WorldWideScience

Sample records for bituminous bases

  1. Review and environmental impact assessment of green technologies for base courses in bituminous pavements

    International Nuclear Information System (INIS)

    Anthonissen, Joke; Van den bergh, Wim; Braet, Johan

    2016-01-01

    This paper provides a critical review of different approaches applied in the Belgian asphalt sector in order to reduce the environmental impact of bituminous road construction works. The focus is on (1) reusing reclaimed asphalt pavement, (2) reducing the asphalt production temperature, and (3) prolonging the service life of the pavement. Environmental impact assessment of these methods is necessary to be able to compare these approaches and understand better the ability to reduce the environmental impact during the life cycle of the road pavement. Attention should be drawn to the possible shift in environmental impact between various life cycle stages, e.g., raw material production, asphalt production, or waste treatment. Life cycle assessment is necessary to adequately assess the environmental impact of these approaches over the entire service life of the bituminous pavement. The three approaches and their implementation in the road sector in Flanders (region in Belgium) are described and the main findings from life cycle assessment studies on these subjects are discussed. It was found from the review that using reclaimed asphalt pavement in new bituminous mixtures might yield significant environmental gains. The environmental impact of the application of warm mix asphalt technologies, on the other hand, depends on the technique used. - Highlights: • Recycling, lower production temperature and durability of asphalt are investigated. • The use of RAP in new asphalt mixtures yields significant environmental advantages. • It would be beneficial to allow RAP in asphalt mixtures for wearing courses. • The use of particular additives might counteract the environmental gain from WMA. • The service life and the environmental data source influence the LCA results.

  2. Review and environmental impact assessment of green technologies for base courses in bituminous pavements

    Energy Technology Data Exchange (ETDEWEB)

    Anthonissen, Joke, E-mail: joke.anthonissen@uantwerpen.be [Faculty of Applied Engineering, University of Antwerp, Rodestraat 4, 2000 Antwerp (Belgium); Van den bergh, Wim, E-mail: wim.vandenbergh@uantwerpen.be [Faculty of Applied Engineering, University of Antwerp, Rodestraat 4, 2000 Antwerp (Belgium); Braet, Johan, E-mail: johan.braet@uantwerpen.be [Department Engineering Management, Faculty of Applied Economics, University of Antwerp, Prinsstraat 13, 2000 Antwerp (Belgium)

    2016-09-15

    This paper provides a critical review of different approaches applied in the Belgian asphalt sector in order to reduce the environmental impact of bituminous road construction works. The focus is on (1) reusing reclaimed asphalt pavement, (2) reducing the asphalt production temperature, and (3) prolonging the service life of the pavement. Environmental impact assessment of these methods is necessary to be able to compare these approaches and understand better the ability to reduce the environmental impact during the life cycle of the road pavement. Attention should be drawn to the possible shift in environmental impact between various life cycle stages, e.g., raw material production, asphalt production, or waste treatment. Life cycle assessment is necessary to adequately assess the environmental impact of these approaches over the entire service life of the bituminous pavement. The three approaches and their implementation in the road sector in Flanders (region in Belgium) are described and the main findings from life cycle assessment studies on these subjects are discussed. It was found from the review that using reclaimed asphalt pavement in new bituminous mixtures might yield significant environmental gains. The environmental impact of the application of warm mix asphalt technologies, on the other hand, depends on the technique used. - Highlights: • Recycling, lower production temperature and durability of asphalt are investigated. • The use of RAP in new asphalt mixtures yields significant environmental advantages. • It would be beneficial to allow RAP in asphalt mixtures for wearing courses. • The use of particular additives might counteract the environmental gain from WMA. • The service life and the environmental data source influence the LCA results.

  3. Crumb Rubber in cold recycled bituminous mixes

    DEFF Research Database (Denmark)

    Dondi, Giulio; Tataranni, Piergiorgio; Pettinari, Matteo

    2014-01-01

    Today recycling is one of the most innovative and interesting techniques for the rehabilitation of destressed road pavements. In recent years the increased interest in this process, has led to the development of various alternative methods for the recovery and the reuse of road bituminous materials....... Cold recycling is, among the recycling techniques, certainly the most studied and developed: it allows the recovering of bituminous material from an existing pavement without the addition of heat, whilst ensuring the creation of high quality bound base layers. A wide range of materials have been tested...

  4. Cold bituminous mixes

    OpenAIRE

    Delak, Boštjan

    2012-01-01

    Asphalt mix (short also asphalt) can be obtained from nature (natural asphalt) or produced technically (artificial asphalt), i. e. as a mix of bituminous binder, stone grain, and other additives that improve the asphalt properties. The beginnings of the use of asphalt can be traced from 6,000 to 4,000 BC since people back then knew some materials that contained bitumen as a binder. A more frequent use of the natural asphalt, however, starts around 3,000 BC. Different peoples used it primar...

  5. Aqueous radioactive waste bituminization

    International Nuclear Information System (INIS)

    Williamson, A.S.

    1980-08-01

    The bituminzation of decontamination and ion exchange resin stripping wastes with four grades of asphalt was investigated to determine the effects of asphalt type on the properties of the final products. All waste forms deformed readily under light loads indicating they would flow if not restrained. It was observed in all cases that product leaching rates increased as the hardness of the asphalt used to treat the waste increased. If bituminization is adopted for any Ontario Hydro aqueous radioactive wastes they should be treated with soft asphalt to obtain optimum leaching resistance and mechanical stability during interim storage should be provided by a corrosion resistant container

  6. Nonlinearity of bituminous mixtures

    Science.gov (United States)

    Mangiafico, S.; Babadopulos, L. F. A. L.; Sauzéat, C.; Di Benedetto, H.

    2018-02-01

    This paper presents an experimental characterization of the strain dependency of the complex modulus of bituminous mixtures for strain amplitude levels lower than about 110 μm/m. A series of strain amplitude sweep tests are performed at different temperatures (8, 10, 12 and 14°C) and frequencies (0.3, 1, 3 and 10 Hz), during which complex modulus is monitored. For each combination of temperature and frequency, four maximum strain amplitudes are targeted (50, 75, 100 and 110 μm/m). For each of them, two series of 50 loading cycles are applied, respectively at decreasing and increasing strain amplitudes. Before each decreasing strain sweep and after each increasing strain sweep, 5 cycles are performed at constant maximum targeted strain amplitude. Experimental results show that the behavior of the studied material is strain dependent. The norm of the complex modulus decreases and phase angle increases with strain amplitude. Results are presented in Black and Cole-Cole plots, where characteristic directions of nonlinearity can be identified. Both the effects of nonlinearity in terms of the complex modulus variation and of the direction of nonlinearity in Black space seem to validate the time-temperature superposition principle with the same shift factors as for linear viscoelasticity. The comparison between results obtained during increasing and decreasing strain sweeps suggests the existence of another phenomenon occurring during cyclic loading, which appears to systematically induce a decrease of the norm of the complex modulus and an increase of the phase angle, regardless of the type of the strain sweep (increasing or decreasing).

  7. Bituminization of liquid radioactive waste. Part 3

    International Nuclear Information System (INIS)

    G'oshev, G.S.; Gradev, G.D.; Stefanova, I.G.; Milusheva, A.G.; Guteva, E.S.; Stefanov, G.I.

    1991-01-01

    The elaborated technology for bituminization of liquid radioactive wastes (salt concentrates) is characterized by the fact that the bituminization process takes place in two stages: concentration of the liquid residue and evaporation of the water with simultaneous homogeneous incorporation of the salts in the melted bitumen. An experimental installation for bituminization of salt concentrates was designed on the basis of this technology. The experience accumulated during the design and construction of the installation for bituminization of salt concentrates could be used for designing and constructing an industrial installation for bituminization of the liquid residue of the nuclear power plants. 2 tabs., 3 figs., 3 refs

  8. Economy of bituminous coal hydrogenation

    Energy Technology Data Exchange (ETDEWEB)

    von Hochstetter, H.

    1944-05-11

    The influence of various factors on the production cost of (Janina) bituminous coal hydrogenation is analyzed briefly. The initial reckoning yielded a production cost of 188 marks per metric ton of gasoline and middle oils. The savings concomitant to changes of one percent in gasification, one percent in utilization of purified coal, one percent raising of space/time yield, one percent increase in throughput, one percent in coal concentration in the paste, and one percent in low temperature carbonization yield are listed. Factors affecting hydrogen consumption are listed in a table. Investigations showed the carbon-richest coal to produce a deviation in the effect of gasification upon the working costs by only 10 percent when compared with the Janina coal. Thus, the values listed were considered as guidelines for all kinds of bituminous coal. The calculations admitted the following conclusions: a maximum concentration of coal in the paste is desirable; one can assume a 2 percent reduction in the utilization with a 10 percent increase in throughput, as long as no changes in low temperature carbonization yield take place by changing the distribution in oil production; this configuration would change if the major concern were gas production instead of working costs, or if hydrogen production were the bottleneck. 1 table.

  9. 30 CFR 716.4 - Special bituminous coal mines.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Special bituminous coal mines. 716.4 Section... INTERIOR INITIAL PROGRAM REGULATIONS SPECIAL PERFORMANCE STANDARDS § 716.4 Special bituminous coal mines. (a) Definition. Special bituminous coal surface mines as used in this section means those bituminous...

  10. Leachability of bituminized radioactive waste. Literature survey

    International Nuclear Information System (INIS)

    Akimoto, Toshiyuki; Nakayama, Shinichi; Iida, Yoshihisa; Nagano, Tetsushi

    1999-02-01

    Bituminized radioactive waste that will be returned from COGEMA, France is planned to be disposed of in deep geologic repository in Japan. Data on leachability of radionuclides from bituminized waste are required for the performance assessment of the disposal. We made a literature survey on bitumen and bituminized radioactive waste, placing emphasis on leach tests and leach data in terms of geologic disposal. This survey revealed that reliable leach data on transuranium elements and data obtained under reducing conditions that is characteristic to deep underground are lacking. (author). 64 refs

  11. Cold weather paving requirements for bituminous concrete.

    Science.gov (United States)

    1973-01-01

    Cold weather paving specifications were developed from work by Corlew and Dickson, who used a computer solution to predict the cooling rate of bituminous concrete. Virginia had used a minimum atmospheric temperature as a criterion; however, it was ev...

  12. Pulp and paper plant wastes valorisation in bituminous mixes.

    Science.gov (United States)

    Modolo, R; Benta, A; Ferreira, V M; Machado, L M

    2010-04-01

    Nowadays, the increasing amount of wastes is a concerning reality and the environmental aspects has become a major priority. Following this worry, the purpose of this experimental study was to investigate the possibility of using pulp and paper inorganic wastes, named dregs and grits, in bituminous mixtures as aggregate replacement to reduce environmental effects of these wastes disposal. First, the wastes were chemically and physically characterized and also tested primarily taking into account the requirements for aggregates in bituminous mixtures. Then, formulations were prepared replacing aggregates with wastes in different amounts. The mechanical properties of these mixtures containing wastes were compared with reference samples based on standard methods. According to the results it was possible to verify that grits had a good performance and it might be directly tested industrially as an aggregate in road construction. On the other hand, dregs need to be treated before incorporation to guarantee stable mixes in terms of water sensitivity. Copyright 2009 Elsevier Ltd. All rights reserved.

  13. Development of bituminization process for radioactive wastes

    International Nuclear Information System (INIS)

    Segawa, Takeshi; Yamamoto, Masao; Miyao, Hidehiko; Mizuno, Ryukichi

    1973-01-01

    For the bituminization of radioactive wastes from a fuel reprocessing plant, the leachability, irradiation stability and burning property of bitumen products have been studied. Sodium nitrate was used for simulated evaporator concentrate, and mixed with distillation bitumen or blown bitumen; the sodium nitrate content in the mixture was 30 to 60 wt%. The distillation bitumen is superior to the blown bitumen in leachability and flash point, but inferior in the increase of volume by irradiation. Since the volume increase is not large, the distillation bitumen is satisfactory for the bituminization of the evaporator concentrate from a fuel reprocessing plant. (Mori, K.)

  14. Firing a sub-bituminous coal in pulverized coal boilers configured for bituminous coals

    Energy Technology Data Exchange (ETDEWEB)

    N. Spitz; R. Saveliev; M. Perelman; E. Korytni; B. Chudnovsky; A. Talanker; E. Bar-Ziv [Ben-Gurion University of the Negev, Beer-Sheva (Israel)

    2008-07-15

    It is important to adapt utility boilers to sub-bituminous coals to take advantage of their environmental benefits while limiting operation risks. We discuss the performance impact that Adaro, an Indonesian sub-bituminous coal with high moisture content, has on opposite-wall and tangentially-fired utility boilers which were designed for bituminous coals. Numerical simulations were made with GLACIER, a computational-fluid-dynamic code, to depict combustion behavior. The predictions were verified with full-scale test results. For analysis of the operational parameters for firing Adaro coal in both boilers, we used EXPERT system, an on-line supervision system developed by Israel Electric Corporation. It was concluded that firing Adaro coal, compared to a typical bituminous coal, lowers NOx and SO{sub 2} emissions, lowers LOI content and improves fouling behavior but can cause load limitation which impacts flexible operation. 21 refs., 7 figs., 3 tabs.

  15. Estimated Valuation of the Cost of Road Construction with the Use of Composite Cationic Bituminous Structures

    Directory of Open Access Journals (Sweden)

    Vorotynseva Anna

    2017-01-01

    Full Text Available The need for formation of prices for road construction works producing, by using composite of cationic bituminous structures, is dictated by absence of this type of work in estimate-normative base, due to the fact that this type of materials had never been used before. Estimated specifications could be used either for determination of work cost or for substantiation of efficiency of using new type of materials. This paper provides basic concepts, related to formation of estimate-normative base for determination of construction and installation works cost, particularly road construction works, also it shows formation of coating installation prices by using composite of cationic bituminous emulsions.

  16. Global market trade policy analysis for petroleum oils and oils obtained from bituminous minerals, crude

    Directory of Open Access Journals (Sweden)

    Bagheri, F.

    2012-01-01

    Full Text Available This article is based on surveying the custom tariffs imposed on the world export market of Petroleum Oils and Oils Obtained from Bituminous Minerals, Crude. We obtained the data according to the most updated available data provided online by UNCTAD and World Bank. The results indicate that none of the 142 countries in the world market of this product have imposed non-tariff trade barriers on the import of Petroleum Oils and Oils Obtained from Bituminous Minerals, Crude. The developed countries and the countries with transition economies are the main world import partners. European Union, United States, China, Japan, South Korea, Canada, Singapore, Taiwan, Thailand, South Africa, Australia, Turkey, Brazil, Sweden and Belarus are the examples and have imposed low custom tariffs on Petroleum Oils and Oils Obtained from Bituminous Minerals, Crude.

  17. Wetting of bituminized ion-exchangers under simulated repository conditions

    International Nuclear Information System (INIS)

    Aalto, H.; Valkiainen, M.

    2001-01-01

    According to the present plans the spent nuclear fuel from four Finnish nuclear power units will be transferred after interim storage to the final disposal site where it will be encapsulated and disposed of in a final repository constructed into the bedrock at a depth of 500 meters. Low and medium level waste generated at nuclear power plants will be finally disposed of in caverns constructed in the bedrock at the power plant site. The safety of the final disposal is based on a multibarrier concept and the degree of safety is estimated by using predictive models. The properties of the waste form are taken into account in the design of the repository construction. Bitumen has been chosen as an immobilisation agent for the wet wastes at Olkiluoto Power Plant, where two BWR units, TVO 1 and TVO 2, have separate bituminization facilities designed by Asea-Atom. Properties of bituminized spent ion-exchange resins from Olkiluoto power plant have been studied by VTT Chemical Technology since the late 70's. These studies have concentrated mainly on determining the long-term behaviour of the bituminization product under the repository conditions. Current interest lies on wetted product as a diffusion barrier. For this purpose a microscopic method for the visualisation of the structure of the wetted product has been developed. The equilibration of the samples in simulated concrete groundwater is currently going on at a temperature of 5-8 deg. C. Preliminary results are presented in this paper. Diffusion experiments have been planned for the further characterising of the wetted product as a release barrier for radionuclides including modelling. (author)

  18. Radioactive wastes bituminization by the pilot-plant equipment

    International Nuclear Information System (INIS)

    Golinsky, M.; Ferenc, M.; Ksendzak, Z.; Tikal, A.

    1978-01-01

    Operation experience of pilot-plant for bituminization of radioactive wastes by the method of hot mixing is described. The results obtained have conffirmed parameters of the process gained in laboratory conditions for asphalts D-35 and P-60. The results are stated for experiments of bituminization of still residuums obtained as a result of distillation of low and intermediate-level of activity sewage waters. Chemical composition of the still residuums and characteristics of the P-60 asphalt are given. Bituminization of crystal sodium nitrate and supersaturated solutions at 200 centigrades up to 30% contents of salt in the compound was performed. It is shown that bituminization results depend on salts composition of radioactive wastes subject to solidification. The results are described of investigations of bituminization by the method of hot mixing of still residuums of radioactive wastes containing sodium nitrates on the pilot-plant. Parameters are given of bituminization process and characteristics of compounds obtained in bituminization of still residuums in a form of concentrates. Leachind process for wastes solidificated by the method of bituminization has been investigated. Leaching rate for radionuclides incorporated into bituminization products depending on time of storage is given. Results of the spectrometric analysis of solidificated concentrates, bituminization product and gaseous products of radioactive wastes processing by the method of hot mixing are given. (I.T.) [ru

  19. Behaviour of bituminized radioactive wastes under irradiation

    International Nuclear Information System (INIS)

    Camaro, S.; Gilardi, T.; Vistoli, P.P.

    2000-01-01

    Studies are carried out by the CEA in order to predict the behaviour of bituminized radioactive wastes under self irradiation. Bitumen radiolysis produces gas (mainly H 2 ) which diffuses in the organic matrix. If the hydrogen yield is higher than the diffusion flux through the free surface, hydrogen concentration increases and exceeds its solubility in bitumen. Beyond saturation, bubbles are formed and gas is also evacuated by bubbles drift. The aim of these studies is to evaluate the evacuation capacity of radiolytic gas produced in function of initial bituminized wasteform characteristics. A model was developed to achieve this purpose, by calculating the evolution of bubbles population considering all elementary mechanisms of gas evacuation. (authors)

  20. Bituminization of liquid radioactive wastes. Part 1

    International Nuclear Information System (INIS)

    Gradev, G.D.; Ivanov, V.I.; Stefanova, I.G.; Milusheva, A.G.; Guteva, E.S.; Zhelyazkov, V.T.; Stefanov, G.I.; G'oshev, G.S.

    1991-01-01

    Salt-bitumen products are produced by the method of 'hot mixing' of some Bulgarian bitumens (road bitumen PB 66/99 and the hydroinsulating bitumen HB 80/25) and salts (chlorides, sulphates, borates, salt mixtures modelling the liquid waste from nuclear power plants) in different ratios to determine the optimum conditions for bituminization of liquid radioactive waste. The penetration, ductility and softening temperature were determined. The sedimentation properties and the thermal resistance of the various bitumen-salt mixtures were studied. The most suitable bitumen for technological research at the Kozloduy NPP was found to be the road bitumen PB 66/90 with softening temperature at 48 o C. The optimum amount of salts incorporated in the bitumen - about 45% - was found. No exothermal effects were observed in the bituminization process in the temperature range of up to 200 o C. The results obtained may be useful in the elaboration of a technology for bituminization of liquid radioactive wastes in the Kozloduy NPP. 4 tabs., 5 figs., 4 refs

  1. Bituminization of low- and medium-level radioactive wastes

    International Nuclear Information System (INIS)

    Lefillatre, G.

    1976-01-01

    French operations are presented concerning mainly: the bituminization of radioactive wastes produced in light water reactors; the direct bituminization of liquid effluents without concentration; the experiments carried out for 18 months on the land burial of concentrates solidified by bitumen into blocks of 100 liters. The knowledge acquired in France is exposed: in Valduc and in Saclay with facilities equipped with thin film evaporators and in Marcoule with the conditioning of trilaurylamine and tributyl-phosphate. At last the Cadarache bituminization [fr

  2. Study of stabilization/solidification processes (of solid porous wastes) based on hydraulic or bituminous binders; Etude des procedes de stabilisation/solidification (des dechets solides poreux) a base de liants hydrauliques ou de liants bitumineux

    Energy Technology Data Exchange (ETDEWEB)

    Sing-Teniere, Ch.

    1998-02-01

    The first part of this thesis presents the regulatory framework and the technical context linked with the study of stabilized/solidified wastes and with the evaluation of stabilization/solidification processes. A presentation of the two type of ultimate wastes under study (a used catalyst and an activated charcoal) and an analysis of the processes is given. The second part is devoted to the experimental characterization of both types of porous wastes. The third part deals with the processing of such wastes using an hydraulic binder. The study stresses on both on the stabilization/solidification efficiency of the process and on the conditions of its implementation. The same work is made for a process that uses a bituminous binder. Some choice criteria for the selection of the better process are deduced from the examination of the overall data collected. The waste characterization methodology is applied six times: two times for the raw wastes, two times for the same wastes processed with an hydraulic binder, and two times for the same wastes processed with a bituminous binder. (J.S.)

  3. Assessment of underground coal gasification in bituminous coals. Volume I. Executive summary. Final report

    Energy Technology Data Exchange (ETDEWEB)

    None

    1981-01-01

    This report describes the bituminous coal resources of the United States, identifies those resources which are potentially amenable to Underground Coal Gasification (UCG), identifies products and markets in the vicinity of selected target areas, identifies UCG concepts, describes the state of the art of UCG in bituminous coal, and presents three R and D programs for development of the technology to the point of commercial viability. Of the 670 billion tons of bituminous coal remaining in-place as identified by the National Coal Data System, 32.2 billion tons or 4.8% of the total are potentially amenable to UCG technology. The identified amenable resource was located in ten states: Alabama, Colorado, Illinois, Kentucky, New Mexico, Ohio, Oklahoma, Utah, Virginia, and West Virginia. The principal criteria which eliminated 87.3% of the resource was the minimum thickness (42 inches). Three R and D programs were developed using three different concepts at two different sites. Open Borehole, Hydraulic Fracture, and Electrolinking concepts were developed. The total program costs for each concept were not significantly different. The study concludes that much of the historical information based on UCG in bituminous coals is not usable due to the poor siting of the early field tests and a lack of adequate diagnostic equipment. This information gap requires that much of the early work be redone in view of the much improved understanding of the role of geology and hydrology in the process and the recent development of analytical tools and methods.

  4. Pretreatment of bituminous coal for hydrogenation

    Energy Technology Data Exchange (ETDEWEB)

    Hupfer, H.

    1943-03-29

    Bituminous coal became plastic at certain temperature ranges and swelled, causing plugging of preheater tubes. With few exceptions, this problem was encountered only when hydrogenating bituminous coal. This swelling often appeared in the coking of coals, and for the majority of the cases it was found that efforts to reduce the baking ability of bituminous coal also reduced the swelling of coal paste in the preheater tubes. Three methods of pretreatment to reduce swelling were preheating, oxidation (anoxidation), and sulfur treatment. The preheating by hot nitrogen at 250 atm for 3 hours showed no improvement in swelling characteristics, but produced a greater asphalt content and a lower amount of gasification. Absorption of oxygen was shown to increase the viscosity of the coal paste, while preheating in a vacuum showed no effects. Oxidation (anoxidation) increased the splitting and gasification and gave higher asphalt content. The baking ability of Saar coal could be destroyed by addition of 2.5% sulfur and heating for 1/sup 1///sub 2/ hours at 110/sup 0/C, in a stream of H/sub 2/S. The volatile content dropped significantly when the same coal was heated to 200/sup 0/ to 250/sup 0/C. When neutralized Saar coal was dried under a stream of H/sub 2/S, only slight deterioration of the yield was noted with equal degree of gasification. It was concluded that a more or less distinct improvement would be observed from the absorption of sulfur, but that residue processing would have to be altered to account for the sulfur content.

  5. Bituminization of radioactive wastes at the Nuclear Research Center Karlsruhe

    International Nuclear Information System (INIS)

    Hild, W.; Kluger, W.; Krause, H.

    1976-05-01

    A summary is given of the main operational experience gained at the Nuclear Research Center Karlsruhe in 4 years operation of the bituminization plant for evaporator concentrates from low- and medium level wastes. At the same time some of the essential results are compiled that have been obtained in the R + D activities on bituminization. (orig.) [de

  6. Response Modelling of Bitumen, Bituminous Mastic and Mortar

    NARCIS (Netherlands)

    Woldekidan, M.F.

    2011-01-01

    This research focuses on testing and modelling the viscoelastic response of bituminous binders. The main goal is to find an appropriate response model for bituminous binders. The desired model should allow implementation into numerical environments such as ABAQUS. On the basis of such numerical

  7. Simple volatility test for bituminous materials

    Energy Technology Data Exchange (ETDEWEB)

    Sharp, J.A.

    1980-04-01

    A simple, inexpensive test measuring the volatility or fuming propensity of bituminous materials with good repeatability has been devised. The test depends on measuring the mass loss which occurs when a small sample of the material is heated in a shallow open dish on a thermostatic hotplate for a fixed time. A rectilinear inverse relation between the mass losses and the softening points of a series of pitches from one source has been found, and the test has been shown to give results which correlate well with other methods for characterizing pitch volatility. Test results obtained with a range of tar products from pitches to creosotes all showed similarly good repeatability. (4 refs.)

  8. Rutting performance of cold bituminous emulsion mixtures

    Science.gov (United States)

    Arshad, Ahmad Kamil; Ali, Noor Azilatom; Shaffie, Ekarizan; Hashim, Wardati; Rahman, Zanariah Abd

    2017-10-01

    Cold Bituminous Emulsion Mixture (CBEM) is an environmentally friendly alternative to hot mix asphalt (HMA) for road surfacing, due to its low energy requirements. However, CBEM has generally been perceived to be less superior in performance, compared to HMA. This paper details a laboratory study on the rutting performance of CBEM. The main objective of this study is to determine the Marshall properties of CBEM and to evaluate the rutting performance. The effect of cement in CBEM was also evaluated in this study. The specimens were prepared using Marshall Mix Design Method and rutting performance was evaluated using the Asphalt Pavement Analyzer (APA). Marshall Properties were analysed to confirm compliance with the PWD Malaysia's specification requirements. The rutting performance for specimens with cement was also found to perform better than specimens without cement. It can be concluded that Cold Bituminous Emulsion Mixtures (CBEM) with cement is a viable alternative to Hot Mix Asphalt (HMA) as their Marshall Properties and performance obtained from this study meets the requirements of the specifications. It is recommended that further study be conducted on CBEM for other performance criteria such as moisture susceptibility and fatigue.

  9. Towards improved correlations between bitumen properties and rutting resistance of bituminous mixtures - FunDBitS literature review

    Science.gov (United States)

    Batista, Fátima A.; Hofko, Bernhard; De Visscher, Joëlle; Tanghe, Tine; da Costa, Margarida Sá

    2017-09-01

    Bitumen is the most common binder used in the production of bituminous mixtures for road paving, having a fundamental influence on the performance of the pavement. However, it is not yet fully understood which bitumen properties have a significant influence on the behaviour of bituminous mixtures. In this context, the FunDBitS project was developed. Its main objective was to prepare recommendations on the properties of the bitumen to be specified in order to obtain suitable bituminous mixtures, namely in what concerns to its resistance to permanent deformation (rutting), stiffness, low temperature cracking, fatigue cracking and binder/aggregate interaction. In this framework, the research studies that have become internationally available since the BiTVal project were reviewed in order to assess performance-based bitumen characteristics, which may be introduced into bitumen specification standards. This paper specifically presents the main conclusions regarding the properties of bitumen related to the behaviour to permanent deformation of bituminous mixtures. It was concluded that the most promising test is the “non-recoverable creep compliance” (Jnr) from the Multiple Stress Creep and Recovery (MSCR) test method, although Zero/Low Shear Viscosity (ZSV/LSV) by creep or oscillation test method can also give good correlations with permanent deformation of bituminous mixtures.

  10. Processing of bituminous coal tar at high temperature with bituminous coal additive

    Energy Technology Data Exchange (ETDEWEB)

    von Hartmann, G.B.; Hupfer, H.; Leonhardt, P.

    1943-05-10

    In short tests, results of the effects of a bituminous coal addition to the processing of tar and pitch were obtainable. Coal used was that from the Heinitz Mines (Upper Silesian), saturated with 1--1.2% iron sulphate. On a mixture of bituminous coal tar residue and tar oil, with a relatively low level of solids and asphalt, a substitution was made for the addition of 2% alkalized iron-grude-catalyst with 20% coal. The same yield was reached using a straight-run procedure. The coal gave somewhat more gasification and additional asphalt in the sludge without increasing the solids content correspondingly. In spite of this, the carbonization results were somewhat improved, which led one to conclude that the coal addition fostered the decomposition of the tar asphalt, and, that the asphalt from the coal could be better carbonized than that out of the tar. One found, also, that the tar mixture with coal additive permitted trouble-free hydrogenation to gasoline and middle oil. Still another short test met with success. A bituminous coal tar pitch containing 24% benzene solids and 36% asphalt, which could not be processed with iron catalyst or even molybdenum-grude, was hydrogenated to gasoline and middle oil with a usable yield of .25 by a 20--25% addition of coal. Here too, the carbonization results were good. The addition of coal had no notable influence on the properties of the resulting oils. The document included test procedures. 11 tables.

  11. Bituminization of radioactive wastes: safety problems and application fields

    International Nuclear Information System (INIS)

    Lefillatre, G.; Leconnetable, J.

    1975-01-01

    The bituminization of low and medium radioactive wastes has many advantages: volume and weight reduction; homogeneity of the solid obtained; good resistance to leaching (biological resistance to microorganisms, resistance to radiations); very favorable characteristics for transport and storage. The latest bituminization facility put into service at the CEA is that of the Saclay Center. The bituminization unit is located after a primary evaporator having a distillation capacity of 2m 3 /h. It enables the coating of effluents at the rate of 60l/h [fr

  12. Skid resistance of bituminous surfaces in Ohio

    Science.gov (United States)

    Colony, D. C.

    1984-03-01

    Statistical studies of skid number (SN) on the state highway system in Ohio reveal apparently systematic variations in distributions of SN among the twelve districts in the state. These variations appear to be significantly related to traffic and to geological characteristics of a given district. Regression calculations using traffic index, a function of ADT and age of the pavement surface in months, show a high correlation with SN, although standard errors of estimate were too large to make the equations useful for predicting SN from traffic variables. Similar results were obtained by elating SN to physiographic features in the state. Pavement surface type (bituminous or pcc) and coarse aggregate type (limestone, gravel or slag) are significantly related to SN.

  13. Effect of antistripping additives on the compaction of bituminous concrete.

    Science.gov (United States)

    1981-01-01

    The objective of this investigation was to determine the effect of antistripping additives on the compaction of bituminous concrete. To do this, the densities obtained on test sections with and without additive were compared. Comparisons of nuclear d...

  14. Long-term properties of bituminized waste products

    International Nuclear Information System (INIS)

    Snellman, M.; Valkiainen, M.

    1985-10-01

    This study is a survey of the factors of importance for long term behaviour of bituminized ion exchange resins. Phenomena occurring in bituminized waste products affected by the treatment, storage and disposal are identified. Test methods have been developed for characterizing product properties, which are important for the long-term behaviour. The long-term properties of bituminized ion-exchange resins are studied in a repository environment with access of water equilibrated with concrete. In these circumstances the most important properties are ralated to the interactions of bituminized waste with the surrounding barriers. The most important phenomena are water uptake due to rehydration of the resins and subsequent swelling of the product. (author)

  15. Long-term properties of bituminized waste products

    International Nuclear Information System (INIS)

    Snellman, M.; Valkiainen, M.

    1985-10-01

    This study is a survey of the factors of importance for the long term behaviour of bituminized ion exchange resins. Phenomena occurring in bituminized waste products affected by the treatment, storage and disposal are identified. Test methods have been developed for characterizing product properties, which are important for the long-term behaviour. The long-term properties of bituminized ion-exchange resins are studied in a repository environment with access of water equilibrated with concrete. In these circumstances the most important properties are related to the interactions of bituminized waste with the surrounding barriers. The most important phenomena are water uptake due to rehydration of the resins and subsequent swelling of the product

  16. Design of bituminous surface mixes with high skid resistance.

    Science.gov (United States)

    1974-01-01

    The Virginia Highway Research Council has proposed a study of the skid resistance of bituminous surfaces incorporating relatively hard and expensive aggregates. The hardness of the aggregates to be used aluminum oxide (Exolon) and calcined kaolin -- ...

  17. Design of bituminous mixes with high skid resistance.

    Science.gov (United States)

    1979-01-01

    Certain highway locations need exceptionally high skid resistance because of the alignment, geometry, and drainage of the roadway and the complex turning maneuvers required. Several beam specimens made of bituminous mixes incorporating unconventional...

  18. Bituminous and asphaltic membranes for radioactive waste repositories on land

    International Nuclear Information System (INIS)

    1988-03-01

    The aim of the study has been to identify, within generic designs for waste facilities, areas where bituminous materials might be incorporated as a barrier. The report is presented in three sections: Part I - The properties of bitumen are described, with particular reference to the long-term behaviour of the material. The durability of bitumen is discussed, including aspects such as ageing, microbial degradation, chemical resistance and radiation resistance. Part II -The use of bituminous materials in hydraulic engineering is outlined. Much of this section of the report concentrates on the use of bituminous materials in embankment dams and reservoir construction. A review of material technology and construction techniques is presented and a detailed assessment made of the performance of the materials in service. Part III - Generic trench type radioactive waste repository designs incorporating bituminous materials are presented. Material and construction specifications for the designs are detailed, and a performance assessment presented. (author)

  19. Estimated Valuation of the Cost of Road Construction with the Use of Composite Cationic Bituminous Structures

    OpenAIRE

    Vorotynseva Anna; Ovsiannikov Andrey; Bolgov Vladimir

    2017-01-01

    The need for formation of prices for road construction works producing, by using composite of cationic bituminous structures, is dictated by absence of this type of work in estimate-normative base, due to the fact that this type of materials had never been used before. Estimated specifications could be used either for determination of work cost or for substantiation of efficiency of using new type of materials. This paper provides basic concepts, related to formation of estimate-normative bas...

  20. Long-term behaviour of bituminized waste: modelling self-irradiation and leaching

    Energy Technology Data Exchange (ETDEWEB)

    Simondi-Teisseire, B.; Vistoli, P.P.; Libert, M.; Gilardi, T. [CEA Cadarache, Dept. de Physico-Chimie, DPC, 13 - Saint-Paul-lez-Durance (France); Chaix, P. [CEA Saclay, Dept. de Physico-Chimie, DPC, 91 - Gif-sur-Yvette (France); Blanc, V. [Cogema, 78 - Saint Quentin en Yvelines (France)

    2001-07-01

    During interim storage, the main evolution factor of bituminized wastes is radiolysis, due to self-irradiation. In deep disposal conditions, after site re-saturation and corrosion of the containers, the main evolution will be due to leaching. This paper deals with two models designed to describe respectively radiolytic gas evacuation (JACOB- 2) and bituminized waste leaching (COLONBO), and some of the typical results obtained from these two models. The first model describes radiolytic gas production, diffusive transport of gas, bubble nucleation and ripening and movement under buoyancy. The second one is based on descriptions of water sorption, solubilization, and diffusion into the matrix, water uptake by the most soluble salts leading to alteration of the matrix and finally to diffusive transport of the salts outside the bitumenisate. (author)

  1. Prediction of Marshall Parameters of Modified Bituminous Mixtures Using Artificial Intelligence Techniques

    Directory of Open Access Journals (Sweden)

    Sunil Khuntia

    2014-09-01

    Full Text Available This study presents the application of artificial neural networks (ANN and least square support vector machine (LS-SVM for prediction of Marshall parameters obtained from Marshall tests for waste polyethylene (PE modified bituminous mixtures. Waste polyethylene in the form of fibres processed from utilized milk packets has been used to modify the bituminous mixes in order to improve their engineering properties. Marshall tests were carried out on mix specimens with variations in polyethylene and bitumen contents. It has been observed that the addition of waste polyethylene results in the improvement of Marshall characteristics such as stability, flow value and air voids, used to evaluate a bituminous mix. The proposed neural network (NN model uses the quantities of ingredients used for preparation of Marshall specimens such as polyethylene, bitumen and aggregate in order to predict the Marshall stability, flow value and air voids obtained from the tests. Out of two techniques used, the NN based model is found to be compact, reliable and predictable when compared with LS-SVM model. A sensitivity analysis has been performed to identify the importance of the parameters considered.

  2. Adhesion Promoters in Bituminous Road Materials: A Review

    Directory of Open Access Journals (Sweden)

    Cesare Oliviero Rossi

    2017-05-01

    Full Text Available This review focuses on certain classes of organic compounds known variously in the specific literature of asphalt as adhesion promoters, antistripping agents, wetting agents, antistrips, or adhesion agents. These kinds of organic additives are currently formulated to enhance the bitumen coating of mineral aggregates and improve the workability of asphalt mixtures. In this review, the term “adhesion promoters” includes both synthetic organic compounds as well as those extracted from natural resources, mixed in trace amounts to bitumen. Their main role is to alter the interfacial energy, so that the presence of water, even in trace, does not weaken the bitumen-aggregate bond and tends to favor adhesion. The report also considers the chemical functionalities that play a predominant role in bonding, as well as the effects of surface modification of the aggregate due to the presence of adhesion promoters in pre-blended bituminous mixtures. Although bitumen is widely used in road pavement construction and the discussion is mainly addressed to the improvement of adhesion in road materials, adhesion and wetting properties can also represent a general issue in various bitumen-based industrial products.

  3. Measurement of heat generation from simulated bituminized product

    Energy Technology Data Exchange (ETDEWEB)

    Kato, Yoshiyuki; Yoneya, Masayuki [TRP Safety Evaluation and Analysis team, Japan Nuclear Cycle Development Inst., Tokai, Ibaraki (Japan)

    1999-09-01

    The fire and explosion incident occurred at Bituminization Demonstration Facility of PNC Tokai Works on March 11, 1997. In order to ascertain the cause of incident, the investigation has been pushed forward. For the investigation, we prepared simulated bituminized product of measurement of heat generation in low temperature region less than 200degC. We used calvet Calorimeter MS80 for the heat generation measurement. Result of measurement, we were able to catch the feeble heat generation from bituminized product. The maximum calorific value that was able to detect it in isothermal measurement was approximately 1 mW/g in 160degC. It was approximately 2 mW/g in 200degC. And, as the another measurement, the measurement condition went heat rate by 0.01degC/minute, the highest temperature 190degC. As a result, the maximum generation of heat value that was able to detect it was approximately 0.5 mW/g. I changed simulated bituminized products and measured these. A difference of condition is salt particle size, salt content rate (45%, 60%), addition of the simulated precipitate. But there was not a difference in the generation of heat characteristic detected. (author)

  4. Reuse of steel slag in bituminous paving mixtures.

    Science.gov (United States)

    Sorlini, Sabrina; Sanzeni, Alex; Rondi, Luca

    2012-03-30

    This paper presents a comprehensive study to evaluate the mechanical properties and environmental suitability of electric arc furnace (EAF) steel slag in bituminous paving mixtures. A variety of tests were executed on samples of EAF slag to characterize the physical, geometrical, mechanical and chemical properties as required by UNI EN specifications, focusing additionally on the volumetric expansion associated with hydration of free CaO and MgO. Five bituminous mixtures of aggregates for flexible road pavement were designed containing up to 40% of EAF slag and were tested to determine Marshall stability and indirect tensile strength. The leaching behaviour of slag samples and bituminous mixtures was evaluated according to the UNI EN leaching test. The tested slag showed satisfactory physical and mechanical properties and a release of pollutants generally below the limits set by the Italian code. Tests on volume stability of fresh materials confirmed that a period of 2-3 months is necessary to reduce effects of oxides hydration. The results of tests performed on bituminous mixtures with EAF slag were comparable with the performance of mixtures containing natural aggregates and the leaching tests provided satisfactory results. Copyright © 2012 Elsevier B.V. All rights reserved.

  5. Biowaste utilization in the process of co-gasification with bituminous coal and lignite

    International Nuclear Information System (INIS)

    Howaniec, Natalia; Smoliński, Adam

    2017-01-01

    Biowaste utilization in co-gasification with bituminous coal and lignite gives the benefits of stable supplies of a primary energy source – coal and utilization of a zero-emission, waste material (i.e. agriculture waste, sewage sludge, etc.) with higher process efficiency and lower negative environmental impact than biomass or coal gasification, respectively. The main focus of the study presented is co-gasification of bituminous coal or lignite with biowaste to hydrogen-rich gas. The experiments were performed in the laboratory scale fixed-bed reactor installation at 700 and 900 °C. The Hierarchical Clustering Analysis complemented with a color map of studied data were applied in the selection of the optimal operating parameters for biowaste utilization in the co-gasification process based on the experimental data of gasification/co-gasification process as well as physical and chemical properties of fuels tested. The experimental results showed that the carbon conversion rate in co-gasification increased with increasing biomass content in a fuel. The total gas volume and hydrogen volume in co-gasification were higher than the values expected based on the results of the gasification process of the fuels analyzed. - Highlights: • Biowaste co-gasification with bituminous coal/lignite to hydrogen-rich gas. • Steam co-gasification in laboratory scale fixed-bed reactor at 700 and 900 °C. • Hierarchical Clustering Analysis complemented with color map of experimental data. • Carbon conversion increase with increasing biomass content. • The highest total gas and hydrogen volume in co-gasification of C-B20 blend at 900C.

  6. Surface Properties of Photo-Oxidized Bituminous Coals: Final report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-09-01

    Natural weathering has a detrimental effect on the hydrophobic nature of coal, which in turn can influence clean-coal recovery during flotation. Few techniques are available that can establish the quality of coal surfaces and that have a short analysis time to provide input for process control. Luminescence emissions which can be quantified with an optical microscope and photometer system, are measurably influenced by degree of weathering as well as by mild storage deterioration. In addition, it has been shown that when vitrinite is irradiated with a relatively high intensity flux of violet- or ultraviolet- light in the presence of air, photo-oxidation of the surface occurs. The combination of measuring the change in luminescence emission intensity with degree of surface oxidation provided the impetus for the current investigation. The principal aim of this research was to determine whether clear correlations could be established among surface oxygen functionality, hydrophobicity induced by photo-oxidation, and measurements of luminescence intensity and alteration. If successful, the project would result in quantitative luminescence techniques based on optical microscopy that would provide a measure of the changes in surface properties as a function of oxidation and relate them to coal cleanability. Two analytical techniques were designed to achieve these goals. Polished surfaces of vitrain bands or a narrow size fraction of powdered vitrain concentrates were photo-oxidized using violet or ultraviolet light fluxes and then changes in surface properties and chemistry were measured using a variety of near-surface analytical techniques. Results from this investigation demonstrate that quantitative luminescence intensity measurements can be performed on fracture surfaces of bituminous rank coals (vitrains) and that the data obtained do reveal significant variations depending upon the level of surface oxidation. Photo-oxidation induced by violet or ultraviolet light

  7. Properties of bituminization product from Olkiluoto power plant

    International Nuclear Information System (INIS)

    Valkiainen, M.; Vuorinen, U.

    1985-09-01

    In Finland, disposal into repositories excavated into bedrock on the present power plant sites is considered to be the most feasible alternative for the low- and intermediate level wastes. The Nuclear Waste Commission of the Finnish power companies has sponsored mainly experimental research work on long-term properties of bituminized ion exchange resin performed in the Reactor Laboratory of the Technical Research Centre of Finland since 1981. This report presents results on follow-up measurements of the leach tests started in 1981 and results on new leach tests with cement equilibrated water. Swelling of the bituminization product caused by water uptake is considered important. Both unrestricted and restricted swelling measurements were performed and are reported here. In addition to leaching and swelling also radiolytic gas generation and pH-changes of the leachant are discussed

  8. Solidification of radioactive wastes by bituminization technology. II

    International Nuclear Information System (INIS)

    Stuchlik, S.; Brzobohaty, J.

    1985-01-01

    The bituminization line consists of a rotor film evaporator, a condenser, reserve tanks of bitumen emulsion and model concentrates, a roller train, a vapour concentrate tank, a control console, a bitumen emulsion pump, a model concentrates pump, and a tank for model concentrate preparation. Anion-active emulsion Silembit S-60 produced by Paramo Pardubice was chosen as the bitumen emulsion. A block diagram is given of the experimental bituminization line and its processing is described of model nonactive concentrates whose composition corresponds to that of actual wastes from the V-1 nuclear power plant. Successful tests of the line showed that it could be used for the disposal of radioactive wastes. (E.S.)

  9. Comparison of the performances of several modified bituminous mix formulas

    Science.gov (United States)

    Saoula, Samia; Haddadi, Smail; Mokhtar, Khedidja Ait

    2012-09-01

    The mechanical behaviour of several formulas of bituminous concrete containing polymer (HDPE), polymer-bitumens (EVA) and waste of sole of shoes (containing copolymer butadiene-styrene-SBR noted DSBR and ethylene and vinyl acetate-EVA noted DEVA) were studied. The aim of this work is to improvement of the poor mechanicals performances of a bituminous concrete formula (0/14) which isn't conforming to the Algerian standards. Also, the mechanical tests showed that the permanent deformations and the indirect tensile strength at the temperatures of service resistances are improved. At high-temperature service, formulas of asphalt bitumen-EVA most resistant against the average temperature in service, it mixes made with waste are best resistant. All the formulas have a good behaviour with water.

  10. Nigerian bituminous coal as a fuel-coal. | OGUGBUAJA | Global ...

    African Journals Online (AJOL)

    Nigerian bituminous coal as a fuel-coal. V O OGUGBUAJA, C L NDIOKWERE, G A DIMARI. http://dx.doi.org/10.4314/gjpas.v6i2.16113 · AJOL African Journals Online. HOW TO USE AJOL... for Researchers · for Librarians · for Authors · FAQ's · More about AJOL · AJOL's Partners · Terms and Conditions of Use · Contact AJOL ...

  11. Identification of aggregates for Tennessee bituminous surface courses

    Science.gov (United States)

    Sauter, Heather Jean

    Tennessee road construction is a major venue for federal and state spending. Tax dollars each year go to the maintenance and construction of roads. One aspect of highway construction that affects the public is the safety of its state roads. There are many factors that affect the safety of a given road. One factor that was focused on in this research was the polish resistance capabilities of aggregates. Several pre-evaluation methods have been used in the laboratory to predict what will happen in a field situation. A new pre-evaluation method was invented that utilized AASHTO T 304 procedure upscaled to accommodate surface bituminous aggregates. This new method, called the Tennessee Terminal Textural Condition Method (T3CM), was approved by Tennessee Department of Transportation to be used as a pre-evaluation method on bituminous surface courses. It was proven to be operator insensitive, repeatable, and an accurate indication of particle shape and texture. Further research was needed to correlate pre-evaluation methods to the current field method, ASTM E 274-85 Locked Wheel Skid Trailer. In this research, twenty-five in-place bituminous projects and eight source evaluations were investigated. The information gathered would further validate the T3CM and find the pre-evaluation method that best predicted the field method. In addition, new sources of aggregates for bituminous surface courses were revealed. The results of this research have shown T3CM to be highly repeatable with an overall coefficient of variation of 0.26% for an eight sample repeatability test. It was the best correlated pre-evaluation method with the locked wheel skid trailer method giving an R2 value of 0.3946 and a Pearson coefficient of 0.710. Being able to predict field performance of aggregates prior to construction is a powerful tool capable of saving time, money, labor, and possibly lives.

  12. Gamma radiation hazard to miners in bituminous coal mines

    International Nuclear Information System (INIS)

    Skubacz, K.

    1986-01-01

    Radiation hazard to miners working in 16 bituminous coal mines was determined by a thermoluminescence method. While the miners exposure to gamma radiation is higher than that of the general population, the yearly dose was never found to exceed 5 mSv in any investigated person. Factors contributing to the estimate of the exposure hazard and the need for individual dose monitoring in mines are discussed in more detail. 3 refs., 4 figs. (author)

  13. An experimental evaluation of coke production from bituminous coal tar

    Energy Technology Data Exchange (ETDEWEB)

    Kaloc, M.; Janik, M.; Rojak, A.

    1981-01-01

    Results of studies of laboratory coking of bituminous coal tar are presented, which verify the technical feasibility and suitability of this engineering process for coke production. Thanks to the closed-system character of the process, it is suitable for technological and hygienic reasons. The yield of pitch coke is higher by comparison with that from chamber coking; also the properties of this coke are better; it is suitable for more varied applications, including the production of large-diameter graphite electrodes.

  14. Biodegradation of bituminous products from processing liquid radioactive wastes

    International Nuclear Information System (INIS)

    Tibensky, L.; Krejci, F.; Hladky, E.; Halama, D.

    1988-01-01

    One of the possible ways of disturbing the stability of bituminous products from liquid radioactive waste processing, is biodegradation caused by common microorganisms. Pseudomonas bacteria and a Bacillus cereus culture were selected for experimental study of cultivation of microorganisms. Experiments with mixed cultures were also performed. Pitches, ajatin and imidazoline were used as inhibitors. The thin layer and the emulsion methods were used in assessing biological corrosion. The results of the experiments are discussed with respect to the dependence of bacterial growth on bitumen biodegradation, the effect of pH on bitumen degradation and the effect of inhibitors on bitumen biodegradation. The salts contained in bituminous products were not found to significantly affect the rate of destruction. The degree of degradation was found to mainly depend on the bitumen, its chemical composition, and on the conditions of storage. It was also found that inhibitor additions in some cases modified the properties of the matrix such that it became more liquid. The coefficient of extractibility thus increased of matrix salts. The recultivation of bacteria on a full-value medium resulted in the loss of the inhibitory effect. In some cases, the inhibitor even stimulated the growth of microorganisms. The use of inhibitors in an effort to achieve biostability of bituminous products thus did not solve the problem. (Z.M.). 2 tabs., 9 refs

  15. Low NOx firing systems for bituminous coal and lignite

    International Nuclear Information System (INIS)

    Knyrim, W.; Scheffknecht, G.

    1997-01-01

    In the case of lignite fluidized boilers the denitrification down to less than 200 mg/m 3 was possible with primary measures on the firing side only. On account of the excellent results achieved with the reconstructed plants the firing systems for the new generation of brown coal fire steam generators with a capacity of 800 MW and more is designed in a similar way. For bituminous coal fire steam generators the primary measures on the firing side are nor sufficient to keep the German NO x emission limit. Therefore these units had to be retrofitted with a SCR-DENOX plant. The experience with the new firing system made in a 110 MW steam generator in Austria with a wide range of fuels is introduced. One of the largest bituminous coal fired once-trough steam generator built by EVT is the boiler for the power station Bexbach I (750 MW). The firing system is designed as a tangential firing system with 32 jet burners. These are arranged in pairs in the corners and divided into 4 burner levels with 4 burner pairs each. One mill is allocated to each burner level. An important characteristic feature is that the four bowl mills are arranged on one side of the steam generator. The plant is constructed with upper air nozzles which are arranged above the top burner level for the reduced of nitrogen oxides. During tests at steam generator with similar design, the nO x formation could be reduced from 750 to 500 mg/m 3 s.t.p. (dry, 6% O 2 ) with an addition of upper air of 20% at 100% unit capacity and constant total flow. As a main approach for the further reduction of the primary NO x emission at bituminous coal fired steam generators with tangential firing systems, the experience gained from the firing of brown coal has also been taken into account. A fundamental aspect in this respect was the vertical air staging in the direction of the furnace height. The results of many tests in a test reactor have shown that the differences of the achievable NO x values of brown and

  16. Pretreatment of bituminous coal for hydrogenation (older experiments)

    Energy Technology Data Exchange (ETDEWEB)

    Hupfer, H.

    1943-03-29

    The tendency for coal paste to become plastic inside a certain temperature range, which sometimes caused plugging in the preheater tubes, was observed only in bituminous coal. This phenomenon, called swelling, was seen as parallel to the increase in volume of the coal in coking or carbonization, which had been observed with melting bituminous coal. Although the parallel did not hold for all cases, the frequent simultaneous occurrence of the two phenomena suggested the possibility that those treatments of coal which reduced its baking ability would also improve its behavior in the preheater. Unequivocal results were not obtained, but certain predictions could be made about a pretreatment of coal for hydrogenation. (1) With preheating, no influence with regard to pressure plugging was detected in Brassert coal, although Saar coal Louisenthal, preheated, produced a better asphalt content and lower gasification experimentally. (2) Change in coal due to anoxidation increased the viscosity of the coal paste, while preheating in vacuum had no effect. (3) The baking ability of Saar coal could be destroyed by a sulfur treatment, without appreciably diminishing the volatile content. In general, a distinct improvement was observed with the absorption of sulfur.

  17. Co-pyrolysis characteristic of biomass and bituminous coal.

    Science.gov (United States)

    Li, Shuaidan; Chen, Xueli; Liu, Aibin; Wang, Li; Yu, Guangsuo

    2015-03-01

    Co-pyrolysis characteristics of biomass and bituminous coal have been studied in this work. The temperature was up to 900°C with the heating rates of 10, 15, 20, 25 and 30°C/min. Rice straw, saw dust, microcrystalline cellulose, lignin and Shenfu bituminous coal were chosen as samples. Six different biomass ratios were used. The individual thermal behavior of each sample was obtained. The experimental weight fractions of the blended samples and the calculated values were compared. The results show that the weight fractions of the blended samples behave differently with calculated ones during the co-pyrolysis process. With the increasing biomass ratio, relative deviations between experimental weight fractions and calculated ones are larger. H/C molar ratio, heat transfer properties of biomass would affect to the interaction between biomass and coal. The maximum degradation rates are slower than the calculated ones. The activation energy distributions also changed by adding some biomass into coal. Copyright © 2014 Elsevier Ltd. All rights reserved.

  18. Natural radioactivity associated with bituminous coal mining in Nigeria

    International Nuclear Information System (INIS)

    Balogun, F.A.; Mokobia, C.E.; Fasasi, M.K.; Ogundare, F.O.

    2003-01-01

    Gamma spectroscopic method was used to determine the natural radioactivity associated with the mining of Nigerian bituminous coal for the purpose of determining the radiological implications of coal mining in the country. The activity concentrations of the radionuclides detected range from 0.20±0.002 to 48.42±5.32 Bq kg -1 . The overall natural radionuclide contribution to the radioactivity of the environment was found to be 404.16±23.44 Bq kg -1 . Of this, coal waste (tailing) alone contributed 49.5% representing the largest contribution. Coal contributed just 5.5%. A comparison of the concentrations obtained in this work for coal with those from other parts of the world indicates that the radioactivity content of the Nigerian bituminous coal is not significantly different. The outdoor and indoor exposure rates in air 1 m above the ground are estimated to be (6.31±1.20)x10 -8 and (7.57±1.20) x10 -8 Gy h -1 , respectively, for the mining environment. These values compare very well with the global values reported by UNSCEAR: 5x10 -8 and 6x10 -8 Gy h -1 , respectively. The resulting annual effective dose equivalent estimated is (4.49±0.74)x10 -4 Sv yr -1 . This also compares favourably with the global value -4x10 -4 Sv yr -1 , reported by UNSCEAR

  19. Using proximate analysis to characterize airborne dust generation from bituminous coals

    Energy Technology Data Exchange (ETDEWEB)

    Page, S.J.; Organiscak, J.A. [NIOSH, Pittsburgh, PA (United States). Pittsburgh Research Lab.

    2002-06-01

    Laboratory crushing experiments were conducted on a range of low to high volatile bituminous coals to investigate the various factors influencing airborne respirable dust generation. Bituminous coal samples from 8 mines (5 U.S. and 3 Polish) were uniformly prepared and processed through a double roll crusher located in a low air velocity wind tunnel. Experimental factors studied included inherent coal seam constituents, specific energy of crushing, product size characteristics, dust cloud electrostatic field, and specific quantity of airborne respirable dust generated. A combination of factors is associated with the generation of airborne respirable dust. One factor involved is the effect of coal rank, described by the inherent moist fuel ratio, on the product size characteristics. However, since coals of high moist fuel ratio (high rank) are generally more extensively cleated, it is suggested that the degree of cleating is directly responsible for the quantity of respirable-sized particles produced in the crushed product material for eastern U.S. coals. This is implied by the relationship of ash content and at least one mineral constituent (pyrite, determined from pyritic sulfur analysis) to the percentage of airborne respirable dust. A clear delineation of coals, based on well-known proximate analysis characteristics, that generate the most respirable dust appears to be possible. It was also shown that the dust-generating characteristics of coals could be reasonably described by both the moist fuel ratio and the Hardgrove Grindability Index (HGI). These results show a clear distinction between eastern and western U.S. coals. However, no consistent distinction for Polish coal was observed.

  20. Study of thermal reactivity during bituminization of radioactive waste

    International Nuclear Information System (INIS)

    Mouffe, Sh.

    2004-10-01

    This work deals with the study of chemical reactions and phases transitions which can occur between magnesium nitrate, sodium nitrate, cobalt sulphur product, and nickel potassium ferrocyanide, when they are heated together during bituminization process of nuclear waste. The applied methodology associates a few techniques: temperature, enthalpy, and kinetics of reaction are determined by calorimetry, reaction products are characterised by chemical analyses, mass spectrometry and XRD analysis. Three fields of temperature and energy are observed in function of composition (one compound or a mixture of compounds). The study of reactions between NaNO 3 and cobalt sulphur product shows that the presence of water has got an effect on reaction temperature. The study of Mg(NO 3 ) 2 , 6 H 2 O and CoS shows an overlapping of different signals, and that the reaction rate is very slow (a few hours). (author)

  1. Environmental problems caused by bituminous schist and possible solutions

    International Nuclear Information System (INIS)

    Elmas, N.; Aykul, H.; Erarslan, K.; Ediz, I.G.

