%外压与沸点和蒸气压的关系浅论

    Institute of Scientific and Technical Information of China (English)

    李俊华; 陈彩虹; 屈景年; 曾荣英

    2009-01-01

    The relationship among external pressure, vapor tension and boiling point is discussed in single-component system and two-component system by thermodynamic formulas and phase diagrams. The relationship amongexternal pressure, vapor tension and boiling point is ascertained under different conditions. Meanwhile this relationships is also discussed ulteriorly from microcosmic points.%运用热力学基本公式和相图对单组分系统和二组分系统中外压与沸点和蒸气压之间的关系进行了讨论,明确了不同条件下三者之间的关系,同时从微观角度进行了进一步分析.

  5. 二甲基氯硅烷生产高沸物的综合利用研究进展%Progress in Application of Methyl Chlorosilane High-Boiling Point Residue

    Institute of Scientific and Technical Information of China (English)

    高风; 李永刚; 汪民康; 张文超; 周魁; 林萌; 黄世强

    2012-01-01

    The progress of comprehensive utilization of high-boiling point residue resulting from the production of methylchlorosilane by direct method within China and abroad was reviewed. The advantages and disadvantages of the methods were also summarized, and the directions for utilization of the high-boiling point residue were pointed.%介绍了国内外应用直接法生产甲基氯硅烷过程中产生的高沸物的综合利用研究进展,总结对比了各种方法的优势和不足,展望了高沸物综合利用前景并指出其发展方向.

  6. Development of a mechanistic model for forced convection subcooled boiling

    Science.gov (United States)

    Shaver, Dillon R.

    The focus of this work is on the formulation, implementation, and testing of a mechanistic model of subcooled boiling. Subcooled boiling is the process of vapor generation on a heated wall when the bulk liquid temperature is still below saturation. This is part of a larger effort by the US DoE's CASL project to apply advanced computational tools to the simulation of light water reactors. To support this effort, the formulation of the dispersed field model is described and a complete model of interfacial forces is formulated. The model has been implemented in the NPHASE-CMFD computer code with a K-epsilon model of turbulence. The interfacial force models are built on extensive work by other authors, and include novel formulations of the turbulent dispersion and lift forces. The complete model of interfacial forces is compared to experiments for adiabatic bubbly flows, including both steady-state and unsteady conditions. The same model is then applied to a transient gas/liquid flow in a complex geometry of fuel channels in a sodium fast reactor. Building on the foundation of the interfacial force model, a mechanistic model of forced-convection subcooled boiling is proposed. This model uses the heat flux partitioning concept and accounts for condensation of bubbles attached to the wall. This allows the model to capture the enhanced heat transfer associated with boiling before the point of net generation of vapor, a phenomenon consistent with existing experimental observations. The model is compared to four different experiments encompassing flows of light water, heavy water, and R12 at different pressures, in cylindrical channels, an internally heated annulus, and a rectangular channel. The experimental data includes axial and radial profiles of both liquid temperature and vapor volume fraction, and the agreement can be considered quite good. The complete model is then applied to simulations of subcooled boiling in nuclear reactor subchannels consistent with the

  7. Multidisciplinary Simulation of Graphite-Composite and Cermet Fuel Elements for NTP Point of Departure Designs

    Science.gov (United States)

    Stewart, Mark E.; Schnitzler, Bruce G.

    2015-01-01

    This paper compares the expected performance of two Nuclear Thermal Propulsion fuel types. High fidelity, fluid/thermal/structural + neutronic simulations help predict the performance of graphite-composite and cermet fuel types from point of departure engine designs from the Nuclear Thermal Propulsion project. Materials and nuclear reactivity issues are reviewed for each fuel type. Thermal/structural simulations predict thermal stresses in the fuel and thermal expansion mis-match stresses in the coatings. Fluid/thermal/structural/neutronic simulations provide predictions for full fuel elements. Although NTP engines will utilize many existing chemical engine components and technologies, nuclear fuel elements are a less developed engine component and introduce design uncertainty. Consequently, these fuel element simulations provide important insights into NTP engine performance.

  8. Application of Topology Index in Aliphatic Aldehydes,Fatty Amines and Aliphatic Hydrocarbons Boiling Point%拓扑指数在脂肪醛、脂肪胺及脂肪烃沸点中的应用

    Institute of Scientific and Technical Information of China (English)

    周长会; 吴启勋; 侯庆高; 高宴梓; 李洪囡; 张瑞

    2013-01-01

    Two matrices and a topological index W were defined,then,topological index W was put into nonlinear regression with the boiling point of aliphatic aldehydes, fatty amines and aliphatic hydrocarbons, respectively, and with good results,the correlation coefficient reaches a good level. The established topological index and two kinds of matrix are easy and convenient to use, which can quickly predict the boiling point of the molecule.%定义了两种矩阵和一种拓扑指数W,将拓扑指数W分别与脂肪醛、脂肪胺及脂肪烃的沸点进行非线性回归,取得了较好的结果,相关性系数达到了良好级别.建立的拓扑指数和两种矩阵简洁方便,可以快速预测分子的沸点.

  9. Molecular polarizability effect index and boiling point of aliphatic aldehydes and alkanones%分子极化效应指数与脂肪族醛酮的沸点

    Institute of Scientific and Technical Information of China (English)

    张秀利; 汪勇先; 林英武; 李俊玲

    2003-01-01

    Based on the molecular polarizabihty effect index,a formula of three parameters was proposed to calculate the boiling point of aliphatic aldehydes and alkanones. ln(820.5 - Tb) = 6.38330- 1.37357 × 10-1 Nc + 5.39350ΔEPI + 8.02603 × 10-2N Where the Nc is the effective length of carbon chain of alkyl group in the aliphatic aldehydes and alkanones. The ΔPEI is the polarizability effect index difference between the corresponding branched and normal alkyl isomer containing the same carbon atom number, which expressed the effcet of carbonyl group on the boiling point of aliphatic aldehydes and alkanones. N is the carbon numbers of aliphatic aldehydes and alkanones.

  10. 低沸点化学物质在无源轿车轮胎温度传感器中的应用%Application of Low-boiling Point Chemicals in Car Tire's Passive Temperature Sensor

    Institute of Scientific and Technical Information of China (English)

    张健伟; 赫广田; 董群; 王鉴; 胡林杰

    2012-01-01

    利用低沸点化学物质具有较高的饱和蒸汽压的特性,设计了一种无源轿车轮胎温度监测系统.系统中的温度传感器是将温度变化通过低沸点化学物质的饱和蒸汽压信号转变为磁铁的位移信号,再利用线性霍尔传感器检测位移信号,实现对轮胎内温度的实时监测.低沸点化学物质是温度传感器的核心之一,结合轮胎温度报警的实际条件,通过考察不同低沸点物质的饱和蒸汽压随温度和压力的变化规律,并考虑化学物质使用的安全性,最终确定了该温度传感器中所适用的感温物质.%Considering the fact that low-boiling point chemical substance has higher saturated steam pressure, a car tire' s temperature monitoring system was designed to have tire' s temperature change translated to the magnet displacement signals through saturated steam pressure change of low-boiling point chemical substance in temperature sensor, and then to have the displacement signals detected with liner Hall element and the tire temperature monitored in real time. The low-boiling point chemical substance means important to the temperature sensor, having the rules that saturated steam pressure of different low-boiling point chemicals varies with temperature and pressure studied, and the conditions of tire temperature alarm and chemical substance security considered, the best temperature sensitive substance for passive temperature sensor was determined.

  11. Diesel and Jet Fuels from Bitumen-derived Middle Distillates

    Institute of Scientific and Technical Information of China (English)

    SokYui

    2004-01-01

    Narrow fractions of light gas oils obtained from various upgrading processes of Athabasca oilsands bitumen were investigated as diesel and jet fuels. The relationship among the boiling range, cetane number, smoke point, and other properties such as aromatics content, aniline point, and the sulfur and nitrogen content was also studied. The study reveals that when appropriate processes and distillation boiling ranges are selected, oilsands bitumen can produce diesel and jet fuels that meet stringent environmental regulations and future product specifications. New correlations to predict CN and smoke point were developed as a function of density, boiling ranges by simulated distillation, and mono- and total aromatics by supercriticaL fluid chromatography. The correlations apply to bitumen-derived middle distiLLates that have a wide range of boiling points.

  12. Duality of boiling systems and uncertainty phenomena

    Institute of Scientific and Technical Information of China (English)

    柴立合; 彭晓峰; 王补宣

    2000-01-01

    Interactions among dry patches at high heat flux are theoretically analyzed. The high heat flux boiling experiments on metal plate wall with different materials and thickness are correspondingly conducted. The duality of boiling system, i.e. hydrodynamic performance and self-organized performance is identified. A unified explanation of hydrodynamic models and dry patches models is given. The scatter and uncertainty in boiling data can be mainly attributed to the intrinsic duality, but not the sole surface effects. The present experimental results explain why the deviation point at high flux boiling is seen only on occasion and why the self-organization of dry patches is often ignored in available literature.

  13. Fischer-Tropsch Synthetic Fuel Evaluations HMMWV Test Track Evaluation

    Science.gov (United States)

    2009-09-01

    FBP Final boiling point FTM Federal Test Method FTP Federal Test Procedure g/kw-h Grams per kilowatt-hour g/mi Grams per...frequency reciprocating rig Hr Hour HMMWV High Mobility Medium Wheeled Vehicle IBP Initial boiling point Kg Kilo-gram L Liter Lbs...Standard deviation SwRI Southwest Research Institute TFLRF U.S. Army TARDEC Fuels and Lubricants Research Facility THC Total hydrocarbons

  14. QSPR Calculation of Normal Boiling Points of Organic Molecules Based on the Use of Correlation Weighting of Atomic Orbitals with Extended Connectivity of Zero- and First-Order Graphs of Atomic Orbitals

    Directory of Open Access Journals (Sweden)

    Eduardo A. Castro

    2004-12-01

    Full Text Available We report the results of a calculation of the normal boiling points of a representative set of 200 organic molecules through the application of QSPR theory. For this purpose we have used a particular set of flexible molecular descriptors, the so called Correlation Weighting of Atomic Orbitals with Extended Connectivity of Zero- and First-Order Graphs of Atomic Orbitals. Although in general the results show suitable behavior to predict this physical chemistry property, the existence of some deviant behaviors points to a need to complement this index with some other sort of molecular descriptors. Some possible extensions of this study are discussed.

  15. FOOD VS. FUEL – A TURNING POINT FOR BIOETHANOL?

    Directory of Open Access Journals (Sweden)

    Katharina Harlander

    2008-09-01

    Full Text Available Recently concerns have been raised that biofuels would affect food prices. Bioethanol is made from sugar or starch containing plants that are also used in food production. In public perception this led to an emotional resistance against biofuels that in real terms is not substantiated. Generally, biofuels are a political product. Triggered by the oil crisis in the early 1970ies national fuel ethanol programmes were first launched in Brazil and in the United States. Concerns regarding energy security and sustainability together with the option of new markets for surplus agricultural production in recent years led to similar policy measures in the European Union and in numerous countries around the globe. Accordingly the industry invested heavily in new bioethanol plants - especially in the US – and created an additional demand for corn and wheat with some record-breaking prices noted in late 2007. A look back into statistics shows a drastic decline of real prices for decades and by now they are only back at the level of 30 years ago. One important detail is the real portion of grain used for bioethanol, which is still only 1.6 percent in the EU and therefore unlikely to be the real driver for the price development. Moreover the share of raw material is up to 70% of bioethanol production cost that makes the bioethanol industry itself a victim of price increases. Subsequently investor interest in this field slowed down, a development also watched in the US. The prospects of the agricultural markets of the European Commission conclude that Europe can do both, nutrition and biofuels.

  16. Four-point Bend Testing of Irradiated Monolithic U-10Mo Fuel

    Energy Technology Data Exchange (ETDEWEB)

    Rabin, B. H. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Lloyd, W. R. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Schulthess, J. L. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Wright, J. K. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Lind, R. P. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Scott, L. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Wachs, K. M. [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2015-03-01

    This paper presents results of recently completed studies aimed at characterizing the mechanical properties of irradiated U-10Mo fuel in support of monolithic base fuel qualification. Mechanical properties were evaluated in four-point bending. Specimens were taken from fuel plates irradiated in the RERTR-12 and AFIP-6 Mk. II irradiation campaigns, and tests were conducted in the Hot Fuel Examination Facility (HFEF) at Idaho National Laboratory (INL). The monolithic fuel plates consist of a U-10Mo fuel meat covered with a Zr diffusion barrier layer fabricated by co-rolling, clad in 6061 Al using a hot isostatic press (HIP) bonding process. Specimens exhibited nominal (fresh) fuel meat thickness ranging from 0.25 mm to 0.64 mm, and fuel plate average burnup ranged from approximately 0.4 x 1021 fissions/cm3 to 6.0 x 1021 fissions/cm3. After sectioning the fuel plates, the 6061 Al cladding was removed by dissolution in concentrated NaOH. Pre- and post-dissolution dimensional inspections were conducted on test specimens to facilitate accurate analysis of bend test results. Four-point bend testing was conducted on the HFEF Remote Load Frame at a crosshead speed of 0.1 mm/min using custom-designed test fixtures and calibrated load cells. All specimens exhibited substantially linear elastic behavior and failed in a brittle manner. The influence of burnup on the observed slope of the stress-strain curve and the calculated fracture strength is discussed.

  17. Evaluation of methods for rapid determination of freezing point of aviation fuels

    Science.gov (United States)

    Mathiprakasam, B.

    1982-01-01

    Methods for identification of the more promising concepts for the development of a portable instrument to rapidly determine the freezing point of aviation fuels are described. The evaluation process consisted of: (1) collection of information on techniques previously used for the determination of the freezing point, (2) screening and selection of these techniques for further evaluation of their suitability in a portable unit for rapid measurement, and (3) an extensive experimental evaluation of the selected techniques and a final selection of the most promising technique. Test apparatuses employing differential thermal analysis and the change in optical transparency during phase change were evaluated and tested. A technique similar to differential thermal analysis using no reference fuel was investigated. In this method, the freezing point was obtained by digitizing the data and locating the point of inflection. Results obtained using this technique compare well with those obtained elsewhere using different techniques. A conceptual design of a portable instrument incorporating this technique is presented.

  18. Microbiological Effectiveness of Disinfecting Water by Boiling in Rural Guatemala

    Science.gov (United States)

    Rosa, Ghislaine; Miller, Laura; Clasen, Thomas

    2010-01-01

    Boiling is the most common means of treating water in the home and the benchmark against which alternative point-of-use water treatment options must be compared. In a 5-week study in rural Guatemala among 45 households who claimed they always or almost always boiled their drinking water, boiling was associated with a 86.2% reduction in geometric mean thermotolerant coliforms (TTC) (N = 206, P boiling significantly improved the microbiological quality of drinking water, though boiled and stored drinking water is not always free of fecal contaminations. PMID:20207876

  19. Woody Biomass Conversion to JP-8 Fuels

    Science.gov (United States)

    2014-02-15

    the downstream hydrotreating required to produce a drop-in transportation fuel. Furthermore, this process does not use a catalyst, making it tolerant...Approximately 40% of the hydrotreated TDO oil mass is in the JP-8 (180-250C), and 60% is in the F-76 (150-325C) boiling point range, respectively

  20. 利用DISLab传感器探究水的沸点与大气压强的关系%Exploring on the relation between boiling point of water and atmospheric pressure using DISLab

    Institute of Scientific and Technical Information of China (English)

    陈剑峰

    2016-01-01

    针对“密闭气体压强与温度间的关系”实验的不足,将DISLab 应用到实验中,通过 DISLab 的压强传感器和温度传感器可以直接精确地读出密闭气体的压强和温度,直观地显示出“压强减少、水的沸点降低”及“压强升高、水的沸点升高”的规律。%Aiming at the deficiency of the experiment of the relation between pressure and temper-ature of sealed gas,a method using DISLab was put forward.By using pressure sensor and tempera-ture sensor,the pressure and temperature could be read directly.It was showed that the lower the pressure,the lower the boiling point of water and the higher the pressure,the higher the boiling point of water.

  1. Analysis of the magnetic corrosion product deposits on a boiling water reactor cladding

    Energy Technology Data Exchange (ETDEWEB)

    Orlov, Andrey [Paul Scherrer Institut, Villigen (Switzerland); Degueldre, Claude, E-mail: claude.degueldre@psi.ch [Paul Scherrer Institut, Villigen (Switzerland); Kaufmann, Wilfried [Kernkraftwerk Leibstadt, Leibstadt (Switzerland)

    2013-01-15

    The buildup of corrosion product deposits (CRUD) on the fuel cladding of the boiling water reactor (BWR) before and after zinc injection has been investigated by applying local experimental analytical techniques. Under the BWR water chemistry conditions, Zn addition together with the presence of Ni and Mn induce the formation of (Zn,Ni,Mn)[Fe{sub 2}O{sub 4}] spinel solid solutions. X-ray absorption spectroscopy (XAS) revealed inversion ratios of cation distribution in spinels deposited from the solid solution. Based on this information, a two-site ferrite spinel solid solution model is proposed. Electron probe microanalysis (EPMA) and extended X-ray absorption fine structure (EXAFS) findings suggest the zinc-rich ferrite spinels formation on BWR fuel cladding mainly at lower pin. - Graphical Abstract: Analysis of spinels in corrosion product deposits on boiling water reactor fuel rod. Combining EPMA and XAFS results: schematic representation of the ferrite spinels in terms of the end members and their extent of inversion. Note that the ferrites are represented as a surface between the normal (upper plane, M[Fe{sub 2}]O{sub 4}) and the inverse (lower plane, Fe[MFe]O{sub 4}). Actual compositions red Black-Small-Square for the specimen at low elevation (810 mm), blue Black-Small-Square for the specimen at mid elevation (1800 mm). The results have an impact on the properties of the CRUD material. Highlights: Black-Right-Pointing-Pointer Buildup of corrosion product deposits on fuel claddings of a boiling water reactor (BWR) are investigated. Black-Right-Pointing-Pointer Under BWR water conditions, Zn addition with Ni and Mn induced formation of (Zn,Ni,Mn)[Fe{sub 2}O{sub 4}]. Black-Right-Pointing-Pointer X-Ray Adsorption Spectroscopy (XAS) revealed inversion of cations in spinel solid solutions. Black-Right-Pointing-Pointer Zinc-rich ferrite spinels are formed on BWR fuel cladding mainly at lower pin elevations.

  2. Water boiling inside carbon nanotubes: toward efficient drug release.

    Science.gov (United States)

    Chaban, Vitaly V; Prezhdo, Oleg V

    2011-07-26

    We show using molecular dynamics simulation that spatial confinement of water inside carbon nanotubes (CNTs) substantially increases its boiling temperature and that a small temperature growth above the boiling point dramatically raises the inside pressure. Capillary theory successfully predicts the boiling point elevation down to 2 nm, below which large deviations between the theory and atomistic simulation take place. Water behaves qualitatively different inside narrow CNTs, exhibiting transition into an unusual phase, where pressure is gas-like and grows linearly with temperature, while the diffusion constant is temperature-independent. Precise control over boiling by CNT diameter, together with the rapid growth of inside pressure above the boiling point, suggests a novel drug delivery protocol. Polar drug molecules are packaged inside CNTs; the latter are delivered into living tissues and heated by laser. Solvent boiling facilitates drug release.

  3. Evaporation, Boiling and Bubbles

    Science.gov (United States)

    Goodwin, Alan

    2012-01-01

    Evaporation and boiling are both terms applied to the change of a liquid to the vapour/gaseous state. This article argues that it is the formation of bubbles of vapour within the liquid that most clearly differentiates boiling from evaporation although only a minority of chemistry textbooks seems to mention bubble formation in this context. The…

  4. Evaporation, Boiling and Bubbles

    Science.gov (United States)

    Goodwin, Alan

    2012-01-01

    Evaporation and boiling are both terms applied to the change of a liquid to the vapour/gaseous state. This article argues that it is the formation of bubbles of vapour within the liquid that most clearly differentiates boiling from evaporation although only a minority of chemistry textbooks seems to mention bubble formation in this context. The…

  5. Classification of jet fuel properties by near-infrared spectroscopy using fuzzy rule-building expert systems and support vector machines.

    Science.gov (United States)

    Xu, Zhanfeng; Bunker, Christopher E; Harrington, Peter de B

    2010-11-01

    Monitoring the changes of jet fuel physical properties is important because fuel used in high-performance aircraft must meet rigorous specifications. Near-infrared (NIR) spectroscopy is a fast method to characterize fuels. Because of the complexity of NIR spectral data, chemometric techniques are used to extract relevant information from spectral data to accurately classify physical properties of complex fuel samples. In this work, discrimination of fuel types and classification of flash point, freezing point, boiling point (10%, v/v), boiling point (50%, v/v), and boiling point (90%, v/v) of jet fuels (JP-5, JP-8, Jet A, and Jet A1) were investigated. Each physical property was divided into three classes, low, medium, and high ranges, using two evaluations with different class boundary definitions. The class boundaries function as the threshold to alarm when the fuel properties change. Optimal partial least squares discriminant analysis (oPLS-DA), fuzzy rule-building expert system (FuRES), and support vector machines (SVM) were used to build the calibration models between the NIR spectra and classes of physical property of jet fuels. OPLS-DA, FuRES, and SVM were compared with respect to prediction accuracy. The validation of the calibration model was conducted by applying bootstrap Latin partition (BLP), which gives a measure of precision. Prediction accuracy of 97 ± 2% of the flash point, 94 ± 2% of freezing point, 99 ± 1% of the boiling point (10%, v/v), 98 ± 2% of the boiling point (50%, v/v), and 96 ± 1% of the boiling point (90%, v/v) were obtained by FuRES in one boundaries definition. Both FuRES and SVM obtained statistically better prediction accuracy over those obtained by oPLS-DA. The results indicate that combined with chemometric classifiers NIR spectroscopy could be a fast method to monitor the changes of jet fuel physical properties.

  6. Investigation of bubble-point vapor pressures for mixtures of an endothermic hydrocarbon fuel with ethanol

    Energy Technology Data Exchange (ETDEWEB)

    Haiyun Sun; Wenjun Fang; Yongsheng Guo; Ruisen Lin [Zhejiang University, Hangzhou (China). Department of Chemistry, Molecular Thermodynamics

    2005-05-01

    Bubble-point vapor pressures and equilibrium temperatures for several mixtures with different mass fractions of a kerosene based endothermic hydrocarbon fuel (EHF) and ethanol were measured by comparative ebulliometry with inclined ebulliometers. Correlation between vapor pressures and equilibrium temperatures by the Antoine equation was given with satisfactory precision. The bubble-point lines of pressure versus composition at different temperatures and temperature versus composition at different pressures were obtained. The pseudo binary systems of EHF+ethanol appear with very large positive deviations from Raoult's law. It follows that the addition of ethanol had a critical effect on the vapor pressure of fuels. Ethanol may be an effective oxygenated hydrocarbon additive to adjust the volatility of EHF. 17 refs., 8 figs., 4 tabs.

  7. 定位分布贡献方法估算有机物正常沸点%Position group contribution method for predicting the normal boiling point of organic compounds

    Institute of Scientific and Technical Information of China (English)

    王强; 马沛生; 王昶; 夏淑倩

    2009-01-01

    A new position group contribution model iS proposed for the estimation of normal boiling data of organic compounds involving a carbon chain from C2 to C18. The characteristic of this method iS the use of position distribution function.It could distinguish most of isomers that include cis-or trans-structure from organic compounds.Contributions for hydrocarbons and hydrocarbon derivatives containing oxygen,nitrogen,chlorine,bromine and sulfur,are given.Compared with the predictions,results made use of the most common existing group contribution methods,the overall average absolute difference of boiling point predictions of 417 organic compounds is 4.2 K:and the average absolute percent derivation is 1.0%,which iS compared with 1 2-3 K and 3.2%with the method of Joback.12.1 K and 3.1%with the method of Constantinou-Gani.This new position contribution groups mcthod is not only much more accurate but also has the advantages of simplicity and stability.

  8. Microlayer during boiling in narrow slot channels

    Science.gov (United States)

    Diev, Mikhail D.; Leontiev, Alexander I.

    1997-01-01

    An international space station Alpha will have a two-phase thermal control system. Boiling of a liquid ammonia will be a process of heat collection in evaporative heat exchangers. Unfortunately, only little data is available for boiling heat transfer in microgravity. Geometries of boiling channels working good in normal gravity are not appropriate in microgravity, and special means should be worked out to avoid some undesired events. From this point of view, the narrow slot channels may be assumed as a promising geometry for microgravity operation. During boiling in narrow slots, the vapor bubbles are flattened between the channel walls. The vapor phase and the channel wall are separated by a thin liquid film which is known as a microlayer. The paper presents the experimental results compared to the theoretical analysis, the paper also shows the narrow slot channels as a perspective configuration for microgravity applications.

  9. High flux film and transition boiling

    Science.gov (United States)

    Witte, L. C.

    1993-02-01

    An investigation was conducted on the potential for altering the boiling curve through effects of high velocity and high subcooling. Experiments using water and Freon-113 flowing over cylindrical electrical heaters in crossflow were made to see how velocity and subcooling affect the boiling curve, especially the film and transition boiling regions. We sought subcooling levels down to near the freezing points of these two liquids to prove the concept that the critical heat flux and the minimum heat flux could be brought together, thereby averting the transition region altogether. Another emphasis was to gain insight into how the various boiling regions could be represented mathematically on various parts of the heating surface. Motivation for the research grew out of a realization that the effects of very high subcooling and velocity might be to avert the transition boiling altogether so that the unstable part of the boiling curve would not limit the application of high flux devices to temperatures less than the burnout temperatures. Summaries of results from the study are described. It shows that the potential for averting the transition region is good and points the way to further research that is needed to demonstrate the potential.

  10. Extension Sliding Mode Controller for Maximum Power Point Tracking of Hydrogen Fuel Cells

    Directory of Open Access Journals (Sweden)

    Meng-Hui Wang

    2013-01-01

    Full Text Available Fuel cells (FCs are characterized by low pollution, low noise, and high efficiency. However, the voltage-current response of an FC is nonlinear, with the result that there exists just one operating point which maximizes the output power given a particular set of operating conditions. Accordingly, the present study proposes a maximum power point tracking (MPPT control scheme based on extension theory to stabilize the output of an FC at the point of maximum power. The simulation results confirm the ability of the controller to stabilize the output power at the maximum power point despite sudden changes in the temperature, hydrogen pressure, and membrane water content. Moreover, the transient response time of the proposed controller is shown to be faster than that of existing sliding mode (SM and extremum seeking (ES controllers.

  11. Aspects of subcooled boiling

    Energy Technology Data Exchange (ETDEWEB)

    Bankoff, S.G. [Northwestern Univ., Evanston, IL (United States)

    1997-12-31

    Subcooled boiling boiling refers to boiling from a solid surface where the bulk liquid temperature is below the saturation temperature (subcooled). Two classes are considered: (1) nucleate boiling, where, for large subcoolings, individual bubbles grow and collapse while remaining attached to the solid wall, and (2) film boiling, where a continuous vapor film separates the solid from the bulk liquid. One mechanism by which subcooled nucleate boiling results in very large surface heat transfer coefficient is thought to be latent heat transport within the bubble, resulting from simultaneous evaporation from a thin residual liquid layer at the bubble base, and condensation at the polar bubble cap. Another is the increased liquid microconvection around the oscillating bubble. Two related problems have been attacked. One is the rupture of a thin liquid film subject to attractive and repulsive dispersion forces, leading to the formation of mesoscopic drops, which then coalesce and evaporate. Another is the liquid motion in the vicinity of an oscillating contact line, where the bubble wall is idealized as a wedge of constant angle sliding on the solid wall. The subcooled film boiling problem has been attacked by deriving a general long-range nonlinear evolution equation for the local thickness of the vapor layer. Linear and weakly-nonlinear stability results have been obtained. A number of other related problems have been attacked.

  12. Single-use paper-based hydrogen fuel cells for point-of-care diagnostic applications

    Science.gov (United States)

    Esquivel, J. P.; Buser, J. R.; Lim, C. W.; Domínguez, C.; Rojas, S.; Yager, P.; Sabaté, N.

    2017-02-01

    This work demonstrates a stand-alone power source that integrates a paper-based hydrogen fuel cell with a customized chemical heater that produces hydrogen in-situ upon the addition of a liquid. The presented approach operates by capillary action and takes advantage of the hydrogen released as a by-product of an exothermic reaction used in point-of-care diagnostics. The paper-based fuel cell produces a maximum power of 25.8 mW (103.2 mW cm-2), which is suitable for powering a diversity of electrical devices such as commercially available digital pregnancy tests and glucometers. While device shape and dimensions can be customized, here it is shown that the fuel cell can be designed in a compact form factor and footprint comparable to a lateral flow test while providing a remarkable power output. This approach holds great promise for powering portable diagnostics, as the generated electric power could enable device functionalities required for advanced assays, such as device timing, actuation, and signal quantification. Part of the same liquid sample that is to be analyzed (urine, saliva, water, etc) could be used to trigger the hydrogen generation and start the fuel cell operation.

  13. Parametric investigation on transient boiling heat transfer of metal rod cooled rapidly in water pool

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Chi Young [Department of Fire Protection Engineering, Pukyong National University, 45, Yongso-ro, Nam-gu, Busan 48513 (Korea, Republic of); Kim, Sunwoo, E-mail: swkim@alaska.edu [Mechanical Engineering Department, University of Alaska Fairbanks, P. O. Box 755905, Fairbanks, AK 99775-5905 (United States)

    2017-03-15

    Highlights: • Effects of liquid subcooling, surface coating, material property, and surface oxidation are examined. • Liquid subcooling affects remarkably the quenching phenomena. • Cr-coated surfaces for ATF might extend the quenching duration. • Solids with low heat capacity shorten the quenching duration. • Surface oxidation can affect strongly the film boiling heat transfer and MFB point. - Abstract: In this work, the effects of liquid subcooling, surface coating, material property, and surface oxidation on transient pool boiling heat transfer were investigated experimentally using the vertical metal rod and quenching method. The change in rod temperature was measured with time during quenching, and the visualization of boiling around the test specimen was performed using the high-speed video camera. As the test materials, the zircaloy (Zry), stainless steel (SS), niobium (Nb), and copper (Cu) were tested. In addition, the chromium-coated niobium (Cr-Nb) and chromium-coated stainless steel (Cr-SS) were prepared for accident tolerant fuel (ATF) application. Low liquid subcooling and Cr-coating shifted the quenching curve to the right, which indicates a prolongation of quenching duration. On the other hand, the material with small heat capacity and surface oxidation caused the quenching curve to move to the left. To examine the influence of the material property and surface oxidation on the film boiling heat transfer performance and minimum film boiling (MFB) point in more detail, the wall temperature and heat flux were calculated from the present transient temperature profile using the inverse heat transfer analysis, and then the curves of wall temperature and heat flux in the film boiling regime were obtained. In the present experimental conditions, the effect of material property on the film boiling heat transfer performance and MFB point seemed to be minor. On the other hand, based on the experimental results of the Cu test specimen, the surface

  14. CONNECTIVITY INDEX OF ENVIRONMENT VALENCE AND QSPR RESEARCH FOR BOILING POINTS OF SATURATED HYDROCARBON%环价连接性指数与饱和烃沸点的QSPR研究

    Institute of Scientific and Technical Information of China (English)

    沐来龙; 冯长君

    2004-01-01

    In this paper, according to the peak numbers of the nuclear magnetic resonance and the Randic embranchment degree (δi) of carbon atom i, the carbon atom's environment valence gi is defined as. gi =(ti+δi)/2. The gi reflect the characteristic of each carbon atom, and as well as the conjunction detail of the carbon atom with other carbon atoms. So, the gi could distinguish better the chemical environment of each carbon atom in the molecule than δi. A connectivity index of environment valence (mS) and its athwart index (mS') are proposed based on the adjacency matrix and the carbon atom's environment valence gi. Among them, the 0S and 0S' include the characteristic and the connectivity of each carbon atom, the 1S and 1S' reflect the second conjunction between carbon atoms. Based on 0S' and N (the number of carbon atom), a new structural parameter symmetry degree (N∝), is defined as. N∝ =[ (0S's0Sc') N]2/3, and the N∝ reflect the size of the molecule as well as the symmetry of the molecule.The N∝, 0S and Rn (the biggest ring's edge numbers of cycloalkanes) of 474 saturated hydrocarbons (216 paraffins and 258 cycloalkanes) were calculated and correlated with their boiling points. The best regression equation was obtained as follow: In ( 1056 - Tb ) = 6. 9480 - 0. 1040N∝ - 0. 0086890S -0. 009614Rn+0. 01998Rm0.5, n=474, R=0. 9989, F=52627, S=5.63K. The model was checked up by the Jackknife's method. It should have overall steadiness and could be used for predicting the boiling point of saturated hydrocarbons.

  15. Odd-Boiled Eggs

    Science.gov (United States)

    Kaminsky, Kenneth; Scheman, Naomi

    2010-01-01

    At a Shabbat lunch in Madrid not long ago, the conversation turned to the question of boiling eggs. One of the guests mentioned that a Dutch rabbi he knew had heard that in order to make it more likely that boiled eggs be kosher, you should add an egg to the pot if the number you began with was even. According to the laws of Kashruth, Jews may not…

  16. Nucleate boiling heat transfer

    Energy Technology Data Exchange (ETDEWEB)

    Saiz Jabardo, J.M. [Universidade da Coruna (Spain). Escola Politecnica Superior], e-mail: mjabardo@cdf.udc.es

    2009-07-01

    Nucleate boiling heat transfer has been intensely studied during the last 70 years. However boiling remains a science to be understood and equated. In other words, using the definition given by Boulding, it is an 'insecure science'. It would be pretentious of the part of the author to explore all the nuances that the title of the paper suggests in a single conference paper. Instead the paper will focus on one interesting aspect such as the effect of the surface microstructure on nucleate boiling heat transfer. A summary of a chronological literature survey is done followed by an analysis of the results of an experimental investigation of boiling on tubes of different materials and surface roughness. The effect of the surface roughness is performed through data from the boiling of refrigerants R-134a and R-123, medium and low pressure refrigerants, respectively. In order to investigate the extent to which the surface roughness affects boiling heat transfer, very rough surfaces (4.6 {mu}m and 10.5 {mu}m ) have been tested. Though most of the data confirm previous literature trends, the very rough surfaces present a peculiar behaviour with respect to that of the smoother surfaces (Ra<3.0 {mu}m). (author)

  17. Active energy harvesting from microbial fuel cells at the maximum power point without using resistors.

    Science.gov (United States)

    Wang, Heming; Park, Jae-Do; Ren, Zhiyong

    2012-05-01

    Microbial fuel cell (MFC) technology offers a sustainable approach to harvest electricity from biodegradable materials. Energy production from MFCs has been demonstrated using external resistors or charge pumps, but such methods can only dissipate energy through heat or receive electrons passively from the MFC without any controllability. This study developed a new approach and system that can actively extract energy from MFC reactors at any operating point without using any resistors, especially at the peak power point to maximize energy production. Results show that power harvesting from a recirculating-flow MFC can be well maintained by the maximum power point circuit (MPPC) at its peak power point, while a charge pump was not able to change operating point due to current limitation. Within 18-h test, the energy gained from the MPPC was 76.8 J, 76 times higher than the charge pump (1.0 J) that was commonly used in MFC studies. Both conditions resulted in similar organic removal, but the Coulombic efficiency obtained from the MPPC was 21 times higher than that of the charge pump. Different numbers of capacitors could be used in the MPPC for various energy storage requirements and power supply, and the energy conversion efficiency of the MPPC was further characterized to identify key factors for system improvement. This active energy harvesting approach provides a new perspective for energy harvesting that can maximize MFC energy generation and system controllability.

  18. Characterization of thermal-hydraulic and ignition phenomena in prototypic, full-length boiling water reactor spent fuel pool assemblies after a complete loss-of-coolant accident.

    Energy Technology Data Exchange (ETDEWEB)

    Lindgren, Eric Richard; Durbin, Samuel G

    2007-04-01

    The objective of this project was to provide basic thermal-hydraulic data associated with a SFP complete loss-of-coolant accident. The accident conditions of interest for the SFP were simulated in a full-scale prototypic fashion (electrically-heated, prototypic assemblies in a prototypic SFP rack) so that the experimental results closely represent actual fuel assembly responses. A major impetus for this work was to facilitate code validation (primarily MELCOR) and reduce questions associated with interpretation of the experimental results. It was necessary to simulate a cluster of assemblies to represent a higher decay (younger) assembly surrounded by older, lower-power assemblies. Specifically, this program provided data and analysis confirming: (1) MELCOR modeling of inter-assembly radiant heat transfer, (2) flow resistance modeling and the natural convective flow induced in a fuel assembly as it heats up in air, (3) the potential for and nature of thermal transient (i.e., Zircaloy fire) propagation, and (4) mitigation strategies concerning fuel assembly management.

  19. ETBP (Extended True Boiling Point) curve extension of extra heavy crudes; Extensao da curva PEV (Ponto de Ebulicao Verdadeiro) de petroleos extrapesados por destilacao molecular e ampliacao da caracterizacao

    Energy Technology Data Exchange (ETDEWEB)

    Rocha, Rodrigo S.; Batistella, Cesar B.; Maciel, Maria Regina W.; Maciel Filho, Rubens [Universidade Estadual de Campinas (UNICAMP), SP (Brazil). Faculdade de Engenharia Quimica; Medina, Lilian C. [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil). Centro de Pesquisas (CENPES)

    2008-07-01

    For the determination of the TBP (True Boiling Point) Curve, which defines the yield of petroleum products, the ASTM D2892 method for petroleum distillation and ASTM D5236 method for vacuum distillation of heavy hydrocarbons were applied. Furthermore, from these distillations, cuts that are submitted to several analyses to determine its physical-chemical properties are obtained, and all this information generates the evaluation of petroleum. For heavy petroleum, these conventional methods have been limited, since the total distilled percentage determined for temperatures up to 565 deg C (maximum reached with ASTM D5236 method) is lower for these oils, reducing the points of the curve, limiting its information. To improve this data set for heavy oils, a methodology for the extension of TBP curve through molecular distillation was established. It was possible to reach values up to 700 deg C, representing a considerable progress for the extension of TBP curve. The objective of this work is to present the results of Extended TBP curve for a heavy petroleum and characterization carried out through the cuts and residues obtained in molecular distillation of the residue 'Zeta' 400 deg C+ (fancy name), made by ASTM D2892 method. (author)

  20. Effects of dimethyl or diethyl carbonate as an additive on volatility and flash point of an aviation fuel.

    Science.gov (United States)

    Li, Dan; Fang, Wenjun; Xing, Yan; Guo, Yongsheng; Lin, Ruisen

    2009-01-30

    Vapor pressures and flash points for several mixtures of an aviation fuel with dimethyl carbonate (DMC) or diethyl carbonate (DEC) have been measured, respectively, over the entire composition range. Correlation between the experimental vapor pressures and the equilibrium temperatures by the Antoine equation is performed for each mixture. The bubble-point lines of pressure versus composition at different temperatures and those of temperature versus composition at different pressures are then obtained from the Antoine correlations. It is found that DMC and DEC are the oxygenated hydrocarbon additives that can adjust effectively the volatility and flash point of the aviation fuel. The correlation of the flash points with the vapor pressure data for the pseudo-binary mixtures of the fuel and DMC or DEC gives satisfactory results.

  1. Refining and blending of aviation turbine fuels.

    Science.gov (United States)

    White, R D

    1999-02-01

    Aviation turbine fuels (jet fuels) are similar to other petroleum products that have a boiling range of approximately 300F to 550F. Kerosene and No.1 grades of fuel oil, diesel fuel, and gas turbine oil share many similar physical and chemical properties with jet fuel. The similarity among these products should allow toxicology data on one material to be extrapolated to the others. Refineries in the USA manufacture jet fuel to meet industry standard specifications. Civilian aircraft primarily use Jet A or Jet A-1 fuel as defined by ASTM D 1655. Military aircraft use JP-5 or JP-8 fuel as defined by MIL-T-5624R or MIL-T-83133D respectively. The freezing point and flash point are the principle differences between the finished fuels. Common refinery processes that produce jet fuel include distillation, caustic treatment, hydrotreating, and hydrocracking. Each of these refining processes may be the final step to produce jet fuel. Sometimes blending of two or more of these refinery process streams are needed to produce jet fuel that meets the desired specifications. Chemical additives allowed for use in jet fuel are also defined in the product specifications. In many cases, the customer rather than the refinery will put additives into the fuel to meet their specific storage or flight condition requirements.

  2. Intelligent energy harvesting scheme for microbial fuel cells: Maximum power point tracking and voltage overshoot avoidance

    Science.gov (United States)

    Alaraj, Muhannad; Radenkovic, Miloje; Park, Jae-Do

    2017-02-01

    Microbial fuel cells (MFCs) are renewable and sustainable energy sources that can be used for various applications. The MFC output power depends on its biochemical conditions as well as the terminal operating points in terms of output voltage and current. There exists one operating point that gives the maximum possible power from the MFC, maximum power point (MPP), for a given operating condition. However, this MPP may vary and needs to be tracked in order to maintain the maximum power extraction from the MFC. Furthermore, MFC reactors often develop voltage overshoots that cause drastic drops in the terminal voltage, current, and the output power. When the voltage overshoot happens, an additional control measure is necessary as conventional MPPT algorithms will fail because of the change in the voltage-current relationship. In this paper, the extremum seeking (ES) algorithm was used to track the varying MPP and a voltage overshoot avoidance (VOA) algorithm is developed to manage the voltage overshoot conditions. The proposed ES-MPPT with VOA algorithm was able to extract 197.2 mJ during 10-min operation avoiding voltage overshoot, while the ES MPPT-only scheme stopped harvesting after only 18.75 mJ because of the voltage overshoot happened at 0.4 min.

  3. Numerical Investigation of Boiling

    Science.gov (United States)

    Sagan, Michael; Tanguy, Sebastien; Colin, Catherine

    2012-11-01

    In this work, boiling is numerically investigated, using two phase flow direct numerical simulation based on a level set / Ghost Fluid method. Nucleate boiling implies both thermal issue and multiphase dynamics issues at different scales and at different stages of bubble growth. As a result, the different phenomena are investigated separately, considering their nature and the scale at which they occur. First, boiling of a static bubble immersed in an overheated liquid is analysed. Numerical simulations have been performed at different Jakob numbers in the case of strong density discontinuity through the interface. The results show a good agreement on bubble radius evolution between the theoretical evolution and numerical simulation. After the validation of the code for the Scriven test case, interaction of a bubble with a wall is studied. A numerical method taking into account contact angle is evaluated by comparing simulations of the spreading of a liquid droplet impacting on a plate, with experimental data. Then the heat transfer near the contact line is investigated, and simulations of nucleate boiling are performed considering different contact angles values. Finally, the relevance of including a model to take into account the evaporation of the micro layer is discussed.

  4. Thermogravimetric analysis of fuel film evaporation

    Institute of Scientific and Technical Information of China (English)

    HU Zongjie; LI Liguang; YU Shui

    2006-01-01

    Thermogravimetric analysis (TGA) was compared with the petrochemical distillation measurement method to better understand the characteristics of fuel film evaporation at different wall tem- peratures. The film evaporation characteristics of 90# gasoline, 93# gasoline and 0# diesel with different initial thicknesses were investigated at different environmental fluxes and heating rates. The influences of heating rate, film thickness and environmental flux on fuel film evaporation for these fuels were found. The results showed that the environmental conditions in TGA were similar to those for fuel films in the internal combustion engines, so data from TGA were suitable for the analysis of fuel film evaporation. TGA could simulate the key influencing factors for fuel film evaporation and could investigate the basic quantificational effect of heating rate and film thickness. To get a rapid and sufficient fuel film evaporation, sufficiently high wall temperature is necessary. Evaporation time decreases at a high heating rate and thin film thickness, and intense gas flow is important to promoting fuel film evaporation. Data from TGA at a heating rate of 100℃/min are fit to analyze the diesel film evaporation during cold-start and warming-up. Due to the tense molecular interactions, the evaporation sequence could not be strictly divided according to the boiling points of each component for multicomponent dissolved mixture during the quick evaporation process, and the heavier components could vaporize before reaching their boiling points. The 0# diesel film would fully evaporate when the wall temperature is beyond 250℃.

  5. Independent evaluation of point source fossil fuel CO2 emissions to better than 10.

    Science.gov (United States)

    Turnbull, Jocelyn Christine; Keller, Elizabeth D; Norris, Margaret W; Wiltshire, Rachael M

    2016-09-13

    Independent estimates of fossil fuel CO2 (CO2ff) emissions are key to ensuring that emission reductions and regulations are effective and provide needed transparency and trust. Point source emissions are a key target because a small number of power plants represent a large portion of total global emissions. Currently, emission rates are known only from self-reported data. Atmospheric observations have the potential to meet the need for independent evaluation, but useful results from this method have been elusive, due to challenges in distinguishing CO2ff emissions from the large and varying CO2 background and in relating atmospheric observations to emission flux rates with high accuracy. Here we use time-integrated observations of the radiocarbon content of CO2 ((14)CO2) to quantify the recently added CO2ff mole fraction at surface sites surrounding a point source. We demonstrate that both fast-growing plant material (grass) and CO2 collected by absorption into sodium hydroxide solution provide excellent time-integrated records of atmospheric (14)CO2 These time-integrated samples allow us to evaluate emissions over a period of days to weeks with only a modest number of measurements. Applying the same time integration in an atmospheric transport model eliminates the need to resolve highly variable short-term turbulence. Together these techniques allow us to independently evaluate point source CO2ff emission rates from atmospheric observations with uncertainties of better than 10%. This uncertainty represents an improvement by a factor of 2 over current bottom-up inventory estimates and previous atmospheric observation estimates and allows reliable independent evaluation of emissions.

  6. Geysering in boiling channels

    Energy Technology Data Exchange (ETDEWEB)

    Aritomi, Masanori; Takemoto, Takatoshi [Tokyo Institute of Technology, Tokyo (Japan); Chiang, Jing-Hsien [Japan NUS Corp. Ltd., Toyko (Japan)] [and others

    1995-09-01

    A concept of natural circulation BWRs such as the SBWR has been proposed and seems to be promising in that the primary cooling system can be simplified. The authors have been investigating thermo-hydraulic instabilities which may appear during the start-up in natural circulation BWRs. In our previous works, geysering was investigated in parallel boiling channels for both natural and forced circulations, and its driving mechanism and the effect of system pressure on geysering occurrence were made clear. In this paper, geysering is investigated in a vertical column and a U-shaped vertical column heated in the lower parts. It is clarified from the results that the occurrence mechanism of geysering and the dependence of system pressure on geysering occurrence coincide between parallel boiling channels in circulation systems and vertical columns in non-circulation systems.

  7. Development of a diesel substitute fuel

    Energy Technology Data Exchange (ETDEWEB)

    Reiter, Anton; Mair-Zelenka, Philipp [Graz Univ. of Technology (Austria). Inst. of Chemical Engineering and Environmental Technology; Zeymer, Marc [OMV Refining and Marketing GmbH, Vienna (Austria). MRDI-D Product Development and Innovation

    2013-06-01

    Substitute fuels composed of few real chemical compounds are an alternative characterisation approach for conventional fuels as opposed to the traditional pseudo-component method. With the algorithm proposed in this paper the generation of such substitutes will be facilitated and well-established thermodynamic methods can be applied for physical property-data prediction. Based on some quality criteria like true boiling-point curve, liquid density, C/H ratio, or cloud point of a target fuel a surrogate which meets these properties is determined by fitting its composition. The application and capabilities of the algorithm developed are demonstrated by means of an exemplary diesel substitute fuel. The substitute mixture obtained can be generated and used for evaluation of property-prediction methods. Furthermore this approach can help to understand the effects of mixing fossil fuels with biogenic compounds. (orig.)

  8. Improving a free air breathing proton exchange membrane fuel cell through the Maximum Efficiency Point Tracking method

    Science.gov (United States)

    Higuita Cano, Mauricio; Mousli, Mohamed Islam Aniss; Kelouwani, Sousso; Agbossou, Kodjo; Hammoudi, Mhamed; Dubé, Yves

    2017-03-01

    This work investigates the design and validation of a fuel cell management system (FCMS) which can perform when the fuel cell is at water freezing temperature. This FCMS is based on a new tracking technique with intelligent prediction, which combined the Maximum Efficiency Point Tracking with variable perturbation-current step and the fuzzy logic technique (MEPT-FL). Unlike conventional fuel cell control systems, our proposed FCMS considers the cold-weather conditions, the reduction of fuel cell set-point oscillations. In addition, the FCMS is built to respond quickly and effectively to the variations of electric load. A temperature controller stage is designed in conjunction with the MEPT-FL in order to operate the FC at low-temperature values whilst tracking at the same time the maximum efficiency point. The simulation results have as well experimental validation suggest that propose approach is effective and can achieve an average efficiency improvement up to 8%. The MEPT-FL is validated using a Proton Exchange Membrane Fuel Cell (PEMFC) of 500 W.

  9. Oscillate boiling from microheaters

    Science.gov (United States)

    Li, Fenfang; Gonzalez-Avila, S. Roberto; Nguyen, Dang Minh; Ohl, Claus-Dieter

    2017-01-01

    We report about an intriguing boiling regime occurring for small heaters embedded on the boundary in subcooled water. The microheater is realized by focusing a continuous wave laser beam to about 10 μ m in diameter onto a 165-nm-thick layer of gold, which is submerged in water. After an initial vaporous explosion a single bubble oscillates continuously and repeatedly at several 100 kHz albeit with constant laser power input. The microbubble's oscillations are accompanied with bubble pinch-off, leading to a stream of gaseous bubbles in the subcooled water. The self-driven bubble oscillation is explained with a thermally kicked oscillator caused by surface attachment and by the nonspherical collapses. Additionally, Marangoni stresses induce a recirculating streaming flow which transports cold liquid towards the microheater, reducing diffusion of heat along the substrate and therefore stabilizing the phenomenon to many million cycles. We speculate that this oscillate boiling regime may overcome the heat transfer thresholds observed during the nucleate boiling crisis and offers a new pathway for heat transfer under microgravity conditions.

  10. Boiling incipience and convective boiling of neon and nitrogen

    Science.gov (United States)

    Papell, S. S.; Hendricks, R. C.

    1977-01-01

    Forced convection and subcooled boiling heat transfer data for liquid nitrogen and liquid neon were obtained in support of a design study for a 30 tesla cryomagnet cooled by forced convection of liquid neon. This design precludes nucleate boiling in the flow channels as they are too small to handle vapor flow. Consequently, it was necessary to determine boiling incipience under the operating conditions of the magnet system. The cryogen data obtained over a range of system pressures, fluid flow rates, and applied heat fluxes were used to develop correlations for predicting boiling incipience and convective boiling heat transfer coefficients in uniformly heated flow channels. The accuracy of the correlating equations was then evaluated. A technique was also developed to calculate the position of boiling incipience in a uniformly heated flow channel. Comparisons made with the experimental data showed a prediction accuracy of plus or minus 15 percent

  11. Self-Sustaining Thorium Boiling Water Reactors

    Directory of Open Access Journals (Sweden)

    Ehud Greenspan

    2012-10-01

    Full Text Available A thorium-fueled water-cooled reactor core design approach that features a radially uniform composition of fuel rods in stationary fuel assembly and is fuel-self-sustaining is described. This core design concept is similar to the Reduced moderation Boiling Water Reactor (RBWR proposed by Hitachi to fit within an ABWR pressure vessel, with the following exceptions: use of thorium instead of depleted uranium for the fertile fuel; elimination of the internal blanket; and elimination of absorbers from the axial reflectors, while increasing the length of the fissile zone. The preliminary analysis indicates that it is feasible to design such cores to be fuel-self-sustaining and to have a comfortably low peak linear heat generation rate when operating at the nominal ABWR power level of nearly 4000 MWth. However, the void reactivity feedback tends to be too negative, making it difficult to have sufficient shutdown reactivity margin at cold zero power condition. An addition of a small amount of plutonium from LWR used nuclear fuel was found effective in reducing the magnitude of the negative void reactivity effect and enables attaining adequate shutdown reactivity margin; it also flattens the axial power distribution. The resulting design concept offers an efficient incineration of the LWR generated plutonium in addition to effective utilization of thorium. Additional R&D is required in order to arrive at a reliable practical and safe design.

  12. Models and Stability Analysis of Boiling Water Reactors

    Energy Technology Data Exchange (ETDEWEB)

    John Dorning

    2002-04-15

    We have studied the nuclear-coupled thermal-hydraulic stability of boiling water reactors (BWRs) using a model that includes: space-time modal neutron kinetics based on spatial w-modes; single- and two-phase flow in parallel boiling channels; fuel rod heat conduction dynamics; and a simple model of the recirculation loop. The BR model is represented by a set of time-dependent nonlinear ordinary differential equations, and is studied as a dynamical system using the modern bifurcation theory and nonlinear dynamical systems analysis. We first determine the stability boundary (SB) - or Hopf bifurcation set- in the most relevant parameter plane, the inlet-subcooling-number/external-pressure-drop plane, for a fixed control rod induced external reactivity equal to the 100% rod line value; then we transform the SB to the practical power-flow map used by BWR operating engineers and regulatory agencies. Using this SB, we show that the normal operating point at 100% power is very stable, that stability of points on the 100% rod line decreases as the flow rate is reduced, and that operating points in the low-flow/high-power region are least stable. We also determine the SB that results when the modal kinetics is replaced by simple point reactor kinetics, and we thereby show that the first harmonic mode does not have a significant effect on the SB. However, we later show that it nevertheless has a significant effect on stability because it affects the basin of attraction of stable operating points. Using numerical simulations we show that, in the important low-flow/high-power region, the Hopf bifurcation that occurs as the SB is crossed is subcritical; hence, growing oscillations can result following small finite perturbations of stable steady-states on the 100% rod line at points in the low-flow/high-power region. Numerical simulations are also performed to calculate the decay ratios (DRs) and frequencies of oscillations for various points on the 100% rod line. It is

  13. A Novel EP Approach for Power Economic Dispatch with Valve-Point Effects and Multiple Fuel Options

    Directory of Open Access Journals (Sweden)

    P.S. Manoharan

    2008-06-01

    Full Text Available This paper presents a novel approach to economic dispatch problems with valve point effects and multiple fuel options using a hybrid evolutionary programming method. Determination of global optimum solution for the practical economic dispatch problem having non smooth cost functions is difficult by using conventional mathematical approaches. Hence several evolutionary algorithm methods were proposed to solve this problem. In this paper, EP-LMO (Evolutionary Programming with Levenberg-Marquardt Optimization technique is proposed to solve economic dispatch problems with valve point effects and multiple fuel options. The EP-LMO is developed in such a way that a simple evolutionary programming (EP is applied as a base level search to find the direction of the optimal global region. And Levenberg-Marquardt Optimization (LMO method is used as a fine tuning to determine the optimal solution. To illustrate the efficiency and effectiveness of the proposed approach, two bench mark problems are considered. First test problem considers multiple fuel options and next problem addresses both valve-point effects and multi-fuel options. To validate the obtained results, the proposed method is compared with the results of conventional numerical methods, Modified Hop-field Neural network, Evolutionary Programming approaches, Modified PSO, Improved PSO and Improved Genetic Algorithm with multiplier updating (IGA_MUmethod.

