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Sample records for bismuth 209 beams

  1. A route for polonium 210 production from alpha-particle irradiated bismuth-209 target

    International Nuclear Information System (INIS)

    A method is proposed for production of polonium-210 via the 209Bi(α,3n)210 At nuclear reaction. Bombardment of a bismuth-209 target was performed with a 37 MeV alpha-particle beam that leads to the production of astatine-210 (T1/2 = 8.1 h), which decays to polonium-210. It is purified from the bismuth target matrix by employing liquid-liquid extraction using tributyl phosphate (TBP) in para-xylene from 7 M hydrochloric acid. Back extraction of polonium-210 was performed by 9 M nitric acid. This method allows to purify a tracer amount of Po-210 (2.6 x 10-13 mol) from macroscopic amount of Bi (2.8 x 10-2 mol).

  2. High-energy neutron-induced fission cross sections of natural lead and bismuth-209

    OpenAIRE

    Calviño Tavares, Francisco; Cortés Rossell, Guillem Pere; Poch Parés, Agustí; Pretel Sánchez, Carme

    2011-01-01

    The CERN Neutron Time-Of-Flight (n TOF) facility is well suited to measure small neutron- induced ssion cross sections, as those of subactinides. The cross section ratios of natPb and 209Bi relative to 235U and 238U were measured using PPAC detectors. The fragment coincidence method allows to unambiguously identify the ssion events. The present experiment provides the rst results for neutron-induced ssion up to 1 GeV for natPb and 209Bi. A good agreement with previous exper...

  3. High-energy Neutron-induced Fission Cross Sections of Natural Lead and Bismuth-209

    CERN Document Server

    Tarrio, D; Carrapico, C; Eleftheriadis, C; Leeb, H; Calvino, F; Herrera-Martinez, A; Savvidis, I; Vlachoudis, V; Haas, B; Koehler, P; Vannini, G; Oshima, M; Le Naour, C; Gramegna, F; Wiescher, M; Pigni, M T; Audouin, L; Mengoni, A; Quesada, J; Becvar, F; Plag, R; Cennini, P; Mosconi, M; Rauscher, T; Couture, A; Capote, R; Sarchiapone, L; Vlastou, R; Domingo-Pardo, C; Dillmann, I; Pavlopoulos, P; Karamanis, D; Krticka, M; Jericha, E; Ferrari, A; Martinez, T; Trubert, D; Oberhummer, H; Karadimos, D; Plompen, A; Isaev, S; Terlizzi, R; Cortes, G; Cox, J; Cano-Ott, D; Pretel, C; Colonna, N; Berthoumieux, E; Vaz, P; Heil, M; Lopes, I; Lampoudis, C; Walter, S; Calviani, M; Gonzalez-Romero, E; Embid-Segura, M; Stephan, C; Igashira, M; Papachristodoulou, C; Aerts, G; Tavora, L; Berthier, B; Rudolf, G; Andrzejewski, J; Villamarin, D; Ferreira-Marques, R; Tain, J L; O'Brien, S; Reifarth, R; Kadi, Y; Neves, F; Poch, A; Kerveno, M; Rubbia, C; Lazano, M; Dahlfors, M; Wisshak, K; Salgado, J; Dridi, W; Ventura, A; Andriamonje, S; Assimakopoulos, P; Santos, C; Voss, F; Ferrant, L; Patronis, N; Chiaveri, E; Guerrero, C; Perrot, L; Vicente, M C; Lindote, A; Praena, J; Baumann, P; Kappeler, F; Rullhusen, P; Furman, W; David, S; Marrone, S; Tassan-Got, L; Gunsig, F; Alvarez-Velarde, F; Massimi, C; Mastinu, P; Pancin, J; Papadopoulos, C; Tagliente, G; Haight, R; Chepel, V; Kossionides, E; Badurek, G; Marganiec, J; Lukic, S; Pavlik, A; Goncalves, I; Duran, I; Alvarez, H; Abbondanno, U; Fujii, K; Milazzo, P M; Moreau, C

    2011-01-01

    The CERN Neutron Time-Of-Flight (n\\_TOF) facility is well suited to measure small neutron-induced fission cross sections, as those of subactinides. The cross section ratios of (nat)Pb and (209)Bi relative to (235)U and (238)U were measured using PPAC detectors. The fragment coincidence method allows to unambiguously identify the fission events. The present experiment provides the first results for neutron-induced fission up to 1 GeV for (nat)Pb and (209)Bi. A good agreement with previous experimental data below 200 MeV is shown. The comparison with proton-induced fission indicates that the limiting regime where neutron-induced and proton-induced fission reach equal cross section is close to 1 GeV.

  4. Determination of the {sup 209}Bi(n,{gamma}){sup 210}Bi and {sup 209}Bi(n,{gamma}){sup 210m,g}Bi reaction cross sections in a cold neutron beam

    Energy Technology Data Exchange (ETDEWEB)

    Borella, A. [European Commission, Joint Research Centre, Institute for Reference Materials and Measurements, B-2440 Geel (Belgium); SCK-CEN, Boeretang 200, B-2400 Mol (Belgium); Belgya, T. [Institute of Isotope, Hungarian Academy of Sciences, POB 77, H-1525 Budapest (Hungary); Kopecky, S. [European Commission, Joint Research Centre, Institute for Reference Materials and Measurements, B-2440 Geel (Belgium); Gunsing, F. [CEA/Saclay, DSM/Irfu, F-91191 Gif-sur-Yvette (France); Moxon, M. [Hyde Copse 3, Marcham (United Kingdom); Rejmund, M. [GANIL, F-14076 Caen (France); Schillebeeckx, P., E-mail: peter.schillebeeckx@ec.europa.e [European Commission, Joint Research Centre, Institute for Reference Materials and Measurements, B-2440 Geel (Belgium); Szentmiklosi, L. [Institute of Isotope, Hungarian Academy of Sciences, POB 77, H-1525 Budapest (Hungary)

    2011-01-15

    Gamma-ray transitions following neutron capture in {sup 209}Bi have been studied at the cold neutron beam facility of the Budapest Neutron Centre. Measurements have been performed using a coaxial HPGe detector with Compton suppression. Partial capture cross sections at a velocity of 2200 m/s (or a neutron energy of 25.3 meV) have been deduced relatively to the one for the 4055 keV transition after thermal neutron capture in {sup 209}Bi. This partial cross section of (8.07 {+-} 0.14) mb has in turn been obtained from measurements with a bismuth nitrate target relatively to the cross section for the 1884 keV transition after thermal neutron capture in {sup 14}N. Shell model calculations have been performed to deduce the half-life of the 3rd excited state at 320 keV and to assign the M1 multipolarity of the 320 keV transition to the ground state. Lower limits of (21.4 {+-} 0.8) mb and (18.2 {+-} 0.7) mb for the cross sections to the ground state and to the isomeric state, respectively, have been deduced from the data for the gamma rays feeding these states. The results obtained in this work are in good agreement with experimental data reported in the literature. The thermal total capture cross section has been compared with the contribution due to observed s-wave resonances.

  5. Size-dependent crystalline fluctuation and growth mechanism of bismuth nanoparticles under electron beam irradiation

    Science.gov (United States)

    Wu, Sujuan; Jiang, Yi; Hu, Lijun; Sun, Jianguo; Wan, Piaopiao; Sun, Lidong

    2016-06-01

    Advanced nanofabrication requires accurate tailoring of various nanostructures with the assistance of electron or ion beam irradiation. However, evolution of the nanostructures under the beam irradiation significantly affects the fabrication process. It is thus of paramount importance to study the evolution behaviors and growth mechanism of the nanostructures. In this study, bismuth nanoparticles were selected to investigate crystalline fluctuation under electron beam irradiation via transmission electron microscopy. The results disclose size-dependent crystalline fluctuation of the nanoparticles. The particles exhibit crystalline and non-crystalline features for sizes of above 15 and below 4 nm, respectively, while a mixture of the two states is observed with sizes in between. The crystalline fluctuation facilitates the growth process of the particles when a crystalline particle is in contact with another non-crystalline one. This is promising for applications in nanofabrication where high quality interfaces are desired between two joining parts.Advanced nanofabrication requires accurate tailoring of various nanostructures with the assistance of electron or ion beam irradiation. However, evolution of the nanostructures under the beam irradiation significantly affects the fabrication process. It is thus of paramount importance to study the evolution behaviors and growth mechanism of the nanostructures. In this study, bismuth nanoparticles were selected to investigate crystalline fluctuation under electron beam irradiation via transmission electron microscopy. The results disclose size-dependent crystalline fluctuation of the nanoparticles. The particles exhibit crystalline and non-crystalline features for sizes of above 15 and below 4 nm, respectively, while a mixture of the two states is observed with sizes in between. The crystalline fluctuation facilitates the growth process of the particles when a crystalline particle is in contact with another non

  6. Bi209 alpha activity

    International Nuclear Information System (INIS)

    The study for measuring Bi209 alpha activity is presented. Ilford L4 nuclear emulsion pellicles loaded with bismuth citrate to obtain a load of 100 mg/cm3 of dry emulsion, were prepared. Other pellicles were prepared with the same. Ilford L4 gel to estimate the background radiation. To observe 'fading' effect, pellicles loaded with bismuth were submitted to neutrons of high energy, aiming to record recoil proton tracks. The pellicles were confined in nitrogen atmosphere at temperature lower than -100C. The Bi209 experimental half-life was obtained and compared with the estimated theoretical data. (M.C.K.)

  7. Long-life bismuth liquid metal ion source for focussed ion beam micromachining application

    Energy Technology Data Exchange (ETDEWEB)

    Mazarov, P. [Lehrstuhl fuer Angewandte Festkoerperphysik, Ruhr-Universitaet Bochum, D-44780 Bochum (Germany)], E-mail: paul.mazarov@ruhr-uni-bochum.de; Melnikov, A.; Wernhardt, R.; Wieck, A.D. [Lehrstuhl fuer Angewandte Festkoerperphysik, Ruhr-Universitaet Bochum, D-44780 Bochum (Germany)

    2008-09-15

    Liquid metal ion sources (LMISs) with Ga as ion species are widely used in focused ion beam (FIB) technology for micromachining and surface treatment on the sub-micron and nano-scale. Key features of a LMIS for investigating mechanical properties and 3D-microfabrication of materials are long life-time, high brightness, stable ion current and a highly effective milling ability for the material to be modified. In order to increase the material removal rate, heavier ions than Ga and their clusters should be applied. Bismuth (Bi) is the heaviest, non-radio-active element in the periodic table, is non-toxic and exhibits a low melting point. We have thus produced a long-life (about 1000 h) Bi LMIS with a good beam performance, applicable in any FIB system. Since Bi is the only element in this source, it is not necessary to separate it from other ions by a mass filter. Investigation of the sputtering rate of NiTi shape memory alloys using Ga and Bi LMIS showed that, for the same experimental conditions, the material removal rate with using of Bi{sub n}{sup k+} ions in a standard FIB machine without a mass separator is about five times larger compared to Ga{sup +} ions. This use of Bi as LMIS-species is the ultimate breakthrough in sputtering applications.

  8. Long-life bismuth liquid metal ion source for focussed ion beam micromachining application

    International Nuclear Information System (INIS)

    Liquid metal ion sources (LMISs) with Ga as ion species are widely used in focused ion beam (FIB) technology for micromachining and surface treatment on the sub-micron and nano-scale. Key features of a LMIS for investigating mechanical properties and 3D-microfabrication of materials are long life-time, high brightness, stable ion current and a highly effective milling ability for the material to be modified. In order to increase the material removal rate, heavier ions than Ga and their clusters should be applied. Bismuth (Bi) is the heaviest, non-radio-active element in the periodic table, is non-toxic and exhibits a low melting point. We have thus produced a long-life (about 1000 h) Bi LMIS with a good beam performance, applicable in any FIB system. Since Bi is the only element in this source, it is not necessary to separate it from other ions by a mass filter. Investigation of the sputtering rate of NiTi shape memory alloys using Ga and Bi LMIS showed that, for the same experimental conditions, the material removal rate with using of Bink+ ions in a standard FIB machine without a mass separator is about five times larger compared to Ga+ ions. This use of Bi as LMIS-species is the ultimate breakthrough in sputtering applications

  9. Structural, optical, and transport properties of nanocrystalline bismuth telluride thin films treated with homogeneous electron beam irradiation and thermal annealing.

    Science.gov (United States)

    Takashiri, Masayuki; Asai, Yuki; Yamauchi, Kazuki

    2016-08-19

    We investigated the effects of homogeneous electron beam (EB) irradiation and thermal annealing treatments on the structural, optical, and transport properties of bismuth telluride thin films. Bismuth telluride thin films were prepared by an RF magnetron sputtering method at room temperature. After deposition, the films were treated with homogeneous EB irradiation, thermal annealing, or a combination of both the treatments (two-step treatment). We employed Williamson-Hall analysis for separating the strain contribution from the crystallite domain contribution in the x-ray diffraction data of the films. We found that strain was induced in the thin films by EB irradiation and was relieved by thermal annealing. The crystal orientation along c-axis was significantly enhanced by the two-step treatment. Scanning electron microscopy indicated the melting and aggregation of nano-sized grains on the film surface by the two-step treatment. Optical analysis indicated that the interband transition of all the thin films was possibly of the indirect type, and that thermal annealing and two-step treatment methods increased the band gap of the films due to relaxation of the strain. Thermoelectric performance was significantly improved by the two-step treatment. The power factor reached a value of 17.2 μW (cm(-1) K(-2)), approximately 10 times higher than that of the as-deposited thin films. We conclude that improving the crystal orientation and relaxing the strain resulted in enhanced thermoelectric performance. PMID:27389820

  10. Structural, optical, and transport properties of nanocrystalline bismuth telluride thin films treated with homogeneous electron beam irradiation and thermal annealing

    Science.gov (United States)

    Takashiri, Masayuki; Asai, Yuki; Yamauchi, Kazuki

    2016-08-01

    We investigated the effects of homogeneous electron beam (EB) irradiation and thermal annealing treatments on the structural, optical, and transport properties of bismuth telluride thin films. Bismuth telluride thin films were prepared by an RF magnetron sputtering method at room temperature. After deposition, the films were treated with homogeneous EB irradiation, thermal annealing, or a combination of both the treatments (two-step treatment). We employed Williamson–Hall analysis for separating the strain contribution from the crystallite domain contribution in the x-ray diffraction data of the films. We found that strain was induced in the thin films by EB irradiation and was relieved by thermal annealing. The crystal orientation along c-axis was significantly enhanced by the two-step treatment. Scanning electron microscopy indicated the melting and aggregation of nano-sized grains on the film surface by the two-step treatment. Optical analysis indicated that the interband transition of all the thin films was possibly of the indirect type, and that thermal annealing and two-step treatment methods increased the band gap of the films due to relaxation of the strain. Thermoelectric performance was significantly improved by the two-step treatment. The power factor reached a value of 17.2 μW (cm‑1 K‑2), approximately 10 times higher than that of the as-deposited thin films. We conclude that improving the crystal orientation and relaxing the strain resulted in enhanced thermoelectric performance.

  11. Beam-foil spectroscopy of n=3 to n=2 transitions in highly stripped bismuth

    International Nuclear Information System (INIS)

    The n=3 to 2 transitions in Ne-like, Na-like, and Mg-like bismuth were measured on the UNILAC accelerator at the Gesellschaft fuer Schwerionenforschung in Darmstadt, West Germany, using the Lawrence Livermore National Laboratory high-resolution double-crystal spectrometer. The measurements cover the region 10--14 keV with precisions of the order of 100 ppm and include electric-dipole and quadrupole transitions. Theoretical multiconfigurational Dirac-Fock calculations were made for the Ne-like system and compared to the experiment. The data exhibit energy shifts of 1.5--2.5 eV from the theory, confirming trends previously observed in tokamak experiments. The Na-like and Mg-like results are compared with unresolved transition array calculations

  12. The Effect of Beam Intensity on Temperature Distribution in ADS Windowless Lead-Bismuth Eutectic Spallation Target

    Directory of Open Access Journals (Sweden)

    Jie Liu

    2014-01-01

    Full Text Available The spallation target is the component coupling the accelerator and the reactor and is regarded as the “heart” of the accelerator driven system (ADS. Heavy liquid metal lead-bismuth eutectic (LBE is served as core coolant and spallation material to carry away heat deposition of spallation reaction and produce high flux neutron. So it is very important to study the heat transfer process in the target. In this paper, the steady-state flow pattern has been numerically obtained and taken as the input for the nuclear physics calculation, and then the distribution of the extreme large power density of the heat load is imported back to the computational fluid dynamics as the source term in the energy equation. Through the coupling, the transient and steady-state temperature distribution in the windowless spallation target is obtained and analyzed based on the flow process and heat transfer. Comparison of the temperature distribution with the different beam intensity shows that its shape is the same as broken wing of the butterfly. Nevertheless, the maximum temperature as well as the temperature gradient is different. The results play an important role and can be applied to the further design and optimization of the ADS windowless spallation target.

  13. Measurements of gas and volatile element production rates from an irradiated molten lead and lead-bismuth spallation target with proton beams of 1 and 1.4 GeV

    International Nuclear Information System (INIS)

    The integrated project EUROTRANS (European Research Programme for the Transmutation of High Level Nuclear Waste in an Accelerator Driven System) of the 6. EURATOM Framework Programme aims to demonstrate the transmutation of radioactive waste in ADS (Accelerator Driven Sub-critical system). It will carry out a first advanced design of an experimental facility to demonstrate the technical feasibility of transmutation, and will produce a conceptual design of an industrial facility dedicated to transmutation. An ADS consists of three fundamental elements: the accelerator of protons, the sub-critical core and the spallation target. SUBATECH (physique Sub-Atomique et des Technologies associees) laboratory is involved to the study of the chosen liquid lead-bismuth as a spallation ADS target. The irradiation of liquid lead-bismuth target with energetic proton beam generates in addition to neutrons, volatile and radioactive residues. In order to determine experimentally the production rates of gas and volatile elements following a spallation reaction in a lead-bismuth target, the experiment IS419 was performed at the ISOLDE facility at CERN (Centre Europeen de la Recherche Nucleaire). This experiment constitutes the frame of the thesis whose main objective is to assess and study the production and release rates of many gas and volatile element from the irradiated lead-bismuth target with an energetic proton beam. The obtained data are compared to Monte Carlo simulation code (MCNPX) results in order to test the intranuclear cascade model of Bertini and of Cugnon, and the evaporation options of Dresner and Schmidt. (author)

  14. Bismuth, Metronidazole, and Tetracycline

    Science.gov (United States)

    Helidac® (as a kit containing Bismuth Subsalicylate, Metronidazole, Tetracycline) ... Bismuth, metronidazole, and tetracycline is used along with other ulcer medications to treat duodenal ulcers. It is in a class of medications called ...

  15. Novel Bismuth Nanotubes

    Institute of Scientific and Technical Information of China (English)

    苏长荣; 李家明

    2002-01-01

    Theoretical investigations show that bismuth nanotubes are semiconductors for all diameters. For smalldiameter bismuth nanotubes, the band structures and bandgaps vary strongly with the strong hybridization effect. When the diameters are larger than 18 A, the bandgaps ofBi (n, n) and (n, 0) nanotubes approach 0.63 e V, corresponding to the bandgap of bismuth sheet at the Γ point. Thus, bismuth nanotubes are expected to be a potential semiconductor nanomaterial in future nanoelectronics.

  16. Measurement of cross sections of the 210Po production reaction by keV-neutron capture of 209Bi

    International Nuclear Information System (INIS)

    The cross sections of the 209Bi(n, γ)210gBi reaction were measured in the keV-neutron region, using an activation method with the detection of α rays from 210Po. Pulsed keV neutrons were generated from the 7Li(p, n)7Be reaction by a 1.5-ns bunched proton beam from the 3-MV Pelletron accelerator of the Research Laboratory for Nuclear Reactors at the Tokyo Institute of Technology. The 209Bi samples were metallic bismuth evaporated on a gold backing. After sample irradiation, the 412-keV γrays from the gold backing were measured with on HPGe detector, and then the α rays from 210Po nuclei in the bismuth sample were measured with a Si surface barrier detector. The derived cross sections were 1.9±0.4 mb and 0.62±0.14 mb at the average neutron energies of 30 keV and 534 keV, respectively. The present value at 30 keV is in agreement with the previous measurement at 24 keV of Booth et al., but about a quarter of the evaluation of JENDL Activation cross section File. The present result at 534 keV is the first experimental one around 500 keV, and is about a half of the evaluation of JENDL Activation cross section File. (author)

  17. Measurements of gas and volatile element production rates from an irradiated molten lead and lead-bismuth spallation target with proton beams of 1 and 1.4 GeV; Mesures de taux de production d'elements gazeux et volatiles lors de reactions induites par des protons de 1 et 1,4 GeV sur des cibles epaisses de plomb et plomb-bismuth liquides

    Energy Technology Data Exchange (ETDEWEB)

    Tall, Y

    2008-03-15

    The integrated project EUROTRANS (European Research Programme for the Transmutation of High Level Nuclear Waste in an Accelerator Driven System) of the 6. EURATOM Framework Programme aims to demonstrate the transmutation of radioactive waste in ADS (Accelerator Driven Sub-critical system). It will carry out a first advanced design of an experimental facility to demonstrate the technical feasibility of transmutation, and will produce a conceptual design of an industrial facility dedicated to transmutation. An ADS consists of three fundamental elements: the accelerator of protons, the sub-critical core and the spallation target. SUBATECH (physique Sub-Atomique et des Technologies associees) laboratory is involved to the study of the chosen liquid lead-bismuth as a spallation ADS target. The irradiation of liquid lead-bismuth target with energetic proton beam generates in addition to neutrons, volatile and radioactive residues. In order to determine experimentally the production rates of gas and volatile elements following a spallation reaction in a lead-bismuth target, the experiment IS419 was performed at the ISOLDE facility at CERN (Centre Europeen de la Recherche Nucleaire). This experiment constitutes the frame of the thesis whose main objective is to assess and study the production and release rates of many gas and volatile element from the irradiated lead-bismuth target with an energetic proton beam. The obtained data are compared to Monte Carlo simulation code (MCNPX) results in order to test the intranuclear cascade model of Bertini and of Cugnon, and the evaporation options of Dresner and Schmidt. (author)

  18. Electron beam induced modifications of bismuth sulphide (Bi2S3) thin films: Structural and optical properties

    International Nuclear Information System (INIS)

    Thin films of Bi2S3 prepared by electrodeposition method are subjected to electron beam irradiation for different doses from 0 to 100 kGy in steps of 20 kGy in air at room temperature. The changes in structural, surface morphological and optical properties that occurred before and after irradiation in Bi2S3 thin films are studied using X-ray diffraction, scanning electron microscopy and UV-vis spectroscopy. It is shown that electron irradiation can be used as a tool to decrease the crystallite size of the irradiated films from 418 to 285 A as the dose varies from 20 to 100 kGy. The decrease in crystallinity of the films leading to the band gap energy of the films get blue shifted from unirradiated films. These results are explained in the light of thermal spike model.

  19. Laser spectroscopy of the ground-state hyperfine structure in H-like and Li-like bismuth

    International Nuclear Information System (INIS)

    The LIBELLE experiment performed at the experimental storage ring (ESR) at the GSI Helmholtz Center in Darmstadt aims for the determination of the ground state hyperfine (HFS) transitions and lifetimes in hydrogen-like (209Bi82+) and lithium-like (209Bi80+) bismuth. The study of HFS transitions in highly charged ions enables precision tests of QED in extreme electric and magnetic fields otherwise not attainable in laboratory experiments. While the HFS transition in H-like bismuth was already observed in earlier experiments at the ESR, the LIBELLE experiment succeeded for the first time to measure the HFS transition in Li-like bismuth in a laser spectroscopy experiment

  20. At R209

    CERN Multimedia

    1977-01-01

    Side view of R209, showing a large muon chamber in front of the Iron toroid magnet. Gunter Feilhauer is looking down from top of the magnet. Ulrich Becker (left), Lars Leistam (right) stand on the floor.

  1. Phase transition of bismuth telluride thin films grown by MBE

    DEFF Research Database (Denmark)

    Fülöp, Attila; Song, Yuxin; Charpentier, Sophie;

    2014-01-01

    A previously unreported phase transition between Bi2Te3 and Bi4Te3 in bismuth telluride grown by molecular beam epitaxy is recorded via XRD, AFM, and SIMS observations. This transition is found to be related to the Te/Bi beam equivalent pressure (BEP) ratio. BEP ratios below 17 favor the formatio...

  2. Identification of 209Hg

    International Nuclear Information System (INIS)

    The new neutron-rich nuclide 209Hg has been identified for the first time. An on-line, gas-thermochromatographic technique was developed for rapidly separating the Hg-element products from 600-MeV 18O+natPb(thick target) reaction system. A special detection arrangement was used in order to detect the weak γ-activities of the neutron-rich Hg isotopes. The half-life of 209Hg was determined to be 35-6+9 s. (orig.)

  3. Comment: 209 [Taxonomy Icon

    Lifescience Database Archive (English)

    Full Text Available Anopheles stephensi Anopheles stephensi Anopheles_stephensi_L.png 209.png Public Do...main CDC(Centers for Disease Control and Prevention)のimage libraryから(Public Domain) http://phil.cdc.gov/phil/home.asp bando 2010/02/15 14:46:05 2010/02/15 14:49:04 ...

  4. Valley polarization in bismuth

    Science.gov (United States)

    Fauque, Benoit

    2013-03-01

    The electronic structure of certain crystal lattices can contain multiple degenerate valleys for their charge carriers to occupy. The principal challenge in the development of valleytronics is to lift the valley degeneracy of charge carriers in a controlled way. In bulk semi-metallic bismuth, the Fermi surface includes three cigar-shaped electron valleys lying almost perpendicular to the high symmetry axis known as the trigonal axis. The in-plane mass anisotropy of each valley exceeds 200 as a consequence of Dirac dispersion, which drastically reduces the effective mass along two out of the three orientations. According to our recent study of angle-dependent magnetoresistance in bismuth, a flow of Dirac electrons along the trigonal axis is extremely sensitive to the orientation of in-plane magnetic field. Thus, a rotatable magnetic field can be used as a valley valve to tune the contribution of each valley to the total conductivity. As a consequence of a unique combination of high mobility and extreme mass anisotropy in bismuth, the effect is visible even at room temperature in a magnetic field of 1 T. Thus, a modest magnetic field can be used as a valley valve in bismuth. The results of our recent investigation of angle-dependent magnetoresistance in other semi-metals and doped semiconductors suggest that a rotating magnetic field can behave as a valley valve in a multi-valley system with sizeable mass anisotropy.

  5. Magnetoconductance fluctuations in open bismuth quantum dots

    Science.gov (United States)

    Hackens, B.; Minet, J. P.; Farhi, G.; Crahay, A.; Faniel, S.; Gustin, C.; Bayot, V.

    2002-03-01

    We investigate the low temperature (300 mK - 10 K) magnetoconductance of open circular bismuth quantum dots (diameter: 500 nm). The structures are fabricated using a combination of electron beam lithography, lift off and plasma etching techniques on bismuth thin films evaporated on heated SiO2 substrates. We observe reproducible magnetoconductance fluctuations (UCFs) up to 5T, qualitatively similar to conductance fluctuations evidenced in open quantum dots patterned in high mobility semiconductor heterostructures. In our samples, UCFs are superposed on a slowly varying negative magnetoconductance background. We also observe a sharp conductance maximum centered in B=0, which is reminescent of the spin-orbit induced anti-localisation phenomenon. The behavior of UCFs and of the conductance maximum is discussed as a function of the temperature, thickness and degree of cristallinity of the cavity.

  6. Synthesis of element 113 in the reaction 209Bi(70Zn, n)278113

    International Nuclear Information System (INIS)

    The convincing candidate event of the isotope of the 113th element, were observed, for the first time, in the 209Bi+70Zn reaction at a beam energy of 349.0 MeV with a total dose of 1.7 x 1019. Alpha decay energies and decay times of the candidates, 278113, 274111, and 270Mt, were (11.68±0.04 MeV, 0.344 ms), (11.15±0.07 MeV, 9.26 ms), and (10.03±0.07 MeV, 7.16 ms), respectively. The production cross section of the isotope was deduced to be 55-45+150 fb(10-39 cm2). The experiment was performed at RIIKEN (The Institute of Physical and Chemical Research) Linear Accelerator (RILAC) Facility. The evaporation residues produced by the reaction with a 70Zn beam provided by the RILAC and the bismuth targets, were separated by a gas-filled recoil separator (GARIS) from the beam particles and the target recoils, and collected at the focus of GARIS. We observed an event of implantation of an evaporation residue in the position-sensitive semiconductor detector followed by four consecutive alpha decays terminated by a spontaneous fission decay. Assignment of the event was based on genetic correlation of sequential alpha decays to the already known nuclides 266Bh and 262Db. The fourth alpha decay and the following spontaneous fission decay were assigned to be the decays of 266Bh and 262Db, respectively because of agreements of decay energies and decay times with the reported values. As a consequence, the preceding three alpha decays were assigned to be ones of 278113, 274111, and 270Mt.

  7. Characteristics of polonium contamination from neutral irradiated lead-bismuth eutectic

    International Nuclear Information System (INIS)

    After neutron capture, bismuth-209 changes to polonium-210 that emits α-particles. Lead-Bismuth eutectic (LBE) in reactor system contaminates the system by polonium. We analyzed adsorbed materials from melted LBE on quartz glass plate. Lead, bismuth and their oxides were confirmed in adsorbed materials. And, we evaluated the baking method in vacuum for removal of polonium and adsorbed materials on quartz glass plate. It was evaluated that it is possible to remove almost all the polonium from the quartz glass plate by baking at temperature more than 300 C. degrees. Unfolding method was applied to calculate polonium distribution in LBE ingot. From measured α-particle pulse height distribution, the polonium distribution in depth of LBE ingot was calculated using quadratic programming code, where response functions are calculated by Monte Carlo method. (authors)

  8. Energetics of bismuth vanadate

    Energy Technology Data Exchange (ETDEWEB)

    Nagabhushana, G.P.; Tavakoli, A.H.; Navrotsky, A., E-mail: anavrotsky@ucdavis.edu

    2015-05-15

    Bismuth vanadate has gained considerable interest as a photoanode for water splitting reactions under visible light. It exists in four different polymorphs, out of which three of them have been synthesized. Thermodynamic properties of these three polymorphs are investigated using high temperature oxide melt solution calorimetry. The monoclinic scheelite phase which exhibits photocatalytic activity under visible light is found to be the most stable polymorph, followed by tetragonal scheelite which exhibits activity under UV light. The photocatalytically inactive tetragonal zircon form is found to be the least stable polymorph. The small difference in enthalpy of formation between the two scheelite structures (−8 kJ/mol) is in accord with the reversibility of the transformation between them and the larger difference between the most stable monoclinic phase and the least stable tetragonal zircon phase (−23 kJ/mol) is in accord with the irreversible (monoclinic→tetragonal zircon) phase transformation. - Graphical abstract: Schematic representation of polymorphic transitions in BiVO{sub 4} along with their formation enthalpies. - Highlights: • Bismuth vanadate crystallizes in three different polymorphs. • High temperature calorimetric measurements were made to determine their formation enthalpies. • Enthalpy of formation decreases in the order BV-ms→BV-ts→BV-tz. • Photocatalytically active monoclinic-BiVO{sub 4} was found to be the most stable polymorph.

  9. An Unusual Bismuth Ethanedisulfonate Network

    Directory of Open Access Journals (Sweden)

    Fabienne Gschwind

    2012-09-01

    Full Text Available The three dimensional bismuth ethanedisulfonate framework Bi(O3SC2H4SO31.5(H2O2 was synthesized under hydrothermal conditions using the bidentate ligand 1,2-ethanedisulfonate and then characterized through X-ray diffraction and elemental analyses. The bismuth cation coordinates at three different ethanedisulfonate ligands and has a coordination number of eight, which is accompanied by a distorted square antiprismatic configuration. Here, we report on the crystal structure of this bismuth metal–organic framework and its coordination behavior, which has thus far not been reported in heavier main group elements.

  10. A Comparison of Modifications Induced by Li3+ and Ag14+ Ion Beam in Spectroscopic Properties of Bismuth Alumino-Borosilicate Glass Thin Films

    Directory of Open Access Journals (Sweden)

    Ravneet Kaur

    2013-01-01

    Full Text Available Ion irradiation effects on the glass network and structural units have been studied by irradiating borosilicate glass thin film samples with 50 MeV Li3+ and 180 MeV Ag14+ swift heavy ions (SHI at different fluence rates ranging from 1012 ions/cm2 to 1014 ions/cm2. Glass of the composition (65-x Bi2O3-10Al2O3-(65-y B2O3-25SiO2 (x = 45, 40; y = 20, 25 has been prepared by melt quench technique. To study the effects of ionizing radiation, the glass thin films have been prepared from these glasses and characterized using XRD, FTIR, and UV-Vis spectroscopic techniques. IR spectra are used to study the structural arrangements in the glass before and after irradiation. The values of optical band gap, Urbach energy, and refractive index have been calculated from the UV-Vis measurements. The variation in optical parameters with increasing Bi2O3 content has been analyzed and discussed in terms of changes occurring in the glass network. A comparative study of the influence of Li3+ ion beam on structural and optical properties of the either glass system with Ag14+ ion is done. The results have been explained in the light of the interaction that SHI undergo on entering the material.

  11. Polonium problem in lead-bismuth flow target

    Energy Technology Data Exchange (ETDEWEB)

    Pankratov, D.V.; Yefimov, E.I.; Bugreev, M.I. [State Scientific Centre of Russian Federation-Institute of Physics and Power Engineering, Obninsk (Russian Federation)

    1996-06-01

    Alpha-active polonium nuclides Po198 - Po210 are formed in a lead-bismuth target as results of reactions Bi{sup 209}(n,{gamma})Bi{sup 210} {yields} Po{sup 210}, Bi{sup 209}(p,xn)Po{sup 210} {yields} Po{sup 210 {minus} x} (x = 1-12), Pb{sup 208}({alpha},xn) {yields} Po{sup 210 {minus} x + 2} (x = 2-14). The most important nuclides are Po-210 (T{sub {1/2}}=138.4 day), Po-209 (T{sub {1/2}}=102 years) and Po-208 (T{sub {1/2}}=2.9 years). Polonium activity of the circuit for SINQ - conditions is about 15,000 Ci after 1-year operation. Polonium radiation hazard is connected with its output from the coolant and formation of aerosol and surface alpha-activity after the circuit break-down for repair works or in accidents. One of the important issues of polonium removal system creation is containing and storing polonium removed. Its storage in solidified alkaline is not expedient because of secondary neutron formation as a result of ({alpha},n) - reaction on oxygen and sodium nucleus. The estimations carried out demonstrated that by polonium concentration {approx} 100 Ci/l neutron current on the container surface can reach {approx} 10{sup 4}n/(cm{sup 2}s). Concentration and storage of polonium in solidified lead-bisumth seems the most convenient. The calculations demonstrated that in a 100 l container 50,000 Ci of polonium can be stored (as much as 3 times more than 1-year polonium product in SINQ-conditions) under temperature in the container less than melting point of lead bismuth (the wall temperature is about 100{degrees}C).

  12. Dose reduction using Bismuth protectors in chest computed tomography

    International Nuclear Information System (INIS)

    This monography is about the Dose reduction using Bismuth protectors in chest CT. The radiation protection of specific areas is necessary when the tissues or radiosensitive organs are near the path of light beam. The correct use of protection represents a challenge for the radiologist because of the time and materials required. The method used was a prospective investigatio in CHPR (TC service) and the doses was measured with TLD dosimeters. It is important to use these protectors in children hospitals.

  13. Superconducting transition temperature of metastable, crystalline lead-bismuth alloys

    International Nuclear Information System (INIS)

    The increase of the superconducting temperature by ion implantation with bismuth-ions in a saturated lead-bismuth alloy, by recoil-implantation and by quenching of a lead-bismuth alloy with bismuth precipitates was studied. At room-temperature an increase of 11 at% Bi over the thermodynamic solution limit in a lead-bismuth alloy could be measured. The highest superconducting temperature was 9.02 K for a lead-bismuth alloy with 43 at% bismuth. (orig.)

  14. New measurement of neutron capture resonances of 209Bi

    CERN Document Server

    Domingo-Pardo, C; Abbondanno, U; Aerts, G; Alvarez-Pol, H; Alvarez-Velarde, F; Andriamonje, Samuel A; Andrzejewski, J; Assimakopoulos, Panayiotis; Audouin, L; Badurek, G; Baumann, P; Becvar, F; Berthoumieux, E; Calviño, F; Cano-Ott, D; Capote, R; Carrillode Albornoz, A; Cennini, P; Chepel, V; Chiaveri, Enrico; Colonna, N; Cortés, G; Couture, A; Cox, J; Dahlfors, M; David, S; Dillman, I; Dolfini, R; Dridi, W; Durán, I; Eleftheriadis, C; Embid-Segura, M; Ferrant, L; Ferrari, A; Ferreira-Marques, R; Fitzpatrick, L; Frais-Kölbl, H; Fujii, K; Furman, W; Gallino, R; Gonçalves, I; Gonzalez-Romero, E; Goverdovski, A; Gramegna, F; Griesmayer, E; Guerrero, C; Gunsing, F; Haas, B; Haight, R; Heil, M; Herrera-Martínez, A; Igashira, M; Isaev, S; Jericha, E; Kadi, Y; Kappeler, F; Karamanis, D; Karadimos, D; Kerveno, M; Ketlerov, V; Köhler, P; Konovalov, V; Kossionides, E; Krticka, M; Lamboudis, C; Leeb, H; Lindote, A; Lopes, I; Lozano, M; Lukic, S; Marganiec, J; Marques, L; Marrone, S; Mastinu, P; Mengoni, A; Milazzo, P M; Moreau, C; Mosconi, M; Neves, F; Oberhummer, Heinz; Oshima, M; O'Brien, S; Pancin, J; Papachristodoulou, C; Papadopoulos, C; Paradela, C; Patronis, N; Pavlik, A; Pavlopoulos, P; Perrot, L; Plag, R; Plompen, A; Plukis, A; Poch, A; Pretel, C; Quesada, J; Rauscher, T; Reifarth, R; Rosetti, M; Rubbia, Carlo; Rudolf, G; Rullhusen, P; Salgado, J; Sarchiapone, L; Savvidis, I; Stéphan, C; Tagliente, G; Taín, J L; Tassan-Got, L; Tavora, L; Terlizzi, R; Vannini, G; Vaz, P; Ventura, A; Villamarín, D; Vincente, M C; Vlachoudis, V; Vlastou, R; Voss, F; Walter, S; Wendler, H; Wiescher, M; Wisshak, K

    2006-01-01

    The neutron capture cross section of Bi209 has been measured at the CERN n TOF facility by employing the pulse-height-weighting technique. Improvements over previous measurements are mainly because of an optimized detection system, which led to a practically negligible neutron sensitivity. Additional experimental sources of systematic error, such as the electronic threshold in the detectors, summing of gamma-rays, internal electron conversion, and the isomeric state in bismuth, have been taken into account. Gamma-ray absorption effects inside the sample have been corrected by employing a nonpolynomial weighting function. Because Bi209 is the last stable isotope in the reaction path of the stellar s-process, the Maxwellian averaged capture cross section is important for the recycling of the reaction flow by alpha-decays. In the relevant stellar range of thermal energies between kT=5 and 8 keV our new capture rate is about 16% higher than the presently accepted value used for nucleosynthesis calculations. At th...

  15. Bismuth bronze from machu picchu, peru.

    Science.gov (United States)

    Gordon, R B; Rutledge, J W

    1984-02-10

    The decorative bronze handle of a tumi excavated at the Inca city of Machu Picchu, Peru, contains 18 percent bismuth and appears to be the first known example of the use of bismuth with tin to make bronze. The alloy is not embrittled by the bismuth because the bismuth-rich constituent does not penetrate the grain boundaries of the matrix phase. The use of bismuth facilitates the duplex casting process by which the tumi was made and forms an alloy of unusual color. PMID:17749940

  16. 48 CFR 209.104 - Standards.

    Science.gov (United States)

    2010-10-01

    ... 48 Federal Acquisition Regulations System 3 2010-10-01 2010-10-01 false Standards. 209.104 Section 209.104 Federal Acquisition Regulations System DEFENSE ACQUISITION REGULATIONS SYSTEM, DEPARTMENT OF... Standards....

  17. A sensitive fluorescence quenching method for determination of bismuth with tiron

    International Nuclear Information System (INIS)

    We describe a fluorescence quenching method for determination of bismuth with tiron. The method is based on the reaction of tiron by bismuth(III) in acidic media. The influence of variables such as the pH, type of buffer, tiron concentration, reaction time and temperature were investigated. Under optimized conditions, the fluorescence quenching extent is proportional to the concentration of bismuth for Bi–tiron system at the range 0.13–2.09 μg mL−1 and the detection limit is 0.05 μg mL−1. The proposed sensor presented good repeatability, evaluated in terms of relative standard deviation (R.S.D.=±0.498%) for 11 replicates. This sensitive, rapid and accurate method has been successfully applied to the determination of trace bismuth(III) in water and hair samples and certified reference materials. -- Highlights: • No previous paper report on use of fluorescence quenching for determination of Bi. • Fluorescence quenching of trion is a sensitive method for determination of Bi(III). • Under the optimum conditions the detection limit is very low (0.05 μg mL−1). • The procedure is simple and safe and has high tolerance limit to interferences

  18. 40 CFR 209.12 - Time.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 24 2010-07-01 2010-07-01 false Time. 209.12 Section 209.12 Protection... Issued Under Section 11(d) of the Noise Control Act § 209.12 Time. (a) In computing any period of time... period of time begins to run shall not be included, except as otherwise provided. Saturdays, Sundays,...

  19. 40 CFR 240.209-1 - Requirement.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 24 2010-07-01 2010-07-01 false Requirement. 240.209-1 Section 240.209-1 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES GUIDELINES FOR THE THERMAL PROCESSING OF SOLID WASTES Requirements and Recommended Procedures § 240.209-1...

  20. 49 CFR 209.5 - Service.

    Science.gov (United States)

    2010-10-01

    ... 49 Transportation 4 2010-10-01 2010-10-01 false Service. 209.5 Section 209.5 Transportation Other... TRANSPORTATION RAILROAD SAFETY ENFORCEMENT PROCEDURES General § 209.5 Service. (a) Each order, notice, or other... mail, except as otherwise provided herein. (b) Service upon a person's duly authorized...

  1. 22 CFR 209.4 - Discrimination prohibited.

    Science.gov (United States)

    2010-04-01

    ... 22 Foreign Relations 1 2010-04-01 2010-04-01 false Discrimination prohibited. 209.4 Section 209.4 Foreign Relations AGENCY FOR INTERNATIONAL DEVELOPMENT NON-DISCRIMINATION IN FEDERALLY-ASSISTED PROGRAMS... § 209.4 Discrimination prohibited. (a) General. No person in the United States shall, on the grounds...

  2. 7 CFR 20.9 - Records.

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 1 2010-01-01 2010-01-01 false Records. 20.9 Section 20.9 Agriculture Office of the Secretary of Agriculture EXPORT SALES REPORTING REQUIREMENTS § 20.9 Records. Each reporting exporter shall... authorized employees of the United States Department of Agriculture and shall be preserved for three...

  3. 40 CFR 240.209 - Safety.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 24 2010-07-01 2010-07-01 false Safety. 240.209 Section 240.209 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES GUIDELINES FOR THE THERMAL PROCESSING OF SOLID WASTES Requirements and Recommended Procedures § 240.209 Safety....

  4. 46 CFR 108.209 - Hospital spaces.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 4 2010-10-01 2010-10-01 false Hospital spaces. 108.209 Section 108.209 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) A-MOBILE OFFSHORE DRILLING UNITS DESIGN AND EQUIPMENT Construction and Arrangement Accommodation Spaces § 108.209 Hospital spaces. (a) Each unit carrying twelve...

  5. 33 CFR 117.209 - Mianus River.

    Science.gov (United States)

    2010-07-01

    ... 33 Navigation and Navigable Waters 1 2010-07-01 2010-07-01 false Mianus River. 117.209 Section 117.209 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY BRIDGES DRAWBRIDGE OPERATION REGULATIONS Specific Requirements Connecticut § 117.209 Mianus River. The draw of the...

  6. 7 CFR 868.209 - Information.

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 7 2010-01-01 2010-01-01 false Information. 868.209 Section 868.209 Agriculture... Application of Standards § 868.209 Information. Requests for the Rice Inspection Handbook, Equipment Handbook, or for information concerning approved devices and procedures, criteria for approved devices,...