    1998-01-01

    Schist, as a disposal of mine, has harmful effects on environment. however, several manners can be utilized to prevent the environmental destruction as well as an economical benefit is gained. In this study, environmental problems caused by bituminous schist and other disposals have been investigated on a specific lignite coal mine where schist is disposed as waste material. Pollution and damage on land and in water sources around the coal district and the villages have been observed, recorded and several solutions to environmental problems have been proposed. Discussed proposals will not only solve the environmental pollution problem but also provide waste management facility. Industrial structure of the district enables such a disposal to be used as an economical raw material. Besides, general effects of the coal mine and the power plant nearby have been discussed from environmental point of view, too. 7 refs

  2. Optimization of the encapsulation process of bituminized radioactive wastes

    International Nuclear Information System (INIS)

    Silva, Jarine E.C.; Tello, Clédola C.O.

    2017-01-01

    The objective of this paper is to propose alternatives for the deposition of bituminized waste in metallic packages coated with a cementitious matrix for surface repository, aiming to meet the standards criteria and increasing the integrity of the metallic packaging during the planned storage time, transportation and disposal. For this purpose, tests will be carried out to evaluate cement pastes and mortar with cementitious additives, aiming at the durability and reduction of pores. Leaching tests with different thicknesses will also be carried out, where optimization of the encapsulation can meet safety, durability and economy standards for the repository, as well as practices that contribute to reduce environmental impacts and the economic burden imposed on future generations

  3. Application of infrared camera to bituminous concrete pavements: measuring vehicle

    Science.gov (United States)

    Janků, Michal; Stryk, Josef

    2017-09-01

    Infrared thermography (IR) has been used for decades in certain fields. However, the technological level of advancement of measuring devices has not been sufficient for some applications. Over the recent years, good quality thermal cameras with high resolution and very high thermal sensitivity have started to appear on the market. The development in the field of measuring technologies allowed the use of infrared thermography in new fields and for larger number of users. This article describes the research in progress in Transport Research Centre with a focus on the use of infrared thermography for diagnostics of bituminous road pavements. A measuring vehicle, equipped with a thermal camera, digital camera and GPS sensor, was designed for the diagnostics of pavements. New, highly sensitive, thermal cameras allow to measure very small temperature differences from the moving vehicle. This study shows the potential of a high-speed inspection without lane closures while using IR thermography.

  4. Determination of bitumen and rubber content in bituminous mixes containing crumb tyre rubber; Determinacion del contenido de betum y de caucho en las mezclas bituminosas que incorporan plvo de caucho procedente de neumaticos fuera de uso

    Energy Technology Data Exchange (ETDEWEB)

    Rubio Guzamn, B.; Jimenez Saez, R.

    2009-07-01

    In recent years the use of crumb rubber from scrap tyres as a component of hot bituminous mixes for road construction, has been officially promoted by the Public Administration in Spain, by issuing several publications of both informative and normative nature, aimed to spread knowledge and experiences on the subject and also to specify the requirement and regulate the working applications for this material. However, it also seems necessary to develop new test methods which, allows control of the rubber content in crumb rubber-added mixes, regardless of the process (wet or dry) followed for the mix production. This article describes a procedure reliable enough to determine both the soluble bituminous binder and the rubber contents in bituminous mixes based on two combined, previously standardized test methods: binder extraction with solvent and ignition. (Author) 7 refs.

  5. Influence of association of "EVA-NBR" on indirect tensile strength of modified bituminous concrete

    Science.gov (United States)

    Chinoun, M.; Soudani, K.; Haddadi, S.

    2016-04-01

    The aim of this work is to contribute to the improvement of the mechanical properties of bituminous concrete by modification of bituminous concrete. In this study, we present the results of the indirect tensile strength "ITS" of modified bituminous concrete by the combination of two modifiers, one is a plastomer EVA (Ethylene Vinyl Acetate) and the other is a industrial waste from the shoe soles grinding NBR (Nitrile Butadiene Rubber) as crumb rubber. To modify the bitumen a wet process was used. The results show that the modification of bitumen by EVA-NBR combination increases their resistance to the indirect traction "ITS" compared to the bituminous concrete control. The mixture of 5% [50% EVA+ 50% NBR] is given the best result among the other associations.

  6. State of the art report on bituminized waste forms of radioactive wastes

    International Nuclear Information System (INIS)

    Kim, Tae Kook; Shon, Jong Sik; Kim, Kil Jeong; Lee, Kang Moo; Jung, In Ha

    1998-03-01

    In this report, research and development results on the bituminization of radioactive wastes are closely reviewed, especially those regarding waste treatment technologies, waste solidifying procedures and the characteristics of asphalt and solidified forms. A new concept of the bituminization method is suggested in this report which can improve the characteristics of solidified forms. Stable solid forms with high leach resistance, high thermal resistance and good compression strength were produced by the suggested bituminization method, in which spent polyethylene from agricultural farms was added. This report can help further research and development of improved bituminized forms of radioactive wastes that will maintain long term stabilities in disposal sites. (author). 59 refs., 19 tabs., 18 figs

  7. A new radiometric instrument designed to measure the parameters of bituminous coal on transport belts

    International Nuclear Information System (INIS)

    Kubicek, P.

    1993-01-01

    A new radiometric instrument developed in Czechoslovakia, for the measurement of ash content of bituminous coal, and for the determination of approximate values of moisture and weight is described. (Author)

  8. Investigation on Using SBS and Active Carbon Filler to Reduce the VOC Emission from Bituminous Materials

    OpenAIRE

    Cui, Peiqiang; Wu, Shaopeng; Li, Fuzhou; Xiao, Yue; Zhang, Honghua

    2014-01-01

    Bituminous materials are playing a vital role in pavement design and the roofing industry because of outstanding properties. Unfortunately, bituminous materials will release volatile organic compounds (VOC), making them non-environmentally friendly. Therefore, technologies that can be used to decrease the VOC emission are urgently required. In this research, the VOC emission and material behaviors were analyzed and compared to investigate the possibility of adding styrene butadiene styrene (S...

  9. Effect of transesterification degree and post-treatment on the in-service performance of NCO-functionalized vegetable oil bituminous products

    OpenAIRE

    Cuadri Vega, Antonio Abad; García Morales, Moisés; Navarro Domínguez, Francisco Javier; Partal López, Pedro

    2014-01-01

    The bitumen modification through polyurethane prepolymers presents significant benefits for the manufacture of bituminous products for the paving industry. In this sense, this work explores the use, as bitumen modifier, of a novel reactive prepolymer synthesized by reaction of 4,4´,diphenylmethane diisocyanate (MDI) and a vegetable oil-based polyol, castor oil (CO), previously transesterified with pentaerythritol. On the one hand, thermal analysis on transesterified CO revealed a highly stabl...

  10. Investigation and analytical results of bituminized products in drums at filing room

    International Nuclear Information System (INIS)

    Shibata, Atsuhiro; Kato, Yoshiyuki; Sano, Yuichi; Kitajima, Takafumi; Fujita, Hideto

    1999-09-01

    This report describes the results of investigation of the bituminized products in drums, liquid waste in the receiving tank V21 and the bituminized mixture in the extruder. The investigation of the products in drums showed most of the unburned products filled after 28B had abnormality, such as hardened surfaces, caves and porous brittle products. The particle sizes of the salt fixed in bituminized products depended neither on batch number nor on feed rate. It indicates the fining of the salt particle caused by the decreased feed rate did not occur. The measured concentrations of metals and anions in the bituminized products showed no abnormality. The catalytic content was not recognized in the products. The infrared absorption spectra obtained with the bituminized products show the oxidation at the incident occurred without oxygen. There was no organic phase on the surface of liquid waste in V21. Chemical analysis and thermal analysis on the precipitate in V21 showed no abnormality. Concentration of sodium nitrate/nitrite in the mixture collected from the extruder was lower than normal products. These results show no chemical activation of the bituminized products. It can be concluded that the chemical characteristics of the products had little abnormality even around the incident. (author)

  11. Bituminous reference document: synthesis of knowledge on the long time behavior of bituminous packages; Dossier de reference bitume: synthese des connaissances sur le comportement a long terme des colis bitumes

    Energy Technology Data Exchange (ETDEWEB)

    Sercombe, J.; Adenot, F.; Vistoli, P.P.; Parraud, S.; Riglet-Martial, C.; Gwinner, B.; Felines, I.; Tiffreau, C.; Libert, M

    2004-07-01

    This document is a synthesis of the knowledge acquired at the CEA on the behavior of bituminous packages. In this framework, the CEA studied bituminous packages in generic conditions of a package lifetime. The main factors, the evolution mechanisms and influential parameters have been determined and quantitative s simulation have been developed. After a description of the main initial bituminous packages characterizations, the evolutions in saturated and un-saturated environment are exposed. (A.L.B.)

  12. Development of bituminous coal chambers with respect to throughput

    Energy Technology Data Exchange (ETDEWEB)

    Schappert, H.

    1942-10-17

    This short report compared three coal liquefaction plants in Germany which operated principally on bituminous coal and which had been built a few years apart in time. From the earliest plant (Scholven) to the latest (Blechhammer), the liquid-phase throughput had been almost tripled, partly because of the change from 300-atm to 700-atm operation, and partly because of the use of heat exchange to heat the coal paste part way to reaction temperature. This introduction of coal paste heat exchange reduced the load on preheaters so much that the amount of heat necessary in the preheater to heat one (metric) ton of coal paste to reaction temperature was reduced from 320,000 kcal to 170,000 kcal. Another development in the middle plant (Gelsenberg) was the addition of a portion of the cold coal paste at the input to the second reaction oven in each chamber, letting the heat of reaction itself heat that paste to reaction temperature (and at the same time regulating the temperature of the reaction better). Finally it was noted that for the production of a given amount of synthetic fuel, Blechhammer needed only about half as many reaction chambers as did Scholven.

  13. The hydrogasification of lignite and sub-bituminous coals

    Science.gov (United States)

    Bhatt, B.; Fallon, P. T.; Steinberg, M.

    1981-02-01

    A North Dakota lignite and a New Mexico sub-bituminous coal have been hydrogenated at up to 900°C and 2500 psi hydrogen pressure. Yields of gaseous hydrocarbons and aromatic liquids have been studied as a function of temperature, pressure, residence time, feed rates and H2/coal ratio. Coal feed rates in excess of 10 lb/hr have been achieved in the 1 in. I. D.×8 ft reactor and methane concentration as high as 55% have been observed. A four-step reaction model was developed for the production and decomposition of the hydrocarbon products. A single object function formulated from the weighted errors for the four dependent process, variables, CH4, C2H6, BTX, and oil yields, was minimized using a program containing three independent iterative techniques. The results of the nonlinear regression analysis for lignite show that a first-order chemical reaction model with respect to C conversion satisfactorily describes the dilute phase hydrogenation. The activation energy for the initial products formation was estimated to be 42,700 cal/gmole and the power of hydrogen partial pressure was found to be +0.14. The overall correlation coefficient was 0.83. The mechanism, the rate expressions, and the design curves developed can be used for scale-up and reactor design.

  14. A process for the bituminization of radioactive wastes

    International Nuclear Information System (INIS)

    Bar-Ziv, E.; Manor, D.; Levin, I.

    1977-06-01

    A process is described for the incorporation of sodium nitrate solutions in bitumen, with a view to the bituminization of radioactive wastes. This process has involved the development of a chemical process and its technological application. A double jacket reactor equipped with an anchor-type stirrer has been built. Sodium nitrate (NaNO 3 ) solutions with sodium hydroxide (NaOH) are fed into the reactor simultaneously with a bitumen emulsion while heated oil is circulated through the double jacket. After all the water has evaporated, the mixture is ''simmered'' at 170/180 deg C for up to 5 hours in order to get a homogeneous product which will be suitable for final storage. The product contains small salt crystals (10/50 μm) and has high viscosity (200/2000 poise at 160 deg C and 12 rpm), so that the possibility of sedimentation is eliminated. In comparative experiments with molten bitumen, large salt aggregates, inhomogeneously distributed, make the product unsuitable. It has been found that NaOH is responsible for the polimerization of the bitumen, which raises its viscosity. The degree of polimerization depends on the NaOH concentration and ''simmering'' time and temperature. NaOH is added to NaNO 3 in order to raise the mixture's viscosity and thereby prevent sedimentation

  15. Chemical and Pyrolytic Thermogravimetric Characterization of Nigerian Bituminous Coals

    Directory of Open Access Journals (Sweden)

    Nyakuma Bemgba Bevan

    2016-12-01

    Full Text Available The discovery of new coal deposits in Nigeria presents solutions for nation’s energy crises and prospects for socioeconomic growth and sustainable development. Furthermore, the quest for sustainable energy to limit global warming, climate change, and environmental degradation has necessitated the exploration of alternatives using cleaner technologies such as coal pyrolysis. However, a lack of comprehensive data on physico-chemical and thermal properties of Nigerian coals has greatly limited their utilization. Therefore, the physico-chemical properties, rank (classification, and thermal decomposition profiles of two Nigerian bituminous coals – Afuze (AFZ and Shankodi-Jangwa (SKJ – were examined in this study. The results indicate that the coals contain high proportions of C, H, N, S, O and a sufficiently high heating value (HHV for energy conversion. The coal classification revealed that the Afuze (AFZ coal possesses a higher rank, maturity, and coal properties compared to the Shankodi-Jangwa (SKJ coal. A thermal analysis demonstrated that coal pyrolysis in both cases occurred in three stages; drying (30-200 °C, devolatilization (200-600 °C, and char decomposition (600-1000 °C. The results also indicated that pyrolysis at 1000 °C is not sufficient for complete pyrolysis. In general, the thermochemical and pyrolytic fuel properties indicate that the coal from both places can potentially be utilized for future clean energy applications.

  16. Gasification of high ash, high ash fusion temperature bituminous coals

    Science.gov (United States)

    Liu, Guohai; Vimalchand, Pannalal; Peng, WanWang

    2015-11-13

    This invention relates to gasification of high ash bituminous coals that have high ash fusion temperatures. The ash content can be in 15 to 45 weight percent range and ash fusion temperatures can be in 1150.degree. C. to 1500.degree. C. range as well as in excess of 1500.degree. C. In a preferred embodiment, such coals are dealt with a two stage gasification process--a relatively low temperature primary gasification step in a circulating fluidized bed transport gasifier followed by a high temperature partial oxidation step of residual char carbon and small quantities of tar. The system to process such coals further includes an internally circulating fluidized bed to effectively cool the high temperature syngas with the aid of an inert media and without the syngas contacting the heat transfer surfaces. A cyclone downstream of the syngas cooler, operating at relatively low temperatures, effectively reduces loading to a dust filtration unit. Nearly dust- and tar-free syngas for chemicals production or power generation and with over 90%, and preferably over about 98%, overall carbon conversion can be achieved with the preferred process, apparatus and methods outlined in this invention.

  17. Investigation on Using SBS and Active Carbon Filler to Reduce the VOC Emission from Bituminous Materials

    Directory of Open Access Journals (Sweden)

    Peiqiang Cui

    2014-08-01

    Full Text Available Bituminous materials are playing a vital role in pavement design and the roofing industry because of outstanding properties. Unfortunately, bituminous materials will release volatile organic compounds (VOC, making them non-environmentally friendly. Therefore, technologies that can be used to decrease the VOC emission are urgently required. In this research, the VOC emission and material behaviors were analyzed and compared to investigate the possibility of adding styrene butadiene styrene (SBS and active carbon filler into bituminous materials to develop environmentally-friendly materials. Thermal gravimetric analysis-mass spectrometry (TG-MS and ultraviolet-visible spectroscopy testing (UV-Vis were employed to characterize the VOC emission process. Temperature sweep testing and frequency sweep testing were conducted to evaluate the rheological properties of bituminous materials. Research results indicated that the combined introduction of 4 wt% styrene butadiene styrene (SBS and 4 wt% active carbon filler cannot only significantly lower the VOC emission speed and amount, but also improve the deformation resistance behavior at a higher temperature. SBS and active carbon filler can be used to reduce the VOC emission form bituminous materials.

  18. Investigation on Using SBS and Active Carbon Filler to Reduce the VOC Emission from Bituminous Materials.

    Science.gov (United States)

    Cui, Peiqiang; Wu, Shaopeng; Li, Fuzhou; Xiao, Yue; Zhang, Honghua

    2014-08-26

    Bituminous materials are playing a vital role in pavement design and the roofing industry because of outstanding properties. Unfortunately, bituminous materials will release volatile organic compounds (VOC), making them non-environmentally friendly. Therefore, technologies that can be used to decrease the VOC emission are urgently required. In this research, the VOC emission and material behaviors were analyzed and compared to investigate the possibility of adding styrene butadiene styrene (SBS) and active carbon filler into bituminous materials to develop environmentally-friendly materials. Thermal gravimetric analysis-mass spectrometry (TG-MS) and ultraviolet-visible spectroscopy testing (UV-Vis) were employed to characterize the VOC emission process. Temperature sweep testing and frequency sweep testing were conducted to evaluate the rheological properties of bituminous materials. Research results indicated that the combined introduction of 4 wt% styrene butadiene styrene (SBS) and 4 wt% active carbon filler cannot only significantly lower the VOC emission speed and amount, but also improve the deformation resistance behavior at a higher temperature. SBS and active carbon filler can be used to reduce the VOC emission form bituminous materials.

  19. Leaching behavior of a simulated bituminized radioactive waste form under deep geological conditions

    International Nuclear Information System (INIS)

    Nakayama, Shinichi; Iida, Yoshihisa; Nagano, Tetsushi; Akimoto, Toshiyuki

    2003-01-01

    The leaching behavior of a simulated bituminized waste form was studied to acquire data for the performance assessment of the geologic disposal of bituminized radioactive waste. Laboratory-scale leaching tests were performed for radioactive and non-radioactive waste specimens simulating bituminized waste of a French reprocessing company, COGEMA. The simulated waste was contacted with deionized water, an alkaline solution (0.03-mol/l KOH), and a saline solution (0.5-mol/l KCl) under atmospheric and anoxic conditions. The concentrations of Na, Ba, Cs, Sr, Np, Pu, NO 3 , SO 4 and I in the leachates were determined. Swelling of the bituminized waste progressed in deionized water and KOH. The release of the soluble components, Na and Cs, was enhanced by the swelling, and considered to be diffusion-controlled in the swelled layers of the specimens. The release of sparingly soluble components such as Ba and Np was solubility-limited in addition to the progression of leaching. Neptunium, a redox-sensitive element, showed a distinct difference in release between anoxic and atmospheric conditions. The elemental release from the bituminized waste specimens leached in the KCl was very low, which is likely due to the suppression of swelling of the specimens at high ionic strength. (author)

  20. Study on the coprocessing of Xingiang Heishan bituminous coal with Tahe petroleum residue

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, C.; Zhao, P.; Li, K. [China Shenhua Coal to Liquefaction Corporation Ltd., Ordo (China)

    2007-02-15

    The reaction process of coprocessing Xinjiang Heishan bituminous coal and petroleum residue from Tahe petroleum chemical corporation was studied by using a Japanese vibrating horizontal autoclave. The effects of different petroleum residual addition on coal liquefaction was investigated and compared with the liquefaction result under the condition of exclusive Heishan bituminous coal. The results show that compared with the liquefaction results with only Heishan bituminous coal, coal-residual coprocessing has the characteristics of low hydrogen consumption, low gas and high oil yield. Coal conversion and oil yield was increased with proper addition of petroleum residues. In this experimental system, the optimum addition of petroleum residue is 20%. Coal conversion and oil yield are increased by 1.5% and 11% respectively. 2 refs., 1 fig., 5 tabs.

  1. Results of exploitation of a pilot-plant installation for bituminization of radioactive sludges

    International Nuclear Information System (INIS)

    Golinski, M.; Ksiazak, Z.; Surala, J.; Dziubecki, R.

    1974-01-01

    Results are discussed of exploitation of a pilot-plant installation for bituminization of radioactive sludges of an efficiency of 25 l/h. In a time period of 20 month 120 cycles were carried out in which 60 m 3 of 2-4% sludges from treatment of low-level waste by the phosphate-ferrocyanide method were solidified. The P-60 asphalt was used for bituminization. The bituminization products contained 5-13.5% of mineral substances. Their activity was in the range 5 x 10 -4 - 5 x 10 -3 μCi/g for alpha emitters and 1.2 - 3.8 x 10 -2 μCi/g for beta emitters. (author)

  2. Highly crystalline Zeolite-A from flyash of bituminous and lignite coal combustion.

    Science.gov (United States)

    Rayalu, S S; Udhoji, J S; Munshi, K N; Hasan, M Z

    2001-11-16

    Flyash is being generated in voluminous amounts by large scale coal combustion process. It poses a serious threat to thermal power industries specifically, in India, wherein the percent of utilisation of flyash is very poor (3-5%). In view of this problem, newer methods of its disposal and utilisation are being explored. The synthesis of zeolite from flyash appears to be one of the most promising alternatives as it has emphasis on value addition to waste material. Flyashes originating from different sources of coal differ in their characteristics and have implications in this work on Zeolite-A production. These factors have been thoroughly investigated and the conditions favourable for formation of Zeolite-A have been delineated. The reactivity of flyash towards zeolite formation is directly dependent on the SiO(2)/Al(2)O(3) ratio, Fe(2)O(3) and CaO content. Amongst the flyashes investigated, so far the sub-bituminous coal based flyash with SiO(2)/Al(2)O(3) ratio of 3.47 appears to be a suitable substrate for Zeolite-A synthesis. These zeolites have been characterised with respect to XRD crystallinity, calcium binding capacity (CBC) and sorption capacity, wherein the crystallinity ranges from 50 to 100%, the CBC ranges from 290 to 560meq/100g and sorption capacity ranges from 16.6 to 23.8%.

  3. Using proximate analysis to characterize airborne dust generation from bituminous coals

    Energy Technology Data Exchange (ETDEWEB)

    Page, S.J.; Organiscak, J.A.

    2005-11-01

    Prolonged exposure to airborne respirable coal dust is responsible for coal workers pneumoconiosis (CWP), commonly called black lung. Health research studies have identified that the prevalence and severity of CWP are directly related to both the amount of dust exposure and the coal rank. The amount of airborne respirable dust (ARD) smaller than 10 micrometers generated from breakage of different coals varies widely. To investigate the cause, researchers for the National Institute for Occupational Safety and Health (NIOSH) have conducted experiments to identify the causes of airborne respirable dust liberation. Laboratory crushing experiments were conducted on a range of low to high volatile bituminous coals from eight mines. The results indicate that the proximate analysis of a coal sample can provide a very good indicator of the potential for a dust problem. For application to the coal mining, processing, and utilization industries, data from 977 US coal seams compiled by the Department of Energy (DoE) has been used to calculate this dust generation potential from an equation based on the NIOSH measured data. A simple procedure for this calculation is provided. 1 fig.

  4. Microstructural self-healing of bituminous materials : Combined experimental and numerical study

    NARCIS (Netherlands)

    Pauli, A.; Schmets, A.J.M.; Kasbergen, C.; Varveri, K.; Scarpas, A.

    2013-01-01

    Bituminous materials form a class of materials that possess the intrinsic ability to selfheal. This self-healing capability is evidenced by the observation that the service life of these materials ‘in the field’ exceeds the service life as predicted by standard mechanical laboratory tests. This

  5. The X-ray fluorescent method for determination of total sulphur in bituminous coals

    International Nuclear Information System (INIS)

    Widowska-Kusmierska, J.; Siess, K.

    1979-01-01

    The X-ray fluorescent technique for the determination of total sulphur covering concentrations from 0,1 to 10% has been applied for bituminous coals showing a great variability in qualitative and quantitative composition of mineral matter (ash). The described method is a quick one giving results during one hour. The obtained good accuracy of determinations gives prospects for wide industrial application. (author)

  6. Effect of bituminous coal properties on carbon dioxide and methane high pressure sorption

    Czech Academy of Sciences Publication Activity Database

    Weishauptová, Zuzana; Přibyl, Oldřich; Sýkorová, Ivana; Machovič, Vladimír

    2015-01-01

    Roč. 139, JAN 1 (2015), s. 115-124 ISSN 0016-2361 Institutional support: RVO:67985891 Keywords : bituminous coal * sorption capacity * maceral composition * Upper Silesian Coal Basin Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 3.611, year: 2015

  7. Noise Reduction Properties of an Experimental Bituminous Slurry with Crumb Rubber Incorporated by the Dry Process

    Directory of Open Access Journals (Sweden)

    Moisés Bueno

    2014-08-01

    Full Text Available Nowadays, cold technology for asphalt pavement in the field of road construction is considered as an alternative solution to conventional procedures from both an economic and environmental point of view. Among these techniques, bituminous slurry surfacing is obtaining an important role due to the properties of the obtained wearing course. The functional performance of this type of surfaces is directly related to its rough texture. Nevertheless, this parameter has a significant influence on the tire/road noise generation. To reduce this undesirable effect on the sound performance, new designs of elastic bituminous slurries have been developed. Within the FENIX project, this work presents the acoustical characterization of an experimental bituminous slurry with crumb rubber from wasted automobile tires incorporated by the dry process. The obtained results show that, under controlled operational parameters, the close proximity sound levels associated to the experimental slurry are considerably lower than those emitted by a conventional slurry wearing course. However, after one year of supporting traffic loads and different weather conditions, the evaluated bituminous slurry, although it conserves the original noise reduction properties in relation to the conventional one, noticeably increases the generated sound emission. Therefore, it is required to continue improving the design of experimental surfaces in order to enhance its long-term performance.

  8. Chemomechanics of Damage Accumulation and Damage-Recovery Healing in Bituminous Asphalt Binders

    NARCIS (Netherlands)

    Pauli, A.T.

    2014-01-01

    As a contribution to the development of mutli-scale multi-physics approaches to modelling pavement performance, the present thesis considers the topic of damage accumulation accompanied by damage recover self-healing of the bituminous asphalt phase of pavement systems. It is found insightful that by

  9. 8th RILEM International Symposium on Testing and Characterization of Sustainable and Innovative Bituminous Materials

    CERN Document Server

    Partl, Manfred

    2016-01-01

    This work presents the results of RILEM TC 237-SIB (Testing and characterization of sustainable innovative bituminous materials and systems). The papers have been selected for publication after a rigorous peer review process and will be an invaluable source to outline and clarify the main directions of present and future research and standardization for bituminous materials and pavements. The following topics are covered: - Characterization of binder-aggregate interaction - Innovative testing of bituminous binders, additives and modifiers - Durability and aging of asphalt pavements - Mixture design and compaction analysis - Environmentally sustainable materials and technologies - Advances in laboratory characterization of bituminous materials - Modeling of road materials and pavement performance prediction - Field measurement and in-situ characterization - Innovative materials for reinforcement and interlayer systems - Cracking and damage characterization of asphalt pavements - Rec...

  10. Pre-treatment of bituminized NPP wastes for disposal in near-surface repository

    Energy Technology Data Exchange (ETDEWEB)

    Vieira, Vanessa Mota; Tello, Clédola Cássia Oliveira de, E-mail: vanessamotavieira@gmail.com, E-mail: tellocc@cdtn.br [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN/CNEN-MG), Belo Horizonte, MG (Brazil)

    2017-07-01

    The implementation of the national repository is an important technical requirement, and a legal requirement for the entry into operation of the nuclear power plant Angra 3. The Brazilian repository is being planned to be a near-surface one. In Brazil the low and intermediate level radioactive wastes are immobilized using cement and bitumen for Angra 1 and Angra 2 NPP, respectively. The main problems due to the disposal of bituminized wastes in repositories are swelling of the waste products and their degradation in the long term. To accommodate the swelling of the bituminized wastes, the drums are filled up to 70 - 90% of their volume, which reduces the structural the repository stability and the disposal availability. Countries, which use bitumen in the solidification of NPP's radioactive waste and have near-surface repositories, need to immobilize this bituminized waste within other drums containing cement pastes or mortars to disposal them. This study aims to find solutions for the storage in surface repository of bituminized radioactive waste products, making them compatible with the acceptance criteria of cemented waste products. It was also performed a modeling with the results obtained in the leaching test using the ALT program and defined the transport model of the cesium leachate element and it was verified that in the early times the leaching was governed by the diffusion model and later by the partition model. The results obtained in this study can be used in the evaluation of performance of repositories. (author)

  11. Aerobic Biofilms Grown from Athabasca Watershed Sediments Are Inhibited by Increasing Concentrations of Bituminous Compounds

    Science.gov (United States)

    Lawrence, John R.; Sanschagrin, Sylvie; Roy, Julie L.; Swerhone, George D. W.; Korber, Darren R.; Greer, Charles W.

    2013-01-01

    Sediments from the Athabasca River and its tributaries naturally contain bitumen at various concentrations, but the impacts of this variation on the ecology of the river are unknown. Here, we used controlled rotating biofilm reactors in which we recirculated diluted sediments containing various concentrations of bituminous compounds taken from the Athabasca River and three tributaries. Biofilms exposed to sediments having low and high concentrations of bituminous compounds were compared. The latter were 29% thinner, had a different extracellular polysaccharide composition, 67% less bacterial biomass per μm2, 68% less cyanobacterial biomass per μm2, 64% less algal biomass per μm2, 13% fewer protozoa per cm2, were 21% less productive, and had a 33% reduced content in chlorophyll a per mm2 and a 20% reduction in the expression of photosynthetic genes, but they had a 23% increase in the expression of aromatic hydrocarbon degradation genes. Within the Bacteria, differences in community composition were also observed, with relatively more Alphaproteobacteria and Betaproteobacteria and less Cyanobacteria, Bacteroidetes, and Firmicutes in biofilms exposed to high concentrations of bituminous compounds. Altogether, our results suggest that biofilms that develop in the presence of higher concentrations of bituminous compounds are less productive and have lower biomass, linked to a decrease in the activities and abundance of photosynthetic organisms likely due to inhibitory effects. However, within this general inhibition, some specific microbial taxa and functional genes are stimulated because they are less sensitive to the inhibitory effects of bituminous compounds or can degrade and utilize some bitumen-associated compounds. PMID:24056457

  12. Characterize Cold Bituminous Emulsion Mixtures Incorporated Ordinary Portland Cement Filler for Local Surface Layer

    Directory of Open Access Journals (Sweden)

    Mustafa Amoori Kadhim

    2018-02-01

    Full Text Available Cold Bituminous Emulsion Mixtures have many environmental, logistical, and economic advantages over conventional Hot Mix Asphalt. Nevertheless, their inferior performance and high water sensitivity at early life attract little attentions. Moreover, it is impossible to apply CBEM as a structural surface layer if left without treatment or enhancement. The main aim of this study is to enhance the properties of CBEM for the hope of using it as a structural layer. Thus, a trial has been made to improve CBEM mechanical and durability properties by replacing the Ordinary Portland Cement by the Conventional Mineral Filler with 3 percentages; namely, 0, 50%, and 100%. CBEM mixtures mechanical properties were evaluated in term of Marshall Stability and Flow, Indirect Tensile Strength, and Wheel Track Test. While Moisture damage was evaluated in terms of Retained Marshall Stability. Test results showed that the addition of 100%OPC filler can improve CBEM mechanical and durability properties efficiently. In terms of mechanical properties results, CBEM comprised 100%OPC, can be used as a structural Surface layer based on local Iraqi specifications limits, where mixture enhanced about 1.9, 1.78, 9,4.85, and 2.6  times in term of MS, MF, rutting deformation resistance, resistance to tensile cracking, and moisture damage resistance, respectively as compared to untreated CBEM. Also, CBEM-100%OPC mix seemed comparable (and sometime superior to HMA, e.g., resistance to rutting of CBEM is about 6.2 times higher than that of HMA. It’s worth to say that OPC upgrades CBEM to a significant level that enables it to use as a structural layer in terms of the mechanical and the durability properties.

  13. Treatments for clays in aggregates used to produce cement concrete, bituminous materials, and chip seals : technical report.

    Science.gov (United States)

    2013-07-01

    The clay contamination of coarse and fine aggregates and its effects on pavement performance of portland cement concrete, bituminous mixes and chip seals is a major concern for Texas Department of Transportation. We proposed (i) to determine what typ...

  14. Use of additives to improve the capacity of bituminous mixtures to be heated by means of microwaves

    International Nuclear Information System (INIS)

    Gallego, J.; Val, M.A. del; Contreras, V.; Páez, A.

    2017-01-01

    This study examines the potential of adding electric arc furnace slag to bituminous mixtures to be heated by microwaves. The susceptibility of bituminous mixtures to microwave energy is limited and so, in order to improve the energy performance of the heating process, it is necessary to incorporate additives or components to the mixture so as to improve the capacity for microwave heating. The article presents the results of adding various components, (steel wool, scrap tire wire, silicon carbide, iron filings) and an alternative aggregate: electric arc furnace slag. According to the results obtained in the laboratory, slag addition of at least 5% by weight of the bituminous mixture represents the best option for both technical and economic reasons. The results may promote the valorization of this steel industry residue in bituminous mixtures by improving microwave heating response. [es

  15. Water Accumulation and Behavior of Surfactant Associated with Moisture Permeation in Bituminous Pavement on Concrete Deck Bridge

    OpenAIRE

    Sasaki, Iwao; Moriyoshi, Akihiro; Tsunekawa, Masami

    2006-01-01

    Water-related damage is one of the major problems for the durability of the bituminous pavement and concrete slabs of concrete deck bridges. In particular, damage can be drastically accelerated by the intervention of water and some chemicals such as surfactants and salts. Therefore, the mass transfer mechanism of water and the mechanism of chemical absorption in pavement materials are important to study. The authors previously pointed out that water storage in bituminous pavement layers is ca...

  16. Sorbent Injection for Small ESP Mercury Control in Low Sulfur Eastern Bituminous Coal Flue Gas

    Energy Technology Data Exchange (ETDEWEB)

    Carl Richardson; Katherine Dombrowski; Douglas Orr

    2006-12-31

    This project Final Report is submitted to the U.S. Department of Energy (DOE) as part of Cooperative Agreement DE-FC26-03NT41987, 'Sorbent Injection for Small ESP Mercury Control in Low Sulfur Eastern Bituminous Coal Flue Gas.' Sorbent injection technology is targeted as the primary mercury control process on plants burning low/medium sulfur bituminous coals equipped with ESP and ESP/FGD systems. About 70% of the ESPs used in the utility industry have SCAs less than 300 ft2/1000 acfm. Prior to this test program, previous sorbent injection tests had focused on large-SCA ESPs. This DOE-NETL program was designed to generate data to evaluate the performance and economic feasibility of sorbent injection for mercury control at power plants that fire bituminous coal and are configured with small-sized electrostatic precipitators and/or an ESP-flue gas desulfurization (FGD) configuration. EPRI and Southern Company were co-funders for the test program. Southern Company and Reliant Energy provided host sites for testing and technical input to the project. URS Group was the prime contractor to NETL. ADA-ES and Apogee Scientific Inc. were sub-contractors to URS and was responsible for all aspects of the sorbent injection systems design, installation and operation at the different host sites. Full-scale sorbent injection for mercury control was evaluated at three sites: Georgia Power's Plant Yates Units 1 and 2 [Georgia Power is a subsidiary of the Southern Company] and Reliant Energy's Shawville Unit 3. Georgia Power's Plant Yates Unit 1 has an existing small-SCA cold-side ESP followed by a Chiyoda CT-121 wet scrubber. Yates Unit 2 is also equipped with a small-SCA ESP and a dual flue gas conditioning system. Unit 2 has no SO2 control system. Shawville Unit 3 is equipped with two small-SCA cold-side ESPs operated in series. All ESP systems tested in this program had SCAs less than 250 ft2/1000 acfm. Short-term parametric tests were conducted on Yates

  17. Research on the thermal decomposition of Mongolian Baganuur lignite and Naryn sukhait bituminous coal

    Directory of Open Access Journals (Sweden)

    A. Ariunaa

    2016-03-01

    Full Text Available The technical characteristics, elemental composition of the organic and mineral matters, ash melting behaviors and carbonization and gasification reactivities of coals from Baganuur and Naryn sukhait deposits were investigated. The results of proximate and ultimate analysis confirmed that the coal from Baganuur deposit can be graded as a low rank lignite B2 mark coal and Naryn sukhait coal is a bituminous G mark one. The carbonization and gasification experiments were performed using TGA apparatus and fixed bed quartz reactor. The data obtained with two experimental reactors showed that Baganuur lignite had lower thermal stability and much higher CO2 gasification reactivity at 950°C as compared to those for Naryn sukhait bituminous coal.Mongolian Journal of Chemistry 16 (42, 2015, 22-29

  18. Study on Plastic Coated Overburnt Brick Aggregate as an Alternative Material for Bituminous Road Construction

    OpenAIRE

    Sarkar, Dipankar; Pal, Manish; Sarkar, Ashoke K.

    2016-01-01

    There are different places in India where natural stone aggregates are not available for constructional work. Plastic coated OBBA can solve the problem of shortage of stone aggregate to some extent. The engineers are always encouraged to use locally available materials. The present investigation is carried out to evaluate the plastic coated OBBA as an alternative material for bituminous road construction. Shredded waste plastics are mixed with OBBA in different percentages as 0.38, 0.42, 0.46...

  19. [Determination of aromatic polycyclic hydrocarbons during the installation of bituminous acoustic insulation panels].

    Science.gov (United States)

    Gianello, G; Marrubini, G; La Bua, R; Laurini, C; Bergamaschi, A

    2006-01-01

    Two kinds of bituminous European and Asiatic origin panels, used as acoustic insulators in the production of electrical household appliances have been analysed. The tests, made at 180 degrees C, operation temperature during the assembly phases, have been executed by sampling the smokes released during the thermal treatment, subsequently analysed by GC-MS. The results showed a marked difference between the two samples in the amount of the issued compounds, essentially constituted by alkyl-aromatic hydrocarbons, IPA and Alkyl-IPA.

  20. Noise Reduction Properties of an Experimental Bituminous Slurry with Crumb Rubber Incorporated by the Dry Process

    OpenAIRE

    Bueno, Moisés; Luong, Jeanne; Terán, Fernando; Viñuela, Urbano; Vázquez, Víctor; Paje, Santiago

    2014-01-01

    Nowadays, cold technology for asphalt pavement in the field of road construction is considered as an alternative solution to conventional procedures from both an economic and environmental point of view. Among these techniques, bituminous slurry surfacing is obtaining an important role due to the properties of the obtained wearing course. The functional performance of this type of surfaces is directly related to its rough texture. Nevertheless, this parameter has a significant influence on th...

  1. Carbon Isotope Analyses of Individual Hydrocarbon Molecules in Bituminous Coal, Oil Shale and Murchison Meteorite

    Directory of Open Access Journals (Sweden)

    Kyoungsook Kim

    1998-06-01

    Full Text Available To study the origin of organic matter in meteorite, terrestrial rocks which contain organic compounds similar to the ones found in carbonaceous chondrites are studied and compared with Murchison meteorite. Hydrocarbon molecules were extracted by benzene and methanol from bituminous coal and oil shale and the extracts were partitioned into aliphatic, aromatic, and polar fractions by silica gel column chromatography. Carbon isotopic ratios in each fractions were analysed by GC-C-IRMS. Molecular compound identifications were carried by GC-MS Engine. Bituminous coal and oil shale show the organic compound composition similar to that of meteorite. Oil shale has a wide range of δ(13C, -20.1%_0 - -54.4%_0 compared to bituminous coal, -25.2%_0 - -34.3%_0. Delta values of several molecular compounds in two terrestrial samples are different. They show several distinct distributions in isotopic ratios compared to those of meteorite; Murchison meteorite has a range of δ(13C from -13%_0 to +30%_0. These results provide interpretation for the source and the formation condition of each rock, in particular alteration and migration processes of organic matter. Especially, they show an important clue whether some hydrocarbon molecules observed in meteorite are indigenous or not.

  2. Continuous bench-scale slurry catalyst testing direct coal liquefaction rawhide sub-bituminous coal

    Energy Technology Data Exchange (ETDEWEB)

    Bauman, R.F.; Coless, L.A.; Davis, S.M. [and others

    1995-12-31

    In 1992, the Department of Energy (DOE) sponsored research to demonstrate a dispersed catalyst system using a combination of molybdenum and iron precursors for direct coal liquefaction. This dispersed catalyst system was successfully demonstrated using Black Thunder sub-bituminous coal at Wilsonville, Alabama by Southern Electric International, Inc. The DOE sponsored research continues at Exxon Research and Development Laboratories (ERDL). A six month continuous bench-scale program using ERDL`s Recycle Coal Liquefaction Unit (RCLU) is planned, three months in 1994 and three months in 1995. The initial conditions in RCLU reflect experience gained from the Wilsonville facility in their Test Run 263. Rawhide sub-bituminous coal which is similar to the Black Thunder coal tested at Wilsonville was used as the feed coal. A slate of five dispersed catalysts for direct coal liquefaction of Rawhide sub-bituminous coal has been tested. Throughout the experiments, the molybdenum addition rate was held constant at 100 wppm while the iron oxide addition rate was varied from 0.25 to 1.0 weight percent (dry coal basis). This report covers the 1994 operations and accomplishments.

  3. Study on Plastic Coated Overburnt Brick Aggregate as an Alternative Material for Bituminous Road Construction

    Directory of Open Access Journals (Sweden)

    Dipankar Sarkar

    2016-01-01

    Full Text Available There are different places in India where natural stone aggregates are not available for constructional work. Plastic coated OBBA can solve the problem of shortage of stone aggregate to some extent. The engineers are always encouraged to use locally available materials. The present investigation is carried out to evaluate the plastic coated OBBA as an alternative material for bituminous road construction. Shredded waste plastics are mixed with OBBA in different percentages as 0.38, 0.42, 0.46, 0.50, 0.54, and 0.60 of the weight of brick aggregates. Marshall Method of mix design is carried out to find the optimum bitumen content of such bituminous concrete mix prepared by plastic coated OBBA. Bulk density, Marshall Stability, flow, Marshall Quotient, ITS, TSR, stripping, fatigue life, and deformations have been determined accordingly. Marshall Stability value of 0.54 percent of plastic mix is comparatively higher than the other mixes except 0.60 percent of plastic mix. Test results are within the prescribed limit for 0.54 percent of plastic mix. There is a significant reduction in rutting characteristics of the same plastic mix. The fatigue life of the mix is also significantly higher. Thus plastic coated OBBA is found suitable in construction of bituminous concrete road.

  4. JV Task 126 - Mercury Control Technologies for Electric Utilities Burning Bituminous Coal

    Energy Technology Data Exchange (ETDEWEB)

    Jason Laumb; John Kay; Michael Jones; Brandon Pavlish; Nicholas Lentz; Donald McCollor; Kevin Galbreath

    2009-03-29

    The EERC developed an applied research consortium project to test cost-effective mercury (Hg) control technologies for utilities burning bituminous coals. The project goal was to test innovative Hg control technologies that have the potential to reduce Hg emissions from bituminous coal-fired power plants by {ge}90% at costs of one-half to three-quarters of current estimates for activated carbon injection (ACI). Hg control technology evaluations were performed using the EERC's combustion test facility (CTF). The CTF was fired on pulverized bituminous coals at 550,000 Btu/hr (580 MJ/hr). The CTF was configured with the following air pollution control devices (APCDs): selective catalytic reduction (SCR) unit, electrostatic precipitator (ESP), and wet flue gas desulfurization system (WFDS). The Hg control technologies investigated as part of this project included ACI (three Norit Americas, Inc., and eleven Envergex sorbents), elemental mercury (Hg{sup 0}) oxidation catalysts (i.e., the noble metals in Hitachi Zosen, Cormetech, and Hitachi SCR catalysts), sorbent enhancement additives (SEAs) (a proprietary EERC additive, trona, and limestone), and blending with a Powder River Basin (PRB) subbituminous coal. These Hg control technologies were evaluated separately, and many were also tested in combination.

  5. Time dependent viscoelastic rheological response of pure, modified and synthetic bituminous binders

    Science.gov (United States)

    Airey, G. D.; Grenfell, J. R. A.; Apeagyei, A.; Subhy, A.; Lo Presti, D.

    2016-08-01

    Bitumen is a viscoelastic material that exhibits both elastic and viscous components of response and displays both a temperature and time dependent relationship between applied stresses and resultant strains. In addition, as bitumen is responsible for the viscoelastic behaviour of all bituminous materials, it plays a dominant role in defining many of the aspects of asphalt road performance, such as strength and stiffness, permanent deformation and cracking. Although conventional bituminous materials perform satisfactorily in most highway pavement applications, there are situations that require the modification of the binder to enhance the properties of existing asphalt material. The best known form of modification is by means of polymer modification, traditionally used to improve the temperature and time susceptibility of bitumen. Tyre rubber modification is another form using recycled crumb tyre rubber to alter the properties of conventional bitumen. In addition, alternative binders (synthetic polymeric binders as well as renewable, environmental-friendly bio-binders) have entered the bitumen market over the last few years due to concerns over the continued availability of bitumen from current crudes and refinery processes. This paper provides a detailed rheological assessment, under both temperature and time regimes, of a range of conventional, modified and alternative binders in terms of the materials dynamic (oscillatory) viscoelastic response. The rheological results show the improved viscoelastic properties of polymer- and rubber-modified binders in terms of increased complex shear modulus and elastic response, particularly at high temperatures and low frequencies. The synthetic binders were found to demonstrate complex rheological behaviour relative to that seen for conventional bituminous binders.

  6. Mineral matter in Spanish bituminous and brown coals. Part 2: mineral matter quantification

    Energy Technology Data Exchange (ETDEWEB)

    Martinez-Tarazona, M.R.; Martinez Alonso, A.; Tascon, J.M.D. (Instituto Nacional del Carbon y sus Derivados, Oviedo (Spain))

    1993-05-01

    A number of methods for mineral matter quantification were applied to a set of Spanish coals. Bituminous coals of different rank from the Asturian Central basin and brown coals from Galician basins were studied. Normative analysis was shown to be an adequate procedure for determining the concentrations of individual mineral species. It was found that mineral constituents of Asturian bituminous coals are, in decreasing abundance order, clay minerals (muscovite, kaolinite), quartz and carbonates. In the case of Galician brown coals kaolinite is the most abundant mineral, followed by quartz and pyrite. Extraction with ammonium acetate and oxidation with hydrogen peroxide yielded equivalent values for the concentrations of alkali and alkaline-earth elements bound to organic matter in brown coals. A series of direct and indirect procedures as well as numerical methods for determining the total mineral matter content of coals were compared. Optimum methods for determining the total mineral matter contents of bituminous coals were low-temperature ashing (LTA) and acid demineralisation. The sum of the LTA yield of ammonium acetate-extracted coal and the total concentration of ion-exchanged elements provided the most reliable results for brown coals. Correction formulae from ash yield previously derived for coals from other basins yielded only slightly satisfactory results for the Spanish coals under study. Results obtained evidence the importance of correctly establishing the nature and concentration of clay minerals present in coal. Also, the convenience of carrying out more comprehensive work to unequivocally establish the mineral matter/ash factors for the various types of Spanish coals is suggested. 65 refs., 6 tabs.

  7. Synergistic effect on thermal behavior during co-pyrolysis of lignocellulosic biomass model components blend with bituminous coal.

    Science.gov (United States)

    Wu, Zhiqiang; Wang, Shuzhong; Zhao, Jun; Chen, Lin; Meng, Haiyu

    2014-10-01

    Co-thermochemical conversion of lignocellulosic biomass and coal has been investigated as an effective way to reduce the carbon footprint. Successful evaluating on thermal behavior of the co-pyrolysis is prerequisite for predicting performance and optimizing efficiency of this process. In this paper, pyrolysis and kinetics characteristics of three kinds of lignocellulosic biomass model components (cellulose, hemicellulose, and lignin) blended with a kind of Chinese bituminous coal were explored by thermogravimetric analyzer and Kissinger-Akahira-Sunose method. The results indicated that the addition of model compounds had different synergistic effects on thermal behavior of the bituminous coal. The cellulose showed positive synergistic effects on the thermal decomposition of the coal bituminous coal with lower char yield than calculated value. For hemicellulose and lignin, whether positive or negative synergistic was related to the mixed ratio and temperature range. The distribution of the average activation energy values for the mixtures showed nonadditivity performance. Copyright © 2014 Elsevier Ltd. All rights reserved.

  8. A Method to Estimate the Dynamic Displacement and Stress of a Multi-layered Pavement with Bituminous or Concrete Materials

    Directory of Open Access Journals (Sweden)

    Zheng LU

    2014-12-01

    Full Text Available In this research work, a method to estimate the dynamic characteristics of a multilayered pavement with bituminous or concrete materials is proposed. A mechanical model is established to investigate the dynamic displacement and stress of the multi-layered pavement structure. Both the flexible and the rigid pavements, corresponding to bituminous materials and concrete materials, respectively, are studied. The theoretical solutions of the multi-layered pavement structure are deduced considering the compatibility condition at the interface of the structural layers. By introducing FFT (Fast Fourier Transform algorithm, some numerical results are presented. Comparisons of the theoretical and experimental result implied that the proposed method is reasonable in predicting the stress and displacement of a multi-layered pavement with bituminous or concrete materials. DOI: http://dx.doi.org/10.5755/j01.ms.20.4.6071

  9. Applied Technological Direction of Power Plant Ash and Slag Waste Management when Kuznetsk Bituminous Coal is Burned

    Directory of Open Access Journals (Sweden)

    Lihach Snejana A.

    2016-01-01

    Full Text Available Currently a lot of power plants have a problem with storage of coal combustion solid by-products (ash and slag. Holding capacity of existing power plants available ash dumps were enlarged and modernized repeatedly. Many plants have two or even three of them. Today new ash dump construction is economically inconvenient due to need to assign new plots of land and their inconveniently big distance from a plant, which increase ash and slag transportation expenses. The goal of our research work is to find promising directions for ash and slag waste mass utilization based on Kuznetsk bituminous coals experimental data on ultimate composition and properties. The experimental research of ash, slag and their mixture samples from ash dumps brought us to conclusion that the most promising direction for these materials application in large quantities is construction industry including road construction. Be-sides, we lined up some other directions for ash, slag, and ash and slag mixture possible application. These directions might not provide mass utilization but they are promising from a point of view of the researched waste properties.

  10. Co-combustion of bituminous coal and biomass fuel blends: Thermochemical characterization, potential utilization and environmental advantage.

    Science.gov (United States)

    Zhou, Chuncai; Liu, Guijian; Wang, Xudong; Qi, Cuicui

    2016-10-01

    The thermochemical characteristics and gaseous trace pollutant behaviors during co-combustion medium-to-low ash bituminous coal with typical biomass residues (corn stalk and sawdust) were investigated. Lowering of ignition index, burnout temperature and activation energy in the major combustion stage are observed in the coal/biomass blends. The blending proportion of 20% and 30% are regarded as the optimum blends for corn stalk and sawdust, respectively, in according the limitations of heating value, activation energy, flame stability and base/acid ratio. The reductions of gaseous As, Cd, Cu, Pb, Zn and polycyclic aromatic hydrocarbon (PAHs) were 4.5%, 7.8%, 6.3%, 9.8%, 9.4% and 17.4%, respectively, when co-combustion coal with 20% corn stalk. The elevated capture of trace elements were found in coal/corn stalk blend, while the coal/sawdust blend has the better PAHs control potential. The reduction mechanisms of gaseous trace pollutants were attributed to the fuel property, ash composition and relative residence time during combustion. Copyright © 2016 Elsevier Ltd. All rights reserved.

  11. The projects of reducing environmental pollution at the collieries belonging to Petrosani Autonomous Bituminous Coal Administration

    International Nuclear Information System (INIS)

    Arad, V.; Arad, S.; Costinas, B.; Marchis, G.

    1997-01-01

    The economic development in the Jiu Valley, as practised in the mining and processing of bituminous coal, has had a dynamic character without taking into account, however, the harmful impact on the environment. The most severe problem of environmental pollution in the Jiu Valley is that of the pollution of the Jiu River due to the discharge of waste water from the technological processes of mining and processing coal. This paper presents some solutions for reducing this environmental pollution, especially the Jiu water pollution. 1 ref

  12. Investigation of activity release from bituminized intermediate-level waste forms under thermal stresses

    International Nuclear Information System (INIS)

    Kluger, W.; Vejmelka, P.; Koester, R.

    1983-01-01

    To determine the consequences of a fire during fabrication, intermediate storage and transport of bituminized NaNO 3 waste forms, the fractions of plutonium released from the waste forms were assessed. For this purpose, laboratory tests were made with PuO 2 -containing specimens as well as a field test with specimens containing Eu 2 O 3 . By the evaluation of plutonium release in the laboratory and by the determination of the total sodium release and the relative Eu/Na release in the field tests the plutonium release can be deduced from full-scale specimens. The results show that for bituminized waste forms with high NaNO 3 contents (approx. 36 wt%) the average plutonium release obtained in laboratory testing is 15%. In the field tests (IAEA fire test conditions) an average Eu release of 8% was found. These results justify the statement that also for waste forms in open 175 L drum inserts a maximum plutonium release of about 15% can be expected. From the time-dependence of Eu/Na release in the field tests an induction period of 15-20 minutes between the start of testing and the first Na/Eu release can be derived. The maximum differential Na/Eu release occurs after a test period of 45 to 60 minutes duration and after 90 to 105 minutes (tests K2 and K4, respectively); after that time also the highest temperatures in the products are measured. The release values were determined for products in open 175 L drum inserts which in this form are not eligible for intermediate and ultimate storage. For bituminized waste forms in concrete packages (lost concrete shieldings) a delayed increase in temperature to only 70-80 deg. C takes place (4-5 hours after extinction of the fire) if the fire lasts 45 minutes. The concrete package remains intact under test conditions. This means that activity release from bituminized waste forms packaged in this way can be ruled out in the case under consideration. (author)

  13. Assessment of the Remaining Life of Bituminous Layers in Road Pavements

    Directory of Open Access Journals (Sweden)

    Kálmán Adorjányi

    2017-02-01

    Full Text Available In this paper, a mechanistic-empirical approach is presented for the assessment of bearing capacity condition of asphalt pavement layers by Falling Weight Deflectometer measurements and laboratory fatigue tests. The bearing capacity condition ratio was determined using past traffic data and the remaining fatigue life which was determined from multilayer pavement response model. The traffic growth rate was taken into account with finite arithmetic and geometric progressions. Fatigue resistance of layers’ bituminous materials was obtained with indirect tensile fatigue tests. Deduct curve of condition scores was derived with Weibull distribution.

  14. Fixed-bed gasification research using US coals. Volume 13. Gasification of Blind Canyon bituminous coal

    Energy Technology Data Exchange (ETDEWEB)

    Thimsen, D.; Maurer, R.E.; Pooler, A.R.; Pui, D.; Liu, B.; Kittelson, D.

    1985-05-01

    A single-staged, fixed-bed Wellman-Galusha gasifier coupled with a hot, raw gas combustion system and scrubber has been used to gasify numerous coals from throughout the United States. The gasification test program is organized as a cooperative effort by private industrial participants and governmental agencies. The consortium of participants is organized under the Mining and Industrial Fuel Gas (MIFGa) Group. This report is the thirteenth volume in a series of reports describing the atmospheric pressure, fixed-bed gasification of US coals. This specific report describes the gasification of Blind Canyon bituminous coal, from July 31, 1984 to August 11, 1984. 6 refs., 22 figs., 20 tabs.

  15. Testing of bituminized ion-exchange resin waste products from a nuclear power plant

    International Nuclear Information System (INIS)

    Muurinen, A.K.; Vuorinen, U.S.

    Testing methods are described and preliminary results presented for the bituminized waste products from TVO nuclear power plant. Radiation effects on the physical and chemical characteristics of the waste product and a pure bitumen sample were studied using an external 60 Co gamma source. Results of the postirradiation study show that the relative density decreases for both the waste products and the bitumen. Softening points rise for waste products but drop for bitumen. Breaking point of the powder resin waste product drops; in the granular resin waste product it rises on the surface and slightly decreases or does not significantly change at the bottom. For bitumen the breaking point rises

  16. Biomarker geochemistry of bituminous shale sequence and crude oil in the Ereǧli-Bor Basin (Konya-Niǧde), Central Anatolia, Turkey

    Science.gov (United States)

    Kara-Gulbay, Reyhan; Erdogan, Mert; Korkmaz, Sadettin; Kadinkiz, Gökhan

    2016-04-01

    In the Ereǧli-Bor Basin (Konya-Niǧde), Central Anatolia, bituminous shale sequence with thickness ranging between 72 and 160 m occurs in lacustrine deposits of Upper Miocene-Pliocene age. The live oil has also been observed in this bituminous shale sequence. Rock-Eval/TOC, GC and GC-MS analyses were conducted on selected bituminous shale samples from four borehole (key-12/1, key-12/2, key-12/3 key-12/4) and one crude oil sample from a borehole (key-12/2) in the basin. In this study, organic matter type, maturity and depositional environment of bituminous shale are evaluated and the origin of crude oil is determined by the bituminous shale-crude oil correlation. The total organic carbon (TOC) values of the bituminous shale samples range from 1.21-13.98 wt% with an average TOC value of 4.75wt%. The bituminous shale sequence is characterized by high HI (127-662 mg HC/g TOC) and low OI (7-50 mgCO2/TOC). Tmax varies from 332-419ᵒC. Very low Pr/Ph ratios of bituminous shale (0.09-0.22) are indicative of anoxic depositional conditions. C27 is dominate sterane for bituminous shale and crude oil samples with C27>C29>C28. Normal steranes are more dominant compare to iso- and diasteranes. Ouite high sterane/hopane ratios (1.14-2.70) indicate dominant algal organic matter input for bituminous shale and source rock of crude oil. C31R/hopane ratio for bituminous shale and crude oil samples are very low (0.09-0.13) and these ratio show a lacustrine depositional envirronment for bituminous shale and source rock of crude oil. Sterane and terpane distributions of bituminous shale and crude oil are very similar. A very good correlation in terms of biomarker between bituminous shale and crude oil samples indicate that source rock of crude oil is bituminous shale. The 22S/(22R + 22S) C32 homohopane ratios of bituminous shale and crude oil samples are found to be 0.56 and 0.61, indicating that homohopane isomerization has attained equilibrium and bituminous shale and crude oil are

  17. Polyfunctional Modifiers for Bitumen and Bituminous Materials with High Performance

    Directory of Open Access Journals (Sweden)

    Alim Feizrakhmanovich Kemalov

    2018-01-01

    Full Text Available Over the last decade increase in capacity and the intensity of vehicular traffic has increased manifoldly, including heavy trucks, super singles, and higher tire pressures, resulting in significant increase of dynamic loads on the road surface which in turn lead to high quality requirements for bitumen in order to avoid premature wear and failure of asphalt concrete pavements. One of the possibilities to increase the quality of bitumen is to use special additives and modifiers that can provide a high adhesion to mineral filler and inhibit the aging and degradation processes in the asphalt coating. To achieve this, in the present study composite modifiers based on bisimidazolines derivatives were synthesized. The developed polyfunctional modifier (PFM of complex action provides enhanced thermal stability, significantly improves the adhesion between bitumen binder and aggregates, and also improves the physical-mechanical properties of the asphalt concrete. Based on the test results it is recommended to use the synthesized samples of the PFM additive with complex action in asphalt mixtures for road paving.

