WorldWideScience

Sample records for boiler corrosion quarterly

  1. Cracking and corrosion recovery boiler

    Energy Technology Data Exchange (ETDEWEB)

    Suik, H. [Tallinn Technical University, Horizon Pulp and Paper, Tallinn (Estonia)

    1998-12-31

    The corrosion of heat surfaces and the cracking the drums are the main problems of the recovery boiler. These phenomena have been appeared during long-term operation of boiler `Mitsubishi - 315` erected at 1964. Depth of the crack is depending on the number of shutdowns and on operation time. Corrosion intensity of different heat surfaces is varying depend on the metal temperature and the conditions at place of positioning of tube. The lowest intensity of corrosion is on the bank tubes and the greatest is on the tubes of the second stage superheater and on the tubes at the openings of air ports. (orig.) 5 refs.

  2. Stress-Assisted Corrosion in Boiler Tubes

    Energy Technology Data Exchange (ETDEWEB)

    Preet M Singh; Steven J Pawel

    2006-05-27

    A number of industrial boilers, including in the pulp and paper industry, needed to replace their lower furnace tubes or decommission many recovery boilers due to stress-assisted corrosion (SAC) on the waterside of boiler tubes. More than half of the power and recovery boilers that have been inspected reveal SAC damage, which portends significant energy and economic impacts. The goal of this project was to clarify the mechanism of stress-assisted corrosion (SAC) of boiler tubes for the purpose of determining key parameters in its mitigation and control. To accomplish this in-situ strain measurements on boiler tubes were made. Boiler water environment was simulated in the laboratory and effects of water chemistry on SAC initiation and growth were evaluated in terms of industrial operations. Results from this project have shown that the dissolved oxygen is single most important factor in SAC initiation on carbon steel samples. Control of dissolved oxygen can be used to mitigate SAC in industrial boilers. Results have also shown that sharp corrosion fatigue and bulbous SAC cracks have similar mechanism but the morphology is different due to availability of oxygen during boiler shutdown conditions. Results are described in the final technical report.

  3. Study of Corrosion in a Biomass Boiler

    OpenAIRE

    Berlanga, C.; Ruiz, J. A.

    2013-01-01

    Biomass plants, apart from producing energy, help to reduce CO2(g) emissions. One of the biggest problems for their development is superheater corrosion due to fuel corrosivity, especially of the straw. This limits both the temperature of the vapour and also the effectiveness of the plant. In order to know more about the reactions which happen inside the boiler of biomass, thermodynamic calculations using software (HSC Chemistry) have been carried out. Field tests have been carried out in the...

  4. Model boiler studies on deposition and corrosion

    International Nuclear Information System (INIS)

    Deposit formation was studied in a model boiler, with sea-water injections to simulate the in-leakage which could occur from sea-water cooled condensers. When All Volatile Treatment (AVT) was used for chemistry control the deposits consisted of the sea-water salts and corrosion products. With sodium phosphate added to the boiler water, the deposits also contained the phosphates derived from the sea-water salts. The deposits were formed in layers of differing compositions. There was no significant corrosion of the Fe-Ni-Cr alloy boiler tube under deposits, either on the open area of the tube or in crevices. However, carbon steel that formed a crevice around the tube was corroded severely when the boiler water did not contain phosphate. The observed corrosion of carbon steel was caused by the presence of acidic, highly concentrated chloride solution produced from the sea-water within the crevice. Results of theoretical calculations of the composition of the concentrated solution are presented. (author)

  5. Sulphur recirculation for reduced boiler corrosion; Minskad pannkorrosion med svavelrecirkulation

    Energy Technology Data Exchange (ETDEWEB)

    Andersson, Sven; Karlsson, Martin (Goetaverken Miljoe AB, Goeteborg (Sweden)); Blomqvist, Evalena; Baefver, Linda; Claesson, Frida; Davidsson, Kent (SP Sveriges Tekniska Forskningsinstitut, Boraas (Sweden)); Froitzheim, Jan; Pettersson, Jesper; Steenari, Britt-Marie (Chalmers Tekniska Hoegskola, Oorganisk miljoekemi, Goeteborg (Sweden))

    2010-03-15

    Sulphur recirculation is a new technology for reducing boiler corrosion and dioxin formation, which was demonstrated in full-scale tests performed at the Renova Waste to Energy plant at Saevenaes in Goeteborg (Sweden). Sulphur is recirculated from the flue gas cleaning back to the boiler, which reduces the chloride content of the deposits, which in turn reduces boiler corrosion and dioxin formation. Sulphur dioxide was separated from the flue gas in a wet scrubber by adding hydrogen peroxide, producing sulphuric acid. The sulphuric acid was injected into the furnace using nozzles with atomization air, surrounded by recirculated flue gas for improved mixing. By recirculating the sulphur, the sulphur dioxide concentration was increased in the boiler. Each sulphur atom passed the boiler several times and no external sulphur had to be added. Dioxin, ash, deposits and particle samplings together with 1000 h corrosion probe measurements were performed for normal operation (reference) and with sulphur recirculation respectively. During spring 2009, reference measurements were made and the recirculation system was installed and tested. During autumn 2009, a long term test with sulphur recirculation was made. An SO{sub 2} concentration of approximately 800 mg/m3 (n, d.g.) was maintained in the boiler by the system except during a period of extremely low sulphur content in the waste. The sulphur dioxide stack concentrations have been far below the emission limit. Sulphuric acid dew point measurements have shown that the sulphuric acid dosage did not lead to elevated SO{sub 3} concentrations, which may otherwise lead to low temperature corrosion. The chlorine content of both fly ash and boiler ash decreased and the sulphur content increased during the sulphur recirculation tests. The molar chlorine/sulphur ratio (Cl/S) decreased by two thirds in the fly ash as well as in the boiler ash, except for one sample. With sulphur recirculation in operation, the deposit growth was

  6. Aspects of high temperature corrosion of boiler tubes

    Energy Technology Data Exchange (ETDEWEB)

    Spiegel, M.; Bendick, W. [Salzgitter-Mannesmann-Forschung GmbH, Duisburg (Germany)

    2008-07-01

    The development of new boiler steels for power generation has to consider significant creep strength as well as oxidation and corrosion resistance. High temperature corrosion of boiler materials concerns steam oxidation as well as fireside corrosion of parts, in contact with the flue gas. It will be shown that depending on the quality of the fuel, especially chlorine and sulphur are responsible for most of the fireside corrosion problems. Corrosion mechanisms will be presented for flue gas induced corrosion (HCl) and deposit induced corrosion (chlorides and sulfates). Especially for the 700 C technology, deposit induced corrosion issues have to be considered and the mechanisms of corrosion by molten sulfates 'Hot Corrosion' will be explained. Finally, an overview will be given on the selection of suitable materials in order to minimise corrosion relates failures. (orig.)

  7. High Temperature Corrosion in Biomass-Fired Boilers

    DEFF Research Database (Denmark)

    Henriksen, Niels; Montgomery, Melanie; Hede Larsen, Ole

    2002-01-01

    condense on superheater components. This gives rise to specific corrosion problems not previously encountered in coal-fired power plants. The type of corrosion attack can be directly ascribed to the composition of the deposit and the metal surface temperature. To avoid such high corrosion rates, woodchip...... has also been utilised as a fuel. Combustion of woodchip results in a smaller amount of ash, and potassium and chlorine are present in lesser amounts. However, significant corrosion rates were still seen. A case study of a woodchip fired boiler is described. The corrosion mechanisms in both straw-fired...... and woodchip fired boilers are discussed....

  8. Corrosion probes for fireside monitoring in coal-fired boilers

    Energy Technology Data Exchange (ETDEWEB)

    Covino, Bernard S., Jr.; Bullard, Sophie J.; Ziomek-Moroz, M.; Holcomb, Gordon R.

    2005-01-01

    Corrosion probes are being developed and combined with an existing measurement technology to provide a tool for assessing the extent of corrosion of metallic materials on the fireside in coal-fired boilers. The successful development of this technology will provide power plant operators the ability to (1) accurately monitor metal loss in critical regions of the boiler, such as waterwalls, superheaters, and reheaters; and (2) use corrosion rates as process variables. In the former, corrosion data could be used to schedule maintenance periods and in the later, processes can be altered to decrease corrosion rates. The research approach involves laboratory research in simulated environments that will lead to field tests of corrosion probes in coal-fired boilers. Laboratory research has already shown that electrochemically-measured corrosion rates for ash-covered metals are similar to actual mass loss corrosion rates. Electrochemical tests conducted using a potentiostat show the corrosion reaction of ash-covered probes at 500?C to be electrochemical in nature. Corrosion rates measured are similar to those from an automated corrosion monitoring system. Tests of corrosion probes made with mild steel, 304L stainless steel (SS), and 316L SS sensors showed that corrosion of the sensors in a very aggressive incinerator ash was controlled by the ash and not by the alloy content. Corrosion rates in nitrogen atmospheres tended to decrease slowly with time. The addition of oxygen-containing gases, oxygen and carbon dioxide to nitrogen caused a more rapid decrease in corrosion rate, while the addition of water vapor increased the corrosion rate.

  9. Boiler tube corrosion characterization with a scanning thermal line

    Science.gov (United States)

    Cramer, K. Elliott; Jacobstein, A. Ronald; Reilly, Thomas L.

    2001-03-01

    Wall thinning due to corrosion in utility boiler waterwall tubing is a significant operational concern for boiler operators. Historically, conventional ultrasonics has been used for inspection of these tubes. Unfortunately, ultrasonic inspection is very manpower intense and slow. Therefore, thickness measurements are typically taken over a relatively small percentage of the total boiler wall and statistical analysis is used to determine the overall condition of the boiler tubing. Other inspection techniques, such as electromagnetic acoustic transducer (EMAT), have recently been evaluated, however they provide only a qualitative evaluation - identifying areas or spots where corrosion has significantly reduced the wall thickness. NASA Langley Research Center, in cooperation with ThermTech Services, has developed a thermal NDE technique designed to quantitatively measure the wall thickness and thus determine the amount of material thinning present in steel boiler tubing. The technique involves the movement of a thermal line source across the outer surface of the tubing followed by an infrared imager at a fixed distance behind the line source. Quantitative images of the material loss due to corrosion are reconstructed from measurements of the induced surface temperature variations. This paper will present a discussion of the development of the thermal imaging system as well as the techniques used to reconstruct images of flaws. The application of the thermal line source coupled with the analysis technique represents a significant improvement in the inspection speed and accuracy for large structures such as boiler waterwalls.

  10. Hot Corrosion Studies in Coal Fired Boiler Environment

    OpenAIRE

    Kamal Subhash; Kumar Chennupati Vijya; Abdul-Rani A.M.

    2014-01-01

    Hot corrosion behaviour of the bare and D-gun coated superfer 800H exposed to low temperature super-heater zone of the coal fired boiler of Guru Nanak Dev Thermal Power Plant, Bathinda, Punjab, India. The specimens were hanged in the platen super-heater of coal fired boiler where the gas temperature was around 900 °C ±10 °C. Hot corrosion experiments were performed for 10 cycles, each cycle consisting of 100 hours exposure followed by 1 hour cooling at ambient temperature. Weight change measu...

  11. Investigation into boiler corrosion on the historic vessel SL Dolly.

    OpenAIRE

    Turnbull, I. A.; Robinson, M J

    2005-01-01

    When SL Dolly was recovered from Ullswater after being submerged for 67 years, the wrought iron boiler was found to have surprisingly little corrosion. This article describes the results of a project to investigate the reasons for this behaviour and determine whether it was a property of the wrought iron or a consequence of the lakebed environment. Weight loss measurements and electrochemical impedance spectroscopy were used to compare the corrosion rates of wrought iron and...

  12. Hot Corrosion Studies in Coal Fired Boiler Environment

    Directory of Open Access Journals (Sweden)

    Kamal Subhash

    2014-07-01

    Full Text Available Hot corrosion behaviour of the bare and D-gun coated superfer 800H exposed to low temperature super-heater zone of the coal fired boiler of Guru Nanak Dev Thermal Power Plant, Bathinda, Punjab, India. The specimens were hanged in the platen super-heater of coal fired boiler where the gas temperature was around 900 °C ±10 °C. Hot corrosion experiments were performed for 10 cycles, each cycle consisting of 100 hours exposure followed by 1 hour cooling at ambient temperature. Weight change measurements were done at the end of each cycle. The weight change data used for predicting hot corrosion behaviour of the coated alloys after the total exposure of 1000 hours. The different phases and their distribution in the hot corroded specimens were analysed with the help of FE-SEM/EDS and X-ray mapping.

  13. High temperature corrosion of boiler steels in hydrochloric atmosphere under oil shale ashes

    International Nuclear Information System (INIS)

    Highlights: • High temperature gaseous hydrochloric corrosion analysis of different boiler steels. • Influence on the corrosion of the presence of oil shale ashes and cyclic removing. • Empiric kinetic coherence equation and diagram for corrosion depth versus time. • Additional oxidation tests of all materials investigated. • Qualitative analysis of the present corrosion mechanisms. - Abstract: High temperature corrosion in power plants is a main breakdown criterion in boiler applications. This study is focused on the high-temperature corrosion resistance of several boiler steels used in Estonian power plants, which were experimentally tested in gaseous hydrochloric environment combined with Estonian oil shale ashes in a high temperature corrosion test up to 600 °C. Scanning electron microscopy supported by energy dispersive X-ray spectroscopy was used to reveal different corrosion mechanisms. Results indicate a strong dependence of the boiler steel corrosion to the present anions in the oil shale ash and their removal in the boiler

  14. Corrosion of evaporator tubes in low emission steam boilers

    Directory of Open Access Journals (Sweden)

    S. Topolska

    2010-04-01

    Full Text Available Purpose: of this paper is to reveal the mechanisms of corrosion processes of outer surfaces of low-emission steam boiler evaporator tubes. Examinations were performed to find the reasons of different corrosion susceptibility of tubes situated at combustion chamber on various levels.Design/methodology/approach: Examinations were conducted on several segments of Ø 57 x 5.0 mm evaporator tubes made of 16M (16Mo3 steel grade. Segments were taken from level of 10 meters and 18 meters from the chamber bottom of low-emission coal fired steam boiler after two years operation. Microstructure degradation of base material was estimated. Metallographic evaluation of scale morphology, its micro sites chemical composition analysis and distribution of elements on cross sections have been performed.Findings: Eexaminations of evaporator tubes indicated that reduction of wall thickness was considerable at the segments taken from level of 10 m, when at level of 18 m this reduction was small. The morphology of scales consisted of external layer which was porous and weakly connected to the tube surface, and internal layer, which was dense and adherent to the base metal. In these two layers the bands reach in sulfur were detected. The sulfide corrosion seems to be the main degradation mechanism of the tube surface at the level of 10 m.Research limitations/implications: Corrosion of the water wall tubes in low-emission steam boilers is a result of reaction of steel tube surface with the aggressive substoichiometric environment contains sulfur. The chemical composition of flue gases changes along the water wall. The exact compound of flue gases has not been determined in this study.Practical implications: Prevention of water wall tubes corrosion can be achieved by changing in operation conditions or replacement of tube materials. The first mentioned action is limited to accurate burner’s adjustment or introduces a flow of additional air along the walls and create

  15. High Temperature Corrosion in Biomass-Fired Boilers

    DEFF Research Database (Denmark)

    Henriksen, Niels; Montgomery, Melanie; Hede Larsen, Ole

    2002-01-01

    In Denmark, biomass such as straw or woodchip is utilised as a fuel for generating energy. Biomass is a "carbon dioxide neutral fuel" and therefore does not contribute to the greenhouse effect. When straw is combusted, potassium chloride and potassium sulphate are present in ash products, which...... has also been utilised as a fuel. Combustion of woodchip results in a smaller amount of ash, and potassium and chlorine are present in lesser amounts. However, significant corrosion rates were still seen. A case study of a woodchip fired boiler is described. The corrosion mechanisms in both straw...

  16. Corrosion of evaporator tubes in low emission steam boilers

    OpenAIRE

    S. Topolska; J. Łabanowski

    2010-01-01

    Purpose: of this paper is to reveal the mechanisms of corrosion processes of outer surfaces of low-emission steam boiler evaporator tubes. Examinations were performed to find the reasons of different corrosion susceptibility of tubes situated at combustion chamber on various levels.Design/methodology/approach: Examinations were conducted on several segments of Ø 57 x 5.0 mm evaporator tubes made of 16M (16Mo3) steel grade. Segments were taken from level of 10 meters and 18 meters from the cha...

  17. Untypical bromine corrosion in boilers co-firing biomass

    Directory of Open Access Journals (Sweden)

    A. Hernas

    2012-09-01

    Full Text Available Purpose: The aim of this study was to determine the untypical corrosion resistance of rotary air preheaters in a biomass co-fired power plant.Design/methodology/approach: The selected results of some components of regenerative rotary air preheaters in a biomass co-fired power plant are presented. The macro and microstructure of corroded components of a LUVO preheater after 3 years of service are presented. The chemical composition of corrosion products was determined by X-ray microanalysis.Findings: Data concerning toxicity and identification of PBDEs (Polibrominated diphenyl ethers in the biomass is very limited. The presented research provides information and the proposed corrosion reaction mechanism in environments containing biomass with aggressive compounds like Cl, Si, H and Br.Research limitations/implications: An extended research on PBDEs in power plant fuels is necessary to give a full assessment of the corrosion mechanism in the presented environment; obligatory classification of the co-fired biomass.Originality/value: Firstly, an assessment of the danger for boiler materials co-firing biomass containing brominated organic flame and presentation of the reaction during the corrosion process and degradation of power boiler components in the presented environment. Secondly, the highlighting of the problem that there is a need to properly select and determine the chemical composition of the biomass used.

  18. Low temperature corrosion in bark fuelled, small boilers

    Energy Technology Data Exchange (ETDEWEB)

    Lindau, Leif; Goldschmidt, Barbara

    2008-05-15

    A number of small (3-12 MW), new biofuel boiler plants in southern Sweden, and (at least) in Austria, have suffered a high (wastage of mm/yrs) corrosion rate on the low temperature boiler side. This problem has been investigated with respect to its occurrence and its character by contacts with operators, by plant inspections, and by analysis of cold-side deposits. The plants affected have low feed water temperatures (< 100 deg C). The plants fire most types of Swedish biofuel: chips, bark, hog fuel, and 'GROT' (=twigs and tops). The results found give basis for a hypothesis that the corrosion results from the presence of an aqueous phase in the deposits, this phase being stabilized by dissolved salts having high solubility. It then follows that for each salt, there is a critical relative humidity (calculated from the flue gas water partial pressure and the cooling surface temperature as is common practice among boiler engineers) for both the presence of the aqueous phase and the corrosion. Some critical single salts, ZnCl{sub 2} and CaCl{sub 2} have been identified, and they give critical 'relative humidities' of 5% and 18% respectively. These figures are a lower bound. The corresponding figure, derived from the practical experience and the reported plant operational data, is between 20 and 30%. Corrosion tests have been carried out by exposing an air-cooled probe in the flue gases at a 12 MW boiler at Saevelundsverket in Alingsaas, and the material wastage at different temperatures has been measured with a profilometer. The high corrosion rates were reproduced in the tests for high relative humidities. The corrosion rate was small and not measurable (<0.1 mm/year) for relative humidity <22%. The work shows by means of indirect evidence that the corrosion critical components are ZnCl{sub 2} and possibly CaCl{sub 2} as well. The practical engineering design criterion derived from the work is that the relative humidity (calculated from the flue

  19. Superheater corrosion in kraft recovery boilers; Korrosion hos oeverhettare i sodapannor. En oeversikt och diskussion

    Energy Technology Data Exchange (ETDEWEB)

    Bruno, F. [AaF-IPK, Stockholm (Sweden)

    1997-02-01

    Corrosion seems to be the most essential factor limiting the life and the availability of kraft recovery boilers. The steam temperature from the kraft recovery boiler has, seen from the view of electricity production and steam turbine operation, traditionally been kept moderate, especially in comparison with steam data from normal utility power plants. So the corrosion of the superheaters has been more a limitation for the temperature of the steam produced by the boiler than a life length limitation. Both the pressure and the temperature of the steam are limited by corrosion. The temperature of the boiling water, and hence the pressure, is limited by the corrosion in the lower furnace. The temperature of the steam is limited by the corrosion in the superheater. Kraft boiler superheater corrosion is here governed not only by the boiler design, but more by the mill chemistry and boiler operation practice. This report discusses the formation and the properties of the deposits and their relation to boiler operation and the corrosion of the superheater tube material. We have tried to understand the corrosion in the kraft boiler superheaters better by comparing with the experience from the utility boilers. 86 refs, 79 figs

  20. Hot Corrosion at Air-Ports in Kraft Recovery Boilers

    Energy Technology Data Exchange (ETDEWEB)

    Holcomb, Gordon R.; Covino, Bernard S., Jr.; Russell, James H.

    2003-01-01

    Hot corrosion can occur on the cold-side of airports in Kraft recovery boilers. The primary corrosion mechanism involves the migration of sodium hydroxide and potassium hydroxide vapors through leaks in the furnace wall at the airports and their subsequent condensation. It has been reported that stainless steel is attacked much faster than carbon steel in composite tubes, and that carbon steel tubing, when used with a low-chromium refractory, does not exhibit this type of corrosion. For hot corrosion fluxing of metal oxides, either acidic or basic fluxing takes place, with a solubility minimum at the basicity of transition between the two reactions. For stainless steel, if the basicity of the fused salt is between the iron and chromium oxide solubility minima, then a synergistic effect can occur that leads to rapid corrosion. The products of one reaction are the reactants of the other, which eliminates the need for rate-controlling diffusion. This effect can explain why stainless steel is attacked more readily than carbon steel.

  1. Ash formation, deposition, corrosion, and erosion in conventional boilers

    Energy Technology Data Exchange (ETDEWEB)

    Benson, S.A.; Jones, M.L. [Univ. of North Dakota, Grand Forks, ND (United States)

    1995-12-01

    The inorganic components (ash-forming species) associated with coals significantly affect boiler design, efficiency of operation, and lifetimes of boiler parts. During combustion in conventional pulverized fuel boilers, the inorganic components are transformed into inorganic gases, liquids, and solids. This partitioning depends upon the association of the inorganic components in the coal and combustion conditions. The inorganic components are associated as mineral grains and as organically associated elements, and these associations of inorganic components in the fuel directly influence their fate upon combustion. Combustion conditions, such as temperature and atmosphere, influence the volatility and the interaction of inorganic components during combustion and gas cooling, which influences the state and size composition distribution of the particulate and condensed ash species. The intermediate species are transported with the bulk gas flow through the combustion systems, during which time the gases and entrained ash are cooled. Deposition, corrosion, and erosion occur when the ash intermediate species are transported to the heat-transfer surface, react with the surface, accumulate, sinter, and develop strength. Research over the past decade has significantly advanced understanding of ash formation, deposition, corrosion, and erosion mechanisms. Many of the advances in understanding and predicting ash-related issues can be attributed to advanced analytical methods to determine the inorganic composition of fuels and the resulting ash materials. These new analytical techniques have been the key to elucidation of the mechanisms of ash formation and deposition. This information has been used to develop algorithms and computer models to predict the effects of ash on combustion system performance.

  2. Low-cost Evaporator Protection Method against Corrosion in a Pulverized Coal Fired Boiler

    OpenAIRE

    Arkadiusz Krzysztof Dyjakon; Przemysław Bukowski

    2010-01-01

    Corrosion processes appearing on the watertubes in a combustion chamber of pulverized coal-fired boilers require permanent control and service. Subject to the power plant strategy, different anti-corrosion protection methods can be applied. Technical-economical analysis has been performed to evaluate and support the decisions on maintenance and operation services. The paper presents and discusses results of the application of an air protection system in boiler OP-230 in view of anti-corrosion...

  3. Evaluation of iron aluminide weld overlays for erosion - corrosion resistant boiler tube coatings in low NO{sub x} boilers

    Energy Technology Data Exchange (ETDEWEB)

    DuPont, J.N.; Banovic, S.W.; Marder, A.R. [Lehigh Univ., Bethlehem, PA (United States)

    1996-08-01

    Low NOx burners are being installed in many fossil fired power plants in order to comply with new Clean Air Regulations. Due to the operating characteristics of these burners, boiler tube sulfidation corrosion is often enhanced and premature tube failures can occur. Failures due to oxidation and solid particle erosion are also a concern. A program was initiated in early 1996 to evaluate the use of iron aluminide weld overlays for erosion/corrosion protection of boiler tubes in Low NOx boilers. Composite iron/aluminum wires will be used with the Gas Metal Arc Welding (GMAW) process to prepare overlays on boiler tubes steels with aluminum contents from 8 to 16wt%. The weldability of the composite wires will be evaluated as a function of chemical composition and welding parameters. The effect of overlay composition on corrosion (oxidation and sulfidation) and solid particle erosion will also be evaluated. The laboratory studies will be complemented by field exposures of both iron aluminide weld overlays and co-extruded tubing under actual boiler conditions.

  4. Mitigating the Risk of Stress Corrosion of Austenitic Stainless Steels in Advanced Gas Cooled Reactor Boilers

    International Nuclear Information System (INIS)

    Advanced Gas-Cooled Reactors (AGRs) operated in the UK by EDF Energy have once-through boilers, which deliver superheated steam at high temperature (∼500 deg. C) and pressure (∼150 bar) to the HP turbine. The boilers have either a serpentine or helical geometry for the tubing of the main heat transfer sections of the boiler and each individual tube is fabricated from mild steel, 9%Cr1%Mo and Type 316 austenitic stainless steel tubing. Type 316 austenitic stainless steel is used for the secondary (final) superheater and steam tailpipe sections of the boiler, which, during normal operation, should operate under dry, superheated steam conditions. This is achieved by maintaining a specified margin of superheat at the upper transition joint (UTJ) between the 9%Cr1%Mo primary superheater and the Type 316 secondary superheater sections of the boiler. Operating in this mode should eliminate the possibility of stress corrosion cracking of the Type 316 tube material on-load. In recent years, however, AGRs have suffered a variety of operational problems with their boilers that have made it difficult to maintain the specified superheat margin at the UTJ. In the case of helical boilers, the combined effects of carbon deposition on the gas side and oxide deposition on the waterside of the tubing have resulted in an increasing number of austenitic tubes operating with less than the specified superheat margin at the UTJ and hence the possibility of wetting the austenitic section of the boiler. Some units with serpentine boilers have suffered creep-fatigue damage of the high temperature sections of the boiler, which currently necessitates capping the steam outlet temperature to prevent further damage. The reduction in steam outlet temperature has meant that there is an increased risk of operation with less than the specified superheat margin at the UTJ and hence stress corrosion cracking of the austenitic sections of the boiler. In order to establish the risk of stress

  5. High Temperature Corrosion Problem of Boiler Components in presence of Sulfur and Alkali based Fuels

    Science.gov (United States)

    Ghosh, Debashis; Mitra, Swapan Kumar

    2011-04-01

    Material degradation and ageing is of particular concern for fossil fuel fired power plant components. New techniques/approaches have been explored in recent years for Residual Life assessment of aged components and material degradation due to different damage mechanism like creep, fatigue, corrosion and erosion etc. Apart from the creep, the high temperature corrosion problem in a fossil fuel fired boiler is a matter of great concern if the fuel contains sulfur, chlorine sodium, potassium and vanadium etc. This paper discusses the material degradation due to high temperature corrosion in different critical components of boiler like water wall, superheater and reheater tubes and also remedial measures to avoid the premature failure. This paper also high lights the Residual Life Assessment (RLA) methodology of the components based on high temperature fireside corrosion. of different critical components of boiler.

  6. Development of Computational Capabilities to Predict the Corrosion Wastage of Boiler Tubes in Advanced Combustion Systems

    Energy Technology Data Exchange (ETDEWEB)

    Kung, Steven; Rapp, Robert

    2014-08-31

    A comprehensive corrosion research project consisting of pilot-scale combustion testing and long-term laboratory corrosion study has been successfully performed. A pilot-scale combustion facility available at Brigham Young University was selected and modified to enable burning of pulverized coals under the operating conditions typical for advanced coal-fired utility boilers. Eight United States (U.S.) coals were selected for this investigation, with the test conditions for all coals set to have the same heat input to the combustor. In addition, the air/fuel stoichiometric ratio was controlled so that staged combustion was established, with the stoichiometric ratio maintained at 0.85 in the burner zone and 1.15 in the burnout zone. The burner zone represented the lower furnace of utility boilers, while the burnout zone mimicked the upper furnace areas adjacent to the superheaters and reheaters. From this staged combustion, approximately 3% excess oxygen was attained in the combustion gas at the furnace outlet. During each of the pilot-scale combustion tests, extensive online measurements of the flue gas compositions were performed. In addition, deposit samples were collected at the same location for chemical analyses. Such extensive gas and deposit analyses enabled detailed characterization of the actual combustion environments existing at the lower furnace walls under reducing conditions and those adjacent to the superheaters and reheaters under oxidizing conditions in advanced U.S. coal-fired utility boilers. The gas and deposit compositions were then carefully simulated in a series of 1000-hour laboratory corrosion tests, in which the corrosion performances of different commercial candidate alloys and weld overlays were evaluated at various temperatures for advanced boiler systems. Results of this laboratory study led to significant improvement in understanding of the corrosion mechanisms operating on the furnace walls as well as superheaters and reheaters in

  7. Factors affecting stress assisted corrosion cracking of carbon steel under industrial boiler conditions

    Science.gov (United States)

    Yang, Dong

    Failure of carbon steel boiler tubes from waterside has been reported in the utility boilers and industrial boilers for a long time. In industrial boilers, most waterside tube cracks are found near heavy attachment welds on the outer surface and are typically blunt, with multiple bulbous features indicating a discontinuous growth. These types of tube failures are typically referred to as stress assisted corrosion (SAC). For recovery boilers in the pulp and paper industry, these failures are particularly important as any water leak inside the furnace can potentially lead to smelt-water explosion. Metal properties, environmental variables, and stress conditions are the major factors influencing SAC crack initation and propagation in carbon steel boiler tubes. Slow strain rate tests (SSRT) were conducted under boiler water conditions to study the effect of temperature, oxygen level, and stress conditions on crack initation and propagation on SA-210 carbon steel samples machined out of boiler tubes. Heat treatments were also performed to develop various grain size and carbon content on carbon steel samples, and SSRTs were conducted on these samples to examine the effect of microstructure features on SAC cracking. Mechanisms of SAC crack initation and propagation were proposed and validated based on interrupted slow strain tests (ISSRT). Water chemistry guidelines are provided to prevent SAC and fracture mechanics model is developed to predict SAC failure on industrial boiler tubes.

  8. Thermal Spray Coatings for High-Temperature Corrosion Protection in Biomass Co-Fired Boilers

    Science.gov (United States)

    Oksa, M.; Metsäjoki, J.; Kärki, J.

    2015-01-01

    There are over 1000 biomass boilers and about 500 plants using waste as fuel in Europe, and the numbers are increasing. Many of them encounter serious problems with high-temperature corrosion due to detrimental elements such as chlorides, alkali metals, and heavy metals. By HVOF spraying, it is possible to produce very dense and well-adhered coatings, which can be applied for corrosion protection of heat exchanger surfaces in biomass and waste-to-energy power plant boilers. Four HVOF coatings and one arc sprayed coating were exposed to actual biomass co-fired boiler conditions in superheater area with a probe measurement installation for 5900 h at 550 and 750 °C. The coating materials were Ni-Cr, IN625, Fe-Cr-W-Nb-Mo, and Ni-Cr-Ti. CJS and DJ Hybrid spray guns were used for HVOF spraying to compare the corrosion resistance of Ni-Cr coating structures. Reference materials were ferritic steel T92 and nickel super alloy A263. The circulating fluidized bed boiler burnt a mixture of wood, peat and coal. The coatings showed excellent corrosion resistance at 550 °C compared to the ferritic steel. At higher temperature, NiCr sprayed with CJS had the best corrosion resistance. IN625 was consumed almost completely during the exposure at 750 °C.

  9. Low-cost Evaporator Protection Method against Corrosion in a Pulverized Coal Fired Boiler

    Directory of Open Access Journals (Sweden)

    Arkadiusz Krzysztof Dyjakon

    2010-07-01

    Full Text Available Corrosion processes appearing on the watertubes in a combustion chamber of pulverized coal-fired boilers require permanent control and service. Subject to the power plant strategy, different anti-corrosion protection methods can be applied. Technical-economical analysis has been performed to evaluate and support the decisions on maintenance and operation services. The paper presents and discusses results of the application of an air protection system in boiler OP-230 in view of anti-corrosion measures. It is indicated that a low-cost protection method of watertubes (evaporator against corrosion can be efficient and lead to financial savings in comparison to the standard procedure of replacement of watertube panels.

  10. Influence of Deposit Formation on Corrosion at a Straw Fired boiler

    DEFF Research Database (Denmark)

    Hansen, Lone Aslaug; Michelsen, Hanne Philbert; Frandsen, Flemming; Dam-Johansen, Kim; Hørlyck, Steffen; Karlsson, Asger

    Straw-fired boilers generally experience severe problems with deposit formation and are expected to suffer from severe superheater corrosion at high steam temperatures due to the large alkali and chlorine content in straw. In this study, deposits collected (1) on air-cooled probes and (2) directly...... at the existing heat transfer surfaces of a straw-fired boiler have been examined. Deposits collected on air-cooled probes were found to consist of an inner layer of KCl and an outer layer of sintered fly ash. Ash deposits formed on the heat transfer surfaces all had a characteristic layered...... structure, with a dense layer of K2SO4 present adjacent to the metal surface. It is argued that the K2SO4 layer present adjacent to the metal surface may lead to reduced corrosion rates at this boiler. A discussion of the deposit structure, the K2SO4 layer formation mechanism, and the influence of the inner...

  11. Corrosion behaviour of boiler tube materials during combustion of fuels containing Zn and Pb

    Energy Technology Data Exchange (ETDEWEB)

    Bankiewicz, D.

    2012-11-01

    Many power plants burning challenging fuels such as waste-derived fuels experience failures of the superheaters and/or increased waterwall corrosion due to aggressive fuel components already at low temperatures. To minimize corrosion problems in waste-fired boilers, the steam temperature is currently kept at a relatively low level which drastically limits power production efficiency. The elements found in deposits of waste and waste-derived fuels burning boilers that are most frequently associated with high-temperature corrosion are: Cl, S, and there are also indications of Br; alkali metals, mainly K and Na, and heavy metals such as Pb and Zn. The low steam pressure and temperature in waste-fired boilers also influence the temperature of the waterwall steel which is nowadays kept in the range of 300 deg C - 400 deg C. Alkali chloride (KCl, NaCl) induced high-temperature corrosion has not been reported to be particularly relevant at such low material temperatures, but the presence of Zn and Pb compounds in the deposits have been found to induce corrosion already in the 300 deg C - 400 deg C temperature range. Upon combustion, Zn and Pb may react with Cl and S to form chlorides and sulphates in the flue gases. These specific heavy metal compounds are of special concern due to the formation of low melting salt mixtures. These low melting, gaseous or solid compounds are entrained in the flue gases and may stick or condense on colder surfaces of furnace walls and superheaters when passing the convective parts of the boiler, thereby forming an aggressive deposit. A deposit rich in heavy metal (Zn, Pb) chlorides and sulphates increases the risk for corrosion which can be additionally enhanced by the presence of a molten phase. The objective of this study was to obtain better insight into high-temperature corrosion induced by Zn and Pb and to estimate the behaviour and resistance of some boiler superheater and waterwall materials in environments rich in those heavy metals

  12. Operation corrosion test of austenitic steel bends for supercritical coal boilers

    Directory of Open Access Journals (Sweden)

    Cizner J.

    2016-03-01

    Full Text Available Corrosion tests of both annealed and not annealed bends of HR3C and S304H steels in operation conditions of black and brown coal combustion boilers in EPRU and EDE. After a long-term exposure, the samples were assessed gravimetrically and metallographically. The comparison of annealed and unannealed states showed higher corrosion rates in the annealed state; corrosion of the sample surface did not essentially differ for compression and tensile parts of the beams. Detailed assessment of both steels is described in detail in this study.

  13. Corrosion in waste-fired boilers: A thermodynamic study

    DEFF Research Database (Denmark)

    Becidan, Michael; Sørum, Lars; Frandsen, Flemming;

    2009-01-01

    A twofold study using thermodynamic equilibrium calculations was carried out to study corrosion in MSW incinerators. Corrosion was associated with the amount of alkalis and trace metals gaseous chlorides. Firstly, a two-level factorial experimental design combined with a data analysis were used t...... corrosion-fighting additives (ammonium sulphate and silica) was investigated. Calculations confirmed experimental results and brought further insight on differentiated results for Na, K, Pb and Zn but also on capture mechanisms.......A twofold study using thermodynamic equilibrium calculations was carried out to study corrosion in MSW incinerators. Corrosion was associated with the amount of alkalis and trace metals gaseous chlorides. Firstly, a two-level factorial experimental design combined with a data analysis were used to...

  14. Furnace Wall Corrosion in a Wood-fired Boiler

    OpenAIRE

    Alipour, Yousef

    2015-01-01

    The use of renewable wood-based fuel has been increasing in the last few decades because it is said to be carbon neutral. However, wood-based fuel, and especially used wood (also known as recycled wood or waste wood), is more corrosive than virgin wood (forest fuel), because of higher amounts of chlorine and heavy metals. These elements increase the corrosion problems at the furnace walls where the oxygen level is low. Corrosion mechanisms are usually investigated at the superheaters where th...

  15. Superheater Corrosion In Biomass Boilers: Today's Science and Technology

    Energy Technology Data Exchange (ETDEWEB)

    Sharp, William (Sandy) [SharpConsultant

    2011-12-01

    This report broadens a previous review of published literature on corrosion of recovery boiler superheater tube materials to consider the performance of candidate materials at temperatures near the deposit melting temperature in advanced boilers firing coal, wood-based fuels, and waste materials as well as in gas turbine environments. Discussions of corrosion mechanisms focus on the reactions in fly ash deposits and combustion gases that can give corrosive materials access to the surface of a superheater tube. Setting the steam temperature of a biomass boiler is a compromise between wasting fuel energy, risking pluggage that will shut the unit down, and creating conditions that will cause rapid corrosion on the superheater tubes and replacement expenses. The most important corrosive species in biomass superheater corrosion are chlorine compounds and the most corrosion resistant alloys are typically FeCrNi alloys containing 20-28% Cr. Although most of these materials contain many other additional additions, there is no coherent theory of the alloying required to resist the combination of high temperature salt deposits and flue gases that are found in biomass boiler superheaters that may cause degradation of superheater tubes. After depletion of chromium by chromate formation or chromic acid volatilization exceeds a critical amount, the protective scale gives way to a thick layer of Fe{sub 2}O{sub 3} over an unprotective (FeCrNi){sub 3}O{sub 4} spinel. This oxide is not protective and can be penetrated by chlorine species that cause further acceleration of the corrosion rate by a mechanism called active oxidation. Active oxidation, cited as the cause of most biomass superheater corrosion under chloride ash deposits, does not occur in the absence of these alkali salts when the chloride is present as HCl gas. Although a deposit is more corrosive at temperatures where it is molten than at temperatures where it is frozen, increasing superheater tube temperatures through

  16. Formation of corrosion products protecting surfaces of the boiler proper tubes from the combustion chamber

    OpenAIRE

    Pietrzyk, M.; S. Król

    2007-01-01

    Purpose: The aim of this paper is to determine how the oxidation product layer of the steel applied for the radiant tubes should increase if we are going to obtain the lowest possible corrosion losses.Design/methodology/approach: Boiler tubes, made of 13CrMo4-5 steel were subjected to tests. In the boiler BP-1150, the tubes ø 30 x 5 mm are joined by fins and form a membrane shield. According to the maps of tube wall thickness, in the zone of the highest heat load, sectors of the shield were s...

  17. Untypical bromine corrosion in boilers co-firing biomass

    OpenAIRE

    A. Hernas; Chmiela, B.; B. Szczucka-Lasota

    2012-01-01

    Purpose: The aim of this study was to determine the untypical corrosion resistance of rotary air preheaters in a biomass co-fired power plant.Design/methodology/approach: The selected results of some components of regenerative rotary air preheaters in a biomass co-fired power plant are presented. The macro and microstructure of corroded components of a LUVO preheater after 3 years of service are presented. The chemical composition of corrosion products was determined by X-ray microanalysis.Fi...

  18. High-Temperature Corrosion of Protective Coatings for Boiler Tubes in Thermal Power Plants

    Institute of Scientific and Technical Information of China (English)

    XU Lianyong; JING Hongyang; HUO Lixing

    2005-01-01

    High-temperature corrosion is a serious problem for the water-wall tubes of boilers used in thermal power plants. Oxidation, sulfidation and molten salt corrosion are main corrosion ways.Thereinto, the most severe corrosion occurs in molten salt corrosion environment. Materials rich in oxides formers, such as chromium and aluminum, are needed to resist corrosion in high-temperature and corrosive environment, but processability of such bulk alloys is very limited. High velocity electric arc spraying (HVAS) technology is adopted to produce coatings with high corrosion resistance. By comparison, NiCr (Ni-45Cr-4Ti) is recommended as a promising alloy coating for the water-wall tubes, which can even resist molten salt corrosion attack. In the study of corrosion mechanism, the modern material analysis methods, such as scanning electron microscopy (SEM), X-ray diffractometry (XRD) and energy dispersive spectrometry (EDS), are used. It is found that the corrosion resistances of NiCr and FeCrAI coatings are much better than that of 20g steel, that the NiCr coatings have the best anti-corrosion properties, and that the NiCr coatings have slightly lower pores than FeCrAI coatings.It is testified that corrosion resistance of coatings is mainly determined by chromium content, and the microstructure of a coating is as important as the chemical composition of the material. In addition, the fracture mechanisms of coatings in the cycle of heating and cooling are put forward. The difference of the thermal physical properties between coatings and base metals results in the thermal stress inside the coatings. Consequently, the coatings spall from the base metal.

  19. Corrosion probes for fireside monitoring in coal-fired boilers

    Energy Technology Data Exchange (ETDEWEB)

    Covino, Bernard S., Jr.; Bullard, Sophie J.; Cramer, Stephen D.; Holcomb, Gordon R.; Ziomek-Moroz, Margaret; Eden, David A. (Intercorr International Inc.); Cayard, Michael S. (Intercorr International Inc.)

    2004-01-01

    Electrochemical corrosion rate (ECR) probes were constructed and exposed along with mass loss coupons in a N2/O2/CO2/H2O environment to determine ECR probe operating characteristics. Temperatures ranged from 450 to 600 C and both ECR probes and mass loss coupons were coated with ash. Results are presented in terms of the probe response to temperature, the measured zero baseline, and the quantitative nature of the probes. The effect of Stern-Geary constant and the choice of electrochemical technique used to measure the corrosion rate are also discussed. ECR probe corrosion rates were a function of time, temperature, and process environment and were found to be quantitative for some test conditions. Measured Stern-Geary constants averaged 0.0141 V/decade and the linear polarization technique was found to be more quantitative than the electrochemical noise technique.

  20. Application of High Temperature Corrosion-Resistant Materials and Coatings Under Severe Corrosive Environment in Waste-to-Energy Boilers

    Science.gov (United States)

    Kawahara, Yuuzou

    2007-06-01

    Corrosion-resistant materials (CRMs) and coatings are key technologies to increase power generation efficiency and reduce maintenance in waste-to-energy (WTE) plants. Corrosion environment became severe as steam temperatures have increased. The steam condition of more than 400 °C/3.9 MPa became possible in WTE boilers by using highly durable corrosion-resistant coatings, such as thermal spray of Al/80Ni20Cr alloy, HVOF-sprayed NiCrSiB alloy, Alloy 625 weld overlay for waterwall tubes and also superheater tubes. Also, the use of 310S type stainless steels and high Cr-high Mo-Ni base and high Si-Cr-Ni-Fe alloys have progressed because of a better understanding of corrosion mechanisms. Furthermore, high durability coatings using cermet and ceramic materials were applied to high temperature superheaters. This paper describes the major developments and the application of CRMs and coating technologies in the last 30 years in WTE plants, the corrosion mechanisms of alloys, the deterioration mechanisms of spray coating layers, and future subjects for the development of corrosion-resistant materials and coatings.

  1. Release of Corrosive Species above the Grate in a Waste Boiler and the Implication for Improved Electrical Efficiency

    DEFF Research Database (Denmark)

    Bøjer, Martin; Jensen, Peter Arendt; Dam-Johansen, Kim;

    2010-01-01

    A relatively low electrical efficiency of 20−25% is obtained in typical west European waste boilers. Ash species released from the grate combustion zone form boiler deposits with high concentrations of Cl, Na, K, Zn, Pb, and S that cause corrosion of superheater tubes at high temperature. The...... superheater steam temperature has to be limited to around 425 °C, and thereby, the electrical efficiency remains low compared to wood or coal-fired boilers. If a separate part of the flue gas from the grate has a low content of corrosive species, it may be used to superheat steam to a higher temperature, and...

  2. Low temperature corrosion in bark fuelled, small boilers; Laagtemperaturkorrosion i barkeldade, mindre pannor

    Energy Technology Data Exchange (ETDEWEB)

    Lindau, Leif; Goldschmidt, Barbara [Sycon Energikonsult AB, Malmoe (Sweden)

    2002-04-01

    A number of small (3-12 MW), new biofuel boiler plants in South Sweden, and (at least) in Austria, have suffered a high (wastage of mm/yrs.) corrosion rate on the low temperature boiler side. This problem has been investigated with respect to its occurrence and its character by contacts with operators, by plant inspections, and by analysis of cold side deposits. The plants affected have low feed water temperatures (< 100 deg C ). The plants fire most types of Swedish biofuel: chips, bark, hog fuel, and 'GROT'(=twigs and tops). The results found give basis for a hypothesis that the corrosion results from the presence of an aqueous phase in the deposits, this phase being stabilized by dissolved salts having high solubility. It then follows that for each salt, there is a critical relative humidity (calculated from the flue gas water partial pressure and the cooling surface temperature as is common practice among boiler engineers) for both the presence of the aqueous phase and the corrosion. Some critical single salts, ZnC12 and CaC12 have been identified, and they give critical 'relative humidities' of 5% and 18% respectively. These figures are a lower bound. The corresponding figure, derived from the practical experience and the reported plant operational data, is between 20 and 30%. Corrosion tests have been carried out by exposing an air-cooled probe in the fluegases at a 12 MW boiler at Saevelundsverket in Alingsaas, and the material wastage at different temperatures has been measured with a profilometer. The high corrosion rates were reproduced in the tests for high relative humidities. The corrosion rate was small and not measurable (<0.1 mm/yr) for relative humidity < 22%. The work shows by means of indirect evidence that the corrosion critical components are ZnCl{sub 2} and possibly CaCl{sub 2} as well. The practical engineering design criterion derived from the work is that the relative humidity (calculated from the flue gas water partial

  3. Application of an empirical model in CFD simulations to predict the local high temperature corrosion potential in biomass fired boilers

    International Nuclear Information System (INIS)

    To gain reliable data for the development of an empirical model for the prediction of the local high temperature corrosion potential in biomass fired boilers, online corrosion probe measurements have been carried out. The measurements have been performed in a specially designed fixed bed/drop tube reactor in order to simulate a superheater boiler tube under well-controlled conditions. The investigated boiler steel 13CrMo4-5 is commonly used as steel for superheater tube bundles in biomass fired boilers. Within the test runs the flue gas temperature at the corrosion probe has been varied between 625 °C and 880 °C, while the steel temperature has been varied between 450 °C and 550 °C to simulate typical current and future live steam temperatures of biomass fired steam boilers. To investigate the dependence on the flue gas velocity, variations from 2 m·s−1 to 8 m·s−1 have been considered. The empirical model developed fits the measured data sufficiently well. Therefore, the model has been applied within a Computational Fluid Dynamics (CFD) simulation of flue gas flow and heat transfer to estimate the local corrosion potential of a wood chips fired 38 MW steam boiler. Additionally to the actual state analysis two further simulations have been carried out to investigate the influence of enhanced steam temperatures and a change of the flow direction of the final superheater tube bundle from parallel to counter-flow on the local corrosion potential. - Highlights: • Online corrosion probe measurements in a fixed bed/drop tube reactor. • Development of an empirical corrosion model. • Application of the model in a CFD simulation of flow and heat transfer. • Variation of boundary conditions and their effects on the corrosion potential

  4. Erosion–corrosion behaviour of Ni-based superalloy Superni-75 in the real service environment of the boiler

    Indian Academy of Sciences (India)

    T S Sidhu; S Prakash; R D Agrawal; Ramesh Bhagat

    2009-04-01

    The super-heater and re-heater tubes of the boilers used in thermal power plants are subjected to unacceptable levels of surface degradation by the combined effect of erosion–corrosion mechanism, resulting in the tube wall thinning and premature failure. The nickel-based superalloys can be used as boiler tube materials to increase the service life of the boilers, especially for the new generation tra-supercritical boilers. The aim of the present investigation is to evaluate the erosion–corrosion behaviour of Ni-based superalloy Superni-75 in the real service environment of the coal-fired boiler of a thermal power plant. The cyclic experimental study was performed for 1000 h in the platen superheater zone of the coal-fired boiler where the temperature was around 900°C. The corrosion products have been characterized with respect to surface morphology, phase composition and element concentration using the combined techniques of X-ray diffractometry (XRD), scanning electron microscopy/energy-dispersive analysis (SEM/EDAX) and electron probe micro analyser (EPMA). The Superni-75 performed well in the coal-fired boiler environment, which has been attributed mainly to the formation of a thick band of chromium in scale due to selective oxidation of the chromium.

  5. Thermal Nondestructive Characterization of Corrosion in Boiler Tubes by Application fo a Moving Line Heat Source

    Science.gov (United States)

    Cramer, K. Elliott; Winfree, William P.

    2000-01-01

    Wall thinning in utility boiler waterwall tubing is a significant inspection concern for boiler operators. Historically, conventional ultrasonics has been used lor inspection of these tubes. This technique has proved to be very labor intensive and slow. This has resulted in a "spot check" approach to inspections, making thickness measurements over a relatively small percentage of the total boiler wall area. NASA Langley Research Center has developed a thermal NDE technique designed to image and quantitatively characterize the amount of material thinning present in steel tubing. The technique involves the movement of a thermal line source across the outer surface of the tubing followed by an infrared imager at a fixed distance behind the line source. Quantitative images of the material loss due to corrosion are reconstructed from measurements of the induced surface temperature variations. This paper will present a discussion of the development of the thermal imaging system as well as the techniques used to reconstruct images of flaws. The application of the thermal line source, coupled with this analysis technique, represents a significant improvement in the inspection speed for large structures such as boiler waterwalls while still providing high-resolution thickness measurements. A theoretical basis for the technique will be presented thus demonstrating the quantitative nature of the technique. Further, results of laboratory experiments on flat Panel specimens with fabricated material loss regions will be presented.

  6. Cracking and Corrosion of Composite Tubes in Black Liquor Recovery Boiler Primary Air Ports

    Energy Technology Data Exchange (ETDEWEB)

    Keiser, James R.; Singbeil, Douglas L.; Sarma, Gorti B.; Kish, Joseph R.; Yuan, Jerry; Frederick, Laurie A.; Choudhury, Kimberly A.; Gorog, J. Peter; Jetté, Francois R.; Hubbard, Camden R.; Swindeman, Robert W.; Singh, Prett M.; Maziasz, Phillip J.

    2006-10-01

    Black liquor recovery boilers are an essential part of kraft mills. Their design and operating procedures have changed over time with the goal of providing improved boiler performance. These performance improvements are frequently associated with an increase in heat flux and/or operating temperature with a subsequent increase in the demand on structural materials associated with operation at higher temperatures and/or in more corrosive environments. Improvements in structural materials have therefore been required. In most cases the alternate materials have provided acceptable solutions. However, in some cases the alternate materials have solved the original problem but introduced new issues. This report addresses the performance of materials in the tubes forming primary air port openings and, particularly, the problems associated with use of stainless steel clad carbon steel tubes and the solutions that have been identified.

  7. Formation of corrosion products protecting surfaces of the boiler proper tubes from the combustion chamber

    Directory of Open Access Journals (Sweden)

    M. Pietrzyk

    2007-04-01

    Full Text Available Purpose: The aim of this paper is to determine how the oxidation product layer of the steel applied for the radiant tubes should increase if we are going to obtain the lowest possible corrosion losses.Design/methodology/approach: Boiler tubes, made of 13CrMo4-5 steel were subjected to tests. In the boiler BP-1150, the tubes ø 30 x 5 mm are joined by fins and form a membrane shield. According to the maps of tube wall thickness, in the zone of the highest heat load, sectors of the shield were sampled in the places where the tube wall thickness was equal or greater than 4.3 mm, i.e. the minimum calculation thickness, according to the specifications given by the boiler manufacturer. It means that the corrosive loss could be determined as small, in spite of a long operation time (more than 60,000 hours.Findings: The authors have determined structure and chemical and phase compositions of products and deposits forming in the radiant tubes in the regions of low corrosive losses after long-lasting operation (up to 60,000 hours. Then, they discussed a mechanism of formation of a compact layer protecting a steel surface against excessive oxidation under combustion gases.Practical implications: The layer on the tubes with small losses of wall thickness are characterized by the following properties: good compactness, very good adhesion to the metallic base, low amount of sulfur, especially in magnetite, no aggressive components at the phase boundary product – steel, small development of the phase boundary product-steel. Owing to those properties, even presence of sulfur in the products do not reduce their passivation qualities.Originality/value: Determination of the oxidation product layer of the steel applied for the radiant tubes.

  8. Development of Erosion-Corrosion-Resistant Cold-Spray Nanostructured Ni-20Cr Coating for Coal-Fired Boiler Applications

    Science.gov (United States)

    Kumar, M.; Singh, H.; Singh, N.; Chavan, N. M.; Kumar, S.; Joshi, S. V.

    2015-12-01

    The erosion-corrosion (E-C) behavior of a cold-spray nanostructured Ni-20Cr coating was studied under cyclic conditions in a coal-fired boiler. This study was done for 15 cycles (1500 h), in which each cycle comprised 100 h of heating in the boiler environment, followed by 1 h of cooling under ambient air conditions. The E-C extent was evaluated in terms of thickness loss data of the samples. The eroded-corroded samples were characterized using XRD, SEM/EDS, and x-ray mapping analyses. The nanostructured coating offered excellent E-C protection to boiler tube material (SA 516 steel) under harsh live conditions of the boiler. This E-C resistance offered by investigated coating may be attributed to the presence of protective NiO and Cr2O3 phases in its oxide scale and its superior as-sprayed microhardness.

  9. High temperature corrosion in a biomass-fired power boiler : Reducing furnace wall corrosion in a waste wood-fired power plant with advanced steam data

    OpenAIRE

    Alipour, Yousef

    2013-01-01

    The use of waste (or recycled) wood as a fuel in heat and power stations is becoming more widespread in Sweden (and Europe), because it is CO2 neutral with a lower cost than forest fuel. However, it is a heterogeneous fuel with a high amount of chlorine, alkali and heavy metals which causes more corrosion than fossil fuels or forest fuel. A part of the boiler which is subjected to a high corrosion risk is the furnace wall (or waterwall) which is formed of tubes welded together. Waterwalls are...

  10. Hot Corrosion Behaviour of Detonation Gun Sprayed Stellite-6 and Stellite-21 Coating on Boiler Steel SAE 431 at 900°C

    OpenAIRE

    N. K. Mishra; Rai, A K; S. B. Mishra; Kumar, R.

    2014-01-01

    Hot corrosion is the serious problem in gas turbines, superheaters, and economizers of coal-fired boilers. It occurs due to the usage of wide range of fuels such as coal, oil, and so on at the elevated temperatures. Protective coatings on boiler steels are used under such environments. In the present investigation, Stellite-6 and Stellite-21 coatings have been deposited on boiler steel SAE 431 by detonation gun method. The hot corrosion performance of Stellite-6 and Stellite-21 coated as well...

  11. Corrosion/erosion detection of boiler tubes utilizing pulsed infrared imaging

    Science.gov (United States)

    Bales, Maurice J.; Bishop, Chip C.

    1995-05-01

    This paper discusses a new technique for locating and detecting wall thickness reduction in boiler tubes caused by erosion/corrosion. Traditional means for this type of defect detection utilizes ultrasonics (UT) to perform a point by point measurement at given intervals of the tube length, which requires extensive and costly shutdown or `outage' time to complete the inspection, and has led to thin areas going undetected simply because they were located in between the sampling points. Pulsed infrared imaging (PII) can provide nearly 100% inspection of the tubes in a fraction of the time needed for UT. The IR system and heat source used in this study do not require any special access or fixed scaffolding, and can be remotely operated from a distance of up to 100 feet. This technique has been tried experimentally in a laboratory environment and verified in an actual field application. Since PII is a non-contact technique, considerable time and cost savings should be realized as well as the ability to predict failures rather than repairing them once they have occurred.

  12. Investigation and analysis of high temperature corrosion and degradation of marine boiler combustion swirler

    Science.gov (United States)

    Virdi, R. S.; Thakur, D. G.

    2016-03-01

    The present paper investigated and analyzed swirler material consisting of mild steel which was subjected to service for the period of one year in a 30 MW marine boiler. Due to the presence of high temperatures in the furnace coupled with the corrosive marine environment swirler material showed accelerated degradation and material wastage. An investigation into the feasibility of manufacturing the existing swirler with an alternate material or coating the swirler material with a thermal barrier coating was undertaken. Based on their properties and performance, SS 304 and SS 316 were proposed as the replacement materials for the swirler. The other alternative of coating the existing swirlers with a form thermal barrier coating to observe for any improvement in their performance at elevated temperatures was also tested. Stellite, which is a Ni-Co based coating, was carried out on the MS samples and the same were exposed to same temperatures mentioned above. The performance of the available options was evaluated with respect to the grain structure of the material, the hardness value of the materials and deterioration at elevated temperatures. Investigation showed the proposed materials/coatings like SS 304, SS 316 and Stellite coating revealed that SS 316 is the material best suited for high temperature application.