  7. 22 CFR 209.6 - Compliance information.

    Science.gov (United States)

    2010-04-01

    ... 22 Foreign Relations 1 2010-04-01 2010-04-01 false Compliance information. 209.6 Section 209.6... § 209.6 Compliance information. (a) Cooperation and assistance. The Administrator shall to the fullest... and accurate compliance reports at such times, and in such form and containing such information,...

  8. 40 CFR 20.9 - Cost recovery.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 1 2010-07-01 2010-07-01 false Cost recovery. 20.9 Section 20.9 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY GENERAL CERTIFICATION OF FACILITIES § 20.9 Cost... (a)(6) of 26 CFR 1.169-2, the Regional Administrator shall so signify in the notice of...

  9. 42 CFR 59.209 - Civil rights.

    Science.gov (United States)

    2010-10-01

    ... issued by the Secretary of Health and Human Services with the approval of the President (45 CFR part 80). ... 42 Public Health 1 2010-10-01 2010-10-01 false Civil rights. 59.209 Section 59.209 Public Health... Grants for Family Planning Service Training § 59.209 Civil rights. Attention is called to...

  10. 14 CFR 91.209 - Aircraft lights.

    Science.gov (United States)

    2010-01-01

    ... 14 Aeronautics and Space 2 2010-01-01 2010-01-01 false Aircraft lights. 91.209 Section 91.209... Requirements § 91.209 Aircraft lights. No person may: (a) During the period from sunset to sunrise (or, in... or the sun is more than 6 degrees below the horizon)— (1) Operate an aircraft unless it has...

  11. 40 CFR 209.26 - Evidence.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 24 2010-07-01 2010-07-01 false Evidence. 209.26 Section 209.26... Orders Issued Under Section 11(d) of the Noise Control Act § 209.26 Evidence. (a) The official... record. Evidence may be received at the hearing even though inadmissible under the rules of...

  12. Comparative Study of Semiconductors Bismuth Iodate, Bismuth Triiodide and Bismuth Trisulphide Crystals

    Directory of Open Access Journals (Sweden)

    T.K. Patil

    2012-12-01

    Full Text Available In the present investigation, crystals of Bismuth Iodate[Bi(IO33], Bismuth Iodide[BiI3] and Bismuth- Tri Sulphide [Bi2S3] were grown by a simple gel technique using single diffusion method. The optimum growth conditions were established by varying various parameters such as pH of gel solution, gel concentration, gel setting time, concentration of reactant etc. Gel was prepared by mixing sodium meta silicate (Na2SiO35H2O, glacial acetic acid (CH3COOH and supernant bismuth chloride (BiCl3 at pH value 4.4 and transferred in glass tube of diameter 2.5 cm and 25 cm in length. The mouth of test tube was covered by cotton plug and kept it for the setting. After setting the gel, it was left for aging. After 13 days duration the second supernant K(IO3, KI3 and H2S water gas solution was poured over the set gel by using pipette then it was kept undisturbed. After 72 hours of pouring the second supernatant, the small nucleation growth was observed at below the interface of gel. The good quality crystals of [Bi(IO33], [BiI3] and [Bi2S3] were grown. These grown crystals were characterized by XRD, FTIR, Chemical Analysis and Electrical Conductivity.

  13. Feasibility study on polonium-209 as radioisotope fuel for space nuclear power

    International Nuclear Information System (INIS)

    We have investigated the performance and the production method of alternative isotopes of 238Pu as a radioisotope fuel for use in space radioisotope power generators. Polonium-209 has the possibility to be an alternative material of 238Pu. It has enough half-time of 102 years and the specific power of 490 W/kg. From the simulation, the beam current of 14 A with 40 MeV proton energy provides 1 kg/yr of 209Po annually. (author)

  14. Authorization basis for the 209-E Building

    International Nuclear Information System (INIS)

    This Authorization Basis document is one of three documents that constitute the Authorization Basis for the 209-E Building. Per the U.S. Department of Energy, Richland Operations Office (RL) letter 98-WSD-074, this document, the 209-E Building Preliminary Hazards Analysis (WHC-SD-WM-TI-789), and the 209-E Building Safety Evaluation Report (97-WSD-074) constitute the Authorization Basis for the 209-E Building. This Authorization Basis and the associated controls and safety programs will remain in place until safety documentation addressing deactivation of the 209-E Building is developed by the contractor and approved by RL

  15. Bismuth absorption from 205 Bi-labelled pharmaceutical bismuth compounds used in the treatment of peptic ulcer disease

    International Nuclear Information System (INIS)

    The absorption of bismuth from five 205Bi-labelled pharmaceutically used bismuth compounds was studied in man. From single oral doses of all compounds under investigation only <0.1% bismuth was absorbed and excreted with the urine. A significantly higher absorption was observed from the colloidal bismuth subcitrate and the basic bismuth gallate than from the basic bismuth salicylate, nitrate and aluminate. No retention of bismuth in the whole body was found from the single dose experiment. The biologic fast-term half-lives of absorbed bismuth were calculated to be 0.12 and 1.5 days. 14 refs., 2 figs., 1 tab

  16. Bismuth absorption from sup 205 Bi-labelled pharmaceutical bismuth compounds used in the treatment of peptic ulcer disease

    Energy Technology Data Exchange (ETDEWEB)

    Dresow, B.; Fischer, R.; Gabbe, E.E.; Wendel, J.; Heinrich, H.C. (Eppendorf University Hospital, Hamburg (Germany))

    1992-04-01

    The absorption of bismuth from five {sup 205}Bi-labelled pharmaceutically used bismuth compounds was studied in man. From single oral doses of all compounds under investigation only <0.1% bismuth was absorbed and excreted with the urine. A significantly higher absorption was observed from the colloidal bismuth subcitrate and the basic bismuth gallate than from the basic bismuth salicylate, nitrate and aluminate. No retention of bismuth in the whole body was found from the single dose experiment. The biologic fast-term half-lives of absorbed bismuth were calculated to be 0.12 and 1.5 days. 14 refs., 2 figs., 1 tab.

  17. Wet-chemistry method for the separation of no-carrier-added 211At/211gPo from 209Bi target irradiated by alpha-beam in cyclotron

    International Nuclear Information System (INIS)

    We present a fast and effective wet-chemistry method, used to obtain the pure alpha-emitter 211At/211gPo (T1/2 = 7.214 h/516 ms), produced by 209Bi(α,2n) reaction in NCA form. It is a selective radiochemical separation of the At radionuclides from the target and the impurities, characterized by a radionuclidic purity close to 100%, based on the dissolution and the dilution of the irradiated target in acidic medium, on the extraction with DIPE, followed by the back-extraction with NaOH. As a result, we obtain a yield greater than 90-97% in a range from 0.75M to 2.00M. (author)

  18. Gamma-ray attenuation coefficients in bismuth borate glasses

    International Nuclear Information System (INIS)

    Mass attenuation coefficients of glasses in the system: xBi2O3(1-x)B2O3 (x=0.30, 0.35, 0.40, 0.45 and 0.55) were determined at 356, 662, 1173 and 1332 keV photon energies using a narrow beam transmission method. Appreciable variations were observed in these coefficients due to changes in the chemical composition of glasses. These coefficients were then used to determine effective atomic numbers of glass samples, which were found to be constant with bismuth concentration and energy

  19. 31 CFR 800.209 - Critical technologies.

    Science.gov (United States)

    2010-07-01

    ... 31 Money and Finance: Treasury 3 2010-07-01 2010-07-01 false Critical technologies. 800.209..., AND TAKEOVERS BY FOREIGN PERSONS Definitions § 800.209 Critical technologies. The term critical technologies means: (a) Defense articles or defense services covered by the United States Munitions List...

  20. 24 CFR 941.209 - Audit.

    Science.gov (United States)

    2010-04-01

    ... HOUSING DEVELOPMENT PHA Eligibility and Program Requirements § 941.209 Audit. All PHAs that receive funds under this part for the development of low-income housing shall comply with audit requirements in 24 CFR... 24 Housing and Urban Development 4 2010-04-01 2010-04-01 false Audit. 941.209 Section...

  1. 44 CFR 209.2 - Definitions.

    Science.gov (United States)

    2010-10-01

    ... project, in accordance with FEMA guidance and using a FEMA-approved methodology. FEMA will review the... 44 Emergency Management and Assistance 1 2010-10-01 2010-10-01 false Definitions. 209.2 Section 209.2 Emergency Management and Assistance FEDERAL EMERGENCY MANAGEMENT AGENCY, DEPARTMENT OF...

  2. Bismuth ions are metabolized into autometallographic traceable bismuth-sulphur quantum dots

    Directory of Open Access Journals (Sweden)

    M Stoltenberg

    2009-06-01

    Full Text Available Bismuth – sulphur quantum dots can be silver enhanced by autometallography (AMG. In the present study, autometallographic silver enhanced bismuth-sulphur nanocrystals were isolated from unfixed cryo-sections of kidneys and livers of rats exposed to bismuth (Bi207 subnitrate. After being subjected to AMG all the organic material was removed by sonication and enzymatic digestion and the silver enhanced Bi- S quantum dots spun down by an ultracentrifuge and analyzed by scintillation. The analysis showed that the autometallographic technique traces approximately 94% of the total bismuth. This implies that the injected bismuth is ultimately captured in bismuthsulphur quantum dots, i.e., that Bi-S nanocrystals are the end product of bismuth metabolism

  3. Extraction and separation of bismuth(III).

    Science.gov (United States)

    Langade, A D; Shinde, V M

    1981-10-01

    Separation of bismuth from beryllium, lead, iron(III), indium, scandium, lanthanum, antimony(III), zirconium, titanium, thorium, vanadium(V), molybdenum(VI), uranium (VI) and chromium(VI) is achieved by selective extraction of bismuth from 0.1M sodium salicylate solution (adjusted to pH 7) into mesityl oxide (MeO). The extracted species is Bi (HOC(6)H(4)COO)(3).3MeO. The results are accurate within +/- 0.5%, with a standard deviation of 0.8%. The separation and determination of bismuth takes only 15 min. PMID:18963000

  4. Gravimetric Analysis of Bismuth in Bismuth Subsalicylate Tablets: A Versatile Quantitative Experiment for Undergraduate Laboratories

    Science.gov (United States)

    Davis, Eric; Cheung, Ken; Pauls, Steve; Dick, Jonathan; Roth, Elijah; Zalewski, Nicole; Veldhuizen, Christopher; Coeler, Joel

    2015-01-01

    In this laboratory experiment, lower- and upper-division students dissolved bismuth subsalicylate tablets in acid and precipitated the resultant Bi[superscript 3+] in solution with sodium phosphate for a gravimetric determination of bismuth subsalicylate in the tablets. With a labeled concentration of 262 mg/tablet, the combined data from three…

  5. Thermal degradation of ultrabroad bismuth NIR luminescence in bismuth-doped tantalum germanate laser glasses.

    Science.gov (United States)

    Wang, Liping; Zhao, Yanqi; Xu, Shanhui; Peng, Mingying

    2016-04-01

    Because of ultra-broadband luminescence in 1000-1700 nm and consequent applications in fiber amplifier and lasers in the new spectral range where traditional rare earth cannot work, bismuth-doped laser glasses have received rising interest recently. For long-term practical application, thermal degradation must be considered for the glasses. This, however, has seldom been investigated. Here we report the thermal degradation of bismuth-doped germanate glass. Heating and cooling cycle experiments at high temperature reveal strong dependence of the thermal degradation on glass compositions. Bismuth and tantalum lead to the reversible degradation, while lithium can produce permanent irreversible degradation. The degradation becomes worse as lithium content increases in the glass. Absorption spectra show this is due to partial oxidation of bismuth near-infrared emission center. Surprisingly, we notice the emission of bismuth exhibits blueshift, rather than redshift at a higher temperature, and the blueshift can be suppressed by increasing the lithium content. PMID:27192231

  6. Hydrothermal synthesis map of bismuth titanates

    International Nuclear Information System (INIS)

    The hydrothermal synthesis of four bismuth titanate materials from common bismuth and titanium precursors under hydrothermal conditions is described. Reaction of NaBiO3·2H2O and anatase TiO2 in concentrated NaOH solution at 240 °C is shown to produce perovskite and sillenite phases Na0.5Bi0.5TiO3 and Bi12TiO20, depending on the ratio of metal precursors used. When KOH solution is used and a 1:1 ratio of the same precursors, a pyrochlore Bi1.43Ti2O6(OH)0.29(H2O)0.66 is formed. The use of a mixture of HNO3 and NaOH is shown to facilitate the formation of the Aurivillius-type bismuth titanate Bi4Ti3O12. The phases have been isolated separately as phase-pure powders and profile refinement of powder X-ray diffraction data allows comparisons with comparable materials reported in the literature. Analysis of Bi LIII-edge X-ray absorption near edge structure (XANES) spectra of the materials shows the oxidation state of bismuth is +3 in all of the hydrothermally derived products. - Graphical abstract: Use of NaBiO3·2H2O and TiO2 as reagents under hydrothermal conditions allows the phase-pure preparation of four crystalline bismuth titanate materials. Highlights: ► NaBiO3 and TiO2 under hydrothermal conditions allow formation of bismuth titanates. ► Synthesis of four distint phases has been mapped. ► Bi LIII-edge XANES shows Bi is reduced to oxidation state +3 in all materials. ► A new hydrated bismuth titanate pyrochlore has been isolated

  7. Thermal-hydraulics of lead bismuth for accelerator driven systems

    International Nuclear Information System (INIS)

    Full text of publication follows: Lead bismuth has been selected as one of the most suitable coolants to be used in accelerator driven systems (ADS) for transmutation of minor actinides. It serves both, as a target material of the spallation source to balance the neutron economy, and as a coolant with high thermal inertia to provide a safe and reliable heat transfer to the secondary power cycle. With the aim to develop the required technologies to enable the later design of such ADS systems, the Karlsruhe Lead bismuth LAboratory KALLA, consisting of three test loops, has been built and set into operation at the Forschungszentrum Karlsruhe since 2000, keeping more than 45 t of PbBi in operation at temperatures up to 550 deg. C. The test program includes oxygen control systems, heat flux simulation tools, electro-magnetic and mechanical pump technologies, heat transfer and flow measurements, reliability and corrosion tests. In a first test campaign, a technology loop called THESYS was built to develop measurement technologies for the acquisition of scalar quantities, like pressures, temperatures, concentrations, and flow rates, as well as velocity fields, which are required for both operational and scientific purposes. THESYS also allowed to perform generic turbulent heat transfer experiments necessary to provide liquid metal adapted turbulent heat transfer models for ADS design analyses. The second loop, the thermalhydraulic loop THEADES with an installed power of 2.5 MW, has been built to conduct prototypical component experiments for beam windows (e.g. MEGAPIE or MYHRRA) or fuel rod configurations. First test results will be reported. The experimental team is supported by a numerical team who studied the thermal hydraulics of the tested components in order to enable a later transfer of the results to industrial systems. Three different types of codes are being improved: lumped parameter codes (e.g. ATHLET) to perform system analyses for lead bismuth in loops

  8. Adaptive statistical iterative reconstruction and bismuth shielding for evaluation of dose reduction to the eye and image quality during head CT

    International Nuclear Information System (INIS)

    There is a concern regarding the adverse effects of increasing radiation doses due to repeated computed tomography (CT) scans, especially in radiosensitive organs and portions thereof, such as the lenses of the eyes. Bismuth shielding with an adaptive statistical iterative reconstruction (ASIR) algorithm was recently introduced in our clinic as a method to reduce the absorbed radiation dose. This technique was applied to the lens of the eye during CT scans. The purpose of this study was to evaluate the reduction in the absorbed radiation dose and to determine the noise level when using bismuth shielding and the ASIR algorithm with the GE DC 750 HD 64-channel CT scanner for CT of the head of a humanoid phantom. With the use of bismuth shielding, the noise level was higher in the beam-hardening artifact areas than in the revealed artifact areas. However, with the use of ASIR, the noise level was lower than that with the use of bismuth alone; it was also lower in the artifact areas. The reduction in the radiation dose with the use of bismuth was greatest at the surface of the phantom to a limited depth. In conclusion, it is possible to reduce the radiation level and slightly decrease the bismuth-induced noise level by using a combination of ASIR as an algorithm process and bismuth as an in-plane hardware-type shielding method.

  9. Metabolism of Bismuth Subsalicylate and Intracellular Accumulation of Bismuth by Fusarium sp. Strain BI

    OpenAIRE

    Dodge, Anthony G.; Wackett, Lawrence P

    2005-01-01

    Enrichment cultures were conducted using bismuth subsalicylate as the sole source of carbon and activated sludge as the inoculum. A pure culture was obtained and identified as a Fusarium sp. based on spore morphology and partial sequences of 18S rRNA, translation elongation factor 1-α, and β-tubulin genes. The isolate, named Fusarium sp. strain BI, grew to equivalent densities when using salicylate or bismuth subsalicylate as carbon sources. Bismuth nitrate at concentrations of up to 200 μM d...

  10. Electrodeposition and Characterization of Bismuth Telluride Nanowires

    Science.gov (United States)

    Frantz, C.; Stein, N.; Gravier, L.; Granville, S.; Boulanger, C.

    2010-09-01

    In this work, we report thermoelectric measurements on electroplated bismuth telluride nanowires. Porous polycarbonate membranes, obtained by ion-track irradiation lithography, were chosen as electroplating templates. Bismuth telluride nanowires were achieved in acidic media under potentiostatic conditions at -100 mV versus saturated silver chloride electrode. The filling ratio of the pores was increased to 80% by adding dimethyl sulfoxide to the electrolyte. Whatever the experimental conditions, the nanowires were polycrystalline in the rhombohedral phase of Bi2Te3. Finally, the power output of arrays of bismuth telluride nanowires was analyzed as a function of load resistance. The results were strongly dependent on the internal resistance, which can be significantly reduced by the presence of dimethyl sulfoxide during electroplating.

  11. Liquid Bismuth Feed System for Electric Propulsion

    Science.gov (United States)

    Markusic, T. E.; Polzin, K. A.; Stanojev, B. J.

    2006-01-01

    Operation of Hall thrusters with bismuth propellant has been shown to be a promising path toward high-power, high-performance, long-lifetime electric propulsion for spaceflight missions. For example, the VHITAL project aims td accurately, experimentally assess the performance characteristics of 10 kW-class bismuth-fed Hall thrusters - in order to validate earlier results and resuscitate a promising technology that has been relatively dormant for about two decades. A critical element of these tests will be the precise metering of propellant to the thruster, since performance cannot be accurately assessed without an accurate accounting of mass flow rate. Earlier work used a pre/post-test propellant weighing scheme that did not provide any real-time measurement of mass flow rate while the thruster was firing, and makes subsequent performance calculations difficult. The motivation of the present work was to develop a precision liquid bismuth Propellant Management System (PMS) that provides real-time propellant mass flow rate measurement and control, enabling accurate thruster performance measurements. Additionally, our approach emphasizes the development of new liquid metal flow control components and, hence, will establish a basis for the future development of components for application in spaceflight. The design of various critical components in a bismuth PMS are described - reservoir, electromagnetic pump, hotspot flow sensor, and automated control system. Particular emphasis is given to material selection and high-temperature sealing techniques. Open loop calibration test results are reported, which validate the systems capability to deliver bismuth at mass flow rates ranging from 10 to 100 mg/sec with an uncertainty of less than +/- 5%. Results of integrated vaporizer/liquid PMS tests demonstrate all of the necessary elements of a complete bismuth feed system for electric propulsion.

  12. Burnout current density of bismuth nanowires

    Science.gov (United States)

    Cornelius, T. W.; Picht, O.; Müller, S.; Neumann, R.; Völklein, F.; Karim, S.; Duan, J. L.

    2008-05-01

    Single bismuth nanowires with diameters ranging from 100nmto1μm were electrochemically deposited in ion track-etched single-pore polycarbonate membranes. The maximum current density the wires are able to carry was investigated by ramping up the current until failure occurred. It increases by three to four orders of magnitude for nanowires embedded in the template compared to bulk bismuth and rises with diminishing diameter. Simulations show that the wires are heated up electrically to the melting temperature. Since the surface-to-volume ratio rises with diminishing diameter, thinner wires dissipate the heat more efficiently to the surrounding polymer matrix and, thus, can tolerate larger current densities.

  13. Holographic data storage in photorefractive bismuth tellurite

    International Nuclear Information System (INIS)

    Bismuth tellurite is a photorefractive material for holographic data storage offering unique fixing capabilities. Important material and electro-optic properties obtained by four-wave-mixing and data storage experiments are reviewed and recent results concerning the applicability of bismuth tellurite for holographic data storage, including dynamic range, multiplexing capabilities and bit-error evaluations, are presented. Furthermore, it is demonstrated how the latest progress in growing Bi2TeO5 made this crystal a candidate for durable holographic recording media.

  14. Structural studies of bismuth nanocrystals embedded in SiO2 or GeO2 matrices

    International Nuclear Information System (INIS)

    The layer of bismuth nanoclusters embedded in glass matrices and the surface layer of bismuth grains have been obtained by thermal treatment in hydrogen atmosphere of Bi0.33Ge0.67O1.84 and Bi0.57Si0.43O1.72 glass. The thickness and structure of such layers strongly depend on temperature and time of reduction. The structural studies of bismuth nanocrystals embedded in SiO2 or GeO2 matrices were performed with optical microscopy and atomic force microscopy. By the use of a slow-positron beam we monitored the structural changes undergoing in near-to-surface layers after the first steps of isothermal annealing. A simple two-layer model of reduced glasses explains the evolution of the surface layer and electrical properties of the material during the reduction process

  15. Electron microscopy of barium bismuth titanate multilayer ceramics

    International Nuclear Information System (INIS)

    For a number of years bismuth containing compounds have been used with pre-calcined barium titanate to reduce the sintering temperature of the capacitor formulations. As reported earlier the backscattered electron (BSE) SEM micrographs of the bismuth containing barium titanate ceramic reveal that the grains having an average size of 1.2μm consist of a two phase structure consisting of relatively pure barium titanate grain cores surrounded by bismuth rich grain shells. The TEM and STEM studies along with the EDS analyses show that the bismuth concentration increases sharply as one steps towards the grain boundary with a maximum bismuth content at the grain boundary. It is the purpose of this work to investigate the distribution of bismuth in these formulations including the bismuth content, if any, at the ceramic metal interface as affected by the sintering temperature. The subsequent effect on the electrical resistivity of these ceramics in the multilayer configuration is reported

  16. Metabolism of bismuth subsalicylate and intracellular accumulation of bismuth by Fusarium sp. strain BI.

    Science.gov (United States)

    Dodge, Anthony G; Wackett, Lawrence P

    2005-02-01

    Enrichment cultures were conducted using bismuth subsalicylate as the sole source of carbon and activated sludge as the inoculum. A pure culture was obtained and identified as a Fusarium sp. based on spore morphology and partial sequences of 18S rRNA, translation elongation factor 1-alpha, and beta-tubulin genes. The isolate, named Fusarium sp. strain BI, grew to equivalent densities when using salicylate or bismuth subsalicylate as carbon sources. Bismuth nitrate at concentrations of up to 200 muM did not limit growth of this organism on glucose. The concentration of soluble bismuth in suspensions of bismuth subsalicylate decreased during growth of Fusarium sp. strain BI. Transmission electron microscopy and energy-dispersive spectroscopy revealed that the accumulated bismuth was localized in phosphorus-rich granules distributed in the cytoplasm and vacuoles. Long-chain polyphosphates were extracted from fresh biomass grown on bismuth subsalicylate, and inductively coupled plasma optical emission spectrometry showed that these fractions also contained high concentrations of bismuth. Enzyme activity assays of crude extracts of Fusarium sp. strain BI showed that salicylate hydroxylase and catechol 1,2-dioxygenase were induced during growth on salicylate, indicating that this organism degrades salicylate by conversion of salicylate to catechol, followed by ortho cleavage of the aromatic ring. Catechol 2,3-dioxygenase activity was not detected. Fusarium sp. strain BI grew with several other aromatic acids as carbon sources: benzoate, 3-hydroxybenzoate, 4-hydroxybenzoate, gentisate, d-mandelate, l-phenylalanine, l-tyrosine, phenylacetate, 3-hydroxyphenylacetate, 4-hydroxyphenylacetate, and phenylpropionate. PMID:15691943

  17. Probing bismuth ferrite nanoparticles by hard x-ray photoemission: Anomalous occurrence of metallic bismuth

    International Nuclear Information System (INIS)

    We have investigated bismuth ferrite nanoparticles (∼75 nm and ∼155 nm) synthesized by a chemical method, using soft X-ray (1253.6 eV) and hard X-ray (3500, 5500, and 7500 eV) photoelectron spectroscopy. This provided an evidence for the variation of chemical state of bismuth in crystalline, phase pure nanoparticles. X-ray photoelectron spectroscopy analysis using Mg Kα (1253.6 eV) source showed that iron and bismuth were present in both Fe3+ and Bi3+ valence states as expected for bismuth ferrite. However, hard X-ray photoelectron spectroscopy analysis of the bismuth ferrite nanoparticles using variable photon energies unexpectedly showed the presence of Bi0 valence state below the surface region, indicating that bismuth ferrite nanoparticles are chemically inhomogeneous in the radial direction. Consistently, small-angle X-ray scattering reveals a core-shell structure for these radial inhomogeneous nanoparticles.

  18. Photosensitive bismuth ions in lead tungstate

    Czech Academy of Sciences Publication Activity Database

    Vazhenin, V.A.; Potapov, A.P.; Asatryan, G.R.; Nikl, Martin

    2013-01-01

    Roč. 55, č. 4 (2013), s. 803-806. ISSN 1063-7834 Institutional support: RVO:68378271 Keywords : PbWO 4 * single crystal * bismuth * electron paramagnetic resonance Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 0.782, year: 2013

  19. Hydrothermal synthesis map of bismuth titanates

    Science.gov (United States)

    Sardar, Kripasindhu; Walton, Richard I.

    2012-05-01

    The hydrothermal synthesis of four bismuth titanate materials from common bismuth and titanium precursors under hydrothermal conditions is described. Reaction of NaBiO3·2H2O and anatase TiO2 in concentrated NaOH solution at 240 °C is shown to produce perovskite and sillenite phases Na0.5Bi0.5TiO3 and Bi12TiO20, depending on the ratio of metal precursors used. When KOH solution is used and a 1:1 ratio of the same precursors, a pyrochlore Bi1.43Ti2O6(OH)0.29(H2O)0.66 is formed. The use of a mixture of HNO3 and NaOH is shown to facilitate the formation of the Aurivillius-type bismuth titanate Bi4Ti3O12. The phases have been isolated separately as phase-pure powders and profile refinement of powder X-ray diffraction data allows comparisons with comparable materials reported in the literature. Analysis of Bi LIII-edge X-ray absorption near edge structure (XANES) spectra of the materials shows the oxidation state of bismuth is +3 in all of the hydrothermally derived products.

  20. Bismuth titanate ceramics obtained by hot forging

    International Nuclear Information System (INIS)

    In this work, bismuth titanate samples were obtained from powder calcined at 800 deg C for 24 h through conventional sintering (OF) and hot-forging (HF) methods. The plate-like morphology grains were observed in ceramics obtained in both process. Samples produced by HF showed higher grain orientation, ≅ 90%. (author)

  1. Polyvinyl chloride filled with bismuth oxychloride powder

    Czech Academy of Sciences Publication Activity Database

    Polášková, M.; Sedláček, T.; Kharlamov, Alexander; Pivokonský, Radek; Saha, P.

    Larnaca : Polymer Processing Society, 2009, s. 242. [Polymer Processing Society Europe/Africa Regional Meeting. Larnaca (GR), 18.10.2009-21.10.2009] Institutional research plan: CEZ:AV0Z20600510 Keywords : olyvinyl chloride * bismuth oxychloride * radiopaque agents Subject RIV: BK - Fluid Dynamics

  2. Hydrothermal synthesis map of bismuth titanates

    Energy Technology Data Exchange (ETDEWEB)

    Sardar, Kripasindhu [Department of Chemistry, University of Warwick, Coventry, CV4 7AL (United Kingdom); Walton, Richard I., E-mail: r.i.walton@warwick.ac.uk [Department of Chemistry, University of Warwick, Coventry, CV4 7AL (United Kingdom)

    2012-05-15

    The hydrothermal synthesis of four bismuth titanate materials from common bismuth and titanium precursors under hydrothermal conditions is described. Reaction of NaBiO{sub 3}{center_dot}2H{sub 2}O and anatase TiO{sub 2} in concentrated NaOH solution at 240 Degree-Sign C is shown to produce perovskite and sillenite phases Na{sub 0.5}Bi{sub 0.5}TiO{sub 3} and Bi{sub 12}TiO{sub 20}, depending on the ratio of metal precursors used. When KOH solution is used and a 1:1 ratio of the same precursors, a pyrochlore Bi{sub 1.43}Ti{sub 2}O{sub 6}(OH){sub 0.29}(H{sub 2}O){sub 0.66} is formed. The use of a mixture of HNO{sub 3} and NaOH is shown to facilitate the formation of the Aurivillius-type bismuth titanate Bi{sub 4}Ti{sub 3}O{sub 12}. The phases have been isolated separately as phase-pure powders and profile refinement of powder X-ray diffraction data allows comparisons with comparable materials reported in the literature. Analysis of Bi L{sub III}-edge X-ray absorption near edge structure (XANES) spectra of the materials shows the oxidation state of bismuth is +3 in all of the hydrothermally derived products. - Graphical abstract: Use of NaBiO{sub 3}{center_dot}2H{sub 2}O and TiO{sub 2} as reagents under hydrothermal conditions allows the phase-pure preparation of four crystalline bismuth titanate materials. Highlights: Black-Right-Pointing-Pointer NaBiO{sub 3} and TiO{sub 2} under hydrothermal conditions allow formation of bismuth titanates. Black-Right-Pointing-Pointer Synthesis of four distint phases has been mapped. Black-Right-Pointing-Pointer Bi LIII-edge XANES shows Bi is reduced to oxidation state +3 in all materials. Black-Right-Pointing-Pointer A new hydrated bismuth titanate pyrochlore has been isolated.

  3. 14 CFR 67.209 - Neurologic.

    Science.gov (United States)

    2010-01-01

    ... Aeronautics and Space FEDERAL AVIATION ADMINISTRATION, DEPARTMENT OF TRANSPORTATION (CONTINUED) AIRMEN MEDICAL STANDARDS AND CERTIFICATION Second-Class Airman Medical Certificate § 67.209 Neurologic. Neurologic standards for a second-class airman medical certificate are: (a) No established medical history or...

  4. 48 CFR 209.270-4 - Procedures.

    Science.gov (United States)

    2010-10-01

    ... designation as aviation or ship critical safety items. See additional information at PGI 209.270-4; (2... activity; and (3) Qualify and identify aviation and ship critical safety item suppliers and products. (b... that a prospective contractor or its product meets or can meet the established qualification...

  5. 47 CFR 53.209 - Biennial audit.

    Science.gov (United States)

    2010-10-01

    ... necessary to ensure compliance with the audit requirements listed in paragraph (b) of this section. If the... independent auditor to take any actions necessary to ensure compliance with the audit requirements in... 47 Telecommunication 3 2010-10-01 2010-10-01 false Biennial audit. 53.209 Section...

  6. Gamma-ray shielding and structural properties of barium-bismuth-borosilicate glasses

    Science.gov (United States)

    Bootjomchai, Cherdsak; Laopaiboon, Jintana; Yenchai, Chadet; Laopaiboon, Raewat

    2012-07-01

    The attenuation coefficients of barium-bismuth-borosilicate glasses have been measured for gamma-ray photon energies of 662, 1173 and 1332 keV using a narrow beam transmission geometry. These coefficients were then used to obtain the values of mass attenuation coefficients, effective atomic number, effective electron density and mean free path. Good agreement has been observed between experimental and theoretical values of these parameters. From the obtained results it is reported here that from the barium-bismuth-borosilicate glasses are better shields to gamma-radiations in comparison to the standard radiation shielding concretes from the shielding point of view. The molar volume, FTIR and acoustic investigations have been used to study the structural properties of the prepared glass system. The obtained results reveal that the formation of non-bridging oxygens occurs at higher concentration of Bi2O3.

  7. Bismuth pyrochlore thin films for dielectric energy storage

    International Nuclear Information System (INIS)

    Thin films of cubic pyrochlore bismuth zinc niobate, bismuth zinc tantalate, and bismuth zinc niobate tantalate were fabricated using chemical solution deposition. This family of materials exhibited moderate relative permittivities between 55 ± 2 and 145 ± 5 for bismuth zinc tantalate and bismuth zinc niobate, respectively, and low loss tangents on the order of 0.0008 ± 0.0001. Increases in the concentration of the tantalum end member increased the dielectric breakdown strength. For example, at 10 kHz, the room temperature breakdown strength of bismuth zinc niobate was 5.1 MV/cm, while that of bismuth zinc tantalate was 6.1 MV/cm. This combination of a high breakdown strength and a moderate permittivity led to a high discharged energy storage density for all film compositions. For example, at a measurement frequency of 10 kHz, bismuth zinc niobate exhibited a maximum recoverable energy storage density of 60.8 ± 2.0 J/cm3, while bismuth zinc tantalate exhibited a recoverable energy storage density of 60.7 ± 2.0 J/cm3. Intermediate compositions of bismuth zinc niobate tantalate offered higher energy storage densities; at 10 mol. % tantalum, the maximum recoverable energy storage density was ∼66.9 ± 2.4 J/cm3

  8. 49 CFR 209.133 - Referral for prosecution.

    Science.gov (United States)

    2010-10-01

    ... 49 Transportation 4 2010-10-01 2010-10-01 false Referral for prosecution. 209.133 Section 209.133... Penalties § 209.133 Referral for prosecution. If an inspector, including a certified state inspector under... case, and if it appears that assessment of a civil penalty would not be an adequate deterrent to...

  9. 46 CFR 153.209 - Bilge pumping systems.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 5 2010-10-01 2010-10-01 false Bilge pumping systems. 153.209 Section 153.209 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) CERTAIN BULK DANGEROUS CARGOES SHIPS CARRYING... Requirements § 153.209 Bilge pumping systems. Bilge pumping systems for cargo pumprooms, slop tanks, and...

  10. 49 CFR 209.131 - Criminal penalties generally.

    Science.gov (United States)

    2010-10-01

    ... 49 Transportation 4 2010-10-01 2010-10-01 false Criminal penalties generally. 209.131 Section 209... Criminal Penalties § 209.131 Criminal penalties generally. A person who knowingly violates 49 U.S.C. 5104(b... hazardous material transportation law or a regulation, order, special permit, or approval issued...

  11. 46 CFR 69.209 - Calculation of tonnages.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 2 2010-10-01 2010-10-01 false Calculation of tonnages. 69.209 Section 69.209 Shipping... MEASUREMENT OF VESSELS Simplified Measurement System § 69.209 Calculation of tonnages. (a) Gross tonnage. (1... percent of that depth is used for gross tonnage calculations. (b) Net tonnage. (1) For a vessel...

  12. 48 CFR 209.406-2 - Causes for debarment.

    Science.gov (United States)

    2010-10-01

    ... 48 Federal Acquisition Regulations System 3 2010-10-01 2010-10-01 false Causes for debarment. 209.406-2 Section 209.406-2 Federal Acquisition Regulations System DEFENSE ACQUISITION REGULATIONS SYSTEM... 209.406-2 Causes for debarment. (1) Any person shall be considered for debarment if...

  13. 5 CFR 842.209 - Members of Congress.

    Science.gov (United States)

    2010-01-01

    ... 5 Administrative Personnel 2 2010-01-01 2010-01-01 false Members of Congress. 842.209 Section 842.209 Administrative Personnel OFFICE OF PERSONNEL MANAGEMENT (CONTINUED) CIVIL SERVICE REGULATIONS (CONTINUED) FEDERAL EMPLOYEES RETIREMENT SYSTEM-BASIC ANNUITY Eligibility § 842.209 Members of Congress....

  14. 33 CFR 209.345 - Water resource policies and authorities.

    Science.gov (United States)

    2010-07-01

    ... 33 Navigation and Navigable Waters 3 2010-07-01 2010-07-01 false Water resource policies and authorities. 209.345 Section 209.345 Navigation and Navigable Waters CORPS OF ENGINEERS, DEPARTMENT OF THE ARMY, DEPARTMENT OF DEFENSE ADMINISTRATIVE PROCEDURE § 209.345 Water resource policies and authorities. Reimbursement for Advance...

  15. 49 CFR 382.209 - Use following an accident.

    Science.gov (United States)

    2010-10-01

    ... 49 Transportation 5 2010-10-01 2010-10-01 false Use following an accident. 382.209 Section 382.209... ALCOHOL USE AND TESTING Prohibitions § 382.209 Use following an accident. No driver required to take a post-accident alcohol test under § 382.303 shall use alcohol for eight hours following the accident,...

  16. Information on antiprotonic atoms and the nuclear periphery from the PS209 experiment

    OpenAIRE

    Trzcinska, A.; Jastrzebski, J.; Czosnyka, T.; von Egidy, T.; Gulda, K.; Hartmann, F. J.; Iwanicki, J.; Ketzer, B.; Kisielinski, M.; Klos, B.; Kurcewicz, W.; Lubinski, P.; Napiorkowski, P. J.; Pienkowski, L.; Schmidt, R.

    2001-01-01

    In the PS209 experiments at CERN two kinds of measurements were performed: the in-beam measurement of X-rays from antiprotonic atoms and the radiochemical, off-line determination of the yield of annihilation products with mass number A_t -1 (less by 1 than the target mass). Both methods give observables which allows to study the peripheral matter density composition and distribution.

  17. Bismuth( Ⅲ ) Salts: Green Catalysts for Organic Transformations

    Institute of Scientific and Technical Information of China (English)

    C. Le Roux

    2005-01-01

    @@ 1Introduction Bismuth, the heaviest stable element in the periodic table, stands out from other heavy elements (such as mercury, thallium and lead) due to its relatively non-toxic character which confers on bismuth the enviable status of being an eco-friendly element. Therefore, bismuth and its compounds hold considerable promise as useful catalysts for green chemistry. The research presented in this communication is devoted to the applications of bismuth( Ⅲ ) salts as catalysts for organic transformations.After some general comments about bismuth and a short presentation of the various applications of bismuth( Ⅲ ) salts in organic synthesis, this communication will focus on the works done in our research group during the last several years which deals mainly with electrophilic substitutions. When appropriate, some mechanistic details will be given.

  18. Electroanalysis of organic compounds at bismuth electrodes: a short review

    OpenAIRE

    Lezi, Nikolitsa; Vyskočil, Vlastimil; Economou, Anastasios; Barek, Jiří

    2012-01-01

    Over the last twelve years, it has been demonstrated that bismuth electrodes have comparable electroanalytical performance to mercury electrodes in the negative potential range. Since the toxicicty of bismuth is lower than that of mercury, bismuth can serve as an alternative “green” electrode material to mercury. However, the great majority of published work at bismuth–based electrodes is concerned with the determination of trace metals by voltammetric techniques with only few applications de...

  19. Electron Paramagnetic Resonance Study of Thermally Treated Bismuth Subgallate

    OpenAIRE

    2014-01-01

    Complex of bismuth, an anti-inflammatory drug, was studied by EPR spectroscopy. The aim of this study was to determine concentrations and properties of free radicals formed during thermal sterilization of bismuth subgallate according to pharmacopoeia norms to optimize its sterilization process. Different temperatures (160°C, 170°C, and 180°C) and times (120 minutes, 60 minutes, and 30 minutes) of sterilization were used. Interactions of bismuth subgallate with DPPH, the model free radical ref...

  20. Stress-driven growth of bismuth nanowires

    Science.gov (United States)

    Cheng, Yang-Tse; Weiner, Anita M.; Wong, Curtis A.; Balogh, Michael P.; Lukitsch, Michael J.

    2003-03-01

    We recently reported that compressive stresses in thin films can be exploited to grow nanowires (Ref.1). Nanowires of bismuth (Bi) with diameters ranging from 30 to 200 nm and lengths up to several millimeters were formed spontaneously at the rate of a few micrometers per second at room temperature on surfaces of freshly grown composite thin films consisting of Bi and chrome-nitride (CrN). The high compressive stress in the composite thin films was shown to be the driving force responsible for the nanowire formation. In this presentation, the effects of stress, composition, and temperature on the growth and structure of bismuth nanowires will be discussed. This method of growing nanowires can also be extended to other material systems. Ref. 1. Yang-Tse Cheng, Anita M. Weiner, Curtis A. Wong, Michael P. Balogh, and Michael J. Lukitsch, Applied Physics Letters 81, 3248 (2002).

  1. Superdeformation in the bismuth nuclei

    International Nuclear Information System (INIS)

    High angular-momentum states in 196,197Bi were populated in the reaction 183W (19F,xn) at a beam energy of 108 MeV, and γ rays were detected with the Gammasphere array. Two weakly populated rotational bands, with energy spacings characteristic of superdeformation have been found. Both cascades can be assigned unambiguously to the Bi nuclei; however, their isotopic assignment to 197Bi is tentative. The properties of the bands and their possible structures are discussed. Our results represent the first identification of superdeformed bands in a nucleus of the A∼190 mass region with Z>82

  2. Electrocatalytic activity of bismuth doped silver electrodes

    CERN Document Server

    Amjad, M

    2002-01-01

    Investigation of redox reactions on silver, and bismuth doped silver electrodes in aqueous KOH solutions, by using potentiostatic steady-state polarization technique, has been carried out. The redox wave potential and current displacements along with multiplicity of the latter have been examined. These electrodes were employed for the oxidation of organic molecules such as ethylamine in alkaline media. Subsequently, these electrodes were ranked with respect to their activity for the redox reactions. (author)

  3. Bismuth film electrodes for heavy metals determination

    Science.gov (United States)

    Rehacek, Vlastimil; Hotovy, Ivan; Vojs, Marian; Mika, Fedor

    2007-05-01

    Bismuth film electrodes (BiFEs) have a potential to replace toxic mercury used most frequently for determination of heavy metals (Cd, Pb, Zn) by anodic stripping voltammetry. We prepared a graphite disc electrode (0.5 mm in diameter) from a pencil-lead rod and developed a nitrogen doped diamond-like carbon (NDLC) microelectrode array consisting of 50 625 microdiscs with 3 μm in diameter and interelectrode distances of 20 μm on a highly conductive silicon substrate as a support for BiFEs. The disc graphite BiFE was used for simultaneous determination of Pb(II), Cd(II) and Zn(II) by square wave voltammetry (SWV) in an aqueous solution. We found the optimum bismuth-to-metal concentration ratio in the solution to be 20. The dependence of the stripping responses on the concentration of target metals was linear in the range from 1×10 -8 to 1.2×10 -7 mol/L. Detection limits 2.4×10 -9 mol/L for Pb(II), 2.9×10 -9 mol/L for Cd(II) and 1.2×10 -8 mol/L for Zn(II) were estimated. A bismuth-plated NDLC microelectrode array was used for Pb(II) determination by differential pulse voltammetry (DPV) in an aqueous solution. We found that the stripping current for bismuth-plated NDLC array was linear in the concentration range of Pb(II) from 2×10 -8 to 1.2×10 -7 mol/L. The detection limit 2.2×10 -8 mol/L was estimated from a calibration plot.