  18. Feasibility study of producing lump fuel using oil-bituminous sands

    Energy Technology Data Exchange (ETDEWEB)

    Moldybaev, A.B.; Ermagambetov, B.T.; Mamraeva, K.M.; Shin, R.G.; Bakirova, R.K. (Institut Organicheskogo Sinteza i Uglekhimii AN KazSSR (USSR))

    1991-04-01

    Describes production of lump fuel by briquetting and coking different mixtures of non-caking coal with coal preparation sludge and bitumen extracted from oil sands. The coal used was from the Shubarkol'sk coal deposit (USSR); the sludge was from the Saburkhanskaya preparation plant. Properties and composition of oil-bituminous sands and of bitumen to be used as binder are given. Technological details of the briquetting and coking processes are provided. Results show that briquets produced from mixtures of coal and oil-bituminous sands can only be used as a high-ash lump fuel, which cannot be further processed into semicoke. Experiments were carried out briquetting coal or coke, sludge and 6-8% bitumen extracted from the sands, varying coal or coke grain fractions and composition of the mixture. An increased briquet strength was found after using the vacuum-distilled 300-350 C bitumen fraction. Briquets from this non-caking coal with bitumen binder are regarded as ecologically clean fuel. 5 refs.

  19. THE HISTORY OF EXPLORATION AND EXPLOITATION OF BITUMINOUS AND KEROGENOUS DEPOSITS IN CROATIA

    Directory of Open Access Journals (Sweden)

    Berislav Šebečić

    1995-12-01

    Full Text Available It is assumed thal the first known sedimens of natural bitumen or asphalt in coastal Croatia were exploited as the early moddle ages. Yet authenticated written documents about Vinišće near Trogir derive from no earlier than 1628, about Vrgorac/Paklina from only 1753. By the end of the 18th century, many deposits were discovered in Dalmatia, but it was Škrip on the Island of Brač and Suhi Dolac that were important. The earliest known deposits and occurrences of kerogenous rocks, or bituminous or oil shales, are mentioned as stone or fossil coal in Sovinjak, in the upper course of the River Mirna, and in Rebići in Istria; near Sinj, Slivno not far from the River Neretva, Mirta and near Nerežišće on the Island uf Brač. All if these were well known and described in 1804, while Sovinjak was mentioned in the 16th century. In the article, some of new information derived from mining and geological research into bituminous and kerogenous sediments and deposits are provided (the paper is published in Croatian.

  20. Isotopic variations in the nitrogen of natural humic and bituminous organic substances

    International Nuclear Information System (INIS)

    Stiehl, G.; Lehmann, M.

    1980-01-01

    delta 15 N-values and nitrogen contents of a series of humic and bituminous organic sediments of different ranks were determined. The change of the isotopic abundance of nitrogen was investigated during heating in model experiments, using a gas flame coal. In the case of humic carbon coals the relative nitrogen contents vary from 0.8 to 1.4% and the delta 15 N-values from + 3.5 to + 6.3 parts per thousand increasing from the brown coal to anthracite ranks. During the coalification process both the delta 15 N-values and the relative nitrogen contents do not vary continuously with the rank, but pass through maxima and minima. Model experiments using a gas flame coal show the same trend. Nitrogen with delta 15 N-values of + 2.8 or -7 parts per thousand was released in pyrolysis experiments, applying a gas flame coal and a steam coal at temperatures of 650 and 1000 0 C, respectively. The investigated bituminous sediments yielded relative amounts of 0.1 to 0.8% with delta 15 N-values of + 4.2 to + 10.7 parts per thousand. The obtained results are discussed with respect to the elucidation of nitrogen genesis in natural gas deposits. (author)

  1. Assessing radioactive concentrates and waste vapor condensate in solidifying radioactive wastes by bituminization

    International Nuclear Information System (INIS)

    Tibensky, L.; Krejci, F.; Breza, M.; Timulak, J.; Hladky, E.

    1986-01-01

    A brief overview is presented of chemical and radiochemical methods used in the world for the analysis of the concentrate of liquid radioactive wastes from nuclear power plants destined for bituminization. Most methods are also suitable for an analysis of the condensate of waste vapors produced in bituminization. The methods of analysis of the radioactive concentrate from the V-1 nuclear power plant in Jaslovske Bohunice and of the waste vapors condensate were developed and tested in practice. Gross gamma activity was measured using a well-type Na(Tl) scintillation detector, the content of radionuclides was determined using semiconductor Ge(Li) spectrometry. The concentration of boric acid in the concentrate was determined by titration with mannite; in the condensate, using spectrophotometry with curcumine. The content of nitrates in both the concentrate and the condensate was determined spectrophotometrically using salicylic acid, the content of nitrites was determined by spectrophotometry using sulfanilic acid and α-naphthylamine. Carbonates and chlorides were determined by titration, sodium and potassium by flame photometry. The content of organic acids was measured by gravimetry of extracted methyl esters, the content of surfactants by spectrophotometry. Infrared spectrophotometry was used in determining hydrocarbons in the waste vapor condensate. The measured value range and the measurement errors are shown for each method. (A.K.)

  2. Reuse of bituminous pavements: A mini-review of research, regulations and modelling.

    Science.gov (United States)

    Anthonissen, Joke; Van den Bergh, Wim; Braet, Johan

    2017-04-01

    Bituminous pavement can be recycled - even multiple times - by reusing it in new bituminous mixtures. If the mechanical properties of the binder get worse, this reclaimed asphalt is often used in the sub-structure of the road. Apparently, up till now, no end-of-life phase exists for the material. Actually, defining the end-of-life and the end-of-waste stage of a material is important for life cycle assessment modelling. Various standards and scientific studies on modelling life cycle assessment are known, but the crucial stages are not yet defined for reclaimed asphalt pavement. Unlike for iron, steel and aluminium scrap, at this moment, no legislative end-of-waste criteria for aggregates are formulated by the European Commission. More research is necessary in order to develop valuable end-of-life criteria for aggregates. This contribution is a mini-review article of the current regulations, standards and studies concerning end-of-life and end-of-waste of reclaimed asphalt pavement. The existing methodology in order to define end-of-waste criteria, a case study on aggregates and the argumentation used in finished legislative criteria are the basis to clarify some modelling issues for reclaimed asphalt material. Hence, this contribution elucidates the assignment of process environmental impacts to a life cycle stage as defined by EN15804, that is, end-of-life stage (C) and the supplementary information Module D with benefits and loads beyond the system boundary.

  3. Application of the cementitious grouts on stability and durability of semi flexible bituminous mixtures

    Science.gov (United States)

    Karami, Muhammad

    2017-11-01

    This paper describes the results of laboratory test for a high durability semi flexible bituminous mixtures (SFBM). The SFBM consists of an open asphalt structure where a high strength mortar is penetrated into the air voids of the bituminous mixtures. The SFBM combines the cement concrete's strength and the asphalt material flexibility. The objective of this study is to involve in the determination of stability and durability of SFBM by located the position of the specimen on an exposed area for 7, 90, 180 and 240 days. The performance of the SFBM was assessed using Marshall and wheel tracking apparatus. Total 18 specimens were prepared and examined for both of test. The Marshall specimens were cylindrical with dimension of 10.16 cm in diameter and 6.35 cm in high. For wheel tracking test, the specimens consisted of slabs with dimension of 30 cm in length, 30 cm in width and 5 cm in height. The results indicated that the first durability index and second durability index increased significantly. For Marshall test, the first and second durability index increased about 0.9% per day and 52.3%, respectively. However, for wheel tracking test, the first and second durability index increased about 1.9% per day and 119%, respectively.

  4. INVESTIGATION ON UTILITY OF PLASTIC WASTE AS AN ADDITIVE FOR BITUMINOUS CONCRETE USING WET PROCESS OF MIXING

    Directory of Open Access Journals (Sweden)

    Anurag Virendra Tiwari

    2017-12-01

    Full Text Available Purpose. Plastic waste has become a major environmental issue of concern due to its exponential growth due to rapid urbanization. The paper investigates utility of plastic waste as an additive for bituminous concrete using wet process of mixing. Methodology. The methodology for the present paper has been designed with complex research consisting of Marshall mix design of the bituminous mix added with plastic waste for modifying bitumen using wet process of mixing, performing the tests on the samples and analyzing the results in the form of table and figures. In the present paper LDPE and HDPE type of plastic waste are used to modify the bitumen. Finding. The results show that addition of 6 percent of bitumen improves the Marshall properties of the mix. Use of plastic to modify the bitumen not only makes the road surface more durable but also it is an eco-friendly way of proper disposal of plastic waste. Originality. The processes used for mixing the plastic waste to the bitumen are dry process and wet process. Dry process of mixing the plastic waste to the bituminous mix is most common and lot of study is carried out on its application. In the present paper wet process of mixing has not yet been studied much. Practical Value. The practical application of utilizing the plastic waste to modify bitumen in the bituminous mix improves the stability values resulting in the more durable road surface. Also the method ensures the proper disposal of plastic waste in eco-friendly way.

  5. Appropriate use of locally available materials in concrete, bituminous surfacings and layerworks for roads in rural areas

    CSIR Research Space (South Africa)

    Paige-Green, P

    2009-06-17

    Full Text Available and durability of the concrete and probably to increase the shrinkage. Bituminous surfacings are currently tightly specified and comparison with other countries indicates that certain areas of relaxation are possible. These are mostly with respect to the grading...

  6. Mechanical properties of hot bituminous mixes manufactured with recycled aggregate of Silestone® waste

    Directory of Open Access Journals (Sweden)

    Rubio, M. C.

    2011-03-01

    Full Text Available This article presents the results of a research project which analyzes the viability of incorporating waste material from decorative quartz solid surfacing in the manufacture of hot bituminous mixes. For this purpose, various bituminous mixes were manufactured with waste aggregate in different percentage. A set of tests were carried out that permitted the characterization of the mechanical behavior of these mixes. The results of these tests were similar to the results obtained when conventional mixes made from virgin quarry aggregate were tested. The results for moisture sensitivity as well as for wheel track rutting on mixes showed the optimal performance of this waste material even under very demanding traffic conditions. Laboratory studies showed that the use of this waste material in the manufacture of bituminous mixes is technically viable and can provide high-quality recycled aggregates at a very low cost, which can be used in the pavement of road.

    Este artículo muestra los resultados de un proyecto de investigación que tiene por objeto analizar la viabilidad de incorporación de residuos procedentes de piedra decorativa en la fabricación de mezclas bituminosas en caliente. Para ello se fabricaron mezclas con áridos reciclados de residuos procedentes de piedra decorativa en distintos porcentajes, realizando un conjunto de ensayos que posibilitaron caracterizar el comportamiento mecánico de dichas mezclas. Los resultados obtenidos fueron similares a los de las mezclas convencionales fabricadas con áridos vírgenes procedentes de cantera. Los valores de resistencia conservada ante la acción del agua y deformación en pista, pusieron de manifiesto la aptitud del residuo incluso ante las condiciones de tráfico más exigentes. Los trabajos realizados en el laboratorio indican que la utilización del residuo en la fabricación de mezclas bituminosas es técnicamente viable, pudiendo obtenerse áridos reciclados de gran calidad y

  7. Thermodynamic analysis and economic evaluation of a 1000 MW bituminous coal fired power plant incorporating low-temperature pre-drying (LTPD)

    International Nuclear Information System (INIS)

    Xu, Cheng; Xu, Gang; Zhu, Mingming; Dong, Wei; Zhang, Yang; Yang, Yongping; Zhang, Dongke

    2016-01-01

    Highlights: • An improved design of coal pre-drying using flue gas waste heat was proposed. • 0.4% energy efficiency increase was achieved with the proposed system. • The additional net economic benefit of the proposed system is $1.91 M per year. • Proposed concept can be widely applied to improve coal-fired power plant efficiency. - Abstract: Low-temperature pre-drying (LTPD) of lignite has been identified as an effective approach to improve the efficiency of lignite fired power plants. In this study, an improved concept for the pre-drying of medium moisture bituminous coals using flue gas waste heat was proposed and its feasibility was assessed. In the proposed configuration, the boiler exhaust flue gas is drawn to dryers to heat and pre-dry the raw coal, removing a large proportion of the coal moisture and leading to an improvement in the energy efficiency of the power plant. Thermodynamic analysis and economic evaluation were performed based on a typical 1000 MW bituminous coal fired power plant incorporating the proposed LTPD concept. The results showed that the net power plant efficiency gain is as much as 0.4 percentage point with additional net power output of 9.3 MW as compared to the reference plant without coal pre-drying. This was attributed to the reduction in the moisture content from 10.3 to 2.7 wt%. The additional net economic benefit attained due to the coal pre-drying was estimated to reach $1.91 M per year. This work provides a broadly applicable and economically feasible approach to further improve the energy efficiency of power plants firing coals with medium moisture contents.

  8. Mathematical simulation of gas pressure in fibre-reinforced concrete container at radiation and biological decomposition of cellulose, bituminized and concrete radwastes

    International Nuclear Information System (INIS)

    Kuruc, J.; Kvito, P.

    2005-01-01

    Fibre-reinforced concrete container (FRCC) are used for long-time repository of radioactive wastes. Low- and middle-active radwastes from operation of the NPPs V-1, V-2 Jaslovske Bohunice, Mochovce NPP and from decommissioned NPP A-1 (Jaslovske Bohunice) are treated in the plant SE-VYZ in Jaslovske Bohunice and after immobilisation are deposited in National Radwaste Repository Mochovce (RU RAO). After filling of the RU RAO, FRCC will be stored during 300 years. During this time the integrity of the FRCC must be guaranteed. By the influence of autoradiolysis of the cellulose and bituminized radwastes as well as in cement grout the gases are formed, mainly the hydrogen, methane and carbon dioxide. In the case of presence of available water (a w ≥ 0.63) and in presence of microbes and moulds at appropriate conditions the biological decomposition of cellulose materials may proceed with formation of H 2 , CH 4 a CO 2 . With increasing of developed gases may increase pressure in FRCC, that may initiate the loss of integrity of the FRCC with following endangering of radiation safety of the RU RAO, respectively of the territory over the repository.Authors developed the new mathematical model of pressure of gases in FRCC and in deposited barrels with cellulose and bituminized radwastes. The mathematical model is based on biological decomposition of cellulose materials as well as on radiation decomposition of cellulose, bitumen and concrete. In this mathematical model the diffusion through the walls of FRCC is the main process responsible for decreasing of the pressure. This model was developed in two basic variants: (1) Mathematical model of gas pressure in FRCC as function of dose; (2) Mathematical model of gas pressure in FRCC as function of mass of cellulose

  9. Comparative study of test methods for bituminized and other low- and medium-level solidified waste materials

    International Nuclear Information System (INIS)

    Brodersen, K.; Mose Pedersen, B.; Vinther, A.

    1983-12-01

    Various aspects of the behaviour of bituminized or cemented simulated low- or medium-level radioactive waste in contact with water or salt solutions have been investigated. The solubility (approximately 0.5%) and the diffusion coefficient (approximately 5.10 -8 cm 2 /sec) determining transort of water in pure bitumen have been measured for Mexphalte 40/50 at room temperature. A weighing method has been used to study water uptake and swelling of bituminized sodium nitrate, sodium sulphate or cation-exchange resin. The swelling of samples in contact with water was in some cases very pronounced. In strong salt solutions the tendency to swell is much less. The particle size of the embedded waste material is an important parameter. Thermal pre-treatment of cation-exchange resin before bituminization does not seem to improve the quality of the final product. The interaction between bituminized-exchange resin and concrete barrier materials has been studied. Microbial degradation of bitumen and bituminized waste under aerobic conditions has been investigated. It is probably of minor importance as far as leaching is concerned. A method for measuring leaching from a plane surface of cemented waste has been developed. The method avoids the problem of cracks between the sample and the container. Leaching from cemented sodium nitrate or sulphate was investigated. Absorption of CO 2 from the atmosphere was found to have only minor effect on Cs- and Na-leaching but gave a pronounced decrease in Ca-leaching. The use of silica-fume as an additive to cemented sodium nitrate decreased the leach rate by a factor 4. (author)

  10. Bituminization of simulated waste, spent resins, evaporator concentrates and animal ashes by extrusion process

    International Nuclear Information System (INIS)

    Grosche Filho, C.E.; Chandra, U.

    1987-01-01

    The results of the study of bituminization of simulated radwaste - spennt ion-exchange resins, borate evaporator/concentrates and animal ashes, are presented and discussed. Distilled and oxidizer bitumen were used. Characterization of the crude material and simulated wastes-bitumen mixtures of varying weigt composition (30, 40, 50, 60% by weight of dry waste material) was carried out. The asphaltene and parafin contents in the bitumens were also determined. Some additives and were used with an aim to improve the characteristcs of solidified wastes. For leaching studies, granular ion-exchange resins were with Cs - 134 and mixtures of resin-bitumen were prepared. The leaching studies were executed using the IAEA recommendation and the ISO method. A conventional screw-extruder, common in plastic industry, was used determine operational parameters and process difficulties. Mixtures of resin-bitumen and evaporator concentrate-bitumen obtained from differents operational conditions were characterized. (Author) [pt

  11. Influence of Antioxidant-Enhanced Polymers in Bitumen Rheology and Bituminous Concrete Mixtures Mechanical Performance

    Directory of Open Access Journals (Sweden)

    Samer Dessouky

    2015-01-01

    Full Text Available This paper evaluates the effect of polymer enhancement with antioxidant in the rheological properties of bitumen and mechanical properties of bituminous concrete mixture (BCM. In this study, two antioxidant-enhanced polymers were utilized in mitigating bitumen hardening due to aging. The rheological testing consists of temperature sweep using Dynamic Shear Rheometer at various aging conditions. Critical stiffness temperature data from the sweep test suggested that enhanced polymer exhibits less long-term hardening and brittleness compared to standard polymer. The mechanical testing consists of dynamic modulus, indirect tensile, flow number, and beam fatigue tests on BCM exposed to short-term aging. Hamburg wheel tracking test was also performed to assess moisture-damage susceptibility. It is found that the enhanced-polymer BCM exhibited higher modulus, higher tensile strength ratio, improved rutting resistance, lower moisture-damage susceptibility, and slightly increased fatigue life as compared to standard-polymer BCM.

  12. Study of Rheological Properties of Bituminous Binders in Middle and High Temperatures

    Directory of Open Access Journals (Sweden)

    Remišová Eva

    2016-05-01

    Full Text Available The bitumen binders in road pavements are exposed traffic loading effect at different climatic conditions. A resistance to these stresses depends on bitumen properties as well. The paper presents rheological properties (G*, δ, ν* determined and compared for four bituminous binders (unmodified and polymer modified bitumen at temperature 46 – 60 (80 °C and dynamic viscosity at temperature 130 – 190 °C (Brookfield viscometer. On the basis of viscosity results it is possible to set optimal production and compaction temperatures. Elastic and viscous behavior of binder in the middle temperature is determined in rheometers. The higher value of complex modulus, the stiffer bitumen binder is able to resist deformation. The greater content of elastic components (e.g. polymer in bitumen varies mainly elastic-viscous properties of primary bitumen.

  13. Development of advanced air-blown entrained-flow two-stage bituminous coal IGCC gasifier

    Directory of Open Access Journals (Sweden)

    Abaimov Nikolay A.

    2017-01-01

    Full Text Available Integrated gasification combined cycle (IGCC technology has two main advantages: high efficiency, and low levels of harmful emissions. Key element of IGCC is gasifier, which converts solid fuel into a combustible synthesis gas. One of the most promising gasifiers is air-blown entrained-flow two-stage bituminous coal gasifier developed by Mitsubishi Heavy Industries (MHI. The most obvious way to develop advanced gasifier is improvement of commercial-scale 1700 t/d MHI gasifier using the computational fluid dynamics (CFD method. Modernization of commercial-scale 1700 t/d MHI gasifier is made by changing the regime parameters in order to improve its cold gas efficiency (CGE and environmental performance, namely H2/CO ratio. The first change is supply of high temperature (900°C steam in gasifier second stage. And the second change is additional heating of blast air to 900°C.

  14. Development of advanced air-blown entrained-flow two-stage bituminous coal IGCC gasifier

    Science.gov (United States)

    Abaimov, Nikolay A.; Ryzhkov, Alexander F.

    2017-10-01

    Integrated gasification combined cycle (IGCC) technology has two main advantages: high efficiency, and low levels of harmful emissions. Key element of IGCC is gasifier, which converts solid fuel into a combustible synthesis gas. One of the most promising gasifiers is air-blown entrained-flow two-stage bituminous coal gasifier developed by Mitsubishi Heavy Industries (MHI). The most obvious way to develop advanced gasifier is improvement of commercial-scale 1700 t/d MHI gasifier using the computational fluid dynamics (CFD) method. Modernization of commercial-scale 1700 t/d MHI gasifier is made by changing the regime parameters in order to improve its cold gas efficiency (CGE) and environmental performance, namely H2/CO ratio. The first change is supply of high temperature (900°C) steam in gasifier second stage. And the second change is additional heating of blast air to 900°C.

  15. Fixed-bed gasification research using US coals. Volume 9. Gasification of Elkhorn bituminous coal

    Energy Technology Data Exchange (ETDEWEB)

    Thimsen, D.; Maurer, R.E.; Pooler, A.R.; Pui, D.; Liu, B.; Kittelson, D.

    1985-05-01

    A single-staged, fixed-bed Wellman-Galusha gasifier coupled with a hot, raw gas combustion system and scrubber has been used to gasify numerous coals from throughout the United States. The gasification test program is organized as a cooperative effort by private industrial participants and governmental agencies. The consortium of participants is organized under the Mining and Industrial Fuel Gas (MIFGa) group. This report is the ninth volume in a series of reports describing the atmospheric pressure, fixed-bed gasification of US coals. This specific report describes the gasification of Elkhorn bituminous coal. The period of gasificastion test was September 13 to October 12, 1983. 9 refs., 24 figs., 35 tabs.

  16. Application of laser microprobe (LAMMA 1000) to "fingerprinting" of coal constituents in bituminous coal

    Science.gov (United States)

    Lyons, P.C.; Hercules, D.M.; Morelli, J.J.; Sellers, G.A.; Mattern, D.; Thompson-Rizer, C. L.; Brown, F.W.; Millay, M.A.

    1987-01-01

    A laser microprobe (LAMMA-1000) microchemical analysis of vitrinites of different morphologies but similar reflectances within the same bituminous coal bed indicates distinct "fingerprint" spectra. The banded form of vitrinite contains Li, Ti, Ba, Sr, F, and Cl which were not detected in the nonbanded vitrinite. These differences may indicate a different plant source or the introduction of these elements from fluids mobilized during diagenesis. The nonbanded vitrinite (called corpocollinite), which was contained in a pyrite coal-ball seed fern permineralization of Myeloxylon, may have been protected from influx of these elements due to entrapment by pyrite during an early peat stage. An ion at M/Z 65, which is characteristic of the banded vitrinite, may indicate C5H5+ and, perhaps a difference in the chemical structure of the two vitrinites. These results demonstrate that "fingerprint" spectra can be obtained from vitrinite macerals by LAMMA and that these "fingerprints" have genetic implications. ?? 1987.

  17. Distribution of inorganic and organic substances in the hydrocyclone separated Slovak sub-bituminous coal

    Energy Technology Data Exchange (ETDEWEB)

    Anton Zubrik; Slavomir Hredzak; Ludmila Turcaniova; Michal Lovas; Ingo Bergmann; Klaus Dieter Becker; Maria Lukcova; Vladimir Sepelak [Slovak Academy of Sciences, Kosice (Slovakia). Institute of Geotechnics

    2010-08-15

    A low-rank Slovak sub-bituminous coal from the Handlova deposit was physically treated by washing in a water-only cyclone with the goal to find the separation effect for inorganic (mainly Fe-bearing minerals) and organic substances (humic acids, diterpanes). A high-quality coal product with the ash content in the dry matter of 9.02% and carbon content of C{sup d} = 68.12% at a mass yield of 29.51% was obtained using the water-only cyclone processing. At first, the physically treated coal samples were detailed characterized by XRD, {sup 57}Fe Moessbauer spectroscopy, FT-IR and HR-TEM. In addition to non-crystalline organic coal components, inorganic compounds belonging to silicate minerals (kaolinite, muscovite and quartz) as well as to Fe-bearing sulphide minerals (pyrite) were identified in the sub-bituminous coal by XRD. {sup 57}Fe Moessbauer spectroscopy detected the presence of iron carbonate (siderite), iron-containing clay mineral and two sulphur-containing minerals (pyrite, jarosite) in the untreated coal. On the other hand, only one Fe-bearing mineral, (pyrite) was found in the washed coal. Effect of the physical separation is also demonstrated in FT-IR spectra, where the peak at 1040 cm{sup -1} representing the silicate component in the untreated sample is not detectable in the washed coal sample. Presence of extractive organic substances, i.e. humic acids and tetracyclic diterpane (16a(H)-phyllocladane), in the hydrocyclone products is also evidenced. It was confirmed that the isolated diterpenoic compound is attendant in the washed product with the lowest ash content and it is assimilated with the organic part of coal. Surprisingly, humic acids were found in the highest concentration in the slurry that has the highest content of ash (63.14%). 54 refs., 8 figs., 5 tabs.

  18. The Structure of Sandstones in Productive Horizons of the Permian Bituminous Deposits of Tatarstan (Russia

    Directory of Open Access Journals (Sweden)

    R.R. Khasanov

    2017-03-01

    Full Text Available The features of sandstones in productive horizons of the Permian bituminous deposits of Tatarstan (Russia have been considered. The composition and internal structure of sandstones have been studied by optical microscopy, electron paramagnetic resonance (EPR, and electron microscopy, as well as using a number of physical and chemical methods to solve special problems. The investigated sandstones belong to the greywacke group. The clastic material of sandstones contains grains of feldspar, quartz, mica, and particles of volcanic rocks. The nature and composition of cement are important parameters that determine the filtration-capacity properties of sedimentary rocks. Bituminous deposits are characterized by vertical zoning, which is expressed in the alternation of sites with varying degrees of cementation of rocks. Atten-tion has been also paid to post-sedimentation processes, such as pyritization and calcification. Pyrite forms rare xenomorphic isometric grains. The formation of pyrite occurs in diagenesis and is associated with the processes of biogenic sulfate reduction. The source of calcium for the crystallization of dispersed cal-cite in the porous space of sandstones is the underground waters of red-colored Ufimian deposits characterized by the alkaline properties favorable for calcium migration. According to the data of X-ray computed tomography, the internal space of the studied rocks is not homogeneous and represented by a system of communicated and isolated pores. In the studied samples, two types of organic matter differing in organic radicals have been detected. The first type is an organic substance of coal origin. The second type of organic matter belongs to the oil origin and refers to bitumens in its properties. The presence of a significant percentage of asphaltenes in the bitumen composition indicates the destruction of the oil substance in the near-surface conditions.

  19. DEPOSITIONAL ENVIRONMENT AND ORGANIC GEOCHEMICAL CHARACTERISTICS OF LOWER EOCENE BITUMINOUS ROCKS, IN THE KÜRNÜÇ/GÖYNÜK-BOLU AREA

    Directory of Open Access Journals (Sweden)

    Ali SARI

    2016-12-01

    Full Text Available In this study, dark gray and dark brown colored, organic-carbon rich bituminous rocks (bituminous marl and bituminous shale exposing around the Kürnüç area (Göynük, Bolu are investigated by means of or- ganic geochemical characteristics. In this respect, rock lithologies, depositional environments, rock source potential, kerogen and organic maturity types and hydrocarbon generation potentials of bituminous rocks were determined. For this reason, pyrolysis (Rock Eval–VI analysis, gas chromatography (GC and gas chromatography-mass spectrometer (GC-MS analyses were carried out. In addition, spore color index (SCI was determined with organic petrographic method and stable carbon analysis (δ13C of the samples were also conducted. Lithology of the studied samples is of clastic source and the depositional environ- ment is a lagoon with a partial connection to the sea. In bituminous rocks with excellent source rock potential TOC values are in the range of 2.52-8.38 wt % (average 6.08 wt %. With the exception of two samples (Type II kerogen type of all samples is Type I. According to pyrolysis, GC and GC-MS organic maturity results, all the samples are in immature stage. Organic geochemical data indicate that bituminous rocks have an excellent oil generation potential and there is no organic contamination.

  20. Processing of a Silesian bituminous coal tar mixture at 600 atm to heavy oil excess in a 10-liter oven

    Energy Technology Data Exchange (ETDEWEB)

    Hupfer, H.

    1942-10-28

    An analysis was made of a bituminous coal tar mixture for consideration as raw material for Blechhammer. A breakdown of the composition and yield charts is provided. A table compared it to a coke tar pitch and a bituminous tar mixture from a different carbonization process and its yields were approximately between the yield values of these two. Although the sludge extraction produced sufficient yields in the experiment, the yields would not be as good within full-scale industry. A day by day progress description of the experimentation is provided including all operational details. The experimental results and the pros and cons are summarized briefly. Fifteen tables of data provide analysis of all the elements tested.

  1. Fuel-oils from co-pyrolysis of scrap tyres with coal and a bituminous waste. Influence of oven configuration

    OpenAIRE

    Acevedo Muñoz, Beatriz; Barriocanal Rueda, Carmen

    2014-01-01

    Two wastes from the tyre recycling industry – the fibers used as reinforcing material and tyre crumbs – were pyrolyzed in two ovens of different configuration. Blends with a low rank coal and a bituminous waste were also prepared to modify the composition of the oils obtained from the pyrolysis of the tyre wastes. Elemental analysis, calorific value, Fourier transform infrared spectroscopy (FTIR) and gas chromatography were used to determine the oil composition. A comparative study taking int...

  2. Catalytic Two-Stage Liquefaction (CTSL) process bench studies with bituminous coal. Final report, [October 1, 1988--December 31, 1992

    Energy Technology Data Exchange (ETDEWEB)

    Comolli, A.G.; Johanson, E.S.; Karolkiewicz, W.F.; Lee, L.K.; Stalzer, R.H.; Smith, T.O.

    1993-03-01

    Reported herein are the details and results of Laboratory and Bench-Scale experiments using bituminous coal concluded at Hydrocarbon Research, Inc., under DOE contract during the period October 1, 1988 to December 31, 1992. The work described is primarily concerned with the application of coal cleaning methods and solids separation methods to the Catalytic Two-Stage Liquefaction (CTSL) Process. Additionally a predispersed catalyst was evaluated in a thermal/catalytic configuration, and an alternative nickel molybdenum catalyst was evaluated for the CTSL process. Three coals were evaluated in this program: Bituminous Illinois No. 6 Burning Star and Sub-bituminous Wyoming Black Thunder and New Mexico McKinley Mine seams. The results from a total of 16 bench-scale runs are reported and analyzed in detail. The tests involving the Illinois coal are reported herein, and the tests involving the Wyoming and New Mexico coals are described in Topical Report No. 1. On the laboratory scale, microautoclave tests evaluating coal, start-up oils, catalysts, thermal treatment, CO{sub 2} addition and sulfur compound effects are reported in Topical Report No. 3. Other microautoclave tests, such as tests on rejuvenated catalyst, coker liquids, and cleaned coals, are described in the Bench Run sections to which they refer. The microautoclave tests conducted for modelling the CTSL process are described in the CTSL Modelling section of Topical Report No. 3 under this contract.

  3. Utilization of Waste Clay from Boron Production in Bituminous Geosynthetic Barrier (GBR-B Production as Landfill Liner

    Directory of Open Access Journals (Sweden)

    Müfide Banar

    2016-01-01

    Full Text Available Bituminous geomembranes, one type of geosynthetics, include a hot bituminous mixture with mineral filler and reinforcement. In this study, boron production waste clay (CW was used as filler to produce a geosynthetic barrier with bentonite, waste tire, and bitumen. Bentonite and waste tires were used as auxiliary fillers and bitumen as the binder. CW/bitumen, CW/bentonite/bitumen, and CW/waste tire/bitumen mixtures were prepared by using a laboratory mixer at 100°C. Hot mixtures were extruded into strips by using a lab-scale corotating twin screw extruder (L/D: 40 followed by die casting (2 mm × 100 mm. Glass fleece or nonwoven polyester was used as reinforcement material and while die casting, both sides of the reinforcement materials were covered with bituminous mixture. Thickness, mass per unit area, tensile strength, elongation at yield, and hydraulic conductivity were used to characterize the geomembranes. Among all geomembranes, nonwoven polyester covered with 30% bitumen-70% boron waste clay mixture (PK-BTM30CW70 was found to be the most promising in terms of structure and mechanical behaviour. After that, consequences of its exposure to distilled water (DW, municipal solid waste landfill leachate (L-MSW, and hazardous waste landfill leachate (L-HW were examined to use for an innovative impermeable liner on solid waste landfills.

  4. Potential of water-washing of rape straw on thermal properties and interactions during co-combustion with bituminous coal.

    Science.gov (United States)

    Ma, Qiulin; Han, Lujia; Huang, Guangqun

    2017-06-01

    The aim of this work was to study the thermal properties and interactions during co-combustion of rape straw (RS) before and after water-washing with bituminous coal. A series of experiments was conducted to investigate the properties and interactions during co-combustion of RS with bituminous coal (at 10, 20, 40 and 60% RS). The feasibility and potential of water-washing as an RS pre-treatment was also explored. Reactivity and the amount of heat released followed a quadratic trend, while changes to the degree of interactions between the fuels conformed to a cosine curve. Water-washing increased the ignition and burn-out temperatures and slightly decreased reactivity. Demineralization negatively affected the previously synergistic co-firing relationship, nevertheless, the amount of heat released increased by 10.28% and the average activation energy (146kJ/mol) was lower than that of the unwashed blend (186kJ/mol). Overall, water-washing of RS could prove a useful pre-treatment before co-combustion with bituminous coal. Copyright © 2017 Elsevier Ltd. All rights reserved.

  5. Assessment of an Impulse GPR Antenna Abilities in Investigation of Transversal Cracks of the Bituminous Pavement

    Science.gov (United States)

    Krysiński, L.; Sudyka, J.

    2012-04-01

    Ground Penetrating Radar (GPR) technique is commonly used for detection of internal singularities of construction structure. The method is particularly efficient in the case of linear horizontal objects when profile scanning is being performed in the direction perpendicular to object elongation and polarization of the electric field is parallel to the elongation. Then the singular object manifests itself in the echogram as a scattering hyperbola. Similar response is generated by an object having shape close to a vertical half plane with horizontal edge, when the edge acts like the scattering linear object. The use of GPR technique for investigation of transversal cracks in the bituminous pavement would seem to be promising, but numerous paradoxes occur just at the beginning tests. Even well visible cracks of more than ten millimeters thickness doesn't generate noticeable GPR response, while thinner ones sometimes can produce strong response but in the deeper interior of the pavement. Thus arise a more general question: what the GPR technique can tell us about the cracks? Trying to study this problem some laboratory tests were performed to estimate efficiency of signal generation by structures simulating idealized cracks' shapes. Next long-term (several years) visual observation and repeated GPR scanning was performed on the three road sections (each one of several hundred meters length) with heavy traffic, where ongoing cracking process occurs. The preliminary measurements were directed to obtain the proper way of scanning. The main aim of the analysis was to find GPR characteristics of cracks that can be noticed on echograms. It was performed by detailed correlation of the visually observed cracks position with echograms using decimeter precision. These efforts provided a list of diagnostic GPR characteristics of cracks and some provisional scale of their intensity. In several cases the cracks were probed by drillings to recognize structures responsible for signal

  6. Relations among pH, sulfate, and metals concentrations in anthracite and bituminous coal-mine discharges, Pennsylvania

    Science.gov (United States)

    Cravotta, III, Charles A.

    2006-01-01

    Water-quality data for discharges from 140 abandoned mines in the Bituminous and Anthracite Coalfields of Pennsylvania illustrate relations among pH, sulfate, and dissolved metal concentrations. The pH for the 140 samples ranged from 2.7 to 7.3, with two modes at pH 2.5 to 4 (acidic) and 6 to 7 (near neutral). Generally, flow rates were smaller and solute concentrations were greater for low-pH samples; flow rates increased with pH. Although the pH distribution was similar for the bituminous and anthracite subsets, the bituminous discharges had smaller median flow rates, greater concentrations of sulfate, iron, and aluminum, and smaller concentrations of barium and lead than anthracite discharges with the same pH values. The observed relations between the pH and constituent concentrations can be attributed to (1) dilution of acidic water by alkaline ground water; (2) solubility control of aluminum, iron, manganese, barium, and lead by hydroxide, sulfate, and/or carbonate minerals; and (3) aqueous sulfate-complex formation. The formation of AlSO4+ and AlHSO4+2 complexes adds to the total dissolved aluminum concentration at pH of equilibrium with aluminum hydroxide or hydroxysulfate minerals and can account for 10 to 20 times greater concentrations of dissolved aluminum in bituminous discharges compared to anthracite discharges at similar pH. Sulfate complexation also can account for 10 to 30 times greater concentrations of dissolved ferric iron concentrations at equilibrium with ferrihydrite (Fe(OH)3) and/or schwertmannite (Fe8O8(OH)4.5(SO4)1.75) at pH of 3 to 5. In contrast, lower barium and lead concentrations in bituminous than anthracite discharges indicates elevated sulfate concentration could decrease mobility of these metals by the formation of insoluble minerals such as barite (BaSO4) or anglesite (PbSO4). Most samples were saturated with barite, but none were saturated with anglesite. Hence, lead concentrations could be controlled by coprecipitation with

  7. Controls on coalbed methane potential and gas sorption characteristics of high-volatile bituminous coals in Indiana

    Science.gov (United States)

    Solano-Acosta, Wilfrido

    The increasing demand for energy and a growing concern for global warming, owing in part to the steep rise in anthropogenic greenhouse gas emissions, have sparked worldwide interest in clean coal technologies. Although the energy potential of coal is large, there are many environmental concerns associated with its large-scale utilization. An alternative solution to increasing demand for energy is the recovery of coalbed methane (CBM), an efficient and clean fossil fuel associated with extensive coal deposits. CBM today represents nearly 10 percent of the energy consumed in the United States. From an environmental perspective, coal beds that are too deep or that contain low-quality coal are being investigated as potential sites for permanently sequestering carbon dioxide emissions (CO2 sequestration). Methane has been documented in coals of various ranks. The occurrence and distribution of economically recoverable quantities of CBM result from the interplay between stratigraphy, tectonics, and hydrology. This study evaluates geologic factors that control the occurrence of CBM in Indiana coals, ranging from large-scale processes (i.e., burial and fracturing) to molecular interactions between CBM and the physical structure of coal (i.e., gas adsorption). This study investigates the role of tectonics and burial in the formation of coal fracture sets (cleats) that are critical for CBM extraction. Based on field data, I investigate the role of fracturing with regard to gas occurrence and CBM producibility. The timing of cleat formation is evaluated via carbon and oxygen isotopic signatures of cleat-filling minerals. In addition to field-scale observations, this study includes an experimental component that, based on a multitude of laboratory data, constrains optimum conditions for coal-sample preservation prior to laboratory analyses for exploration. Chemical analyses, petrography, grain-size distributions, Fourier transform infra-red (FTIR) spectroscopy, pore

  8. Contribution to physico-chemical study of Timahdit bituminous schists (Morocco): Organic matters and metalloporphyrins

    International Nuclear Information System (INIS)

    Saoiabi, A.

    1982-01-01

    The Timahdit bituminous schists have been analysed by different methods. The experimental results obtained using these methods concern the behaviour of the schists and the Kerogen facing the pyrolysis, as well as the separation of the hydrocarbons and the metalloporphyrins. For this purpose the techniques used are: 'Rock Eval' pyrolysis, thermogravimetric analysis and electron paramagnetic resonance (E.P.R.) for the raw rock and the Kerogen; infrared (I.R.), gas chromatography and E.P.R. for the extracted organic matters; E.P.R., I.R., nuclear magnetic resonance (N.M.R.), ultraviolet (U.V.) and mass spectrometry for the metalloporphyrins identification and characterization. The analysis of these schists has shown that: We can extract per solvent only 1% of organic matters, ferric oxide hasn't any effect neither on the pyrolysis nor on the organic matters extraction and that the Kerogen of these schists are relatively rich in hydrocarbonic compounds. The gas chromatography reveal the presence of alkanes with odd number of carbons and isoprenoids. All these criteria indicate an immature, little developped organic matter which having probably a marine origin but possessing a good oil potential. It has also been observed that a part of Iron, Nickel and Vanadium in the schists are incorporated into the organic matters. Nickel and Vanadium are into macrocycles which are porphyrins. A method for extracting and separating these porphyrins has been developped. 43 figs., 21 tabs., 58 refs. (author)

  9. Note on the chemical composition of the asphalts of bituminous coal hydrogenation

    Energy Technology Data Exchange (ETDEWEB)

    Boente, L.

    1942-10-13

    This report was written not as a result of extensive unified experiments, but as a result of collected observations during the course of various investigations. It interpreted two of the major groups of constituents of the asphalts from hydrogenation of bituminous coal as the following: (1) highly condensed aromatics (including heterocyclic compounds with oxygen, nitrogen, or sulfur in the rings) (a) in dehydrogenated form, or (b) in partially hydrogenated form, and (2) reaction products from labile, partially hydrogenated highly condensed aromatics (a) through oxidation reactions, or (b) through condensation and polymerization reactions. These types of compounds seemed to come from rather symmetric precursors that were not split during pressure hydrogenation, as were most constituents of coal, but were dehydrogenated instead. The types of compounds mentioned above shared several properties with the asphalts, including precipitation and adsorption properties. Some examples given of Group 1 compounds were coronene and several derived from it, as well as napthoxanthene, carbazole, and diphenylene sulfide. One example given to illustrate Group 2 was some hypothetical reactions of a proposed hexakeideca-hydrocoronene.

  10. Co-gasification of bituminous coal and hydrochar derived from municipal solid waste: Reactivity and synergy.

    Science.gov (United States)

    Wei, Juntao; Guo, Qinghua; He, Qing; Ding, Lu; Yoshikawa, Kunio; Yu, Guangsuo

    2017-09-01

    In this work, the influences of gasification temperature and blended ratio on co-gasification reactivity and synergy of Shenfu bituminous coal (SF) and municipal solid waste-derived hydrochar (HTC) were investigated using TGA. Additionally, active alkaline and alkaline earth metal (AAEM) transformation during co-gasification was quantitatively analyzed by inductively coupled plasma optical emission spectrometer for correlating synergy on co-gasification reactivity. The results showed that higher char gasification reactivity existed at higher HTC char proportion and gasification temperature, and the main synergy behaviour on co-gasification reactivity was performed as synergistic effect. Enhanced synergistic effect at lower temperature was mainly resulted from more obviously inhibiting the primary AAEM (i.e. active Ca) transformation, and weak synergistic effect still existed at higher temperature since more active K with prominent catalysis was retained. Furthermore, more active HTC-derived AAEM remaining in SF sample during co-gasification would lead to enhanced synergistic effect as HTC char proportion increased. Copyright © 2017 Elsevier Ltd. All rights reserved.

  11. Recycling of polyethylene terephthalate (PET plastic bottle wastes in bituminous asphaltic concrete

    Directory of Open Access Journals (Sweden)

    Adebayo Olatunbosun Sojobi

    2016-12-01

    Full Text Available This research sheds light on the concept of eco-friendly road construction which comprises eco-design, eco-extraction, eco-manufacturing, eco-construction, eco-rehabilitation, eco-maintenance, eco-demolition, and socioeconomic empowerment. It also revealed the challenges being faced in its adoption and the benefits derivable from its application. Furthermore, the effects of recycling PET plastic bottle wastes produced in North Central Nigeria in bituminous asphaltic concrete (BAC used in flexible pavement construction were also evaluated. The mix design consists of 60/70 penetration-grade asphaltic concrete (5%, 68% coarse aggregate, 6% fine aggregate, and 21% filler using the dry process at 170°C. The optimum bitumen content (OBC for conventional BAC was obtained as 4% by weight of total aggregates and filler. Polymer-coated aggregate (PCA-modified BAC seems preferable because it has the potential to utilize more plastic wastes with a higher optimum plastic content (OPC of 16.7% by weight of total aggregates and filler compared to that of 9% by weight of OBC achieved by PMB-BAC. For both PMB- and PCA-modified BAC, an increase in air void, void in mineral aggregate, and Marshall stability were observed. Eco-friendly road construction which recycles PET wastes should be encouraged by government considering its potential environmental and economic benefits.

  12. Temperature induced development of porous structure of bituminous coal chars at high pressure

    Directory of Open Access Journals (Sweden)

    Natalia Howaniec

    2016-01-01

    Full Text Available The porous structure of chars affects their reactivity in gasification, having an impact on the course and product distribution of the process. The shape, size and connections between pores determine the mechanical properties of chars, as well as heat and mass transport in thermochemical processing. In the study the combined effects of temperature in the range of 973–1273 °K and elevated pressure of 3 MPa on the development of porous structure of bituminous coal chars were investigated. Relatively low heating rate and long residence time characteristic for the in-situ coal conversion were applied. The increase in the temperature to 1173 °K under pressurized conditions resulted in the enhancement of porous structure development reflected in the values of the specific surface area, total pore volume, micropore area and volume, as well as ratio of the micropore volume to the total pore volume. These effects were attributed to the enhanced vaporization and devolatilization, as well as swelling behavior along the increase of temperature and under high pressure, followed by a collapse of pores over certain temperature value. This proves the strong dependence of the porous structure of chars not only on the pyrolysis process conditions but also on the physical and chemical properties of the parent fuel.

  13. Relation Between Bitumen Content and Percentage Air Voids in Semi Dense Bituminous Concrete

    Science.gov (United States)

    Panda, R. P.; Das, Sudhanshu Sekhar; Sahoo, P. K.

    2018-02-01

    Hot mix asphalt (HMA) is a heterogeneous mix of aggregate, mineral filler, bitumen, additives and air voids. Researchers have indicated that the durability of the HMA is sensitive on the actual bitumen content and percentage air void. This paper aims at establishing the relationship between the bitumen content and the percentage air voids in Semi Dense Bituminous Concrete (SDBC) using Viscosity Grade-30 (VG-30) bitumen. Total 54 samples have been collected, for formulation and validation of relationship and observed that the percentage air voids increases with decrease in actual bitumen content and vice versa. A minor increase in percentage air voids beyond practice of designed air voids in Marshall Method of design is required for better performance, indicating a need for reducing the codal provision of minimum bitumen content for SDBC as specified in Specification for Road & Bridges (Fourth Revision) published by Indian Road Congress, 2001. The study shows a possibility of reducing designed minimum bitumen content from codal provision for SDBC by 0.2% of weight with VG-30 grade of Bitumen.

  14. Characteristic Study of Shenmu Bituminous Coal Combustion with Online TG-MS-FTIR

    Science.gov (United States)

    Pan, Guanfu

    2018-01-01

    The combustion characteristics of Shenmu bituminous pulverized coal (SBC) were comprehensively investigated with a combined TG-MS-FTIR system by considering the effect of particle size, heating rate and total flowrate. The combustion products were accurately quantified by normalization and numerical analysis of MS results. The results indicate that the decrease of the particle size, heating rate and total flowrate result in lower ignition and burnout temperatures. The activation energy tends to be lower with smaller particle size, lower heating rate and total flowrate. The MS and FTIR results demonstrate that lower concentrations of different products, such as NO, NO2, HCN, CH4 and SO2 were produced with smaller particle size, slower heating rate and lower total flowrate. The decrease of particle size would lead to more contact area with oxygen and slower heating rate could provide more sufficient time for the diffusion. High total flowrate would reduce the oxygen adsorbability on the coal particle surface and shorten the residence time of oxygen, which makes the ignition difficult to occur. This work will guide to understand the combustion kinetics of pulverized coals and be beneficial to control the formation of pollutants.

  15. Elemental analysis of Indonesian and Australian bituminous coal used at Kapar Power Station

    International Nuclear Information System (INIS)

    Muneer Saleh; Ahmad Suhaimi

    2008-01-01

    An instrumental neutron activation analytical (INAA) technique is used for the determination of thirty elements in five coal samples collected from Kapar power station, imported from Indonesia and Australia. Analyses of the samples are being associated with standards. All irradiation were performed in the nuclear reactor of Malaysia Nuclear Agency (MNA). samples were counted by Hyper Pure Germanium (HPGe) detector for short period irradiations at MNA, while for the long period irradiations the samples were counted at Universiti Kebangsaan Malaysia (UKM). The concentrations of thirty elements have been determined: The major components are Cl, Ca, Mg, K, Fe, Ti, and Na with the mean concentrations in the range between 70±69 ppm-6100±1639 ppm; and the trace elements are Zr, V, Mn, Sc, Cr, Co, As, Br, Rb, Sb, Ba, La, Ce, Nd, Sm, Eu, Tb, Yb, Lu, Hf, Th, U and Ta with the mean concentrations in the range between 0.1381±0.0202 - 69.0±2.8 ppm. The results have been compared to the reported data of eight coal samples from the United States and the reported data of Australian bituminous coal. (Author)

  16. Cigarette smoking and federal black lung benefits in bituminous coal miners.

    Science.gov (United States)

    Roy, T M; Collins, L C; Snider, H L; Anderson, W H

    1989-02-01

    The records of 1000 consecutive coal miners applying for benefits under the Federal Coal Mine Health and Safety Act were examined to determine the contribution of age, dust accumulation, and cigarette smoking to the profile of the miner who satisfies the current pulmonary criteria for disability. Using the presence of pneumoconiosis on chest radiograph as the indication of significant coal dust accumulation, the miners were separated into Group A--those without pneumoconiosis (n = 316) and Group B--those with pneumoconiosis (n = 684). The federal spirometric criteria for disability identified 55/316 miners in Group A (14.5%) and 99/684 miners in Group B (17.4%) potentially eligible for an award (P = .27). The mean ages of miners in both groups did not differ significantly, nor was there difference in the mean ages of groups that did or did not meet the federal criteria. In both groups, those miners potentially eligible for a financial award smoked more cigarettes than did their counterparts (Group A, 31.0 v 18.5 pack-years, P less than .001; Group B, 31.3 v 23.6 pack-years, P less than .001). There was no difference in the smoking histories of the miners from either group who met the federal criteria. Our data indicate that, in the case of bituminous coal miners, the present federal legislation intended to identify and remunerate those who suffer lung impairment from chronic occupational exposure to coal dust is biased in favor of those who sustain additional damage to their ventilatory capacity by smoking cigarettes.

  17. Surface composition of silica particles embedded in an Australian bituminous coal.

    Science.gov (United States)

    Gong, B; Pigram, P J; Lamb, R N

    1999-07-01

    The composition and structure of the surface layers of a series of silica particles (10-20 microns across), embedded in a bituminous coal from the Whybrow seam, Sydney Basin, Australia, have been characterized in situ using time-of-flight secondary ion mass spectrometry (TOFSIMS), ion imaging, and depth profiling. The silica particles investigated are typically encased in a multilayered shell, the composition of which differs from average composition of both the silica and the bulk coal. The analysis directly demonstrates the presence of a silanol-rich (Si-OH) interfacial layer 3 nm in thickness. This silanol-rich region separates the bulk silica and a complex non-silica layer encasing the particles. The interfacial region also shows significant lithium enrichment (approximately fivefold over bulk) which implies diffusion and precipitation of lithium-containing species during the authigenetic formation of the surface layers of the silica grains. The outer layer encasing the silica particles is 10 nm in thickness and is composed of clays and carbonates, and, in some cases, includes organic material. The elemental constituents of this layer include aluminium, sodium, potassium, magnesium, iron, and lesser amounts of titanium and copper. The variation in the aluminium concentration from the outermost surface to the deeper layers is less than that of other non-silica species. A relatively high amount of calcium is found associated with the silica bulk. Although only non-respirable-sized silica particles are examined in this work, the methods of analysis developed have potential in providing an insight into the surface composition of respirable particles and in further studies of the surface bioavailability of silica species.

  18. Analysis of the sensitivity of the impact resonance frequency test as a tool to determine the elastic properties of bituminous materials

    Directory of Open Access Journals (Sweden)

    R. Tauste

    2017-07-01

    Full Text Available The modulus value of bituminous materials is a key factor in the design of road pavements and the estimation of their life service. This parameter can be measured in laboratory but, unfortunately, this requires the deterioration of the pavement so as the consumption of time and resources. Therefore, this study analyses the feasibility of using impact resonance frequency tests as an alternative to traditional methods for determining the dynamic modulus of bituminous mixtures. The sensitivity of this technique has been studied by analyzing its repeatability and reproducibility, studying the variations in the values measured by modifying the dimensions of the specimens, test temperatures and types of mixture tested. In addition, this non-destructive technique has been compared with other traditional tests used to determine the elastic properties of bituminous materials. The results show that this test could be an interesting tool to characterize the properties and damage state of asphalt layers.

  19. Analysis of the sensitivity of the impact resonance frequency test as a tool to determine the elastic properties of bituminous materials

    International Nuclear Information System (INIS)

    Tauste, R.; Moreno-Navarro, F.; Gallego, R.; Rubio-Gámez, M.C.

    2017-01-01

    The modulus value of bituminous materials is a key factor in the design of road pavements and the estimation of their life service. This parameter can be measured in laboratory but, unfortunately, this requires the deterioration of the pavement so as the consumption of time and resources. Therefore, this study analyses the feasibility of using impact resonance frequency tests as an alternative to traditional methods for determining the dynamic modulus of bituminous mixtures. The sensitivity of this technique has been studied by analyzing its repeatability and reproducibility, studying the variations in the values measured by modifying the dimensions of the specimens, test temperatures and types of mixture tested. In addition, this non-destructive technique has been compared with other traditional tests used to determine the elastic properties of bituminous materials. The results show that this test could be an interesting tool to characterize the properties and damage state of asphalt layers. [es

  20. Multinomial logit analysis of injury severity in U.S. underground bituminous coal mines, 1975-1982.

    Science.gov (United States)

    Bennett, J D; Passmore, D L

    1985-10-01

    Relationships among mine and injured miner characteristics and degrees of injury are examined for 91 404 injuries in underground bituminous coal mines in the United States from 1975 through 1982. Injury severity varies by the mining system, geographical region, circumstances surrounding the injury, the injured miner's age, whether the miner was using powered equipment, the year in which the injury occurred and the location in the mine where the injury happened. Injury severity is not related to the injured miner's total mining experience, job experience and experience in the mine in which the injury occurred.

  1. Particle size distribution of fly ash from co-incineration of bituminous coal with municipal solid waste

    Science.gov (United States)

    Cieślik, Ewelina; Konieczny, Tomasz; Bobik, Bartłomiej

    2018-01-01

    One of the source of air pollutants is emission from local coal-fired boiler-houses and domestic heating boilers. The consequence of incineration of municipal waste is the introduction of additional pollutants into the atmosphere, including fly ash. The aim of this work was to evaluate the particle size distribution of fly ash emitted by coal combustion and co-incineration of coal with municipal waste in a domestic 18 kW central heating boiler equipped with an automatic fuel feeder. Mixtures of bituminous coal with different types of solid waste (5, 10 and 15% of mass fraction) were used. Solid waste types consisted of: printed, colored PE caps, fragmented cable trunking, fragmented car gaskets and shredded tires from trucks. During the incineration of a given mixture of municipal waste with bituminous coal, the velocity of exhaust gas was specified, the concentration and mass flow of fly ash were determined together with the physico-chemical parameters of the exhaust gas, the samples of emitted fly ash were taken as the test material. Particle size analysis of fly ash was performed using laser particle sizer Fritch Analysette 22. The PM10 share from all fly ashes from incineration of mixtures was about 100%. Differences were noted between PM2.5 and PM1.

  2. Particle size distribution of fly ash from co-incineration of bituminous coal with municipal solid waste

    Directory of Open Access Journals (Sweden)

    Cieślik Ewelina

    2018-01-01

    Full Text Available One of the source of air pollutants is emission from local coal-fired boiler-houses and domestic heating boilers. The consequence of incineration of municipal waste is the introduction of additional pollutants into the atmosphere, including fly ash. The aim of this work was to evaluate the particle size distribution of fly ash emitted by coal combustion and co-incineration of coal with municipal waste in a domestic 18 kW central heating boiler equipped with an automatic fuel feeder. Mixtures of bituminous coal with different types of solid waste (5, 10 and 15% of mass fraction were used. Solid waste types consisted of: printed, colored PE caps, fragmented cable trunking, fragmented car gaskets and shredded tires from trucks. During the incineration of a given mixture of municipal waste with bituminous coal, the velocity of exhaust gas was specified, the concentration and mass flow of fly ash were determined together with the physico-chemical parameters of the exhaust gas, the samples of emitted fly ash were taken as the test material. Particle size analysis of fly ash was performed using laser particle sizer Fritch Analysette 22. The PM10 share from all fly ashes from incineration of mixtures was about 100%. Differences were noted between PM2.5 and PM1.

  3. Report: Potential environmental impact of exempt site materials - a case study of bituminous road planings and waste soils.

    Science.gov (United States)

    Bark, Marjorie; Bland, Michael; Grimes, Sue

    2009-09-01

    The use of waste materials for ecological benefit, agricultural improvement or as part of construction works are often exempt from waste management control in order to maximize the reuse of material that would otherwise be disposed of to landfill. It is important, however, to determine whether there is potential for such waste to cause environmental harm in the context of the basis for granting exemptions under the relevant framework objective to ensure that waste is recovered or disposed of without risk to water, air, soil, plants or animals. The potential for environmental harm was investigated by leaching studies on two wastes commonly found at exempt sites: bituminous road planings and waste soils. For bituminous road planings, the organic components of the waste were identified by their solubility in organic solvents but these components would have low environmental impact in terms of bioavailability. Leaching studies of the heavy metals copper, lead and zinc, into the environment, under specific conditions and particularly those modelling acid rain and landfill leachate conditions showed that, except for copper, the amounts leached fell within Waste Acceptance Criteria compliance limits for defining waste as inert waste. The fact that the amount of copper leached was greater than the Waste Acceptance Criteria level suggests that either additional testing of wastes regarded as exempt should be carried out to ensure that they are in analytical compliance or that legislation should allow for the potential benefits of reuse to supersede deviations from analytical compliance.