  14. 78 FR 61401 - Entergy Nuclear Operations, Inc.; Big Rock Point; Independent Spent Fuel Storage Installation

    Science.gov (United States)

    2013-10-03

    ... Nuclear Material Safety and Safeguards, U.S. Nuclear Regulatory Commission, Washington, DC 20555-0001..., and 10 CFR part 50, allows ENO to possess and store spent nuclear fuel at the permanently shutdown and... Director, Division of Spent Fuel Storage and Transportation, Office of Nuclear Material Safety...

  15. Boiling liquid cauldron status report

    Energy Technology Data Exchange (ETDEWEB)

    Hoffman, M.A.

    1980-12-28

    The progress made over the past year in assessing the feasibility of the high-temperature, boiling cauldron blanket concept for the tanden mirror reactor is reviewed. The status of the proposed experiments and recently revised estimates of the vapor void fraction in the boiling pool are discussed.

  16. 基于低沸点化学物质的无源轿车轮胎温度监测系统%A Passive Car Tire Temperature Monitoring System Using Low-boiling Point Chemical Substance

    Institute of Scientific and Technical Information of China (English)

    张健伟; 董群; 王鉴; 胡林杰

    2014-01-01

    利用低沸点化学物质具有较高的饱和蒸汽压的特性,设计了一种无源轿车轮胎温度监测系统。系统中的胎温传感器将温度变化通过低沸点化学物质的饱和蒸汽压的相应变化转变为磁铁的位移信号,再利用线性霍尔传感器转变为电压信号,最后通过信号检测系统对信号进行处理和转换,实现对轮胎温度的实时监测和高温报警。通过静态实验,选定了满足胎温传感器要求的感温物质;通过动态实验,考察了报警系统的检测精确度。结果表明,系统检测相对误差绝对值≤6%,测温精度为1℃。%By utilizing the property of higher saturated vapor pressure of low-boiling point chemical sub-stances, a passive car tire temperature monitoring system is designed, in which the change of temperature in tire temperature sensor is transformed into the displacement signal of magnet through the corresponding change in satu-rated vapor pressure of chemical substance. Then the displacement signal of magnet is transformed into voltage sig-nal by linear Hall sensor, and through certain signal processing and transform, the real time monitoring and high temperature alarm of tire temperature are realized. The temperature sensing chemical substance meeting the require-ments of tire temperature sensor are selected by static test, while the detection accuracy of warning system is investi-gated by dynamic test. The results show that the system achieves a relative error no more than 6% and a temperature measuring accuracy of 1℃.

  17. The Separation of Trace Substance With High Boiling Point and Refractory Volatility From Liquor%白酒中微量高沸点难挥发性物质的分离

    Institute of Scientific and Technical Information of China (English)

    戴惠东; 张良均; 黎金霞

    2013-01-01

      采用复合溶剂间歇萃取精馏提取白酒中的微量高沸点难挥发性物质(主要是邻苯二甲酸二丁酯(DBP)和邻苯二甲酸二异丁酯(DIBP)),并同时考察溶剂种类、溶剂流率和回流比对分离效果的影响。实验结果表明:复合溶剂的最佳配比为7∶3(正戊烷与无水乙醚质量比);随着溶剂流率与回流比的增大,复合溶剂分离效果增强;在最佳配比下,当回流比为2、溶剂流率为13mL/min 时,塔釜中邻苯二甲酸二丁酯和邻苯二甲酸二异丁酯的质量分数可达95.56%。%The trace substances with high boiling point and refractory volatility in liquor (mainly are Dibutyl phthalate, DBP and Diisobutyl phthalate, DIBP) were extracted by batch extractive distillation with mixed solvent, at the same time the effect of different types of solvent, solvent flow rate and reflux ratio on separation efficiency was investigated. The results shows that the best proportion of n-pentane to diethyletheranhydrous is 7∶3, and the separation effect is improved with the increasing of solvent rate and reflux ratio, and under the conditions that the optimum value of solvent m (n-pentane):m (diethyletheranhydrous)=7∶3, reflux ratio is 2, and flow rate of solvent is 13mL/min, the mass fraction of DBP and DIBP in the bottom reaches 98.56%.

  18. Experimental study of external fuel vaporization

    Science.gov (United States)

    Szetela, E. J.; Tevelde, J. A.

    1982-01-01

    The fuel properties used in the design of a flash vaporization system for aircraft gas turbine engines were evaluated in experiments using a flowing system to determine critical temperature and pressure, boiling points, dew points, heat transfer coefficients, deposit formation rates, and deposit removal. Three fuels were included in the experiments: Jet-A, an experimental referree broad specification fuel, and a premium No. 2 diesel fuel. Engine conditions representing a NASA Energy Efficient Engine at sea-level take-off, cruise, and idle were simulated in the vaporization system and it was found that single phase flow was maintained in the heat exchanger and downstream of the throttle. Deposits encountered in the heat exchanger represented a thermal resistance as high as 1300 sq M K/watt and a deposit formation rate over 1000 gC/sq cm hr.

  19. Experimental Evidence of the Vapor Recoil Mechanism in the Boiling Crisis

    CERN Document Server

    Nikolayev, Vadim; Garrabos, Y; Beysens, D

    2016-01-01

    Boiling crisis experiments are carried out in the vicinity of the liquid-gas critical point of H2. A magnetic gravity compensation setup is used to enable nucleate boiling at near critical pressure. The measurements of the critical heat flux that defines the threshold for the boiling crisis are carried out as a function of the distance from the critical point. The obtained power law behavior and the boiling crisis dynamics agree with the predictions of the vapor recoil mechanism and disagree with the classical vapor column mechanism.

  20. Combustion of liquid fuels floating on water

    Directory of Open Access Journals (Sweden)

    Garo Jean-Pierre

    2007-01-01

    Full Text Available The research presented consists of a study of the burning characteristics of a liquid fuel floating on water with emphasis in the phenomena known as boilover. The problem is of technical interest in the petro-chemical industry, particularly from the point of view of pollution and fires resulting from accidental liquid fuel spills in open water. Testing with multicomponent fuels gives information's about events that can occur in a practical situation, while testing with single component fuels permits obtaining fundamental information about the problem. It evidences the major effects caused by the transfer of heat from the fuel to the water underneath. One of these effects is the disruptive burning of the fuel known as boilover, that is caused by the water boiling and splashing, and results in a sharp increase in burning rate and often in the explosive burning of the fuel. It is shown that this event is caused by the onset of water boiling nucleation at the fuel/water interface and that it occurs at an approximate constant temperature that is above the saturation temperature of the water (water is superheated. These measurements conducted in two laboratories, address the major issues of the process by analyzing the effect of the variation of the parameters of the problem (initial fuel-layer thickness, pool diameter, and fuel type, on the burning rate, time to start of boilover, pre-boilover mass ratio, and boilover intensity. Finally, two types of modeling are proposed to describe the heat transfer in fuel and water phases: one simple for practical purposes, the other, more elaborated and transient, taking particularly into consideration the radiation in depth.

  1. Fuel performance improvement program. Quarterly/annual progress report, October 1977--September 1978. [BWR; PWR

    Energy Technology Data Exchange (ETDEWEB)

    Crouthamel, C.E. (comp.)

    1978-10-01

    This quarterly/annual report reviews and summarizes the activities performed in support of the Fuel Performance Improvement Program (FPIP) during Fiscal Year 1978 with emphasis on those activities that transpired during the quarter ending September 30, 1978. Significant progress has been made in achieving the primary objectives of the program, i.e., to demonstrate commercially viable fuel concepts with improved fuel - cladding interaction (FCI) behavior. This includes out-of-reactor experiments to support the fuel concepts being evaluated, initiation of instrumented test rod experiments in the Halden Boiling Water Reactor (HBWR), and fabrication of the first series of demonstration rods for irradiation in the Big Rock Point Reactor (BRPR).

  2. Film boiling of mercury droplets

    Science.gov (United States)

    Baumeister, K. J.; Schoessow, G. J.; Chmielewski, C. E.

    1975-01-01

    Vaporization times of mercury droplets in Leidenfrost film boiling on a flat horizontal plate are measured in an air atmosphere. Extreme care was used to prevent large amplitude droplet vibrations and surface wetting; therefore, these data can be compared to film boiling theory. For these data, diffusion from the upper surface of the drop is a dominant mode of mass transfer from the drop. A closed-form analytical film boiling theory is developed to account for the diffusive evaporation. Reasonable agreement between data and theory is seen.

  3. Fuels and Lubricants for Aircraft

    Science.gov (United States)

    1975-02-27

    Alcohol is formed as a result of fermatation of sugary substances. The latter are obtained by processing starch present in food raw material, or by...elementalcomposition are given in ’fable 1; 29. 2Approximate data; 3 At the boiling point. 31. 4 Without consumption from outside; 32. 5Boric anhydride being...where P is the thrust force;ý ’•lis the time of its action during the consumption of 1 kg of fuel. The unit impulse is equal to the thrust of the

  4. Two dimensional point of use fuel cell : a final LDRD project report.

    Energy Technology Data Exchange (ETDEWEB)

    Zavadil, Kevin Robert; Hickner, Michael A. (Pennsylvania State University, University Park, PA); Gross, Matthew L. (Pennsylvania State University, University Park, PA)

    2011-03-01

    The Proliferation Assessment (program area - Things Thin) within the Defense Systems and Assessment Investment Area desires high energy density and long-lived power sources with moderate currents (mA) that can be used as building blocks in platforms for the continuous monitoring of chemical, biological, and radiological agents. Fuel cells can be an optimum choice for a power source because of the high energy densities that are possible with liquid fuels. Additionally, power generation and fuel storage can be decoupled in a fuel cell for independent control of energy and power density for customized, application-driven power solutions. Direct methanol fuel cells (DMFC) are explored as a possible concept to develop into ultrathin or two-dimensional power sources. New developments in nanotechnology, advanced fabrication techniques, and materials science are exploited to create a planar DMFC that could be co-located with electronics in a chip format. Carbon nanotubes and pyrolyzed polymers are used as building block electrodes - porous, mechanically compliant current collectors. Directed assembly methods including surface functionalization and layer-by-layer deposition with polyelectrolytes are used to pattern, build, and add functionality to these electrodes. These same techniques are used to incorporate nanoscale selective electrocatalyst into the carbon electrodes to provide a high density of active electron transfer sites for the methanol oxidation and oxygen reduction reactions. The resulting electrodes are characterized in terms of their physical properties, electrocatalytic function, and selectivity to better understand how processing impacts their performance attributes. The basic function of a membrane electrode assembly is demonstrated for several prototype devices.

  5. High flux film and transition boiling

    Energy Technology Data Exchange (ETDEWEB)

    Witte, L.C.

    1990-01-01

    This report is a bench-scale experiment on transition boiling. The author gives a detailed description on experimental apparatus and conditions. The visual observed boiling phenomena; nucleate boiling and film boiling, and the effect of heat transfer are also elucidated. 10 refs., 11 figs., 1 tab.

  6. Enhanced heat transfer in confined pool boiling

    NARCIS (Netherlands)

    Rops, C.M.; Lindken, R.; Velthuis, J.F.M.; Westerweel, J.

    2009-01-01

    We report the results of an experimental investigation of the heat transfer during nucleate boiling on a spatially confined boiling surface. The heat flux as a function of the boiling surface temperature was measured in pool boiling pots with diameters ranging from 15 mm down to 4.5 mm. It was found

  7. Enhanced heat transfer in confined pool boiling

    NARCIS (Netherlands)

    Rops, C.M.; Lindken, R.; Velthuis, J.F.M.; Westerweel, J.

    2009-01-01

    We report the results of an experimental investigation of the heat transfer during nucleate boiling on a spatially confined boiling surface. The heat flux as a function of the boiling surface temperature was measured in pool boiling pots with diameters ranging from 15 mm down to 4.5 mm. It was found

  8. Film boiling on vertical surfaces.

    Science.gov (United States)

    Suryanarayana, N. V.; Merte, H., Jr.

    1972-01-01

    Film boiling of a saturated liquid on a vertical surface is analyzed to determine the local heat-transfer rates as a function of height and heater-surface superheat. Experiments show that the laminar-flow model is inadequate. A turbulent-vapor-flow model is used, and the influence of the interfacial oscillations is incorporated on a semiempirical basis. Measurements of local film boiling were obtained with a transient technique using saturated liquid nitrogen.

  9. Technical Breakthrough Points and Opportunities in Transition Scenarios for Hydrogen as Vehicular Fuel

    Energy Technology Data Exchange (ETDEWEB)

    Diakov, V.; Ruth, M.; James, B.; Perez, J.; Spisak, A.

    2011-12-01

    This technical reports is about investigating a generic case of hydrogen production/delivery/dispensing pathway evolution in a large population city, assuming that hydrogen fuel cell electric vehicles (FCEV) will capture a major share of the vehicle market by the year 2050. The range of questions that are considered includes (i) what is the typical succession of hydrogen pathways that minimizes consumer cost? (ii) what are the major factors that will likely influence this sequence?

  10. ALTERNATIVE AVIATION FUELS FOR USE IN MILITARY APUS AND ENGINES VERSATILE AFFORDABLE ADVANCED TURBINE ENGINE (VAATE), PHASE II AND III. Delivery Order 0007: Alternative Aviation Fuels for Use in Military Auxiliary Power Units (APUs) and Engines

    Science.gov (United States)

    2017-06-03

    due to the very low emissions levels, and since small changes in measured values result in large percent changes. Smoke emissions with the GD...decreased less than 6%v due to the low blend ratio. Smoke emissions were very low (SN < 10) at all conditions with all fuels, so small variation...and emissions of aircraft gas turbine engines. Blends of a low freeze point HEFA synthetic paraffinic kerosene (SPK) in the diesel fuel boiling

  11. Experiments of Pool Boiling Performance (Boiling Heat Transfer and Critical Heat Flux) on Designed Micro-Structures

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Seol Ha; Kang, Jun Young; Lee, Gi Chol; Kiyofumia, Moriyama; Kim, Moo Hwan; Park, Hyun Sun [POSTECH, Pohang (Korea, Republic of)

    2015-05-15

    In general, the evaluation of the boiling performance mainly focuses on two physical parameters: boiling heat transfer (BHT) and critical heat flux (CHF). In the nuclear power plants, both BHT and CHF contribute the nuclear system efficiency and safety, respectively. In this study, BHT and CHF of the pool boiling on well-organized fabricated structured (micro scaled) surface has been evaluated. As a results, BHT change on microstructured surface shows strongly dependent on Pin-fin effect analysis. In terms of CHF, critical size of micro structure for CHF enhancement has been observed and analyzed based on the capillary wicking effect. In this study, BHT and CHF of the pool boiling on well-organized fabricated structured (micro scaled) surface has been evaluated. As a results, BHT change on microstructured surface shows strongly dependent on the roughness ratio. The extended heat transfer area contributes the boiling heat transfer increase on the structured surface, and its quantitative analysis has been performed. In terms of CHF, the critical size of micro structure for CHF enhancement has been observed and analyzed based on the capillary wicking effect. We suggested a capillary limit to CHF delay for modeling capillary induced liquid inflow through microstructured surfaces. The critical size of the capillary limit on the prepared structured surface, determined by a model, could be reasonable explanation points for the experimental results (optimal size for CHF delay). The present experimental results also showed clearly the critical size (10 - 20 μm) for CHF delay, predicted by capillary limit analysis. This study provides fundamental insight into BHT and CHF enhancement of structured surfaces, and an optimal design guide for the required CHF and boiling heat-transfer performance. Finally, this study can contribute the basic understanding of the boiling on designed microstructure surface, and it also suggest the optimal micro scaled structured surface of boiling

  12. On the rational formulation of alternative fuels: melting point and net heat of combustion predictions for fuel compounds using machine learning methods.

    Science.gov (United States)

    Saldana, D A; Starck, L; Mougin, P; Rousseau, B; Creton, B

    2013-01-01

    We report the development of predictive models for two fuel specifications: melting points (T(m)) and net heat of combustion (Δ(c)H). Compounds inside the scope of these models are those likely to be found in alternative fuels, i.e. hydrocarbons, alcohols and esters. Experimental T(m) and Δ(c)H values for these types of molecules have been gathered to generate a unique database. Various quantitative structure-property relationship (QSPR) approaches have been used to build models, ranging from methods leading to multi-linear models such as genetic function approximation (GFA), or partial least squares (PLS) to those leading to non-linear models such as feed-forward artificial neural networks (FFANN), general regression neural networks (GRNN), support vector machines (SVM), or graph machines. Except for the case of the graph machines method for which the only inputs are SMILES formulae, previously listed approaches working on molecular descriptors and functional group count descriptors were used to develop specific models for T(m) and Δ(c)H. For each property, the predictive models return slightly different responses for each molecular structure. Therefore, models labelled as 'consensus models' were built by averaging values computed with selected individual models. Predicted results were then compared with experimental data and with predictions of models in the literature.

  13. Thermodynamic and Gasdynamic Aspects of a Boiling Liquid Expanding Vapour Explosion

    NARCIS (Netherlands)

    Xie, M.

    2013-01-01

    The risk of explosion due to rupture of a tank filled with pressurized liquefied gas (PLG) is one of the risks to be considered in the context of studies on tunnel safety. When a vessel containing liquid well above its boiling point at normal atmospheric pressure fails catastrophically a Boiling Liq

  14. Stability monitoring for boiling water reactors

    Science.gov (United States)

    Cecenas-Falcon, Miguel

    1999-11-01

    A methodology is presented to evaluate the stability properties of Boiling Water Reactors based on a reduced order model, power measurements, and a non-linear estimation technique. For a Boiling Water Reactor, the feedback reactivity imposed by the thermal-hydraulics has an important effect in the system stability, where the dominant contribution to this feedback reactivity is provided by the void reactivity. The feedback reactivity is a function of the operating conditions of the system, and cannot be directly measured. However, power measurements are relatively easy to obtain from the nuclear instrumentation and process computer, and are used in conjunction with a reduced order model to estimate the gain of the thermal-hydraulics feedback using an Extended Kalman Filter. The reduced order model is obtained by estimating the thermal-hydraulic transfer function from the frequency-domain BWR code LAPUR, and the stability properties are evaluated based on the pair of complex conjugate eigenvalues. Because of the recursive nature of the Kalman Filter, an estimate of the decay ratio is generated every sampling time, allowing continuous estimation of the stability parameters. A test platform based on a nuclear-coupled boiling channel is developed to validate the capability of the BWR stability monitoring methodology. The thermal-hydraulics for the boiling channel is modeled and coupled with neutron kinetics to analyze the non-linear dynamics of the closed-loop system. The model uses point kinetics to study core-wide oscillations, and normalized modal kinetics are introduced to study out-of-phase oscillations. The coolant flow dynamics is dominant in the power fluctuations observed by in-core nuclear instrumentation, and additive white noise is added to the solution for the channel flow in the thermal-hydraulic model to generate noisy power time series. The operating conditions of the channel can be modified to accommodate a wide range of stability conditions

  15. Rising and boiling of a drop of volatile liquid in a heavier one: application to the LMFBR severe accidents

    Energy Technology Data Exchange (ETDEWEB)

    Pigny, Sylvain L.; Coste, Pierre F. [DEN/DER/SSTH, CEA/Grenoble, 38054 Grenoble Cedex 9 (France)

    2005-07-01

    Full text of publication follows: The rising and, simultaneously the boiling, of a droplet of volatile liquid in a heavier one is computation-ally investigated. Our calculations are performed with the help of the SIMMER code, in which a specific DNS algorithm is developed, to represent surface tension between the different media in an explicit way. This is required to represent the physical contact that occurs between two liquids and the vapor from the lighter one, since interfacial heat transfers, and therefore boiling kinetics, merely depend on it. The behavior of the three fluids system is of interest as a key phenomenon related to the transition phase of LMFBR severe accidents, before the formation of a fully developed bubble column. The driven force due to the boiling of steel drops can play a major role in the relocation, and, consequently, the recriticality of UO{sub 2} fuel. The problem is investigated focusing first on analytical experiments, built-up with simulating materials, and for which accurate experimental results are provided. The dependence of results with regard to thermodynamical and physical properties is underlined. This point is of interest in view of some uncertainties in the knowledge of data concerning the materials present in the reactor at high temperature. The pressure level is a key parameter in the accident scenarios: its influence is uppermost on the volumic mass of the gas. It is also outlined. (authors)

  16. High heat flux transport by microbubble emission boiling

    Science.gov (United States)

    Suzuki, Koichi

    2007-10-01

    In highly subcooled flow boiling, coalescing bubbles on the heating surface collapse to many microbubbles in the beginning of transition boiling and the heat flux increases higher than the ordinary critical heat flux. This phenomenon is called Microbubble Emission Boiling, MEB. It is generated in subcooled flow boiling and the maximum heat flux reaches about 1 kW/cm2(10 MW/m2) at liquid subcooling of 40 K and liquid velocity of 0.5 m/s for a small heating surface of 10 mm×10 mm which is placed at the bottom surface of horizontal rectangular channel. The high pressure in the channel is observed at collapse of the coalescing bubbles and it is closely related the size of coalescing bubbles. Periodic pressure waves are observed in MEB and the heat flux increases linearly in proportion to the pressure frequency. The frequency is considered the frequency of liquid-solid exchange on the heating surface. For the large sized heating surface of 50 mm length×20 mm width, the maximum heat flux obtained is 500 W/cm2 (5 MW/m2) at liquid subcooling of 40 K and liquid velocity of 0.5 m/s. This is considerably higher heat flux than the conventional cooling limit in power electronics. It is difficult to remove the high heat flux by MEB for a longer heating surface than 50 mm by single channel type. A model of advanced cooling device is introduced for power electronics by subcooled flow boiling with impinging jets. Themaxumum cooling heat flux is 500 W/cm2 (5 MW/m2). Microbubble emission boiling is useful for a high heat flux transport technology in future power electronics used in a fuel-cell power plant and a space facility.

  17. Flow boiling in expanding microchannels

    CERN Document Server

    Alam, Tamanna

    2017-01-01

    This Brief presents an up to date summary of details of the flow boiling heat transfer, pressure drop and instability characteristics; two phase flow patterns of expanding microchannels. Results obtained from the different expanding microscale geometries are presented for comparison and addition to that, comparison with literatures is also performed. Finally, parametric studies are performed and presented in the brief. The findings from this study could help in understanding the complex microscale flow boiling behavior and aid in the design and implementation of reliable compact heat sinks for practical applications.

  18. Coupled analysis of core thermal hydraulics and fuel performance to evaluate a thermally induced fuel failure in an SFR subassembly

    Energy Technology Data Exchange (ETDEWEB)

    Choi, Sun Rock; Chang, Doo Soo; Kim, Sang Ji [KAERI, Daejeon (Korea, Republic of)

    2012-10-15

    A limiting factor analysis in a core thermal design is highly important to assure the safe and reliable operation of a reactor system. In a sodium cooled fast reactor (SFR), the coolant thermal conductivity is about hundreds of times larger than the thermal conductivity of water. Moreover, the coolant boiling temperature in an SFR is around 900 .deg. C, which is much higher than that of the water coolant in a PWR. Considering typical operating temperatures, an SFR has about a 300 .deg. C thermal margin to its boiling point. Therefore, instead of DNBR (Departure from Nucleate Boiling Ratio) in a PWR, the core thermal design of SFRs requires assuring proper fuel performance and safety, where the design limits are highly related to the temperature distribution and material behavior under various operating conditions. Typical limiting factors in SFRs are the thermal component of the plastic hoop strain, radial primary hoop stress, and cumulative damage factor during normal operation. However, the previous fuel performance codes only evaluate a single fuel pin performance, which neglects the radial peaking factors and reveals too conservative results. In this work, the multi physics analysis is performed using both thermalhydraulic and fuel performance codes.

  19. Geologic Controls of Sand Boil Formation at Buck Chute, Mississippi

    Science.gov (United States)

    2017-06-30

    Geology ........................................................................................................................... 4 2.3 Description of...18 3.1 Geology of the Lower Mississippi River Valley...Hypothesis Sand boil formation at the Buck Chute site is the result of geology consisting of point bar and abandoned channel deposits with a thin

  20. Achieving a Green Solution: Limitations and Focus Points for Sustainable Algal Fuels

    Directory of Open Access Journals (Sweden)

    Blanca Antizar-Ladislao

    2012-05-01

    Full Text Available Research investigating the potential of producing biofuels from algae has been enjoying a recent revival due to heightened oil prices, uncertain fossil fuel sources and legislative targets aimed at reducing our contribution to climate change. If the concept is to become a reality however, many obstacles need to be overcome. Recent studies have suggested that open ponds provide the most sustainable means of cultivation infrastructure due to their low energy inputs compared to more energy intensive photobioreactors. Most studies have focused on strains of algae which are capable of yielding high oil concentrations combined with high productivity. Yet it is very difficult to cultivate such strains in open ponds as a result of microbial competition and limited radiation-use efficiency. To improve viability, the use of wastewater has been considered by many researchers as a potential source of nutrients with the added benefit of tertiary water treatment however productivity rates are affected and optimal conditions can be difficult to maintain year round. This paper investigates the process streams which are likely to provide the most viable methods of energy recovery from cultivating and processing algal biomass. The key findings are the importance of a flexible approach which depends upon location of the cultivation ponds and the industry targeted. Additionally this study recommends moving towards technologies producing higher energy recoveries such as pyrolysis or anaerobic digestion as opposed to other studies which focused upon biodiesel production.

  1. Research of some marks contemporary hydrocarbon fuel surface tension

    Directory of Open Access Journals (Sweden)

    С.В. Бойченко

    2005-01-01

    Full Text Available  The  surface  tension  of  some  marks  domestic  and  foreign  gasoline’s  and  jet  fuels  is  investigated  depending  on  distillation. Dependences  of  surface  tension,  composition,  boiling  points  liquid  fuel  experimentally  are  received.

  2. Intensification and forecasting of low-pour-point diesel fuel production via modelling reactor and stabilizer column at industrial unit

    Science.gov (United States)

    Belinskaya, N. S.; Frantsina, E. V.; Ivanchina, E. D.; Popova, N. V.; Zyryanova, I. V.; Averyanova, E. V.

    2016-09-01

    In this work forecast calculation of stabilizer column in the technology of low-pour- point diesel fuel production was modelled. The results of forecast calculation were proved by full-scale experiment at diesel fuel catalytic dewaxing unit. The forecast calculation and full- scale experiment made it possible to determine the ways of mass transfer intensification, as well as to increase the degree of hydrogen sulphide removal in the column, and thereby to decrease corrosiveness of the product stream. It was found out that maintenance of the reflux rate in the range of 80-90 m3/h and injection of additional vapourizing streams, such as stable naphtha from distillation unit (in the volume of 10-22 m3/h) and hydrogen-containing gas (in the volume of 100-300 m3/h), ensure complete elimination of corrosive hydrogen sulphide from the product stream. Reduction of stream corrosive activity due to suggested solutions extends service life of equipment and pipelines at industrial catalytic dewaxing unit.

  3. Boiling heat transfer in dilute emulsions

    CERN Document Server

    Roesle, Matthew Lind

    2013-01-01

    Boiling Heat Transfer in Dilute Emulsions synthesizes recent advances and established understanding on the subject of boiling in dilute emulsions. Experimental results from various sources are collected and analyzed, including contemporary experiments that correlate visualization with heat transfer data. Published models of boiling heat transfer in dilute emulsions, and their implementation, are described and assessed against experimental data.

  4. Data summary report for the destructive examination of Rods G7, G9, J8, I9, and H6 from Turkey Point Fuel Assembly B17

    Energy Technology Data Exchange (ETDEWEB)

    Davis, R B; Pasupathi, V

    1981-04-01

    Destructive examination results of five spent fuel rods from a Turkey Point Unit 3 pressurized water reactor are reported. Examinations included fission gas analysis, cladding hydrogen content analysis, fuel burnup analysis, metallographic examination, autoradiography and shielded electron microprobe analysis. All rods were found to be of sound integrity with an average burnup of 27 GWd/MTU and a 0.3% fission gas release.

  5. Experimental Study on Boiling Crisis in Pool Boiling

    Energy Technology Data Exchange (ETDEWEB)

    Jung, Satbyoul; Kim, Hyungdae [Kyung Hee University, Yongin (Korea, Republic of)

    2016-10-15

    They postulated that failure in re-wetting of a dry patch by a cooling liquid is governed by microhydrodynamics near the wall. Chu et al. commonly observed that active coalescence of newly generated bubbles with preexisting bubbles results in a residual dry patch and prevents the complete rewetting of the dry patch, leading to CHF. In this work, to reveal the key physical mechanism of CHF during the rewetting process of a dry patch, dynamics of dry patches and thermal pattern of a boiling surface are simultaneously observed using TR and IR thermometry techniques. Local dynamics of dry patch and thermal pattern on a boiling surface in synchronized manner for both space and time using TR and IR thermometry were measured during pool boiling of water. Observation and quantitative examination of CHF was performed. - The hydrodynamic and thermal behaviors of irreversible dry patch were observed. The dry patches coalesce into a large dry patch and it locally dried out. Due to the failure of liquid rewetting, the dry patch is not completely rewetted, resulting in the burn out at which temperature is -140°C. - When temperature of a dry patch rises beyond the instantaneous nucleation temperature, several bubbles nucleate at the head of the advancing liquid meniscus and prevents the liquid front, and eventually the overheated dry patch remains alive after the departure of the massive bubble.

  6. Evaluation of correlations of flow boiling heat transfer of R22 in horizontal channels.

    Science.gov (United States)

    Zhou, Zhanru; Fang, Xiande; Li, Dingkun

    2013-01-01

    The calculation of two-phase flow boiling heat transfer of R22 in channels is required in a variety of applications, such as chemical process cooling systems, refrigeration, and air conditioning. A number of correlations for flow boiling heat transfer in channels have been proposed. This work evaluates the existing correlations for flow boiling heat transfer coefficient with 1669 experimental data points of flow boiling heat transfer of R22 collected from 18 published papers. The top two correlations for R22 are those of Liu and Winterton (1991) and Fang (2013), with the mean absolute deviation of 32.7% and 32.8%, respectively. More studies should be carried out to develop better ones. Effects of channel dimension and vapor quality on heat transfer are analyzed, and the results provide valuable information for further research in the correlation of two-phase flow boiling heat transfer of R22 in channels.

  7. High conversion pressurized water reactor with boiling channels

    Energy Technology Data Exchange (ETDEWEB)

    Margulis, M., E-mail: maratm@post.bgu.ac.il [The Unit of Nuclear Engineering, Ben Gurion University of the Negev, POB 653, Beer Sheva 84105 (Israel); Shwageraus, E., E-mail: es607@cam.ac.uk [Department of Engineering, University of Cambridge, CB2 1PZ Cambridge (United Kingdom)

    2015-10-15

    Highlights: • Conceptual design of partially boiling PWR core was proposed and studied. • Self-sustainable Th–{sup 233}U fuel cycle was utilized in this study. • Seed-blanket fuel assembly lattice optimization was performed. • A coupled Monte Carlo, fuel depletion and thermal-hydraulics studies were carried out. • Thermal–hydraulic analysis assured that the design matches imposed safety constraints. - Abstract: Parametric studies have been performed on a seed-blanket Th–{sup 233}U fuel configuration in a pressurized water reactor (PWR) with boiling channels to achieve high conversion ratio. Previous studies on seed-blanket concepts suggested substantial reduction in the core power density is needed in order to operate under nominal PWR system conditions. Boiling flow regime in the seed region allows more heat to be removed for a given coolant mass flow rate, which in turn, may potentially allow increasing the power density of the core. In addition, reduced moderation improves the breeding performance. A two-dimensional design optimization study was carried out with BOXER and SERPENT codes in order to determine the most attractive fuel assembly configuration that would ensure breeding. Effects of various parameters, such as void fraction, blanket fuel form, number of seed pins and their dimensions, on the conversion ratio were examined. The obtained results, for which the power density was set to be 104 W/cm{sup 3}, created a map of potentially feasible designs. It was found that several options have the potential to achieve end of life fissile inventory ratio above unity, which implies potential feasibility of a self-sustainable Thorium fuel cycle in PWRs without significant reduction in the core power density. Finally, a preliminary three-dimensional coupled neutronic and thermal–hydraulic analysis for a single seed-blanket fuel assembly was performed. The results indicate that axial void distribution changes drastically with burnup. Therefore

  8. Structure Activity Relationship Study of Topological Index in Boiling Point and Molar Ref raction of Aliphatic Aldehydes,Ketones,Amines%拓扑指数在脂肪族醛酮胺沸点和摩尔折射中的构效关系研究

    Institute of Scientific and Technical Information of China (English)

    周长会; 吴启勋; 张瑞; 高宴梓

    2013-01-01

    通过对杂原子进行“染色”,建立了脂肪醛、脂肪酮和脂肪胺化合物分子的距离矩阵和邻接矩阵,在邻接矩阵和距离矩阵的基础上,构建了一种拓扑指数W,将拓扑指数W分别与脂肪醛、脂肪酮和脂肪胺化合物的沸点及摩尔折射进行非线性回归,取得的结果可以用来预测脂肪醛、脂肪酮和脂肪胺化合物的沸点及摩尔折射Rm ,这为脂肪族类化合物的研究提供理论基础。%In this paper the distance matrix and adjacency matrix of aliphatic aldehydes ,ketones , and amines compounds molecules were established primarily by tintaging the heteroatoms ,then on the basis of distance matrix and adjacency matrix a topological index was constructed .Subsequently , the topological index and the boiling point and the molar refraction of aliphatic aldehydes ,ketones , and amines compounds were put into nonlinear regression respectively .Fortunately a satisfactory re-sult was obtained which can be used to predict the boiling point and molar refraction of aliphatic alde-hydes ,ketones ,and amines .This work provides theoretical foundation for the investigation of the types of aliphatic compounds .

  9. Modeling acid-gas generation from boiling chloride brines

    Directory of Open Access Journals (Sweden)

    Sonnenthal Eric

    2009-11-01

    Full Text Available Abstract Background This study investigates the generation of HCl and other acid gases from boiling calcium chloride dominated waters at atmospheric pressure, primarily using numerical modeling. The main focus of this investigation relates to the long-term geologic disposal of nuclear waste at Yucca Mountain, Nevada, where pore waters around waste-emplacement tunnels are expected to undergo boiling and evaporative concentration as a result of the heat released by spent nuclear fuel. Processes that are modeled include boiling of highly concentrated solutions, gas transport, and gas condensation accompanied by the dissociation of acid gases, causing low-pH condensate. Results Simple calculations are first carried out to evaluate condensate pH as a function of HCl gas fugacity and condensed water fraction for a vapor equilibrated with saturated calcium chloride brine at 50-150°C and 1 bar. The distillation of a calcium-chloride-dominated brine is then simulated with a reactive transport model using a brine composition representative of partially evaporated calcium-rich pore waters at Yucca Mountain. Results show a significant increase in boiling temperature from evaporative concentration, as well as low pH in condensates, particularly for dynamic systems where partial condensation takes place, which result in enrichment of HCl in condensates. These results are in qualitative agreement with experimental data from other studies. Conclusion The combination of reactive transport with multicomponent brine chemistry to study evaporation, boiling, and the potential for acid gas generation at the proposed Yucca Mountain repository is seen as an improvement relative to previously applied simpler batch evaporation models. This approach allows the evaluation of thermal, hydrological, and chemical (THC processes in a coupled manner, and modeling of settings much more relevant to actual field conditions than the distillation experiment considered. The actual

  10. Modeling acid-gas generation from boiling chloride brines

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Guoxiang; Spycher, Nicolas; Sonnenthal, Eric; Steefel, Carl

    2009-11-16

    This study investigates the generation of HCl and other acid gases from boiling calcium chloride dominated waters at atmospheric pressure, primarily using numerical modeling. The main focus of this investigation relates to the long-term geologic disposal of nuclear waste at Yucca Mountain, Nevada, where pore waters around waste-emplacement tunnels are expected to undergo boiling and evaporative concentration as a result of the heat released by spent nuclear fuel. Processes that are modeled include boiling of highly concentrated solutions, gas transport, and gas condensation accompanied by the dissociation of acid gases, causing low-pH condensate. Simple calculations are first carried out to evaluate condensate pH as a function of HCl gas fugacity and condensed water fraction for a vapor equilibrated with saturated calcium chloride brine at 50-150 C and 1 bar. The distillation of a calcium-chloride-dominated brine is then simulated with a reactive transport model using a brine composition representative of partially evaporated calcium-rich pore waters at Yucca Mountain. Results show a significant increase in boiling temperature from evaporative concentration, as well as low pH in condensates, particularly for dynamic systems where partial condensation takes place, which result in enrichment of HCl in condensates. These results are in qualitative agreement with experimental data from other studies. The combination of reactive transport with multicomponent brine chemistry to study evaporation, boiling, and the potential for acid gas generation at the proposed Yucca Mountain repository is seen as an improvement relative to previously applied simpler batch evaporation models. This approach allows the evaluation of thermal, hydrological, and chemical (THC) processes in a coupled manner, and modeling of settings much more relevant to actual field conditions than the distillation experiment considered. The actual and modeled distillation experiments do not represent

  11. Length Scale and Gravity Effects on Microgravity Boiling Heat Transfer

    Science.gov (United States)

    Kim, Jungho; McQuillen, John; Balombin, Joe

    2002-01-01

    Boiling is a complex phenomenon where hydrodynamics, heat transfer, mass transfer, and interfacial phenomena are tightly interwoven. An understanding of boiling and critical heat flux in microgravity environments is of importance to space based hardware and processes such as heat exchange, cryogenic fuel storage and transportation, electronic cooling, and material processing due to the large amounts of heat that can be removed with relatively little increase in temperature. Although research in this area has been performed in the past four decades, the mechanisms by which heat is removed from surfaces in microgravity are still unclear. In earth gravity, buoyancy is an important parameter that affects boiling heat transfer through the rate at which bubbles are removed from the surface. A simple model describing the bubble departure size based on a quasistatic force balance between buoyancy and surface tension is given by the Fritz [I] relation: Bo(exp 1/2) = 0.0208 theta where Bo is the ratio between buoyancy and surface tension forces. For small, rapidly growing bubbles, inertia associated with the induced liquid motion can also cause bubble departure. In microgravity, the magnitude of effects related to natural convection and buoyancy are small and physical mechanisms normally masked by natural convection in earth gravity such as Marangoni convection can substantially influence the boiling and vapor bubble dynamics. CHF (critical heat transfer) is also substantially affected by microgravity. In 1 g environments, Bo has been used as a correlating parameter for CHF. Zuber's CHF model for an infinite horizontal surface assumes that vapor columns formed by the merger of bubbles become unstable due to a Helmholtz instability blocking the supply of liquid to the surface. The jets are spaced lambda(sub D) apart, where lambda(sub D) = 2pi square root of 3[(sigma)/(g(rho(sub l) - rho(sub v)](exp 1/2) = 2pi square root of 3 L Bo(exp -1/2) = square root of 3 lambda(sub c

  12. Increase in the boiler's performance in terms of the acid dew point temperature: Environmental advantages of replacing fuels

    Energy Technology Data Exchange (ETDEWEB)

    Blanco, J.M.; Pena, F. [Dpto. Maquinas y Motores Termicos, Escuela Tecnica Superior de Ingenieria, Universidad del Pais Vasco/E.H.U., Alameda de Urquijo s/n (48013) Bilbao (Spain)

    2008-05-15

    The aim of air pre-heaters is to raise the temperature of the combustion air in boilers, using heat recovered from the power plant combustion gases. On the one hand, this paper compares the effects of the acid dew point temperature (ADT) on pre-heaters in a reference thermal power plant for two types of fuel, ''fuel No. 2'' and ''low sulphur fuel'' respectively and on the other hand, it shows how a changeover to this latter fuel would increase the useful lifetime of this equipment, reducing this way cost of maintenance due to the considerable decrease in the area exposed to ADT with the subsequent increase in the boiler's performance. (author)

  13. Enhanced heat transfer in confined pool boiling

    Energy Technology Data Exchange (ETDEWEB)

    Rops, C.M. [TNO Science and Industry, P.O. Box 155, 2600 AD Delft (Netherlands)], E-mail: cor.rops@tno.nl; Lindken, R. [Laboratory for Aero and Hydrodynamics, Delft University of Technology (Netherlands); Velthuis, J.F.M. [TNO Science and Industry, P.O. Box 155, 2600 AD Delft (Netherlands); Westerweel, J. [Laboratory for Aero and Hydrodynamics, Delft University of Technology (Netherlands)

    2009-08-15

    We report the results of an experimental investigation of the heat transfer during nucleate boiling on a spatially confined boiling surface. The heat flux as a function of the boiling surface temperature was measured in pool boiling pots with diameters ranging from 15 mm down to 4.5 mm. It was found that a reduction of the pool diameter leads to an enhancement of the nucleate boiling heat flux for most of the boiling curve. Our experimental results indicate that this enhancement is not affected by the depth of the boiling pot, the material of the bounding wall, or the diameter of the inlet water supply. High-speed camera imaging shows that the heat transfer enhancement for the spatially confined pool boiling occurs in conjunction with a stable circulating flow, which is in contrast to the chaotic and mainly upward motion for boiling in larger pool diameters. An explanation for the enhancement of the heat transfer and the associated change in flow pattern is found in the singularisation of the nucleate boiling process.

  14. BOILING WATER REACTOR WITH FEED WATER INJECTION NOZZLES

    Science.gov (United States)

    Treshow, M.

    1963-04-30

    This patent covers the use of injection nozzles for pumping water into the lower ends of reactor fuel tubes in which water is converted directly to steam. Pumping water through fuel tubes of this type of boiling water reactor increases its power. The injection nozzles decrease the size of pump needed, because the pump handles only the water going through the nozzles, additional water being sucked into the tubes by the nozzles independently of the pump from the exterior body of water in which the fuel tubes are immersed. The resulting movement of exterior water along the tubes holds down steam formation, and thus maintains the moderator effectiveness, of the exterior body of water. (AEC)

  15. Self-overcoming of the boiling condition by pressure increment in a water target irradiated by proton beam

    Energy Technology Data Exchange (ETDEWEB)

    Hong, Bong Hwan, E-mail: burnn@kirams.re.kr [Korea Institute of Radiological and Medical Sciences (KIRMAS), 75 Nowon-Gil, Nowon-Gu, Seoul 139-706 (Korea, Republic of); Kang, Joonsun; Jung, In Su; Ram, Han Ga; Park, Yeun Soo [Korea Institute of Radiological and Medical Sciences (KIRMAS), 75 Nowon-Gil, Nowon-Gu, Seoul 139-706 (Korea, Republic of); Cho, Hyung Hee [Department of Mechanical Engineering, Yonsei University, 134 Sinchon-Dong, Seodaemun-Gu, Seoul 120-749 (Korea, Republic of)

    2013-11-11

    An experiment was conducted to examine and visualize the boiling phenomena inside a water target by irradiating it with a proton beam from MC-50 cyclotron. The boiling phenomena were recorded with a CMOS camera. While an increase of the fraction of the water vapor volume is generally considered to be normal when water is boiled by a proton beam, our experiment showed the opposite result. The volume expansion of the liquid water exceeded the compressibility of the initial air volume. A grid structure in front of the entrance window foil held the target volume constant. Therefore, the phenomena inside the target underwent an isochoric process, and the pressure inside the target was increased rapidly beyond the pressure at the boiling point. Consequently, there was no more bulk boiling in the Bragg-peak region in the target water. Our results show that the boiling of the water can be controlled by controlling the equilibrium pressure of the water target.

  16. Fuel performance improvement program. Quarterly progress report, April--June 1978. [LWR

    Energy Technology Data Exchange (ETDEWEB)

    Crouthamel, C.E. (comp.)

    1978-07-01

    The Fuel Performance Improvement Program has as its objective the identification and demonstration of fuel concepts with improved power ramp performance. Improved fuels are being sought to allow reduction or elimination of fuel related operating guidelines on nuclear power plants such that the fuel may be power maneuvered within the rates allowed by the system technical specifications. The program contains a combination of out-of-reactor studies, in-reactor experiments and in-reactor demonstrations. Fuel concepts initially being considered include annular pellets, cladding internally coated with graphite and packed-particle fuels. The performance capability of each concept will be compared to a reference fuel of contemporary pellet design by irradiations in the Halden Boiling Water Reactor. Fuel design and process development is being completed and fuel rod fabrication will begin for the Halden test rods and for the first series of in-reactor experiments. The in-reactor demonstrations are being performed in the Big Rock Point reactor to show that the concepts pose no undue risk to commercial operation. Additional concepts may be considered as the result of a state-of-the-technology review of fuel-cladding interaction and assessment of fuel concepts and the out-of-reactor studies. The results of the program will be used to establish the technical bases for design of fuels with improved power ramp performance.

  17. Nuclear-coupled thermal-hydraulic stability analysis of boiling water reactors

    Science.gov (United States)

    Karve, Atul A.

    We have studied the nuclear-coupled thermal-hydraulic stability of boiling water reactors (BWRs) using a model we developed from: the space-time modal neutron kinetics equations based on spatial omega-modes, the equations for two-phase flow in parallel boiling channels, the fuel rod heat conduction equations, and a simple model for the recirculation loop. The model is represented as a dynamical system comprised of time-dependent nonlinear ordinary differential equations, and it is studied using stability analysis, modern bifurcation theory, and numerical simulations. We first determine the stability boundary (SB) in the most relevant parameter plane, the inlet-subcooling-number/external-pressure-drop plane, for a fixed control rod induced external reactivity equal to the 100% rod line value and then transform the SB to the practical power-flow map. Using this SB, we show that the normal operating point at 100% power is very stable, stability of points on the 100% rod line decreases as the flow rate is reduced, and that points are least stable in the low-flow/high-power region. We also determine the SB when the modal kinetics is replaced by simple point reactor kinetics and show that the first harmonic mode has no significant effect on the SB. Later we carry out the relevant numerical simulations where we first show that the Hopf bifurcation, that occurs as a parameter is varied across the SB is subcritical, and that, in the important low-flow/high-power region, growing oscillations can result following small finite perturbations of stable steady-states on the 100% rod line. Hence, a point on the 100% rod line in the low-flow/high-power region, although stable, may nevertheless be a point at which a BWR should not be operated. Numerical simulations are then done to calculate the decay ratios (DRs) and frequencies of oscillations for various points on the 100% rod line. It is determined that the NRC requirement of DR loop model that we develop is studied by carrying

  18. Gamma heated subassembly for sodium boiling experiments

    Energy Technology Data Exchange (ETDEWEB)

    Artus, S.C.

    1975-01-01

    The design of a system to boil sodium in an LMFBR is examined. This design should be regarded as a first step in a series of boiling experiments. The reactor chosen for the design of the boiling apparatus is the Experimental Breeder Reactor-II (EBR-II), located at the National Reactor Testing Station in Idaho. Criteria broadly classified as design objectives and design requirements are discussed.

  19. Instability in flow boiling in microchannels

    CERN Document Server

    Saha, Sujoy Kumar

    2016-01-01

    This Brief addresses the phenomena of instability in flow boiling in microchannels occurring in high heat flux electronic cooling. A companion edition in the SpringerBrief Subseries on Thermal Engineering and Applied Science to “Critical Heat Flux in Flow Boiling in Microchannels,” and "Heat Transfer and Pressure Drop in Flow Boiling in Microchannels,"by the same author team, this volume is idea for professionals, researchers, and graduate students concerned with electronic cooling.

  20. Nucleate boiling pressure drop in an annulus: Book 5

    Energy Technology Data Exchange (ETDEWEB)

    1992-11-01

    The application of the work described in this report is the production reactors at the Savannah River Site, and the context is nuclear reactor safety. The Loss of Coolant Accident (LOCA) scenario considered involves a double-ended break of a primary coolant pipe in the reactor. During a LOCA, the flow through portions of the reactor may reverse direction or be greatly reduced, depending upon the location of the break. The reduced flow rate of coolant (D{sub 2}O) through the fuel assembly channels of the reactor -- downflow in this situation -- can lead to boiling and to the potential for flow instabilities which may cause some of the fuel assembly channels to overheat and melt. That situation is to be avoided. The experimental approach is to provide a test annulus which simulates geometry, materials, and flow conditions in a Mark-22 fuel assembly (Coolant Channel 3) to the extent possible. The key analysis approaches are: To compare the minima in the measured demand curves with analytical criteria, in particular the Saha-Zuber (1974) model; and to compare the pressure and temperature as a function of length in the annulus with an integral model for flow boiling in a heated channel. Nineteen test series and a total of 178 tests were performed. Testing addressed the effects of: Heat flux; pressure; helium gas; power tilt; ribs; asymmetric heat flux. This document consists solely of the plato file index from 11/87 to 11/90.

  1. Pool Boiling of Hydrocarbon Mixtures on Water

    Energy Technology Data Exchange (ETDEWEB)

    Boee, R.

    1996-09-01

    In maritime transport of liquefied natural gas (LNG) there is a risk of spilling cryogenic liquid onto water. The present doctoral thesis discusses transient boiling experiments in which liquid hydrocarbons were poured onto water and left to boil off. Composition changes during boiling are believed to be connected with the initiation of rapid phase transition in LNG spilled on water. 64 experimental runs were carried out, 14 using pure liquid methane, 36 using methane-ethane, and 14 using methane-propane binary mixtures of different composition. The water surface was open to the atmosphere and covered an area of 200 cm{sup 2} at 25 - 40{sup o}C. The heat flux was obtained by monitoring the change of mass vs time. The void fraction in the boiling layer was measured with a gamma densitometer, and a method for adapting this measurement concept to the case of a boiling cryogenic liquid mixture is suggested. Significant differences in the boil-off characteristics between pure methane and binary mixtures revealed by previous studies are confirmed. Pure methane is in film boiling, whereas the mixtures appear to enter the transitional boiling regime with only small amounts of the second component added. The results indicate that the common assumption that LNG will be in film boiling on water because of the high temperature difference, may be questioned. Comparison with previous work shows that at this small scale the results are influenced by the experimental apparatus and procedures. 66 refs., 76 figs., 28 tabs.

  2. A review on saturated boiling of liquids on tube bundles

    Science.gov (United States)

    Swain, Abhilas; Das, Mihir Kumar

    2014-05-01

    A review of recent investigation on boiling of saturated liquids over plain and enhanced tube bundles has been carried out taking the earlier review works as reference point. The experimental observations of various geometry and performance parameters studied by researchers are analyzed keeping current demand of industries in design and development of compact, efficient heat exchanging devices. The study shows that tube spacing plays an important role in determination of compactness of the heat exchanger.

  3. Effectiveness of Additives in Improving Fuel Lubricity and Preventing Pump Failure at High Temperature

    Science.gov (United States)

    2013-01-01

    Distillation Loss, % 1.5 max 1 0.3 .1 D56 Flash point, °C 38 min 48 42 37 D4052 Density at -15°C, kg/m³ 0.801 0.742 0.769 D2386 Freezing Point, °C...Cert 2007 Diesel D93 Flash Point, °C 52 min 76.6 D2709 Water and Sediment, vol % 0.05 max 0.01 D86 Distillation temp °C Initial boiling point...The transfer pump blades are sintered metal, and likely absorbed fuel to gain weight, or gain weight due to fuel deposition. In addition all fuel

  4. Boiling Heat-Transfer Processes and Their Application in the Cooling of High Heat Flux Devices

    Science.gov (United States)

    1993-06-01

    large for very smooth surfaces or highly wettable fluids (e.g., refrigerants or liquid metals) which can lead to explosive boiling (known as bumping) that...of the high wettability of liquid metals, high superheats are normally required to initiate boiling, in some cases having an explosive transition that...About the same time, Staub and Walmet (Ref. 175) identified the two regions before and after the point of significant vapor generation (SNVG) where the

  5. Mass flow rate sensitivity and uncertainty analysis in natural circulation boiling water reactor core from Monte Carlo simulations

    Energy Technology Data Exchange (ETDEWEB)

    Espinosa-Paredes, Gilberto, E-mail: gepe@xanum.uam.m [Area de Ingenieria en Recursos Energeticos, Universidad Autonoma Metropolitana-Iztapalapa, Av. San Rafael Atlixco, 186, Col. Vicentina, Mexico D.F., 09340 (Mexico); Verma, Surendra P. [Centro de Investigacion en Energia, Universidad Nacional Autonoma de Mexico, Priv. Xochicalco s/no., Col Centro, Apartado Postal 34, Temixco 62580 (Mexico); Vazquez-Rodriguez, Alejandro [Area de Ingenieria en Recursos Energeticos, Universidad Autonoma Metropolitana-Iztapalapa, Av. San Rafael Atlixco, 186, Col. Vicentina, Mexico D.F., 09340 (Mexico); Nunez-Carrera, Alejandro [Comision Nacional de Seguridad Nuclear y Salvaguardias, Doctor Barragan 779, Col. Narvarte, Mexico D.F. 03020 (Mexico)

    2010-05-15

    Our aim was to evaluate the sensitivity and uncertainty of mass flow rate in the core on the performance of natural circulation boiling water reactor (NCBWR). This analysis was carried out through Monte Carlo simulations of sizes up to 40,000, and the size, i.e., repetition of 25,000 was considered as valid for routine applications. A simplified boiling water reactor (SBWR) was used as an application example of Monte Carlo method. The numerical code to simulate the SBWR performance considers a one-dimensional thermo-hydraulics model along with non-equilibrium thermodynamics and non-homogeneous flow approximation, one-dimensional fuel rod heat transfer. The neutron processes were simulated with a point reactor kinetics model with six groups of delayed neutrons. The sensitivity was evaluated in terms of 99% confidence intervals of the mean to understand the range of mean values that may represent the entire statistical population of performance variables. The regression analysis with mass flow rate as the predictor variable showed statistically valid linear correlations for both neutron flux and fuel temperature and quadratic relationship for the void fraction. No statistically valid correlation was observed for the total heat flux as a function of the mass flow rate although heat flux at individual nodes was positively correlated with this variable. These correlations are useful for the study, analysis and design of any NCBWR. The uncertainties were propagated as follows: for 10% change in the mass flow rate in the core, the responses for neutron power, total heat flux, average fuel temperature and average void fraction changed by 8.74%, 7.77%, 2.74% and 0.58%, respectively.