  4. Influence of bismuth content on viscosity of lead-bismuth alloy

    International Nuclear Information System (INIS)

    In this paper, viscosities of Pb44.5 Bi55.5 (LBE), Pb60 Bi40, Pb70 Bi30, Pb80 Bi20 and Pb are studied in a certain temperature range above liquidus, the results show that the viscosities of five melts decrease with the increase of temperature. Excepting for pure Pb, anomalous changes in the viscosity values are found in LBE, Pb60 Bi40, Pb70 Bi30 and Pb80 Bi20 in the test temperature range, it is presumed that melts structure occurs at the anomalous point of the viscosity. In the temperature range of 623∼923 K, viscosity value of Pb60 Bi40 is obviously higher than that of the other proportion of lead bismuth alloy, and it increases with the decrease of bismuth content at temperature above 1023 K. The experimental results provide data support for the choice of lead-bismuth hypoeutectic applied in advanced nuclear reactor. (authors)

  5. Flame spray synthesis under a non-oxidizing atmosphere: Preparation of metallic bismuth nanoparticles and nanocrystalline bulk bismuth metal

    International Nuclear Information System (INIS)

    Metallic bismuth nanoparticles of over 98% purity were prepared by a modified flame spray synthesis method in an inert atmosphere by oxygen-deficient combustion of a bismuth-carboxylate based precursor. The samples were characterized by X-ray diffraction, thermal analysis and scanning electron microscopy confirming the formation of pure, crystalline metallic bismuth nanoparticles. Compression of the as-prepared powder resulted in highly dense, nanocrystalline pills with strong electrical conductivity and bright metallic gloss

  6. Spin dynamics of complex oxides, bismuth-antimony alloys, and bismuth chalcogenides

    Science.gov (United States)

    Sahin, Cuneyt

    The emerging field of spintronics relies on the manipulation of electron spin in order to use it in spin-based electronics. Such a paradigm change has to tackle several challenges including finding materials with sufficiently long spin lifetimes and materials which are efficient in generating pure spin currents. This thesis predicts that two types of material families could be a solution to the aforementioned challenges: complex oxides and bismuth based materials. We derived a general approach for constructing an effective spin-orbit Hamiltonian which is applicable to all nonmagnetic materials. This formalism is useful for calculating spin-dependent properties near an arbitrary point in momentum space. We also verified this formalism through comparisons with other approaches for III-V semiconductors, and its general applicability is illustrated by deriving the spin-orbit interaction and predicting spin lifetimes for strained strontium titanate (STO) and a two-dimensional electron gas in STO (such as at the LAO/STO interface). Our results suggest robust spin coherence and spin transport properties in STO related materials even at room temperature. In the second part of the study we calculated intrinsic spin Hall conductivities for bismuth-antimony (BISb) semimetals with strong spin-orbit couplings, from the Kubo formula and using Berry curvatures evaluated throughout the Brillouin zone from a tight-binding Hamiltonian. Nearly crossing bands with strong spin-orbit interaction generate giant spin Hall conductivities in these materials, ranging from 474 ((h/e)O--1cm--1) for bismuth to 96((h/e)O--1cm --1) for antimony; the value for bismuth is more than twice that of platinum. The large spin Hall conductivities persist for alloy compositions corresponding to a three-dimensional topological insulator state, such as Bi0.83Sb0.17. The spin Hall conductivity could be changed by a factor of 5 for doped Bi, or for Bi0.83Sb0.17, by changing the chemical potential by 0.5 e

  7. Growth of GaAsBi alloy under alternated bismuth flows by metalorganic vapor phase epitaxy

    Science.gov (United States)

    Chine, Z.; Fitouri, H.; Zaied, I.; Rebey, A.; El Jani, B.

    2011-09-01

    A successful method to epitaxy GaAsBi layer on (0 0 1) GaAs substrate is proposed. During growth, alternated trimethyl bismuth (TMBi) flows were used. These TMBi flashes were switched on for a short time. The growth was monitored in situ by laser reflectometry using a 632.8 nm beam. The reflectance signal is found to change significantly during both bismuth flashes and GaAs growth stages. High-resolution X-ray diffraction (HRXRD), secondary ion mass spectroscopy (SIMS) and photoreflectance spectroscopy (PR) have been used to characterize the obtained GaAsBi layer. HRXRD curve shows a diffraction peak that can be attributed to a GaAsBi epilayer. SIMS measurements of GaAsBi layer suggest that bismuth diffuses faster near the interface. The PR spectrum indicates the band-to-band transition in GaAsBi layer. The band gap energy was determined by adjusting the PR spectrum with a multilayer model.

  8. Hall-Effect Thruster Utilizing Bismuth as Propellant

    Science.gov (United States)

    Szabo, James; Gasdaska, Charles; Hruby, Vlad; Robin, Mike

    2008-01-01

    A laboratory-model Hall-effect spacecraft thruster was developed that utilizes bismuth as the propellant. Xenon was used in most prior Hall-effect thrusters. Bismuth is an attractive alternative because it has a larger atomic mass, a larger electron-impact-ionization cross-section, and is cheaper and more plentiful.

  9. Optical spectroscopy of Bismuth-doped pure silica fiber preform

    OpenAIRE

    Razdobreev, Igor,; El Hamzaoui, Hicham; Ivanov, V. Yu; Kustov, E. F.; Capoen, Bruno; Bouazaoui, Mohamed

    2010-01-01

    International audience We report on the optical spectroscopy of monolithic fiber preform prepared from nanoporous bismuth-doped silica glass. The experiments reveal the existence of at least two different types of active centers and clearly demonstrate that the presence in the glass matrix of other dopant is not necessary to obtain the near-IR photoluminescence connected to Bismuth.

  10. Bismuth-doped fibre amplifier operating between 1600 and 1800 nm

    Science.gov (United States)

    Firstov, S. V.; Alyshev, S. V.; Riumkin, K. E.; Khopin, V. F.; Mel'kumov, M. A.; Gurjanov, A. N.; Dianov, E. M.

    2015-12-01

    We report the first bismuth-doped fibre amplifier operating between 1600 and 1800 nm, which utilises bidirectional pumping (co-propagating and counter-propagating pump beams) by laser diodes at a wavelength of 1550 nm. The largest gain coefficient of the amplifier is 23 dB, at a wavelength of 1710 nm. It has a noise figure of 7 dB, 3-dB gain bandwidth of 40 nm and gain efficiency of 0.1 dB mW-1.

  11. Bismuth(III) dialkyldithiophosphates: Facile single source precursors for the preparation of bismuth sulfide nanorods and bismuth phosphate thin films

    Energy Technology Data Exchange (ETDEWEB)

    Biswal, Jasmine B. [Department of Chemistry, University of Mumbai, Vidyanagari, Santacruz (East), Mumbai 400098 (India); Garje, Shivram S., E-mail: ssgarje@chem.mu.ac.in [Department of Chemistry, University of Mumbai, Vidyanagari, Santacruz (East), Mumbai 400098 (India); Nuwad, Jitendra; Pillai, C.G.S. [Chemistry Division, Bhabha Atomic Research Centre, Trombay, Mumbai 400085 (India)

    2013-08-15

    Two different phase pure materials (Bi{sub 2}S{sub 3} and Bi{sub 2}P{sub 4}O{sub 13}) have been prepared under different conditions using the same single source precursors. Solvothermal decomposition of the complexes, Bi(S{sub 2}P(OR){sub 2}){sub 3} [where, R=Methyl (Me) (1), Ethyl (Et) (2), n-Propyl (Pr{sup n}) (3) and iso-Propyl (Pr{sup i}) (4)] in ethylene glycol gave orthorhombic bismuth sulfide nanorods, whereas aerosol assisted chemical vapor deposition (AACVD) of the same precursors deposited monoclinic bismuth tetraphosphate (Bi{sub 2}P{sub 4}O{sub 13}) thin films on glass substrates. Surface study of the thin films using SEM illustrated the formation of variety of nanoscale morphologies (spherical-, wire-, pendent-, doughnut- and flower-like) at different temperatures. AFM studies were carried out to evaluate quality of the films in terms of uniformity and roughness. Thin films of average roughness as low as 1.4 nm were deposited using these precursors. Photoluminescence studies of Bi{sub 2}P{sub 4}O{sub 13} thin films were also carried out. - Graphical abstract: Solvothermal decomposition of bismuth(III) dialkyldithiophosphates in ethylene glycol gave Bi{sub 2}S{sub 3} nanoparticles, whereas aerosol assisted chemical vapor deposition of these single source precursors deposited Bi{sub 2}P{sub 4}O{sub 13} thin films. Display Omitted - Highlights: • Preparation of phase pure orthorhombic Bi{sub 2}S{sub 3} nanorods and monoclinic Bi{sub 2}P{sub 4}O{sub 13} thin films. • Use of single source precursors for deposition of bismuth phosphate thin films. • Use of solvothermal decomposition and AACVD methods. • Morphology controlled synthesis of Bi{sub 2}P{sub 4}O{sub 13} thin films. • Bi{sub 2}S{sub 3} nanorods and Bi{sub 2}P{sub 4}O{sub 13} thin films using same single source precursors.

  12. A case of bismuth intoxication with irreversible renal damage

    Directory of Open Access Journals (Sweden)

    Erden A

    2013-11-01

    Full Text Available Abdulsamet Erden, Samet Karahan, Kadir Bulut, Mustafa Basak, Tuncay Aslan, Ali Cetinkaya, Hatice Karagoz, Deniz Avci Internal Medicine Department, Kayseri Training and Research Hospital, Kayseri, Turkey Abstract: Bismuth is a chemical element symbolized as Bi and is a trivalent poor metal, which chemically resembles arsenic and antimony. Colloidal bismuth subcitrate (CBS and bismuth subsalicylate are the bismuth salts widely used in the treatment of peptic ulcers, functional dyspepsia, and chronic gastritis. Intoxications with CBS are rare. In a few case reports, acute renal failure was described, but the literature review revealed no chronic renal failure related to CBS intoxication. In this case report we present a 21-year old female with chronic renal failure after a one year follow-up of CBS intoxication. Keywords: acute renal failure, bismuth, intoxication, chronic renal failure

  13. An evaluated neutronic data file for bismuth

    International Nuclear Information System (INIS)

    A comprehensive evaluated neutronic data file for bismuth, extending from 10-5 eV to 20.0 MeV, is described. The experimental database, the application of the theoretical models, and the evaluation rationale are outlined. Attention is given to uncertainty specification, and comparisons are made with the prior ENDF/B-V evaluation. The corresponding numerical file, in ENDF/B-VI format, has been transmitted to the National Nuclear Data Center, Brookhaven National Laboratory. 106 refs., 10 figs., 6 tabs

  14. Electron Paramagnetic Resonance Study of Thermally Treated Bismuth Subgallate

    Directory of Open Access Journals (Sweden)

    Paweł Ramos

    2014-01-01

    Full Text Available Complex of bismuth, an anti-inflammatory drug, was studied by EPR spectroscopy. The aim of this study was to determine concentrations and properties of free radicals formed during thermal sterilization of bismuth subgallate according to pharmacopoeia norms to optimize its sterilization process. Different temperatures (160°C, 170°C, and 180°C and times (120 minutes, 60 minutes, and 30 minutes of sterilization were used. Interactions of bismuth subgallate with DPPH, the model free radical reference, were checked. g-Factors, amplitudes (A, integral intensities (I, and linewidths (ΔBpp were obtained. Integral intensities were obtained by double integration of the first-derivative EPR lines. The influence of microwave power in the range of 2.2–70 mW on shape and parameters of the EPR spectra was examined. Thermal sterilization produced free radicals in bismuth subgallate in all tested cases. Strong interactions with free radicals were pointed out for all the analysed samples containing bismuth independent of sterilization conditions. Optimal conditions of thermal sterilization for bismuth subgallate with the lowest free radical formation are temperature 170°C and time of heating 60 minutes. Strong dipolar interactions exist in thermally sterilized bismuth subgallate. EPR spectroscopy is a useful method of examination of thermal sterilization conditions.

  15. Electron paramagnetic resonance study of thermally treated bismuth subgallate.

    Science.gov (United States)

    Ramos, Paweł; Pilawa, Barbara

    2014-01-01

    Complex of bismuth, an anti-inflammatory drug, was studied by EPR spectroscopy. The aim of this study was to determine concentrations and properties of free radicals formed during thermal sterilization of bismuth subgallate according to pharmacopoeia norms to optimize its sterilization process. Different temperatures (160°C, 170°C, and 180°C) and times (120 minutes, 60 minutes, and 30 minutes) of sterilization were used. Interactions of bismuth subgallate with DPPH, the model free radical reference, were checked. g-Factors, amplitudes (A), integral intensities (I), and linewidths (ΔB pp) were obtained. Integral intensities were obtained by double integration of the first-derivative EPR lines. The influence of microwave power in the range of 2.2-70 mW on shape and parameters of the EPR spectra was examined. Thermal sterilization produced free radicals in bismuth subgallate in all tested cases. Strong interactions with free radicals were pointed out for all the analysed samples containing bismuth independent of sterilization conditions. Optimal conditions of thermal sterilization for bismuth subgallate with the lowest free radical formation are temperature 170°C and time of heating 60 minutes. Strong dipolar interactions exist in thermally sterilized bismuth subgallate. EPR spectroscopy is a useful method of examination of thermal sterilization conditions. PMID:25525421

  16. Inclusive measurement of (p,πsup(-)xn) double charge exchange reactions on bismuth from threshold to 800 MeV

    International Nuclear Information System (INIS)

    The energy dependence of the total angle-integrated cross section for the production of astatine isotopes from (p,πsup(-)xn) double charge exchange reactions on bismuth (sup(209)Bi) was measured from 120 to 800 MeV using activation and radiochemical techniques. Chemical yields were estimated by direct radioassaying of sup(211)At activity in thin (approximately 1 mg/cmsup(2)), irradiated bismuth targets. Calculations of the contributions of secondary (2-step) reactions to these measured astatine yields were performed, based partially upon the observed sup(211)At activity although even at the highest energies, the contribution to products lighter than sup(207)At was negligible. These data for products with as many as 7 neutrons removed from the doubly coherent product (sup(210)At) display nearby gaussian shapes for the mass distributions of the astatine residues with the maximum occurring for about sup(204)At. The most probable momentum transfer deduced from these distributions for the initial πsup(-) production step was 335 MeV/c. The observed excitation functions display a behaviour similar to that observed for the yield of sup(210)Po from a (p,πsup(O)) reaction on sup(209)Bi, but radically different from that observed for inclusive πsup(-) reactions on a heavy nucleus. These data are discussed in terms of recent theoretical approaches to negative pion production from bismuth. In addition, a simple, schematic model is developed to treat the rapidly decreasing percentage of the total inclusive πsup(-) emission which is observed for this double charge exchange reaction. This model reflects the capacity of a nucleus to a source of internal energetic protons

  17. Life time of the HFS transition in Li-like {sup 209}Bi{sup 80+}

    Energy Technology Data Exchange (ETDEWEB)

    Geppert, C.; Noertershaeuser, W. [Institut fuer Kernchemie, Uni Mainz (Germany); GSI, Darmstadt (Germany); Hannen, V.; Joehren, R.; Ortjohann, H.W.; Vollbrecht, J.; Weinheimer, C. [Institut fuer Kernphysik, Uni Muenster (Germany); Kuehl, T. [Institut fuer Kernchemie, Uni Mainz (Germany); GSI, Darmstadt (Germany); Helmholtz Institut Jena (Germany); S' anchez, R.; Winters, D. [GSI, Darmstadt (Germany); Stoehlker, T. [Institut fuer Kernchemie, Uni Mainz (Germany); GSI, Darmstadt (Germany); Helmholtz Institut Jena (Germany); Uni Jena (Germany)

    2014-07-01

    Measuring the hyperfine splitting of heavy, highly charged ions enables tests of QED in strong fields. HFS calculations have a relative uncertainty of more than 10{sup -3} due to the distribution of the magnetic moment (Bohr-Weisskopf-Effekt). With an appropriate comparison of H- and Li-like ions this nuclear structure contribution can be suppressed. Bismuth is a suitable element for these studies, as the HFS splitting for both configurations are in a wavelength range suitable for laser spectroscopy. For this purpose the two ion species were stored in the Experimental Storage Ring at GSI at a velocity of β = 0.71. To efficiently collect the forward emitted photons a specially developed movable detector system was used. Thereby the HFS of Li-like {sup 209}Bi{sup 80+} was successfully measured for the first time. Besides the determination of the transition energy it was possible to extract the lifetime of the transition out of the collected data. The corresponding analysis and the results are presented on this poster.

  18. Life time of the HFS transition in Li-like 209Bi80+

    International Nuclear Information System (INIS)

    Measuring the hyperfine splitting of heavy, highly charged ions enables tests of QED in strong fields. HFS calculations have a relative uncertainty of more than 10-3 due to the distribution of the magnetic moment (Bohr-Weisskopf-Effekt). With an appropriate comparison of H- and Li-like ions this nuclear structure contribution can be suppressed. Bismuth is a suitable element for these studies, as the HFS splitting for both configurations are in a wavelength range suitable for laser spectroscopy. For this purpose the two ion species were stored in the Experimental Storage Ring at GSI at a velocity of β = 0.71. To efficiently collect the forward emitted photons a specially developed movable detector system was used. Thereby the HFS of Li-like 209Bi80+ was successfully measured for the first time. Besides the determination of the transition energy it was possible to extract the lifetime of the transition out of the collected data. The corresponding analysis and the results are presented on this poster.

  19. Dicty_cDB: VSJ209 [Dicty_cDB

    Lifescience Database Archive (English)

    Full Text Available VS (Link to library) VSJ209 (Link to dictyBase) - - - Contig-U15456-1 VSJ209E (Link to Original ... _1( U60995 |pid:none) Schistosoma mansoni aspartic proteinas ... 172 6e-79 protein update 2009. 3.25 PSORT psg: ...

  20. Dicty_cDB: VFA209 [Dicty_cDB

    Lifescience Database Archive (English)

    Full Text Available VF (Link to library) VFA209 (Link to dictyBase) - - - Contig-U15456-1 VFA209P (Link to Original ... 85_1( EF193385 |pid:none) Musca domestica aspartic proteinas ... 171 1e-75 AB078420_1( AB078420 |pid:none) Brugi ...

  1. 50 CFR 226.209 - Critical habitat for hawksbill turtle.

    Science.gov (United States)

    2010-10-01

    ... 50 Wildlife and Fisheries 7 2010-10-01 2010-10-01 false Critical habitat for hawksbill turtle. 226.209 Section 226.209 Wildlife and Fisheries NATIONAL MARINE FISHERIES SERVICE, NATIONAL OCEANIC AND... Critical habitat for hawksbill turtle. (a) Mona and Monito Islands, Puerto Rico—Waters surrounding...

  2. 7 CFR 761.209 - Loan funds for beginning farmers.

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 7 2010-01-01 2010-01-01 false Loan funds for beginning farmers. 761.209 Section 761... Funds to State Offices § 761.209 Loan funds for beginning farmers. Each fiscal year, the Agency reserves a portion of direct and guaranteed FO and OL loan funds for beginning farmers in accordance...

  3. 21 CFR 209.1 - Scope and purpose.

    Science.gov (United States)

    2010-04-01

    ... dispensing or administering prescription drug products to inpatients in a hospital or health care facility... 21 Food and Drugs 4 2010-04-01 2010-04-01 false Scope and purpose. 209.1 Section 209.1 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) DRUGS:...

  4. 8 CFR 209.1 - Adjustment of status of refugees.

    Science.gov (United States)

    2010-01-01

    ... 8 Aliens and Nationality 1 2010-01-01 2010-01-01 false Adjustment of status of refugees. 209.1... STATUS OF REFUGEES AND ALIENS GRANTED ASYLUM § 209.1 Adjustment of status of refugees. The provisions of this section shall provide the sole and exclusive procedure for adjustment of status by a...

  5. 14 CFR 1274.209 - Evaluation and selection.

    Science.gov (United States)

    2010-01-01

    ...) Technical evaluation. The technical evaluation of proposals may include peer reviews. Because the business... 14 Aeronautics and Space 5 2010-01-01 2010-01-01 false Evaluation and selection. 1274.209 Section... WITH COMMERCIAL FIRMS Pre-Award Requirements § 1274.209 Evaluation and selection. (a)...

  6. Dicty_cDB: VSK209 [Dicty_cDB

    Lifescience Database Archive (English)

    Full Text Available VS (Link to library) VSK209 (Link to dictyBase) - - - Contig-U15669-1 VSK209P (Link to Original ... .2 T31109( T31109 )myosin III - Atlantic horseshoe crab ... 34 6.2 protein update 2009. 3.26 PSORT psg: 0.81 g ...

  7. 27 CFR 46.209 - Articles in vending machines.

    Science.gov (United States)

    2010-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 2 2010-04-01 2010-04-01 false Articles in vending machines. 46.209 Section 46.209 Alcohol, Tobacco Products and Firearms ALCOHOL AND TOBACCO TAX AND TRADE BUREAU, DEPARTMENT OF THE TREASURY (CONTINUED) TOBACCO MISCELLANEOUS REGULATIONS RELATING TO TOBACCO PRODUCTS AND CIGARETTE PAPERS AND TUBES...

  8. 28 CFR 36.209 - Illegal use of drugs.

    Science.gov (United States)

    2010-07-01

    ... 28 Judicial Administration 1 2010-07-01 2010-07-01 false Illegal use of drugs. 36.209 Section 36... PUBLIC ACCOMMODATIONS AND IN COMMERCIAL FACILITIES General Requirements § 36.209 Illegal use of drugs. (a... discrimination against an individual based on that individual's current illegal use of drugs. (2) A...

  9. 33 CFR 209.220 - Flood control regulations.

    Science.gov (United States)

    2010-07-01

    ... 33 Navigation and Navigable Waters 3 2010-07-01 2010-07-01 false Flood control regulations. 209..., DEPARTMENT OF DEFENSE ADMINISTRATIVE PROCEDURE § 209.220 Flood control regulations. (a) Local protection... probable date of transfer. (b) Use of storage allocated for flood control or navigation at...

  10. 33 CFR 209.300 - Flood control regulations.

    Science.gov (United States)

    2010-07-01

    ... 33 Navigation and Navigable Waters 3 2010-07-01 2010-07-01 false Flood control regulations. 209..., DEPARTMENT OF DEFENSE ADMINISTRATIVE PROCEDURE § 209.300 Flood control regulations. (a) Regulations for the... authority contained in Section 3 of the Flood Control Act of June 22, 1936, as amended and supplemented,...

  11. 49 CFR 1540.209 - Fees for security threat assessment.

    Science.gov (United States)

    2010-10-01

    ... 49 Transportation 9 2010-10-01 2010-10-01 false Fees for security threat assessment. 1540.209...: GENERAL RULES Security Threat Assessments § 1540.209 Fees for security threat assessment. This section describes the payment process for completion of the security threat assessments required under subpart....

  12. 49 CFR 209.109 - Payment of penalty; compromise.

    Science.gov (United States)

    2010-10-01

    ... the Internet at https://www.pay.gov/paygov/. Instructions for online payment are found on the Web site... 49 Transportation 4 2010-10-01 2010-10-01 false Payment of penalty; compromise. 209.109 Section... Civil Penalties § 209.109 Payment of penalty; compromise. (a) Payment of a civil penalty may be made...

  13. 20 CFR 209.16 - Disposal of payroll records.

    Science.gov (United States)

    2010-04-01

    ... 20 Employees' Benefits 1 2010-04-01 2010-04-01 false Disposal of payroll records. 209.16 Section... RAILROAD EMPLOYERS' REPORTS AND RESPONSIBILITIES § 209.16 Disposal of payroll records. Employers may dispose of payroll records for periods subsequent to 1936, provided that the payroll records are more...

  14. Determining the background levels of bismuth in tissues of wild game birds: a first step in addressing the environmental consequences of using bismuth shotshells

    International Nuclear Information System (INIS)

    Bismuth shotshells have been approved as a 'nontoxic' alternative to lead in North America. Approval was based on a limited number of studies; even background levels of bismuth in wildfowl were unknown. We report on the concentration of bismuth (and lead) in muscle and liver tissues of wildfowl (Anas platyrhynchos, Anas acuta, Anas crecca, Branta canadensis, Chen caerulescens) harvested with lead shotshell. Average liver-bismuth levels detected in the present study (e.g., teal, 0.05 μg/g dw; mallard, 0.09 μg/g dw) suggest analytical error in other studies examining the effects of bismuth in birds. Significant positive relationships between bismuth- and lead-tissue levels for muscle when all species were combined (and for B. canadensis and C. caerulescens separately) can be explained by noting that bismuth is a contaminant of lead. Thus, more research is recommended to confirm the appropriateness of bismuth as a 'nontoxic' shot alternative

  15. Radiationless transition probabilities in muonic 209Bi

    International Nuclear Information System (INIS)

    The probability for non-radiative (n.r.) excitations in muonic 209Bi was determined from a (μ-, γγ)-measurement by comparing the intensities of muonic X-ray transitions in single and coincidence spectra. The values of Pn.r.(3p→1s)=(17.9±2.0)% and Pn.r.(3d→1s)=(3.0±2.2)% were measured for the first time. The strength of the n.r. decay of the 2p-level was found to be (4.2±2.2)%. The n.r. transition probabilities of two subcomplexes of the (2p→1s)-transition leading to different mean excitation energies are (3.2±1.8)% and (5.0±2.0)%, respectively. (orig.)

  16. Hierarchical bismuth phosphate microspheres with high photocatalytic performance

    Energy Technology Data Exchange (ETDEWEB)

    Pei, Lizhai; Wei, Tian; Lin, Nan; Yu, Haiyun [Anhui University of Technology, Ma' anshan (China). Key Laboratory of Materials Science and Processing of Anhui Province

    2016-05-15

    Hierarchical bismuth phosphate microspheres have been prepared by a simple hydrothermal process with polyvinyl pyrrolidone. Scanning electron microscopy observations show that the hierarchical bismuth phosphate microspheres consist of nanosheets with a thickness of about 30 nm. The diameter of the microspheres is about 1 - 3 μm. X-ray diffraction analysis shows that the microspheres are comprised of triclinic Bi{sub 23}P{sub 4}O{sub 44.5} phase. The formation of the hierarchical microspheres depends on polyvinyl pyrrolidone concentration, hydrothermal temperature and reaction time. Gentian violet acts as the pollutant model for investigating the photocatalytic activity of the hierarchical bismuth phosphate microspheres under ultraviolet-visible light irradiation. Irradiation time, dosage of the hierarchical microspheres and initial gentian violet concentration on the photocatalytic efficiency are also discussed. The hierarchical bismuth phosphate microspheres show good photocatalytic performance for gentian violet removal in aqueous solution.

  17. Bismuth electrodes, an alternative in stripping voltammetry

    International Nuclear Information System (INIS)

    The heavy metals are known as highly toxic contaminants, the processes carried out in industry contribute that finally they remain dispersed in effluents and sewage, doing part of the food chain. The importance of controlling the levels of these heavy metals has become an international policy, so it has generated interest in developing new analytical methodologies for its determination [1, 2, 3, 4]. The stripping voltammetry has been considered as a family of electro-sensitive analytical techniques useful for the determination of trace levels of many metals in environmental, clinical and industrial samples [3, 4]. This work presents an overview of these bismuth-based electrodes which were introduced around 2000, which have interesting characteristics for detection of heavy metals and which represent an alternative to mercury electrodes

  18. Bismuth electrodes, an alternative in stripping voltammetry

    Science.gov (United States)

    Barón-Jaimez, J.; Joya, M. R.; Barba-Ortega, J.

    2013-11-01

    The heavy metals are known as highly toxic contaminants, the processes carried out in industry contribute that finally they remain dispersed in effluents and sewage, doing part of the food chain. The importance of controlling the levels of these heavy metals has become an international policy, so it has generated interest in developing new analytical methodologies for its determination [1, 2, 3, 4]. The stripping voltammetry has been considered as a family of electro-sensitive analytical techniques useful for the determination of trace levels of many metals in environmental, clinical and industrial samples [3, 4]. This work presents an overview of these bismuth-based electrodes which were introduced around 2000, which have interesting characteristics for detection of heavy metals and which represent an alternative to mercury electrodes.

  19. High magnetoresistance in inhomogeneous bismuth microwires

    International Nuclear Information System (INIS)

    The present paper describes investigation of the dependence of magnetoresistance of microwires made of semimetal or semiconductor materials with high electric mobility doped with impurities introduced in the form of deposits at solidification. Till present it has been assumed that microscopic inhomogeneity in semimetals or semiconductors leads to a decrease of mobilities due to additional dispersion of charge carriers on impurities. Wolfe et al. have shown that impurities in the material with high mobility lead to an increase of mobilities due to geometric effect. In our case it is shown that presence of magnetic impurities in bismuth semimetal characterized by high mobility leads to an increase of magnetoresistance. This increase is very important for the technology of magnetic field converters and especially for application of high velocities of record of a magnetic head with a high capability of magnetic record. (authors)

  20. Platinum-Bismuth Bimetallic Catalysts: Synthesis, Characterization and Applications

    OpenAIRE

    Saucedo, Jose A, Jr; Xiao, Yang; Varma, Arvind

    2015-01-01

    Bimetallic catalysts have been explored and shown to exhibit unique characteristics which are not present in monometallic catalysts. Platinum is well known as an effective catalyst for oxidation and reduction reactions, and it can be made more effective when bismuth is introduced as a promotor. Thus, the effectiveness of the Pt-Bi catalyst was demonstrated in prior work. What is not clear, however, is the mechanism behind the catalyst function; why addition of bismuth to platinum decreases de...

  1. Electron cooling and Debye-Waller effect in photoexcited bismuth

    OpenAIRE

    Arnaud, B.; Giret, Y.

    2012-01-01

    By means of first principles calculations, we computed the effective electron-phonon coupling constant $G_0$ governing the electron cooling in photoexcited bismuth. $G_0$ strongly increases as a function of electron temperature, which can be traced back to the semi-metallic nature of bismuth. We also used a thermodynamical model to compute the time evolution of both electron and lattice temperatures following laser excitation. Thereby, we simulated the time evolution of (1 -1 0), (-2 1 1) and...

  2. Piezoelectric bismuth titanate ceramics for high temperature applications

    OpenAIRE

    Shulman, Holly Sue; Setter, Nava

    2005-01-01

    Bismuth titanate (Bi4Ti3O12) shows promise in piezoelectric applications in a temperature range (300-600 °C) which is not well served by standard piezoelectric ceramics. The proposal to use bismuth titanate ceramics for these applications has a major flaw, namely that the high electrical conductivity precludes the efficient polarization of these materials in an electric field. The degree of polarization is critical since it is directly related to the piezoelectric response. In addition, once ...

  3. Improved lead and bismuth (n,{gamma}) cross sections and their astrophysical impact

    Energy Technology Data Exchange (ETDEWEB)

    Domingo-Pardo, C.; Abbondanno, U.; Aerts, G.; Alvarez, H.; Alvarez-Velarde, F.; Andriamonje, S.; Andrzejewski, J.; Assimakopoulos, P.; Audouin, L.; Badurek, G.; Baumann, P.; Becvar, F.; Berthoumieux, E.; Calvino, F.; Calviani, M.; Cano-Ott, D.; Capote, R.; Carrapico, C.; Cennini, P.; Chepel, V.; Chiaveri, E.; Colonna, N.; Cortes, G.; Couture, A.; Cox, J.; Dahlfors, M.; David, S.; Dillmann, I.; Dridi, W.; Duran, I.; Eleftheriadis, C.; Embid-Segura, M.; Ferrant, L.; Ferrari, A.; Ferreira-Marques, R.; Fujii, K.; Furman, W.; Goncalves, I.; Gonzalez-Romero, E.; Gramegna, F.; Guerrero, C.; Gunsing, F.; Haas, B.; Haight, R.; Heil, M.; Herrera-Martinez, A.; Igashira, M.; Jericha, E.; Kiappeler, F.; Kadi, Y.; Karadimos, D.; Karamanis, D.; Kerveno, M.; Koehler, P.; Kossionides, E.; Krticka, M.; Lampoudis, C.; Leeb, H.; Lindote, A.; Lopes, I.; Lozano, M.; Lukic, S.; Marganiec, J.; Marrone, S.; Martinez, T.; Massimi, C.; Mastinu, P.; Mengoni, A.; Milazzo, P.M.; Moreau, C.; Mosconi, M.; Neves, F.; Oberhummer, H.; O' Brien, S.; Pancin, J.; Papachristodoulou, C.; Papadopoulos, C.; Paradela, C.; Patronis, N.; Pavlik, A.; Pavlopoulos, P.; Perrot, L.; Pigni, M.T.; Plag, R.; Plompen, A.; Plukis, A.; Poch, A.; Praena, J.; Pretel, C.; Quesada, J.; Rauscher, T.; Reifarth, R.; Rubbia, C.; Rudolf, G.; Rullhusen, P.; Salgado, J.; Santos, C.; Sarchiapone, L.; Savvidis, I.; Stephan, C.; Tagliente, G.; Tain, J.L.; Tassan-Got, L.; Tavora, L.; Terlizzi, R.; Vannini, G.; Vaz, P.; Ventura, A.; Villamarin, D.; Vincente, M.C.; Vlachoudis, V.; Vlastou, R.; Voss, F.; Walter, S.; Wiescher, M.; Wisshak, K

    2008-07-01

    A series of (n,{gamma}) neutron capture measurements on the lead isotopes and bismuth have been carried out at the CERN n-TOF installation in the neutron energy range from 1 eV up to 1 MeV. At n-TOF, contaminations due to scattered neutrons were reduced down to a negligible level by using improved {gamma}-ray detectors with very low neutron sensitivity. The background level has been determined precisely from a complementary measurement. Other experimental effects related to the electronic threshold in the detectors and the angular distribution of the prompt {gamma}-rays were investigated via Monte Carlo simulations and could be taken into account in the analysis of the capture data. With this set of measurements the energy differential (n,{gamma}) cross sections of {sup 204,206,207}Pb and {sup 209}Bi have been determined with good accuracy. The information obtained in this work becomes of interest for constraining r-process calculations and in particular for the Th/U cosmo-chronometer. (authors)

  4. Improved lead and bismuth (n,γ) cross sections and their astrophysical impact

    International Nuclear Information System (INIS)

    A series of (n,γ) neutron capture measurements on the lead isotopes and bismuth have been carried out at the CERN n-TOF installation in the neutron energy range from 1 eV up to 1 MeV. At n-TOF, contaminations due to scattered neutrons were reduced down to a negligible level by using improved γ-ray detectors with very low neutron sensitivity. The background level has been determined precisely from a complementary measurement. Other experimental effects related to the electronic threshold in the detectors and the angular distribution of the prompt γ-rays were investigated via Monte Carlo simulations and could be taken into account in the analysis of the capture data. With this set of measurements the energy differential (n,γ) cross sections of 204,206,207Pb and 209Bi have been determined with good accuracy. The information obtained in this work becomes of interest for constraining r-process calculations and in particular for the Th/U cosmo-chronometer. (authors)

  5. Studies on bismuth carboxylates—synthesis and characterization of a new structural form of bismuth(III) dipicolinate

    Indian Academy of Sciences (India)

    O Anjaneyulu; K C Kumara Swamy

    2011-03-01

    Synthesis and X-ray structure of a new bismuth dipicolinate cooordination polymer, {[Bi((2,6-O2C)2C5H3N)((2-HO2C-6-O2C)C5H3N)(H2O)]2.5H2O} (7) are presented. Compound 7 has dimeric units with a Bi2O2 skeleton that are linked by additional weak Bi-O interactions leading to a polymeric structure. The overall coordination number at bismuth is 9 [two Bi-N and seven Bi-O bonds]. New routes to a second crystalline modification (4′) of the previously reported coordination polymer, bismuth tris(picolinate), [Bi(2-O2C-C5H4N)3] (4), are described; bond parameters in the two crystalline forms (4 and 4′) are compared. In both the compounds 4′ and 7, bismuth has a distorted tricapped trigonal prismatic geometry.

  6. Optical property tuning of bismuth chalcogenides using chemical intercalation (Presentation Recording)

    Science.gov (United States)

    Yao, Jie

    2015-10-01

    Two-dimensional (2D) materials with natural layer structures have been proven to provide extraordinary physical and chemical properties. Bismuth chalcogenides are examples of such two-dimensional materials. They are strongly bonded within layers and weak van der Waals interaction ties those layers together. Such naturally layered structure allows chemical intercalation of foreign atoms into the van der Waals gaps. Here, we show that by adding large number of copper atoms into van der Waals gaps of bismuth chalcogenides, we observed counter-intuitive enhancement of optical transparency together with improved electrical conductivity, which is on the contrary to most bulk materials in which doping reduces the light transmission. This surprising behavior is caused by substantial tuning of material optical property and nanophotonic anti-reflection effect unique to ultra-thin nanoplates. With the intercalation of copper atoms, large number of electrons have been added into the semiconducting material system and effectively lift the Fermi level of the resulting material to its conduction band, as proved by our densityfunctional- theory computations. Occupied lower states in the conduction band do not allow the optical excitation of electrons in the valence band to the bottom of the conduction band, leading to an effective widening of optical band gap. Optical transmission is further enhanced by constructive interference of reflected beams as bismuth chalcogenides have large permittivity than the environment. The synergy of these two effects in two-dimensional nanostructures can be exploited for various optoelectronic applications including transparent electrode. The reversible intercalation process allows potential dynamic tuning capability.

  7. Synthesis and Characterization of High-Purity Bismuth Nanowires via Seed-Assisted Growth Approach

    Science.gov (United States)

    Mu, Xin; Zhao, Wen-Yu; He, Dan-Qi; Zhou, Hong-Yu; Zhu, Wan-Ting; Zhang, Qing-Jie

    2015-06-01

    Nanowires are considered as high-performance thermoelectric materials with large Seebeck coefficients due to quantum confinement and low thermal conductivity because of enhanced boundary scattering of phonons. In this work, a seed-assisted growth method has been developed to synthesize high-purity bismuth nanowires. The bismuth seeds were first synthesized by reducing BiCl3 in the ice water with NaBH4. The high-purity bismuth nanowires about 40-50 nm in diameter and several tens of micrometers in length were then grown on bismuth seeds by reducing NaBiO3 with ethylene glycol. X-ray diffraction, scanning electron microscopy, and transmission electron microscopy were employed to characterize the crystal structure, microstructure, and growth direction of the bismuth seeds and nanowires. The effects of temperature, reductant, and bismuth seeds template on the microstructures of the bismuth nanowires were also investigated. The synthesis conditions of bismuth seeds and nanowires were optimized. The selected area electron diffraction pattern confirms that the growth direction of bismuth nanowires is parallel to [] direction. It was discovered that high-purity bismuth nanowires with high aspect ratio can be synthesized by precisely controlling the temperature to adjust the nucleation rate of the bismuth nuclei, selecting the appropriate reductant to maintain a low nucleation rate, and using bismuth seeds as the template of the epitaxial growth of the bismuth nuclei.

  8. [Survival after gastrectomy for cancer. 209 cases].

    Science.gov (United States)

    Le Treut, Y P; Capobianco, C; Botti, G; Christophe, M; Lebreuil, G; Bricot, R

    1992-09-26

    The long-term results of 209 gastrectomies performed for adenocarcinoma, including 117 which were prospectively collected, are presented. Resection was curative in 154 cases (73.6 percent). The TNM distribution of the tumours was: stage I (TxNOMO) 75 cases, stage II (TxN1MO) 46 cases, stage III (TxN2MO) 33 cases and stage IV (TxNxM1) 55 cases. Lymph node involvement was more frequent in the prospective than in the retrospective study. With a more than 5 years' follow-up of 80 percent of the patients operated upon, the actuarial survival rate at 5 years (operative mortality included) was 38 percent for all lesions, 52 percent for curative resection and 2 percent for palliative resection. Following curative resection, the survival rates for tumours of the upper, middle and lower thirds of the stomach were 40, 60 and 55 percent respectively. These rates were 60 percent for stage I tumours, 54 percent for stage II tumours and 25 percent for stage III tumours. The results obtained in this series, where most of the curative gastrectomies included excision of N1 and N2 lymph nodes, show that lymph node involvement has no significant importance for the prognosis when it is proximal (N1) and is not incompatible with prolonged survival when it is pedicular (N2). PMID:1465364

  9. Underground research laboratory room 209 instrument array

    International Nuclear Information System (INIS)

    An in situ excavation response test was conducted at the Canadian Underground Research Laboratory (URL) in conjunction with excavation of a tunnel (Room 209) through a near-vertical water-bearing fracture oriented almost perpendicular to the tunnel axis. Encountering a fracture with such desirable characteristics provided a unique opportunity during construction of the URL to try out instrumentation and analytical methods for use in the Excavation Response Experiment (ERE), one of the major URL experiments. This is the first of four reports that cover the excavation response test. This report contains the information provided to the numerical modelling groups before the start of excavation. It includes survey information of the excavations within 30 m of the instrument array; the layout of the instrument array; details of the geology, rock properties, joint characteristics, in situ stresses, and in situ rock temperature distribution; the results of hydrogeological testing and monitoring; the planned excavation sequence; and the format for the modellers to present their results to facilitate easy comparison with the measured responses. Includes 13 excavation charts in back pocket

  10. Dicty_cDB: SSH209 [Dicty_cDB

    Lifescience Database Archive (English)

    Full Text Available g factor A genes, complete cds; and hypothetical translation initiation factor IF-2 gen...AF308672 |AF308672.1 Cowdria ruminantium clone 23hw hypothetical transmembrane protein and hypothetical ribosome-bindin...SS (Link to library) SSH209 (Link to dictyBase) - - - Contig-U05323-1 SSH209F (Link to Original site...ctyBase) Atlas ID - NBRP ID - dictyBase ID - Link to Contig Contig-U05323-1 Original site URL http://dict...ycdb.biol.tsukuba.ac.jp/CSM/SS/SSH2-A/SSH209Q.Seq.d/ Representative seq. ID SSH209F (Link to Original site

  11. Enhanced thermoelectric properties of phase-separating bismuth selenium telluride thin films via a two-step method

    International Nuclear Information System (INIS)

    A two-step method that combines homogeneous electron beam (EB) irradiation and thermal annealing has been developed to enhance the thermoelectric properties of nanocrystalline bismuth selenium telluride thin films. The thin films, prepared using a flash evaporation method, were treated with EB irradiation in a N2 atmosphere at room temperature and an acceleration voltage of 0.17 MeV. Thermal annealing was performed under Ar/H2 (5%) at 300 °C for 60 min. X-ray diffraction was used to determine that compositional phase separation between bismuth telluride and bismuth selenium telluride developed in the thin films exposed to higher EB doses and thermal annealing. We propose that the phase separation was induced by fluctuations in the distribution of selenium atoms after EB irradiation, followed by the migration of selenium atoms to more stable sites during thermal annealing. As a result, thin film crystallinity improved and mobility was significantly enhanced. This indicates that the phase separation resulting from the two-step method enhanced, rather than disturbed, the electron transport. Both the electrical conductivity and the Seebeck coefficient were improved following the two-step method. Consequently, the power factor of thin films that underwent the two-step method was enhanced to 20 times (from 0.96 to 21.0 μW/(cm K2) that of the thin films treated with EB irradiation alone

  12. Enhanced thermoelectric properties of phase-separating bismuth selenium telluride thin films via a two-step method

    Energy Technology Data Exchange (ETDEWEB)

    Takashiri, Masayuki, E-mail: takashiri@tokai-u.jp; Kurita, Kensuke [Department of Materials Science, Tokai University, 4-1-1 Kitakaname, Hiratsuka, Kanagawa 259-1292 (Japan); Hagino, Harutoshi; Miyazaki, Koji [Department of Mechanical and Control Engineering, Kyushu Institute of Technology, 1-1 Sensui, Tobata-ku, Kitakyushu 804-8550 (Japan); Tanaka, Saburo [Department of Mechanical Engineering, College of Engineering, Nihon University, 1 Nakagawara, Tokusada, Tamuramachi, Koriyama, Fukushima 963-8642 (Japan)

    2015-08-14

    A two-step method that combines homogeneous electron beam (EB) irradiation and thermal annealing has been developed to enhance the thermoelectric properties of nanocrystalline bismuth selenium telluride thin films. The thin films, prepared using a flash evaporation method, were treated with EB irradiation in a N{sub 2} atmosphere at room temperature and an acceleration voltage of 0.17 MeV. Thermal annealing was performed under Ar/H{sub 2} (5%) at 300 °C for 60 min. X-ray diffraction was used to determine that compositional phase separation between bismuth telluride and bismuth selenium telluride developed in the thin films exposed to higher EB doses and thermal annealing. We propose that the phase separation was induced by fluctuations in the distribution of selenium atoms after EB irradiation, followed by the migration of selenium atoms to more stable sites during thermal annealing. As a result, thin film crystallinity improved and mobility was significantly enhanced. This indicates that the phase separation resulting from the two-step method enhanced, rather than disturbed, the electron transport. Both the electrical conductivity and the Seebeck coefficient were improved following the two-step method. Consequently, the power factor of thin films that underwent the two-step method was enhanced to 20 times (from 0.96 to 21.0 μW/(cm K{sup 2}) that of the thin films treated with EB irradiation alone.

