WorldWideScience

Sample records for body-nonwetting liquid system

  1. PEP liquid level system

    International Nuclear Information System (INIS)

    Lauritzen, T.; Sah, R.C.

    1981-03-01

    A liquid level system has been installed in the accelerator housing of the PEP storage ring. This instrument spans the entire 2.2 km circumference of the PEP project, and over one hundred readouts provide reference elevations which are used for the accurate alignment of accelerator components. The liquid level has proven to be extremely precise (+-0.10 mm) and quick to use, and it has contributed to the accurate alignment of PEP before beam turn-on. Since the liquid level readouts are rigidly attached to the accelerator housing, the liquid level has been a convenient means to monitor the settling of the accelerator housing

  2. Liquid Level Sensing System

    Science.gov (United States)

    Korman, Valentin (Inventor); Wiley, John T. (Inventor); Duffell, Amanda G. (Inventor)

    2014-01-01

    A liquid level sensing system includes waveguides disposed in a liquid and distributed along a path with a gap between adjacent waveguides. A source introduces electromagnetic energy into the waveguides at a first end of the path. A portion of the electromagnetic energy exits the waveguides at a second end of the path. A detector measures the portion of the electromagnetic energy exiting the second end of the path.

  3. Volatile liquid storage system

    International Nuclear Information System (INIS)

    Laverman, R.J.; Winters, P.J.; Rinehart, J.K.

    1992-01-01

    This patent describes a method of collecting and abating emission from a volatile liquid in an above ground storage tank. It comprises the liquid storage tank having a bottom, a vertical cylindrical circular wall having a lower edge portion joined to the bottom, and an external fixed roof, the tank having an internal floating roof floating on a volatile liquid stored in the tank, and air vent means in the tank in communication with a vapor space in the tank constituting at least the space above the floating roof when the floating roof floats on a predetermined maximum volume of volatile liquid in the tank; permitting ambient air; pumping emission laden air from the tank vapor space above the floating roof; and by means of the emissions abatement apparatus eliminating most of the emission from the emissions laden air with formation of a gaseous effluent and then discharging the resulting gaseous effluent to the atmosphere

  4. Ferrofluids in liquid crystalline systems

    International Nuclear Information System (INIS)

    Figueiredo Neto, A.M.; Liebert, L.

    1989-08-01

    It is a well-known fact that intermediate or mesomorphic phase may exist between the crystalline and the isotropic liquid phases. The symmetry properties of these mesophases are intermediate between those of a crystal and a liquid. In this paper, some aspects of the use of ferrofluids in thermotropic and lyotropic systems are studied both the experimental difficulties as well as the fundamental phypical phenomena involved. (A.C.A.S.) [pt

  5. Radioactive liquid waste processing system

    International Nuclear Information System (INIS)

    Noda, Tetsuya; Kuramitsu, Kiminori; Ishii, Tomoharu.

    1997-01-01

    The present invention provides a system for processing radioactive liquid wastes containing laundry liquid wastes, shower drains or radioactive liquid wastes containing chemical oxygen demand (COD) ingredients and oil content generated from a nuclear power plant. Namely, a collecting tank collects radioactive liquid wastes. A filtering device is connected to the exit of the collective tank. A sump tank is connected to the exit of the filtering device. A powdery active carbon supplying device is connected to the collecting tank. A chemical fluid tank is connected to the collecting tank and the filtering device by way of chemical fluid injection lines. Backwarding pipelines connect a filtered water flowing exit of the filtering device and the collecting tank. The chemical solution is stored in the chemical solution tank. Then, radioactive materials in radioactive liquid wastes generated from a nuclear power plant are removed by the filtering device. The water quality standard specified in environmental influence reports can be satisfied. In the filtering device, when the filtering flow rate is reduced, the chemical fluid is supplied from the chemical fluid tank to the filtering device to recover the filtering flow rate. (I.S.)

  6. Liquid waste treatment system. Final report

    International Nuclear Information System (INIS)

    Baker, M.N.; Houston, H.M.

    1999-01-01

    Pretreatment of high-level liquid radioactive waste (HLW) at the West Valley Demonstration Project (WVDP) involved three distinct processing operations: decontamination of liquid HLW in the Supernatant Treatment System (STS); volume reduction of decontaminated liquid in the Liquid Waste Treatment System (LWTS); and encapsulation of resulting concentrates into an approved cement waste form in the Cement Solidification System (CSS). Together, these systems and operations made up the Integrated Radwaste Treatment System (IRTS)

  7. Liquid metal MHD generator systems

    International Nuclear Information System (INIS)

    Satyamurthy, P.; Dixit, N.S.; Venkataramani, N.; Rohatgi, V.K.

    1985-01-01

    Liquid Metal MHD (LMMHD) Generator Systems are becoming increasingly important in space and terrestrial applications due to their compactness and versatility. This report gives the current status and economic viability of LMMHD generators coupled to solar collectors, fast breeder reactors, low grade heat sources and conventional high grade heat sources. The various thermodynamic cycles in the temperatures range of 100degC-2000degC have been examined. The report also discusses the present understanding of various loss mechanisms inherent in LMMHD systems and the techniques for overcoming these losses. A small mercury-air LMMHD experimental facility being set up in Plasma Physics Division along with proposals for future development of this new technology is also presented in this report. (author)

  8. Liquid level control system for vapour generator

    International Nuclear Information System (INIS)

    Singh, G.

    1984-01-01

    A system for regulating the liquid level in a vapor generator, in which the incoming flow of feed liquid is regulated in response to the difference between the measured liquid level and a reference level, the difference between the exiting vapor mass flow rate and the incoming liquid mass flow rate, and a function of the measured incoming liquid temperature. The temperature function produces a gain value, which increases in response to decreasing incoming liquid temperature. The purpose of the temperature function is to stabilize the level control under transient conditions (e.g. sudden lose of load). (author)

  9. Liquidity policies and systemic risk

    OpenAIRE

    Adrian, Tobias; Boyarchenko, Nina

    2013-01-01

    The growth of wholesale-funded credit intermediation has motivated liquidity regulations. We analyze a dynamic stochastic general equilibrium model in which liquidity and capital regulations interact with the supply of risk-free assets. In the model, the endogenously time-varying tightness of liquidity and capital constraints generates intermediaries’ leverage cycle, influencing the pricing of risk and the level of risk in the economy. Our analysis focuses on liquidity policies’ implications ...

  10. Dual liquid and gas chromatograph system

    Science.gov (United States)

    Gay, D.D.

    A chromatographic system is described that utilizes one detection system for gas chromatographic and micro-liquid chromatographic determinations. The detection system is a direct-current, atmospheric-pressure, helium plasma emission spectrometer. The detector utilizes a nontransparent plasma source unit which contains the plasma region and two side-arms which receive effluents from the micro-liquid chromatograph and the gas chromatograph. The dual nature of this chromatographic system offers: (1) extreme flexibility in the samples to be examined; (2) extreme low sensitivity; (3) element selectivity; (4) long-term stability; (5) direct correlation of data from the liquid and gas samples; (6) simpler operation than with individual liquid and gas chromatographs, each with different detection systems; and (7) cheaper than a commercial liquid chromatograph and a gas chromatograph.

  11. Liquid-Liquid Extraction in Systems Containing Butanol and Ionic Liquids – A Review

    Directory of Open Access Journals (Sweden)

    Kubiczek Artur

    2017-03-01

    Full Text Available Room-temperature ionic liquids (RTILs are a moderately new class of liquid substances that are characterized by a great variety of possible anion-cation combinations giving each of them different properties. For this reason, they have been termed as designer solvents and, as such, they are particularly promising for liquid-liquid extraction, which has been quite intensely studied over the last decade. This paper concentrates on the recent liquid-liquid extraction studies involving ionic liquids, yet focusing strictly on the separation of n-butanol from model aqueous solutions. Such research is undertaken mainly with the intention of facilitating biological butanol production, which is usually carried out through the ABE fermentation process. So far, various sorts of RTILs have been tested for this purpose while mostly ternary liquid-liquid systems have been investigated. The industrial design of liquid-liquid extraction requires prior knowledge of the state of thermodynamic equilibrium and its relation to the process parameters. Such knowledge can be obtained by performing a series of extraction experiments and employing a certain mathematical model to approximate the equilibrium. There are at least a few models available but this paper concentrates primarily on the NRTL equation, which has proven to be one of the most accurate tools for correlating experimental equilibrium data. Thus, all the presented studies have been selected based on the accepted modeling method. The reader is also shown how the NRTL equation can be used to model liquid-liquid systems containing more than three components as it has been the authors’ recent area of expertise.

  12. Plasma-liquid system with rotational gliding discharge with liquid electrode

    International Nuclear Information System (INIS)

    Nedybaliuk, O.A.; Solomenko, O.V; Martysh, E.V.; Fedirchuk, I.I.

    2014-01-01

    Plasma-liquid system based on rotational gliding discharge with one liquid electrode was developed. Emission spectra of plasma of rotational gliding discharge with one liquid electrode were investigated. Discovered effective mechanism of controlling non-isothermal level of plasma in dynamic plasma-liquid systems. Major mechanism of expulsion of metal anode material from plasma-liquid systems with rotational discharges was shown.

  13. Radioactive liquid waste processing system

    International Nuclear Information System (INIS)

    Inakuma, Masahiko; Takahara, Nobuaki; Hara, Satomi.

    1996-01-01

    Laundry liquid wastes and shower drains containing radioactive materials generated in a nuclear power plant are removed with radioactive materials by a fiber filtration device and an activated carbon filtration device to satisfy standers of water quality described in the environmental effect investigation report. Spent activated carbon is dehydrated together with the back-wash liquid from the fiber filtration device and the activated carbon filtration device using a Nutsche-type filtration dryer. With such procedures, the scale of the facility is minimized, space for devices, maintenance for equipments and radiation dose rate are reduced. (T.M.)

  14. Excimer fluorescence of liquid crystalline systems

    Science.gov (United States)

    Sakhno, Tamara V.; Khakhel, Oleg A.; Barashkov, Nikolay N.; Korotkova, Irina V.

    1996-04-01

    The method of synchronous scanning fluorescence spectroscopy shows a presence of dimers of pyrene in a polymeric matrix. The results suggest that excimer formation takes place with dimers in liquid crystalline systems.

  15. Cryogenic system for liquid hydrogen polarimeter

    International Nuclear Information System (INIS)

    Kitami, T.; Chiba, M.; Hirabayashi, H.; Ishii, T.; Kato, S.

    1979-01-01

    A cryogenic system has been constructed for a liquid hydrogen polarimeter in order to measure polarization of high energy proton at the 1.3 GeV electron synchrotron of Institute for Nuclear Study, University of Tokyo. The system principally consists of a cryogenerator with a cryogenic transfer line, a liquid hydrogen cryostat, and a 14.5 l target container of thin aluminum alloy where liquid hydrogen is served for the experiment. The refrigeration capacity is about 54 W at 20.4 K without a target container. (author)

  16. (Liquid + liquid) phase behavior for systems containing (aromatic + TBA + methylcyclohexane)

    International Nuclear Information System (INIS)

    Ghanadzadeh, H.; Ghanadzadeh, A.

    2004-01-01

    The determination region of solubility of TBA (tert-butanol) with representative compounds of the gasoline was investigated experimentally at temperature of 298.2 K. Type 1 (liquid + liquid) phase diagrams were obtained for (methylcyclohexane + TBA + aromatic compounds). These results were correlated simultaneously by the UNIQUAC model. The values of the interaction parameters between each pair of components in the systems were obtained for the UNIQUAC model using the experimental result. The root mean square deviation (RMSD) between the observed and calculated mole percents was 1.88 for (methylcyclohexane + TBA + benzene), 2.45 for (methylcyclohexane + TBA + toluene) and 2.86 for (methylcyclohexane + TBA + ethylbenzene). The mutual solubility of methylcyclohexane and aromatic compounds (e.g., benzene toluene and ethylbenzene (BTE)) was also investigated by the addition of TBA at temperature of 298.2 K

  17. The Bevatron liquid nitrogen circulation system

    International Nuclear Information System (INIS)

    Hunt, D.; Stover, G.

    1987-03-01

    A nitrogen liquefier and computer controlled valving system have been added to the Bevatron cryoliner vacuum system to cut operating costs by reducing liquid nitrogen consumption. The computer and interface electronic systems, which control the temperatures of twenty-eight liquid nitrogen circuits, have been chosen and designed to operate in the Bevatron's pulsating magnetic field. The nitrogen exhaust is routed back to a liquefier, of about five kilowatt capacity, liquefied, and rerouted through the cooling circuits. A description of the system and operating results are presented

  18. Systemic Liquidity Crisis with Dynamic Haircuts

    OpenAIRE

    Sever, Can

    2014-01-01

    In this paper, using network tools, I analyse systemic impacts of liquidity shocks in interbank market in case of endogenous haircuts. Gai, Haldane and Kapadia (2011) introduce a benchmark for liquidity crisis following haircut shocks, and Gorton and Metrick (2010) reveal the evidence from 2007-09 crisis for increasing haircuts with banking panic. In the benchmark model, I endogenize and update haircuts dynamically during the period of stress. The results significantly differ from...

  19. 46 CFR 128.450 - Liquid-mud systems.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 4 2010-10-01 2010-10-01 false Liquid-mud systems. 128.450 Section 128.450 Shipping...: EQUIPMENT AND SYSTEMS Design Requirements for Specific Systems § 128.450 Liquid-mud systems. (a) Liquid-mud... this chapter. (b) Tanks for oil-based liquid mud must be fitted with tank vents equipped with flame...

  20. Bireactor Electronuclear Systems with Liquid Cadmium Valve

    CERN Document Server

    Bznuni, S A; Zhamkochyan, V M; ASosnin, A N; Polanski, A; Khudaverdyan, A H

    2002-01-01

    Three main types of bireactor electronuclear systems are discussed. From the point of view of assuring high level of functional characteristics and safety bireactor electronuclear systems with booster using enriched uranium (20 %) and with a liquid cadmium valve appears to be the most effective. It is shown by means of Monte-Carlo modeling that such operation conditions can be achieved which lead to the destruction of the intermediate cadmium layer making the systems supercritical (k_{eff}>1). One can avoid the problem by using a special design of the liquid cadmium valve. In comparison with other nuclear systems (critical reactors, one-reactor electronuclear systems) cascade electronuclear systems have essential advantages allowing the decrease of the proton beam current by one order of magnitude and providing at same time the necessary level of power generation and neutron flux. Availability of both the thermal and fast cones allows one to transmute not only transuranics but also the fission products - cesi...

  1. Liquid low level waste management expert system

    International Nuclear Information System (INIS)

    Ferrada, J.J.; Abraham, T.J.; Jackson, J.R.

    1991-01-01

    An expert system has been developed as part of a new initiative for the Oak Ridge National Laboratory (ORNL) systems analysis program. This expert system will aid in prioritizing radioactive waste streams for treatment and disposal by evaluating the severity and treatability of the problem, as well as the final waste form. The objectives of the expert system development included: (1) collecting information on process treatment technologies for liquid low-level waste (LLLW) that can be incorporated in the knowledge base of the expert system, and (2) producing a prototype that suggests processes and disposal technologies for the ORNL LLLW system. 4 refs., 9 figs

  2. The Liquid Annular Reactor System (LARS) propulsion

    International Nuclear Information System (INIS)

    Powell, J.; Ludewig, H.; Horn, F.; Lenard, R.

    1990-01-01

    A concept for very high specific impulse (greater than 2000 seconds) direct nuclear propulsion is described. The concept, termed the liquid annular reactor system (LARS), uses liquid nuclear fuel elements to heat hydrogen propellant to very high temperatures (approximately 6000 K). Operating pressure is moderate (approximately 10 atm), with the result that the outlet hydrogen is virtually 100 percent dissociated to monatomic H. The molten fuel is contained in a solid container of its own material, which is rotated to stabilize the liquid layer by centripetal force. LARS reactor designs are described, together with neutronic and thermal-hydraulic analyses. Power levels are on the order of 200 megawatts. Typically, LARS designs use seven rotating fuel elements, are beryllium moderated, and have critical radii of approximately 100 cm (core L/D approximately equal to 1.5)

  3. Liquid chromatography detection unit, system, and method

    Science.gov (United States)

    Derenzo, Stephen E.; Moses, William W.

    2015-10-27

    An embodiment of a liquid chromatography detection unit includes a fluid channel and a radiation detector. The radiation detector is operable to image a distribution of a radiolabeled compound as the distribution travels along the fluid channel. An embodiment of a liquid chromatography system includes an injector, a separation column, and a radiation detector. The injector is operable to inject a sample that includes a radiolabeled compound into a solvent stream. The position sensitive radiation detector is operable to image a distribution of the radiolabeled compound as the distribution travels along a fluid channel. An embodiment of a method of liquid chromatography includes injecting a sample that comprises radiolabeled compounds into a solvent. The radiolabeled compounds are then separated. A position sensitive radiation detector is employed to image distributions of the radiolabeled compounds as the radiolabeled compounds travel along a fluid channel.

  4. Advanced liquid metal reactor plant control system

    International Nuclear Information System (INIS)

    Dayal, Y.; Wagner, W.; Zizzo, D.; Carroll, D.

    1993-01-01

    The modular Advanced Liquid Metal Reactor (ALMR) power plant is controlled by an advanced state-of-the-art control system designed to facilitate plant operation, optimize availability, and protect plant investment. The control system features a high degree of automatic control and extensive amount of on-line diagnostics and operator aids. It can be built with today's control technology, and has the flexibility of adding new features that benefit plant operation and reduce O ampersand M costs as the technology matures

  5. Liquid Effluent Monitoring Information System (LEMIS) System Construction

    International Nuclear Information System (INIS)

    Adams, R.T.

    1994-01-01

    The liquid effluent sampling program is part of the effort to minimize adverse environmental impact during the cleanup operation at the Hanford Site. Of the 33 Phase I and Phase II liquid effluents, all streams actively discharged to the soil column will be sampled. The Liquid Effluent Monitoring Information System (LEMIS) is being developed as the organized information repository facility in support of the liquid effluent monitoring requirements of the Tri-Party Agreement. It is necessary to provide an automated repository into which the results from liquid effluent sampling will be placed. This repository must provide for effective retention, review, and retrieval of selected sample data by authorized persons and organizations. This System Construction document is the aggregation of the DMR P+ methodology project management deliverables. Together they represent a description of the project and its plan through four Releases, corresponding to the definition and prioritization of requirements defined by the user

  6. Data liquidity in health information systems.

    Science.gov (United States)

    Courtney, Paul K

    2011-01-01

    In 2001, the Institute of Medicine report Crossing the Quality Chasm and the National Committee on Vital and Health Statistics report Information for Health were released, and they provided the context for the development of information systems used to support health-supporting processes. Both had as their goals, implicit or explicit, to ensure the right data are provided to the right person at the right time, which is one definition of "data liquidity." This concept has had some traction in recent years as a shorthand way to express a system property for health information technology, but there is not a well-defined characterization of what properties of a system or of its components give it better or worse data liquidity. This article looks at some recent work that help to identify those properties and perhaps can help to ground the concept with metrics that are assessable.

  7. Algorithm design of liquid lens inspection system

    Science.gov (United States)

    Hsieh, Lu-Lin; Wang, Chun-Chieh

    2008-08-01

    In mobile lens domain, the glass lens is often to be applied in high-resolution requirement situation; but the glass zoom lens needs to be collocated with movable machinery and voice-coil motor, which usually arises some space limits in minimum design. In high level molding component technology development, the appearance of liquid lens has become the focus of mobile phone and digital camera companies. The liquid lens sets with solid optical lens and driving circuit has replaced the original components. As a result, the volume requirement is decreased to merely 50% of the original design. Besides, with the high focus adjusting speed, low energy requirement, high durability, and low-cost manufacturing process, the liquid lens shows advantages in the competitive market. In the past, authors only need to inspect the scrape defect made by external force for the glass lens. As to the liquid lens, authors need to inspect the state of four different structural layers due to the different design and structure. In this paper, authors apply machine vision and digital image processing technology to administer inspections in the particular layer according to the needs of users. According to our experiment results, the algorithm proposed can automatically delete non-focus background, extract the region of interest, find out and analyze the defects efficiently in the particular layer. In the future, authors will combine the algorithm of the system with automatic-focus technology to implement the inside inspection based on the product inspective demands.

  8. Systems and methods for monitoring a solid-liquid interface

    Science.gov (United States)

    Stoddard, Nathan G; Lewis, Monte A.; Clark, Roger F

    2013-06-11

    Systems and methods are provided for monitoring a solid-liquid interface during a casting process. The systems and methods enable determination of the location of a solid-liquid interface during the casting process.

  9. Liquid over-feeding air conditioning system and method

    Science.gov (United States)

    Mei, Viung C.; Chen, Fang C.

    1993-01-01

    A refrigeration air conditioning system utilizing a liquid over-feeding operation is described. A liquid refrigerant accumulator-heat exchanger is placed in the system to provide a heat exchange relationship between hot liquid refrigerant discharged from condenser and a relatively cool mixture of liquid and vaporous refrigerant discharged from the evaporator. This heat exchange relationship substantially sub-cools the hot liquid refrigerant which undergoes little or no evaporation across the expansion device and provides a liquid over-feeding operation through the evaporator for effectively using 100 percent of evaporator for cooling purposes and for providing the aforementioned mixture of liquid and vaporous refrigerant.

  10. Liquid over-feeding air conditioning system and method

    Science.gov (United States)

    Mei, V.C.; Chen, F.C.

    1993-09-21

    A refrigeration air conditioning system utilizing a liquid over-feeding operation is described. A liquid refrigerant accumulator-heat exchanger is placed in the system to provide a heat exchange relationship between hot liquid refrigerant discharged from condenser and a relatively cool mixture of liquid and vaporous refrigerant discharged from the evaporator. This heat exchange relationship substantially sub-cools the hot liquid refrigerant which undergoes little or no evaporation across the expansion device and provides a liquid over-feeding operation through the evaporator for effectively using 100 percent of evaporator for cooling purposes and for providing the aforementioned mixture of liquid and vaporous refrigerant. 1 figure.

  11. Liquid-Liquid Extraction in Systems Containing Butanol and Ionic Liquids – A Review

    OpenAIRE

    Kubiczek Artur; Kamiński Władysław

    2017-01-01

    Room-temperature ionic liquids (RTILs) are a moderately new class of liquid substances that are characterized by a great variety of possible anion-cation combinations giving each of them different properties. For this reason, they have been termed as designer solvents and, as such, they are particularly promising for liquid-liquid extraction, which has been quite intensely studied over the last decade. This paper concentrates on the recent liquid-liquid extraction studies involving ionic liqu...

  12. Development of Automotive Liquid Hydrogen Storage Systems

    Science.gov (United States)

    Krainz, G.; Bartlok, G.; Bodner, P.; Casapicola, P.; Doeller, Ch.; Hofmeister, F.; Neubacher, E.; Zieger, A.

    2004-06-01

    Liquid hydrogen (LH2) takes up less storage volume than gas but requires cryogenic vessels. State-of-the-art applications for passenger vehicles consist of double-wall cylindrical tanks that hold a hydrogen storage mass of up to 10 kg. The preferred shell material of the tanks is stainless steel, since it is very resistant against hydrogen brittleness and shows negligible hydrogen permeation. Therefore, the weight of the whole tank system including valves and heat exchanger is more than 100 kg. The space between the inner and outer vessel is mainly used for thermal super-insulation purposes. Several layers of insulation foils and high vacuums of 10-3 Pa reduce the heat entry. The support structures, which keep the inner tank in position to the outer tank, are made of materials with low thermal conductivity, e.g. glass or carbon fiber reinforced plastics. The remaining heat in-leak leads to a boil-off rate of 1 to 3 percent per day. Active cooling systems to increase the stand-by time before evaporation losses occur are being studied. Currently, the production of several liquid hydrogen tanks that fulfill the draft of regulations of the European Integrated Hydrogen Project (EIHP) is being prepared. New concepts of lightweight liquid hydrogen storage tanks will be investigated.

  13. Upgradation of automatic liquid scintillation counting system

    International Nuclear Information System (INIS)

    Bhattacharya, Sadhana; Behere, Anita; Sonalkar, S.Y.; Vaidya, P.P.

    2001-01-01

    This paper describes the upgradation of Microprocessor based Automatic Liquid Scintillation Counting systems (MLSC). This system was developed in 1980's and subsequently many systems were manufactured and supplied to Environment Survey labs at various Nuclear Power Plants. Recently this system has been upgraded to a more sophisticated one by using PC add-on hardware and developing Windows based software. The software implements more intuitive graphical user interface and also enhances the features making it comparable with commercially available systems. It implements data processing using full spectrum analysis as against channel ratio method adopted earlier, improving the accuracy of the results. Also it facilitates qualitative as well as quantitative analysis of the β-spectrum. It is possible to analyze a sample containing an unknown β-source. (author)

  14. Spillage detector for liquid chromatography systems

    Science.gov (United States)

    Jarvis, M. J.; Fulton, D. S. (Inventor)

    1986-01-01

    A spillage detector device for use in conjunction with fractionation of liquid chromatography systems which includes a spillage recieving enclosure beneath the fractionation area is described. A sensing device having a plurality of electrodes of alternating polarity is mounted within the spillage recieving enclosure. Detection circuitry, responsive to conductivity between electrodes, is operatively connected to the sensing device. The detection circuitry feeds into the output circuitry. The output circuit has relaying and switching circuitry directed to a solenoid, an alarm system and a pump. The solenoid is connected to the pliable conduit of the chromatography system. The alarm system comprises an audio alarm and a visual signal. A 115-volt power system interconnected with the pump, the solenoid, the sensing device, and the detection and output circuitry.

  15. Liquid-liquid phase transition and glass transition in a monoatomic model system.

    Science.gov (United States)

    Xu, Limei; Buldyrev, Sergey V; Giovambattista, Nicolas; Stanley, H Eugene

    2010-01-01

    We review our recent study on the polyamorphism of the liquid and glass states in a monatomic system, a two-scale spherical-symmetric Jagla model with both attractive and repulsive interactions. This potential with a parametrization for which crystallization can be avoided and both the glass transition and the liquid-liquid phase transition are clearly separated, displays water-like anomalies as well as polyamorphism in both liquid and glassy states, providing a unique opportunity to study the interplay between the liquid-liquid phase transition and the glass transition. Our study on a simple model may be useful in understanding recent studies of polyamorphism in metallic glasses.

  16. Liquidity in Retirement Savings Systems: An International Comparison

    OpenAIRE

    Beshears, John Leonard; Choi, James J.; Hurwitz, Joshua Bayard; Laibson, David I.; Madrian, Brigitte

    2015-01-01

    What is the socially optimal level of liquidity in a retirement savings system? Liquid retirement savings are desirable because liquidity enables agents to flexibly respond to pre-retirement events that raise the marginal utility of consumption. On the other hand, pre-retirement liquidity is undesirable when it leads to under-saving arising from, for example, planning mistakes or self-control problems. This paper compares the liquidity that six developed economies have built into their employ...

  17. Kinetics of glycoalkaloid hydrolysis and solanidine extraction in liquid-liquid systems

    Directory of Open Access Journals (Sweden)

    Stanković Mihajlo Z.

    2002-01-01

    Full Text Available The kinetics of glycoalkaloid hydrolysis and solanidine extraction in Analyzed in this study. obtained from dried and milled potato haulm to to which hydrochlotic acid was added is the first liquid phase, while chloroform trichloroethylene or carbon tetrachlondeisthe second organic, liquid phase. The purpose of this paper was to combine the processes of glycoalkaloid hydrolysis to solanidine and solanidine extraction into one step, and to find the optimal liquid-liquid system for such a process.

  18. (Liquid + liquid), (solid + liquid), and (solid + liquid + liquid) equilibria of systems containing cyclic ether (tetrahydrofuran or 1,3-dioxolane), water, and a biological buffer MOPS

    International Nuclear Information System (INIS)

    Altway, Saidah; Taha, Mohamed; Lee, Ming-Jer

    2015-01-01

    Graphical abstract: - Highlights: • MOPS buffer induced liquid phase splitting for mixtures of water with THF or 1,3-dioxolane. • Phase boundaries of LLE, SLE, and SLLE were determined experimentally. • Tie-lines at LLE and at SLLE were also measured. • Phase diagrams of MOPS + water + THF or 1,3-dioxolane are prepared. • LLE tie-line data are correlated satisfactorily with the NRTL model. - Abstract: Two liquid phases were formed as the addition of a certain amount of biological buffer 3-(N-morpholino)propane sulfonic acid (MOPS) in the aqueous solutions of tetrahydrofuran (THF) or 1,3-dioxolane. To evaluate the feasibility of recovering the cyclic ethers from their aqueous solutions with the aid of MOPS, we determined experimentally the phase diagrams of the ternary systems of {cyclic ether (THF or 1,3-dioxolane) + water + MOPS} at T = 298.15 K under atmospheric pressure. In this study, the solubility data of MOPS in water and in the mixed solvents of water/cyclic ethers were obtained from the results of a series of density measurements, while the (liquid + liquid) and the (solid + liquid + liquid) phase boundaries were determined by visually inspection. Additionally, the tie-line results for (liquid + liquid) equilibrium (LLE) and for (solid + liquid + liquid) equilibrium (SLLE) were measured using an analytical method. The reliability of the experimental LLE tie-line results data was validated by using the Othmer–Tobias correlation. These LLE tie-line values were correlated well with the NRTL model. The phase diagrams obtained from this study reveal that MOPS is a feasible green auxiliary agent to recover the cyclic ethers from their aqueous solutions, especially for 1,3-dioxolane

  19. Systems and methods for analyzing liquids under vacuum

    Science.gov (United States)

    Yu, Xiao-Ying; Yang, Li; Cowin, James P.; Iedema, Martin J.; Zhu, Zihua

    2013-10-15

    Systems and methods for supporting a liquid against a vacuum pressure in a chamber can enable analysis of the liquid surface using vacuum-based chemical analysis instruments. No electrical or fluid connections are required to pass through the chamber walls. The systems can include a reservoir, a pump, and a liquid flow path. The reservoir contains a liquid-phase sample. The pump drives flow of the sample from the reservoir, through the liquid flow path, and back to the reservoir. The flow of the sample is not substantially driven by a differential between pressures inside and outside of the liquid flow path. An aperture in the liquid flow path exposes a stable portion of the liquid-phase sample to the vacuum pressure within the chamber. The radius, or size, of the aperture is less than or equal to a critical value required to support a meniscus of the liquid-phase sample by surface tension.

  20. Radianttrademark Liquid Radioisotope Intravascular Radiation Therapy System

    International Nuclear Information System (INIS)

    Eigler, N.; Whiting, J.; Chernomorsky, A.; Jackson, J.; Knapp, F.F. Jr.; Litvack, F.

    1998-01-01

    RADIANTtrademark is manufactured by United States Surgical Corporation, Vascular Therapies Division, (formerly Progressive Angioplasty Systems). The system comprises a liquid β-radiation source, a shielded isolation/transfer device (ISAT), modified over-the-wire or rapid exchange delivery balloons, and accessory kits. The liquid β-source is Rhenium-188 in the form of sodium perrhenate (NaReO 4 ), Rhenium-188 is primarily a β-emitter with a physical half-life of 17.0 hours. The maximum energy of the β-particles is 2.1 MeV. The source is produced daily in the nuclear pharmacy hot lab by eluting a Tungsten-188/Rhenium-188 generator manufactured by Oak Ridge National Laboratory (ORNL). Using anion exchange columns and Millipore filters the effluent is concentrated to approximately 100 mCi/ml, calibrated, and loaded into the (ISAT) which is subsequently transported to the cardiac catheterization laboratory. The delivery catheters are modified Championtrademark over-the-wire, and TNTtrademark rapid exchange stent delivery balloons. These balloons have thickened polyethylene walls to augment puncture resistance; dual radio-opaque markers and specially configured connectors

  1. The H1 liquid argon calorimeter system

    International Nuclear Information System (INIS)

    Andrieu, B.; Babayev, A.; Ban, J.

    1993-06-01

    The liquid argon calorimeter of the H1 detector presently taking data at the HERA ep - collider at DESY, Hamburg, is described here. The main physics requirements and the most salient design features relevant to this calorimeter are given. The aim to have smooth and hermetic calorimetric coverage over the polar angular range 4 ≤ θ ≤ 154 is achieved by a single liquid argon cryostat containing calorimeter stacks structured in wheels and octants for easy handling. The absorber materials used are lead in the electromagnetic part and stainless steel in the hadronic part. The read-out system is pipelined to reduce the dead time induced by the high trigger rate expected at the HERA collider where consecutive bunches are separated in time by 96 ns. The main elements of the calorimeter, such as the cryostat, with its associated cryogenics, the stack modules, the read-out, calibration and trigger electronics as well as the data acquisition system are described. Performance results from data taken in calibration runs with full size H1 calorimeter stacks at a CERN test beam, as well as results from data collected with the complete H1 detector using cosmic rays during the initial phase of ep operations are presented. The observed energy resolutions and linearities are well in agreement with the requirements. (orig.)

  2. Optics study of liquid scintillation counting systems

    International Nuclear Information System (INIS)

    Duran Ramiro, M. T.; Garcia-Torano, E.

    2005-01-01

    Optics is a key issue in the development of any liquid scintillation counting (LSC) system. Light emission in the scintillating solution, transmission through the vial and reflector design are some aspects that need to be considered in detail. This paper describes measurements and calculations carried out to optimise these factors for the design of a new family of LSC counters. Measurements of the light distribution emitted by a scintillation vial were done by autoradiographs of cylindrical vials made of various materials and results were compared to those obtained by direct measurements of the light distribution made by scanning the vial with a photomultiplier tube. Calculations were also carried out to study the light transmission in the vial and the optimal design of the reflector for a system with one photomultiplier tube. (Author)

  3. Solid-Liquid and Liquid-Liquid Equilibrium in the Formamide-Acetophenone System.

    Czech Academy of Sciences Publication Activity Database

    Malijevská, I.; Sedláková, Zuzana; Řehák, K.; Vrbka, P.

    2006-01-01

    Roč. 71, 9 (2006) , s. 1350-1358 ISSN 0010-0765 Institutional research plan: CEZ:AV0Z40720504 Keywords : solid-liquid equilibria * liquid-liquid equilibria * metastable Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 0.881, year: 2006

  4. Modeling leaks from liquid hydrogen storage systems.

    Energy Technology Data Exchange (ETDEWEB)

    Winters, William Stanley, Jr.

    2009-01-01

    This report documents a series of models for describing intended and unintended discharges from liquid hydrogen storage systems. Typically these systems store hydrogen in the saturated state at approximately five to ten atmospheres. Some of models discussed here are equilibrium-based models that make use of the NIST thermodynamic models to specify the states of multiphase hydrogen and air-hydrogen mixtures. Two types of discharges are considered: slow leaks where hydrogen enters the ambient at atmospheric pressure and fast leaks where the hydrogen flow is usually choked and expands into the ambient through an underexpanded jet. In order to avoid the complexities of supersonic flow, a single Mach disk model is proposed for fast leaks that are choked. The velocity and state of hydrogen downstream of the Mach disk leads to a more tractable subsonic boundary condition. However, the hydrogen temperature exiting all leaks (fast or slow, from saturated liquid or saturated vapor) is approximately 20.4 K. At these temperatures, any entrained air would likely condense or even freeze leading to an air-hydrogen mixture that cannot be characterized by the REFPROP subroutines. For this reason a plug flow entrainment model is proposed to treat a short zone of initial entrainment and heating. The model predicts the quantity of entrained air required to bring the air-hydrogen mixture to a temperature of approximately 65 K at one atmosphere. At this temperature the mixture can be treated as a mixture of ideal gases and is much more amenable to modeling with Gaussian entrainment models and CFD codes. A Gaussian entrainment model is formulated to predict the trajectory and properties of a cold hydrogen jet leaking into ambient air. The model shows that similarity between two jets depends on the densimetric Froude number, density ratio and initial hydrogen concentration.

  5. Detection based on rainbow refractometry of droplet sphericity in liquid-liquid systems.

    Science.gov (United States)

    Lohner, H; Lehmann, P; Bauckhage, K

    1999-03-01

    The shape of droplets in liquid-liquid systems influences their mass and momentum transfer processes. The deviation from sphericity of rising droplets in liquid-liquid systems was investigated for different droplet sizes. Rainbow refractometry permits one to test, in this case, whether the use of laser-optical particle sizing will be correct or faulty. Since the assumption of spherical particle geometry is a general basis of laser-optical particle-sizing techniques such as rainbow refractometry or phase Doppler anemometry, deviation from the spherical shape results in a measuring error. A sphericity check based on rainbow refractometry is introduced.

  6. Thermal properties of ionic systems near the liquid-liquid critical point.

    Science.gov (United States)

    Méndez-Castro, Pablo; Troncoso, Jacobo; Pérez-Sánchez, Germán; Peleteiro, José; Romaní, Luis

    2011-12-07

    Isobaric heat capacity per unit volume, C(p), and excess molar enthalpy, h(E), were determined in the vicinity of the critical point for a set of binary systems formed by an ionic liquid and a molecular solvent. Moreover, and, since critical composition had to be accurately determined, liquid-liquid equilibrium curves were also obtained using a calorimetric method. The systems were selected with a view on representing, near room temperature, examples from clearly solvophobic to clearly coulombic behavior, which traditionally was related with the electric permittivity of the solvent. The chosen molecular compounds are: ethanol, 1-butanol, 1-hexanol, 1,3-dichloropropane, and diethylcarbonate, whereas ionic liquids are formed by imidazolium-based cations and tetrafluoroborate or bis-(trifluromethylsulfonyl)amide anions. The results reveal that solvophobic critical behavior-systems with molecular solvents of high dielectric permittivity-is very similar to that found for molecular binary systems. However, coulombic systems-those with low permittivity molecular solvents-show strong deviations from the results usually found for these magnitudes near the liquid-liquid phase transition. They present an extremely small critical anomaly in C(p)-several orders of magnitude lower than those typically obtained for binary mixtures-and extremely low h(E)-for one system even negative, fact not observed, up to date, for any liquid-liquid transition in the nearness of an upper critical solution temperature. © 2011 American Institute of Physics

  7. A system extinguishing a fire by insulating a liquid fuel

    International Nuclear Information System (INIS)

    Colome, Jacques; Duchene, Alain; Regnier, Jean.

    1975-01-01

    The invention refers to a system for quickly extinguishing a liquid fuel body on fire by insulating it completely from the ambient air. It applies particularly to the case of a high temperature liquid sodium sheet flowing accidentally from a circuit belonging to a fast neutron reactor. The system in question includes a lower receptacle for collecting the liquid fuel and a top cover shutting off the receptacle. This cover has inclined channels to take the liquid fuel flow and openings to allow this liquid through at the bottom end of the channels. These openings are closed by retractable shutters moving away under the pressure of the liquid in the channels and closing automatically after the liquid has flowed into the receptacle [fr

  8. Recent developments in biocatalysis in multiphasic ionic liquid reaction systems.

    Science.gov (United States)

    Meyer, Lars-Erik; von Langermann, Jan; Kragl, Udo

    2018-06-01

    Ionic liquids are well known and frequently used 'designer solvents' for biocatalytic reactions. This review highlights recent achievements in the field of multiphasic ionic liquid-based reaction concepts. It covers classical biphasic systems including supported ionic liquid phases, thermo-regulated multi-component solvent systems (TMS) and polymerized ionic liquids. These powerful concepts combine unique reaction conditions with a high potential for future applications on a laboratory and industrial scale. The presence of a multiphasic system simplifies downstream processing due to the distribution of the catalyst and reactants in different phases.

  9. Thermophysical properties of biodiesel and related systems: (Liquid + liquid) equilibrium data for castor oil biodiesel

    International Nuclear Information System (INIS)

    Mazutti, Marcio A.; Voll, Fernando A.P.; Cardozo-Filho, Lúcio; Corazza, Marcos L.; Lanza, Marcelo; Priamo, Wagner L.; Oliveira, J. Vladimir

    2013-01-01

    Highlights: ► (Liquid + liquid) equilibrium data for multicomponent castor oil FAME and FAEE castor oil. ► Tie-lines and solubility curves (binodal) by cloud-point method for FAME and FAEE systems. ► Experimental data correlated using the UNIQUAC model. -- Abstract: This work reports new liquid–liquid solubility values (binodal curves) as well as (liquid + liquid) equilibrium data for, ternary and quaternary systems containing fatty acid methyl esters (FAME) and fatty acid ethyl esters (FAEE) from castor oil, water, glycerol, methanol and anhydrous ethanol at T = (303.15, 318.15, and 333.15) K. Solubility curves (binodal) were also obtained by the cloud-point method for binary systems containing FAME, FAEE, water, or glycerol. All results obtained can be considered of good quality. The experimental values were correlated using the UNIQUAC model, whose results presented good performance and satisfactory fitting of equilibrium values

  10. Systemic liquidity risk: a European approach

    NARCIS (Netherlands)

    Perotti, E.

    2011-01-01

    How should financial regulators address problems stemming from liquidity risk? This column argues that the liquidity coverage and net funding ratios proposed for Basel III are economically and politically impractical. It recommends using those ratios as long-term targets while imposing ‘prudential

  11. Liquid-Liquid Phase Transition and Glass Transition in a Monoatomic Model System

    Directory of Open Access Journals (Sweden)

    Nicolas Giovambattista

    2010-12-01

    Full Text Available We review our recent study on the polyamorphism of the liquid and glass states in a monatomic system, a two-scale spherical-symmetric Jagla model with both attractive and repulsive interactions. This potential with a parametrization for which crystallization can be avoided and both the glass transition and the liquid-liquid phase transition are clearly separated, displays water-like anomalies as well as polyamorphism in both liquid and glassy states, providing a unique opportunity to study the interplay between the liquid-liquid phase transition and the glass transition. Our study on a simple model may be useful in understanding recent studies of polyamorphism in metallic glasses.

  12. Liquidity Risk and its Management in Lithuanian Banking System

    Directory of Open Access Journals (Sweden)

    Erika Bareikaitė

    2014-04-01

    Full Text Available Banks are the main part of financial sector in each economy and strength of banking system becomes vital for ensuringfavourable economic stability and growth. Recent failure of two commercial banks in Lithuania showed that managershaven’t evaluated liquidity risk or haven’t dealt with it properly. The tasks of the paper are to investigate Lithuanian banksposition towards liquidity risk, analyse what kind of management tools banks use for ensuring favourable position towardsliquidity and to explore the liquidity influence to profitability in Lithuanian banking sector. The article examines liquidity andits management processes in Lithuanian banking sector. Description of liquidity importance is presented. Liquidity risk and itsmeasurement as well as the ways of managing the above mentioned risk is analysed in the article. In order to analyse the relationshipbetween liquidity risk and profitability of banks, analysis of scientific literature, research synthesis and generalizationshave been made.

  13. Air liquide's space pulse tube cryocooler systems

    Science.gov (United States)

    Trollier, T.; Tanchon, J.; Buquet, J.; Ravex, A.

    2017-11-01

    Thanks to important development efforts completed with ESA funding, Air Liquide Advanced Technology Division (AL/DTA), is now in position to propose two Pulse Tube cooler systems in the 40-80K temperature range for coming Earth Observation missions such as Meteosat Third Generation (MTG), SIFTI, etc… The Miniature Pulse Tube Cooler (MPTC) is lifting up to 2.47W@80K with 50W compressor input power and 10°C rejection temperature. The weight is 2.8 kg. The Large Pulse Tube Cooler (LPTC) is providing 2.3W@50K for 160W input power and 10°C rejection temperature. This product is weighing 5.1 kg. The two pulse tube coolers thermo-mechanical units are qualified against environmental constraints as per ECSS-E-30. They are both using dual opposed pistons flexure bearing compressor with moving magnet linear motors in order to ensure very high lifetime. The associated Cooler Drive Electronics is also an important aspect specifically regarding the active control of the cooler thermo-mechanical unit during the launch phase and the active reduction of the vibrations induced by the compressor (partly supported by the French Agency CNES). This paper details the presentation of the two Pulse Tube Coolers together with the Cooler Drive Electronics aspects.

  14. Boiling water reactor liquid radioactive waste processing system

    International Nuclear Information System (INIS)

    Anon.

    1977-01-01

    The standard sets forth minimum design, construction and performance requirements with due consideration for operation of the liquid radioactive waste processing system for boiling water reactor plants for routine operation including design basis fuel leakage and design basis occurrences. For the purpose of this standard, the liquid radioactive waste processing system begins at the interfaces with the reactor coolant pressure boundary, at the interface valve(s) in lines from other systems and at those sumps and floor drains provided for liquid waste with the potential of containing radioactive material. The system terminates at the point of controlled discharge to the environment, at the point of interface with the waste solidification system and at the point of recycle back to storage for reuse. The standard does not include the reactor coolant clean-up system, fuel pool clean-up system, sanitary waste system, any nonaqueous liquid system or controlled area storm drains

  15. Pneumatically Modulated Liquid Delivery System for Nebulizers

    Science.gov (United States)

    2011-12-02

    passing a high-velocity sheath gas over the orifice of a liquid filled capillary. Due to the Venturi effect , liquid is pulled from the capillary orifice... pump , or through self-aspiration. Each nebulizer is calibrated to a specific gas flow for self-aspiration, eliminating the need for an external pump ...the components in a single box. Flow rates with less than 0.5% relative standard deviation are possible, and results are compared with a syringe pump

  16. An Integrated Approach Using Liquid Culture System Can it Make ...

    African Journals Online (AJOL)

    These automated liquid culture systems, when combined with commercial molecular ... Culture System. Can it Make an Impact for Clinical Diagnosis of ... affected by this disease. .... Tuberculosis in non‑UK‑born persons, England and Wales ...

  17. Water-saving liquid-gas conditioning system

    Science.gov (United States)

    Martin, Christopher; Zhuang, Ye

    2014-01-14

    A method for treating a process gas with a liquid comprises contacting a process gas with a hygroscopic working fluid in order to remove a constituent from the process gas. A system for treating a process gas with a liquid comprises a hygroscopic working fluid comprising a component adapted to absorb or react with a constituent of a process gas, and a liquid-gas contactor for contacting the working fluid and the process gas, wherein the constituent is removed from the process gas within the liquid-gas contactor.

  18. The automatic liquid nitrogen filling system for GDA detectors

    Indian Academy of Sciences (India)

    . Abstract. An indigenously developed automatic liquid nitrogen (LN2) filling system has been installed in gamma detector array (GDA) facility at Nuclear Science Centre. Electro-pneumatic valves are used for filling the liquid nitrogen into the ...

  19. Liquid hydrogen transfer pipes and level regulation systems

    International Nuclear Information System (INIS)

    Marquet, M.; Prugne, P.; Roubeau, P.

    1961-01-01

    Describes: 1) Transfer pipes - Plunging rods in liquid hydrogen Dewars; transfer pipes: knee-joint system for quick and accurate positioning of plunging Dewar rods; system's rods: combined valve and rod; valves are activated either by a bulb pressure or by a solenoid automatically or hand controlled. The latter allows intermittent filling. 2) Level regulating systems: Level bulbs: accurate to 1 or 4 m; maximum and minimum level bulbs: automatic control of the liquid hydrogen valve. (author) [fr

  20. Thermophysical properties of biodiesel and related systems: (Liquid + liquid) equilibrium data for Jatropha curcas biodiesel

    International Nuclear Information System (INIS)

    Silva, Juliana R.F.; Mazutti, Marcio A.; Voll, Fernando A.P.; Cardozo-Filho, Lúcio; Corazza, Marcos L.; Lanza, Marcelo; Priamo, Wagner L.; Vladimir Oliveira, J.

    2013-01-01

    Highlights: ► (Liquid + liquid) equilibrium data for multicomponent Jatropha curcas FAME and FAEE. ► Tie-lines, solubility curves (binodal curves) with low deviations from mass balance. ► Experimental data correlated with the UNIQUAC model. -- Abstract: Reported in this study are (liquid + liquid) equilibrium data for binary, ternary, and quaternary systems formed by fatty acid methyl esters (FAME) and fatty acid ethyl esters (FAEE) of Jatropha curcas oil, water, glycerol, methanol, and ethanol at temperatures of (303.15, 318.15, and 333.15) K. In general, all the systems investigated resulted in good agreement between phase compositions of crunodes of tie-lines, solubility curves (binodal curves) and overall compositions, hence indicating low deviations from mass balance. Experimental results were correlated with the UNIQUAC model, showing low deviations among experimental and calculated values

  1. (Vapour + liquid) equilibria of ternary systems with ionic liquids using headspace gas chromatography

    International Nuclear Information System (INIS)

    Mokhtarani, Babak; Gmehling, Juergen

    2010-01-01

    (Vapour + liquid) equilibrium (VLE) data for the ternary systems (hexane + benzene), (hexane + cyclohexane), (benzene + cyclohexane), and (ethanol + water) with an ionic liquid as entrainer for extractive distillation were measured by headspace gas chromatography. As ionic liquids, 1-hexyl-3-methyl-imidazolium bis (trifluoromethyl-sulfonyl) imide [HMIM][BTI], 1-octyl-3-methyl-imidazolium bis (trifluoromethyl-sulfonyl) imide [OMIM][BTI], 1-octyl-3-methyl-imidazolium trifluoro-methanesulfonate [OMIM][OTF], and 1-butyl-3-methyl-imidazolium trifluoro-methanesulfonate [BMIM][OTF] were used. The experimental data show that the ionic liquids investigated have a great influence on the separation factors of the systems (hexane + benzene), (hexane + cyclohexane), and (benzene + cyclohexane). The experimental data were compared with the predicted results using mod. UNIFAC (Do). The predicted results are in good agreement with the experimental data.

  2. (Vapour + liquid) equilibria of ternary systems with ionic liquids using headspace gas chromatography

    Energy Technology Data Exchange (ETDEWEB)

    Mokhtarani, Babak [Chemistry and Chemical Engineering Research Center of Iran, P.O. Box 14335-186, Tehran (Iran, Islamic Republic of); Gmehling, Juergen, E-mail: gmehling@tech.chem.uni-oldenburg.d [Carl von Ossietzky Universitaet Oldenburg, Technische Chemie, D-26111 Oldenburg (Germany)

    2010-08-15

    (Vapour + liquid) equilibrium (VLE) data for the ternary systems (hexane + benzene), (hexane + cyclohexane), (benzene + cyclohexane), and (ethanol + water) with an ionic liquid as entrainer for extractive distillation were measured by headspace gas chromatography. As ionic liquids, 1-hexyl-3-methyl-imidazolium bis (trifluoromethyl-sulfonyl) imide [HMIM][BTI], 1-octyl-3-methyl-imidazolium bis (trifluoromethyl-sulfonyl) imide [OMIM][BTI], 1-octyl-3-methyl-imidazolium trifluoro-methanesulfonate [OMIM][OTF], and 1-butyl-3-methyl-imidazolium trifluoro-methanesulfonate [BMIM][OTF] were used. The experimental data show that the ionic liquids investigated have a great influence on the separation factors of the systems (hexane + benzene), (hexane + cyclohexane), and (benzene + cyclohexane). The experimental data were compared with the predicted results using mod. UNIFAC (Do). The predicted results are in good agreement with the experimental data.

  3. System and method of liquid scintillation counting

    International Nuclear Information System (INIS)

    Rapkin, E.

    1977-01-01

    A method of liquid scintillation counting utilizing a combustion step to overcome quenching effects comprises novel features of automatic sequential introduction of samples into a combustion zone and automatic sequential collection and delivery of combustion products into a counting zone. 37 claims, 13 figures

  4. Efficient energy storage in liquid desiccant cooling systems

    Energy Technology Data Exchange (ETDEWEB)

    Hublitz, Astrid

    2008-07-18

    Liquid Desiccant Cooling Systems (LDCS) are open loop sorption systems for air conditioning that use a liquid desiccant such as a concentrated salt solution to dehumidify the outside air and cool it by evaporative cooling. Thermochemical energy storage in the concentrated liquid desiccant can bridge power mismatches between demand and supply. Low-flow LDCS provide high energy storage capacities but are not a state-of-the-art technology yet. The key challenge remains the uniform distribution of the liquid desiccant on the heat and mass transfer surfaces. The present research analyzes the factors of influence on the energy storage capacity by simulation of the heat and mass transfer processes and specifies performance goals for the distribution of the process media. Consequently, a distribution device for the liquid desiccant is developed that reliably meets the performance goals. (orig.)

  5. Enhanced electroforced sedimentation of various solid- liquid systems

    African Journals Online (AJOL)

    GREGORY

    2011-12-16

    Dec 16, 2011 ... liquid systems. Mohammed S. Jami1* ... significant challenges in wastewater management. ... environmental sludge and biosolids, thereby reducing the volumes to be disposed through landfills, incineration or other means.

  6. CANDU 6 liquid injection shutdown system waterhammer analysis using PTRAN

    International Nuclear Information System (INIS)

    Ko, Deuk Yoon; Kim, Eun Ki; Ko, Yong Sang; Park, Byung Ho; Kim, Seok Bum

    1996-06-01

    An in-core LOCA could result in flooding of the helium header in the liquid injection shutdown system. Flooding of the helium header will result in severe pressure transients (waterhammer) in the liquid injection shutdown system when the shutdown signal is initiated. To evaluate the impact of the dynamic effects of this event, a pressure transient analysis has been performed. This analysis is performed using PTRAN, which is a computer program based on the method of characteristics. The results of this analysis are used in the stress analysis of the piping and pipe supports to ensure that the liquid injection shutdown system can withstand the pressure transient loadings. This analysis report documents the results of waterhammer analysis performed for the liquid injection shutdown system for the Wolsung nuclear power plant unit 2, 3 and 4. 4 tabs., 11 figs., 15 refs. (Author)

  7. CANDU 6 liquid injection shutdown system waterhammer analysis using PTRAN

    Energy Technology Data Exchange (ETDEWEB)

    Ko, Deuk Yoon; Kim, Eun Ki; Ko, Yong Sang; Park, Byung Ho; Kim, Seok Bum [Korea Atomic Energy Research Institute, Taejon (Korea, Republic of)

    1996-06-01

    An in-core LOCA could result in flooding of the helium header in the liquid injection shutdown system. Flooding of the helium header will result in severe pressure transients (waterhammer) in the liquid injection shutdown system when the shutdown signal is initiated. To evaluate the impact of the dynamic effects of this event, a pressure transient analysis has been performed. This analysis is performed using PTRAN, which is a computer program based on the method of characteristics. The results of this analysis are used in the stress analysis of the piping and pipe supports to ensure that the liquid injection shutdown system can withstand the pressure transient loadings. This analysis report documents the results of waterhammer analysis performed for the liquid injection shutdown system for the Wolsung nuclear power plant unit 2, 3 and 4. 4 tabs., 11 figs., 15 refs. (Author).

  8. A smartphone controlled handheld microfluidic liquid handling system.

    Science.gov (United States)

    Li, Baichen; Li, Lin; Guan, Allan; Dong, Quan; Ruan, Kangcheng; Hu, Ronggui; Li, Zhenyu

    2014-10-21

    Microfluidics and lab-on-a-chip technologies have made it possible to manipulate small volume liquids with unprecedented resolution, automation and integration. However, most current microfluidic systems still rely on bulky off-chip infrastructures such as compressed pressure sources, syringe pumps and computers to achieve complex liquid manipulation functions. Here, we present a handheld automated microfluidic liquid handling system controlled by a smartphone, which is enabled by combining elastomeric on-chip valves and a compact pneumatic system. As a demonstration, we show that the system can automatically perform all the liquid handling steps of a bead-based HIV1 p24 sandwich immunoassay on a multi-layer PDMS chip without any human intervention. The footprint of the system is 6 × 10.5 × 16.5 cm, and the total weight is 829 g including battery. Powered by a 12.8 V 1500 mAh Li battery, the system consumed 2.2 W on average during the immunoassay and lasted for 8.7 h. This handheld microfluidic liquid handling platform is generally applicable to many biochemical and cell-based assays requiring complex liquid manipulation and sample preparation steps such as FISH, PCR, flow cytometry and nucleic acid sequencing. In particular, the integration of this technology with read-out biosensors may help enable the realization of the long-sought Tricorder-like handheld in vitro diagnostic (IVD) systems.

  9. (Liquid + liquid) equilibrium of {water + phenol + (1-butanol, or 2-butanol, or tert-butanol)} systems

    International Nuclear Information System (INIS)

    Hadlich de Oliveira, Leonardo; Aznar, Martin

    2010-01-01

    (Liquid + liquid) equilibrium (LLE) and binodal curve data were determined for the systems (water + phenol + tert-butanol) at T = 298.15 K, (water + phenol + 2-butanol) and (water + phenol + 1-butanol) at T = 298.15 K and T = 313.15 K by the combined techniques of densimetry and refractometry. Type I curve (for tert-butanol) and Type II curves (for 1- and 2-butanol) were found. The data were correlated with the NRTL model and the parameters estimated present root mean square deviations below 2% for the system with tert-butanol and lower than 0.8% for the other systems.

  10. Development of prototype liquid scintillator system for monitoring liquid radioactive waste

    International Nuclear Information System (INIS)

    Nam, Uk Won; Seon, Kwang Il; Kong, Kyoung Nam; Kim, Chang Kyu; Lee, Dong Myung; Lee, Sang Kook

    2003-01-01

    A prototype liquid scillatillator system for measurement of multiple beta-labeled mixtures was developed and its characteristic was investigated. The signal processing system consists of two photomultiplier tubes and the coincident count circuit. The characteristic of the system was analyzed using 4 beta-labeled samples ( 3 H, 14 C, 36 Cl and 90 Sr). Beta spectra from the samples were obtained without radiation shielding, and the detection limits for each nuclides were estimated based on the spectra. The estimated detection limits were compared to the legal regulation values. It is found that the liquid radioactive nuclides are detectable well below the legal regulation values

  11. Binary liquid-liquid equilibria of aniline-paraffin and furfural-paraffin systems

    Energy Technology Data Exchange (ETDEWEB)

    Sen, S.C.; Maity, S.; Ganguli, K.; Ray, P. (Calcutta Univ., (India))

    1991-12-01

    Liquid-liquid-equilibria (L-L-E) of hydrocarbon containing systems are of considerable commercial importance to refineries. But prediction of L-L-E of such systems is extremely difficult owing to the complex nature of the petroleum fluids. For treating such complex mixtures, a continuous component method is appropriate and for representing such liquids, a group contribution model like the UNIFAC is extremely convenient. It is, however, necessary to determine the appropriate group interaction parameters, and also to test the applicability of the UNIFAC method to these cases. Binary liquid-liquid-equilibria data for several aniline-paraffin and furfural-paraffin systems have been taken. These data along with data for other aniline-hydrocarbon and furfural-hydrocarbon systems from literature have been correlated using the UNIFAC model. The UNIFAC group interaction parameters have been found to have a linear temperature dependence. The CH{sub 2} groups in cyclo and non-cyclo paraffins require different interaction parameters. It was also found that a scaling of the combinatorial term is necessary for higher molecular weight hydrocarbons. 13 refs., 12 figs., 5 tabs.

  12. Preliminary investigation of liquid phase sintering in ferrous systems

    International Nuclear Information System (INIS)

    Klein, J.

    1975-04-01

    Liquid phase sintering was utilized to achieve, by a simple compaction and sintering procedure involving short times and moderate temperatures, a virtually full dense high carbon Fe:C alloy and high boron Fe:B alloy. Parameters such as powder characteristics and mixing, compacting pressure, heating program and the liquid phase fraction were found to influence the sintered density. The response of the Fe:C alloy to a heat treatment is reported along with preliminary experiments in the iron base ternary system Fe:W:C. Residual porosities observed in microstructures of certain liquid phase sintered compacts were accounted for by a proposed capillary flow of the liquid phase and a local densification competing against an overall densification. Some general recommendations are made for liquid phase sintering of powder aggregates. 15 fig., 7 tables

  13. Experimental measurement and prediction of (liquid + liquid + liquid) equilibrium for the system (n-hexadecane + water + triacetin)

    International Nuclear Information System (INIS)

    Revellame, Emmanuel D.; Holmes, William E.; Hernandez, Rafael; French, W. Todd; Forks, Allison; Ashe, Taylor; Estévez, L. Antonio

    2016-01-01

    Highlights: • Phase diagram for the system n-hexadecane + water + triacetin was established at T = 296.15 K and atmospheric pressure (0.1 MPa). • Both NRTL and UNIQUAC activity coefficient model adequately predicts the LLLE of the ternary system. • The phase equilibrium of the system is predominantly dictated by enthalpic contributions to the activity coefficient. - Abstract: The phase diagram for the ternary system containing (n-hexadecane + water + triacetin) was obtained experimentally at T = 296.15 K and ambient pressure. Results show that this system is of Type 3 according to the Treybal classification of ternary system. NRTL and UNIQUAC interaction parameters were calculated from binary phase equilibrium values and were used to predict the (liquid + liquid + liquid) equilibrium (LLLE) region. Results indicated that both NRTL and UNIQUAC could predict the LLLE region of the system with similar precision as indicated by the comparable standard deviations. This indicates that the enthalpic contribution to the activity coefficient is predominant and entropic contributions can be neglected.

  14. Systems engineering implementation plan for the liquid effluents services program

    International Nuclear Information System (INIS)

    Lowe, S.S.

    1995-01-01

    A graded approach is being taken by the Liquid Effluents Services Program in implementing systems engineering because of the advanced state of the program. The approach is cost-effective and takes credit for related work already completed, yet retains the benefits of systems engineering. This plan describes how the Liquid Effluents Services Program will implement systems engineering so there is a common understanding. Systems engineering work to be performed and the products of that work are identified. The relation to the current planning process and integration with the sitewide systems engineering effort is described

  15. Liquid Chromatography Applied to Space System

    Science.gov (United States)

    Poinot, Pauline; Chazalnoel, Pascale; Geffroy, Claude; Sternberg, Robert; Carbonnier, Benjamin

    Searching for signs of past or present life in our Solar System is a real challenge that stirs up the curiosity of scientists. Until now, in situ instrumentation was designed to detect and determine concentrations of a wide number of organic biomarkers. The relevant method which was and still is employed in missions dedicated to the quest of life (from Viking to ExoMars) corresponds to the pyrolysis-GC-MS. Along the missions, this approach has been significantly improved in terms of extraction efficiency and detection with the use of chemical derivative agents (e.g. MTBSTFA, DMF-DMA, TMAH…), and in terms of analysis sensitivity and resolution with the development of in situ high-resolution mass spectrometer (e.g. TOF-MS). Thanks to such an approach, organic compounds such as amino acids, sugars, tholins or polycyclic aromatic hydrocarbons (PAHs) were expected to be found. However, while there’s a consensus that the GC-MS of Viking, Huygens, MSL and MOMA space missions worked the way they had been designed to, pyrolysis is much more in debate (Glavin et al. 2001; Navarro-González et al. 2006). Indeed, (1) it is thought to remove low levels of organics, (2) water and CO2 could interfere with the detection of likely organic pyrolysis products, and (3) only low to mid-molecular weight organic molecules can be detected by this technique. As a result, researchers are now focusing on other in situ techniques which are no longer based on the volatility of the organic matter, but on the liquid phase extraction and analysis. In this line, micro-fluidic systems involving sandwich and/or competitive immunoassays (e.g. LMC, SOLID; Parro et al. 2005; Sims et al. 2012), micro-chip capillary electrophoreses (e.g. MOA; Bada et al. 2008), or nanopore-based analysis (e.g. BOLD; Schulze-Makuch et al. 2012) have been conceived for in situ analysis. Thanks to such approaches, molecular biological polymers (polysaccharides, polypeptides, polynucleotides, phospholipids, glycolipids

  16. Application of salting-out effect equation to modelling of liquid-liquid distribution systems

    International Nuclear Information System (INIS)

    Pitsch, H.K.