  13. Hot Corrosion Studies of HVOF-Sprayed Coating on T-91 Boiler Tube Steel at Different Operating Temperatures

    Science.gov (United States)

    Bhatia, Rakesh; Singh, Hazoor; Sidhu, Buta Singh

    2013-11-01

    The aim of the present work is to investigate the usefulness of high velocity oxy fuel-sprayed 75% Cr3C2-25% (Ni-20Cr) coating to control hot corrosion of T-91 boiler tube steel at different operating temperatures viz 550, 700, and 850 °C. The deposited coatings on the substrates exhibit nearly uniform, adherent and dense microstructure with porosity less than 2%. Thermogravimetry technique is used to study the high temperature hot corrosion behavior of uncoated and coated samples. The corrosion products of the coating on the substrate are analyzed by using XRD, SEM, and FE-SEM/EDAX to reveal their microstructural and compositional features for the corrosion mechanisms. It is found that the coated specimens have shown minimum weight gain at all the operating temperatures when compared with uncoated T-91 samples. Hence, coating is effective in decreasing the corrosion rate in the given molten salt environment. Oxides and spinels of nickel-chromium may be the reason for successful resistance against hot corrosion.

  14. Engineering development of advanced coal-fired low emission boiler systems. First quarterly report, FY94, January 1994--March 1994

    Energy Technology Data Exchange (ETDEWEB)

    1994-08-01

    The major task during this quarter was testing and evaluation of the 25 MBtu/hr Toroidal Vortex Combustor (TVC) at Textron Defense Systems`` (TDS) Haverhill laboratories. The tests were completed and the results are being evaluated along with other scale up and integration issues. The preliminary conclusion is that the NOx performance and current design uncertainties do not justify the development risk within the Low Emission Boiler System (LEBS) timetable. Further program effort will focus on advanced U-firing arrangements. The second major effort during the period was the engineering development of the moving bed copper oxide system for SOx/NOx control. Through application of a DOE-developed model and the team`s engineering analysis, significant progress was made on developing an improved process design. Work began on a small scale test of the moving bed concept under realistic temperature and dust loading conditions. Work continued through the quarter on finalizing the Preliminary Engineering Design, Design Deficiency Analysis, and Research, Development, and Test Plan. The Design and Development Report containing these three deliverables was released in March. Sargent & Lundy printed and distributed the report to team members, as well as to the advisory panelists. The advisory panel numbers approximately fifteen organizations as of the end of the period.

  15. Problems of corrosion of the exterior heating surfaces of steam boilers which use fuel oil as fuel

    Energy Technology Data Exchange (ETDEWEB)

    Braconi, P.; Gianni, C.

    1983-01-01

    The intensity of formation of deposits on the heating surfaces of steam boilers with their operation on fuel oil is basically determined by the physicalcarry away characteristics and the speed of the flue gases. An autectic is formed in the pipes of the PP which includes sodium sulfate (Na20 with V204 with 5V203). H2SO3 and H2SO4 are contained in the zone of the convective sheafs, and the VE and VP deposits. Low temperature or high temperature corrosion (K) forms on the metal of the pipes as a result of the chemical effect of the deposits. The process of oxidation of SO2 into SO3 in flue gases is examined, along with the effect of its corrosion products and the vanadium oxides contained in the deposits and the concentration of O2 in the flue gases. With an increase in the SO3 concentration the dew point rises. A graphic dependence of the corrosion speed of the metal on the concentration of the SO3 in the flue gases, the temperature of the pipe wall and the air excess is cited.

  16. Deposition and High-Temperature Corrosion in Biomass-Fired Boilers

    DEFF Research Database (Denmark)

    Michelsen, Hanne Philbert

    boiler steel under conditions similar to straw-fired boilers. A characteristic layer of potassium sulfate and iron oxide was found adjacent to the metal oxide layers on all the metal test elements covered with a deposit containing KCl. The layer had a characteristic structure with iron oxide threads in...... deposits mainly as potassium chloride in straw-fired boilers. If large amounts of sulfur are present in the system, the composition of the condensed potassium salts changes in favor of more potassium sulfate. This phenomenon was observed when straw was co-fired with oil at the Kyndby Power Station and when...... where iron and chromium in the metal react with gaseous chlorine forming volatile metal chlorides. The high partial pressure of chlorine close to the metal is believed to be caused by a rapid sulfation of KCl to K2SO4 in a melt formed adjacent to the metal surface. This mechanism can explain the shift...

  17. Hot Corrosion Behaviour of Detonation Gun Sprayed Stellite-6 and Stellite-21 Coating on Boiler Steel SAE 431 at 900°C

    Directory of Open Access Journals (Sweden)

    N. K. Mishra

    2014-01-01

    Full Text Available Hot corrosion is the serious problem in gas turbines, superheaters, and economizers of coal-fired boilers. It occurs due to the usage of wide range of fuels such as coal, oil, and so on at the elevated temperatures. Protective coatings on boiler steels are used under such environments. In the present investigation, Stellite-6 and Stellite-21 coatings have been deposited on boiler steel SAE 431 by detonation gun method. The hot corrosion performance of Stellite-6 and Stellite-21 coated as well as uncoated SAE 431 steel has been evaluated in aggressive environment of Na2SO4-82%Fe2(SO43 under cyclic conditions at an elevated temperature of 900°C for total duration of 50 cycles. Thermogravimetric technique was used to approximate the kinetics of hot corrosion. Stellite-6 coating imparted better hot corrosion resistance than Stellite-21 coating in the given environment. Scanning electron microscopy was used to characterize the surface of hot corrosion products.

  18. High temperature corrosion in biomass- and waste fired boilers. A status report; Kunskapslaeget betraeffande hoegtemperaturkorrosion i aangpannor foer biobraensle och avfall

    Energy Technology Data Exchange (ETDEWEB)

    Henderson, P.; Ifwer, K.; Staalenheim, A.; Montgomery, M.; Hoegberg, J.; Hjoernhede, A.

    2006-12-15

    Many biomass- or waste-fired plants have problems with high temperature corrosion on the furnace walls or at the superheaters, especially if the steam temperature is greater than 500 deg C. An increase in the combustion of waste fuels means that an increasing number of boilers have had problems. Therefore, there is great interest from plant owners to reduce the costs associated with high temperature corrosion. At the same time there exists a considerable driving force towards improving the electrical efficiency of a plant by the use of more advanced steam data. The purpose of the work presented here was to answer three main questions: What can be done to reduce high temperature corrosion with current fuel blends and steam temperatures? How can more waste fuels be burnt without an increased risk for corrosion? What needs to be done to reach higher steam temperatures in the future? The level of knowledge of high temperature corrosion in biomass- and waste-fired boilers has been described and summarised. The following measures are recommended to reduce corrosion in existing plant: Make sure that the fuel is well mixed and improve fuel feeding to obtain a more even spread of the fuel over the cross-section of the boiler. Use combustion technology methods to stabilize the oxygen content of the flue gases near the membrane walls and other heat transfer surfaces. Experiment with additives and/or supplementary fuels which contain sulphur in some form, for example peat. Reduce the flue gas temperature at the superheaters. Review soot-blowing procedures or protect heat transfer surfaces from soot blowers. Evaluate coated membrane wall panels in parts of the furnace that experience the worst corrosion. Test more highly alloyed steels suitable for superheaters and when replacing a superheater change to a more highly alloyed steel. For the future, the following should be considered: The role of sulphur needs to be investigated more and other additives should be investigated

  19. Increased Lifetime for Biomass and Waste to Energy Power Plant Boilers with HVOF Coatings: High Temperature Corrosion Testing Under Chlorine-Containing Molten Salt

    Science.gov (United States)

    Oksa, Maria; Tuurna, Satu; Varis, Tommi

    2013-06-01

    Heat exchanger surfaces of waste to energy and biomass power plant boilers experience often severe corrosion due to very aggressive components in the used fuels. High velocity oxy-fuel (HVOF) coatings offer excellent protection for boiler tubes against high temperature corrosion due to their high density and good adherence to the substrate material. Several thermal spray coatings with high chromium content were sprayed with HVOF technique. Their mechanical properties and high temperature corrosion resistance were tested and analyzed. The coating materials included NiCr, IN625, Ni-21Cr-10W-9Mo-4Cu, and iron-based partly amorphous alloy SHS9172 (Fe-25Cr-15W-12Nb-6Mo). High temperature corrosion testing was performed in NaCl-KCl-Na2SO4 salt with controlled H2O atmosphere at 575 and 625 °C. The corrosion test results of the coatings were compared to corrosion resistance of tube materials (X20, Alloy 263 and Sanicro 25).

  20. quarters

    Directory of Open Access Journals (Sweden)

    Elena Grigoryeva

    2016-12-01

    Full Text Available Are there many words combining both space and time? A quarter is one of such rare words: it means both a part of the city space and a period of the year. A regular city has parts bordered by four streets. For example, Chita is a city with an absolutely orthogonal historical center. This Utopian city was designed by Decembrists in the depth of Siberian ore-mines (120. The 130 Quarter in Irkutsk is irregular from its inception because of its triangular form. Located between two roads, the forked quarter was initially bordered by flows along the west-east axis – the main direction of the country. That is why it appreciated the gift for the 350 anniversary of its transit existence – a promenade for an unhurried flow of pedestrians. The quarter manages this flow quite well, while overcoming the difficulties of new existence and gathering myths (102. Arousing many expectations, the “Irkutsk’s Quarters” project continues the theme that was begun by the 130 Quarter and involved regeneration, revival and search for Genius Loci and the key to each single quarter (74. Beaded on the trading axis, these shabby and unfriendly quarters full of rubbish should be transformed for the good of inhabitants, guests and the small business. The triptych by Lidin, Rappaport and Nevlyutov is about happiness of urbanship and cities for people, too (58. The City Community Forum was also devoted to the urban theme (114. Going through the last quarter of the year, we hope that Irkutsk will keep to the right policy, so that in the near future the wooden downtown quarters will become its pride, and the design, construction and investment complexes will join in desire to increase the number of comfortable and lively quarters in our city. The Baikal Beam will get one more landmark: the Smart School (22 for Irkutsk’s children, including orphans, will be built in several years on the bank of Chertugeevsky Bay.

  1. Boiler and steam-generator corrosion. January 1970-May 1989 (Citations from the NTIS data base). Report for January 1970-May 1989

    International Nuclear Information System (INIS)

    This bibliography contains citations concerning corrosion effects, mechanisms, detection, and inhibition in fossil-fuel fired boilers and nuclear-powered steam generators. Corrosion studies performed on the water side and hot gas side of heat exchanger tubes and support structures are presented. Water treatment, chemical cleaning, and descaling methods are considered. Although emphasis is placed on large-scale power generation systems, residential and commercial heating systems are also discussed. (This updated bibliography contains 308 citations, 20 of which are new entries to the previous edition.)

  2. Experimental study and mechanism analysis on low temperature corrosion of coal fired boiler heating surface

    International Nuclear Information System (INIS)

    The low temperature corrosion experiment was made to investigate the phenomena and mechanism in the process of the flue gas deep-cooling. The experiment tube was installed in the flue gas channel between the air preheater and the electrostatic precipitator in the power plant. The scanning electron microscope (SEM), energy spectrum analysis and X-ray diffraction (XRD) experiment were used to the analysis of the ash samples obtained from the outer wall of experiment tube under the different tube wall temperature. By contrasting energy spectrum figures and XRD figures among different ash samples, it has been found that the sulfuric acid corrosion occurred on the surface of the experiment tube under the temperature ranging from 65 °C to 71 °C and the corrosion was caused by SO2 and water vapor under the temperature ranging from 41 °C to 47 °C in the certain types of coal conditions. The wall temperature range was proposed which low temperature heating surface would be capable of long-term operation for the experiment unit. The analysis also showed that the ash particles would gather together under the impact of physical chemistry in the course of deep-cooling flue gas for heat recovery and efficiency gain. - Highlights: • The phenomena and mechanism of the low temperature corrosion was analyzed. • The SEM and XRD methods were used to analysis ash samples. • The ash particles would gather together in the course of deep-cooling flue gas. • The experiment tube occurred severe sulfuric acid corrosion in the specific wall temperature range

  3. Study on the corrosion inhibition characteristic of HEDP in industrial boiler water%工业锅炉炉水中HEDP缓蚀特性研究

    Institute of Scientific and Technical Information of China (English)

    朱志平; 李茂东; 金鹏; 袁汉涛; 邹志超; 黄先军

    2014-01-01

    Using electrochemical impedance spectroscopy and Tafel polarization method in simulated boiler water medium of the low pressure industrial boiler,the HEDP corrosion inhibition capacity for 20 # carbon steel has been studied. The effects of Ca2+,Cl-and SO42-in boiler water on the corrosion inhibition capacity of HEDP are discussed. The results show that when 25 mg/L of HEDP is added to the stimulated boiler water medium,the best corrosion in-hibition result can be obtained. he inhibition effect of HEDP on carbon steel is mainly in anode betatopic reaction. HEDP is a kind of corrosion inhibitor mainly used for inhibiting anode. The presence of Ca2+in boiler water can af-fect the polarization process of carbon steel electrode by HEDP. The erosive anions,such as Cl-and SO42-etc. can in-tensify the corrosion and have negative effect on HEDP corrosion inhibiting capacity.%使用电化学阻抗法及Tafel极化法在模拟低压工业锅炉炉水介质中研究了HEDP对20#碳钢的缓蚀性能,并探讨了炉水中Ca2+、Cl-以及SO42-对HEDP缓蚀性能的影响。实验结果表明:在模拟炉水介质中,当HEDP投加量为25 mg/L时,其对碳钢具有最佳的缓蚀效果;HEDP对碳钢腐蚀的抑制主要作用于阳极失电子反应,HEDP是一种以抑制阳极为主的缓蚀剂;炉水中Ca2+的存在会影响HEDP对碳钢电极的极化过程;Cl-、SO42-等侵蚀性阴离子会促进腐蚀的加剧,影响HEDP的缓蚀性能。

  4. The erosion-corrosion of boiler inlet ferrule assemblies: Part 4

    International Nuclear Information System (INIS)

    Results are given for four experiments carried out on the CERL Isothermal Rig aimed at defining the temperature and flow dependency of erosion-corrosion at pH 9.30 and 9.50. At pH 9.50 it was found that the flow dependency for the maximum rate in the post-orifice region was relatively low, Vsup(1.08) to Vsup(1.34), and showed only a small variation with temperature, the dependency tending to increase with increasing temperature. This behaviour differs from that seen at pH 9.04 where a higher flow dependency and a greater variation with temperature was seen. An assessment of the available data indicates that the flow dependency falls significantly as pH rises from 9.0 to 9.3, but that thereafter there is little further change up to pH 9.65. The temperature dependency at pH 9.50 gave a peak in the erosion-corrosion rate at about 1350C, the position of which moved to higher temperatures with increasing rates. Compared with the data at pH 9.04, the temperature maxima occurred at higher temperatures at equivalent erosion-corrosion rates. A comparison of the data at pH 9.04 and 9.50 shows that there is no unique pH dependency for erosion-corrosion under the conditions tested. At 1150C an almost constant pH dependency was found, but at higher temperatures there was a marked variation in pH dependency with flow. For 100% MCR conditions at 1490C, the present data are consistent with those obtained in early Isothermal Rig experiments. (author)

  5. Relations between combustion, deposition, flue gas temperatures and corrosion in straw-fired boilers

    DEFF Research Database (Denmark)

    Montgomery, Melanie

    2004-01-01

    ABSTRACT: Additives trials in three different plants, Sønderborg waste incineration plant and Ensted woodchip and straw firing boiler, are described. Both aluminium silicate containing additives and ammonium sulphate was tested. At Sønderborg, there was a drastic decrease in Cl deposition when...... using an aluminium silicate additive, however the relative chlorine content of the deposits was unchanged. At Ensted woodchip plant, a dosage level of additives was reached which reduced the chlorine flux. For straw firing where the chlorine level in the fuel is higher and the fuel load is greater, the...... chlorine flux on deposition probes was not affected by additive dosage. An indication that some chlorine had been removed could be measured by the increased HCl output during additive dosage. The importance of temperature and where the additive is dosed is discussed....

  6. Sewage sludge as additive to reduce the initial fireside corrosion caused by combustion of shredder residues in a waste-fired BFB boiler

    Energy Technology Data Exchange (ETDEWEB)

    Jonsson, T.; Pettersson, J.; Johansson, L.G.; Svensson, J.E. [Chalmers Univ. of Technology, Goeteborg (Sweden). Environmental Inorganic Chemistry; Davidsson, K. [SP Technical Research Institute of Sweden, Boraas (Sweden)

    2010-07-01

    Corrosion/deposition field tests have been carried out in a commercial waste-fired BFB boiler using air-cooled probes. The influence of 20% shredder light fraction (SLF), from recovery of metal scrap material, mixed with waste was studied at different material temperatures (280-420 C). In addition, 3% sewage sludge was added to the 20% SLF/waste mixture. The initial deposit and corrosion products were compared to when the normal waste (municipal solid waste and industrial wastes) fuel was used. After 24 hours exposure, the deposits were analyzed as for elemental composition while the corrosion products were characterised by ESEM/EDX and XRD. The results show that combustion of 20% SLF increased the amount of deposition, which in addition contains a larger fraction chlorine. This causes a higher initial corrosion rate. Adding 3% sewage sludge removes the effect of the SLF and deposits and corrosion products were comparable with the ones formed during the reference exposure. The results indicate that the initial fireside corrosion is chlorine induced and no signs of low-melting heavy metals salts were observed in the corrosion products. (orig.)

  7. Stress Corrosion Cracking of SA-543 High-Strength Steel in All-Volatile Treatment Boiler Feed Water

    Science.gov (United States)

    Rihan, R.; Basha, M.; Al-Meshari, A.; Bayramov, A.; van Zyl, G.; Dafalla, H.; Mohamed, A. I.

    2015-10-01

    Susceptibility of SA-543 steel, its welds (with and without stress relief treatment), and the heat-affected zone (HAZ) to stress corrosion cracking (SCC) was investigated in de-aerated and aerated boiler feed water subjected to the all-volatile treatment (AVT-BFW), and distilled water at 275 °C using the slow strain rate testing (SSRT) technique. The SSRT specimens were tested at three extension rates (3.50 × 10-6, 9.00 × 10-6, and 7.50 × 10-5 mm/s) using a novel SCC testing rig capable of testing at high temperatures and pressures. There are no significant differences in the time-to-failure among the four tested specimens. The elongation of the specimens at the time of failure is in the range of 10-23%. The reduction of the cross-sectional area of the failed specimens is large (45-77%) and the absence of any signs of intergranular propagation in fractured specimens, determined by scanning electron microscopy, indicates that the failure is due to mechanical load and not due to SCC. Dissolved oxygen does not affect the susceptibility of the specimens to SCC, which could be due to the inhibition effect of the test solution. SA-543 steel as the base metal, its welds (with and without stress relief treatment), and the HAZ are suitable for use in hot AVT-BFW and distilled water.

  8. A Study of the Effect of Kaolin as a Fuel Oil Additive on the Corrosion Inhibition of Fireside Superheater Boiler Tubes

    Directory of Open Access Journals (Sweden)

    Alaa' Mshjel Ali

    2010-01-01

    Full Text Available The objective of the present study is to determine the effect of Kaolin as a fuel oil additive to minimize the fireside corrosion of superheater boiler tubes of ASTM designation (A213-T22 by increasing the melting point of the formed slag on the outside tubes surface, through the formation of new compounds with protective properties to the metal surface. The study included measuring corrosion rates at different temperatures with and without additive use with various periods of time, through crucible test method and weight loss technique.A mathematical model represents the relation between corrosion rate and the studied variables, is obtained using statistical regression analysis. Using this model, the best additive to ash weight ratio was specified. Then scanning electron microscopic images taken to the two treated and untreated samples with additive to study the difference in nature of slag formed on the metal surface to the two cases.

  9. Comparative High-Temperature Corrosion Behavior of Ni-20Cr Coatings on T22 Boiler Steel Produced by HVOF, D-Gun, and Cold Spraying

    Science.gov (United States)

    Kaushal, Gagandeep; Bala, Niraj; Kaur, Narinder; Singh, Harpreet; Prakash, Satya

    2014-01-01

    To protect materials from surface degradations such as wear, corrosion, and thermal flux, a wide variety of materials can be deposited on the materials by several spraying processes. This paper examines and compares the microstructure and high-temperature corrosion of Ni-20Cr coatings deposited on T22 boiler steel by high velocity oxy-fuel (HVOF), detonation gun spray, and cold spraying techniques. The coatings' microstructural features were characterized by means of XRD and FE-SEM/EDS analyses. Based upon the results of mass gain, XRD, and FE-SEM/EDS analyses it may be concluded that the Ni-20Cr coating sprayed by all the three techniques was effective in reducing the corrosion rate of the steel. Among the three coatings, D-gun spray coating proved to be better than HVOF-spray and cold-spray coatings.

  10. NOx Control Options and Integration for US Coal Fired Boilers

    Energy Technology Data Exchange (ETDEWEB)

    Mike Bockelie; Kevin Davis; Temi Linjewile; Connie Senior; Eric Eddings; Kevin Whitty; Larry Baxter; Calvin Bartholomew; William Hecker; Stan Harding; Robert Hurt

    2003-12-31

    This is the fourteenth Quarterly Technical Report for DOE Cooperative Agreement No: DEFC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. Using the initial CFD baseline modeling of the Gavin Station and the plant corrosion maps, six boiler locations for the corrosion probes were identified and access ports have been installed. Preliminary corrosion data obtained appear consistent and believable. In situ, spectroscopic experiments at BYU reported in part last quarter were completed. New reactor tubes have been made for BYU's CCR that allow for testing smaller amounts of catalyst and thus increasing space velocity; monolith catalysts have been cut and a small reactor that can accommodate these pieces for testing is in its final stages of construction. A poisoning study on Ca-poisoned catalysts was begun this quarter. A possible site for a biomass co-firing test of the slipstream reactor was visited this quarter. The slipstream reactor at Rockport required repair and refurbishment, and will be re-started in the next quarter. This report describes the final results of an experimental project at Brown University on the fundamentals of ammonia / fly ash interactions with relevance to the operation of advanced NOx control technologies such as selective catalytic reduction. The Brown task focused on the measurement of ammonia adsorption isotherms on commercial fly ash samples subjected to a variety of treatments and on the chemistry of dry and semi-dry ammonia removal processes.

  11. Superheater corrosion in biomass boiler - theories and tests in Vaestermalmsverket, Falun; Oeverhettarkorrosion i bioeldad panna - teorier och prov i Vaestermalmsverket, Falun

    Energy Technology Data Exchange (ETDEWEB)

    Roennquist, Eva-Marie

    2000-10-01

    It has lately been evident that a number of biomass-fired plants are experiencing major problems with corrosion of their superheaters. The major aim with this project is to contribute with increased knowledge in this area. The efforts to build up experience around different materials applicable for superheaters with high steam data is of great importance for future plants in Sweden. The main objective for 'Vaermeforsk' has been to transfer the experiences from this investigation to other boilers or plants with different types of fuel. This investigation has therefore been focused on the verification of SYCON's assumptions regarding the roles of chloride and alkali and the possibility of influencing/minimising superheater corrosion by optimisation of the fuel mix. Another important part was to verify that the boiler design, as such, does not create an unfavourable environment for the superheaters by producing reducing zones due to plume formation. Based on the above, the investigation has been divided into three loosely connected parts. (1) The role and reaction by chlorides in the deposits on a superheater, (2) Reducing environment - plume formation of non-combusted fuel, and (3) Choice of materials in the superheater. Serious corrosion has been detected in the superheater tubes of 'Vaestermalmsverket' in Falun. The material temperature was below 530 deg C. No serious inhomogeneous combustion problems or areas with reducing environments have been detected. The corrosion was therefore judged to be caused by alkali chlorides which condense on the superheater tubes. Tests with minor amounts of sulphur added to the biomass fuel have been shown to suppress the generation of alkali chlorides and their condensation on the superheater surfaces. A good correlation between calculated and measured values have been achieved. Very low corrosion rates have been measured on the test probes, constructed with different superheater material and placed in the

  12. Development of high strength and high corrosion resistance 23Cr-18Ni-3Cu-1.5W steel tubes for boilers; Boiler yo kokyodo kotaishoku 23Cr-18Ni-3Cu-1.5W kokan no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Senba, H.; Sawaragi, Y.; Yamadera, Y.; Igarashi, M. [Sumitomo Metal Industries, Ltd., Osaka (Japan)

    1998-06-15

    An austenitic steel 23Cr-18Ni-3Cu-1.5W-0.4Nb-0.2N tube (SAVE25) is developed, high in strength and corrosion resistance, intended for use singly under the ultimate steam conditions (650degC and 350atm) for ultra supercritical power plants. This steel exhibits a high creep rupture strength, thanks to precipitation strengthened by a Cu-rich phase and carbon nitrides and to solid solution strengthened by texture-stabilizing W and N, and exhibits an estimated rupture strength of 91MPa after 10{sup 5}h at 700degC, equivalent to that of the high-Ni, high-W alloy HR6W (23Cr-43Ni-6W-Ti, Nb). Furthermore, its steam oxidation resistance and high-temperature corrosion resistance are so high as to be comparable to those of the HR3C (25Cr-20Ni-0.4Nb-0.25N). As for weldability, the SAVE25 is equal or superior to the TP347H which is widely used for boilers. New welding consumables are also under development, using the same alloy as the parent alloy, which produce welded joints which are equal to the parent alloy in terms of strength and corrosion resistance. This steel tube is already installed on service boilers for performance evaluation, and it is believed that the new steel tube will greatly contribute to the embodiment of ultra supercritical power plants. 11 refs., 19 figs., 2 tabs.

  13. NOx CONTROL OPTIONS AND INTEGRATION FOR US COAL FIRED BOILERS

    Energy Technology Data Exchange (ETDEWEB)

    Mike Bockelie; Marc Cremer; Kevin Davis; Bob Hurt; Eric Eddings

    2001-01-31

    This is the second Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for firing US coals. The focus of our efforts during the last three months have been on: (1) Completion of a long term field test for Rich Reagent Injection (RRI) at the Conectiv BL England Station Unit No.1, a 130 MW Cyclone fired boiler; (2) Extending our Computational Fluid Dynamics (CFD) based NOx model to accommodate the chemistry for RRI in PC fired boilers; (3) Design improvements and calibration tests of the corrosion probe; and (4) Investigations on ammonia adsorption mechanisms and removal processes for Fly Ash.

  14. Corrosion

    Science.gov (United States)

    Slabaugh, W. H.

    1974-01-01

    Presents some materials for use in demonstration and experimentation of corrosion processes, including corrosion stimulation and inhibition. Indicates that basic concepts of electrochemistry, crystal structure, and kinetics can be extended to practical chemistry through corrosion explanation. (CC)

  15. Engineering development of advanced coal-fired low emission boiler systems. Fourth quarterly technical progress report, July 1993--September 1993

    Energy Technology Data Exchange (ETDEWEB)

    1993-12-31

    The LEBS plant design will be based on a high-sulfur Illinois No. 6 coal. This coal meets program selection requirements of extensive reserves and production, sulfur content, and representativeness. Two alternate test coals have been selected to examine fuel effects, and to broaden the range of application of the technology being developed. The alternate coals are a medium sulfur, Pittsburgh No. 8 bituminous, and a Wyoming subbituminous coal. The efficiency goals for the LEBS are challenging, particularly with the demands environmental controls are likely to place on auxiliary power. Table 1 shows estimates of overall plant efficiencies for three steam cycles: (1) a 2400 psi subcritical single reheat cycle typical of current plants; (2) a 3500 psi supercritical single reheat cycle; and (3) an advanced 4500 psi double reheat cycle. The plant heat rates are based on maximum boiler efficiency and minimum auxiliary power requirements consistent with conventional plant design for the design and alternate coals. The aggressive efficiency goals clearly require advanced steam conditions, as well as careful management of any added auxiliary power requirements for environmental controls. The EPRI SOAPP (State-of-the-Art Power Plant) project has selected the 4500 psi cycle as maximizing plant efficiency while minimizing generating costs for a commercial plant to be constructed by the year 2000. This program will incorporate the SOAPP base case cycle. The LESS design will incorporate a high-efficiency, once-through boiler design known as the Benson. Significant improvements in availability and operating flexibility have made this boiler design the system of choice for European power generation over the last fifteen years.

  16. Corrosion Behavior of TP316L of Superheater in Biomass Boiler with Simulated Atmosphere and Deposit%TP316L在模拟生物质锅炉过热器气相和积灰条件下的腐蚀特性

    Institute of Scientific and Technical Information of China (English)

    印佳敏; 吴占松

    2009-01-01

    Corrosion behavior of TP316L was investigated with simulated atmosphere and ash deposition for the superheater in biomass boiler. Corrosion dynamic curves were plotted by mass gain. The results showed that the corrosion was dependent on temperature and was greatly accelerated by ash deposition. The mass gain was distinctly reduced in the presence of SO_2 with and without ash deposition on the specimens. Corrosion rates with ash deposit at different temperatures were calculated. Two feasible methods were provided to avoid serious high-temperature corrosion in the biomass boiler.

  17. 处理后的油田污水对热采锅炉20G腐蚀性的研究%CORROSIVITY OF TREATED WASTEWATER ON STEEL 20GOF BOILER FOR THERMAL PRODUCTION WELL IN OIL FIELD

    Institute of Scientific and Technical Information of China (English)

    温建萍; 李文戈; 李海; 张乃峰; 温涛

    2001-01-01

    The corrosion behavior of steel 20G in wastewater treatment system has been investigated by means of the weight loss test combining with optical microscope、SEM and XPS etc..The results show that the corrosion of boiler steel 20G in wastewater,which has been treated,is serious with obvious feature of pitting corrosion.Therefore,the treated wastewater should be excluded from futher use for boiler for thermal production well in oil field.%通过现场挂片试验,应用光学显微镜、扫描电镜、X射线能谱分析方法研究了20G材料在油田污水中的腐蚀性.结果表明,处理后的污水对高温高压锅炉材料的腐蚀严重,不能用于热采锅炉.

  18. Hot Corrosion Behaviour of Type 316 Stainless Steel Tubes used in Reheaters and Superheaters of Oil-Fired Boilers

    International Nuclear Information System (INIS)

    High temperature corrosion behaviour of commercial type 316 stainless steel tubes has been studied in the presence of Na2 SO4 and NaCl at temperature ranged from 500 to 800 degree C. Tubes of different diameters ranging from 8 to 25 mm and thickness ranging from 1.9 to 4.3 mm were used in the study. The aggressive environment was 1 N Na2 SO4 + 1 N NaCl and vanadium compound was added as ammonium meta vanadate in some tests. corrosion kinetics based on weight change vs. Time measurements and microstructural analysis were used to determine the mode of corrosion attack and nature of the formed scales. As a result of the study it was found that the spilling increases as the temperature increases and led to weight loss, also the addition of vanadium to the solution caused a sharp increase in weight i.e. high corrosion rate, for all diameters. 11 Figs

  19. Development of Self-Powered Wireless-Ready High Temperature Electrochemical Sensors for In-Situ Corrosion Monitoring for Boiler Tubes in Next Generation Coal-based Power Systems

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Xingbo [West Virginia Univ., Morgantown, WV (United States)

    2015-06-30

    The key innovation of this project is the synergy of the high temperature sensor technology based on the science of electrochemical measurement and state-of-the-art wireless communication technology. A novel self-powered wireless high temperature electrochemical sensor system has been developed for coal-fired boilers used for power generation. An initial prototype of the in-situ sensor demonstrated the capability of the wireless communication system in the laboratory and in a pilot plant (Industrial USC Boiler Setting) environment to acquire electrochemical potential and current signals during the corrosion process. Uniform and localized under-coal ash deposit corrosion behavior of Inconel 740 superalloy has been studied at different simulated coal ash hot corrosion environments using the developed sensor. Two typical potential noise patterns were found to correlate with the oxidation and sulfidation stages in the hot coal ash corrosion process. Two characteristic current noise patterns indicate the extent of the corrosion. There was a good correlation between the responses of electrochemical test data and the results from corroded surface analysis. Wireless electrochemical potential and current noise signals from a simulated coal ash hot corrosion process were concurrently transmitted and recorded. The results from the performance evaluation of the sensor confirm a high accuracy in the thermodynamic and kinetic response represented by the electrochemical noise and impedance test data.

  20. 油田热电厂注汽锅炉炉管腐蚀因素分析与控制措施%Corrosion Factors Analysis and Control Measures of Boiler Tubes in Steam In?jection Boiler in the Oilfield

    Institute of Scientific and Technical Information of China (English)

    周登印

    2016-01-01

    The steam injection boiler furnace tube of Daqing oilfield thermal power plant is in high temperature, high pressure and other harsh environmental conditions. The corrosion types are mainly alkali corrosion,dissolved oxygen corrosion,cavitation erosion,steam wa-ter corrosion and stop furnace corrosion. The corrosion factors produced by the medium mainly include temperature, flow rate and water treatment quality. The dissolved oxygen in the oxygen, and the boiler water in the steam injection boiler furnace, that have accelerated the corrosion rate of the furnace tubes. On the basis of corrosion factors targeted research, from the control of boiler feed water quality, reduce boiler oxygen exposure probability and improve the furnace pipe anti-corrosion properties of the essence, four aspects:the use of science and technology,and puts forward the corresponding control measures,aiming to de-lay and reduce the corrosion of all aspects, to prevent corrosion of the probability of more than 99.9%. By controlling the water quality of boiler and reducing the chance of contact with oxygen,the corrosion of boiler tubes is reduced.%大庆油田热电厂注汽锅炉炉管处于高温、高压的恶劣环境工况,腐蚀严重,其腐蚀类型主要为碱腐蚀、溶解氧腐蚀、气蚀、汽水腐蚀和停炉腐蚀.由介质产生的腐蚀因素主要有温度、流速及水处理质量;注汽锅炉炉管中存在的氧气以及锅炉水中溶解的氧加速了炉管腐蚀速率.为延缓腐蚀并减小腐蚀程度,提出以下对应的控制措施:严把水质源头管控,杜绝出现不达标水质进入锅炉;完善运行参数,防止超温、超压环境出现;将多种除氧方法结合使用,以达到最佳除氧效果.停炉后采用TH901法在炉管表面形成保护膜以隔离氧气,该保护法加药量少,成本低,阻止腐蚀的概率达到99.9%以上.通过控制锅炉给水水质,减少锅炉接触氧几率等措施,减缓了注汽锅炉炉管的腐蚀.

  1. High-Temperature Erosion-Corrosion Performance of High-Velocity Oxy-Fuel Sprayed Ni-20 Cr Coating in Actual Boiler Environment

    Science.gov (United States)

    Kaushal, G.; Singh, H.; Prakash, S.

    2011-07-01

    The high-velocity oxy-fuel (HVOF) spray technique was used to deposit Ni-20Cr coating on a commonly used boiler steel ASTM A213 347H. The specimens with and without coating were exposed to the super heater zone of a thermal power plant boiler at a temperature of 973 K (700 °C) under cyclic conditions to ascertain their erosion-corrosion (E-C) behavior. High-temperature oxidation behavior of the specimens was also evaluated under cyclic thermal loading conditions at an elevated temperature of 1173 K (900 °C). Mass change data and thickness loss were measured to formulate the kinetics of E-C/oxidation for the specimens. The exposed specimens were characterized by X-ray diffraction (XRD) and field emission-scanning electron microscopy/energy dispersive spectroscopy (FE-SEM/EDS). The uncoated steel suffered higher E-C in comparison with its coated counterpart in terms of mass loss as well as thickness loss. It was observed that overall mass loss was reduced by 31 pct and thickness loss by 44 pct after the application of the coating. The possible formation of Cr2O3 phase in the coated substrate may be suggested to contribute to better E-C behavior. During air oxidation exposures, the coating was found to be intact with only marginal spallation of its oxide scales, which is an indicator of good adhesion between the coating and substrate steel. The air oxidation mass change data indicated that the coating enhanced the oxidation resistance of the steel by 85 pct.

  2. 锅炉水汽系统一、二次网腐蚀问题的分析与解决%Analysis and solution examples for the first and second network corrosion of boiler water gas system

    Institute of Scientific and Technical Information of China (English)

    肖强; 沈晓东

    2012-01-01

    锅炉的“红水问题”是由于炉水对锅炉本体及系统设备的腐蚀造成的,其不仅会使凝结水无法回用,造成大量的补充水和能源的损失,还会对锅炉本身、后续相关系统的设备造成损坏,甚至对相关操作人员的安全都造成威胁.从一次网和二次网的腐蚀原因入手,通过分析分别找到各自系统存在的问题,提出解决方案,现场应用时收到了良好的效果.%The "red water" problem of boilers is caused by the corrosion effect of the boiler water on the boiler body and the equipment of the system. Because of the corrosion, the condensation water cannot be reused, which results in the great loss to make-up water and energy. The corrosion also damages the boiler as well as the follow-up system equipment, or even threatens the safety of the related operating personnel. Starting from the mechanism of the first and second network corrosion, and by way of analysis, the problems in each system have been found out, and solutions which were put forward and applied to worksites have received good effects.

  3. Evaluation of MELTGUARD{sup TM} - a measuring system for control of fireside corrosion in boilers; Utvaerdering av MELTGUARD{sup TM} - ett maetsystem foer kontroll av roekgassidig korrosion i pannor

    Energy Technology Data Exchange (ETDEWEB)

    Henderson, Pamela [Vattenfall Utveckling AB, Stockholm (Sweden)

    2001-10-01

    Studsvik AB has developed and now owns the patent for a product called MELTGUARD. According to information from Studsvik, Meltguard is a measuring probe that shows in real-time how much corrosion is occurring and that can reduce costs and increase the lifetime of power boilers burning biomass. The product consists of a tubular air-cooled probe which is exposed in the flue gas through an existing inspection port. The electrodes in the probe react with the flue gas and ash deposit and corrosion is registered as the short-circuited corrosion current (using the zero resistance method) between rings made of the investigated material. The aim of the project was to independently evaluate Meltguard, compare it with a conventional corrosion probe and to publish the results for the Swedish thermal power industry. Two steels have been compared on the probes (a Meltguard-probe can accommodate a maximum of two test pieces), with about the same temperature. Measurements have been carried out with the steels SS2218 (T22) and Esshete 1250 on a Meltguard probe in the biomass fired boiler at Naessjoe combined heat and power plant during the period November 2000 to March 2001. For a 48 hour period sulphur was added to the fuel supply to change the fuel chemistry and influence the corrosion rate. The corrosion current for SS2218 was unstable, fluctuating considerably throughout the measuring period, and was greatly affected by soot-blowing. Usually, soot-blowing resulted in a marked decrease in the corrosion current. No simple or clear relationship between the boiler load and the average corrosion current could be determined. The corrosion current for Esshete 1250 was mostly stable, about 20{mu}A. The current for SS2218 was a little higher than that for E1250, but the relationship between current and corrosion rate was unclear. It was obviously not a linear function as the corrosion measured in 2218, when the testing was completed, was approximately four times greater than that in E

  4. Corrosion/95 conference papers

    International Nuclear Information System (INIS)

    The papers in this conference represent the latest technological advances in corrosion control and prevention. The following subject areas are covered: cathodic protection in natural waters; materials for fossil fuel combustion and conversion systems; modern problems in atmospheric corrosion; innovative ideas for controlling the decaying infrastructure; deposits and their effects on corrosion in industry; volatile high temperature and non aqueous corrosion inhibitors; corrosion of light-weight and precoated metals for automotive application; refining industry corrosion; corrosion in pulp and paper industry; arctic/cold weather corrosion; materials selection for waste incinerators and associated equipment; corrosion measurement technology; environmental cracking of materials; advancing technology in the coating industry; corrosion in gas treating; green inhibition; recent advances in corrosion control of rail equipment; velocity effects and erosion corrosion in oil and gas production; marine corrosion; corrosion of materials in nuclear systems; underground corrosion control; corrosion in potable and industrial water systems in buildings and its impact on environmental compliance; deposit related boiler tube failures; boiler systems monitoring and control; recent developments and experiences in reactive metals; microbiologically influenced corrosion; corrosion and corrosion control for steel reinforced concrete; international symposium on the use of 12 and 13 Cr stainless steels in oil and gas production environments; subsea corrosion /erosion monitoring in production facilities; fiberglass reinforced pipe and tubulars in oilfield service; corrosion control technology in power transmission and distribution; mechanisms and methods of scale and deposit control; closing the loop -- results oriented cooling system monitoring and control; and minimization of aqueous discharge

  5. Evaluation of surrogate boilers for steam generators. Final report

    International Nuclear Information System (INIS)

    Corrosion in PWR systems is a continuing problem that can result in significant expenditures for inspection, repair, and replacement of steam generators as well as for power replacement during outages. Model boilers operated in parallel to the steam generator may provide a useful tool for monitoring and studying steam generator corrosion and corrosion prevention processes. The potential benefits of such boilers as well as several conceptual boiler design alternatives are described, and approximate costs for fabrication and operation of such systems are presented

  6. 锅炉设备碱性腐蚀原因分析及水处理工艺改进%Analysis on the causes of boiler equipment alkaline corrosion and improvements on water treatment process

    Institute of Scientific and Technical Information of China (English)

    肖强; 霍文敏; 陆明

    2013-01-01

    锅炉的碱性腐蚀经常被人们所忽视,但其造成的后果往往是非常严重的,轻则造成爆管导致停产,重则会威胁到操作人员的人身安全.传统的锅炉水处理方法虽然价格低廉,但其存在先天的不足,在一定条件下无法阻止碱性腐蚀的发生.而近些年逐渐产生的锅炉水处理工艺及与其配套的有机锅炉水处理药剂则全方面改进了传统锅炉水处理方法的不足,并在现场应用中收到了良好的效果.%The problem of boiler equipment alkaline corrosion has always been neglected,resulting in serious consequence.It causes the burst of pipes leading to suspending operations,or threaten the safety of the operation staff.Although the price for traditional water treatment process is low,it has congenitally deficiency.It can not prevent the happening of alkaline corrosion under certain conditions.However,nowadays,some new boiler water treatment processes and organic boiler water treatment agents that go with the process can improve the deficiency of traditional boiler water treatment methods.It has been used in field application and received good effects.

  7. 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Technical progress report, second quarter 1994, April 1994--June 1994

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-09-01

    This quarterly report discusses the technical progress of an Innovative Clean Coal Technology (ICCT) demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from coal-fired boilers. The project is being conducted at Georgia Power Company`s Plant Hammond Unit 4 located near Rome, Georgia. The primary goal of this project is the characterization of the low NOx combustion equipment through the collection and analysis of long-term emissions data. A target of achieving fifty percent NOx reduction using combustion modifications has been established for the project. The project provides a stepwise retrofit of an advanced overfire air (AOFA) system followed by low NOx burners (LNB). During each test phase of the project, diagnostic, performance, long-term, and verification testing will be performed. These tests are used to quantify the NOx reductions of each technology and evaluate the effects of those reductions on other combustion parameters. Results are described.

  8. NOx CONTROL OPTIONS AND INTEGRATION FOR US COAL FIRED BOILERS

    International Nuclear Information System (INIS)

    This is the seventh Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. This program contains multiple tasks and good progress is being made on all fronts. A series of field tests for RRI at the Ameren Sioux Unit No.1 have demonstrated that RRI can provide up to 30% NOx reduction over the use of over fire air in large scale (480MW) cyclone fired utility boilers. The field tests and modeling results are in good agreement. Final data analysis has been completed for tests performed at Eastlake Power Station of a real-time waterwall corrosion monitoring system. The tests demonstrated that corrosion could be measured accurately in real-time in normal boiler operations, and an assessment of waterwall wastage could be made without impacting boiler availability. Detailed measurements of soot volume fraction have been performed for a coal burner in a pilot scale test furnace. The measured values are in good agreement with the expected trends for soot generation and destruction. Catalysts from four commercial manufacturers have been ordered and one of the samples was received this quarter. Several in situ analyses of vanadium-based SCR catalyst systems were completed at BYU. Results to date indicate that the system produces results that represent improvements compared to literature examples of similar experiments. Construction of the catalyst characterization system (CCS) reactor is nearly complete, with a few remaining details discussed in this report. A literature review originally commissioned from other parties is being updated and will be made available under separate cover as part of this investigation. Fabrication of the multi-catalyst slipstream

  9. Innovative Clean Coal Technology (ICCT): 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Technical progress report, fourth quarter 1991

    Energy Technology Data Exchange (ETDEWEB)

    1992-04-21

    This quarterly report discusses the technical progress of an Innovative Clean Coal Technology (ICCT) demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. The project is being conducted at Georgia Power Company`s Plant Hammond Unit 4 located near Rome, Georgia. The primary goal of this project is the characterization of the low NO{sub x} combustion equipment through the collection and analysis of long-term emissions data. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project. The project provides a stepwise retrofit of an advanced overfire air (AOFA) system followed by low NO{sub x} burners (LNB). During each test phase of the project, diagnostic, performance, long-term, and verification testing will be performed. These tests are used to quantify the NO{sub x} reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as parameters such as particulate characteristics and boiler efficiency.

  10. Experimental Study on Under-deposit Corrosion of Water Wall Tube in a 420t Utility Boiler%一台420t电站锅炉水冷壁管垢下腐蚀试验研究

    Institute of Scientific and Technical Information of China (English)

    李勇; 赵彦杰; 欧俊

    2015-01-01

    在对某电厂一台420t电站锅炉检验过程中,发现该锅炉水冷壁管存在结垢现象,水冷壁管垢下腐蚀会对锅炉的安全、经济运行造成影响。通过均匀腐蚀失效试验、氢脆腐蚀失效试验确定其腐蚀原理,并对其腐蚀速率进行了研究。%There were two under-deposit corrosion forming causes, uniform corrosion and hydrogen corrosion. In the inspection of a 420t/h utility boiler, scaling was found in its water wall tube leading to the temperature difference between different sides of water wall tube. The safety and economy will be affected. Through theory and experiment, corrosion mechanism and prevention measures were presented in this paper.

  11. Innovative Clean Coal Technology (ICCT): 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Technical progress report: First quarter 1993

    Energy Technology Data Exchange (ETDEWEB)

    1993-12-31

    This quarterly report discusses the technical progress of an Innovative Clean Coal Technology (ICCT) demonstration being conducted at Georgia Power Company`s Plant Hammond Unit 4 located near Rome, Georgia. The primary goal of this project is the characterization of the low NO{sub x} combustion equipment through the collection and analysis of long-term emissions data. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project. The project provides a stepwise retrofit of an advanced overfire air (AOFA) system followed by low NO{sub x} burners (LNB). During each test phase of the project, diagnostic, performance, long-term, and verification testing will be performed. These tests are used to quantify the NO{sub x} reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency. During this quarter, long-term testing of the LNB + AOFA configuration continued and no parametric testing was performed. Further full-load optimization of the LNB + AOFA system began on March 30, 1993. Following completion of this optimization, comprehensive testing in this configuration will be performed including diagnostic, performance, verification, long-term, and chemical emissions testing. These tests are scheduled to start in May 1993 and continue through August 1993. Preliminary engineering and procurement are progressing on the Advanced Low NOx Digital Controls scope addition to the wall-fired project. The primary activities during this quarter include (1) refinement of the input/output lists, (2) procurement of the distributed digital control system, (3) configuration training, and (4) revision of schedule to accommodate project approval cycle and change in unit outage dates.

  12. Engineering development of advanced coal-fired low-emission boiler systems. Quarterly technical progress report, January 1--March 31, 1994

    Energy Technology Data Exchange (ETDEWEB)

    1994-04-28

    This project is concerned with the development of an a coal-fired low-emission boiler system. During march, separate kick-off meetings were held with PSI Powerserve, Raytheon and B&W`s Environmental Equipment Division to begin work on Phase I Task 5, the Commercial Plant Design. In addition, a meeting was held with MIT to discuss and review work completed and schedule work remaining on the project.

  13. Biomass boilers

    OpenAIRE

    Nahodil, Jiří

    2011-01-01

    Bachelor’s thesis deals with the use of biomass for heating houses and apartment houses. The first part is dedicated to biomass. Here are mentioned the possibility of energy recovery, treatment and transformation of biomass into a form suitable for burning, its properties and combustion process itself. The second part is devoted to biomass boilers, their separation and description. The last section compares the specific biomass boiler with a boiler to natural gas, particularly from an economi...

  14. UK corrosion 90. V. 1-3

    International Nuclear Information System (INIS)

    This volume contains 30 papers presented at the Conference. They are collected together under the following headings: corrosion science; cathodic protection; boiler and coding water treatments to control corrosion; high temperature corrosion; waxes and asphatenes. A separate abstract has been prepared for the one paper dealing with corrosion specifically related to nuclear facilities; namely, crevice corrosion in BWRs. (UK)

  15. Corrosion/94 conference papers

    International Nuclear Information System (INIS)

    The approximately 500 papers from this conference are divided into the following sections: Rail transit systems--stray current corrosion problems and control; Total quality in the coatings industry; Deterioration mechanisms of alloys at high temperatures--prevention and remediation; Research needs and new developments in oxygen scavengers; Computers in corrosion control--knowledge based system; Corrosion and corrosivity sensors; Corrosion and corrosion control of steel reinforced concrete structures; Microbiologically influenced corrosion; Practical applications in mitigating CO2 corrosion; Mineral scale deposit control in oilfield-related operations; Corrosion of materials in nuclear systems; Testing nonmetallics for life prediction; Refinery industry corrosion; Underground corrosion control; Mechanisms and applications of deposit and scale control additives; Corrosion in power transmission and distribution systems; Corrosion inhibitor testing and field application in oil and gas systems; Decontamination technology; Ozone in cooling water applications, testing, and mechanisms; Corrosion of water and sewage treatment, collection, and distribution systems; Environmental cracking of materials; Metallurgy of oil and gas field equipment; Corrosion measurement technology; Duplex stainless steels in the chemical process industries; Corrosion in the pulp and paper industry; Advances in cooling water treatment; Marine corrosion; Performance of materials in environments applicable to fossil energy systems; Environmental degradation of and methods of protection for military and aerospace materials; Rail equipment corrosion; Cathodic protection in natural waters; Characterization of air pollution control system environments; and Deposit-related problems in industrial boilers. Papers have been processed separately for inclusion on the data base

  16. NOx CONTROL OPTIONS AND INTEGRATION FOR US COAL FIRED BOILERS

    International Nuclear Information System (INIS)

    This is the sixth Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. This program contains multiple tasks and good progress is being made on all fronts. Preliminary results from laboratory and field tests of a corrosion probe to predict waterwall wastage indicate good agreement between the electrochemical noise corrosion rates predicted by the probe and corrosion rates measured by a surface profilometer. Four commercial manufacturers agreed to provide catalyst samples to the program. BYU has prepared two V/Ti oxide catalysts (custom, powder form) containing commercially relevant concentrations of V oxide and one containing a W oxide promoter. Two pieces of experimental apparatus being built at BYU to carry out laboratory-scale investigations of SCR catalyst deactivation are nearly completed. A decision was made to carry out the testing at full-scale power plants using a slipstream of gas instead of at the University of Utah pilot-scale coal combustor as originally planned. Design of the multi-catalyst slipstream reactor was completed during this quarter. One utility has expressed interest in hosting a long-term test at one of their plants that co-fire wood with coal. Tests to study ammonia adsorption onto fly ash have clearly established that the only routes that can play a role in binding significant amounts of ammonia to the ash surface, under practical ammonia slip conditions, are those that must involve co-adsorbates

  17. NOx CONTROL OPTIONS AND INTEGRATION FOR US COAL FIRED BOILERS

    Energy Technology Data Exchange (ETDEWEB)

    Mike Bockelie; Marc Cremer; Kevin Davis; Connie Senior; Bob Hurt; Eric Suuberg; Eric Eddings; Larry Baxter

    2002-01-31

    This is the sixth Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. This program contains multiple tasks and good progress is being made on all fronts. Preliminary results from laboratory and field tests of a corrosion probe to predict waterwall wastage indicate good agreement between the electrochemical noise corrosion rates predicted by the probe and corrosion rates measured by a surface profilometer. Four commercial manufacturers agreed to provide catalyst samples to the program. BYU has prepared two V/Ti oxide catalysts (custom, powder form) containing commercially relevant concentrations of V oxide and one containing a W oxide promoter. Two pieces of experimental apparatus being built at BYU to carry out laboratory-scale investigations of SCR catalyst deactivation are nearly completed. A decision was made to carry out the testing at full-scale power plants using a slipstream of gas instead of at the University of Utah pilot-scale coal combustor as originally planned. Design of the multi-catalyst slipstream reactor was completed during this quarter. One utility has expressed interest in hosting a long-term test at one of their plants that co-fire wood with coal. Tests to study ammonia adsorption onto fly ash have clearly established that the only routes that can play a role in binding significant amounts of ammonia to the ash surface, under practical ammonia slip conditions, are those that must involve co-adsorbates.

  18. Life extension of boilers using weld overlay protection

    Energy Technology Data Exchange (ETDEWEB)

    Lai, G.; Hulsizer, P. [Welding Services Inc., Norcross, GA (United States); Brooks, R. [Welding Services Inc., Welding Services Europe, Spijkenisse (Netherlands)

    1998-12-31

    The presentation describes the status of modern weld overlay technology for refurbishment, upgrading and life extension of boilers. The approaches to life extension of boilers include field overlay application, shop-fabricated panels for replacement of the worn, corroded waterwall and shop-fabricated overlay tubing for replacement of individual tubes in superheaters, generating banks and other areas. The characteristics of weld overlay products are briefly described. Also discussed are successful applications of various corrosion-resistant overlays for life extension of boiler tubes in waste-to-energy boilers, coal-fired boilers and chemical recovery boilers. Types of corrosion and selection of weld overlay alloys in these systems are also discussed. (orig.) 14 refs.

  19. PENCEGAHAN KOROSI DENGAN BOILER WATER TREATMENT (BWT PADA KETEL UAP KAPAL.

    Directory of Open Access Journals (Sweden)

    Suleman Suleman

    2012-03-01

    Full Text Available This paper explained about a using of Boiler Water Treatment (BWT as corrosion protection for boiler on ship. BWT used as addition on boiler water, which used destilat water. As experiment results, BWT used on destilat water and destilat - seawater mixed given not koagulan patch on. The simulation given not satisfied results, caused by good not equipment.

  20. Corrosion/96 conference papers

    International Nuclear Information System (INIS)

    Topics covered by this conference include: cathodic protection in natural waters; cleaning and repassivation of building HVAC systems; worldwide opportunities in flue gas desulfurization; advancements in materials technology for use in oil and gas service; fossil fuel combustion and conversion; technology of corrosion inhibitors; computers in corrosion control--modeling and information processing; recent experiences and advances of austenitic alloys; managing corrosion with plastics; corrosion measurement technology; corrosion inhibitors for concrete; refining industry; advances in corrosion control for rail and tank trailer equipment; CO2 corrosion--mechanisms and control; microbiologically influenced corrosion; corrosion in nuclear systems; role of corrosion in boiler failures; effects of water reuse on monitoring and control technology in cooling water applications; methods and mechanisms of scale and deposit control; corrosion detection in petroleum production lines; underground corrosion control; environmental cracking--relating laboratory results and field behavior; corrosion control in reinforced concrete structures; corrosion and its control in aerospace and military hardware; injection and process addition facilities; progress reports on the results of reinspection of deaerators inspected or repaired per RP0590 criteria; near 100% volume solids coating technology and application methods; materials performance in high temperature environments containing halides; impact of toxicity studies on use of corrosion/scale inhibitors; mineral scale deposit control in oilfield related operations; corrosion in gas treating; marine corrosion; cold climate corrosion; corrosion in the pulp and paper industry; gaseous chlorine alternatives in cooling water systems; practical applications of ozone in recirculating cooling water systems; and water reuse in industry. Over 400 papers from this conference have been processed separately for inclusion on the data base

  1. Evaluation of surrogate boilers for steam generators

    International Nuclear Information System (INIS)

    Steam generator damage in pressurized water reactors is a continuing problem which results from a combination of factors including mechanical design, thermal hydraulics, materials selection, fabrication techniques, water chemistry, and system design and operation. A wide variety of steam generator damage mechanisms has been identified in operating PWRs including intergranular attack, thinning, stress corrosion cracking, erosion, denting, fatigue cracking, pitting, and fretting. Model boilers operated in parallel to the steam generators, i.e., surrogate boilers, may provide a useful tool in the study of these damage mechanisms, their causative factors, and the effects of corrosion actions. To evaluate the applicability of surrogate boilers to such studies, Steam Generator Owners Group I project S111-2 was established. Evaluation of numerous surrogate boiler design alternates led to identification of several possible acceptable approaches. The appropriate surrogate feedwater was identified as plant feedwater. Capability to operate with a tube-side temperature similar to the hot-leg temperature was considered necessary as was the ability to provide mechanical, thermal, and chemical corrosion acceleration. Practical and economically feasible surrogate boiler designs were developed in response to these design requirements

  2. 锅炉水冷壁管氢腐蚀爆管原因分析%Cause Analysis of Hydrogen Corrosion Induced Bursting of Waterwall Tubes in a Boiler

    Institute of Scientific and Technical Information of China (English)

    张亚明; 夏邦杰; 董爱华

    2012-01-01

    某热电厂5号锅炉水冷壁发生爆管.对取样水冷壁管进行了宏观观察、化学分析、金相分析、扫描电镜与电子能谱分析及x射线衍射分析等.结果表明,爆管原因是水冷壁管向火侧内壁局部区域发生氢腐蚀所致.提出了预防此类事故发生的措施.%Bursting failure occurred on waterwall tubes of No.5 boiler in a power plant. Macroscop- ic inspection, chemical analysis, metallurgraphy, scanning electron microscopy (SEM), energy dis-persive spectroscopy (EDS) and X-ray diffraction (XRD) were adopted to examine the failed tube. The results indicated that the tube rupture was resulted from localized hydrogen corrosion of the part facing fire. Preventive measures of such failures are put forward.

  3. Corrosion of support materials

    International Nuclear Information System (INIS)

    Results from a heavily fouled 19 tube C-E model boiler test to investigate the potential for egg crate corrosion in aggressively fouled AVT chemistry are reported. Substantial support plate and egg crate corrosion was produced in this test. Carbon steel drilled support plates exhibited extensive denting which resulted in flow hole ligament cracking. Corrosion of the carbon steel egg crate, through-wall at areas of tube contact, resulted in denting of the Alloy 600 heat transfer tubes. Corrosion performance of the 409 stainless steel egg crate was improved compared to the carbon steel egg crate although localized through-wall corrosion was noted. The results from the above test and previously reported tests were compared based on the following simplifying assumptions: maximum dent size and/or corrosion penetrations utilized, average bulk water chloride concentrations, pilling bedworth ratios, pot and model boilers data are equivalent, heat flux not significantly variable, and plot is semi-quantitative. Conclusions based on plots of maximum corrosion rates as a function of average bulk water chloride concentrations are presented. Finally, the corrosion performance of the various materials of construction for support systems were ranked for each test. Final material selection for future support systems must be based on a balance of thermal/hydraulic, metallurgical, corrosion and design considerations

  4. The effect of water quality on reliability of boiler plants performance

    OpenAIRE

    Gajić Anto S.; Tomić Milorad V.; Pavlović Ljubica J.; Pavlović Miomir G.