  6. Properties of residual marine fuel produced by thermolysis from polypropylene waste

    Directory of Open Access Journals (Sweden)

    Linas Miknius

    2015-06-01

    Full Text Available Thermal degradation of waste plastics with the aim of producing liquid fuel is one of the alternative solutions to landfill disposal or incineration. The paper describes thermal conversion of polypropylene waste and analysis of produced liquid fuel that would satisfy ISO 8217-2012 requirements for a residual marine fuel. Single pass batch thermolysis processes were conducted at different own vapour pressures (20-80 barg that determined process temperature, residence time of intermediates what resulted in different yields of the liquid product. Obtained products were stabilized by rectification to achieve required standard flash point. Gas chromatography and 1H NMR spectrometry show aliphatic nature of the liquid product where majority of the compounds are isoalkanes and isoalkenes. Only lightest fractions boiling up to a temperature of 72 oC have significant amount of n-pentane. Distribution of aromatic hydrocarbons is not even along the boiling range. The fractions boiling at a temperature of 128 oC and 160 oC have the highest content of monocyclic arenes – 3.16 % and 4.09 % respectively. The obtained final liquid residual product meets all but one requirements of ISO 8217-2012 for residual marine fuels.DOI: http://dx.doi.org/10.5755/j01.ms.21.2.6105

  7. Boiling flow through diverging microchannel

    Indian Academy of Sciences (India)

    V S Duryodhan; S G Singh; Amit Agrawal

    2013-12-01

    An experimental study of flow boiling through diverging microchannel has been carried out in this work, with the aim of understanding boiling in nonuniform cross-section microchannel. Diverging microchannel of 4° of divergence angle and 146 m hydraulic diameter (calculated at mid-length) has been employed for the present study with deionised water as working fluid. Effect of mass flux (118–1182 kg/m2-s) and heat flux (1.6–19.2 W/cm2) on single and two-phase pressure drop and average heat transfer coefficient has been studied. Concurrently, flow visualization is carried out to document the various flow regimes and to correlate the pressure drop and average heat transfer coefficient to the underlying flow regime. Four flow regimes have been identified from the measurements: bubbly, slug, slug–annular and periodic dry-out/rewetting. Variation of pressure drop with heat flux shows one maxima which corresponds to transition from bubbly to slug flow. It is shown that significantly large heat transfer coefficient (up to 107 kW/m2-K) can be attained for such systems, for small pressure drop penalty and with good flow stability.

  8. Investigation of film boiling thermal hydraulics under FCI conditions. Results of a numerical study

    Energy Technology Data Exchange (ETDEWEB)

    Dinh, T.N.; Dinh, A.T.; Nourgaliev, R.R.; Sehgal, B.R. [Div. of Nuclear Power Safety Royal Inst. of Tech. (RIT), Brinellvaegen 60, 10044 Stockholm (Sweden)

    1998-01-01

    Film boiling on the surface of a high-temperature melt jet or of a melt particle is one of key phenomena governing the physics of fuel-coolant interactions (FCIs) which may occur during the course of a severe accident in a light water reactor (LWR). A number of experimental and analytical studies have been performed, in the past, to address film boiling heat transfer and the accompanying hydrodynamic aspects. Most of the experiments have, however, been performed for temperature and heat flux conditions, which are significantly lower than the prototypic conditions. For ex-vessel FCIs, high liquid subcooling can significantly affect the FCI thermal hydraulics. Presently, there are large uncertainties in predicting natural-convection film boiling of subcooled liquids on high-temperature surfaces. In this paper, research conducted at the Division of Nuclear Power Safety, Royal Institute of Technology (RIT/NPS), Stockholm, concerning film-boiling thermal hydraulics under FCI condition is presented. Notably, the focus is placed on the effects of (1) water subcooling, (2) high-temperature steam properties, (3) the radiation heat transfer and (4) mixing zone boiling dynamics, on the vapor film characteristics. Numerical investigations are performed using a novel CFD modeling concept named as the local-homogeneous-slip model (LHSM). Results of the analytical and numerical studies are discussed with respect to boiling dynamics under FCI conditions. (author)

  9. Bubble spreading during the boiling crisis: modelling and experimenting in microgravity

    Science.gov (United States)

    Nikolayev, V.; Beysens, D.; Garrabos, Y.; Lecoutre, C.; Chatain, D.

    2006-09-01

    Boiling is a very efficient way to transfer heat from a heater to the liquid carrier. We discuss the boiling crisis, a transition between two regimes of boiling: nucleate and film boiling. The boiling crisis results in a sharp decrease in the heat transfer rate, which can cause a major accident in industrial heat exchangers. In this communication, we present a physical model of the boiling crisis based on the vapor recoil effect. Under the action of the vapor recoil the gas bubbles begin to spread over the heater thus forming a germ for the vapor film. The vapor recoil force not only causes its spreading, it also creates a strong adhesion to the heater that prevents the bubble departure, thus favoring the further spreading. Near the liquid-gas critical point, the bubble growth is very slow and allows the kinetics of the bubble spreading to be observed. Since the surface tension is very small in this regime, only microgravity conditions can preserve a convex bubble shape. In the experiments both in the Mir space station and in the magnetic levitation facility, we directly observed an increase of the apparent contact angle and spreading of the dry spot under the bubble. Numerical simulations of the thermally controlled bubble growth show this vapor recoil effect too thus confirming our model of the boiling crisis.

  10. Criticality in the slowed-down boiling crisis at zero gravity.

    Science.gov (United States)

    Charignon, T; Lloveras, P; Chatain, D; Truskinovsky, L; Vives, E; Beysens, D; Nikolayev, V S

    2015-05-01

    Boiling crisis is a transition between nucleate and film boiling. It occurs at a threshold value of the heat flux from the heater called CHF (critical heat flux). Usually, boiling crisis studies are hindered by the high CHF and short transition duration (below 1 ms). Here we report on experiments in hydrogen near its liquid-vapor critical point, in which the CHF is low and the dynamics slow enough to be resolved. As under such conditions the surface tension is very small, the experiments are carried out in the reduced gravity to preserve the conventional bubble geometry. Weightlessness is created artificially in two-phase hydrogen by compensating gravity with magnetic forces. We were able to reveal the fractal structure of the contour of the percolating cluster of the dry areas at the heater that precedes the boiling crisis. We provide a direct statistical analysis of dry spot areas that confirms the boiling crisis at zero gravity as a scale-free phenomenon. It was observed that, in agreement with theoretical predictions, saturated boiling CHF tends to zero (within the precision of our thermal control system) in zero gravity, which suggests that the boiling crisis may be observed at any heat flux provided the experiment lasts long enough.

  11. Transient boiling heat transfer in saturated liquid nitrogen and F113 at standard and zero gravity

    Science.gov (United States)

    Oker, E.; Merte, H., Jr.

    1973-01-01

    Transient and steady state nucleate boiling in saturated LN2 and F113 at standard and near zero gravity conditions were investigated for the horizontal up, vertical and horizontal down orientations of the heating surface. Two distinct regimes of heat transfer mechanisms were observed during the interval from the step increase of power input to the onset of nucleate boiling: the conduction and convection dominated regimes. The time duration in each regime was considerably shorter with LN2 than with F113, and decreased as heat flux increased, as gravity was reduced, and as the orientation was changed from horizontal up to horizontal down. In transient boiling, boiling initiates at a single point following the step increase in power, and then spreads over the surface. The delay time for the inception of boiling at the first site, and the velocity of spread of boiling varies depending upon the heat flux, orientation, body force, surface roughness and liquid properties, and are a consequence of changes in boundary layer temperature levels associated with changes in natural convection. Following the step increase in power input, surface temperature overshoot and undershoot occur before the steady state boiling temperature level is established.

  12. Transient boiling crisis of cryogenic liquids

    NARCIS (Netherlands)

    Deev, [No Value; Kharitonov, VS; Kutsenko, KV; Lavrukhin, AA

    2004-01-01

    This paper introduces a new physical model of boiling crisis under rapid increase of power on the heated surface. The calculation of the time interval of the transition to film boiling in cryogenic liquids was carried out depending on heat flux and pressure. The obtained results are in good

  13. Transient boiling crisis of cryogenic liquids

    NARCIS (Netherlands)

    Deev, [No Value; Kharitonov, VS; Kutsenko, KV; Lavrukhin, AA

    2004-01-01

    This paper introduces a new physical model of boiling crisis under rapid increase of power on the heated surface. The calculation of the time interval of the transition to film boiling in cryogenic liquids was carried out depending on heat flux and pressure. The obtained results are in good agreemen

  14. Boiling turbulent Rayleigh-Bénard convection

    NARCIS (Netherlands)

    Lakkaraju, R.

    2013-01-01

    A fundamental understanding of liquid-vapor phase transitions, mainly boiling phenomenon, is essential due to its omnipresence in science and technology. In industries, many empirical correlations exist on the heat transport to get an optimized and efficient thermal design of the boiling equipment.

  15. Boiling turbulent Rayleigh-Bénard convection

    NARCIS (Netherlands)

    Lakkaraju, R.

    2013-01-01

    A fundamental understanding of liquid-vapor phase transitions, mainly boiling phenomenon, is essential due to its omnipresence in science and technology. In industries, many empirical correlations exist on the heat transport to get an optimized and efficient thermal design of the boiling equipment.

  16. Enhanced convective and film boiling heat transfer by surface gas injection

    Energy Technology Data Exchange (ETDEWEB)

    Duignan, M.R.; Greene, G.A. (Brookhaven National Lab., Upton, NY (United States)); Irvine, T.F., Jr. (State Univ. of New York, Stony Brook, NY (United States). Dept. of Mechanical Engineering)

    1992-04-01

    Heat transfer measurements were made for stable film boiling of water over a horizontal, flat stainless steel plate from the minimum film boiling point temperature, T{sub SURFACE} {approximately}500K, to T{sub SURFACE} {approximately}950K. The pressure at the plate was approximately 1 atmosphere and the temperature of the water pool was maintained at saturation. The data were compared to the Berenson film-boiling model, which was developed for minimum film-boiling-point conditions. The model accurately represented the data near the minimum film-boiling point and at the highest temperatures measured, as long it was corrected for the heat transferred by radiation. On the average, the experimental data lay within {plus minus}7% of the model. Measurements of heat transfer were made without film boiling for nitrogen jetting into an overlying pool of water from nine 1-mm- diameter holes, drilled in the heat transfer plate. The heat flux was maintained constant at approximately 26.4 kW/m{sup 2}. For water-pool heights of less than 6cm the heat transfer coefficient deceased linearly with a decrease in heights. Above 6cm the heat transfer coefficient was unaffected. For the entire range of gas velocities measured (0 to 8.5 cm/s), the magnitude of the magnitude of the heat transfer coefficient only changed by approximately 20%. The heat transfer data bound the Konsetov model for turbulent pool heat transfer which was developed for vertical heat transfer surfaces. This agreement suggests that surface orientation may not be important when the gas jets do not locally affect the surface heat transfer. Finally, a database was developed for heat transfer from the plate with both film boiling and gas jetting occurring simultaneously, in a pool of water maintained at its saturation temperature. The effect of passing nitrogen through established film boiling is to increase the heat transfer from that surface. 60 refs.

  17. Enhanced convective and film boiling heat transfer by surface gas injection

    Energy Technology Data Exchange (ETDEWEB)

    Duignan, M.R.; Greene, G.A. [Brookhaven National Lab., Upton, NY (United States); Irvine, T.F., Jr. [State Univ. of New York, Stony Brook, NY (United States). Dept. of Mechanical Engineering

    1992-04-01

    Heat transfer measurements were made for stable film boiling of water over a horizontal, flat stainless steel plate from the minimum film boiling point temperature, T{sub SURFACE} {approximately}500K, to T{sub SURFACE} {approximately}950K. The pressure at the plate was approximately 1 atmosphere and the temperature of the water pool was maintained at saturation. The data were compared to the Berenson film-boiling model, which was developed for minimum film-boiling-point conditions. The model accurately represented the data near the minimum film-boiling point and at the highest temperatures measured, as long it was corrected for the heat transferred by radiation. On the average, the experimental data lay within {plus_minus}7% of the model. Measurements of heat transfer were made without film boiling for nitrogen jetting into an overlying pool of water from nine 1-mm- diameter holes, drilled in the heat transfer plate. The heat flux was maintained constant at approximately 26.4 kW/m{sup 2}. For water-pool heights of less than 6cm the heat transfer coefficient deceased linearly with a decrease in heights. Above 6cm the heat transfer coefficient was unaffected. For the entire range of gas velocities measured [0 to 8.5 cm/s], the magnitude of the magnitude of the heat transfer coefficient only changed by approximately 20%. The heat transfer data bound the Konsetov model for turbulent pool heat transfer which was developed for vertical heat transfer surfaces. This agreement suggests that surface orientation may not be important when the gas jets do not locally affect the surface heat transfer. Finally, a database was developed for heat transfer from the plate with both film boiling and gas jetting occurring simultaneously, in a pool of water maintained at its saturation temperature. The effect of passing nitrogen through established film boiling is to increase the heat transfer from that surface. 60 refs.

  18. Boiling as Household Water Treatment in Cambodia: A Longitudinal Study of Boiling Practice and Microbiological Effectiveness

    Science.gov (United States)

    Brown, Joseph; Sobsey, Mark D.

    2012-01-01

    This paper focuses on the consistency of use and microbiological effectiveness of boiling as it is practiced in one study site in peri-urban Cambodia. We followed 60 randomly selected households in Kandal Province over 6 months to collect longitudinal data on water boiling practices and effectiveness in reducing Escherichia coli in household drinking water. Despite > 90% of households reporting that they used boiling as a means of drinking water treatment, an average of only 31% of households had boiled water on hand at follow-up visits, suggesting that actual use may be lower than self-reported use. We collected 369 matched untreated and boiled water samples. Mean reduction of E. coli was 98.5%; 162 samples (44%) of boiled samples were free of E. coli (boiled water in a covered container was associated with safer product water than storage in an uncovered container. PMID:22826487

  19. Buoyancy-driven flow excursions in fuel assemblies

    Energy Technology Data Exchange (ETDEWEB)

    Laurinat, J.E.; Paul, P.K.; Menna, J.D.

    1995-12-31

    A power limit criterion was developed for a postulated Loss of Pumping Accident (LOPA) in one of the recently shut down heavy water production reactors at the Savannah River Site. These reactors were cooled by recirculating moderator downward through channels in cylindrical fuel tubes. Powers were limited to prevent a flow excursion from occurring in one or more of these parallel channels. During full-power operation, limits prevented a boiling flow excursion from taking place. At low flow rates, during the addition of emergency cooling water, buoyant forces reverse the flow in one of the coolant channels before boiling occurs. As power increases beyond the point of flow reversal, the maximum wall temperature approaches the fluid saturation temperature, and a thermal excursion occurs. The power limit criterion for low flow rates was the onset of flow reversal. To determine conditions for flow reversal, tests were performed in a mock-up of a fuel assembly that contained two electrically heated concentric tubes surrounded by three flow channels. These tests were modeled using a finite difference thermal-hydraulic code. According to code calculations, flow reversed in the outer flow channel before the maximum wall temperature reached the local fluid saturation temperature. Thermal excursions occurred when the maximum wall temperature approximately equaled the saturation temperature. For a postulated LOPA, the flow reversal criterion for emergency cooling water addition was more limiting than the boiling excursion criterion for full power operation. This criterion limited powers to 37% of historical levels.

  20. Buoyancy-driven flow excursions in fuel assemblies

    Energy Technology Data Exchange (ETDEWEB)

    Laurinat, J.E.; Paul, P.K.; Menna, J.D. [Westinghouse Savannah River Company, Aiken, SC (United States)

    1995-09-01

    A power limit criterion was developed for a postulated Loss of Pumping Accident (LOPA) in one of the recently shut down heavy water production reactors at the Savannah River Site. These reactors were cooled by recirculating heavy water moderator downward through channels in cylindrical fuel tubes. Powers were limited to safeguard against a flow excursion in one of more of these parallel channels. During-full-power operation, limits safeguarded against a boiling flow excursion. At low flow rates, during the addition of emergency cooling water, buoyant forces reverse the flow in one of the coolant channels before boiling occurs. As power increased beyond the point of flow reversal, the maximum wall temperature approaches the fluid saturation temperature, and a thermal excursion occurs. The power limit criterion for low flow rates was the onset of flow reversal. To determine conditions for flow reversal, tests were performed in a mock-up of a fuel assembly that contained two electrically heated concentric tubes surrounded by three flow channels. These tests were modeled using a finite difference thermal-hydraulic code. According to code calculations, flow reversed in the outer flow channel before the maximum wall temperature reached the local fluid saturation temperature. Thermal excursions occurred when the maximum wall temperature approximately equaled the saturation temperature. For a postulated LOPA, the flow reversal criterion for emergency cooling water addition was more limiting than the boiling excursion criterion for full power operation. This criterion limited powers to 37% of the limiting power for previous long-term reactor operations.

  1. Starting Point, Keys and Milestones of a Computer Code for the Simulation of the Behaviour of a Nuclear Fuel Rod

    Directory of Open Access Journals (Sweden)

    Armando C. Marino

    2011-01-01

    Full Text Available The BaCo code (“Barra Combustible” was developed at the Atomic Energy National Commission of Argentina (CNEA for the simulation of nuclear fuel rod behaviour under irradiation conditions. We present in this paper a brief description of the code and the strategy used for the development, improvement, enhancement, and validation of a BaCo during the last 30 years. “Extreme case analysis”, parametric (or sensitivity, probabilistic (or statistic analysis plus the analysis of the fuel performance (full core analysis are the tools developed in the structure of BaCo in order to improve the understanding of the burnup extension in the Atucha I NPP, and the design of advanced fuel elements as CARA and CAREM. The 3D additional tools of BaCo can enhance the understanding of the fuel rod behaviour, the fuel design, and the safety margins. The modular structure of the BaCo code and its detailed coupling of thermo-mechanical and irradiation-induced phenomena make it a powerful tool for the prediction of the influence of material properties on the fuel rod performance and integrity.

  2. Boiling crisis as inhibition of bubble detachment by the vapor recoil force

    CERN Document Server

    Nikolayev, Vadim; Garrabos, Yves

    2016-01-01

    Boiling crisis is a transition between nucleate and film boiling. In this communication we present a physical model of the boiling crisis based on the vapor recoil effect. Our numerical simulations of the thermally controlled bubble growth at high heat fluxes show how the bubble begins to spread over the heater thus forming a germ for the vapor film. The vapor recoil force not only causes the vapor spreading, it also creates a strong adhesion to the heater that prevents the bubble departure, thus favoring the further bubble spreading. Near the liquid-gas critical point, the bubble growth is very slow and allows the kinetics of the bubble spreading to be observed. Since the surface tension is very small in this regime, only microgravity conditions can preserve a convex bubble shape. Under such conditions, we observed an increase of the apparent contact angle and spreading of the dry spot under the bubble, thus confirming our model of the boiling crisis.

  3. Heat Transfer in Nucleate Pool Boiling of Binary and Ternary Refrigerant Mixtures

    Institute of Scientific and Technical Information of China (English)

    赵耀华; 刁彦华; 鹤田隆治; 西川日出男

    2004-01-01

    Heat transfer coefficients in nucleate pool boiling were measured on a horizontal copper surface for refrigerants, HFC-134a, HFC-32, and HFC-125, their binary and ternary mixtures under saturated conditions at 0.9MPa. Compared to pure components, both binary and ternary mixtures showed lower heat transfer coefficients.This deterioration was more pronounced as heat flux was increased. Experimental data were compared with some empirical and semi-empirical correlations available in literature. For binary mixture, the accuracy of the correlations varied considerably with mixtures and the heat flux. Experimental data for HFC-32/134a/125 were also compared with available correlated equation obtained by Thome. For ternary mixture, the boiling range of binary mixture composed by the pure fluids with the lowest and the medium boiling points, and their concentration difference had important effects on boiling heat transfer coefficients.

  4. Fuel distribution

    Energy Technology Data Exchange (ETDEWEB)

    Tison, R.R.; Baker, N.R.; Blazek, C.F.

    1979-07-01

    Distribution of fuel is considered from a supply point to the secondary conversion sites and ultimate end users. All distribution is intracity with the maximum distance between the supply point and end-use site generally considered to be 15 mi. The fuels discussed are: coal or coal-like solids, methanol, No. 2 fuel oil, No. 6 fuel oil, high-Btu gas, medium-Btu gas, and low-Btu gas. Although the fuel state, i.e., gas, liquid, etc., can have a major impact on the distribution system, the source of these fuels (e.g., naturally-occurring or coal-derived) does not. Single-source, single-termination point and single-source, multi-termination point systems for liquid, gaseous, and solid fuel distribution are considered. Transport modes and the fuels associated with each mode are: by truck - coal, methanol, No. 2 fuel oil, and No. 6 fuel oil; and by pipeline - coal, methane, No. 2 fuel oil, No. 6 oil, high-Btu gas, medium-Btu gas, and low-Btu gas. Data provided for each distribution system include component makeup and initial costs.

  5. Multiphysics modeling of two-phase film boiling within porous corrosion deposits

    Energy Technology Data Exchange (ETDEWEB)

    Jin, Miaomiao, E-mail: mmjin@mit.edu; Short, Michael, E-mail: hereiam@mit.edu

    2016-07-01

    Porous corrosion deposits on nuclear fuel cladding, known as CRUD, can cause multiple operational problems in light water reactors (LWRs). CRUD can cause accelerated corrosion of the fuel cladding, increase radiation fields and hence greater exposure risk to plant workers once activated, and induce a downward axial power shift causing an imbalance in core power distribution. In order to facilitate a better understanding of CRUD's effects, such as localized high cladding surface temperatures related to accelerated corrosion rates, we describe an improved, fully-coupled, multiphysics model to simulate heat transfer, chemical reactions and transport, and two-phase fluid flow within these deposits. Our new model features a reformed assumption of 2D, two-phase film boiling within the CRUD, correcting earlier models' assumptions of single-phase coolant flow with wick boiling under high heat fluxes. This model helps to better explain observed experimental values of the effective CRUD thermal conductivity. Finally, we propose a more complete set of boiling regimes, or a more detailed mechanism, to explain recent CRUD deposition experiments by suggesting the new concept of double dryout specifically in thick porous media with boiling chimneys. - Highlights: • A two-phase model of CRUD's effects on fuel cladding is developed and improved. • This model eliminates the formerly erroneous assumption of wick boiling. • Higher fuel cladding temperatures are predicted when accounting for two-phase flow. • Double-peaks in thermal conductivity vs. heat flux in experiments are explained. • A “double dryout” mechanism in CRUD is proposed based on the model and experiments.

  6. Pressure gradients and boiling as mechanisms for localizing ore in porphyry systems

    Science.gov (United States)

    Cunningham, Charles G.

    1978-01-01

    Fluid inclusions in ore zones of porphyry systems indicate that extensive boiling of hydrothermal fluids accompanies deposition of ore and gangue minerals. The boiling commonly accompanied a change from a lithostatic to a hydrostatic environment during evolution of an epizonal stock. Pressure gradients near the margin of the stock can determine whether ore or only a diffuse zone of mineralization is formed. A sharp drop in pressure in an epizonal environment is more likely to cause extensive boiling than a comparable change in a deeper environment, as the slope of the boiling curve steepens with an increase 'in pressure. The drop in pressure causes the hydrothermal fluids to boil and creates a crackle (stockwork) breccia, which hosts the veinlets of gangue quartz and ore minerals. The boiling selectively partitions CO2, H2S, and HCl into the vapor phase, changing the pH, composition, ionic strength, and thus the solubility product of metal complexes in the remaining liquid and causing the ore and gangue to come out of solution. Fluid inclusions trapped from boiling solutions can exhibit several forms, depending on the physical and chemical conditions of the hydrothermal fluid from which they were trapped. In one case, inclusions when heated can homogenize to either liquid or vapor at the same temperature, which is the true boiling temperature. In another case, homogenization of various inclusions can occur through a range of temperatures. The latter case results from the trapping of mixture of liquid and vapor. Variations in salinity can result from boiling of the hydrothermal fluid, or intermittent incorporation of high-salinity fluids from the magma, or trapping of fluids of varying densities at pressure-temperature conditions above the critical point of the fluid. In places, paleopressure-temperature transition zones can be recognized by fluid-inclusion homogenization temperatures and phase relationships and by the presence of anhydrite daughter minerals

  7. Zero Boil Off Cryogen Storage for Future Launchers

    Science.gov (United States)

    Valentian, D.; Plachta, D.; Kittel, P.; Hastings, L. J.; Salerno, Louis J.; Arnold, James O. (Technical Monitor)

    2001-01-01

    Zero boil off (ZBO) cryogen storage using both cryocoolers and passive insulation technologies will enable long-term exploration missions by allowing designers to optimize tankage without the need for excess cryogen storage to account for boil off. Studies of ZBO (zero boil off) have been on-going in the USA for several years. More recently, a review of the needs of advanced space propulsion took place in Europe. This showed the interest of the European community in cryogenic propulsion for planetary missions as well as the use of liquid hydrogen for large power electric propulsion (manned Mars missions). Although natural boiling could be acceptable for single leg missions, passive insulation techniques yield roughly a I% per month cryogen loss and this would not be cost effective for robotic planetary missions involving storage times greater than one year. To make economic sense, long-term exploration missions require lower tank capacity and longer storage times. Recent advances in cryocooler technology, resulting in vast improvements in both cooler efficiency and reliability, make ZBO is a clear choice for planetary exploration missions. Other, more near term applications of ZBO include boil-off reduction or elimination applied to first and upper stages of future earth-to-orbit (ETO) launchers. This would extend launch windows and reduce infrastructure costs. Successors to vehicles like Ariane 5 could greatly benefit by implementing ZBO. Zero Boil Off will only be successful in ETO launcher applications if it makes economic sense to implement. The energy cost is only a fraction of the total cost of buying liquid cryogen, the rest being transportation and other overhead. Because of this, higher boiling point cryogens will benefit more from on-board liquefaction, thus reducing the infrastructure costs. Since hydrogen requires a liquefier with at least a 17% efficiency just to break even from a cost standpoint, one approach for implementing ZBO in upper stages would

  8. Boiling Heat Transfer to Halogenated Hydrocarbon Refrigerants

    Science.gov (United States)

    Yoshida, Suguru; Fujita, Yasunobu

    The current state of knowledge on heat transfer to boiling refrigerants (halogenated hydrocarbons) in a pool and flowing inside a horizontal tube is reviewed with an emphasis on information relevant to the design of refrigerant evaporators, and some recommendations are made for future research. The review covers two-phase flow pattern, heat transfer characteristics, correlation of heat transfer coefficient, influence of oil, heat transfer augmentation, boiling from tube-bundle, influence of return bend, burnout heat flux, film boiling, dryout and post-dryout heat transfer.

  9. Boiling of an emulsion in a yield stress fluid

    Science.gov (United States)

    Guéna, Geoffroy; Wang, Ji; D'Espinose, Jean-Baptiste; Lequeux, François; Talini, Laurence

    2010-11-01

    We report the boiling behavior of pentane emulsified in a yield stress fluid, a colloidal clay (Laponite) suspension. We have observed that a superheated state is easily reached: the emulsion, heated more than 50°C above the alkane boiling point, does not boil. Superheating is made possible by the suppression of heterogeneous nucleation in pentane, resulting from the emulsification process, a phenomenon evidenced decades ago in studies of the superheating of two phase fluids. We have furthermore studied the growth of isolated bubbles nucleated in the emulsion. The rate of increase of the bubble radius with time depends on both the temperature and emulsion volume fraction but, rather unexpectedly, does not depend on the fluid rheology. We show that the bubbles grow by diffusion of the alkane through the aqueous phase between liquid droplets and bubbles, analogously to an Ostwald ripening process. The peculiarity of the process reported here is that a layer depleted in oil droplets forms around the bubble, layer to which the alkane concentration gradient is confined. We successfully describe our experimental results with a simple transfer model.

  10. Boiling and quenching heat transfer advancement by nanoscale surface modification.

    Science.gov (United States)

    Hu, Hong; Xu, Cheng; Zhao, Yang; Ziegler, Kirk J; Chung, J N

    2017-07-21

    All power production, refrigeration, and advanced electronic systems depend on efficient heat transfer mechanisms for achieving high power density and best system efficiency. Breakthrough advancement in boiling and quenching phase-change heat transfer processes by nanoscale surface texturing can lead to higher energy transfer efficiencies, substantial energy savings, and global reduction in greenhouse gas emissions. This paper reports breakthrough advancements on both fronts of boiling and quenching. The critical heat flux (CHF) in boiling and the Leidenfrost point temperature (LPT) in quenching are the bottlenecks to the heat transfer advancements. As compared to a conventional aluminum surface, the current research reports a substantial enhancement of the CHF by 112% and an increase of the LPT by 40 K using an aluminum surface with anodized aluminum oxide (AAO) nanoporous texture finish. These heat transfer enhancements imply that the power density would increase by more than 100% and the quenching efficiency would be raised by 33%. A theory that links the nucleation potential of the surface to heat transfer rates has been developed and it successfully explains the current finding by revealing that the heat transfer modification and enhancement are mainly attributed to the superhydrophilic surface property and excessive nanoscale nucleation sites created by the nanoporous surface.

  11. 21 CFR 872.6710 - Boiling water sterilizer.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Boiling water sterilizer. 872.6710 Section 872...) MEDICAL DEVICES DENTAL DEVICES Miscellaneous Devices § 872.6710 Boiling water sterilizer. (a) Identification. A boiling water sterilizer is an AC-powered device that consists of a container for boiling water...

  12. Boiling significantly promotes photodegradation of perfluorooctane sulfonate.

    Science.gov (United States)

    Lyu, Xian-Jin; Li, Wen-Wei; Lam, Paul K S; Yu, Han-Qing

    2015-11-01

    The application of photochemical processes for perfluorooctane sulfonate (PFOS) degradation has been limited by a low treatment efficiency. This study reports a significant acceleration of PFOS photodegradation under boiling condition compared with the non-boiling control. The PFOS decomposition rate increased with the increasing boiling intensity, but declined at a higher hydronium level or under oxygenation. These results suggest that the boiling state of solution resulted in higher effective concentrations of reactants at the gas-liquid interface and enhanced the interfacial mass transfer, thereby accelerating the PFOS decomposition. This study broadens our knowledge of PFOS photodegradation process and may have implications for development of efficient photodegradation technologies. Copyright © 2015 Elsevier Ltd. All rights reserved.

  13. Effect of Running Parameters on Flow Boiling Instabilities in Microchannels.

    Science.gov (United States)

    Zong, Lu-Xiang; Xu, Jin-Liang; Liu, Guo-Hua

    2015-04-01

    Flow boiling instability (FBI) in microchannels is undesirable because they can induce the mechanical vibrations and disturb the heat transfer characteristics. In this study, the synchronous optical visualization experimental system was set up. The pure acetone liquid was used as the working fluid, and the parallel triangle silicon microchannel heat sink was designed as the experimental section. With the heat flux ranging from 0-450 kW/m2 the microchannel demand average pressure drop-heater length (Δp(ave)L) curve for constant low mass flux, and the demand pressure drop-mass flux (Δp(ave)G) curve for constant length on main heater surface were obtained and studied. The effect of heat flux (q = 188.28, 256.00, and 299.87 kW/m2), length of main heater surface (L = 4.5, 6.25, and 8.00 mm), and mass flux (G = 188.97, 283.45, and 377.94 kg/m2s) on pressure drops (Ap) and temperatures at the central point of the main heater surface (Twc) were experimentally studied. The results showed that, heat flux, length of the main heater surface, and mass flux were identified as the important parameters to the boiling instability process. The boiling incipience (TBI) and critical heat flux (CHF) were early induced for the lower mass flux or the main heater surface with longer length. With heat flux increasing, the pressure drops were linearly and slightly decreased in the single liquid region but increased sharply in the two phase flow region, in which the flow boiling instabilities with apparent amplitude and long period were more easily triggered at high heat flux. Moreover, the system pressure was increased with the increase of the heat flux.

  14. How To Boil the Perfect Egg

    Institute of Scientific and Technical Information of China (English)

    小雨

    2007-01-01

    A British inventor says he has cracked(破解)the age-old riddle(难题)of how to boil the perfect egg,get rid of(摆脱)the water. Simon Rhymes uses powerful light bulbs instead of boiling water to cook the egg. The gadget(小发明)does the job in six minutes,and then chons off(削)the top of

  15. Using Boiling for Treating Waste Activated Sludge

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    In this work we investigated the feasibility of using short time, low superheat boiling to treat biological sludge. The treated sludge exhibited reduced filterability and enhanced settleability. The boiling treatment released a large amount of extra-cellular polymers (ECPs) from the solid phase and reduced the microbial density levels of the total coliform bacteria and the heterotrophic bacteria. A diluted sludge is preferable for its high degree of organic hydrolysis and sufficient reduction in microbial density levels.

  16. The investigation of boiling crisis of nanofluids

    Directory of Open Access Journals (Sweden)

    Minakov Andrey

    2016-01-01

    Full Text Available Saturated boiling of nanofluids on a cylindrical heater with different diameters is experimentally studied. Studied nanofluids were prepared using distilled water and different metal oxides nanoparticles. The volume concentration of the nanoparticles was changed from 0.05 to 1%. It has been measured that the critical heat flux for nanofluids was much higher than for water. A strong dependence of CHF on the material and size of the nanoparticles and duration of boiling and size of heater was shown.

  17. Burnout in subcooled flow boiling of water. A visual experimental study

    Energy Technology Data Exchange (ETDEWEB)

    Celata, G.P.; Mariani, A.; Zummo, G. [ENEA, Engineering Div., National Institute of Thermal Fluid-Dynamics, Rome (Italy); Cumo, M. [University of Rome la Sapienza, Rome (Italy)

    2000-12-01

    The objective of the present work is to perform a photographic study of the burnout in highly subcooled flow boiling, in order to provide a qualitative description of the flow pattern under different conditions of boiling regime: ONB (onset of nucleate boiling), subcooled flow boiling and thermal crisis. In particular, the flow visualisation is focused on the phenomena occurring on the heated wall during the thermal crisis up to the physical burnout of the heater. Vapour bubble parameters are measured from flow images recorded, while the wall temperature is measured with an indirect method, by recording the heater elongation during all flow regimes studied. The combination of bubble parameters and wall temperature measurements as well as direct observations of the flow pattern, for all flow regimes, are collected in graphs which provide a useful global point of view of boiling phenomena, especially during boiling crisis. Under these conditions, a detailed analysis of the mechanisms leading to the critical heat flux is reported, and the so called events sequence, from thermal crisis occurrence up to heater burnout, is illustrated. (authors)

  18. Bubble spreading during the boiling crisis: modelling and experimenting in microgravity

    CERN Document Server

    Nikolayev, Vadim; Garrabos, Y; Lecoutre, C; Chatain, D

    2016-01-01

    Boiling is a very efficient way to transfer heat from a heater to the liquid carrier. We discuss the boiling crisis, a transition between two regimes of boiling: nucleate and film boiling. The boiling crisis results in a sharp decrease in the heat transfer rate, which can cause a major accident in industrial heat exchangers. In this communication, we present a physical model of the boiling crisis based on the vapor recoil effect. Under the action of the vapor recoil the gas bubbles begin to spread over the heater thus forming a germ for the vapor film. The vapor recoil force not only causes its spreading, it also creates a strong adhesion to the heater that prevents the bubble departure, thus favoring the further spreading. Near the liquid-gas critical point, the bubble growth is very slow and allows the kinetics of the bubble spreading to be observed. Since the surface tension is very small in this regime, only microgravity conditions can preserve a convex bubble shape. In the experiments both in the Mir spa...

  19. Overview and Computational Approach for Studying the Physicochemical Characterization of High-Boiling-Point Petroleum Fractions (350°C+ Approche informatique pour l’étude des propriétés physico-chimiques de fraction pétrolière lourde (350°C+

    Directory of Open Access Journals (Sweden)

    Plazas Tovar L.

    2012-06-01

    Full Text Available The processing and upgrading of high-boilingpoint petroleum fractions, containing a large number of components from different groups (paraffins, olefins, naphthenes, aromatics require an in-depth evaluation. In order to characterize them, their thermodynamic and thermophysical properties must be determined. This work presents a computational approach based on the breakdown of the petroleum fraction into pseudocomponents defined by a trial-and-error exercise in which the mass- and molar-balance errors were minimized. Cases studies are illustrated to three heavy residues 400°C+ from “W, Y and Z” crude oil. This procedure requires the boiling point distillation curve and the density of the whole fraction as the input bulk properties. The methods proposed according to available correlations in the literature and standard industrial methods were mainly used to estimate properties that include the basic properties (normal boiling point, density and Watson factor characterization, the thermodynamic properties (molar mass and critical properties and the thermophysical and transport properties (kinematic viscosity, thermal conductivity, specific heat capacity and vapor pressure. The methodology developed has shown to be a useful tool for calculating a remarkably broad range of physicochemical properties of high-boiling-point petroleum fractions with good accuracy when the bulk properties are available, since computational approach gave an overall absolute deviation lower than 10% when compared with the experimental results obtained in the research laboratories LDPS/LOPCA/UNICAMP. Le traitement et la valorisation des fractions pétrolières lourdes nécessitent une étude très détaillée dans la mesure où le pétrole contient un très grand nombre de composants différents (paraffines, oléfines, naphtènes, arômes. Afin de caractériser les fractions, il est indispensable de déterminer les propriétés thermodynamiques et thermophysiques des

  20. Nucleate boiling pressure drop in an annulus: Book 3

    Energy Technology Data Exchange (ETDEWEB)

    Block, J.A.; Crowley, C.; Dolan, F.X.; Sam, R.G.; Stoedefalke, B.H.

    1992-11-01

    The application of the work described in this report is the production reactors at the Savannah River Site, and the context is nuclear reactor safety. The Loss of Coolant Accident (LOCA) scenario considered involves a double-ended break of a primary coolant pipe in the reactor. During a LOCA, the flow through portions of the reactor may reverse direction or be greatly reduced, depending upon the location of the break. The reduced flow rate of coolant (D{sub 2}O) through the fuel assembly channels of the reactor -- downflow in this situation -- can lead to boiling and to the potential for flow instabilities which may cause some of the fuel assembly channels to overheat and melt. That situation is to be avoided. The experimental approach is to provide a test annulus which simulates geometry, materials, and flow conditions in a Mark-22 fuel assembly (Coolant Channel 3) to the extent possible. The annulus has a full-scale geometry, and in fat uses SRL dummy hardware for the inner annulus wall in the ribbed geometry. The materials aluminum. The annulus is uniformly heated in the axial direction, but the circumferential heat flux can be varied to provide ``power tilt`` or asymmetric heating of the inner and outer annulus walls. The test facility uses H{sub 2}O rather than D{sub 2}O, but it includes the effects of dissolved helium gas present in the reactor. The key analysis approaches are: To compare the minima in the measured demand curves with analytical criteria, in particular the Saha-Zuber (1974) model; and to compare the pressure and temperature as a function of length in the annulus with an integral model for flow boiling in a heated channel. This document consists of data plots and summary files of temperature measurements.

  1. Nucleate boiling pressure drop in an annulus: Book 6

    Energy Technology Data Exchange (ETDEWEB)

    1992-11-01

    The application of the work described in this report is the production reactors at the Savannah River Site, and the context is nuclear reactor safety. The Loss of Coolant Accident (LOCA) scenario considered involves a double-ended break of a primary coolant pipe in the reactor. During a LOCA, the flow through portions of the reactor may reverse direction or be greatly reduced, depending upon the location of the break. The reduced flow rate of coolant (D{sub 2}O) through the fuel assembly channels of the reactor -- downflow in this situation -- can lead to boiling and to the potential for flow instabilities which may cause some of the fuel assembly channels to overheat and melt. That situation is to be avoided. The experimental approach is to provide a test annulus which simulates geometry, materials, and flow conditions in a Mark-22 fuel assembly (Coolant Channel 3) to the extent possible. The annulus has a full-scale geometry, and in fat uses SRL dummy hardware for the inner annulus wall in the ribbed geometry. The materials aluminum. The annulus is uniformly heated in the axial direction, but the circumferential heat flux can be varied to provide ``power tilt`` or asymmetric heating of the inner and outer annulus walls. The test facility uses H{sub 2}O rather than D{sub 2}O, but it includes the effects of dissolved helium gas present in the reactor. The key analysis approaches are: To compare the minima in the measured demand curves with analytical criteria, in particular the Saha-Zuber (1974) model; and to compare the pressure and temperature as a function of length in the annulus with an integral model for flow boiling in a heated channel. This document consists of a summary of temperature measurements to include recorded minima, maxima, averages and standard deviations.

  2. Nucleate boiling pressure drop in an annulus: Book 4

    Energy Technology Data Exchange (ETDEWEB)

    Block, J.A.; Crowley, C.; Dolan, F.X.; Sam, R.G.; Stoedefalke, B.H.

    1992-11-01

    The application of the work described in this report is the production reactors at the Savannah River Site, and the context is nuclear reactor safety. The Loss of Coolant Accident (LOCA) scenario considered involves a double-ended break of a primary coolant pipe in the reactor. During a LOCA, the flow through portions of the reactor may reverse direction or be greatly reduced, depending upon the location of the break. The reduced flow rate of coolant (D{sub 2}O) through the fuel assembly channels of the reactor -- downflow in this situation -- can lead to boiling and to the potential for flow instabilities which may cause some of the fuel assembly channels to overheat and melt. That situation is to be avoided. The experimental approach is to provide a test annulus which simulates geometry, materials, and flow conditions in a Mark-22 fuel assembly (Coolant Channel 3) to the extent possible. The annulus has a full-scale geometry, and in fat uses SRL dummy hardware for the inner annulus wall in the ribbed geometry. The materials aluminum. The annulus is uniformly heated in the axial direction, but the circumferential heat flux can be varied to provide ``power tilt`` or asymmetric heating of the inner and outer annulus walls. The test facility uses H{sub 2}O rather than D{sub 2}O, but it includes the effects of dissolved helium gas present in the reactor. The key analysis approaches are: To compare the minima in the measured demand curves with analytical criteria, in particular the Saha-Zuber (1974) model; and to compare the pressure and temperature as a function of length in the annulus with an integral model for flow boiling in a heated channel. This document consists of data plots and summary files of temperature measurements.

  3. Nucleate boiling pressure drop in an annulus: Book 2

    Energy Technology Data Exchange (ETDEWEB)

    Block, J.A.; Crowley, C.; Dolan, F.X.; Sam, R.G.; Stoedefalke, B.H.

    1992-11-01

    The application of the work described in this report is the production reactors at the Savannah River Site, and the context is nuclear reactor safety. The Loss of Coolant Accident (LOCA) scenario considered involves a double-ended break of a primary coolant pipe in the reactor. During a LOCA, the flow through portions of the reactor may reverse direction or be greatly reduced, depending upon the location of the break. The reduced flow rate of coolant (D{sub 2}O) through the fuel assembly channels of the reactor -- downflow in this situation -- can lead to boiling and to the potential for flow instabilities which may cause some of the fuel assembly channels to overheat and melt. That situation is to be avoided. The experimental approach is to provide a test annulus which simulates geometry, materials, and flow conditions in a Mark-22 fuel assembly (Coolant Channel 3) to the extent possible. The annulus has a full-scale geometry, and in fat uses SRL dummy hardware for the inner annulus wall in the ribbed geometry. The materials aluminum. The annulus is uniformly heated in the axial direction, but the circumferential heat flux can be varied to provide ``power tilt`` or asymmetric heating of the inner and outer annulus walls. The test facility uses H{sub 2}O rather than D{sub 2}O, but it includes the effects of dissolved helium gas present in the reactor. The key analysis approaches are: To compare the minima in the measured demand curves with analytical criteria, in particular the Saha-Zuber (1974) model; and to compare the pressure and temperature as a function of length in the annulus with an integral model for flow boiling in a heated channel. Nineteen test series and a total of 178 tests were performed. Testing addressed the effects of: Heat flux; pressure; helium gas; power tilt; ribs; asymmetric heat flux.

  4. Nucleate boiling pressure drop in an annulus: Book 8

    Energy Technology Data Exchange (ETDEWEB)

    1992-11-01

    The application of the work described in this report is the production reactors at the Savannah River Site, and the context is nuclear reactor safety. The Loss of Coolant Accident (LOCA) scenario considered involves a double-ended break of a primary coolant pipe in the reactor. During a LOCA, the flow through portions of the reactor may reverse direction or be greatly reduced, depending upon the location of the break. The reduced flow rate of coolant (D{sub 2}O) through the fuel assembly channels of the reactor -- downflow in this situation -- can lead to boiling and to the potential for flow instabilities which may cause some of the fuel assembly channels to overheat and melt. That situation is to be avoided. The experimental approach is to provide a test annulus which simulates geometry, materials, and flow conditions in a Mark-22 fuel assembly (Coolant Channel 3) to the extent possible. The annulus has a full-scale geometry, and in fat uses SRL dummy hardware for the inner annulus wall in the ribbed geometry. The materials aluminum. The annulus is uniformly heated in the axial direction, but the circumferential heat flux can be varied to provide ``power tilt`` or asymmetric heating of the inner and outer annulus walls. The test facility uses H{sub 2}O rather than D{sub 2}O, but it includes the effects of dissolved helium gas present in the reactor. The key analysis approaches are: To compare the minima in the measured demand curves with analytical criteria, in particular the Saha-Zuber (1974) model; and to compare the pressure and temperature as a function of length in the annulus with an integral model for flow boiling in a heated channel. This document consists of tables of temperature measurements.

  5. Study on model of onset of nucleate boiling in natural circulation with subcooled boiling using unascertained mathematics

    Energy Technology Data Exchange (ETDEWEB)

    Zhou Tao [Department of Thermal Engineering, Tsinghua University, Beijing 100084 (China)]. E-mail: zhoutao@mail.tsinghua.edu.cn; Wang Zenghui [Department of Engineering Mechanics, Tsinghua University, Beijing 100084 (China); Yang Ruichang [Department of Thermal Engineering, Tsinghua University, Beijing 100084 (China)

    2005-10-01

    Experiment data got from onset of nucleate boiling (ONB) in natural circulation is analyzed using unascertained mathematics. Unitary mathematics model of the relation between the temperature and onset of nucleate boiling is built up to analysis ONB. Multiple unascertained mathematics models are also built up with the onset of natural circulation boiling equation based on the experiment. Unascertained mathematics makes that affirmative results are a range of numbers that reflect the fluctuation of experiment data more truly. The fluctuating value with the distribution function F(x) is the feature of unascertained mathematics model and can express fluctuating experimental data. Real status can be actually described through using unascertained mathematics. Thus, for calculation of ONB point, the description of unascertained mathematics model is more precise than common mathematics model. Based on the unascertained mathematics, a new ONB model is developed, which is important for advanced reactor safety analysis. It is conceivable that the unascertained mathematics could be applied to many other two-phase measurements as well.

  6. Physical and chemical effects of low octane gasoline fuels on compression ignition combustion

    KAUST Repository

    Badra, Jihad

    2016-09-30

    Gasoline compression ignition (GCI) engines running on low octane gasoline fuels are considered an attractive alternative to traditional spark ignition engines. In this study, three fuels with different chemical and physical characteristics have been investigated in single cylinder engine running in GCI combustion mode at part-load conditions both experimentally and numerically. The studied fuels are: Saudi Aramco light naphtha (SALN) (Research octane number (RON) = 62 and final boiling point (FBP) = 91 °C), Haltermann straight run naphtha (HSRN) (RON = 60 and FBP = 140 °C) and a primary reference fuel (PRF65) (RON = 65 and FBP = 99 °C). Injection sweeps, where the start of injection (SOI) is changed between −60 and −11 CAD aTDC, have been performed for the three fuels. Full cycle computational fluid dynamics (CFD) simulations were executed using PRFs as chemical surrogates for the naphtha fuels. Physical surrogates based on the evaporation characteristics of the naphtha streams have been developed and their properties have been implemented in the engine simulations. It was found that the three fuels have similar combustion phasings and emissions at the conditions tested in this work with minor differences at SOI earlier than −30 CAD aTDC. These trends were successfully reproduced by the CFD calculations. The chemical and physical effects were further investigated numerically. It was found that the physical characteristics of the fuel significantly affect the combustion for injections earlier than −30 CAD aTDC because of the low evaporation rates of the fuel because of the higher boiling temperature of the fuel and the colder in-cylinder air during injection. © 2016 Elsevier Ltd

  7. Flow boiling heat transfer in circulating fluidized bed

    Institute of Scientific and Technical Information of China (English)

    Xiaoguang REN; Jiangdong ZHENG; Sefiane KHELLII; Arumemi-Ikhide MICHAEL

    2009-01-01

    In order to enhance heat transfer and mitigate contamination in the boiling processes, a new type of vapor-liquid-solid (3-phase) circulating fluidized bed boil-ing system has been designed, combining a circulating fluidized bed with boiling heat transfer. Experimental results show an enhancement of the boiling curve. Flow visualization studies concerning flow hydrodynamics within the riser column are also conducted whose results are presented and discussed.

  8. Multiphysics modeling of two-phase film boiling within porous corrosion deposits

    Science.gov (United States)

    Jin, Miaomiao; Short, Michael

    2016-07-01

    Porous corrosion deposits on nuclear fuel cladding, known as CRUD, can cause multiple operational problems in light water reactors (LWRs). CRUD can cause accelerated corrosion of the fuel cladding, increase radiation fields and hence greater exposure risk to plant workers once activated, and induce a downward axial power shift causing an imbalance in core power distribution. In order to facilitate a better understanding of CRUD's effects, such as localized high cladding surface temperatures related to accelerated corrosion rates, we describe an improved, fully-coupled, multiphysics model to simulate heat transfer, chemical reactions and transport, and two-phase fluid flow within these deposits. Our new model features a reformed assumption of 2D, two-phase film boiling within the CRUD, correcting earlier models' assumptions of single-phase coolant flow with wick boiling under high heat fluxes. This model helps to better explain observed experimental values of the effective CRUD thermal conductivity. Finally, we propose a more complete set of boiling regimes, or a more detailed mechanism, to explain recent CRUD deposition experiments by suggesting the new concept of double dryout specifically in thick porous media with boiling chimneys.

  9. On the Boiling Points of the Alkyl Halides.

    Science.gov (United States)

    Correia, John

    1988-01-01

    Discusses the variety of explanations in organic chemistry textbooks of a physical property of organic compounds. Focuses on those concepts explaining attractive forces between molecules. Concludes that induction interactions play a major role in alkyl halides and other polar organic molecules and should be given wider exposure in chemistry texts.…

  10. Operational limitations of light water reactors relating to fuel performance

    Energy Technology Data Exchange (ETDEWEB)

    Cheng, H S

    1976-07-01

    General aspects of fuel performance for typical Boiling and Pressurized Water Reactors are presented. Emphasis is placed on fuel failures in order to make clear important operational limitations. A discussion of fuel element designs is first given to provide the background information for the subsequent discussion of several fuel failure modes that have been identified. Fuel failure experiences through December 31, 1974, are summarized. The operational limitations that are required to mitigate the effects of fuel failures are discussed.

  11. Operational limitations of light water reactors relating to fuel performance

    Energy Technology Data Exchange (ETDEWEB)

    Cheng, H S

    1976-07-01

    General aspects of fuel performance for typical Boiling and Pressurized Water Reactors are presented. Emphasis is placed on fuel failures in order to make clear important operational limitations. A discussion of fuel element designs is first given to provide the background information for the subsequent discussion of several fuel failure modes that have been identified. Fuel failure experiences through December 31, 1974, are summarized. The operational limitations that are required to mitigate the effects of fuel failures are discussed.

  12. Surface boiling of superheated liquid

    Energy Technology Data Exchange (ETDEWEB)

    Reinke, P. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    1997-01-01

    A basic vaporization mechanism that possibly affects the qualitative and quantitative prediction of the consequences of accidental releases of hazardous superheated liquids was experimentally and analytically investigated. The studies are of relevance for the instantaneous failure of a containment vessel filled with liquefied gas. Even though catastrophical vessel failure is a rare event, it is considered to be a major technological hazard. Modeling the initial phase of depressurisation and vaporization of the contents is an essential step for the subsequent analysis of the spread and dispersion of the materials liberated. There is only limited understanding of this inertial expansion stage of the superheated liquid, before gravity and atmospheric turbulence begin to dominate the expansion. This work aims at a better understanding of the vaporization process and to supply more precise source-term data. It is also intended to provide knowledge for the prediction of the behavior of large-scale releases by the investigation of boiling on a small scale. Release experiments with butane, propane, R-134a and water were conducted. The vaporization of liquids that became superheated by sudden depressurisation was studied in nucleation-site-free glass receptacles. Several novel techniques for preventing undesired nucleation and for opening the test-section were developed. Releases from pipes and from a cylindrical geometry allowed both linear one-dimensional, and radial-front two-dimensional propagation to be investigated. Releases were made to atmospheric pressure over a range of superheats. It was found that, above a certain superheat temperature, the free surface of the metastable liquid rapidly broke up and ejected a high-velocity vapor/liquid stream. The zone of intense vaporization and liquid fragmentation proceeded as a front that advanced into the test fluids. No nucleation of bubbles in the bulk of the superheated liquid was observed. (author) figs., tabs., refs.