    1986-03-01

    Physicochemical interpretation of salting-out is reviewed and effects of the medium on liquid-liquid distribution equilibria are described by two non-specific parameters of salting-out agents: total concentration of species in the aqueous phase and water activity. Thus extraction of a given constituent in various media can be forecasted with few data. Different uranyl and technetium (VII) extraction systems are analyzed to show the potentiality of the method. Coextraction of nitric acid and uranyl nitrate by tributyl phosphate is used to show the possibility of modelling complex distribution systems in industrial conditions [fr

  17. Experimental performance of indirect air–liquid membrane contactors for liquid desiccant cooling systems

    International Nuclear Information System (INIS)

    Das, Rajat Subhra; Jain, Sanjeev

    2013-01-01

    Owing to the stringent indoor air quality (IAQ) requirements and high cost of desiccants, one of the major concerns in liquid desiccant technology has been the carryover, which can be eliminated through indirect contact between desiccant and air. Membrane contactors using microporous semipermeable hydrophobic membranes have a great potential in this regard. This communication investigates the performance of semipermeable membrane based indirect contactors as dehumidifiers in liquid desiccant cooling applications. Experiments on different types of membrane contactors are carried out using lithium chloride (LiCl) solution as desiccant. The membrane contactors consist of alternate channels of air and liquid desiccant flowing in cross-flow direction. Hydrophobic membranes form a liquid tight, vapor permeable porous barrier between hygroscopic solution and moist air, thus eliminating carryover of desiccant droplets. In order to provide maximum contact area for air–desiccant interaction, a wicking material is sandwiched between two membranes in the liquid channel. It is observed that vapor flux upto 1300 g/m 2 h can be achieved in a membrane contactor with polypropylene (PP) membranes, although the dehumidification effectiveness remains low. The effect of key parameters on the transmembrane vapor transport is presented in the paper. - Highlights: • Indirect membrane contactors developed to avoid carryover in liquid desiccant system. • Dehumidification effectiveness and vapor flux reported under varying conditions. • Vapor flux upto 1295 g/m 2 h in polypropylene contactor with high area density. • Dehumidification effectiveness with LiCl solution varies within 23% to 45%

  18. A system of hydrogen powered vehicles with liquid organic hydrides

    International Nuclear Information System (INIS)

    Taube, M.

    1981-07-01

    A motor car system based on the hydrogen produced by nuclear power stations during the night in the summer, and coupled with organic liquid hydride seems to be a feasible system in the near future. Such a system is discussed and the cost is compared with gasoline. (Auth.)

  19. H2T liquid hydrogen delivery system

    International Nuclear Information System (INIS)

    Roy, S.

    2002-01-01

    This Power Point presentation provides a preliminary evaluation of the cost of delivering liquid hydrogen produced in Quebec to hydrogen fuelled cars in Germany. The presentation describes the chain of events regarding liquid hydrogen delivery, beginning with the production of hydrogen from an initial source of hydro power. Water passes through an electrolyzer where hydrogen is liquefied and then placed into a container which is transported to market via truck, rail or tanker. Once transported, the hydrogen fuel is made available for consumers at refueling stations. The paper lists the costs related to transportation with reference to safety rules, pure transportation costs, leasing fees for the containers, and permission of customs duties for the import of hydrogen and export of empty containers between Quebec and Germany. A graph depicting a typical refueling station in Germany and the refueling events per hour was presented. For safety reasons, refueling is performed by a refueling robot. A blueprint of safety and protection distances at a refueling station was also presented. tabs., figs

  20. Operating safety requirements for the intermediate level liquid waste system

    International Nuclear Information System (INIS)

    1980-07-01

    The operation of the Intermediate Level Liquid Waste (ILW) System, which is described in the Final Safety Analysis, consists of two types of operations, namely: (1) the operation of a tank farm which involves the storage and transportation through pipelines of various radioactive liquids; and (2) concentration of the radioactive liquids by evaporation including rejection of the decontaminated condensate to the Waste Treatment Plant and retention of the concentrate. The following safety requirements in regard to these operations are presented: safety limits and limiting control settings; limiting conditions for operation; and surveillance requirements. Staffing requirements, reporting requirements, and steps to be taken in the event of an abnormal occurrence are also described

  1. Mobile liquid VR system: a cost effective alternative

    International Nuclear Information System (INIS)

    Soto, R.; Harkins, R.; HPD, Inc., Naperville, IL)

    1985-01-01

    The need for cost effective alternatives to treat large volumes of liquid radwaste has never been more evident. As part of a continuing effort to introduce such alternatives, HPD, Inc., and Chem-Nuclear Systems, Inc., have integrated two proven state-of-the-art technologies to offer a mobile liquid volume reduction system that satisfies nuclear industry requirements, with respect to liquid radwaste handling. This system optimizes proven technology by employing a crystallizer unit to concentrate the waste liquids to 50 weight percent solids, thereby reducing the volume to be solidified by factors of 40, while using only 20 percent of the energy required by conventional evaporative systems. In addition, the system employs a field proven cement solidification process which has been accepted in a Topical Report by the US NRC and which offers the highest waste to container volume ratios for stable waste forms in the industry. This volume reduction-solidification system is able to reduce over 7000 gallons of liquid waste per day to less than 30 cubic feet of 10CFR61 certified stable solidified waste for ultimate disposal or on-site storage. This document describes the GEODE System; its applicability; economics; volume reduction; scope of responsibility and experience. Major benefits include higher VR factors; assurance of continual regulatory compliance; and no capital investment

  2. Liquid nitrogen fire extinguishing system test report

    International Nuclear Information System (INIS)

    Beidelman, J.A.

    1972-01-01

    The objective of this test series was to demonstrate the feasibility of using liquid nitrogen as a fire-extinguishing agent for certain types of metal fires. It was intended to provide data and experience appropriate to the design of a second series which will test the applicability of this technique to plutonium fires and which will develop more detailed operating information and permit more precise measurement of test parameters-oxygen depletion rates and equilibrium concentrations, temperature effects, and nitrogen pressures, flow rates, spray methods and patterns, etc. The test series was directed specifically toward extinguishment of metal fires occurring in well-confined areas and was not intended to be representative of any larger classification. Fires of several types were tested, e.g., magnesium, mixed magnesium and zirconium, sodium and cerium

  3. Thermophysical properties of biodiesel and related systems: (Liquid + liquid) equilibrium data for soybean biodiesel

    International Nuclear Information System (INIS)

    Mazutti, Marcio A.; Voll, Fernando A.P.; Cardozo-Filho, Lúcio; Corazza, Marcos L.; Lanza, Marcelo; Priamo, Wagner L.; Oliveira, J. Vladimir

    2013-01-01

    Highlights: ► (Liquid + liquid) equilibrium data for the systems of biodiesel production. ► LLE data for multicomponent FAME and FAEE from (303.15 to 333.15) K. ► Experimental data correlated using the UNIQUAC model. -- Abstract: This work reports (liquid + liquid) equilibrium (LLE) data for the systems of interest in soybean biodiesel production. Numerical data for LLE were obtained for binary, ternary and quaternary systems comprising fatty acid methyl esters (FAME) and fatty acid ethyl esters (FAEE) from soybean oil, water, glycerol, methanol, and ethanol at temperatures of (303.15, 318.15, and 333.15) K. Quantification of compounds in equilibrium in both phases was determined by analytical methods whereas solubility curves (binodal) were obtained by the cloud-point method. For all systems investigated, good alignments were obtained between phase compositions and the initial as well as overall compositions hence indicating low deviations from the mass balance. Experimental results were correlated using the UNIQUAC model with satisfactory agreement between experiment and theory

  4. Liquid radioactive waste processing system for pressurized water reactor plants

    International Nuclear Information System (INIS)

    Anon.

    1976-01-01

    This Standard sets forth design, construction, and performance requirements, with due consideration for operation, of the Liquid Radioactive Waste Processing System for pressurized water reactor plants for design basis inputs. For the purpose of this Standard, the Liquid Radioactive Waste Processing System begins at the interfaces with the reactor coolant pressure boundary and the interface valve(s) in lines from other systems, or at those sumps and floor drains provided for liquid waste with the potential of containing radioactive material; and it terminates at the point of controlled discharge to the environment, at the point of interface with the waste solidification system, and at the point of recycle back to storage for reuse

  5. Factors influencing the thermodynamic isotope effect of lithium in polyetherlithium liquid-liquid extraction systems

    International Nuclear Information System (INIS)

    Fu Lian; Fang Shengqiang; Yao Zhongqi; Gao Zhichang; Tan Ganzhu

    1989-01-01

    The published data up to now concerning polyether-lithium liquid-liquid extraction systems, can be summarized by the equation, ε p = (α-1)/[1 + 0.46(1-P)], where α denotes the isotope separation factor; P - the ratio of the lithium concentration in the organic phase to the initial concentration of crown ethers; ε p -the enrichment coefficient as P = 100%. Based on the changes in ε p , P, α and D(distribution ratio), the functions of factors such as polyether's structure, polyether's side group, polyether's concentration, organic solvent, negative ion of lithium salt and lithium salt's concentration, are discussed and reported

  6. Solid-Liquid and Liquid-Liquid Equilibrium in the Ternary System Acetic Acid-Propanoic Acid-Formamide.

    Czech Academy of Sciences Publication Activity Database

    Sedláková, Zuzana; Malijevská, I.

    2007-01-01

    Roč. 261, 1-2 (2007) , s. 129-132 ISSN 0378-3812. [International Conference on Properties and Phase Equilibria for Product and Process Design PPEPPD 2007 /11./. Hersonissos, Crete, 20.05.2007-25.05.2007] Institutional research plan: CEZ:AV0Z40720504 Keywords : solid-liquid equilibrium * ternary system * solid adduct Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 1.506, year: 2007

  7. Explosion hazard in liquid nitrogen cooled fusion systems

    International Nuclear Information System (INIS)

    Brereton, S.J.

    1988-01-01

    The explosion hazard associated with the use of liquid nitrogen in a radiation environment in fusion facilities has been investigated. The principal product of irradiating liquid nitrogen is thought to be ozone, resulting from the action of radiation on oxygen impurity. Ozone is a very unstable material, and explosions may occur as it rapidly decomposes to oxygen. Occurrences of this problem in irradiated liquid nitrogen systems are reviewed. An empirical expression, from early experiments, for the yield of ozone in liquid nitrogen-oxygen mixtures exposed to gamma radiation is employed to assess the degree of ozone explosion hazard expected at fusion facilities. The problem is investigated for the Compact Ignition Tokamak (CIT) as a particular example. 16 refs., 5 figs., 1 tab

  8. Operational test report for 2706-T complex liquid transfer system

    International Nuclear Information System (INIS)

    BENZEL, H.R.

    1999-01-01

    This document is the Operational Test Report (OTR). It enters the Record Copy of the W-259 Operational Test Procedure (HNF-3610) into the document retrieval system. Additionally, the OTR summarizes significant issues associated with testing the 2706-T waste liquid transfer and storage system

  9. Mechanically assisted liquid lens zoom system for mobile phone cameras

    Science.gov (United States)

    Wippermann, F. C.; Schreiber, P.; Bräuer, A.; Berge, B.

    2006-08-01

    Camera systems with small form factor are an integral part of today's mobile phones which recently feature auto focus functionality. Ready to market solutions without moving parts have been developed by using the electrowetting technology. Besides virtually no deterioration, easy control electronics and simple and therefore cost-effective fabrication, this type of liquid lenses enables extremely fast settling times compared to mechanical approaches. As a next evolutionary step mobile phone cameras will be equipped with zoom functionality. We present first order considerations for the optical design of a miniaturized zoom system based on liquid-lenses and compare it to its mechanical counterpart. We propose a design of a zoom lens with a zoom factor of 2.5 considering state-of-the-art commercially available liquid lens products. The lens possesses auto focus capability and is based on liquid lenses and one additional mechanical actuator. The combination of liquid lenses and a single mechanical actuator enables extremely short settling times of about 20ms for the auto focus and a simplified mechanical system design leading to lower production cost and longer life time. The camera system has a mechanical outline of 24mm in length and 8mm in diameter. The lens with f/# 3.5 provides market relevant optical performance and is designed for an image circle of 6.25mm (1/2.8" format sensor).

  10. Efficiency of liquid culture systems over conventional ...

    African Journals Online (AJOL)

    The most common methods of micropropagation involve the proliferation of shoots via a semi solid system. While such semi solid systems have been moderately to highly successful in terms of multiplication yields, it has become increasingly important to improve productivity and reduce the time taken to multiply ...

  11. Study of open systems with molecules in isotropic liquids

    Science.gov (United States)

    Kondo, Yasushi; Matsuzaki, Masayuki

    2018-05-01

    We are interested in dynamics of a system in an environment, or an open system. Such phenomena as crossover from Markovian to non-Markovian relaxation and thermal equilibration are of our interest. Open systems have experimentally been studied with ultra cold atoms, ions in traps, optics, and cold electric circuits because well-isolated systems can be prepared here and thus the effects of environments can be controlled. We point out that some molecules solved in isotropic liquid are well isolated and thus they can also be employed for studying open systems in Nuclear Magnetic Resonance (NMR) experiments. First, we provide a short review on related phenomena of open systems that helps readers to understand our motivation. We, then, present two experiments as examples of our approach with molecules in isotropic liquids. Crossover from Markovian to non-Markovian relaxation was realized in one NMR experiment, while relaxation-like phenomena were observed in approximately isolated systems in the other.

  12. Advanced liquid radwaste decontamination by using a centrifuge system

    International Nuclear Information System (INIS)

    Tscheschlok, K.; Szukala, M.

    1999-01-01

    Waste water streams basically include undissolved suspended solids which contain almost the main part of the activated products. The centrifuge system, called LRS (Liquid Radwaste Treatment System), is able to remove these solids from the liquid content and fills the dewatered product into disposal containers. For this purpose a chemical pre-treatment step is often used for selective precipitation of special radionuclides and flocculents to agglomerate smaller sized particles (colloids) to make them separatable with the LRS. The plant arrangement, the process optimization and the collected operational experiences are described. 2 refs., 1 tab., 8 figs

  13. A magnetic suspension system for measuring liquid density

    Directory of Open Access Journals (Sweden)

    Luz María Centeno González

    2013-01-01

    Full Text Available Density is a derived quantity of mass and length; it is defined as mass per volume unit and its SI unit is kg/m3. National metrology institutes have been designing and building their own magnetic suspension systems during the last 5 decades for making fluid density measurements; this has allowed them to carry out research into liquids and gases’ physical characteristics. This paper was aimed at designing and developing a magnetic suspension system for a magnetic balance used in determining liquid density to be used in CENAM’s metrology density laboratories.

  14. Continuous liquid level monitoring sensor system using fiber Bragg grating

    Science.gov (United States)

    Sengupta, Dipankar; Kishore, Putha

    2014-01-01

    The design and packaging of simple, small, and low cost sensor heads, used for continuous liquid level measurement using uniformly thinned (etched) optical fiber Bragg grating (FBG) are proposed. The sensor system consists of only an FBG and a simple detection system. The sensitivity of sensor is found to be 23 pm/cm of water column pressure. A linear optical fiber edge filter is designed and developed for the conversion of Bragg wavelength shift to its equivalent intensity. The result shows that relative power measured by a photo detector is linearly proportional to the liquid level. The obtained sensitivity of the sensor is nearly -15 mV/cm.

  15. A single-chip computer analysis system for liquid fluorescence

    International Nuclear Information System (INIS)

    Zhang Yongming; Wu Ruisheng; Li Bin

    1998-01-01

    The single-chip computer analysis system for liquid fluorescence is an intelligent analytic instrument, which is based on the principle that the liquid containing hydrocarbons can give out several characteristic fluorescences when irradiated by strong light. Besides a single-chip computer, the system makes use of the keyboard and the calculation and printing functions of a CASIO printing calculator. It combines optics, mechanism and electronics into one, and is small, light and practical, so it can be used for surface water sample analysis in oil field and impurity analysis of other materials

  16. Systemic Liquidity Shocks and Banking Sector Liquidity Characteristics on the Eve of Liquidity Coverage Ratio Application - The Case of the Czech Republic1

    Directory of Open Access Journals (Sweden)

    Brůna Karel

    2016-01-01

    Full Text Available The paper contains an analysis of the economic and regulatory concept of bank liquidity in the context of systemic liquidity shock. A formal model analysis shows that the application of liquidity coverage ratio (LCR based on Basel III will lead to a significant adaptation of banks liquidity management. LCR causes a change in bank’s liquidity allocation and funding to be less effective and more costly and restrictive for providing credits comparing with economic determinants. It is demonstrated that the application of LCR underestimates actual liquidity position of a bank and leads to allocation ineffectiveness. The empirical part contains simulation of impacts of systemic liquidity shock on the banking sector’s ability to withstand the unfavourable credit shock while solvency is maintained. The results confirm the robustness of the Czech banking system ensuing from the systemic surplus of liquidity, high volume of bank capital and its high profitability. The estimations of the VAR model show that the relations between liquidity characteristics of banks, sources of aggregate liquidity shock, interbank market illiquidity and the credit facilities of the Czech National Bank are relatively weak, supporting the conclusion that the banks face liquidity shocks of non-persistent character.

  17. Liquid Nitrogen (Oxygen Simulant) Thermodynamic Vent System Test Data Analysis

    Science.gov (United States)

    Hedayat, A.; Nelson, S. L.; Hastings, L. J.; Flachbart, R. H.; Tucker, S. P.

    2005-01-01

    In designing systems for the long-term storage of cryogens in low-gravity (space) environments, one must consider the effects of thermal stratification on tank pressure that will occur due to environmental heat leaks. During low-gravity operations, a Thermodynamic Vent System (TVS) concept is expected to maintain tank pressure without propellant resettling. A series of TVS tests was conducted at NASA Marshall Space Flight Center (MSFC) using liquid nitrogen (LN2) as a liquid oxygen (LO2) simulant. The tests were performed at tank til1 levels of 90%, 50%, and 25%, and with a specified tank pressure control band. A transient one-dimensional TVS performance program is used to analyze and correlate the test data for all three fill levels. Predictions and comparisons of ullage pressure and temperature and bulk liquid saturation pressure and temperature with test data are presented.

  18. The liquid helium system of ATLAS

    International Nuclear Information System (INIS)

    Nixon, J.M.; Bollinger, L.M.

    1989-01-01

    Starting in 1978 with one small refrigerator and distribution line, the LHe system of ATLAS has gradually grown into a complex network, as required by several enlargements of the superconducting linac. The cryogenic system now comprises 3 refrigerators, 11 helium compressors, /approximately/340 ft. of coaxial LHe transfer line, 3 1000-l dewars, and /approximately/76 LHe valves that deliver steady-state flowing LHe to 16 beam-line cryostats. In normal operation, the 3 refrigerators are linked so as to provide cooling where needed. LHe heat exchangers in distribution lines play an important role. This paper discusses design features of the system, including the logic of the controls that permit the coupled refrigerators to operate stably in the presence of large and sudden changes in heat load. 8 refs., 3 figs

  19. The finite-size effect in thin liquid crystal systems

    Science.gov (United States)

    Śliwa, I.

    2018-05-01

    Effects of surface ordering in liquid crystal systems confined between cell plates are of great theoretical and experimental interest. Liquid crystals introduced in thin cells are known to be strongly stabilized and ordered by cell plates. We introduce a new theoretical method for analyzing the effect of surfaces on local molecular ordering in thin liquid crystal systems with planar geometry of the smectic layers. Our results show that, due to the interplay between pair long-range intermolecular forces and nonlocal, relatively short-range, surface interactions, both orientational and translational orders of liquid crystal molecules across confining cells are very complex. In particular, it is demonstrated that the SmA, nematic, and isotropic phases can coexist. The phase transitions from SmA to nematic, as well as from nematic to isotropic phases, occur not simultaneously in the whole volume of the system but begin to appear locally in some regions of the LC sample. Phase transition temperatures are demonstrated to be strongly affected by the thickness of the LC system. The dependence of the corresponding shifts of phase transition temperatures on the layer number is shown to exhibit a power law character. This new type of scaling behavior is concerned with the coexistence of local phases in finite systems. The influence of a specific character of interactions of molecules with surfaces and other molecules on values of the resulting critical exponents is also analyzed.

  20. Measured performance of four PWR liquid radioactive waste treatment systems

    International Nuclear Information System (INIS)

    McIsaac, C.V.; Mandler, J.W.; Stalker, A.C.

    1980-01-01

    This paper presents results of a study of the liquid radwaste treatment and boron recovery systems of four operating PWR power plants. The performance of a given system was determined from measurements of radionuclide inventories in samples drawn from demineralizers, evaporators, filters, and gaseous cleanup systems. The plants at which measurements were made are Fort Calhoun, Zion 1 and 2, Turkey Point 3 and 4, and Rancho Seco

  1. Thaw flow control for liquid heat transport systems

    Science.gov (United States)

    Kirpich, Aaron S.

    1989-01-01

    In a liquid metal heat transport system including a source of thaw heat for use in a space reactor power system, the thaw flow throttle or control comprises a fluid passage having forward and reverse flow sections and a partition having a plurality of bleed holes therein to enable fluid flow between the forward and reverse sections. The flow throttle is positioned in the system relatively far from the source of thaw heat.

  2. Liquid Nitrogen (Oxygen Simulent) Thermodynamic Venting System Test Data Analysis

    Science.gov (United States)

    Hedayat, A.; Nelson, S. L.; Hastings, L. J.; Flachbart, R. H.; Tucker, S. P.

    2005-01-01

    In designing systems for the long-term storage of cryogens in low gravity space environments, one must consider the effects of thermal stratification on excessive tank pressure that will occur due to environmental heat leakage. During low gravity operations, a Thermodynamic Venting System (TVS) concept is expected to maintain tank pressure without propellant resettling. The TVS consists of a recirculation pump, Joule-Thomson (J-T) expansion valve, and a parallel flow concentric tube heat exchanger combined with a longitudinal spray bar. Using a small amount of liquid extracted by the pump and passing it though the J-T valve, then through the heat exchanger, the bulk liquid and ullage are cooled, resulting in lower tank pressure. A series of TVS tests were conducted at the Marshall Space Flight Center using liquid nitrogen as a liquid oxygen simulant. The tests were performed at fill levels of 90%, 50%, and 25% with gaseous nitrogen and helium pressurants, and with a tank pressure control band of 7 kPa. A transient one-dimensional model of the TVS is used to analyze the data. The code is comprised of four models for the heat exchanger, the spray manifold and injector tubes, the recirculation pump, and the tank. The TVS model predicted ullage pressure and temperature and bulk liquid saturation pressure and temperature are compared with data. Details of predictions and comparisons with test data regarding pressure rise and collapse rates will be presented in the final paper.

  3. Unimolecular Solvolyses in Ionic Liquid: Alcohol Dual Solvent Systems

    Directory of Open Access Journals (Sweden)

    Elizabeth D. Kochly

    2016-01-01

    Full Text Available A study was undertaken of the solvolysis of pivaloyl triflate in a variety of ionic liquid:alcohol solvent mixtures. The solvolysis is a kΔ process (i.e., a process in which ionization occurs with rearrangement, and the resulting rearranged carbocation intermediate reacts with the alcohol cosolvent via two competing pathways: nucleophilic attack or elimination of a proton. Five different ionic liquids and three different alcohol cosolvents were investigated to give a total of fifteen dual solvent systems. 1H-NMR analysis was used to determine relative amounts of elimination and substitution products. It was found, not surprisingly, that increasing the bulkiness of alcohol cosolvent led to increased elimination product. The change in the amount of elimination product with increasing ionic liquid concentration, however, varied greatly between ionic liquids. These differences correlate strongly, though not completely, to the Kamlet–Taft solvatochromic parameters of the hydrogen bond donating and accepting ability of the solvent systems. An additional factor playing into these differences is the bulkiness of the ionic liquid anion.

  4. Expert system for liquid low-level waste management

    International Nuclear Information System (INIS)

    Ferrada, J.J.

    1992-01-01

    An expert system prototype has been developed to support system analysis activities at the Oak Ridge National Laboratory (ORNL) for waste management tasks. This expert system will aid in prioritizing radioactive waste streams for treatment and disposal by evaluating the severity and treatability of the problem as well as the final waste form. The objectives of the expert system development included: (1) collecting information on process treatment technologies for liquid low-level waste (LLLW) that can be incorporated in the knowledge base of the expert system, and (2) producing a prototype that suggests processes and disposal technologies for the ORNL LLLW system. The concept under which the expert system has been designed is integration of knowledge. There are many sources of knowledge (data bases, text files, simulation programs, etc.) that an expert would regularly consult in order to solve a problem of liquid waste management. The expert would normally know how to extract the information from these different sources of knowledge. The general scope of this project would be to include as much pertinent information as possible within the boundaries of the expert system. As a result, the user, who may not be an expert in every aspect of liquid waste management, may be able to apply the content of the information to a specific waste problem. This paper gives the methodological steps to develop the expert system under this general framework

  5. Liquid / liquid biphasic electrochemistry in ultra-turrax dispersed acetonitrile / aqueous electrolyte systems

    International Nuclear Information System (INIS)

    Watkins, John D.; Amemiya, Fumihiro; Atobe, Mahito; Bulman-Page, Philip C.; Marken, Frank

    2010-01-01

    Unstable acetonitrile | aqueous emulsions generated in situ with ultra-turrax agitation are investigated for applications in dual-phase electrochemistry. Three modes of operation for liquid / liquid aqueous-organic electrochemical processes are demonstrated with no intentionally added electrolyte in the organic phase based on (i) the formation of a water-soluble product in the aqueous phase in the presence of the organic phase, (ii) the formation of a product and ion transfer at the liquid / liquid-electrode triple phase boundary, and (iii) the formation of a water-insoluble product in the aqueous phase which then transfers into the organic phase. A three-electrode electrolysis cell with ultra-turrax agitator is employed and characterised for acetonitrile / aqueous 2 M NaCl two phase electrolyte. Three redox systems are employed in order to quantify the electrolysis cell performance. The one-electron reduction of Ru(NH 3 ) 6 3+ in the aqueous phase is employed to determine the rate of mass transport towards the electrode surface and the effect of the presence of the acetonitrile phase. The one-electron oxidation of n-butylferrocene in acetonitrile is employed to study triple phase boundary processes. Finally, the one-electron reduction of cobalticenium cations in the aqueous phase is employed to demonstrate the product transfer from the electrode surface into the organic phase. Potential applications in biphasic electrosynthesis are discussed.

  6. System of liquid thermostatic control for jet experiments on NMR

    International Nuclear Information System (INIS)

    Selivanov, S.I.; Bogatkin, R.A.; Ershov, B.A.

    1983-01-01

    The system of liquid thermostating of a sensor of NMR spectrometer, used as a registering device in the method of continuous and interrupting stream, is described. Such method of thermostating permits to make kinetic measurements in the temperature range from -40 to +60 deg C with the accuracy +-0.1 deg C and removes the necessity for applying secondary temperature NMR standards

  7. An integrated calibration system for liquid argon calorimetry

    CERN Document Server

    Marschalkowski, E; Mense, T; Nürnberger, H A; Schäfer, U

    1999-01-01

    A novel technical solution for an integrated version of the pulse generator of a calibration system for liquid argon calorimeters is presented. It consists of a differential amplifier with automatic offset compensation, a current mirror and a switching logic. These components are integrated on an ASIC chip in CMOS technology. The technical realisation as well as results on the performance are presented. (author)

  8. Liquid scintillation counting system with automatic gain correction

    International Nuclear Information System (INIS)

    Frank, R.B.

    1976-01-01

    An automatic liquid scintillation counting apparatus is described including a scintillating medium in the elevator ram of the sample changing apparatus. An appropriate source of radiation, which may be the external source for standardizing samples, produces reference scintillations in the scintillating medium which may be used for correction of the gain of the counting system

  9. An Integrated Approach Using Liquid Culture System Can it Make ...

    African Journals Online (AJOL)

    Diagnostic dilemma is a common problem faced as culture and polymerase chain reaction results vary in their sensitivity and specificity. A thorough knowledge of epidemiology, immunopathogenesis, and spectrum of the disease and importance of including liquid culture system for the diagnosis of this disease are ...

  10. Microcomputer-aided monitor for liquid hydrogen target system

    International Nuclear Information System (INIS)

    Kitami, T.; Watanabe, K.

    1983-03-01

    A microcomputer-aided monitor for a liquid hydrogen target system has been designed and tested. Various kinds of input data such as temperature, pressure, vacuum, etc. are scanned in a given time interval. Variation with time in any four items can be displayed on CRT and, if neccessary, printed out on a sheet of recording paper. (author)

  11. Experimental study on desulfurization efficiency and gas-liquid mass transfer in a new liquid-screen desulfurization system

    International Nuclear Information System (INIS)

    Sun, Zhongwei; Wang, Shengwei; Zhou, Qulan; Hui, Shi'en

    2010-01-01

    This paper presents a new liquid-screen gas-liquid two-phase flow pattern with discarded carbide slag as the liquid sorbent of sulfur dioxide (SO 2 ) in a wet flue gas desulfurization (WFGD) system. On the basis of experimental data, the correlations of the desulfurization efficiency with flue gas flow rate, slurry flow rate, pH value of slurry and liquid-gas ratio were investigated. A non-dimensional empirical model was developed which correlates the mass transfer coefficient with the liquid Reynolds number, gas Reynolds number and liquid-gas ratio (L/G) based on the available experimental data. The kinetic reaction between the SO 2 and the carbide slag depends on the pressure distribution in this desulfurizing tower, gas liquid flow field, flue gas component, pH value of slurry and liquid-gas ratio mainly. The transient gas-liquid mass transfer involving with chemical reaction was quantified by measuring the inlet and outlet SO 2 concentrations of flue gas as well as the characteristics of the liquid-screen two-phase flow. The mass transfer model provides a necessary quantitative understanding of the hydration kinetics of sulfur dioxide in the liquid-screen flue gas desulfurization system using discarded carbide slag which is essential for the practical application. (author)

  12. A broadband helical saline water liquid antenna for wearable systems

    Science.gov (United States)

    Li, Gaosheng; Huang, Yi; Gao, Gui; Yang, Cheng; Lu, Zhonghao; Liu, Wei

    2018-04-01

    A broadband helical liquid antenna made of saline water is proposed. A transparent hollow support is employed to fabricate the antenna. The rotation structure is fabricated with a thin flexible tube. The saline water with a concentration of 3.5% can be injected into or be extracted out from the tube to change the quantity of the solution. Thus, the tunability of the radiation pattern could be realised by applying the fluidity of the liquid. The radiation feature of the liquid antenna is compared with that of a metal one, and fairly good agreement has been achieved. Furthermore, three statements of the radiation performance corresponding to the ratio of the diameter to the wavelength of the helical saline water antenna have been proposed. It has been found that the resonance frequency increases when the length of the feeding probe or the radius of the vertical part of the liquid decreases. The fractional bandwidth can reach over 20% with a total height of 185 mm at 1.80 GHz. The measured results indicate reasonable approximation to the simulated. The characteristics of the liquid antenna make it a good candidate for various wireless applications, especially the wearable systems.

  13. Construction and implementation of a liquid scintillation TDCR system

    International Nuclear Information System (INIS)

    Wu Yongle; Liang Juncheng; Liu Jiacheng; Yang Yuandi; Yuan Daqing

    2012-01-01

    The triple-to-double coincidence ratio (TDCR) method is an absolute measurement method of radioactivity, and is a popular technique for the standardization of pure beta radionuclides. A triple-to-double coincidence ratio (TDCR) liquid scintillation counting system has been constructed in China. A description of the system and measured activities for sources such as 3 H and 99 Te are presented. (authors)

  14. Analytical concepts for health management systems of liquid rocket engines

    Science.gov (United States)

    Williams, Richard; Tulpule, Sharayu; Hawman, Michael

    1990-01-01

    Substantial improvement in health management systems performance can be realized by implementing advanced analytical methods of processing existing liquid rocket engine sensor data. In this paper, such techniques ranging from time series analysis to multisensor pattern recognition to expert systems to fault isolation models are examined and contrasted. The performance of several of these methods is evaluated using data from test firings of the Space Shuttle main engines.

  15. Glass and liquid phase diagram of a polyamorphic monatomic system

    Science.gov (United States)

    Reisman, Shaina; Giovambattista, Nicolas

    2013-02-01

    We perform out-of-equilibrium molecular dynamics (MD) simulations of a monatomic system with Fermi-Jagla (FJ) pair potential interactions. This model system exhibits polyamorphism both in the liquid and glass state. The two liquids, low-density (LDL) and high-density liquid (HDL), are accessible in equilibrium MD simulations and can form two glasses, low-density (LDA) and high-density amorphous (HDA) solid, upon isobaric cooling. The FJ model exhibits many of the anomalous properties observed in water and other polyamorphic liquids and thus, it is an excellent model system to explore qualitatively the thermodynamic properties of such substances. The liquid phase behavior of the FJ model system has been previously characterized. In this work, we focus on the glass behavior of the FJ system. Specifically, we perform systematic isothermal compression and decompression simulations of LDA and HDA at different temperatures and determine "phase diagrams" for the glass state; these phase diagrams varying with the compression/decompression rate used. We obtain the LDA-to-HDA and HDA-to-LDA transition pressure loci, PLDA-HDA(T) and PHDA-LDA(T), respectively. In addition, the compression-induced amorphization line, at which the low-pressure crystal (LPC) transforms to HDA, PLPC-HDA(T), is determined. As originally proposed by Poole et al. [Phys. Rev. E 48, 4605 (1993)], 10.1103/PhysRevE.48.4605 simulations suggest that the PLDA-HDA(T) and PHDA-LDA(T) loci are extensions of the LDL-to-HDL and HDL-to-LDL spinodal lines into the glass domain. Interestingly, our simulations indicate that the PLPC-HDA(T) locus is an extension, into the glass domain, of the LPC metastability limit relative to the liquid. We discuss the effects of compression/decompression rates on the behavior of the PLDA-HDA(T), PHDA-LDA(T), PLPC-HDA(T) loci. The competition between glass polyamorphism and crystallization is also addressed. At our "fast rate," crystallization can be partially suppressed and the

  16. Lyotropic liquid crystalline phase behaviour in amphiphile-protic ionic liquid systems.

    Science.gov (United States)

    Chen, Zhengfei; Greaves, Tamar L; Fong, Celesta; Caruso, Rachel A; Drummond, Calum J

    2012-03-21

    Approximate partial phase diagrams for nine amphiphile-protic ionic liquid (PIL) systems have been determined by synchrotron source small angle X-ray scattering, differential scanning calorimetry and cross polarised optical microscopy. The binary phase diagrams of some common cationic (hexadecyltrimethyl ammonium chloride, CTAC, and hexadecylpyridinium bromide, HDPB) and nonionic (polyoxyethylene (10) oleyl ether, Brij 97, and Pluronic block copolymer, P123) amphiphiles with the PILs, ethylammonium nitrate (EAN), ethanolammonium nitrate (EOAN) and diethanolammonium formate (DEOAF), have been studied. The phase diagrams were constructed for concentrations from 10 wt% to 80 wt% amphiphile, in the temperature range 25 °C to >100 °C. Lyotropic liquid crystalline phases (hexagonal, cubic and lamellar) were formed at high surfactant concentrations (typically >50 wt%), whereas at thermal stability of the phases formed by these surfactants persisted to temperatures above 100 °C. The phase behaviour of amphiphile-PIL systems was interpreted by considering the PIL cohesive energy, liquid nanoscale order, polarity and ionicity. For comparison the phase behaviour of the four amphiphiles was also studied in water.

  17. The liquid lithium limiter control system on FTU

    Energy Technology Data Exchange (ETDEWEB)

    Bertocchi, A. [EURATOM-ENEA Association, Frascati Research Center, Via E. Fermi 45, 00044 Frascati (Rome) (Italy)], E-mail: bertocchi@frascati.enea.it; Di Donna, M [Department of Informatics, Systems and Productions, University of Rome Tor Vergata, Rome (Italy); Panella, M; Vitale, V [EURATOM-ENEA Association, Frascati Research Center, Via E. Fermi 45, 00044 Frascati (Rome) (Italy)

    2007-10-15

    In the second half of 2005, a liquid lithium limiter (LLL) with capillary porous system (CPS) configuration was installed to test on Tokamak FTU. The liquid lithium flows through capillaries from a reservoir to the side faced to the plasma to form a thin lithium film as wall coating. The system includes three stainless steel cases, which contain two thermocouples each one. A heating system brings the Li temperature about 200 deg. C to allow the liquid to flow. This temperature, monitored by thermocouples, needs to be controlled. To carry out this experimental procedure, some new features have been introduced in the existent control system based on Opto22{sup TM} modules and a CORBA/PHP/MySQL software architecture. The historical data storage to keep the lithium temperature evolution has been added. Two graphical tools - developed in MATLAB{sup TM} and Java environments, respectively, to monitor the lithium temperature coming from thermocouples - have been also implemented. The LLL control system allows to regulate the heater temperature in each unit to reach operational conditions, where the temperature adjustment can be performed either automatically through a specific control law or manually by the operator. During the plasma shot the system switches off the limiter power supply to prevent instruments damage. Moreover, in the same experimental context, a first approach to automatically obtain executable code - starting from control laws designed by Simulink{sup TM} tool - has been realized.

  18. The liquid lithium limiter control system on FTU

    International Nuclear Information System (INIS)

    Bertocchi, A.; Di Donna, M.; Panella, M.; Vitale, V.

    2007-01-01

    In the second half of 2005, a liquid lithium limiter (LLL) with capillary porous system (CPS) configuration was installed to test on Tokamak FTU. The liquid lithium flows through capillaries from a reservoir to the side faced to the plasma to form a thin lithium film as wall coating. The system includes three stainless steel cases, which contain two thermocouples each one. A heating system brings the Li temperature about 200 deg. C to allow the liquid to flow. This temperature, monitored by thermocouples, needs to be controlled. To carry out this experimental procedure, some new features have been introduced in the existent control system based on Opto22 TM modules and a CORBA/PHP/MySQL software architecture. The historical data storage to keep the lithium temperature evolution has been added. Two graphical tools - developed in MATLAB TM and Java environments, respectively, to monitor the lithium temperature coming from thermocouples - have been also implemented. The LLL control system allows to regulate the heater temperature in each unit to reach operational conditions, where the temperature adjustment can be performed either automatically through a specific control law or manually by the operator. During the plasma shot the system switches off the limiter power supply to prevent instruments damage. Moreover, in the same experimental context, a first approach to automatically obtain executable code - starting from control laws designed by Simulink TM tool - has been realized

  19. Liquid Cooling System for CPU by Electroconjugate Fluid

    Directory of Open Access Journals (Sweden)

    Yasuo Sakurai

    2014-06-01

    Full Text Available The dissipated power of CPU for personal computer has been increased because the performance of personal computer becomes higher. Therefore, a liquid cooling system has been employed in some personal computers in order to improve their cooling performance. Electroconjugate fluid (ECF is one of the functional fluids. ECF has a remarkable property that a strong jet flow is generated between electrodes when a high voltage is applied to ECF through the electrodes. By using this strong jet flow, an ECF-pump with simple structure, no sliding portion, no noise, and no vibration seems to be able to be developed. And then, by the use of the ECF-pump, a new liquid cooling system by ECF seems to be realized. In this study, to realize this system, an ECF-pump is proposed and fabricated to investigate the basic characteristics of the ECF-pump experimentally. Next, by utilizing the ECF-pump, a model of a liquid cooling system by ECF is manufactured and some experiments are carried out to investigate the performance of this system. As a result, by using this system, the temperature of heat source of 50 W is kept at 60°C or less. In general, CPU is usually used at this temperature or less.

  20. Improved liquid waste processing system of PWR plant

    International Nuclear Information System (INIS)

    Suehiro, Kazuyasu

    1977-01-01

    Mitsubishi Heavy Industries, Ltd. has engaged in the improvement and enhancement of waste-processing facilities for PWR power stations, and recently established the improved processing system. With this system, it becomes possible to contain radioactive waste gas semi-permanently within plants and to recycle waste liquid after the treatment, thus to make the release of radioactive wastes practically zero. The improved system has the following features, namely the recycling system is adopted, drain is separated and each separated drain is treated by specialized process, the reboiler type evaporator and the reverse osmosis equipment are used, and the leakless construction is adopted for the equipments. The radioactive liquid wastes in PWR power stations are classified into coolant drain, drain from general equipments, chemical drain and cleaning water. The outline of the improved processing system and the newly developed equipments such as the reboiler type evaporator and the reverse osmosis equipment are explained. With the evaporator, the concentration rate of waste liquid can be raised to about three times, and foaming waste can be treated efficiently. The decontamination performance is excellent. The reverse osmosis treatment is stable and reliable method, and is useful for the treatment of cleaning water. It is also effective for concentrating treatment. The unmanned automatic operation is possible. (Kako, I.)

  1. The Liquid Lithium Limiter control system on FTU

    International Nuclear Information System (INIS)

    Bertocchi, A.; Panella, M.; Vitale, V.; Sinibaldi, S.

    2006-01-01

    In the second half of 2005, a liquid lithium limiter (LLL) with capillary porous system configuration was installed for testing on the FTU tokamak. The liquid lithium flows through capillaries from a reservoir to the side facing the plasma to form a thin liquid lithium film. The system is composed of three stainless steel sections, which contain two thermocouples each. A heating system brings the Li temperature to about 200 o C allowing the liquid to flow. This temperature, monitored by thermocouples, needs to be controlled. [M. Apicella, G. Mazzitelli et al., First experiment with Lithium Limiter on FTU, 17 o International Conference on Plasma Surface Interaction in Controlled Fusion Devices, 22 - 26 May 2006, Hefei Anhui, China]. To carry out this experimental procedure, some new features have been introduced in the existent control system based on Opto22 TM modules and a CORBA/PHP/MySQL software architecture [A. Bertocchi, S. Podda, V. Vitale, Fusion Eng. Des. 74 (2005) 787-791]. The historical data storage to keep the lithium temperature evolution has been added. Two graphical tools - developed in MATLab and Java environments respectively to monitor the lithium temperature coming from thermocouples - have been also implemented. The control system allows regulating the heater temperature in each section of the LLL to reach operational conditions, where the temperature adjustment can be performed either automatically through a specific control law or manually by the operator. During plasma operations the system switches off the limiter power supply to prevent instruments damage. Moreover, in the same experimental context, a first approach to automatically obtain executable code - starting from control laws designed by Simulink TM tool - has been realized. (author)

  2. The Liquid Lithium Limiter control system on FTU

    Energy Technology Data Exchange (ETDEWEB)

    Bertocchi, A; Panella, M; Vitale, V [Associazione EURATOM- ENEA sulla Fusione, Via Enrico Fermi 45, I-00044 Frascati (RM) (Italy); Sinibaldi, S [Rome University ' ' Tor Vergata ' ' , Informatics, Systems and Production Dept., Via del Politecnico 1, 00133 Rome (Italy)

    2006-07-01

    In the second half of 2005, a liquid lithium limiter (LLL) with capillary porous system configuration was installed for testing on the FTU tokamak. The liquid lithium flows through capillaries from a reservoir to the side facing the plasma to form a thin liquid lithium film. The system is composed of three stainless steel sections, which contain two thermocouples each. A heating system brings the Li temperature to about 200 {sup o}C allowing the liquid to flow. This temperature, monitored by thermocouples, needs to be controlled. [M. Apicella, G. Mazzitelli et al., First experiment with Lithium Limiter on FTU, 17{sup o} International Conference on Plasma Surface Interaction in Controlled Fusion Devices, 22 - 26 May 2006, Hefei Anhui, China]. To carry out this experimental procedure, some new features have been introduced in the existent control system based on Opto22{sup TM} modules and a CORBA/PHP/MySQL software architecture [A. Bertocchi, S. Podda, V. Vitale, Fusion Eng. Des. 74 (2005) 787-791]. The historical data storage to keep the lithium temperature evolution has been added. Two graphical tools - developed in MATLab and Java environments respectively to monitor the lithium temperature coming from thermocouples - have been also implemented. The control system allows regulating the heater temperature in each section of the LLL to reach operational conditions, where the temperature adjustment can be performed either automatically through a specific control law or manually by the operator. During plasma operations the system switches off the limiter power supply to prevent instruments damage. Moreover, in the same experimental context, a first approach to automatically obtain executable code - starting from control laws designed by Simulink{sup TM} tool - has been realized. (author)

  3. (Liquid + liquid) equilibrium for binary systems of N-formylmorpholine with alkanes

    International Nuclear Information System (INIS)

    Wang Zhengrong; Xia Shuqian; Ma Peisheng; Liu Tao; Han Kewei

    2012-01-01

    Highlights: ► The LLE data of four binary systems containing N-formylmorpholine were measured. ► Both NRTL and UNIQUAC models can fit the experimental data well. ► The new group interaction parameters of UNIFAC (Do) were regressed from the LLE data. ► The estimated result shows that the group interaction parameters and methods are reliable. - Abstract: (Liquid + liquid) equilibrium (LLE) data were determined for four binary systems containing N-formylmorpholine (NFM) and alkanes (3-methylpentane, heptane, nonane, and 2,2,4-trimethylpentane) over the temperature range from around 300 K to near 420 K using a set of newly designed equilibrium equipment. The compositions of both light and heavy phases were analyzed by gas chromatography. The mutual solubility increased as the temperature increased for all these systems. The binary (liquid + liquid) equilibrium data were correlated by the NRTL and UNIQUAC equations with temperature-dependent parameters. Both models correlate the experimental results well. Furthermore, the UNIFAC (Do) group contribution model was used to correlate and estimate the LLE data for NFM containing systems. Two methods of group division for NFM were used. NFM is treated as a single group: NFM group (method I) or divided into two groups: CHO and C 4 H 8 NO (method II), respectively. The group interaction parameters for CH 2 –NFM, or CH 2 –CHO and CH 2 –C 4 H 8 NO were fitted from the experimental LLE data. The UNIFAC (Do) model correlates the experimental data well. In addition, in order to develop UNIFAC (Do) group contribution model to estimate the LLE data of (NFM + cycloalkane) systems, some literature LLE data were used. The group interaction parameters for c-CH 2 –NFM, c-CH 2 –CHO and c-CH 2 –C 4 H 8 NO were correlated. Then these group interaction parameters were used to estimate the phase equilibrium data of binary systems in the literature by the UNIFAC (Do) model. The results showed that the estimated values are in

  4. Liquid gating elastomeric porous system with dynamically controllable gas/liquid transport.

    Science.gov (United States)

    Sheng, Zhizhi; Wang, Honglong; Tang, Yongliang; Wang, Miao; Huang, Lizhi; Min, Lingli; Meng, Haiqiang; Chen, Songyue; Jiang, Lei; Hou, Xu

    2018-02-01

    The development of membrane technology is central to fields ranging from resource harvesting to medicine, but the existing designs are unable to handle the complex sorting of multiphase substances required for many systems. Especially, the dynamic multiphase transport and separation under a steady-state applied pressure have great benefits for membrane science, but have not been realized at present. Moreover, the incorporation of precisely dynamic control with avoidance of contamination of membranes remains elusive. We show a versatile strategy for creating elastomeric microporous membrane-based systems that can finely control and dynamically modulate the sorting of a wide range of gases and liquids under a steady-state applied pressure, nearly eliminate fouling, and can be easily applied over many size scales, pressures, and environments. Experiments and theoretical calculation demonstrate the stability of our system and the tunability of the critical pressure. Dynamic transport of gas and liquid can be achieved through our gating interfacial design and the controllable pores' deformation without changing the applied pressure. Therefore, we believe that this system will bring new opportunities for many applications, such as gas-involved chemical reactions, fuel cells, multiphase separation, multiphase flow, multiphase microreactors, colloidal particle synthesis, and sizing nano/microparticles.

  5. Prediction of (liquid + liquid) equilibrium for binary and ternary systems containing ionic liquids with the bis[(trifluoromethyl)sulfonyl]imide anion using the ASOG method

    International Nuclear Information System (INIS)

    Robles, Pedro A.; Cisternas, Luis A.

    2015-01-01

    Highlights: • ASOG model was used to predict LLE data for ionic liquid systems. • Twenty five binary and seven ternary systems that include the NTf 2 anion were used. • New group interaction parameters were determined. • The results are satisfactory, with rms deviations of about 3%. - Abstract: Ionic liquids are neoteric, environmentally friendly solvents (as they do not produce emissions) composed of large organic cations and relatively small inorganic anions. They have favorable physical properties, such as negligible volatility and a wide range of liquid existence. (Liquid + liquid) equilibrium (LLE) data for systems including ionic liquids, although essential for the design, optimization and operation of separation processes, remain scarce. However, some recent studies have presented ternary LLE data involving several ionic liquids and organic compounds such as alkanes, alkenes, alkanols, ethers and aromatics, as well as water. In this work, the ASOG model for the activity coefficient is used to predict LLE data for 25 binary and 07 ternary systems at 101.3 kPa and several temperatures; all the systems are formed by ionic liquids including the bis[(trifluoromethyl)sulfonyl]imide (NTf 2 ) anion plus alkanes, alkenes, cycloalkanes, alkanols, water, thiophene and aromatics. New group interaction parameters were determined using a modified Simplex method, minimizing a composition-based objective function of experimental data obtained from the literature. The results are satisfactory, with rms deviations of approximately 3%

  6. Microcontroller based automatic liquid poison addition control system

    International Nuclear Information System (INIS)

    Kapatral, R.S.; Ananthakrishnan, T.S.; Pansare, M.G.

    1989-01-01

    Microcontrollers are finding increasing applications in instrumentation where complex digital circuits can be substituted by a compact and simple circuit, thus enhancing the reliability. In addition to this, intelligence and flexibility can be incorporated. For applications not requiring large amount of read/write memory (RAM), microcontrollers are ideally suited since they contain programmable memory (Eprom), parallel input/output lines, data memory, programmable timers and serial interface ports in one chip. This paper describes the design of automatic liquid poison addition control system (ALPAS) using intel's 8 bit microcontroller 8751, which is used to generate complex timing control sequence signals for liquid poison addition to the moderator in a nuclear reactor. ALPAS monitors digital inputs coming from protection system and regulating system of a nuclear reactor and provides control signals for liquid poison addition for long term safe shutdown of the reactor after reactor trip and helps the regulating system to reduce the power of the reactor during operation. Special hardware and software features have been incorporated to improve performance and fault detection. (author)

  7. Evaluation of a contact device type ejector system for liquid-liquid extraction

    International Nuclear Information System (INIS)

    Schwamback, Niomedes

    2002-04-01

    The objective of the present work was to evaluate an ejector system, operated simultaneously with two immiscible liquid phases and a gas phase, as a contact device for liquid-liquid extraction processes. The ejector, made of perspex, has a variable geometry, although this feature was not explored in the thesis. Motivated by recent uses of liquid-liquid extraction processes for the removal of traces of heavy metal from waste waters, it was decided to carry out tests with synthetic effluents. This strategy, typical of experimental work under evaluation of technical feasibility, greatly simplifies experiments, since the nature of the chemical species involved and their feed concentrations are known exactly and do not fluctuate. The extractant used was DEHPA (diethyl hexyl phosphoric acid). The metal chosen for tests was iron with oxidation number +3, because of its high extraction coefficient towards DEHPA and also for its chemical behavior similar to americium and other heavy metals. In addition to that, iron forms soluble coloured complexes adequate to spectrophotometric determination analysis, a simple, quick and very reliable analytical technique. The effects of electrolytes of interest, namely NaCl, FeSO 4 and Al(NO 3 ) 3 , upon the extraction process were investigated. The effects resulting from the introduction of a gas phase, actually air (bubbles), in the ejector upon the extraction efficiency were studied. By coupling advanced digital photographic technique and image analysis with microcomputer, the bubble mean size was measured. It was then correlated with equipment's geometrical (characteristic diameters) and operational variables (phases' flow rates and gas hold-ups). To enable scale-up procedures, data were preferably correlated by means of dimensionless groups. For the systems and conditions investigated in this thesis and under the same operational conditions, the introduction of air bubbles by means of an ejector has greatly improved the process

  8. The Liquid Argon Calorimeter system for the SLC Large Detector

    International Nuclear Information System (INIS)

    Haller, G.M.; Fox, J.D.; Smith, S.R.

    1988-09-01

    In this paper the physical packaging and the logical organization of the Liquid Argon Calorimeter (LAC) electronics system for the Stanford Linear Collider Large Detector (SLD) at SLAC are described. This system processes signals from approximately 44,000 calorimeter towers and is unusual in that most electronic functions are packaged within the detector itself as opposed to an external electronics support rack. The signal path from the towers in the liquid argon through the vacuum to the outside of the detector is explained. The organization of the control logic, analog electronics, power regulation, analog-to-digital conversion circuits, and fiber optic drivers mounted directly on the detector are described. Redundancy considerations for the electronics and cooling issues are discussed. 12 refs., 5 figs

  9. Scintillation trigger system of the liquid argon neutrino detector

    International Nuclear Information System (INIS)

    Belikov, S.V.; Gurzhiev, S.N.; Gutnikov, Yu.E.; Denisov, A.G.; Kochetkov, V.I.; Matveev, M.Yu.; Mel'nikov, E.A.; Usachev, A.P.

    1994-01-01

    This paper presents the organization of the Scintillation Trigger System (STS) for the Liquid Argon Neutrino Detector of the Tagged Neutrino Facility. STS is aimed at the effective registration of the needed neutrino interaction type and production of a fast trigger signal with high time resolution. The fast analysis system of analog signal from the trigger scintillation planes for rejection of the trigger signals from background processes is described. Real scintillation trigger planes characteristics obtained on the basis of the presented data acquisition system are shown. 10 refs., 12 figs., 3 tabs

  10. Performance investigation on the ultrasonic atomization liquid desiccant regeneration system

    International Nuclear Information System (INIS)

    Yang, Zili; Zhang, Kaisheng; Hwang, Yunho; Lian, Zhiwei

    2016-01-01

    Highlights: • We applied ultrasonic atomization technology to boost liquid desiccant regeneration. • We established a novel UARS and made a thorough study on its performance. • We developed a performance prediction model for UARS and validated its accuracy. • The necessary regeneration temperature dropped significantly (4.4 °C) in UARS. • Energy consumption for regenerating desiccant was reduced greatly (60.4%) in UARS. - Abstract: Liquid desiccant dehumidification systems have accumulated considerable research interest in recent years for their great energy saving potential in buildings. Within the system, the regenerator recovering liquid desiccant plays a major role in its performance. When the ultrasonic atomization technology is applied to atomize the desiccant solution into numerous tiny droplets with diameters around 50 μm, the regeneration process could be greatly enhanced. To validate this approach, a novel ultrasonic atomization liquid desiccant regeneration system (UARS) was studied in this work. An Ideal Regeneration Model (IRM) was developed to predict the regeneration performance of the UARS. Additionally, thorough experiments were carried out to validate the model under different operating conditions of the desiccant solution and air stream. The model predicted values and the experimental results coincided, with the average deviation less than 7.9%. The performance of UARS was compared with other regeneration systems from the open literature, while a case study was conducted for the power consumption and energy saving potential of UARS. It was found that the ultrasonic atomization technology enabled utilization of lower-grade energy for desiccant regeneration with the regeneration temperature lowered as much as 4.4 °C. In addition, a considerable energy saving potential of up to 23.4% could be achieved by the UARS for regenerating per unit mass flow of desiccant solution, while the power consumption of the ultrasonic atomization system

  11. Microscopic Fermi liquid approach to disordered narrow band systems

    International Nuclear Information System (INIS)

    Kolley, E.; Kolley, W.

    1977-01-01

    A Fermi liquid approach to tightly bound electrons in disordered systems is proposed to evaluate two-particle correlation functions L at T=0 deg K. Starting with a random Hubbard model and using a local ladder approximation in the particle-particle channel the irreducible particle-hole vertex is derived, being the kernel of the Bethe-Salpeter equation for L. CPA vertex corrections to the electrical conductivity and, for the ordered case, the correlation-enhanced paramagnetic susceptibility are calculated

  12. Cryogenic Liquid Sample Acquisition System for Remote Space Applications

    Science.gov (United States)

    Mahaffy, Paul; Trainer, Melissa; Wegel, Don; Hawk, Douglas; Melek, Tony; Johnson, Christopher; Amato, Michael; Galloway, John

    2013-01-01

    There is a need to acquire autonomously cryogenic hydrocarbon liquid sample from remote planetary locations such as the lakes of Titan for instruments such as mass spectrometers. There are several problems that had to be solved relative to collecting the right amount of cryogenic liquid sample into a warmer spacecraft, such as not allowing the sample to boil off or fractionate too early; controlling the intermediate and final pressures within carefully designed volumes; designing for various particulates and viscosities; designing to thermal, mass, and power-limited spacecraft interfaces; and reducing risk. Prior art inlets for similar instruments in spaceflight were designed primarily for atmospheric gas sampling and are not useful for this front-end application. These cryogenic liquid sample acquisition system designs for remote space applications allow for remote, autonomous, controlled sample collections of a range of challenging cryogenic sample types. The design can control the size of the sample, prevent fractionation, control pressures at various stages, and allow for various liquid sample levels. It is capable of collecting repeated samples autonomously in difficult lowtemperature conditions often found in planetary missions. It is capable of collecting samples for use by instruments from difficult sample types such as cryogenic hydrocarbon (methane, ethane, and propane) mixtures with solid particulates such as found on Titan. The design with a warm actuated valve is compatible with various spacecraft thermal and structural interfaces. The design uses controlled volumes, heaters, inlet and vent tubes, a cryogenic valve seat, inlet screens, temperature and cryogenic liquid sensors, seals, and vents to accomplish its task.

  13. On the abundance and general nature of the liquid-liquid phase transition in molecular systems

    International Nuclear Information System (INIS)

    Kurita, Rei; Tanaka, Hajime

    2005-01-01

    Even a single-component liquid may have more than two kinds of isotropic liquid states. The transition between these different states is called a liquid-liquid transition (LLT). An LLT has been considered to be a rather rare phenomenon, in particular for molecular liquids. Very recently, however, we found an LLT in triphenyl phosphite, which may be the first experimental observation of an LLT for molecular liquids. Here we report convincing evidence of the second example of LLT for another molecular liquid, n-butanol. Despite large differences in the chemical structure and the molecular shape between triphenyl phosphite and n-butanol, the basic features of the transformation kinetics are strikingly similar. This suggests that an LLT may not be a rare phenomenon restricted to specific liquids, but may exist in various molecular liquids, which have a tendency to form long-lived locally favoured structures due to anisotropic interactions (e.g., hydrogen bonding). (letter to the editor)

  14. Identification of chemical compounds in a liquid-liquid extraction system

    International Nuclear Information System (INIS)

    Ramirez C, F de M de la.

    1980-01-01

    The objective of the present work is to identify the chemical compounds that are distributed in a liquid-liquid extraction system in which the third phase is observed; for this purpose the FeCl 3 (0.12M) - HCl (8.43M) - Diisopropilic ether - system was used, for the quantitative determination of the chemical compounds, FeCl 3 solutions labelled with 59 Fe or witH 38 Cl were used; the Karl Fischer method for the determination of the water concentration at the organic phases was used, the obtained data was used for the calculations of the H + distribution in each phase. The results are that when the distribution equilibrium is reached, the aqueous phase is a 7.5M HCl solution; the light organic phase contains 2 H[FeCl 4 ].6H 2 O and the dense organic phase contains 2 H[FeCl 4 ].6H 2 O.3HCl.12H 2 O. The differences between these compounds are due to a high concentration of water and the HCl in the organic solvent. This causes a heterogeneous physic field, and then the third phase formation. (author)

  15. 21 CFR 862.2250 - Gas liquid chromatography system for clinical use.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Gas liquid chromatography system for clinical use... Instruments § 862.2250 Gas liquid chromatography system for clinical use. (a) Identification. A gas liquid chromatography system for clinical use is a device intended to separate one or more drugs or compounds from a...

  16. 21 CFR 862.2260 - High pressure liquid chromatography system for clinical use.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 8 2010-04-01 2010-04-01 false High pressure liquid chromatography system for... Clinical Laboratory Instruments § 862.2260 High pressure liquid chromatography system for clinical use. (a) Identification. A high pressure liquid chromatography system for clinical use is a device intended to separate...

  17. Development of Liquid Propulsion Systems Testbed at MSFC

    Science.gov (United States)

    Alexander, Reginald; Nelson, Graham

    2016-01-01

    As NASA, the Department of Defense and the aerospace industry in general strive to develop capabilities to explore near-Earth, Cis-lunar and deep space, the need to create more cost effective techniques of propulsion system design, manufacturing and test is imperative in the current budget constrained environment. The physics of space exploration have not changed, but the manner in which systems are developed and certified needs to change if there is going to be any hope of designing and building the high performance liquid propulsion systems necessary to deliver crew and cargo to the further reaches of space. To further the objective of developing these systems, the Marshall Space Flight Center is currently in the process of formulating a Liquid Propulsion Systems testbed, which will enable rapid integration of components to be tested and assessed for performance in integrated systems. The manifestation of this testbed is a breadboard engine configuration (BBE) with facility support for consumables and/or other components as needed. The goal of the facility is to test NASA developed elements, but can be used to test articles developed by other government agencies, industry or academia. Joint government/private partnership is likely the approach that will be required to enable efficient propulsion system development. MSFC has recently tested its own additively manufactured liquid hydrogen pump, injector, and valves in a BBE hot firing. It is rapidly building toward testing the pump and a new CH4 injector in the BBE configuration to demonstrate a 22,000 lbf, pump-fed LO2/LCH4 engine for the Mars lander or in-space transportation. The value of having this BBE testbed is that as components are developed they may be easily integrated in the testbed and tested. MSFC is striving to enhance its liquid propulsion system development capability. Rapid design, analysis, build and test will be critical to fielding the next high thrust rocket engine. With the maturity of the

  18. A Historical Systems Study of Liquid Rocket Engine Throttling Capabilities

    Science.gov (United States)

    Betts, Erin M.; Frederick, Robert A., Jr.

    2010-01-01

    This is a comprehensive systems study to examine and evaluate throttling capabilities of liquid rocket engines. The focus of this study is on engine components, and how the interactions of these components are considered for throttling applications. First, an assessment of space mission requirements is performed to determine what applications require engine throttling. A background on liquid rocket engine throttling is provided, along with the basic equations that are used to predict performance. Three engines are discussed that have successfully demonstrated throttling. Next, the engine system is broken down into components to discuss special considerations that need to be made for engine throttling. This study focuses on liquid rocket engines that have demonstrated operational capability on American space launch vehicles, starting with the Apollo vehicle engines and ending with current technology demonstrations. Both deep throttling and shallow throttling engines are discussed. Boost and sustainer engines have demonstrated throttling from 17% to 100% thrust, while upper stage and lunar lander engines have demonstrated throttling in excess of 10% to 100% thrust. The key difficulty in throttling liquid rocket engines is maintaining an adequate pressure drop across the injector, which is necessary to provide propellant atomization and mixing. For the combustion chamber, cooling can be an issue at low thrust levels. For turbomachinery, the primary considerations are to avoid cavitation, stall, surge, and to consider bearing leakage flows, rotordynamics, and structural dynamics. For valves, it is necessary to design valves and actuators that can achieve accurate flow control at all thrust levels. It is also important to assess the amount of nozzle flow separation that can be tolerated at low thrust levels for ground testing.

  19. The high pressure electronic control system in liquid chromatography

    International Nuclear Information System (INIS)

    Popescu, Stefan; Popeneciu, Gabriel; Toadere, Florin

    2002-01-01

    The Liquid Chromatography system can perform a wide variety of measurements and separations especially for the organic liquids, with maximum applications flexibility for less than half price of Gas Chromatography. The repeatability and accuracy of results in quantitative high pressure liquid chromatography are highly dependent on the reproducibility and accuracy of both integrated flow rate and mobile phase composition. Flow rate fluctuation leads to poor reproducibility in both integrated peak areas and retention times. Similarly, poor control of mobile phase composition will cause poor repeatability of retention time and peak heights. The our Solvent Delivery System SDS 200 is a single pump system which provides precise compensated flow rates from 0.01 to 10 mL/min, selectable upper pressure limits of 0 to 100 bar or 10 to 450 bar, and solvent compressibility correction. Ternary solvent system on-line mixing capability saves time, reduces solvent waste and provides more flexibility for difficult separations. The pump itself has two different displacement pistons which are used alternately on both suction and discharge, so that intake of the solvent are synchronous. The evacuated solvent from the two pump's chambers is mixed in the reference unit and then is supplied to the damping unit for flow ripple reduction. The SDS Electronic Module ensures the functions: controls the programmed flow rate, detects and shows the solvent pressure in solvent, supplies the step motor, measures and limits the solvent pressure. The control panel of SDS 200, contains a two-stages flow decimal programmer, a eight-positions knob for upper pressure limits, an alarm LED and a parallel port for connection to a PC system. (authors)

  20. Temperature control system for liquid-fed ceramic melters

    International Nuclear Information System (INIS)

    Westsik, J.H. Jr.