    2010-01-01

    This paper presents sources and types of corrosion processes of boiler tube system of the Thermal Power Plant "Ugljevik". The main goal in the electric power production is to achieve lower prices, which can only be done by providing low maintenance costs. While it is not possible to completely stop corrosion, it could be slowed down and it's effects could be reduced. In order to reduce corrosion to a minimum on thermal power plants' vital equipment, particularly boilers, it is necessary to de...

  5. Steam boiler technology

    Energy Technology Data Exchange (ETDEWEB)

    Teir, S.

    2002-07-01

    The steam boiler technology e-Book is provided by the Laboratory of Energy Engineering and Environmental Protection at Helsinki University of Technology. The book covers the basics and the history of steam generation, modern boilers types and applications, steam/water circulation design, feedwater and steam systems components, heat exchangers in steam boilers, boiler calculations, thermal design of heat exchangers.

  6. Application of 1-hydroxyethylidene-1, 1-diphosphonic acid in boiler water for industrial boilers.

    Science.gov (United States)

    Zeng, Bin; Li, Mao-Dong; Zhu, Zhi-Ping; Zhao, Jun-Ming; Zhang, Hui

    2013-01-01

    The primary method used for boiler water treatment is the addition of chemicals to industrial boilers to prevent corrosion and scaling. The static scale inhibition method was used to evaluate the scale inhibition performance of 1-hydroxyethylidene-1, 1-diphosphonic acid (HEDP). Autoclave static experiments were used to study the corrosion inhibition properties of the main material for industrial boilers (20# carbon steel) with an HEDP additive in the industrial boiler water medium. The electrochemical behavior of HEDP on carbon steel corrosion control was investigated using electrochemical impedance spectroscopy and Tafel polarization techniques. Experimental results indicate that HEDP can have a good scale inhibition effect when added at a quantity of 5 to 7 mg/L at a test temperature of not more than 100 °C. To achieve a high scale inhibition rate, the HEDP dosage must be increased when the test temperature exceeds 100 °C. Electrochemical and autoclave static experimental results suggest that HEDP has a good corrosion inhibition effect on 20# carbon steel at a concentration of 25 mg/L. HEDP is an excellent water treatment agent. PMID:23552243

  7. Review of conditions for reliable boiler operation; Bedingungen fuer einen zuverlaessigen Kesselbetrieb

    Energy Technology Data Exchange (ETDEWEB)

    Stodola, J.

    1999-08-01

    This paper discusses fundamentals of corrosion protection in boilers, different boiler water treatments used by the utility industry to achieve this objective as well as limitations boiler designs may impose on long term boiler performance. The purpose there is to determine whether chemists have the ability to guarantee reliable and problem free operation of any boiler. (orig.) [German] Dieser Artikel diskutiert die Grundlagen des Korrosionsschutzes in Kesseln, die verschiedenen von den Kraftwerken angewandten Kesselwasser-Fahrweisen und die Auswirkung der Kesselauslegung auf das langfristige Kesselverhalten. Es wird ueberlegt, ob Chemiker einen zuverlaessigen und problemfreien Betrieb eines jeden Kessels garantieren koennen. (orig.)

  8. Boilers, evaporators, and condensers

    International Nuclear Information System (INIS)

    This book reports on the boilers, evaporators and condensers that are used in power plants including nuclear power plants. Topics included are forced convection for single-phase side heat exchangers, heat exchanger fouling, industrial heat exchanger design, fossil-fuel-fired boilers, once through boilers, thermodynamic designs of fossil fuel-first boilers, evaporators and condensers in refrigeration and air conditioning systems (with respect to reducing CFC's) and nuclear steam generators

  9. Central heating: package boilers

    Energy Technology Data Exchange (ETDEWEB)

    Farahan, E.

    1977-05-01

    Performance and cost data for electrical and fossil-fired package boilers currently available from manufacturers are provided. Performance characteristics investigated include: unit efficiency, rated capacity, and average expected lifetime of units. Costs are tabulated for equipment and installation of various package boilers. The information supplied in this report will simplify the process of selecting package boilers required for industrial, commercial, and residential applications.

  10. Oxy-Combustion Boiler Material Development

    Energy Technology Data Exchange (ETDEWEB)

    Gagliano, Michael; Seltzer, Andrew; Agarwal, Hans; Robertson, Archie; Wang, Lun

    2012-01-31

    Under U.S. Department of Energy Cooperative Agreement No. DE-NT0005262 Foster Wheeler North America Corp conducted a laboratory test program to determine the effect of oxy-combustion on boiler tube corrosion. In this program, CFD modeling was used to predict the gas compositions that will exist throughout and along the walls of air-fired and oxy-fired boilers operating with low to high sulfur coals. Test coupons of boiler tube materials were coated with deposits representative of those coals and exposed to the CFD predicted flue gases for up to 1000 hours. The tests were conducted in electric tube furnaces using oxy-combustion and air-fired flue gases synthesized from pressurized cylinders. Following exposure, the test coupons were evaluated to determine the total metal wastage experienced under air and oxy-combustions conditions and materials recommendations were made. Similar to air-fired operation, oxy-combustion corrosion rates were found to vary with the boiler material, test temperature, deposit composition, and gas composition. Despite this, comparison of air-fired and oxy-fired corrosion rates showed that oxy-firing rates were, for the most part, similar to, if not lower than those of air-firing; this finding applied to the seven furnace waterwall materials (wrought and weld overlay) and the ten superheater/reheater materials (wrought and weld overlay) that were tested. The results of the laboratory oxy-combustion tests, which are based on a maximum bulk flue gas SO2 level of 3200 ppmv (wet) / 4050 ppmv (dry), suggest that, from a corrosion standpoint, the materials used in conventional subcritical and supercritical, air-fired boilers should also be suitable for oxy-combustion retrofits. Although the laboratory test results are encouraging, they are only the first step of a material evaluation process and it is recommended that follow-on corrosion tests be conducted in coal-fired boilers operating under oxy-combustion to provide longer term (one to two year

  11. Oxy-Combustion Boiler Material Development

    Energy Technology Data Exchange (ETDEWEB)

    Michael Gagliano; Andrew Seltzer; Hans Agarwal; Archie Robertson; Lun Wang

    2012-01-31

    Under U.S. Department of Energy Cooperative Agreement No. DE-NT0005262 Foster Wheeler North America Corp conducted a laboratory test program to determine the effect of oxy-combustion on boiler tube corrosion. In this program, CFD modeling was used to predict the gas compositions that will exist throughout and along the walls of air-fired and oxy-fired boilers operating with low to high sulfur coals. Test coupons of boiler tube materials were coated with deposits representative of those coals and exposed to the CFD predicted flue gases for up to 1000 hours. The tests were conducted in electric tube furnaces using oxy-combustion and air-fired flue gases synthesized from pressurized cylinders. Following exposure, the test coupons were evaluated to determine the total metal wastage experienced under air and oxy-combustions conditions and materials recommendations were made. Similar to air-fired operation, oxy-combustion corrosion rates were found to vary with the boiler material, test temperature, deposit composition, and gas composition. Despite this, comparison of air-fired and oxy-fired corrosion rates showed that oxy-firing rates were, for the most part, similar to, if not lower than those of air-firing; this finding applied to the seven furnace waterwall materials (wrought and weld overlay) and the ten superheater/reheater materials (wrought and weld overlay) that were tested. The results of the laboratory oxy-combustion tests, which are based on a maximum bulk flue gas SO{sub 2} level of 3200 ppmv (wet) / 4050 ppmv (dry), suggest that, from a corrosion standpoint, the materials used in conventional subcritical and supercritical, air-fired boilers should also be suitable for oxy-combustion retrofits. Although the laboratory test results are encouraging, they are only the first step of a material evaluation process and it is recommended that follow-on corrosion tests be conducted in coal-fired boilers operating under oxy-combustion to provide longer term (one to

  12. High temperature corrosion during waste incineration : characterisation, causes and prevention of chlorine-induced corrosion

    OpenAIRE

    Viklund, Peter

    2011-01-01

    Waste-fired boilers suffer severely from corrosion of critical components such as superheater tubes. In this work the high temperature corrosion of candidate superheater alloys have been investigated by detailed laboratory studies and controlled field exposures in full-scale boilers. In a laboratory study the detrimental effect of gaseous hydrochloric acid (HCl) on three  different ground surface and preoxidised austenitic stainless steels was investigated. Exposures were conducted in an envi...

  13. The effect of water quality on reliability of boiler plants performance

    Directory of Open Access Journals (Sweden)

    Gajić Anto S.

    2010-01-01

    Full Text Available This paper presents sources and types of corrosion processes of boiler tube system of the Thermal Power Plant "Ugljevik". The main goal in the electric power production is to achieve lower prices, which can only be done by providing low maintenance costs. While it is not possible to completely stop corrosion, it could be slowed down and it's effects could be reduced. In order to reduce corrosion to a minimum on thermal power plants' vital equipment, particularly boilers, it is necessary to determine in each particular case the acting mechanism of corrosion and agents that cause it. Damages and failures on thermal power plants are largely caused by the development of various types of corrosion processes. Special attention is given to the preparation of water, considering its importance to the occurrence of corrosion. The following types of corrosion were detected on the screen tube boiler by visual examination on the side of water and steam: erosive, pitting and impact corrosion. The inner surface of screen pipes, from which the scale layer was removed, indicates that the erosive corrosion with the thinning of pipe walls occurs. Perforation of the welded screen pipes shows that stress corrosion occurred on the screen pipe with formation of cracks and that pipe exploded. Pits on the inner surface of the screen pipes, visible after the removal of scale and corrosion products, are proof that pitting corrosion occurred. The causes of corrosion were discovered and proposed measures for their elimination were given.

  14. Analysis of Causes for Corrosion of Tube Bundle Welded Joint of Waste Heat Boiler in Ammonia Synthesis System and Improvement%氨合成系统废热锅炉管束焊接接头腐蚀原因分析及改进

    Institute of Scientific and Technical Information of China (English)

    张英杰; 韩荣芹; 左卫锋

    2013-01-01

    氨合成系统废热锅炉投运8个月后,其管束的气体进口端联箱管与换热管间的焊接接头出现连续点状腐蚀坑样缺陷,而管束的气体出口端相应位置没有出现此类缺陷,设备其他部位未见异常.通过对氨合成系统废热锅炉管束焊接接头腐蚀部位的宏观形貌、低倍形态、化学组分、扩展方向及金相组织等特征进行分析,判定腐蚀形态为电偶腐蚀.针对腐蚀形态,采取了相应的改进措施,取得了明显的效果.%8 months after putting into operation of the waste heat boiler in ammonia synthesis system,defects of continuous dotted etch pit appeared at welded joints between gas inlet connecting tube and heat exchange tube of tube bundle,while no such kind of defect found at relevant position of gas outlet of tube bundle,and there are no troubles seen in other parts of the equipment.Through analyzing features of micro profile,macroscopic appearance,chemical composition,extension direction and metallographic structure,etc.of corroded parts of the tube bundle welded joints of the waste heat boiler in ammonia synthesis system,it is determined that the corrosion form is galvanic corrosion.In connection with the corrosion form,relevant improvement measures are taken and significant effect is obtained.

  15. Deposition and high temperature corrosion in a 10 MW straw

    DEFF Research Database (Denmark)

    Michelsen, Hanne Philbert; Frandsen, Flemming; Dam-Johansen, Kim; Larsen, Ole Hede

    Deposition and corrosion measurements were conducted at a 10 MW wheat straw fired stoker boiler used for combined power and heat production. The plant experiences major problems with deposits on the heat transfer surfaces, and test probes have shown enhanced corrosion due to selective corrosion for...

  16. Evaluation of corrosion attack of chimney liners

    OpenAIRE

    Blahetová M.; Horák J.; Kubesa P.; Lasek S.; Ochodek T.

    2016-01-01

    The case study of chimney liner corrosion addresses three specific cases of damage of chimney systems from of stainless steels. These systems were used for flue of gas arising from the combustion of brown coal in small automatic boilers, which are used for heating. Detailed analyzes implied that the cause of devastating corrosion of the steel AISI 316 and 304 steel (CSN 17349, 17241) was particularly high content of halides (chlorides and fluorides), which caused a severe pitting corrosion, w...

  17. Steam boiler for fytomass

    OpenAIRE

    Baláš, Jiří

    2008-01-01

    The purpose of this Diploma Thesis was the construction design of the steam boiler for fytomass. For the specified parameters of biomass have been gradually implemented stoichiometric calculations of which are further based calculation of enthalpies of combustion gas. In the next part have been dealt with heat balance of the boiler, the efficiency of the boiler, recirculation of exhaust gases and the temperature of the combustion gases in outlet from fire. Thereinafter, the proposal of partic...

  18. Boiler conversions for biomass

    Energy Technology Data Exchange (ETDEWEB)

    Kinni, J. [Tampella Power Inc., Tampere (Finland)

    1996-12-31

    Boiler conversions from grate- and oil-fired boilers to bubbling fluidized bed combustion have been most common in pulp and paper industry. Water treatment sludge combustion, need for additional capacity and tightened emission limits have been the driving forces for the conversion. To accomplish a boiler conversion for biofuel, the lower part of the boiler is replaced with a fluidized bed bottom and new fuel, ash and air systems are added. The Imatran Voima Rauhalahti pulverized-peat-fired boiler was converted to bubbling fluidized bed firing in 1993. In the conversion the boiler capacity was increased by 10 % to 295 MWth and NO{sub x} emissions dropped. In the Kymmene Kuusankoski boiler, the reason for conversion was the combustion of high chlorine content biosludge. The emissions have been under general European limits. During the next years, the emission limits will tighten and the boilers will be designed for most complete combustion and compounds, which can be removed from flue gases, will be taken care of after the boiler. (orig.) 3 refs.

  19. Computational Modeling and Assessment Of Nanocoatings for Ultra Supercritical Boilers

    Energy Technology Data Exchange (ETDEWEB)

    Gandy, David W. [Electric Power Research Institute, Inc., Palo Alto, CA (United States); Shingledecker, John P. [Electric Power Research Institute, Inc., Palo Alto, CA (United States)

    2011-05-11

    Coal-fired power plants are a significant part of the nation's power generating capacity, currently accounting for more than 55% of the country's total electricity production. Extending the reliable lifetimes of fossil fired boiler components and reducing the maintenance costs are essential for economic operation of power plants. Corrosion and erosion are leading causes of superheater and reheater boiler tube failures leading to unscheduled costly outages. Several types of coatings and weld overlays have been used to extend the service life of boiler tubes; however, the protection afforded by such materials was limited approximately one to eight years. Power companies are more recently focused in achieving greater plant efficiency by increasing steam temperature and pressure into the advanced-ultrasupercritical (A-USC) condition with steam temperatures approaching 760°C (1400°F) and operating pressures in excess of 35MPa (5075 psig). Unfortunately, laboratory and field testing suggests that the resultant fireside environment when operating under A-USC conditions can potentially cause significant corrosion to conventional and advanced boiler materials1-2. In order to improve reliability and availability of fossil fired A-USC boilers, it is essential to develop advanced nanostructured coatings that provide excellent corrosion and erosion resistance without adversely affecting the other properties such as toughness and thermal fatigue strength of the component material.

  20. Studies Concerning Water-Surface Deposits in Recovery Boilers

    International Nuclear Information System (INIS)

    The Feed-water Committee of the Stiftelsen Svensk Cellulosaforskning (Foundation for Swedish Cellulose Research) has initiated research and investigations which aim to increase knowledge about water-surface deposits in boiler tubes, and the resulting risks of gas-surface corrosion in chemical recovery boilers (sulphate pulp industry). The Committee has arranged with AB Atomenergi, Studsvik, for investigations into the water-surface deposits on tubes from six Scandinavian boilers. These investigations have included direct measurements of the thermal conductivity of the deposits, and determinations of their quantity, thickness and structure have been carried out. Previous investigations have shown that gas-surface corrosion can occur at tube temperatures above 330 deg C. The measured values for the thermal conductivity of the deposits indicate that even with small quantities of deposit (c. 1 g/dm2 ) and a moderate boiler pressure (40 atm), certain types of deposit can give rise to the above-mentioned surface temperature, at which the risk of gas-surface corrosion becomes appreciable. For higher boiler pressures the risk is great even with a minimal layer of deposit. The critical deposit thickness can be as low as 0.1 mm

  1. Integrated boiler, superheater, and decomposer for sulfuric acid decomposition

    Science.gov (United States)

    Moore, Robert; Pickard, Paul S.; Parma, Jr., Edward J.; Vernon, Milton E.; Gelbard, Fred; Lenard, Roger X.

    2010-01-12

    A method and apparatus, constructed of ceramics and other corrosion resistant materials, for decomposing sulfuric acid into sulfur dioxide, oxygen and water using an integrated boiler, superheater, and decomposer unit comprising a bayonet-type, dual-tube, counter-flow heat exchanger with a catalytic insert and a central baffle to increase recuperation efficiency.

  2. Fourth quarterly report 1976

    International Nuclear Information System (INIS)

    The 4th quarterly report 1976 describes activities which were carried out within the framework of the Fast Breeder project at the Gesellschaft fuer Kernforschung, Karlsruhe, or on its behalf. The sections refer to the following subjects: Fuel rod development; material studies and development; corrosion experiments and coolant analysis; physics experiments; reactor theory; fast breeder safety; instrumentation and signal processing for core control; effects on the environment; sodium technology experiments; thermo- and fluid-dynamic tests in gas; design studies concerning sodium-cooled breeders. (HR)

  3. High temperature corrosion investigation in an oxyfuel combustion test rig

    DEFF Research Database (Denmark)

    Montgomery, Melanie; Bjurman, M.; Hjörnhede, A;

    2014-01-01

    Oxyfuel firing and subsequent capture of CO2 is a way to reduce CO2 emissions from coal‐fired boilers. Literature is summarized highlighting results which may contribute to understanding of the corrosion processes in an oxyfuel boiler.Tests were conducted in a 500 kWth oxyfuel test facility...

  4. Materials for the pulp and paper industry. Section 1: Development of materials for black liquor recovery boilers

    Energy Technology Data Exchange (ETDEWEB)

    Keiser, J.R.; Hubbard, C.R.; Payzant, E.A. [Oak Ridge National Lab., TN (United States)] [and others

    1997-04-01

    Black liquor recovery boilers are essential components of kraft pulp and paper mills because they are a critical element of the system used to recover the pulping chemicals required in the kraft pulping process. In addition, the steam produced in these boilers is used to generate a significant portion of the electrical power used in the mill. Recovery boilers require the largest capital investment of any individual component of a paper mill, and these boilers are a major source of material problems in a mill. The walls and floors of these boilers are constructed of tube panels that circulate high pressure water. Molten salts (smelt) accumulate on the floor of recovery boilers, and leakage of water into the boiler can result in a violent explosion when the leaked water instantly vaporizes upon contacting the molten smelt. Because corrosion of the conventionally-used carbon steel tubing was found to be excessive in the lower section of recovery boilers, use of stainless steel/carbon steel co-extruded tubing was adopted for boiler walls to lessen corrosion and reduce the likelihood of smelt/water explosions. Eventually, this co-extruded or composite (as it is known in the industry) tubing was selected for use as a portion or all of the floor of recovery boilers, particularly those operating at pressures > 6.2 MPa (900 psi), because of the corrosion problems encountered in carbon steel floor tubes. Since neither the cause of the cracking nor an effective solution has been identified, this program was established to develop a thorough understanding of the degradation that occurs in the composite tubing used for walls and floors. This is being accomplished through a program that includes collection and review of technical reports, examination of unexposed and cracked tubes from boiler floors, computer modeling to predict residual stresses under operating conditions, and operation of laboratory tests to study corrosion, stress corrosion cracking, and thermal fatigue.

  5. Chemical and mechanical control of corrosion product transport

    Energy Technology Data Exchange (ETDEWEB)

    Hede Larsen, O.; Blum, R. [I/S Fynsvaerket, Faelleskemikerne, Odense (Denmark); Daucik, K. [I/S Skaerbaekvaerket, Faelleskemikerne, Fredericia (Denmark)

    1996-12-01

    The corrosion products formed in the condensate and feedwater system of once-through boilers are precipitated and deposited inside the evaporator tubes mainly in the burner zone at the highest heat flux. Depositions lead to increased oxidation rate and increased metal temperature of the evaporator tubes, hereby decreasing tube lifetime. This effect is more important in the new high efficiency USC boilers due to increased feedwater temperature and hence higher thermal load on the evaporator tubes. The only way to reduce the load on the evaporator tubes is to minimise corrosion product transport to the boiler. Two general methods for minimising corrosion product transport to the boiler have been evaluated through measurement campaigns for Fe in the water/steam cycle in supercritical boilers within the ELSAM area. One method is to reduce corrosion in the low temperature condensate system by changing conditioning mode from alkaline volatile treatment (AVT) to oxygenated treatment (OT). The other method is to filtrate part of the condensate with a mechanical filter at the deaerator. The results show, that both methods are effective at minimising Fe-transport to the boiler, but changing to OT has the highest effect and should always be used, whenever high purity condensate is maintained. Whether mechanical filtration also is required, depends on the boiler, specifically the load on the evaporator. A simplified calculation model for lifetime evaluation of evaporator tubes has been developed. This model has been used for evaluating the effect of corrosion product transport to the boiler on evaporator tube lifetime. Conventional supercritical boilers generally can achieve sufficient lifetime by AVT and even better by OT, whereas all measures to reduce Fe-content of feedwater, including OT and mechanical filtration, should be taken, to ensure sufficient lifetime for the new boilers with advanced steam data - 290 bar/580 deg. C and above. (au)

  6. ENERGY STAR Certified Boilers

    Data.gov (United States)

    U.S. Environmental Protection Agency — Certified models meet all ENERGY STAR requirements as listed in the Version 3.0 ENERGY STAR Program Requirements for Boilers that are effective as of October 1,...

  7. Charting the boiler market

    International Nuclear Information System (INIS)

    The ''boiler market'' of electricity, sometimes called unsecured transmission, is electric power consumption that in public statistics is restricted by the obligation of the customers to cut their consumption at short notice and therefore are granted some discount on the network lease. The present document is part of a project that aims to provide a better understanding of the flexibility in the Norwegian power market, limited by the power-intensive industry and the boiler market. It discusses the boiler market. It begins with a discusses of the available statistics, where different sources show very dissimilar consumption figures. Then it examines how the consumption in the boiler market developed during the winter 2002/2003. Finally, there is a description of the regulations of unsecured transmission and how the various network owners adapt to the regulations.

  8. Organic Contaminants and Treatment Chemicals in Steam-Water Cycles: Thermal stability, decomposition products and flow-accelerated corrosion

    NARCIS (Netherlands)

    Moed, D.H.

    2015-01-01

    Boiler feedwater and steam have to be of high purity, because of the susceptibility of the steam-water cycle to corrosion. Organic contaminants break down in boilers by hydrothermolysis, leading to the formation of organic acid anions, which are suspected to cause corrosion of steam-water cycle comp

  9. Corrosion in sulfur recovery units

    Energy Technology Data Exchange (ETDEWEB)

    Fraisse, M.

    1979-06-01

    Corrosion in sulfur recovery units may be caused by sulfuric acid formed at cold points in operating units or during the startup, shutdown, or catalyst regeneration periods. Insufficient high-temperature resistance of main boiler materials to sulfuric acid is another common cause of severe corrosion. The specific corrosion problems encountered in hydrotreating units include high- and low-temperature hydrogen embrittlement of steel above 200/sup 0/C and between -50/sup 0/ and +20/sup 0/C, respectively, sometimes accompanied with blistering; carbon steel corrosion by hydrogen sulfide above 280/sup 0/C in desulfurization units; low-temperature stress corrosion or hydrogen blistering by H/sub 2/S in aqueous environments; corrosion by chloride ions coupled with precipitation of ammonium chloride in catalytic reformers during catalyst regeneration; corrosion and fouling by ammonium sulfide in gas oil hydrodesulfurization units and reformers below 90/sup 0/C; and intergranular and stress corrosion of austenitic steels by polythionic acids which may be formed during startup or catalyst regeneration periods. Methods for preventing these types of corrosion are outlined.

  10. Steam boiler technology

    Energy Technology Data Exchange (ETDEWEB)

    Teir, S.

    2003-07-01

    This book is the published version of the e-book with the same name. The interactive lecture slides, which accompany most chapters, exist only in the online version and on the attached CD-Rom. The Steam Boiler Technology e-book is the main course book for the course on steam boiler technology provided by the Laboratory of Energy Engineering and Environmental Protection at Helsinki University of Technology. The steam boiler technology e-Book is provided by the Laboratory of Energy Engineering and Environmental Protection at Helsinki University of Technology. The book covers the basics and the history of steam generation, modern boilers types and applications, steam/water circulation design, feedwater and steam systems components, heat exchangers in steam boilers, boiler calculations, thermal design of heat exchangers. The chapters of the second edition have been corrected based on reader and reviewer comments, and four new chapters have been added. The user interface of the electronic version has also been updated. The password for the online book will be changed once a year. If you have problems accessing the online book, or need a new password, please contact sebastian.teir@hut.fi.

  11. MODELLING, SIMULATING AND OPTIMIZING BOILERS

    DEFF Research Database (Denmark)

    Sørensen, Kim; Condra, Thomas Joseph; Houbak, Niels

    In the present work a framework for optimizing the design of boilers for dynamic operation has been developed. A cost function to be minimized during the optimization has been formulated and for the present design variables related to the Boiler Volume and the Boiler load Gradient (i.e. ring rate...... on the boiler) have been dened. Furthermore a number of constraints related to: minimum and maximum boiler load gradient, minimum boiler size, Shrinking and Swelling and Steam Space Load have been dened. For dening the constraints related to the required boiler volume a dynamic model for simulating...... the boiler performance has been developed. Outputs from the simulations are shrinking and swelling of water level in the drum during for example a start-up of the boiler, these gures combined with the requirements with respect to allowable water level uctuations in the drum denes the requirements with...

  12. ADVANCED, LOW/ZERO EMISSION BOILER DESIGN AND OPERATION

    Energy Technology Data Exchange (ETDEWEB)

    Ovidiu Marin; Fabienne Chatel-Pelage

    2003-04-01

    This document reviews the work performed during the quarter January-March 2003. The main objectives of the project are: To demonstrate the feasibility of the full-oxy combustion with flue gas recirculation on Babcock & Wilcox's 1.5MW pilot boiler, To measure its performances in terms of emissions and boiler efficiency while selecting the right oxygen injection strategies, To perform an economical feasibility study, comparing this solution with alternate technologies, and To design a new generation, full oxy-fired boiler. The main objective of this quarter was to initiate the project, primarily the experimental tasks. The contractor and its subcontractors have defined a working plan, and the first tasks have been started. Task 1 (Site Preparation) is now in progress, defining the modifications to be implemented to the boiler and oxygen delivery system. The changes are required in order to overcome some current limitations of the existing system. As part of a previous project carried out in 2002, several changes have already been made on the pilot boiler, including the enrichment of the secondary and tertiary air with oxygen or the replacement of these streams with oxygen-enriched recycled flue gas. A notable modification for the current project involves the replacement of the primary air with oxygen-enriched flue gas. Consequently, the current oxygen supply and flue gas recycle system is being modified to meet this new requirement. Task 2 (Combustion and Emissions Performance Optimization) has been initiated with a preliminary selection of four series of tests to be performed. So far, the project schedule is on-track: site preparation (Task 1) should be completed by August 1st, 2003 and the tests (Task 2) are planned for September-October 2003. The Techno-Economic Study (Task 3) will be initiated in the following quarter.

  13. Installations of SNCR on bark-fired boilers

    International Nuclear Information System (INIS)

    Experience has been collected from the twelve bark-fired boilers in Sweden with selective non catalytic reduction (SNCR) installations to reduce emissions of nitrogen oxides. Most of the boilers have slope grates, but there are also two boilers with cyclone ovens and two fluidized bed boilers. In addition to oil there are also possibilities to burn other fuel types in most boilers, such as sludge from different parts of the pulp and paper mills, saw dust and wood chips. The SNCR installations seems in general to be of simple design. In most installations the injection nozzles are located in existing holes in the boiler walls. The availability is reported to be good from several of the SNCR installations. There has been tube leakage in several boilers. The urea system has resulted in corrosion and in clogging of one oil burner. This incident has resulted in a decision not to use SNCR system with the present design of the system. The fuel has also caused operational problems with the SNCR system in several of the installations due to variations in the moisture content and often high moisture content in bark and sludge, causing temperature variations. The availability is presented to be high for the SNCR system at several of the plants, in two of them about 90 %. The results in NOx reduction vary between the installations depending on boiler, fuel and operation. The emissions are between 45 and 100 mg NO2/MJ fuel input and the NOx reduction rates are in most installations between 30 and 40 %, the lowest 20 and the highest 70 %. 13 figs, 3 tabs

  14. Corrosion '98: 53. annual conference and exposition, proceedings

    International Nuclear Information System (INIS)

    Vehicle Corrosion Resistance; Seawater Injection Systems; Automating Improved Materials Performance; Boiler Water Corrosion; and New Advances in Pipeline Rehabilitation Coatings and Associated Technology. Separate abstracts were prepared for some of the papers

  15. Ash deposition and high temperature corrosion at combustion of aggressive fuels

    Energy Technology Data Exchange (ETDEWEB)

    Hede Larsen, O. [I/S Fynsvaerket, Faelleskemikerne, Odense (Denmark); Henriksen, N. [Elsamprojekt A/S, Faelleskemikerne, Fredericia (Denmark)

    1996-12-01

    In order to reduce CO{sub 2} emission, ELSAM is investigating the possibilities of using biomass - mainly straw - for combustion in high efficiency power plants. As straw has very high contents of chlorine and potassium, a fuel with high corrosion and ash deposition propensities has been introduced. ELSAM has investigated 3 ultra supercritical boiler concepts for combustion of straw alone or together with coal: (1) PF boilers with a relatively low share of straw, (2) CFB boilers with low to high share of straw and (3) vibrating grate boilers with 100% straw. These investigations has mainly been full-scale tests with straw fed into existing boilers. Corrosion tests have been performed in these boilers using temperature regulated probes and in-plant test tubes in existing superheaters. The corrosion has been determined by detailed measurements of wall thickness reduction and light optical microscopic measurements of the material degradation due to high temperature corrosion. Corrosion mechanisms have been evaluated using SEM/EDX together with thermodynamical considerations based on measurements of the chemical environment in the flue gas. Ash deposition is problematic in CFB boilers and in straw fired boilers, especially in years with high potassium and chlorine content of the straw. This ash deposition also is related to condensation of KCl and can probably only be handled by improved cleaning devices. (EG)

  16. Dynamic Boiler Performance

    DEFF Research Database (Denmark)

    Sørensen, Kim

    Traditionally, boilers have been designed mainly focussing on the static operation of the plant. The dynamic capability has been given lower priority and the analysis has typically been limited to assuring that the plant was not over-stressed due to large temperature gradients. New possibilities...... developed. Analyzing boilers for dynamic operation gives rise to a number of opposing aims: shrinking and swelling, steam quality, stress levels, control system/philosophy, pressurization etc. Common for these opposing aims is that an optimum can be found for selected operation conditions. The framework has...

  17. Characterization of model boiler specimens

    International Nuclear Information System (INIS)

    This paper describes the general results of an investigation of three crevice corrosion samples provided by Westinghouse from the S112-1 Model Boiler Program. These samples had all been formed under essentially the same initial chemical conditions, but two had been treated with inhibitors at the end of the experimental runs. The first received no neutralization during the model runs, the second was treated with Ca(OH)2 and the third was treated with boric acid. The samples were prepared for examination in several different ways. The samples were characteristic of dented intersections and had the general conformation of a thin-walled inner Inconel cylinder within a thick-walled carbon steel cylinder. An original 12-mil inter-cylinder gap had been packed with powdered magnetite. This magnetite had been augmented by further growth of magnetite during the model runs, making the oxide layer considerably thicker than the original 12-mils in some areas of the samples. The cylinders were sectioned and polished perpendicular to their long axes and the resulting surfaces examined

  18. Evaluation of corrosion attack of chimney liners

    Directory of Open Access Journals (Sweden)

    Blahetová M.

    2016-06-01

    Full Text Available The case study of chimney liner corrosion addresses three specific cases of damage of chimney systems from of stainless steels. These systems were used for flue of gas arising from the combustion of brown coal in small automatic boilers, which are used for heating. Detailed analyzes implied that the cause of devastating corrosion of the steel AISI 316 and 304 steel (CSN 17349, 17241 was particularly high content of halides (chlorides and fluorides, which caused a severe pitting corrosion, which led up to the perforation of the liner material. Simultaneous reduction of the thickness of the used sheets was due to by the general corrosion, which was caused by the sulfur in the solid fuel. The condensation then led to acid environment and therefore the corrosion below the dew point of the sulfuric acid has occurred. All is documented by metallographic analysis and microanalysis of the corrosion products.

  19. A risk approach to the management of boiler tube thinning

    International Nuclear Information System (INIS)

    A large set of industrial thickness inspection data covering four boiler units of a power station over a period of five years was made available to the authors. The measurements were made in regions of the boiler where corrosion/erosion was the major cause of failure of the boiler tubes. There were over 40,000 separately measured data points in the data and all were collected with some care and expense. In the development of maintenance strategies for equipment, this type of data is typical of the data that must be collected and assessed. This data thus represents an opportunity to evaluate the ability to generate a useful risk approach to the management of the tubing. An important example of a risk-based approach is the American Petroleum Institute (API) Risk Based Inspection ('RBI'), API 581. A variety of problems were encountered applying this to boiler tubes. The problems include irrelevant API 581 corrosion rate tables, lack of information on how to analyse inspection data, difficulty of dealing with multiple inspection categories and lack of suitable direction for programming inspection intervals

  20. High temperature corrosion in straw-fired power plants: Influence of steam/metal temperature on corrosion rates for TP347H

    DEFF Research Database (Denmark)

    Montgomery, Melanie; Biede, O; Larsen, OH

    2002-01-01

    The corrosion in straw-fired boilers has been investigated at various straw-fired power plants in Denmark. Water/air-cooled probes, a test superheater and test sections removed from the actual superheater have been utilised to characterise corrosion and corrosion rates. This paper describes the...... difference in the results could be traced back to a lower flue gas temperature on one side of the boiler. Although metal temperature is the most important parameter with respect to corrosion rate, flue gas temperature also plays an important role. Efforts to quantify the effect of flue gas temperature on...

  1. NST Quarterly

    International Nuclear Information System (INIS)

    NST Quarterly reports current development in nuclear science and technology in Malaysia. It keeps readers informed on the progress of research, services, application of nuclear science and technology, and other technical news. It highlights MINT activities and also announces coming events

  2. Solid-phase extraction-gas chromatography and solid-phase extraction-gas chromatography-mass spectrometry determination of corrosion inhibiting long-chain primary alkyl amines in chemical treatment of boiler water in water-steam systems of power plants.

    Science.gov (United States)

    Kusch, Peter; Knupp, Gerd; Hergarten, Marcus; Kozupa, Marian; Majchrzak, Maria

    2006-04-28

    Gas chromatography with simultaneous flame-ionization detection (FID) and a nitrogen-phosphorus detection (NPD) as well as gas chromatography-mass spectrometry (GC/MS) has been used to characterize long-chain primary alkyl amines after derivatization with trifluoroacetic anhydride (TFAA). Electron impact ionization- (EI) and negative chemical ionization (NCI) mass spectra of trifluoroacetylated derivatives of the identified tert-octadecylamines are presented for the first time. The corrosion inhibiting alkyl amines were applied in a water-steam circuit of energy systems in the power industry. Solid-phase extraction (SPE) with octadecyl bonded silica (C18) sorbents followed by gas chromatography were used for quantification of the investigated tert-octadecylamines in boiler water, superheated steam and condensate samples from the power plant. The estimated values were: 89 microg l(-1)(n = 5, RSD = 7.8%), 45 microg l(-1) (n = 5, RSD = 5.4%) and 37 microg l(-1)(n = 5, RSD = 2.3%), respectively. PMID:16483586

  3. MODELLING, SIMULATING AND OPTIMIZING BOILERS

    DEFF Research Database (Denmark)

    Sørensen, K.; Condra, T.; Houbak, Niels

    to operate a boiler plant dynamically means that the boiler designs must be able to absorb any fluctuations in water level and temperature gradients resulting from the pressure change in the boiler. On the one hand a large water-/steam space may be required, i.e. to build the boiler as big as......This paper describes the modelling, simulating and optimizing including experimental verification as being carried out as part of a Ph.D. project being written resp. supervised by the authors. The work covers dynamic performance of both water-tube boilers and fire tube boilers. A detailed dynamic...... model of the boiler has been developed and simulations carried out by means of the Matlab integration routines. The model is prepared as a dynamic model consisting of both ordinary differential equations and algebraic equations, together formulated as a Differential-Algebraic-Equation system. Being able...

  4. MODELLING, SIMULATING AND OPTIMIZING BOILERS

    DEFF Research Database (Denmark)

    Sørensen, K.; Condra, T.; Houbak, Niels

    This paper describes the modelling, simulating and optimizing including experimental verification as being carried out as part of a Ph.D. project being written resp. supervised by the authors. The work covers dynamic performance of both water-tube boilers and fire tube boilers. A detailed dynamic...... model of the boiler has been developed and simulations carried out by means of the Matlab integration routines. The model is prepared as a dynamic model consisting of both ordinary differential equations and algebraic equations, together formulated as a Differential-Algebraic-Equation system. Being able...... to operate a boiler plant dynamically means that the boiler designs must be able to absorb any fluctuations in water level and temperature gradients resulting from the pressure change in the boiler. On the one hand a large water-/steam space may be required, i.e. to build the boiler as big as...

  5. Modelling, simulating and optimizing Boilers

    DEFF Research Database (Denmark)

    Sørensen, Kim; Condra, Thomas Joseph; Houbak, Niels

    2003-01-01

    This paper describes the modelling, simulating and optimizing including experimental verication as being carried out as part of a Ph.D. project being written resp. supervised by the authors. The work covers dynamic performance of both water-tube boilers and re tube boilers. A detailed dynamic model...... of the boiler has been developed and simulations carried out by means of the Matlab integration routines. The model is prepared as a dynamic model consisting of both ordinary differential equations and algebraic equations, together formulated as a Differential-Algebraic- Equation system. Being able...... to operate a boiler plant dynamically means that the boiler designs must be able to absorb any uctuations in water level and temperature gradients resulting from the pressure change in the boiler. On the one hand a large water-/steam space may be required, i.e. to build the boiler as big as possible...

  6. Corrosion products in power generating systems

    International Nuclear Information System (INIS)

    The important mechanisms of corrosion and corrosion product movement and fouling in the heat transport systems of thermal electric generating stations are reviewed. Oil- and coal-fired boilers are considered, along with nuclear power systems - both direct and indirect cycle. Thus, the fireside and waterside in conventional plants, and the primary coolant and steam-raising circuits in water-cooled reactors, are discussed. Corrosion products in organic- and liquid-metal-cooled reactors also are shown to cause problems if not controlled, while their beneficial effects on the cooling water side of condensers are described. (auth)

  7. Optimization of Load Assignment to Boilers in Industrial Boiler Plants

    Institute of Scientific and Technical Information of China (English)

    CAO Jia-cong; QIU Guang; CAO Shuang-hua; LIU Feng-qiang

    2004-01-01

    Along with the increasing importance of sustainable energy, the optimization of load assignment to boilers in an industrial boiler plant becomes one of the major projects for the optimal operation of boiler plants. Optimal load assignment for power systems has been a long-lasting subject, while it is quite new for industrial boiler plants. The existing methods of optimal load assignment for boiler plants are explained and analyzed briefly in the paper. They all need the fuel cost curves of boilers. Thanks to some special features of the curves for industrial boilers, a new model referred to as minimized departure model (MDM) of optimization of load assignment for boiler plants is developed and proposed in the paper. It merely relies upon the accessible data of two typical working conditions to build the model, viz. the working conditions with the highest efficiency of a boiler and with no-load. Explanation of the algorithm of computer program is given, and effort is made so as to determine in advance how many and which boilers are going to work. Comparison between the results using MDM and the results reported in references is carried out, which proves that MDM is preferable and practicable.

  8. Steam generator corrosion 2007; Dampferzeugerkorrosion 2007

    Energy Technology Data Exchange (ETDEWEB)

    Born, M. (ed.)

    2007-07-01

    Between 8th and 9th November, 2007, SAXONIA Standortentwicklungs- und -verwertungsgesellschaft GmbH (Freiberg, Federal Republic of Germany) performed the 3rd Freiberger discussion conference ''Fireside boiler corrosion''. The topics of the lectures are: (a) Steam generator corrosion - an infinite history (Franz W. Alvert); (b) CFD computations for thermal waste treatment plants - a contribution for the damage recognition and remedy (Klaus Goerner, Thomas Klasen); (c) Experiences with the use of corrosion probes (Siegfried R. Horn, Ferdinand Haider, Barbara Waldmann, Ragnar Warnecke); (d) Use of additives for the limitation of the high temperature chlorine corrosion as an option apart from other measures to the corrosion protection (Wolfgang Spiegel); (e) Current research results and aims of research with respect to chlorine corrosion (Ragnar Warnecke); (f) Systematics of the corrosion phenomena - notes for the enterprise and corrosion protection (Thomas Herzog, Wolfgang Spiegel, Werner Schmidl); (g) Corrosion protection by cladding in steam generators of waste incinerators (Joerg Metschke); (h) Corrosion protection and wear protection by means of thermal spraying in steam generators (Dietmar Bendix); (i) Review of thick film nickelized components as an effective protection against high-temperature corrosion (Johann-Wilhelm Ansey); (j) Fireproof materials for waste incinerators - characteristics and profile of requirement (Johannes Imle); (k) Service life-relevant aspects of fireproof linings in the thermal recycling of waste (Till Osthoevener and Wolfgang Kollenberg); (l) Alternatives to the fireproof material in the heating space (Heino Sinn); (m) Cladding: Inconal 625 contra 686 - Fundamentals / applications in boiler construction and plant construction (Wolfgang Hoffmeister); (n) Thin films as efficient corrosion barriers - thermal spray coating in waste incinerators and biomass firing (Ruediger W. Schuelein, Steffen Hoehne, Friedrich

  9. Effect of dissolved oxygen on denting corrosion

    International Nuclear Information System (INIS)

    The following conclusions are drawn from the study of the effects of dissolved oxygen on corrosion denting: 1) Following the ingress of fresh-water contamination into a PWR boiler, an acidic chloride solution can be formed in the crevice between tube and tube support plate when an oxidant such as dissolved oxygen or copper ions is present in the boiler water. 2) In the absence of copper, very high levels of dissolved oxygen and neutral chloride are necessary to initiate corrosion. 3) When copper is present in the feed system, sufficient copper ions to initiate corrosion within the crevice are released when the chloride concentration is 0.8 mg/kg and probably also at lower chloride values. Corrosion initiation however may require prior exposure of the copper to dissolved oxygen and can be suppressed by pretreatment with hydrazine. 4) The effect of dissolved oxygen on corrosion already occurring was not explored; neither was the effect of dissolved oxygen on corrosion by acid-forming contamination such as sea-water. In both cases, corrosion rates are likely to be enhanced by the presence of dissolved oxygen

  10. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    Energy Technology Data Exchange (ETDEWEB)

    R. Viswanathan; K. Coleman; J. Shingledecker; J. Sarver; G. Stanko; M. Borden; W. Mohn; S. Goodstine; I. Perrin

    2005-08-01

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). A limiting factor in this can be the materials of construction. The project goal is to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi). This goal seems achievable based on a preliminary assessment of material capabilities. The project is further intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of April 1 to June 30, 2005.

  11. Boiler Materials for Ultrasupercritical Coal Power Plants

    Energy Technology Data Exchange (ETDEWEB)

    R. Viswanathan; J. Sarver; M. Borden; K. Coleman; J. Blough; S. Goodstine; R.W. Swindeman; W. Mohn; I. Perrin

    2003-04-21

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). The project goal initially was to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi), although this goal for the main steam temperature had to be revised down to 732 C (1350 F), based on a preliminary assessment of material capabilities. The project is intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of July 1 to September 30, 2004.

  12. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    Energy Technology Data Exchange (ETDEWEB)

    R. Viswanathan; K. Coleman; J. Shingledecker; J. Sarver; G. Stanko; M. Borden; W. Mohn; S. Goodstine; I. Perrin

    2005-10-27

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). A limiting factor in this can be the materials of construction. The project goal is to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi). This goal seems achievable based on a preliminary assessment of material capabilities. The project is further intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of July 1 to September 30, 2005.

  13. Boiler Materials for Ultrasupercritical Coal Power Plants

    Energy Technology Data Exchange (ETDEWEB)

    R. Viswanathan; K. Coleman; J. Shingledecker; J. Sarver; G. Stanko; M. Borden; W. Mohn; S. Goodstine; I. Perrin

    2006-01-31

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). A limiting factor in this can be the materials of construction. The project goal is to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi). This goal seems achievable based on a preliminary assessment of material capabilities. The project is further intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of October 1 to December 30, 2005.

  14. Boiler Materials for Ultrasupercritical Coal Power Plants

    Energy Technology Data Exchange (ETDEWEB)

    R. Viswanathan; K. Coleman; J. Shingledecker; J. Sarver; G. Stanko; M. Borden; W. Mohn; S. Goodstine; I. Perrin

    2006-04-20

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). A limiting factor in this can be the materials of construction. The project goal is to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi). This goal seems achievable based on a preliminary assessment of material capabilities. The project is further intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of January 1 to March 31, 2006.

  15. Boiler Materials for Ultrasupercritical Coal Power Plants

    Energy Technology Data Exchange (ETDEWEB)

    R. Viswanathan; K. Coleman; J. Shingledecker; J. Sarver; G. Stanko; M. Borden; W. Mohn; S. Goodstine; I. Perrin

    2006-07-17

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). A limiting factor in this can be the materials of construction. The project goal is to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi). This goal seems achievable based on a preliminary assessment of material capabilities. The project is further intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of April 1 to June 30, 2006.

  16. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    Energy Technology Data Exchange (ETDEWEB)

    R. Viswanathan; K. Coleman; J. Shingledecker; J. Sarver; G. Stanko; W. Mohn; M. Borden; S. Goodstine; I. Perrin

    2004-04-23

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). The project goal initially was to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi), although this goal for the main steam temperature had to be revised down to 732 C (1350 F), based on a preliminary assessment of material capabilities. The project is intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of October 1 to December 30, 2003.

  17. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    Energy Technology Data Exchange (ETDEWEB)

    K. Coleman; R. Viswanathan; J. Shingledecker; J. Sarver; G. Stanko; W. Mohn; M. Borden; S. Goodstine; I. Perrin

    2004-01-23

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). The project goal initially was to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi), although this goal for the main steam temperature had to be revised down to 732 C (1350 F), based on a preliminary assessment of material capabilities. The project is intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of October 1 to December 30, 2003.

  18. Boiler Materials For Ultrasupercritical Coal Power Plants

    Energy Technology Data Exchange (ETDEWEB)

    R. Viswanathan; K. Coleman; J. Shingledecker; J. Sarver; G. Stanko; M. Borden; W. Mohn; S. Goodstine; I. Perrin

    2006-09-30

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). A limiting factor in this can be the materials of construction. The project goal is to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi). This goal seems achievable based on a preliminary assessment of material capabilities. The project is further intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of July 1 to September 30, 2006.

  19. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    Energy Technology Data Exchange (ETDEWEB)

    R. Viswanathan; K. Coleman; J. Shingledecker; J. Sarver; G. Stanko; M. Borden; W. Mohn; S. Goodstine; I. Perrin

    2005-04-27

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). The project goal initially was to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi), although this goal for the main steam temperature had to be revised down to 732 C (1350 F), based on a preliminary assessment of material capabilities. The project is intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of July 1 to September 30, 2004.

  20. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    Energy Technology Data Exchange (ETDEWEB)

    R. Viswanathan; K. Coleman; J. Shingledecker; J. Sarver; G. Stanko; M. Borden; W. Mohn; S. Goodstine; I. Perrin

    2004-10-30

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). The project goal initially was to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi), although this goal for the main steam temperature had to be revised down to 732 C (1350 F), based on a preliminary assessment of material capabilities. The project is intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of April to June 30, 2004.

  1. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    Energy Technology Data Exchange (ETDEWEB)

    R. Viswanathan; K. Coleman; J. Shingledecker; J. Sarver; G. Stanko; W. Mohn; M. Borden; S. Goodstine; I. Perrin

    2004-07-30

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). The project goal initially was to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi), although this goal for the main steam temperature had to be revised down to 732 C (1350 F), based on a preliminary assessment of material capabilities. The project is intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of April to June 30, 2004.

  2. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    Energy Technology Data Exchange (ETDEWEB)

    R. Viswanathan; K. Coleman; J. Shingledecker; J. Sarver; G. Stanko; M. Borden; W. Mohn; S. Goodstine; I. Perrin

    2005-01-31

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). The project goal initially was to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi), although this goal for the main steam temperature had to be revised down to 732 C (1350 F), based on a preliminary assessment of material capabilities. The project is intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of July 1 to September 30, 2004.

  3. EXPERIMENTAL INVESTIGATION OF NICKEL ALUMINIDE (NI3AL) NANOSTRUCTURED COATED ECONOMISER TUBE IN BOILER

    OpenAIRE

    * Gokulakannan A, Karuppasamy K

    2016-01-01

    Thermal Power Stations all over the world are facing the problem of boiler tube leakage frequently. The consequences of which affects the performance of power plant and huge amount of money loss. Hot corrosion and erosion are recognized as serious problems in coal based power generation plants in India. The maximum number of cause of failure in economizer unit is due to flue gas erosion. The corrosion resistant coatings used conventionally are having some limitations like degradation of the c...

  4. Optimising boiler performance.

    Science.gov (United States)

    Mayoh, Paul

    2009-01-01

    Soaring fuel costs continue to put the squeeze on already tight health service budgets. Yet it is estimated that combining established good practice with improved technologies could save between 10% and 30% of fuel costs for boilers. Paul Mayoh, UK technical manager at Spirax Sarco, examines some of the practical measures that healthcare organisations can take to gain their share of these potential savings. PMID:19192603

  5. Composite tube cracking in kraft recovery boilers: A state-of-the-art review

    Energy Technology Data Exchange (ETDEWEB)

    Singbeil, D.L.; Prescott, R. [Pulp and Paper Research Inst. of Canada, Vancouver, British Columbia (Canada); Keiser, J.R.; Swindeman, R.W. [Oak Ridge National Lab., TN (United States)

    1997-07-01

    Beginning in the mid-1960s, increasing energy costs in Finland and Sweden made energy recovery more critical to the cost-effective operation of a kraft pulp mill. Boiler designers responded to this need by raising the steam operating pressure, but almost immediately the wall tubes in these new boilers began to corrode rapidly. Test panels installed in the walls of the most severely corroding boiler identified austenitic stainless steel as sufficiently resistant to the new corrosive conditions, and discussions with Sandvik AB, a Swedish tube manufacturer, led to the suggestion that coextruded tubes be used for water wall service in kraft recovery boilers. Replacement of carbon steel by coextruded tubes has solved most of the corrosion problems experienced by carbon steel wall tubes, however, these tubes have not been problem-free. Beginning in early 1995, a multidisciplinary research program funded by the US Department of Energy was established to investigate the cause of cracking in coextruded tubes and to develop improved materials for use in water walls and floors of kraft recovery boilers. One portion of that program, a state-of-the-art review of public- and private-domain documents related to coextruded tube cracking in kraft recovery boilers is reported here. Sources of information that were consulted for this review include the following: tube manufacturers, boiler manufacturers, public-domain literature, companies operating kraft recovery boilers, consultants and failure analysis laboratories, and failure analyses conducted specifically for this project. Much of the information contained in this report involves cracking problems experienced in recovery boiler floors and those aspects of spout and air-port-opening cracking not readily attributable to thermal fatigue. 61 refs.

  6. High temperature corrosion of metals

    International Nuclear Information System (INIS)

    This paper covers three main topics: 1. high temperature oxidation of metals and alloys, 2. corrosion in sulfur containing environments and 3. structural changes caused by corrosion. The following 21 subjects are discussed: Influence of implanted yttrium and lanthanum on the oxidation behaviour of beta-NiA1; influence of reactive elements on the adherence and protective properties of alumina scales; problems related to the application of very fine markers in studying the mechanism of thin scale formation; oxidation behaviour of chromia forming Co-Cr-Al alloys with or without reactive element additions; growth and properties of chromia-scales on high-temperature alloys; quantification of the depletion zone in high temperature alloys after oxidation in process gas; effects of HC1 and of N2 in the oxidation of Fe-20Cr; investigation under nuclear safety aspects of Zircaloy-4 oxidation kinetics at high temperatures in air; on the sulfide corrosion of metallic materials; high temperature sulfide corrosion of Mn, Nb and Nb-Si alloys; corrosion behaviour or NiCrAl-based alloys in air and air-SO2 gas mixtures; sulfidation of cobalt at high temperatures; preoxidation for sulfidation protection; fireside corrosion and application of additives in electric utility boilers; transport properties of scales with complex defect structures; observations of whiskers and pyramids during high temperature corrosion of iron in SO2; corrosion and creep of alloy 800H under simulated coal gasification conditions; microstructural changes of HK 40 cast alloy caused by exploitation in tubes in steam reformer installation; microstructural changes during exposure in corrosive environments and their effect on mechanical properties; coatings against carburization; mathematical modeling of carbon diffusion and carbide precipitation in Ni-Cr-based alloys. (MM)

  7. Super Boiler 2nd Generation Technology for Watertube Boilers

    Energy Technology Data Exchange (ETDEWEB)

    Mr. David Cygan; Dr. Joseph Rabovitser

    2012-03-31

    This report describes Phase I of a proposed two phase project to develop and demonstrate an advanced industrial watertube boiler system with the capability of reaching 94% (HHV) fuel-to-steam efficiency and emissions below 2 ppmv NOx, 2 ppmv CO, and 1 ppmv VOC on natural gas fuel. The boiler design would have the capability to produce >1500 F, >1500 psig superheated steam, burn multiple fuels, and will be 50% smaller/lighter than currently available watertube boilers of similar capacity. This project is built upon the successful Super Boiler project at GTI. In that project that employed a unique two-staged intercooled combustion system and an innovative heat recovery system to reduce NOx to below 5 ppmv and demonstrated fuel-to-steam efficiency of 94% (HHV). This project was carried out under the leadership of GTI with project partners Cleaver-Brooks, Inc., Nebraska Boiler, a Division of Cleaver-Brooks, and Media and Process Technology Inc., and project advisors Georgia Institute of Technology, Alstom Power Inc., Pacific Northwest National Laboratory and Oak Ridge National Laboratory. Phase I of efforts focused on developing 2nd generation boiler concepts and performance modeling; incorporating multi-fuel (natural gas and oil) capabilities; assessing heat recovery, heat transfer and steam superheating approaches; and developing the overall conceptual engineering boiler design. Based on our analysis, the 2nd generation Industrial Watertube Boiler when developed and commercialized, could potentially save 265 trillion Btu and $1.6 billion in fuel costs across U.S. industry through increased efficiency. Its ultra-clean combustion could eliminate 57,000 tons of NOx, 460,000 tons of CO, and 8.8 million tons of CO2 annually from the atmosphere. Reduction in boiler size will bring cost-effective package boilers into a size range previously dominated by more expensive field-erected boilers, benefiting manufacturers and end users through lower capital costs.

  8. DOWNSCALE APPLICATION OF BOILER THERMAL CALCULATION APPROACH

    OpenAIRE

    Zelený, Zbynĕk; Hrdlička, Jan

    2016-01-01

    Commonly used thermal calculation methods are intended primarily for large scale boilers. Hot water small scale boilers, which are commonly used for home heating have many specifics, that distinguish them from large scale boilers especially steam boilers. This paper is focused on application of thermal calculation procedure that is designed for large scale boilers, on a small scale boiler for biomass combustion of load capacity 25 kW. Special issue solved here is influence of formation of dep...

  9. Small boiler uses waste coal

    Energy Technology Data Exchange (ETDEWEB)

    Virr, M.J. [Spinheat Ltd. (United States)

    2009-07-15

    Burning coal waste in small boilers at low emissions poses considerable problem. While larger boiler suppliers have successfully installed designs in the 40 to 80 MW range for some years, the author has been developing small automated fluid bed boiler plants for 25 years that can be applied in the range of 10,000 to 140,000 lbs/hr of steam. Development has centered on the use of an internally circulating fluid bed (CFB) boiler, which will burn waste fuels of most types. The boiler is based on the traditional D-shaped watertable boiler, with a new type of combustion chamber that enables a three-to-one turndown to be achieved. The boilers have all the advantages of low emissions of the large fluid boilers while offering a much lower height incorporated into the package boiler concept. Recent tests with a waste coal that had a high nitrogen content of 1.45% demonstrated a NOx emission below the federal limit of 0.6 lbs/mm Btu. Thus a NOx reduction on the order of 85% can be demonstrate by combustion modification alone. Further reductions can be made by using a selective non-catalytic reduction (SNCR) system and sulfur absorption of up to 90% retention is possible. The article describes the operation of a 30,000 lbs/hr boiler at the Fayette Thermal LLC plant. Spinheat has installed three ICFB boilers at a nursing home and a prison, which has been tested on poor-grade anthracite and bituminous coal. 2 figs.