  4. A note on the market potential of low-volatile bituminous coal, Willow Creek property, northeastern British Columbia

    Energy Technology Data Exchange (ETDEWEB)

    Barry Ryan; Ted Todoschuk; Bob Lane [British Columbia Ministry of Energy and Mines, BC (Canada)

    2004-07-01

    The international coking coal market is very competitive and is segmented into many non inter changeable coal products. Two products, that are more in demand than many are, low-volatile bituminous high rank coking coal for blends into coke ovens, and low-volatile bituminous coal for pulverization and injection into blast furnaces (PCI coal). The Willow Creek property contains coal that may be suitable for these two markets. The higher priced market is the low-volatile coking coal market where up to 30% of this coal can be added into coal blends for coke ovens. This is a higher priced market than the PCI market and it is advantageous for mines if possible to switch from the low-volatile PCI market to the low-volatile coking coal market. Low-volatile coking coal is also in short supply as reserves in the US and other countries are running out. This note looks at the possible use of 7 Seam from the Willow Creek property in northeastern British Columbia as a low-volatile component in a standard coke oven blend. The Willow Creek property is located 40 kilometres west of Chetwynd and overlies seams in the Gething Formation. 15 refs., 4 figs., 11 tabs.

  5. Sedimentation technique of waste bituminization and thermogravimetric characteristics of the finalproducts

    International Nuclear Information System (INIS)

    Zeger, J.; Knotik, K.

    1976-01-01

    In the research centre of the Oesterreichische Studiengesellschaft fuer Atomenergie GesmbH a semitechnical plant has been installed for waste bituminization, which has been tested inactively since 1973. This plant is using a new technological process for embedding. One of the important features of this new process is that the, normally inactive solution water is distilled off prior to the embedding, resulting in dry and powdery salts. The second important feature is that the mixing of these dry salts with the thin fluid bitumen is done by sedimentation. Expecially there is no mechanical aid used for mixing. Thermogravimetric analysis of samples which simulated the final products of this pilot plant, were carried out to verify the best working parameters and to study the possible chemical damage to the bitumen. Analysis was performed by heating the samples, consisting of various mixtures of bitumen and inorganic salts, in a METTLER-Thermoanalyzer up to 500 0 C using different atmospheres (air, nitrogen). It could be shown that only nitrate and nitrite especially in combination with Fe(III)-ions are of negative influence on the thermostability of bitumen. They lead to a sudden and quick weight loss of the samples between 370 and 410 0 C (above the melting point of both NaNO 2 and NaNO 3 ). The Fe-ions hava a catalytic influence, as it could be shown that 1 1% addiation of Fe(NO 3 ) 3 to NaNO 3 leads to a considerable acceleration of the incineration. This influence of the Fe(III)-ion can be suppressed to some extend by a hydrolysis prior to the embedding. In preparation of further studies concerning the behaviour of radiation damaged bitumen there has been developed a method of measuring the dose rate of an unknown radioactive salt mixture at any point of this mixture. This is done by making two measurements with glass dosimeters. One with a beta-absorber to get a pure gamma-dose and the other without it to get the combined beta and gamma dose. (author)

  6. Non-catalytic co-gasification of sub-bituminous coal and biomass

    Science.gov (United States)

    Nyendu, Guevara Che

    Fluidization characteristics and co-gasification of pulverized sub-bituminous coal, hybrid poplar wood, corn stover, switchgrass, and their mixtures were investigated. Co-gasification studies were performed over temperature range from 700°C to 900°C in different media (N2, CO2, steam) using a bubbling fluidized bed reactor. In fluidization experiments, pressure drop (Delta P) observed for coal-biomass mixtures was higher than those of single coal and biomass bed materials in the complete fluidization regime. There was no systematic trend observed for minimum fluidization velocity ( Umf) with increasing biomass content. However, porosity at minimum fluidization (εmf) increased with increasing biomass content. Channeling effects were observed in biomass bed materials and coal bed with 40 wt.% and 50 wt.% biomass content at low gas flowrates. The effect of coal pressure overshoot reduced with increasing biomass content. Co-gasification of coal and corn stover mixtures showed minor interactions. Synergetic effects were observed with 10 wt.% corn stover. Coal mixed with corn stover formed agglomerates during co-gasification experiments and the effect was severe with increase in corn stover content and at 900°C. Syngas (H2 + CO) concentrations obtained using CO2 as co-gasification medium were higher (~78 vol.% at 700°C, ~87 vol.% at 800°C, ~93 vol.% at 900°C) than those obtained with N2 medium (~60 vol.% at 700°C, ~65 vol.% at 800°C, ~75 vol.% at 900°C). Experiments involving co-gasification of coal with poplar showed no synergetic effects. Experimental yields were identical to predicted yields. However, synergetic effects were observed on H2 production when steam was used as the co-gasification medium. Additionally, the presence of steam increased H2/CO ratio up to 2.5 with 10 wt.% hybrid poplar content. Overall, char and tar yields decreased with increasing temperature and increasing biomass content, which led to increase in product gas.

  7. Dependence of carbon dioxide sorption on the petrographic composition of bituminous coals from the Czech part of the Upper Silesian Basin, Czech Republic

    Czech Academy of Sciences Publication Activity Database

    Weishauptová, Zuzana; Sýkorová, Ivana

    2011-01-01

    Roč. 90, č. 1 (2011), s. 312-323 ISSN 0016-2361 R&D Projects: GA ČR GA106/08/1146; GA AV ČR IAA300460804 Institutional research plan: CEZ:AV0Z30460519 Keywords : bituminous coal * sorption capacity * maceral composition Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 3.248, year: 2011

  8. Organic petrology and geochemistry of Eocene Suzak bituminous marl, north-central Afghanistan: Depositional environment and source rock potential

    Science.gov (United States)

    Hackley, Paul C.; Sanfilipo, John

    2016-01-01

    Organic geochemistry and petrology of Eocene Suzak bituminous marl outcrop samples from Madr village in north-central Afghanistan were characterized via an integrated analytical approach to evaluate depositional environment and source rock potential. Multiple proxies suggest the organic-rich (TOC ∼6 wt.%) bituminous marls are ‘immature’ for oil generation (e.g., vitrinite Ro extracts with high polar components, consistent with extraction from S-rich Type IIs organic matter which could generate hydrocarbons at low thermal maturity. Low Fe-sulfide mineral abundance and comparison of Pr/Ph ratios between saturate and whole extracts suggest limited Fe concentration resulted in sulfurization of organic matter during early diagenesis. From these observations, we infer that a Type IIs kerogen in ‘immature’ bituminous marl at Madr could be generating high sulfur viscous oil which is seeping from outcrop. However, oil-seep samples were not collected for correlation studies. Aluminum-normalized trace element concentrations indicate enrichment of redox sensitive trace elements Mo, U and V and suggest anoxic-euxinic conditions during sediment deposition. The bulk of organic matter observed via optical microscopy is strongly fluorescent amorphous bituminite grading to lamalginite, possibly representing microbial mat facies. Short chain n-alkanes peak at C14–C16 (n-C17/n-C29 > 1) indicating organic input from marine algae and/or bacterial biomass, and sterane/hopane ratios are low (0.12–0.14). Monoaromatic steroids are dominated by C28clearly indicating a marine setting. High gammacerane index values (∼0.9) are consistent with anoxia stratification and may indicate intermittent saline-hypersaline conditions. Stable C isotope ratios also suggest a marine depositional scenario for the Suzak samples, consistent with the presence of marine foraminifera including abundant planktic globigerinida(?) and rare benthic discocyclina(?) and nummulites(?). Biomarker 2

  9. Analysis of the use of coal tar as a binder in bituminous mixtures, using Marshall and Ramcodes methodologies

    Science.gov (United States)

    Ochoa-Díaz, R.

    2013-11-01

    This paper presents an alternative use of coal tar, a by-product of the steel industry, given the problems of accumulation and negative environmental impact. Therefore, it is necessary to analyze the incorporation of coal tar as a binder in paving mixtures. First, this paper presents the origin, description of the main characteristics, and properties of tar. Then, this paper evaluates the mix of coal tar by means of the RAMCODES and Marshall methodologies to determine its resistance. The results of the tests explain the physical and mechanical properties of the mix. Taking into account the results of both methods, this paper makes a comparison to determine the suitability of the RAMCODES methodology in the mix design. Finally, it analyzes the alternatives to coal tar that can be used as binders in bituminous mixes for pavement and the advantages of their uses under some specific conditions.

  10. Combustion characteristics of Malaysian oil palm biomass, sub-bituminous coal and their respective blends via thermogravimetric analysis (TGA).

    Science.gov (United States)

    Idris, Siti Shawalliah; Rahman, Norazah Abd; Ismail, Khudzir

    2012-11-01

    The combustion characteristics of Malaysia oil palm biomass (palm kernel shell (PKS), palm mesocarp fibre (PMF) and empty fruit bunches (EFB)), sub-bituminous coal (Mukah Balingian) and coal/biomass blends via thermogravimetric analysis (TGA) were investigated. Six weight ratios of coal/biomass blends were prepared and oxidised under dynamic conditions from temperature 25 to 1100°C at four heating rates. The thermogravimetric analysis demonstrated that the EFB and PKS evolved additional peak besides drying, devolatilisation and char oxidation steps during combustion. Ignition and burn out temperatures of blends were improved in comparison to coal. No interactions were observed between the coal and biomass during combustion. The apparent activation energy during this process was evaluated using iso-conversional model free kinetics which resulted in highest activation energy during combustion of PKS followed by PMF, EFB and MB coal. Blending oil palm biomass with coal reduces the apparent activation energy value. Copyright © 2012 Elsevier Ltd. All rights reserved.

  11. Development of new non destructive methods for bituminized radioactive waste drums characterization; Developpement de nouvelles methodes de caracterisation non destructive pour des dechets radioactifs enrobes dans du bitume

    Energy Technology Data Exchange (ETDEWEB)

    Pin, P

    2004-10-15

    Radioactive waste constitute a major issue for the nuclear industry. One of the key points is their characterization to optimize their management: treatment and packaging, orientation towards the suited disposal. This thesis proposes an evaluation method of the low-energy photon attenuation, based on the gamma-ray spectra Compton continuum. Effectively, the {sup 241}Am measurement by gamma-ray spectrometry is difficult due to the low energy of its main gamma-ray (59.5 keV). The photon attenuation strongly depends on the bituminous mix composition, which includes very absorbing elements. As the Compton continuum also depends on this absorption, it is possible to link the 59.5 keV line attenuation to the Compton level. Another technique is proposed to characterize uranium thanks to its fluorescence X-rays induced by the gamma emitters already present in the waste. The uranium present in the drums disturbs the neutron measurements and its measurement by self-induced X-ray fluorescence allows to correct this interference. Due to various causes of error, the total uncertainty is around 50 % on the activity of the radioisotope {sup 241}Am, corrected by the peak to Compton technique. The same uncertainty is announced on the uranium mass measured by self induced X-ray fluorescence. As a consequence of these promising results, the two methods were included in the industrial project of the 'Marcoule Sorting Unit'. One major advantage is that they do not imply any additional material because they use information already present in the gamma-ray spectra. (author)

  12. Bituminous solidification, disposal, transport and burial of spent ion-exchange resins. Part of a coordinated programme on treatment of spent ion exchange resins

    International Nuclear Information System (INIS)

    Mozes, G.; Kristof, M.

    1983-07-01

    The project dealing with the incorporation of spent ion-exchange resins into bitumen was performed within the Agency coordinated research programme on treatment of spent ion-exchange resins. Physical and chemical properties of commercial ion-exchange resins, bitumens and bituminized resins were studied. It was shown that bitumen with low oil content and with a softening point of 60-70 deg. C are applicable for the incorporation of resins. The final waste form is allowed to contain maximum 50% resin. The comprehensive study of the biological resistance of B-30 bitumen was performed. That showed that any bacteriological attack can be regarded as generally insignificant. A continuously operating technology was realized on a semi-plant scale. The best operating conditions of this technology were determined. On the basis of the experience gained from the experiments a design of the bituminization plant of 50m 3 dry resin/year treatment capacity was proposed

  13. Advances in Interlaboratory Testing and Evaluation of Bituminous Materials State-of-the-Art Report of the RILEM Technical Committee 206-ATB

    CERN Document Server

    Bahia, Hussain; Canestrari, Francesco; Roche, Chantal; Benedetto, Hervé; Piber, Herald; Sybilski, Dariusz

    2013-01-01

    This STAR on asphalt materials presents the achievements of RILEM TC 206 ATB, acquired over many years of interlaboratory tests and international knowledge exchange. It covers experimental aspects of bituminous binder fatigue testing; the background on compaction methods and imaging techniques for characterizing asphalt mixtures including validation of a new imaging software; it focuses on experimental questions and analysis tools regarding mechanical wheel tracking tests, comparing results from different labs and using finite element techniques. Furthermore, long-term rutting prediction and evaluation for an Austrian road are discussed, followed by an extensive analysis and test program on interlayer bond testing of three different test sections which were specifically constructed for this purpose. Finally, the key issue of manufacturing reclaimed hot mix asphalt in the laboratory is studied and recommendations for laboratory ageing of bituminous mixtures are given.

  14. Evaluation of bituminous sub-ballast manufactured at low temperatures as an alternative for the construction of more sustainable railway structures

    Directory of Open Access Journals (Sweden)

    L. Pirozzolo

    2017-07-01

    Full Text Available Hot bituminous mixtures are becoming widely used in modern railway tracks in the sub-ballast layer. The reason is that these materials allow for both an increase in bearing capacity and greater protection of the substructure respect the traditional granular sub-ballast. Despite these advantages, the fact that these materials are manufactured at a temperature of 160°C means that their application can lead to an important increase in construction costs, pollution and energy consumption. This paper aims to study the possibility of using WMA manufactured at lower temperatures, as bituminous sub-ballast, in order to save energy and reduce emissions throughout the production process, as well as diminish the global costs of this layer. To this end, this study focuses on a comparison of the mechanical behaviour of warm and hot bituminous mixtures as sub-ballast under various loading conditions. The results indicate that WMA offers mechanical behaviour that is comparable to conventional HMA.

  15. Sphagnum mosses from 21 ombrotrophic bogs in the athabasca bituminous sands region show no significant atmospheric contamination of "heavy metals".

    Science.gov (United States)

    Shotyk, William; Belland, Rene; Duke, John; Kempter, Heike; Krachler, Michael; Noernberg, Tommy; Pelletier, Rick; Vile, Melanie A; Wieder, Kelman; Zaccone, Claudio; Zhang, Shuangquan

    2014-11-04

    Sphagnum moss was collected from 21 ombrotrophic (rain-fed) peat bogs surrounding open pit mines and upgrading facilities of Athabasca bituminous sands in Alberta (AB). In comparison to contemporary Sphagnum moss from four bogs in rural locations of southern Germany (DE), the AB mosses yielded lower concentrations of Ag, Cd, Ni, Pb, Sb, and Tl, similar concentrations of Mo, but greater concentrations of Ba, Th, and V. Except for V, in comparison to the "cleanest", ancient peat samples ever tested from the northern hemisphere (ca. 6000-9000 years old), the concentrations of each of these metals in the AB mosses are within a factor of 3 of "natural, background" values. The concentrations of "heavy metals" in the mosses, however, are proportional to the concentration of Th (a conservative, lithophile element) and, therefore, contributed to the plants primarily in the form of mineral dust particles. Vanadium, the single most abundant trace metal in bitumen, is the only anomaly: in the AB mosses, V exceeds that of ancient peat by a factor of 6; it is therefore enriched in the mosses, relative to Th, by a factor of 2. In comparison to the surface layer of peat cores collected in recent years from across Canada, from British Columbia to New Brunswick, the Pb concentrations in the mosses from AB are far lower.

  16. Utilising neural networks and closed form solutions to determine static creep behaviour and optimal polypropylene amount in bituminous mixtures

    Directory of Open Access Journals (Sweden)

    Serkan Tapkın

    2012-12-01

    Full Text Available The testing procedure in order to determine the precise mechanical testing results in Marshall design is very time consuming. Also, the physical properties of the asphalt samples are obtained by further calculations. Therefore if the researchers can obtain the stability and flow values of a standard mixture with the help of mechanical testing, the rest of the calculations will just be mathematical manipulations. Determination of mechanical testing parameters such as strain accumulation, creep stiffness, stability, flow and Marshall Quotient of dense bituminous mixtures by utilising artificial neural networks is important in the sense that, cumbersome testing procedures can be avoided with the help of the closed form solutions provided in this study. Marshall specimens, prepared by utilising polypropylene fibers, were tested by universal testing machine carrying out static creep tests to investigate the rutting potential of these mixtures. On the very well trained data basis, artificial neural network analyses were carried out to propose five separate models for mechanical testing properties. The explicit formulation of these five main mechanical testing properties by closed form solutions are presented for further use for researches.

  17. Study on co-pyrolysis characteristics of rice straw and Shenfu bituminous coal blends in a fixed bed reactor.

    Science.gov (United States)

    Li, Shuaidan; Chen, Xueli; Liu, Aibin; Wang, Li; Yu, Guangsuo

    2014-03-01

    Co-pyrolysis behaviors of rice straw and Shenfu bituminous coal were studied in a fixed bed reactor under nitrogen atmosphere. The pyrolysis temperatures were 700°C, 800°C and 900°C, respectively. Six different biomass ratios were used. Gas, tar components were analyzed by a gas chromatograph and a gas chromatography-mass spectrometry respectively. Under co-pyrolysis conditions, the gas volume yields are higher than the calculated values. Co-pyrolysis tar contains more phenolics, less oxygenate compounds than calculated values. The addition of biomass changes the atmosphere during the pyrolysis process and promotes tar decomposition. The SEM results show that the differences between the blended char and their parents char are not significant. The results of char yields and ultimate analysis also show that no significant interactions exist between the two kinds of particles. The changes of gas yield and components are caused by the secondary reactions and tar decomposition. Copyright © 2014 Elsevier Ltd. All rights reserved.

  18. Assessment of underground coal gasification in bituminous coals: potential UCG products and markets. Final report, Phase I

    Energy Technology Data Exchange (ETDEWEB)

    None

    1982-01-31

    The following conclusions were drawn from the study: (1) The US will continue to require new sources of energy fuels and substitutes for petrochemical feedstocks into the foreseeable future. Most of this requirement will be met using coal. However, the cost of mining, transporting, cleaning, and preparing coal, disposing of ash or slag and scrubbing stack gases continues to rise; particularly, in the Eastern US where the need is greatest. UCG avoids these pitfalls and, as such, should be considered a viable alternative to the mining of deeper coals. (2) Of the two possible product gases LBG and MBG, MBG is the most versatile. (3) The most logical use for UCG product in the Eastern US is to generate power on-site using a combined-cycle or co-generation system. Either low or medium Btu gas (LBG or MBG) can be used. (4) UCG should be an option whenever surface gasification is considered; particularly, in areas where deeper, higher sulfur coal is located. (5) There are environmental and social benefits to use of UCG over surface gasification in the Eastern US. (6) A site could be chosen almost anywhere in the Illinois and Ohio area where amenable UCG coal has been determined due to the existence of existing transportation or transmission systems. (7) The technology needs to be demonstrated and the potential economic viability determined at a site in the East-North-Central US which has commercial quantities of amenable bituminous coal before utilities will show significant interest.

  19. Dye-adsorption capacity of bituminous fly ash and its pozzolanic property after used as dye-adsorbent

    Directory of Open Access Journals (Sweden)

    Penpolcharoen, M.

    2004-02-01

    Full Text Available Bituminous fly ash, which is an industrial waste, was used as an adsorbent to remove dyestuff from the textile-dye wastewater. The batch kinetic and isotherm experiments of the synthetic wastewater were firstly conducted to determine the adsorption behavior and optimal conditions for adsorption. The optimal conditions were then applied to the actual textile-dye wastewater. Under the original conditions of fly ash and wastewater, the results indicated that the color could be removed up to 86.65% by 12 g of the fly ash /L of the wastewater within 30 min. Its adsorption was described by the Freundlich isotherm. The dye-adsorbed fly ash was further studied on its pozzolanic property in terms of compressive strength by using it as a partial substitute to Portland cement type I to produce mortar. The result revealed that the highest compressive strength was of the sample containing 10% by weight of the dye-adsorbed fly ash in replacement of cement. It possessed 215 kg/cm2 at 28 days, which is 92.67% of the sample containing 10% by weight of the original fly ash in replacement of cement, or 83.33 of the cement mortar. For the environmental concern, leachabilities of lead (Pb, chromium (Cr, copper (Cu and zinc (Zn from all mortars were also carried out. No leaching of the heavy metals from any samples could be detected. Hence, the dye-adsorbed fly ash can be used as an environmental friendly construction material.

  20. Effect of asphaltene and resin oils on the viscosity of bituminous petroleum materials to be used as asphalt primers

    Directory of Open Access Journals (Sweden)

    Bencomo, M. R.

    2006-03-01

    Full Text Available The bituminous crude from the Machete, Venezuela, area, which has such a fluid consistency that it falls outside the normal scope of the A5TM D-5 (1 penetration test exceeding the 3D-mm ceiling specified in that standard and can be used as an asphalt primer: Like other asphalt products, these materials are -chemically speaking- a mix of numerous naphthenic, paraffinic and aromatic hydrocarbons and heterocyclic compounds containing sulphur, nitrogen, oxygen and so on. They have a dense and a malthene oil phase which, along with the natural hydrocarbons additives used in these products acts as a volatile fluidizer. The former is described as a mix of asphaltenes: complex high molecular weight substances that are insoluble in paraffinic hydrocarbons and soluble in aromatic compounds such as benzene. The malthene oil phase, in turn, consists in a mix of resins and hydrocarbons and together the two constitute a colloidal system. The experiments discussed in the present paper were conducted to determine the effect of the proportion of asphaltenes and resin oils on the viscosity of such bituminous crude emulsions/ with a view to their use as primers. These experiments were run in a Parr batch reactor in a nitrogen atmosphere using n-heptane as a solvent. The resins were separated after the asphaltenes precipitated from the samples and subsequently from the malthene fraction obtained. The results showed that the asphaltenes account for the structural characteristics and consistency of the medium and the resin oils for its cohesive properties/,the malthene oils act as solvents.Los crudos extrapesados procedentes del área Machete (Venezuela son materiales de consistencia blanda o fluida, por lo que se salen del campo en el que normalmente se aplica el ensayo de penetración a productos asfálticos según el método ASTM D-5 (1, cuyo límite máximo es 30 mm, y pueden ser utilizados como pinturas asfálticas de imprimación. Al igual que otros productos

  1. Effects of Steam and CO2 in the Fluidizing Gas when Using Bituminous Coal in Chemical-Looping Combustion

    Science.gov (United States)

    Leion, H.; Lyngfelt, A.; Mattisson, T.

    Chemical-looping combustion (CLC) is a combustion technology where an oxygen carrier is used to transfer oxygen from the combustion air to the fuel in order to avoid direct contact between air and fuel. Thus, the CO2 is inherently separated from the flue gases with a potential for considerably lower energy penalty and cost compared to other techniques for CO2 separation. The oxygen carrier is circulated between two reactors, a fuel and an air reactor, where the flue gas from the air reactor contains oxygen depleted air and the flue gas from the fuel reactor contains mainly CO2 and H2O. The water can easily be condensed and the remaining CO2 can be transported for underground storage. Most of the prior work with CLC has focused on using natural gas and syngas as fuel and oxygen carrying material normally produced from pure chemicals. However, recent work on adapting the CLC process for solid fuels with ores and natural minerals as oxygen carrier shows promising results. This paper will present results from reactivity investigations in a laboratory fluidized-bed reactor system using previously investigated natural mineral ilmenite as oxygen carrier and a bituminous Colombian coal as fuel. Experiments were conducted at a temperature of 970°C with N2, steam, and/or CO2 in the fluidizing gas. Synergy effects between steam and CO2 on fuel conversion was noted. The results show that the fuel conversion was a roughly a factor 5 faster with steam as compared to CO2 in the fluidizing gas.

  2. Adapting palynological preparation methods in subbituminous and bituminous coals from Colombia to improve palynofacies and hydrocarbon source rock evaluations

    Energy Technology Data Exchange (ETDEWEB)

    Blandon, Astrid; Arango, Fredy [Facultad de Minas, Universidad Nacional de Colombia, Calle 65, 78-28, Medellin (Colombia); Parra, Norberto [Facultad de Ciencias, Universidad Nacional de Colombia, Calle 59A, 63-020, Medellin (Colombia); Gorin, Georges E. [Dpmt. Geology-Paleontology, University of Geneva, 13 rue des Maraichers, 1205 Geneva (Switzerland)

    2008-01-21

    Apart from their potential as fossil fuel, bituminous and subbituminous coals in Colombia may prove to be potential source rocks for the generation of hydrocarbons. The assessment of such properties requires the combination of petrographic and palynofacies studies. The latter correspond to the microscopic investigation in transmitted white and reflected UV lights of sedimentary organic matter insoluble in organic and inorganic solvents. To date, mineral acid and Schulze methods have failed to produce good samples of palynofacies constituents from Cenozoic coals in Colombia, so that the latter method had to be modified. The main modifications consist in adapting the KClO{sub 3} to HNO{sub 3} ratio in the Schulze mixture and introducing two extra phases of oxidation with NaOH and NH{sub 4}OH, which permit the washing off of humic substances. This method yields the full spectrum of palynofacies constituents, which are not destroyed or damaged by the alkali treatment. Neither is their fluorescence colour affected by the initial acid treatment. On the contrary, the particle fluorescence intensity tends to increase because of the dissolution of humic acids, making their identification easier. The achievements of the modified method are threefold: 1) it permits the correlation between macerals in petrographic polished sections and their equivalent in palynofacies slides, making the two methods complementary; 2) palynofacies provides a better identification of sporomorphs than petrography, resulting in better paleoenvironmental interpretations; 3) palynofacies tend to give a more precise quantitative evaluation of the liptinitic constituents, and consequently, of the coal hydrocarbon generation potential. (author)

  3. The influence of seam height on lost-time injury and fatality rates at small underground bituminous coal mines.

    Science.gov (United States)

    Peters, R H; Fotta, B; Mallett, L G

    2001-11-01

    Due to variations in the thickness of U.S. coal seams, there is great variability in the height of the roof where underground miners work. Restrictions imposed by low seam heights have important safety consequences. As the height of their workplace decreases, miners must stoop, duck walk, or crawl, and their vision, posture, and mobility become increasingly restricted. Low seam height also places important restrictions on the design of mobile equipment and other mining machinery. Using the employment and injury data reported to the Mine Safety and Health Administration (MSHA) from 1990 to 1996, small underground bituminous coal mines with less than 50 employees were stratified by average coal seam height according to the following categories: low ( or =61"). Injury rates for both nonfatal days lost and fatality cases were examined by seam height and leading type of injury incidents. The leading types of incidents associated with fatalities were roof falls and powered haulage equipment. In comparison to high-seam mines, miners working in low or medium seams are at higher risk of being killed by powered haulage equipment, roof bolting machines, and falls of unsupported roof. The leading types of incidents associated with nonfatal injuries were handling materials and powered haulage. As mining height decreases, miners are at increasingly higher risk of having a nonfatal injury from incidents involving roof bolting machines, load-haul-dump equipment, personnel carriers, and powered haulage conveyors. As mining height increases, miners are at increasingly higher risk of having a nonfatal injury from slips and falls and incidents involving shuttle cars and roof and rib falls. Knee injuries are a particularly severe problem in low-seam mines. The rate of injuries to miners while crawling or kneeling is 10 times higher in low seams than in high seams.

  4. Catalytic Two-Stage Liquefaction (CTSL{trademark}) process bench studies and PDU scale-up with sub-bituminous coal. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Comolli, A.G.; Johanson, E.S.; Karolkiewicz, W.F.; Lee, L.K.T.; Stalzer, R.H.; Smith, T.O.

    1993-03-01

    Reported are the details and results of Laboratory and Bench-Scale experiments using sub-bituminous coal conducted at Hydrocarbon Research, Inc., under DOE Contract No. DE-AC22-88PC88818 during the period October 1, 1988 to December 31, 1992. The work described is primarily concerned with testing of the baseline Catalytic Two-Stage Liquefaction (CTSL{trademark}) process with comparisons with other two stage process configurations, catalyst evaluations and unit operations such as solid separation, pretreatments, on-line hydrotreating, and an examination of new concepts. In the overall program, three coals were evaluated, bituminous Illinois No. 6, Burning Star and sub-bituminous Wyoming Black Thunder and New Mexico McKinley Mine seams. The results from a total of 16 bench-scale runs are reported and analyzed in detail. The runs (experiments) concern process variables, variable reactor volumes, catalysts (both supported, dispersed and rejuvenated), coal cleaned by agglomeration, hot slurry treatments, reactor sequence, on-line hydrotreating, dispersed catalyst with pretreatment reactors and CO{sub 2}/coal effects. The tests involving the Wyoming and New Mexico Coals are reported herein, and the tests involving the Illinois coal are described in Topical Report No. 2. On a laboratory scale, microautoclave tests evaluating coal, start-up oils, catalysts, thermal treatment, CO{sub 2} addition and sulfur compound effects were conducted and reported in Topical Report No. 3. Other microautoclave tests are described in the Bench Run sections to which they refer such as: rejuvenated catalyst, coker liquids and cleaned coals. The microautoclave tests conducted for modelling the CTSL{trademark} process are described in the CTSL{trademark} Modelling section of Topical Report No. 3 under this contract.

  5. Data for comparing hydrogenation with low temperature carbonization (L. T. C. ) of bituminous coal

    Energy Technology Data Exchange (ETDEWEB)

    Fahr

    1943-05-24

    A chart is presented with three main headings for processes applied to coal with 7,000 heat units/kg and 8% H/sub 2/O: (A) Lurgi Spuelgas (rinsing gas) Carbonization for Upper Silesia, and (B) Brennstoff-Technik (B.T.) Carbonization for Upper Silesia, and (C) Coke Plant for Upper Silesia. The following were given for each heading: coke yield at 7,000 heat units and 5% H/sub 2/O; tar yield; LTC gas; heat requirements for the kiln drum; production involving coal for weak gas; power requirements; steam requirements; coal for current and steam; and tar processing. Coke with 0% H/sub 2/O based on a dry coal basis showed yields of 72.5% for (A), 75.0% for (B), and 71.0% for (C). Coke with 5% H/sub 2/O based on anhydrated dry coal showed 70.2% for (A), 72.5% for (B), and 68.7% for (C). Particle sizes that were 20 mm in size or larger constituted 82.3% of (A), 71.6% of (B), and 85.0% of (C). Volatile constituents were given as 7.0% for (A), 9.0% for (B), and 7.0% for (C). Tar yield based on dry coal was 9.2% for (A), 8.5% for (B), and 4.0% for (C). Tar yield based on anhydrated dry coal was 10.1% for (A), 9.8% for (B), and 5.0% for (C). Power requirements in KW hr/hr for 1 million tons dry coal were 2,100 for (A), 3,100 for (B), and 2,000 for (C). Coal for current and steam for 1 million tons anhydrated dry coal were 12,900 tons/yr for (A), 12,000 tons/yr for (B), and 20,000 tons/yr for (C). 1 table

  6. Model based decision support for planning of road maintenance

    NARCIS (Netherlands)

    van Harten, Aart; Worm, J.M.; Worm, J.M.

    1996-01-01

    In this article we describe a Decision Support Model, based on Operational Research methods, for the multi-period planning of maintenance of bituminous pavements. This model is a tool for the road manager to assist in generating an optimal maintenance plan for a road. Optimal means: minimising the

  7. Evolution of rheological properties of nuclear bituminized waste products, towards an ageing/viscosity law

    International Nuclear Information System (INIS)

    Mouazen, M.

    2011-01-01

    This work is a contribution to the understanding of rheological properties of bitumen and their evolution under gamma irradiation. The prediction of swelling ratio is necessary to evaluate the state of the containers, particularly during the reversibility phase of the storage. The objective of this work is thus to establish the rheological data its evolution under irradiation in order to predict the container swelling with time. After the rheological and thermal characterization of pure bitumen, a series of extrusion trials has been carried out. The state of dispersion essentially depends on the ratio N/Q (screw speed to feed rate). Extreme values of N/Q show the highest yield stress, indicating an improved dispersion state. The industrial bitumen compound exhibits the highest viscosity compared to model compounds, which limits bubble migration. Finally, the effect of gamma irradiation on pure bitumen and compounds behaviour has been studied. External and structural modifications have been evidenced. A theoretical model based on Krieger-Dougherty equation has been developed and shows a good agreement with experimental data. (author)

  8. Production costs of auto gasoline and DHD feed from bituminous coal

    Energy Technology Data Exchange (ETDEWEB)

    1942-11-04

    This report consists of three tables. The first table shows data concerning the 700 atm liquid phase and a production capacity of 146,000 tons/yr of gasoline and middle oil. The cost is shown in Reichsmarks per ton of gasoline and middle oil for individual areas such as: 1.73 tons of hydrogenation coal, with 10% water and 4% ash as being 40 RM, 1900 m/sup 3/ H/sub 2/ being 83.50 RM, catalysts and chemicals being 2.40 RM, power being 32.0 RM, and wages, materials, operating materials and laboratory costs as being 19.6 RM. The total of all areas listed was 211.60 RM/ton of gasoline and middle oil. The second table is for the 300 atm vapor phase showing RM/ton of auto gasoline and RM/ton 170/sup 0/-endpoint gasoline based on the gasoline being free of C/sub 4/. This is given for liquid phase gasoline and middle oil, hydrogen, liquid petroleum gasoline credit, hydrogenation gas credit, catalyst and chemicals, power, wages, repairs, fire protection and taxes, amortization, general, 3% interest, and 5% interest. The same information given in the second chart is also given in the third chart except it was for a 700 atm vapor phase operation. The 300 atm-process seemed to have slightly higher cost than the 700 atm process, partly because of using more hydrogen and more expensive catalyst. 3 tables

  9. Bituminous concrete overlay studies.

    Science.gov (United States)

    1971-01-01

    Deflection tests conducted on eight sections of primary highway, both before and after asphaltic concrete resurfacings, were analyzed as a study of the utility of such tests in the design of overlays. The application of tentative traffic and allowabl...

  10. Technical and economic assessment of process of treatment of coated bituminous sludge by combustion/vitrification (report PNGMDR 2013-2015)

    International Nuclear Information System (INIS)

    2015-01-01

    This note reports the assessment of a processing by combustion/vitrification of about 60.000 parcels of coated bituminous sludge belonging to intermediate-level long-lived and low-level long-lived category, and warehoused on the Marcoule CEA site. This assessment identifies the front-end cost of an exploratory R and D which would be required to undo technological locks, the cost of design, realisation and exploitation of the associated installation, and the negative features dues to the lack of technological maturity and to the management of environmental risks and impacts in comparison with the reference industrial solution (geological storage). As a conclusion, the authors state that the process is still not technically feasible

  11. Comparative study on combined co-pyrolysis/gasification of walnut shell and bituminous coal by conventional and congruent-mass thermogravimetric analysis (TGA) methods.

    Science.gov (United States)

    Zhang, Yan; Fan, Di; Zheng, Yan

    2016-01-01

    Combined co-pyrolysis/gasification of bituminous coal (BC) and walnut shell (WS) are comparatively studied with both conventional and congruent-mass thermogravimertric analysis (TGA) methods. The results indicate that BC and WS exhibit additivity in the co-pyrolysis step. However, the gasification reactivity of chars in subsequent gasification step exhibits remarkable sample-mass dependence, which causes the illusions in synergy and inhibition effects when conventional TGA tests are conducted. A congruent-mass TGA method has been developed to overcome the limitations of the conventional TGA mode. One of the advantages of this method is that it can reduce to a minimum the effect of sample mass on reactivity. Thus, the degree of synergy or inhibition can be directly estimated from the deviation of the experimental TG curves between the two separated and blended samples. We recommend this method in studying the co-processing behavior between coal and biomass. Copyright © 2015 Elsevier Ltd. All rights reserved.

  12. Real-time analysis of soot emissions from bituminous coal pyrolysis and combustion with a vacuum ultraviolet photoionization aerosol time-of-flight mass spectrometer.

    Science.gov (United States)

    Gao, Shaokai; Zhang, Yang; Meng, Junwang; Shu, Jinian

    2009-01-15

    This paper reports on-line analyses of the soot emissions from the Inner Mongolia bituminous coal combustion and pyrolysis processes with a vacuum ultraviolet photoionization aerosol time-of-flight mass spectrometer (VUV-ATOFMS). The soot particles are generated by heating a small amount of screened coal powder in synthetic air and nitrogen atmosphere in a tubular oven. The vacuum ultraviolet photoionization time-of-flight (VUV-TOF) mass spectra of the soot particles emitted from combustion and pyrolysis at different oven temperatures and different stages are obtained. The VUV-TOF mass spectra are assigned with the references of the results of the off-line GC/MS analysis.

  13. CO2 capture from power plants. Part I : A parametric study of the technical performance based on monoethanolamine

    NARCIS (Netherlands)

    Abu-Zahra, M. R. M.; Schneiders, L. H. J.; Niederer, J. P. M.; Feron, P. H. M.; Versteeg, G. F.

    Capture and storage of CO2 from fossil fuel fired power plants is drawing increasing interest as a potential method for the control of greenhouse gas emissions. An optimization and technical parameter study for a CO2 capture process from flue gas of a 600 MWe bituminous coal fired power plant, based

  14. Thermo-mechanical behavior of bituminous mixtures at low temperatures. Links between the binder characteristics and the mix properties; Comportement thermomecanique des enrobes bitumeux a basses temperatures: relations entre les proprietes du liant et de l'enrobe

    Energy Technology Data Exchange (ETDEWEB)

    Olard, F.

    2003-10-01

    This thesis has been realized within the framework of a partnership between the Ecole Nationale des TPE, APPIA and EUROVIA. The company Total has also been associated to this project. The study deals with the thermo-mechanical behavior of bituminous materials at low temperatures. The aim is to establish the links between the characteristics of the binder and the properties of bituminous mixes at low temperatures, and to better understand the existing low-temperature parameters and criteria for binders (or to propose new ones), related to the in-situ behavior of bituminous mixtures. A large experimental campaign has been carried out so as to fulfill this goal. After a bibliographical study on the rheology and the thermo-mechanical properties of (pure or modified) binders, putties and mixes, the experimental campaign carried out both in the small strain domain and in the large strain domain, is presented. The low temperature behavior of binders has been evaluated with three common fundamental tests: i)the complex modulus determination, ii)the Bending Beam Rheometer and iii)the tensile strength at a constant strain rate and constant temperatures. A new three point bending test on pre-notched bitumen beams has also been developed at the ENTPE. The low-temperature fracture properties of bitumens were studied at constant temperatures and cross-head speeds considering the Linear Elastic Fracture Mechanics (LEFM) assumptions. The thermo-mechanical behavior of bituminous mixtures has been studied by performing i)complex modulus tests, ii)measurements of the coefficient of thermal dilatation and contraction, iii)tensile tests at constant temperatures and strain rates, and iv)Thermal Stress Restrained Specimen Tests. Apart from the determination of some pertinent links between binder and mix properties and discriminating characteristics with regard to the thermal cracking of bituminous mixes at low temperatures, the analysis has also consisted in modeling the behavior of

  15. Effect of the temperature of different combustion zones in the boiler grate on changes in physical and chemical parameters of bituminous coal and slags

    Directory of Open Access Journals (Sweden)

    Przemysław Rompalski

    2016-01-01

    Full Text Available This paper presents the results of a study on the influence of the temperature of characteristic zones of coal combustion in a stoker fired boiler (drying, degassing, and burn-out, on changes in physical and chemical parameters of bituminous coal and slags. This information is important as it helps identify the impact of coal properties on the accumulation of trace elements, primarily mercury, in combustion waste. The study is the continuation of research work on the impact of mercury compounds accumulated in combustion waste on the natural environment (mercury from landfills of slag, and fly ash. Studies were undertaken because no in-depth analysis of the impact of the temperature of particular zones of stoker fired boilers on the physical and chemical parameters of the post-process slag, including mercury content, had been reported in literature. Both of the coals examined, classified as bituminous coal according to the International Classification of Seam Coals and of type 32.1 according to the PN-G-97002:1982 standard, showed an average mercury content of 0.0849 μg/g. In the chemical composition determined for the ash derived from burnt coal, the dominance of SiO2 and Al2O3 over other oxides was found. This feature results in the increase of the softening temperature and ash melting and, therefore, during the combustion of coal tested in a stoker fired boiler, only ash was subjected to the sintering process. Mercury content in the other examined samples taken from various locations of the stoker fired boiler (drying – 32–1050 °C, degassing – 1050–1020 °C, and burn-out – 1020–400 °C varied from 0.0668 to 0.0009 μg/g and was determined with the use of a LECO atomic absorption spectrometer. The analyses of the elemental composition, performed with the application of XRF spectrometry, for ash obtained from samples collected from different sampling points of the stoker fired boiler showed that the largest concentration of

  16. Mercury emissions during cofiring of sub-bituminous coal and biomass (chicken waste, wood, coffee residue, and tobacco stalk) in a laboratory-scale fluidized bed combustor.

    Science.gov (United States)

    Cao, Yan; Zhou, Hongcang; Fan, Junjie; Zhao, Houyin; Zhou, Tuo; Hack, Pauline; Chan, Chia-Chun; Liou, Jian-Chang; Pan, Wei-Ping

    2008-12-15

    Four types of biomass (chicken waste, wood pellets, coffee residue, and tobacco stalks) were cofired at 30 wt % with a U.S. sub-bituminous coal (Powder River Basin Coal) in a laboratory-scale fluidized bed combustor. A cyclone, followed by a quartz filter, was used for fly ash removal during tests. The temperatures of the cyclone and filter were controlled at 250 and 150 degrees C, respectively. Mercury speciation and emissions during cofiring were investigated using a semicontinuous mercury monitor, which was certified using ASTM standard Ontario Hydra Method. Test results indicated mercury emissions were strongly correlative to the gaseous chlorine concentrations, but not necessarily correlative to the chlorine contents in cofiring fuels. Mercury emissions could be reduced by 35% during firing of sub-bituminous coal using only a quartz filter. Cofiring high-chlorine fuel, such as chicken waste (Cl = 22340 wppm), could largely reduce mercury emissions by over 80%. When low-chlorine biomass, such as wood pellets (Cl = 132 wppm) and coffee residue (Cl = 134 wppm), is cofired, mercury emissions could only be reduced by about 50%. Cofiring tobacco stalks with higher chlorine content (Cl = 4237 wppm) did not significantly reduce mercury emissions. This was also true when limestone was added while cofiring coal and chicken waste because the gaseous chlorine was reduced in the freeboard of the fluidized bed combustor, where the temperature was generally below 650 degrees C without addition of the secondary air. Gaseous speciated mercury in flue gas after a quartz filter indicated the occurrence of about 50% of total gaseous mercury to be the elemental mercury for cofiring chicken waste, but occurrence of above 90% of the elemental mercury for all other cases. Both the higher content of alkali metal oxides or alkali earth metal oxides in tested biomass and the occurrence of temperatures lower than 650 degrees C in the upper part of the fluidized bed combustor seemed to be

  17. Flow sheet at Lu-Op plant for auto gasoline for 170/sup 0/ E. P. gasoline for DHD from bituminous coal

    Energy Technology Data Exchange (ETDEWEB)

    1942-11-02

    Several tables with varied information concerning gasoline production are presented. The first table concerned the 700 atm liquid phase running to produce: (1) gasoline and middle oil or (2) 32% heavy oil excess. This gave information such as the rate of primary crusing, drying, paste milling and pressing, gas circulation, oil washing, compression, centrifuge plant operations, kiln plant operations, cold catchpot products, and yields. It also gave stall sizes. The second and third charts contained information for the 300 atm and 700 atm vapor phase processes with subdivisions for auto gasoline and 170/sup 0/C endpoint gasoline. It showed rates for injection pumps, gas circulation, compression, yield from columns, L.P.G. production, gasoline stabilization and wash, hydrogenation gas production with 95% recovery, percent of aromatic recovery, and total hydrogen consumption. The fourth chart concerned hydrogen production for the Lu-Op plant from bituminous coal. The first major category was coke with subcategories of DHD gasoline in the 700 atm vapor phase system and in the 300 atm vapor phase system. The second category was hydrogenation gas splitting with the same subcategories as above. A table of power requirements for 170/sup 0/C endpoint gasoline including the liquid phase and hydrogen production for 300 atm and 700 atm vapor phase processes is included. 5 tables

  18. Rapid co-pyrolysis of rice straw and a bituminous coal in a high-frequency furnace and gasification of the residual char.

    Science.gov (United States)

    Yuan, Shuai; Dai, Zheng-hua; Zhou, Zhi-jie; Chen, Xue-li; Yu, Guang-suo; Wang, Fu-chen

    2012-04-01

    Rapid pyrolysis of rice straw (RS) and Shenfu bituminous coal (SB) separately, and rapid co-pyrolysis of RS/SB blends (mass ratio 1:4, 1:4, and 4:1), were carried out in a high-frequency furnace which can ensure both high heating rate and satisfying contact of fuel particles. Synergies between RS and SB during rapid co-pyrolysis were investigated. Intrinsic and morphological structures of residual char from co-pyrolysis, and their effects on gasification characteristics were also studied. Synergies occurred during rapid co-pyrolysis of RS and SB (RS/SB=1:4) resulting in decreasing char yields and increasing volatile yields. Synergies also happened during gasification of the char derived from co-pyrolysis of RS and SB with mass ratio of 1:4. The increased mass ratio of RS to SB did not only weaken synergies during co-pyrolysis, but significantly reduced the gasification rates of the co-pyrolysis char compared to the calculated values. Results can help to optimize co-conversion process of biomass/coal. Copyright © 2012 Elsevier Ltd. All rights reserved.

  19. Analysis of Porous Structure Parameters of Biomass Chars Versus Bituminous Coal and Lignite Carbonized at High Pressure and Temperature—A Chemometric Study

    Directory of Open Access Journals (Sweden)

    Adam Smoliński

    2017-09-01

    Full Text Available The characteristics of the porous structure of carbonized materials affect their physical properties, such as density or strength, their sorption capacity, and their reactivity in thermochemical processing, determining both their applicability as fuels or sorbents and their efficiency in various processes. The porous structure of chars is shaped by the combined effects of physical and chemical properties of a carbonaceous material and the operating parameters applied in the carbonization process. In the study presented, the experimental dataset covering parameters of various fuels, ranging from biomass through lignite to bituminous coal, and chars produced at 1273 K and under the pressure of 1, 2, 3, and 4 MPa was analyzed with the application of the advanced method of data exploration. The principal component analysis showed that the sample of the highest coal rank was characterized by lower values of parameters reflecting the development of the porous structure of chars. A negative correlation was also observed between the carbon content in a fuel and the evolution of the porous structure of chars at high pressure. The highest total pore volume of chars produced under 1 and 3 MPa and the highest micropore surface area under 3 MPa were reported for a carbonized fuel sample of the highest moisture content.

  20. Changes in optical properties, chemistry, and micropore and mesopore characteristics of bituminous coal at the contact with dikes in the Illinois Basin

    Science.gov (United States)

    Mastalerz, Maria; Drobniak, A.; Schimmelmann, A.

    2009-01-01

    Changes in high-volatile bituminous coal (Pennsylvanian) near contacts with two volcanic intrusions in Illinois were investigated with respect to optical properties, coal chemistry, and coal pore structure. Vitrinite reflectance (Ro) increases from 0.62% to 5.03% within a distance of 5.5??m from the larger dike, and from 0.63% to 3.71% within 3.3??m from the small dike. Elemental chemistry of the coal shows distinct reductions in hydrogen and nitrogen content close to the intrusions. No trend was observed for total sulfur content, but decreases in sulfate content towards the dikes indicate thermochemical sulfate reduction (TSR). Contact-metamorphism has a dramatic effect on coal porosity, and microporosity in particular. Around the large dike, the micropore volume, after a slight initial increase, progressively decreases from 0.0417??cm3/g in coal situated 4.7??m from the intrusive contact to 0.0126??cm3/g at the contact. Strongly decreasing mesopore and micropore volumes in the altered zone, together with frequent cleat and fracture filling by calcite, indicate deteriorating conditions for both coalbed gas sorption and gas transmissibility. ?? 2008 Elsevier B.V. All rights reserved.

  1. Changes in optical properties, chemistry, and micropore and mesopore characteristics of bituminous coal at the contact with dikes in the Illinois Basin

    Energy Technology Data Exchange (ETDEWEB)

    Mastalerz, M.; Drobniak, A. [Indiana University, Indiana Geological Survey, Bloomington, IN 47405 (United States); Schimmelmann, A. [Indiana University, Dept. of Geological Sciences, Bloomington, IN 47405-1405 (United States)

    2009-01-31

    Changes in high-volatile bituminous coal (Pennsylvanian) near contacts with two volcanic intrusions in Illinois were investigated with respect to optical properties, coal chemistry, and coal pore structure. Vitrinite reflectance (R{sub o}) increases from 0.62% to 5.03% within a distance of 5.5 m from the larger dike, and from 0.63% to 3.71% within 3.3 m from the small dike. Elemental chemistry of the coal shows distinct reductions in hydrogen and nitrogen content close to the intrusions. No trend was observed for total sulfur content, but decreases in sulfate content towards the dikes indicate thermochemical sulfate reduction (TSR). Contact-metamorphism has a dramatic effect on coal porosity, and microporosity in particular. Around the large dike, the micropore volume, after a slight initial increase, progressively decreases from 0.0417 cm{sup 3}/g in coal situated 4.7 m from the intrusive contact to 0.0126 cm{sup 3}/g at the contact. Strongly decreasing mesopore and micropore volumes in the altered zone, together with frequent cleat and fracture filling by calcite, indicate deteriorating conditions for both coalbed gas sorption and gas transmissibility. (author)

  2. Evaluation of Control Strategies to Effectively Meet 70-90% Mercury Reduction on an Eastern Bituminous Coal Cyclone Boiler with SCR

    Energy Technology Data Exchange (ETDEWEB)

    Tom Campbell

    2008-12-31

    This is the final site report for testing conducted at Public Service of New Hampshire's (PSNH) Merrimack Unit 2 (MK2). This project was funded through the DOE/NETL Innovations for Existing Plants program. It was a Phase III project with the goal to develop mercury control technologies that can achieve 50-70% mercury capture at costs 25-50% less than baseline estimates of $50,000-$70,000/lb of mercury removed. While results from testing at Merrimack indicate that the DOE goal was partially achieved, further improvements in the process are recommended. Merrimack burned a test blend of eastern bituminous and Venezuelan coals, for a target coal sulfur content of 1.2%, in its 335-MW Unit 2. The blend ratio is approximately a 50/50 split between the two coals. Various sorbent injection tests were conducted on the flue gas stream either in front of the air preheater (APH) or in between the two in-series ESPs. Initial mercury control evaluations indicated that, without SO3 control, the sorbent concentration required to achieve 50% control would not be feasible, either economically or within constraints specific to the maximum reasonable particle loading to the ESP. Subsequently, with SO{sub 3} control via trona injection upstream of the APH, economically feasible mercury removal rates could be achieved with PAC injection, excepting balance-of-plant concerns. The results are summarized along with the impacts of the dual injection process on the air heater, ESP operation, and particulate emissions.

  3. Pyrolysis and liquefaction of acetone and mixed acetone/ tetralin swelled Mukah Balingian Malaysian sub-bituminous coal-The effect on coal conversion and oil yield

    International Nuclear Information System (INIS)

    Mohd Pauzi Abdullah; Mohd Azlan Mohd Ishak; Khudzir Ismail

    2008-01-01

    The effect of swelling on Mukah Balingian (MB) Malaysian sub-bituminous coal macrostructure was observed by pyrolysing the swelled coal via thermogravimetry under nitrogen at ambient pressure. The DTG curves of the pyrolyzed swelled coal samples show the presence of evolution peaks at temperature ranging from 235 - 295 degree Celsius that are due to releasing of light molecular weight hydrocarbons. These peaks, however, were not present in the untreated coal, indicating some changes in the coal macrostructure has occurred in the swelled coal samples. The global pyrolysis kinetics for coal that follows the first-order decomposition reaction was used to evaluate the activation energy of the pyrolyzed untreated and swelled coal samples. The results thus far have shown that the activation energy for the acetone and mixed acetone/ tetralin-swelled coal samples exhibit lower values than untreated coal, indicating less energy is required during the pyrolysis process due to the weakening of the coal-coal macromolecular interaction network. Moreover, liquefaction on the swelled coal samples that was carried out at temperatures ranging from 360 to 450 degree Celsius at 4 MPa of nitrogen pressure showed the enhancement of the coal conversion and oil yield at temperature of 420 degree Celsius, with retrogressive reaction started to dominate at higher temperature as indicated by decreased and increased in oil yield and high molecular weight pre-asphaltene, respectively. These observations suggest that the solvent swelling pre-treatment using acetone and mixed acetone/ tetralin can improve the coal conversion and oil yields at less severe liquefaction condition. (author)

  4. The Role of Bituminous Sands in Extending the Petroleum Era Beyond 2000 A. D. (Summary Le rôle des sables bitumineux pour prolonger l'ère du pétrole au-delà de l'an 2000 (résumé

    Directory of Open Access Journals (Sweden)

    Carrigy M.

    2006-10-01

    Full Text Available Bituminous sand is an energy resource that is receiving increasing attention and there is a strong interest by the international community in co-operating in the development of new methods of exploration, and in the solution of common technological problems to reduce the time when oil from this enormous energy source is available. A detailed knowledge of the geological setting and the reservoir is of paramount importance to the assessment of the magnitude of the resource, its successful exploitation and to facilitate the transfer of the highly complicated recovery technology from one deposit to another. Much research also remains to be done to improve our understanding of the origin of the bitumen and the factors controlling the location of its accumulation. Based on the scant information we have, it is estimated that bituminous sand deposits contain from 5 to 10 x 10. 12 (trillion barrels of crude bitumen and are surely large enough to make a significant contribution to extending the petroleum era until alternative energy sources are developed. However, great amounts of synthetic oil from this source will probably not be brought onto the market until after the year 2000 A. D. because of the high capital cost, and large numbers of skilled technicians required to bring them into production. In the more industrialized nations where the demand for portable liquid fuel is strongest, notably Canada, Venezuela, and USA, billions of dollars are being spent on exploring and exploiting their bituminous sand resources. It is, however, in those undeveloped nations, who cannot afford to buy light crude oil, and who have bituminous deposits, where exploitation of this resource should have its greatest impact. It is therefore imperative that all geologists be aware of the new technologies that are now available to turn these low-grade hydrocarbons into high-grade products. Une attention croissante est accordée aux sables bitumineux comme source d

  5. Study on the conditions of bituminization of radioactive wastes and their influence on the stability of stored products

    International Nuclear Information System (INIS)

    Golinski, M.; Ksiazak, Z.

    1975-05-01

    Investigations carried out on a laboratory and semi-industrial scale showed that the Polish oxidised industrial bitumen P-60 was suitable for the solidification of liquid radioactive waste and particularly for non-concentrated post-precipitation sludges. The bitumen products were highly stable and were resistant to leaching by acids, salt solutions and water. Laboratory leach tests gave values similar to those obtained by others using different bitumen. By evaluating the sorption characteristics of the soil and the hydrogeological conditions existing at a proposed storage site, it was shown that the solidified wastes could be stored directly in the soil without further isolation from the soil water. Based on the liquid wastes arising from a nuclear power plant it has been shown that solidification of the wastes in bitumen will be cheaper than solidification of the same wastes using cement

  6. Thermal relaxation of bituminous coal to improve donation ability of hydrogen radicals in flash pyrolysis; Sekitan kozo kanwa ni yoru suiso radical kyoyo noryoku no kojo wo mezashita netsubunkai mae shori

    Energy Technology Data Exchange (ETDEWEB)

    Mori, T.; Isoda, T.; Kusakabe, K.; Morooka, S. [Kyushu University, Fukuoka (Japan). Faculty of Engineering; Hayashi, J. [Hokkaido University, Sapporo (Japan). Center for Advanced Research of Energy Technology

    1996-10-28

    In terms of coal conversion reaction, the behavior of bituminous coal heated beyond a glass transition point was examined on the basis of pyrolyzed products, and the effect of an increase in proton mobility on promotion of coal decomposition was evaluated. In experiment, after Illinois bituminous coal specimen was heated up to a specific temperature in N2 or He gas flow at a rate of 5K/min, the specimen was directly transferred to a pyrolyzer for instantaneous pyrolysis. As the experimental result, the glass transition temperature of the Illinois coal specimen was calculated to be 589K from a differential scanning calorimetry (DSC) profile. From the pyrolysis result of the Illinois coal specimen heated up to 623K, the char yield decreased by 3kg as compared with that of the original coal, while the tar yield increased by 4kg up to 27kg per 100kg of the original coal. This tar increase was larger than that of cooled coal. These results suggested that the donation of hydrogen radicals to coal fragments is improved with an increase in proton mobility. 4 refs., 4 figs., 1 tab.

