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Sample records for boiler tube fouling

  1. Surface chemistry interventions to control boiler tube fouling - Part II

    Energy Technology Data Exchange (ETDEWEB)

    Turner, C.W.; Guzonas, D.A.; Klimas, S.J

    2004-06-15

    This is the third in a series of reports from an investigation co-funded by the Electric Power Research Institute (EPRI) and by Atomic Energy of Canada Limited (AECL) into the effectiveness of alternative amines for controlling the rate of tube-bundle fouling under steam generator (SG) operating conditions. The objectives of this investigation are to determine whether the fouling rate depends on the amine used for pH control, to identify those factors that influence the effectiveness, and use this information to optimize the selection of an amine for chemistry control and deposit control in the steam cycle and steam generator, respectively. Work to date has demonstrated that the rate of particle deposition under steam generator operating conditions is strongly influenced by surface chemistry (Turner et al., 1997; Turner et al., 1999). This dependence upon surface chemistry is illustrated by the difference between the deposition rates measured for hematite and magnetite, and by the dependence of the particle deposition rate on the amine used for pH control. Deposition rates of hematite were found to be more than 10 times greater than those for magnetite under similar test conditions (Turner et al., 1997). At 270{sup o}C and pH{sub T} 6.2, the surfaces of hematite and magnetite are predicted to be positively charged and negatively charged, respectively (Shoonen, 1994). Measurements of the point of zero charge (PZC) of magnetite at temperatures from 25{sup o}C to 290{sup o}C by Wesolowski et al. (1999) have confirmed that magnetite is negatively charged at the stated conditions. A PZC of 4.2 was measured for Alloy 600 at 25{sup o}C (Balakrishnan and Turner, un-published results), and its surface is expected to remain negatively charged for alkaline chemistry over the temperature range of interest. Therefore, there will be a repulsive force between the surfaces of magnetite particles and Alloy 600 at 270{sup o}C and pH{sub T} 6.2 that is absent for hematite particles

  2. Surface chemistry interventions to control boiler tube fouling

    Energy Technology Data Exchange (ETDEWEB)

    Turner, C.W.; Guzonas, D.A.; Klimas, S.J

    2000-06-01

    The adsorption of ammonia, morpholine, ethanolamine, and dimethylamine onto the surfaces of colloidal magnetite and hematite was measured at 25{sup o}C. The effect of the adsorption on the surface potential was quantified by measuring the resulting shift in the isoelectric point of the corrosion products and by the direct measurement of the surface interaction force between the corrosion products and Inconel 600. These measurements have served to support the hypothesis that adsorption of amine affects the magnetite deposition rate by lowering the force of repulsion between magnetite and the surface of Inconel 600. The deposition rate of hematite increased as the oxygen concentration increased. A mechanism to account for enhanced deposition rates at high mixture qualities (> 0.35) has been identified and shown to predict behaviour that is consistent with both experimental and plant data. As a result of this investigation, several criteria are proposed to reduce the extent of corrosion product deposition on the tube bundle. Low hematite deposition is favoured by a low concentration of dissolved oxygen, and low magnetite deposition is favoured by choosing an amine for pH control that has little tendency to adsorb onto the surface of magnetite. To minimize adsorption the amine should have a high base strength and a large 'footprint' on the surface of magnetite. To prevent enhanced deposition at high mixture qualities, it is proposed that a modified amine be used that will reduce the surface tension or the elasticity of the steam-water interface or both.

  3. Fuel sulfur and boiler fouling

    Energy Technology Data Exchange (ETDEWEB)

    Litzke, W.; Celebi, Y.; Butcher, T. [Brookhaven National Lab., Upton, NY (United States)

    1995-04-01

    Fouling of the heat transfer surfaces of boilers and furnaces by `soot` leads to reduced efficiency and increased service requirements. The average level of annual efficiency reduction as a result of fouling if generally accepted as 2% per year. Improving the efficiency of equipment in the field may be the most important oil heat conservation opportunity at present. Improvements can be realized by reducing fouling rates, promoting lower firing rates in existing equipment, and enabling excess air levels to be set lower without raising concerns about increased service requirements. In spite of the importance of efficiency in the field there is very little data available on efficiency degradation rates with modern equipment, actual field operating conditions (excess air and smoke number settings) and service problems which affect efficiency. During 1993-94 field tests were initiated to obtain such data and to obtain information that would compliment existing and current laboratory work. Experimental work conducted on a bench scale level have included tests with various advanced burners, fuel types, and different operating conditions which have been done at the BNL Rapid Fouling Test Facility. This report will focus on the field study of fouling effects on ten residential heating service problems at each site are summarized. In addition, the technical difficulties involved with conducting such a field study shall also be discussed as the findings should serve to improve future work in this area.

  4. Transparent and Explicable Boiler Fouling Monitoring with Fuzzy Neural Newtwork

    Institute of Scientific and Technical Information of China (English)

    BinWu; You-TingShen

    1998-01-01

    Fouling on boiler beating surfaces is one of the important factors that damage boiler's economical performance and safety,with on-line monitoring of foiling states on boler heating surfaces,it is possible to optimize sootblower system,to visualize fouling states,to improve performance,as well as to remedy the insufficiency of experiment research in boiler heating surface fouling process.New method based on Fuzzy Neural Network(FNN) is presented to monitor fouling states on boiler heating surfaces on-line.Compared with regular methods,since FNN's reasoning process is transparent and comprehensible,it is possible to explain and comprehend reasoning process,which makes the FNN based system perform as an additional operation consulting system.

  5. Stress-Assisted Corrosion in Boiler Tubes

    Energy Technology Data Exchange (ETDEWEB)

    Preet M Singh; Steven J Pawel

    2006-05-27

    A number of industrial boilers, including in the pulp and paper industry, needed to replace their lower furnace tubes or decommission many recovery boilers due to stress-assisted corrosion (SAC) on the waterside of boiler tubes. More than half of the power and recovery boilers that have been inspected reveal SAC damage, which portends significant energy and economic impacts. The goal of this project was to clarify the mechanism of stress-assisted corrosion (SAC) of boiler tubes for the purpose of determining key parameters in its mitigation and control. To accomplish this in-situ strain measurements on boiler tubes were made. Boiler water environment was simulated in the laboratory and effects of water chemistry on SAC initiation and growth were evaluated in terms of industrial operations. Results from this project have shown that the dissolved oxygen is single most important factor in SAC initiation on carbon steel samples. Control of dissolved oxygen can be used to mitigate SAC in industrial boilers. Results have also shown that sharp corrosion fatigue and bulbous SAC cracks have similar mechanism but the morphology is different due to availability of oxygen during boiler shutdown conditions. Results are described in the final technical report.

  6. Fouling characteristics of compact heat exchangers and enhanced tubes.

    Energy Technology Data Exchange (ETDEWEB)

    Panchal, C. B.; Rabas, T. J.

    1999-07-15

    Fouling is a complex phenomenon that (1) encompasses formation and transportation of precursors, and (2) attachment and possible removal of foulants. A basic understanding of fouling mechanisms should guide the development of effective mitigation techniques. The literature on fouling in complex flow passages of compact heat exchangers is limited; however, significant progress has been made with enhanced tubes.

  7. Removal of External Deposits on Boiler Tubes

    Directory of Open Access Journals (Sweden)

    C. P. De

    1970-07-01

    Full Text Available The superheater tubes in Port and Starboard boilers were found to have completely clogged by heavy deposits, which on analysis mainly vanadium pentoxide and sodium sulphmatter. The cleaning of the deposits was accomplished by alternate spraying with 15-20 per cent hydrogen peroxide and washing with hot water jets. Over the past two years, since the date of cleaning, the IN ship is operating without any trouble in the boilers.

  8. Computer simulation of the fire-tube boiler hydrodynamics

    Directory of Open Access Journals (Sweden)

    Khaustov Sergei A.

    2015-01-01

    Full Text Available Finite element method was used for simulating the hydrodynamics of fire-tube boiler with the ANSYS Fluent 12.1.4 engineering simulation software. Hydrodynamic structure and volumetric temperature distribution were calculated. The results are presented in graphical form. Complete geometric model of the fire-tube boiler based on boiler drawings was considered. Obtained results are suitable for qualitative analysis of hydrodynamics and singularities identification in fire-tube boiler water shell.

  9. Computer simulation of the fire-tube boiler hydrodynamics

    OpenAIRE

    Khaustov Sergei A.; Zavorin Alexander S.; Buvakov Konstantin V.; Sheikin Vyacheslav A.

    2015-01-01

    Finite element method was used for simulating the hydrodynamics of fire-tube boiler with the ANSYS Fluent 12.1.4 engineering simulation software. Hydrodynamic structure and volumetric temperature distribution were calculated. The results are presented in graphical form. Complete geometric model of the fire-tube boiler based on boiler drawings was considered. Obtained results are suitable for qualitative analysis of hydrodynamics and singularities identification in fire-tube boiler water shell.

  10. Smooth Surfaces: A review of current and planned smooth surface technologies for fouling resistance in boiler

    Energy Technology Data Exchange (ETDEWEB)

    Corkery, Robert; Baefver, Linda; Davidsson, Kent; Feiler, Adam

    2012-02-15

    Here we have described the basics of boilers, fuels, combustion, flue gas composition and mechanisms of deposition. We have reviewed coating technologies for boiler tubes, including their materials compositions, nano structures and performances. The surface forces in boilers, in particular those relevant to formation of unwanted deposits in boilers have also been reviewed, and some comparative calculations have been included to indicate the procedures needed for further study. Finally practical recommendations on the important considerations in minimizing deposition on boiler surfaces are made

  11. CFD investigation of flow through internally riffled boiler tubes

    DEFF Research Database (Denmark)

    Rasmussen, Christian; Houbak, Niels; Sørensen, Jens Nørkær

    1997-01-01

    In this paper we show how to model the swirling flow in an internally riffled boiler tube. The flow field is visualized and the results are compared with measurements.......In this paper we show how to model the swirling flow in an internally riffled boiler tube. The flow field is visualized and the results are compared with measurements....

  12. CFD Studies on Multi Lead Rifled [MLR] Boiler Tubes

    Directory of Open Access Journals (Sweden)

    Dr T C Mohankumar

    2013-09-01

    Full Text Available This paper reports the merits of multi lead rifled [MLR] tubes in vertical water tube boiler using CFD tool. Heat transfer enhancement of MLR tubes was mainly taken in to consideration. Performance of multi lead rifled tube was studied by varying its influencing geometrical parameter like number of rifling, height of rifling, length of pitch of rifling for a particular length. The heat transfer analysis was done at operating conditions of an actual coal fired water tube boiler situated at Apollo Tyres LTD, Chalakudy, India for saturated process steam production. The results showed that the heat transfer increased when compared with existing inner plane wall water tubes.

  13. Influence of Sorbent Characteristics on Fouling and Deposition in Circulating Fluid Bed Boilers Firing High Sulfur Indian Lignite

    Directory of Open Access Journals (Sweden)

    Selvakumaran Palaniswamy

    2013-01-01

    Full Text Available 125 MWe circulating fluidized bed combustion (CFBC boiler experienced severe fouling in backpass of the boiler leading to obstruction of gas flow passage, while using high sulfur lignite with sorbent, calcium carbonate, to capture sulfur dioxide. Optical microscopy of the hard deposits showed mainly anhydrite (CaSO4 and absence of intermediate phases such as calcium oxide or presence of sulfate rims on decarbonated limestone. It is hypothesized that loose unreacted calcium oxides that settle on tubes are subjected to recarbonation and further extended sulfation resulting in hard deposits. Foul probe tests were conducted in selected locations of backpass for five different compositions of lignite, with varied high sulfur and ash contents supplied from the mines along with necessary rates of sorbent limestone to control SO2, and the deposits build-up rate was determined. The deposit build-up was found increasing, with increase in ash content of lignite, sorbent addition, and percentage of fines in limestone. Remedial measures and field modifications to dislodge deposits on heat transfer surfaces, to handle the deposits in ash conveying system, and to control sorbent fines from the milling circuit are explained.

  14. CONCENTRIC TUBE-FOULING RIG FOR INVESTIGATION OF FOULING DEPOSIT FORMATION FROM PASTEURISER OF VISCOUS FOOD LIQUID

    Directory of Open Access Journals (Sweden)

    N. I. KHALID

    2013-02-01

    Full Text Available This paper reports the work on developing concentric tube-fouling rig, a new fouling deposit monitoring device. This device can detect and quantify the level of fouling deposit formation. It can also functioning as sampler for fouling deposit study, which can be attached at any food processing equipment. The design is initiated with conceptual design. The rig is designed with inner diameter of 7 cm and with tube length of 37 cm. A spiral insert with 34.5 cm length and with 5.4 cm diameter is fitted inside the tube to ensure the fluid flows around the tube. In this work, the rig is attached to the lab-scale concentric tube-pasteurizer to test its effectiveness and to collect a fouling sample after pasteurization of pink guava puree. Temperature changes are recorded during the pasteurization and the data is used to plot the heat transfer profile. Thickness of the fouling deposit is also measured. The trends for thickness, heat resistance profile and heat transfer profile for concentric tube-fouling rig matched the trends obtained from lab-scale concentric tube-pasteurizer very well. The findings from this work have shown a good potential of this rig however there is a limitation with spiral insert, which is discussed in this paper.

  15. Analysis of fouling characteristic in enhanced tubes using multiple heat and mass transfer analogies☆

    Institute of Scientific and Technical Information of China (English)

    Zepeng Wang; Guanqiu Li; Jingliang Xu; Jinjia Wei; Jun Zeng; Decang Lou; Wei Li

    2015-01-01

    This paper provides a comprehensive analysis on cooling tower fouling data taken from seven 15.54 mm I.D. helically ribbed, copper tubes and a plain tube at Re=16000. There are two key processes during fouling formation:fouling deposition and fouling removal, which can be determined by mass transfer and fluid friction respectively. The mass transfer coefficient can be calculated through three analogies:Prandtl analogy, Von–Karman analogy, and Chilton–Colburn analogy. Based on our analyses, Von–Karman analogy is the optimized analogy, which can well predict the formation of cooling tower fouling. Series of semi-theoretical fouling correlations as a function of the product of area indexes and efficiency indexes were developed, which can be applicable to different internally ribbed geometries. The correlations can be directly used to assess the fouling potential of enhanced tubes in actual cooling tower water situations.

  16. A Comparative Study of Fouling and Bottom Ash from Woody Biomass Combustion in a Fixed-Bed Small-Scale Boiler and Evaluation of the Analytical Techniques Used

    Directory of Open Access Journals (Sweden)

    Lara Febrero

    2015-05-01

    Full Text Available In this work, fouling and bottom ash were collected from a low-power boiler after wood pellet combustion and studied using several analytical techniques to characterize and compare samples from different areas and determine the suitability of the analysis techniques employed. TGA results indicated that the fouling contained a high amount of organic matter (70%. The XRF and SEM-EDS measurements revealed that Ca and K are the main inorganic elements and exhibit clear tendency in the content of Cl that is negligible in the bottom ash and increased as it penetrated into the innermost layers of the fouling. Calcite, magnesia and silica appeared as the major crystalline phases in all the samples. However, the bottom ash was primarily comprised of calcium silicates. The KCl behaved identically to the Cl, preferably appeared in the adhered fouling samples. This salt, which has a low melting point, condenses upon contact with the low temperature tube and played a crucial role in the early stages of fouling formation. XRD was the most useful technique applied, which provided a semi-quantitative determination of the crystalline phases. FTIR was proven to be inadequate for this type of sample. The XRF and SEM-EDS, techniques yield similar results despite being entirely different.

  17. Modelling and simulating fire tube boiler performance

    DEFF Research Database (Denmark)

    Sørensen, K.; Condra, T.; Houbak, Niels;

    2003-01-01

    A model for a flue gas boiler covering the flue gas and the water-/steam side has been formulated. The model has been formulated as a number of sub models that are merged into an overall model for the complete boiler. Sub models have been defined for the furnace, the convection zone (split in 2......: a zone submerged in water and a zone covered by steam), a model for the material in the boiler (the steel) and 2 models for resp. the water/steam zone (the boiling) and the steam. The dynamic model has been developed as a number of Differential-Algebraic-Equation system (DAE). Subsequently Mat......Lab/Simulink has been applied for carrying out the simulations. To be able to verify the simulated results experiments has been carried out on a full scale boiler plant....

  18. Modelling and simulating fire tube boiler performance

    DEFF Research Database (Denmark)

    Sørensen, Kim; Karstensen, Claus; Condra, Thomas Joseph;

    2003-01-01

    A model for a ue gas boiler covering the ue gas and the water-/steam side has been formulated. The model has been formulated as a number of sub models that are merged into an overall model for the complete boiler. Sub models have been dened for the furnace, the convection zone (split in 2: a zone...... submerged in water and a zone covered by steam), a model for the material in the boiler (the steel) and 2 models for resp. the water/steam zone (the boiling) and the steam. The dynamic model has been developed as a number of Differential-Algebraic- Equation system (DAE). Subsequently MatLab/Simulink has...... been applied for carrying out the simulations. To be able to verify the simulated results an experiments has been carried out on a full scale boiler plant....

  19. Investigations of ash fouling with cattle wastes as reburn fuel in a small-scale boiler burner under transient conditions.

    Science.gov (United States)

    Oh, Hyukjin; Annamalai, Kalyan; Sweeten, John M

    2008-04-01

    Fouling behavior under reburn conditions was investigated with cattle wastes (termed as feedlot biomass [FB]) and coal as reburn fuels under a transient condition and short-time operation. A small-scale (30 kW or 100,000 Btu/hr) boiler burner research facility was used for the reburn experiments. The fuels considered for these experiments were natural gas (NG) for the ashless case, pure coal, pure FB, and blends of coal and FB. Two parameters that were used to characterize the ash "fouling" were (1) the overall heat-transfer coefficient (OHTC) when burning NG and solid fuels as reburn fuels, and (2) the combustible loss through ash deposited on the surfaces of heat exchanger tubes and the bottom ash in the ash port. A new methodology is presented for determining ash-fouling behavior under transient conditions. Results on the OHTCs for solid reburn fuels are compared with the OHTCs for NG. It was found that the growth of the layer of ash depositions over longer periods typically lowers OHTC, and the increased concentration of ash in gas phase promotes radiation in high-temperature zones during initial periods while decreasing the heat transfer in low-temperature zones. The ash analyses indicated that the bottom ash in the ash port contained a smaller percentage of combustibles with a higher FB percentage in the fuels, indicating better performance compared with coal because small particles in FB burn faster and the FB has higher volatile matter on a dry ash-free basis promoting more burn out.

  20. Boiler Tube Corrosion Characterization with a Scanning Thermal Line

    Science.gov (United States)

    Cramer, K. Elliott; Jacobstein, Ronald; Reilly, Thomas

    2001-01-01

    Wall thinning due to corrosion in utility boiler water wall tubing is a significant operational concern for boiler operators. Historically, conventional ultrasonics has been used for inspection of these tubes. Unfortunately, ultrasonic inspection is very manpower intense and slow. Therefore, thickness measurements are typically taken over a relatively small percentage of the total boiler wall and statistical analysis is used to determine the overall condition of the boiler tubing. Other inspection techniques, such as electromagnetic acoustic transducer (EMAT), have recently been evaluated, however they provide only a qualitative evaluation - identifying areas or spots where corrosion has significantly reduced the wall thickness. NASA Langley Research Center, in cooperation with ThermTech Services, has developed a thermal NDE technique designed to quantitatively measure the wall thickness and thus determine the amount of material thinning present in steel boiler tubing. The technique involves the movement of a thermal line source across the outer surface of the tubing followed by an infrared imager at a fixed distance behind the line source. Quantitative images of the material loss due to corrosion are reconstructed from measurements of the induced surface temperature variations. This paper will present a discussion of the development of the thermal imaging system as well as the techniques used to reconstruct images of flaws. The application of the thermal line source coupled with the analysis technique represents a significant improvement in the inspection speed and accuracy for large structures such as boiler water walls. A theoretical basis for the technique will be presented to establish the quantitative nature of the technique. Further, a dynamic calibration system will be presented for the technique that allows the extraction of thickness information from the temperature data. Additionally, the results of the application of this technology to actual water wall

  1. Modelling of a one pass smoke tube boiler

    DEFF Research Database (Denmark)

    Karstensen, Claus M. S.; Sørensen, Kim

    2004-01-01

    A nonlinear state-space model with five states describing a one pass smoke tube boiler has been formulated. By means of mass- and energy-balance the model describes the dynamics of the Furnace, the Convection Zone and the Water/Steam Part and the three sub models are merged into an overall model...

  2. Influence of furnace tube shapeon thermal strain of fire-tube boilers

    Directory of Open Access Journals (Sweden)

    Gaćeša Branka

    2014-01-01

    Full Text Available The aim of this paper is to use numerical analysis and fine element method-FEM to investigate the influence of furnace tube shape on the thermal strain of fire-tube boilers. Thermal stresses in corrugated furnace tubes of different shape, i.e. with different corrugation pitch and depth, were analysed first. It was demonstrated that the thermal stresses in corrugated furnace tube are significantly reduced with the increase of corrugation depth. Than deformations and stresses in the structure of a fire-tube boiler were analysed in a real operating condition, for the cases of installed plain furnace tube and corrugated furnace tubes with different shapes. It was concluded that in this fire-tube boiler, which is of larger steam capacity, the corrugated furnace tube must be installed, as well as that the maximal stress in the construction is reduced by the installation of the furnace tube with greater corrugation depth. The analysis of stresses due to pressure and thermal loads pointed out that thermal stresses are not lower-order stresses in comparison to stresses due to pressure loads, so they must be taken into consideration for boiler strength analysis. [Projekat Ministarstva nauke Republike Srbije, br. TR 35040 i br. TR 35011

  3. Crystallization fouling of finned tubes during pool boiling: effect of fin density

    Energy Technology Data Exchange (ETDEWEB)

    Esawy, M.; Malayeri, M.R. [University of Stuttgart, Institute for Thermodynamics and Thermal Engineering (ITW), Stuttgart (Germany); Mueller-Steinhagen, H. [University of Stuttgart, Institute for Thermodynamics and Thermal Engineering (ITW), Stuttgart (Germany); German Aerospace Centre (DLR), Institute of Technical Thermodynamics, Stuttgart (Germany)

    2010-11-15

    Bubble characteristics such as density, size, frequency and motion are key factors that contribute to the superiority of nucleate pool boiling over other modes of heat transfer. Nevertheless, if heat transfer occurs in an environment prone to fouling, the very same parameters may lead to accelerated deposit formation due to concentration effects beneath the growing bubbles. This has led to the widely accepted design recommendation to maintain the heat transfer surface temperature below the boiling point if fouling may occur, e.g., in seawater desalination. The present paper aims at investigating the formation of deposits on finned tubes during nucleate pool boiling of CaSO{sub 4} solutions. The test finned tubes are low finned tubes with fin densities of 19 and 26 fins/in. made from Cu-Ni. The fouling experiments were carried out at atmospheric pressure for different heat fluxes ranging from 100 to 300 kW/m{sup 2} and a CaSO{sub 4} concentration of 1.6 g/L. For the sake of comparison, similar runs were performed with smooth stainless steel tubes. The results show that: (1) the fouling resistance decreases with increasing fin density, (2) fouling on the finned tubes was reduced with increasing nucleate boiling activity and (3) if any fouling layer occurred on the finned tubes it could be removed easily. (orig.)

  4. Probe Measures Fouling As In Heat Exchangers

    Science.gov (United States)

    Marner, Wilbur J.; Macdavid, Kenton S.

    1990-01-01

    Combustion deposits reduce transfer of heat. Instrument measures fouling like that on gas side of heat exchanger in direct-fired boiler or heat-recovery system. Heat-flux probe includes tube with embedded meter in outer shell. Combustion gases flow over probe, and fouling accumulates on it, just as fouling would on heat exchanger. Embedded heat-flow meter is sandwich structure in which thin Chromel layers and middle alloy form thermopile. Users determine when fouling approaches unacceptable levels so they schedule cleaning and avoid decreased transfer of heat and increased drop in pressure fouling causes. Avoids cost of premature, unnecessary maintenance.

  5. Influence of boiler load on water tubes burnout

    Energy Technology Data Exchange (ETDEWEB)

    Said, S.A.M.; Habib, M.A.; Badr, H.M.; Mansour, R. [King Fahd Univ. of Petroleum and Minerals, Dhahran (Saudi Arabia). Dept. of Mechanical Engineering

    2009-07-01

    The influence of boiler loads on water tube burnout was investigated. The in-service boiler had 2 burners at different levels located in the front of the burner's wall. Homogenous-flow and separated-flow models were designed to simulate the water circulation and combustion processes inside the boiler tubes. Heat flux calculations were derived by solving the conservation of mass, momentum, and energy equations and species concentration as well as by solving turbulence, reaction rate, and radiation model equations. Results of the study showed that heat flux during full loads ranged from close to 0 to 270 kW/m2. The right side screen wall of the burner exhibited higher heat flux values in the middle region of the wall where large areas were subjected to heat flux close to a maximum of 270 kW/m2. Results also included reductions in heat flux values at partial loads. Maximum values were reduced from 270 kW/m2 ato 230 kW/m2 at 75 per cent capacity and 200 kW/m2 at 60 per cent capacity. The rate of steam generation increased from 0.1 kg/s to 0.153 kg/s when the distance from the burner wall increased from 2 meters to 12 meters. 10 refs., 10 figs.

  6. Mineralogical composition of boiler fouling and slagging deposits and their relation to fly ashes: the case of Kardia power plant.

    Science.gov (United States)

    Kostakis, George

    2011-01-30

    Slagging and fouling deposits from a pulverized lignite fired steam generating unit of the Kardia power plant (West Macedonia, Greece) were mineralogically investigated. The structure and cohesion of these deposits varied, usually depending on the level height of the boiler unit where they were formed. Some of the deposits had complex phase composition. The dominant components of the deposits of the burner zone and of the lower and intermediate boiler zones were the amorphous, anhydrite and hematite, while those of the highest levels contained amorphous, and anhydrite. Furthermore, in deposits formed in various other boiler areas gehlenite, anorthite, diopside, quartz, Ca(2)SiO(4), brownmillerite and other crystalline phases were also identified, usually in low amounts or in traces. The major part of the phases constituting the deposits were formed in the boiler, since only a minor part derived from the unreacted minerals present in lignite. Anhydrite was generated from the reaction of SO(2) with CaO formed mainly by the calcination of calcite as well as from dehydration of gypsum contained in lignite, while hematite was produced mainly from the oxidation of pyrite. The calcium-containing silicates formed in the boiler were mainly the products of reactions between CaO and minerals contained in the lignite.

  7. Final Report: Guided Acoustic Wave Monitoring of Corrosion in Recovery Boiler Tubing

    Energy Technology Data Exchange (ETDEWEB)

    Chinn, D J; Quarry, M J; Rose, J L

    2005-03-31

    Corrosion of tubing used in black-liquor recovery boilers is a major concern in all pulp and paper mills. Extensive corrosion in recovery boiler tubes can result in a significant safety and environmental hazard. Considerable plant resources are expended to inspect recovery boiler tubing. Currently, visual and ultrasonic inspections are primarily used during the annual maintenance shutdown to monitor corrosion rates and cracking of tubing. This Department of Energy, Office of Industrial Technologies project is developing guided acoustic waves for use on recovery boiler tubing. The feature of this acoustic technique is its cost-effectiveness in inspecting long lengths of tubes from a single inspection point. A piezoelectric or electromagnetic transducer induces guided waves into the tubes. The transducer detects fireside defects from the cold side or fireside of the tube. Cracking and thinning on recovery boiler tubes have been detected with this technique in both laboratory and field applications. This technique appears very promising for recovery boiler tube application, potentially expediting annual inspection of tube integrity.

  8. Evaluation of iron aluminide weld overlays for erosion - corrosion resistant boiler tube coatings in low NO{sub x} boilers

    Energy Technology Data Exchange (ETDEWEB)

    DuPont, J.N.; Banovic, S.W.; Marder, A.R. [Lehigh Univ., Bethlehem, PA (United States)

    1996-08-01

    Low NOx burners are being installed in many fossil fired power plants in order to comply with new Clean Air Regulations. Due to the operating characteristics of these burners, boiler tube sulfidation corrosion is often enhanced and premature tube failures can occur. Failures due to oxidation and solid particle erosion are also a concern. A program was initiated in early 1996 to evaluate the use of iron aluminide weld overlays for erosion/corrosion protection of boiler tubes in Low NOx boilers. Composite iron/aluminum wires will be used with the Gas Metal Arc Welding (GMAW) process to prepare overlays on boiler tubes steels with aluminum contents from 8 to 16wt%. The weldability of the composite wires will be evaluated as a function of chemical composition and welding parameters. The effect of overlay composition on corrosion (oxidation and sulfidation) and solid particle erosion will also be evaluated. The laboratory studies will be complemented by field exposures of both iron aluminide weld overlays and co-extruded tubing under actual boiler conditions.

  9. Design of shell-and-tube heat exchangers when the fouling depends on local temperature and velocity

    Energy Technology Data Exchange (ETDEWEB)

    Butterworth, D. [HTFS, Hyprotech, Didcot (United Kingdom)

    2002-07-01

    Shell-and-tube heat exchangers are normally designed on the basis of a uniform and constant fouling resistance that is specified in advance by the exchanger user. The design process is then one of determining the best exchanger that will achieve the thermal duty within the specified pressure drop constraints. It has been shown in previous papers [Designing shell-and-tube heat exchangers with velocity-dependant fouling, 34th US national Heat Transfer Conference, 20-22 August 2000, Pittsburg, PA; Designing shell-and-tube heat exchangers with velocity-dependant fouling, 2nd Int. Conf. on Petroleum and Gas Phase Behavior and Fouling, 27-31 August 2000, Copenhagen] that this approach can be extended to the design of exchangers where the design fouling resistance depends on velocity. The current paper briefly reviews the main findings of the previous papers and goes on to treat the case where the fouling depends also on the local temperatures. The Ebert-Panchal [Analysis of Exxon crude-oil, slip-stream coking data, Engineering Foundation Conference on Fouling Mitigation of Heat Exchangers, 18-23 June 1995, California] form of fouling rate equation is used to evaluate this fouling dependence. When allowing for temperature effects, it becomes difficult to divorce the design from the way the exchanger will be operated up to the point when the design fouling is achieved. However, rational ways of separating the design from the operation are proposed. (author)

  10. Composite tube cracking in kraft recovery boilers: A state-of-the-art review

    Energy Technology Data Exchange (ETDEWEB)

    Singbeil, D.L.; Prescott, R. [Pulp and Paper Research Inst. of Canada, Vancouver, British Columbia (Canada); Keiser, J.R.; Swindeman, R.W. [Oak Ridge National Lab., TN (United States)

    1997-07-01

    Beginning in the mid-1960s, increasing energy costs in Finland and Sweden made energy recovery more critical to the cost-effective operation of a kraft pulp mill. Boiler designers responded to this need by raising the steam operating pressure, but almost immediately the wall tubes in these new boilers began to corrode rapidly. Test panels installed in the walls of the most severely corroding boiler identified austenitic stainless steel as sufficiently resistant to the new corrosive conditions, and discussions with Sandvik AB, a Swedish tube manufacturer, led to the suggestion that coextruded tubes be used for water wall service in kraft recovery boilers. Replacement of carbon steel by coextruded tubes has solved most of the corrosion problems experienced by carbon steel wall tubes, however, these tubes have not been problem-free. Beginning in early 1995, a multidisciplinary research program funded by the US Department of Energy was established to investigate the cause of cracking in coextruded tubes and to develop improved materials for use in water walls and floors of kraft recovery boilers. One portion of that program, a state-of-the-art review of public- and private-domain documents related to coextruded tube cracking in kraft recovery boilers is reported here. Sources of information that were consulted for this review include the following: tube manufacturers, boiler manufacturers, public-domain literature, companies operating kraft recovery boilers, consultants and failure analysis laboratories, and failure analyses conducted specifically for this project. Much of the information contained in this report involves cracking problems experienced in recovery boiler floors and those aspects of spout and air-port-opening cracking not readily attributable to thermal fatigue. 61 refs.

  11. Enhanced tubes for steam condensers. Volume 1, Summary of condensation and fouling; Volume 2, Detailed study of steam condensation

    Energy Technology Data Exchange (ETDEWEB)

    Webb, R.L.; Chamra, L.; Jaber, H.

    1992-02-01

    Electric utility steam condensers typically use plain tubes made of titanium, stainless steel, or copper alloys. Approximately two-thirds of the total thermal resistance is on the water side of the plain tube. This program seeks to conceive and develop a tube geometry that has special enhancement geometries on the tube (water) side and the steam (shell) side. This ``enhanced`` tube geometry, will provide increased heat transfer coefficients. The enhanced tubes will allow the steam to condense at a lower temperature. The reduced condensing temperature will reduce the turbine heat rate, and increase the plant peak load capability. Water side fouling and fouling control is a very important consideration affecting the choice of the tube side enhancement. Hence, we have consciously considered fouling potential in our selection of the tube side surface geometry. Using appropriate correlations and theoretical models, we have designed condensation and water side surface geometries that will provide high performance and be cleanable using sponge ball cleaning. Commercial tube manufacturers have made the required tube geometries for test purposes. The heat transfer test program includes measurement of the condensation and water side heat transfer coefficients. Fouling tests are being run to measure the waterside fouling resistance, and to the test the ability of the sponge ball cleaning system to clean the tubes.

  12. Utilization of coal-water fuels in fire-tube boilers

    Energy Technology Data Exchange (ETDEWEB)

    Morrison, D.K.; Melick, T.A.; Sommer, T.M. [Energy and Environmental Research Corp., Orrville, OH (United States)

    1993-12-31

    The Energy and Environmental Research Corporation (EER), in cooperation with the University of Alabama and Jim Walter Resources, was awarded a DOE contract to retrofit an existing fire-tube boiler with a coal-water slurry (CWS) firing system. Recognizing that combustion efficiency is the principle concern when firing slurry in fire-tube boilers, EER has focused the program on innovative approaches for improving carbon burnout without major modifications to the boiler. The boiler was successfully operated on coal-water slurry for 800 hours. A boiler derate of 20 percent was necessary for successful operation with slurry accounting 62 percent of the total heat input with the balance provided by natural gas. Under these boiler conditions, the carbon conversion was 90 percent. Further data evaluation, a market analysis, and final report preparation remain to be completed.

  13. The use of laser-induced plasma spectroscopy technique for the characterization of boiler tubes

    Energy Technology Data Exchange (ETDEWEB)

    Nicolas, G. [Universidad de A Coruna, Departamento de Ingenieria Industrial II, E-15403 Ferrol (A Coruna) (Spain)], E-mail: gines@cdf.udc.es; Mateo, M.P.; Yanez, A. [Universidad de A Coruna, Departamento de Ingenieria Industrial II, E-15403 Ferrol (A Coruna) (Spain)

    2007-12-15

    The present work focuses on the characterization of boiler tube walls using laser-induced plasma spectroscopy technique with visual inspection by optical and scanning electron microscopy of the cross-sections of these tubes. In a watertube boiler, water runs through tubes that are surrounded by a heating source. As a result, the water is heated to very high temperatures, causing accumulation of deposits on the inside surfaces of the tubes. These deposits play an important role in the efficiency of the boiler tube because they produce a reduction of the boiler heat rate and an increase in the number of tube failures. The objectives are to determine the thickness and arrangement of deposits located on the highest heat area of the boiler and compare them with tube parts where the heat flux is lower. The major deposits found were copper and magnetite. These deposits come mainly from the boiler feedwater and from the reaction between iron and water, and they do not form on the tube walls at a uniform rate over time. Their amount depends on the areas where they are collected. A Nd:YAG laser operating at 355 nm has been used to perform laser-induced plasma spectra and depth profiles of the deposits.

  14. On-Line Life Monitoring Technique for Tube Bundles of Boiler High-Temperature Heating Surface

    Institute of Scientific and Technical Information of China (English)

    Yang Dong; Wang Zhongyuan

    2005-01-01

    High-temperature heating surface such as superheater and reheater of large-sized utility boiler all experiences a relatively severe working conditions. The failure of boiler tubes will directly impact the safe and economic operation of boiler. An on-line life monitoring model of high-temperature heating surface was set up according to the well-known L-M formula of the creep damages. The tube wall metal temperature and working stress was measured by on-line monitoring, and with this model, the real-time calculation of the life expenditure of the heating surface tube bundles were realized. Based on the technique the on-line life monitoring and management system of high-temperature heating surface was developed for a 300 MW utility boiler. An effective device was thus suggested for the implementation of the safe operation and the condition-based maintenance of utility boilers.

  15. Countermeasures against Fouling in Circulating Fluidized Bed Boiler%循环流化床锅炉抵御沾污的对策

    Institute of Scientific and Technical Information of China (English)

    鲁佳易; 巩李明; 聂立; 王鹏; 苏虎; 胡修奎

    2016-01-01

    对循环流化床( Circulating Fluidized Bed, CFB)锅炉燃用典型高钠煤及解决方案进行了综述。首先对比了沾污与结渣的特点与区别,明确目前尚无成熟可靠的方法来解决沾污问题。接着从沾污生成机理着手,分析了沾污的生成过程,阐明沾污通常还伴随着腐蚀。然后根据CFB锅炉的特点,论述其低燃烧温度及气固两相流动在抵御沾污方面的优势,并根据试验结果及现场实际锅炉的运行情况阐述了CFB锅炉的沾污特性。最后,根据CFB锅炉的沾污特点,总结了CFB锅炉燃高钠煤时防止沾污的措施。%This paper presents a review of solutions to and countermeasures against typical fouling due to high sodium content in coal combusted in circulating fluidized bed ( CFB) boilers, The mechanism of fouling and that of slagging are compared concluding that there are no effective and available methods to solve the fouling issues till now. The paper further provides details of the fouling mechanism and its formation process, indicating that the fouling is usually followed by corrosion. Advantages of CFB boilers in anti-fouling due to the two-phase flow characteristic and combustion temperature are given, and the fouling in a CFB boiler along with an experimental study and on a test rig is discussed. Finally, on the basis of the fouling characteristics in CFB boilers, the anti-fouling solutions and methods are presented and relative active methods such as boiler with flue gas recycling system are submitted.

  16. Mechanical Design of Steel Tubing for Use in Black Liquor Recovery Boilers

    Energy Technology Data Exchange (ETDEWEB)

    Taljat, B.; Zacharaia, T.; Wang, X.; Kesier, J.; Swindeman, R.; Hubbard, C.

    1999-05-26

    Finite element models were developed for thermal-mechanical analysis of black liquor recovery boiler floor tubes. Residual stresses in boiler floors due to various manufacturing processes were analyzed. The modeling results were verified by X-ray and neutron diffraction measurements at room temperature on as-manufactured tubes as well as tubes after service. The established finite element models were then used to evaluate stress conditions during boiler operation. Using these finite element models, a parametric response surface study was performed to investigate the influence of material properties of the clad layer on stresses in the floor tubes during various boiler operating conditions, which yielded a generalized solution of stresses in the composite tube floors. The results of the study are useful for identifying the mechanisms of cracking experienced by recovery boilers. Based on the results of the response surface study, a recommendation was made for more suitable materials in terms of the analyzed mechanical properties. Alternative materials and manufacturing processes are being considered to improve the resistance to cracking and the in-service life of composite tubes. To avoid numerous FE stress-strain analyses of composite tubes made of different material combinations, a response surface study was performed that considered two essential mechanical properties of the clad material - coefficient of thermal expansion and yield stress - as independent variables. The response surface study provided a generalized solution of stresses in the floor in terms of the two selected parameters.

  17. Superheater fouling in a BFB boiler firing wood-based fuel blends

    NARCIS (Netherlands)

    Stam, A.F.; Haasnoot, K.; Brem, G.

    2014-01-01

    Four different fuel blends have been fired in a 28 MWel BFB. Wood pellets (test 0) were not problematic for about ten years, contrary to a mixture of demolition wood, wood cuttings, compost overflow, paper sludge and roadside grass (test 1) which caused excessive fouling at a superheater bundle afte

  18. Corrosion of boiler tube alloys in refuse firing: Shredded vs bulk refuse

    Energy Technology Data Exchange (ETDEWEB)

    Krause, H.H. (Battelle, Columbus, OH (United States)); Daniel, P.L.; Blue, J.D. (Babcock Wilcox, Barberton, OH (United States))

    1994-08-01

    Results of corrosion probe exposures at two mass burning incinerators were compared with those conducted in a unit burning refuse-derived fuel. Tests were conducted with carbon steel, low-alloy steels, stainless steels, and high nickel-chromium alloys. Corrosion rates at similar metal and gas temperatures were essentially the same for both types of fuel. Boiler tube performance in the waterwalls of other incinerators confirmed these results. Boiler design and operating conditions appear to be more important factors in tube wastage than the extent of refuse processing.

  19. INVESTIGATION OF FOULING DEPOSIT FORMATION DURING PASTEURIZATION OF CHILI SAUCE BY USING LAB-SCALE CONCENTRIC TUBE-PASTEURIZER

    Directory of Open Access Journals (Sweden)

    NUR ATIKA ALI

    2014-06-01

    Full Text Available This paper investigates the characteristics of fouling deposits obtained from chilli sauce pasteurization. A lab-scale concentric tube-pasteurizer was used to pasteurize the chilli sauce at 0.712 kg/min and 90±5°C. It was operated for 3 hours. Temperature changes were recorded during pasteurization and the data was used to plot the heat transfer profile and the fouling resistance profile. The thickness of the fouling deposit was also measured and the image was taken for every hour. The fouling deposit was collected at every hour to test its stickiness, hardness and flow behaviour. Proximate analysis was also performed and it shows that the fouling deposit from the chilli sauce is categorized as carbohydrate-based fouling deposits. Activation energy of chilli sauce is 7049.4 J.mole-1 which shows a greater effect of temperature on the viscosity. The hardness, stickiness of fouling deposit and the heat resistance increases as the chilli sauce continuously flows inside the heat exchanger.

  20. Corrosion-resistant tube materials for extended life of openings in recovery boilers

    Energy Technology Data Exchange (ETDEWEB)

    Paul, L.D.; Danielson, M.J.; Harper, S.L. (Babcock and Wilcox Co., Alliance, OH (United States). Research and Development Div.); Barna, J.L. (Babcock and Wilcox Co., Barberton, OH (United States). Fossil Power Div.)

    1993-08-01

    The corrosive conditions causing rapid corrosion of Type 304L stainless steel in tube openings have been duplicated in the laboratory. Alternate materials also have been tested, and some show improved corrosion resistance over Type 304L. Alloy 825 and Alloy 625 composite tubing and Alloy 600 and Alloy 625 weld overlay materials all show promise as a replacement for Type 304L in tube openings. All recovery boilers designed or operated at 8.375 MPa (1,200 psi) and above should consider using these replacement materials for tube openings.

  1. Parameter Tuning via Genetic Algorithm of Fuzzy Controller for Fire Tube Boiler

    Directory of Open Access Journals (Sweden)

    Osama I. Hassanein

    2012-04-01

    Full Text Available The optimal use of fuel energy and water in a fire tube boiler is important in achieving economical system operation, precise control system design required to achieve high speed of response with no overshot. Two artificial intelligence techniques, fuzzy control (FLC and genetic-fuzzy control (GFLC applied to control both of the water/steam temperature and water level control loops of boiler. The parameters of the FLC are optimized to locating the optimal solutions to meet the required performance objectives using a genetic algorithm. The parameters subject to optimization are the width of the membership functions and scaling factors. The performance of the fire tube boiler that fitted with GFLC has reliable dynamic performance as compared with the system fitted with FLC.

  2. Nickel-chromium plasma spray coatings: A way to enhance degradation resistance of boiler tube steels in boiler environment

    Energy Technology Data Exchange (ETDEWEB)

    Sidhu, B.S.; Prakash, S.

    2006-03-15

    Boiler tube steels, namely low carbon steel ASTM-SA210-Grade A1 (GrA1), 1Cr-0.5Mo steel ASTM-SA213-T-11 (T11), and 2.25Cr-1Mo steel ASTM-SA213-T-22 (T22), were used as substrate steels. Ni-22Cr-10AI-1Y powder was sprayed as a bond coat 150 {mu}m thick before a 200 {mu}m final coating of Ni-20Cr was applied. Coatings were characterized prior to testing in the environment of a coal fired boiler. The uncoated and coated steels were inserted in the platen superheater zone of a coal fired boiler at around 755{sup o}C for 10 cycles, each 100 h. Coated steels showed lower degradation (erosion-corrosion) rate than uncoated steels showed. The lowest rate was observed in the case of Ni-20Cr coated T11 steel. Among the uncoated steels, the observed rate of degradation was the lowest for the T22 steel.

  3. Nickel-chromium plasma spray coatings: A way to enhance degradation resistance of boiler tube steels in boiler environment

    Science.gov (United States)

    Sidhu, Buta Singh; Prakash, S.

    2006-03-01

    Boiler tube steels, namely low carbon steel ASTM-SA-210-Grades A1 (GrA1), 1Cr-0.5Mo steel ASTM-SA213-T-11 (T11), and 2.25Cr-1 Mo steel ASTM-SA213-T-22(T22), were used as substrate steels. Ni-22Cr-10Al-1Y powder was sprayed as a bond coat 150 μm thick before a 200 μm final coating of Ni-20Cr was applied Coatings were characterized prior to testing in the environment of a coal fire boiler. The uncoated and coated steels were inserted in the platen superheater zone of a coal fired boiler at around 755°C for 10 cycles, each 100 h. Coated steels showed lower degradation (erosion-corrosion) rate than uncoated steels showed. The lowest rate was observed in the case of Ni-20Cr coated T11 steel. Among the uncoated steels, the observed rate of degradation was the lowest for the T22 steel.

  4. Analysis of Boiler Operational Variables Prior to Tube Leakage Fault by Artificial Intelligent System

    Directory of Open Access Journals (Sweden)

    Al-Kayiem Hussain H.

    2014-07-01

    Full Text Available Steam boilers are considered as a core of any steam power plant. Boilers are subjected to various types of trips leading to shut down of the entire plant. The tube leakage is the worse among the common boiler faults, where the shutdown period lasts for around four to five days. This paper describes the rules of the Artificial Intelligent Systems to diagnosis the boiler variables prior to tube leakage occurrence. An Intelligent system based on Artificial Neural Network was designed and coded in MATLAB environment. The ANN was trained and validated using real site data acquired from coal fired power plant in Malaysia. Ninety three boiler operational variables were identified for the present investigation based on the plant operator experience. Various neural networks topology combinations were investigated. The results showed that the NN with two hidden layers performed better than one hidden layer using Levenberg-Maquardt training algorithm. Moreover, it was noticed that hyperbolic tangent function for input and output nodes performed better than other activation function types.

  5. Flue gas dust composition and fouling tendency in recovery boilers; Flygaskans sammansaettning och nedsmutsande tendens i sodapannan

    Energy Technology Data Exchange (ETDEWEB)

    Forssen, Mikael; Backman, Rainer; Wallen, Jonas; Hupa, Mikko [Aabo Akademi (Finland)

    2000-02-01

    In this work eight Swedish black liquors have been characterized for the following properties: Combustability and bed behavior; Dust formation tendency; Fouling tendency of dust; SO{sub 2} formation tendency; and, NO formation tendency. The research was made using; (i) chemical analysis of the samples, (ii) special laboratory scale combustion and pyrolysis tests and (iii) an advanced computer model (Recovery Boiler Chemistry Advisor) for calculating the chemical composition and melting properties of the flue gas dust (fly ash). All tests and analysis were successfully performed and the results were reproducible and reliable. The results were classified for each of the five properties from one to five, and summarised into a table. The liquors showed good or extremely good combustability, also the behavior of the bed was normal or extremely good. None of the liquors had extremely high or low values in their swelling tendency or in their total combustion times. The liquors showed bigger differences in their tendency to form dust. Most of the liquors were 'good' because of the lower than normal tendency to form dust during combustion. Only one of the liquors, liquor B, was rated as 'bad', one of the liquors, liquor E, was rated 'extremely good', in other words liquor B had the highest tendency to form dust whereas liquor E had the lowest tendency to form dust. The advanced computer modelling work gave the composition, and the melting properties for the two dust components, carry-over and the condensed dust. The fouling tendency of the liquors were extremely good (low), the differences were so small that no distinction could be made between the liquors. Compared to earlier studies, the sticky temperature, T{sub 15}, for the eight liquors were extremely high, for both modelling cases when the combustion was assumed to take place either in a 'cold' or in a 'hot' furnace. This is partly explained by the fact that the

  6. Overview of the DOE studies of recovery boiler floor tube cracking

    Energy Technology Data Exchange (ETDEWEB)

    Keiser, J.R.; Taljat, B.; Wang, X.L. [and others

    1998-03-01

    Cracking of the stainless steel layer of coextruded 304L/SA210 recovery boiler floor tubes has been observed in an increasing number of black liquor recovery boilers. Because failure of such tubes is a serious safety concern as well as an economic issue, this project was initiated with the objective of identifying alternate materials or process changes that would prevent tube cracking. Tensile stresses are essential for the most likely failure mechanisms, i.e., fatigue or stress corrosion cracking, therefore stresses were measured at room temperature and modeling was used to predict stresses under operating conditions. Laboratory studies have identified conditions under which composite tubes crack due to thermal fatigue and stress corrosion. Floor tube temperature measurements have defined the magnitude and frequency of temperature fluctuations experienced by such tubes, and smelt corrosion studies have measured the degradation rate when molten smelt comes in contact with tubes. Based on these observations, certain materials appear more likely to resist cracking and certain process changes should help avoid conditions that cause composite tube cracking.

  7. Modelling of thermal behaviour of iron oxide layers on boiler tubes

    Science.gov (United States)

    Angelo, J. D.; Bennecer, A.; Kaczmarczyk, S.; Picton, P.

    2016-05-01

    Slender boiler tubes are subject to localised swelling when they are expose to excessive heat. The latter is due to the formation of an oxide layer, which acts as an insulation barrier. This excessive heat can lead to microstructural changes in the material that would reduce the mechanical strength and would eventually lead to critical and catastrophic failure. Detecting such creep damage remains a formidable challenge for boiler operators. It involves a costly process of shutting down the plant, performing electromagnetic and ultrasonic non-destructive inspection, repairing or replacing damaged tubes and finally restarting the plant to resume its service. This research explores through a model developed using a finite element computer simulation platform the thermal behaviour of slender tubes under constant temperature exceeding 723 °K. Our simulation results demonstrate that hematite layers up to 15 μm thickness inside the tubes do not act as insulation. They clearly show the process of long term overheating on the outside of boiler tubes which in turn leads to initiation of flaws.

  8. Early tube leak detection system for steam boiler at KEV power plant

    Directory of Open Access Journals (Sweden)

    Ismail Firas B.

    2016-01-01

    Full Text Available Tube leakage in boilers has been a major contribution to trips which eventually leads to power plant shut downs. Training of network and developing artificial neural network (ANN models are essential in fault detection in critically large systems. This research focusses on the ANN modelling through training and validation of real data acquired from a sub-critical boiler unit. The artificial neural network (ANN was used to develop a compatible model and to evaluate the working properties and behaviour of boiler. The training and validation of real data has been applied using the feed-forward with back-propagation (BP. The right combination of number of neurons, number of hidden layers, training algorithms and training functions was run to achieve the best ANN model with lowest error. The ANN was trained and validated using real site data acquired from a coal fired power plant in Malaysia. The results showed that the Neural Network (NN with one hidden layers performed better than two hidden layer using feed-forward back-propagation network. The outcome from this study give us the best ANN model which eventually allows for early detection of boiler tube leakages, and forecast of a trip before the real shutdown. This will eventually reduce shutdowns in power plants.

  9. Mathematical Model for Predicting Corrosion Rates in Furnace Internal Wall Tubes of The Refinery Boiler

    Directory of Open Access Journals (Sweden)

    Edori, E. S

    2016-08-01

    Full Text Available A model for predicting the corrosion rates in the furnace internal wall tubes of the refinery boiler was resolved, using the first order differential equation derived from the material balance equation of the system. The mathematical model was able to predict the metal loss recorded by ultrasonic thickness scanning technique (UTS, and the results shows an agreement. The results from both the model and UTS shows that in the various tubes of the furnace, internal wall of the refinery boiler were between the same range. The percentage deviation which was calculated to ascertain the acceptability of the model result as compared to that from UTS proved that the model is effective. The inhibitor model result show that corrosion will drastically reduce in the presence of corrosion inhibitors under proper chemical treatment and management. The model developed can be used to monitor furnace internal wall corrosion even when the system is in operation by extrapolating the result to further years.

  10. Cracking and Corrosion of Composite Tubes in Black Liquor Recovery Boiler Primary Air Ports

    Energy Technology Data Exchange (ETDEWEB)

    Keiser, James R.; Singbeil, Douglas L.; Sarma, Gorti B.; Kish, Joseph R.; Yuan, Jerry; Frederick, Laurie A.; Choudhury, Kimberly A.; Gorog, J. Peter; Jetté, Francois R.; Hubbard, Camden R.; Swindeman, Robert W.; Singh, Prett M.; Maziasz, Phillip J.

    2006-10-01

    Black liquor recovery boilers are an essential part of kraft mills. Their design and operating procedures have changed over time with the goal of providing improved boiler performance. These performance improvements are frequently associated with an increase in heat flux and/or operating temperature with a subsequent increase in the demand on structural materials associated with operation at higher temperatures and/or in more corrosive environments. Improvements in structural materials have therefore been required. In most cases the alternate materials have provided acceptable solutions. However, in some cases the alternate materials have solved the original problem but introduced new issues. This report addresses the performance of materials in the tubes forming primary air port openings and, particularly, the problems associated with use of stainless steel clad carbon steel tubes and the solutions that have been identified.

  11. EXPERIMENTAL INVESTIGATION OF NICKEL ALUMINIDE (NI3AL) NANOSTRUCTURED COATED ECONOMISER TUBE IN BOILER

    OpenAIRE

    * Gokulakannan A, Karuppasamy K

    2016-01-01

    Thermal Power Stations all over the world are facing the problem of boiler tube leakage frequently. The consequences of which affects the performance of power plant and huge amount of money loss. Hot corrosion and erosion are recognized as serious problems in coal based power generation plants in India. The maximum number of cause of failure in economizer unit is due to flue gas erosion. The corrosion resistant coatings used conventionally are having some limitations like degradation of the c...

  12. On the influence of chlorides and sulphureous compounds on the corrosion of superheater tubes in boilers with special consideration on kraft recovery boilers

    Energy Technology Data Exchange (ETDEWEB)

    Bruno, Fredrik [AaF-IPK AB, Stockholm (Sweden)

    1999-03-01

    This report reviews the thermochemistry of the most relevant corrosion reactions and mechanisms with chloride especially considering the kraft pulp mill recovery boiler. The flue gas side corrosion of superheater tubes is governed by the fuel constituents, and by the carryover particles and the gaseous impurities accompanying the flue gases and the local chemical conditions they cause on the superheater tube surface. A study made on coal-fired boilers in Germany has been interpreted so that the protective ability of the oxide layer on the tube surface of a superheater tube is limited, which causes a close to linear time dependence of the material loss due to corrosion. The thermochemistry of the reactions of the protective oxide layer itself with the components of the deposited carryover and the flue gas sulphur components seems thus to govern the mechanism of the corrosion. The corrosion in the recovery boiler is concluded to be more dependant on this combined action of carry-over and sulphureous oxides, so the presence of chlorides in the flue gases only influences the melting range properties of the sulphate deposits, but seems to exert less influence on the chemical reactions which attack the oxides of the passive layer. The thermochemistry also explains the formation of a sulphide layer often found between the deposits and the surface of the tube metal on superheater tubes as a result of reaction with sulpureous oxides from the flue gas and carbon in the carryover. The factors which in practice limit the superheater corrosion in the recovery boiler are interpreted as both material and process dependent. The main limiting factor for the steam temperature is still the melting range of the sulphate deposit. There seems thus to be little hope for the aim to raise the steam temperature of the kraft recovery boiler above the range which is already achievable with the presently available composite tubes 22 refs, 10 figs

  13. Iron aluminide weld overlay coatings for boiler tube protection in coal-fired low NOx boilers

    Energy Technology Data Exchange (ETDEWEB)

    Banovic, S.W.; DuPont, J.N.; Marder, A.R. [Lehigh Univ., Bethlehem, PA (United States). Energy Research Center

    1997-12-01

    Iron aluminide weld overlay coatings are currently being considered for enhanced sulfidation resistance in coal-fired low NO{sub x} boilers. The use of these materials is currently limited due to hydrogen cracking susceptibility, which generally increases with an increase in aluminum concentration of the deposit. The overall objective of this program is to attain an optimum aluminum content with good weldability and improved sulfidation resistance with respect to conventional materials presently in use. Research has been initiated using Gas Tungsten Arc Welding (GTAW) in order to achieve this end. Under different sets of GTAW parameters (wire feed speed, current), both single and multiple pass overlays were produced. Characterization of all weldments was conducted using light optical microscopy, scanning electron microscopy, and electron probe microanalysis. Resultant deposits exhibited a wide range of aluminum contents (5--43 wt%). It was found that the GTAW overlays with aluminum contents above {approximately}10 wt% resulted in cracked coatings. Preliminary corrosion experiments of 5 to 10 wt% Al cast alloys in relatively simple H{sub 2}/H{sub 2}S gas mixtures exhibited corrosion rates lower than 304 stainless steel.

  14. On-line monitoring and control of furnace wall corrosion in pf-fired boilers

    Energy Technology Data Exchange (ETDEWEB)

    Farrell, D.M.; Robbins, B.J.; Sikka, P.; Seaman, M. [Rowan Technologies Ltd., Manchester (United Kingdom)

    2004-05-15

    Corrosion, fouling and sometimes failure of heat exchanger tubing that makes up the boiler walls is a major obstacle to minimising boiler downtime. Rowan Technologies Ltd., has been developing corrosion scanners to enable the condition of these heat exchanger tubes to be assessed online. These scanners are able to monitor fireside corrosion over entire boiler walls and whilst the boiler is operational. This paper describes how the scanner systems can be used to monitor this corrosion and how the corrosion can be subsequently controlled. 8 refs., 9 figs.

  15. An advanced maintenance advisory and surveillance system for boiler tubes - AMASS

    Energy Technology Data Exchange (ETDEWEB)

    Tomkins, A.B. [ERA Technology Ltd, Leatherhead (United Kingdom)

    1998-12-31

    In a recently completed European collaborative project, the aim was to address the issue of boiler tube failures and thereby plant availability. The reduction of forced outages due to component failures and the reduction of planned outages for preventative maintenance can both contribute in this respect. It has been possible to assess tube degradation due to erosion, corrosion and overheating through the use of on-line techniques (thin layer activation, corrosion probes and novel temperature sensors) and off-line techniques (cold air velocity measurements, laser shearography and measurements of steam side oxide) which have been developed in the project. These techniques have been demonstrated on an oil fired boiler in Portugal and a coal fired unit in Spain. The output from the monitoring techniques has been integrated in the AMASS maintenance advisory and surveillance system. This is a computerised system comprising a spatial database with add-on tools designed to assess data from individual monitors and to provide the user with information on tube life utilisation rates and the probability of tube failure occurring. A description of the monitoring techniques will be described along with some of the results of demonstrating them in the field. Also an overview of the computerized system and the way in which it works will be given along with examples of how it can be used to assist with preventative maintenance and to help avoid unplanned outages. (orig.) 10 refs.

  16. Automating data analysis during the inspection of boiler tubes using line scanning thermography

    Science.gov (United States)

    Ley, Obdulia; Momeni, Sepand; Ostroff, Jason; Godinez, Valery

    2012-05-01

    Failures in boiler waterwalls can occur when a relatively small amount of corrosion and loss of metal have been experienced. This study presents our efforts towards the application of Line Scanning Thermography (LST) for the analysis of thinning in boiler waterwall tubing. LST utilizes a line heat source to thermally excite the surface to be inspected and an infrared detector to record the transient surface temperature increase observed due to the presence of voids, thinning or other defects. In waterwall boiler tubes the defects that can be detected using LST correspond to corrosion pitting, hydrogen damage and wall thinning produced by inadequate burner heating or problems with the water chemistry. In this paper we discuss how the LST technique is implemented to determine thickness from the surface temperature data, and we describe our efforts towards developing a semiautomatic analysis tool to speed up the time between scanning, reporting and implementing repairs. We compare the density of data produced by the common techniques used to assess wall thickness and the data produced by LST.

  17. 基于冯·卡门类比的强化管污垢模型及抗垢机理%Fouling model of enhanced tubes based on von Karman analogy and anti-fouling mechanism

    Institute of Scientific and Technical Information of China (English)

    张仲彬; 李煜; 徐志明

    2012-01-01

    The comparative experiments on the CaCO3 fouling characteristics of four enhanced tubes (including the corrugated tube, convergent-divergent tube I , convergent-divergent tube II and arc-line tube) and a plain tube under the same operating conditions, such as the inlet temperature, flow velocity and hardness of artificial hard water and bath temperature of tubes, were carried out. Based on the von Karman analogy, ψ and ψ were regarded as their performance evaluation factors of heat transfer, ηψ and ηψ were used as their comprehensive performance evaluation indexes, and then a fouling model of enhanced tubes was established through the analysis of experimental data, such as their fouling resistance Rf and geometric parameters. The anti-fouling mechanisms of each enhanced tube were analyzed. The results show that it is the secondary turbulence and periodic pulse along the axis of flow velocity direction in the corrugated tube scouring near-wall flow that enhances the removal mass rate of fouling dramatically so that it is difficult for the tube to cause fouling and even realize automatic cleaning. The arc-line tube has the anti-fouling performance in which the periodic disturbance of flow in it weakens fouling deposition and the sharp increasing laryngeal wall shear stress boosting fouling removes greatly. The convergent-divergent tube can resist fouling because the fouling removal mass rate is enhanced doubly by fluid's intensive periodic disturbance caused by the alternate switch of axis pressure gradient and the swing eddy current at the laryngeal.%对比实验研究4种强化管(波纹管、缩放管Ⅰ、缩放管Ⅱ和弧线管)和光管在相同工况(人工硬水入口温度、流速、硬度及水浴温度)下的CaCO3污垢特性.通过分析强化管污垢热阻Rf与几何参数等,基于冯·卡门类比法,以ψ和ψ为强化管传热性能评价因子,η(Ψ)和η(ψ)为其综合性能评价指标,构建强化管污垢数据分析模型,并逐一

  18. FAILURE ANALYSIS IN TUBING OF AIR PREHEATER OF BOILER FROM A SUGARCANE MILL

    Directory of Open Access Journals (Sweden)

    Joner Oliveira Alves

    2014-10-01

    Full Text Available The increased demand for energy from sugarcane bagasse has made the sugar and alcohol mills search alternatives to reduce maintenance of the boilers, releasing more time to the production. The stainless steel use has become one of the main tools for such reduction. However, specification errors can lead to premature failures. This work reports the factors that led tubes of AISI 409 stainless steel fail after half season when applied in a air preheater of boiler from a sugarcane mill. In such application, the AISI 304 lasts about 15 seasons and the carbon steel about 3. A tube sent by the sugar mill was characterized by wet chemical analysis, optical microscopy and EDS. Results indicated chloride formation on the internal walls of the tube, which combined with the environment, accelerated the corrosion process. The carbon steel showed high lifetime due to a 70% higher thickness. Due to the work condictions is recommended the use of stainless steels with higher corrosion resistance, such as the traditional AISI 304 or the ferritic AISI 444, the last presents better thermal exchange.

  19. Modificaciones en las calderas igneotubulares cubanas // Modifications in the Cuban boilers of fire tube

    Directory of Open Access Journals (Sweden)

    I. Pérez Mallea

    1998-01-01

    Full Text Available El objetivo de este trabajo es optimizar y diseñar las calderas igneotubulares nacionales, incluyendo las de inversión de llama yagua caliente. Con este fin se creo un software como soporte científico técnico que permite realizar los diferentes cálculosverificativos a través de los cuales se optimiza._________________________________________________________________________Abstract .The objective of this work is the optimizing and designing of the Cuban boilers of fire tube, including those of inverting offlame and hot water. A software have been developed as technical scientific supper for different calculations and optimizingprocess.

  20. INTRODUCTION TO INCONEL ALLOY 740: AN ALLOY DESIGNED FOR SUPERHEATER TUBING IN COAL-FIRED ULTRA SUPERCRITICAL BOILERS

    Institute of Scientific and Technical Information of China (English)

    S.J. Patel

    2005-01-01

    Chinese utilities as well as those worldwide are facingincreased demand for additional electric-ity, reduced plant emissions and greater efficiency.To meet this challenge willrequire increas-ing boiler temperature,pressure and coal ashcorrosion resistance of the materials of boiler construction of future coal-fired boilers. A new nickel-based tube alloy, INCONELRalloy 740,is described aiming at meeting this challenge. Emphasis will be on describing the alloy s mechanical properties, coal-ash and steam corrosion resistance.Microstructural stability as a function of temperature and time is addressed as well as some of the early methodology employed to arrive at the current chemical composition.

  1. Stress and integrity analysis of steam superheater tubes of a high pressure boiler

    Directory of Open Access Journals (Sweden)

    Neves Daniel Leite Cypriano

    2004-01-01

    Full Text Available Sources that can lead to deterioration of steam superheater tubes of a high pressure boiler were studied by a stress analysis, focused on internal pressure and temperature experienced by the material at real operating conditions. Loss of flame control, internal deposits and unexpected peak charge are factors that generate loads above the design limit of tube materials, which can be subjected to strain, buckling, cracks and finally rupture in service. To evaluate integrity and dependability of these components, the microstructure of selected samples along the superheater was studied by optical microscopy. Associated with this analysis, dimensional inspection, nondestructive testing, hardness measurement and deposit examination were made to determine the resultant material condition after twenty three years of operation.