    1986-10-01

    A temperature-feedback system has been developed for controlling electrical power to liquid-fed ceramic melters (LFCM). Software, written for a microcomputer-based data acquisition and process monitoring system, compares glass temperatures with a temperature setpoint and adjusts the electrical power accordingly. Included in the control algorithm are steps to reject failed thermocouples, spatially average the glass temperatures, smooth the averaged temperatures over time using a digital filter, and detect foaming in the glass. The temperature control system has proved effective during all phases of melter operation including startup, steady operation, loss of feed, and shutdown. This system replaces current, power, and resistance feedback control systems used previously in controlling the LFCM process

  1. Distributed Health Monitoring System for Reusable Liquid Rocket Engines

    Science.gov (United States)

    Lin, C. F.; Figueroa, F.; Politopoulos, T.; Oonk, S.

    2009-01-01

    The ability to correctly detect and identify any possible failure in the systems, subsystems, or sensors within a reusable liquid rocket engine is a major goal at NASA John C. Stennis Space Center (SSC). A health management (HM) system is required to provide an on-ground operation crew with an integrated awareness of the condition of every element of interest by determining anomalies, examining their causes, and making predictive statements. However, the complexity associated with relevant systems, and the large amount of data typically necessary for proper interpretation and analysis, presents difficulties in implementing complete failure detection, identification, and prognostics (FDI&P). As such, this paper presents a Distributed Health Monitoring System for Reusable Liquid Rocket Engines as a solution to these problems through the use of highly intelligent algorithms for real-time FDI&P, and efficient and embedded processing at multiple levels. The end result is the ability to successfully incorporate a comprehensive HM platform despite the complexity of the systems under consideration.

  2. Liquid metal liner implosion systems with blade lattice for fusion

    International Nuclear Information System (INIS)

    Itoh, Yasuyuki; Fujiie, Yoichi

    1980-01-01

    In this paper, the liquid liner implosion systems with the blade lattice is proposed for the rotational stabilization of the liner inner surface which is facing a plasma in a fusion reactor. The blades are electrically conducting and inclined to the radial direction. Its major function is either acceleration or deceleration of the liner in the azimuthal direction. This system enables us to exclude the rotary mechanism for the liner rotation. In this system, the liner is formed as an annular flow of a liquid metal (the waterfall concept). Results show that there is no significant difference of the energy cost for the stabilization compared with the earlier proposed system where a liner is rotated rigidly before implosion. Furthermore, the application of the rotating blade lattice makes it possible to reduce the rotational kinetic energy required for the stabilization at turnaround, where the lattice acts as an impeller in the initial liner rotation. There is an optimum blade angle to maximize the compressed magnetic field energy inside the liner for a given driving energy. (author)

  3. System of the incineration for the liquid scintillation garbage

    International Nuclear Information System (INIS)

    Naba, Katsumi

    1981-12-01

    In Japan from 1980 the incineration of the used scintillation liquid has been permitted according to the safety guide regulation of Japan Scientific Technology Agency. This incineration method would disperse the radioactivity in local site and destroy the chemicals at the same time. This system are consist of three parts. (1) Filtration and pH. adjustment of liquid garbage. (2) Bubbling vaporization in closed cycle. The temperature of the solution inside vessel is kept from 65 0 C to 85 0 C and the solution is bubbled with nealy 4 0 C circulated air. After the end of distillation, water layer is separated from the organic chemical layer and put it down the drain according to the regulation. (3) The residue is mixed with only the distilled organic chemicals according to the next classification, thereafter incineration is carried out. (a) For under the radioactive concentration of 1 x 10 -3 μCi/ml, the mixed scintillation liquid are burned up in specially designed incinerator. (b) For over the level of 1 x 10 -3 μCi/ml, only the distilled organic chemicals are burned up and the residue will be sent to the Waste Disposal Site. (c) For under the water content of 5% these liquid garbage can be directly are burned up without distillation The residue seemed to be suitable for the combustion of the dried carcased animals as the auxiliary fuels. This incinerator will be able to use as room heater or water heater for the bath without radioactive contamination inside of install room. (author)

  4. Performance of the TGT liquid argon calorimeter and trigger system

    Science.gov (United States)

    Braunschweig, W.; Geulig, E.; Schöntag, M.; Siedling, R.; Wlochal, M.; Wotschack, J.; Cheplakov, A.; Feshchenko, A.; Kazarinov, M.; Kukhtin, V.; Ladygin, E.; Obudovskij, V.; Geweniger, C.; Hanke, P.; Kluge, E.-E.; Krause, J.; Putzer, A.; Rensch, B.; Schmidt, M.; Stenzel, H.; Tittel, K.; Wunsch, M.; Zerwas, D.; Ban, J.; Bruncko, D.; Jusko, A.; Kocper, B.; Aderholz, M.; Brettel, H.; Dulny, B.; Dydak, F.; Fent, J.; Huber, J.; Jakobs, K.; Oberlack, H.; Schacht, P.; Bogolyubsky, M. Y.; Chekulaev, S. V.; Kiryunin, A. E.; Kurchaninov, L. L.; Levitsky, M. S.; Maksimov, V. V.; Minaenko, A. A.; Moiseev, A. M.; Semenov, P. A.; Tikhonov, V. V.

    1996-02-01

    A novel concept of a liquid argon calorimeter, the "Thin Gap Turbine" (TGT) calorimeter, is presented. A TGT test module, equipped with specially developed cold front-end electronics in radiation hard GaAs technology, has been operated in a particle beam. Results on its performance are given. A 40 MHz FADC system with a "circular data store" and standalone readout and play-back capability has been developed to test the properties of the TGT detector for trigger purposes. Results on trigger efficiency, response and energy resolution are given.

  5. Performance of the TGT liquid argon calorimeter and trigger system

    International Nuclear Information System (INIS)

    Braunschweig, W.; Geuling, E.; Schoentag, M.

    1996-03-01

    A novel concept of a liquid argon calorimeter, the thin gap turbine (TGT) calorimeter, is presented. A TGT test module, equipped with specially developed cold front-end electronics in radiation hard GaAs technology, has been operated in a particle beam. Results on its performance are given. A 40 MHz FADC system with a circular data store and standalone readout and playback capability has been developed to test the properties of the TGT detector for trigger purposes. Results on trigger efficiency, response and energy resolution are given. (orig.)

  6. Performance of the TGT liquid argon calorimeter and trigger system

    Energy Technology Data Exchange (ETDEWEB)

    Braunschweig, W.; Geulig, E.; Schoentag, M.; Siedling, R.; Wlochal, M.; Wotschack, J.; Cheplakov, A.; Feshchenko, A.; Kazarinov, M.; Kukhtin, V.; Ladygin, E.; Obudovskij, V.; Geweniger, C.; Hanke, P.; Kluge, E.-E.; Krause, J.; Putzer, A.; Rensch, B.; Schmidt, M.; Stenzel, H.; Tittel, K.; Wunsch, M.; Zerwas, D.; Ban, J.; Bruncko, D.; Jusko, A.; Kocper, B.; Aderholz, M.; Brettel, H.; Dulny, B.; Dydak, F.; Fent, J.; Huber, J.; Jakobs, K.; Oberlack, H.; Schacht, P.; Bogolyubsky, M.Y.; Chekulaev, S.V.; Kiryunin, A.E.; Kurchaninov, L.L.; Levitsky, M.S.; Maksimov, V.V.; Minaenko, A.A.; Moiseev, A.M.; Semenov, P.A.; Tikhonov, V.V. [Tech. Hochschule Aachen (Germany). 1. Phys. Inst.]|[CERN, Geneva (Switzerland)]|[Joint Institute for Nuclear Research, Dubna (Russian Federation)]|[Institut fuer Hochenergiephysik der Universitaet Heidelberg, Heidelberg (Germany)]|[Institute of Experimental Physics, Slovak Academy of Sciences, Kosice (Slovakia)]|[Max-Planck-Institut fuer Physik, Muenchen (Germany)]|[Institute for High Energy Physics, Protvino (Russian Federation)

    1996-08-21

    A novel concept of a liquid argon calorimeter, the ``thin gap turbine`` (TGT) calorimeter, is presented. A TGT test module, equipped with specially developed cold front-end electronics in radiation hard GaAs technology, has been operated in a particle beam. Results on its performance are given. A 40 MHz FADC system with a ``circular data store`` and standalone readout and play-back capability has been developed to test the properties of the TGT detector for trigger purposes. Results on trigger efficiency, response and energy resolution are given. (orig.).

  7. Performance of the TGT liquid argon calorimeter and trigger system

    International Nuclear Information System (INIS)

    Braunschweig, W.; Geulig, E.; Schoentag, M.

    1996-01-01

    A novel concept of a liquid argon calorimeter, the 'Thin Gap Turbine' (TGT) calorimeter, is presented. A TGT test module, equipped with specially developed cold front-end electronics in radiation hard GaAs technology, has been operated in a particle beam. Results on its performance are given. A 40 MHz FADC system with a 'circular data store' and standalone readout and playback capability has been developed to test the properties of the TGT detector for trigger purposes. Results on trigger efficiency, response and energy resolution are given. 12 refs., 21 figs., 6 tabs

  8. Performance of the TGT liquid argon calorimeter and trigger system

    International Nuclear Information System (INIS)

    Braunschweig, W.; Geulig, E.; Schoentag, M.; Siedling, R.; Wlochal, M.; Wotschack, J.; Cheplakov, A.; Feshchenko, A.; Kazarinov, M.; Kukhtin, V.; Ladygin, E.; Obudovskij, V.; Geweniger, C.; Hanke, P.; Kluge, E.-E.; Krause, J.; Putzer, A.; Rensch, B.; Schmidt, M.; Stenzel, H.; Tittel, K.; Wunsch, M.; Zerwas, D.; Ban, J.; Bruncko, D.; Jusko, A.; Kocper, B.; Aderholz, M.; Brettel, H.; Dulny, B.; Dydak, F.; Fent, J.; Huber, J.; Jakobs, K.; Oberlack, H.; Schacht, P.; Bogolyubsky, M.Y.; Chekulaev, S.V.; Kiryunin, A.E.; Kurchaninov, L.L.; Levitsky, M.S.; Maksimov, V.V.; Minaenko, A.A.; Moiseev, A.M.; Semenov, P.A.; Tikhonov, V.V.

    1996-01-01

    A novel concept of a liquid argon calorimeter, the ''thin gap turbine'' (TGT) calorimeter, is presented. A TGT test module, equipped with specially developed cold front-end electronics in radiation hard GaAs technology, has been operated in a particle beam. Results on its performance are given. A 40 MHz FADC system with a ''circular data store'' and standalone readout and play-back capability has been developed to test the properties of the TGT detector for trigger purposes. Results on trigger efficiency, response and energy resolution are given. (orig.)

  9. Modelling of liquid injection shutdown system (LISS) in ACR-1000

    International Nuclear Information System (INIS)

    Boubcher, M.; Colton, A.; Donnelly, J.V.

    2008-01-01

    Modelling of the Liquid Injection Shutdown System (LISS) in the ACR-1000 reactor core must account for the major phenomena that occur following its activation, namely the moderator hydraulics and core neutronics. The former requires modelling of the poison volumes, their time of entry into the reactor, and their propagation into the moderator after emission from the nozzle. The latter requires the reactivity worth of varying volumes and geometries of poisoned moderator fluid in order to simulate the reactivity effect of the injected poison. The time-dependent poison map is generated from hydraulic calculations, and then the neutronics data for standard geometries and concentrations is constructed using DRAGON. (author)

  10. Treatment systems for liquid wastes generated in chemical analysis laboratories

    International Nuclear Information System (INIS)

    Linda Berrio; Oscar Beltran; Edison Agudelo; Santiago Cardona

    2012-01-01

    Nowadays, handling of liquid wastes from chemical analysis laboratories is posing problems to different public and private organizations because of its requirements of an integrated management. This article reviews various treatment technologies and its removal efficiencies in order to establish criteria for selecting the system and the appropriate variables to achieve research objectives as well as environmental sustainability. Review begins with a description of the problem and continues with the study of treatments for laboratory wastes. These technologies are segregated into physicochemical and biological treatments that comprise a variety of processes, some of which are considered in this review.

  11. Study of Baffle Boundary and System Parameters on Liquid-Solid Coupling Vibration of Rectangular Liquid-Storage Structure

    Directory of Open Access Journals (Sweden)

    Wei Jing

    2016-01-01

    Full Text Available In order to study the vibration problem of liquid-solid coupling of rectangular liquid-storage structure with horizontal elastic baffle, ignoring the influence of surface gravity wave, two different velocity potential functions corresponding to the liquid above and below the elastic baffle are assumed; based on the theory of mathematical equation and energy method, the formulas of basic frequency of liquid-solid coupling vibration system are derived, the baffle joined to the tank wall with 3 kinds of boundary conditions, namely, four edges simply supported, two opposite edges clamped and two opposite edges simply supported, and four edges clamped; the influence rules of baffle length-width ratio, the ratio of baffle height to liquid level, baffle elastic modulus, baffle density, baffle thickness, and liquid density on the coupling vibration performance are studied. The results show that the frequency of the clamped boundary is minimum; the influences of baffle length-width ratio and relative height on the basic frequency are much greater than that of the other system parameters; the relation between baffle length-width ratio and the frequency is exponential, while baffle relative height has a parabola relation with the frequency; the larger the baffle length-width ratio, the closer the baffle to the liquid level; the coupling frequency will be reduced more obviously.

  12. (Liquid + liquid) equilibria of four alcohol–water systems containing 1,8-cineole at T = 298.15 K

    International Nuclear Information System (INIS)

    Li, Hengde; Feng, Zhangni; Wan, Li; Huang, Cheng; Zhang, Tianfei; Fang, Yanxiong

    2016-01-01

    Graphical abstract: (Liquid + liquid) equilibria of C_1–C_4 alcohol–water systems containing 1,8-cineole are presented. Distribution ratios of alcohol in the mixtures are examined. The immiscible region of the LLE systems is evaluated and discussed. - Highlights: • Ternary (liquid + liquid) equilibria containing 1,8-cineole are presented. • Distribution ratios of C_1–C_4 alcohol in the mixtures are examined. • The LLE values were correlated using the NRTL and UNIQUAC models. - Abstract: As an eco-friendly compound from essential oils, 1,8-cineole (cineole, eucalyptol) has the potential to replace the ozone depleting industrial solvents. This paper presents experimental (liquid + liquid) equilibrium (LLE) data for four alcohol–water systems containing 1,8-cineole. To evaluate the phase equilibrium properties of 1,8-cineole in aqueous alcohol mixtures, LLE values for the ternary systems (water + methanol or ethanol or 1-propanol or 1-butanol + 1,8-cineole) were determined with a tie-line method at T = 298.15 K under atmospheric pressure. The well-known Hand, Bachman and Othmer–Tobias equations were used to test the reliability of the experimental results. The binodal curves and distribution ratios of alcohol in the mixtures are shown and discussed. The experimental LLE values were satisfactorily correlated by the NRTL and UNIQUAC models.

  13. Radiant{trademark} Liquid Radioisotope Intravascular Radiation Therapy System

    Energy Technology Data Exchange (ETDEWEB)

    Eigler, N.; Whiting, J.; Chernomorsky, A.; Jackson, J.; Knapp, F.F., Jr.; Litvack, F.

    1998-01-16

    RADIANT{trademark} is manufactured by United States Surgical Corporation, Vascular Therapies Division, (formerly Progressive Angioplasty Systems). The system comprises a liquid {beta}-radiation source, a shielded isolation/transfer device (ISAT), modified over-the-wire or rapid exchange delivery balloons, and accessory kits. The liquid {beta}-source is Rhenium-188 in the form of sodium perrhenate (NaReO{sub 4}), Rhenium-188 is primarily a {beta}-emitter with a physical half-life of 17.0 hours. The maximum energy of the {beta}-particles is 2.1 MeV. The source is produced daily in the nuclear pharmacy hot lab by eluting a Tungsten-188/Rhenium-188 generator manufactured by Oak Ridge National Laboratory (ORNL). Using anion exchange columns and Millipore filters the effluent is concentrated to approximately 100 mCi/ml, calibrated, and loaded into the (ISAT) which is subsequently transported to the cardiac catheterization laboratory. The delivery catheters are modified Champion{trademark} over-the-wire, and TNT{trademark} rapid exchange stent delivery balloons. These balloons have thickened polyethylene walls to augment puncture resistance; dual radio-opaque markers and specially configured connectors.

  14. Liquid radioactive waste processing system in Improved OPR-1000

    International Nuclear Information System (INIS)

    Lee, Soonmin; Kim, Kiljung; Park, Jungsu

    2008-01-01

    The design goal of liquid rad waste system is to minimize the release of radioactive materials to the environment, the occupational radiation exposure to workers, and the solid rad waste volume generated from LRS operation. In 1998, KOPEC in conjunction with KHNP (Korea Hydro and Nuclear Power Co.) started a special task study which had been focused on the worldwide advanced technologies in the liquid rad waste process area by considering the design goals above. As a result of this task, KOPEC and KHNP finally decided to adopt a reverse osmosis processing method for Improved OPR-1000 in Korea. The advanced LRS design incorporating the R/O process has been introduced into Shin-Wolsong 1 and 2 (SWN 1 and 2) as well as Shin-Kori 1 and 2 (SKN 1 and 2), which are recently under construction, and also is adopted for Shin-Kori 3 and 4 (SKN 3 and 4) and Shin-Ulchin 1 and 2 (SUN 1 and 2), which are planned for the near future construction as the first APR-1400 type of Korean reactors. The LRS shop performance test for SKN 1 and 2 (Improved OPR-1000 R/O package system) was conducted by DOOSAN and DTS (Diversified Technologies Services, Inc) in January, 2008. The purpose of the test was to demonstrate the performance of actual R/O system to be installed in SKN 1 and 2 site. In this paper, overall system configuration and the shop performance test result is presented based on Improved OPR-1000 LRS R/O Package system

  15. Plasma Reforming of Liquid Hydrocarbon Fuels in Non-Thermal Plasma-Liquid Systems

    Science.gov (United States)

    2010-04-30

    channel with liquid wall in the microporous media under the ultrasound cavitations has shown the following: · The action of the ultrasound field in the...microporous liquid which has a very large ratio of the plasma-liquid contact surface to the plasma volume. As is known the ultrasonic (US) cavitation is a very...2) and it ran over a flat dielectric surface of the magnetostrictive transmitter (5) which produced ultrasonic (US) cavitations , so the discharge

  16. Identifying Liquid-Gas System Misconceptions and Addressing Them Using a Laboratory Exercise on Pressure-Temperature Diagrams of a Mixed Gas Involving Liquid-Vapor Equilibrium

    Science.gov (United States)

    Yoshikawa, Masahiro; Koga, Nobuyoshi

    2016-01-01

    This study focuses on students' understandings of a liquid-gas system with liquid-vapor equilibrium in a closed system using a pressure-temperature ("P-T") diagram. By administrating three assessment questions concerning the "P-T" diagrams of liquid-gas systems to students at the beginning of undergraduate general chemistry…

  17. Total hydrocarbon content (THC) testing in liquid oxygen (LOX) systems

    Science.gov (United States)

    Meneghelli, B. J.; Obregon, R. E.; Ross, H. R.; Hebert, B. J.; Sass, J. P.; Dirschka, G. E.

    2015-12-01

    The measured Total Hydrocarbon Content (THC) levels in liquid oxygen (LOX) systems at Stennis Space Center (SSC) have shown wide variations. Examples of these variations include the following: 1) differences between vendor-supplied THC values and those obtained using standard SSC analysis procedures; and 2) increasing THC values over time at an active SSC test stand in both storage and run vessels. A detailed analysis of LOX sampling techniques, analytical instrumentation, and sampling procedures will be presented. Additional data obtained on LOX system operations and LOX delivery trailer THC values during the past 12-24 months will also be discussed. Field test results showing THC levels and the distribution of the THC's in the test stand run tank, modified for THC analysis via dip tubes, will be presented.

  18. Quaternary isobaric (vapor + liquid + liquid) equilibrium and (vapor + liquid) equilibrium for the system (water + ethanol + cyclohexane + heptane) at 101.3 kPa

    International Nuclear Information System (INIS)

    Pequenin, Ana; Asensi, Juan Carlos; Gomis, Vicente

    2011-01-01

    Highlights: → Water-ethanol-cyclohexane-heptane and water-cyclohexane-heptane isobaric VLLE. → Isobaric experimental data were determined at 101.3 kPa. → A dynamic recirculating still with an ultrasonic homogenizer was used. → The quaternary system does not present quaternary azeotropes. - Abstract: Experimental isobaric (vapor + liquid + liquid) and (vapor + liquid) equilibrium data for the ternary system {water (1) + cyclohexane (2) + heptane (3)} and the quaternary system {water (1) + ethanol (2) + cyclohexane (3) + heptane (4)} were measured at 101.3 kPa. An all-glass, dynamic recirculating still equipped with an ultrasonic homogenizer was used to determine the VLLE. The results obtained show that the system does not present quaternary azeotropes. The point-by-point method by Wisniak for testing the thermodynamic consistency of isobaric measurements was used to test the equilibrium data.

  19. Universality classes and critical phenomena in confined liquid systems

    Directory of Open Access Journals (Sweden)

    A.V. Chalyi

    2013-06-01

    Full Text Available It is well known that the similar universal behavior of infinite-size (bulk systems of different nature requires the same basic conditions: space dimensionality; number components of order parameter; the type (short- or long-range of the intermolecular interaction; symmetry of the fluctuation part of thermodynamical potential. Basic conditions of similar universal behavior of confined systems needs the same supplementary conditions such as the number of monolayers for a system confinement; low crossover dimensionality, i.e., geometric form of restricted volume; boundary conditions on limiting surfaces; physical properties under consideration. This review paper is aimed at studying all these conditions of similar universal behavior for diffusion processes in confined liquid systems. Special attention was paid to the effects of spatial dispersion and low crossover dimensionality. This allowed us to receive receiving correct nonzero expressions for the diffusion coefficient at the critical point and to take into account the specific geometric form of the confined liquid volume. The problem of 3D⇔2D dimensional crossover was analyzed. To receive a smooth crossover for critical exponents, the Kawasaki-like approach from the theory of mode coupling in critical dynamics was proposed. This ensured a good agreement between data of computer experiment and theoretical calculations of the size dependence of the critical temperature Tc(H of water in slitlike pores. The width of the quasi-elastic scattering peak of slow neutrons near the structural phase transition in the aquatic suspensions of plasmatic membranes (mesostructures with the typical thickness up to 10 nm was studied. It was shown that the width of quasi-elastic peak of neutron scattering decreases due to the process of cell proliferation, i.e., with an increase of the membrane size (including the membrane thickness. Thus, neutron studies could serve as an additional diagnostic test for the

  20. Computer simulation of confined and flexoelectric liquid crystalline systems

    International Nuclear Information System (INIS)

    Barmes, F.

    2003-01-01

    In this Thesis, systems of confined and flexoelectric liquid crystal systems have been studied using molecular computer simulations. The aim of this work was to provide a molecular model of a bistable display cell in which switching is induced through the application of directional electric field pulses. In the first part of this Thesis, the study of confined systems of liquid crystalline particles has been addressed. Computation of the anchoring phase diagrams for three different surface interaction models showed that the hard needle wall and rod-surface potentials induce both planar and homeotropic alignment separated by a bistability region, this being stronger and wider for the rod-surface varant. The results obtained using the rod-sphere surface model, in contrast, showed that tilled surface arrangements can be induced by surface absorption mechanisms. Equivalent studies of hybrid anchored systems showed that a bend director structure can be obtained in a slab with monostable homeotropic anchoring at the top surface and bistable anchoring at the bottom, provided that the slab height is sufficiently large and the top homeotropic anchoring is not too strong. In the second part of the Thesis, the development of models for tapered (pear-shaped) mesogens has been addressed. The first model considered, the truncated Stone expansion model, proved to be unsuccessful in that it did not display liquid crystalline phases. This drawback was then overcome using the alternative parametric hard Gaussian overlap model which was found to display a much richer phase behaviour. With a molecular elongation k = 5, both nematic and interdigitated smectic A 2 phases were obtained. In the final part of this Thesis, the knowledge acquired from the two previous studies was united in an attempt to model a bistable display cell. Switching between the hybrid aligned nematic and vertical states of the cell was successfully performed using pear shaped particles with both dielectric and

  1. Fire fighting system for inflammable liquids and process using it

    International Nuclear Information System (INIS)

    Levillain, C.

    1988-01-01

    For fighting fires of flammable liquids, such as liquid sodium or hydrocarbons, a layer of floating spheres (cellular concrete or hollow metal) is maintained on the surface by a square or preferentially triangular-meshed metallic net [fr

  2. Process and fire extinguishing system for inflammable liquids

    International Nuclear Information System (INIS)

    Levillain, C.

    1988-01-01

    A fire on the surface of a flammable liquid is extinguished by spreading a compact layer of sphere of uniform diameter, floating on the liquid surface. Spheres are stored in a tank and run out by gravity [fr

  3. Thermodynamic modeling of ternary and quaternary (liquid + liquid) systems containing water, FeCl3, HCl and diisopropyl ether

    International Nuclear Information System (INIS)

    Milosevic, Miran; Hendriks, Ilse; Smits, Ralph E.R.; Schuur, Boelo; Haan, André B. de

    2013-01-01

    Highlights: • Literature data from various sources was validated experimentally. • Ternary and quaternary (liquid + liquid) systems were successfully described with the NRTL model. • Some deflection at higher HCl concentrations between model and data. • Additional data verification proved correctness of the literature data. -- Abstract: Liquid–liquid extraction using ethers as solvents is a potentially energy saving alternative for the concentration of aqueous ferric chloride solutions. Adequate thermodynamic models that describe the behavior of the resulting quaternary systems (FeCl 3 , ether, acid and water) are not available in the literature. In this paper, the development of an equilibrium description applying the NRTL-model is presented, including experimental validation and fitting of the NRTL-parameters on the validated data. Equilibrium experiments were performed for the ternary systems (water + HCl + DiPE) and (water + FeCl 3 + DiPE) and the obtained data is in good agreement with the results from Maljkovic et al.[37] and Cambell et al.[39]. Experimental data of the quaternary system is taken from Maljkovic et al.[37]. The obtained binary interaction parameters to describe the (liquid + liquid) quaternary system (water + FeCl 3 + HCl + DiPE) and the constituting ternaries by the NRTL model are presented. Model predictions are in good agreement with the experimental data

  4. An Overview of Liquid Fluoride Salt Heat Transport Systems

    Energy Technology Data Exchange (ETDEWEB)

    Holcomb, David Eugene [ORNL; Cetiner, Sacit M [ORNL

    2010-09-01

    Heat transport is central to all thermal-based forms of electricity generation. The ever increasing demand for higher thermal efficiency necessitates power generation cycles transitioning to progressively higher temperatures. Similarly, the desire to provide direct thermal coupling between heat sources and higher temperature chemical processes provides the underlying incentive to move toward higher temperature heat transfer loops. As the system temperature rises, the available materials and technology choices become progressively more limited. Superficially, fluoride salts at {approx}700 C resemble water at room temperature being optically transparent and having similar heat capacity, roughly three times the viscosity, and about twice the density. Fluoride salts are a leading candidate heat-transport material at high temperatures. Fluoride salts have been extensively used in specialized industrial processes for decades, yet they have not entered widespread deployment for general heat transport purposes. This report does not provide an exhaustive screening of potential heat transfer media and other high temperature liquids such as alkali metal carbonate eutectics or chloride salts may have economic or technological advantages. A particular advantage of fluoride salts is that the technology for their use is relatively mature as they were extensively studied during the 1940s-1970s as part of the U.S. Atomic Energy Commission's program to develop molten salt reactors (MSRs). However, the instrumentation, components, and practices for use of fluoride salts are not yet developed sufficiently for commercial implementation. This report provides an overview of the current understanding of the technologies involved in liquid salt heat transport (LSHT) along with providing references to the more detailed primary information resources. Much of the information presented here derives from the earlier MSR program. However, technology has evolved over the intervening years

  5. Branch-cut singularities in thermodynamics of Fermi liquid systems.

    Science.gov (United States)

    Shekhter, Arkady; Finkel'stein, Alexander M

    2006-10-24

    The recently measured spin susceptibility of the two-dimensional electron gas exhibits a strong dependence on temperature, which is incompatible with the standard Fermi liquid phenomenology. In this article, we show that the observed temperature behavior is inherent to ballistic two-dimensional electrons. Besides the single-particle and collective excitations, the thermodynamics of Fermi liquid systems includes effects of the branch-cut singularities originating from the edges of the continuum of pairs of quasiparticles. As a result of the rescattering induced by interactions, the branch-cut singularities generate nonanalyticities in the thermodynamic potential that reveal themselves in anomalous temperature dependences. Calculation of the spin susceptibility in such a situation requires a nonperturbative treatment of the interactions. As in high-energy physics, a mixture of the collective excitations and pairs of quasiparticles can effectively be described by a pole in the complex momentum plane. This analysis provides a natural explanation for the observed temperature dependence of the spin susceptibility, both in sign and in magnitude.

  6. The Nature and Assessment of Systemic Risk in Terms of Liquidity of the Banking System

    Directory of Open Access Journals (Sweden)

    Lavreniuk Vladyslav V.

    2016-11-01

    Full Text Available The aim of the article is to determine the nature of systemic risk as a threat to the financial stability of the banking system and develop analytical tools to assess its impact on the banking system in terms of its liquidity. To solve the tasks assigned, there used general scientific and specific methods, such as: logical and dialectical method, mathematical and graphical one. Based on the generalization, analysis and comparison of different interpretations, there clarified the concept of «systemic risk» as a risk generated by financial institutions or individual sectors through the implementation of the mechanism of risk transmission, achieving significant scale of distribution and adversely affecting the stability of the financial system and the real sector of economy. There identified key aspects of systemic risk: a systemic risk is not a sum of all individual risks of financial institutions; b spreads through the channels of interconnectedness between financial institutions; c is a result of accumulated structural imbalances; d affects the stability of the financial/banking system, public confidence and the real sector of economy. Analytical tools for estimation of the bank’s contribution to the systemic liquidity risk on the basis of which it is determined that the first place in terms of the effect on the aggregate systemic risk of liquidity of the Ukrainian banking system is occupied by banks of Group I, the second place — by Privatbank, the third, fourth, fifth places — by banks in Group II — Oschadbank, Ukreximbank. It is found that it is systemically important state-owned banks that have a significant impact on systemic liquidity risk. It is determined that the probability of default of a leading systemically important bank could result in considerable cumulative losses for the entire banking system and real economy. The prospects of further research are the development of tools for systemic risk assessment with respect to

  7. Rational approach to solvent system selection for liquid-liquid extraction-assisted sample pretreatment in counter-current chromatography.

    Science.gov (United States)

    Wang, Jiajia; Gu, Dongyu; Wang, Miao; Guo, Xinfeng; Li, Haoquan; Dong, Yue; Guo, Hong; Wang, Yi; Fan, Mengqi; Yang, Yi

    2017-05-15

    A rational liquid-liquid extraction approach was established to pre-treat samples for high-speed counter-current chromatography (HSCCC). n-Hexane-ethyl acetate-methanol-water (4:5:4:5, v/v) and (1:5:1:5, v/v) were selected as solvent systems for liquid-liquid extraction by systematically screening K of target compounds to remove low- and high-polarity impurities in the sample, respectively. After liquid-liquid extraction was performed, 1.4g of crude sample II was obtained from 18.5g of crude sample I which was extracted from the flowers of Robinia pseudoacacia L., and then separated with HSCCC by using a solvent system composed of n-hexane-ethyl acetate-methanol-water (1:2:1:2, v/v). As a result, 31mg of robinin and 37mg of kaempferol 7-O-α-l-rhamnopyranoside were isolated from 200mg of crude sample II in a single run of HSCCC. A scale-up separation was also performed, and 160mg of robinin with 95% purity and 188mg of kaempferol 7-O-α-l-rhamnopyranoside with 97% purity were produced from 1.2g of crude sample II. Copyright © 2017 Elsevier B.V. All rights reserved.

  8. Method for determining efficiency in a liquid scintillation system

    International Nuclear Information System (INIS)

    Laney, B.H.

    1975-01-01

    In a liquid scintillation system utilizing plural photomultiplyier means, a method for determining efficiency of coincident pulse detection. Various incremental counting efficiency levels are associated with asymptotic functions in a two dimension matrix in which the abscissa and ordinate correspond to the pulse heights of each of a pair of coincident pulses from different photomultiplier means. An efficiency determining point is located in the matrix based on the sum of the pulse heights of each of the coincident pulses as well as on the amplitude of the smallest pulse of the coincident pulses. The single counting efficiency determining point is recorded as the level of efficiency at which the photomultiplier means detect scintillations that generate coincident pulses having pulse heights equal to those recorded. (Patent Office Record)

  9. Refrigeration system with a compressor-pump unit and a liquid-injection desuperheating line

    Science.gov (United States)

    Gaul, Christopher J.

    2001-01-01

    The refrigeration system includes a compressor-pump unit and/or a liquid-injection assembly. The refrigeration system is a vapor-compression refrigeration system that includes an expansion device, an evaporator, a compressor, a condenser, and a liquid pump between the condenser and the expansion device. The liquid pump improves efficiency of the refrigeration system by increasing the pressure of, thus subcooling, the liquid refrigerant delivered from the condenser to the expansion device. The liquid pump and the compressor are driven by a single driving device and, in this regard, are coupled to a single shaft of a driving device, such as a belt-drive, an engine, or an electric motor. While the driving device may be separately contained, in a preferred embodiment, the liquid pump, the compressor, and the driving device (i.e., an electric motor) are contained within a single sealable housing having pump and driving device cooling paths to subcool liquid refrigerant discharged from the liquid pump and to control the operating temperature of the driving device. In another aspect of the present invention, a liquid injection assembly is included in a refrigeration system to divert liquid refrigerant from the discharge of a liquid pressure amplification pump to a compressor discharge pathway within a compressor housing to desuperheat refrigerant vapor to the saturation point within the compressor housing. The liquid injection assembly includes a liquid injection pipe with a control valve to meter the volume of diverted liquid refrigerant. The liquid injection assembly may also include a feedback controller with a microprocessor responsive to a pressure sensor and a temperature sensor both positioned between the compressor to operate the control valve to maintain the refrigerant at or near saturation.

  10. 324 Building liquid waste handling and removal system project plan

    Energy Technology Data Exchange (ETDEWEB)

    Ham, J.E.

    1998-07-29

    This report evaluates the modification options for handling radiological liquid waste generated during decontamination and cleanout of the 324 Building. Recent discussions indicate that the Hanford site railroad system will be closed by the end of FY 1998 necessitating the need for an alternate transfer method. The issue of handling of Radioactive Liquid Waste (RLW) from the 324 Building (assuming the 340 Facility is not available to accept the RLW) has been examined in at least two earlier engineering studies (Parsons 1997a and Hobart 1997). Each study identified a similar preferred alternative that included modifying the 324 Building RLWS to allow load-out of wastewater to a truck tanker, while making maximum use of existing piping, tanks, instrumentation, controls and other features to minimize costs and physical changes to the building. This alternative is accepted as the basis for further discussion presented in this study. The goal of this engineering study is to verify the path forward presented in the previous studies and assure that the selected alternative satisfies the 324 Building deactivation goals and objectives as currently described in the project management plan. This study will also evaluate options available to implement the preferred alternative and select the preferred option for implementation of the entire system. Items requiring further examination will also be identified. Finally, the study will provide a conceptual design, schedule and cost estimate for the required modifications to the 324 Building to allow removal of RLW. Attachment 5 is an excerpt from the project baseline schedule found in the Project Management Plan.

  11. Competition, liquidity and stability: international evidence at the bank and systemic levels

    OpenAIRE

    Nguyen, Thi Ngoc My

    2017-01-01

    This thesis investigates the impact of market power on bank liquidity; the association between competition and systemic liquidity; and whether the associations between liquidity and stability at both bank- and systemic- levels are affected by competition. The first research question is explored in the context of 101 countries over 1996-2013 while the second and the third, which require listed banks, use a smaller sample of 32 nations during 2001-2013. The Panel Least Squares and the system Ge...

  12. Homogeneous Liquid–Liquid Extraction of Rare Earths with the Betaine—Betainium Bis(trifluoromethylsulfonyl)imide Ionic Liquid System

    Science.gov (United States)

    Hoogerstraete, Tom Vander; Onghena, Bieke; Binnemans, Koen

    2013-01-01

    Several fundamental extraction parameters such as the kinetics and loading were studied for a new type of metal solvent extraction system with ionic liquids. The binary mixture of the ionic liquid betainium bis(trifluoromethylsulfonyl)imide and water shows thermomorphic behavior with an upper critical solution temperature (UCST), which can be used to avoid the slower mass transfer due to the generally higher viscosity of ionic liquids. A less viscous homogeneous phase and mixing on a molecular scale are obtained when the mixture is heated up above 55 °C. The influence of the temperature, the heating and cooling times, were studied for the extraction of neodymium(III) with betaine. A plausible and equal extraction mechanism is proposed in bis(trifluoromethylsulfonyl)imide, nitrate, and chloride media. After stripping of the metals from the ionic liquid phase, a higher recovery of the ionic liquid was obtained by salting-out of the ionic liquid fraction lost by dissolution in the aqueous phase. The change of the upper critical solution temperature by the addition of HCl or betaine was investigated. In addition, the viscosity was measured below and above the UCST as a function of the temperature. PMID:24169434

  13. Melter viewing system for liquid-fed ceramic melters

    International Nuclear Information System (INIS)

    Westsik, J.H. Jr.; Brenden, B.B.

    1988-01-01

    Melter viewing systems are an integral component of the monitoring and control systems for liquid-fed ceramic melters. The Pacific Northwest Laboratory (PNL) has designed cameras for use with glass melters at PNL, the Hanford Waste Vitrification Plant (HWVP), and West Valley Demonstration Project (WVDP). This report is a compilation of these designs. Operating experiences with one camera designed for the PNL melter are discussed. A camera has been fabricated and tested on the High-Bay Ceramic Melter (HBCM) and the Pilot-Scale Ceramic Melter (PSCM) at PNL. The camera proved to be an effective tool for monitoring the cold cap formed as the feed pool developed on the molten glass surface and for observing the physical condition of the melter. Originally, the camera was built to operate using the visible light spectrum in the melter. It was later modified to operate using the infrared (ir) spectrum. In either configuration, the picture quality decreases as the size of the cold cap increases. Large cold caps cover the molten glass, reducing the amount of visible light and reducing the plenum temperatures below 600 0 C. This temperature corresponds to the lowest level of blackbody radiation to which the video tube is sensitive. The camera has been tested in melter environments for about 1900 h. The camera has withstood mechanical shocks and vibrations. The cooling system in the camera has proved effective in maintaining the optical and electronic components within acceptable temperature ranges. 10 refs., 15 figs

  14. Environmental system applied to radioactive liquid effluent release

    International Nuclear Information System (INIS)

    Nisti, Marcelo Bessa

    2009-01-01

    The current environmental administration considers the productive activity as an environmental system, defined as a group of processes, interactions, parameters and factors involved in the production. This mastering dissertation evaluated the release of the liquid radioactive effluents at Instituto de Pesquisas Energeticas e Nucleares (IPEN), under a systemic environmental study. The study evaluated the source term at IPEN in the period from 2004 to 2008, making use of gamma-ray and alpha spectrometry, instrumental neutron activation analysis, liquid phase scintillation and atomic absorption spectrometry. The employed methodologies were verified using samples from the Intercomparison National Program - PNI/IRD and Reference Materials. The facilities that contributed the most in these releases were the Radiopharmaceutical Center (CR) and the Research Reactor Center (CRPq) with an average of 11,4% and 87,4%, respectively, relative to the present radioactive activity. The sewer system releases were within the radioactive protection regulations, showing the effectiveness of IPEN's Radioactive Effluents Monitoring Program. The concentration of the stable elements Ag, Cd, Cr, Fe, Mn, Ni, Pb and Zn was determined in the liquid effluent in ali the samples from the storage tanks TR1 and CR in the period from 2004 to 2008 and in some of the samples of other IPEN's facilities in the period from 2004 to 2007. Among the analyzed effluents, two samples were higher than the stable elements discharge standards established in the state of Sao Paulo, one sample was higher than the required value of the element cadmium and the other higher than required value of the element zinco The storage tank TR1 discharge flow was estimated in 10,9 ± 0,9 m3 h -1 . The dilution factor at discharge point E1 was estimated using a radiotracers the isotopes 3 H, 137 CS, 60 Co, 54 Mn and 65 Zn, which are commonly released into IPEN's sewer system. The executed radiotracer study was carried out

  15. Ionic liquid and nanoparticle hybrid systems: Emerging applications.

    Science.gov (United States)

    He, Zhiqi; Alexandridis, Paschalis

    2017-06-01

    Having novel electronic and optical properties that emanate from their nano-scale dimensions, nanoparticles are central to numerous applications. Ionic liquids can confer to nanoparticle chemical protection and physicochemical property enhancement through intermolecular interactions and can consequently improve the stability and reusability of nanoparticle for various operations. With an aim to combine the novel properties of nanoparticles and ionic liquids, different structures have been generated, based on a balance of several intermolecular interactions. Such ionic liquid and nanoparticle hybrids are showing great potential in diverse applications. In this review, we first introduce various types of ionic liquid and nanoparticle hybrids, including nanoparticle colloidal dispersions in ionic liquids, ionic liquid-grafted nanoparticles, and nanoparticle-stabilized ionic liquid-based emulsions. Such hybrid materials exhibit interesting synergisms. We then highlight representative applications of ionic liquid and nanoparticle hybrids in the catalysis, electrochemistry and separations fields. Such hybrids can attain better stability and higher efficiency under a broad range of conditions. Novel and enhanced performance can be achieved in these applications by combining desired properties of ionic liquids and of nanoparticles within an appropriate hybrid nanostructure. Copyright © 2016 Elsevier B.V. All rights reserved.

  16. Process equipment waste and process waste liquid collection systems

    International Nuclear Information System (INIS)

    1990-06-01

    The US DOE has prepared an environmental assessment for construction related to the Process Equipment Waste (PEW) and Process Waste Liquid (PWL) Collection System Tasks at the Idaho Chemical Processing Plant. This report describes and evaluates the environmental impacts of the proposed action (and alternatives). The purpose of the proposed action would be to ensure that the PEW and PWL collection systems, a series of enclosed process hazardous waste, and radioactive waste lines and associated equipment, would be brought into compliance with applicable State and Federal hazardous waste regulations. This would be accomplished primarily by rerouting the lines to stay within the buildings where the lined floors of the cells and corridors would provide secondary containment. Leak detection would be provided via instrumented collection sumps locate din the cells and corridors. Hazardous waste transfer lines that are routed outside buildings will be constructed using pipe-in-pipe techniques with leak detection instrumentation in the interstitial area. The need for the proposed action was identified when a DOE-sponsored Resource Conservation and Recovery Act (RCRA) compliance assessment of the ICPP facilities found that singly-contained waste lines ran buried in the soil under some of the original facilities. These lines carried wastes with a pH of less than 2.0, which were hazardous waste according to the RCRA standards. 20 refs., 7 figs., 1 tab

  17. Aqueous biphasic systems involving alkylsulfate-based ionic liquids

    Energy Technology Data Exchange (ETDEWEB)

    Deive, Francisco J. [Instituto de Tecnologia Quimica e Biologica, UNL, Av. Republica, Apartado 127, 2780-901 Oeiras (Portugal); Department of Chemical Engineering, University of Vigo, P.O. Box 36310, Vigo (Spain); Rodriguez, Ana [Department of Chemical Engineering, University of Vigo, P.O. Box 36310, Vigo (Spain); Marrucho, Isabel M., E-mail: imarrucho@itqb.unl.pt [Instituto de Tecnologia Quimica e Biologica, UNL, Av. Republica, Apartado 127, 2780-901 Oeiras (Portugal); Rebelo, Luis P.N. [Instituto de Tecnologia Quimica e Biologica, UNL, Av. Republica, Apartado 127, 2780-901 Oeiras (Portugal)

    2011-11-15

    Highlights: > K{sub 3}PO{sub 4}, K{sub 2}CO{sub 3}, Na{sub 2}CO{sub 3}, and (NH{sub 4}){sub 2}SO{sub 4} act as phase promoter in aqueous solutions of ILs. > Remarkable influence of alkyl-chain length on solubility curves of alkylsulfate-based ILs. > Merchuck correlation was used for describing these systems. > {Delta}S{sub hyd} and Hofmeister series were used to discuss the different salting out effects. - Abstract: The specific effects of K{sub 3}PO{sub 4}, K{sub 2}CO{sub 3}, Na{sub 2}CO{sub 3}, and (NH{sub 4}){sub 2}SO{sub 4}, as high charge-density inorganic salts and thus inducers of the formation of aqueous biphasic systems (ABS) containing several ethyl-methylimidazolium alkylsulfate ionic liquids, C{sub 2}MIM C{sub n}SO{sub 4} (n = 2, 4, 6, or 8), have been assessed at T = 298.15 K. The results are analyzed in the light of the Hofmeister series. The influence of different alkyl chain lengths in the anion, together with the ability of the selected inorganic salts to induce the formation of ABS, is discussed. Phase diagrams have been determined through turbidimetry, including tie lines assignments from mass phase ratios according to the lever - arm rule. The Merchuck equation was satisfactorily used to correlate the solubility curve.

  18. 900-L liquid xenon cryogenic system operation for the MEG experiment

    CERN Document Server

    Haruyama, T; Mihara, S; Hisamatsu, Y; Iawamoto, W; Mori, T; Nishiguchi, H; Otani, W; Sawada, R; Uchiyama, Y; Nishitani, T

    2009-01-01

    A cryogenic system for the MEG (muon rare decay) experiment has started operation at the Paul Sherrer Institute in Zurich. The main part of the MEG detector is the 900-L liquid xenon calorimeter for gamma ray detection, equipped with 850 photo multipliers directly immersed in liquid xenon. A 200 W pulse tube cryocooler enabled LN2-free operation of this calorimeter. A liquid purification system; using a liquid pump and a zero boil-off 1000-L cryogenic buffer dewar is also included in the system. The first entire engineering run was carried out in November-December 2007 and satisfactory cryogenic performances were confirmed.

  19. The Daily Liquidity Effect in a Floor System – Empirical Evidence from the Norwegian

    OpenAIRE

    Syrstad, Olav

    2013-01-01

    This paper analyses the liquidity effect in Norway by examining the relationship between a range of liquidity variables and five different measures of the short-term interbank premium. The models are estimated on data from January 2007 and up to the end of September 2011, a period in which Norges Bank implemented its liquidity policy within a so-called floor system, and prior to the new liquidity system introduced on 3 October 2011. In a floor system the key policy rate is equal to banks’ dep...

  20. The Daily Liquidity Effect in a Floor System – Empirical Evidence from the Norwegian Market

    OpenAIRE

    Syrstad, Olav

    2012-01-01

    This paper analyses the liquidity effect in Norway by examining the relationship between a range of liquidity variables and five different measures of the short-term interbank premium. The models are estimated on data from January 2007 and up to the end of September 2011, a period in which Norges Bank implemented its liquidity policy within a so-called floor system, and prior to the new liquidity system introduced on 3 October 2011. In a floor system the key policy rate is equal to banks' dep...

  1. Liquid-liquid phase equilibria for ternary systems of several polyethers with NaCl and H2O

    NARCIS (Netherlands)

    Milosevic, M.; Staal, K.J.J.; Schuur, Boelo; de Haan, A.B.

    2014-01-01

    Liquid–liquid extraction using polymers followed by induced phase separation is a potential energy reducing technology for water–salt separation. Ternary equilibrium data have been determined and reported for the (block co)poly ethers–sodium chloride–water systems at two different temperatures at

  2. Thermodynamic modeling of ternary and quaternary (liquid + liquid) systems containing water, FeCl3, HCl and diisopropyl ether

    NARCIS (Netherlands)

    Milosevic, M.; Hendriks, I.; Smits, R.E.R.; Schuur, B.; Haan, de A.B.

    2013-01-01

    Liquid–liquid extraction using ethers as solvents is a potentially energy saving alternative for the concentration of aqueous ferric chloride solutions. Adequate thermodynamic models that describe the behavior of the resulting quaternary systems (FeCl3, ether, acid and water) are not available in

  3. False alarm rates of liquid explosives detection systems

    NARCIS (Netherlands)

    Dzhongova, E.; Anderson, D.; Ruiter, J. de; Novakovic, V.; Ruiz Oses, M.

    2017-01-01

    Restrictions on the carriage of liquids, aerosol, and gels (LAGs) by airline passengers have been in place since November 2006, following the discovery of a terrorist plot involving homemade liquid explosives to be used on transatlantic flights (Wikipedia, 2006). Restrictions on the carriage of LAGs

  4. Hydroponic system for the treatment of anaerobic liquid.

    Science.gov (United States)

    Krishnasamy, K; Nair, J; Bäuml, B

    2012-01-01

    The effluent from anaerobic digestion process has high concentrations of nutrients, particularly nitrogen, essential for plant growth but is not suitable for direct disposal or application due to high chemical oxygen demand (COD), low dissolved oxygen (DO), odour issues and is potentially phytotoxic. This research explored the optimum conditions of anaerobic effluent for application and dilutions of the effluent required to obtain better plant growth. A small-scale hydroponic system was constructed in a glasshouse to test different concentrations of anaerobic effluent against a commercial hydroponic medium as the control for the growth of silverbeet. It was found that the survival of silverbeet was negatively affected at 50% concentration due to low DO and NH(4) toxicity. The concentration of 20% anaerobic liquid was found to be the most efficient with highest foliage yield and plant growth. The hydroponic system with 20% concentrated effluent had better utilisation of nutrients for plant growth and a COD reduction of 95% was achieved during the 50-day growth period. This preliminary evaluation revealed that the growth and development of silverbeet was significantly lower in anaerobic effluent compared with a commercial hydroponic plant growth solution. The nutrient quality of anaerobic effluent could be highly variable with the process and the waste material used and dilution may depend on the nutrient content of the effluent. It is recommended that, a pre-treatment of the effluent to increase DO and reduce ammonium content is required before plant application, and simple dilution by itself is not suitable for optimum plant growth in a hydroponic system.

  5. Regularity of solutions to the liquid crystals systems in R2 and R3

    International Nuclear Information System (INIS)

    Dai, Mimi; Qing, Jie; Schonbek, Maria

    2012-01-01

    In this paper, we establish regularity and uniqueness for solutions to density dependent nematic liquid crystals systems. The results presented extend the regularity and uniqueness for constant density liquid crystals systems, obtained by Lin and Liu (1995 Commun. Pure Appl. Math. XLVIII 501–37)

  6. Coolant Design System for Liquid Propellant Aerospike Engines

    Science.gov (United States)

    McConnell, Miranda; Branam, Richard

    2015-11-01

    Liquid propellant rocket engines burn at incredibly high temperatures making it difficult to design an effective coolant system. These particular engines prove to be extremely useful by powering the rocket with a variable thrust that is ideal for space travel. When combined with aerospike engine nozzles, which provide maximum thrust efficiency, this class of rockets offers a promising future for rocketry. In order to troubleshoot the problems that high combustion chamber temperatures pose, this research took a computational approach to heat analysis. Chambers milled into the combustion chamber walls, lined by a copper cover, were tested for their efficiency in cooling the hot copper wall. Various aspect ratios and coolants were explored for the maximum wall temperature by developing our own MATLAB code. The code uses a nodal temperature analysis with conduction and convection equations and assumes no internal heat generation. This heat transfer research will show oxygen is a better coolant than water, and higher aspect ratios are less efficient at cooling. This project funded by NSF REU Grant 1358991.

  7. Pipeline protection with multi component liquid polyurethane coating systems

    Energy Technology Data Exchange (ETDEWEB)

    Kuprion, Rainer; Hornig, Maja [TIB Chemicals Ag, Mannheim (Germany)

    2009-07-01

    Protective coating systems are one of the major defence mechanisms against corrosion for transmission pipelines, pipes within a refinery or petrochemical processing facilities. More and more pipelines are being constructed for the supply and transmission of gas and oil, each year but, in addition many existing pipelines are approaching an age where inspection reveals the necessity to consider complete refurbishment. However, the number of rehabilitation projects each year is still relatively small. Therefore, in the coming years, a rising need and necessity can be expected, for the owners and operating companies to be faced with the option of either replacing the pipeline or refurbishing of the existing pipeline. If the pipeline is known to have external corrosion, then safe and economic operation should be assured. Rehabilitation should be done before it is too late in order to ensure its future integrity and operational life. Rehabilitation of pipelines has been both the economic solution and, more significantly, the ecological solution and in many of those cases the coatings selected for the external protection has been multi component liquids based on 100% solids polyurethanes. (author)

  8. Coolant circulation system for a liquid metal nuclear reactor

    International Nuclear Information System (INIS)

    DeLuca, R.A.; Garabedian, G.

    1988-01-01

    This patent describes a liquid metal circulation system comprising an electromagnetic pump comprised of: (a) an elongated cylindrical pump support housing; (b) a cylindrical pressure dome structure coaxially situated and supported within the pump support housing, having a closed, hemispherical upper end and an open, cylindrical lower end; (c) a cylindrical pump coaxially situated within the pressure dome structure including: (1) a central core body of laminated transformer steel having six peripherally equally spaced helical grooves on its outer surface extending the entire length of the central core body, (2) a multiplicity of square, ceramic insulated copper wires situated in the helical grooves, (3) electrical leads extending from the terminal ends of the square copper wires through the upper end of the pressure dome structure and to a three-phase low voltage/high amperage power source, (4) an austenitic stainless steel jacket covering the outer surface of the central core body and covering the helically coiled square copper wires, the outer stainless steel jacket and the inner surface of the pressure dome structure defining an annular flow passage

  9. The liquid metastable miscibility gap in Cu-based systems

    DEFF Research Database (Denmark)

    Curiotto, S.; Greco, R.; Pryds, Nini

    2007-01-01

    Some Cu-based alloys, like Cu–Co, Cu–Fe and Cu–Co–Fe, display a liquid metastable miscibility gap. When the melt is undercooled below a certain temperature depending on the alloy composition, they present a separation in two liquid phases, followed by coagulation before dendritic solidification....... In order to predict the phase equilibria and the mechanisms of microstructure formation, a determination of the metastable monotectics in the phase diagrams is essential. This paper focuses on the up-to-date findings on the Cu–Co, Cu–Fe and Cu–Co–Fe metastable miscibility gap in the liquid phase...

  10. Prediction of liquid-liquid equilibria for polyethylene glycol based aqueous two-phase system by ASOG and UNIFAC method

    Directory of Open Access Journals (Sweden)

    M. Perumalsamy

    2009-03-01

    Full Text Available Liquid-Liquid equilibrium data were obtained for the polyethylene glycol2000(PEG2000-sodium citrate-water system at 298.15, 308.15 and 318.15 K. The effect of temperature on binodal and tie line data was studied and published in a previous article (Murugesan and Perumalsamy, 2005. The interaction parameters of ASOG and UNIFAC models were estimated using the LLE data of PEG2000-sodium citrate-water system and are used to predict the LLE data for PEG6000-sodium citrate-water system at 298.15, 308.15 and 318.15 K (literature data. The predicted LLE data by both ASOG and UNIFAC models showed good agreement with the experimental and literature data.

  11. Solid/liquid interfacial free energies in binary systems

    Science.gov (United States)

    Nason, D.; Tiller, W. A.

    1973-01-01

    Description of a semiquantitative technique for predicting the segregation characteristics of smooth interfaces between binary solid and liquid solutions in terms of readily available thermodynamic parameters of the bulk solutions. A lattice-liquid interfacial model and a pair-bonded regular solution model are employed in the treatment with an accommodation for liquid interfacial entropy. The method is used to calculate the interfacial segregation and the free energy of segregation for solid-liquid interfaces between binary solutions for the (111) boundary of fcc crystals. The zone of compositional transition across the interface is shown to be on the order of a few atomic layers in width, being moderately narrower for ideal solutions. The free energy of the segregated interface depends primarily upon the solid composition and the heats of fusion of the component atoms, the composition difference of the solutions, and the difference of the heats of mixing of the solutions.

  12. Liquid fuels from renewable resources in Canada: systems economics studies

    National Research Council Canada - National Science Library

    Osler, C. F

    1978-01-01

    This paper highlights the methodology and results of a six volume study completed for the Canadian government on alternatives for liquid fuel production from renewable resources after the mid-1980s...

  13. Decontamination of radioactive liquid systems by modified clay minerals

    OpenAIRE

    Petrushka, Ihor; Moroz, Olexandr

    2016-01-01

    The process mechanism for sorption of strontium and cesium from liquid radioactive waste using modified bentonites from Yaziv sulfur deposit was investigated. The technique for predicting the intensity of the sorption process based on the comparison of experimental and calculated values of mass transfer coefficients was proposed. It was detected that the process of sorption extraction of strontium and cesium from liquid medium using modified clay minerals may be bes...

  14. Development and Integration of the Janus Robotic Lander: A Liquid Oxygen-Liquid Methane Propulsion System Testbed

    Science.gov (United States)

    Ponce, Raul

    Initiatives have emerged with the goal of sending humans to other places in our solar system. New technologies are being developed that will allow for more efficient space systems to transport future astronauts. One of those technologies is the implementation of propulsion systems that use liquid oxygen and liquid methane (LO2-LCH4) as propellants. The benefits of a LO2-LCH4 propulsion system are plenty. One of the main advantages is the possibility of manufacturing the propellants at the destination body. A space vehicle which relies solely on liquid oxygen and liquid methane for its main propulsion and reaction control engines is necessary to exploit this advantage. At the University of Texas at El Paso (UTEP) MIRO Center for Space Exploration Technology Research (cSETR) such a vehicle is being developed. Janus is a robotic lander vehicle with the capability of vertical take-off and landing (VTOL) which integrates several LO2-LCH 4 systems that are being devised in-house. The vehicle will serve as a testbed for the parallel operation of these propulsion systems while being fed from common propellant tanks. The following work describes the efforts done at the cSETR to develop the first prototype of the vehicle as well as the plan to move forward in the design of the subsequent prototypes that will lead to a flight vehicle. In order to ensure an eventual smooth integration of the different subsystems that will form part of Janus, requirements were defined for each individual subsystem as well as the vehicle as a whole. Preliminary testing procedures and layouts have also been developed and will be discussed to detail in this text. Furthermore, the current endeavors in the design of each subsystem and the way that they interact with one another within the lander will be explained.

  15. Solid-Liquid Equilibrium in the Systems with an Ionic Liquid

    Czech Academy of Sciences Publication Activity Database

    Sedláková, Zuzana; Sauton, H.; Hynek, V.; Malijevská, I.

    2008-01-01

    Roč. 73, č. 5 (2008), s. 657-664 ISSN 0010-0765 R&D Projects: GA ČR GA104/07/0444; GA AV ČR IAA400720710 Institutional research plan: CEZ:AV0Z40720504 Keywords : experimental data * solid-liquid equlibrium * 1-butyl-3-methylimidazolium chloride Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 0.784, year: 2008

  16. Calculation of liquid-liquid phase separation in a ternary system of a polymer in a mixture of a solvent and a nonsolvent

    NARCIS (Netherlands)

    Altena, Frank W.; Smolders, C.A.

    1982-01-01

    A numerical method for the calculation of the binodal of liquid-liquid phase separation in a ternary system is described. The Flory-Huggins theory for three-component systems is used. Binodals are calculated for polymer/solvent/nonsolvent systems which are used in the preparation of asymmetric

  17. Extraction Equilibrium of Acrylic Acid by Aqueous Two-Phase Systems Using Hydrophilic Ionic Liquids

    International Nuclear Information System (INIS)

    Lee, Yong Hwa; Lee, Woo Youn; Kim, Ki-Sub; Hong, Yeon Ki

    2014-01-01

    As an effective method for extraction of acrylic acid, aqueous two-phase systems based on morpholinium ionic liquids were used in this study. Effects of the alkyl chain length of cation in morpholinium ionic liquids on phase diagram and extraction efficiencies were investigated. Experimental results show that aqueous two phase systems can be formed by adding appropriate amount of morpholinium ionic liquids to aqueous K 2 HPO 4 solutions. It can be found that the ability of morpholinium ionic liquids for phase separation followed the order [HMMor][Br]>[OMMor][Br]>[BMMor][Br]>[EMMor][Br]. There was little difference between binodal curves of imidazolium ionic liquids and those of morpholinium ionic liquids. 50-90% of the extraction efficiency was observed for acrylic acid by aqueous two phase extraction of acrylic acid with morpholinium ionic liquids. It can be concluded that morpholinium ionic liquids/K 2 HPO 4 were effective for aqueous two phases extraction of acrylic acid comparing to imidazolium ionic liquids/K 2 HPO 4 systems because of their lower cost

  18. Nuclear-station post-accident liquid-sampling system: developed by Duke Power Company

    International Nuclear Information System (INIS)

    Burton, D.A.; Birch, M.L.; Orth, W.C.

    1981-01-01

    The accident at Three Mile Island showed that means must be provided to determine the radioactivity levels in high activity liquid and gaseous systems of a nuclear power plant without undue radiation exposure to personnel. The Duke Power Post Accident Liquid Sampling System provides the means for obtaining diluted liquid samples and diluted dissolved gas samples following a reactor accident involving substantial core damage. Their approach yields a straightforward engineering solution at a fraction of the cost of other systems. A description of the system, general design criteria, and color coded flow diagrams are included

  19. Isobaric vapour-liquid-liquid equilibrium and vapour-liquid equilibrium for the system water + ethanol + iso-octane at 101.3 kPa

    OpenAIRE

    Ruiz Beviá, Francisco; Gomis Yagües, Vicente; Asensi Steegmann, Juan Carlos; Font Escamilla, Alicia

    2002-01-01

    Poster enviado a Equifase 2002, VI Iberoamerican Conference on Phase Equilibria for Process Design, Foz de Iguazú (Brazil), October 12th to 16th, 2002. Many studies have been carried out in the heterogeneous azeotropic distillation field either by experiment or by simulation. The development of all these studies requires the use of sets of isobaric vapour–liquid–liquid equilibrium (VLLE) data. However, the number of ternary systems with experimental VLLE data is very limited, since it is d...

  20. MEASUREMENT AND CORRELATION OF THE MASS TRANSFER COEFFICIENT FOR A LIQUID-LIQUID SYSTEM WITH HIGH DENSITY DIFFERENCE

    Directory of Open Access Journals (Sweden)

    Zhixian Huang

    Full Text Available Abstract To investigate the mass transfer behavior of a liquid-liquid system with high density difference (∆ρ≈500 kg/m3, single drop experiments were performed by using the ternary chloroform-ethanol-water system. The mass transfer direction was from the dispersed phase to the continuous phase, while the aqueous phase was dispersed in chloroform to generate drops. The influences of drop diameter, initial solute concentration and temperature on the mass transfer were investigated. The effects of the drop diameter and initial solute concentration on interfacial instability of droplets hanging in the continuous phase were also observed. For the purpose of correlation, a mass transfer enhancement factor F was introduced and then correlated as a function of dimensionless variables. The modified correlation from the mass transfer coefficient model was found to fit well with the experimental values.