  10. Computational Modeling and Assessment Of Nanocoatings for Ultra Supercritical Boilers

    Energy Technology Data Exchange (ETDEWEB)

    David W. Gandy; John P. Shingledecker

    2011-04-11

    Forced outages and boiler unavailability in conventional coal-fired fossil power plants is most often caused by fireside corrosion of boiler waterwalls. Industry-wide, the rate of wall thickness corrosion wastage of fireside waterwalls in fossil-fired boilers has been of concern for many years. It is significant that the introduction of nitrogen oxide (NOx) emission controls with staged burners systems has increased reported waterwall wastage rates to as much as 120 mils (3 mm) per year. Moreover, the reducing environment produced by the low-NOx combustion process is the primary cause of accelerated corrosion rates of waterwall tubes made of carbon and low alloy steels. Improved coatings, such as the MCrAl nanocoatings evaluated here (where M is Fe, Ni, and Co), are needed to reduce/eliminate waterwall damage in subcritical, supercritical, and ultra-supercritical (USC) boilers. The first two tasks of this six-task project-jointly sponsored by EPRI and the U.S. Department of Energy (DE-FC26-07NT43096)-have focused on computational modeling of an advanced MCrAl nanocoating system and evaluation of two nanocrystalline (iron and nickel base) coatings, which will significantly improve the corrosion and erosion performance of tubing used in USC boilers. The computational model results showed that about 40 wt.% is required in Fe based nanocrystalline coatings for long-term durability, leading to a coating composition of Fe-25Cr-40Ni-10 wt.% Al. In addition, the long term thermal exposure test results further showed accelerated inward diffusion of Al from the nanocrystalline coatings into the substrate. In order to enhance the durability of these coatings, it is necessary to develop a diffusion barrier interlayer coating such TiN and/or AlN. The third task 'Process Advanced MCrAl Nanocoating Systems' of the six-task project jointly sponsored by the Electric Power Research Institute, EPRI and the U.S. Department of Energy (DE-FC26-07NT43096)- has focused on

  11. COMBINED BOILER WITH TPV

    OpenAIRE

    Björk, Magnus

    2013-01-01

    A TPV-system consists of a hot surface emitting heat radiation on a solar cell with a narrow bandgap.  A unit consisting of a boiler and a TPV-system has been constructed for testing of the performance of TPV cells. The emitter is heated by a fuel consisting of RME-oil. The radiation is collected and concentrated through two reflecting cones formed like a Faberge-egg, with an edge-type optical filter between the cones. The Faberge-egg is treated with electro-polishing in order to obtain a hig...

  12. Boilers a practical reference

    CERN Document Server

    Rayaprolu, Kumar

    2012-01-01

    AAbrasion and Abrasion Index (see Wear)Absolute or Dynamic Viscosity (æ) (see Viscosity in Fluid Characteristics)Acid Cleaning (see Commissioning)Acid Rain (also see Air Pollution Emissions and Controls and Gas Cleaning)Acid Sludge (see Refuse Fuels from Refinery in Liquid Fuels)Acid Smuts (see Oil Ash)Acoustic Soot Blowers (see Sonic Horns)Acoustic Enclosure (see Noise Control)Acoustic Leak Detection SystemAdiabatic Flame Temperature (see Combustion)Aeroderivative (see Types of GTs in Turbines, Gas)Ageing of Boiler ComponentsAgro-Fuels and FiringAir Ducts (see Draught Plant)Air Flow Measureme

  13. Boiler for ships; Hakuyo boira

    Energy Technology Data Exchange (ETDEWEB)

    Shimoda, F. [Mitsubishi Heavy Industries, Ltd., Tokyo (Japan)

    1999-07-20

    In this paper, production and technology trend of boiler for ships in 1998 are described. The actual results of main boiler are as follows. As the main boiler for LNG ships, 4 boilers produced by Mitsui Engineering and Shipbuilding for Qatar Project, 8 produced by Kawasaki Heavy Industries for South Korea and 10 produced by Mitsubishi Heavy Industries for domestic use and South Korea. 1998 was an active year for the main boiler for ships. The auxiliary boiler of steam pressure of 16k to 25k equipping for tanker ships was 115 (4,441t/h of steam quantity in total), it greatly increased in comparison with 88 (3,172t/h) produced in the proceeding year. Donkey boilers of steam pressure of 6k to 10k equipping for container ships and bulk cargo was 147 (672t/h), and it substantially decreased in comparison with 274 (693t/h) of the proceeding year, but capacity per boiler increased. The gas exhaust economizer for turbo power generation plants was 6 produced for VLCC. (NEDO)

  14. High Temperature Behavior of Cr3C2-NiCr Coatings in the Actual Coal-Fired Boiler Environment

    Science.gov (United States)

    Bhatia, Rakesh; Sidhu, Hazoor Singh; Sidhu, Buta Singh

    2015-03-01

    Erosion-corrosion is a serious problem observed in steam-powered electricity generation plants, and industrial waste incinerators. In the present study, four compositions of Cr3C2-(Ni-20Cr) alloy coating powder were deposited by high-velocity oxy-fuel spray technique on T-91 boiler tube steel. The cyclic studies were performed in a coal-fired boiler at 1123 K ± 10 K (850 °C ± 10 °C). X-ray diffraction, scanning electron microscopy/energy dispersive X-ray analysis and elemental mapping analysis techniques were used to analyze the corrosion products. All the coatings deposited on T-91 boiler tube steel imparted hot corrosion resistance. The 65 pctCr3C2 -35 pct (Ni-20Cr)-coated T-91 steel sample performed better than all other coated samples in the given environment.

  15. METHANE DE-NOX FOR UTILITY PC BOILERS

    International Nuclear Information System (INIS)

    The project seeks to develop and validate a new pulverized coal combustion system to reduce utility PC boiler NO(sub x) emissions to 0.15 lb/million Btu or less without post-combustion flue gas cleaning. Work during the quarter included completion of the equipment fabrication and installation efforts for the 3-million Btu/h pilot system at BBP's Pilot-Scale Combustion Facility (PSCF) in Worcester, MA. Selection and procurement of the first two test coals and preliminary selection of the final two test coals were completed. Shakedown and commissioning activities were finished and PC Preheat pilot scale tests commenced with PRB coal

  16. Pellet wood gasification boiler / Combination boiler. Market review. 7. ed.; Scheitholzvergaser-/Kombikessel. Marktuebersicht

    Energy Technology Data Exchange (ETDEWEB)

    Uth, Joern

    2010-08-15

    In the market review under consideration on pellet wood gasification boilers and combination boilers, the Federal Ministry of Food, Agriculture and Consumer Protection (Bonn, Federal Republic of Germany) report on planning and installation of wood-fired heating systems, recommendations regarding to the technical assessment of boiler systems, buffers/combination boilers, prices of pellet wood gasification boilers, data sheets of the compared pellet wood gasification boilers, pellet wood combination boilers, prices of pellet wood combination boilers, data sheets of the compared pellet wood gasification boilers, list of providers.

  17. Market review. Pellet wood gasification boiler / combination boiler. 8. ed.; Marktuebersicht. Scheitholzvergaser-/Kombikessel

    Energy Technology Data Exchange (ETDEWEB)

    Uth, Joern

    2012-01-15

    In the market review under consideration on pellet wood gasification boilers and combination boilers, the Federal Ministry of Food, Agriculture and Consumer Protection (Bonn, Federal Republic of Germany) reports on planning and installation of wood-fired heating systems, recommendations regarding to the technical assessment of boiler systems, buffers/combination boilers, prices of pellet wood gasification boilers, data sheets of the compared pellet wood gasification boilers, pellet wood combination boilers, prices of pellet wood combination boilers, data sheets of the compared pellet wood gasification boilers, list of providers.

  18. Corrosion-product inventory: the Bruce-B secondary system

    International Nuclear Information System (INIS)

    Corrosion inspection and corrosion-product characterization in water and steam systems are important for component and systems maintenance in nuclear power stations. Corrosion products are produced, released and redeposited at various sites in the secondary system. Depending on the alloys used in the condenser and feedwater heaters, particulate iron oxides and hydroxides can account for about 95-99% of the total corrosion-product transport. Where brass or cupro-nickel alloys are present, copper and zinc contribute significantly to the total transport and deposition. Particulates are transported by the feedwater to the steam generators, where they accumulate and can cause a variety of problems, such as loss of heat transfer capability through deposition on boiler tubes, blockage of flow through boiler-tube support plates and accelerated corrosion in crevices, either in deep sludge piles or at blocked tube supports. The influx of oxidized corrosion products may have a particularly adverse effect on the redox environment of steam generator tubing, thereby increasing the probability of localized corrosion and other degradation mechanisms. In this paper, there is a description of a survey of general corrosion deposits in Bruce-B, Units 5-8, which helps to identify the origin, evolution and inventory of corrosion products along the secondary system of Candu reactors

  19. Failure analyses and weld repair of boiler feed water pumps

    Energy Technology Data Exchange (ETDEWEB)

    Vulpen, R. van [KemaPower Generation, Arnhem (Netherlands)

    1998-12-31

    During a regular inspection of the Boiler Auxiliaries at one of the Dutch Electricity Production Companies serious cracks were found in the cover and casings of the feed water circulation pumps in two units after 108.000 and 122.000 hours of boiler operation. Kema Laboratories carried out Failure analyses on boat samples at the cracked areas. Corrosion fatigue cracking was found on the inner side of the GS-24CrNiMo325 casing. Shop Weld repairs were carried out using a newly developed mechanized Plasma Welding Technique. The repaired feed water circulation pumps showed no problems alter several years of operation. The costs of repair were substantially lower than the costs of replacement. (orig.) 3 refs.

  20. NOx CONTROL OPTIONS AND INTEGRATION FOR US COAL FIRED BOILERS

    Energy Technology Data Exchange (ETDEWEB)

    Mike Bockelie; Marc Cremer; Kevin Davis; Temi Linjewile; Connie Senior; Hong-Shig Shim; Bob Hurt; Eric Eddings; Larry Baxter

    2003-01-30

    This is the tenth Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NO{sub x} control strategies and their possible impact on boiler performance for firing US coals. The Electric Power Research Institute (EPRI) is providing cofunding for this program. This program contains multiple tasks and good progress is being made on all fronts. During this quarter, progress was made on the computational simulation of a full-scale boiler with the purpose of understanding the potential impacts of burner operating conditions on soot and NO{sub x} generation. Sulfation tests on both the titania support and vanadia/titania catalysts were completed using BYU's in situ spectroscopy reactor this quarter. These experiments focus on the extent to which vanadia and titania sulfate in an SO{sub 2}-laden, moist environment. Construction of the CCS reactor system is essentially complete and the control hardware and software are largely in place. A large batch of vanadia/titania catalyst in powder form has been prepared for use in poisoning tests. During this quarter, minor modifications were made to the multi-catalyst slipstream reactor and to the control system. The slipstream reactor was installed at AEP's Rockport plant at the end of November 2002. In this report, we describe the reactor system, particularly the control system, which was created by REI specifically for the reactor, as well as the installation at Rockport.

  1. Summary of workshop on materials issues associated with low-NO{sub x} combustion conditions in fossil-fired boilers

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-08-01

    It was anticipated by some members of the high-temperature corrosion community that the fitting of low-NO{sub x} burners to coal-fired power plants would lead to an increase in furnace wall corrosion, as a result of the relatively substoichiometric conditions created by the staged combustion process. These expectations were not borne out by initial experience. Recently, however, cases of severe furnace wall corrosion have been reported by some U.S. utility boilers retrofitted with modern low-NO{sub x} burners. There is extensive experience of furnace wall corrosion in utility boilers in the U.K., which indicates that excessive fireside corrosion rates (>200 nm/hr; 34 mil/yr) are experienced when tubes are exposed simultaneously to substoichiometric gaseous environments (CO>3.0 percent) and high radiant heat fluxes. Such conditions may be generated when flame impingement occurs. Where such conditions persist, increases in fuel chlorine content will exacerbate the rate of metal loss. In the absence of either circumstances, corrosion rates are much reduced and little influence of coal chlorine content is anticipated. Although the corrosion is essentially sulfidation caused by H{sub 2}S in the flue gas, the contribution of fuel sulfur in the corrosion experience by U.K. boilers is unresolved, partly because of the relatively small range in sulfur content of coals burned in U.K. utility boilers. The intent of this workshop was three-fold: to better define the problem in terms of the form and rate of attack; to examine what is known about its root causes; and to review the potential for using corrosion-resistant materials as part of the solution.

  2. Organic Contaminants and Treatment Chemicals in Steam-Water Cycles: Thermal stability, decomposition products and flow-accelerated corrosion

    OpenAIRE

    D. H. Moed

    2015-01-01

    Boiler feedwater and steam have to be of high purity, because of the susceptibility of the steam-water cycle to corrosion. Organic contaminants break down in boilers by hydrothermolysis, leading to the formation of organic acid anions, which are suspected to cause corrosion of steam-water cycle components. The impact and behavior of organic decomposition products in the steam-water cycle are not well understood. While guidelines for organic contaminants are becoming stricter, organic treatmen...

  3. CFB boilers in multifuel application

    International Nuclear Information System (INIS)

    Fuel flexibility characteristic for CFB boilers plays an important rule in industrial and utility size applications. Possibility to use wider range of fuels that has been long time considered as by-products or wastes and possibility to design boilers able to operate with alternative fuels is an important factor that improves fuel delivery security and plant economy. Presented article is based on similar publications that present Foster Wheeler's experience in design and delivery of the CFB boilers for wide range of coals and cofiring by- products of crude oil refining and coal processing. Aspects of biomass cofiring will be also presented. (author)

  4. Corrosion protection

    International Nuclear Information System (INIS)

    This invention describes a corrosion protection device for long-term storage containers of radioactive matter, in particular of irradiated fuel elements stored in geological formations apt for the purpose. This device prevents corrosion of the containers even if water emerges unexpectedly, or, in any case, inhibits and minimizes corrosion. The device comprehends reactive anodes that are connected to the containers by means of conductive connections. (orig.)

  5. Final Report, Materials for Industrial Heat Recovery Systems, Tasks 3 and 4 Materials for Heat Recovery in Recovery Boilers

    Energy Technology Data Exchange (ETDEWEB)

    Keiser, James R.; Kish, Joseph R.; Singh, Preet M.; Sarma, Gorti B.; Yuan, Jerry; Gorog, J. Peter; Frederick, Laurie A.; Jette, Francois R.; Meisner, Roberta A.; Singbeil, Douglas L.

    2007-12-31

    The DOE-funded project on materials for industrial heat recovery systems included four research tasks: materials for aluminum melting furnace recuperator tubes, materials and operational changes to prevent cracking and corrosion of the co-extruded tubes that form primary air ports in black liquor recovery boilers, the cause of and means to prevent corrosion of carbon steel tubes in the mid-furnace area of recovery boilers, and materials and operational changes to prevent corrosion and cracking of recovery boiler superheater tubes. Results from studies on the latter two topics are given in this report while separate reports on results for the first two tasks have already been published. Accelerated, localized corrosion has been observed in the mid-furnace area of kraft recovery boilers. This corrosion of the carbon steel waterwall tubes is typically observed in the vicinity of the upper level of air ports where the stainless clad co-extruded wall tubes used in the lower portion of the boiler are welded to the carbon steel tubes that extend from this transition point or “cut line” to the top of the boiler. Corrosion patterns generally vary from one boiler to another depending on boiler design and operating parameters, but the corrosion is almost always found within a few meters of the cut line and often much closer than that. This localized corrosion results in tube wall thinning that can reach the level where the integrity of the tube is at risk. Collection and analysis of gas samples from various areas near the waterwall surface showed reducing and sulfidizing gases were present in the areas where corrosion was accelerated. However, collection of samples from the same areas at intervals over a two year period showed the gaseous environment in the mid-furnace section can cycle between oxidizing and reducing conditions. These fluctuations are thought to be due to gas flow instabilities and they result in an unstable or a less protective scale on the carbon steel

  6. Development of automatic inspection robot for boiler tubes using EMAT

    International Nuclear Information System (INIS)

    In this study, a mobile robotic system using NDT (Non-destructive testing) method is developed for automatic diagnosis of the boiler tubes. The developed mobile robot crawls the surface of the tubes and detects in-pipe defects such as pinholes, cracks and thickness reduction by corrosion and/or erosion using EMAT (Electro-magnetic Acoustic Transducer) sensors. Automation of fault detection by means of mobile robotic systems for large-scale structures helps to prevent significant troubles without danger of human beings under harmful environment. In this study a preliminary result with guided wave inspection for defect detection is shown.

  7. Hybrid model of steam boiler

    International Nuclear Information System (INIS)

    In the case of big energy boilers energy efficiency is usually determined with the application of the indirect method. Flue gas losses and unburnt combustible losses have a significant influence on the boiler's efficiency. To estimate these losses the knowledge of the operating parameters influence on the flue gases temperature and the content of combustible particles in the solid combustion products is necessary. A hybrid model of a boiler developed with the application of both analytical modelling and artificial intelligence is described. The analytical part of the model includes the balance equations. The empirical models express the dependence of the flue gas temperature and the mass fraction of the unburnt combustibles in solid combustion products on the operating parameters of a boiler. The empirical models have been worked out by means of neural and regression modelling.

  8. Boiler-turbine life extension

    Energy Technology Data Exchange (ETDEWEB)

    Natzkov, S. [TOTEMA, Ltd., Sofia (Bulgaria); Nikolov, M. [CERB, Sofia (Bulgaria)

    1995-12-01

    The design life of the main power equipment-boilers and turbines is about 105 working hours. The possibilities for life extension are after normatively regulated control tests. The diagnostics and methodology for Boilers and Turbines Elements Remaining Life Assessment using up to date computer programs, destructive and nondestructive control of metal of key elements of units equipment, metal creep and low cycle fatigue calculations. As well as data for most common damages and some technical decisions for elements life extension are presented.

  9. High-Temperature Behavior of a NiCr-Coated T91 Boiler Steel in the Platen Superheater of Coal-Fired Boiler

    Science.gov (United States)

    Chatha, Sukhpal Singh; Sidhu, Hazoor S.; Sidhu, Buta S.

    2013-06-01

    Ni-20Cr coating was deposited on T91 boiler tube steel by high-velocity oxy-fuel (HVOF) process to enhance high-temperature oxidation resistance. High-temperature performance of bare, as well as HVOF-coated steel specimens was evaluated for 1500 h under in the platen superheater zone of coal-fired boiler, where the temperature was around 900 °C. Experiments were carried out for 15 cycles, each of 100-h duration followed by 1-h cooling at ambient temperature. The extent of degradation of the specimens was assessed by the thickness loss and depth of internal corrosion attack. Ni-20Cr-coated steel performed better than the uncoated steel in actual boiler environment. The improved degradation resistance of Ni-20Cr coating can be attributed to the presence of Cr2O3 in the top oxide scale and dense microstructure.

  10. Developments and operational experience with ceramic boiler wall protection systems in fluidised bed boilers; Entwicklungen und Betriebserfahrungen mit keramischen Rohrwandschutzsystemen in der Wirbelschicht

    Energy Technology Data Exchange (ETDEWEB)

    Horn, Markus [Juenger + Graeter GmbH, Schwetzingen (Germany); Roschek, Dirk; Ipsen, Christoph [Stadtwerke Flensburg GmbH, Flensburg (Germany)

    2013-02-01

    More alternative fuels, such as biomass, refuse derived fuels, sewage sludge, meat and bone meal etc. are being used in conventional CFB power plants originally designed for coal combustion. However, co-combustion of these materials causes problems which are not always advantageous for continuous plant operation, i.e. mostly substantially higher fouling susceptibility of the plants was noticed. In some cases even a far greater tendency to boiler damage was observed as result of corrosion, erosion, and mechanical effects. Based on these constraints, the cooperation between Stadtwerke Flensburg and Juenger+Graeter (J+G) resulted in the development of a ceramic boiler wall protection system which would significantly reduce the susceptibility to boiler damage in the combustion chamber.

  11. NOx Control Options and Integration for US Coal Fired Boilers

    Energy Technology Data Exchange (ETDEWEB)

    Mike Bockelie; Marc Cremer; Kevin Davis; Martin Denison; Adel Sarofim; Connie Senior; Hong-Shig Shim; Dave Swenson; Bob Hurt; Eric Suuberg; Eric Eddings; Kevin Whitty; Larry Baxter; Calvin Bartholomew; William Hecker

    2006-06-30

    This is the Final Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project was to develop cost-effective analysis tools and techniques for demonstrating and evaluating low-NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) provided co-funding for this program. This project included research on: (1) In furnace NOx control; (2) Impacts of combustion modifications on boiler operation; (3) Selective Catalytic Reduction (SCR) catalyst testing and (4) Ammonia adsorption/removal on fly ash. Important accomplishments were achieved in all aspects of the project. Rich Reagent Injection (RRI), an in-furnace NOx reduction strategy based on injecting urea or anhydrous ammonia into fuel rich regions in the lower furnace, was evaluated for cyclone-barrel and PC fired utility boilers. Field tests successfully demonstrated the ability of the RRI process to significantly reduce NOx emissions from a staged cyclone-fired furnace operating with overfire air. The field tests also verified the accuracy of the Computational Fluid Dynamic (CFD) modeling used to develop the RRI design and highlighted the importance of using CFD modeling to properly locate and configure the reagent injectors within the furnace. Low NOx firing conditions can adversely impact boiler operation due to increased waterwall wastage (corrosion) and increased soot production. A corrosion monitoring system that uses electrochemical noise (ECN) corrosion probes to monitor, on a real-time basis, high temperature corrosion events within the boiler was evaluated. Field tests were successfully conducted at two plants. The Ohio Coal Development Office provided financial assistance to perform the field tests. To investigate soot behavior, an advanced model to predict soot production and destruction was implemented into an existing reacting CFD modeling tool. Comparisons between experimental data collected

  12. Stress corrosion cracking behaviour of gas tungsten arc welded super austenitic stainless steel joints

    OpenAIRE

    M. Vinoth Kumar; Balasubramanian, V.; S. RAJAKUMAR; Shaju K. Albert

    2015-01-01

    Super 304H austenitic stainless steel with 3% of copper posses excellent creep strength and corrosion resistance, which is mainly used in heat exchanger tubing of the boiler. Heat exchangers are used in nuclear power plants and marine vehicles which are intended to operate in chloride rich offshore environment. Chloride stress corrosion cracking is the most likely life limiting failure with austenitic stainless steel tubing. Welding may worsen the stress corrosion cracking susceptibility of t...

  13. CFD Simulation On CFBC Boiler

    Directory of Open Access Journals (Sweden)

    Amol S. Kinkar

    2015-02-01

    Full Text Available Abstract Heavy industrialization amp modernization of society demands in increasing of power cause to research amp develop new technology amp efficient utilization of existing power units. Variety of sources are available for power generation such as conventional sources like thermal hydro nuclear and renewable sources like wind tidal biomass geothermal amp solar. Out of these most common amp economical way for producing the power is by thermal power stations. Various industrial boilers plays an important role to complete the power generation cycle such as CFBC Circulating Fluidized Bed Combustion FBC Fluidized Bed Combustion AFBC Atmospheric Fluidized Bed Combustion Boiler CO Boiler RG amp WHR Boiler Waster heat recovery Boiler. This paper is intended to comprehensively give an account of knowledge related to refractory amp its failure in CFBC boiler with due effect of flue gas flow during operation on refractory by using latest technology of CAD Computer aided Design amp CAE Computer aided Engineering. By conceptual application of these technology the full scale model is able to analyze in regards the flow of flue gas amp bed material flow inside the CFBC loop via CFD Computational Fluid Dynamics software. The results obtained are helpful to understand the impact of gas amp particles on refractory in different areas amp also helped to choose suitable refractory material in different regions.

  14. Corrosion Engineering.

    Science.gov (United States)

    White, Charles V.

    A description is provided for a Corrosion and Corrosion Control course offered in the Continuing Engineering Education Program at the General Motors Institute (GMI). GMI is a small cooperative engineering school of approximately 2,000 students who alternate between six-week periods of academic study and six weeks of related work experience in…

  15. Co-firing straw and coal in a 150-MWe utility boiler: in situ measurements

    DEFF Research Database (Denmark)

    Hansen, P. F.B.; Andersen, Karin Hedebo; Wieck-Hansen, K.; Overgaard, P.; Rasmussen, I.; Frandsen, Flemming; Hansen, Lone Aslaug; Dam-Johansen, Kim

    A 2-year demonstration program is carried out by the Danish utility I/S Midtkraft at a 150-MWe PF-boiler unit reconstructed for co-firing straw and coal. As a part of the demonstration program, a comprehensive in situ measurement campaign was conducted during the spring of 1996 in collaboration......-research program to predict deposition propensities and high temperature corrosion during co-combustion of straw and coal in PF-boilers. Danish full scale results from co-firing straw and coal, the test facility and test program, and the potential theoretical support from the Technical University of Denmark are...

  16. Corrosion inhibitors

    International Nuclear Information System (INIS)

    In this paper, we briefly describe the characteristics, cost and electrochemical nature of the corrosion phenomena as well as some of the technologies that are currently employed to minimize its effect. The main subject of the paper however, deals with the description, classification and mechanism of protection of the so-called corrosion inhibitors. Examples of the use of these substances in different aggressive environments are also presented as means to show that these compounds, or their combination, can in fact be used as excellent and relatively cheap technologies to control the corrosion of some metals. In the last part of the paper, the most commonly used techniques to evaluate the efficiency and performance of corrosion inhibitors are presented as well as some criteria to make a careful and proper selection of a corrosion inhibitor technology in a given situation. (Author) 151 refs

  17. Grain boundary engineering technology : materials to reduce recovery boiler maintenance

    Energy Technology Data Exchange (ETDEWEB)

    Rivers, K.C.; MacKenzie, C.M. [Babcock and Wilcox Canada Ltd., Cambridge, ON (Canada)

    2001-05-01

    This paper presented a new technology designed to improve the mechanical reliability of recovery boilers. Thermal fatigue and environmentally-assisted stress corrosion cracking often cause cracking in 304L composite tubes in the lower recovery furnace. In March 1999, Babcock and Wilcox Canada created Integran Technologies Inc. with co-shareholders Ontario Power Generation and Nanometals to develop and market advanced materials applications using patented Grain Boundary Engineering (GBE) and nanocrystalline technologies. The main objective was to provide their customers with a better return on equipment investments. GBE is the method by which the local grain boundary structure is characterized and the material processing variables are adjusted to create an optimized grain boundary structure that improves the performance of the material beyond that which would result from conventional processing techniques. The technology has resulted in significant improvements in intergranular corrosion cracking resistance, creep resistance and fatigue resistance. 9 refs., 4 figs.

  18. Investigations on the Behavior of HVOF and Cold Sprayed Ni-20Cr Coating on T22 Boiler Steel in Actual Boiler Environment

    Science.gov (United States)

    Bala, Niraj; Singh, Harpreet; Prakash, Satya; Karthikeyan, J.

    2012-01-01

    High temperature corrosion accompanied by erosion is a severe problem, which may result in premature failure of the boiler tubes. One countermeasure to overcome this problem is the use of thermal spray protective coatings. In the current investigation high velocity oxy-fuel (HVOF) and cold spray processes have been used to deposit commercial Ni-20Cr powder on T22 boiler steel. To evaluate the performance of the coatings in actual conditions the bare as well as the coated steels were subjected to cyclic exposures, in the superheater zone of a coal fired boiler for 15 cycles. The weight change and thickness loss data were used to establish kinetics of the erosion-corrosion. X-ray diffraction, surface and cross-sectional field emission scanning electron microscope/energy dispersive spectroscopy (FE-SEM/EDS) and x-ray mapping techniques were used to analyse the as-sprayed and corroded specimens. The HVOF sprayed coating performed better than its cold sprayed counterpart in actual boiler environment.

  19. Fast Reactor Programme. Third Quarter 1969. Progress Report

    International Nuclear Information System (INIS)

    The RCN research programme on fast spectrum nuclear reactors comprises reactor physics, fuel performance, radiation damage in canning materials, corrosion behaviour in canning materials, aerosol research and heat transfer and hydraulics. An overview is given of the fast reactor experiments at the STEK critical facility in Petten, the Netherlands, in the third quarter of 1969

  20. Boiler using combustible fluid

    Science.gov (United States)

    Baumgartner, H.; Meier, J.G.

    1974-07-03

    A fluid fuel boiler is described comprising a combustion chamber, a cover on the combustion chamber having an opening for introducing a combustion-supporting gaseous fluid through said openings, means to impart rotation to the gaseous fluid about an axis of the combustion chamber, a burner for introducing a fluid fuel into the chamber mixed with the gaseous fluid for combustion thereof, the cover having a generally frustro-conical configuration diverging from the opening toward the interior of the chamber at an angle of between 15/sup 0/ and 55/sup 0/; means defining said combustion chamber having means defining a plurality of axial hot gas flow paths from a downstream portion of the combustion chamber to flow hot gases into an upstream portion of the combustion chamber, and means for diverting some of the hot gas flow along paths in a direction circumferentially of the combustion chamber, with the latter paths being immersed in the water flow path thereby to improve heat transfer and terminating in a gas outlet, the combustion chamber comprising at least one modular element, joined axially to the frustro-conical cover and coaxial therewith. The modular element comprises an inner ring and means of defining the circumferential, radial, and spiral flow paths of the hot gases.

  1. Iron aluminide weld overlay coatings for boiler tube protection in coal-fired low NOx boilers

    Energy Technology Data Exchange (ETDEWEB)

    Banovic, S.W.; DuPont, J.N.; Marder, A.R. [Lehigh Univ., Bethlehem, PA (United States). Energy Research Center

    1997-12-01

    Iron aluminide weld overlay coatings are currently being considered for enhanced sulfidation resistance in coal-fired low NO{sub x} boilers. The use of these materials is currently limited due to hydrogen cracking susceptibility, which generally increases with an increase in aluminum concentration of the deposit. The overall objective of this program is to attain an optimum aluminum content with good weldability and improved sulfidation resistance with respect to conventional materials presently in use. Research has been initiated using Gas Tungsten Arc Welding (GTAW) in order to achieve this end. Under different sets of GTAW parameters (wire feed speed, current), both single and multiple pass overlays were produced. Characterization of all weldments was conducted using light optical microscopy, scanning electron microscopy, and electron probe microanalysis. Resultant deposits exhibited a wide range of aluminum contents (5--43 wt%). It was found that the GTAW overlays with aluminum contents above {approximately}10 wt% resulted in cracked coatings. Preliminary corrosion experiments of 5 to 10 wt% Al cast alloys in relatively simple H{sub 2}/H{sub 2}S gas mixtures exhibited corrosion rates lower than 304 stainless steel.

  2. New controls spark boiler efficiency

    Energy Technology Data Exchange (ETDEWEB)

    Engels, T. (Monsanto, University Park, IL (United States))

    1993-09-01

    Monsanto's NutraSweet plant in University Park, IL, produces aspartame, the patented NutraSweet artificial sweetener product. Until recently, boiler control was managed by a '60s-era Fireye jackshaft system in which air and natural gas were mechanically linked with an offset to compensate for oxygen trim. The interlocking devices on the Fireye system were becoming obsolete, and the boiler needed a new front end retrofitted for low emissions. In order to improve boiler control efficiency, we decided to modernize and automate the entire boiler control system. We replaced the original jackshaft system, and installed a Gordon-Piet burner system, including gas valves, air dampers, blowers, and burner. The upgrade challenges included developing a control strategy and selecting and implementing a process control system. Since our plant has standardized on the PROVOX process management information system from Fisher Controls (now Fisher-Rosemount Systems) to support most of our process, it was a natural and logical choice for boiler controls as well. 2 figs.

  3. 10 CFR 431.82 - Definitions concerning commercial packaged boilers.

    Science.gov (United States)

    2010-01-01

    ... pressure boiler means a packaged boiler that is: (1) A steam boiler designed to operate at a steam pressure... steam boiler designed to operate at or below a steam pressure of 15 psig; or (2) A hot water boiler... efficiency for a commercial packaged boiler is determined using test procedures prescribed under § 431.86...

  4. Computation Modeling and Assessment of Nanocoatings for Ultra Supercritical Boilers

    Energy Technology Data Exchange (ETDEWEB)

    J. Shingledecker; D. Gandy; N. Cheruvu; R. Wei; K. Chan

    2011-06-21

    Forced outages and boiler unavailability of coal-fired fossil plants is most often caused by fire-side corrosion of boiler waterwalls and tubing. Reliable coatings are required for Ultrasupercritical (USC) application to mitigate corrosion since these boilers will operate at a much higher temperatures and pressures than in supercritical (565 C {at} 24 MPa) boilers. Computational modeling efforts have been undertaken to design and assess potential Fe-Cr-Ni-Al systems to produce stable nanocrystalline coatings that form a protective, continuous scale of either Al{sub 2}O{sub 3} or Cr{sub 2}O{sub 3}. The computational modeling results identified a new series of Fe-25Cr-40Ni with or without 10 wt.% Al nanocrystalline coatings that maintain long-term stability by forming a diffusion barrier layer at the coating/substrate interface. The computational modeling predictions of microstructure, formation of continuous Al{sub 2}O{sub 3} scale, inward Al diffusion, grain growth, and sintering behavior were validated with experimental results. Advanced coatings, such as MCrAl (where M is Fe, Ni, or Co) nanocrystalline coatings, have been processed using different magnetron sputtering deposition techniques. Several coating trials were performed and among the processing methods evaluated, the DC pulsed magnetron sputtering technique produced the best quality coating with a minimum number of shallow defects and the results of multiple deposition trials showed that the process is repeatable. scale, inward Al diffusion, grain growth, and sintering behavior were validated with experimental results. The cyclic oxidation test results revealed that the nanocrystalline coatings offer better oxidation resistance, in terms of weight loss, localized oxidation, and formation of mixed oxides in the Al{sub 2}O{sub 3} scale, than widely used MCrAlY coatings. However, the ultra-fine grain structure in these coatings, consistent with the computational model predictions, resulted in accelerated Al

  5. Production of high quality distillate to meet a fit-for-purpose boiler feedwater specification

    Energy Technology Data Exchange (ETDEWEB)

    Minnich, K. [Veolia Water Solutions Oil and Gas, Calgary, AB (Canada); Neu, D. [Veolia Water Solutions and Technologies/HPD, Pewaukee, WI (United States); Drone, J.L. [Veolia Water Solutions and Technologies/HPD, Plainfield, IL (United States)

    2009-07-01

    Veolia Water Solutions and Technologies has significant experience managing boiler water chemistry and is the world's largest manufacturer of evaporation systems. The company has conducted extensive testing and analysis for produced water evaporation distillate from multiple facilities. In order to produce boiler feed water, evaporation of produced water is used at several steam assisted gravity drainage (SAGD) facilities. There are no official guidelines for the required quality of evaporator distillate to feed a once through steam generator (OTSG) or high pressure industrial watertube boiler (IWT) that will produce injection steam. This paper presented a basis for a fit-for-purpose specification for IWT boilers as well as data on the performance of a Vapor Washer, which produces high quality distilled water that meets fit-for-purpose specifications even during normal variations in feed conditions. Specifically, the paper discussed boiler water requirements for steam injection IWTs; the quality of distillate from a produced water evaporator; the benefits of vapour washing to maintain distillate quality; and suggested boiler chemistry limits for a fit-for-purpose specification. Oxygen, iron, and copper were discussed as being implicated with corrosion and reaction in boilers. Hardness contaminants such as calcium and magnesium were also presented. Suggested limits for boiler water in the fit-for-purpose specification were also presented for silica, total alkalinity, free OH alkalinity, and total dissolved solids in steam. It was concluded that foaming episodes can occur in produced water evaporators due to normal variations, and the distillate can fail to meet the fit-for-purpose specification during foam upsets. 3 refs., 9 figs.

  6. Metallurgical Analysis of Cracks Formed on Coal Fired Boiler Tube

    Science.gov (United States)

    Kishor, Rajat; Kyada, Tushal; Goyal, Rajesh K.; Kathayat, T. S.

    2015-02-01

    Metallurgical failure analysis was carried out for cracks observed on the outer surface of a boiler tube made of ASME SA 210 GR A1 grade steel. The cracks on the surface of the tube were observed after 6 months from the installation in service. A careful visual inspection, chemical analysis, hardness measurement, detailed microstructural analysis using optical and scanning electron microscopy coupled with energy dispersive X-ray spectroscopy were carried out to ascertain the cause for failure. Visual inspection of the failed tube revealed the presence of oxide scales and ash deposits on the surface of the tube exposed to fire. Many cracks extending longitudinally were observed on the surface of the tube. Bulging of the tube was also observed. The results of chemical analysis, hardness values and optical micrographs did not exhibit any abnormality at the region of failure. However, detailed SEM with EDS analysis confirmed the presence of various oxide scales. These scales initiated corrosion at both the inner and outer surfaces of the tube. In addition, excessive hoop stress also developed at the region of failure. It is concluded that the failure of the boiler tube took place owing to the combined effect of the corrosion caused by the oxide scales as well as the excessive hoop stress.

  7. Nickel-chromium plasma spray coatings: A way to enhance degradation resistance of boiler tube steels in boiler environment

    Science.gov (United States)

    Sidhu, Buta Singh; Prakash, S.

    2006-03-01

    Boiler tube steels, namely low carbon steel ASTM-SA-210-Grades A1 (GrA1), 1Cr-0.5Mo steel ASTM-SA213-T-11 (T11), and 2.25Cr-1 Mo steel ASTM-SA213-T-22(T22), were used as substrate steels. Ni-22Cr-10Al-1Y powder was sprayed as a bond coat 150 μm thick before a 200 μm final coating of Ni-20Cr was applied Coatings were characterized prior to testing in the environment of a coal fire boiler. The uncoated and coated steels were inserted in the platen superheater zone of a coal fired boiler at around 755°C for 10 cycles, each 100 h. Coated steels showed lower degradation (erosion-corrosion) rate than uncoated steels showed. The lowest rate was observed in the case of Ni-20Cr coated T11 steel. Among the uncoated steels, the observed rate of degradation was the lowest for the T22 steel.

  8. Corrosion and Materials Performance in biomass fired and co-fired power plants

    DEFF Research Database (Denmark)

    Montgomery, Melanie; Larsen, OH; Biede, O

    2003-01-01

    not previously encountered in coal-fired power plants. The type of corrosion attack can be directly ascribed to the composition of the deposit and the metal surface temperature. In woodchip boilers, a similar corrosion rate and corrosion mechanism has on some occasions been observed. Co-firing of straw (10...... and 20% energy basis) with coal has shown corrosion rates lower than those in straw-fired plants. With both 10 and 20% straw, no chlorine corrosion was seen. This paper will describe the results from in situ investigations undertaken in Denmark on high temperature corrosion in biomass fired plants....... Results from 100% straw-firing, woodchip and co-firing of straw with coal will be reported. The corrosion mechanisms observed are summarized and the corrosion rates for 18-8 type stainless steels are compared....

  9. Boiler Retrofit for the Utilization of Biodiesel

    OpenAIRE

    Leily Nurul Komariah; Marwani Marwani

    2016-01-01

    Fuel oil used in the boiler is able to substitute with biodiesel. In lower blends, there are no engine modification needed, but some researchers recommended some technical adjustments in order to maintain the boiler's performance and equipment durability. This study consists of the comparison between the performance of boiler before and after retrofitting on the use of biodiesel. The diesel oil was introduced in biodiesel blends of 10% (B10), 20% (B20) and 25% (B25). A fire tube boiler was us...

  10. Internal corrosion

    Energy Technology Data Exchange (ETDEWEB)

    Joosten, M. [ConocoPhillips, Bartlesville, OK (United States); Anderson, W. [Spectra Energy Transmission, Vancouver, BC (Canada)

    2007-07-01

    Working Group 11 identified internal corrosion issues in both upstream and downstream oil and gas pipelines and suggested ways to address them through integrity management, modeling, and monitoring. Three sessions were held in an effort to provided a better understanding between integrity professionals engaged in different aspects of pipeline management. Opportunities for reducing cost or improving integrity performance of the whole system were also identified. It was determined that management support is needed in order to monitor and mitigate internal corrosion of pipelines. The role of regulations in ensuring pipeline integrity was also discussed along with rules for pigging and batching of inhibitors. In-line inspections have identified under-deposit corrosion and solids/water deposition as two key problems facing pipeline operators. It was noted that an internal corrosion course offered by the National Association of Corrosion Engineers (NACE) is being well attended and is providing worthwhile training. Other issues discussed by this working group were: bacteria with upstream problems; effects of carbon dioxide, hydrogen sulphide and partial pressures on corrosion; and, procedures and guidelines to maintain clean pipelines. tabs., figs.

  11. 49 CFR 230.47 - Boiler number.

    Science.gov (United States)

    2010-10-01

    ... 49 Transportation 4 2010-10-01 2010-10-01 false Boiler number. 230.47 Section 230.47... Steam Gauges § 230.47 Boiler number. (a) Generally. The builder's number of the boiler, if known, shall be stamped on the steam dome or manhole flange. If the builder's number cannot be obtained,...

  12. 29 CFR 1915.162 - Ship's boilers.

    Science.gov (United States)

    2010-07-01

    ... Ship's boilers. (a) Before work is performed in the fire, steam, or water spaces of a boiler where employees may be subject to injury from the direct escape of a high temperature medium such as steam, or... dead boiler with the live system or systems shall be secured, blanked, and tagged indicating...

  13. Sootblowing optimization for improved boiler performance

    Science.gov (United States)

    James, John Robert; McDermott, John; Piche, Stephen; Pickard, Fred; Parikh, Neel J

    2013-07-30

    A sootblowing control system that uses predictive models to bridge the gap between sootblower operation and boiler performance goals. The system uses predictive modeling and heuristics (rules) associated with different zones in a boiler to determine an optimal sequence of sootblower operations and achieve boiler performance targets. The system performs the sootblower optimization while observing any operational constraints placed on the sootblowers.

  14. Sootblowing optimization for improved boiler performance

    Energy Technology Data Exchange (ETDEWEB)

    James, John Robert; McDermott, John; Piche, Stephen; Pickard, Fred; Parikh, Neel J.

    2012-12-25

    A sootblowing control system that uses predictive models to bridge the gap between sootblower operation and boiler performance goals. The system uses predictive modeling and heuristics (rules) associated with different zones in a boiler to determine an optimal sequence of sootblower operations and achieve boiler performance targets. The system performs the sootblower optimization while observing any operational constraints placed on the sootblowers.

  15. Investigation into Cause of High Temperature Failure of Boiler Superheater Tube

    Science.gov (United States)

    Ghosh, D.; Ray, S.; Roy, H.; Shukla, A. K.

    2015-04-01

    The failure of the boiler tubes occur due to various reasons like creep, fatigue, corrosion and erosion. This paper highlights a case study of typical premature failure of a final superheater tube of 210 MW thermal power plant boiler. Visual examination, dimensional measurement, chemical analysis, oxide scale thickness measurement, microstructural examination are conducted as part of the investigations. Apart from these investigations, sulfur print, Energy Dispersive spectroscopy (EDS) and X ray diffraction analysis (XRD) are also conducted to ascertain the probable cause of failure of final super heater tube. Finally it has been concluded that the premature failure of the super heater tube can be attributed to the combination of localized high tube metal temperature and loss of metal from the outer surface due to high temperature corrosion. The corrective actions have also been suggested to avoid this type of failure in near future.

  16. Boiler efficiency increase by building-in the additional heating surfaces (heat utilizer)

    International Nuclear Information System (INIS)

    Rationalization of the energy consumption is of general social interest, and therefore it is necessary to undertake all measures that will increase the degree of utilization of the power plants. One way of rationalization in thermal energy production is reducing the temperature of flue gases by building-in the additional heating surfaces in boiler flue channel. The results and analyses of several years measuring of boiler parameters, with built-in heat exchanger, by system of the remote control and data acquisition are presented in this paper. The particular review is given for fuel saving and time of the investment payback. Working on this problem in cooperation with the Institute for energetic and process techniques of the Faculty of Technical Sciences in Novi Sad, hot water boiler of 9.3 MW power is chosen for concrete checking of the previous investigations. The feasibility of building-in additional water heater (utilizer) in flue channel of the existing hot water boiler was established in the paper. From the table and presented diagrams obtained by measuring, and on the basis of tech-economic analysis it can be concluded that there is the complete feasibility of building-in the additional heat exchanger. The building-in costs are very quickly paid back. The efficiency of water reheater in utmost extent depends on the inlet water temperature as well, and it is higher as the inlet water temperature is lower, and even the condensation of flue gases is desirable. At boilers that use natural gas as the fuel there is no danger of low temperature corrosion, as natural gas doesn't contain sulphur. The experience during the natural gas fired boiler exploitation shows that steam condensation from flue gases does not influence the heating surface corrosion in great extent, as the condensate is almost neutral. Due to the mentioned reasons it is desirable for boilers that use natural gas to have as large as possible heating surfaces, which can be obtained at the existing

  17. Investigation and analysis of short overheat in boiler tube failure in power plant units

    International Nuclear Information System (INIS)

    Boiler tube failure are the main cause of forced outages of power generating units and due to cost, Penalty is very high. Sources and reasons of tube failures are various, but it can be generally categorized by mechanical and corrosion factors with 81% and 19% contributions, respectively. Among the mechanical factors short overheat has the major contribution in water wall and superheater tube, failure. In this paper short overheat mechanism (with appearance and metallurgical features) and its prevention method is over viewed

  18. CORROSION IN AIRFRAMES

    OpenAIRE

    PETROVIC ZORAN C.

    2016-01-01

    The introductory chapter provides a brief reference to the issue of corrosion and corrosion damage to aircraft structures. Depending on the nature and dimensions of this non uniformity, three different categories of corrosion are defined: uniform, selective and localized corrosion. The following chapters present the forms of corrosion that can occur in three defined categories of corrosion. Conditions that cause certain types of corrosion in various corrosive environments are discussed. Examp...

  19. Fireside corrosion testing of candidate superheater tube alloys, coatings, and claddings - phase II

    Energy Technology Data Exchange (ETDEWEB)

    Blough, J.L.; Stanko, G.J. [Foster Wheeler Development Corp., Livingston, NJ (United States)

    1996-08-01

    In Phase I a variety of developmental and commercial tubing alloys and claddings were exposed to laboratory fireside corrosion testing simulating a superheater or reheater in a coal-fired boiler. Phase II (in situ testing) has exposed samples of 347, RA-8511, HR3C, 253MA, Fe{sub 3}Al + 5Cr, 310 modified, 800HT, NF 709, 690 clad, and 671 clad for over 10,000 hours to the actual operating conditions of a 250-MW coal-fired boiler. The samples were installed on an air-cooled, retractable corrosion probe, installed in the reheater cavity, and controlled to the operating metal temperatures of an existing and advanced-cycle coal-fired boiler. Samples of each alloy will be exposed for 4000, 12,000, and 16,000 hours of operation. The results will be presented for the metallurgical examination of the corrosion probe samples after 4000 hours of exposure.

  20. Corrosion amalgams

    International Nuclear Information System (INIS)

    The release of copper, mercury, silver, tin or zinc from conventional, dispersed phase and spherical high copper content amalgams immersed in artificial saliva solutions for periods up to 30 d has been measured using nuclear tracer techniques. During initial corrosion, i.e. within a few hours, substantial amounts of mercury were found to be present in particulate matter in the three types of amalgams. The release of particulate matter was pronounced for the dispersed phase type of amalgam. After about 30 d electrochemical corrosion was found to be the predominant process for release of various corrosion products. Zinc was demonstrated to be the major corrosion product released to the artificial saliva solutions from conventional as well as dispersed phase amalgams. Due to low radioactivity levels silver and tin could not be quantitatively asayed. However, the upper limits of release of silver and tin in the artificial saliva solutions referring to exposure periods up to 30 d were estimated to 0.1 μg and 25 μg respectively. The chemical state of the various corrosion products has been evaluated. The deposition of CuCl2 . 3 Cu(OH)2 on the surfaces of copper rich amalgams was observed according to X-ray diffraction analysis. (author)

  1. Adaptive controlling of power boiler

    OpenAIRE

    Wojcik, W.; Kalita, M; Smolarz, A.

    2004-01-01

    This paper presents research on adaptive control (AC) of combastion process in in¬dustry. Results were obtained from research conducted in laboratory combustion chamber with usage of Fiber Optical Measurement System (FOMS) with electronic block. Simulation proved that implementing AC and FOMS to burning process improves flue gasses parameters -direct measure of power boiler ecologic and economical quality of work.

  2. Developing Boiler Concepts as Integrated Units

    DEFF Research Database (Denmark)

    Sørensen, Kim; Condra, Thomas Joseph; Houbak, Niels

    2004-01-01

    With the objective to be able to optimize the design and operation of steam boiler concepts Aalborg Industries A/S [1] has together with Aalborg University, Institute of Energy Technology [9] carried out a development project paying special attention to the boiler concept as an integrated unit......, emissions and to obtain long time operation experiences with the boiler concept, a full scale prototype has been built and these tests have been accomplished on the prototype. By applying this integrated unit approach to the boiler concept development it has been possible to optimize the different building...... bricks in the boiler concept to each other and hereby obtain signicant reductions in the boiler concepts weight and foot-print . The actual development project has focused on an heavy fuel oil-red boiler for the marine market with a capacity in the range 1-10 t/h saturated steam. The development project...

  3. Failure Analysis of 600 MW Supercritical Boiler Water Wall

    OpenAIRE

    Fu Huilin; Cai Zhengchun; Yan Xiaozhong; He Jinqiao; Zhou Yucai

    2013-01-01

    Boiler tube often causes abnormal boiler outage, bringing greater economic losses. This thesis mainly comes from the dynamics of boiler water, boiler furnace accident location of wall temperature distribution to explore the cause of the accident boiler. Calculation results show that the deformation will seriously reduce the boiler allowable maximum temperature difference between the screens. And the boiler is not over-temperature, low temperature difference between the screens, which have bur...

  4. Superheater materials for waste incinerator boilers. Trials at the Hoegdalen plant

    International Nuclear Information System (INIS)

    In order to obtain an acceptable length of life for the superheaters in waste incinerated boilers a considerably lower steam temperature is used than when incinerating conventional fuel. In spite of this the life of the superheaters is unsatisfactory, with the occurrence of damage in some type of incinerator boilers after only a few years operation. The use of high alloyed material instead of conventional pressure vessel steels can increase the length of life and improve operational efficiency in existing incinerator boilers. Such tubes permit higher steam data for new plants. Cooled materials testing probes have been mounted in the flue gas duct close to the superheater in two boilers in the Hoegdalen plant, Stockholm. The materials temperatures have been maintained in the range 400-500 degrees C. Low metal losses have been obtained, in particular with Alloy 625, but also with Alloy 825 and Sandvik Sanicro 28. The attack on the tubes is corrosion, caused by the aggressive dust which is trapped in the superheaters. In these trials it has been shown that correct boiler design is very important, in conjunction with the choice of materials

  5. Stress corrosion cracking experience in steam generators at Bruce NGS

    International Nuclear Information System (INIS)

    In late 1990 and through 1991, units 1 and 2 at the Bruce A Nuclear Generating Station (BNGS-A) experienced a number of steam generator tube leaks. Tube failures were identified by eddy current to be circumferential cracks at U-bend supports on the hot-leg side of the boilers. In late 1991, tubes were removed from these units for failure characterization. Two active failure modes were found: corrosion fatigue in both units 1 and 2 and stress corrosion cracking (SCC) in unit 2. In unit 2, lead was found in deposits, on tubes, and in cracks, and the cracking was mixed-mode: transgranular and intergranular. This convincingly indicated the involvement of lead in the stress corrosion cracking failures. A program of inspection and tube removals was carried out to investigate more fully the extent of the problem. This program found significant cracking only in lead-affected boilers in unit 2, and also revealed a limited extent of non-lead-related intergranular stress corrosion cracking in other boilers and units. Various aspects of the failures and tube examinations are presented in this paper. Included is discussion of the cracking morphology, measured crack size distributions, and chemical analysis of tube surfaces, crack faces, and deposits -- with particular emphasis on lead

  6. Screening and Quantification of Aliphatic Primary Alkyl Corrosion Inhibitor Amines in Water Samples by Paper Spray Mass Spectrometry.

    Science.gov (United States)

    Jjunju, Fred P M; Maher, Simon; Damon, Deidre E; Barrett, Richard M; Syed, S U; Heeren, Ron M A; Taylor, Stephen; Badu-Tawiah, Abraham K

    2016-01-19

    Direct analysis and identification of long chain aliphatic primary diamine Duomeen O (n-oleyl-1,3-diaminopropane), corrosion inhibitor in raw water samples taken from a large medium pressure water tube boiler plant water samples at low LODs (water samples was confirmed via tandem mass spectrometry using collision-induced dissociation and supported by exact mass measurement and reactive paper spray experiments using an LTQ Orbitrap Exactive instrument. Data shown herein indicate that paper spray ambient ionization can be readily used as a rapid and robust method for in situ direct analysis of polymanine corrosion inhibitors in an industrial water boiler plant and other related samples in the water treatment industry. This approach was applied for the analysis of three complex water samples including feedwater, condensate water, and boiler water, all collected from large medium pressure (MP) water tube boiler plants, known to be dosed with varying amounts of polyamine and amine corrosion inhibitor components. Polyamine chemistry is widely used for example in large high pressure (HP) boilers operating in municipal waste and recycling facilities to prevent corrosion of metals. The samples used in this study are from such a facility in Coventry waste treatment facility, U.K., which has 3 × 40 tonne/hour boilers operating at 17.5 bar. PMID:26727190

  7. Underground pipeline corrosion

    CERN Document Server

    Orazem, Mark

    2014-01-01

    Underground pipelines transporting liquid petroleum products and natural gas are critical components of civil infrastructure, making corrosion prevention an essential part of asset-protection strategy. Underground Pipeline Corrosion provides a basic understanding of the problems associated with corrosion detection and mitigation, and of the state of the art in corrosion prevention. The topics covered in part one include: basic principles for corrosion in underground pipelines, AC-induced corrosion of underground pipelines, significance of corrosion in onshore oil and gas pipelines, n

  8. CFD Simulation On CFBC Boiler

    OpenAIRE

    Amol S. Kinkar; G. M. Dhote; R.R. Chokkar

    2015-01-01

    Abstract Heavy industrialization amp modernization of society demands in increasing of power cause to research amp develop new technology amp efficient utilization of existing power units. Variety of sources are available for power generation such as conventional sources like thermal hydro nuclear and renewable sources like wind tidal biomass geothermal amp solar. Out of these most common amp economical way for producing the power is by thermal power stations. Various industrial boilers plays...

  9. Scandinavian baffle boiler design revisited

    OpenAIRE

    Stepanov Borivoj Lj.; Pešenjanski Ivan K.; Spasojević Momčilo Đ.

    2015-01-01

    The aim of this paper is to examine whether the use of baffles in a combustion chamber, one of the well-known low-cost methods for the boiler performance improvement, can be enhanced. Modern day tools like computational fluid dynamics were not present at the time when these measures were invented, developed and successfully applied. The objective of this study is to determine the influence of location and length of a baffle in a furnace, for different mass ...

  10. Further development of recovery boiler; Soodakattilan kehitystyoe

    Energy Technology Data Exchange (ETDEWEB)

    Janka, K.; Siiskonen, P.; Sundstroem, K. [Tampella Power Oy, Tampere (Finland)] [and others

    1996-12-01

    The global model of a recovery boiler was further developed. The aim is to be able to model the velocity, temperature and concentration fields in a boiler. At this moment the model includes submodels for: droplet drying, pyrolysis, char burning, gas burning and for droplet trajectory. The preliminary study of NO{sub x} and fly ash behaviour in a boiler was carried out. The study concerning flow field in the superheater area was carried out a 2-dimensional case in which the inflow parameters were taken from global model of a recovery boiler. Further the prediction methods of fouling in a recovery boiler were developed based on theoretical calculations of smelting behaviour of multicomponent mixtures and measurements at operating recovery boilers. (author)

  11. Inception report and gap analysis. Boiler inspection

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2004-06-01

    This inception and gap analysis report on boilers in Latvia, has been prepared in the framework of the 'Implementation of the EU directive on energy performance of buildings: development of the Latvian Scheme for energy auditing of building and inspection of boilers'. The report is the basis for the establishment of training of boiler inspectors; it develops a gap analysis for better understanding and estimating the number of installations in Latvia and develops suggestions for the institutional set up. In particular includes information on existing standard and regulation on boiler, suggestion for the content of the training material of experts for boiler inspections and a syllabus of the training course. A specific section is dedicated to the suggestion for certification system of trained boiler inspectors. (au)

  12. Peculiar high temperature corrosion of martensite alloy under impact of Estonian oil shale fly ash

    Energy Technology Data Exchange (ETDEWEB)

    Tallermo, H.; Klevtsov, I. [Thermal Engineering Department of Tallinn Technical University, Tallinn (Estonia)

    1998-12-31

    The superheaters` surfaces of oil shale steam boiler made of pearlitic and austenitic alloys, are subject to intensive corrosion, mainly due to presence of chlorine in external deposits. The applicability of martensitic alloys X1OCrMoVNb91 and X20CrMoV121 for superheaters is examined here and empirical equations allowing to predict alloys` corrosion resistance in the range of operational temperatures are established. Alloy X1OCrMoVNb91 is found been most perspective for superheaters of boilers firing fossil fuel that contain alkaline metals and chlorine. The abnormal dependence of corrosion resistance of martensitic alloys on temperature is revealed, namely, corrosion at 580 deg C in presence of oil shale fly ash is more intensive than at 620 deg C. (orig.) 2 refs.

  13. Business opportunities in boiler control systems

    Energy Technology Data Exchange (ETDEWEB)

    McHale, A.P.

    1988-03-01

    Each year some Pound 4.5 billion is spent on fuel to fire the UK non-domestic boiler stock. The average age of the 500 000 population of boilers is more than 10 years and in that time great advances have been made in the capacity and capability of microprocessor controls. There is undoubtedly an enormous potential to retrofit existing boilers with the latest controls both to improve efficiency of production and utilisation.

  14. High Temperature Corrosion in Biomass Incineration Plants

    DEFF Research Database (Denmark)

    Montgomery, Melanie; Maahn, Ernst emanuel; Gotthjælp, K.;

    1997-01-01

    The aim of the project is to study the role of ash deposits in high temperature corrosion of superheater materials in biomass and refuse fire combined heat and power plants. The project has included the two main activities: a) A chemical characterisation of ash deposits collected from a major...... number of biomass and refuse fired combined heat and power plant boilers, b) Laboratory exposures and metallurgical examinations of material specimens with ash deposits in well-defined gas environments with HCl and SO2 in a furnace....

  15. Modeling of fire-tube boilers

    OpenAIRE

    Ortiz, F.J. Gutiérrez

    2011-01-01

    Abstract In fire-tube boilers, the flue gas passes inside boiler tubes, and heat is transferred to water on the shell side. A dynamic model has been developed for the analysis of boiler performance, and Matlab has been applied for integrating it. The mathematical model developed is based on the first principles of mass, energy and momentum conservations. In the model, the two parts of the boiler (fire/gas and water/steam sides), the economizer, the superheater and the heat recovery...