  13. Recent Progress in the Development of Diesel Surrogate Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Pitz, W J

    2009-09-04

    There has been much recent progress in the area of surrogate fuels for diesel. In the last few years, experiments and modeling have been performed on higher molecular weight components of relevance to diesel fuel such as n-hexadecane (n-cetane) and 2,2,4,4,6,8,8-heptamethylnonane (iso-cetane). Chemical kinetic models have been developed for all the n-alkanes up to 16 carbon atoms. Also, there has been much experimental and modeling work on lower molecular weight surrogate components such as n-decane and do-decane which are most relevant to jet fuel surrogates, but are also relevant to diesel surrogates where simulation of the full boiling point range is desired. For the cycloalkanes, experimental work on decalin and tetralin recently has been published. For multi-component surrogate fuel mixtures, recent work on modeling of these mixtures and comparisons to real diesel fuel is reviewed. Detailed chemical kinetic models for surrogate fuels are very large in size. Significant progress also has been made in improving the mechanism reduction tools that are needed to make these large models practicable in multidimensional reacting flow simulations of diesel combustion. Nevertheless, major research gaps remain. In the case of iso-alkanes, there are experiments and modeling work on only one of relevance to diesel: iso-cetane. Also, the iso-alkanes in diesel are lightly branched and no detailed chemical kinetic models or experimental investigations are available for such compounds. More components are needed to fill out the iso-alkane boiling point range. For the aromatic class of compounds, there has been no new work for compounds in the boiling point range of diesel. Most of the new work has been on alkyl aromatics that are of the range C7 to C8, below the C10 to C20 range that is needed. For the chemical class of cycloalkanes, experiments and modeling on higher molecular weight components are warranted. Finally for multi-component surrogates needed to treat real diesel

  14. Recent Progress in the Development of Diesel Surrogate Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Pitz, W J; Mueller, C J

    2009-12-09

    There has been much recent progress in the area of surrogate fuels for diesel. In the last few years, experiments and modeling have been performed on higher molecular weight components of relevance to diesel fuel such as n-hexadecane (n-cetane) and 2,2,4,4,6,8,8-heptamethylnonane (iso-cetane). Chemical kinetic models have been developed for all the n-alkanes up to 16 carbon atoms. Also, there has been much experimental and modeling work on lower molecular weight surrogate components such as n-decane and n-dodecane that are most relevant to jet fuel surrogates, but are also relevant to diesel surrogates where simulation of the full boiling point range is desired. For two-ring compounds, experimental work on decalin and tetralin recently has been published. For multi-component surrogate fuel mixtures, recent work on modeling of these mixtures and comparisons to real diesel fuel is reviewed. Detailed chemical kinetic models for surrogate fuels are very large in size. Significant progress also has been made in improving the mechanism reduction tools that are needed to make these large models practicable in multi-dimensional reacting flow simulations of diesel combustion. Nevertheless, major research gaps remain. In the case of iso-alkanes, there are experiments and modeling work on only one of relevance to diesel: iso-cetane. Also, the iso-alkanes in diesel are lightly branched and no detailed chemical kinetic models or experimental investigations are available for such compounds. More components are needed to fill out the iso-alkane boiling point range. For the aromatic class of compounds, there has been no new work for compounds in the boiling point range of diesel. Most of the new work has been on alkyl aromatics that are of the range C7 to C8, below the C10 to C20 range that is needed. For the chemical class of cycloalkanes, experiments and modeling on higher molecular weight components are warranted. Finally for multi-component surrogates needed to treat real

  15. Passive gamma analysis of the boiling-water-reactor assemblies

    Science.gov (United States)

    Vo, D.; Favalli, A.; Grogan, B.; Jansson, P.; Liljenfeldt, H.; Mozin, V.; Schwalbach, P.; Sjöland, A.; Tobin, S.; Trellue, H.; Vaccaro, S.

    2016-09-01

    This research focused on the analysis of a set of stationary passive gamma measurements taken on the spent nuclear fuel assemblies from a boiling water reactor (BWR) using pulse height analysis data acquisition. The measurements were performed on 25 different BWR assemblies in 2014 at Sweden's Central Interim Storage Facility for Spent Nuclear Fuel (Clab). This study was performed as part of the Next Generation of Safeguards Initiative-Spent Fuel project to research the application of nondestructive assay (NDA) to spent fuel assemblies. The NGSI-SF team is working to achieve the following technical goals more easily and efficiently than in the past using nondestructive assay (NDA) measurements of spent fuel assemblies: (1) verify the initial enrichment, burnup, and cooling time of facility declaration; (2) detect the diversion or replacement of pins, (3) estimate the plutonium mass, (4) estimate the decay heat, and (5) determine the reactivity of spent fuel assemblies. The final objective of this project is to quantify the capability of several integrated NDA instruments to meet the aforementioned goals using the combined signatures of neutrons, gamma rays, and heat. This report presents a selection of the measured data and summarizes an analysis of the results. Specifically, trends in the count rates measured for spectral lines from the following isotopes were analyzed as a function of the declared burnup and cooling time: 137Cs, 154Eu, 134Cs, and to a lesser extent, 106Ru and 144Ce. From these measured count rates, predictive algorithms were developed to enable the estimation of the burnup and cooling time. Furthermore, these algorithms were benchmarked on a set of assemblies not included in the standard assemblies set used by this research team.

  16. Passive gamma analysis of the boiling-water-reactor assemblies

    Energy Technology Data Exchange (ETDEWEB)

    Vo, D., E-mail: ducvo@lanl.gov [Los Alamos National Laboratory, Los Alamos, NM (United States); Favalli, A. [Los Alamos National Laboratory, Los Alamos, NM (United States); Grogan, B. [Oak Ridge National Laboratory, Oak Ridge, TN (United States); Jansson, P. [Uppsala University, Uppsala (Sweden); Liljenfeldt, H. [Oak Ridge National Laboratory, Oak Ridge, TN (United States); Mozin, V. [Lawrence Livermore National Laboratory, Livermore, CA (United States); Schwalbach, P. [European Atomic Energy Community (EURATOM), Luxemburg (Luxembourg); Sjöland, A. [Swedish Nuclear Fuel and Waste Management Company, Stockholm (Sweden); Tobin, S.; Trellue, H. [Los Alamos National Laboratory, Los Alamos, NM (United States); Vaccaro, S. [European Atomic Energy Community (EURATOM), Luxemburg (Luxembourg)

    2016-09-11

    This research focused on the analysis of a set of stationary passive gamma measurements taken on the spent nuclear fuel assemblies from a boiling water reactor (BWR) using pulse height analysis data acquisition. The measurements were performed on 25 different BWR assemblies in 2014 at Sweden's Central Interim Storage Facility for Spent Nuclear Fuel (Clab). This study was performed as part of the Next Generation of Safeguards Initiative–Spent Fuel project to research the application of nondestructive assay (NDA) to spent fuel assemblies. The NGSI–SF team is working to achieve the following technical goals more easily and efficiently than in the past using nondestructive assay (NDA) measurements of spent fuel assemblies: (1) verify the initial enrichment, burnup, and cooling time of facility declaration; (2) detect the diversion or replacement of pins, (3) estimate the plutonium mass, (4) estimate the decay heat, and (5) determine the reactivity of spent fuel assemblies. The final objective of this project is to quantify the capability of several integrated NDA instruments to meet the aforementioned goals using the combined signatures of neutrons, gamma rays, and heat. This report presents a selection of the measured data and summarizes an analysis of the results. Specifically, trends in the count rates measured for spectral lines from the following isotopes were analyzed as a function of the declared burnup and cooling time: {sup 137}Cs, {sup 154}Eu, {sup 134}Cs, and to a lesser extent, {sup 106}Ru and {sup 144}Ce. From these measured count rates, predictive algorithms were developed to enable the estimation of the burnup and cooling time. Furthermore, these algorithms were benchmarked on a set of assemblies not included in the standard assemblies set used by this research team.

  17. Lattice Boltzmann modeling of boiling heat transfer: The boiling curve and the effects of wettability

    CERN Document Server

    Li, Q; Francois, M M; He, Y L; Luo, K H

    2015-01-01

    A hybrid thermal lattice Boltzmann (LB) model is presented to simulate thermal multiphase flows with phase change based on an improved pseudopotential LB approach [Q. Li, K. H. Luo, and X. J. Li, Phys. Rev. E 87, 053301 (2013)]. The present model does not suffer from the spurious term caused by the forcing-term effect, which was encountered in some previous thermal LB models for liquid-vapor phase change. Using the model, the liquid-vapor boiling process is simulated. The boiling curve together with the three boiling stages (nucleate boiling, transition boiling, and film boiling) is numerically reproduced in the LB community for the first time. The numerical results show that the basic features and the fundamental characteristics of boiling heat transfer are well captured, such as the severe fluctuation of transient heat flux in the transition boiling and the feature that the maximum heat transfer coefficient lies at a lower wall superheat than that of the maximum heat flux. Furthermore, the effects of the he...

  18. Cryogenic Boil-Off Reduction System

    Science.gov (United States)

    Plachta, David W.; Guzik, Monica C.

    2014-03-01

    A computational model of the cryogenic boil-off reduction system being developed by NASA as part of the Cryogenic Propellant Storage and Transfer technology maturation project has been applied to a range of propellant storage tanks sizes for high-performing in-space cryogenic propulsion applications. This effort focuses on the scaling of multi-layer insulation (MLI), cryocoolers, broad area cooling shields, radiators, solar arrays, and tanks for liquid hydrogen propellant storage tanks ranging from 2 to 10 m in diameter. Component scaling equations were incorporated into the Cryogenic Analysis Tool, a spreadsheet-based tool used to perform system-level parametric studies. The primary addition to the evolution of this updated tool is the integration of a scaling method for reverse turbo-Brayton cycle cryocoolers, as well as the development and inclusion of Self-Supporting Multi-Layer Insulation. Mass, power, and sizing relationships are traded parametrically to establish the appropriate loiter period beyond which this boil-off reduction system application reduces mass. The projected benefit compares passive thermal control to active thermal control, where active thermal control is evaluated for reduced boil-off with a 90 K shield, zero boil-off with a single heat interception stage at the tank wall, and zero boil-off with a second interception stage at a 90 K shield. Parametric studies show a benefit over passive storage at loiter durations under one month, in addition to showing a benefit for two-stage zero boil-off in terms of reducing power and mass as compared to single stage zero boil-off. Furthermore, active cooling reduces the effect of varied multi-layer insulation performance, which, historically, has been shown to be significant.

  19. Measurement of boiling heat transfer coefficient in liquid nitrogen bath by inverse heat conduction method

    Institute of Scientific and Technical Information of China (English)

    Tao JIN; Jian-ping HONG; Hao ZHENG; Ke TANG; Zhi-hua GAN

    2009-01-01

    Inverse heat conduction method (IHCM)is one of the most effective approaches to obtaining the boiling heat transfer coefficient from measured results.This paper focuses on its application in cryogenic boiling heat transfer.Experiments were conducted on the heattransfer of a stainless steel block in a liquid nitrogen bath.with the assumption of a ID conduction condition to realize fast acquisition of the temperature of the test points inside the block.With the inverse-heat conduction theory and the explicit finite difference model,a solving program was developed to calculate the heat flux and the boiling heat transfer coefficient of a stainless steel block in liquid nitrogen bath based on the temperature acquisition data.Considering the oscillating data and some unsmooth transition points in the inverse-heat-conduction calculation result of the heat-transfer coefficient,a two-step data-fitting procedure was proposed to obtain the expression for the boiling heat transfer coefficients.The coefficient was then verified for accuracy by a comparison between the simulation results using this expression and the verifying experimental results of a stainless steel block.The maximum error with a revised segment fitting iS around 6%.which verifies the feasibility of using IHCM to measure the boiling heat transfer coefficient in liquid nitrogen bath.

  20. Highly selective condensation of biomass-derived methyl ketones as a source of aviation fuel.

    Science.gov (United States)

    Sacia, Eric R; Balakrishnan, Madhesan; Deaner, Matthew H; Goulas, Konstantinos A; Toste, F Dean; Bell, Alexis T

    2015-05-22

    Aviation fuel (i.e., jet fuel) requires a mixture of C9 -C16 hydrocarbons having both a high energy density and a low freezing point. While jet fuel is currently produced from petroleum, increasing concern with the release of CO2 into the atmosphere from the combustion of petroleum-based fuels has led to policy changes mandating the inclusion of biomass-based fuels into the fuel pool. Here we report a novel way to produce a mixture of branched cyclohexane derivatives in very high yield (>94 %) that match or exceed many required properties of jet fuel. As starting materials, we use a mixture of n-alkyl methyl ketones and their derivatives obtained from biomass. These synthons are condensed into trimers via base-catalyzed aldol condensation and Michael addition. Hydrodeoxygenation of these products yields mixtures of C12 -C21 branched, cyclic alkanes. Using models for predicting the carbon number distribution obtained from a mixture of n-alkyl methyl ketones and for predicting the boiling point distribution of the final mixture of cyclic alkanes, we show that it is possible to define the mixture of synthons that will closely reproduce the distillation curve of traditional jet fuel.

  1. A theoretical model for coupled neutronic-thermohydraulic out-of-phase oscillations in Boiling Water Reactors

    Energy Technology Data Exchange (ETDEWEB)

    Bragt, D.D.B. van

    1995-10-01

    A theoretical model for out-of-phase power oscillations in BWRs is proposed. This model describes the dynamic behavior of the neutronic and thermohydraulic subsystems during out-of-phase oscillations, and the coupling of these subsystems via the fuel temperature dynamics and void- and Doppler feedback effects. The zero-power neutron kinetics of the out-of-phase flux density mode is derived by expanding the (time- and space-dependent) neutron flux density in the static solutions of the neutron transport equation. This procedure yields the modal point-kinetic equations for the (first-harmonic) out-of-phase mode. The fuel temperature dynamics is described by a lumped parameter first-order process, characterized by a typical fuel time constant. Using the quasistatic approach, the basic equations of the channel thermohydraulics are derived from the conservation laws of mass and energy and the momentum equation. The momentum equation is coupled with the appropriate boundary condition (constant core pressure drop) for out-of phase oscillations. This procedure yields a set of nonlinear equations describing the dynamic behavior of the boiling boundary, void fraction and mass flux density in the cooling channel. A frequency-domain parametric study confirms that if the out-of-phase mode has a more negative subcriticality, reactor stability increases. On the other hand, a more negative void reactivity coefficient has a destabilizing effect. Besides these two parameters, the fuel time constant was found to be an important parameter determining stability. Where possible, the linearized equations describing the channel thermohydraulics were compare with exact solutions of the governing partial-differential channel equations. This comparison shows that in the frequency range of interest, discrepancies between the proposed quasi-static model and more complicated exact solutions are to be expected. (orig.).

  2. The dew point temperature as a criterion for optimizing the operating conditions of proton exchange membrane fuel cells

    DEFF Research Database (Denmark)

    Berning, Torsten

    2012-01-01

    of the operating pressure, the stoichiometric flow ratios and the net drag coefficient of water through the membrane. Then, computational modeling results obtained with a previously published model are analyzed and compared with the dew point charts, and it is demonstrated how cell flooding or membrane dry-out can...... be predicted a priori with the aid of these diagrams. Finally, guidelines for the desired cell operating temperature based on the expected dew point temperatures are developed. In the current work these guidelines are limited to the interdigitated flow field design, and they are likely to be different...

  3. Did the big bang boil?

    CERN Multimedia

    Wilczek, Frank

    2006-01-01

    "Standard theories tell us that, at some point in the Universe's evolution, free quarks and gluons must have become bound together into the hadronic matter we see today. But was this transition abrupt or smooth?

  4. The entropy balance for boiling flow

    Energy Technology Data Exchange (ETDEWEB)

    Collado, Francisco-Javier E-mail: fjk@posta.unizar.es

    2001-10-01

    Subcooled forced convection boiling of water is recognized as one of the best means of accommodating the very high heat fluxes that plasma facing components of fusion reactors have to withstand. The boiling curve, giving the wall temperature in function of the applied flux and flow conditions, is essential for the design of such cooling configurations. In this paper, a new entropy balance for subcooled boiling flow, which allows the wall temperature to be obtained, is presented and successfully compared with experimental data from the Joint US-EURATOM R and D Program. The derivation of this entropy balance is based on a new strict application of the Reynolds theorem to multiphase flows recently proposed by the author.

  5. Thermodynamics of Flow Boiling Heat Transfer

    Science.gov (United States)

    Collado, F. J.

    2003-05-01

    Convective boiling in sub-cooled water flowing through a heated channel is essential in many engineering applications where high heat flux needs to be accommodated. It has been customary to represent the heat transfer by the boiling curve, which shows the heat flux versus the wall-minus-saturation temperature difference. However it is a rather complicated problem, and recent revisions of two-phase flow and heat transfer note that calculated values of boiling heat transfer coefficients present many uncertainties. Quite recently, the author has shown that the average thermal gap in the heated channel (the wall temperature minus the average temperature of the coolant) was tightly connected with the thermodynamic efficiency of a theoretical reversible engine placed in this thermal gap. In this work, whereas this correlation is checked again with data taken by General Electric (task III) for water at high pressure, a possible connection between this wall efficiency and the reversible-work theorem is explored.

  6. Boiling on Microconfigured Composite Surfaces Enhanced

    Science.gov (United States)

    Chao, David F.

    2000-01-01

    Boiling heat transfer is one of the key technologies for the two-phase active thermal-control system used on space platforms, as well as for the dynamic power systems aboard the International Space Station. Because it is an effective heat transfer mode, boiling is integral to many space applications, such as heat exchangers and other cooling devices. Nucleate boiling near the critical heat flux (CHF) can transport very large thermal loads with a much smaller device and much lower pumping power than for single-phase heat exchangers. However, boiling performance sharply deteriorates in a reduced-gravity environment, and operation in the CHF regime is somewhat perilous because of the risk of burnout to the device surface. New materials called microconfigured metal-graphite composites can enhance boiling. The photomicrograph shows the microconfiguration (x3000) of the copper-graphite (Cu-Gr) surface as viewed by scanning electronic microscope. The graphite fiber tips appear as plateaus with rugged surfaces embedded in the copper matrix. It has been experimentally demonstrated that this type of material manifests excellent boiling heat transfer performance characteristics and an increased CHF. Nonisothermal surfaces were less sensitive to variations of wall superheat in the CHF regime. Because of the great difference in conductivity between the copper base and the graphite fiber, the composite surfaces have a nonisothermal surface characteristic and, therefore, will have a much larger "safe" operating region in the CHF regime. In addition, the thermocapillary forces induced by the temperature differences between the fiber tips and the metal matrix play an important role in bubble detachment, and may not be adversely affected in a reduced-gravity environment. All these factors indicate that microconfigured composites may improve the reliability and economy (dominant factors in all space applications) of various thermal components found on spacecraft during future

  7. Fuel cells

    Directory of Open Access Journals (Sweden)

    D. N. Srivastava

    1962-05-01

    Full Text Available The current state of development of fuel cells as potential power sources is reviewed. Applications in special fields with particular reference to military requirements are pointed out.

  8. The dew point temperature as a criterion for optimizing the operating conditions of proton exchange membrane fuel cells

    DEFF Research Database (Denmark)

    Berning, Torsten

    2012-01-01

    be predicted a priori with the aid of these diagrams. Finally, guidelines for the desired cell operating temperature based on the expected dew point temperatures are developed. In the current work these guidelines are limited to the interdigitated flow field design, and they are likely to be different...

  9. ASTRID: A 3D Eulerian software for subcooled boiling modelling - comparison with experimental results in tubes and annuli

    Energy Technology Data Exchange (ETDEWEB)

    Briere, E.; Larrauri, D.; Olive, J. [Electricite de France, Chatou (France)

    1995-09-01

    For about four years, Electricite de France has been developing a 3-D computer code for the Eulerian simulation of two-phase flows. This code, named ASTRID, is based on the six-equation two-fluid model. Boiling water flows, such as those encountered in nuclear reactors, are among the main applications of ASTRID. In order to provide ASTRID with closure laws and boundary conditions suitable for boiling flows, a boiling model has been developed by EDF and the Institut de Mecanique des Fluides de Toulouse. In the fluid, the heat and mass transfer between a bubble and the liquid is being modelled. At the heating wall, the incipient boiling point is determined according to Hsu`s criterion and the boiling heat flux is split into three additive terms: a convective term, a quenching term and a vaporisation term. This model uses several correlations. EDF`s program in boiling two-phase flows also includes experimental studies, some of which are performed in collaboration with other laboratories. Refrigerant subcooled boiling both in tubular (DEBORA experiment, CEN Grenoble) and in annular geometry (Arizona State University Experiment) have been computed with ASTRID. The simulations show the satisfactory results already obtained on void fraction and liquid temperature. Ways of improvement of the model are drawn especially on the dynamical part.

  10. BOILING SLURRY REACTOR AND METHOD FO CONTROL

    Science.gov (United States)

    Petrick, M.; Marchaterre, J.F.

    1963-05-01

    The control of a boiling slurry nuclear reactor is described. The reactor consists of a vertical tube having an enlarged portion, a steam drum at the top of the vertical tube, and at least one downcomer connecting the steam drum and the bottom of the vertical tube, the reactor being filled with a slurry of fissionabie material in water of such concentration that the enlarged portion of the vertical tube contains a critical mass. The slurry boils in the vertical tube and circulates upwardly therein and downwardly in the downcomer. To control the reactor by controlling the circulation of the slurry, a gas is introduced into the downcomer. (AEC)

  11. Facilitating Students' Conceptual Understanding of Boiling Using a Four-Step Constructivist Teaching Method

    Science.gov (United States)

    Calik, Muammer

    2008-01-01

    The aim of the work presented here was to devise an activity associated with factors affecting boiling points. The intervention used a four-step constructivist-based teaching strategy, which was subsequently evaluated by a cohort of students. Data collection consisted of application of a purpose designed questionnaire consisting of four open-ended…

  12. Development of a new simulation code for evaluation of criticality transients involving fissile solution boiling

    Energy Technology Data Exchange (ETDEWEB)

    Basoglu, Benan; Yamamoto, Toshihiro; Okuno, Hiroshi; Nomura, Yasushi [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment

    1998-03-01

    In this work, we report on the development of a new computer code named TRACE for predicting the excursion characteristics of criticality excursions involving fissile solutions. TRACE employs point neutronics coupled with simple thermal-hydraulics. The temperature, the radiolytic gas effects, and the boiling phenomena are estimated using the transient heat conduction equation, a lumped-parameter energy model, and a simple boiling model, respectively. To evaluate the model, we compared our results with the results of CRAC experiments. The agreement in these comparisons is quite satisfactory. (author)

  13. Application of fractal characteristic quantities of pressure fluctuation in subcooled boiling regime recognition

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    The dynamical behavior of the subcoole d boiling two-phase system ws introduced and discussed. With the introduction of fractal concept, an analysis of the fractal feature of pressure wave signals fiom nonlinear dynamics point of view. was carried out. Meanwhile, the pseudo phase diagrans of typical time series of sound pressure were given. Finally, through dynamic clustering and on the basis of calculating correlation dimension and Hurst exponent of pressure wave time series on different subcooling conditions, the recognition of developing regime of the two-phase system was delivered, which might provide a promising approach of recognition and diagnosis of a boiling system.

  14. Reexamination of Correlations for Nucleate Site Distribution on Boiling Surface by Fractal Theory

    Institute of Scientific and Technical Information of China (English)

    YangChunxin

    1997-01-01

    Nucleate site distribution plays an essential role in nucleate boiling process.In this paper,it is pointed out that the size and spatial distributioin density of nucleate sites presented on real boiling surface can be described by the normalized fractal distribution function,and the physical meaning of parameters involved in some experimental correlations proposed by early investigations are identified according to fractal distribution function.It is further suggested that the surface micro geometry characteristics such as the shape of cavities should be described and analyzed qualitatively by using fractal theory.

  15. Development of a new simulation code for evaluation of criticality transients involving fissile solution boiling

    Energy Technology Data Exchange (ETDEWEB)

    Basoglu, Benan; Yamamoto, Toshihiro; Okuno, Hiroshi; Nomura, Yasushi [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment

    1998-03-01

    In this work, we report on the development of a new computer code named TRACE for predicting the excursion characteristics of criticality excursions involving fissile solutions. TRACE employs point neutronics coupled with simple thermal-hydraulics. The temperature, the radiolytic gas effects, and the boiling phenomena are estimated using the transient heat conduction equation, a lumped-parameter energy model, and a simple boiling model, respectively. To evaluate the model, we compared our results with the results of CRAC experiments. The agreement in these comparisons is quite satisfactory. (author)

  16. Synthetic fuel aromaticity and staged combustion

    Energy Technology Data Exchange (ETDEWEB)

    Longanbach, J. R.; Chan, L. K.; Levy, A.

    1982-11-15

    Samples of middle and heavy SRC-II distillates were distilled into 50 C boiling point range fractions. These were characterized by measurements of their molecular weight, elemental analysis and basic nitrogen content and calculation of average molecular structures. The structures typically consisted of 1 to 3 aromatic rings fused to alicyclic rings with short, 1 to 3 carbon aliphatic side chains. The lower boiling fractions contained significant amounts (1 atom/molecule) of oxygen while the heavier fractions contained so few heteroatoms that they were essentially hydrocarbons. Laboratory scale oxidative-pyrolysis experiments were carried out at pyrolysis temperatures of 500 to 1100 C and oxygen concentrations from 0 to 100 percent of stoichiometry. Analysis of liquid products, collected in condensers cooled with liquid nitrogen showed that aromatization is a major reaction in the absence of oxygen. The oxygen-containing materials (phenolics) seem to be more resistant to thermal pyrolysis than unsubstituted aromatics. Nitrogen converts from basic to nonbasic forms at about 500 C. The nonbasic nitrogen is more stable and survives up to 700 C after which it is slowly removed. A recently constructed 50,000 Btu/hr staged combustor was used to study the chemistry of the nitrogen and aromatics. SRC II combustion was studied under fuel-rich, first-stage conditions at air/fuel ratios from 0.6 to 1.0 times stoichiometric. The chemistry of the fuel during combustion calls for further investigation in order to examine the mechanism by which HCN is evolved as a common intermediate for the formation of the nitrogen-containing gaseous combustion products. 25 references, 45 figures, 25 tables.

  17. An Investigation of Graduate Scientists' Understandings of Evaporation and Boiling.

    Science.gov (United States)

    Goodwin, Alan; Orlik, Yuri

    2000-01-01

    Uses a video presentation of six situations relating to the evaporation and boiling of liquids and the escape of dissolved gases from solution and investigates graduate scientists' understanding of the concepts of boiling and evaporation. (Author/YDS)

  18. Design and in-core fuel management of reload fuel elements for reactors made by other manufacturers. Auslegung und Einsatzplanung von Nachlade-Brennelementen fuer Reaktoren anderer Hersteller

    Energy Technology Data Exchange (ETDEWEB)

    Neufert, A.; Urban, P.

    1990-12-01

    By the end of 1990 Siemens had performed fuel element designs and in-core fuel management for 94 operating cycles in 27 pressurized and boiling water reactors of other manufacturers. Together with the client different fuel element designs are developed and proof is furnished of the reactor physics compatibility of different fuel elements from various producers, and of plant safety. (DG).

  19. Early Onset of Nucleate Boiling on Gas-covered Biphilic Surfaces.

    Science.gov (United States)

    Shen, Biao; Yamada, Masayuki; Hidaka, Sumitomo; Liu, Jiewei; Shiomi, Junichiro; Amberg, Gustav; Do-Quang, Minh; Kohno, Masamichi; Takahashi, Koji; Takata, Yasuyuki

    2017-05-17

    For phase-change cooling schemes for electronics, quick activation of nucleate boiling helps safeguard the electronics components from thermal shocks associated with undesired surface superheating at boiling incipience, which is of great importance to the long-term system stability and reliability. Previous experimental studies show that bubble nucleation can occur surprisingly early on mixed-wettability surfaces. In this paper, we report unambiguous evidence that such unusual bubble generation at extremely low temperatures-even below the boiling point-is induced by a significant presence of incondensable gas retained by the hydrophobic surface, which exhibits exceptional stability even surviving extensive boiling deaeration. By means of high-speed imaging, it is revealed that the consequently gassy boiling leads to unique bubble behaviour that stands in sharp contrast with that of pure vapour bubbles. Such findings agree qualitatively well with numerical simulations based on a diffuse-interface method. Moreover, the simulations further demonstrate strong thermocapillary flows accompanying growing bubbles with considerable gas contents, which is associated with heat transfer enhancement on the biphilic surface in the low-superheat region.

  20. Heat Transfer From Electrically Heated Nichrome Wires to Boiling Water at Different Pressures

    Directory of Open Access Journals (Sweden)

    Devi Dayal

    1968-01-01

    Full Text Available Boiling curves for nucleate and film boiling have been drawn for nichrome of three sizes in distilled and degasified water at saturation temperatures under five different sub-atmospheric vapour pressure. It has been observed that (i for the same Q/A (heat transfer, Delta Theta (excess of wire temperature over saturation point of water decreases with pressure in both nucleate and film boiling ranges, (ii Both Q/A max. and Delta Theta/SubC show a rapid decrease with pressure but these variations become more gradual at higher pressures, and (iii Q/A max. and Delta Theta/SubC increase with wire size at all pressures; increase in Delta Theta/SubC however, becomes less conspicuous at higher pressures approaching one atmosphere.

  1. Bubble Behavior in Nucleate Boiling Experiment Aboard the Space Shuttle

    OpenAIRE

    Koeln, Justin P.; Boulware, Jeffrey C.; Ban, Heng

    2009-01-01

    Boiling dynamics in microgravity need to be better understood before heat transfer systems based on boiling mechanism can be developed for space applications. This paper presents the results of a nucleate boiling experiment aboard Space Shuttle Endeavor (STS- 108). The experiment utilized nickel-chromium resistance wire to boil water in microgravity, and the data was recorded with a CCD camera and six thermistors. This data was analyzed to determine the behavior of bubble formation, detachmen...

  2. Cryogenic Propellant Boil-Off Reduction System

    Science.gov (United States)

    Plachta, D. W.; Christie, R. J.; Carlberg, E.; Feller, J. R.

    2008-03-01

    Lunar missions under consideration would benefit from incorporation of high specific impulse propellants such as LH2 and LO2, even with their accompanying boil-off losses necessary to maintain a steady tank pressure. This paper addresses a cryogenic propellant boil-off reduction system to minimize or eliminate boil-off. Concepts to do so were considered under the In-Space Cryogenic Propellant Depot Project. Specific to that was an investigation of cryocooler integration concepts for relatively large depot sized propellant tanks. One concept proved promising—it served to efficiently move heat to the cryocooler even over long distances via a compressed helium loop. The analyses and designs for this were incorporated into NASA Glenn Research Center's Cryogenic Analysis Tool. That design approach is explained and shown herein. Analysis shows that, when compared to passive only cryogenic storage, the boil-off reduction system begins to reduce system mass if durations are as low as 40 days for LH2, and 14 days for LO2. In addition, a method of cooling LH2 tanks is presented that precludes development issues associated with LH2 temperature cryocoolers.

  3. Heat transfer coefficient for boiling carbon dioxide

    DEFF Research Database (Denmark)

    Knudsen, Hans Jørgen Høgaard; Jensen, Per Henrik

    1998-01-01

    Heat transfer coefficient and pressure drop for boiling carbon dioxide (R744) flowing in a horizontal pipe has been measured. The calculated heat transfer coeeficient has been compared with the Chart correlation of Shah. The Chart Correlation predits too low heat transfer coefficient but the ratio...

  4. Heat transfer coeffcient for boiling carbon dioxide

    DEFF Research Database (Denmark)

    Knudsen, Hans Jørgen Høgaard; Jensen, Per Henrik

    1997-01-01

    Heat transfer coefficient and pressure drop for boiling carbon dioxide (R744) flowing in a horizontal pipe has been measured. The pipe is heated by condensing R22 outside the pipe. The heat input is supplied by an electrical heater wich evaporates the R22. With the heat flux assumed constant over...

  5. Electrically Driven Liquid Film Boiling Experiment

    Science.gov (United States)

    Didion, Jeffrey R.

    2016-01-01

    This presentation presents the science background and ground based results that form the basis of the Electrically Driven Liquid Film Boiling Experiment. This is an ISS experiment that is manifested for 2021. Objective: Characterize the effects of gravity on the interaction of electric and flow fields in the presence of phase change specifically pertaining to: a) The effects of microgravity on the electrically generated two-phase flow. b) The effects of microgravity on electrically driven liquid film boiling (includes extreme heat fluxes). Electro-wetting of the boiling section will repel the bubbles away from the heated surface in microgravity environment. Relevance/Impact: Provides phenomenological foundation for the development of electric field based two-phase thermal management systems leveraging EHD, permitting optimization of heat transfer surface area to volume ratios as well as achievement of high heat transfer coefficients thus resulting in system mass and volume savings. EHD replaces buoyancy or flow driven bubble removal from heated surface. Development Approach: Conduct preliminary experiments in low gravity and ground-based facilities to refine technique and obtain preliminary data for model development. ISS environment required to characterize electro-wetting effect on nucleate boiling and CHF in the absence of gravity. Will operate in the FIR - designed for autonomous operation.

  6. Big Bubbles in Boiling Liquids: Students' Views

    Science.gov (United States)

    Costu, Bayram

    2008-01-01

    The aim of this study was to elicit students' conceptions about big bubbles in boiling liquids (water, ethanol and aqueous CuSO[subscript 4] solution). The study is based on twenty-four students at different ages and grades. The clinical interviews technique was conducted to solicit students' conceptions and the interviews were analyzed to…

  7. Contact Angle Effects in Boiling Heat Transfer

    OpenAIRE

    Urquiola, Erwin; Fujita, Yasunobu

    2002-01-01

    This paper reports boiling experiments with pure water and surfactant solutions of SDS on horizontal heating surface. The static contact angle, rather than the surface tension value, was found to be the leading factor for the results and probably its prev

  8. Natural saltwater upconing by boils: field measurements and numerical modeling

    NARCIS (Netherlands)

    De Louw, Perry G.B.; Vandenbohede, A.; Oude Essink, Gualbert; Werner, Adrian D.

    2013-01-01

    Natural saltwater upconing caused by the preferential groundwater discharge of boils is a key proce ss in the salinization of Dutch deep polders. The factors controlling upconing by boil discharge and boil water salinities are poorly constrained and have not been previously documented. We addressed

  9. A study of flow boiling phenomena using real time neutron radiography

    Science.gov (United States)

    Novog, David Raymond

    The operation and safety of both fossil-fuel and nuclear power stations depend on adequate cooling of the thermal source involved. This is usually accomplished using liquid coolants that are forced through the high temperature regions by a pumping system; this fluid then transports the thermal energy to another section of the power station. However, fluids that undergo boiling during this process create vapor that can be detrimental, and influence safe operation of other system components. The behavior of this vapor, or void, as it is generated and transported through the system is critical in predicting the operational and safety performance. This study uses two advanced penetrating radiation techniques, Real Time Neutron Radiography (RTNR), and High Speed X-Ray Tomography (HS-XCT), to examine void generation and transport behavior in a flow boiling system. The geometries studied were tube side flow boiling in a cylindrical configuration, and a similar flow channel with an internal twisted tape swirl flow generator. The heat transfer performance and pressure drop characteristics were monitored in addition to void distribution measurements, so that the impact of void distribution could be determined. The RTNR and heat transfer pipe flow studies were conducted using boiling Refrigerant 134a at pressures from 500 to 700 kPa, inlet subcooling from 3 to 12°C and mass fluxes from 55 to 170kg/m 2-s with heat fluxes up to 40 kW/m2. RTNR and HS-XCT were used to measure the distribution and size of the vapor phases in the channel for cylindrical tube-side flow boiling and swirl-flow boiling geometries. The results clearly show that the averaged void is similar for both geometries, but that there is a significant difference in the void distribution, velocity and transport behavior from one configuration to the next. Specifically, the void distribution during flow boiling in a cylindrical-tube test section showed that the void fraction was largest near the tube center and

  10. The law of stable equilibrium and the entropy-based boiling curve for flow boiling

    Energy Technology Data Exchange (ETDEWEB)

    Collado, F.J. [Universidad de Zaragoza (Spain). Dpto. Ingenieria Mecanica Motores Termicos

    2005-05-01

    Convective flow boiling in sub-cooled fluids is recognized as one of the few means of accommodating very high heat fluxes. There are many available correlations for predicting the inner wall temperature of the heated duct in the several regimes of the empirical Nukiyama boiling curve, although unfortunately there is no physical fundamentals of such curve. Recently, the author has shown that the classical entropy balance could contain key information about boiling heat transfer. So, it was found that the average thermal gap in the heated channel (the inner wall temperature minus the average temperature of the coolant fluid) was strongly correlated with the efficiency of a theoretical reversible engine placed in this thermal gap. From this new correlation, a new boiling curve plotting the wall temperature versus the average fluid temperature was derived and successfully checked against low- and high-pressure water data. This curve suggested a new and simple definition of the critical heat flux (CHF) namely, the value of the coolant average temperature at the maximum. In this work, after briefly reviewing the entropy balance of a non-equilibrium boiling flow and its relationship with the thermodynamic average temperature and the law of stable equilibrium (LSE), the possibilities of the new approach for the design of flow boiling cooling systems are highlighted. Finally, the strong correlation found between the reversible engine efficiency and the thermal driving force is verified again, now with high-pressure refrigerant 22 (R-22) data. (author)

  11. A heat transfer model for slug flow boiling within microchannels

    Science.gov (United States)

    Magnini, Mirco; Thome, John

    2016-11-01

    We propose a novel physics-based model for the fluid mechanics and heat transfer associated with slug flow boiling in horizontal circular microchannels, to update the widely used three-zone model for the design of multi-microchannel evaporators. The flow is modelled as the cyclic passage of a liquid slug, an elongated bubble which traps a thin liquid film against the channel wall, and a dry vapor plug. The capillary flow theory, extended to incorporate evaporation effects, is applied to estimate the bubble velocity along the channel. A liquid film thickness prediction method considering bubble proximity effects, which may limit the radial extension of the film, is included. Theoretical heat transfer models accounting for the thermal inertia of the liquid film and for the recirculating flow within the liquid slug are utilized. The heat transfer model is compared to experimental data taken from three independent studies: 833 slug flow boiling data points covering R134a, R245fa and R236fa and channel diameters from 0.4 mm to 1 mm. The new model predicts more than 80% of the database to within +/- 30 % and it represents an important step toward a complete physics-based modelling of bubble dynamics and heat transfer within microchannels under evaporating flow conditions.

  12. Correlation of pool boiling curves for the homogeous group freons

    Energy Technology Data Exchange (ETDEWEB)

    Westwater, J.W. (Dept. of Chemical Engineering, Univ. of Illnois, Urban, IL (US)); Zinn, J.C. (Monsanto, Co., St. Louis, MO (US)); Brodbeck, K.J. (Clorox Corp., Pleasanton, CA (US))

    1989-02-01

    A knowledge of the complete boiling curve q verses {Delta}T for a liquid, including the regimes of nucleate boiling, transition boiling, and a film boiling is needed for the design and operation of various types of heat transfer equipment. No general method exists for predicting the complete curve. Most difficult is the prediction of the nucleate boiling curve, the transition curve, and the temperature that separates the two. If the curve for every liquid at every pressure must be determined experimentally, we are faced with a formidable task. This paper shows that some simplification is possible for members of a homologous group.

  13. Flow boiling in microgap channels experiment, visualization and analysis

    CERN Document Server

    Alam, Tamanna; Jin, Li-Wen

    2013-01-01

    Flow Boiling in Microgap Channels: Experiment, Visualization and Analysis presents an up-to-date summary of the details of the confined to unconfined flow boiling transition criteria, flow boiling heat transfer and pressure drop characteristics, instability characteristics, two phase flow pattern and flow regime map and the parametric study of microgap dimension. Advantages of flow boiling in microgaps over microchannels are also highlighted. The objective of this Brief is to obtain a better fundamental understanding of the flow boiling processes, compare the performance between microgap and c

  14. Thermohydrodynamics of boiling in a van der Waals fluid.

    Science.gov (United States)

    Laurila, T; Carlson, A; Do-Quang, M; Ala-Nissila, T; Amberg, G

    2012-02-01

    We present a modeling approach that enables numerical simulations of a boiling Van der Waals fluid based on the diffuse interface description. A boundary condition is implemented that allows in and out flux of mass at constant external pressure. In addition, a boundary condition for controlled wetting properties of the boiling surface is also proposed. We present isothermal verification cases for each element of our modeling approach. By using these two boundary conditions we are able to numerically access a system that contains the essential physics of the boiling process at microscopic scales. Evolution of bubbles under film boiling and nucleate boiling conditions are observed by varying boiling surface wettability. We observe flow patters around the three-phase contact line where the phase change is greatest. For a hydrophilic boiling surface, a complex flow pattern consistent with vapor recoil theory is observed.

  15. Methods of producing transportation fuel

    Science.gov (United States)

    Nair, Vijay; Roes, Augustinus Wilhelmus Maria; Cherrillo, Ralph Anthony; Bauldreay, Joanna M.

    2011-12-27

    Systems, methods, and heaters for treating a subsurface formation are described herein. At least one method for producing transportation fuel is described herein. The method for producing transportation fuel may include providing formation fluid having a boiling range distribution between -5.degree. C. and 350.degree. C. from a subsurface in situ heat treatment process to a subsurface treatment facility. A liquid stream may be separated from the formation fluid. The separated liquid stream may be hydrotreated and then distilled to produce a distilled stream having a boiling range distribution between 150.degree. C. and 350.degree. C. The distilled liquid stream may be combined with one or more additives to produce transportation fuel.

  16. Boiling Heat Transfer in Circulating Fluidized Beds

    Institute of Scientific and Technical Information of China (English)

    张利斌; 李修伦

    2001-01-01

    A model is proposed to predict boiling heat transfer coefficient in a three-phase circulating fluidized bed (CFB), which is a new type of evaporation boiling means for enhancing heat transfer and preventing fouling. To verify the model, experiments are conducted in a stainless steel column with 39 mm ID and 2.0 m height, in which the heat transfer coefficient is measured for different superficial velocities, steam pressures, particle concentrations and materials of particle. As the steam pressure and particle concentrations increase, the heat transfer coefficient in the bed increases. The heat transfer coefficient increases with the liquid velocity but it exhibits a local minimum.The heat transfer coefficient is correlated with cluster renewed model and two-mechanism method. The prediction of the model is in good agreement with experimental data.

  17. Boiling Heat Transfer in Circulating Fluidized Beds

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    A model is proposed to predict boiling heat transfer coefficient in a three-phase circulating fluidized bed (CFB), which is a new type of evaporation boiling means for enhancing heat transfer and preventing fouling. To verify the model, experiments are conducted in a stainless steel column with 39mm ID and 2.0m height, in which the heat transfer coefficient is measured for different superficial velocities, steam pressures, particle concentrations and materials of particle. As the steam pressure and particle concentrations increase, the heat transfer coefficient in the bed increases. The heat transfer coefficient increases with the liquid velocity but it exhibits a local minimum. The heat transfer coefficient is correlated with cluster renewed model and two-mechanism method. The prediction of the model is in good agreement with experimental data.

  18. Nanowires for enhanced boiling heat transfer.

    Science.gov (United States)

    Chen, Renkun; Lu, Ming-Chang; Srinivasan, Vinod; Wang, Zhijie; Cho, Hyung Hee; Majumdar, Arun

    2009-02-01

    Boiling is a common mechanism for liquid-vapor phase transition and is widely exploited in power generation and refrigeration devices and systems. The efficacy of boiling heat transfer is characterized by two parameters: (a) heat transfer coefficient (HTC) or the thermal conductance; (b) the critical heat flux (CHF) limit that demarcates the transition from high HTC to very low HTC. While increasing the CHF and the HTC has significant impact on system-level energy efficiency, safety, and cost, their values for water and other heat transfer fluids have essentially remained unchanged for many decades. Here we report that the high surface tension forces offered by liquids in nanowire arrays made of Si and Cu can be exploited to increase both the CHF and the HTC by more than 100%.

  19. Enhanced Droplet Control by Transition Boiling

    Science.gov (United States)

    Grounds, Alex; Still, Richard; Takashina, Kei

    2012-10-01

    A droplet of water on a heated surface can levitate over a film of gas produced by its own evaporation in the Leidenfrost effect. When the surface is prepared with ratchet-like saw-teeth topography, these droplets can self-propel and can even climb uphill. However, the extent to which the droplets can be controlled is limited by the physics of the Leidenfrost effect. Here, we show that transition boiling can be induced even at very high surface temperatures and provide additional control over the droplets. Ratchets with acute protrusions enable droplets to climb steeper inclines while ratchets with sub-structures enable their direction of motion to be controlled by varying the temperature of the surface. The droplets' departure from the Leidenfrost regime is assessed by analysing the sound produced by their boiling. We anticipate these techniques will enable the development of more sophisticated methods for controlling small droplets and heat transfer.

  20. Dynamic Bubble Behaviour during Microscale Subcooled Boiling

    Institute of Scientific and Technical Information of China (English)

    WANG Hao; PENG Xiao-Feng; David M.Christopher

    2005-01-01

    @@ Bubble cycles, including initiation, growth and departure, are the physical basis of nucleate boiling. The presentinvestigation, however, reveals unusual bubble motions during subcooled nucleate boiling on microwires 25 orl00μm in diameter. Two types of bubble motions, bubble sweeping and bubble return, are observed in theexperiments. Bubble sweeping describes a bubble moving back and forth along the wire, which is motion parallelto the wire. Bubble return is the bubble moving back to the wire after it has detached or leaping above thewire. Theoretical analyses and numerical simulations are conducted to investigate the driving mechanisms forboth bubble sweeping and return. Marangoni flow from warm to cool regions along the bubble interface is foundto produce the shear stresses needed to drive these unusual bubble movements.

  1. Pool Boiling Heat Transfer on structured Surfaces

    Science.gov (United States)

    Addy, J.; Olbricht, M.; Müller, B.; Luke, A.

    2016-09-01

    The development in the process and energy sector shows the importance of efficient utilization of available resources to improve thermal devices. To achieve this goal, all thermal components have to be optimized continuously. Various applications of multi-phase heat and mass transfer have to be improved. Therefore, the heat transfer and the influence of surface roughness in nucleate boiling with the working fluid propane is experimentally investigated on structured mild steel tubes, because only few data are available in the literature. The mild steel tube is sandblasted to obtain different surface roughness. The measurements are carried out over wide ranges of heat flux and pressure. The experimental results are compared with correlations from literature and the effect of surface roughness on the heat transfer is discussed. It is shown that the heat transfer coefficient increases with increasing surface roughness, heat flux and reduced pressure at nucleate pool boiling.

  2. Pool Boiling Heat Transfer Characteristics of Chromium Coatings Deposited by RF Magnetron Sputtering

    Energy Technology Data Exchange (ETDEWEB)

    Seo, Gwang Hyeok; Son, Hong Hyun; Jeong, Uiju; Jeun, Gyoodong; Kim, Sung Joong [Hanyang University, Seoul (Korea, Republic of)

    2015-05-15

    Many researches have suggested fundamental changes to satisfy the safety requirements, including development of accident tolerant fuels (ATFs). The adoption of coating techniques is one of promising approaches for ATF systems because surface modification with a highly oxidation-resistant material can prevent hydrogen generation and cladding embrittlement. Compared to the development of a new cladding for the replacement of the current zirconium-based alloy cladding and new fuel forms instead of the current ceramic oxide fuels, the surface coating technique is cost-effective and easily applicable to the current LWR system with no significant design changes. Recently, a wide variety of oxidation-resistant materials have been proposed: iron-based alloys and SiC-based materials. Among them, chromium (Cr) is suggested as a coating material for fuel claddings because it is known for has oxidation-resistant characteristic. In order to assess the feasibility of coating techniques with an oxidation-resistant material, in this study chromium (Cr) film was deposited on a metal substrate via a physical vapor deposition (PVD) process. After preparing test specimens, pool boiling heat transfer experiments were carried out to investigate the boiling performance of both cases. Moreover, during a test, visualization works were conducted for a phenomenological understanding. In this study, Cr deposition on the SS316 surface was conducted using the sputtering process. Specifically, sophisticated surface characterization was performed with the wettability measurement and surface morphology analysis. Furthermore, the pool boiling heat transfer experiments were carried out to obtain the CHF value of the test heater. The major findings observed from this study can be summarized as follows. The surface wettability increased 77% after the sputtering deposition.

  3. Self-propelled film-boiling liquids

    OpenAIRE

    Linke, H.; Aleman, B. J.; Melling, L. D.; Taormina, M. J.; Francis, M J; Dow-Hygelund, C. C.; Narayanan, V.; Taylor, R. P.; Stout, A.

    2005-01-01

    We report that liquids perform self-propelled motion when they are placed in contact with hot surfaces with asymmetric (ratchet-like) topology. The pumping effect is observed when the liquid is in the film-boiling regime, for many liquids and over a wide temperature range. We propose that liquid motion is driven by a viscous force exerted by vapor flow between the solid and the liquid.

  4. Steady State Vapor Bubble in Pool Boiling

    Science.gov (United States)

    Zou, An; Chanana, Ashish; Agrawal, Amit; Wayner, Peter C.; Maroo, Shalabh C.

    2016-02-01

    Boiling, a dynamic and multiscale process, has been studied for several decades; however, a comprehensive understanding of the process is still lacking. The bubble ebullition cycle, which occurs over millisecond time-span, makes it extremely challenging to study near-surface interfacial characteristics of a single bubble. Here, we create a steady-state vapor bubble that can remain stable for hours in a pool of sub-cooled water using a femtosecond laser source. The stability of the bubble allows us to measure the contact-angle and perform in-situ imaging of the contact-line region and the microlayer, on hydrophilic and hydrophobic surfaces and in both degassed and regular (with dissolved air) water. The early growth stage of vapor bubble in degassed water shows a completely wetted bubble base with the microlayer, and the bubble does not depart from the surface due to reduced liquid pressure in the microlayer. Using experimental data and numerical simulations, we obtain permissible range of maximum heat transfer coefficient possible in nucleate boiling and the width of the evaporating layer in the contact-line region. This technique of creating and measuring fundamental characteristics of a stable vapor bubble will facilitate rational design of nanostructures for boiling enhancement and advance thermal management in electronics.

  5. Flow boiling test of GDP replacement coolants

    Energy Technology Data Exchange (ETDEWEB)

    Park, S.H. [comp.

    1995-08-01

    The tests were part of the CFC replacement program to identify and test alternate coolants to replace CFC-114 being used in the uranium enrichment plants at Paducah and Portsmouth. The coolants tested, C{sub 4}F{sub 10} and C{sub 4}F{sub 8}, were selected based on their compatibility with the uranium hexafluoride process gas and how well the boiling temperature and vapor pressure matched that of CFC-114. However, the heat of vaporization of both coolants is lower than that of CFC-114 requiring larger coolant mass flow than CFC-114 to remove the same amount of heat. The vapor pressure of these coolants is higher than CFC-114 within the cascade operational range, and each coolant can be used as a replacement coolant with some limitation at 3,300 hp operation. The results of the CFC-114/C{sub 4}F{sub 10} mixture tests show boiling heat transfer coefficient degraded to a minimum value with about 25% C{sub 4}F{sub 10} weight mixture in CFC-114 and the degree of degradation is about 20% from that of CFC-114 boiling heat transfer coefficient. This report consists of the final reports from Cudo Technologies, Ltd.

  6. Pressure drop in saturated flow boiling

    Energy Technology Data Exchange (ETDEWEB)

    Collado, Francisco J. [Universidad de Zaragoza, Zaragoza (Spain)

    2003-07-01

    A new mass balance for flow boiling have been recently suggested by the author following a quite simple idea: if the phases have different velocities, they can not cover the same distance -the control volume length for a 1-d system- in the same time. Thus, the time scales of the phases have to be different, and we should scale the time dependent magnitudes of one phase to the other one before combining them. Furthermore, it is reasonable to think that conservation equations should have to include in some manner this evident physical fact. In complete coherence with the former mass balance, a new energy balance, which does include the slip ratio has been also stated. This work, whilst reviews these new fundamentals for saturated flow boiling, stresses those aspects related with the prediction of the pressure drop in saturated flow boiling. The new correlations found for the data carefully measured by Thom during the Cambridge project would confirm the new two-phase flowapproach.

  7. CFD for Subcooled Flow Boiling: Parametric Variations

    Directory of Open Access Journals (Sweden)

    Roland Rzehak

    2013-01-01

    Full Text Available We investigate the present capabilities of CFD for wall boiling. The computational model used combines the Euler/Euler two-phase flow description with heat flux partitioning. Very similar modeling was previously applied to boiling water under high pressure conditions relevant to nuclear power systems. Similar conditions in terms of the relevant nondimensional numbers have been realized in the DEBORA tests using dichlorodifluoromethane (R12 as the working fluid. This facilitated measurements of radial profiles for gas volume fraction, gas velocity, liquid temperature, and bubble size. Robust predictive capabilities of the modeling require that it is validated for a wide range of parameters. It is known that a careful calibration of correlations used in the wall boiling model is necessary to obtain agreement with the measured data. We here consider tests under a variety of conditions concerning liquid subcooling, flow rate, and heat flux. It is investigated to which extent a set of calibrated model parameters suffices to cover at least a certain parameter range.