  7. Valuation of investments in natural resources using contingent-claim framework with application to bituminous coal developments in Korea

    International Nuclear Information System (INIS)

    Won, Chaehwan

    2009-01-01

    As Brennan and Schwartz [Brennan M, Schwartz E. Evaluating natural resource investment. Journal of Business 1985;58:135-57] point out in their pioneering work, the valuation of natural resources projects is particularly difficult due to the high degree of uncertainty in output prices of resources. In general, there are two competing procedures to evaluate risky projects in natural resources developments. One is decision analytic, based on traditional discounted cash flow and stochastic dynamic programming [Fleten SE, Maribu KM, Wangensteen I. Optimal investment strategies in decentralized renewable power generation under uncertainty. Energy 2007;32:803-15; Smith J, McCardle K. Valuing oil properties: integrating option pricing and decision analysis approaches. Operations Research 1998;46(2):198-217; Szklo AS, Carneiro JTG, Machado G. Break-even price for upstream activities in Brazil: evaluation of the opportunity cost of oil production delay in a non-mature sedimentary production region. Energy 2008;33:589-600], and the other is contingent claims analysis, based on the no-arbitrage theory of financial markets [Brennan M, Schwartz E. Evaluating natural resource investment. Journal of Business 1985;58:135-57; Emhjellen M, Alaouze CM. A comparison of discounted cash flow and modern asset pricing methods - project selection and policy implications. Energy Policy 2003;31:1213-20; Laughton D. The management of flexibility in the upstream petroleum industry. The Energy Journal 1998;19:83-114; Paddock L, Siegel D, Smith J. Option valuation of claims on real assets: the case of offshore petroleum leases. Quarterly Journal of Economics 1988;103(3):479-508; Schwartz ES. Valuing long-term commodity assets. Journal of Energy Finance and Development 1998;3(2):85-99; Sezgen O, Goldman CA, Krishnarao P. Option value of electricity demand response. Energy 2007;32:108-19]. In this paper, we use the second approach to develop a new model, and the main contributions are providing a

  8. Comprehensive geobiological characterization of a bituminous carbonate facies with Ediacara-type fossils (Shibantan Member, South China)

    Science.gov (United States)

    Duda, Jan-Peter; Blumenberg, Martin; Thiel, Volker; Simon, Klaus; Zhu, Maoyan; Reitner, Joachim

    2015-04-01

    The Shibantan Member (Dengying Formation, Ediacaran Period) is one of only few carbonate settings with Ediacara-type fossils worldwide (e.g. Ding & Chen, 1981; Sun, 1986; Xiao et al., 2005; Shen et al., 2009; Chen et al., 2014). However, only little is known about the sedimentology and biogeochemistry of the environments in which these organisms throve. Here we provide a comprehensive geobiological characterization of the Shibantan Member, addressing the interplay between sedimentary and (bio-) geochemical processes. Sedimentary analysis revealed that black laminated limestones of the lower Shibantan Member were deposited after a sudden local deepening in a subtidal lower- to middle ramp environment close to the storm wave base, while the dark wavy dolomites of the upper Shibantan Member were deposited in a subtidal middle ramp environment between storm- and fair weather wave base. Sedimentation in the Shibantan basin was generally highly dynamic as evidenced by a distinct slumping horizon and mass-flow deposits that were possibly due to synsedimentary tectonic processes. The microbial-mat associated biota including Ediacara-type fossils is restricted to the lower Shibantan Member. Sedimentary analysis of this part reveals a close relationship between autochthonous mat growth and allochthonous and/or para-autochthonous event deposition. During deposition of the lower Shibantan Member the water column was probably temporarily stratified, with a sub- to anoxic water layer (evidenced by Ni/Co-, V/(V+Ni) and V/Sc ratios) overlain by a oxygenated upper layer (evidenced by negative Ce anomalies and low V/Cr ratios). However, such stratification was not permanent, as mixing by storm events is evidenced by hummocky cross stratification structures. 13C-enrichments in carbonates of the Lower Shibantan Member (δ13C = +3.3 to +4.0o VPDB) together with 13C-depletions of syngenetic n-alkanes cleaved from the respective extraction residue using catalytic hydropyrolysis (HyPy;

  9. Hydrogenation balances for bituminous coal

    Energy Technology Data Exchange (ETDEWEB)

    Hoelscher

    1944-02-11

    This report was intended to set up predictive curves concerning how certain variables involved in coal hydrogenation output would change in response to changes in certain operational or input variables, for hydrogenation of Gelsenberg coal. The particular dependences investigated in the article were the following: (1) for liquid phase, the dependence of oil output, amount of product to be distilled, and hydrogen use upon the ash content of the coal, the carbon content of the coal, and the percentage of formation of gases, and (2) for vapor phase, the dependence of gasoline yield, hydrogen use, and excess hydrocarbon gas products on the percentage of gasification in the 6434 step. Within certain limits of validity, these dependences seemed mostly to be linear and were illustrated in graphs in the report (most of which were very hard to read on the microfilm image). The limits of validity were 2 to 8% ash content, 80 to 86.2% carbon content, 20 to 25% gasification in liquid phase, and 17 to 25% gasification in the 6434 vapor phase. As an example of the data and calculations, it was observed that at 2% ash content, there was 628 kg of oil output in the liquid phase, at 4% ash content, there was 621 kg oil output, and at 8% ash content, there was 607 kg oil output, so it was calculated that oil output would decrease by 0.56% for each percent increase in ash content between 2% and 8%. 7 tables, 2 graphs.

  10. Dust is the dominant source of "heavy metals" to peat moss (Sphagnum fuscum) in the bogs of the Athabasca Bituminous Sands region of northern Alberta.

    Science.gov (United States)

    Shotyk, William; Bicalho, Beatriz; Cuss, Chad W; Duke, M John M; Noernberg, Tommy; Pelletier, Rick; Steinnes, Eiliv; Zaccone, Claudio

    2016-01-01

    Sphagnum fuscum was collected from twenty-five ombrotrophic (rain-fed) peat bogs surrounding open pit mines and upgrading facilities of Athabasca Bituminous Sands (ABS) in northern Alberta (AB) in order to assess the extent of atmospheric contamination by trace elements. As a control, this moss species was also collected at a bog near Utikuma (UTK) in an undeveloped part of AB and 264km SW of the ABS region. For comparison, this moss was also collected in central AB, in the vicinity of the City of Edmonton which is approximately 500km to the south of the ABS region, from the Wagner Wetland which is 22km W of the City, from Seba Beach (ca. 90km W) and from Elk Island National Park (ca. 45km E). All of the moss samples were digested and trace elements concentrations determined using ICP-SMS at a commercial laboratory, with selected samples also analyzed using instrumental neutron activation analysis at the University of Alberta. The mosses from the ABS region yielded lower concentrations of Ag, As, Bi, Cd, Cu, Pb, Sb, Tl, and Zn compared to the moss from the Edmonton area. Concentrations of Ni and Mo in the mosses were comparable in these two regions, but V was more abundant in the ABS samples. Compared with the surface vegetation of eight peat cores collected in recent years from British Columbia, Ontario, Quebec and New Brunswick, the mean concentrations of Ag, As, Bi, Cd, Cu, Mo, Ni, Pb, Sb, Tl and Zn in the mosses from the ABS region are generally much lower. In fact, the concentrations of these trace elements in the samples from the ABS region are comparable to the corresponding values in forest moss from remote regions of central and northern Norway. Lithophile element concentrations (Ba, Be, Ga, Ge, Li, Sc, Th, Ti, Zr) explain most of the variation in trace metal concentrations in the moss samples. The mean concentrations of Th and Zr are greatest in the moss samples from the ABS region, reflecting dust inputs to the bogs from open pit mines, aggregate

  11. Microbial activity in argillite waste storage cells for the deep geological disposal of French bituminous medium activity long lived nuclear waste: Impact on redox reaction kinetics and potential

    Science.gov (United States)

    Albrecht, A.; Leone, L.; Charlet, L.

    2009-04-01

    Micro-organisms are ubiquitous and display remarkable capabilities to adapt and survive in the most extreme environmental conditions. It has been recognized that microorganisms can survive in nuclear waste disposal facilities if the required major (P, N, K) and trace elements, a carbon and energy source as well as water are present. The space constraint is of particular interest as it has been shown that bacteria do not prosper in compacted clay. An evaluation of the different types of French medium and high level waste, in a clay-rich host rock storage environment at a depth between 500 and 600 m, has shown that the bituminous waste is the most likely candidate to accommodate significant microbial activity. The waste consists of a mixture of bitumen (source of bio-available organic matter and H2 as a consequence of its degradation and radiolysis) and nitrates and sulphates kept in a stainless steel container. The assumption, that microbes only have an impact on reaction kinetics needs to be reassessed in the case where nitrates and sulphates are present since both are known not to react at low temperatures without bacterial catalysis. The additional impact of both oxy-anions and their reduced species on redox conditions, radionuclide speciation and mobility gives this evaluation their particular relevance. Storage architecture proposes four primary waste containers positioned into armoured cement over packs and placed with others into the waste storage cell itself composed of a cement mantle enforcing the argillite host rock, the latter being characterized by an excavation damaged zone constricted both in space and in time and a pristine part of 60 m thickness. Bacterial activity within the waste and within the pristine argillite is disregarded because of the low water activity (colonies is the high pH controlled by the cement solution. Archea are able to survive at high pH, when hydrogen gas is available as an energy sources; they are therefore likely candidates

  12. Bituminous coal production in the Appalachian basin: past, present, and future: Chapter D.3 in Coal and petroleum resources in the Appalachian basin: distribution, geologic framework, and geochemical character

    Science.gov (United States)

    Milici, Robert C.; Polyak, Désirée E.; Ruppert, Leslie F.; Ryder, Robert T.

    2014-01-01

    Although small quantities of coal first were produced from the Appalachian basin in the early 1700s, the first production statistics of significance were gathered during the census of 1830 (Eavenson, 1942). Since then, about 35 billion short tons of bituminous coal have been produced from the Appalachian basin from an original potential coal reserve (PCR(o)) estimated to range from about 60 to 90 billion short tons. The term “reserve” refers to economically producible coal, and a “potential coal reserve” (PCR(n)) is an estimate of the amount of coal economically recoverable in a region (State, coal field) over a defined time period (n = number of years) and under a range of economic, societal, and technological conditions. Thus, the current cumulative production plus the PCR(n) equals an estimated cumulative production (ECP(n)). The maps in this report (oversized figures 1, 2, 3, and 4) were produced from a digital database of historical and current coal production records by county. Sources of the original data include various State geological surveys, the U.S. Geological Survey, the former U.S. Bureau of Mines, and the U.S. Department of Energy’s Energy Information Administration. This report is part of the U.S. Geological Survey’s National Coal Resource Assessment Project.

  13. Influence of natural weathering of two medium-volatile bituminous coals of similar rank on coke quality; Influencia de la alteracion meteorica de dos carbones coquizables con contenido medio de materia volatil en la calidad del coque producido

    Energy Technology Data Exchange (ETDEWEB)

    Casal, M.D.; Diez, M.A.; Alvarez, R.; Barriocanal, C.; Canga, C.S.; Pis, J.J. [Instituto Nacional del Carbon. Oviedo (Spain)

    1998-06-01

    The study of the weathering of the two bituminous coals stored at the INCAR stockyard and its influence on coke quality is presented. These coals of similar rank are present in industrial blends used by the Corporation Siderurgica Integral (CSI) for the production of blast-furnace coke. Of all the techniques used to determine the degree of weathering, via thermoplastic properties. Gieseler plastometry was found to be the most sensitive. Coking tests were carried out in the semi-industrial coking plant at INCAR. The effect of weathering on each coal series is completely different. Weathering produces a loss of maximum fluidity accompanied by a decrease in aliphatic hydrogen in both coals. However, the los rate is different in each case. Coke quality clearly decreases in one, while in the other improves at first but then gradually deteriorates. An improvement in coke quality due to weathering not only affects some high-volatile coals as it is well known but also medium-volatile coals. (Author) 16 refs.

  14. Enteric virus removal inactivation by coal-based media

    Energy Technology Data Exchange (ETDEWEB)

    Gupta, A.; Chaudhuri, M. [Indian Institute of Technology, Kanpur (India). Dept. of Civil Engineering

    1995-02-01

    Four coal-based media, viz. alum-pretreated or ferric hydroxide-impregnated Giridih bituminous coal and lignite (alum-GBC, Fe-GBC; alum-lignite and Fe-Lignite) were laboratory tested to assess their potential in removing/inactivating enteric viruses in water. Batch-sorption screening tests, employing a poliovirus-spiked canal water, indicated high poliovirus sorption by Fe-GBC and alum-GBC in a short contact time of 5 min. Based on the results of further batch-sorption tests, using silver incorporated media (alum/Ag-GBC, alum-GBC-Ag and Fe-GBC-Ag), as well as aesthetic water quality consideration and previous findings on removal of coliforms and turbidity, alum/Ag-GBC, alum-GBC and alum-GBC-AG were included in downflow column studies employing poliovirus-spiked canal water. All three media showed potential in removing/inactivating enteric viruses. In a separate column study employing a joint challenge of poliovirus and rotavirus, alum/Ag-GBC removed 59.3-86.5% of the viruses along with more than 99% reduction in indigenous heterotrophic bacteria. Alum/silver-pretreated bituminous coal medium appears promising for use in household water filters in rural areas of the developing world. However, improved medium preparation to further enhance its efficiency is needed; also, its efficacy in removing/inactivating indigenous enteric bacteria, viruses and protozoa has to be ensured and practicalities or economics of application need to be considered.

  15. Morphology and microstructure of co-pyrolysis char from bituminous coal blended with lignocellulosic biomass: Effects of cellulose, hemicellulose and lignin

    International Nuclear Information System (INIS)

    Wu, Zhiqiang; Yang, Wangcai; Chen, Lin; Meng, Haiyu; Zhao, Jun; Wang, Shuzhong

    2017-01-01

    Highlights: • Influence of biomass model compounds on co-pyrolysis char structure was investigated. • Transformation of carbon structure was explored by Raman and spectral deconvolution. • Evolution of surface morphology was quantitatively described by the fractal analysis. • Three biomass model compounds showed different influence on the structure evolution. - Abstract: Co-pyrolysis of coal and lignocellulose biomass and coal is the key step of other co-thermochemical conversion, and conversion of co-pyrolysis char is the rate-determining step of co-gasification and co-combustion. In this paper, the influence of biomass model compounds (cellulose, hemicellulose, and lignin, abbreviated as CE, HCE and LIG) on the co-pyrolysis char structure transformation was investigated. Carbon structure and surface morphology of co-pyrolysis char were examined by Raman spectroscopy and scanning electron microscope (SEM). A comprehensive comparison of Raman spectral deconvolution methods based on various fitting functions and peak numbers was explored, and Gaussian-Lorentzian-function with no less than nine peaks showed the best performance. Three biomass model show different effects on the transformation of microstructure structure. The addition of CE increased the ordering of char structure. HCE promoted the disordering degree of microstructure structure and reached the maximum at 50% HCE mass ratio. The microstructure structure changes of co-pyrolysis char for 25% and 50% LIG mass ratios were not evident, while 75% LIG increased the disordering degree of the co-pyrolysis char. Fractal analysis was applied for describing the char surface morphology quantitatively with two and three-dimensional fractal dimensions. CE decreased the fractal dimensions of co-pyrolysis, and the influence of HCE and LIG depended on the mass ratio.

  16. Cellulose-containing Waste and Bituminized Salts

    International Nuclear Information System (INIS)

    Valcke, E.

    2005-01-01

    In Belgium, Medium-Level radioactive Waste (MLW) would be eventually disposed off in an underground repository in a geological formation such as the Boom Clay, which is studied as a reference host rock formation. MLW contains large quantities of non-radioactive chemicals that are released upon contact with pore water. It could be the case, for instance, for plutonium bearing cellulosic waste - such as paper tissues used to clean alpha glove boxes - issued from nuclear fuel fabrication (Belgonucleaire). At high pH, as in a disposal gallery backfilled with cement, the chemical degradation of cellulose will generate water-soluble products that may form strong complexes with actinides such as Am, Pu, Np, and U. This could lower the sorption of these elements onto the clay minerals, and hence increase their migration through the clay barrier. Another chemical perturbation could occur from the 3000 m 3 of so-called Eurobitum bituminised MLW, with precipitation sludges from the chemical treatment of spent nuclear fuel, and containing about 750 tons of NaNO 3 . The presence of NaNO 3 in this waste will give rise to several processes susceptible to affect the safety of the disposal system. Amongst others, it is necessary to verify that the swelling pressure of bitumen on the gallery wall and the osmotic pressure within the near-field are not too high to induce a fissuration of the host rock, leading to the formation of preferential migration pathways. The major objective of our work is to obtain a broad understanding of the different processes induced by the release of non-radioactive chemicals in the clay formation, to assess the chemical compatibility of different MLW forms with the clay

  17. Development of New Bituminous Pavement Design Method

    DEFF Research Database (Denmark)

    Ullidtz, Per

    The report and work of COST Action 333 sets in place the foundation for a coherent, cost-effective and harmonised European pavement design method. In order to do this, the work programme focused on information gathering, identification of requirements and the selection of the necessary design...

  18. Deformation Properties and Fatigue of Bituminous Mixtures

    Directory of Open Access Journals (Sweden)

    Frantisek Schlosser

    2013-01-01

    Full Text Available Deformation properties and fatigue performance are important characteristics of asphalt bound materials which are used for construction of pavement layers. Viscoelastic asphalt mixtures are better characterized via dynamic tests. This type of tests allows us to collate materials with regard to axle vibrations which lie usually in the range of 6 Hz–25 Hz for standard conditions. Asphalt modified for heat sensitivity in the range from −20°C to +60°C has significant impact on the overall characteristics of the mixture. Deformation properties are used as inputs for empirical mixture design, and fatigue performance of asphalt mixtures reflects the parameters of functional tests. Master curves convey properties of asphalt mixtures for various conditions and allow us to evaluate them without the need of time expensive testing.

  19. Bituminization of liquid radioactive wastes. Part 2

    International Nuclear Information System (INIS)

    Gradev, G.D.; Ivanov, V.I.; Stefanova, I.G.; Milusheva, A.G.; Guteva, E.S.; Stefanov, G.I.; G'oshev, G.S.

    1991-01-01

    The leaching of alcaline cations, as well as of chloride, sulphate and borate anions and radionuclides was studied. The leach rates and the diffusion coefficients of some of the incorporated ions for the salt-bitumen products obtained from Bulgarian bitumens (road bitumen PB 66/90 and hydroinsulating bitumen HB 80/25) and salts (chlorides, sulphates, borates, salt mixtures modelling the concentrate from the evaporators at the Kozloduy NPP and radionuclides) were determined. Most suitable for technological research under the conditions of the Kozloduy NPP proved to be the road bitumen PB 66/90 with softening temperature at 48 o C. The optimum bitumen/salt ratio is found to be about 1.2. Admixtures of natural inorganic sorbents (clinoptiolite, vermiculite and bentonite) in quantities of 5-10% are found to decrease the leaching of radionuclides from the bitumen products. The action of the hydromica vermiculite is particularly pronounced. 6 tabs., 5 refs

  20. Calorific efficiency of bituminous coal hydrogenation

    Energy Technology Data Exchange (ETDEWEB)

    Wilde, H.; Schappert, H.

    1942-02-20

    The calorific efficiency of coal hydrogenation was the relation between the calories contained in the desired final product, that is, gasoline and liquefied petroleum gas (L.P.G.), and the calories contained in the coal required to produce the desired final product. A table of the efficiency of the power plant was given. Calorific efficiency of hydrogen production was then discussed, with figure 1 showing the heat flow diagram; tables 1 and 2 contained data for the coke plant and the water gas plant, respectively. Calorific efficiency of hydrogenation proper was discussed, with figure 2 showing the heat flow diagram for the production of aviation gasoline, and with the corresponding energy values given in table 3. The next topic of discussion was the possibility of increasing the calorific efficiency of total hydrogenation by: introduction of Linde process, utilization of kiln residues, introduction of paste heat exchange, and recovering the waste heat from the hot letdown and products. Table 4 gave data on the hydrogenation for aviation gasoline. The efficiency of hydrogen production was 26.3% without counting possible improvements or by-products for the process. The efficiency of the hydrogenation process itself was 49.0% for production of aviation gasoline and 51.1% for production of auto gasoline. However, for combined hydrogenation and hydrogen production, the efficiencies became 27.2% and 28.9% respectively. If all of the improvements mentioned above (including hydrogen production by Linde-process decomposition of product gases) were introduced, the efficiencies would rise to about 34.6% and 36.8%, respectively. 5 diagrams, 4 tables

  1. Solar Radiation effect on the bituminous binder

    International Nuclear Information System (INIS)

    Tadeo Rico, A.; Torres Perez, A.

    2010-01-01

    Asphalt, used as binder in road construction, becomes more brittle and harder during working life on the surface of the road pavement, conducting toward their deterioration. This is caused by the oxidation of the molecular functional groups of the asphalt molecular structure. Moreover, it is observed that ultraviolet radiation increases the oxidation process. However, the effect of solar light on the asphalt degradation has been poorly researched. The aim of this work is to study asphalt ageing caused by effect of solar radiation, by using standard test. Four commercial asphalts from different companies were selected: two with penetration number 50/70, and the other two polymer modified asphalts. From each of the asphalts forty samples were taken off and placed in four different aging conditions of temperature and radiation for a period ranging from 40 to 500 days. Ring and Ball test, and Fraass breaking Point test, were used to analyse the changes of asphalt properties after exposition to solar radiation. The results of the four analyzed asphalts showed a distinct behaviour; not only in the test temperature increase but also in the rate. Another experiment was carried out. Samples from a hot mix asphalt batch were placed under solar radiation, and were compacted by the Marshall procedure after increasing periods of time. Density and resistance to plastic flow using Marshall Apparatus were measured. Results showed an increase in the stability of samples under radiation. Both experiments show that the solar radiation is enough to cause changes in the asphalt molecular structure due to oxidation. So that, the study of the effect of the solar radiation on the asphalt properties could be a good tool to asses the performances of asphalt pavement. (Author) 26 refs.

  2. Studies of the fate of sulfur trioxide in coal-fired utility boilers based on modified selected condensation methods.

    Science.gov (United States)

    Cao, Yan; Zhou, Hongcang; Jiang, Wu; Chen, Chien-Wei; Pan, Wei-Ping

    2010-05-01

    The formation of sulfur trioxide (SO(3)) in coal-fired utility boilers can have negative effects on boiler performance and operation, such as fouling and corrosion of equipment, efficiency loss in the air preheater (APH), increase in stack opacity, and the formation of PM(2.5). Sulfur trioxide can also compete with mercury when bonding with injected activated carbons. Tests in a lab-scale reactor confirmed there are major interferences between fly ash and SO(3) during SO(3) sampling. A modified SO(3) procedure to maximize the elimination of measurement biases, based on the inertial-filter-sampling and the selective-condensation-collecting of SO(3), was applied in SO(3) tests in three full-scale utility boilers. For the two units burning bituminous coal, SO(3) levels starting at 20 to 25 ppmv at the inlet to the selective catalytic reduction (SCR), increased slightly across the SCR, owing to catalytic conversion of SO(2) to SO(3,) and then declined in other air pollutant control device (APCD) modules downstream to approximately 5 ppmv and 15 ppmv at the two sites, respectively. In the unit burning sub-bituminous coal, the much lower initial concentration of SO(3) estimated to be approximately 1.5 ppmv at the inlet to the SCR was reduced to about 0.8 ppmv across the SCR and to about 0.3 ppmv at the exit of the wet flue gas desulfurization (WFGD). The SO(3) removal efficiency across the WFGD scrubbers at the three sites was generally 35% or less. Reductions in SO(3) across either the APH or the dry electrostatic precipitator (ESP) in units burning high-sulfur bituminous coal were attributed to operating temperatures being below the dew point of SO(3).

  3. Experimental evaluation of high performance base course and road base asphalt concrete with electric arc furnace steel slags.

    Science.gov (United States)

    Pasetto, Marco; Baldo, Nicola

    2010-09-15

    The paper presents the results of a laboratory study aimed at verifying the use of two types of electric arc furnace (EAF) steel slags as substitutes for natural aggregates, in the composition of base course and road base asphalt concrete (BBAC) for flexible pavements. The trial was composed of a preliminary study of the chemical, physical, mechanical and leaching properties of the EAF steel slags, followed by the mix design and performance characterization of the bituminous mixes, through gyratory compaction tests, permanent deformation tests, stiffness modulus tests at various temperatures, fatigue tests and indirect tensile strength tests. All the mixtures with EAF slags presented better mechanical characteristics than those of the corresponding asphalts with natural aggregate and satisfied the requisites for acceptance in the Italian road sector technical standards, thus resulting as suitable for use in road construction. Copyright 2010 Elsevier B.V. All rights reserved.

  4. Report on results for fiscal 1997 (B edition) on development of coal liquefaction technology. Development of bituminous coal liquefaction technology (research by pilot plant) 1/2; 1997 nendo sekitan ekika gijutsu kaihatsu seika hokokusho (B ban). Rekiseitan ekika gijutsu no kaihatsu (pilot plant ni yoru kenkyu) 2/2

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-06-01

    This paper reports the operation of a pilot plant of a bituminous coal liquefaction technology as the 1/2 report. The operation research of the Run-2 through the Run-4-2 was conducted using, as the material, tanitoharum coal which is operating basis coal. The Run-2 achieved a coal charging continuous operation for 42 days. During the operation of 80% slurry supply load, various data were obtained including material balance under the NEDOL standard liquefaction conditions, with a liquefaction yield of 54% daf coal achieved. Steam blowing into the heating tube was found effective as measures to cope with coking generation in the heating furnace of a vacuum distillation tower. The softening point of liquefaction residuals was improved to 178 degrees C through the extracting adjustment of reduced pressure heavy gravity light oil fraction for washing. The Run-3/4-1 achieved a plant load ratio of 100% and a long-term coal charging continuous operation for 80 days, while the Run-3 achieved a slurry supply load of 100% under the NEDOL standard liquefaction conditions. The Run-4-1 achieved a high liquefaction yield of 58wt% daf coal. Performance was confirmed of a neutron beam source irradiation apparatus/measuring system and a tracer injection equipment. (NEDO)

  5. Overlay design method based on visual pavement distress.

    Science.gov (United States)

    1978-01-01

    A method for designing the thickness of overlays for bituminous concrete pavements in Virginia is described. In this method the thickness is calculated by rating the amount and severity of observed pavement distress and determining the total accumula...

  6. Energy Analysis of a Biomass Co-firing Based Pulverized Coal Power Generation System

    Directory of Open Access Journals (Sweden)

    Marc A. Rosen

    2012-03-01

    Full Text Available The results are reported of an energy analysis of a biomass/coal co-firing based power generation system, carried out to investigate the impacts of biomass co-firing on system performance. The power generation system is a typical pulverized coal-fired steam cycle unit, in which four biomass fuels (rice husk, pine sawdust, chicken litter, and refuse derived fuel and two coals (bituminous coal and lignite are considered. Key system performance parameters are evaluated for various fuel combinations and co-firing ratios, using a system model and numerical simulation. The results indicate that plant energy efficiency decreases with increase of biomass proportion in the fuel mixture, and that the extent of the decrease depends on specific properties of the coal and biomass types.

  7. Base

    DEFF Research Database (Denmark)

    Hjulmand, Lise-Lotte; Johansson, Christer

    2004-01-01

    BASE - Engelsk basisgrammatik er resultatet af Lise-Lotte Hjulmands grundige bearbejdning og omfattende revidering af Christer Johanssons Engelska basgrammatik. Grammatikken adskiller sig fra det svenske forlæg på en lang række punkter. Den er bl.a. tilpasset til et dansk publikum og det danske...

  8. Method development for mass spectrometry based molecular characterization of fossil fuels and biological samples

    Science.gov (United States)

    Mahat, Rajendra K.

    In an analytical (chemical) method development process, the sample preparation step usually determines the throughput and overall success of the analysis. Both targeted and non-targeted methods were developed for the mass spectrometry (MS) based analyses of fossil fuels (coal) and lipidomic analyses of a unique micro-organism, Gemmata obscuriglobus. In the non-targeted coal analysis using GC-MS, a microwave-assisted pressurized sample extraction method was compared with the traditional extraction method, such as Soxhlet. On the other hand, methods were developed to establish a comprehensive lipidomic profile and to confirm the presence of endotoxins (a.k.a. lipopolysaccharides, LPS) in Gemmata.. The performance of pressurized heating techniques employing hot-air oven and microwave irradiation were compared with that of Soxhlet method in terms of percentage extraction efficiency and extracted analyte profiles (via GC-MS). Sub-bituminous (Powder River Range, Wyoming, USA) and bituminous (Fruitland formation, Colorado, USA) coal samples were tested. Overall 30-40% higher extraction efficiencies (by weight) were obtained with a 4 hour hot-air oven and a 20 min microwave-heating extraction in a pressurized container when compared to a 72 hour Soxhlet extraction. The pressurized methods are 25 times more economic in terms of solvent/sample amount used and are 216 times faster in term of time invested for the extraction process. Additionally, same sets of compounds were identified by GC-MS for all the extraction methods used: n-alkanes and diterpanes in the sub-bituminous sample, and n-alkanes and alkyl aromatic compounds in the bituminous coal sample. G. obscuriglobus, a nucleated bacterium, is a micro-organism of high significances from evolutionary, cell and environmental biology standpoints. Although lipidomics is an essential tool in microbiological systematics and chemotaxonomy, complete lipid profile of this bacterium is still lacking. In addition, the presence of

  9. Simulation of one-dimensional heat transfer system based on the blended coal combustion

    Science.gov (United States)

    Jin, Y. G.; Li, W. B.; Cheng, Z. S.; Cheng, J. W.; liu, Y.

    2017-12-01

    In this paper, the supercritical boiler thermodynamic calculation model is studied. Three types of heat exchangers are proposed, namely furnace (total radiation type), semi-radiation and convection, and discussed. Two cases were simulated - mixing of two bituminous coals and mixing of a bituminous coal and lignite- order to analyze the performance on the flue gas side. The study shows that the influence of flue air leakage and gas distribution coefficient on the system.

  10. Innovative Additive for Bitumen Based on Processed Fats

    Science.gov (United States)

    Babiak, Michał; Kosno, Jacek; Ratajczak, Maria; Zieliński, Krzysztof

    2017-10-01

    Various additives, admixtures and modifiers are used to improve technical properties and strength characteristics of building materials. Manufacturers of waterproofing materials, concrete, ceramics and bitumen have to use innovative, increasingly complex and costly additives, admixtures or modifiers. As a result, simple and inexpensive substances have been replaced by complex, long chain polymers, multi component resins or plastics. For economic and ecological reasons waste materials are more frequently used as additives, admixtures and modifiers. Nowadays the most commonly used physical modifiers of bitumen belong to the group of polymers - large molecular organic compounds of natural origin or being the result of planned chemical synthesis. Polymers are substances that do not chemically react with bitumen, they act as fillers or create a spatial network within bitumen (the so called physical cross-linking). The development of organic chemistry has allowed the synthesis of a number of substances chemically modifying bitumen. The most promising are heterocyclic organic compounds belonging to the group of imidazolines. The aim of the study presented in this paper was to demonstrate the suitability of processed natural and post-refining fat waste (diamidoamine dehydrate) as bitumen modifier. This paper discusses the impact of adding technical imidazoline on selected bitumen characteristics. Samples of bitumen 160/220, which is most commonly used for the production of waterproofing products, were analysed. For base bitumen and bitumen modified with technical imidazoline the following measurements were taken: measurement of the softening point by Ball and Ring method, determination of the breaking point by Fraass method and needle penetration measurement at 25°C. Later the samples were aged using TFOT laboratory method and the basic characteristics were determined again. The results showed that a small amount of imidazoline improved bitumen thermoplastic parameters at

  11. Characterizing volumetric deformation behavior of naturally occuring bituminous sand materials

    CSIR Research Space (South Africa)

    Anochie-Boateng, Joseph

    2009-05-01

    Full Text Available indicated that the considerable amount of bitumen in the oil sands, high applied loads from mining equipment and seasonal changes in temperature are major fac- tors that control the modulus and deformation behavior of oil sands (Joseph 2002). To date... angle and cohesion are the material properties used for modeling the strength and stiffness behavior. Bulk modulus is an important material property that describes the resistance to volume change when an element of soil is subjected to hydrostat- ic...

  12. Shear strength properties of naturally occurring bituminous sands

    CSIR Research Space (South Africa)

    Anochie-Boateng, Joseph

    2009-06-01

    Full Text Available on the oil sand materials with bitumen contents of 8.5%, 13.3% and 14.5% at 20C and 30C test temperatures. Results from the two tests could not be effectively compared since the triaxial tests produced zero fric-tion angles for all the oil sand materials...

  13. Permanent deformation behavior of naturally occurring bituminous sands

    CSIR Research Space (South Africa)

    Anochie-Boateng, Joseph

    2008-01-01

    Full Text Available were compacted close to field densities and then tested for permanent deformation at two temperatures using a newly proposed test procedure. The procedure applied stress states and ratios determined from field-loading characteristics of haul trucks...

  14. Advanced testing and characterization of transportation soils and bituminous sands

    CSIR Research Space (South Africa)

    Anochie-Boateng, Joseph

    2007-12-01

    Full Text Available , Illinois Doctoral Committee: Associate Professor Erol Tutumluer, Chair Professor Imad L. Al-Qadi Professor Emeritus Samuel H. Carpenter Professor Emeritus Marshall R. Thompson Dr. Liqun Chi, Caterpillar Inc., Peoria, IL ii ABSTRACT... ................................................................. 30 2.5 Review of Wheel-Soil Interaction Models ........................................................... 35 2.5.1 Vertical Stress-Displacement (Pressure-Sinkage) Models ............................ 36 2.5.2 Horizontal Shear Stress...

  15. Natural analogues of bitumen and bituminized radioactive waste

    International Nuclear Information System (INIS)

    Hellmuth, K.-H.

    1989-07-01

    Occurrences of natural bitumen provide possibilities to identify and assess materials, processes, phenomena and conditions in nature which can serve as model cases valid also with respect to a final repository. Natural bitumens meet the basic requirements for use as natural analogues. In natural sites, processes of bitumen formation and degradation often work simultaneously. The major processes are thermal alteration, evaporation, reaction with water, biodegradation, oxidation, weathering and radiation degradation. Progress in analytical organic geochemistry made during recent years has enabled a deeper understanding of the structural and compositional effects of these processes on bitumen. This is necessary in natural analogue applications. The time scales involved in degradation processes, as observed in natural occurrences, exceed the time scales dictated by the half-lives of most important fission products in low and medium level waste by orders of magnitude. Only exposure to the weather at the surface leads to a more rapid destruction of bitumen. Trace metals in bitumen arenot released until the matrix is completely destroyed. Products of radiation degradation and weathering of bitumen are able, to a certain degree, to delay migration of the metal ions released. Impregnation with bitumen may effectively reduce the microbial decomposition of easily destructable organic waste components, as can be deduced on the basis of the excellent preservation of fossils observed in bitumen. The complexity of all the natural sites described requires extensive understanding of the origin and kind of organic material in bitumen, its maturation, migration, alteration and degradation and of the geological and tectonic evolution of the site. The latter is used for establishing the time scale

  16. Provenance Study Of Bituminous Sands In Eastern Dahomey Basin ...

    African Journals Online (AJOL)

    The separation of these heavy minerals using bromoform (specific gravity 2.85) and slide examination under the petrographic microscope indicated the presence of zircon, rutile, staurolite, sillimanite, kyanite, garnet and epidote. Opaque minerals dominate the assemblage and they occur in significant quantities in some ...

  17. An evaluation of fracture toughness of bituminous coal

    International Nuclear Information System (INIS)

    Pathan, A.G.

    2005-01-01

    The role of fracture mechanics in the design of rock structures is vitally important. However, because of the complexities of rock structures and lack of understanding of the fundamentals of the failure mechanism, it has become customary to use the engineering properties approach in the design of stable rock structures. Recently considerable attention has been given and attempts are being made to apply the fracture mechanics approach to the design of safe mining structures. In mining engineering the fracture mechanics may be applied to calculate the formation of fracture zones around mine opening, thus estimating support requirements and formulating guide lines for the selection of mine roadway support system. The research work presented here is concerned with the evaluation of fracture toughness of coal under laboratory conditions. Diametral compression test method is used to determine the fracture toughness parameter of coal in the opening model failure. The effect of crack length and dimensionless crack length on the fracture toughness was studied also. A laboratory investigation of fracture toughness of coal in tensile mode failure has led to the conclusion that fracture toughness could be treated as a material property. (author)

  18. Characterization and Identification of Bituminous Materials Modified with Montmorillonite Nanoclay

    NARCIS (Netherlands)

    Liu, G.

    2011-01-01

    Montmorillonite (Mt) nanoclay is a layered silicate mineral with a 2:1-type layer structure, two tetrahedrals sandwiching one octahedral. In recent decades, it is successfully introduced into polymer systems to form polymer-clay nanocomposites (PCN) in which the silicate layers of the Mt are

  19. Full depth bituminous recycling of I-70, Thomas County, Kansas

    Science.gov (United States)

    2004-01-01

    In 1990, 13 full depth asphalt pavement test sections were built on a portion of I-70 in Thomas County, Kansas. Various combinations of hot mix and cold recycle mixes with different additives were used to build the test sections. Two of the test sect...

  20. 30 CFR 75.380 - Escapeways; bituminous and lignite mines.

    Science.gov (United States)

    2010-07-01

    ... coil at least eight inches in length. The spiraled coil must be placed within reach of the lifeline..., provided they are located on or near a working section and are moved as the section advances or retreats... located on or near a working section that are moved as the section advances or retreats; (E) Pumps...

  1. Bituminization process of radioactive liquid wastes by domestic bitumen

    International Nuclear Information System (INIS)

    Sang, H.L.

    1977-11-01

    A study has been carried out of the incorporation of intermediate level wastes in bitumen. Two kinds of wastes: a) an evaporator concentrate from a PWR (containing boric acid), b) second cycle wastes from the Purex process (containing sodium salts), were satisfactorily incorporated into a mixture of straight and blown domestic bitumen, to yield a product containing 50wt% solids. The products were stable to radiation exposure of 5'8x10 8 rads. Leach rates were measured in both distilled and sea water over periods up to 200 days at 5 0 C and 25 0 C and at both 1 atm and 8 atm pressure. Results confirmed that long term storage of the products would be satisfactory

  2. Use of expanded clay aggregate in bituminous construction.

    Science.gov (United States)

    1959-01-01

    In an effort to find a solution to the shortage of aggregate, for use in highway construction, Louisiana Department of Highways initiated a study. : In early 1955, we started experimenting with expanded aggregate or lightweight aggregate as commonly ...

  3. Poultry litter-based activated carbon for removing heavy metal ions in water.

    Science.gov (United States)

    Guo, Mingxin; Qiu, Guannan; Song, Weiping

    2010-02-01

    Utilization of poultry litter as a precursor material to manufacture activated carbon for treating heavy metal-contaminated water is a value-added strategy for recycling the organic waste. Batch adsorption experiments were conducted to investigate kinetics, isotherms, and capacity of poultry litter-based activated carbon for removing heavy metal ions in water. It was revealed that poultry litter-based activated carbon possessed significantly higher adsorption affinity and capacity for heavy metals than commercial activated carbons derived from bituminous coal and coconut shell. Adsorption of metal ions onto poultry litter-based carbon was rapid and followed Sigmoidal Chapman patterns as a function of contact time. Adsorption isotherms could be described by different models such as Langmuir and Freundlich equations, depending on the metal species and the coexistence of other metal ions. Potentially 404 mmol of Cu2+, 945 mmol of Pb2+, 236 mmol of Zn2+, and 250-300 mmol of Cd2+ would be adsorbed per kg of poultry litter-derived activated carbon. Releases of nutrients and metal ions from litter-derived carbon did not pose secondary water contamination risks. The study suggests that poultry litter can be utilized as a precursor material for economically manufacturing granular activated carbon that is to be used in wastewater treatment for removing heavy metals.

  4. Lawrence Livermore National Laboratory underground coal gasification data base. [US DOE-supported field tests; data

    Energy Technology Data Exchange (ETDEWEB)

    Cena, R. J.; Thorsness, C. B.

    1981-08-21

    The Department of Energy has sponsored a number of field projects to determine the feasibility of converting the nation's vast coal reserves into a clean efficient energy source via underground coal gasification (UCG). Due to these tests, a significant data base of process information has developed covering a range of coal seams (flat subbituminous, deep flat bituminous and steeply dipping subbituminous) and processing techniques. A summary of all DOE-sponsored tests to data is shown. The development of UCG on a commercial scale requires involvement from both the public and private sectors. However, without detailed process information, accurate assessments of the commercial viability of UCG cannot be determined. To help overcome this problem the DOE has directed the Lawrence Livermore National Laboratory (LLNL) to develop a UCG data base containing raw and reduced process data from all DOE-sponsored field tests. It is our intent to make the data base available upon request to interested parties, to help them assess the true potential of UCG.

  5. Transuranic contaminated waste form characterization and data base

    International Nuclear Information System (INIS)

    Kniazewycz, B.G.; McArthur, W.C.

    1980-07-01

    This volume contains appendices A to F. The properties of transuranium (TRU) radionuclides are described. Immobilization of TRU wastes by bituminization, urea-formaldehyde polymers, and cements is discussed. Research programs at DOE facilities engaged in TRU waste characterization and management studies are described

  6. Transuranic contaminated waste form characterization and data base

    Energy Technology Data Exchange (ETDEWEB)

    Kniazewycz, B.G.; McArthur, W.C.

    1980-07-01

    This volume contains appendices A to F. The properties of transuranium (TRU) radionuclides are described. Immobilization of TRU wastes by bituminization, urea-formaldehyde polymers, and cements is discussed. Research programs at DOE facilities engaged in TRU waste characterization and management studies are described.

  7. [Research and Design of an Experimental Apparatus Based on the "Open Fireplace" in Xuanwei District].

    Science.gov (United States)

    Yang, Jiapeng; Huang, Yunchao; Zi, Wenhua; Bai, Yunbao; Li, Guangjian; Ye, Lianhua; Zhou, Yongchun; Zhao, Guangqiang; Lei, Yujie; Chen, Xiaobo; Chen, Ying; Zhang Yanjun

    2016-02-01

    Xuanwei district in Yunnan Province of China has pretty high incidence of lung cancer in China, even a- round the world. Studies have shown that there exists a close relationship between lung cancer and local indoor air pollution caused by Bituminous coal. Considering that the indoor air pollution in Xuanwei District is caused by "open fireplace", an indoor air pollution simulation system was designed, and an F344 rats lung damage model was estab- lished for this indoor air pollution fireplace. The model is based on indoor air pollution simulation system with signal multiplexer control and multi-channel acquisition, and mining PID algorithm was used for polynomial fitting to each test point, and a relatively constant PM2. 5 air pollution status was simulated. The results showed that the system could simulate a variety of states of air pollution, provide a new test method for evaluation of human injury caused by indoor air pollution and a new idea for the study of the incidence of lung cancer in Xuanwei district and other places.

  8. Gasification under CO2–Steam Mixture: Kinetic Model Study Based on Shared Active Sites

    Directory of Open Access Journals (Sweden)

    Xia Liu

    2017-11-01

    Full Text Available In this work, char gasification of two coals (i.e., Shenfu bituminous coal and Zunyi anthracite and a petroleum coke under a steam and CO2 mixture (steam/CO2 partial pressures, 0.025–0.075 MPa; total pressures, 0.100 MPa and CO2/steam chemisorption of char samples were conducted in a Thermogravimetric Analyzer (TGA. Two conventional kinetic models exhibited difficulties in exactly fitting the experimental data of char–steam–CO2 gasification. Hence, a modified model based on Langmuir–Hinshelwood model and assuming that char–CO2 and char–steam reactions partially shared active sites was proposed and had indicated high accuracy for estimating the interactions in char–steam–CO2 reaction. Moreover, it was found that two new model parameters (respectively characterized as the amount ratio of shared active sites to total active sites in char–CO2 and char–steam reactions in the modified model hardly varied with gasification conditions, and the results of chemisorption indicate that these two new model parameters mainly depended on the carbon active sites in char samples.

  9. Determination of char combustion kinetics parameters: comparison of point detector and imaging-based particle-sizing pyrometry.

    Science.gov (United States)

    Schiemann, Martin; Geier, Manfred; Shaddix, Christopher R; Vorobiev, Nikita; Scherer, Viktor

    2014-07-01

    In this study, the char burnout characteristics of two German coals (a lignite and a high-volatile bituminous coal) were investigated using two different experimental configurations and optical techniques in two distinct laboratories for measurement of temperature and size of burning particles. The optical diagnostic hardware is quite different in the two systems, but both perform two-color pyrometry and optical sizing measurements on individual particles burning in isolation from each other in high-temperature laminar flows to characterize the char consumption kinetics. The performance of the specialized systems is compared for two different combustion atmospheres (with 6.6 and 12 vol.% O2) and gas temperatures between 1700 and 1800 K. The measured particle temperatures and diameters are converted to char burning rate parameters for several residence times during the course of the particles' burnout. The results confirm that comparable results are obtained with the two configurations, although higher levels of variability in the measured data were observed in the imaging-based pyrometer setup. Corresponding uncertainties in kinetics parameters were larger, and appear to be more sensitive to systematic measurement errors when lower oxygen contents are used in the experiments. Consequently, burnout experiments in environments with sufficiently high O2 contents may be used to measure reliable char burning kinetics rates. Based on simulation results for the two coals, O2 concentrations in the range 10%-30% are recommended for kinetic rate measurements on 100 μm particles.

  10. METHANE de-NOX for Utility PC Boilers

    Energy Technology Data Exchange (ETDEWEB)

    Bruce Bryan; Joseph Rabovitser; Serguei Nester; Stan Wohadlo

    2004-12-31

    Preparations for conducting large-scale combustion tests with caking bituminous coal continued during the start of this quarter. Major project accomplishments related to bituminous coal testing included: a CFD preheat model and evaluation, an update of the process flow diagram and a detailed preheat burner mechanical design (suitable for construction) for firing bituminous coal. Installation and testing of the 85 MMBtu/h bituminous coal preheating system was planned to take place before the end of December. Based on the inability to conduct testing in Riley's Commercial Burner Test Facility (CBTF) during freezing weather, a schedule review indicated required site work for testing bituminous coal at the CBTF could not be completed before freezing weather set in at the site. Further bituminous preheat modification work was put on hold and efforts turned to securing the test facility over the winter season. Bituminous coal tests are therefore delayed; April-May 2005 is earliest estimate of when testing can resume. A request for a time extension was submitted to DOE to extend the project through September 2005 to allow time to secure additional funding and complete the bituminous coal testing. Removal of the PRB PC Preheater from the CBTF burner deck was completed. Decommissioning of the CBTF for the winter was also completed.

  11. Development of non-petroleum-based binders for use in flexible pavements - phase II.

    Science.gov (United States)

    2015-10-01

    Bio-binders can be utilized as asphalt modifiers, extenders, and replacements for conventional asphalt in bituminous binders. : From the rheology results of Phase I of this project, it was found that the bio-binders tested had good performance, simil...

  12. Using Field Data for Energy Efficiency Based on Maintenance and Operational Optimisation. A Step towards PHM in Process Plants

    Directory of Open Access Journals (Sweden)

    Micaela Demichela

    2018-03-01

    Full Text Available Energy saving is an important issue for any industrial sector; in particular, for the process industry, it can help to minimize both energy costs and environmental impact. Maintenance optimization and operational procedures can offer margins to increase energy efficiency in process plants, even if they are seldom explicitly taken into account in the predictive models guiding the energy saving policies. To ensure that the plant achieves the desired performance, maintenance operations and maintenance results should be monitored, and the connection between the inputs and the outcomes of the maintenance process, in terms of total contribution to manufacturing performance, should be explicit. In this study, a model for the energy efficiency analysis was developed, based on cost and benefits balance. It is aimed at supporting the decision making in terms of technical and operational solutions for energy efficiency, through the optimization of maintenance interventions and operational procedures. A case study is here described: the effects on energy efficiency of technical and operational optimization measures for bituminous materials production process equipment. The idea of the Conservation Supply Curve (CSC was used to capture both the cost effectiveness of the measures and the energy efficiency effectiveness. The optimization was thus based on the energy consumption data registered on-site: data collection and modelling of the relevant data were used as a base to implement a prognostic and health management (PHM policy in the company. Based on the results from the analysis, efficiency measures for the industrial case study were proposed, also in relation to maintenance optimization and operating procedures. In the end, the impacts of the implementation of energy saving measures on the performance of the system, in terms of technical and economic feasibility, were demonstrated. The results showed that maintenance optimization could help in reaching

  13. Amenability of some Witbank bituminous ultra fine coals to binderless briquetting

    CSIR Research Space (South Africa)

    Mangena, SJ

    2004-10-15

    Full Text Available briquetting press, at various feed moisture contents. The formed briquettes were then tested for compressive strength and water resistance and the values correlated with the coal characteristics and the briquetting conditions. The coals were found...

  14. Development and evaluation of an automated reflectance microscope system for the petrographic characterization of bituminous coals

    Energy Technology Data Exchange (ETDEWEB)

    Hoover, D. S.; Davis, A.

    1980-10-01

    The development of automated coal petrographic techniques will lessen the demands on skilled personnel to do routine work. This project is concerned with the development and successful testing of an instrument which will meet these needs. The fundamental differences in reflectance of the three primary maceral groups should enable their differentiation in an automated-reflectance frequency histogram (reflectogram). Consequently, reflected light photometry was chosen as the method for automating coal petrographic analysis. Three generations of an automated system (called Rapid Scan Versions I, II and III) were developed and evaluated for petrographic analysis. Their basic design was that of a reflected-light microscope photometer with an automatic stage, interfaced with a minicomputer. The hardware elements used in the Rapid Scan Version I limited the system's flexibility and presented problems with signal digitization and measurement precision. Rapid Scan Version II was designed to incorporate a new microscope photometer and computer system. A digital stepping stage was incorporated into the Rapid Scan Version III system. The precision of reflectance determination of this system was found to be +- 0.02 percent reflectance. The limiting factor in quantitative interpretation of Rapid Scan reflectograms is the resolution of reflectance populations of the individual maceral groups. Statistical testing indicated that reflectograms were highly reproducible, and a new computer program, PETAN, was written to interpret the curves for vitrinite reflectance parameters ad petrographic.

  15. Case study: dynamic modulus characterization of naturally occurring bituminous sands for sustainable pavement applications

    CSIR Research Space (South Africa)

    Anochie-Boateng, Joseph

    2010-11-01

    Full Text Available . The presence of high bitumen content makes oil sand materials problematic for field operations of off-road haul trucks and shovels during the warm spring and summer months. The behavior of oil sand materials is primarily dependent upon stress states...

  16. Alternative Fillers for the Production of Bituminous Mixtures: A Screening Investigation on Waste Powders

    Directory of Open Access Journals (Sweden)

    Cesare Sangiorgi

    2017-06-01

    Full Text Available There has been a significant increase in the demand for using recycled materials in construction because of the lack and limitation of available natural resources. A number of industrial and domestic waste products are being used in the replacement of traditional materials for road construction, and many studies have been carried out in recent years on the use of different recycled materials in substitution of conventional fillers in Asphalt Concretes (AC. The aim of this laboratory research is to analyze the physical characteristics of three different recycled fillers and compare them with those of a traditional limestone filler. The alternative fillers presented in this paper are: a waste bleaching clay that comes from two consecutive stages in the industrial process for decolouring vegetable oils and producing biogas (Ud filler, a dried mud waste from a tungsten mine (MW filler and a recycled glass powder (Gl filler. Results show significant differences between the fillers, and, in particular, Rigden Voids (RV seem to have the largest potential influence on the rheology of ACs.

  17. Utilization of polyethylene terephthalate (PET) in bituminous mixture for improved performance of roads

    Science.gov (United States)

    Ahmad, A. F.; Razali, A. R.; Razelan, I. S. M.; Jalil, S. S. A.; Noh, M. S. M.; Idris, A. A.

    2017-05-01

    Plastic bottle for recycling can be found from the household waste stream, and most of them are made from Polyethylene Terephthalate. In this research, PET is utilized to explore the potential prospects to upgrade asphalt mixture properties. The objectives include deciding the best measure of PET to be used. For experimental, Marshall mix design was utilized to determine the ideal bitumen binder content and to test the modified mixture properties. The samples were created per the requirement for aggregate course wearing (ACW14) using the Standard Specification of Road Work (SSRW) in Malaysia. 20 samples were utilized to determine the binder content, and 30 samples were used to research the impact of modifying asphalt mixtures. 2%, 5%, 10%, 15% and 20% of PET by weight of the optimum binder content (4.8%) were tested. Optimum PET content is 10%, and the result shows a good stability with 16.824kN, 2.32g/cm3 bulk density, void filled with bitumen (VFB) with 71.35%, flow with 3.2248mm, air void (AV) with 4.53%, and void of mineral aggregate (VMA) with 15.15%. The outcomes showed that PET modifier gives better engineering properties. Therefore, 10% of PET by the weight of binder content was suggested as the best amount of the modifier.

  18. XRD and FT–IR investigations of sub-bituminous Assam coals

    Indian Academy of Sciences (India)

    TECS

    ash content (5⋅70 %wt). The percentage of ash is of signi- ficance in the usefulness of coals. On the other hand, the highest ash containing Tipong coal has lower sulphur content with a value of 4⋅14 (%wt). The composition of ash varies with the rank of coal and in some cases, variations are observed in the same seam.

  19. Use of bottom ash from thermal power plant and lime as filler in bituminous mixtures

    Directory of Open Access Journals (Sweden)

    López-López, E.

    2015-06-01

    Full Text Available This study focuses on the characterization of bottom ash (PCC-BA and determining the mechanical characteristics of hot mix asphalt (HMA using PCC-BA and hydrated lime (HL as filler. Physical and chemical characterization of the bottom ash was carried out to evaluate its eventual reutilization as filler substitute. The materials tested in this study were made using 0%, 25%, 50%, 70% and 100% of PCC-BA combined with HL. HMA mixes were evaluated in terms of their engineering properties, namely: air voids in the mixes, water sensitivity, stiffness modulus, performance in wheel tracking test and fatigue resistance. The results obtained indicate that HMA mixes with a filler blend of 70% PCC-BA and 30% HL fulfil European standards and are suitable for light traffic or small infrastructures.Este estudio se centra en la caracterización de las cenizas de fondo (PCC-BA y la determinación de las características mecánicas de mezclas bituminosas en caliente (HMA, utilizando cenizas de fondo y la cal hidratada (HL como filler. Se realizó la caracterización física y química de las cenizas de fondo para evaluar su empleo como sustituto de filler. Las mezclas ensayadas en este estudio se realizaron utilizando 0%, 25%, 50%, 70% y 100% de cenizas de fondo combinadas con cal hidratada. Se evaluaron propiedades ingenieriles de las mezclas bituminosas, tales como los huecos de aire en las mezclas, la sensibilidad al agua, el módulo de rigidez, el ensayo de pista y la resistencia a la fatiga. Los resultados obtenidos indican que las mezclas bituminosas fabricadas con una combinación de filler del 70% de cenizas de fondo y el 30% cal hidratada, cumplen con las normas europeas y son adecuados para su aplicación con tráficos ligeros o en pequeñas infraestructuras.

  20. Current developments in performance testing of bituminous emulsions used in chip seals

    CSIR Research Space (South Africa)

    Johannes, PT

    2015-08-01

    Full Text Available literature review identifying common distresses occurring in chip seals, both during construction and in-service. Emulsion properties related to specific distresses as well as potential laboratory test methods for evaluating the identified emulsion properties...

  1. Modeling of bubble growth in complex fluids. Application to radiolytic swelling of nuclear bituminized waste products

    International Nuclear Information System (INIS)

    Marchal, Antoine

    2015-01-01

    The aim of this PhD thesis is to predict the swelling of bitumen barrels in which radioactive salts are mixed. The bitumen exposed to radioactivity undergoes a chemical reaction: the radiolysis. This implies a generation of dihydrogen. The created is solubilized until the concentration reaches a limit value which is called saturation. Over this limit nucleation of bubbles is observed. Then they will grow thank to the contribution of the gas generated by radiolysis and they will be submitted to Archimede's principle so that they will rise in the fluid. The swelling is the result of the competition between generation and evacuation of gas. A model has been built to describe the evolution of a bubble population. Because of it is not possible to solve it analytically, a numerical program was developed. The results show that an increase of the fluid viscosity, the gas generation or the container height lead to an increase of the swelling and that an increase of the diffusion coefficient contributes to a decrease of the swelling. In the particular case of a yield stress fluid, the behavior of the bubble population is modified and the evacuation of gas is done with several shots, at the opposite of the case of a Newtonian fluid for which a stationary evacuation is reached. (author)

  2. Characterization of granite and limestone powders for use as fillers in bituminous mastics dosage

    Directory of Open Access Journals (Sweden)

    BRENO BARRA

    2014-06-01

    Full Text Available This paper discusses the importance of studies on materials known as fillers from different mineral origins, used in asphalt mixes, specifically in the formulation of mastics. The research was carried out on samples of limestone and granite rock filler and asphalt binder (50/70. The samples were evaluated through semiquantitative chemical analyses by X-ray fluorescence, granulometry by low angle laser emission, scanning electron microscopy, softening point tests, penetration tests, and aggregate-asphalt binder and aggregate-mastic adhesion tests. The results highlighted convergent trends, indicating that the active behavior of the fillers in the mastic formulation is not related to the size of the particles, but rather to their form, surface texture, specific surface area and mineralogical nature, allowing the filler activity concept to be divided into two components: physical (hardening and chemical (adhesion.

  3. Creep recovery behaviour of bituminous binders - relevance to permanent deformation of asphalt pavements

    CSIR Research Space (South Africa)

    Mturi, GAJ

    2012-05-01

    Full Text Available to differentiate the resistance to permanent deformation of different road binders. The MSCR test is essentially a repeated creep-recovery test at a fixed loading/unloading interval. This paper aims to highlight the limitations of the MSCR test but also show how...

  4. Rheological behaviour of polymer-modified bituminous mastics : a comparative analysis between physical and chemical modification

    OpenAIRE

    Shivokhin, Maxim; García Morales, Moisés; Partal López, Pedro; Cuadri Vega, Antonio Abad; Gallegos Montes, Críspulo

    2012-01-01

    Mastic, a bitumen/filler blend which naturally forms when bitumen is mixed with aggregates is the actual product used to bind coarse mineral particles in the asphalt mixtures. As a result, the characterisation of mastics is essential to improve the understanding of the response and performance of asphalt concrete pavements. On the other hand, the lack of experimental data concerning the behaviour of mastics and, above all, polymer-modified mastics has been lately claimed. In that sense, this ...