  13. Oxidation of steels in liquid lead bismuth: Oxygen control to achieve efficient corrosion protection

    Energy Technology Data Exchange (ETDEWEB)

    Martinelli, Laure, E-mail: laure.martinelli@cea.f [CEA, DEN, DPC, SCCME, Laboratoire d' Etude de la Corrosion Non Aqueuse, F-91191 Gif-sur-Yvette (France); Jean-Louis, Courouau; Fanny, Balbaud-Celerier [CEA, DEN, DPC, SCCME, Laboratoire d' Etude de la Corrosion Non Aqueuse, F-91191 Gif-sur-Yvette (France)

    2011-05-15

    Hybrid systems dedicated to waste transmutation are constituted of an accelerator generating a high energy proton flux, a spallation target on which the accelerated proton beam impinges to produce neutrons and a subcritical core. The Pb-Bi eutectic liquid alloy is considered as spallation target material due to its suitable nuclear and physical properties. However, liquid metals can be corrosive towards containment materials (austenitic and Fe9Cr alloys). In the case of liquid lead bismuth alloy, one of the protection means considered against the dissolution of the steels is the in situ protection by the formation of an oxide layer at the steels' surface. However, in order to ensure the efficient protection of the steels by an oxide layer, the control and the monitoring of the oxygen content in the Pb-Bi alloy is a major issue. The paper recalls, first, the oxygen chemistry in a lead alloy system, in order to propose the oxygen operating window that complies with both the contamination by lead oxide of the coolant and the corrosion control by the promotion of an oxide film on the structure. Results of tests performed in stagnant lead bismuth at high oxygen concentrations are also presented showing the effect of various operating parameters on the oxidation kinetics and on the nature of the oxide layer. An oxidation mechanism and model are also proposed and compared with experimental data.

  14. Evaluation in the use of bismuth shielding on cervical spine CT scan using a male phantom

    Energy Technology Data Exchange (ETDEWEB)

    Aleme, C.; Mourao, A. P. [Centro Federal de Educacion Tecnologica de Minas Gerais, Biomedical Engineering Center, Belo Horizonte - MG (Brazil); Lyra, M. A., E-mail: carolinaaleme@gmail.com [Universidad Federal de Minas Gerais, Department of Nuclear Engineering, Av. Pdte. Antonio Carlos 6627, Pampulha, 31270-91 Belo Horizonte - MG (Brazil)

    2014-08-15

    The cervical spine is the region of the column that articulates the head and chest. The tests of computed tomography (CT) performed in this region have as main objectives to diagnose fractures, dislocations and tumors. In CT scans the cervical spine volume is limited by the foramen Magnum and the first thoracic vertebra. In this region is the thyroid that is directly irradiated by X-ray beam during cervical scan. Based on this information, it was studied the dose variation deposited in thyroid and in nearby organs, such as: lenses, spinal cord in the foramen Magnum region and breasts, with and without the use of bismuth protector. In this study was used a male anthropomorphic phantom and thermoluminescent s dosimeters (TLD-100) were required to register the individual doses in the organs of interest. CT scans were performed on a GE Bright Speed scanner of 32 channels. With the data obtained, it was found the organ dose variation. The largest recorded dose was in the thyroid. Comparing two scans it was possible to note that the use of the bismuth protector promoted a 26% reduction in the thyroid dose and an increase in the lens dose. (Author)

  15. Evaluation in the use of bismuth shielding on cervical spine CT scan using a male phantom

    International Nuclear Information System (INIS)

    The cervical spine is the region of the column that articulates the head and chest. The tests of computed tomography (CT) performed in this region have as main objectives to diagnose fractures, dislocations and tumors. In CT scans the cervical spine volume is limited by the foramen Magnum and the first thoracic vertebra. In this region is the thyroid that is directly irradiated by X-ray beam during cervical scan. Based on this information, it was studied the dose variation deposited in thyroid and in nearby organs, such as: lenses, spinal cord in the foramen Magnum region and breasts, with and without the use of bismuth protector. In this study was used a male anthropomorphic phantom and thermoluminescent s dosimeters (TLD-100) were required to register the individual doses in the organs of interest. CT scans were performed on a GE Bright Speed scanner of 32 channels. With the data obtained, it was found the organ dose variation. The largest recorded dose was in the thyroid. Comparing two scans it was possible to note that the use of the bismuth protector promoted a 26% reduction in the thyroid dose and an increase in the lens dose. (Author)

  16. Treatment of ulcerative reflux oesophagitis with colloidal bismuth subcitrate in combination with cimetidine.

    OpenAIRE

    Borkent, M V; Beker, J A

    1988-01-01

    Twenty patients took part in a controlled double blind study comparing the efficacy of colloidal bismuth and cimetidine (800 mg at night) with cimetidine alone in the treatment of ulcerative reflux oesophagitis. Colloidal bismuth 120 mg was administered through an intraoesophageal tube four times a day. Cimetidine with colloidal bismuth gives significantly (p less than 0.001) better results than cimetidine alone. Of 10 patients treated with cimetidine and bismuth, seven had no endoscopic sign...

  17. Liquid Metal Embrittlement of a 9Cr-1Mo Ferritic-martensitic Steel in Lead-bismuth Eutectic Environment under Low Cycle Fatigue

    OpenAIRE

    Gong, Xing

    2015-01-01

    Ferritic-martensitic T91 steel is a candidate material for constructing the proton beam window of the MYRRHA nuclear reactor, which is being developed in SCK•CEN, Belgium for transmuting long-lived nuclear waste. As one important part of the MYRRHA material qualification program, liquid metal embrittlement (LME), a phenomenon could cause premature brittle failure of components, is crucial to be checked for T91 steel in contact with lead-bismuth eutectic (LBE) which is the coolant and spallati...

  18. Ultrasonication of Bismuth Telluride Nanocrystals Fabricated by Solvothermal Method

    Science.gov (United States)

    Chu, Sang-Hyon; Choi, Sang H.; Kim, Jae-Woo; King, Glen C.; Elliott, James R.

    2006-01-01

    The objective of this study is to evaluate the effect of ultrasonication on bismuth telluride nanocrystals prepared by solvothermal method. In this study, a low dimensional nanocrystal of bismuth telluride (Bi2Te3) was synthesized by a solvothermal process in an autoclave at 180 C and 200 psi. During the solvothermal reaction, organic surfactants effectively prevented unwanted aggregation of nanocrystals in a selected solvent while controlling the shape of the nanocrystal. The atomic ratio of bismuth and tellurium was determined by energy dispersive spectroscopy (EDS). The cavitational energy created by the ultrasonic probe was varied by the ultrasonication process time, while power amplitude remained constant. The nanocrystal size and its size distribution were measured by field emission scanning electron microscopy (FESEM) and a dynamic light scattering system. When the ultrasonication time increased, the average size of bismuth telluride nanocrystal gradually increased due to the direct collision of nanocrystals. The polydispersity of the nanocrystals showed a minimum when the ultrasonication was applied for 5 min. Keywords: bismuth telluride, nanocrystal, low-dimensional, ultrasonication, solvothermal

  19. Laser Spectroscopy of Neutron Rich Bismuth Isotopes

    CERN Multimedia

    2002-01-01

    %IS344 :\\\\ \\\\ The aim of the experiment is to measure the optical isotope shifts and hyperfine structures of bismuth isotopes across the N=126 shell closure in order to extract the change in mean square charge radii ($\\delta\\langle r^{2}\\rangle$) and static moments. These include the first isotones of lead to be measured directly above the shell closure and will provide new information on the systematics of the kink ($\\delta\\langle r^{2}\\rangle)$ seen in the lead isotopic chain. After two very successful runs the programme has been extended to include the neutron deficient isotopes below $^{201}$Bi to study the systematics across the $i_{13/2}$ neutron sub-shell closure at N=118.\\\\ \\\\ During the initial 2 runs (9 shifts) the isotope shifts and hyperfine structures of three new isotopes, $ ^{210,212,213}$Bi and the 9$^{-}$ isomer of $^{210}$Bi have been measured. The accuracy of the previous measurements of $^{205,206,208}$Bi have been greatly improved. The samples of $ ^{208,210,210^{m}}$Bi were prepared by c...

  20. Ultrasound in lead-bismuth eutectic

    International Nuclear Information System (INIS)

    The Belgian Nuclear Research Centre (SCK.CEN) is in the process of designing MYRRHA, a new multi-purpose irradiation facility to replace the ageing BR2. MYRRHA is a fast spectrum reactor cooled with lead-bismuth eutectic (LBE). As liquid metal is opaque to visual light, ultrasonic measurement techniques are selected to fulfill essential tasks that, according to our assessment, will be demanded by licensing authorities, in particular: fuel assembly identification and localization of a lost fuel assembly. To that end, a considerable research effort at SCK.CEN is devoted to study ultrasonic propagation in LBE. As ultrasonic experiments in LBE are elaborate and expensive to set up, we are particularly interested in to what extent experiments in water can be extrapolated to LBE - one of the main focuses of this article. We describe and present results of a first experiment with this goal which shows that the signal to noise ratio is better in LBE and that we even see small diffuse reflections up to 40 deg. off normal. On the other hand, we do not see internal reflections in stainless steel objects in LBE which we do in water. Therefore, we conclude that experiments in water can be used to validate algorithms for LBE on the condition that they do not rely on internal reflections. We also present solutions to tackle the essential tasks: fuel assembly identification and lost object localization. The requirements for the ultrasonic equipment implementing these solutions are also discussed. (authors)

  1. Laser-induced oxidation kinetics of bismuth surface microdroplets on GaAsBi studied in situ by Raman microprobe analysis.

    Science.gov (United States)

    Steele, J A; Lewis, R A

    2014-12-29

    We report the cw-laser-induced oxidation of molecular-beam-epitaxy grown GaAsBi bismuth surface microdroplets investigated in situ by micro-Raman spectroscopy under ambient conditions as a function of irradiation power and time. Our results reveal the surface droplets are high-purity crystalline bismuth and the resultant Bi2O3 transformation to be β-phase and stable at room temperature. A detailed Raman study of Bi microdroplet oxidation kinetics yields insights into the laser-induced oxidation process and offers useful real-time diagnostics. The temporal evolution of new β-Bi2O3 Raman modes is shown to be well described by Johnson-Mehl-Avrami-Kolmogorov kinetic transformation theory and while this study limits itself to the laser-induced oxidation of GaAsBi bismuth surface droplets, the results will find application within the wider context of bismuth laser-induced oxidation and direct Raman laser processing. PMID:25607191

  2. Use of Russian technology of ship reactors with lead-bismuth coolant in nuclear power

    International Nuclear Information System (INIS)

    The experience of using lead-bismuth coolant in Russian nuclear submarine reactors has been presented. The fundamental statements of the concept of using the reactors cooled by lead-bismuth alloy in nuclear power have been substantiated. The results of developments for using lead bismuth coolant in nuclear power have been presented. (author)

  3. 40 CFR 471.10 - Applicability; description of the lead-tin-bismuth forming subcategory.

    Science.gov (United States)

    2010-07-01

    ...-tin-bismuth forming subcategory. 471.10 Section 471.10 Protection of Environment ENVIRONMENTAL... POINT SOURCE CATEGORY Lead-Tin-Bismuth Forming Subcategory § 471.10 Applicability; description of the lead-tin-bismuth forming subcategory. This subpart applies to discharges of pollutants to waters of...

  4. Prognostic Value of Bismuth Typing and Modified T-stage in Hilar Cholangiocarcinoma

    Directory of Open Access Journals (Sweden)

    Shengen Yi

    2015-01-01

    Conclusion: The majority of our patients with HCC were characterized as Subtype IV in Bismuth typing and Stage T3 in modified T-stage. Both Bismuth typing and modified T-stage showed prognostic value in HCC. Compared with Bismuth typing, modified T-stage is a better indicator of the resectability of HCC.

  5. Comparative study of lead borate and bismuth lead borate glass systems as gamma-radiation shielding materials

    Science.gov (United States)

    Singh, Narveer; Singh, Kanwar Jit; Singh, Kulwant; Singh, Harvinder

    2004-09-01

    Gamma-ray mass attenuation coefficients have been measured experimentally and calculated theoretically for PbO-B 2O 3 and Bi 2O 3-PbO-B 2O 3 glass systems using narrow beam transmission method. These values have been used to calculate half value layer (HVL) parameter. These parameters have also been calculated theoretically for some standard radiation shielding concretes at same energies. Effect of replacing lead by bismuth has been analyzed in terms of density, molar volume and mass attenuation coefficient.

  6. Beam-Beam Effects

    OpenAIRE

    Herr, W; Pieloni, T.

    2016-01-01

    One of the most severe limitations in high-intensity particle colliders is the beam-beam interaction, i.e. the perturbation of the beams as they cross the opposing beams. This introduction to beam-beam effects concentrates on a description of the phenomena that are present in modern colliding beam facilities.

  7. Beam-Beam Effects

    CERN Document Server

    Herr, W

    2014-01-01

    One of the most severe limitations in high-intensity particle colliders is the beam-beam interaction, i.e. the perturbation of the beams as they cross the opposing beams. This introduction to beam-beam effects concentrates on a description of the phenomena that are present in modern colliding beam facilities.

  8. Phase transitions in the Hubbard model for the bismuth nickelate

    Science.gov (United States)

    Kojima, Shoya; Nasu, Joji; Koga, Akihisa

    2016-07-01

    We study low temperature properties of the Hubbard model for the bismuth nickelate, where degenerate orbitals in the nickel ions and a single orbital in the bismuth ions are taken into account, combining dynamical mean-field theory with the continuous-time quantum Monte Carlo method. We discuss the effect of the attractive interactions to mimic the valence skipping phenomenon in the bismuth ions. We demonstrate how the charge and magnetically ordered states are stable against thermal fluctuations. It is furthermore clarified that the ferromagnetically ordered and orbital ordered states are stabilized due to the presence of the orbital degeneracy at low temperatures. The crossover between metallic and insulating states is also discussed.

  9. Inexpensive laser-induced surface modification in bismuth thin films

    International Nuclear Information System (INIS)

    Highlights: • Laser-induced microbumps were formed on bismuth films using a simple, low-cost, laser setup. • The patterns, similar to those typically obtained with high-power lasers, were characterized. • Control of laser ablation conditions is critical in the fabrication of surface microbumps. - Abstract: In this work, we present results on texturing a 500 nm thick bismuth film, deposited by sputtering onto a glass slide using a low-cost homemade, near-infrared pulsed laser platform. A 785 nm laser diode of a CD–DVD pickup head was precisely focused on the sample mounted on a motorized two-axis translation stage to generate localized surface microbumps on the bismuth films. This simple method successfully transferred desired micropatterns on the films in a computer-numerical control fashion. Irradiated zones were characterized by atomic force microscopy and scanning electron microscopy. It was observed that final results are strongly dependent on irradiation parameters

  10. Inexpensive laser-induced surface modification in bismuth thin films

    Energy Technology Data Exchange (ETDEWEB)

    Contreras, A. Reyes [Facultad de Ciencias, Universidad Autónoma del Estado de México, Carretera Toluca, Ixtlahuaca Kilómetro 15.5, C.P. 50200 Edo. de México (Mexico); Hautefeuille, M., E-mail: mathieu_h@ciencias.unam.mx [Facultad de Ciencias, Universidad Nacional Autónoma de México, Avenida Universidad 3000, Circuito Exterior S/N, Coyoacán, Ciudad Universitaria, C.P. 04510 D.F. Mexico (Mexico); García, A. Esparza [Fotofísica y Películas Delgadas, Departamento de Tecnociencias, CCADET-UNAM, Circuito exterior s/n C.P. 04510 Cd. Universitaria, D.F. Mexico (Mexico); Mejia, O. Olea [Centro Conjunto de Investigación en Química Sustentable UAEM-UNAM, Carretera Toluca-Atlacomulco, Km 14.5, Unidad El Rosedal, 50200 San Cayetano, Estado de México (Mexico); López, M.A. Camacho [Facultad de Química, Universidad Autónoma del Estado de México, Tollocan s/n, esq. Paseo Colón, Toluca, Estado de México 50110 (Mexico)

    2015-05-01

    Highlights: • Laser-induced microbumps were formed on bismuth films using a simple, low-cost, laser setup. • The patterns, similar to those typically obtained with high-power lasers, were characterized. • Control of laser ablation conditions is critical in the fabrication of surface microbumps. - Abstract: In this work, we present results on texturing a 500 nm thick bismuth film, deposited by sputtering onto a glass slide using a low-cost homemade, near-infrared pulsed laser platform. A 785 nm laser diode of a CD–DVD pickup head was precisely focused on the sample mounted on a motorized two-axis translation stage to generate localized surface microbumps on the bismuth films. This simple method successfully transferred desired micropatterns on the films in a computer-numerical control fashion. Irradiated zones were characterized by atomic force microscopy and scanning electron microscopy. It was observed that final results are strongly dependent on irradiation parameters.

  11. Characterization of bismuth nanospheres deposited by plasma focus device

    International Nuclear Information System (INIS)

    A new method for producing thin layer of bismuth nanospheres based on the use of low energy plasma focus device is demonstrated. Various techniques such as scanning electron microscopy, Rutherford backscattering spectroscopy, X-ray diffraction, X-ray photoelectron spectroscopy, and Raman spectroscopy have been used to characterize the morphology and the composition of the nanospheres. Experimental parameters may be adjusted to favour the formation of bismuth nanospheres instead of microspheres. Therefore, the formation of large surface of homogeneous layer of bismuth nanospheres with sizes of below 100 nm can be obtained. The natural snowball phenomenon is observed to be reproduced in nanoscale where spheres roll over the small nanospheres and grow up to bigger sizes that can reach micro dimensions. The comet-like structure, a reverse phenomenon to snowball is also observed

  12. Mixed-phase bismuth ferrite nanoflake electrodes for supercapacitor application

    Science.gov (United States)

    Jadhav, Vijaykumar V.; Zate, Manohar K.; Liu, Shude; Naushad, Mu.; Mane, Rajaram S.; Hui, K. N.; Han, Sung-Hwan

    2016-04-01

    Nanoflake bismuth ferrite thin film was synthesized by means of electrodeposition technique at room temperature. The morphology and phase evaluation of the synthesized electrode were analyzed using scanning electron microscopy, X-ray diffraction, Raman spectroscopy, and surface wettability techniques. Specifically, the bismuth ferrite nanoflake electrode exhibited high specific capacitance of 72.2 F g-1 at a current density of 1 A g-1, and high rate capability with 37 % retention of capacitance even up to 20A g-1, and excellent cycling stability with 82.8 % retention of the initial capacitance after 1500 charge/discharge cycles, supporting that the bismuth ferrite thin-film electrode could be a potential candidate for supercapacitor application.

  13. Thermal, structural and electrical studies of bismuth zinc borate glasses

    Science.gov (United States)

    Shanmugavelu, B.; Ravi Kanth Kumar, V. V.

    2013-06-01

    Bismuth Zinc Borate glasses with compositions xBi2O3-30ZnO-(70 - x)B2O3 (where x = 30, 35, 40 and 45 mol %) have been prepared by melt quenching method. These glasses were characterized by X-ray diffraction (XRD), Differential Thermal Analysis (DTA), Fourier Transform Infrared Spectrometer (FTIR) and Broad Band Dielectric Spectrometer (BDS). DTA and FTIR analysis reveals that Non-Bridging Oxygens (NBOs) increase with increase of bismuth content in the glass. Electrical data have been analyzed in the framework of impedance and modulus formalisms. The activation energy for dc conductivity decreases with increase of bismuth concentration. The imaginary part of modulus spectra has been fitted to non-exponential Kohlrausch-Williams-Watts (KWW) function and the value of the stretched exponent (β) is found to be almost independent of temperature but slightly dependent on composition.

  14. Characterization of bismuth nanospheres deposited by plasma focus device

    Energy Technology Data Exchange (ETDEWEB)

    Ahmad, M., E-mail: cscientific2@aec.org.sy [IBA Laboratory, Chemistry Department, Atomic Energy Commission of Syria, P.O. Box 6091, Damascus (Syrian Arab Republic); Al-Hawat, Sh.; Akel, M. [Physics Department, Atomic Energy Commission of Syria, P.O. Box 6091, Damascus (Syrian Arab Republic); Mrad, O. [Chemistry Department, Atomic Energy Commission of Syria, P.O. Box 6091, Damascus (Syrian Arab Republic)

    2015-02-14

    A new method for producing thin layer of bismuth nanospheres based on the use of low energy plasma focus device is demonstrated. Various techniques such as scanning electron microscopy, Rutherford backscattering spectroscopy, X-ray diffraction, X-ray photoelectron spectroscopy, and Raman spectroscopy have been used to characterize the morphology and the composition of the nanospheres. Experimental parameters may be adjusted to favour the formation of bismuth nanospheres instead of microspheres. Therefore, the formation of large surface of homogeneous layer of bismuth nanospheres with sizes of below 100 nm can be obtained. The natural snowball phenomenon is observed to be reproduced in nanoscale where spheres roll over the small nanospheres and grow up to bigger sizes that can reach micro dimensions. The comet-like structure, a reverse phenomenon to snowball is also observed.

  15. Compact and Integrated Liquid Bismuth Propellant Feed System

    Science.gov (United States)

    Polzin, Kurt A.; Stanojev, Boris; Korman, Valentin; Gross, Jeffrey T.

    2007-01-01

    Operation of Hall thrusters with bismuth propellant has been shown to be a promising path toward high-power, high-performance, long-lifetime electric propulsion for spaceflight missions [1]. There has been considerable effort in the past three years aimed at resuscitating this promising technology and validating earlier experimental results indicating the advantages of a bismuth-fed Hall thruster. A critical element of the present effort is the precise metering of propellant to the thruster, since performance cannot be accurately assessed without an accurate accounting of mass flow rate. Earlier work used a pre./post-test propellant weighing scheme that did not provide any real-time measurement of mass flow rate while the thruster was firing, and makes subsequent performance calculations difficult. The motivation of the present work is to develop a precision liquid bismuth Propellant Management System (PMS) that provides hot, molten bismuth to the thruster while simultaneously monitoring in real-time the propellant mass flow rate. The system is a derivative of our previous propellant feed system [2], but the present system represents a more compact design. In addition, all control electronics are integrated into a single unit and designed to reside on a thrust stand and operate in the relevant vacuum environment where the thruster is operating, significantly increasing the present technology readiness level of liquid metal propellant feed systems. The design of various critical components in a bismuth PMS are described. These include the bismuth reservoir and pressurization system, 'hotspot' flow sensor, power system and integrated control system. Particular emphasis is given to selection of the electronics employed in this system and the methods that were used to isolate the power and control systems from the high-temperature portions of the feed system and thruster. Open loop calibration test results from the 'hotspot' flow sensor are reported, and results of

  16. Dynamics of Light-Absorption Variations Induced in a Bismuth Silicate Crystal by Visible Laser Illumination

    Science.gov (United States)

    Khudyakova, E. S.; Kisteneva, M. G.; Shandarov, S. M.; Kornienko, T. A.; Tolstik, A. L.; Kargin, Yu. F.

    2015-01-01

    We present the results of experimental studies of the dynamics of the photoinduced optical absorption in a bismuth silicate crystal subject to continuous laser irradiation with wavelengths of 532 and 655 nm. The semiconductor-laser light beam with the wavelength λ = 655 nm causes the crystal bleaching at this wavelength, whereas its exposure to a shorter-wavelength irradiation from the optical-spectrum green region with a wavelength of 532 nm increases the optical absorption at both wavelengths, of 532 and 655 nm. The experimental results are interpreted using the theoretical model which assumes that the crystal has deep defect centers of two types so that an electron at each of these centers can be in one of the states characterized by different photoionization cross sections.

  17. Lead-bismuth spallation target design of the accelerator-driven test facility (ADTF)

    International Nuclear Information System (INIS)

    A design methodology for the lead-bismuth eutectic (LBE) spallation target has been developed and applied for the accelerator-driven test facility (ADTF) target. This methodology includes the target interface with the subcritical multiplier (SCM) of the ADTF and the different engineering aspects of the target design, physics, heat-transfer, hydraulics, structural, radiological, and safety analyses. Several design constrains were defined and utilised for the target design process to satisfy different engineering requirements and to minimise the time and the cost of the design development. Interface requirements with the subcritical multiplier were defined based on target performance parameters and material damage issues to enhance the lifetime of the target structure. Different structural materials were considered to define the most promising candidate based on the current database including radiation effects. The developed target design has a coaxial geometrical configuration to minimise the target footprint and it is installed vertically along the SCM axis. LBE is the target material and the target coolant with ferritic steel (HT-9 Alloy) structural material. The proton beam has 8.33 mA current uniformly distributed and 8.14 cm beam radius resulting in a current density of 40 μA/cm2. The beam power is 5 MW and the proton energy is 600 MeV. The beam tube has 10 cm radius to accommodate the halo current. A hemi-spherical geometry is used for the target window, which is connected to the beam tube. The beam tube is enclosed inside two coaxial tubes to provide inlet and outlet manifolds for the LBE coolant. The inlet and the outlet coolant manifolds and the proton beam are entered from the top above the SCM. The paper describes the design criteria, engineering constraints, and the developed target design for the ADTF. (authors)

  18. Tin-silver-bismuth solders for electronics assembly

    Science.gov (United States)

    Vianco, Paul T.; Rejent, Jerome A.

    1995-01-01

    A lead-free solder alloy for electronic assemblies composed of a eutectic alloy of tin and silver with a bismuth addition, x, of 0tin effective to depress the melting point of the tin-silver composition to a desired level. Melting point ranges from about 218.degree. C. down to about 205.degree. C. depending an the amount of bismuth added to the eutectic tin-silver alloy as determined by DSC analysis, 10.degree. C./min. A preferred alloy composition is 91.84Sn-3.33Ag-4.83Bi (weight percent based on total alloy weight).

  19. High-Q bismuth silicate nonlinear glass microsphere resonators

    OpenAIRE

    Wang, Pengfei; Murugan, Ganapathy; Lee, Timothy; Ding, Ming; Brambilla, Gilberto; Semenova, Yuliya; Wu, Qiang; Koizumi,Fumihito; Farrell, Gerald

    2012-01-01

    The fabrication and characterization of a bismuth-silicate glass microsphere resonator has been demonstrated. At wavelengths near 1550 nm, high-modes can be efficiently excited in a 179-μm diameter bismuth-silicate glass microsphere via evanescent coupling using a tapered silica fiber with a waist diameter of circa 2 μm. Resonances with Q-factors as high as were observed. The dependence of the spectral response on variations in the input power level was studied in detail to gain an insight in...

  20. Lead–bismuth eutectic technology for Hyperion reactor

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, J., E-mail: Zhang.3558@osu.edu [Dept. of Mechanical and Aerospace Engineering, The Ohio State University, 201 W, 19th Avenue, Columbus, OH 43210 (United States); Nuclear Engineering and Nonproliferation Division, Los Alamos National Laboratory, Los Alamos, NM 87544 (United States); Kapernick, R.J.; McClure, P.R. [Nuclear Engineering and Nonproliferation Division, Los Alamos National Laboratory, Los Alamos, NM 87544 (United States); Trapp, T.J. [Hyperion Power Generation (United States)

    2013-10-15

    A small lead–bismuth eutectic-cooled reactor concept (referred to as the Hyperion reactor concept) is being studied at Los Alamos National Laboratory and Hyperion Power Generation. In this report, a critical assessment of the lead–bismuth eutectic technology for Hyperion reactor is presented based on currently available knowledge. Included are: material compatibility, oxygen control, thermal hydraulics, polonium control. The key advances in the technology and their applications to Hyperion reactor design are analyzed. Also, the near future studies in main areas of the technology are recommended for meeting the design requirements.

  1. Bismuth onion thin film in situ grown on silicon wafer synthesized through a hydrothermal approach

    International Nuclear Information System (INIS)

    Bismuth onion structured nanospheres with the same structure as carbon onions have been synthesized and observed. The nanospheres were synthesized through a hydrothermal method using bismuth hydroxide and silicon wafer as reactants. By controlling the heating temperature, heating time, and the pressure, nanoscale bismuth spheres can be in situ synthesized on silicon wafer, and forms a bismuth onion film on the substrate. The electronic property of the films was investigated. A formation mechanism of the formation of bismuth onions and the onion film has been proposed on the basis of experimental observations.

  2. Bismuth centred magnetic perovskite: A projected multiferroic

    International Nuclear Information System (INIS)

    In recent time substantial attention has been initiated to understand the physics behind multiferroism and to design new multiferroic materials. BiMnO3 and BiFeO3 are the well-studied Bi-centred multiferroic oxides. BiMnO3 is a ferromagnetic–ferroelectric (metastable) phase and require drastic conditions to synthesize. However, lanthanum substituted BiMnO3 phases stabilized at ambient pressure. It is thus of major importance to increase the number of ferromagnetic perovskites with Bi cations that could be designed under ambient conditions. In this article, we have presented an up to date report of investigations on Bi-centred magnetic perovskites, a prospective material for multiferroic application. Central focus is concentrated on La0.5Bi0.5MnO3 perovskite with various substitutions at different levels. A few of these perovskites are found to be of practical importance e.g. La0.5Bi0.5Mn0.67Co0.33O3 with high dielectric permittivity coupled with ferromagnetism. A comprehensive analysis of different physical functionalities and their interrelation for a wide range of compositions of these Bi-centred perovskites is presented. It has been found that the complex magnetic behaviour originates from mixed valence metal ions. The ferroelectricity is associated with the 6s2 lone pair of Bi3+ cations. The magnetic ground state influences the dielectric properties reflecting the multiferroism in a single material. - Highlights: • Multiferroics have attracted increasing attention due to their possible device applications. • Bismuth centred magnetic perovskite is one kind of such promising multiferroic materials. • Ferromagnetic Bi-perovskites, which are synthesized at ambient conditions, have been discussed

  3. A biokinetic study of {sup 209}Po in man

    Energy Technology Data Exchange (ETDEWEB)

    Henricsson, C.F.; Ranebo, Y. [Department of Medical Radiation Physics, Clinical Sciences in Lund, Lund University, Skane University Hospital in Lund (Sweden); Hansson, M. [Medical Radiation Physics, Department of Clinical Sciences in Malmoe, Lund University, Skane University Hospital in Malmoe (Sweden); Raeaef, C.L., E-mail: Christopher.Raaf@med.lu.se [Medical Radiation Physics, Department of Clinical Sciences in Malmoe, Lund University, Skane University Hospital in Malmoe (Sweden); Holm, E. [Norwegian Radiation Protection Authority, Osteras (Norway)

    2012-10-15

    Five adult volunteers participated in a biokinetic study of radioactive polonium. Portions of about 10 Bq of {sup 209}Po were orally administrated to four of the volunteers in a single ingestion. The fifth volunteer ingested a daily amount of 53 mBq of 209Po for 243 d to study the time to achieve equilibrium between intake and excretion for protracted intakes. For the subjects ingesting single intakes of {sup 209}Po complete sampling of urine and feces was subsequently collected the first few days upon the ingestion. The samples were processed with radiochemical extraction and analyzed with alpha spectrometry. In the study, the maximum daily excretion rates in feces were 18-50% of the ingested activity, observed within 3 d after intake. Regarding the urine excretion, the daily excretion peaked, on average, at 0.15-1% of the ingested activity within two days upon intake. These results indicate an average gastro-intestinal uptake fraction of 0.46 {+-} 0.08, which agrees well with earlier biokinetic studies of polonium in man. -- Highlights: Black-Right-Pointing-Pointer Human metabolism of an oral intake of polonium. Black-Right-Pointing-Pointer 4 individuals were administrated about 10 Bq polonium-209. Black-Right-Pointing-Pointer Gastro-intestinal uptake fraction, if orally administrated polonium-209 was investigated. Black-Right-Pointing-Pointer The biological half-time of polonium in human body was studied.

  4. The continuum shell-model neutron states of 209Pb

    Indian Academy of Sciences (India)

    Ramendra Nath Majumdar

    2003-12-01

    The neutron strength distributions of the three high-spin 117/2, 2ℎ11/2 and 113/2 states of 209Pb have been obtained within the formalism of the core-polarisation effect where the effect of interaction of the neutron shell-model states of 209Pb with the collective vibrational states (originating also from the giant resonances) have been taken into consideration. The theoretical results have been discussed in the light of works on 117/2, 2ℎ11/2 and 113/2 neutron orbitals of 209Pb. The shell-model energies of the neutron states have been obtained by Skyrme–Hartree–Fock method.

  5. Reducing the radiation dose to the eye lens region during CT brain examination: the potential beneficial effect of the combined use of bolus and a bismuth shield

    International Nuclear Information System (INIS)

    Objective: Computed Tomography (CT) is the leading contributor to medical exposure to ionizing radiation. Although the use of CT brain scans for patients with head injuries and convulsions has shown a tremendous growth, it has raised substantial concerns in the general public because of the risk of radiation-induced cataracts: the current available strategies to reduce the radiation dose to the eye lens region are limited. Therefore, the present research project was initiated with the aim of evaluating the potential benefit of the combined use of bolus and a bismuth shield on reducing the radiation dose to the eye lens region during CT brain examination. Materials and methods: We conducted a series of phantom studies to measure the entrance surface dose (ESD) that is delivered to the eye lens region during CT brain examination under the effect of different scanning and shielding setups. Results: Our results indicated, during CT brain examination: (1) a drastic reduction of 92.5% in the ESD to the eye lens region was found when the CT gantry was tilted from 0 deg. (overall ESD = 30.7 mGy) to 30 deg. cranially (overall ESD = 2.4 mGy), and (2) when the CT gantry was positioned at 0 deg. (the common practice in the clinical setting), the setups with the application of a) a bismuth shield, b) a bismuth shield with a face shield (air gap), c) a bismuth shield with bolus, and d) a bismuth shield with bolus and an air gap can result in an acceptable level of image quality with a smaller overall ESD delivered to the eye lens region (overall ESD = 23.2 mGy, 24 mGy, 21 mGy and 19.9 mGy, respectively) than the setup without the bismuth shield applied (overall ESD = 30.7 mGy). Conclusion: When the primary beam scanning through the eye lens region is unavoidable during CT brain examination, the combined use of a bismuth shield with bolus and a face shield is an easy-to-use and inexpensive shielding setup to reduce the radiation dose delivered to the eye lens region while

  6. Bismuth Ferrite for Active Control of Surface Plasmon Polariton Modes

    DEFF Research Database (Denmark)

    Babicheva, Viktoriia; Zhukovsky, Sergei; Lavrinenko, Andrei

    We propose and investigate several layouts of m etal-insulator-metal waveguide with active core which can be utilized for dynamic switching in photonic integrated circuits. The active material, bismuth ferrite (BiFeO3), is sandwiched between metal plates and changes i ts refractive index through ...

  7. Ultrafast electron diffraction studies of optically excited thin bismuth films

    International Nuclear Information System (INIS)

    This thesis contains work on the design and the realization of an experimental setup capable of providing sub-picosecond electron pulses for ultrafast electron diffraction experiments, and performing the study of ultrafast dynamics in bismuth after optical excitation using this setup. (orig.)

  8. Polymeric architectures of bismuth citrate based on dimeric building blocks

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    Four bismuth complexes, (H2En)[Bi2(cit)2(H2O)4/3]·(H2O)x (1), (H2En)3[Bi2(cit)2Cl4]·(H2O)x (2), (HPy)2[Bi2(cit)2(H2O)8/5]·(H2O)x (3) and (H2En)[Bi2(cit)2](H2O)x (4) [cit = citrate4-; En = ethylenediamine; Py = pyridine] have been synthesized and crystallized. The crystal structures reveal that the basic building blocks in all of these complexes are bismuth citrate dimeric units which combine to form polymeric architectures. The embedded protonated ethylenediamine and pyridine moieties in the polymeric frameworks have been identified by X-ray crystallography and solid-state cross polarization/magic angle spinning (CP/MAS) 13C NMR. Based on the framework of complex 1, a structural model of a clinically used antiulcer drug, ranitidine bismuth citrate (RBC) was generated. The behavior of the protonated amine-bismuth citrate complexes in acidic aqueous solution has been studied by electrospray ionization-mass spectrometry (ESI-MS).

  9. Bismuth Ferrite for Active Control of Surface Plasmon Polariton Modes

    DEFF Research Database (Denmark)

    Babicheva, Viktoriia; Zhukovsky, Sergei; Lavrinenko, Andrei

    2014-01-01

    We propose and investigate several layouts of m etal-insulator-metal waveguide with active core which can be utilized for dynamic switching in photonic integrated circuits. The active material, bismuth ferrite (BiFeO3), is sandwiched between metal plates and changes i ts refractive index through...

  10. Synthesis and structural characterization of Ce-doped bismuth titanate

    International Nuclear Information System (INIS)

    Ce-modified bismuth titanate nanopowders Bi4-xCexTi3O12 (x ≤ 1) have been synthesized using a coprecipitation method. DTA/TG, FTIR, XRD, SEM/EDS and BET methods were used in order to investigate the effect of Ce-substitution on the structure, morphology and sinterability of the obtained powders. The phase structure investigation revealed that after calcinations at 600 deg. C powder without Ce addition exhibited pure bismuth titanate phase; however, powders with Ce (x = 0.25, 0.5 and 0.75) had bismuth titanate pyrochlore phase as the second phase. The strongest effect of Ce addition on the structure was noted for the powder with the highest amount of Ce (x = 1) having a cubic pyrochlore structure. The presence of pure pyrochlore phase was explained by its stabilization due to the incorporation of cerium ions in titanate structure. Ce-modified bismuth titanate ceramic had a density over 95% of theoretical density and the fracture in transgranular manner most probably due to preferable distribution of Ce in boundary region

  11. Measured and evaluated neutron cross sections of elemental bismuth

    International Nuclear Information System (INIS)

    Neutron total cross sections of elemental bismuth are measured with broad resolution from 1.2 to 4.5 MeV to accuracies of approx. = 1%. Neutron-differential-elastic-scattering cross sections of bismuth are measured from 1.5 to 4.0 MeV at incident neutron energy intervals of approx.< 0.2 MeV over the scattered-neutron angular range approx. = 20 to 160 deg. Differential neutron cross sections for the excitation of observed states in bismuth at 895 +- 12, 1606 +- 14, 2590 +- 15, 2762 +- 29, 3022 +- 21, and 3144 +- 15 keV are determined at incident neutron energies up to 4.0 MeV. An optical-statistical model is deduced from the measured values. This model, the present experimental results, and information available elsewhere in the literature are used to construct a comprehensive evaluated nuclear data file for elemental bismuth in the ENDF format. The evaluated file is particularly suited to the neutronic needs of the fusion-fission hybrid designer. 87 references, 10 figures, 6 tables

  12. Ultrafast electronic dynamics in laser-excited crystalline bismuth

    Directory of Open Access Journals (Sweden)

    Chekalin S.

    2013-03-01

    Full Text Available Femtosecond spectroscopy was applied to capture complex dynamics of non equilibrium electrons in bismuth. Data analysis reveals significant wavevector dependence of electron-hole and electron-phonon coupling strength along the Γ-T direction of the Brillouin zone

  13. Ultrafast electron diffraction studies of optically excited thin bismuth films

    Energy Technology Data Exchange (ETDEWEB)

    Rajkovic, Ivan

    2008-10-21

    This thesis contains work on the design and the realization of an experimental setup capable of providing sub-picosecond electron pulses for ultrafast electron diffraction experiments, and performing the study of ultrafast dynamics in bismuth after optical excitation using this setup. (orig.)

  14. Surface depletion in the vacuum distillation of metals from bismuth

    International Nuclear Information System (INIS)

    Surface depletion was investigated in laboratory- and plant-scale distillation units with mixing by natural convection or by mechanical surface agitation. A model was developed for predicting the degree of surface depletion during the distillation of metals from bismuth as a function of temperature, still pot dimensions, and degree of agitation. This paper discusses those findings

  15. Discovery of the thallium, lead, bismuth, and polonium isotopes

    OpenAIRE

    Fry, C; Thoennessen, M

    2012-01-01

    Currently, forty-two thallium, forty-two lead, forty-one bismuth, and forty-two polonium isotopes have so far been observed; the discovery of these isotopes is discussed. For each isotope a brief summary of the first refereed publication, including the production and identification method, is presented.

  16. Third order nonlinear optical properties of bismuth zinc borate glasses

    International Nuclear Information System (INIS)

    Third order nonlinear optical characterization of bismuth zinc borate glasses are reported here using different laser pulse durations. Bismuth zinc borate glasses with compositions xBi2O3-30ZnO-(70-x) B2O3 (where x = 30, 35, 40, and 45 mol. %) have been prepared by melt quenching method. These glasses were characterized by Raman, UV-Vis absorption, and Z scan measurements. Raman and UV-Vis spectroscopic results indicate that non-bridging oxygens increase with increase of bismuth content in the glass. Nonlinear absorption and refraction behavior in the nanosecond (ns), picosecond (ps), and femtosecond (fs) time domains were studied in detail. Strong reverse saturable absorption due to dominant two-photon absorption (TPA) was observed with both ps and fs excitations. In the case of ns pulse excitations, TPA and free-carrier absorption processes contribute for the nonlinear absorption. Two-photon absorption coefficient (β) and the absorption cross section due to free carriers (σe) are estimated by theoretical fit of the open aperture Z-scan measurements and found to be dependent on the amount of bismuth oxide in the glass composition. In both ns and fs regimes the sign and magnitude of the third order nonlinearity are evaluated, and the optical limiting characteristics are also reported

  17. Third order nonlinear optical properties of bismuth zinc borate glasses

    Science.gov (United States)

    Shanmugavelu, B.; Ravi Kanth Kumar, V. V.; Kuladeep, R.; Narayana Rao, D.

    2013-12-01

    Third order nonlinear optical characterization of bismuth zinc borate glasses are reported here using different laser pulse durations. Bismuth zinc borate glasses with compositions xBi2O3-30ZnO-(70-x) B2O3 (where x = 30, 35, 40, and 45 mol. %) have been prepared by melt quenching method. These glasses were characterized by Raman, UV-Vis absorption, and Z scan measurements. Raman and UV-Vis spectroscopic results indicate that non-bridging oxygens increase with increase of bismuth content in the glass. Nonlinear absorption and refraction behavior in the nanosecond (ns), picosecond (ps), and femtosecond (fs) time domains were studied in detail. Strong reverse saturable absorption due to dominant two-photon absorption (TPA) was observed with both ps and fs excitations. In the case of ns pulse excitations, TPA and free-carrier absorption processes contribute for the nonlinear absorption. Two-photon absorption coefficient (β) and the absorption cross section due to free carriers (σe) are estimated by theoretical fit of the open aperture Z-scan measurements and found to be dependent on the amount of bismuth oxide in the glass composition. In both ns and fs regimes the sign and magnitude of the third order nonlinearity are evaluated, and the optical limiting characteristics are also reported.

  18. Third order nonlinear optical properties of bismuth zinc borate glasses

    Energy Technology Data Exchange (ETDEWEB)

    Shanmugavelu, B.; Ravi Kanth Kumar, V. V., E-mail: ravi.phy@pondiuni.edu.in [Department of Physics, Pondicherry University, Puducherry 605 014 (India); Kuladeep, R.; Narayana Rao, D. [School of Physics, University of Hyderabad, Hyderabad 500046, Andhra Pradesh (India)

    2013-12-28

    Third order nonlinear optical characterization of bismuth zinc borate glasses are reported here using different laser pulse durations. Bismuth zinc borate glasses with compositions xBi{sub 2}O{sub 3}-30ZnO-(70-x) B{sub 2}O{sub 3} (where x = 30, 35, 40, and 45 mol. %) have been prepared by melt quenching method. These glasses were characterized by Raman, UV-Vis absorption, and Z scan measurements. Raman and UV-Vis spectroscopic results indicate that non-bridging oxygens increase with increase of bismuth content in the glass. Nonlinear absorption and refraction behavior in the nanosecond (ns), picosecond (ps), and femtosecond (fs) time domains were studied in detail. Strong reverse saturable absorption due to dominant two-photon absorption (TPA) was observed with both ps and fs excitations. In the case of ns pulse excitations, TPA and free-carrier absorption processes contribute for the nonlinear absorption. Two-photon absorption coefficient (β) and the absorption cross section due to free carriers (σ{sub e}) are estimated by theoretical fit of the open aperture Z-scan measurements and found to be dependent on the amount of bismuth oxide in the glass composition. In both ns and fs regimes the sign and magnitude of the third order nonlinearity are evaluated, and the optical limiting characteristics are also reported.