  8. Steady State Vapor Bubble in Pool Boiling.

    Science.gov (United States)

    Zou, An; Chanana, Ashish; Agrawal, Amit; Wayner, Peter C; Maroo, Shalabh C

    2016-02-03

    Boiling, a dynamic and multiscale process, has been studied for several decades; however, a comprehensive understanding of the process is still lacking. The bubble ebullition cycle, which occurs over millisecond time-span, makes it extremely challenging to study near-surface interfacial characteristics of a single bubble. Here, we create a steady-state vapor bubble that can remain stable for hours in a pool of sub-cooled water using a femtosecond laser source. The stability of the bubble allows us to measure the contact-angle and perform in-situ imaging of the contact-line region and the microlayer, on hydrophilic and hydrophobic surfaces and in both degassed and regular (with dissolved air) water. The early growth stage of vapor bubble in degassed water shows a completely wetted bubble base with the microlayer, and the bubble does not depart from the surface due to reduced liquid pressure in the microlayer. Using experimental data and numerical simulations, we obtain permissible range of maximum heat transfer coefficient possible in nucleate boiling and the width of the evaporating layer in the contact-line region. This technique of creating and measuring fundamental characteristics of a stable vapor bubble will facilitate rational design of nanostructures for boiling enhancement and advance thermal management in electronics.

  9. Evaluation of onset of nucleate boiling models

    Energy Technology Data Exchange (ETDEWEB)

    Huang, LiDong [Heat Transfer Research, Inc., College Station, TX (United States)], e-mail: lh@htri.net

    2009-07-01

    This article discusses available models and correlations for predicting the required heat flux or wall superheat for the Onset of Nucleate Boiling (ONB) on plain surfaces. It reviews ONB data in the open literature and discusses the continuing efforts of Heat Transfer Research, Inc. in this area. Our ONB database contains ten individual sources for ten test fluids and a wide range of operating conditions for different geometries, e.g., tube side and shell side flow boiling and falling film evaporation. The article also evaluates literature models and correlations based on the data: no single model in the open literature predicts all data well. The prediction uncertainty is especially higher in vacuum conditions. Surface roughness is another critical criterion in determining which model should be used. However, most models do not directly account for surface roughness, and most investigators do not provide surface roughness information in their published findings. Additional experimental research is needed to improve confidence in predicting the required wall superheats for nucleation boiling for engineering design purposes. (author)

  10. Fuel flexible fuel injector

    Science.gov (United States)

    Tuthill, Richard S; Davis, Dustin W; Dai, Zhongtao

    2015-02-03

    A disclosed fuel injector provides mixing of fuel with airflow by surrounding a swirled fuel flow with first and second swirled airflows that ensures mixing prior to or upon entering the combustion chamber. Fuel tubes produce a central fuel flow along with a central airflow through a plurality of openings to generate the high velocity fuel/air mixture along the axis of the fuel injector in addition to the swirled fuel/air mixture.

  11. Nucleate pool boiling in microgravity: Recent progress and future prospects

    Science.gov (United States)

    Colin, Catherine; Kannengieser, Olivier; Bergez, Wladimir; Lebon, Michel; Sebilleau, Julien; Sagan, Michaël; Tanguy, Sébastien

    2017-01-01

    Pool boiling on flat plates in microgravity has been studied for more than 50 years. The results of recent experiments performed in sounding rocket are presented and compared to previous results. At low heat flux, the vertical oscillatory motion of the primary bubble is responsible for the increase in the heat transfer coefficient in microgravity compared to ground experiments. The effect of a non-condensable gas on the stabilisation of the large primary bubble on the heater is pointed out. Experiments on isolated bubbles are also performed on ground and in parabolic flight. The effect of a shear flow on the bubble detachment is highlighted. A force balance model allows determining an expression of the capillary force and of the drag force acting on the bubble.

  12. Experimental study about ONB and subcooled boiling heat transfer

    Energy Technology Data Exchange (ETDEWEB)

    Changhong, P.; Myint, A.; Yun, G.; Dounan, J. [State Key Laboratory of Multiphase Flow in power engineering, Department of Nuclear and Thermal Power Engineering, Xian (China)

    2004-07-01

    Water subcooled boiling heat transfer were experimentally investigated in the vertical annuli with narrow gap. Subcooled flow boiling covers the region from the location where the bubbles forms on the wall to the location where the bulk temperature reaches saturated temperature. Three locations in the subcooled flow boiling have been identified by earlier researchers as the onset of nucleate boiling (ONB), the beginning of fully developed boiling, and the location where the thermodynamic quality is zero that is inferred from the enthalpy balance equation. The heat transfer regions are identified as single-phase heat transfer prior to ONB, partial boiling (PB) and fully developed boiling (FDB). In this study, the available models for predicting heat transfer in the different regions and the modified correlation can predict our experimental data: -) the heat flux of ONB can be predicted by the Unal correlation, nevertheless the h{sub FC} is calculated by the modified Dittus-Boelter correlations in the narrow annuli, -) Griffith's method can be modified to identify the beginning of fully develop boiling, -) in the partial boiling region, the heat transfer coefficient can be calculated by h{sub PB} equals (1-a)*h{sub L} + a*h{sub FDB}, and -) in the fully developed region, the correlation for saturated flow boiling can be employed to describe the heat transfer.

  13. Formulation and Testing of Paraffin-Based Solid Fuels Containing Energetic Additives for Hybrid Rockets

    Science.gov (United States)

    Larson, Daniel B.; Boyer, Eric; Wachs,Trevor; Kuo, Kenneth K.; Story, George

    2012-01-01

    with both paraffin and RDX, the mixture will be combined with the melted paraffin. With the melting point of the paraffin far below the decomposition temperature of the RDX, the solvent will be boiled off, leaving the crystallized RDX embedded in the paraffin. At low percentages of RDX additive and with crystallized RDX surrounded by paraffin, the fuel grains will remain inert, maintaining a key benefit of hybrids in the safety of the solid fuel.

  14. Feasibility of producing jet fuel from GPGP (Great Plains Gasification Plant) by-products

    Energy Technology Data Exchange (ETDEWEB)

    Willson, W.G.; Knudson, C.L.; Rindt, J.R.

    1987-01-01

    The Great Plains Gasification Plant (GPGP) in Beulah, North Dakota, is in close proximity to several Air Force bases along our northern tier. This plant is producing over 137 million cubic feet per day high-Btu SNG from North Dakota lignite. In addition, the plant generates three liquid streams, naphtha, crude phenol, and tar oil. The naphtha may be directly marketable because of its low boiling point and high aromatic content. The other two streams, totalling about 4300 barrels per day, are available as potential sources of aviation jet fuel for the Air Force. The overall objective of this project is to assess the technical and economic feasibility of producing aviation turbine fuel from the by-product streams of GPGP. These streams, as well as fractions thereof, will be characterized and subsequently processed over a wide range of process conditions. The resulting turbine fuel products will be analyzed to determine their chemical and physical characteristics as compared to petroleum-based fuels to meet the military specification requirements. A second objective is to assess the conversion of the by-product streams into a new, higher-density aviation fuel. Since no performance specifications currently exist for a high-density jet fuel, reaction products and intermediates will only be characterized to indicate the feasibility of producing such a fuel. This report describes results on feedstock characterization. 6 figs., 5 tabs.

  15. Heat Transfer of Single and Binary Systems inPool Boiling

    Directory of Open Access Journals (Sweden)

    Abbas J. Sultan

    2010-01-01

    Full Text Available The present research focuses on the study of the effect of mass transfer resistance on the rate of heat transfer in pool boiling. The nucleate pool boiling heat transfer coefficients for binary mixtures (ethanol-n-butanol, acetone-n-butanol, acetone-ethanol, hexane-benzene, hexane-heptane, and methanol-water were measured at different concentrations of the more volatile components. The systems chosen covered a wide range of mixture behaviors.The experimental set up for the present investigation includes electric heating element submerged in the test liquid mounted vertically. Thermocouple and a digital indictor measured the temperature of the heater surface. The actual heat transfer rate being obtained by multiplying the voltmeter and ammeter readings. A water cooled coil condenses the vapor produced by the heat input and the liquid formed returns to the cylinder for re-evaporation.The boiling results show that the nucleate pool boiling heat transfer coefficients of binary mixtures were always lower than the pure components nucleate pool boiling heat transfer coefficients. This confirmed that the mass transfer resistance to the movement of the more volatile component was responsible for decrease in heat transfer and that the maximum deterioration that was observed at a point was the absolute concentration differences between vapor and liquid phases at their maximum. All the data points were tested with the most widely known correlations namely those of Calus-Leonidopoulos, Fujita and Thome. It was found that Thome's correlation is the more representative form, for it gave the least mean and standard deviations

  16. Thermal analysis of IRT-T reactor fuel elements

    OpenAIRE

    Naymushin, Artem Georgievich; Chertkov, Yuri Borisovich; Lebedev, Ivan Igorevich; Anikin, Mikhail Nikolaevich

    2015-01-01

    The article describes the method and results of thermo-physical calculations of IRT-T reactor core. Heat fluxes, temperatures of cladding, fuel meat and coolant were calculated for height of core, azimuth directions of FA and each fuel elements in FA. Average calculated values of uniformity factor of energy release distribution for height of fuel assemblies were shown in this research. Onset nucleate boiling temperature and ONB-ratio were calculated. Shows that temperature regimes of fuel ele...

  17. Lattice Boltzmann modeling of boiling heat transfer: The boiling curve and the effects of wettability

    OpenAIRE

    Li, Q; Kang, Q. J.; Francois, M. M.; He, Y. L.; Luo, K. H.

    2015-01-01

    A hybrid thermal lattice Boltzmann (LB) model is presented to simulate thermal multiphase flows with phase change based on an improved pseudopotential LB approach [Q. Li, K. H. Luo, and X. J. Li, Phys. Rev. E 87, 053301 (2013)]. The present model does not suffer from the spurious term caused by the forcing-term effect, which was encountered in some previous thermal LB models for liquid-vapor phase change. Using the model, the liquid-vapor boiling process is simulated. The boiling curve togeth...

  18. A review on boiling heat transfer enhancement with nanofluids.

    Science.gov (United States)

    Barber, Jacqueline; Brutin, David; Tadrist, Lounes

    2011-04-04

    There has been increasing interest of late in nanofluid boiling and its use in heat transfer enhancement. This article covers recent advances in the last decade by researchers in both pool boiling and convective boiling applications, with nanofluids as the working fluid. The available data in the literature is reviewed in terms of enhancements, and degradations in the nucleate boiling heat transfer and critical heat flux. Conflicting data have been presented in the literature on the effect that nanofluids have on the boiling heat-transfer coefficient; however, almost all researchers have noted an enhancement in the critical heat flux during nanofluid boiling. Several researchers have observed nanoparticle deposition at the heater surface, which they have related back to the critical heat flux enhancement.

  19. Infrared thermometry study of nanofluid pool boiling phenomena

    Science.gov (United States)

    2011-01-01

    Infrared thermometry was used to obtain first-of-a-kind, time- and space-resolved data for pool boiling phenomena in water-based nanofluids with diamond and silica nanoparticles at low concentration (boiling heat transfer (by as much as 50%) and an increase in the CHF (by as much as 100%). The bubble departure frequency and NSD were found to be lower in nanofluids compared with water for the same wall superheat. Furthermore, it was found that a porous layer of nanoparticles built up on the heater surface during nucleate boiling, which improved surface wettability compared with the water-boiled surfaces. Using the prevalent nucleate boiling models, it was possible to correlate this improved surface wettability to the experimentally observed reductions in the bubble departure frequency, NSD, and ultimately to the deterioration in the nucleate boiling heat transfer and the CHF enhancement. PMID:21711754

  20. Crystallization fouling of finned tubes during pool boiling: effect of fin density

    Energy Technology Data Exchange (ETDEWEB)

    Esawy, M.; Malayeri, M.R. [University of Stuttgart, Institute for Thermodynamics and Thermal Engineering (ITW), Stuttgart (Germany); Mueller-Steinhagen, H. [University of Stuttgart, Institute for Thermodynamics and Thermal Engineering (ITW), Stuttgart (Germany); German Aerospace Centre (DLR), Institute of Technical Thermodynamics, Stuttgart (Germany)

    2010-11-15

    Bubble characteristics such as density, size, frequency and motion are key factors that contribute to the superiority of nucleate pool boiling over other modes of heat transfer. Nevertheless, if heat transfer occurs in an environment prone to fouling, the very same parameters may lead to accelerated deposit formation due to concentration effects beneath the growing bubbles. This has led to the widely accepted design recommendation to maintain the heat transfer surface temperature below the boiling point if fouling may occur, e.g., in seawater desalination. The present paper aims at investigating the formation of deposits on finned tubes during nucleate pool boiling of CaSO{sub 4} solutions. The test finned tubes are low finned tubes with fin densities of 19 and 26 fins/in. made from Cu-Ni. The fouling experiments were carried out at atmospheric pressure for different heat fluxes ranging from 100 to 300 kW/m{sup 2} and a CaSO{sub 4} concentration of 1.6 g/L. For the sake of comparison, similar runs were performed with smooth stainless steel tubes. The results show that: (1) the fouling resistance decreases with increasing fin density, (2) fouling on the finned tubes was reduced with increasing nucleate boiling activity and (3) if any fouling layer occurred on the finned tubes it could be removed easily. (orig.)

  1. Consumers' perception and acceptance of boiled and fermented sausages from strongly boar tainted meat.

    Science.gov (United States)

    Meier-Dinkel, Lisa; Gertheiss, Jan; Schnäckel, Wolfram; Mörlein, Daniel

    2016-08-01

    Characteristic off-flavours may occur in uncastrated male pigs depending on the accumulation of androstenone and skatole. Feasible processing of strongly tainted carcasses is challenging but gains in importance due to the European ban on piglet castration in 2018. This paper investigates consumers' acceptability of two sausage types: (a) emulsion-type (BOILED) and (b) smoked raw-fermented (FERM). Liking (9 point scales) and flavour perception (check-all-that-apply with both, typical and negatively connoted sensory terms) were evaluated by 120 consumers (within-subject design). Proportion of tainted boar meat (0, 50, 100%) affected overall liking of BOILED, F (2, 238)=23.22, Psausages, F (2, 238)=0.89, P=.414. Consumers described the flavour of BOILED-100 as strong and sweaty. In conclusion, FERM products seem promising for processing of tainted carcasses whereas formulations must be optimized for BOILED in order to eliminate perceptible off-flavours. Boar taint rejection thresholds may be higher for processed than those suggested for unprocessed meat cuts.

  2. Heat transport in boiling turbulent Rayleigh-B\\'{e}nard convection

    CERN Document Server

    Lakkaraju, Rajaram; Oresta, Paolo; Verzicco, Roberto; Lohse, Detlef; Prosperetti, Andrea

    2014-01-01

    Boiling is an extremely effective way to promote heat transfer from a hot surface to a liquid due to several mechanisms many of which are not understood in quantitative detail. An important component of the overall process is that the buoyancy of the bubbles compounds with that of the liquid to give rise to a much enhanced natural convection. In this paper we focus specifically on this enhancement and present a numerical study of the resulting two-phase Rayleigh-B\\'enard convection process. We make no attempt to model other aspects of the boiling process such as bubble nucleation and detachment. We consider a cylindrical cell with a diameter equal to its height. The cell base and top are held at temperatures above and below the boiling point of the liquid, respectively. By keeping the temperature difference constant and changing the liquid pressure we study the effect of the liquid superheat in a Rayleigh number range that, in the absence of boiling, would be between $2\\times10^6$ and $5\\times10^9$. We find a...

  3. Boiling Experiment Facility for Heat Transfer Studies in Microgravity

    Science.gov (United States)

    Delombard, Richard; McQuillen, John; Chao, David

    2008-01-01

    Pool boiling in microgravity is an area of both scientific and practical interest. By conducting tests in microgravity, it is possible to assess the effect of buoyancy on the overall boiling process and assess the relative magnitude of effects with regards to other "forces" and phenomena such as Marangoni forces, liquid momentum forces, and microlayer evaporation. The Boiling eXperiment Facility is now being built for the Microgravity Science Glovebox that will use normal perfluorohexane as a test fluid to extend the range of test conditions to include longer test durations and less liquid subcooling. Two experiments, the Microheater Array Boiling Experiment and the Nucleate Pool Boiling eXperiment will use the Boiling eXperiment Facility. The objectives of these studies are to determine the differences in local boiling heat transfer mechanisms in microgravity and normal gravity from nucleate boiling, through critical heat flux and into the transition boiling regime and to examine the bubble nucleation, growth, departure and coalescence processes. Custom-designed heaters will be utilized to achieve these objectives.

  4. Investigation of Enhanced Boiling Heat Transfer from Porous Surfaces

    Institute of Scientific and Technical Information of China (English)

    LinZhiping; MaTongze; 等

    1994-01-01

    Experimental investigations of boiling heat transfer from porous surfaces at atmospheric pressure were performne.The porous surfaces are plain tubes coverd with metal screens.V-shaped groove tubes covered with screens,plain tubes sintered with screens.and V-shaped groove tubes sintered with screens,The experimental results show that sintering metal screens around spiral V-shaped groove tubes can greatly improve the boiling heat transfer,The boiling hystesis was observed in the experiment.This paper discusses the mechanism of the boiling heat transfer from those kinds of porous surfaces stated above.

  5. Pool boiling heat transfer performance of Newtonian nanofluids

    Energy Technology Data Exchange (ETDEWEB)

    Soltani, Saide; Etemad, Seyed Gholamreza [Isfahan University of Technology, Department of Chemical Engineering, Isfahan (Iran); Thibault, Jules [University of Ottawa, Department of Chemical and Biological Engineering, Ottawa, ON (Canada)

    2009-10-15

    Experimental measurements were carried out on the boiling heat transfer characteristics of {gamma}-Al{sub 2}O{sub 3}/water and SnO{sub 2}/water Newtonian nanofluids. Nanofluids are liquid suspensions containing nanoparticles with sizes smaller than 100 nm. In this research, suspensions with different concentrations of {gamma}-Al{sub 2}O{sub 3} and SnO{sub 2} nanoparticles in water were studied under nucleate pool boiling heat transfer conditions. Results show that nanofluids possess noticeably higher boiling heat transfer coefficients than the base fluid. The boiling heat transfer coefficients depend on the type and concentration of nanoparticles. (orig.)

  6. Boiling heat transfer modern developments and advances

    CERN Document Server

    Lahey, Jr, RT

    2013-01-01

    This volume covers the modern developments in boiling heat transfer and two-phase flow, and is intended to provide industrial, government and academic researchers with state-of-the-art research findings in the area of multiphase flow and heat transfer technology. Special attention is given to technology transfer, indicating how recent significant results may be used for practical applications. The chapters give detailed technical material that will be useful to engineers and scientists who work in the field of multiphase flow and heat transfer. The authors of all chapters are members of the

  7. Pool boiling visualization on open microchannel surfaces

    Directory of Open Access Journals (Sweden)

    Kaniowski Robert

    2017-01-01

    Full Text Available The paper presents visualization investigations into pool boiling heat transfer for open minichannel surfaces. The experiments were carried out wih saturated water at atmospheric pressure. Parallel microchannels fabricated by machining were about 0.3 mm wide and 0.2 to 0.4 mm deep. High-speed videos were used as an aid to understanding the heat transfer mechanism. The visualization study aimed at identifying nucleation sites of the departing bubbles and determining their diameters and frequency at various superheats.

  8. Explosive Boiling of Superheated Cryogenic Liquids

    CERN Document Server

    Baidakov, V G

    2007-01-01

    The monograph is devoted to the description of the kinetics of spontaneous boiling of superheated liquefied gases and their solutions. Experimental results are given on the temperature of accessible superheating, the limits of tensile strength of liquids due to processes of cavitation and the rates of nucleation of classical and quantum liquids. The kinetics of evolution of the gas phase is studied in detail for solutions of cryogenic liquids and gas-saturated fluids. The properties of the critical clusters (bubbles of critical sizes) of the newly evolving gas phase are analyzed for initial st

  9. Subcooled pool boiling CHF in ethanol

    OpenAIRE

    Park, Jongdoc; Fukuda, Katsuya; Liu, Qiusheng

    2006-01-01

    Steady-state and transient critical heat fluxes (CHFs) were measured using a 1.0 mm diameter horizontal cylinder in a pool of highly wetting liquid, such as ethanol, due to steady and transient heat generation rate for wide range of subcoolings and pressures. Boiling CHF was assumed to happen based on a kind of hydrodynamic instability (HI) at CHF, and the model is supposed that the increase in vapor generation from the cylinder surface causes a limit of the steady-state vapor escape flow whe...

  10. Heat transfer coefficient for boiling carbon dioxide

    DEFF Research Database (Denmark)

    Knudsen, Hans Jørgen Høgaard; Jensen, Per Henrik

    1998-01-01

    between the measured and the calculated heat transfer coefficient is nearly constant and equal 1.9. With this factor the correlation predicts the measured data within 14% (RMS). The pressure drop is of the same order as the measuring uncertainty and the pressure drop has not been compared with correlation's.......Heat transfer coefficient and pressure drop for boiling carbon dioxide (R744) flowing in a horizontal pipe has been measured. The calculated heat transfer coeeficient has been compared with the Chart correlation of Shah. The Chart Correlation predits too low heat transfer coefficient but the ratio...

  11. Modal control of unstable boiling states in three-dimensional nonlinear pool-boiling

    NARCIS (Netherlands)

    van Gils, R.W.; Speetjens, M.F.M; Zwart, Heiko J.; Nijmeijer, H.

    2014-01-01

    Topic is feedback stabilisation of a nonlinear pool-boiling system in three spatial dimensions (3D). Regulation of its unstable (non-uniform) equilibria has great potential for application in micro-electronics cooling and thermal-management systems. Here, as a first step, stabilisation of such 3D

  12. Modal control of unstable boiling states in three-dimensional nonlinear pool-boiling

    NARCIS (Netherlands)

    Gils, van R.W.; Speetjens, M.F.M; Zwart, H.J.; Nijmeijer, H.

    2014-01-01

    Topic is feedback stabilisation of a nonlinear pool-boiling system in three spatial dimensions (3D). Regulation of its unstable (non-uniform) equilibria has great potential for application in micro-electronics cooling and thermal-management systems. Here, as a first step, stabilisation of such 3D eq

  13. Aging study of boiling water reactor high pressure injection systems

    Energy Technology Data Exchange (ETDEWEB)

    Conley, D.A.; Edson, J.L.; Fineman, C.F. [Lockheed Idaho Technologies Co., Idaho Falls, ID (United States)

    1995-03-01

    The purpose of high pressure injection systems is to maintain an adequate coolant level in reactor pressure vessels, so that the fuel cladding temperature does not exceed 1,200{degrees}C (2,200{degrees}F), and to permit plant shutdown during a variety of design basis loss-of-coolant accidents. This report presents the results of a study on aging performed for high pressure injection systems of boiling water reactor plants in the United States. The purpose of the study was to identify and evaluate the effects of aging and the effectiveness of testing and maintenance in detecting and mitigating aging degradation. Guidelines from the United States Nuclear Regulatory Commission`s Nuclear Plant Aging Research Program were used in performing the aging study. Review and analysis of the failures reported in databases such as Nuclear Power Experience, Licensee Event Reports, and the Nuclear Plant Reliability Data System, along with plant-specific maintenance records databases, are included in this report to provide the information required to identify aging stressors, failure modes, and failure causes. Several probabilistic risk assessments were reviewed to identify risk-significant components in high pressure injection systems. Testing, maintenance, specific safety issues, and codes and standards are also discussed.

  14. Study of Pu consumption in advanced light water reactors: Evaluation of GE advanced boiling water reactor plants - compilation of Phase 1B task reports

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1993-09-15

    This report contains an extensive evaluation of GE advanced boiling water reactor plants prepared for United State Department of Energy. The general areas covered in this report are: core and system performance; fuel cycle; infrastructure and deployment; and safety and environmental approval.

  15. Optimizing the Combination of Smoking and Boiling on Quality of Korean Traditional Boiled Loin (M. longissimus dorsi).

    Science.gov (United States)

    Choi, Yun-Sang; Kim, Hyun-Wook; Hwang, Ko-Eun; Song, Dong-Heon; Kim, Yong-Jae; Jung, Tae-Jun; Kim, Young-Boong; Kim, Cheon-Jei

    2015-01-01

    The combined effects of smoking and boiling on the proximate composition, technological quality traits, shear force, and sensory characteristics of the Korean traditional boiled loin were studied. Cooking loss, processing loss, and shear force were lower in the smoked/boiled samples than those in the control (without smoking treatment) (pboiled loin samples between the control and treatment did not differ significantly in protein, fat, or ash contents, or pH values (p>0.05). The treated samples had higher score for overall acceptability than the control (pboiled loin treated with smoking for 60 min before boiling had improved physicochemical properties and sensory characteristics.

  16. Observation of Boiling Structure and CHF Phenomena between Parallel Vertical Plates Submerged in a Pool

    Energy Technology Data Exchange (ETDEWEB)

    Chu, In-Cheol; Euh, Dong Jin; Song, Chul-Hwa [KAERI, Daejeon (Korea, Republic of)

    2015-05-15

    The dynamic behavior of dry areas or phase distribution on the heating surface were observed by total reflection technique and DEPIcT. Instantaneous two-dimensional temperature distribution of a boiling surface was measured by infrared thermometry. These studies reported that the key physics of the CHF triggering mechanism was the dynamic behavior of the dry area under the massive bubble hovering on a surface and the appearance of a non-rewetting dry area. The gap between parallel vertical fuel plates ranges from 2 to 3 mm, typically for the research reactors. In addition, boiling in a confined narrow channel is encountered in high-performance heat exchangers and electronics component cooling. The CHF value for a vertical plate in a pool is strongly affected by the existence of the narrow confinement. However, the studies to identify the local boiling structure on a heating surface and CHF mechanism for this kind of geometry are quite lacking. In this study, CHF phenomena as well as global and local boiling structures near a heating surface were observed for a vertical narrow channel submerged in a pool, using total reflection and shadow graph visualization techniques. In-depth visualization studies were made to observe the global and local boiling structures, dynamic behavior of the dry area, and its rewetting process in a vertical narrow channel submerged in a pool of saturated Freon R-113. Based on this observation, new CHF mechanism was suggested for the present boiling configuration. The periodic feature of a slug flow prevailed above the heat flux of 77.2% CHF. The heating surface under the slug bubble was almost dry, but this large dry patch was effectively rewetted as the slug tail region rushed into the region covered by the slug bubble. The dry area fraction in the slug tail region increased gradually with an increase in the heat flux, and the rewetting efficiency of the slug tail region became deteriorated due to an enhancement of bubble nucleation

  17. Calculation system for physical analysis of boiling water reactors; Modelisation des phenomenes physiques specifiques aux reacteurs a eau bouillante, notamment le couplage neutronique-thermohydraulique

    Energy Technology Data Exchange (ETDEWEB)

    Bouveret, F

    2001-07-01

    Although Boiling Water Reactors generate a quarter of worldwide nuclear electricity, they have been only little studied in France. A certain interest now shows up for these reactors. So, the aim of the work presented here is to contribute to determine a core calculation methodology with CEA (Commissariat a l'Energie Atomique) codes. Vapour production in the reactor core involves great differences in technological options from pressurised water reactor. We analyse main physical phenomena for BWR and offer solutions taking them into account. BWR fuel assembly heterogeneity causes steep thermal flux gradients. The two dimensional collision probability method with exact boundary conditions makes possible to calculate accurately the flux in BWR fuel assemblies using the APOLLO-2 lattice code but induces a very long calculation time. So, we determine a new methodology based on a two-level flux calculation. Void fraction variations in assemblies involve big spectrum changes that we have to consider in core calculation. We suggest to use a void history parameter to generate cross-sections libraries for core calculation. The core calculation code has also to calculate the depletion of main isotopes concentrations. A core calculation associating neutronics and thermal-hydraulic codes lays stress on points we still have to study out. The most important of them is to take into account the control blade in the different calculation stages. (author)

  18. Gravity Effects in Microgap Flow Boiling

    Science.gov (United States)

    Robinson, Franklin; Bar-Cohen, Avram

    2017-01-01

    Increasing integration density of electronic components has exacerbated the thermal management challenges facing electronic system developers. The high power, heat flux, and volumetric heat generation of emerging devices are driving the transition from remote cooling, which relies on conduction and spreading, to embedded cooling, which facilitates direct contact between the heat-generating device and coolant flow. Microgap coolers employ the forced flow of dielectric fluids undergoing phase change in a heated channel between devices. While two phase microcoolers are used routinely in ground-based systems, the lack of acceptable models and correlations for microgravity operation has limited their use for spacecraft thermal management. Previous research has revealed that gravitational acceleration plays a diminishing role as the channel diameter shrinks, but there is considerable variation among the proposed gravity-insensitive channel dimensions and minimal research on rectangular ducts. Reliable criteria for achieving gravity-insensitive flow boiling performance would enable spaceflight systems to exploit this powerful thermal management technique and reduce development time and costs through reliance on ground-based testing. In the present effort, the authors have studied the effect of evaporator orientation on flow boiling performance of HFE7100 in a 218 m tall by 13.0 mm wide microgap cooler. Similar heat transfer coefficients and critical heat flux were achieved across five evaporator orientations, indicating that the effect of gravity was negligible.

  19. Development boiling to sprinkled tube bundle

    Directory of Open Access Journals (Sweden)

    Kracík Petr

    2016-01-01

    Full Text Available This paper presents results of a studied heat transfer coefficient at the surface of a sprinkled tube bundle where boiling occurs. Research in the area of sprinkled exchangers can be divided into two major parts. The first part is research on heat transfer and determination of the heat transfer coefficient at sprinkled tube bundles for various liquids, whether boiling or not. The second part is testing of sprinkle modes for various tube diameters, tube pitches and tube materials and determination of individual modes’ interface. All results published so far for water as the falling film liquid apply to one to three tubes for which the mentioned relations studied are determined in rigid laboratory conditions defined strictly in advance. The sprinkled tubes were not viewed from the operational perspective where there are more tubes and various modes may occur in different parts with various heat transfer values. The article focuses on these processes. The tube is located in a low-pressure chamber where vacuum is generated using an exhauster via ejector. The tube consists of smooth copper tubes of 12 mm diameter placed horizontally one above another.

  20. Unsteady heat transfer during subcooled film boiling

    Science.gov (United States)

    Yagov, V. V.; Zabirov, A. R.; Lexin, M. A.

    2015-11-01

    Cooling of high-temperature bodies in subcooled liquid is of importance for quenching technologies and also for understanding the processes initiating vapor explosion. An analysis of the available experimental information shows that the mechanisms governing heat transfer in these processes are interpreted ambiguously; a more clear-cut definition of the Leidenfrost temperature notion is required. The results of experimental observations (Hewitt, Kenning, and previous investigations performed by the authors of this article) allow us to draw a conclusion that there exists a special mode of intense heat transfer during film boil- ing of highly subcooled liquid. For revealing regularities and mechanisms governing intense transfer of energy in this process, specialists of Moscow Power Engineering Institute's (MPEI) Department of Engineering Thermal Physics conduct systematic works aimed at investigating the cooling of high-temperature balls made of different metals in water with a temperature ranging from 20 to 100°C. It has been determined that the field of temperatures that takes place in balls with a diameter of more than 30 mm in intense cooling modes loses its spherical symmetry. An approximate procedure for solving the inverse thermal conductivity problem for calculating the heat flux density on the ball surface is developed. During film boiling, in which the ball surface temperature is well above the critical level for water, and in which liquid cannot come in direct contact with the wall, the calculated heat fluxes reach 3-7 MW/m2.

  1. Development boiling to sprinkled tube bundle

    Science.gov (United States)

    Kracík, Petr; Pospíšil, Jiří

    2016-03-01

    This paper presents results of a studied heat transfer coefficient at the surface of a sprinkled tube bundle where boiling occurs. Research in the area of sprinkled exchangers can be divided into two major parts. The first part is research on heat transfer and determination of the heat transfer coefficient at sprinkled tube bundles for various liquids, whether boiling or not. The second part is testing of sprinkle modes for various tube diameters, tube pitches and tube materials and determination of individual modes' interface. All results published so far for water as the falling film liquid apply to one to three tubes for which the mentioned relations studied are determined in rigid laboratory conditions defined strictly in advance. The sprinkled tubes were not viewed from the operational perspective where there are more tubes and various modes may occur in different parts with various heat transfer values. The article focuses on these processes. The tube is located in a low-pressure chamber where vacuum is generated using an exhauster via ejector. The tube consists of smooth copper tubes of 12 mm diameter placed horizontally one above another.

  2. Zero boil-off system testing

    Science.gov (United States)

    Plachta, D. W.; Johnson, W. L.; Feller, J. R.

    2016-03-01

    Cryogenic propellants such as liquid hydrogen (LH2) and liquid oxygen (LO2) are a part of NASA's future space exploration plans due to their high specific impulse for rocket motors of upper stages. However, the low storage temperatures of LH2 and LO2 cause substantial boil-off losses for long duration missions. These losses can be eliminated by incorporating high performance cryocooler technology to intercept heat load to the propellant tanks and modulating the cryocooler temperature to control tank pressure. The technology being developed by NASA is the reverse turbo-Brayton cycle cryocooler and its integration to the propellant tank through a distributed cooling tubing network coupled to the tank wall. This configuration was recently tested at NASA Glenn Research Center in a vacuum chamber and cryoshroud that simulated the essential thermal aspects of low Earth orbit, its vacuum and temperature. This test series established that the active cooling system integrated with the propellant tank eliminated boil-off and robustly controlled tank pressure.

  3. Prospective Chemistry Teachers' Misconceptions about Colligative Properties: Boiling Point Elevation and Freezing Point Depression

    Science.gov (United States)

    Pinarbasi, Tacettin; Sozbilir, Mustafa; Canpolat, Nurtac

    2009-01-01

    This study aimed at identifying prospective chemistry teachers' misconceptions of colligative properties. In order to fulfill this aim, a diagnostic test composed of four open-ended questions was used. The test was administered to seventy-eight prospective chemistry teachers just before qualifying to teaching in secondary schools. Nine different…

  4. Boiling Heat Transfer Mechanisms in Earth and Low Gravity: Boundary Condition and Heater Aspect Ratio Effects

    Science.gov (United States)

    Kim, Jungho

    2004-01-01

    Boiling is a complex phenomenon where hydrodynamics, heat transfer, mass transfer, and interfacial phenomena are tightly interwoven. An understanding of boiling and critical heat flux in microgravity environments is of importance to space based hardware and processes such as heat exchange, cryogenic fuel storage and transportation, electronic cooling, and material processing due to the large amounts of heat that can be removed with relatively little increase in temperature. Although research in this area has been performed in the past four decades, the mechanisms by which heat is removed from surfaces in microgravity are still unclear. Recently, time and space resolved heat transfer data were obtained in both earth and low gravity environments using an array of microheaters varying in size between 100 microns to 700 microns. These heaters were operated in both constant temperature as well as constant heat flux mode. Heat transfer under nucleating bubbles in earth gravity were directly measured using a microheater array with 100 m resolution operated in constant temperature mode with low and high subcooled bulk liquid along with images from below and from the side. The individual bubble departure diameter and energy transfer were larger with low subcooling but the departure frequency increased at high subcooling, resulting in higher overall heat transfer. The bubble growth for both subcoolings was primarily due to energy transfer from the superheated liquid layer relatively little was due to wall heat transfer during the bubble growth process. Oscillating bubbles and sliding bubbles were also observed in highly subcooled boiling. Transient conduction and/or microconvection was the dominant heat transfer mechanism in the above cases. A transient conduction model was developed and compared with the experimental data with good agreement. Data was also obtained with the heater array operated in a constant heat flux mode and measuring the temperature distribution across

  5. A Development of Technical Specification of a Research Reactor with Plate Fuels Cooled by Upward Flow

    Energy Technology Data Exchange (ETDEWEB)

    Park, Sujin; Kim, Jeongeun; Kim, Hyeonil [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2016-10-15

    The contents of the TS(Technical Specifications) are definitions, safety limits, limiting safety system settings, limiting conditions for operation, surveillance requirements, design features, and administrative controls. TS for Nuclear Power Plants (NPPs) have been developed since many years until now. On the other hands, there are no applicable modernized references of TS for research reactors with many differences from NPPs in purpose and characteristics. Fuel temperature and Departure from Nuclear Boiling Ratio (DNBR) are being used as references from the thermal-hydraulic analysis point of view for determining whether the design of research reactors satisfies acceptance criteria for the nuclear safety or not. Especially for research reactors using plate-type fuels, fuel temperature and critical heat flux, however, are very difficult to measure during the reactor operation. This paper described the outline of main contents of a TS for open-pool research reactor with plate-type fuels using core cooling through passive systems, where acceptance criteria for nuclear safety such as CHF and fuel temperature cannot be directly measured, different from circumstances in NPPs. Thus, three independent variables instead of non-measurable acceptance criteria: fuel temperature and CHF are considered as safety limits, i.e., power, flow, and flow temperature.

  6. Production of dimethylfuran for liquid fuels from biomass-derived carbohydrates.

    Science.gov (United States)

    Román-Leshkov, Yuriy; Barrett, Christopher J; Liu, Zhen Y; Dumesic, James A

    2007-06-21

    Diminishing fossil fuel reserves and growing concerns about global warming indicate that sustainable sources of energy are needed in the near future. For fuels to be useful in the transportation sector, they must have specific physical properties that allow for efficient distribution, storage and combustion; these properties are currently fulfilled by non-renewable petroleum-derived liquid fuels. Ethanol, the only renewable liquid fuel currently produced in large quantities, suffers from several limitations, including low energy density, high volatility, and contamination by the absorption of water from the atmosphere. Here we present a catalytic strategy for the production of 2,5-dimethylfuran from fructose (a carbohydrate obtained directly from biomass or by the isomerization of glucose) for use as a liquid transportation fuel. Compared to ethanol, 2,5-dimethylfuran has a higher energy density (by 40 per cent), a higher boiling point (by 20 K), and is not soluble in water. This catalytic strategy creates a route for transforming abundant renewable biomass resources into a liquid fuel suitable for the transportation sector, and may diminish our reliance on petroleum.

  7. Influence of Pressure on Stable Film Boiling of Subcooled Liquid

    Science.gov (United States)

    Zabirov, A. R.; Yagov, V. V.; Kaban'kov, O. N.; Leksin, M. A.; Kanin, P. K.

    2016-11-01

    Film boiling of subcooled liquids is an integral part of the hardening process. Understanding of the mechanisms underlying film boiling is important for modeling processes in atomic power engineering and cryogenic technology. Stationary processes of film boiling of subcooled liquids under conditions of their free motion near cylindrical heaters, just as subcooled liquid turbulent flow past high-temperature surfaces, represent quite a different type of process. In cooling metal spheres heated to a high temperature by a subcooled water, a special regime of film boiling is observed (microbubble boiling) distinguished by high intensity of heat transfer. Such a regime has not been revealed up to now for nonaqueous liquids. The paper presents new experimental data on heat transfer regimes in cooling nickel spheres in subcooled isopropanol and perfluorohexane at pressures of up to 1 MPa. It has been established that stable film boiling is the main regime of heat transfer that accounts for the larger part of the total time of cooling. The regimes of highly intensive film boiling heat transfer were not observed in the entire range of operational parameters even in the case of extreme subcoolings of liquid below their saturation temperature (to 170 K). The intensity of heat transfer in stable film boiling increases noticeably with subcooling of a chilling liquid.

  8. Boiling treatment of ABS and PS plastics for flotation separation.

    Science.gov (United States)

    Wang, Chong-qing; Wang, Hui; Wu, Bao-xin; Liu, Qun

    2014-07-01

    A new physical method, namely boiling treatment, was developed to aid flotation separation of acrylonitrile-butadiene-styrene (ABS) and polystyrene (PS) plastics. Boiling treatment was shown to be effective in producing a hydrophilic surface on ABS plastic. Fourier Transform Infrared analysis was conducted to investigate the mechanism of boiling treatment of ABS. Surface rearrangement of polymer may be responsible for surface change of boiling treated ABS, and the selective influence of boiling treatment on the floatability of boiling treated plastics may be attributed to the difference in the molecular mobility of polymer chains. The effects of flotation time, frother concentration and particle size on flotation behavior of simple plastic were investigated. Based on flotation behavior of simple plastic, flotation separation of boiling treatment ABS and PS with different particle sizes was achieved efficiently. The purity of ABS and PS was up to 99.78% and 95.80%, respectively; the recovery of ABS and PS was up to 95.81% and 99.82%, respectively. Boiling treatment promotes the industrial application of plastics flotation and facilitates plastic recycling.

  9. Thermal-hydraulic performance of convective boiling jet array impingement

    Science.gov (United States)

    Jenkins, R.; De Brún, C.; Kempers, R.; Lupoi, R.; Robinson, A. J.

    2016-09-01

    Jet impingement boiling is investigated with regard to heat transfer and pressure drop performance using a novel laser sintered 3D printed jet impingement manifold design. Water was the working fluid at atmospheric pressure with inlet subcooling of 7oC. The convective boiling performance of the impinging jet system was investigated for a flat copper target surface for 2700≤Re≤5400. The results indicate that the heat transfer performance of the impinging jet is independent of Reynolds number for fully developed boiling. Also, the investigation of nozzle to plate spacing shows that low spacing delays the onset of nucleate boiling causing a superheat overshoot that is not observed with larger gaps. However, no sensitivity to the gap spacing was measured once boiling was fully developed. The assessment of the pressure drop performance showed that the design effectively transfers heat with low pumping power requirements. In particular, owing to the insensitivity of the heat transfer to flow rate during fully developed boiling, the coefficient of performance of jet impingement boiling in the fully developed boiling regime deteriorates with increased flow rate due to the increase in pumping power flux.

  10. Low-Flow Film Boiling Heat Transfer on Vertical Surfaces

    DEFF Research Database (Denmark)

    Munthe Andersen, J. G.; Dix, G. E.; Leonard, J. E.

    1976-01-01

    The phenomenon of film boiling heat transfer for high wall temperatures has been investigated. Based on the assumption of laminar flow for the film, the continuity, momentum, and energy equations for the vapor film are solved and a Bromley-type analytical expression for the heat transfer...... length, an average film boiling heat transfer coefficient is obtained....

  11. Critical heat flux in flow boiling in microchannels

    CERN Document Server

    Saha, Sujoy Kumar

    2015-01-01

    This Brief concerns the important problem of critical heat flux in flow boiling in microchannels. A companion edition in the SpringerBrief Subseries on Thermal Engineering and Applied Science to “Heat Transfer and Pressure Drop in Flow Boiling in Microchannels,” by the same author team, this volume is idea for professionals, researchers, and graduate students concerned with electronic cooling.

  12. Rewetting and Flow Film Boiling Along Hot Surface

    Institute of Scientific and Technical Information of China (English)

    王补宣Thermal Engineering Department; Tsinghua University; Beijing 100084; PRC; 彭晓峰

    1994-01-01

    The recent investigations on the rewettmg and film boiling of liquid flowing along a hot/heated surface are briefly reviewed and discussed.Some advanced theoretical analyses are conducted and new conclusions achieved.These investigations describe the fundamental characteristics of liquid flow boiling and further the complicated rewetting phenomena,and have resulted in considerable insight intothe mechanism.

  13. Explosive Boiling at Very Low Heat Fluxes: A Microgravity Phenomenon

    Science.gov (United States)

    Hasan, M. M.; Lin, C. S.; Knoll, R. H.; Bentz, M. D.

    1993-01-01

    The paper presents experimental observations of explosive boiling from a large (relative to bubble sizes) flat heating surface at very low heat fluxes in microgravity. The explosive boiling is characterized as either a rapid growth of vapor mass over the entire heating surface due to the flashing of superheated liquid or a violent boiling spread following the appearance of single bubbles on the heating surface. Pool boiling data with saturated Freon 113 was obtained in the microgravity environment of the space shuttle. The unique features of the experimental results are the sustainability of high liquid superheat for long periods and the occurrence of explosive boiling at low heat fluxes (0.2 to 1.2 kW/sq m). For a heat flux of 1.0 kW/sq m a wall superheat of 17.9 degrees C was attained in ten minutes of heating. This was followed by an explosive boiling accompanied with a pressure spike and a violent bulk liquid motion. However, at this heat flux the vapor blanketing the heating surface could not be sustained. Stable nucleate boiling continued following the explosive boiling.

  14. Prospective Primary School Teachers' Perceptions on Boiling and Freezing

    Science.gov (United States)

    Senocak, Erdal

    2009-01-01

    The aim of this study was to investigate the perceptions of prospective primary school teachers on the physical state of water during the processes of boiling and freezing. There were three stages in the investigation: First, open-ended questions concerning the boiling and freezing of water were given to two groups of prospective primary school…

  15. Direct Numerical Simulation and Visualization of Subcooled Pool Boiling

    Directory of Open Access Journals (Sweden)

    Tomoaki Kunugi

    2014-01-01

    Full Text Available A direct numerical simulation of the boiling phenomena is one of the promising approaches in order to clarify their heat transfer characteristics and discuss the mechanism. During these decades, many DNS procedures have been developed according to the recent high performance computers and computational technologies. In this paper, the state of the art of direct numerical simulation of the pool boiling phenomena during mostly two decades is briefly summarized at first, and then the nonempirical boiling and condensation model proposed by the authors is introduced into the MARS (MultiInterface Advection and Reconstruction Solver developed by the authors. On the other hand, in order to clarify the boiling bubble behaviors under the subcooled conditions, the subcooled pool boiling experiments are also performed by using a high speed and high spatial resolution camera with a highly magnified telescope. Resulting from the numerical simulations of the subcooled pool boiling phenomena, the numerical results obtained by the MARS are validated by being compared to the experimental ones and the existing analytical solutions. The numerical results regarding the time evolution of the boiling bubble departure process under the subcooled conditions show a very good agreement with the experimental results. In conclusion, it can be said that the proposed nonempirical boiling and condensation model combined with the MARS has been validated.

  16. Nanostructure of Metallic Particles in Light Water Reactor Used Nuclear Fuel

    Energy Technology Data Exchange (ETDEWEB)

    Buck, Edgar C. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Mausolf, Edward J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Mcnamara, Bruce K. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Soderquist, Chuck Z. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Schwantes, Jon M. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2015-03-11

    The extraordinary nano-structure of metallic particles in light water reactor fuels points to possible high reactivity through increased surface area and a high concentration of high energy defect sites. We have analyzed the metallic epsilon particles from a high burn-up fuel from a boiling water reactor using transmission electron microscopy and have observed a much finer nanostructure in these particles than has been reported previously. The individual round particles that varying in size between ~20 and ~50 nm appear to consist of individual crystallites on the order of 2-3 nm in diameter. It is likely that in-reactor irradiation induce displacement cascades results in the formation of the nano-structure. The composition of these metallic phases is variable yet the structure of the material is consistent with the hexagonal close packed structure of epsilon-ruthenium. These findings suggest that unusual catalytic behavior of these materials might be expected, particularly under accident conditions.

  17. Experimental investigation on fuel properties of biodiesel prepared from cottonseed oil

    Science.gov (United States)

    Payl, Ashish Naha; Mashud, Mohammad

    2017-06-01

    In recent time's world's energy demands are satisfied by coal, natural gas as well as petroleum though the prices of these are escalating. If this continues, global recession is unavoidable and diminution of world reserve accelerates undoubtedly. Recently, Biodiesel is found to be more sustainable, non-toxic and energy efficient alternative which is also biodegradable. The use of biofuels in compression ignition engines is now a contemplation attention in place of petrochemicals. In view of this, cottonseed oil is quite a favorable candidate as an alternative fuel. The present study covers the various aspects of biodiesels fuel prepared from cottonseed oil. In this work Biodiesel was prepared from cottonseed oil through transesterification process with methanol, using sodium hydroxide as catalyst. The fuel properties of cottonseed oil methyl esters, kinematic viscosity, flash point, density, calorific value, boiling point etc. were evaluated and discussed in the light of Conventional Diesel Fuel. The properties of biodiesel produced from cotton seed oil are quite close to that of diesel except from flash point. And so the methyl esters of cottonseed oil can be used in existing diesel engines without any modifications.

  18. Influence of the wettability on the boiling onset.

    Science.gov (United States)

    Bourdon, B; Rioboo, R; Marengo, M; Gosselin, E; De Coninck, J

    2012-01-17

    Experimental investigation of pool boiling is conducted in stationary conditions over very smooth bronze surfaces covered by a very thin layer of gold presenting various surface treatments to isolate the role of wettability. We show that even with surfaces presenting mean roughness amplitudes below 10 nm the role of surface topography is of importance. The study shows also that wettability alone can trigger the boiling and that the boiling position on the surface can be controlled by chemical grafting using for instance alkanethiol. Moreover, boiling curves, that is, heat flux versus the surface superheat (which is the difference between the solid surface temperature and the liquid saturation temperature), are recorded and enabled to quantify, for this case, the significant reduction of the superheat at the onset of incipient boiling due to wettability. © 2011 American Chemical Society

  19. Mechanistic Multidimensional Modeling of Forced Convection Boiling Heat Transfer

    Directory of Open Access Journals (Sweden)

    Michael Z. Podowski

    2009-01-01

    Full Text Available Due to the importance of boiling heat transfer in general, and boiling crisis in particular, for the analysis of operation and safety of both nuclear reactors and conventional thermal power systems, extensive efforts have been made in the past to develop a variety of methods and tools to evaluate the boiling heat transfer coefficient and to assess the onset of temperature excursion and critical heat flux (CHF at various operating conditions of boiling channels. The objective of this paper is to present mathematical modeling concepts behind the development of mechanistic multidimensional models of low-quality forced convection boiling, including the mechanisms leading to temperature excursion and the onset of CHF.

  20. Boiling in porous media; Ebullition en milieux poreux

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-11

    This conference day of the French society of thermal engineers was devoted to the analysis of heat transfers and fluid flows during boiling phenomena in porous media. This book of proceedings comprises 8 communications entitled: `boiling in porous medium: effect of natural convection in the liquid zone`; `numerical modeling of boiling in porous media using a `dual-fluid` approach: asymmetrical characteristic of the phenomenon`; `boiling during fluid flow in an induction heated porous column`; `cooling of corium fragment beds during a severe accident. State of the art and the SILFIDE experimental project`; `state of knowledge about the cooling of a particulates bed during a reactor accident`; `mass transfer analysis inside a concrete slab during fire resistance tests`; `heat transfers and boiling in porous media. Experimental analysis and modeling`; `concrete in accidental situation - influence of boundary conditions (thermal, hydric) - case studies`. (J.S.)

  1. Assessment of RANS at low Prandtl number and simulation of sodium boiling flows with a CMFD code

    Energy Technology Data Exchange (ETDEWEB)

    Mimouni, S., E-mail: stephane.mimouni@edf.fr; Guingo, M.; Lavieville, J.

    2017-02-15

    Highlights: • Modelling of boiling sodium flows in a multiphase flow solver. • Rod heated with a constant heat flux in a pipe liquid metal flow. • Sodium boiling flow around a rod heated with a constant heat. • Computations in progress in an assembly constituted of 19 pins equipped with a wrapped wire. - Abstract: In France, Sodium-cooled Fast Reactors (SFR) have recently received a renewed interest. In 2006, the decision was taken by the French Government to initiate research in order to build a first Generation IV prototype (called ASTRID) by 2020. The improvement in the safety of SFR is one of the key points in their conception. Accidental sequences may lead to a significant increase of reactivity. This is for instance the case when the sodium coolant is boiling within the fissile zone. As a consequence, incipient boiling superheat of sodium is an important parameter, as it can influence boiling process which may appear during some postulated accidents as the unexpected loss of flow (ULOF). The problem is that despite the reduction in core power, when boiling conditions are reached, the flow decreases progressively and vapour expands into the heating zone. A crucial investigating way is to optimize the design of the fissile assemblies of the core in order to lead to stable boiling during a ULOF accident, without voiding of the fissile zone. Moreover, in order to evaluate nuclear plant design and safety, a CFD tool has been developed at EDF in the framework of the nuclear industry. Advanced models dedicated to boiling flows have been implemented and validated against experimental data for ten years now including a wall law for boiling flows, wall transfer for nucleate boiling, turbulence and polydispersion model. This paper aims at evaluating the generalization of these models to SFR. At least two main issues are encountered. Firstly, at low Prandtl numbers such as those of liquid metal, classical approaches derived for unity or close to unity fail to

  2. Changes provoked by boiling, steaming and sous-vide cooking in the lipid and volatile profile of European sea bass.

    Science.gov (United States)

    Nieva-Echevarría, Bárbara; Manzanos, María J; Goicoechea, Encarnación; Guillén, María D

    2017-09-01

    This study aims to shed light on the changes provoked by boiling, steaming and sous-vide cooking on the lipids and volatile profile of farmed and wild European sea bass meat. None of the cooking techniques provoked changes due to hydrolytic or oxidation processes detectable by (1)H NMR on sea bass lipids. The lipid profile of main and minor lipidic components was maintained after cooking. However, study by SPME-GC/MS evidenced that steaming and sous-vide cooking modified the volatile profile of sea bass meat, especially in farmed specimens. The compounds generated came from the occurrence, to a very small extent, of lipid and protein degradation. By contrast, boiling scarcely modified the initial characteristics of raw sea bass. Thus, from a sensory point of view and considering the odour-active compounds generated, steaming and sous-vide cooking provoked more noticeable changes than boiling, especially in farmed sea bass meat. Copyright © 2017. Published by Elsevier Ltd.

  3. Cellulosic Biomass Sugars to Advantaged Jet Fuel – Catalytic Conversion of Corn Stover to Energy Dense, Low Freeze Point Paraffins and Naphthenes

    Energy Technology Data Exchange (ETDEWEB)

    Cortright, Randy [Virent, Inc., Madison, WI (United States)

    2015-07-31

    The purpose of this project was to demonstrate the technical and commercial feasibility of producing liquid fuels, particularly jet fuel, from lignocellulosic materials, such as corn stover. This project was led by Virent, Inc. (Virent) which has developed a novel chemical catalytic process (the BioForming® platform) capable of producing “direct replacement” liquid fuels from biomass-derived feedstocks. Virent has shown it is possible to produce an advantaged jet fuel from biomass that meets or exceeds specifications for commercial and military jet fuel through Fuel Readiness Level (FRL) 5, Process Validation. This project leveraged The National Renewable Energy Lab’s (NREL) expertise in converting corn stover to sugars via dilute acid pretreatment and enzymatic hydrolysis. NREL had previously developed this deconstruction technology for the conversion of corn stover to ethanol. In this project, Virent and NREL worked together to condition the NREL generated hydrolysate for use in Virent’s catalytic process through solids removal, contaminant reduction, and concentration steps. The Idaho National Laboratory (INL) was contracted in this project for the procurement, formatting, storage and analysis of corn stover and Northwestern University developed fundamental knowledge of lignin deconstruction that can help improve overall carbon recovery of the combined technologies. Virent conducted fundamental catalytic studies to improve the performance of the catalytic process and NREL provided catalyst characterization support. A technoeconomic analysis (TEA) was conducted at each stage of the project, with results from these analyses used to inform the direction of the project.