  2. Development of Computational Capabilities to Predict the Corrosion Wastage of Boiler Tubes in Advanced Combustion Systems

    Energy Technology Data Exchange (ETDEWEB)

    Kung, Steven; Rapp, Robert

    2014-08-31

    coal-fired boilers resulting from the coexistence of sulfur and chlorine in the fuel. A new corrosion mechanism, i.e., “Active Sulfidation Corrosion Mechanism,” has been proposed to account for the accelerated corrosion wastage observed on the furnace walls of utility boilers burning coals containing sulfur and chlorine. In addition, a second corrosion mechanism, i.e., “Active Sulfide-to-Oxide Corrosion Mechanism,” has been identified to account for the rapid corrosion attack on superheaters and reheaters. Both of the newly discovered corrosion mechanisms involve the formation of iron chloride (FeCl2) vapor from iron sulfide (FeS) and HCl, followed by the decomposition of FeCl2 via self-sustaining cycling reactions. For higher alloys containing sufficient chromium, the attack on superheaters and reheaters is dominated by Hot Corrosion in the presence of a fused salt. Furthermore, two stages of the hot corrosion mechanism have been identified and characterized in detail. The initiation of hot corrosion attack induced by molten sulfate leads to Stage 1 “acidic” fluxing and re-precipitation of the protective scale formed initially on the deposit-covered alloy surfaces. Once the protective scale is penetrated, Stage 2 Hot Corrosion is initiated, which is dominated by “basic” fluxing and re-precipitation of the scale in the fused salt. Based on the extensive corrosion information generated from this project, corrosion modeling was performed using non-linear regression analysis. As a result of the modeling efforts, two predictive equations have been formulated, one for furnace walls and the other for superheaters and reheaters. These first-of-the-kind equations can be used to estimate the corrosion rates of boiler tubes based on coal chemistry, alloy compositions, and boiler operating conditions for advanced boiler systems.

  3. 管内颗粒污垢特性分析%Analysis of in tubes particulate fouling characteristic

    Institute of Scientific and Technical Information of China (English)

    李红霞; 李冠球; 李蔚

    2012-01-01

    为了研究强化管管内污垢特性,选取一组直肋管与光管管内颗粒污垢实验进行了分析,对光管和不同几何设计的3种内置直肋管进行了研究,实验所用颗粒为氧化铝和氧化铁颗粒,平均直径分别为1.75 μm和2.11 μm,质量密度约为1 500 mg/L,实验段的热流密度约为13 kW/m2.实验发现,光管的污垢热阻渐进值最小,其次是型号为30/10,30/20,15/10的直肋管,为此建立了一半理论化模型,对影响颗粒污垢形成的主要因素进行了研究.污垢模型从最常用的质量平衡模型出发,分别讨论了质量传递系数、壁面剪切应力、黏附几率、污垢抗分散强度的影响因素,理论模型与实验结果吻合良好.另外,在进行相应简化后,对实验相应管型进行了二维数值分析,数值分析采用控制容积法和标准k-ω模型.为解释不同管型在抗垢性能上的差异,讨论了不同管型的近壁面流场分布以及壁面剪切应力对颗粒污垢沉积的影响,发现壁面剪切力越大,污垢热阻值越小,而肋间距是影响壁面剪切力的重要几何参数.数值模拟结果与经验公式和实验结果相比也有合理的偏差.%In order to discover the fouling characteristic inside enhanced tubes, the paniculate fouling tests including one smooth tube and three internal repeated rib tubes with different geometry designs were carried out. Foulant in the particulate fouling tests was aluminum oxide and ferric oxide, which had an average diameter of 1. 75 μm and 2. 11 μm, respectively. The foulant concentration was about 1500 mg/L and the heat flux in the test section was about 13 kW/m2. The experimental results show that the plane tube has the smallest fouling resistance, and the next is rib tube of product code 30/10, 30/20, 15/10, A semi-theoretical model was developed to investigate the main factors of particulate fouling formation from the fouling tests. The fouling model which started from the mass balance

  4. The Hot Corrosion Performance of NiCr-Cr3 C2 Cermet Coating to Boiler Tube

    Institute of Scientific and Technical Information of China (English)

    DINGZhang-xiong; TUGuo-fu

    2004-01-01

    Three kinds of NiCr-Cr3 C2 cermet coatings were designed and deposited by the subsonic velocity flame spraying, and their performances of hot corrosion performance were evaluated in comt)arison with 102G,20G boiler tube steel, FeCrAl, NiCrTi, Ni5OCr and NiCrAIMoFe-Cr3 C2 coatings, which are widely used at present for protection of boiler tubes. Meanwhile, the influence of sealer on the hot corrosion resistance of warious coatings and the mechanisms of coating corrosion were explored.

  5. Thermographic Imaging of Material Loss in Boiler Water-Wall Tubing by Application of Scanning Line Source

    Science.gov (United States)

    Cramer, K. Elliott; Winfree, William P.

    2000-01-01

    Localized wall thinning due to corrosion in utility boiler water-wall tubing is a significant inspection concern for boiler operators. Historically, conventional ultrasonics has been used for inspection of these tubes. This technique has proven to be very manpower and time intensive. This has resulted in a spot check approach to inspections, documenting thickness measurements over a relatively small percentage of the total boiler wall area. NASA Langley Research Center has developed a thermal NDE technique designed to image and quantitatively characterize the amount of material thinning present in steel tubing. The technique involves the movement of a thermal line source across the outer surface of the tubing followed by an infrared imager at a fixed distance behind the line source. Quantitative images of the material loss due to corrosion are reconstructed from measurements of the induced surface temperature variations. This paper will present a discussion of the development of the thermal imaging system as well as the techniques used to reconstruct images of flaws. The application of the thermal line source coupled with the analysis technique represents a significant improvement in the inspection speed for large structures such as boiler water-walls. A theoretical basis for the technique will be presented which explains the quantitative nature of the technique. Further, a dynamic calibration system will be presented for the technique that allows the extraction of thickness information from the temperature data. Additionally, the results of applying this technology to actual water-wall tubing samples and in situ inspections will be presented.

  6. Remaining Life Analysis of Boiler Tubes on Behalf of Hoop Stresses Produced During Operation of Power Plant

    Directory of Open Access Journals (Sweden)

    Mohd. Zeeshan Gauri

    2014-07-01

    Full Text Available Boiler tube material plays an important role in efficient power generation from a fossil fuel power plant. In order to meet out the gap between fluids to increase heat available per unit mass flow of steam. Waste heat utilization phenomenon is a big challenge on fossil fuel power plants as after use of high grade coal in thermal power plants the efficiency of power plants is not at the level of required value. Clean and efficient power generation with economical aspects is the basic need of growing power generation plants to justify the quality of power and clean power generation. Life analysis technique to calculate remaining life of boiler tubes at critical zones of high temperature requires much attention and is an important hypothesis in research field. Generation of repetitive and fluctuating stress during flow of high temperature and pressure fluid require proper attention on the methodology to be used to calculate the efficiency of system and absorption efficiency of tube material. In this paper complete mathematical analysis of boiler tubes is conducted for calculation of remaining life of boiler tubes, Hoop stress values are calculated and used with mathematical tool to calculate the efficiency. Hoop stress based calculation of efficiency is more reliable and may give more accurate and practical aspects based results.

  7. Thermal-hydraulic modeling of the steady-state operating conditions of a fire-tube boiler

    Directory of Open Access Journals (Sweden)

    Rahmani Ahmed

    2009-01-01

    Full Text Available In this work, we are interested to simulate the thermal-hydraulic behavior of three-pass type fire-tube boiler. The plant is designed to produce 4.5 tons per hour of saturated steam at 8 bar destined principally for heating applications. A calculation program is developed in order to simulate the boiler operation under several steady-state operating conditions. This program is based upon heat transfer laws between hot gases and the fire-tube internal walls. In the boiler combustion chamber, the heat transfer has been simulated using the well-stirred furnace model. In the convection section, heat balance has been carried out to estimate the heat exchanges between the hot gases and the tube banks. The obtained results are compared to the steady-state operating data of the considered plant. A comparative analysis shows that the calculation results are in good agreement with the boiler operating data. Furthermore, a sensitivity study has been carried out to assess the effects of input parameters, namely the fuel flow rate, air excess, ambient temperature, and operating pressure, upon the boiler thermal performances.

  8. Particle Image Velocimetry Measurment of Flow Across Tube Bundle in Waste Heat Boiler

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    In the present paper the experimental investigations of flow across staggered tube bundles in waste heat boiler are conducted by mans of PIV (Particle Image Velocimetry)system,Flow visualization and velocity distribution of the wake between different cylinders are measured in detail.It is concluded that there are still Von Karman vortices in the wake and the phenomenas of vortex shedding,pairing,merging are observed in the flow.The Von Karman vortices can't fully developed because of the existence of the downstream cylinder.There is interaction between main streams and vortices,and the development of the vortex is enhanced by this interaction.Meanwhile some statistical results are performed.The distribution of correlated variables of the velocity fluctuations μ′μ′,μ′ν′,ν′ν′ and the space correlation coefficients are obtained.

  9. Microstructural degradation of boiler tube steels under long term exposure to high temperature

    Energy Technology Data Exchange (ETDEWEB)

    Salonen, J.; Auerkari, P. [VTT Manufacturing Technology, Espoo (Finland)

    1996-12-31

    Thermal microstructural degradation was investigated by isothermal annealing of samples from boiler tube steels St 35.8, 15 Mo 3, 13 CrMo 44, 10 CrMo 9 10 and X20 CrMoV 12 1 in the temperature range 600-780 deg C for up to 2 000 h. Optical and scanning electron microscopy and hardness testing were used for characterising the micro structural changes and their time-temperature dependence. The results suggest a simple and consistent time-temperature dependence for all investigated materials, expected to apply also to long term service beyond the annealing time range of the present work. This would allow assessment of the in-service thermal exposure from the observed microstructure. A collection of micro graphs has been prepared for this purpose, to aid in classifying and evaluating the observed microstructural state in terms of isothermal exposure to high temperature. (orig.) (6 refs.)

  10. Developing an early laekage detection system for thermal power plant boiler tubes by using acoustic emission technology

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Sang Bum [RECTUSON, Co., LTD, Masan (Korea, Republic of); Roh, Seon Man [Samcheonpo Division, Korea South-East Power Co., Samcheonpo (Korea, Republic of)

    2016-06-15

    A thermal power plant has a heat exchanger tube to collect and convert the heat generated from the high temperature and pressure steam to energy, but the tubes are arranged in a complex manner. In the event that a leakage occurs in any of these tubes, the high-pressure steam leaks out and may cause the neighboring tubes to rupture. This leakage can finally stop power generation, and hence there is a dire need to establish a suitable technology capable of detecting tube leaks at an early stage even before it occurs. As shown in this paper, by applying acoustic emission (AE) technology in existing boiler tube leak detection equipment (BTLD), we developed a system that detects these leakages early enough and generates an alarm at an early stage to necessitate action; the developed system works better that the existing system used to detect fine leakages. We verified the usability of the system in a 560 MW-class thermal power plant boiler by conducting leak tests by simulating leakages from a variety of hole sizes (⌀2, ⌀5, ⌀10 mm). Results show that while the existing fine leakage detection system does not detect fine leakages of ⌀2 mm and ⌀5 mm, the newly developed system could detect leakages early enough and generate an alarm at an early stage, and it is possible to increase the signal to more than 18 dB.

  11. Needs-driven soot blowing in waste boilers; Behovsstyrd sotblaasning i avfallspannor

    Energy Technology Data Exchange (ETDEWEB)

    Niklasson, Fredrik; Davidsson, Kent

    2009-09-15

    The increased use of alternative and waste fuels has resulted in an increased number of plants having trouble with fouling and corrosion on boiler banks and superheater tubes. Frequent sootblowing will keep the surfaces relatively clean, but on the other hand, it may erode the tube material. An intelligent sootblowing system will initiate sootblowings on individual tube banks only when needed for that specific tube bank. Such a system depends on the detection of the degree of fouling of specific tube banks. In this project, the conditions for an intelligent sootblowing system at the waste fired boilers in Boraas are investigated from measured flows, temperatures and pressure drop. New thermocouples at the water tubes between the banks of the economiser have been installed and connected to the control and monitoring system of the boiler. From measured temperatures and flows, heat transfer coefficients are calculated and used to detect the fouling on the heat exchangers. A pressure transducer has been altered to measure the pressure over the boiler bank. At the superheaters, the measurements show a significant improvement of the heat transfer coefficients immediately following sootblowing. Thereafter, the heat transfer coefficients decline more slowly, almost linearly. The measurements indicate that the fouling rate is almost same for the two superheaters and do not motivate individual sootblowing sequences of the two superheaters. The pressure drop over the boiler bank was found too insensitive a measure to be used as an indicator for an intelligent sootblowing system, at least in this specific boiler. In the economiser, the decline of calculated heat transfer coefficients showed a relative rate of fouling on individual tube banks. The results show that the fouling rate is significantly higher in the top tube banks, which comes first in the direction of the flue gas, compared to downstream banks. Experiments by sootblowing the top tube bank more frequently than the

  12. Development of an electrochemistry-based corrosion sensor to monitor corrosion of boiler tubes, pipes, and painted structures

    Science.gov (United States)

    Davis, Guy D.; Dacres, C. M.; Shook, M. B.

    1998-03-01

    An electrochemical impedance spectroscopy (EIS)-based in-situ corrosion sensor has been adapted and evaluated for use with steel heat exchanger tubes in boilers, coated buried steel pipes, and painted steel structures. An excellent correlation was obtained between the algorithm of the ratio of the breakpoint frequencies, as measured by the sensor, and corrosion rate for the boiler tubes. Use of this sensor and appropriate electronics would allow the corrosion of the boiler tubes to be monitored in real time and the inhibitor concentration automatically controlled to prevent excessive corrosion. The EIS sensor is also sensitive to the quality of coating of a buried steel pipe with and without the application of cathodic protection. Similar results were obtained from a sensor attached to the pipe and from a separate electrode driven into the soil. A hand-held version of the EIS in-situ sensor is suitable for inspecting painted metal structures, such as storage tanks and locks and dams, under ambient, service conditions. An excellent correlation was obtained between the sensor measurements, and the amount of corrosion on test panels immersed for up to 28 years.

  13. High-Temperature Corrosion of Protective Coatings for Boiler Tubes in Thermal Power Plants

    Institute of Scientific and Technical Information of China (English)

    XU Lianyong; JING Hongyang; HUO Lixing

    2005-01-01

    High-temperature corrosion is a serious problem for the water-wall tubes of boilers used in thermal power plants. Oxidation, sulfidation and molten salt corrosion are main corrosion ways.Thereinto, the most severe corrosion occurs in molten salt corrosion environment. Materials rich in oxides formers, such as chromium and aluminum, are needed to resist corrosion in high-temperature and corrosive environment, but processability of such bulk alloys is very limited. High velocity electric arc spraying (HVAS) technology is adopted to produce coatings with high corrosion resistance. By comparison, NiCr (Ni-45Cr-4Ti) is recommended as a promising alloy coating for the water-wall tubes, which can even resist molten salt corrosion attack. In the study of corrosion mechanism, the modern material analysis methods, such as scanning electron microscopy (SEM), X-ray diffractometry (XRD) and energy dispersive spectrometry (EDS), are used. It is found that the corrosion resistances of NiCr and FeCrAI coatings are much better than that of 20g steel, that the NiCr coatings have the best anti-corrosion properties, and that the NiCr coatings have slightly lower pores than FeCrAI coatings.It is testified that corrosion resistance of coatings is mainly determined by chromium content, and the microstructure of a coating is as important as the chemical composition of the material. In addition, the fracture mechanisms of coatings in the cycle of heating and cooling are put forward. The difference of the thermal physical properties between coatings and base metals results in the thermal stress inside the coatings. Consequently, the coatings spall from the base metal.

  14. Erosion in Steam General Tubes in Boiler and ID Fans in Coal Fired FBC Power Plant

    Directory of Open Access Journals (Sweden)

    Shaheen Aziz

    2012-01-01

    Full Text Available The FBC (Fluidized Bed Combustion is a technique used to make solid particles behave like fluid and grow very fast for the power generation using low grade coal. Due to its merits, first time this technology has been introduced in Pakistan by installing 3x50 MW power plants at Khanote. Fluidized beds have long been used for the combustion of low-quality, difficult fuels and have become a rapidly developing technology for the clean burning of coal. The FBC Power Plant at Khanote has been facing operational and technical problems, resulting frequently shut down of generation units, consequently facing heavy financial losses. This study reveals that due to the presence of high percentage of silica in the lime stone that are further distributed in the bottom ash, fly ash and re-injection material, the generation tubes in the boiler and wings/blades of ID (Induced Draft fans were eroded. In addition, filter bags were also ruptured; resulting frequent shut down of power plant units.

  15. Simulation of heat transfer in combustion chamber waterwall tubes of supercritical steam boilers

    Directory of Open Access Journals (Sweden)

    Grądziel Sławomir

    2016-06-01

    Full Text Available The paper presents the results of numerical computations performed for the furnace chamber waterwalls of a supercritical boiler with a steam output of 2400 × 103 kg/h. A model of distributed parameters is proposed for the waterwall operation simulation. It is based on the solution of equations describing the mass, momentum and energy conservation laws. The aim of the calculations was to determine the distribution of enthalpy, mass flow and fluid pressure in tubes. The balance equations can be brought to a form where on the left-hand side space derivatives, and on the right-hand side – time derivatives are obtained. The time derivatives on the right-hand side were replaced with backward difference quotients. This system of ordinary differential equations was solved using the Runge-Kutta method. The calculation also takes account of the variable thermal load of the chamber along its height. This thermal load distribution is known from the calculations of the heat exchange in the combustion chamber. The calculations were carried out with the zone method.

  16. The Boiler Tube Wall Thickness Quantitative Evaluation Fusing the Magnetic and Ultrasonic Technique

    Institute of Scientific and Technical Information of China (English)

    SONG Xiaochun; HUANG Songling; ZHAO Daxing

    2006-01-01

    Wall thickness is always a key index for boiler tube inspection in power plant, in order to improve the inspection efficiency and accuracy, a new method fusing the magnetic and ultrasonic technique was proposed. The magnetic technique was used to do full inspection and locate the flaws, and the ultrasonic was employed to implement further quantitative inspection accurately. After comparing the precision of the polynomial, exponential and logarithmic function, the polynomial model was selected to fit the relations between the wall thickness and the peak value of magnetic signals, and the data measured by ultrasonic thickness meter was used to calibrate the model parameters online, the defect depth can be sized quickly. The experimental results demonstrate that the model used in this system has better accuracy than the statistics relation model clearly, and it is also suitable for defect evaluation real-time. Moreover, it is unnecessary to have much more experimental data for the curve fitting technology, so it has better practicability than the other methods.

  17. Development of Square Coal Tube in Boiler%方型锅炉落煤筒的研制

    Institute of Scientific and Technical Information of China (English)

    高平; 王婵; 郭在在; 付利涛; 兰兰; 邸建辉; 闫志飞; 田迎春; 郭永亮

    2014-01-01

    Aimed at the reasons for the early deformation in service and cracking failure of the welding-manufactured square tubes in coal boiler,a lost foam casting process scheme for the square tubes in coal boiler was put forward,and some measures were adopted,such as designing a "well" shape deformation brace,increasing casting chamfering radius,adjusting chemical composition of the material,and so on.The production process for the square tubes in coal boiler were introduced,including lost foam casting process,melting and pouring process,model making and coating process,and model packing process.Practice proves that the service life of the cast square tubes is 1.6 times of welding tubes,which effectively improve the efficiency of transporting coal and the enterprise economic benefit.%针对焊接制造锅炉落煤筒服役早期出现变形和开裂失效的原因,提出了消失模铸造落煤筒的方案,并采取了设计“井”形防变形拉筋,加大铸件铸造倒角半径,调整优化材料的化学成分等措施.同时介绍了消失模铸造落煤筒的熔炼、浇注、模型制作、涂料涂刷和模型装箱等工艺.实践证明,研制的落煤筒使用寿命是焊接制造的1.6倍,有效地提高输煤效率和企业的经济效益.

  18. Analisa Efisiensi Water Tube Boiler Berbahan Bakar Fiber, Cangkang Sawit dan Kulit Kayu Menggunakan Metode Langsung

    OpenAIRE

    Gaol, Dosma Putra Lumban

    2016-01-01

    Some of the factors that affect the efficiency of the boiler is a superheater pressure, water feed temperature, steam temperature, the amount of steam produced, the amount of fuel consumption and calorific value fuel combustion. Steamtab chemicallogic use companion software to calculate the value of enthalpy. The aim of this study is to get relations variations in pressure superheater with boiler efficiency, the relationship of variation of temperature feed water to the boiler efficiency, the...

  19. Thermal design of horizontal tube boilers. Numerical and experimental investigation; Modelisation thermique de bouilleurs a tubes horizontaux. Etude numerique et validation experimentale

    Energy Technology Data Exchange (ETDEWEB)

    Roser, R.

    1999-11-26

    This work concerns the thermal design of kettle reboilers. Current methods are highly inaccurate, regarded to the correlations for external heat transfer coefficient at one tube scale, as well as to two-phase flow modelling at boiler scale. The aim of this work is to improve these thermal design methods. It contains an experimental investigation with typical operating conditions of such equipment: an hydrocarbon (n-pentane) with low mass flux. This investigation has lead to characterize the local flow pattern through void fraction measurements and, from this, to develop correlations for void fraction, pressure drop and heat transfer coefficient. The approach is original, since the developed correlations are based on the liquid velocity at minimum cross section area between tubes, as variable characterizing the hydrodynamic effects on pressure drop and heat transfer coefficient. These correlations are shown to give much better results than those suggested up to now in the literature, which are empirical transpositions from methods developed for inside tube flows. Furthermore, the numerical code MC3D has been applied using the correlations developed in this work, leading to a modeling of the two-phase flow in the boiler, which is a significant progress compared to current simplified methods. (author)

  20. Development of tubes and pipe for ultra-supercritical power plant boilers. Chocho rinkaiatsu boira yo kokan no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Naoi, H.; Mimura, H.; Ogami, M.; Sakakibara, M.; Araki, S.; Sogo, Y.; Ogawa, T.; Sakurai, H. (Nippon Steel Corp., Tokyo (Japan)); Fujita, T. (Tokyo Univ. (Japan))

    1992-11-30

    For aiming to improve the power plant efficiency for a purpose of the energy saving, in recent years, the steam condition of the boilers has become to be supercritical in a degree of the high temperature 566[degree]C[times] high pressure 246 atm. For protecting the global environment, the extensive researches for the further improvement of power plant efficiency are under way in many countries, and the immediate targets of the steam condition for boilers are 316 atm [times]593[degree]C while the final targets are ultra-supercritical as 352 atm [times]649[degree]C. In order to realize the plant which can withstand these conditions, the Nippon Steel Corp. has been conducting a development of the materials which can withstand the high temperature and pressure. Those are the ferritic steel 9Cr-0.5Mo-1.8W-Nb-V (NF616) and the austenitic steel 20Cr-25Ni-1.5Mo-Nb-Ti-N (NF709). The creep rupture strength of the former steel at 600[degree]C is equal to or higher than that of existing 18-8 austenitic stainless steel, while the creep rupture strength of the latter steel at 700[degree]C[times] 100,000 hours is 88MPa or above. The development of these 2 kinds of tubes and pipes for the ultra-supercritical boilers is described. 7 refs., 14 figs., 3 tabs.

  1. Numerical Investigation of Simultaneously Deposition and Re-Entrainment Fouling Processes in Corrugated Tubes by Coupling CFD and DEM

    DEFF Research Database (Denmark)

    Hærvig, Jakob; Condra, Thomas Joseph; Sørensen, Kim

    The deposition of particulate fouling on flue gas heat exchanger surfaces results in decreased heat transfer. Even though an increasingly amount of work is done on the design of clean heat exchanger surfaces, the effect of fouling remains a challenge. As some heat exchanger designs are more prone...... Computational Fluid Dynamics (CFD) software OpenFOAM is coupled to the Discrete Element Method (DEM) software LIGGGHTS using the coupling software CFDEM. A four-way coupling is used to model fluid-particle and particle-particle interactions and thereby allowing for a particle fouling layer to build up along...

  2. Determining the parameters at which burnout occurs in the waterwall tubes of drum boilers

    Energy Technology Data Exchange (ETDEWEB)

    I.I. Belyakov [Central Boiler-Turbine Institute Research and Production Association (OAO TsKTI), St. Petersburg (Russian Federation)

    2007-09-15

    Parameters at which burnout occurs are presented that were obtained by measuring the temperature and heat fluxes during experiments carried out directly on a boiler. The results of a comparison between the obtained values and the data of investigations on a test facility are given.

  3. 糖厂锅炉爆管原因分析及对策%Analysis and countermeasures of sugar refinery boiler tube blasting

    Institute of Scientific and Technical Information of China (English)

    孔树学

    2012-01-01

    The sugar refinery boiler two successive water-wall tubes pipe explosion, through the pipe explosion running record check, after a broken tube boiler internal, blasting the shape of the mouth, blasting as pipe diameter changes, organize and performance of blasting mouth changes and tube wall and scaling inspection analysis, etc. Short-term overheat blowout of tube, its reason is run sugar.%某糖厂锅炉连续两次水冷壁管爆管,通过对爆管前的运行记录检查、爆管后锅炉内部、爆破口的形貌、爆破管的管径变化、爆破口的组织和性能变化及管内壁结垢等检验分析,属短期过热爆管,其原因是“跑糖”。

  4. Analysis of High-temperature Boiler Tube Failure for T91 &T22

    Institute of Scientific and Technical Information of China (English)

    SHU Guo-gang; DING Hui; ZHAO Yan-fen; XUE Fei; ZHAO Ling-song; ZHANG Lu; LIU Jiang-nan; WANG Zheng-pin

    2004-01-01

    The tube failures took place frequently in the superheater of 2x600MW units in a power plant. According to the condition of tube failures, the mechanical property and microstructure on running and failed tubes were tested and evaluated. The chemical composition and structure phase of inner oxide scale and deposit inside of the tubes were examined.The fractured surfaces of failed tube samples were observed. And the material examination was performed for original tube steels SA213-T91 and SA213-T22. The results show that raw materials of SA213-T91 and SA213-T22 tube in superheater are qualified. Besides, the characteristics of the SA213-T91 and SA213-T22 tube failure are typical short-term overheated rupture. The rupture temperature is located between two phase Ac1 ~ Ac3 of the two steels. It is recognized that putting SA213-T22 tubes in operation under the condition of long-term over heating causes the rupture of SA213-T91 and SA213-T22.

  5. Design and implementation of a control system to improve the quality of the combustion gases in the fire-tube boiler of 5 BHP

    Directory of Open Access Journals (Sweden)

    Carlos Alfredo Pérez Albán

    2016-06-01

    Full Text Available The goal of this paper is the design and implementation of a system for controlling the quality of the combustion gases in a fire-tube boiler of 5 BHP. Based on the percentage of O2 present in the combustion gases, measured by a lambda sensor, the percentage of CO2 emitted into the atmosphere is determined. PID proportional control is responsible for the automatic regulation of the entry of air to the boiler by an actuator, according to the percentage of the oxygen concentration in the combustion gases. The control system has an HMI display and a modular PLC. The results achieved ensure pollutant gases emissions within the parameters established by current environmental standards, achieving the required quality of combustion gases and reducing the fuel consumption of the boiler.

  6. Deposit-related failures of boiler superheater tubing and steam piping

    Energy Technology Data Exchange (ETDEWEB)

    Kotwica, D.J. [Betz Labs. Inc., The Woodlands, TX (United States)

    1995-12-01

    Deposition in superheater tubing can originate from the carryover of water droplets into the superheater bank from the steam drum. Deposition occurs because the concentration of impurities present in the entrained water droplets can be several orders of magnitude greater than that present in steam alone. When the water flashes to steam in the superheater, salts, hardness species, and corrosion products dissolved or suspended in the water build-up on the internal surfaces of the superheater tubing. The detrimental effects of carryover deposition in superheater tubing has been shown to contribute to at least three types of failure: stress-corrosion cracking, overheating, and corrosion gouging. A case history illustrating each one of these failure mechanisms is presented.

  7. Experimental and numerical investigation of gas side particulate fouling onto heat exchanger tubes; Etude des differents mecanismes de depot conduisant a l'encrassement particulaire en phase gazeuse des tubes d'echangeurs de chaleur

    Energy Technology Data Exchange (ETDEWEB)

    Bailer, F.

    1998-11-06

    This works deals with gas side particulate fouling onto heat exchanger tubes. An experimental and numerical investigation was carried out. By means of a new testing loop designed for this study the deposit kinetics were obtained in dust-controlled conditions at the beginning of the fouling process, Experimental results pointed out the existence of various transport regimes: for sub-micron particles, convective diffusion augmented by thermophoresis in the presence of a temperature gradient governs the particle deposition: inertial impaction controls the super-micron particles deposition, in the intermediate granulometric range, combined action of particle inertia and thermophoresis must be considered. Moreover, measurements on an other testing loop using a more concentrated aerosol allowed us to point out the modification of the mechanisms with time and the influence of the deposit shape. A numerical model predicting the particle deposition, based on the TRIO software and an Eulerian-Lagrangian approach, was developed and validated against experimental results from the literature and from our study. Numerical approach gave us an accurate understanding of the phenomena by means of local parameters computations. In this way, the different mechanisms which control particulate deposition onto heat exchangers tubes were identified and modeled, especially before the onset of the inertial impaction. (authors)

  8. Design Model for the Heat Transfer in a Short Straight Tube Boiler.

    Science.gov (United States)

    1981-06-01

    in vertical upflow for Re򒾐. Water properties are evaluated at the film tempera- ture; Prw, at the wall temperature. The work done by Sieder and...Boiling and Condensation, McGraw-Hill Book Co., New York, 1972. 16. Sieder , E.N., and Tate, C.E., Heat Transfer and Pressure Drop of Liquids in Tubes, Inc

  9. 交叉缩放椭圆管CaCO3污垢特性的实验研究%Experimental Investigation on the CaCO3 Fouling Characteristics of the Alternating Elliptical Axis Tube

    Institute of Scientific and Technical Information of China (English)

    张仲彬; 李兴灿; 郭进生; 徐志明

    2011-01-01

    The characteristics of heat transfer and CaCO3 fouling were studied by the method of comparative experiments for the alternating elliptical axis tube and the copper tube in this paper, the flow field and wall shear stress in the alternating elliptical axis tube were numerically simulated and analyzed. The results show that the alternating elliptical axis tube has better heat transfer performance and anti-fouling ability than its corresponding copper tube, the periodic change of flow field and wall shear stress in the alternating elliptical axis tube may be the primary reason. In addition, the alternating elliptical axis tube has greater asymptotic value of fouling resistance at low speed. While the flow velocity increased to a certain value, there is not obvious effect on the asymptotic value of fouling resistance.%采用对比实验的方法对交叉缩放椭圆管与铜光管的传热和CaCO3污垢特性进行了研究,并用数值方法模拟了交叉缩放椭圆管的内部流场和壁面剪切力。实验结果表明:交叉缩放椭圆管的换热和抗垢性能均优于在对应状态下的铜光管,这主要是由于交叉缩放椭圆管的内部流场和壁面剪切力的周期性变化所引起的。交叉缩放椭圆管在低流速时污垢热阻渐近值较大,当流速增大到一定程度后,再提高流速对污垢热阻渐近值的影响不明显。

  10. Combustion monitoring of a water tube boiler using a discriminant radial basis network.

    Science.gov (United States)

    Sujatha, K; Pappa, N

    2011-01-01

    This research work includes a combination of Fisher's linear discriminant (FLD) analysis and a radial basis network (RBN) for monitoring the combustion conditions for a coal fired boiler so as to allow control of the air/fuel ratio. For this, two-dimensional flame images are required, which were captured with a CCD camera; the features of the images-average intensity, area, brightness and orientation etc of the flame-are extracted after preprocessing the images. The FLD is applied to reduce the n-dimensional feature size to a two-dimensional feature size for faster learning of the RBN. Also, three classes of images corresponding to different burning conditions of the flames have been extracted from continuous video processing. In this, the corresponding temperatures, and the carbon monoxide (CO) emissions and those of other flue gases have been obtained through measurement. Further, the training and testing of Fisher's linear discriminant radial basis network (FLDRBN), with the data collected, have been carried out and the performance of the algorithms is presented.

  11. Evaluation of Thermocyclic Oxidation Behavior of HVOF-Sprayed NiCrFeSiB Coatings on Boiler Tube Steels

    Science.gov (United States)

    Ramesh, M. R.; Prakash, S.; Nath, S. K.; Sapra, Pawan Kumar; Krishnamurthy, N.

    2011-09-01

    High velocity oxy-fuel (HVOF) spray process has grown into a well-accepted industrial technology for obtaining coatings resistant to significant surface degradation processes. In the present study, HVOF process was used to deposit Ni-based hardfacing NiCrFeSiB alloy powder on kinds of boiler tube steels designated as SA210 grade-A1, SA213-T11, and SA213-T22. The microstructures and several properties of the as-sprayed coatings have been investigated. Thermocyclic oxidation studies were performed in static air at 900 °C. NiCrFeSiB-coated steels showed slow oxidation kinetics and considerably lower weight gains than that of uncoated steels. The superior performance of NiCrFeSiB coatings can be attributed to continuous and protective thin oxide scale of amorphous SiO2 and Cr2O3 formed on the surface of the oxidized coatings. The combined technique of x-ray diffraction, scanning electron microscopy, energy dispersive x-ray analysis, and electron probe microanalysis are used to characterize reaction products of the oxidized surfaces.

  12. Hot Corrosion Studies of HVOF-Sprayed Coating on T-91 Boiler Tube Steel at Different Operating Temperatures

    Science.gov (United States)

    Bhatia, Rakesh; Singh, Hazoor; Sidhu, Buta Singh

    2013-11-01

    The aim of the present work is to investigate the usefulness of high velocity oxy fuel-sprayed 75% Cr3C2-25% (Ni-20Cr) coating to control hot corrosion of T-91 boiler tube steel at different operating temperatures viz 550, 700, and 850 °C. The deposited coatings on the substrates exhibit nearly uniform, adherent and dense microstructure with porosity less than 2%. Thermogravimetry technique is used to study the high temperature hot corrosion behavior of uncoated and coated samples. The corrosion products of the coating on the substrate are analyzed by using XRD, SEM, and FE-SEM/EDAX to reveal their microstructural and compositional features for the corrosion mechanisms. It is found that the coated specimens have shown minimum weight gain at all the operating temperatures when compared with uncoated T-91 samples. Hence, coating is effective in decreasing the corrosion rate in the given molten salt environment. Oxides and spinels of nickel-chromium may be the reason for successful resistance against hot corrosion.

  13. Experimental Investigation on Fouling Characteristics of the Discrete Double Inclined Ribs Tube%不连续双斜向内肋管污垢特性实验研究

    Institute of Scientific and Technical Information of China (English)

    徐志明; 李兴灿; 王宇朋; 李晓丽; 李煜; 张仲彬

    2012-01-01

    Using the Songhua River water as the cooling water, the characteristics of heat transfer and the fouling of the discrete double inclined ribs tube and the plain tube were studied by the method of comparative experiments, the flow field and wall shear stress in the discrete double inclined ribs tube were numerically simulated and analyzed. The results show that with the increase of flow velocity, the discrete double inclined ribs tube Nusselt trend of growth begin slowing down. Discrete double-inclined ribs tube have fouling induction period in the three flow rates, the higher flow rate, the induction period will be longer, double inclined ribs could extend the fouling time. When the flow rate increases to 0.5 m/s, improving velocity has not obvious effect on the asymptotic value of fouling resistance, and it is related to the heat transfer characteristics of the discrete double inclined ribs tube. The discrete double inclined ribs tube has better heat transfer performance and anti-fouling ability than that of plain tube, the periodic change of flow field and wall shear stress in the discrete double inclined ribs tube may be the primary reason.%以松花江水为工质,采用对比的实验方法对不连续双斜向内肋管与光管的传热和污垢特性进行研究,并用数值方法模拟不连续双斜向内肋管内流场和壁面剪切力.结果表明:随着流速的增加,不连续双斜向内肋管Nu数的增长趋势开始变缓;不连续双斜向内肋管在3种流速下都出现结垢诱导期,流速高时诱导期会相对更长,说明其内肋对管型结构会延长结垢时间;管内流速约达到0.5m/s后,提高流速对污垢热阻的影响已不明显,且与不连续双斜向内肋管传热特性的变化趋势相关;由于不连续双斜向内肋管的内部流场和剪切力的周期性变化,不连续双斜向内肋管的换热和抗垢性能均优于光管.

  14. Causes and Characteristics for Frequent Tube Blasting of Utility Boiler%电站锅炉热管常见泄漏原因及主要特征

    Institute of Scientific and Technical Information of China (English)

    沈美华; 祝新伟; 潘金平; 程宏辉; 徐卫东

    2013-01-01

    电站锅炉受热面管内外广泛接触烟、火、灰、水、汽、垢等介质,其工作环境恶劣且复杂,经常会因为各种原因而导致爆管泄漏失效的发生,给企业带来巨大的经济损失.详细介绍了磨损、长期过热、短期过热、氢损伤、腐蚀疲劳、氧腐蚀、应力腐蚀、碱性腐蚀以及酸腐蚀9种常见的电站锅炉受热面管的泄漏失效原因及其主要特征,对迅速确定锅炉爆管原因以及提出解决措施,规范锅炉系统的操作等具有重要指导意义.%Heating surface tubes of utility boiler widely contact the media of smoke,fire,ash,water,steam,scale and etc.The tubes,which have wicked and complex working conditions,often blast and result in leakage failure because of many reasons.These bring huge economic losses to the enterprises.Nine kinds of tube blasting reasons and their main representation characters were detailedly introduced.These tube blasting reasons include abrasive erosion,long-term overheating,short term overheating,hydrogen damage,corrosion fatigue,oxygen corrosion,stress corrosion,caustic corrosion and acid corrosion.It has important guiding significance to rapidly ascertain the causes and ultimately resolve the tube blasting problems of the utility boiler and to normalize boiler system operation.

  15. Characteristics of the Initial Stage of CaCO3 Crystallization Fouling on Two Kinds of Oblique Fin Tube%两种斜翅管表面碳酸钙垢初始阶段结垢特性

    Institute of Scientific and Technical Information of China (English)

    盛健; 张华; 赵萍

    2014-01-01

    To investigate the effect of CaCO3 concentration and velocity on CaCO3 scaling fouling process on plain,straight oblique and saw-tooth oblique fin tubes,experiments were done at different CaCO3 concentration,velocity and surface parameter of the three kinds of tubes.The results show that the homogeneous nucleation rate and the growing rate both increase when CaCO3 concentration increases.This makes the scaling particle concentration and fouling ion concentration increase,the former leads to more scaling on tubes and the later enlarges the heterogeneous nucleation rate and growing rate.Higher velocity decreases the nucleation of scaling,scaling crystal and fouling resistance,but it can prolong the induction period.Higher velocity increases nucleation rates on straight oblique fin tube and saw-tooth oblique fin tube,but the induction period extends and the mass of scaling and fouling resistance decrease.Straight oblique fin tube and saw-tooth oblique fin tube have bigger heat transfer coefficient than plain tube under both clean and fouling conditions in despite of smaller fouling resistance and a little more scaling.Under the same condition,saw-tooth oblique fin tubes have bigger heat transfer coefficient and fouling mass than straight oblique fin tubes,but the total heat transfer coefficient is bigger than that of straight oblique fin tubes.%进行了3种强化管在不同碳酸钙溶液浓度和流速下的动态结垢实验,得到碳酸钙浓度、流速和不同管型对碳酸钙析晶垢结垢过程的影响。结果表明,碳酸钙浓度增大,使溶液中均相成核速率和所形成晶核的生长速率增大,使溶液换热表面界面的污垢晶粒浓度和成垢离子浓度均增大,前者使更多的污垢附着换热面,而后者使表面异相成核速率和生长速率增大。流速增大,使光管表面形成的晶核、污垢晶体和污垢热阻均减少,而诱导期延长;使平直和锯齿斜翅管初始成核增多,但诱

  16. Based on the acoustic emission technology Boiler "Four Tubes" leakage detection system%基于声发射技术的锅炉“四管”泄漏检测系统

    Institute of Scientific and Technical Information of China (English)

    张里阳

    2014-01-01

    针对电厂中锅炉“四管”泄漏时产生的广义声发射现象,对空间声场分布和声发射信号进行了分析研究。通过采集这种声发射信号并分析处理,建立了检测锅炉“四管”泄漏的检测系统,即锅炉炉管泄漏自动报警系统,给出了检测系统的软、硬件设计。该系统能够实现对锅炉炉管泄漏的早期测报,并判断出泄露的区域位置及泄漏程度,防止事故扩大,减少经济损失。%According to the power plant boiler "four tube" leakage in the generalized acoustic emission phenomenon, On the space sound field distribution and acoustic emission signal is studied. Through collecting and analyze the acoustic emission signal processing, detection is established boiler "four tube" leakage detection system, The boiler furnace tube leakage automatic alarm system, Detection system hardware and software design are also given in this paper. The system can realize early telemetry of boiler tube leakage, can realize early telemetry of boiler tube leakage, to prevent accidents, reduce economic loss.

  17. Ultrasonic water level determination of the high-pressure boilers tubes; Determinacao do nivel d'agua em tubos verticais de caldeiras aquatubulares por ultra-som

    Energy Technology Data Exchange (ETDEWEB)

    Goettems, Felipe Samuel; Reolon, Amon Marques; Avancini, Flavio; Braga, Rubem Manoel de; Reguly, Afonso [Universidade Federal do Rio Grande do Sul (UFRGS), Porto Alegre, RS (Brazil). Lab. de Metalurgia Fisica], e-mail: fgoettems@demet.ufrgs.br

    2006-07-01

    Electric power is very important to our society and thermoelectric power plant. They are especially important mainly in the summer when there is a scarcity in water supply to hydroelectric power plants. Southern Brazilian thermoelectric power plants employ high-pressure boilers in order to generate water vapor which, in turn, moves turbines to produce electricity. These high-pressure boilers must work in a continuous way to avoid damages caused by emergency halts. To accomplish this, some actions must be taken. The water height inside of the tubes must be kept in a strict level to avoid thermal gradient in both water walls and super-heater header. In this water walls the water become in vapor. The best way to regulate the valves that command the water level is through the control of the water height and this is the main purpose of this work. The ultrasound is a nondestructive test which is able in doing this control without damaging the tube. This method allows determining the water level, improving the system performance and reducing the maintenance costs caused by tube collapse. (author)

  18. Analysis and Prevention of the Crack on the Smoke Tube End and Tube Sheet in the Gas Boiler%燃气锅炉烟管管端和管板裂纹分析及防止

    Institute of Scientific and Technical Information of China (English)

    王明强; 吴金星; 王超; 刘艳会

    2016-01-01

    The smoke tube end and tube plate often generate cracks during the long-term operating of gas boiler, the main reason of which is big thermal loading, serious scaling of tube plate, caustic embrittlement, etc. Aimed at the causes of various cracks, and combining with engineering cases, this paper expounds the prevention measures, such as adding insulation layer to gas side of tube plate, strengthening water cycle, improving manufacturing process and strengthening water quality management, to make the working conditions of smoke tube end and tube plate highly improved so as to prevent the occurrence of cracks and ensure the operating of boiler safely and efifciently.%燃气锅炉在长期运行中烟管管端及管板常常产生裂纹,其主要原因是热负荷较大、管板结垢严重、苛性脆化等。本文针对各种裂纹产生的原因并结合工程案例,阐述了管板烟气侧加设隔热层、加强水循环、改善制造工艺、加强水质管理等防止措施,使烟管管端及管板工作条件得到很大改善,以防止裂纹的发生,保证锅炉安全、高效地运行。

  19. 方形螺旋管中CaSO4污垢特性的数值模拟%Numerical Simulation of CaSO4 Crystallization Fouling Characteristics in Square Spiral Tube

    Institute of Scientific and Technical Information of China (English)

    张艾萍; 丁权; 夏荣涛; 杨钊; 何莹; 张媛媛; 韩扬

    2016-01-01

    Starting with the heat and mass transfer, the mathematical model for forming process of CaSO4 crys-tallization fouling within square spiral tubes was built to analyze influences of CaSO4 concentration, pitch of helical pipe and inlet velocity on the fouling deposit rate, denudation rate and the fouling resistance in spiral tubes. Basing on temperature field, velocity field and CaSO4 concentration field and the fouling model simula-ted, the CaSO4 scale deposition rate, erosion rate, net deposition rate and fouling resistance’ s variation with time were calculated. Analysis results show that, rise of CaSO4 concentration can increase fouling’ s mass dep-osition rate and denudation rate and resistance;the bigger pitch of square spiral tube can reduce tube fouling’ s mass deposition rate and denudation rate and resistance;and increase of inlet velocity can decrease fouling’ s mass rate and resistance in the tube. Analyzing the variation trend of dirt’ s net deposition rate in spiral tubes with different pitches indicates that in a certain stage, the fouling rate in the tube is negative, and that is to say the square spiral tube has a certain anti-scale effect in a certain time. Smaller CaSO4 concentration and bigger pitch of the square screw tube as well as higher inlet velocity can bring about better scale inhibition effect.%从传热传质的角度建立了方形螺旋管内CaSO4析晶污垢形成过程的数学模型,通过对数学模型进行数值模拟计算,得到了CaSO4浓度、螺距及入口速度等参数对管内污垢的沉积率、剥蚀率、净沉积率和污垢热阻的影响。根据模拟得到的方形螺旋管管内的温度场、速度场和CaSO4浓度场,进而结合污垢模型,计算出CaSO4污垢的沉积率、剥蚀率、净沉积率和污垢热阻随时间的变化规律。通过分析计算数值模拟结果,得到CaSO4浓度的增加会增加污垢的质量沉积率和剥蚀率,同时也会增加污垢热阻;方

  20. Failure Analysis of 600 MW Supercritical Boiler Water Wall

    OpenAIRE

    Fu Huilin; Cai Zhengchun; Yan Xiaozhong; He Jinqiao; Zhou Yucai

    2013-01-01

    Boiler tube often causes abnormal boiler outage, bringing greater economic losses. This thesis mainly comes from the dynamics of boiler water, boiler furnace accident location of wall temperature distribution to explore the cause of the accident boiler. Calculation results show that the deformation will seriously reduce the boiler allowable maximum temperature difference between the screens. And the boiler is not over-temperature, low temperature difference between the screens, which have bur...

  1. MODELLING, SIMULATING AND OPTIMIZING BOILERS

    DEFF Research Database (Denmark)

    Sørensen, K.; Condra, T.; Houbak, Niels

    2003-01-01

    This paper describes the modelling, simulating and optimizing including experimental verification as being carried out as part of a Ph.D. project being written resp. supervised by the authors. The work covers dynamic performance of both water-tube boilers and fire tube boilers. A detailed dynamic...... model of the boiler has been developed and simulations carried out by means of the Matlab integration routines. The model is prepared as a dynamic model consisting of both ordinary differential equations and algebraic equations, together formulated as a Differential-Algebraic-Equation system. Being able...... to operate a boiler plant dynamically means that the boiler designs must be able to absorb any fluctuations in water level and temperature gradients resulting from the pressure change in the boiler. On the one hand a large water-/steam space may be required, i.e. to build the boiler as big as possible. Due...

  2. Modelling, simulating and optimizing Boilers

    DEFF Research Database (Denmark)

    Sørensen, Kim; Condra, Thomas Joseph; Houbak, Niels

    2003-01-01

    This paper describes the modelling, simulating and optimizing including experimental verication as being carried out as part of a Ph.D. project being written resp. supervised by the authors. The work covers dynamic performance of both water-tube boilers and re tube boilers. A detailed dynamic model...... of the boiler has been developed and simulations carried out by means of the Matlab integration routines. The model is prepared as a dynamic model consisting of both ordinary differential equations and algebraic equations, together formulated as a Differential-Algebraic- Equation system. Being able to operate...... a boiler plant dynamically means that the boiler designs must be able to absorb any uctuations in water level and temperature gradients resulting from the pressure change in the boiler. On the one hand a large water-/steam space may be required, i.e. to build the boiler as big as possible. Due...

  3. High-temperature organic-fluid fouling unit

    Energy Technology Data Exchange (ETDEWEB)

    Kuru, W.C.; Panchal, C.B.

    1997-06-01

    A new type of fouling unit is developed for high-temperature (500 C) and high-pressure (70 atmosphere) fouling experiments by modifying a commercial autoclave. Key modifications are the installation of a helical impeller in a flow tube and a fouling probe in the autoclave to simulate the fluid dynamics and heat transfer of typical heat-exchange equipment. A calibration technique is described, and fouling results are presented for experimental runs with indene and kerosene. The results are compared with those obtained using other types of fouling test units. Other potential applications of the fouling unit, such as corrosion and micro-scale reaction experiments, are discussed.

  4. A CFD study on the dust behaviour in a metallurgical waste-heat boiler

    Energy Technology Data Exchange (ETDEWEB)

    Yang Yongxiang; Jokilaakso, A. [Helsinki Univ. of Technology, Otaniemi (Finland). Lab. of Materials Processing and Powder Metallurgy

    1997-12-31

    A waste-heat boiler forms an essential part for the treatment of high temperature flue-gases in most metallurgical processes. Flue-dust carried by the furnace off-gas has to be captured efficiently in the waste-heat boilers before entering the downstream gas purification equipment. Flue dust may accumulate and foul on the heat transfer surfaces such as tube-walls, narrow conjunctions between the boiler and the furnace uptake, and thus may cause smelter shutdown, and interrupt the production. A commercial CFD package is used as the major tool on modelling the dust flow and settling in the waste-heat boiler of an industrial copper flash smelter. In the presentation, dust settling behaviour is illustrated for a wide range of particle sizes, and dust capture efficiency in the radiation section of the boiler for different particle sizes has been shown with the transient simulation. The simulation aims at providing detailed information of dust behaviour in the waste-heat boiler in sulphide smelting. (author) 11 refs.

  5. ECUT energy data reference series: boilers

    Energy Technology Data Exchange (ETDEWEB)

    Chockie, A.D.; Johnson, D.R.

    1984-09-01

    Information on the population and fuel consumption of water-tube, fire-tube and cast iron boilers is summarized. The use of each boiler type in the industrial and commercial sector is examined. Specific information on each boiler type includes (for both 1980 and 2000) the average efficiency of the boiler, the capital stock, the amount of fuel consumed, and the activity level as measured by operational load factor.

  6. Cause analysis of leakage by tube failure of power station boiler%电站锅炉管件失效泄漏原因分析

    Institute of Scientific and Technical Information of China (English)

    岳忠; 张月山

    2012-01-01

    Tube burst accident of heating surface tubes in a thermal power plant takes place frequently, which seriously affects the safety and economic operation of thermal power plant. In this paper the tube failure leakage accidents of economizer and low temperature reheater in a power plant were analyzed. Three kinds of methods were applied, including macroscopic analysis, metallographic analysis and strength analysis. It showed that overheating was not the cause of this tube burst. Oxygen corrosion and defects of low reheater leaded tube leakage. Then leaking fluid from low temperature reheater tube caused fluid scour and cavitations erosion on the rear wall economizer. Fluid scour and cavitations erosion leaded leakage of the rear wall economizer. The fluid from the rear wall economizer tube caused fluid scour and cavitations erosion on the low reheater which strengthened leakage of low reheater. At last the treatment measure and proposals of preventing similar accident were put forward. The failure tube should be replaced. The examination and test of metal tube should be paid attention to during boiler maintenance. Metal tube which is easy to be scoured should be put on protection covering or coating to prevent from fluid scouring.%火力发电厂管件失效泄漏是频发事故,严重影响机组的安全、经济运行.以某发电厂后墙省煤器和低温再热器管子失效泄漏事故为例,通过对失效泄漏的管件进行宏观形貌分析、金相分析和强度分析,论证了泄漏事故的原因是由于腐蚀和钢管固有缺陷导致低温再热器高温段弯管外侧发生泄漏,泄漏的高速流体冲刷、气蚀导致后隔墙省煤器发生泄漏,进而对低温再热器反冲刷,加剧泄漏事故的恶化.最后提出更换失效管件,加强金属监督,尽量扩大防磨防爆检查范围,对易被气流磨损、冲刷部位进行防磨喷涂或加装防磨罩.

  7. Studies on Hot Corrosion of the Microstructurally Different Regions of 2.25Cr-1Mo (T22) Boiler Tube Steel Weldment

    Science.gov (United States)

    Kumar, Ravindra; Tewari, V. K.; Prakash, Satya

    2009-10-01

    This study examines the effect of microstructurally different regions on the hot corrosion of tungsten inert gas weldment in 2.25Cr-1Mo (T22) boiler tube steel. Various regions of weldment were oxidized in molten salt Na2SO4-60% V2O5 environment at 900 °C. The base metal was found to oxidize at much higher rates than the weld metal and the heat-affected zone. Oxide scales formed in the three regions were compared by scanning electron microscopy with energy dispersive of X-ray analysis, X-ray diffraction pattern, and electron probe microanalysis. The research investigates the formation of inner scales with free Cr over the HAZ.

  8. Discussion and Analysis of the Causes of Accident of Steam Boiler Tube Rupture and the Processing Methods%蒸汽锅炉爆管事故原因及处理方法探讨分析

    Institute of Scientific and Technical Information of China (English)

    李伟忠; 安文广; 张丽波

    2012-01-01

    蒸汽锅炉在运行过程中,一旦发生爆管事故,会损坏邻近的管壁,冲塌炉墙,并且在很短的时间造成锅炉严重缺水,使事故扩大,因此须保证安全可靠,确保安全生产运行.本文主要探讨蒸汽锅炉运行中锅炉爆管事故原因及处理方法.%Once the accident of tube rupture for steam boiler during operation happened, it can damage the nearby tube wall, and collapse furnace wall, resulting in serious water shortages for boiler in a very short period of time, expanding the accident, therefore, we must ensure the safety and reliability, safe production and operation. This paper mainly discusses the causes and treatment methods of accident of boiler tube rupture in the operation of steam boiler.

  9. Degradation behavior of Ni3Al plasma-sprayed boiler tube steels in an energy generation system

    Science.gov (United States)

    Sidhu, Buta Singh; Prakash, S.

    2005-06-01

    Boiler steels, namely, low-C steel, ASTM-SA210-Grade A1 (GrA1), 1Cr-0.5Mo steel, ASTM-SA213-T-11 (T11) and 2.25Cr-1Mo steel, ASTM-SA213-T-22 (T22) were plasma sprayed with Ni3Al. The alloy powder was prepared by mixing Ni and Al in the stoichiometric ratio of 3 to 1. The Ni-22Cr-10Al-1Y alloy powder was used as a bond coat, with a 150 µm thick layer sprayed onto the surface before applying the 200 µm coating of Ni3Al. Exposure studies have been performed in the platen superheater zone of a coal-fired boiler at around 755 °C for 10 cycles, each of 100 h duration. The protection to the base steel was minimal for the three steels. Scale spallation and the formation of a porous and nonadherent NiO scale were probably the main reasons for the lack of protection. In the case of T22-coated steel, cracks in the coatings have been observed after the first 100 h exposure cycle.

  10. Degradation behavior of Ni{sub 3}Al plasma-sprayed boiler tube steels in an energy generation system

    Energy Technology Data Exchange (ETDEWEB)

    Sidhu, B.S.; Prakash, S. [GZS, Bathinda (India). College of Engineering

    2005-06-01

    Boiler steels, namely, low-C steel, ASTM-SA210-Grade A1 (GrA1), 1Cr-0.5Mo steel, ASTM-SA213-T-11 (T11) and 2.25Cr-1Mo steel, ASTM-SA213-T-22 (T22) were plasma sprayed with Ni3Al. The alloy powder was prepared by mixing Ni and Al in the stoichiometric ratio of 3 to 1. The Ni-22Cr-10Al-1Y alloy powder was used as a bond coat, with a 150{mu} m thick layer sprayed onto the surface before applying the 200{mu}m coating of Ni{sub 3}Al. Exposure studies have been performed in the platen superheater zone of a coal-fired boiler at around 755{sup o}C for 10 cycles, each of 100 h duration. The protection to the base steel was minimal for the three steels. Scale spallation and the formation of a porous and nonadherent NiO scale were probably the main reasons for the lack of protection. In the case of T22-coated steel, cracks in the coatings have been observed after the first 100 h exposure cycle.

  11. Desain Compact Heat Exchanger Tipe Fin And Tube Sebagai Alat Pendingin Motor Pada Boiler Feed Pump. Studi Kasus Pada Sebuah Perusahaan Pembangkit Tenaga Listrik

    Directory of Open Access Journals (Sweden)

    Luki Apriliasari

    2013-09-01

    Full Text Available Motor listrik penggerak boiler feed pump harus bekerja secara kontinyu, dan hanya boleh mati pada saat dilakukan maintenance, apabila tidak diberikan pendinginan maka akan terjadi overheating dan menyebabkan kerusakan pada motor. Hal ini sering terjadi di PLTU, motor listrik hanya didinginkan dengan dialiri udara bebas. System ini memiliki keterbatasan yaitu kotoran yang terkandung di udara bisa menempel di dinding motor, justru menyebabkan panas dalam motor tidak keluar dengan maksimal. Untuk mengatasi keterbatasan tersebut, maka diusulkan suatu metode pendinginan yaitu dengan mendesain heat exchanger tipe compact (fin and tube. Data – data operasi diambil dari suatu perusahaan pembangkit tenaga listrik yang dijadikan obyek study. Perhitungan desain heat exchanger dengan metode ∆TLMTD. Setelah mendapat dimensi yang sesuai dengan panas yang akan didinginkan, maka dilakukan analisa performansi yaitu nilai effectiveness terhadap perubahan beban. Hasil yang didapatkan dari penyelesaian study kasus ini adalah dimensi compact heat exchanger yang memiliki spesifikasi sesuai surface 7.75-5/8T dari Kays and London dengan panjang fin 1 meter, lebar fin 0,3 m, dan panjang tube 1 meter. Hasil analisa performansi (effectiveness terhadap variasi beban yaitu semakin tinggi pembebanan maka nilai effectiveness juga semakin tinggi.

  12. Structured Mathematical Modeling of Industrial Boiler

    OpenAIRE

    Abdullah Nur Aziz; Yul Yunazwin Nazaruddin; Parsaulian Siregar; Yazid Bindar

    2014-01-01

    As a major utility system in industry, boilers consume a large portion of the total energy and costs. Significant reduction of boiler cost operation can be gained through improvements in efficiency. In accomplishing such a goal, an adequate dynamic model that comprehensively reflects boiler characteristics is required. This paper outlines the idea of developing a mathematical model of a water-tube industrial boiler based on first principles guided by the bond graph method in its derivation. T...

  13. Further development of recovery boiler; Soodakattilan kehitystyoe

    Energy Technology Data Exchange (ETDEWEB)

    Janka, K.; Siiskonen, P.; Sundstroem, K. [Tampella Power Oy, Tampere (Finland)] [and others

    1996-12-01

    The global model of a recovery boiler was further developed. The aim is to be able to model the velocity, temperature and concentration fields in a boiler. At this moment the model includes submodels for: droplet drying, pyrolysis, char burning, gas burning and for droplet trajectory. The preliminary study of NO{sub x} and fly ash behaviour in a boiler was carried out. The study concerning flow field in the superheater area was carried out a 2-dimensional case in which the inflow parameters were taken from global model of a recovery boiler. Further the prediction methods of fouling in a recovery boiler were developed based on theoretical calculations of smelting behaviour of multicomponent mixtures and measurements at operating recovery boilers. (author)

  14. Cracking and corrosion recovery boiler

    Energy Technology Data Exchange (ETDEWEB)

    Suik, H. [Tallinn Technical University, Horizon Pulp and Paper, Tallinn (Estonia)

    1998-12-31

    The corrosion of heat surfaces and the cracking the drums are the main problems of the recovery boiler. These phenomena have been appeared during long-term operation of boiler `Mitsubishi - 315` erected at 1964. Depth of the crack is depending on the number of shutdowns and on operation time. Corrosion intensity of different heat surfaces is varying depend on the metal temperature and the conditions at place of positioning of tube. The lowest intensity of corrosion is on the bank tubes and the greatest is on the tubes of the second stage superheater and on the tubes at the openings of air ports. (orig.) 5 refs.

  15. 螺旋槽管降膜蒸发强化传热与结垢特性研究%Enhanced Heat Transfer and Fouling Performance of the Spirally Fluted Tube in Falling Film Evaporation

    Institute of Scientific and Technical Information of China (English)

    邢玉雷; 齐春华; 韩旭; 冯厚军; 吕庆春; 冯建民

    2013-01-01

    降膜蒸发是海水淡化的一项主要技术.传热管是降膜蒸发器的核心部件.螺旋槽管是一种应用广泛的高效强化传热管,但在海水淡化中应用较少,缺乏相关的实验数据.为论证螺旋槽管用于海水淡化的可行性,首先在水平管降膜蒸发传热实验平台上,以自来水为工质,研究了螺旋槽管的强化传热特性,分析了喷淋密度、热通量、传热温差和蒸发温度对其传热的影响;然后借助低温多效蒸馏(LT-MED)海水淡化中试装置,在海水淡化实际工况下,运行测试180 d,研究了螺旋槽管的结垢特性.在本实验中,螺旋槽管传热系数较光管平均提高35%左右;其结垢厚度小于光管,结垢疏松多孔,易于清除.%Falling film evaporation is one main technique of seawater desalination.Heat transfer tube is core component of falling film evaporator.Spirally fluted tube is one of the widely used enhanced heat transfer tubes with high efficiency.However,there are few practical applications of the spirally fluted tube to seawater desalination.In order to evaluate the feasibility of its application to desalination,the enhanced heat transfer performance of the aluminum brass spirally fluted tube was investigated firstly,relying on the horizontal tube falling film evaporation heat transfer platform with the tap water as medium.The effect of sprinkling density,heat flux,temperature difference and evaporating temperature on heat transfer of the tube was analyzed.Then,the fouling performance of the spirally fluted tube was researched by means of a pilot plant of low temperature multiple effect distillation (LT-MED) desalination which was running 180 days in the actual working conditions of desalination projects.The results show that heat transfer efficiency of spirally fluted tube is 35% higher than that of smooth tube,and the fouling on the spirally fluted tube is thinner,more porous and easier to remove than that on the smooth tube.

  16. Arc-Sprayed Iron-Based Coatings for Erosion-Corrosion Protection of Boiler Tubes at Elevated Temperatures

    Science.gov (United States)

    Pokhmurskii, Vasyl; Student, Mykhailo; Gvozdeckii, Volodymyr; Stypnutskyy, Taras; Student, Oleksandra; Wielage, Bernhard; Pokhmurska, Hanna

    2013-06-01

    Wire arc spraying is an economically attractive thermal spray process that is especially interesting for the protection of large-scale parts or constructions. This study presents the results of the development and investigation of a number of cored wires based on the Fe-Cr-Al system with minor addition of alloying elements (B, Mn, Ni, Si, Ti, Mg, etc.). The microstructure of the coatings, their electrochemical behavior, and isothermal oxidation performance over a temperature range of 20-700 °C were investigated. Erosion resistance at elevated temperatures was determined with a laboratory test unit under test conditions that have simulated the work conditions in fossil-fuel-fired boilers. It was established that the oxidation resistance and the gas-abrasive wear resistance of arc-sprayed coatings depend mostly on the coating microstructure and homogeneity of element distribution rather than on the general alloying level and microhardness of the coating. A new parameter for coating characterization, namely, the coefficient of chemical microheterogeneity, K CMH, is introduced to quantify this influence. Formation of the coating microstructure at elevated temperatures and its influence on the protection ability of the coating are discussed.

  17. High-Temperature Erosion of HVOF Sprayed Cr3C2-NiCr Coating and Mild Steel for Boiler Tubes

    Science.gov (United States)

    Yang, Guan-Jun; Li, Chang-Jiu; Zhang, Shi-Jun; Li, Cheng-Xin

    2008-12-01

    The comparison of the high-temperature erosion behavior of a High-velocity oxyfuel (HVOF) sprayed Cr3C2-NiCr coating with mild steel for circulating fluidized bed boiler tubes was investigated. Results showed that the erosion rate of the mild steel at 800 °C was four times that at 300 °C at an erosion angle of 30°. However, the erosion rate of the HVOF sprayed Cr3C2-NiCr coating was not influenced by the temperature in the range of 300-800 °C. It was found that the erosion resistance of HVOF sprayed Cr3C2-NiCr coating was more than three times higher than that of the mild steel at 700-800 °C. In addition to the ploughing on the coating surface, the cracking along splat interfaces in the coating was clearly observed on the cross-sectional microstructure. The results indicate that the erosion performance of the HVOF sprayed Cr3C2-NiCr coating is controlled by the cohesion between splats and can be further enhanced by improving splat cohesion.

  18. Long term properties and microstructural evolution of 18Cr-10Ni-3Cu-Ti-Nb austenitic stainless steel for boiler tube application

    Energy Technology Data Exchange (ETDEWEB)

    Minami, Y.; Fukui, T.; Ono, T. [TenarisNKK Tubes, Kawasaki, Kanagawa (Japan); Caminada, S. [TenarisDalmine, Dalmine, BG (Italy)

    2010-07-01

    The allowable tensile stress of 0.1C-18Cr-10Ni-3Cu-Ti-Nb steel (TEMPALOY AA-1; ASME C.C. 2512) is more than 30% higher compared with that of ASME SA-213 Grade TP347H in the temperature range 600-700 C. This high creep rupture strength is obtained by the precipitation of MC and M{sub 23}C{sub 6} carbides, and Cu-rich phase. Long term creep rupture tests over 10{sup 5}h enabled to verify the superior creep rupture strength of this steel. The investigation of microstructural evolution on the creep ruptured and aged specimens has shown the high structural stability of this material. Hardness and impact properties after high temperature aging reveal similar performance as conventional 18-8 stainless steels. Excellent steam oxidation resistance can be achieved by a shot-blasting method. The scale thickness of shot-blasted tube after 1000h at 750 C is below a few micron meters. These results have revealed that the mechanical properties and environmental resistance of this steel enable the use of TEMPALOY AA-1 in the latest generation of advanced USC boiler. (orig.)