  1. Phase equilibrium in systems with ionic liquids: An example for the downstream process of the Biphasic Acid Scavenging utilizing Ionic Liquids (BASIL) process. Part I: Experimental data

    International Nuclear Information System (INIS)

    Sahandzhieva, Katya; Maurer, Gerd

    2012-01-01

    Highlights: ► Phase equilibrium for a downstream process in sustainable chemical technology. ► Biphasic Acid Scavenging Utilizing Ionic Liquids (BASIL) Process. ► SLE, LLE, and SLLE of (NaCl + water + 1-propanol + 1-MIM) and its ternary subsystems. ► Experimental phase equilibrium data at temperatures between 298 K and 333 K. - Abstract: Experimental results are presented for the (liquid + liquid), (solid + liquid) and (solid + liquid + liquid) equilibria occurring in the downstream process of a typical example for the Biphasic Acid Scavenging Utilizing Ionic Liquids (BASIL)-processes. In a BASIL process an organic base is used to catalyze a chemical reaction and, at the same time, to scavenge an acid that is an undesired side product of that reaction. The particular example of a BASIL process treated here is the reaction of 1-butanol and acetylchloride to butylacetate and hydrochloric acid, where the acid is scavenged by the organic base 1-methyl imidazole (1-MIM) resulting in the ionic liquid 1-methyl imidazolium chloride. The reaction results in a two-phase system as butylacetate and the ionic liquid reveal a large liquid–liquid miscibility gap. The organic base has to be recovered. This is commonly achieved by treating the ionic liquid–rich liquid phase with an aqueous solution of sodium hydroxide (i.e., converting the ionic liquid to the organic base) and extracting the organic base by an appropriate organic solvent (e.g., 1-propanol). The work presented here deals in experimental work with the (liquid + liquid), (solid + liquid) and (solid + liquid + liquid) phase equilibria that are encountered in such extraction processes. Experimental results are reported for temperatures between about 298 K and 333 K: for the solubility of NaCl in several solvents (1-propanol, 1-MIM), (water + 1-MIM), (1-propanol + 1-MIM), (water + 1-propanol), and (water + 1-propanol + 1-MIM) and for the (liquid + liquid) equilibrium as well as for the (solid + liquid

  2. Emergency cooling system for a liquid metal cooled reactor

    International Nuclear Information System (INIS)

    Murata, Ryoichi; Fujiwara, Toshikatsu.

    1980-01-01

    Purpose: To suitably cool liquid metal as coolant in emergency in a liquid metal cooled reactor by providing a detector for the pressure loss of the liquid metal passing through a cooling device in a loop in which the liquid metal is flowed and communicating the detector with a coolant flow regulator. Constitution: A nuclear reactor is stopped in nuclear reaction by control element or the like in emergency. If decay heat is continuously generated for a while and secondary coolant is insufficiently cooled with water or steam flowed through a steam and water loop, a cooler is started. That is, low temperature air is supplied by a blower through an inlet damper to the cooler to cool the secondary coolant flowed into the cooler through a bypass pipe so as to finally safely stop an entire plant. Since the liquid metal is altered in its physical properties by the temperature at this time, it is detected to regulate the opening of the valve of the damper according to the detected value. (Sekiya, K.)

  3. Liquids - vapor and liquids - solids equilibria in the system Th(NO3)4 - UO2(NO3)2 - HNO3 - H2O

    International Nuclear Information System (INIS)

    Volk, V.I.; Vakhrushin, A.Yu.; Mamaev, S.L.; Zhirnov, Yu.P.

    1999-01-01

    Liquids - vapor and liquids - solids equilibria in the system Th(NO 3 ) 4 - UO 2 (NO 3 ) 2 - HNO 3 - H 2 O were investigated. It was established that in this system thorium nitrate hexahydrate and uranyl nitrate hexa- and trihydrate are formed. Empiric equations of solubility isotherm at 25 deg C were found. Densities of liquid phases of the system were determined. It was established that uranyl nitrates and thorium nitrates salt out nitric acid in vapor phase just as separately so in the case of mutual presence. Empiric equation fixing relationship between nitric acid concentration in condensed phase and concentrations of all components in liquid phase was found

  4. Modelling dynamic liquid-gas systems: Extensions to the volume-of-fluid solver

    CSIR Research Space (South Africa)

    Heyns, Johan A

    2013-06-01

    Full Text Available This study presents the extension of the volume-of-fluid solver, interFoam, for improved accuracy and efficiency when modelling dynamic liquid-gas systems. Examples of these include the transportation of liquids, such as in the case of fuel carried...

  5. Non-conventional solvents in liquid phase microextraction and aqueous biphasic systems.

    Science.gov (United States)

    An, Jiwoo; Trujillo-Rodríguez, María J; Pino, Verónica; Anderson, Jared L

    2017-06-02

    The development of rapid, convenient, and high throughput sample preparation approaches such as liquid phase microextraction techniques have been continuously developed over the last decade. More recently, significant attention has been given to the replacement of conventional organic solvents used in liquid phase microextraction techniques in order to reduce toxic waste and to improve selectivity and/or extraction efficiency. With these objectives, non-conventional solvents have been explored in liquid phase microextraction and aqueous biphasic systems. The utilized non-conventional solvents include ionic liquids, magnetic ionic liquids, and deep eutectic solvents. They have been widely used as extraction solvents or additives in various liquid phase microextraction modes including dispersive liquid-liquid microextraction, single-drop microextraction, hollow fiber-liquid phase microextraction, as well as in aqueous biphasic systems. This review provides an overview into the use of non-conventional solvents in these microextraction techniques in the past 5 years (2012-2016). Analytical applications of the techniques are also discussed. Copyright © 2017 Elsevier B.V. All rights reserved.

  6. Extensive Evaluation of the Conductor-like Screening Model for Real Solvents Method in Predicting Liquid-Liquid Equilibria in Ternary Systems of Ionic Liquids with Molecular Compounds.

    Science.gov (United States)

    Paduszyński, Kamil

    2018-04-12

    A conductor-like screening model for real solvents (COSMO-RS) is nowadays one of the most popular and commonly applied tools for the estimation of thermodynamic properties of complex fluids. The goal of this work is to provide a comprehensive review and analysis of the performance of this approach in calculating liquid-liquid equilibrium (LLE) phase diagrams in ternary systems composed of ionic liquid and two molecular compounds belonging to diverse families of chemicals (alkanes, aromatics, S/N-compounds, alcohols, ketones, ethers, carboxylic acid, esters, and water). The predictions are presented for extensive experimental database, including 930 LLE data sets and more than 9000 data points (LLE tie lines) reported for 779 unique ternary mixtures. An impact of the type of molecular binary subsystem on the accuracy of predictions is demonstrated and discussed on the basis of representative examples. The model's capability of capturing qualitative trends in the LLE distribution ratio and selectivity is also checked for a number of structural effects. Comparative analysis of two levels of quantum chemical theory (BP-TZVP-COSMO vs BP-TZVPD-FINE) for the input molecular data for COSMO-RS is presented. Finally, some general recommendations for the applicability of the model are indicated based on the analysis of the global performance as well as on the results obtained for systems relevant from the point of view of important separation problems.

  7. One- and zero-dimensional electron systems over liquid helium (Review article)

    CERN Document Server

    Kovdrya, Y Z

    2003-01-01

    Experimental and theoretical investigations of one-dimensional and zero-dimensional electron systems near the liquid helium surface are surveyed. The properties of electron states over the plane surface of liquid helium including thin layers of helium are considered. The methods of realization of one- and zero-dimensional electron systems are discussed, and the results of experimental and theoretical investigations of their properties are given. The experiments with localization processes in a quasi-one-dimensional electron systems on liquid helium are described. The collective effects in one-dimensional and quasi-one-dimensional electron systems are considered, and the point of possible application of low-dimensional electron systems on liquid helium in electron devices and quantum computers is discussed.

  8. On a hyperbolic system arising in liquid crystals modeling

    Czech Academy of Sciences Publication Activity Database

    Feireisl, Eduard; Rocca, E.; Schimperna, G.; Zarnescu, A.

    2018-01-01

    Roč. 15, č. 1 (2018), s. 15-35 ISSN 0219-8916 EU Projects: European Commission(XE) 320078 - MATHEF Institutional support: RVO:67985840 Keywords : dissipative solution * liquid crystal * weak-strong uniqueness Subject RIV: BA - General Mathematics OBOR OECD: Pure mathematics Impact factor: 0.940, year: 2016 https://www.worldscientific.com/doi/abs/10.1142/S0219891618500029

  9. Ionic liquids in separations of azeotropic systems – A review

    International Nuclear Information System (INIS)

    Pereiro, A.B.; Araújo, J.M.M.; Esperança, J.M.S.S.; Marrucho, I.M.; Rebelo, L.P.N.

    2012-01-01

    Highlights: ► This paper provides a review of methods using ionic liquids as azeotrope breakers. ► Azeotrope breaking potential of ILs was compared to that of conventional solvents. ► The influence of ILs structure on the azeotrope breaking capacity was accomplished. ► Guidelines to select the most suitable ILs as azeotrope breakers were established. - Abstract: Efforts to make existing separation methods more efficient and eco-friendly may get a boost from the use of a relatively new class of compounds known as ionic liquids (ILs). The separation of azeotropic mixtures has conventionally been one of the most challenging tasks in industrial processes due to the fact that their separation by simple distillation is basically impossible. This paper provides a critical review of methods using ILs as azeotrope breakers. Three separation processes were addressed: liquid–liquid extraction, extractive distillation, and supported liquid membranes. We examine the azeotrope breaking potential of ILs and compare their performance to that of conventional solvents. A systematic analysis of the influence of the structure of ILs on their azeotrope breaking capacity contributes to the establishment of guidelines for selecting the most suitable ILs for the separation of specific azeotropic mixtures.

  10. Wetting in a Colloidal Liquid-Gas System

    Science.gov (United States)

    Wijting, W. K.; Besseling, N. A.; Stuart, M. A.

    2003-05-01

    We present first observations of wetting phenomena in depletion interaction driven, phase separated colloidal dispersions (coated silica cyclohexane-polydimethylsiloxane). The contact angle of the colloidal liquid-gas interface at a solid substrate (coated glass) was determined for a series of compositions. Upon approach to the critical point, a transition occurs from partial to complete wetting.

  11. Wetting in a colloidal liquid-gas system

    OpenAIRE

    Wijting, W.K.; Besseling, N.A.M.; Cohen Stuart, M.A.

    2003-01-01

    We present first observations of wetting phenomena in depletion interaction driven, phase separated colloidal dispersions (coated silica-cyclohexane-polydimethylsiloxane). The contact angle of the colloidal liquid-gas interface at a solid substrate (coated glass) was determined for a series of compositions. Upon approach to the critical point, a transition occurs from partial to complete wetting.

  12. Wetting in a colloidal liquid-gas system

    NARCIS (Netherlands)

    Wijting, W.K.; Besseling, N.A.M.; Cohen Stuart, M.A.

    2003-01-01

    We present first observations of wetting phenomena in depletion interaction driven, phase separated colloidal dispersions (coated silica-cyclohexane-polydimethylsiloxane). The contact angle of the colloidal liquid-gas interface at a solid substrate (coated glass) was determined for a series of

  13. System Design Description Salt Well Liquid Pumping Dynamic Simulation

    International Nuclear Information System (INIS)

    HARMSEN, R.W.

    1999-01-01

    The Salt Well Liquid (SWL) Pumping Dynamic Simulation used by the single-shell tank (SST) Interim Stabilization Project is described. A graphical dynamic simulation predicts SWL removal from 29 SSTs using an exponential function and unique time constant for each SST. Increasing quarterly efficiencies are applied to adjust the pumping rates during fiscal year 2000

  14. Commissioning of the XENON1T liquid level measurement system

    Energy Technology Data Exchange (ETDEWEB)

    Geis, Christopher [Institut fuer Physik, Johannes Gutenberg-Universitaet, Mainz (Germany)

    2016-07-01

    Two-phase xenon time projection chambers (TPCs) have been operated very successfully in direct detection experiments for dark matter. This kind of detector uses liquid xenon as the sensitive target and is operated in two-phase (liquid/gas) mode, where the liquid level needs to be monitored and controlled with sub-millimeter precision. We present the installation, commissioning and first measurement data of two kinds of level meters operated in the XENON1T TPC: short level meters are three-plated capacitors measuring the level of the liquid-gas interface with a measurement range h∼5 mm and a resolution of ΔC/h∼1 pF/mm. The long level meters are cylindrical double-walled capacitors, measuring the overall filling level of the XENON1T TPC at a measurement range of h=1.4 m and a resolution of ΔC/h∼0.1 pF/mm. Further, we present the design and programming of the readout electronic based on the UTI chip by Smartec, which allows to read all six levelmeters simultaneously.

  15. Design of shutdown system no.2 liquid poison injection system for 500 MWe PHWR

    International Nuclear Information System (INIS)

    Bhatnagar, S.; Balasubrahmanian, A.K.; Pillai, A.V.

    1997-01-01

    Defence in depth and two group system concepts form the basic design philosophy for the shutdown systems. There are two independent, diverse and fast acting shutdown systems provided for the 500 MWe PHWR. The design is based on fail-safe principle, sufficient component redundancy and on-line testing. Liquid poison injection system, as shutdown system 2, is newly developed for the 500 MWe PHWRs. The system operates by rapidly injecting gadolinium nitrate solution into bulk moderator using stored helium pressure thereby inserting negative reactivity. A high pressure helium supply tank which provides the energy for system actuation, is connected, through an array of fast acting valves in series-parallel arrangement, to the individual poison tanks storing gadolinium nitrate solution. The valves, belonging to three different channels of reactor Protection System 2, are the only active components in the system. The valves are fail safe and are periodically tested on-line without actually firing the system. The system comprising of in-core assemblies and the external process system has been engineered. Experimental work is being carried out by BARC for design validation and data generation. This paper describes the conceptual development, design basis, design parameters and detailed engineering of the system. (author)

  16. High bulk modulus of ionic liquid and effects on performance of hydraulic system.

    Science.gov (United States)

    Kambic, Milan; Kalb, Roland; Tasner, Tadej; Lovrec, Darko

    2014-01-01

    Over recent years ionic liquids have gained in importance, causing a growing number of scientists and engineers to investigate possible applications for these liquids because of their unique physical and chemical properties. Their outstanding advantages such as nonflammable liquid within a broad liquid range, high thermal, mechanical, and chemical stabilities, low solubility for gases, attractive tribological properties (lubrication), and very low compressibility, and so forth, make them more interesting for applications in mechanical engineering, offering great potential for new innovative processes, and also as a novel hydraulic fluid. This paper focuses on the outstanding compressibility properties of ionic liquid EMIM-EtSO4, a very important physical chemically property when IL is used as a hydraulic fluid. This very low compressibility (respectively, very high Bulk modulus), compared to the classical hydraulic mineral oils or the non-flammable HFDU type of hydraulic fluids, opens up new possibilities regarding its usage within hydraulic systems with increased dynamics, respectively, systems' dynamic responses.

  17. System and method for liquid extraction electrospray-assisted sample transfer to solution for chemical analysis

    Science.gov (United States)

    Kertesz, Vilmos; Van Berkel, Gary J.

    2016-07-12

    A system for sampling a surface includes a surface sampling probe comprising a solvent liquid supply conduit and a distal end, and a sample collector for suspending a sample collection liquid adjacent to the distal end of the probe. A first electrode provides a first voltage to solvent liquid at the distal end of the probe. The first voltage produces a field sufficient to generate electrospray plume at the distal end of the probe. A second electrode provides a second voltage and is positioned to produce a plume-directing field sufficient to direct the electrospray droplets and ions to the suspended sample collection liquid. The second voltage is less than the first voltage in absolute value. A voltage supply system supplies the voltages to the first electrode and the second electrode. The first electrode can apply the first voltage directly to the solvent liquid. A method for sampling for a surface is also disclosed.

  18. Automated Liquid-Level Control of a Nutrient Reservoir for a Hydroponic System

    Science.gov (United States)

    Smith, Boris; Asumadu, Johnson A.; Dogan, Numan S.

    1997-01-01

    A microprocessor-based system for control of the liquid level of a nutrient reservoir for a plant hydroponic growing system has been developed. The system uses an ultrasonic transducer to sense the liquid level or height. A National Instruments' Multifunction Analog and Digital Input/Output PC Kit includes NI-DAQ DOS/Windows driver software for an IBM 486 personal computer. A Labview Full Development system for Windows is the graphical programming system being used. The system allows liquid level control to within 0.1 cm for all levels tried between 8 and 36 cm in the hydroponic system application. The detailed algorithms have been developed and a fully automated microprocessor based nutrient replenishment system has been described for this hydroponic system.

  19. RECOVERY OF CARBOXYLIC ACIDS FROM AQUEOUS SOLUTIONS BY LIQUID-LIQUID EXTRACTION WITH A TRIISOOCTYLAMINE DILUENT SYSTEM

    Directory of Open Access Journals (Sweden)

    G. Malmary

    2001-12-01

    Full Text Available Tertiary alkylamines in solution with organic diluents are attractive extractants for the recovery of carboxylic acids from dilute aqueous phases. The aim of this study was to investigate the mechanism for extraction of organic acids from water by a long-chain aliphatic tertiary amine. In order to attain this objective, we studied the liquid-liquid equilibria between the triisooctylamine + 1-octanol + n-heptane system as solvent and an aqueous solution of an individual carboxylic acid such as citric, lactic and malic acids. The experiments showed that the partition coefficient for a particular organic acid depends on the kind of solute, notably when the acid concentration in the aqueous phase is low. A mathematical model, where both chemical association and physical distribution are taken into consideration, is proposed. The model suggests that the various complexes obtained between amine and organic acids contribute to the distribution of the solute between the coexisting phases in equilibrium.

  20. Liquid-liquid equilibrium of water + PEG 8000 + magnesium sulfate or sodium sulfate aqueous two-phase systems at 35°C: experimental determination and thermodynamic modeling

    Directory of Open Access Journals (Sweden)

    B. D. Castro

    2005-09-01

    Full Text Available Liquid-liquid extraction using aqueous two-phase systems is a highly efficient technique for separation and purification of biomolecules due to the mild properties of both liquid phases. Reliable data on the phase behavior of these systems are essential for the design and operation of new separation processes; several authors reported phase diagrams for polymer-polymer systems, but data on polymer-salt systems are still relatively scarce. In this work, experimental liquid-liquid equilibrium data on water + polyethylene glycol 8000 + magnesium sulfate and water + polyethylene glycol 8000 + sodium sulfate aqueous two-phase systems were obtained at 35°C. Both equilibrium phases were analyzed by lyophilization and ashing. Experimental results were correlated with a mass-fraction-based NRTL activity coefficient model. New interaction parameters were estimated with the Simplex method. The mean deviations between the experimental and calculated compositions in both equilibrium phases is about 2%.

  1. Performance analysis of a novel energy storage system based on liquid carbon dioxide

    International Nuclear Information System (INIS)

    Wang, Mingkun; Zhao, Pan; Wu, Yi; Dai, Yiping

    2015-01-01

    Due to the intermittence and fluctuation of wind resource, the increasing penetration level of wind power will bring huge challenges to maintain the stability of power system. Integrating compressed air energy storage (CAES) system with wind farms can weaken this negative effect. However CAES system needs large caverns or mines to store compressed air, which is restricted in application. In this paper, a novel energy storage system based on liquid carbon dioxide is presented. The mathematical models of compressed liquid-carbon dioxide energy storage system are developed. The parametric analysis is conducted to examine the effect of some key thermodynamic parameters on the system performance. Compared with AA-CAES, the liquid carbon dioxide energy storage system has advantages such as a high energy density, high EVR. Moreover, the round trip efficiency of this system can reach about 56.64%, which is acceptable in consideration of the storage volume. Therefore, this proposed system has a good potential for storing wind power in large scale and offers an attractive solution to the challenges of the increasing penetration level of wind power. - Highlights: • A novel energy storage system based on liquid carbon dioxide is presented. • The effects of some key parameters on the system performance are studied. • The operation optimization is conducted by genetic algorithm. • Comparative analysis of AA-CAES and liquid carbon dioxide system is studied.

  2. Liquid-liquid equilibria for binary and ternary systems containing glycols, aromatic hydrocarbons, and water: Experimental measurements and modeling with the CPA EoS

    DEFF Research Database (Denmark)

    Folas, Georgios; Kontogeorgis, Georgios; Michelsen, Michael Locht

    2006-01-01

    Liquid-liquid equilibrium data of four binary glycol + aromatic hydrocarbon systems and three ternary systems containing water have been measured at atmospheric pressure. The measured systems are monoethylene glycol (MEG) + benzene or toluene, triethylene glycol (TEG) + benzene or toluene, MEG...... + water + benzene, MEG + water + toluene, and TEG + water + toluene. The binary systems are correlated with the Cubic-Plus-Association (CPA) equation of state while the ternary systems are predicted from interaction parameters obtained from the binary systems. Very satisfactory liquid-liquid equilibrium...... correlations are obtained for the binary systems using temperature-independent interaction parameters, while adequate predictions are achieved for multicomponent water + glycol + aromatic hydrocarbons systems when accounting for the solvation between the aromatic hydrocarbons and glycols or water....

  3. Liquid Effluent Monitoring Information System test plans releases 2.0 and 3.0

    International Nuclear Information System (INIS)

    Guettler, D.A.

    1995-01-01

    The Liquid Effluent Monitoring Information System (LEMIS) is being developed as the organized information repository facility in support of the liquid effluent monitoring requirements of the Tri-Party Agreement. It is necessary to provide an automated repository into which the results from liquid effluent sampling will be placed. This repository must provide for effective retention, review, and retrieval of selected sample data by authorized persons and organizations. This System Architecture document is the aggregation of the DMR P+ methodology project management deliverables. Together they represent a description of the project and its plan through four Releases, corresponding to the definition and prioritization of requirements defined by the user

  4. Liquid Effluent Monitoring Information System (LEMIS) test plans release 1.0

    International Nuclear Information System (INIS)

    Adams, R.T.

    1994-01-01

    The Liquid Effluent Monitoring Information System (LEMIS) is being developed as the organized information repository facility in support of the liquid effluent monitoring requirements of the Tri-Party Agreement. It is necessary to provide an automated repository into which the results from liquid effluent sampling will be placed. This repository must provide for effective retention, review, and retrieval of selected sample data by authorized persons and organizations. This System Architecture document is the aggregation of the DMR P+ methodology project management deliverables. Together they represent a description of the project and its plan through four Releases, corresponding to the definition and prioritization of requirements defined by the user

  5. Liquid Effluent Monitoring Information System test plans release 1.2

    International Nuclear Information System (INIS)

    Adams, R.T.

    1994-01-01

    The Liquid Effluent Monitoring Information System (LEMIS) is being developed as the organized information repository facility in support of the liquid effluent monitoring requirements of the Tri-Party Agreement. It is necessary to provide an automated repository into which the results from liquid effluent sampling will be placed. This repository must provide for effective retention, review, and retrieval of selected sample data by authorized persons and organizations. This System Architecture document is the aggregation of the DMR P+ methodology project management deliverables. Together they represent a description of the project and its plan through four Releases, corresponding to the definition and prioritization of requirements defined by the user

  6. Liquid Effluent Monitoring Information System (LEMIS) test plans release 1.1

    International Nuclear Information System (INIS)

    Adams, R.T.

    1994-01-01

    The Liquid Effluent Monitoring Information System (LEMIS) is being developed as the organized information repository facility in support of the liquid effluent monitoring requirements of the Tri-Party Agreement. It is necessary to provide an automated repository into which the results from liquid effluent sampling will be placed. This repository must provide for effective retention, review, and retrieval of selected sample data by authorized persons and organizations. This System Architecture document is the aggregation of the DMR P+ methodology project management deliverables. Together they represent a description of the project and its plan through four Releases, corresponding to the definition and prioritization of requirements defined by the user

  7. Large area liquid argon detectors for interrogation systems

    Energy Technology Data Exchange (ETDEWEB)

    Gary, Charles; Kane, Steve; Firestone, Murray I.; Smith, Gregory [Adelphi Technology LLC, Purdue Technology Center, 5225 Exploration Drive, Indianapolis, IN 46241 (United States); Gozani, Tsahi; Brown, Craig; Kwong, John; King, Michael J. [Rapiscan Laboratories, 520 Almanor Avenue, Sunnyvale, CA 94085 (United States); Nikkel, James A.; McKinsey, Dan [Physics Department, Yale University, New Haven, CT 06520 (United States)

    2013-04-19

    Measurements of the efficiency, pulse shape, and energy and time resolution of liquid argon (LAr) detectors are presented. Liquefied noble gas-based (LNbG) detectors have been developed for the detection of dark matter and neutrinoless double-beta decay. However, the same qualities that make LNbG detectors ideal for these applications, namely their size, cost, efficiency, pulse shape discrimination and resolution, make them promising for portal screening and the detection of Special Nuclear Materials (SNM). Two 18-liter prototype detectors were designed, fabricated, and tested, one with pure LAr and the other doped with liquid Xe (LArXe). The LArXe detector presented the better time and energy resolution of 3.3 ns and 20% at 662 KeV, respectively. The total efficiency of the detector was measured to be 35% with 4.5% of the total photons detected in the photopeak.

  8. Large area liquid argon detectors for interrogation systems

    International Nuclear Information System (INIS)

    Gary, Charles; Kane, Steve; Firestone, Murray I.; Smith, Gregory; Gozani, Tsahi; Brown, Craig; Kwong, John; King, Michael J.; Nikkel, James A.; McKinsey, Dan

    2013-01-01

    Measurements of the efficiency, pulse shape, and energy and time resolution of liquid argon (LAr) detectors are presented. Liquefied noble gas-based (LNbG) detectors have been developed for the detection of dark matter and neutrinoless double-beta decay. However, the same qualities that make LNbG detectors ideal for these applications, namely their size, cost, efficiency, pulse shape discrimination and resolution, make them promising for portal screening and the detection of Special Nuclear Materials (SNM). Two 18-liter prototype detectors were designed, fabricated, and tested, one with pure LAr and the other doped with liquid Xe (LArXe). The LArXe detector presented the better time and energy resolution of 3.3 ns and 20% at 662 KeV, respectively. The total efficiency of the detector was measured to be 35% with 4.5% of the total photons detected in the photopeak.

  9. Vapor-liquid equilibria for the acetone-ethanol-n-propanol-tert-butanol-water system

    Energy Technology Data Exchange (ETDEWEB)

    Tochigi, K.; Uchida, K.; Kojima, K.

    1981-12-01

    This study deals with the measurement of vapor-liquid equilibria for the five-component system acetone-ethanol-n-propanol-tert-butanol-water at 760 mmHg and prediction of vapor-liquid equilibria by the ASOG group contribution method. The five-component system in this work is composed of a part of the components obtained during ethanol production by vapor-phase hydration of ethylene. 6 refs.

  10. The elimination of singularities in pair correlation functions of a multicomponent liquid system

    International Nuclear Information System (INIS)

    Vasil'jev, O.M.; Chalij, O.V.

    2004-01-01

    In this paper we propose a method that allows to find nonsingular expressions for pair correlation functions of a multicomponent liquid system. The nature of the method deals with using integral and differential Ornstein-Zernike equations for finding asymptotic expressions for pair correlation functions and their subsequent precision. The obtained results are analyzed taking into account their possible applicability for studying the correlative behaviour of multicomponent liquid systems

  11. Novel liquid application systems for poorly soluble drugs

    OpenAIRE

    Luschmann, Christoph Roman

    2015-01-01

    This thesis was focused on the development of efficient novel liquid formulations for poorly water soluble drugs for the treatment of inflammatory ophthalmic diseases. With Restasis® there is currently only one drug product approved by the FDA, in the US only, for the treatment of dry eye syndrome. It still suffers from low bioavailability, bad biocompatibility and thus a low patient compliance, as well as cumbersome manufacturing. Hence, there is a tremendous lack in the options for a causal...

  12. Modeling vapor liquid equilibrium of ionic liquids + gas binary systems at high pressure with cubic equations of state

    Directory of Open Access Journals (Sweden)

    A. C. D. Freitas

    2013-03-01

    Full Text Available Ionic liquids (IL have been described as novel environmentally benign solvents because of their remarkable characteristics. Numerous applications of these solvents continue to grow at an exponential rate. In this work, high pressure vapor liquid equilibria for 17 different IL + gas binary systems were modeled at different temperatures with Peng-Robinson (PR and Soave-Redlich-Kwong (SRK equations of state, combined with the van der Waals mixing rule with two binary interaction parameters (vdW-2. The experimental data were taken from the literature. The optimum binary interaction parameters were estimated by minimization of an objective function based on the average absolute relative deviation of liquid and vapor phases, using the modified Simplex algorithm. The solubilities of all gases studied in this work decrease as the temperature increases and increase with increasing pressure. The correlated results were highly satisfactory, with average absolute relative deviations of 2.10% and 2.25% for PR-vdW-2 and SRK-vdW-2, respectively.

  13. Liquid densities and excess molar volumes for (ionic liquids + methanol + water) ternary system at atmospheric pressure and at various temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Deenadayalu, Nirmala [Department of Chemistry, Durban University of Technology, Steve Biko Campus, P.O. Box 1334, Durban, KwaZulu-Natal 4001 (South Africa)], E-mail: NirmalaD@dut.ac.za; Kumar, Satish; Bhujrajh, Pravena [Department of Chemistry, Durban University of Technology, Steve Biko Campus, P.O. Box 1334, Durban, KwaZulu-Natal 4001 (South Africa)

    2007-09-15

    Excess molar volumes, V{sub m}{sup E} have been evaluated from density measurements over the entire composition range for ternary liquid system of ionic liquid (1-ethyl-3-methyl-imidazolium diethylenglycol monomethylether sulphate {l_brace}[EMIM][CH{sub 3}(OCH{sub 2}CH{sub 2}){sub 2}OSO{sub 3}]) (1) + methanol (2) + water (3){r_brace} at T = (298.15, 303.15, and 313.15) K. A vibrating tube densimeter was used for these measurements at atmospheric pressure. The V{sub m}{sup E} values were found to be negative at T = (298.15 and 303.15) K. For {l_brace}[EMIM][CH{sub 3}(OCH{sub 2}CH{sub 2}){sub 2}OSO{sub 3}] (1) + methanol (2) + water (3){r_brace} at T = 313.15 K the V{sub m}{sup E} values become positive at higher mole fraction of ionic liquid and at a corresponding decrease in mole fraction of water. All the experimental data were fitted with the Redlich-Kister equation. The results have also been analysed in term of graph theoretical approach.

  14. Measurements and correlation of liquid-liquid equilibrium data for the ternary (3-heptanone + phenol + water) system

    International Nuclear Information System (INIS)

    Xu, Gaojie; Yang, Deling; Ning, Pengge; Wang, Qingjie; Gong, Fuchun; Cao, Hongbin

    2017-01-01

    Highlights: • The liquid-liquid equilibrium data for 3-heptanone + phenol + water were measured. • The distribution coefficient of phenol and selectivity for solvent extraction efficiency were calculated. • The NRTL model (two regression methods) and UNIQUAC model were used to correlate the experimental data with good results. • The physical meaning of the regressed binary parameters was explained by intermolecular attractive energy. • The activity coefficient of phenol and enthalpy change in extraction process were investigated. - Abstract: Liquid-liquid equilibrium (LLE) for the ternary (3-heptanone + phenol + water) system has been determined under atmospheric pressure at 298.15 K, 303.15 K, 318.15 K and 323.15 K. The NRTL and UNIQUAC models were used to correlate the experimental results. The corresponding binary parameters were obtained and their physical meaning is explained by intermolecular attractive energy. The results from the two models agree well with experimental values. The NRTL model was more accurate than that of the UNIQUAC model. Meanwhile, the NRTL model was used to regress all the experimental values at different temperatures simultaneously, which is defined as total-regression. Compared with the individual regression by the NRTL model, the total regression by the NRTL model has fewer parameters and covers a wider interpolated range from 298.15 K to 323.15 K. The distribution coefficient for phenol changes with temperature. The phenol concentration can be expressed as a function of activity coefficient of phenol in both phases. The effect of temperature on the extraction performance of 3-heptanone was also investigated. The phenol extraction process by 3-heptanone is exothermic. The increase of temperature is not a benefit to phenol extraction.

  15. Optical Mass Gauging System for Measuring Liquid Levels in a Reduced Gravity Environment

    Science.gov (United States)

    Sullenberger, Ryan M.; Munoz, Wesley M.; Lyon, Matt P.; Vogel, Kenny; Yalin, Azer P.; Korman, Valentin; Polzin, Kurt A.

    2010-01-01

    A compact and rugged fiber-coupled liquid volume sensor designed for flight on a sounding rocket platform is presented. The sensor consists of a Mach-Zehnder interferometer capable of measuring the amount of liquid contained in a tank under any gravitational conditions, including a microgravity environment, by detecting small changes in the index of refraction of the gas contained within a sensing region. By monitoring changes in the interference fringe pattern as the system undergoes a small compression provided by a piston, the ullage volume of a tank can be directly measured allowing for a determination of the liquid volume. To demonstrate the technique, data are acquired using two tanks containing different volumes of liquid, which are representative of the levels of liquid in a tank at different time periods during a mission. The two tanks are independently exposed to the measurement apparatus, allowing for a determination of the liquid level in each. In a controlled, laboratory test of the unit, the system demonstrated a capability of measuring a liquid level in an individual tank of 10.53 mL with a 2% error. The overall random uncertainty for the flight system is higher than that one test, at +/- 1.5 mL.

  16. Measurement and modeling of high-pressure (vapor + liquid) equilibria of (CO2 + alkanol) binary systems

    International Nuclear Information System (INIS)

    Bejarano, Arturo; Gutierrez, Jorge E.; Araus, Karina A.; Fuente, Juan C. de la

    2011-01-01

    Research highlights: → (Vapor + liquid) equilibria of three (CO 2 + C 5 alcohol) binary systems were measured. → Complementary data are reported at (313, 323 and 333) K and from (2 to 11) MPa. → No liquid immiscibility was observed at the temperatures and pressures studied. → Experimental data were correlated with the PR-EoS and the van de Waals mixing rules. → Correlation results showed relative deviations ≤8 % (liquid) and ≤2 % (vapor). - Abstract: Complementary isothermal (vapor + liquid) equilibria data are reported for the (CO 2 + 3-methyl-2-butanol), (CO 2 + 2-pentanol), and (CO 2 + 3-pentanol) binary systems at temperatures of (313, 323, and 333) K, and at pressure range of (2 to 11) MPa. For all (CO 2 + alcohol) systems, it was visually monitored that there was no liquid immiscibility at the temperatures and pressures studied. The experimental data were correlated with the Peng-Robinson equation of state using the quadratic mixing rules of van der Waals with two adjustable parameters. The calculated (vapor + liquid) equilibria compositions were found to be in good agreement with the experimental data with deviations for the mole fractions <8% and <2% for the liquid and vapor phase, respectively.

  17. ASSESING THE DETERMINANTS OF BANK LIQUIDITY. CASE STUDY ROMANIAN BANKING SYSTEM

    Directory of Open Access Journals (Sweden)

    Florin Alexandru LUCA

    2016-06-01

    Full Text Available The financial crisis has highlighted the importance of liquidity risk for the banking system. Therefore, this study focuses on identifing the determinants of liquidity of Romanian banks. The data cover the period from 2006 to 2013 and take into account only bank-specific factors. The empirical study was applied on 16 Romanian banks and based on previous studies and uses different liquidity ratios, encompassing different points of view on liquidity. Regarding the explanatory variables considered in this analysis, they include various items of internal character concerning: capital adequacy, asset quality, profitability, efficiency of financial intermediation and the size of the banks. The results of our regression analysis indicate that bank liquidity is positively related to capital adequacy of banks and bank profitability and negatively related to the rate of non-performing loans, net interest margin and the size of the bank.

  18. Numerical simulation on stir system of jet ballast in high level liquid waste storage tank

    International Nuclear Information System (INIS)

    Lu Yingchun

    2012-01-01

    The stir system of jet ballast in high level liquid waste storage tank was simulation object. Gas, liquid and solid were air, sodium nitrate liquor and titanium whitening, respectively. The mathematic model based on three-fluid model and the kinetic theory of particles was established for the stir system of jet ballast in high level liquid waste storage tank. The CFD commercial software was used for solving this model. The detail flow parameters as three phase velocity, pressure and phase loadings were gained. The calculated results agree with the experimental results, so they can well define the flow behavior in the tank. And this offers a basic method for the scale-up and optimization design of the stir system of jet ballast in high level liquid waste storage tank. (author)

  19. Experimental system design of liquid lithium-lead alloy bubbler for DFLL-TBM

    International Nuclear Information System (INIS)

    Xie Bo; Li Junge; Xu Shaomei; Weng Kuiping

    2011-01-01

    The liquid lithium-lead alloy bubbler is a very important composition in the tritium unit of Chinese Dual-Functional Lithium Lead Test Blanket Module (DFLL-TBM). In order to complete the construction and run of the bubbler experimental system,overall design of the system, main circuit design and auxiliary system design have been proposed on the basis of theoretical calculations for the interaction of hydrogen isotope with lithium-lead alloy and experiment for hydrogen extraction from liquid lithium-lead alloy by bubbling with rotational jet nozzle. The key of this design is gas-liquid exchange packed column, to achieve the measurement and extraction of hydrogen isotopes from liquid lithium-lead alloy. (authors)

  20. Thermodynamic analysis of an innovative liquid desiccant air conditioning system to supply potable water

    International Nuclear Information System (INIS)

    Ahmed, M.A.; Gandhidasan, P.; Zubair, Syed M.; Bahaidarah, Haitham M.

    2017-01-01

    Highlights: • The study objective is to reduce the energy consumption of desiccant AC system. • Heat and mass losses are recovered in the proposed system using a condenser. • The conventional and the proposed systems are compared in terms of COP. • The proposed system performance is better than the conventional system. • The proposed system produces freshwater in addition to space cooling. - Abstract: Liquid desiccant air conditioning systems are cost-effective, environmentally friendly and energy efficient techniques, especially in coastal areas. In the conventional liquid desiccant air conditioning system, the scavenging air is expelled into the atmosphere carrying a considerable amount of energy and water vapor. Thus, there is plenty of room to improve the system performance by recovering these losses. The proposed system consists of a conventional liquid desiccant air conditioning system plus a condenser. The aim of this study is to reduce the energy consumption by recovering the heat from the scavenging air using the condenser while also producing freshwater in addition to space cooling. Lithium chloride (LiCl) is used as the liquid desiccant for this study. The mathematical formulation for simultaneous heat and mass transfer between the condenser and the regenerator was developed to establish a comparison between the performance of the conventional and modified systems. Using the generated model, it is found that the modified system performance is 11.25% better than the conventional system and that it produces 86.4 kg of freshwater per hour as a by-product under the given conditions.

  1. Functions and requirements document, WESF decoupling project, low-level liquid waste system

    Energy Technology Data Exchange (ETDEWEB)

    Rasmussen, J.H., Fluor Daniel Hanford

    1997-02-27

    The Waste Encapsulation and Storage Facility (WESF) was constructed in 1974 to encapsulate and store cesium and strontium which were isolated at B Plant from underground storage tank waste. The WESF, Building 225-B, is attached physically to the west end of B Plant, Building 221-B, 200 East area. The WESF currently utilizes B Plant facilities for disposing liquid and solid waste streams. With the deactivation of B Plant, the WESF Decoupling Project will provide replacement systems allowing WESF to continue operations independently from B Plant. Four major systems have been identified to be replaced by the WESF Decoupling Project, including the following: Low Level Liquid Waste System, Solid Waste Handling System, Liquid Effluent Control System, and Deionized Water System.

  2. Structural studies on volatile, air and moisture sensitive liquids at ambient and elevated temperatures using liquid X-ray scattering. The structure of liquid gallium (III) chloride systems

    Science.gov (United States)

    Ulvenlund, Stefan; Bengtsson, Lars A.

    1994-09-01

    An X-ray scattering method is presented which provides accurate structural information on air and moisture sensitive liquids at ambient and elevated temperatures using a standard θ-θ X-ray diffractometer. The method utilizes capillary glass tubes as sample containers and requires no corrections for sample container absorption or scattering, as shown by structural studies of well-known systems such as benzene, carbon tetrachloride and antimony trichloride. Artefacts produced by the sample holder are insignificant and very easy to correct for. The major drawback of the method is the long time of experiment, due to the small (compared with the standard set-up) area/volume ratio of the liquid which contributes to the intensity of the scattered radiation. However, the time required is not unduly long except for liquids containing light elements only (very low scattering power) or very heavy ones (high liner absorptivity). Liquid GaCl 3 is shown to have a dimeric structure consisting of edge-sharing GaCl 4 tetrahedra. This structure is analogous to that previously found for GaCl 3 in the gaseous and solid state and for AlCl 3 in the gaseous and liquid state. Concentrated solutions of GaCl 3 in benzene have been shown to comprise monomeric GaCl 3 units with C3v symmetry. However, it is suggested that such units form as a result of a radiolytically induced cleavage of the Ga 2Cl 6 moieties. No GaC correlation is resolved, which is explained by assuming a σ-type complex GaCl 3 and benzene and/or an ill-defined interaction between the GaCl 3 unit and benzene. The former sitution would most probably produce too few GaC correlation to be observable by the present method, whereas the latter situation would produce a very broad GaC correlation difficult to separate from the background. However, the deviation from the D3h symmetry adopted by GaCl 3 in the gas phase indicates a specific interation between GaCl 3 and benzene.

  3. High rate amplifier-digitizer system for liquid argon calorimeters

    International Nuclear Information System (INIS)

    Droege, T.F.; Lobkowicz, F.; Fukushima, Y.

    1978-01-01

    A low-cost charge amplifier for a liquid argon photon detector and a new method for pulse height analysis are described. This scheme is suitable for high-energy photon detection with high counting rate. Samples of preamplifer output are taken just before and just after the arrival of the charge from the detector. The difference of these samples provides a stable pedestal and rejects low frequency noise. Short two-pulse resolving time (approximately equal to 200ns) is achieved. 6 refs

  4. Method for determining efficiency in a liquid scintillation system

    International Nuclear Information System (INIS)

    Laney, B.H.

    1975-01-01

    This invention relates to a method of counting radioactive events in a liquid scintillation radiation detecting and counting apparatus by utilizing pulses generated by a photomultiplying means resulting from scintillations caused by radioactive events. A counting efficiency value is assigned to each pulse generated in the photomultiplying means according to the height of the pulse. The numerical inverse of each assigned counting efficiency value is determined and each numerical inverse is recorded as an actual number of radioactive events with each having a pulse height identical to that of the corresponding pulse generated in the photomultiplying means. (Patent Office Record)

  5. Flow measurement in two-phase (gas-liquid) systems

    International Nuclear Information System (INIS)

    Hewitt, G.F.; Whalley, P.B.

    1980-01-01

    The main methods of measuring mass flow and quality in gas-liquid flows in industrial situations are reviewed. These include gamma densitometry coupled with differential pressure devices such as crifice plates, turbine flow meters and drag screens. For each method the principle of operation, and the advantages and disadvantages, are given. Some further techniques which are currently being investigated and developed for routine use are also described briefly. Finally the detailed flow measurements possible on a particular flow pattern - annular flow - is examined. (author)

  6. Selion offers a unique system for treating liquid nuclear waste

    Energy Technology Data Exchange (ETDEWEB)

    Tusa, E.; Kurki, H. [ed.

    1998-07-01

    Studies on the treatment of liquid nuclear waste have been conducted actively in the IVO Group since the early 1980s. And the work has borne fruit: the CsTreat and SrTreat ion exchange products, developed by the IVO Group, were launched three years ago. The ion exchangers have already been in full use at a number of sites throughout the world. In addition, they are currently being tested at many nuclear research institutes and power plants in the USA, Japan and Europe

  7. Thermal degradation of polymer systems having liquid crystalline oligoester segment

    Directory of Open Access Journals (Sweden)

    Renato Matroniani

    Full Text Available Abstract Block copolymers and blends comprised by liquid crystalline oligoester and polystyrene were prepared and their thermal stability were characterized by thermogravimetric analysis (TGA. The samples have shown three main decomposition temperatures due to (1 lost of flexible chain and decomposition of mesogenic segment, (2 decomposition of polystyrene and (3 final decomposition of oligoester rigid segment. Both copolymers and polymer blends presented lower thermal stability compared to polystyrene and oligoester. The residual mass after heating at 600 °C in copolymers and polymer blends were lower than those found in the oligoesters. A degradative process of aromatic segments of oligoester induced by decomposition of polystyrene is suggested.

  8. Diffuse-charge dynamics of ionic liquids in electrochemical systems.

    Science.gov (United States)

    Zhao, Hui

    2011-11-01

    We employ a continuum theory of solvent-free ionic liquids accounting for both short-range electrostatic correlations and steric effects (finite ion size) [Bazant et al., Phys. Rev. Lett. 106, 046102 (2011)] to study the response of a model microelectrochemical cell to a step voltage. The model problem consists of a 1-1 symmetric ionic liquid between two parallel blocking electrodes, neglecting any transverse transport phenomena. Matched asymptotic expansions in the limit of thin double layers are applied to analyze the resulting one-dimensional equations and study the overall charge-time relation in the weakly nonlinear regime. One important conclusion is that our simple scaling analysis suggests that the length scale √(λ*(D)l*(c)) accurately characterizes the double-layer structure of ionic liquids with strong electrostatic correlations where l*(c) is the electrostatic correlation length (in contrast, the Debye screening length λ*(D) is the primary double-layer length for electrolytes) and the response time of λ(D)(*3/2)L*/(D*l(c)(1/2)) (not λ*(D)L*/D* that is the primary charging time of electrolytes) is the correct charging time scale of ionic liquids with strong electrostatic correlations where D* is the diffusivity and L* is the separation length of the cell. With these two new scales, data of both electric potential versus distance from the electrode and the total diffuse charge versus time collapse onto each individual master curve in the presence of strong electrostatic correlations. In addition, the dependance of the total diffuse charge on steric effects, short-range correlations, and driving voltages is thoroughly examined. The results from the asymptotic analysis are compared favorably with those from full numerical simulations. Finally, the absorption of excess salt by the double layer creates a depletion region outside the double layer. Such salt depletion may bring a correction to the leading order terms and break down the weakly nonlinear

  9. Liquid formation in the Y-Si-Al-O-N system

    Energy Technology Data Exchange (ETDEWEB)

    Redington Keely, W.; Redington, M.; Hampshire, S. [Limerick Univ. (Ireland). Materials Research Centre

    2000-07-01

    Some silicon nitride ceramics are sintered using a combination of Y{sub 2}O{sub 3} and Al{sub 2}O{sub 3} additives to form a Y-Si-Al-O-N liquid that promotes densification and allows the {alpha}{yields}{beta} transformation to take place by solution/precipitation through the liquid which cools as an intergranular phase. The type and amount of additive determines the nature and quantity of the resulting grain boundary phase as indicated and this can affect high temperature strength, creep resistance and oxidation resistance. Thus it is important to understand the phase equilibria in these complex systems and then apply this knowledge to processing, the development of beneficial microstructures and the relationship between these and properties. One difficulty is that, for any particular composition, the quantity and composition of the liquid at the sintering temperature is not known accurately and a full compositional representation has not been achieved. This paper attempts to represent the liquid region at various temperatures in the Jaenecke prism of the Y-Si-Al-O-N system. Published information on liquid compositions, standardised into eq.% format, was combined with experimental data interpolated from the less well defined regions to build a composite picture of liquid in this system. Representation was achieved using a customised graphical environment, AutoCAD trademark. AutoLISP trademark routines combined with this drafting package allow data from multiple sources to be integrated. This results in a series of overlays which indicate the liquid region from its initial formation at 1335 C and its subsequent development at different ''milestone'' temperatures. At 1700 C the orthographic projections of the liquid region are combined to give a volume bounded by nurbs surfaces, using ALIAS trademark software, to enable visualisation of the proposed liquid region. (orig.)

  10. NAPP liquid shutoff rod system design, development, testing and precommissioning feed back study

    International Nuclear Information System (INIS)

    Soni, K.L.; Kaushik, R.V.; Mahajan, S.V.

    1989-01-01

    The development testing of a liquid poison shutoff rod system has enabled the evolution of a proven and acceptable design of the secondary shutdown system for 235 MWe standardised Pressurised Heavy Water Reactors (PHWRs). The availability of a full scale test loop is also proving for checking and qualifying the various suggestions for online improvements in the system. (author)

  11. Application of ionic liquids in electrochemical sensing systems.

    Science.gov (United States)

    Shiddiky, Muhammad J A; Torriero, Angel A J

    2011-01-15

    Since 1992, when the room temperature ionic liquids (ILs) based on the 1-alkyl-3-methylimidazolium cation were reported to provide an attractive combination of an electrochemical solvent and electrolyte, ILs have been widely used in electrodeposition, electrosynthesis, electrocatalysis, electrochemical capacitor, and lithium batteries. However, it has only been in the last few years that electrochemical biosensors based on carbon ionic liquid electrodes (CILEs) and IL-modified macrodisk electrodes have been reported. However, there are still a lot of challenges in achieving IL-based sensitive, selective, and reproducible biosensors for high speed analysis of biological and environmental compounds of interest. This review discusses the principles of operation of electrochemical biosensors based on CILEs and IL/composite-modified macrodisk electrodes. Subsequently, recent developments and major strategies for enhancing sensing performance are discussed. Key challenges and opportunities of IL-based biosensors to further development and use are considered. Emphasis is given to direct electron-transfer reaction and electrocatalysis of hemeproteins and enzyme-modified composite electrodes. Copyright © 2010 Elsevier B.V. All rights reserved.

  12. Chirality transfer technique between liquid crystal microdroplets using microfluidic systems

    Science.gov (United States)

    Guo, Jin-kun; Lee, Doyeon; Song, Jang-kun

    2018-02-01

    Cholesteric liquid crystal (LC) microdroplet is applied in many areas, such as tunable laser, biosensor, information display and security identification, due to its unique optical properties. The topological structure, defects, and photonic crystallinity in the cholesteric liquid crystal (LC) microdroplet can be controlled through the chirality. Here we report an interesting phenomenon that chirality information can be shared among dispersed LC microdroplets in surfactant aqueous solution, which is driven by the transferring of chiral dopant molecules. As a result, we developed an artificial molecule transfer technology which could in situ vary the material composition within the isolated dispersed microdroplets. The molecular transfer is switchable and the transfer speed is controllable by tuning the molecular solubility in continuous phase. Based on this technique, we manipulated, forward and backward, the topological evolution and the photonic crystal band-gap of the dispersed LC droplet. This technique is an easy and powerful experimental tool, and it may be applicable to other fields in optical application, biology, chemistry and material science.

  13. Characterization of adsorption uptake curves for both intraparticle diffusion and liquid film mass transfer controlling systems

    International Nuclear Information System (INIS)

    Sonetaka, Noriyoshi; Fan, Huan-Jung; Kobayashi, Seiji; Su, Yang-Chih; Furuya, Eiji

    2009-01-01

    In general, the adsorption uptake curve (AUC) can be easily determined in either intraparticle diffusion or liquid film mass transfer dominating systems. However, for both intraparticle diffusion and liquid film mass transfer controlling systems, the characterization of AUC is much more complicated, for example, when relatively small adsorbent particles are employed. In addition, there is no analytical solution available for both intraparticle diffusion and liquid film mass transfer controlling systems. Therefore, this paper is trying to characterize AUC for both intraparticle diffusion and liquid film mass transfer controlling adsorption systems using the shallow bed reactor technique. Typical parameters influencing AUC include liquid film mass transfer coefficient (k F ), effective intraparticle diffusivity (D S ), influent concentration (c 0 ) and equilibrium parameters (such as Freundlich isotherm constants k and 1/n). These parameters were investigated in this research and the simulated results indicated that the ratio of k F /D S and Freundlich constant 1/n had impact on AUC. Biot number (Bi) was used to replace the ratio of k F /D S in this study. Bi represents the ratio of the rate of transport across the liquid layer to the rate of intraparticle diffusion. Furthermore, Bi is much more significant than that of 1/n for AUC. Therefore, AUC can be characterized by Bi. In addition, the obtained Bi could be used to determine D S and k F simultaneously. Both parameters (D S and k F ) are important for designing and operating fixed bed reactors.

  14. Cross-Linked Liquid Crystalline Systems From Rigid Polymer Networks to Elastomers

    CERN Document Server

    Broer, Dirk

    2011-01-01

    With rapidly expanding interest in liquid crystalline polymers and elastomers among the liquid crystal community, researchers are currently exploring the wide range of possible application areas for these unique materials, including optical elements on displays, tunable lasers, strain gauges, micro-structures, and artificial muscles. Written by respected scientists from academia and industry around the world, who are not only active in the field but also well-known in more traditional areas of research, "Cross-Linked Liquid Crystalline Systems: From Rigid Polymer Networks to Elastomers&qu

  15. Development of a test system for high level liquid waste partitioning

    Directory of Open Access Journals (Sweden)

    Duan Wu H.

    2015-01-01

    Full Text Available The partitioning and transmutation strategy has increasingly attracted interest for the safe treatment and disposal of high level liquid waste, in which the partitioning of high level liquid waste is one of the critical technical issues. An improved total partitioning process, including a tri-alkylphosphine oxide process for the removal of actinides, a crown ether strontium extraction process for the removal of strontium, and a calixcrown ether cesium extraction process for the removal of cesium, has been developed to treat Chinese high level liquid waste. A test system containing 72-stage 10-mm-diam annular centrifugal contactors, a remote sampling system, a rotor speed acquisition-monitoring system, a feeding system, and a video camera-surveillance system was successfully developed to carry out the hot test for verifying the improved total partitioning process. The test system has been successfully used in a 160 hour hot test using genuine high level liquid waste. During the hot test, the test system was stable, which demonstrated it was reliable for the hot test of the high level liquid waste partitioning.

  16. Effect of transient liquid flow on retention characteristics of screen acquisition systems. [design of Space Shuttle feed system

    Science.gov (United States)

    Cady, E. C.

    1977-01-01

    A design analysis, is developed based on experimental data, to predict the effects of transient flow and pressure surges (caused either by valve or pump operation, or by boiling of liquids in warm lines) on the retention performance of screen acquisition systems. A survey of screen liquid acquisition system applications was performed to determine appropriate system environment and classification. A screen model was developed which assumed that the screen device was a uniformly distributed composite orthotropic structure, and which accounted for liquid inflow/outflow, gas ingestion quality, screen stress, and liquid spill. A series of 177 tests using 13 specimens (5 screen meshes, 4 screen device construction/backup methods, and 2 orientations) with three test fluids (isopropyl alcohol, Freon 114, and LH2) provided data which verified important features of the screen model and resulted in a design tool which could accurately predict the transient startup performance acquisition devices.

  17. The Daya Bay antineutrino detector filling system and liquid mass measurement

    Science.gov (United States)

    Band, H. R.; Cherwinka, J. J.; Draeger, E.; Heeger, K. M.; Hinrichs, P.; Lewis, C. A.; Mattison, H.; McFarlane, M. C.; Webber, D. M.; Wenman, D.; Wang, W.; Wise, T.; Xiao, Q.

    2013-09-01

    The Daya Bay Reactor Neutrino Experiment has measured the neutrino mixing angle θ13 to world-leading precision. The experiment uses eight antineutrino detectors filled with 20-tons of gadolinium-doped liquid scintillator to detect antineutrinos emitted from the Daya Bay nuclear power plant through the inverse beta decay reaction. The precision measurement of sin22θ13 relies on the relative antineutrino interaction rates between detectors at near (400 m) and far (roughly 1.8 km) distances from the nuclear reactors. The measured interaction rate in each detector is directly proportional to the number of protons in the liquid scintillator target. A precision detector filling system was developed to simultaneously fill the three liquid zones of the antineutrino detectors and measure the relative target mass between detectors to < 0.02%. This paper describes the design, operation, and performance of the system and the resulting precision measurement of the detectors' target liquid masses.

  18. Influence of radiation on the system liquid radioactive wastes: geologic formation

    International Nuclear Information System (INIS)

    Spitsyn, V.I.; Balukova, V.D.; Kabakchi, S.A.; Medvedeva, M.L.

    1979-01-01

    Introduction of liquid radioactive wastes into deep strata-collectors results in a number of physical-chemical processes: precipitation, dissolution, complex formation, sorption, etc. The area occupied by the injected waste and changes in the nature of the liquid phase depend primarily on radiolysis processes in the heterogeneous system of liquid waste-stratal material occurring at elevated temperatures and pressures. Experiments that simulate actual conditions of temperature, pressure and high radiation levels on this system have been performed. Results are presented for radiolytic gas formation and for changes in the liquid phase and sorption capacity of stratal minerals. It is shown that the temperature increase in the stratum-collector significantly enhances waste decomposition processes, promotes sorption of radionuclides and decreases the mobility of the waste in the formation

  19. THE FINANCIAL LIQUIDITY OF THE FOOD INDUSTRY ENTERPRISES IN POLAND IN THE SYSTEM SIZE OF ENTERPRISES

    Directory of Open Access Journals (Sweden)

    Anna Bieniasz

    2013-12-01

    Full Text Available The article presents the diversification of financial liquidity of food industry enterprises in Poland in 2009-2011 and indicates the main factors shaping liquidity. The study used unpublished data of Central Statistical Office, allowing for the analysis of liquidity in the system classes the food industry and the system enterprise size (small, medium, large. The analyses show, that the food industry in Poland in 2009-2011, regardless of their size and adopted ratios, have the ability to regulate the current liabilities, but kept at a low level. Analysis of the factors influencing liquidity showed, that the primary importance was turnover ratio of current liabilities, as well as ratio of financing of income through equity.

  20. Measurement and modeling of high-pressure (vapour + liquid) equilibria of (CO2 + alcohol) binary systems

    International Nuclear Information System (INIS)

    Gutierrez, Jorge E.; Bejarano, Arturo; Fuente, Juan C. de la

    2010-01-01

    An apparatus based on a static-analytic method assembled in this work was utilized to perform high pressure (vapour + liquid) equilibria measurements with uncertainties estimated at 2 + 1-propanol), (CO 2 + 2-methyl-1-propanol), (CO 2 + 3-methyl-1-butanol), and (CO 2 + 1-pentanol) binary systems at temperatures of (313, 323, and 333) K, and at pressure range of (2 to 12) MPa. For all the (CO 2 + alcohol) systems, it was visually monitored to insure that there was no liquid immiscibility at the temperatures and pressures studied. The experimental results were correlated with the Peng-Robinson equation of state using the quadratic mixing rules of van der Waals with two adjustable parameters. The calculated (vapour + liquid) equilibria compositions were found to be in good agreement with the experimental values with deviations for the mol fractions <0.12 and <0.05 for the liquid and vapour phase, respectively.

  1. Thermodynamic characteristics of a novel wind-solar-liquid air energy storage system

    Science.gov (United States)

    Ji, W.; Zhou, Y.; Sun, Y.; Zhang, W.; Pan, C. Z.; Wang, J. J.

    2017-12-01

    Due to the nature of fluctuation and intermittency, the utilization of wind and solar power will bring a huge impact to the power grid management. Therefore a novel hybrid wind-solar-liquid air energy storage (WS-LAES) system was proposed. In this system, wind and solar power are stored in the form of liquid air by cryogenic liquefaction technology and thermal energy by solar thermal collector, respectively. Owing to the high density of liquid air, the system has a large storage capacity and no geographic constraints. The WS-LAES system can store unstable wind and solar power for a stable output of electric energy and hot water. Moreover, a thermodynamic analysis was carried out to investigate the best system performance. The result shows that the increases of compressor adiabatic efficiency, turbine inlet pressure and inlet temperature all have a beneficial effect.

  2. Comparative technical-economical analysis of solar systems with liquid absorbent

    International Nuclear Information System (INIS)

    Kaloyanov, N.; Popova, I.

    2005-01-01

    An analyses of solar water heating systems with two types liquid absorbent is presented. A system with classic collector design is used for comparison. The dependence between the value of the collectors active area and the absorbent type, collectors slope and design parameters is discussed. Two economic indexes (payback period and index of actual net value, based on the electricity price) are used for comparison of the different variants of the system. The presented results shown that: 1) the payback period can be reduced twice if the collectors with liquid absorbent are used; 2) the index of actual net value of the systems using the collectors with fluid absorbent is about four times higher than this one with classic collectors; 3) the systems using distilled water like a liquid absorbent can not fulfil the requirements for the positive economic indicators

  3. Experience on the removal of impurities from liquid metal systems by cold-trapping

    Energy Technology Data Exchange (ETDEWEB)

    Bray, J. A.

    1963-10-15

    Experience in impurity removal by cold-trapping, which was obtained on DFR and its associated liquid metal rigs, is reviewed. The development of the present DFR cold-trapping system is outlined, and the operation of the additional pumped loops, which were required in order to control the reactor impurity levels, are described. Operation of the liquid metal rigs ancillary to the reactor project is discussed with particular reference to the control of impurity levels. (auth)

  4. Microalgal Cultivation in Treating Liquid Digestate from Biogas Systems.

    Science.gov (United States)

    Xia, Ao; Murphy, Jerry D

    2016-04-01

    Biogas production via anaerobic digestion (AD) has rapidly developed in recent years. In addition to biogas, digestate is an important byproduct. Liquid digestate is the major fraction of digestate and may contain high levels of ammonia nitrogen. Traditional processing technologies (such as land application) require significant energy inputs and raise environmental risks (such as eutrophication). Alternatively, microalgae can efficiently remove the nutrients from digestate while producing high-value biomass that can be used for the production of biochemicals and biofuels. Both inorganic and organic carbon sources derived from biogas production can significantly improve microalgal production. Land requirement for microalgal cultivation is estimated as 3% of traditional direct land application of digestate. Copyright © 2015 Elsevier Ltd. All rights reserved.

  5. Symbiotic Nuclear—Coal Systems for Production of Liquid Fuels

    Science.gov (United States)

    Taczanowski, S.

    The notion of safety is not confined to the technological or non-proliferation aspects. It covers also the elements of energy policy: irrational reactions of societies, emotions, egoistic interests of more or less powerful pressure of economical and external political factors. One should be conscious that the country's privilege of being equipped by the Nature with rich resources of oil or gas is not solely economical, but even more a political one. Simultaneously, the gradual depletion of world hydrocarbons that draws behind irrevocable price increase has to be expected within the time scale of exploitation of power plants (now amounted to ~60 years). Therefore consequences of energy policy last much longer than the perspectives the political or economical decision makers are planning and acting within and the public is expecting successes and finally evaluating them. The world oil and gas resources are geopolitically very non-uniformly distributed, in contrast to coal and uranium. Since the level of energy self-sufficiency of the EU is highest for coal, the old idea of synfuels production from coal is recalled. Yet, in view of limits to the CO2 emissions in the EU another method has to be used here than the conventional coal liquefaction just applied in China. Simultaneously, an interesting evolution of energy prices was be observed, namely an increase in that of motor fuels in contrast to that of electricity remaining well stable. This fact suggests that the use of electricity (mainly the off-peak load), generated without emissions of CO2 for production of liquid fuels can prove reasonable. Thus, the essence of the presented idea of coal-nuclear symbiosis lies in the supply of energy in the form of H2, necessary for this process, from a nuclear reactor. Particularly, in the present option H2 is obtained by electrolytic water splitting supplying also O2 as a precious by-product in well mature and commercially available already since decades, Light Water Reactors

  6. Interfacial transport phenomena and stability in liquid-metal/water systems: scaling considerations

    International Nuclear Information System (INIS)

    Abdulla, S.; Liu, X.; Anderson, M.; Bonazza, R.; Corradini, M.; Cho, D.