  4. High level disinfection of a home care device; to boil or not to boil?

    Science.gov (United States)

    Winthrop, K L; Homestead, N

    2012-03-01

    We developed a percutaneous electrical transducer for home therapy of chronic pain, a device that requires high level disinfection between uses. The utility of boiling water to provide high level disinfection was evaluated by inoculating transducer pads with potential skin pathogens (Staphylococcus aureus, Mycobacterium terrae, Pseudomonas aeruginosa, Candida albicans) and subjecting them to full immersion in water boiling at 4200 feet elevation (95 °C). Log10 reductions in colony-forming units (cfu) at 10 min were 7.1, >6.3 and >5.5 for S. aureus, P. aeruginosa and C. albicans, respectively, but only 4.6 for M. terrae. At 15 min the reductions had increased to 7.5, >6.8, >6.6 and >7.5 cfu, respectively.

  5. The Physics of Boiling at Burnout

    Science.gov (United States)

    Theofanous, T. G.; Tu, J. P.; Dinh, T. N.; Salmassi, T.; Dinh, A. T.; Gasljevic, K.

    2000-01-01

    The basic elements of a new experimental approach for the investigation of burnout in pool boiling are presented. The approach consists of the combined use of ultrathin (nano-scale) heaters and high speed infrared imaging of the heater temperature pattern as a whole, in conjunction with highly detailed control and characterization of heater morphology at the nano and micron scales. It is shown that the burnout phenomenon can be resolved in both space and time. Ultrathin heaters capable of dissipating power levels, at steady-state, of over 1 MW/square m are demonstrated. A separation of scales is identified and it is used to transfer the focus of attention from the complexity of the two-phase mixing layer in the vicinity of the heater to a micron-scaled microlayer and nucleation and associated film-disruption processes within it.

  6. Hybrid modelling of a sugar boiling process

    CERN Document Server

    Lauret, Alfred Jean Philippe; Gatina, Jean Claude

    2012-01-01

    The first and maybe the most important step in designing a model-based predictive controller is to develop a model that is as accurate as possible and that is valid under a wide range of operating conditions. The sugar boiling process is a strongly nonlinear and nonstationary process. The main process nonlinearities are represented by the crystal growth rate. This paper addresses the development of the crystal growth rate model according to two approaches. The first approach is classical and consists of determining the parameters of the empirical expressions of the growth rate through the use of a nonlinear programming optimization technique. The second is a novel modeling strategy that combines an artificial neural network (ANN) as an approximator of the growth rate with prior knowledge represented by the mass balance of sucrose crystals. The first results show that the first type of model performs local fitting while the second offers a greater flexibility. The two models were developed with industrial data...

  7. Heat transfer coeffcient for boiling carbon dioxide

    DEFF Research Database (Denmark)

    Knudsen, Hans Jørgen Høgaard; Jensen, Per Henrik

    1997-01-01

    transfer coefficient but the ratio between the measured and the calculated heat transfer coefficient is nearly constant and equal 1.9. With this factor the correlation predicts the measured data within 14% (RMS). The pressure drop is of the same order as the measuring uncertainty and the pressure drop has......Heat transfer coefficient and pressure drop for boiling carbon dioxide (R744) flowing in a horizontal pipe has been measured. The pipe is heated by condensing R22 outside the pipe. The heat input is supplied by an electrical heater wich evaporates the R22. With the heat flux assumed constant over...... the whole surface and with measured temperature difference between the inner surface and the evaporation temperature a mean heat transfer coefficient is calculated. The calculated heat transfer coefficient has been compared with the Chart Correlation of Shah. The Chart Correlation predicts too low heat...

  8. Nucleate boiling of halogenated coolants - correlation analysis; Ebulicao nucleada de refrigerantes halogenados: analise de correlacoes

    Energy Technology Data Exchange (ETDEWEB)

    Ribatski, Gherhardt; Jabardo, Jose M. Saiz [Sao Paulo Univ., Sao Carlos, SP (Brazil). Escola de Engenharia. Dept. de Engenharia Mecanica

    1998-07-01

    Present study has been focused on a literature of heat transfer under nucleate boiling conditions of halocarbon refrigerants and their mixtures with lubricating oil. Two kind of correlations regarding the heat transfer mechanism have been found: strictly empirical, based on a straight curve fitting of experimental data, and semi-empirical, based on the particular point of view of the author regarding the physical mechanism but still fitted with experimental data. As a general rule, it has been noted that correlations present significant discrepancies among each other, a result which mostly reflects the wide range of experimental conditions used as a reference. A similar trend has been observed with refrigerant/oil mixtures. Given the current status of halocarbon refrigerants for refrigeration applications, there is clearly a need for further research regarding the nucleate boiling phenomenon related to those compounds. (author)

  9. Validation of a multidimensional computational fluid dynamics model for subcooled flow boiling analysis

    Energy Technology Data Exchange (ETDEWEB)

    Braz Filho, Francisco A.; Caldeira, Alexandre D.; Borges, Eduardo M., E-mail: fbraz@ieav.cta.b, E-mail: alexdc@ieav.cta.b, E-mail: eduardo@ieav.cta.b [Instituto de Estudos Avancados (IEAv/CTA), Sao Jose dos Campos, SP (Brazil). Div. de Energia Nuclear

    2011-07-01

    In a heated vertical channel, the subcooled flow boiling regime occurs when the bulk fluid temperature is lower than the saturation temperature, but the fluid temperature reaches the saturation point near the channel wall. This phenomenon produces a significant increase in heat flux, limited by the critical heat flux. This study is particularly important to the thermal-hydraulics analysis of pressurized water reactors. The purpose of this work is the validation of a multidimensional model to analyze the subcooled flow boiling comparing the results with experimental data found in literature. The computational fluid dynamics code FLUENT was used with Eulerian multiphase model option. The calculated values of wall temperature in the liquid-solid interface presented an excellent agreement when compared to the experimental data. Void fraction calculations presented satisfactory results in relation to the experimental data in pressures of 15, 30 and 45 bars. (author)

  10. Using largest Lyapunov exponent to confirm the intrinsic stability of boiling water reactors

    Energy Technology Data Exchange (ETDEWEB)

    Gavilian-Moreno, Carlos [Iberdrola Generacion, S.A., Cofrentes Nuclear Power Plant, Project Engineering Department, Paraje le Plano S/N, Valencia (Spain); Espinosa-Paredes, Gilberto [Area de ingeniera en Recursos Energeticos, Universidad Autonoma Metropolitana-Iztapalapa, Mexico city (Mexico)

    2016-04-15

    The aim of this paper is the study of instability state of boiling water reactors with a method based in largest Lyapunov exponents (LLEs). Detecting the presence of chaos in a dynamical system is an important problem that is solved by measuring the LLE. Lyapunov exponents quantify the exponential divergence of initially close state-space trajectories and estimate the amount of chaos in a system. This method was applied to a set of signals from several nuclear power plant (NPP) reactors under commercial operating conditions that experienced instabilities events, apparently each of a different nature. Laguna Verde and Forsmark NPPs with in-phase instabilities, and Cofrentes NPP with out-of-phases instability. This study presents the results of intrinsic instability in the boiling water reactors of three NPPs. In the analyzed cases the limit cycle was not reached, which implies that the point of equilibrium exerts influence and attraction on system evolution.

  11. Effect of geometrical parameters of open microchannel surfaces on pool boiling heat transfer

    Directory of Open Access Journals (Sweden)

    Kaniowski Robert

    2017-01-01

    Full Text Available This study focuses on the effect of channel depth on the heat transfer coefficient during nucleate pool boiling. Experimental studies were performed for saturated deionized water, and Novec-649 as working fluids at atmospheric pressure. Copper surfaces were modified to form microchannels with different geometrical properties. The microchannels were from 0.2 mm to 0.4 mm deep, 0.3 mm wide and spaced every 0.1 mm. The experiment was conducted for increasing heat flux up to the critical heat flux point. The surface modification provided an appreciably higher heat transfer coefficient compared to the smooth surface for all boiling liquids. The maximum heat transfer coefficient obtained exceeded 60 kW/m2K.

  12. Evaluation of fuel properties for microalgae Spirulina platensis bio-diesel and its blends with Egyptian petro-diesel

    Directory of Open Access Journals (Sweden)

    Soha S.M. Mostafa

    2017-05-01

    In this study, the feasibility of biodiesel production from microalga Spirulina platensis has been investigated. The physico–chemical characteristics of the produced biodiesel were studied according to the standards methods of analysis (ASTM and evaluated according to their fuel properties as compared to Egyptian petro-diesel. Blends of microalgae biodiesel and petro-diesel (B2, B5, B10 and B20 were prepared on a volume basis and their physico–chemical characteristics have been also studied. The obtained results showed that; with the increase of biodiesel concentration in the blends; the viscosity, density, total acid number, initial boiling point, calorific value, flash point, cetane number and diesel index increase. While the pour point, cloud point, carbon residue and sulfur, ash and water contents decrease. The observed properties of the blends were within the recommended petro-diesel standard specifications and they are in favor of better engine performance.

  13. ELEVATION ON BOINLING POINT OF COFFE EXTRACT

    Directory of Open Access Journals (Sweden)

    J. Telis-Romero

    2002-03-01

    Full Text Available The rise in boiling point of coffee extract was experimentally measured at soluble solids concentrations in the range of 9.2 to 52.4ºBrix and pressures between 5.8 × 10³ and 9.4 × 10(4 Pa (abs.. Different approaches to representing experimental data, including the Dühring's rule, the Antoine equation and empirical models proposed in the literature were tested. In the range of 9.2 to 16.2ºBrix, the rise in boiling point was nearly independent of pressure, varying only with extract concentration. Considerable deviations of this behavior began to occur at concentrations higher than 16.2ºBrix. Experimental data could best be predicted by adjusting an empirical model which consists of a single equation that takes into account the dependence of rise in boiling point on pressure and concentration.

  14. 混合制冷工质核态沸腾的传热研究%Heat transfer in nucleate pool boiling of binary and ternary refrigerant mixtures

    Institute of Scientific and Technical Information of China (English)

    赵耀华; 刁彦华; 鹤田隆治; 西川日出男

    2004-01-01

    Heat transfer coefficients in nucleate pool boiling were measured on a horizontal copper surface for refrigerants,HFC-134a,HFC-32,and HFC-125,their binary and ternary mixtures under saturated conditions at 0.9MPa.Compared to pure components,both binary and ternary mixtures showed lower heat transfer coefficients.This deterioration was more pronounced as heat flux was increased.Experimental data were compared with some empirical and semi-empirical correlations available in literature.For binary mixture,the accuracy of the correlations varied considerably with mixtures and the heat flux.Experimental data for HFC-32/134a/125 were also compared with available correlated equation obtained by Thome.For ternary mixture,the boiling range of binary mixture composed by the pure fluids with the lowest and the medium boiling points,and their concentration difference had important effects on boiling heat transfer coefficients.

  15. A study of implementing In-Cycle-Shuffle strategy to a decommissioning boiling water reactor

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Chung-Yuan, E-mail: tuckjason@iner.gov.tw; Tung, Wu-Hsiung; Yaur, Shyun-Jung

    2017-06-15

    Highlights: • A loading pattern strategy ICS (In-Cycle-Shuffle) was implemented to the last cycle of the boiling water reactor. • The best power sharing distribution and ICS timing was found. • A new parameter “Burnup sharing” is presented to evaluate ICS strategy. - Abstract: In this paper, a loading pattern strategy In-Cycle-Shuffle (ICS) is implemented to the last cycle of the boiling water reactor (BWR) before decommissioning to save the fuel cycle cost. This method needs a core shutdown during the operation of a cycle to change the loading pattern to gain more reactivity. The reactivity model is used to model the ICS strategy in order to find out the best ICS timing and the optimum power sharing distribution before ICS and after ICS. Several parameters of reactivity model are modified and the effect of burnable poison, gadolinium (Gd), is considered in this research. Three cases are presented and it is found that the best ICS timing is at about two-thirds of total cycle length no matter the poisoning effect of Gd is considered or not. According to the optimum power sharing distribution result, it is suggested to decrease the once burnt power and increase the thrice burnt fuel power as much as possible before ICS. After ICS, it is suggested to increase the positive reactivity fuel power and decrease the thrice burnt fuel power as much as possible. A new parameter “Burnup sharing” is presented to evaluate the special case whose EOC power weighting factor and the burnup accumulation factor in the reactivity model are quite different.

  16. Study of plutonium disposition using existing GE advanced Boiling Water Reactors

    Energy Technology Data Exchange (ETDEWEB)

    1994-06-01

    The end of the cold war and the resulting dismantlement of nuclear weapons has resulted in the need for the US to dispose of 50 to 100 metric tons of excess of plutonium in a safe and proliferation resistant manner. A number of studies, including the recently released National Academy of Sciences (NAS) study, have recommended conversion of plutonium into spent nuclear fuel with its high radiation barrier as the best means of providing permanent conversion and long-term diversion resistance to this material. The NAS study ``Management and Disposition of Excess Weapons Plutonium identified Light Water Reactor spent fuel as the most readily achievable and proven form for the disposition of excess weapons plutonium. The study also stressed the need for a US disposition program which would enhance the prospects for a timely reciprocal program agreement with Russia. This summary provides the key findings of a GE study where plutonium is converted into Mixed Oxide (MOX) fuel and a typical 1155 MWe GE Boiling Water Reactor (BWR) is utilized to convert the plutonium to spent fuel. A companion study of the Advanced BWR has recently been submitted. The MOX core design work that was conducted for the ABWR enabled GE to apply comparable fuel design concepts and consequently achieve full MOX core loading which optimize plutonium throughput for existing BWRs.

  17. Transition boiling heat transfer and the film transition regime

    Science.gov (United States)

    Ramilison, J. M.; Lienhard, J. H.

    1987-01-01

    The Berenson (1960) flat-plate transition-boiling experiment has been recreated with a reduced thermal resistance in the heater, and an improved access to those portions of the transition boiling regime that have a steep negative slope. Tests have been made in Freon-113, acetone, benzene, and n-pentane boiling on horizontal flat copper heaters that have been mirror-polished, 'roughened', or teflon-coated. The resulting data reproduce and clarify certain features observed by Berenson: the modest surface finish dependence of boiling burnout, and the influence of surface chemistry on both the minimum heat flux and the mode of transition boiling, for example. A rational scheme of correlation yields a prediction of the heat flux in what Witte and Lienhard (1982) previously identified as the 'film-transition boiling' region. It is also shown how to calculate the heat flux at the boundary between the pure-film, and the film-transition, boiling regimes, as a function of the advancing contact angle.

  18. Research progresses and future directions on pool boiling heat transfer

    Directory of Open Access Journals (Sweden)

    M. Kumar

    2015-12-01

    Full Text Available This paper reviews the previous work carried on pool boiling heat transfer during heating of various liquids and commodities categorized as refrigerants and dielectric fluids, pure liquids, nanofluids, hydrocarbons and additive mixtures, as well as natural and synthetic colloidal solutions. Nucleate pool boiling is an efficient and effective method of boiling because high heat fluxes are possible with moderate temperature differences. It is characterized by the growth of bubbles on a heated surface. It occurs during boiling of liquids for excess temperature ranging from 5 to 30 °C in various processes related to high vaporization of liquid for specific purposes like sugarcane juice heating for jaggery making, milk heating for khoa making, steam generation, cooling of electronic equipments, refrigeration and etcetera. In this review paper, pool boiling method during heating of liquids for specific purpose is depicted. It is inferred that enhancement in pool boiling heat transfer is a challenging and complex task. Also, recent research and use of various correlations for natural convection pool boiling is reviewed.

  19. Transition boiling heat transfer and the film transition regime

    Science.gov (United States)

    Ramilison, J. M.; Lienhard, J. H.

    1987-01-01

    The Berenson (1960) flat-plate transition-boiling experiment has been recreated with a reduced thermal resistance in the heater, and an improved access to those portions of the transition boiling regime that have a steep negative slope. Tests have been made in Freon-113, acetone, benzene, and n-pentane boiling on horizontal flat copper heaters that have been mirror-polished, 'roughened', or teflon-coated. The resulting data reproduce and clarify certain features observed by Berenson: the modest surface finish dependence of boiling burnout, and the influence of surface chemistry on both the minimum heat flux and the mode of transition boiling, for example. A rational scheme of correlation yields a prediction of the heat flux in what Witte and Lienhard (1982) previously identified as the 'film-transition boiling' region. It is also shown how to calculate the heat flux at the boundary between the pure-film, and the film-transition, boiling regimes, as a function of the advancing contact angle.

  20. Prediction of nucleate boiling heat transfer on horizontal U-shaped heat exchanger submerged in a pool of water using MARS code

    Energy Technology Data Exchange (ETDEWEB)

    Jeon, Seong-Su [Department of Nuclear Thermal-hydraulic Research, FNC Technology Co., Ltd., 46, Tapsil-ro, Giheung-gu, Yongin-si 446-902, Gyeonggi-do (Korea, Republic of); Department of Nuclear Engineering, Seoul National University, Gwanak-gu, Seoul 151-744 (Korea, Republic of); Hong, Soon-Joon [Department of Nuclear Thermal-hydraulic Research, FNC Technology Co., Ltd., 46, Tapsil-ro, Giheung-gu, Yongin-si 446-902, Gyeonggi-do (Korea, Republic of); Cho, Hyoung-Kyu, E-mail: chohk@snu.ac.kr [Department of Nuclear Engineering, Seoul National University, Gwanak-gu, Seoul 151-744 (Korea, Republic of); Park, Goon-Cherl [Department of Nuclear Engineering, Seoul National University, Gwanak-gu, Seoul 151-744 (Korea, Republic of)

    2015-12-15

    . Process Des. Dev. 5 (3), 329) in MARS. A total of 366 data points were predicted with a mean deviation of 8.1%. Hence, the proposed nucleate boiling model appears to be usable to the reliable design and the safety analysis of the passive safety system using the best estimate codes.

  1. Correlation of rocket propulsion fuel properties with chemical composition using comprehensive two-dimensional gas chromatography with time-of-flight mass spectrometry followed by partial least squares regression analysis

    Energy Technology Data Exchange (ETDEWEB)

    Kehimkar, Benjamin; Hoggard, Jamin C.; Marney, Luke C.; Billingsley, Matthew; Fraga, Carlos G.; Bruno, Thomas J.; Synovec, Robert E.

    2014-01-31

    There is an increased need to more fully assess and control the composition of kerosene based rocket propulsion fuels, namely RP-1 and RP-2. In particular, it is crucial to be able to make better quantitative connections between the following three attributes: (a) fuel performance, (b) fuel properties (flash point, density, kinematic viscosity, net heat of combustion, hydrogen content, etc) and (c) the chemical composition of a given fuel (i.e., specific chemical compounds and compound classes present as a result of feedstock blending and processing). Indeed, recent efforts in predicting fuel performance through modeling put greater emphasis on detailed and accurate fuel properties and fuel compositional information. In this regard, advanced distillation curve (ADC) metrology provides improved data relative to classical boiling point and volatility curve techniques. Using ADC metrology, data obtained from RP-1 and RP-2 fuels provides compositional variation information that is directly relevant to predictive modeling of fuel performance. Often, in such studies, one-dimensional gas chromatography (GC) combined with mass spectrometry (MS) is typically employed to provide chemical composition information. Building on approaches using GC-MS, but to glean substantially more chemical composition information from these complex fuels, we have recently studied the use of comprehensive two dimensional gas chromatography combined with time-of-flight mass spectrometry (GC × GC - TOFMS) to provide chemical composition data that is significantly richer than that provided by GC-MS methods. In this report, by applying multivariate data analysis techniques, referred to as chemometrics, we are able to readily model (correlate) the chemical compositional information from RP-1 and RP-2 fuels provided using GC × GC - TOFMS, to the fuel property information such as that provided by the ADC method and other specification properties. We anticipate that this new chemical analysis

  2. Constant Boiling Substances,Constant Boiling Point and Constant Boiling Distillation of Alcohol%恒沸物、恒沸点与酒精恒沸蒸馏

    Institute of Scientific and Technical Information of China (English)

    金晶; 赵德炎; 赵德新; 赵开健

    2004-01-01

    酒精恒沸蒸馏是在有水酒精中加入第三种物质,如苯、戊烷、环己烷等,使水与添加物形成另一种恒沸物,并先行挥发,而得到无水酒精.该法在蒸馏时不需将原料全部汽化,也不需要很大回流比,只要能做到使新的恒沸物汽化即可,对设备规模的选型和能量消耗均有益.(陶然)

  3. Development of sodium boiling model, 'SOBOIL'

    Energy Technology Data Exchange (ETDEWEB)

    Chang, Won Pyo; Hahn, Do Hee

    2002-01-01

    The objective of this research is to develop an algorithm for the sodium boiling modeling, essential to the KALIMER HCDA Analysis. The basic theory is based on the 'Muti-slug Ejection Model' in SAS2A. It allows a finite number of bubbles in a channel at any time, and a formed bubble fills the whole cross section of the coolant channel except for liquid film left on the cladding surface. The essence of the model is to estimate the bubble pressure and temperature by balancing the bubble state change with the energy transfer into the bubble at both the wall and interfaces. It assumes that the bubble is saturated with a uniform pressure and temperature, and a bubble is generated when the coolant temperature exceeds a specified superheat. The period of the algorithm development has been divided into two phases. The algorithm development and application during the first phase is limited to the active fuel region where relatively simple physical phenomena are anticipated under ULOHS accident conditions in KALIMER, because it is favorable to the verification of the basic algorithm. The main revision is made during the 2nd phase to take into account mass transfer between the liquid film and bubble, bubble collapse, and coalescence as a liquid slug diminishes. In conclusion, the model represents the anticipated physical phenomena reasonably. The bubble has grown rapidly in consistence with the previous model predictions. Instability, however, is found in the wall heat transfer because the bubble size exceeds a certain value, over which the homogeneous model is no longer valid. Therefore, the model is expected to be improved by taking account of the pressure drop due to vapor flow inside such a large bubble to extend its applicability.

  4. Bubble Coalescence Heat Transfer During Subcooled Nucleate Pool Boiling

    Institute of Scientific and Technical Information of China (English)

    Abdoulaye Coulibaly; LIN Xipeng; Bi Jingliang; David M Christopher

    2012-01-01

    Bubble coalescence during subcooled nucleate pool boiling was investigated experimentally using constant wall temperature boundary conditions while the wall heat flux was measured at a various locations to understand the effects of coalescence on the heat transfer. The observations showed that the coalesced bubble moved and oscillated on the heater surface with significant heat transfer variations prior to departure. Some observations also showed coalescence with no increase in the heat transfer rate. The heat flux for boiling with coalescence fluctuated much more than for single bubble boiling due to the vaporization of the liquid layer trapped between the bubbles.

  5. Boiling Heat Transfer on Porous Surfaces with Vapor Channels

    Institute of Scientific and Technical Information of China (English)

    吴伟; 杜建华; 王补宣

    2002-01-01

    Boiling heat transfer on porous coated surfaces with vapor channels was investigated experimentally to determine the effects of the size and density of the vapor channels on the boiling heat transfer. Observations showed that bubbles escaping from the channels enhanced the heat transfer. Three regimes were identified: liquid flooding, bubbles in the channel and the bottom drying out region. The maximum heat transfer occurred for an optimum vapor channel density and the boiling heat transfer performance was increased if the channels were open to the bottom of the porous coating.

  6. Modeling of Heat Exchange with Developed Nucleate Boiling on Tenons

    Directory of Open Access Journals (Sweden)

    A. V. Оvsiannik

    2007-01-01

    Full Text Available The paper proposes a thermal and physical model for heat exchange processes with developed nucleate boiling on the developed surfaces (tenons with various contours of heat transfer surface. Dependences for calculating convective heat exchange factor have been obtained on the basis of modeling representation. Investigations have shown that an intensity of convective heat exchange does not depend on tenon profile when boiling takes place on the tenons. The intensity is determined by operating conditions, thermal and physical properties of liquid, internal characteristics of boiling processes and geometrical characteristics of a tenon.

  7. Experimental study on the explosive boiling in saturated liquid nitrogen

    Institute of Scientific and Technical Information of China (English)

    DONG Zhaoyi; HUAI Xiulan; LIU Dengying

    2005-01-01

    Studies on the heat-transfer characteristics of liquid nitrogen (LN2) have received increasing attention. When there is a transient high heatflux input to the LN2, explosive boiling may take place. In this paper, using the high-power short-duration pulsed laser heating method and the high-speed photography technology, the experimental result of explosive boiling in saturated LN2 is illustrated; and the two exclusive characteristics of explosive boiling in LN2: changeover time and the relative long-time adherence of the bubble cluster to the surface, are investigated.

  8. Subcooled boiling of nano-particle suspensions on Pt wires

    Institute of Scientific and Technical Information of China (English)

    LI Chunhui; WANG Buxuan; PENG Xiaofeng

    2004-01-01

    An experimental investigation is conducted to explore the subcooled boiling characteristics of nano-particle suspensions on Pt wires. Some phenomena are observed for the boiling of water-SiO2 nano-particle suspensions on Pt wires. The experiments show that there exist not any evident differences for boiling of pure water and of nano-particle suspensions at high heat fluxes. However, bubble overlap phenomenon can be easily found for nano-particle suspensions at low heat fluxes, which probably results from the increase of the attracter force between bubbles and of the bubble mass.

  9. Phenomenology of break-up modes in contact free externally heated nanoparticle laden fuel droplets

    Science.gov (United States)

    Pathak, Binita; Basu, Saptarshi

    2016-12-01

    We study thermally induced atomization modes in contact free (acoustically levitated) nanoparticle laden fuel droplets. The initial droplet size, external heat supplied, and suspended particle concentration (wt. %) in droplets govern the stability criterion which ultimately determines the dominant mode of atomization. Pure fuel droplets exhibit two dominant modes of breakup namely primary and secondary. Primary modes are rather sporadic and normally do not involve shape oscillations. Secondary atomization however leads to severe shape deformations and catastrophic intense breakup of the droplets. The dominance of these modes has been quantified based on the external heat flux, dynamic variation of surface tension, acoustic pressure, and droplet size. Addition of particles alters the regimes of the primary and secondary atomization and introduces bubble induced boiling and bursting. We analyze this new mode of atomization and estimate the time scale of bubble growth up to the point of bursting using energy balance to determine the criterion suitable for parent droplet rupture. All the three different modes of breakup have been well identified in a regime map determined in terms of Weber number and the heat utilization rate which is defined as the energy utilized for transient heating, vaporization, and boiling in droplets.

  10. An experimental investigation of liquid methane convection and boiling in rocket engine cooling channels

    Science.gov (United States)

    Trujillo, Abraham Gerardo

    In the past decades, interest in developing hydrocarbon-fueled rocket engines for deep spaceflight missions has continued to grow. In particular, liquid methane (LCH4) has been of interest due to the weight efficiency, storage, and handling advantages it offers over several currently used propellants. Deep space exploration requires reusable, long life rocket engines. Due to the high temperatures reached during combustion, the life of an engine is significantly impacted by the cooling system's efficiency. Regenerative (regen) cooling is presented as a viable alternative to common cooling methods such as film and dump cooling since it provides improved engine efficiency. Due to limited availability of experimental sub-critical liquid methane cooling data for regen engine design, there has been an interest in studying the heat transfer characteristics of the propellant. For this reason, recent experimental studies at the Center for Space Exploration Technology Research (cSETR) at the University of Texas at El Paso (UTEP) have focused on investigating the heat transfer characteristics of sub-critical CH4 flowing through sub-scale cooling channels. To conduct the experiments, the csETR developed a High Heat Flux Test Facility (HHFTF) where all the channels are heated using a conduction-based thermal concentrator. In this study, two smooth channels with cross sectional geometries of 1.8 mm x 4.1 mm and 3.2 mm x 3.2 mm were tested. In addition, three roughened channels all with a 3.2 mm x 3.2 mm square cross section were also tested. For the rectangular smooth channel, Reynolds numbers ranged between 68,000 and 131,000, while the Nusselt numbers were between 40 and 325. For the rough channels, Reynolds numbers ranged from 82,000 to 131,000, and Nusselt numbers were between 65 and 810. Sub-cooled film-boiling phenomena were confirmed for all the channels presented in this work. Film-boiling onset at Critical Heat Flux (CHF) was correlated to a Boiling Number (Bo) of

  11. Development of a novel infrared-based visualization technique to detect liquid-gas phase dynamics on boiling surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Hyung Dae [Kyunghee University, Yongin (Korea, Republic of)

    2011-05-15

    Complex two-phase heat transfer phenomena such as nucleate boiling, critical heat flux, quenching and condensation govern the thermal performance of Light Water Reactors (LWRs) under normal operation and during transients/accidents. These phenomena are typically characterized by the presence of a liquid vapor- solid contact line on the surface from/to which the heat is transferred. For example, in nucleate boiling, a significant fraction of the energy needed for bubble growth comes from evaporation of a liquid meniscus, or microlayer, underneath the bubble itself. As the liquid vapor- solid line at the edge of the meniscus retreats, a circular dry patch in the middle of the bubble is exposed; the speed of the triple line retreat is a measure of the ability of the surface to transfer heat to the bubble. At very high heat fluxes, near the upper limit of the nucleate boiling regime, also known as Critical Heat Flux (CHF), the situation is characterized by larger dry areas on the surface, dispersed within an interconnected network of liquid menisci. In quenching heat transfer, which refers to the rapid cooling of a very hot object by immersion in a cooler liquid, the process is initially dominated by film boiling. In film boiling a continuous vapor film completely separates the liquid phase from the solid surface: however, as the temperature gets closer to the Leidenfrost point, intermittent and short-lived liquid-solid contacts occur at discrete locations on the surface, thus creating liquid vapor- solid interfaces once again. Ultimately, if bubble nucleation ensues at such contact points, the vapor film is disrupted and the heat transfer regime transitions from film boiling to transition boiling. Finally, in dropwise condensation, the phase transition from vapor to liquid occurs via formation of discrete droplets on the surface, and the resulting liquid-vapor-solid triple line is where heat transfer is most intense. To gain insight into and enable mechanistic

  12. Qualification of helium measurement system for detection of fuel failures in a BWR

    Science.gov (United States)

    Larsson, I.; Sihver, L.; Loner, H.; Grundin, A.; Helmersson, J.-O.; Ledergerber, G.

    2014-05-01

    There are several methods for surveillance of fuel integrity during the operation of a boiling water reactor (BWR). The detection of fuel failures is usually performed by analysis of grab samples of off-gas and coolant activities, where a measured increased level of ionizing radiation serves as an indication of new failure or degradation of an already existing one. At some nuclear power plants the detection of fuel failures is performed by on-line nuclide specific measurements of the released fission gases in the off-gas system. However, it can be difficult to distinguish primary fuel failures from degradation of already existing failures. In this paper, a helium measuring system installed in connection to a nuclide specific measuring system to support detection of fuel failures and separate primary fuel failures from secondary ones is presented. Helium measurements provide valuable additional information to measurements of the gamma emitting fission gases for detection of primary fuel failures, since helium is used as a fill gas in the fuel rods during fabrication. The ability to detect fuel failures using helium measurements was studied by injection of helium into the feed water systems at the Forsmark nuclear power plant (NPP) in Sweden and at the nuclear power plant Leibstadt (KKL) in Switzerland. In addition, the influence of an off-gas delay line on the helium measurements was examined at KKL by injecting helium into the off-gas system. By using different injection rates, several types of fuel failures with different helium release rates were simulated. From these measurements, it was confirmed that the helium released by a failed fuel can be detected. It was also shown that the helium measurements for the detection of fuel failures should be performed at a sampling point located before any delay system. Hence, these studies showed that helium measurements can be useful to support detection of fuel failures. However, not all fuel failures which occurred at

  13. Experimental Investigation on the Effects of Coolant Concentration on Sub-Cooled Boiling and Crud Deposition on Reactor Cladding at Prototypical PWR Operating Conditions

    Energy Technology Data Exchange (ETDEWEB)

    Schultis, J., Kenneth; Fenton, Donald, L.

    2006-10-20

    Increasing demand for energy necessitates nuclear power units to increase power limits. This implies significant changes in the design of the core of the nuclear power units, therefore providing better performance and safety in operations. A major hindrance to the increase of nuclear reactor performance especially in Pressurized Deionized water Reactors (PWR) is Axial Offset Anomaly (AOA)--the unexpected change in the core axial power distribution during operation from the predicted distribution. This problem is thought to be occur because of precipitation and deposition of lithiated compounds like boric acid (H{sub 2}BO{sub 3}) and lithium metaborate (LiBO{sub 2}) on the fuel rod cladding. Deposited boron absorbs neutrons thereby affecting the total power distribution inside the reactor. AOA is thought to occur when there is sufficient build-up of crud deposits on the cladding during subcooled nucleate boiling. Predicting AOA is difficult as there is very little information regarding the heat and mass transfer during subcooled nucleate boiling. An experimental investigation was conducted to study the heat transfer characteristics during subcooled nucleate boiling at prototypical PWR conditions. Pool boiling tests were conducted with varying concentrations of lithium metaborate (LiBO{sub 2}) and boric acid (H{sub 2}BO{sub 3}) solutions in deionized water. The experimental data collected includes the effect of coolant concentration, subcooling, system pressure and heat flux on pool the boiling heat transfer coefficient. The analysis of particulate deposits formed on the fuel cladding surface during subcooled nucleate boiling was also performed. The results indicate that the pool boiling heat transfer coefficient degrades in the presence of boric acid and lithium metaborate compared to pure deionized water due to lesser nucleation. The pool boiling heat transfer coefficients decreased by about 24% for 5000 ppm concentrated boric acid solution and by 27% for 5000 ppm

  14. Experimental Investigation of the Influence of Fuel Viscosity on the Spray Characteristics of Diesel Nozzle

    Institute of Scientific and Technical Information of China (English)

    L(U) Xing-cai; QIAO Xin-qi; CHENG Jia; HUANG Zhen

    2007-01-01

    This paper presented an investigation of atomization characteristics including the velocity vector field and the mean droplet sizes for different percentages of DMM-diesel blended fuels using a phase doppler anemometry (PDA) analyzer system. Based on the fuel design concept, an oxygenated fuel named dimethoxy methane (DMM),which has lower viscosity, surface tension, and boiling point, was used to blend with diesel. The experiments were carried out under atmospheric conditions on a single-hole type diesel nozzle, liquid conditions comprise a temperature of 298 K under the needle valve opening pressure of 6 MPa. The results show that the sauter mean diameter (SMD) and spray cone angle of blended fuels decrease with the increase of DMM content; the axial mean velocity in the centerline increases with the increase of DMM. However, the spray behavior of blended fuel in which DMM exceeds 75% is virtually identical to that of neat DMM. The measurement also reveals the existence of an "S" shape in the radial mean velocity variations with radial distance.

  15. Numerical investigation on the characteristics of two-phase flow in fuel assemblies with spacer grid

    Energy Technology Data Exchange (ETDEWEB)

    Chen, D.; Yang, Z.; Zhong, Y.; Xiao, Y.; Hu, L. [Chongqing Univ. (China). Key Lab. of Low-grade Energy Utilization Technologies and Systems

    2016-07-15

    In pressurized water reactors (PWRs), the spacer grids of the fuel assembly has significant impact on the thermal-hydraulic performance of the fuel assembly. Particularly, the spacer grids with the mixing vanes can dramatically enhance the secondary flow and have significant effect on the void distribution in the fuel assembly. In this paper, the CFD study has been carried out to analyze the effects of the spacer grid with the steel contacts, dimples and mixing vanes on the boiling two-phase flow characteristics, such as the two-phase flow field, the void distribution, and so on. Considered the influence of the boiling phase change on two-phase flow, a boiling model was proposed and applied in the CFD simulation by using the UDF (User Defined Function) method. Furthermore, in order to analyze the effects of the spacer grid with mixing vanes, the adiabatic (without boiling) two-phase flow has also been investigated as comparison with the boiling two-phase flow in the fuel assembly with spacer grids. The CFD simulation on two-phase flow in the fuel assembly with the proposed boiling model can predict the characteristics of two-phase flow better.

  16. A Ghost Fluid/Level Set Method for boiling flows and liquid evaporation: Application to the Leidenfrost effect

    Energy Technology Data Exchange (ETDEWEB)

    Rueda Villegas, Lucia; Alis, Romain; Lepilliez, Mathieu; Tanguy, Sébastien, E-mail: tanguy@imft.fr

    2016-07-01

    The development of numerical methods for the direct numerical simulation of two-phase flows with phase change, in the framework of interface capturing or interface tracking methods, is the main topic of this study. We propose a novel numerical method, which allows dealing with both evaporation and boiling at the interface between a liquid and a gas. Indeed, in some specific situations involving very heterogeneous thermodynamic conditions at the interface, the distinction between boiling and evaporation is not always possible. For instance, it can occur for a Leidenfrost droplet; a water drop levitating above a hot plate whose temperature is much higher than the boiling temperature. In this case, boiling occurs in the film of saturated vapor which is entrapped between the bottom of the drop and the plate, whereas the top of the water droplet evaporates in contact of ambient air. The situation can also be ambiguous for a superheated droplet or at the contact line between a liquid and a hot wall whose temperature is higher than the saturation temperature of the liquid. In these situations, the interface temperature can locally reach the saturation temperature (boiling point), for instance near a contact line, and be cooler in other places. Thus, boiling and evaporation can occur simultaneously on different regions of the same liquid interface or occur successively at different times of the history of an evaporating droplet. Standard numerical methods are not able to perform computations in these transient regimes, therefore, we propose in this paper a novel numerical method to achieve this challenging task. Finally, we present several accuracy validations against theoretical solutions and experimental results to strengthen the relevance of this new method.

  17. Microgravity Boiling Enhancement Using Vibration-Based Fluidic Technologies

    Science.gov (United States)

    Smith, Marc K.; Glezer, Ari; Heffington, Samuel N.

    2002-11-01

    Thermal management is an important subsystem in many devices and technologies used in a microgravity environment. The increased power requirements of new Space technologies and missions mean that the capacity and efficiency of thermal management systems must be improved. The current work addresses this need through the investigation and development of a direct liquid immersion heat transfer cell for microgravity applications. The device is based on boiling heat transfer enhanced by two fluidic technologies developed at Georgia Tech. The first of these fluidic technologies, called vibration-induced bubble ejection, is shown in Fig. 1. Here, an air bubble in water is held against a vibrating diaphragm by buoyancy. The vibrations at 440 Hz induce violent oscillations of the air/water interface that can result in small bubbles being ejected from the larger air bubble (Fig. 1a) and, simultaneously, the collapse of the air/water interface against the solid surface (Fig. 1b). Both effects would be useful during a heat transfer process. Bubble ejection would force vapor bubbles back into the cooler liquid so that they can condense. Interfacial collapse would tend to keep the hot surface wet thereby increasing liquid evaporation and heat transfer to the bulk liquid. Figure 2 shows the effect of vibrating the solid surface at 7.6 kHz. Here, small-scale capillary waves appear on the surface of the bubble near the attachment point on the solid surface (the grainy region). The vibration produces a net force on the bubble that pushes it away from the solid surface. As a result, the bubble detaches from the solid and is propelled into the bulk liquid. This force works against buoyancy and so it would be even more effective in a microgravity environment. The benefit of the force in a boiling process would be to push vapor bubbles off the solid surface, thus helping to keep the solid surface wet and increasing the heat transfer. The second fluidic technology to be employed in this

  18. Numerical investigation of boiling heat transfer on the shell-side of spiral wound heat exchanger

    Science.gov (United States)

    Wu, Zhi-Yong; Wang, He; Cai, Wei-Hua; Jiang, Yi-Qiang

    2016-09-01

    The aim of this paper is to numerically study boiling heat transfer on the shell-side of spiral wound heat exchanger (SWHE). The physical model for the shell-side of SWHE is established and the volume of fluid (VOF) method is used in the calculation. For propane and ethane, there are thirty cases to be simulated . Through the comparison with experimental data, the cause which leads to the simulation distortion is found, and the satisfied results of calculation are finally achieved. The simulation results show that the VOF model can be adopted well to those calculations whose inlet quality are lower than 0.1 kg/kg, and the calculation deviations are generally within ±20 %. In falling film flow, the heat transfer performance for the shell-side of SWHE is primarily influenced by Reynolds number. The visualization of simulation results displays that the boiling bubbles have three flow directions, besides flowing down with liquid phase, one portion of bubbles flows reversely up, and another portion is blocked at axial gaps of coils where the heat transfer is reduced. The studies of boiling on the shell-side of SWHE not only reveal the characteristics of heat transfer, but also point out the improvement direction of SWHE.

  19. Numerical Prediction for Subcooled Boiling Flow of Liquid Nitrogen in a Vertical Tube with MUSIG Model

    Institute of Scientific and Technical Information of China (English)

    王斯民; 文键; 李亚梅; 杨辉著; 厉彦忠

    2013-01-01

    Multiple size group (MUSIG) model combined with a three-dimensional two-fluid model were em-ployed to predict subcooled boiling flow of liquid nitrogen in a vertical upward tube. Based on the mechanism of boiling heat transfer, some important bubble model parameters were amended to be applicable to the modeling of liquid nitrogen. The distribution of different discrete bubble classes was demonstrated numerically and the distribu-tion patterns of void fraction in the wall-heated tube were analyzed. It was found that the average void fraction in-creases nonlinearly along the axial direction with wall heat flux and it decreases with inlet mass flow rate and sub-cooled temperature. The local void fraction exhibited a U-shape distribution in the radial direction. The partition of the wall heat flux along the tube was obtained. The results showed that heat flux consumed on evaporation is the leading part of surface heat transfer at the rear region of subcooled boiling. The turning point in the pressure drop curve reflects the instability of bubbly flow. Good agreement was achieved on the local heat transfer coefficient against experimental measurements, which demonstrated the accuracy of the numerical model.

  20. 40 CFR 180.1056 - Boiled linseed oil; exemption from requirement of tolerance.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 23 2010-07-01 2010-07-01 false Boiled linseed oil; exemption from... From Tolerances § 180.1056 Boiled linseed oil; exemption from requirement of tolerance. Boiled linseed... “boiled linseed oil.” This exemption is limited to use on rice before edible parts form. ...

  1. Prediction of bubble detachment diameter in flow boiling based on force analysis

    Energy Technology Data Exchange (ETDEWEB)

    Chen Deqi [Key Laboratory of Low-grade Energy Utilization Technologies and Systems (Chongqing University), Ministry of Education, Chongqing 400044 (China); Pan Liangming, E-mail: cneng@cqu.edu.cn [Key Laboratory of Low-grade Energy Utilization Technologies and Systems (Chongqing University), Ministry of Education, Chongqing 400044 (China); Ren Song [Key Laboratory of Low-grade Energy Utilization Technologies and Systems (Chongqing University), Ministry of Education, Chongqing 400044 (China)

    2012-02-15

    Highlights: Black-Right-Pointing-Pointer All the forces acting on the growing bubbles are taken into account in the model. Black-Right-Pointing-Pointer The bubble contact diameter has significant effect on bubble detachment. Black-Right-Pointing-Pointer Bubble growth force and surface tension are more significant in narrow channel. Black-Right-Pointing-Pointer A good agreement between the predicted and the measured results is achieved. - Abstract: Bubble detachment diameter is one of the key parameters in the study of bubble dynamics and boiling heat transfer, and it is hard to be measured in a boiling system. In order to predict the bubble detachment diameter, a theoretical model is proposed based on forces analysis in this paper. All the forces acting on a bubble are taken into account to establish a model for different flow boiling configurations, including narrow and conventional channels, upward, downward and horizontal flows. A correlation of bubble contact circle diameter is adopted in this study, and it is found that the bubble contact circle diameter has significant effect on bubble detachment. A new correlation taking the bubble contact circle diameter into account for the evaluation of bubble growth force is proposed in this study, and it is found that the bubble growth force and surface tension force are more significant in narrow channel when comparing with that in conventional channel. A visual experiment was carried out in order to verify present model; and the experimental data from published literature are used also. A good agreement between predicted and measured results is achieved.

  2. Zero Boil Off System for Cryogen Storage Project

    Data.gov (United States)

    National Aeronautics and Space Administration — This work proposes to develop a zero boil off (ZBO) dewar using a two-stage pulse-tube cooler together with two innovative, continuous-flow cooling loops and an...

  3. Boiling local heat transfer enhancement in minichannels using nanofluids.

    Science.gov (United States)

    Chehade, Ali Ahmad; Gualous, Hasna Louahlia; Le Masson, Stephane; Fardoun, Farouk; Besq, Anthony

    2013-03-18

    This paper reports an experimental study on nanofluid convective boiling heat transfer in parallel rectangular minichannels of 800 μm hydraulic diameter. Experiments are conducted with pure water and silver nanoparticles suspended in water base fluid. Two small volume fractions of silver nanoparticles suspended in water are tested: 0.000237% and 0.000475%. The experimental results show that the local heat transfer coefficient, local heat flux, and local wall temperature are affected by silver nanoparticle concentration in water base fluid. In addition, different correlations established for boiling flow heat transfer in minichannels or macrochannels are evaluated. It is found that the correlation of Kandlikar and Balasubramanian is the closest to the water boiling heat transfer results. The boiling local heat transfer enhancement by adding silver nanoparticles in base fluid is not uniform along the channel flow. Better performances and highest effect of nanoparticle concentration on the heat transfer are obtained at the minichannels entrance.

  4. Boiling of HFE-7100 on a Straight Pin Fin

    Institute of Scientific and Technical Information of China (English)

    Z. W. Liu; W.W. Lin; D.J. Lee; J.P. Hsu

    2001-01-01

    This paper deals with an experimental investigation of pin fin boiling of saturated and subcooled HFE-7100 under atmospheric pressure. Fin base temperature and heat flux data are measured along with the fin tip temperature. The basic features of boiling stability of HFE-7100 boiling on pin fin had been reported for the first time. For a given liquid/heating surface combination there exist upper steady-state (USS) branch and lower steady-state (LSS)branch, and a large, unstable regime located in between. Zones with different stability characteristics are mapped according to boiling on fins with different aspect ratios. Liquid subcooling can largely enhance heat transfer performance. A longer fin can provide a safer operation.

  5. Smoothed particle hydrodynamics simulations of evaporation and explosive boiling of liquid drops in microgravity

    Science.gov (United States)

    Sigalotti, Leonardo Di G.; Troconis, Jorge; Sira, Eloy; Peña-Polo, Franklin; Klapp, Jaime

    2015-07-01

    The rapid evaporation and explosive boiling of a van der Waals (vdW) liquid drop in microgravity is simulated numerically in two-space dimensions using the method of smoothed particle hydrodynamics. The numerical approach is fully adaptive and incorporates the effects of surface tension, latent heat, mass transfer across the interface, and liquid-vapor interface dynamics. Thermocapillary forces are modeled by coupling the hydrodynamics to a diffuse-interface description of the liquid-vapor interface. The models start from a nonequilibrium square-shaped liquid of varying density and temperature. For a fixed density, the drop temperature is increased gradually to predict the point separating normal boiling at subcritical heating from explosive boiling at the superheat limit for this vdW fluid. At subcritical heating, spontaneous evaporation produces stable drops floating in a vapor atmosphere, while at near-critical heating, a bubble is nucleated inside the drop, which then collapses upon itself, leaving a smaller equilibrated drop embedded in its own vapor. At the superheat limit, unstable bubble growth leads to either fragmentation or violent disruption of the liquid layer into small secondary drops, depending on the liquid density. At higher superheats, explosive boiling occurs for all densities. The experimentally observed wrinkling of the bubble surface driven by rapid evaporation followed by a Rayleigh-Taylor instability of the thin liquid layer and the linear growth of the bubble radius with time are reproduced by the simulations. The predicted superheat limit (Ts≈0.96 ) is close to the theoretically derived value of Ts=1 at zero ambient pressure for this vdW fluid.

  6. Smoothed particle hydrodynamics simulations of evaporation and explosive boiling of liquid drops in microgravity.

    Science.gov (United States)

    Sigalotti, Leonardo Di G; Troconis, Jorge; Sira, Eloy; Peña-Polo, Franklin; Klapp, Jaime

    2015-07-01

    The rapid evaporation and explosive boiling of a van der Waals (vdW) liquid drop in microgravity is simulated numerically in two-space dimensions using the method of smoothed particle hydrodynamics. The numerical approach is fully adaptive and incorporates the effects of surface tension, latent heat, mass transfer across the interface, and liquid-vapor interface dynamics. Thermocapillary forces are modeled by coupling the hydrodynamics to a diffuse-interface description of the liquid-vapor interface. The models start from a nonequilibrium square-shaped liquid of varying density and temperature. For a fixed density, the drop temperature is increased gradually to predict the point separating normal boiling at subcritical heating from explosive boiling at the superheat limit for this vdW fluid. At subcritical heating, spontaneous evaporation produces stable drops floating in a vapor atmosphere, while at near-critical heating, a bubble is nucleated inside the drop, which then collapses upon itself, leaving a smaller equilibrated drop embedded in its own vapor. At the superheat limit, unstable bubble growth leads to either fragmentation or violent disruption of the liquid layer into small secondary drops, depending on the liquid density. At higher superheats, explosive boiling occurs for all densities. The experimentally observed wrinkling of the bubble surface driven by rapid evaporation followed by a Rayleigh-Taylor instability of the thin liquid layer and the linear growth of the bubble radius with time are reproduced by the simulations. The predicted superheat limit (T(s)≈0.96) is close to the theoretically derived value of T(s)=1 at zero ambient pressure for this vdW fluid.

  7. Visualization of boiling flow structure in a natural circulation boiling loop

    Energy Technology Data Exchange (ETDEWEB)

    Karmakar, Arnab; Paruya, Swapan, E-mail: swapanparuya@gmail.com

    2015-04-15

    Highlights: • Vapor–liquid jet flows in natural circulation boiling loop. • Flow patterns and their transitions during geysering instability in the loop. • Evaluation of the efficiency of the needle probe in detecting the vapor–liquid and boiling flow structure. - Abstract: The present study reports vapor–liquid jet flows, flow patterns and their transitions during geysering instability in a natural circulation boiling loop under varied inlet subcooling ΔT{sub sub} (30–50 °C) and heater power Q (4–5 kW). Video imaging, voltage measurement using impedance needle probe, measurement of local pressure and loop flow rate have been carried out in this study. Power spectra of the voltage, the pressure and the flow rate reveal that at a high ΔT{sub sub} the jet flows have long period (21.36–86.95 s) and they are very irregular with a number of harmonics. The period decreases and becomes regular with a decrease of ΔT{sub sub}. The periods of the jet flows at ΔT{sub sub} = 30–50 °C and Q = 4 kW are in close agreement with those obtained from the video imaging. The probe was found to be more efficient than the pressure sensor in detecting the jet flows within an uncertainty of 9.5% and in detecting a variety of bubble classes. Both the imaging and the probe consistently identify the bubbly flow/vapor-mushrooms transition or the bubbly flow/slug flow transition on decreasing ΔT{sub sub} or on increasing Q.

  8. Taylor stability of viscous fluids with application to film boiling

    Science.gov (United States)

    Dhir, V. K.; Lienhard, J. H.

    1973-01-01

    The dispersion relation is evaluated numerically for Taylor waves in a viscous unstable interface with surface tension. The solution takes account of transverse curvature and the numerical evaluations apply to horizontal cylindrical, as well as to plane, interfaces. The result is verified with frequency and wavelength data obtained during film boiling on horizontal wires. A very general empirical correlation is given, en passant, for the vapor blanket thickness during film boiling.

  9. Heat transfer and pressure drop in flow boiling in microchannels

    CERN Document Server

    Saha, Sujoy Kumar

    2016-01-01

    This Brief addresses the phenomena of heat transfer and pressure drop in flow boiling in micro channels occurring in high heat flux electronic cooling. A companion edition in the Springer Brief Subseries on Thermal Engineering and Applied Science to “Critical Heat Flux in Flow Boiling in Micro channels,” by the same author team, this volume is idea for professionals, researchers and graduate students concerned with electronic cooling.

  10. Nucleate Boiling Heat Transfer Studied Under Reduced-Gravity Conditions

    Science.gov (United States)

    Chao, David F.; Hasan, Mohammad M.