  19. Superheater Corrosion In Biomass Boilers: Today's Science and Technology

    Energy Technology Data Exchange (ETDEWEB)

    Sharp, William (Sandy) [SharpConsultant

    2011-12-01

    the measured first melting point of fly ash deposits does not necessarily produce a step increase in corrosion rate. Corrosion rate typically accelerates at temperatures below the first melting temperature and mixed deposits may have a broad melting temperature range. Although the environment at a superheater tube surface is initially that of the ash deposits, this chemistry typically changes as the deposits mature. The corrosion rate is controlled by the environment and temperature at the tube surface, which can only be measured indirectly. Some results are counter-intuitive. Two boiler manufacturers and a consortium have developed models to predict fouling and corrosion in biomass boilers in order to specify tube materials for particular operating conditions. It would be very useful to compare the predictions of these models regarding corrosion rates and recommended alloys in the boiler environments where field tests will be performed in the current program. Manufacturers of biomass boilers have concluded that it is more cost-effective to restrict steam temperatures, to co-fire biofuels with high sulfur fuels and/or to use fuel additives rather than try to increase fuel efficiency by operating with superheater tube temperatures above melting temperature of fly ash deposits. Similar strategies have been developed for coal fired and waste-fired boilers. Additives are primarily used to replace alkali metal chloride deposits with higher melting temperature and less corrosive alkali metal sulfate or alkali aluminum silicate deposits. Design modifications that have been shown to control superheater corrosion include adding a radiant pass (empty chamber) between the furnace and the superheater, installing cool tubes immediately upstream of the superheater to trap high chloride deposits, designing superheater banks for quick replacement, using an external superheater that burns a less corrosive biomass fuel, moving circulating fluidized bed (CFB) superheaters from the

  20. 300MW级亚临界锅炉管爆裂原因及剩余寿命评估%Burst Reason Analysis of 300MW Subcritical Boiler Tube and Residual Life Evaluation

    Institute of Scientific and Technical Information of China (English)

    何石磊

    2016-01-01

    通过对过热器管道向火面和背火面的力学性能、 爆口处金相组织、 裂纹与组织的关系及氧化层的分析,得出了300MW过热器锅炉管爆裂失效的原因.结果表明,长期超温运行、 冲蚀、内壁氧化层脱落和局部短时过热综合作用导致过热器锅炉管爆裂发生.利用球化分析法和Larson-Miller参数主曲线外推法,估算了12Cr1MoV材质的过热器锅炉管金属当量温度和剩余寿命,表明锅炉管向火面金属当量温度明显高于背火面,剩余寿命远低于背火面.建议严格控制锅炉运行温度和压力,防止锅炉管局部长时间过热.%The burst failure reason of 300MW reheater boiler tube was obtained by analyzing some aspects, such as the mechanical properties of fire side and back to the fire side, the metallographic structure of burst point, the relationship between crack and structure, and oxide layer. The results indicated that the burst of reheater boiler tube was caused by combined action, including overtemperature operation for a long time, washout, oxide layer shedding from inner wall, and local short-time overheating. Utilizing spheroidization analysis and Larson-Miller parameter master curve to estimate the metal equivalent temperature and remaining life of reheater boiler tube made of 12Cr1MoV material, it showed that the metal equivalent temperature of boiler tube fire side is obvious higher than that of back to the fire side, and the residual life is far lower than back to the fire side. It is suggested the operation temperature and pressure should be strictly controlled to prevent the boiler tube from overheating.

  1. Structured Mathematical Modeling of Industrial Boiler

    Directory of Open Access Journals (Sweden)

    Abdullah Nur Aziz

    2014-04-01

    Full Text Available As a major utility system in industry, boilers consume a large portion of the total energy and costs. Significant reduction of boiler cost operation can be gained through improvements in efficiency. In accomplishing such a goal, an adequate dynamic model that comprehensively reflects boiler characteristics is required. This paper outlines the idea of developing a mathematical model of a water-tube industrial boiler based on first principles guided by the bond graph method in its derivation. The model describes the temperature dynamics of the boiler subsystems such as economizer, steam drum, desuperheater, and superheater. The mathematical model was examined using industrial boiler performance test data.It can be used to build a boiler simulator or help operators run a boiler effectively.

  2. 火电厂锅炉水冷壁管横向裂纹开裂原因分析%Failure Analysis on Water Wail Tube Transversal Crack of Power Plant Boiler

    Institute of Scientific and Technical Information of China (English)

    杨峰; 崔玮; 韩福全

    2011-01-01

    对电厂锅炉水冷壁管与鳍板焊接处开裂原因进行失效分析.结果表明:水冷壁管向火一侧表面氧化严重,管内侧存在结垢现象,同时水冷壁管珠光体发生球化,在运行过程中,在循环热应力和焊接残余应力叠加作用下,裂纹在焊缝接头处萌生,沿着拉应力区扩展,造成疲劳开裂.%The crack reason of the water wall tube in power plant boiler which attached to the welding with the fin tube wall was analyzed. The results show that superficial oxidation takes place on the appearance of water wall tube, typical scaling scale exists on the internal surface and partial pearlite is spheroidized. Cracks initiate in areas with attachment weld,leading to the explosion of the water wall tube in the boiler due to the cycle thermal stress and welding stress.

  3. 49 CFR 230.61 - Arch tubes, water bar tubes, circulators and thermic siphons.

    Science.gov (United States)

    2010-10-01

    ... (Continued) FEDERAL RAILROAD ADMINISTRATION, DEPARTMENT OF TRANSPORTATION STEAM LOCOMOTIVE INSPECTION AND MAINTENANCE STANDARDS Boilers and Appurtenances Washing Boilers § 230.61 Arch tubes, water bar tubes, circulators and thermic siphons. (a) Frequency of cleaning. Each time the boiler is washed, arch tubes...

  4. Corrosion Factors Analysis and Control Measures of Boiler Tubes in Steam In?jection Boiler in the Oilfield%油田热电厂注汽锅炉炉管腐蚀因素分析与控制措施

    Institute of Scientific and Technical Information of China (English)

    周登印

    2016-01-01

    大庆油田热电厂注汽锅炉炉管处于高温、高压的恶劣环境工况,腐蚀严重,其腐蚀类型主要为碱腐蚀、溶解氧腐蚀、气蚀、汽水腐蚀和停炉腐蚀.由介质产生的腐蚀因素主要有温度、流速及水处理质量;注汽锅炉炉管中存在的氧气以及锅炉水中溶解的氧加速了炉管腐蚀速率.为延缓腐蚀并减小腐蚀程度,提出以下对应的控制措施:严把水质源头管控,杜绝出现不达标水质进入锅炉;完善运行参数,防止超温、超压环境出现;将多种除氧方法结合使用,以达到最佳除氧效果.停炉后采用TH901法在炉管表面形成保护膜以隔离氧气,该保护法加药量少,成本低,阻止腐蚀的概率达到99.9%以上.通过控制锅炉给水水质,减少锅炉接触氧几率等措施,减缓了注汽锅炉炉管的腐蚀.%The steam injection boiler furnace tube of Daqing oilfield thermal power plant is in high temperature, high pressure and other harsh environmental conditions. The corrosion types are mainly alkali corrosion,dissolved oxygen corrosion,cavitation erosion,steam wa-ter corrosion and stop furnace corrosion. The corrosion factors produced by the medium mainly include temperature, flow rate and water treatment quality. The dissolved oxygen in the oxygen, and the boiler water in the steam injection boiler furnace, that have accelerated the corrosion rate of the furnace tubes. On the basis of corrosion factors targeted research, from the control of boiler feed water quality, reduce boiler oxygen exposure probability and improve the furnace pipe anti-corrosion properties of the essence, four aspects:the use of science and technology,and puts forward the corresponding control measures,aiming to de-lay and reduce the corrosion of all aspects, to prevent corrosion of the probability of more than 99.9%. By controlling the water quality of boiler and reducing the chance of contact with oxygen,the corrosion of boiler tubes is reduced.

  5. Detection Methods for Oxide Skin on Inner Heating Surface of Boiler Tubes%电站锅炉高温受热面管内壁氧化皮检测方法

    Institute of Scientific and Technical Information of China (English)

    郑小腾; 余焕伟; 董伟雄

    2016-01-01

    高温受热面管内壁氧化皮剥落堵管造成的爆管问题是影响电站锅炉正常安全运行的主要因素之一。本文在简要介绍铁素体耐热钢和奥氏体不锈钢两种不同材质高温受热面管内壁氧化皮生成原理、结构形式及剥落特性的基础上,重点介绍了高频超声和磁技术检测两种高温受热面管内壁氧化皮检测方法的检测原理、系统组成、适用范围及使用特点,以期为现场检验检测提供参考。%The metal oxidation of boiler tubes becomes one of the main factors which affect the safe operation of the utility boiler. To provide references for the on-site inspection, this paper briefly introduced the generation, structure and exfoliation of oxide skin on the inner heating surface of boiler tubes with ferrite heat resistant steel and austenitic stainless steel, and then mainly introduced two important detection methods of oxide skin : high frequency ultrasound and magnetic technology, including their detection principles, system compositions, application scopes as well as the usage characters.

  6. Green boilers; La chaudiere verte

    Energy Technology Data Exchange (ETDEWEB)

    Scrive, L.; Lebois, P.; Schlienger, M.; Moser, D. [Gaz de France (GDF), 75 - Paris (France)

    1997-12-31

    The ``green`` boiler was designed and developed by the Gaz de France and GEC Alsthom Stein Fasel partnership. It is a new make of steam boiler with smoke tubes from 4 to 15 MW. This range meets tow of the requirements guaranteed by the engineer: a NOx emission level lower than 100 mg/m{sup 3} (n) with 3% of oxygen and an combustion output of no less than 95 + 2% on n.v.c. A pilot operation was carried out by CNI Technologies in France. This 8.6 MW boiler was installed in June 1995 and performances checks were carried out by Apave Normandie in September 1995. This environmentally friendly boiler as well as the results obtained during the pilot operation are addressed in this article. (authors)

  7. Tube Plate Structure Coupling Analysis of Reformed Gas Waste Heat Boiler%转化气余热锅炉管板结构的温度耦合分析

    Institute of Scientific and Technical Information of China (English)

    赵梓童; 任建民

    2016-01-01

    转化气余热锅炉入口温度达到860℃,管壳程温差载荷较大,管板承受内压和温差载荷的双重作用,在管板管程侧、换热管管板部位和旁通管内部设计了防热材料,管板的管壳程的连接结构采用H型锻件,在温差载荷和管壳程设计压力相互作用的三种工况条件下,依据JB4732对设备相应部位进行应力评定,评定结果合格,为工程设计人员提供可参考的数据.%The inlet temperature of the reformed gas waste heat boiler reaches 860 ℃, the temperature difference load along the tube shell was large, the tube plate subjected to internal pressure and the temperature difference. Designed the thermal protection material at the tube pass side of tube plate, the heat exchange tube sheet parts, and inside the by-pass pipe. Connecting structure of the tube sheet shell used H-forging. For three working conditions under the designed temperature differences and tube shell pressures, the stress assessment of the corresponding parts of the device was done according to JB4732, evaluation the results were qualified, provide reference data for engineering design personnel.

  8. Life extension of boilers using weld overlay protection

    Energy Technology Data Exchange (ETDEWEB)

    Lai, G.; Hulsizer, P. [Welding Services Inc., Norcross, GA (United States); Brooks, R. [Welding Services Inc., Welding Services Europe, Spijkenisse (Netherlands)

    1998-12-31

    The presentation describes the status of modern weld overlay technology for refurbishment, upgrading and life extension of boilers. The approaches to life extension of boilers include field overlay application, shop-fabricated panels for replacement of the worn, corroded waterwall and shop-fabricated overlay tubing for replacement of individual tubes in superheaters, generating banks and other areas. The characteristics of weld overlay products are briefly described. Also discussed are successful applications of various corrosion-resistant overlays for life extension of boiler tubes in waste-to-energy boilers, coal-fired boilers and chemical recovery boilers. Types of corrosion and selection of weld overlay alloys in these systems are also discussed. (orig.) 14 refs.

  9. Computer system for monitoring power boiler operation

    Energy Technology Data Exchange (ETDEWEB)

    Taler, J.; Weglowski, B.; Zima, W.; Duda, P.; Gradziel, S.; Sobota, T.; Cebula, A.; Taler, D. [Cracow University of Technology, Krakow (Poland). Inst. for Process & Power Engineering

    2008-02-15

    The computer-based boiler performance monitoring system was developed to perform thermal-hydraulic computations of the boiler working parameters in an on-line mode. Measurements of temperatures, heat flux, pressures, mass flowrates, and gas analysis data were used to perform the heat transfer analysis in the evaporator, furnace, and convection pass. A new construction technique of heat flux tubes for determining heat flux absorbed by membrane water-walls is also presented. The current paper presents the results of heat flux measurement in coal-fired steam boilers. During changes of the boiler load, the necessary natural water circulation cannot be exceeded. A rapid increase of pressure may cause fading of the boiling process in water-wall tubes, whereas a rapid decrease of pressure leads to water boiling in all elements of the boiler's evaporator - water-wall tubes and downcomers. Both cases can cause flow stagnation in the water circulation leading to pipe cracking. Two flowmeters were assembled on central downcomers, and an investigation of natural water circulation in an OP-210 boiler was carried out. On the basis of these measurements, the maximum rates of pressure change in the boiler evaporator were determined. The on-line computation of the conditions in the combustion chamber allows for real-time determination of the heat flowrate transferred to the power boiler evaporator. Furthermore, with a quantitative indication of surface cleanliness, selective sootblowing can be directed at specific problem areas. A boiler monitoring system is also incorporated to provide details of changes in boiler efficiency and operating conditions following sootblowing, so that the effects of a particular sootblowing sequence can be analysed and optimized at a later stage.

  10. An assessment of gas-side fouling in cement plants

    Science.gov (United States)

    Marner, W. J.

    1982-01-01

    The cement industry is the most energy-intensive industry in the United States in terms of energy cost as a percentage of the total product cost. An assessment of gas-side fouling in cement plants with special emphasis on heat recovery applications is provided. In the present context, fouling is defined as the buildup of scale on a heat-transfer surface which retards the transfer of heat and includes the related problems of erosion and corrosion. Exhaust gases in the cement industry which are suitable for heat recovery range in temperature from about 100 to 1300 K, are generally dusty, may be highly abrasive, and are often heavily laden with alkalies, sulfates, and chlorides. Particulates in the exhaust streams range in size from molecular to about 100 micrometers in diameter and come from both the raw feed as well as the ash in the coal which is the primary fuel used in the cement industry. The major types of heat-transfer equipment used in the cement industry include preheaters, gas-to-air heat exchangers, waste heat boilers, and clinker coolers. At the present time, the trend in this country is toward suspension preheater systems, in which the raw feed is heated by direct contact with the hot kiln exit gases, and away from waste heat boilers as the principal method of heat recovery. The most important gas-side fouling mechanisms in the cement industry are those due to particulate, chemical reaction, and corrosion fouling.

  11. Steam generators and waste heat boilers for process and plant engineers

    CERN Document Server

    Ganapathy, V

    2014-01-01

    Incorporates Worked-Out Real-World ProblemsSteam Generators and Waste Heat Boilers: For Process and Plant Engineers focuses on the thermal design and performance aspects of steam generators, HRSGs and fire tube, water tube waste heat boilers including air heaters, and condensing economizers. Over 120 real-life problems are fully worked out which will help plant engineers in evaluating new boilers or making modifications to existing boiler components without assistance from boiler suppliers. The book examines recent trends and developments in boiler design and technology and presents novel idea

  12. The structure and behavior of salts in kraft recovery boilers

    Energy Technology Data Exchange (ETDEWEB)

    Backman, R.; Badoi, R.D.; Enestam, S. [Aabo Akademi Univ., Turku (Finland). Combustion Chemistry Research Group

    1997-10-01

    The melting behavior in the salt system (Na,K)(CO{sub 3},SO{sub 4},S,Cl,OH) is investigated by laboratory methods to enhance and further develop a chemical model for salt mixtures with compositions relevant for recovery boilers. The model, based on both literature data and experimental work can be used as (a) submodel in models for the over-all chemistry in recovery boilers and to estimate (b) deposit formation on heat transfer surfaces (fouling), (c) the melting properties of the fly ash, and (d) the smelt bed in recovery boilers. Experimental techniques used are thermal analysis, high temperature microscopy` and scanning electron microscopy. The model is implemented in a global calculation model which can handle both gas phases and condensed phases in the recovery boiler. The model gives a detailed description of the chemical reactions involved in the fume and dust formation in different locations of the flue gas channel in the boiler. (orig.)

  13. Boiler corrosion. Corrosion of boilers at low boiler water temperatures. Heizkessel-Korrosion. Korrosion von Heizkesseln bei tiefen Kesselwassertemperaturen

    Energy Technology Data Exchange (ETDEWEB)

    Koebel, M.; Elsener, M.

    1989-02-01

    Thermostatic cast iron and steel 35.8 specimens were inserted between the fire tubes of a test boiler and exposed to flue gases for a period of three weeks. The corrosion rates at material temperatures between 20 and 60deg C as well as the effects of continuous and intermittent boiler operation were determined. Details are given on the specimens alloying constituents, the testing and test conditions (schematic representation of the experimental set-up). Diagrams and tables facilitate access to test results informing about corrosion rates and corrosion product structure analyses for continuous burner operation. While low boiler water temperatures (below 60deg C in the case of extra light heating oils) are found to necessarily involve higher risks and shorter boiler service lives, low flue gas temperatures alone are considered not to be increasing the risk of boiler corrosion. (HWJ).

  14. 锅炉管高频熔覆温度场的数值模拟%Numerical simulation on temperature field of boiler tube coating fabricated by high frequency induction cladding

    Institute of Scientific and Technical Information of China (English)

    岑虎; 王云山; 雷剑波; 孟庆若; 刘少军

    2013-01-01

    Induction heating and Fourier heat conduction principles were used to simulate the temperature field of the boiler tube and alloy layer. The changing law of the temperature field under different cladding parameters was researched, and the cladding experiments were carried out on the surface of the boiler tube. The results show that the efficiency of the induction cladding is mainly influenced by power frequency and electric current. The heating rate of the boiler tube’s surface increases with increasing power frequency of induction power source or electric current of cladding. When high frequency cladding process is fixed, the lower the temperature of tube’s inwall is, the less the heating affect on base material is. When the power frequency is 250 kHz and electric current is 1 180 A, the transitional zone exits in the zone between the cladding layer and the matrix and forms metallurgical bouding.%应用感应加热原理和傅立叶导热定律对高频熔覆中锅炉管壁和合金层的温度场进行模拟计算,分析不同熔覆参数下锅炉管及合金层温度场随时间的变化规律;并对锅炉管表面进行熔覆实验研究。结果表明,在熔覆工作头和管的结构及参数给定的条件下,感应加热速度主要受高频感应加热电源频率和熔覆电流的影响。在一定范围内,感应加热电源的频率越高,或熔覆电流越大,则锅炉管表面升温速度越快,熔覆结束时管内壁温度越低,基体受热影响越小;当频率为250 kHz、熔覆电流为1180 A时,熔覆层与基体间有明显的白亮过渡带,形成了冶金结合。

  15. Analog-experiment analysis of ash-deposition monitoring model of boiler economizers in power plants

    Institute of Scientific and Technical Information of China (English)

    CHENG Wei-liang; XIA Guo-dong; XU Shou-chen

    2005-01-01

    Ash deposition is a form of particulate fouling, and appears usually in boiler economizers. The ash deposition increases capital expenditure, energy input and maintenance costs. An analog experiment for monitoring ash deposition was performed from the analogous objective of a 410 t/h boiler economizer to verify the rationality and reliability of the ash-deposition-monitoring model presented in order to increase the security and economy in economizer running. The analog experiment platform is a tube-shell exchanger that conforms well to the conditions of a self-modeling area. The analog flue gas in the shell side is the heated air mixed with ash,and in the tube side the fluid is water heated by the flue gas. The fluid state in the water side and the flue gas side follows the second self-modeling area. A 4-factor-3 level orthogonal table was used to schedule 9 operation conditions of orthogonal experiment, with the 4 factors being heat power, flue gas velocity, ashes grain diameter and adding ashes quantity while the three levels are different values due to different position classes in every factor. The ash deposition thermal resistances is calculated by the model with the measure parameters of temperature and pressure drop. It shows that the values of the ash deposition thermal resistances gradually increase up to a stable state. And the experimental results are reliable by F testing method at α = 0. 001. Therefore, the model can be applied in online monitoring of ash deposition in a boiler economizers in power plants and provides scientific decision on ash deposition prediction and sootblowing.

  16. Optimal scheduling of sootblowers in power plant boilers

    Science.gov (United States)

    Vasquez-Urbano, Pedro Manuel

    1997-11-01

    Burning coal or other fossil fuels in a utility boiler fouls the surfaces of its heat exchangers with ash and soot residues. These deposits affect the performance of the power plant since they reduce heat transfer from the combustion gases to the water or steam. Fouling can be removed during the operation of the plant with the use of lances, called sootblowers, that direct high-pressure air or steam onto the fouled surfaces. Sootblowing operations are key to plant efficiency and boiler maintenance, but they also incur operating costs. A utility boiler may have a hundred or so sootblowers placed in fixed locations. Deciding which of these should be used at any moment is complicated by the lack of instrumentation that can monitor fouling levels. This dissertation studies the optimization problem of scheduling sootblowing activities at a utility plant. The objective is to develop an optimization approach to determine which sootblowers should be activated at any moment in order to maximize plant efficiency. To accomplish this, three issues are addressed. First, models are developed that can estimate fouling conditions indirectly during plant operation using commonly available data. The approach used relies on a sequential application of linear regression fits. Secondly, autoregressive exogenous (ARX) models are used to describe the dynamics of the fouling process and to estimate the consequences of fouling on plant efficiency. All the foregoing empirical models are developed using data from a power plant. Finally, using the empirical models, an optimization model is formulated for the sootblowing scheduling problem and different optimization approaches that combine nonlinear programming with heuristics methods are investigated for its solution. The applicability of dynamic programming to this optimization problem is also explored.

  17. Experimental Research on Anti-fouling of Heat Exchange Tube under Pulsating Flow%脉动流下热交换圆管抑垢实验研究

    Institute of Scientific and Technical Information of China (English)

    郑小涛; 徐成; 喻九阳; 刘利军; 林纬

    2013-01-01

    A mean of experimental system was set up to test fouling, and use fouling resistance method compared pulsating flow with steady-state flow to research the fouling growth characteristics in pipe. The results showed that with increased frequency of pulse flow, the induce period became longer and the deposition growth rate slowed down. Fouling resistance decreased by 25 percent compared with that of the steady-state when the frequency of pulsating flow was 2 Hz and has obvious effect of restrain fouling.%建立污垢测试实验系统,采用污垢热阻法研究了脉动流和稳态流下光管内的污垢生长特性.实验结果表明,随着脉动流频率增加,污垢生长的诱导期延长,污垢生长速率减慢.当脉动流频率为2.0 Hz时,污垢的渐进热阻值较稳态流时减小25%,具有明显的阻垢效果.

  18. Impact of fouling on UV effectiveness

    Energy Technology Data Exchange (ETDEWEB)

    Dykstra, T.S. [Dalhouse Univ., Dept. of Civil Engineering, Halifax, Nova Scotia (Canada); Chauret, C. [Indiana Univ. Kokomo, Kokomo, Biological and Physical Sciences, Indiana (United States)

    2002-06-15

    In recent years ultraviolet light has gained in popularity as an attractive disinfection alternative due to its ability to inactivate bacteria and viruses. UV light has the potential to inactivate Cryptosporidium parvum and Giardia lamblia with a very low potential for the formation of harmful disinfection by-products. Previous studies have reported that particulate material present in the water can act to reduce the exposure of UV light to the receiving waters and that the interference of organic particles can serve to protect bacteria and viruses from intended disinfection. Disinfection capacity can also be reduced by organics in the source water that can accumulate on the surface of quartz sleeves. The purpose of this study was to determine the ability of a medium pressure UV light, at drinking water treatment levels, to inactivate MS 2 bacteriophage after a quartz tube has been fouled with organic rich source water for a 12- week period. To this end the inactivation of MS 2 was determined under clean and fouled conditions, in the presence and absence of humic rich water. The effect of lamp age on inactivation was also investigated. The results suggest that organic fouling of a quartz tube has a significant impact on the disinfection capacity of a medium pressure UV lamp. The presence of organics in the source water also plays a significant role in reducing the capacity of UV for bacterial and viral disinfection. Lamp age also seems to have some effect on the efficiency of UV disinfection. (author)

  19. Superheater Corrosion In Biomass Boilers: Today's Science and Technology

    Energy Technology Data Exchange (ETDEWEB)

    Sharp, William (Sandy) [SharpConsultant

    2011-12-01

    the measured first melting point of fly ash deposits does not necessarily produce a step increase in corrosion rate. Corrosion rate typically accelerates at temperatures below the first melting temperature and mixed deposits may have a broad melting temperature range. Although the environment at a superheater tube surface is initially that of the ash deposits, this chemistry typically changes as the deposits mature. The corrosion rate is controlled by the environment and temperature at the tube surface, which can only be measured indirectly. Some results are counter-intuitive. Two boiler manufacturers and a consortium have developed models to predict fouling and corrosion in biomass boilers in order to specify tube materials for particular operating conditions. It would be very useful to compare the predictions of these models regarding corrosion rates and recommended alloys in the boiler environments where field tests will be performed in the current program. Manufacturers of biomass boilers have concluded that it is more cost-effective to restrict steam temperatures, to co-fire biofuels with high sulfur fuels and/or to use fuel additives rather than try to increase fuel efficiency by operating with superheater tube temperatures above melting temperature of fly ash deposits. Similar strategies have been developed for coal fired and waste-fired boilers. Additives are primarily used to replace alkali metal chloride deposits with higher melting temperature and less corrosive alkali metal sulfate or alkali aluminum silicate deposits. Design modifications that have been shown to control superheater corrosion include adding a radiant pass (empty chamber) between the furnace and the superheater, installing cool tubes immediately upstream of the superheater to trap high chloride deposits, designing superheater banks for quick replacement, using an external superheater that burns a less corrosive biomass fuel, moving circulating fluidized bed (CFB) superheaters from the

  20. Slagging and Fouling Characteristics of HRSG for Ferrosilicon Electric Furnaces

    Directory of Open Access Journals (Sweden)

    Yungang Wang

    2015-02-01

    Full Text Available The slagging and fouling characteristics of the heat recovery steam generator (HRSG for ferrosilicon electric furnaces are discussed in this paper. Three ash samples were taken from the HRSG of a ferrosilicon furnace in Ningxia Province, China, which suffered from serious slagging and fouling. X-ray fluorescence (XRF, X-ray powder diffraction (XRD and scanning electron microscope (SEM were used to analyze the ash samples. The results show that low melting point salt Na2SO4 and composite salts Na (AlSi3O8 and 3K2SO4·CaSO4 deposit on the superheater tube walls in aerosol form and solidify to form the initial slag layer. With the continuous deposition of the low melting point compounds, more and more ash particles in the flue gas adhere to the slag surface to form a thicker slag. Low melting point composite salt NaO·Al2O3·SiO2 is absorbed on the evaporator tube walls in aerosol form. With the deposition of NaO·Al2O3·SiO2, more and more ash particles are absorbed to form the fouling. Since there is less space between pin-finned tubes, the large iron-rich slag particles are easily deposited on tube walls and fin surfaces, which is advantageous to the fouling process. There are large quantities of superfine ash particles in the flue gas that easily adhere to other particles or tube walls, which facilitates the slagging and fouling process.

  1. Active brickworks - phase I[For application in biofuel boilers]; Aktiva murverk - etapp I

    Energy Technology Data Exchange (ETDEWEB)

    Wrangensten, Lars; Schuster, Robert; Ingman, Rolf; Sendelius, Mikael; Ehleskog, Rickard [AaF-Energikonsult AB, Stockholm (Sweden)

    2003-10-01

    This report is the first step of the R and D project 'Active brickworks' within the program 'Possibilities to improve the operation conditions in industrial bark boilers by optimised combustion control'. Good high temperature resistance is one of the major characteristics of ceramics. They are based on quartz and aluminium oxide, an attachment component (acid or cement) and also different types of additives which, together with the heating treatment, gives the ceramic materials their features. The brickwork in a boiler has several assignments. First of all resistance to corrosion, erosion and protection against fouling of the water tube walls, but also to significant affect the combustion process by energy saving features and heating radiation. This project has been focused on the last named features, namely to be able to make a more active choice of brickwork in order to utilise the ceramic features and hereby making it possible to lower the combustion process emissions. The material samples received from the manufactures have been tested in a small-scale laboratory rig. Features investigated are emissivity/reflection, heat conductivity and heat capacity. Mathematic simulations have also been performed with a representative type boiler model in order to make conclusions concerning how the results can be transformed to and applied in a real full-scale boiler. The most important designing case for ceramics in bark boilers is when boiler load rapidly increases or during a fast fuel moisture change from dry to wet fuel. It has been concluded in the study that that the ceramic walls in a boiler should be divided into different layers. The outer layer in the ceiling and sidewalls of the drying zone must consist of highly insulating material in order to get a high temperature of heating surfaces close to the furnace. To store heat during load transients the heating surfaces must have high emissivity factor and good heating capacity. From this point of

  2. 基于大数据分析的电厂锅炉水冷壁失效研究%Failure investigation on boiler water wall tubes in power plant by large data analysis

    Institute of Scientific and Technical Information of China (English)

    石荣雪; 张适宜; 张胜寒

    2016-01-01

    通过对270篇电厂锅炉水冷壁爆管事故类文献研读,归纳得出造成爆管的直接原因是超温和化学腐蚀分别占21.27%、18.73%,作为根本原因之一的燃料粒度不均以及燃烧方式不当占14.44%,器壁结垢堵塞作为水冷壁管泄漏的一个间接原因占10.79%,这几种因素合计引起的泄漏次数在总泄漏次数中占65.23%,为水冷壁发生泄漏时应该优先考虑的因素。按水冷壁发生化学腐蚀的位置进行统计,得出水侧和火侧的化学腐蚀分别占64.41%和35.59%。将水冷壁水侧的化学腐蚀因素进一步分类得到氢腐蚀占36.84%,碱腐蚀占21.05%,酸腐蚀占15.79%以及蒸汽腐蚀占11.84%。这4种化学腐蚀因素合计引起的爆漏次数占所有水侧化学腐蚀因素引起爆漏次数的85.52%,为化学腐蚀因素中应该优先考虑的因素。另外,还分别讨论了不同功率机组的水冷壁腐蚀失效情况。以上结论对现有电厂水冷壁泄漏原因的快速查找和预防起到一定作用,在维持设备长期经济安全运行方面具有一定的实际意义。%This paper is based on the literature survey,after collecting the power plants’ water wall tube burst accident data,and making research on the 270 pieces of literature on boiler water wall tube explosion accident,it comes to the conclusion that the direct reasons for the tube explosion of boiler water wall in power plant are overheating and chemical corrosion which accounted for 21.27% and 18.73%,respectively. The improper boiling way and uneven grain size of burning fuel which serves as the primary causes accounted for 14.44% and the deposition jams on the wall which is one of the indirect causes accounted for 10.79%. The summation of these main reasons can make up for 65.23% in the total number of explosive leakage. When boiler water wall tube leakage happened,the above reasons were the first to be considered. Also,the material quality and abrasion are the

  3. 超超临界锅炉小径管焊缝的超声相控阵检测工艺%Ultrasonic Phased Array Testing for Small Diameter Tube Weld of Ultra-supercritical Boiler

    Institute of Scientific and Technical Information of China (English)

    王维东; 王亦民; 孟倩倩; 曹云峰; 张振华

    2015-01-01

    A series of ultrasonic phased array inspection contrast test blocks were developed according to the distribution range of the boiler pipe weld defect,and at the same time tests were conducted on the simulation and natural defects,respectively.By making distance amplitude curve for 1 mm diameter horizontal hole,we quantified and measured indicating length of defects both inside and outside of the tube with different diameter and thickness, and thus corrected the errors of the traditional detection and established the testing method of ultrasonic phased array for small pipe weld.%根据锅炉小径管焊缝的缺陷分布范围,研制出系列超声相控阵检测的对比试块,并进行了模拟与自然缺陷的检测试验。测试采用ϕ1 mm横孔制作距离-波幅曲线,对不同外径与壁厚的内外壁缺陷进行定量与指示长度测定,修正了传统检测的误区,建立了超声相控阵小径管焊缝的检测工艺方法。

  4. Mixed salt crystallisation fouling

    CERN Document Server

    Helalizadeh, A

    2002-01-01

    The main purpose of this investigation was to study the mechanisms of mixed salt crystallisation fouling on heat transfer surfaces during convective heat transfer and sub-cooled flow boiling conditions. To-date no investigations on the effects of operating parameters on the deposition of mixtures of calcium sulphate and calcium carbonate, which are the most common constituents of scales formed on heat transfer surfaces, have been reported. As part of this research project, a substantial number of experiments were performed to determine the mechanisms controlling deposition. Fluid velocity, heat flux, surface and bulk temperatures, concentration of the solution, ionic strength, pressure and heat transfer surface material were varied systematically. After clarification of the effect of these parameters on the deposition process, the results of these experiments were used to develop a mechanistic model for prediction of fouling resistances, caused by crystallisation of mixed salts, under convective heat transfer...

  5. Characterization of Oxy-combustion Impacts in Existing Coal-fired Boilers

    Energy Technology Data Exchange (ETDEWEB)

    Bradley Adams; Andrew Fry; Constance Senior; Hong Shim; Huafeng Wang; Jost Wendt; Christopher Shaddix

    2009-06-30

    This report summarizes Year 1 results of a research program designed to use multi-scale experimental studies and fundamental theoretical models to characterize and predict the impacts of retrofit of existing coal-fired utility boilers for oxy-combustion. Through the course of Year 1 activities, great progress was made toward understanding the issues associated with oxy-combustion retrofit of coal-fired boilers. All four Year 1 milestones and objectives have been, or will be, completed on schedule and within budget. Progress in the four milestone areas may be summarized as follows: • University of Utah has performed size segregated ash composition measurements in the Oxy-Fuel Combustor (OFC). These experiments indicate that oxy-combustion retrofit may impact ash aerosol mineral matter composition. Both flame temperature and flue gas composition have been observed to influence the concentration of calcium, magnesium and iron in the fine particulate. This could in turn impact boiler fouling and slagging. • Sandia National Labs has shown that char oxidation rate is dependent on particle size (for sizes between 60 and 100 microns) by performing fundamental simulations of reacting char particles. These predictions will be verified by making time-resolved optical measurements of char particle temperature, velocity and size in bench-scale experiments before the end of Year 1. • REI and Siemens have completed the design of an oxy-research burner that will be mounted on University of Utah’s pilot-scale furnace, the L1500. This burner will accommodate a wide range of O2, FGR and mixing strategies under conditions relevant for utility boiler operation. Through CFD modeling of the different burner designs, it was determined that the key factor influencing flame stabilization location is particle heat-up rate. The new oxy-research burner and associated equipment is scheduled for delivery before the end of Year 1. • REI has completed a literature survey of slagging and

  6. Design of Boiler Welding for Improvement of Lifetime and Cost Control

    OpenAIRE

    Atcharawadi Thong-On; Chatdanai Boonruang

    2016-01-01

    Fe-2.25Cr-1Mo a widely used material for headers and steam tubes of boilers. Welding of steam tube to header is required for production of boiler. Heat affected zone of the weld can have poor mechanical properties and poor corrosion behavior leading to weld failure. The cost of material used for steam tube and header of boiler should be controlled. This study propose a new materials design for boiler welding to improve the lifetime and cost control, using tungsten inert gas (TIG) welding of F...

  7. Control Properties of Bottom Fired Marine Boilers

    DEFF Research Database (Denmark)

    Solberg, Brian; Andersen, Palle; Karstensen, Claus M. S.

    2007-01-01

    This paper focuses on model analysis of a dynamic model of a bottom fired one-pass smoke tube boiler. Linearized versions of the model are analyzed and show large variations in system gains at steady state as function of load whereas gain variations near the desired bandwidth are small. An analysis...

  8. Thermal Analysis of Superheater Platen Tubesin Boilers

    Directory of Open Access Journals (Sweden)

    Shahram Falahatkar

    2014-01-01

    Full Text Available Superheaters are among the most important components of boilers and have major importance due to this operation in high temperatures and pressures. Turbines are sensitive to the fluctuation of superheaterstemperature;therefore even the slightest fluctuation in the outlet vapor temperature from the superheaters does damage the turbine axis and fins. Examining the potential damages of combustion in the boilers and components such as the superheaters can have a vital contribution to the progression of the productivity of boiler, turbine and the power plant altogether it solutions are to be fund to improve such systems. In this study, the focus is on the nearest tube set of superheaters to the combustion chamber.These types of tubes are exposed to a wide range ofcombustion flames such that the most heat transfer to them is radiation type.Here, the 320 MW boiler of Isfahan power plant (Iran, the combustion chamber, 16 burners and the platensuperheater tubes were remodeled by CFD technique. The fluid motion, the heat transfer and combustion processes are analyzed. The two-equation turbulence model of k-εis adopted to measure the eddy viscosity. The eddy dissipation model is used to calculate the combustion as well as the P-1 radiation model to quantify the radiation. The overheated zones of superheater tubes and the combustion chamber are identified in order toimprove this problem by applying the radiation thermal shields and knees with porous crust which are introduced as the new techniques.

  9. A Rule-Based Industrial Boiler Selection System

    Science.gov (United States)

    Tan, C. F.; Khalil, S. N.; Karjanto, J.; Tee, B. T.; Wahidin, L. S.; Chen, W.; Rauterberg, G. W. M.; Sivarao, S.; Lim, T. L.

    2015-09-01

    Boiler is a device used for generating the steam for power generation, process use or heating, and hot water for heating purposes. Steam boiler consists of the containing vessel and convection heating surfaces only, whereas a steam generator covers the whole unit, encompassing water wall tubes, super heaters, air heaters and economizers. The selection of the boiler is very important to the industry for conducting the operation system successfully. The selection criteria are based on rule based expert system and multi-criteria weighted average method. The developed system consists of Knowledge Acquisition Module, Boiler Selection Module, User Interface Module and Help Module. The system capable of selecting the suitable boiler based on criteria weighted. The main benefits from using the system is to reduce the complexity in the decision making for selecting the most appropriate boiler to palm oil process plant.

  10. Fouling and thermal-performance characteristics of the Humboldt Bay Unit 2 power-plant condenser

    Energy Technology Data Exchange (ETDEWEB)

    Rabas, T.J. [Argonne National Lab., IL (United States); Elliott, E.S. [Pacific Gas and Electric Co., San Ramon, CA (US)

    1993-07-01

    An experimental program was conducted at the Humboldt Bay condenser using eight clusters of four neighboring tubes with different conditions. In each cluster, there were (1) a new tube, the tubeside fluid being distilled water; (2) a new tube, the tubeside fluid being plant circulating water (seawater) and no cleaning; (3) an old tube, plant circulating water with no cleaning; and (4) an old tube, plant circulating water with normal periodic manual cleaning (blowing plugs or sponge balls). These tube clusters were located at four different locations within both the first and second passes of this two-pass condenser. Because of the different conditions, the fouling and cleaning characteristics can be obtained with measurements of the flow rate and inlet, outlet, and saturation temperatures. In addition to the fouling data, the thermal performance can be compared to that obtained with the standard rating method. There was a reduction in the thermal performance of the new, distilled-water tubes for about the first 80 days, and then the performance remained essentially constant. This performance change was most likely the result of the change from dropwise to filmwise condensation on the 7/8-in OD, 18 BWG Admiralty tubes. There was a continued increase of the tubeside fouling resistance with time (no asymptotic behavior) for the tubes that were not cleaned in each cluster using the plant circulating water. The fouling rates were somewhat larger for the first or lower temperature pass initially for the new tubes and after about 100 days for the old tubes. However, the fouling resistance values were substantially larger for the old tubes.

  11. Factors affecting stress assisted corrosion cracking of carbon steel under industrial boiler conditions

    Science.gov (United States)

    Yang, Dong

    Failure of carbon steel boiler tubes from waterside has been reported in the utility boilers and industrial boilers for a long time. In industrial boilers, most waterside tube cracks are found near heavy attachment welds on the outer surface and are typically blunt, with multiple bulbous features indicating a discontinuous growth. These types of tube failures are typically referred to as stress assisted corrosion (SAC). For recovery boilers in the pulp and paper industry, these failures are particularly important as any water leak inside the furnace can potentially lead to smelt-water explosion. Metal properties, environmental variables, and stress conditions are the major factors influencing SAC crack initation and propagation in carbon steel boiler tubes. Slow strain rate tests (SSRT) were conducted under boiler water conditions to study the effect of temperature, oxygen level, and stress conditions on crack initation and propagation on SA-210 carbon steel samples machined out of boiler tubes. Heat treatments were also performed to develop various grain size and carbon content on carbon steel samples, and SSRTs were conducted on these samples to examine the effect of microstructure features on SAC cracking. Mechanisms of SAC crack initation and propagation were proposed and validated based on interrupted slow strain tests (ISSRT). Water chemistry guidelines are provided to prevent SAC and fracture mechanics model is developed to predict SAC failure on industrial boiler tubes.

  12. Oil ash corrosion; A review of utility boiler experience

    Energy Technology Data Exchange (ETDEWEB)

    Paul, L.D. (Babcock and Wilcox Co., Alliance, OH (United States)); Seeley, R.R. (Babcock and Wilcox Canada Ltd., Cambridge, ON (Canada))

    1991-02-01

    In this paper a review of experience with oil ash corrosion is presented along with current design practices used to avoid excessive tube wastage. Factors influencing oil ash corrosion include fuel chemistry, boiler operation, and boiler design. These factors are interdependent and determine the corrosion behavior in utility boilers. Oil ash corrosion occurs when vanadium-containing ash deposits on boiler tube surfaces become molten. These molten ash deposits dissolve protective oxides and scales causing accelerated tube wastage. Vanadium is the major fuel constituent responsible for oil ash corrosion. Vanadium reacts with sodium, sulfur, and chlorine during combustion to produce lower melting temperature ash compositions, which accelerate tube wastage. Limiting tube metal temperatures will prevent ash deposits from becoming molten, thereby avoiding the onset of oil ash corrosion. Tube metal temperatures are limited by the use of a parallel stream flow and by limiting steam outlet temperatures. Operating a boiler with low excess air has helped avoid oil ash corrosion by altering the corrosive combustion products. Air mixing and distribution are essential to the success of this palliative action. High chromium alloys and coatings form more stable protective scaled on tubing surfaces, which result in lower oil ash corrosion rates. However, there is not material totally resistant to oil ash corrosion.

  13. Prevention of corrosion and deposit formation in wood chip fired boilers; Forebyggelse af korrosion og belaegningsdannelse i flisfyrede kedler

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2003-10-15

    The report describes methods for reducing deposition of chlorides on boiler tubes in relation to biomass combustion with the overall purpose of avoiding corrosion and fouling problems. Mechanisms for release and deposition of chlorides are described as well as mechanisms for high temperature corrosion. Three methods for reduction of chloride binding have been identified and evaluated: 1) removal of chloride containing biomass fractions, 2) optimization of boiler air and fuel supply, 3) additive dosing. Among those possibilities it has turned out that additive dosage is the only method which is practicable and economically feasible, and which ensures the requested effect at the same time. A number of additives within the sulphur-based, aluminium/silicon-based and calcium phosphate-based groups have been tested. The selection of an additive will be based on optimisation of the following parameters: additive effect, additive costs, health, safety and environmental impacts, handling costs and costs in connection with residual products disposal and possible sulphur dioxide emission. Costs in connection with the additive dosing have been compared to estimated repair costs in connection with corrosion damages. The comparison indicates that additive dosing is economically attractive in some but not all cases. (au)

  14. Milk fouling in heat exchangers.

    NARCIS (Netherlands)

    Jeurnink, Th.J.M.

    1996-01-01

    The mechanisms of fouling of heat exchangers by milk were studied. Two major fouling mechanisms were indentified during the heat treatment of milk: (i) the formation and the subsequent deposition of activated serum protein molecules as a result of the heat denaturation; (ii) the precipitation of cal

  15. Central heating: package boilers

    Energy Technology Data Exchange (ETDEWEB)

    Farahan, E.

    1977-05-01

    Performance and cost data for electrical and fossil-fired package boilers currently available from manufacturers are provided. Performance characteristics investigated include: unit efficiency, rated capacity, and average expected lifetime of units. Costs are tabulated for equipment and installation of various package boilers. The information supplied in this report will simplify the process of selecting package boilers required for industrial, commercial, and residential applications.

  16. Commercial production practice on steel 12Cr1MoV for boiler tube%锅炉管用钢12Cr1MoV 生产实践

    Institute of Scientific and Technical Information of China (English)

    刘兵; 吕安明; 刘利; 梁艳; 刘超群

    2015-01-01

    The high pressure boiler tube steel 12Cr1MoV was produced with the path of hot metal+scrap → 100 t EAF→double LF→ double VD→ round billet continuous casting(section 650 mm),in the special steel division new district of Laiwu Steel.The difficulties that existed in the actual production of 12Cr1MoV can be overcame with the methods of the reinforcement smelting process,adjusting the refining slag,strengthen protective casting and so on. So the chemical composition,low power structure,non-metallic inclusions rating and other indicators of the 12Cr1MoV meet the customers requirement.%莱钢特钢事业部新区采用铁水+废钢→100 t 电炉→双工位 LF→双工位 VD→圆坯连铸(650 mm)→步进式加热炉→950轧机轧制的流程生产高压锅炉管钢12Cr1MoV,通过优化冶炼工艺、调整精炼渣系、强化保护浇铸等措施,克服了12Cr1MoV 钢在实际生产中的困难,使12Cr1MoV 钢的化学成分、低倍以及非金属夹杂物评级等各项指标均满足用户要求。

  17. Control Properties of Bottom Fired Marine Boilers

    DEFF Research Database (Denmark)

    Solberg, Brian; Andersen, Palle; Karstensen, Claus M. S.

    2005-01-01

    This paper focuses on model analysis of a dynamic model of a bottom fired one-pass smoke tube boiler. Linearised versions of the model are analysed to determine how gain, time constants and right half plane zeros (caused by the shrink-and-swell phenomenon) depend on the steam flow load. Furthermore...... the interactions in the system are inspected to analyse potential benefit from using a multivariable control strategy in favour of the current strategy based on single loop theory. An analysis of the nonlinear model is carried out to further determine the nonlinear characteristics of the boiler system...

  18. 声波吹灰器在旋风炉脱硝改造中的应用%The Application of Sonic Soot-Blower in the Cyclone-type Boiler of Denitration Transformation

    Institute of Scientific and Technical Information of China (English)

    李晓贺; 徐欣欣

    2016-01-01

    介绍了天津大沽化工股份有限公司热电分厂130,t/h旋风炉经过烟气脱硝改造后,空气预热器出现大量积灰,管束堵塞非常严重,最终导致烟气阻力增大,严重影响了锅炉运行的安全性和经济性。通过在空气预热器加装声波吹灰器,空气预热器的积灰问题得到了有效解决,锅炉运行的安全性和经济效益得到了保证。%The 130,t/h cyclone-type boiler of Tianjin Dagu Chemical Co.,LTD.Thermal Power Plant,which after flue gas denitration transformation,in the process of running,has been found a large amount of ash accumulation in the air preheater,resulting in tube bundle,eventually led to increased flue gas resistance.It seriously affects the safety and econ-omy of boiler operation.By adding sound wave soot blower in air preheater,the fouling problem of air preheater has been effectively solved,the safety and economy of boiler operation are thus guaranteed.

  19. Diffusion Combustion in a Tube-Nested Combustor

    OpenAIRE

    Tetsuji, Seko; Ryosuke, Matsumoto; Yoshitomo, Shintani; Isao, Ishihara; Mamoru, Ozawa

    2004-01-01

    An advanced-type compact water-tube boiler has been designed on the basis of the new concept of cooling flame by water-tube bank in the furnace, and is referred to as "tube-nested combustor". It realized drastic reduction in boiler size as well as in the NO_x emission. In this present study, aiming at further improvement of boiler efficiency and reduction of NO_x emission, the combustion characteristics in the furnace were investigated by using the test boiler of 0.5t/h steam output. Experime...

  20. Development of P22 Tube Blank Steel for High Pressure Boiler Tube%高压锅炉管用P22管坯钢的开发生产

    Institute of Scientific and Technical Information of China (English)

    袁淑君; 李业才

    2016-01-01

    Based on the technology of steel requirements, the chemical composition and internal control requirements of the steel were designed. Using clean steel technology to control S, P and inclusion, selecting high-quality scrap and molten iron to control As, Sn, Pb, Sb, Bi and other harmful elements, and the Ca treatment can reduce the harm of the inclusion. P22 tube blank steel was produced by the process“EAF-LF-VD-CC”in Laiwu Steel, physical quality inspection shows that the steel is pure, the trace harmful elements are low, the temper brittleness sensitivity coefficient J and the CEF value were controlled ideal, the macrostructure and surface quality of the round billet are better.%依据钢的技术要求,设计了钢的化学成分及内控要求,采用纯净钢技术控制S、P及夹杂物,选用优质废钢和铁水控制As、Sn、Pb、Sb、Bi等有害元素,并通过Ca处理降低夹杂物的危害,莱钢采用EAF-LF-VD-CC工艺流程开发了P22管坯钢。实物质量检测表明,钢质纯净,微量有害元素低,回火脆性敏感系数J、CEF控制理想,圆坯低倍组织和表面质量良好。

  1. Boiler conversions for biomass

    Energy Technology Data Exchange (ETDEWEB)

    Kinni, J. [Tampella Power Inc., Tampere (Finland)

    1996-12-31

    Boiler conversions from grate- and oil-fired boilers to bubbling fluidized bed combustion have been most common in pulp and paper industry. Water treatment sludge combustion, need for additional capacity and tightened emission limits have been the driving forces for the conversion. To accomplish a boiler conversion for biofuel, the lower part of the boiler is replaced with a fluidized bed bottom and new fuel, ash and air systems are added. The Imatran Voima Rauhalahti pulverized-peat-fired boiler was converted to bubbling fluidized bed firing in 1993. In the conversion the boiler capacity was increased by 10 % to 295 MWth and NO{sub x} emissions dropped. In the Kymmene Kuusankoski boiler, the reason for conversion was the combustion of high chlorine content biosludge. The emissions have been under general European limits. During the next years, the emission limits will tighten and the boilers will be designed for most complete combustion and compounds, which can be removed from flue gases, will be taken care of after the boiler. (orig.) 3 refs.

  2. Super Boiler: Packed Media/Transport Membrane Boiler Development and Demonstration

    Energy Technology Data Exchange (ETDEWEB)

    Liss, William E; Cygan, David F

    2013-04-17

    Gas Technology Institute (GTI) and Cleaver-Brooks developed a new gas-fired steam generation system the Super Boiler for increased energy efficiency, reduced equipment size, and reduced emissions. The system consists of a firetube boiler with a unique staged furnace design, a two-stage burner system with engineered internal recirculation and inter-stage cooling integral to the boiler, unique convective pass design with extended internal surfaces for enhanced heat transfer, and a novel integrated heat recovery system to extract maximum energy from the flue gas. With these combined innovations, the Super Boiler technical goals were set at 94% HHV fuel efficiency, operation on natural gas with <5 ppmv NOx (referenced to 3%O2), and 50% smaller than conventional boilers of similar steam output. To demonstrate these technical goals, the project culminated in the industrial demonstration of this new high-efficiency technology on a 300 HP boiler at Clement Pappas, a juice bottler located in Ontario, California. The Super Boiler combustion system is based on two stage combustion which combines air staging, internal flue gas recirculation, inter-stage cooling, and unique fuel-air mixing technology to achieve low emissions rather than external flue gas recirculation which is most commonly used today. The two-stage combustion provides lower emissions because of the integrated design of the boiler and combustion system which permit precise control of peak flame temperatures in both primary and secondary stages of combustion. To reduce equipment size, the Super Boiler's dual furnace design increases radiant heat transfer to the furnace walls, allowing shorter overall furnace length, and also employs convective tubes with extended surfaces that increase heat transfer by up to 18-fold compared to conventional bare tubes. In this way, a two-pass boiler can achieve the same efficiency as a traditional three or four-pass firetube boiler design. The Super Boiler is consequently

  3. WASTE HEAT RECOVERY FROM BOILER OF LARGE-SCALE TEXTILE INDUSTRY

    OpenAIRE

    Prateep Pattanapunt; Kanokorn Hussaro; Tika Bunnakand; Sombat Teekasap

    2013-01-01

    Many industrial heating processes generate waste energy in textile industry; especially exhaust gas from the boiler at the same time reducing global warming. Therefore, this article will present a study the way to recovery heat waste from boiler exhaust gas by mean of shell and tube heat exchanger. Exhaust gas from boiler dyeing process, which carries a large amount of heat, energy consumptions could be decrease by using of waste-heat recovery systems. In this study, using ANASYS simulation p...

  4. Observation on fouling organisms collected from Indian naval ships at Bombay

    Directory of Open Access Journals (Sweden)

    V. Gopalakrishnan

    1959-01-01

    Full Text Available Fouling organisms collected from Indian Naval Ships dry-docked at Bombay during a period of two years (July 1956-June 1958 were studied in detail. Forty six of the forms collected have been identified. The most important groups of ship-fouling Organisms in Bombay waters are Barnacles, Hydroids, Polyzoans and Tube-worms. Eleven different Fouling Communities have been found to dominate the settlements on the hulls at different occasions. Definite zonations that could be observed were restriction of green algae to the boot-top area and mussels and oysters to the pipes and gratings. An attempt has been made to find the sequence of settlement of the different major fouling groups. Some general remarks on the observations have also been included.

  5. Study of the Flow and Heat Transfer Characters in the Tube Sheet Cooling Chamber of a Fire Tube Waste Heat Boiler%火管式余热锅炉管板冷却室内流动传热研究

    Institute of Scientific and Technical Information of China (English)

    李超; 黄波; 代正华; 杨骥; 于广锁; 王辅臣

    2015-01-01

    气流床气化–废锅流程具有较高的热效率并可副产一定量蒸汽,适宜于整体气化联合循环(IGCC)发电或无需合成气变换的工况。文中对常用于气态/液体烃气流床气化的工业火锅式余热锅炉管板冷却室建立了三维数值模型。采用Realizable k-ε模型模拟了湍流流动过程,用离散坐标模型(DOM)计算了合成气辐射传热过程,耦合研究了流体与固体壁面间的流动和传热过程。考察了冷却水入口形式、冷却水流量和出口环隙宽度对冷却室内流动传热过程的影响。结果表明,3冷却水入口的形式能够有效改善合成气管水侧壁面的冷却效果,同时获得更均匀的冷却室内速度、温度分布。现有的2冷却水入口形式下,优化的冷却水质量流量为200 t/h。此外,在合成气管道的入口处加入刚玉套管能够使合成气管道壁面的最高温度降低106 K,有效保护合成气管端部。%Due to its high energy efficiency and steam production, the entrained-flow gasification process with the radiant and conductive cooler is suitable for the integrated gasification combined cycle (IGCC) or other processes without water gas shift unit. In this work, a 3D numerical model was established to study the characters of fluid dynamic and heat transfer of the tube sheet cooling chamber of a commercial scale fire-tube waste heat boiler, which was adopted in the gaseous/liquid hydrocarbon gasification process. The realizable k-ε model and discrete ordinate model (DOM) were employed to simulate the turbulence and syngas radiant heat transfer, respectively. The fluid-solid coupling analysis of flow and heat transfer was conducted. The effects of inlet types and mass flow of the cooling water and the width of the cooling water outlet on the velocity and temperature distribution were investigated. The results show that the 3 inlets of the cooling water is the most appropriate type in enhancing the

  6. Modelling transition states of a small once-through boiler

    Energy Technology Data Exchange (ETDEWEB)

    Talonpoika, T. [Lappeenranta Univ. of Technology (Finland). Dept. of Energy Technology

    1997-12-31

    This article presents a model for the unsteady dynamic behaviour of a once-through counter flow boiler that uses an organic working fluid. The boiler is a compact waste-heat boiler without a furnace and it has a preheater, a vaporiser and a superheater. The relative lengths of the boiler parts vary with the operating conditions since they are all parts of a single tube. The boiler model is presented using a selected example case that uses toluene as the process fluid and flue gas from natural gas combustion as the heat source. The dynamic behaviour of the boiler means transition from the steady initial state towards another steady state that corresponds to the changed process conditions. The solution method chosen is to find such a pressure of the process fluid that the mass of the process fluid in the boiler equals the mass calculated using the mass flows into and out of the boiler during a time step, using the finite difference method. A special method of fast calculation of the thermal properties is used, because most of the calculation time is spent in calculating the fluid properties. The boiler is divided into elements. The values of the thermodynamic properties and mass flows are calculated in the nodes that connect the elements. Dynamic behaviour is limited to the process fluid and tube wall, and the heat source is regarded as to be steady. The elements that connect the preheater to the vaporiser and the vaporiser to the superheater are treated in a special way that takes into account a flexible change from one part to the other. The initial state of the boiler is received from a steady process model that is not a part of the boiler model. The known boundary values that may vary during the dynamic calculation were the inlet temperature and mass flow rates of both the heat source fluid and the process fluid. The dynamic boiler model is analysed for linear and step charges of the entering fluid temperatures and flow rates. The heat source side tests show that

  7. 49 CFR 214.323 - Foul time.

    Science.gov (United States)

    2010-10-01

    ... 49 Transportation 4 2010-10-01 2010-10-01 false Foul time. 214.323 Section 214.323 Transportation... TRANSPORTATION RAILROAD WORKPLACE SAFETY Roadway Worker Protection § 214.323 Foul time. Working limits established on controlled track through the use of foul time procedures shall comply with the...

  8. 高压锅炉管钢P12铸锭中夹杂物分布解剖研究%Investigation of inclusion distribution in ingots of high pressure boiler tube steel P12 by dissection

    Institute of Scientific and Technical Information of China (English)

    刘建华; 包燕平; 王国宣; 阳燕; 李开明; 李立新

    2012-01-01

    Inclusion distribution in 16.8 t ingots of high pressure boiler tube steel P12 was studied by dissection, total oxygen analysis, original position statistic distribution analysis (OPA) , metallographie microscope static analysis and small sample electroly- sis. It was found that a negative inclusion segregation area existed in the central part of the ingot head where the inclusion quantity is lower; while a positive inclusion segregation area existed in the center and lower part of the ingot where the inclusion quantity is higher. A new concept of inclusion segregation index was put forward to describe the segregation degree of inclusions. Total oxygen analysis and OPA results demonstrated that the segregation indexes of oxide inclusions were 1.4 to 1.6 in the central and lower part of the ingot and 0. 5 to 0.7 in the central part of the ingot head. As both oxide and sulphide inclusions were tested by metallographic microscope static analysis and slime small sample electrolysis, the inclusion segregation indexes were about 0. 7 to 0. 8 in the central part of the ingot head and 1.15 to 1.35 in the center and lower part of the ingot. The average size of oxide inclusions in the central and lower part of the ingot was bigger than that in other places, showing that the main mechanism for inclusion segregation in the central and lower part of the ingot is the picking of large inclusions by showering crystallites during floatation.%分别采用解剖、总氧分析(T[O])、原位统计分析、金相显微镜统计分析和小样电解实验研究了16.8 t高压锅炉管钢P12铸锭中夹杂物的分布.发现在铸锭的上中部存在夹杂物数量较低的负偏聚区域,而在中心及尾部中心部位存在夹杂物数量较高的正偏聚区域.为了表征夹杂物的偏聚程度,提出了夹杂物偏聚指数的新概念.总氧分析和原位统计分析结果表明铸锭中下部氧化物夹杂物偏聚指数达到1.4~1.6,而在上中部氧化物

  9. Materials and boiler rig testing to support chemical cleaning of once-through AGR boilers

    Energy Technology Data Exchange (ETDEWEB)

    Tice, D.R.; Platts, N.; Raffel, A.S. [Serco Assurance (United Kingdom); Rudge, A. [British Energy Generation Ltd. (United Kingdom)

    2002-07-01

    An extensive programme of work has been carried out to evaluate two candidate inhibited cleaning solutions for possible implementation on plant, which would be the first chemical clean of an AGR boiler. The two candidate cleaning solutions considered were a Stannine-inhibited citric acid/formic acid mixture (GOM106) and inhibited hydrofluoric acid. Citric acid-based cleaning processes are widely used within the UK Power Industry. The GOM106 solution, comprising a mixture of 3% citric acid, 0.5% formic acid and 0.05% Stannine LTP inhibitor, buffered with ammonia to pH 3.5, was developed specifically for the AGR boilers during the 1970's. Although a considerable amount of materials testing work was carried out by British Energy's predecessor companies to produce a recommended cleaning procedure there were some remaining concerns with the use of GOM106, from these earlier studies, for example, an increased risk of pitting attack associated with the removal of thick 9Cr oxide deposits and a risk of unacceptable damage in critical locations such as the upper transition joints and other weld locations. Hence, additional testing was still required to validate the solution for use on plant. Inhibited hydrofluoric acid (HFA) was also evaluated as an alternative reagent to GOM106. HFA has been used extensively for cleaning mild and low'alloy steel boiler tubes in fossil-fired plant in the UK and elsewhere in Europe and is known to remove oxide quickly. Waste treatment is also easier than for the GOM106 process and some protection against damage to the boiler tube materials is provided by complexing of fluoride with ferric ion. Validation of the potential reagents and inhibitors was achieved by assessing the rate and effectiveness of oxide removal from specimens of helical boiler tubing and welds, together with establishing the extent of any metal loss or localised damage. The initial materials testing resulted in the inhibited ammoniated citric / formic acid

  10. Materials for the pulp and paper industry. Section 1: Development of materials for black liquor recovery boilers

    Energy Technology Data Exchange (ETDEWEB)

    Keiser, J.R.; Hubbard, C.R.; Payzant, E.A. [Oak Ridge National Lab., TN (United States)] [and others

    1997-04-01

    Black liquor recovery boilers are essential components of kraft pulp and paper mills because they are a critical element of the system used to recover the pulping chemicals required in the kraft pulping process. In addition, the steam produced in these boilers is used to generate a significant portion of the electrical power used in the mill. Recovery boilers require the largest capital investment of any individual component of a paper mill, and these boilers are a major source of material problems in a mill. The walls and floors of these boilers are constructed of tube panels that circulate high pressure water. Molten salts (smelt) accumulate on the floor of recovery boilers, and leakage of water into the boiler can result in a violent explosion when the leaked water instantly vaporizes upon contacting the molten smelt. Because corrosion of the conventionally-used carbon steel tubing was found to be excessive in the lower section of recovery boilers, use of stainless steel/carbon steel co-extruded tubing was adopted for boiler walls to lessen corrosion and reduce the likelihood of smelt/water explosions. Eventually, this co-extruded or composite (as it is known in the industry) tubing was selected for use as a portion or all of the floor of recovery boilers, particularly those operating at pressures > 6.2 MPa (900 psi), because of the corrosion problems encountered in carbon steel floor tubes. Since neither the cause of the cracking nor an effective solution has been identified, this program was established to develop a thorough understanding of the degradation that occurs in the composite tubing used for walls and floors. This is being accomplished through a program that includes collection and review of technical reports, examination of unexposed and cracked tubes from boiler floors, computer modeling to predict residual stresses under operating conditions, and operation of laboratory tests to study corrosion, stress corrosion cracking, and thermal fatigue.

  11. Application of the decree 2910 for coal fired boilers; Application de l`arrete 2910 aux chaudieres a charbon

    Energy Technology Data Exchange (ETDEWEB)

    Hing, K. [CDF Energie, Charbonnages de France, 92 - Rueil-Malmaison (France)

    1997-12-31

    The impacts of the new French decree 2910 concerning the classification of all combustion equipment with regards to their energy sources, energy efficiency and pollution control, on 2 to 20 MW coal-fired boilers, are discussed, with emphasis on their pollutant emissions (SO{sub 2}, NO{sub x} and ashes). The compositions of several coals is presented and the various types of coal-fired boilers adapted to the new decree are presented: automatic boilers, dense fluidized bed boilers, vibrating and chain grids with fume tubes and water tubes

  12. Oxy-Combustion Boiler Material Development

    Energy Technology Data Exchange (ETDEWEB)

    Michael Gagliano; Andrew Seltzer; Hans Agarwal; Archie Robertson; Lun Wang

    2012-01-31

    Under U.S. Department of Energy Cooperative Agreement No. DE-NT0005262 Foster Wheeler North America Corp conducted a laboratory test program to determine the effect of oxy-combustion on boiler tube corrosion. In this program, CFD modeling was used to predict the gas compositions that will exist throughout and along the walls of air-fired and oxy-fired boilers operating with low to high sulfur coals. Test coupons of boiler tube materials were coated with deposits representative of those coals and exposed to the CFD predicted flue gases for up to 1000 hours. The tests were conducted in electric tube furnaces using oxy-combustion and air-fired flue gases synthesized from pressurized cylinders. Following exposure, the test coupons were evaluated to determine the total metal wastage experienced under air and oxy-combustions conditions and materials recommendations were made. Similar to air-fired operation, oxy-combustion corrosion rates were found to vary with the boiler material, test temperature, deposit composition, and gas composition. Despite this, comparison of air-fired and oxy-fired corrosion rates showed that oxy-firing rates were, for the most part, similar to, if not lower than those of air-firing; this finding applied to the seven furnace waterwall materials (wrought and weld overlay) and the ten superheater/reheater materials (wrought and weld overlay) that were tested. The results of the laboratory oxy-combustion tests, which are based on a maximum bulk flue gas SO{sub 2} level of 3200 ppmv (wet) / 4050 ppmv (dry), suggest that, from a corrosion standpoint, the materials used in conventional subcritical and supercritical, air-fired boilers should also be suitable for oxy-combustion retrofits. Although the laboratory test results are encouraging, they are only the first step of a material evaluation process and it is recommended that follow-on corrosion tests be conducted in coal-fired boilers operating under oxy-combustion to provide longer term (one to

  13. Oxy-Combustion Boiler Material Development

    Energy Technology Data Exchange (ETDEWEB)

    Gagliano, Michael; Seltzer, Andrew; Agarwal, Hans; Robertson, Archie; Wang, Lun

    2012-01-31

    Under U.S. Department of Energy Cooperative Agreement No. DE-NT0005262 Foster Wheeler North America Corp conducted a laboratory test program to determine the effect of oxy-combustion on boiler tube corrosion. In this program, CFD modeling was used to predict the gas compositions that will exist throughout and along the walls of air-fired and oxy-fired boilers operating with low to high sulfur coals. Test coupons of boiler tube materials were coated with deposits representative of those coals and exposed to the CFD predicted flue gases for up to 1000 hours. The tests were conducted in electric tube furnaces using oxy-combustion and air-fired flue gases synthesized from pressurized cylinders. Following exposure, the test coupons were evaluated to determine the total metal wastage experienced under air and oxy-combustions conditions and materials recommendations were made. Similar to air-fired operation, oxy-combustion corrosion rates were found to vary with the boiler material, test temperature, deposit composition, and gas composition. Despite this, comparison of air-fired and oxy-fired corrosion rates showed that oxy-firing rates were, for the most part, similar to, if not lower than those of air-firing; this finding applied to the seven furnace waterwall materials (wrought and weld overlay) and the ten superheater/reheater materials (wrought and weld overlay) that were tested. The results of the laboratory oxy-combustion tests, which are based on a maximum bulk flue gas SO2 level of 3200 ppmv (wet) / 4050 ppmv (dry), suggest that, from a corrosion standpoint, the materials used in conventional subcritical and supercritical, air-fired boilers should also be suitable for oxy-combustion retrofits. Although the laboratory test results are encouraging, they are only the first step of a material evaluation process and it is recommended that follow-on corrosion tests be conducted in coal-fired boilers operating under oxy-combustion to provide longer term (one to two year

  14. Dynamic Boiler Performance

    DEFF Research Database (Denmark)

    Sørensen, Kim

    Traditionally, boilers have been designed mainly focussing on the static operation of the plant. The dynamic capability has been given lower priority and the analysis has typically been limited to assuring that the plant was not over-stressed due to large temperature gradients. New possibilities...... for buying and selling energy has increased the focus on the dynamic operation capability, efciency, emissions etc. For optimizing the design of boilers for dynamic operation a quantication of the dynamic capability is needed. A framework for optimizing design of boilers for dynamic operation has been...... developed. Analyzing boilers for dynamic operation gives rise to a number of opposing aims: shrinking and swelling, steam quality, stress levels, control system/philosophy, pressurization etc. Common for these opposing aims is that an optimum can be found for selected operation conditions. The framework has...