    2001-01-01

    One concept being considered for steam generation in innovative nuclear reactor applications, involves water coming into direct contact with a circulating molten metal. The vigorous agitation of the two fluids, the direct liquid-liquid contact and the consequent large interfacial area give rise to very high heat transfer coefficients and rapid steam generation. For an optimum design of such direct contact heat exchange and vaporization systems, detailed knowledge is necessary of the various flow regimes, interfacial transport phenomena, heat transfer and operational stability. In this paper we describe current results from the first year of this research that studies the transport phenomena involved with the injection of water into molten metals (e.g., lead alloys). In particular, this work discusses scaling considerations related to direct contact heat exchange, our experimental plans for investigation and a test plan for the important experimental parameters; i.e., the water and liquid metal mass flow rates, the liquid metal pool temperature and the ambient pressure of the direct contact heat exchanger. Past experimental work and initial scaling results suggest that our experiments can directly represent the proper liquid metal pool temperature and the water subcooling. The experimental variation in water and liquid metal flow rates and system pressure (1-10 bar), although smaller than the current conceptual system designs, is sufficient to verify the expected scale effects to demonstrate the phenomena. (authors)

  7. Programmable System-on-Chip (PSoC) Embedded Readout Designs for Liquid Helium Level Sensors.

    Science.gov (United States)

    Parasakthi, C; Gireesan, K; Usha Rani, R; Sheela, O K; Janawadkar, M P

    2014-08-01

    This article reports the development of programmable system-on-chip (PSoC)-based embedded readout designs for liquid helium level sensors using resistive liquid vapor discriminators. The system has been built for the measurement of liquid helium level in a concave-bottomed, helmet-shaped, fiber-reinforced plastic cryostat for magnetoencephalography. This design incorporates three carbon resistors as cost-effective sensors, which are mounted at desired heights inside the cryostat and were used to infer the liquid helium level by measuring their temperature-dependent resistance. Localized electrical heating of the carbon resistors was used to discriminate whether the resistor is immersed in liquid helium or its vapor by exploiting the difference in the heat transfer rates in the two environments. This report describes a single PSoC chip for the design and development of a constant current source to drive the three carbon resistors, a multiplexer to route the sensor outputs to the analog-to-digital converter (ADC), a buffer to avoid loading of the sensors, an ADC for digitizing the data, and a display using liquid crystal display cum light-emitting diode modules. The level sensor readout designed with a single PSoC chip enables cost-effective and reliable measurement system design. © 2014 Society for Laboratory Automation and Screening.

  8. Design and operation of off-gas cleaning systems at high level liquid waste conditioning facilities

    International Nuclear Information System (INIS)

    1988-01-01

    The immobilization of high level liquid wastes from the reprocessing of irradiated nuclear fuels is of great interest and serious efforts are being undertaken to find a satisfactory technical solution. Volatilization of fission product elements during immobilization poses the potential for the release of radioactive substances to the environment and necessitates effective off-gas cleaning systems. This report describes typical off-gas cleaning systems used in the most advanced high level liquid waste immobilization plants and considers most of the equipment and components which can be used for the efficient retention of the aerosols and volatile contaminants. In the case of a nuclear facility consisting of several different facilities, release limits are generally prescribed for the nuclear facility as a whole. Since high level liquid waste conditioning (calcination, vitrification, etc.) facilities are usually located at fuel reprocessing sites (where the majority of the high level liquid wastes originates), the off-gas cleaning system should be designed so that the airborne radioactivity discharge of the whole site, including the emission of the waste conditioning facility, can be kept below the permitted limits. This report deals with the sources and composition of different kinds of high level liquid wastes and describes briefly the main high level liquid waste solidification processes examining the sources and characteristics of the off-gas contaminants to be retained by the off-gas cleaning system. The equipment and components of typical off-gas systems used in the most advanced (large pilot or industrial scale) high level liquid waste solidification plants are described. Safety considerations for the design and safe operation of the off-gas systems are discussed. 60 refs, 31 figs, 17 tabs

  9. Progress on the MICE Liquid Absorber Cooling and Cryogenic Distribution System

    International Nuclear Information System (INIS)

    Green, M.A.; Baynham, E.; Bradshaw, T.; Drumm, P.; Ivanyushenkov, Y.; Ishimoto, S.; Cummings, M.A.C.; Lau, W.W.; Yang, S.Q.

    2005-01-01

    This report describes the progress made on the design of the cryogenic cooling system for the liquid absorber for the international Muon Ionization Cooling Experiment (MICE). The absorber consists of a 20.7-liter vessel that contains liquid hydrogen (1.48 kg at 20.3 K) or liquid helium (2.59 kg at 4.2 K). The liquid cryogen vessel is located within the warm bore of the focusing magnet for the MICE. The purpose of the magnet is to provide a low beam beta region within the absorber. For safety reasons, the vacuum vessel for the hydrogen absorber is separated from the vacuum vessel for the superconducting magnet and the vacuum that surrounds the RF cavities or the detector. The absorber thin windows separate the liquid in the absorber from the absorber vacuum. The absorber vacuum vessel also has thin windows that separate the absorber vacuum space from adjacent vacuum spaces. Because the muon beam in MICE is of low intensity, there is no beam heating in the absorber. The absorber can use a single 4 K cooler to cool either liquid helium or liquid hydrogen within the absorber

  10. Ionic Liquids for Utilization of Waste Heat from Distributed Power Generation Systems

    Energy Technology Data Exchange (ETDEWEB)

    Joan F. Brennecke; Mihir Sen; Edward J. Maginn; Samuel Paolucci; Mark A. Stadtherr; Peter T. Disser; Mike Zdyb

    2009-01-11

    The objective of this research project was the development of ionic liquids to capture and utilize waste heat from distributed power generation systems. Ionic Liquids (ILs) are organic salts that are liquid at room temperature and they have the potential to make fundamental and far-reaching changes in the way we use energy. In particular, the focus of this project was fundamental research on the potential use of IL/CO2 mixtures in absorption-refrigeration systems. Such systems can provide cooling by utilizing waste heat from various sources, including distributed power generation. The basic objectives of the research were to design and synthesize ILs appropriate for the task, to measure and model thermophysical properties and phase behavior of ILs and IL/CO2 mixtures, and to model the performance of IL/CO2 absorption-refrigeration systems.

  11. Palladium catalyst system comprising zwitterion and/or acid-​functionalized ionic liquid

    DEFF Research Database (Denmark)

    2011-01-01

    The present invention concerns a catalyst system in particular a catalyst system comprising Palladium (Pd), a zwitterion and/or an acid-functionalized ionic liquid, and one or more phosphine ligands, wherein the Pd catalyst can be provided by a complex precursor, such as Pd(CH3COO)2, PdCI2, Pd(CH3...... methyl methacrylate and/or methacrylic acid. Catalyst systems according to the invention are suitable for reactions forming separable product and catalyst phases and supported ionic liquid phase SILP applications....

  12. A cryogenic monitor system for the Liquid Argon Calorimeter in the SLD detector

    International Nuclear Information System (INIS)

    Fox, M.J.; Fox, J.D.

    1988-10-01

    This paper describes the monitoring electronics system design for the Liquid Argon Calorimeter (LAC) portion of the SLD detector. This system measures temperatures and liquid levels inside the LAC cryostat and transfers the results over a fiber-optic serial link to an external monitoring computer. System requirements, unique design constraints, and detailed analog, digital and software designs are presented. Fault tolerance and the requirement for a single design to work in several different operating environments are discussed. 4 refs., 3 figs., 1 tab

  13. Complex Formation in a Liquid-Liquid Extraction System Containing Cobalt(II, 4-(2-Pyridylazoresorcinol, and Nitron

    Directory of Open Access Journals (Sweden)

    Petya Vassileva Racheva

    2013-01-01

    Full Text Available Complex formation and liquid-liquid extraction were studied in a system containing cobalt(II, 4-(2-pyridylazoresorcinol (PAR, 1,4-diphenyl-3-(phenylamino-1H-1,2,4-triazole (Nitron, Nt, water, and chloroform. The effect of some experimental parameters (pH, shaking time, concentration of PAR, and concentration of Nt was systematically investigated, and the optimum conditions for cobalt extraction as an ion-association complex, (NtH+[Co3+(PAR2], were found. The following key equilibrium constants were calculated: constant of association (Log β=4.77±0.06, constant of distribution (LogKD=1.34±0.01, and constant of extraction (LogKex=6.11±0.07. Beer’s law was obeyed for Co concentrations up to 1.7 μg mL−1 with a molar absorptivity of 6.0×104 L mol−1 cm−1 at λmax=520 nm. Some additional characteristics, such as limit of detection, limit of quantification, and Sandell’s sensitivity, were estimated as well.

  14. Optimization and application of homogeneous liquid-liquid extraction in preconcentration of copper (II) in a ternary solvent system

    Energy Technology Data Exchange (ETDEWEB)

    Farajzadeh, Mir Ali [Department of Analytical Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz (Iran, Islamic Republic of)], E-mail: farajzade@yahoo.com; Bahram, Morteza [Department of Chemistry, Faculty of Science, Urmia University, Urmia (Iran, Islamic Republic of); Zorita, Saioa [Department of Analytical Chemistry, University of Lund, P.O. Box 124, 221 00 Lund (Sweden); Mehr, Behzad Ghorbani [Department of Chemistry, Faculty of Science, Urmia University, Urmia (Iran, Islamic Republic of)

    2009-01-30

    In this study a homogeneous liquid-liquid extraction based on the Ph-dependent phase-separation process was investigated using a ternary solvent system (water-acetic acid-chloroform) for the preconcentration of Cu{sup 2+} ions. 8-Hydroxy quinoline was used as the chelating agent prior to its extraction. Flame atomic absorption spectrophotometry using acetylene-air flame was used for the quantitation of analyte after preconcentration. The effect of various experimental parameters in extraction step was investigated using two optimization methods, one variable at a time and central composite design. The experimental design was done at five levels of operating parameters. Nearly the same optimized results were obtained using both methods: sample size, 5 mL; volume of NaOH 10 M, 2 mL; chloroform volume, 300 {mu}L; 8-hydroxy quinoline concentration more than 0.01 M and salt amount did not affect the extraction significantly. Under the optimum conditions the calibration graph was linear over the range 10-2000 {mu}g L{sup -1}. The relative standard deviation was 7.6% for six repeated determinations (C = 500 {mu}g L{sup -1}). Furthermore, the limit of detection (S/N = 3) and limit of quantification (S/N = 10) of the method were obtained as 1.74 and 6 {mu}g L{sup -1}, respectively.

  15. Measurement of liquid-liquid equilibria for condensate + glycol and condensate + glycol + water systems

    DEFF Research Database (Denmark)

    Riaz, Muhammad; Kontogeorgis, Georgios; Stenby, Erling Halfdan

    2011-01-01

    ,2-ethanediol (MEG) + condensate and MEG + water + condensate systems at temperatures from (275 to 323) K at atmospheric pressure. The condensate used in this work is a stabilized natural gas condensate from an offshore field in the North Sea. Compositional analysis of the natural gas condensate was carried out...... by gas chromatography, and detailed separation of individual condensate's components has been carried out. Approximately 85 peaks eluting before nonane were identified by their retention time. Peak areas were converted to mass fraction using 1-heptene as an internal standard. The components were divided...... into boiling range groups from hexane to nonane. Paraffinic (P), naphthenic (N), and aromatic (A) distributions were obtained for the boiling point fractions up to nonane. The average molar mass and the overall density of the condensate were measured experimentally. For the mutual solubility of MEG...

  16. Decontamination and decommissioning of TAN radioactive liquid-waste-evaporator system (PM-2A). Final report

    International Nuclear Information System (INIS)

    Smith, D.L.

    1983-03-01

    This report describes the decontamination and decommissioning of the Test Area North (TAN) liquid waste evaporator (PM-2A). The PM-2A facility included the aboveground evaporator system, two underground holding tanks and feedlines, an electrical distribution subsystem, and one above ground concrete tank. Much surface soil of the PM-2A area was also radioactively contaminated. Stabilization of the liquid and sludge in the holding tanks, a major task, was achieved by pumping most of the liquid into 55-gal drums and mixing it with cement. The drums were buried in the Radioactive Waste Management Complex (RWMC). The remaining liquid and sludge were dried in place by layers of diatomaceous earth. The most contaminated surface soil was removed, and the area backfilled with clean topsoil and graded, reducing the surface radiation field to background. A 6-ft-high chain link fence now surrounds the area. Most of the area was seeded to crested wheatgrass. 46 figures, 9 tables

  17. Failure detection of liquid cooled electronics in sealed packages. [in airborne information management system

    Science.gov (United States)

    Hoadley, A. W.; Porter, A. J.

    1991-01-01

    The theory and experimental verification of a method of detecting fluid-mass loss, expansion-chamber pressure loss, or excessive vapor build-up in NASA's Airborne Information Management System (AIMS) are presented. The primary purpose of this leak-detection method is to detect the fluid-mass loss before the volume of vapor on the liquid side causes a temperature-critical part to be out of the liquid. The method detects the initial leak after the first 2.5 pct of the liquid mass has been lost, and it can be used for detecting subsequent situations including the leaking of air into the liquid chamber and the subsequent vapor build-up.

  18. Fully integrated microfluidic measurement system for real-time determination of gas and liquid mixtures composition

    NARCIS (Netherlands)

    Lötters, Joost Conrad; Groenesteijn, Jarno; van der Wouden, E.J.; Sparreboom, Wouter; Lammerink, Theodorus S.J.; Wiegerink, Remco J.

    2015-01-01

    We have designed and realised a fully integrated microfluidic measurement system for real-time determination of both flow rate and composition of gas- and liquid mixtures. The system comprises relative permittivity sensors, pressure sensors, a Coriolis flow and density sensor, a thermal flow sensor

  19. Ultrasonic instrument for continuous measurement of liquid levels in sodium systems

    International Nuclear Information System (INIS)

    Boehmer, L.S.

    1975-01-01

    An ultrasonic level measurement system which provides a continuous digital readout over a range of 3-180 inches, was tested in 500 0 F liquid sodium. The system proved to be accurate and reliable, required no initial warm-up period and experienced no long term drift. Modifications can extend the present operating temperatures to greater than 1200 0 F

  20. Open loop, auto reversing liquid nitrogen circulation thermal system for thermo vacuum chamber

    International Nuclear Information System (INIS)

    Naidu, M C A; Nolakha, Dinesh; Saharkar, B S; Kavani, K M; Patel, D R

    2012-01-01

    In a thermo vacuum chamber, attaining and controlling low and high temperatures (-100 Deg. C to +120 Deg. C) is a very important task. This paper describes the development of 'Open loop, auto reversing liquid nitrogen based thermal system'. System specifications, features, open loop auto reversing system, liquid nitrogen flow paths etc. are discussed in this paper. This thermal system consists of solenoid operated cryogenic valves, double embossed thermal plate (shroud), heating elements, temperature sensors and PLC. Bulky items like blowers, heating chambers, liquid nitrogen injection chambers, huge pipe lines and valves were not used. This entire thermal system is very simple to operate and PLC based, fully auto system with auto tuned to given set temperatures. This system requires a very nominal amount of liquid nitrogen (approx. 80 liters / hour) while conducting thermo vacuum tests. This system was integrated to 1.2m dia thermo vacuum chamber, as a part of its augmentation, to conduct extreme temperature cycling tests on passive antenna reflectors of satellites.

  1. Tribological properties of rice starch in liquid and semi-solid food model systems

    NARCIS (Netherlands)

    Liu, K.; Stieger, M.A.; Linden, van der E.; Velde, van de Fred

    2016-01-01

    This study investigated the tribological and rheological properties of liquid and semi-solid food model systems containing micro-granular rice starch. Native (uncooked) and gelatinized rice starch dispersions, o/w emulsions and emulsion-filled gelatin gels were studied as food model systems. Native

  2. Fluctuations in an Inorganic Glass Forming System Capable of Liquid-Liquid Phase Separation

    Science.gov (United States)

    Bogdanov, V.; Maksimov, L.; Anan'ev, A.; Nemilov, S.; Rusan, V.

    2012-08-01

    Rayleigh and Mandel'shtam-Brillouin scattering (RMBS) spectroscopy and high temperature ultrasonic study (HTUS) are applied to PbO-Al2O3-B2O3 glass forming system characterized by over liquidus miscibility gap. Temperature dependences of ultrasonic velocity of glass melts were measured in 600-1200°C range. "Frozen-in" density fluctuations in two phase glasses were estimated from HTUS data by Macedo-Shroeder formulation. Landau-Placzek ratios were found from RMBS spectra of single phase glasses at room temperature. Results of RMBS and HTUS were compared with well-known SAXS data. It was found that contribution of "frozen-in" density fluctuations into light scattering by two-phase glasses is much smaller than the scattering on particles of the second glassy phase causing opalescence of the glasses. Abnormal "water-like" growth of ultrasonic velocity with melt temperature can be explained by coexistence of two types of packaging of structural elements.

  3. Liquid Hydrogen Recirculation System for Forced Flow Cooling Test of Superconducting Conductors

    Science.gov (United States)

    Shirai, Y.; Kainuma, T.; Shigeta, H.; Shiotsu, M.; Tatsumoto, H.; Naruo, Y.; Kobayashi, H.; Nonaka, S.; Inatani, Y.; Yoshinaga, S.

    2017-12-01

    The knowledge of forced flow heat transfer characteristics of liquid hydrogen (LH2) is important and necessary for design and cooling analysis of high critical temperature superconducting devices. However, there are few test facilities available for LH2 forced flow cooling for superconductors. A test system to provide a LH2 forced flow (∼10 m/s) of a short period (less than 100 s) has been developed. The test system was composed of two LH2 tanks connected by a transfer line with a controllable valve, in which the forced flow rate and its period were limited by the storage capacity of tanks. In this paper, a liquid hydrogen recirculation system, which was designed and fabricated in order to study characteristics of superconducting cables in a stable forced flow of liquid hydrogen for longer period, was described. This LH2 loop system consists of a centrifugal pump with dynamic gas bearings, a heat exchanger which is immersed in a liquid hydrogen tank, and a buffer tank where a test section (superconducting wires or cables) is set. The buffer tank has LHe cooled superconducting magnet which can produce an external magnetic field (up to 7T) at the test section. A performance test was conducted. The maximum flow rate was 43.7 g/s. The lowest temperature was 22.5 K. It was confirmed that the liquid hydrogen can stably circulate for 7 hours.

  4. Degradation of 1-butyl-3-methylimidazolium chloride ionic liquid in a Fenton-like system

    International Nuclear Information System (INIS)

    Siedlecka, E.M.; Mrozik, W.; Kaczynski, Z.; Stepnowski, P.

    2008-01-01

    The study examined the usefulness of a Fenton-like system for the degradation of ionic liquid residues in water. The ionic liquid was oxidized in a dilute aqueous solution of 1-butyl-3-methylimidazolium chloride (bmimCl). The ionic liquid decomposes readily and rapidly in aqueous solution by chemical degradation in a Fenton-like system. Under chosen conditions the initial bmimCl solution was reduced by a factor of 0.973 within 90 min. Additional results showed that bmimCl degradations in a Fenton-like system in excess H 2 O 2 could be interpreted as a combined oxidation-reduction mechanism. Preliminary investigations of the mechanism of such degradations have indicated that initial OH· radicals can attack any one of the three carbon atoms on the imidazolium ring. The intermediates of this reaction may be mono- di- or amino- carboxylic acids

  5. Calculation of liquid-liquid equilibrium of aqueous two-phase systems using a chemical-theory-based excess Gibbs energy model

    Directory of Open Access Journals (Sweden)

    Pessôa Filho P. A.

    2004-01-01

    Full Text Available Mixtures containing compounds that undergo hydrogen bonding show large deviations from ideal behavior. These deviations can be accounted for through chemical theory, according to which the formation of a hydrogen bond can be treated as a chemical reaction. This chemical equilibrium needs to be taken into account when applying stability criteria and carrying out phase equilibrium calculations. In this work, we illustrate the application of the stability criteria to establish the conditions under which a liquid-phase split may occur and the subsequent calculation of liquid-liquid equilibrium using a chemical-theory-modified Flory-Huggins equation to describe the non ideality of aqueous two-phase systems composed of poly(ethylene glycol and dextran. The model was found to be able to correlate ternary liquid-liquid diagrams reasonably well by simple adjustment of the polymer-polymer binary interaction parameter.

  6. Sodium leak detection system for liquid metal cooled nuclear reactors

    International Nuclear Information System (INIS)

    Modarres, D.

    1991-01-01

    This patent describes a device for detecting sodium leaks from a reactor vessel of a liquid sodium cooled nuclear reactor the reactor vessel being concentrically surrounded by a a containment vessel so as to define an airtight gap containing argon. It comprises: a light source for generating a first light beam, the first light beam having first and second predominant wavelengths, the first wavelength being substantially equal to an absorption line of sodium and the second wavelength being chosen such that it is not absorbed by sodium and argon; an optical multiplexer optically coupled to the light source; optically coupled to the multiplexer, each of the sensors being embedded in the containment vessel of the reactor, each of the sensors projecting the first light beam into the gap and collecting the first light beam after it has reflected off of a surface of the reactor vessel; a beam splitter optically coupled to each of the sensors through the multiplexer, the beam splitter splitting the first light beam into second and third light beams of substantially equal intensities; a first filter dispersed within a path of second light beam for filtering the second wavelength out of the third light beam; first and second detector beams disposed with in the paths of the second and third light beams so as to detect the intensities of the second and third light beams, respectively; and processing means connected to the first and second detector means for calculating the amount of the first wavelength which is absorbed when passing through the argon

  7. Thermodynamic equilibrium model to predict the cobalt distribution coefficient in the CoCl2--HCl--H2O--TBP liquid--liquid extraction system

    International Nuclear Information System (INIS)

    Nevarez, M.; Bautista, R.G.

    1976-01-01

    The development of a thermodynamic equilibrium model to predict the cobalt distribution coefficient in the CoCl 2 -HCl-H 2 O-TBP system is described. The model makes use of the various aqueous phase cobaltous chloride complexes stoichiometric stability constants expressed as their degree of formation, their mechanism of extraction into the organic phase, and the equilibrium constant for the extraction reaction. The model was verified by the good agreement between the calculated cobalt distribution coefficients and those obtained experimentally both in the present study and published by other investigators. The optimum extraction of cobalt by the TBP occurred at an HCl equilibrium aqueous place concentration between 8.5 and 9.5M. The development of efficient procedures for the separation and concentration of important industrial metals from their aqueous solutions by liquid-liquid extraction has recently been given impetus by the realization of an impending shortage of energy and mineral resources. Liquid-liquid extraction is one of the few methods by which it is possible to quantitatively separate elements which are similar in properties. The use of liquid-liquid extraction to separate cobalt and nickel, which very frequently occur in nature together, is an important separation problem in nonferrous metallurgy. There is some fundamental information available in the chemical literature regarding the mechanism and equilibrium thermodynamic properties of selected liquid-liquid extraction systems. This research effort shows how this available information can be utilized to improve existing separation and concentration theory and technique. The development and application of a thermodynamic equilibrium model for describing the liquid-liquid extraction of cobaltous chloride from aqueous HCl solutions by tributyl phosphate (TBP) using experimental data obtained in this investigation and from the literature are presented

  8. Effect of alkanolammonium formates ionic liquids on vapour liquid equilibria of binary systems containing water, methanol, and ethanol

    International Nuclear Information System (INIS)

    Li Xuemei; Shen Chong; Li Chunxi

    2012-01-01

    Highlights ► Vapour pressures for six ternary systems containing an IL were measured. ► Components studied were water, ethanol, methanol, and alkanolammonium formates. ► The isobaric VLE were predicted using the fitted binary NRTL parameters. ► The ILs studied can generate a promising salt effect on VLE of azeotrope. ► [HMEA][HCOO] might be used as a potential entrainer in extractive distillation. - Abstract: Vapour pressures were measured using a quasi-static ebulliometer for the pseudo-binary mixtures of (water + ethanol), (water + methanol), and (methanol + ethanol) containing an alkanolammonium-based ionic liquid (IL), namely, mono-ethanolammonium formate ([HMEA][HCOO]) and di-ethanolammonium formate ([HDEA][HCOO]), respectively, with fixed IL mass fraction of 0.30 and over the temperature ranges of (292.12 to 371.13) K. The vapour pressures of the IL-containing ternary systems were favourably correlated using the NRTL model with an overall average absolute relative deviation (AARD) of 0.0082. Further, the salt effects of [HMEA][HCOO] and [HDEA][HCOO] on isobaric vapour liquid equilibria (VLE) of azeotrope and close boiling mixture, especially for the mixtures of (water + ethanol) and (methanol + ethanol), were investigated and compared with other ILs in terms of the x′–y phase diagrams predicted with the binary NRTL parameters. It is demonstrated that the relative volatilities of ethanol to water and ethanol to methanol are enhanced, and [HMEA][HCOO] might be used as a promising entrainer for the efficient separation of ethanol aqueous solution by special rectification.

  9. Liquid-vapor phase transition upon pressure decrease in the lead-bismuth system

    Science.gov (United States)

    Volodin, V. N.

    2009-11-01

    The liquid-vapor phase transitions boundaries were calculated on the basis of the values of vapor pressure of the components in the lead-bismuth system during the stepwise pressure decrease by one order of magnitude from 105 down to 1 Pa. The emergence of azeotropic liquid under pressure lower than 19.3 kPa was ascertained. The emergence of azeotropic mixture near the lead edge of the phase diagram was concluded to be the reason for technological difficulties in the distillation separation of the system into the components in a vacuum.

  10. Correlations between phase behaviors and ionic conductivities of (ionic liquid + alcohol) systems

    International Nuclear Information System (INIS)

    Park, Nam Ku; Bae, Young Chan

    2010-01-01

    To understand the basic properties of ionic liquids (ILs), we examined the phase behavior and ionic conductivity characteristics using various compositions of different ionic liquids (1-ethyl-3-methylimidazolium hexafluorophosphate [emim] [PF6] and 1-benzyl-3-methylimidazolium hexafluorophosphate [bzmim] [PF6]) in several different alcohols (ethanol, propanol, 1-butanol, 2-butanol, and hexanol). We conducted a systematic study of the impact of different factors on the phase behavior of imidazolium-based ionic liquids in alcohols. Using a new experimental method with a liquid electrolyte system, we observed that the ionic conductivity of the ionic liquid/alcohol was sensitive to the surrounding temperature. We employed Chang et al.'s thermodynamic model [Chang et al. (1997, 1998) ] based on the lattice model. The obtained co-ordinated unit parameter from this model was used to describe the phase behavior and ionic conductivities of the given system. Good agreement with experimental data of various alcohol and ILs systems was obtained in the range of interest.

  11. Design and Development of Embedded Based System for the Measurement of Dielectric Constant Spectroscopy for Liquids

    Directory of Open Access Journals (Sweden)

    V. V. Ramana C. H.

    2010-09-01

    Full Text Available An embedded based system for the measurement of dielectric constant spectroscopy (for frequencies 1 kHz, 10 kHz, 100 kHz, 1 MHz and 10 MHz for liquids has been designed and developed. It is based on the principle that the change in frequency of an MAX 038 function generator, when the liquid forms the dielectric medium of the dielectric cell, is measured with a microcontroller. Atmel’s AT89LP6440 microcontroller is used in the present study. Further, an LCD module is interfaced with the microcontroller in 4-bit mode, which reduces the hardware complexity. Software is developed in C using Keil’s C-cross compiler. The instrument system covers a wide range of dielectric constants for various liquids at various frequencies and at different temperatures. The system is quite successful in the measurement of dielectric constant in liquids with an accuracy of ± 0.01 %. The dielectric constant is very dependent on the frequency of their measurement. No one-measurement technique is available, however, that will give the frequency range needed to characterize the liquid sample. The paper deals with the hardware and software details.

  12. Effect of Liquid Crystalline Systems Containing Antimicrobial Compounds on Infectious Skin Bacteria.

    Science.gov (United States)

    Souza, Carla; Watanabe, Evandro; Aires, Carolina Patrícia; Lara, Marilisa Guimarães

    2017-08-01

    This study aimed (i) to prepare liquid crystalline systems (LCS) of glyceryl monooleate (GMO) and water containing antibacterial compounds and (ii) to evaluate their potential as drug delivery systems for topical treatment of bacterial infections. Therefore, LCS containing CPC (cetylpyridinium chloride) (LCS/CPC) and PHMB (poly(hexamethylene biguanide) hydrochloride) (LCS/PHMB) were prepared and the liquid crystalline phases were identified by polarizing light microscopy 24 h and 7 days after preparation. The in vitro drug release profile and in vitro antibacterial activity of the systems were assessed using the double layer agar diffusion method against Staphylococcus aureus, methicillin-resistant S. aureus, Staphylococcus epidermidis, Escherichia coli, and Enterococcus faecalis. The interaction between GMO and the drugs was evaluated by a drug absorption study. Stable liquid crystalline systems containing CPC and PHMB were obtained. LCS/PHMB decreased the PHMB release rate and exerted strong antibacterial activity against all the investigated bacteria. In contrast, CPC interacted with GMO so strongly that it became attached to the system; the amount released was not sufficient to exert antibacterial activity. Therefore, the studied liquid crystalline systems were suitable to deliver PHMB, but not CPC. Accordingly, it was demonstrated that GMO interacts with each drug differently, which may interfere in the final efficiency of GMO/water LCS.

  13. Development and Evaluation of Liquid and Solid Self-Emulsifying Drug Delivery Systems for Atorvastatin

    Directory of Open Access Journals (Sweden)

    Anna Czajkowska-Kośnik

    2015-11-01

    Full Text Available The objective of this work was to design and characterize liquid and solid self-emulsifying drug delivery systems (SEDDS for poorly soluble atorvastatin. To optimize the composition of liquid atorvastatin-SEDDS, solubility tests, pseudoternary phase diagrams, emulsification studies and other in vitro examinations (thermodynamic stability, droplet size and zeta potential analysis were performed. Due to the disadvantages of liquid SEDDS (few choices for dosage forms, low stability and portability during the manufacturing process, attempts were also made to obtain solid SEDDS. Solid SEDDS were successfully obtained using the spray drying technique from two optimized liquid formulations, CF3 and OF2. Despite liquid SEDDS formulation, CF3 was characterized by lower turbidity, higher percentage transmittance and better self-emulsifying properties, and based on the in vitro dissolution study it can be concluded that better solubilization properties were exhibited by solid formulation OF2. Overall, the studies demonstrated the possibility of formulating liquid and solid SEEDS as promising carriers of atorvastatin. SEDDS, with their unique solubilization properties, provide the opportunity to deliver lipophilic drugs to the gastrointestinal tract in a solubilized state, avoiding dissolution—a restricting factor in absorption rate of BCS Class 2 drugs, including atorvastatin.

  14. Simulation of Water Level Fluctuations in a Hydraulic System Using a Coupled Liquid-Gas Model

    Directory of Open Access Journals (Sweden)

    Chao Wang

    2015-08-01

    Full Text Available A model for simulating vertical water level fluctuations with coupled liquid and gas phases is presented. The Preissmann implicit scheme is used to linearize the governing equations for one-dimensional transient flow for both liquid and gas phases, and the linear system is solved using the chasing method. Some classical cases for single liquid and gas phase transients in pipelines and networks are studied to verify that the proposed methods are accurate and reliable. The implicit scheme is extended using a dynamic mesh to simulate the water level fluctuations in a U-tube and an open surge tank without consideration of the gas phase. Methods of coupling liquid and gas phases are presented and used for studying the transient process and interaction between the phases, for gas phase limited in a chamber and gas phase transported in a pipeline. In particular, two other simplified models, one neglecting the effect of the gas phase on the liquid phase and the other one coupling the liquid and gas phases asynchronously, are proposed. The numerical results indicate that the asynchronous model performs better, and are finally applied to a hydropower station with surge tanks and air shafts to simulate the water level fluctuations and air speed.

  15. (Liquid + liquid) equilibrium data for the ternary systems (cycloalkane + ethylbenzene + 1-ethyl-3-methylimidazolim ethylsulfate) at T = 298.15 K and atmospheric pressure

    International Nuclear Information System (INIS)

    Gonzalez, Emilio J.; Calvar, Noelia; Dominguez, Irene; Dominguez, Angeles

    2011-01-01

    Research highlights: → [EMim][ESO 4 ] was studied as solvent to extract ethylbenzene from cycloalkanes. → (Liquid + liquid) equilibrium data were measured at 298.15K and atmospheric pressure. → Selectivity and solute distribution ratio were obtained and compared with literature. → Experimental data were satisfactorily correlated using NRTL and UNIQUAC models. → [EMim][ESO 4 ] can be used as solvent for the studied (liquid + liquid) extraction. - Abstract: In this paper, (liquid + liquid) equilibrium (LLE) data for the ternary systems (cyclohexane, or cyclooctane, or methylcyclohexane + ethylbenzene + 1-ethyl-3-methylimidazolium ethylsulfate) have been determined experimentally at T = 298.15 K and atmospheric pressure. The solubility curves and the tie-line compositions of the conjugate phases were obtained by means of density. The degree of consistency of the tie-lines was tested using the Othmer-Tobias equation, and the Non-Random Two-Liquid (NRTL) and the Universal Quasi-Chemical (UNIQUAC) models were used to correlate the phase equilibrium in the systems. Selectivity and solute distribution ratio were evaluated for the immiscible region.

  16. The method for simultaneous extraction and back extraction in liquid three-phase system and equipment for simultaneous extraction and back extraction in liquid three-phase system

    International Nuclear Information System (INIS)

    Palyska, W.; Chmielewski, A.G.

    1992-01-01

    The method for simultaneous extraction and back extraction in liquid three-phase system has been worked out. The equipment designed for that process has been also subject of the patent. The interesting component is extracted first to intermediate phase consists of magnetic solvent keeping two extracting phases separately. The intermediate magnetic liquid has been kept in its position using a stable magnet maintained on the surface of the extraction vessel. Then the component pass from intermediate phase to the third phase as a result of back extraction. Mixing in the extraction and back extraction zones is organized by means of rotating shaft going along the whole apparatus. The extraction and back extraction processes occur simultaneously as a result of continuous flow of solvent in their zones. The single extraction back extraction facilities can be joined in larger batteries. 3 figs

  17. Liquid crystalline systems for transdermal delivery of celecoxib: in vitro drug release and skin permeation studies.

    Science.gov (United States)

    Estracanholli, Eder André; Praça, Fabíola Silva Garcia; Cintra, Ana Beatriz; Pierre, Maria Bernadete Riemma; Lara, Marilisa Guimarães

    2014-12-01

    Liquid crystalline systems of monoolein/water could be a promising approach for the delivery of celecoxib (CXB) to the skin because these systems can sustain drug release, improve drug penetration into the skin layers and minimize side effects. This study evaluated the potential of these systems for the delivery of CXB into the skin based on in vitro drug release and skin permeation studies. The amount of CXB that permeated into and/or was retained in the skin was assayed using an HPLC method. Polarizing light microscopy studies showed that liquid crystalline systems of monoolein/water were formed in the presence of CXB, without any changes in the mesophases. The liquid crystalline systems decreased drug release when compared to control solution. Drug release was independent of the initial water content of the systems and CXB was released from cubic phase systems, irrespective of the initial water content. The systems released the CXB following zero-order release kinetics. In vitro drug permeation studies showed that cubic phase systems allowed drug permeation and retention in the skin layers. Cubic phase systems of monoolein/water may be promising vehicles for the delivery of CXB in/through the skin because it improved CXB skin permeation compared with the control solution.

  18. Automatic quench compensation for liquid scintillation counting system

    International Nuclear Information System (INIS)

    Nather, R.E.

    1978-01-01

    A method of automatic quench compensation is provided, where a reference measure of quench is taken on a sample prior to taking a sample count. The measure of quench is then compared with a reference voltage source which has been established to vary in proportion to the variation of the measure of quench with the level of a system parameter required to restore at least one isotope spectral energy endpoint substantially to a selected counting window discriminator level in order to determine the amount of adjustment of the system parameter required to restore the endpoint. This is followed by the appropriate adjustment of the system parameter required to restore the relative position of the discriminator windows and the sample spectrum and is followed in turn by taking a sample count

  19. The evolution of the mass-transfer functions in liquid Yukawa systems

    Energy Technology Data Exchange (ETDEWEB)

    Vaulina, O. S., E-mail: olga.vaulina@bk.ru [Russian Academy of Sciences, Joint Institute for High Temperatures (Russian Federation)

    2016-09-15

    The results of analytic and numerical investigation of mass-transfer processes in nonideal liquid systems are reported. Calculations are performed for extended 2D and 3D systems of particles that interact with a screened Yukawa-type Coulomb potential. The main attention is paid to 2D structures. A new analytic model is proposed for describing the evolution of mass-transfer functions in systems of interacting particles, including the transition between the ballistic and diffusion regimes of their motion.

  20. Study of the liquid vapor equilibrium in the bromine-hydrobromic acid-water system

    Science.gov (United States)

    Benizri, R.; Lessart, P.; Courvoisier, P.

    1984-01-01

    A glass ebullioscope was built and at atmospheric pressure, liquid-vapor equilibria relative to the Br2-HBr-H2O system, in the concentration range of interest for evaluation of the Mark 13 cycle was studied. Measurements were performed for the brome-azeotrope (HBr-H2O) pseudo-binary system and for the ternary system at temperatures lower than 125 C and in the bromine concentration range up to 13% wt.

  1. Improvements in iodine and ruthenium removal from advanced liquid processing system

    Energy Technology Data Exchange (ETDEWEB)

    Skibo, A. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2017-09-27

    SRNL has considerable experience in designing, engineering, and operating systems for removing iodine-129 (I-129) and ruthenium-106 (Ru-106) from waste streams that are directly analogous to the Advanced Liquid Processing System (ALPS) waste streams. SRNL proposes to provide the technical background and design and engineering support for an improved I-129 and Ru-106 removal system for application to ALPS on the Fukushima Daiichi Nuclear Power Station (NPS).

  2. Simulation and economic analysis of a liquid-based solar system with a direct-contact liquid-liquid heat exchanger, in comparison to a system with a conventional heat exchanger

    Science.gov (United States)

    Brothers, P.; Karaki, S.

    Using a solar computer simulation package called TRNSYS, simulations of the direct contact liquid-liquid heat exchanger (DCLLHE) solar system and a system with conventional shell-and-tube heat exchanger were developed, based in part on performance measurements of the actual systems. The two systems were simulated over a full year on an hour-by-hour basis at five locations; Boston, Massachusetts, Charleston, South Carolina, Dodge City, Kansas, Madison, Wisconsin, and Phoenix, Arizona. Typically the direct-contact system supplies slightly more heat for domestic hot water and space heating in all locations and about 5 percentage points more cooling as compared to the conventional system. Using a common set of economic parameters and the appropriate federal and state income tax credits, as well as property tax legislation for solar systems in the corresponding states, the results of the study indicate for heating-only systems, the DCLLHE system has a slight life-cycle cost disadvantage compared to the conventional system. For combined solar heating and cooling systems, the DCLLHE has a slight life-cycle cost advantage which varies with location and amounts to one to three percent difference from the conventional system.

  3. Thermodynamic analysis of a liquid air energy storage system

    International Nuclear Information System (INIS)

    Guizzi, Giuseppe Leo; Manno, Michele; Tolomei, Ludovica Maria; Vitali, Ruggero Maria

    2015-01-01

    The rapid increase in the share of electricity generation from renewable energy sources is having a profound impact on the power sector; one of the most relevant effects of this trend is the increased importance of energy storage systems, which can be used to smooth out peaks and troughs of production from renewable energy sources. Besides their role in balancing the electric grid, energy storage systems may provide also several other useful services, such as price arbitrage, stabilizing conventional generation, etc.; therefore, it is not surprising that many research projects are under way in order to explore the potentials of new technologies for electric energy storage. This paper presents a thermodynamic analysis of a cryogenic energy storage system, based on air liquefaction and storage in an insulated vessel. This technology is attractive thanks to its independence from geographical constraints and because it can be scaled up easily to grid-scale ratings, but it is affected by a low round-trip efficiency due to the energy intensive process of air liquefaction. The present work aims to assess the efficiency of such a system and to identify if and how it can achieve an acceptable round-trip efficiency (in the order of 50–60%).

  4. The automatic liquid nitrogen filling system for GDA detectors

    Indian Academy of Sciences (India)

    In addition, no physical access to the beam hall is required during routine filling operation. The system consists of ... PSI with the manual valve (MV) on the dewar kept open. For filling the detectors on one ... sequence the opening/closing of the valves depending upon the outlet temperature. By monitoring the time taken for ...

  5. The simple analytics of systemic liquidity risk regulation

    NARCIS (Netherlands)

    Perotti, E.; Suarez, J.

    2011-01-01

    How to regulate systemic risk? This column presents a new CEPR discussion paper assessing the performance of Pigouvian taxes and quantity-based regulations in containing the social costs of high-risk banking. It finds that, depending on how banks differ, the socially efficient solution may be

  6. Experimental study of liquid-metal target designs of accelerating-controlled systems

    International Nuclear Information System (INIS)

    Iarmonov, Mikhail; Makhov, Kirill; Novozhilova, Olga; Meluzov, A.G.; Beznosov, A.V.

    2011-01-01

    Models of a liquid-metal target of an accelerator-controlled system have been experimentally studied at the Nizhny Novgorod State Technical University to develop an optimal design of the flow part of the target. The main explored variants of liquid-metal targets are: Design with a diaphragm (firm-and-impervious plug) mounted on the pipe tap of particle transport from the accelerator cavity to the working cavity of the liquid-metal target. Design without a diaphragm on the pipe tab of particle transport from the accelerator. The study was carried out in a high-temperature liquid-metal test bench under the conditions close to full-scale ones: the temperature of the eutectic lead-bismuth alloy was 260degC - 400degC, the coolant mass flow was 5-80 t/h, and the rarefaction in the gas cavity was 10 5 Pa, the coefficient of geometric similarity equal to 1. The experimental studies of hydrodynamic characteristics of flow parts in the designs of targets under full-scale conditions indicated high efficiency of a target in triggering, operating, and deactivating modes. Research and technology instructions for designs of the flow part of the liquid-metal target, the target design as a whole, and the target circuit of accelerator-controlled systems were formulated as a result of the studies. (author)

  7. Dual analyzer system for surface analysis dedicated for angle-resolved photoelectron spectroscopy at liquid surfaces and interfaces

    Energy Technology Data Exchange (ETDEWEB)

    Niedermaier, Inga; Kolbeck, Claudia; Steinrück, Hans-Peter; Maier, Florian, E-mail: florian.maier@fau.de [Lehrstuhl für Physikalische Chemie II, FAU Universität Erlangen-Nürnberg, Egerlandstraße 3, 91058 Erlangen (Germany)

    2016-04-15

    The investigation of liquid surfaces and interfaces with the powerful toolbox of ultra-high vacuum (UHV)-based surface science techniques generally has to overcome the issue of liquid evaporation within the vacuum system. In the last decade, however, new classes of liquids with negligible vapor pressure at room temperature—in particular, ionic liquids (ILs)—have emerged for surface science studies. It has been demonstrated that particularly angle-resolved X-ray Photoelectron Spectroscopy (ARXPS) allows for investigating phenomena that occur at gas-liquid and liquid-solid interfaces on the molecular level. The results are not only relevant for IL systems but also for liquids in general. In all of these previous ARXPS studies, the sample holder had to be tilted in order to change the polar detection angle of emitted photoelectrons, which restricted the liquid systems to very thin viscous IL films coating a flat solid support. We now report on the concept and realization of a new and unique laboratory “Dual Analyzer System for Surface Analysis (DASSA)” which enables fast ARXPS, UV photoelectron spectroscopy, imaging XPS, and low-energy ion scattering at the horizontal surface plane of macroscopically thick non-volatile liquid samples. It comprises a UHV chamber equipped with two electron analyzers mounted for simultaneous measurements in 0° and 80° emission relative to the surface normal. The performance of DASSA on a first macroscopic liquid system will be demonstrated.

  8. Dual analyzer system for surface analysis dedicated for angle-resolved photoelectron spectroscopy at liquid surfaces and interfaces

    International Nuclear Information System (INIS)

    Niedermaier, Inga; Kolbeck, Claudia; Steinrück, Hans-Peter; Maier, Florian

    2016-01-01

    The investigation of liquid surfaces and interfaces with the powerful toolbox of ultra-high vacuum (UHV)-based surface science techniques generally has to overcome the issue of liquid evaporation within the vacuum system. In the last decade, however, new classes of liquids with negligible vapor pressure at room temperature—in particular, ionic liquids (ILs)—have emerged for surface science studies. It has been demonstrated that particularly angle-resolved X-ray Photoelectron Spectroscopy (ARXPS) allows for investigating phenomena that occur at gas-liquid and liquid-solid interfaces on the molecular level. The results are not only relevant for IL systems but also for liquids in general. In all of these previous ARXPS studies, the sample holder had to be tilted in order to change the polar detection angle of emitted photoelectrons, which restricted the liquid systems to very thin viscous IL films coating a flat solid support. We now report on the concept and realization of a new and unique laboratory “Dual Analyzer System for Surface Analysis (DASSA)” which enables fast ARXPS, UV photoelectron spectroscopy, imaging XPS, and low-energy ion scattering at the horizontal surface plane of macroscopically thick non-volatile liquid samples. It comprises a UHV chamber equipped with two electron analyzers mounted for simultaneous measurements in 0° and 80° emission relative to the surface normal. The performance of DASSA on a first macroscopic liquid system will be demonstrated.

  9. Comparison of immersed liquid and air cooling of NASA's Airborne Information Management System

    Science.gov (United States)

    Hoadley, A. W.; Porter, A. J.

    1992-01-01

    The Airborne Information Management System (AIMS) is currently under development at NASA Dryden Flight Research Facility. The AIMS is designed as a modular system utilizing surface mounted integrated circuits in a high-density configuration. To maintain the temperature of the integrated circuits within manufacturer's specifications, the modules are to be filled with Fluorinert FC-72. Unlike ground based liquid cooled computers, the extreme range of the ambient pressures experienced by the AIMS requires the FC-72 be contained in a closed system. This forces the latent heat absorbed during the boiling to be released during the condensation that must take within the closed module system. Natural convection and/or pumping carries the heat to the outer surface of the AIMS module where the heat transfers to the ambient air. This paper will present an evaluation of the relative effectiveness of immersed liquid cooling and air cooling of the Airborne Information Management System.

  10. A system for traceable measurement of the microwave complex permittivity of liquids at high pressures and temperatures

    International Nuclear Information System (INIS)

    Dimitrakis, G A; Robinson, J; Kingman, S; Lester, E; George, M; Poliakoff, M; Harrison, I; Gregory, A P; Lees, K

    2009-01-01

    A system has been developed for direct traceable dielectric measurements on liquids at high pressures and temperatures. The system consists of a coaxial reflectometric sensor terminated by a metallic cylindrical cell to contain the liquid. It has been designed for measurements on supercritical liquids, but as a first step measurements on dielectric reference liquids were performed. This paper reports on a full evaluation of the system up to 2.5 GHz using methanol, ethanol and n-propanol at pressures up to 9 MPa and temperatures up to 273 °C. A comprehensive approach to the evaluation of uncertainties using Monte Carlo modelling is used

  11. Activity and stability of feruloyl esterase A from Aspergillus niger in ionic liquid systems

    DEFF Research Database (Denmark)

    Zeuner, Birgitte; Riisager, Anders; Meyer, Anne S.

    in solvents that favour synthesis over hydrolysis, i.e. systems with low water content such as organic solvents or ionic liquids (ILs). The esterification of sinapic acid with glycerol catalysed by FAE A from Aspergillus niger (AnFaeA) in a series of ILs containing 15% (v/v) buffer showed that An...

  12. Pathology of the reproductive system and thyroid of women liquidators of Chernobyl accident

    International Nuclear Information System (INIS)

    Babkin, A.A.; Merkulova, I.P.

    2014-01-01

    Data of the annual health follow up of the 100 women-liquidators of the Chernobyl accident performed by Republic centre of medical rehabilitation and balneotherapy have been analyzed. The high frequency of thyroid disease as well as the reproductive system pathology revealed: they were detected in 96% and 87% patients correspondingly. Oncological diseases were detected in 25% of studied cohort. (authors)

  13. Primitive Liquid Water of the Solar System in an Aqueous Altered Carbonaceous Chondrite

    Science.gov (United States)

    Tsuchiyama, A.; Miyake, A.; Kitayama, A.; Matsuno, J.; Takeuchi, A.; Uesugi, K.; Suzuki, Y.; Nakano, T.; Zolensky, M. E.

    2016-01-01

    Non-destructive 3D observations of the aqueous altered CM chondrite Sutter's Mill using scanning imaging x-ray microscopy (SIXM) showed that some of calcite and enstatite grains contain two-phase inclusion, which is most probably composed of liquid water and bubbles. This water should be primitive water responsible for aqueous alteration in an asteroid in the early solar system.

  14. Conductive properties of switchable photoluminescence thermosetting systems based on liquid crystals.

    Science.gov (United States)

    Tercjak, Agnieszka; Gutierrez, Junkal; Ocando, Connie; Mondragon, Iñaki

    2010-03-16

    Conductive properties of different thermosetting materials modified with nematic 4'-(hexyl)-4-biphenyl-carbonitrile (HBC) liquid crystal and rutile TiO(2) nanoparticles were successfully studied by means of tunneling atomic force miscroscopy (TUNA). Taking into account the liquid crystal state of the HBC at room temperature, depending on both the HBC content and the presence of TiO(2) nanoparticles, designed materials showed different TUNA currents passed through the sample. The addition of TiO(2) nanoparticles into the systems multiply the detected current if compared to the thermosetting systems without TiO(2) nanoparticles and simultaneously stabilized the current passed through the sample, making the process reversible since the absolute current values were almost the same applying both negative and positive voltage. Moreover, thermosetting systems modified with liquid crystals with and without TiO(2) nanoparticles are photoluminescence switchable materials as a function of temperature gradient during repeatable heating/cooling cycle. Conductive properties of switchable photoluminescence thermosetting systems based on liquid crystals can allow them to find potential application in the field of photoresponsive devices, with a high contrast ratio between transparent and opaque states.

  15. Novel routes to liquid-based self-healing polymer systems

    NARCIS (Netherlands)

    Mookhoek, S.D.

    2010-01-01

    Inspired by the current state-of-the-art and the progressing advancements in the field of self-healing materials, this thesis addresses several novel routes to advance the concept of liquid-based self-healing polymer systems. This thesis presents the concept and characterisation of a one-component

  16. Nonlinear absorption of fullerene- and nanotubes-doped liquid crystal systems

    Czech Academy of Sciences Publication Activity Database

    Kamanina, N.; Reshak, Ali H; Vasiliev, P.Y.; Vangonen, A. I.; Studeonov, V. I.; Usanov, Y. E.; Ebothe, J.; Gondek, E.; Wojcik, W.; Danel, A.

    2009-01-01

    Roč. 41, č. 3 (2009), s. 391-394 ISSN 1386-9477 Institutional research plan: CEZ:AV0Z60870520 Keywords : nonlinear absorption properties * organic electrooptical systems * liquid crystal * fullerene s * nanotubes * PVK-derivatives Subject RIV: BO - Biophysics Impact factor: 1.177, year: 2009

  17. MEMBRANOUS FLOWS IN GAS-LIQUID COLLECTORS-REGENERATORS OF SOLAR ABSORPTIVE SYSTEMS FEATURES

    Directory of Open Access Journals (Sweden)

    Doroshenko А.V.

    2009-12-01

    Full Text Available Article is devoted to the creation of new generation of solar collectors of the gas-liquid type, intended for use in alternative refrigerating and conditioning systems of drying-evaporating type with direct solar regeneration of absorbent. Special attention is given to the study of membranous flows features on inclined surfaces, including questions of such flows stability.

  18. Injecting a liquid bacteria-based repair system to make porous network conrete healed

    NARCIS (Netherlands)

    Sangadji, S.; Wiktor, V.A.C.; Jonkers, H.M.; Schlangen, H.E.J.G.

    2013-01-01

    Bacteria induced calcite precipitation has been proven to be effective in making concrete structure self-healing. In Microlab TU Delft, the concept has been enhanced by developing a liquid bacteria-based concrete repair system. The solution contains calcite precipitating bacteria, nutrients and

  19. Counting efficiency for liquid scintillator systems with a single multiplier phototube

    International Nuclear Information System (INIS)

    Grau Malonda, A.; Garcia-Torano, E.

    1984-01-01

    In this paper counting efficiency as a function of a free parameter (the figure of merit) has been computed. The results are applicable to liquid scintillator systems with a single multiplier phototube. Tables of counting efficiency for 62 pure beta emitters are given for figures of merit in the range 0.25 to 50. (Author) 16 refs

  20. Evaluation of air-liquid interface exposure systems for in vitro assessment of airborne pollutants

    Science.gov (United States)

    Exposure of cells to airborne pollutants at the air-liquid interface (ALI) is a more realistic approach than exposures of submerged cells. The published literature, however, describes irreproducible and/or unrealistic experimental conditions using ALI systems. We have compared fi...

  1. Modeling of vapor-liquid-solid equilibrium in gas - aqueous electrolyte systems

    DEFF Research Database (Denmark)

    Thomsen, Kaj; Rasmussen, Peter

    1999-01-01

    A thermodynamic model for the description of vapor-liquid-solid equilibria is introduced. This model is a combination of the extended UNIQUAC model for electrolytes and the Soave-Redlich-Kwong cubic equation of state. The model has been applied to aqueous systems containing ammonia and/or carbon ...

  2. Vapor-Liquid Equilibrium Measurements and Modeling of the Propyl Mercaptan plus Methane plus Water System

    DEFF Research Database (Denmark)

    Awan, Javeed; Thomsen, Kaj; Coquelet, Christophe

    2010-01-01

    In this work, vapor−liquid equilibrium (VLE) measurements of propyl mercaptan (PM) in pure water were performed at three different temperatures, (303, 323, and 365) K, with a pressure variation from (1 to 8) MPa. The total system pressure was maintained by CH4. The inlet mole fraction of propyl...

  3. Isobaric (vapour + liquid + liquid) equilibrium data for (di-n-propyl ether + n-propyl alcohol + water) and (diisopropyl ether + isopropyl alcohol + water) systems at 100 kPa

    International Nuclear Information System (INIS)

    Lladosa, Estela; Monton, Juan B.; Burguet, MaCruz; Torre, Javier de la

    2008-01-01

    Isobaric (vapour + liquid + liquid) equilibria were measured for the (di-n-propyl ether + n-propyl alcohol + water) and (diisopropyl ether + isopropyl alcohol + water) system at 100 kPa. The apparatus used for the determination of (vapour + liquid + liquid) equilibrium data was an all-glass dynamic recirculating still with an ultrasonic homogenizer couple to the boiling flask. The experimental data demonstrated the existence of a heterogeneous ternary azeotrope for both ternary systems. The (vapour + liquid + liquid) equilibria data were found to be thermodynamically consistent for both systems. The experimental data were compared with the estimation using UNIQUAC and NRTL models and the prediction of UNIFAC model

  4. Seismic analysis of liquid metal reactor piping systems

    International Nuclear Information System (INIS)

    Wang, C.Y.

    1987-01-01

    This paper describes the finite-element numerical algorithm and its applications to LMR piping under seismic excitations. A time-history analysis technique using the implicit temporal integration scheme is addressed. A 3-D pipe element is formulated which has eight degrees of freedom per node (three displacements, three rotations, one membrane displacement, and one bending rotation) to account for the hoop, flexural, rotational, and torsional modes of the piping system. Both geometric and material nonlinearities are considered. This algorithm is unconditionally stable and is particularly suited for the seismic analysis. (orig./GL)

  5. Seismic analysis of liquid metal reactor piping systems

    International Nuclear Information System (INIS)

    Wang, C.Y.

    1987-01-01

    To safely assess the adequacy of the LMR piping, a three-dimensional piping code, SHAPS, has been developed at Argonne National Laboratory. This code was initially intended for calculating hydrodynamic-wave propagation in a complex piping network. It has salient features for treating fluid transients of fluid-structure interactions for piping with in-line components. The code also provides excellent structural capabilities of computing stresses arising from internal pressurization and 3-D flexural motion of the piping system. As part of the development effort, the SHAPS code has been further augmented recently by introducing the capabilities of calculating piping response subjected to seismic excitations. This paper describes the finite-element numerical algorithm and its applications to LMR piping under seismic excitations. A time-history analysis technique using the implicit temporal integration scheme is addressed. A 3-D pipe element is formulated which has eight degrees of freedom per node (three displacements, three rotations, one membrane displacement, and one bending rotation) to account for the hoop, flexural, rotational, and torsional modes of the piping system. Both geometric and material nonlinearities are considered. This algorithm is unconditionally stable and is particularly suited for the seismic analysis

  6. Stationary Flowing Liquid Lithium (SFLiLi) systems for tokamaks

    Science.gov (United States)

    Zakharov, Leonid; Gentile, Charles; Roquemore, Lane

    2013-10-01

    The present approach to magnetic fusion which relies on high recycling plasma-wall interaction has exhausted itself at the level of TFTR, JET, JT-60 devices with no realistic path to the burning plasma. Instead, magnetic fusion needs a return to its original idea of insulation of the plasma from the wall, which was the dominant approach in the 1970s and upon implementations has a clear path to the DEMO device with PDT ~= 100 MW and Qelectric > 1 . The SFLiLi systems of this talk is the technology tool for implementation of the guiding idea of magnetic fusion. It utilizes the unique properties of flowing LiLi to pump plasma particles and, thus, insulate plasma from the walls. The necessary flow rate, ~= 1 g3/s, is very small, thus, making the use of lithium practical and consistent with safety requirements. The talk describes how chemical activity of LiLi, which is the major technology challenge of using LiLi in tokamaks, is addressed by SFLiLi systems at the level of already performed (HT-7) experiment, and in ongoing implementations for a prototype of SFLiLi for tokamak divertors and the mid-plane limiter for EAST tokamak (to be tested in the next experimental campaign). This work is supported by US DoE contract No. DE-AC02-09-CH11466.

  7. Liquid-Liquid Equilibrium and Excess Enthalpies in the Binary System 2-Methylpentane + N,N-Dimethylformamide

    Czech Academy of Sciences Publication Activity Database

    Bendová, Magdalena; Řehák, K.; Matouš, J.; Novák, J. P.

    2004-01-01

    Roč. 49, č. 5 (2004), s. 1318-1322 ISSN 0021-9568 Institutional research plan: CEZ:AV0Z4072921 Keywords : liquid-liquid equilibrium * excess enthalpies * thermodynamic models Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 1.368, year: 2004

  8. (Liquid + liquid) equilibrium of {l_brace}water + phenol + (1-butanol, or 2-butanol, or tert-butanol){r_brace} systems

    Energy Technology Data Exchange (ETDEWEB)

    Hadlich de Oliveira, Leonardo [School of Chemical Engineering, State University of Campinas, UNICAMP, P.O. Box 6066, 13083-970 Campinas-SP (Brazil); Aznar, Martin, E-mail: maznar@feq.unicamp.b [School of Chemical Engineering, State University of Campinas, UNICAMP, P.O. Box 6066, 13083-970 Campinas-SP (Brazil)

    2010-11-15

    (Liquid + liquid) equilibrium (LLE) and binodal curve data were determined for the systems (water + phenol + tert-butanol) at T = 298.15 K, (water + phenol + 2-butanol) and (water + phenol + 1-butanol) at T = 298.15 K and T = 313.15 K by the combined techniques of densimetry and refractometry. Type I curve (for tert-butanol) and Type II curves (for 1- and 2-butanol) were found. The data were correlated with the NRTL model and the parameters estimated present root mean square deviations below 2% for the system with tert-butanol and lower than 0.8% for the other systems.

  9. Ion Transfer Voltammetry Associated with Two Polarizable Interfaces Within Water and Moderately Hydrophobic Ionic Liquid Systems

    DEFF Research Database (Denmark)

    Gan, Shiyu; Zhou, Min; Zhang, Jingdong

    2013-01-01

    An electrochemical system composed of two polarizable interfaces (the metallic electrode|water and water|ionic liquid interfaces), namely two‐polarized‐interface (TPI) technique, has been proposed to explore the ion transfer processes between water and moderately hydrophobic ionic liquids (W...... to an extremely narrow polarized potential window (ppw) caused by these moderately hydrophobic ionic components. In this article, we show that TPI technique has virtually eliminated the ppw limitation based on a controlling step of concentration polarization at the electrode|water interface. With the aid...

  10. Advances in liquid metal cooled ADS systems, and useful results for the design of IFMIF

    International Nuclear Information System (INIS)

    Massaut, V.; Debruyn, D.; Decreton, M.

    2007-01-01

    Full text of publication follows: Liquid metal cooled Accelerator Driven Systems (ADS) have a lot of design commonalities with the design of IFMIF. The use of a powerful accelerator and a liquid metal spallation source makes it similar to the main features of the IFMIF irradiator. Developments in the field of liquid metal ADS can thus be very useful for the design phase of IFMIF, and synergy between both domains should be enhanced to avoid dubbing work already done. The liquid metal ADS facilities are developed for testing materials under high fast (> 1 MeV) neutron flux, and also for studying the transmutation of actinides as foreseen in the P and T (Partitioning and Transmutation) strategy of future fission industry. The ADS are mostly constituted of a sub-critical fission fuel assembly matrix, a spallation source (situated at the centre of the fuel arrangement) and a powerful accelerator targeting the spallation source. In liquid metal ADS, the spallation source is a liquid metal (like Pb-Bi) which is actively cooled to remove the power generated by the particle beam, spallation reactions and neutrons. Based on an advanced ADS design (e.g. the MYRRHA/XT-ADS facility), the paper shows the various topics which are common for both facilities (ADS and IFMIF) and highlights their respective specificities, leading to focused R and D activities. This would certainly cover the common aspects related to high power accelerators, liquid metal targets and beam-target coupling. But problems of safety, radioprotection, source heating and cooling, neutrons shielding, etc... lead also to common features and developments. Results already obtained for the ADS development will illustrate this synergy. This paper will therefore allow to take profit of recent developments in both fission and fusion programs and enhance the collaboration among the R and D teams in both domains. (authors)

  11. Advances in liquid metal cooled ADS systems, and useful results for the design of IFMIF

    Energy Technology Data Exchange (ETDEWEB)

    Massaut, V.; Debruyn, D. [SCK CEN, Mol (Belgium); Decreton, M. [Ghent Univ., Dept. of Applied Physics (Belgium)

    2007-07-01

    Full text of publication follows: Liquid metal cooled Accelerator Driven Systems (ADS) have a lot of design commonalities with the design of IFMIF. The use of a powerful accelerator and a liquid metal spallation source makes it similar to the main features of the IFMIF irradiator. Developments in the field of liquid metal ADS can thus be very useful for the design phase of IFMIF, and synergy between both domains should be enhanced to avoid dubbing work already done. The liquid metal ADS facilities are developed for testing materials under high fast (> 1 MeV) neutron flux, and also for studying the transmutation of actinides as foreseen in the P and T (Partitioning and Transmutation) strategy of future fission industry. The ADS are mostly constituted of a sub-critical fission fuel assembly matrix, a spallation source (situated at the centre of the fuel arrangement) and a powerful accelerator targeting the spallation source. In liquid metal ADS, the spallation source is a liquid metal (like Pb-Bi) which is actively cooled to remove the power generated by the particle beam, spallation reactions and neutrons. Based on an advanced ADS design (e.g. the MYRRHA/XT-ADS facility), the paper shows the various topics which are common for both facilities (ADS and IFMIF) and highlights their respective specificities, leading to focused R and D activities. This would certainly cover the common aspects related to high power accelerators, liquid metal targets and beam-target coupling. But problems of safety, radioprotection, source heating and cooling, neutrons shielding, etc... lead also to common features and developments. Results already obtained for the ADS development will illustrate this synergy. This paper will therefore allow to take profit of recent developments in both fission and fusion programs and enhance the collaboration among the R and D teams in both domains. (authors)

  12. Trial fabrication and preliminary characterization of electrical insulator for liquid metal system

    International Nuclear Information System (INIS)

    Nakamichi, Masaru; Kawamura, Hiroshi; Oyamada, Rokuro

    1995-03-01

    In the design of the liquid metal blanket, MHD pressure drop is one of critical issues. Ceramic coating on the surface of structural material is considered as an electrical insulator to reduce the MHD pressure drop. Ceramic coating such as Y 2 O 3 is a promising electrical insulator due to its high electrical resistivity and good compatibility with liquid lithium. This report describes the trial fabrication and preliminary characterization of electrical insulator for a design study of the liquid metal system. From the results of trial fabrication and preliminary characterization, it is concluded that densified atmospheric plasma spray Y 2 O 3 coating with 410SS undercoating between 316SS substrate and Y 2 O 3 coating is suitable for Y 2 O 3 coating fabrication. (author)

  13. Liquid Metals as Plasma-facing Materials for Fusion Energy Systems: From Atoms to Tokamaks

    Energy Technology Data Exchange (ETDEWEB)

    Stone, Howard A. [Princeton Univ., NJ (United States); Koel, Bruce E. [Princeton Univ., NJ (United States); Bernasek, Steven L. [Princeton Univ., NJ (United States); Carter, Emily A. [Princeton Univ., NJ (United States); Debenedetti, Pablo G. [Princeton Univ., NJ (United States); Panagiotopoulos, Athanassios Z. [Princeton Univ., NJ (United States)

    2017-06-23

    The objective of our studies was to advance our fundamental understanding of liquid metals as plasma-facing materials for fusion energy systems, with a broad scope: from atoms to tokamaks. The flow of liquid metals offers solutions to significant problems of the plasma-facing materials for fusion energy systems. Candidate metals include lithium, tin, gallium, and their eutectic combinations. However, such liquid metal solutions can only be designed efficiently if a range of scientific and engineering issues are resolved that require advances in fundamental fluid dynamics, materials science and surface science. In our research we investigated a range of significant and timely problems relevant to current and proposed engineering designs for fusion reactors, including high-heat flux configurations that are being considered by leading fusion energy groups world-wide. Using experimental and theoretical tools spanning atomistic to continuum descriptions of liquid metals, and bridging surface chemistry, wetting/dewetting and flow, our research has advanced the science and engineering of fusion energy materials and systems. Specifically, we developed a combined experimental and theoretical program to investigate flows of liquid metals in fusion-relevant geometries, including equilibrium and stability of thin-film flows, e.g. wetting and dewetting, effects of electromagnetic and thermocapillary fields on liquid metal thin-film flows, and how chemical interactions and the properties of the surface are influenced by impurities and in turn affect the surface wetting characteristics, the surface tension, and its gradients. Because high-heat flux configurations produce evaporation and sputtering, which forces rearrangement of the liquid, and any dewetting exposes the substrate to damage from the plasma, our studies addressed such evaporatively driven liquid flows and measured and simulated properties of the different bulk phases and material interfaces. The range of our studies

  14. Method of and system for identification or estimation of a refractive index of a liquid

    DEFF Research Database (Denmark)

    2015-01-01

    This invention relates to a method of and a system (100) for identification or estimation of a refractive index of a liquid (120) comprising a light receiving part (111) adapted to receive polarised or non-polarised light (125; 135), a light emitting part (112) adapted, during use, to transmit...... light (130), an optical structure (110) being adapted to receive, during use, polarised light (125) via or from the light receiving part (111), and being adapted to receive, during use, a liquid (120) having a predetermined refractive index to be identified or estimated, and a first polariser (115......); is adapted, during use, to pass the received light (135) through the optical path so that a narrow wavelength range of the transmitted light (130) is influenced by the predetermined refractive index of the received liquid (120) and that the influenced narrow wavelength range, when observed by a user and...