  19. Bismuth-based oxide semiconductors: Mild synthesis and practical applications

    Science.gov (United States)

    Timmaji, Hari Krishna

    In this dissertation study, bismuth based oxide semiconductors were prepared using 'mild' synthesis techniques---electrodeposition and solution combustion synthesis. Potential environmental remediation and solar energy applications of the prepared oxides were evaluated. Bismuth vanadate (BiVO4) was prepared by electrodeposition and solution combustion synthesis. A two step electrosynthesis strategy was developed and demonstrated for the first time. In the first step, a Bi film was first electrodeposited on a Pt substrate from an acidic BiCl3 medium. Then, this film was anodically stripped in a medium containing hydrolyzed vanadium precursor, to generate Bi3+, and subsequent BiVO4 formation by in situ precipitation. The photoelectrochemical data were consistent with the in situ formation of n-type semiconductor films. In the solution combustion synthesis procedure, BiVO4 powders were prepared using bismuth nitrate pentahydrate as the bismuth precursor and either vanadium chloride or vanadium oxysulfate as the vanadium precursor. Urea, glycine, or citric acid was used as the fuel. The effect of the vanadium precursor on the photocatalytic activity of combustion synthesized BiVO 4 was evaluated in this study. Methyl orange was used as a probe to test the photocatalytic attributes of the combustion synthesized (CS) samples, and benchmarked against a commercial bismuth vanadate sample. The CS samples showed superior activity to the commercial benchmark sample, and samples derived from vanadium chloride were superior to vanadium oxysulfate counterparts. The photoelectrochemical properties of the various CS samples were also studied and these samples were shown to be useful both for environmental photocatalytic remediation and water photooxidation applications. Silver bismuth tungstate (AgBiW2O8) nanoparticles were prepared for the first time by solution combustion synthesis by using silver nitrate, bismuth nitrate, sodium tungstate as precursors for Ag, Bi, and W

  20. CFD analysis and optimization of a liquid lead–bismuth loop target for ISOL facilities

    International Nuclear Information System (INIS)

    In the context of the forthcoming next generation of Radioactive Ion Beams (RIBs) facilities based on an Isotope Separation On Line (ISOL) method, the development of production targets capable of dissipating the high power deposited by the primary beam is a major challenge. The concept of a high-power target based on a liquid Pb–Bi loop incorporating a heat-exchanger and a diffusion chamber was proposed within EURISOL DS and is being developed within the LIEBE project. Due to the non-static character of the target, specific hydrodynamics issues are of concern. In this paper, these issues are studied mostly based on three-dimensional (3D) Computational Fluid Dynamics analysis of the flow of the Lead Bismuth Eutectic (LBE) target, resulting in optimized designs. The concept and hydrodynamic challenges of generating RIBs from a liquid-metal-loop target irradiated with a high-power primary beam are presented. The optimization of the target design has been conducted keeping in mind the need for a fast and efficient release of short-lived isotopes. This study shows that approximately 100 ms after the proton pulse the irradiated liquid-metal is entirely and uniformly evacuated from the irradiation volume and spread in a shower of small droplets (100-μm radii), in order to reduce the diffusion length of isotopes. Solutions to deal with the typical cavitation risk due to the presence of low-pressure zones in the liquid have also been found and simulated

  1. CFD analysis and optimization of a liquid lead–bismuth loop target for ISOL facilities

    Energy Technology Data Exchange (ETDEWEB)

    Houngbo, D., E-mail: dhoungbo@sckcen.be [Belgian Nuclear Research Centre (SCK-CEN), Boeretang 200, B-2400 Mol (Belgium); Department of Flow, Heat and Combustion Mechanics, Ghent University (UGent), St.-Pietersnieuwstraat 41, B-9000 Gent (Belgium); Popescu, L.; Schuurmans, P. [Belgian Nuclear Research Centre (SCK-CEN), Boeretang 200, B-2400 Mol (Belgium); Delonca, M.; Losito, R.; Maglioni, C.; Stora, T. [CERN, 1211 Geneva 23 (Switzerland); Bricault, P. [TRIUMF, 4004 Wesbrook Mall, Vancouver, B.C., V6T 2A3 (Canada); Vierendeels, J. [Department of Flow, Heat and Combustion Mechanics, Ghent University (UGent), St.-Pietersnieuwstraat 41, B-9000 Gent (Belgium)

    2015-03-21

    In the context of the forthcoming next generation of Radioactive Ion Beams (RIBs) facilities based on an Isotope Separation On Line (ISOL) method, the development of production targets capable of dissipating the high power deposited by the primary beam is a major challenge. The concept of a high-power target based on a liquid Pb–Bi loop incorporating a heat-exchanger and a diffusion chamber was proposed within EURISOL DS and is being developed within the LIEBE project. Due to the non-static character of the target, specific hydrodynamics issues are of concern. In this paper, these issues are studied mostly based on three-dimensional (3D) Computational Fluid Dynamics analysis of the flow of the Lead Bismuth Eutectic (LBE) target, resulting in optimized designs. The concept and hydrodynamic challenges of generating RIBs from a liquid-metal-loop target irradiated with a high-power primary beam are presented. The optimization of the target design has been conducted keeping in mind the need for a fast and efficient release of short-lived isotopes. This study shows that approximately 100 ms after the proton pulse the irradiated liquid-metal is entirely and uniformly evacuated from the irradiation volume and spread in a shower of small droplets (100-μm radii), in order to reduce the diffusion length of isotopes. Solutions to deal with the typical cavitation risk due to the presence of low-pressure zones in the liquid have also been found and simulated.

  2. 48 CFR 3052.209-72 - Organizational conflict of interest.

    Science.gov (United States)

    2010-10-01

    ... CONTRACT CLAUSES Text of Provisions and Clauses 3052.209-72 Organizational conflict of interest. As prescribed in (HSAR) 48 CFR 3009.507-1, insert the following provision: Organizational Conflict of Interest... 48 Federal Acquisition Regulations System 7 2010-10-01 2010-10-01 false Organizational conflict...

  3. 48 CFR 3452.209-70 - Organizational conflict of interest.

    Science.gov (United States)

    2010-10-01

    ... 48 Federal Acquisition Regulations System 7 2010-10-01 2010-10-01 false Organizational conflict of... Clauses 3452.209-70 Organizational conflict of interest. As prescribed in 3409.570, insert the following provision in all certifications: Organizational Conflict of Interest (OCT 1987) The offeror certifies...

  4. Engineering study for closure of 209E facility

    International Nuclear Information System (INIS)

    This document is an engineering study for evaluating alternatives to determine the most cost effective closure plan for the 209E Facility, Critical Mass Laboratory. This laboratory is located in the 200 East Area of the Hanford Site and contains a Critical Assembly Room and a Mix room were criticality experiments were once performed

  5. 40 CFR 209.19 - Informal settlement and consent agreement.

    Science.gov (United States)

    2010-07-01

    ... ABATEMENT PROGRAMS RULES OF PRACTICE GOVERNING PROCEEDINGS UNDER THE NOISE CONTROL ACT OF 1972 Rules of Practice Governing Hearings for Orders Issued Under Section 11(d) of the Noise Control Act § 209.19...) admits the jurisdictional allegations of the complaint; (2) admits the facts as stipulated in the...

  6. 7 CFR 400.209 - Electronic transmission and receiving system.

    Science.gov (United States)

    2010-01-01

    ... Contract-Standards for Approval § 400.209 Electronic transmission and receiving system. Any Contractor under the Contract is required to: (a) Adopt a plan for the purpose of transmitting and receiving... 7 Agriculture 6 2010-01-01 2010-01-01 false Electronic transmission and receiving system....

  7. 27 CFR 27.209 - Used liquor bottles.

    Science.gov (United States)

    2010-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Used liquor bottles. 27..., DEPARTMENT OF THE TREASURY LIQUORS IMPORTATION OF DISTILLED SPIRITS, WINES, AND BEER Requirements for Liquor Bottles § 27.209 Used liquor bottles. The appropriate TTB officer may pursuant to letterhead...

  8. 48 CFR 952.209-72 - Organizational conflicts of interest.

    Science.gov (United States)

    2010-10-01

    ....209-72 Organizational conflicts of interest. As prescribed at 48 CFR 909.507-2, insert the following... (Contracting Officer see 48 CFR 909.507-2 and enter specific term) years after the completion of this contract... facts required to be disclosed or the existence of an actual or potential organizational conflict...

  9. 49 CFR 209.11 - Request for confidential treatment.

    Science.gov (United States)

    2010-10-01

    ... 49 Transportation 4 2010-10-01 2010-10-01 false Request for confidential treatment. 209.11 Section... confidential treatment. (a) This section governs the procedures for requesting confidential treatment of any... documents required to be submitted by FRA regulations, and all investigative and compliance activities,...

  10. 41 CFR 101-6.209-1 - Cooperation and assistance.

    Science.gov (United States)

    2010-07-01

    ... 41 Public Contracts and Property Management 2 2010-07-01 2010-07-01 true Cooperation and...-Nondiscrimination in Programs Receiving Federal Financial Assistance § 101-6.209-1 Cooperation and assistance. Each responsible GSA official shall to the fullest extent practicable seek the cooperation of recipients...

  11. 40 CFR 209.2 - Use of number and gender.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 24 2010-07-01 2010-07-01 false Use of number and gender. 209.2... gender. In these rules of practice, words in the singular number apply to the plural and words in the masculine gender apply to the feminine and vice versa....

  12. 15 CFR 971.209 - Processing outside the United States.

    Science.gov (United States)

    2010-01-01

    ... 15 Commerce and Foreign Trade 3 2010-01-01 2010-01-01 false Processing outside the United States... Applications Contents § 971.209 Processing outside the United States. (a) Except as provided in this section and § 971.408, the processing of hard minerals recovered pursuant to a permit shall be...

  13. 48 CFR 14.209 - Cancellation of invitations before opening.

    Science.gov (United States)

    2010-10-01

    ... REGULATION CONTRACTING METHODS AND CONTRACT TYPES SEALED BIDDING Solicitation of Bids 14.209 Cancellation of... invitation is desirable. (b) When an invitation issued other than electronically is cancelled, bids that have... prospective bidders to whom invitations were issued. When an invitation issued electronically is cancelled,...

  14. 9 CFR 113.209 - Rabies Vaccine, Killed Virus.

    Science.gov (United States)

    2010-01-01

    ... 5 U.S.C. 552(a) and 1 CFR part 51. Copies may be obtained from the World Health Organization... 9 Animals and Animal Products 1 2010-01-01 2010-01-01 false Rabies Vaccine, Killed Virus. 113.209... AGRICULTURE VIRUSES, SERUMS, TOXINS, AND ANALOGOUS PRODUCTS; ORGANISMS AND VECTORS STANDARD...

  15. 12 CFR 209.3 - Cancellation of Reserve Bank stock.

    Science.gov (United States)

    2010-01-01

    ... Section 209.3 Banks and Banking FEDERAL RESERVE SYSTEM BOARD OF GOVERNORS OF THE FEDERAL RESERVE SYSTEM... the Federal Reserve System, voluntarily liquidates or ceases business, is merged or consolidated into... by a state member bank, a vote to place a member bank in voluntary liquidation, or the appointment...

  16. 40 CFR 209.23 - Trade secrets and privileged information.

    Science.gov (United States)

    2010-07-01

    ... administrative law judge shall preserve the confidentiality of trade secrets and other privileged commercial and... 40 Protection of Environment 24 2010-07-01 2010-07-01 false Trade secrets and privileged... Practice Governing Hearings for Orders Issued Under Section 11(d) of the Noise Control Act § 209.23...

  17. Inclusive Jet Production in Photon-Photon Collisions at $\\sqrt{s_{ee}}$ from 189 to 209 GeV

    CERN Document Server

    Abbiendi, G; Åkesson, P F; Alexander, G; Anagnostou, G; Anderson, K J; Asai, S; Axen, D; Bailey, I; Barberio, E; Barillari, T; Barlow, R J; Batley, R J; Bechtle, P; Behnke, T; Bell, K W; Bell, P J; Bella, G; Bellerive, A; Benelli, G; Bethke, S; Biebel, O; Boeriu, O; Bock, P; Boutemeur, M; Braibant, S; Brown, R M; Burckhart, H J; Campana, S; Capiluppi, P; Carnegie, R K; Carter, A A; Carter, J R; Chang, C Y; Charlton, D G; Ciocca, C; Csilling, A; Cuffiani, M; Dado, S; Dallavalle, G M; de Roeck, A; De Wolf, E A; Desch, K; Dienes, B; Dubbert, J; Duchovni, E; Duckeck, G; Duerdoth, I P; Etzion, E; Fabbri, F; Ferrari, P; Fiedler, F; Fleck, I; Ford, M; Frey, A; Gagnon, P; Gary, J W; Geich-Gimbel, C; Giacomelli, G; Giacomelli, P; Giunta, M; Goldberg, J; Gross, E; Grunhaus, J; Gruwé, M; Sen-Gupta, A; Hajdu, C; Hamann, M; Hanson, G G; Harel, A; Hauschild, M; Hawkes, C M; Hawkings, R; Herten, G; Heuer, R D; Hill, J C; Horváth, D; Igo-Kemenes, P; Ishii, K; Jeremie, H; Jovanovic, P; Junk, T R; Kanzaki, J; Karlen, D; Kawagoe, K; Kawamoto, T; Keeler, R K; Kellogg, R G; Kennedy, B W; Kluth, S; Kobayashi, T; Kobel, M; Komamiya, S; Kramer, T; Krasznahorkay, A; Krieger, P; Von Krogh, J; Kühl, T; Kupper, M; Lafferty, G D; Landsman, H; Lanske, D; Lellouch, D; Letts, J; Levinson, L; Lillich, J; Lloyd, S L; Loebinger, F K; Lü, J; Ludwig, A; Ludwig, J; Mader, W; Marcellini, S; Martin, A J; Mashimo, T; Mättig, P; McKenna, J; McPherson, R A; Meijers, F; Menges, W; Merritt, F S; Mes, H; Meyer, N; Michelini, A; Mihara, S; Mikenberg, G; Miller, D J; Mohr, W; Mori, T; Mutter, A; Nagai, K; Nakamura, I; Nanjo, H; Neal, H A; Nisius, R; O'Neale, S W; Oh, A; Oreglia, M J; Orito, S; Pahl, C; Pásztor, G; Pater, J R; Pilcher, J E; Pinfold, J L; Plane, D E; Pooth, O; Przybycien, M; Quadt, A; Rabbertz, K; Rembser, C; Renkel, P; Roney, J M; Rossi, A M; Rozen, Y; Runge, K; Sachs, K; Saeki, T; Sarkisyan-Grinbaum, E; Schaile, A D; Schaile, O; Scharff-Hansen, P; Schiecks, J; Schörner-Sadenius, T; Schröder, M; Schumacher, M; Seuster, R; Shears, T G; Shen, B C; Sherwood, P; Skuja, A; Smith, A M; Sobie, R J; Söldner-Rembold, S; Spanó, F; Stahl, A; Strom, D; Ströhmer, R; Tarem, S; Tasevsky, M; Teuscher, R; Thomson, M A; Torrence, E; Toya, D; Tran, P; Trigger, I; Trócsányi, Z L; Tsur, E; Turner-Watson, M F; Ueda, I; Ujvári, B; Vollmer, C F; Vannerem, P; Vertesi, R; Verzocchi, M; Voss, H; Vossebeld, J; Ward, C P; Ward, D R; Watkins, P M; Watson, A T; Watson, N K; Wells, P S; Wengler, T; Wermes, N; Wilson, G W; Wilson, J A; Wolf, G; Wyatt, T R; Yamashita, S; Zer-Zion, D; Zivkovic, L

    2008-01-01

    Inclusive jet production (e+e- -> e+e- +jet+X) is studied in collisions of quasi-real photons radiated by the LEP beams at e+e- centre-of-mass energies sqrt see from 189 to 209 GeV. Jets are reconstructed using the kp jet algorithm. The inclusive differential cross-section is measured as a function of the jet transverse momentum, ptjet, in the range 5

  18. 41 CFR 101-27.209 - Utilization and distribution of shelf-life items.

    Science.gov (United States)

    2010-07-01

    ... distribution of shelf-life items. 101-27.209 Section 101-27.209 Public Contracts and Property Management... PROCUREMENT 27-INVENTORY MANAGEMENT 27.2-Management of Shelf-Life Materials § 101-27.209 Utilization and distribution of shelf-life items. Where it is determined that specified quantities of both Type I and Type...

  19. 41 CFR 101-6.209-3 - Access to sources of information.

    Science.gov (United States)

    2010-07-01

    ... information. 101-6.209-3 Section 101-6.209-3 Public Contracts and Property Management Federal Property...-Nondiscrimination in Programs Receiving Federal Financial Assistance § 101-6.209-3 Access to sources of information... business hours to such of its books, records, accounts, and other sources of information, and...

  20. 33 CFR 209.230 - Use of reservoir areas for recreation.

    Science.gov (United States)

    2010-07-01

    ... in 36 CFR parts 311 to 326. Licenses and leases are granted under the law containing conditions and... recreation. 209.230 Section 209.230 Navigation and Navigable Waters CORPS OF ENGINEERS, DEPARTMENT OF THE ARMY, DEPARTMENT OF DEFENSE ADMINISTRATIVE PROCEDURE § 209.230 Use of reservoir areas for...

  1. 8 CFR 209.2 - Adjustment of status of alien granted asylum.

    Science.gov (United States)

    2010-01-01

    ... 8 Aliens and Nationality 1 2010-01-01 2010-01-01 false Adjustment of status of alien granted asylum. 209.2 Section 209.2 Aliens and Nationality DEPARTMENT OF HOMELAND SECURITY IMMIGRATION REGULATIONS ADJUSTMENT OF STATUS OF REFUGEES AND ALIENS GRANTED ASYLUM § 209.2 Adjustment of status of...

  2. 24 CFR 570.209 - Guidelines for evaluating and selecting economic development projects.

    Science.gov (United States)

    2010-04-01

    ... selecting economic development projects. 570.209 Section 570.209 Housing and Urban Development Regulations... DEVELOPMENT BLOCK GRANTS Eligible Activities § 570.209 Guidelines for evaluating and selecting economic... activities to be carried out for economic development purposes. Specifically, these guidelines are...

  3. 48 CFR 1414.209-70 - Examination of records by the Department of the Interior.

    Science.gov (United States)

    2010-10-01

    ... the Department of the Interior. 1414.209-70 Section 1414.209-70 Federal Acquisition Regulations System DEPARTMENT OF THE INTERIOR CONTRACTING METHODS AND CONTRACT TYPES CONTRACTING BY NEGOTIATION Solicitation and Receipt of Proposals and Information 1414.209-70 Examination of records by the Department of the...

  4. 49 CFR 180.209 - Requirements for requalification of specification cylinders.

    Science.gov (United States)

    2010-10-01

    ... cylinders. 180.209 Section 180.209 Transportation Other Regulations Relating to Transportation PIPELINE AND... CONTINUING QUALIFICATION AND MAINTENANCE OF PACKAGINGS Qualification, Maintenance and Use of Cylinders § 180.209 Requirements for requalification of specification cylinders. (a) Periodic qualification...

  5. Hyperfine Clock Transitions of Bismuth Donors in Silicon Detected by Spin Dependent Recombination

    OpenAIRE

    Mortemousque, Pierre-André; Berger, Simon; Sekiguchi, Takeharu; Culan, Christophe; Elliman, Robert G.; Kohei M. Itoh

    2014-01-01

    Bismuth donors ion-implanted in $^{28}$Si and $^\\text{nat}$Si are studied using magnetic resonance spectroscopy based on spin dependent recombination. The hyperfine clock transition, at which the linewidth is significantly narrowed, is observed for the bismuth donors. The experimental results are modeled quantitatively by molecular orbital theory for a coupled pair consisting of a bismuth donor and a spin dependent recombination readout center, including the effect of hyperfine and Zeeman int...

  6. Bismuth nitrate-induced microwave-assisted expeditious synthesis of vanillin from curcumin

    OpenAIRE

    Bandyopadhyay, Debasish; Banik, Bimal K

    2012-01-01

    Background Curcumin and vanillin are the two useful compounds in food and medicine. Bismuth nitrate pentahydrate is an economical and ecofriendly reagent. Method Bismuth nitrate pentahydrate impregnated montmorillonite KSF clay and curcumin were subjected to microwave irradiation. Results Microwave-induced bismuth nitrate-promoted synthesis of vanillin from curcumin has been accomplished in good yield under solvent-free condition. Twenty-five different reaction conditions have been studied to...

  7. Rapid semi-quantitative determination of bismuth in minerals using ascending paper chromatography (1961)

    International Nuclear Information System (INIS)

    The bismuth is separated by a solvent made up of acetone, water, and hydrofluoric and hydrochloric acids. The bismuth is developed with dimercapto-2.5 thio-diazole-1.3.4 and ammonium sulphide. The use of this method for the detection of bismuth in minerals makes it possible to determine the metal at a concentration of 5 x 10-6. (author)

  8. Standard triple, bismuth pectin quadruple and sequential therapies for Helicobacter pylori eradication

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    AIM: To compare the effectiveness of standard triple, bismuth pectin quadruple and sequential therapies for Helicobacter pylori (H. pylori ) eradication in a randomized, double-blinded, comparative clinical trial in China. METHODS: A total of 215 H. pylori -positive patients were enrolled in the study and randomly allocated into three groups: group A (n = 72) received a 10-d bismuth pectin quadruple therapy (20 mg rabeprazole bid , 1000 mg amoxicillin bid , 100 mg bismuth pectin qid , and 500 mg levofloxaci...

  9. Influence of bismuth on structural, elastic and spectroscopic properties of Nd{sup 3+} doped Zinc–Boro-Bismuthate glasses

    Energy Technology Data Exchange (ETDEWEB)

    Gupta, Gaurav; Sontakke, Atul D.; Karmakar, P.; Biswas, K.; Balaji, S.; Saha, R.; Sen, R.; Annapurna, K., E-mail: annapurnak@cgcri.res.in

    2014-05-01

    The present investigation reports, influence of bismuth addition on structural, elastic and spectral properties of [(99.5−x) {4ZnO−3B_2O_3}−0.5Nd{sub 2}O{sub 3}−x Bi{sub 2}O{sub 3} where x=0, 5, 10, 20, 30, 40, 50 and 60] glasses. The measured FTIR reflectance spectra facilitated a thorough insight of methodical modifications that are arising in the glass structure from borate (build by BO{sub 3} and BO{sub 4} units) to bismuthate (BiO{sub 3} and BiO{sub 6} units) network due to the increase of bismuth content ensuing with a steady decrease in host phonon energy (ν{sub ph}). The elastic properties estimated from measured longitudinal and shear ultrasonic velocities (U{sub L} and U{sub s}) demonstrated the reduction in network rigidity of glasses on Bi{sub 2}O{sub 3} inclusion. The three phenomenological Judd–Ofelt intensity parameters (Ω{sub 2,4,6}) were obtained from recorded absorption spectra of Nd{sup 3+} ions in these glasses and have been used to predict radiative properties as a function of variation in bismuth content. The reduced host phonon energy and high optical basicity effect due to Bi{sub 2}O{sub 3} incorporation remarkably improved the Nd{sup 3+} luminescence properties such as emission intensity, quantum yield and emission cross-section. The quantum yield showed a strong increase from mere 16% in Zinc–Borate glass to almost 73% in 60 mol% Bi{sub 2}O{sub 3} containing glass. Similarly, the emission cross-section for Nd{sup 3+4}F{sub 3/2}→{sup 4}I{sub 11/2} laser transition raised from 2.43×10{sup −20} cm{sup 2} to 3.95×10{sup −20} cm{sup 2} in studied concentration suggesting a strong improvement in Nd{sup 3+} laser spectroscopic properties in Zinc–Boro-Bismuthate glass. These materials may be promising for compact solid state infrared lasers. - Highlights: • Continuous structural changes associated with reduction in host phonon energy by Bi{sub 2}O{sub 3} inclusion. • Ultrasonic velocity study revealed reduced Debye

  10. Influence of bismuth on structural, elastic and spectroscopic properties of Nd3+ doped Zinc–Boro-Bismuthate glasses

    International Nuclear Information System (INIS)

    The present investigation reports, influence of bismuth addition on structural, elastic and spectral properties of [(99.5−x) {4ZnO−3B2O3}−0.5Nd2O3−x Bi2O3 where x=0, 5, 10, 20, 30, 40, 50 and 60] glasses. The measured FTIR reflectance spectra facilitated a thorough insight of methodical modifications that are arising in the glass structure from borate (build by BO3 and BO4 units) to bismuthate (BiO3 and BiO6 units) network due to the increase of bismuth content ensuing with a steady decrease in host phonon energy (νph). The elastic properties estimated from measured longitudinal and shear ultrasonic velocities (UL and Us) demonstrated the reduction in network rigidity of glasses on Bi2O3 inclusion. The three phenomenological Judd–Ofelt intensity parameters (Ω2,4,6) were obtained from recorded absorption spectra of Nd3+ ions in these glasses and have been used to predict radiative properties as a function of variation in bismuth content. The reduced host phonon energy and high optical basicity effect due to Bi2O3 incorporation remarkably improved the Nd3+ luminescence properties such as emission intensity, quantum yield and emission cross-section. The quantum yield showed a strong increase from mere 16% in Zinc–Borate glass to almost 73% in 60 mol% Bi2O3 containing glass. Similarly, the emission cross-section for Nd3+4F3/2→4I11/2 laser transition raised from 2.43×10−20 cm2 to 3.95×10−20 cm2 in studied concentration suggesting a strong improvement in Nd3+ laser spectroscopic properties in Zinc–Boro-Bismuthate glass. These materials may be promising for compact solid state infrared lasers. - Highlights: • Continuous structural changes associated with reduction in host phonon energy by Bi2O3 inclusion. • Ultrasonic velocity study revealed reduced Debye temperature and elastic properties with bismuth addition. • Correlation of Judd–Ofelt parameters with structural modifications. • Realization of enhanced fluorescence quantum yield with

  11. Ion beam irradiated optical channel waveguides

    Czech Academy of Sciences Publication Activity Database

    Banyasz, I.; Rajta, I.; Nagy, G. U. L.; Zolnai, Z.; Havránek, Vladimír; Pelli, S.; Veres, M.; Himics, L.; Berneschi, S.; Nunzi-Conti, G.; Righini, G. C.

    Vol. 8988. Washington: SPIE International, 2014, s. 898814. ISBN 978-0-8194-9901-1. ISSN 0277-786X. [Conference on Integrated Optics - Devices, materials, and Technologies XVIII. San Francisco (US), 03.02.2014-05.02.2014] R&D Projects: GA MŠk LM2011019 Institutional support: RVO:61389005 Keywords : channel optical waveguides * ion beam irradiation * Er-doped tungsten-tellurite glass * bismuth germanate * SRIM simulation * phase contrast microscopy * micro Raman spectroscopy * focused ion beam Subject RIV: BH - Optics, Masers, Lasers

  12. Ab initio electronic structure and optical conductivity of bismuth tellurohalides

    CERN Document Server

    Schwalbe, Sebastian; Starke, Ronald; Schober, Giulio A H; Kortus, Jens

    2016-01-01

    We investigate the electronic structure, dielectric and optical properties of bismuth tellurohalides BiTeX (X = I, Cl, Br) by means of all-electron density functional theory. In particular, we present the ab initio conductivities and dielectric tensors calculated over a wide frequency range, and compare our results with the recent measurements by Akrap et al. , Makhnev et al. , and Rusinov et al. . We show how the low-frequency branch of the optical conductivity can be used to identify characteristic intra- and interband transitions between the Rashba spin-split bands in all three bismuth tellurohalides. We further calculate the refractive indices and dielectric constants, which in turn are systematically compared to previous predictions and measurements. We expect that our quantitative analysis will contribute to the general assessment of bulk Rashba materials for their potential use in spintronics devices.

  13. Chrysanthemum-like bismuth sulfide microcrystals: Synthesis, characterization, and properties

    Science.gov (United States)

    Jiang, Jinghui; Gao, Guanhua; Yu, Runnan; Qiu, Guanzhou; Liu, Xiaohe

    2011-02-01

    Uniform chrysanthemum-like bismuth sulfide (Bi 2S 3) microcrystals assembled from nanosheet building blocks were successfully synthesized via a convenient hydrothermal synthetic route under mild conditions in which hydrated bismuth nitrate and L-cysteine were employed to supply Bi and S source and ethylenediaminetetraacetic acid disodium salt (EDTA-Na 2) was employed as chelating agent. The influences of reaction temperatures and time on the morphologies of final products were investigated. The phase structures, morphologies, and properties of as-prepared products were investigated by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, high-resolution transmission electron microscope, and photoluminescence spectra. The possible growth mechanism for the formation of chrysanthemum-like Bi 2S 3 microcrystals was discussed on the basis of the experimental results.

  14. Quantum nernst effect in a bismuth single crystal

    International Nuclear Information System (INIS)

    We calculate the phonon-drag contribution to the transverse (Nernst) thermoelectric power Syx in a bismuth single crystal subjected to a quantizing magnetic field. The calculated heights of the Nernst peaks originating from the hole Landau levels and their temperature dependence reproduce the right order of magnitude for those of the pronounced magneto-oscillations recently reported by Behnia et al. A striking experimental finding that Syx is much larger than the longitudinal (Seebeck) thermoelectric power Sxx can be naturally explained as the effect of the phonon drag, combined with the well-known relation between the longitudinal and the Hall resistivity ρxx >> |ρyx| in a semi-metal bismuth. The calculation that includes the contribution of both holes and electrons suggests that some of the hitherto unexplained minor peaks located roughly at the fractional filling of the hole Landau levels are attributable to the electron Landau levels. (author)

  15. Thermophysical properties of liquid lead-bismuth eutectic

    International Nuclear Information System (INIS)

    Background: Liquid lead-bismuth eutectic (LBE) is important spallation target materials and candidate coolant materials in accelerator driven subcritical (ADS) system. Purpose: Its thermodynamic physical properties are keys to understand the basic problems in ADS R&D. Methods: By the calculation of scientific laws as well as fitting other scholars' experimental results, we tried to obtain the above thermodynamics physical properties. Results: By the calculation, we got formula about characteristic temperatures, density, specific heat, viscosity and thermal conductivity of liquid lead-bismuth alloy. And by fitting other scholars' experimental results, we got the fitting formula. Conclusions: Finally, by the contrast analysis, we found that the fitting formula and calculation formula agree well, and fitting formula more approaches the experimental value with a high accuracy whose differential deviation is not over 1%. (authors)

  16. Colloidal bismuth subcitrate in non-ulcer dyspepsia.

    Directory of Open Access Journals (Sweden)

    Khanna M

    1992-07-01

    Full Text Available The effect of colloidal bismuth subcitrate (De-Nol on symptoms, Helicobacter pylori status and histological features was studied in 35 patients with non-ulcer dyspepsia. Pain (34 cases and gas bloat (18 were the predominant symptoms. H pylori was present in 26 (74.3% patients. Gastritis and duodenitis were present in 29 of 32 and 22 of 31 cases respectively in whom biopsies were available. Relief in symptoms after treatment was seen in 29 (82.8% cases. Improvement in gastritis and duodenitis was noted in 60.8% and 58.8% respectively; over 70% of H pylori positive patients cleared the organism. These changes did not correlate with the relief in symptoms. We conclude that colloidal bismuth subcitrate is effective in the short term treatment of non-ulcer dyspepsia. It also clears H pylori infection and results in improvement of histological features.

  17. Effects of microwave sintering power on microstructure, dielectric, ferroelectric and magnetic properties of bismuth ferrite ceramics

    International Nuclear Information System (INIS)

    Highlights: ► Single-phase BFO ceramics have been prepared by microwave sintering. ► The lower sintering power is benefit for the decrease of its dielectric loss and leakage. ► Pr and Ec decrease with the increase of sintering power. ► Mr and Hc increase as sintering power increases. -- Abstract: Multiferroic bismuth ferrite ceramics were fabricated via microwave sintering. The microstructure, dielectric, ferroelectric and magnetic properties of bismuth ferrite ceramics sintered at different microwave powers are characterized by X-ray diffraction, scanning electron microscope, impedance analyzers, ferroelectric test system and vibrating sample magnetometer. Bismuth ferrite ceramics sintered at 3.4 kW is single phase and has dense structure and uniform grains. The lower microwave sintering power for bismuth ferrite ceramics is benefit for the decrease of its dielectric loss. The remnant polarization and coercive electric field of bismuth ferrite ceramics decrease with the increasing of microwave sintering power. The remnant polarization and the coercive electric field of bismuth ferrite ceramics decrease simultaneously as frequency increases. The leakage current of bismuth ferrite ceramics increases with the increase of microwave sintering power. Bismuth ferrite ceramics prepared by microwave sintering exhibit typical antiferromagnetic behaviors and the remnant magnetization and coercive magnetic field increase as the microwave sintering power increases. It is inferred that the optimum microwave sintering power for bismuth ferrite ceramics is 3.4 kW

  18. Optimal biliary drainage for inoperable Klatskin's tumor based on Bismuth type

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    AIM: To investigate differences in the effects of biliary drainage procedures in patients with inoperable Klatskin's tumor based on Bismuth type, considering endoscopic retrograde biliary drainage (ERBD), external percutaneous transhepatic biliary drainage (EPTBD) and internal biliary stenting via the PTBD tract (IPTBD).METHODS: The initial success rate, cumulative patency rate, and complication rate were compared retrospectively, according to the Bismuth type and ERBD,EPTBD, and IPTBD. Patency was defined as the duration for adequate initial bile drainage or to the point of the patient's death associated with inadequate drainage.RESULTS: One hundred thirty-four patients (93 men,41 women; 21 Bismuth type Ⅱ, 47 Ⅲ, 66 Ⅳ; 34 ERBD,66 EPTBD, 34 IPTBD) were recruited. There were no differences in demographics among the groups.Adequate initial relief of jaundice was achieved in 91% of patients without a significant difference in the results among different procedures or Bismuth types. The cumulative patency rates for ERBD and IPTBD were better than those for EPTBD with Bismuth type Ⅲ.IPTBD provided an excellent response for Bismuth type Ⅳ. However, there was no difference in the patency rate among drainage procedures for Bismuth type Ⅱ.Procedure-related cholangitis occurred less frequently with EPTBD than with ERBD and IPTBD.CONCLUSION: ERBD is recommended as the firstline drainage procedure for the palliation of jaundice in patients with inoperable Klatskin's tumor of Bismuth type Ⅱ or Ⅲ, but IPTBD is the best option for Bismuth type Ⅳ.

  19. Preparation of high-purity bismuth by sulphur deleadization in vacuum distillation

    Institute of Scientific and Technical Information of China (English)

    熊利芝; 何则强; 刘文萍; 麻成金; 戴永年

    2004-01-01

    The feasibility of separation of impurities in refined bismuth and sulphur deleadization with vacuum distillation was studied theoretically. Experimental studies on sulphur deleadization were carried out under vacuum.The influences of amount of sulphur, distillation temperature, vacuum degree and distillation time on deleadization were investigated and an optimal technical condition was achieved. The content of lead in refined bismuth can be decreased from 30 μg/g to 0.21 μg/g, which has reached the level of "5N" high-purity bismuth. Other impurities in refined bismuth can be also removed effectively under certain conditions.

  20. The Transmission of Thermal Neutrons through a Large Single Crystal of Bismuth at Liquid Nitrogen Temperature

    International Nuclear Information System (INIS)

    The transmission of a bismuth filter, at the temperature of liquid nitrogen, was measured using a slow chopper and a flight path of 5.4 m. The filter is made of two ''single crystals'', each 20 cm long and 5 cm in diameter. According to specification of the manufacturer each ''single crystal'' consists of maximum three of four columns of single crystals. In the energy range from 25 - 10 meV, the transmitted intensity is about 30% of the expected value. In the range from 5 meV to lower energies, the transmission is of the order of 60 - 70%. A cadmium ratio of 5000 was measured. The actual cadmium ratio may still be higher since the measurement was not made with a really fast neutron collimator. In spite of manv coherent dips in the transmission curve, the performance of the filter is rather satisfactory for thhe production of a thermal neutron beam that is predominantly free from fast neutrons and γ-rays. Possible applications of a filtered neutron beam are discussed. (author)

  1. Magnetic Properties of Bismuth Ferrite Nanopowder Obtained by Mechanochemical Synthesis

    OpenAIRE

    Szafraniak-Wiza, I.; Andrzejewski, B.; Hilczer, B.

    2014-01-01

    Multiferroic bismuth ferrite (BiFeO3) nanopowders have been obtained in room temperature by mechanical synthesis. Depending on the post-synthesis processing the nanopowders have exhibited differences in the mean sizes, presence of amorphous layer and/or secondary phases. Extended magnetic study performed for fresh, annealed and hot-pressed nanopowders have revealed substantial improvement of the magnetic properties in the as-prepared powder.

  2. The bismuth burden - a challenge for the accident insurance (Berufsgenossenschaften)

    International Nuclear Information System (INIS)

    The Soviet-German Bismuth AG was a state within a state in the former GDR. Uranium mining not only caused great ecological burdens but also gave rise to many problems for the accident insurance. Occupational diseases are of course, very important in the context of malignous growth caused by ionised radiation. The accident insurances (Berufsgenossenschaften) recognised the size of this unique problem and have initiated measures towards its solution. (orig.)

  3. Structural and electromechanical properties of bismuth-strontium titanate ceramics

    International Nuclear Information System (INIS)

    Bismuth-strontium titanate ceramics were obtained by conventional sinterization method (without orientation of grains - OF) and hot-forging (with oriented grains - HF). The physics, dielectrics and plutocracies properties these ceramics were compared. At piezoelectric characterization, the Kt values were higher in ceramics obtained by hot-forging (HF) when compared to ceramics obtained by OF, which indicates the high anisotropy of these materials. (author)

  4. Tunneling behavior of bismuth telluride nanoplates in electrical transport

    OpenAIRE

    Eginligil, Mustafa; Zhang, Weiqing; Kalitsov, Alan; Lu, Xianmao; Yang, Hyunsoo

    2012-01-01

    We study the electrical transport properties of ensembles of bismuth telluride (Bi2Te3) nanoplates grown by solution based chemical synthesis. Devices consisting of Bi2Te3 nanoplates are fabricated by surface treatment after dropping the solution on the structured gold plates and the temperature dependence of resistance shows a nonmetallic behavior. Symmetric tunneling behavior in I-V was observed in both our experimental results and theoretical calculation of surface conductance based on a s...

  5. In vivo cellular uptake of bismuth ions from shotgun pellets

    OpenAIRE

    Stoltenberg, M; Locht, L.; Larsen, Agnete; Jensen, D.

    2003-01-01

    Shotgun pellets containing bismuth (Bi) are widely used and may cause a rather intense exposure of some wild animals to Bi. A Bi shotgun pellet was implanted intramuscularly in the triceps surae muscle of 18 adult male Wistar rats. Another group of 9 animals had a Bi shotgun pellet implanted intracranially in the neocortex. Eight weeks to 12 months later the release of Bi ions was analysed by autometallography (AMG) of tissue sections from different organs (bra...

  6. Lead-bismuth coolant cleaning from solid impurities using filtration

    International Nuclear Information System (INIS)

    The factors, influencing the efficiency of the circuit cleaning of the lead-bismuth coolant from the solid phase impurities through filtration, are analyzed. The choice of the filtration material is substantiated proceeding from the properties of the given coolant as a dispersion system. The results of the experiments on determining the efficiency of cleaning capacity by retained impurities, throughput and regeneration made it possible to develop the industrial filters for the NPU needs

  7. Weak antilocalization and UCFs in an open bismuth quantum dot

    Science.gov (United States)

    Hackens, B.; Minet, J. P.; Farhi, G.; Faniel, G.; Gustin, C.; Bayot, V.

    2003-04-01

    We report on the observation of weak antilocalization and universal conductance fluctuations in the magnetoconductance of an open quasi-ballistic bismuth nano-cavity. The electron decoherence length is comparable to sample dimensions at low temperature, while the spin-orbit coupling length is smaller. The temperature dependence of both the conductance and the dephasing length are consistent with two-dimensional electron-electron interactions being the dominant decoherence process.

  8. Proton irradiation on textured bismuth based cuprate superconductors

    International Nuclear Information System (INIS)

    Textured bulk polycrystalline samples of bismuth based cuprate superconductors have been subjected to irradiation with 15 MeV protons. In case of Bi-2212, there has been substantial increase in Tc, which may be due to proton induced knock-out of loosely bound oxygen. In case of (Bi,Pb)-2223, there has been a reduction in Tc. The difference in behaviour in these two systems towards proton irradiation has been explained. (author). 7 refs., 3 figs., 1 tab

  9. Shape-controlled solvothermal synthesis of bismuth subcarbonate nanomaterials

    International Nuclear Information System (INIS)

    Much effort has been devoted to the synthesis of novel nanostructured materials because of their unique properties and potential applications. Bismuth subcarbonate ((BiO)2CO3) is one of commonly used antibacterial agents against Helicobacter pylori (H. pylori). Different (BiO)2CO3 nanostructures such as cube-like nanoparticles, nanobars and nanoplates, were fabricated from bismuth nitrate via a simple solvothermal method. The nanostructures were characterized by powder X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscopy (TEM) and high-resolution transmission electron microscopy (HRTEM). It was found that the solvents and precursors have an influence on the morphologies of (BiO)2CO3 nanostructures. The possible formation mechanism of different (BiO)2CO3 nanostructures fabricated under different conditions was also discussed. - Graphical abstract: Different bismuth subcarbonate ((BiO)2CO3) nanostructures were successfully synthesized by a simple solvothermal method. It was found that the solvents and precursors have an influence on the morphologies of (BiO)2CO3 nanostructures.

  10. Aerosol deposition of (Cu,Ti) substituted bismuth vanadate films

    International Nuclear Information System (INIS)

    Bismuth vanadate, Bi4V2O11, and related compounds with various metal (Me) substitutions, Bi4(MexV1−x)2O11−δ, show some of the highest ionic conductivities among the known solid oxide electrolytes. Films of Cu and Ti substituted bismuth vanadate were prepared by an aerosol deposition method, a spray coating process also described as room temperature impact consolidation. Resultant films, several microns in thickness, were dense with good adhesion to the substrate. Scanning electron microscopy and high temperature X-ray diffraction were used to monitor the effects of temperature on the structure and microstructure of the film. The particle size remained nano-scale while microstrain decreased rapidly up to 500 °C, above which coarsening and texturing increased rapidly. Impedance measurements of films deposited on inter-digital electrodes revealed an annealing effect on the ionic conductivity, with the conductivity exceeding that of a screen printed film, and approaching that of bulk ceramic. - Highlights: • Cu and Ti doped bismuth vanadate films were prepared by aerosol deposition (AD). • Dense 3–5 μm thick films were deposited on alumina, silicon and gold electrodes. • Annealing of the AD-layer increases the conductivity by 1.5 orders of magnitude. • Effect of temperature on structure and microstructure was investigated

  11. Atomic Layer Deposition of Bismuth Vanadates for Solar Energy Materials.

    Science.gov (United States)

    Stefik, Morgan

    2016-07-01

    The fabrication of porous nanocomposites is key to the advancement of energy conversion and storage devices that interface with electrolytes. Bismuth vanadate, BiVO4 , is a promising oxide for solar water splitting where the controlled fabrication of BiVO4 layers within porous, conducting scaffolds has remained a challenge. Here, the atomic layer deposition of bismuth vanadates is reported from BiPh3 , vanadium(V) oxytriisopropoxide, and water. The resulting films have tunable stoichiometry and may be crystallized to form the photoactive scheelite structure of BiVO4 . A selective etching process was used with vanadium-rich depositions to enable the synthesis of phase-pure BiVO4 after spinodal decomposition. BiVO4 thin films were measured for photoelectrochemical performance under AM 1.5 illumination. The average photocurrents were 1.17 mA cm(-2) at 1.23 V versus the reversible hydrogen electrode using a hole-scavenging sulfite electrolyte. The capability to deposit conformal bismuth vanadates will enable a new generation of nanocomposite architectures for solar water splitting. PMID:27246652

  12. Study of barium bismuth titanate prepared by mechanochemical synthesis

    Directory of Open Access Journals (Sweden)

    Lazarević Z.Ž.

    2009-01-01

    Full Text Available Barium-bismuth titanate, BaBi4Ti4O15 (BBT, a member of Aurivillius bismuth-based layer-structure perovskites, was prepared from stoichiometric amounts of barium titanate and bismuth titanate obtained via mechanochemical synthesis. Mechanochemical synthesis was performed in air atmosphere in a planetary ball mill. The reaction mechanism of BaBi4Ti4O15 and the preparation and characteristics of BBT ceramic powders were studied using XRD, Raman spectroscopy, particle analysis and SEM. The Bi-layered perovskite structure of BaBi4Ti4O15 ceramic forms at 1100 °C for 4 h without a pre-calcination step. The microstructure of BaBi4Ti4O15 exhibits plate-like grains typical for the Bi-layered structured material and spherical and polygonal grains. The Ba2+ addition leads to changes in the microstructure development, particularly in the change of the average grain size.