  15. ENERGY STAR Certified Boilers

    Data.gov (United States)

    U.S. Environmental Protection Agency — Certified models meet all ENERGY STAR requirements as listed in the Version 3.0 ENERGY STAR Program Requirements for Boilers that are effective as of October 1,...

  16. Heat flux distribution on circulating fluidized bed boiler water wall

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    The future of circulating fluidized bed (CFB)combustion technology is in raising the steam parameters to supercritical levels.Understanding the heat flux distribution on the water wall is one of the most important issues in the design and operation of supercritical pressure CFB boilers.In the present paper,the finite element analysis (FEA) method is adopted to predict the heat transfer coefficient as well as the heat flux of the membrane wall and the results are validated by direct measurement of the temperature around the tube.Studies on the horizontal heat flux distribution were conducted in three CFB boilers with different furnace size,tube dimension and water temperature.The results are useful in supercritical pressure CFB boiler design.

  17. Ash particle erosion on steam boiler convective section

    Energy Technology Data Exchange (ETDEWEB)

    Meuronen, V.

    1997-12-31

    In this study, equations for the calculation of erosion wear caused by ash particles on convective heat exchanger tubes of steam boilers are presented. A new, three-dimensional test arrangement was used in the testing of the erosion wear of convective heat exchanger tubes of steam boilers. When using the sleeve-method, three different tube materials and three tube constructions could be tested. New results were obtained from the analyses. The main mechanisms of erosion wear phenomena and erosion wear as a function of collision conditions and material properties have been studied. Properties of fossil fuels have also been presented. When burning solid fuels, such as pulverized coal and peat in steam boilers, most of the ash is entrained by the flue gas in the furnace. In bubbling and circulating fluidized bed boilers, particle concentration in the flue gas is high because of bed material entrained in the flue gas. Hard particles, such as sharp edged quartz crystals, cause erosion wear when colliding on convective heat exchanger tubes and on the rear wall of the steam boiler. The most important ways to reduce erosion wear in steam boilers is to keep the velocity of the flue gas moderate and prevent channelling of the ash flow in a certain part of the cross section of the flue gas channel, especially near the back wall. One can do this by constructing the boiler with the following components. Screen plates can be used to make the velocity and ash flow distributions more even at the cross-section of the channel. Shield plates and plate type constructions in superheaters can also be used. Erosion testing was conducted with three types of tube constructions: a one tube row, an in- line tube bank with six tube rows, and a staggered tube bark with six tube rows. Three flow velocities and two particle concentrations were used in the tests, which were carried out at room temperature. Three particle materials were used: quartz, coal ash and peat ash particles. Mass loss

  18. Integrated boiler, superheater, and decomposer for sulfuric acid decomposition

    Science.gov (United States)

    Moore, Robert; Pickard, Paul S.; Parma, Jr., Edward J.; Vernon, Milton E.; Gelbard, Fred; Lenard, Roger X.

    2010-01-12

    A method and apparatus, constructed of ceramics and other corrosion resistant materials, for decomposing sulfuric acid into sulfur dioxide, oxygen and water using an integrated boiler, superheater, and decomposer unit comprising a bayonet-type, dual-tube, counter-flow heat exchanger with a catalytic insert and a central baffle to increase recuperation efficiency.

  19. PERFORMANCE EVALUATION OF BOILERS (80 AND 40 TPH AND 21MW STEAM TURBINE OF COGEN PLANT

    Directory of Open Access Journals (Sweden)

    D.P.TAWARE

    2014-06-01

    Full Text Available The proposed study is conducted at The Malegaon Sugar Mills, Baramati, and District Pune. Data is collected for a high pressure 80 TPH & 40TPH bagasse fired boiler. The boilers are natural circulation and bi-drum water tube type. The both boilers are equipped with super heater, air heater and economizer in order to utilize maximum available heat of flue gases. Boiler efficiency is calculated by indirect method. Also plant has 21 MW cogeneration capacity, with two turbines are installed with capacity 14MW (Back Pressure Type & 7MW (Extraction Cum Condensing Type. From the heat input given to turbines per unit of electricity generated, the turbine heat rate is calculated. Different instruments and devices are used to record the different parameters of both boilers & turbines. Steam produced per ton of bagasse is being found out for both boilers.

  20. A Flue Gas Tube for Thermoelectric Generator

    DEFF Research Database (Denmark)

    2013-01-01

    The invention relates to a flue gas tube (FGT) (1) for generation of thermoelectric power having thermoelectric elements (8) that are integrated in the tube. The FTG may be used in combined heat and power (CHP) system (13) to produce directly electricity from waste heat from, e.g. a biomass boiler...

  1. Developments and operational experience with ceramic boiler wall protection systems in fluidised bed boilers; Entwicklungen und Betriebserfahrungen mit keramischen Rohrwandschutzsystemen in der Wirbelschicht

    Energy Technology Data Exchange (ETDEWEB)

    Horn, Markus [Juenger + Graeter GmbH, Schwetzingen (Germany); Roschek, Dirk; Ipsen, Christoph [Stadtwerke Flensburg GmbH, Flensburg (Germany)

    2013-02-01

    More alternative fuels, such as biomass, refuse derived fuels, sewage sludge, meat and bone meal etc. are being used in conventional CFB power plants originally designed for coal combustion. However, co-combustion of these materials causes problems which are not always advantageous for continuous plant operation, i.e. mostly substantially higher fouling susceptibility of the plants was noticed. In some cases even a far greater tendency to boiler damage was observed as result of corrosion, erosion, and mechanical effects. Based on these constraints, the cooperation between Stadtwerke Flensburg and Juenger+Graeter (J+G) resulted in the development of a ceramic boiler wall protection system which would significantly reduce the susceptibility to boiler damage in the combustion chamber.

  2. Anti-fouling bioactive surfaces.

    Science.gov (United States)

    Yu, Qian; Zhang, Yanxia; Wang, Hongwei; Brash, John; Chen, Hong

    2011-04-01

    Bioactive surfaces refer to surfaces with immobilized bioactive molecules aimed specifically at promoting or supporting particular interactions. Such surfaces are of great importance for various biomedical and biomaterials applications. In the past few years, considerable effort has been made to create bioactive surfaces by forming specific biomolecule-modified surfaces on a non-biofouling "base" or "background". Hydrophilic and bioinert polymers have been widely used as anti-fouling layers that resist non-specific protein interactions. They can also serve as "spacers" to effectively move the immobilized biomolecule away from the surface, thus enhancing its bioactivity. In this review we summarize several successful approaches for the design and preparation of bioactive surfaces based on different types of anti-fouling/spacer materials. Some perspectives on future research in this area are also presented.

  3. Investigation of a twisted-tube type shell-and-tube heat exchanger

    OpenAIRE

    Danielsen, Sven Olaf

    2009-01-01

    This master thesis investigates twisted tube type shell-and-tube heat exchangers with emphasis on thermal-hydraulic characteristics, fouling and vibration properties. An extensive literature study has been carried out in order to map all published research reports written on the topic. The mapping of performed research shows that the available information is limited.Mathematical correlations for twisted tube thermal-hydraulic characteristics are extracted from the research reports found in th...

  4. MODELLING, SIMULATING AND OPTIMIZING BOILERS

    DEFF Research Database (Denmark)

    Sørensen, Kim; Condra, Thomas Joseph; Houbak, Niels

    2004-01-01

    on the boiler) have been dened. Furthermore a number of constraints related to: minimum and maximum boiler load gradient, minimum boiler size, Shrinking and Swelling and Steam Space Load have been dened. For dening the constraints related to the required boiler volume a dynamic model for simulating the boiler...... size. The model has been formulated with a specied building-up of the pressure during the start-up of the plant, i.e. the steam production during start-up of the boiler is output from the model. The steam outputs together with requirements with respect to steam space load have been utilized to dene...... of the boiler is (with an acceptable accuracy) proportional with the volume of the boiler. For the dynamic operation capability a cost function penalizing limited dynamic operation capability and vise-versa has been dened. The main idea is that it by mean of the parameters in this function is possible to t its...

  5. Biofuel Pilot at St. Juliens Creek and Proposed NAVFAC Policy on Use of Biofuel In Heating Boilers

    Science.gov (United States)

    2013-09-01

    Portsmouth. It is a “D”-type water-tube boiler with a capacity of 40,000 lbs steam per hour, which is approximately 8% less than what is considered...HEATING BOILERS Steven Guzinski Ray West Andy Gallagher Approved for public release; distribution is unlimited...NAVFAC POLICY ON USE OF BIOFUEL IN HEATING BOILERS 5b. GRANT NUMBER 5c. PROGRAM ELEMENT NUMBER 6. AUTHOR(S) 5d. PROJECT NUMBER

  6. Computational Modeling and Assessment Of Nanocoatings for Ultra Supercritical Boilers

    Energy Technology Data Exchange (ETDEWEB)

    Gandy, David W. [Electric Power Research Institute, Inc., Palo Alto, CA (United States); Shingledecker, John P. [Electric Power Research Institute, Inc., Palo Alto, CA (United States)

    2011-05-11

    Coal-fired power plants are a significant part of the nation's power generating capacity, currently accounting for more than 55% of the country's total electricity production. Extending the reliable lifetimes of fossil fired boiler components and reducing the maintenance costs are essential for economic operation of power plants. Corrosion and erosion are leading causes of superheater and reheater boiler tube failures leading to unscheduled costly outages. Several types of coatings and weld overlays have been used to extend the service life of boiler tubes; however, the protection afforded by such materials was limited approximately one to eight years. Power companies are more recently focused in achieving greater plant efficiency by increasing steam temperature and pressure into the advanced-ultrasupercritical (A-USC) condition with steam temperatures approaching 760°C (1400°F) and operating pressures in excess of 35MPa (5075 psig). Unfortunately, laboratory and field testing suggests that the resultant fireside environment when operating under A-USC conditions can potentially cause significant corrosion to conventional and advanced boiler materials1-2. In order to improve reliability and availability of fossil fired A-USC boilers, it is essential to develop advanced nanostructured coatings that provide excellent corrosion and erosion resistance without adversely affecting the other properties such as toughness and thermal fatigue strength of the component material.

  7. Compact exhaust gas boilers. Investigation of heat transfer and pressure drop for serrated finned tubes. (Abbreviated edition); Kompakte avgasskjeler. Undersoekelse av varmeovergang og trykktap for serraterte finnede roer. (Forkortet utgave.)

    Energy Technology Data Exchange (ETDEWEB)

    Midtbust, H.O.; Naess, E.

    1995-07-03

    This report discusses investigations of pressure drops and heat transfer in cross-current flow of gases (air) on bundles of serrated finned tubes. For the various geometries the tube spacing and tube diameter varied while the geometry of the fins remained unchanged. Pressure drop and heat transfer were measured at six different air flows for each geometry, and the results compared with available correlations from the literature. The measurements are at variance with the correlations and indicate that the pressure loss coefficient for all the tested geometries are less influenced by the flow conditions (air speed) than predicted by the correlations. Compared with the correlation recommended by the tube supplier (Weierman`s correlation) the measured results are mostly somewhat higher than predicted for the larger air flows. The maximum observed deviation is 70%. The deviation between the published pressure loss correlations is also considerable. The heat transfer measurements agree qualitatively with the published correlations with respect to the flow conditions. Comparison with the heat transfer correlation recommended by the tube supplier indicates that the correlation over-predicts the heat transfer quite considerably. The deviation increases systematically with reduced tube diameter and with increased angle of the tube arrangement. 16 figs., 7 tabs.

  8. The Modified Fouling Index Ultrafiltration constant flux for assessing particulate/colloidal fouling of RO systems

    NARCIS (Netherlands)

    Salinas-Rodriguez, S.G.; Amy, G.L.; Schippers, J.C.; Kennedy, M.D.

    2015-01-01

    Reliable methods for measuring and predicting the fouling potential of reverse osmosis (RO) feed water are important in preventing and diagnosing fouling at the design stage, and for monitoring pre-treatment performance during plant operation. The Modified Fouling Index Ultrafiltration (MFI-UF) cons

  9. On the design of residential condensing gas boilers

    Energy Technology Data Exchange (ETDEWEB)

    Naeslund, M.

    1997-02-01

    Two main topics are dealt with in this thesis. Firstly, the performance of condensing boilers with finned tube heat exchangers and premix burners is evaluated. Secondly, ways of avoiding condensate formation in the flue system are evaluated. In the first investigation, a transient heat transfer approach is used to predict performance of different boiler configurations connected to different heating systems. The smallest efficiency difference between heat loads and heating systems is obtained when the heat exchanger gives a small temperature difference between flue gases and return water, the heat transfer coefficient is low and the thermostat hysteresis is large. Taking into account heat exchanger size, the best boiler is one with higher heat transfer per unit area which only causes a small efficiency loss. The total heating cost at part load, including gas and electricity, has a maximum at the lowest simulated heat load. The heat supplied by the circulation heat pump is responsible for this. The second investigation evaluates methods of drying the flue gases. Reheating the flue gases in different ways and water removal in an adsorbent bed are evaluated. Reheating is tested in two specially designed boilers. The necessary reheating is calculated to approximately 100-150 deg C if an uninsulated masonry chimney is used. The tested boilers show that it is possible to design a proper boiler. The losses, stand-by and convective/radiative, must be kept at a minimum in order to obtain a high efficiency. 86 refs, 70 figs, 16 tabs

  10. Applied studies in advanced boiler technology for Rankine cycle power systems

    Energy Technology Data Exchange (ETDEWEB)

    Paul, F.W.; Negreanu, M.J.

    1978-02-01

    A study is presented on a new rotational boiler design which has improved passive dynamic response and two-phase flow stability characteristics. A survey of small boiler manufacturers in the United States indicated that currently available designs are based on steady-state operating requirements rather than for dynamic performance. Recent work by EPA and ERDA which addressed boiler designs for mobile automotive Rankine cycle power systems showed that boilers of a monotube or multipass tube configuration design could be developed which were physically compact, but still were subject to the two-phase flow instability problem when coupled within an operating power system. The objectives of this work were to evaluate alternative boiler configurations which would improve boiler dynamic response and also have good two-phase liquid-vapor interface flow stability. The major physical design limitation of any boiler is the small external hot gas heat transfer coefficient. Such a low coefficient requires considerable design enhancements to increase the rate of energy transfer to the circulation system fluid. The rotational boiler is a physical design configuration which addresses this problem. The results of an analytic study using several mathematical model formulations showed that a rotational boiler could have a passive response time constant which was approximately one-half the magnitude for an equivalent single pass monotube boiler. An experimental prototype rotational boiler was designed, manufactured and tested, with the experimental results confirming that the experimental passive response time constants were comparable to the estimates from the analytic models. The experimental boiler operating in two-phase flow was found to be stable and responsive to external inputs. A rotational boiler configuration is a good alternative design configuration for small compact vapor generator designs based on fast transient passive response and two-phase flow stability.

  11. Investigation into fouling factor in compact heat exchanger

    OpenAIRE

    Masoud Asadi; Ramin Haghighi Khoshkhoo

    2013-01-01

    Fouling problems cannot be avoided in many heat exchanger operations, and it is necessary to introduce defensive measures to minimize fouling and the cost of cleaning. The fouling control measures used during either design or operation must be subjected to a thorough economic analysis, taking into consideration all the costs of the fouling control measures and their projected benefits in reducing costs due to fouling. Under some conditions, nearly asymptotic fouling resistances can be obtaine...

  12. The causes for the leakage of DZL type boiler smoke tube bulge mouth and maintenance%DZL型锅炉烟管胀口泄漏的原因及维修

    Institute of Scientific and Technical Information of China (English)

    李杰; 郭建新; 王儒瑞

    2014-01-01

    本文主要探讨在高温烟气中,锅炉的某些高温原件将与烟气中的氧发生氧化反应,生成氧化膜,如果氧化膜不能紧密地包覆在钢材表面而发生脱落,则氧化现象将不断发展,导致的破坏。对修理预防,防止蒸汽锅炉事故有着一定的现实意义。%This article mainly discusses in high temperature flue gas,original some of boiler high temperature oxidizing reaction with the oxygen in flue gas,generated oxide film,if oxidation film can't closely coated on the surface of steel and fall off,the oxidation phenomenon will continuously development,lead to destruction.For repair prevention, prevent accident of steam boiler has a certain practical significance..

  13. Development of Self-Powered Wireless-Ready High Temperature Electrochemical Sensors for In-Situ Corrosion Monitoring for Boiler Tubes in Next Generation Coal-based Power Systems

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Xingbo [West Virginia Univ., Morgantown, WV (United States)

    2015-06-30

    The key innovation of this project is the synergy of the high temperature sensor technology based on the science of electrochemical measurement and state-of-the-art wireless communication technology. A novel self-powered wireless high temperature electrochemical sensor system has been developed for coal-fired boilers used for power generation. An initial prototype of the in-situ sensor demonstrated the capability of the wireless communication system in the laboratory and in a pilot plant (Industrial USC Boiler Setting) environment to acquire electrochemical potential and current signals during the corrosion process. Uniform and localized under-coal ash deposit corrosion behavior of Inconel 740 superalloy has been studied at different simulated coal ash hot corrosion environments using the developed sensor. Two typical potential noise patterns were found to correlate with the oxidation and sulfidation stages in the hot coal ash corrosion process. Two characteristic current noise patterns indicate the extent of the corrosion. There was a good correlation between the responses of electrochemical test data and the results from corroded surface analysis. Wireless electrochemical potential and current noise signals from a simulated coal ash hot corrosion process were concurrently transmitted and recorded. The results from the performance evaluation of the sensor confirm a high accuracy in the thermodynamic and kinetic response represented by the electrochemical noise and impedance test data.

  14. EVALUASI KINERJA HEAT EXCHANGER DENGAN METODE FOULING F

    Directory of Open Access Journals (Sweden)

    Bambang Setyoko

    2012-02-01

    Full Text Available The performance of heat exchangers usually deteriorates with time as a result of accumulation of depositson heat transfer surfaces. The layer of deposits represents additional resistance to heat transfer and causesthe rate of heat transfer in a heat exchanger to decrease. The net effect of these accumulations on heattransfer is represented by a fouling factor Rf , which is a measure of the thermal resistance introduced byfouling.In this case, the type of fouling is the precipitation of solid deposits in a fluid on the heat transfer surface.The mineral deposits forming on the inner and the outer surfaces of fine tubes in the heat exchanger. Thefouling factor is increases with time as the solid deposits build up on the heat exchanger surface. Foulingincreases with increasing temperature and decreasing velocity.In this research, we obtain the coefisien clean overal 5,93 BTU/h.ft2.oF, Dirt factor 0,004 BTU/h.ft2 0F,Pressure drope in tube 2,84 . 10-3 Psi and pressure drope in shell 4,93 . 10-4 Psi.This result are less thanthe standard of parameter. Its means this Heat exchanger still clean relativity and can operate continousslywithout cleaning.

  15. Oil shale fueled FBC power plant - ash deposits and fouling problems

    Energy Technology Data Exchange (ETDEWEB)

    O. Yoffe; A. Wohlfarth; Y. Nathan; S. Cohen; T. Minster [Geological Survey of Israel, Jerusalem (Israel)

    2007-12-15

    41 MWth oil shale fired demonstration power plant was built in 1989 by PAMA in Mishor Rotem, Negev, Israel. The raw material for the plant is the local 'oil shale', which is in fact organic-rich marl. Since then, and until today, the unit is operated at high reliability and availability. At first, heavy soft fouling occurred due to the Circulating Fluidized Bed Combustion (CFBC) mode of operation, which caused a considerable reduction in the heat transfer coefficient of the heat exchangers. By going over to the Fluidized Bed Combustion (FBC) mode of operation the soft fouling phenomenon stopped at once, the heat transfer coefficient improved, and the power plant could be operated at its designed values. After five months of operation at the FBC mode the boiler had to be shut down because Hard Deposits (HD) blocked physically the passes in the boiler. These deposits could be removed only with the help of mechanical devices. During the first two years the boiler had to be stopped, at least, three times a year for deposit cleaning purposes. Research conducted at the plant and in the laboratories of the Geological Survey of Israel enabled us to understand the mechanism of formation of these deposits. The results showed that the HD are formed in two stages: (1) Deposition of very fine ash particles on the pipes of the boiler, as a result of the impact of larger particles on the pipes. The fine particles adhere to the pipes and to each other, and step by step build the deposit. The growth of the deposit on the pipe surface is always perpendicular to the particles flow direction. (2) The deposits harden due to chemical reactions. 17 refs., 14 figs., 5 tabs.

  16. Influence of Heat Flux and Friction Coefficient on Thermal Stresses in Risers of Drum Boilers under Dynamic Conditions of Steam Demand

    Directory of Open Access Journals (Sweden)

    M. A. Habib

    2013-01-01

    Full Text Available Boiler swing rate, which is the rate at which the boiler load is changed, has significant influence on the parameters of the boiler operating conditions such as drum water pressure and level, steam quality in the riser tubes, wall temperatures of riser tubes, and the associated thermal stresses. In this paper, the thermal stresses developed in boiler tubes due to elevated rates of heat transfer and friction are presented versus thermal stresses developed in tubes operated under normal conditions. The differential equations comprising the nonlinear model and governing the flow inside the boiler tubes were formulated to study different operational scenarios in terms of resulting dynamic response of critical variables. The experimental results and field data were obtained to validate the present nonlinear dynamic model. The calculations of the heat flux and the allowable steam quality were used to determine the maximum boiler swing rates at different conditions of riser tube of friction factor and heat flux. Diagrams for the influence of friction factor of the boiler tubes and the heat flux, that the tube is subjected to, on the maximum swing rate were examined.

  17. Optimising boiler performance.

    Science.gov (United States)

    Mayoh, Paul

    2009-01-01

    Soaring fuel costs continue to put the squeeze on already tight health service budgets. Yet it is estimated that combining established good practice with improved technologies could save between 10% and 30% of fuel costs for boilers. Paul Mayoh, UK technical manager at Spirax Sarco, examines some of the practical measures that healthcare organisations can take to gain their share of these potential savings.

  18. Design of Boiler Welding for Improvement of Lifetime and Cost Control

    Directory of Open Access Journals (Sweden)

    Atcharawadi Thong-On

    2016-11-01

    Full Text Available Fe-2.25Cr-1Mo a widely used material for headers and steam tubes of boilers. Welding of steam tube to header is required for production of boiler. Heat affected zone of the weld can have poor mechanical properties and poor corrosion behavior leading to weld failure. The cost of material used for steam tube and header of boiler should be controlled. This study propose a new materials design for boiler welding to improve the lifetime and cost control, using tungsten inert gas (TIG welding of Fe-2.25Cr-1Mo tube to carbon steel pipe with chromium-containing filler. The cost of production could be reduced by the use of low cost material such as carbon steel pipe for boiler header. The effect of chromium content on corrosion behavior of the weld was greater than that of the microstructure. The lifetime of the welded boiler can be increased by improvement of mechanical properties and corrosion behavior of the heat affected zone.

  19. Offshore fouling:investigation methods

    Institute of Scientific and Technical Information of China (English)

    YAN Tao; YAN Wenxia; DONG Yu; LIANG Guanhe; YAN Yan; WANG Huajie

    2004-01-01

    On the hasis of the reason that the offshore oil development areas in the northern South China Sea are at greater depth,more hazardous conditions and distance from shore, the methods and technologies used in coastal waters are not feasible because of the higher risk of losing investigation equipment or facilities. A series of methods and technologies for offshore fouling investigation that have been successfully applied is given in detail and it is hoped that the experience can be helpful for further studies.

  20. Optimization of Load Assignment to Boilers in Industrial Boiler Plants

    Institute of Scientific and Technical Information of China (English)

    CAO Jia-cong; QIU Guang; CAO Shuang-hua; LIU Feng-qiang

    2004-01-01

    Along with the increasing importance of sustainable energy, the optimization of load assignment to boilers in an industrial boiler plant becomes one of the major projects for the optimal operation of boiler plants. Optimal load assignment for power systems has been a long-lasting subject, while it is quite new for industrial boiler plants. The existing methods of optimal load assignment for boiler plants are explained and analyzed briefly in the paper. They all need the fuel cost curves of boilers. Thanks to some special features of the curves for industrial boilers, a new model referred to as minimized departure model (MDM) of optimization of load assignment for boiler plants is developed and proposed in the paper. It merely relies upon the accessible data of two typical working conditions to build the model, viz. the working conditions with the highest efficiency of a boiler and with no-load. Explanation of the algorithm of computer program is given, and effort is made so as to determine in advance how many and which boilers are going to work. Comparison between the results using MDM and the results reported in references is carried out, which proves that MDM is preferable and practicable.

  1. Superheater corrosion in kraft recovery boilers; Korrosion hos oeverhettare i sodapannor. En oeversikt och diskussion

    Energy Technology Data Exchange (ETDEWEB)

    Bruno, F. [AaF-IPK, Stockholm (Sweden)

    1997-02-01

    Corrosion seems to be the most essential factor limiting the life and the availability of kraft recovery boilers. The steam temperature from the kraft recovery boiler has, seen from the view of electricity production and steam turbine operation, traditionally been kept moderate, especially in comparison with steam data from normal utility power plants. So the corrosion of the superheaters has been more a limitation for the temperature of the steam produced by the boiler than a life length limitation. Both the pressure and the temperature of the steam are limited by corrosion. The temperature of the boiling water, and hence the pressure, is limited by the corrosion in the lower furnace. The temperature of the steam is limited by the corrosion in the superheater. Kraft boiler superheater corrosion is here governed not only by the boiler design, but more by the mill chemistry and boiler operation practice. This report discusses the formation and the properties of the deposits and their relation to boiler operation and the corrosion of the superheater tube material. We have tried to understand the corrosion in the kraft boiler superheaters better by comparing with the experience from the utility boilers. 86 refs, 79 figs

  2. Reliability Based Management of Marine Fouling

    DEFF Research Database (Denmark)

    Faber, Michael Havbro; Hansen, Peter Friis

    1999-01-01

    of uncertainties of a set of parameters. These are the seasonal variation of marine fouling parameters, the wave loading (taking into account the seasonal variation in sea-state statistics), and the effects of spatial variations and seasonal effects of marine fouling parameters. Comparison of design values...... obtained by the present model taking into account seasonal effects with those inherent in the current design specifications are made and criteria are formulated for removal of marine fouling taking into account seasonal differences in marine fouling. A methodology is outlined on how to establish new......The present paper describes the results of a recent study on the application of methods from structural reliability to optimise management of marine fouling on jacket type structures.In particular the study addresses effects on the structural response by assessment and quantification...

  3. An experimental study on the thermal and fouling characteristics in a washable shell and helically coiled heat exchanger by the Wilson plot method

    Energy Technology Data Exchange (ETDEWEB)

    Koo, Kyoung Min; Ahn, Young Chull [Pusan National University, Busan (Korea, Republic of); Hwang, Jun Hyeon; Hur, Hyun; Na, Byung Chul; Hwang, Yoon Jae; Kim, Byung Soon [LG Electronics, Changwon (Korea, Republic of); Lee, Jae Keun [EcoEnergy Research Institute, Busan (Korea, Republic of)

    2016-06-15

    Brazed plate heat exchangers (BPHEX) are broadly used in water source heat pump systems for their large heat transfer capacity. Despite their high heat transfer rate, their high-performance rate tends to decrease sharply, due to fouling and they cannot be cleaned. So the thermal and fouling resistances of washable Shell and helically coiled tube heat exchangers (SCHEX) are designed and experimentally investigated in this study. Heat exchangers with two different tube types are studied and compared with a brazed plate heat exchanger. The overall thermal resistance coefficient of the heat exchangers as determined by using Wilson plots is 38% lower than that of the brazed plate heat exchanger at a Reynolds number of 2460. Fouling test results revealed that regular maintenance and physical cleaning can be used to maintain the thermal resistance of fouling of the washable heat exchanger at a level equal to or less than that of the brazed plate heat exchanger.

  4. NOx Control Options and Integration for US Coal Fired Boilers

    Energy Technology Data Exchange (ETDEWEB)

    Mike Bockelie; Kevin Davis; Temi Linjewile; Connie Senior; Eric Eddings; Kevin Whitty; Larry Baxter; Calvin Bartholomew; William Hecker; Stan Harding

    2004-03-31

    This is the fifteenth Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. At AEP's Gavin Plant, data from the corrosion probes showed that corrosion rate increased as boiler load was increased. During an outage at the plant, the drop in boiler load, sensor temperature and corrosion rate could all be seen clearly. Restarting the boiler saw a resumption of corrosion activity. This behavior is consistent with previous observations made at a 600MWe utility boiler. More data are currently being examined for magnitudes of corrosion rates and changes in boiler operating conditions. Considerable progress was made this quarter in BYU's laboratory study of catalyst deactivation. Surface sulfation appears to partially suppress NO adsorption when the catalyst is not exposed to NH3; NH3 displaces surface-adsorbed NO on SCR catalysts and surface sulfation increases the amount of adsorbed NH3, as confirmed by both spectroscopy and TPD experiments. However, there is no indication of changes in catalyst activity despite changes in the amount of adsorbed NH3. A monolith test reactor (MTR), completed this quarter, provided the first comparative data for one of the fresh and field-exposed monolith SCR catalysts yet developed in this project. Measurements of activity on one of the field-exposed commercial monolith catalysts do not show significant changes in catalyst activity (within experimental error) as compared to the fresh catalyst. The exposed surface of the sample contains large amounts of Ca and Na, neither of which is present in the fresh sample, even after removal of visibly obvious fouling deposits. However, these fouling compounds do

  5. System for measuring the effect of fouling and corrosion on heat transfer under simulated OTEC conditions. [HTAU and LABTTF codes

    Energy Technology Data Exchange (ETDEWEB)

    Fetkovich, J.G.

    1976-12-01

    A complete system designed to measure, with high precision, changes in heat transfer rates due to fouling and corrosion of simulated heat exchanger tubes, at sea and under OTEC conditions is described. All aspects of the system are described in detail, including theory, mechanical design, electronics design, assembly procedures, test and calibration, operating procedures, laboratory results, field results, and data analysis programs.

  6. Fouling distribution in forward osmosis membrane process.

    Science.gov (United States)

    Lee, Junseok; Kim, Bongchul; Hong, Seungkwan

    2014-06-01

    Fouling behavior along the length of membrane module was systematically investigated by performing simple modeling and lab-scale experiments of forward osmosis (FO) membrane process. The flux distribution model developed in this study showed a good agreement with experimental results, validating the robustness of the model. This model demonstrated, as expected, that the permeate flux decreased along the membrane channel due to decreasing osmotic pressure differential across the FO membrane. A series of fouling experiments were conducted under the draw and feed solutions at various recoveries simulated by the model. The simulated fouling experiments revealed that higher organic (alginate) fouling and thus more flux decline were observed at the last section of a membrane channel, as foulants in feed solution became more concentrated. Furthermore, the water flux in FO process declined more severely as the recovery increased due to more foulants transported to membrane surface with elevated solute concentrations at higher recovery, which created favorable solution environments for organic adsorption. The fouling reversibility also decreased at the last section of the membrane channel, suggesting that fouling distribution on FO membrane along the module should be carefully examined to improve overall cleaning efficiency. Lastly, it was found that such fouling distribution observed with co-current flow operation became less pronounced in counter-current flow operation of FO membrane process.

  7. Optimisation of Marine Boilers using Model-based Multivariable Control

    DEFF Research Database (Denmark)

    Solberg, Brian

    Traditionally, marine boilers have been controlled using classical single loop controllers. To optimise marine boiler performance, reduce new installation time and minimise the physical dimensions of these large steel constructions, a more comprehensive and coherent control strategy is needed. Th......). In the thesis the pressure control is based on this new method when on/off burner switching is required while the water level control is handled by a model predictive controller........ This research deals with the application of advanced control to a specific class of marine boilers combining well-known design methods for multivariable systems. This thesis presents contributions for modelling and control of the one-pass smoke tube marine boilers as well as for hybrid systems control. Much...... of the focus has been directed towards water level control which is complicated by the nature of the disturbances acting on the system as well as by low frequency sensor noise. This focus was motivated by an estimated large potential to minimise the boiler geometry by reducing water level fluctuations...

  8. High-Temperature Graphitization Failure of Primary Superheater Tube

    Science.gov (United States)

    Ghosh, D.; Ray, S.; Roy, H.; Mandal, N.; Shukla, A. K.

    2015-12-01

    Failure of boiler tubes is the main cause of unit outages of the plant, which further affects the reliability, availability and safety of the unit. So failure analysis of boiler tubes is absolutely essential to predict the root cause of the failure and the steps are taken for future remedial action to prevent the failure in near future. This paper investigates the probable cause/causes of failure of the primary superheater tube in a thermal power plant boiler. Visual inspection, dimensional measurement, chemical analysis, metallographic examination and hardness measurement are conducted as the part of the investigative studies. Apart from these tests, mechanical testing and fractographic analysis are also conducted as supplements. Finally, it is concluded that the superheater tube is failed due to graphitization for prolonged exposure of the tube at higher temperature.

  9. DOWNSCALE APPLICATION OF BOILER THERMAL CALCULATION APPROACH

    OpenAIRE

    Zelený, Zbynĕk; Hrdlička, Jan

    2016-01-01

    Commonly used thermal calculation methods are intended primarily for large scale boilers. Hot water small scale boilers, which are commonly used for home heating have many specifics, that distinguish them from large scale boilers especially steam boilers. This paper is focused on application of thermal calculation procedure that is designed for large scale boilers, on a small scale boiler for biomass combustion of load capacity 25 kW. Special issue solved here is influence of formation of dep...

  10. Super Boiler 2nd Generation Technology for Watertube Boilers

    Energy Technology Data Exchange (ETDEWEB)

    Mr. David Cygan; Dr. Joseph Rabovitser

    2012-03-31

    This report describes Phase I of a proposed two phase project to develop and demonstrate an advanced industrial watertube boiler system with the capability of reaching 94% (HHV) fuel-to-steam efficiency and emissions below 2 ppmv NOx, 2 ppmv CO, and 1 ppmv VOC on natural gas fuel. The boiler design would have the capability to produce >1500 F, >1500 psig superheated steam, burn multiple fuels, and will be 50% smaller/lighter than currently available watertube boilers of similar capacity. This project is built upon the successful Super Boiler project at GTI. In that project that employed a unique two-staged intercooled combustion system and an innovative heat recovery system to reduce NOx to below 5 ppmv and demonstrated fuel-to-steam efficiency of 94% (HHV). This project was carried out under the leadership of GTI with project partners Cleaver-Brooks, Inc., Nebraska Boiler, a Division of Cleaver-Brooks, and Media and Process Technology Inc., and project advisors Georgia Institute of Technology, Alstom Power Inc., Pacific Northwest National Laboratory and Oak Ridge National Laboratory. Phase I of efforts focused on developing 2nd generation boiler concepts and performance modeling; incorporating multi-fuel (natural gas and oil) capabilities; assessing heat recovery, heat transfer and steam superheating approaches; and developing the overall conceptual engineering boiler design. Based on our analysis, the 2nd generation Industrial Watertube Boiler when developed and commercialized, could potentially save 265 trillion Btu and $1.6 billion in fuel costs across U.S. industry through increased efficiency. Its ultra-clean combustion could eliminate 57,000 tons of NOx, 460,000 tons of CO, and 8.8 million tons of CO2 annually from the atmosphere. Reduction in boiler size will bring cost-effective package boilers into a size range previously dominated by more expensive field-erected boilers, benefiting manufacturers and end users through lower capital costs.

  11. Fouling and Antifouling of Depetanizer in Ethylene Units

    Institute of Scientific and Technical Information of China (English)

    Dong Zhongjie; Li Yunlong; Fan Xuezhi; Hong Qingyao

    2002-01-01

    Factors affecting fouling of depentanizer in ethylene units wereexplored through study of thecomposition of pyrolysis gasoline, C5 distillate and fouling deposits from the depentanizer while takinginto consideration the processing parameters. A variety of antifouling measures, in particular the injec-tion of a special anti-fouling agent into the Cs gas phase pipeline and the C5 distillate reflux pipelinewere introduced. Commercial evaluation test of a multifunctional anti-fouling agent, the RIPP-1404anti-fouling agent, was also described.

  12. Microbial Relevant Fouling in Membrane Bioreactors: Influencing Factors, Characterization, and Fouling Control

    OpenAIRE

    Anthony G. Fane; Bing Wu

    2012-01-01

    Microorganisms in membrane bioreactors (MBRs) play important roles on degradation of organic/inorganic substances in wastewaters, while microbial deposition/growth and microbial product accumulation on membranes potentially induce membrane fouling. Generally, there is a need to characterize membrane foulants and to determine their relations to the evolution of membrane fouling in order to identify a suitable fouling control approach in MBRs. This review summarized the factors in MBRs that inf...

  13. A review on biomass as a fuel for boilers

    Energy Technology Data Exchange (ETDEWEB)

    Saidur, R.; Abelaziz, E.A.; Demirbas, A.; Hossain, M.S.; Mekhilef, S. [University of Malaya, Kuala Lumpur (Malaysia). Dept. of Mechanical Engineering

    2011-06-15

    Currently, fossil fuels such as oil, coal and natural gas represent the prime energy sources in the world. However, it is anticipated that these sources of energy will deplete within the next 40-50 years. Moreover, the expected environmental damages such as the global warming, acid rain and urban smog due to the production of emissions from these sources have tempted the world to try to reduce carbon emissions by 80% and shift towards utilizing a variety of renewable energy resources (RES) which are less environmentally harmful such as solar, wind, biomass etc. in a sustainable way. Biomass is one of the earliest sources of energy with very specific properties. In this review, several aspects which are associated with burning biomass in boilers have been investigated such as composition of biomass, estimating the higher heating value of biomass, comparison between biomass and other fuels, combustion of biomass, co-firing of biomass and coal, impacts of biomass, economic and social analysis of biomass, transportation of biomass, densification of biomass, problems of biomass and future of biomass. It has been found that utilizing biomass in boilers offers many economical, social and environmental benefits such as financial net saving, conservation of fossil fuel resources, job opportunities creation and CO{sub 2} and NO emissions reduction. However, care should be taken to other environmental impacts of biomass such as land and water resources, soil erosion, loss of biodiversity and deforestation. Fouling, marketing, low heating value, storage and collections and handling are all associated problems when burning biomass in boilers. The future of biomass in boilers depends upon the development of the markets for fossil fuels and on policy decisions regarding the biomass market.

  14. Amphiphilic copolymers for fouling-release coatings

    DEFF Research Database (Denmark)

    Noguer, Albert Camós; Olsen, Stefan Møller; Hvilsted, Søren

    Polydimethylsiloxane (PDMS) resins are extensively used as binder in fouling-release coatings due to the low critical surface energy and low elastic modulus of PDMS. These properties result in poor adhesion of the fouling organisms, which are therefore detached by hydrodynamic forces during...... navigation [1,2,3]. Other compounds are usually mixed together with the binder (e.g. silica and pigments) in order to improve the mechanical, thixotropic and visual properties of the coatings. It has ben shown, however, that these ingredients have a negative effect on the fouling-release properties...... of the coatings [1,2,4]. Together with the PDMS-system, non-reactive polymers have been used to improve the fouling-release properties of the coatings. Initially, hydrophobic siloxane-based polymers were used, which aimed to increase the hydrophobicity of the PDMS surface [5,6]. However, copolymers comprising...

  15. Amphiphilic copolymers for fouling-release coatings

    OpenAIRE

    Noguer, Albert Camós; Olsen, Stefan Møller; Hvilsted, Søren; Kiil, Søren

    2016-01-01

    Polydimethylsiloxane (PDMS) resins are extensively used as binder in fouling-release coatings due to the low critical surface energy and low elastic modulus of PDMS. These properties result in poor adhesion of the fouling organisms, which are therefore detached by hydrodynamic forces during navigation [1,2,3]. Other compounds are usually mixed together with the binder (e.g. silica and pigments) in order to improve the mechanical, thixotropic and visual properties of the coatings. It has ben s...

  16. The recovery boiler advisor. Combination of practical experience and advanced thermodynamic modelling

    Energy Technology Data Exchange (ETDEWEB)

    Backman, R. [Aabo Akademi, Turku (Finland); Eriksson, G. [LTH/RWTH (Germany); Sundstroem, K. [Tampella Power Oy, Tampere (Finland)

    1996-12-31

    The Aabo Advisor is a computer based program intended to provide information about the high temperature ash and fluegas chemistry in pulping spent black liquor recovery boilers of kraft pulp mills. The program can be used for predictions of a variety of furnace and flue gas phenomena, such as fireside fouling of the heat exchanger surfaces caused by the flue gas particulate matter, emissions of SO{sub 2}(g), HCl(g) and NO{sub x}(g) with the flue gas etc. The program determines the composition of the fluegas as well as the amount and composition of the two typical fly ash fractions found in recovery boiler fluegases, the condensed fly ash particles and the carry over particles. These data are used for calculating the melting behavior of the fly ash present at different locations in the boiler and this characteristic behavior is used for the fireside fouling predictions. The program may also be used for studying how different mill processes affecting the black liquor composition affects on the fireside chemistry of the recovery boiler. As input data for the calculations only a few boiler operation parameters and the composition of the black liquor is required. The calculations are based on a one-dimensional, multi-stage chemistry model where both thermodynamic equilibrium calculations and stoichiometric material balances are used. The model calculates at first the chemistry in the lower furnace and smelt after which it moves to the upper furnace and the radiative parts of the fluegas channel. As the last block the program calculates the chemistry in the convective part, the electrostatic precipitator cath and stack. The results from each block are presented in tables, key numbers and melt curves representing the fluegas or fly ash fraction present at each location

  17. Boiler design for fuel economy

    Energy Technology Data Exchange (ETDEWEB)

    Ramaswamy, M.P.; Sastry, C.V.R.L.; Tharakraj, M.

    1980-03-01

    In view of the limited fuel resources and ever increasing demand, Bharat Heavy Electricals, Ltd. (BHEL), as the leading boiler manufacturer, always endeavours to effect fuel economy in all possible avenues, leaving no stone unturned in this effort. This paper outlines some of the major efforts of BHEL in the area of boiler design to effect fuel economy.

  18. Boiler for ships; Hakuyo boira

    Energy Technology Data Exchange (ETDEWEB)

    Shimoda, F. [Mitsubishi Heavy Industries, Ltd., Tokyo (Japan)

    1999-07-20

    In this paper, production and technology trend of boiler for ships in 1998 are described. The actual results of main boiler are as follows. As the main boiler for LNG ships, 4 boilers produced by Mitsui Engineering and Shipbuilding for Qatar Project, 8 produced by Kawasaki Heavy Industries for South Korea and 10 produced by Mitsubishi Heavy Industries for domestic use and South Korea. 1998 was an active year for the main boiler for ships. The auxiliary boiler of steam pressure of 16k to 25k equipping for tanker ships was 115 (4,441t/h of steam quantity in total), it greatly increased in comparison with 88 (3,172t/h) produced in the proceeding year. Donkey boilers of steam pressure of 6k to 10k equipping for container ships and bulk cargo was 147 (672t/h), and it substantially decreased in comparison with 274 (693t/h) of the proceeding year, but capacity per boiler increased. The gas exhaust economizer for turbo power generation plants was 6 produced for VLCC. (NEDO)

  19. Boilers a practical reference

    CERN Document Server

    Rayaprolu, Kumar

    2012-01-01

    AAbrasion and Abrasion Index (see Wear)Absolute or Dynamic Viscosity (æ) (see Viscosity in Fluid Characteristics)Acid Cleaning (see Commissioning)Acid Rain (also see Air Pollution Emissions and Controls and Gas Cleaning)Acid Sludge (see Refuse Fuels from Refinery in Liquid Fuels)Acid Smuts (see Oil Ash)Acoustic Soot Blowers (see Sonic Horns)Acoustic Enclosure (see Noise Control)Acoustic Leak Detection SystemAdiabatic Flame Temperature (see Combustion)Aeroderivative (see Types of GTs in Turbines, Gas)Ageing of Boiler ComponentsAgro-Fuels and FiringAir Ducts (see Draught Plant)Air Flow Measureme

  20. Pellet wood gasification boiler / Combination boiler. Market review. 7. ed.; Scheitholzvergaser-/Kombikessel. Marktuebersicht

    Energy Technology Data Exchange (ETDEWEB)

    Uth, Joern

    2010-08-15

    In the market review under consideration on pellet wood gasification boilers and combination boilers, the Federal Ministry of Food, Agriculture and Consumer Protection (Bonn, Federal Republic of Germany) report on planning and installation of wood-fired heating systems, recommendations regarding to the technical assessment of boiler systems, buffers/combination boilers, prices of pellet wood gasification boilers, data sheets of the compared pellet wood gasification boilers, pellet wood combination boilers, prices of pellet wood combination boilers, data sheets of the compared pellet wood gasification boilers, list of providers.

  1. Market review. Pellet wood gasification boiler / combination boiler. 8. ed.; Marktuebersicht. Scheitholzvergaser-/Kombikessel

    Energy Technology Data Exchange (ETDEWEB)

    Uth, Joern

    2012-01-15

    In the market review under consideration on pellet wood gasification boilers and combination boilers, the Federal Ministry of Food, Agriculture and Consumer Protection (Bonn, Federal Republic of Germany) reports on planning and installation of wood-fired heating systems, recommendations regarding to the technical assessment of boiler systems, buffers/combination boilers, prices of pellet wood gasification boilers, data sheets of the compared pellet wood gasification boilers, pellet wood combination boilers, prices of pellet wood combination boilers, data sheets of the compared pellet wood gasification boilers, list of providers.

  2. Increased algal fouling on mussels with barnacle epibionts: a fouling cascade

    Science.gov (United States)

    Gutiérrez, Jorge L.; Palomo, M. Gabriela

    2016-06-01

    If the external surfaces of epibionts are more suitable to other fouling species than those of their basibionts, a 'fouling cascade' might occur where epibionts facilitate secondary colonization by other epibionts. Here we evaluate whether the presence of epibiotic barnalces (Balanus glandula) influences the probability of mussel (Brachidontes rodriguezii) fouling by ephemeral red algae (Porphyra sp.) in a Southwestern Atlantic rocky shore. Mussels with barnacle epibionts showed a higher prevalence of Porphyra sp. fouling (32-40% depending on sampling date) than mussels without them (3-7%). Two lines of evidence indicate that barnacles facilitate Porphyra sp. fouling. First, most Porphyra sp. thalli in mussels with barnacle epibionts were attached to barnacle shells (75-92% of cases). Secondly, Porphyra sp. associated with mussels with barnacle epibionts in a proportion that significantly exceeded that expected under random co-occurrence. These results suggest the occurrence of a fouling cascade where barnacle epibiosis on mussels facilitates subsequent algal fouling. Recognizing the occurrence of such fouling cascades is important because they might explain the non-random aggregation of multiple epibiotic species onto a proportionally few individuals of the host species.

  3. Erosion–corrosion behaviour of Ni-based superalloy Superni-75 in the real service environment of the boiler

    Indian Academy of Sciences (India)

    T S Sidhu; S Prakash; R D Agrawal; Ramesh Bhagat

    2009-04-01

    The super-heater and re-heater tubes of the boilers used in thermal power plants are subjected to unacceptable levels of surface degradation by the combined effect of erosion–corrosion mechanism, resulting in the tube wall thinning and premature failure. The nickel-based superalloys can be used as boiler tube materials to increase the service life of the boilers, especially for the new generation tra-supercritical boilers. The aim of the present investigation is to evaluate the erosion–corrosion behaviour of Ni-based superalloy Superni-75 in the real service environment of the coal-fired boiler of a thermal power plant. The cyclic experimental study was performed for 1000 h in the platen superheater zone of the coal-fired boiler where the temperature was around 900°C. The corrosion products have been characterized with respect to surface morphology, phase composition and element concentration using the combined techniques of X-ray diffractometry (XRD), scanning electron microscopy/energy-dispersive analysis (SEM/EDAX) and electron probe micro analyser (EPMA). The Superni-75 performed well in the coal-fired boiler environment, which has been attributed mainly to the formation of a thick band of chromium in scale due to selective oxidation of the chromium.

  4. Erosion-corrosion behaviour of Ni-based superalloy Superni-75 in the real service environment of the boiler

    Energy Technology Data Exchange (ETDEWEB)

    Sidhu, T.S.; Prakash, S.; Agrawal, R.D.; Bhagat, R. [Shaheed Bhagat Singh College of Engineering & Technology, Ferozepur (India)

    2009-04-15

    The super-heater and re-heater tubes of the boilers used in thermal power plants are subjected to unacceptable levels of surface degradation by the combined effect of erosion-corrosion mechanism, resulting in the tube wall thinning and premature failure. The nickel-based superalloys can be used as boiler tube materials to increase the service life of the boilers, especially for the new generation ultra-supercritical boilers. The aim of the present investigation is to evaluate the erosion-corrosion behaviour of Ni-based superalloy Superni-75 in the real service environment of the coal-fired boiler of a thermal power plant. The cyclic experimental study was performed for 1000 h in the platen superheater zone of the coal-fired boiler where the temperature was around 900{sup o}C. The corrosion products have been characterized with respect to surface morphology, phase composition and element concentration using the combined techniques of X-ray diffractometry (XRD), scanning electron microscopy/energy-dispersive analysis (SEM/EDAX) and electron probe micro analyser (EPMA). The Superni-75 performed well in the coal-fired boiler environment, which has been attributed mainly to the formation of a thick band of chromium in scale due to selective oxidation of the chromium.

  5. 30 CFR 77.413 - Boilers.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Boilers. 77.413 Section 77.413 Mineral... Mechanical Equipment § 77.413 Boilers. (a) Boilers shall be equipped with guarded, well-maintained water... the gages shall be kept clean and free of scale and rust. (b) Boilers shall be equipped with...

  6. 29 CFR 1915.162 - Ship's boilers.

    Science.gov (United States)

    2010-07-01

    ... 29 Labor 7 2010-07-01 2010-07-01 false Ship's boilers. 1915.162 Section 1915.162 Labor Regulations... Ship's boilers. (a) Before work is performed in the fire, steam, or water spaces of a boiler where... dead boiler with the live system or systems shall be secured, blanked, and tagged indicating...

  7. 49 CFR 230.47 - Boiler number.

    Science.gov (United States)

    2010-10-01

    ... 49 Transportation 4 2010-10-01 2010-10-01 false Boiler number. 230.47 Section 230.47..., DEPARTMENT OF TRANSPORTATION STEAM LOCOMOTIVE INSPECTION AND MAINTENANCE STANDARDS Boilers and Appurtenances Steam Gauges § 230.47 Boiler number. (a) Generally. The builder's number of the boiler, if known,...

  8. 46 CFR 61.05-10 - Boilers in service.

    Science.gov (United States)

    2010-10-01

    ... INSPECTIONS Tests and Inspections of Boilers § 61.05-10 Boilers in service. (a) Each boiler, including superheater, reheater, economizer, auxiliary boiler, low-pressure heating boiler, and unfired steam boiler... 46 Shipping 2 2010-10-01 2010-10-01 false Boilers in service. 61.05-10 Section 61.05-10...

  9. 电站锅炉文氏管减温器检查孔端盖失效原因分析%Failure Analysis of Desuperheater Manhole Cover of Boiler Venturi Tube Station

    Institute of Scientific and Technical Information of China (English)

    张明贤; 李以善; 唐杰

    2014-01-01

    本文通过金相、扫描电镜,并辅以视频内窥镜检验加以验证,对某热电厂夹套式文氏管减温器检查孔泄漏原因进行分析,总结了文氏管减温器的失效原因及对该类减温器检验中应采取的措施和方法。%Through metallographic , SEM , and supplemented by video endoscopic inspection to verify , this paper carries on the analysis to a power plant jacket type venturi desuperheaters inspection hole leakage, summarizes the reasons of Desuperheater venturi tube failure and the measures that should be taken .

  10. Drag of Clean and Fouled Net Panels--Measurements and Parameterization of Fouling.

    Directory of Open Access Journals (Sweden)

    Lars Christian Gansel

    Full Text Available Biofouling is a serious problem in marine aquaculture and it has a number of negative impacts including increased forces on aquaculture structures and reduced water exchange across nets. This in turn affects the behavior of fish cages in waves and currents and has an impact on the water volume and quality inside net pens. Even though these negative effects are acknowledged by the research community and governmental institutions, there is limited knowledge about fouling related effects on the flow past nets, and more detailed investigations distinguishing between different fouling types have been called for. This study evaluates the effect of hydroids, an important fouling organism in Norwegian aquaculture, on the forces acting on net panels. Drag forces on clean and fouled nets were measured in a flume tank, and net solidity including effect of fouling were determined using image analysis. The relationship between net solidity and drag was assessed, and it was found that a solidity increase due to hydroids caused less additional drag than a similar increase caused by change in clean net parameters. For solidities tested in this study, the difference in drag force increase could be as high as 43% between fouled and clean nets with same solidity. The relationship between solidity and drag force is well described by exponential functions for clean as well as for fouled nets. A method is proposed to parameterize the effect of fouling in terms of an increase in net solidity. This allows existing numerical methods developed for clean nets to be used to model the effects of biofouling on nets. Measurements with other types of fouling can be added to build a database on effects of the accumulation of different fouling organisms on aquaculture nets.

  11. Drag of Clean and Fouled Net Panels – Measurements and Parameterization of Fouling

    Science.gov (United States)

    Gansel, Lars Christian; Plew, David R.; Endresen, Per Christian; Olsen, Anna Ivanova; Misimi, Ekrem; Guenther, Jana; Jensen, Østen

    2015-01-01

    Biofouling is a serious problem in marine aquaculture and it has a number of negative impacts including increased forces on aquaculture structures and reduced water exchange across nets. This in turn affects the behavior of fish cages in waves and currents and has an impact on the water volume and quality inside net pens. Even though these negative effects are acknowledged by the research community and governmental institutions, there is limited knowledge about fouling related effects on the flow past nets, and more detailed investigations distinguishing between different fouling types have been called for. This study evaluates the effect of hydroids, an important fouling organism in Norwegian aquaculture, on the forces acting on net panels. Drag forces on clean and fouled nets were measured in a flume tank, and net solidity including effect of fouling were determined using image analysis. The relationship between net solidity and drag was assessed, and it was found that a solidity increase due to hydroids caused less additional drag than a similar increase caused by change in clean net parameters. For solidities tested in this study, the difference in drag force increase could be as high as 43% between fouled and clean nets with same solidity. The relationship between solidity and drag force is well described by exponential functions for clean as well as for fouled nets. A method is proposed to parameterize the effect of fouling in terms of an increase in net solidity. This allows existing numerical methods developed for clean nets to be used to model the effects of biofouling on nets. Measurements with other types of fouling can be added to build a database on effects of the accumulation of different fouling organisms on aquaculture nets. PMID:26151907

  12. Development of advanced monitoring methods to improve boiler availability and performance

    Energy Technology Data Exchange (ETDEWEB)

    Leino, T.; Kaerki, J.; Vainikka, P. (and others) [VTT, Jyvaskyla (Finland)

    2008-07-01

    Development of on-line monitoring tools is a key activity in the supervision, diagnosis and control of the impact of ash fouling on the efficiency and operation of large co-fired boilers. These monitoring tools have to be based both on the design of new measurement practices an don the mathematical modelling of the physical processes, aiming at the accurate determination of the deposition rates. The ADMONI-project aim was to develop on-line calculation methods for plant performance monitoring. The project focused on the design of a new pilot and power plant scale deposition probes, the execution of co-firing tests in experimental rigs and on the power plants and the development of monitoring tools to detect fouling rates both under pilot and full-scale perspectives. 43 refs., 142 figs., 13 tabs.

  13. Condensing economizers for small coal-fired boilers and furnaces

    Energy Technology Data Exchange (ETDEWEB)

    Butcher, T.A.; Litzke, W.

    1994-01-01

    Condensing economizers increase the thermal efficiency of boilers by recovering sensible and latent heat from exhaust gas. These economizers are currently being used commercially for this purpose in a wide range of applications. Performance is dependent upon application-specific factors affecting the utility of recovered heat. With the addition of a condensing economizer boiler efficiency improvements up to 10% are possible. Condensing economizers can also capture flue gas particulates. In this work, the potential use of condensing economizers for both efficiency improvement and control of particulate emissions from small, coal water slurry-fired boilers was evaluated. Analysis was done to predict heat transfer and particulate capture by mechanisms including: inertial impaction, interception, diffusion, thermophoretic forces, and condensation growth. Shell-and-tube geometries were considered with flue gas on the outside of Teflon-covered tubes. Experimental studies were done with both air- and water-cooled economizers refit to a small boiler. Two experimental arrangements were used including oil-firing with injection of flyash upstream of the economizer and direct coal water slurry firing. Firing rates ranged from 27 to 82 kW (92,000 to 280,000 Btu/hr). Inertial impaction was found to be the most important particulate capture mechanism and removal efficiencies to 95% were achieved. With the addition of water sprays directly on the first row of tubes, removal efficiencies increased to 98%. Use of these sprays adversely affects heat recovery. Primary benefits of the sprays are seen to be the addition of small impaction sites and future design improvements are suggested in which such small impactors are permanently added to the highest velocity regions of the economizer. Predicted effects of these added impactors on particulate removal and pressure drop are presented.

  14. Study of Corrosion in a Biomass Boiler

    Directory of Open Access Journals (Sweden)

    C. Berlanga

    2013-01-01

    Full Text Available Biomass plants, apart from producing energy, help to reduce CO2(g emissions. One of the biggest problems for their development is superheater corrosion due to fuel corrosivity, especially of the straw. This limits both the temperature of the vapour and also the effectiveness of the plant. In order to know more about the reactions which happen inside the boiler of biomass, thermodynamic calculations using software (HSC Chemistry have been carried out. Field tests have been carried out in the Sangüesa Biomass Plant in Navarra (Spain: determination of the types of oxides and the deposits formed on the superheaters tubes as well as a program to measure temperatures. Finally, the global results are discussed.

  15. Interaction of ions in water system containing copper-zinc alloy for boiler energy saving

    Institute of Scientific and Technical Information of China (English)

    MING Xing; LIANG Jinsheng; OU Xiuqin; TANG Qingguo; DING Yan

    2006-01-01

    Copper-zinc alloy element for boiler energy saving was put in the intake of simulated boiler system to investigate the interaction and transfer of ions in water system both theoretically and experimentally. The fouling was analyzed by scanning electron microscopy (SEM) and energy dispersive X-ray detector (EDX). The results show that the transfer of calcium and magnesium ions in heat-transfer-surface-water system is affected by zinc ions dissolved from the alloy because of primary battery reaction. Some calcium ions of calcium carbonate crystal are replaced by zinc ions, the growth of aragonite crystal nucleus is retarded, and the transition of calcium carbonate from aragonite to calcite is hampered.

  16. Characterization of Oxy-combustion Impacts in Existing Coal-fired Boilers

    Energy Technology Data Exchange (ETDEWEB)

    Adams, Bradley [Univ. of Utah, Salt Lake City, UT (United States); Davis, Kevin [Univ. of Utah, Salt Lake City, UT (United States); Senior, Constance [Univ. of Utah, Salt Lake City, UT (United States); Shim, Hong Shim [Univ. of Utah, Salt Lake City, UT (United States); Otten, Brydger Van [Univ. of Utah, Salt Lake City, UT (United States); Fry, Andrew [Univ. of Utah, Salt Lake City, UT (United States); Wendt, Jost [Univ. of Utah, Salt Lake City, UT (United States); Eddings, Eric [Univ. of Utah, Salt Lake City, UT (United States); Paschedag, Alan [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Shaddix, Christopher [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Cox, William [Brigham Young Univ., Provo, UT (United States); Tree, Dale [Brigham Young Univ., Provo, UT (United States)

    2013-09-30

    Reaction Engineering International (REI) managed a team of experts from University of Utah, Siemens Energy, Praxair, Vattenfall AB, Sandia National Laboratories, Brigham Young University (BYU) and Corrosion Management Ltd. to perform multi-scale experiments, coupled with mechanism development, process modeling and CFD modeling, for both applied and fundamental investigations. The primary objective of this program was to acquire data and develop tools to characterize and predict impacts of CO{sub 2} flue gas recycle and burner feed design on flame characteristics (burnout, NO{sub x}, SO{sub x}, mercury and fine particle emissions, heat transfer) and operational concerns (fouling, slagging and corrosion) inherent in the retrofit of existing coal-fired boilers for oxy-coal combustion. Experimental work was conducted at Sandia National Laboratories’ Entrained Flow Reactor, the University of Utah Industrial Combustion Research Facility, and Brigham Young University. Process modeling and computational fluid dynamics (CFD) modeling was performed at REI. Successful completion of the project objectives resulted in the following key deliverables: 1) Multi-scale test data from 0.1 kW bench-scale, 100 kW and 200 kW laboratory-scale, and 1 MW semi-industrial scale combustors that describe differences in flame characteristics, fouling, slagging and corrosion for coal combustion under air-firing and oxygen-firing conditions, including sensitivity to oxy-burner design and flue gas recycle composition. 2) Validated mechanisms developed from test data that describe fouling, slagging, waterwall corrosion, heat transfer, char burnout and sooting under coal oxy-combustion conditions. The mechanisms were presented in a form suitable for inclusion in CFD models or process models. 3) Principles to guide design of pilot-scale and full-scale coal oxy-firing systems and flue gas recycle configurations, such that boiler operational impacts from oxy-combustion retrofits are minimized. 4

  17. Investigation of organic fouling of microfiltration membrane

    Institute of Scientific and Technical Information of China (English)

    XIAO Feng; CUI Chong-wei; MA Jun

    2005-01-01

    Because the natural organic matters (NOMs) and proteins are the principal foulants of microfiltration membranes in drinking water, the primary aim of this paper is to obtain a better understanding of the interactions between those foulants and the microfiltration membrane from a novel view of coagulation. Based on reviewed literature and our own analysis, the authors consider that the behaviors of NOMs in the fouling of microfiltration membrane are like a form of crystal growth, and we recognize that the extent of the membrane hydrophobicity plays an essential role in NOMs fouling. However, proteins' fouling is more affected by intermolecular interaction. Additionally, the effect of membrane surface chemistry is not as essential as it is in the situation of NOMs.

  18. Understanding membrane fouling mechanisms through computational simulations

    Science.gov (United States)

    Xiang, Yuan

    This dissertation focuses on a computational simulation study on the organic fouling mechanisms of reverse osmosis and nanofiltration (RO/NF) membranes, which have been widely used in industry for water purification. The research shows that through establishing a realistic computational model based on available experimental data, we are able to develop a deep understanding of membrane fouling mechanism. This knowledge is critical for providing a strategic plan for membrane experimental community and RO/NF industry for further improvements in membrane technology for water treatment. This dissertation focuses on three major research components (1) Development of the realistic molecular models, which could well represent the membrane surface properties; (2) Investigation of the interactions between the membrane surface and foulants by steered molecular dynamics simulations, in order to determine the major factors that contribute to surface fouling; and (3) Studies of the interactions between the surface-modified membranes (polyethylene glycol) to provide strategies for antifouling.

  19. 76 FR 76896 - International Anti-Fouling System Certificate

    Science.gov (United States)

    2011-12-09

    ... SECURITY Coast Guard 46 CFR Part 8 RIN 1625-AB79 International Anti-Fouling System Certificate AGENCY... regulations to add the International Anti-fouling System (IAFS) Certificate to the list of certificates a... Harmful Anti-fouling Systems on Ships, 2001. This final rule will enable recognized...

  20. 76 FR 54419 - International Anti-Fouling System Certificate

    Science.gov (United States)

    2011-09-01

    ... SECURITY Coast Guard 46 CFR Part 8 RIN 1625-AB79 International Anti-Fouling System Certificate AGENCY... vessel inspection regulations to add the International Anti-fouling System (IAFS) Certificate to the list... Convention on the Control of Harmful Anti-fouling Systems on Ships, 2001. This proposed rule would...

  1. Two-phase flow for fouling control in membranes

    NARCIS (Netherlands)

    Wibisono, Yusuf

    2014-01-01

    The real challenge of the use of NF/RO spiral-wound membrane modules in water treatment is membrane fouling. Fouling problems in NF/RO systems are more complicated than in low pressure membrane processes, becaused fouling usually occurs on the nanoscale, combined with the complex geometry of spiral-

  2. Review of hypotheses for fouling during beer clarification using membranes

    NARCIS (Netherlands)

    Mepschen, A.; Sman, van der R.G.M.; Vollebregt, H.M.; Noordman, T.R.