  15. Phase diagram and universality of the Lennard-Jones gas-liquid system

    KAUST Repository

    Watanabe, Hiroshi

    2012-01-01

    The gas-liquid phase transition of the three-dimensional Lennard-Jones particles system is studied by molecular dynamics simulations. The gas and liquid densities in the coexisting state are determined with high accuracy. The critical point is determined by the block density analysis of the Binder parameter with the aid of the law of rectilinear diameter. From the critical behavior of the gas-liquid coexisting density, the critical exponent of the order parameter is estimated to be β = 0.3285(7). Surface tension is estimated from interface broadening behavior due to capillary waves. From the critical behavior of the surface tension, the critical exponent of the correlation length is estimated to be ν = 0.63(4). The obtained values of β and ν are consistent with those of the Ising universality class. © 2012 American Institute of Physics.

  16. Palladium catalyst system comprising zwitterion and/or acid-functionalized ionic liquid

    DEFF Research Database (Denmark)

    2011-01-01

    The present invention concerns a catalyst system in particular a catalyst system comprising Palladium (Pd), a zwitterion and/or an acid-functionalized ionic liquid, and one or more phosphine ligands, wherein the Pd catalyst can be provided by a complex precursor, such as Pd(CH3COO)2, PdCI2, Pd(CH3......COCHCOCH3), Pd (CF3COO)2, Pd(PPh3)4 or Pd2(dibenzylideneacetone)3. Such catalyst systems can be used for e.g. alkoxycarbonylation reactions, carboxylation reactions, and/or in a co-polymerization reaction, e.g. in the production of methyl propionate and/or propanoic acid, optionally in processes forming...... methyl methacrylate and/or methacrylic acid. Catalyst systems according to the invention are suitable for reactions forming separable product and catalyst phases and supported ionic liquid phase SILP applications....

  17. Design and simulation of liquid cooled system for power battery of PHEV

    Science.gov (United States)

    Wang, Jianpeng; Xu, Haijun; Xu, Xiaojun; Pan, Cunyun

    2017-09-01

    Various battery chemistries have different responses to failure, but the most common failure mode of a cell under abusive conditions is the generation of heat and gas. To prevent battery thermal abuse, a battery thermal management system is essential. An excellent design of battery thermal management system can ensure that the battery is working at a suitable temperature and keeps the battery temperature diffenence at 2-3 °C. This paper presents a thermal-elcetric coupling model for a 37Ah lithium battery using AMESim. A liquid cooled system of hybrid electric vehicle power battery is designed to control the battery temperature.A liquid cooled model of thermal management system is built using AMESim, the simulation results showed that the temperature difference within 3°C of cell in the pack.

  18. High Bulk Modulus of Ionic Liquid and Effects on Performance of Hydraulic System

    Directory of Open Access Journals (Sweden)

    Milan Kambic

    2014-01-01

    Full Text Available Over recent years ionic liquids have gained in importance, causing a growing number of scientists and engineers to investigate possible applications for these liquids because of their unique physical and chemical properties. Their outstanding advantages such as nonflammable liquid within a broad liquid range, high thermal, mechanical, and chemical stabilities, low solubility for gases, attractive tribological properties (lubrication, and very low compressibility, and so forth, make them more interesting for applications in mechanical engineering, offering great potential for new innovative processes, and also as a novel hydraulic fluid. This paper focuses on the outstanding compressibility properties of ionic liquid EMIM-EtSO4, a very important physical chemically property when IL is used as a hydraulic fluid. This very low compressibility (respectively, very high Bulk modulus, compared to the classical hydraulic mineral oils or the non-flammable HFDU type of hydraulic fluids, opens up new possibilities regarding its usage within hydraulic systems with increased dynamics, respectively, systems’ dynamic responses.

  19. (Vapor + liquid + liquid) equilibrium measurements and correlation for {1,1,2,2-tetrafluoroethane (R134) + isobutane (R600a)} system

    International Nuclear Information System (INIS)

    Zhao, Yanxing; Gong, Maoqiong; Dong, Xueqiang; Guo, Hao; Wu, Jianfeng

    2014-01-01

    Highlights: • VLLE data for the (R134 + R600a) system at temperatures ranging from (235.311 to 241.720) K was measured. • The experiment was carried out using an apparatus based on the recirculation of vapor into liquid. • Correlation of VLE data was made using PR−HV−NRTL model. • A strong critical opalescence was observed. - Abstract: In this work, a study on the (vapor + liquid + liquid) equilibrium (VLLE) for the (R134 + R600a) system was carried out using an apparatus based on the recirculation of vapor into liquid at temperatures ranging from (235.311 to 241.720) K. The uncertainties of the composition, temperature, and pressure were less than ±0.005, ±5 mK and ±0.5 kPa, respectively. Thirty-eight experimental p–T–x data covering both branches of the binodal boundary and nineteen experimental p–T–y data were presented. Three numerical methods were used to obtain the second liquid phase compositions coexisting in equilibrium, and all the three methods lead to consistent results. Moreover, all of the experimental data were correlated by the Peng–Robinson equation of state (PR EoS) with the Huron–Vidal (HV) mixing rule involving the non-random two-liquid (NRTL) activity coefficient model. Then the vapor phase compositions were calculated. The results show good agreement with the experimental data, and the maximum deviation is less than 0.006

  20. Experimental investigation of liquid-liquid system drop size distribution in Taylor-Couette flow and its application in the CFD simulation

    Science.gov (United States)

    Farzad, Reza; Puttinger, Stefan; Pirker, Stefan; Schneiderbauer, Simon

    Liquid-liquid systems are widely used in the several industries such as food, pharmaceutical, cosmetic, chemical and petroleum. Drop size distribution (DSD) plays a key role as it strongly affects the overall mass and heat transfer in the liquid-liquid systems. To understand the underlying mechanisms single drop breakup experiments have been done by several researchers in the Taylor-Couette flow; however, most of those studies concentrate on the laminar flow regime and therefore, there is no sufficient amount of data in the case of in turbulent flows. The well-defined pattern of the Taylor-Couette flow enables the possibility to investigate DSD as a function of the local fluid dynamic properties, such as shear rate, which is in contrast to more complex devices such as stirred tank reactors. This paper deals with the experimental investigation of liquid-liquid DSD in Taylor-Couette flow. From high speed camera images we found a simple correlation for the Sauter mean diameter as a function of the local shear employing image processing. It is shown that this correlation holds for different oil-in-water emulsions. Finally, this empirical correlation for the DSD is used as an input data for a CFD simulation to compute the local breakup of individual droplets in a stirred tank reactor.

  1. (Liquid + liquid) equilibria of (water + linalool + limonene) ternary system at T = (298.15, 308.15, and 318.15) K

    International Nuclear Information System (INIS)

    Gramajo de Doz, Monica B.; Cases, Alicia M.; Solimo, Horacio N.

    2008-01-01

    (Liquid + liquid) equilibrium (LLE) data for {water (1) + linalool (2) + limonene (3)} ternary system at T = (298.15, 308.15, and 318.15 ± 0.05) K are reported. The organic chemicals were quantified by gas chromatography using a flame ionisation detector while water was quantified using a thermal conductivity detector. The effect of the temperature on (liquid + liquid) equilibrium is determined and discussed. Experimental data for the ternary mixture are compared with values calculated by the NRTL and UNIQUAC equations, and predicted by means of the UNIFAC group contribution method. It is found that the UNIQUAC and NRTL models provide a good correlation of the solubility curve at these three temperatures, while comparing the calculated values with the experimental ones, the best fit is obtained with the NRTL model. Finally, the UNIFAC model provides poor results, since it predicts a greater heterogeneous region than experimentally observed

  2. Potential of multi-purpose liquid metallic fuelled fast reactor (MPFR) as a hydrogen production system

    International Nuclear Information System (INIS)

    Endo, H.; Ninokata, H.; Netchaev, A.; Sawada, T.

    2001-01-01

    Nuclear energy is the only effective alternative energy source to fossil fuels in the next century. Therefore future nuclear power plants should satisfy the following three requirements: i) multiple energy conversion capability with high temperature not only for electricity generation but also for hydrogen production, ii) extended siting capability so as to eliminate on-site refuelling, and iii) passive safety features. An aim of this paper is to describe the basic concept of the multi-purpose liquid metallic fuelled fast reactor system (MPFR). The MPFR introduces the U-Pu-X (X: Mn, Fe, Co) liquid metallic alloy with Ta and Ta/TaC structural materials, and satisfies all of the conditions listed above based on the following characteristics of the liquid metallic fuel: high temperature operation between 650 deg C (sodium-cooled system) and 1 200 deg C (lead-cooled system), a core lifetime of 15-30 years without radiation damage of fuel materials, and enhanced passive safety by the thermal expansion of liquid fuel and the avoidance of re-criticality due to local core fuel dispersion at fuel failure events. (authors)

  3. A filter paper-based liquid culture system for citrus shoot organogenesis - a mixture-amount experiment

    Science.gov (United States)

    The objective of this study was to determine the effects of a static liquid culture system on shoot regeneration from citrus epicotyl explants. Two citrus types were used, Carrizo citrange and Ridge Pineapple sweet orange. A liquid culture system comprised of a Petri dish, cellulose filter paper dis...

  4. Systemic embolism produced by subcutaneous injections of liquid silicone for esthetic purposes

    International Nuclear Information System (INIS)

    Falconi, Guillermo

    2003-01-01

    Even though its use is not recommended, liquid silicone is a substance that has been used illegally for esthetic purposes for a long time. A case report is presented in which a young woman was injected subcutaneously, by an uncertified practitioner, industrial fluid silicone and subsequently developed a case of systemic embolism with pulmonary, skin and ocular complications. This article explains the physiopathology and the different manifestations of systemic embolism produced by fluid silicone. TAC was used. (The author)

  5. Definition and means of maintaining the process vacuum liquid detection interlock systems portion of the PFP safety envelope

    International Nuclear Information System (INIS)

    THOMAS, R.J.

    1999-01-01

    The Process Vacuum Liquid Detection interlock systems prevent intrusion of process liquids into the HEPA filters downstream of demisters No.6 and No.7 during Process Vacuum System operation. This prevents liquid intrusion into the filters, which could cause a criticality. The Safety Envelope (SE) includes the equipment, which detects the presence of liquids in the vacuum headers; isolates the filters; shuts down the vacuum pumps; and alarms the condition. This report identifies the equipment in the SE operating, maintenance, and surveillance procedures needed to maintain the SE equipment; and rationale for exclusion of some equipment and testing from the SE

  6. Liquid Rocket Booster (LRB) for the Space Transportation System (STS) Systems Study; Volume 1 - Executive Summary

    National Research Council Canada - National Science Library

    Ware, Larry

    1989-01-01

    ...) solid rocket boosters (SRBs) with liquid rocket boosters (LRBs), Figure 1.0-1. The main objectives of a LRB substitution for the SRB were increased STS safety and reliability and increased payload performance...

  7. Absorber and regenerator models for liquid desiccant air conditioning systems. Validation and comparison using experimental data

    Energy Technology Data Exchange (ETDEWEB)

    Krause, M.; Heinzen, R.; Jordan, U.; Vajen, K. [Kassel Univ., Inst. of Thermal Engineering, Kassel (Germany); Saman, W.; Halawa, E. [Sustainable Energy Centre, Univ. of South Australia, Mawson Lakes, Adelaide (Australia)

    2008-07-01

    Solar assisted air conditioning systems using liquid desiccants represent a promising option to decrease high summer energy demand caused by electrically driven vapor compression machines. The main components of liquid desiccant systems are absorbers for dehumidifying and cooling of supply air and regenerators for concentrating the desiccant. However, high efficient and validated reliable components are required and the design and operation have to be adjusted to each respective building design, location, and user demand. Simulation tools can help to optimize component and system design. The present paper presents new developed numerical models for absorbers and regenerators, as well as experimental data of a regenerator prototype. The models have been compared with a finite-difference method model as well as experimental data. The data are gained from the regenerator prototype presented and an absorber presented in the literature. (orig.)

  8. Analysis and computer simulation for transient flow in complex system of liquid piping

    International Nuclear Information System (INIS)

    Mitry, A.M.

    1985-01-01

    This paper is concerned with unsteady state analysis and development of a digital computer program, FLUTRAN, that performs a simulation of transient flow behavior in a complex system of liquid piping. The program calculates pressure and flow transients in the liquid filled piping system. The analytical model is based on the method of characteristics solution to the fluid hammer continuity and momentum equations. The equations are subject to wide variety of boundary conditions to take into account the effect of hydraulic devices. Water column separation is treated as a boundary condition with known head. Experimental tests are presented that exhibit transients induced by pump failure and valve closure in the McGuire Nuclear Station Low Level Intake Cooling Water System. Numerical simulation is conducted to compare theory with test data. Analytical and test data are shown to be in good agreement and provide validation of the model

  9. Performance analysis of a mixed nitride fuel system for an advanced liquid metal reactor

    International Nuclear Information System (INIS)

    Lyon, W.F.; Baker, R.B.; Leggett, R.D.

    1991-01-01

    In this paper, the conceptual development and analysis of a proposed mixed nitride driver and blanket fuel system for a prototypic advanced liquid metal reactor design is performed. As a first step, an intensive literature survey is completed on the development and testing of nitride fuel systems. Based on the results of this survey, prototypic mixed nitride fuel and blanket pins is designed and analyzed using the SIEX computer code. The analysis predicts that the nitride fuel consistently operated at peak temperatures and cladding strain levels that compared quite favorably with competing fuel designs. These results, along with data available in the literature on nitride fuel performance, indicate that a nitride fuel system should offer enhanced capabilities for advanced liquid metal reactors

  10. Performance analysis of a mixed nitride fuel system for an advanced liquid metal reactor

    International Nuclear Information System (INIS)

    Lyon, W.F.; Baker, R.B.; Leggett, R.D.

    1990-11-01

    The conceptual development and analysis of a proposed mixed nitride driver and blanket fuel system for a prototypic advanced liquid metal reactor design has been performed. As a first step, an intensive literature survey was completed on the development and testing of nitride fuel systems. Based on the results of this survey, prototypic mixed nitride fuel and blanket pins were designed and analyzed using the SIEX computer code. The analysis predicted that the nitride fuel consistently operated at peak temperatures and cladding strain levels that compared quite favorably with competing fuel designs. These results, along with data available in the literature on nitride fuel performance, indicate that a nitride fuel system should offer enhanced capabilities for advanced liquid metal reactors. 13 refs., 10 figs., 2 tabs

  11. Microchip systems for imaging liquid and high temperature processes in TEM & SEM

    DEFF Research Database (Denmark)

    Jensen, Eric; Canepa, Silvia; Møller-Nilsen, Rolf Erling Robberstad

    2014-01-01

    Microchips systems have found their way into electron microscopes in order to make miniatureplatforms for controlled liquid and gaseous environments that also begin to include electricalcontacts and other types of interactions with the sample, such as application of forces andirradiation with light.......This presentation will explain the different types of microchip systems and give examples of someof the results we have achieved with our devices and examples of how such devices can be usedfor research related to energy storage and conversion.Heaters can be made in several ways, and monocrystalline silicon......]. Both systems will allowhigh resolution imaging of heterogeneous electrochemical processes such as those in batteries.Based on the suspended microfluidic channels, we are also developing microchips that enableultrafast freezing of processes in liquids....

  12. Vibration analysis for IHTS piping system of LMR conveying hot liquid sodium

    International Nuclear Information System (INIS)

    Koo, Gyeong Hoi; Lee, Hyeong Yeon; Lee, Jae Han

    2001-01-01

    In this paper, the vibration characteristics of IHTS(Intermediate Heat Transfer System) piping system of LMR(Liquid Metal Reactor) conveying hot liquid sodium are investigated to eliminate the pipe supports for economic reasons. To do this, a 3-dimensional straight pipe element and a curved pipe element conveying fluid are formulated using the dynamic stiffness method of the wave approach and coded to be applied to any complex piping system. Using this method, the dynamic characteristics including the natural frequency, the frequency response functions, and the dynamic instability due to the pipe internal flow velocity are analyzed. As one of the design parameters, the vibration energy flow is also analyzed to investigate the disturbance transmission paths for the resonant excitation and the non-resonant excitations

  13. Liquid argon dielectric breakdown studies with the MicroBooNE purification system

    Energy Technology Data Exchange (ETDEWEB)

    Acciarri, R.; Carls, B.; James, C.; Johnson, B.; Jostlein, H.; Lockwitz, S.; Lundberg, B.; Raaf, J. L.; Rameika, R.; Rebel, B.; Zeller, G. P.; Zuckerbrot, M.

    2014-11-01

    The proliferation of liquid argon time projection chamber detectors makes the characterization of the dielectric properties of liquid argon a critical task. To improve understanding of these properties, a systematic study of the breakdown electric field in liquid argon was conducted using a dedicated cryostat connected to the MicroBooNE cryogenic system at Fermilab. An electrode sphere-plate geometry was implemented using spheres with diameters of 1.3 mm, 5.0 mm, and 76 mm. The MicroBooNE cryogenic system allowed measurements to be taken at a variety of electronegative contamination levels ranging from a few parts-per-million to tens of parts-per-trillion. The cathode-anode distance was varied from 0.1 mm to 2.5 cm. The results demonstrate a geometric dependence of the electric field strength at breakdown. This study is the first time that the dependence of the breakdown field on stressed cathode area has been shown for liquid argon.

  14. Method for controlling a coolant liquid surface of cooling system instruments in an atomic power plant

    International Nuclear Information System (INIS)

    Monta, Kazuo.

    1974-01-01

    Object: To prevent coolant inventory within a cooling system loop in an atomic power plant from being varied depending on loads thereby relieving restriction of varied speed of coolant flow rate to lowering of a liquid surface due to short in coolant. Structure: Instruments such as a superheater, an evaporator, and the like, which constitute a cooling system loop in an atomic power plant, have a plurality of free liquid surface of coolant. Portions whose liquid surface is controlled and portions whose liquid surface is varied are adjusted in cross-sectional area so that the sum total of variation in coolant inventory in an instrument such as a superheater provided with an annulus portion in the center thereof and an inner cylindrical portion and a down-comer in the side thereof comes equal to that of variation in coolant inventory in an instrument such as an evaporator similar to the superheater. which is provided with an overflow pipe in its inner cylindrical portion or down-comer, thereby minimizing variation in coolant inventory of the entire coolant due to loads thus minimizing variation in varied speed of the coolant. (Kamimura, M.)

  15. Design and construction of the low-level liquid waste treatment system

    International Nuclear Information System (INIS)

    Baker, M.N.; Mateer, W.E.; Metzler, G.H.; Reeves, S.R.; Rickettson, D.J.

    1989-03-01

    This report describes the design and construction of the Low-Level Liquid Waste Treatment System (LWTS). The LWTS is part of a system that will prepare High-Level Radioactive Waste for solidification in glass. This preparation includes removal of water and salts from the stored waste. The topics addressed are: the design objective to reuse the Process Building to contain LWTS, the special considerations that arise when building a new system inside a decontaminated facility, interface to existing plant systems, phased construction, and construction testing. 8 refs., 24 figs

  16. A Novel Physical Sensing Principle for Liquid Characterization Using Paper-Based Hygro-Mechanical Systems (PB-HMS).

    Science.gov (United States)

    Perez-Cruz, Angel; Stiharu, Ion; Dominguez-Gonzalez, Aurelio

    2017-07-20

    In recent years paper-based microfluidic systems have emerged as versatile tools for developing sensors in different areas. In this work; we report a novel physical sensing principle for the characterization of liquids using a paper-based hygro-mechanical system (PB-HMS). The PB-HMS is formed by the interaction of liquid droplets and paper-based mini-structures such as cantilever beams. The proposed principle takes advantage of the hygroscopic properties of paper to produce hygro-mechanical motion. The dynamic response of the PB-HMS reveals information about the tested liquid that can be applied to characterize certain properties of liquids. A suggested method to characterize liquids by means of the proposed principle is introduced. The experimental results show the feasibility of such a method. It is expected that the proposed principle may be applied to sense properties of liquids in different applications where both disposability and portability are of extreme importance.

  17. Molten metal technologies advance waste processing systems for liquid radioactive waste treatment for PWRs and BWRs

    International Nuclear Information System (INIS)

    Strand, Gary; Vance, Jene N.

    1997-01-01

    Molten Metal Technologies (MMT) has recently acquired a proprietary filtration process for specific use in radioactive liquid waste processing systems. The filtration system has been incorporated in to a PWR liquid radwaste system which is currently being designed for the ComEd Byron Nuclear Station. It has also been adopted as the prefiltration step up from of the two RO systems which were part of the VECTRA acquisition and which are currently installed in the ComEd Dresden and Lacily Nuclear Stations. The filtration process has been successfully pilot-tested at both Byron and Dresden and is currently being tested at LaSalle. The important features of the filtration process are the high removal efficiencies for particulates, including colloidal particles, and the low solid waste volume generation per gallon filtered which translates into very small annual solid waste volumes. This filtration process system has been coupled with the use of selective ion exchange media in the PWR processing system to reduce the solid waste volumes generated compared to the current processing methods and to reduce the curie quantities discharged to the environs. In the BWR processing system, this filtration method allows the coupling of an RO system to provide for recycling greater than 95% of the liquid radwaste back to the plant for reuse while significantly reducing the solid waste volumes and operating costs. This paper discusses the process system configurations for the MMT Advanced Waste Processing Systems for both PWRs and BWRs. In addition, the pilot test data and full-scale performance projections for the filtration system are discussed which demonstrate the important features of the filtration process

  18. On the molecular anisotropy of liquid crystalline and flexible polymer systems

    Science.gov (United States)

    van Horn, Brett L.

    The demand for products of ever increasing quality or for novel applications has required increasing attention to or manipulation of the anisotropy of manufactured parts. Oriented plastics are used everywhere from recording film to automotive body parts to monofilament fishing line. Liquid crystals are also used in a wide array of applications including their dominance in the flat panel display industry, color changing temperature sensors, and woven bullet resistant fabrics. Anisotropy can also be detrimental, for instance sometimes leading to poor fracture resistance or low yield stress along specific directions. Controlling and measuring anisotropy of materials has become increasingly important, but doing so is wrought with challenges. Measuring physical properties of isotropic liquids, such as water or most oils can be done in a straightforward fashion. Their viscosities and densities, for example, have unique values under a given set of conditions. With anisotropic fluids, like liquid crystals, the viscosity, for instance, will not only depend upon temperature, concentration, etc. but also upon the direction of observation, degree of anisotropy, source of anisotropy, and so forth. This added degree of complexity complicates our ability to define the state of the material at which the measurements are made and generally necessitates the use of more sophisticated measurement strategies or techniques. This work presents techniques and tools for investigating anisotropy in liquid crystalline and stretched polymeric systems. Included are the use of conoscopy for the determination of birefringence and orientation of nematic liquid crystals and stretched polymers, the shear response of flow aligning nematic liquid crystal monodomains, and the design of a novel linear rheometer that allows for in situ optical or scattering investigations.

  19. Development of a Liquid Scintillator-Based Active Interrogation System for LEU Fuel Assemblies

    International Nuclear Information System (INIS)

    Lavietes, Anthony D.; Plenteda, Romano; Mascahrenas, Nicholas; Cronholm, L. Marie; Aspinall, Michael; Joyce, Malcolm; Tomanin, Alice; Peerani, Paolo

    2013-06-01

    The IAEA, in collaboration with the Joint Research Center (Ispra, IT) and Hybrid Instruments (Lancaster, UK), has developed a full scale, liquid scintillator-based active interrogation system to determine uranium (U) mass in fresh fuel assemblies. The system implements an array of moderate volume (∼1000 ml) liquid scintillator detectors, a multichannel pulse shape discrimination (PSD) system, and a high-speed data acquisition and signal processing system to assess the U content of fresh fuel assemblies. Extensive MCNPX-PoliMi modelling has been carried out to refine the system design and optimize the detector performance. These measurements, traditionally performed with 3 He-based assay systems (e.g., Uranium Neutron Coincidence Collar [UNCL], Active Well Coincidence Collar [AWCC]), can now be performed with higher precision in a fraction of the acquisition time. The system uses a high-flash point, non-hazardous scintillating fluid (EJ309) enabling their use in commercial nuclear facilities and achieves significantly enhanced performance and capabilities through the combination of extremely short gate times, adjustable energy detection threshold, real-time PSD electronics, and high-speed, FPGA-based data acquisition. Given the possible applications, this technology is also an excellent candidate for the replacement of select 3 He-based systems. Comparisons to existing 3 He-based active interrogation systems are presented where possible to provide a baseline performance reference. This paper will describe the laboratory experiments and associated modelling activities undertaken to develop and initially test the prototype detection system. (authors)

  20. Liquid scintillation systems and apparatus for measuring high-energy radiation emitted by samples in standard laboratory test tubes

    International Nuclear Information System (INIS)

    Benvenutti, R.A.

    1976-01-01

    Liquid scintillation detection system employs improved sample holders in which the cap of a glass vial is provided with a well for receiving a standard laboratory test tube containing a radioactive sample. The well is immersed in a liquid scintillator in the vial, the scintillator containing lead acetate solution to enhance its efficiency. A commercially available beta-counting liquid scintillation apparatus is modified to provide gamma-counting with the improved sample holders

  1. Experimental performance of a liquid desiccant dehumidification system under tropical climates

    International Nuclear Information System (INIS)

    Jain, Sanjeev; Tripathi, Sagun; Das, Rajat Subhra

    2011-01-01

    Research highlights: → Indirect contact between air and desiccant using a porous surface to avoid carryover. → Humidity effectiveness and moisture removal rate reported under varying conditions. → Humidity effectiveness with LiCl as desiccant in the range 0.36-0.45. → Mass transfer characteristic of contactor surface restricted system performance. -- Abstract: The current energy crisis, climate change and increased air conditioning demands have generated a need for developing technologies based on renewable energy sources. Foremost amongst the cooling technologies are the sorption technologies working on low grade heat that can be supplied by solar energy. Liquid desiccant technologies seem to be a promising option as these tend to have higher thermal COPs, lower regeneration temperatures, facilitate simultaneous cooling and ease of storage of concentrated desiccant that can be used during the nonsunshine hours. But few concerns like carryover of liquid desiccant in air require further investigations. The liquid desiccant system under study incorporates a double channelled exchanger for air to liquid desiccant heat and mass transfer. It provides a large surface area for air/desiccant contact and reduces the carryover as direct contact between desiccant and air is minimized unlike spray towers, packed bed and falling film designs. Desiccant is heated in a plate heat exchanger using hot water and then regenerated in a regenerator. The set-up comprises of a dehumidifier, along with a regenerator, a cooling tower, plate heat exchangers and a control unit. Experiments were conducted on the system using calcium chloride and lithium chloride as desiccants by varying parameters like inlet air conditions, hot water temperature and desiccant concentration in order to evaluate the performance of the system under different operating conditions. The performance of the system is presented in terms of moisture removal rates, dehumidifier and regenerator effectiveness.

  2. Liquid-liquid extraction of cadmium(II by TIOACl (tri-iso-octylammonium chloride ionic liquid and its application to a TIOACl impregnated carbon nanotubes system

    Directory of Open Access Journals (Sweden)

    Alguacil, Francisco J.

    2015-09-01

    Full Text Available The extraction of cadmium(II by the ionic liquid (R3NH+Cl- (R: tri-iso-octyl in Exxsol D100 from hydrochloric acid solution has been investigated. The extraction reaction is exothermic. The numerical analysis of metal distribution data suggests the formation of R3NH+CdCl3− and (R3NH+2CdCl42− species in the organic phase. The results obtained for cadmium(II distribution have been implemented in an impregnated multi-walled carbon nanotubes system. The influence of aqueous solution stirring speed (250–2000 min−1, adsorbent dosage (0.05–0.2 g and temperature (20 °C–60 °C on cadmium adsorption have been investigated.Se ha estudiado la extracción de cadmio(II, de disoluciones en medio HCl, por el líquido iónico (R3NH+Cl- (R: tri-iso-octyl disuelto en Exxsol D100. La reacción de extracción tiene un carácter exotérmico. El análisis numérico de la distribución del metal sugiere la formación de las especies R3NH+CdCl3− y (R3NH+2CdCl42− en la fase orgánica. Estos resultados se han implementado en un sistema que utiliza nanotubos de carbono de pared múltiple impregnados con este líquido iónico. Se han investigado diversas variables experimentales: velocidad de agitación de la disolución acuosa (250–2000 min−1, adición del adsorbente (0,05–0,2 g y temperatura (20–60 °C.

  3. The Liquid Droplet Radiator - an Ultralightweight Heat Rejection System for Efficient Energy Conversion in Space

    Science.gov (United States)

    Mattick, A. T.; Hertzberg, A.

    1984-01-01

    A heat rejection system for space is described which uses a recirculating free stream of liquid droplets in place of a solid surface to radiate waste heat. By using sufficiently small droplets ( 100 micron diameter) of low vapor pressure liquids the radiating droplet sheet can be made many times lighter than the lightest solid surface radiators (heat pipes). The liquid droplet radiator (LDR) is less vulnerable to damage by micrometeoroids than solid surface radiators, and may be transported into space far more efficiently. Analyses are presented of LDR applications in thermal and photovoltaic energy conversion which indicate that fluid handling components (droplet generator, droplet collector, heat exchanger, and pump) may comprise most of the radiator system mass. Even the unoptimized models employed yield LDR system masses less than heat pipe radiator system masses, and significant improvement is expected using design approaches that incorporate fluid handling components more efficiently. Technical problems (e.g., spacecraft contamination and electrostatic deflection of droplets) unique to this method of heat rejectioon are discussed and solutions are suggested.

  4. Mechanisms and rules of anion partition into ionic liquids: phenolate ions in ionic liquid/water biphasic systems.

    Science.gov (United States)

    Katsuta, Shoichi; Nakamura, Ko-ichi; Kudo, Yoshihiro; Takeda, Yasuyuki

    2012-01-19

    It is important to understand the mechanisms and general rules of ion partitioning in hydrophobic ionic liquid (IL)/water biphasic systems in order to predict the extractability of an ionic species with various ILs. In this study, we have investigated the partition of picrate ion (target anion, T(-)) from aqueous sodium picrate solutions into several ILs and the accompanying changes in aqueous concentrations of the IL component cation (C(+)) and anion (A(-)) at 298.2 K. The main ILs examined are 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)amide, 1-butyl-3-methylimidazolium hexafluorophosphate, and 1-methyl-3-octylimidazolium bis(trifluoromethanesulfonyl)amide. The aqueous concentrations of C(+) and A(-) decreased and increased, respectively, with the extraction of T(-) into the IL phase. From the standpoint of equilibrium, the partition behavior of T(-) can be explained both by the anion exchange with A(-) in the IL phase and by the ion pair extraction with C(+) in the aqueous phase. The aqueous concentrations of C(+) and A(-) are governed by the solubility product of the IL (K(sp)). The distribution ratio of T(-) is expressed as a function of Δ[T(-)](W), namely, the difference between the initial and equilibrium concentrations of T(-) in the aqueous phase; the distribution ratio of T(-) is nearly constant when Δ[T(-)](W) < K(sp)(1/2), but decreases with increasing Δ[T(-)](W) in the larger Δ[T(-)](W) region. The equilibrium constants of the ion pair extraction and the ion exchange extraction have been determined for picrate and other phenolate ions whose partition data were previously reported. The dependences of the extraction constants and extractability on the kinds of IL component ions can be quantitatively explained on the basis of the variations of K(sp).

  5. Evaluation of Microemulsion and Lamellar Liquid Crystalline Systems for Transdermal Zidovudine Delivery.

    Science.gov (United States)

    Carvalho, André Luis Menezes; Silva, José Alexsandro da; Lira, Ana Amélia Moreira; Conceição, Tamara Matos Freire; Nunes, Rogéria de Souza; de Albuquerque Junior, Ricardo Luiz Cavalcanti; Sarmento, Victor Hugo Vitorino; Leal, Leila Bastos; de Santana, Davi Pereira

    2016-07-01

    This study proposed to investigate and to compare colloidal carrier systems containing Zidovudine (3'-azido-3'-deoxythymidine) (AZT) for transdermal administration and optimization of antiretroviral therapy. Microemulsion (ME) and lamellar phase (LP) liquid crystal were obtained and selected from pseudoternary diagrams previously developed. Small-angle X-ray scattering and rheology analysis confirmed the presence of typical ME and liquid crystalline structures with lamellar arrangement, respectively. Both colloidal carrier systems, ME, and LP remained stable, homogeneous, and isotropic after AZT addition. In vitro permeation study (using pig ear skin) showed that the amount of permeated drug was higher for ME compared to the control and LP, obtaining a permeation enhancing effect on the order of approximately 2-fold (p drug permeation without causing apparent skin irritation. On the order hand, LP functioned as a drug reservoir reducing AZT partitioning into the skin. Copyright © 2016 American Pharmacists Association®. Published by Elsevier Inc. All rights reserved.

  6. Advances in the physics modelling of CANDU liquid injection shutdown systems

    International Nuclear Information System (INIS)

    Smith, H.J.; Robinson, R.; Guertin, C.

    1993-01-01

    The physics modelling of liquid poison injection shutdown systems in CANDU reactors accounts for the major phenomena taking place by combining the effects of both moderator hydraulics and neutronics. This paper describes the advances in the physics modelling of liquid poison injection shutdown systems (LISS), discusses some of the effects of the more realistic modelling, and briefly describes the automation methodology. Modifications to the LISS methodology have improved the realism of the physics modelling, showing that the previous methodology significantly overestimated energy deposition during the simulation of a loss of coolant transient in Bruce A, by overestimating the reactivity transient. Furthermore, the automation of the modelling process has reduced the time needed to carry put LISS evaluations to the same level as required for shutoff-rod evaluations, while at the same time minimizing the amount of input, and providing a method for tracing all files used, thus adding a level of quality assurance to the calculation. 5 refs., 11 figs

  7. Strongly correlated Fermi-systems: Non-Fermi liquid behavior, quasiparticle effective mass and their interplay

    Energy Technology Data Exchange (ETDEWEB)

    Shaginyan, V.R. [Petersburg Nuclear Physics Institute, RAS, Gatchina 188300 (Russian Federation); Racah Institute of Physics, Hebrew University, Jerusalem 91904 (Israel)], E-mail: vrshag@thd.pnpi.spb.ru; Amusia, M.Ya. [Racah Institute of Physics, Hebrew University, Jerusalem 91904 (Israel); Popov, K.G. [Komi Science Center, Ural Division, RAS, Syktyvkar 167982 (Russian Federation)

    2009-06-15

    Basing on the density functional theory of fermion condensation, we analyze the non-Fermi liquid behavior of strongly correlated Fermi-systems such as heavy-fermion metals. When deriving equations for the effective mass of quasiparticles, we consider solids with a lattice and homogeneous systems. We show that the low-temperature thermodynamic and transport properties are formed by quasiparticles, while the dependence of the effective mass on temperature, number density, magnetic fields, etc., gives rise to the non-Fermi liquid behavior. Our theoretical study of the heat capacity, magnetization, energy scales, the longitudinal magnetoresistance and magnetic entropy are in good agreement with the remarkable recent facts collected on the heavy-fermion metal YbRh{sub 2}Si{sub 2}.

  8. Strongly correlated Fermi-systems: Non-Fermi liquid behavior, quasiparticle effective mass and their interplay

    International Nuclear Information System (INIS)

    Shaginyan, V.R.; Amusia, M.Ya.; Popov, K.G.

    2009-01-01

    Basing on the density functional theory of fermion condensation, we analyze the non-Fermi liquid behavior of strongly correlated Fermi-systems such as heavy-fermion metals. When deriving equations for the effective mass of quasiparticles, we consider solids with a lattice and homogeneous systems. We show that the low-temperature thermodynamic and transport properties are formed by quasiparticles, while the dependence of the effective mass on temperature, number density, magnetic fields, etc., gives rise to the non-Fermi liquid behavior. Our theoretical study of the heat capacity, magnetization, energy scales, the longitudinal magnetoresistance and magnetic entropy are in good agreement with the remarkable recent facts collected on the heavy-fermion metal YbRh 2 Si 2 .

  9. A rope-net support system for the liquid scintillator detector for the SNO+ experiment

    Energy Technology Data Exchange (ETDEWEB)

    Bialek, A., E-mail: abialek@snolab.ca [University of Alberta, Edmonton (Canada); Chen, M. [Queen' s University, Kingston (Canada); Cleveland, B. [SNOLAB, Lively (Canada); Gorel, P.; Hallin, A. [University of Alberta, Edmonton (Canada); Harvey, P.J.; Heise, J. [Queen' s University, Kingston (Canada); Kraus, C. [Laurentian University, Sudbury (Canada); Krauss, C.B. [University of Alberta, Edmonton (Canada); Lawson, I. [SNOLAB, Lively (Canada); Ng, C.J.; Pinkney, B. [University of Alberta, Edmonton (Canada); Rogowsky, D.M. [Rogowsky Engineering Ltd, AECOM Canada Ltd (Canada); Sibley, L.; Soluk, R.; Soukup, J. [University of Alberta, Edmonton (Canada); Vázquez-Jáuregui, E. [SNOLAB, Lively (Canada); Laurentian University, Sudbury (Canada)

    2016-08-11

    The detector for the SNO+ experiment consists of 780 000 kg of liquid scintillator contained in an acrylic vessel that is surrounded by water. A mechanical system has been installed to counteract the 1.25 MN of buoyant force on the acrylic and prevent the vessel from moving. The system is a rope net, designed using a Finite Element Analysis to calculate the amount of stress on the acrylic induced by the ropes, hydrostatic pressures and gravity. A dedicated test was performed to measure strains in the acrylic arising from the complex geometry of the knots in the rope system. The ratio between measured and FEA calculated strains was 1.3.

  10. The electrodeposition and rare earths reduction in the molten salt actinides recovery systems using liquid metal

    International Nuclear Information System (INIS)

    Shim, J-B.; Lee, J-H.; Kwon, S-W.; Ahn, B-G.; Woo, M-S.; Lee, B-J.; Kim, E-H.; Park, H-S.; Yoo, J-H.

    2005-01-01

    A pyrochemical partitioning system uses liquid metals such as cadmium and bismuth in order to recover the actinide metals from a molten salt mixture containing rare earth fission product metals. The liquid metals play roles as a cathode in the electrowinning or an extracting phase in the reductive extraction operation. The product resulting from the above operations is metal-cadmium or-bismuth alloy, which should contain the rare earth element amounts as low as possible for a transmutation purpose. In this study, the electrodeposition behaviours of uranium and lanthanide elements such as La, Ce and Nd were investigated for solid molybdenum and liquid cadmium electrodes in a molten LiCl-KCl eutectic salt. Electrochemical methods used are a cyclic voltammetry (CV) and a chronopotentiometry for monitoring the salt phase and recovering the metals, respectively. The CV graphs for monitoring the oxidizing agent CdCl 2 in the salt phase were obtained. These show a time dependently disappearance of the oxidizing agent corresponding to the formation of UCl 3 by inserting the uranium metal into the salt. Also, a sequential oxidation technique which is added at a controlled amount of the oxidizing agents into the salt phase was applied. It was found that this method is feasible for the selective reduction of the rare earths content in liquid metal alloys. (author)

  11. Simulation of complete neutron scattering experiments: from model systems to liquid germanium

    International Nuclear Information System (INIS)

    Hugouvieux, V.

    2004-11-01

    In this thesis, both theoretical and experimental studies of liquids are done. Neutron scattering enables structural and dynamical properties of liquids to be investigated. On the theoretical side, molecular dynamics simulations are of great interest since they give positions and velocities of the atoms and the forces acting on each of them. They also enable spatial and temporal correlations to be computed and these quantities are also available from neutron scattering experiments. Consequently, the comparison can be made between results from molecular dynamics simulations and from neutron scattering experiments, in order to improve our understanding of the structure and dynamics of liquids. However, since extracting reliable data from a neutron scattering experiment is difficult, we propose to simulate the experiment as a whole, including both instrument and sample, in order to gain understanding and to evaluate the impact of the different parasitic contributions (absorption, multiple scattering associated with elastic and inelastic scattering, instrument resolution). This approach, in which the sample is described by its structure and dynamics as computed from molecular dynamics simulations, is presented and tested on isotropic model systems. Then liquid germanium is investigated by inelastic neutron scattering and both classical and ab initio molecular dynamics simulations. This enables us to simulate the experiment we performed and to evaluate the influence of the contributions from the instrument and from the sample on the detected signal. (author)

  12. Testing of a Spray-bar Thermodynamic Vent System in Liquid Nitrogen

    Science.gov (United States)

    Flachbart, R. H.; Hastings, L. J.; Hedayat, A.; Nelson, S. L.; Tucker, S. P.

    2005-01-01

    To support development of a microgravity pressure control capability for liquid oxygen, thermodynamic vent system (TVS) testing was conducted at Marshall Space Flight Center (MSFC) using liquid nitrogen (LN2) as a LOX simulant. The spray bar TVS hardware used was originally designed by the Boeing Company for testing in liquid hydrogen (LH2). With this concept, a small portion of the tank fluid is passed through a Joule-Thomson (J-T) device, and then through a longitudinal spray bar mixed-heat exchanger in order to cool the bulk fluid. To accommodate the larger mass flow rates associated with LN2, the TVS hardware was modified by replacing the recirculation pump with an LN2 compatible pump and replacing the J-T valve. The primary advantage of the spray-bar configuration is that tank pressure control can be achieved independent of liquid and vapor location, enhancing the applicability of ground test data to microgravity conditions. Performance testing revealed that the spray-bar TVS was effective in controlling tank pressure within a 6.89 kPa band for fill levels of 90%, 50%, and 25%. Tests were also conducted with gaseous helium (GHe) in the ullage. The TVS operated nominally with GHe in the ullage, with performance similar to the tests with gaseous nitrogen (GN2). Testing demonstrated that the spray-bar TVS design was flexible enough for use in two different propellants with minimal hardware modifications.

  13. Thermocapillary and shear driven flows in gas/liquid system in annular duct

    International Nuclear Information System (INIS)

    Gaponenko, Yu; Shevtsova, V; Nepomnyashchy, A

    2011-01-01

    We report the results of numerical study of two-phase flows in annulus for different aspect ratios obtained in the frame of the JEREMI experiment preparation. The geometry of the physical problem is a cylindrical and non-deformable liquid bridge concentrically surrounded by an annular gas channel under conditions of zero gravity. Thermocapillary (Marangoni) convection in liquid bridge of Pr = 68 is analyzed in the case when the interface is subjected to an axial gas stream. The gas flow is counter-directed with respect to the Marangoni flow. The inlet gas velocity U 0 g , temperature difference ΔT between end rods of the liquid bridge and aspect ratio are the control parameters of the system. In the case when the gas stream comes from the cold side, it cools down the interface to a temperature lower than that of the liquid beneath, and in a certain region of the parameter space that cooling causes instability due to a temperature difference in the direction, perpendicular to the interface. The present study is focused on the influence of the aspect ratio on the existence and characteristic features of the oscillatory regime.

  14. The analog processing system for the Liquid Argon Calorimeter for SLD at SLAC

    International Nuclear Information System (INIS)

    Haller, G.M.; Nelson, D.; Freytag, D.R.

    1986-09-01

    The analog processing system for the Liquid Argon Calorimeter for the SLD project at SLAC is described. Amplification, storage of the analog information, and multiplexing is realized on specially developed hybrids, which will be mounted directly on the detector. This leads to a substantial reduction of the cable plant. Test results for the amplifier and for the sampling and multiplexing hybrid (CDU hybrid) are presented. The latter hybird contains a custom monolithic device, the Calorimeter Data Unit

  15. Plasma-liquid system with reverse vortex flow of 'tornado' type (TORNADO-LE)

    International Nuclear Information System (INIS)

    Nedybalyuk, O.A.; Chernyak, V.Ya.; Olszewski, S.V.

    2010-01-01

    The results of experimental investigations of the plasma in plasma-liquid system with reverse vortex flow of 'tornado' type are presented. Volt-ampere characteristic of discharge in the current range from 200 to 400 mA were measured. Emission spectra of plasma in range from 200 to 1100 nm were measured. Excitation temperatures (electronic T e * , vibrational T v * and rotational T r * ) were obtained. Emission spectra of hydroxyl OH were calculated.

  16. A Simple Opto-Fluidic Switch Detecting Liquid Filling in Polymer-Based Microfluidic Systems

    DEFF Research Database (Denmark)

    Bundgaard, Frederik; Geschke, Oliver; Zengerle, R

    2007-01-01

    A novel detection scheme for detection of liquid levels and bubbles in microfluidic systems, using the principle of total internal reflection (TIR) is presented. A laser beam impinges on the side walls of a channel which are inclined at 45deg. In an unfilled channel of such a "V-groove", TIR defl...... of the microfluidic channels. The machining of the V-groves can seamlessly be integrated into common polymer microfabrication schemes such as injection molding....

  17. Liquid poison injection system (LPIS) for KAIGA 1, 2 and RAPP 3, 4, 220 MWe PHWRs

    International Nuclear Information System (INIS)

    Soni, K.L.; Aparna; Mohan, L.R.; Nema, M.K.; Mahajan, S.C.

    1997-01-01

    LPIS is the modified version of existing Bulk Addition Mode (BAM) of the Automatic Liquid Poison Addition System (ALPAS). This BAM mode of ALPAS serves as slow acting supplementary shutdown system to PSS or SS as the case may be and hence it becomes a part of reactor safety system. The system (LPIS) has been envisaged to perform similar functions of ALPAS mode BAM. Now this is a self standing system. This feature of the system eliminates need of Gravity Addition of Boron System (GRAB). As the concept evolved is to be introduced for first time for the power reactors (from KAIGA-1, 2 and RAPP-3, 4 onwards), it has become necessary to check and verify its working by carrying out the necessary experimental and developmental work

  18. Zoom system without moving element by using two liquid crystal lenses with spherical electrode

    Science.gov (United States)

    Yang, Ren-Kai; Lin, Chia-Ping; Su, Guo-Dung J.

    2017-08-01

    A traditional zoom system is composed of several elements moving relatively toward other components to achieve zooming. Unlike tradition system, an electrically control zoom system with liquid crystal (LC) lenses is demonstrated in this paper. To achieve zooming, we apply two LC lenses whose optical power is controlled by voltage to replace two moving lenses in traditional zoom system. The mechanism of zoom system is to use two LC lenses to form a simple zoom system. We found that with such spherical electrodes, we could operate LC lens at voltage range from 31V to 53 V for 3X tunability in optical power. For each LC lens, we use concave spherical electrode which provide lower operating voltage and great tunability in optical power, respectively. For such operating voltage and compact size, this zoom system with zoom ratio approximate 3:1 could be applied to mobile phone, camera and other applications.

  19. Design study of the cooling scheme for SMES system in ASPCS by using liquid hydrogen

    Energy Technology Data Exchange (ETDEWEB)

    Makida, Yasuhiro, E-mail: yasuhiro.makida@kek.jp [High Energy Accelerator Research Organization, Oho 1-1, Tsukuba 305-0801 (Japan); Shintomi, Takakazu [Nihon University, Chiyoda-ku, Tokyo 102-8251 (Japan); Asami, Takuya; Suzuki, Goro; Takao, Tomoaki [Sophia University, Chiyoda-ku, Tokyo 102-8554 (Japan); Hamajima, Takataro [Hachinohe Institutue of Technology, Hachinohe, Aomori 031-8501 (Japan); Tsuda, Makoto; Miyagi, Daisuke [Tohoku University, Aoba-ku, Sendai 980-8579 (Japan); Munakata, Kouhei; Kajiwara, Masataka [Iwatani Corp., Minato-ku, Tokyo 104-8058 (Japan)

    2013-11-15

    Highlights: •Advanced Superconducting Power Conditioning System is composed of SMES, FC–EL, H{sub 2} storage. •The ASPCS is proposed to be built beside a LH{sub 2} storage of a vehicle station to effectively use the cooling capability of liquid hydrogen. •The SMES coil, which is made from an MgB{sub 2} conductor, is indirectly cooled by LH{sub 2} through its own conduction. -- Abstract: From the point of view of environment and energy problems, the renewable energies have been attracting attention. However, fluctuating power generation by the renewable energies affects the stability of the power network. Thus, we propose a new electric power storage and stabilization system, Advanced Superconducting Power Conditioning System (ASPCS), in which a Superconducting Magnetic Energy Storage (SMES) and a hydrogen-energy-storage converge on a liquid hydrogen station for fuel cell vehicles. The ASPCS proposes that the SMES coils wound with MgB{sub 2} conductor are indirectly cooled by thermo-siphon circulation of liquid hydrogen to use its cooling capability. The conceptual design of cooling scheme of the ASPCS is presented.

  20. Oak Ridge National Lebroatory Liquid&Gaseous Waste Treatment System Strategic Plan

    Energy Technology Data Exchange (ETDEWEB)

    Van Hoesen, S.D.

    2003-09-09

    Excellence in Laboratory operations is one of the three key goals of the Oak Ridge National Laboratory (ORNL) Agenda. That goal will be met through comprehensive upgrades of facilities and operational approaches over the next few years. Many of ORNL's physical facilities, including the liquid and gaseous waste collection and treatment systems, are quite old, and are reaching the end of their safe operating life. The condition of research facilities and supporting infrastructure, including the waste handling facilities, is a key environmental, safety and health (ES&H) concern. The existing infrastructure will add considerably to the overhead costs of research due to increased maintenance and operating costs as these facilities continue to age. The Liquid Gaseous Waste Treatment System (LGWTS) Reengineering Project is a UT-Battelle, LLC (UT-B) Operations Improvement Program (OIP) project that was undertaken to develop a plan for upgrading the ORNL liquid and gaseous waste systems to support ORNL's research mission.

  1. Design study of the cooling scheme for SMES system in ASPCS by using liquid hydrogen

    International Nuclear Information System (INIS)

    Makida, Yasuhiro; Shintomi, Takakazu; Asami, Takuya; Suzuki, Goro; Takao, Tomoaki; Hamajima, Takataro; Tsuda, Makoto; Miyagi, Daisuke; Munakata, Kouhei; Kajiwara, Masataka

    2013-01-01

    Highlights: •Advanced Superconducting Power Conditioning System is composed of SMES, FC–EL, H 2 storage. •The ASPCS is proposed to be built beside a LH 2 storage of a vehicle station to effectively use the cooling capability of liquid hydrogen. •The SMES coil, which is made from an MgB 2 conductor, is indirectly cooled by LH 2 through its own conduction. -- Abstract: From the point of view of environment and energy problems, the renewable energies have been attracting attention. However, fluctuating power generation by the renewable energies affects the stability of the power network. Thus, we propose a new electric power storage and stabilization system, Advanced Superconducting Power Conditioning System (ASPCS), in which a Superconducting Magnetic Energy Storage (SMES) and a hydrogen-energy-storage converge on a liquid hydrogen station for fuel cell vehicles. The ASPCS proposes that the SMES coils wound with MgB 2 conductor are indirectly cooled by thermo-siphon circulation of liquid hydrogen to use its cooling capability. The conceptual design of cooling scheme of the ASPCS is presented

  2. Gamma irradiation of hydrocarbon-liquid nitrogen systems and the synthesis of ammonia

    International Nuclear Information System (INIS)

    Fleming, H.L.

    1982-01-01

    The 60 Co-gamma radiolysis of hydrocarbons (HC)-liquid N 2 mixtures at 77 0 K and 1.8 atm of pressure was investigated. Batch irradiation studies of methane, ethane, and ethylene and semibatch studies of methane were made in the presence and absence of transition metal oxide catalysts. In noncatalyzed systems, the effects of varying the radiation dose, total dose, solute feed rate and concentration and liquid N 2 volume were investigated. NH 3 was found to be the major N-containing product in the alkane solute system. N 2 and HC radical addition was found to be the predominate initial reaction for nitrogeneous product formation. Results of scavenger studies indicate that excited N 2 played a lesser role in precursor formation. All product yields were found to be dependent upon the H-containing species availability in the liquid N 2 solution. Production rates were limited by HC solubility. The use of the transition metal oxide supported catalyst greatly increased product formation in all systems. Product yields were found to be dependent upon the available catalyst surface area, metal loading, and reduction techniques for each metal examined. As evidenced by the radiation lag time studies, the stability of the N 2 precursors on the catalyst surface was believed to be a significant factor in reaction enhancement. Energy transfer from the catalyst to the absorbates was examined and could not be ruled out

  3. Condition assessment of the Los Alamos National Laboratory radioactive liquid waste collection system

    International Nuclear Information System (INIS)

    Edgemon, G.L.; Moss, W.D.; Worland, V.P.

    2004-01-01

    The radioactive liquid waste collection system (RLWCS) at Los Alamos National Laboratory (LANE) is a site-wide double-encased piping system installed in 1982 that allows radioactive liquid waste (RLW) producing facilities to gravity drain their waste to the radioactive liquid waste treatment facility (RLWTF) through a system of underground high-density polyethylene (HDPE) pipes and vaults. The RLWCS stretches approximately four miles and typically receives approximately 10,000 gallons of RLW per day for treatment at the RLWTF. Uncertainty of the current condition of the RLWCS was recently identified as a potential risk to the future continued availability of the RLW treatment function. A condition assessment was performed in April 2004 to evaluate the risks and estimate the remaining useful life of the existing RLWCS. Several representative and 'worst-case' RLWCS primary piping sections and their associated inspection vaults were selected for direct visual assessment, remote borescopic examination, and in-situ durometer testing. This field investigation combined with an RLWCS materials compatibility review showed that the primary piping of the RLWCS is in relatively good condition, with only a few noteworthy areas of degradation.

  4. Characterization of proacrosin/acrosin system after liquid storage and cryopreservation of turkey semen (Meleagris gallopavo).

    Science.gov (United States)

    Słowińska, M; Liszewska, E; Dietrich, G J; Ciereszko, A

    2012-09-15

    This study was designed to identify the effect of liquid storage at 4 °C for 48 h and cryopreservation on the proacrosin/acrosin system of turkey spermatozoa. Anti-acrosin I antibodies were produced and used to demonstrate Western blot analysis profile of the proacrosin/acrosin system of sperm and seminal plasma and possible changes in the proacrosin/acrosin system of turkey sperm stored for 2.5, 24, and 48 h or cryopreserved. At the same time acrosin-like activity was examined by the measurement of amidase activity of sperm extracts, sperm suspension, and seminal plasma of turkey semen. A computer-assisted sperm analysis system was used to monitor the sperm motility characteristics of turkey sperm stored for 48 h or cryopreserved. Different profiles of the sperm proacrosin/acrosin system were observed regarding the presence or absence of inhibitors (p-nitrophenyl-p'-guanidine benzoate [NPGB] and Kazal family inhibitor) during the extraction process. When NPGB was present three main bands were observed with the molecular weight ranging from 66 to 35 kDa. Bands corresponding to acrosin I and II were not observed. In sperm extract without NPGB, three or four bands were observed with the molecular weight ranging from 41 to 30 kDa. The bands corresponding to acrosin I and II were observed. During liquid storage a decrease in sperm motility and an increase in sperm-extracted amidase activity were observed. After 24 and 48 h of storage, extracted amidase activity was higher than at 2.5 h by 24% and 31%, respectively. However, no changes in the Western blot analysis profiles of sperm extract and seminal plasma were visible during liquid storage. After cryopreservation a decrease in sperm motility and all sperm motility parameters were observed. In contrast to liquid storage, cryopreservation did not increase extracted amidase activity. However, changes in Western blot analysis profiles were visible in sperm extract and seminal plasma after cryopreservation. After

  5. Transition metal oxide nanopowder and ionic liquid: an efficient system for the synthesis of diorganyl selenides, selenocysteine and derivatives

    Energy Technology Data Exchange (ETDEWEB)

    Narayanaperumal, Senthil; Gul, Kashif; Kawasoko, Cristiane Y.; Singh, Devender; Dornelles, Luciano; Rodrigues, Oscar E.D. [Universidade Federal de Santa Maria (UFSC), RS (Brazil). Dept. de Quimica. LabSelen-NanoBio; Braga, Antonio L. [Universidade Federal de Santa Catarina (UFSC), Florianopolis, SC (Brazil). Dept. de Quimica. LabSelen

    2010-07-01

    We have developed an efficient method for the synthesis of diorganyl selenides and {beta}-seleno amines using Zn, catalytic amounts of ZnO nanopowder, as a catalyst and ionic liquid as a recyclable solvent. This ZnO/ionic liquid system shows high efficiency in catalyzing these transformations with the formation of the desired products in high yields. (author)

  6. Engineered safety in development of liquid poison injection system (shut down system-2) for 500 MWe PHWR

    International Nuclear Information System (INIS)

    Sapra, M.K.; Kundu, S.N.; Mohan, L.R.

    2002-01-01

    Full text: The provision of shut down systems (SDS) is a mandatory requirement for safety of any nuclear reactor. The SDS shall be capable of making and holding the core adequately subcritical in the event of any anticipated operational occurrence and postulated accident conditions. The shut down function will perform as intended when its design and components are thoroughly evaluated for their reliability and effectiveness. A full scale mock up for one injection unit was designed and developed at Hall No.7, BARC. Experimental studies were carried out to qualify the design and evolve process parameters such as gas tank pressure, poison discharge rate and poison injection time. In liquid poison injection system i.e. shutdown system -2, there is no physical barrier, between the two liquids i.e. the poison and the moderator. A liquid in liquid interface, called poison moderator interface (PMI) separates these fluids. Extensive lab scale studies have been carried out on PMI movement study i.e. the interface movement due to molecular diffusion and due to process disturbances under simulated reactor condition. On the basis of lab scale results, a full-scale PMI setup has been designed and developed to generate plant data. From reactor safety consideration, the floating ball in poison tank is designed in such a way that it prevents the over pressurisation of calandria. For this purpose a non-intrusive ultrasonic ball detection system (U-BDS) has been developed. This paper covers the PMI system for 500 MWe PHWR with relevant safety aspects and describes in detail, the experimental results of PMI study. The engineered safety in design, methodology and qualification of U-BDS and its role intended in performance of SDS-2 have been also discussed in the paper

  7. Complex Formation in a Liquid-Liquid Extraction System Containing Cobalt(II), 4-(2-Pyridylazo)resorcinol, and Nitron

    OpenAIRE

    Racheva, Petya Vassileva; Gavazov, Kiril Blazhev; Lekova, Vanya Dimitrova; Dimitrov, Atanas Nikolov

    2013-01-01

    Complex formation and liquid-liquid extraction were studied in a system containing cobalt(II), 4-(2-pyridylazo)resorcinol (PAR), 1,4-diphenyl-3-(phenylamino)-1H-1,2,4-triazole (Nitron, Nt), water, and chloroform. The effect of some experimental parameters (pH, shaking time, concentration of PAR, and concentration of Nt) was systematically investigated, and the optimum conditions for cobalt extraction as an ion-association complex, (NtH+)[Co3+(PAR)2], were found. The following key equilibrium ...

  8. LIQUID-LIQUID EQUILIBRIA OF THE TERNARY SYSTEMS PROPIONIC ACID - WATER - SOLVENT (n-AMYL ALCOHOL AND n-AMYL ACETATE

    Directory of Open Access Journals (Sweden)

    Dilek ÖZMEN

    2005-02-01

    Full Text Available The experimental liquid-liquid equilibrium (LLE data have been obtained at 25 oC for ternary systems propionic acid-water-n-amyl alcohol and propionic acid-water-n-amyl acetate. The reliability of the experimental tie line data are checked using the methods of Othmer-Tobias and Hand. The distribution coefficients and separation factors were obtained from experimental results and are also reported. The predicted tie line data obtained by UNIFAC method are compared with experimental data. It is concluded that n-amyl alcohol and n-amyl acetate are suitable separating agents for dilute aqueous propionic acid solutions.

  9. Experimental investigation of passive thermodynamic vent system (TVS) with liquid nitrogen

    Science.gov (United States)

    Bae, Junhyuk; Yoo, Junghyun; Jin, Lingxue; Jeong, Sangkwon

    2018-01-01

    Thermodynamic vent system (TVS) is an attractive technology to maintain an allowable pressure level of a cryogenic propellant storage in a spacecraft under micro-gravity condition. There are two types of TVS; active or passive. In this paper, the passive TVS which does not utilize a cryogenic liquid circulation pump is experimentally investigated with liquid nitrogen and numerically analyzed by thermodynamic and heat transfer model. A cylindrical copper tank, which is 198 mm in inner diameter and 216 mm in height, is utilized to suppress a thermal-stratification effect of inside cryogenic fluid. A coil heat exchanger, which is 3 m in length and 6.35 mm in outer diameter, and a fixed size orifice of which diameter is 0.4 mm are fabricated to remove heat from the stored fluid to the vented flow. Each vent process is initiated at 140 kPa and ended at 120 kPa with liquid nitrogen fill levels which are 30%, 50% and 70%, respectively. In the numerical model, the fluid in the tank is assumed to be homogeneous saturated liquid-vapor. Mass and energy balance equations with heat transfer conditions suggested in this research are considered to calculate the transient pressure variation in the tank and the amount of heat transfer across the heat exchanger. We achieve the average heat rejection rate of more than 9 W by TVS and conclude that the passive TVS operates satisfactorily. In addition, the prediction model is verified by experimental results. Although the model has limitation in providing accurate results, it can surely predict the tendency of pressure and temperature changes in the tank. Furthermore, the model can suggest how we can improve the heat exchanger design to enhance an overall efficiency of passive TVS. Moreover, the performance of passive TVS is compared with other cryogenic vent systems (direct vent system and active TVS) by suggested performance indicator.