  16. Boiler plants completed in record time

    International Nuclear Information System (INIS)

    Bubbling fluidised bed (BFB) combustion has steadily increased its share of the boiler market in recent years, particularly in the Nordic region, where it is particularly well-suited to handling the high moisture content biofuels produced and used by the forest products industry. Foster Wheeler is the world's leading supplier of fluidised bed combustion technology. Over 200 of the more than 300 fluidised bed boilers supplied by the company are circulating fluidised bed (CFB) designs, a market in which Foster Wheeler has more than a 40% share. Foster Wheeler Energia Oy supplied the Myllykoski project at Anjalankoski with a fluidised bed boiler, auxiliary steam boilers, and flue gas scrubber systems

  17. 49 CFR 230.30 - Lap-joint seam boilers.

    Science.gov (United States)

    2010-10-01

    ..., DEPARTMENT OF TRANSPORTATION STEAM LOCOMOTIVE INSPECTION AND MAINTENANCE STANDARDS Boilers and Appurtenances Inspection and Repair § 230.30 Lap-joint seam boilers. Every boiler having lap-joint longitudinal...

  18. Combating corrosion in biomass and waste-fired plant

    OpenAIRE

    Henderson, Pamela; Hjörnhede, Anders

    2010-01-01

    Many biomass- or waste-fired plants have problems with high temperature corrosion especially if the steam temperature is greater than500°C.  An increase in the combustion of waste fuels means that an increasing number of boilers have had problems. Therefore, there is great interest in reducing the costs associated with high temperature corrosion and at the same time there exists a desire to improve the electrical efficiency of a plant by the use of higher steam temperatures.  Assuming that th...

  19. Characterization of Oxy-combustion Impacts in Existing Coal-fired Boilers

    Energy Technology Data Exchange (ETDEWEB)

    Adams, Bradley; Davis, Kevin; Senior, Constance; Shim, Hong Shim; Otten, Brydger; Fry, Andrew; Wendt, Jost; Eddings, Eric; Paschedag, Alan; Shaddix, Christopher; Cox, William; Tree, Dale

    2013-09-30

    Reaction Engineering International (REI) managed a team of experts from University of Utah, Siemens Energy, Praxair, Vattenfall AB, Sandia National Laboratories, Brigham Young University (BYU) and Corrosion Management Ltd. to perform multi-scale experiments, coupled with mechanism development, process modeling and CFD modeling, for both applied and fundamental investigations. The primary objective of this program was to acquire data and develop tools to characterize and predict impacts of CO{sub 2} flue gas recycle and burner feed design on flame characteristics (burnout, NO{sub x}, SO{sub x}, mercury and fine particle emissions, heat transfer) and operational concerns (fouling, slagging and corrosion) inherent in the retrofit of existing coal-fired boilers for oxy-coal combustion. Experimental work was conducted at Sandia National Laboratories’ Entrained Flow Reactor, the University of Utah Industrial Combustion Research Facility, and Brigham Young University. Process modeling and computational fluid dynamics (CFD) modeling was performed at REI. Successful completion of the project objectives resulted in the following key deliverables: 1) Multi-scale test data from 0.1 kW bench-scale, 100 kW and 200 kW laboratory-scale, and 1 MW semi-industrial scale combustors that describe differences in flame characteristics, fouling, slagging and corrosion for coal combustion under air-firing and oxygen-firing conditions, including sensitivity to oxy-burner design and flue gas recycle composition. 2) Validated mechanisms developed from test data that describe fouling, slagging, waterwall corrosion, heat transfer, char burnout and sooting under coal oxy-combustion conditions. The mechanisms were presented in a form suitable for inclusion in CFD models or process models. 3) Principles to guide design of pilot-scale and full-scale coal oxy-firing systems and flue gas recycle configurations, such that boiler operational impacts from oxy-combustion retrofits are minimized. 4

  20. Performance of high-velocity oxy-fuel-sprayed chromium carbide-nickel chromium coating in an actual boiler environment of a thermal power plant

    Energy Technology Data Exchange (ETDEWEB)

    Sidhu, T.S.; Prakash, S.; Agrawal, R.D. [Industrial Technology Institute, Roorkee (India)

    2007-09-15

    The present study aims to evaluate the performance of a high-velocity oxy-fuel (HVOF)-sprayed Cr{sub 3}C{sub 2}-NiCr (chromium carbide-nickel chromium) coating on a nickel-based super-alloy in an actual industrial environment of a coal-fired boiler, with the objective to protect the boiler super-heater and reheater tubes from hot corrosion. The tests were performed in the platen super heater zone of a coal-fired boiler for 1,000 h at 900 degrees C under cyclic conditions. The Cr{sub 3}C{sub 2}-NiCr coating imparted the necessary protection to the nickel-based super alloy in the given environment. The dense and flat splat structure of the coating, and the formation of oxides of chromium and nickel and their spinels, might have protected the substrate super alloy from the inward permeation of corrosive species.

  1. Evaluation of electrochemical techniques for measurement of fireside corrosion in thermal power plants; Utvaerdering av elektrokemiska tekniker foer maetning av roekgassidig hoegtemperaturkorrosion i pannor

    Energy Technology Data Exchange (ETDEWEB)

    Hjorrnhede, Anders

    2007-12-15

    The possibility to measure the corrosion rate on-line, in situ, is getting more and more interesting due to increased corrosion. The worsening may be a result of lower fuel quality or increased steam data due to raised efficiency demands. Also the use of inhibitors can be improved and the lifetime of important components can be increased. Today, virtually all corrosion measurements of materials used for waterwalls, superheaters, economisers and other heat-transferring surfaces are based on in-situ probe tests of coupons or rings. The aim of the project is to evaluate the practicability of commercial or semicommercial on-line in-situ corrosion probes for use in waste fired boilers. The target groups are owners of boilers, operators, service personnel but also boiler manufacturer and material producers. Since the use of on-line, in situ, corrosion probes is substantial, some of the most promising corrosion probes have been tested in a waste fired boiler in Hamburg, Germany. Tests in waste fired boiler have never before been performed. The MECO CB, a Linear Polarisation Resistance (LPR) corrosion probe from Coresto Oy, Finland was tested and from Lehrstuhl fuer Umweltverfahrenstechnik und Anlagentechnik (LUAT) der Universitaet Duisburg-Essen, Germany an Electrochemical Noise (EN) - probe was tested. From Pepperl + Fuchs both EN- and LPR-CorrTran corrosion sensors were tested. The test periods were lasting from 1050h to 3750h. The test materials were the low alloyed steel 15Mo3, the Ni-based super alloys Sanicro 63 and Haynes Hastelloy C-2000. The fluegas temperatures were 635 deg C or 520 deg C. The material temperatures were 440 deg C, 420 deg, 350 deg C and was swept from 400 deg C to 300 deg C. All probes are measuring a signal which has a correlation to the corrosion process, but the quantification procedure is not working well. The results achieved from the corrosion probes must be calibrated against corrosion rates measured by means of conventional corrosion

  2. 46 CFR 109.555 - Propulsion boilers.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 4 2010-10-01 2010-10-01 false Propulsion boilers. 109.555 Section 109.555 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) A-MOBILE OFFSHORE DRILLING UNITS OPERATIONS Miscellaneous § 109.555 Propulsion boilers. The master or person in charge and the engineer in charge...

  3. Seeking for total efficiency on boiler operation

    International Nuclear Information System (INIS)

    In this paper, as for the boiler in the private power generation plant which has been in operation since July, 1974 based on the production increase project of the factory, the measures for energy conservation considered from the planning and design stage, the countermeasures to the low loading of the boiler by the epoch-making effect of the energy conservation in the production system since the oil crisis in 1973, and the cost management of the boiler are described. The outline of the private power generation plant is shown. The boiler facilities are the boiler for power generation of 81 kg/cm2, 433degC, 65 t/h, the saturation boiler of 30 kg/cm2, 211degC, 47 t/h, and the waste heat boiler of 22 kg/cm2, 211 degC, 4.2 t/h. As the measures for energy conservation, tangential corner firing-two stage combustion process was adopted, and the total heat of recovered drain has been utilized. The remodeling and the effect of improvement of the boiler and the turbine as the countermeasures to low loading are reported. The examples of other energy conservation in the waste tire incinerator, air compressor, exhaust desulfurizer and air preheater are described. (K.I.)

  4. A Study on the Creep Rupture Life of SUS 304 Stainless Steel Subjected to Hot Corrosion

    International Nuclear Information System (INIS)

    In order to predict the creep life of SUS 304 stainless steel being used as boiler superheater tubes under hot corrosion and creep environment, the creep tests were carried out at the temperature range of 630 to 750 .deg. C in static air for the specimens with or without coating of double layer corrosives according to the new hot corrosion test method. Finally, the equation for creep life prediction of SUS 304 stainless steel under hot corrosion condition was derived by method extrapolating creep rupture data. From the investigations of the creep rupture properties, it was also clarified that the creep life of SUS 304 stainless steel subjected to hot corrosion is chiefly determined by the aggressive intergranular penetration of sulfides and tube wall thinning, and that the creep rupture life is remarkably shortened at temperature near the melting point of the corrosive products

  5. The Characterization of Twin-Wire Arc-Sprayed FeCrBSi Coating and the Application in Sewage Sludge Boilers

    Science.gov (United States)

    Qin, Enwei; Huang, Qian; Shao, Yumin; Chen, Guoxing; Ye, Lin; Gu, Qin; Wu, Shuhui

    2014-12-01

    Incineration in boilers is an environment-friendly treatment for industrial and civil sewage sludge. However, due to the aggressive nature of the sludge, the boiler fireside-surface is subjected to severe wear, erosive, and high temperature corrosion problems during incineration. In this study, we developed an economical FeCrBSi wire material with iron weight content as high as 80%. The coating was prepared by twin-wire arc spraying processing. The chemical compositions of the coating, as well as phase components were analyzed by energy-dispersive spectroscopy and x-ray diffraction method. The surface roughness, porosity, and cross-sectional morphology were further characterized. The coating hardness is close to that of the commercial Armacor M and Armacor C materials. In-boiler test was also carried out. The low thickness loss of the tube indicates a promising application future in sludge boilers.

  6. Hot Corrosion Behaviour of Detonation Gun Sprayed Al2O3-40TiO2 Coating on Nickel Based Superalloys at 900°C

    OpenAIRE

    N. K. Mishra; Naveen Kumar; S. B. Mishra

    2014-01-01

    Hot corrosion is the major degradation mechanism of failure of boiler and gas turbine components. These failures occur because of the usage of wide range of fuels such as, coal and oil at the elevated temperatures. Nickel based superalloys having excellent mechanical strength and creep resistance at elevated temperature are used under such environment but they lack resistance to hot corrosion at high temperature. To overcome these problems hot corrosion resistant coatings are deposited on the...

  7. Optimizing the integrated design of boilers - simulation

    DEFF Research Database (Denmark)

    Sørensen, Kim; Karstensen, Claus M. S.; Condra, Thomas Joseph;

    2004-01-01

    Boilers can be considered as consisting of three main components: (i) the pressure part, (ii) the burner and (iii) the control system. To be able to develop the boilers of the future (i.e. the boilers with the lowest emissions, the highest efciency, the best dynamic performance etc.) it is...... important to see the 3 components as an integrated unit and optimize these as such. This means that the burner must be designed and optimized exactly to the pressure part where it is utilized, the control system must have a conguration optimal for the pressure part and burner where it is utilized etc....... Traditionally boiler control systems have been designed in a rather simple manner consisting of a feed water controller and a pressure controller; two controllers which, in principle, operated without any interaction - for more details on boiler control see [4]. During the last year Aalborg Industries A/S has...

  8. Current and advanced NO/sub x/-control technology for coal-fired industrial boilers

    Energy Technology Data Exchange (ETDEWEB)

    1978-12-01

    A NOx-control-technology assessment study of coal-fired industrial boilers was conducted to examine the effectiveness of combustion-modification methods, including low excess air, staged combustion, and burner modifications. Boiler types considered included overfed and underfed stokers, spreader stokers, pulverized-coal and coal-fired cyclone units. Significant variations in NOx emissions occur with boiler type, firing method, and coal type; a relative comparison of emission-control performance, cost, and operational considerations is presented for each method. Baseline (as-found) emissions from grate-fired stokers were shown to be in the range of 200 to 300 ppM. Similarly, as-found emissions from suspension-fired units were quite low (350 to 600 ppM) as compared to comparably designed utility-sized units. Low excess air was shown to be the most effective method on existing units, reducing emissions by approximately 10%. Evaluation of staged combustion and burner modification, however, were limited due to current boiler designs. Major hardware modification/design and implementation are necessary before the potential of these techniques can be fully evaluated. The study emphasized the numerous operational factors that are of major importance to the user in selecting and implementing a combustion-modification program, including energy considerations, incremental capital and operating costs, corrosion, secondary pollutants, and retrofit potential.

  9. PAH emission from the industrial boilers.

    Science.gov (United States)

    Li, C; Mi, H; Lee, W; You, W; Wang, Y

    1999-10-01

    Polycyclic aromatic hydrocarbons (PAHs) emitted from 25 industrial boilers were investigated. The fuels used for these 25 boilers included 21 heavy oil, two diesel, a co-combustion of heavy oil and natural gas (HO+NG) and a co-combustion of coke oven gas and blast furnace gas (COG+BFG) boilers. PAH samples from the stack flue gas (gas and particle phases) of these 25 boilers were collected by using a PAH stack sampling system. Twenty one individual PAHs were analyzed primarily by a gas chromatography/mass spectrometer (GC/MS). Total-PAH concentration in the flue gas of 83 measured data for these 25 boiler stacks ranged between 29.0 and 4250 microg/m(3) and averaged 488 microg/m(3). The average of PAH-homologue mass (F%) counted for the total-PAH mass was 54.7%, 9.47% and 15.3% for the 2-ring, 3-ring and 4-ring PAHs, respectively. The PAHs in the stack flue gas were dominant in the lower molecular weight PAHs. The emission factors (EFs) of total-PAHs were 13,300, 2920, 2880 and 208 microg/kg-fuel for the heavy oil, diesel, HO+NG and COG+BFG fueled-boiler, respectively. Nap was the most predominant PAH occurring in the stack flue gas. In addition, the EF of 21 individual PAHs in heavy-oil boiler were almost the highest among the four various fueled-boilers except for those of FL and BkF in the diesel boiler. Furthermore, the EF of total-PAHs or BaP for heavy oil were both one order of magnitude higher than that for the diesel-fueled boiler. PMID:10502602

  10. Computer system for monitoring power boiler operation

    Energy Technology Data Exchange (ETDEWEB)

    Taler, J.; Weglowski, B.; Zima, W.; Duda, P.; Gradziel, S.; Sobota, T.; Cebula, A.; Taler, D. [Cracow University of Technology, Krakow (Poland). Inst. for Process & Power Engineering

    2008-02-15

    The computer-based boiler performance monitoring system was developed to perform thermal-hydraulic computations of the boiler working parameters in an on-line mode. Measurements of temperatures, heat flux, pressures, mass flowrates, and gas analysis data were used to perform the heat transfer analysis in the evaporator, furnace, and convection pass. A new construction technique of heat flux tubes for determining heat flux absorbed by membrane water-walls is also presented. The current paper presents the results of heat flux measurement in coal-fired steam boilers. During changes of the boiler load, the necessary natural water circulation cannot be exceeded. A rapid increase of pressure may cause fading of the boiling process in water-wall tubes, whereas a rapid decrease of pressure leads to water boiling in all elements of the boiler's evaporator - water-wall tubes and downcomers. Both cases can cause flow stagnation in the water circulation leading to pipe cracking. Two flowmeters were assembled on central downcomers, and an investigation of natural water circulation in an OP-210 boiler was carried out. On the basis of these measurements, the maximum rates of pressure change in the boiler evaporator were determined. The on-line computation of the conditions in the combustion chamber allows for real-time determination of the heat flowrate transferred to the power boiler evaporator. Furthermore, with a quantitative indication of surface cleanliness, selective sootblowing can be directed at specific problem areas. A boiler monitoring system is also incorporated to provide details of changes in boiler efficiency and operating conditions following sootblowing, so that the effects of a particular sootblowing sequence can be analysed and optimized at a later stage.

  11. Thermographic imaging of material loss in boiler water-wall tubing by application of scanning line source

    Science.gov (United States)

    Cramer, K. Elliott; Winfree, William P.

    2000-06-01

    Localized wall thinning due to corrosion in utility boiler water-wall tubing is a significant inspection concern for boiler operators. Historically, conventional ultrasonics has been used for inspection of these tubes. This technique has proven to be very manpower and time intensive. This has resulted in a 'spot check' approach to inspections, documenting thickness measurements over a relatively small percentage of the total boiler wall area. NASA Langley Research Center has developed a thermal NDE technique designed to image and quantitatively characterize the amount of material thinning present in steel tubing. The technique involves the movement of a thermal line source across the outer surface of the tubing followed by an infrared imager at a fixed distance behind the line source. Quantitative images of the material loss due to corrosion are reconstructed from measurements of the induced surface temperature variations. This paper will present a discussion of the development of the thermal imaging system as well as the techniques used to reconstruct images of flaws. The application of the thermal line source coupled with the analysis technique represents a significant improvement in the inspection speed for large structures such as boiler water-walls. A theoretical basis for the technique will be presented which explains the quantitative nature of the technique. Further, a dynamic calibration system will be presented for the technique that allows the extraction of thickness information from the temperature data. Additionally, the results of applying this technology to actual water-wall tubing samples and in situ inspections will be presented.

  12. Low Cost Polymer heat Exchangers for Condensing Boilers

    Energy Technology Data Exchange (ETDEWEB)

    Butcher, Thomas [Brookhaven National Lab. (BNL), Upton, NY (United States); Trojanowski, Rebecca [Brookhaven National Lab. (BNL), Upton, NY (United States); Wei, George [Brookhaven National Lab. (BNL), Upton, NY (United States); Worek, Michael [Brookhaven National Lab. (BNL), Upton, NY (United States)

    2015-09-30

    Work in this project sought to develop a suitable design for a low cost, corrosion resistant heat exchanger as part of a high efficiency condensing boiler. Based upon the design parameters and cost analysis several geometries and material options were explored. The project also quantified and demonstrated the durability of the selected polymer/filler composite under expected operating conditions. The core material idea included a polymer matrix with fillers for thermal conductivity improvement. While the work focused on conventional heating oil, this concept could also be applicable to natural gas, low sulfur heating oil, and biodiesel- although these are considered to be less challenging environments. An extruded polymer composite heat exchanger was designed, built, and tested during this project, demonstrating technical feasibility of this corrosion-resistant material approach. In such flue gas-to-air heat exchangers, the controlling resistance to heat transfer is in the gas-side convective layer and not in the tube material. For this reason, the lower thermal conductivity polymer composite heat exchanger can achieve overall heat transfer performance comparable to a metal heat exchanger. However, with the polymer composite, the surface temperature on the gas side will be higher, leading to a lower water vapor condensation rate.

  13. EMSL Quarterly Highlights Report: 1st Quarter, Fiscal Year 2009

    Energy Technology Data Exchange (ETDEWEB)

    Showalter, Mary Ann; Kathmann, Loel E.; Manke, Kristin L.

    2009-02-02

    The EMSL Quarterly Highlights Report covers the science, staff and user recognition, and publication activities that occurred during the 1st quarter (October 2008 - December 2008) of Fiscal Year 2009.

  14. EMSL Quarterly Highlights Report: FY 2008, 3rd Quarter

    Energy Technology Data Exchange (ETDEWEB)

    Showalter, Mary Ann

    2008-09-16

    The EMSL Quarterly Highlights Report covers the science, staff and user recognition, and publication activities that occurred during the 1st quarter (October 2007 - December 2007) of Fiscal Year 2008.

  15. EMSL Quarterly Highlights Report: 1st Quarter, FY08

    Energy Technology Data Exchange (ETDEWEB)

    Showalter, Mary Ann

    2008-01-28

    The EMSL Quarterly Highlights Report covers the science, staff and user recognition, and publication activities that occurred during the 1st quarter (October 2007 - December 2007) of Fiscal Year 2008.

  16. Technical overview on FW-CFB boiler technology burning refuse derived fuel

    International Nuclear Information System (INIS)

    Municipalities in towns and cities across U.S. and in other developed countries are urgently seeking solutions for the disposal of municipal solid waste (MSW). This is because landfill sites are rapidly becoming inundated. Many of these municipalities are considering various methods to incinerate the wastes efficiently and cleanly while recovering energy. Municipal wastes vary greatly in size and composition, depending on the town, city or country where it is generated. Incinerating MSW directly requires complex combustion systems which include a moving or travelling grate furnace, stoker boiler or rotary kiln incinerator. These combustion systems have many moving parts and bum at an elevated furnace temperature that often result in a high furnace corrosion rate, frequent equipment failures and low plant availability. Additionally, they produce flue gas with high emissions of pollutants requiring expensive back end emission control systems. An alternate to incineration is to transform MSW to refuse derived fuel (RDF) and burn it in a fluidized bed boiler

  17. Utilization of ventilation air methane as a supplementary fuel at a circulating fluidized bed combustion boiler.

    Science.gov (United States)

    You, Changfu; Xu, Xuchang

    2008-04-01

    Ventilation air methane (VAM) accounts for 60-80% of the total emissions from coal mining activities in China, which is of serious greenhouse gas concerns as well as a waste of valuable fuel sources. This contribution evaluates the use of the VAM utilization methods as a supplementary fuel at a circulating fluidized bed combustion boiler. The paper describes the system design and discusses some potential technical challenges such as methane oxidation rate, corrosion, and efficiency. Laboratory experimentation has shown that the VAM can be burnt completely in circulated fluidized bed furnaces, and the VAM oxidation does not obviously affect the boiler operation when the methane concentration is less than 0.6%. The VAM decreased the incomplete combustion loss for the circulating fluidized bed combustion furnace. The economic benefit from the coal saving insures that the proposed system is more economically feasible. PMID:18505001

  18. Ash transformation in suspension fired boilers co-firing coal and straw

    DEFF Research Database (Denmark)

    Zheng, Yuanjing; Jensen, Peter Arendt; Jensen, Anker Degn

    of flue gas cleaning equipment. This survey includes discussions on the inorganic constituents transformation during straw and coal combustion, alkali-ash and alkali sulfur reactions, a survey of power plant and test rig co-firing experiments, a discussion of equilibrium calculations, a discussion......In this literature report is provided a status for the present knowledge level on ash properties when co-firing coal and biomass. The fly ash formed in boilers using co-firing of coal and straw do have a large influence on ash deposit formation, boiler corrosion, fly ash utilization and operation...... of alkali getter experiments and a discussion of modeling of alkali reaction with kaolin. Presently there is still a need for a better understanding of especially the reaction of potassium with coal ash, thereby making better predictions of co-firing ash properties....

  19. Low toxicity corrosion inhibitors

    International Nuclear Information System (INIS)

    This paper discusses the design and testing of low toxicity corrosion inhibitors. New chemistries have been investigated with respect to corrosion protection and impact on the marine environment. The resulting chemicals, while they are effective corrosion inhibitors, present significant improvements in terms of environmental properties over current products. The discussion includes results of the corrosion inhibition, toxicity, biodegradability and partitioning studies

  20. Boiler system lay-up; Avstaellning och konservering av pannanlaeggningar

    Energy Technology Data Exchange (ETDEWEB)

    Hellman, Mats

    2007-04-15

    Corrosion in power plant equipment is to a large extent a result of poor lay-up procedures. This applies for all equipment on the water and steam side e.g. condensers, boilers, turbines, heat exchangers etc. In theory, lay-up procedures are quite straightforward. The main objective is to avoid a combination of water and oxygen on the steel surfaces within the system. When using dry lay-up procedure, a totally dry environment is essential. The corrosion of steel cannot take place if there is no humidity; in spite of the abundance of oxygen i.e. air. As an alternative the steam side system can be purged with nitrogen so that no air ingress can take place. When using wet lay-up procedures it is important to achieve an oxygen free environment. Creating a slight over-pressure thus avoiding air in leakage can achieve this. Oxygen scavengers might be used as an alternative. Usually problems of maintaining the above mentioned conditions are rarely of technical art. More likely it is due to a lack of knowledge and commitment or short sighted economical considerations. This report summarises the experiences gathered at several visits at plants and discussions with vendors, users and consultants in the power industry. In addition to that, guidelines from well-reputed organisations, international and domestic, have been studied. In many cases the power plant managers believe they have proper lay-up routines but often the routines just regard long time lay-up. This may be regarded as the most important case. However, a number of shorter plant outages in combination with poor lay-up routines can result in severe damages. There is a consensus that a proper lay-up can only be achieved by plant specific lay-up procedures. Each unit is unique in terms of needs and requirements. In order to have as low corrosion as possible a systematic review to evaluate and revise lay-up procedures is preferred. A high in-house knowledge of the power plant enhances the possibility to maintain the

  1. 46 CFR 61.05-20 - Boiler safety valves.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 2 2010-10-01 2010-10-01 false Boiler safety valves. 61.05-20 Section 61.05-20 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) MARINE ENGINEERING PERIODIC TESTS AND INSPECTIONS Tests and Inspections of Boilers § 61.05-20 Boiler safety valves. Each safety valve for a drum, superheater, or reheater of a boiler shall...

  2. Corrosion erosion of steels in high temperature water and wet steam

    International Nuclear Information System (INIS)

    In this meeting is examined the deterioration of different components of boilers and turbines due a rapid corrosion in conventional and nuclear power plants. This type of corrosion affects mainly carbon and low alloyed steel components, when in contact either with water or with high temperature steam-water mixtures, running at high velocities. Such type of corrosion occurs for instance, in feed water pumps, in connexion pipes of turbines or in certain parts of steam generators when in contact with steam-water mixtures, etc..

  3. Single phase and two phase erosion corrosion in broilers of gas-cooled reactors

    International Nuclear Information System (INIS)

    Erosion-corrosion is a phenomenon causing metal wastage in a variety of locations in water and water-steam circuits throughout the power generation industry. Erosion-corrosion can occur in a number of regions of the once-through boiler designs used in the later Magnox and AGR type of gas cooled nuclear reactor. This paper will consider two cases of erosion-corrosion damage (single and two phase) in once through boilers of gas cooled reactors and will describe the solutions that have been developed. The single phase problem is associated with erosion-corrosion damage of mild steel downstream of a boiler inlet flow control orifice. With metal loss rates of up to 1 mm/year at 150 deg. C and pH in the range 9.0-9.4 it was found that 5 μg/kg oxygen was sufficient to reduce erosion-corrosion rates to less than 0.02 mm/year. A combined oxygen-ammonia-hydrazine feedwater regime was developed and validated to eliminate oxygen carryover and hence give protection from stress corrosion in the austenitic section of the AGR once through boiler whilst still providing erosion-corrosion control. Two phase erosion-corrosion tube failures have occurred in the evaporator of the mild steel once through boilers of the later Magnox reactors operating at pressures in the range 35-40 bar. Rig studies have shown that amines dosed in the feedwater can provide a significant reduction in metal loss rates and a tube lifetime assessment technique has been developed to predict potential tube failure profiles in a fully operational boiler. The solutions identified for both problems have been successfully implemented and the experience obtained following implementation including any problems or other benefits arising from the introduction of the new regimes will be presented. Methods for monitoring and evaluating the efficiency of the solutions have been developed and the results from these exercises will also be discussed. Consideration will also be given to the similarities in the metal loss

  4. Electrical design requirements for electrode boilers for nuclear plants

    International Nuclear Information System (INIS)

    Medium-voltage steam electrode boilers, in the 20- to 50-MW range, have become an attractive alternative to comparable fossil-fueled boilers as a source of auxiliary steam during the startup and normal shutdown of nuclear power plants. The electrode boiler represents a favorable option because of environmental, fire protection, and licensing considerations. However, this electrical option brings some difficult design problems for which solutions are required in order to integrate the electrode boiler into the plant low resistance grounded power system. These considerations include the effects of an unbalanced electrode boiler on the performance of polyphase induction motors, boiler grounding for personnel safety, boiler neutral grounding, and ground relaying

  5. Boiler Retrofit for the Utilization of Biodiesel

    Directory of Open Access Journals (Sweden)

    Leily Nurul Komariah

    2016-02-01

    Full Text Available Fuel oil used in the boiler is able to substitute with biodiesel. In lower blends, there are no engine modification needed, but some researchers recommended some technical adjustments in order to maintain the boiler's performance and equipment durability. This study consists of the comparison between the performance of boiler before and after retrofitting on the use of biodiesel. The diesel oil was introduced in biodiesel blends of 10% (B10, 20% (B20 and 25% (B25. A fire tube boiler was used for the test with pressure of 3 bar and heat input capacity of 60,000 kcal. The boiler retrofit is conducted by fine tuning the fan damper scale (FDS and adding a heating feature on fuel system. It was specifically intended to maintain the quality of combustion and boiler efficiency as well as to avoid an increase in fuel consumption. The combustion behaviour was monitored by exhaust emissions of CO, NOx, and SO2. The fan damper scale (FDS and fuel temperature is adjusted by the increasing portion of biodiesel used. The fuel heating apparatus was set at temperature of 40oC for the use of B10, and 60oC for B20 and B25. The FDS adjustment was successfully resulted a reduction in rate of combustion air by average of 9.2%. The boiler retrofitting for the utilization of B10, B20 and B25 showed an increase in boiler efficiency by 0.64%, 0.42% and 2.6% respectively. The boiler retrofitting is surprisingly reduced the fuel consumption by average of 11.2%.

  6. Power for the industrial age: a brief history of boilers

    Energy Technology Data Exchange (ETDEWEB)

    Kuehn, S.E.

    1996-02-01

    Boilers were first designed in Greece during the Hellenistic period by Hero, but they were regarded purely as a novelty and no industrial application was found for these toys until the seventeenth century when mining engineers used them for steam-powered pumps. By the end of the 17th century the early shell boilers were replaced by tube boilers, the direct ancestors of the modern boiler. Among the best known of the early boiler manufacturers was Babcock and Wilcox, and they supplied boilers to one of the first electric power plants. In the early 20th century superheaters, economizers, stokers and pulverizers were added to the design of the utility boiler. Fusion-welded boiler drums added to safety. More recently environmental concerns have initiated a new generation of boilers, such as the pressurised fluidised bed combustion boilers and their advanced versions. 5 refs., 3 figs.

  7. Chemical cleaning of UK AGR boilers

    International Nuclear Information System (INIS)

    For a number of years, the waterside pressure drops across the advanced gas-cooled reactor (AGR) pod boilers have been increasing. The pressure drop increases have accelerated with time, which is the converse behaviour to that expected for rippled magnetite formation (rapid initial increase slowing down with time). Nonetheless, magnetite deposition remains the most likely cause for the increasing boiler resistances. A number of potential countermeasures have been considered in response to the boiler pressure drop increases. However, there was no detectable reduction in the rate of pressure drop increase. Chemical cleaning was therefore considered and a project to substantiate and then implement chemical cleaning was initiated. (authors)

  8. Boiler efficiency methodology for solar heat applications

    Science.gov (United States)

    Maples, D.; Conwell, J. C.; Pacheco, J. E.

    1992-08-01

    This report contains a summary of boiler efficiency measurements which can be applied to evaluate the performance of steam-generating boilers via both the direct and indirect methods. This methodology was written to assist industries in calculating the boiler efficiency for determining the applicability and value of thermal industrial heat, as part of the efforts of the Solar Thermal Design Assistance Center (STDAC) funded by Sandia National Laboratories. Tables of combustion efficiencies are enclosed as functions of stack temperatures and the amount of carbon dioxide and carbon monoxide in the gas stream.

  9. Combating corrosion in biomass and waste fired plant

    Energy Technology Data Exchange (ETDEWEB)

    Henderson, Pamela [Vattenfall AB, Stockholm (Sweden). Research and Development; Hjoernhede, Anders [Vattenfall AB, Gothenburg (Sweden). Power Consultant

    2010-07-01

    Many biomass- or waste-fired plants have problems with high temperature corrosion especially if the steam temperature is greater than 500 C. An increase in the combustion of waste fuels means that an increasing number of boilers have had problems. Therefore, there is great interest in reducing the costs associated with high temperature corrosion and at the same time there exists a desire to improve the electrical efficiency of a plant by the use of higher steam temperatures. Assuming that the fuel is well-mixed and that there is good combustion control, there are in addition a number of other measures which can be used to reduce superheater corrosion in biomass and waste fired plants, and these are described in this paper. These include the use of fuel additives, specifically sulphur-containing ones; design aspects like placing superheaters in less corrosive positions in a boiler, using tube shielding, a wider pitch between the tubes; operational considerations such as more controlled soot-blowing and the use of better materials. (orig.)

  10. Coal-fired power plants and the causes of high temperature corrosion

    Energy Technology Data Exchange (ETDEWEB)

    Oakey, J.E.; Simms, N.J. [British Coal Corporation, Coal Technology Development Div., Cheltenham, Glos (United Kingdom); Tomkings, A.B. [ERA Technology Ltd., Leatherhead, Surrey (United Kingdom)

    1996-12-01

    The heat exchangers in all types of coal-fired power plant operate in aggressive, high temperature environments where high temperature corrosion can severely limit their service lives. The extent of this corrosion is governed by the combined effects of the operating conditions of the heat exchanger and the presence of corrosive species released from the coal during operation. This paper reviews the coal-related factors, such as ash deposition, which influence the operating environments of heat exchangers in three types of coal-fired power plant - conventional pulverized coal boilers, fluidized bed boilers and coal gasification systems. The effects on the performance of the materials used for these heat exchangers are then compared. (au) 35 refs.

  11. Research on the treatment of boiler water of a factory%某厂蒸汽锅炉水处理研究

    Institute of Scientific and Technical Information of China (English)

    郭锋

    2015-01-01

    某厂蒸汽锅炉工作压力1.25 MPa,蒸汽量19 t/h,除氧器不开。锅炉为企业职工食堂、洗衣间提供蒸汽,冬天负责供暖。通过添加锅炉除氧剂、阻垢剂、冷凝水缓蚀剂,有效地控制了水冷壁的腐蚀、结垢和蒸汽管道与冷凝回水管道的腐蚀。药剂现场使用1a多,锅炉运行良好,顺利通过年检。%The operation situation of the steam boiler of a factory is as follows:its pressure is 1.25 MPa and the amount of steam is 19 t/h,but the boiler deaerator is not open. The boiler is used for providing steam for staff canteen laundry and heating in winter. By adding boiler deoxidizing agent ,scale inhibitor and condensed water corrosion in-hibitor,the corrosion on water-cooled-wall,the corrosion on the pipes of scaling and steam,and on the return pipes of condensate are effectively controlled. The chemicals in use for more than a year have been running well and passed the annual inspection successfully.

  12. Steam generator chemical cleaning demonstration test No. 1 in a pot boiler

    International Nuclear Information System (INIS)

    The effectiveness of the Electric Power Research Institute (EPRI Mark I) chemical cleaning solvent process was tested utilizing a 12 tube pot boiler that had previously been fouled and dented under 30 days of high chloride fault chemistry operation. Specifically, the intent of this chemical cleaning test was to: (1) dissolve sludge from the tubesheet, (2) remove non-protective magnetite from dented tube/support crevice regions, and (3) quantify the extent of corrosion of steam generator material during the test. Two laboratory cleaning demonstrations of 191 and 142 hours were performed

  13. Modelling and simulating fire tube boiler performance

    DEFF Research Database (Denmark)

    Sørensen, K.; Condra, T.; Houbak, Niels; Karstensen, C.

    2003-01-01

    A model for a flue gas boiler covering the flue gas and the water-/steam side has been formulated. The model has been formulated as a number of sub models that are merged into an overall model for the complete boiler. Sub models have been defined for the furnace, the convection zone (split in 2: a...... zone submerged in water and a zone covered by steam), a model for the material in the boiler (the steel) and 2 models for resp. the water/steam zone (the boiling) and the steam. The dynamic model has been developed as a number of Differential-Algebraic-Equation system (DAE). Subsequently Mat......Lab/Simulink has been applied for carrying out the simulations. To be able to verify the simulated results experiments has been carried out on a full scale boiler plant....

  14. Modelling and simulating fire tube boiler performance

    DEFF Research Database (Denmark)

    Sørensen, Kim; Karstensen, Claus; Condra, Thomas Joseph; Houbak, Niels

    2003-01-01

    A model for a ue gas boiler covering the ue gas and the water-/steam side has been formulated. The model has been formulated as a number of sub models that are merged into an overall model for the complete boiler. Sub models have been dened for the furnace, the convection zone (split in 2: a zone...... submerged in water and a zone covered by steam), a model for the material in the boiler (the steel) and 2 models for resp. the water/steam zone (the boiling) and the steam. The dynamic model has been developed as a number of Differential-Algebraic- Equation system (DAE). Subsequently MatLab/Simulink has...... been applied for carrying out the simulations. To be able to verify the simulated results an experiments has been carried out on a full scale boiler plant....

  15. Behaviour of welded high-strength, fine-grained structural steels with regard to cathodic stress crack corrosion

    International Nuclear Information System (INIS)

    The heat-affected zone is the zone most susceptible to hydrogen and naphta-cracking-gas corrosion. The material StE 355 exhibited high resistance to both corrosive substances. In materials in contact with boiler feedwater, stress relief annealing of welds will prevent cracking even in the case of high-strength StE 600. Hydrogen cracking induced by electrochemical processes was found to be temperature-dependent. (DG)

  16. Metal corrosion for nanofabrication.

    Science.gov (United States)

    Yu, Hai-Dong; Zhang, Zhongping; Han, Ming-Yong

    2012-09-10

    The annual cost of corrosion has been increasing globally, and it has now reached beyond 3% of the world's gross domestic product. It remains a challenge to reduce or prevent unwanted corrosion effectively after many decades of effort. Nowadays, more efforts are being made to develop anti-corrosion platforms for decreasing the huge cost of corrosion. In parallel, it is also highly expected to be able to use corrosion for producing useful materials with reduced energy consumption. In this review, recent progress in how methods for controlling metal corrosion can be used to produce structure-diversified nanomaterials are summarized along with a presentation of their applications. As a valuable addition to the scientists' toolbox, metal corrosion strategies can be applied to different metals and their alloys for the production of various nanostructured materials; this also provides insights into how metal corrosion can be further prevented and into how corrosion wastage can be reduced. PMID:22707341

  17. Ecological boiler modernization, feasible energy solutions

    International Nuclear Information System (INIS)

    Alstom Power, s.r.o., ALSTOM GROUP in Brno, Czech Republic is a successor of PBS (First Brno Machine Works). PBS was a well-known company in Bulgaria - mainly as Heating Power Plant (HPP) and Industrial Plant supplier of boilers, industrial steam turbines, milling systems, heat exchangers Btc. PBS has been privatised in two stages starting at1993 year. Alstom recently deals with boiler and heat exchanger products. Industrial turbine but has been sold to Siemens in 2004

  18. Gas fired boilers and atmospheric pollution

    International Nuclear Information System (INIS)

    A general analysis concerning atmospheric pollution is presented: chemical composition and vertical distribution of atmosphere and pollutants, chemical reactions, ozone destruction and production cycles, COx, NOx and SOx pollutions. The gas fired boiler number and repartition in France are presented and the associated pollution is analyzed (CO2, CO, NOx) and quantified. Various pollution control technics concerning gas fired boiler pollutants are described and a pollution criterion for clean gas fired generators is proposed

  19. Removal of External Deposits on Boiler Tubes

    Directory of Open Access Journals (Sweden)

    C. P. De

    1970-07-01

    Full Text Available The superheater tubes in Port and Starboard boilers were found to have completely clogged by heavy deposits, which on analysis mainly vanadium pentoxide and sodium sulphmatter. The cleaning of the deposits was accomplished by alternate spraying with 15-20 per cent hydrogen peroxide and washing with hot water jets. Over the past two years, since the date of cleaning, the IN ship is operating without any trouble in the boilers.

  20. Boiler burden reduced at Bedford site.

    Science.gov (United States)

    Horsley, Chris

    2011-10-01

    With the NHS aiming to reduce its 2007 carbon footprint by 10% by 2015, Chris Horsley, managing director of Babcock Wanson UK, a provider of industrial boilers and burners, thermal oxidisers, air treatment, water treatment, and associated services, looks at how one NHS Trust has approached the challenge, and considerably reduced its carbon emissions, by refurbishing its boiler house and moving from oil to gas-fired steam generation. PMID:22049674

  1. Transients in a circulating fluidized bed boiler

    OpenAIRE

    Baskakov, A. P.; Munts, V. A.; Pavlyuk, E. Yu.

    2013-01-01

    Transients in a circulating fluidized bed boiler firing biomass are considered. An attempt is made to describe transients with the use of concepts applied in the automatic control theory. The parameters calculated from an analysis of unsteady heat balance equations are compared with the experimental data obtained in the 12-MW boiler of the Chalmers University of Technology. It is demonstrated that these equations describe the transient modes of operation with good accuracy. Dependences for ca...

  2. Stress corrosion cracking and vibration corrosion cracking

    International Nuclear Information System (INIS)

    Under certain conditions of stress practically all metallic materials are subject to such cracking corrosion processes. They are much feared because as a rule they are not recognized until the damage - leakage of a container, fracture of a component part-occurs. They may belong to the category of either stress corrosion cracking or vibration corrosion cracking, depending on the different mechanisms of the damage process. As the denominations indicate, one constitutes the interaction between local corrosion attack and mainly static tensile stress (load stress and/or non-load stress) and the other a combination of varying mechanical stress over time and corrosion. Hydrogen-induced cracking is a special form of stress corrosion cracking characterized by trapping of atomic hydrogen in material and subsequent cracking owing to the interaction with mechanical stress. (orig./HP)

  3. Assessment of physical workload in boiler operations.

    Science.gov (United States)

    Rodrigues, Valéria Antônia Justino; Braga, Camila Soares; Campos, Julio César Costa; Souza, Amaury Paulo de; Minette, Luciano José; Sensato, Guilherme Luciano; Moraes, Angelo Casali de; Silva, Emília Pio da

    2012-01-01

    The use of boiler wood-fired is fairly common equipment utilized in steam generation for energy production in small industries. The boiler activities are considered dangerous and heavy, mainly due to risks of explosions and the lack of mechanization of the process. This study assessed the burden of physical labor that operators of boilers are subjected during the workday. Assessment of these conditions was carried out through quantitative and qualitative measurements. A heart rate monitor, a wet-bulb globe thermometer (WBGT), a tape-measure and a digital infrared camera were the instruments used to collect the quantitative data. The Nordic Questionnaire and the Painful Areas Diagram were used to relate the health problems of the boiler operator with activity. With study, was concluded that the boiler activity may cause pains in the body of intensity different, muscle fatigue and diseases due to excessive weight and the exposure to heat. The research contributed to improve the boiler operator's workplace and working conditions. PMID:22316759

  4. Additive for reducing operational problems in waste fired grate boilers; Additiv foer att minska driftproblem vid rostfoerbraenning av avfall

    Energy Technology Data Exchange (ETDEWEB)

    Gyllenhammar, Marianne; Herstad Svaerd, Solvie; Davidsson, Kent; Hermansson, Sven; Liske, Jesper; Larsson, Erik; Jonsson, Torbjoern; Zhao, Dongmei

    2013-09-01

    The combustion of waste implies a risk for deposits and corrosion in different parts of the combustion facility. In recent years, research and tests have been performed in order to find ways to mitigate these problems in waste-fired plants. Most waste-fired plants in Sweden are grates whereas most of the research has been carried out in fluidized bed plants. The purpose of this project is to examine whether co-firing of sewage sludge and waste can reduce deposition and corrosion also in grate-fired boilers as has been shown in fludised beds. The objective is to determine the deposit growth and its composition as well as describing the initial corrosion attack. Representing sulphur-rich waste, elementary sulphur is also added to the waste and thereby compared with sludge as an additive. The target groups for this project are plant owners, researchers, consultants and authorities. Tests were performed in a 15 MWth waste-fired boiler with moving grate at Gaerstadverket, Tekniska Verken (Linkoeping). The boiler produces saturated steam of 17 bars and 207 deg C, and the normal fuel mixture contains of household and industry waste. The results show that co-firing with as heigh as 20 weight-% SLF (25 energy-%) was possible from an operational point of view, but the deposit rate increased especially at the two warmest positions. Generally the deposit rate was highest in the position closest to the boiler and decreased further downstream. During the tests a lot higher amount of SLF than normal was used (recommended mix is 5-10 % of SLF) this to be able to see effects of the different measures. Up to 23 weight-% of the rather moist sewage sludge was possible to fire when co-firing waste and SLF, without addition of oil. By adding sludge the deposit rate decreased but the increase upon adding SLF to ordinary waste was not totally eliminated. In the tests 'Avfall and SLF' the deposits were rich in chlorine. High concentrations of metal chlorides were found in the

  5. Countermeasures to corrosion on water walls; Aatgaerder mot eldstadskorrosion paa panntuber

    Energy Technology Data Exchange (ETDEWEB)

    Storesund, Jan; Sund, Goeran; Pettersson, Rachel; Nordling, Magnus; Hoegberg, Jan

    2007-12-15

    Corrosion of water walls is becoming a problem for an increasing number of boilers. Wider use of biomass and waste for fuel, as well as requirements of reduced NO{sub x} emissions, makes it much more difficult to avoid combustion in a reducing atmosphere adjacent to the water walls. This has increased the need for corrosion protection in many existing boilers. In addition, biomass and waste fuelled plants currently being planned or built require well-functioning water wall protection from the start. The traditional water wall materials - ferritic low alloyed steels - are not easy to replace because of their outstanding heat transfer properties, ability to form a protective oxide layer on the inside of the tubes and low thermal expansion. For this reason, corrosion protection generally involves the use of some kind of coating on the tubes. In this report, the state-of-the-art regarding water wall corrosion protection is described in a literature survey. Methods covered are the use of refractories, overlay weld cladding, composite tubes and thermal spraying. The interest for overlay welding has increased recently since it can offer similar corrosion protection to composite tubes at a significantly reduced cost. Test panels have been exposed and monitored in different boilers. Six weld overlay materials were tested: the well-proven Alloy 625, a modified Alloy 625 in which niobium has been replaced by tungsten, Alloy 59, Alloy 22, a cheaper nickel base alloy 650 which contains some iron and a 310 grade stainless steel. A total of six panels were exposed in the most vulnerable positions in three different boilers. These included waste and biomass combustion as well as different steam data, sizes and types of boilers. Two further facilities, in which the test materials Alloy 625 and Sanicro 28 had already been installed, were also included in the investigation. The duration of service exposure was one operating season. The weld cladding was measured with a thickness

  6. Fireside corrosion testing of candidate superheater tube alloys, coatings, and claddings -- Phase 2

    Energy Technology Data Exchange (ETDEWEB)

    Blough, J.L.; Seitz, W.W. [Foster Wheeler Development Corp., Livingston, NJ (United States)

    1997-12-01

    In Phase 1 a variety of developmental and commercial tubing alloys and claddings were exposed to laboratory fireside corrosion testing simulating a superheater or reheater in a coal-fired boiler. Phase 2 (in situ testing) has exposed samples of 347 RA-85H, HR3C, 253MA, Fe{sub 3}Al + 5Cr, 310 Ta modified, NF 709, 690 clad, and 671 clad for approximately 4,000, 12,000, and 16,000 hours to the actual operating conditions of a 250-MW coal-fired boiler. The samples were assembled on an air-cooled, retractable corrosion probe, the probe was installed in the reheater activity of the boiler and controlled to the operating metal temperatures of an existing and advanced-cycle coal-fired boiler. The results will be presented for the preliminary metallurgical examination of the corrosion probe samples after 16,000 hours of exposure. Continued metallurgical and interpretive analysis is still on going.

  7. Rivesville multicell fluidized bed boiler. Annual technical progress report. July 1978-June 1979

    Energy Technology Data Exchange (ETDEWEB)

    1980-08-01

    Design, construction and test program of a 300,000 lb/hr steam generating capacity multicell fluidized bed boiler (MFB), as a pollution free method of burning high-sulfur or highly corrosive coals, is being carried out. The concept involves burning fuels such as coal, in a fluidized bed of limestone particles that react with the sulfur compounds formed during combustion to reduce air pollution. Nitrogen oxide emissions are also reduced at the lower combustion temperatures. The CaSO/sub 4/ produced in the furnace is discharged with the ash or regenerated to CaO for reuse in the fluidized bed. Information is presented on continued operation of the Rivesville MFB steam generating plant in a commercial mode and for determining performance and emission characteristics; studies and tests on flyash characterization and reinjection, fuel feed eductors and needles, air distributor, corrosion-erosion and sulfur capture; engineering studies to improve MFB performance and reliability.

  8. METHANE de-NOX for Utility PC Boilers

    Energy Technology Data Exchange (ETDEWEB)

    Bruce Bryan; Serguei Nester; Joseph Rabovitser; Stan Wohadlo

    2005-09-30

    The overall project objective is the development and validation of an innovative combustion system, based on a novel coal preheating concept prior to combustion, that can reduce NO{sub x} emissions to 0.15 lb/million Btu or less on utility pulverized coal (PC) boilers. This NO{sub x} reduction should be achieved without loss of boiler efficiency or operating stability, and at more than 25% lower levelized cost than state-of-the-art SCR technology. A further objective is to ready technology for full-scale commercial deployment to meet the market demand for NO{sub x} reduction technologies. Over half of the electric power generated in the U.S. is produced by coal combustion, and more than 80% of these units utilize PC combustion technology. Conventional measures for NOx reduction in PC combustion processes rely on combustion and post-combustion modifications. A variety of combustion-based NO{sub x} reduction technologies are in use today, including low-NO{sub x} burners (LNBs), flue gas recirculation (FGR), air staging, and natural gas or other fuel reburning. Selective non-catalytic reduction (SNCR) and selective catalytic reduction (SCR) are post-combustion techniques. NO{sub x} reduction effectiveness from these technologies ranges from 30 to 60% and up to 90-93% for SCR. Typically, older wall-fired PC burner units produce NO{sub x} emissions in the range of 0.8-1.6 lb/million Btu. Low-NO{sub x} burner systems, using combinations of fuel staging within the burner and air staging by introduction of overfire air in the boiler, can reduce NO{sub x} emissions by 50-60%. This approach alone is not sufficient to meet the desired 0.15 lb/million Btu NO{sub x} standard with a range of coals and boiler loads. Furthermore, the heavy reliance on overfire air can lead to increased slagging and corrosion in furnaces, particularly with higher-sulfur coals, when LNBs are operated at sub-stoichiometric conditions to reduce fuel-derived NOx in the flame. Therefore, it is desirable

  9. Extensive feedwater quality control and monitoring concept for preventing chemistry-related failures of boiler tubes in a subcritical thermal power plant

    International Nuclear Information System (INIS)

    Prevention and minimizing corrosion processes on steam generating equipment is highly important in the thermal power industry. The maintenance of feedwater quality at a level corresponding to the standards of technological designing, followed by timely respond to the fluctuation of measured parameters, has a decisive role in corrosion prevention. In this study, the comprehensive chemical control of feedwater quality in 210 MW Thermal Power Plant (TPP) was carried out in order to evaluate its potentiality to assure reliable function of the boiler and discover possible irregularity that might be responsible for frequent boiler tube failures. Sensitive on-line and off-line analytical instruments were used for measuring key and diagnostic parameters considered to be crucial for boiler safety and performances. Obtained results provided evidences for exceeded levels of oxygen, silica, sodium, chloride, sulfate, copper, and conductivity what distinctly demonstrated necessity of feedwater control improvement. Consequently, more effective feedwater quality monitoring concept was recommended. In this paper, the explanation of presumable root causes of corrosive contaminants was given including basic directions for their maintenance in proscribed limits. -- Highlights: • Feedwater quality monitoring practice in a thermal power plant has been evaluated. • The more efficient feedwater quality control have been applied. • Analysis of feedwater quality parameters has been performed. • Exceeded levels of corrosive contaminants were found. • Recommendations for their maintenance at proscribed values were given

  10. FEASIBILITY ANALYSIS FOR INSTALLING A CIRCULATING FLUIDIZED BED BOILER FOR COFIRING MULTIPLE BIOFUELS AND OTHER WASTES WITH COAL AT PENN STATE UNIVERSITY

    Energy Technology Data Exchange (ETDEWEB)

    Bruce G. Miller; Sharon Falcone Miller; Robert Cooper; John Gaudlip; Matthew Lapinsky; Rhett McLaren; William Serencsits; Neil Raskin; Tom Steitz; Joseph J. Battista

    2003-03-26

    The Pennsylvania State University, utilizing funds furnished by the U.S. Department of Energy's Biomass Power Program, investigated the installation of a state-of-the-art circulating fluidized bed boiler at Penn State's University Park campus for cofiring multiple biofuels and other wastes with coal, and developing a test program to evaluate cofiring biofuels and coal-based feedstocks. The study was performed using a team that included personnel from Penn State's Energy Institute, Office of Physical Plant, and College of Agricultural Sciences; Foster Wheeler Energy Services, Inc.; Foster Wheeler Energy Corporation; Parsons Energy and Chemicals Group, Inc.; and Cofiring Alternatives. The activities included assessing potential feedstocks at the University Park campus and surrounding region with an emphasis on biomass materials, collecting and analyzing potential feedstocks, assessing agglomeration, deposition, and corrosion tendencies, identifying the optimum location for the boiler system through an internal site selection process, performing a three circulating fluidized bed (CFB) boiler design and a 15-year boiler plant transition plan, determining the costs associated with installing the boiler system, developing a preliminary test program, determining the associated costs for the test program, and exploring potential emissions credits when using the biomass CFB boiler.

  11. Research and design of 330 MW circulating fluidized bed boiler

    Energy Technology Data Exchange (ETDEWEB)

    Sun, Xianbin; Shi, Zhenghai; Huang, Zhong [Thermal Power Research Institute, Xi' an (China); Jiang, Minhua [China Huaneg Group, Beijing (China); Yu, Long; Zhang, Yanjun; Wang, Fengjun; Zhang, Man [Harbin Boiler CO., Ltd, Harbin (China)

    2013-07-01

    Based on research and manufacture of 210MW circulating fluidized bed (CFB) boiler, the key technologies of large CFB boiler have been Research, the plan design of 330MW CFB boiler have been performed, construction design of key components and scaling up characteristics were analysed, The 330MW CFB boiler designed demonstration project has been put into commercial operation, It is the largest capacity CFB boiler operated in china now, Operation of 330MW CFB boiler was stable and good performance has been proved.

  12. Corrosion inhibiting organic coatings

    Energy Technology Data Exchange (ETDEWEB)

    Sasson, E.

    1984-10-16

    A corrosion inhibiting coating comprises a mixture of waxes, petroleum jelly, a hardener and a solvent. In particular, a corrosion inhibiting coating comprises candelilla wax, carnauba wax, microcrystalline waxes, white petrolatum, an oleoresin, lanolin and a solvent.

  13. Fuel sulfur and boiler fouling

    Energy Technology Data Exchange (ETDEWEB)

    Litzke, W.; Celebi, Y.; Butcher, T. [Brookhaven National Lab., Upton, NY (United States)

    1995-04-01

    Fouling of the heat transfer surfaces of boilers and furnaces by `soot` leads to reduced efficiency and increased service requirements. The average level of annual efficiency reduction as a result of fouling if generally accepted as 2% per year. Improving the efficiency of equipment in the field may be the most important oil heat conservation opportunity at present. Improvements can be realized by reducing fouling rates, promoting lower firing rates in existing equipment, and enabling excess air levels to be set lower without raising concerns about increased service requirements. In spite of the importance of efficiency in the field there is very little data available on efficiency degradation rates with modern equipment, actual field operating conditions (excess air and smoke number settings) and service problems which affect efficiency. During 1993-94 field tests were initiated to obtain such data and to obtain information that would compliment existing and current laboratory work. Experimental work conducted on a bench scale level have included tests with various advanced burners, fuel types, and different operating conditions which have been done at the BNL Rapid Fouling Test Facility. This report will focus on the field study of fouling effects on ten residential heating service problems at each site are summarized. In addition, the technical difficulties involved with conducting such a field study shall also be discussed as the findings should serve to improve future work in this area.

  14. Influence of corrosion on the strain profiles of pipelines

    Energy Technology Data Exchange (ETDEWEB)

    Jamieson, G.; Newhook, J.P. [Dalhousie Univ., Halifax, NS (Canada). Dept. of Civil Engineering

    2003-07-01

    Natural gas, oil and petroleum products in Canada are transported by pipelines, many of which are over a quarter of a century old. A major challenge facing the petroleum industry is corrosion of pipelines. To minimize the probability of a line failure, pipeline owners adhere to strict inspection and maintenance schedules. Maintenance, using current in-line inspection tools, necessitates the transmission lines to be shut down. This paper described an alternative way to detect pipeline corrosion, using a numerical investigation of the change in strain profile of a corroded pipeline under internal pressure. A finite element model of a typical thin-walled pressure vessel was created under linear elastic axisymmetric conditions. The thinning of the wall simulated corrosion. The authors studied the change in longitudinal and circumferential strain under the same operating pressure. A parametric study was performed using a wide array of corrosion geometries and depths. A distinct and detectable change in strain for specific degrees of corrosion was identified. An increase in the amount of corrosion resulted in an increase in the rate of circumferential and longitudinal strains. The geometry of the corrosion profile had a big influence on the slope of the strain gradient. According to the initial evaluation, it appears feasible to design a structural health monitoring system using continuous strain monitoring as its basis, but additional studies are required to model actual in-situ pipeline conditions, as well as an assessment of non-linear response. 5 refs., 2 tabs., 7 figs.

  15. Modelling of Corrosion Cracks

    DEFF Research Database (Denmark)

    Thoft-Christensen, Palle

    Modelling of corrosion cracking of reinforced concrete structures is complicated as a great number of uncertain factors are involved. To get a reliable modelling a physical and mechanical understanding of the process behind corrosion in needed.......Modelling of corrosion cracking of reinforced concrete structures is complicated as a great number of uncertain factors are involved. To get a reliable modelling a physical and mechanical understanding of the process behind corrosion in needed....