    2012-01-01

    Hypotheses concerning the fouling of membranes during beer clarification via crossflow microfiltration are reviewed. Beer has been classified into three groups of components, each having a different kind of fouling mechanisms – but also having interactions with other modes of fouling. The membrane f

  3. Fouling mechanisms of dairy streams during membrane distillation

    NARCIS (Netherlands)

    Hausmann, A.; Sanciolo, P.; Vasiljevic, T.; Weeks, M.; Schroën, C.G.P.H.; Gray, S.; Duke, M.

    2013-01-01

    This study reports on fouling mechanisms of skim milk and whey during membrane distillation (MD) using polytetrafluoroethylene (PTFE) membranes. Structural and elemental changes along the fouling layer from the anchorpoint at the membrane to the topsurface of the fouling layer have been investigated

  4. Boiler-turbine life extension

    Energy Technology Data Exchange (ETDEWEB)

    Natzkov, S. [TOTEMA, Ltd., Sofia (Bulgaria); Nikolov, M. [CERB, Sofia (Bulgaria)

    1995-12-01

    The design life of the main power equipment-boilers and turbines is about 105 working hours. The possibilities for life extension are after normatively regulated control tests. The diagnostics and methodology for Boilers and Turbines Elements Remaining Life Assessment using up to date computer programs, destructive and nondestructive control of metal of key elements of units equipment, metal creep and low cycle fatigue calculations. As well as data for most common damages and some technical decisions for elements life extension are presented.

  5. CFD Simulation On CFBC Boiler

    Directory of Open Access Journals (Sweden)

    Amol S. Kinkar

    2015-02-01

    Full Text Available Abstract Heavy industrialization amp modernization of society demands in increasing of power cause to research amp develop new technology amp efficient utilization of existing power units. Variety of sources are available for power generation such as conventional sources like thermal hydro nuclear and renewable sources like wind tidal biomass geothermal amp solar. Out of these most common amp economical way for producing the power is by thermal power stations. Various industrial boilers plays an important role to complete the power generation cycle such as CFBC Circulating Fluidized Bed Combustion FBC Fluidized Bed Combustion AFBC Atmospheric Fluidized Bed Combustion Boiler CO Boiler RG amp WHR Boiler Waster heat recovery Boiler. This paper is intended to comprehensively give an account of knowledge related to refractory amp its failure in CFBC boiler with due effect of flue gas flow during operation on refractory by using latest technology of CAD Computer aided Design amp CAE Computer aided Engineering. By conceptual application of these technology the full scale model is able to analyze in regards the flow of flue gas amp bed material flow inside the CFBC loop via CFD Computational Fluid Dynamics software. The results obtained are helpful to understand the impact of gas amp particles on refractory in different areas amp also helped to choose suitable refractory material in different regions.

  6. Alternate tube plugging criteria for steam generator tubes

    Energy Technology Data Exchange (ETDEWEB)

    Cueto-Felgueroso, C.; Aparicio, C.B. [Tecnatom, S.A., Madrid (Spain)

    1997-02-01

    The tubing of the Steam Generators constitutes more than half of the reactor coolant pressure boundary. Specific requirements governing the maintenance of steam generator tubes integrity are set in Plant Technical Specifications and in Section XI of the ASME Boiler and Pressure Vessel Code. The operating experience of Steam Generator tubes of PWR plants has shown the existence of some types of degradatory processes. Every one of these has an specific cause and affects one or more zones of the tubes. In the case of Spanish Power Plants, and depending on the particular Plant considered, they should be mentioned the Primary Water Stress Corrosion Cracking (PWSCC) at the roll transition zone (RTZ), the Outside Diameter Stress Corrosion Cracking (ODSCC) at the Tube Support Plate (TSP) intersections and the fretting with the Anti-Vibration Bars (AVBs) or with the Support Plates in the preheater zone. The In-Service Inspections by Eddy Currents constitutes the standard method for assuring the SG tubes integrity and they permit the monitoring of the defects during the service life of the plant. When the degradation reaches a determined limit, called the plugging limit, the SG tube must be either repaired or retired from service by plugging. Customarily, the plugging limit is related to the depth of the defect. Such depth is typically 40% of the wall thickness of the tube and is applicable to any type of defect in the tube. In its origin, that limit was established for tubes thinned by wastage, which was the predominant degradation in the seventies. The application of this criterion for axial crack-like defects, as, for instance, those due to PWSCC in the roll transition zone, has lead to an excessive and unnecessary number of tubes being plugged. This has lead to the development of defect specific plugging criteria. Examples of the application of such criteria are discussed in the article.

  7. 热循环对锅炉管热喷涂Ni-Cr基纳米涂层的影响%Effect of thermal cycle on Ni-Cr based nanostructured thermal spray coating in boiler tubes

    Institute of Scientific and Technical Information of China (English)

    V.SENTHILKUMAR; B.THIYAGARAJAN; M.DURAISELVAM; K.KARTHICK

    2015-01-01

    采用机械球磨法制备Ni-Cr基纳米原料粉末.粉末颗粒在行星球磨机中反复经历焊合、碎裂和重焊合过程.采用超音速火焰喷涂工艺(HVOF)在碳钢管上喷涂球磨纳米粉末.利用金相显微镜、XRD、扫描电子显微镜(SEM),高分辨透射电子显微镜(HR-TEM)、能谱(EDS)和显微硬度测试对原料粉和HVOF喷涂涂层进行表征.对喷涂和未喷涂试样进行热循环分析,研究相、冶金性能和显微硬度的变化.与传统喷涂试样相比,Ni-Cr纳米涂层试样具有更高的力学和冶金性能.与传统涂层相比,纳米涂层的显微组织更均匀和紧密.%Ni-Cr based nanostructured feedstock powder was prepared by mechanical milling technique involving repeated welding, fracturing, and re-welding of powder particles in a planetary ball mill. The milled nanocrystalline powders were used to coat carbon steel tubes using high velocity oxygen fuel (HVOF) thermal spraying process. The characterization of the feedstock powder and HVOF coated substrates was performed using optical microscope, X-ray diffractometer (XRD), scanning electron microscope (SEM), high resolution transmission electron microscope (HR-TEM), energy dispersive spectrometer (EDS) and microhardness tests. The coated and uncoated samples were subjected to different thermal cycles and characterized for their phase changes, metallurgical changes and microhardness variations. Ni-Cr nanostructured coated samples exhibited higher mechanical and metallurgical properties compared to their conventionally coated counter parts. The results showed that the nanostructured coating possessed a more uniform and denser microstructure than the conventional coating.

  8. Black liquor combustion validated recovery boiler modeling, five-year report

    Energy Technology Data Exchange (ETDEWEB)

    Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

    1996-08-01

    The objective of this project was to develop a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. The project originated in October 1990 and was scheduled to run for four years. At that time, there was considerable emphasis on developing accurate predictions of the physical carryover of macroscopic particles of partially burnt black liquor and smelt droplets out of the furnace, since this was seen as the main cause of boiler plugging. This placed a major emphasis on gas flow patterns within the furnace and on the mass loss rates and swelling and shrinking rates of burning black liquor drops. As work proceeded on developing the recovery boiler furnace model, it became apparent that some recovery boilers encounter serious plugging problems even when physical carryover was minimal. After the original four-year period was completed, the project was extended to address this issue. The objective of the extended project was to improve the utility of the models by including the black liquor chemistry relevant to air emissions predictions and aerosol formation, and by developing the knowledge base and computational tools to relate furnace model outputs to fouling and plugging of the convective sections of the boilers. The work done to date includes CFD model development and validation, acquisition of information on black liquor combustion fundamentals and development of improved burning models, char bed model development, and model application and simplification.

  9. Black liquor combustion validated recovery boiler modeling: Final year report. Volume 4 (Appendix IV)

    Energy Technology Data Exchange (ETDEWEB)

    Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

    1998-08-01

    This project was initiated in October 1990, with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. The key tasks to be accomplished were as follows: (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes. (2) Validate the enhanced furnace models, so that users can have confidence in the predicted results. (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler. (4) Facilitate the transfer of codes, black liquid submodels, and fundamental knowledge to the US kraft pulp industry. Volume 4 contains the following appendix sections: Radiative heat transfer properties for black liquor combustion -- Facilities and techniques and Spectral absorbance and emittance data; and Radiate heat transfer determination of the optical constants of ash samples from kraft recovery boilers -- Calculation procedure; Computation program; Density determination; Particle diameter determination; Optical constant data; and Uncertainty analysis.

  10. INDUSTRIAL BOILER RETROFIT FOR NOX CONTROL: COMBINED SELECTIVE NONCATALYTIC REDUCTION AND SELECTIVE CATALYTIC REDUCTION

    Science.gov (United States)

    The paper describes retrofitting and testing a 590 kW (2 MBtu/hr), oil-fired, three-pass, fire-tube package boiler with a combined selective noncatalytic reduction (SNCR) and selective catalytic reduction (SCR) system. The system demonstrated 85% nitrogen oxides (NOx) reduction w...

  11. Fouling and Antifouling of Depetanizer in Ethylene Units

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    Factors affecting fouling of depentanizer in ethylene units were explored through study of thecomposition of pyrolysis gasoline, C5 distillate and fouling deposits from the depentanizer while takinginto consideration the processing parameters. A variety of antifouling measures, in particular the injec-tion of a special anti-fouling agent into the Cs gas phase pipeline and the C5 distillate reflux pipelinewere introduced. Commercial evaluation test of a multifunctional anti-fouling agent, the RIPP-1404anti-fouling agent, was also described.

  12. Fouling and Antifouling of Depetanizer in Ethylene Units

    Institute of Scientific and Technical Information of China (English)

    DongZhongjie; LiYunlong; 等

    2002-01-01

    Factors affecting fouling of depentanizer in ethylene units were explored through study of the composition of pyrolysis gasoline,C5 distillate and fouling deposits from the depentanizer while taking into consideration the processing parameters.A variety of antifouling measures,in particular the injec-tion of a special anti-fouling agent into the C5 gas phase pipeline and the C5 distillate reflux pipeline were introduced.Commercial evaluation test of a multifunctional anti-fouling agent,the RIPP-1404 anti-fouling agent,was also described.

  13. CROSS-FLOW ULTRAFILTRATION OF SECONDARY EFFLUENTS. MEMBRANE FOULING ANALYSIS

    Directory of Open Access Journals (Sweden)

    Luisa Vera

    2014-12-01

    Full Text Available The application of cross-flow ultrafiltration to regenerate secondary effluents is limited by membrane fouling. This work analyzes the influence of the main operational parameters (transmembrane pressure and cross-flow velocity about the selectivity and fouling observed in an ultrafiltration tubular ceramic membrane. The experimental results have shown a significant retention of the microcolloidal and soluble organic matter (52 – 54% in the membrane. The fouling analysis has defined the critical operational conditions where the fouling resistance is minimized. Such conditions can be described in terms of a dimensionless number known as shear stress number and its relationship with other dimensionless parameter, the fouling number.

  14. Development of Low Fouling and High Fouling-release Zwitterionic Marine Coatings

    Science.gov (United States)

    2016-01-04

    NOTES 14. ABSTRACT This grant from ONR to Zwitter Technology, LLC is to develop, scale up and formulate a low-fouling and high-fouling-release marine...Transition progress or updates to plan 5 Program Objective This grant from ONR to Zwitter Technology, LLC is to develop, scale up and formulate a low...method to make block copolymers. Among several Controlled/Living radical polymerization techniques, Atom Transfer Radical Polymerization (ATRP) is most

  15. Nickel- and iron-based HVOF thermal spray coatings for high temperature corrosion protection in biomass-fired power plant boilers

    OpenAIRE

    Oksa, Maria

    2015-01-01

    Biomass burning for production of electricity and heat has been increasing due to legislation in Europe. Growing awareness of environmental problems has led to strict restrictions on greenhouse emissions in the energy sector, and increased demand for higher use of renewable energy sources and carbon-neutral fuels, such as biomass. There are over 1000 biomass boilers in Europe, and the number is increasing. These plants often face serious problems due to high temperature corrosion. Fouling and...

  16. Fouled Anchors: The CONSTELLATION Question Answered

    Science.gov (United States)

    1991-09-01

    1711804 87AU 73 89-1-3401 11. TITLE (kcn e S.cE) Caut,.cawn) Fouled Anchors: The Constellation Question Answered IL. PERSONA .. AUTHOPS) Wegner, Dana M...was familia , with the unaltered Constellation in Newport and, unknown to the Committee, had indeed visited the ship once in Baltimore (see p. 45). It is

  17. Fouling corrosion in aluminum heat exchangers

    Directory of Open Access Journals (Sweden)

    Su Jingxin

    2015-06-01

    Full Text Available Fouling deposits on aluminum heat exchanger reduce the heat transfer efficiency and cause corrosion to the apparatus. This study focuses on the corrosive behavior of aluminum coupons covered with a layer of artificial fouling in a humid atmosphere by their weight loss, Tafel plots, electrochemical impedance spectroscopy (EIS, and scanning electron microscope (SEM observations. The results reveal that chloride is one of the major elements found in the fouling which damages the passive film and initiates corrosion. The galvanic corrosion between the metal and the adjacent carbon particles accelerates the corrosive process. Furthermore, the black carbon favors the moisture uptake, and gives the dissolved oxygen greater chance to migrate through the fouling layer and form a continuous diffusive path. The corrosion rate decreasing over time is conformed to electrochemistry measurements and can be verified by Faraday’s law. The EIS results indicate that the mechanism of corrosion can be interpreted by the pitting corrosion evolution mechanism, and that pitting was observed on the coupons by SEM after corrosive exposure.

  18. Fouling in reverse electrodialysis under natural conditions

    NARCIS (Netherlands)

    Vermaas, David A.; Kunteng, Damnearn; Saakes, Michel; Nijmeijer, Kitty

    2013-01-01

    Renewable energy can be generated from mixing salt water and fresh water in reverse electrodialysis. The potential for energy generation from mixing seawater and river water is enormous. To investigate the effect of fouling when such natural feed waters are used, the performance of three different s

  19. Characterization of fouling of membrane contactors

    DEFF Research Database (Denmark)

    Ciurkot, Kaludia; Zarebska, Agata; Christensen, Knud Villy

    2013-01-01

    achieved higher ammonia removal than the synthetic model manure solution. This might be due to the larger particle size of the milled straw in the model solution compared to the size of suspended solids present in real manure. From the fouling autopsy, it was found that PTFE membranes are more prone...

  20. The Modified Fouling Index Ultrafiltration constant flux for assessing particulate/colloidal fouling of RO systems

    KAUST Repository

    Salinas-Rodriguez, Sergio G.

    2015-02-18

    Reliable methods for measuring and predicting the fouling potential of reverse osmosis (RO) feed water are important in preventing and diagnosing fouling at the design stage, and for monitoring pre-treatment performance during plant operation. The Modified Fouling Index Ultrafiltration (MFI-UF) constant flux is a significant development with respect to assessing the fouling potential of RO feed water. This research investigates (1) the variables influencing the MFI-UF test at constant flux filtration (membrane pore size, membrane material, flux rate); and (2) the application of MFI-UF into pre-treatment assessment and RO fouling estimation. The dependency of MFI on flux, means that to assess accurately particulate fouling in RO systems, the MFI should be measured at a flux similar to a RO system (close to 20 L/m2/h) or extrapolated from higher fluxes. The two studied membrane materials showed reproducible results; 10% for PES membranes and 6.3% for RC membranes. Deposition factors (amount of particles that remain on the surface of membrane) were measured in a full-scale plant ranging between 0.2 and 0.5. The concept of “safe MFI” is presented as a guideline for assessing pre-treatment for RO systems.

  1. Protein antifouling and fouling-release in perfluoropolyether surfaces

    Science.gov (United States)

    Molena, Elena; Credi, Caterina; De Marco, Carmela; Levi, Marinella; Turri, Stefano; Simeone, Giovanni

    2014-08-01

    Perfluoropolyether polymers have been described as high performance fouling-release materials for marine coatings. Moreover, they have a good potential to be exploited in the biomedical field too. In this article several perfuoropolyether photopolymers were characterized in terms of surface and mechanical properties outlining the relationship between these properties and the polymer molecular structure. In particular the anti-fouling and fouling-release performances, evaluated using Bovine Serum Albumin as testing protein, was correlated to other material properties, like a parameter considering both surface tension components γ and elastic modulus E. A good correlation between the anti-fouling/fouling-release of perfluoropolyethers and (E*γpolar)1/2 can actually be established. Our results show that perfluoropolyether photopolymers are good protein anti-fouling/fouling-release materials.

  2. Mitigation of Syngas Cooler Plugging and Fouling

    Energy Technology Data Exchange (ETDEWEB)

    Bockelie, Michael J. [Reaction Engineering International, Salt Lake City, UT (United States)

    2015-06-29

    This Final Report summarizes research performed to develop a technology to mitigate the plugging and fouling that occurs in the syngas cooler used in many Integrated Gasification Combined Cycle (IGCC) plants. The syngas cooler is a firetube heat exchanger located downstream of the gasifier. It offers high thermal efficiency, but its’ reliability has generally been lower than other process equipment in the gasification island. The buildup of ash deposits that form on the fireside surfaces in the syngas cooler (i.e., fouling) lead to reduced equipment life and increased maintenance costs. Our approach to address this problem is that fouling of the syngas cooler cannot be eliminated, but it can be better managed. The research program was funded by DOE using two budget periods: Budget Period 1 (BP1) and Budget Period 2 (BP2). The project used a combination of laboratory scale experiments, analysis of syngas cooler deposits, modeling and guidance from industry to develop a better understanding of fouling mechanisms and to develop and evaluate strategies to mitigate syngas cooler fouling and thereby improve syngas cooler performance. The work effort in BP 1 and BP 2 focused on developing a better understanding of the mechanisms that lead to syngas cooler plugging and fouling and investigating promising concepts to mitigate syngas cooler plugging and fouling. The work effort focused on the following: • analysis of syngas cooler deposits and fuels provided by an IGCC plant collaborating with this project; • performing Jet cleaning tests in the University of Utah Laminar Entrained Flow Reactor to determine the bond strength between an ash deposit to a metal plate, as well as implementing planned equipment modifications to the University of Utah Laminar Entrained Flow Reactor and the one ton per day, pressurized Pilot Scale Gasifier; • performing Computational Fluid Dynamic modeling of industrially relevant syngas cooler configurations to develop a better

  3. Boiler using combustible fluid

    Science.gov (United States)

    Baumgartner, H.; Meier, J.G.

    1974-07-03

    A fluid fuel boiler is described comprising a combustion chamber, a cover on the combustion chamber having an opening for introducing a combustion-supporting gaseous fluid through said openings, means to impart rotation to the gaseous fluid about an axis of the combustion chamber, a burner for introducing a fluid fuel into the chamber mixed with the gaseous fluid for combustion thereof, the cover having a generally frustro-conical configuration diverging from the opening toward the interior of the chamber at an angle of between 15/sup 0/ and 55/sup 0/; means defining said combustion chamber having means defining a plurality of axial hot gas flow paths from a downstream portion of the combustion chamber to flow hot gases into an upstream portion of the combustion chamber, and means for diverting some of the hot gas flow along paths in a direction circumferentially of the combustion chamber, with the latter paths being immersed in the water flow path thereby to improve heat transfer and terminating in a gas outlet, the combustion chamber comprising at least one modular element, joined axially to the frustro-conical cover and coaxial therewith. The modular element comprises an inner ring and means of defining the circumferential, radial, and spiral flow paths of the hot gases.

  4. Heat transfer characteristics of air cross-flow for in-line arrangement of spirally corrugated tube and smooth tube bundles

    Institute of Scientific and Technical Information of China (English)

    LU Guo-dong; ZHOU Qiang-tai; TIAN Mao-cheng; CHENG Lin; YU Xiao-li

    2005-01-01

    An experimental study on heat transfer and resistance coefficients of linearly arranged smooth and spirally corrugated tube bundles in cross-flow was performed. The heat transfer and resistance coefficients are presented in this paper with transverse and longitudinal tube-pitch and tube geometries taken into account. The experiment's results can provide technical guidelines for application to horizontal air preheater with arranged in-line spirally corrugated tube bundles, especially to the air preheater for CFBCBs (Circulating Fluidized Bed Combustion Boilers).

  5. KINERJA ECONOMIZER PADA BOILER

    Directory of Open Access Journals (Sweden)

    Muhammad Sjahid Akbar

    2009-01-01

    Full Text Available This paper employed the dual response approach for case of Multivariate Robust Parameter Design (MRPD which is developed by Del Castillo and Miro Quesada. MRPD method can be applied for any design of experiment. The optimization in this method uses minimizing variance function with restriction on mean function. In this paper, MRPD is applied to the case of optimization of heat transfer efectivity and operational cost at economizer. Those two responses are optimized by setting the level of control factors; diametre of tube hole, transversal spacing, and fin nearness. Temperature of feedwater is hold as a noise factor. Optimization is calculated by fmincon in MATLAB 7.0. The optimal condition for heat tranfer efectivity is 77.17% and operational cost is 30.58 kW. The optimal condition is attained at diametre of tube hole 1.5 inch, transversal spacing 3.5 inch, and fin density 3 fin/inch. Abstract in Bahasa Indonesia: Penelitian ini menggunakan metode pendekatan dual response terhadap kasus Multivariate Robust Parameter Design (MRPD yang dikembangkan oleh Del Castillo dan Miro Quesada. Metode MRPD tidak mensyaratkan jenis rancangan percobaan yang dapat digunakan dalam proses optimasi, yang dilakukan dengan meminimalkan fungsi varians terhadap kendala fungsi rerata. Pada penelitian ini, metode MRPD diterapkan untuk kasus pencarian nilai optimal respon yaitu efektifitas perpindahan panas dan biaya operasi pada economizer. Optimasi kedua respon dilakukan dengan cara mengoptimalkan level faktor kontrol diameter luar tubing, transversal spacing, dan kerapatan fin. Temperatur feedwater berlaku sebagai faktor noise. Optimasi dilakukan dengan bantuan fmincon pada MATLAB 7.0 yang menghasilkan kondisi optimum untuk efektifitas perpindahan panas sebesar 77,17% dan biaya operasi sebesar 30,58 kW. Kondisi tersebut dicapai pada saat level diameter luar tubing sebesar 1,5 inci, transversal spacing sebesar 3,5 inci, dan kerapatan fin sebesar 3 fin/inci. Kata kunci

  6. Boiler for generating high quality vapor

    Science.gov (United States)

    Gray, V. H.; Marto, P. J.; Joslyn, A. W.

    1972-01-01

    Boiler supplies vapor for use in turbines by imparting a high angular velocity to the liquid annulus in heated rotating drum. Drum boiler provides a sharp interface between boiling liquid and vapor, thereby, inhibiting the formation of unwanted liquid droplets.

  7. New controls spark boiler efficiency

    Energy Technology Data Exchange (ETDEWEB)

    Engels, T. (Monsanto, University Park, IL (United States))

    1993-09-01

    Monsanto's NutraSweet plant in University Park, IL, produces aspartame, the patented NutraSweet artificial sweetener product. Until recently, boiler control was managed by a '60s-era Fireye jackshaft system in which air and natural gas were mechanically linked with an offset to compensate for oxygen trim. The interlocking devices on the Fireye system were becoming obsolete, and the boiler needed a new front end retrofitted for low emissions. In order to improve boiler control efficiency, we decided to modernize and automate the entire boiler control system. We replaced the original jackshaft system, and installed a Gordon-Piet burner system, including gas valves, air dampers, blowers, and burner. The upgrade challenges included developing a control strategy and selecting and implementing a process control system. Since our plant has standardized on the PROVOX process management information system from Fisher Controls (now Fisher-Rosemount Systems) to support most of our process, it was a natural and logical choice for boiler controls as well. 2 figs.

  8. Black liquor combustion validated recovery boiler modeling: Final year report. Volume 3 (Appendices II, sections 2--3 and III)

    Energy Technology Data Exchange (ETDEWEB)

    Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

    1998-08-01

    This project was initiated in October 1990, with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. The key tasks to be accomplished were as follows: (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes. (2) Validate the enhanced furnace models, so that users can have confidence in the predicted results. (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler. (4) Facilitate the transfer of codes, black liquid submodels, and fundamental knowledge to the US kraft pulp industry. Volume 3 contains the following appendix sections: Formation and destruction of nitrogen oxides in recovery boilers; Sintering and densification of recovery boiler deposits laboratory data and a rate model; and Experimental data on rates of particulate formation during char bed burning.

  9. Fouling resistance prediction using artificial neural network nonlinear auto-regressive with exogenous input model based on operating conditions and fluid properties correlations

    Science.gov (United States)

    Biyanto, Totok R.

    2016-06-01

    Fouling in a heat exchanger in Crude Preheat Train (CPT) refinery is an unsolved problem that reduces the plant efficiency, increases fuel consumption and CO2 emission. The fouling resistance behavior is very complex. It is difficult to develop a model using first principle equation to predict the fouling resistance due to different operating conditions and different crude blends. In this paper, Artificial Neural Networks (ANN) MultiLayer Perceptron (MLP) with input structure using Nonlinear Auto-Regressive with eXogenous (NARX) is utilized to build the fouling resistance model in shell and tube heat exchanger (STHX). The input data of the model are flow rates and temperatures of the streams of the heat exchanger, physical properties of product and crude blend data. This model serves as a predicting tool to optimize operating conditions and preventive maintenance of STHX. The results show that the model can capture the complexity of fouling characteristics in heat exchanger due to thermodynamic conditions and variations in crude oil properties (blends). It was found that the Root Mean Square Error (RMSE) are suitable to capture the nonlinearity and complexity of the STHX fouling resistance during phases of training and validation.

  10. High-Temperature Behavior of a NiCr-Coated T91 Boiler Steel in the Platen Superheater of Coal-Fired Boiler

    Science.gov (United States)

    Chatha, Sukhpal Singh; Sidhu, Hazoor S.; Sidhu, Buta S.

    2013-06-01

    Ni-20Cr coating was deposited on T91 boiler tube steel by high-velocity oxy-fuel (HVOF) process to enhance high-temperature oxidation resistance. High-temperature performance of bare, as well as HVOF-coated steel specimens was evaluated for 1500 h under in the platen superheater zone of coal-fired boiler, where the temperature was around 900 °C. Experiments were carried out for 15 cycles, each of 100-h duration followed by 1-h cooling at ambient temperature. The extent of degradation of the specimens was assessed by the thickness loss and depth of internal corrosion attack. Ni-20Cr-coated steel performed better than the uncoated steel in actual boiler environment. The improved degradation resistance of Ni-20Cr coating can be attributed to the presence of Cr2O3 in the top oxide scale and dense microstructure.

  11. Dynamic simulation model for ultra supercritical 1 000 MW unit boilers%Dynamic simulation model for ultra supercritical 1000 MW unit boilers

    Institute of Scientific and Technical Information of China (English)

    XU Hui; XU Ershu

    2013-01-01

    On the basis of heat transfer characteristics of working fluid at different pressures inside the water wall tube and structure of the ultra supercritical 1 000 MW unit once through boiler in Jianbi Power Plant,the varying phase transformation point method was adopted to establish the moving-boundary dynamic simulation model of water wall in ultra supercritical once through boilers,especially the length variation of hot water section,evaporation section and superheat section against the load changing.On this basis,the real-time dynamic simulation model for ultra-supercritical 1 000 MW unit boiler in Jianbi Power Plant was built on the STAR-90 simulation platform.The dynamic and static characteristics test showed that,this model can simulate the unit's startup/shutdown process and some typical fault conditions accurately,and had good dynamic and static performance.

  12. Sootblowing optimization for improved boiler performance

    Science.gov (United States)

    James, John Robert; McDermott, John; Piche, Stephen; Pickard, Fred; Parikh, Neel J

    2013-07-30

    A sootblowing control system that uses predictive models to bridge the gap between sootblower operation and boiler performance goals. The system uses predictive modeling and heuristics (rules) associated with different zones in a boiler to determine an optimal sequence of sootblower operations and achieve boiler performance targets. The system performs the sootblower optimization while observing any operational constraints placed on the sootblowers.

  13. NOx Control Options and Integration for US Coal Fired Boilers

    Energy Technology Data Exchange (ETDEWEB)

    Mike Bockelie; Marc Cremer; Kevin Davis; Martin Denison; Adel Sarofim; Connie Senior; Hong-Shig Shim; Dave Swenson; Bob Hurt; Eric Suuberg; Eric Eddings; Kevin Whitty; Larry Baxter; Calvin Bartholomew; William Hecker

    2006-06-30

    in a pilot scale furnace and soot behavior predicted by the CFD model showed good agreement. Field and laboratory tests were performed for SCR catalysts used for coal and biomass co-firing applications. Fundamental laboratory studies were performed to better understand mechanisms involved with catalyst deactivation. Field tests with a slip stream reactor were used to create catalyst exposed to boiler flue gas for firing coal and for co-firing coal and biomass. The field data suggests the mechanisms leading to catalyst deactivation are, in order of importance, channel plugging, surface fouling, pore plugging and poisoning. Investigations were performed to better understand the mechanisms involved with catalyst regeneration through mechanical or chemical methods. A computer model was developed to predict NOx reduction across the catalyst in a SCR. Experiments were performed to investigate the fundamentals of ammonia/fly ash interactions with relevance to the operation of advanced NOx control technologies such as selective catalytic reduction. Measurements were performed for ammonia adsorption isotherms on commercial fly ash samples subjected to a variety of treatments and on the chemistry of dry and semi-dry ammonia removal processes. This work resulted in the first fundamental ammonia isotherms on carbon-containing fly ash samples. This work confirms industrial reports that aqueous solution chemistry takes place upon the introduction of even very small amounts of water, while the ash remains in a semi-dry state.

  14. PREDICTION OF OXIDE SCALE EXFOLIATION IN STEAM TUBES

    Energy Technology Data Exchange (ETDEWEB)

    Sabau, Adrian S [ORNL; Wright, Ian G [ORNL

    2010-01-01

    Numerical simulation results are presented for the prediction of the likelihood of oxide scale exfoliation from superheater tubes. The scenarios considered involved alloys T22, TP347H, and TP347HFG subjected to a simplified operating cycle in a power plant generating supercritical steam. The states of stress and strain of the oxides grown in steam were based solely on modeling the various phenomena experienced by superheater tubes during boiler operation, current understanding of the oxidation behavior of each alloy in steam, and consideration of operating parameters such as heat flux, tube dimensions, and boiler duty cycle. Interpretation of the evolution of strain in these scales, and the approach to conditions where scale failure (hence exfoliation) is expected, makes use of the type of Exfoliation Diagrams that incorporate various cracking and exfoliation criteria appropriate for the system considered. In these diagrams, the strain accumulation with time in an oxide is represented by a strain trajectory derived from the net strain resulting from oxide growth, differences in coefficients of thermal expansion among the components, and relaxation due to creep. It was found that an oxide growing on a tube subjected to routine boiler load cycling conditions attained relatively low values of net strain, indicating that oxide failure would not be expected to occur during normal boiler operation. However, during a boiler shut-down event, strains sufficient to exceed the scale failure criteria were developed after times reasonably in accord with plant experience, with the scales on the ferritic steel failing in tension, and those on the austenitic steels in compression. The results presented illustrate that using this approach to track the state of strain in the oxide scale through all phases of boiler operation, including transitions from full-to-low load and shut-down events, offers the possibility of identifying the phase(s) of boiler operation during which oxide

  15. Probabilistic approach to determining the optimum replacement of a superheater stage in 680 MW coal-fired boiler

    Energy Technology Data Exchange (ETDEWEB)

    Bos, Robert; Star, Ruud van der [Nuon Power Generation, Amsterdam (Netherlands)

    2009-07-01

    The boiler of the NUON power plant HW08 that went into operation in 1993 is designed as Benson boiler and mainly fired with hard coal. A creep-related tube failure occurred in the tertiary superheater that had been due to increased wall temperature caused by steam side formation of oxide layers. The theoretical lifetime of the components was calculated with the aid of the results of steam side oxide measurements and condition evaluation of the tertiary superheater with the aid of tube samples. The objective is to establish an operation and maintenance schedule for the desired operating lifetime of 300,000 hours. (orig.)

  16. Identification of Material Parameters for the Simulation of Acoustic Absorption of Fouled Sintered Fiber Felts

    Directory of Open Access Journals (Sweden)

    Nicolas Lippitz

    2016-08-01

    Full Text Available As a reaction to the increasing noise pollution, caused by the expansion of airports close to residential areas, porous trailing edges are investigated to reduce the aeroacoustic noise produced by flow around the airframe. Besides mechanical and acoustical investigations of porous materials, the fouling behavior of promising materials is an important aspect to estimate the performance in long-term use. For this study, two sintered fiber felts were selected for a long-term fouling experiment where the development of the flow resistivity and accumulation of dirt was observed. Based on 3D structural characterizations obtained from X-ray tomography of the initial materials, acoustic models (Biot and Johnson–Champoux–Allard in the frame of the transfer matrix method were applied to the sintered fiber felts. Flow resistivity measurements and the measurements of the absorption coefficient in an impedance tube are the basis for a fouling model for sintered fiber felts. The contribution will conclude with recommendations concerning the modeling of pollution processes of porous materials.

  17. Diesel injector fouling bench test methodology

    Science.gov (United States)

    Stavinoha, Leon L.; Yost, Douglas M.; Lestz, Sidney J.

    1992-06-01

    Compared to conventional compression ignition (CI) engine operation with the fuel being delivered at approximately 149 C (300 F), adiabatic engine operation potentially may deliver the fuel at temperatures as high as 260 C (500 F). Hypergolic CI engine combustion systems now in theoretical design stages will deliver fuel at temperatures approaching 427 to 538 C (800 to 1000 F). The ability of a fuel to resist formation of deposits on internal injector system surfaces is a form of thermal oxidative stability for which test methodology will be required. The injector Fouling Bench Test (IFBT) methodology evaluated in this report will assist in defining fuel contribution to injector fouling and control of fuel thermal stability in procurement specifications. The major observations from this project are discussed. Forty-hour cyclic IFB tests employing both Bosch APE 113 and Detroit Diesel (DD) N70 injectors are viable procedures for evaluating fuel effects on injector fouling. Cyclic operation appears to be superior to steady-state operation for both type injectors. Eighty-hour cyclic tests are more discriminating than 40-hour cyclic tests using the Bosch APE 113 injectors. JFTOT tests of fuels provide directional information on thermal stability-related deposits and filter plugging but show limited good correlation with IFBT DD N70 ratings, and none with IFBT Bosch APE 113 injector ratings. Deposition on injector pintles was more realistically rated by optical microscopy and Scanning Electron Microscopy (SEM) than conventional visual and bench rating methods. High-sulfur fuel readily caused sticking of Detroit Diesel injectors. Injector sticking is an important mode of injector fouling.

  18. Impact of sludge flocs on membrane fouling in membrane bioreactors

    DEFF Research Database (Denmark)

    Christensen, Morten Lykkegaard; Niessen, Wolfgang; Jørgensen, Mads Koustrup

    Membrane bioreactors (MBR) are widely used for wastewater treatment, but membrane fouling reduces membrane performance and thereby increases the cost for membranes and fouling control. Large variation in filtration properties measured as flux decline was observed for the different types of sludges...... and the physico-chemical properties, is an efficient method to reduce membrane fouling in the MBR. High concentration of suspended extracellular substances (EPS) and small particles (up to 10 µm) resulted in pronounced fouling propensity. The membrane fouling resistance was reduced at high concentration...... flocs reduced membrane fouling, and more compact and strong flocs were formed if the concentration of divalent ions were high. Sludge was fractionated by centrifugation providing supernatant with soluble EPS and colloidal particles but without flocs. Filtration test on untreated sludge and supernatant...

  19. Proteins causing membrane fouling in membrane bioreactors.

    Science.gov (United States)

    Miyoshi, Taro; Nagai, Yuhei; Aizawa, Tomoyasu; Kimura, Katsuki; Watanabe, Yoshimasa

    2015-01-01

    In this study, the details of proteins causing membrane fouling in membrane bioreactors (MBRs) treating real municipal wastewater were investigated. Two separate pilot-scale MBRs were continuously operated under significantly different operating conditions; one MBR was a submerged type whereas the other was a side-stream type. The submerged and side-stream MBRs were operated for 20 and 10 days, respectively. At the end of continuous operation, the foulants were extracted from the fouled membranes. The proteins contained in the extracted foulants were enriched by using the combination of crude concentration with an ultrafiltration membrane and trichloroacetic acid precipitation, and then separated by two-dimensional polyacrylamide gel electrophoresis (2D-PAGE). The N-terminal amino acid sequencing analysis of the proteins which formed intensive spots on the 2D-PAGE gels allowed us to partially identify one protein (OmpA family protein originated from genus Brevundimonas or Riemerella anatipestifer) from the foulant obtained from the submerged MBR, and two proteins (OprD and OprF originated from genus Pseudomonas) from that obtained from the side-stream MBR. Despite the significant difference in operating conditions of the two MBRs, all proteins identified in this study belong to β-barrel protein. These findings strongly suggest the importance of β-barrel proteins in developing membrane fouling in MBRs.

  20. Coke fouling monitoring by electrical resistivity

    Energy Technology Data Exchange (ETDEWEB)

    Bombardelli, Clovis; Mari, Livia Assis; Kalinowski, Hypolito Jose [Universidade Tecnologica Federal do Parana (UTFPR), Curitiba, PR (Brazil). Programa de Pos-Graduacao em Engenharia Eletrica e Informatica Industrial (CPGEI)

    2008-07-01

    An experimental method to simulate the growth of the coke fouling that occurs in the oil processing is proposed relating the thickness of the encrusted coke to its electrical resistivity. The authors suggest the use of the fouling electrical resistivity as a transducer element for determining its thickness. The sensor is basically two electrodes in an electrically isolated device where the inlay can happen in order to compose a purely resistive transducer. Such devices can be easily constructed in a simple and robust form with features capable to face the high temperatures and pressures found in relevant industrial processes. For validation, however, it is needed a relationship between the electrical resistivity and the fouling thickness, information not yet found in the literature. The present work experimentally simulates the growth of a layer of coke on an electrically insulating surface, equipped with electrodes at two extremities to measure the electrical resistivity during thermal cracking essays. The method is realized with a series of consecutive runs. The results correlate the mass of coke deposited and its electrical resistivity, and it can be used to validate the coke depositions monitoring employing the resistivity as a control parameter. (author)

  1. Application of membrane type economizer in 220 t/h boiler%膜式省煤器在220 t/h锅炉中的应用

    Institute of Scientific and Technical Information of China (English)

    2013-01-01

      膜式省煤器在电厂锅炉得到了普遍应用,文章根据其在220 t/h锅炉上的实际应用情况,对膜式省煤器和光管式省煤器的优劣进行比较,并得出具有实际意义的结论,为今后的锅炉对流受热面的改造提供指导。%Compared the membrane economizer with properties of bare tube economizer,the former has more advantages.For 220t/h boiler tube economizer's severe wear and frequent tube explosion,the No. 1 and No. 2 boiler of low temperature economizer were trans-formed. In fact,it not only improves the boiler efficiency but also ensures no tube explosion.

  2. Release of Corrosive Species above the Grate in a Waste Boiler and the Implication for Improved Electrical Efficiency

    DEFF Research Database (Denmark)

    Bøjer, Martin; Jensen, Peter Arendt; Dam-Johansen, Kim;

    2010-01-01

    A relatively low electrical efficiency of 20−25% is obtained in typical west European waste boilers. Ash species released from the grate combustion zone form boiler deposits with high concentrations of Cl, Na, K, Zn, Pb, and S that cause corrosion of superheater tubes at high temperature. The sup......A relatively low electrical efficiency of 20−25% is obtained in typical west European waste boilers. Ash species released from the grate combustion zone form boiler deposits with high concentrations of Cl, Na, K, Zn, Pb, and S that cause corrosion of superheater tubes at high temperature....... The superheater steam temperature has to be limited to around 425 °C, and thereby, the electrical efficiency remains low compared to wood or coal-fired boilers. If a separate part of the flue gas from the grate has a low content of corrosive species, it may be used to superheat steam to a higher temperature......, and thereby, the electrical efficiency of the plant can be increased. In this study, the local temperature, the gas concentrations of CO, CO2, and O2, and the release of the volatile elements Cl, S, Na, K, Pb, Zn, Cu, and Sn were measured above the grate in a waste boiler to investigate if a selected fraction...

  3. Computational Modeling and Assessment Of Nanocoatings for Ultra Supercritical Boilers

    Energy Technology Data Exchange (ETDEWEB)

    David W. Gandy; John P. Shingledecker

    2011-04-11

    Forced outages and boiler unavailability in conventional coal-fired fossil power plants is most often caused by fireside corrosion of boiler waterwalls. Industry-wide, the rate of wall thickness corrosion wastage of fireside waterwalls in fossil-fired boilers has been of concern for many years. It is significant that the introduction of nitrogen oxide (NOx) emission controls with staged burners systems has increased reported waterwall wastage rates to as much as 120 mils (3 mm) per year. Moreover, the reducing environment produced by the low-NOx combustion process is the primary cause of accelerated corrosion rates of waterwall tubes made of carbon and low alloy steels. Improved coatings, such as the MCrAl nanocoatings evaluated here (where M is Fe, Ni, and Co), are needed to reduce/eliminate waterwall damage in subcritical, supercritical, and ultra-supercritical (USC) boilers. The first two tasks of this six-task project-jointly sponsored by EPRI and the U.S. Department of Energy (DE-FC26-07NT43096)-have focused on computational modeling of an advanced MCrAl nanocoating system and evaluation of two nanocrystalline (iron and nickel base) coatings, which will significantly improve the corrosion and erosion performance of tubing used in USC boilers. The computational model results showed that about 40 wt.% is required in Fe based nanocrystalline coatings for long-term durability, leading to a coating composition of Fe-25Cr-40Ni-10 wt.% Al. In addition, the long term thermal exposure test results further showed accelerated inward diffusion of Al from the nanocrystalline coatings into the substrate. In order to enhance the durability of these coatings, it is necessary to develop a diffusion barrier interlayer coating such TiN and/or AlN. The third task 'Process Advanced MCrAl Nanocoating Systems' of the six-task project jointly sponsored by the Electric Power Research Institute, EPRI and the U.S. Department of Energy (DE-FC26-07NT43096)- has focused on

  4. A STUDY OF MARINE FOULING IN MONTEREY HARBOR.

    Science.gov (United States)

    PIERS, *FOULING, *HARBORS, *MARINE BIOLOGY, CALIFORNIA, PACIFIC OCEAN, NAVAL RESEARCH, CRUSTACEA, ANIMALS, PERIODIC VARIATIONS, ENVIRONMENTAL TESTS, TIME, DISTRIBUTION, SEA WATER, PLATYHELMINTHES , OCEANOGRAPHIC DATA.

  5. Sedimentation and fouling of optical surfaces at the ANTARES site

    Science.gov (United States)

    ANTARES Collaboration; CAU CEFREM Collaboration; Amram, P.; Anghinolfi, M.; Anvar, S.; Ardellier-Desages, F. E.; Aslanides, E.; Aubert, J.-J.; Azoulay, R.; Bailey, D.; Basa, S.; Battaglieri, M.; Bellotti, R.; Beltramelli, J.; Benhammou, Y.; Berthier, R.; Bertin, V.; Billault, M.; Blaes, R.; Bland, R. W.; Blondeau, F.; de Botton, N.; Boulesteix, J.; Brooks, C. B.; Brunner, J.; Cafagna, F.; Calzas, A.; Capone, A.; Caponetto, L.; Cârloganu, C.; Carmona, E.; Carr, J.; Cartwright, S. L.; Cecchini, S.; Ciacio, F.; Circella, M.; Compère, C.; Cooper, S.; Coyle, P.; Cuneo, S.; Danilov, M.; van Dantzig, R.; de Marzo, C.; Destelle, J.-J.; de Vita, R.; Dispau, G.; Druillole, F.; Engelen, J.; Feinstein, F.; Ferdi, C.; Festy, D.; Fopma, J.; Gallone, J.-M.; Giacomelli, G.; Goret, P.; Gournay, J.-F.; Hallewell, G.; Heijboer, A.; Hernández-Rey, J. J.; Hubbard, J. R.; Jaquet, M.; de Jong, M.; Karolak, M.; Keller, P.; Kooijman, P.; Kouchner, A.; Kudryavtsev, V. A.; Lafoux, H.; Lagier, P.; Lamare, P.; Languillat, J.-C.; Laubier, L.; Laugier, J.-P.; Leilde, B.; Le Provost, H.; Le van Suu, A.; Lo Nigro, L.; Lo Presti, D.; Loucatos, S.; Louis, F.; Lyashuk, V.; Magnier, P.; Marcelin, M.; Margiotta, A.; Masullo, R.; Mazéas, F.; Mazeau, B.; Mazure, A.; McMillan, J. E.; Migneco, E.; Millot, C.; Mols, P.; Montanet, F.; Montaruli, T.; Moscoso, L.; Musumeci, M.; Nezri, E.; Nooren, G. J.; Oberski, J. E. J.; Olivetto, C.; Oppelt-Pohl, A.; Palanque-Delabrouille, N.; Papaleo, R.; Payre, P.; Perrin, P.; Petruccetti, M.; Petta, C.; Piattelli, P.; Poinsignon, J.; Potheau, R.; Queinec, Y.; Racca, C.; Raia, G.; Randazzo, N.; Rethore, F.; Riccobene, G.; Ricol, J.-S.; Ripani, M.; Roca-Blay, V.; Romeyer, A.; Rostovstev, A.; Russo, G. V.; Sacquin, Y.; Salusti, E.; Schuller, J.-P.; Schuster, W.; Soirat, J.-P.; Souvorova, O.; Spooner, N. J. C.; Spurio, M.; Stolarczyk, T.; Stubert, D.; Taiuti, M.; Tao, C.; Thompson, L. F.; Tilav, S.; Triay, R.; Usik, A.; Valdy, P.; Valente, V.; Varlamov, I.; Vaudaine, G.; Vernin, P.; Vladimirsky, E.; Vorobiev, M.; de Witt Huberts, P.; de Wolf, E.; Zakharov, V.; Zavatarelli, S.; Zornoza, Juan de Dios; Zún~Iga, J.; Aloïsi, J.-C.; Kerhervé, Ph.; Monaco, A.

    2003-05-01

    ANTARES is a project leading towards the construction and deployment of a neutrino telescope in the deep Mediterranean Sea. The telescope will use an array of photomultiplier tubes to detect the Cherenkov light emitted by muons resulting from the interaction with matter of high energy neutrinos. In the vicinity of the deployment site the ANTARES Collaboration has performed a series of in situ measurements to study the change in light transmission through glass surfaces during immersions of several months. The average loss of light transmission is estimated to be only ~2% at the equator of a glass sphere one year after deployment. It decreases with increasing zenith angle, and tends to saturate with time. The transmission loss, therefore, is expected to remain small for the several year lifetime of the ANTARES detector whose optical modules are oriented downwards. The measurements were complemented by the analysis of the 210Pb activity profile in sediment cores and the study of biofouling on glass plates. Despite a significant sedimentation rate at the site, in the 0.02-0.05 cmyr-1 range, the sediments adhere loosely to the glass surfaces and can be washed off by water currents. Further, fouling by deposits of light-absorbing particulates is only significant for surfaces facing upwards.

  6. Low excess air operations of oil boilers

    Energy Technology Data Exchange (ETDEWEB)

    Butcher, T.A.; Celebi, Y.; Litzke, Wai Lin [Brookhaven National Labs., Upton, NY (United States)

    1997-09-01

    To quantify the benefits which operation at very low excess air operation may have on heat exchanger fouling BNL has recently started a test project. The test allows simultaneous measurement of fouling rate, flue gas filterable soot, flue gas sulfuric acid content, and flue gas sulfur dioxide.

  7. Superheater Tube Flat Wall Stationary Temperature Field

    Directory of Open Access Journals (Sweden)

    Parpiev A.T.

    2016-01-01

    Full Text Available The BKZ-220-100-9 steam generator platen superheater tube flat wall stationary temperature fields analysis have been made. The six steel grades, using in boiler fabrication, namely, St. 10, St. 20, 12H1MF, 15HM, 1H18N9T and 12H18N12T, have been used. The temperature curves calculation has been made by using outer and inner surface heat-transfer coefficients nine different combinations.

  8. Development of Empirical Correlation to Calculate Pool Boiling Heat Transfer of Tandem Tubes

    Energy Technology Data Exchange (ETDEWEB)

    Kang, Myeong-Gie [Andong National University, Andong (Korea, Republic of)

    2015-10-15

    The heat exchanging tubes are in vertical alignment. For the cases, the upper tube is affected by the lower tube. Since heat transfer is closely related to the conditions of tube surface, bundle geometry, and liquid, lots of studies have been carried out for the several decades to investigate the combined effects of those factors on pool boiling heat transfer. One of the most important parameters in the analysis of a tube array is the pitch ( P ) between tubes. Many researchers have been investigated its effect on heat transfer enhancement for the tube bundles and the tandem tubes. The effect of a tube array on heat transfer enhancement was also studied for application to the flooded evaporators. Cornwell and Schuller studied the sliding bubbles by high speed photography to account the enhancement of heat transfer observed at the upper tubes of a bundle. The study by Memory et al. shows the effects of the enhanced surface and oil adds to the heat transfer of tube bundles. They identified that, for the structured and porous bundles, oil addition leads to a steady decrease in performance. The flow boiling of n-pentane across a horizontal tube bundle was investigated experimentally by Roser et al. They identified that convective evaporation played a significant part of the total heat transfer. The fouling of the tube bundle under pool boiling was also studied by Malayeri et al. They identified that the mechanisms of fouling on the middle and top heater substantially differ from those at the bottom heater.

  9. Full Scale Deposition Trials at 150 MWe PF-boiler Co-firing COal and Straw: Summary of Results

    DEFF Research Database (Denmark)

    Andersen, Karin Hedebo; Frandsen, Flemming; Hansen, Peter Farkas Binderup

    1999-01-01

    . In the visual analysis, a significant increase in amount and tenacity of primarily the upstream deposit was observed as a function of increased straw share, exposure time and/or boiler load.The chemical analysis of the deposits suggest an increased participation of K and S in the formation of the deposits...... for the coal types utilised in the tests.The deposit formation observed during co-firing with up to 20% straw (energy basis), does not lead to fouling and slagging problems which cannot be overcome by increased sootblowing when firing the two coals used in the demonstration programme. However, slagging...

  10. Development of Erosion-Corrosion-Resistant Cold-Spray Nanostructured Ni-20Cr Coating for Coal-Fired Boiler Applications

    Science.gov (United States)

    Kumar, M.; Singh, H.; Singh, N.; Chavan, N. M.; Kumar, S.; Joshi, S. V.

    2015-12-01

    The erosion-corrosion (E-C) behavior of a cold-spray nanostructured Ni-20Cr coating was studied under cyclic conditions in a coal-fired boiler. This study was done for 15 cycles (1500 h), in which each cycle comprised 100 h of heating in the boiler environment, followed by 1 h of cooling under ambient air conditions. The E-C extent was evaluated in terms of thickness loss data of the samples. The eroded-corroded samples were characterized using XRD, SEM/EDS, and x-ray mapping analyses. The nanostructured coating offered excellent E-C protection to boiler tube material (SA 516 steel) under harsh live conditions of the boiler. This E-C resistance offered by investigated coating may be attributed to the presence of protective NiO and Cr2O3 phases in its oxide scale and its superior as-sprayed microhardness.

  11. A two-parameter preliminary optimization study for a fluidized-bed boiler through a comprehensive mathematical simulator

    Energy Technology Data Exchange (ETDEWEB)

    Rabi, Jose A.; Souza-Santos, Marcio L. de [Universidade Estadual de Campinas, SP (Brazil). Faculdade de Engenharia Mecanica. Dept. de Energia]. E-mails: jrabi@fem.unicamp.br; dss@fem.unicamp.br

    2000-07-01

    Modeling and simulation of fluidized-bed equipment have demonstrated their importance as a tool for design and optimization of industrial equipment. Accordingly, this work carries on an optimization study of a fluidized-bed boiler with the aid of a comprehensive mathematical simulator. The configuration data of the boiler are based on a particular Babcock and Wilcox Co. (USA) test unit. Due to their importance, the number of tubes in the bed section and the air excess are chosen as the parameters upon which the optimization study is based. On their turn, the fixed-carbon conversion factor and the boiler efficiency are chosen as two distinct optimization objectives. The results from both preliminary searches are compared. The present work is intended to be just a study on possible routes for future optimization of larger boilers. Nonetheless, the present discussion might give some insight on the equipment behavior. (author)

  12. 46 CFR 52.25-20 - Exhaust gas boilers.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 2 2010-10-01 2010-10-01 false Exhaust gas boilers. 52.25-20 Section 52.25-20 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) MARINE ENGINEERING POWER BOILERS Other Boiler Types § 52.25-20 Exhaust gas boilers. Exhaust gas boilers with a maximum allowable working...

  13. Final Report, Materials for Industrial Heat Recovery Systems, Tasks 3 and 4 Materials for Heat Recovery in Recovery Boilers

    Energy Technology Data Exchange (ETDEWEB)

    Keiser, James R.; Kish, Joseph R.; Singh, Preet M.; Sarma, Gorti B.; Yuan, Jerry; Gorog, J. Peter; Frederick, Laurie A.; Jette, Francois R.; Meisner, Roberta A.; Singbeil, Douglas L.

    2007-12-31

    The DOE-funded project on materials for industrial heat recovery systems included four research tasks: materials for aluminum melting furnace recuperator tubes, materials and operational changes to prevent cracking and corrosion of the co-extruded tubes that form primary air ports in black liquor recovery boilers, the cause of and means to prevent corrosion of carbon steel tubes in the mid-furnace area of recovery boilers, and materials and operational changes to prevent corrosion and cracking of recovery boiler superheater tubes. Results from studies on the latter two topics are given in this report while separate reports on results for the first two tasks have already been published. Accelerated, localized corrosion has been observed in the mid-furnace area of kraft recovery boilers. This corrosion of the carbon steel waterwall tubes is typically observed in the vicinity of the upper level of air ports where the stainless clad co-extruded wall tubes used in the lower portion of the boiler are welded to the carbon steel tubes that extend from this transition point or “cut line” to the top of the boiler. Corrosion patterns generally vary from one boiler to another depending on boiler design and operating parameters, but the corrosion is almost always found within a few meters of the cut line and often much closer than that. This localized corrosion results in tube wall thinning that can reach the level where the integrity of the tube is at risk. Collection and analysis of gas samples from various areas near the waterwall surface showed reducing and sulfidizing gases were present in the areas where corrosion was accelerated. However, collection of samples from the same areas at intervals over a two year period showed the gaseous environment in the mid-furnace section can cycle between oxidizing and reducing conditions. These fluctuations are thought to be due to gas flow instabilities and they result in an unstable or a less protective scale on the carbon steel

  14. Hydraulically irreversible fouling on ceramic MF/UF membranes: comparison of fouling indices, foulant composition and irreversible pore narrowing

    KAUST Repository

    Shang, Ran

    2015-05-06

    The application of ceramic membranes in water treatment is becoming increasing attractive because of their long life time and excellent chemical, mechanical and thermal stability. However, fouling of ceramic membranes, especially hydraulically irreversible fouling, is still a critical aspect affecting the operational cost and energy consumption in water treatment plants. In this study, four ceramic membranes with pore sizes or molecular weight cut-off (MWCO) of 0.20 μm, 0.14 μm, 300 kDa and 50 kDa were compared during natural surface water filtration with respect to hydraulically irreversible fouling index (HIFI), foulant composition and narrowing of pore size due to the irreversible fouling. Our results showed that the hydraulically irreversible fouling index (HIFI) was proportional to the membrane pore size (r2=0.89) when the same feed water was filtrated. The UF membranes showed lower HIFI values than the MF membranes. Pore narrowing (internal fouling) was found to be a main fouling pattern of the hydraulically irreversible fouling. The internal fouling was caused by monolayer adsorption of foulants with different sizes that is dependent on the size of the membrane pore.

  15. High Temperature Behavior of Cr3C2-NiCr Coatings in the Actual Coal-Fired Boiler Environment

    Science.gov (United States)

    Bhatia, Rakesh; Sidhu, Hazoor Singh; Sidhu, Buta Singh

    2015-03-01

    Erosion-corrosion is a serious problem observed in steam-powered electricity generation plants, and industrial waste incinerators. In the present study, four compositions of Cr3C2-(Ni-20Cr) alloy coating powder were deposited by high-velocity oxy-fuel spray technique on T-91 boiler tube steel. The cyclic studies were performed in a coal-fired boiler at 1123 K ± 10 K (850 °C ± 10 °C). X-ray diffraction, scanning electron microscopy/energy dispersive X-ray analysis and elemental mapping analysis techniques were used to analyze the corrosion products. All the coatings deposited on T-91 boiler tube steel imparted hot corrosion resistance. The 65 pctCr3C2 -35 pct (Ni-20Cr)-coated T-91 steel sample performed better than all other coated samples in the given environment.

  16. Inception report and gap analysis. Boiler inspection

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2004-06-01

    This inception and gap analysis report on boilers in Latvia, has been prepared in the framework of the 'Implementation of the EU directive on energy performance of buildings: development of the Latvian Scheme for energy auditing of building and inspection of boilers'. The report is the basis for the establishment of training of boiler inspectors; it develops a gap analysis for better understanding and estimating the number of installations in Latvia and develops suggestions for the institutional set up. In particular includes information on existing standard and regulation on boiler, suggestion for the content of the training material of experts for boiler inspections and a syllabus of the training course. A specific section is dedicated to the suggestion for certification system of trained boiler inspectors. (au)

  17. Black liquor combustion validated recovery boiler modeling: Final year report. Volume 2 (Appendices I, section 5 and II, section 1)

    Energy Technology Data Exchange (ETDEWEB)

    Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

    1998-08-01

    This project was initiated in October 1990, with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. The key tasks to be accomplished were as follows: (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes. (2) Validate the enhanced furnace models, so that users can have confidence in the predicted results. (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler. (4) Facilitate the transfer of codes, black liquid submodels, and fundamental knowledge to the US kraft pulp industry. Volume 2 contains the last section of Appendix I, Radiative heat transfer in kraft recovery boilers, and the first section of Appendix II, The effect of temperature and residence time on the distribution of carbon, sulfur, and nitrogen between gaseous and condensed phase products from low temperature pyrolysis of kraft black liquor.

  18. Fouling Kinetics and Associated Dynamics of Structural Modifications

    DEFF Research Database (Denmark)

    Jacob, Jerome; Prádanos, Pedro; Calvo, J. I.;

    1998-01-01

    by Sartorius (ST02 and ST045, neutral) and Spectrum (SP02 and SP045, positively charged) when fouled by permeating a protein aqueous solution (bovine serum albumin (BSA) at 1 g l(-1)) under 10 kPa in a dead-end device. The structure after different fouling times is obtained by using an extended bubble point...

  19. CFD Simulation On CFBC Boiler

    OpenAIRE

    Amol S. Kinkar; G. M. Dhote; R.R. Chokkar

    2015-01-01

    Abstract Heavy industrialization amp modernization of society demands in increasing of power cause to research amp develop new technology amp efficient utilization of existing power units. Variety of sources are available for power generation such as conventional sources like thermal hydro nuclear and renewable sources like wind tidal biomass geothermal amp solar. Out of these most common amp economical way for producing the power is by thermal power stations. Various industrial boilers plays...

  20. Energy storage-boiler tank

    Science.gov (United States)

    Chubb, T. A.; Nemecek, J. J.; Simmons, D. E.

    1980-01-01

    Activities performed in an effort to demonstrate heat of fusion energy storage in containerized salts are reported. The properties and cycle life characteristics of a eutectic salt having a boiling point of about 385 C (NaCl, KCl, Mg Cl2) were determined. M-terphenyl was chosen as the heat transfer fluid. Compatibility studies were conducted and mild steel containers were selected. The design and fabrication of a 2MWh storage boiler tank are discussed.

  1. Equilibrium-phase precipitation behaviors of typical nickel-base alloys for 700 ℃ advanced ultra-supercritical boiler tubes%700℃以上超超临界电站锅炉过热器管材用典型镍基合金的平衡析出相规律

    Institute of Scientific and Technical Information of China (English)

    王珏; 董建新; 张麦仓; 谢锡善

    2012-01-01

    Thermodynamic equilibrium phase diagrams of three candidate materials, Incone1740, Inconel617, and GH2984, for 700 ℃ advanced ultra-supercritical boiler tubes were calculated by Thermo-Cale software and nickel-base alloy databases. Precipitation behaviors of phases in the three alloys were investigated by comparison. There are similar equilibrium phases in the three alloys, inclu- dingγ, γ', carbides, α,η , δ, μ, and α-Cr. Serious segregations of No, Ti and Nb may occur during solidification based on the calculation, which would decrease the initial melting points of the three alloys; therefore the consequent homogenization treatment is quite important. On the other hand, the amount of γ' precipitated in Incone1740 is higher than that in the other two alloys at 750 ℃. A1 and Ti eontents can strongly effeet the precipitation of γ and γ phases. The calculation of carbides indicates that primary carbides in Ineonel617 are different from those in the other two alloys, and the precipitation temperature range of secondary carbides in Ineonel617 is larger. The presence of of in GH2984 alloy is harmful to the rneehanical orooerties due to a higher Po enntont%利用热力学计算软件Thermo--Calc及镍基合金数据库,计算了三种700℃以上超超临界电站用过热器管道材料Inconel740、Inconel617和GH2984合金的热力学平衡相图,并对比了三种材料主要析出相的析出行为.计算结果表明:三种合金主要的析出相包括γ、γ'、碳化物、σ、η、δ、μ及α--Cr等,凝固过程中Mo、Nb和Ti元素偏析严重,会降低合金的初熔点,因此后期均匀化退火处理十分重要.另一方面,750℃时Inconel740合金γ'相析出量大于另外两种合金,并且Al和Ti含量对γ'相和η相析出行为有较大影响.碳化物的计算表明,Inconel617合金一次碳化物与另两种合金不同,并且其二次碳化物的析出温度范围最大.GH2984合金中Fe含量较大时会导致σ相出

  2. 等离子喷涂工艺对锅炉管束用Fe基非晶涂层组织结构和耐蚀性能的影响%Effect of Spray Process on the Microstructure and Corrosion-resistance of Fe-based Amorphous Coatings Obtained by Plasma Spray on the Boiler Tubes

    Institute of Scientific and Technical Information of China (English)

    高振; 郝建民; 韩建军; 鲁元; 陈永楠; 李世波

    2015-01-01

    ABSTRACT:Objective To investigate the effects of plasma spray power and time on the phase, microstructure and corrosion-re-sistance of the amorphous coating on the boiler tubes. Methods XRD, SEM and electrochemical polarization research were adopt-ed. Results The coating with high fraction of amorphous phase was obtained, which had a flat and compact surface. The amorphous fraction and porosity decreased and the density increased with the increasing spray power and time. The coatings exhibited an excel-lent ability to resist corrosion with wide passive region in 0. 5 mol/L H2 SO4 and 3. 5% NaCl solutions. And the coatings exhibited wider passive region and lower corrosion current density in 0. 5 mol/L H2 SO4 and 3. 5% NaCl solutions, respectively. With in-crease of the spray power and time, the anodic polarization curves of the amorphous coatings were passivated with wider passive re-gion and lower passive current density. Conclusion The path and flow resistance that corrosive liquid permeated the substrate were increased, and the corrosion resistance of the coating was improved, owing to the decreased porosity and increased coating thick-ness with the increasing spray power and time.%目的:研究等离子喷涂功率和喷涂时间对锅炉管束用Fe基非晶涂层的相组成、微观组织结构及涂层耐蚀性能的影响。方法通过X射线衍射、扫描电子显微镜和三电极电化学研究进行分析。结果涂层主要由非晶相组成,表面较为平整致密;随着喷涂功率和喷涂时间的增加,涂层非晶相含量降低,孔隙率降低,致密性升高。非晶涂层在0.5 mol/L H2SO4溶液和在3.5%(质量分数)NaCl溶液中均表现出良好的钝化作用,在0.5 mol/L H2 SO4溶液中钝化区较宽,在3.5%NaCl溶液中自腐蚀电流密度较低。随喷涂功率和时间的增加,阳极极化曲线钝化区加宽,电流密度降低。结论喷涂功率升高会导致涂层孔隙率下降

  3. Research of Boiler Combustion Regulation for Reducing Nox Emission and its Effect on Boiler Efficiency

    Institute of Scientific and Technical Information of China (English)

    WANG Xue-dong; LUAN Tao; CHENG Lin; XIAO Kun

    2007-01-01

    The effect of boiler combustion regulation on Nox emission of two 1025t/h boilers has been studied. The researches show that Nox emission is influenced by coal species, operation conditions, etc, and can be reduced by regulating the combustion conditions. The effect of combustion regulation on boiler efficiency has also been checked.

  4. FOULING DETECTION IN FOOD VESSELS USING INTERDIGITAL LAMB WAVE TRANSDUCER

    Institute of Scientific and Technical Information of China (English)

    JIAO Jingpin; GE Haiyan; WU Bin; HE Cunfu

    2007-01-01

    Lamb waves are used to detect fouling in food vessels. The propagation of the Lamb waves in plates exhibits many modes and dispersion characteristics, which have great influence on fouling detection. The relative distribution of the in-plane and out-of-plane displacement of the mode across the thickness of the plate will determine the sensitivity of the mode to a particular loading condition. By considering the dispersion and multi-mode characteristics of guided waves, an interdigital polyvinylidene fluoride (PVDF) transducer is designed to realize the mode selection of guided waves, and a single α0 mode is used for guided wave detection. Fouling detection experiments are conducted in the laboratory using epoxy adhesive on a thin plate. Using the interdigital PVDF transducer, three fouled areas are detected. Using one of the time-frequency analysis methods, the waveforms are further processed. This also demonstrates the validity of this method of fouling detection.