  10. Liquid carbon dioxide/pulverized limestone globulsion delivery system for deep ocean storage

    Energy Technology Data Exchange (ETDEWEB)

    Swett, P.; Golomb, D.; Barry, E.; Ryan, D.; Lawton, C. [Massachusetts Univ., Lowell, MA (United States)

    2005-07-01

    Ocean storage of carbon dioxide (CO{sub 2}) raises serious environmental, technical and economic problems because a massive point injection of pure liquid CO{sub 2} at depth would create a plume of carbonic acid with a pH lower than 7. Acidified seawater is considered to be harmful to aquatic organisms. Laboratory studies have shown that injecting a globulsion consisting of CO{sub 2}, water (H{sub 2}O) and calcium carbonate (CaCO{sub 3}) instead of pure liquid CO{sub 2} results in an alkaline reaction rather than an acidic reaction. Because calcium carbonate and bicarbonate are natural ingredients of seawater, there is no expected harm due to the additive limestone. This paper presented a practical delivery system for the underwater creation of globulsion. When liquid or supercritical CO{sub 2} is mixed with a slurry of finely pulverized limestone (CaCO{sub 3}) in pure or seawater, a macro-emulsion is formed consisting of CO{sub 2} droplets coated with CaCO{sub 3} particles dispersed in water. In this study, liquid CO{sub 2} was piped to approximately 500 m depth, which is below the flash point of liquid CO{sub 2} into vapor. A slurry of pulverized limestone in seawater was also separately piped to this depth. A static mixer was mounted at the end of the pipes. Liquid CO{sub 2}, along with a slurry of pulverized limestone and ambient seawater were pumped into the mixer by a turbine. The globulsion exited from the other end of the mixer and sank like a dense plume to greater depths while entraining ambient seawater. The CaCO{sub 3}-coated globules precipitated from the neutrally buoyant plume toward the ocean bottom following equilibration. As such, the ocean was not be acidified with this method of CO{sub 2} discharging. It was concluded that even inland seas, such as the Mediterranean and Black Seas, could be considered for sequestration of a CO{sub 2}/H{sub 2}O/CaCO{sub 3} globulsion. Although adding pulverized limestone to liquid CO{sub 2} and the mixing

  11. Characterization of liquid scintillation detector (BC-501A) and digital pulse shape discrimination (DPSD) system

    Energy Technology Data Exchange (ETDEWEB)

    Lombigit, L., E-mail: lojius@nm.gov.my; Yussup, N., E-mail: nolida@nm.gov.my; Ibrahim, Maslina Mohd; Rahman, Nur Aira Abd; Rawi, M. Z. M. [Instrumentation Group, Malaysian Nuclear Agency, Bangi, 43000 Kajang, Selangor (Malaysia)

    2015-04-29

    A digital n/γ pulse shape discrimination (PSD) system is currently under development at Instrumentation and Automation Centre, Malaysian Nuclear Agency. This system aims at simultaneous detection of fast neutron and gamma ray in mixed radiations environment. This work reports the system characterization performed on the liquid scintillation detector (BC-501A) and digital pulse shape discrimination (DPSD) system. The characterization involves measurement of electron light output from the BC-501A detector and energy channels calibration of the pulse height spectra acquired with DPSD system using set of photon reference sources. The main goal of this experiment is to calibrate the ADC channel of our DPSD system, characterized the BC-501 detector and find the position of Compton edge which later could be used as threshold for the n/γ PSD experiment. The detector resolution however is worse as compared to other published data but it is expected as our detector has a smaller active volume.

  12. Fail-safe system for activity cooled supersonic and hypersonic aircraft. [using liquid hydrogen fuel

    Science.gov (United States)

    Jones, R. A.; Braswell, D. O.; Richie, C. B.

    1975-01-01

    A fail-safe-system concept was studied as an alternative to a redundant active cooling system for supersonic and hypersonic aircraft which use the heat sink of liquid-hydrogen fuel for cooling the aircraft structure. This concept consists of an abort maneuver by the aircraft and a passive thermal protection system (TPS) for the aircraft skin. The abort manuever provides a low-heat-load descent from normal cruise speed to a lower speed at which cooling is unnecessary, and the passive TPS allows the aircraft skin to absorb the abort heat load without exceeding critical skin temperature. On the basis of results obtained, it appears that this fail-safe-system concept warrants further consideration, inasmuch as a fail-safe system could possibly replace a redundant active cooling system with no increase in weight and would offer other potential advantages.

  13. Aging assessment of the boiling-water reactor (BWR) standby liquid control system

    International Nuclear Information System (INIS)

    Orton, R.D.; Johnson, A.B.; Buckley, G.D.; Larson, L.L.

    1992-10-01

    Pacific Northwest Laboratory conducted a Phase I aging assessment of the standby liquid control (SLC) system used in boiling-water reactors. The study was based on detailed reviews of SLC system component and operating experience information obtained from the Nuclear Plant Reliability Database System, the Nuclear Document System, Licensee Event Reports, and other databases. Sources dealing with sodium pentaborate, borates, boric acid, and the effects of environment and corrosion in the SLC system were reviewed to characterize chemical properties and corrosion characteristics of borated solutions. The leading aging degradation concern to date appears to be setpoint drift in relief valves, which has been discovered during routine surveillance and is thought to be caused by mechanical wear. Degradation was also observed in pump seals and internal valves. In general, however, the results of the Phase I study suggest that age-related degradation of SLC systems has not been serious

  14. Characterization of liquid scintillation detector (BC-501A) and digital pulse shape discrimination (DPSD) system

    International Nuclear Information System (INIS)

    Lombigit, L.; Yussup, N.; Ibrahim, Maslina Mohd; Rahman, Nur Aira Abd; Rawi, M. Z. M.

    2015-01-01

    A digital n/γ pulse shape discrimination (PSD) system is currently under development at Instrumentation and Automation Centre, Malaysian Nuclear Agency. This system aims at simultaneous detection of fast neutron and gamma ray in mixed radiations environment. This work reports the system characterization performed on the liquid scintillation detector (BC-501A) and digital pulse shape discrimination (DPSD) system. The characterization involves measurement of electron light output from the BC-501A detector and energy channels calibration of the pulse height spectra acquired with DPSD system using set of photon reference sources. The main goal of this experiment is to calibrate the ADC channel of our DPSD system, characterized the BC-501 detector and find the position of Compton edge which later could be used as threshold for the n/γ PSD experiment. The detector resolution however is worse as compared to other published data but it is expected as our detector has a smaller active volume

  15. Deterpenation of eucalyptus essential oil by liquid + liquid extraction: Phase equilibrium and physical properties for model systems at T = 298.2 K

    International Nuclear Information System (INIS)

    Gonçalves, Daniel; Koshima, Cristina Chiyoda; Nakamoto, Karina Thiemi; Umeda, Thayla Karla; Aracava, Keila Kazue; Gonçalves, Cintia Bernardo; Rodrigues, Christianne Elisabete da Costa

    2014-01-01

    Highlights: • Fractionation of essential oil compounds. • Liquid + liquid equilibria of limonene, citronellal, ethanol and water were studied. • Distribution coefficients of limonene and citronellal were evaluated. • Densities and viscosities of the phases were experimentally determined. • Solvent selectivities and physical properties were dependent on citronellal and water mass fractions. -- Abstract: As the principal source in Brazil of eucalyptus essential oil extracts, Eucalyptus citriodora contains citronellal, an oxygenated compound responsible for the flavour characteristics. Deterpenation processes, consisting of the removal of terpenic hydrocarbons with the subsequent concentration of the oxygenated compounds, can be used to improve the aromatic characteristics of this essential oil. The purpose of this work was to perform a study of the technical feasibility of using a liquid + liquid extraction process to deterpenate eucalyptus essential oil. Model systems with various mixtures of limonene and citronellal (representing eucalyptus essential oil) as well as solvent (ethanol with various water mass fractions) were used to obtain liquid + liquid equilibrium data. The raffinate and extract phases were also analyzed to characterize the physical properties (density and viscosity). The equilibrium data were used to adjust the NRTL and UNIQUAC parameters. Two empirical models, the simple mixing rule and the Grunberg–Nissan model, were evaluated for use in the descriptions of the densities and viscosities, respectively, of the samples. Increasing the water content in the solvent resulted in decreases in the limonene and citronellal distribution coefficients, with consequential increases in the solvent selectivity values. Increasing values of the densities and viscosities, especially for the solvent-rich phases, were associated with systems using high amounts of hydrated ethanolic solvents

  16. An investigation of an uninterruptible power supply (UPS) based on supercapacitor and liquid nitrogen hybridization system

    International Nuclear Information System (INIS)

    Zhang, Xinjing; Xue, Haobai; Xu, Yujie; Chen, Haisheng; Tan, Chunqing

    2014-01-01

    Highlights: • A hybrid UPS based on supercapacitor and liquid nitrogen engine is proposed. • The dynamic modelling of the hybrid UPS system is conducted. • The dynamic working performance is obtained and analysed based on the simulation. • The hybrid UPS enjoys environmental benignity, long life and easy maintenance. • It is a highly possible solution to replace conventional UPS systems. - Abstract: An uninterruptible power supply (UPS) system based on supercapacitor and liquid nitrogen (LN 2 ) hybridization is first introduced in this paper. Of the newly designed UPS, the supercapacitor reacts instantaneously once the main supply fails, and it also starts the LN 2 power system to produce continuing electricity for the customer. This hybrid UPS system is of environment cleanness, long life time, easy maintenaince, etc. A 10 kW model is analyzed in this study. A two-stage nitrogen expander is designed with the rated speed of 900 rpm as the long time power generation device of the LN 2 cycle. The UPS starting process calculation is carried out. The results reveal that commercial supercapacitors could fulfill this request. This UPS could be a competent choice for the UPS application. Further discussion indicates the LN 2 power system could be used widely from UPS to low carbon vehicles

  17. Replacement of the cross-site transfer system liquid waste transport alternatives evaluation, Project W-058

    International Nuclear Information System (INIS)

    Vo, D.V.; Epperson, E.M.

    1995-05-01

    This document examines high-/low-level radioactive liquid waste transport alternatives. Radioactive liquid waste will be transported from the 200 West Area to the 200 East Area and within the 200 East Areas for safe storage and disposal. The radioactive waste transport alternatives are the Aboveground Transport System (French LR-56 Cask System [3,800 L (1,000 gal)]), 19,000-L (5,000-gal) trailer tanker system, 75,700-L (20,000-gal) rail tanker system and Underground Transport System (buried pipe [unlimited transfer volume capability]). The evaluation focused on the following areas: initial project cost, operational cost, secondary waste generation, radiation exposure, and final decommissioning. The evaluation was based on the near term (1995 to 2005) estimated volume of 49.509 million L (13.063 million gal) and long term (1995 to 2028) estimated volume of 757.1 million L (200 million gal). The conclusion showed that the buried pipe (Underground Transport System) resulted in the lowest overall total cost for near and long term, the trailer container resulted in the highest total cost for near and long term, and the French truck was operationally impractical and cost prohibitive

  18. Design, calculation and experimental studies for liquid metal system main parameters in support of the liquid lithium fusion reactor

    International Nuclear Information System (INIS)

    Evtikhin, V.A.; Lyublinski, I.E.; Vertkov, A.V.

    2001-01-01

    A new concept of a Liquid Lithium Fusion Reactor and the first experimental results were presented at the 16th IAEA Conference on Fusion Energy. During the past two years theoretical estimations have been made, and calculated and experimental results have been obtained in confirmation of this concept and supporting its progress. The main results of this work are given in the paper. (author)

  19. Design, calculation and experimental studies for liquid metal system main parameters in support of the liquid lithium fusion reactor

    International Nuclear Information System (INIS)

    Evtikhin, V.A.; Lyublinski, I.E.; Vertkov, A.V.

    1999-01-01

    A new concept of a Liquid Lithium Fusion Reactor and the first experimental results were presented at the 16th IAEA Conference on Fusion Energy. During the past two years theoretical estimations have been made, and calculated and experimental results have been obtained in confirmation of this concept and supporting its progress. The main results of this work are given in the paper. (author)

  20. On the long wavelength thermodynamic limit of a neutron diffraction experiment in the vicinity of a liquid-liquid critical point. Application to the concentration fluctuations in the Li-ND3 system

    International Nuclear Information System (INIS)

    Chieux, P.; Damay, P.

    1978-01-01

    A quantitative comparison is made between the thermodynamics as obtained from the long wavelength limit of a small angle neutron scattering experiment in the vicinity of a liquid-liquid critical point for the Li-ND 3 system and the data obtained from vapour pressure measurements. The agreement is fair. It is shown how the comparison always implies an underlying model of the interacting species leading to the liquid-liquid phase separation. (Auth.)

  1. Implementation of unscented transform to estimate the uncertainty of a liquid flow standard system

    Energy Technology Data Exchange (ETDEWEB)

    Chun, Sejong; Choi, Hae-Man; Yoon, Byung-Ro; Kang, Woong [Korea Research Institute of Standards and Science, Daejeon (Korea, Republic of)

    2017-03-15

    First-order partial derivatives of a mathematical model are an essential part of evaluating the measurement uncertainty of a liquid flow standard system according to the Guide to the expression of uncertainty in measurement (GUM). Although the GUM provides a straightforward method to evaluate the measurement uncertainty of volume flow rate, the first-order partial derivatives can be complicated. The mathematical model of volume flow rate in a liquid flow standard system has a cross-correlation between liquid density and buoyancy correction factor. This cross-correlation can make derivation of the first-order partial derivatives difficult. Monte Carlo simulation can be used as an alternative method to circumvent the difficulty in partial derivation. However, the Monte Carlo simulation requires large computational resources for a correct simulation because it considers the completeness issue whether an ideal or a real operator conducts an experiment to evaluate the measurement uncertainty. Thus, the Monte Carlo simulation needs a large number of samples to ensure that the uncertainty evaluation is as close to the GUM as possible. Unscented transform can alleviate this problem because unscented transform can be regarded as a Monte Carlo simulation with an infinite number of samples. This idea means that unscented transform considers the uncertainty evaluation with respect to the ideal operator. Thus, unscented transform can evaluate the measurement uncertainty the same as the uncertainty that the GUM provides.

  2. Experimental observations on electrorefining spent nuclear fuel in molten LiCl-KCl/liquid cadmium system

    International Nuclear Information System (INIS)

    Johnson, T. A.; Laug, D. V.; Li, S. X.; Sofu, T.

    1999-01-01

    Argonne National Laboratory (ANL) is currently performing a demonstration program for the Department of Energy (DOE) which processes spent nuclear fuel from the Experimental Breeder Reactor (EBR-II). One of the key steps in this demonstration program is electrorefining of the spent fuel in a molten LiCl-KCl/liquid cadmium system using a pilot scale electrorefiner (Mk-IV ER). This article summarizes experimental observations and engineering aspects for electrorefining spent fuel in the molten LiCl-KCl/liquid cadmium system. It was found that the liquid cadmium pool acted as an intermediate electrode during the electrorefining process in the ER. The cadmium level was gradually decreased due to its high vapor pressure and vaporization rate at the ER operational temperature. The low cadmium level caused the anode assembly momentarily to touch the ER vessel hardware, which generated a periodic current change at the salt/cathode interface and improved uranium recovery efficiency for the process. The primary current distributions calculated by numerical simulations were used in interpreting the experimental results

  3. A high-force controllable MR fluid damper–liquid spring suspension system

    International Nuclear Information System (INIS)

    Raja, Pramod; Wang, Xiaojie; Gordaninejad, Faramarz

    2014-01-01

    The goal of the present research is to investigate the feasibility of incorporating a liquid spring in a semi-active suspension system for use in heavy off-road vehicles. A compact compressible magneto-rheological (MR) fluid damper–liquid spring (CMRFD–LS) with high spring rate is designed, developed and tested. Compressible MR fluids with liquid spring and variable damping characteristics are used. These fluids can offer unique functions in reducing the volume/weight of vehicle struts and improving vehicle dynamic stability and safety. The proposed device consists of a cylinder and piston–rod arrangement with an internal annular MR fluid valve. The internal pressures in the chambers on either side of the piston develop the spring force, while the pressure difference across the MR valve produces the damping force, when the fluid flows through the MR valve. Harmonic characterization of the CMRFD–LS is performed and the force–displacement results are presented. A fluid-mechanics based model is also developed to predict the performance of the system at different operating conditions and compared to the experimental results. Good agreement between the experimental results and theoretical predictions has been achieved. (paper)

  4. Effects of weak localization in quasi-one-dimensional electronic system over liquid helium

    CERN Document Server

    Kovdrya, Y Z; Gladchenko, S P

    2001-01-01

    One measured rho sub x sub x magnetoresistance of a quasi-one-dimensional electronic system over liquid helium within gas scattering range (1.3-2.0 K temperature range). It is shown that with increase of magnetic field the magnetoresistance is reduced at first and them upon passing over minimum it begins to increase from rho sub x sub x approx B sup 2 law. One anticipated that the negative magnetoresistance detected in the course of experiments resulted from the effects of weak localization. The experiment results are in qualitative conformity with the theoretical model describing processes of weak localization in single-dimensional nondegenerate electronic systems

  5. Windows base sodium liquid high-speed measuring system software development

    International Nuclear Information System (INIS)

    Kolokol'tsev, M.V.

    2005-01-01

    This work describes software creation process, that allows to realize data capture from the sodium liquid parameter measuring system, information processing and imaging in the real-time operation mode, retrieval, visualization and documentation of the information in post-startup period as well. Nonstandard decision is described: creation of high-speed data capture system, based on Windows and relatively inexpensive hardware component. Technical description (enterprise classes, interface elements) of the developed and introduced enclosures, realizing data capture and post-startup information visualization are given. (author)

  6. Noise filtering in a multi-channel system using a tunable liquid crystal photonic bandgap fiber

    DEFF Research Database (Denmark)

    Petersen, Martin Nordal; Scolari, Lara; Tokle, Torger

    2008-01-01

    This paper reports on the first application of a liquid crystal infiltrated photonic bandgap fiber used as a tunable filter in an optical transmission system. The device allows low-cost amplified spontaneous emission (ASE) noise filtering and gain equalization with low insertion loss and broad...... tunability. System experiments show that the use of this filter increases for times the distance over which the optical signal-to-noise ratio (OSNR) is sufficient for error-free transmission with respect to the case in which no filtering is used....

  7. Separation coefficients of liquid-vapor in systems formed by yttrium chloride with some impurities

    International Nuclear Information System (INIS)

    Volkov, V.T.; Nikiforova, T.V.; Nisel'son, L.A.; Telegin, G.F.

    1990-01-01

    Using equilibrium Rayleigh distillation in the 800-950 deg C temperature range, separation coefficients of liquid-vapor for systems, formed by yttrium chloride with Co, Cr, Ni, Mn, Fe, Cu, Na, K, Mg, Ca, Li impurities are determined. The impurity concentration lies within 0.02-0.4 mass. % limits of each impurity, and total impurity concentration does not exceed 1 mass. %. The tested impurities, except for calcium, are more volatile than the base, yttrium trichloride. In most systems negative deviation from the Raoult's law is observed

  8. Phase equilibrium study of the binary systems (N-hexyl-3-methylpyridinium tosylate ionic liquid + water, or organic solvent)

    International Nuclear Information System (INIS)

    Domanska, Urszula; Krolikowski, Marek

    2011-01-01

    Highlights: → Synthesis, DSC, and measurements of phase equilibrium of N-hexyl-3-methylpyridinium tosylate. → Solvents used: water, alcohols, benzene, alkylbenzenes, and aliphatic hydrocarbons. → Correlation with UNIQUAC, Wilson and NRTL models. → Comparison with different tosylate-based ILs. - Abstract: The (solid + liquid) phase equilibrium (SLE) and (liquid + liquid) phase equilibrium (LLE) for the binary systems ionic liquid (IL) N-hexyl-3-methylpyridinium tosylate (p-toluenesulfonate), {([HM 3 Py][TOS] + water, or an alcohol (1-butanol, or 1-hexanol, or 1-octanol, or 1-decanol), or an aromatic hydrocarbon (benzene, toluene, or ethylbenzene, or propylbenzene), or an alkane (n-hexane, n-heptane, n-octane)} have been determined at ambient pressure using a dynamic method. Simple eutectic systems with complete miscibility in the liquid phase were observed for the systems involving water and alcohols. The phase equilibrium diagrams of IL and aromatic or aliphatic hydrocarbons exhibit eutectic systems with immiscibility in the liquid phase with an upper critical solution temperature as for most of the ILs. The correlation of the experimental data has been carried out using the UNIQUAC, Wilson and the non-random two liquid (NRTL) correlation equations. The results reported here have been compared with analogous phase diagrams reported by our group previously for systems containing the tosylate-based ILs.

  9. Galvanic Liquid Applied Coating System for Protection of Embedded Steel Surfaces from Corrosion

    Science.gov (United States)

    Curran, Joseph; MacDowell, Louis; Voska, N. (Technical Monitor)

    2002-01-01

    The corrosion of reinforcing steel in concrete is an insidious problem for the Kennedy Space Center, government agencies, and the general public. Existing corrosion protection systems on the market are costly, complex, and time-consuming to install, require continuous maintenance and monitoring, and require specialized skills for installation. NASA's galvanic liquid-applied coating offers companies the ability to conveniently protect embedded steel rebar surfaces from corrosion. Liquid-applied inorganic galvanic coating contains one ore more of the following metallic particles: magnesium, zinc, or indium and may contain moisture attracting compounds that facilitate the protection process. The coating is applied to the outer surface of reinforced concrete so that electrical current is established between metallic particles and surfaces of embedded steel rebar; and electric (ionic) current is responsible for providing the necessary cathodic protection for embedded rebar surfaces.

  10. Performance of a prototype active veto system using liquid scintillator for a dark matter search experiment

    Energy Technology Data Exchange (ETDEWEB)

    Park, J.S. [Center for Underground Physics, Institute for Basic Science (IBS), Daejeon 34047 (Korea, Republic of); Adhikari, P.; Adhikari, G.; Oh, S.Y. [Department of Physics, Sejong University, Seoul 05006 (Korea, Republic of); Kim, N.Y. [Center for Underground Physics, Institute for Basic Science (IBS), Daejeon 34047 (Korea, Republic of); Kim, Y.D. [Center for Underground Physics, Institute for Basic Science (IBS), Daejeon 34047 (Korea, Republic of); Department of Physics, Sejong University, Seoul 05006 (Korea, Republic of); Ha, C.; Park, K.S. [Center for Underground Physics, Institute for Basic Science (IBS), Daejeon 34047 (Korea, Republic of); Lee, H.S., E-mail: hyunsulee@ibs.re.kr [Center for Underground Physics, Institute for Basic Science (IBS), Daejeon 34047 (Korea, Republic of); Jeon, E.J. [Center for Underground Physics, Institute for Basic Science (IBS), Daejeon 34047 (Korea, Republic of)

    2017-04-11

    We report the performance of an active veto system using a liquid scintillator with NaI(Tl) crystals for use in a dark matter search experiment. When a NaI(Tl) crystal is immersed in the prototype detector, the detector tags 48% of the internal {sup 40}K background in the 0–10 keV energy region. We also determined the tagging efficiency for events at 6–20 keV as 26.5±1.7% of the total events, which corresponds to 0.76±0.04 events/keV/kg/day. According to a simulation, approximately 60% of the background events from U, Th, and K radioisotopes in photomultiplier tubes are tagged at energies of 0–10 keV. Full shielding with a 40-cm-thick liquid scintillator can increase the tagging efficiency for both the internal {sup 40}K and external background to approximately 80%.

  11. Simultaneous Design of Ionic Liquids and Azeotropic Separation for Systems Containing Water

    DEFF Research Database (Denmark)

    Roughton, Brock; Camarda, Kyle V.; Gani, Rafiqul

    Separation of azeotropic mixtures is a very common but challenging task, covering a wide range of industrial sectors and issues. For example, most down-stream separation problems following a synthesis step of pharmaceutical and/or biochemical processes, involve the separation of azeotropes. Also......, many separation tasks in the petrochemical and chemical industries involve separation of azeotropic mixtures. A common issue with the design and operation of these separation tasks is whether or not to use solvents? And, if solvents are to be used, what kind of solvent should be used and what would....... Since a large number of azeotropes encountered include water as one of the compounds, the use of ionic liquids in solvent-based separation of water in azeotropic systems has been investigated. Along with the design of the ionic liquid being used to entrain water, the extractive distillation process has...

  12. A new type of liquid-3He target system using small mechanical refrigerators

    International Nuclear Information System (INIS)

    Kato, S.; Kobayashi, K.; Maruyama, K.; Okuno, H.; Konno, O.; Suda, T.; Maki, T.; Asami, H.; Koizumi, T.

    1991-04-01

    A new type of liquid- 3 He target has been developed for photoabsorption experiments at intermediate energies. Using the cooling power of liquid 4 He at reduced vapour pressure, 3 He gas is liquefied into a cylindrical target cell of 180 ml and is maintained at 2.0 K during the experiment. Evaporated 4 He gas is evacuated by a rotary pump and returned into the 4 He bath in the cryostat, where two small mechanical refrigerators with cooling capacities of 3 W at 4.3 K and 10 W at 20 K are operated for the purpose of 4 He recondensation. A maintenance-free operation of more than 1,000 hours has become possible by adopting the 4 He circulation system. (author)

  13. Cryogenic system with the sub-cooled liquid nitrogen for cooling HTS power cable

    Energy Technology Data Exchange (ETDEWEB)

    Fan, Y.F. [Chinese Academy of Sciences, Beijing (China). Technical Institute of Physics and Chemistry; Graduate School of Chinese Academy of Sciences, Beijing (China); Gong, L.H.; Xu, X.D.; Li, L.F.; Zhang, L. [Chinese Academy of Sciences, Beijing (China). Technical Institute of Physics and Chemistry; Xiao, L.Y. [Chinese Academy of Sciences, Beijing (China). Institute of Electrical Engineering

    2005-04-01

    A 10 m long, three-phase AC high-temperature superconducting (HTS) power cable had been fabricated and tested in China August 2003. The sub-cooled liquid nitrogen (LN{sub 2}) was used to cool the HTS cable. The sub-cooled LN{sub 2} circulation was built by means of a centrifugal pump through a heat exchanger in the sub-cooler, the three-phase HTS cable cryostats and a LN{sub 2} gas-liquid separator. The LN{sub 2} was cooled down to 65 K by means of decompressing, and the maximum cooling capacity was about 3.3 kW and the amount of consumed LN{sub 2} was about 72 L/h at 1500 A. Cryogenic system design, test and some experimental results would be presented in this paper. (author)

  14. Interfacial instability induced by a shock wave in a gas-liquid horizontal stratified system

    International Nuclear Information System (INIS)

    Sutradhar, S.C.; Chang, J.S.; Yoshida, H.

    1987-01-01

    The experiments are performed in a rectangular lucite duct equipped with the facility of generating shock waves. Piezo-type pressure transducers are used to monitor the strength and propagation velocity of the shock wave. As the liquid phase has high sound velocity, a prepulse wave system of flow amplitude travels in this phase at a speed faster than the principal shock wave. The magnitude of the transmitted wave in the liquid phase is estimated using a transmission coefficient for gas-liquid system. From the initial pressure ratio of the shock wave, the amplitude of the prepulse as well as the induced interfacial fluid velocity are calculated. The wave length and height of the ripples during the passage of the shock wave are estimated for a specific strength of shock wave moving through the phases. From the high speed photographs, the wave length of the ripples can be assessed. The interfacial friction factor is calculated using colebrook's equation for high speed flow. At least five distinct phenomena are observed to exist during the propagation of a shock wave. These are - (1) the energy carried by the pre-pulse is utilized in perturbing the interface; (2) shock wave induces a mass velocity at the interface; (3) the wavelength of the ripples at the interface is the product of induced interfacial mass velocity and the time period of the prepulse; (4) a portion of the liquid mass of the perturbed interface is entrained in the gas phase may be due to the hydrodynamic lift in that phase; and finally (5) waves with long wavelength are established at the interface

  15. A mobile system for treating low-salinity low-activity liquid wastes

    International Nuclear Information System (INIS)

    Sobolev, I.A.; Timofeev, E.M.; Panteleev, V.I.; Karlin Yu.V.; Kropotov, V.N.; Slastennikov, Yu.T.; Chuikov, V.Yu.; Demkin, V.I.; Rozhkov, V.T.

    1993-01-01

    Radioactive wastes are produced not only in radiochemical production and nuclear power stations but also in numerous research institutes and industrial organizations. The specific activities of these wastes are low, and the volumes do not exceed a few dozen cubic meters a year at each individual organization, but processing such territorially distributed wastes is complicated. This particularly applies to liquid wastes, whose transportation involves a high risk of contamination if the sealing fails. As a rule, liquid wastes are solidified before transportation to a storage site. In some cases, that simplified approach leads to an unduly large consumption of solidifying materials, and particularly to an increase in volume, while storage is an expensive technique. A considerable volume reduction in the wastes to be stored is provided by processing the liquid wastes to concentrate the radionuclides in a small volume, with the main volume of treated water discharged to the drains. Two styles are possible: a stationary plant for processing wastes at each institution or a mobile one with a centralized service base, e.g., at the storage site. Mobile systems have been reported in world practice, although there is no detailed information on them. From the economic viewpoint, the second approach is preferable because it enables one to conduct such operations with fewer plants and fewer staff. That a mobile concept that was used at the Moscow Radon Cooperative in 1985 in processing liquid wastes at regional storage locations is summarized in this article. Research and development led in 1989 to the manufacture of a prototype mobile system mounted on an MAZ articulated vehicle, which included three basic modules: ultrafiltration, electrodialysis, and filtration ones. Each module is located on a separate framework and is connected to the others by reinforced rubber hoses

  16. Characterization of liquid entrainment in the AP1000 automatic depressurization system from APEX tests

    International Nuclear Information System (INIS)

    Richard F Wright; Terry L Schulz; Jose N Reyes; John Groome

    2005-01-01

    Full text of publication follows: The AP1000 is a 1000 MWe advanced nuclear power plant that uses passive safety features to enhance plant safety and to provide significant and measurable improvements in plant simplification, reliability, investment protection and plant costs. The AP1000 relies heavily on the 600 MWe AP600 which received design certification in 1999. A critical part of the AP600 design certification process involved the testing of the passive safety systems. A one-fourth height, one-fourth pressure test facility, APEX-600, was constructed at the Oregon State University to study design basis events, and to provide a body of data to be used to validate the computer models used to analyze the AP600. This facility was extensively modified to reflect the design changes for AP1000 including higher power in the electrically heated rods representing the reactor core, and changes in the size of the pressurizer, core makeup tanks and automatic depressurization system. The APEX-1000 test facility was used to perform design basis accident simulations and separate effects tests to support the AP1000 design certification process. In the event of a LOCA, the AP1000 passive core cooling system provides sources of core makeup water along with an automatic depressurization system (ADS) consisting of several stages of valves which reduce the reactor coolant system pressure in a controlled manner. The final stage of this system, ADS-4, consists of four large valves that open off the hot legs, reducing the pressure to allow gravity injection from the in-containment refueling water storage tank (IRWST) and eventually the containment sump. The 67% increase in power from AP600 to AP1000 results in proportionally larger steam velocities exiting the core. Higher steam velocities could increases the potential for significant liquid entrainment out the ADS-4 lines, affecting the liquid inventory in the reactor. Tests were performed in APEX-1000 to characterize the two

  17. The banking system of liquidity risk management in commercial banks in Kosovo for 2015

    Directory of Open Access Journals (Sweden)

    Adnan Berisha

    2017-03-01

    Full Text Available The financial system in general and banking system in particular in Kosovo, is one of the most stable sectors, even though the Kosovo Economy is not in any enviable position and a stable financial system which would have an impact on greater economic growth. The focus of this research will be in the structure and organization of the financial system in Kosovo with particular emphasis on Kosovo's banking system for 2015. In this research we are focused on the Commercial Banks operating in the framework of the banking sector in Kosovo, what is their capital, how many banks have local- and how many have foreign capital, by whom are licensed and supervised, how is the loans potential of commercial banks in Kosovo, how much and how was the variation of interest rates on loans and deposits for 2015 and their comparison with the previous year, what is capital sufficiency and how many commercial banks do have liquidity in Kosovo? Kosovo banking sector exposure to risk will also have a special attention where it is known that there are several types of financial risk and they are: crediting risk, liquidity risk, market risk, operational risk, etc. Our interest in this research will be focused on liquidity risk and the analysis about the management of each bank including some specific regulative frameworks such as: framework of the Basel Committee known as Basel I, Basel II and more recently Basel III, which have strict rules and which change from time to time depending on financial flows or potential crises.

  18. Extension of nano-scaled exploration into solution/liquid systems using tip-enhanced Raman scattering

    Science.gov (United States)

    Pienpinijtham, Prompong; Vantasin, Sanpon; Kitahama, Yasutaka; Ekgasit, Sanong; Ozaki, Yukihiro

    2017-08-01

    This review shows updated experimental cases of tip-enhanced Raman scattering (TERS) operated in solution/liquid systems. TERS in solution/liquid is still infancy, but very essential and challenging because crucial and complicated biological processes such as photosynthesis, biological electron transfer, and cellular respiration take place and undergo in water, electrolytes, or buffers. The measurements of dry samples do not reflect real activities in those kinds of systems. To deeply understand them, TERS in solution/liquid is needed to be developed. The first TERS experiment in solution/liquid is successfully performed in 2009. After that time, TERS in solution/liquid has gradually been developed. It shows a potential to study structural changes of biomembranes, opening the world of dynamic living cells. TERS is combined with electrochemical techniques, establishing electrochemical TERS (EC-TERS) in 2015. EC-TERS creates an interesting path to fulfil the knowledge about electrochemical-related reactions or processes. TERS tip can be functionalized with sensitive molecules to act as a "surface-enhanced Raman scattering (SERS) at tip" for investigating distinct properties of systems in solution/liquid e.g., pH and electron transfer mechanism. TERS setup is continuously under developing. Versatile geometry of the setup and a guideline of a systematic implementation for a setup of TERS in solution/liquid are proposed. New style of setup is also reported for TERS imaging in solution/liquid. From all of these, TERS in solution/liquid will expand a nano-scaled exploration into solution/liquid systems of various fields e.g., energy storages, catalysts, electronic devices, medicines, alternative energy sources, and build a next step of nanoscience and nanotechnology.

  19. Preliminary analysis of the ORNL Liquid Low-Level Waste system

    International Nuclear Information System (INIS)

    Abraham, T.J.; DePaoli, S.M.; Robinson, S.M.; Walker, A.B.

    1994-08-01

    The objective of this report is to summarize the status of the Liquid Low-Level Waste (LLLW) Systems Analysis project. The focus of this project has been to collect and tabulate data concerning the LLLW system, analyze the current LLLW system operation, and develop the information necessary for the development of long-term treatment options for the LLLW generated at ORNL. The data used in this report were collected through a survey of Oak Ridge National Laboratory (ORNL) literature, various letter reports, and a survey of all current LLLW generators. These data are also being compiled in a user friendly database for ORNL-wide distribution. The database will allow the quick retrieval of all information collected on the ORNL LLLW system and will greatly benefit any LLLW analysis effort. This report summarizes the results for the analyses performed to date on the LLLW system

  20. Seismic evaluation of existing liquid low level waste system at the Oak Ridge National Laboratory

    International Nuclear Information System (INIS)

    Hammond, C.R.; Holmes, R.M.; Kincaid, J.H.; Singhal, M.K.; Stockdale, B.I.; Walls, J.C.; Webb, D.S.

    1993-01-01

    The existing liquid low level waste (LLLW) system at the Oak Ridge National Laboratory is used to collect, neutralize, concentrate, and store the radioactive and toxic waste from various sources at the Laboratory. The waste solutions are discharged from source facilities to individual collection tanks, transferred by underground piping to an evaporator facility for concentration, and pumped through the underground piping to storage in underground tanks. The existing LLLW system was installed in the 1950s with several system additions up to the present. The worst-case accident postulated is an earthquake of sufficient magnitude to rupture the tanks and/or piping so as to damage the containment integrity to the surrounding soil and environment. The objective of an analysis of the system is to provide a level of confidence in the seismic resistance of the LLLW system to withstand the postulated earthquake

  1. Liquid chromatography automatic system with optical activity laser detector and its applications

    International Nuclear Information System (INIS)

    Fajer, V.; Naranjo, S.; Fernandez, H.; Mora, W.; Cepero, T.; Arista, E.; Mesa, G.; Cossio, G.; Arreche, J.; Fonfria, C.; Rodriguez, C.W.

    2009-01-01

    A new liquid chromatographic system with polarimetric detection and a computer program allowing the output of chromatograms to a display on line and electronic data storing was designed, built and put to work. The chromatographic system includes the laser polarimetric detector, having a measuring interval of one second, the chromatographic columns, the continuous flux polarimeter tubes of 50 and 100 mm, the programs for data acquisition, processing and storing, and the technical know-how for its most efficiently application. Thirty minutes is all the time needed to obtain a chromatogram by this method which is reasonably shorter than the time required for any other known comparable technique, and offering, besides, lower operation cost. The combination of molecular exclusion liquid chromatography and laser polarimetric detection has turned into a carbohydrate separation and quantification system of basic importance for the evaluation of plants fluids of industrial interest (sugarcane, agave, vegetable extracts, etc.). It is described here the application of this system as an early or complementary indicator of leaf scald -disease that affects sugarcane plants-. Another application on algae extracts gave good results in the separation and identification of biologically active components. The introduction of this system in several research centers in Cuba and abroad has resulted in practical information for the industry. (Author)

  2. Study on liquid-metal MHD power generation system with two-phase natural circulation. Applicability to fast reactor conditions

    International Nuclear Information System (INIS)

    Saito, Masaki

    2000-03-01

    Feasibility study of the liquid-metal MHD power generation system combined with the high-density two-phase natural circulation has been performed for the applicability to the simple, autonomic energy conversion system of the liquid-metal cooled fast reactor. The present system has many promising aspects not only in the energy conversion process, but also in safety and economical improvements of the liquid-metal cooled fast reactor. For example, the high cycle efficiency can be expected because of the similarity of the present cycle to the Ericsson cycle. Sodium-Water Interaction problem can be excluded by proper combination of the working fluids. As the economical feature, the present system is so simple that the liquid-metal main circular pump, the steam turbine generator, and even the steam generator can be excluded if the thermodynamic working fluid is injected directly into the high temperature liquid metal MHD working fluid. In addition, the present system has the potential to be applied to various heat sources including solar energy because of the high flexibility of the operation temperature. In the present paper, as the first step of the feasibility study, the cycle analyses were performed to examine the effects of the main system parameters on the fundamental characteristics of the system. It is found that the cycle efficiency of the present system is enough competitive with that of the conventional steam turbine system. It is, however, found that the cycle efficiency depends strongly on the gas-liquid slip ratio in the two-phase flow channel. As the conclusions, it is recommended to perform experimental study to obtain the fundamental data, such as the gas-liquid slip ratio in the high-density liquid-metal two-phase natural circulation. (author)

  3. Scaling relation and regime map of explosive gas–liquid flow of binary Lennard-Jones particle system

    KAUST Repository

    Inaoka, Hajime; Yukawa, Satoshi; Ito, Nobuyasu

    2012-01-01

    liquid droplets, and gas particles, which remain supercritical gaseous states under the depressurization realized by simulations. The system has a pipe-like structure similar to the model of a shock tube. We observed physical quantities and flow regimes

  4. Concept of a subcritical transmutation system with fast neutron spectrum and liquid fuel

    International Nuclear Information System (INIS)

    Tittelbach, S.

    2002-11-01

    The annual amount of nearly 9500 t of spent fuel from worldwide industrial nuclear energy utilization has to be disposed as high level waste. The retention of nuclear waste from the biosphere has to be assured until the radiological risk decreases to tolerable levels. The long-term radiological risk of spent fuel is dominated by actinide elements, i.e. plutonium, americium and curium. It is intended to reduce this amount of high level waste by Partitioning and Transmutation, so that the radiotoxicity of the disposed waste falls short of the reference value of fresh fuel decaying naturally after about thousand years. For this time period the retention of high level waste can be assured by technical means. The scope of this work is the design of a subcritical fast transmutation system with liquid metal cooling and liquid metal fuel. The lead bismuth eutectic has been choosen as the liquid metal coolant and fuel carrier. To dissolve at least 3 at% of transuran elements, a minimum fuel temperature of 600 C is required. The calculations were carried out with a fuel composition, which results from two plutonium recycling steps in a thorium fuel cycle. Two homogeneous and two heterogeneous blankets have been designed and evaluated leading to one preferred heterogeneous blanket design, which has been investigated in more detail. This blanket design merges the positive properties of a solid fuel system (better control of fuel and reactivity because of smaller and closed fuel volumina) and a liquid fuel system (continous charge and discharge or extraction of fission products). The blanket design is based on the core design of fast breeder liquid metal reactors. It consists of hexagonal fuel elements housing up to six annular shaped fuel cylinders. The hexagonal shape of the fuel elements leads to three fuel zones positioned concentrically around the central spallation target. There is a strong heterogeneous distribution of power and heat flux in this blanket design. Besides

  5. A review on oral liquid as an emerging technology in controlled drug delivery system.

    Science.gov (United States)

    Torne, Sangmesh Raosaheb; Sheela, Angappan; Sarada, N C

    2017-12-03

    The oral liquid drug delivery system (OLDDS) remains as the primary choice of dosage form, though challenging, for the pharmaceutical scientists. In the last two decades, Oral Liquid Controlled Release (OLCR) formulation has gained a lot of attention because of its advantages over the conventional dosage forms. The world of nanotechnology has paved multiple ways to administer the drug through oral cavity in liquid dosage form with an additional advantage of control over the release. In the current study, the various approaches towards the same have been discussed comprehensively to understand the different mechanisms of OLCR. This review also emphasizes on the existing techniques and the developments that have been made to improve on its efficacy including various formulation related factors. It also provides valuable insights into the role of polymers in the development of OLCR formulation that can be used in the management of Gastroesophageal reflux disease (GERD). Copyright© Bentham Science Publishers; For any queries, please email at epub@benthamscience.org.

  6. Pre-breakdown phenomena and discharges in a gas-liquid system

    Science.gov (United States)

    Tereshonok, D. V.; Babaeva, N. Yu; Naidis, G. V.; Panov, V. A.; Smirnov, B. M.; Son, E. E.

    2018-04-01

    In this paper, we investigate pre-breakdown and breakdown phenomena in gas-liquid systems. Cavitation void formation and breakdown in bubbles immersed in liquids are studied numerically, while complete breakdown of bubbled water is studied in experiments. It is shown that taking into account the dependence of water dielectric constant on electric field strength plays the same important role for cavitation void appearance under the action of electrostriction forces as the voltage rise time. It is also shown that the initial stage of breakdown in deformed bubbles immersed in liquid strongly depends on spatial orientation of the bubbles relative to the external electric field. The effect of immersed microbubbles, distributed in bulk water, on breakdown time and voltage is studied experimentally. At the breakdown voltage, the slow ‘thermal’ mechanism is changed by the fast ‘streamer-leader’ showing a decrease in breakdown time by two orders of magnitude by introducing microbubbles (0.1% of volumetric gas content) into the water. In addition, the plasma channel is found to pass between nearby microbubbles, exhibiting some ‘guidance’ effect.

  7. Eco-friendly Energy Storage System: Seawater and Ionic Liquid Electrolyte.

    Science.gov (United States)

    Kim, Jae-Kwang; Mueller, Franziska; Kim, Hyojin; Jeong, Sangsik; Park, Jeong-Sun; Passerini, Stefano; Kim, Youngsik

    2016-01-08

    As existing battery technologies struggle to meet the requirements for widespread use in the field of large-scale energy storage, novel concepts are urgently needed concerning batteries that have high energy densities, low costs, and high levels of safety. Here, a novel eco-friendly energy storage system (ESS) using seawater and an ionic liquid is proposed for the first time; this represents an intermediate system between a battery and a fuel cell, and is accordingly referred to as a hybrid rechargeable cell. Compared to conventional organic electrolytes, the ionic liquid electrolyte significantly enhances the cycle performance of the seawater hybrid rechargeable system, acting as a very stable interface layer between the Sn-C (Na storage) anode and the NASICON (Na3 Zr2 Si2 PO12) ceramic solid electrolyte, making this system extremely promising for cost-efficient and environmentally friendly large-scale energy storage. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  8. Local Preparation and Evaluation of Double - antibody Liquid Phase Radioimmunoassay System for Detection of Human Testosterone

    International Nuclear Information System (INIS)

    Shafik, H.M.; Sallam, Kh.M.; Ebeid, N.H.; Elshaer, M.R.; Elshae, M.R.

    2016-01-01

    Preparation, evaluation and optimization of testosterone radioimmunoassay (RIA) system using liquid phase double antibody is considered to be the main objective. Three primary components were prepared and characterized to obtain valid and accurate system. These components were polyclonal testosterone antibody, the "1"2"5I-testosterone tracer and set of testosterone standards. The production of polyclonal testosterone antibody was undertaken by immunizing two groups of females white New-Zealand rabbits with testosterone-3-(O-carboxy methyloxime): BSA as immunogen through primary immunization and five boosters. Both R 1 and R 4 gave anti-serum has a high immuno reactivity. The preparation of "1"2"5I-testosterone tracer was carried out using three different conjugates (testosterone-3-TME, testosterone-3-histamine and testosterone-3-BSA) by electrophilic substitution mechanism using chloramine-T as oxidizing agent. Tracers were characterized in terms of radiochemical yield %, radiochemical purity %, specific activity and immuno reactivity. A set of testosterone standards were prepared using highly purified testosterone antigen. Optimization and validation tests of the local liquid phase RIA system were carried out. In conclusion, the results showed that, the local testosterone RIA system is sensitive, specific and accurate with significant cost reduction in comparison with commertial kit and extended use of the method for routine investigation of variety of diseases especially hypogonadism and associated male infertility

  9. Miniature Compressive Ultra-spectral Imaging System Utilizing a Single Liquid Crystal Phase Retarder

    Science.gov (United States)

    August, Isaac; Oiknine, Yaniv; Abuleil, Marwan; Abdulhalim, Ibrahim; Stern, Adrian

    2016-03-01

    Spectroscopic imaging has been proved to be an effective tool for many applications in a variety of fields, such as biology, medicine, agriculture, remote sensing and industrial process inspection. However, due to the demand for high spectral and spatial resolution it became extremely challenging to design and implement such systems in a miniaturized and cost effective manner. Using a Compressive Sensing (CS) setup based on a single variable Liquid Crystal (LC) retarder and a sensor array, we present an innovative Miniature Ultra-Spectral Imaging (MUSI) system. The LC retarder acts as a compact wide band spectral modulator. Within the framework of CS, a sequence of spectrally modulated images is used to recover ultra-spectral image cubes. Using the presented compressive MUSI system, we demonstrate the reconstruction of gigapixel spatio-spectral image cubes from spectral scanning shots numbering an order of magnitude less than would be required using conventional systems.

  10. Insulation systems for liquid methane fuel tanks for supersonic cruise aircraft

    Science.gov (United States)

    Brady, H. F.; Delduca, D.

    1972-01-01

    Two insulation systems for tanks containing liquid methane in supersonic cruise-type aircraft were designed and tested after an extensive materials investigation. One system is an external insulation and the other is an internal wet-type insulation system. Tank volume was maximized by making the tank shape approach a rectangular parallelopiped. One tank was designed to use the external insulation and the other tank to use the internal insulation. Performance of the external insulation system was evaluated on a full-scale tank under the temperature environment of -320 F to 700 F and ambient pressures of ground-level atmospheric to 1 psia. Problems with installing the internal insulation on the test tank prevented full-scale evaluation of performance; however, small-scale testing verified thermal conductivity, temperature capability, and installed density.

  11. A Liquid Scintillator System for Dosimetry of Photon and Proton Beams

    International Nuclear Information System (INIS)

    Beddar S

    2010-01-01

    We have developed a 3D system based on liquid scintillator (LS) for the dosimetry of photon and proton therapy. We have validated the LS detector system for fast and accurate quality assurance of IMRT and proton therapy fields. Further improvements are required to optimize the quantitative analysis of the light output provided by the system in photon beams. We have also demonstrated its usefulness for protons as it can determine the position and the range of proton beams. This system has also been shown to be capable of fast, sub-millimeter spatial localization of proton spots delivered in a 3D volume and could be used for quality assurance of IMPT. Further developments are on-going to measure beam intensities in 3D.

  12. Experimental Results Obtained with Air Liquide Cold Compression System CERN LHC and SNS Projects

    CERN Document Server

    Delcayre, F; Hamber, F; Hilbert, B; Monneret, E; Toia, J L

    2006-01-01

    Large scale collider facilities will make intensive use of superconducting magnets, operating below 2.0 K. This dictates high‐capacity refrigeration systems operating below 2.0 K. These systems, making use of cryogenic centrifugal compressors in a series arrangement with room temperature screw compressors will be coupled to a refrigerator, providing a certain power at 4.5 K. A first Air Liquide Cold Compression System (CCS) unit was built and delivered to CERN in 2001. Installed at the beginning of 2002, it was commissioned and tested successfully during year 2002. A series of four sets of identical CCS were then tested in 2004. Another set of four cryogenic centrifugal compressors (CCC) has been delivered to Thomas Jefferson National Accelerator Facility (JLAB) for the Spallation Neutron Source (SNS) in 2002. These compressors were tested and commissioned from December 2004 to July 2005. The experimental results obtained with these systems will be presented and discussed: the characteristics of the CCC wil...

  13. A system for destroying mixed and hazardous wastes with no gas or liquid effluents

    International Nuclear Information System (INIS)

    Camp, D.W.; Upadhye, R.S.

    1992-04-01

    We developed a conceptual design for a processing system in which the organic components of hazardous or mixed waste would be destroyed, while discharging virtually no gaseous or liquid effluents. Only solid products would be produced. For mixed waste feeds these could then be transported and disposed as low level waste. This system would oxidize the organics using any one of several destruction processes adapted to replace air with a mixture of O 2 and recycled CO 2 . Net production Of CO 2 , HC1, and H 2 O in the dosed recycle system would be scrubbed or reacted to solid products such as CaCO 3 , NaCl, and concrete. This no-effluent design may improve community acceptance of a waste destruction system

  14. Analytical model for performance verification of liquid poison injection system of a nuclear reactor

    International Nuclear Information System (INIS)

    Kansal, Anuj Kumar; Maheshwari, Naresh Kumar; Vijayan, Pallippattu Krishnan

    2014-01-01

    Highlights: • One-dimensional modelling of shut down system-2. • Semi-empirical correlation poison jet progression. • Validation of code. - Abstract: Shut down system-2 (SDS-2) in advanced vertical pressure tube type reactor, provides rapid reactor shutdown by high pressure injection of a neutron absorbing liquid called poison, into the moderator in the calandria. Poison inside the calandria is distributed by poison jets issued from holes provided in the injection tubes. Effectiveness of the system depends on the rate and spread of the poison in the moderator. In this study, a transient one-dimensional (1D) hydraulic code, COPJET is developed, to predict the performance of system by predicting progression of poison jet with time. Validation of the COPJET is done with the data available in literature. Thereafter, it is applied for advanced vertical pressure type reactor

  15. A curcumin-loaded liquid crystal precursor mucoadhesive system for the treatment of vaginal candidiasis

    Directory of Open Access Journals (Sweden)

    Salmazi R

    2015-07-01

    Full Text Available Rafael Salmazi, Giovana Calixto, Jéssica Bernegossi, Matheus Aparecido dos Santos Ramos, Taís Maria Bauab, Marlus Chorilli School of Pharmaceutical Sciences, UNESP – Sao Paulo State University, Campus Araraquara, Department of Drugs and Medicines, Araraquara, Sao Paulo, Brazil Abstract: Women often develop vaginal infections that are caused primarily by organisms of the genus Candida. The current treatments of vaginal candidiasis usually involve azole-based antifungals, though fungal resistance to these compounds has become prevalent. Therefore, much attention has been given to molecules with antifungal properties from natural sources, such as curcumin (CUR. However, CUR has poor solubility in aqueous solvents and poor oral bioavailability. This study attempted to overcome this problem by developing, characterizing, and evaluating the in vitro antifungal action of a CUR-loaded liquid crystal precursor mucoadhesive system (LCPM for vaginal administration. A low-viscosity LCPM (F consisting of 40% wt/wt polyoxpropylene-(5-polyoxyethylene-(20-cetyl alcohol, 50% wt/wt oleic acid, and 10% wt/wt chitosan dispersion at 0.5% with the addition of 16% poloxamer 407 was developed to take advantage of the lyotropic phase behavior of this formulation. Notably, F could transform into liquid crystal systems when diluted with artificial vaginal mucus at ratios of 1:3 and 1:1 (wt/wt, resulting in the formation of F30 and F100, respectively. Polarized light microscopy and rheological studies revealed that F behaved like an isotropic formulation, whereas F30 and F100 behaved like an anisotropic liquid crystalline system (LCS. Moreover, F30 and F100 presented higher mucoadhesion to porcine vaginal mucosa than F. The analysis of the in vitro activity against Candida albicans revealed that CUR-loaded F was more potent against standard and clinical strains compared with a CUR solution. Therefore, the vaginal administration of CUR-loaded LCPMs represents a

  16. Control of ROS and RNS productions in liquid in atmospheric pressure plasma-jet system

    Science.gov (United States)

    Uchida, Giichiro; Ito, Taiki; Takenaka, Kosuke; Ikeda, Junichiro; Setsuhara, Yuichi

    2016-09-01

    Non-thermal plasma jets are of current interest in biomedical applications such as wound disinfection and even treatment of cancer tumors. Beneficial therapeutic effects in medical applications are attributed to excited species of oxygen and nitrogen from air. However, to control the production of these species in the plasma jet is difficult because their production is strongly dependent on concentration of nitrogen and oxygen from ambient air into the plasma jet. In this study, we analyze the discharge characteristics and the ROS and RNS productions in liquid in low- and high-frequency plasma-jet systems. Our experiments demonstrated the marked effects of surrounding gas near the plasma jet on ROS and RNS productions in liquid. By controlling the surround gas, the O2 and N2 main plasma jets are selectively produced even in open air. We also show that the concentration ratio of NO2- to H2O2 in liquid is precisely tuned from 0 to 0.18 in deionized water by changing N2 gas ratio (N2 / (N2 +O2)) in the main discharge gas, where high NO2- ratio is obtained at N2 gas ratio at N2 / (N2 +O2) = 0 . 8 . The low-frequency plasma jet with controlled surrounding gas is an effective plasma source for ROS and RNS productions in liquid, and can be a useful tool for biomedical applications. This study was partly supported by a Grant-in-Aid for Scientific Research on Innovative Areas ``Plasma Medical Innovation'' (24108003) from the Ministry of Education, Culture, Sports, Science and Technology, Japan (MEXT).

  17. Errors detected in pediatric oral liquid medication doses prepared in an automated workflow management system.

    Science.gov (United States)

    Bledsoe, Sarah; Van Buskirk, Alex; Falconer, R James; Hollon, Andrew; Hoebing, Wendy; Jokic, Sladan

    2018-02-01

    The effectiveness of barcode-assisted medication preparation (BCMP) technology on detecting oral liquid dose preparation errors. From June 1, 2013, through May 31, 2014, a total of 178,344 oral doses were processed at Children's Mercy, a 301-bed pediatric hospital, through an automated workflow management system. Doses containing errors detected by the system's barcode scanning system or classified as rejected by the pharmacist were further reviewed. Errors intercepted by the barcode-scanning system were classified as (1) expired product, (2) incorrect drug, (3) incorrect concentration, and (4) technological error. Pharmacist-rejected doses were categorized into 6 categories based on the root cause of the preparation error: (1) expired product, (2) incorrect concentration, (3) incorrect drug, (4) incorrect volume, (5) preparation error, and (6) other. Of the 178,344 doses examined, 3,812 (2.1%) errors were detected by either the barcode-assisted scanning system (1.8%, n = 3,291) or a pharmacist (0.3%, n = 521). The 3,291 errors prevented by the barcode-assisted system were classified most commonly as technological error and incorrect drug, followed by incorrect concentration and expired product. Errors detected by pharmacists were also analyzed. These 521 errors were most often classified as incorrect volume, preparation error, expired product, other, incorrect drug, and incorrect concentration. BCMP technology detected errors in 1.8% of pediatric oral liquid medication doses prepared in an automated workflow management system, with errors being most commonly attributed to technological problems or incorrect drugs. Pharmacists rejected an additional 0.3% of studied doses. Copyright © 2018 by the American Society of Health-System Pharmacists, Inc. All rights reserved.

  18. Measurement and modeling of high-pressure (vapor + liquid) equilibria of (CO{sub 2} + alkanol) binary systems

    Energy Technology Data Exchange (ETDEWEB)

    Bejarano, Arturo; Gutierrez, Jorge E. [Departamento de Ingenieria Quimica y Ambiental, Universidad Tecnica Federico Santa Maria, Avda. Espana 1680, Valparaiso (Chile); Araus, Karina A. [Departamento de Ingenieria Quimica y Bioprocesos, Pontificia Universidad Catolica de Chile, Avda. Vicuna Mackenna 4860, Macul, Santiago (Chile); Fuente, Juan C. de la, E-mail: juan.delafuente@usm.c [Departamento de Ingenieria Quimica y Ambiental, Universidad Tecnica Federico Santa Maria, Avda. Espana 1680, Valparaiso (Chile); Centro Regional de Estudios en Alimentos Saludables, Blanco 1623, Valparaiso (Chile)

    2011-05-15

    Research highlights: (Vapor + liquid) equilibria of three (CO{sub 2} + C{sub 5} alcohol) binary systems were measured. Complementary data are reported at (313, 323 and 333) K and from (2 to 11) MPa. No liquid immiscibility was observed at the temperatures and pressures studied. Experimental data were correlated with the PR-EoS and the van de Waals mixing rules. Correlation results showed relative deviations {<=}8 % (liquid) and {<=}2 % (vapor). - Abstract: Complementary isothermal (vapor + liquid) equilibria data are reported for the (CO{sub 2} + 3-methyl-2-butanol), (CO{sub 2} + 2-pentanol), and (CO{sub 2} + 3-pentanol) binary systems at temperatures of (313, 323, and 333) K, and at pressure range of (2 to 11) MPa. For all (CO{sub 2} + alcohol) systems, it was visually monitored that there was no liquid immiscibility at the temperatures and pressures studied. The experimental data were correlated with the Peng-Robinson equation of state using the quadratic mixing rules of van der Waals with two adjustable parameters. The calculated (vapor + liquid) equilibria compositions were found to be in good agreement with the experimental data with deviations for the mole fractions <8% and <2% for the liquid and vapor phase, respectively.

  19. A curcumin-loaded liquid crystal precursor mucoadhesive system for the treatment of vaginal candidiasis.

    Science.gov (United States)

    Salmazi, Rafael; Calixto, Giovana; Bernegossi, Jéssica; Ramos, Matheus Aparecido dos Santos; Bauab, Taís Maria; Chorilli, Marlus

    2015-01-01

    Women often develop vaginal infections that are caused primarily by organisms of the genus Candida. The current treatments of vaginal candidiasis usually involve azole-based antifungals, though fungal resistance to these compounds has become prevalent. Therefore, much attention has been given to molecules with antifungal properties from natural sources, such as curcumin (CUR). However, CUR has poor solubility in aqueous solvents and poor oral bioavailability. This study attempted to overcome this problem by developing, characterizing, and evaluating the in vitro antifungal action of a CUR-loaded liquid crystal precursor mucoadhesive system (LCPM) for vaginal administration. A low-viscosity LCPM (F) consisting of 40% wt/wt polyoxpropylene-(5)-polyoxyethylene-(20)-cetyl alcohol, 50% wt/wt oleic acid, and 10% wt/wt chitosan dispersion at 0.5% with the addition of 16% poloxamer 407 was developed to take advantage of the lyotropic phase behavior of this formulation. Notably, F could transform into liquid crystal systems when diluted with artificial vaginal mucus at ratios of 1:3 and 1:1 (wt/wt), resulting in the formation of F30 and F100, respectively. Polarized light microscopy and rheological studies revealed that F behaved like an isotropic formulation, whereas F30 and F100 behaved like an anisotropic liquid crystalline system (LCS). Moreover, F30 and F100 presented higher mucoadhesion to porcine vaginal mucosa than F. The analysis of the in vitro activity against Candida albicans revealed that CUR-loaded F was more potent against standard and clinical strains compared with a CUR solution. Therefore, the vaginal administration of CUR-loaded LCPMs represents a promising platform for the treatment of vaginal candidiasis.

  20. The application of polyelectrolytes to improve liquid radwaste treatment system radionuclide removal efficiency

    International Nuclear Information System (INIS)

    Homyk, W.A.; Spall, M.J.; Vance, J.N.

    1990-01-01

    At nuclear plants, miscellaneous waste water treated in the liquid radwaste processing system contains a significant fraction of suspended particulate materials ranging in size from a few microns down to the submicron region. The fewer particles that typically exist as colloids are generally negatively charged by virtue of inorganic and organic anions absorbed onto the particle surfaces. Because many of the radionuclides exist as colloids and resist agglomeration and settling they are not easily removed by mechanical filtration or ion exchange processes. The colloidal materials will easily pass through most filters with conventional pore size ratings and through most ion exchange media. This leads to poor decontamination Factors (dFs) and higher radionuclide releases to the environment. A laboratory-scale testing program was conducted at Indian Point Unit No. 2 to determine the effectiveness of the use of organic polyelectrolytes to destabilize colloidal suspensions in liquid radwaste. Destabilizing colloidal suspensions will improve the removal efficiencies of the suspended material by typical filtration and ion exchange processes. The increased removal efficiencies will provide increased dFs in the liquid radwaste treatment system. The testing focused on identifying the specific organic polyelectrolytes and the associated dosages which would be effective in destabilizing the colloidal suspensions on actual waste water samples. The testing also examined the filtration characteristics of the water source to determine filter parameters such as: body feed material, body feed dosages, specific flow rates, etc., which would provide the basis for the design of filtration systems for these applications. The testing effort and the major conclusions from this investigation are given. 4 refs., 8 figs., 2 tabs

  1. Electrochemical assessment of water|ionic liquid biphasic systems towards cesium extraction from nuclear waste.

    Science.gov (United States)

    Stockmann, T Jane; Zhang, Jing; Montgomery, Anne-Marie; Ding, Zhifeng

    2014-04-22

    A room temperature ionic liquid (IL) composed of a quaternary alkylphosphonium (trihexyltetradecylphosphonium, P66614(+)) and tetrakis(pentafluorophenyl)borate anion (TB(-)) was employed within a water|P66614TB (w|P66614TB or w|IL) biphasic system to evaluate cesium ion extraction in comparison to that with a traditional water|organic solvent (w|o) combination. (137)Cs is a major contributor to the radioactivity of spent nuclear fuel as it leaves the reactor, and its extraction efficiency is therefore of considerable importance. The extraction was facilitated by the ligand octyl(phenyl)-N,N'-diisobutylcarbamoylphosphine oxide (CMPO) used in TRans-Uranium EXtraction processes and investigated through well established liquid|liquid electrochemistry. This study gave access to the metal ion to ligand (1:n) stoichiometry and overall complexation constant, β, of the interfacial complexation reaction which were determined to be 1:3 and 1.6×10(11) at the w|P66614TB interface while the study at w|o elicited an n equal to 1 with β equal to 86.5. Through a straightforward relationship, these complexation constant values were converted to distribution coefficients, δ(α), with the ligand concentrations studied for comparison to other studies present in the literature; the w|o and w|IL systems gave δ(α) of 2 and 8.2×10(7), respectively, indicating a higher overall extraction efficiency for the latter. For the w|o system, the metal ion-ligand stoichiometries were confirmed through isotopic distribution analysis of mass spectra obtained by the direct injection of an emulsified water-organic solvent mixture into an electron spray ionization mass spectrometer. Copyright © 2014 Elsevier B.V. All rights reserved.

  2. Studies on Three Liquid Phase Extraction (TLPE) system for separation of rare earths

    International Nuclear Information System (INIS)

    Yadav, Kartikey K.; Singh, D.K.; Anitha, M.; Singh, H.