  13. Aerosol deposition of (Cu,Ti) substituted bismuth vanadate films

    Energy Technology Data Exchange (ETDEWEB)

    Exner, Jörg, E-mail: Functional.Materials@Uni-Bayreuth.de [University of Bayreuth, Department of Functional Materials, Universitätsstraße 30, 95440 Bayreuth (Germany); Fuierer, Paul [Materials and Metallurgical Engineering Department, New Mexico Institute of Mining and Technology, Socorro, NM 87801 (United States); Moos, Ralf [University of Bayreuth, Department of Functional Materials, Universitätsstraße 30, 95440 Bayreuth (Germany)

    2014-12-31

    Bismuth vanadate, Bi{sub 4}V{sub 2}O{sub 11}, and related compounds with various metal (Me) substitutions, Bi{sub 4}(Me{sub x}V{sub 1−x}){sub 2}O{sub 11−δ}, show some of the highest ionic conductivities among the known solid oxide electrolytes. Films of Cu and Ti substituted bismuth vanadate were prepared by an aerosol deposition method, a spray coating process also described as room temperature impact consolidation. Resultant films, several microns in thickness, were dense with good adhesion to the substrate. Scanning electron microscopy and high temperature X-ray diffraction were used to monitor the effects of temperature on the structure and microstructure of the film. The particle size remained nano-scale while microstrain decreased rapidly up to 500 °C, above which coarsening and texturing increased rapidly. Impedance measurements of films deposited on inter-digital electrodes revealed an annealing effect on the ionic conductivity, with the conductivity exceeding that of a screen printed film, and approaching that of bulk ceramic. - Highlights: • Cu and Ti doped bismuth vanadate films were prepared by aerosol deposition (AD). • Dense 3–5 μm thick films were deposited on alumina, silicon and gold electrodes. • Annealing of the AD-layer increases the conductivity by 1.5 orders of magnitude. • Effect of temperature on structure and microstructure was investigated.

  14. Beam-beam effects

    Energy Technology Data Exchange (ETDEWEB)

    Zholents, A.

    1994-12-01

    The term beam-beam effects is usually used to designate different phenomena associated with interactions of counter-rotating beams in storage rings. Typically, the authors speak about beam-beam effects when such interactions lead to an increase of the beam core size or to a reduction of the beam lifetime or to a growth of particle`s population in the beam halo and a correspondent increase of the background. Although observations of beam-beam effects are very similar in most storage rings, it is very likely that every particular case is largely unique and machine-dependent. This constitutes one of the problems in studying the beam-beam effects, because the experimental results are often obtained without characterizing a machine at the time of the experiment. Such machine parameters as a dynamic aperture, tune dependencies on amplitude of particle oscillations and energy, betatron phase advance between the interaction points and some others are not well known, thus making later analysis uncertain. The authors begin their discussion with demonstrations that beam-beam effects are closely related to non linear resonances. Then, they will show that a non linearity of the space charge field is responsible for the excitation of these resonances. After that, they will consider how beam-beam effects could be intensified by machine imperfections. Then, they will discuss a leading mechanism for the formation of the beam halo and will describe a new technique for beam tails and lifetime simulations. They will finish with a brief discussion of the coherent beam-beam effects.

  15. Multinucleon photonuclear reactions on {sup 209}Bi: Experiment and evaluation

    Energy Technology Data Exchange (ETDEWEB)

    Belyshev, S.S.; Kurilik, A.S. [Lomonosov Moscow State University, Department of Physics, Moscow (Russian Federation); Filipescu, D.M.; Tesileanu, O. [Extreme Light Infrastructure - Nuclear Physics/Horia Hulubei National Institute for R and D in Physics and Nuclear Engineering, Bucharest-Magurele (Romania); Gheoghe, I. [Extreme Light Infrastructure - Nuclear Physics/Horia Hulubei National Institute for R and D in Physics and Nuclear Engineering, Bucharest-Magurele (Romania); University of Bucharest, Faculty of Physics, Bucharest-Magurele (Romania); Ishkhanov, B.S. [Lomonosov Moscow State University, Department of Physics, Moscow (Russian Federation); Skobeltsyn Institute of Nuclear Physics, Lomonosov Moscow State University, Moscow (Russian Federation); Khankin, V.V.; Kuznetsov, A.A.; Orlin, V.N.; Peskov, N.N.; Stopani, K.A.; Varlamov, V.V. [Skobeltsyn Institute of Nuclear Physics, Lomonosov Moscow State University, Moscow (Russian Federation)

    2015-06-15

    Photon activation technique using bremsstrahlug with end-point energy 55.6 MeV is used to induce photonuclear reactions in a {sup 209}Bi target. Absolute yields and integrated cross sections of multiparticle reactions (γ, 2n-6n), (γ, 4n1p), and (γ, 5n1p) are obtained. The results are compared to predictions of statistical models using systematical and microscopic description of photoabsorption and to the result of evaluation of the partial photoneutron reaction cross sections. Based on a comparison with existing experimental photoneutron cross sections and model calculations, we make a conclusion that neutron multiplicity assignment in available photoneutron cross sections on {sup 209}Bi can be corrected and evaluated cross sections of (γ, 1n) and (γ, 2n) are obtained that are in an agreement with the obtained experimental results. (orig.)

  16. 209-E Building -- Response to ventilation failure evaluation

    International Nuclear Information System (INIS)

    This document provides an evaluation and recommendations for radiological workplace air monitoring and response to ventilation failure for the Critical Mass Laboratory, 209-E Building. The Critical Mass Laboratory, part of the 209-E Building, was designed to provide a heavily shielded room where plutonium and uranium liquid solutions could be brought into various critical configurations under readily controlled and monitored conditions. The facility is contained within a one-story L-shaped concrete block and reinforced concrete building. One wing houses offices, a control room, shops, and a common area while the other wing includes an equipment room, the change room, work areas, and the two-story Critical Assembly Room (CAR). Three of the rooms contain radiologically contaminated equipment and materials

  17. Properties of lead-bismuth coolant and perspectives of non-electric applications of lead-bismuth reactor

    International Nuclear Information System (INIS)

    Key physical and chemical properties of lead-bismuth eutectic alloy are reviewed. Based on the low chemical activity of the alloy to other work media, a new concept of direct contact heat exchangers is proposed. A series of experiments were performed to validate the concept, using water, model salt solutions of sodium chloride, and oil. Key experimental results are summarized in the report. (author)

  18. Bismuth Propellant Feed System Development at NASA-MSFC

    Science.gov (United States)

    Polzin, Kurt A.

    2007-01-01

    NASA-MSFC has been developing liquid metal propellant feed systems capable of delivering molten bismuth at a prescribed mass flow rate to the vaporizer of an electric thruster. The first such system was delivered to NASA-JPL as part of the Very High Isp Thruster with Anode Layer (VHITAL) program. In this system, the components pictured were placed in a vacuum chamber and heated while the control electronics were located outside the chamber. The system was successfully operated at JPL in conjunction with a propellant vaporizer, and data was obtained demonstrating a new liquid bismuth flow sensing technique developed at MSFC. The present effort is aimed at producing a feed-system for use in conjunction with a bismuth-fed Hall thruster developed by Busek Co. Developing this system is more ambitious, however, in that it is designed to self-contain all the control electronics inside the same vacuum chamber as an operating bismuth-fed thruster. Consequently, the entire system, including an on-board computer, DC-output power supplies, and a gas-pressurization electro-pneumatic regulator, must be designed to survive a vacuum environment and shielded to keep bismuth plasma from intruding on the electronics and causing a shortcircuit. In addition, the hot portions of the feed system must be thermally isolated from the electronics to avoid failure due to high heat loads. This is accomplished using a thermal protection system (TPS) consisting of multiple layers of aluminum foil. The only penetrations into the vacuum chamber are an electrically isolated (floating) 48 VDC line and a fiberoptic line. The 48 VDC provides power for operation of the power supplies and electronics co-located with the system in the vacuum chamber. The fiberoptic Ethernet connection is used to communicate user-input control commands to the on-board computer and transmit real-time data back to the external computer. The partially assembled second-generation system is shown. Before testing at Busek, a

  19. Unusual anti-thermal degradation of bismuth NIR luminescence in bismuth doped lithium tantalum silicate laser glasses.

    Science.gov (United States)

    Tan, Linling; Wang, Liping; Peng, Mingying; Xu, Shanhui; Zhang, Qinyuan

    2016-08-01

    For application of bismuth laser glasses in either fiber amplifier or laser, their performance stability in long run should be understood especially in extreme conditions. However, so far, there are few reports on it. Here, we found, after the cycle experiments on heating and cooling, that the proper increase of lithium content in lithium tantalum silicate laser glass can lead to unusual anti-thermal degradation of bismuth NIR luminescence, which completely differs from the scenario in germanate glass. FTIR, 29Si MAS NMR spectra, absorption and dynamic photoluminescence spectra are employed to unravel how this happens. The results illustrate that it should be due to the decrease of polymerization of silicate glass network, which in turn allows the regeneration at 250°C, and therefore, the content increase of bismuth NIR emission centers. In the meanwhile, we noticed though Bi luminescence can be thermally quenched its peak does not shift along with temperature, which seldom appears in laser materials. The unique property might guarantee the unshift of Bi fiber laser wavelength once such glass was made into fiber devices even as the environmental temperature changes. The role of lithium is discussed in the evolution of glass structures, the suppression of glass heterogeneity, and the thermal stability of Bi luminescence, and it should be helpful to design homogeneous silicate laser glass with outstanding thermal stability. PMID:27505827

  20. Study on corrosion test techniques in lead bismuth eutectic flow. Joint research report in JFY2002

    International Nuclear Information System (INIS)

    The evaluation of corrosion behaviors of core and structural materials in lead bismuth eutectic is one of the key issues for the utilization of lead bismuth eutectic as a coolant of the primary loops of lead bismuth cooled fast breeder reactors (FBRs) and the intermediate heat transport media of new-type steam generators of the sodium cooled FBRs. The purpose of the present study is to establish corrosion test techniques in lead bismuth eutectic flow. The techniques of steel corrosion test and oxygen control in flowing lead bismuth eutectic, and the technologies of a lead bismuth flow test at high temperature and high velocity were developed through corrosion test using a lead bismuth flow test loop of the Tokyo Institute of Technology in JFY2002. The major results are summarized as follows: (1) Techniques of fabrication, mount and rinse of corrosion specimens, measurement method of weight loss, and SEM/EDX analysis method have been established through lead bismuth corrosion test. (2) Weight losses were measured, corrosion and lead bismuth-adhered layers and eroded parts were observed in two 1000 hr-corrosion tests, and the results were compared with each other for twelve existing steels including ODS, F82H and SUH-3. (3) An oxygen sensor made of zirconia electrolyte structurally resistant to thermal stress and thermal shock was developed and tested in the lead bismuth flow loop. Good performance has been obtained. (4) An oxygen control method by injecting argon and hydrogen mixture gas containing steam into lead bismuth was applied to the lead bismuth flow loop, and technical issues for the development of the oxygen control method were extracted. (5) Technical measures for freezing and leakage of lead bismuth in the flow loop were accumulated. (6) Technical measures for flow rate decrease/blockage due to precipitation of oxide and corrosion products in a low temperature section of the lead bismuth flow loop were accumulated. (7) Electromagnetic flow meters with MI

  1. The accurate determination of bismuth in lead concentrates and other non-ferrous materials by AAS after separation and preconcentration of the bismuth with mercaptoacetic acid.

    Science.gov (United States)

    Howell, D J; Dohnt, B R

    1982-05-01

    A method for determining 0.0001% and upwards of bismuth in lead, zinc or copper concentrates, metals or alloys and other smelter residues is described. Bismuth is separated from lead, iron and gangue materials with mercaptoacetic acid after reduction of the iron with hydrazine. Large quantities of tin can be removed during the dissolution. An additional separation is made for materials high in copper and/or sulphate. The separated and concentrated bismuth is determined by atomic-absorption spectrometry using the Bi line at 223.1 nm. The proposed method also allows the simultaneous separation and determination of silver. PMID:18963145

  2. Breeding of New Maize Cultivar Danyu 209%玉米杂交种丹玉209的选育

    Institute of Scientific and Technical Information of China (English)

    陈晓旭; 岳辉; 王作英; 鲁俊田; 陈丽; 刘日尊; 左青

    2015-01-01

    丹玉209是丹东农业科学院、辽宁丹玉种业科技股份有限公司于2009年选育的中熟玉米品种。以玉米自交系 R88为母本,以自交系 L34为父本杂交组配而成的玉米杂交种,该杂交种具有高产、优质、抗倒伏、抗叶斑病和适应性广等特点。适应在辽宁省春播玉米区种植。种植密度适宜在5.25万株~6万株/ hm2。%Corn hybrid cultivar Danyu 209 was developed by Dan Dong Academy of Agricultural Sciences of Liaoning Province and Liaoning Danyu Seed Science and Technology Co. ,Ltd. Using inbred line R88 as fe-male parent and the L34 as male parent . According to the variety production test ,Danyu 209 has the charac-teristics of high yield,good quality,muli-resistance and wide adaptation. The variety is suitable for direct see-ding in spring in Liaoning province . The density of the variety was up to 52 500 plants / hm 2 ~ 60 000 plants /hm2 .

  3. Selective oxidation of propylene to acrolein by silica-supported bismuth molybdate catalysts

    DEFF Research Database (Denmark)

    Duc, Duc Truong; Ha, Hanh Nguyen; Fehrmann, Rasmus;

    2011-01-01

    Silica-supported bismuth molybdate catalysts have been prepared by impregnation, structurally characterized and examined as improved catalysts for the selective oxidation of propylene to acrolein. Catalysts with a wide range of loadings (from 10 to 90 wt%) of beta bismuth molybdate (β-Bi2Mo2O9) w...

  4. Attenuation and image quality in the use of protective bismuth in chest CT scans

    International Nuclear Information System (INIS)

    For chest CT scans are protective of bismuth (Bi) with the aim of reducing the dose in the breast. The aim of this study was to evaluate the attenuation with thermoluminescent dosimeters in the glandular dose average when using these protective breast CT scans and to evaluate the image quality with and without protective Bismuth.

  5. Electronic Properties of Tin and Bismuth from Angular Correlation of Annihilation Photons

    DEFF Research Database (Denmark)

    Mogensen, O.E.; Trumpy, Georg

    1969-01-01

    liquid-metal curves are smaller and of another form than the tails of polycrystalline curves; no Gaussian with only one adjustable constant factor can give a fit to both tails. No useful method for interpreting liquid-metal angular-correlation curves seems to exist. Two deformed bismuth samples gave......A linear slit setup has been used to obtain results of angular-correlation measurements in (a) tin single crystals in three orientations: [001], [100], and [110], (b) bismuth single crystals in four orientations: [111], [100], [1¯10], and [2¯1¯1], (c) solid and liquid tin and bismuth, and (d......) deformed bismuth. For both metals, the single-crystal angular-correlation curves lie near to the free-electron parabola. The tin curves show more anisotropy than the bismuth curves. An important result is the clear anisotropy found in the high-momentum part of the curves—the tails—for both metals. Little...

  6. Conjugate Heat Transfer and Thermal Mechanical Analysis for Liquid Metal Targets for High Power Electron Beams

    International Nuclear Information System (INIS)

    A conjugate heat transfer and thermal structural analysis was completed, with the objective of determining the following: Lead bismuth eutectic (LBE) peak temperature, free convective velocity patterns in the LBE, peak beam window temperature, and thermal stress/deformation in the window.

  7. Conjugate Heat Transfer and Thermal Mechanical Analysis for Liquid Metal Targets for High Power Electron Beams.

    Energy Technology Data Exchange (ETDEWEB)

    Olivas, Eric Richard [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2016-02-26

    A conjugate heat transfer and thermal structural analysis was completed, with the objective of determining the following: Lead bismuth eutectic (LBE) peak temperature, free convective velocity patterns in the LBE, peak beam window temperature, and thermal stress/deformation in the window.

  8. Conduction mechanism in bismuth silicate glasses containing titanium

    International Nuclear Information System (INIS)

    Bismuth silicate glasses mixed with different concentrations of titanium dioxide having compositions xTiO2–(60−x)Bi2O3–40SiO2 with x=0, 5, 10, 15 and 20 were prepared by the normal melt quench technique. The frequency dependence of the ac electrical conductivity of different compositions of titanium bismuth silicate glasses has been studied in the frequency range 10−1 Hz to 10 MHz and in the temperature range 623–703 K. The temperature and frequency dependent conductivity is found to obey Jonscher's universal power law for all the compositions of titanium bismuth silicate glass system. The dc conductivity (σdc), so called crossover frequency (ωH), and frequency exponent (s) have been estimated from the fitting of experimental data of ac conductivity with Jonscher's universal power law. Enthalpy to dissociate the cation from its original site next to a charge compensating center (Hf) and enthalpy of migration (Hm) have also been estimated. The conductivity data have been analyzed in terms of different theoretical models to determine the possible conduction mechanism. Analysis of the conductivity data and the frequency exponent shows that the correlated barrier hopping of electrons between Ti3+ and Ti4+ ions in the glasses is the most favorable mechanism for ac conduction. The temperature dependent dc conductivity has been analyzed in the framework of theoretical variable range hopping model (VRH) proposed by Mott which describe the hopping conduction in disordered semiconducting systems. The various polaron hopping parameters have also been deduced. Mott's VRH model is found to be in good agreement with experimental data and the values of inverse localization length of s-like wave function (α) obtained by this model with modifications suggested by Punia et al. are close to the ones reported for a number of oxide glasses

  9. Effect of FGMs on thermoelectric cooling properties of bismuth telluride

    International Nuclear Information System (INIS)

    Every thermoelectric material shows high performance at a specific narrow temperature range. The temperature range with high performance can be expanded by joining the materials with different peak temperature. This is the concept of an FGM. The FGMs for Peltier cooling materials have never been reported though the FGMs for thermoelectric power generation were reported to enhance conversion efficiency. Bismuth telluride is the best material for cooling devices at around room temperature. Then we investigated the thermoelectric cooling properties for bismuth telluride with two steps graded structure FGM. Two kinds of melt-grown materials of p-type bismuth telluride (hereafter, sample 1 and sample 2) were used. The samples 1 and 2 of 3 mm square x 2.5 mm were joined to form an FGM of 3 mm square x 5 mm in length by soldering with ultrasonic vibration. Thermoelectric cooling properties were evaluated by observing the maximum temperature drop to electric current when the high temperature side was kept constant. When the high temperature side is kept at 370 K, the temperature drop of the monolithic sample 1 was 34.6 K, and 39.7 K for sample 2, because of the difference of the carrier density. In the case of the FGM, the temperature drop was 45.2 K when the sample 1 was placed at the high temperature side. On the other hand, the temperature drop was only 27.6 K when the sample 2 was placed at the high temperature side. From these results, it is clear that high performance can be obtained by forming an FGM when the proper material arrangement is performed along the temperature gradient. (orig.)

  10. Yttrium bismuth titanate pyrochlore mixed oxides for photocatalytic hydrogen production

    Energy Technology Data Exchange (ETDEWEB)

    Merka, Oliver

    2012-10-18

    In this work, the sol-gel synthesis of new non-stoichiometric pyrochlore titanates and their application in photocatalytic hydrogen production is reported. Visible light response is achieved by introducing bismuth on the A site or by doping the B site by transition metal cations featuring partially filled d orbitals. This work clearly focusses on atomic scale structural changes induced by the systematical introduction of non-stoichiometry in pyrochlore mixed oxides and the resulting influence on the activity in photocatalytic hydrogen production. The materials were characterized in detail regarding their optical properties and their atomic structure. The pyrochlore structure tolerates tremendous stoichiometry variations. The non-stoichiometry in A{sub 2}O{sub 3} rich compositions is compensated by distortions in the cationic sub-lattice for the smaller Y{sup 3+} cation and by evolution of a secondary phase for the larger Bi{sup 3+} cation on the A site. For TiO{sub 2} rich compositions, the non-stoichiometry leads to a special vacancy formation in the A and optionally O' sites. It is shown that pyrochlore mixed oxides in the yttrium bismuth titanate system represent very active and promising materials for photocatalytic hydrogen production, if precisely and carefully tuned. Whereas Y{sub 2}Ti{sub 2}O{sub 7} yields stable hydrogen production rates over time, the bismuth richer compounds of YBiTi{sub 2}O{sub 7} and Bi{sub 2}Ti{sub 2}O{sub 7} are found to be not stable under irradiation. This drawback is overcome by applying a special co-catalyst system consisting of a precious metal core and a Cr{sub 2}O{sub 3} shell on the photocatalysts.

  11. Determination of lead-210 in bottom sediments via bismuth-210

    International Nuclear Information System (INIS)

    Determination of lead-210 in bottom sediments is applied for evaluation of sedimentation rates and sediments ages by concentration profiles of disequilibrated lead-210 from atmospheric sources. Advances in low level liquid scintillation spectrometry (LS) fitted for natural radioactivity measurements, permit to combine the possibility of immediate bismuth-210 separation with its radioactivity registration using LS spectrometer Quantulus (LKS-1220, Wallak, Finland). The method was tested on bottom sediment samples from Baltic Sea shelf, collected during the 76th cruise of RV 'Academician S. Vavilov'. (author) 6 refs.; 1 tab

  12. Thermal stimulation of exoelectronic emission in bismuth germanate single crystals

    Energy Technology Data Exchange (ETDEWEB)

    Kalent' ev, V.A.; Kargin, V.F.; Kargin, Yu.F.; Kortov, V.S.; Skorikov, V.M.; Shul' gin, B.V.

    1987-08-01

    A systematic study of the properties of Bi/sub 4/Ge/sub 3/O/sub 12/ (BGO) indicates that these crystals, along with photoemission (luminescence and scintillation) show exoelectronic emission following thermal excitation from x-ray irradiation. Samples of BGO studied in this paper were grown by the Czochralski method. It is found that the relationship between exoemission in BGO and ordinary GeO/sub 2/ indicates the dominant role played by perturbation of the germanium oxide sublattice in the emission process in bismuth germanate.

  13. Colloidal bismuth subcitrate in non-ulcer dyspepsia.

    OpenAIRE

    Khanna M; Abraham P; Nair N; Mistry F; Vora I

    1992-01-01

    The effect of colloidal bismuth subcitrate (De-Nol) on symptoms, Helicobacter pylori status and histological features was studied in 35 patients with non-ulcer dyspepsia. Pain (34 cases) and gas bloat (18) were the predominant symptoms. H pylori was present in 26 (74.3%) patients. Gastritis and duodenitis were present in 29 of 32 and 22 of 31 cases respectively in whom biopsies were available. Relief in symptoms after treatment was seen in 29 (82.8%) cases. Improvement in gastri...

  14. Fano interference for large-amplitude coherent phonons in bismuth

    International Nuclear Information System (INIS)

    We report femtosecond time-resolved measurements of lattice dynamics in bismuth made over a wide range of temperatures and excitation levels. We demonstrate that time-integrated Fourier transforms for both the fully symmetric A1g and doubly degenerate Eg coherent oscillations of large amplitude exhibit asymmetric line shapes described by the Fano formula. Measuring the real and imaginary part of the phonon self-energy, we attempt to identify the nature of the continuum responsible for the configuration mixing. Based on the measured pump and temperature dependences, we suggest that the continuum responsible for the interference includes both the electronic and lattice degrees of freedom

  15. Melting and solidification of bismuth inclusions in aluminium

    DEFF Research Database (Denmark)

    Thoft, N.B.; Bohr, J.; Buras, B.;

    1995-01-01

    experimental methods (and on different samples) agree remarkably well. The inclusions melt at temperatures at or below the bismuth bulk melting point, and the solid/liquid phase transition exhibits a hysteresis of 100-150 K. Average inclusion sizes ranged from a few nm to some tens of nm. The x-ray diffraction...... melting data are discussed in relation to different existing models for the melting temperature of an inclusion as a function of its size. From this an approximate size distribution for the inclusions is derived....

  16. STM observation of twin microlayers on cleaved bismuth surfaces

    Science.gov (United States)

    Edel'man, V. S.

    1996-02-01

    Scanning tunneling microscopy of cleaved bismuth surfaces at low temperatures revealed the presence of thin twin microlayers, whose width ∼70 Å is determined by the fact that the height gained in crossing such a microlayer due to its tilt with respect to the surface of the undisturbed crystal equals the interlunar distance in the [0001] direction. The microlayers were strictly aligned with the surface atomic rows. Their lengths were macroscopically large, being no smaller than a few fractions of a micron. It was found that, near the microlayer boundaries, the electron properties were significantly different from those at other points on the surface.

  17. Toxic effects of decabromodiphenyl ether (BDE-209 on human embryonic kidney cells

    Directory of Open Access Journals (Sweden)

    Min eLi

    2014-05-01

    Full Text Available Polybrominated diphenyl ethers (PBDEs are widely used as flame-retardant additives in consumer and household products and can escape into the environment over time. PBDEs have become a global environmental organic pollutant due to the properties of persistence, toxicity, and bioaccumulation. The well-studied toxic effects of PBDEs mainly include thyroid hormone disruption and neurotoxicity. There is no consistent conclusions on the carcinogenic potential of PBDEs to date. Here, we explored the toxic effects of BDE-209 on human embryonic kidney cells (HEK293T. The comparison of the gene expression profiles of HEK293T cells with BDE-209 treatment and the negative control found that BDE-209 exposure may alter nucleosome organization through significantly changing the expression of histone gene clusters. The remodeled chromatin structure could further disturb systemic lupus erythematosus as one of the toxic effects of BDE-209. Additionally, gene sets of different cancer modules are positively correlated with BDE-209 exposure. This suggests that BDE-209 has carcinogenic potential for a variety of tumors. Collectively, BDE-209 has a broader toxicity not limited to disruption of thyroid hormone-related biological processes. Notably, the toxic effects of BDE-209 dissolved in dimethyl sulfoxide (DMSO is not the simply additive effects of BDE-209 and DMSO alone.

  18. Investigation of corrosion, water reaction, polonium evaporation and bismuth resource in liquid metal lead-bismuth technology

    Energy Technology Data Exchange (ETDEWEB)

    Takano, Hideki; Takizuka, Takakazu [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment; Kitano, Teruaki [Mitsui Shipbuilding and Engineering Co. Ltd., Tokyo (Japan)

    2000-10-01

    Lead-bismuth is the first candidate material for liquid metal target find coolant of fueled blanket system in accelerator-driven system (ADS) studied at JAERI. Advantages of the lead-bismuth utilization are non-active material, very low capture cross section, low melting point of 125degC and high boiling point of 1670degC, and beside coolant void reactivity become negative. But problems are due to the high corrosivity to most of the structural materials and the corrosive data are scarcity. In this report, corrosivity, reaction with water, thermal-hydraulics, chemical toxicity etc. are studied by investigating some facilities utilized and researched really for lead or lead-bismuth. And, furthermore, polonium evaporation rate and bismuth resource are investigated. Main results obtained are as follows: (1) In a refinery, there are enough employment experience for liquid Pb-Bi in period of about 17 years and not corrosion for the thermal conductive materials (1Cr-0.5Mo steel) used under the condition of natural convection with temperature around 400degC. (2) In Russia, extensive experience in the use as Russian submarines and in R and D during about 50 years are available. And as a result, it will be able to lead approximately zero corrosion for Cr-Si materials by adjusting oxygen film with oxygen concentration control between 10{sup -7} to 10{sup -5}% mass. However, the corrosion data are not enough systematically collected involving them in radiation dose field. (3) In liquid-dropping experiment, it is shown that interaction between water and high temperature liquid Pb-Bi is reduced steeply with rising of atmosphere pressure. But, in order to design the second circuit removal model of ADS, the interaction should be evaluated by water continuous injection experiment. (4) Polonium forms PbPo in Pb-Bi, and the evaporation rate become less three factor than that of Po, and furthermore, the rate decreases in the atmosphere. The effects of Po on employee and environment

  19. Investigation of corrosion, water reaction, polonium evaporation and bismuth resource in liquid metal lead-bismuth technology

    International Nuclear Information System (INIS)

    Lead-bismuth is the first candidate material for liquid metal target find coolant of fueled blanket system in accelerator-driven system (ADS) studied at JAERI. Advantages of the lead-bismuth utilization are non-active material, very low capture cross section, low melting point of 125degC and high boiling point of 1670degC, and beside coolant void reactivity become negative. But problems are due to the high corrosivity to most of the structural materials and the corrosive data are scarcity. In this report, corrosivity, reaction with water, thermal-hydraulics, chemical toxicity etc. are studied by investigating some facilities utilized and researched really for lead or lead-bismuth. And, furthermore, polonium evaporation rate and bismuth resource are investigated. Main results obtained are as follows: (1) In a refinery, there are enough employment experience for liquid Pb-Bi in period of about 17 years and not corrosion for the thermal conductive materials (1Cr-0.5Mo steel) used under the condition of natural convection with temperature around 400degC. (2) In Russia, extensive experience in the use as Russian submarines and in R and D during about 50 years are available. And as a result, it will be able to lead approximately zero corrosion for Cr-Si materials by adjusting oxygen film with oxygen concentration control between 10-7 to 10-5% mass. However, the corrosion data are not enough systematically collected involving them in radiation dose field. (3) In liquid-dropping experiment, it is shown that interaction between water and high temperature liquid Pb-Bi is reduced steeply with rising of atmosphere pressure. But, in order to design the second circuit removal model of ADS, the interaction should be evaluated by water continuous injection experiment. (4) Polonium forms PbPo in Pb-Bi, and the evaporation rate become less three factor than that of Po, and furthermore, the rate decreases in the atmosphere. The effects of Po on employee and environment will not be

  20. Synthesis and characterization of bismuth alkaline titanate powders

    International Nuclear Information System (INIS)

    In this work, samples of bismuth alkaline titanate, (K0.5Na0.5)(2-x/2)Bi(x/6)TiO3, (x = 0.05-0.75) have been prepared by conventional ceramic technique and molten salts. Metal oxides or carbonates powders were used as starting raw materials. The crystalline phase of the synthesized powders was identified by the X-ray diffraction (XRD) and particle morphology was characterized by scanning electron microscopy (SEM). Solid state reaction method was unsuccessful to obtain pellets. From XRD results, a rhombohedral structure was detected and the parameter lattice were estimated to be a = 5.5478 A and α = 59.48o. These parameters were used to refine the structure by Rietveld analysis. SEM results showed several morphologies. Apparently, bismuth is promoting the grain growth whose sizes vary from 30 nm to 180 nm It is expected that these materials can be utilized in practical applications as substitutes for lead zirconatetitanate (PZT)-based ceramics.

  1. Production of bismuth germanate ceramic scintillators by combustion synthesis route

    International Nuclear Information System (INIS)

    The present work presents the results from production of ceramic scintillator Bi4Ge3O12 (bismuth germanate – BGO), which is very sensitive to beta, gamma and X-rays. The production route adopted was combustion synthesis. In this route, the precursors germanium oxide and bismuth nitrate were mixed to urea, used as fuel, and heated up to the ignition temperature, 500 °C. The ignition starts an exothermic reaction that promotes the formation of the desired crystalline phase. It was observed a dependency of the agglomeration of the synthesized powders upon the pH of the initial mixture. The pH was controlled through the addition of ammonium dioxide, and was varied from zero up to 9. Intermediate crystalline phases were observed by DRX measurements of the product of the combustion reaction. After calcination at 600 °C/24 h, the Bi12GeO20 content was enhanced. The optimum conditions of synthesis and sintering of the samples were determined through auxiliary techniques such as DTA and SEM. The synthesized powders presented particle size near 10 nm, whereas the sintered grains reached near 2 μm. The relative density of sintered ceramics, obtained from Archimedes’ method, was 96%. (author)

  2. Field-induced polarization of Dirac valleys in bismuth

    Science.gov (United States)

    Behnia, Kamran; Zhu, Zengwei; Callaudin, Aurelie; Fauque, Benoit; Kang, Woun

    2012-02-01

    The principal challenge in the field of ``valleytronics'' is to lift the valley degeneracy of electrons in a controlled way. In graphene, a number of methods to generate a valley-polarized flow of electrons have been proposed, which are yet to be experimentally realized. In bulk semi-metallic bismuth, the Fermi surface includes three cigar-shaped electron valleys lying almost perpendicular to the high-symmetry axis known as the trigonal axis. The in-plane mass anisotropy of each valley exceeds 200 as a consequence of Dirac dispersion, which drastically reduces the effective mass along two out of the three orientations. We present a study of angle-dependent magnetoresistance in bismuth which shows that a flow of Dirac electrons along the trigonal axis is extremely sensitive to the orientation of in-plane magnetic field. The effect is visible even at room temperature. Thus, a rotatable magnetic field can be used as a valley valve to tune the contribution of each valley to the total conductivity. At high temperature and low magnetic field, the three valleys are interchangeable and the three-fold symmetry of the underlying lattice is respected. As the temperature is decreased or the magnetic field increased, this symmetry is spontaneously lost. This loss may be an experimental manifestation of the recently proposed valley-nematic Fermi liquid state.

  3. Electrodeposition of bismuth alloys by the controlled potential method

    International Nuclear Information System (INIS)

    We worked with the electrodeposition of three bismuth alloys, the composition of the first electrolyte was: 0.3 g/l. Bi; 20 g/l. Ni; and the conditions were pH = 5.2 - 5.6; T = 25 Centigrade degrees; current density 0.3 A / dm2 - 6.6 A / dm2. Following alloy was between Bi - Pb, composition of the electrolyte was 3.18 g/l. Bi (metallic); 31.81 g/l. Pb (Pb(NO3)2) pH : 1; T = 20 Centigrade degrees; current density 10.20 A/dm2 . The third electrolyte was Bi-Cu, its composition was: 20.89 g/l. Bi; (metallic) 63.54 g/l Cu (Cu(NO3)2) pH : 1.5 - 1.8; T = 25-30 Centigrade degrees; current density 1-2 A/dm2 . The best results were obtained with the third electrolyte. The purpose of this work was to experiment with different parameters like temperature, pH and the electrolyte concentration to obtain a bismuth alloy. (Author)

  4. Magnetic anisotropies in ultrathin bismuth iron garnet films

    International Nuclear Information System (INIS)

    Ultrathin bismuth iron garnet Bi3Fe5O12 films were grown epitaxially on (001)-oriented gadolinium gallium garnet substrates. Film thickness varied from two to three dozens of unit cells. Bi3Fe5O12 films grow pseudomorphically on substrates up to a thickness of 20 nm, and then a lattice relaxation occurs. Magnetic properties of the films were studied as a function of bismuth iron garnet thickness. The magnetization and cubic anisotropy decrease with decreasing film thickness. The uniaxial magnetocrystalline anisotropy is constant for all film thicknesses. For two unit cell thick films, the easy magnetization axis changes from in-plane to perpendicular to the plane direction. Such a reorientation takes place as a result of the competition of constant uniaxial perpendicular anisotropy with weakening film magnetization. - Highlights: ► Ultrathin Bi3Fe5O12 films were grown epitaxially on structure-matching substrates. ► Magnetic properties of Bi3Fe5O12 were studied down to the thickness of 2.5 nm. ► Reorientation of easy magnetization axis as a function of film thickness was observed

  5. Layered bismuth oxyhalide nanomaterials for highly efficient tumor photodynamic therapy

    Science.gov (United States)

    Xu, Yu; Shi, Zhenzhi; Zhang, Ling'e.; Brown, Eric Michael Bratsolias; Wu, Aiguo

    2016-06-01

    Layered bismuth oxyhalide nanomaterials have received much more interest as promising photocatalysts because of their unique layered structures and high photocatalytic performance, which can be used as potential inorganic photosensitizers in tumor photodynamic therapy (PDT). In recent years, photocatalytic materials have been widely used in PDT and photothermal therapy (PTT) as inorganic photosensitizers. This investigation focuses on applying layered bismuth oxyhalide nanomaterials toward cancer PDT, an application that has never been reported so far. The results of our study indicate that the efficiency of UV-triggered PDT was highest when using BiOCl nanoplates followed by BiOCl nanosheets, and then TiO2. Of particular interest is the fact that layered BiOCl nanomaterials showed excellent PDT effects under low nanomaterial dose (20 μg mL-1) and low UV dose (2.2 mW cm-2 for 10 min) conditions, while TiO2 showed almost no therapeutic effect under the same parameters. BiOCl nanoplates and nanosheets have shown excellent performance and an extensive range of applications in PDT.

  6. Mechanically activating formation of layered structured bismuth titanate

    International Nuclear Information System (INIS)

    Bismuth titanate-Bi4Ti3O12 (BIT) with wide application in the electronic industry as capacitors, memory devices and sensors is the simplest compound in the Aurivillius family, which consists of (Bi2O2)2+ sheets alternating with (Bi2Ti3O10)2- perovskite-like layers. The synthesis of more resistive BIT ceramics would be preferable advance in obtaining of well-densified ceramic with small grains randomly oriented to limit the conductivity along the (Bi2O2)2+ layers. Having in mind that the conventional ceramic route for the synthesis can lead to non-stoichiometry in composition, in consequence of the undesirable loss in bismuth content through volatilization of Bi2O3 at elevated temperature, our efforts were addressed to preparation of BIT by mechanical activation the constituent oxides. The nucleation and phase formation of BIT, crystal structure, microstructure, powder particle size and specific surface area were followed by XRD, Rietveld refinement analysis, thermal analysis, scanning electron microscopy (SEM) and the BET specific surface area measurements

  7. Genotoxic effects of bismuth (III oxide nanoparticles by comet assay

    Directory of Open Access Journals (Sweden)

    Reecep Liman

    2015-06-01

    Full Text Available Bismuth oxide is one of the important transition metal oxides and it has been intensively studied due to their peculiar characteristics (semiconductor band gap, high refractive index, high dielectric permittivity, high oxygen conductivity, resistivity, photoconductivity and photoluminescence etc.. Therefore, it is used such as microelectronics, sensor technology, optical coatings, transparent ceramic glass manufacturing, nanoenergetic gas generator, biosensor for DNA hybridization, potential immobilizing platforms for glucose oxidase and polyphenol oxidase, fuel cells, a additive in paints, an astringent in a variety of medical creams and topical ointments, and for the determination of heavy metal ions in drinking water, mineral water and urine. In addition this, Bismuth (III oxide nanoparticles (BONPs are favorable for the biomolecules adsorption than regular sized particles because of their greater advantages and novel characteristics (much higher specific surface, greater surface free energy, and good electrochemical stability etc.. Genotoxic effects of BONPs were investigated on the root cells of Allium cepa by Comet assay. A. cepa roots were treated with the aqueous dispersions of BONPs at 5 different concentrations (12.5, 25, 50, 75, and 100 ppm for 4 h. A significant increase in DNA damage was also observed at all concentrations of BONPs except 12.5 ppm by Comet assay. The results were also analyzed statistically by using SPSS for Windows; Duncan’s multiple range test was performed. These result indicate that BONPs exhibit genotoxic activity in A. cepa root meristematic cells.

  8. Superconductivity in Bismuth. A New Look at an Old Problem.

    Science.gov (United States)

    Mata-Pinzón, Zaahel; Valladares, Ariel A; Valladares, Renela M; Valladares, Alexander

    2016-01-01

    To investigate the relationship between atomic topology, vibrational and electronic properties and superconductivity of bismuth, a 216-atom amorphous structure (a-Bi216) was computer-generated using our undermelt-quench approach. Its pair distribution function compares well with experiment. The calculated electronic and vibrational densities of states (eDOS and vDOS, respectively) show that the amorphous eDOS is about 4 times the crystalline at the Fermi energy, whereas for the vDOS the energy range of the amorphous is roughly the same as the crystalline but the shapes are quite different. A simple BCS estimate of the possible crystalline superconducting transition temperature gives an upper limit of 1.3 mK. The e-ph coupling is more preponderant in a-Bi than in crystalline bismuth (x-Bi) as indicated by the λ obtained via McMillan's formula, λc = 0.24 and experiment λa = 2.46. Therefore with respect to x-Bi, superconductivity in a-Bi is enhanced by the higher values of λ and of eDOS at the Fermi energy. PMID:26815431

  9. Synthesis and characterization of bismuth alkaline titanate powders

    Energy Technology Data Exchange (ETDEWEB)

    Torres-Huerta, A.M., E-mail: atorresh@ipn.mx [CICATA-Altamira, Instituto Politecnico Nacional, Km. 14.5 Carretera Tampico Puerto Industrial Altamira, Altamira, Tamps. 89600 (Mexico); Dominguez-Crespo, M.A. [CICATA-Altamira, Instituto Politecnico Nacional, Km. 14.5 Carretera Tampico Puerto Industrial Altamira, Altamira, Tamps. 89600 (Mexico); Hernandez-Perez, M.A. [ESIQIE, Metalurgia, Instituto Politecnico Nacional, Mexico, D. F (Mexico); Garcia-Zaleta, D.S. [CICATA-Altamira, Instituto Politecnico Nacional, Km. 14.5 Carretera Tampico Puerto Industrial Altamira, Altamira, Tamps. 89600 (Mexico); Brachetti-Sibaja, S.B. [CICATA-Altamira, Instituto Politecnico Nacional, Km. 14.5 Carretera Tampico Puerto Industrial Altamira, Altamira, Tamps. 89600 (Mexico); Instituto Tecnologico de Ciudad Madero, Av. 1o. de Mayo esq. Sor Juana Ines de la Cruz s/n Col. Los Mangos C.P.89440 Cd. Madero Tamaulipas (Mexico)

    2011-06-15

    In this work, samples of bismuth alkaline titanate, (K{sub 0.5}Na{sub 0.5}){sub (2-x/2)}Bi{sub (x/6)}TiO{sub 3}, (x = 0.05-0.75) have been prepared by conventional ceramic technique and molten salts. Metal oxides or carbonates powders were used as starting raw materials. The crystalline phase of the synthesized powders was identified by the X-ray diffraction (XRD) and particle morphology was characterized by scanning electron microscopy (SEM). Solid state reaction method was unsuccessful to obtain pellets. From XRD results, a rhombohedral structure was detected and the parameter lattice were estimated to be a = 5.5478 A and {alpha} = 59.48{sup o}. These parameters were used to refine the structure by Rietveld analysis. SEM results showed several morphologies. Apparently, bismuth is promoting the grain growth whose sizes vary from 30 nm to 180 nm It is expected that these materials can be utilized in practical applications as substitutes for lead zirconatetitanate (PZT)-based ceramics.

  10. Superconductivity in Bismuth. A New Look at an Old Problem.

    Directory of Open Access Journals (Sweden)

    Zaahel Mata-Pinzón

    Full Text Available To investigate the relationship between atomic topology, vibrational and electronic properties and superconductivity of bismuth, a 216-atom amorphous structure (a-Bi216 was computer-generated using our undermelt-quench approach. Its pair distribution function compares well with experiment. The calculated electronic and vibrational densities of states (eDOS and vDOS, respectively show that the amorphous eDOS is about 4 times the crystalline at the Fermi energy, whereas for the vDOS the energy range of the amorphous is roughly the same as the crystalline but the shapes are quite different. A simple BCS estimate of the possible crystalline superconducting transition temperature gives an upper limit of 1.3 mK. The e-ph coupling is more preponderant in a-Bi than in crystalline bismuth (x-Bi as indicated by the λ obtained via McMillan's formula, λc = 0.24 and experiment λa = 2.46. Therefore with respect to x-Bi, superconductivity in a-Bi is enhanced by the higher values of λ and of eDOS at the Fermi energy.

  11. The internal barriers of rotation for the 209 polychlorinated biphenyls.

    Science.gov (United States)

    Andersson, P L; Haglund, P; Tysklind, M

    1997-01-01

    The internal barrier of rotation (Erot) was calculated for all 209 polychlorinated biphenyls (PCBs) by using a semi-empirical method, viz. the Austin Model 1 (AMI) Hamiltonian. The difference in total energy between a forced planar state and an optimised twisted structure was defined as Erot. The Erot values were in the range of 8.33 to 483 kJ/mol, and were significantly influenced by the number of chlorine atoms in ortho position. An additional structural characteristic of the PCBs influencing Erot of ortho substituted congeners was substitution by chlorine atoms in vicinal meta positions, which is assumed to prevent outward bending of ortho substituents. This so-called buttressing effect contributed with 4 to 31 kJ/mol per added chlorine atom. In conclusion, the internal barrier of rotation, calculated for all 209 PCBs, provides an important structure dependent physico-chemical parameter for multivariate modelling of future quantitative structure-activity and structure-property relationships (QSARs/QSPRs). PMID:19005788

  12. Galaxy Evolution in the Environment of ABCG 209

    CERN Document Server

    Haines, C P; Merluzzi, P; La Barbera, F; Massarotti, M; Busarello, G; Girardi, M

    2004-01-01

    We examine the environmental effects on the photometric properties of galaxies for the rich galaxy cluster ABCG 209 at z=0.209. We use archive CFHT optical imaging of a 42'x28' field centred on the cluster to produce a galaxy sample complete to B=25.0 and R=24.5. Both the composite and red sequence galaxy luminosity functions are found to be dependent on the local galaxy surface density, their faint-end slopes becoming shallower with increasing density. We explain this as a combination of the morphology-density relation, and dwarf galaxies being cannibalised and/or disrupted by the cD galaxy and the ICM in the cluster core. The B-R colour of the red sequence itself appears 0.02mag redder for the highest-density regions, indicative of their stellar populations being marginally (<5%) older or (<20%) more metal-rich. This may be due to the galaxies themselves forming earliest in the rarest overdensities marked by rich clusters, or their star-formation being suppressed earliest by the ICM.