  5. WASTE HEAT RECOVERY FROM BOILER OF LARGE-SCALE TEXTILE INDUSTRY

    Directory of Open Access Journals (Sweden)

    Prateep Pattanapunt

    2013-01-01

    Full Text Available Many industrial heating processes generate waste energy in textile industry; especially exhaust gas from the boiler at the same time reducing global warming. Therefore, this article will present a study the way to recovery heat waste from boiler exhaust gas by mean of shell and tube heat exchanger. Exhaust gas from boiler dyeing process, which carries a large amount of heat, energy consumptions could be decrease by using of waste-heat recovery systems. In this study, using ANASYS simulation performs a thermodynamics analysis. An energy-based approach is performed for optimizing the effective working condition for waste-heat recovery with exhaust gas to air shell and tube heat exchanger. The variations of parameters, which affect the system performance such as, exhaust gas and air temperature, velocity and mass flow rate and moisture content is examined respectively. From this study, it was found that heat exchanger could be reduced temperature of exhaust gases and emission to atmosphere and the time payback is the fastest. The payback period was determined about 6 months for investigated ANSYS. The air is circulated in four passes from the top to the bottom of the test section, in overall counter-flow with exhaust gas. The front area is 1720×1720 mm, the flow length 7500 mm, the inner and outer diameter of exhaust gas is 800 mm, the tube assembly consist of 196 tubes, the tube diameter is 76.2 mm, the tube thickness is 2.6 mm, the tube length is 4500 mm, the tube length of air inner and outer is 500 mm. The result show that, the boiler for superheated type there are exhaust gas temperature is 190°C, 24% the moisture content of fuel and there are palm kernel shell 70 tons day-1 which there are the high temperature after the heat exchanger, 150°C. It was occurred acid rain. The hot air from heat exchanger process can be reduced the moisture of palm kernel shell fuel to 15%.The fuel consumption is reduced by about 2.05% (322.72 kJ kg-1

  6. Organic Fouling of Graphene Oxide Membranes and Its Implications for Membrane Fouling Control in Engineered Osmosis.

    Science.gov (United States)

    Hu, Meng; Zheng, Sunxiang; Mi, Baoxia

    2016-01-19

    This study provides experimental evidence to mechanistically understand some contradicting effects of the characteristic properties of graphene oxide (GO), such as the high hydrophilicity, negative charge, strong adsorption capability, and large surface area, on the antifouling properties of GO membranes. Furthermore, this study demonstrates the effectiveness of forming a dense GO barrier layer on the back (i.e., porous) side of an asymmetric membrane for fouling control in pressure-retarded osmosis (PRO), an emerging engineered osmosis process whose advancement has been much hindered due to the severe irreversible fouling that occurs as foulants accumulate inside the porous membrane support. In the membrane fouling experiments, protein and alginate were used as model organic foulants. When operated in forward osmosis mode, the GO membrane exhibited fouling performance comparable with that of a polyamide (PA) membrane. Analysis of the membrane adsorption capacity showed that, likely due to the presence of hydrophobic regions in the GO basal plane, the GO membrane has an affinity toward organic foulants 4 to 5 times higher than the PA membrane. Such a high adsorption capacity along with a large surface area, however, did not noticeably aggravate the fouling problem. Our explanation for this phenomenon is that organic foulants are adsorbed mainly on the basal plane of GO nanosheets, and water enters the GO membrane primarily around the oxidized edges of GO, making foulant adsorption not create much hindrance to water flux. When operated in PRO mode, the GO membrane exhibited much better antifouling performance than the PA membrane. This is because unlike the PA membrane for which foulants can be easily trapped inside the porous support and hence cause severe irreversible fouling, the GO membrane allows the foulants to accumulate primarily on its surface due to the sealing effect of the GO layer assembled on the porous side of the asymmetric membrane support. Results

  7. World largest KAWASAKI KJ type soda recovery boiler, generating high pressure and high temperature steam. For the Iwakuni mill of Nippon Paper Industries Co. Ltd.; Sekai saidaikyu no koatsu koon soda kaishu boiler. Nippon seishi (kabu) Iwakuni kojo dono muke

    Energy Technology Data Exchange (ETDEWEB)

    Hirokawa, M.; Matsuda, T.; Masuda, T.; Suemitsu, N.; Makito, Y.; Tanihara, T.; Asada, S. [Kawasaki Heavy Industries, Ltd., Kobe (Japan)

    1996-10-15

    This paper presents the important notices in design and issues on the large KAWASAKI KJ type soda recovery boiler under construction for the Iwakuni mill of Nippon Paper Industries Co., Ltd. This soda recovery boiler is the largest one in volume in Japan, and the highest one in pressure and temperature in the world. Since saturation temperature rises with steam pressure, corrosion resistance of the water cooling wall of a combustion chamber should be considered enough. This boiler thus adopts the double contact tube with an outer tube of SUS310 most superior in corrosion resistance. Alkaline molten salt corrosion of a superheater is one of the most severe problems on steam temperature rise. This boiler thus adopts SUS309J2TB superior in alkaline molten salt corrosion resistance for the highest-temperature portion of a superheater and the lower U bent subjected to radiant heat from a combustion chamber. Flow in a furnace and stress of a superheater were analyzed using computer for scale-up of boiler and preliminary verification. 1 ref., 14 figs., 2 tabs.

  8. Black liquor combustion validated recovery boiler modeling: Final year report. Volume 1 (Main text and Appendix I, sections 1--4)

    Energy Technology Data Exchange (ETDEWEB)

    Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

    1998-08-01

    This project was initiated in October 1990, with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. The key tasks to be accomplished were as follows: (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes. (2) Validate the enhanced furnace models, so that users can have confidence in the predicted results. (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler. (4) Facilitate the transfer of codes, black liquid submodels, and fundamental knowledge to the US kraft pulp industry. Volume 1 contains the main body of the report and the first 4 sections of Appendix 1: Modeling of black liquor recovery boilers -- summary report; Flow and heat transfer modeling in the upper furnace of a kraft recovery boiler; Numerical simulation of black liquor combustion; and Investigation of turbulence models and prediction of swirling flows for kraft recovery furnaces.

  9. Model performance of a biomass-fueled power station with variable furnace exit gas temperature to control fouling deposition

    Science.gov (United States)

    Yomogida, David Edwin

    A major problem associated with the utilization of any biomass fuel in direct-combustion energy production is fouling (ash deposition on boiler surfaces) and the related issue of slagging, resulting from transformations among the inorganic constituents of the fuel. These deposits reduce heat transfer from the fire- to water-side, reducing power plant efficiency and necessitating the design of more tolerant heat exchange equipment. Wood: currently serves as the major source of fuel in biomass conversion to energy because of its more general availability, and it suffers less from fouling and slagging than many other biomass fuels such as rice straw. To reduce fouling severity, furnace exit gas temperature (FEGT) may be decreased to solidify ash ahead of superheaters and other heat exchanger equipment. Thermal and economic computer models of a direct-combustion Rankine cycle power plant were developed to predict the impact of variable FEGT and overall heat transfer coefficient on power plant efficiency and economy. No attempt was made to model the fire-side processes leading to the formation of fouling deposits. A base case: operational and economic profile of a biomass power plant was established, and models, were executed using these parameters, approximating a power plant efficiency of 19.9% and a cost of electricity (COE) of 0.0636 kWh-1 (including capital costs). If no capital, costs are included, then COE is 0.0205 kWh-1. Sensitivity analyses were performed on power plant efficiency and COE. Changes in FEGT through variable excess air resulted in substantial sensitivity in power plant efficiency (plant efficiency of 21.4% for FEGT of 1030°C (5% excess air) and 18.7% for 924°C (55% excess air)). Plant efficiency was determined to be moderately sensitive to changes in overall heat transfer coefficient on the secondary superheater (18.7% for no heat transfer through secondary superheater and 19.9% for base case heat transfer). Fouling scenarios showed that FEGT

  10. Investigations on the Behavior of HVOF and Cold Sprayed Ni-20Cr Coating on T22 Boiler Steel in Actual Boiler Environment

    Science.gov (United States)

    Bala, Niraj; Singh, Harpreet; Prakash, Satya; Karthikeyan, J.

    2012-01-01

    High temperature corrosion accompanied by erosion is a severe problem, which may result in premature failure of the boiler tubes. One countermeasure to overcome this problem is the use of thermal spray protective coatings. In the current investigation high velocity oxy-fuel (HVOF) and cold spray processes have been used to deposit commercial Ni-20Cr powder on T22 boiler steel. To evaluate the performance of the coatings in actual conditions the bare as well as the coated steels were subjected to cyclic exposures, in the superheater zone of a coal fired boiler for 15 cycles. The weight change and thickness loss data were used to establish kinetics of the erosion-corrosion. X-ray diffraction, surface and cross-sectional field emission scanning electron microscope/energy dispersive spectroscopy (FE-SEM/EDS) and x-ray mapping techniques were used to analyse the as-sprayed and corroded specimens. The HVOF sprayed coating performed better than its cold sprayed counterpart in actual boiler environment.

  11. Seasonal variations in fouling diatom communities on the Yantai coast

    Science.gov (United States)

    Yang, Cuiyun; Wang, Jianhua; Yu, Yang; Liu, Sujing; Xia, Chuanhai

    2015-03-01

    Fouling diatoms are a main component of biofilm, and play an important role in marine biofouling formation. We investigated seasonal variations in fouling diatom communities that developed on glass slides immersed in seawater, on the Yantai coast, northern Yellow Sea, China, using microscopy and molecular techniques. Studies were conducted during 2012 and 2013 over 3, 7, 14, and 21 days in each season. The abundance of attached diatoms and extracellular polymeric substances increased with exposure time of the slides to seawater. The lowest diatom density appeared in winter and the highest species richness and diversity were found in summer and autumn. Seasonal variation was observed in the structure of fouling diatom communities. Pennate diatoms Cylindrotheca, Nitzschia, Navicula, Amphora, Gomphonema, and Licmophora were the main fouling groups. Cylindrotheca sp. dominated in the spring. Under laboratory culture conditions, we found that Cylindrotheca grew very fast, which might account for the highest density of this diatom in spring. The lower densities in summer and autumn might result from the emergence of fouling animals and environmental factors. The Cylindrotheca sp. was identified as Cylindrotheca closterium using18S rDNA sequencing. The colonization process of fouling diatoms and significant seasonal variation in this study depended on environmental and biological factors. Understanding the basis of fouling diatoms is essential and important for developing new antifouling techniques.

  12. Loss of feed flow, steam generator tube rupture and steam line break thermohydraulic experiments

    Energy Technology Data Exchange (ETDEWEB)

    Mendler, O J; Takeuchi, K; Young, M Y

    1986-10-01

    The Westinghouse Model Boiler No. 2 (MB-2) steam generator test model at the Engineering Test Facility in Tampa, Florida, was reinstrumented and modified for performing a series of tests simulating steam generator accident transients. The transients simulated were: loss of feed flow, steam generator tube rupture, and steam line break events. This document presents a description of (1) the model boiler and the associated test facility, (2) the tests performed, and (3) the analyses of the test results.

  13. 46 CFR 109.555 - Propulsion boilers.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 4 2010-10-01 2010-10-01 false Propulsion boilers. 109.555 Section 109.555 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) A-MOBILE OFFSHORE DRILLING UNITS OPERATIONS Miscellaneous § 109.555 Propulsion boilers. The master or person in charge and the engineer in charge...

  14. Tubulo - a train-like miniature inspection climbing robot for ferromagnetic tubes

    OpenAIRE

    Schoeneich, Patrick; Rochat, Frédéric; Truong-Dat Nguyen, Olivier; Caprari, Gilles; Moser, Roland; Bleuler, Hannes; Mondada, Francesco

    2010-01-01

    A train-like miniature climbing inspection robot for ferromagnetic tubes is presented in this paper. Using magnetic wheels, it climbs in tubes of 25 mm of diameter and bigger in any orientation, and pass bends with curvatures above 150 mm in some cases. It has embedded electronics and energy, and can transmit images through a cable. Applications are in tubes inspections as found in power plant boilers for example.

  15. Fouling and slagging problems at recovered wood fuel combustion; Orsaker till askrelaterade driftproblem vid eldning av returtraeflis

    Energy Technology Data Exchange (ETDEWEB)

    Andersson, Christer; Hoegberg, Jan [Vattenfall Utveckling AB, Stockholm (Sweden)

    2001-03-01

    CHP-plants that use a large portion of sorted wood waste fuel can face ash-related problems. By analysing the circumstances about these problems, the goal is to find causes for the problems and measures that can be taken. This knowledge can then be utilised in plants where it is desired to increase the portion of sorted wood waste fuel. For the measurements, a deposit probe is a good tool to use since the result is independent of many boiler-specific factors. Compared with forest residues, sorted wood waste causes a more problematic ash. The risk of troublesome fouling and corrosion seems to increase with increased admixture of sorted wood waste fuel. Plugging of the grate is associated with melts that are formed from metallic contamination in the fuel. These melts obstruct the air holes. The melts that have been seen during the project have had a content of aluminium, brass and zinc. In order to solve these problems, the construction and cooling of the grate and quality assurance of the fuel are important aspects. One problem that was found in all of the studied boilers (grates as well as fluidized beds) is growth of fouling on surfaces for heat transfer. Measurements with deposit probe show that the initial growth rate on superheaters are approximately 3 - 5 times higher when sorted wood waste is used than if forest residues is used. Even if this growth rate can not be extrapolated to a complete operating season, the relative difference between the fuels remains. The extent of the problem depends on the dimensioning of the boiler. The fouling tends to have a light outer layer that can be disadvantageous for the absorption of heat radiation. Haendeloe P11 needs for example to be stopped for cleaning with an interval of 2 - 3 months because of lost heat absorption in the furnace and the convection path. The most obvious ash related problem that was found in Haendeloe P11 when 100 % sorted wood waste fuel was used was corrosion on the walls of the lower parts of the

  16. Heat mass transfer model of fouling process of calcium carbonate on heat transfer surface

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    A new heat mass transfer model was developed to predict the fouling process of calcium carbonate on heat transfer surface. The model took into account not only the crystallization fouling but also the particle fouling which was formed on the heat transfer surface by the suspension particles of calcium carbonate in the su- persaturated solution. Based on experimental results of the fouling process, the deposition and removal rates of the mixing fouling were expressed. Furthermore, the coupling effect of temperature with the fouling process was considered in the physics model. As a result the fouling resistance varying with time was obtained to describe the fouling process and the prediction was compared with experimental data under same conditions. The results showed that the present model could give a good prediction of fouling process, and the deviation was less than 15% of the experimental data in most cases. The new model is credible to predict the fouling process.

  17. Membrane fouling in a membrane bioreactor (MBR): sludge cake formation and fouling characteristics.

    Science.gov (United States)

    Ping Chu, Hiu; Li, Xiao-Yan

    2005-05-05

    A submerged membrane bioreactor (MBR) with a working volume of 1.4 L and a hollow fiber microfiltration membrane was used to treat a contaminated raw water supply at a short hydraulic retention time (HRT) of approximately 1 h. Filtration flux tests were conducted regularly on the membrane to determine various fouling resistances, and confocal laser scanning microscopy (CLSM) and scanning electron microscopy (SEM) were employed to characterize the biofouling development and sludge cake formation on the membrane. The experimental results demonstrate that the MBR is highly effective in drinking water treatment for the removal of organic pollutants, ammonia, and UV absorbance. During the MBR operation, the fouling materials were not uniformly distributed on the entire surface of all of the membrane fibers. The membrane was covered partially by a static sludge cake that could not be removed by the shear force of aeration, and partially by a thin sludge film that was frequently washed away by aeration turbulence. The filtration resistance coefficients were 308.4 x 10(11) m(-1) on average for the sludge cake, 32.5 x 10(11) m(-1) on average for the dynamic sludge film, and increased from 10.5 x 10(11) to 59.7 x 10(11) m(-1) for the membrane pore fouling after 10 weeks of MBR operation at a filtration flux of 0.5 m3/m2 x d. Polysaccharides and other biopolymers were found to accumulate on the membrane, and hence decreased membrane permeability. More important, the adsorption of biopolymers on the membrane modified its surface property and led to easier biomass attachment and tighter sludge cake deposition, which resulted in a progressive sludge cake growth and serious membrane fouling. The sludge cake coverage on the membrane can be minimized by the separation, with adequate space, of the membrane filters, to which sufficient aeration turbulence can then be applied.

  18. Developing Boiler Concepts as Integrated Units

    DEFF Research Database (Denmark)

    Sørensen, Kim; Condra, Thomas Joseph; Houbak, Niels

    2004-01-01

    With the objective to be able to optimize the design and operation of steam boiler concepts Aalborg Industries A/S [1] has together with Aalborg University, Institute of Energy Technology [9] carried out a development project paying special attention to the boiler concept as an integrated unit...... - consisting of pressure part, burner and control system. The Technical University of Denmark, MEK - Energy Engineering Section [12] has participated in the modelling process. The project has included static and dynamic modelling of the boiler concept. For optimization of operation, verication of performance......, emissions and to obtain long time operation experiences with the boiler concept, a full scale prototype has been built and these tests have been accomplished on the prototype. By applying this integrated unit approach to the boiler concept development it has been possible to optimize the different building...

  19. Heat transfer to finned tubes exposed to hot waste gas

    Energy Technology Data Exchange (ETDEWEB)

    Scholand, E.; Kremer, H.

    1975-05-01

    Transfer of heat by forced convection to finned tubes, particularly to those with an elliptical center pipe, is described. These pipes are used in gas-fired water heaters, boilers, and heat exchangers. Finned tubes in a test tunnel were exposed to a stream of waste gas from a gas/air mixture at different Reynolds numbers. Mathematical relationships showing the dependence of the Nusselt number on the Reynolds number and on the geometry of the tubes were derived. The single pipe showed a significant drop in the heat-transfer coefficient as the gap between fins became closer. The results of the measurement of heat transfer by forced convection to finned tubes were expressed in a standard form for all tubes. The same heat transfer law can be applied to electrically heated finned tubes exposed to a stream of cooling air.

  20. PAH emission from the industrial boilers.

    Science.gov (United States)

    Li, C; Mi, H; Lee, W; You, W; Wang, Y

    1999-10-01

    Polycyclic aromatic hydrocarbons (PAHs) emitted from 25 industrial boilers were investigated. The fuels used for these 25 boilers included 21 heavy oil, two diesel, a co-combustion of heavy oil and natural gas (HO+NG) and a co-combustion of coke oven gas and blast furnace gas (COG+BFG) boilers. PAH samples from the stack flue gas (gas and particle phases) of these 25 boilers were collected by using a PAH stack sampling system. Twenty one individual PAHs were analyzed primarily by a gas chromatography/mass spectrometer (GC/MS). Total-PAH concentration in the flue gas of 83 measured data for these 25 boiler stacks ranged between 29.0 and 4250 microg/m(3) and averaged 488 microg/m(3). The average of PAH-homologue mass (F%) counted for the total-PAH mass was 54.7%, 9.47% and 15.3% for the 2-ring, 3-ring and 4-ring PAHs, respectively. The PAHs in the stack flue gas were dominant in the lower molecular weight PAHs. The emission factors (EFs) of total-PAHs were 13,300, 2920, 2880 and 208 microg/kg-fuel for the heavy oil, diesel, HO+NG and COG+BFG fueled-boiler, respectively. Nap was the most predominant PAH occurring in the stack flue gas. In addition, the EF of 21 individual PAHs in heavy-oil boiler were almost the highest among the four various fueled-boilers except for those of FL and BkF in the diesel boiler. Furthermore, the EF of total-PAHs or BaP for heavy oil were both one order of magnitude higher than that for the diesel-fueled boiler.

  1. A New Concept of Ultrafiltration Fouling Control: Backwashing with Low Ionic Strength Water

    OpenAIRE

    Li, S.

    2011-01-01

    Ultrafiltration (UF) is a proven technology in water treatment nowadays. However, fouling remains a major challenge in the operation of UF, especially in regard to colloidal NOM fouling. In general, a number of colloidal NOM fouling mechanisms may occur, such as adsorption, gel formation. Colloidal NOM fouling is influenced by multivalent cations, ionic strength and pH. In order to control membrane fouling, different pretreatments such as powder activated carbon adsorption, lime softening, io...

  2. Fouling-resistant polymer brush coatings

    KAUST Repository

    Thérien-Aubin, Héloïse

    2011-11-01

    A major problem to be addressed with thin composite films used in processes such as coatings or water purification is the biofouling of the surface. To address this problem in a model system, functionalized polyaramide membranes containing an atom transfer radical polymerization (ATRP) initiator were synthesized as a versatile approach to easily modify the surface properties of the polyaramide. Poly(methacrylic acid) brushes were grown using surface initiated ATRP followed by the functionalization of the poly(methacrylic acid) brushes with different side-chains chosen to reduce adhesion between the membrane and foulant. The relation between membrane fouling and the physicochemical properties of the surface was investigated in detail. © 2011 Elsevier Ltd. All rights reserved.

  3. NOx Control Options and Integration for US Coal Fired Boilers

    Energy Technology Data Exchange (ETDEWEB)

    Mike Bockelie; Kevin Davis; Temi Linjewile; Connie Senior; Eric Eddings; Kevin Whitty; Larry Baxter; Calvin Bartholomew; William Hecker; Stan Harding; Robert Hurt

    2003-12-31

    This is the fourteenth Quarterly Technical Report for DOE Cooperative Agreement No: DEFC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. Using the initial CFD baseline modeling of the Gavin Station and the plant corrosion maps, six boiler locations for the corrosion probes were identified and access ports have been installed. Preliminary corrosion data obtained appear consistent and believable. In situ, spectroscopic experiments at BYU reported in part last quarter were completed. New reactor tubes have been made for BYU's CCR that allow for testing smaller amounts of catalyst and thus increasing space velocity; monolith catalysts have been cut and a small reactor that can accommodate these pieces for testing is in its final stages of construction. A poisoning study on Ca-poisoned catalysts was begun this quarter. A possible site for a biomass co-firing test of the slipstream reactor was visited this quarter. The slipstream reactor at Rockport required repair and refurbishment, and will be re-started in the next quarter. This report describes the final results of an experimental project at Brown University on the fundamentals of ammonia / fly ash interactions with relevance to the operation of advanced NOx control technologies such as selective catalytic reduction. The Brown task focused on the measurement of ammonia adsorption isotherms on commercial fly ash samples subjected to a variety of treatments and on the chemistry of dry and semi-dry ammonia removal processes.

  4. Erosion-corrosion of plasma as sprayed and laser remelted Stellite-6 coatings in a coal fired boiler

    Energy Technology Data Exchange (ETDEWEB)

    Sidhu, B.S.; Prakash, S. [College of Engineering & Technology, Bathinda (India). Dept. of Mechanical Engineering

    2006-05-31

    Unacceptable levels of surface degradation of metal containment walls and heat exchanger tubing by a combined erosion-corrosion (E-C) mechanism have been experienced in some boilers. The recent use of coatings to protect the heat exchanger tubes of fluidized bed combustor from E-C problems has been suggested by many authors. The laser remelting of the surface coating is suggested as a promising technique to improve its physical properties. Aim of the present investigation is to evaluate the erosion-corrosion (E-C) behaviour of plasma as sprayed and laser remelted Stellite-6 (St-6) coatings on boiler tube steels in the actual coal fired boiler environment. The cyclic experimental studies were performed in the platen superheater zone of a coal fired boiler where the temperature was around 755{sup o}C and the study was carried out up to 10 cycles each of 100 h duration followed by 1 h cooling at ambient temperature. Coated steels were found to possess higher resistance to E-C than the uncoated steels. The highest degradation resistance has been indicated by the T11 steel coated and subsequently laser remelted.

  5. Applicable methods for NDT of tubes

    Energy Technology Data Exchange (ETDEWEB)

    Pitkaenen, J.; Lipponen, A.; Kauppinen, P. [VTT Industrial Systems Espoo (Finland)

    2004-05-01

    For inside inspection of tubes, eddy current testing (ET) and internal rotating ultrasonic inspection (IRIS) are mainly used at the moment. Special eddy current method, remote field technique (RFEC) is being used to some extent, but normally only for ferritic tubes. This paper presents a review of techniques that can be used for internal inspections of tubes in boilers, heat exchangers and steam generators. Material affects the choice of the method, considering given defect type and detectability with the selected technique. In general ET methods are used for inspection of non- ferromagnetic tubes and IRIS and RFEC methods for inspection of ferromagnetic tubes. New techniques have been introduced, to determine the tube condition accurately. One of the developed techniques is for instance inspection of the internal surface by combination of dye penetrant and optical laser inspection. New applications of ultrasonic techniques include defect detection and characterisation by tip diffraction echoes, defect analysis by echo dynamics and the TOFD-technique for defect sizing. Ultrasonic guided waves have a great potential to increase inspection speed for defect detection, although sizing is still under development. For inspection of ferromagnetic tubes, a method based on magnetic flux leakage has been used. In addition to the basic techniques visualisation of the measured data is one of the. key factors for improved exploitation of the inspection results. (orig.)

  6. 10 CFR 431.82 - Definitions concerning commercial packaged boilers.

    Science.gov (United States)

    2010-01-01

    ... COMMERCIAL AND INDUSTRIAL EQUIPMENT Commercial Packaged Boilers § 431.82 Definitions concerning commercial...). Commercial packaged boiler means a type of packaged low pressure boiler that is industrial equipment with a... 10 Energy 3 2010-01-01 2010-01-01 false Definitions concerning commercial packaged boilers....

  7. 49 CFR 230.36 - Hydrostatic testing of boilers.

    Science.gov (United States)

    2010-10-01

    ... ADMINISTRATION, DEPARTMENT OF TRANSPORTATION STEAM LOCOMOTIVE INSPECTION AND MAINTENANCE STANDARDS Boilers and Appurtenances Pressure Testing of Boilers § 230.36 Hydrostatic testing of boilers. (a) Time of test. The... 49 Transportation 4 2010-10-01 2010-10-01 false Hydrostatic testing of boilers. 230.36 Section...

  8. 46 CFR 63.25-7 - Exhaust gas boilers.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 2 2010-10-01 2010-10-01 false Exhaust gas boilers. 63.25-7 Section 63.25-7 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) MARINE ENGINEERING AUTOMATIC AUXILIARY BOILERS Requirements for Specific Types of Automatic Auxiliary Boilers § 63.25-7 Exhaust gas boilers. (a)...

  9. 49 CFR 230.30 - Lap-joint seam boilers.

    Science.gov (United States)

    2010-10-01

    ... 49 Transportation 4 2010-10-01 2010-10-01 false Lap-joint seam boilers. 230.30 Section 230.30..., DEPARTMENT OF TRANSPORTATION STEAM LOCOMOTIVE INSPECTION AND MAINTENANCE STANDARDS Boilers and Appurtenances Inspection and Repair § 230.30 Lap-joint seam boilers. Every boiler having lap-joint longitudinal...

  10. 46 CFR 61.05-20 - Boiler safety valves.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 2 2010-10-01 2010-10-01 false Boiler safety valves. 61.05-20 Section 61.05-20 Shipping... INSPECTIONS Tests and Inspections of Boilers § 61.05-20 Boiler safety valves. Each safety valve for a drum, superheater, or reheater of a boiler shall be tested at the interval specified by table 61.05-10....

  11. 46 CFR 61.05-15 - Boiler mountings and attachments.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 2 2010-10-01 2010-10-01 false Boiler mountings and attachments. 61.05-15 Section 61.05... TESTS AND INSPECTIONS Tests and Inspections of Boilers § 61.05-15 Boiler mountings and attachments. (a....05-10. (b) Each stud or bolt for each boiler mounting that paragraph (c) of this section requires...

  12. 40 CFR 65.149 - Boilers and process heaters.

    Science.gov (United States)

    2010-07-01

    ... thermal units per hour) or greater. (ii) A boiler or process heater into which the vent stream is... 40 Protection of Environment 15 2010-07-01 2010-07-01 false Boilers and process heaters. 65.149... System or a Process § 65.149 Boilers and process heaters. (a) Boiler and process heater equipment...

  13. Experimental Study on an On-Line Measurement of High Temperature Circulating Ash Flux in a Circulating Fluidized Bed Boiler

    Institute of Scientific and Technical Information of China (English)

    Lu Xiaofeng; Li Yourong

    2001-01-01

    A new kind of measuring method that may be used to measure high temperature circulating solid particles flux in a circulating fluidized bed boiler is studied in this paper. The measuring method is founded on the principle of thermal equilibrium. A series of cold tests and hot tests were carried to optimize the structure and collocation of water-cooling tubes and showed that the method had the advantage of simple, accurate, reliable and good applicability for on-line usage in a circulating fluidized bed boiler.

  14. Desulphurization in peat-fired circulating and bubbling fluidized bed boilers

    Energy Technology Data Exchange (ETDEWEB)

    Kouvo, P. [Imatran Voima Oy, Vantaa (Finland); Salmenoja, K. [Kvaerner Pulping Oy, Tampere (Finland)

    1997-12-31

    The new emission limit values for large combustion plants are under consideration both at the EU level and in Finland. Peat and wood are the only indigenous fuels of Finland. In 1995 appr. 8 % of electricity was produced with peat. The lower heating value of peat is around 10 MJ/kg. The moisture content varies between 35-55 % and sulphur content in dry solids between 0.15-0.35 %. The total peat power capacity of Finland in 1995 was 1400 MW. Because there was not enough information available about the desulphurization of the flue gases from peat-fired fluidized bed boilers, a group of Finnish companies and Ministry of Trade and Industry decided to carry out the full-scale desulphurisation study. In the project the desulphurization with limestone injection into the furnace of two types of peat-fired boilers were studied. The goal of the project was to investigate: what the technically and economically feasible emission level is by limestone injection in the fluidized bed combustion; how the limestone injection affects the other flue gas emissions and the fouling of the boiler and, what the economy of desulphurisation is. The tests were carried out at Kokkola and Kemi power plants in Finland. At Kokkola (108 MW{sub f}) circulating fluidized bed boiler, the emission limit of 200 mg/m{sup 3}n was leached at a Ca/S-molar ratio of appr. 10, with limestone containing 92 % of calcium carbonate, CaCO{sub 3}. At Kemi (267 MW{sub f}) bubbling fluidized bed boiler, the emission limit of 280 mg/m{sup 3}n with limestone containing appr. 95 % of CaCO{sub 3} was reached at a Ca/S-molar ratio of appr. 7.0. Emissions of NO{sub x}, N{sub 2}O, NH{sub 3} and dust after the ESP were not elevated due to the limestone feed. At the Kokkola power plant the NO{sub x} emissions varied from 300 to 400 mg/m{sup 3}n, and, at the Kemi power station the NO{sub x} emissions were around 200 mg/m{sup 3}n. The fouling of the Kemi boiler was found to be significant in the scheduled outage after the test

  15. Fouling Characteristics and Prevention Techniques for Membrane Bioreactor

    Institute of Scientific and Technical Information of China (English)

    LU Hua; WANG Zhi-qiang; YANG Jin-ying

    2005-01-01

    Membrane fouling is the main problem of membrane bioreactors (MBR), which seriously influences its wastewater treatment effect and running. The characteristics of microbiology and hydrodynamics concerning membrane fouling were investigated and the measure was put forward for optimum operation of MBR. The measure is that 1) the parameters of activated sludge concentration (X) and membrane flux should be lower than the critical values of X and membrane flux respectively, and 2) the activated sludge should be discharged periodically. The experimental results show that the combination backwashing of gas and permeated effluent is better than single gas backwashing or single permeated effluent backwashing. This technique can remove the cake layer deposited on the membrane surface, decrease the membrane fouling, and recover the membrane flux effectively. So it is effective for prevention of membrane fouling.

  16. Scaling and particulate fouling in membrane filtration systems

    NARCIS (Netherlands)

    Boerlage, S.F.E.

    2001-01-01

    Membrane filtration technologies have emerged as cost competitive and viable techniques in drinking and industrial water production. Despite advancements in membrane manufacturing and technology, membrane scaling and fouling remain major problems and may limit future growth in the industry. Scaling

  17. Membrane fouling control by ultrasound in an anaerobic membrane bioreactor

    Institute of Scientific and Technical Information of China (English)

    SUI Pengzhe; WEN Xianghua; HUANG Xia

    2007-01-01

    In this study,ultrasound was used to control the membrane fouling online in an anaerobic membrane bioreactor (AMBR).Short-term running experiments were carried out under different operating conditions to explore feasible ultrasonic parameters.The experimental results indicated that when the crossflow velocity was more than 1.0 m/s,membrane fouling could be controlled effectively only by hydrodynamic methods without ultrasound.When ultrasound was applied,an ultrasonic power range of 60-150 W was suitable for the membrane fouling control in the experimental system.The experimental results showed that the membrane fouling was controlled so well that membrane filtration resistance(ΣR) could stay at 5×1011 m-1 for more than a week with the crossflow velocity of 0.75 m/s,which equaled the effect of crossflow velocity of more than 1.0 m/s without ultrasound.

  18. Fouling in small hydro projects; Verschmutzung von Kleinwasserkraftwerken - Schlussbericht

    Energy Technology Data Exchange (ETDEWEB)

    Abgottspon, A.; Staubli, T.

    2010-03-15

    This comprehensive final report for the Swiss Federal Office of Energy (SFOE) takes a look at fouling problems encountered in small hydro installations. The report is based on ten interviews made with operators of small hydro power stations in Switzerland. A parallel project carried out in Germany is mentioned. A large variation in the degree of fouling in the various hydro power stations is noted. Sources such as leaves in autumn and algae are discussed, as are the various rinsing procedures used to clear the turbines of fouling. Power losses are discussed and measures that can be taken to prevent fouling are described. Measurements made at an installation in Freienstein, Switzerland, are presented and discussed. The report is completed with an appendix containing calculations, details on the Freienstein power plant and the results of interviews made with the ten hydro power installations examined.

  19. Records of Australian Fouling Organisms: Sessile Barnacles (Crustacea, Cirripedia),

    Science.gov (United States)

    1981-04-01

    Dr. W.A. Newman) Laboratorio de Ensayo de Materiales e Investigaciones Tecnologicas (LEMIT), Argentina. (Attention: Dr. V. Rascio) Dept. of Zoology...AD-A105 265 MATERIALS RESEARCH LABS ASCOT VALE (AUSTRALIA) FIG B/1 RECORDS OF AUSTRALIAN FOULING ORGANISMS: SESSILE BARNACLES (CRU--ETC(U) APR 81 J A...SCIENCE AND TECHNOLOGY ORGANISATION MATERIALS RESEARCH LABORATORIES MELBOURNE, VICTORIA REPORT . MRL-R-809 RECORDS OF AUSTRALIAN FOULING ORGANISMS: SESSILE

  20. Ultrafiltration Membrane Fouling and the Effect of Ion Exchange Resins

    KAUST Repository

    Jamaly, Sanaa

    2011-12-01

    Membrane fouling is a challenging process for the ultrafiltration membrane during wastewater treatment. This research paper determines the organic character of foulants of different kinds of wastewater before and after adding some ion exchange resins. Two advanced organic characterization methods are compared in terms of concentration of dissolved organic carbons: The liquid chromatography with organic carbon (LC-OCD) and Shimadzu total organic carbon (TOC). In this study, two secondary wastewater effluents were treated using ultrafiltration membrane. To reduce fouling, pretreatment using some adsorbents were used in the study. Six ion exchange resins out of twenty were chosen to compare the effect of adsorbents on fouling membrane. Based on the percent of dissolved organic carbon’s removal, three adsorbents were determined to be the most efficient (DOWEX Marathon 11 anion exchange resin, DOWEX Optipore SD2 polymeric adsorbent, and DOWEX PSR2 anion exchange), and three other ones were determined to the least efficient (DOWEX Marathon A2 anion exchange resin, DOWEX SAR anion exchange resin, and DOWEX Optipore L493 polymeric adsorbent). Organic characterization for feed, permeate, and backwash samples were tested using LC-OCD and TOC to better understand the characteristics of foulants to prevent ultrafiltration membrane fouling. The results suggested that the polymeric ion exchange resin, DOWEX SD2, reduced fouling potential for both treated wastewaters. All the six ion exchange resins removed more humic fraction than other organic fractions in different percent, so this fraction is not the main for cause for UF membrane fouling. The fouling of colloids was tested before and after adding calcium. There is a severe fouling after adding Ca2+ to effluent colloids.

  1. Slagging and Fouling Characteristics of HRSG for Ferrosilicon Electric Furnaces

    OpenAIRE

    2015-01-01

    The slagging and fouling characteristics of the heat recovery steam generator (HRSG) for ferrosilicon electric furnaces are discussed in this paper. Three ash samples were taken from the HRSG of a ferrosilicon furnace in Ningxia Province, China, which suffered from serious slagging and fouling. X-ray fluorescence (XRF), X-ray powder diffraction (XRD) and scanning electron microscope (SEM) were used to analyze the ash samples. The results show that low melting point salt Na 2 SO 4 and composit...

  2. High Flux, Fouling Resistant Membranes for RO Pretreatment

    Science.gov (United States)

    2012-05-31

    improved flux and fouling resistance . This in turn will lead to more compact and efficient filtration systems that reduce maintenance and downtime...size, and resistance to protein fouling by BSA filtration . Hollow Fiber Development and Testing Hollow fibers were produced by a generally...layer during dead- end filtration . The shear forces in cross-flow operation can impact the effective particle size in the feed and compact the cake

  3. CONDENSING ECONOMIZERS FOR SMALL COAL-FIRED BOILERS AND FURNACES PROJECT REPORT - JANUARY 1994

    Energy Technology Data Exchange (ETDEWEB)

    BUTCHER,T.A.

    1994-01-04

    Condensing economizers increase the thermal efficiency of boilers by recovering sensible and latent heat from exhaust gas. These economizers are currently being used commercially for this purpose in a wide range of applications. Performance is dependent upon application-specific factors affecting the utility of recovered heat. With the addition of a condensing economizer boiler efficiency improvements up to 10% are possible. Condensing economizers can also capture flue gas particulates. In this work, the potential use of condensing economizers for both efficiency improvement and control of particulate emissions from small, coal water slurry-fired boilers was evaluated. Analysis was done to predict heat transfer and particulate capture by mechanisms including: inertial impaction, interception, diffusion, thermophoretic forces, and condensation growth. Shell-and-tube geometries were considered with flue gas on the outside of Teflon-covered tubes. Experimental studies were done with both air- and water-cooled economizers refit to a small boiler. Two experimental arrangements were used including oil-firing with injection of flyash upstream of the economizer and direct coal water slurry firing. Firing rates ranged from 27 to 82 kW (92,000 to 280,000 Btu/hr). Inertial impaction was found to be the most important particulate capture mechanism and removal efficiencies to 95% were achieved. With the addition of water sprays directly on the first row of tubes, removal efficiencies increased to 98%. Use of these sprays adversely affects heat recovery. Primary benefits of the sprays are seen to be the addition of small impaction sites and future design improvements are suggested in which such small impacts are permanently added to the highest velocity regions of the economizer. Predicted effects of these added impactors on particulate removal and pressure drop are presented.

  4. Initial study of a method for IR measurements in boilers; Inledande studie av metod foer IR-maetning i aangpannor

    Energy Technology Data Exchange (ETDEWEB)

    Sandberg, Martin; Joensson, Magnus; Lundin, Leif [Swedish National Testing and Research Inst., Boraas (Sweden)

    1999-10-01

    The tubes in steam boilers are required to be regularly inspected, in order to find water-side deposits, thinning of walls or material defects. This is for safety, problem-free operation and high availability. No non-destructive method of inspection is available today for finding deposits on the insides of boiler tubes. Nor is there any method that can not only detect deposits on the insides of the tubes but also monitor the tubes' wall thicknesses. A suitable method - reliable, safe, easy to use and cost-efficient - is therefore needed. One such method is to measure the surface temperature of a larger area of the diaphragm wall, using a non-contact method, and from the resulting information to assess the material thickness and possible water-side or steam-side deposits. An IR camera is used for non-contact measurement of the radiated energy from several adjacent surface elements, and thus also of their temperature. The temperature is displayed on the camera's screen to produce a picture of the temperature distribution. This is a well-established method today, and is used in applications such as the steel industry, the electricity industry, electronics and health care. The surface temperatures of the tube walls can be measured by inserting an IR camera on an arm into the combustion chamber, without anyone having to get inside the boiler. The combustion chamber is the part of the boiler that is of main interest for inspection, as it is the easiest to reach. Measurements are facilitated by higher temperatures and thus higher heat fluxes through the tube walls. Diaphragm wall temperatures can be measured quickly and rationally over large areas. Points of interest in inspections include determining where there are water-side deposits in the tubes, where tubes are thin, where flow is obstructed and where there might be material defects. With the exception of material defects, all of these mechanisms result in changes in the surface temperature, which in many

  5. Dirty air conditioners: Energy implications of coil fouling

    Energy Technology Data Exchange (ETDEWEB)

    Siegel, Jeffrey; Walker, Iain; Sherman, Max

    2002-03-01

    Residential air conditioning is responsible for a substantial amount of peak electrical demand and energy consumption throughout most of the United States. Coil fouling, the deposition of indoor dusts and other particulate matter on evaporator heat exchangers, increases system pressure drop and, correspondingly, decreases system air flow and air conditioner performance. In this paper, we apply experimental and simulation results describing particle deposition on evaporator coils as well as research about indoor particle and dust concentrations to determine coil fouling rates. The results suggest that typical coils foul enough to double evaporator pressure drop in about 7.5 years, much sooner than the expected 15-30 year life time for an evaporator coil. The most important parameters in determining coil fouling times are the efficiency of the filter and indoor particle concentrations, although filter bypass and duct and coil design are important as well. The reduced air flows that result from coil fouling cause typical efficiency and capacity degradations of less than 5%, however they can be much greater for marginal systems or extreme conditions. These energy issues, as well as possible indoor air quality issues resulting from fouling by biological aerosols, suggest that regular coil cleaning to ameliorate low flow and the elimination of filter bypass should be an important part of residential air conditioning commissioning and maintenance practices.

  6. Kinetic study of seawater reverse osmosis membrane fouling

    KAUST Repository

    Khan, Muhammad

    2013-10-01

    Reverse osmosis (RO) membrane fouling is not a static state but a dynamic phenomenon. The investigation of fouling kinetics and dynamics of change in the composition of the foulant mass is essential to elucidate the mechanism of fouling and foulant-foulant interactions. The aim of this work was to study at a lab scale the fouling process with an emphasis on the changes in the relative composition of foulant material as a function of operating time. Fouled membrane samples were collected at 8 h, and 1, 2, and 4 weeks on a lab-scale RO unit operated in recirculation mode. Foulant characterization was performed by CLSM, AFM, ATR-FTIR, pyrolysis GC-MS, and ICP-MS techniques. Moreover, measurement of active biomass and analysis of microbial diversity were performed by ATP analysis and DNA extraction, followed by pyro-sequencing, respectively. A progressive increase in the abundance of almost all the foulant species was observed, but their relative proportion changed over the age of the fouling layer. Microbial population in all the membrane samples was dominated by specific groups/species belonging to Proteobacteria and Actinobacteria phyla; however, similar to abiotic foulant, their relative abundance also changed with the biofilm age. © 2013 American Chemical Society.

  7. Ammonia recovery from agricultural wastes by membrane distillation: fouling characterization and mechanism.

    Science.gov (United States)

    Zarebska, A; Nieto, D Romero; Christensen, K V; Norddahl, B

    2014-06-01

    One of the main obstacles impeding implementation of membrane distillation for the recovery and concentration of ammonia from swine manure is wetting caused by fouling. Due to the different types of fouling which can occur in a membrane system, foulants characterization is a complex problem. To elucidate the fouling mechanism, deposit morphology and composition of foulants have been determined using Scanning Electron Microscopy, X-ray Energy Dispersive Spectrometry, Attenuated Total Reflectance Infrared Spectrometry, Ion chromatography and Inductively coupled plasma-optical emission spectroscopy. Based on the analysis of fouled membranes, it is concluded that membrane fouling is dominated by organic fouling in combination with deposits of inorganic elements and microorganisms. After a week of running the membrane process without cleaning, the average fouling layer thickness was estimated to 10-15 μm. The fouling layer further results in a loss of membrane hydrophobicity. This indicates that fouling could be a severe problem for membrane distillation performance.

  8. Development of pressurized internally circulating fluidized bed combustion technology; Kaatsu naibu junkan ryudosho boiler no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Ishihara, I. [Center for Coal Utilization, Japan, Tokyo (Japan); Nagato, S.; Toyoda, S. [Ebara Corp., Tokyo (Japan)

    1996-09-01

    The paper introduced support research on element technology needed for the design of hot models of the pressurized internally circulating fluidized bed combustion boiler in fiscal 1995 and specifications for testing facilities of 4MWt hot models after finishing the basic plan. The support research was conduced as follows: (a) In the test for analysis of cold model fluidization, it was confirmed that each characteristic value of hot models is higher than the target value. Further, calculation parameters required for computer simulation were measured and data on the design of air diffusion nozzle for 1 chamber wind box were sampled. (b) In the CWP conveyance characteristic survey, it was confirmed that it is possible to produce CWP having favorable properties. It was also confirmed that favorable conveyability can be maintained even if the piping size was reduced down to 25A. (c) In the gas pressure reducing test, basic data required for the design of gas pressure reducing equipment were sampled. Specifications for the fluidized bed combustion boiler of hot models are as follows: evaporation amount: 3070kg/h, steam pressure: 1.77MPa, fuel supply amount: 600kg-coal/h, boiler body: cylinder shape water tube internally circulating fluidized bed combustion boiler. 4 refs., 4 figs.

  9. Temperature Distribution of Biodiesel Blends Combustion in Boiler using CFD-Fluent

    Directory of Open Access Journals (Sweden)

    Lia Cundari

    2016-02-01

    Full Text Available The use of biodiesel have been tested on some combustion devices extensively, including on the boiler. Biodiesel blends use in boiler is possibly affected the behaviour of combustion. It can be evaluated by analysing the exhaust gas composition and temperature. This study is conducted to show the distribution of temperature in the combustion chamber and boiler stack’s using Computational Fluid Dynamic (CFD software Fluent. Experimentally, the tests carried out on the fire tube boiler vertical type cylinder with pressure of 3 bar. Temperature measurement is performed at three points in the combustion chamber and boilers’ stack using optional thermocouple and gas analyzer IMR 1400. The biodiesel used in the tests is palm oil based with blending portion varies from 5-25%. The results show that in the higher blend of biodiesel, the temperature of combustion chamber tend to be lower but the exhaust gas temperature at the end of the chimney was likely to increase. On the other hand, the simulation using FLUENT showed the pattern of temperature distribution was relatively equal between the use of biodiesel in the blends under 25% compared to the use of diesel (B0.

  10. Alkali metal pool boiler life tests for a 25 kWe advanced Stirling conversion system

    Science.gov (United States)

    Anderson, W. G.; Rosenfeld, J. H.; Noble, J.

    The overall operating temperature and efficiency of solar-powered Stirling engines can be improved by adding an alkali metal pool boiler heat transport system to supply heat more uniformly to the heater head tubes. One issue with liquid metal pool boilers is unstable boiling. Stable boiling is obtained with an enhanced boiling surface containing nucleation sites that promote continuous boiling. Over longer time periods, it is possible that the boiling behavior of the system will change. An 800-h life test was conducted to verify that pool boiling with the chosen fluid/surface combination remains stable as the system ages. The apparatus uses NaK boiling on a - 100 + 140 stainless steel sintered porous layer, with the addition of a small amount of xenon. Pool boiling remained stable to the end of life test. The pool boiler life test included a total of 82 cold starts, to simulate startup each morning, and 60 warm restarts, to simulate cloud cover transients. The behavior of the cold and warm starts showed no significant changes during the life test. In the experiments, the fluid/surface combination provided stable, high-performance boiling at the operating temperature of 700 C. Based on these experiments, a pool boiler was designed for a full-scale 25-kWe Stirling system.

  11. KARAKTERISTIK INTERAKSI MEMBRAN-FOULANT DAN FOULANT-FOULANT SEBAGAI DASAR PENGENDALIAN FOULING

    Directory of Open Access Journals (Sweden)

    Heru Susanto

    2012-05-01

    Full Text Available THE CHARACTERISTICS OF MEMBRANE-FOULANT AND FOULANT-FOULANT INTERACTIONS AS THE BASIS FOR CONTROL OF FOULING. Industrial membrane applications for solid liquid and liquid-liquid filtration are limited by fouling and concentration polarization. Because fouling significantly reduces the membrane performance and often changes the membrane selectivity, efforts to overcome the fouling problem are very important from practical applications point of view. This paper presents the basic knowledge required to control fouling and recent development in fouling control including the method developed by the author. Control of fouling can be done by (i commercial membrane modification (post modification by photo-graft polymerization, (ii modification by polymer blending during membrane manufacturing and (iii integration of a pretreatment into membrane processes. The results showed that all the developed methods can significantly reduce the resulting fouling; however, none of the method could totally remove the occurring fouling. The understanding of the membrane-foulant and foulant-foulant interactions is the key to success in control of fouling.Aplikasi teknologi membran untuk pemisahan padat cair di  berbagai industri dibatasi oleh peristiwa fouling yang menyebabkan penurunan laju produk dan perubahan selektifitas membran. Oleh karena itu, pengendalian fouling merupakan upaya yang mutlak harus dilakukan. Makalah ini mempresentasikan pengetahuan dasar yang diperlukan untuk pengendalian fouling dan perkembangan terkini dalam pengendalian fouling termasuk hasil-hasil yang telah dikembangkan oleh penulis. Pengendalian fouling dilakukan dengan (i modifikasi membran komersial (post modification menggunakan metode photo-grafting, (ii modifikasi dengan pencampuran polimer selama proses pembuatan (polymer blend dan (iii integrasi unit perlakuan awal (pre-treatment dengan proses membran. Hasil penelitian menunjukkan bahwa kesemua metode yang dikembangkan dapat

  12. The Characterization of Twin-Wire Arc-Sprayed FeCrBSi Coating and the Application in Sewage Sludge Boilers

    Science.gov (United States)

    Qin, Enwei; Huang, Qian; Shao, Yumin; Chen, Guoxing; Ye, Lin; Gu, Qin; Wu, Shuhui

    2014-12-01

    Incineration in boilers is an environment-friendly treatment for industrial and civil sewage sludge. However, due to the aggressive nature of the sludge, the boiler fireside-surface is subjected to severe wear, erosive, and high temperature corrosion problems during incineration. In this study, we developed an economical FeCrBSi wire material with iron weight content as high as 80%. The coating was prepared by twin-wire arc spraying processing. The chemical compositions of the coating, as well as phase components were analyzed by energy-dispersive spectroscopy and x-ray diffraction method. The surface roughness, porosity, and cross-sectional morphology were further characterized. The coating hardness is close to that of the commercial Armacor M and Armacor C materials. In-boiler test was also carried out. The low thickness loss of the tube indicates a promising application future in sludge boilers.

  13. Superhydrophilic thin-film composite forward osmosis membranes for organic fouling control: fouling behavior and antifouling mechanisms.

    Science.gov (United States)

    Tiraferri, Alberto; Kang, Yan; Giannelis, Emmanuel P; Elimelech, Menachem

    2012-10-16

    This study investigates the fouling behavior and fouling resistance of superhydrophilic thin-film composite forward osmosis membranes functionalized with surface-tailored nanoparticles. Fouling experiments in both forward osmosis and reverse osmosis modes are performed with three model organic foulants: alginate, bovine serum albumin, and Suwannee river natural organic matter. A solution comprising monovalent and divalent salts is employed to simulate the solution chemistry of typical wastewater effluents. Reduced fouling is consistently observed for the superhydrophilic membranes compared to control thin-film composite polyamide membranes, in both reverse and forward osmosis modes. The fouling resistance and cleaning efficiency of the functionalized membranes is particularly outstanding in forward osmosis mode where the driving force for water flux is an osmotic pressure difference. To understand the mechanism of fouling, the intermolecular interactions between the foulants and the membrane surface are analyzed by direct force measurement using atomic force microscopy. Lower adhesion forces are observed for the superhydrophilic membranes compared to the control thin-film composite polyamide membranes. The magnitude and distribution of adhesion forces for the different membrane surfaces suggest that the antifouling properties of the superhydrophilic membranes originate from the barrier provided by the tightly bound hydration layer at their surface, as well as from the neutralization of the native carboxyl groups of thin-film composite polyamide membranes.

  14. Fouling of a spiral-wound reverse osmosis membrane processing swine wastewater: effect of cleaning procedure on fouling resistance.

    Science.gov (United States)

    Camilleri-Rumbau, M S; Masse, L; Dubreuil, J; Mondor, M; Christensen, K V; Norddahl, B

    2016-01-01

    Swine manure is a valuable source of nitrogen, phosphorus and potassium. After solid-liquid separation, the resulting swine wastewater can be concentrated by reverse osmosis (RO) to produce a nitrogen-potassium rich fertilizer. However, swine wastewater has a high fouling potential and an efficient cleaning strategy is required. In this study, a semi-commercial farm scale RO spiral-wound membrane unit was fouled while processing larger volumes of swine wastewater during realistic cyclic operations over a 9-week period. Membrane cleaning was performed daily. Three different cleaning solutions, containing SDS, SDS+EDTA and NaOH were compared. About 99% of the fouling resistance could be removed by rinsing the membrane with water. Flux recoveries (FRs) above 98% were achieved for all the three cleaning solutions after cleaning. No significant differences in FR were found between the cleaning solutions. The NaOH solution thus is a good economical option for cleaning RO spiral-wound membranes fouled with swine wastewater. Soaking the membrane for 3 days in permeate water at the end of each week further improved the FR. Furthermore, a fouling resistance model for predicting the fouling rate, permeate flux decay and cleaning cycle periods based on processing time and swine wastewater conductivity was developed.

  15. Superhydrophilic Thin-Film Composite Forward Osmosis Membranes for Organic Fouling Control: Fouling Behavior and Antifouling Mechanisms

    KAUST Repository

    Tiraferri, Alberto

    2012-10-16

    This study investigates the fouling behavior and fouling resistance of superhydrophilic thin-film composite forward osmosis membranes functionalized with surface-tailored nanoparticles. Fouling experiments in both forward osmosis and reverse osmosis modes are performed with three model organic foulants: alginate, bovine serum albumin, and Suwannee river natural organic matter. A solution comprising monovalent and divalent salts is employed to simulate the solution chemistry of typical wastewater effluents. Reduced fouling is consistently observed for the superhydrophilic membranes compared to control thin-film composite polyamide membranes, in both reverse and forward osmosis modes. The fouling resistance and cleaning efficiency of the functionalized membranes is particularly outstanding in forward osmosis mode where the driving force for water flux is an osmotic pressure difference. To understand the mechanism of fouling, the intermolecular interactions between the foulants and the membrane surface are analyzed by direct force measurement using atomic force microscopy. Lower adhesion forces are observed for the superhydrophilic membranes compared to the control thin-film composite polyamide membranes. The magnitude and distribution of adhesion forces for the different membrane surfaces suggest that the antifouling properties of the superhydrophilic membranes originate from the barrier provided by the tightly bound hydration layer at their surface, as well as from the neutralization of the native carboxyl groups of thin-film composite polyamide membranes. © 2012 American Chemical Society.

  16. Ear Tubes

    Science.gov (United States)

    ... of the ear drum or eustachian tube, Down Syndrome, cleft palate, and barotrauma (injury to the middle ear caused by a reduction of air pressure, ... specialist) may be warranted if you or your child has experienced repeated ... fluid in the middle ear, barotrauma, or have an anatomic abnormality that ...

  17. Reduced Bed Temperature in FB-Boilers Burning Waste - part II; Saenkt baeddtemperatur i FB-pannor foer avfallsfoerbraenning - etapp 2

    Energy Technology Data Exchange (ETDEWEB)

    Niklasson, Fredrik; Pettersson, Anita; Claesson, Frida; Johansson, Andreas; Gunnarsson, Anders; Gyllenhammar, Marianne; Victoren, Anders; Gustafsson, Goeran

    2010-07-01

    This project focuses on evaluating whether lowered bed temperature in FB-boilers for waste combustion gives operational benefits, such as reduced fouling in the convection pass. If so, this mode of operation could reduce the number of unplanned boiler outages, reduce the need for soot blowing, and extend the lifetime of the superheaters at unaltered steam temperature. The project is based on full-scale experiments performed at Ryaverket in Boraas. The plant has two waste-fired 20 MW{sub t} FB-boilers. The study is based on a comparison between operational data and measurement results from two different operating conditions of the boilers. In addition to the data that normally are logged by the control system, samples of fuel, ashes, particles, and deposits were taken and subsequently analyzed. The structure of the bed ash was altered by lowering the bed temperature. Under normal boiler operation, the bed ash contains many small agglomerates that disappeared when the bed temperature was lowered. Due to this, the sand consumption of the plant could be reduced by roughly 25 %. At lowered bed temperature, the concentration of chlorine increased in the bed ash and in the recycled sand while it decreased in the ashes from the cyclone and fabric filter. The concentration of HCl in the flue gas increased as the bed temperature was lowered. This is considered a consequence of less chlorine forming alkali chlorides. Moreover, the particle measurements showed that the amount of submicron particles decreased during lowered bed temperature, which also is an indication of less alkali chlorides in the flue gas. The deposit probes showed an approximate 20 % reduction of the fouling rate when the bed temperature was lowered from 876 to 714 deg C. The chlorine content also decreased in the deposits. For the deposit probes at 500 deg C, (corresponds to a steam temperature of 465 deg C) significant amounts of KCl were found in the deposits, even when the bed temperature was lowered

  18. Evaluation of the behavior of shrouded plasma spray coatings in the platen superheater of coal-fired boilers

    Science.gov (United States)

    Sidhu, Buta Singh; Prakash, S.

    2006-06-01

    Nickel- and cobalt-based coatings were formulated by a shrouded plasma spray process on boiler tube steels, namely, ASTM-SA210-grade A1 (GrA1), ASTM-SA213-T-11 (T11), and ASTM-SA213-T-22 (T22). The Ni-22Cr-10Al-1Y alloy powder was sprayed as a bond in each case before the final coating. The degradation behavior of the bared and coated steels was studied in the platen superheater of the coal-fired boiler. The samples were inserted through the soot blower dummy points with the help of stainless steel wires. The coatings were found to be effective in increasing resistance to degradation in the given boiler environment. The maximum protection was observed in the case of Stellite-6 (St-6) coating.

  19. Evaluation of the behavior of shrouded plasma spray coatings in the platen superheater of coal-fired boilers

    Energy Technology Data Exchange (ETDEWEB)

    Sidhu, B.S.; Prakash, S. [GZS College of Engineering & Technology, Bathinda (India). Dept. of Mechanical Engineering

    2006-06-15

    Nickel- and cobalt-based coatings were formulated by a shrouded plasma spray process on boiler tube steels, namely, ASTM-SA210-grade A1 (GrA1), ASTM-SA213-T-11 (T11), and ASTM-SA213-T-22 (T22). The Ni-22Cr-10A1-1Y alloy powder was sprayed as a bond in each case before the final coating. The degradation behavior of the bared and coated steels was studied in the platen superheater of the coal-fired boiler. The samples were inserted through the soot blower dummy points with the help of stainless steel wires. The coatings were found to be effective in increasing resistance to degradation in the given boiler environment. The maximum protection was observed in the case of Stellite-6 (St-6) coating.

  20. Combustion of mediterranean agro-forest biomasses in small and medium scale pellet boilers: strategies for minimizing ash fusion and slagging

    Energy Technology Data Exchange (ETDEWEB)

    Vega-Nieva, Daniel J.; Dopazo, Raquel; Ortiz, Luis [Forest Engineering Univ. School. Univ. of Vigo, Pontevedra (Spain)], e-mail: DanielJVN@gmail.com

    2012-11-01

    The slagging and fouling risk remain as important barriers that are currently limiting the use of various agricultural residues and potential energy crops feedstocks (e.g. [1-3]), which remain largely unutilized, particularly in Mediterranean countries. In this oral communication, the main results from the VI Framework European Project Domoheat on the combustion of mediterranean biomasses and its mixtures on small and medium size domestic pellet boilers, are presented, together with the goals of the ongoing VII Framework European Project AshMelT focusing on the definition of objective criteria and tests for ash slagging in domestic pellet boilers. The utilization of ash slagging indices based on ash composition and the definition of biomass mixtures based on such ash indices are presented as potentially useful tools for minimizing the occurrence of ash fusion and slagging during combustion.

  1. 30 CFR 56.13030 - Boilers.

    Science.gov (United States)

    2010-07-01

    ... Valves BNon-ASME Code Boilers and Pressure Vessels CStorage of Mild Steel Covered Arc Welding Electrodes... American Society of Mechanical Engineers, 22 Law Drive, P.O. Box 2900, Fairfield, New Jersey 07007,...

  2. Boiler scale prevention employing an organic chelant

    Science.gov (United States)

    Wallace, Steven L.; Griffin, Jr., Freddie; Tvedt, Jr., Thorwald J.

    1984-01-01

    An improved method of treating boiler water which employs an oxygen scavenging compound and a compound to control pH together with a chelating agent, wherein the chelating agent is hydroxyethylethylenediaminetriacetic acid.

  3. New thinking for the boiler room.

    Science.gov (United States)

    Rose, Wayne

    2008-09-01

    Wayne Rose, marketing manager at integrated plant room manufacturer Armstrong Integrated Systems, explains how increasing use of off-site manufacture, the latest 3D modelling technology, and advances in control technology, are revolutionising boiler room design and construction.

  4. The effect of water quality on reliability of boiler plants performance

    Directory of Open Access Journals (Sweden)

    Gajić Anto S.

    2010-01-01

    Full Text Available This paper presents sources and types of corrosion processes of boiler tube system of the Thermal Power Plant "Ugljevik". The main goal in the electric power production is to achieve lower prices, which can only be done by providing low maintenance costs. While it is not possible to completely stop corrosion, it could be slowed down and it's effects could be reduced. In order to reduce corrosion to a minimum on thermal power plants' vital equipment, particularly boilers, it is necessary to determine in each particular case the acting mechanism of corrosion and agents that cause it. Damages and failures on thermal power plants are largely caused by the development of various types of corrosion processes. Special attention is given to the preparation of water, considering its importance to the occurrence of corrosion. The following types of corrosion were detected on the screen tube boiler by visual examination on the side of water and steam: erosive, pitting and impact corrosion. The inner surface of screen pipes, from which the scale layer was removed, indicates that the erosive corrosion with the thinning of pipe walls occurs. Perforation of the welded screen pipes shows that stress corrosion occurred on the screen pipe with formation of cracks and that pipe exploded. Pits on the inner surface of the screen pipes, visible after the removal of scale and corrosion products, are proof that pitting corrosion occurred. The causes of corrosion were discovered and proposed measures for their elimination were given.

  5. Boiler burden reduced at Bedford site.

    Science.gov (United States)

    Horsley, Chris

    2011-10-01

    With the NHS aiming to reduce its 2007 carbon footprint by 10% by 2015, Chris Horsley, managing director of Babcock Wanson UK, a provider of industrial boilers and burners, thermal oxidisers, air treatment, water treatment, and associated services, looks at how one NHS Trust has approached the challenge, and considerably reduced its carbon emissions, by refurbishing its boiler house and moving from oil to gas-fired steam generation.

  6. IHI-FW circulating fluidized bed boiler

    Energy Technology Data Exchange (ETDEWEB)

    Watanabe, S.; Omata, K.; Ishimoto, R.; Asai, M. (Ishikawajima-Harima Heavy Industries, Co. Ltd., Tokyo (Japan))

    1993-07-01

    The technology and application of the circulating fluidized bed boiler (IHI-FW) are outlined. Circulating fluidized bed boilers have various features as compared with bubbling fluidized bed boilers as follows; a high combustion efficiency, efficient use of limestone for desulfurization, low NOx emission, adaptability to various fuels and capability to cope with load change. The IHI-FW boiler is furthermore featured by water-wall furnace of all-welded structure, water-cooled/steam cooled cyclone, and simple circulating system. The 30 t/h circulating fluidized bed boiler was introduced into the Tsu Works, Omikenshi Co., Ltd., Japan for private power generation. The boiler equipped with a backup heavy oil burner mainly uses semi-anthracite coal, and besides sulfur capture and NOx reduction functions of a bed, a bag filter with a high dust collecting efficiency is installed in an exhaust gas system. The installation period was reduced to 2.5 months, a half of conventional ones, by more assembly in a factory followed by less field works. 7 figs., 2 tabs.

  7. Assessment of physical workload in boiler operations.

    Science.gov (United States)

    Rodrigues, Valéria Antônia Justino; Braga, Camila Soares; Campos, Julio César Costa; Souza, Amaury Paulo de; Minette, Luciano José; Sensato, Guilherme Luciano; Moraes, Angelo Casali de; Silva, Emília Pio da

    2012-01-01

    The use of boiler wood-fired is fairly common equipment utilized in steam generation for energy production in small industries. The boiler activities are considered dangerous and heavy, mainly due to risks of explosions and the lack of mechanization of the process. This study assessed the burden of physical labor that operators of boilers are subjected during the workday. Assessment of these conditions was carried out through quantitative and qualitative measurements. A heart rate monitor, a wet-bulb globe thermometer (WBGT), a tape-measure and a digital infrared camera were the instruments used to collect the quantitative data. The Nordic Questionnaire and the Painful Areas Diagram were used to relate the health problems of the boiler operator with activity. With study, was concluded that the boiler activity may cause pains in the body of intensity different, muscle fatigue and diseases due to excessive weight and the exposure to heat. The research contributed to improve the boiler operator's workplace and working conditions.

  8. Sodium reflux pool-boiler solar receiver on-sun test results

    Energy Technology Data Exchange (ETDEWEB)

    Andraka, C E; Moreno, J B; Diver, R B; Moss, T A [Oak Ridge National Lab., TN (United States)

    1992-06-01

    The efficient operation of a Stirling engine requires the application of a high heat flux to the relatively small area occupied by the heater head tubes. Previous attempts to couple solar energy to Stirling engines generally involved directly illuminating the heater head tubes with concentrated sunlight. In this study, operation of a 75-kW{sub t} sodium reflux pool-boiler solar receiver has been demonstrated and its performance characterized on Sandia's nominal 75-kW{sub t} parabolic-dish concentrator, using a cold-water gas-gap calorimeter to simulate Stirling engine operation. The pool boiler (and more generally liquid-metal reflux receivers) supplies heat to the engine in the form of latent heat released from condensation of the metal vapor on the heater head tubes. The advantages of the pool boiler include uniform tube temperature, leading to longer life and higher temperature available to the engine, and decoupling of the design of the solar absorber from the engine heater head. The two-phase system allows high input thermal flux, reducing the receiver size and losses, therefore improving system efficiency. The receiver thermal efficiency was about 90% when operated at full power and 800{degree}C. Stable sodium boiling was promoted by the addition of 35 equally spaced artificial cavities in the wetted absorber surface. High incipient boiling superheats following cloud transients were suppressed passively by the addition of small amounts of xenon gas to the receiver volume. Stable boiling without excessive incipient boiling superheats was observed under all operating conditions. The receiver developed a leak during performance evaluation, terminating the testing after accumulating about 50 hours on sun. The receiver design is reported here along with test results including transient operations, steady-state performance evaluation, operation at various temperatures, infrared thermography, x-ray studies of the boiling behavior, and a postmortem analysis.