    2000-01-01

    Boiling is known to be a very efficient mode of heat transfer, and as such, it is employed in component cooling and in various energy-conversion systems. In space, boiling heat transfer may be used in thermal management, fluid handling and control, power systems, and on-orbit storage and supply systems for cryogenic propellants and life-support fluids. Recent interest in the exploration of Mars and other planets and in the concept of in situ resource utilization on the Martian and Lunar surfaces highlights the need to understand how gravity levels varying from the Earth's gravity to microgravity (1g = or > g/g(sub e) = or > 10(exp -6)g) affect boiling heat transfer. Because of the complex nature of the boiling process, no generalized prediction or procedure has been developed to describe the boiling heat transfer coefficient, particularly at reduced gravity levels. Recently, Professor Vijay K. Dhir of the University of California at Los Angeles proposed a novel building-block approach to investigate the boiling phenomena in low-gravity to microgravity environments. This approach experimentally investigates the complete process of bubble inception, growth, and departure for single bubbles formed at a well-defined and controllable nucleation site. Principal investigator Professor Vijay K. Dhir, with support from researchers from the NASA Glenn Research Center at Lewis Field, is performing a series of pool boiling experiments in the low-gravity environments of the KC 135 microgravity aircraft s parabolic flight to investigate the inception, growth, departure, and merger of bubbles from single- and multiple-nucleation sites as a function of the wall superheat and the liquid subcooling. Silicon wafers with single and multiple cavities of known characteristics are being used as test surfaces. Water and PF5060 (an inert liquid) were chosen as test liquids so that the role of surface wettability and the magnitude of the effect of interfacial tension on boiling in reduced

  11. Self-Sustaining Thorium Boiling Water Reactors

    Energy Technology Data Exchange (ETDEWEB)

    Greenspan, Ehud [Univ. of California, Berkeley, CA (United States); Gorman, Phillip M. [Univ. of California, Berkeley, CA (United States); Bogetic, Sandra [Univ. of California, Berkeley, CA (United States); Seifried, Jeffrey E. [Univ. of California, Berkeley, CA (United States); Zhang, Guanheng [Univ. of California, Berkeley, CA (United States); Varela, Christopher R. [Univ. of California, Berkeley, CA (United States); Fratoni, Massimiliano [Univ. of California, Berkeley, CA (United States); Vijic, Jasmina J. [Univ. of California, Berkeley, CA (United States); Downar, Thomas [Univ. of Michigan, Ann Arbor, MI (United States); Hall, Andrew [Univ. of Michigan, Ann Arbor, MI (United States); Ward, Andrew [Univ. of Michigan, Ann Arbor, MI (United States); Jarrett, Michael [Univ. of Michigan, Ann Arbor, MI (United States); Wysocki, Aaron [Univ. of Michigan, Ann Arbor, MI (United States); Xu, Yunlin [Univ. of Michigan, Ann Arbor, MI (United States); Kazimi, Mujid [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Shirvan, Koroush [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Mieloszyk, Alexander [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Todosow, Michael [Brookhaven National Lab. (BNL), Upton, NY (United States); Brown, Nicolas [Brookhaven National Lab. (BNL), Upton, NY (United States); Cheng, Lap [Brookhaven National Lab. (BNL), Upton, NY (United States)

    2015-03-15

    The primary objectives of this project are to: Perform a pre-conceptual design of a core for an alternative to the Hitachi proposed fuel-self- sustaining RBWR-AC, to be referred to as a RBWR-Th. The use of thorium fuel is expected to assure negative void coefficient of reactivity (versus positive of the RBWR-AC) and improve reactor safety; Perform a pre-conceptual design of an alternative core to the Hitachi proposed LWR TRU transmuting RBWR-TB2, to be referred to as the RBWR-TR. In addition to improved safety, use of thorium for the fertile fuel is expected to improve the TRU transmutation effectiveness; Compare the RBWR-Th and RBWR-TR performance against that of the Hitachi RBWR core designs and sodium cooled fast reactor counterparts - the ARR and ABR; and, Perform a viability assessment of the thorium-based RBWR design concepts to be identified along with their associated fuel cycle, a technology gap analysis, and a technology development roadmap. A description of the work performed and of the results obtained is provided in this Overview Report and, in more detail, in the Attachments. The major findings of the study are summarized.

  12. Infrared thermometry study of nanofluid pool boiling phenomena

    Directory of Open Access Journals (Sweden)

    Hu Lin-wen

    2011-01-01

    Full Text Available Abstract Infrared thermometry was used to obtain first-of-a-kind, time- and space-resolved data for pool boiling phenomena in water-based nanofluids with diamond and silica nanoparticles at low concentration (<0.1 vol.%. In addition to macroscopic parameters like the average heat transfer coefficient and critical heat flux [CHF] value, more fundamental parameters such as the bubble departure diameter and frequency, growth and wait times, and nucleation site density [NSD] were directly measured for a thin, resistively heated, indium-tin-oxide surface deposited onto a sapphire substrate. Consistent with other nanofluid studies, the nanoparticles caused deterioration in the nucleate boiling heat transfer (by as much as 50% and an increase in the CHF (by as much as 100%. The bubble departure frequency and NSD were found to be lower in nanofluids compared with water for the same wall superheat. Furthermore, it was found that a porous layer of nanoparticles built up on the heater surface during nucleate boiling, which improved surface wettability compared with the water-boiled surfaces. Using the prevalent nucleate boiling models, it was possible to correlate this improved surface wettability to the experimentally observed reductions in the bubble departure frequency, NSD, and ultimately to the deterioration in the nucleate boiling heat transfer and the CHF enhancement.

  13. Infrared thermometry study of nanofluid pool boiling phenomena.

    Science.gov (United States)

    Gerardi, Craig; Buongiorno, Jacopo; Hu, Lin-Wen; McKrell, Thomas

    2011-03-16

    Infrared thermometry was used to obtain first-of-a-kind, time- and space-resolved data for pool boiling phenomena in water-based nanofluids with diamond and silica nanoparticles at low concentration (heat transfer coefficient and critical heat flux [CHF] value, more fundamental parameters such as the bubble departure diameter and frequency, growth and wait times, and nucleation site density [NSD] were directly measured for a thin, resistively heated, indium-tin-oxide surface deposited onto a sapphire substrate. Consistent with other nanofluid studies, the nanoparticles caused deterioration in the nucleate boiling heat transfer (by as much as 50%) and an increase in the CHF (by as much as 100%). The bubble departure frequency and NSD were found to be lower in nanofluids compared with water for the same wall superheat. Furthermore, it was found that a porous layer of nanoparticles built up on the heater surface during nucleate boiling, which improved surface wettability compared with the water-boiled surfaces. Using the prevalent nucleate boiling models, it was possible to correlate this improved surface wettability to the experimentally observed reductions in the bubble departure frequency, NSD, and ultimately to the deterioration in the nucleate boiling heat transfer and the CHF enhancement.

  14. Electrohydrodynamics of boiling on microstructured surfaces for space applications

    Science.gov (United States)

    Saccone, Giacomo; Moran, Jeffrey L.; Bucci, Matteo; Buongiorno, Jacopo; di Marco, Paolo; Mit-Nuclear Science; Engineering Team; University Of Pisa-Destec Dept. Team

    2016-11-01

    Surface wettability is a major parameter in boiling heat transfer. It affects the departure of bubbles from the boiling surface and consequently determines the maximum heat flux transferrable in safe conditions, known as critical heat flux (CHF). Surface wettability can be enhanced through passive techniques, including micro-engineered surfaces and coatings, or through active techniques, e.g. by applying a tunable electric field (electrowetting) that modifies the bubble shape in such a way as to drive bubble detachment. The latter technique is particularly interesting for space applications, where the electric field is used to create a body force that compensates for the absence of gravity. The present work is focused on boiling heat transfer on surfaces whose wettability has been modified by passive and active techniques. We have built a pool boiling apparatus composed of a micro-structured heater acting as boiling surface and an axisymmetric electrode High-speed optical and infrared imaging have been used to investigate the dynamics of boiling phenomena. The aims of this project are twofold: to achieve a superior understanding of wetting phenomena, and to improve the efficiency of cooling devices for space applications.

  15. Survey of Thermal-Fluids Evaluation and Confirmatory Experimental Validation Requirements of Accident Tolerant Cladding Concepts with Focus on Boiling Heat Transfer Characteristics

    Energy Technology Data Exchange (ETDEWEB)

    Brown, Nicholas R. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Wysocki, Aaron J. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Terrani, Kurt A. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Ali, Amir [Univ. of New Mexico, Albuquerque, NM (United States); Liu, Maolong [Univ. of New Mexico, Albuquerque, NM (United States); Blandford, Edward [Univ. of New Mexico, Albuquerque, NM (United States)

    2016-06-01

    The U.S. Department of Energy Office of Nuclear Energy (DOE-NE) Advanced Fuels Campaign (AFC) is working closely with the nuclear industry to develop fuel and cladding candidates with potentially enhanced accident tolerance, also known as accident tolerant fuel (ATF). Thermal-fluids characteristics are a vital element of a holistic engineering evaluation of ATF concepts. One vital characteristic related to boiling heat transfer is the critical heat flux (CHF). CHF plays a vital role in determining safety margins during normal operation and also in the progression of potential transient or accident scenarios. This deliverable is a scoping survey of thermal-fluids evaluation and confirmatory experimental validation requirements of accident tolerant cladding concepts with a focus on boiling heat transfer characteristics. The key takeaway messages of this report are: 1. CHF prediction accuracy is important and the correlations may have significant uncertainty. 2. Surface conditions are important factors for CHF, primarily the wettability that is characterized by contact angle. Smaller contact angle indicates greater wettability, which increases the CHF. Surface roughness also impacts wettability. Results in the literature for pool boiling experiments indicate changes in CHF by up to 60% for several ATF cladding candidates. 3. The measured wettability of FeCrAl (i.e., contact angle and roughness) indicates that CHF should be investigated further through pool boiling and flow boiling experiments. 4. Initial measurements of static advancing contact angle and surface roughness indicate that FeCrAl is expected to have a higher CHF than Zircaloy. The measured contact angle of different FeCrAl alloy samples depends on oxide layer thickness and composition. The static advancing contact angle tends to decrease as the oxide layer thickness increases.

  16. Disposal of spent nuclear fuel

    Energy Technology Data Exchange (ETDEWEB)

    1979-12-01

    This report addresses the topic of the mined geologic disposal of spent nuclear fuel from Pressurized Water Reactors (PWR) and Boiling Water Reactors (BWR). Although some fuel processing options are identified, most of the information in this report relates to the isolation of spent fuel in the form it is removed from the reactor. The characteristics of the waste management system and research which relate to spent fuel isolation are discussed. The differences between spent fuel and processed HLW which impact the waste isolation system are defined and evaluated for the nature and extent of that impact. What is known and what needs to be determined about spent fuel as a waste form to design a viable waste isolation system is presented. Other waste forms and programs such as geologic exploration, site characterization and licensing which are generic to all waste forms are also discussed. R and D is being carried out to establish the technical information to develop the methods used for disposal of spent fuel. All evidence to date indicates that there is no reason, based on safety considerations, that spent fuel should not be disposed of as a waste.

  17. Preliminary Calculation on a Spent Fuel Pool Accident using GOTHIC

    Energy Technology Data Exchange (ETDEWEB)

    Park, Jaehwan; Choi, Yu Jung; Hong, Tae Hyub; Kim, Hyeong-Taek [KHNP-CRI, Daejeon (Korea, Republic of)

    2015-10-15

    The probability of an accident happening at the spent fuel pool was believed to be quite low until the 2011 Fukushima accident occurred. Notably, large amount of spent fuel are normally stored in the spent fuel pool for a long time compared to the amount of fuel in the reactor core and the total heat released from the spent fuel is high enough to boil the water of the spent fuel pool when the cooling system does not operate. In addition, the enrichment and the burnup of the fuel have both increased in the past decade and heat generation from the spent fuel thereby has also increased. The failure of the cooling system at the spent fuel pool (hereafter, a loss-of-cooling accident) is one of the principal hypothetical causes of an accident that could occur at the spent fuel pool. In this paper, the preliminary calculation of a loss-of-cooling accident was performed. In this paper, the preliminary calculation of a loss-of cooling accident was performed with GOTHIC. The calculation results show boiling away of water in the spent fuel pool due to the loss-of-cooling accident and similar thermal performance of the spent fuel pool with previous research results.

  18. Complete Numerical Simulation of Subcooled Flow Boiling in the Presence of Thermal and Chemical Interactions

    Energy Technology Data Exchange (ETDEWEB)

    V.K. Dhir

    2003-04-28

    At present, guidelines for fuel cycle designs to prevent axial offset anomalies (AOA) in pressurized water reactor (PWR) cores are based on empirical data from several operating reactors. Although the guidelines provide an ad-hoc solution to the problem, a unified approach based on simultaneous modeling of thermal-hydraulics, chemical, and nuclear interactions with vapor generation at the fuel cladding surface does not exist. As a result, the fuel designs are overly constrained with a resulting economic penalty. The objective of present project is to develop a numerical simulation model supported by laboratory experiments that can be used for fuel cycle design with respect to thermal duty of the fuel to avoid economic penalty, as well as, AOA. At first, two-dimensional numerical simulation of the growth and departure of a bubble in pool boiling with chemical interaction is considered. A finite difference scheme is used to solve the equations governing conservation of mass, momentum, energy, and species concentration. The Level Set method is used to capture the evolving liquid-vapor interface. A dilute aqueous boron solution is considered in the simulation. From numerical simulations, the dynamic change in concentration distribution of boron during the bubble growth shows that the precipitation of boron can occur near the advancing and receding liquid-vapor interface when the ambient boron concentration level is 3,000 ppm by weight. Secondly, a complete three-dimensional numerical simulation of inception, growth and departure of a single bubble subjected to forced flow parallel to the heater surface was developed. Experiments on a flat plate heater with water and with boron dissolved in the water were carried out. The heater was made out of well-polished silicon wafer. Numbers of nucleation sites and their locations were well controlled. Bubble dynamics in great details on an isolated nucleation site were obtained while varying the wall superheat, liquid subcooling

  19. Void fraction prediction in saturated flow boiling

    Energy Technology Data Exchange (ETDEWEB)

    Francisco J Collado [Dpto de Ingenieria Mecanica-Motores Termicos, CPS-B, Universidad de Zaragoza, Maria de Luna 50018-Zaragoza (Spain)

    2005-07-01

    Full text of publication follows: An essential element in thermal-hydraulics is the accurate prediction of the vapor void fraction, or fraction of the flow cross-sectional area occupied by steam. Recently, the author has suggested to calculate void fraction working exclusively with thermodynamic properties. It is well known that the usual 'flow' quality, merely a mass flow rate ratio, is not at all a thermodynamic property because its expression in function of thermodynamic properties includes the slip ratio, which is a parameter of the process not a function of state. By the other hand, in the classic and well known expression of the void fraction - in function of the true mass fraction of vapor (also called 'static' quality), and the vapor and liquid densities - does not appear the slip ratio. Of course, this would suggest a direct procedure for calculating the void fraction, provided we had an accurate value of the true mass fraction of vapor, clearly from the heat balance. However the classic heat balance is usually stated in function of the 'flow' quality, what sounds really contradictory because this parameter, as we have noted above, is not at all a thermodynamic property. Then we should check against real data the actual relationship between the thermodynamic properties and the applied heat. For saturated flow boiling just from the inlet of the heated tube, and not having into account the kinetic and potential terms, the uniform applied heat per unit mass of inlet water and per unit length (in short, specific linear heat) should be closely related to a (constant) slope of the mixture enthalpy. In this work, we have checked the relation between the specific linear heat and the thermodynamic enthalpy of the liquid-vapor mixture using the actual mass fraction. This true mass fraction is calculated using the accurate measurements of the outlet void fraction taken during the Cambridge project by Knights and Thom in the sixties for

  20. Heat transfer mechanisms in microgravity flow boiling.

    Science.gov (United States)

    Ohta, Haruhiko

    2002-10-01

    The objective of this paper is to clarify the mechanisms of heat transfer and dryout phenomena in flow boiling under microgravity conditions. Liquid-vapor behavior in annular flow, encountered in the moderate quality region, has extreme significance for practical application in space. To clarify the gravity effect on the heat transfer observed for an upward flow in a tube, the research described here started from the measurement of pressure drop for binary gas-liquid mixture under various gravity conditions. The shear stress acting on the surface of the annular liquid film was correlated by an empirical method. Gravity effects on the heat transfer due to two-phase forced convection were investigated by the analysis of velocity and temperature profiles in the film. The results reproduce well the trends of heat transfer coefficients varying with the gravity level, quality, and mass velocity. Dryout phenomena in the moderate quality region were observed in detail by the introduction of a transparent heated tube. At heat fluxes just lower and higher than CHF value, a transition of the heat transfer coefficient was calculated from oscillating wall temperature, where a series of opposing heat transfer trends--the enhancement due to the quenching of dried areas or evaporation from thin liquid films and the deterioration due to the extension of dry patches--were observed between the passage of disturbance waves. The CHF condition that resulted from the insufficient decrease of wall temperature in the period of enhanced heat transfer was overcome by a temperature increase in the deterioration period. No clear effect of gravity on the mechanisms of dryout was observed within the range of experiments.

  1. Microwave-Assisted Superheating and/or Microwave-Specific Superboiling (Nucleation-Limited Boiling of Liquids Occurs under Certain Conditions but is Mitigated by Stirring

    Directory of Open Access Journals (Sweden)

    Anthony Ferrari

    2015-12-01

    Full Text Available Temporary superheating and sustained nucleation-limited “superboiling” of unstirred liquids above the normal atmospheric boiling point have been documented during microwave heating. These phenomena are reliably observed under prescribed conditions, although the duration (of superheating and magnitude (of superheating and superboiling vary according to system parameters such as volume of the liquid and the size and shape of the vessel. Both phenomena are mitigated by rapid stirring with an appropriate stir bar and/or with the addition of boiling chips, which provide nucleation sites to support the phase-change from liquid to gas. With proper experimental design and especially proper stirring, the measured temperature of typical organic reaction mixtures heated at reflux will be close to the normal boiling point temperature of the solvent, whether heated using microwave radiation or conventional convective heat transfer. These observations are important to take into consideration when comparing reaction rates under conventional and microwave heating.

  2. Thermomechanical evaluation of BWR fuel elements for procedures of preconditioned with FEMAXI-V; Evaluacion termomecanica de elementos combustible BWR para procedimientos de preacondicionado con FEMAXI-V

    Energy Technology Data Exchange (ETDEWEB)

    Hernandez L, H.; Lucatero, M.A.; Ortiz V, J. [ININ, Carretera Mexico-Toluca Km 36.5, La Marquesa, Estado de Mexico (Mexico)]. e-mail: hhl@nuclear.inin.mx

    2006-07-01

    The limitations in the burnt of the nuclear fuel usually are fixed by the one limit in the efforts to that undergo them the components of a nuclear fuel assembly. The limits defined its provide the direction to the fuel designer to reduce to the minimum the fuel failure during the operation, and they also prevent against some thermomechanical phenomena that could happen during the evolution of transitory events. Particularly, a limit value of LHGR is fixed to consider those physical phenomena that could lead to the interaction of the pellet-shirt (Pellet Cladding Interaction, PCI). This limit value it is related directly with an PCI limit that can be fixed based on experimental tests of power ramps. This way, to avoid to violate the PCI limit, the conditioning procedures of the fuel are still required for fuel elements with and without barrier. Those simulation procedures of the power ramp are carried out for the reactor operator during the starting maneuvers or of power increase like preventive measure of possible consequences in the thermomechanical behavior of the fuel. In this work, the thermomechanical behavior of two different types of fuel rods of the boiling water reactor is analyzed during the pursuit of the procedures of fuel preconditioning. Five diverse preconditioning calculations were carried out, each one with three diverse linear ramps of power increments. The starting point of the ramps was taken of the data of the cycle 8 of the unit 1 of the Laguna Verde Nucleo electric Central. The superior limit superior of the ramps it was the threshold of the lineal power in which a fuel failure could be presented by PCI, in function of the fuel burnt. The analysis was carried out with the FEMAXI-V code. (Author)

  3. Study of film boiling collapse behavior during vapor explosion

    Energy Technology Data Exchange (ETDEWEB)

    Yagi, Masahiro; Yamano, Norihiro; Sugimoto, Jun [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment; Abe, Yutaka; Adachi, Hiromichi; Kobayashi, Tomoyoshi

    1996-06-01

    Possible large scale vapor explosions are safety concern in nuclear power plants during severe accident. In order to identify the occurrence of the vapor explosion and to estimate the magnitude of the induced pressure pulse, it is necessary to investigate the triggering condition for the vapor explosion. As a first step of this study, scooping analysis was conducted with a simulation code based on thermal detonation model. It was found that the pressure at the collapse of film boiling much affects the trigger condition of vapor explosion. Based on this analytical results, basic experiments were conducted to clarify the collapse conditions of film boiling on a high temperature solid ball surface. Film boiling condition was established by flooding water onto a high temperature stainless steel ball heated by a high frequency induction heater. After the film boiling was established, the pressure pulse generated by a shock tube was applied to collapse the steam film on the ball surface. As the experimental boundary conditions, materials and size of the balls, magnitude of pressure pulse and initial temperature of the carbon and stainless steel balls were varied. The transients of pressure and surface temperature were measured. It was found that the surface temperature on the balls sharply decreased when the pressure wave passed through the film on balls. Based on the surface temperature behavior, the film boiling collapse pattern was found to be categorized into several types. Especially, the pattern for stainless steel ball was categorized into three types; no collapse, collapse and reestablishment after collapse. It was thus clarified that the film boiling collapse behavior was identified by initial conditions and that the pressure required to collapse film boiling strongly depended on the initial surface temperature. The present results will provide a useful information for the analysis of vapor explosions based on the thermal detonation model. (J.P.N.)

  4. Inspection of Pool Boiling with Superhydrophilic and Superhydrophobic Coating

    Energy Technology Data Exchange (ETDEWEB)

    Son, Gyumin; Moon, Sung Bo; Bang, In Cheol [UNIST, Ulsan (Korea, Republic of)

    2015-05-15

    In conventional nuclear power plants, increasing critical heat flux (CHF) margin by converting existing parts is economically meaningful since it means overall energy production increase without building additional power plants. There were researches to enhance margin from the very beginning of the commercialization of nuclear power plants and many efforts have led to current model of plants, optimized for both safety and production efficiency. Examples are mixing vane which is actually applied to plants nowadays, using nanofluids to enhance heat transfer coefficient (HTC), trying porous surfaces and so on. Takata et al. studied effects of surface wettability by using hydrophobic coating and observed enhanced nucleate boiling at coated surface regions. Betz et al. experimented superhydrophilic (SHPi), superhydrophobic (SHPo), and superbiphilic surfaces. Results indicate heat transfer coefficient enhancement due to increase of nucleation sites by hydrophobic regions and constrained diameter of growing bubbles by hydrophilic regions. Although it would be rough to apply their concept to real reactor coolant surface wall, understanding the possibility of enhanced boiling is meaningful. In this paper, SHPi and SHPo coatings were applied to wire at traditional pool boiling experiment by Nukiyama. By observing altered CHF margin and nucleate boiling, the effects of each coating and their tendencies are discussed. SHPi, SHPo and bare wire's pool boiling was investigated and their boiling graphs were discussed. SHPi shows enhancement in CHF while SHPo's case is more complicated since there were variables like partial CHF or micro scale bubbles. Additional experiment could be comparing HTC, checking whether hydrophobic wire's nucleate boiling enhancement can exceed the decreased CHF margin. More sophisticated method to remove unwanted bubbles should be considered such as using degassed water.

  5. Performance of Charcoal Cookstoves for Haiti Part 1: Results from the Water Boiling Test

    Energy Technology Data Exchange (ETDEWEB)

    Booker, Kayje; Han, Tae Won; Granderson, Jessica; Jones, Jennifer; Lsk, Kathleen; Yang, Nina; Gadgil, Ashok

    2011-06-01

    In April 2010, a team of scientists and engineers from Lawrence Berkeley National Lab (LBNL) and UC Berkeley, with support from the Darfur Stoves Project (DSP), undertook a fact-finding mission to Haiti in order to assess needs and opportunities for cookstove intervention. Based on data collected from informal interviews with Haitians and NGOs, the team, Scott Sadlon, Robert Cheng, and Kayje Booker, identified and recommended stove testing and comparison as a high priority need that could be filled by LBNL. In response to that recommendation, five charcoal stoves were tested at the LBNL stove testing facility using a modified form of version 3 of the Shell Foundation Household Energy Project Water Boiling Test (WBT). The original protocol is available online. Stoves were tested for time to boil, thermal efficiency, specific fuel consumption, and emissions of CO, CO{sub 2}, and the ratio of CO/CO{sub 2}. In addition, Haitian user feedback and field observations over a subset of the stoves were combined with the experiences of the laboratory testing technicians to evaluate the usability of the stoves and their appropriateness for Haitian cooking. The laboratory results from emissions and efficiency testing and conclusions regarding usability of the stoves are presented in this report.

  6. Properties of high-temperature phase diagram and critical point parameters in silica

    CERN Document Server

    Iosilevskiy, Igor; Solov'ev, Alexander

    2013-01-01

    Some uncertainties are discussed on the high-temperature phase boundaries and critical point parameters for gas-liquid phase transition in silica (SiO2). The thermal and caloric phase diagrams are compared and examined as being predicted by various theoretical approaches, such as the quasi-chemical representation, the wide-range semi-empirical equation of state and the ionic model under direct molecular dynamic simulation. The theoretical predictions are confronted with handbook recommendations and scanty experimental data on the equilibrium vapor composition over SiO2 boiling. Validity of conventional semi-empirical rules is tested for the theoretically predicted SiO2-phase diagrams. The non-congruence of gas-liquid phase transition in SiO2 is considered for this matter to be used as a modeling body to study the non-congruent evaporation in uranium dioxide and other uranium-bearing fuels at both existing and perspective nuclear reactors.

  7. Gravity and Heater Size Effects on Pool Boiling Heat Transfer

    Science.gov (United States)

    Kim, Jungho; Raj, Rishi

    2014-01-01

    The current work is based on observations of boiling heat transfer over a continuous range of gravity levels between 0g to 1.8g and varying heater sizes with a fluorinert as the test liquid (FC-72/n-perfluorohexane). Variable gravity pool boiling heat transfer measurements over a wide range of gravity levels were made during parabolic flight campaigns as well as onboard the International Space Station. For large heaters and-or higher gravity conditions, buoyancy dominated boiling and heat transfer results were heater size independent. The power law coefficient for gravity in the heat transfer equation was found to be a function of wall temperature under these conditions. Under low gravity conditions and-or for smaller heaters, surface tension forces dominated and heat transfer results were heater size dependent. A pool boiling regime map differentiating buoyancy and surface tension dominated regimes was developed along with a unified framework that allowed for scaling of pool boiling over a wide range of gravity levels and heater sizes. The scaling laws developed in this study are expected to allow performance quantification of phase change based technologies under variable gravity environments eventually leading to their implementation in space based applications.

  8. Marangoni heat transfer in subcooled nucleate pool boiling

    Energy Technology Data Exchange (ETDEWEB)

    Petrovic, S.; Robinson, T.; Judd, R.L. [McMaster University, Hamilton, ON (Canada). Dept. of Mechanical Engineering

    2004-11-01

    The liquid motion induced by surface tension variation, termed the Marangoni effect, and its contribution to boiling heat transfer has been an issue of much controversy. Boiling heat transfer theory, although acknowledging its existence, considers its contribution to heat transfer to be insignificant in comparison with buoyancy induced convection. However, recent microgravity experiments have shown that although the boiling mechanism in a reduced gravity environment is different, the corresponding heat transfer rates are similar to those obtained under normal gravity conditions, raising questions about the validity of the assumption. An experimental investigation was performed in which distilled water was gradually heated to boiling conditions on a copper heater surface at four different levels of subcooling. Photographic investigation of the bubbles appearing on the surface was carried out in support of the measurements. The results obtained indicate that Marangoni convection associated with the bubbles formed by the air dissolved in the water which emerged from solution when the water was heated sufficiently, significantly influenced the heat transfer rate in subcooled nucleate pool boiling. A heat transfer model was developed in order to explain the phenomena observed. (author)

  9. Heater size effect on subcooled pool boiling of FC-72

    Energy Technology Data Exchange (ETDEWEB)

    Raj, Rishi; Kim, Jungho [University of Maryland, College Park, MD (United States). Dept. of Mechanical Engineering

    2009-07-01

    Extensive research has been conducted on pool boiling using heaters larger than the capillary length. For large heaters and/or high gravity conditions, boiling is dominated by buoyancy, and the heat transfer is heater size independent. Much less is known about boiling on small heaters and at low gravity levels. The ratio of heater size L{sub h} to capillary length L{sub c} is an important parameter in the determination of heater size dependence on heat transfer. As the ratio L{sub h}/L{sub c} decreases due to a decrease in either heater size or gravity, surface tension forces become dominant. It is proposed that transition from buoyancy to surface tension dominated boiling occurs when the heater size and bubble departure diameter are of the same order. Previous work in variable gravity with flat surfaces has shown that the heat transfer was heater size independent only when the ratio L{sub h}/L{sub c} was considerably larger than 1. An array of 96 platinum resistance heater elements in a 10 x 10 configuration with individual elements 0.7 x 0.7 mm{sup 2} in size was used to vary heater size and measure the heat transfer. The threshold value of L{sub h}/L{sub c} above which pool boiling is heater size independent was found to be about 2.8. (author)

  10. Boiling crisis and non-equilibrium drying transition

    CERN Document Server

    Nikolayev, Vadim

    2016-01-01

    Boiling crisis is the rapid formation of the quasi-continuous vapor film between the heater and the liquid when the heat supply exceeds a critical value. We propose a mechanism for the boiling crisis that is based on the spreading of the dry spot under a vapor bubble. The spreading is initiated by the vapor recoil force, a force coming from the liquid evaporation into the bubble. Since the evaporation intensity increases sharply near the triple contact line, the influence of the vapor recoil can be described as a change of the apparent contact angle. Therefore, for the most usual case of complete wetting of the heating surface by the liquid, the boiling crisis can be understood as a drying transition from complete to partial wetting. The state of nucleate boiling, which is boiling in its usual sense, is characterized by a very large rate of heat transfer from the heating surface to the bulk because the superheated liquid is carried away from the heating surface by the departing vapor bubbles. If the heating p...

  11. A Prototype Therapy System for Transcutaneous Application of Boiling Histotripsy.

    Science.gov (United States)

    Maxwell, Adam D; Yuldashev, Petr V; Kreider, Wayne; Khokhlova, Tatiana D; Schade, George R; Hall, Timothy L; Sapozhnikov, Oleg A; Bailey, Michael R; Khokhlova, Vera A

    2017-08-14

    Boiling histotripsy is a method of focused ultrasound surgery that noninvasively applies millisecond-length pulses with high-amplitude shock fronts to generate liquefied lesions in tissue. Such a technique requires unique outputs compared to a focused ultrasound thermal therapy apparatus, particularly to achieve high in situ pressure levels through intervening tissue. This article describes the design and characterization of a system capable of producing the necessary pressure to transcutaneously administer boiling histotripsy therapy through clinically relevant overlying tissue paths using pulses with duration up to 10 ms. A high-voltage electronic pulser was constructed to drive a 1-MHz focused ultrasound transducer to produce shock waves with amplitude capable of generating boiling within the pulse duration in tissue. The system output was characterized by numerical modeling with the 3D Westervelt equation using boundary conditions established by acoustic holography measurements of the source field. Such simulations were found to be in agreement with directly measured focal waveforms. An existing derating method for nonlinear therapeutic fields was used to estimate in situ pressure levels at different tissue depths. The system was tested in ex vivo bovine liver samples to create boiling histotripsy lesions at depths up to 7 cm. Lesions were also created through excised porcine body wall (skin, adipose, muscle) with 3-5 cm thickness. These results indicate that the system is capable of producing the necessary output for transcutaneous ablation with boiling histotripsy.

  12. Numerical investigation of nucleate pool boiling heat transfer

    Directory of Open Access Journals (Sweden)

    Stojanović Andrijana D.

    2016-01-01

    Full Text Available Multidimensional numerical simulation of the atmospheric saturated pool boiling is performed. The applied modelling and numerical methods enable a full representation of the liquid and vapour two-phase mixture behaviour on the heated surface, with included prediction of the swell level and heated wall temperature field. In this way the integral behaviour of nucleate pool boiling is simulated. The micro conditions of bubble generation at the heated wall surface are modelled by the bubble nucleation site density, the liquid wetting contact angle and the bubble grow time. The bubble nucleation sites are randomly located within zones of equal size, where the number of zones equals the nucleation site density. The conjugate heat transfer from the heated wall to the liquid is taken into account in wetted heated wall areas around bubble nucleation sites. The boiling curve relation between the heat flux and the heated wall surface temperature in excess of the saturation temperature is predicted for the pool boiling conditions reported in the literature and a good agreement is achieved with experimentally measured data. The influence of the nucleation site density on the boiling curve characteristic is confirmed. In addition, the influence of the heat flux intensity on the spatial effects of vapour generation and two-phase flow are shown, such as the increase of the swell level position and the reduced wetting of the heated wall surface by the heat flux increase. [Projekat Ministarstva nauke Republike Srbije, br. TR-33018 i br. OI-174014

  13. The D&D of the Experimental Boiling Water Reactor (EBWR)

    Energy Technology Data Exchange (ETDEWEB)

    Fellhauer, C.R.; Boling, L.E.; Yule, T.J.; Bhattacharyya, S.K.

    1996-03-01

    Argonne National Laboratory has completed the D&D of the Experimental Boiling Water Reactor. The Project consisted of decontaminating and for packaging as radioactive waste the reactor vessel and internals, contaminated piping systems, miscellaneous tanks, pumps, and associated equipment. The D&D work involved dismantling process equipment and associated plumbing, ductwork drain lines, etc., performing size reduction of reactor vessel internals in the fuel pool, packaging and manifesting all radioactive and mixed waste, and performing a thorough survey of the facility after the removal of activated and contaminated material. Non-radioactive waste was disposed of in the ANL-E landfill or recycled. In January 1996 the EBWR facility was formally decommissioned and transferred from EM-40 to EM-30. This paper will discuss the details of this ten year effort.

  14. Determination of a Jet Fuel Metal Deactivator by High Performance Liquid Chromatography

    Science.gov (United States)

    1983-06-01

    HIGH PERFORMANCE LIQUID CHROMATOGRAPHY Paul C. Hayes, Jr. Fuels Branch...SUPPLEMENTARY NOTES 19. KEY WORDS (Continue on reverse side if necessary and identify by block number) High Performance Liquid Chromatography absorbance...SYMBOL HPLC High Performance Liquid Chromatography P-4 jet propulsion fuel, wide-boiling range, conforming to MIL-T-5624L MDA metal deactivator,

  15. Using plasma-fuel systems at Eurasian coal-fired thermal power stations

    Science.gov (United States)

    Karpenko, E. I.; Karpenko, Yu. E.; Messerle, V. E.; Ustimenko, A. B.

    2009-06-01

    The development of plasma technology for igniting solid fuels at coal-fired thermal power stations in Russia, Kazakhstan, China, and other Eurasian countries is briefly reviewed. Basic layouts and technical and economic characteristics of plasma-fuel systems installed in different coal-fired boiles are considered together with some results from using these systems at coal-fired thermal power stations.

  16. Using plasma-fuel systems at Eurasian coal-fired thermal power stations

    Energy Technology Data Exchange (ETDEWEB)

    E.I. Karpenko; Y.E. Karpenko; V.E. Messerle; A.B. Ustimenko [RAO Unified Energy Systems of Russia, Gusinoozersk (Russian Federation). Russia Sectional Center for Plasma-Power Technologies

    2009-07-01

    The development of plasma technology for igniting solid fuels at coal-fired thermal power stations in Russia, Kazakhstan, China, and other Eurasian countries is briefly reviewed. Basic layouts and technical and economic characteristics of plasma-fuel systems installed in different coal-fired boiles are considered together with some results from using these systems at coal-fired thermal power stations.

  17. Emission reduction from a diesel engine fueled by pine oil biofuel using SCR and catalytic converter

    Science.gov (United States)

    Vallinayagam, R.; Vedharaj, S.; Yang, W. M.; Saravanan, C. G.; Lee, P. S.; Chua, K. J. E.; Chou, S. K.

    2013-12-01

    In this work, we propose pine oil biofuel, a renewable fuel obtained from the resins of pine tree, as a potential substitute fuel for a diesel engine. Pine oil is endowed with enhanced physical and thermal properties such as lower viscosity and boiling point, which enhances the atomization and fuel/air mixing process. However, the lower cetane number of the pine oil hinders its direct use in diesel engine and hence, it is blended in suitable proportions with diesel so that the ignition assistance could be provided by higher cetane diesel. Since lower cetane fuels are prone to more NOX formation, SCR (selective catalyst reduction), using urea as reducing agent, along with a CC (catalytic converter) has been implemented in the exhaust pipe. From the experimental study, the BTE (brake thermal efficiency) was observed to be increased as the composition of pine oil increases in the blend, with B50 (50% pine oil and 50% diesel) showing 7.5% increase over diesel at full load condition. The major emissions such as smoke, CO, HC and NOX were reduced by 70.1%, 67.5%, 58.6% and 15.2%, respectively, than diesel. Further, the average emissions of B50 with SCR and CC assembly were observed to be reduced, signifying the positive impact of pine oil biofuel on atmospheric environment. In the combustion characteristics front, peak heat release rate and maximum in-cylinder pressure were observed to be higher with longer ignition delay.

  18. Transient and stability analysis of a BWR core with thorium-uranium fuel

    Energy Technology Data Exchange (ETDEWEB)

    Nunez-Carrera, Alejandro [Comision Nacional de Seguridad Nuclear y Salvaguardias, Dr. Barragan 779 Col. Narvarte, 03020 Mexico, DF (Mexico); Espinosa-Paredes, Gilberto [Division de Ciencias Basicas e Ingenieria, Universidad Autonoma Metropolitana, Av. San Rafael Atlixco 186, Col. Vicentina, 09340 Mexico, DF (Mexico)], E-mail: gepe@xanum.uam.mx; Francois, Juan-Luis [Departamento de Sistemas Energeticos, Facultad de Ingenieria, Universidad Nacional Autonoma de Mexico, Paseo Cuauhnahuac 8532, 62550 Jiutepec Mor. (Mexico)

    2008-08-15

    The kinetic response of a boiling water reactor (BWR) equilibrium core using thorium as a nuclear material, in an integrated blanket-seed assembly, is presented in this work. Additionally an in-house code was developed to evaluate this core under steady state and transient conditions including a stability analysis. The code has two modules: (a) the time domain module for transient analysis and (b) the frequency domain module for stability analysis. The thermal-hydraulic process is modeled by a set of five equations, considering no homogeneous flow with drift-flux approximation and non-equilibrium thermodynamic. The neutronic process is calculated with a point kinetics model. Typical BWR reactivity effects are considered: void fraction, fuel temperature, moderator temperature and control rod density. Collapsed parameters were included in the code to represent the core using an average fuel channel. For the stability analysis, in the frequency domain, the transfer function is determined by applying Laplace-transforming to the calculated pressure drop perturbations in each of the considered regions where a constant total pressure drop was considered. The transfer function was used to study the system response in the frequency domain when an inlet flow perturbation is applied. The results show that the neutronic behavior of the core with thorium uranium fuel is similar to a UO{sub 2} core, even during transient conditions. The stability and transient analysis show that the thorium-uranium fuel can be operated safely in current BWRs.

  19. Use of boiled hexamethylenetetramine and urea to increase the porosity of cerium dioxide microspheres formed in the internal gelation process

    Science.gov (United States)

    Hunt, R. D.; Collins, J. L.; Cowell, B. S.

    2017-08-01

    Cerium dioxide (CeO2) is a commonly used simulant for plutonium dioxide and for plutonium (Pu) in uranium (U) and Pu oxide [(U, Pu)O2] mixtures used in nuclear fuel development. This effort developed CeO2 microspheres with a various porosities and diameters. The internal gelation technique has only been used to produce CeO2 microspheres with limited initial porosity. Previous studies have shown that the crystallite size and porosity of mixed U and thorium oxide microspheres and the (U, Pu)O2 microspheres from the internal gelation process increased when an equal molar solution of hexamethylenetetramine (HMTA) and urea is gently boiled for 1 h prior to its use in the gelation process. In this study with cerium, the combination of ammonium cerium nitrate and 1-h boiled HMTA-urea failed to produce a stable feed broth. However, when the 1-h heated HMTA-urea was combined with unheated HMTA-urea in 1-3 vol ratio or the boiling time of the HMTA-urea was reduced to 15-20 min, a stable solution of HMTA, urea, and Ce was formed at 273 K. This new Ce solution produced very porous CeO2 microspheres, which are suitable simulants for uranium microspheres.

  20. Thermal-hydraulic instabilities in pressure tube graphite - moderated boiling water reactors

    Energy Technology Data Exchange (ETDEWEB)

    Tsiklauri, G.; Schmitt, B.

    1995-09-01

    Thermally induced two-phase instabilities in non-uniformly heated boiling channels in RBMK-1000 reactor have been analyzed using RELAP5/MOD3 code. The RELAP5 model of a RBMK-1000 reactor was developed to investigate low flow in a distribution group header (DGH) supplying 44 fuel pressure tubes. The model was evaluated against experimental data. The results of the calculations indicate that the period of oscillation for the high power tube varied from 3.1s to 2.6s, over the power range of 2.0 MW to 3.0 MW, respectively. The amplitude of the flow oscillation for the high powered tube varied from +100% to -150% of the tube average flow. Reverse flow did not occur in the lower power tubes. The amplitude of oscillation in the subcooled region at the inlet to the fuel region is higher than in the saturated region at the outlet. In the upper fuel region and outlet connectors the flow oscillations are dissipated. The threshold of flow instability for the high powered tubes of a RBMK reactor is compared to Japanese data and appears to be in good agreement.

  1. Best estimate approach for the evaluation of critical heat flux phenomenon in the boiling water reactors

    Energy Technology Data Exchange (ETDEWEB)

    Kaliatka, Tadas; Kaliatka, Algirdas; Uspuras, Eudenijus; Vaisnoras, Mindaugas [Lithuanian Energy Institute, Kaunas (Lithuania); Mochizuki, Hiroyasu; Rooijen, W.F.G. van [Fukui Univ. (Japan). Research Inst. of Nuclear Engineering

    2017-05-15

    Because of the uncertainties associated with the definition of Critical Heat Flux (CHF), the best estimate approach should be used. In this paper the application of best-estimate approach for the analysis of CHF phenomenon in the boiling water reactors is presented. At first, the nodalization of RBMK-1500, BWR-5 and ABWR fuel assemblies were developed using RELAP5 code. Using developed models the CHF and Critical Heat Flux Ratio (CHFR) for different types of reactors were evaluated. The calculation results of CHF were compared with the well-known experimental data for light water reactors. The uncertainty and sensitivity analysis of ABWR 8 x 8 fuel assembly CHFR calculation result was performed using the GRS (Germany) methodology with the SUSA tool. Finally, the values of Minimum Critical Power Ratio (MCPR) were calculated for RBMK-1500, BWR-5 and ABWR fuel assemblies. The paper demonstrate how, using the results of sensitivity analysis, to receive the MCPR values, which covers all uncertainties and remains best estimated.

  2. Reactor physics analysis for the design of nuclear fuel lattices with burnable poisons

    Energy Technology Data Exchange (ETDEWEB)

    Espinosa-Paredes, G. [Area de Ingenieria en Recursos Energeticos, Universidad Autonoma Metropolitana-Iztapalapa, Av. San Rafael Atlixco 186, Col. Vicentina, 09340 Mexico, D.F. (Mexico); Guzman, Juan R., E-mail: maestro_juan_rafael@hotmail.com [Departamento de Fisica y Matematicas, Instituto Politecnico Nacional, Adolfo Lopez Mateos, San Pedro Zacatenco, 07738 Mexico, D.F. (Mexico)

    2011-12-15

    Highlights: Black-Right-Pointing-Pointer A fuel rod optimization for the coupled bundle-core design in a BWR is developed. Black-Right-Pointing-Pointer An algorithm to minimize the rod power peaking factor is used. Black-Right-Pointing-Pointer The fissile content is divided in two factors. Black-Right-Pointing-Pointer A reactor physics analysis of these factors is performed. Black-Right-Pointing-Pointer The algorithm is applied to a typical BWR fuel lattice. - Abstract: The main goals in nuclear fuel lattice design are: (1) minimizing the rod power peaking factor (PPF) in order that the power level distribution is the most uniform; (2) obtaining a prescribed target value for the multiplication factor (k) at the end of the irradiation in order that the fuel lattice reaches the desired reactivity; and (3) obtaining a prescribed target value for the k at the beginning of the irradiation in order that the reactivity excess is neither a high value (to ease the maneuvering of the control systems) nor a low value (to avoid the penalization of the high cost of the burnable poison content). In this work a simple algorithm to design the burnable poison bearing nuclear fuel lattice is presented. This algorithm is based on a reactor physics analysis. The algorithm is focused on finding the radial distribution of the fuel rods having different fissile and burnable poison contents in order to obtain: (1) an adequate minimum PPF; (2) a prescribed target value of the k at the end of the irradiation; and (3) a prescribed target value of the k at the beginning of the irradiation. This algorithm is based on the factorization of the fissile and burnable poison contents of each fuel rod and on the application of the first-order perturbation theory. The performance of the algorithm is demonstrated with the design of a fuel lattice composed of uranium dioxide (UO{sub 2}) and gadolinium dioxide (Gd{sub 2}O{sub 3}) for boiling water reactors (BWR). This algorithm has been accomplished

  3. Effects of ethylene glycol ethers on diesel fuel properties and emissions in a diesel engine

    Energy Technology Data Exchange (ETDEWEB)

    Gomez-Cuenca, F.; Gomez-Marin, M. [Compania Logistica de Hidrocarburos (CLH), Central Laboratory, Mendez Alvaro 44, 28045 Madrid (Spain); Folgueras-Diaz, M.B., E-mail: belenfd@uniovi.es [Department of Energy, University of Oviedo, Independencia 13, 33004 Oviedo (Spain)

    2011-08-15

    Highlights: {yields} Effect of ethylene glycol ethers on diesel fuel properties. {yields} Effect of ethylene glycol ethers on diesel engine specific consumption and emissions. {yields} Blends with {<=}4 wt.% of oxygen do not change substantially diesel fuel quality. {yields} Blends with 1 and 2.5 wt.% of oxygen reduce CO and HC emissions, but not smoke. - Abstract: The effect of ethylene glycol ethers on both the diesel fuel characteristics and the exhaust emissions (CO, NO{sub x}, smoke and hydrocarbons) from a diesel engine was studied. The ethers used were monoethylene glycol ethyl ether (EGEE), monoethylene glycol butyl ether (EGBE), diethylene glycol ethyl ether (DEGEE). The above effect was studied in two forms: first by determining the modification of base diesel fuel properties by using blends with oxygen concentration around 4 wt.%, and second by determining the emission reductions for blends with low oxygen content (1 wt.%) and with 2.5 wt.% of oxygen content. The addition of DEGEE enhances base diesel fuel cetane number, but EGEE and EGBE decrease it. For concentrations of {>=}4 wt.% of oxygen, EGEE and diesel fuel can show immiscibility problems at low temperatures ({<=}0 {sup o}C). Also, every oxygenated compound, according to its boiling point, modifies the distillation curve at low temperatures and the distillate percentage increases. These compounds have a positive effect on diesel fuel lubricity, and slightly decrease its viscosity. Blends with 1 and 2.5 wt.% oxygen concentrations were used in order to determine their influence on emissions at both full and medium loads and different engine speeds. Generally, all compounds help to reduce CO, and hydrocarbon emissions, but not smoke. The best results were obtained for blends with 2.5 wt.% of oxygen. At this concentration, the additive efficiency in decreasing order was EGEE > DEGEE > EGBE for CO emissions and DGEE > EGEE > EGBE for hydrocarbon emissions. For NO{sub x}, both its behaviour and the

  4. Numerical simulation of pool boiling of a Lennard-Jones liquid

    KAUST Repository

    Inaoka, Hajime

    2013-09-01

    We performed a numerical simulation of pool boiling by a molecular dynamics model. In the simulation, a liquid composed of Lennard-Jones particles in a uniform gravitational field is heated by a heat source at the bottom of the system. The model successfully reproduces the change in regimes of boiling from nucleate boiling to film boiling with the increase of the heat source temperature. We present the pool boiling curve by the model, whose general behavior is consistent with those observed in experiments of pool boiling. © 2013 Elsevier B.V. All rights reserved.

  5. Visualization of pool boiling from complex surfaces with internal tunnels

    Directory of Open Access Journals (Sweden)

    Pastuszko Robert

    2012-04-01

    Full Text Available The paper presents experimental investigations of boiling heat transfer for a system of connected narrow horizontal and vertical tunnels. These extended surfaces, named narrow tunnel structure (NTS, can be applied to electronic element cooling. The experiments were carried out with ethanol at atmospheric pressure. The tunnel external covers were manufactured out of 0.1 mm thick perforated copper foil (hole diameters 0.5 mm, sintered with the mini-fins, formed on the vertical side of the 10 mm high rectangular fins and horizontal inter-fin surface. Visualization studies were conducted with a transparent structured model of joined narrow tunnels limited with the perforated foil. The visualization investigations aimed to formulate assumptions for the boiling model through distinguishing boiling types and defining all phases of bubble growth.

  6. Boiling heat transfer on fins – experimental and numerical procedure

    Directory of Open Access Journals (Sweden)

    Orzechowski T.

    2014-03-01

    Full Text Available The paper presents the research methodology, the test facility and the results of investigations into non-isothermal surfaces in water boiling at atmospheric pressure, together with a discussion of errors. The investigations were conducted for two aluminium samples with technically smooth surfaces and thickness of 4 mm and 10 mm, respectively. For the sample of lower thickness, on the basis of the surface temperature distribution measured with an infrared camera, the local heat flux and the heat transfer coefficient were determined and shown in the form of a boiling curve. For the thicker sample, for which 1-D model cannot be used, numerical calculations were conducted. They resulted in obtaining the values of the local heat flux on the surface the invisible to the infrared, camera i.e. on the side on which the boiling of the medium proceeds.

  7. Changes of enthalpy slope in subcooled flow boiling

    Energy Technology Data Exchange (ETDEWEB)

    Collado, Francisco J.; Monne, Carlos [Universidad de Zaragoza-CPS, Departamento de Ingenieria Mecanica-Motores Termicos, Zaragoza (Spain); Pascau, Antonio [Universidad de Zaragoza-CPS, Departamento de Ciencia de los Materiales y Fluidos-Mecanica de Fluidos, Zaragoza (Spain)

    2006-03-01

    Void fraction data in subcooled flow boiling of water at low pressure measured by General Electric in the 1960s are analyzed following the classical model of Griffith et al. (in Proceedings of ASME-AIChE heat transfer conference, 58-HT-19, 1958). In addition, a new proposal for analyzing one-dimensional steady flow boiling is used. This is based on the physical fact that if the two phases have different velocities, they cannot cover the same distance - the control volume length - in the same time. So a slight modification of the heat balance is suggested, i.e., the explicit inclusion of the vapor-liquid velocity ratio or slip ratio as scaling time factor between the phases, which is successfully checked against the data. Finally, the prediction of void fraction using correlations of the net rate of change of vapor enthalpy in the fully developed regime of subcooled flow boiling is explored. (orig.)

  8. Changes of enthalpy slope in subcooled flow boiling

    Science.gov (United States)

    Collado, Francisco J.; Monné, Carlos; Pascau, Antonio

    2006-03-01

    Void fraction data in subcooled flow boiling of water at low pressure measured by General Electric in the 1960s are analyzed following the classical model of Griffith et al. (in Proceedings of ASME-AIChE heat transfer conference, #58-HT-19, 1958). In addition, a new proposal for analyzing one-dimensional steady flow boiling is used. This is based on the physical fact that if the two phases have different velocities, they cannot cover the same distance—the control volume length—in the same time. So a slight modification of the heat balance is suggested, i.e., the explicit inclusion of the vapor liquid velocity ratio or slip ratio as scaling time factor between the phases, which is successfully checked against the data. Finally, the prediction of void fraction using correlations of the net rate of change of vapor enthalpy in the fully developed regime of subcooled flow boiling is explored.

  9. On mechanism of explosive boiling in nanosecond regime

    Science.gov (United States)

    Çelen, Serap

    2016-06-01

    Today laser-based machining is used to manufacture vital parts for biomedical, aviation and aerospace industries. The aim of the paper is to report theoretical, numerical and experimental investigations of explosive boiling under nanosecond pulsed ytterbium fiber laser irradiation. Experiments were performed in an effective peak power density range between 1397 and 1450 MW/cm2 on pure titanium specimens. The threshold laser fluence for phase explosion, the pressure and temperature at the target surface and the velocity of the expulsed material were reported. A narrow transition zone was realized between the normal vaporization and phase explosion fields. The proof of heterogeneous boiling was given with detailed micrographs. A novel thermal model was proposed for laser-induced splashing at high fluences. Packaging factor and scattering arc radius terms were proposed to state the level of the melt ejection process. Results of the present investigation explain the explosive boiling during high-power laser interaction with metal.

  10. Micro-column enhanced boiling structure and its ramification

    Institute of Scientific and Technical Information of China (English)

    汤勇; 陆龙生; 袁冬; 苏达士

    2008-01-01

    Enhanced boiling experiments of two different enhanced structures were carried out in a thermosyphon loop evaporator chamber. One was micro-columns array structure (MCAS), which was fabricated on copper plate surface with interaction high speed wire electrode discharge machining (HS-WEDM). The other was the ramification of MCAS, named micro-column-array and sintered-copper compound structure (MSCS), which was fabricated with sintered method on micro-column array structure. Considering the wall superheat and critical heat flux (CHF), comparisons were made between them. The results show that both MCAS and MSCS can enhance the boiling heat transfer. It is also found that the enhanced boiling heat transfer ability of MSCS is changed obviously while the porosity of the sintered copper layer is changed.

  11. Defluoridation of drinking water by boiling with brushite and calcite.

    Science.gov (United States)

    Larsen, M J; Pearce, E I F

    2002-01-01

    Existing methods for defluoridating drinking water involve expensive high technology or are slow, inefficient and/or unhygienic. A new method is now suggested, encompassing brushite and calcite suspension followed by boiling. Our aim was to examine the efficiency of the method and the chemical reactions involved. Brushite, 0.3-0.5 g, and an equal weight of calcite were suspended in 1 litre water containing 5-20 ppm fluoride. The suspensions were boiled in an electric kettle, left to cool and the calcium salts to sediment. Solution ion concentrations were determined and sediments were examined by X-ray diffraction. In distilled water initially containing 5, 10 and 20 ppm fluoride the concentration was reduced to 0.06, 0.4 and 5.9 ppm, respectively. Using Aarhus tap water which contained 2.6 mmol/l calcium the final concentrations were 1.2, 2.5 and 7.7 ppm, respectively, and runs without calcite gave results similar to those with calcite. Without boiling the fluoride concentration remained unaltered, as did the brushite and calcite salts, despite occasional agitation by hand. All solutions were supersaturated with respect to fluorapatite and hydroxyapatite and close to saturation with respect to brushite. Boiling produced well-crystallised apatite and traces of calcite, while boiling of brushite alone left a poorly crystallised apatite. We conclude that boiling a brushite/calcite suspension rapidly converts the two salts to apatite which incorporates fluoride if present in solution, and that this process may be exploited to defluoridate drinking water.