  5. Hydrogen production by two-stage co-pyrolysis of bituminous coal-polymers mixtures

    Czech Academy of Sciences Publication Activity Database

    Straka, Pavel; Kříž, Vlastimil

    2008-01-01

    Roč. 5, č. 1 (2008), s. 77-82 ISSN 1214-9705 R&D Projects: GA ČR(CZ) GA105/07/1407 Institutional research plan: CEZ:AV0Z30460519 Keywords : co-pyrolysis * coal * polymers Subject RIV: CD - Macromolecular Chemistry

  6. Aggregate strength for bituminous surfacings for low volume roads: a heavy vehicle simulator experience

    CSIR Research Space (South Africa)

    Paige-Green, P

    2004-09-01

    Full Text Available This paper discusses an investigation using the CSIR Transportek Heavy Vehicle Simulator (HVS) to determine the impact of using aggregates softer than specified in chip seals and to propose possible relaxations in the currently specified strength...

  7. Eastern gas shales bibliography selected annotations: gas, oil, uranium, etc. Citations in bituminous shales worldwide

    Energy Technology Data Exchange (ETDEWEB)

    Hall, V.S. (comp.)

    1980-06-01

    This bibliography contains 2702 citations, most of which are annotated. They are arranged by author in numerical order with a geographical index following the listing. The work is international in scope and covers the early geological literature, continuing through 1979 with a few 1980 citations in Addendum II. Addendum I contains a listing of the reports, well logs and symposiums of the Unconventional Gas Recovery Program (UGR) through August 1979. There is an author-subject index for these publications following the listing. The second part of Addendum I is a listing of the UGR maps which also has a subject-author index following the map listing. Addendum II includes several important new titles on the Devonian shale as well as a few older citations which were not found until after the bibliography had been numbered and essentially completed. A geographic index for these citations follows this listing.

  8. Temperature induced healing in strained bituminous materials observed by atomic force microscopy

    NARCIS (Netherlands)

    Nahar, S.N.; Schmets, A.J.M.; Scarpas, A.; Schitter, G.

    2013-01-01

    Bitumen is the binder in the composite material named asphalt concrete. Under cyclic mechanical loading of traffic passing over the pavement, eventually damage will initiate in the pavement, leading to eventual structural failure. This damaging process is accelerated by time dependent change of the

  9. Evaluation of the fatigue macro-cracking behavior of crumb rubber modified bituminous mixes

    Directory of Open Access Journals (Sweden)

    Moreno-Navarro, F.

    2014-09-01

    Full Text Available The use of crumb rubber modified bitumen (CRMB in asphalt mixes is a road engineering technology that has become increasingly important in recent years. Given the many economic and environmental benefits of this type of binder, the goal is to give CRMB the same level of performance as conventional polymer-modified bitumen. The appearance and propagation of cracks due to fatigue phenomena is one of the most common distresses affecting road pavements. Since crumb rubber enhances the mechanical properties of asphalt mixes, it can provide a viable solution for fatigue cracking. This paper presents the results of a comparative analysis of the fatigue-cracking behavior of asphalt mixtures manufactured with crumb rubber modified bitumen and polymer-modified bitumen.El empleo de betunes modificados con polvo de neumático usado en la fabricación de mezclas bituminosas es una de las técnicas que mayor auge está teniendo en los últimos años en la ingeniería de carreteras. Dadas sus grandes ventajas económicas y ambientales, este tipo de ligantes pretende conseguir prestaciones similares a la de los betunes modificados con polímeros utilizados habitualmente. La aparición de fisuras debido a fenómenos de fatiga es una de las patologías más comunes en firmes de carretera. Debido a las mejoras de las propiedades mecánicas del betún aportadas tras la incorporación de polvo de neumático, las mezclas fabricadas con estos ligantes se postulan como una posible solución a dicho problema. En este artículo se lleva a cabo un análisis comparativo del comportamiento a fisuración por fatiga realizado sobre mezclas bituminosas fabricadas con betún modificado con polvo de neumático y con polímeros.

  10. Interfacial interactions and mass transfer at the interfacial region of bituminous hydrocarbon mixtures

    NARCIS (Netherlands)

    Van Lent, D.Q.

    2014-01-01

    The adhesion between bitumen and aggregate is a complex process with numerous of variables. To improve the understanding of the bond between bitumen and aggregates in road applications, this research focuses on preferential adsorption, which is one aspect of bitumen-aggregate adhesion. The main

  11. The analysis and use of black steel slag in bituminous mixtures

    OpenAIRE

    Korbar, Primož

    2013-01-01

    In my diploma thesis I dealt with the use of black steel slag in road construction. In the introductory part of my work I discussed the general characteristics of the materials used in road construction and later on in the paper I focused exclusively on black steel slag. I described the history of the use of slag in the construction industry, various types of iron and steel slags, and the processing of black and white steel slag. I was interested in positive and negative characteristics of sl...

  12. Recommended procedures and techniques for the petrographic description of bituminous coals

    Science.gov (United States)

    Chao, E.C.T.; Minkin, J.A.; Thompson, C.L.

    1982-01-01

    Modern coal petrology requires rapid and precise description of great numbers of coal core or bench samples in order to acquire the information required to understand and predict vertical and lateral variation of coal quality for correlation with coal-bed thickness, depositional environment, suitability for technological uses, etc. Procedures for coal description vary in accordance with the objectives of the description. To achieve our aim of acquiring the maximum amount of quantitative information within the shortest period of time, we have adopted a combined megascopic-microscopic procedure. Megascopic analysis is used to identify the distinctive lithologies present, and microscopic analysis is required only to describe representative examples of the mixed lithologies observed. This procedure greatly decreases the number of microscopic analyses needed for adequate description of a sample. For quantitative megascopic description of coal microlithotypes, microlithotype assemblages, and lithotypes, we use (V) for vitrite or vitrain, (E) for liptite, (I) for inertite or fusain, (M) for mineral layers or lenses other than iron sulfide, (S) for iron sulfide, and (X1), (X2), etc. for mixed lithologies. Microscopic description is expressed in terms of V representing the vitrinite maceral group, E the exinite group, I the inertinite group, and M mineral components. volume percentages are expressed as subscripts. Thus (V)20(V80E10I5M5)80 indicates a lithotype or assemblage of microlithotypes consisting of 20 vol. % vitrite and 80% of a mixed lithology having a modal maceral composition V80E10I5M5. This bulk composition can alternatively be recalculated and described as V84E8I4M4. To generate these quantitative data rapidly and accurately, we utilize an automated image analysis system (AIAS). Plots of VEIM data on easily constructed ternary diagrams provide readily comprehended illustrations of the range of modal composition of the lithologic units making up a given coal bed. The use of bulk-specific-gravity determinations is alo recommended for identification and characterization of the distinctive lithologic units. The availability of an AIAS also enhances the capability to acquire textural information. Ranges of size of maceral and mineral grains can be quickly and precisely determined by use of an AIAS. We assume that shape characteristics of coal particles can also be readily evaluated by automated image analysis, although this evaluation has not yet been attempted in our laboratory. Definitive data on the particulate mineral content of coal constitute another important segment of petrographic description. Characterization of mineral content may be accomplished by optical identification, electron microprobe analysis, X-ray diffraction, and scanning and transmission electron microscopy. Individual mineral grains in place in polished blocks or polished this sections, or separated from the coal matrix by sink-float methods are studied by analytical techniques appropriate to the conditions of sampling. Finally, whenever possible, identification of the probable genus or plant species from which a given coal component is derived will add valuable information and meaning to the petrographic description. ?? 1982.

  13. ANALYSIS OF COAL TAR COMPOSITIONS PRODUCED FROM SUB-BITUMINOUS KALIMANTAN COAL TAR

    OpenAIRE

    Dewi Selvia Fardhyanti; Astrilia Damayanti

    2016-01-01

    Coal tar is a liquid by-product of coal pyrolysis processes. This liquid oil mixture contains various kinds of useful compounds such as benzoic aromatic compounds and phenolic compounds. These compounds are widely used as raw material for insecticides, dyes, medicines, perfumes, coloring matters, and many others. The coal tar was collected by pyrolysis process of coal obtained from PT Kaltim Prima Coal and Arutmin-Kalimantan. The experiments typically occurred at the atmo...

  14. ANALYSIS OF COAL TAR COMPOSITIONS PRODUCED FROM SUB-BITUMINOUS KALIMANTAN COAL TAR

    Directory of Open Access Journals (Sweden)

    Dewi Selvia Fardhyanti

    2016-10-01

    Full Text Available Coal tar is a liquid by-product of coal pyrolysis processes. This liquid oil mixture contains various kind of useful compounds such as benzoic aromatic compounds and phenolic compounds. These compounds are widely used as raw material for insecticides, dyes, medicines, perfumes, coloring matters, and many others. The coal tar was collected by pyrolysis process of coal obtained from PT Kaltim Prima Coal and Arutmin-Kalimantan. The experiments typically occurred at the atmospheric pressure in a laboratory furnace at temperatures ranging from 300 to 550oC with a heating rate of 10oC/min and a holding time of 1 hour at the pyrolysis temperature. The Gas Chromatography-Mass Spectroscopy (GCMS was used to analyze the coal tar components. The obtained coal tar has the viscosity of 3.12 cp, the density of 2.78 g/cm3, the calorific value of 11,048.44 cal/g, and the molecular weight of 222.67. The analysis result showed that the coal tar contained more than 78 chemical compounds such as benzene, cresol, phenol, xylene, naphtalene, etc. The total phenolic compounds contained in coal tar is 33.25% (PT KPC and 17.58% (Arutmin-Kalimantan. The total naphtalene compounds contained in coal tar is 14.15% (PT KPC and 17.13% (ArutminKalimantan.

  15. Characterizing resilient behavior of naturally occurring bituminous sands for road construction

    CSIR Research Space (South Africa)

    Anochie-Boateng, Joseph

    2010-11-01

    Full Text Available large capacity haul trucks and shovels. This paper focuses on determining in laboratory the resilient behavior of three oil sand materials with bitumen contents of 8.5, 13.3, and 14.5% by weight. The resilient modulus MR properties were obtained using a...

  16. Chemical characteristics of organic aerosol in Bab-Ezzouar (Algiers). Contribution of bituminous product manufacture.

    Science.gov (United States)

    Yassaa, N; Meklati, B Y; Cecinato, A; Marino, F

    2001-10-01

    The organic compositions of atmospheric particulate matter from Bab-Ezzouar (Algiers) have been investigated to assess the air pollution levels suspected to be caused by asphalt product and yeast manufactures. After a medium-volume air sampling, soxhlet extraction, alumina elution and HPLC separation, the extracts were analysed by high-resolution gas chromatography (HRGC) and gas chromatography coupled to mass spectrometry (GC-MS). The composition of n-alkane and polycyclic aromatic hydrocarbons (PAH) fractions reflected the petrogenic origin from the emission of asphalt materials production in addition to vascular plant wax emissions. In contrast, microbial activities seemed to play the main role for the presence of n-alkanoic acids at Bab-Ezzouar. The sole nitrated polycyclic aromatic hydrocarbons (NPAH) observed, i.e., 2-nitrofluoranthene (2NFA), was very likely to arise from gas-phase photochemical reaction of parent PAH in the atmosphere. The total aerial levels ranged from 75 to 206 ng m(-3) for n-alkanes, from 153 to 345 ng m(-3) for n-alkanoic acids and from 44 to 100 ng m(-3) for PAH and NPAH. Although the samples were collected during the hot season, the levels of these pollutants seemed to be important and of environmental concern, especially for PAH species.

  17. Acid mine drainage abatement resulting from pressure grouting of buried bituminous mine spoils

    International Nuclear Information System (INIS)

    Scheetz, B.; Silsbee, M.; Schueck, J.

    1998-01-01

    A 37 acre surface coal mine located in Clinton County, PA, USA, was mined and reclaimed between 1974 and 1977. Buried pyrite-rich pit floor cleanings and tipple refuse were found to be producing severe acid mine drainage. The pyritic material is located in discrete piles or pods in the backfill. The pods and the resulting contaminant plumes were initially defined using geophysical techniques and confirmed by drilling. The approach taken was to use a cementitious grout, composed of fluidized bed combustion ash and water, which would be placed in a manner which would prevent water and oxygen from contacting the pyritic materials. Statistically significant water quality improvements have been noted as a result of the grouting. After four years of post-grouting monitoring, reductions in concentrations of most of the mine drainage parameters range from 40 to 90%. 12 refs., 1 fig., 4 tabs

  18. Solar Radiation effect on the bituminous binder; Efecto de la radiacion solar sobre el ligante bituminoso

    Energy Technology Data Exchange (ETDEWEB)

    Tadeo Rico, A.; Torres Perez, A.

    2010-07-01

    Asphalt, used as binder in road construction, becomes more brittle and harder during working life on the surface of the road pavement, conducting toward their deterioration. This is caused by the oxidation of the molecular functional groups of the asphalt molecular structure. Moreover, it is observed that ultraviolet radiation increases the oxidation process. However, the effect of solar light on the asphalt degradation has been poorly researched. The aim of this work is to study asphalt ageing caused by effect of solar radiation, by using standard test. Four commercial asphalts from different companies were selected: two with penetration number 50/70, and the other two polymer modified asphalts. From each of the asphalts forty samples were taken off and placed in four different aging conditions of temperature and radiation for a period ranging from 40 to 500 days. Ring and Ball test, and Fraass breaking Point test, were used to analyse the changes of asphalt properties after exposition to solar radiation. The results of the four analyzed asphalts showed a distinct behaviour; not only in the test temperature increase but also in the rate. Another experiment was carried out. Samples from a hot mix asphalt batch were placed under solar radiation, and were compacted by the Marshall procedure after increasing periods of time. Density and resistance to plastic flow using Marshall Apparatus were measured. Results showed an increase in the stability of samples under radiation. Both experiments show that the solar radiation is enough to cause changes in the asphalt molecular structure due to oxidation. So that, the study of the effect of the solar radiation on the asphalt properties could be a good tool to asses the performances of asphalt pavement. (Author) 26 refs.

  19. Hydrogen from the two-stage pyrolysis of bituminous coal/waste plastics mixtures

    Czech Academy of Sciences Publication Activity Database

    Kříž, Vlastimil; Bičáková, Olga

    2011-01-01

    Roč. 36, č. 15 (2011), s. 9014-9022 ISSN 0360-3199 R&D Projects: GA ČR(CZ) GA105/07/1407 Institutional research plan: CEZ:AV0Z30460519 Keywords : hydrogen * two-stage pyrolysis * coal Subject RIV: CI - Industrial Chemistry, Chemical Engineering Impact factor: 4.054, year: 2011 http://www.sciencedirect.com/science/article/pii/S0360319911007622

  20. XRD and FT–IR investigations of sub-bituminous Assam coals

    Indian Academy of Sciences (India)

    TECS

    extremely difficult and therefore, research on coal structure is still a challenging task and continues to be pursued intensively. The investigation of the chemical structure of coal has led to comprehensive and well-defined results on the basis of development of spectroscopic methods. These are FTIR, UV-visible spectroscopy, ...

  1. Localized interaction between coal-included minerals and Ca-based CO{sub 2} sorbents during the high-pressure steam coal gasification (HyPr-RING) process

    Energy Technology Data Exchange (ETDEWEB)

    Kuramoto, K.; Ohtomo, K.; Suzuki, K.; Fujimoto, S.; Shibano, S.; Matsuoka, K.; Suzuki, Y.; Hatano, H.; Yamada, O.; Shi-Ying, L.; Harada, M.; Morishita, K.; Takarada, T. [National Institute of Advanced Industrial Science & Technology, Ibaraki (Japan)

    2004-12-08

    Pulverized Japanese bituminous coal (Taiheiyo coal) samples with diameter ranges of 38-75 {mu}m and 180-250 {mu}m were gasified with high-pressure steam in the presence of Ca-based CO{sub 2} sorbents. The experiments were carried out at 873 and 973 K and at holding times ranging from 0 to 120 min using a laboratory-scale fixed-bed reactor, and the solid-solid reaction between the Ca-based sorbents and the coal-included minerals during the steam gasification was investigated. Local scanning electron microscopy-energy-dispersive X-ray analysis of the solid residues obtained under different conditions showed that some constituents of the coal-included minerals, such as Si and Al, were contained in the sorbent particles. The solid-solid interaction between the Ca-based sorbents and coal-included minerals became significant at the higher temperature and at longer holding periods. This interaction will locally decrease the CO{sub 2} sorption ability of the sorbents. However, when a holding time of less than 10 min was employed, the solid-solid reaction between the minerals and the sorbents was suppressed, even at 973 K, because the rate of formation of inorganic compounds through solid-solid reaction was low. In this case, our target carbon conversion (about 50%) was attainable, owing to the devolatilization during the heating period. Our results indicate that the holding time of the feedstock in the reactor should be shortened to avoid deactivation of the Ca-based sorbents during high-pressure steam gasification.

  2. Touch BASE

    CERN Multimedia

    Antonella Del Rosso

    2015-01-01

    In a recent Nature article (see here), the BASE collaboration reported the most precise comparison of the charge-to-mass ratio of the proton to its antimatter equivalent, the antiproton. This result is just the beginning and many more challenges lie ahead.   CERN's AD Hall, where the BASE experiment is set-up. The Baryon Antibaryon Symmetry Experiment (BASE) was approved in June 2013 and was ready to take data in August 2014. During these 14 months, the BASE collaboration worked hard to set up its four cryogenic Penning traps, which are the heart of the whole experiment. As their name indicates, these magnetic devices are used to trap antiparticles – antiprotons coming from the Antiproton Decelerator – and particles of matter – negative hydrogen ions produced in the system by interaction with a degrader that slows the antiprotons down, allowing scientists to perform their measurements. “We had very little time to set up the wh...

  3. Geodynamic methods for assessing methane distribution in bituminous coal deposits and measures to intensify methane fluxes during mine gas drainage

    Directory of Open Access Journals (Sweden)

    Е. В. Гончаров

    2016-12-01

    Full Text Available This paper explores states of methane within the coal bearing stratum and shows heavy dependency of the intrastratal gas migration on the forms of porous space and petrographic properties of coal. The adsorbed methane is found to be predominant in the coal of Kuznetsk Basin. Different forms of coal diffusion and filtration are described revealing their dependency on geological and thermodynamic conditions. The paper provides justification for the primary focus on geodynamic processes when designing gas drainage systems and applicability of morphometric methods and remote sensing data for their identification. The significance of researches into the processes activating exothermic reactions resulting in methane transition to free state is explained. The paper presents the results of using seismic-acoustic stimulation techniques as one of the practical approaches to addressing this issue. Results of successful industrial testing have been compared with the results of numerical modelling of stress-strain state, which can also be managed through seismic-acoustic stimulation.

  4. Research on Reasonable Particle Size of Coal Blends for Blast Furnace Injection: Semi Coke and Bituminous Coal

    Science.gov (United States)

    Wang, Haiyang; Xu, Runsheng; Song, Tengfei; Zhang, Pengcheng

    Semi coke, a byproduct in the chemical industry, is a new fuel for blast furnace injection in China. In this study, semi coke and bitumite were milled into different size, ranged from 0.147mm to under 0.074mm. The content of volatile matter and ash, which affect the combustibility of semi coke, were measured using muffle furnace. The mixture, in which the proportion of coal in different sizes changed, was blend by semi coke and bitumite with different size. Activation energy calculation and the comprehensive combustion characteristic index of all kinds of blends was also discussed. The result obtained by Thermogravimetry -Derivative Thermogravimetry curves indicates that the smaller the size of mixture is, the lower for the characteristic temperature, and the better for its combustibility, Semi coke can be a substitute for anthracite in blast furnace injection.

  5. Waste tire and shingle scrap/bituminous paving test sections on the Munger Recreational Trail Gateway segment. interim report

    Science.gov (United States)

    1991-02-01

    The need to reduce Minnesota's dependence on land fills resulted in a unique cooperative venture by three state agencies. A partnership was forged between the Minnesota Pollution Control Agency (MPCA), the Minnesota Department of Natural Resources (D...

  6. Study on the structure and gasification characteristics of selected South African bituminous coal in fluidised bed gasification

    CSIR Research Space (South Africa)

    Oboirien, BO

    2009-10-01

    Full Text Available . The microstructural characteristics of the parent coals and their resultant chars were determined using XRD, FTIR, Raman and petrographic analysis. The microstructural changes that occurred in the organic (maceral) and the inorganic (mineral) fractions of the selected...

  7. An adsorption diffusion model for removal of para-chlorophenol by activated carbon derived from bituminous coal.

    Science.gov (United States)

    Sze, M F F; McKay, G

    2010-05-01

    Batch adsorption experiments were carried out to study the adsorptive removal and diffusion mechanism of para-chlorophenol (p-CP) onto Calgon Filtrasorb 400 (F400) activated carbon. The external mass transfer resistance is negligible in the adsorption process carried out under different conditions in batch operation. Intraparticle diffusion model plots were used to correlate the batch p-CP adsorption data; three distinct linear sections were obtained for every batch operation. The textural properties of F400 activated carbon showed that it has a large portion of supermicropores, which is comparable to the size of the p-CP molecules. Due to the stronger interactions between p-CP molecules and F400 micropores, p-CP molecules predominantly diffused and occupied active sites in micropore region by hopping mechanism, and eventually followed by a slow filling of mesopores and micropores. This hypothesis is proven by the excellent agreement of the intraparticle diffusion model plots and the textural properties of F400 activated carbon. Copyright 2009 Elsevier Ltd. All rights reserved.

  8. Particle size distribution of fly ash from co-incineration of bituminous coal with municipal solid waste

    OpenAIRE

    Cieślik Ewelina; Konieczny Tomasz; Bobik Bartłomiej

    2018-01-01

    One of the source of air pollutants is emission from local coal-fired boiler-houses and domestic heating boilers. The consequence of incineration of municipal waste is the introduction of additional pollutants into the atmosphere, including fly ash. The aim of this work was to evaluate the particle size distribution of fly ash emitted by coal combustion and co-incineration of coal with municipal waste in a domestic 18 kW central heating boiler equipped with an automatic fuel feeder. Mixtures ...

  9. Study on the structure and gasification characteristics of selected South African bituminous coals in fluidised bed gasification

    CSIR Research Space (South Africa)

    Oboirien, BO

    2011-04-01

    Full Text Available . The microstructural characteristics of the parent coals and their resultant chars were determined using XRD, FT-IR, Raman and petrographic analysis. The microstructural changes that occurred in the organic (maceral) and the inorganic (mineral) fractions...

  10. Down-scaling of bituminous coal mining, restructuring of steel works and heavy engineering in the Ostrava region

    Czech Academy of Sciences Publication Activity Database

    Klusáček, Petr

    2005-01-01

    Roč. 13, č. 2 (2005), s. 3-12 ISSN 1210-8812 R&D Projects: GA AV ČR(CZ) IBS3086005 Institutional research plan: CEZ:AV0Z30860518 Keywords : Ostrava region * restructuring * steemaking and heavy industry * downscaling of coal- mining Subject RIV: DE - Earth Magnetism, Geodesy, Geography

  11. Web based foundry knowledge base

    Directory of Open Access Journals (Sweden)

    A. Stawowy

    2009-01-01

    Full Text Available The main assumptions and functions of proposed Foundry Knowledge Base (FKB are presented in this paper. FKB is a framework forinformation exchange of casting products and manufacturing methods. We use CMS (Content Management System to develope andmaintain our web-based system. The CastML – XML dialect developed by authors for description of casting products and processes – isused as a tool for information interchange between ours and outside systems, while SQL is used to store and edit knowledge rules and alsoto solve the basic selection problems in the rule-based module. Besides the standard functions (companies data, news, events, forums and media kit, our website contains a number of nonstandard functions; the intelligent search module based on expert system is the main advantage of our solution. FKB is to be a social portal which content will be developed by foundry community.

  12. Intrusion resistant underground structure (IRUS) : design and operations

    International Nuclear Information System (INIS)

    Lange, B.A.

    1997-01-01

    The safety case for the IRUS low-level radioactive waste disposal facility is based on the fact that IRUS will contain three specific types of wastes only. The types of these wastes are baled wastes, bituminized incinerator ash, and bituminized reverse osmosis concentrate. IRUS will be a below-ground vault consisting of an open bottom reinforced-concrete structure (approximate dimensions 30m x 20m x 8m) with a reinforced-concrete roof. This paper covers the vault design and construction and operational features. 2 tabs

  13. Proceedings of Symposium on Energy Engineering in the 21st Century (SEE 2000). Volume Four

    Science.gov (United States)

    2000-01-13

    9.6%, respectively, based on the proximate analysis results of each paper. The heating value of the paper mixture is equivalent to that of the lignite ...Char A Bituminous 10-10 bars He + Lignite ° Bituminous 0 bar • » I bar He 600 700 Pyrolysis Temperature 800 0(< 900 1000...Mechanics, v. 2, pp.437-440, Allied Publishers Ltd, Chennai, India (1997). ^ 10 J. Mi, R.E. Luxton and G.J. Nathan, "The mean velocity field of a

  14. Intrusion resistant underground structure (IRUS) : design and operations

    Energy Technology Data Exchange (ETDEWEB)

    Lange, B.A. [Atomic Energy of Canada Ltd., Chalk River, ON (Canada)

    1997-12-31

    The safety case for the IRUS low-level radioactive waste disposal facility is based on the fact that IRUS will contain three specific types of wastes only. The types of these wastes are baled wastes, bituminized incinerator ash, and bituminized reverse osmosis concentrate. IRUS will be a below-ground vault consisting of an open bottom reinforced-concrete structure (approximate dimensions 30m x 20m x 8m) with a reinforced-concrete roof. This paper covers the vault design and construction and operational features. 2 tabs.

  15. Routine Testing of Bitumen Binders

    Directory of Open Access Journals (Sweden)

    Holý Michal

    2017-12-01

    Full Text Available The quality of bituminous binders used in the construction and maintenance of road surfaces is currently assessed by empirical testing based on obtaining one value for specific boundary conditions, which were designed about 100 years ago. Basic empirical tests include the softening point and penetration, but the practice shows that these tests appear to be inadequate. The evaluation of changes of bitumen properties during the production and paving process of bituminous mixture is also important. The paper points out how the “traditional” tests as softening point and penetration and viscosity are sufficient to evaluate properties of bitumen binders.

  16. Routine Testing of Bitumen Binders

    Science.gov (United States)

    Holý, Michal; Remišová, Eva

    2017-12-01

    The quality of bituminous binders used in the construction and maintenance of road surfaces is currently assessed by empirical testing based on obtaining one value for specific boundary conditions, which were designed about 100 years ago. Basic empirical tests include the softening point and penetration, but the practice shows that these tests appear to be inadequate. The evaluation of changes of bitumen properties during the production and paving process of bituminous mixture is also important. The paper points out how the "traditional" tests as softening point and penetration and viscosity are sufficient to evaluate properties of bitumen binders.

  17. Fragmentation based

    Directory of Open Access Journals (Sweden)

    Shashank Srivastava

    2014-01-01

    Gaining the understanding of mobile agent architecture and the security concerns, in this paper, we proposed a security protocol which addresses security with mitigated computational cost. The protocol is a combination of self decryption, co-operation and obfuscation technique. To circumvent the risk of malicious code execution in attacking environment, we have proposed fragmentation based encryption technique. Our encryption technique suits the general mobile agent size and provides hard and thorny obfuscation increasing attacker’s challenge on the same plane providing better performance with respect to computational cost as compared to existing AES encryption.

  18. Near-Zero Emissions Oxy-Combustion Flue Gas Purification - Power Plant Performance

    Energy Technology Data Exchange (ETDEWEB)

    Andrew Seltzer; Zhen Fan

    2011-03-01

    A technical feasibility assessment was performed for retrofitting oxy-fuel technology to an existing power plant burning low sulfur PRB fuel and high sulfur bituminous fuel. The focus of this study was on the boiler/power generation island of a subcritical steam cycle power plant. The power plant performance in air and oxy-firing modes was estimated and modifications required for oxy-firing capabilities were identified. A 460 MWe (gross) reference subcritical PC power plant was modeled. The reference air-fired plant has a boiler efficiency (PRB/Bituminous) of 86.7%/89.3% and a plant net efficiency of 35.8/36.7%. Net efficiency for oxy-fuel firing including ASU/CPU duty is 25.6%/26.6% (PRB/Bituminous). The oxy-fuel flue gas recirculation flow to the boiler is 68%/72% (PRB/bituminous) of the flue gas (average O{sub 2} in feed gas is 27.4%/26.4%v (PRB/bituminous)). Maximum increase in tube wall temperature is less than 10ºF for oxy-fuel firing. For oxy-fuel firing, ammonia injected to the SCR was shut-off and the FGD is applied to remove SOx from the recycled primary gas stream and a portion of the SOx from the secondary stream for the high sulfur bituminous coal. Based on CFD simulations it was determined that at the furnace outlet compared to air-firing, SO{sub 3}/SO{sub 2} mole ratio is about the same, NOx ppmv level is about the same for PRB-firing and 2.5 times for bituminous-firing due to shutting off the OFA, and CO mole fraction is approximately double. A conceptual level cost estimate was performed for the incremental equipment and installation cost of the oxyfuel retrofit in the boiler island and steam system. The cost of the retrofit is estimated to be approximately 81 M$ for PRB low sulfur fuel and 84 M$ for bituminous high sulfur fuel.

  19. METHANE de-NOX for Utility PC Boilers

    Energy Technology Data Exchange (ETDEWEB)

    Bruce Bryan; Joseph Rabovitser; Serguei Nester; Stan Wohadlo

    2004-09-30

    Large-scale PRB testing during the current quarter was cut short due to the inability of the coal mill to meet the 85 MMBtu/h design firing rate. The project was therefore redirected toward design, installation and testing of the 85-million Btu/h preheater for bituminous coal. Based on extensive pilot-scale testing completed earlier in the project, 2-D modeling and preliminary design activities were started based on the use of staged, annular protective air films to control temperature and prevent deposition on the preheater walls. A total of 14 2-D modeling cases were completed for the modified preheater for bituminous coal. The preheater concept modeled was based on an expanding preheater chamber where the diameter of the chamber is increased in steps along its length and annular cooling/protective air is introduced at each step. A process flow diagram for the bituminous coal preheating system and a preliminary preheater design drawing were developed based on the modeling results. A project schedule to complete design, installation and testing of the 85 MMBtu/h bituminous coal preheating system before the end of December was also developed.

  20. Uruguay minerals fuels

    International Nuclear Information System (INIS)

    Goso, H.

    1967-01-01

    In this report the bases for the development of the necessary works of prospection are exposed on mineral fuels of Uruguay. We have taken the set from: coal, lutitas bituminous, uranium, petroleum and disturbs. In all the cases we have talked about to the present state of the knowledge and to the works that we considered necessary to develop in each case

  1. 77 FR 76871 - Approval and Promulgation of Implementation Plans; State of Colorado; Regional Haze State...

    Science.gov (United States)

    2012-12-31

    ... to a number of different fuels. The State determined that Units 4 and 5 are not capable of burning... average annual emission rates that Colorado used for cost calculations with 30- day rolling average... based on the primary type of coal burned there, which is sub-bituminous. EPA should establish the...

  2. Foundation: Transforming data bases into knowledge bases

    Science.gov (United States)

    Purves, R. B.; Carnes, James R.; Cutts, Dannie E.

    1987-01-01

    One approach to transforming information stored in relational data bases into knowledge based representations and back again is described. This system, called Foundation, allows knowledge bases to take advantage of vast amounts of pre-existing data. A benefit of this approach is inspection, and even population, of data bases through an intelligent knowledge-based front-end.

  3. Underwater behaviour of bitumen coated radioactive wastes: experimental validation of the Colonbo degradation model; Comportement sous eau des dechets radioactifs bitumes: validation experimentale du modele de degradation Colonbo

    Energy Technology Data Exchange (ETDEWEB)

    Gwinner, B

    2004-03-01

    In the release scenario considered for geologic repository, water is thought to be the main aggressive agent with regards to bituminized radioactive waste (composed in general of 60 weight % of bitumen, 40% of soluble/insoluble salts and a few ppm of radionuclides). Since liquid water can diffuse in pure bitumen, leaching of bituminized waste results in the dissolution of the most soluble salts and leads to the development of a more or less concentrated saline solution-filled pore structure (called permeable layer). In consequence of the generation of a porous layer in the bituminized waste, leaching of salts and radionuclides can then take place. Research performed at the Atomic Energy Commission (CEA) aims therefore at understanding the consequences of ground-water immersion on the transport properties and radionuclides leaching of bituminized waste materials. To this end, a constitutive model (called COLONBO) which describes mathematically the leaching of bituminized waste has been developed. The COLONBO model is based on the following assumptions: 1. Water and dissolved salts migrate in the permeable layer according to Fick's first law. The diffusion of water and salts are quantified by effective diffusion coefficients which are unknown. 2. The mechanical properties of the bitumen matrix are not considered during leaching (free swelling). Up to now, the COLONBO model has been used only to model experimental water uptake and salt leach curves, leading (theoretical) estimates of the effective diffusion coefficients of water and salts in the permeable layer. The aim of this work was to validate experimentally the numerical results obtained with the COLONBO model. First, the correspondence between experimental and simulated water uptake and salt leach rates obtained on various bituminized waste materials is checked, leading estimates of the effective diffusion coefficients of water and salts in the permeable layer. Second, the evolution of the thickness and of

  4. Close-coupled Catalytic Two-Stage Liquefaction (CTSL{trademark}) process bench studies. Final report, [October 1, 1988--July 31, 1993

    Energy Technology Data Exchange (ETDEWEB)

    Comolli, A.G.; Johanson, E.S.; Karolkiewicz, W.F.; Lee, L.K.; Popper, G.A.; Stalzer, R.H.; Smith, T.O.

    1993-06-01

    This is the final report of a four year and ten month contract starting on October 1, 1988 to July 31, 1993 with the US Department of Energy to study and improve Close-Coupled Catalytic Two-Stage Direct Liquefaction of coal by producing high yields of distillate with improved quality at lower capital and production costs in comparison to existing technologies. Laboratory, Bench and PDU scale studies on sub-bituminous and bituminous coals are summarized and referenced in this volume. Details are presented in the three topical reports of this contract; CTSL Process Bench Studies and PDU Scale-Up with Sub-Bituminous Coal-DE-88818-TOP-1, CTSL Process Bench Studies with Bituminous Coal-DE-88818-TOP-2, and CTSL Process Laboratory Scale Studies, Modelling and Technical Assessment-DE-88818-TOP-3. Results are summarized on experiments and studies covering several process configurations, cleaned coals, solid separation methods, additives and catalysts both dispersed and supported. Laboratory microautoclave scale experiments, economic analysis and modelling studies are also included along with the PDU-Scale-Up of the CTSL processing of sub-bituminous Black Thunder Mine Wyoming coal. During this DOE/HRI effort, high distillate yields were maintained at higher throughput rates while quality was markedly improved using on-line hydrotreating and cleaned coals. Solid separations options of filtration and delayed coking were evaluated on a Bench-Scale with filtration successfully scaled to a PDU demonstration. Directions for future direct coal liquefaction related work are outlined herein based on the results from this and previous programs.

  5. The physics data base

    International Nuclear Information System (INIS)

    Gault, F.D.

    1984-01-01

    The physics data base is introduced along with its associated data base management system. The emphasis is on data and their use and a classification of data and of data bases is developed to distinguish compilation organizations. The characteristics of these organizations are examined briefly and the long term consequences of the physics data base discussed. (orig.)

  6. Solid Base Catalysis

    CERN Document Server

    Ono, Yoshio

    2011-01-01

    The importance of solid base catalysts has come to be recognized for their environmentally benign qualities, and much significant progress has been made over the past two decades in catalytic materials and solid base-catalyzed reactions. The book is focused on the solid base. Because of the advantages over liquid bases, the use of solid base catalysts in organic synthesis is expanding. Solid bases are easier to dispose than liquid bases, separation and recovery of products, catalysts and solvents are less difficult, and they are non-corrosive. Furthermore, base-catalyzed reactions can be performed without using solvents and even in the gas phase, opening up more possibilities for discovering novel reaction systems. Using numerous examples, the present volume describes the remarkable role solid base catalysis can play, given the ever increasing worldwide importance of "green" chemistry. The reader will obtain an overall view of solid base catalysis and gain insight into the versatility of the reactions to whic...

  7. Development of nanomodifiers and research into their influence on the properties of bituminous binders Разработка наномодификаторов и исследование их влияния на свойства битумных вяжущих веществ

    Directory of Open Access Journals (Sweden)

    Inozemtsev Sergey Sergeevich

    2013-09-01

    Full Text Available Nine types of nanomodifiers designated for asphalt binder are considered in the article. Three mineral material types of are considered, including dolomite powder MP-1, diatomite and activated silica sand. As the second component cotton oil, synthetic rubber and a colloid solution of ferric (III hydroxide and silica acid are selected. The results of the study disclose the influence of nanomodifiers on needle penetration depth at 0 °C and 25 °C, as well as the softening temperature, brittleness properties and stability after aging. The penetration depth is a criterion of the ability of the bitumen to resist mechanical stress, while brittleness and / or softening are the criteria of its ability to resist temperature. The generalized effectiveness criterion of bitumen modifiers is also taken into account. The generalized effectiveness criterion of nanomodifiers was revealed based on the obtained data. One of the most effective modifiers is diatomite with a colloid solution of ferric hydroxide (III and silica acid. Dolomite powder with sol and diatomite with synthetic rubber (layer 70 nm are promising methods of modification, though they require optimization in terms of their technology and formulations.Рассмотрено несколько вариантов наномодификаторов для битумного вяжущего, синтез которых заключается в нанесении на минеральные компоненты (минеральный порошок МП-1, диатомит, активированный кварцевый песок нанометрового слоя госсиполовой смолы, каучука СКДН или двухкомпонентного золя. Приведены результаты исследования влияния разработанных наномодификаторов на свойства битумного вяжущего. На

  8. Mobile Inquiry Based Learning

    NARCIS (Netherlands)

    Specht, Marcus

    2012-01-01

    Specht, M. (2012, 8 November). Mobile Inquiry Based Learning. Presentation given at the Workshop "Mobile inquiry-based learning" at the Mobile Learning Day 2012 at the Fernuniversität Hagen, Hagen, Germany.

  9. VectorBase

    Data.gov (United States)

    U.S. Department of Health & Human Services — VectorBase is a Bioinformatics Resource Center for invertebrate vectors. It is one of four Bioinformatics Resource Centers funded by NIAID to provide web-based...

  10. The ground based plan

    International Nuclear Information System (INIS)

    1989-01-01

    The paper presents a report of ''The Ground Based Plan'' of the United Kingdom Science and Engineering Research Council. The ground based plan is a plan for research in astronomy and planetary science by ground based techniques. The contents of the report contains a description of:- the scientific objectives and technical requirements (the basis for the Plan), the present organisation and funding for the ground based programme, the Plan, the main scientific features and the further objectives of the Plan. (U.K.)

  11. AUTOMATED CONTROL SYSTEM AND MONITORING BY TECHNOLOGICAL PROCESSES BY PRODUCTION OF POLYMERIC AND BITUMINOUS TAPES ON THE BASIS OF APPLICATION OF SCADA OF SYSTEM

    Directory of Open Access Journals (Sweden)

    A. S. Kirienko

    2016-01-01

    Full Text Available Expediency of use of a control system and monitoring of technological processes of production is proved in article that will allow to lower work expenses, and also to increase productivity due to the best production process.The main objective of system, remote monitoring is that gives the chance far off and to quickly give an assessment to the current situation on production, to accept reasonable and timely administrative decisions.

  12. Laboratory and field evaluations of non-bituminous hot melt pavement marker adhesive Georgia test deck : two year evaluation (fall 2006 product submissions).

    Science.gov (United States)

    2008-10-01

    Purpose: : The purpose of the National Transportation Product Evaluation Program (NTPEP) is to provide a cost-effective method of evaluation for materials of common interest among all participating NTPEP member departments. NTPEP reports allow member...

  13. Evaluation of co-cokes from bituminous coal with vacuum resid or decant oil, and evaluation of anthracites, as precursors to graphite

    Science.gov (United States)

    Nyathi, Mhlwazi S.

    2011-12-01

    Graphite is utilized as a neutron moderator and structural component in some nuclear reactor designs. During the reactor operaction the structure of graphite is damaged by collision with fast neutrons. Graphite's resistance to this damage determines its lifetime in the reactor. On neutron irradiation, isotropic or near-isotropic graphite experiences less structural damage than anisotropic graphite. The degree of anisotropy in a graphite artifact is dependent on the structure of its precursor coke. Currently, there exist concerns over a short supply of traditional precursor coke, primarily due to a steadily increasing price of petroleum. The main goal of this study was to study the anisotropic and isotropic properties of graphitized co-cokes and anthracites as a way of investigating the possibility of synthesizing isotropic or near-isotropic graphite from co-cokes and anthracites. Demonstrating the ability to form isotropic or near-isotropic graphite would mean that co-cokes and anthracites have a potential use as filler material in the synthesis of nuclear graphite. The approach used to control the co-coke structure was to vary the reaction conditions. Co-cokes were produced by coking 4:1 blends of vacuum resid/coal and decant oil/coal at temperatures of 465 and 500 °C for reaction times of 12 and 18 hours under autogenous pressure. Co-cokes obtained were calcined at 1420 °C and graphitized at 3000 °C for 24 hours. Optical microscopy, X-ray diffraction, temperature-programmed oxidation and Raman spectroscopy were used to characterize the products. It was found that higher reaction temperature (500 °C) or shorter reaction time (12 hours) leads to an increase in co-coke structural disorder and an increase in the amount of mosaic carbon at the expense of textural components that are necessary for the formation of anisotropic structure, namely, domains and flow domains. Characterization of graphitized co-cokes showed that the quality, as expressed by the degree of graphitization and crystallite dimensions, of the final product is dependent on the nature of the precursor co-coke. The methodology for studying anthracites was to select two anthracites on basis of rank, PSOC1515 being semi-anthracite and DECS21 anthracite. The selected anthracites were graphitized, in both native and demineralized states, under the same conditions as co-cokes. Products obtained from DECS21 showed higher degrees of graphitization and larger crystallite dimensions than products obtained from PSOC1515. Demineralization of anthracites served to increase the degree of graphitization, indicating that the minerals contained in these anthracites have no graphitization-enhancing ability. A larger crystallite length for products obtained from native versions, compared to demineralized versions, was attributed to a formation and decomposition of a silicon carbide during graphitization of native versions. In order to examine the anisotropic and isotropic properties, nuclear-grade graphite samples obtained from Oak Ridge National Laboratory (ORNL) and commercial graphite purchased from Fluka were characterized under similar conditions as graphitized co-cokes and anthracites. These samples served as representatives of "two extremes", with ORNL samples being the isotropic end and commercial graphite being the anisotropic end. Through evaluating relationships between structural parameters, it was observed that graphitized co-cokes are situated, structurally, somewhere between the "two extremes", whereas graphitized anthracites are closer to the anisotropic end. Basically, co-cokes have a better potential than anthracites to transform to isotropic or near-isotropic graphite upon graphitization. By co-coking vacuum resid/coal instead of decant oil/coal or using 500 °C instead of 465 °C, a shift away from commercial graphite towards ORNL samples was attained. Graphitizing a semi-anthracite or demineralizing anthracites before graphitization also caused a shift towards ORNL samples.

  14. Efecto de la tenacidad del asfalto en la resistencia a fatiga de las mezclas asfálticas Asphalt toughness effect on bituminous mixture fatigue behavior

    OpenAIRE

    Alfredo H Noguera; Rodrigo Miró

    2011-01-01

    Uno de los parámetros más importantes para definir el comportamiento de la mezcla en servicio es la tenacidad que el asfalto proporciona al aglomerar los agregados, es decir, la energía que se disipa al fracturar la mezcla, entre mayor sea dicha energía mejor será su calidad. Y por lo tanto, deberá existir una relación si dicha cantidad de energía se disipa en un ciclo de carga (tracción) o con muchos ciclos durante el tiempo (fatiga). El objetivo de éste trabajo es establecer una relación en...

  15. BITUMINOUS MIX RESPONSE TO PLASTIC DEFORMATIONS: COMPARISON OF THE SPANISH NLT-173 AND UNE-EN 12697-22 WHEEL-TRACKING TESTS

    Directory of Open Access Journals (Sweden)

    GEMA GARCÍA-TRAVÉ

    2012-01-01

    Full Text Available La formación de roderas es uno de los mayores deterioros que se producen en los firmes flexibles, lo que ocasiona la pérdida de regularidad superficial que repercute de forma negativa en la calidad del servicio prestado a los usuarios. Existen distintos ensayos de laboratorio que permiten evaluar las deformaciones plásticas producidas en las capas del pavimento, entre ellos podemos destacar los ensayos de simulación. El objetivo de esta investigación es analizar el comportamiento de una mezcla bituminosa en caliente frente a deformaciones plásticas, mediante dos métodos de ensayo diferentes; ensayo en pista de laboratorio de acuerdo a la normativa española NLT-173 y el ensayo de rodadura UNE-EN 12697-22 (ensayo obligatorio tras la entrada en vigor del Marcado CE de mezclas bituminosas en 2008. La finalidad última de este artículo es formular una propuesta de modificación de la normativa española (PG-3 sobre los límites exigibles en éste último ensayo.

  16. The effect of aggregate type and mix design on the wet skid resistance of bituminous pavement : recommendations for Virginia's Wet Accident Reduction Program.

    Science.gov (United States)

    1995-01-01

    This report (1) identified and characterized Virginia's nonpolishing aggregates in terms of their wet skid resistance, (2) compared the standard ASTM E 274-90 skid test to the British Accelerated Polishing Machine (BAPM) and British PendulumTester (B...

  17. Fluid-dynamical and poro-elastic coupling of gas permeability of inert and sorbing gases on an Australian sub-bituminous coal

    Science.gov (United States)

    Gensterblum, Y.; Krooss, B. M.

    2013-12-01

    The interaction and the coupling of slip-flow, a fluid dynamic phenomenon, and the cleat volume compressibility which is a poroelastic phenomenon has been investigated on two samples from the Taroom coal measure, Surat Basin, Queensland Australia. Measurements were performed using inert (helium and argon) and sorbing gases (nitrogen, methane and carbon dioxide) at controlled effective stress. We observed the following regular sequence of permeability coefficients for the different gases: Helium >> argon => nitrogen > methane >> CO2 Even after slip-flow correction, different intrinsic permeability coefficients are obtained for the same sample if different gases are used in the tests. The permeability values determined with helium are largest while those measured with CO2 are lowest. Inert gases like helium and argon show higher apparent- and even slip flow-corrected permeability coefficients than sorbing gases like methane or carbon dioxide. This observation is contrary to the prediction that the slip-flow corrected permeability have to be the same for all gases. The cleat volume compressibility cf was evaluated using the 'matchstick approach' [1, 2]. The cleat volume compressibility coefficients cf are almost identical for the two samples taken from the same well. However, for one sample a strong dependence of the cf with the mean pore pressure was observed. This is attributed to a strong slip-flow effect caused by a narrow cleat system as compared to the sister sample. The cleat volume compressibility coefficient cf is almost the same for inert and sorbing gases. We conclude that the occurrence of slip-flow in coals is able to compensate the permeability reduction resulting from increasing effective stress. This should lead to a much higher productivity of coal bed methane reservoirs in the third production phase (pseudo-steady state phase; [3]). This conclusion appears to be also valid for shale gas and tight gas reservoirs, where the gas transport takes place in meso- and micropores, as well.

  18. Blackened bioclasts and bituminous impregnations in the Koněprusy Limestone (Lover Devonian), the Barrandian area, Czech Republic: Implications for basin analysis

    Czech Academy of Sciences Publication Activity Database

    Suchý, V.; Sýkorová, Ivana; Dobeš, P.; Machovič, Vladimír; Filip, Jiří; Zeman, Antonín; Stejskal, M.

    2012-01-01

    Roč. 58, č. 4 (2012), s. 759-777 ISSN 0172-9179 R&D Projects: GA ČR GA205/09/1162 Institutional support: RVO:67985891 ; RVO:68378297 ; RVO:67985831 Keywords : blackened bioclasts * bitumen * reef carbonates Subject RIV: DB - Geology ; Mineralogy Impact factor: 1.771, year: 2012

  19. Stolen Base Physics

    Science.gov (United States)

    Kagan, David

    2013-01-01

    Few plays in baseball are as consistently close and exciting as the stolen base. While there are several studies of sprinting, the art of base stealing is much more nuanced. This article describes the motion of the base-stealing runner using a very basic kinematic model. The model will be compared to some data from a Major League game. The…

  20. Value-based pricing

    OpenAIRE

    Netseva-Porcheva Tatyana

    2010-01-01

    The main aim of the paper is to present the value-based pricing. Therefore, the comparison between two approaches of pricing is made - cost-based pricing and value-based pricing. The 'Price sensitively meter' is presented. The other topic of the paper is the perceived value - meaning of the perceived value, the components of perceived value, the determination of perceived value and the increasing of perceived value. In addition, the best company strategies in matrix 'value-cost' are outlined. .

  1. Soy-based polyols

    Science.gov (United States)

    Suppes, Galen; Lozada, Zueica; Lubguban, Arnold

    2013-06-25

    The invention provides processes for preparing soy-based oligomeric polyols or substituted oligomeric polyols, as well as urethane bioelasteromers comprising the oligomeric polyols or substituted oligomeric polyols.

  2. XML-BASED REPRESENTATION

    Energy Technology Data Exchange (ETDEWEB)

    R. KELSEY

    2001-02-01

    For focused applications with limited user and use application communities, XML can be the right choice for representation. It is easy to use, maintain, and extend and enjoys wide support in commercial and research sectors. When the knowledge and information to be represented is object-based and use of that knowledge and information is a high priority, then XML-based representation should be considered. This paper discusses some of the issues involved in using XML-based representation and presents an example application that successfully uses an XML-based representation.

  3. Imagery Data Base Facility

    Data.gov (United States)

    Federal Laboratory Consortium — The Imagery Data Base Facility supports AFRL and other government organizations by providing imagery interpretation and analysis to users for data selection, imagery...

  4. Synthetic Base Fluids

    Science.gov (United States)

    Brown, M.; Fotheringham, J. D.; Hoyes, T. J.; Mortier, R. M.; Orszulik, S. T.; Randles, S. J.; Stroud, P. M.

    The chemical nature and technology of the main synthetic lubricant base fluids is described, covering polyalphaolefins, alkylated aromatics, gas-to-liquid (GTL) base fluids, polybutenes, aliphatic diesters, polyolesters, polyalkylene glycols or PAGs and phosphate esters.Other synthetic lubricant base oils such as the silicones, borate esters, perfluoroethers and polyphenylene ethers are considered to have restricted applications due to either high cost or performance limitations and are not considered here.Each of the main synthetic base fluids is described for their chemical and physical properties, manufacture and production, their chemistry, key properties, applications and their implications when used in the environment.

  5. Strengths-based Learning

    DEFF Research Database (Denmark)

    Ledertoug, Mette Marie

    Strength-based learning - Children͛s Character Strengths as Means to their Learning Potential͛ is a Ph.D.-project aiming to create a strength-based mindset in school settings and at the same time introducing strength-based interventions as specific tools to improve both learning and well......-being. The Ph.D.-project in Strength-based learning took place in a Danish school with 750 pupils age 6-16 and a similar school was functioning as a control group. The presentation will focus on both the aware-explore-apply processes and the practical implications for the schools involved, and on measurable...

  6. Monitoring Knowledge Base (MKB)

    Data.gov (United States)

    U.S. Environmental Protection Agency — The Monitoring Knowledge Base (MKB) is a compilation of emissions measurement and monitoring techniques associated with air pollution control devices, industrial...

  7. Case-based reasoning

    CERN Document Server

    Kolodner, Janet

    1993-01-01

    Case-based reasoning is one of the fastest growing areas in the field of knowledge-based systems and this book, authored by a leader in the field, is the first comprehensive text on the subject. Case-based reasoning systems are systems that store information about situations in their memory. As new problems arise, similar situations are searched out to help solve these problems. Problems are understood and inferences are made by finding the closest cases in memory, comparing and contrasting the problem with those cases, making inferences based on those comparisons, and asking questions whe

  8. Secure base stations

    NARCIS (Netherlands)

    Bosch, Peter; Brusilovsky, Alec; McLellan, Rae; Mullender, Sape J.; Polakos, Paul

    2009-01-01

    With the introduction of the third generation (3G) Universal Mobile Telecommunications System (UMTS) base station router (BSR) and fourth generation (4G) base stations, such as the 3rd Generation Partnership Project (3GPP) Long Term Evolution (LTE) Evolved Node B (eNB), it has become important to

  9. Mutually unbiased bases

    Indian Academy of Sciences (India)

    Abstract. After a brief review of the notion of a full set of mutually unbiased bases in an N- dimensional Hilbert space, we summarize the work of Wootters and Fields (W K Wootters and. B C Fields, Ann. Phys. 191, 363 (1989)) which gives an explicit construction for such bases for the case N pr, where p is a prime. Further, we ...

  10. Game-Based Teaching

    DEFF Research Database (Denmark)

    Hanghøj, Thorkild

    2013-01-01

    This chapter outlines theoretical and empirical perspectives on how Game-Based Teaching can be integrated within the context of formal schooling. Initially, this is done by describing game scenarios as models for possible actions that need to be translated into curricular knowledge practices...... approaches to game-based teaching, which may or may not correspond with the pedagogical models of particular games....

  11. Home-based care

    African Journals Online (AJOL)

    Mrs. Patience Edoho Samson-Akpan

    PLWHA. The recommendation was that home based care should be encouraged and given priority by stake holders in the management of PLWHA. KEY WORDS: home-based care, quality of life, basic nursing care, psychosocial care. INTRODUCTION. HIV/AIDS is a chronic progressive disease which threatens the quality ...

  12. Diffusion Based Photon Mapping

    DEFF Research Database (Denmark)

    Schjøth, Lars; Olsen, Ole Fogh; Sporring, Jon

    2006-01-01

    . To address this problem we introduce a novel photon mapping algorithm based on nonlinear anisotropic diffusion. Our algorithm adapts according to the structure of the photon map such that smoothing occurs along edges and structures and not across. In this way we preserve the important illumination features......, while eliminating noise. We call our method diffusion based photon mapping....

  13. Skull base tumours

    Energy Technology Data Exchange (ETDEWEB)

    Borges, Alexandra [Instituto Portugues de Oncologia Francisco Gentil, Servico de Radiologia, Rua Professor Lima Basto, 1093 Lisboa Codex (Portugal)], E-mail: borgesalexandra@clix.pt

    2008-06-15

    With the advances of cross-sectional imaging radiologists gained an increasing responsibility in the management of patients with skull base pathology. As this anatomic area is hidden to clinical exam, surgeons and radiation oncologists have to rely on imaging studies to plan the most adequate treatment. To fulfil these endeavour radiologists need to be knowledgeable about skull base anatomy, about the main treatment options available, their indications and contra-indications and needs to be aware of the wide gamut of pathologies seen in this anatomic region. This article will provide a radiologists' friendly approach to the central skull base and will review the most common central skull base tumours and tumours intrinsic to the bony skull base.

  14. Context Based Wikipedia Linking

    Science.gov (United States)

    Granitzer, Michael; Seifert, Christin; Zechner, Mario

    Automatically linking Wikipedia pages can be done either content based by exploiting word similarities or structure based by exploiting characteristics of the link graph. Our approach focuses on a content based strategy by detecting Wikipedia titles as link candidates and selecting the most relevant ones as links. The relevance calculation is based on the context, i.e. the surrounding text of a link candidate. Our goal was to evaluate the influence of the link-context on selecting relevant links and determining a links best-entry-point. Results show, that a whole Wikipedia page provides the best context for resolving link and that straight forward inverse document frequency based scoring of anchor texts achieves around 4% less Mean Average Precision on the provided data set.

  15. Evidence-based radiography

    International Nuclear Information System (INIS)

    Hafslund, Bjorg; Clare, Judith; Graverholt, Birgitte; Wammen Nortvedt, Monica

    2008-01-01

    Evidence-based practice (EBP) offers the integration of the best research evidence with clinical knowledge and expertise and patient values. EBP is a well known term in health care. This paper discusses the implementation of EBP into radiography and introduces the term evidence-based radiography. Evidence-based radiography is radiography informed and based on the combination of clinical expertise and the best available research-based evidence, patient preferences and resources available. In Norway, EBP in radiography is being debated and radiographers are discussing the challenges of implementing EBP in both academic and clinical practice. This discussion paper explains why EBP needs to be a basis for a radiography curriculum and a part of radiographers' practice. We argue that Norwegian radiographers must increase participation in research and developing practice within their specific radiographic domain

  16. Field cracking performance of airfield rigid pavements

    Directory of Open Access Journals (Sweden)

    Yusuf Mehta

    2017-08-01

    Full Text Available This paper discusses cracking in airport pavements as studied in Construction Cycle 6 of testing carried out at the National Airport Pavement Testing Facility by the Federal Aviation Administration. Pavements of three different flexural strengths as well as two different subgrades, a soft bituminous layer and a more rigid layer known as econocrete, were tested. In addition to this, cracking near two types of isolated transition joints, a reinforced edge joint and a thickened edge joint, was considered. The pavement sections were tested using a moving load simulating that of an aircraft. It has been determined that the degree of cracking was reduced as the flexural strength of the pavement was increased and that fewer cracks formed over the econocrete base than over the bituminous base. In addition, the thickened edge transition joint was more effective in preventing cracking at the edges compared to the reinforced edge joint.

  17. QuickBase

    CERN Document Server

    Conner, Nancy

    2007-01-01

    Ready to put Intuit's QuickBase to work? Our new Missing Manual shows you how to capture, modify, share, and manage data and documents with this web-based data-sharing program quickly and easily. No longer do you have to coordinate your team through a blizzard of emails or play frustrating games of "guess which document is the right one."QuickBase saves your organization time and money, letting you manage and share the information that makes your business tick: sales figures, project timelines, drafts of documents, purchase or work requests--whatever information you need to keep business flowi

  18. Equipment fragility data base

    International Nuclear Information System (INIS)

    Cover, L.E.