  9. Heat Transfer Studies in Tube Banks with Integral Wake Splitters

    Directory of Open Access Journals (Sweden)

    Suzairin Md Seri

    2009-09-01

    Full Text Available This paper reports the findings from heat transfer studies with the presence of extended surfaces from tube banks which are termed as integral wake splitter plates. Employing this type of fins, investigations on heat transfer characteristics on a single circular tube as well as tube banks were carried out in cross flow of air in a rectangular duct. Experiments were carried out in the Reynolds number range 5 x 103 to 105 on a single cylinder of various splitter length-to-tube diameter ratios, L/D = 0.5, 1.0, 1.5 and 2.0. Further, tube banks consisting of 12 rows and 3 tubes per row in equilateral triangle arrangements with transverse pitch to diameter ratio, a = 2, were also investigated, the banks being made up of plain tubes or tubes with splitters. Heat transfer characteristics were studied for tubes with L/D = 0, 0.5 and 1.0 under constant heat flux conditions. Tube banks with L/D = 1.0 yielded the highest heat transfer rates. Findings from this work may be adopted to be utilized in various industrial applications such as economizer of a steam boiler, air-conditioning coils or waste heat recovery systems.

  10. Jejunostomy feeding tube

    Science.gov (United States)

    ... page: //medlineplus.gov/ency/patientinstructions/000181.htm Jejunostomy feeding tube To use the sharing features on this ... vomiting Your child's stomach is bloated Alternate Names Feeding - jejunostomy tube; G-J tube; J-tube; Jejunum ...

  11. Rejection of Organic Micropollutants by Clean and Fouled Nanofiltration Membranes

    Directory of Open Access Journals (Sweden)

    Lifang Zhu

    2015-01-01

    Full Text Available The rejection of organic micropollutants, including three polycyclic aromatic hydrocarbons (PAHs and three phthalic acid esters (PAEs, by clean and fouled nanofiltration membranes was investigated in the present study. The rejection of organic micropollutants by clean NF90 membranes varied from 87.9 to more than 99.9%, while that of NF270 membranes ranged from 32.1 to 92.3%. Clear time-dependence was observed for the rejection of hydrophobic micropollutants, which was attributed to the adsorption of micropollutants on the membrane. Fouling with humic acid had a negligible influence on the rejection of organic micropollutants by NF90 membranes, while considerable effects were observed with NF270 membranes, which are significantly looser than NF90 membranes. The observed enhancement in the rejection of organic micropollutants by fouled NF270 membranes was attributed to pore blocking, which was a dominating fouling mechanism for loose NF membranes. Changes in the ionic strength (from 10 to 20 mM reduced micropollutant rejection by both fouled NF membranes, especially for the rejection of dimethyl phthalate and diethyl phthalate by NF270 membranes (from 65.8 to 25.0% for dimethyl phthalate and 75.6 to 33.3% for diethyl phthalate.

  12. In-line quantification and characterization of membrane fouling

    KAUST Repository

    Bucs, Szilard

    2016-06-16

    Methods of detecting, quantifying and/or characterizing the fouling of a device from a combination of pressure and spectroscopic data are provided. The device can be any device containing components susceptible to fouling. Components can include membranes, pipes, or reactors. Suitable devices include membrane devices, heat exchangers, and chemical or bio-reactors. Membrane devices can include, for example, microfiltration devices, ultrafiltration devices, nanofiltration devices, reverse osmosis, forward osmosis, osmosis, reverse electrodialysis, electro- deionisation or membrane distillation devices. The methods can be applied to any type of membrane, including tubular, spiral, hollow fiber, flat sheet, and capillary membranes. The spectroscopic characterization can include measuring one or more of the absorption, fluorescence, or raman spectroscopic data of one or more foulants. The methods can allow for the early detection and/or characterization of fouling. The characterization can include determining the specific foulant(s) or type of foulant(s) present. The characterization of fouling can allow for the selection of an appropriate de-fouling method and timing.

  13. The new performance calculation method of fouled axial flow compressor.

    Science.gov (United States)

    Yang, Huadong; Xu, Hong

    2014-01-01

    Fouling is the most important performance degradation factor, so it is necessary to accurately predict the effect of fouling on engine performance. In the previous research, it is very difficult to accurately model the fouled axial flow compressor. This paper develops a new performance calculation method of fouled multistage axial flow compressor based on experiment result and operating data. For multistage compressor, the whole compressor is decomposed into two sections. The first section includes the first 50% stages which reflect the fouling level, and the second section includes the last 50% stages which are viewed as the clean stage because of less deposits. In this model, the performance of the first section is obtained by combining scaling law method and linear progression model with traditional stage stacking method; simultaneously ambient conditions and engine configurations are considered. On the other hand, the performance of the second section is calculated by averaged infinitesimal stage method which is based on Reynolds' law of similarity. Finally, the model is successfully applied to predict the 8-stage axial flow compressor and 16-stage LM2500-30 compressor. The change of thermodynamic parameters such as pressure ratio, efficiency with the operating time, and stage number is analyzed in detail.

  14. The New Performance Calculation Method of Fouled Axial Flow Compressor

    Directory of Open Access Journals (Sweden)

    Huadong Yang

    2014-01-01

    Full Text Available Fouling is the most important performance degradation factor, so it is necessary to accurately predict the effect of fouling on engine performance. In the previous research, it is very difficult to accurately model the fouled axial flow compressor. This paper develops a new performance calculation method of fouled multistage axial flow compressor based on experiment result and operating data. For multistage compressor, the whole compressor is decomposed into two sections. The first section includes the first 50% stages which reflect the fouling level, and the second section includes the last 50% stages which are viewed as the clean stage because of less deposits. In this model, the performance of the first section is obtained by combining scaling law method and linear progression model with traditional stage stacking method; simultaneously ambient conditions and engine configurations are considered. On the other hand, the performance of the second section is calculated by averaged infinitesimal stage method which is based on Reynolds’ law of similarity. Finally, the model is successfully applied to predict the 8-stage axial flow compressor and 16-stage LM2500-30 compressor. The change of thermodynamic parameters such as pressure ratio, efficiency with the operating time, and stage number is analyzed in detail.

  15. Regeneration of sulfur-fouled bimetallic Pd-based catalysts.

    Science.gov (United States)

    Chaplin, Brian P; Shapley, John R; Werth, Charles J

    2007-08-01

    Pd-based catalysts provide efficient and selective reduction of several drinking water contaminants, but their long-term application requires effective treatments for catalyst regeneration following fouling by constituents in natural waters. This studytested alumina-supported Pd-Cu and Pd-In bimetallic catalysts for nitrate reduction with H2 after sulfide fouling and oxidative regeneration procedures. Both catalysts were severely deactivated after treatment with microM levels of sulfide. Regeneration was attempted with dissolved oxygen, hydrogen peroxide, sodium hypochlorite, and heated air. Only sodium hypochlorite and heated air were effective regenerants, specifically restoring nitrate reduction rates for a Pd-In/gamma-Al2O3 catalyst from 20% to between 39 and 60% of original levels. Results from ICP-MS revealed that sodium hypochlorite caused dissolution of Cu from the Pd-Cu catalyst but that the Pd-In catalyst was chemically stable over a range of sulfide fouling and oxidative regenerative conditions. Analysis byXPS indicated that PdS and In2S3 complexes form during sulfide fouling, where sulfur is present as S2-, and that regeneration with sodium hypochlorite converts a portion of the S2- to S6+, with a corresponding increase in reduction rates. These results indicate that Pd-In catalysts show exceptional promise for being robust under fouling and regeneration conditions that may occur when treating natural waters.

  16. Zeta-potential of fouled thin film composite membrane

    Energy Technology Data Exchange (ETDEWEB)

    Ikeda, K.; Hachisuka, H.; Nakamura, T. [Nitto denko Corp., Ibaraki, (Japan); Kimura, S. [Kogakuin University, Tokyo (Japan). Dept. of Environ. Chemical Engineering; Ueyama, K. [Osaka University, Osaka (Japan). Dept. of Chemical Engineering

    1999-10-01

    The surface zeta-potential of a cross-linked polyamide thin film composite reverse osmosis membrane was measured using an electrophoresis method. It was confirmed that this method could be effectively applied to analyze the fouling of such membranes. It is known that the water flux of membranes drastically decreases as a result of fouling by surfactants. Although the surfactants adsorbed on reverse osmosis membranes could not be detected by conventional methods such as SEM, EDX and FT-IR, their presence could be clarified by the profile measurements of the surface zeta-potential. The profiles of the membrane surface zeta-potentials changed to more positive values in the measured pH range as a result of fouling by cationic or amphoteric surfactants. This measuring method of surface zeta-potentials allowed us to analyze a very small amount of fouling of a thin film composite reverse osmosis membrane. This method could be used to analyze the fouled surface of the thin film composite reverse osmosis membrane which is used for production of ultrapure water and shows a remarkable decrease in flux. It also became clear that this method is easy and effective for the reverse osmosis membrane surface analysis of adsorbed materials such as surfactants. (author)

  17. ENVIRONMENTAL ASPECTS OF MODERNIZATION OF HIGH POWER WATER-HEATING BOILERS

    Directory of Open Access Journals (Sweden)

    P. M. Glamazdin

    2016-01-01

    Full Text Available Boilers of KVGM and PTVM series are characterized by high values of NOx and CO content in the combustion products. Reduction of NOx and CO content can be achieved by two ways: by installing the condensing heat recovery unit at the boiler outlet and by improving the heat and mass transfer processes in boiler furnaces. Application of the condensing heat recovery units causes pollution of resulting condensate by low-concentration acids. The authors conducted a study in order to determine the effectiveness of the previously applied methods of suppressing the emission of nitrogen oxides in the boilers of these types. Equalization of the temperature field and, consequently, enhancement of heat transfer in the furnace by substitution the used burners by the more advanced ones, the design of which facilitates reduction the emission of nitrogen oxides, were applied to all the upgraded facilities. The studies fulfilled demonstrate that a reduction of NOx emissions in water-heating high power boilers is fairly possible by means of modernization of the latter. The authors have developed the project of the PTVM-30 boiler modernization, which was implemented at a large boiler plant in the city of Vinnitsa (Ukraine. The project included a number of technical solutions. Six burners were replaced by the two ones that were located in the hearth; also the hearth screen was dismantled. At the same time, reducing the total surface area of the heating caused by the exclusion of hearth screen was compensated by filling the locations of the six embrasures of staff burners on the side screens with straightened furnace tubes. Installing the burners separate from the screen made it possible to eliminate the transfer of vibration to the furnace tubes, and – via them – to the boilers setting. Automation provided “associated regulations”. Draught machines were equipped with frequency regulators. During commissioning of the boiler the studies were carried out that

  18. Deposition and High-Temperature Corrosion in Biomass-Fired Boilers

    DEFF Research Database (Denmark)

    Michelsen, Hanne Philbert

    This thesis describes the fate of potassium, chlorine, and sulfur in regard to deposition and corrosion problems in straw-fired boilers. Full-scale deposition studies at Rudkøbing CHP, Kyndby Power Station and Masnedø CHP revealed that straw may form massive deposits in the convective pass...... has only been detected in insignificant amounts in mature deposits in straw-fired boilers formed over months of operation.The corrosion of superheater tubes is closely connected to the material which are deposited on the surface and deposits containing potassium chloride can cause severe high......-temperature corrosion at elevated metal temperatures. Lab-scale corrosion experiments, where metal test elements were covered with synthetic potassium salts and real deposits and exposed to a simulated flue gas containing HCl(g) and SO2(g), provided information about the corrosion rate and corrosion mechanisms...

  19. Apparatus to reduce or eliminate combustor perimeter wall erosion in fluidized bed boilers or reactors

    Energy Technology Data Exchange (ETDEWEB)

    McCoy, D.E.

    1993-08-31

    A fluidized bed boiler or reactor is described comprising a housing, a reaction chamber within said housing, air distribution means within said reaction chamber, a plurality of water wall tubes approximately vertically disposed and arranged about the interior walls of said housing so as to define said reaction chamber, wherein the improvement comprises: providing at least a portion of the vertically disposed water wall tubes with an outward slope in the range between 2.5 to 10 such that the cross-section of the upper portion of said reaction chamber is smaller than the cross-section of the lower portion of said reaction chamber so as to reduce or eliminate erosion of said water wall tubes caused by impact from downward flowing solid particles.

  20. Species interactions within a fouling diatom community: Roles of nutrients, initial inoculum and competitive strategies

    Digital Repository Service at National Institute of Oceanography (India)

    Mitbavkar, S.; Anil, A

    Diatoms constitute an important component of the fouling community. Although a lot of work has dealt with the fouling diatom community structure, work on the species interactions within the community is still meager. In this regard, a study...

  1. Corrosion of oil-fired domestic boilers

    Energy Technology Data Exchange (ETDEWEB)

    Koebel, M.; Elsener, M.

    1989-05-01

    Depending on the surface temperature of the flue gas side the corrosion of oil fired domestic boilers proceeds either mainly by acid corrosion or by oxygen corrosion: (1) At surface temperatures of 60/sup 0/C and higher the corrosion mechanism of acid corrosion prevails and the corrosion rates amount to 0.1-0.3 mm/year (values referred to continuous burner operation). The corrosion products consist of soluble iron(II)- and iron(III)sulfates. Higher corrosion rates can be attributed to an appreciable catalytic formation of sulfur trioxide on the corrosion products formed on the convective heating surfaces. (2) At surface temperatures of 40/sup 0/C the mechanism of oxygen corrosion already dominates and the corrosion rates are about ten times higher (1.5-3 mm/year, referred to continuous burner operation). The high portion of iron oxide hydrates, especially goethit (/alpha/-FeOOH), makes the corrosion products difficult to remove. (3) Distinctly reduced service lives are also expected for the so called reduced temperature boilers ('Niedertemperaturkessel') and low temperature boilers ('Tieftemperaturkessel'): According to the manufacturers these boilers may be operated at boiler water temperatures well below 60/sup 0/C, as they are equipped with constructive measures to enhance the surface temperature on the flue gas side. However, these measures are only fully effective under stationary conditions. Some of the results were obtained from weight loss measurements on test specimen made from St 35.8 and gray cast iron, that were exposed to the flue gases of an fired experimental boiler. Other important results come from field measurements of the sulfuric acid content of about 30 boilers that are in practical use. (orig.).

  2. Industrial fouling: problem characterization, economic assessment, and review of prevention, mitigation, and accommodation techniques

    Energy Technology Data Exchange (ETDEWEB)

    Garrett-Price, B.A.; Smith, S.A.; Watts, R.L.

    1984-02-01

    A comprehensive overview of heat exchanger fouling in the manufacturing industries is provided. Specifically, this overview addresses: the characteristics of industrial fouling problems; the mitigation and accommodation techniques currently used by industry; and the types and magnitude of costs associated with industrial fouling. A detailed review of the fouling problems, costs and mitigation techniques is provided for the food, textile, pulp and paper, chemical, petroleum, cement, glass and primary metals industries.

  3. Scandinavian baffle boiler design revisited

    Directory of Open Access Journals (Sweden)

    Stepanov Borivoj Lj.

    2015-01-01

    Full Text Available The aim of this paper is to examine whether the use of baffles in a combustion chamber, one of the well-known low-cost methods for the boiler performance improvement, can be enhanced. Modern day tools like computational fluid dynamics were not present at the time when these measures were invented, developed and successfully applied. The objective of this study is to determine the influence of location and length of a baffle in a furnace, for different mass flows, on gas residence time. The numerical simulations have been performed of a simple Scandinavian stove like furnace. The isothermal model is used, while air is used as a medium and turbulence is modeled by realizable k-epsilon model. The Lagrange particle tracking is used for the residence time distribution determination. The statistical analysis yielded the average residence time. The results of the computational fluid dynamics studies for different baffle positions, dimensions and flow rates show from up to 17% decrease to up to 13 % increase of residence time. The conclusion is that vertical position of the baffle is the most important factor, followed by the length of the baffle, while the least important showed to be the mass flow. [Projekat Ministarstva nauke Republike Srbije, br. III 43008: Development of methods, sensors and systems for monitoring of quality of water, air and land

  4. Pretreatment and Membrane Hydrophilic Modification to Reduce Membrane Fouling

    Directory of Open Access Journals (Sweden)

    Huaqiang Chu

    2013-09-01

    Full Text Available The application of low pressure membranes (microfiltration/ultrafiltration has undergone accelerated development for drinking water production. However, the major obstacle encountered in its popularization is membrane fouling caused by natural organic matter (NOM. This paper firstly summarizes the two factors causing the organic membrane fouling, including molecular weight (MW and hydrophilicity/hydrophobicity of NOM, and then presents a brief introduction of the methods which can prevent membrane fouling such as pretreatment of the feed water (e.g., coagulation, adsorption, and pre-oxidation and membrane hydrophilic modification (e.g., plasma modification, irradiation grafting modification, surface coating modification, blend modification, etc.. Perspectives of further research are also discussed.

  5. A New Concept of Ultrafiltration Fouling Control: Backwashing with Low Ionic Strength Water

    NARCIS (Netherlands)

    Li, S.

    2011-01-01

    Ultrafiltration (UF) is a proven technology in water treatment nowadays. However, fouling remains a major challenge in the operation of UF, especially in regard to colloidal NOM fouling. In general, a number of colloidal NOM fouling mechanisms may occur, such as adsorption, gel formation. Colloidal

  6. Grafting polymer brushes on biomimetic structural surfaces for anti-algae fouling and foul release.

    Science.gov (United States)

    Wan, Fei; Pei, Xiaowei; Yu, Bo; Ye, Qian; Zhou, Feng; Xue, Qunji

    2012-09-26

    Sylgard-184 silicone elastomer negative replica and resorcinol-formaldehyde (RF) positive replica were made by biomimicking the patterns of natural Trifolium and three other kinds of leaves using the micromolding lithography. An effective antifouling (AF) polymer, poly(3-sulfopropyl methacrylate) (PSPMA), was then grafted on these replica surfaces via the surface-initiated atom transfer radical polymerization (SI-ATRP). The AF property of the modified biomimetic surfaces was tested via the settlement assay with two microalgae in different sizes, and their fouling-release (FR) property was evaluated by the removal assay. The results indicate that the structure of microspines on Trifolium leaf can inhibit settlement of microalgae and facilitate the cell release. The AF property was improved by modification with PSPMA brushes.

  7. Measurement Methodology for Monitoring Fouling Resistance in Condenser of Chiller

    Institute of Scientific and Technical Information of China (English)

    YU Dan; GAN Li-si; CAO Yong

    2009-01-01

    This paper established an on-line monitoring model for fouling resistance of cooling water based on heat transfer theory,which was mainly applied to the fouling resistance test for condenser of chiller in operation,and the test requirements were presented.It proves that the load ratio of chiller has big influence on the test re-sult,and the best load ratio for test is the range of 80%~100%.A case has been executed to validate the mod-el's feasibility.

  8. Cleaning protocol for a FO membrane fouled in wastewater reuse

    KAUST Repository

    Valladares Linares, Rodrigo

    2013-05-30

    Forward osmosis (FO) is an emerging technology which can be applied in water reuse applications. Osmosis is a natural process that involves less energy consumption than reverse osmosis (RO), and therefore can be applied as a dilution process before low-pressure RO; it is expected to compete favourably against current advanced water reuse technologies that use microfiltration/ultrafiltration and RO. The focus of this research was to assess the efficiency of different cleaning procedures to remove fouling from the surface of a FO membrane during the operation of a submerged system working in FO-mode (active layer (AL) facing feed solution) intended for secondary wastewater effluent (SWWE) recovery, using seawater as draw solution (DS), which will be diluted and can further be fed to a low-pressure RO unit to produce fresh water. Natural organic matter (NOM) fouling was expected to affect the AL, while for the support layer (SL), transparent exopolymer particles (TEP) were used as indicators of fouling due to their stickiness and propensity to enhance the attachment of other foulants in seawater on the membrane surface. The composition of the NOM fouling layer was determined after proper characterisation with a liquid chromatograph coupled with organic carbon detection (LC-OCD), showing biopolymers and protein-like substances as the main constituents. NOM fouling showed high hydraulic reversibility after a 25% flux decline was observed, up to 89.5% when in situ air scouring for 15 min was used as a cleaning technique. Chemical cleaning with a mixture of Alconox, an industrial detergent containing phosphates, and sodium EDTA showed to increase the reversibility (93.6%). Osmotic backwash using a 4% NaCl solution and DI water proved to be ineffective to recover flux due to the salt diffusion phenomena occurring at the AL. Part of the flux that could not be recovered is attributable to TEP fouling on the SL, which forms clusters clearly identifiable with an optical

  9. Boiler house modernization through shared savings program

    Energy Technology Data Exchange (ETDEWEB)

    Breault, R.W. [Tecogen, Waltham, MA (United States)

    1995-12-31

    Throughout Poland as well as the rest of Eastern Europe, communities and industries rely on small heat only boilers to provide district and process heat. Together these two sectors produce about 85,000 MW from boilers in the 2 to 35 MW size range. The bulk of these units were installed prior to 1992 and must be completely overhauled to meet the emission regulations which will be coming into effect on January 1, 1998. Since the only practical fuel is coal in most cases, these boilers must be either retrofit with emission control technology or be replaced entirely. The question that arises is how to accomplish this given the current tight control of capital in Poland and other East European countries. A solution that we have for this problem is shared savings. These boilers are typically operating with a quiet low efficiency as compared to western standards and with excessive manual labor. Installing modernization equipment to improve the efficiency and to automate the process provides savings. ECOGY provides the funds for the modernization to improve the efficiency, add automation and install emission control equipment. The savings that are generated during the operation of the modernized boiler system are split between the client company and ECOGY for a number of years and then the system is turned over in entirety to the client. Depending on the operating capacity, the shared savings agreement will usually span 6 to 10 years.

  10. photomultiplier tube

    CERN Multimedia

    photomultiplier tubes. A device to convert light into an electric signal (the name is often abbreviated to PM). Photomultipliers are used in all detectors based on scintillating material (i.e. based on large numbers of fibres which produce scintillation light at the passage of a charged particle). A photomultiplier consists of 3 main parts: firstly, a photocathode where photons are converted into electrons by the photoelectric effect; secondly, a multiplier chain consisting of a serie of dynodes which multiply the number of electron; finally, an anode, which collects the resulting current.

  11. photomultiplier tubes

    CERN Multimedia

    photomultiplier tubes. A device to convert light into an electric signal (the name is often abbreviated to PM). Photomultipliers are used in all detectors based on scintillating material (i.e. based on large numbers of fibres which produce scintillation light at the passage of a charged particle). A photomultiplier consists of 3 main parts: firstly, a photocathode where photons are converted into electrons by the photoelectric effect; secondly, a multiplier chain consisting of a serie of dynodes which multiply the number of electron; finally, an anode, which collects the resulting current.

  12. Straight Fin for Fouling Reduction in Heat-Pipe Exchanger%直翅片在热管换热器减轻积灰中的应用

    Institute of Scientific and Technical Information of China (English)

    马勇; 虞斌; 郝彪; 芮志平

    2013-01-01

    提出了使用纵向直翅片管代替光管来缓解积灰.采用流体力学软件Fluent分别对光管管束和直翅片管束进行数值模拟,对比其流场特性.结果表明:在光管背风区会产生负压尾涡区,灰尘易被卷入涡区,而直翅片管的外形更接近流线,边界层分离点明显后移,并且直翅片对尾涡区还有一定的分隔作用,颗粒被气流卷吸的强度明显小于光管,故很好地阻碍了积灰的产生.%Replacing the light tube with longitudinal finned tube to alleviate the fouling was proposed.Having the bundles of light tube and straight finned tube simulated with the Fluent and then having their flow field characteristics compared show that the negative pressure wake vortex easily occurs in the light tube's leeward areas along with dust,and the shape of straight finned tube becomes closer to streamline,and its separation point of the boundary layer shifts backward significantly,in addition,the straight fin can divide the vortex area,and the strength of dust's entrainment by airflow is significantly less than light tube,this can prevent the fouling occurrence.

  13. Independent Research and Design of 600-MW Supercritical CFB Boiler

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    In order to further develop and improve the technologies for large-capacity supercritical CFB boiler, the key technologies for large CFB boiler were systematically studied, based on the development of first domestically-made 210-MW and 330-MW CFB boilers. The scheme of 600-MW supercritical CFB boiler was designed, including the furnace structure, key components, steam-water system and auxiliary systems, which laid a technical foundation for the engineering applications.

  14. Application of GPRS and GIS in Boiler Remote Monitoring System

    OpenAIRE

    Hongchao Wang; Yifeng Wu

    2012-01-01

    Application of GPRS and GIS in boiler remote monitoring system was designed in this paper by combining the advantage of GPRS and GIS in remote data transmission with configuration monitoring technology. The detail information of the operating conditions of the industrial boiler can be viewed by marking the location of boiler on the electronic map dynamically which can realize the unified management for industrial boiler of a region or city conveniently. Experimental application show that the ...

  15. Experimental Investigation of Heat Transfer and Pressure Drop Characteristics of H-type Finned Tube Banks

    OpenAIRE

    2014-01-01

    H-type finned tube heat exchanger elements maintain a high capacity for heat transfer, possess superior self-cleaning properties and retain the ability to effect flue gas waste heat recovery in boiler renovations. In this paper, the heat transfer and pressure drop characteristics of H-type finned tube banks are studied via an experimental open high-temperature wind tunnel system. The effects of fin width, fin height, fin pitch and air velocity on fin efficiency, convective heat transfer coe...

  16. Efficient heat-transfer surfaces assembled from partially finned flat-oval tubes

    Science.gov (United States)

    Pis'mennyi, E. N.

    2011-04-01

    The state of finned convective heat-transfer surfaces and prospects for using them in power engineering and industry are briefly reviewed. The characteristics of a heat-recovery economizer made of partially finned flat-oval tubes are presented by way of comparing them with design versions employing known types of finned tubes, and the results gained from its operation downstream of a PTVM-30M boiler are given.

  17. Protein fouling in carbon nanotubes enhanced ultrafiltration membrane: Fouling mechanism as a function of pH and ionic strength

    KAUST Repository

    Lee, Jieun

    2016-11-04

    The protein fouling behavior was investigated in the filtration of the multiwall carbon nanotube (MWCNT) composite membrane and commercial polyethersulfone ultrafiltration (PES-UF) membrane. The effect of solution chemistry such as pH and ionic strength on the protein fouling mechanism was systematically examined using filtration model such as complete pore blocking, intermediate pore blocking and cake layer formation. The results showed that the initial permeate flux pattern and fouling behavior of the MWCNT composite membrane were significantly influenced by pH and ionic strength while the effect of PES-UF membrane on flux was minimal. In a lysozyme (Lys) filtration, the severe pore blocking in the MWCNT membrane was made by the combined effect of intra-foulant interaction (Lys-Lys) and electrostatic repulsion between the membrane surface and the foulant at pH 4.7 and 10.4, and increasing ionic strength where the foulant-foulant interaction and membrane-fouling interaction were weak. In a bovine serum albumin (BSA) filtration, severe pore blocking was reduced by less deposition via the electrostatic interaction between the membrane and foulant at pH 4.7 and 10.4 and increasing ionic strength, at which the interaction between the membrane and BSA became weak. For binary mixture filtration, the protein fouling mechanism was more dominantly affected by foulant-foulant interaction (Lys-BSA, Lys-Lys, and BSA-BSA) at pH 7.0 and increase in ionic strength. This research demonstrates that MWCNT membrane fouling can be alleviated by changing pH condition and ionic strength based on the foulant-foulant interaction and the electrostatic interaction between the membrane and foulant.

  18. 46 CFR 176.812 - Pressure vessels and boilers.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 7 2010-10-01 2010-10-01 false Pressure vessels and boilers. 176.812 Section 176.812... TONS) INSPECTION AND CERTIFICATION Material Inspections § 176.812 Pressure vessels and boilers. (a.... (b) Periodic inspection and testing requirements for boilers are contained in § 61.05 in subchapter...

  19. 40 CFR 761.71 - High efficiency boilers.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 30 2010-07-01 2010-07-01 false High efficiency boilers. 761.71... PROHIBITIONS Storage and Disposal § 761.71 High efficiency boilers. (a) To burn mineral oil dielectric fluid containing a PCB concentration of ≥50 ppm, but boiler shall comply with the...

  20. 46 CFR 56.50-30 - Boiler feed piping.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 2 2010-10-01 2010-10-01 false Boiler feed piping. 56.50-30 Section 56.50-30 Shipping... APPURTENANCES Design Requirements Pertaining to Specific Systems § 56.50-30 Boiler feed piping. (a) General... least two separate means of supplying feed water for the boilers. All feed pumps shall be fitted...

  1. 46 CFR 109.205 - Inspection of boilers and machinery.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 4 2010-10-01 2010-10-01 false Inspection of boilers and machinery. 109.205 Section 109... OPERATIONS Tests, Drills, and Inspections § 109.205 Inspection of boilers and machinery. The chief engineer or engineer in charge, before he assumes charge of the boilers and machinery of a unit shall...

  2. THERMAL BOUNDARY LAYER IN CFB BOILER RISER

    Institute of Scientific and Technical Information of China (English)

    Jinwei; Wang; Xinmu; Zhao; Yu; Wang; Xing; Xing; Jiansheng; Zhang; Guangxi; Yue

    2006-01-01

    Measurement of temperature profiles of gas-solid two-phase flow at different heights in commercial-scale circulating fluidized bed (CFB) boilers was carried out. Experimental results showed that the thickness of thermal boundary layer was generally independent of the distance from the air distributor, except when close to the riser outlet. Through analysis of flow and combustion characteristics in the riser, it was found that the main reasons for the phenomena were: 1) the hydrodynamic boundary layer was thinner than the thermal layer and hardly changed along the CFB boiler height, and 2) both radial and axial mass and heat exchanges were strong in the CFB boiler. Numerical simulation of gas flow in the outlet zone confirmed that the distribution of the thermal boundary layer was dominated by the flow field characteristics.

  3. Evaluation of thermal overload in boiler operators.

    Science.gov (United States)

    Braga, Camila Soares; Rodrigues, Valéria Antônia Justino; Campos, Julio César Costa; de Souza, Amaury Paulo; Minette, Luciano José; de Moraes, Angêlo Casali; Sensato, Guilherme Luciano

    2012-01-01

    The Brazilians educational institutions need a large energy demand for the operation of laundries, restaurants and accommodation of students. Much of that energy comes from steam generated in boilers with wood fuel. The laboral activity in boiler may present problems for the operator's health due to exposure to excessive heat, and its operation has a high degree of risk. This paper describes an analysis made the conditions of thermal environment in the operation of a B category boiler, located at a Higher Education Institution, located in the Zona da Mata Mineira The equipments used to collect data were Meter WBGT of the Heat Index; Meter of Wet Bulb Index and Globe Thermometer (WBGT); Politeste Instruments, an anemometer and an Infrared Thermometer. By the application of questionnaires, the second phase consisted of collecting data on environmental factors (temperature natural environment, globe temperature, relative humidity and air velocity). The study concluded that during the period evaluated, the activity had thermal overload.

  4. Direct contact, binary fluid geothermal boiler

    Science.gov (United States)

    Rapier, Pascal M.

    1982-01-01

    Energy is extracted from geothermal brines by direct contact with a working fluid such as isobutane which is immiscible with the brine in a geothermal boiler. The geothermal boiler provides a distributor arrangement which efficiently contacts geothermal brine with the isobutane in order to prevent the entrainment of geothermal brine in the isobutane vapor which is directed to a turbine. Accordingly the problem of brine carry-over through the turbine causes corrosion and scaling thereof is eliminated. Additionally the heat exchanger includes straightening vanes for preventing startup and other temporary fluctuations in the transitional zone of the boiler from causing brine carryover into the turbine. Also a screen is provided in the heat exchanger to coalesce the working fluid and to assist in defining the location of the transitional zone where the geothermal brine and the isobutane are initially mixed.

  5. Effect of oxygen on fouling behavior in lead bismuth coolant systems

    Science.gov (United States)

    Niu, Fenglei; Candalino, Robert; Li, Ning

    2007-06-01

    This experimental research investigates the effects of the oxygen in lead-bismuth eutectic on fouling. The analysis was carried out by performing three tests with different oxygen concentration on the recuperator where the heat transfer rate is susceptible to fouling, and introducing a correlation for the fouling factor. The comparison of fouling factors obtained with each oxygen level is presented, the relationship between fouling factors and oxygen concentrations is correlated, and the effects of oxidation on heat transfer are demonstrated qualitatively by wetting conditions of the samples.

  6. Planning Annual Shutdown Inspection for BFB Boiler

    OpenAIRE

    Sorsa, Tatu

    2014-01-01

    The goal of this thesis was to create an illustrative guidebook of annual inspection planning for BFB boiler to help power plant operator when planning of annual inspection is topical. This thesis was made for Andritz Oy and it is based on inspection reports and experiences of BFB boiler’s maintenance and inspection staff. In this thesis it is shown how to plan an annual inspection for BFB boiler and thesis gives good tools and hints for operator to manage inspection from the beginning ...

  7. Transients in a circulating fluidized bed boiler

    Science.gov (United States)

    Baskakov, A. P.; Munts, V. A.; Pavlyuk, E. Yu.

    2013-11-01

    Transients in a circulating fluidized bed boiler firing biomass are considered. An attempt is made to describe transients with the use of concepts applied in the automatic control theory. The parameters calculated from an analysis of unsteady heat balance equations are compared with the experimental data obtained in the 12-MW boiler of the Chalmers University of Technology. It is demonstrated that these equations describe the transient modes of operation with good accuracy. Dependences for calculating the time constants of unsteady processes are obtained.

  8. Central heating: fossil-fired boilers

    Energy Technology Data Exchange (ETDEWEB)

    Blazek, C.F.; Baker, N.R.; Tison, R.R.

    1979-05-01

    This evaluation provides performance and cost data for fossil-fuel-fired steam boilers, hot-water generators, and thermal fluid generators currently available from manufacturers. Advanced-technology fluidized-bed boilers also are covered. Performance characteristics investigated include unit efficiencies, turndown capacity, and pollution requirements. Costs are tabulated for equipment and installation of both field-erected and packaged units. The information compiled in this evaluation will assist in the process of selecting energy-conversion units required for industrial, commercial, and residential applications.

  9. A tube-in-tube thermophotovoltaic generator

    Energy Technology Data Exchange (ETDEWEB)

    Ashcroft, J.; Campbell, B.; Depoy, D.

    1996-12-31

    A thermophotovoltaic device includes at least one thermal radiator tube, a cooling tube concentrically disposed within each thermal radiator tube and an array of thermophotovoltaic cells disposed on the exterior surface of the cooling tube. A shell having a first end and a second end surrounds the thermal radiator tube. Inner and outer tubesheets, each having an aperture corresponding to each cooling tube, are located at each end of the shell. The thermal radiator tube extends within the shell between the inner tubesheets. The cooling tube extends within the shell through the corresponding apertures of the two inner tubesheets to the corresponding apertures of the two outer tubesheets. A plurality of the thermal radiator tubes can be arranged in a staggered or an in-line configuration within the shell.

  10. Boiler and steam generator corrosion. (Latest citations from the NTIS bibliographic database). Published Search

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-11-01

    The bibliography contains citations concerning corrosion effects, mechanisms, detection, and inhibition in fossil fuel fired boilers and nuclear powered steam generators. Corrosion studies performed on the water side and hot gas side of heat exchanger tubes and support structures are presented. Water treatment, chemical cleaning, and descaling methods are considered. Although emphasis is placed on large-scale power generation systems, residential and commercial heating systems are also discussed. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  11. Temperature and body weight affect fouling of pig pens

    NARCIS (Netherlands)

    Aarnink, A.J.A.; Schrama, J.W.; Heetkamp, M.J.W.; Stefanowska, J.; Huynh, T.T.T.

    2006-01-01

    Fouling of the solid lying area in pig housing is undesirable for reasons of animal welfare, animal health, environmental pollution, and labor costs. In this study the influence of temperature on the excreting and lying behavior of growing-finishing pigs of different BW (25, 45, 65, 85, or 105 kg) w

  12. Electromagnetic anti-fouling technology for prevention of scale

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    An electromagnetic anti-fouling technology(EAFT) was developed further. The operating principle of the EAFT was presented using fundamental physics laws. To validate the effect of EAFT and identify the mechanism, a circulating flow setup was built. A series of fouling tests were carried out with and without EAFT, measuring fouling thermal resistance as function of time, making scanning electron microscope images and analyzing the particles size distribution in solution by dynamics light scattering technology. The main results were as follows: 1)All the precipitated crystals in solution were calcite and there were little differences between with EAFT and without EAFT in the experimental range. 2) The number of precipitate nucleation in solution was small and the particle growth was slow without EAFT. In opposition to the case untreated, a rapid particle growth was observed and the number of nucleation was expected to be large, due to the fact that the EAFT effectively increases the ions and crystals collision frequency and effectiveness by utilizing the induced electric field. It is indicated that the particle growth is promoted mainly by coagulation process but not nucleation growth. 3) The EAFT could prolong the delay time of fouling greatly, and after the delay time, the thermal resistance quickly increased. Therefore, in order to mitigate scale significantly, the floccules in solution should be deposited beforehand in a low-lying area of the exchangers and let off in time.

  13. Fouling acorn barnacles in China——a review

    Institute of Scientific and Technical Information of China (English)

    CAO Wenhao; YAN Tao; LI Zufu; LI Jing; CHENG Zhiqiang

    2013-01-01

    We review the species composition,distribution,and seasonal variation of fouling acorn barnacles in Chinese waters—from Bohai Sea and Yellow Sea to East and South China Seas.Thirty-two species of acorn barnacles were found,of which,the dominant species are Amphibalanus amphitrite,A.reticulatus,A.variegates,Balanus trigonus,Fistulobalanus kondakovi,Megabalanus tintinnabulum,Striatobalanus amaryllis,and Eurapha withersi in the fouling communities.A.amphitrite is the dominant species in the coastal waters of Bohai Sea and Yellow Sea and A.reticulatus is dominant in the East and South China Seas.The settlement period of fouling acorn barnacles is usually in summer and autumn.From north to south with the decrease of latitude,their settlement period obviously extends,even to the whole year,and the species number also increases.Other environmental factors,such as salinity and distance from shore,also play an important role in the distribution of fouling acorn barnacles.

  14. SINTESIS MEMBRAN ULTRAFILTRASI NON FOULING UNTUK APLIKASI PEMPROSESAN BAHAN PANGAN

    Directory of Open Access Journals (Sweden)

    Luqman Buchori

    2012-02-01

    Full Text Available Membran ultrafiltrasi (UF telah terbukti sebagai proses yang menjanjikan untuk aplikasi di bidang pemprosesan bahan pangan. Namun, peristiwa fouling dapat menurunkan kinerja membran secara signifikan. Meskipun banyak metode pengendalian fouling telah diusulkan, dalam banyak kasus kinerja proses sangat dipengaruhi oleh membran sebagai jantung dari proses. Dalam makalah ini pengendalian fouling dilakukan dengan memodifikasi permukaan membran dengan teknik kopolimerisasi foto-grafting. Acrylic acid (AA, acrylamido methylpropane sulfonic acid (AMPS, poly(ethylene glycol methacrylate (PEGMA, dan N,N-dimethyl-N-(2-methacryloyloxyethyl-N-(3sulfopropylammonium betaine sebagai senyawa zwitterion (ZI digunakan sebagai monomer fungsional. Pengaruh waktu iradiasi terhadap efektifitas modifikasi telah diamati. Kinerja membran hasil modifikasi kemudian diuji dengan menggunakan berbagai model larutan foulant yang meliputi larutan protein, larutan polisakarida dan larutan polifenol. Hasil penelitian menunjukkan bahwa sifat non fouling membran sangat jelas dapat ditingkatkan baik dengan PEGMA maupun dengan ZI. Secara umum, modifikasi menggunakan PEGMA menunjukkan kinerja yang lebih baik. Larutan polifenol menunjukkan karakter foulant yang paling kuat diantara model foulant.

  15. Reduced fouling of ultrafiltration membranes via surface fluorination

    Energy Technology Data Exchange (ETDEWEB)

    Sedath, R.H.; Yates, S.F.; Li, N.N.

    1993-03-01

    Surface fluorination can affect significantly the performance of an ultrafiltration membrane used to concentrate a food-related stream. Membranes fluorinated and tested as flat sheets exhibit higher initial fluxes, and do not foul as rapidly as untreated membranes. This improvement is linked to increased surface hydrophilicity, as shown in decreased contact angle with water. This increased hydrophilicity, in turn, is linked to the addition of fluorine and oxygen to the surface. The pilot plant study did-not show the difference in membrane flux and fouling observed in the flat sheet study. Instead, fluorinated and unfluorinated modules behaved similarly. Fouling by potato waste feed was severe and resulted in formation of an extensive gel layer within the module on the membrane surface. XPS, SEM and FTIR indicate that buildup of organic material occurred on both fluorinated and unfluorinated membranes, but SEM indicates that a fibrous mat of material was observed only on the nonfluorinated membrane. We conclude that in the pilot study, membrane fouling and gel formation were so extensive that the surface interaction effect was overwhelmed.

  16. CHEMICAL CLEANING OF NANOFILTRATION MEMBRANES FOULED BY ORGANIC MATTERS

    Directory of Open Access Journals (Sweden)

    CHARLENE C. H. KOO

    2016-07-01

    Full Text Available Membrane fouling is a term to describe non-integral substance on membrane surface which results in rapid decline of permeation flux and deteriorate the performance of membrane. Chemical cleaning agents especially like alkaline cleaners are most widely employed to restore the membrane performance. This research mainly investigated the potential use of sodium hydroxide (NaOH and sodium hypochlorite (NaOCl as the chemical cleaning agents to restore the permeate flux of organically fouled nanofiltration (NF membranes under varying applied pressure and flow condition. The performances of the cleaning protocols were quantified using flux recovery and resistance removal. The results demonstrated that NaOCl is more effective than NaOH. This observation is also in line with FTIR analysis in which the transmittance intensity showed by FTIR spectra of NaOCl is higher than that of NaOH. The results also reported that higher flux recovery and resistance removal were achieved when the fouled NF membranes were cleaned with higher concentration of chemical agents and applied pressure. However, the improvements of flux recovery and resistance removal by increasing the applied pressure were found insignificant at higher applied pressure range (16 to 18 bar than the lower applied pressure range (i.e. 12 to 14 bar. This research plays an important role by identifying the key parameters that could restore the flux of organically fouled NF membranes significantly.

  17. Influence of membrane properties on fouling in submerged membrane bioreactors

    NARCIS (Netherlands)

    Marel, van der P.; Zwijnenburg, A.; Kemperman, A.; Wessling, M.; Temmink, B.G.; Meer, van der W.

    2010-01-01

    Polymeric flat-sheet membranes with different properties were used in filtration experiments with activated sludge from a pilot-scale MBR to investigate the influence of membrane pore size, surface porosity, pore morphology, and hydrophobicity on membrane fouling. An improved flux-step method was us

  18. Water hammer reduces fouling during natural water ultrafiltration.

    Science.gov (United States)

    Broens, F; Menne, D; Pothof, I; Blankert, B; Roesink, H D W; Futselaar, H; Lammertink, R G H; Wessling, M

    2012-03-15

    Today's ultrafiltration processes use permeate flow reversal to remove fouling deposits on the feed side of ultrafiltration membranes. We report an as effective method: the opening and rapid closing of a valve on the permeate side of an ultrafiltration module. The sudden valve closure generates pressure fluctuations due to fluid inertia and is commonly known as "water hammer". Surface water was filtrated in hollow fiber ultrafiltration membranes with a small (5%) crossflow. Filtration experiments above sustainable flux levels (>125 l (m2h)(-1)) show that a periodic closure of a valve on the permeate side improves filtration performance as a consequence of reduced fouling. It was shown that this effect depends on flux and actuation frequency of the valve. The time period that the valve was closed proved to have no effect on filtration performance. The pressure fluctuations generated by the sudden stop in fluid motion due to the valve closure are responsible for the effect of fouling reduction. High frequency recording of the dynamic pressure evolution shows water hammer related pressure fluctuations to occur in the order of 0.1 bar. The pressure fluctuations were higher at higher fluxes (higher velocities) which is in agreement with the theory. They were also more effective at higher fluxes with respect to fouling mitigation.

  19. Self-Replenishing Vascularized Fouling-Release Surfaces

    Science.gov (United States)

    2014-01-01

    by generating a conditioning layer of proteins or polysaccharides to mask and condition the underlying surface.22,23 Fouling-release coatings are an...Webster, D. C. High Throughput Combinatorial Characterization of Thermosetting Silox- ane−urethane Coatings Having Spontaneously Formed Microtopo

  20. Temporal and spatial variation in the fouling of silicone coatings in Pearl Harbor, Hawaii.

    Science.gov (United States)

    Holm, E R; Nedved, B T; Phillips, N; Deangelis, K L; Hadfield, M G; Smith, C M

    2000-01-01

    An antifouling or foul-release coating cannot be globally effective if it does not perform well in a range of environmental conditions, against a diversity of fouling organisms. From 1996 to 1998, the field test sites participating in the United States Navy's Office of Naval Research 6.2 Biofouling program examined global variation in the performance of 3 silicone foul-release coatings, viz. GE RTV11, Dow Corning RTV 3140, and Intersleek (International Coatings Ltd), together with a control anticorrosive coating (Ameron Protective Coatings F-150 series). At the University of Hawaii's test site in Pearl Harbor, significant differences were observed among the coatings in the rate of accumulation of fouling. The control coating failed rapidly; after 180-220 d immersion a community dominated by molluscs and sponges developed that persisted for the remainder of the experiment. Fouling of the GE and Dow Corning silicone coatings was slower, but eventually reached a similar community structure and coverage as the control coatings. The Intersleek coating remained lightly fouled throughout the experiment. Spatial variation in the structure of the community fouling the coatings was observed, but not in the extent of fouling. The rate of accumulation of fouling reflected differences among the coatings in adhesion of the tubeworm Hydroides elegans. The surface properties of these coatings may have affected the rate of fouling and the structure of the fouling community through their influence on larval settlement and subsequent interactions with other residents, predators, and the physical environment.

  1. Membrane fouling mechanism transition in relation to feed water composition

    KAUST Repository

    Myat, Darli Theint

    2014-12-01

    The impact of secondary effluent wastewater from the Eastern Treatment Plant (ETP), Melbourne, Australia, before and after ion exchange (IX) treatment and polyaluminium chlorohydrate (PACl) coagulation, on hydrophobic polypropylene (PP) and hydrophilic polyvinylidene fluoride (PVDF) membrane fouling was studied. Laboratory fouling tests were operated over 3-5 days with regular, intermittent backwash. During the filtration with PP membranes, organic rejection data indicated that humic adsorption on hydrophobic PP membrane occurred during the first 24h of filtration and contributed to fouling for both raw wastewater and pre-treated wastewaters. However, after the first 24h of filtration the contribution of humic substances to fouling diminished and biopolymers that contribute to cake layer development became more prominent in their contribution to the fouling rate. For PVDF membranes, the per cent removal of humic substances from both raw wastewater and pre-treated wastewaters was very small as indicated by no change in UV254 from the feed to the permeate over the filtration period, even during the early stages of filtration. This suggested that the hydrophobic PP membrane adsorbed humic substances while the hydrophilic PVDF membrane did not. The highest mass of biopolymer removal by each PVDF membrane was from ETP water followed by PACl and IX treated water respectively. This was possibly due to differences in the backwashing efficiency linked to the filter cake contributed by biopolymers. Hydraulic backwashing was more effective during the later stages of filtration for the ETP water compared to IX and PACl treated waters, indicating that the filter cake contributed by ETP biopolymers was more extensively removed by hydraulic backwashing. It was proposed that humic substances may act to stabilise biopolymers in solution and that removing humics substances by coagulation or IX results in greater adhesive forces between the biopolymers and membrane/filter cake

  2. Application of GPRS and GIS in Boiler Remote Monitoring System

    Directory of Open Access Journals (Sweden)

    Hongchao Wang

    2012-12-01

    Full Text Available Application of GPRS and GIS in boiler remote monitoring system was designed in this paper by combining the advantage of GPRS and GIS in remote data transmission with configuration monitoring technology. The detail information of the operating conditions of the industrial boiler can be viewed by marking the location of boiler on the electronic map dynamically which can realize the unified management for industrial boiler of a region or city conveniently. Experimental application show that the system has convenience to use, high reliability, which play an active role to improve the operating efficiency, to prevent the boiler accident, and to decrease the energy consumption.

  3. Rejection of micropollutants by clean and fouled forward osmosis membrane.

    Science.gov (United States)

    Valladares Linares, Rodrigo; Yangali-Quintanilla, Victor; Li, Zhenyu; Amy, Gary

    2011-12-15

    As forward osmosis (FO) gains attention as an efficient technology to improve wastewater reclamation processes, it is fundamental to determine the influence of fouling in the rejection of emerging contaminants (micropollutants). This study focuses on the rejection of 13 selected micropollutants, spiked in a secondary wastewater effluent, by a FO membrane, using Red Sea water as draw solution (DS), differentiating the effects on the rejection caused by a clean and fouled membrane. The resulting effluent was then desalinated at low pressure with a reverse osmosis (RO) membrane, to produce a high quality permeate and determine the rejection with a coupled forward osmosis - low pressure reverse osmosis (FO-LPRO) system. When considering only FO with a clean membrane, the rejection of the hydrophilic neutral compounds was between 48.6% and 84.7%, for the hydrophobic neutrals the rejection ranged from 40.0% to 87.5%, and for the ionic compounds the rejections were between 92.9% and 96.5%. With a fouled membrane, the rejections were between 44.6% and 95.2%, 48.7%-91.5% and 96.9%-98.6%, respectively. These results suggest that, except for the hydrophilic neutral compounds, the rejection of the micropollutants is increased by the presence of a fouling layer, possibly due to the higher hydrophilicity of the FO fouled membrane compared to the clean one, the increased adsorption capacity of hydrophilic compounds and reduced mass transport capacity, membrane swelling, and the higher negative charge of the membrane surface, related to the foulants composition, mainly NOM acids (carboxylic radicals) and polysaccharides or polysaccharide-like substances. However, when coupled with RO, the rejections in both cases increased above 96%. The coupled FO-LPRO system was an effective double barrier against the selected micropollutants.

  4. Rejection of micropollutants by clean and fouled forward osmosis membrane

    KAUST Repository

    Valladares Linares, Rodrigo

    2011-12-01

    As forward osmosis (FO) gains attention as an efficient technology to improve wastewater reclamation processes, it is fundamental to determine the influence of fouling in the rejection of emerging contaminants (micropollutants). This study focuses on the rejection of 13 selected micropollutants, spiked in a secondary wastewater effluent, by a FO membrane, using Red Sea water as draw solution (DS), differentiating the effects on the rejection caused by a clean and fouled membrane. The resulting effluent was then desalinated at low pressure with a reverse osmosis (RO) membrane, to produce a high quality permeate and determine the rejection with a coupled forward osmosis - low pressure reverse osmosis (FO-LPRO) system. When considering only FO with a clean membrane, the rejection of the hydrophilic neutral compounds was between 48.6% and 84.7%, for the hydrophobic neutrals the rejection ranged from 40.0% to 87.5%, and for the ionic compounds the rejections were between 92.9% and 96.5%. With a fouled membrane, the rejections were between 44.6% and 95.2%, 48.7%-91.5% and 96.9%-98.6%, respectively. These results suggest that, except for the hydrophilic neutral compounds, the rejection of the micropollutants is increased by the presence of a fouling layer, possibly due to the higher hydrophilicity of the FO fouled membrane compared to the clean one, the increased adsorption capacity of hydrophilic compounds and reduced mass transport capacity, membrane swelling, and the higher negative charge of the membrane surface, related to the foulants composition, mainly NOM acids (carboxylic radicals) and polysaccharides or polysaccharide-like substances. However, when coupled with RO, the rejections in both cases increased above 96%. The coupled FO-LPRO system was an effective double barrier against the selected micropollutants. © 2011 Elsevier Ltd.

  5. Fouling control in seawater by on-line acid addition

    Energy Technology Data Exchange (ETDEWEB)

    Salvago, G.; Taccani, G.; Polimeni, R. [ITM-CNR, Milano (Italy); Fumagalli, G.; Picenoni, D. [CNR-CESPEL Politecnico di Milano (Italy)

    1996-11-01

    An experimental plant was set up containing once-through test lines supplied with seawater. The pH level of the seawater was maintained at 6.3 by the acids addition. Heat exchange monitoring equipment and channels exposing different metal specimens were installed on each of the lines. Observation by microscope and EDS analyses were carried out both on the specimen surfaces and on the cross section of the fouling after fracturing in liquid N{sub 2}. The results obtained show that: fouling must not be confused with its effects or simply with its biological components; acidifying seawater can prevent the resistance to heat exchange from increasing without impeding its biological activity. Observation by microscope of the fouling cross sections showed that in untreated seawater the foulings on stainless steel were composed of a continuous compact layer, covered by disorderly clusters. These compact layers were found to contain high quantities of corrosion products of the metals. Elements typical of corrosion products of ferrous materials (Fe, Mn) were also found on Pt, copper alloys and plastic materials. The addition of HCl or H{sub 2}SO{sub 4} to the seawater, to bring it to pH 6.3, reduces the amount of fouling adhering to the surfaces, prevents the development of the continuous layer containing iron and prevents significant increases in heat exchange resistance. The addition of CO{sub 2} can encourage the development of incoherent fibrous material with high Si content and low Fe content which is of little impediment to heat exchange. The addition of lactic acid can encourage both the abnormal development of biomass and the formation of several, separate, layers on stainless steel surfaces.

  6. Nanoparticle fouling and its combination with organic fouling during forward osmosis process for silver nanoparticles removal from simulated wastewater

    Science.gov (United States)

    Zhao, Yanxiao; Wang, Xinhua; Wang, Zhiwei; Li, Xiufen; Ren, Yueping

    2016-05-01

    The increasing and wide application of silver nanoparticles (Ag NPs) has resulted in their appearance in wastewater. In consideration of their potential toxicity and environmental impacts, it is necessary to find effective technology for their removal from wastewater. Here, forward osmosis (FO) membrane was applied for Ag NPs removal from wastewater, and single and combined fouling of nanoparticles and organic macromolecules were further investigated during the FO process. The findings demonstrated that FO membrane can effectively remove Ag NPs from wastewater due to its high rejection performance. Fouling tests indicated that water flux declined appreciably even at the beginning of the single Ag NPs fouling test, and more remarkable flux decline and larger amounts of deposited Ag NPs were observed with an increase of Ag NPs concentration. However, the addition of bovine serum albumin (BSA) could effectively alleviate the FO membrane fouling induced by Ag NPs. The interaction between Ag NPs and BSA was responsible for this phenomenon. BSA can easily form a nanoparticle-protein corona surrounded nanoparticles, which prevented nanoparticles from aggregation due to the steric stabilization mechanism. Furthermore, the interaction between BSA and Ag NPs occurred not only in wastewater but also on FO membrane surface.

  7. Foul Play in Sport as a Phenomenon Inconsistent with the Rules, yet Acceptable and Desirable: Ethical Conditions

    Directory of Open Access Journals (Sweden)

    Kosiewicz Jerzy

    2014-06-01

    Full Text Available The article has strictly a theoretical and non-empirical character. The author presents examples resulting from various observations. The aim of the paper is to present the causes, functions, and results of fouls, fouling, and foul play. Although fouls do not comply with the rules of games, the paper demonstrates that fouls are often used; they enjoy a quiet acceptance of the sporting world; they are tolerated and accepted; even more, they are often - more or less explicitly - desirable.

  8. Characteristics and sources of intermediate size particles in recovery boilers : final project report.

    Energy Technology Data Exchange (ETDEWEB)

    Baxter, Larry L. (Brigham Young University, Provo, UT); Shaddix, Christopher R.; Verrill, Christopher L. (Georgia Institute of Technology, Institute of Paper Science and Technology, Atlanta, GA); Wessel, Richard A. (Babcock & Wilcox Company, Barberton, OH)

    2005-02-01

    As part of the U.S. Department of Energy (DOE) Office of Industrial Technologies (OIT) Industries of the Future (IOF) Forest Products research program, a collaborative investigation was conducted on the sources, characteristics, and deposition of particles intermediate in size between submicron fume and carryover in recovery boilers. Laboratory experiments on suspended-drop combustion of black liquor and on black liquor char bed combustion demonstrated that both processes generate intermediate size particles (ISP), amounting to 0.5-2% of the black liquor dry solids mass (BLS). Measurements in two U.S. recovery boilers show variable loadings of ISP in the upper furnace, typically between 0.6-3 g/Nm{sup 3}, or 0.3-1.5% of BLS. The measurements show that the ISP mass size distribution increases with size from 5-100 {micro}m, implying that a substantial amount of ISP inertially deposits on steam tubes. ISP particles are depleted in potassium, chlorine, and sulfur relative to the fuel composition. Comprehensive boiler modeling demonstrates that ISP concentrations are substantially overpredicted when using a previously developed algorithm for ISP generation. Equilibrium calculations suggest that alkali carbonate decomposition occurs at intermediate heights in the furnace and may lead to partial destruction of ISP particles formed lower in the furnace. ISP deposition is predicted to occur in the superheater sections, at temperatures greater than 750 C, when the particles are at least partially molten.

  9. Feeding tube - infants

    Science.gov (United States)

    ... this page: //medlineplus.gov/ency/article/007235.htm Feeding tube - infants To use the sharing features on this page, please enable JavaScript. A feeding tube is a small, soft, plastic tube placed ...

  10. Selecting Actuator Configuration for a Benson Boiler

    DEFF Research Database (Denmark)

    Kragelund, Martin Nygaard; Leth, John-Josef; Wisniewski, Rafal

    2009-01-01

    with particular focus on a boiler in a power plant operated by DONG Energy - a Danish energy supplier. The problem has been reformulated using mathematic notions from economics. The selection of actuator configuration has been limited to the fuel system which in the considered plant consists of three different...

  11. Environmental control during steam boiler washing

    Energy Technology Data Exchange (ETDEWEB)

    Guimaraes, Marcio A.B.; Abreu Pereira, Vera L. de [Companhia Petroquimica do Nordeste (COPENE), Camacari, BA (Brazil). Div. de Engenharia Ambiental; Ringler, Ulrich E.S. [PROMON Engenharia Ltda., Salvador, BA (Brazil)

    1993-12-31

    The washing and chemical cleaning of boilers, activities of a high polluting potential, are responsible for the generation of wastewater of high contents of heavy metals, suspended solids and chemical oxygen demand (COD). This paper describes the actions carried out by COPENE - Petroquimica do Nordeste S/A - in order to reduce this problem. (author). 10 refs., 3 figs., 2 tabs.

  12. Debugging and Rectification of Electric Heating Boilers

    Institute of Scientific and Technical Information of China (English)

    GE; Cheng-song

    2015-01-01

    Steam system of CRARL mainly provides steam for dissolving system,and steam was transported through pipes.The major equipment is a150kW steam electric heating boiler(FH-JZ-003),with rated evaporation 0.2T/h and rated pressure 1.0MPa.It was found during debugging

  13. Is That Boiler Ready To Blow?

    Science.gov (United States)

    Robinson, Glenn S.; Trombley, Robert E.

    2001-01-01

    Discusses implementation of a thorough assessment program to determine the condition of boilers, pressure vessels and other plant equipment to determine the feasibility of part or entire system replacement. Assessment basics are examined as are tips for selecting the right inspection and engineering contractor for assessments. (GR)

  14. Qualification of stainless steel for OTEC heat exchanger tubes

    Energy Technology Data Exchange (ETDEWEB)

    LaQue, F.L.

    1979-01-01

    The history of the AL-6X alloy is reviewed and its credentials as a candidate for use as tubing in Ocean Thermal Energy Conversion Heat Exchangers are examined. Qualification is based on results of accelerated tests using ferric chloride for resistance to crevice corrosion and pitting, long-time crevice corrosion and pitting tests in natural sea water and anticipated resistance to attack by ammonia and mixtures of ammonia and sea water. Since the alloy has no natural resistance to fouling by marine organisms, it must be able to accomodate action to prevent fouling by chlorination or to remove it by mechanical cleaning techniques or appropriate chemical cleaning methods. The satisfactory behavior indicated by the various accelerated and long-time corrosion tests has been confirmed by excellent performance of several million feet of tubing in condensers in coastal power plants. Early evaluation tests demonstrated the need for proper heat treatment to avoid the presence of a sigma phase, which promoted severe pitting of some, but not all, specimens in tests in natural sea water. The available data qualify the AL-6X alloy as being a satisfactory alternate to titanium for tubes in OTEC heat exchangers.

  15. Reliability analysis on a shell and tube heat exchanger

    Science.gov (United States)

    Lingeswara, S.; Omar, R.; Mohd Ghazi, T. I.

    2016-06-01

    A shell and tube heat exchanger reliability was done in this study using past history data from a carbon black manufacturing plant. The heat exchanger reliability study is vital in all related industries as inappropriate maintenance and operation of the heat exchanger will lead to major Process Safety Events (PSE) and loss of production. The overall heat exchanger coefficient/effectiveness (Uo) and Mean Time between Failures (MTBF) were analyzed and calculated. The Aspen and down time data was taken from a typical carbon black shell and tube heat exchanger manufacturing plant. As a result of the Uo calculated and analyzed, it was observed that the Uo declined over a period caused by severe fouling and heat exchanger limitation. This limitation also requires further burn out period which leads to loss of production. The MTBF calculated is 649.35 hours which is very low compared to the standard 6000 hours for the good operation of shell and tube heat exchanger. The guidelines on heat exchanger repair, preventive and predictive maintenance was identified and highlighted for better heat exchanger inspection and repair in the future. The fouling of heat exchanger and the production loss will be continuous if proper heat exchanger operation and repair using standard operating procedure is not followed.

  16. Convective Heat and Mass Transfer in Water at Super—Critical Pressures under Heating or Cooling Conditions in Vertical Tubes

    Institute of Scientific and Technical Information of China (English)

    Pei-XueJiang; Ze-PeiRen; 等

    1995-01-01

    Forced and mixed convection heat and mass transfer are studied numerically for water containing metallic corrosion products in a heated or cooled vertical tube with variable thermophysical properties at super-citical pressures.the fouling mechanisms and fouling models are presented.The influence of variable properties at super-critical pressures on forced or mixed convection has been analyzed.The differences between heat and mass transfer under heating and cooling conditions are discussed.It is found that variable properties,especially buoyancy,greatly influence the fluid flow and heat mass fransfer.

  17. Experimental Study on Heat Transfer Characteristics of Shell and Tube Heat Exchanger Using Hitran Wire Matrix Turbulators As Tube Inserts.

    Directory of Open Access Journals (Sweden)

    Manoj

    2014-06-01

    Full Text Available Shell and tube heat exchangers are extensively used in boilers, oil coolers, pre-heaters, condensers etc. They are also having special importance in process application as well as refrigeration and air conditioning industries. The present paper emphasizes on heat transfer characteristics of shell and tube heat exchangers with the aid of hiTRAN wire matrix inserts is been studied. Investigations were made on effect of mass flow rate of water on heat transfer characteristics in case of plain tube without inserts. When hiTRAN wire matrix tube inserts are used, which effectively increases the turbulence of tube side flow due to the hydrodynamic and thermal agitation of boundary layer in turns increases additional pressure drop is available in the system. This results in increase in the wall shear, reduced wall temperature which enhances substantial increase in tube side heat transfer characteristics. Heat and cooling processes streams is a standard operation in many industries this operation is often performed in heat exchangers where the heated or cold fluid flows under laminar conditions inside the tubes the mechanisms of under those flow conditions are complex poorly understood since they can involve both forced and natural convection making accurate prediction for heat exchanger. Heat transfer in laminar flow regimes is low by default but can be greatly increased by the use of passive heat transfer enhancement such as tube inserts. The present analysis the hiTRAN wire matrix turbulators were used and increased heat transfer characteristics as expected outcomes.

  18. Analysis of b-lactoglobulin and ovalbumin fouling on a tube heated surface.

    OpenAIRE

    Daniela Helena Pelegrine Guimarães

    2003-01-01

    Resumo: Este é um trabalho sobre a incrustação de proteínas de origem animal, b-lactoglobulina e ovoalbumina, sobre superfícies cilíndricas aquecidas, comuns nos equipamentos de tratamento térmico e de concentração por evaporação. A incrustação é um fenômeno de transferência de massa que é uma função da solubilidade dessas proteínas. Para descrever a cinética da incrustação foi desenvolvido um algoritmo de cálculo que teve como subsídio a solubilidade das proteínas. A solubilidade foi determi...

  19. Computation Modeling and Assessment of Nanocoatings for Ultra Supercritical Boilers

    Energy Technology Data Exchange (ETDEWEB)

    J. Shingledecker; D. Gandy; N. Cheruvu; R. Wei; K. Chan

    2011-06-21

    Forced outages and boiler unavailability of coal-fired fossil plants is most often caused by fire-side corrosion of boiler waterwalls and tubing. Reliable coatings are required for Ultrasupercritical (USC) application to mitigate corrosion since these boilers will operate at a much higher temperatures and pressures than in supercritical (565 C {at} 24 MPa) boilers. Computational modeling efforts have been undertaken to design and assess potential Fe-Cr-Ni-Al systems to produce stable nanocrystalline coatings that form a protective, continuous scale of either Al{sub 2}O{sub 3} or Cr{sub 2}O{sub 3}. The computational modeling results identified a new series of Fe-25Cr-40Ni with or without 10 wt.% Al nanocrystalline coatings that maintain long-term stability by forming a diffusion barrier layer at the coating/substrate interface. The computational modeling predictions of microstructure, formation of continuous Al{sub 2}O{sub 3} scale, inward Al diffusion, grain growth, and sintering behavior were validated with experimental results. Advanced coatings, such as MCrAl (where M is Fe, Ni, or Co) nanocrystalline coatings, have been processed using different magnetron sputtering deposition techniques. Several coating trials were performed and among the processing methods evaluated, the DC pulsed magnetron sputtering technique produced the best quality coating with a minimum number of shallow defects and the results of multiple deposition trials showed that the process is repeatable. scale, inward Al diffusion, grain growth, and sintering behavior were validated with experimental results. The cyclic oxidation test results revealed that the nanocrystalline coatings offer better oxidation resistance, in terms of weight loss, localized oxidation, and formation of mixed oxides in the Al{sub 2}O{sub 3} scale, than widely used MCrAlY coatings. However, the ultra-fine grain structure in these coatings, consistent with the computational model predictions, resulted in accelerated Al

  20. Impact of effluent organic matter on low-pressure membrane fouling in tertiary treatment

    KAUST Repository

    Ayache, C.