  16. Corrosion in waste incineration facilities; Korrosion i avfallsfoerbraenningsanlaeggningar

    Energy Technology Data Exchange (ETDEWEB)

    Staalenheim, Annika; Henderson, Pamela

    2004-11-01

    Waste is a heterogeneous fuel, often with high levels of chlorine, alkali and heavy metals. This leads to much more severe corrosion problems than combustion of fossil fuels. The corrosion rates of the materials used can be extremely high. Materials used for heat transferring parts are usually carbon steel or low alloyed steel. These are significantly cheaper than other steels. Austenitic stainless steel is also used, but is often avoided due to its sensitivity to stress corrosion cracking. More advanced materials, such as nickel base alloys, can be used in extremely aggressive environments. Since these materials are expensive and do not always have sufficient mechanical properties, they are often used as coatings on carbon steel tubes or as composite tubes. A new method, which shows good results at the first tests in plants, is electroplating with nickel. Plastic materials can be used in low temperature parts if the temperature does not exceed 150 deg C. A glass fibre inforced material is probably the best choice. The parts of the furnace that are most prone to corrosion are waterwalls where the refractory coating is lost, has not been applied to a sufficient height in the boiler or is not used at all. Failures of superheaters often occur in areas near soot blowers or on the tubes exposed to the highest flue gas temperatures. Few cases of low temperature corrosion are reported in the literature, possibly because these problems are unusual or because low temperature corrosion rarely causes costly and dramatic failures. Waterwall tubes should be made of carbon steel, because of the price and to minimise the risk for stress corrosion cracking. Usually the tubes must be covered with a more corrosion resistant material to withstand the environment in the boiler. Metal coatings can be used in less demanding environments. Refractory is probably the best protection for waterwalls from severe erosion. Surfaces in extremely corrosive areas, e.g. the fuel feed area, should

  17. Erosion-corrosion

    International Nuclear Information System (INIS)

    A literature study on erosion-corrosion of pipings in the nuclear industry was performed. Occurred incidents are reviewed, and the mechanism driving the erosion-corrosion is described. Factors that influence the effect in negative or positive direction are treated, as well as programs for control and inspection. Finally, examples of failures from databases on erosion-corrosion are given in an attachment

  18. Management of Reinforcement Corrosion

    DEFF Research Database (Denmark)

    Küter, André; Geiker, Mette Rica; Møller, Per

    Reinforcement corrosion is the most important cause for deterioration of reinforced concrete structures, both with regard to costs and consequences. Thermodynamically consistent descriptions of corrosion mechanisms are expected to allow the development of innovative concepts for the management of...... reinforcement corrosion....

  19. Effect of hot corrosion on the creep properties of types 321 and 347 stainless steels

    Science.gov (United States)

    González-Rodríguez, J. G.; Luna-Ramírez, A.; Martínez-Villafañe, A.

    1999-02-01

    Problems caused by hot corrosion and creep damage on superheater and reheater tubes of power plants using heavy oil as fuel inhibit the continuous service of the boilers and shorten their design lives. The acceleration of hot corrosion attack of boilers is caused by the presence of fuel ash deposits containing V, Na, and S, in the form of Na2SO4 and V2O5, which form low melting point phases. In addition to this, the tubes are exposed to the action of both high stresses and high temperatures, producing a continuous plastic deformation of the tube walls called creep damage. Creep rupture tests were carried out in the temperature range 620 to 670 °C in static air in the presence of corrosive environments using 321H and 347H type stainless steels used in superheater and reheater tubes under hot corrosion and creep environments. The corrosive environment includes synthetic Na2SO4, V2O5, and the mixture 80% V2O5-20%Na2SO4. Also, the role of the different elements present in the environments on corrosion was investigated using electronic microscopy and x-ray diffraction techniques.

  20. Quarterly Report (QR1)

    OpenAIRE

    Loomis, Charles; O'Callaghan, David; Bégin, Marc-Elian; Floros, Evangelos; Caceres, Juan

    2010-01-01

    In the first quarter of the project, the participants have successfully laid the foundations for creating a stable, comprehensive, open-source cloud platform. The project has put in place the tools and processes to quickly build and expand the StratusLab distribution. Through dialog with targeted communities and through the partners' experience it has developed the initial architecture of the StratusLab distribution. The initial releases have been validated on the project's cloud infrastructu...

  1. Fireside corrosion testing of candidate superheater tube alloys, coatings, and claddings - Phase II

    Energy Technology Data Exchange (ETDEWEB)

    Blough, J.L.; Krawchuk, M.T.; Van Weele, S.F. [Foster Wheeler Development Corp., Livingston, NJ (United States)

    1995-08-01

    A number of developmental and commercial tubing alloys and claddings have previously been exposed in Phase I to laboratory fireside corrosion testing simulating a superheater or reheater in a coal-fired boiler. This program is exposing samples of TP 347, RA-85H, HR-3C, 253MA, Fe{sub 3}Al + 5Cr, 310 modified, NF-709, 690 clad, and 671 clad, which showed good corrosion resistance from Phase 1, to the actual operating conditions of a 250-MW, coal-fired boiler. The samples were installed on air-cooled, retractable corrosion probes, installed in the reheater cavity, and are being controlled to the operating metal temperatures of an existing and advanced-cycle coal-fired boiler. The exposure will continue for 4000, 12,000, and 16,000 hours of operation. After the three exposure times, the samples will be metallurgically examined to determine the wastage rates and mode of attack. The probes were commissioned November 16, 1994. The temperatures are being recorded every 15 minutes, and the weighted average temperature calculated for each sample. Each of the alloys is being exposed to a temperature in each of two temperature bands-1150 to 1260{degrees}F and 1260 to 1325{degrees}F. After 2000 hours of exposure, one of the corrosion probes was cleaned and the wall thicknesses were ultrasonically measured. The alloy performance from the field probes will be discussed.

  2. EDF - Quarterly Financial Information

    International Nuclear Information System (INIS)

    EDF's sales in the first quarter of 2014 were euro 21.2 billion, down 3.9% from the first quarter of 2013. At constant scope and exchange rates, sales were down 4.2% due to mild weather conditions, which impacted sales of electricity in France, gas sales abroad and trading activities in Europe. UK sales were nonetheless sustained by B2B sales due to higher realised wholesale market prices. In Italy, sales growth was driven by an increase in electricity volumes sold. The first quarter of 2014 also saw the strengthening of the Group's financial structure with the second phase of its multi-annual hybrid funding programme (nearly euro 4 billion equivalent) as well as the issue of two 100-year bonds in dollars and sterling aimed at significantly lengthening average debt maturity. 2014 outlook and 2014-2018 vision: - EDF Group has confirmed its financial objectives for 2014; - Group EBITDA excluding Edison: organic growth of at least 3%; - Edison EBITDA: recurring EBITDA target of euro 1 billion and at least euro 600 million in 2014 before effects of gas contract re-negotiations; - Net financial debt / EBITDA: between 2x and 2.5x; - Pay-out ratio of net income excluding non-recurring items post-hybrid: 55% to 65%. The Group has reaffirmed its goal of achieving positive cash flow after dividends, excluding Linky, in 2018

  3. Boiler house modernization through shared savings program

    Energy Technology Data Exchange (ETDEWEB)

    Breault, R.W. [Tecogen, Waltham, MA (United States)

    1995-12-31

    Throughout Poland as well as the rest of Eastern Europe, communities and industries rely on small heat only boilers to provide district and process heat. Together these two sectors produce about 85,000 MW from boilers in the 2 to 35 MW size range. The bulk of these units were installed prior to 1992 and must be completely overhauled to meet the emission regulations which will be coming into effect on January 1, 1998. Since the only practical fuel is coal in most cases, these boilers must be either retrofit with emission control technology or be replaced entirely. The question that arises is how to accomplish this given the current tight control of capital in Poland and other East European countries. A solution that we have for this problem is shared savings. These boilers are typically operating with a quiet low efficiency as compared to western standards and with excessive manual labor. Installing modernization equipment to improve the efficiency and to automate the process provides savings. ECOGY provides the funds for the modernization to improve the efficiency, add automation and install emission control equipment. The savings that are generated during the operation of the modernized boiler system are split between the client company and ECOGY for a number of years and then the system is turned over in entirety to the client. Depending on the operating capacity, the shared savings agreement will usually span 6 to 10 years.

  4. Boiler MACT Technical Assistance (Fact Sheet)

    Energy Technology Data Exchange (ETDEWEB)

    2012-03-01

    Fact sheet describing the changes to Environmental Protection Act process standards. The DOE will offer technical assistance to ensure that major sources burning coal and oil have information on cost-effective, clean energy strategies for compliance, and to promote cleaner, more efficient boiler burning to cut harmful pollution and reduce operational costs. The U.S. Environmental Protection Agency (EPA) is expected to finalize the reconsideration process for its Clean Air Act pollution standards National Emissions Standards for Hazardous Air Pollutants for Major Sources: Industrial, Commercial, and Institutional Boilers and Process Heaters (known as Boiler Maximum Achievable Control Technology (MACT)), in Spring 2012. This rule applies to large and small boilers in a wide range of industrial facilities and institutions. The U.S. Department of Energy (DOE) will offer technical assistance to ensure that major sources burning coal or oil have information on cost-effective clean energy strategies for compliance, including combined heat and power, and to promote cleaner, more efficient boilers to cut harmful pollution and reduce operational costs.

  5. Countermeasures to corrosion on water walls. Part 2; Aatgaerder mot eldstadskorrosion paa panntuber. Etapp 2

    Energy Technology Data Exchange (ETDEWEB)

    Storesund, Jan; Elger, Ragna; Nordling, Magnus; Viklund, Peter

    2011-01-15

    Background: The problems with water wall corrosion have been accelerating over the last years. There are a number of reasons for this. Originally mild steels were successfully used in power plant water walls. The magnetite layer that forms at the fire side of the tubes when the boiler is taken into operation protected from corrosion attack. The fuels at that time (oil, coal, gas) were not able to break down the magnetite by corrosion. In addition, there were no restrictions for pollutions and for the combustion itself that could contribute to corrosion attack. The usage of fossil fuels has decreased substantially over the last 25 years, not least by environmental reasons. As a replacement a number of different kinds of bio mass fuels are used. These are typically more or less corrosive and the magnetite layers are attacked. The corrosion is often supported by reducing conditions as a result of the restrictions of the NO{sub x}-pollution. Also the waste fuelled boilers have huge corrosion problems. This has been the case for the last 25 years but nowadays the number of such plants is so much higher and the service data have been turned up. Corrosion protection of the water wall tubes started to be successful in the beginning of the seventies by the introduction of the composite tube. Such tubes are fabricated by mild steel or a low alloy core and corrosion resistant austenite steel or nickel base as an about 2 mm thick corrosion protective coating. Weld cladding of the water wall tubes was introduced in the 1980's as a significantly cheaper alternative to the composite tubes. Thermal spraying and refractory protection are other methods. These corrosion protection methods have not always been effective. For example, depending on incorrect materials selection, incorrect performance and incorrect method selection for the current corrosion or erosion attack. Therefore, there is a need for increased knowledge of which protection method and material that will work

  6. Data for modern boilers used in co-combustion; Moderna panndata inom samfoerbraenning

    Energy Technology Data Exchange (ETDEWEB)

    Thorson, Ola [S.E.P. Scandinavian Energy Project AB, Goeteborg (Sweden)

    2004-04-01

    This project is a survey and a description of today's technical status and future development trends in the field of co-combustion. The survey is done from an energy production company's point of view and two technical questions have been studied; the possibilities for high steam data and the possibilities for a wide load range. These parameters are limited by the corrosive properties of the fuel and the environmental requirements in the EU directive for combustion of waste. In the report following issues are discussed: Examples of and experiences from co-combustion plants and plants that combust problematic fuels and have high steam data. A future prospect of high steam data in co-combustion plants by the usage of modern technical solutions and a description of these solutions. Important research and development results from combustion of problematic fuels in combination with high steam data. Choice of firing technology, boiler design and auxiliary systems and its affection on the load range in a boiler for co-combustion. A literature survey has been done to get the latest results from combustion of problematic fuels. Then a number of interesting plants have been identified and facts about them have been collected by contacts with plant owners, suppliers and professional researchers and also through publications. The report shows that Sweden, Finland and Denmark are in the front line of using high steam data for co-combustion of biomass and waste fuels. There are/have been problems with superheater corrosion in many of these plants but a number of ways how to handle high steam data have been identified: Adjust the fuel mix or add additives; Use high alloy materials; Consider the final super heater as a part that is worn out by time; Place the final super heater in the particle loop seal/sand locker; Use an external separate fired super heater; Gasification and then co-combustion of the pyrolysis gas in a conventional existing boiler; Place the

  7. FAILURE ANALYSIS IN TUBING OF AIR PREHEATER OF BOILER FROM A SUGARCANE MILL

    Directory of Open Access Journals (Sweden)

    Joner Oliveira Alves

    2014-10-01

    Full Text Available The increased demand for energy from sugarcane bagasse has made the sugar and alcohol mills search alternatives to reduce maintenance of the boilers, releasing more time to the production. The stainless steel use has become one of the main tools for such reduction. However, specification errors can lead to premature failures. This work reports the factors that led tubes of AISI 409 stainless steel fail after half season when applied in a air preheater of boiler from a sugarcane mill. In such application, the AISI 304 lasts about 15 seasons and the carbon steel about 3. A tube sent by the sugar mill was characterized by wet chemical analysis, optical microscopy and EDS. Results indicated chloride formation on the internal walls of the tube, which combined with the environment, accelerated the corrosion process. The carbon steel showed high lifetime due to a 70% higher thickness. Due to the work condictions is recommended the use of stainless steels with higher corrosion resistance, such as the traditional AISI 304 or the ferritic AISI 444, the last presents better thermal exchange.

  8. An advanced maintenance advisory and surveillance system for boiler tubes - AMASS

    Energy Technology Data Exchange (ETDEWEB)

    Tomkins, A.B. [ERA Technology Ltd, Leatherhead (United Kingdom)

    1998-12-31

    In a recently completed European collaborative project, the aim was to address the issue of boiler tube failures and thereby plant availability. The reduction of forced outages due to component failures and the reduction of planned outages for preventative maintenance can both contribute in this respect. It has been possible to assess tube degradation due to erosion, corrosion and overheating through the use of on-line techniques (thin layer activation, corrosion probes and novel temperature sensors) and off-line techniques (cold air velocity measurements, laser shearography and measurements of steam side oxide) which have been developed in the project. These techniques have been demonstrated on an oil fired boiler in Portugal and a coal fired unit in Spain. The output from the monitoring techniques has been integrated in the AMASS maintenance advisory and surveillance system. This is a computerised system comprising a spatial database with add-on tools designed to assess data from individual monitors and to provide the user with information on tube life utilisation rates and the probability of tube failure occurring. A description of the monitoring techniques will be described along with some of the results of demonstrating them in the field. Also an overview of the computerized system and the way in which it works will be given along with examples of how it can be used to assist with preventative maintenance and to help avoid unplanned outages. (orig.) 10 refs.

  9. Discrepancies Between Quarterly GDP Estimates

    OpenAIRE

    Adriaan M. Bloem

    1997-01-01

    Countries compiling quarterly estimates for gross domestic product (GDP) often use alternative approaches simultaneously. This may result in the publication of different measures of quarterly GDP and discrepancies between these measures. Such discrepancies are unavoidable, unless reconciliation takes place or the measures are mutually interdependent. This paper examines international practices in this respect, focusing on OECD member countries that publish quarterly GDP data. Of these, five p...

  10. Establishment of Optimum Ecological System for Monitoring Boiler Units

    OpenAIRE

    V. I. Nazarov

    2014-01-01

    A mathematical model has been proposed for ecological monitoring of a boiler unit. This model makes it possible to obtain maximum decrease in effluents at minimum reduction in economical operational efficiency of the boiler unit.

  11. Differences in the composition of organic impurities in ground and surface waters. Consequences for the preparation of boiler feed water

    International Nuclear Information System (INIS)

    It is generally accepted that current limits for total organic carbon (TOC) in the pharmaceutical industry (500 ppb) and semiconductor industry (10-25 ppb) should be regarded as precautionary measures and do not necessarily reflect true scientific evidence. For the power industry the situation is different. Here, recommended TOC-limits for boiler feed waters (in 1999: VGB: 200 ppb; EPRI: 100 ppb) are based on scientific and empirical data. The oxidation of, say, 50 ppb TOC to carbon dioxide in the water/steam cycle will increase steam condensate conductivity by 0.48 μS/cm (values may depend on literature source, here [1]), a value which is not acceptable as it desensitizes the detection of leaks in cooling water heat exchangers. Apart from this indirect effect of TOC there is also evidence for direct negative effects of TOC on steel materials. Even small amounts of organic acids, which are produced as intermediates in the TOC oxidation process, may locally lower the pH down to levels [2] where erosion corrosion of boiler tubes can take place. It was also found that carbon is enriched in stress corrosion cracks of turbine materials [3]. The present paper will discuss the ''TOC-issue'' in boiler feed water preparation. Most of the results can be applied also to other industries, e.g. semiconductor, chemical or pharmaceutical. (authors)

  12. Theory and Practice of steel surface protection in boilers; Schutz der Stahloberflaechen von Dampferzeugern. Theorie und Praxis

    Energy Technology Data Exchange (ETDEWEB)

    Jensen, J.P.; Daucik, K. [SV Produktion a.m.b.a., Skaerbaek, Fredericia (Denmark); Smitshuysen, E.F. [Faelleskemikerne, I/S Vestkraft, Esbjerg (Denmark)

    1999-10-01

    Protective magnetite steel surface layers developing in steam generators may be subject to aggressive attacks. However, even if general guidelines for the bulk water are met with respect to the water purity (acid conductivity) and conditioning chemicals, damage can occur. The reason may be the disregarding of interaction among material, design and chemistry. Different boiler water treatments are discussed in detail. The influence of pressure and pH on the stability of the protective layer is described. Experience on how solid alkaline conditioning combined with inadequate design can result in severe corrosion and boiler tube failures is outlined. It is also being described how simple modifications of the boiler design can resolve solid alkaline corrosion. (orig.) [Deutsch] Magnetit-Schutzschichten, die sich auf den Stahlflaechen von Dampferzeugern ausbilden, sind oftmals aggressiven Angriffen ausgesetzt. Daraus koennen sich Schaeden entwickeln, die nur durch optimales Speise- und Kesselwasser vermieden werden koennen. Doch selbst bei Einhaltung allgemeiner Richtlinien im Hinblick auf Wasserreinheit (Saeureleitfaehigkeit) und Alkalisierungsmittel koennen Schaeden auftreten, wenn bedeutende, sich gegenseitig beeinflussende Parameter, wie Werkstoffwahl, Auslegung und chemische Fahrweise, nicht ausreichend beachtet werden. Die unterschiedlichen Moeglichkeiten der Wasserkonditionierung werden detailliert eroertert. Druck und pH-Wert nehmen ebenfalls Einfluss auf die Stabilitaet der Schutzschicht. Die Autoren berichten ueber Faelle, in denen feste Alkalisierungsmittel in Kombination mit einer nicht geeigneten Kesselkonstruktion zu schwerwiegender Korrosion und Rohrschaeden gefuehrt haben. Weiterhin wird gezeigt, wie dank einfacher Veraenderungen am Dampferzeuger das durch feste Alkalisierungsmittel hervorgerufene Korrosionsproblem geloest werden kann. (orig.)

  13. Co-firing of coal with biomass and waste in full-scale suspension-fired boilers

    Energy Technology Data Exchange (ETDEWEB)

    Dam-Johansen, Kim; Frandsen, Flemming J.; Jensen, Peter A.; Jensen, Anker D. [Technical Univ. of Denmark, Lyngby (Denmark). Dept. of chemical and Biochemical Engineering

    2013-07-01

    The energy policy in Denmark has for many years focused on lowering the net CO{sub 2} emission from heat and power production by replacing fossil fuels by renewable resources. This has been done by developing dedicated grate-fired boilers for biomass and waste fuels but also by developing coal-based suspension-fired boilers to accept still higher fractions of biomass or waste material as fuels. This last development has been challenging of many reasons, including pre-treatment of fuels, and solving potential emission and operational problems during the simultaneous development of supercritical steam cycles with steam temperatures close to 600 C, providing power efficiencies close to 50% (Hein KRG, Sustainable energy supply and environment protection - strategies, resources and technologies. In: Gupta R, Wall T, Hupa M, Wigley F, Tillman D, Frandsen FJ (eds) Proceedings of international conference on impact of fuel quality on power production and the environment, Banff Conference Centre, Banff, Alberta, Canada, 29 Sept-4 Oct, 2008). For 25 years the CHEC (Combustion and Harmful Emission Control) Research Centre at DTU Chemical Engineering, has attained a leading role in research, supporting power producing industry, plant owners and boiler manufacturers to optimize design and operation and minimize cost and environmental impact using alternative fuels in suspension fired boilers. Our contribution has been made via a combination of full-scale measuring campaigns, pilot-scale studies, lab-scale measurements and modeling tools. The research conducted has addressed many issues important for co-firing, i.e. fuel processing, ash induced boiler deposit formation and corrosion, boiler chamber fuel conversion and emission formation, influence on flue gas cleaning equipment and the utilization of residual products. This chapter provides an overview of research activities, aiming at increasing biomass shares during co-firing in suspension, conducted in close collaboration with

  14. Towards Corrosion Detection System

    Directory of Open Access Journals (Sweden)

    B.B.Zaidan

    2010-05-01

    Full Text Available Corrosion is a natural process that seeks to reduce the binding energy in metals. The end result of corrosion involves a metal atom being oxidized. Surface corrosion on aluminum aircraft skins, near joints and around fasteners, is often an indicator of buried structural corrosion and cracking In this paper we proposed a new method on which we are moving towards designing a method to detect the corrosion within the metals, the new method has defined texture analysis as the main method for this approach, the proposed enhancement shows less false positive and less false negative. The main functions used in this approach beside texture analysis are Edge detection, structure element and image dilation. The new approach has designed to detect a part of the image that has been affected by the corrosion, the tested images has showed a good result lying on detecting the corrosion part from the image.

  15. Corrosion behavior of mild steel and SS 304L in presence of dissolved nickel under aerated and deaerated conditions

    OpenAIRE

    Mohd Mobin; Hina Shabnam

    2011-01-01

    In dual purpose water/power co-generation plants, the presence of high concentration of Cu and Ni in the re-circulating brine/condensate as a result of condenser tubes corrosion has been attributed as one of the several causes of corrosion damage of flash chamber materials and water touched parts of the boilers. The present investigation deals with the effect of dissolved nickel in the concentration range of 10 ppb to 100 ppm on the corrosion behavior of mild steel and SS 304L in two aqueous ...

  16. Computer simulation of the fire-tube boiler hydrodynamics

    Directory of Open Access Journals (Sweden)

    Khaustov Sergei A.

    2015-01-01

    Full Text Available Finite element method was used for simulating the hydrodynamics of fire-tube boiler with the ANSYS Fluent 12.1.4 engineering simulation software. Hydrodynamic structure and volumetric temperature distribution were calculated. The results are presented in graphical form. Complete geometric model of the fire-tube boiler based on boiler drawings was considered. Obtained results are suitable for qualitative analysis of hydrodynamics and singularities identification in fire-tube boiler water shell.

  17. Application of GPRS and GIS in Boiler Remote Monitoring System

    OpenAIRE

    Hongchao Wang; Yifeng Wu

    2012-01-01

    Application of GPRS and GIS in boiler remote monitoring system was designed in this paper by combining the advantage of GPRS and GIS in remote data transmission with configuration monitoring technology. The detail information of the operating conditions of the industrial boiler can be viewed by marking the location of boiler on the electronic map dynamically which can realize the unified management for industrial boiler of a region or city conveniently. Experimental application show that the ...

  18. Modelling and predictive control of a drum-type boiler

    OpenAIRE

    Molloy, Barbara

    1997-01-01

    Boilers generate steam continuously and on a large scale. Controlling the boiler process is extremely difficult - it is a highly nonlinear process, its dynamics vary with load and it is strongly multivariable. It is also inherently unstable due to the integrator effect of the drum. In addition, boilers are commonly used in situations where the load can change suddenly and without prior warning. Traditionally, boilers have been controlled by Single-Input, Single-Output (SISO) Proportional ...

  19. Computer simulation of the fire-tube boiler hydrodynamics

    OpenAIRE

    Khaustov Sergei A.; Zavorin Alexander S.; Buvakov Konstantin V.; Sheikin Vyacheslav A.

    2015-01-01

    Finite element method was used for simulating the hydrodynamics of fire-tube boiler with the ANSYS Fluent 12.1.4 engineering simulation software. Hydrodynamic structure and volumetric temperature distribution were calculated. The results are presented in graphical form. Complete geometric model of the fire-tube boiler based on boiler drawings was considered. Obtained results are suitable for qualitative analysis of hydrodynamics and singularities identification in fire-tube boiler water shell.

  20. Experimental installation with pressurized fluidized bed boiler

    Energy Technology Data Exchange (ETDEWEB)

    Dobrzanski, W.; Szwarc, W.; Jurek, K.; Prokop, A. (Politechnika Warszawska (Poland). Instytut Techniki Cieplnej)

    1990-01-01

    Describes a test installation with a 3 MW pressurized fluidized bed boiler. The installation was commissioned at the Institute of Heat Engineering at the Technical University in Warsaw. Predesign assumptions and the lay-out of the installation are given. A schematic diagram of the pressurized (0.6 MPa) fluidized bed boiler with an inner diameter of 1.4 m and a total height of 5.45 m is shown. The fuel feeding system consists of a coal and adsorbent container, two feeders and an air jet pump for pneumatic transport. A water type boiler is integrated into the pressure vessel. Flue gas cyclones are also integrated into a separate pressure vessel. The computerized control system and instrumentation are described. Temperatures, pressures, pressure differences, rotational speeds and the chemical composition of gases are monitored.

  1. Evaluation of thermal overload in boiler operators.

    Science.gov (United States)

    Braga, Camila Soares; Rodrigues, Valéria Antônia Justino; Campos, Julio César Costa; de Souza, Amaury Paulo; Minette, Luciano José; de Moraes, Angêlo Casali; Sensato, Guilherme Luciano

    2012-01-01

    The Brazilians educational institutions need a large energy demand for the operation of laundries, restaurants and accommodation of students. Much of that energy comes from steam generated in boilers with wood fuel. The laboral activity in boiler may present problems for the operator's health due to exposure to excessive heat, and its operation has a high degree of risk. This paper describes an analysis made the conditions of thermal environment in the operation of a B category boiler, located at a Higher Education Institution, located in the Zona da Mata Mineira The equipments used to collect data were Meter WBGT of the Heat Index; Meter of Wet Bulb Index and Globe Thermometer (WBGT); Politeste Instruments, an anemometer and an Infrared Thermometer. By the application of questionnaires, the second phase consisted of collecting data on environmental factors (temperature natural environment, globe temperature, relative humidity and air velocity). The study concluded that during the period evaluated, the activity had thermal overload. PMID:22316768

  2. Design, construction and operating experience of boilers at Wylfa power station

    International Nuclear Information System (INIS)

    The report will describe the boilers, but will emphasise the problems encountered and the solutions. The boilers are 'once through' with start up drums. Some redundancy was provided but this advantage was lost due to downrating of gas temperature. The boilers are carbon steel suspended plattens (992 per reactor) tightly packed in the annular space between the core shielding and the spherical wall of the pressure vessel. This construction denies access to repair tube leaks. when a leak occurs the faulty platten has to be plugged off. This is done with the reactor at 60% power. The process will be described. Reactor 1 commenced operation in 1971, Reactor 2 in June 1971. Between 1972 and May 1984 21 leaks occurred which resulted in a major shutdown for investigation. This revealed the leaks were caused by gas flow induced vibration resulting in fretting of tubes in clips. Restraints and additional clamps were fitted. This has been successful but the modifications were extensive and in very difficult working conditions, the Reactor being shut down until May 1976. A family of leaks adjacent to personnel access ways commenced in Reactor 1 in 1975 which was later identified as erosion/corrosion on the water/steam side caused by the feed flow instability. This problem is common to both Reactors. Various modifications have been applied. Redistribution of feed flow using orifice plates and ferrules was only temporarily successful. Following extensive rig testing the feed water has been dosed with amino methyl proponal (AMP) since September 1983 with an immediate and sustained reduction in the leak rate. The amine provides protection through the steam/water phase. Rig testing continues to attain a better understanding of the erosion/corrosion. (author)

  3. Boiler referruling on the Hartlepool and Heysham 1 advanced gas-cooled reactors

    International Nuclear Information System (INIS)

    The Hartlepool and Heysham I reactors each use eight cylindrical boilers having nineteen rows of helical tubes. The advantages of this design are partially offset by the relatively poor radial gas mixing. Some rows of tubing may have an imbalance between heat input from the gas and the flow of feedwater. causing a temperature profile at the upper transition joints. The thermal/hydraulic behaviour meant that the metallurgical constraints limited output. Analysis of the behaviour of these boilers required a new two-dimensional mathematical model, known as PODMIX. This describes the thermal hydraulics in each of the rows of tubing and also in the gas between the rows. Not all of the parameters for the model can be determined from first principles. However, two out of the thirty two pods have thermocouples at some of the upper transition joints and these made back calculation possible. In order to translate this model to other boiler pods, a novel thermocouple rake system was designed for sampling superheated steam temperatures in selected tubes. A result of this analysis was to show that different, individual ferrule patterns were needed for each pod. The characteristics could, in general, best be met using twin orifice ferrules. Unfortunately, the installed system did not permit the replacement of orifices, so that a completely new system had to be developed. In the course of designing this, the opportunity was taken to over come susceptibilities to erosion/corrosion and crevice corrosion. Removal of the old ferrules and replacement with the new ones necessitated the development of high precision, programmable machines to operate under difficult site conditions. These carried out drilling, boring, grinding and polishing operations as well as making face welds and tube bore welds. Modifications have already achieved substantial improvements in performance and output, but an extended, iterative programme still lies ahead. (author)

  4. Impact of coal fly ash addition on ash transformation and deposition in a full-scale wood suspension-firing boiler

    DEFF Research Database (Denmark)

    Wu, Hao; Bashir, Muhammad Shafique; Jensen, Peter Arendt;

    2013-01-01

    Ash transformation and deposition during pulverized wood combustion in a full-scale power plant boiler of 800 MWth were studied with and without the addition of coal fly ash. The transient ash deposition behavior was characterized by using an advanced deposit probe system at two boiler locations...... of the deposits. Overall, the results from this work suggest that coal fly ash can be an effective additive to minimize the possible ash deposition and corrosion problems during suspension-firing of wood. © 2013 Elsevier Ltd. All rights reserved....... constant after a few hours. The formed deposits, especially those at the location with low flue gas temperatures, contained a considerable amount of K2SO4, KCl, and KOH/K2CO3. With the addition of a large amount (about 4 times of the mass flow of wood ash) of coal fly ash to the boiler, these alkali...

  5. Optimization of Boiler Heat Load in Water-Heating Boiler-House

    OpenAIRE

    B. A. Bayrashevsky; N. P. Borushko

    2014-01-01

    An analytical method for optimization of water-heating boiler loads has been developed on the basis of approximated semi-empirical dependences pertaining to changes of boiler gross efficiency due to its load. A complex (∂tух/∂ξ)Δξ is determined on the basis of a systematic analysis (monitoring) of experimental data and the Y. P. Pecker’s formula for calculation of balance losses q2. This complex makes it possible to set a corresponding correction to a standard value of the boiler gross effici...

  6. 46 CFR 109.205 - Inspection of boilers and machinery.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 4 2010-10-01 2010-10-01 false Inspection of boilers and machinery. 109.205 Section 109... OPERATIONS Tests, Drills, and Inspections § 109.205 Inspection of boilers and machinery. The chief engineer or engineer in charge, before he assumes charge of the boilers and machinery of a unit shall...

  7. 46 CFR 56.50-30 - Boiler feed piping.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 2 2010-10-01 2010-10-01 false Boiler feed piping. 56.50-30 Section 56.50-30 Shipping... APPURTENANCES Design Requirements Pertaining to Specific Systems § 56.50-30 Boiler feed piping. (a) General... least two separate means of supplying feed water for the boilers. All feed pumps shall be fitted...

  8. 49 CFR 230.36 - Hydrostatic testing of boilers.

    Science.gov (United States)

    2010-10-01

    ... Appurtenances Pressure Testing of Boilers § 230.36 Hydrostatic testing of boilers. (a) Time of test. The... following any hydrostatic test where the pressure exceeds MAWP. ... 49 Transportation 4 2010-10-01 2010-10-01 false Hydrostatic testing of boilers. 230.36 Section...

  9. Lower price for solar boilers must improve market penetration

    International Nuclear Information System (INIS)

    The Dutch government aims at 1.7 PJ thermal energy for the year 2007 to be supplied by solar water heaters. For that target the number of installed solar boilers must increase seven times the number of installed solar boilers in 1998. This can be stimulated by a considerable reduction of the market price for such boilers

  10. Aspects of new material application for boilers construction

    International Nuclear Information System (INIS)

    Review of steel types commonly used for energetic boilers construction has been done. The worldwide trends in new materials application for improvement of boilers quality have been discussed. The mechanical properties of boiler construction steels have been shown and compared. 3 refs, 5 figs, 1 tab

  11. Central heating: fossil-fired boilers

    Energy Technology Data Exchange (ETDEWEB)

    Blazek, C.F.; Baker, N.R.; Tison, R.R.

    1979-05-01

    This evaluation provides performance and cost data for fossil-fuel-fired steam boilers, hot-water generators, and thermal fluid generators currently available from manufacturers. Advanced-technology fluidized-bed boilers also are covered. Performance characteristics investigated include unit efficiencies, turndown capacity, and pollution requirements. Costs are tabulated for equipment and installation of both field-erected and packaged units. The information compiled in this evaluation will assist in the process of selecting energy-conversion units required for industrial, commercial, and residential applications.

  12. Planning Annual Shutdown Inspection for BFB Boiler

    OpenAIRE

    Sorsa, Tatu

    2014-01-01

    The goal of this thesis was to create an illustrative guidebook of annual inspection planning for BFB boiler to help power plant operator when planning of annual inspection is topical. This thesis was made for Andritz Oy and it is based on inspection reports and experiences of BFB boiler’s maintenance and inspection staff. In this thesis it is shown how to plan an annual inspection for BFB boiler and thesis gives good tools and hints for operator to manage inspection from the beginning ...

  13. The level control of the boiler drum

    OpenAIRE

    He, Chenhui

    2014-01-01

    Level control uses the boiler drum as a controlled object, and uses the level as a controller value. By making sure the level control is attached accurately we get better dynamic performance. I use the cascade control to make the difference to the traditional control. In this thesis, I summarize many problems with the level control in the steam boiler field as the false level phenomenon. I design three methods for the level control process system with different ways. I make the final choi...

  14. Transients in a circulating fluidized bed boiler

    Science.gov (United States)

    Baskakov, A. P.; Munts, V. A.; Pavlyuk, E. Yu.

    2013-11-01

    Transients in a circulating fluidized bed boiler firing biomass are considered. An attempt is made to describe transients with the use of concepts applied in the automatic control theory. The parameters calculated from an analysis of unsteady heat balance equations are compared with the experimental data obtained in the 12-MW boiler of the Chalmers University of Technology. It is demonstrated that these equations describe the transient modes of operation with good accuracy. Dependences for calculating the time constants of unsteady processes are obtained.

  15. NOx EMISSIONS PRODUCED WITH COMBUSTION OF POWDER RIVER BASIN COAL IN A UTILITY BOILER

    Energy Technology Data Exchange (ETDEWEB)

    John S. Nordin; Norman W. Merriam

    1997-04-01

    The objective of this report is to estimate the NOx emissions produced when Powder River Basin (PRB) coal is combusted in a utility boiler. The Clean Air Act regulations specify NOx limits of 0.45 lb/mm Btu (Phase I) and 0.40 lb/mm Btu (Phase II) for tangentially fired boilers, and 0.50 lb/mm 13tu (Phase II) and 0.46 lb/mm Btu (Phase II) for dry-bottom wall-fired boilers. The Clean Air Act regulations also specify other limits for other boiler types. Compliance for Phase I has been in effect since January 1, 1996. Compliance for Phase II goes into effect on January 1, 2000. Emission limits are expressed as equivalent NO{sub 2} even though NO (and sometimes N{sub 2}O) is the NOx species emitted during combustion. Regulatory agencies usually set even lower NOx emission limits in ozone nonattainment areas. In preparing this report, Western Research Institute (WRI) used published test results from utilities burning various coals, including PRB coal, using state-of-the art control technology for minimizing NOx emissions. Many utilities can meet Clean Air Act NOx emission limits using a combination of tight combustion control and low-NOx burners and by keeping furnaces clean (i.e., no slag buildup). In meeting these limits, some utilities also report problems such as increased carbon in their fly ash and excessive furnace tube corrosion. This report discusses utility experience. The theory of NOx emission formation during coal combustion as related to coal structure and how the coal is combusted is also discussed. From this understanding, projections are made for NOx emissions when processed PRB coal is combusted in a test similar to that done with other coals. As will be shown, there are a lot of conditions for achieving low NOx emissions, such as tight combustion control and frequent waterlancing of the furnace to avoid buildup of deposits.

  16. Improved Materials for Use as Components in Kraft Black Liquor Recovery Boilers; TOPICAL

    International Nuclear Information System (INIS)

    This Cooperative Research and Development Agreement (CRADA) was undertaken to evaluate current and improved materials and materials processing conditions for use as components in kraft black liquor recovery boilers and other unit processes. The main areas addressed were: (1) Improved Black Liquor Nozzles, (2) Weld Overlay of Composite Floor Tubes, and (3) Materials for Lime Kilns. Iron aluminide was evaluated as an alternate material for the nozzles used to inject an aqueous solution known as black liquor into recovery boilers as well for the uncooled lining in the ports used for the nozzles. Although iron aluminide is known to have much better sulfidation resistance in gases than low alloy and stainless steels, it did not perform adequately in the environment where it came into contact with molten carbonate, sulfide and sulfate salts. Weld overlaying carbon steel tubes with a layer of stainless weld metal was a proposed method of extending the life of recovery boiler floor tubes that have experienced considerable fireside corrosion. After exposure under service conditions, sections of weld overlaid floor tubes were removed from a boiler floor and examined metallographically. Examination results indicated satisfactory performance of the tubes. Refractory-lined lime kilns are a critical component of the recovery process in kraft pulp mills, and the integrity of the lining is essential to the successful operation of the kiln. A modeling study was performed to determine the cause of, and possible solutions for, the repeated loss of the refractory lining from the cooled end of a particular kiln. The evaluation showed that the temperature, the brick shape and the coefficient of friction between the bricks were the most important parameters influencing the behavior of the refractory lining

  17. NaK pool-boiler solar receiver durability bench test. Volume 2: Metallurgical analysis

    Science.gov (United States)

    Goods, S. H.; Bradshaw, R. W.

    1995-01-01

    The principal materials used in the construction of a NaK based pool-boiler were analyzed. The device, operated for 7500 hours, accumulated 1000 thermal cycles to a peak temperature of 750 C. Haynes 230, used to fabricate the pool-boiler vessel, was found to perform satisfactorily. Air-side corrosion of the pool-boiler vessel was insignificant. Internal surface of the alloy exhibited some NaK-induced elemental dissolution; this dissolution was somewhat more extensive where the alloy was exposed to the liquid metal compared to regions exposed only to NaK vapor; however, the corresponding metal loss in all regions was inconsequential, never exceeding more than a few microns. Autogenous seam welds of the alloy responded in a similar fashion, exhibiting only minimal metal loss over the course of the experiment. While there was 50% loss in ductility of the alloy there remained adequate ductility for the anticipated operating environment. An enhanced boiling nucleation surface comprised of stainless steel powder brazed to the vessel ID showed no change in its structure. It remained intact, showing no cracking after repeated thermal cycling. Other materials used in the experiment showed more extensive degradation after exposure to the NaK. IN 600, used to fabricate thermowells, exhibited extensive surface and intergranular dissolution. Grain boundary dissolution was sufficiently severe in one of the thermowells to cause an air leak, resulting in experiment termination. BNi-3, a brazing alloy used to join the pool-boiler vessel, endcaps and thermowells, showed some dissolution where it was exposed to the NaK as well as thermal aging effects. However, all brazes remained structurally sound. A nickel metal ribbon showed catastrophic dissolution, resulting in the formation of deep (greater than 30 (mu)m) pits and cavities. A zirconium metal foil used to getter oxygen from the NaK became extremely brittle.

  18. A novel capacitance sensor for fireside corrosion measurement.

    Science.gov (United States)

    Ban, Heng; Li, Zuoping

    2009-11-01

    Fireside corrosion in coal-fired power plants is a leading mechanism for boiler tube failures. Online monitoring of fireside corrosion can provide timely data to plant operators for mitigation implementation. This paper presents a novel sensor concept for measuring metal loss based on electrical capacitance. Laboratory-scale experiments demonstrated the feasibility of design, fabrication, and operation of the sensor. The fabrication of the prototype sensor involved sputtering deposition of a thin metal coating with varying thickness on a ceramic substrate. Corrosion metal loss resulted in a proportional decrease in electrical capacitance of the sensor. Laboratory experiments using a muffle furnace with an oxidation environment demonstrated that low carbon steel coatings on ceramic substrate survived cyclic temperatures over 500 degrees C. Measured corrosion rates of sputtered coating in air had an Arrhenius exponential dependence on temperature, with metal thickness loss ranging from 2.0 nm/h at 200 degrees C to 2.0 microm/h at 400 degrees C. Uncertainty analysis indicated that the overall measurement uncertainty was within 4%. The experimental system showed high signal-to-noise ratio, and the sensor could measure submicrometer metal thickness changes. The laboratory experiments demonstrated that the sensor concept and measurement system are capable of short term, online monitoring of metal loss, indicating the potential for the sensor to be used for fireside corrosion monitoring and other metal loss measurement. PMID:19947757

  19. The analysis of furnace wall deposits in a low-NO{sub x} waste wood-fired bubbling fluidised bed boiler

    Energy Technology Data Exchange (ETDEWEB)

    Alipour, Yousef [KTH Royal Institute of Technology, Stockholm (Sweden). Div. of Surface and Corrosion Science; Viklund, Peter [Swerea - KIMAB, Kista (Sweden); Henderson, Pamela [Vattenfall Research and Development, Stockholm (Sweden)

    2012-07-01

    Increasing use is being made of biomass as fuel for electricity production as the price of natural wood continues to rise. Therefore, more use is being made of waste wood (recycled wood). However, waste wood contains more chlorine, zinc and lead, which are believed to increase corrosion rates. Corrosion problems have occurred on the furnace walls of a fluidised bed boiler firing 100 % waste wood under low-NO{sub x} conditions. The deposits have been collected and analysed in order to understand the impact of the fuel. (orig.)

  20. Coal liquefaction. Quarterly report, January--March 1977

    Energy Technology Data Exchange (ETDEWEB)

    None

    1977-12-01

    Current ERDA work in coal liquefaction is aimed at improved process configurations for both catalytic and non-catalytic processes to provide more attractive processing economics and lower capital investment. Coal liquefaction can now be achieved under more moderate processing conditions and more rapidly than was the case in the 1930's. The advantage of coal liquefaction is that the entire range of liquid products, including heavy boiler fuel, distillate fuel oil, gasoline, jet fuel, and diesel oil, can be produced from coal by varying the type of process and operating conditions used in the process. Furthermore, coal-derived liquid fuels also have the potential for use as chemical feedstocks. To determine the most efficient means of utilizing coal resources, ERDA is sponsoring the development of several conversion processes that are currently in the pilot plant stage. Nineteen projects under development are described and progress for each in the quarter is detailed briefly. (LTN)

  1. Coal liquefaction. Quarterly report, July--September 1977

    Energy Technology Data Exchange (ETDEWEB)

    None

    1978-02-01

    ERDA's program for the conversion of coal to liquid fuels is aimed at improved process configurations for both catalytic and noncatalytic processes to provide more attractive processing economics and lower capital investment. The advantage of coal liquefaction is that the entire range of liquid products, including heavy boiler fuel, distillate fuel oil, gasoline, jet fuel, and diesel oil, can be produced from coal by varying the type of process and operating conditions used in the process. Furthermore, coal-derived liquids also have the potential for use as chemical feedstocks. To provide efficient and practical means of utilizing coal resources, ERDA is sponsoring the development of several conversion processes that are currently in the pilot plant stage. Responsibility for the design, construction, and operation of these facilities is given and progress in the quarter is summarized. Several supporting or complementary projects are described similarly. (LTN)

  2. Quarterly overviews of thermal solar energy systems 1993

    International Nuclear Information System (INIS)

    The title overviews were compiled to support the market introduction campaign for solar water heaters in the Netherlands. Use has been made of the data-banks of the Dutch subsidy administrator 'Senter'. 88% of the 1,883 systems, that were installed in 1993, are solar water heaters. Considering the solar collector surface the largest contribution is from the use of mainly uncovered collectors in swimming pools: 51% (37% for the collector surface of solar water heaters). Energy utilities are involved in the installation of 70% of the solar heating systems (even 77% for the solar water heaters). Next to the quarterly overviews, the subsidy data for the period 1988 up to and including 1993 are analyzed. 70% of the installed systems has been purchased and 30% was rented. At the end of 1993 preparations were made to install more than 3,000 solar boilers in 1994 and 1995. 3 figs., 21 tabs

  3. Statement of incidents at nuclear installations fourth quarter 1985

    International Nuclear Information System (INIS)

    The three incidents which are reported for the fourth quarter of 1985 occurred at Transfynydd and Hinkley Point-B reactors (operated by CEGB) and there is a follow-up report on an earlier incident at Hunterston A reactor (operated by the South of Scotland Electricity Board). The Transfynydd incident concerned a fire in conventional plant and although the reactor was shut down as a precaution, the damage was limited to conventional plant and there was no radiation hazard. The two incidents at Hinkley Point-B concerned a boiler tube leak which allowed high pressure steam into the coolant gas circuit and a leakage of reactor coolant gas which caused the site emergency arrangements to be invoked but which caused no contamination outside the reactor building. The Hunterston-A report concerns the replacement of an active effluent discharge pipeline which had been found to have a leak. (UK)

  4. The microbial corrosion; La corrosion microbienne

    Energy Technology Data Exchange (ETDEWEB)

    Beech, I.B. [University of Portsmouth, School of Pharmacy - Biomedical Science, Chemistry-Physics and Radiography, Portsmouth (United Kingdom)

    1999-02-01

    Underestimated for a long time, corrosion due to microorganisms induces degradation, sometimes fulminant, of a lot of metallic structures in the world. Searchers are using plentiful analytical tools to understand this phenomenon. (O.M.)

  5. Super Boiler: Packed Media/Transport Membrane Boiler Development and Demonstration

    Energy Technology Data Exchange (ETDEWEB)

    Liss, William E; Cygan, David F

    2013-04-17

    Gas Technology Institute (GTI) and Cleaver-Brooks developed a new gas-fired steam generation system the Super Boiler for increased energy efficiency, reduced equipment size, and reduced emissions. The system consists of a firetube boiler with a unique staged furnace design, a two-stage burner system with engineered internal recirculation and inter-stage cooling integral to the boiler, unique convective pass design with extended internal surfaces for enhanced heat transfer, and a novel integrated heat recovery system to extract maximum energy from the flue gas. With these combined innovations, the Super Boiler technical goals were set at 94% HHV fuel efficiency, operation on natural gas with <5 ppmv NOx (referenced to 3%O2), and 50% smaller than conventional boilers of similar steam output. To demonstrate these technical goals, the project culminated in the industrial demonstration of this new high-efficiency technology on a 300 HP boiler at Clement Pappas, a juice bottler located in Ontario, California. The Super Boiler combustion system is based on two stage combustion which combines air staging, internal flue gas recirculation, inter-stage cooling, and unique fuel-air mixing technology to achieve low emissions rather than external flue gas recirculation which is most commonly used today. The two-stage combustion provides lower emissions because of the integrated design of the boiler and combustion system which permit precise control of peak flame temperatures in both primary and secondary stages of combustion. To reduce equipment size, the Super Boiler's dual furnace design increases radiant heat transfer to the furnace walls, allowing shorter overall furnace length, and also employs convective tubes with extended surfaces that increase heat transfer by up to 18-fold compared to conventional bare tubes. In this way, a two-pass boiler can achieve the same efficiency as a traditional three or four-pass firetube boiler design. The Super Boiler is consequently

  6. Optimization of Boiler Heat Load in Water-Heating Boiler-House

    Directory of Open Access Journals (Sweden)

    B. A. Bayrashevsky

    2014-06-01

    Full Text Available An analytical method for optimization of water-heating boiler loads has been developed on the basis of approximated semi-empirical dependences pertaining to changes of boiler gross efficiency due to its load. A complex (∂tух/∂ξΔξ is determined on the basis of a systematic analysis (monitoring of experimental data and the Y. P. Pecker’s formula for calculation of balance losses q2. This complex makes it possible to set a corresponding correction to a standard value of the boiler gross efficiency due to contamination of heating surfaces.Software means for optimization of water-heating boilers has been developed and it is recommended to be applied under operational conditions.

  7. Optimization of Bed Material Consumption in a CFBC Boiler

    Directory of Open Access Journals (Sweden)

    Ashish M. Pullekunnel

    2015-01-01

    Full Text Available The proposed Case-Study is to identify the scope of energy conservation and cost saving through optimization of bed material in a CFBC Boiler during plant start up. The study was undertaken at Abhijeet MADC Nagpur Energy Pvt. Ltd (AMNEPL, a 4X61.5 MW power plant at MIHAN, Khairy Khurd, Hingna, Nagpur. The scope of the study covers the savings achieved during light up of 4X250 TPH boiler and the effect of the application of the proposed method on the energy conservation possibilities and efficiency of boiler operation. The proposed method is an alternative to the conventional boiler light up of a CFBC boiler

  8. Dynamic Boiler Performance:Modelling, simulating and optimizing boilers for dynamic operation

    OpenAIRE

    Sørensen, Kim

    2004-01-01

    Traditionally, boilers have been designed mainly focussing on the static operation of the plant. The dynamic capability has been given lower priority and the analysis has typically been limited to assuring that the plant was not over-stressed due to large temperature gradients.New possibilities for buying and selling energy has increased the focus on the dynamic operation capability, efciency, emissions etc. For optimizing the design of boilers for dynamic operation a quantication of the dyna...

  9. Development of 18Cr-9Ni-W-Nb-V-N Austenitic Stainless Steel Tube for Thermal Power Boilers

    Science.gov (United States)

    Ishitsuka, Tetsuo; Mimura, Hiroyuki

    An 18Cr-9Ni-W-Nb-V-N austenitic stainless steel tube for thermal power boilers has been newly developed. The high temperature mechanical properties and corrosion resistance of the steel were investigated. The creep rupture strength of the developed steel is about 1.5 times as high as that of SUS347HTB, and is almost the same as that of Ka-SUS310J2TB at 650°C. This excellent creep strength of the steel is mainly due to solid solution strengthening by tungsten and nitrogen, and precipitation strengthening by nitrides of niobium and vanadium. The carbon content of the steel is reduced to 0.03% to improve intergranular corrosion resistance. The steam oxidation resistance and the high temperature corrosion resistance of the tube are almost the same as those of SUS347HTB. Weldability of the developed steel is superior to that of SUS304HTB and SUS310TB. Thus the developed steel is suitable for use as a material for superheater and reheater tubes of thermal power boilers.

  10. Thermal Analysis of Superheater Platen Tubesin Boilers

    Directory of Open Access Journals (Sweden)

    Shahram Falahatkar

    2014-01-01

    Full Text Available Superheaters are among the most important components of boilers and have major importance due to this operation in high temperatures and pressures. Turbines are sensitive to the fluctuation of superheaterstemperature;therefore even the slightest fluctuation in the outlet vapor temperature from the superheaters does damage the turbine axis and fins. Examining the potential damages of combustion in the boilers and components such as the superheaters can have a vital contribution to the progression of the productivity of boiler, turbine and the power plant altogether it solutions are to be fund to improve such systems. In this study, the focus is on the nearest tube set of superheaters to the combustion chamber.These types of tubes are exposed to a wide range ofcombustion flames such that the most heat transfer to them is radiation type.Here, the 320 MW boiler of Isfahan power plant (Iran, the combustion chamber, 16 burners and the platensuperheater tubes were remodeled by CFD technique. The fluid motion, the heat transfer and combustion processes are analyzed. The two-equation turbulence model of k-εis adopted to measure the eddy viscosity. The eddy dissipation model is used to calculate the combustion as well as the P-1 radiation model to quantify the radiation. The overheated zones of superheater tubes and the combustion chamber are identified in order toimprove this problem by applying the radiation thermal shields and knees with porous crust which are introduced as the new techniques.

  11. Environmental control during steam boiler washing

    Energy Technology Data Exchange (ETDEWEB)

    Guimaraes, Marcio A.B.; Abreu Pereira, Vera L. de [Companhia Petroquimica do Nordeste (COPENE), Camacari, BA (Brazil). Div. de Engenharia Ambiental; Ringler, Ulrich E.S. [PROMON Engenharia Ltda., Salvador, BA (Brazil)

    1993-12-31

    The washing and chemical cleaning of boilers, activities of a high polluting potential, are responsible for the generation of wastewater of high contents of heavy metals, suspended solids and chemical oxygen demand (COD). This paper describes the actions carried out by COPENE - Petroquimica do Nordeste S/A - in order to reduce this problem. (author). 10 refs., 3 figs., 2 tabs.

  12. REBURN TECHNOLOGY FOR BOILER NOX CONTROL

    Science.gov (United States)

    The paper reports the progress principally of design-relate phases of a demonstration of reburning on a large cyclone-fired boiler, for which coal is the primary fuel and natural gas, the reburn fuel. Reburn system design criteria are presented, as well as the methodology and res...

  13. The investigation of the locomotive boiler material

    International Nuclear Information System (INIS)

    In the paper, the history of narrow-gauge railway system is described. The other information about the steam locomotive construction, as well as the technical regulations of its construction and exploitation are also done. The results of the studies of the locomotive boiler material are presented. (authors)

  14. New thinking for the boiler room.

    Science.gov (United States)

    Rose, Wayne

    2008-09-01

    Wayne Rose, marketing manager at integrated plant room manufacturer Armstrong Integrated Systems, explains how increasing use of off-site manufacture, the latest 3D modelling technology, and advances in control technology, are revolutionising boiler room design and construction. PMID:18822819

  15. Monitoring Microbially Influenced Corrosion

    DEFF Research Database (Denmark)

    Hilbert, Lisbeth Rischel

    Abstract Microbially influenced corrosion (MIC) of carbon steel may occur in media with microbiological activity of especially sulphate-reducing bacteria (SRB). The applicability and reliability of a number of corrosion monitoring techniques for monitoring MIC has been evaluated in experiments...... diffusional effects and unreliable corrosion rates, when biofilm and ferrous sulphide corrosion products cover the steel surface. Corrosion rates can be overestimated by a factor of 10 to 100 by electrochemical techniques. Weight loss coupons and ER are recommended as necessary basic monitoring techniques....... EIS might be used for detection of MIC as the appearance of very large capacitances can be attributed to the combined ferrous sulphide and biofilm formation. Capacitance correlates directly with sulphide concentration in sterile sulphide media. Keywords: Corrosion monitoring, carbon steel, MIC, SRB...

  16. Needs-driven soot blowing in waste boilers; Behovsstyrd sotblaasning i avfallspannor

    Energy Technology Data Exchange (ETDEWEB)

    Niklasson, Fredrik; Davidsson, Kent

    2009-09-15

    The increased use of alternative and waste fuels has resulted in an increased number of plants having trouble with fouling and corrosion on boiler banks and superheater tubes. Frequent sootblowing will keep the surfaces relatively clean, but on the other hand, it may erode the tube material. An intelligent sootblowing system will initiate sootblowings on individual tube banks only when needed for that specific tube bank. Such a system depends on the detection of the degree of fouling of specific tube banks. In this project, the conditions for an intelligent sootblowing system at the waste fired boilers in Boraas are investigated from measured flows, temperatures and pressure drop. New thermocouples at the water tubes between the banks of the economiser have been installed and connected to the control and monitoring system of the boiler. From measured temperatures and flows, heat transfer coefficients are calculated and used to detect the fouling on the heat exchangers. A pressure transducer has been altered to measure the pressure over the boiler bank. At the superheaters, the measurements show a significant improvement of the heat transfer coefficients immediately following sootblowing. Thereafter, the heat transfer coefficients decline more slowly, almost linearly. The measurements indicate that the fouling rate is almost same for the two superheaters and do not motivate individual sootblowing sequences of the two superheaters. The pressure drop over the boiler bank was found too insensitive a measure to be used as an indicator for an intelligent sootblowing system, at least in this specific boiler. In the economiser, the decline of calculated heat transfer coefficients showed a relative rate of fouling on individual tube banks. The results show that the fouling rate is significantly higher in the top tube banks, which comes first in the direction of the flue gas, compared to downstream banks. Experiments by sootblowing the top tube bank more frequently than the

  17. Infrared imaging of fossil fuel power plant boiler interiors

    Science.gov (United States)

    Howard, James W.; Cranton, Brian W.; Armstrong, Karen L.; Hammaker, Robert G.

    1997-08-01

    Fossil fuel power plant boilers operate continuously for months at a time, typically shutting down only for routine maintenance or to address serious equipment failures. These shutdowns are very costly, and diagnostic tools and techniques which could be used to minimize shutdown duration and frequency are highly desirable. Due to the extremely hostile environment in these boilers, few tools exist to inspect and monitor operating boiler interiors. This paper presents the design of a passively cooled, infrared borescope used to inspect the interior of operating boilers. The borescope operates at 3.9 micrometer, where flame is partially transparent. The primary obstacles overcome in the instrument design were the harsh industrial environment surrounding the boilers and the high temperatures encountered inside the boilers. A portable yet durable lens system and enclosure was developed to work with a scanning radiometer to address these two problems by both shielding the radiometer from the environment and by extending the optical train into a snout designed to be inserted into access ports on the sides of the boiler. In this manner, interior images of the boiler can be made while keeping the radiometer safely outside the boiler. The lens views a 40 degree field of view through any 2.5' or larger opening in a foot thick boiler wall. Three of these borescopes have been built, and high resolution images of boiler interiors have been obtained.

  18. Utilisation of forest chips, produced with different harvesting chains, in fluidised bed boilers of large power plants; Erilaisten korjuuketjujen tuottaman metsaehakkeen kaeyttoe suurten voimaloiden leijukerroskattiloissa - PUUT08

    Energy Technology Data Exchange (ETDEWEB)

    Orjala, M.; Ingalsuo, R. [VTT Energy, Jyvaeskylae (Finland)

    2001-07-01

    When combusting wood fuels the chemical composition of woof fuels can cause fouling and high-temperature corrosion of the heat transfer and superheater surfaces of the boiler. Problems are caused especially by forest chips, which include high quantities of needles and thin branches. Even though low alkali metal and chlorine contents are typical for wood fuels, the problem is that they are easily vaporised during combustion. Depending on the combustion conditions, the alkali metals can be oxidised to alkali metal oxides or they can form sulphates or chlorides. When combustion pure wood the sulphur content in combustion process is low and alkali metal compounds form chlorides easily, which can be condensed on the heat transfer surfaces of the boiler and form a significant high-temperature corrosion risk. If the sulphur content of the combustion process is increased e.g. by additional utilisation of peat, the chemistry of alkali metals is directed to formation of alkali metal sulphates instead of chlorides, and the chlorine liberated in the furnace forms gaseous hydrogen chloride (HCI). Hydrogen chloride, formed in combustion of wood fuels, is transferred in low concentrations in flue gases out of the boiler so it does not cause significant chlorine corrosion or emission risk. (orig.)