    2014-01-01

    Three-liquid-phase extraction (TLPE) is relatively a new separation technique, which takes the advantage of the differences in physicochemical properties of three coexisted phases to achieve multi-phase liquid separation of two or more components in one-step extraction. TLPE system consists of three liquid layers namely an organic solvent phase (organophosphorous type) and two aqueous phases one rich in polymer phase (poly alkylene glycol) and other a salt solution. To study the feasibility of using such system for separation of rare earths, it is important to optimize the preparatory conditions by selective suitable polymer and salt solutions at an appropriate pH to obtain a stable three phase layers to effect the separation. D2EHPA (di-2-ethyl hexyl phosphoric acid) is a well- established extractant in the rare earth industry and has been chosen in the present work to form a TLPE with polymer and salt solution. In the present investigation after preparing the stable three phase, the feasibility of using TLPE has been examined to separate rare earths from a multicomponent solutions. This study has demonstrated the ability of TLPE having D2EHPA as organic phase to separate rare earths from a multicomponent system. Effect of pH, concentration and types of polymer, complexing agent and D2EHPA concentration has been studied. Variation in pH study indicated that 4.0 leads to extraction of rare earths in the polymer phase. PEG 600 was found to be best amongst the polymer investigated. Presence of DTPA as complexing agent in the salt solution having pH >4.0 resulted in enhanced extraction of rare earths in PEG phase

  3. (Liquid + liquid) equilibrium in binary systems of isomeric C8 aliphatic monoethers with acetonitrile and its interpretation by the COSMO-SAC model

    International Nuclear Information System (INIS)

    Reda, Mateusz; Ruszczyński, Łukasz; Gliński, Marek; Hofman, Tadeusz

    2015-01-01

    The (liquid + liquid) solubility curves have been determined by a synthetic method for six binary mixtures of [acetonitrile + {heptyl methyl ether CH 3 O n C 7 H 15 , or ethyl hexyl ether C 2 H 5 O n C 6 H 13 , or pentyl propyl ether n C 3 H 7 O n C 5 H 11 , or isopentyl propyl ether n C 3 H 7 O i C 5 H 11 , or dibutyl ether n C 4 H 9 O n C 4 H 9 , or butyl isobutyl ether n C 4 H 9 O i C 4 H 9 }]. The possibility of the COSMO-SAC model to account for the thermodynamic differences between these systems has been tested and the discussion on the influence of screening charge of ethers on the system properties was undertaken

  4. Electronic transport properties of 4f shell elements of liquid metal using hard sphere Yukawa system

    Science.gov (United States)

    Patel, H. P.; Sonvane, Y. A.; Thakor, P. B.

    2018-04-01

    The electronic transport properties are analyzed for 4f shell elements of liquid metals. To examine the electronic transport properties like electrical resistivity (ρ), thermal conductivity (σ) and thermo electrical power (Q), we used our own parameter free model potential with the Hard Sphere Yukawa (HSY) reference system. The screening effect on aforesaid properties has been examined by using different screening functions like Hartree (H), Taylor (T) and Sarkar (S). The correlations of our resultsand other data with available experimental values are intensely promising. Also, we conclude that our newly constructed parameter free model potential is capable of explaining the above mentioned electronic transport properties.

  5. Polonium release from an ATW burner system with liquid lead-bismuth coolant

    International Nuclear Information System (INIS)

    Li, N.; Yefimov, E.; Pankratov, D.

    1998-04-01

    The authors analyzed polonium release hazards in a conceptual pool-type ATW burner with liquid lead-bismuth eutectic (LBE) coolant. Simplified quantitative models are used based on experiments and real NPP experience. They found little Po contamination outside the burner under normal operating conditions with nominal leakage from the gas system. In sudden gas leak and/or coolant spill accidents, the P contamination level can reach above the regulation limit but short exposure would not lead to severe health consequences. They are evaluating and developing mitigation methods

  6. MECHANISM OF OPTICAL NONLINEARITY IN “LYOTROPIC LIQUID CRYSTAL — VIOLOGEN” SYSTEM

    Directory of Open Access Journals (Sweden)

    Hanna Bordyuh

    2014-06-01

    Full Text Available In the present work we analyze the characteristics of holographic grating recording and consider a mechanism of optical nonlinearity in the lyotropic liquid crystal (LLC — viologen samples. Taking into account structural and electrooptical properties of the admixture molecules it is possible to suggest that the recording is realized due to the change of polarizability of π-electron system of coloured viologen derivatives under the action of laser radiation. The main nonlinear optical parameters such as nonlinear refraction coefficient n2, cubic nonlinear susceptibility χ(3, and hyperpolarizability γ were calculated.

  7. Wettability in the liquid Cu-Ag alloy – fireproof material – gas phase system

    Directory of Open Access Journals (Sweden)

    G. Siwiec

    2013-07-01

    Full Text Available In the present paper, results of wettability studies on the liquid metal – fireproof material – gas phase system using copper and Cu-Ag alloys as well as typical fireproof materials, i.e. aluminium oxide, magnesium oxide and graphite, are presented. Contact angle measurements were conducted at 1 373–1 573 K by means of a high-temperature microscope coupled with a camera and a computer equipped with a program for recording and analysing images. For the measurements, the sessile drop method was used.

  8. Equilibrium vapor-liquid-crystal in Sn-In-P system

    International Nuclear Information System (INIS)

    Ermilin, V.N.; Selin, A.A.; Khukhryanskij, Yu.P.

    1991-01-01

    Using flow method the dependence of phosphorus vapor pressure was investigated on the composition of equilibrium with indium phosphide crystal of Sn-In-P system melt (x P l ≤x In l ) and temperature (in the range 918 to 978 K). Its multiplicative character conditioned by change in phosphorus solubility in liquid phase and reconstruction of internal structure of the melt was established. It is revealed that in the considered melts phosphorus is in atomic form (possible as In n P complexes)

  9. Total Synthesis of Ionic Liquid Systems for Dissolution of Lunar Simulant

    Science.gov (United States)

    Sharpe, Robert J.; Karr, Laurel J.; Paley, Mark S.

    2010-01-01

    For purposes of Space Resource Utilization, work in the total synthesis of a new ionic liquid system for the extraction of oxygen and metals from lunar soil is studied and described. Reactions were carried out according to procedures found in the chemical literature, analyzed via Thin-Layer Chromatography and 1H Nuclear Magnetic Resonance Spectroscopy and purified via vacuum distillation and rotary evaporation. Upon final analysis via 1H NMR, it was found that while the intermediates of the synthesis had been achieved, unexpected side products were also present. The mechanisms and constraints of the synthesis are described as well as the final results of the project and recommendations for continued study

  10. Liquid radwaste processing, operational experience utilizing Duratek Mobile Process System (MPS)

    International Nuclear Information System (INIS)

    Hunkele, W.; Jensen, C.E.; Duratek Corp., Beltsville, MD)

    1985-01-01

    The use of Duratek's Mobile Process System (MPS) employing sluiceable pressure vessels and improved operational techniques generates operational efficiencies including volume reduction (VR), reduced personnel labor and exposure and higher flowrates for cleanup of liquid radwaste streams in an operating nuclear power plant (Salem Generating Station). Significant additional VR is achievable based on laboratory and on-site experience utilizing Durasil 70. Under high conductivity, actual waste stream conditions, this proprietary media has demonstrated through-puts of a magnitude 15 times higher than organic cation resin. A long-term problem, cobalt species removal, is mitigated by this media

  11. Microscopic origin of marginal Fermi-liquid in strongly correlated spin systems

    International Nuclear Information System (INIS)

    Protogenov, A.P.; Ryndyk, D.A.

    1992-08-01

    We consider the consequences of separation of spin and charge degrees of freedom in 2+1D strongly correlated spin systems. Self-consistent spin and charge motions induced by doping in sites of ground and dual lattices form such a spectrum of quasiparticles which together with the dispersionless character of the collective excitation spectrum and the chemical potential pinning in the band centre yield the necessary behavior of charge and spin polarizability to support the theory of marginal liquid formulated by C.M. Varma et al. (Phys. Rev. Lett. 63, 1996 (1989)). (author). 28 refs, 4 figs

  12. Liquid scintillation counting efficiency in three photomultiplier systems. Pure electron capture

    International Nuclear Information System (INIS)

    Los Arcos, J. M.; Grau Carles, A.; Grau Malonda, A.

    1990-01-01

    The tables of counting efficiency as a function of the figure of merit for a liquid scintillation counting system working with three phototubes are presented. The evaluation has been carried out for a Toluene-based scintillator with 5, 10 and 15 ml column, and 19 different radionuclides decaying by pure electron capture: 37Ar 41Ca, 49V, 53 Mn, 55Fe, 59Ni, 68Ge 7iGe, 82Sr, 97Tc, 118Te, 131CS, 137La, 140Ca, 157Tb, 165Er, 193Pt, 194Hg, 205Pb. (Author) 22 refs

  13. A liquid He-3 target system for use at intermediate energies

    International Nuclear Information System (INIS)

    Hassell, D.K.; Abegg, R.; Murdoch, B.T.; van Oers, W.J.H.; Soukup, J.

    1981-04-01

    A liquid 3 He target system with remote instrumentation and handling capabilities has been developed for experiments using the 180-525 MeV TRIUMF cyclotron. Helium-3 gas is liquefied by means of a 4 He cryostat into a cylindrical target cell (4.4 cm diameter, 1.6 cm thick) and maintained during operation at approximately 1.6 K. This provides an areal target density of approximately 2.7 x 10 22 He-3 nuclei/cm 2 (128 mg/cm 2 ), suitable for intermediate energy proton scattering. (author)

  14. Pulse mode actuation-readout system based on MEMS resonator for liquid sensing

    DEFF Research Database (Denmark)

    Tang, Meng; Cagliani, Alberto; Davis, Zachary James

    2014-01-01

    A MEMS (Micro-Electro-Mechanical Systems) bulk disk resonator is applied for mass sensing under its dynamic mode. The classical readout circuitry involves sophisticated feedback loop and feedthrough compensation. We propose a simple straightforward non-loop pulse mode actuation and capacitive...... readout scheme. In order to verify its feasibility in liquid bio-chemical sensing environment, an experimental measurement is conducted with humidity sensing application. The measured resonant frequency changes 60kHz of 67.7MHz with a humidity change of 0~80%....

  15. Electrically tunable spatially variable switching in ferroelectric liquid crystal/water system

    Science.gov (United States)

    Choudhary, A.; Coondoo, I.; Prakash, J.; Sreenivas, K.; Biradar, A. M.

    2009-04-01

    An unusual switching phenomenon in the region outside conducting patterned area in ferroelectric liquid crystal (FLC) containing about 1-2 wt % of water has been observed. The presence of water in the studied heterogeneous system was confirmed by Fourier transform infrared spectroscopy. The observed optical studies have been emphasized on the "spatially variable switching" phenomenon of the molecules in the nonconducting region of the cell. The observed phenomenon is due to diffusion of water between the smectic layers of the FLC and the interaction of the curved electric field lines with the FLC molecules in the nonconducting region.

  16. An in-situ RBS system for measuring nuclides adsorbed at the liquid-solid interface

    Energy Technology Data Exchange (ETDEWEB)

    Morita, K; Yuhara, J; Ishigami, R [Nagoya Univ. (Japan). School of Engineering; and others

    1997-03-01

    An in-situ RBS system has been developed in which heavier nuclides adsorbed at the inner surface of a thin lighter window specimen of liquid container in order to determine the rate constants for their sorption and release at the interface. The testing of a thin silicon window of the sample assembly, in which Xe gas of one atmosphere was enclosed, against the bombardment of the probing ion beam has been performed. A desorption behavior of a lead layer adsorbed at the SiO{sub 2} layer of silicon window surface into deionized water has been measured as a preliminary experiment. (author)

  17. Electrochemical assessment of water|ionic liquid biphasic systems towards cesium extraction from nuclear waste

    OpenAIRE

    Stockmann, T. Jane; Zhang, Jing; Montgomery, Anne-Marie; Ding, Zhifeng

    2014-01-01

    A room temperature ionic liquid (IL) composed of a quaternary alkylphosphonium (trihexyltetradecylphosphonium, P66614(+)) and tetrakis(pentafluorophenyl) borate anion (TB) was employed within a water| P66614TB (w|P66614TB or w|IL) biphasic system to evaluate cesium ion extraction in comparison to that with a traditional water|organic solvent (w|o) combination. Cs-137 is a major contributor to the radioactivity of spent nuclear fuel as it leaves the reactor, and its extraction efficiency is th...

  18. Determination of descriptors for polycyclic aromatic hydrocarbons and related compounds by chromatographic methods and liquid-liquid partition in totally organic biphasic systems.

    Science.gov (United States)

    Ariyasena, Thiloka C; Poole, Colin F

    2014-09-26

    Retention factors on several columns and at various temperatures using gas chromatography and from reversed-phase liquid chromatography on a SunFire C18 column with various mobile phase compositions containing acetonitrile, methanol and tetrahydrofuran as strength adjusting solvents are combined with liquid-liquid partition coefficients in totally organic biphasic systems to calculate descriptors for 23 polycyclic aromatic hydrocarbons and eighteen related compounds of environmental interest. The use of a consistent protocol for the above measurements provides descriptors that are more self consistent for the estimation of physicochemical properties (octanol-water, air-octanol, air-water, aqueous solubility, and subcooled liquid vapor pressure). The descriptor in this report tend to have smaller values for the L and E descriptors and random differences in the B and S descriptors compared with literature sources. A simple atom fragment constant model is proposed for the estimation of descriptors from structure for polycyclic aromatic hydrocarbons. The new descriptors show no bias in the prediction of the air-water partition coefficient for polycyclic aromatic hydrocarbons unlike the literature values. Copyright © 2014 Elsevier B.V. All rights reserved.

  19. Conceptual study of a complementary scram system for liquid metal cooled nuclear reactors

    International Nuclear Information System (INIS)

    Vanmaercke, S.; Van den Eynde, G.; Tijskens, E.; Bartosiewicz, Y.

    2009-01-01

    GEN-IV reactors promise higher safety and reliability as one of the major improvements over previous generations of reactors. To achieve that, all GEN-IV reactor concepts require two completely independent shutdown systems that rely on different operating principles. For liquid metal cooled reactors the first system is an absorber-rod based solution. The second system that by requirement should rely on another principle, is however quite a challenge to design. The second system used in current PWR reactors is to dissolve a neutron absorber, boric acid, into the primary coolant. This method cannot be used in liquid metal cooled reactors because of the high cost of cleaning the coolant. In this paper an overview of the existing literature on scram systems is given, each with their advantages and limitations. A promising new concept is also presented. This concept leads to a totally passive self activating device using small absorbing particles that flow into a dedicated channel to shutdown the reactor. The system consists of tubes filled with particles of an absorber material. During normal operation, these particles are kept above the active core by means of a metallic seal. In case of an accident, the system is activated by the temperature increase in the coolant. This leads to melting of the metal seal. The ongoing work conducted at SCK·CEN and UCL/TERM aims at assessing the reliability of this new concept both experimentally and numerically. This study is multidisciplinary as neutronic and thermal hydraulics issues are tackled. Most challenging is however the thermal hydraulics related to understanding and predicting the liberation and flow of the absorber particles during a shutdown. Simple experiments are envisaged to compare to numerical simulations using the Discrete Element Method for simulating the particles. In a later stage this will be coupled with Smoothed Particles Hydrodynamics for simulating the melting of the seal. Some preliminary experimental and

  20. Research towards ultrasonic systems to assist in-vessel manipulations in liquid metal cooled reactors

    International Nuclear Information System (INIS)

    Dierckx, Marc; Van-Dyck, Dries

    2013-06-01

    We describe the state of the art of the research towards ultrasonic measurement methods for use in lead-bismuth cooled liquid metal reactors. Our current research activities are highly focused on specific tasks in the MYRRHA system, which is a fast spectrum research reactor cooled with the eutectic mixture of lead and bismuth (LBE) and is conceived as an accelerator driven system capable of operating in both sub-critical and critical mode. As liquid metal is opaque to light, normal visual feedback during fuel manipulations in the reactor vessel is not available and must therefore be replaced by a system that is not hindered by the opacity of the coolant. In this respect ultrasonic measurement techniques have been proposed and even developed in the past for operation in sodium cooled reactors. To our knowledge, no such systems have ever been deployed in lead based reactors and we are the first to have a research program in this direction as will be detailed in this paper. We give an overview of the acoustic properties of LBE and compare them with the properties of sodium and water to theoretically show the feasibility of ultrasonic systems operating in LBE. In the second part of the paper we discuss the results of the validation experiments in water and LBE. A typical scene is ultrasonically probed by a mechanical scanning system while the signals are processed to render a 3D visualization on a computer screen. It will become clear that mechanical scanning is capable of producing acceptable images but that it is a time consuming process that is not fit to solve the initial task to providing feedback during manipulations in the reactor vessel. That is why we propose to use several dedicated ultrasonic systems each adapted to a specific task and capable to provide real-time feedback of the ongoing manipulations, as is detailed in the third and final part of the paper. (authors)

  1. On the quantification of the dissolved hydroxyl radicals in the plasma-liquid system using the molecular probe method

    Science.gov (United States)

    Ma, Yupengxue; Gong, Xinning; He, Bangbang; Li, Xiaofei; Cao, Dianyu; Li, Junshuai; Xiong, Qing; Chen, Qiang; Chen, Bing Hui; Huo Liu, Qing

    2018-04-01

    Hydroxyl (OH) radical is one of the most important reactive species produced by plasma-liquid interactions, and the OH in liquid phase (dissolved OH radical, OHdis) takes effect in many plasma-based applications due to its high reactivity. Therefore, the quantification of the OHdis in a plasma-liquid system is of great importance, and a molecular probe method usually used for the OHdis detection might be applied. Herein, we investigate the validity of using the molecular probe method to estimate the [OHdis] in the plasma-liquid system. Dimethyl sulfoxide is used as the molecular probe to estimate the [OHdis] in an air plasma-liquid system, and usually the estimation of [OHdis] is deduced by quantifying the OHdis-induced derivative, the formaldehyde (HCHO). The analysis indicates that the true concentration of the OHdis should be estimated from the sum of three terms: the formed HCHO, the existing OH scavengers, and the H2O2 formed from the OHdis. The results show that the measured [HCHO] needs to be corrected since the HCHO consumption is not negligible in the plasma-liquid system. We conclude from the results and the analysis that the molecular probe method generally underestimates the [OHdis] in the plasma-liquid system. If one wants to obtain the true concentration of the OHdis in the plasma-liquid system, one needs to know the consumption behavior of the OHdis-induced derivatives, the information of the OH scavengers (such as hydrated electron, atomic hydrogen besides the molecular probe), and also the knowledge of the H2O2 formed from the OHdis.

  2. Lignin Structure and Aggregation Behavior in a Two-Component Ionic Liquid Solvent System

    Directory of Open Access Journals (Sweden)

    Susanne Bylin

    2014-08-01

    Full Text Available Ionic liquids are of potential interest in the processing of lignocellulosic biomass. In this study, the ionic liquid co-solvent system of 1-methylimidazole (MIM and 1-ethyl-3-methyl-imidazolium acetate (EMIMAc was used to solvate LignoBoost lignin fractionated from black liquor obtained from a kraft paper mill. Lignin ethanol-precipitated (LEP and ethanol-soluble (LES fractions were characterized via gel permeation chromatography (GPC and 13C- and 31P-nuclear magnetic resonance spectroscopy (NMR to determine structural characteristics and their relationship to polymer solubility in the system. Polymer integrity and solubility were optimal at ~20% lignin loading (w/w. Results showed that LEPs were generally of higher apparent molecular weight (Mw and enriched with condensed/aliphatic ether linkages and aliphatic hydroxyls. The LESs had a lower apparent Mw and were enriched with carboxylic and phenolic groups. This newly gained knowledge on lignin fractionation and aggregation in the present solvent system provides future opportunities for tuning fractionation/extraction to suit a specific biomass-derived product, e.g., carbon fibers.

  3. Genetic algorithms for the optimization of pipeline systems for liquid distribution (2)

    International Nuclear Information System (INIS)

    Narvaez, Paulo Cesar; Galeano, Haiver

    2004-01-01

    This is the second of two articles presenting a Genetic Algorithm (GA) to obtain an optimal design, from an economical and operational point of view, of a pipeline system for the distribution of liquids, based on criteria such as complying with the laws of preservation of mass and energy, volume of flow requirements in the points of consumption where pressure is known, restriction in pressure value in those points of the system where it is unknown as well as in the velocity which must be under the erosion limit. In this article the traditional techniques for designing a GA in this type of problems are combined with some ideas that have not been applied to this field previously. The proposed GA allows for the sizing of liquid distribution systems that include pipelines, nodes for consumption and provision, tanks, pumping equipment, nozzles, control valves and accessories. The first article of this series (Galeano, 2003), presents the different formulations found in literature for the design of networks through optimization techniques and formulates mathematically, the optimization problem. In this article, the characteristics of the GA are specified and it is applied to solve the Alperovits and Shamir (1977) network and for a fireproof network, which allowed testing some of the characteristics of the model that are not found in the literature, such as the possibility of including pumping equipment, aspersion nozzles and accessories. In addition, the contribution of the components and sensitivity are analyzed in order to investigate some characteristics and parameters of the implemented GA

  4. High Pressure Vapor-Liquid Equilibrium of Supercritical Carbon Dioxide + n-Hexane System

    Institute of Scientific and Technical Information of China (English)

    YU Jinglin; TIAN Yiling; ZHU Rongjiao; LIU Zhihua

    2006-01-01

    Vapor-liquid equilibrium data of supercritical carbon dioxide + n-hexane system were measured at 313.15 K,333.15 K,353.15 K,and 373.15 K and their molar volumes and densities were measured both in the subcritical and supercritical regions ranging from 2.15 to 12.63 MPa using a variable-volume autoclave.The thermodynamic properties including mole fractions,densities,and molar volumes of the system were calculated with an equation of state by Heilig and Franck,in which a repulsion term and a square-well potential attraction term for intermolecular interaction was used.The pairwise combination rule was used to calculate the square-well molecular interaction potential and three adjustable parameters (ω,kε,kσ) were obtained.The Heilig-Franck equation of state is found to have good correlation with binary vapor-liquid equilibrium data of the carbon dioxide + n-hexane system.

  5. A decontamination system for chemical weapons agents using a liquid solution on a solid sorbent.

    Science.gov (United States)

    Waysbort, Daniel; McGarvey, David J; Creasy, William R; Morrissey, Kevin M; Hendrickson, David M; Durst, H Dupont

    2009-01-30

    A decontamination system for chemical warfare agents was developed and tested that combines a liquid decontamination reagent solution with solid sorbent particles. The components have fewer safety and environmental concerns than traditional chlorine bleach-based products or highly caustic solutions. The liquid solution, based on Decon Greentrade mark, has hydrogen peroxide and a carbonate buffer as active ingredients. The best solid sorbents were found to be a copolymer of ethylene glycol dimethacrylate and n-lauryl methacrylate (Polytrap 6603 Adsorber); or an allyl methacrylate cross-linked polymer (Poly-Pore E200 Adsorber). These solids are human and environmentally friendly and are commonly used in cosmetics. The decontaminant system was tested for reactivity with pinacolyl methylphosphonofluoridate (Soman, GD), bis(2-chloroethyl)sulfide (Mustard, HD), and S-(2-diisopropylaminoethyl) O-ethyl methylphosphonothioate (VX) by using NMR Spectroscopy. Molybdate ion (MoO(4)(-2)) was added to the decontaminant to catalyze the oxidation of HD. The molybdate ion provided a color change from pink to white when the oxidizing capacity of the system was exhausted. The decontaminant was effective for ratios of agent to decontaminant of up to 1:50 for VX (t(1/2) decontamination solution were measured to show that the sorbent decreased the vapor concentration of GD. The E200 sorbent had the additional advantage of absorbing aqueous decontamination solution without the addition of an organic co-solvent such as isopropanol, but the rate depended strongly on mixing for HD.

  6. Energy Conversion Alternatives Study (ECAS), Westinghouse phase 1. Volume 10: Liquid-metal MHD systems. [energy conversion efficiency of electric power plants using liquid metal magnetohydrodynamics

    Science.gov (United States)

    Holman, R. R.; Lippert, T. E.

    1976-01-01

    Electric Power Plant costs and efficiencies are presented for two basic liquid-metal cycles corresponding to 922 and 1089 K (1200 and 1500 F) for a commercial applications using direct coal firing. Sixteen plant designs are considered for which major component equipment were sized and costed. The design basis for each major component is discussed. Also described is the overall systems computer model that was developed to analyze the thermodynamics of the various cycle configurations that were considered.

  7. (Liquid + liquid) equilibria measurements for ternary systems (sulfolane + a carboxylic acid + n-heptane) at T = 303.15 K and at 0.1 MPa

    International Nuclear Information System (INIS)

    Cele, N.P.; Bahadur, I.; Redhi, G.G.; Ebenso, E.E.

    2016-01-01

    Highlights: • The (liquid + liquid) equilibrium for (sulfolane + a carboxylic acid + heptane) was measured. • Selectivity values for solvent separation efficiency were calculated. • Separation of carboxylic acids from heptane is feasible by extraction. • Three parameter equations have been fitted to the binodal curve data. • The NRTL and UNIQUAC models were used to correlate the experimental data. - Abstract: In the present work, new (liquid + liquid) equilibrium (LLE) values are reported for ternary systems {sulfolane(1) + acetic acid, or propanoic acid, or butanoic acid, or 2-methylpropanoic acid, or pentanoic acid, or 3-methylbutanoic acid (2) + n-heptane (3)} at T = 303.15 K and at p = 0.1 MPa. The mutual solubility of carboxylic acid in sulfolane is dependent on the length and structure of the alkyl chain of the carboxylic acid; it progressively increases with an increase in the alkyl chain of the carboxylic acid. The single phase homogenous region increases as the alkyl chain of the carboxylic acid increases. The n-heptane is most soluble in the carboxylic acid mixtures with long alkyl chain, that is, (3-methylbutanoic acid + sulfolane) and (pentanoic acid + sulfolane) systems and least soluble in the carboxylic acid with short alkyl chain (acetic acid + sulfolane) system. Carboxylic acid together with many other oxygenates and hydrocarbons are produced by SASOL Company in South Africa using the Fischer–Tropsch process. The details about this process are given in introduction section. The NRTL and UNIQUAC models were used to correlate the experimental tie-lines and to calculate the phase compositions of the ternary systems. It was found that the NRTL model fits the experimental values significantly better than the UNIQUAC model.

  8. Extended UNIQUAC Model for Correlation and Prediction of Vapor-Liquid-Liquid-Solid Equilibria in Aqueous Salt Systems Containing Non-Electrolytes. Part B. Alcohol (Ethanol, Propanols, Butanols) - Water-salt systems

    DEFF Research Database (Denmark)

    Thomsen, Kaj; Iliuta, Maria Cornelia; Rasmussen, Peter

    2004-01-01

    The Extended UNIQUAC model for electrolyte solutions is an excess Gibbs energy function consisting of a Debye-Huckel term and a term corresponding to the UNIQUAC equation. For vapor-liquid equilibrium calculations, the fugacities of gas-phase components are calculated with the Soave-Redlich-Kwong......The Extended UNIQUAC model for electrolyte solutions is an excess Gibbs energy function consisting of a Debye-Huckel term and a term corresponding to the UNIQUAC equation. For vapor-liquid equilibrium calculations, the fugacities of gas-phase components are calculated with the Soave...... solid-liquid-vapor equilibrium and thermal property data for strongly non-ideal systems. In this work, the model is extended to aqueous salt systems containing higher alcohols. The calculations are based on an extensive database consisting of salt solubility data, vapor liquid equilibrium data...

  9. Leak testing plan for the Oak Ridge National Laboratory liquid low- level waste system (active tanks)

    International Nuclear Information System (INIS)

    Douglas, D.G.; Wise, R.F.; Starr, J.W.; Maresca, J.W. Jr.

    1992-06-01

    A leak testing plan for a portion of the Liquid Low-Level Waste (LLLW) system at the Oak Ridge National Laboratory (ORNL) is provided in the two volumes that form this document. This plan was prepared in response to the requirements of the Federal Facilities Agreement (FFA) between the US Department of Energy and two other agencies, the US Environmental Protection Agency (EPA) and the Tennessee Department of Environment and Conservation (TDEC). The effective date of this agreement was 1 January 1992. The LLLW system is an interconnected complex of tanks and pipelines. The FFA distinguishes four different categories of tank and pipeline systems within this complex: new systems (Category A), doubly contained systems (Category B), singly contained systems (Category C), and inactive systems (Category D). The FFA's specific requirements for leak testing of the Category C systems is addressed in this plan. The plan also addresses leak testing of the Category B portions of the LLLW system. Leak testing of the Category B components was brought into the plan to supplement the secondary containment design demonstration effort that is under way for these components

  10. Vapor-liquid, liquid-liquid and vapor-liquid-liquid equilibrium of binary and multicomponent systems with MEG modeling with the CPA EoS and an EoS/G(E) model

    DEFF Research Database (Denmark)

    Folas, Georgios; Kontogeorgis, Georgios; Michelsen, Michael Locht

    2006-01-01

    The cubic-plus-association (CPA) EoS is applied to multicomponent multiphase equilibria of systems containing MEG as a hydrate inhibitor. It is shown that the model provides very satisfactory prediction of the phase behavior for the systems tested. A more conventional engineering model for handling...

  11. Process configuration of Liquid-nitrogen Energy Storage System (LESS) for maximum turnaround efficiency

    Science.gov (United States)

    Dutta, Rohan; Ghosh, Parthasarathi; Chowdhury, Kanchan

    2017-12-01

    Diverse power generation sector requires energy storage due to penetration of variable renewable energy sources and use of CO2 capture plants with fossil fuel based power plants. Cryogenic energy storage being large-scale, decoupled system with capability of producing large power in the range of MWs is one of the options. The drawback of these systems is low turnaround efficiencies due to liquefaction processes being highly energy intensive. In this paper, the scopes of improving the turnaround efficiency of such a plant based on liquid Nitrogen were identified and some of them were addressed. A method using multiple stages of reheat and expansion was proposed for improved turnaround efficiency from 22% to 47% using four such stages in the cycle. The novelty here is the application of reheating in a cryogenic system and utilization of waste heat for that purpose. Based on the study, process conditions for a laboratory-scale setup were determined and presented here.

  12. Systems analysis of a 100-MWe modular liquid metal cooled reactor

    International Nuclear Information System (INIS)

    Morris, E.E.; Rhow, S.K.; Switick, D.M.

    1985-01-01

    The response of a 100-MWe modular liquid metal cooled reactor to unprotected loss of flow and/or loss of primary heat removal accidents is analyzed using the systems analysis code SASSYS. The reactor response is tracked for the first 1000 s following a postulated upset in the primary heat removal system. The calculations do not take credit for the functioning of any decay heat removal other than through the secondary system. In addition to the power rating, other features of the reactor are an average sodium temperature rise of 148 K, a sodium void worth (counting the core and upper axial blanket) of 1.89 $, and 3.6 $ of Doppler feedback due to a uniform e-fold fuel temperature increase

  13. Electronic equipment of the extended system for beam diagnostics of the ''Lyudmila'' liquid-hydrogen chamber

    International Nuclear Information System (INIS)

    Basiladze, S.G.; Bulanov, N.F.; Nguen V'et Zung; Yudin, V.K.

    1978-01-01

    The electronic equipment of an expanded system of beam monitoring for the Lyudmila liquid-hydrogen bubble chamber is described. The system contains ten proportional chambers: nine two-coordinate and one one-coordinate chambers, spacing being 1 mm. The total number of wires is 912. Signals are measured in parallel from all the 48 wires for any plane, or for two planes from even and odd wires. The electronic equipment includes preamplifiers on a field transistor, charge-digital converters, and followers. The electronic circuits in the chambers are distinguished by simplicity and low power consumption: one transistor and 1 mW per wire respectively. The system operates with a small TPA-i computer

  14. Study of a system for tritium analysis in water by electrolytic enrichment and liquid scintillation

    International Nuclear Information System (INIS)

    Pane, L.

    1979-01-01

    A system for the measurement of the low-level tritium concentrations in water samples has been experimentally studied. The enrichment of the samples is performed through electrolysis in twenty cells connected in series, and the counting is made in a liquid scintillation counter. Several parameters that could affect the accuracy of the results are analysed and the optimization of the system is discussed. For a sample volume reduction from 1000 to 15ml, the recovery of tritium, during electrolysis is of 63% and the enrichment factor is about 40. The lowest detection limit of the system is 1.0+-0.5 U.T. Its analytical capacity is of 30 samples a month. The results obtained in the determination of 3 H concentration in a series of samples from rain, surface and underground waters can be considered satisfactory. (Author) [pt

  15. Neutronics investigation of advanced self-cooled liquid blanket systems in helical reactor

    International Nuclear Information System (INIS)

    Tanaka, T.; Sagara, A.; Muroga, T.; Youssef, M.Z.

    2006-10-01

    Neutronics performances of advanced self-cooled liquid blanket systems have been investigated in design activity of the helical-type reactor FFHR2. In the present study, a new three-dimensional (3-D) neutronics calculation system has been developed for the helical-type reactor to enhance quick feedback between neutronics evaluation and design modification. Using this new calculation system, advanced Flibe-cooled and Li-cooled liquid blanket systems proposed for FFHR2 have been evaluated to make clear design issues to enhance neutronics performance. Based on calculated results, modification of the blanket dimensions and configuration have been attempted to achieve the adequate tritium breeding ability and neutron shielding performance in the helical reactor. The total tritium breeding ratios (TBRs) obtained after modifying the blanket dimensions indicated that all the advanced blanket systems proposed for FFHR2 would achieve adequate tritium self-sufficiency by dimension adjustment and optimization of structures in the breeder layers. Issues in neutron shielding performance have been investigated quantitatively using 3-D geometry of the helical blanket system, support structures, poloidal coils etc. Shielding performance of the helical coils against direct neutrons from core plasma would achieve design target by further optimization of shielding materials. However, suppression of the neutron streaming and reflection through the divertor pumping areas in the original design is important issue to protect the poloidal coils and helical coils, respectively. Investigation of the neutron wall loading indicated that the peaking factor of the neutron wall load distribution would be moderated by the toroidal and helical effect of the plasma distribution in the helical reactor. (author)

  16. Study on stair-step liquid triggered capillary valve for microfluidic systems

    Science.gov (United States)

    Zhang, Lei; Jones, Ben; Majeed, Bivragh; Nishiyama, Yukari; Okumura, Yasuaki; Stakenborg, Tim

    2018-06-01

    In lab-on-a-chip systems, various microfluidic technologies are being developed to handle fluids at very small quantities, e.g. in the scale of nano- or pico-liter. To achieve autonomous fluid handling at a low cost, passive fluidic control, based on the capillary force between the liquid and microchannel surface, is of the utmost interest in the microsystem. Valves are an essential component for flow control in many microfluidic systems, which enables a sequence of fluidic operations to be performed. In this paper, we present a new passive valve structure for a capillary driven microfluidic device. It is a variation of a capillary trigger valve that is amenable to silicon microfabrication; it will be referred to as a stair-step liquid triggered valve. In this paper, the valve functionality and its dependencies on channel geometry, surface contact angle, and surface roughness are studied both experimentally and with numerical modeling. The effect of the contact angle was explored in experiments on the silicon microfabricated valve structure; a maximal working contact angle, above which the valve fails to be triggered, was demonstrated. The fluidic behavior in the stair-step channel structure was further explored computationally using the finite volume method with the volume-of-fluid approach. Surface roughness due to scalloping of the sidewall during the Bosch etch process was hypothesized to reduce the sidewall contact angle. The reduced contact angle has considerable impacts on the capillary pressure as the liquid vapor interface traverses the stair-step structure of the valve. An improved match in the maximal working contact angle between the experiments and model was obtained when considering this surface roughness effect.

  17. 3-D seismic response analysis of liquid-tank-foundation system by using BEM-FEM-impedance function combination

    International Nuclear Information System (INIS)

    Cho, Eu-Kyeong; Park, Jung-Il; Lee, Jong-Rim

    1995-01-01

    A new analytic scheme to resolve the liquid-soil-structure interaction problem in cylindrical liquid storage tanks on the deformable soil is presented. Boundary elements and finite elements are combined to simulate the liquid-structure coupling effect while tuned foundation impedance functions (TFIF's) are representing the motion of the rigid foundation block on the flexible soil. Because the coupled dynamic system is expressed explicitly in terms of mass and stiffness, the developed scheme is applicable to any standard dynamic analysis methodologies. (author)

  18. Modelling (vapour + liquid) and (vapour + liquid + liquid) equilibria of {water (H2O) + methanol (MeOH) + dimethyl ether (DME) + carbon dioxide (CO2)} quaternary system using the Peng-Robinson EoS with Wong-Sandler mixing rule

    International Nuclear Information System (INIS)

    Ye Kongmeng; Freund, Hannsjoerg; Sundmacher, Kai

    2011-01-01

    Highlights: → Phase behaviour modelling of H 2 O-MeOH-DME under pressurized CO 2 (anti-solvent) using PRWS. → PRWS-UNIFAC-PSRK has better performance than PRWS-UNIFAC-Lby in general. → Reliable to extend the VLE and VLLE phase behaviour from binary to multicomponent systems. → Successful prediction of the VLE and VLLE of binary, ternary, and quaternary systems. → Potential to apply the model for designing new DME separation process. - Abstract: The (vapour + liquid) equilibria (VLE) and (vapour + liquid + liquid) equilibria (VLLE) binary data from literature were correlated using the Peng-Robinson (PR) equation of state (EoS) with the Wong-Sandler mixing rule (WS). Two group contribution activity models were used in the PRWS: UNIFAC-PSRK and UNIFAC-Lby. The systems were successfully extrapolated from the binary systems to ternary and quaternary systems. Results indicate that the PRWS-UNIFAC-PSRK generally displays a better performance than the PRWS-UNIFAC-Lby.

  19. High-pressure (vapor + liquid) equilibria in the (nitrogen + n-heptane) system

    Energy Technology Data Exchange (ETDEWEB)

    Garcia-Sanchez, Fernando [Laboratorio de Termodinamica, Programa de Ingenieria Molecular, Instituto Mexicano del Petroleo, Eje Central Lazaro Cardenas 152, 07730 Mexico, D.F. (Mexico)]. E-mail: fgarcias@imp.mx; Eliosa-Jimenez, Gaudencio [Laboratorio de Termodinamica, Programa de Ingenieria Molecular, Instituto Mexicano del Petroleo, Eje Central Lazaro Cardenas 152, 07730 Mexico, D.F. (Mexico); Silva-Oliver, Guadalupe [Laboratorio de Termodinamica, Programa de Ingenieria Molecular, Instituto Mexicano del Petroleo, Eje Central Lazaro Cardenas 152, 07730 Mexico, D.F. (Mexico); Godinez-Silva, Armando [Laboratorio de Termodinamica, Programa de Ingenieria Molecular, Instituto Mexicano del Petroleo, Eje Central Lazaro Cardenas 152, 07730 Mexico, D.F. (Mexico)

    2007-06-15

    In this work, new (vapor + liquid) equilibrium data for the (N{sub 2} + n-heptane) system were experimentally measured over a wide temperature range from (313.6 to 523.7) K and pressures up to 50 MPa. A static-analytic apparatus with visual sapphire windows and pneumatic capillary samplers was used in the experimental measurements. Equilibrium phase compositions and (vapor + liquid) equilibrium ratios are reported. The new results were compared with those reported by other authors. The comparison showed that the pressure-composition data reported in this work are less scattered than those determined by others. Hence, the results demonstrate the reliability of the experimental apparatus at high temperatures and pressures. The experimental data were represented with the PR and PC-SAFT equations of state by using one-fluid mixing rules and a single temperature independent interaction parameter. Results of the representation showed that the PC-SAFT equation was superior to the PR equation in correlating the experimental data of the (N{sub 2} + n-heptane) system.

  20. Ultrasonic measurement of gap between calandria tube and liquid injection shutdown system tube in PHWR

    International Nuclear Information System (INIS)

    Kim, Tae Ryong; Sohn, Seok Man; Lee, Jun Shin; Lee, Sun Ki; Lee, Jong Po

    2001-01-01

    Sag of CT or liquid injection shutdown system tubes in pressurized heavy water reactor is known to occur due to irradiation creep and growth during plant operation. When the sag of CT is big enough, the CT tube possibly comes in contact with liquid injection shutdown system tube (LIN) crossing beneath the CT, which subsequently may prevent the safe operation. It is therefore necessary to check the gap between the two tubes in order to confirm no contacts when using a proper measure periodically during the plant life. An ultrasonic gap measuring probe assembly which can be fed through viewing port installed on the calandria was developed and utilized to measure the sags of both tubes in a pressurized heavy water reactor in Korea. It was found that the centerlines of CT and LIN can be precisely detected by ultrasonic wave. The gaps between two tubes were easily obtained from the relative distance of the measured centerline elevations of the tubes. But the measured gap data observed at the viewing port were actually not the data at the crossing point of CT and LIN. To get the actual gap between two tubes, mathematical modeling for the deflection curves of two tubes was used. The sags of CT and LIN tubes were also obtained by comparison of the present centerlines with the initial elevations at the beginning of plant operation. The gaps between two tubes in the unmeasurable regions were calculated based on the measurement data and the channel power distribution

  1. Proceedings of the FNCA 2002 workshop on application of electron accelerator. Radiation system for liquid samples

    International Nuclear Information System (INIS)

    Yoshii, Fumio; Kume, Tamikazu

    2003-10-01

    'Forum for Nuclear Cooperation in Asia (FNCA) Workshop on Application of Electron Accelerator' was sponsored by the Ministry of Education, Culture, Sports, Science and Technology (MEXT) and hosted by Japan Atomic Energy Research Institute (JAERI) and Japan Atomic Industry Forum (JAIF). It was held at the Takasaki Radiation Chemistry Research Establishment (TRCRE), JAERI, Takasaki, Japan from 16 to 20 December 2002. The attendants at the workshop were consisted of 13 experts on application of electron accelerator from each of the participating countries, i.e., China, Indonesia, Korea, Malaysia, the Philippines, Thailand and Vietnam, and 40 participants from Japan. A total of 18 papers including invited papers on liquid waste treatment by electron beam, reviews of the radiation systems, and designing and cost analysis of EB irradiation system were presented. The major areas of interest of FNCA countries for cooperation were identified for application of low energy electron accelerator as liquid, thin film and granules. The gas and wastewater treatments were added to the above major areas. Based on the proposal from the participating countries, discussions were carried out to re-formulate the work plan of the project for three years until FY 2004. All manuscripts submitted by every speaker were included in the proceedings. The 17 of the presented papers are indexed individually. (J.P.N.)

  2. High-pressure (vapor + liquid) equilibria in the (nitrogen + n-heptane) system

    International Nuclear Information System (INIS)

    Garcia-Sanchez, Fernando; Eliosa-Jimenez, Gaudencio; Silva-Oliver, Guadalupe; Godinez-Silva, Armando

    2007-01-01

    In this work, new (vapor + liquid) equilibrium data for the (N 2 + n-heptane) system were experimentally measured over a wide temperature range from (313.6 to 523.7) K and pressures up to 50 MPa. A static-analytic apparatus with visual sapphire windows and pneumatic capillary samplers was used in the experimental measurements. Equilibrium phase compositions and (vapor + liquid) equilibrium ratios are reported. The new results were compared with those reported by other authors. The comparison showed that the pressure-composition data reported in this work are less scattered than those determined by others. Hence, the results demonstrate the reliability of the experimental apparatus at high temperatures and pressures. The experimental data were represented with the PR and PC-SAFT equations of state by using one-fluid mixing rules and a single temperature independent interaction parameter. Results of the representation showed that the PC-SAFT equation was superior to the PR equation in correlating the experimental data of the (N 2 + n-heptane) system

  3. Liquid-waste management systems improvement programmes at Los Alamos Scientific Laboratory

    International Nuclear Information System (INIS)

    Emelity, L.A.; Stanley, P.M.; Buchholz, J.R.

    1981-01-01

    Programmes at the Los Alamos Scientific Laboratory (LASL) are approximately 50% nuclear weapons related and 50% general energy research and development. Since its beginning in the 1940s, liquid industrial wastes have been contaminated with isotopes of plutonium, americium, uranium and various beta-gamma emitters, but management and treatment efforts were, owing to the proportions of the various isotopes, directed primarily at the alpha emitters. The evolution in management methods at LASL since the 1940s has been reported in previous papers. This treatise discusses the most recent three-phase effort to modernize the systems to the probable standards of the next twenty years. The first phase, provision of a double-encased, continuously monitored sewer system will soon be under construction. The second phase, modernization of the treatment facilities, has been funded and is in the final design stage. The third phase, not funded as of this date, will provide lined, monitored solar evaporation ponds for total management of the treated industrial wastes with no release of any liquid to the environment. (author)

  4. Liquid waste management systems improvement programs at Los Alamos Scientific Laboratory

    International Nuclear Information System (INIS)

    Emelity, L.A.; Stanley, P.M.; Buchholz, J.R.

    1980-01-01

    Programs at the Los Alamos Scientific Laboratory (LASL) are approximately 50% nuclear weapons related and 50% general energy research and development. Since its beginning in the 1940's liquid industrial wastes have been contaminated with isotopes of plutonium, americium, uranium and various beta-gamma emitters, but management and treatment efforts were, due to the proportions of the various isotopes, directed primarily at the alpha emitters. The evolution in management methods at LASL since the 40's has been reported in previous papers. This treatise discusses the most recent three-phase effort to modernize the systems to the probable standards of the next twenty years. The first phase, provision of double-encased, continuously monitored sewer system will soon be under construction. The second phase, modernization of the treatment facilities, has been funded and is in the final design stage. The third phase, not funded as of this date, will provide lined, monitored solar evaporation ponds for total management of the treated industrial wastes with no release of any liquid to the environment

  5. Investigation of two-phase liquid-metal magnetohydrodynamic power systems

    International Nuclear Information System (INIS)

    Amend, W.E.; Fabris, G.; Cutting, J.

    1975-01-01

    A two-phase Liquid-Metal MHD (LMMHD) system is under development at the Argonne National Laboratory, and results are presented for detailed cycle analysis and systems studies, the experimental facility, and the thermal and magneto fluid mechanics problems encountered. The studies indicate that the LMMHD cycle will operate efficiently in the temperature range of 1000-1600 0 F (50 percent efficiency with a maximum cycle temperature of 1600 0 F) and is therefore potentially compatible with many advanced heat sources under development such as the LMFBR, fluidized-bed coal combustor, HTGCR and the fusion reactor. Of special interest is the coupling to the LMFBR thereby eliminating the costly, potentially hazardous liquid-metal/water interface. The results of detailed parametric studies of the heat transfer interfaces between an LMMHD power cycle and an LMFBR and a steam bottoming plant are described. Experimental evaluation of the two-phase LMMHD generator was performed in an ambient temperature NaK--N 2 facility at ANL. Results of these experiments, performed to determine the operating characteristics of the device as a function of the various independent parameters and to investigate two-phase flow, are given. (U.S.)

  6. Extraction of Biomolecules Using Phosphonium-Based Ionic Liquids + K3PO4 Aqueous Biphasic Systems

    Science.gov (United States)

    Louros, Cláudia L. S.; Cláudio, Ana Filipa M.; Neves, Catarina M. S. S.; Freire, Mara G.; Marrucho, Isabel M.; Pauly, Jérôme; Coutinho, João A. P.

    2010-01-01

    Aqueous biphasic systems (ABS) provide an alternative and efficient approach for the extraction, recovery and purification of biomolecules through their partitioning between two liquid aqueous phases. In this work, the ability of hydrophilic phosphonium-based ionic liquids (ILs) to form ABS with aqueous K3PO4 solutions was evaluated for the first time. Ternary phase diagrams, and respective tie-lines and tie-lines length, formed by distinct phosphonium-based ILs, water, and K3PO4 at 298 K, were measured and are reported. The studied phosphonium-based ILs have shown to be more effective in promoting ABS compared to the imidazolium-based counterparts with similar anions. Moreover, the extractive capability of such systems was assessed for distinct biomolecules (including amino acids, food colourants and alkaloids). Densities and viscosities of both aqueous phases, at the mass fraction compositions used for the biomolecules extraction, were also determined. The evaluated IL-based ABS have been shown to be prospective extraction media, particularly for hydrophobic biomolecules, with several advantages over conventional polymer-inorganic salt ABS. PMID:20480041

  7. PEF and UV combined system for pathogen microorganisms inactivation in liquid food products

    Energy Technology Data Exchange (ETDEWEB)

    Cramariuc, R [Competence Center in Electrostatics and Electrotechnologies, Bucharest (Romania); Popa, M; Mitelut, A; Geicu, M [University of Agronomic Science and Veterinary Medicine, Bucharest (Romania); Tudorache, A; Brinduse, E; Kontek, A; Fotescu, L [Research and Development Institute in Viticulture and Vinification Valea Calugareasca (Romania); Cramariuc, B [IT Center for Science and Technology, Bucharest (Romania); Nisiparu, L, E-mail: raducramariuc@yahoo.com [Carol Davila University of Medicine and Pharmacy, Bucharest (Romania)

    2011-06-23

    Pulsed electrical field (PEF) treatment is a non-thermal food preservation technology based on the use of the electrical field in impulses applied in order to inactivate and control pathogen microorganisms in foods. This technology is highly appreciated for its ability to prolong the shelf life of the treated product without the use of heat and also for its ability to preserve the product's sensory qualities and nutritional value as well as for the microbiological control of the treated products. This paper presents the PEF and UV treatment methods, or a combination between the two, for microbe inactivation in liquid products. The experiments were carried out using yeasts, lactic bacteria and acetic bacteria in the following systems: stand-alone treatments (PEF or UV) or in combination (UV+PEF or PEF+UV). The results of these experiments showed that one can obtain total inactivation of microorganisms using the combined UV+PEF system, thus leading to the possibility of increasing liquid food products quality as compared to the quality obtained using thermal pasteurization.

  8. PEF and UV combined system for pathogen microorganisms inactivation in liquid food products

    Science.gov (United States)

    Cramariuc, R.; Popa, M.; Tudorache, A.; Brînduşe, E.; Kontek, A.; Mitelut, A.; Fotescu, L.; Cramariuc, B.; Geicu, M.; Nisiparu, L.

    2011-06-01

    Pulsed electrical field (PEF) treatment is a non-thermal food preservation technology based on the use of the electrical field in impulses applied in order to inactivate and control pathogen microorganisms in foods. This technology is highly appreciated for its ability to prolong the shelf life of the treated product without the use of heat and also for its ability to preserve the product's sensory qualities and nutritional value as well as for the microbiological control of the treated products. This paper presents the PEF and UV treatment methods, or a combination between the two, for microbe inactivation in liquid products. The experiments were carried out using yeasts, lactic bacteria and acetic bacteria in the following systems: stand-alone treatments (PEF or UV) or in combination (UV+PEF or PEF+UV). The results of these experiments showed that one can obtain total inactivation of microorganisms using the combined UV+PEF system, thus leading to the possibility of increasing liquid food products quality as compared to the quality obtained using thermal pasteurization.

  9. PEF and UV combined system for pathogen microorganisms inactivation in liquid food products

    International Nuclear Information System (INIS)

    Cramariuc, R; Popa, M; Mitelut, A; Geicu, M; Tudorache, A; Brinduse, E; Kontek, A; Fotescu, L; Cramariuc, B; Nisiparu, L

    2011-01-01

    Pulsed electrical field (PEF) treatment is a non-thermal food preservation technology based on the use of the electrical field in impulses applied in order to inactivate and control pathogen microorganisms in foods. This technology is highly appreciated for its ability to prolong the shelf life of the treated product without the use of heat and also for its ability to preserve the product's sensory qualities and nutritional value as well as for the microbiological control of the treated products. This paper presents the PEF and UV treatment methods, or a combination between the two, for microbe inactivation in liquid products. The experiments were carried out using yeasts, lactic bacteria and acetic bacteria in the following systems: stand-alone treatments (PEF or UV) or in combination (UV+PEF or PEF+UV). The results of these experiments showed that one can obtain total inactivation of microorganisms using the combined UV+PEF system, thus leading to the possibility of increasing liquid food products quality as compared to the quality obtained using thermal pasteurization.

  10. Modern Evaluation of Liquisolid Systems with Varying Amounts of Liquid Phase Prepared Using Two Different Methods

    Directory of Open Access Journals (Sweden)

    Barbora Vraníková

    2015-01-01

    Full Text Available Liquisolid systems are an innovative dosage form used for enhancing dissolution rate and improving in vivo bioavailability of poorly soluble drugs. These formulations require specific evaluation methods for their quality assurance (e.g., evaluation of angle of slide, contact angle, or water absorption ratio. The presented study is focused on the preparation, modern in vitro testing, and evaluation of differences of liquisolid systems containing varying amounts of a drug in liquid state (polyethylene glycol 400 solution of rosuvastatin in relation to an aluminometasilicate carrier (Neusilin US2. Liquisolid powders used for the formulation of final tablets were prepared using two different methods: simple blending and spraying of drug solution onto a carrier in fluid bed equipment. The obtained results imply that the amount of liquid phase in relation to carrier material had an effect on the hardness, friability, and disintegration of tablets, as well as their height. The use of spraying technique enhanced flow properties of the prepared mixtures, increased hardness values, decreased friability, and improved homogeneity of the final dosage form.

  11. Solubility limit of methyl red and methylene blue in microemulsions and liquid crystals of water, sds and pentanol systems

    OpenAIRE

    Beri, D.; Pratami, A.; Gobah, P. L.; Dwimala, P.; Amran, A.

    2017-01-01

    Solubility of dyes in amphiphilic association structures of water, SDS and penthanol system (i.e. in the phases of microemulsions and liquid crystals) was attracted much interest due to its wide industrial and technological applications. This research was focused on understanding the solubility limitation of methyl red and methylene blue in microemulsion and liquid crystal phases. Experimental results showed that the highest solubility of methyl red was in LLC, followed by w/o microemulsion a...

  12. Galvanic Liquid Applied Coating System For Protection of Embedded Steel Surfaces from Corrosion

    Science.gov (United States)

    Curran, Joseph; Curran, Jerome; Voska, N. (Technical Monitor)

    2002-01-01

    Corrosion of reinforcing steel in concrete is an insidious problem facing Kennedy Space Center (KSC), other Government Agencies, and the general public. These problems include KSC launch support structures, highway bridge infrastructure, and building structures such as condominium balconies. Due to these problems, the development of a Galvanic Liquid Applied Coating System would be a breakthrough technology having great commercial value for the following industries: Transportation, Infrastructure, Marine Infrastructure, Civil Engineering, and the Construction Industry. This sacrificial coating system consists of a paint matrix that may include metallic components, conducting agents, and moisture attractors. Similar systems have been used in the past with varying degrees of success. These systems have no proven history of effectiveness over the long term. In addition, these types of systems have had limited success overcoming the initial resistance between the concrete/coating interface. The coating developed at KSC incorporates methods proven to overcome the barriers that previous systems could not achieve. Successful development and continued optimization of this breakthrough system would produce great interest in NASA/KSC for corrosion engineering technology and problem solutions. Commercial patents on this technology would enhance KSC's ability to attract industry partners for similar corrosion control applications.

  13. Solidification of liquid concentrate and solid waste generated as by-products of the liquid radwaste treatment systems in light-water reactors

    International Nuclear Information System (INIS)

    Neilson, R.M. Jr.; Colombo, P.

    1977-01-01

    The treatment of liquid concentrate and solid waste produced in light-water reactors as by-products of liquid radwaste treatment systems consists of five basic operations: waste collection, waste pretreatment, solidification agent handling, mixing/packaging (solidification) and waste package handling. This paper will concern itself primarily with the solidification operation, however, the other operations enumerated as well as the types of wastes treated and their origins will be briefly described, especially with regards to their effects on solidification. During solidification, liquid concentrate and solid wastes are incorporated with a solidification agent to form a monolithic, free-standing solid. The basic solidification agent types either currently used in the United States or proposed for use include absorbants, hydraulic cement, urea-formaldehyde, other polymer systems, and bitumen. The operation, formulations and limitations of these agents as used for radwaste solidification will be discussed. Properties relevant to the evaluation of solidified waste forms will be identified and relative comparisons made for wastes solidified by various processes

  14. Application of PLC to dynamic control system for liquid He cryogenic pumping facility on JT-60U NBI system

    International Nuclear Information System (INIS)

    Honda, A.; Okano, F.; Ooshima, K.; Akino, N.; Kikuchi, K.; Tanai, Y.; Takenouchi, T.; Numazawa, S.; Ikeda, Y.

    2008-01-01

    The control system of the cryogenic facility in the JT-60 NBI system has been replaced by employing the PLC (Programmable Logic Controller) and SCADA (Supervisory Control And Data Acquisition) system. The original control system was constructed about 20 years ago by specifying the DCS (Distributed Control System) computer to deal with ∼400 feedback loops. Recently, troubles on this control system have increased due to its age-induced deterioration. To maintain the high reliability of the cryogenic facility, a new control system has been planned with the PLC and SCADA systems. Their attractive features include high market availability and cost-effectiveness, however, the use of PLC for such a large facility with ∼400 feedback loops has not been established because of insufficient processing capability of the early PLC. Meanwhile, the recent progress in the PLC enables to use the FBD (function block diagram) programming language for 500 function blocks. By optimizing the function blocks and connecting them in the FBD language, the feedback loops have been successfully replaced from DCS to PLC without a software developer. Moreover, an oscillation of the liquid He level, which often occurs during the cooldown mode of the cryopumps, can be automatically stabilized by easily adding a new process program in the PLC. At present, the new control system has worked well

  15. Determination of Sunset Yellow and Tartrazine in Food Samples by Combining Ionic Liquid-Based Aqueous Two-Phase System with High Performance Liquid Chromatography

    Science.gov (United States)

    Sha, Ou; Zhu, Xiashi; Feng, Yanli; Ma, Weixing

    2014-01-01

    We proposed a simple and effective method, by coupling ionic liquid-based aqueous two-phase systems (IL-ATPSs) with high performance liquid chromatography (HPLC), for the analysis of determining tartrazine and sunset yellow in food samples. Under the optimized conditions, IL-ATPSs generated an extraction efficiency of 99% for both analytes, which could then be directly analyzed by HPLC without further treatment. Calibration plots were linear in the range of 0.01–50.0 μg/mL for both Ta and SY. The limits of detection were 5.2 ng/mL for Ta and 6.9 ng/mL for SY. This method proves successful for the separation/analysis of tartrazine and sunset yellow in soft drink sample, candy sample, and instant powder drink and leads to consistent results as obtained from the Chinese national standard method. PMID:25538857

  16. Determination of Sunset Yellow and Tartrazine in Food Samples by Combining Ionic Liquid-Based Aqueous Two-Phase System with High Performance Liquid Chromatography

    Directory of Open Access Journals (Sweden)

    Ou Sha

    2014-01-01

    Full Text Available We proposed a simple and effective method, by coupling ionic liquid-based aqueous two-phase systems (IL-ATPSs with high performance liquid chromatography (HPLC, for the analysis of determining tartrazine and sunset yellow in food samples. Under the optimized conditions, IL-ATPSs generated an extraction efficiency of 99% for both analytes, which could then be directly analyzed by HPLC without further treatment. Calibration plots were linear in the range of 0.01–50.0 μg/mL for both Ta and SY. The limits of detection were 5.2 ng/mL for Ta and 6.9 ng/mL for SY. This method proves successful for the separation/analysis of tartrazine and sunset yellow in soft drink sample, candy sample, and instant powder drink and leads to consistent results as obtained from the Chinese national standard method.

  17. Determination of sunset yellow and tartrazine in food samples by combining ionic liquid-based aqueous two-phase system with high performance liquid chromatography.

    Science.gov (United States)

    Sha, Ou; Zhu, Xiashi; Feng, Yanli; Ma, Weixing

    2014-01-01

    We proposed a simple and effective method, by coupling ionic liquid-based aqueous two-phase systems (IL-ATPSs) with high performance liquid chromatography (HPLC), for the analysis of determining tartrazine and sunset yellow in food samples. Under the optimized conditions, IL-ATPSs generated an extraction efficiency of 99% for both analytes, which could then be directly analyzed by HPLC without further treatment. Calibration plots were linear in the range of 0.01-50.0 μg/mL for both Ta and SY. The limits of detection were 5.2 ng/mL for Ta and 6.9 ng/mL for SY. This method proves successful for the separation/analysis of tartrazine and sunset yellow in soft drink sample, candy sample, and instant powder drink and leads to consistent results as obtained from the Chinese national standard method.

  18. Ionic liquids as entrainers for water + ethanol, water + 2-propanol, and water + THF systems: A quantum chemical approach

    Energy Technology Data Exchange (ETDEWEB)

    Verma, Vijay Kumar [Department of Chemical Engineering, Indian Institute of Technology Guwahati, Guwahati 781 039, Assam (India); Banerjee, Tamal, E-mail: tamalb@iitg.ernet.i [Department of Chemical Engineering, Indian Institute of Technology Guwahati, Guwahati 781 039, Assam (India)

    2010-07-15

    Ionic liquids (ILs) are used as entrainers in azeotropic systems such as water + ethanol, water + 2-propanol, and water + tetrahydrofuran (THF). Ionic liquids consisting of a cation and an anion has limitless combinations, thereby making experimentation expensive and time taking. For the prediction of the liquid phase nonidealities resulting from molecular interactions, 'COnductor-like Screening MOdel for Real Solvents' (COSMO-RS) approach is used in this work for the screening of potential ionic liquids. Initially benchmarking has been done on 12 reported isobaric IL based ternary systems with an absolute average deviation of 4.63% in vapor phase mole fraction and 1.07% in temperature. After successful benchmarking, ternary vapor + liquid equilibria for the azeotropic mixture of (a) ethanol + water, (b) 2-propanol + water, and (c) THF + water with combinations involving 10 cations (imidazolium, pyridinium, quinolium) and 24 anions were predicted. The VLE prediction, which gave the relative volatility, showed that the imidazolium based ionic liquid were the best entrainer for the separation of the three systems at their azeotropic point. ILs with [MMIM] cation in combination with acetate [OAc], chloride [Cl], and bromide [Br] anion gave the highest relative volatility.

  19. Optimization of the automated colorimetric measurement system for pH of liquid

    Directory of Open Access Journals (Sweden)

    Katin Oleg

    2017-01-01

    Full Text Available This article considers the issue of automatic control of the acidity of the aquatic environment, which is relevant in such branches of agriculture as hydroponics and aeroponics. A method for measuring the pH of a liquid using a potentiometric method is considered. This method allows to obtain the most accurate pH values, but has some drawbacks. In particular, the article analyzes the advantages of this method over the use of a universal indicator paper and a color sensor for pH determination, describes the components, the conditions of their operation and storage, describes the basic principles of the measuring system operation. A method for converting a signal received at a pH electrode into a microcontroller suitable for processing is also contemplated. The main goal of the development and application of the measuring system described in the article is to achieve a high degree of autonomy and automation of aeroponic and hydroponic greenhouse complexes.

  20. The ATLAS liquid argon calorimeter high-voltage system: commissioning, optimisation and LHC relative luminosity measurement

    International Nuclear Information System (INIS)

    Arfaoui, S.

    2011-10-01

    The main goals of the ATLAS scientific programme are the observation or exclusion of physics beyond the Standard Model (SM), as well as the measurement of production cross-sections of SM processes. In order to do so, it is important to measure the luminosity at the interaction point with great precision. The ATLAS luminosity is extracted using several detectors with varying efficiencies and acceptances. Different methods, such as inclusive - or coincidence - event counting and calorimeter integrated current measurements, are calibrated and cross-compared to provide the most accurate luminosity determination. In order to provide more cross-checks and a better control on the systematic uncertainties, an independent measurement using the liquid argon (LAr) forward calorimeter (FCal), based on the readout current of its high-voltage system, has been developed. This document describes how the LAr calorimeter high-voltage system has been installed and commissioned, as well as its application to a relative luminosity determination. (author)