    1982-03-01

    Part of the effort of the Seismic Safety Margins Research Program (SSMRP) has been directed at generating a fragility data base for equipment used in control and safety systems in commercial nuclear power plants. Component fragility data exist in various forms, depending on their content, intended use, and level of reduction. Th data are stored in a relational data base on the LLNL CDC 7600 computers; this provides easy accessibility for LLNL computer users. This report describes the present structure of the data base and presents its contents through the use of tables

  19. Value-based pricing

    Directory of Open Access Journals (Sweden)

    Netseva-Porcheva Tatyana

    2010-01-01

    Full Text Available The main aim of the paper is to present the value-based pricing. Therefore, the comparison between two approaches of pricing is made - cost-based pricing and value-based pricing. The 'Price sensitively meter' is presented. The other topic of the paper is the perceived value - meaning of the perceived value, the components of perceived value, the determination of perceived value and the increasing of perceived value. In addition, the best company strategies in matrix 'value-cost' are outlined. .

  20. Design-Based Research

    DEFF Research Database (Denmark)

    Gynther, Karsten; Christensen, Ove; Petersen, Trine Brun

    2012-01-01

    I denne artikel introduceres Design Based Research for første gang på dansk i et videnskabeligt tidsskrift. Artiklen præsenterer de grundlæggende antagelser, som ligger til grund for Design Based Research-traditionen, og artiklen diskuterer de principper, som ligger til grund for gennemførelse af...... et DBR-forskningsprojekt. Med udgangspunkt i forsknings- og udviklingsprojektet ELYK: E-læring, Yderområder og Klyngedannelse, præsenteres den innovationsmodel, som projektet har udviklet med udgangspunkt i Design Based Research traditionen. ELYKs DBR innovationsmodel har vist sig effektiv i forhold...

  1. Nature-based integration

    DEFF Research Database (Denmark)

    Pitkänen, Kati; Oratuomi, Joose; Hellgren, Daniela

    Increased attention to, and careful planning of the integration of migrants into Nordic societies is ever more important. Nature based integration is a new solution to respond to this need. This report presents the results of a Nordic survey and workshop and illustrates current practices of nature...... based integration by case study descriptions from Denmark, Sweden Norway and Finland. Across Nordic countries several practical projects and initiatives have been launched to promote the benefits of nature in integration and there is also growing academic interest in the topic. Nordic countries have...... the potential of becoming real forerunners in nature based integration even at the global scale....

  2. Cheboygan Vessel Base

    Data.gov (United States)

    Federal Laboratory Consortium — Cheboygan Vessel Base (CVB), located in Cheboygan, Michigan, is a field station of the USGS Great Lakes Science Center (GLSC). CVB was established by congressional...

  3. Biomimetics: nature based innovation

    National Research Council Canada - National Science Library

    Bar-Cohen, Yoseph

    2012-01-01

    "Based on the concept that nature offers numerous sources of inspiration for inventions related to mechanisms, materials, processes, and algorithms, this book covers the topic of biomimetics and the inspired innovation...

  4. Kelomehele preemia Baseli festivalil

    Index Scriptorium Estoniae

    2000-01-01

    Baselis festivalil "VIPER - International Festival for Film Video and New Media" tunnistati parimaks CD-ROMiks Gustav Deutschi/Anna Schimeki "Odysee today", netiprojektiks itaallaste "01.ORG", äramärkimispreemia - Raivo Kelomehe "Videoweaver"

  5. Hanscom Air Force Base

    Data.gov (United States)

    Federal Laboratory Consortium — MIT Lincoln Laboratory occupies 75 acres (20 acres of which are MIT property) on the eastern perimeter of Hanscom Air Force Base, which is at the nexus of Lexington,...

  6. Network-Based Effectiveness

    National Research Council Canada - National Science Library

    Friman, Henrik

    2006-01-01

    ... (extended from Leavitt, 1965). This text identifies aspects of network-based effectiveness that can benefit from a better understanding of leadership and management development of people, procedures, technology, and organizations...

  7. Evidence based practice

    DEFF Research Database (Denmark)

    Hjørland, Birger

    2011-01-01

    Evidence-based practice (EBP) is an influential interdisciplinary movement that originated in medicine as evidence-based medicine (EBM) about 1992. EBP is of considerable interest to library and information science (LIS) because it focuses on a thorough documentation of the basis for the decision...... making that is established in research as well as an optimization of every link in documentation and search processes. EBP is based on the philosophical doctrine of empiricism and, therefore, it is subject to the criticism that has been raised against empiricism. The main criticism of EBP...... is that practitioners lose their autonomy, that the understanding of theory and of underlying mechanisms is weakened, and that the concept of evidence is too narrow in the empiricist tradition. In this article, it is suggested that we should speak of “research-based practice” rather than EBP, because this term is open...

  8. WormBase

    Data.gov (United States)

    U.S. Department of Health & Human Services — WormBase is an international consortium of biologists and computer scientists dedicated to providing the research community with accurate, current, accessible...

  9. Loyalty Based Investment

    OpenAIRE

    Pei-Hsuan Lee; Ching-Wen Wang

    2010-01-01

    This study investigates the loyalty-based investment behavior in Taiwan. The link between team associations and loyalty has been examined to understand the characteristics of loyalty-based investors. The results revealed that both behavioral loyalty and attitudinal loyalty have significant positive effects on fans' investment intentions. Moreover, both attributes and benefits are significantly and positively related to either aspect of loyalty. In specific, behavioral loyalty has a higher inf...

  10. Game-based telerehabilitation.

    Science.gov (United States)

    Lange, B; Flynn, Sheryl M; Rizzo, A A

    2009-03-01

    This article summarizes the recent accomplishments and current challenges facing game-based virtual reality (VR) telerehabilitation. Specifically this article addresses accomplishments relative to realistic practice scenarios, part to whole practice, objective measurement of performance and progress, motivation, low cost, interaction devices and game design. Furthermore, a description of the current challenges facing game based telerehabilitation including the packaging, internet capabilities and access, data management, technical support, privacy protection, seizures, distance trials, scientific scrutiny and support from insurance companies.

  11. REST based mobile applications

    Science.gov (United States)

    Rambow, Mark; Preuss, Thomas; Berdux, Jörg; Conrad, Marc

    2008-02-01

    Simplicity is the major advantage of REST based webservices. Whereas SOAP is widespread in complex, security sensitive business-to-business aplications, REST is widely used for mashups and end-user centric applicatons. In that context we give an overview of REST and compare it to SOAP. Furthermore we apply the GeoDrawing application as an example for REST based mobile applications and emphasize on pros and cons for the use of REST in mobile application scenarios.

  12. Participatory design based research

    DEFF Research Database (Denmark)

    Dau, Susanne; Falk, Lars; Jensen, Louise Bach

    This poster reveal how participatory design based research by the use of a CoED inspired creative process can be used for designing solutions to problems regarding students study activities outside campus.......This poster reveal how participatory design based research by the use of a CoED inspired creative process can be used for designing solutions to problems regarding students study activities outside campus....

  13. Knowledge Based Strategy

    OpenAIRE

    Nicolescu, Ovidiu

    2006-01-01

    The paper is focused on the essential of knowledge-based strategy taking into consideration the theoretical and practical development during the last 10 years and especially knowledge revolution. It demonstrates the specificity of the company knowledgebased strategies and their necesity. More than this it presents essential elements regarding how to elaborate and to implement a knowledge based strategy starting from well know research in the field.

  14. Evidence-Based Development

    DEFF Research Database (Denmark)

    Hertzum, Morten; Simonsen, Jesper

    2004-01-01

    Systems development is replete with projects that represent substantial resource investments but result in systems that fail to meet users’ needs. Evidence-based development is an emerging idea intended to provide means for managing customer-vendor relationships and working systematically toward...... and electronic patient records for diabetes patients, this paper reports research in progress regarding the prospects and pitfalls of evidence-based development....

  15. [Endonasal skull base endoscopy].

    Science.gov (United States)

    Simal-Julián, Juan Antonio; Miranda-Lloret, Pablo; Pancucci, Giovanni; Evangelista-Zamora, Rocío; Pérez-Borredá, Pedro; Sanromán-Álvarez, Pablo; Perez-de-Sanromán, Laila; Botella-Asunción, Carlos

    2013-01-01

    The endoscopic endonasal techniques used in skull base surgery have evolved greatly in recent years. Our study objective was to perform a qualitative systematic review of the likewise systematic reviews in published English language literature, to examine the evidence and conclusions reached in these studies comparing transcranial and endoscopic approaches in skull base surgery. We searched the references on the MEDLINE and EMBASE electronic databases selecting the systematic reviews, meta-analyses and evidence based medicine reviews on skull based pathologies published from January 2000 until January 2013. We focused on endoscopic impact and on microsurgical and endoscopic technique comparisons. Full endoscopic endonasal approaches achieved gross total removal rates of craniopharyngiomas and chordomas higher than those for transcranial approaches. In anterior skull base meningiomas, complete resections were more frequently achieved after transcranial approaches, with a trend in favour of endoscopy with respect to visual prognosis. Endoscopic endonasal approaches minimised the postoperative complications after the treatment of cerebrospinal fluid (CSF) leaks, encephaloceles, meningoceles, craniopharyngiomas and chordomas, with the exception of postoperative CSF leaks. Randomized multicenter studies are necessary to resolve the controversy over endoscopic and microsurgical approaches in skull base surgery. Copyright © 2013 Sociedad Española de Neurocirugía. Published by Elsevier España. All rights reserved.

  16. LDEF materials data bases

    Science.gov (United States)

    Funk, Joan G.; Strickland, John W.; Davis, John M.

    1993-01-01

    The Long Duration Exposure Facility (LDEF) and the accompanying experiments were composed of and contained a wide variety of materials representing the largest collection of materials flown in low Earth orbit (LEO) and retrieved for ground based analysis to date. The results and implications of the mechanical, thermal, optical, and electrical data from these materials are the foundation on which future LEO space missions will be built. The LDEF Materials Special Investigation Group (MSIG) has been charged with establishing and developing data bases to document these materials and their performance to assure not only that the data are archived for future generations but also that the data are available to the spacecraft user community in an easily accessed, user-friendly form. This paper discusses the format and content of the three data bases developed or being developed to accomplish this task. The hardware and software requirements for each of these three data bases are discussed along with current availability of the data bases. This paper also serves as a user's guide to the MAPTIS LDEF Materials Data Base.

  17. Swarm-based medicine.

    Science.gov (United States)

    Putora, Paul Martin; Oldenburg, Jan

    2013-09-19

    Occasionally, medical decisions have to be taken in the absence of evidence-based guidelines. Other sources can be drawn upon to fill in the gaps, including experience and intuition. Authorities or experts, with their knowledge and experience, may provide further input--known as "eminence-based medicine". Due to the Internet and digital media, interactions among physicians now take place at a higher rate than ever before. With the rising number of interconnected individuals and their communication capabilities, the medical community is obtaining the properties of a swarm. The way individual physicians act depends on other physicians; medical societies act based on their members. Swarm behavior might facilitate the generation and distribution of knowledge as an unconscious process. As such, "swarm-based medicine" may add a further source of information to the classical approaches of evidence- and eminence-based medicine. How to integrate swarm-based medicine into practice is left to the individual physician, but even this decision will be influenced by the swarm.

  18. Improvement of compatibility and stability on polyethylene-modified bitumen by use of an aromatic extra as compatibilizer.

    OpenAIRE

    Viñas Sánchez, María Teresa; Paez, Antonio; Sánchez Caba, Jesús

    2012-01-01

    Bitumen modification by polyethylene addition usually improves the mechanical properties of the binder and, therefore, the behavior in service of the bituminous mix: thermal susceptibility and rutting can be diminished, whilst the resistance to low temperature cracking may increase. To achieve this improvement it is necessary a good compatibility between the base bitumen and the polyethylene. Low compatibility between bitumen and polyethylene can lead to phase separation: the polymer- asph...

  19. Paper based electronics platform

    KAUST Repository

    Nassar, Joanna Mohammad

    2017-07-20

    A flexible and non-functionalized low cost paper-based electronic system platform fabricated from common paper, such as paper based sensors, and methods of producing paper based sensors, and methods of sensing using the paper based sensors are provided. A method of producing a paper based sensor can include the steps of: a) providing a conventional paper product to serve as a substrate for the sensor or as an active material for the sensor or both, the paper product not further treated or functionalized; and b) applying a sensing element to the paper substrate, the sensing element selected from the group consisting of a conductive material, the conductive material providing contacts and interconnects, sensitive material film that exhibits sensitivity to pH levels, a compressible and/or porous material disposed between a pair of opposed conductive elements, or a combination of two of more said sensing elements. The method of sensing can further include measuring, using the sensing element, a change in resistance, a change in voltage, a change in current, a change in capacitance, or a combination of any two or more thereof.

  20. Cantilever Based Mass Sensing

    DEFF Research Database (Denmark)

    Dohn, Søren

    2007-01-01

    suitable for a portable device and to investigate the possibility of enhancing the functionality and sensitivity of cantilever based mass sensors. A readout method based on the hard contact between the cantilever and a biased electrode placed in close proximity to the cantilever is proposed. The viability...... the mass and position of a particle attached to a cantilever to the resonant frequency. It is shown theoretical possible to find the mass and position of a particle by measurements of the resonant frequency of several bending modes. In the measurements the sensitivity of the cantilever based mass sensor...... is improved when operated at higher bending modes. By measuring the resonant frequency of several bending modes both the mass and position of an attached gold bead are determined....

  1. Problem Based Learning

    DEFF Research Database (Denmark)

    de Graaff, Erik; Guerra, Aida

    Problem-Based Learning (PBL) is an innovative method to organize the learning process in such a way that the students actively engage in finding answers by themselves. During the past 40 years PBL has evolved and diversified resulting in a multitude in variations in models and practices. However......, the key principles remain the same everywhere. Graaff & Kolmos (2003) identify the main PBL principles as follows: 1. Problem orientation 2. Project organization through teams or group work 3. Participant-directed 4. Experiental learning 5. Activity-based learning 6. Interdisciplinary learning and 7...... in Engineering Education. In answer to the requests for visits the Aalborg Centre for Problem Based Learning in Engineering Science and Sustainability under the auspices of UNESCO (UCPBL) a two days programme for visitors is offered two times a year. The workshop is an introduction workshop to the Aalborg PBL...

  2. Location-based Scheduling

    DEFF Research Database (Denmark)

    Andersson, Niclas; Christensen, Knud

    the predominant scheduling method since it was introduced in the late 1950s. Over the years, CPM has proven to be a very powerful technique for planning, scheduling and controlling projects, which among other things is indicated by the development of a large number of CPM-based software applications available...... on the market. However, CPM is primarily an activity based method that takes the activity as the unit of focus and there is criticism raised, specifically in the case of construction projects, on the method for deficient management of construction work and continuous flow of resources. To seek solutions...... to the identified limitations of the CPM method, an alternative planning and scheduling methodology that includes locations is tested. Location-based Scheduling (LBS) implies a shift in focus, from primarily the activities to the flow of work through the various locations of the project, i.e. the building. LBS uses...

  3. Skull Base Anatomy.

    Science.gov (United States)

    Patel, Chirag R; Fernandez-Miranda, Juan C; Wang, Wei-Hsin; Wang, Eric W

    2016-02-01

    The anatomy of the skull base is complex with multiple neurovascular structures in a small space. Understanding all of the intricate relationships begins with understanding the anatomy of the sphenoid bone. The cavernous sinus contains the carotid artery and some of its branches; cranial nerves III, IV, VI, and V1; and transmits venous blood from multiple sources. The anterior skull base extends to the frontal sinus and is important to understand for sinus surgery and sinonasal malignancies. The clivus protects the brainstem and posterior cranial fossa. A thorough appreciation of the anatomy of these various areas allows for endoscopic endonasal approaches to the skull base. Copyright © 2016 Elsevier Inc. All rights reserved.

  4. Mutually unbiased unitary bases

    Science.gov (United States)

    Shaari, Jesni Shamsul; Nasir, Rinie N. M.; Mancini, Stefano

    2016-11-01

    We consider the notion of unitary transformations forming bases for subspaces of M (d ,C ) such that the square of the Hilbert-Schmidt inner product of matrices from the differing bases is a constant. Moving from the qubit case, we construct the maximal number of such bases for the four- and two-dimensional subspaces while proving the nonexistence of such a construction for the three-dimensional case. Extending this to higher dimensions, we commit to such a construct for the case of qutrits and provide evidence for the existence of such unitaries for prime dimensional quantum systems. Focusing on the qubit case, we show that the average fidelity for estimating any such transformation is equal to the case for estimating a completely unknown unitary from SU(2 ) . This is then followed by a quick application for such unitaries in a quantum cryptographic setup.

  5. On multivariate Wilson bases

    DEFF Research Database (Denmark)

    Bownik, Marcin; Jakobsen, Mads Sielemann; Lemvig, Jakob

    2017-01-01

    A Wilson system is a collection of finite linear combinations of time frequency shifts of a square integrable function. In this paper we give an account of the construction of bimodular Wilson bases in higher dimensions from Gabor frames of redundancy two.......A Wilson system is a collection of finite linear combinations of time frequency shifts of a square integrable function. In this paper we give an account of the construction of bimodular Wilson bases in higher dimensions from Gabor frames of redundancy two....

  6. Inkjet-based micromanufacturing

    CERN Document Server

    Korvink, Jan G; Shin, Dong-Youn; Brand, Oliver; Fedder, Gary K; Hierold, Christofer; Tabata, Osamu

    2012-01-01

    Inkjet-based Micromanufacturing Inkjet technology goes way beyond putting ink on paper: it enables simpler, faster and more reliable manufacturing processes in the fields of micro- and nanotechnology. Modern inkjet heads are per se precision instruments that deposit droplets of fluids on a variety of surfaces in programmable, repeating patterns, allowing, after suitable modifications and adaptations, the manufacturing of devices such as thin-film transistors, polymer-based displays and photovoltaic elements. Moreover, inkjet technology facilitates the large-scale production of flexible RFID tr

  7. Scenario-based strategizing

    DEFF Research Database (Denmark)

    Lehr, Thomas; Lorenz, Ullrich; Willert, Markus

    2017-01-01

    on behavioural strategy as a theoretical lens, we design a yardstick to study the impact of scenario-based strategizing. We then describe our approach, which includes developing scenarios and alternative strategies separately and supporting the strategy selection through an integrated assessment of the goal......-based efficacy and robustness. To facilitate the colla- borative strategizing in teams, we propose a matrix with robustness and efficacy as the two axes, which we call the Parmenides Matrix. We assess the impact of the novel approach by applying it in two cases, at a govern- mental agency (German Environmental...... Ministry) and a firm affected by disruptive change (Bosch, leading global supplier of technology and solutions)....

  8. Iron-based superconductivity

    CERN Document Server

    Johnson, Peter D; Yin, Wei-Guo

    2015-01-01

    This volume presents an in-depth review of experimental and theoretical studies on the newly discovered Fe-based superconductors.  Following the Introduction, which places iron-based superconductors in the context of other unconventional superconductors, the book is divided into three sections covering sample growth, experimental characterization, and theoretical understanding.  To understand the complex structure-property relationships of these materials, results from a wide range of experimental techniques and theoretical approaches are described that probe the electronic and magnetic proper

  9. Identity-based encryption

    CERN Document Server

    Chatterjee, Sanjit

    2011-01-01

    Identity Based Encryption (IBE) is a type of public key encryption and has been intensely researched in the past decade. Identity-Based Encryption summarizes the available research for IBE and the main ideas that would enable users to pursue further work in this area. This book will also cover a brief background on Elliptic Curves and Pairings, security against chosen Cipher text Attacks, standards and more. Advanced-level students in computer science and mathematics who specialize in cryptology, and the general community of researchers in the area of cryptology and data security will find Ide

  10. Video-based rendering

    CERN Document Server

    Magnor, Marcus A

    2005-01-01

    Driven by consumer-market applications that enjoy steadily increasing economic importance, graphics hardware and rendering algorithms are a central focus of computer graphics research. Video-based rendering is an approach that aims to overcome the current bottleneck in the time-consuming modeling process and has applications in areas such as computer games, special effects, and interactive TV. This book offers an in-depth introduction to video-based rendering, a rapidly developing new interdisciplinary topic employing techniques from computer graphics, computer vision, and telecommunication en

  11. Evidence-Based Development

    DEFF Research Database (Denmark)

    Hertzum, Morten; Simonsen, Jesper

    2004-01-01

    Systems development is replete with projects that represent substantial resource investments but result in systems that fail to meet users’ needs. Evidence-based development is an emerging idea intended to provide means for managing customer-vendor relationships and working systematically toward...... meeting customer needs. We are suggesting that the effects of the use of a system should play a prominent role in the contractual definition of IT projects and that contract fulfilment should be determined on the basis of evidence of these effects. Based on two ongoing studies of home-care management...

  12. Scenario-based strategizing

    DEFF Research Database (Denmark)

    Lehr, Thomas; Lorenz, Ullrich; Willert, Markus

    2017-01-01

    For over 40 years, scenarios have been promoted as a key technique for forming strategies in uncertain en- vironments. However, many challenges remain. In this article, we discuss a novel approach designed to increase the applicability of scenario-based strategizing in top management teams. Drawing...... on behavioural strategy as a theoretical lens, we design a yardstick to study the impact of scenario-based strategizing. We then describe our approach, which includes developing scenarios and alternative strategies separately and supporting the strategy selection through an integrated assessment of the goal...... Ministry) and a firm affected by disruptive change (Bosch, leading global supplier of technology and solutions)....

  13. Molecule-based magnets

    Indian Academy of Sciences (India)

    The design of molecule-based magnets has also been extended to the design of poly-functional molecular magnets, such as those exhibiting second-order optical nonlinearity, liquid crystallinity, or chirality simultaneously with long-range magnetic order. Solubility, low density and biocompatibility are attractive features of ...

  14. Project-Based Science

    Science.gov (United States)

    Krajcik, Joe

    2015-01-01

    Project-based science is an exciting way to teach science that aligns with the "Next Generation Science Standards" ("NGSS"). By focusing on core ideas along with practices and crosscutting concepts, classrooms become learning environments where teachers and students engage in science by designing and carrying out…

  15. based gel polymer electrolytes

    Indian Academy of Sciences (India)

    Bull. Mater. Sci., Vol. 29, No. 7, December 2006, pp. 673–678. © Indian Academy of Sciences. 673. Investigation on poly (vinylidene fluoride) based gel polymer electrolytes ... (Alamgir and Abraham 1993; Sukeshini et al 1996; Ra- jendran and Uma ... Yang et al 1996; Ramesh and Arof 2001) and such elec- trolytes exhibit ...

  16. Wrought cobalt- base superalloys

    Science.gov (United States)

    Klarstrom, D. L.

    1993-08-01

    Wrought cobalt-base superalloys are used extensively in gas turbine engines because of their excellent high-temperature creep and fatigue strengths and resistance to hot corrosion attack. In addition, the unique character of the oxide scales that form on some of the alloys provides outstanding resistance to high-temperature sliding wear. This article provides a review of the evolutionary development of wrought cobalt-base alloys in terms of alloy design and physical metallurgy. The topics include solid-so-lution strengthening, carbide precipitation characteristics, and attempts to introduce age hardening. The use of PHACOMP to enhance thermal stability characteristics and the incorporation of rare-earth ele-ments to improve oxidation resistance is also reviewed and discussed. The further development of cobalt-base superalloys has been severely hampered by past political events, which have accentuated the strategic vulnerability of cobalt as a base or as an alloying element. Consequently, alternative alloys have been developed that use little or no cobalt. One such alternative, Haynes® 230TMalloy, is discussed briefly.

  17. Refractive index based measurements

    DEFF Research Database (Denmark)

    2014-01-01

    In a method for performing a refractive index based measurement of a property of a fluid such as chemical composition or temperature by observing an apparent angular shift in an interference fringe pattern produced by back or forward scattering interferometry, ambiguities in the measurement caused...

  18. Refractive index based measurements

    DEFF Research Database (Denmark)

    2014-01-01

    In a method for performing a refractive index based measurement of a property of a fluid such as chemical composition or temperature, a chirp in the local spatial frequency of interference fringes of an interference pattern is reduced by mathematical manipulation of the recorded light intensity...

  19. Refractive index based measurements

    DEFF Research Database (Denmark)

    2014-01-01

    A refractive index based measurement of a property of a fluid is measured in an apparatus comprising a variable wavelength coherent light source (16), a sample chamber (12), a wavelength controller (24), a light sensor (20), a data recorder (26) and a computation apparatus (28), by - directing...

  20. Community-Based Care

    Science.gov (United States)

    ... Health A to Z › Community-Based Care Font size A A A Print Share Glossary Basic Facts & Information Other Resources Caregiving How To's Tools & Tips Latest Research Getting More Help Related Topics Assisted Living Home Care Nursing Homes Join our e-newsletter! ...

  1. Mutually unbiased bases

    Indian Academy of Sciences (India)

    Mutually unbiased bases play an important role in quantum cryptography [2] and in the optimal determination of the density operator of an ensemble [3,4]. A density operator ρ in N-dimensions depends on N2 1 real quantities. With the help of MUB's, any such density operator can be encoded, in an optimal way, in terms of ...

  2. Lunar Base Sitting

    Science.gov (United States)

    Staehle, Robert L.; Burke, James D.; Snyder, Gerald C.; Dowling, Richard; Spudis, Paul D.

    1993-01-01

    Speculation with regard to a permanent lunar base has been with us since Robert Goddard was working on the first liquid-fueled rockets in the 1920's. With the infusion of data from the Apollo Moon flights, a once speculative area of space exploration has become an exciting possibility. A Moon base is not only a very real possibility, but is probably a critical element in the continuation of our piloted space program. This article, originally drafted by World Space Foundation volunteers in conjuction with various academic and research groups, examines some of the strategies involved in selecting an appropriate site for such a lunar base. Site selection involves a number of complex variables, including raw materials for possible rocket propellant generation, hot an cold cycles, view of the sky (for astronomical considerations, among others), geological makeup of the region, and more. This article summarizes the key base siting considerations and suggests some alternatives. Availability of specific resources, including energy and certain minerals, is critical to success.

  3. Problem-based learning

    NARCIS (Netherlands)

    Loyens, Sofie; Kirschner, Paul A.; Paas, Fred

    2010-01-01

    Loyens, S. M. M., Kirschner, P. A., & Paas, F. (2011). Problem-based learning. In S. Graham (Editor-in-Chief), A. Bus, S. Major, & L. Swanson (Associate Editors), APA educational psychology handbook: Vol. 3. Application to learning and teaching (pp. 403-425). Washington, DC: American Psychological

  4. ISFET based enzyme sensors

    NARCIS (Netherlands)

    van der Schoot, Bart H.; Bergveld, Piet

    1987-01-01

    This paper reviews the results that have been reported on ISFET based enzyme sensors. The most important improvement that results from the application of ISFETs instead of glass membrane electrodes is in the method of fabrication. Problems with regard to the pH dependence of the response and the

  5. Internet based benchmarking

    DEFF Research Database (Denmark)

    Bogetoft, Peter; Nielsen, Kurt

    2005-01-01

    We discuss the design of interactive, internet based benchmarking using parametric (statistical) as well as nonparametric (DEA) models. The user receives benchmarks and improvement potentials. The user is also given the possibility to search different efficiency frontiers and hereby to explore...

  6. Financing Competency Based Programs.

    Science.gov (United States)

    Daniel, Annette

    Literature on the background, causes, and current prevalence of competency based programs is synthesized in this report. According to one analysis of the actual and probable costs of minimum competency testing, estimated costs for test development, test administration, bureaucratic structures, and remedial programs for students who cannot pass the…

  7. Diffusion Based Photon Mapping

    DEFF Research Database (Denmark)

    Schjøth, Lars; Fogh Olsen, Ole; Sporring, Jon

    2007-01-01

    . To address this problem we introduce a novel photon mapping algorithm based on nonlinear anisotropic diffusion. Our algorithm adapts according to the structure of the photon map such that smoothing occurs along edges and structures and not across. In this way we preserve the important illumination features...

  8. Graphene-based spaser

    Science.gov (United States)

    Berman, Oleg; Kezerashvili, Roman; Lozovik, Yurii

    2013-03-01

    We propose graphene-based surface plasmon amplification by stimulated emission of radiation (spaser) formed in the graphene nanoribbon located near a semiconductor quantum dot (QD). The population inversion of the two electron levels of the QD can be achieved by applying external electric current or laser pumping. If the frequency of the dipole plasmon resonance in a graphene nanoribbon comes in the resonance with the transition frequency for the QD, it is possible to excite plasmons and generate the coherent surface plasmon states in the graphene nanoribbon. Therefore, the oscillating dipole in the QD excites coherent surface plasmons in the graphene nanoribbon. By solving the system of equations for the number of coherent localized plasmons in a graphene-based spaser the optimal design, optimal width of graphene nanoribbon and optimal regime for the graphene-based spaser are found. The minimal size and minimal threshold pumping intensity for the graphene-based spaser are obtained. The advantage of using graphene for the spaser is discussed.

  9. Molecule-based magnets

    Indian Academy of Sciences (India)

    Administrator

    Being weakly coloured, unlike their opaque classical magnet 'cousins' listed above, possibilities of ..... which confers a memory effect on it. Stronger coercive fields are expected for Co. 2+. -based molecular ... of them a colour change, too, occurs reversibly and simultaneously with the change in magnetic properties at.

  10. Fundamental research data base

    Science.gov (United States)

    1983-01-01

    A fundamental research data base containing ground truth, image, and Badhwar profile feature data for 17 North Dakota, South Dakota, and Minnesota agricultural sites is described. Image data was provided for a minimum of four acquisition dates for each site and all four images were registered to one another.

  11. Base tree property

    Czech Academy of Sciences Publication Activity Database

    Balcar, B.; Doucha, Michal; Hrušák, M.

    2015-01-01

    Roč. 32, č. 1 (2015), s. 69-81 ISSN 0167-8094 R&D Projects: GA AV ČR IAA100190902 Institutional support: RVO:67985840 Keywords : forcing * Boolean algebras * base tree Subject RIV: BA - General Mathematics Impact factor: 0.614, year: 2015 http://link.springer.com/article/10.1007/s11083-013-9316-2

  12. Steel column base classification

    OpenAIRE

    Jaspart, J.P.; Wald, F.; Weynand, K.; Gresnigt, A.M.

    2008-01-01

    The influence of the rotational characteristics of the column bases on the structural frame response is discussed and specific design criteria for stiffness classification into semi-rigid and rigid joints are derived. The particular case of an industrial portal frame is then considered. Peer reviewed

  13. Web Based VRML Modelling

    NARCIS (Netherlands)

    Kiss, S.; Sarfraz, M.

    2004-01-01

    Presents a method to connect VRML (Virtual Reality Modeling Language) and Java components in a Web page using EAI (External Authoring Interface), which makes it possible to interactively generate and edit VRML meshes. The meshes used are based on regular grids, to provide an interaction and modeling

  14. Web Based VRML Modelling

    NARCIS (Netherlands)

    Kiss, S.; Banissi, E.; Khosrowshahi, F.; Sarfraz, M.; Ursyn, A.

    2001-01-01

    Presents a method to connect VRML (Virtual Reality Modeling Language) and Java components in a Web page using EAI (External Authoring Interface), which makes it possible to interactively generate and edit VRML meshes. The meshes used are based on regular grids, to provide an interaction and modeling

  15. based gel polymer electrolytes

    Indian Academy of Sciences (India)

    operating systems. With this situation, attempts have been made in poly (ethylene oxide) (PEO) based polymer electrolytes to reach an appreciable electrical conducti- vity at ambient temperature (Wright 1975; Martuscelli et al 1984). Generally solid polymer electrolytes have many advantages, viz. high ionic conductivity, ...

  16. Dictionary Based Image Segmentation

    DEFF Research Database (Denmark)

    Dahl, Anders Bjorholm; Dahl, Vedrana Andersen

    2015-01-01

    We propose a method for weakly supervised segmentation of natural images, which may contain both textured or non-textured regions. Our texture representation is based on a dictionary of image patches. To divide an image into separated regions with similar texture we use an implicit level sets...

  17. Molecule-based magnets

    Indian Academy of Sciences (India)

    Administrator

    SmCo5, Nd2Fe14B etc are all atom-based, and their preparation/processing require high temperature routes. Employing ... synthesis of molecular magnets in 1986, a large variety of them have been synthesized, which can be catego- rized on the basis of the ..... magnetic behaviour of Fe[Fe(CN)6⋅xH2O nanoparticles.

  18. REST based service composition

    DEFF Research Database (Denmark)

    Grönvall, Erik; Ingstrup, Mads; Pløger, Morten

    2011-01-01

    This paper presents an ongoing work developing and testing a Service Composition framework based upon the REST architecture named SECREST. A minimalistic approach have been favored instead of a creating a complete infrastructure. One focus has been on the system's interaction model. Indeed, an ai...

  19. Zero-Base Budgeting.

    Science.gov (United States)

    Harvey, L. James

    The concept of Zero-Base Budgeting (ZBB) is discussed in terms of its application, advantages, disadvantages, and implementation in an effective planning, management, and evaluation (PME) system. A ZBB system requires administrators to: review all programs and expenditures annually, set clear cut goals, and analyze all possible alternatives for…

  20. Zero-Base Budgeting.

    Science.gov (United States)

    Yagielski, John

    In outline form, this document presents basic information on the school district, the reasons the district considered zero-base budgeting (ZBB), the formation and membership of the advisory School Cost Analysis Team, the district's investigation of the ZBB concept, an overview of the ways the district used the ZBB process, the identification of…

  1. Internet Based Benchmarking

    OpenAIRE

    Bogetoft, Peter; Nielsen, Kurt

    2002-01-01

    We discuss the design of interactive, internet based benchmarking using parametric (statistical) as well as non-parametric (DEA) models. The user receives benchmarks and improvement potentials. The user is also given the possibility to search different efficiency frontiers and hereby to explore alternative improvement strategies. An implementation of both a parametric and a non parametric model are presented.

  2. Mutually unbiased bases

    Indian Academy of Sciences (India)

    ... we show how, by exploiting certain freedom in the Wootters–Fields construction, the task of explicitly writing down such bases can be simplified for the case when is an odd prime. In particular, we express the results entirely in terms of the character vectors of the cyclic group of order . We also analyse the connection ...

  3. Surfel Based Geometry Resonstruction

    DEFF Research Database (Denmark)

    Andersen, Vedrana; Aanæs, Henrik; Bærentzen, Jakob Andreas

    2010-01-01

    We propose a method for retrieving a piecewise smooth surface from noisy data. In data acquired by a scanning process sampled points are almost never on the discontinuities making reconstruction of surfaces with sharp features difficult. Our method is based on a Markov Random Field (MRF) formulat...

  4. Performance based fault diagnosis

    DEFF Research Database (Denmark)

    Niemann, Hans Henrik

    2002-01-01

    Different aspects of fault detection and fault isolation in closed-loop systems are considered. It is shown that using the standard setup known from feedback control, it is possible to formulate fault diagnosis problems based on a performance index in this general standard setup. It is also shown...

  5. Cotton-based nonwovens

    Science.gov (United States)

    This article is an abbreviated description of a new cotton-based nonwovens research program at the Southern Regional Research Center, which is one of the four regional research centers of the Agricultural Research Service, U.S. Department of Agriculture. Since cotton is a significant cash crop inte...

  6. Diffusion Based Photon Mapping

    DEFF Research Database (Denmark)

    Schjøth, Lars; Sporring, Jon; Fogh Olsen, Ole

    2008-01-01

    . To address this problem, we introduce a photon mapping algorithm based on nonlinear anisotropic diffusion. Our algorithm adapts according to the structure of the photon map such that smoothing occurs along edges and structures and not across. In this way, we preserve important illumination features, while...

  7. Spiritual-based Leadership

    DEFF Research Database (Denmark)

    Pruzan, Peter

    2015-01-01

    Although far from mainstream, the concept of spiritual-based leadership is emerging as an inclusive and yet highly personal approach to leadership that integrates a leader’s inner perspectives on identity, purpose, responsibility and success with her or his decisions and actions in the outer worl...

  8. Tritium sorption on protective coatings for concrete

    International Nuclear Information System (INIS)

    Miller, J.M.; Senohrabek, J.A.; Allsop, P.A.

    1992-11-01

    Because of the high sorption level of tritium on unprotected concrete, a program to examine the effectiveness of various concrete coatings and sealants in reducing tritium sorption was undertaken, and various exposure conditions were examined. Coatings of epoxy, polyurethane, bituminous sealant, bituminous sealant covered with polyvinylidene chloride wrap, alkyd paint, and sodium silicate were investigated with tritium (HTO) vapor concentration, humidity and contact time being varied. An exposure to HT was also carried out, and the effect of humidity on the tritium desorption rate was investigated. The relative effectiveness of the coatings was in the order of bituminous sealant + wrap > bituminous sealant > solvent-based epoxy > 100%-solids epoxy > alkyd paint > sodium silicate. The commercially available coatings for concrete resulted in tritium sorption being reduced to less than 7% of unprotected concrete. This was improved to ∼0.1% with the use of the Saran wrap (polyvinylidene chloride). The amount of tritium sorbed was proportional to tritium concentration. The total tritium sorbed decreased with an increase in humidity. A saturation effect was observed with increasing exposure time for both the coated and unprotected samples. Under the test conditions, complete saturation was not achieved within the maximum 8-hour contact time, except for the solvent-based epoxy. The desorption rate increased with a higher-humidity air purge stream. HT desorbed more rapidly than HTO, but the amount sorbed was smaller. The experimental program showed that HTO sorption by concrete can be significantly reduced with the proper choice of coating. However, tritium sorption on concrete and proposed coatings will continue to be a concern until the effects of the various conditions that affect the adsorption and desorption of tritium are firmly established for both chronic and acute tritium release conditions. Material sorption characteristics must also be considered in

  9. Asphalt mixtures with a high amount of RAP - case study

    Science.gov (United States)

    Koudelka, Tomas; Varaus, Michal

    2017-09-01

    A case study of one trial section in the Pilsen region is presented. The pavement in the section was newly constructed in 2015 using one type of an asphalt concrete mixtures with varying RAP content. The constructed surface course comprises of 0% to 50% RAP. In order to restore the aged binder properties and to avoid the embrittlement of the produced mixtures, a rubber-based modifier/rejuvenator was employed. For technological reasons during manufacturing processes, which engage a parallel drying drum, a crude oil-based rejuvenator was also added. This article contains the preliminary data from an on-going project focused on monitoring the properties of bituminous binders contained in asphalt mixtures. The actual bituminous binders were extracted straight after production, after 6 months and after 12 months. The binder characteristics are evaluated using empirical testing as well as functional tests. Low temperature properties are measured by a Bending Beam Rheometer (BBR). The preliminary results show, that the bituminous binders properties change significantly in a relatively short period of time. The progress in binder’ characteristics is contradictory to up-to date knowledge. The probability that the phenomenon of diffusion between aged binder and rejuvenator agents occurs exists. Moreover, the data might indicate that the process of rejuvenator evaporation takes place.

  10. Convolution based profile fitting

    International Nuclear Information System (INIS)

    Kern, A.; Coelho, A.A.; Cheary, R.W.

    2002-01-01

    Full text: In convolution based profile fitting, profiles are generated by convoluting functions together to form the observed profile shape. For a convolution of 'n' functions this process can be written as, Y(2θ)=F 1 (2θ)x F 2 (2θ)x... x F i (2θ)x....xF n (2θ). In powder diffractometry the functions F i (2θ) can be interpreted as the aberration functions of the diffractometer, but in general any combination of appropriate functions for F i (2θ) may be used in this context. Most direct convolution fitting methods are restricted to combinations of F i (2θ) that can be convoluted analytically (e.g. GSAS) such as Lorentzians, Gaussians, the hat (impulse) function and the exponential function. However, software such as TOPAS is now available that can accurately convolute and refine a wide variety of profile shapes numerically, including user defined profiles, without the need to convolute analytically. Some of the most important advantages of modern convolution based profile fitting are: 1) virtually any peak shape and angle dependence can normally be described using minimal profile parameters in laboratory and synchrotron X-ray data as well as in CW and TOF neutron data. This is possible because numerical convolution and numerical differentiation is used within the refinement procedure so that a wide range of functions can easily be incorporated into the convolution equation; 2) it can use physically based diffractometer models by convoluting the instrument aberration functions. This can be done for most laboratory based X-ray powder diffractometer configurations including conventional divergent beam instruments, parallel beam instruments, and diffractometers used for asymmetric diffraction. It can also accommodate various optical elements (e.g. multilayers and monochromators) and detector systems (e.g. point and position sensitive detectors) and has already been applied to neutron powder diffraction systems (e.g. ANSTO) as well as synchrotron based

  11. Spintronics-based computing

    CERN Document Server

    Prenat, Guillaume

    2015-01-01

    This book provides a comprehensive introduction to spintronics-based computing for the next generation of ultra-low power/highly reliable logic, which is widely considered a promising candidate to replace conventional, pure CMOS-based logic. It will cover aspects from device to system-level, including magnetic memory cells, device modeling, hybrid circuit structure, design methodology, CAD tools, and technological integration methods. This book is accessible to a variety of readers and little or no background in magnetism and spin electronics are required to understand its content.  The multidisciplinary team of expert authors from circuits, devices, computer architecture, CAD and system design reveal to readers the potential of spintronics nanodevices to reduce power consumption, improve reliability and enable new functionality.  .

  12. PACS Data Base Design

    Science.gov (United States)

    Zeleznik, Michael P.; Maguire, G. Q.; Baxter, B.

    1983-05-01

    A PACS database must manage three different types of data; structured data in the form of patient/exam identification information, and unstructured data in the form of text and images. Queries based on the content of text documents as well as the content of images must be suported, in addition to those based on standard, well structured keys such as name, age and sex. We model the PACS database as three logically distinct databases, each supporting one of these data types, with mapping structures relating all three. Several design issues which have a bearing, both on these models and on physical implemtations, are discussed. Because image database systems are the least understood at this time, most of the paper focusses on the them. We briefly discuss current trends in structured and text databases, without discussing commercial systems, and then present some current methods of implementing image database systems.

  13. Concrete lunar base investigation

    Science.gov (United States)

    Lin, T. D.; Senseny, Jonathan A.; Arp, Larry D.; Lindbergh, Charles

    1992-01-01

    This paper presents results of structural analyses and a preliminary design of a precast, prestressed concrete lunar base subjected to 1-atm internal pressure. The proposed infrastructure measures 120 ft in diameter and 72 ft in height, providing 33,000 sq ft of work area for scientific and industrial operations. Three loading conditions were considered in the design (1) during construction, (2) under pressurization, and (3) during an air-leak scenario. A floating foundation, capable of rigid body rotation and translation as the lunar soil beneath it yields, was developed to support the infrastructure and to ensure the airtightness of the system. Results reveal that it is feasible to use precast, prestressed concrete for construction of large lunar bases on the Moon.

  14. Technology based Education System

    DEFF Research Database (Denmark)

    Kant Hiran, Kamal; Doshi, Ruchi; Henten, Anders

    2016-01-01

    Abstract - Education plays a very important role for the development of the country. Education has multiple dimensions from schooling to higher education and research. In all these domains, there is invariably a need for technology based teaching and learning tools are highly demanded in the acad......Abstract - Education plays a very important role for the development of the country. Education has multiple dimensions from schooling to higher education and research. In all these domains, there is invariably a need for technology based teaching and learning tools are highly demanded...... and operational data that is used within a university for daily routine work. This paper presents a hybrid cloud computing model for higher education institutions to share intellectual data. Moreover, it proposes, the strategies for the implementation of the cloud computing in the academic institutions. Keywords...

  15. Animation-based Sketching

    DEFF Research Database (Denmark)

    Vistisen, Peter

    of contributions. In the produced work, I expand upon animation as a sketching approach to communicate, and explore interaction and user experience design concepts that are hard to grasp via traditional means of sketching. I propose that the sequential, temporal, material and narrative qualities of animation may...... experiments has been carried out, applying animation-based sketching in various contexts and at varying points in the design process. In the studies, I evaluate the viability of the approach, the practical integration into the design process, and map how consensus between stakeholders in design can...... be established through animation -based sketches. Thus, the scope of this project is practice-inclined, towards qualifying animation as an approach for design sketching in practice....

  16. Sparse approximation with bases

    CERN Document Server

    2015-01-01

    This book systematically presents recent fundamental results on greedy approximation with respect to bases. Motivated by numerous applications, the last decade has seen great successes in studying nonlinear sparse approximation. Recent findings have established that greedy-type algorithms are suitable methods of nonlinear approximation in both sparse approximation with respect to bases and sparse approximation with respect to redundant systems. These insights, combined with some previous fundamental results, form the basis for constructing the theory of greedy approximation. Taking into account the theoretical and practical demand for this kind of theory, the book systematically elaborates a theoretical framework for greedy approximation and its applications.  The book addresses the needs of researchers working in numerical mathematics, harmonic analysis, and functional analysis. It quickly takes the reader from classical results to the latest frontier, but is written at the level of a graduate course and do...

  17. Maintaining Relationship Based Procurement

    Directory of Open Access Journals (Sweden)

    Peter Davis

    2012-11-01

    Full Text Available Alliance and relationship projects are increasingin number and represent a large pool of work. Tobe successful relationship style contracts dependon soft-dollar factors, particularly the participants'ability to work together within an agreedframework, generally they are not based on lowbid tendering. Participants should be prepared todo business in an open environment based ontrust and mutually agreed governance. Theresearch evaluates relationship maintenance inthe implementation phase of constructionalliances - a particular derivative of relationshipstyle contracts. To determine the factors thatcontribute to relationship maintenance forty-nineexperienced Australian alliance projectmanagers were interviewed. The main findingswere; the development of relationships early inthe project form building blocks of success fromwhich relationships are maintained and projectvalue added; quality facilitation plays animportant part in relationship maintenance and ahybrid organisation created as a result of alliancedevelopment overcomes destructiveorganisational boundaries. Relationshipmaintenance is integral to alliance project controland failure to formalise it and pay attention toprocess and past outcomes will undermine analliance project's potential for success.

  18. Fusion safety data base

    International Nuclear Information System (INIS)

    Laats, E.T.; Hardy, H.A.

    1983-01-01

    The purpose of this Fusion Safety Data Base Program is to provide a repository of data for the design and development of safe commercial fusion reactors. The program is sponsored by the United States Department of Energy (DOE), Office of Fusion Energy. The function of the program is to collect, examine, permanently store, and make available the safety data to the entire US magnetic-fusion energy community. The sources of data will include domestic and foreign fusion reactor safety-related research programs. Any participant in the DOE Program may use the Data Base Program from his terminal through user friendly dialog and can view the contents in the form of text, tables, graphs, or system diagrams

  19. Conducting Polymer Based Nanobiosensors

    Directory of Open Access Journals (Sweden)

    Chul Soon Park

    2016-06-01

    Full Text Available In recent years, conducting polymer (CP nanomaterials have been used in a variety of fields, such as in energy, environmental, and biomedical applications, owing to their outstanding chemical and physical properties compared to conventional metal materials. In particular, nanobiosensors based on CP nanomaterials exhibit excellent performance sensing target molecules. The performance of CP nanobiosensors varies based on their size, shape, conductivity, and morphology, among other characteristics. Therefore, in this review, we provide an overview of the techniques commonly used to fabricate novel CP nanomaterials and their biosensor applications, including aptasensors, field-effect transistor (FET biosensors, human sense mimicking biosensors, and immunoassays. We also discuss prospects for state-of-the-art nanobiosensors using CP nanomaterials by focusing on strategies to overcome the current limitations.

  20. Knowledge based maintenance

    Energy Technology Data Exchange (ETDEWEB)

    Sturm, A. [Hamburgische Electacitaets-Werke AG Hamburg (Germany)

    1997-12-31

    The establishment of maintenance strategies is of crucial significance for the reliability of a plant and the economic efficiency of maintenance measures. Knowledge about the condition of components and plants from the technical and business management point of view therefore becomes one of the fundamental questions and the key to efficient management and maintenance. A new way to determine the maintenance strategy can be called: Knowledge Based Maintenance. A simple method for determining strategies while taking the technical condition of the components of the production process into account to the greatest possible degree which can be shown. A software with an algorithm for Knowledge Based Maintenance leads the user during complex work to the determination of maintenance strategies for this complex plant components. (orig.)

  1. Arduino based laser control

    OpenAIRE

    Bernal Muñoz, Ferran

    2015-01-01

    ARDUINO is a vey usefull platform for prototypes. In this project ARDUINO will be used for controling a Semiconductor Tuneable Laser. [ANGLÈS] Diode laser for communications control based on an Arduino board. Temperature control implementation. Software and hardware protection for the laser implementation. [CASTELLÀ] Control de un láser de comunicaciones ópticas desde el ordenador utilizando una placa Arduino. Implementación de un control de temperatura y protección software y hardware ...

  2. Design bases - Concrete structures

    International Nuclear Information System (INIS)

    Diaz-Llanos Ros, M.

    1993-01-01

    The most suitable title for Section 2 is 'Design Bases', which covers not only calculation but also the following areas: - Structural design concepts. - Project criteria. - Material specifications. These concepts are developed in more detail in the following sections. The numbering in this document is neither complete nor hierarchical since, for easier cross referencing, it corresponds to the paragraphs of Eurocode 2 Part 1 (hereinafter 'EUR-2') which are commented on. (author)

  3. Boid Based Timetable Generation

    Science.gov (United States)

    Fulmański, Piotr

    2008-09-01

    The general timetabling problem consists of scheduling a number of events into a finite number of periods so that no individual entity is required to attend two or more events simultaneously. In most cases there will also be restrictions on the amount of resources, time etc. In this document we try to investigate a new method of timetable generation based not on popular evolutionary approach but on boids concept.

  4. Copper Pyrimidine based MOFs

    Indian Academy of Sciences (India)

    Cl..Cu.. interactions but restricted ..Cu..N N..Cu interacations. Supramolecular isomers of Br and I are reported for the first time in this paper. [Cu2I(pdz)X2]. Figure S18. Self assembly of the simultaneous presence of tecton {Cu(sol)3X} and {Cu(pdz)(sol)2X} result in [Cu2I(pdz)X2]. 1. Table S3. Copper Pyrimidine based MOFs ...

  5. Air Force Smart Bases

    Science.gov (United States)

    2017-10-19

    and mobility for generating combat power while maintaining cybersecurity and accruing the benefits of technology in their lives . Figure 2...Designers ideate 100’s if not 1000’s of ways IoT and smart base technologies may improve the lives of Airmen. Figure 3: A conceptual AF mobile...innovation that unlock mission capabilities for Airmen. Both use cases are important (and can be integrated), but the functionals must continue to remind

  6. Microbead agglutination based assays

    KAUST Repository

    Kodzius, Rimantas

    2013-01-21

    We report a simple and rapid room temperature assay for point-of-care (POC) testing that is based on specific agglutination. Agglutination tests are based on aggregation of microbeads in the presence of a specific analyte thus enabling the macroscopic observation. Such tests are most often used to explore antibody-antigen reactions. Agglutination has been used for protein assays using a biotin/streptavidin system as well as a hybridization based assay. The agglutination systems are prone to selftermination of the linking analyte, prone to active site saturation and loss of agglomeration at high analyte concentrations. We investigated the molecular target/ligand interaction, explaining the common agglutination problems related to analyte self-termination, linkage of the analyte to the same bead instead of different microbeads. We classified the agglutination process into three kinds of assays: a two- component assay, a three-component assay and a stepped three- component assay. Although we compared these three kinds of assays for recognizing DNA and protein molecules, the assay can be used for virtually any molecule, including ions and metabolites. In total, the optimized assay permits detecting analytes with high sensitivity in a short time, 5 min, at room temperature. Such a system is appropriate for POC testing.

  7. As bases do petismo

    Directory of Open Access Journals (Sweden)

    David Samuels

    2004-10-01

    Full Text Available A partir dos dados do ESEB de 2002 o autor realiza um estudo das bases eleitorais do PT e de hipóteses sobre a natureza do petismo. Através de técnicas estatísticas multivariadas, são testadas relações do petismo com variáveis demográficas, socioeconômicas e variáveis relativas a questões políticas específicas. Os resultados apontam que apenas a escolaridade tem uma associação específica com o petismo, com implicações para o seu comportamento sócio-político.Based on the results of the 2002 Brazilian Electoral Study, the author analyses the electoral bases of the Worker´s Party and the factors associated with the "petismo". The relationships between the "petismo"and the socioeconomic, demographic and political variables are tested using multivariate analysis. The results indicate that the only "social category"associated with "petismo"is level of education, and it has clear implications to their social and political behavior.

  8. Knowledge-based utility

    International Nuclear Information System (INIS)

    Chwalowski, M.

    1997-01-01

    This presentation provides industry examples of successful marketing practices by companies facing deregulation and competition. The common thread through the examples is that long term survival of today's utility structure is dependent on the strategic role of knowledge. As opposed to regulated monopolies which usually own huge physical assets and have very little intelligence about their customers, unregulated enterprises tend to be knowledge-based, characterized by higher market value than book value. A knowledge-based enterprise gathers data, creates information and develops knowledge by leveraging it as a competitive weapon. It institutionalizes human knowledge as a corporate asset for use over and over again by the use of databases, computer networks, patents, billing, collection and customer services (BCCS), branded interfaces and management capabilities. Activities to become knowledge-based such as replacing inventory/fixed assets with information about material usage to reduce expenditure and achieve more efficient operations, and by focusing on integration and value-adding delivery capabilities, were reviewed

  9. Evidence-based policy

    DEFF Research Database (Denmark)

    Vohnsen, Nina Holm

    2013-01-01

    A current ambition in welfare states as diverse as Denmark, the UK, and in the USA is to base political decision making on rigorous research (Cartwright et al 2009; Mulgan 2009; Bason 2010). Sound as this might seem the ambition has nevertheless been problematized by both policy-makers and the re......A current ambition in welfare states as diverse as Denmark, the UK, and in the USA is to base political decision making on rigorous research (Cartwright et al 2009; Mulgan 2009; Bason 2010). Sound as this might seem the ambition has nevertheless been problematized by both policy......-makers and the research community (e.g. Boden & Epstein 2006; House of Commons 2006; Cartwright et al 2009; Rod 2010; Vohnsen 2011). This article intends to draw out some general pitfalls in the curious meeting of science and politics by focusing on a particular attempt to make evidence-based legislation in Denmark (for...... a full account, see Vohnsen 2011). These insights will be relevant for the anthropological researcher of legislative processes who wishes to move beyond a merely discursive approach to the study of policy and politics....

  10. Nanoplatform-based molecular imaging

    National Research Council Canada - National Science Library

    Chen, Xiaoyuan

    2011-01-01

    "Nanoplathform-Based Molecular Imaging provides rationale for using nanoparticle-based probes for molecular imaging, then discusses general strategies for this underutilized, yet promising, technology...

  11. Comparison of sequence-based and structure-based phylogenetic ...

    Indian Academy of Sciences (India)

    Prakash

    Sequence-based and structure-based phylogeny. 85. J. Biosci. 32(1), January 2007 dispersion is independent of phylogenetic tree construction algorithms. 3. ... two groups only. 3.1 Families with high correlation between sequence- based and structure-based phylogenetic trees. There are 27 families with considerably high ...

  12. Factors influencing the selection of the past and future strategies for electricity generation in the Czech Republic

    International Nuclear Information System (INIS)

    Sivek, Martin; Kavina, Pavel; Jirásek, Jakub; Malečková, Veronika

    2012-01-01

    The Czech Republic is the world's sixth largest exporter of electricity. It currently faces a fundamental decision on a new orientation of its energy strategy. Current electricity generation is based on coal (54.7%) and nuclear energy (32.7%). Nowadays the lifespan of the recoverabe reserves is less than 20 years in case of sub-bituminous coal and less than 2 years in case of uranium. Also the original lifespan of all 4 blocks of the power station Dukovany, one of county's two nuclear power plants, is approaching. These are the main reason why the Czech Republic is forced to revise its future energy strategy as well as its current optimal energy mix. This paper analyses the role of individual energy minerals in the future electricity generation portfolio of the Czech Republic. From the point of the energy security, it seems to be optimal to increase the availability of domestic sub-bituminous coal and continue with the preparation of new nuclear energy blocks and extending the lifespan of existing ones. These actions should be supported by investments to the geological survey of domestic uranium deposits. Impartial evaluation of RES potential and impact of their use on the electricity price is advisable simultaneously. - Highlights: ► Czech Republic ranks sixth in the world and fourth in Europe in electricity exports. ► Sub-bituminous coal accounts for 47.7 % of electricity generation, nuclear energy for 32.7%. ► Accessible sub-bituminous coal reserves are decreasing significantly. ► Oil and gas reserves are marginal, uranium reserves are inadequately explored. ► A new energy strategy must be found.

  13. DOM Based XSS Detecting Method Based on Phantomjs

    Science.gov (United States)

    Dong, Ri-Zhan; Ling, Jie; Liu, Yi

    Because malicious code does not appear in html source code, DOM based XSS cannot be detected by traditional methods. By analyzing the causes of DOM based XSS, this paper proposes a detection method of DOM based XSS based on phantomjs. This paper uses function hijacking to detect dangerous operation and achieves a prototype system. Comparing with existing tools shows that the system improves the detection rate and the method is effective to detect DOM based XSS.

  14. Evidence-based guidelines

    DEFF Research Database (Denmark)

    Rovira, Àlex; Wattjes, Mike P; Tintoré, Mar

    2015-01-01

    The clinical use of MRI in patients with multiple sclerosis (MS) has advanced markedly over the past few years. Technical improvements and continuously emerging data from clinical trials and observational studies have contributed to the enhanced performance of this tool for achieving a prompt...... diagnosis in patients with MS. The aim of this article is to provide guidelines for the implementation of MRI of the brain and spinal cord in the diagnosis of patients who are suspected of having MS. These guidelines are based on an extensive review of the recent literature, as well as on the personal...... of MRI in clinical practice for the diagnosis of MS....

  15. Vision-based interaction

    CERN Document Server

    Turk, Matthew

    2013-01-01

    In its early years, the field of computer vision was largely motivated by researchers seeking computational models of biological vision and solutions to practical problems in manufacturing, defense, and medicine. For the past two decades or so, there has been an increasing interest in computer vision as an input modality in the context of human-computer interaction. Such vision-based interaction can endow interactive systems with visual capabilities similar to those important to human-human interaction, in order to perceive non-verbal cues and incorporate this information in applications such

  16. Polymerization Using Phosphazene Bases

    KAUST Repository

    Zhao, Junpeng

    2015-09-01

    In the recent rise of metal-free polymerization techniques, organic phosphazene superbases have shown their remarkable strength as promoter/catalyst for the anionic polymerization of various types of monomers. Generally, the complexation of phosphazene base with the counterion (proton or lithium cation) significantly improves the nucleophilicity of the initiator/chain end resulting in highly enhanced polymerization rates, as compared with conventional metalbased initiating systems. In this chapter, the general features of phosphazenepromoted/catalyzed polymerizations and the applications in macromolecular engineering (synthesis of functionalized polymers, block copolymers, and macromolecular architectures) are discussed with challenges and perspectives being pointed out.