  19. Characterization of deposits and their influence on corrosion in waste incineration plants in Denmark

    DEFF Research Database (Denmark)

    Montgomery, Melanie; Larsen, OH

    2001-01-01

    A program has been initiated in Denmark to investigate the aggressive environment in various waste incineration plants. The results described are the preliminary results from one waste incineration plant. Deposits and corrosion products have been removed from various locations in the boiler. These...... have been analyzed with respect to morphology and composition using electron microscopy techniques. This results in a map indicating the conditions that exist throughout the plant. This can be compared with a map of flue gas and steam temperatures through the plant and with the amount of corrosion that...

  20. Corrosion control. 2. ed.

    International Nuclear Information System (INIS)

    The purpose of this text is to train engineers and technologists not just to understand corrosion but to control it. Materials selection, coatings, chemical inhibitors, cathodic and anodic protection, and equipment design are covered in separate chapters. High-temperature oxidation is discussed in the final two chapters ne on oxidation theory and one on controlling oxidation by alloying and with coatings. This book treats corrosion and high-temperature oxidation separately. Corrosion is divided into three groups: (1) chemical dissolution including uniform attack, (2) electrochemical corrosion from either metallurgical or environmental cells, and (3) stress-assisted corrosion. Corrosion is logically grouped according to mechanisms rather than arbitrarily separated into different types of corrosion as if they were unrelated. For those university students and industry personnel who approach corrosion theory very hesitantly, this text will present the electrochemical reactions responsible for corrosion summed up in only five simple half-cell reactions. When these are combined on a polarization diagram, which is also explained in detail, the electrochemical processes become obvious. For those who want a text stripped bare of electrochemical theory, several noted sections can be omitted without loss of continuity. However, the author has presented the material in such a manner that these sections are not beyond the abilities of any high school graduate who is interested in technology

  1. Computational thermal-hydraulic modeling of a steam generator and a boiler simulator autoclave

    International Nuclear Information System (INIS)

    Corrosion of heat transfer tubing in nuclear steam generators has been a persistent problem in the power generation industry, assuming many different forms over the years depending on chemistry and operating conditions. Whatever the corrosion mechanism, a funding understanding of the process is essential to establish effective management strategies. To gain this fundamental understanding requires an integrated investigative approach that merges technology from many diverse scientific disciplines. An important aspect of an integrated approach is characterization of the corrosive environment at high temperature. This begins with a thorough understanding of local thermal-hydraulic conditions, since they affect deposit formation, chemical concentration, and ultimately corrosion. Computational Fluid Dynamics (CFD) can and should play an important role in characterizing the thermal-hydraulic environment and in predicting the consequences of that environment. The evolution of CFD technology now allows accurate calculation of steam generator thermal-hydraulic conditions and the resulting sludge deposit profiles. Similar calculations are also possible for model boilers, so that tests can be designed to be prototypic of the heat exchanger environment they are supposed to simulate. This paper illustrates the utility of CFD technology by way of examples in each of these two areas. This technology can be further extended to produce more detailed local calculations of the chemical environment in support plate crevices, beneath thick deposits on tubes, and deep in tubesheet sludge. Knowledge of this local chemical environment will provide the foundation for development of mechanistic corrosion models, which can be used to optimize inspection and cleaning schedules and focus the search for a viable fix

  2. Corrosion in the oil industry

    Energy Technology Data Exchange (ETDEWEB)

    Brondel, D. (Sedco Forex, Montrouge (France)); Edwards, R. (Schlumberger Well Services, Columbus, OH (United States)); Hayman, A. (Etudes et Productions Schlumberger, Clamart (France)); Hill, D. (Schlumberger Dowell, Tulsa, OK (United States)); Mehta, S. (Schlumberger Dowell, St. Austell (United Kingdom)); Semerad, T. (Mobil Oil Indonesia, Inc., Sumatra (Indonesia))

    1994-04-01

    Corrosion costs the oil industry billions of dollars a year, a fact that makes the role of the corrosion engineer an increasingly important one. Attention is paid to how corrosion affects every aspect of exploration and production, from offshore rigs to casing. Also the role of corrosion agents such as drilling and production fluids is reviewed. Methods of control and techniques to monitor corrosion are discussed, along with an explanation of the chemical causes of corrosion. 21 figs., 32 refs.

  3. The Necessity of Small Industrial Boiler Feed Water Deoxidization%小型工业锅炉给水除氧必要性的探讨

    Institute of Scientific and Technical Information of China (English)

    张荣华; 买买提艾力·肉孜

    2015-01-01

    In this paper, the necessity of deoxidization for small pressure hot water and steam boiler(hereinafter referred to as"small boiler”) is proposed. And points out that oxygen treatment for small boiler is one of an important way of water treatment, and also an important issue worth considering. According to the update of standard GB1576 and the requirement of economic operation of the boiler, it is necessary to add small boiler oxygen corrosion protection in water quality monitoring, and the water quality is the basic prerequisite for boiler safe and economic operation. For small boiler, especially for small hot water boiler, deoxidization measures should be taken.%本文提出小型承压热水及蒸汽锅炉(以下简称小型锅炉)给水除氧处理的必要性,并指出除氧处理对于小型锅炉同样是一项重要的水处理方式之一,也是一项值得考虑的重要问题。根据GB1576新老标准的更新与锅炉经济运行的要求,笔者认为重新把小型锅炉除氧防腐工作加入到水质监测工作中是必要的,水质的好坏是锅炉安全、经济运行的基本前提条件。所以,对于小型锅炉、尤其是对于小型热水锅炉应采取除氧措施。

  4. DEVELOPMENT OF AN ENVIRONMENTALLY BENIGN MICROBIAL INHIBITOR TO CONTROL INTERNAL PIPELINE CORROSION

    Energy Technology Data Exchange (ETDEWEB)

    Bill W. Bogan; Brigid M. Lamb; John J. Kilbane II

    2004-10-30

    The overall program objective is to develop and evaluate environmentally benign agents or products that are effective in the prevention, inhibition, and mitigation of microbially influenced corrosion (MIC) in the internal surfaces of metallic natural gas pipelines. The goal is to develop one or more environmentally benign (a.k.a. ''green'') products that can be applied to maintain the structure and dependability of the natural gas infrastructure. Previous testing indicated that the growth, and the metal corrosion caused by pure cultures of sulfate reducing bacteria were inhibited by hexane extracts of some pepper plants. This quarter tests were performed to determine if chemical compounds other than pepper extracts could inhibit the growth of corrosion-associated microbes and to determine if pepper extracts and other compounds can inhibit corrosion when mature biofilms are present. Several chemical compounds were shown to be capable of inhibiting the growth of corrosion-associated microorganisms, and all of these compounds limited the amount of corrosion caused by mature biofilms to a similar extent. It is difficult to control corrosion caused by mature biofilms, but any compound that disrupts the metabolism of any of the major microbial groups present in corrosion-associated biofilms shows promise in limiting the amount/rate of corrosion.

  5. Quality parameters for corrosion and scaling control in industrial waters

    International Nuclear Information System (INIS)

    Consumption of water by human beings is enormous as drinking water, in foods, irrigation, as coolant and numerous other applications. All the environmental pollutants, harmful constituents from the atmosphere and wastage are washed into water through rain and other uses and are transferred to water sources, making it unsafe for drinking and industrial applications. Thus knowledge of water chemistry and its quality control is very important for its safe applications. Water is very good heat transfer medium and is abundantly used in heat exchangers and boilers. During this process it transfers solids, salts, corrosion products, gases and radioactive products from one system to other. Use of impure water causes corrosion and scale formation problems and reduces the life of heat exchangers, steam generators and boilers increasing the replacement, repair, maintenance and operation costs many times and may also lead to closure of industrial plants. Before application of water for industrial purposes, materials of the plants must be identified and quality parameters like pH, conductivity, total dissolved solids, dissolved gases, different anions, cations must be established and maintained during operation. To increase the life of the plants phosphoric and all volatile treatments are done, pH is conditioned and levels of different constituents are maintained. For better performance of plants, better design, better tubes and other materials and proper water chemistry are necessary. Nuclear reactor cooling systems involve primary systems, secondary systems and their related processes e.g. radiolysis, activation processes, steam generation, corrosion processes, sources of impurities, water purification, ion exchangers, sampling and monitoring etc. To avoid corrosion and scaling problems in nuclear reactor cooling systems use of pure water according to specifications is necessary. In order to offset different radiation induced reactions chemical shim control is also required

  6. Fireside corrosion testing of candidate superheater tube alloys, coatings, and claddings -- Phase 2 field testing

    Energy Technology Data Exchange (ETDEWEB)

    Blough, J.L.; Seitz, W.W.; Girshik, A. [Foster Wheeler Development Corp., Livingston, NJ (United States)

    1998-06-01

    In Phase 1 of this project, laboratory experiments were performed on a variety of developmental and commercial tubing alloys and claddings by exposing them to fireside corrosion tests which simulated a superheater or reheater in a coal-fired boiler. Phase 2 (in situ testing) has exposed samples of 347, RA85H, HR3C, RA253MA, Fe{sub 3}Al + 5Cr, Ta-modified 310, NF 709, 690 clad, 671 clad, and 800HT for up to approximately 16,000 hours to the actual operating conditions of a 250-MW, coal-fired boiler. The samples were installed on air-cooled, retractable corrosion probes, installed in the reheater cavity, and controlled to the operating metal temperatures of an existing and advanced-cycle, coal-fired boiler. Samples of each alloy were exposed for 4,483, 11,348, and 15,883 hours of operation. The present results are for the metallurgical examination of the corrosion probe samples after the full 15,883 hours of exposure. A previous topical report has been issued for the 4,483 hours of exposure.

  7. NRC quarterly [status] report

    International Nuclear Information System (INIS)

    This report covers the third quarter of calendar year 1987. The NRC licensing activity during the period of this report included the issuance of a full-power license for Beaver Valley 2 on August 14, 1987, and operating license restricted to five percent power for South Texas Unit 1 on August 21, 1987. Additional licensing delay for Shoreham is projected due to complex litigation. Also, licensing delay may occur for Comanche Peak Unit 1, because the duration of the hearing is uncertain. Although a license authorizing fuel loading and precriticality testing for Seabrook Unit 1 has been issued, there is a projected delay for low-power licensing. Full-power licensing for Seabrook Unit 1 will be delayed due to offsite emergency preparedness issues. The length of the delay is not known at this time. With the exception of Seabrook and Shoreham, regulatory delays in this report are not impacted by the schedules for resolving off-site emergency preparedness issues

  8. Guide to Low-Emission Boiler and Combustion Equipment Selection

    Energy Technology Data Exchange (ETDEWEB)

    Oland, CB

    2002-05-06

    Boiler owners and operators who need additional generating capacity face a number of legal, political, environmental, economic, and technical challenges. Their key to success requires selection of an adequately sized low-emission boiler and combustion equipment that can be operated in compliance with emission standards established by state and federal regulatory agencies. Recognizing that many issues are involved in making informed selection decisions, the U.S. Department of Energy (DOE), Office of Industrial Technologies (OIT) sponsored efforts at the Oak Ridge National Laboratory (ORNL) to develop a guide for use in choosing low-emission boilers and combustion equipment. To ensure that the guide covers a broad range of technical and regulatory issues of particular interest to the commercial boiler industry, the guide was developed in cooperation with the American Boiler Manufacturers Association (ABMA), the Council of Industrial Boiler Owners (CIBO), and the U.S. Environmental Protection Agency (EPA). The guide presents topics pertaining to industrial, commercial, and institutional (ICI) boilers. Background information about various types of commercially available boilers is provided along with discussions about the fuels that they burn and the emissions that they produce. Also included are discussions about emissions standards and compliance issues, technical details related to emissions control techniques, and other important selection considerations. Although information in the guide is primarily applicable to new ICI boilers, it may also apply to existing boiler installations.

  9. Quarterly coal report, July--September 1997

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-02-01

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks. Coke production consumption, distribution, imports, and exports data are also provided. This report presents detailed quarterly data for July through September 1997 and aggregated quarterly historical data for 1991 through the second quarter of 1997. Appendix A displays, from 1991 on, detailed quarterly historical coal imports data. 72 tabs.

  10. Archaeological analogs and corrosion

    International Nuclear Information System (INIS)

    In the framework of the high level and long life radioactive wastes disposal deep underground, the ANDRA built a research program on the material corrosion. In particular they aim to design containers for a very long time storage. Laboratory experiments are in progress and can be completed by the analysis of metallic archaeological objects and their corrosion after hundred years. (A.L.B.)

  11. Corrosion evaluation technology

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Uh Chul; Han, Jeong Ho; Nho, Kye Ho; Lee, Eun Hee; Kim, Hong Pyo; Hwang, Seong Sik; Lee, Deok Hyun; Hur, Do Haeng; Kim, Kyung Mo

    1997-09-01

    A multifrequency ACPD system was assembled which can measure very small crack. Stress corrosion cracking test system with SSRT operating high temperature was installed. Stress corrosion cracking test of newly developed alloy 600 and existing alloy 600 was carried out in steam atmosphere of 400 deg C. No crack was observed in both materials within a test period of 2,000 hrs. Corrosion fatigue test system operating at high temperature was installed in which fatigue crack was measured by CDPD. Lead enhanced the SCC of the Alloy 600 in high temperature water, had a tendency to modify a cracking morphology from intergranular to transgranular. Pit initiation preferentially occurred at Ti-rich carbide. Resistance to pit initiation decreased with increasing temperature up to 300 deg C. Test loop for erosion corrosion was designed and fabricated. Thin layer activation technique was very effective in measuring erosion corrosion. Erosion corrosion of a part of secondary side pipe was evaluated by the Check Family Codes of EPRI. Calculated values of pipe thickness by Check Family Codes coincided with the pipe thickness measured by UT with an error of {+-} 20%. Literature review on turbine failure showed that failure usually occurred in low pressure turbine rotor disc and causes of failure are stress corrosion cracking and corrosion fatigue. (author). 12 refs., 20 tabs., 77 figs.

  12. Corrosion in power engineering

    International Nuclear Information System (INIS)

    The proceedings contain full texts of 28 contributions, out of which 3 fall within the INIS subject scope. These are concerned with general corrosion problems in nuclear power industry and with corrosion effects of decontamination solutions on the structural materials of primary circuits of nuclear power plants. (Z.M.)

  13. Carbon Dioxide Corrosion:

    DEFF Research Database (Denmark)

    Fosbøl, Philip Loldrup

    2008-01-01

    CO2 corrosion is a general problem in the industry and it is expensive. The focus of this study is an oil gas production related problem. CO2 corrosion is observed in offshore natural gas transportation pipelines. A general overview of the problem is presented in chapter 1. The chemical system co...

  14. Monitoring of first condensate corrosion (FCC) in industrial steam systems; Ueberwachung der Korrosion des ersten Kondensats in industriellen Dampfsystemen

    Energy Technology Data Exchange (ETDEWEB)

    Savekoul, J.; Janssen, P.; Verhoef, H.

    2001-06-01

    In DSM's chemical process plants, water is often used for conveying energy from one plant to another. Steam is commonly used for direct or indirect process heating and for driving turbines. Steam pressures of 125 bar and temperatures up to 540 C are not exceptional. Demineralized surface water and process condensates are used as boiler feedwater. Minor amounts of impurities in condensate may lead to the formation of volatile acids in steam. Such acids present in the first condensate are able to initiate first condensate corrosion, resulting in chemical attack and fouling of steam boilers, turbines, and condensers. (orig.)

  15. NST Quarterly. October 1996 issue

    International Nuclear Information System (INIS)

    NST Quarterly reports current development in Nuclear Science and Technology in Malaysia. In this issue it highlights MINT activities in latex vulcanization (first RVNRL-based rubber gloves produced in Malaysia), tank floor scanning system (TAFLOSS), incineration and radiotherapeutic agent

  16. NST Quarterly. July 1996 issue

    International Nuclear Information System (INIS)

    NST Quarterly reports current development in Nuclear Science and Technology in Malaysia. In this issue it highlights MINT activities in in-vitro mutagenesis of ornamental plants, soil erosion studies and animal feed production from agricultural waste

  17. Control Properties of Bottom Fired Marine Boilers

    DEFF Research Database (Denmark)

    Solberg, Brian; Andersen, Palle; Karstensen, Claus M. S.

    2005-01-01

    This paper focuses on model analysis of a dynamic model of a bottom fired one-pass smoke tube boiler. Linearised versions of the model are analysed to determine how gain, time constants and right half plane zeros (caused by the shrink-and-swell phenomenon) depend on the steam flow load. Furthermore...... the interactions in the system are inspected to analyse potential benefit from using a multivariable control strategy in favour of the current strategy based on single loop theory. An analysis of the nonlinear model is carried out to further determine the nonlinear characteristics of the boiler system...... and to verify whether nonlinear control is needed. Finally a controller based on single loop theory is used to analyse if input constraints become active when rejecting transient behaviour from the disturbance steam flow. The model analysis shows large variations in system gains at steady state as...

  18. Maximising safety in the boiler house.

    Science.gov (United States)

    Derry, Carr

    2013-03-01

    Last month's HEJ featured an article, the second in our new series of guidance pieces aimed principally at Technician-level engineers, highlighting some of the key steps that boiler operators can take to maximise system performance and efficiency, and thus reduce running both costs and carbon footprint. In the third such article, Derry Carr, C.Env, I.Eng, BSc (Hons), M.I.Plant.E., M.S.O.E., technical manager & group gas manager at Dalkia, who is vice-chairman of the Combustion Engineering Association, examines the key regulatory and safety obligations for hospital energy managers and boiler technicians, a number of which have seen changes in recent years with revision to guidance and other documentation. PMID:23573684

  19. Recovery boiler model; Soodakattilan kehitystyoe III

    Energy Technology Data Exchange (ETDEWEB)

    Janka, K.; Ylitalo, M.; Sundstroem, K.; Helke, R.; Heinola, M. [Kvaerner Pulping Oy, Tampere (Finland)

    1997-10-01

    The recovery boiler model was further tested and developed. At this moment the model includes submodels for: droplet drying, pyrolysis, char burning, gas burning and for droplet trajectory. During 1996 the formation of CH{sub 4} during pyrolysis and release of sulfur was included to the model. Further the formation of NO from fuel nitrogen and formation of thermal- NO were included to the model using Arrhenius type reaction rate equations. The calculated results are realistic and the model is used as a tool to find out methods to increase the efficiency and availability and decrease the emissions. Analysing the results of the earlier field study of 8 boilers showed that the furnace heat load, fuming rate, find the black liquor composition have influence on the enrichment of the potassium to the fly ash. (orig.)

  20. Cause analysis and treatment of boiler water abnormity in a 300 MW unit%300 MW热电机组锅炉水质异常分析及处理

    Institute of Scientific and Technical Information of China (English)

    刘玮; 马知敬; 贾蓉

    2014-01-01

    新疆米东热电厂1号机组锅炉炉水电导率和 pH 值较高,超出正常范围,对水冷壁管存在腐蚀的风险。检测发现炉水中出现了大量游离NaOH,分析发现其由作为给水补水的热网疏水受热网循环水的污染所致。由于连续排污扩容器的分离蒸汽至除氧器的逆止阀存在缺陷,造成锅炉未真正有效排污,炉水长期处于过度浓缩状态,最终产生大量游离NaOH,对锅炉加强排污后,炉水水质恢复正常。%The conductivity and pH value of boiler water in No.1 unit of Midong Thermal Power Plant were over standard.So the water wall tubes suffered the risk of alkaline corrosion and boiler water concentrate corrosion.Detection finds a larger number of free sodium hydroxide appears in the boiler water.This is because the heat-supply network drain which is used as the feed water supplement water was polluted by leakage of circulating water of district heating system heater. The check valve between the steam separated from continuous blow-down flash vessel and the de-aerator had some defects,leading to invalid blow down,so the boiler water were over concentrat-ed,a larger number of free sodium hydroxide appeared in the boiler water,resulting in boiler wa-ter abnormality eventually.Finally,after improving continuous blow down,the boiler water turned back to normal.

  1. Boiler Modelling of Simple Combustion Processes

    OpenAIRE

    Radovan Nosek; Jozef Jandacka; Andrzej Szlek

    2012-01-01

    The aim of the work is to investigate coal combustion in fixed bed reactor. The experimental results were worked out in the form of approximation functions describing gas composition at the exit of fixed bed reactor. Furthermore, developed functions were applied for defining the boundary conditions at the interface between the fixed bed and gas phase using FLUENT. The simulations of a domestic boiler have been done and the relative effects of different factors in CFD code were evaluated by se...

  2. Incidence of cancer among Norwegian boiler welders.

    OpenAIRE

    Danielsen, T E; Langård, S; Andersen, A.

    1996-01-01

    OBJECTIVES: The cancer incidence among 2957 boiler welders was investigated. The subjects were registered electrical welders from 1942 to 1981. A subcohort of 606 stainless steel welders was studied separately. METHODS: The investigation was a historical prospective cohort study based on a national registry. The loss of follow up was 4.9%. RESULTS: There were 625 deaths (659 expected). There were 269 cancer cases (264 expected). An excess of lung cancer was found; 50 cases v 37.5 expected. Th...

  3. Circulating fluidized bed boilers design and operations

    CERN Document Server

    Basu, Prabir

    1991-01-01

    This book provides practicing engineers and students with insight into the design and operation of circulating fluidized bed (CFB) boilers. Through a combination of theoretical concepts and practical experience, this book gives the reader a basic understanding of the many aspects of this subject.Important environmental considerations, including solid waste disposal and predicted emissions, are addressed individually in separate chapters. This book places an emphasis on combustion, hydrodynamics, heat transfer, and material issues, and illustrates these concepts with numerous examples of pres

  4. ENVIRONMENTAL BENIGN MITIGATION OF MICROBIOLOGICALLY INFLUENCED CORROSION (MIC)

    Energy Technology Data Exchange (ETDEWEB)

    J.R. Paterek; G. Husmillo; V. Trbovic

    2003-01-01

    The overall program objective is to develop and evaluate environmental benign agents or products that are effective in the prevention, inhibition, and mitigation of microbially influenced corrosion (MIC) in the internal surfaces of metallic natural gas pipelines. The goal is one or more environmental benign, a.k.a. ''green'' products that can be applied to maintain the structure and dependability of the natural gas infrastructure. The technical approach for this quarter were isolation and cultivation of MIC-causing microorganisms from corroded pipeline samples, optimizing parameters in the laboratory-scale corrosion test loop system and testing the effective concentrations of Capsicum sp. extracts to verify the extent of corrosion on metal coupons by batch culture method. A total of 22 strains from the group of heterotrophic, acid producing, denitrifying and sulfate reducing bacteria were isolated from the gas pipeline samples obtained from Northern Indiana Public Service Company in Trenton, Indiana. They were purified and will be sent out for identification. Bacterial strains of interest were used in antimicrobial screenings and test loop experiments. Parameters for the laboratory-scale test loop system such as gas and culture medium flow rate; temperature; inoculation period; and length of incubation were established. Batch culture corrosion study against Desulfovibrio vulgaris showed that one (S{sub 1}M) out of the four Capsicum sp. extracts tested was effective in controlling the corrosion rate in metal coupons by 33.33% when compared to the untreated group.

  5. Gas mixing processes in nuclear AGR boilers

    International Nuclear Information System (INIS)

    To ensure the safe operation and control of Nuclear (A.G.R.) boilers, 2-D computational models are currently under development. The aim of these models is to predict the flow and temperature distribution of the gas and water side under different operational conditions. These models are based on numerical solutions of the 2-D flow and heat transfer equations for turbulent flow in boilers. Measurements on a closely pitched tube bank with water cooling have demonstrated considerable discrepancies between experimental results and computer predictions. This investigation is therefore being carried out to study theoretically and experimentally the flow and heat transfer process under such a boiler condition. A two dimensional computer model has been developed which incorporates the effects of gas mixing and the interactions between the gas and water side. To cover the complete heat exchanger the governing equations are written in the lumped parameter form. The governing equations have been solved by a computer code written in FORTRAN-77. To test the validity of this model, the computer predictions have been compared with experimental results. Results to date indicate reasonable agreement with experiment and a further refinement of the computer model is indicated. (author)

  6. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    Energy Technology Data Exchange (ETDEWEB)

    R. Viswanathan; K. Coleman; R.W. Swindeman; J. Sarver; J. Blough; W. Mohn; M. Borden; S. Goodstine; I. Perrin

    2003-10-20

    The principal objective of this project is to develop materials technology for use in ultrasupercritical (USC) plant boilers capable of operating with 760 C (1400 F), 35 MPa (5000 psi) steam. This project has established a government/industry consortium to undertake a five-year effort to evaluate and develop of advanced materials that allow the use of advanced steam cycles in coal-based power plants. These advanced cycles, with steam temperatures up to 760 C, will increase the efficiency of coal-fired boilers from an average of 35% efficiency (current domestic fleet) to 47% (HHV). This efficiency increase will enable coal-fired power plants to generate electricity at competitive rates (irrespective of fuel costs) while reducing CO{sub 2} and other fuel-related emissions by as much as 29%. Success in achieving these objectives will support a number of broader goals. First, from a national prospective, the program will identify advanced materials that will make it possible to maintain a cost-competitive, environmentally acceptable coal-based electric generation option. High sulfur coals will specifically benefit in this respect by having these advanced materials evaluated in high-sulfur coal firing conditions and from the significant reductions in waste generation inherent in the increased operational efficiency. Second, from a national prospective, the results of this program will enable domestic boiler manufacturers to successfully compete in world markets for building high-efficiency coal-fired power plants.

  7. Particulate emission abatement for Krakow boiler houses

    Energy Technology Data Exchange (ETDEWEB)

    Wysk, R.

    1995-12-31

    Among the many strategies for improving air quality in Krakow, one possible method is to adapt new and improved emission control technology. This project focuses on such a strategy. In order to reduce dust emissions from coal-fueled boilers, a new device called a Core Separator has been introduced in several boiler house applications. This advanced technology has been successfully demonstrated in Poland and several commercial units are now in operation. Particulate emissions from the Core Separator are typically 3 to 5 times lower than those from the best cyclone collectors. It can easily meet the new standard for dust emissions which will be in effect in Poland after 1997. The Core Separator is a completely inertial collector and is based on a unique recirculation method. It can effectively remove dust particles below 10 microns in diameter, the so-called PM-10 emissions. Its performance approaches that of fabric filters, but without the attendant cost and maintenance. It is well-suited to the industrial size boilers located in Krakow. Core Separators are now being marketed and sold by EcoInstal, one of the leading environmental firms in Poland, through a cooperative agreement with LSR Technologies.

  8. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    Energy Technology Data Exchange (ETDEWEB)

    R. Viswanathan; K. Coleman; R.W. Swindeman; J. Sarver; J. Blough; W. Mohn; M. Borden; S. Goodstine; I. Perrin

    2003-08-04

    The principal objective of this project is to develop materials technology for use in ultrasupercritical (USC) plant boilers capable of operating with 760 C (1400 F), 35 MPa (5000 psi) steam. This project has established a government/industry consortium to undertake a five-year effort to evaluate and develop of advanced materials that allow the use of advanced steam cycles in coal-based power plants. These advanced cycles, with steam temperatures up to 760 C, will increase the efficiency of coal-fired boilers from an average of 35% efficiency (current domestic fleet) to 47% (HHV). This efficiency increase will enable coal-fired power plants to generate electricity at competitive rates (irrespective of fuel costs) while reducing CO{sub 2} and other fuel-related emissions by as much as 29%. Success in achieving these objectives will support a number of broader goals. First, from a national prospective, the program will identify advanced materials that will make it possible to maintain a cost-competitive, environmentally acceptable coal-based electric generation option. High sulfur coals will specifically benefit in this respect by having these advanced materials evaluated in high-sulfur coal firing conditions and from the significant reductions in waste generation inherent in the increased operational efficiency. Second, from a national prospective, the results of this program will enable domestic boiler manufacturers to successfully compete in world markets for building high-efficiency coal-fired power plants.

  9. Field Test of Boiler Primary Loop Temperature Controller

    Energy Technology Data Exchange (ETDEWEB)

    Glanville, P. [Partnership for Advanced Residential Retrofit, Des Plaines, IL (United States); Rowley, P. [Partnership for Advanced Residential Retrofit, Des Plaines, IL (United States); Schroeder, D. [Partnership for Advanced Residential Retrofit, Des Plaines, IL (United States); Brand, L. [Partnership for Advanced Residential Retrofit, Des Plaines, IL (United States)

    2014-09-01

    Beyond these initial system efficiency upgrades are an emerging class of Advanced Load Monitoring (ALM) aftermarket controllers that dynamically respond to the boiler load, with claims of 10% to 30% of fuel savings over a heating season. For hydronic boilers specifically, these devices perform load monitoring, with continuous measurement of supply and, in some cases, return water temperatures. Energy savings from these ALM controllers are derived from dynamic management of the boiler differential, where a microprocessor with memory of past boiler cycles prevents the boiler from firing for a period of time, to limit cycling losses and inefficient operation during perceived low load conditions. These differ from OTR controllers, which vary boiler setpoint temperatures with ambient conditions while maintaining a fixed differential.

  10. A Rule-Based Industrial Boiler Selection System

    Science.gov (United States)

    Tan, C. F.; Khalil, S. N.; Karjanto, J.; Tee, B. T.; Wahidin, L. S.; Chen, W.; Rauterberg, G. W. M.; Sivarao, S.; Lim, T. L.

    2015-09-01

    Boiler is a device used for generating the steam for power generation, process use or heating, and hot water for heating purposes. Steam boiler consists of the containing vessel and convection heating surfaces only, whereas a steam generator covers the whole unit, encompassing water wall tubes, super heaters, air heaters and economizers. The selection of the boiler is very important to the industry for conducting the operation system successfully. The selection criteria are based on rule based expert system and multi-criteria weighted average method. The developed system consists of Knowledge Acquisition Module, Boiler Selection Module, User Interface Module and Help Module. The system capable of selecting the suitable boiler based on criteria weighted. The main benefits from using the system is to reduce the complexity in the decision making for selecting the most appropriate boiler to palm oil process plant.

  11. Behavioral study solar boilers 1994. Summary. Part 2 (households)

    International Nuclear Information System (INIS)

    The aim of the Dutch national solar boiler campaign of NOVEM and Holland Solar is to realize the installation of 300,000 solar boilers in the Netherlands in the year 2010. In 1995 10,000 boilers were installed. More knowledge of the decision making process and the backgrounds and motives of (potential) buyers is required. From September 1994 to March 1995 a survey has been carried out of the decision making processes in households and housing corporations. The most important results, conclusions and recommendations of the survey are summarized in this report. The parameters that can influence the decision whether to purchase a solar boiler or not are knowledge about the solar boiler, the attitude towards the solar boiler and towards the use of energy and the environment, risk perception, social aspects, information retrieval behavior, constraints, and socio-economic aspects. 44 tabs

  12. Modelling, simulating and optimizing boiler heating surfaces and evaporator circuits

    DEFF Research Database (Denmark)

    Sørensen, K.; Condra, T.; Houbak, Niels

    2003-01-01

    A model for optimizing the dynamic performance of boiler have been developed. Design variables related to the size of the boiler and its dynamic performance have been defined. The object function to be optimized takes the weight of the boiler and its dynamic capability into account. As constraints...... for the optimization a dynamic model for the boiler is applied. Furthermore a function for the value of the dynamic performance is included in the model. The dynamic models for simulating boiler performance consists of a model for the flue gas side, a model for the evaporator circuit and a model for...... the drum. The dynamic model has been developed for the purpose of determining boiler material temperatures and heat transfer from the flue gas side to the water-/steam side in order to simulate the circulation in the evaporator circuit and hereby the water level fluctuations in the drum. The dynamic...

  13. The behavior of ash species in suspension fired biomass boilers

    DEFF Research Database (Denmark)

    Jensen, Peter Arendt

    to generate ash particles typically in the size range of 50 to 200 μm on biomass suspension fired power plant boilers. A fragmentation rate of fuel particles of 3 have been used to describe both the residual ash formation process in laboratory entrained flow reactors and in full scale boilers.A range...... coal fly ash with a high content of Si and Al isused as an additive on wood fired plants to reduce the problems with alkali salt de-activationof SCR catalysts. While the fundamental chemistry of the additives are well known detailed reaction models of the interaction of salts and additive particles......While fluid bed and grate fired boilers initially was the choice of boilers used for power production from both wood and herbaceous biomass, in recent years suspension fired boilers have been increasingly used for biomass based power production. In Denmark several large pulverized fuel boilers have...

  14. Deposit Probe Measurements in Large Biomass-Fired Grate Boilers and Pulverized-Fuel Boilers

    DEFF Research Database (Denmark)

    Hansen, Stine Broholm; Jensen, Peter Arendt; Jappe Frandsen, Flemming;

    2014-01-01

    build-up increased with the K-content of the fuel ash and fly ash for grate-fired boilers. For suspension-fired boilers, deposition rates are comparatively low for wood-firing and increase with increasing fuel straw shares. Shedding of deposits occurs by melting during straw-firing on a grate at high......A number of full-scale deposit probe measuring campaigns conducted in grate-fired and suspension-fired boilers, fired with biomass, have been reviewed and compared. The influence of operational parameters on the chemistry of ash and deposits, on deposit build-up rates, and on shedding behavior has...... been examined. The firing technology and the fuel utilized influence the fly ash and deposit chemical composition. In grate-firing, K, Cl, and S are enriched in the fly ash compared to the fuel ash, while the fly ash in suspension-firing is relatively similar to the fuel ash. The chemical composition...

  15. Corrosion Inhibitors for Reinforced Concrete

    OpenAIRE

    ECT Team, Purdue

    2007-01-01

    Steel corrosion in reinforced concrete structures has been a major problem across the U.S. Steel-reinforced concrete structures are continually subject to attack by corrosion brought on by naturally occurring environmental conditions. FerroGard, a corrosion inhibitor, developed by Sika Corporation, penetrates hardened concrete to dramatically reduce corrosion by 65% and extend the structure's service life.

  16. Automated Methods Of Corrosion Measurements

    DEFF Research Database (Denmark)

    Bech-Nielsen, Gregers; Andersen, Jens Enevold Thaulov; Reeve, John Ch;

    1997-01-01

    The chapter describes the following automated measurements: Corrosion Measurements by Titration, Imaging Corrosion by Scanning Probe Microscopy, Critical Pitting Temperature and Application of the Electrochemical Hydrogen Permeation Cell.......The chapter describes the following automated measurements: Corrosion Measurements by Titration, Imaging Corrosion by Scanning Probe Microscopy, Critical Pitting Temperature and Application of the Electrochemical Hydrogen Permeation Cell....

  17. Corrosion Failures in Marine Environment

    Directory of Open Access Journals (Sweden)

    R. Krishnan

    1985-04-01

    Full Text Available This paper gives a brief description of typical marine environments and the most common form of corrosion of materials used in this environment. Some typical case histories of failures pertaining to pitting, bimetallic corrosion, dealloying, cavitation and stress corrosion cracking are illustrated as typical examples of corrosion failures.

  18. Optimal Combustion Conditions for a Small-scale Biomass Boiler

    OpenAIRE

    Viktor Plaček; Cyril Oswald; Jan Hrdlička

    2012-01-01

    This paper reports on an attempt to achieve maximum efficiency and lowest possible emissions for a small-scale biomass boiler. This aim can be attained only by changing the control algorithm of the boiler, and in this way not raising the acquisition costs for the boiler. This paper describes the experimental facility, the problems that arose while establishing the facility, and how we have dealt with them. The focus is on discontinuities arising after periodic grate sweeping, and on finding t...

  19. Investigations of operation problems at a 200 MWe PF boiler

    OpenAIRE

    Peta Sandile; Toit Chris du; Naidoo Reshendren; Schmitz Walter; Jestin Louis

    2015-01-01

    To minimize oxides of nitrogen (NOx) emission, maximize boiler combustion efficiency, achieve safe and reliable burner combustion, it is crucial to master global boiler and at-the-burner control of fuel and air flows. Non-uniform pulverized fuel (PF) and air flows to burners reduce flame stability and pose risk to boiler safety by risk of reverse flue gas and fuel flow into burners. This paper presents integrated techniques implemented at pilot ESKOM power plants for the determination of glob...

  20. PERANCANGAN pH METER PADA BOILER HRSG BERBASIS ARDUINO

    OpenAIRE

    Yuliza .; Gatot Susanto

    2015-01-01

    Air merupakan zat yang sangat dibutuhkan pada setiap sektor industri, termasuk pemanfaatan untuk kebutuhan energi dan pemanasan. Kebutuhan energi dan pemanasan di industri umumnya dipenuhi dengan cara memanfaatkan steam yang dibangkitkan dalam suatu ketel (boiler). Air yang digunakan sebagai umpan boiler dapat diperoleh dari berbagai sumber yaitu danau, sungai, laut, maupun sumur. Kandungan  air ini sangat mempengaruhi Harga pH pada air umpan boiler, penting untuk diperhatikan untuk mencegah ...

  1. Development and testing of a high efficiency advanced coal combustor phase III industrial boiler retrofit. Technical progress report No. 17, 18 and 19, September 30, 1991--December 31, 1996

    Energy Technology Data Exchange (ETDEWEB)

    Borio, R.W.; Patel, R.L.; Thornock, D.E. [and others

    1996-07-29

    The objective of this project is to retrofit a burner, capable of firing microfine coal, to a standard gas/oil designed industrial boiler to assess the technical and economic viability of displacing premium fuels with microfine coal. This report documents the technical aspects of this project during the last three quarters [seventeenth (October `95 through December `95), eighteenth (January `96 through March `96), and nineteenth (April `96 through June `96)] of the program.

  2. The behavior of ash species in suspension fired biomass boilers

    OpenAIRE

    Jensen, Peter Arendt

    2015-01-01

    While fluid bed and grate fired boilers initially was the choice of boilers used for power production from both wood and herbaceous biomass, in recent years suspension fired boilers have been increasingly used for biomass based power production. In Denmark several large pulverized fuel boilers have been converted from coal to biomass combustion in the last 15 years. This have included co-firing of coal and straw, up to 100% firing of wood or straw andthe use of coal ash as an additive to reme...

  3. Relocation of boilers to Gulbene, Latvia. Final report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-09-01

    This report describes the relocation of two coal-fired boilers from Hoeje-Taastrup, Denmark to the City of Gulbene, Latvia and the conversion of one of these boilers to combustion of wood chips. The selection of Gulbene DHE as recipient of the two boilers was made by the Danish Energy Agency. The selection was based on e feasibility study, `Small Boilers Fuel Conversion Study` prepared by the Consulting Engineering Company Birch and Krogeoe/Esbensen in 1994. The recommendations regarding the relocation and conversion of the former coal-fired boilers to use wood chips have been given in a study performed by dk-TEKNIK in the year 1994. The objectives of the Consultant`s project can be summarized as follows: Prequalification of Contractors for the boiler relocation; Preparation of Tender Documents for relocation of two formerly coal-fired boilers placed in Hoeje-Taastrup to Gulbene and conversion of the boilers to combustion of wood fuel; Evaluation and Contracting; Site supervision; Handing-over. The scope of the report describes the final reporting of the boiler relocation to Gulbene. This includes: The process of the relocation; Financial calculations; Experience gained through the project. (EG)

  4. Field Test of Boiler Primary Loop Temperature Controller

    Energy Technology Data Exchange (ETDEWEB)

    Glanville, P.; Rowley, P.; Schroeder, D.; Brand, L.

    2014-09-01

    Beyond these initial system efficiency upgrades are an emerging class of Advanced Load Monitoring (ALM) aftermarket controllers that dynamically respond to the boiler load, with claims of 10% to 30% of fuel savings over a heating season. For hydronic boilers specifically, these devices perform load monitoring, with continuous measurement of supply and in some cases return water temperatures. Energy savings from these ALM controllers are derived from dynamic management of the boiler differential, where a microprocessor with memory of past boiler cycles prevents the boiler from firing for a period of time, to limit cycling losses and inefficient operation during perceived low load conditions. These differ from OTR controllers, which vary boiler setpoint temperatures with ambient conditions while maintaining a fixed differential. PARR installed and monitored the performance of one type of ALM controller, the M2G from Greffen Systems, at multifamily sites in the city of Chicago and its suburb Cary, IL, both with existing OTR control. Results show that energy savings depend on the degree to which boilers are over-sized for their load, represented by cycling rates. Also savings vary over the heating season with cycling rates, with greater savings observed in shoulder months. Over the monitoring period, over-sized boilers at one site showed reductions in cycling and energy consumption in line with prior laboratory studies, while less over-sized boilers at another site showed muted savings.

  5. Thermal power of small scale manually fed boiler

    OpenAIRE

    Janić Todor V.; Igić Saša M.; Dedović Nebojša M.; Pavlović Darijan B.; Turan Jan J.; Sedlar Aleksandar D.

    2015-01-01

    This study reviews test results of the combustion of square soybean straw bales used as fuel in manually fed boiler with nominal thermal power of 120 kWth. The influence of the mass flow rate (180, 265, 350, 435, and 520 kg h-1) of inlet air and flue gas recirculation (0%, 16.5%, and 33%) fed to the boiler furnace was continuously monitored. Direct method was used for determination of the boiler thermal power. Correlation between boiler thermal power and ba...

  6. Between the boiler and buffer tank; Zwischen Kessel und Speicher

    Energy Technology Data Exchange (ETDEWEB)

    Ertmer, Katharina

    2013-08-06

    Some manufacturers offer new heating pump groups for return temperature raising for solid-fuel boilers. [German] Einige Hersteller bieten neue Heizungspumpengruppen zur Ruecklauftemperaturanhebung bei Festbrennstoffkesseln an.

  7. Thermomechanical finite element analysis of hot water boiler structure

    OpenAIRE

    Živković Dragoljub S.; Milčić Dragan S.; Banić Milan S.; Milosavljević Peđa M.

    2012-01-01

    The paper presents an application of the Finite Elements Method for stress and strain analysis of the hot water boiler structure. The aim of the research was to investigate the influence of the boiler scale on the thermal stresses and strains of the structure of hot water boilers. Results show that maximum thermal stresses appear in the zone of the pipe carrying wall of the first reversing chamber. This indicates that the most critical part of the boiler are weld spots of the smoke pipe...

  8. 46 CFR 52.20-17 - Opening between boiler and safety valve (modifies PFT-44).

    Science.gov (United States)

    2010-10-01

    ... ENGINEERING POWER BOILERS Requirements for Firetube Boilers § 52.20-17 Opening between boiler and safety valve (modifies PFT-44). When a discharge pipe is used, it must be installed in accordance with the...

  9. Elucidating Sweet Corrosion Scales

    OpenAIRE

    Joshi, Gaurav Ravindra

    2015-01-01

    The objective of this thesis is to improve understanding of the development of corrosion products (scales) that form on the inner walls of carbon steel pipelines in CO2-rich (sweet) oilfield environments. If well adherent to the carbon steel surface, such scales can significantly reduce the metal’s rate of corrosion. Typically, the open literature labels sweet corrosion scale as ferrous (II) carbonate (FeCO3) or siderite, although this may not always be the case. For example, Fe2(OH)2CO3 (chu...

  10. Understanding localized corrosion

    Directory of Open Access Journals (Sweden)

    G.S. Frankel

    2008-10-01

    Full Text Available The breakdown of a protective passive film leading to accelerated dissolution at localized sites is an important practical issue and a vexing scientific problem. The small dimensions, short timescale, and dynamic interplay between a heterogeneous surface and changing potential and solution concentration gradients complicate the development of a complete understanding of the phenomena. This review touches on some of the recent developments in the field, including scanning tunneling microscopy imaging of the earliest stages of pitting which supports a new model explaining the localization of attack, pitting in thin aqueous layers relevant to atmospheric corrosion, the factors controlling crevice corrosion, and predictive modeling of localized corrosion.

  11. Microbiologically influenced corrosion testing

    International Nuclear Information System (INIS)

    This symposium was held November 16--17, 1992 in Miami, Florida. The purpose of the symposium was to provide a forum for state-of-the-art information on the effects of microorganisms on the corrosion of metals. Many industrial needs in the area of microbial influenced corrosion testing are identified in the presentations along with latest laboratory and field testing techniques. Strategies to monitor and control corrosion and biofouling in water distribution systems, underground pipelines, buildings, and marine vessels are discussed. Individual papers have been processed separately for inclusion in the appropriate data bases

  12. Irritants and corrosives.

    Science.gov (United States)

    Tovar, Richard; Leikin, Jerrold B

    2015-02-01

    This article reviews toxic chemicals that cause irritation and damage to single and multiple organ systems (corrosion) in an acute fashion. An irritant toxic chemical causes reversible damage to skin or other organ system, whereas a corrosive agent produces irreversible damage, namely, visible necrosis into integumentary layers, following application of a substance for up to 4 hours. Corrosive reactions can cause coagulation or liquefaction necrosis. Damaged areas are typified by ulcers, bleeding, bloody scabs, and eventual discoloration caused by blanching of the skin, complete areas of alopecia, and scars. Histopathology should be considered to evaluate questionable lesions. PMID:25455665

  13. Archaeological analogues and corrosion

    International Nuclear Information System (INIS)

    One solution retained for the management of high-level and long living radioactive wastes is the disposal in deep underground. Among the studies carried out by the Andra for the evaluation this solution, one concerns the research on metals corrosion for the development of reliable containers. Laboratory corrosion tests are in progress and are compared to the corrosion state of archaeological metal specimens of several hundred years old. Gallic or Mesopotamian remnants are some of these archaeological analogues which are analyzed using the most advanced techniques of materials science. (J.S.)

  14. Corrosion resistant amorphous alloys

    International Nuclear Information System (INIS)

    A review of publication data on corrosion resistance of amorphous alloys and the methods of amorphization of surface layers of massive materials (laser treatment, iron implantation, detonation-gas spraying, cathode and ion sputtering, electrodeposition) was made. A study was made on corrosion properties of Fe66Cr11B10Si4 alloy in cast state and after laser irradiation, rendering the surface amorphous as well as the samples of Arenco iron and steel 20 with ion-plasma coatings of Fe-Cr-Ni-Ti alloy. It was established that amorphous coatings posses much higher corrosion resistance as compared to crystalline alloys on the same base

  15. Improvement in super heater deposition of straw boiler based on numerical simulation

    Energy Technology Data Exchange (ETDEWEB)

    Tai, Lv; Zhou, Ting-ting; Wang, Hai [Northeast Dianli Univ., Jilin (China). College of Energy and Power Engineering

    2013-07-01

    There is the problem of deposition exits generally in straw boiler super heater due to chlorine and alkalescent substance consists in the straw fuel, which agglomerate combustion material, especially for crops. Deposition does not only behave to raise the tube temperature, but also accelerate corrosion, even hide cartridge igniter trouble. This paper based on the study of some 75 t/h plant to optimize the ash removal system of super heater. According to the CFD simulation, the flue flow situation in tube bundle of super heater diverse along with the position of the tube. Based on the regular of deposit researched from the simulation outcome, this paper propose to optimize the structure of shock wave soot blower of pattern BH-100 used by the plant, which did not performance a proper role.

  16. Investigations of the Failure in Boilers Economizer Tubes Used in Power Plants

    Science.gov (United States)

    Moakhar, Roozbeh Siavash; Mehdipour, Mehrad; Ghorbani, Mohammad; Mohebali, Milad; Koohbor, Behrad

    2013-09-01

    In this study, failure of a high pressure economizer tube of a boiler used in gas-Mazut combined cycle power plants was studied. Failure analysis of the tube was accomplished by taking into account visual inspection, thickness measurement, and hardness testing as well as microstructural observations using scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and x-ray diffraction (XRD). Optical microscopy images indicate that there is no phase transformation during service, and ferrite-pearlite remained. The results of XRD also revealed Iron sulfate (FeSO4) and Iron hydroxide sulfate (FeOH(SO4)) phases formed on the steel surface. A considerable amount of Sulfur was also detected on the outer surface of the tube by EDS analysis. Dew-point corrosion was found to be the principal reason for the failure of the examined tube while it has been left out-of-service.

  17. Pipe Lines – External Corrosion

    OpenAIRE

    Dan Babor

    2008-01-01

    Two areas of corrosion occur in pipe lines: corrosion from the medium carried inside the pipes; corrosion attack upon the outside of the pipes (underground corrosion. Electrolytic processes are also involved in underground corrosion. Here the moisture content of the soil acts as an electrolyte, and the ions required to conduct the current are supplied by water-soluble salts (chlorides, sulfates, etc.) present in the soil. The nature and amount of these soluble materials can vary within a wide...

  18. Quarterly environmental data summary for fourth quarter 1997

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-12-31

    The Quarterly Environmental Data Summary (QEDS) for the fourth quarter of 1997 is prepared in support of the Weldon Spring Site Remedial Action Project Federal Facilities Agreement. The data presented constitute the QEDS. The data were received from the contract laboratories, verified by the Weldon Spring Site verification group and, except for air monitoring data and site KPA generated data (uranium analyses), merged into the data base during the fourth quarter of 1997. Air monitoring data presented are the most recent complete sets of quarterly data. Air data are not stored in the data base and KPA data are not merged into the regular data base. Significant data, defined as data values that have exceeded defined ``above normal`` level 2 values, are discussed in this letter for Environmental Monitoring Plan (EMP) generated data only. Above normal level 2 values are based, in ES and H procedures, on historical high values, DOE Derived Concentration Guides (DCGs), NPDES limits and other guidelines. The procedures also establish actions to be taken in response to such data. Data received and verified during the fourth quarter were within a permissible range of variability except for those which are detailed.

  19. Short-term energy outlook: Quarterly projections, fourth quarter 1997

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-10-14

    The Energy Information Administration (EIA) prepares quarterly short-term energy supply, demand, and price projections for printed publication in January, April, July, and October in the Short-Term Energy Outlook. The details of these projections, as well as monthly updates on or about the 6th of each interim month, are available on the internet at: www.eia.doe.gov/emeu/steo/pub/contents.html. The forecast period for this issue of the Outlook extends from the fourth quarter of 1997 through the fourth quarter of 1998. Values for the fourth quarter of 1997, however, are preliminary EIA estimates (for example, some monthly values for petroleum supply and disposition are derived in part from weekly data reported in EIA`s Weekly Petroleum Status Report) or are calculated from model simulations that use the latest exogenous information available (for example, electricity sales and generation are simulated by using actual weather data). The historical energy data, compiled in the fourth quarter 1997 version of the Short-Term Integrated Forecasting System (STIFS) database, are mostly EIA data regularly published in the Monthly Energy Review, Petroleum Supply Monthly, and other EIA publications. Minor discrepancies between the data in these publications and the historical data in this Outlook are due to independent rounding. The STIFS model is driven principally by three sets of assumptions or inputs: estimates of key macroeconomic variables, world oil price assumptions, and assumptions about the severity of weather. 19 tabs.

  20. Quarterly coal report, April--June 1997

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-11-01

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience. Coke production, consumption, distribution, imports, and exports data are also provided. This report presents detailed quarterly data for April through June 1997 and aggregated quarterly historical data for 1991 through the first quarter of 1997. Appendix A displays, from 1991 on, detailed quarterly historical coal imports data. Appendix B gives selected quarterly tables converted to metric tons. To provide a complete picture of coal supply and demand in the US, historical information has been integrated in this report. 8 figs., 73 tabs.

  1. Fouling and corrosion problems of raw water circuits of FBTR and RAPS

    International Nuclear Information System (INIS)

    Fouling and corrosion are two major operational problems in the heat exchangers of power plant cooling system. Nuclear power plants are more susceptible to fouling induced corrosion than their thermal counterparts due to their inherent design characteristics like long gestation period, multiple standby systems etc. Problems such as flow blockage of pipes, pipe punctures and relatively high corrosion rates were experienced in the service water system of the Fast Breeder Test Reactor (FBTR) at Kalpakkam. Similarly about 1100 condenser tubes in Rajasthan Atomic Power Station (RAPS) II have failed during two years of operation resulting in leakage (80-2100 l/h) of condenser cooling water into the boiler feed water. As a result of this total dissolved solids (TDS), chloride, total hardness and silica content in the boiler water remained above the specified limit for a good amount of time. In view of the possible linkage between water quality and microbial activity resulting in material degradation, experiments on water quality (Palar subsoil, open reservoir, RAPS intake and out fall), corrosion rate measurements, microbiological counts and experiment on chlorination vs bacterial mortality were carried out with a view to study the effectiveness of existing treatment programme in FBTR cooling system and also to look for possible linkage between water quality and condenser tubes failures of RAPS. 10 refs., 2 tabs., 1 fig

  2. Panel report on corrosion in energy systems

    International Nuclear Information System (INIS)

    Corrosion problems in high-temperature (non aqueous) energy systems, corrosion in aqueous energy systems and institutional problems inhibiting the development of corrosion science and engineering are discussed

  3. Corrosion Inhibitors for Aluminum.

    Science.gov (United States)

    Muller, Bodo

    1995-01-01

    Describes a simple and reliable test method used to investigate the corrosion-inhibiting effects of various chelating agents on aluminum pigments in aqueous alkaline media. The experiments that are presented require no complicated or expensive electronic equipment. (DDR)

  4. The microbial corrosion

    International Nuclear Information System (INIS)

    Underestimated for a long time, corrosion due to microorganisms induces degradation, sometimes fulminant, of a lot of metallic structures in the world. Searchers are using plentiful analytical tools to understand this phenomenon. (O.M.)

  5. BWR steel containment corrosion

    International Nuclear Information System (INIS)

    The report describes regulatory actions taken after corrosion was discovered in the drywell at the Oyster Creek Plant and in the torus at the Nine Mile Point 1 Plant. The report describes the causes of corrosion, requirements for monitoring corrosion, and measures to mitigate the corrosive environment for the two plants. The report describes the issuances of generic letters and information notices either to collect information to determine whether the problem is generic or to alert the licensees of similar plants about the existence of such a problem. Implementation of measures to enhance the containment performance under severe accident conditions is discussed. A study by Brookhaven National Laboratory (BNL) of the performance of a degraded containment under severe accident conditions is summarized. The details of the BNL study are in the appendix to the report

  6. Accelerated cyclic corrosion tests

    OpenAIRE

    Prošek T.

    2016-01-01

    Accelerated corrosion testing is indispensable for material selection, quality control and both initial and residual life time prediction for bare and painted metallic, polymeric, adhesive and other materials in atmospheric exposure conditions. The best known Neutral Salt Spray (NSS) test provides unrealistic conditions and poor correlation to exposures in atmosphere. Modern cyclic accelerated corrosion tests include intermittent salt spray, wet and dry phases and eventually other technical p...

  7. Short-term energy outlook. Quarterly projections, first quarter 1995

    International Nuclear Information System (INIS)

    The Energy Information Administration (EIA) prepares quarterly, short-term energy supply, demand, and price projections for publication in February, May, August, and November in the Short-Term Energy Outlook (Outlook). The forecast period for this issue of the Outlook extends from the first quarter of 1995 through the fourth quarter of 1996. Values for the fourth quarter of 1994, however, are preliminary EIA estimates or are calculated from model simulations using the latest exogenous information available (for example, electricity sales and generation are simulated using actual weather data). The historical energy data, compiled into the first quarter 1995 version of the Short-Term Integrated Forecasting System (STIFS) database, are mostly EIA data regularly published in the Monthly Energy Review, Petroleum Supply Monthly, and other EIA publications. Minor discrepancies between the data in these publications and the historical data in this Outlook are due to independent rounding. The STIFS database is archived quarterly and is available from the National Technical Information Service. The cases are produced using the Short-Term Integrated Forecasting System (STIFS). The STIFS model is driven principally by three sets of assumptions or inputs: estimates of key macroeconomic variables, world oil price assumptions, and assumptions about the severity of weather. Macroeconomic estimates are produced by DRI/McGraw-Hill but are adjusted by EIA to reflect EIA assumptions about the world price of crude oil, energy product prices, and other assumptions which may affect the macroeconomic outlook. The EIA model is available on computer tape from the National Technical Information Service

  8. Corrosion monitoring in a straw-fired power plant using an electrochemical noise probe

    DEFF Research Database (Denmark)

    Cappeln, Frederik Vilhelm; Bjerrum, Niels; Petrushina, Irina

    2007-01-01

    Electrochemical Noise Measurements have been carried out in situ in a straw-fired power plant using an experimental probe constructed from alumina and AlSl 347 steel. Based on a framework of controlled laboratory experiments it has been found that electrochemical noise has the unique ability to...... provide in-situ monitoring of intergranular corrosion in progress. The probe had a lifetime of two months. It was shown that down-time corrosion in the boiler was negligible. Electrochemical noise data indicated that metal temperatures around 590 degrees C should be avoided as the intergranular corrosion...... is at an increased level at this temperature, most likely because of favorable conditions for molten salt film condensation....

  9. Study of the Intercrystalline Corrosion in Pipes of Stainless Steel in a Combined Cycle

    Directory of Open Access Journals (Sweden)

    Raúl Andrés Montejo Serrano

    2014-09-01

    Full Text Available The present work is carried out with the purpose of giving answer to the possible presence ofintercrystalline corrosion and its future consequences in the built tubes of stainless steel 304L anddedicated to the conduction from the water to the boilers of a combined cycle of electricity production.The plant is these in this moments in installation of process investor and assembly and this study wasrequested since during the trial of installation of the pipes of stainless steel that will drive the watertried to the steam generators, they were detected on the part of the operatives some imperfections inthe material, what generated the doubt about the possibility of presence of intercrystalline corrosion orof another type in the pipes. After the realized rehearsals according to international norms and alsousing rehearsals metallography you concludes that the material employee is not sensitive to this typeof corrosion.