  13. Effect of O-vacancies on magnetic properties of bismuth ferrite nanoparticles by solution evaporation method

    Science.gov (United States)

    Afzal, A. M.; Umair, M.; Dastgeer, G.; Rizwan, M.; Yaqoob, M. Z.; Rashid, R.; Munir, H. S.

    2016-02-01

    Bismuth ferrite is a multiferroic material which shows high magnetization and polarization at room temperature. In present work, the effect of Oxygen (O) vacancies on magnetic properties of bismuth ferrite nanoparticles is studied. Bismuth ferrite nanoparticles (BiFeO3) were synthesized by solution evaporation method (SEM) at room temperature. The sample was annealed under two different atmospheres such as in air and oxygen, to check the effect of O-vacancies on magnetic properties. The average crystallite size of Bismuth ferrite nanoparticles (NPs) as calculated by X-ray diffraction (XRD) falls in the range of 23-32 nm and 26-39 nm for the case of air and oxygen respectively. The crystallite size of bismuth ferrite nanoparticles increases as the temperature was varied from 450 °C to 650 °C. Further the influence of annealing temperature on the magnetic properties of the bismuth ferrite nanoparticles was also observed. It was concluded that the magnetic properties of Bismuth ferrite nanoparticles are directly interconnected to annealing atmosphere and annealing temperature. The magnetic properties were increased in the case of oxygen annealing, which actually leads in our case to an improvement of the crystallinity.

  14. Ultra-flat bismuth films for diamagnetic levitation by template-stripping

    Energy Technology Data Exchange (ETDEWEB)

    Kokorian, J. [University of Twente, P.O. Box 217, 7500 AE Enschede (Netherlands); TU Delft — 3mE-PME, Mekelweg 2, 2628 CD Delft (Netherlands); Engelen, J.B.C. [University of Twente, P.O. Box 217, 7500 AE Enschede (Netherlands); IBM Research — Zurich, Säumerstrasse 4, CH-8803 Rüschlikon (Switzerland); Vries, J. de; Nazeer, H.; Woldering, L.A. [University of Twente, P.O. Box 217, 7500 AE Enschede (Netherlands); Abelmann, L., E-mail: l.abelmann@utwente.nl [University of Twente, P.O. Box 217, 7500 AE Enschede (Netherlands)

    2014-01-01

    In this paper we present a method to deposit thin films of bismuth with sub-nanometer surface roughness for application to diamagnetic levitation. Evaporated films of bismuth have a high surface roughness with peak to peak values in excess of 100 nm and average values on the order of 20 nm. We expose the smooth backside of the films using a template stripping method, resulting in a great reduction of the average surface roughness, to 0.8 nm. Atomic force microscope and X-ray diffraction measurements show that the films have a polycrystalline texture with preferential c-axis orientation. On the back side of the film, fine grains are grouped into larger clusters. Cantilever resonance shift measurements indicate that the Young's modulus of the films is on the order of 20 GPa. - Highlights: • We deposited continuous but rough bismuth films of 200–500 nm in thickness by thermal evaporation. • We analyzed the material properties of bismuth films using a variety of measurement techniques. • We reduced the roughness of bismuth films from 20 nm to 0.8 nm by a template stripping method. • The Young's modulus of bismuth thin films is comparable to bulk bismuth.

  15. Fabrication of optical channel waveguides in crystals and glasses using macro- and micro ion beams

    Czech Academy of Sciences Publication Activity Database

    Banyasz, I.; Rajta, I.; Nagy, G. U. L.; Zolnai, Z.; Havránek, Vladimír; Veres, M.; Berneschi, S.; Nunzi-Conti, G.; Righini, G. C.

    2014-01-01

    Roč. 331, JUL (2014), s. 157-162. ISSN 0168-583X R&D Projects: GA MŠk(XE) LM2011019 Institutional support: RVO:61389005 Keywords : channel optical waveguides * ion beam irradiation * focussed ion beam * Er-doped tungsten-tellurite glass * Bismuth germanate * Micro Raman spectroscopy Subject RIV: BG - Nuclear, Atomic and Molecular Physics, Colliders Impact factor: 1.124, year: 2014

  16. Bismuth Modified Carbon-Based Electrodes for the Determination of Selected Neonicotinoid Insecticides

    OpenAIRE

    Marko Rodić; Olga Vajdle; Valéria Guzsvány; Jasmina Zbiljić; Zsigmond Papp

    2011-01-01

    Two types of bismuth modified electrodes, a bismuth-film modified glassy carbon (BiF-GCE) and a bismuth bulk modified carbon paste, were applied for the determination of selected nitroguanidine neonicotinoid insecticides. The method based on an ex situ prepared BiF-GCE operated in the differential pulse voltammetric (DPV) mode was applied to determine clothianidin in the concentration range from 2.5 to 23 μg cm−3 with a relative standard deviation (RSD) not exceeding 1.5%. The tricresyl phosp...

  17. Structural and optical characterization of thermally evaporated bismuth and antimony films for photovoltaic applications

    Science.gov (United States)

    Srimathy, N.; Ruban Kumar, A.

    2016-05-01

    In this present study, the thin film of bismuth and antimony is coated by thermal evaporation system equipped with the inbuilt ultra high vacuum system. XRD analysis confirmed the rhombohedral structure of Bismuth and Antimony on the prepared film. The surface roughness and physical appearance is analyzed by Atomic force microscopy. The results of Raman Spectroscopy show the wave functions and the spectrum of electrons. The preparation technique and conditions strongly influence the crystalline structure and the phase composition of bismuth and antimony thin films. The electrical and optical properties for the prepared film are analyzed. The results show a great interest and promising applications in Photovoltaic devices.

  18. Exploiting Chemistry to Improve Performance of Screen-Printed, Bismuth Film Electrodes (SP-BiFE

    Directory of Open Access Journals (Sweden)

    Carlo Dossi

    2016-07-01

    Full Text Available Mercury substitution is a big issue in electroanalysis, and the search for a suitable, and less toxic, replacement is still under development. Of all the proposed alternatives, bismuth films appear to be the most viable solution, although they are still suffering some drawbacks, particularly the influence of deposition conditions and linearity at low concentrations. In this paper, the most promising strategies for bismuth film deposition on screen-printed electrodes (surface modifications, polymeric film deposition, insoluble salt precursors will be evaluated for trace metal analysis. Particular attention will be devoted to bismuth chemistry, aiming to rationalize their electroanalytic performance.

  19. Bismuth ferrite as low-loss switchable material for plasmonic waveguide modulator

    DEFF Research Database (Denmark)

    Babicheva, Viktoriia; Zhukovsky, Sergei; Lavrinenko, Andrei

    2014-01-01

    We propose new designs of plasmonic modulators, which can beused for dynamic signal switching in photonic integrated circuits. We studyperformance of a plasmonic waveguide modulator with bismuth ferrite as atunable material. The bismuth ferrite core is sandwiched between metalplates (metal-insulator-metal...... modulation in both phase andamplitude control schemes. Due to high field confinement between themetal layers, existence of mode cut-offs for certain values of the corethickness, and near-zero material losses in bismuth ferrite, efficientmodulation performance is achieved. For the phase control scheme...

  20. Increased InAs quantum dot size and density using bismuth as a surfactant

    International Nuclear Information System (INIS)

    We have investigated the growth of self-assembled InAs quantum dots using bismuth as a surfactant to control the dot size and density. We find that the bismuth surfactant increases the quantum dot density, size, and uniformity, enabling the extension of the emission wavelength with increasing InAs deposition without a concomitant reduction in dot density. We show that these effects are due to bismuth acting as a reactive surfactant to kinetically suppress the surface adatom mobility. This mechanism for controlling quantum dot density and size has the potential to extend the operating wavelength and enhance the performance of various optoelectronic devices

  1. The Effects of Proposition 209 on California: Higher Education, Public Employment, and Contracting

    Science.gov (United States)

    Geshekter, Charles L.

    2008-01-01

    In 1996, Californians overwhelmingly approved Proposition 209, which prohibited all state agencies from discriminating on the basis of race, ethnicity, or gender in university admissions, public employment, or competition for a state contract. Opponents of Proposition 209 predicted dire consequences for California's ethnic minorities and women if…

  2. 33 CFR 209.180 - Temporary closure of waterway to navigation.

    Science.gov (United States)

    2010-07-01

    ... 33 Navigation and Navigable Waters 3 2010-07-01 2010-07-01 false Temporary closure of waterway to navigation. 209.180 Section 209.180 Navigation and Navigable Waters CORPS OF ENGINEERS, DEPARTMENT OF THE... navigation. (a) When an application is received for the temporary closure of a waterway for the...

  3. Aerobic degradation of BDE-209 by Enterococcus casseliflavus: Isolation, identification and cell changes during degradation process.

    Science.gov (United States)

    Tang, Shaoyu; Yin, Hua; Chen, Shuona; Peng, Hui; Chang, Jingjing; Liu, Zehua; Dang, Zhi

    2016-05-01

    Decabromodiphenyl ether (BDE-209) is one of the most commonly used brominated flame retardants that have contaminated the environment worldwide. Microbial bioremediation has been considered as an effective technique to remove these sorts of persistent organic pollutants. Enterococcus casseliflavus, a gram-positive bacterium capable of aerobically transforming BDE-209, was isolated by our team from sediments in Guiyu, an e-waste dismantling area in Guangdong Province, China. To promote microbial bioremediation of BDE-209 and elucidate the mechanism behind its aerobic degradation, the effects of BDE-209 on the cell changes of E. casseliflavus were examined in this study. The experimental results demonstrated that the high cell surface hydrophobicity (CSH) of E. casseliflavus made the bacteria absorb hydrophobic BDE-209 more easily. E. casseliflavus responded to BDE-209 stress, resulting in an increase in cell membrane permeability and accumulation of BDE-209 inside the cell. The differential expression of intracellular protein was analyzed through two-dimensional gel electrophoresis (2-DE). More than 50 differentially expressed protein spots were reproducibly detected, including 25 up, and 25 down regulated after a 4 days exposure. Moreover, the apoptotic-like cell changes were observed during E. casseliflavus mediated degradation of BDE-209 by means of flow cytometry. PMID:26852209

  4. Evaluation and calculation of photonuclear reaction data for 209Bi below 30 MeV

    International Nuclear Information System (INIS)

    Based on available experimental data of neutron and photonuclear reaction, both neutron optical potential parameter and giant resonance parameters of gamma for 209Bi were obtained. The photonuclear reaction data for 209Bi were calculated, compared with experimental data and recommended below 30 MeV

  5. 31 CFR 560.209 - Prohibited transactions with respect to the development of Iranian petroleum resources.

    Science.gov (United States)

    2010-07-01

    ... to the development of Iranian petroleum resources. 560.209 Section 560.209 Money and Finance... respect to the development of Iranian petroleum resources. Except as otherwise authorized, and... development of petroleum resources located in Iran, or (2) A guaranty of another person's performance...

  6. 29 CFR 778.209 - Method of inclusion of bonus in regular rate.

    Science.gov (United States)

    2010-07-01

    ... 29 Labor 3 2010-07-01 2010-07-01 false Method of inclusion of bonus in regular rate. 778.209... LABOR STATEMENTS OF GENERAL POLICY OR INTERPRETATION NOT DIRECTLY RELATED TO REGULATIONS OVERTIME COMPENSATION Payments That May Be Excluded From the âRegular Rateâ Bonuses § 778.209 Method of inclusion...

  7. 33 CFR 209.320 - Policy on release of commercial statistics.

    Science.gov (United States)

    2010-07-01

    ... statistics. 209.320 Section 209.320 Navigation and Navigable Waters CORPS OF ENGINEERS, DEPARTMENT OF THE... statistics. The collection of commercial statistics pertaining to rivers, harbors, and waterways, and annual... waterway statistics. In case Federal or State agencies or local interests request other than...

  8. 40 CFR 600.209-95 - Calculation of fuel economy values for labeling.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 29 2010-07-01 2010-07-01 false Calculation of fuel economy values for labeling. 600.209-95 Section 600.209-95 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) ENERGY POLICY FUEL ECONOMY AND CARBON-RELATED EXHAUST EMISSIONS OF MOTOR VEHICLES Fuel...

  9. 40 CFR 600.209-85 - Calculation of fuel economy values for labeling.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 29 2010-07-01 2010-07-01 false Calculation of fuel economy values for labeling. 600.209-85 Section 600.209-85 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) ENERGY POLICY FUEL ECONOMY AND CARBON-RELATED EXHAUST EMISSIONS OF MOTOR VEHICLES Fuel...

  10. 48 CFR 252.209-7007 - Prohibited Financial Interests for Lead System Integrators.

    Science.gov (United States)

    2010-10-01

    ... 48 Federal Acquisition Regulations System 3 2010-10-01 2010-10-01 false Prohibited Financial Interests for Lead System Integrators. 252.209-7007 Section 252.209-7007 Federal Acquisition Regulations System DEFENSE ACQUISITION REGULATIONS SYSTEM, DEPARTMENT OF DEFENSE CLAUSES AND FORMS SOLICITATION PROVISIONS AND CONTRACT CLAUSES Text of...

  11. 20 CFR 209.14 - Report of separation allowances subject to tier II taxation.

    Science.gov (United States)

    2010-04-01

    ... 20 Employees' Benefits 1 2010-04-01 2010-04-01 false Report of separation allowances subject to tier II taxation. 209.14 Section 209.14 Employees' Benefits RAILROAD RETIREMENT BOARD REGULATIONS UNDER... separation allowances subject to tier II taxation. For any employee who is paid a separation payment,...

  12. Conduction mechanism in bismuth silicate glasses containing titanium

    Energy Technology Data Exchange (ETDEWEB)

    Dult, Meenakshi; Kundu, R.S. [Department of Applied Physics, Guru Jambheshwar University of Science and Technology, Hisar 125001 (India); Murugavel, S. [Department of Physics and Astrophysics, University of Delhi, Delhi 110007 (India); Punia, R., E-mail: rajeshpoonia13@gmail.com [Department of Applied Physics, Guru Jambheshwar University of Science and Technology, Hisar 125001 (India); Kishore, N. [Department of Applied Physics, Guru Jambheshwar University of Science and Technology, Hisar 125001 (India)

    2014-11-01

    Bismuth silicate glasses mixed with different concentrations of titanium dioxide having compositions xTiO{sub 2}–(60−x)Bi{sub 2}O{sub 3}–40SiO{sub 2} with x=0, 5, 10, 15 and 20 were prepared by the normal melt quench technique. The frequency dependence of the ac electrical conductivity of different compositions of titanium bismuth silicate glasses has been studied in the frequency range 10{sup −1} Hz to 10 MHz and in the temperature range 623–703 K. The temperature and frequency dependent conductivity is found to obey Jonscher's universal power law for all the compositions of titanium bismuth silicate glass system. The dc conductivity (σ{sub dc}), so called crossover frequency (ω{sub H}), and frequency exponent (s) have been estimated from the fitting of experimental data of ac conductivity with Jonscher's universal power law. Enthalpy to dissociate the cation from its original site next to a charge compensating center (H{sub f}) and enthalpy of migration (H{sub m}) have also been estimated. The conductivity data have been analyzed in terms of different theoretical models to determine the possible conduction mechanism. Analysis of the conductivity data and the frequency exponent shows that the correlated barrier hopping of electrons between Ti{sup 3+} and Ti{sup 4+} ions in the glasses is the most favorable mechanism for ac conduction. The temperature dependent dc conductivity has been analyzed in the framework of theoretical variable range hopping model (VRH) proposed by Mott which describe the hopping conduction in disordered semiconducting systems. The various polaron hopping parameters have also been deduced. Mott's VRH model is found to be in good agreement with experimental data and the values of inverse localization length of s-like wave function (α) obtained by this model with modifications suggested by Punia et al. are close to the ones reported for a number of oxide glasses.

  13. Study of rare processes induced by 209-Gev muons

    International Nuclear Information System (INIS)

    Analysis of dimuon final states from 1.4 x 1011 positive and 2.9 x 1010 negative 209-Gev muons in a magnetized iron calorimeter has set a lower limit of 9 Gev/c2 on the mass of a heavy neutral muon (M0), and a 90%-confidence level upper limit of sigma(μN→b anti bX)B(b anti b→μX)-36 cm2 for the production of bottom hadrons by muons. The dimuon mass spectrum from 102,678 trimuon final states places a 90%-confidence level upper limit for the muoproduction of upsilon states: sigma(μN→μ UPSILON X)B(UPSILON→μ+μ-)-39 cm2. In addition, analysis of 71 rare multimuon events, including 4- and 5-muon final states, is presented

  14. Shielding property of bismuth glass based on MCNP 5 and WINXCOM simulated calculation

    International Nuclear Information System (INIS)

    Background: Currently, lead glass is widely used as observation window, while lead is toxic heavy metal. Purpose: Non-toxic materials and their shielding effects are researched in order to find a new material to replace lead containing material. Methods: The mass attenuation coefficients of bismuth silicate glass were investigated with gamma-ray's energy at 0.662 MeV, 1.17 MeV and 1.33 MeV, respectively, by MCNP 5 (Monte Carlo) and WINXCOM program, and compared with those of the lead glass. Results: With attenuation factor K, shielding and mechanical properties taken into consideration bismuth glass containing 50% bismuth oxide might be selected as the right material. Dose rate distributions of water phantom were calculated with 2-cm and 10-cm thick glass, respectively, irradiated by 137Cs and 60Co in turn. Conclusion: Results show that the bismuth glass may replace lead glass for radiation shielding with appropriate energy. (authors)

  15. Three-component synthesis of amidoalkyl naphthols catalyzed by bismuth(Ⅲ) nitrate pentahydrate

    Institute of Scientific and Technical Information of China (English)

    Min Wang; Yan Liang; Ting Ting Zhang; Jing Jing Gao

    2012-01-01

    Bismuth(Ⅲ) nitrate pentahydrate catalyzed the three-component condensation of β-naphthol,aldehydes and amines/urea under solvent-free conditions to afford the corresponding amidoalkyl naphthols in excellent yields.

  16. Surface tension of liquid dilute solutions of lead-cesium and bismuth-cesium systems

    International Nuclear Information System (INIS)

    Method of the maximal pressure in a drop was used to measure the surface tension of 15 liquid dilute solutions of lead-cesium system in 0-0.214 at% concentration range and of 12 diluted solutions of bismuth-cesium system in 0-0.160 at.% cesium range from solidification temperature up to 500 dec C. It was found that cesium was characterized as surfactant in lead and bismuth melts. It was established that the temperature coefficient of surface tension changes sufficiently in maximally diluted solutions of alkali metals in bismuth and lead melts. Effect of sodium, potassium, rubidum and cesium on the value of surface tension of lead and bismuth was systematized. Growth of activity in sodium, potassium, rubidium and cesium series was noted

  17. Corrosion by liquid lead and lead-bismuth: experimental results review and analysis

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Jinsuo [Los Alamos National Laboratory

    2008-01-01

    Liquid metal technologies for liquid lead and lead-bismuth alloy are under wide investigation and development for advanced nuclear energy systems and waste transmutation systems. Material corrosion is one of the main issues studied a lot recently in the development of the liquid metal technology. This study reviews corrosion by liquid lead and lead bismuth, including the corrosion mechanisms, corrosion inhibitor and the formation of the protective oxide layer. The available experimental data are analyzed by using a corrosion model in which the oxidation and scale removal are coupled. Based on the model, long-term behaviors of steels in liquid lead and lead-bismuth are predictable. This report provides information for the selection of structural materials for typical nuclear reactor coolant systems when selecting liquid lead or lead bismuth as heat transfer media.

  18. RECYCLING TECHNOLOGY INTO INDUSTRIAL TURNOVER OF BISMUTH AND MOLYBDENUM FROM DEAD CATALYST

    Directory of Open Access Journals (Sweden)

    O. S. Komarov

    2015-05-01

    Full Text Available The technology of separate extraction of bismuth and molybdenum from spent catalyst was presented and information on the effectiveness of its use in a composition of comprehensive modifier in the iron-carbon alloy was given.

  19. Standard triple, bismuth pectin quadruple and sequential therapies for Helicobacter pylori eradication

    OpenAIRE

    Gao, Xiao-Zhong; Qiao, Xiu-li; Song, Wen-chong; Wang, Xiao-Feng; Liu, Feng

    2010-01-01

    AIM: To compare the effectiveness of standard triple, bismuth pectin quadruple and sequential therapies for Helicobacter pylori (H. pylori) eradication in a randomized, double-blinded, comparative clinical trial in China.

  20. Azo dyes photobleaching and operando FTIR study of acetaldehyde photoinduced decomposition on bismuth doped titania

    Czech Academy of Sciences Publication Activity Database

    Henych, Jiří; Štengl, Václav; Mattsson, A.; Österlund, L.

    Thessaloniki : Aristotle University of Thessaloniki, 2014. s. 101. [European Meeting on Solar Chemistry and Photocatalysis: Environmental Applications (SPEA) /8./. 25.6.2014-28.6.2014, Thessaloniki] Institutional support: RVO:61388980 Keywords : bismuth doped titania Subject RIV: CA - Inorganic Chemistry

  1. Cluster beam investigation with MCPs

    International Nuclear Information System (INIS)

    High intensity cluster-jet beams produced in Laval nozzles represent a very attractive and extremely interesting tool for studies at storage ring experiments, such as PANDA, or for laser-induced particle acceleration. Since the cluster properties vary with increasing number of constituents, it is essential to perform systematic measurements on the target thickness and especially on the cluster masses. For this purpose a monitoring system based on Micro Channel Plates (MCPs) combined with a phosphor screen has been developed and installed at the beam dump of the PANDA prototype cluster-jet target in Muenster. It could be shown that this MCP system allows for a direct observation of an ionised cluster beam. In addition, with this setup the possibility to visualise the vertex zone at the ANKE cluster-jet target at COSY was succesfully demonstrated, where a proton beam with a momentum of 2.09 GeV/c interacted with a hydrogen cluster-jet beam. Furthermore, cluster mass investigations can be performed in conjunction with a retardation field. In this presentation an overview of the MCP detection system, images of the cluster-jet beam and the vertex zone as well as the results of the current cluster mass measurements are presented and discussed.

  2. A novel synthesis of perovskite bismuth ferrite nanoparticles

    Directory of Open Access Journals (Sweden)

    Alexandre Z. Simões

    2011-09-01

    Full Text Available Microwave assisted hydrothermal (MAH method was used to synthesize crystalline bismuth ferrite (BiFeO3 nanoparticles (BFO at temperature of 180°C with times ranging from 5 min to 1 h. For comparison, BFO powders were also crystallized by the soft chemistry route in a conventional furnace at a temperature of 850°C for 4 h. X-ray diffraction (XRD results verified the formation of perovskite BFO crystallites while infrared data showed no traces of carbonate. Field emission scanning microcopy (FE/SEM revealed a homogeneous size distribution of nanometric BFO powders. MAH method produced nanoparticles of 96% pure perovskite, with a size of 130 nm. These results are in agreement with Raman scattering values which show that the MAH synthesis route is rapid and cost effective. This method could be used as an alternative to other chemical methods in order to obtain BFO nanoparticles.

  3. Vibrational spectra and structure of bismuth based quaternary glasses

    International Nuclear Information System (INIS)

    Quaternary bismuthate glasses containing Li2O, ZnO and B2O3 have been prepared by melt quench technique and studied by density, DSC, IR and Raman spectroscopy. Raman and infrared spectroscopy have been employed to investigate the (75 - x)Bi2O3-xLi2O-10ZnO-15B2O3 glasses in order to obtain information about the competitive role of Bi2O3 and B2O3 in the formation of glass network. The increase of Bi2O3 content causes a progressive conversion of three- to four-fold coordinated boron. IR and Raman spectra show that these glasses are made up of [BiO3] pyramidal and [BiO6] octahedral units. The formation of Zn in tetrahedral coordination was observed

  4. Evaporation of mercury impurity from liquid lead–bismuth eutectic

    International Nuclear Information System (INIS)

    The equilibrium evaporation of mercury from dilute solutions in liquid lead–bismuth eutectic (LBE) was studied in argon atmosphere. Mercury present as impurity in LBE was evaporated and detected by atomic fluorescence spectroscopy. A method which could accurately simulate the experimental data was developed. Coefficients of the Henry constant temperature correlation for mercury dissolved in LBE were determined. Experiments with samples from several different batches of LBE revealed that mercury at mole fractions between 10−6 and 10−12 and temperatures between 150 and 350 °C evaporated from liquid LBE close to ideal behavior. Evaporation of mercury from solid LBE on the other hand was unexpectedly high. These results are important for safety evaluations of LBE based spallation targets and accelerator driven systems

  5. High power and compact switchable bismuth based multiwavelength fiber laser

    International Nuclear Information System (INIS)

    A compact switchable multiwavelength fibre laser (SWFL) is proposed and demonstrated using a bismuth based erbium doped fibre amplifier (Bi-EDFA) and a Sagnac loop mirror (SLM) in a ring cavity. The proposed compact SWFL can generate up to 6 switchable wavelengths with an average peak power of 11 dBm and also shows good stability over time with a high side mode signal ratio (SMSR) of 40 dB that negates minor fluctuations in the laser output. The Bi-EDF based gain medium gives the SWFL a large usable bandwidth of up to 80 nm, and it is expected that this will allow the SWFL to be used as a tunable laser source for high power applications to meet increasing demand

  6. Structural investigation of Zn doped sodium bismuth borate glasses

    Science.gov (United States)

    Bhatia, V.; Kumar, D.; Singh, D.; Singh, S. P.

    2016-05-01

    A series of Bismuth Borate Oxide Glass samples with composition x(ZnO):(15-x)Na2O:15Bi2O3:70B2O3 (variation in x is from 6 to 12 mole %) have been prepared by conventional melt quenching technique. All the chemicals used were of Analytical Grade. In order to verify the amorphous nature of the prepared samples the X-Ray Diffraction (XRD) was done. The physical and structural properties have been explored by using the techniques such as density, molar volume and FTIR in order to understand the effect of alkali and transition metal ions on the structure of these glasses. The results obtained by these techniques are in good agreement to one another and with literature as well. With the increase in the content of ZnO, the increase in density and some variations in structural coordination (ratio of BO3 & BO4 structural units) have been observed.

  7. Compatibility of structural materials with liquid bismuth, lead, and mercury

    Energy Technology Data Exchange (ETDEWEB)

    Weeks, J.R. [Brookhaven National Lab., Upton, NY (United States)

    1996-06-01

    During the 1950s and 1960s, a substantial program existed at Brookhaven National Laboratory as part of the Liquid Metal Fuel reactor program on the compatibility of bismuth, lead, and their alloys with structural materials. Subsequently, compatibility investigations of mercury with structural materials were performed in support of development of Rankine cycle mercury turbines for nuclear applications. The present talk will review present understanding of the corrosion/mass-transfer reactions of structural materials with these liquid metal coolants. Topics to be discussed include the basic solubility relationships of iron, chromium, nickel, and refractory metals in these liquid metals, the results of inhibition studies, the role of oxygen on the corrosion processes, and specialized topics such as cavitation-corrosion and liquid metal embrittlement. Emphasis will be placed on utilizing the understanding gained in this earlier work on the development of heavy liquid metal targets in spallation neutron sources.

  8. Formic Acid Oxidation at Platinum-Bismuth Clusters

    DEFF Research Database (Denmark)

    Lovic, J. D.; Stevanovic, S. I.; Tripkovic, D. V.; Tripkovic, Vladimir; Stevanovic, R. M.; Popovic, K. Dj.; Jovanovic, V. M.

    2014-01-01

    Formic acid oxidation was studied on platinum-bismuth deposits on glassy carbon (GC) substrate. The catalysts of equimolar ratio were prepared by potentiostatic deposition using chronocoulometry. Bimetallic structures obtained by two-step process, comprising deposition of Bi followed by deposition...... dissolution, deposits were subjected to electrochemical oxidation, in the relevant potential range and supporting electrolyte, prior to use as catalysts for HCOOH oxidation. Anodic striping charges indicated that along oxidation procedure most of deposited Bi was oxidized. ICP mass spectroscopy analysis of...... latter. Catalysts prepared in this way exhibit about 10 times higher activity for formic acid oxidation in comparison to pure Pt, as revealed both by potentiodynamic and quasy-potentiostatic measurements. This high activity is the result of well-balanced ensemble effect induced by Bi-oxide species...

  9. Ni-rich precipitates in a lead bismuth eutectic loop

    Science.gov (United States)

    Kikuchi, K.; Saito, S.; Hamaguchi, D.; Tezuka, M.

    2010-03-01

    Solidified LBE was sampled from the specimens, electro-magnetic pump, filter, drain valve and oxygen sensor at the JAEA Lead Bismuth Loop-1 (JLBL-1) where the structural material was made of SS316. The concentration of Ni, Fe and Cr in LBE were analyzed by the Inductive Coupled Plasma atomic emission spectrometer. It was concluded that the solution of Ni into LBE was not saturated although the concentration of Fe and Cr almost achieved to the values in the literature. A needle-type structure appeared on the surface of solidified LBE inside the tube specimens. It was found to be Ni-rich precipitates by X-ray analyses (Field Emission Scanning Electron Microscope, FE-SEM). LBE samples collected from a circulating loop after discharging did not show the amount of impurities equivalent to the LBE bulk property.

  10. Evaporation of mercury impurity from liquid lead–bismuth eutectic

    Energy Technology Data Exchange (ETDEWEB)

    Aerts, A., E-mail: aaertsl@sckcen.be [SCK-CEN (Belgian Nuclear Research Centre), Boeretang 200, 2400 Mol (Belgium); Danaci, S. [SCK-CEN (Belgian Nuclear Research Centre), Boeretang 200, 2400 Mol (Belgium); Gonzalez Prieto, B. [SCK-CEN (Belgian Nuclear Research Centre), Boeretang 200, 2400 Mol (Belgium); Centre for Surface Chemistry and Catalysis, KU Leuven, Kasteelpark Arenberg 23, 3001 Heverlee (Belgium); Van den Bosch, J. [SCK-CEN (Belgian Nuclear Research Centre), Boeretang 200, 2400 Mol (Belgium); Neuhausen, J. [Laboratory for Radio- and Environmental Chemistry, Paul Scherrer Institute, CH-5232 Villigen PSI (Switzerland)

    2014-05-01

    The equilibrium evaporation of mercury from dilute solutions in liquid lead–bismuth eutectic (LBE) was studied in argon atmosphere. Mercury present as impurity in LBE was evaporated and detected by atomic fluorescence spectroscopy. A method which could accurately simulate the experimental data was developed. Coefficients of the Henry constant temperature correlation for mercury dissolved in LBE were determined. Experiments with samples from several different batches of LBE revealed that mercury at mole fractions between 10{sup −6} and 10{sup −12} and temperatures between 150 and 350 °C evaporated from liquid LBE close to ideal behavior. Evaporation of mercury from solid LBE on the other hand was unexpectedly high. These results are important for safety evaluations of LBE based spallation targets and accelerator driven systems.

  11. Process dependent thermoelectric properties of EDTA assisted bismuth telluride

    Science.gov (United States)

    Kulsi, Chiranjit; Kargupta, Kajari; Banerjee, Dipali

    2016-04-01

    Comparison between the structure and thermoelectric properties of EDTA (Ethylene-diamine-tetra-acetic acid) assisted bismuth telluride prepared by electrochemical deposition and hydrothermal route is reported in the present work. The prepared samples have been structurally characterized by high resolution X-ray diffraction spectra (HRXRD), field emission scanning electron microscopy (FESEM) and high resolution transmission electron microscopic images (HRTEM). Crystallite size and strain have been determined from Williamson-Hall plot of XRD which is in conformity with TEM images. Measurement of transport properties show sample in the pellet form (S1) prepared via hydrothermal route has higher value of thermoelectric power (S) than the electrodeposited film (S2). But due to a substantial increase in the electrical conductivity (σ) of the film (S2) over the pellet (S1), the power factor and the figure of merit is higher for sample S2 than the sample S1 at room temperature.

  12. Enhanced multiferroic properties of Pr doped bismuth ferrite ceramics

    International Nuclear Information System (INIS)

    Pr modified Bi0.9-xLa0.1PrxFeO3 (BLPFO-x, x = 0, 0.1 and 0.2) ceramics were prepared by solid state reaction using oxide reagents and a detailed multiferroic properties is reported. X-ray analysis shows the formation of a bismuth ferrite rhombohedral phase. Pr doping significantly increases the resistivity and leads to a successful observation of electrical polarization hysteresis loops. All the samples have been found to possess a spontaneous magnetic moment at room temperature which increases further at low temperatures. The strong dependence of remnant polarization and dielectric constant on the strength of magnetic field is a direct evidence of magnetoelectric coupling in BLPFO ceramics. (author)

  13. Scanning tunneling microscopy of the cleavage surface of bismuth crystals

    International Nuclear Information System (INIS)

    The results of in situ studies of the surface structure of the cleavages of bismuth crystals by the method of scanning tunneling microscopy are presented. It is established that cleavage 'opens' the (111) surface with atomically smooth terraces of diatomic steps whose heights are equal to 0.4 nm or a multiple of this value. If the cleavage is made at room temperature, the boundaries of the terraces are usually curved and diffuse owing to the thermal motion with the activation energy of ∼700 K. The cleavage at liquid nitrogen or helium temperatures provides the formation of straight boundaries along the atomic rows on the surface. Twin interlayers of the quantized width of ∼7 nm are revealed. This width value indicates that the atomic planes on both sides of such interlayers intergrow with the interlayer planes inclined to them at a small angle

  14. Toxicity of Volatile Methylated Species of Bismuth, Arsenic, Tin, and Mercury in Mammalian Cells In Vitro

    OpenAIRE

    Rettenmeier, A W; Zimmermann, U.; Richard, J.; R. A. Diaz-Bone; Hippler, J; U. von Recklinghausen; Dopp, E.; Hirner, A. V.

    2011-01-01

    The biochemical transformation of mercury, tin, arsenic and bismuth through formation of volatile alkylated species performs a fundamental role in determining the environmental processing of these elements. While the toxicity of inorganic forms of most of these compounds are well documented (e.g., arsenic, mercury) and some of them are of relatively low toxicity (e.g., tin, bismuth), the more lipid-soluble organometals can be highly toxic. In the present study we investigated the cyto- and ge...

  15. Determination of vanadium concentration in bismuth titanate monocrystals and its relation to optical properties and photoconductivity

    International Nuclear Information System (INIS)

    Using Czochralski method optically perfect bismuth titanate crytals doped by vanadium (0.14-0.46 mass.%) are prepared. A technique of vanadium concentration measurement by Raman spectra is developed. Photoconductivity and optical properties of tehse monocrystals are studied. It is shown that in λ > 530 nm wave range photoconductivity of doped monocrystals is by 1-2 order higher than in pure bismuth titanate monocrystal

  16. In vitro synergistic activity between bismuth subcitrate and various antimicrobial agents against Campylobacter pyloridis (C. pylori).

    OpenAIRE

    Van Caekenberghe, D L; Breyssens, J

    1987-01-01

    The in vitro interactions between bismuth subcitrate and a variety of antimicrobial agents against 12 Campylobacter pyloridis (C. pylori) isolates were studied by the agar dilution checkerboard technique. The combination of bismuth subcitrate with the older quinolone, oxolinic acid, produced synergistic activity against all strains. This observation, however, could not be extended to the (aryl) fluoroquinolones, norfloxacin, ofloxacin, and difloxacin, since synergy was rare or absent when bis...

  17. Intermetallic growth at the interface between copper and bismuth-tin solder

    OpenAIRE

    Vollweiler, Fred O. P.

    1993-01-01

    Approved for public release; distribution is unlimited. Tin-bismuth alloys have been proposed as alternatives to lead containing solders for interconnection and packaging applications. Consequently, the interface between copper metallizations and bismuth-tin solders needs to be evaluated with respect to brittle intermetallic formation. In the binary Bi-Sn alloys both the Cu6Sn5 and Cu3Sn intermetallic phases were found at the Cu/ solder interface after exposure at 250 deg C, 300 deg C, and...

  18. Shock compression and adiabatic decompression of a dense bismuth plasma at extreme thermal energy densities

    International Nuclear Information System (INIS)

    Experimental results on the shock-wave compression of solid and porous bismuth samples at pressures over the range 0.4-6 Mbar are reported. The course of the supercritical decompression isentropes between a highly compressed condensed state and a low-density plasma has been determined. The experimental results are used to write a thermodynamic description of the high-energy states of a dense bismuth plasma. 11 references

  19. Direct Electrochemical Synthesis of Bismuth(III) Phenoxides and their Coordination Compounds

    OpenAIRE

    Harpreet Kaur; Baljit Singh

    2012-01-01

    Bismuth(III) phenoxides have been synthesized by electrochemical reactions of 1-naphthol, 2-naphthol, 4-aminophenol, 2-nitrophenol, 4-nitrophenol, 2-hydroxybenzoic acid, p-cresol, phenol, resorcinol, 2-tert-butylphenol and 2-tert-butyl-4-methoxyphenol at sacrificial bismuth anode and inert platinum cathode using tetrabutylammonium chloride as supporting electrolyte. The coordination compounds of these phenols with 1, 10-phenanthroline and 2, 2ʼ-bipyridyl have also been synthesized electrochem...

  20. Study of bismuth minerals belonging to the mineralogical collection from the National Museum

    International Nuclear Information System (INIS)

    With the purpose of searching the presence of Tellurium minerals in the Ouro Preto-Mariana country, Minas Gerais State, and considering the existence of a great number of minerals in which this element come across allied with Bismuth, samples of the mineralogical collection of the Museu Nacional, proceeding that region and classified as Bismuth minerals were studied by X-ray fluorescence analysis and diffractometric analysis. In this report the results of this research are presented. (Author)

  1. Lead-bismuth eutectic corrosion behaviors of ferritic/martensitic steels in low oxygen concentration environment

    OpenAIRE

    Liu, Jian; Shi, Quanqiang; Luan, He; Yan, Wei; Sha, Wei; Wang, Wei; Shan, Yiyin; Yang, Ke

    2015-01-01

    In order to investigate the compatibility of candidate structural materials with liquid metals, two kinds of ferritic/martensitic steels were chosen to contact with lead–bismuth eutectic in sealed quartz–glass tubes. The corrosion exposures were for 500 and 3000 h. Results showed that the oxidation layer and carbide dissolution layer on the two steels grew with contact time under oxygen unsaturated condition. Short-term corrosion behavior of a newly developed steel showed better lead–bismuth ...

  2. Comparison of radiation shielding ratios of nano-sized bismuth trioxide and molybdenum

    Science.gov (United States)

    Cho, J. H.; Kim, M. S.; Rhim, J. D.

    2015-07-01

    In this study, radiation shielding fibers using non-hazardous nano-sized bismuth trioxide and molybdenum instead of lead were developed and evaluated. Among the elements with high densities and atomic numbers, non-hazardous elements such as bismuth trioxide and molybdenum were chosen as a shielding element. Then, bismuth trioxide (Bi2O3) with average particle size 1-500 µm was ball milled for 10 min to produce a powdered form of nanoparticles with average particle size of 10-100 nm. Bismuth trioxide nanoparticles were dispersed to make a colloidal suspension, followed by spreading and hardening onto one or two sides of fabric, to create the radiation shielding fabric. The thicknesses of the shielding sheets using nano-sized bismuth and molybdenum were 0.4 and 0.7 mm. According to the lead equivalent test of X-ray shielding products suggested by KS, the equivalent dose was measured, followed by calculation of the shielding rate. The shielding rate of bismuth with 0.4 mm thickness and at 50 kVp was 90.5%, which is comparable to lead of 0.082 mm thickness. The shielding rate of molybdenum was 51.89%%, which is comparable to lead of 0.034 mm. At a thickness of 0.7 mm, the shielding rate of bismuth was 98.73%, equivalent to 0.101 mm Pb, whereas the shielding rate of molybdenum was 74.68%, equivalent to 0.045 mm Pb. In conclusion, the radiation shielding fibers using nano-sized bismuth developed in this study are capable of reducing radiation exposure by X-ray and its low-dose scatter ray.

  3. Ferroelectric thin film bismuth titanate prepared from acetate precursors

    Energy Technology Data Exchange (ETDEWEB)

    Lu, Yanxia; Hoelzer, D.T.; Schulze, W.A. [Alfred Univ., NY (United States); Tuttle, B.A.; Potter, B.G. [Sandia National Labs., Albuquerque, NM (United States)

    1994-10-01

    Bismuth titanate (Bi{sub 4}Ti{sub 3}O{sub 12}) thin films were fabricated by spin coat deposition followed by rapid thermal processing (RTP). Acetate derived solutions for deposition were synthesized by blending bismuth acetate in aqueous acetic acid and then adding titanium acetate. A series of electrically insulating, semiconducting and conducting substrates were evaluated for Bi{sub 4}Ti{sub 3}O{sub 12} film deposition. While X-ray diffraction and TEM analyses indicated that the initial perovskite crystallization temperature was 500{degrees}C or less for these Bi{sub 4}Ti{sub 3}O{sub 12} films, a 700{degrees}C crystallization treatment was used to obtain single phase perovskite films. Bi{sub 4}Ti{sub 3}O{sub 12} film crystallographic orientation was shown to depend on three factors: substrate surface morphology, the number of coating layers and thermal processing. While preferred c-direction orientation was observed for Bi{sub 4}Ti{sub 3}O{sub 12} films deposited on silver foil substrates, preferred a-direction orientation was obtained for films deposited on both Si and Pt coated Si wafers. The films were dense, smooth, crack free, and had grain sizes ranging from 20 nm to 100 nm. Film thickness and refractive index were determined using a combination of ellipsometry, waveguide refractometry and TEM measurements. Both low field dielectric and ferroelectric properties were measured for an 800 nm thick film deposited on a Pt coated MgO substrate. A remanent polarization of 38 {mu}C/cm{sup 2} and a coercive field of 98 kV/cm were measured for this film that was crystallized at 700{degrees}C.

  4. Thermal response of the multiplier of an accelerator-driven system to beam interruptions

    International Nuclear Information System (INIS)

    Thermal response of the multiplier of an accelerator-driven system to beam trips has been calculated for sodium cooled and lead-bismuth cooled multipliers. The temperature transients caused by a beam trip lead to thermal fatigue in structural components, and restoring the beam causes an additional temperature transient that adds to thermal fatigue. Design lifetimes for various multiplier components are calculated, based on the frequency of beam interruptions and on the thermal fatigue per interruption. Mitigation strategies to increase design lifetimes are discussed. (author)

  5. Thermal response of the multiplier of an accelerator driven system to beam interruptions

    International Nuclear Information System (INIS)

    Thermal response of the multiplier of an accelerator driven system to beam trips has been calculated for sodium cooled and lead-bismuth cooled multipliers. The temperature transients caused by a beam trip lead to thermal fatigue in structural components, and restoring the beam causes an additional temperature transient that adds to thermal fatigue. Design lifetimes for various multiplier components are calculated, based on the frequency of beam interruptions and on the thermal fatigue per interruption. Mitigation strategies to increase design lifetimes are discussed

  6. Nano sized bismuth oxy chloride by metal organic chemical vapour deposition

    Energy Technology Data Exchange (ETDEWEB)

    Jagdale, Pravin, E-mail: pravin.jagdale@polito.it [Department of Applied Science and Technology (DISAT), Politecnico di Torino, 10129 (Italy); Castellino, Micaela [Center for Space Human Robotics, Istituto Italiano di Tecnologia, Corso Trento 21, 10129 Torino (Italy); Marrec, Françoise [Laboratory of Condensed Matter Physics, University of Picardie Jules Verne (UPJV), Amiens 80039 (France); Rodil, Sandra E. [Instituto de Investigaciones en Materiales, Universidad Nacional Autonoma de Mexicom (UNAM), Mexico D.F. 04510 (Mexico); Tagliaferro, Alberto [Department of Applied Science and Technology (DISAT), Politecnico di Torino, 10129 (Italy)

    2014-06-01

    Metal organic chemical vapour deposition (MOCVD) method was used to prepare thin films of bismuth based nano particles starting from bismuth salts. Nano sized bismuth oxy chloride (BiOCl) crystals were synthesized from solution containing bismuth chloride (BiCl{sub 3}) in acetone (CH{sub 3}-CO-CH{sub 3}). Self-assembly of nano sized BiOCl crystals were observed on the surface of silicon, fused silica, copper, carbon nanotubes and aluminium substrates. Various synthesis parameters and their significant impact onto the formation of self-assembled nano-crystalline BiOCl were investigated. BiOCl nano particles were characterized by X-ray diffraction, X-ray photoelectron spectroscopy, field emission scanning electron microscopy, energy-dispersive X-ray spectroscopy and Micro-Raman spectroscopy. These analyses confirm that bismuth nanometer-sized crystal structures showing a single tetragonal phase were indeed bismuth oxy chloride (BiOCl) square platelets 18–250 nm thick and a few micrometres wide.