    2013-05-01

    This study aims at comparing low-pressure membrane fouling obtained with two different secondary effluents at bench and pilot-scale based on the determination of two fouling indices: the total fouling index (TFI) and the hydraulically irreversible fouling index (HIFI). The main objective was to investigate if simpler and less costly bench-scale experimentation can substitute for pilot-scale trials when assessing the fouling potential of secondary effluent in large scale membrane filtration plants producing recycled water. Absolute values for specific flux and total fouling index for the bench-scale system were higher than those determined from pilot-scale, nevertheless a statistically significant correlation (r2 = 0.63, α = 0.1) was obtained for the total fouling index at both scales. On the contrary no such correlation was found for the hydraulically irreversible fouling index. Advanced water characterization tools such as excitation-emission matrix fluorescence spectroscopy (EEM) and liquid chromatography with organic carbon detection (LC-OCD) were used for the characterization of foulants. On the basis of statistical analysis, biopolymers and humic substances were found to be the major contribution to total fouling (r2 = 0.95 and r2 = 0.88, respectively). Adsorption of the low molecular weight neutral compounds to the membrane was attributed to hydraulically irreversible fouling (r2 = 0.67). © 2013 Elsevier Ltd.

  1. Robust design optimization method for centrifugal impellers under surface roughness uncertainties due to blade fouling

    Science.gov (United States)

    Ju, Yaping; Zhang, Chuhua

    2016-03-01

    Blade fouling has been proved to be a great threat to compressor performance in operating stage. The current researches on fouling-induced performance degradations of centrifugal compressors are based mainly on simplified roughness models without taking into account the realistic factors such as spatial non-uniformity and randomness of the fouling-induced surface roughness. Moreover, little attention has been paid to the robust design optimization of centrifugal compressor impellers with considerations of blade fouling. In this paper, a multi-objective robust design optimization method is developed for centrifugal impellers under surface roughness uncertainties due to blade fouling. A three-dimensional surface roughness map is proposed to describe the nonuniformity and randomness of realistic fouling accumulations on blades. To lower computational cost in robust design optimization, the support vector regression (SVR) metamodel is combined with the Monte Carlo simulation (MCS) method to conduct the uncertainty analysis of fouled impeller performance. The analyzed results show that the critical fouled region associated with impeller performance degradations lies at the leading edge of blade tip. The SVR metamodel has been proved to be an efficient and accurate means in the detection of impeller performance variations caused by roughness uncertainties. After design optimization, the robust optimal design is found to be more efficient and less sensitive to fouling uncertainties while maintaining good impeller performance in the clean condition. This research proposes a systematic design optimization method for centrifugal compressors with considerations of blade fouling, providing a practical guidance to the design of advanced centrifugal compressors.

  2. Biomimetic characterisation of key surface parameters for the development of fouling resistant materials.

    Science.gov (United States)

    Scardino, A J; Hudleston, D; Peng, Z; Paul, N A; de Nys, R

    2009-01-01

    Material science provides a direct route to developing a new generation of non-toxic, surface effect-based antifouling technologies with applications ranging from biomedical science to marine transport. The surface topography of materials directly affects fouling resistance and fouling removal, the two key mechanisms for antifouling technologies. However, the field is hindered by the lack of quantified surface characteristics to guide the development of new antifouling materials. Using a biomimetic approach, key surface parameters are defined and quantified and correlated with fouling resistance and fouling removal from the shells of marine molluscs. Laser scanning confocal microscopy was used to acquire images for quantitative surface characterisation using three-dimensional surface parameters, and field assays correlated these with fouling resistance and fouling release. Principle component analysis produced a major component (explaining 54% of total variation between shell surfaces) that correlated with fouling resistance. The five surface parameters positively correlated to increased fouling resistance were, in order of importance, low fractal dimension, high skewness of both the roughness and waviness profiles, higher values of isotropy and lower values of mean surface roughness. The second component (accounting for 20% of variation between shells) positively correlated to fouling release, for which higher values of mean waviness almost exclusively dictated this relationship. This study provides quantified surface parameters to guide the development of new materials with surface properties that confer fouling resistance and release.

  3. [Fouling behavior of sodium alginate during microfiltration at various ionic compositions: XDLVO approach].

    Science.gov (United States)

    Zhao, Ying-Xu; Zong, Rui-Qiang; Gao, Xin-Yu; Xie, Hui-Jun; Yin, Yong-Quan; Liang, Shuang

    2014-04-01

    The extended Derjaguin-Laudau-Verwey-Overbeek (XDLVO) theory was utilized to quantitatively evaluate short-range interfacial interactions involved in microfiltration (MF) membrane fouling by sodium alginate (SA) at various ionic compositions. Results showed that for hydrophilic membrane surfaces, van der Waals interactions facilitated fouling, whereas acid-base interactions alleviated fouling; for hydrophobic membrane surfaces, however, van der Waals interactions mitigated fouling and acid-base interactions turned out to be favorable for fouling. Electrostatic double layer interactions contributed minimally to fouling when SA molecules came into contact with MF membrane surface. Ionic strength and Ca2+ affected SA fouling of MF membranes mainly through alteration of acid-base interactions between membrane and SA or among SA themselves. Higher ionic strength could make acid-base interaction less repulsive or more attractive, thus aggravating SA fouling of MF membrane. Although Ca2+ accelerated flux decline significantly, Ca2+ could enhance physical cleaning efficiencies. Under all tested ionic compositions, fouling potentials (K) of initial and subsequent stages correlated well with membrane-SA interfacial free energy of adhesion and SA-SA interfacial free energy of cohesion, respectively. This implies that the XDLVO theory is applicable for description of MF membrane fouling by SA at various ionic compositions.

  4. Membrane fouling in pilot-scale membrane bioreactors (MBRs) treating municipal wastewater.

    Science.gov (United States)

    Kimura, Katsuki; Yamato, Nobuhiro; Yamamura, Hiroshi; Watanabe, Yoshimasa

    2005-08-15

    The main obstacle for wider use of membrane bioreactors (MBRs) for wastewater treatment is membrane fouling (i.e., deterioration of membrane permeability),which increases operating costs. For more efficient control of membrane fouling in MBRs, an understanding of the mechanisms of membrane fouling is important. However, there is a lack of information on membrane fouling in MBRs, especially information on features of components that are responsible for the fouling. We conducted a pilot-scale experiment using real municipal wastewater with three identical MBRs under different operating conditions. The results obtained in this study suggested that the food-microorganisms ratio (F/M) and membrane filtration flux were the important operating parameters that significantly influenced membrane fouling in MBRs. Neither concentrations of dissolved organic matter in the reactors nor viscosity of mixed liquor, which have been thought to have influences on fouling in MBRs, showed clear relationships with membrane fouling in this study. Organic substances that had caused the membrane fouling were desorbed from fouled membranes of the MBRs at the termination of the operation and were subjected to Fourier transform infrared (FTIR) and 13C nuclear magnetic resonance (NMR) analyses. These analyses revealed that the nature of the membrane foulant changes depending on F/M. It was shown that high F/M would make the foulant more proteinaceous. Carbohydrates were dominant in membrane foulants in this study, while features of humic substances were not apparent.

  5. Robust Design Optimization Method for Centrifugal Impellers under Surface Roughness Uncertainties Due to Blade Fouling

    Institute of Scientific and Technical Information of China (English)

    JU Yaping; ZHANG Chuhua

    2016-01-01

    Blade fouling has been proved to be a great threat to compressor performance in operating stage. The current researches on fouling-induced performance degradations of centrifugal compressors are based mainly on simplified roughness models without taking into account the realistic factors such as spatial non-uniformity and randomness of the fouling-induced surface roughness. Moreover, little attention has been paid to the robust design optimization of centrifugal compressor impellers with considerations of blade fouling. In this paper, a multi-objective robust design optimization method is developed for centrifugal impellers under surface roughness uncertainties due to blade fouling. A three-dimensional surface roughness map is proposed to describe the nonuniformity and randomness of realistic fouling accumulations on blades. To lower computational cost in robust design optimization, the support vector regression (SVR) metamodel is combined with the Monte Carlo simulation (MCS) method to conduct the uncertainty analysis of fouled impeller performance. The analyzed results show that the critical fouled region associated with impeller performance degradations lies at the leading edge of blade tip. The SVR metamodel has been proved to be an efficient and accurate means in the detection of impeller performance variations caused by roughness uncertainties. After design optimization, the robust optimal design is found to be more efficient and less sensitive to fouling uncertainties while maintaining good impeller performance in the clean condition. This research proposes a systematic design optimization method for centrifugal compressors with considerations of blade fouling, providing a practical guidance to the design of advanced centrifugal compressors.

  6. Heat mass transfer model of fouling process of calcium carbonate on heat transfer surface

    Institute of Scientific and Technical Information of China (English)

    QUAN ZhenHua; CHEN YongChang; MA ChongFang

    2008-01-01

    A new heat mass transfer model was developed to predict the fouling process of calcium carbonate on heat transfer surface.The model took into account not only the crystallization fouling but also the particle fouling which was formed on the heat transfer surface by the suspension particles of calcium carbonate in the su-persaturated solution.Based on experimental results of the fouling process,the deposition and removal rates of the mixing fouling were expressed.Furthermore,the coupling effect of temperature with the fouling process was considered in the physics model.As a result the fouling resistance varying with time was obtained to describe the fouling process and the prediction was compared with experimental data under same conditions.The results showed that the present model could give a good prediction of fouling process,and the deviation was less than 15% of the experimental data in most cases.The new model is credible to predict the fouling process.

  7. NOx EMISSIONS PRODUCED WITH COMBUSTION OF POWDER RIVER BASIN COAL IN A UTILITY BOILER

    Energy Technology Data Exchange (ETDEWEB)

    John S. Nordin; Norman W. Merriam

    1997-04-01

    The objective of this report is to estimate the NOx emissions produced when Powder River Basin (PRB) coal is combusted in a utility boiler. The Clean Air Act regulations specify NOx limits of 0.45 lb/mm Btu (Phase I) and 0.40 lb/mm Btu (Phase II) for tangentially fired boilers, and 0.50 lb/mm 13tu (Phase II) and 0.46 lb/mm Btu (Phase II) for dry-bottom wall-fired boilers. The Clean Air Act regulations also specify other limits for other boiler types. Compliance for Phase I has been in effect since January 1, 1996. Compliance for Phase II goes into effect on January 1, 2000. Emission limits are expressed as equivalent NO{sub 2} even though NO (and sometimes N{sub 2}O) is the NOx species emitted during combustion. Regulatory agencies usually set even lower NOx emission limits in ozone nonattainment areas. In preparing this report, Western Research Institute (WRI) used published test results from utilities burning various coals, including PRB coal, using state-of-the art control technology for minimizing NOx emissions. Many utilities can meet Clean Air Act NOx emission limits using a combination of tight combustion control and low-NOx burners and by keeping furnaces clean (i.e., no slag buildup). In meeting these limits, some utilities also report problems such as increased carbon in their fly ash and excessive furnace tube corrosion. This report discusses utility experience. The theory of NOx emission formation during coal combustion as related to coal structure and how the coal is combusted is also discussed. From this understanding, projections are made for NOx emissions when processed PRB coal is combusted in a test similar to that done with other coals. As will be shown, there are a lot of conditions for achieving low NOx emissions, such as tight combustion control and frequent waterlancing of the furnace to avoid buildup of deposits.

  8. Contribution of effluent organic matter (EfOM) to ultrafiltration (UF) membrane fouling: Isolation, characterization, and fouling effect of EfOM fractions

    KAUST Repository

    Zheng, Xing

    2014-11-01

    EfOM has been regarded as a major organic foulant resulting in UF membrane fouling in wastewater reclamation. To investigate fouling potential of different EfOM fractions, the present study isolated EfOM into hydrophobic neutrals (HPO-N), colloids, hydrophobic acids (HPO-A), transphilic neutrals and acids (TPI), and hydrophilics (HPI), and tested their fouling effect in both salt solution and pure water during ultrafiltration (UF). Major functional groups and chemical structure of the isolates were identified using Fourier transform infrared spectroscopy (FT-IR) and solid-state carbon nuclear magnetic resonance (13C NMR) analysis. The influence of the isolation process on the properties of EfOM fractions was minor because the raw and reconstituted secondary effluents were found similar with respect to UV absorbance, molecular size distribution, and fluorescence character. In membrane filtration tests, unified membrane fouling index (UMFI) and hydraulic resistance were used to quantify irreversible fouling potential of different water samples. Results show that under similar DOC level in feed water, colloids present much more irreversible fouling than other fractions. The fouling effect of the isolates is related to their size, chemical properties, and solution chemistry. Further investigations have identified that the interaction between colloids and other fractions also influences the performance of colloids in fouling phenomena. © 2014 Elsevier Ltd.

  9. Guide to Low-Emission Boiler and Combustion Equipment Selection

    Energy Technology Data Exchange (ETDEWEB)

    Oland, CB

    2002-05-06

    Boiler owners and operators who need additional generating capacity face a number of legal, political, environmental, economic, and technical challenges. Their key to success requires selection of an adequately sized low-emission boiler and combustion equipment that can be operated in compliance with emission standards established by state and federal regulatory agencies. Recognizing that many issues are involved in making informed selection decisions, the U.S. Department of Energy (DOE), Office of Industrial Technologies (OIT) sponsored efforts at the Oak Ridge National Laboratory (ORNL) to develop a guide for use in choosing low-emission boilers and combustion equipment. To ensure that the guide covers a broad range of technical and regulatory issues of particular interest to the commercial boiler industry, the guide was developed in cooperation with the American Boiler Manufacturers Association (ABMA), the Council of Industrial Boiler Owners (CIBO), and the U.S. Environmental Protection Agency (EPA). The guide presents topics pertaining to industrial, commercial, and institutional (ICI) boilers. Background information about various types of commercially available boilers is provided along with discussions about the fuels that they burn and the emissions that they produce. Also included are discussions about emissions standards and compliance issues, technical details related to emissions control techniques, and other important selection considerations. Although information in the guide is primarily applicable to new ICI boilers, it may also apply to existing boiler installations.

  10. Characteristics of heat transfer fouling of thin stillage using model thin stillage and evaporator concentrates

    Science.gov (United States)

    Challa, Ravi Kumar

    The US fuel ethanol demand was 50.3 billion liters (13.3 billion gallons) in 2012. Corn ethanol was produced primarily by dry grind process. Heat transfer equipment fouling occurs during corn ethanol production and increases the operating expenses of ethanol plants. Following ethanol distillation, unfermentables are centrifuged to separate solids as wet grains and liquid fraction as thin stillage. Evaporator fouling occurs during thin stillage concentration to syrup and decreases evaporator performance. Evaporators need to be shutdown to clean the deposits from the evaporator surfaces. Scheduled and unscheduled evaporator shutdowns decrease process throughput and results in production losses. This research were aimed at investigating thin stillage fouling characteristics using an annular probe at conditions similar to an evaporator in a corn ethanol production plant. Fouling characteristics of commercial thin stillage and model thin stillage were studied as a function of bulk fluid temperature and heat transfer surface temperature. Experiments were conducted by circulating thin stillage or carbohydrate mixtures in a loop through the test section which consisted of an annular fouling probe while maintaining a constant heat flux by electrical heating and fluid flow rate. The change in fouling resistance with time was measured. Fouling curves obtained for thin stillage and concentrated thin stillage were linear with time but no induction periods were observed. Fouling rates for concentrated thin stillage were higher compared to commercial thin stillage due to the increase in solid concentration. Fouling rates for oil skimmed and unskimmed concentrated thin stillage were similar but lower than concentrated thin stillage at 10% solids concentration. Addition of post fermentation corn oil to commercial thin stillage at 0.5% increments increased the fouling rates up to 1% concentration but decreased at 1.5%. As thin stillage is composed of carbohydrates, protein, lipid

  11. Erosion-corrosion of as-plasma-sprayed and laser-remelted NiCrAlY bond coats in working conditions of a coal-fired boiler

    Energy Technology Data Exchange (ETDEWEB)

    Sidhu, B.S.; Prakash, S. [College of Engineering & Technology, Bathinda (India). Dept. of Mechanical Engineering

    2008-01-15

    Ni-22Cr-10Al-1Y plasma spray coating has been formulated on boiler tube steels. namely, low-carbon steel ASTM SA210-Grade A1. 1Cr-0.5Mo steel ASTM SA213-T-11, and 2.25Cr-1Mo steel ASTM SA213-T-22. The coated steels also have been laser-remelted using a Nd:YAG laser. The degradation behavior of as-sprayed and laser-remelted coatings have been evaluated in actual conditions in a coal-fired boiler for 1,000 h at 755{sup o}C. The laser remelting has been found to be effective to increase the degradation resistance of plasma-sprayed boiler steels. ASTM SA213-T-22-coated and laser-remelted steel has proved to be most effective in resistance to degrading species.

  12. Evaluation of hot corrosion behaviour of HVOF sprayed Ni-5Al and NiCrAl coatings in coal fired boiler environment

    Energy Technology Data Exchange (ETDEWEB)

    Mahesh, R.A.; Jayaganthan, R.; Prakash, S. [VA Tech EWF Pvt Ltd., Prithla (India)

    2010-08-15

    Hot corrosion was recognised as a serious problem in connection with the degradation of fireside boiler tubes in coal fired steam generating plants. It is one of the most deleterious forms of surface degradation which can lead to the loss of mechanical strength and catastrophic failure of structural and engineering components. In the present investigation, an attempt has been made to evaluate the hot corrosion behaviour of high velocity oxyfuel (HVOF) sprayed Ni-5Al and NiCrAl coatings on iron based superalloy in an actual coal fired boiler environment. The coated specimens were hung in the low temperature superheater zone (about 700{sup o}C) of a coal fired boiler. The studies were carried out for 10 cycles each cycle consisting of exposing the coated specimens for 100 h followed by 1 h cooling to ambient conditions. NiCrAl coated specimen provided better resistance to hot corrosion than Ni-5Al coated specimen in the given environment.

  13. Physical and Numerical Analysis of Extrusion Process for Production of Bimetallic Tubes

    Energy Technology Data Exchange (ETDEWEB)

    Misiolek, W.Z.; Sikka, V.K.

    2006-08-10

    Bimetallic tubes are used for very specific applications where one of the two metals provides strength and the other provides specific properties such as aqueous corrosion and carburization, coking resistance, and special electrical and thermal properties. Bimetallic tubes have application in pulp and paper industry for heat-recovery boilers, in the chemical industry for ethylene production, and in the petrochemical industry for deep oil well explorations. Although bimetallic tubes have major applications in energy-intensive industry, they often are not used because of their cost and manufacturing sources in the United States. This project was intended to address both of these issues.

  14. Low Cost Polymer heat Exchangers for Condensing Boilers

    Energy Technology Data Exchange (ETDEWEB)

    Butcher, Thomas [Brookhaven National Lab. (BNL), Upton, NY (United States); Trojanowski, Rebecca [Brookhaven National Lab. (BNL), Upton, NY (United States); Wei, George [Brookhaven National Lab. (BNL), Upton, NY (United States); Worek, Michael [Brookhaven National Lab. (BNL), Upton, NY (United States)

    2015-09-30

    Work in this project sought to develop a suitable design for a low cost, corrosion resistant heat exchanger as part of a high efficiency condensing boiler. Based upon the design parameters and cost analysis several geometries and material options were explored. The project also quantified and demonstrated the durability of the selected polymer/filler composite under expected operating conditions. The core material idea included a polymer matrix with fillers for thermal conductivity improvement. While the work focused on conventional heating oil, this concept could also be applicable to natural gas, low sulfur heating oil, and biodiesel- although these are considered to be less challenging environments. An extruded polymer composite heat exchanger was designed, built, and tested during this project, demonstrating technical feasibility of this corrosion-resistant material approach. In such flue gas-to-air heat exchangers, the controlling resistance to heat transfer is in the gas-side convective layer and not in the tube material. For this reason, the lower thermal conductivity polymer composite heat exchanger can achieve overall heat transfer performance comparable to a metal heat exchanger. However, with the polymer composite, the surface temperature on the gas side will be higher, leading to a lower water vapor condensation rate.

  15. Worldwide genetic differentiation in the common fouling barnacle, Amphibalanus amphitrite

    KAUST Repository

    Chen, Hsi-Nien

    2014-10-21

    © 2014, © 2014 Taylor & Francis. Amphibalanus amphitrite is a common fouling barnacle distributed globally in tropical and subtropical waters. In the present study, the genetic (mitochondrial cytochrome oxidase subunit I) and morphological differentiation in A. amphitrite from 25 localities around the world were investigated. The results revealed three clades within A. amphitrite with a genetic divergence of ~ 4% among clades, whereas there were no diagnostic morphological differences among clades. Clade 1 is widely distributed in both temperate and tropical waters, whereas Clade 3 is currently restricted to the tropical region. The deep divergence among clades suggests historical isolation within A. amphitrite; thus, the present geographical overlaps are possibly a result of the combined effects of rising sea level and human-mediated dispersals. This study highlights the genetic differentiation that exists in a common, widely distributed fouling organism with great dispersal potential; future antifouling research should take into account the choice of lineages.

  16. A new concept for anti-fouling paint for Yachts

    DEFF Research Database (Denmark)

    Wallstroem, Eva; Jespersen, Henrik T.; Schaumburg, Kjeld

    2011-01-01

    -fouling products for yachts. To be able to reduce the amount of biocide, in this case zinc pyrithione, it is necessary to have control over the amount of biocide present in the surface layer. The control is achieved by encapsulating the biocide in a silica gel. The silica gel is dispersed together with pigments...... and fillers in the paint. The gel contributes to the polishing properties, where the gel particles are worn down throughout the polishing process. When a gel particle is opened by wear the biocide will be effective on the coating surface. It is also shown that zinc pyrithione is more efficient when...... it is encapsulated in a gel compared to a situation where it is not. This conclusion is based on the fact that the gel swells when exposed to water, and therefore the leach of zinc pyrithione is initially delayed and the biocide may start to solubilise and degrade. The result is an anti-fouling product...

  17. Characterization of a non-fouling ultrafiltration membrane

    DEFF Research Database (Denmark)

    Wei, J.; Helm, G.S.; Corner-Walker, N.

    2006-01-01

    -off (MWCO) were characterized by filtration studies using bovine serum albumin (BSA) and an enzyme solution as test media, and the membranes exhibited the non-fouling property. The surface chemistry of the unmodified and modified PVDF membranes was characterized by X-ray photoelectron spectroscopy (XPS...... surfaces was determined by the radio labeling technique. For the protein adsorption experiments, we have developed a method, which ensures that protein molecules only adsorb on the membrane surface, and that no adsorption on the pore walls of the porous sub-layer takes place.......This report describes the properties of surface-modified poly(vinylidene fluoride) (PVDF) membranes. These membranes were created by coating hydrophilic polymers on the support PVDF membrane to reduce the tendency to protein fouling. The modified membranes with different molecular weight cut...

  18. [Application of chemical ecology in controlling marine fouling organisms].

    Science.gov (United States)

    Fang, Fang; Yan, Tao; Liu, Qing

    2005-10-01

    Many marine organisms can produce secondary metabolites beneficial to the protection of marine environments against fouling, and thus, applying chemo-ecological methods to extract the natural antifoulants from marine organisms to resolve the problems relevant to marine fouling is a new thinking in resent years. Its aim is to search for high efficient and non-toxic antifoulants to replace the existing chemically synthetic ones which are unfortunately found to have widespread toxic effects on marine environment. Although we know few about the antifouling mechanisms of secondary metabolites, many natural products have been proved to have antifouling activity. Therefore, basic and applied researches on the ecological roles of these natural compounds, their action mechanisms, coating compatibility, controlled release, and field test are required in the future.

  19. Beer Clarification with polysulfone membrane and study on fouling mechanism

    Directory of Open Access Journals (Sweden)

    Ricardo Cardoso de Oliveira

    2011-12-01

    Full Text Available The aims of the present work were to study the relationship between the fluxes, permeate quality, and fouling mechanism. A polysulfone membrane with 100 KDa and 0.12 m² of surface area was used. Permeate fluxes were measured for different pressures (0.5, 1.0, 1.5, and 2.0 bar at the same temperature of 8 ºC. The fluxes measured for each pressure ranged from 22, 24, 27 and 30 kg h-1m-2 at 0.5, 1.0, 1.5 and 2.0 bar, respectively. Samples of the feed and permeate were analyzed for pH, color, turbidity, sugar, bitterness, and proteins. The fouling mechanisms observed were cake filtration, partial pore blocking, and complete pore blocking.

  20. Irreversible fouling during multicycle microfiltration of wastewater effluent.

    Science.gov (United States)

    Shan, Huifeng; Neufeld, Ronald D

    2007-12-01

    This study focused on irreversible fouling during microfiltration of primary and secondary effluents from municipal wastewater treatment plants. Flow resistances were calculated from the sum of clean membrane resistances, resultant cake layer resistances, and consequent irreversible fouling resistances. Results from a dead-end cell experimental system showed that the accumulated cake resistance was dominating for microfiltration of primary/secondary effluents. Suspended solids in the primary and secondary effluents had a similar compressibility index, n, with a value of approximately 0.5, indicating that they were moderately compressible particles. The value of irreversible resistance is dependent on the intensity of membrane cleaning; however, for a given membrane cleaning strategy, this value steadily increased and reached a maximum after approximately 6 cycles of filtration and cleaning. This study provided an explanation for the significant drop of throughput flux in the early application of membrane processes, and a plateau flux approached correspondingly.

  1. Membrane Fouling in Microfiltration used for Cell Harvesting

    Institute of Scientific and Technical Information of China (English)

    Tahereh Kaghazchi; Farzin Zokaee; Abbas Zare

    2001-01-01

    In the present study the membrane fouling in microfiltration used for cell harvesting in a deadend system has been investigated. Experimental results were analysed in terms of existing membrane filtration models and membrane resistances. The cake filtration model (CFM) and standard blocking model (SBM) have been considered in this study.Various membrane resistances were determined at different processing time, feed concentration and stirring speed. Resistances to permeation in this system include filter medium, pore blocking, adsorption, cake layer and concentration polarization.

  2. Membrane fouling in microfiltration used for cell harvesting

    Science.gov (United States)

    Kaghazchi, Tahereh; Zokaee, Farzin; Zare, Abbas

    2001-03-01

    In the present study the membrane fouling in microfiltration used for cell harvesting in a deadend system has been investigated. Experimental results were analysed in terms of existing membrane filtration models and membrane resistances. The cake filtration model (CFM) and standard blocking model (SBM) have been considered in this study. Various membrane resistances were determined at different processing time, feed concentration and stirring speed. Resistances to permeation in this system include filter medium, pore blocking, adsorption, cake layer and concentration polarization.

  3. Fouling-induced enzyme immobilization for membrane reactors

    DEFF Research Database (Denmark)

    Luo, Jianquan; Meyer, Anne S.; Jonsson, Gunnar Eigil

    2013-01-01

    , but the reverse mode allowed for higher enzyme loading and stability, and irreversible fouling (i.e. pore blocking) developed more readily in the support structure than in the skin layer. Compared with an enzymatic membrane reactor (EMR) with free enzymes, the novel EMR with enzymes immobilized in membrane...... support improved the enzyme reusability (especially for ADH), and reduced the product inhibition (especially for GDH). © 2013 Elsevier Ltd....

  4. Studies of the fate of sulfur trioxide in coal-fired utility boilers based on modified selected condensation methods.

    Science.gov (United States)

    Cao, Yan; Zhou, Hongcang; Jiang, Wu; Chen, Chien-Wei; Pan, Wei-Ping

    2010-05-01

    The formation of sulfur trioxide (SO(3)) in coal-fired utility boilers can have negative effects on boiler performance and operation, such as fouling and corrosion of equipment, efficiency loss in the air preheater (APH), increase in stack opacity, and the formation of PM(2.5). Sulfur trioxide can also compete with mercury when bonding with injected activated carbons. Tests in a lab-scale reactor confirmed there are major interferences between fly ash and SO(3) during SO(3) sampling. A modified SO(3) procedure to maximize the elimination of measurement biases, based on the inertial-filter-sampling and the selective-condensation-collecting of SO(3), was applied in SO(3) tests in three full-scale utility boilers. For the two units burning bituminous coal, SO(3) levels starting at 20 to 25 ppmv at the inlet to the selective catalytic reduction (SCR), increased slightly across the SCR, owing to catalytic conversion of SO(2) to SO(3,) and then declined in other air pollutant control device (APCD) modules downstream to approximately 5 ppmv and 15 ppmv at the two sites, respectively. In the unit burning sub-bituminous coal, the much lower initial concentration of SO(3) estimated to be approximately 1.5 ppmv at the inlet to the SCR was reduced to about 0.8 ppmv across the SCR and to about 0.3 ppmv at the exit of the wet flue gas desulfurization (WFGD). The SO(3) removal efficiency across the WFGD scrubbers at the three sites was generally 35% or less. Reductions in SO(3) across either the APH or the dry electrostatic precipitator (ESP) in units burning high-sulfur bituminous coal were attributed to operating temperatures being below the dew point of SO(3).

  5. Anti-fouling Coatings of Poly(dimethylsiloxane) Devices for Biological and Biomedical Applications.

    Science.gov (United States)

    Zhang, Hongbin; Chiao, Mu

    Fouling initiated by nonspecific protein adsorption is a great challenge in biomedical applications, including biosensors, bioanalytical devices, and implants. Poly(dimethylsiloxane) (PDMS), a popular material with many attractive properties for device fabrication in the biomedical field, suffers serious fouling problems from protein adsorption due to its hydrophobic nature, which limits the practical use of PDMS-based devices. Effort has been made to develop biocompatible materials for anti-fouling coatings of PDMS. In this review, typical nonfouling materials for PDMS coatings are introduced and the associated basic anti-fouling mechanisms, including the steric repulsion mechanism and the hydration layer mechanism, are described. Understanding the relationships between the characteristics of coating materials and the accompanying anti-fouling mechanisms is critical for preparing PDMS coatings with desirable anti-fouling properties.

  6. Microscopic approach for the identification of cationic membrane fouling during cheddar cheese whey electroacidification.

    Science.gov (United States)

    Lin Teng Shee, F; Angers, P; Bazinet, L

    2008-06-15

    This is the first time that fouling of cation-exchange membranes during cheddar cheese whey electroacidification with bipolar membranes is reported. A mineral fouling was observed only on the cationic membrane side in contact with the base. The deposit was identified as magnesium hydroxide and this fouling was more important on the cation-exchange membrane situated close to the cathode. Little deposit was formed after six electroacidification runs, but on long time, the buildup of fouling film would lead after many electroacidifications to an important decrease of the system efficiency. Since, fouling of permselective membranes represents one of the major issues in electrodialytic processes, this result will be the basis for the determination of cleaning conditions allowing the prevention of such a fouling.

  7. The role of EPS in fouling and foaming phenomena for a membrane bioreactor.

    Science.gov (United States)

    Cosenza, Alida; Di Bella, Gaetano; Mannina, Giorgio; Torregrossa, Michele

    2013-11-01

    In contraposition to conventional activated sludge processes, the foaming phenomenon in membrane bioreactor (MBR) is still in its infancy. On the other hand, although several studies have been carried out for better understanding the fouling phenomenon in MBR there are still some gaps in the up-to-date knowledge. The extracellular polymeric substances (EPSs) may have a primary role in fouling and foaming phenomena which in turn can be crucial for MBRs. The aim of this study is to detect a possible relationship that EPSs may have with fouling and foaming in an MBR for wastewater treatment. Foaming phenomenon is monitored by performing specific foam-tests: Foam Power, Scum Index, Foam Rating and filamentous abundance. Results show a high correlation between fouling vs EPS and foaming vs bound EPSs. A relationship between foaming and fouling was also found: in general, when foaming occurred the fouling rate decreases because the EPS bound remained trapped in the floating scum.

  8. Fouling Issues in Membrane Bioreactors (MBRs for Wastewater Treatment: Major Mechanisms, Prevention and Control Strategies

    Directory of Open Access Journals (Sweden)

    Petros K. Gkotsis

    2014-10-01

    Full Text Available Membrane fouling is one of the most important considerations in the design and operation of membrane systems as it affects pretreatment needs, cleaning requirements, operating conditions, cost and performance. Given that membrane fouling represents the main limitation to membrane process operation, it is unsurprising that the majority of membrane material and process research and development conducted is dedicated to its characterization and amelioration. This work presents the fundamentals of fouling issues in membrane separations, with specific regard to membrane fouling in Membrane Bioreactors (MBRs and the most frequently applied preventive-control strategies. Feed pretreatment, physical and chemical cleaning protocols, optimal operation of MBR process and membrane surface modification are presented and discussed in detail. Membrane fouling is the major obstacle to the widespread application of the MBR technology and, therefore, fouling preventive-control strategies is a hot issue that strongly concerns not only the scientific community, but industry as well.

  9. New biocide-free anti-fouling paints are toxic.

    Science.gov (United States)

    Karlsson, Jenny; Eklund, Britta

    2004-09-01

    A number of new anti-fouling paints claimed to be more friendly to the environment, have entered the market since prohibition of biocide containing paints have been enforced in many areas. Leakage waters from five new anti-fouling paints were tested for toxic effects to the macro algae Ceramium tenuicorne and Ceramium strictum and to the crustacean Nitocra spinipes. A banned copper and irgarol 1051 containing anti-fouling paint was used as reference. Five of the six paints tested were toxic to all or some of the organisms after two weeks of leakage with EC50 ranging from 0.08 to around 2% leakage water and LC50 ranging from 1.1% to 88%. The toxicity of leakage water from these paints was still high after 16 weeks. We conclude that these paints contain substances toxic to common organisms in the coastal Baltic ecosystem. A silicone based paint did not exhibit toxic effects to the two organisms. We recommend that biological tests should be used to identify the most harmful products before they are released on the market.

  10. CFD Simulation of Fouling by Biological materials in Membrane Bioreactor

    Directory of Open Access Journals (Sweden)

    Raziye, Ahmadi

    2016-06-01

    Full Text Available In recent years membrane bioreactors filtration is increasingly used in wastewater treatment to enhance the quality of wastewater. The main problem in preventing the widespread use of membrane bioreactor is its congestion which has a severe impact on output flux to time ratio. If solid suspensions with high concentrations exist in the wastewater, this influence will be even more severe. In addition to the suspended solids in the liquid mixture, Extracellular polymeric materials (EPS and soluble microbial products (SMP are also known as basic microbial products that cause membrane fouling. EPS can be calculated within and on the membrane which increases the viscosity of suspended solids in the liquid mixture and increases filtration resistance. SMPs cannot penetrate the pores of the ultra filtration membrane due to the limited size of the pores which would cause fouling in membrane processes. According to the above issues, providing a model that indicates the properties and conditions of formation and destruction of SMP and EPS at the same time seems necessary. In this paper, CFD simulation of biological fouling in membrane bioreactor is provided using Fluent software.

  11. Fouling-release Property of Water-filled Porous Elastomers

    Institute of Scientific and Technical Information of China (English)

    Lai-yong Xie; Fei Hong; Chuan-xin He; Jian-hong Liu; Chi Wu

    2012-01-01

    Since the fouling-releasing ability of silicone elastomers increased as their modulus decreases,we designed and prepared composites with embedded tiny NaCl crytals that were soluble after their immersion in water,resulting in water-filled porous elastomers.The scanning electron microscope images confirmed such a designed water-filling porous structure.The existence of many micro-drops of water in these specially designed elastomers decreased the shear storage modulus and increased the loss factors.The decrease of shear modulus plays a leading role here and is directly related to a lower critical peeling-off stress of a pseudo-barnacle on them.Therefore,such a novel preparation with cheap salts instead of an expensive silicone provides a better way to make fouling-release paints with a lower modulus,a lower critical peeling-off stress and a better fouling-release property without a significant decrease of the cross-linking density.

  12. Research and development to overcome fouling of membranes

    Energy Technology Data Exchange (ETDEWEB)

    Narang, S.C.; Sharma, S.K.; Ventura, S.C.; Roberts, D.L.; Ahner, N.

    1992-06-01

    During this first year of the program, we have successfully accomplished the main objective of demonstrating the feasibility of using piezoelectrically assisted ultrafiltration to reduce membrane fouling and enhance the flux through ultrafiltration membranes. A preliminary economic evaluation, accounting for the power consumption of the piezoelectric driver and the extent of permeate flow rate enhancement, has also shown that piezoelectrically assisted ultrafiltration is cost effective and economically competitive with traditional separation processes. Piezoelectric transducers, such as a piezoelectric lead zirconate titanate (PZT) disc or a piezoelectric horn, driven by moderate power, significantly enhance the permeate flux on fouled membranes, presumably because they promote local turbulence. Several experiments were conducted on polysulfone and regenerated cellulose UF membranes fouled during filtration of model feed solutions. Solutions of poly(ethylene glycol) and of high-molecular weight dextran were used as models. We found that we could significantly increase the permeate flux by periodically driving the piezoelectric transducer, horn, or PZT disc, by application of moderate power over short periods of time, from 20 to 90 seconds. Enhancements as high as a factor of 8 were recorded with a few seconds, and enhanced permeate fluxes were maintained over a prolonged period (up to 3 hours). The prolonged flux enhancement makes it feasible to drive the piezoelectric transducer intermittently, thereby reducing the power consumption of the piezoelectric driver.

  13. Desalination and water recovery: Control of membrane fouling

    Energy Technology Data Exchange (ETDEWEB)

    Reddy, A.V.R.; Jagan Mohan, D.; Buch, P.R.; Joshi, S.V.; Pushpito Kumar Ghosh [Reverse Osmosis Discipline, Central Salt and Marine Chemicals Research Institute, Bhavnagar, Gujarat (India)]. E-mail: salt@csir.res.in

    2006-07-01

    Ultrafiltration (UF), Nanofiltration (NF) and Reverse Osmosis (RO) technologies are widely used for the production of safe drinking water, and for the recovery of reusable water from various industrial effluent streams. The most commonly encountered phenomenon in these processes, especially in water recovery application, is membrane fouling, and control of membrane fouling is regarded as a significant challenge. Membranes with charged and hydrophilic surfaces are reported to be less susceptible to fouling and often reversible. UF/RO membranes containing negatively charged and/or neutral hydrophilic functional groups on the surface were prepared by surface modification of suitable membranes. The surface modified membranes exhibited separations of 68%-85% for Na{sub 2}SO{sub 4}, 19%-31% for MgSO{sub 4}, 10%-26% for NaCl and 2%-12% for CaCl{sub 2} with water permeation rates of 9-50 l/m{sup 2}-h at the operating pressure of 4 kg/cm{sup 2}. The UF membranes were tested for water recovery from reactive dye effluents containing solutes with molecular sizes in the range of 600-1000 Da along with inorganic solutes. Surface-modified RO membranes were utilised for desalination of brackish water. (author)

  14. Novel filtration mode for fouling limitation in membrane bioreactors.

    Science.gov (United States)

    Wu, Jinling; Le-Clech, Pierre; Stuetz, Richard M; Fane, Anthony G; Chen, Vicki

    2008-08-01

    A novel filtration mode is presented to reduce fouling propensity in membrane bioreactors (MBR). During this mode, an elevated high instantaneous flux (60Lm(-2)h(-1)) is initially applied for a short time (120s), followed by a longer filtration (290s) at lower flux (10.3Lm(-2)h(-1)) and a backwash in each filtration cycle. The mixed mode is expected to limit irreversible fouling as the reversible fouling created during the initial stage appears to protect the membrane. Hydraulic performance and the components of foulants were analyzed and compared with conventional continuous and backwash modes. It was found that the mixed mode featured lower trans-membrane pressure (TMP) after 24h of filtration when compared to other modes. The mixed mode was effective in preventing soluble microbial products (SMP) attaching directly onto the membrane surface, keeping the cake layer weakly compressed, and reducing the mixed liquor suspended solids (MLSS) accumulation on the membrane. This strategy reduced the resistances of both the cake layer and the gel layer. A factorial experimental design was carried out for eight runs with different conditions to identify the major operational parameters affecting the hydraulic performances. The results showed that the value of the flux in the initial high-flux period had the most effect on the performance of the mixed mode: high initial flux (60Lm(-2)h(-1)) led to improved performance.

  15. Field Test of Boiler Primary Loop Temperature Controller

    Energy Technology Data Exchange (ETDEWEB)

    Glanville, P. [Partnership for Advanced Residential Retrofit, Des Plaines, IL (United States); Rowley, P. [Partnership for Advanced Residential Retrofit, Des Plaines, IL (United States); Schroeder, D. [Partnership for Advanced Residential Retrofit, Des Plaines, IL (United States); Brand, L. [Partnership for Advanced Residential Retrofit, Des Plaines, IL (United States)

    2014-09-01

    Beyond these initial system efficiency upgrades are an emerging class of Advanced Load Monitoring (ALM) aftermarket controllers that dynamically respond to the boiler load, with claims of 10% to 30% of fuel savings over a heating season. For hydronic boilers specifically, these devices perform load monitoring, with continuous measurement of supply and, in some cases, return water temperatures. Energy savings from these ALM controllers are derived from dynamic management of the boiler differential, where a microprocessor with memory of past boiler cycles prevents the boiler from firing for a period of time, to limit cycling losses and inefficient operation during perceived low load conditions. These differ from OTR controllers, which vary boiler setpoint temperatures with ambient conditions while maintaining a fixed differential.

  16. Modelling, simulating and optimizing boiler heating surfaces and evaporator circuits

    DEFF Research Database (Denmark)

    Sørensen, K.; Condra, T.; Houbak, Niels

    2003-01-01

    A model for optimizing the dynamic performance of boiler have been developed. Design variables related to the size of the boiler and its dynamic performance have been defined. The object function to be optimized takes the weight of the boiler and its dynamic capability into account. As constraints...... for the optimization a dynamic model for the boiler is applied. Furthermore a function for the value of the dynamic performance is included in the model. The dynamic models for simulating boiler performance consists of a model for the flue gas side, a model for the evaporator circuit and a model for the drum....... The dynamic model has been developed for the purpose of determining boiler material temperatures and heat transfer from the flue gas side to the water-/steam side in order to simulate the circulation in the evaporator circuit and hereby the water level fluctuations in the drum. The dynamic model has been...

  17. Modelling, simulating and optimizing boiler heating surfaces and evaporator circuits

    DEFF Research Database (Denmark)

    Sørensen, Kim; Condra, Thomas Joseph; Houbak, Niels

    2003-01-01

    A model for optimizing the dynamic performance of boiler have been developed. Design variables related to the size of the boiler and its dynamic performance have been dened. The object function to be optimized takes the weight of the boiler and its dynamic capability into account. As constraints...... for the optimization a dynamic model for the boiler is applied. Furthermore a function for the value of the dynamic performance is included in the model. The dynamic models for simulating boiler performance consists of a model for the ue gas side, a model for the evaporator circuit and a model for the drum....... The dynamic model has been developed for the purpose of determining boiler material temperatures and heat transfer from the ue gas side to the water-/steam side in order to simulate the circulation in the evaporator circuit and hereby the water level uctuations in the drum. The dynamic model has been...

  18. R&D and Demonstration of Large Domestic CFB Boilers

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    @@ In order to develop large CFB boilers with independent intellectual property,Xi'an Thermal Power Research Institute (TPRI) established a laboratory with complete functions for the technical development of CFB boilers.This laboratory consists ofa 1-MW and a 4-MW CFB combustion test facilities and a laboratory for limestone desulphurization performance evaluation.It carried out tests on CFB combustion and desulphurization for Chinese typical coals and limestone and research on heat-transfer characteristics and key parts,and developed the first home-made 100-MW CFB boiler.Based on the experience of R&D,the laboratory further researched key techniques for enlarging capacity systematically,and cooperating with Harbin Boiler Co.(HBC),developed the first domestic 210-MW CFB boiler with independent intellectual property and put it into engineering demonstration,laying a solid foundation for the development of CFB boilers of even larger capacity.

  19. Maximising safety in the boiler house.

    Science.gov (United States)

    Derry, Carr

    2013-03-01

    Last month's HEJ featured an article, the second in our new series of guidance pieces aimed principally at Technician-level engineers, highlighting some of the key steps that boiler operators can take to maximise system performance and efficiency, and thus reduce running both costs and carbon footprint. In the third such article, Derry Carr, C.Env, I.Eng, BSc (Hons), M.I.Plant.E., M.S.O.E., technical manager & group gas manager at Dalkia, who is vice-chairman of the Combustion Engineering Association, examines the key regulatory and safety obligations for hospital energy managers and boiler technicians, a number of which have seen changes in recent years with revision to guidance and other documentation.

  20. Recovery boiler model; Soodakattilan kehitystyoe III

    Energy Technology Data Exchange (ETDEWEB)

    Janka, K.; Ylitalo, M.; Sundstroem, K.; Helke, R.; Heinola, M. [Kvaerner Pulping Oy, Tampere (Finland)

    1997-10-01

    The recovery boiler model was further tested and developed. At this moment the model includes submodels for: droplet drying, pyrolysis, char burning, gas burning and for droplet trajectory. During 1996 the formation of CH{sub 4} during pyrolysis and release of sulfur was included to the model. Further the formation of NO from fuel nitrogen and formation of thermal- NO were included to the model using Arrhenius type reaction rate equations. The calculated results are realistic and the model is used as a tool to find out methods to increase the efficiency and availability and decrease the emissions. Analysing the results of the earlier field study of 8 boilers showed that the furnace heat load, fuming rate, find the black liquor composition have influence on the enrichment of the potassium to the fly ash. (orig.)

  1. Flow Induced Acoustic Resonance in In-line Tube Banks

    Institute of Scientific and Technical Information of China (English)

    Hiromitsu Hamakawa; Tohru Fukano; Eiichi Nishida; Yoshikazu Satou

    2006-01-01

    In the present paper the attention is focused on the relation between vortex shedding phenomena and acoustic resonance which occurred in the two-dimensional model of boiler. There were tube banks with in-line arrangement for small tube pitch ratio. We measured the sound pressure level, the phase delay of acoustic pressures, the spectrum of velocity fluctuation and the gap velocity. As a result, we found two peak frequencies of sound pressure level with different Strouhal numbers St, mainly about 0.26 and 0.52. The noise of St=0.26 was the resonance of transverse mode and St=0.52 was longitudinal mode. The vortex shedding of St=0.15 was generated inside the tube banks without acoustic resonance. As gap velocity increased, we observed that the peak level of spectrum was weak and broad-banded. The onset velocity of the acoustic resonance of longitudinal mode was lower than that of transverse mode.

  2. Development of an on-line monitoring expert system for heating system fouling

    Science.gov (United States)

    Wang, Yuan-yuan; Wang, Jian-guo

    2008-12-01

    This paper intends to develop an on-line monitoring expert system for heating system fouling. It chooses pressure, flowing and temperature as basic diagnostic variables. The basic evaluative guide lines are the coefficient of flowing resistance, the efficiency and cost of heating system. This system can be used to monitor the fouling degrees and estimate the fouling positions. The expert system is programmed by Delphi to realize all functions.

  3. Prediction and mitigation of air preheater fouling due to ammonium bisulfate

    Energy Technology Data Exchange (ETDEWEB)

    Afonso, R.; Tavoulareas, S.; Stallings, J. [Energy and Environmental Strategies, MA (United States)

    2001-07-01

    This paper provides a brief review of the fundamentals of ammonium bisulfate (ABS) formation, deposition and fouling in the air preheater. It presents a software-based predictive model for assessing the potential for air preheater fouling as a result of proposed SNCR or SCR retrofits and considering site-specific conditions and introduces a software-based cost-benefit model for assessing the economic trade-offs of various ABS fouling mitigation options. 7 refs., 13 figs.

  4. Mathematical Modelling and Simulation of Fouling of Nigerian Crude Oil Equipment Installations

    OpenAIRE

    Abdulsalami S. KOVO

    2006-01-01

    The aim of this research work was to develop Mathematical Model to Predict the Fouling of Nigeria Oil Equipment Installation. The term fouling can defined as the deposition of unwanted material on heat transfer equipment, which results in an increase in thermal resistance to heat transfer and subsequent loss of equipment thermal efficiency. The modelling equation formulated was based on the principle of fouling process being in unsteady state condition. That is, the rate of deposition is not ...

  5. Particulate and organic matter fouling of seawater reverse osmosis systems: Characterization, modelling and applications

    OpenAIRE

    Salinas Rodriguez, S.G.

    2011-01-01

    Particulate/colloidal and organic fouling in seawater reverse osmosis (SWRO) systems results in flux decline, higher energy costs, increased salt passage, increased cleaning frequency, and use of chemicals. In practice, indices like SDI and MFI are used to assess particulate fouling, but they are performed at very high initial flux (> 1500 L/m2-h) and do not take into account the deposition of particles/colloids in RO systems. In this study, the Modified Fouling Index with ultrafiltration mem...

  6. Particulate and organic matter fouling of SWRO systems: Characterization, modelling and applications

    OpenAIRE

    Salinas Rodríguez, S.G.

    2011-01-01

    Particulate/colloidal and organic fouling in seawater reverse osmosis (SWRO) systems results in flux decline, higher energy costs, increased salt passage, increased cleaning frequency, and use of chemicals. In practice, indices like SDI and MFI are used to assess particulate fouling, but they are performed at very high initial flux (> 1500 L/m2-h) and do not take into account the deposition of particles/colloids in RO systems. In this study, the Modified Fouling Index with ultrafiltration mem...

  7. TRIO specification of a steam boiler controller

    Energy Technology Data Exchange (ETDEWEB)

    Gargantini, A. [Politecnico di Milano (Italy). Dipt. di Electronica e Informazione; Morzenti, A. [Politecnico di Milano (Italy). Dipt. di Electronica e Informazione

    1996-12-31

    We specify a controller for a steam boiler starting from an informal descriptions of its requirements. The specification is formalized in the temporal logic TRIO and its object-oriented extension TRIO+. To obtain a maximum of abstraction and reuse we make the specification parametric with respect to all equipment and hardware features, and we avoid to impose any particular strategy in the management of the available resources and in the control of the critical physical quantities. (orig.)

  8. Circulating fluidized bed boilers design and operations

    CERN Document Server

    Basu, Prabir

    1991-01-01

    This book provides practicing engineers and students with insight into the design and operation of circulating fluidized bed (CFB) boilers. Through a combination of theoretical concepts and practical experience, this book gives the reader a basic understanding of the many aspects of this subject.Important environmental considerations, including solid waste disposal and predicted emissions, are addressed individually in separate chapters. This book places an emphasis on combustion, hydrodynamics, heat transfer, and material issues, and illustrates these concepts with numerous examples of pres

  9. Computer monitoring and optimization of the steam boiler performance

    OpenAIRE

    Sobota Tomasz

    2017-01-01

    The paper presents a method for determination of thermo-flow parameters for steam boilers. This method allows to perform the calculations of the boiler furnace chamber and heat flow rates absorbed by superheater stages. These parameters are important for monitoring the performance of the power unit. Knowledge of these parameters allows determining the degree of the furnace chamber slagging. The calculation can be performed in online mode and use to monitoring of steam boiler. The presented me...

  10. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    Energy Technology Data Exchange (ETDEWEB)

    R. Viswanathan; K. Coleman; R.W. Swindeman; J. Sarver; J. Blough; W. Mohn; M. Borden; S. Goodstine; I. Perrin

    2003-10-20

    The principal objective of this project is to develop materials technology for use in ultrasupercritical (USC) plant boilers capable of operating with 760 C (1400 F), 35 MPa (5000 psi) steam. This project has established a government/industry consortium to undertake a five-year effort to evaluate and develop of advanced materials that allow the use of advanced steam cycles in coal-based power plants. These advanced cycles, with steam temperatures up to 760 C, will increase the efficiency of coal-fired boilers from an average of 35% efficiency (current domestic fleet) to 47% (HHV). This efficiency increase will enable coal-fired power plants to generate electricity at competitive rates (irrespective of fuel costs) while reducing CO{sub 2} and other fuel-related emissions by as much as 29%. Success in achieving these objectives will support a number of broader goals. First, from a national prospective, the program will identify advanced materials that will make it possible to maintain a cost-competitive, environmentally acceptable coal-based electric generation option. High sulfur coals will specifically benefit in this respect by having these advanced materials evaluated in high-sulfur coal firing conditions and from the significant reductions in waste generation inherent in the increased operational efficiency. Second, from a national prospective, the results of this program will enable domestic boiler manufacturers to successfully compete in world markets for building high-efficiency coal-fired power plants.

  11. Optimised control of coal-fired boilers

    Energy Technology Data Exchange (ETDEWEB)

    Owens, D.H.; MacConnell, P.F.A.; Neuffer, D.; Dando, R. [University of Exeter, Exeter (United Kingdom). Centre for System and Control Engineering

    1997-07-01

    The objective of the project is to develop and specify a control methodology that will enable existing coal combustion plant to take maximum advantage of modern control techniques. The research is specifically aimed at chain-grate stoker plant (such as the test facility at the Coal Research Establishment, Cheltenham) on which little work has been done for thirty years yet which still represents a large proportion of industrial coal-fired plant in operation worldwide. In detail, the project: reviewed existing control strategies for moving grate stokers, highlighting their limitations and areas for improvements; carried out plant trials to identify the system characteristics such as response time and input/output behaviour; developed a theoretical process based on physical and chemical laws and backed up by trial data; specified control strategies for a single boiler; simulated and evaluated the control strategies using model simulations; developed of an optimised. Control strategy for a single boiler; and assessed the applicability and effects of this control strategy on multiple boiler installations. 67 refs., 34 figs.

  12. Particulate emission abatement for Krakow boiler houses

    Energy Technology Data Exchange (ETDEWEB)

    Wysk, R.

    1995-12-31

    Among the many strategies for improving air quality in Krakow, one possible method is to adapt new and improved emission control technology. This project focuses on such a strategy. In order to reduce dust emissions from coal-fueled boilers, a new device called a Core Separator has been introduced in several boiler house applications. This advanced technology has been successfully demonstrated in Poland and several commercial units are now in operation. Particulate emissions from the Core Separator are typically 3 to 5 times lower than those from the best cyclone collectors. It can easily meet the new standard for dust emissions which will be in effect in Poland after 1997. The Core Separator is a completely inertial collector and is based on a unique recirculation method. It can effectively remove dust particles below 10 microns in diameter, the so-called PM-10 emissions. Its performance approaches that of fabric filters, but without the attendant cost and maintenance. It is well-suited to the industrial size boilers located in Krakow. Core Separators are now being marketed and sold by EcoInstal, one of the leading environmental firms in Poland, through a cooperative agreement with LSR Technologies.

  13. Tailoring Membrane Surface Charges: A Novel Study on Electrostatic Interactions during Membrane Fouling

    Directory of Open Access Journals (Sweden)

    Daniel Breite

    2015-10-01

    Full Text Available In this work we aim to show that the overall surface potential is a key factor to understand and predict anti-fouling characteristics of a polymer membrane. Therefore, polyvinylidene fluoride membranes were modified by electron beam-induced grafting reactions forming neutral, acidic, alkaline or zwitterionic structures on the membrane surface. The differently charged membranes were investigated regarding their surface properties using diverse analytical methods: zeta potential, static and dynamic water contact angle, scanning electron microscopy (SEM and X-ray photoelectron spectroscopy (XPS. Porosimetry measurements proved that there is no pore blocking due to the modifications. Monodisperse suspensions of differently charged polystyrene beads were synthesized by a radical emulsion polymerization reaction and were used as a model fouling reagent, preventing comparability problems known from current literature. To simulate membrane fouling, different bead suspensions were filtered through the membranes. The fouling characteristics were investigated regarding permeation flux decline and concentration of model fouling reagent in filtrate as well as by SEM. By considering electrostatic interactions equal to hydrophobic interactions we developed a novel fouling test system, which enables the prediction of a membrane’s fouling tendency. Electrostatic forces are dominating, especially when charged fouling reagents are present, and can help to explain fouling characteristics that cannot be explained considering the surface wettability.

  14. Investigation of CaCO3 fouling in plate heat exchangers

    Science.gov (United States)

    Li, Wei; Zhou, Kan; Manglik, Raj M.; Li, Guan-Qiu; Bergles, Arthur E.

    2016-11-01

    An experimental investigation, coupled with theoretical modeling of CaCO3 fouling in plate-and-frame type heat exchangers (PHEs) have been conducted. Four different plates, made of SS-304, are used in two different surface patterns (chevron and zig-zag) of varying corrugation severity (waviness depth and pitch) and area enhancement. They were further characterized in clean, non-fouled convection by their measured heat transfer coefficients and friction factors in the Reynolds number range of 600-6000. The flow-fouling experiments delineate the effects of temperature and plate-surface geometry on growth rates and stabilization of fouling resistance, along with the anti-fouling behavior of plates coated with a hydrophobic PTFE (Teflon) film. Moreover, the microscopic structure of fouling deposits is mapped in a scanning-electron microscope. Corrugated plates with the largest height-to-pitch ratio and hydraulic diameter are found to have the lowest fouling growth rate and resistance; Teflon-film coating of plate surface is also found to mitigate fouling relative to the performance of bare stainless steel plates. Finally, a semi-empirical fouling model, based on the Prandtl-Taylor analogy, has been devised to describe the experimental data and provide a predictive tool.

  15. Membrane Bioreactor (MBR Technology for Wastewater Treatment and Reclamation: Membrane Fouling

    Directory of Open Access Journals (Sweden)

    Oliver Terna Iorhemen

    2016-06-01

    Full Text Available The membrane bioreactor (MBR has emerged as an efficient compact technology for municipal and industrial wastewater treatment. The major drawback impeding wider application of MBRs is membrane fouling, which significantly reduces membrane performance and lifespan, resulting in a significant increase in maintenance and operating costs. Finding sustainable membrane fouling mitigation strategies in MBRs has been one of the main concerns over the last two decades. This paper provides an overview of membrane fouling and studies conducted to identify mitigating strategies for fouling in MBRs. Classes of foulants, including biofoulants, organic foulants and inorganic foulants, as well as factors influencing membrane fouling are outlined. Recent research attempts on fouling control, including addition of coagulants and adsorbents, combination of aerobic granulation with MBRs, introduction of granular materials with air scouring in the MBR tank, and quorum quenching are presented. The addition of coagulants and adsorbents shows a significant membrane fouling reduction, but further research is needed to establish optimum dosages of the various coagulants/adsorbents. Similarly, the integration of aerobic granulation with MBRs, which targets biofoulants and organic foulants, shows outstanding filtration performance and a significant reduction in fouling rate, as well as excellent nutrients removal. However, further research is needed on the enhancement of long-term granule integrity. Quorum quenching also offers a strong potential for fouling control, but pilot-scale testing is required to explore the feasibility of full-scale application.

  16. Assessment of Silt Density Index (SDI) as Fouling Propensity Parameter in Reverse Osmosis Desalination

    KAUST Repository

    Rachman, Rinaldi

    2011-07-01

    Reverse osmosis operations are facing persistent fouling phenomenon that has challenged the integrity of these processes. Prediction of fouling potential by measuring a fouling index toward feed water is essential to ensure robust operation. Moreover, employing a reliable fouling index with good reproducibility and precision is necessary. Silt density index (SDI) is considered insufficient in terms of reliability and empirical theory, among other limitations. Nevertheless due its simplicity, SDI measurement is utilized extensively in RO desalination systems. The aim of this research is to assess the reliability of SDI. Methods include the investigation of different SDI membranes and study of the nature of the SDI filtration. Results demonstrate the existence of the membrane properties\\' variation within manufacturers, which then causes a lack of accuracy in fouling risk estimation. The nature of particles during SDI filtration provides information that particle concentration and size play a significant role on SDI quantification with substantial representation given by particles with size close to membrane nominal pore size. Moreover, turbidity assisted SDI measurements along with determination of UF pretreated and clean water fouling potential, establishes the indication of non-fouling related phenomena involved on SDI measurement such as a natural organic matter adsorption and hydrodynamic condition that alters during filtration. Additionally, it was found that the latter affects the sensitivity of SDI by being represented by some portions of SDI value. Keywords: Reverse Osmosis, Fouling index, Particulate Fouling, Silt Density Index (SDI), and Assessment of SDI.

  17. Mathematical Modelling and Simulation of Fouling of Nigerian Crude Oil Equipment Installations

    Directory of Open Access Journals (Sweden)

    Abdulsalami S. KOVO

    2006-07-01

    Full Text Available The aim of this research work was to develop Mathematical Model to Predict the Fouling of Nigeria Oil Equipment Installation. The term fouling can defined as the deposition of unwanted material on heat transfer equipment, which results in an increase in thermal resistance to heat transfer and subsequent loss of equipment thermal efficiency. The modelling equation formulated was based on the principle of fouling process being in unsteady state condition. That is, the rate of deposition is not equal to the rate of removal. In other words, there is an accumulation. The final mathematical model developed representing the fouling of Nigeria Oil equipment was obtained as:... The correlation between the experimental and simulated result obtained using Average Absolute Deviation (A.A.D was between 0.0131 - 0.0201. The fluid temperature of 43°C and 63°C and wire temperature 200°C, 250°C and 300°C were the operating conditions for the investigation and prediction. The model was simulated using VISUAL BASIC 6.0 to predict the fouling behaviour. The results obtained showed that refinery Naptha fouls very heavily and this fouling decreases with increasing fluid and wire temperature. Fouling was very severe for wire temperature 200°C and fluid temperature 46°C. The main mechanism of fouling for refinery Naptha was chemical polymerization.

  18. Membrane Bioreactor (MBR) Technology for Wastewater Treatment and Reclamation: Membrane Fouling.

    Science.gov (United States)

    Iorhemen, Oliver Terna; Hamza, Rania Ahmed; Tay, Joo Hwa

    2016-01-01

    The membrane bioreactor (MBR) has emerged as an efficient compact technology for municipal and industrial wastewater treatment. The major drawback impeding wider application of MBRs is membrane fouling, which significantly reduces membrane performance and lifespan, resulting in a significant increase in maintenance and operating costs. Finding sustainable membrane fouling mitigation strategies in MBRs has been one of the main concerns over the last two decades. This paper provides an overview of membrane fouling and studies conducted to identify mitigating strategies for fouling in MBRs. Classes of foulants, including biofoulants, organic foulants and inorganic foulants, as well as factors influencing membrane fouling are outlined. Recent research attempts on fouling control, including addition of coagulants and adsorbents, combination of aerobic granulation with MBRs, introduction of granular materials with air scouring in the MBR tank, and quorum quenching are presented. The addition of coagulants and adsorbents shows a significant membrane fouling reduction, but further research is needed to establish optimum dosages of the various coagulants/adsorbents. Similarly, the integration of aerobic granulation with MBRs, which targets biofoulants and organic foulants, shows outstanding filtration performance and a significant reduction in fouling rate, as well as excellent nutrients removal. However, further research is needed on the enhancement of long-term granule integrity. Quorum quenching also offers a strong potential for fouling control, but pilot-scale testing is required to explore the feasibility of full-scale application.

  19. Understanding the risk of scaling and fouling in hollow fiber forward osmosis membrane application

    KAUST Repository

    Majeed, Tahir

    2016-06-23

    Fouling studies of forward osmosis (FO) were mostly conducted based on fouling evaluation principals applied to pressure membrane processes such as reverse osmosis (RO)/nanofiltration (NF)/microfiltration (MF)/ultrafiltration (UF). For RO/NF/MF/UF processes, the single flux driving force (hydraulic pressure) remains constant, thus the fouling effect is easily evaluated by comparing flux data with the baseline. Whilst, the scenario of fouling effects for FO process is entirely different from RO/NF/MF/UF processes. Continuously changing driving force (osmotic pressure difference), the changes in concentration polarization associated with the varying draw solution/feed solution concentration and the fouling layer effects collectively influence the FO flux. Thus, usual comparison of the FO flux outcome with the baseline results can not exactly indicate the real affect of membrane fouling, rather presents a misleading cumulative effect. This study compares the existing FO fouling technique with an alternate fouling evaluation approach using two FO set-ups. Scaling and fouling risk for hollow fiber FO was separately investigated using synthetic water samples and model organic foulants as alginate, humic acid and bovine serum albumin. Results indicated that FO flux declines up to 5% and 49% in active layer-feed solution and active layer-draw solution orientations respectively.

  20. Membrane Bioreactor (MBR) Technology for Wastewater Treatment and Reclamation: Membrane Fouling

    Science.gov (United States)

    Iorhemen, Oliver Terna; Hamza, Rania Ahmed; Tay, Joo Hwa

    2016-01-01

    The membrane bioreactor (MBR) has emerged as an efficient compact technology for municipal and industrial wastewater treatment. The major drawback impeding wider application of MBRs is membrane fouling, which significantly reduces membrane performance and lifespan, resulting in a significant increase in maintenance and operating costs. Finding sustainable membrane fouling mitigation strategies in MBRs has been one of the main concerns over the last two decades. This paper provides an overview of membrane fouling and studies conducted to identify mitigating strategies for fouling in MBRs. Classes of foulants, including biofoulants, organic foulants and inorganic foulants, as well as factors influencing membrane fouling are outlined. Recent research attempts on fouling control, including addition of coagulants and adsorbents, combination of aerobic granulation with MBRs, introduction of granular materials with air scouring in the MBR tank, and quorum quenching are presented. The addition of coagulants and adsorbents shows a significant membrane fouling reduction, but further research is needed to establish optimum dosages of the various coagulants/adsorbents. Similarly, the integration of aerobic granulation with MBRs, which targets biofoulants and organic foulants, shows outstanding filtration performance and a significant reduction in fouling rate, as well as excellent nutrients removal. However, further research is needed on the enhancement of long-term granule integrity. Quorum quenching also offers a strong potential for fouling control, but pilot-scale testing is required to explore the feasibility of full-scale application. PMID:27314394