  10. Field test corrosion experiences when co-firing straw and coal: 10 year status within Elsam

    DEFF Research Database (Denmark)

    Frandsen, Rasmus Berg; Montgomery, Melanie; Larsen, Ole Hede

    2007-01-01

    In Denmark, straw is utilised for the generation of energy and district heating in power plants. Combustion of straw gives rise to high contents of potassium chloride and some sulphur dioxide in the flue gas. These compounds can lead to deposits with high content of potassium chloride and potassium...... sulphate on superheater tubes resulting in increased corrosion rates. From field experimental results this paper show, that by co-firing straw with coal, corrosion rates can be brought down to an acceptable level. This paper firstly deals with the results from a demonstration program co-firing coal...... and straw at the 150 MW pulverized coal fired boiler Studstrup unit 1. Two exposure series lasting 3000 hours each were performed for co-firing 10 and 20% of straw (% energy basis) with coal. Using built in test tubes in the hot end of the actual superheaters and air/water cooled corrosion probes...

  11. Materials and boiler rig testing to support chemical cleaning of once-through AGR boilers

    Energy Technology Data Exchange (ETDEWEB)

    Tice, D.R.; Platts, N.; Raffel, A.S. [Serco Assurance (United Kingdom); Rudge, A. [British Energy Generation Ltd. (United Kingdom)

    2002-07-01

    An extensive programme of work has been carried out to evaluate two candidate inhibited cleaning solutions for possible implementation on plant, which would be the first chemical clean of an AGR boiler. The two candidate cleaning solutions considered were a Stannine-inhibited citric acid/formic acid mixture (GOM106) and inhibited hydrofluoric acid. Citric acid-based cleaning processes are widely used within the UK Power Industry. The GOM106 solution, comprising a mixture of 3% citric acid, 0.5% formic acid and 0.05% Stannine LTP inhibitor, buffered with ammonia to pH 3.5, was developed specifically for the AGR boilers during the 1970's. Although a considerable amount of materials testing work was carried out by British Energy's predecessor companies to produce a recommended cleaning procedure there were some remaining concerns with the use of GOM106, from these earlier studies, for example, an increased risk of pitting attack associated with the removal of thick 9Cr oxide deposits and a risk of unacceptable damage in critical locations such as the upper transition joints and other weld locations. Hence, additional testing was still required to validate the solution for use on plant. Inhibited hydrofluoric acid (HFA) was also evaluated as an alternative reagent to GOM106. HFA has been used extensively for cleaning mild and low'alloy steel boiler tubes in fossil-fired plant in the UK and elsewhere in Europe and is known to remove oxide quickly. Waste treatment is also easier than for the GOM106 process and some protection against damage to the boiler tube materials is provided by complexing of fluoride with ferric ion. Validation of the potential reagents and inhibitors was achieved by assessing the rate and effectiveness of oxide removal from specimens of helical boiler tubing and welds, together with establishing the extent of any metal loss or localised damage. The initial materials testing resulted in the inhibited ammoniated citric / formic acid

  12. Materials and boiler rig testing to support chemical cleaning of once-through AGR boilers

    International Nuclear Information System (INIS)

    An extensive programme of work has been carried out to evaluate two candidate inhibited cleaning solutions for possible implementation on plant, which would be the first chemical clean of an AGR boiler. The two candidate cleaning solutions considered were a Stannine-inhibited citric acid/formic acid mixture (GOM106) and inhibited hydrofluoric acid. Citric acid-based cleaning processes are widely used within the UK Power Industry. The GOM106 solution, comprising a mixture of 3% citric acid, 0.5% formic acid and 0.05% Stannine LTP inhibitor, buffered with ammonia to pH 3.5, was developed specifically for the AGR boilers during the 1970's. Although a considerable amount of materials testing work was carried out by British Energy's predecessor companies to produce a recommended cleaning procedure there were some remaining concerns with the use of GOM106, from these earlier studies, for example, an increased risk of pitting attack associated with the removal of thick 9Cr oxide deposits and a risk of unacceptable damage in critical locations such as the upper transition joints and other weld locations. Hence, additional testing was still required to validate the solution for use on plant. Inhibited hydrofluoric acid (HFA) was also evaluated as an alternative reagent to GOM106. HFA has been used extensively for cleaning mild and low'alloy steel boiler tubes in fossil-fired plant in the UK and elsewhere in Europe and is known to remove oxide quickly. Waste treatment is also easier than for the GOM106 process and some protection against damage to the boiler tube materials is provided by complexing of fluoride with ferric ion. Validation of the potential reagents and inhibitors was achieved by assessing the rate and effectiveness of oxide removal from specimens of helical boiler tubing and welds, together with establishing the extent of any metal loss or localised damage. The initial materials testing resulted in the inhibited ammoniated citric / formic acid reagent being

  13. CFD modeling of a boiler's tubes rupture

    International Nuclear Information System (INIS)

    This paper reports the results of a study on the reason for tubes damage in the superheater Platen section of the 320 MW Bisotoun power plant, Iran. The boiler has three types of superheater tubes and the damage occurs in a series of elbows belongs to the long tubes. A three-dimensional modeling was performed using an in-house computational fluid dynamics (CFD) code in order to explore the reason. The code has ability of simultaneous solving of the continuity, the Reynolds-Averaged Navier-Stokes (RANS) equations and employing the turbulence, combustion and radiation models. The whole boiler including; walls, burners, air channels, three types of tubes, etc., was modeled in the real scale. The boiler was meshed into almost 2,000,000 tetrahedral control volumes and the standard k-ε turbulence model and the Rosseland radiation model were used in the model. The theoretical results showed that the inlet 18.9 MPa saturated steam becomes superheated inside the tubes and exit at a pressure of 17.8 MPa. The predicted results showed that the temperature of the steam and tube's wall in the long tubes is higher than the short and medium size tubes. In addition, the predicted steam mass flow rate in the long tube was lower than other ones. Therefore, it was concluded that the main reason for the rupture in the long tubes elbow is changing of the tube's metal microstructure due to working in a temperature higher than the design temperature. In addition, the structural fatigue tension makes the last elbow of the long tube more ready for rupture in comparison with the other places. The concluded result was validated by observations from the photomicrograph of the tube's metal samples taken from the damaged and undamaged sections

  14. Corrosion and anticorrosion. Industrial practice

    International Nuclear Information System (INIS)

    This book comprises 14 chapters written with the collaboration of about 50 French experts of corrosion. It is complementary to another volume entitled 'corrosion of metals and alloys' and published by the same editor. This volume comprises two parts: part 1 presents the basic notions of corrosion phenomena, the properties of surfaces, the electrochemical properties of corrosion etc.. Part 2 describes the most frequent forms of corrosion encountered in industrial environments and corresponding to specific problems of protection: marine environment, atmospheric corrosion, galvanic corrosion, tribo-corrosion, stress corrosion etc.. The first 8 chapters (part 1) treat of the corrosion problems encountered in different industries and processes: oil and gas production, chemical industry, phosphoric acid industry, PWR-type power plants, corrosion of automobile vehicles, civil engineering and buildings, corrosion of biomaterials, non-destructive testing for the monitoring of corrosion. The other chapters (part 2) deal with anticorrosion and protective coatings and means: choice of materials, coatings and surface treatments, thick organic coatings and enamels, paints, corrosion inhibitors and cathodic protection. (J.S.)

  15. Nuclear reactors with auxiliary boiler circuit

    International Nuclear Information System (INIS)

    A gas-cooled nuclear reactor has a main circulatory system for the gaseous coolant incorporating one or more main energy converting units, such as gas turbines, and an auxiliary circulatory system for the gaseous coolant incorporating at least one steam generating boiler arranged to be heated by the coolant after its passage through the reactor core to provide steam for driving an auxiliary steam turbine, such an arrangement providing a simplified start-up procedure also providing emergency duties associated with long term heat removal on reactor shut down

  16. Control Properties of Bottom Fired Marine Boilers

    OpenAIRE

    Solberg, Brian; Andersen, Palle; Karstensen, Claus M. S.

    2005-01-01

    This paper focuses on model analysis of a dynamic model of a bottom fired one-pass smoke tube boiler. Linearised versions of the model are analysed to determine how gain, time constants and right half plane zeros (caused by the shrink-and-swell phenomenon) depend on the steam flow load. Furthermore the interactions in the system are inspected to analyse potential benefit from using a multivariable control strategy in favour of the current strategy based on single loop theory. An analysis of t...

  17. Selecting Actuator Configuration for a Benson Boiler

    DEFF Research Database (Denmark)

    Kragelund, Martin Nygaard; Leth, John-Josef; Wisniewski, Rafal

    2009-01-01

    This paper addresses the problem of an optimal actuator configuration in an economic perspective. The objective is to minimize the economical cost of operating a given plant. Functionals encapsulating information of the business objectives given the different actuators has been established...... with particular focus on a boiler in a power plant operated by DONG Energy - a Danish energy supplier. The problem has been reformulated using mathematic notions from economics. The selection of actuator configuration has been limited to the fuel system which in the considered plant consists of three different...

  18. Reactive leaching of recovery boiler fly ash

    OpenAIRE

    Frigård, Antti

    2016-01-01

    This thesis studied a new CaO leaching method for chloride and potassium removal from recovery boiler fly ash. The concept of this method is to use calcium oxide (or calcium hydroxide) as an additive in the leaching stage in order to ease the subsequent solid-liquid separation. CaO leaching has several benefits over traditional leaching process which uses sulphuric acid as an additive: CaO does not include sulphur that would affect the mills sulphur sodium balance, CaO is readily available in...

  19. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    International Nuclear Information System (INIS)

    The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO(sub 3) and ammonia. During this reporting quarter, installation of a flue gas conditioning system was completed at PacifiCorp Jim Bridger Power Plant. Performance testing was underway. Results will be detailed in the next quarterly and subsequent technical summary reports. Also in this quarter, discussions were initiated with a prospective long-term candidate plant. This plant fires a bituminous coal and has opacity performance issues related to fly ash re-entrainment. Ammonia conditioning has been proposed here, but there is interest in liquid additives as a safer alternative

  20. Thermomechanical finite element analysis of hot water boiler structure

    Directory of Open Access Journals (Sweden)

    Živković Dragoljub S.

    2012-01-01

    Full Text Available The paper presents an application of the Finite Elements Method for stress and strain analysis of the hot water boiler structure. The aim of the research was to investigate the influence of the boiler scale on the thermal stresses and strains of the structure of hot water boilers. Results show that maximum thermal stresses appear in the zone of the pipe carrying wall of the first reversing chamber. This indicates that the most critical part of the boiler are weld spots of the smoke pipes and pipe carrying plate, which in the case of significant scale deposits can lead to cracks in the welds and water leakage from the boiler. The nonlinear effects were taken into account by defining the bilinear isotropic hardening model for all boiler elements. Temperature dependency was defined for all relevant material properties, i. e. isotropic coefficient of thermal expansion, Young’s modulus, and isotropic thermal conductivity. The verification of the FEA model was performed by comparing the measured deformations of the hot water boiler with the simulation results. As a reference object, a Viessmann - Vitomax 200 HW boiler was used, with the installed power of 18.2 MW. CAD modeling was done within the Autodesk Inventor, and stress and strain analysis was performed in the ANSYS Software.

  1. Assessment of the candidate markets for liquid boiler fuels

    Energy Technology Data Exchange (ETDEWEB)

    None

    1979-12-01

    Liquid fuels can be produced from coal in a number of indirect and direct liquefaction processes. While indirect coal liquefaction has been proved commercially outside the United States, most attention in this country has focused on the direct liquefaction processes, which include the processes under examination in this report; namely, the Exxon Donor Solvent (EDS), the H-Coal, and the Solvent Refined Coal (SRC) II processes. The objectives of the study were to: compare the boiler fuels of direct coal liquefaction with residual fuel oil (No. 6 fuel oil) including physical characteristics and environmental hazards, such as carcinogenic characteristics and toxic hazard characteristics; determine whether a boiler fuel market would exist for the coal liquefaction products given their physical characteristics and potential environmental hazards; determine the advantages of utilizing methanol as a boiler fuel on a continuous basis in commercial boilers utilizing existing technology; identify the potential regional candidate markets for direct coal liquefaction products as liquid boiler fuels; determine the distributing and handling costs associated with marketing coal liquefaction products as liquid boiler fuels; determine the current regulatory issues associated with the marketing of coal liquefaction products as boiler fuels; and determine and evaluate other institutional issues associated with the marketing of direct coal liquefaction products as boiler fuels.

  2. DESIGN REPORT LOW-NOX BURNERS FOR PACKAGE BOILERS

    Science.gov (United States)

    The report describes a low-NOx burner design, presented for residual-oil-fired industrial boilers and boilers cofiring conventional fuels and nitrated hazardous wastes. The burner offers lower NOx emission levels for these applications than conventional commercial burners. The bu...

  3. DESIGN REPORT: LOW-NOX BURNERS FOR PACKAGE BOILERS

    Science.gov (United States)

    The report describes a low-NOx burner design, presented for residual-oil-fired industrial boilers and boilers cofiring conventional fuels and nitrated hazardous wastes. The burner offers lower NOx emission levels for these applications than conventional commercial burners. The bu...

  4. NOX EMISSION FACTORS FOR WOOD-FIRED BOILERS

    Science.gov (United States)

    The report gives results of a review of NOx emission data from 14 wood-fired boilers. Types of wood used as fuel included sawdust, chips, shavings, edgings, bark, and other processing residues. Boilers tested ranged in size from 1.5 to 67 MW (4,500 to 200,000 lb steam/hr). The ma...

  5. Quality assurance in fabrication of boilers and pressure vessels

    International Nuclear Information System (INIS)

    Quality assurance for safety and reliability of boilers and pressure vessels is a systematic approach involving various stages right from material identification to final stages of testing, transportation and storage before commissioning. This paper brings out various quality . Assurance aspects to be implemented by manufacturers of boilers and pressure vessels. 1 fig

  6. Water Boiler Change-Over in Mini-TPP Mode

    OpenAIRE

    B. A. Bayrashevsky

    2014-01-01

    The paper considers water boiler modernization by its change-over in mini-TPP mode with an expansion tank and a heating turbine of small capacity.  A software complex permitting to evaluate competitive ability of such water boiler modernization in comparison with a cogeneration plant.

  7. CFD investigation of flow through internally riffled boiler tubes

    DEFF Research Database (Denmark)

    Rasmussen, Christian; Houbak, Niels; Sørensen, Jens Nørkær

    1997-01-01

    In this paper we show how to model the swirling flow in an internally riffled boiler tube. The flow field is visualized and the results are compared with measurements.......In this paper we show how to model the swirling flow in an internally riffled boiler tube. The flow field is visualized and the results are compared with measurements....

  8. Water Boiler Change-Over in Mini-TPP Mode

    Directory of Open Access Journals (Sweden)

    B. A. Bayrashevsky

    2014-08-01

    Full Text Available The paper considers water boiler modernization by its change-over in mini-TPP mode with an expansion tank and a heating turbine of small capacity.  A software complex permitting to evaluate competitive ability of such water boiler modernization in comparison with a cogeneration plant.

  9. Solved and unsolved problems in boiler systems. Learning from accidents

    International Nuclear Information System (INIS)

    This paper begins with a brief review on the similarity law of conventional fossil-fuel-fired boilers. The concept is based on the fact that the heat release due to combustion in the furnace is restricted by the furnace volume but the heat absorption is restricted by the heat transfer surface area. This means that a small-capacity boiler has relatively high specific furnace heat release rate, about 10 MW/m3, and on the contrary a large-capacity boiler has lower value. The surface-heat-flux limit is mainly dominated by the CHF inside the water-wall tubes of the boiler furnace, about 350 kW/m2. This heat-flux limit is almost the same order independently on the capacity of boilers. For the safety of water-walls, it is essential to retain suitable water circulation, i.e. circulation ratio and velocity of water. This principle is a common knowledge of boiler designer, but actual situation is not the case. Newly designed boilers often suffer from similar accidents, especially burnout due to circulation problems. This paper demonstrates recent accidents encountered in practical boilers, and raises problems of rather classical but important two-phase flow and heat transfer. (author)

  10. Potential applications of renewable energy sources, biomass combustion problems in boiler power systems and combustion related environmental issues

    International Nuclear Information System (INIS)

    This paper describes the potential applications of renewable energy sources to replace fossil fuel combustion as the prime energy sources in various countries, and discusses problems associated with biomass combustion in boiler power systems. Here, the term biomass includes organic matter produced as a result of photosynthesis as well as municipal, industrial and animal waste material. Brief summaries of the basic concepts involved in the combustion of biomass fuels are presented. Renewable energy sources (RES) supply 14% of the total world energy demand. RES are biomass, hydropower, geothermal, solar, wind and marine energies. The renewables are the primary, domestic and clean or inexhaustible energy resources. The percentage share of biomass was 62.1% of total renewable energy sources in 1995. Experimental results for a large variety of biomass fuels and conditions are presented. Numerical studies are also discussed. Biomass is an attractive renewable fuel in utility boilers. The compositions of biomass among fuel types are variable. Ash composition for the biomass is fundamentally different from ash composition for the coal. Especially inorganic constituents cause to critical problems of toxic emissions, fouling and slagging. Metals in ash, in combination with other fuel elements such as silica and sulfur, and facilitated by the presence of chlorine, are responsible for many undesirable reactions in combustion furnaces and power boilers. Elements including K, Na, S, Cl, P, Ca, Mg, Fe, Si are involved in reactions leading to ash fouling and slagging in biomass combustors. Chlorine in the biomass may affect operation by corrosion. Ash deposits reduce heat transfer and may also result in severe corrosion at high temperatures. Other influences of biomass composition are observed for the rates of combustion and pollutant emissions. Biomass combustion systems are non-polluting and offer significant protection of the environment. The reduction of greenhouse gases

  11. Quarterly coal report, July--September 1998

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-02-01

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. This report presents detailed quarterly data for July through September 1998 and aggregated quarterly historical data for 1992 through the second quarter of 1998. 58 tabs.

  12. Coal Ash Corrosion Resistant Materials Testing

    Energy Technology Data Exchange (ETDEWEB)

    D. K. McDonald; P. L. Daniel; D. J. DeVault

    2007-12-31

    In April 1999, three identical superheater test sections were installed into the Niles Unit No.1 for the purpose of testing and ranking the coal ash corrosion resistance of candidate superheater alloys. The Niles boiler burns high sulfur coal (3% to 3.5%) that has a moderate alkali content (0.2% sodium equivalents), thus the constituents necessary for coal ash corrosion are present in the ash. The test sections were controlled to operate with an average surface metal temperature from approximately 1060 F to 1210 F which was within the temperature range over which coal ash corrosion occurs. Thus, this combination of aggressive environment and high temperature was appropriate for testing the performance of candidate corrosion-resistant tube materials. Analyses of the deposit and scale confirmed that aggressive alkali sulfate constituents were present at the metal surface and active in tube metal wastage. The test sections were constructed so that the response of twelve different candidate tube and/or coating materials could be studied. The plan was to remove and evaluate one of the three test sections at time intervals of 1 year, 3 years, and 5 years. This would permit an assessment of performance of the candidate materials as a function of time. Test Section A was removed in November 2001 after about 24 months of service at the desired steam temperature set point, with about 15.5 months of exposure at full temperature. A progress report, issued in October 2002, was written to document the performance of the candidate alloys in that test section. The evaluation described the condition of each tube sample after exposure. It involved a determination of the rate of wall thickness loss for these samples. In cases where there was more than one sample of a candidate material in the test section, an assessment was made of the performance of the alloy as a function of temperature. Test Sections B and C were examined during the November 2001 outage, and it was decided that

  13. First quarter 2005 sales data

    International Nuclear Information System (INIS)

    This press release brings information on the AREVA group sales data. First quarter 2005 sales for the group were 2,496 millions of euros, up 3,6% year-on-year from 2,41 millions. The change in foreign exchange rates between the two periods show a negative impact of 22 millions euros, which is much lower than in the first quarter of 2004. It analyzes also in more details the situation of the front end, the reactors and service division, the back end division, the transmission and distribution division and the connectors division. (A.L.B.)

  14. The structure and behavior of salts in kraft recovery boilers

    Energy Technology Data Exchange (ETDEWEB)

    Backman, R.; Badoi, R.D.; Enestam, S. [Aabo Akademi Univ., Turku (Finland). Combustion Chemistry Research Group

    1997-10-01

    The melting behavior in the salt system (Na,K)(CO{sub 3},SO{sub 4},S,Cl,OH) is investigated by laboratory methods to enhance and further develop a chemical model for salt mixtures with compositions relevant for recovery boilers. The model, based on both literature data and experimental work can be used as (a) submodel in models for the over-all chemistry in recovery boilers and to estimate (b) deposit formation on heat transfer surfaces (fouling), (c) the melting properties of the fly ash, and (d) the smelt bed in recovery boilers. Experimental techniques used are thermal analysis, high temperature microscopy` and scanning electron microscopy. The model is implemented in a global calculation model which can handle both gas phases and condensed phases in the recovery boiler. The model gives a detailed description of the chemical reactions involved in the fume and dust formation in different locations of the flue gas channel in the boiler. (orig.)

  15. 10 CFR 34.29 - Quarterly inventory.

    Science.gov (United States)

    2010-01-01

    ... 10 Energy 1 2010-01-01 2010-01-01 false Quarterly inventory. 34.29 Section 34.29 Energy NUCLEAR... RADIOGRAPHIC OPERATIONS Equipment § 34.29 Quarterly inventory. (a) Each licensee shall conduct a quarterly physical inventory to account for all sealed sources and for devices containing depleted uranium...

  16. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report No. 4

    Energy Technology Data Exchange (ETDEWEB)

    Smit, F.J.; Hogsett, R.F.; Jha, M.C.

    1993-11-04

    This project is a major step in the Department of Energy`s program to show that ultra-clean coal-water slurry fuel (CWF) can be produced from selected coals and that this premium fuel will be a cost-effective replacement for oil and natural gas now fueling some of the industrial and utility boilers in the United States. The replacement of oil and gas with CWF can only be realized if retrofit costs are kept to a minimum and retrofit boiler emissions meet national goals for clean air. These concerns establish the specifications for maximum ash and sulfur levels and combustion properties of the CWF. This cost-share contract is a 48-month program which started on September 30, 1992. This report discusses the technical progress made during the 4th quarter of the project from July 1 to September 30, 1993.

  17. Short-term energy outlook: Quarterly projections, Third quarter 1992

    International Nuclear Information System (INIS)

    The Energy Information Administration (EIA) prepares quarterly, short-term energy supply, demand, and price projections for publication in February, May, August, and November in the Short-Term Energy Outlook (Outlook). An annual supplement analyzes the performance of previous forecasts, compares recent cases with those of other forecasting services, and discusses current topics related to the short-term energy markets. (See Short-Term Energy Outlook Annual Supplement, DOE/EIA-0202.) The principal users of the Outlook are managers and energy analysts in private industry and government. The forecast period for this issue of the Outlook extends from the third quarter of 1992 through the fourth quarter of 1993. Values for the second quarter of 1992, however, are preliminary EIA estimates (for example, some monthly values for petroleum supply and disposition are derived in part from weekly data reported in the Weekly Petroleum Status Report) or are calculated from model simulations using the latest exogenous information available (for example, electricity sales and generation are simulated using actual weather data). The historical energy data are EIA data published in the Monthly Energy Review, Petroleum Supply Monthly, and other EIA publications. Minor discrepancies between the data in these publications and the historical data in this Outlook are due to independent rounding

  18. Short-term energy outlook, Quarterly projections. Third quarter 1993

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1993-08-04

    The Energy Information Administration (EIA) prepares quarterly, short-term energy supply, demand, and price projections for publication in February, May, August, and November in the Short-Term Energy Outlook (Outlook). An annual supplement analyzes the performance of previous forecasts, compares recent cases with those of other forecasting services, and discusses current topics related to the short-term energy markets. (See Short-Term Energy Outlook Annual Supplement, DOE/EIA-0202.) The forecast period for this issue of the Outlook extends from the third quarter of 1993 through the fourth quarter of 1994. Values for the second quarter of 1993, however, are preliminary EIA estimates (for example, some monthly values for petroleum supply and disposition are derived in part from weekly data reported in the Weekly Petroleum Status Report) or are calculated from model simulations using the latest exogenous information available (for example, electricity sales and generation are simulated using actual weather data). The historical energy data are EIA data published in the Monthly Energy Review, Petroleum Supply Monthly, and other EIA publications. Minor discrepancies between the data in these publications and the historical data in this Outlook are due to independent rounding.

  19. Short-term energy outlook, quarterly projections, first quarter 1998

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-01-01

    The forecast period for this issue of the Outlook extends from the first quarter of 1998 through the fourth quarter of 1999. Values for the fourth quarter of 1997, however, are preliminary EIA estimates (for example, some monthly values for petroleum supply and disposition are derived in part from weekly data reported in EIA`s Weekly Petroleum Status Report) or are calculated from model simulations that use the latest exogenous information available (for example, electricity sales and generation are simulated by using actual weather data). The historical energy data, compiled in the first quarter 1998 version of the Short-Term Integrated Forecasting System (STIFS) database, are mostly EIA data regularly published in the Monthly Energy Review, Petroleum Supply Monthly, and other EIA publications. Minor discrepancies between the data in these publications and the historical data in this Outlook are due to independent rounding. The STIFS model is driven principally by three sets of assumptions or inputs: estimates of key macroeconomic variables, world oil price assumptions, and assumptions about the severity of weather. Macroeconomic estimates are adjusted by EIA to reflect EIA assumptions which may affect the macroeconomic outlook. By varying the assumptions, alternative cases are produced by using the STIFS model. 24 figs., 19 tabs.

  20. Applied Meteorology Unit (AMU) Quarterly Report First Quarter FY-04

    Science.gov (United States)

    Bauman, William; Wheeler, Mark; Labert, Winifred; Jonathan Case; Short, David

    2004-01-01

    This report summarizes the Applied Meteorology Unit (AMU) activities for the First Quarter of Fiscal Year 2004 (October - December 2003). Tasks reviewed are: (1) Objective Lightning Probability Forecast, (2) Mesonet Temperature and Wind Climatology, (3) Severe Weather Forecast Decision Aid and (4) Anvil Transparency Relationship to Radar Reflectivity

  1. Short-Term Energy Outlook: Quarterly projections. Fourth quarter 1993

    Energy Technology Data Exchange (ETDEWEB)

    1993-11-05

    The Energy Information Administration (EIA) prepares quarterly, short-term energy supply, demand, and price projections for publication in February, May, August, and November in the Short-Term Energy Outlook (Outlook). An annual supplement analyzes the performance of previous forecasts, compares recent cases with those of other forecasting services, and discusses current topics related to the short-term energy markets. (See Short-Term Energy Outlook Annual Supplement, DOE/EIA-0202.) The forecast period for this issue of the Outlook extends from the fourth quarter of 1993 through the fourth quarter of 1994. Values for the third quarter of 1993, however, are preliminary EIA estimates (for example, some monthly values for petroleum supply and disposition are derived in part from weekly data reported in the Weekly Petroleum Status Report) or are calculated from model simulations using the latest exogenous information available (for example, electricity sales and generation are simulated using actual weather data). The historical energy data are EIA data published in the Monthly Energy Review, Petroleum Supply Monthly, and other EIA publications.

  2. 'Boilers' along the southeast coast of Bermuda

    Science.gov (United States)

    2002-01-01

    Along the south shore of Bermuda, waves break continuously along algal/vermetid reefs (composed of algae and molluscs, not coral), forming 'boilers.' Boilers are named because the continuous breaking of waves makes it look as if the sea is boiling. This photograph taken from the International Space Station shows the eastern half of the main islands of Bermuda. Land use is about 6 percent cropland, 55 percent developed and 34 percent rural. Reflective white-colored areas are buildings and other developments surrounded by green areas of vegetation. St. David's Island is also home to the airport, with runways built out into Castle Harbour. Hurricane Erin passed northeast of Bermuda early on September 10 with 115 mile-per-hour winds (a Category 3 storm on the Saffir-Simpson Scale), but causing very minimal damage. Astronauts aboard Space Station Alpha photographed the area on September 14, 2001. By then, the skies had cleared and Erin had become an extratropical low near Newfoundland. Image ISS003-E-5735, was provided by the Earth Sciences and Image Analysis Laboratory at Johnson Space Center. Additional images taken by astronauts and cosmonauts can be viewed at the NASA-JSC Gateway to Astronaut Photography of Earth.

  3. Investigation of thermal spray coatings on austenitic stainless steel substrate to enhance corrosion protection

    Science.gov (United States)

    Rogers, Daniel M.

    The research is aimed to evaluate thermal spray coatings to address material issues in supercritical and ultra-supercritical Rankine cycles. The primary purpose of the research is to test, evaluate, and eventually implement a coating to improve corrosion resistance and increase efficiency of coal fired power plants. The research is performed as part of a comprehensive project to evaluate the ability of titanium, titanium carbide, or titanium diboride powders to provide fireside corrosion resistance in supercritical and ultra-supercritical steam boilers, specifically, coal driven boilers in Illinois that must utilize high sulfur and high chlorine content coal. [1] The powder coatings that were tested are nano-sized titanium carbide (TiC) and titanium di-boride (TiB2) powders that were synthesized by a patented process at Southern Illinois University. The powders were then sent to Gas Technology Institute in Chicago to coat steel coupons by HVOF (High Velocity Oxy-Fuel) thermal spray technique. The powders were coated on an austenitic 304H stainless steel substrate which is commonly found in high temperature boilers, pipelines, and heat exchangers. The samples then went through various tests for various lengths of time under subcritical, supercritical, and ultra-supercritical conditions. The samples were examined using a scanning electron microscope and x-ray diffraction techniques to study microstructural changes and then determined which coating performed best.

  4. Monitoring corrosion rates and localised corrosion in low conductivity water

    DEFF Research Database (Denmark)

    Hilbert, Lisbeth Rischel

    2006-01-01

    Monitoring of low corrosion rates and localised corrosion in a media with low conductivity is a challenge. In municipal district heating, quality control may be improved by implementing on-line corrosion monitoring if a suitable technique can be identified to measure both uniform and localised...

  5. Quarterly coal report, April--June, 1998

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-11-01

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. This report presents detailed quarterly data for April through June 1998 and aggregated quarterly historical data for 1992 through the first quarter of 1998. Appendix A displays, from 1992 on, detailed quarterly historical coal imports data. 58 tabs.

  6. Quarterly coal report, October--December 1996

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-05-01

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. This report presents detailed quarterly data for October through December 1996 and aggregated quarterly historical data for 1990 through the third quarter of 1996. Appendix A displays, from 1988 on, detailed quarterly historical coal imports data. To provide a complete picture of coal supply and demand in the US, historical information has been integrated in this report. 8 figs., 72 tabs.

  7. Quarterly coal report, January--March 1998

    Energy Technology Data Exchange (ETDEWEB)

    Young, P.

    1998-08-01

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. This report presents detailed quarterly data for January through March 1998 and aggregated quarterly historical data for 1992 through the fourth quarter of 1997. Appendix A displays, from 1992 on, detailed quarterly historical coal imports data. To provide a complete picture of coal supply and demand in the United States, historical information has been integrated in this report. 58 tabs.

  8. Quarterly coal report, October--December 1998

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-07-01

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. This report presents detailed quarterly data for October through December 1998 and aggregated quarterly historical data for 1992 through the third quarter of 1998. Appendix A displays, from 1992 on, detailed quarterly historical coal imports data. 58 tabs.

  9. Energy supply the 4th quarter and the whole years 2001 and 2002. Preliminary data

    International Nuclear Information System (INIS)

    The final consumption of energy in Sweden the 4th quarter 2002 increased by 8 per cent compared to the corresponding period 2001, from 106 TWh to 114 TWh. The consumption within industrial sector and transport sector increased by 3 per cent each and household sector increased by 14 per cent. The energy consumption during 2002 was 400 TWh, which is an increase by 1 per cent since 2001 when the consumption was 394 TWh. The consumption in industry sector rose by 3 per cent, which can be explained by an increase of using district heating. This quarter has the use increased from 6.0 PJ to 8.9 PJ which responds to an 48 per cent increase. It is the rising activity with ready made heat that explains this figures. Ready made heat is when the energy sector runs the boilers that used to belong to the industries. The fuel input, of for instance biomass fuel, could earlier be found within industry whereas nowadays the fuel input is within the energy sector. The gross supply of energy in Sweden the 4th quarter 2002 increased by 7 per cent compared to the 4th quarter 2001. The production of electricity from nuclear plants was 5 per cent lower compared with the same quarter 2001. Hydroelectric power production decreased by 29 per cent during the same period. The supply of natural gas rose by 17 per cent and the supply of domestic fuels rose by 13 per cent. The supply of coal and coke increased by 14 per cent and there was an 17 per cent increase in the supply of oil products. The total gross supply of energy was unchanged during 2002 compared with 2001. But we can see an increase in the supply of coal and coke, 4 per cent, domestic fuels, 5 per cent, oil products, 3 per cent and district heating, 4 per cent

  10. Equine disease surveillance: quarterly summary.

    Science.gov (United States)

    2016-05-14

    Multiple reports of equine herpesvirus type 1 in the UKFirst cases of dourine in Botswana and equine infectious anaemia in GreeceSummary of UK surveillance testing, October to December 2015These are among matters discussed in the most recent quarterly equine disease surveillance report, prepared by Defra, the Animal Health Trust and the British Equine Veterinary Association. PMID:27179087

  11. Indonesia Economic Quarterly FY13

    OpenAIRE

    World Bank

    2013-01-01

    The Indonesia economic quarterly reports on and synthesizes the past three months key developments in Indonesia s economy. It places them in a longer-term and global context, and assesses the implications of these developments and other changes in policy for the outlook for Indonesia s economic and social welfare. Its coverage ranges from the macroeconomy to financial markets to indicators of ...

  12. Equine disease surveillance: quarterly summary.

    Science.gov (United States)

    2016-07-30

    National and international disease outbreaksAfrican horse sickness in South AfricaRising EHV-1 abortion cases in the UKSummary of surveillance testing, January to March 2016 These are among matters discussed in the most recent quarterly equine disease surveillance report, prepared by Defra, the Animal Health Trust and the British Equine Veterinary Association. PMID:27474057

  13. NST Quarterly. January 1996 issue

    International Nuclear Information System (INIS)

    NST Quarterly reports current development in Nuclear Science and Technology in Malaysia. In this issue it highlights MINT activities in nuclear medicine, healthcare products sterilization, industrial irradiation dosimetry and heavy metals determination in food. The Malaysian standard for food irradiation was discussed in this issue

  14. Microbial Corrosion: 1988 Workshop Proceedings

    Energy Technology Data Exchange (ETDEWEB)

    None

    1989-04-01

    Microbial action can greatly increase corrosion damage in power plant water systems. This workshop pulled together practical experience and theoretical knowledge on microbially induced corrosion, documented diagnostic and treatment methods, and identified areas for future research.

  15. Severe Environmental Corrosion Erosion Facility

    Data.gov (United States)

    Federal Laboratory Consortium — NETL’s Severe Environment Corrosion Erosion Facility in Albany, OR, allows researchers to safely examine the performance of materials in highly corrosive or erosive...

  16. Substantiation of causes for damage of water-wall tubes of an external salt compartment of a high-pressure boiler

    Science.gov (United States)

    Fedorov, A. I.

    2014-10-01

    The damageability for water-wall tubes of an external salt compartment of a TPE-208 boiler is analyzed. The general cause for tube damage is the intensive underslime corrosion of the inner surface, which is caused by a local increase in the salt concentration in boiler water. The experiment-calculated method showed that continuous bleeding from an external cyclone being the first in water downstream causes a substantial increase in the concentration of salts (more than by a factor of three) and scale-forming agents within a contour of the loop of a distant cyclone in comparison with the variant of bleeding from a loop being the second in water downstream.

  17. Plastics for corrosion inhibition

    CERN Document Server

    Goldade, Victor A; Makarevich, Anna V; Kestelman, Vladimir N

    2005-01-01

    The development of polymer composites containing inhibitors of metal corrosion is an important endeavour in modern materials science and technology. Corrosion inhibitors can be located in a polymer matrix in the solid, liquid or gaseous phase. This book details the thermodynamic principles for selecting these components, their compatibility and their effectiveness. The various mechanisms of metal protection – barrier, inhibiting and electromechanical – are considered, as are the conflicting requirements placed on the structure of the combined material. Two main classes of inhibited materials (structural and films/coatings) are described in detail. Examples are given of structural plastics used in friction units subjected to mechano-chemical wear and of polymer films/coatings for protecting metal objects against corrosion.

  18. Atmospheric corrosion of mild steel

    OpenAIRE

    Morcillo, Manuel; Fuente, Daniel de la; Díaz Ocaña, Iván; Cano, Heidis

    2011-01-01

    The atmospheric corrosion of mild steel is an extensive topic that has been studied by many authors in different regions throughout the world. This compilation paper incorporates relevant publications on the subject, in particular about the nature of atmospheric corrosion products, mechanisms of atmospheric corrosion and kinetics of the atmospheric corrosion process, paying special attention to two matters upon which relatively less information has been published: a) the morpholog...

  19. Atmospheric corrosion of mild steel

    OpenAIRE

    Morcillo, M.; de la Fuente, D.; I. Díaz; Cano, H.

    2011-01-01

    The atmospheric corrosion of mild steel is an extensive topic that has been studied by many authors in different regions throughout the world. This compilation paper incorporates relevant publications on the subject, in particular about the nature of atmospheric corrosion products, mechanisms of atmospheric corrosion and kinetics of the atmospheric corrosion process, paying special attention to two matters upon which relatively less information has been published: a) the morphology of steel c...

  20. Corrosion-resistant metal surfaces

    Science.gov (United States)

    Sugama, Toshifumi

    2009-03-24

    The present invention relates to metal surfaces having thereon an ultrathin (e.g., less than ten nanometer thickness) corrosion-resistant film, thereby rendering the metal surfaces corrosion-resistant. The corrosion-resistant film includes an at least partially crosslinked amido-functionalized silanol component in combination with rare-earth metal oxide nanoparticles. The invention also relates to methods for producing such corrosion-resistant films.

  1. Thermographic detection and quantitative characterization of corrosion by application of thermal line source

    Science.gov (United States)

    Cramer, K. Elliott; Winfree, William P.; Reid, Dan; Johnson, Jane

    1999-02-01

    Wall thinning in utility boiler waterwall tubing is a significant inspection concern for boiler operators. Historically, conventional ultrasonics has been used for inspection of these tubes. This technique has proved to be very labor intensive and slow. This has resulted in a `spot check' approach to inspections, making thickness measurements over a relatively small percentage of the total boiler wall area. NASA Langley Research Center has developed a thermal NDE technique designed to image and quantitatively characterize the amount of material thinning present in steel tubing. The technique involves the movement of a thermal line source across the outer surface of the tubing followed by an infrared imager at a fixed distance behind the line source. Quantitative images of the material loss due to corrosion are reconstructed from measurements of the induced surface temperature variations. This paper will present a discussion of the development of the thermal imaging system as well as the techniques used to reconstruct images of flaws. The application of the thermal line source, coupled with this analysis technique, represents a significant improvement in the inspection speed for large structures such as boiler waterwalls while still providing high-resolution thickness measurements. A theoretical basis for the technique will be presented thus demonstrating the quantitative nature of the technique. Further, results of laboratory experiments on flat panel specimens with fabricated material loss regions will be presented to demonstrate the capabilities of the technique. Additionally, the results of applying this technology to actual waterwall tubing samples will be presented.

  2. 46 CFR 71.15-1 - Standards in inspection of hulls, boilers, and machinery.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 3 2010-10-01 2010-10-01 false Standards in inspection of hulls, boilers, and machinery..., boilers, and machinery. In the inspection of hulls, boilers, and machinery of vessels, the standards... and inspection of hulls, boilers, and machinery, and the certificate of classification...

  3. 46 CFR 189.15-1 - Standards in inspection of hulls, boilers, and machinery.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 7 2010-10-01 2010-10-01 false Standards in inspection of hulls, boilers, and machinery... inspection of hulls, boilers, and machinery. In the inspection of hulls, boilers, and machinery of vessels... chapter, respecting material and construction of hulls, boilers, and machinery, and certificate...

  4. 46 CFR 91.15-1 - Standards in inspection of hulls, boilers, and machinery.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 4 2010-10-01 2010-10-01 false Standards in inspection of hulls, boilers, and machinery... hulls, boilers, and machinery. In the inspection of hulls, boilers, and machinery of vessels, the..., respecting material and inspection of hulls, boilers, and machinery, and the certificate of...

  5. 49 CFR 230.20 - Alteration and repair report for steam locomotive boilers.

    Science.gov (United States)

    2010-10-01

    ... boilers. (a) Alterations. When an alteration is made to a steam locomotive boiler, the steam locomotive... steam locomotive boiler, the steam locomotive owner and/or operator shall file with the FRA Regional... the boiler. Whenever welded or riveted repairs are performed on stayed portions of a steam...

  6. Coal liquefaction. Quarterly report, January--March 1978. [Brief summary of 15 pilot plant projects supported by US DOE

    Energy Technology Data Exchange (ETDEWEB)

    1978-09-01

    The advantage of coal liquefaction is that the entire range of liquid products, including heavy boiler fuel, distillate fuel oil, gasoline, jet fuel, and diesel oil, can be produced from coal by varying the type of process and operating conditions used in the process. Furthermore, coal-derived liquids have the potential for use as chemical feedstocks. To provide efficient and practical means of utilizing coal resources, DOE is sponsoring the development of several conversion processes currently in the pilot plant stage. Fifteen coal liquefaction projects supported by US DOE are described briefly, with flowsheets, funding, history and progress during the quarter. (LTN)

  7. Supercritical boiler material selection using fuzzy analytic network process

    Directory of Open Access Journals (Sweden)

    Saikat Ranjan Maity

    2012-08-01

    Full Text Available The recent development of world is being adversely affected by the scarcity of power and energy. To survive in the next generation, it is thus necessary to explore the non-conventional energy sources and efficiently consume the available sources. For efficient exploitation of the existing energy sources, a great scope lies in the use of Rankin cycle-based thermal power plants. Today, the gross efficiency of Rankin cycle-based thermal power plants is less than 28% which has been increased up to 40% with reheating and regenerative cycles. But, it can be further improved up to 47% by using supercritical power plant technology. Supercritical power plants use supercritical boilers which are able to withstand a very high temperature (650-720˚C and pressure (22.1 MPa while producing superheated steam. The thermal efficiency of a supercritical boiler greatly depends on the material of its different components. The supercritical boiler material should possess high creep rupture strength, high thermal conductivity, low thermal expansion, high specific heat and very high temperature withstandability. This paper considers a list of seven supercritical boiler materials whose performance is evaluated based on seven pivotal criteria. Given the intricacy and difficulty of this supercritical boiler material selection problem having interactions and interdependencies between different criteria, this paper applies fuzzy analytic network process to select the most appropriate material for a supercritical boiler. Rene 41 is the best supercritical boiler material, whereas, Haynes 230 is the worst preferred choice.

  8. Evaluation of conditions of SNCR in small boilers

    International Nuclear Information System (INIS)

    The report describes the first part of a project 'SNCR for small boilers', supported by Vaermeforsk (Thermal Engineering Research Institute), with the purpose of assessing the potential for SNCR in small boilers. Given favourable conditions, the project was to be continued in a second part with the demonstration of a SNCR system in a small boiler (or several boilers). During the base establishment, the temperatures in four locations per boiler, in a couple of horizontal or vertical levels and at 2-3 thermal outputs, were measured. Out of the four locations two showed temperatures mainly within the theoretical temperature window for SNCR. These locations were used during the try-out tests to inject urea and ammonia. The locations and the equipment used during the try-out tests together with existing operation strategies seem to limit the reduction levels to approximately 10-20% at acceptable levels of ammonia slip. The measurements and try-out tests carried out does not provide enough basis for forming any general conclusions concerning SNCR in small boilers. Neither the base establishment nor the try-out tests included any optimisation of the boilers regarding the operation strategy or, for the try-out tests, locations and equipment (drop size, flow shape and direction). Therefore, it is likely to believe that better results can be obtained, given other conditions of operation and using well established SNCR technology, adapted to the circumstances. 2 refs, 27 figs, 5 tabs

  9. Modeling operation mode of pellet boilers for residential heating

    International Nuclear Information System (INIS)

    In recent years the consumption of wood pellets as energy source for residential heating lias increased, not only as fuel for stoves, but also for small-scale residential boilers that, produce hot water used for both space heating and domestic hot water. Reduction of fuel consumption and pollutant emissions (CO, dust., HC) is an obvious target of wood pellet boiler manufacturers, however they are also quite interested in producing low- maintenance appliances. The need of frequent maintenance turns in higher operating costs and inconvenience for the user, and in lower boiler efficiency and higher emissions also. The aim of this paper is to present a theoretical model able to simulate the dynamic behavior of a pellet boiler. The model takes into account many features of real pellet boilers. Furthermore, with this model, it is possible to pay more attention to the influence of the boiler control strategy. Control strategy evaluation is based not only on pellet consumption and on total emissions, but also on critical operating conditions such as start-up and stop or prolonged operation at substantially reduced power level. Results are obtained for a residential heating system based on a wood pellet boiler coupled with a thermal energy storage. Results obtained so far show a weak dependence of performance in terms of fuel consumption and total emissions on control strategy, however some control strategies present some critical issues regarding maintenance frequency

  10. MSWI Boiler Ashes: Production and Quality Through the Horizontal Section of a Boiler

    DEFF Research Database (Denmark)

    Allegrini, Elisa; Boldrin, Alessio; Astrup, Thomas Fruergaard

    SUMMARY: the central role of waste-to-energy (WtE) plants in Denmark asks for a deep knowledge of all different residues produced by these facilities. The main objective of solid residues characterization is the optimization of their management system. In this study we present the results of the...... first phase of a wider study about the solid residues produced at the heat recovery system (boiler) of a waste incineration plant. The characterization was carried out not on the total output of the boiler but on the different solid residues produced at ten different horizontal sections. The aim was to...... characterize the different streams in order to identify differences that can justify potentially different utilization/disposal options. First results showed differences between sections in terms of chemical composition, leaching behavior and content of dioxins, but additional results are needed to cope with...

  11. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    Energy Technology Data Exchange (ETDEWEB)

    R. Viswanathan; K. Coleman

    2002-10-15

    The principal objective of this project is to develop materials technology for use in ultrasupercritical (USC) plant boilers capable of operating with 760 C (1400 F), 35 MPa (5000 psi) steam. In the 21st century, the world faces the critical challenge of providing abundant, cheap electricity to meet the needs of a growing global population while at the same time preserving environmental values. Most studies of this issue conclude that a robust portfolio of generation technologies and fuels should be developed to assure that the United States will have adequate electricity supplies in a variety of possible future scenarios. The use of coal for electricity generation poses a unique set of challenges. On the one hand, coal is plentiful and available at low cost in much of the world, notably in the U.S., China, and India. Countries with large coal reserves will want to develop them to foster economic growth and energy security. On the other hand, traditional methods of coal combustion emit pollutants and CO{sub 2} at high levels relative to other generation options. Maintaining coal as a generation option in the 21st century will require methods for addressing these environmental issues. This project has established a government/industry consortium to undertake a five-year effort to evaluate and develop of advanced materials that allow the use of advanced steam cycles in coal-based power plants. These advanced cycles, with steam temperatures up to 760 C, will increase the efficiency of coal-fired boilers from an average of 35% efficiency (current domestic fleet) to 47% (HHV). This efficiency increase will enable coal-fired power plants to generate electricity at competitive rates (irrespective of fuel costs) while reducing CO{sub 2} and other fuel-related emissions by as much as 29%. Success in achieving these objectives will support a number of broader goals. First, from a national prospective, the program will identify advanced materials that will make it possible to

  12. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    Energy Technology Data Exchange (ETDEWEB)

    R. Viswanathan; K. Coleman

    2003-01-20

    The principal objective of this project is to develop materials technology for use in ultrasupercritical (USC) plant boilers capable of operating with 760 C (1400 F), 35 MPa (5000 psi) steam. In the 21st century, the world faces the critical challenge of providing abundant, cheap electricity to meet the needs of a growing global population while at the same time preserving environmental values. Most studies of this issue conclude that a robust portfolio of generation technologies and fuels should be developed to assure that the United States will have adequate electricity supplies in a variety of possible future scenarios. The use of coal for electricity generation poses a unique set of challenges. On the one hand, coal is plentiful and available at low cost in much of the world, notably in the U.S., China, and India. Countries with large coal reserves will want to develop them to foster economic growth and energy security. On the other hand, traditional methods of coal combustion emit pollutants and CO{sub 2} at high levels relative to other generation options. Maintaining coal as a generation option in the 21st century will require methods for addressing these environmental issues. This project has established a government/industry consortium to undertake a five-year effort to evaluate and develop of advanced materials that allow the use of advanced steam cycles in coal-based power plants. These advanced cycles, with steam temperatures up to 760 C, will increase the efficiency of coal-fired boilers from an average of 35% efficiency (current domestic fleet) to 47% (HHV). This efficiency increase will enable coal-fired power plants to generate electricity at competitive rates (irrespective of fuel costs) while reducing CO{sub 2} and other fuel-related emissions by as much as 29%. Success in achieving these objectives will support a number of broader goals. First, from a national prospective, the program will identify advanced materials that will make it possible to

  13. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    Energy Technology Data Exchange (ETDEWEB)

    R. Viswanathan

    2002-04-15

    The principal objective of this project is to develop materials technology for use in ultrasupercritical (USC) plant boilers capable of operating with 760 C (1400 F), and up to 5500 psi with emphasis upon 35 MPa (5000 psi) steam. In the 21st century, the world faces the critical challenge of providing abundant, cheap electricity to meet the needs of a growing global population while at the same time preserving environmental values. Most studies of this issue conclude that a robust portfolio of generation technologies and fuels should be developed to assure that the United States will have adequate electricity supplies in a variety of possible future scenarios. The use of coal for electricity generation poses a unique set of challenges. On the one hand, coal is plentiful and available at low cost in much of the world, notably in the U.S., China, and India. Countries with large coal reserves will want to develop them to foster economic growth and energy security. On the other hand, traditional methods of coal combustion emit pollutants and CO{sub 2} at high levels relative to other generation options. Maintaining coal as a generation option in the 21st century will require methods for addressing these environmental issues. This project has established a government/industry consortium to undertake a five-year effort to evaluate and develop advanced materials that allow the use of advanced steam cycles in coal-based power plants. These advanced cycles, with steam temperatures up to 760 C, will increase the efficiency of coal-fired boilers from an average of 35% efficiency (current domestic fleet) to 47% (HHV). This efficiency increase will enable coal-fired power plants to generate electricity at competitive rates (irrespective of fuel costs) while reducing CO{sub 2} and other fuel-related emissions by as much as 29%. Success in achieving these objectives will support a number of broader goals. First, from a national prospective, the program will identify advanced

  14. COAL COMBUSTION EFFICIENCY IN CFB BOILER

    Institute of Scientific and Technical Information of China (English)

    Hairui Yang; Guangxi Yue

    2005-01-01

    The carbon content in the fly ash from most Chinese circulating fluidized bed (CFB) boilers is much higher than expected, thus directly influencing the combustion efficiency. In the present paper, carbon burnout was investigated both in field tests and laboratory experiments. The effect of coal property, operation condition, gas-solid mixing, char deactivation,residence time and cyclone performance are analyzed seriatim based on large amount of experimental results.A coal index is proposed to describe the coal rank, defined by the ratio of the volatile content to the coal heat value, is a useful parameter to analyze the char burnout. The carbon content in the fly ash depends on the coal rank strongly. CFB boilers burning anthracite, which has low coal index, usually have high carbon content in the fly ash. On the contrary, the CFB boilers burning brown coal, which has high coal index, normally have low carbon content.Poor gas-solid mixing in the furnace is another important reason of the higher carbon content in the fly ash. Increasing the velocity and rigidity of the secondary air could extend the penetration depth and induce more oxygen into the furnace center. Better gas solid mixing will decrease the lean oxygen core area and increase char combustion efficiency.The fine char particles could be divided into two groups according to their reactivity. One group is "fresh" char particles with high reactivity and certain amount of volatile content. The other group of char particles has experienced sufficient combustion time both in the furnace and in the cyclone, with nearly no volatile. These "old" chars in the fly ash will be deactivated during combustion of large coal particles and have very low carbon reactivity. The generated fine inert char particles by attrition of large coal particles could not easily burn out even with the fly ash recirculation. The fraction of large coal particles in coal feed should be reduced during fuel preparation process.The cyclone

  15. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    Energy Technology Data Exchange (ETDEWEB)

    R. Viswanathan; K. Coleman

    2002-07-15

    The principal objective of this project is to develop materials technology for use in ultrasupercritical (USC) plant boilers capable of operating with 760 C (1400 F), 35 MPa (5000 psi) steam. In the 21st century, the world faces the critical challenge of providing abundant, cheap electricity to meet the needs of a growing global population while at the same time preserving environmental values. Most studies of this issue conclude that a robust portfolio of generation technologies and fuels should be developed to assure that the United States will have adequate electricity supplies in a variety of possible future scenarios. The use of coal for electricity generation poses a unique set of challenges. On the one hand, coal is plentiful and available at low cost in much of the world, notably in the U.S., China, and India. Countries with large coal reserves will want to develop them to foster economic growth and energy security. On the other hand, traditional methods of coal combustion emit pollutants and CO{sub 2} at high levels relative to other generation options. Maintaining coal as a generation option in the 21st century will require methods for addressing these environmental issues. This project has established a government/industry consortium to undertake a five-year effort to evaluate and develop of advanced materials that allow the use of advanced steam cycles in coal-based power plants. These advanced cycles, with steam temperatures up to 760 C, will increase the efficiency of coal-fired boilers from an average of 35% efficiency (current domestic fleet) to 47% (HHV). This efficiency increase will enable coal-fired power plants to generate electricity at competitive rates (irrespective of fuel costs) while reducing CO{sub 2} and other fuel-related emissions by as much as 29%. Success in achieving these objectives will support a number of broader goals. First, from a national prospective, the program will identify advanced materials that will make it possible to

  16. Corrosion inhibition in the presence of microbial corrosion

    Energy Technology Data Exchange (ETDEWEB)

    Videla, H.A. [Univ. of La Plata (Argentina). Dept. of Chemistry

    1996-12-01

    Microorganisms influence corrosion by changing the electrochemical conditions at the metal/solution interface. These changes may have different effects, ranging from the induction of localized corrosion to corrosion inhibition. The key to the alteration of conditions at a metal surface and hence, the enhancement or inhibition of corrosion is the formation of a biofilm. On a biologically conditioned metal surface microorganisms can induce corrosion inhibition in several ways: (a) by neutralizing the action of a corrosive substance already present in the medium; (b) by stabilizing a protective film on a metal surface or (c) by inducing a decrease in the medium aggressiveness. Seldomly mentioned in the literature, microbial inhibition of corrosion could be a potentially useful tool to counteract many of the biodeterioration cases encountered in practice.

  17. Effect of Li and Cu addition on corrosion of Fe–40 at.% Al intermetallics in molten LiCl–KCl eutectic salt

    International Nuclear Information System (INIS)

    Highlights: ► Identified effect of Li addition on corrosion of Fe–40 at.% Al into molten LiCl–KCl. ► Identified effect of Cu addition on corrosion of Fe–40 at.% Al into molten LiCl–KCl. ► Identified corrosion mechanism of Li addition of Fe–40 at.% Al into molten LiCl–KCl. ► Identified corrosion mechanism of Cu addition of Fe–40 at.% Al into molten LiCl–KCl. ► FeAl intermetallics doped with Li and Cu has great contribution as boiler coating. - Abstract: The effect of Li and Cu addition to base intermetallic Fe–40 at.% Al on corrosion behaviour in an electrolytic medium of molten LiCl–55 wt.% KCl eutectic salt at 450, 500 and 550 °C is studied. For this purpose, an electrochemical assessment is carried out through polarization curves and polarization resistance techniques. Corrosion products are characterized through scanning electron microscope and electron diffraction scanning. The test results show that Li additions slightly increase the corrosion rate, while Cu additions improve the corrosion resistance; both results are compared with the base material resistance. Further, a first approach of the corrosion mechanism is proposed, including the formation of protective layers.

  18. Failure of marine boiler tube: A case history

    Directory of Open Access Journals (Sweden)

    V. A. Dere

    1963-01-01

    Full Text Available An interesting case of marine boiler tube failure is described. As a result of local overheating, a ballooning burst occurred in a boiler tube. Evidence showed that a temperature of over 1600/degree/F (87/degree/C had been reached before rupture. The presence of a thin film of copper arising from the auxiliary equipments of the boiler, caused pittings in the metal. failure was thus attributed to local overheating accelerated by an inner deposit of heat insulating scale.

  19. Modelling transition states of a small once-through boiler

    Energy Technology Data Exchange (ETDEWEB)

    Talonpoika, T. [Lappeenranta Univ. of Technology (Finland). Dept. of Energy Technology

    1997-12-31

    This article presents a model for the unsteady dynamic behaviour of a once-through counter flow boiler that uses an organic working fluid. The boiler is a compact waste-heat boiler without a furnace and it has a preheater, a vaporiser and a superheater. The relative lengths of the boiler parts vary with the operating conditions since they are all parts of a single tube. The boiler model is presented using a selected example case that uses toluene as the process fluid and flue gas from natural gas combustion as the heat source. The dynamic behaviour of the boiler means transition from the steady initial state towards another steady state that corresponds to the changed process conditions. The solution method chosen is to find such a pressure of the process fluid that the mass of the process fluid in the boiler equals the mass calculated using the mass flows into and out of the boiler during a time step, using the finite difference method. A special method of fast calculation of the thermal properties is used, because most of the calculation time is spent in calculating the fluid properties. The boiler is divided into elements. The values of the thermodynamic properties and mass flows are calculated in the nodes that connect the elements. Dynamic behaviour is limited to the process fluid and tube wall, and the heat source is regarded as to be steady. The elements that connect the preheater to the vaporiser and the vaporiser to the superheater are treated in a special way that takes into account a flexible change from one part to the other. The initial state of the boiler is received from a steady process model that is not a part of the boiler model. The known boundary values that may vary during the dynamic calculation were the inlet temperature and mass flow rates of both the heat source fluid and the process fluid. The dynamic boiler model is analysed for linear and step charges of the entering fluid temperatures and flow rates. The heat source side tests show that

  20. Maintenance of immersion ultrasonic testing on the water tube boiler

    International Nuclear Information System (INIS)

    There are 4-boiler in nuclear fuel cycle engineering laboratories (NCL). These boilers have been operated in the long term over 20 years. One of them, the leakage of boiler water was found at one of the generating tubes, and 2 adjoining generating tubes were corroded in Dec, 2011. These generating tubes were investigated by immersion ultrasonic testing (UT) for measure thickness of the tube. As a result, thinner tube was found in a part of a bend and near the water drum. These parts are covered with sulfide deposit, it seems that the generating tubes were corroded by sulfide. (author)