  17. Oil based mud discharges

    International Nuclear Information System (INIS)

    Tiesma, R.

    1996-01-01

    The intensive use of oil based muds by the offshore oil and gas industry during the 1980s has caused considerable contamination around drilling sites. A recent investigation on the Norwegian continental shelf indicates that the situation is much worse than previously thought. This material suggests that oil pollution of this kind could be damaging the North Sea's endangered fish stocks, including cod, haddock and plaice. The amount of oil discharged in the UK sector is many times higher than in the other sectors, suggesting that the problem there may be even more serious. The amount discharged in the Dutch and Norwegian sectors are comparable. (author)

  18. Agent-Based Optimization

    CERN Document Server

    Jędrzejowicz, Piotr; Kacprzyk, Janusz

    2013-01-01

    This volume presents a collection of original research works by leading specialists focusing on novel and promising approaches in which the multi-agent system paradigm is used to support, enhance or replace traditional approaches to solving difficult optimization problems. The editors have invited several well-known specialists to present their solutions, tools, and models falling under the common denominator of the agent-based optimization. The book consists of eight chapters covering examples of application of the multi-agent paradigm and respective customized tools to solve  difficult optimization problems arising in different areas such as machine learning, scheduling, transportation and, more generally, distributed and cooperative problem solving.

  19. Teradata data base computer

    Energy Technology Data Exchange (ETDEWEB)

    1984-04-01

    To meet the growing demand for information management of large databases, Teradata Corporation has introduced the DBC/1012 data base computer, an IBM plug-compatible system that can handle data volumes up to a trillion bytes. Teradata estimates the DBC/1012 to be one-third the cost of an all-software relational system on a general purpose mainframe. Cost effectiveness, as well as fault tolerance, is achieved by a parallel architecture which processes data asynchronously using multiple independent microprocessors. Another cost saving results from the resources on the host mainframe that become available once the mainframe is relieved of the burden of maintaining the database.

  20. Problem Based Game Design

    DEFF Research Database (Denmark)

    Reng, Lars; Schoenau-Fog, Henrik

    2011-01-01

    At Aalborg University’s department of Medialogy, we are utilizing the Problem Based Learning method to encourage students to solve game design problems by pushing the boundaries and designing innovative games. This paper is concerned with describing this method, how students employ it in various...... projects and how they learn to analyse, design, and develop for innovation by using it. We will present various cases to exemplify the approach and focus on how the method engages students and aspires for innovation in digital entertainment and games....

  1. LIGHTWEIGHT CONCRETE BASED GRANSHLAK

    Directory of Open Access Journals (Sweden)

    NETESA M. I.

    2016-02-01

    Full Text Available Raising of problem. Concrete advisable to obtain a low strength with local secondary resources for recycling and reduce the environmental burden on the environment. But it is important to design such concrete compositions with a reduced flow of cement. It is known that the coefficient of efficiency of use of cement in the concrete of the heavy and B10 is less than about 0.5, which is almost two times smaller than in class B15 concrete and above. Even lower coefficient of efficiency in light concrete cement low strength. Therefore, it is important to find patterns determining the composition of lightweight concrete based on local-products industry with more efficient use of cement in them. Purpose.. Based on the analysis of earlier research results, including with the use of methods of mathematical planning of experiments to determine the concrete contents, which can provide the requirements for the underlying layers of the floor, the compressive strength of which should correspond to the class B5. It is important to provide the required strength at minimum flow of the cement, which is the most expensive and energy-intensive part of concrete. Conclusion. Analysis of the test results of control samples of concrete in 28-day-old, the following laws. The required tensile strength of concrete compressive strength of 7.0 MPa can be obtained in the test range when used in formulations as a filler as the Dnieper hydroelectric power station fly ash and tailings Krivoy Rog iron ore YuGOK. To ensure providing the required characteristic strength of the concrete in the underlying layers of the floor is advisable to use a nominal composition per cubic meter of concrete: cement 160 kg granshlaka Plant named after Petrovsky, 675 kg of fly ash Dnieper HPP 390 kg, 400 kg of sand, 230 liters of water. Thus, while ensuring rational grain composition components can obtain the desired strength lightweight concrete based granshlaka plant Petrovsky, using as fillers

  2. Web Based Customized Design

    OpenAIRE

    Moi, Morten Benestad

    2013-01-01

    This thesis studies the methods needed to create a web based application to remotely customize a CAD model. This includes customizing a CAD model by using a graphical user interface to be able to remotely control the inputs to- and outputs from the model in NX, and to get the result sent back to the user. Using CAD systems such as NX requires intensive training, is often a slow process and gives a lot of room for errors. An intuitive, simple user interface will eliminate the need for CAD trai...

  3. Sustainability Base Construction Update

    Science.gov (United States)

    Mewhinney, Michael

    2012-01-01

    Construction of the new Sustainability Base Collaborative support facility, expected to become the highest performing building in the federal government continues at NASA's Ames Research Center, Moffet Field, Calif. The new building is designed to achieve a platinum rating under the leadership in Energy and Environment Design (LEED) new construction standards for environmentally sustainable construction developed by the U. S. Green Building Council, Washington, D. C. When completed by the end of 2011, the $20.6 million building will feature near zero net energy consumption, use 90 percent less potable water than conventionally build buildings of equivalent size, and will result in reduced building maintenance costs.

  4. Cellular based cancer vaccines

    DEFF Research Database (Denmark)

    Hansen, M; Met, Ö; Svane, I M

    2012-01-01

    Cancer vaccines designed to re-calibrate the existing host-tumour interaction, tipping the balance from tumor acceptance towards tumor control holds huge potential to complement traditional cancer therapies. In general, limited success has been achieved with vaccines composed of tumor...... to transiently affect in vitro migration via autocrine receptor-mediated endocytosis of CCR7. In the current review, we discuss optimal design of DC maturation focused on pre-clinical as well as clinical results from standard and polarized dendritic cell based cancer vaccines....

  5. Pitch Based Sound Classification

    DEFF Research Database (Denmark)

    Nielsen, Andreas Brinch; Hansen, Lars Kai; Kjems, U

    2006-01-01

    A sound classification model is presented that can classify signals into music, noise and speech. The model extracts the pitch of the signal using the harmonic product spectrum. Based on the pitch estimate and a pitch error measure, features are created and used in a probabilistic model with soft......-max output function. Both linear and quadratic inputs are used. The model is trained on 2 hours of sound and tested on publicly available data. A test classification error below 0.05 with 1 s classification windows is achieved. Further more it is shown that linear input performs as well as a quadratic...

  6. Accelerator-based BNCT.

    Science.gov (United States)

    Kreiner, A J; Baldo, M; Bergueiro, J R; Cartelli, D; Castell, W; Thatar Vento, V; Gomez Asoia, J; Mercuri, D; Padulo, J; Suarez Sandin, J C; Erhardt, J; Kesque, J M; Valda, A A; Debray, M E; Somacal, H R; Igarzabal, M; Minsky, D M; Herrera, M S; Capoulat, M E; Gonzalez, S J; del Grosso, M F; Gagetti, L; Suarez Anzorena, M; Gun, M; Carranza, O

    2014-06-01

    The activity in accelerator development for accelerator-based BNCT (AB-BNCT) both worldwide and in Argentina is described. Projects in Russia, UK, Italy, Japan, Israel, and Argentina to develop AB-BNCT around different types of accelerators are briefly presented. In particular, the present status and recent progress of the Argentine project will be reviewed. The topics will cover: intense ion sources, accelerator tubes, transport of intense beams, beam diagnostics, the (9)Be(d,n) reaction as a possible neutron source, Beam Shaping Assemblies (BSA), a treatment room, and treatment planning in realistic cases. © 2013 Elsevier Ltd. All rights reserved.

  7. Situation based housing

    DEFF Research Database (Denmark)

    Duelund Mortensen, Peder; Welling, Helen; Wiell Nordberg, Lene

    2007-01-01

    of approaches to these goals. This working paper reviews not only a selection of new housing types, but also dwellings from the past, which each contain an aspect of changeability. Our study is based on information from users in the selected housing schemes, gathered from questionnaires, information about...... for living. The suitable condition consists of the dwelling's ability for physical displacement, spatial changes that can suit changing life styles. The situational condition is the not defined, the unfinished and the transitory, which continuously challenges the imagination and calls for the experiment. Our...

  8. Knowledge based Entrepreneurship

    DEFF Research Database (Denmark)

    Heebøll, John

    This book is dedicated enterprising people with a technical or a scientific background who consider commercializing ideas and inventions within their field of expertise via a new business activity or a new company. It aims at distilling experiences from many successful and not so successful start......-up ventures from the Technical University of Denmark, 1988 – 2008 into practical, portable knowledge that can be used by future knowledge-based entrepreneurs to set up new companies efficiently or to stay away from it; to do what’s needed and avoid the pitfalls....

  9. Problem Based Learning Online

    DEFF Research Database (Denmark)

    Kolbæk, Ditte

    2018-01-01

    “How do two online learning designs affect student engagement in the PBL online modules?” The empirical data were collected and analyzed using a netnographic approach. The study finds that concepts such as self-directed learning and active involvement may be perceived very differently from the students......Problem- and project- based learning (PBL) was originally developed for collaboration between physically present students and teachers, but political decisions at many universities also require that collaboration, dialogues, and other PBL activities take place online. Teachers design learning...

  10. Microlaser-based displays

    Science.gov (United States)

    Bergstedt, Robert; Fink, Charles G.; Flint, Graham W.; Hargis, David E.; Peppler, Philipp W.

    1997-07-01

    Laser Power Corporation has developed a new type of projection display, based upon microlaser technology and a novel scan architecture, which provides the foundation for bright, extremely high resolution images. A review of projection technologies is presented along with the limitations of each and the difficulties they experience in trying to generate high resolution imagery. The design of the microlaser based projector is discussed along with the advantage of this technology. High power red, green, and blue microlasers have been designed and developed specifically for use in projection displays. These sources, in combination with high resolution, high contrast modulator, produce a 24 bit color gamut, capable of supporting the full range of real world colors. The new scan architecture, which reduces the modulation rate and scan speeds required, is described. This scan architecture, along with the inherent brightness of the laser provides the fundamentals necessary to produce a 5120 by 4096 resolution display. The brightness and color uniformity of the display is excellent, allowing for tiling of the displays with far fewer artifacts than those in a traditionally tiled display. Applications for the display include simulators, command and control centers, and electronic cinema.

  11. SPACE BASED INTERCEPTOR SCALING

    Energy Technology Data Exchange (ETDEWEB)

    G. CANAVAN

    2001-02-01

    Space Based Interceptor (SBI) have ranges that are adequate to address rogue ICBMs. They are not overly sensitive to 30-60 s delay times. Current technologies would support boost phase intercept with about 150 interceptors. Higher acceleration and velocity could reduce than number by about a factor of 3 at the cost of heavier and more expensive Kinetic Kill Vehicles (KKVs). 6g SBI would reduce optimal constellation costs by about 35%; 8g SBI would reduce them another 20%. Interceptor ranges fall rapidly with theater missile range. Constellations increase significantly for ranges under 3,000 km, even with advanced interceptor technology. For distributed launches, these estimates recover earlier strategic scalings, which demonstrate the improved absentee ratio for larger or multiple launch areas. Constellations increase with the number of missiles and the number of interceptors launched at each. The economic estimates above suggest that two SBI per missile with a modest midcourse underlay is appropriate. The SBI KKV technology would appear to be common for space- and surface-based boost phase systems, and could have synergisms with improved midcourse intercept and discrimination systems. While advanced technology could be helpful in reducing costs, particularly for short range theater missiles, current technology appears adequate for pressing rogue ICBM, accidental, and unauthorized launches.

  12. Location-based games

    DEFF Research Database (Denmark)

    Ejsing-Duun, Stine

    In this dissertation, it is explored which prerequisites are necessary in location-based games (LBGs) to make meaningful the meeting between players and spatiality with an emphasis on physical locations. Throughout the dissertation, it has been shown that LBGs affect players’ perception of and be......In this dissertation, it is explored which prerequisites are necessary in location-based games (LBGs) to make meaningful the meeting between players and spatiality with an emphasis on physical locations. Throughout the dissertation, it has been shown that LBGs affect players’ perception...... of and behavior in everyday spaces, as the games reside on the boundaries between the continuums of play and ordinary, authentic and fictional, and as they merge physical and digital media. These are termed the six dimensions of LBGs. LBGs let the player explore the boundaries between these dimensions...... experiences of being in the world and the creation of meaning. The theory on motivation defines what motivation consists of and how it relates to our actions. This theory has been combined with theories concerning play and play culture, digital media, (digital) games, (optimal) experiences, landscape...

  13. DVD Based Electronic Pulser

    International Nuclear Information System (INIS)

    Morris, Scott J.; Pratt, Rick M.; Hughes, Michael A.; Kouzes, Richard T.; Pitts, W K.; Robinson, Eric E.

    2005-01-01

    This paper describes the design, construction, and testing of a DVD based electronic pulser system (DVDEPS). Such a device is used to generate pulse streams for simulation of both gamma and neutron detector systems. The DVDEPS reproduces a random pulse stream of a full HPGe spectrum as well as a digital pulse stream representing the output of a neutron multiplicity detector. The exchangeable DVD media contains over an hour of data for both detector systems and can contain an arbitrary gamma spectrum and neutron pulse stream. The data is written to the DVD using a desktop computer program from either actual or simulated spectra. The targeted use of the DVDEPS is authentication or validation of monitoring equipment for non-proliferation purposes, but it is also of general use whenever a complex data stream is required. The DVD based pulser combines the storage capacity and simplicity of DVD technology with commonly available electronic components to build a relatively inexpensive yet highly capable testing instrument

  14. Metasurface-Based Polarimeters

    Directory of Open Access Journals (Sweden)

    Fei Ding

    2018-04-01

    Full Text Available The state of polarization (SOP is an inherent property of light that can be used to gain crucial information about the composition and structure of materials interrogated with light. However, the SOP is difficult to experimentally determine since it involves phase information between orthogonal polarization states, and is uncorrelated with the light intensity and frequency, which can be easily determined with photodetectors and spectrometers. Rapid progress on optical gradient metasurfaces has resulted in the development of conceptually new approaches to the SOP characterization. In this paper, we review the fundamentals of and recent developments within metasurface-based polarimeters. Starting by introducing the concepts of generalized Snell’s law and Stokes parameters, we explain the Pancharatnam–Berry phase (PB-phase which is instrumental for differentiating between orthogonal circular polarizations. Then we review the recent progress in metasurface-based polarimeters, including polarimeters, spectropolarimeters, orbital angular momentum (OAM spectropolarimeters, and photodetector integrated polarimeters. The review is ended with a short conclusion and perspective for future developments.

  15. [Competence based medical education].

    Science.gov (United States)

    Bernabó, Jorge G; Buraschi, Jorge; Olcese, Juan; Buraschi, María; Duro, Eduardo

    2007-01-01

    The strategy of curriculum planning in the majority of the Schools of Medicine has shifted, in the past years, from curriculum models based in contents to outcome oriented curricula. Coincidently the interest in defining and evaluating the clinical competences that a graduate must have has grown. In our country, and particularly in the Associated Hospitals belonging to the Unidad Regional de Enseñanza IV of the UBA School of Medicine, evidence has been gathered showing that the acquisition of clinical competences during the grade is in general insufficient. The foundations and characteristics of PREM (Programa de Requisitos Esenciales Mínimos) are described. PREM is a tool to promote the apprenticeship of abilities and necessary skills for the practice of medicine. The objective of the program is to promote the apprenticeship of a well defined list of core competences considered indispensable for a general practitioner. An outcome oriented curriculum with a clear definition of the expected knowledge, skills and attitudes of a graduate of the programme, the promotion of learning experiences centered in the practice and evaluation tools based in direct observation of the student's performance should contribute to close the gap between what the Medicine Schools traditionally teach and evaluate, and what the doctor needs to know and needs to do to perform correctly its profession.

  16. Challenge Based Innovation gala

    CERN Multimedia

    CERN. Geneva; Utriainen, Tuuli Maria; Toivonen, Harri; Nordberg, Markus

    2014-01-01

    Challenge Based Innovation gala   There’s a new experiment starting in CERN called IdeaLab where we work together with detector R&D researchers to help them to bridge their knowledge into a more human, societally oriented context. Currently we are located in B153, but will move our activities to a new facility next to the Globe in May 2014. One of our first pilot projects is a 5 month course CBI (Challenge Based Innovation) where two multidisciplinary student teams join forces with Edusafe & TALENT projects at CERN. Their goal is to discover what kind of tools for learning could be created in collaboration with the two groups. After months of user interviews and low resolution prototyping they are ready to share the results with us in the form of an afternoon gala. We warmly welcome you to join us to see the students' results and experience the prototypes they have conceived. The event is in three parts, you are welcome to visit all of them,...

  17. Model Based Definition

    Science.gov (United States)

    Rowe, Sidney E.

    2010-01-01

    In September 2007, the Engineering Directorate at the Marshall Space Flight Center (MSFC) created the Design System Focus Team (DSFT). MSFC was responsible for the in-house design and development of the Ares 1 Upper Stage and the Engineering Directorate was preparing to deploy a new electronic Configuration Management and Data Management System with the Design Data Management System (DDMS) based upon a Commercial Off The Shelf (COTS) Product Data Management (PDM) System. The DSFT was to establish standardized CAD practices and a new data life cycle for design data. Of special interest here, the design teams were to implement Model Based Definition (MBD) in support of the Upper Stage manufacturing contract. It is noted that this MBD does use partially dimensioned drawings for auxiliary information to the model. The design data lifecycle implemented several new release states to be used prior to formal release that allowed the models to move through a flow of progressive maturity. The DSFT identified some 17 Lessons Learned as outcomes of the standards development, pathfinder deployments and initial application to the Upper Stage design completion. Some of the high value examples are reviewed.

  18. Constraint-based reachability

    Directory of Open Access Journals (Sweden)

    Arnaud Gotlieb

    2013-02-01

    Full Text Available Iterative imperative programs can be considered as infinite-state systems computing over possibly unbounded domains. Studying reachability in these systems is challenging as it requires to deal with an infinite number of states with standard backward or forward exploration strategies. An approach that we call Constraint-based reachability, is proposed to address reachability problems by exploring program states using a constraint model of the whole program. The keypoint of the approach is to interpret imperative constructions such as conditionals, loops, array and memory manipulations with the fundamental notion of constraint over a computational domain. By combining constraint filtering and abstraction techniques, Constraint-based reachability is able to solve reachability problems which are usually outside the scope of backward or forward exploration strategies. This paper proposes an interpretation of classical filtering consistencies used in Constraint Programming as abstract domain computations, and shows how this approach can be used to produce a constraint solver that efficiently generates solutions for reachability problems that are unsolvable by other approaches.

  19. Skull base tumor model.

    Science.gov (United States)

    Gragnaniello, Cristian; Nader, Remi; van Doormaal, Tristan; Kamel, Mahmoud; Voormolen, Eduard H J; Lasio, Giovanni; Aboud, Emad; Regli, Luca; Tulleken, Cornelius A F; Al-Mefty, Ossama

    2010-11-01

    Resident duty-hours restrictions have now been instituted in many countries worldwide. Shortened training times and increased public scrutiny of surgical competency have led to a move away from the traditional apprenticeship model of training. The development of educational models for brain anatomy is a fascinating innovation allowing neurosurgeons to train without the need to practice on real patients and it may be a solution to achieve competency within a shortened training period. The authors describe the use of Stratathane resin ST-504 polymer (SRSP), which is inserted at different intracranial locations to closely mimic meningiomas and other pathological entities of the skull base, in a cadaveric model, for use in neurosurgical training. Silicone-injected and pressurized cadaveric heads were used for studying the SRSP model. The SRSP presents unique intrinsic metamorphic characteristics: liquid at first, it expands and foams when injected into the desired area of the brain, forming a solid tumorlike structure. The authors injected SRSP via different passages that did not influence routes used for the surgical approach for resection of the simulated lesion. For example, SRSP injection routes included endonasal transsphenoidal or transoral approaches if lesions were to be removed through standard skull base approach, or, alternatively, SRSP was injected via a cranial approach if the removal was planned to be via the transsphenoidal or transoral route. The model was set in place in 3 countries (US, Italy, and The Netherlands), and a pool of 13 physicians from 4 different institutions (all surgeons and surgeons in training) participated in evaluating it and provided feedback. All 13 evaluating physicians had overall positive impressions of the model. The overall score on 9 components evaluated--including comparison between the tumor model and real tumor cases, perioperative requirements, general impression, and applicability--was 88% (100% being the best possible

  20. Space-Based Range

    Science.gov (United States)

    2008-01-01

    Space-Based Range (SBR), previously known as Space-Based Telemetry and Range Safety (STARS), is a multicenter NASA proof-of-concept project to determine if space-based communications using NASA's Tracking and Data Relay Satellite System (TDRSS) can support the Range Safety functions of acquiring tracking data and generating flight termination signals, while also providing broadband Range User data such as voice, video, and vehicle/payload data. There was a successful test of the Range Safety system at Wallops Flight Facility (WFF) on December 20, 2005, on a two-stage Terrier-Orion spin-stabilized sounding rocket. SBR transmitted GPS tracking data and maintained links with two TDRSS satellites simultaneously during the 10-min flight. The payload section deployed a parachute, landed in the Atlantic Ocean about 90 miles downrange from the launch site, and was successfully recovered. During the Terrier-Orion tests flights, more than 99 percent of all forward commands and more than 95 percent of all return frames were successfully received and processed. The time latency necessary for a command to travel from WFF over landlines to White Sands Complex and then to the vehicle via TDRSS, be processed onboard, and then be sent back to WFF was between 1.0 s and 1.1 s. The forward-link margins for TDRS-10 (TDRS East [TDE]) were 11 dB to 12 dB plus or minus 2 dB, and for TDRS-4 (TDRS Spare [TDS]) were 9 dB to 10 dB plus or minus 1.5 dB. The return-link margins for both TDE and TDS were 6 dB to 8 dB plus or minus 3 dB. There were 11 flights on an F-15B at Dryden Flight Research Center (DFRC) between November 2006 and February 2007. The Range User system tested a 184-element TDRSS Ku-band (15 GHz) phased-array antenna with data rates of 5 Mbps and 10 Mbps. This data was a combination of black-and-white cockpit video, Range Safety tracking and transceiver data, and aircraft and antenna controller data streams. IP data formatting was used.

  1. Touching base with OPERA

    CERN Multimedia

    CERN Bulletin

    2011-01-01

    Three seminars – at CERN, at Gran Sasso and in Japan – and an article calling for the scrutiny of the scientific community: the OPERA Collaboration opened its research publicly. In addition to huge press coverage, this triggered welcome reactions from colleagues around the world, many of whom will attempt to independently interpret and reproduce the measurement. OPERA’s Spokesperson touches base with the Bulletin.   The CERN Main Auditorium was crowded as OPERA Physics co-ordinator Dario Autiero presented the results of their research (23 September 2011). According to the OPERA strategy, the results of the measurements are in the hands of the scientific community and, as for any other scientific result, several months will be needed before other groups will be able to perform an independent measurement. In the meantime, the OPERA Collaboration is dealing with an avalanche of emails from the scientific community, members of the general public, and the press. &...

  2. Bases para proyectiles dirigidos

    Directory of Open Access Journals (Sweden)

    Editorial, Equipo

    1959-03-01

    Full Text Available Aunque actualmente no se ha llegado a una línea general de métodos o sistemas que gobiernen un tipo característico de rampa y servicios auxiliares necesarios para el lanzamiento al espacio de proyectiles dirigidos a grandes alturas y distancias, las experiencias obtenidas en diferentes ensayos, utilizando distintos tipos de proyectiles y trayectorias balísticas, han sentado toda una serie de procedimientos, datos y conclusiones de gran valor balístico que, aun teniendo en cuenta la continua evolución del proyectil, sus formas, combustibles y alcances, se conocen ya, con bastante aproximación, las condiciones mínimas que ha de reunir una base dedicada a este tipo de lanzamientos.

  3. Rate based failure detection

    Science.gov (United States)

    Johnson, Brett Emery Trabun; Gamage, Thoshitha Thanushka; Bakken, David Edward

    2018-01-02

    This disclosure describes, in part, a system management component and failure detection component for use in a power grid data network to identify anomalies within the network and systematically adjust the quality of service of data published by publishers and subscribed to by subscribers within the network. In one implementation, subscribers may identify a desired data rate, a minimum acceptable data rate, desired latency, minimum acceptable latency and a priority for each subscription. The failure detection component may identify an anomaly within the network and a source of the anomaly. Based on the identified anomaly, data rates and or data paths may be adjusted in real-time to ensure that the power grid data network does not become overloaded and/or fail.

  4. Behavior based safety

    International Nuclear Information System (INIS)

    Sudhikumaran, T.V.; Mehta, S.C.; Goyal, D.K.

    2009-01-01

    Behaviour Based Safety (popularly known as BBS) is a new methodology for achieving injury free work place and total Safety Culture. BBS is successfully being implemented and is being practiced as a work methodology for achieving a loss and injury free work environment and work practice. Through BBS, it was brought out that the root causes of all Industrial accidents some how originate from the 'at risk' behaviour of some individual or group of individuals at some level. The policy of NPCIL is to excel in the field of Industrial and Fire Safety in comparison to international standards. This article indents to bring out the various parameters helping in installing BBS programme at any plant. (author)

  5. Fuel cycle based safeguards

    International Nuclear Information System (INIS)

    De Montmollin, J.M.; Higinbotham, W.A.; Gupta, D.

    1985-07-01

    In NPT safeguards the same model approach and absolute-quantity inspection goals are applied at present to all similar facilities, irrespective of the State's fuel cycle. There is a continuing interest and activity on the part of the IAEA in new NPT safeguards approaches that more directly address a State's nuclear activities as a whole. This fuel cycle based safeguards system is expected to a) provide a statement of findings for the entire State rather than only for individual facilities; b) allocate inspection efforts so as to reflect more realistically the different categories of nuclear materials in the different parts of the fuel cycle and c) provide more timely and better coordinated information on the inputs, outputs and inventories of nuclear materials in a State. (orig./RF) [de

  6. Integrated data base program

    International Nuclear Information System (INIS)

    Notz, K.J.

    1981-01-01

    The IDB Program provides direct support to the DOE Nuclear Waste Management and Fuel Cycle Programs and their lead sites and support contractors by providing and maintaining a current, integrated data base of spent fuel and radioactive waste inventories and projections. All major waste types (HLW, TRU, and LLW) and sources (government, commerical fuel cycle, and I/I) are included. A major data compilation was issued in September, 1981: Spent Fuel and Radioactive Waste Inventories and Projections as of December 31, 1980, DOE/NE-0017. This report includes chapters on Spent Fuel, HLW, TRU Waste, LLW, Remedial Action Waste, Active Uranium Mill Tailings, and Airborne Waste, plus Appendices with more detailed data in selected areas such as isotopics, radioactivity, thermal power, projections, and land usage. The LLW sections include volumes, radioactivity, thermal power, current inventories, projected inventories and characteristics, source terms, land requirements, and a breakdown in terms of government/commercial and defense/fuel cycle/I and I

  7. Space-based detectors

    DEFF Research Database (Denmark)

    Sesana, A.; Weber, W. J.; Killow, C. J.

    2014-01-01

    ) is planned for 2015. This mission and its payload “LISA Technology Package” will demonstrate key technologies for LISA. In this context, reference masses in free fall for LISA, and gravitational physics in general, was described by William Weber, laser interferometry at the pico-metre level and the optical......The parallel session C5 on Space-Based Detectors gave a broad overview over the planned space missions related to gravitational wave detection. Overviews of the revolutionary science to be expected from LISA was given by Alberto Sesana and Sasha Buchman. The launch of LISA Pathfinder (LPF...... bench of LPF was presented by Christian Killow and the performance of the LPF optical metrology system by Paul McNamara. While LPF will not yet be sensitive to gravitational waves, it may nevertheless be used to explore fundamental physics questions, which was discussed by Michele Armano. Some parts...

  8. Base isolation: Fresh insight

    Energy Technology Data Exchange (ETDEWEB)

    Shustov, V.

    1993-07-15

    The objective of the research is a further development of the engineering concept of seismic isolation. Neglecting the transient stage of seismic loading results in a widespread misjudgement: The force of resistance associated with velocity is mostly conceived as a source of damping vibrations, though it is an active force at the same time, during an earthquake type excitation. For very pliant systems such as base isolated structures with relatively low bearing stiffness and with artificially added heavy damping mechanism, the so called `damping`` force may occur even the main pushing force at an earthquake. Thus, one of the two basic pillars of the common seismic isolation philosophy, namely, the doctrine of usefulness and necessity of a strong damping mechanism, is turning out to be a self-deception, sometimes even jeopardizing the safety of structures and discrediting the very idea of seismic isolation. There is a way out: breaking with damping dependancy.

  9. Transaction based approach

    Science.gov (United States)

    Hunka, Frantisek; Matula, Jiri

    2017-07-01

    Transaction based approach is utilized in some methodologies in business process modeling. Essential parts of these transactions are human beings. The notion of agent or actor role is usually used for them. The paper on a particular example describes possibilities of Design Engineering Methodology for Organizations (DEMO) and Resource-Event-Agent (REA) methodology. Whereas the DEMO methodology can be regarded as a generic methodology having its foundation in the theory of Enterprise Ontology the REA methodology is regarded as the domain specific methodology and has its origin in accountancy systems. The results of these approaches is that the DEMO methodology captures everything that happens in the reality with a good empirical evidence whereas the REA methodology captures only changes connected with economic events. Economic events represent either change of the property rights to economic resource or consumption or production of economic resources. This results from the essence of economic events and their connection to economic resources.

  10. Mucin-Based Vaccines

    Science.gov (United States)

    Richardson, Jonathan P.; MacMillan, Derek

    Mucins are heavily O-glycosylated cell surface and secreted glycoproteins . In addition to orchestrating cell-extracellular matrix and cell-cell interactions in healthy organisms mucins are also the major carriers of altered glycosylation in carcinomas. Tumor-associated antigens displayed by cancer cells comprise oligosaccharide and glycopeptide motifs not encountered in the same locale or at the same frequency in healthy cells, and potentially confer a selective advantage to the tumor. Frequently tumor-associated antigens are under-glycosylated and prematurely sialylated, and it is these relatively simple saccharide and glycopeptide structures that have been targeted to serve as drug candidates in most cases. A major goal is to assemble glycopeptide vaccine candidates based on partial mucin sequences and displaying tumor-associated antigens that can mount a potent immunological tumor-specific response when, in reality, the tumor has already coerced the immune system into a state of co-existence.

  11. Cellular based cancer vaccines

    DEFF Research Database (Denmark)

    Hansen, M; Met, Ö; Svane, I M

    2012-01-01

    -associated antigens introduced to dendritic cells (DCs) generated in vitro. This may in part result from suboptimal maturation of DCs leading to insufficient production of IL-12, a key driver of cellular immunity. Therefore, tremendous efforts have been put into the design of maturation cocktails that are able...... of tolerogenic molecules and activation-induced dendritic cell death should be avoided. Thus, compounds such as IFN-γ may initially induce immunity but later on tolerance. Maturation with PGE(2) obviously promotes migration via expression of CCR7 but on the down side PGE(2) limits the production of IL-12...... to transiently affect in vitro migration via autocrine receptor-mediated endocytosis of CCR7. In the current review, we discuss optimal design of DC maturation focused on pre-clinical as well as clinical results from standard and polarized dendritic cell based cancer vaccines....

  12. PROBLEM-BASED LEARNING

    Directory of Open Access Journals (Sweden)

    David Esema

    2012-12-01

    Full Text Available Problem-Based Learning (PBL, adalah model pembelajaran yang awalnya dikembangkan di dunia pendidikan medis, namun kini telah digunakan secara luas di berbagai jenjang dan bidang pendidikan. Basis teortits dari PBL adalah kolaborativisme dan konstruktivisme. Kemitraan, keterbukaan dan kejujuran, rasa hormat, dan kepercayaan menjadi nilai-nilai yang mendasari dan sekaligus menjadi prasyarat bagi keberhasilan PBL Sintaks PBL meliputi: pengenalan dan pemahaman konsep dasar, eksplorasi fakta dan informasi relevan secara mandiri, bertukar pemahaman dalam kelompok/kelas, kesimpulan dan evaluasi. Beberapa riset mengenai PBL baik di luar maupun di dalam negeri yang dipaparkan dan dibandingkan dalam tulisan ini menunjukkan data tentang efektifitas PBL dalam kegiatan pembelajaran.

  13. Graphene based biosensors

    Energy Technology Data Exchange (ETDEWEB)

    Gürel, Hikmet Hakan, E-mail: hhakan.gurel@kocaeli.edu.tr [Kocaeli University, Kocaeli (Turkey); Salmankurt, Bahadır [Sakarya University, Sakarya (Turkey)

    2016-03-25

    Nanometer-sized graphene as a 2D material has unique chemical and electronic properties. Because of its unique physical, chemical, and electronic properties, its interesting shape and size make it a promising nanomaterial in many biological applications. It is expected that biomaterials incorporating graphene will be developed for the graphene-based drug delivery systems and biomedical devices. The interactions of biomolecules and graphene are long-ranged and very weak. Development of new techniques is very desirable for design of bioelectronics sensors and devices. In this work, we present first-principles calculations within density functional theory to calculate effects of charging on nucleobases on graphene. It is shown that how modify structural and electronic properties of nucleobases on graphene by applied charging.

  14. Liaison based assembly design

    Energy Technology Data Exchange (ETDEWEB)

    Ames, A.; Kholwadwala, D.; Wilson, R.H.

    1996-12-01

    Liaison Based Assembly Design extends the current information infrastructure to support design in terms of kinematic relationships between parts, or liaisons. These liaisons capture information regarding contact, degrees-of-freedom constraints and containment relationships between parts in an assembly. The project involved defining a useful collection of liaison representations, investigating their properties, and providing for maximum use of the data in downstream applications. We tested our ideas by implementing a prototype system involving extensions to Pro/Engineer and the Archimedes assembly planner. With an expanded product model, the design system is more able to capture design intent. When a product update is attempted, increased knowledge availability improves our ability to understand the effect of design changes. Manufacturing and analysis disciplines benefit from having liaison information available, so less time is wasted arguing over incomplete design specifications and our enterprise can be more completely integrated.

  15. Lunar based massdriver applications

    Science.gov (United States)

    Ehresmann, Manfred; Gabrielli, Roland Atonius; Herdrich, Georg; Laufer, René

    2017-05-01

    The results of a lunar massdriver mission and system analysis are discussed and show a strong case for a permanent lunar settlement with a site near the lunar equator. A modular massdriver concept is introduced, which uses multiple acceleration modules to be able to launch large masses into a trajectory that is able to reach Earth. An orbital mechanics analysis concludes that the launch site will be in the Oceanus Procellarum a flat, Titanium rich lunar mare area. It is further shown that the bulk of massdriver components can be manufactured by collecting lunar minerals, which are broken down into its constituting elements. The mass to orbit transfer rates of massdriver case study are significant and can vary between 1.8 kt and 3.3 megatons per year depending on the available power. Thus a lunar massdriver would act as a catalyst for any space based activities and a game changer for the scale of feasible space projects.

  16. Model Based Temporal Reasoning

    Science.gov (United States)

    Rabin, Marla J.; Spinrad, Paul R.; Fall, Thomas C.

    1988-03-01

    Systems that assess the real world must cope with evidence that is uncertain, ambiguous, and spread over time. Typically, the most important function of an assessment system is to identify when activities are occurring that are unusual or unanticipated. Model based temporal reasoning addresses both of these requirements. The differences among temporal reasoning schemes lies in the methods used to avoid computational intractability. If we had n pieces of data and we wanted to examine how they were related, the worst case would be where we had to examine every subset of these points to see if that subset satisfied the relations. This would be 2n, which is intractable. Models compress this; if several data points are all compatible with a model, then that model represents all those data points. Data points are then considered related if they lie within the same model or if they lie in models that are related. Models thus address the intractability problem. They also address the problem of determining unusual activities if the data do not agree with models that are indicated by earlier data then something out of the norm is taking place. The models can summarize what we know up to that time, so when they are not predicting correctly, either something unusual is happening or we need to revise our models. The model based reasoner developed at Advanced Decision Systems is thus both intuitive and powerful. It is currently being used on one operational system and several prototype systems. It has enough power to be used in domains spanning the spectrum from manufacturing engineering and project management to low-intensity conflict and strategic assessment.

  17. DNA-based machines.

    Science.gov (United States)

    Wang, Fuan; Willner, Bilha; Willner, Itamar

    2014-01-01

    The base sequence in nucleic acids encodes substantial structural and functional information into the biopolymer. This encoded information provides the basis for the tailoring and assembly of DNA machines. A DNA machine is defined as a molecular device that exhibits the following fundamental features. (1) It performs a fuel-driven mechanical process that mimics macroscopic machines. (2) The mechanical process requires an energy input, "fuel." (3) The mechanical operation is accompanied by an energy consumption process that leads to "waste products." (4) The cyclic operation of the DNA devices, involves the use of "fuel" and "anti-fuel" ingredients. A variety of DNA-based machines are described, including the construction of "tweezers," "walkers," "robots," "cranes," "transporters," "springs," "gears," and interlocked cyclic DNA structures acting as reconfigurable catenanes, rotaxanes, and rotors. Different "fuels", such as nucleic acid strands, pH (H⁺/OH⁻), metal ions, and light, are used to trigger the mechanical functions of the DNA devices. The operation of the devices in solution and on surfaces is described, and a variety of optical, electrical, and photoelectrochemical methods to follow the operations of the DNA machines are presented. We further address the possible applications of DNA machines and the future perspectives of molecular DNA devices. These include the application of DNA machines as functional structures for the construction of logic gates and computing, for the programmed organization of metallic nanoparticle structures and the control of plasmonic properties, and for controlling chemical transformations by DNA machines. We further discuss the future applications of DNA machines for intracellular sensing, controlling intracellular metabolic pathways, and the use of the functional nanostructures for drug delivery and medical applications.

  18. Organic Biochar Based Fertilization

    Science.gov (United States)

    Schmidt, Hans-Peter; Pandit, Bishnu Hari; Cornelissen, Gerard; Kammann, Claudia

    2017-04-01

    Biochar produced in cost-efficient flame curtain kilns (Kon-Tiki) was nutrient enriched either with cow urine or with dissolved mineral (NPK) fertilizer to produce biochar-based fertilizers containing between 60-100 kg N, 5-60 kg P2O5 and 60-100 kg K2O, respectively, per ton of biochar. In 21 field trials nutrient-enriched biochars were applied at rates of 0.5 to 2 t ha-1 into the root zone of 13 different annual and perennial crops. Treatments combining biochar, compost and organic or chemical fertilizer were evaluated; control treatments contained the same amounts of nutrients but without biochar. All nutrient-enriched biochar substrates improved yields compared to their respective no-biochar controls. Biochar enriched with dissolved NPK produced on average 20% ± 5.1% (N=4) higher yields than standard NPK fertilization without biochar. Cow urine-enriched biochar blended with compost resulted on average in 123% ± 76.7% (N=13) higher yields compared to the organic farmer practice with cow urine-blended compost and outcompeted NPK-enriched biochar (same nutrient dose) by 103% ± 12.4% (N=4) on average. 21 field trials robustly revealed that low-dosage root zone application of organic biochar-based fertilizers caused substantial yield increases in rather fertile silt loam soils compared to traditional organic fertilization and to mineral NPK- or NPK-biochar fertilization. This can likely be explained by the nutrient carrier effect of biochar causing a slow nutrient release behavior, more balanced nutrient fluxes and reduced nutrient losses especially when liquid organic nutrients are used for the biochar enrichment. The results promise new pathways for optimizing organic farming and improving on-farm nutrient cycling.

  19. Mainstreaming gesture based interfaces

    Directory of Open Access Journals (Sweden)

    David Procházka

    2013-01-01

    Full Text Available Gestures are a common way of interaction with mobile devices. They emerged especially with the iPhone production. Gestures in currently used devices are usually based on the original gestures presented by Apple in its iOS (iPhone Operating System. Therefore, there is a wide agreement on the mobile gesture design. In last years, it is possible to see experiments with gesture usage also in the other areas of consumer electronics and computers. The examples can include televisions, large projections etc. These gestures can be marked as spatial or 3D gestures. They are connected with a natural 3D environment rather than with a flat 2D screen. Nevertheless, it is hard to find a comparable design agreement within the spatial gestures. Various projects are based on completely different gesture sets. This situation is confusing for their users and slows down spatial gesture adoption.This paper is focused on the standardization of spatial gestures. The review of projects focused on spatial gesture usage is provided in the first part. The main emphasis is placed on the usability point-of-view. On the basis of our analysis, we argue that the usability is the key issue enabling the wide adoption. The mobile gesture emergence was possible easily because the iPhone gestures were natural. Therefore, it was not necessary to learn them.The design and implementation of our presentation software, which is controlled by gestures, is outlined in the second part of the paper. Furthermore, the usability testing results are provided as well. We have tested our application on a group of users not instructed in the implemented gestures design. These results were compared with the other ones, obtained with our original implementation. The evaluation can be used as the basis for implementation of similar projects.

  20. Telephone-Based Coaching.

    Science.gov (United States)

    Boccio, Mindy; Sanna, Rashel S; Adams, Sara R; Goler, Nancy C; Brown, Susan D; Neugebauer, Romain S; Ferrara, Assiamira; Wiley, Deanne M; Bellamy, David J; Schmittdiel, Julie A

    2017-03-01

    Many Americans continue to smoke, increasing their risk of disease and premature death. Both telephone-based counseling and in-person tobacco cessation classes may improve access for smokers seeking convenient support to quit. Little research has assessed whether such programs are effective in real-world clinical populations. Retrospective cohort study comparing wellness coaching participants with two groups of controls. Kaiser Permanente Northern California, a large integrated health care delivery system. Two hundred forty-one patients who participated in telephonic tobacco cessation coaching from January 1, 2011, to March 31, 2012, and two control groups: propensity-score-matched controls, and controls who participated in a tobacco cessation class during the same period. Wellness coaching participants received an average of two motivational interviewing-based coaching sessions that engaged the patient, evoked their reason to consider quitting, and helped them establish a quit plan. Self-reported quitting of tobacco and fills of tobacco cessation medications within 12 months of follow-up. Logistic regressions adjusting for age, gender, race/ethnicity, and primary language. After adjusting for confounders, tobacco quit rates were higher among coaching participants vs. matched controls (31% vs. 23%, p Coaching participants and class attendees filled tobacco-cessation prescriptions at a higher rate (47% for both) than matched controls (6%, p coaching was as effective as in-person classes and was associated with higher rates of quitting compared to no treatment. The telephonic modality may increase convenience and scalability for health care systems looking to reduce tobacco use and improve health.

  1. Loyalty-based management.

    Science.gov (United States)

    Reichheld, F F

    1993-01-01

    Despite a flurry of activities aimed at serving customers better, few companies have systematically revamped their operations with customer loyalty in mind. Instead, most have adopted improvement programs ad hoc, and paybacks haven't materialized. Building a highly loyal customer base must be integral to a company's basic business strategy. Loyalty leaders like MBNA credit cards are successful because they have designed their entire business systems around customer loyalty--a self-reinforcing system in which the company delivers superior value consistently and reinvents cash flows to find and keep high-quality customers and employees. The economic benefits of high customer loyalty are measurable. When a company consistently delivers superior value and wins customer loyalty, market share and revenues go up, and the cost of acquiring new customers goes down. The better economics mean the company can pay workers better, which sets off a whole chain of events. Increased pay boosts employee moral and commitment; as employees stay longer, their productivity goes up and training costs fall; employees' overall job satisfaction, combined with their experience, helps them serve customers better; and customers are then more inclined to stay loyal to the company. Finally, as the best customers and employees become part of the loyalty-based system, competitors are left to survive with less desirable customers and less talented employees. To compete on loyalty, a company must understand the relationships between customer retention and the other parts of the business--and be able to quantify the linkages between loyalty and profits. It involves rethinking and aligning four important aspects of the business: customers, product/service offering, employees, and measurement systems.

  2. Base Research Program

    Energy Technology Data Exchange (ETDEWEB)

    Everett Sondreal; John Hendrikson

    2009-03-31

    In June 2009, the Energy & Environmental Research Center (EERC) completed 11 years of research under the U.S. Department of Energy (DOE) Base Cooperative Agreement No. DE-FC26-98FT40320 funded through the Office of Fossil Energy (OFE) and administered at the National Energy Technology Laboratory (NETL). A wide range of diverse research activities were performed under annual program plans approved by NETL in seven major task areas: (1) resource characterization and waste management, (2) air quality assessment and control, (3) advanced power systems, (4) advanced fuel forms, (5) value-added coproducts, (6) advanced materials, and (7) strategic studies. This report summarizes results of the 67 research subtasks and an additional 50 strategic studies. Selected highlights in the executive summary illustrate the contribution of the research to the energy industry in areas not adequately addressed by the private sector alone. During the period of performance of the agreement, concerns have mounted over the impact of carbon emissions on climate change, and new programs have been initiated by DOE to ensure that fossil fuel resources along with renewable resources can continue to supply the nation's transportation fuel and electric power. The agreement has addressed DOE goals for reductions in CO{sub 2} emissions through efficiency, capture, and sequestration while expanding the supply and use of domestic energy resources for energy security. It has further contributed to goals for near-zero emissions from highly efficient coal-fired power plants; environmental control capabilities for SO{sub 2}, NO{sub x}, fine respirable particulate (PM{sub 2.5}), and mercury; alternative transportation fuels including liquid synfuels and hydrogen; and synergistic integration of fossil and renewable resources (e.g., wind-, biomass-, and coal-based electrical generation).

  3. Integrated Agent-based and Case-based Reasoning System

    International Nuclear Information System (INIS)

    Mohamed, A.H.

    2014-01-01

    Increasing the complexity of the modern systems drives to use multiple case bases in the case based reasoning (CBR) system to solve a single problem. Sometimes, it is difficult and unman gable task to store the knowledge of the domain of these complex systems in a single case base. On the other hand, usually these multiple case bases having different structures that cause main limitation for solving the problem. This research introduces integrating the case based systems using multiple case bases with agent-based technique. This enables the system to use different case base structures. The proposed system has been applied for designing the radiotherapy of the kidney, liver and skin cancers. It is found that, the suggested system has simplified, managed the complexity, increasing the accuracy of the of CBR systems. Therefore, it can be applied with a good performance for the practical sites

  4. A comparison between centre-based and expedition-based ...

    African Journals Online (AJOL)

    A comparison between centre-based and expedition-based (wilderness) adventure experiential learning regarding group effectiveness: A mixed methodology ... it is strongly recommended that a centre-based adventure program be used – mainly on account of active involvement, intensive social interaction and continuous ...

  5. NMR studies concerning base-base interactions in oligonucleotides

    International Nuclear Information System (INIS)

    Hoogen, Y.T. van den.

    1988-01-01

    Two main subjects are treated in the present thesis. The firsst part principally deals with the base-base interactions in single-stranded oligoribonucleotides. The second part presents NMR and model-building studies of DNA and RNA duplexes containing an unpaired base. (author). 242 refs.; 26 figs.; 24 tabs

  6. Implementation of Task-based and problem-based ...

    African Journals Online (AJOL)

    This paper describes implementation of new task-based and problem-based pharmacotherapy course for 3rd year pre-clinical medical students at Faculty of Medicine and Health Sciences, Omdurman Islamic University. Keywords: Pharmacotherapy, Task-based learning, P -drug. Sudan Journal of Medical Science Vol.

  7. Flow-Based Provenance

    Directory of Open Access Journals (Sweden)

    Sabah Al-Fedaghi

    2017-02-01

    Full Text Available Aim/Purpose: With information almost effortlessly created and spontaneously available, current progress in Information and Communication Technology (ICT has led to the complication that information must be scrutinized for trustworthiness and provenance. Information systems must become provenance-aware to be satisfactory in accountability, reproducibility, and trustworthiness of data. Background:\tMultiple models for abstract representation of provenance have been proposed to describe entities, people, and activities involved in producing a piece of data, including the Open Provenance Model (OPM and the World Wide Web Consortium. These models lack certain concepts necessary for specifying workflows and encoding the provenance of data products used and generated. Methodology: Without loss of generality, the focus of this paper is on OPM depiction of provenance in terms of a directed graph. We have redrawn several case studies in the framework of our proposed model in order to compare and evaluate it against OPM for representing these cases. Contribution: This paper offers an alternative flow-based diagrammatic language that can form a foundation for modeling of provenance. The model described here provides an (abstract machine-like representation of provenance. Findings: The results suggest a viable alternative in the area of diagrammatic representation for provenance applications. Future Research: Future work will seek to achieve more accurate comparisons with current models in the field.

  8. Refractory metal based superalloys

    International Nuclear Information System (INIS)

    Alonso, Paula R.; Vicente, Eduardo E.; Rubiolo, Gerardo H.

    1999-01-01

    Refractory metals are looked as promising materials for primary circuits in fission reactors and even as fusion reactor components. Indeed, superalloys could be developed which take advantage of their high temperature properties together with the benefits of a two- phase (intermetallic compound-refractory metal matrix) coherent structure. In 1993, researchers of the Office National d'Etudes et de Recherches Aerospatiales of France reported the observation of such a coherent structure in the Ta-Ti-Zr-Al-Nb-Mo system although the exact composition is not reported. The intermetallic compound would be Ti 2 AlMo based. However, the formation of this compound and its possible coexistence with a disordered bcc phase in the ternary system Ti-Al-Mo is a controversial subject in the related literature. In this work we develop a technique to obtain homogeneous alloys samples with 50 Ti-25 Al-25 Mo composition. The resulting specimens were characterized by optical and electronic metallography (SEM), microprobe composition measurements (EPMA) and X-ray diffraction (XRD) analyses. The results show the evidence for a bcc (A2→B2) ordering reaction in the Ti-Al-Mo system in the 50 Ti-25 Al-25 Mo composition. (author)

  9. Fluorescence lifetime based bioassays

    Science.gov (United States)

    Meyer-Almes, Franz-Josef

    2017-12-01

    Fluorescence lifetime (FLT) is a robust intrinsic property and material constant of fluorescent matter. Measuring this important physical indicator has evolved from a laboratory curiosity to a powerful and established technique for a variety of applications in drug discovery, medical diagnostics and basic biological research. This distinct trend was mainly driven by improved and meanwhile affordable laser and detection instrumentation on the one hand, and the development of suitable FLT probes and biological assays on the other. In this process two essential working approaches emerged. The first one is primarily focused on high throughput applications employing biochemical in vitro assays with no requirement for high spatial resolution. The second even more dynamic trend is the significant expansion of assay methods combining highly time and spatially resolved fluorescence data by fluorescence lifetime imaging. The latter approach is currently pursued to enable not only the investigation of immortal tumor cell lines, but also specific tissues or even organs in living animals. This review tries to give an actual overview about the current status of FLT based bioassays and the wide range of application opportunities in biomedical and life science areas. In addition, future trends of FLT technologies will be discussed.

  10. Mentalization-Based Treatment.

    Science.gov (United States)

    Bateman, Anthony; Fonagy, Peter

    2013-11-01

    The concept of mentalizing has captured the interest and imagination of an astonishing range of people-from psychoanalysts to neuroscientists, from child development researchers to geneticists, from existential philosophers to phenomenologists-all of whom seem to have found it useful. According to the Thompson Reuter maintained Web of Science, the use of the term in titles and abstracts of scientific papers increased from 10 to 2,750 between 1991 and 2011. Clinicians in particular have enthusiastically embraced the idea, and have put it to innovative use in their practices. Mentalization-based treatment (MBT)-making mentalizing a core focus of therapy-was initially developed for the treatment of borderline personality disorder (BPD) in routine clinical services delivered in group and individual modalities. Therapy with mentalizing as a central component is currently being developed for treatment of numerous groups, including people with antisocial personality disorder, substance abuse, eating disorders, and at-risk mothers with infants and children (A. Bateman & Fonagy, 2011). It is also being used with families and adolescents, in schools, and in managing social groups (Asen & Fonagy, 2011; Fonagy et al., 2009; Twemlow, Fonagy, & Sacco, 2005a, 2005b). In this article, we focus on MBT in the treatment of BPD.

  11. Communication Base Station Log Analysis Based on Hierarchical Clustering

    Directory of Open Access Journals (Sweden)

    Zhang Shao-Hua

    2017-01-01

    Full Text Available Communication base stations generate massive data every day, these base station logs play an important value in mining of the business circles. This paper use data mining technology and hierarchical clustering algorithm to group the scope of business circle for the base station by recording the data of these base stations.Through analyzing the data of different business circle based on feature extraction and comparing different business circle category characteristics, which can choose a suitable area for operators of commercial marketing.

  12. Risk-based configuration control

    International Nuclear Information System (INIS)

    Szikszai, T.

    1997-01-01

    The presentation discusses the following issues: The Configuration Control; The Risk-based Configuration Control (during power operation mode, and during shutdown mode). PSA requirements. Use of Risk-based Configuration Control System. Configuration Management (basic elements, benefits, information requirements)

  13. Mindfulness-Based Stress Reduction

    Science.gov (United States)

    ... R S T U V W X Y Z Mindfulness-Based Stress Reduction (MBSR) Information 6 Things You ... Disease and Dementia (12/20/13) Research Spotlights Mindfulness-Based Stress Reduction, Cognitive-Behavioral Therapy Shown To ...

  14. ‘"Education-based Research"

    DEFF Research Database (Denmark)

    Degn Johansson, Troels

    This paper lays out a concept of education-based research-the production of research knowledge within the framework of tertiary design education-as an integration of problem-based learning and research-based education. This leads to a critique of reflective practice as the primary way to facilita...... learning at this level, a discussion of the nature of design problems in the instrumentalist tradition, and some suggestions as to how design studies curricula may facilitate education-based research....

  15. ASCOT data base management system

    Energy Technology Data Exchange (ETDEWEB)

    Barbieri, J.; Nyholm, R.; Castro, C.; Hill, K.

    1980-07-01

    The ASCOT data base management system is designed to handle the data produced by both the experimental and theoretical efforts of the DOE Atmospheric Studies in Complex Terrain (ASCOT) project. The data base envisioned is hierarchically structured, sparse, and compact. Information concerning any given data file is stored in a directory file. The data base management system uses a relational data management approach. Presently three management schema are being developed for use with the data base. 5 figures.

  16. Graphene based gene transfection

    Science.gov (United States)

    Feng, Liangzhu; Zhang, Shuai; Liu, Zhuang

    2011-03-01

    Graphene as a star in materials research has been attracting tremendous attentions in the past few years in various fields including biomedicine. In this work, for the first time we successfully use graphene as a non-toxic nano-vehicle for efficient gene transfection. Graphene oxide (GO) is bound with cationic polymers, polyethyleneimine (PEI) with two different molecular weights at 1.2 kDa and 10 kDa, forming GO-PEI-1.2k and GO-PEG-10k complexes, respectively, both of which are stable in physiological solutions. Cellular toxicity tests reveal that our GO-PEI-10k complex exhibits significantly reduced toxicity to the treated cells compared to the bare PEI-10k polymer. The positively charged GO-PEI complexes are able to further bind with plasmid DNA (pDNA) for intracellular transfection of the enhanced green fluorescence protein (EGFP) gene in HeLa cells. While EGFP transfection with PEI-1.2k appears to be ineffective, high EGFP expression is observed using the corresponding GO-PEI-1.2k as the transfection agent. On the other hand, GO-PEI-10k shows similar EGFP transfection efficiency but lower toxicity compared with PEI-10k. Our results suggest graphene to be a novel gene delivery nano-vector with low cytotoxicity and high transfection efficiency, promising for future applications in non-viral based gene therapy.Graphene as a star in materials research has been attracting tremendous attentions in the past few years in various fields including biomedicine. In this work, for the first time we successfully use graphene as a non-toxic nano-vehicle for efficient gene transfection. Graphene oxide (GO) is bound with cationic polymers, polyethyleneimine (PEI) with two different molecular weights at 1.2 kDa and 10 kDa, forming GO-PEI-1.2k and GO-PEG-10k complexes, respectively, both of which are stable in physiological solutions. Cellular toxicity tests reveal that our GO-PEI-10k complex exhibits significantly reduced toxicity to the treated cells compared to the bare PEI

  17. Home-based Healthcare Technology

    DEFF Research Database (Denmark)

    Verdezoto, Nervo

    of these systems target a specific treatment or condition and might not be sufficient to support the care management work at home. Based on a case study approach, my research investigates home-based healthcare practices and how they can inform future design of home-based healthcare technology that better account...

  18. Securing web-based exams

    NARCIS (Netherlands)

    Sessink, O.D.T.; Beeftink, H.H.; Tramper, J.; Hartog, R.J.M.

    2004-01-01

    Learning management systems may offer web-based exam facilities. Such facilities entail a higher risk to exams fraud than traditional paper-based exams. The article discusses security issues with web-based exams, and proposes precautionary measures to reduce the risks. A security model is presented

  19. Performance-Based Funding Brief

    Science.gov (United States)

    Washington Higher Education Coordinating Board, 2011

    2011-01-01

    A number of states have made progress in implementing performance-based funding (PFB) and accountability. This policy brief summarizes main features of performance-based funding systems in three states: Tennessee, Ohio, and Indiana. The brief also identifies key issues that states considering performance-based funding must address, as well as…

  20. Condition based spare parts supply

    NARCIS (Netherlands)

    Lin, X.; Basten, Robertus Johannes Ida; Kranenburg, A.A.; van Houtum, Geert-Jan

    2012-01-01

    We consider a spare parts stock point that serves an installed base of machines. Each machine contains the same critical component, whose degradation behavior is described by a Markov process. We consider condition based spare parts supply, and show that an optimal, condition based inventory policy