  12. A high-fidelity approach towards simulation of pool boiling

    Energy Technology Data Exchange (ETDEWEB)

    Yazdani, Miad; Radcliff, Thomas; Soteriou, Marios; Alahyari, Abbas A. [United Technologies Research Center, East Hartford, Connecticut 06108 (United States)

    2016-01-15

    A novel numerical approach is developed to simulate the multiscale problem of pool-boiling phase change. The particular focus is to develop a simulation technique that is capable of predicting the heat transfer and hydrodynamic characteristics of nucleate boiling and the transition to critical heat flux on surfaces of arbitrary shape and roughness distribution addressing a critical need to design enhanced boiling heat transfer surfaces. The macro-scale of the phase change and bubble dynamics is addressed through employing off-the-shelf Computational Fluid Dynamics (CFD) methods for interface tracking and interphase mass and energy transfer. The micro-scale of the microlayer, which forms at early stage of bubble nucleation near the wall, is resolved through asymptotic approximation of the thin-film theory which provides a closed-form solution for the distribution of the micro-layer and its influence on the evaporation process. In addition, the sub-grid surface roughness is represented stochastically through probabilistic density functions and its role in bubble nucleation and growth is then represented based on the thermodynamics of nucleation process. This combination of deterministic CFD, local approximation, and stochastic representation allows the simulation of pool boiling on any surface with known roughness and enhancement characteristics. The numerical model is validated for dynamics and hydrothermal characteristics of a single nucleated bubble on a flat surface against available literature data. In addition, the prediction of pool-boiling heat transfer coefficient is verified against experimental measurements as well as reputable correlations for various roughness distributions and different surface orientations. Finally, the model is employed to demonstrate pool-boiling phenomenon on enhanced structures with reentrance cavities and to explore the effect of enhancement feature design on thermal and hydrodynamic characteristics of these surfaces.

  13. A high-fidelity approach towards simulation of pool boiling

    Science.gov (United States)

    Yazdani, Miad; Radcliff, Thomas; Soteriou, Marios; Alahyari, Abbas A.

    2016-01-01

    A novel numerical approach is developed to simulate the multiscale problem of pool-boiling phase change. The particular focus is to develop a simulation technique that is capable of predicting the heat transfer and hydrodynamic characteristics of nucleate boiling and the transition to critical heat flux on surfaces of arbitrary shape and roughness distribution addressing a critical need to design enhanced boiling heat transfer surfaces. The macro-scale of the phase change and bubble dynamics is addressed through employing off-the-shelf Computational Fluid Dynamics (CFD) methods for interface tracking and interphase mass and energy transfer. The micro-scale of the microlayer, which forms at early stage of bubble nucleation near the wall, is resolved through asymptotic approximation of the thin-film theory which provides a closed-form solution for the distribution of the micro-layer and its influence on the evaporation process. In addition, the sub-grid surface roughness is represented stochastically through probabilistic density functions and its role in bubble nucleation and growth is then represented based on the thermodynamics of nucleation process. This combination of deterministic CFD, local approximation, and stochastic representation allows the simulation of pool boiling on any surface with known roughness and enhancement characteristics. The numerical model is validated for dynamics and hydrothermal characteristics of a single nucleated bubble on a flat surface against available literature data. In addition, the prediction of pool-boiling heat transfer coefficient is verified against experimental measurements as well as reputable correlations for various roughness distributions and different surface orientations. Finally, the model is employed to demonstrate pool-boiling phenomenon on enhanced structures with reentrance cavities and to explore the effect of enhancement feature design on thermal and hydrodynamic characteristics of these surfaces.

  14. Method of controlling crystallite size in nuclear-reactor fuels

    Science.gov (United States)

    Lloyd, M.H.; Collins, J.L.; Shell, S.E.

    Improved spherules for making enhanced forms of nuclear-reactor fuels are prepared by internal gelation procedures within a sol-gel operation and are accomplished by first boiling the concentrated HMTA-urea feed solution before engaging in the spherule-forming operation thereby effectively controlling crystallite size in the product spherules.

  15. The Advanced High-Temperature Reactor (AHTR) for Producing Hydrogen to Manufacture Liquid Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Forsberg, C.W.; Peterson, P.F.; Ott, L.

    2004-10-06

    Conventional world oil production is expected to peak within a decade. Shortfalls in production of liquid fuels (gasoline, diesel, and jet fuel) from conventional oil sources are expected to be offset by increased production of fuels from heavy oils and tar sands that are primarily located in the Western Hemisphere (Canada, Venezuela, the United States, and Mexico). Simultaneously, there is a renewed interest in liquid fuels from biomass, such as alcohol; but, biomass production requires fertilizer. Massive quantities of hydrogen (H2) are required (1) to convert heavy oils and tar sands to liquid fuels and (2) to produce fertilizer for production of biomass that can be converted to liquid fuels. If these liquid fuels are to be used while simultaneously minimizing greenhouse emissions, nonfossil methods for the production of H2 are required. Nuclear energy can be used to produce H2. The most efficient methods to produce H2 from nuclear energy involve thermochemical cycles in which high-temperature heat (700 to 850 C) and water are converted to H2 and oxygen. The peak nuclear reactor fuel and coolant temperatures must be significantly higher than the chemical process temperatures to transport heat from the reactor core to an intermediate heat transfer loop and from the intermediate heat transfer loop to the chemical plant. The reactor temperatures required for H2 production are at the limits of practical engineering materials. A new high-temperature reactor concept is being developed for H2 and electricity production: the Advanced High-Temperature Reactor (AHTR). The fuel is a graphite-matrix, coated-particle fuel, the same type that is used in modular high-temperature gas-cooled reactors (MHTGRs). The coolant is a clean molten fluoride salt with a boiling point near 1400 C. The use of a liquid coolant, rather than helium, reduces peak reactor fuel and coolant temperatures 100 to 200 C relative to those of a MHTGR. Liquids are better heat transfer fluids than gases

  16. On Boiling of Crude Oil under Elevated Pressure

    CERN Document Server

    Pimenova, Anastasiya V

    2015-01-01

    We construct a thermodynamic model for theoretical calculation of the boiling process of multicomponent mixtures of hydrocarbons (e.g., crude oil). The model governs kinetics of the mixture composition in the course of the distillation process along with the boiling temperature increase. The model heavily relies on the theory of dilute solutions of gases in liquids. Importantly, our results are applicable for modelling the process under elevated pressure (while the empiric models for oil cracking are not scalable to the case of extreme pressure), such as in an oil field heated by lava intrusions.

  17. Heat Transfer in Boiling Dilute Emulsion with Strong Buoyancy

    Science.gov (United States)

    Freeburg, Eric Thomas

    Little attention has been given to the boiling of emulsions compared to that of boiling in pure liquids. The advantages of using emulsions as a heat transfer agent were first discovered in the 1970s and several interesting features have since been studied by few researchers. Early research focuses primarily on pool and flow boiling and looks to determine a mechanism by which the boiling process occurs. This thesis looks at the boiling of dilute emulsions in fluids with strong buoyant forces. The boiling of dilute emulsions presents many favorable characteristics that make it an ideal agent for heat transfer. High heat flux electronics, such as those seen in avionics equipment, produce high heat fluxes of 100 W/cm2 or more, but must be maintained at low temperatures. So far, research on single phase convection and flow boiling in small diameter channels have yet to provide an adequate solution. Emulsions allow the engineer to tailor the solution to the specific problem. The fluid can be customized to retain the high thermal conductivity and specific heat capacity of the continuous phase while enhancing the heat transfer coefficient through boiling of the dispersed phase component. Heat transfer experiments were carried out with FC-72 in water emulsions. FC-72 has a saturation temperature of 56 °C, far below that of water. The parameters were varied as follows: 0% ≤ epsilon ≤ 1% and 1.82 x 1012 ≤ RaH ≤ 4.42 x 1012. Surface temperatures along the heated surface reached temperature that were 20 °C in excess of the dispersed phase saturation temperature. An increase of ˜20% was seen in the average Nusselt numbers at the highest Rayleigh numbers. Holography was used to obtain images of individual and multiple FC-72 droplets in the boundary layer next to the heated surface. The droplet diameters ranged from 0.5 mm to 1.3 mm. The Magnus effect was observed when larger individual droplets were injected into the boundary layer, causing the droplets to be pushed

  18. Hysteresis of boiling for different tunnel-pore surfaces

    Directory of Open Access Journals (Sweden)

    Pastuszko Robert

    2015-01-01

    Full Text Available Analysis of boiling hysteresis on structured surfaces covered with perforated foil is proposed. Hysteresis is an adverse phenomenon, preventing high heat flux systems from thermal stabilization, characterized by a boiling curve variation at an increase and decrease of heat flux density. Experimental data were discussed for three kinds of enhanced surfaces: tunnel structures (TS, narrow tunnel structures (NTS and mini-fins covered with the copper wire net (NTS-L. The experiments were carried out with water, R-123 and FC-72 at atmospheric pressure. A detailed analysis of the measurement results identified several cases of type I, II and III for TS, NTS and NTS-L surfaces.

  19. Effects of Al2O3 nanoparticles deposition on critical heat flux of R-123 in flow boiling heat transfer

    Directory of Open Access Journals (Sweden)

    Seok Bin seo

    2015-06-01

    Full Text Available In this study, R-123 flow boiling experiments were carried out to investigate the effects of nanoparticle deposition on heater surfaces on flow critical heat flux (CHF and boiling heat transfer. It is known that CHF enhancement by nanoparticles results from porous structures that are very similar to layers of Chalk River unidentified deposit formed on nuclear fuel rod surfaces during the reactor operation period. Although previous studies have investigated the surface effects through surface modifications, most studies are limited to pool boiling conditions, and therefore, the effects of porous surfaces on flow boiling heat transfer are still unclear. In addition, there have been only few reports on suppression of wetting for decoupled approaches of reasoning. In this study, bare and Al2O3 nanoparticle-coated surfaces were prepared for the study experiments. The CHF of each surface was measured with different mass fluxes of 1,600 kg/m2s, 1,800 kg/m2s, 2,100 kg/m2s, 2,400 kg/m2s, and 2,600 kg/m2s. The nanoparticle-coated tube showed CHF enhancement up to 17% at a mass flux of 2,400 kg/m2s compared with the bare tube. The factors for CHF enhancement are related to the enhanced rewetting process derived from capillary action through porous structures built-up by nanoparticles while suppressing relative wettability effects between two sample surfaces as a highly wettable R-123 refrigerant was used as a working fluid.

  20. Precharacterization Report for Instrumented Fuel Assembly (IFA)-527

    Energy Technology Data Exchange (ETDEWEB)

    Cunningham, M. E.; Bradley, E. R.; Daniel, J. L.; Davis, N. C.; Lanning, D. D.; Williford, R. E.

    1981-07-01

    This report is a resource document covering the rationale, design, fabrication, and preirradiation characterization of instrumented fuel assembly (IFA)-527. This assembly is being irradiated in the Halden Boiling Water Reactor (HBWR) in Norway as part of the Experimental Support and Development of Single-Rod Fuel Codes Program conducted by Pacific Northwest laboratory (PNL) and sponsored by the Fuel Behavior Research Branch of the U.S. Nuclear Regulatory Commission (NRC). Data from this assembly will be used to better understand light water reactor (LWR) fuel behavior under normal operating conditions.

  1. Spent fuel characteristics & disposal considerations

    Energy Technology Data Exchange (ETDEWEB)

    Oversby, V.M.

    1996-06-01

    The fuel used in commercial nuclear power reactors is uranium, generally in the form of an oxide. The gas-cooled reactors developed in England use metallic uranium enclosed in a thin layer of Magnox. Since this fuel must be processed into a more stable form before disposal, we will not consider the characteristics of the Magnox spent fuel. The vast majority of the remaining power reactors in the world use uranium dioxide pellets in Zircaloy cladding as the fuel material. Reactors that are fueled with uranium dioxide generally use water as the moderator. If ordinary water is used, the reactors are called Light Water Reactors (LWR), while if water enriched in the deuterium isotope of hydrogen is used, the reactors are called Heavy Water reactors. The LWRs can be either pressurized reactors (PWR) or boiling water reactors (BWR). Both of these reactor types use uranium that has been enriched in the 235 isotope to about 3.5 to 4% total abundance. There may be minor differences in the details of the spent fuel characteristics for PWRs and BWRs, but for simplicity we will not consider these second-order effects. The Canadian designed reactor (CANDU) that is moderated by heavy water uses natural uranium without enrichment of the 235 isotope as the fuel. These reactors run at higher linear power density than LWRs and produce spent fuel with lower total burn-up than LWRs. Where these difference are important with respect to spent fuel management, we will discuss them. Otherwise, we will concentrate on spent fuel from LWRs.

  2. Optimization of fuel rod enrichment distribution for BWR fuel assembly

    Energy Technology Data Exchange (ETDEWEB)

    Hirano, Yasushi; Hida, Kazuki; Sakurada, Koichi; Yamamoto, Munenari [Toshiba Corp., Kawasaki, Kanagawa (Japan). Nuclear Engineering Lab.

    1996-09-01

    A practical method was developed for determining the optimum fuel enrichment distribution within a boiling water reactor fuel assembly. The method deals with two different optimization problems, i.e. the combinatorial optimization problem of grouping fuel rods into a given number of rod groups with the same enrichment, and the problem of determining an optimal enrichment for each fuel rod under the resultant rod-grouping pattern. In solving these problems, the primary goal is to minimize a predefined objective function over a given exposure period. The objective function used here is defined by the linear combination C{sub 1}X + C{sub 2}X{sub G}, where X and X{sub G} stand, respectively, for control variables giving constraint to the local power peaking factor and the gadolinium rod power. C{sub 1} and C{sub 2} are user-definable weighting factors to accommodate design preferences. The algorithm for solving this combinatorial optimization problem starts by finding the optimal enrichment vector without any rod-grouping, and promising candidates of rod-grouping patterns are found by exhaustive enumeration based on the resulting fuel enrichment ordering. This latter problem is solved using the method of approximation programming. A practical application is shown for a contemporary 8 x 8 Pu mixed-oxide fuel assembly with 10 gadolinium-poisoned rods. (author)

  3. Vernotte-Cattaneo approximation for heat conduction in fuel rod

    Energy Technology Data Exchange (ETDEWEB)

    Espinosa P, G.; Espinosa M, E. G. [Universidad Autonoma Metropolitana, Unidad Iztapalapa, Area de Ingenieria en Recursos Energeticos, Av. San Rafael Atlixco 186, Col. Vicentina, 09340 Mexico D. F. (Mexico)], e-mail: gepe@xanum.uam.mx

    2009-10-15

    In this paper we explore the applicability of a fuel rod mathematical model based on the Vernotte-Cattaneo transient heat conduction as constitutive law (Non-Fourier approach) for light water reactors transient analysis. In the classical theory of diffusion, the Fourier law of heat conduction is used to describe the relation between the heat conduction is used to describe the relation between the heat flux vector and the temperature gradient assuming that the heat propagation speeds are infinite. The motivation for this research was to eliminate the paradox of an infinite. The motivation for this research was to eliminate the paradox of an infinite thermal wave speed. The time-dependent heat sources were considered in the fuel rod heat transfer model. The close of the main steam isolated valves transient in a boiling water reactor was analyzed for different relaxation times. The results show that for long-times the heat fluxes on the clad surface under Vernotte-Cattaneo approach can be important, while for short-times and from the engineering point of view the changes are very small. (Author)

  4. Aviation turbine fuel properties and their trends

    Science.gov (United States)

    Friedman, R.

    1981-01-01

    Fuel property values and their trends were studied through a review of a recognized, wide ranging sample population from actual fuel inspection data. A total of 676 fuel samples of Jet A aviation turbine fuel were compiled over an eleven year period. Results indicate that most fuel samples have one to three near-specification properties, the most common being aromatics, smoke point, and freezing point.

  5. KALIMER-600-clad Core Fuel Assembly Calculation using MATRA-LMR (V2.0) Code

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Young Gyun; Kim, Young Il

    2006-12-15

    Since the sodium boiling point is very high, maximum cladding and pin temperatures are used for design limit condition in sodium cooled liquid metal reactor. It is necessary to predict accurately the temperature distribution in the core and in the subassemblies to increase the sodium coolant efficiency. Based on the MATRA code, which is developed for PWR analysis, MATRA-LMR has been developed for SFR. The major modifications are: the sodium properties table is implemented as subprogram in the code, Heat transfer coefficients are changed for SFR, te pressure drop correlations are changed for more accurate calculations, which are Novendstern, Chiu-Rohsenow-Todreas, and Cheng-Todreas correlations. This This report describes briefly code structure and equations of MATRA-LMR (Version 2.0), explains input data preparation and shows some calculation results for the KALIMER-600-clad core fuel assembly for which has been performed the conceptual design of the core in the year 2006.

  6. A one-dimensional semi-empirical model considering transition boiling effect for dispersed flow film boiling

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Yu-Jou [Institute of Nuclear Engineering and Science, National Tsing Hua University, Hsinchu 30013, Taiwan, ROC (China); Pan, Chin, E-mail: cpan@ess.nthu.edu.tw [Institute of Nuclear Engineering and Science, National Tsing Hua University, Hsinchu 30013, Taiwan, ROC (China); Department of Engineering and System Science, National Tsing Hua University, Hsinchu 30013, Taiwan, ROC (China); Low Carbon Energy Research Center, National Tsing Hua University, Hsinchu 30013, Taiwan, ROC (China)

    2017-05-15

    Highlights: • Seven heat transfer mechanisms are studied numerically by the model. • A semi-empirical method is proposed to account for the transition boiling effect. • The parametric effects on the heat transfer mechanisms are investigated. • The thermal non-equilibrium phenomenon between vapor and droplets is investigated. - Abstract: The objective of this paper is to develop a one-dimensional semi-empirical model for the dispersed flow film boiling considering transition boiling effects. The proposed model consists of conservation equations, i.e., vapor mass, vapor energy, droplet mass and droplet momentum conservation, and a set of closure relations to address the interactions among wall, vapor and droplets. The results show that the transition boiling effect is of vital importance in the dispersed flow film boiling regime, since the flowing situation in the downstream would be influenced by the conditions in the upstream. In addition, the present paper, through evaluating the vapor temperature and the amount of heat transferred to droplets, investigates the thermal non-equilibrium phenomenon under different flowing conditions. Comparison of the wall temperature predictions with the 1394 experimental data in the literature, the present model ranging from system pressure of 30–140 bar, heat flux of 204–1837 kW/m{sup 2} and mass flux of 380–5180 kg/m{sup 2} s, shows very good agreement with RMS of 8.80% and standard deviation of 8.81%. Moreover, the model well depicts the thermal non-equilibrium phenomenon for the dispersed flow film boiling.

  7. 77 FR 3009 - Knowledge and Abilities Catalog for Nuclear Power Plant Operators: Advanced Boiling Water Reactors

    Science.gov (United States)

    2012-01-20

    ... From the Federal Register Online via the Government Publishing Office NUCLEAR REGULATORY COMMISSION Knowledge and Abilities Catalog for Nuclear Power Plant Operators: Advanced Boiling Water Reactors..., ``Knowledge and Abilities Catalog for Nuclear Power Plant Operators: Advanced Boiling Water Reactors.''...

  8. A Study of the Influence of Solid Particles on Boiling Hysteresis

    Institute of Scientific and Technical Information of China (English)

    M.H.Shi; J.Ma

    1992-01-01

    Experiments have been performed to determine the effects on boiling hysteresis of locally fluidized particles contained in a liquid that serves as coolant for electronic equipment.The results show that Iocally fluidized particles can diminish boiling hysteresis.

  9. Science 101: Why Does It Take Longer to Boil Potatoes at High Altitudes?

    Science.gov (United States)

    Robertson, Bill

    2017-01-01

    Why Does It Take Longer to Boil Potatoes at High Altitudes? This column provides background science information for elementary teachers. This month's issue looks at why water boils at different temperatures at different altitudes.

  10. 76 FR 14437 - Economic Simplified Boiling Water Reactor Standard Design: GE Hitachi Nuclear Energy; Issuance of...

    Science.gov (United States)

    2011-03-16

    ... From the Federal Register Online via the Government Publishing Office ] NUCLEAR REGULATORY COMMISSION Economic Simplified Boiling Water Reactor Standard Design: GE Hitachi Nuclear Energy; Issuance of... GE Hitachi Nuclear Energy (GEH) for the economic simplified boiling water reactor (ESBWR) standard...

  11. Development of nuclear thermal hydraulic verification test and evaluation technology; study on 3-dimension measurement of two-phase flow parameters in subcooled boiling flow

    Energy Technology Data Exchange (ETDEWEB)

    Park, Goon Cherl; Kim, Moon Oh; Cho, Hyung Kyoo; Kim, Seong Jin [Seoul National University, Seoul (Korea)

    2002-04-01

    In this study, the experiments were conducted at different levels of inlet subcooling, flow rate and heat flux in a vertical concentric annulus channel located heater at the center with subcooled boiling conditions of atmosphere pressure and superficial velocity under 1.5m/s. The profiles of void fraction, vapor size, vapor frequency, vapor velocity and IAC were measured by 2 sensor conductivity probe in axially 3 points (L/D{sub h}=90.5,80.1,71.4) and those of liquid velocity by pitot tube. Based on the experiment data subcooled boiling models in MARS and multidimensional code, CFX-4.2 were evaluated was verified for analysis ability of these codes in subcooled boiling. 61 refs., 41 figs., 11 tabs. (Author)

  12. A Review of Boiling Heat Transfer Processes at High Heat Flux

    Science.gov (United States)

    1991-04-01

    liquid metals) which can lead to explosive boiling (known as bumping) that can lead to structural damage to hardware. 3 Transition boiling occurs between...to initiate boiling, in some cases having an explosive transition that can cause structural damage to hardware. A thorough understanding of boiling...graphical correlations for the pressure drops encountered in their experiments. About the same time, Staub and Walmet (Ref. 173) identified the two regions

  13. Measuring radon reduction in xenon boil-off gas

    Energy Technology Data Exchange (ETDEWEB)

    Bruenner, Stefan; Cichon, Dominick; Lindemann, Sebastian; Marrodan Undagoitia, Teresa; Simgen, Hardy [MPIK, Heidelberg (Germany)

    2016-07-01

    {sup 222}Rn, which originates from the decay of primordial {sup 238}U, is one of the major background sources for ultra-low background noble gas detectors. One of them is XENON1T, which is a dark matter direct detection experiment looking for hypothetical weakly interacting massive particles (WIMPs). It uses liquid xenon (LXe) as a detection medium and aims to be sensitive to spin-independent WIMP-nucleon cross-sections of σ∝2.10{sup -47} cm{sup 2} at a WIMP mass of ∝50 GeV/c{sup 2}. To achieve this goal, radon activity inside the detector must be limited to a few mBq/kg. One possible way for reducing the concentration of {sup 222}Rn inside such an LXe detector is using the so-called ''boil-off method''. It takes advantage of the fact, that the radon concentration in boil-off xenon is smaller compared to the concentration in the liquid xenon from which the boil-off xenon evaporated. This can be understood by the different vapor pressures of radon and xenon. In this talk, tests conducted at the MPIK are outlined which probe the feasibility and effectiveness of the boil-off method. The results prove, that a reduction of the radon concentration can indeed be achieved. In addition, an outlook for possible future applications of this technique is given.

  14. How long does it take to boil an egg? Revisited

    Energy Technology Data Exchange (ETDEWEB)

    Buay, D [Natural Sciences and Science Education, National Institute of Education, Nanyang Technological University, 1, Nanyang Walk, Singapore 637616 (Singapore); Foong, S K [Natural Sciences and Science Education, National Institute of Education, Nanyang Technological University, 1, Nanyang Walk, Singapore 637616 (Singapore); Kiang, D [Department of Physics, Chinese University of Hong Kong, Shatin, New Territories, Hong Kong (China); Kuppan, L [Natural Sciences and Science Education, National Institute of Education, Nanyang Technological University, 1, Nanyang Walk, Singapore 637616 (Singapore); Centre for Research in Pedagogy and Practice, National Institute of Education, Nanyang Technological University, 1, Nanyang Walk, Singapore 637616 (Singapore); Liew, V H [Natural Sciences and Science Education, National Institute of Education, Nanyang Technological University, 1, Nanyang Walk, Singapore 637616 (Singapore)

    2006-01-01

    How long does it take to boil an egg? Theoretical prediction, based on a simple adaptation of the solution to the exact thermal diffusion equation for a sphere, is consistent with experiments. The experimental data are also used to estimate an average value for the thermal diffusivity of an egg.

  15. Boiling process in oil coolers on porous elements

    Directory of Open Access Journals (Sweden)

    Genbach Alexander A.

    2016-01-01

    Full Text Available Holography and high-speed filming were used to reveal movements and deformations of the capillary and porous material, allowing to calculate thermo-hydraulic characteristics of boiling liquid in the porous structures. These porous structures work at the joint action of capillary and mass forces, which are generalised in the form of dependences used in the calculation for oil coolers in thermal power plants (TPP. Furthermore, the mechanism of the boiling process in porous structures in the field of mass forces is explained. The development process of water steam formation in the mesh porous structures working at joint action of gravitational and capillary forces is investigated. Certain regularities pertained to the internal characteristics of boiling in cells of porous structure are revealed, by means of a holographic interferometry and high-speed filming. Formulas for calculation of specific thermal streams through thermo-hydraulic characteristics of water steam formation in mesh structures are obtained, in relation to heat engineering of thermal power plants. This is the first calculation of heat flow through the thermal-hydraulic characteristics of the boiling process in a reticulated porous structure obtained by a photo film and holographic observations.

  16. Boiling heat transfer and droplet spreading of nanofluids.

    Science.gov (United States)

    Murshed, S M Sohel; de Castro, C A Nieto

    2013-11-01

    Nanofluids- a new class of heat transfer fluids have recently been a very attractive area of research due to their fascinating thermophysical properties and numerous potential benefits and applications in many important fields. However, there are many controversies and inconsistencies in reported arguments and experimental results on various thermal characteristics such as effective thermal conductivity, convective heat transfer coefficient and boiling heat transfer rate of nanofluids. As of today, researchers have mostly focused on anomalous thermal conductivity of nanofluids. Although investigations on boiling and droplet spreading are very important for practical application of nanofluids as advanced coolants, considerably fewer efforts have been made on these thermal features of nanofluids. In this paper, recent research and development in boiling heat transfer and droplet spreading of nanofluids are reviewed together with summarizing most related patents on nanofluids published in literature. Review reveals that despite some inconsistent results nanofluids exhibit significantly higher boiling heat transfer performance compared to their base fluids and show great promises to be used as advanced heat transfer fluids in numerous applications. However, there is a clear lack of in-depth understanding of heat transport mechanisms during phase change of nanofluids. It is also found that the nanofluids related patents are limited and among them most of the patents are based on thermal conductivity enhancement and synthesising processes of specific type of nanofluids.

  17. Boiling on fins with wire screen of variable effective conductivity

    Directory of Open Access Journals (Sweden)

    Orzechowski Tadeusz

    2017-01-01

    Full Text Available The high scale of integration of modern equipment used for medical, military and other purposes puts heavy demands as regards the removal of great heat fluxes. This can be achieved only in exchangers that apply the phase change phenomena. Among many methods to improve boiling heat transfer, the wire mesh covering demonstrates some advantages due to the possibilities of designing the desired microstructure parameters, availability on the market, and low cost. The wire mesh microstucture with specified geometrical parameters produces anisotropy in conductivity. The different arrangement of the mesh layers relative to the direction of the heat flux is a cause of the change of temperature distribution within the layer. The consequence is a respective change in the discharge conditions of the gas phase and liquid feed. The experiments were conducted on fins covered with a single layer of copper mesh with lumen of 38 % and boiling FC-72 at ambient pressure. Compared with the smooth surface, the wire mesh structures yield an increase in the heat transfer rate at boiling. It is also shown that nucleate boiling is initiated at lower wall superheat. Formulas for longitudinal and perpendicular thermal conductivity are given for different mesh structure arrangements.

  18. Treatment of cork boiling wastewater using chemical oxidation and biodegradation.

    Science.gov (United States)

    Dias-Machado, Manuela; Madeira, Luis M; Nogales, Balbina; Nunes, Olga C; Manaia, Célia M

    2006-06-01

    Three cultures were enriched from cork boiling wastewater using tannic acid as the selective carbon substrate, at 25 degrees C and pH 7.2, 25 degrees C and pH 4.7 and 50 degrees C and pH 4.7. The enrichment culture obtained at neutral pH was composed of five culturable isolates, whereas from each acidic enrichment two bacterial strains were isolated. Mesophilic isolates were Gram negative bacteria belonging to the genera Klebsiella, Pseudomonas, Stenotrophomonas and Burkholderia. Thermophilic isolates were members of the genus Bacillus. Despite the capability of the enrichment cultures to use tannic acid as single carbon and energy source, those cultures were unable to reduce the total polyphenols or the total organic carbon content of cork boiling wastewater. In order to increase the bioavailability of the organic carbon in cork boiling wastewater, biodegradation was preceded by Fenton oxidation. It was demonstrated that the combined process, using small amounts of Fenton reagents and biodegradative inoculum added almost simultaneously to cork boiling wastewater, leads to TOC reductions of more than 90%.

  19. On the eruptive boiling in silicon-based microchannels

    Energy Technology Data Exchange (ETDEWEB)

    Lee, P.C.; Pan, Chin [Department of Engineering and System Science, National Tsing Hua University, Hsinchu 30043 (China)

    2008-09-15

    This study investigates experimentally eruptive boiling in a silicon-based rectangular microchannel with a hydraulic diameter of 33.7 {mu}m, a width of 99.8 {mu}m and a depth-to-width ratio of 0.203. The microchannel is made of SOI wafer and prepared using bulk micro-machining and anodic bonding. The surface roughness for both the bottom and the side walls was measured using an atomic force microscope. The evolution of the eruptive boiling of water in the smooth microchannel was clearly observed using an ultra high-speed video camera (up to 50,000 frames/s) at mass fluxes of 417 and 625 kg/m{sup 2} s and a heat flux from 14.9 to 372 kW/m{sup 2}. It is confirmed that eruptive boiling is a form of rapid bubble nucleation after which the bubble merges with a slug bubble downstream in a short distance or evolve to a slug bubble. The bubble frequency in all of the cases studied is provided. Eruptive boiling may be predicted classically with nano-sized cavities that are consistent with the measured surface roughness. (author)

  20. Experimental demonstration of contaminant removal from fractured rock by boiling.

    Science.gov (United States)

    Chen, Fei; Liu, Xiaoling; Falta, Ronald W; Murdoch, Lawrence C

    2010-08-15

    This study was conducted to experimentally demonstrate removal of a chlorinated volatile organic compound from fractured rock by boiling. A Berea sandstone core was contaminated by injecting water containing dissolved 1,2-DCA (253 mg/L) and sodium bromide (144 mg/L). During heating, the core was sealed except for one end, which was open to the atmosphere to simulate an open fracture. A temperature gradient toward the outlet was observed when boiling occurred in the core. This indicates that steam was generated and a pressure gradient developed toward the outlet, pushing steam vapor and liquid water toward the outlet. As boiling occurred, the concentration of 1,2-DCA in the condensed effluent peaked up to 6.1 times higher than the injected concentration. When 38% of the pore volume of condensate was produced, essentially 100% of the 1,2-DCA was recovered. Nonvolatile bromide concentration in the condensate was used as an indicator of the produced steam quality (vapor mass fraction) because it can only be removed as a solute, and not as a vapor. A higher produced steam quality corresponds to more concentrated 1,2-DCA removal from the core, demonstrating that the chlorinated volatile compound is primarily removed by partitioning into vapor phase flow. This study has experimentally demonstrated that boiling is an effective mechanism for CVOC removal from the rock matrix.

  1. Numerical thermal analysis of water's boiling heat transfer based on a turbulent jet impingement on heated surface

    Science.gov (United States)

    Toghraie, D.

    2016-10-01

    In this study, a numerical method for simulation of flow boiling through subcooled jet on a hot surface with 800 °C has been presented. Volume fraction (VOF) has been used to simulate boiling heat transfer and investigation of the quench phenomena through fluid jet on a hot horizontal surface. Simulation has been done in a fixed Tsub=55 °C, Re=5000 to Re=50,000 and also in different Tsub =Tsat -Tf between 10 °C and 95 °C. The effect of fluid jet velocity and subcooled temperature on the rewetting temperature, wet zone propagation, cooling rate and maximum heat flux has been investigated. The results of this study show that by increasing the velocity of fluid jet of water, convective heat transfer coefficient at stagnation point increases. More ever, by decreasing the temperature of the fluid jet, convective heat transfer coefficient increases.

  2. Leidenfrost Point and Estimate of the Vapour Layer Thickness

    Science.gov (United States)

    Gianino, Concetto

    2008-01-01

    In this article I describe an experiment involving the Leidenfrost phenomenon, which is the long lifetime of a water drop when it is deposited on a metal that is much hotter than the boiling point of water. The experiment was carried out with high-school students. The Leidenfrost point is measured and the heat laws are used to estimate the…

  3. Nucleate Pool Boiling Experiments (NPBX) on the International Space Station

    Science.gov (United States)

    Dhir, Vijay Kumar; Warrier, Gopinath R.; Aktinol, Eduardo; Chao, David; Eggers, Jeffery; Sheredy, William; Booth, Wendell

    2012-11-01

    During the period of March-May 2011, a series of boiling experiments was carried out in the Boiling Experimental Facility (BXF) located in the Microgravity Science Glovebox (MSG) of the International Space Station (ISS). The BXF Facility was carried to ISS on Space Shuttle Mission STS-133 on February 24, 2011. Nucleate Pool Boiling Experiment (NPBX) was one of the two experiments housed in the BXF. Results of experiments on single bubble dynamics (e.g., inception and growth), multiple bubble dynamics (lateral merger and departure, if any), nucleate pool boiling heat transfer, and critical heat flux are described. In the experiments Perfluoro-n-hexane was used as the test liquid. The system pressure was varied from 51 to 243 kPa, pool temperature was varied from 30° to 59°C, and test surface temperature was varied from 40° to 80°C. The test surface was a polished aluminum disc (1 mm thick, 89.5 mm in diameter) heated from below with strain gage heaters. Five cylindrical cavities were formed on the surface with four cavities located at the corners of a square and one in the middle. During experiments the magnitude of mean gravity level normal to the heater surface varied from 1.2 × 10 - 7g e to 6 × 10 - 7g e . The results of the experiments show that a single bubble continues to grow to occupy the size of the chamber without departing from the heater surface. During lateral merger of bubbles, at high superheats a large bubble may lift off from the surface but continues to hover near the surface. Neighboring bubbles are continuously pulled into the large bubble. At low superheats bubbles at neighboring sites simply merge to yield a larger bubble. The larger bubble mostly locates in the middle of the heated surface and serves as a vapor sink. The latter mode continues to persist when boiling is occurring all over the heater surface. Heat fluxes for steady state nucleate boiling and critical heat fluxes are found to be much lower than those obtained under earth

  4. 77 FR 36014 - Initial Test Program of Emergency Core Cooling Systems for Boiling-Water Reactors

    Science.gov (United States)

    2012-06-15

    ... COMMISSION Initial Test Program of Emergency Core Cooling Systems for Boiling-Water Reactors AGENCY: Nuclear...-1277, ``Initial Test Program of Emergency Core Cooling Systems for Boiling- Water Reactors.'' This... testing features of emergency core cooling systems (ECCSs) for boiling-water reactors (BWRs). DATES...

  5. 76 FR 78096 - U.S. Advanced Boiling Water Reactor Aircraft Impact Design Certification Amendment

    Science.gov (United States)

    2011-12-16

    ... COMMISSION 10 CFR Part 52 RIN 3150-AI84 U.S. Advanced Boiling Water Reactor Aircraft Impact Design.... Advanced Boiling Water Reactor (U.S. ABWR) standard plant design to comply with the NRC's aircraft impact...--Design Certification Rule for the U.S. Advanced Boiling Water Reactor IV. Section-by-Section Analysis A...

  6. 77 FR 38338 - Dairyland Power Cooperative; La Crosse Boiling Water Reactor Exemption From Certain Security...

    Science.gov (United States)

    2012-06-27

    ... COMMISSION Dairyland Power Cooperative; La Crosse Boiling Water Reactor Exemption From Certain Security Requirements 1.0 Background The La Crosse Boiling Water Reactor (LACBWR) is owned and was operated by the..., which utilized a forced-circulation, direct-cycle boiling water reactor as its heat source. The plant is...

  7. 76 FR 3540 - U.S. Advanced Boiling Water Reactor Aircraft Impact Design Certification Amendment

    Science.gov (United States)

    2011-01-20

    ... COMMISSION 10 CFR Part 52 RIN 3150-AI84 U.S. Advanced Boiling Water Reactor Aircraft Impact Design... the U.S. Advanced Boiling Water Reactor (ABWR) standard plant design to comply with the NRC's aircraft...--Design Certification Rule for the U.S. Advanced Boiling Water Reactor IV. Section-by-Section Analysis A...

  8. Study of plutonium disposition using the GE Advanced Boiling Water Reactor (ABWR)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-04-30

    The end of the cold war and the resulting dismantlement of nuclear weapons has resulted in the need for the U.S. to disposition 50 to 100 metric tons of excess of plutonium in parallel with a similar program in Russia. A number of studies, including the recently released National Academy of Sciences (NAS) study, have recommended conversion of plutonium into spent nuclear fuel with its high radiation barrier as the best means of providing long-term diversion resistance to this material. The NAS study {open_quotes}Management and Disposition of Excess Weapons Plutonium{close_quotes} identified light water reactor spent fuel as the most readily achievable and proven form for the disposition of excess weapons plutonium. The study also stressed the need for a U.S. disposition program which would enhance the prospects for a timely reciprocal program agreement with Russia. This summary provides the key findings of a GE study where plutonium is converted into Mixed Oxide (MOX) fuel and a 1350 MWe GE Advanced Boiling Water Reactor (ABWR) is utilized to convert the plutonium to spent fuel. The ABWR represents the integration of over 30 years of experience gained worldwide in the design, construction and operation of BWRs. It incorporates advanced features to enhance reliability and safety, minimize waste and reduce worker exposure. For example, the core is never uncovered nor is any operator action required for 72 hours after any design basis accident. Phase 1 of this study was documented in a GE report dated May 13, 1993. DOE`s Phase 1 evaluations cited the ABWR as a proven technical approach for the disposition of plutonium. This Phase 2 study addresses specific areas which the DOE authorized as appropriate for more in-depth evaluations. A separate report addresses the findings relative to the use of existing BWRs to achieve the same goal.

  9. Bubble and boundary layer behaviour in subcooled flow boiling

    Energy Technology Data Exchange (ETDEWEB)

    Maurus, Reinhold; Sattelmayer, Thomas [Lehrstuhl fuer Thermodynamik, Technische Universitaet Muenchen, 85747 Garching (Germany)

    2006-03-15

    Subcooled flow boiling is a commonly applied technique for achieving efficient heat transfer. In the study, an experimental investigation in the nucleate boiling regime was performed for water circulating in a closed loop at atmospheric pressure. The horizontal orientated test-section consists of a rectangular channel with a one side heated copper strip and good optical access. Various optical observation techniques were applied to study the bubble behaviour and the characteristics of the fluid phase. The bubble behaviour was recorded by the high-speed cinematography and by a digital high resolution camera. Automated image processing and analysis algorithms developed by the authors were applied for a wide range of mass flow rates and heat fluxes in order to extract characteristic length and time scales of the bubbly layer during the boiling process. Using this methodology, the bubbles were automatically analysed and the bubble size, bubble lifetime, waiting time between two cycles were evaluated. Due to the huge number of observed bubbles a statistical analysis was performed and distribution functions were derived. Using a two-dimensional cross-correlation algorithm, the averaged axial phase boundary velocity profile could be extracted. In addition, the fluid phase velocity profile was characterised by means of the particle image velocimetry (PIV) for the single phase flow as well as under subcooled flow boiling conditions. The results indicate that the bubbles increase the flow resistance. The impact on the flow exceeds by far the bubbly region and it depends on the magnitude of the boiling activity. Finally, the ratio of the averaged phase boundary velocity and of the averaged fluid velocity was evaluated for the bubbly region. (authors)

  10. Numerical Investigation of Microgravity Tank Pressure Rise Due to Boiling

    Science.gov (United States)

    Hylton, Sonya; Ibrahim, Mounir; Kartuzova, Olga; Kassemi, Mohammad

    2015-01-01

    The ability to control self-pressurization in cryogenic storage tanks is essential for NASAs long-term space exploration missions. Predictions of the tank pressure rise in Space are needed in order to inform the microgravity design and optimization process. Due to the fact that natural convection is very weak in microgravity, heat leaks into the tank can create superheated regions in the liquid. The superheated regions can instigate microgravity boiling, giving rise to pressure spikes during self-pressurization. In this work, a CFD model is developed to predict the magnitude and duration of the microgravity pressure spikes. The model uses the Schrage equation to calculate the mass transfer, with a different accommodation coefficient for evaporation at the interface, condensation at the interface, and boiling in the bulk liquid. The implicit VOF model was used to account for the moving interface, with bounded second order time discretization. Validation of the models predictions was carried out using microgravity data from the Tank Pressure Control Experiment, which flew aboard the Space Shuttle Mission STS-52. Although this experiment was meant to study pressurization and pressure control, it underwent boiling during several tests. The pressure rise predicted by the CFD model compared well with the experimental data. The ZBOT microgravity experiment is scheduled to fly on February 2016 aboard the ISS. The CFD model was also used to perform simulations for setting parametric limits for the Zero-Boil-Off Tank (ZBOT) Experiments Test Matrix in an attempt to avoid boiling in the majority of the test runs that are aimed to study pressure increase rates during self-pressurization. *Supported in part by NASA ISS Physical Sciences Research Program, NASA HQ, USA

  11. A Study of Nucleate Boiling with Forced Convection in Microgravity

    Science.gov (United States)

    Merte, Herman, Jr.

    1999-01-01

    The ultimate objective of basic studies of flow boiling in microgravity is to improve the understanding of the processes involved, as manifested by the ability to predict its behavior. This is not yet the case for boiling heat transfer even in earth gravity, despite the considerable research activity over the past 30 years. The elements that constitute the nucleate boiling process - nucleation, growth, motion, and collapse of the vapor bubbles (if the bulk liquid is subcooled) - are common to both pool and flow boiling. It is well known that the imposition of bulk liquid motion affects the vapor bubble behavior relative to pool boiling, but does not appear to significantly influence the heat transfer. Indeed, it has been recommended in the past that empirical correlations or experimental data of pool boiling be used for design purposes with forced convection nucleate boiling. It is anticipated that such will most certainly not be possible for boiling in microgravity, based on observations made with pool boiling in microgravity. In earth gravity buoyancy will act to remove the vapor bubbles from the vicinity of the heater surface regardless of how much the imposed bulk velocity is reduced, depending, of course, on the geometry of the system. Vapor bubbles have been observed to dramatically increase in size in pool boiling in microgravity, and the heat flux at which dryout took place was reduced considerably below what is generally termed the critical heat flux (CHF) in earth gravity, depending on the bulk liquid subcooling. However, at heat flux levels below dryout, the nucleate pool boiling process was enhanced considerably over that in earth gravity, in spite of the large vapor bubbles formed in microgravity and perhaps as a consequence. These large vapor bubbles tended to remain in the vicinity of the heater surface, and the enhanced heat transfer appeared to be associated with the presence of what variously has been referred to as a liquid microlayer between the

  12. Flow regimes and mechanistic modeling of critical heat flux under subcooled flow boiling conditions

    Science.gov (United States)

    Le Corre, Jean-Marie

    the post-DNB heater temperature up to the point of heater melting. Validation of the proposed model was performed using detailed measured wall boiling parameters near CHF, thereby bypassing most needed constitutive relations. It was found that under limiting nucleation conditions; a peak wall temperature at the time of bubble departure can be reached at CHF preventing wall cooling by quenching. The simulations show that the resulting dry patch can survive the surrounding quenching event, preventing further nucleation and leading to a fast heater temperature increase. For more practical applications, the model was applied at known CHF conditions in simple geometry coupled with one-dimensional and three-dimensional (CFD) codes. It was found that, in the case where CHF occurs under bubbly flow conditions, the local wall superheat underneath nucleating bubbles is predicted to reach the Leidenfrost temperature. However, a better knowledge of statistical variations in wall boiling parameters would be necessary to correctly capture the CHF trends with mass flux (or Weber number). In addition, consideration of relevant parameter influences on the Leidenfrost temperature and consideration of interfacial microphysics at the wall would allow improved simulation of the wall rewetting prevention and subsequent dry patch spreading.

  13. Validation of system codes RELAP5 and SPECTRA for natural convection boiling in narrow channels

    Energy Technology Data Exchange (ETDEWEB)

    Stempniewicz, M.M., E-mail: stempniewicz@nrg.eu; Slootman, M.L.F.; Wiersema, H.T.

    2016-10-15

    Highlights: • Computer codes RELAP5/Mod3.3 and SPECTRA 3.61 validated for boiling in narrow channels. • Validated codes can be used for LOCA analyses in research reactors. • Code validation based on natural convection boiling in narrow channels experiments. - Abstract: Safety analyses of LOCA scenarios in nuclear power plants are performed with so called thermal–hydraulic system codes, such as RELAP5. Such codes are validated for typical fuel geometries applied in nuclear power plants. The question considered by this article is if the codes can be applied for LOCA analyses in research reactors, in particular exceeding CHF in very narrow channels. In order to answer this question, validation calculations were performed with two thermal–hydraulic system codes: RELAP and SPECTRA. The validation was based on natural convection boiling in narrow channels experiments, performed by Prof. Monde et al. in the years 1990–2000. In total 42 vertical tube and annulus experiments were simulated with both codes. A good agreement of the calculated values with the measured data was observed. The main conclusions are: • The computer codes RELAP5/Mod 3.3 (US NRC version) and SPECTRA 3.61 have been validated for natural convection boiling in narrow channels using experiments of Monde. The dimensions applied in the experiments were performed for a range that covers the values observed in typical research reactors. Therefore it is concluded that both codes are validated and can be used for LOCA analyses in research reactors, including natural convection boiling. The applicability range of the present validation is: hydraulic diameters of 1.1 ⩽ D{sub hyd} ⩽ 9.0 mm, heated lengths of 0.1 ⩽ L ⩽ 1.0 m, pressures of 0.10 ⩽ P ⩽ 0.99 MPa. In most calculations the burnout was predicted to occur at lower power than that observed in the experiments. In several cases the burnout was observed at higher power. The overprediction was not larger than 16% in RELAP and 15% in

  14. Thermal singularity and contact line motion in pool boiling: Effects of substrate wettability

    Science.gov (United States)

    Taylor, M. T.; Qian, Tiezheng

    2016-03-01

    The dynamic van der Waals theory [Phys. Rev. E 75, 036304 (2007), 10.1103/PhysRevE.75.036304] is employed to model the growth of a single vapor bubble in a superheated liquid on a flat homogeneous substrate. The bubble spreading dynamics in the pool boiling regime has been numerically investigated for one-component van der Waals fluids close to the critical point, with a focus on the effect of the substrate wettability on bubble growth and contact line motion. The substrate wettability is found to control the apparent contact angle and the rate of bubble growth (the rate of total evaporation), through which the contact line speed is determined. An approximate expression is derived for the contact line speed, showing good agreement with the simulation results. This demonstrates that the contact line speed is primarily governed by (1) the circular shape of interface (for slow bubble growth), (2) the constant apparent contact angle, and (3) the constant bubble growth rate. It follows that the contact line speed has a sensitive dependence on the substrate wettability via the apparent contact angle which also determines the bubble growth rate. Compared to hydrophilic surfaces, hydrophobic surfaces give rise to a thinner shape of bubble and a higher rate of total evaporation, which combine to result in a much faster contact line speed. This can be linked to the earlier formation of a vapor film and hence the onset of boiling crisis.

  15. Design Technique for the High-Boiling Propellant Storage and Preparation Facility at the Cosmodrome «Vostochny»

    Directory of Open Access Journals (Sweden)

    O. E. Denisov

    2014-01-01

    Full Text Available The offered project of storage facility allows us to simplify and unitise the ground-based infrastructure objects. The storage facility implements a full preparatory cycle of the propellant components (PC in all parameters. Another problem the developers of complexes of groundbased equipment face now is bulk receipt of PC from manufacturer. The tanks of launch complexes cannot accept such volumes of propellant. It proves that there is a need to create a storage facility. The facility solves problems concerning the components receipt, temperature preparation, moisture content (drying, gas content, and supply to consumers. For preparation the perspective technologies with low power consumption are used.Receiving the propellant from the dispensing platform is carried out via filters of rough cleaning. Transfer from transport tankage goes using a pump. The received product passes through a gas separator to clean technological gas impurity.To prepare propellant temperature, a technology of cryogenic bubbling by boiling nitrogen is chosen. To improve efficiency of cryogenic bubbling it is advised to use the specialized capacities. Railway dimensions, admissible for the trainload goods across the railroads of Siberia and the Far East, define their sizes.As a drying technology and a gas content preparation the preliminary propellant filtration using vertical electro-separators is chosen to save a space. The chamber vertical electroseparators allow 2 — 3 times increase of dehydration capacity.The article presents calculations to prove that using the chosen cooling and drying technologies is efficient.Prepared PC can be supplied:• to transport-fueling containers (TFC with the subsequent transportation to the launch complexes either by the railway or by road;• to mobile fuelling tanks, which feed rocket-carrier tanks on arrival at the blast-off;• to transport capacities for transportation to the object outside the cosmodrome (spaceport;• directly

  16. Radon depletion in xenon boil-off gas

    Energy Technology Data Exchange (ETDEWEB)

    Bruenner, S.; Cichon, D.; Lindemann, S.; Undagoitia, T.M.; Simgen, H. [Max-Planck-Institut fuer Kernphysik, Heidelberg (Germany)

    2017-03-15

    An important background in detectors using liquid xenon for rare event searches arises from the decays of radon and its daughters. We report for the first time a reduction of {sup 222}Rn in the gas phase above a liquid xenon reservoir. We show a reduction factor of >or similar 4 for the {sup 222}Rn concentration in boil-off xenon gas compared to the radon enriched liquid phase. A semiconductor-based α-detector and miniaturized proportional counters are used to detect the radon. As the radon depletion in the boil-off gas is understood as a single-stage distillation process, this result establishes the suitability of cryogenic distillation to separate radon from xenon down to the 10{sup -15} mol/mol level. (orig.)

  17. Radon depletion in xenon boil-off gas

    CERN Document Server

    Bruenner, S; Lindemann, S; Undagoitia, T Marrodán; Simgen, H

    2016-01-01

    An important background in detectors using liquid xenon for rare event searches arises from the decays of radon and its daughters. We report for the first time a reduction of $^{222}$Rn in the gas phase above a liquid xenon reservoir. We show a reduction factor of $\\gtrsim 4$ for the $^{222}$Rn concentration in boil-off xenon gas compared to the radon enriched liquid phase. A semiconductor-based $\\alpha$-detector and miniaturized proportional counters are used to detect the radon. As the radon depletion in the boil-off gas is understood as a single-stage distillation process, this result establishes the suitability of cryogenic distillation to separate radon from xenon down to the $10^{-15}\\,$mol/mol level.

  18. Catastrophe characteristics of the condensation and pool boiling phenomena

    Science.gov (United States)

    Ma, Xuehu; Xu, Dunqi; Lin, Jifang

    1995-02-01

    Recently, Utaka proposed two types of the transition modes of dropwise condensation, i.e. the continuous and the jumping modes, and presented a criterion for determining the condensation transition mode. Stylianous and Rose proposed two hypotheses, the coalescence-limited transition and the nucleation site saturation transition. Neither Utaka's criterion nor Rose's hypotheses could clearly interpret the physical mechanisms of the transition both from filmwise to dropwise and from dropwise to pseudofilm condensation, and explicitly presented the main factors affecting the transitions. Kalinin hs given a general review of the transition boiling heat transfer. The catastrophe theory will be applied here to eluicidate the complex phenomena of the transitions of the condensation and boiling pattern states.

  19. Numerical analysis on pool boiling using user defined function

    Energy Technology Data Exchange (ETDEWEB)

    Ryu, Sung Uk; Jeon, Byong Guk; Kim, Seok; Euh, Dong-Jin [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2015-10-15

    PAFS (passive auxiliary feedwater system) adopted in the APR+ (Advanced Power Reactor Plus) of Korea is one such application. When PAFS is activated with an actuation signal, steam from the steam generator passes through heat exchanger tubes submerged in a water tank of the PAFS. Outside these heat exchanger tubes, nucleate boiling phenomena appears. In the present work, a numerical study is reported on three-dimensional transient state pool boiling of water having an immersed heat source. The velocity vector fields during the decrease in the water level are numerically investigated in a pool, and the accuracy of the results is checked by comparing the experimental results conducted using the PIV techniques by Kim et al. These numerical results can be used as basic research data for an analysis and prediction of the natural circulation phenomena in the cooling tank of the passive safety system in a nuclear power plant.

  20. Critical heat flux maxima during boiling crisis on textured surfaces

    Science.gov (United States)

    Dhillon, Navdeep Singh; Buongiorno, Jacopo; Varanasi, Kripa K.

    2015-01-01

    Enhancing the critical heat flux (CHF) of industrial boilers by surface texturing can lead to substantial energy savings and global reduction in greenhouse gas emissions, but fundamentally this phenomenon is not well understood. Prior studies on boiling crisis indicate that CHF monotonically increases with increasing texture density. Here we report on the existence of maxima in CHF enhancement at intermediate texture density using measurements on parametrically designed plain and nano-textured micropillar surfaces. Using high-speed optical and infrared imaging, we study the dynamics of dry spot heating and rewetting phenomena and reveal that the dry spot heating timescale is of the same order as that of the gravity and liquid imbibition-induced dry spot rewetting timescale. Based on these insights, we develop a coupled thermal-hydraulic model that relates CHF enhancement to rewetting of a hot dry spot on the boiling surface, thereby revealing the mechanism governing the hitherto unknown CHF enhancement maxima. PMID:26346098