  7. Adverse events with bismuth salts for Helicobacter pylori eradication:Systematic review and meta-analysis

    Institute of Scientific and Technical Information of China (English)

    Alexander C Ford; Peter Malfertheiner; Monique Giguére; José Santana; Mostafizur Khan; Paul Moayyedi

    2008-01-01

    AIM:To assess the safety of bismuth used in Helicobacter pylori (H pylori) eradication therapy regimens.METHODS:We conducted a systematic review and meta-analysis.MEDLINE and EMBASE were searched (up to October 2007) to identify randomised controlled trials comparing bismuth with placebo or no treatment,or bismuth salts in combination with antibiotics as part of eradication therapy with the same dose and duration of antibiotics alone or,in combination,with acid suppression.Total numbers of adverse events were recorded.Data were pooled and expressed as relative risks with 95% confidence intervals (CI).RESULTS:We identified 35 randomised controlled trials containing 4763 patients.There were no serious adverse events occurring with bismuth therapy.There was no statistically significant difference detected in total adverse events with bismuth [relative risk (RR)=1.01;95% CI:0.87-1.16],specific individual adverse events,with the exception of dark stools (RR = 5.06;95% CI:1.59-16.12),or adverse events leading to withdrawal of therapy (RR = 0.86;95% CI:0.54-1.37).CONCLUSION:Bismuth for the treatment of H pylori is safe and well-tolerated.The only adverse event occurring significantly more commonly was dark stools.

  8. Nonlinear beam-beam resonances

    International Nuclear Information System (INIS)

    Head-on collisions of bunched beams are considered, assuming the two colliding beams have opposite charges. A few experimental observations are described. The single resonance analysis is developed that is applicable to the strong-weak case of the beam-beam interaction. In this case, the strong beam is unperturbed by the beam-beam interaction; motions of the weak beam particles are then analyzed in the presence of the nonlinear electromagnetic force produced by the strong beam at the collision points. The coherent motions of the two coupled strong beams are shown to exhibit distinct nonlinear resonance behavior. 16 refs., 22 figs

  9. Windowless Electron Beam Experimental Irradiation WEBExplr

    International Nuclear Information System (INIS)

    The design of the MYRRHA/XT-ADS, the European eXperimental Accelerator Driven System for the demonstration of Transmutation, includes a high power windowless spallation target operating with liquid LBE (Lead-Bismuth Eutectic) that will be irradiated with a 600 MeV proton beam at currents of up to 2.5 mA. When considering such a high power windowless target design, a number of questions need to be addressed, such as the stability of the free surface flow and its ability to remove the power deposited by the proton beam by forced convection, the compatibility of a large hot LBE reservoir with the beam line vacuum and the outgassing of the LBE in the spallation target circuit. These issues have been studied during previous experiments supported by numerical simulations. Another crucial point in the development of the spallation target is the demonstration of the safe and stable operation of the free LBE surface during irradiation with a high power proton beam. As a first step in this program, the WEBExpIr (Windowless target Electron Beam Experimental Irradiation) experiment was set up. The purpose of the WEBExpIr experiment was to investigate the influence of LBE surface heating caused by a charged particle beam in a situation representative of the MYRRHA/XT-ADS. More in particular, we wanted to assess possible free surface distortion or shockwave effects in nominal conditions and during sudden beam on/off transient situations, as well as possible enhanced evaporation

  10. Spark plasma sintered bismuth telluride-based thermoelectric materials incorporating dispersed boron carbide

    Energy Technology Data Exchange (ETDEWEB)

    Williams, H.R., E-mail: hugo.williams@leicester.ac.uk [Department of Engineering, University of Leicester, University Road, Leicester LE1 7RH (United Kingdom); Ambrosi, R.M. [Space Research Centre, Department of Physics and Astronomy, University of Leicester, University Road, Leicester LE1 7RH (United Kingdom); Chen, K. [School of Engineering and Materials Science, Queen Mary, University of London, Mile End Road, London E1 4NS (United Kingdom); Friedman, U. [Department of Engineering, University of Leicester, University Road, Leicester LE1 7RH (United Kingdom); Ning, H.; Reece, M.J. [School of Engineering and Materials Science, Queen Mary, University of London, Mile End Road, London E1 4NS (United Kingdom); Robbins, M.C.; Simpson, K. [European Thermodynamics Ltd., 8 Priory Business Park, Wistow Road, Kibworth LE8 0R (United Kingdom); Stephenson, K. [European Space Agency, ESTEC TEC-EP, Keplerlaan 1, 2201AZ Noordwijk (Netherlands)

    2015-03-25

    Highlights: • Nano-B{sub 4}C reinforced Bi{sub 0.5}Sb{sub 1.5}Te{sub 3} p-type thermoelectric produced by SPS. • Addition of B{sub 4}C up to 0.2 vol% to SPS’d material has little effect on zT. • Vickers hardness improved by 27% by adding 0.2 vol% B{sub 4}C. • Fracture toughness of SPS material: K{sub IC} = 0.80 MPa m{sup 1/2} by SEVNB. • Mechanical properties much better than commercial directionally solidified material. - Abstract: The mechanical properties of bismuth telluride based thermoelectric materials have received much less attention in the literature than their thermoelectric properties. Polycrystalline p-type Bi{sub 0.5}Sb{sub 1.5}Te{sub 3} materials were produced from powder using spark plasma sintering (SPS). The effects of nano-B{sub 4}C addition on the thermoelectric performance, Vickers hardness and fracture toughness were measured. Addition of 0.2 vol% B{sub 4}C was found to have little effect on zT but increased hardness by approximately 27% when compared to polycrystalline material without B{sub 4}C. The K{sub IC} fracture toughness of these compositions was measured as 0.80 MPa m{sup 1/2} by Single-Edge V-Notched Beam (SEVNB). The machinability of polycrystalline materials produced by SPS was significantly better than commercially available directionally solidified materials because the latter is limited by cleavage along the crystallographic plane parallel to the direction of solidification.

  11. Electrical transport measurements of individual bismuth nanowires and carbon nanotubes

    Science.gov (United States)

    Jang, Wan Young

    Nanostructures are defined by reducing dimensions. When the reduced size of materials is comparable to the Fermi wavelength, quantum size effect occurs. Dimensionality plays a critical role in determining the electronic properties of materials, because the density of states of materials is quite different. Nanowires have attracted much attention recently due to their fundamental interest and potential applications. A number of materials have been tried. Among them, bismuth has unique properties. Bismuth has the smallest effective mass as small as 0.001me. This small effective mass of Bi nanowires allows one to observe the quantum confinement effect easily. Also Bi nanowires are good candidates for a low-dimensional transport study due to long mean free path. Because of these remarkable properties of Bi nanowires, many efforts have been made to study Bi nanowires. However, because bismuth is extremely sensitive to the oxide, it is very difficult to make a reliable device. So far, array measurements of Bi nanowires have been reported. The study is focused on the synthesis and electric transport measurements of individual Bi nanowires. Bi nanowires are synthesized by electrodeposition using either anodic aluminum oxide (AAO) templates or commercially available track etched polycarbonate membranes (PCTE). The desired nanowire has a heterostructure of Au - Bi - Au. Au wires on both sides serve as contact electrodes with Bi. To extract nanowires from PCTE or AAO, several attempts have been made. Devices consisting of single Bi nanowires grown by hydrothermal method are fabricated and electrical measurements have been carried out after in-situ deposition of Pt electrodes. The temperature dependence of resistance of majority of nanowires increases with decreasing temperature, showing polycrystalline nature of nanowires. However, some nanowires show resistance peaks at low temperature, suggesting quantum size effect (QSE). Magnetoresistance (MR) has also been measured. We

  12. Corrosion behavior of Si-enriched steels for nuclear applications in liquid lead–bismuth

    Energy Technology Data Exchange (ETDEWEB)

    Kurata, Yuji, E-mail: kurata.yuji@jaea.go.jp [Japan Atomic Energy Agency, Tokai-mura, Ibaraki-ken 319-1195 (Japan)

    2013-06-15

    Highlights: ► The corrosion behavior of Si-enriched steels in liquid lead–bismuth was studied. ► The corrosion tests were conducted at the two controlled oxygen levels. ► The Si addition reduces the scale thickness under the high oxygen condition. ► The Si addition has no significant effect under the low oxygen condition. -- Abstract: The corrosion behavior of Si-enriched steels in liquid lead–bismuth was studied in order to develop accelerator driven systems for transmutation of long-lived radioactive wastes and lead–bismuth cooled fast reactors. The corrosion tests of 316SS, Si-enriched 316SS, Mod.9Cr–1Mo steel (T91) and Si-enriched T91 were conducted at 550 °C in liquid lead–bismuth at the two controlled oxygen levels. Both the additions of 2.5 wt.% Si to 316SS and 1.5 wt.% Si to T91 had the effect of reducing the thickness of oxide layer in liquid lead–bismuth at the high oxygen concentration (2.5 × 10{sup −5} wt.%). Although the Si addition to 316SS reduced the depth of ferritization caused by Ni dissolution in liquid lead–bismuth at the low oxygen concentration (4.4 × 10{sup −8} wt.%), it could not suppress the ferritization and the penetration of Pb and Bi completely. The Si addition to T91 did not have the effect of preventing the penetration of Pb and Bi in the liquid lead–bismuth at the low oxygen concentration. The oxide scales formed on both Si-enriched steels did not have sufficient corrosion resistance under the low oxygen condition.

  13. Bismuth oxide aqueous colloidal nanoparticles inhibit Candida albicans growth and biofilm formation

    Directory of Open Access Journals (Sweden)

    Hernandez-Delgadillo R

    2013-04-01

    Full Text Available Rene Hernandez-Delgadillo,1 Donaji Velasco-Arias,3 Juan Jose Martinez-Sanmiguel,2 David Diaz,3 Inti Zumeta-Dube,3 Katiushka Arevalo-Niño,1 Claudio Cabral-Romero2 1Facultad de Ciencias Biológicas, Instituto de Biotecnologia, Universidad Autonoma de Nuevo Leon, UANL, Monterrey, Mexico; 2Facultad de Odontología, Universidad Autonoma de Nuevo Leon, UANL, Monterrey, México; 3Facultad de Quimica, Universidad Nacional Autonoma de Mexico, UNAM, Distrito Federal, México Abstract: Multiresistance among microorganisms to common antimicrobials has become one of the most significant concerns in modern medicine. Nanomaterials are a new alternative to successfully treat the multiresistant microorganisms. Nanostructured materials are used in many fields, including biological sciences and medicine. Recently, it was demonstrated that the bactericidal activity of zero-valent bismuth colloidal nanoparticles inhibited the growth of Streptococcus mutans; however the antimycotic potential of bismuth nanostructured derivatives has not yet been studied. The main objective of this investigation was to analyze the fungicidal activity of bismuth oxide nanoparticles against Candida albicans, and their antibiofilm capabilities. Our results showed that aqueous colloidal bismuth oxide nanoparticles displayed antimicrobial activity against C. albicans growth (reducing colony size by 85% and a complete inhibition of biofilm formation. These results are better than those obtained with chlorhexidine, nystatin, and terbinafine, the most effective oral antiseptic and commercial antifungal agents. In this work, we also compared the antimycotic activities of bulk bismuth oxide and bismuth nitrate, the precursor metallic salt. These results suggest that bismuth oxide colloidal nanoparticles could be a very interesting candidate as a fungicidal agent to be incorporated into an oral antiseptic. Additionally, we determined the minimum inhibitory concentration for the synthesized

  14. New bismuth borophosphate Bi4BPO10: Synthesis, crystal structure, optical and band structure analysis

    International Nuclear Information System (INIS)

    New bismuth borophosphate Bi4BPO10 was obtained by spontaneous crystallization from the melt of correspondent composition at 804 °C. Crystal structure with orthorhombic lattice parameters: a = 22.5731(3) Å, b = 14.0523(2) Å, c = 5.5149(1) Å, V = 1749.34(4), Z = 8, SG Pcab was determined by X-ray powder diffraction technique. The [Bi2O2]2+ -layers, which are typical for bismuth oxide compounds, transform into cationic endless strips of 4 bismuth atoms width directed along the c-axis in Bi4BPO10. The strips combining stacks are separated by flat triangle [BO3]3− -anions within stacks. Neighboring stacks are separated by tetrahedral [PO4]3−-anions and shifted relatively to each other. Bismuth atoms are placed in 5–7 vertex oxygen irregular polyhedra. Bi4BPO10 is stable up to 812 °C, then melts according to the peritectic law. The absorption spectrum in the range 350–700 nm was obtained and the width of the forbidden band was estimated as 3.46 eV. The band electronic structure of Bi4BPO10 was modeled using DFT approach. The calculated band gap (3.56 eV) is in good agreement with the experimentally obtained data. - Graphical abstract: Display Omitted - Highlights: • New bismuth borophosphate with composition Bi4BPO10 was synthesized. • The crystal structure was determined by X-ray powder diffraction technique. • Bismuth-oxygen part [Bi4O3]6+ forms endless strips of 4 bismuth atoms width. • Electronic structure was modeled by DFT method. • The calculated band gap (3.56 eV) is very close to the experimental one (3.46 eV)

  15. Zerovalent bismuth nanoparticles inhibit Streptococcus mutans growth and formation of biofilm

    Directory of Open Access Journals (Sweden)

    Hernandez-Delgadillo R

    2012-04-01

    Full Text Available Rene Hernandez-Delgadillo1, Donaji Velasco-Arias2, David Diaz2, Katiushka Arevalo-Niño1, Marianela Garza-Enriquez1, Myriam A De la Garza-Ramos1, Claudio Cabral-Romero11Instituto de Biotecnologia, Centro de Investigacion y Desarrollo en Ciencias de la Salud, CIDICS, Facultad de Odontologia, Universidad Autonoma de Nuevo Leon, UANL, Monterrey, Nuevo Leon, 2Facultad de Quimica, Universidad Nacional Autonoma de Mexico, Distrito Federal, MexicoBackground and methods: Despite continuous efforts, the increasing prevalence of resistance among pathogenic bacteria to common antibiotics has become one of the most significant concerns in modern medicine. Nanostructured materials are used in many fields, including biological sciences and medicine. While some bismuth derivatives has been used in medicine to treat vomiting, nausea, diarrhea, and stomach pain, the biocidal activity of zerovalent bismuth nanoparticles has not yet been studied. The objective of this investigation was to analyze the antimicrobial activity of bismuth nanoparticles against oral bacteria and their antibiofilm capabilities.Results: Our results showed that stable colloidal bismuth nanoparticles had 69% antimicrobial activity against Streptococcus mutans growth and achieved complete inhibition of biofilm formation. These results are similar to those obtained with chlorhexidine, the most commonly used oral antiseptic agent. The minimal inhibitory concentration of bismuth nanoparticles that interfered with S. mutans growth was 0.5 mM.Conclusion: These results suggest that zerovalent bismuth nanoparticles could be an interesting antimicrobial agent to be incorporated into an oral antiseptic preparation.Keywords: zerovalent bismuth nanoparticles, antimicrobial agent, biofilm, Streptococcus mutans

  16. Weak Lensing Mass Reconstruction of the Galaxy Cluster Abell 209

    CERN Document Server

    Paulin-Henriksson, S; Haines, C P; Radovich, M; Mercurio, A; Becciani, U

    2007-01-01

    Weak lensing applied to deep optical images of clusters of galaxies provides a powerful tool to reconstruct the distribution of the gravitating mass associated to these structures. We use the shear signal extracted by an analysis of deep exposures of a region centered around the galaxy cluster Abell 209, at redshift z=0.2, to derive both a map of the projected mass distribution and an estimate of the total mass within a characteristic radius. We use a series of deep archival R-band images from CFHT-12k, covering an area of 0.3 deg^2. We determine the shear of background galaxy images using a new implementation of the modified Kaiser-Squires-Broadhurst pipeline for shear determination, which we has been tested against the ``Shear TEsting Program 1 and 2'' simulations. We use mass aperture statistics to produce maps of the 2 dimensional density distribution, and parametric fits using both Navarro-Frenk-White (NFW) and singular-isothermal-sphere profiles to constrain the total mass. The projected mass distributi...

  17. Measurement of high energy neutrons (E > 50 MeV) at electron accelerators of INDUS accelerator complex using bismuth fission detectors

    International Nuclear Information System (INIS)

    This paper reports the measurement of high energy neutron component (E > 50 MeV) carried out at INDUS-I (450 MeV) and INDUS-II (2.5 GeV) electron accelerators (RRCAT, Indore, India). The study is based on the registration of neutron induced fission fragments from bismuth films in solid polymeric track detectors. These BFD stacks were exposed at the injection septums of booster synchrotron, Indus-1 and Indus-2 storage rings, where the possibility of dose due to beam loss is expected to be maximum. The detection efficiency of the bismuth fission detector (BFD) could be enhanced by enlarging the detector surface area and accordingly a large area spark counter was fabricated for automatic and rapid counting of the track densities. The dose equivalent rates were found to be 11.0 ± 0.7 mrem/h (73 h total exposure time), 11.0 ± 2.6 mrem/h (35 h total exposure time) and 65.0 mrem/h (5 h total exposure time) for the injection septums of booster synchrotron, Indus-1 and Indus-2 respectively. However, the values reported here were not corrected for the contribution from photo fissions, if any. (author)

  18. Optical and morphological study of misoriented GaAs substrates exposed to bismuth flow using in situ spectral reflectance and atomic force microscopy

    Science.gov (United States)

    Massoudi, I.; Habchi, M. M.; Rebey, A.; El Jani, B.

    2012-08-01

    (100) GaAs substrates with different misorientations were exposed to trimethyl-bismuth (TMBi) flow. The wafers were examined after exposure times of 9 and 43 min. The wafers growth was carried out at atmospheric pressure, in a metalorganic vapor phase epitaxy (MOVPE) reactor, at a temperature of 375 °C. The in situ spectral reflectance (SR) in the spectral range 400-1000 nm was used to monitor the deposition. The reflectivity is marked by two temporal phases, an increase followed by a slow decrease. The atomic force microscopy (AFM) measurements show two different growth modes of bismuth, big isolated islands for early exposure time and a high density of small islands for long exposure times. We also note that the islands' density and size change greatly with the misorientation of the substrate. The correlation between the results given by ex situ AFM and in situ SR is performed via theoretical simulations. We show that roughness, as well as optical and thermal effects are mainly responsible for the reflectivity behavior. We have successfully quantified the spectral evolution of the sensitivity σSR of the incident beam wavelength to the surface undulations.

  19. Developments of 207Pb, 208Pb and 209Bi target wheels in the synthesis of 107Ns, 108Hs and 109Mt

    International Nuclear Information System (INIS)

    The developments of 207Pb, 208Pb and 209Bi target wheels and their applications in heavy-ion fusion reactions are reviewed. In both, fabrication and use, the centers of the evaporator or accelerator beams are focussed at wheel radii of 155 mm to specially shaped frames which generate very homogeneous target layers and very constant reaction and counting rates in the experiment. Target areas of up to ∼98% of a wheel's circumference of 974 mm can be provided. The preparation procedures for necessary C backings and protecting layers of C are described, and details are given for the developments of high-vacuum evaporations of 207Pb, 208Pb and 209Bi with deposition yields of 35-55% from tantalum crucibles. The applications of the target wheels in heavy-ion fusion reactions with beams of 54Cr and 58Fe at energies near the Coulomb barrier and intensities of ∼1012 particles/s are mentioned. The target parameters for the production runs of the new chemical elements 107Ns, 108Hs and 109Mt are included. (orig.)

  20. Synthesis, Characterization and Molecular Structures of some Bismuth(III) Complexes with Thiosemicarbazones and Dithiocarbazonic Acid Methylester Derivatives with Activity against Helicobacter Pylori

    OpenAIRE

    Diemer, Rolf; Dittes, Uwe; Nuber, Bernhard; Seifried, Volker; Opferkuch, Wolfgang; Keppler, Bernhard K.

    1995-01-01

    The reactions of bismuth(III) nitrate pentahydrate and bismuth(III) chloride with heterocyclic thiosemicarbazones and derivatives of dithiocarbazonic acid methylester were used to synthesize the respective bismuth(III) complexes, which could be divided into five groups D-H because of their stoichiometrical properties and their molecular structures. The molecular structure and the near coordination sphere of the bismuth(III) central atom of four representative compounds were determined by sing...

  1. Fission of 209Bi, natPb and 197Au in the particle field of a fast accelerator driven system

    International Nuclear Information System (INIS)

    Highlights: ► Fission rates of Bi, Pb and Au were measured in a particle field similar to that of fast ADS. ► The experimental results on fission rates are in agreement with MCNPX calculations. ► The most up to date fission cross-sections and related parameterizations were used. ► New parameterizations were produced from the published cross-section data. - Abstract: Accelerator driven systems (ADS) are expected to have particle spectra of significantly greater energy range than that of current power reactors. The Energy plus Transmutation (EpT) set-up of the Joint Institute for Nuclear Research, Dubna, Russia, is designed to emulate the neutron spectrum in a fast ADS through the use of a spallation target surrounded by a blanket of natural uranium. The spectrum is further modified by a reflective layer of polyethylene and an internal absorbing layer of cadmium. The spallation target of EpT was irradiated with a beam of 4 GeV deuterons, and the fission rates of bismuth, lead and gold samples, placed in the target-blanket region were recorded using a fission track detector technique. The fission rates were also calculated using the MCNPX Monte Carlo code with the INCL4 cascade model and cross sections for nucleon induced fission obtained from literature. Agreement between the measured and calculated results indicates the model’s ability to predict the particle spectra and spatial distribution

  2. BDE-209: kinetic studies and effect of humic substances on photodegradation in water.

    Science.gov (United States)

    Leal, J F; Esteves, V I; Santos, E B H

    2013-12-17

    BDE-209 is a brominated flame retardant and a priority contaminant, which has been found in several environmental matrices, namely, in water. To date, there are no quantum yield data for BDE-209 photodegradation by sunlight in water, to allow predicting half-life times in aquatic systems. In this work, the kinetics of BDE-209 photodegradation in water was studied and the influence of different fractions of aquatic humic substances (HS) was evaluated. Aqueous solutions of BDE-209 exposed for different periods of time to simulated sunlight were analyzed by HPLC-UV after being concentrated using dispersive liquid-liquid microextraction (DLLME) or solid-phase extraction (SPE). The photodegradation of BDE-209 in aqueous solution followed pseudo-first-order kinetics. The average quantum yield obtained of 0.010 ± 0.001 (about 20-fold lower than the quantum yield determined in ethanol) allow to predict an outdoor half-life time of 3.5 h. The photodegradation percentage of BDE-209 was not significantly affected by the XAD-4 fraction of HS, but it decreased substantially in the presence of humic and fulvic acids. Light screening by the humic substances could not explain this delay, which is probably the result of the association of the compound with the hydrophobic sites of the humic material. PMID:24245794

  3. Effect of cadmium ion on biodegradation of decabromodiphenyl ether (BDE-209) by Pseudomonas aeruginosa

    International Nuclear Information System (INIS)

    Highlights: • BDE-209 degradation by P. aeruginosa in the presence of Cd was investigated. • Degradation was accelerated by the increase of CSH induced by low level of Cd. • Higher membrane permeability caused by low level of Cd promoted degradation. • Depression of cell growth and metabolism by high content Cd inhibited degradation. -- Abstract: The influence of Cd(II) ions on the degradation of decabromodiphenyl ether (BDE-209) by an aerobic degrading strain, Pseudomonas aeruginosa, was investigated. The results demonstrated that the strain P. aeruginosa exhibited a high level of resistance against cadmium toxicity, and Cd(II) ions of different concentrations possessed mixed reactions on BDE-209 bioremoval. The degradation efficiency was stimulated at low concentrations of Cd(II) ions (≤1 mg L−1) but inhibited at higher levels (≥5 mg L−1). Subsequent analyses revealed that the increase of cell hydrophobicity and membrane permeability were two main factors for Cd(II) ions of low concentrations to accelerate BDE-209 degradation. However, inhibition effect by high concentrations of Cd(II) ions was mainly attributed to the negative impact of metals on growth and metabolism of the strain. It was also showed through cellular distribution of BDE-209 that different concentration of Cd(II) ions affected the amount of BDE-209 inside or outside the cell at different incubation time

  4. Effect of cadmium ion on biodegradation of decabromodiphenyl ether (BDE-209) by Pseudomonas aeruginosa

    Energy Technology Data Exchange (ETDEWEB)

    Shi, Guangyu [State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Science, Guangzhou 510640 (China); Yin, Hua, E-mail: huayin@scut.edu.cn [Key Laboratory of Pollution Control and Ecosystem Restoration in Industry Clusters, Ministry of Education, College of Environment and Energy, South China University of Technology, Guangzhou 510006 (China); Ye, Jinshao [Department of Environmental Engineering, Jinan University, Guangzhou 510632 (China); Peng, Hui [Department of Chemistry, Jinan University, Guangzhou 510632 (China); Li, Jun; Luo, Chunling [State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Science, Guangzhou 510640 (China)

    2013-12-15

    Highlights: • BDE-209 degradation by P. aeruginosa in the presence of Cd was investigated. • Degradation was accelerated by the increase of CSH induced by low level of Cd. • Higher membrane permeability caused by low level of Cd promoted degradation. • Depression of cell growth and metabolism by high content Cd inhibited degradation. -- Abstract: The influence of Cd(II) ions on the degradation of decabromodiphenyl ether (BDE-209) by an aerobic degrading strain, Pseudomonas aeruginosa, was investigated. The results demonstrated that the strain P. aeruginosa exhibited a high level of resistance against cadmium toxicity, and Cd(II) ions of different concentrations possessed mixed reactions on BDE-209 bioremoval. The degradation efficiency was stimulated at low concentrations of Cd(II) ions (≤1 mg L{sup −1}) but inhibited at higher levels (≥5 mg L{sup −1}). Subsequent analyses revealed that the increase of cell hydrophobicity and membrane permeability were two main factors for Cd(II) ions of low concentrations to accelerate BDE-209 degradation. However, inhibition effect by high concentrations of Cd(II) ions was mainly attributed to the negative impact of metals on growth and metabolism of the strain. It was also showed through cellular distribution of BDE-209 that different concentration of Cd(II) ions affected the amount of BDE-209 inside or outside the cell at different incubation time.

  5. Altitudinal distributions of BDE-209 and other polybromodiphenyl ethers in high mountain lakes

    International Nuclear Information System (INIS)

    The present study shows the occurrence of 2,2',3,3',4,4',5,5',6,6'-decabromodiphenyl ether (BDE-209) in microbial biofilms of Pyrenean and Tatra high mountain lakes despite its low vapor pressure and high hydrophobicity. Aerosol air transport is therefore a feasible mechanism for BDE-209 accumulation in sites up to 2688 m above sea level. This compound and other PBDEs exhibit altitudinally-dependent distribution involving higher concentrations with increasing mountain lake elevation. However, the apparently very high enthalpies of the concentration gradients observed, including BDE-209, suggest that bacterial anaerobic debromination also plays a significant role in the resulting altitudinal distributions. This microbial mechanism explains the relative abundances of PBDEs and their within lake differences between rocky and sediment microbial biofilms, thereby showing that the altitudinal pattern observed is not purely due to water temperature control on bacterial activity but also to changes in the availability of anaerobic microenvironments which increase with increasing lake productivity at lower altitudes. - Highlights: → BDE-209 is found in high mountain areas despite its low vapor pressure. → Aerosol air transport may transport BDE-209 to high mountain sites. → BDE-209 and PBDEs exhibit altitudinally-dependent distributions. → PBDE bacterial anaerobic debromination is important in mountain areas. → Biodegradation may generate altitudinal and latitudinal concentration gradients. - Decabromodiphenyl ether and the other polybromodiphenyl congeners show vertical distributions in high mountains due to temperature effects and microbial degradation.

  6. Altitudinal distributions of BDE-209 and other polybromodiphenyl ethers in high mountain lakes

    Energy Technology Data Exchange (ETDEWEB)

    Bartrons, Mireia [Department of Environmental Chemistry, Institute of Environmental Assessment and Water Research (IDAEA-CSIC), Jordi Girona, 18, 08034 Barcelona, Catalonia (Spain); Limnology Unit (CSIC-UB), Centre for Advanced Studies of Blanes (CEAB-CSIC), Acces Cala St. Francesc, 14, 17300 Blanes, Catalonia (Spain); Grimalt, Joan O., E-mail: joan.grimalt@idaea.csic.es [Department of Environmental Chemistry, Institute of Environmental Assessment and Water Research (IDAEA-CSIC), Jordi Girona, 18, 08034 Barcelona, Catalonia (Spain); Catalan, Jordi [Limnology Unit (CSIC-UB), Centre for Advanced Studies of Blanes (CEAB-CSIC), Acces Cala St. Francesc, 14, 17300 Blanes, Catalonia (Spain)

    2011-07-15

    The present study shows the occurrence of 2,2',3,3',4,4',5,5',6,6'-decabromodiphenyl ether (BDE-209) in microbial biofilms of Pyrenean and Tatra high mountain lakes despite its low vapor pressure and high hydrophobicity. Aerosol air transport is therefore a feasible mechanism for BDE-209 accumulation in sites up to 2688 m above sea level. This compound and other PBDEs exhibit altitudinally-dependent distribution involving higher concentrations with increasing mountain lake elevation. However, the apparently very high enthalpies of the concentration gradients observed, including BDE-209, suggest that bacterial anaerobic debromination also plays a significant role in the resulting altitudinal distributions. This microbial mechanism explains the relative abundances of PBDEs and their within lake differences between rocky and sediment microbial biofilms, thereby showing that the altitudinal pattern observed is not purely due to water temperature control on bacterial activity but also to changes in the availability of anaerobic microenvironments which increase with increasing lake productivity at lower altitudes. - Highlights: > BDE-209 is found in high mountain areas despite its low vapor pressure. > Aerosol air transport may transport BDE-209 to high mountain sites. > BDE-209 and PBDEs exhibit altitudinally-dependent distributions. > PBDE bacterial anaerobic debromination is important in mountain areas. > Biodegradation may generate altitudinal and latitudinal concentration gradients. - Decabromodiphenyl ether and the other polybromodiphenyl congeners show vertical distributions in high mountains due to temperature effects and microbial degradation.

  7. Electrochemical study on determination of diffusivity, activity and solubility of oxygen in liquid bismuth

    Energy Technology Data Exchange (ETDEWEB)

    Ganesan, Rajesh [Liquid Metals and Structural Chemistry Division, Chemistry Group, Indira Gandhi Centre for Atomic Research, Kalpakkam 603 102 (India); Gnanasekaran, T. [Liquid Metals and Structural Chemistry Division, Chemistry Group, Indira Gandhi Centre for Atomic Research, Kalpakkam 603 102 (India)]. E-mail: gnani@igcar.ernet.in; Srinivasa, Raman S. [Department of Metallurgical Engineering and Materials Science, Indian Institute of Technology Bombay, Mumbai 400 076 (India)

    2006-06-15

    Diffusivity of oxygen in liquid bismuth was measured by potentiostatic method and is given bylg(D{sub O}{sup Bi}/cm{sup 2}.s{sup -1})(+/-0.042)=-3.706-1377/(TK{sup -1})(804bismuth was determined by coulometric titrations and using the measured data standard free energy of dissolution of oxygen in liquid bismuth was derived for the reaction:1/2O{sub 2}(g)=[O]{sub Bi}(at.%)and is given by{delta}G{sub O(Bi)}{sup o}/(J.g-atomO{sup -1})(+/-720)=-108784+20.356TK{sup -1}(753bismuth was derived as a function of temperature and is given by the following expressions:lg(S/at%O)(+/-0.05)=-4476/TK{sup -1}+4.05(753bismuth is compared with the literature data.

  8. Bismuth nanoparticles synthesized by laser ablation in lubricant oils for tribological tests

    International Nuclear Information System (INIS)

    Highlights: • Bismuth nanoparticles have been obtained by laser ablation of solids in liquids. • The technique allows controlling the size and concentration of the samples. • Bi np’s in base oils can improve the tribological characteristics of the lubricant. - Abstract: The improvement of the tribological properties of mineral base oils through the addition of bismuth nanoparticles as an additive, together with the idea of obtaining lubricants free of heavy metals, was evaluated. Bismuth nanoparticles were produced directly in the heavy and light viscosity mineral base oils (BS900 and BS6500) using the technique of laser ablation of solids immersed in liquids. Transmission electron microscopy measurements showed the presence of pure bismuth nanoparticles. Small Angle X-ray Scattering (SAXS) measurements showed that the average size of the nanoparticles was between 7 and 65 nm depending on the experimental conditions used. The tribological properties of the base oil with the bismuth nanoparticles additives were evaluated using a four-ball tester. Tests were performed using the base oil with and without Bi nanoparticles. It was observed that the coefficient of friction of the oil decrease with an increasing concentration of the nanoparticles. The results also showed that the wear rate was reduced when the Bi nanoparticle additives were used

  9. Crystallinity and electrical properties of neodymium-substituted bismuth titanate thin films

    International Nuclear Information System (INIS)

    We report on the properties of Nd-substituted bismuth titanate Bi4-xNd xTi3O12 (BNdT) thin films for ferroelectric non-volatile memory applications. The Nd-substituted bismuth titanate thin films fabricated by modified chemical solution deposition technique showed much improved properties compared to pure bismuth titanate. A pyrochlore free crystalline phase was obtained at a low annealing temperature of 640 deg. C and grain size was found to be considerably increased as the annealing temperature increased. The film properties were found to be strongly dependent on the Nd content and annealing temperatures. The measured dielectric constant of BNdT thin films was in the range 172-130 for Bi4-xNd xTi3O12 with x 0.0-0.75. Ferroelectric properties of Nd-substituted bismuth titanate thin films were significantly improved compared to pure bismuth titanate. For example, the observed 2P r and E c for Bi3.25Nd0.75Ti3O12, annealed at 680 deg. C, were 38 μC/cm2 and 98 kV/cm, respectively. The improved microstructural and ferroelectric properties of BNdT thin films suggest their suitability for high density ferroelectric random access memory applications

  10. Bismuth Modified Carbon-Based Electrodes for the Determination of Selected Neonicotinoid Insecticides

    Directory of Open Access Journals (Sweden)

    Marko Rodić

    2011-05-01

    Full Text Available Two types of bismuth modified electrodes, a bismuth-film modified glassy carbon (BiF-GCE and a bismuth bulk modified carbon paste, were applied for the determination of selected nitroguanidine neonicotinoid insecticides. The method based on an ex situ prepared BiF-GCE operated in the differential pulse voltammetric (DPV mode was applied to determine clothianidin in the concentration range from 2.5 to 23 μg cm−3 with a relative standard deviation (RSD not exceeding 1.5%. The tricresyl phosphate-based carbon paste electrodes (TCP-CPEs, bulk modified with 5 and 20 w/w% of bismuth, showed a different analytical performance in the determination of imidacloprid, regarding the peak shape, potential window, and noise level. The TCP-CPE with 5% Bi was advantageous, and the developed DPV method based on it allowed the determination in the concentration range from 1.7 to 60 μg cm−3 with an RSD of 2.4%. To get a deeper insight into the morphology of the bismuth-based sensor surfaces, scanning electron microscopic measurements were performed of both the surface film and the bulk modified electrodes.

  11. Bioaccumulation and biosorption of bismuth Bi (III) by filamentous fungus Aspergillus clavatus

    International Nuclear Information System (INIS)

    In this work we focused on bismuth (III) biosorption and bioaccumulation. Prior the bioaccumulation experiments the 7-day-old conidia were collected from mycelia surface of filamentous fungus Aspergillus clavatus and used as inocula for 50 ml of nutrient media with different bismuth (III) concentrations. After 15-day cultivation under laboratory conditions (dark, 25 grad C) the bismuth concentration in grown fungal biomass was measured using ICP OES. Maximum achieved accumulation capacity of dry biomass was 112 μmol.g-1. Batch biosorption experiments were performed in Erlenmeyer flasks with pelletized wet fungal biomass/solution ratio 1.8% and with various bismuth (III) concentrations. The equilibrium time was studied within the time interval of 0-240 min. The reaction kinetics were well described by both pseudo-first and pseudo-second order rate models, and equilibrium was reached after 50 min. Langmuir and Freundlich isotherm models were used to represent equilibrium data, and the calculated maximum biosorption capacity of fungal biomass for bismuth(III) was 0.40 mmol.g-1. (authors)

  12. Bismuth nanoparticles synthesized by laser ablation in lubricant oils for tribological tests

    Energy Technology Data Exchange (ETDEWEB)

    Flores-Castañeda, M., E-mail: mar.floc@hotmail.com [Universidad Autónoma del Estado de México, Av. Instituto Literario No. 100, Oriente Col. Centro, Toluca, Estado de México C.P. 50000, México (Mexico); Instituto Nacional de Investigaciones Nucleares, Carretera México-Toluca s/n, La Marquesa, Ocoyoacac, Edo. de México C.P. 52750, México (Mexico); Camps, E. [Instituto Nacional de Investigaciones Nucleares, Carretera México-Toluca s/n, La Marquesa, Ocoyoacac, Edo. de México C.P. 52750, México (Mexico); Camacho-López, M. [Universidad Autónoma del Estado de México, Av. Instituto Literario No. 100, Oriente Col. Centro, Toluca, Estado de México C.P. 50000, México (Mexico); Muhl, S. [Instituto de Investigación en Materiales (UNAM), Circuito Exterior, Ciudad Universitaria, Coyoacán, 04510 México, D.F., México (Mexico); and others

    2015-09-15

    Highlights: • Bismuth nanoparticles have been obtained by laser ablation of solids in liquids. • The technique allows controlling the size and concentration of the samples. • Bi np’s in base oils can improve the tribological characteristics of the lubricant. - Abstract: The improvement of the tribological properties of mineral base oils through the addition of bismuth nanoparticles as an additive, together with the idea of obtaining lubricants free of heavy metals, was evaluated. Bismuth nanoparticles were produced directly in the heavy and light viscosity mineral base oils (BS900 and BS6500) using the technique of laser ablation of solids immersed in liquids. Transmission electron microscopy measurements showed the presence of pure bismuth nanoparticles. Small Angle X-ray Scattering (SAXS) measurements showed that the average size of the nanoparticles was between 7 and 65 nm depending on the experimental conditions used. The tribological properties of the base oil with the bismuth nanoparticles additives were evaluated using a four-ball tester. Tests were performed using the base oil with and without Bi nanoparticles. It was observed that the coefficient of friction of the oil decrease with an increasing concentration of the nanoparticles. The results also showed that the wear rate was reduced when the Bi nanoparticle additives were used.

  13. Role of bismuth in improving Helicobacter pylori eradication with triple therapy.

    Science.gov (United States)

    Dore, Maria Pina; Lu, Hong; Graham, David Y

    2016-05-01

    In most regions of the world, antimicrobial resistance has increased to the point where empirical standard triple therapy forHelicobacter pylorieradication is no longer recommended. The treatment outcome in a population is calculated as the sum of the treatment success in the subpopulation with susceptible infections plus treatment success in the subpopulation with resistant infections. The addition of bismuth (ie, 14-day triple therapy plus bismuth) can improve cure rates despite a high prevalence of antimicrobial resistance. The major bismuth effect is to add an additional 30%-40% to the success with resistant infections. The overall result is therefore dependent on the prevalence of resistance and the treatment success in the subpopulation with resistant infections (eg, with proton-pump inhibitor-amoxicillin dual therapy). Here, we explore the contribution of each component and the mechanisms of how bismuth might enhance the effectiveness of triple therapy. We also discuss the limitations of this approach and provide suggestions how triple therapy plus bismuth might be further improved. PMID:26848181

  14. Magnetoelectric Effect in Ceramics Based on Bismuth Ferrite

    Science.gov (United States)

    Jartych, Elżbieta; Pikula, Tomasz; Kowal, Karol; Dzik, Jolanta; Guzdek, Piotr; Czekaj, Dionizy

    2016-04-01

    Solid-state sintering method was used to prepare ceramic materials based on bismuth ferrite, i.e., (BiFeO3)1 - x -(BaTiO3) x and Bi1 - x Nd x FeO3 solid solutions and the Aurivillius Bi5Ti3FeO15 compound. The structure of the materials was examined using X-ray diffraction, and the Rietveld method was applied to phase analysis and structure refinement. Magnetoelectric coupling was registered in all the materials using dynamic lock-in technique. The highest value of magnetoelectric coupling coefficient α ME was obtained for the Bi5Ti3FeO15 compound ( α ME ~ 10 mVcm-1 Oe-1). In the case of (BiFeO3)1 - x -(BaTiO3) x and Bi1 - x Nd x FeO3 solid solutions, the maximum α ME is of the order of 1 and 2.7 mVcm-1 Oe-1, respectively. The magnitude of magnetoelectric coupling is accompanied with structural transformation in the studied solid solutions. The relatively high magnetoelectric effect in the Aurivillius Bi5Ti3FeO15 compound is surprising, especially since the material is paramagnetic at room temperature. When the materials were subjected to a preliminary electrical poling, the magnitude of the magnetoelectric coupling increased 2-3 times.

  15. Ferroelectric and photocatalytic behavior of bismuth ferrite nano wire

    Science.gov (United States)

    William, R. V.; Marikani, A.; Madhavan, D.

    2016-05-01

    Multiferroic bismuth ferrite nanowires are prepared through polyol method with an average diameter of 35 nm with a narrow size distribution. The band gap was determined to be 2.10 eV, indicating their potential application as visible-light-response photo catalyst. The magnificent photocatalytic behaviors of BiFeO3 nanowires are understood from the methyl violet degradation under visible light irradiation. Moreover, the nano-wire takes only a lesser time for the diffusion of electron-hole pair from the surface of the sample. Further the BiFeO3 nano-wire was characterized using XRD, SEM, and U-V. The ferroelectric studies of BiFeO3 nano-wire show a frequency dependent property and maximum coercivity of 2.7 V/cm were achieved with a remanent polarization at 0.5 µC/cm2 at the frequency 4 kHz. The coercivity of BiFeO3 nano wire changes with variation of frequency from 1 kHz to 4 kHz.

  16. Energy levels scheme simulation of divalent cobalt doped bismuth germanate

    International Nuclear Information System (INIS)

    The aim of this paper is to simulate the energy levels scheme for Bismuth Germanate (BGO) doped with divalent cobalt, in order to give a reliable explanation for spectral experimental data. In the semiempirical crystal field theory we first modeled the Crystal Field Parameters (CFPs) of BGO:Cr2+ system, in the frame of Exchange Charge Model (ECM), with actually site symmetry of the impurity ions after doping. The values of CFPs depend on the geometry of doped host matrix and by parameter G of ECM. First, we optimized the geometry of undoped BGO host matrix and afterwards, that of doped BGO with divalent cobalt. The charges effect of ligands and covalence bonding between cobalt cations and oxygen anions, in the cluster approach, also were taken into account. With the obtained values of the CFPs we simulate the energy levels scheme of cobalt ions, by diagonalizing the matrix of the doped crystal Hamiltonian. Obviously, energy levels and estimated Racah parameters B and C were compared with the experimental spectroscopic data and discussed. Comparison of obtained results with experimental data shows quite satisfactory, which justify the model and simulation schemes used for the title system

  17. Characterization of electrodeposited bismuth-tellurium nanowires and nanotubes

    International Nuclear Information System (INIS)

    Arrays of nanowires and nanotubes of bismuth-tellurium (Bi-Te) were fabricated by electrodeposition techniques. Scanning electron microscopy was employed to characterize the morphology of the fabricated BiTe nanowires and nanotubes. The fabricated BiTe nanowire and nanotube arrays are shown to be polycrystalline with no preferred orientation. Wavelength dispersive spectroscopy analysis shows that either p-type (Bi rich) or n-type (Te rich) nanowires or nanotubes can be obtained by changing the electrodeposition potentials. The lamellar thickness of the nanowires and nanotube crystallites were determined using the Scherrer equation and found to be ∼17-24 nm. The Seebeck coefficient measurements at room temperature obtained for the nanowires and nanotubes deposited at -400 mV were +11.5 and +17 μV K-1, respectively, whereas those obtained at -65 mV were -48 and -63 μV K-1, respectively. The electrical resistance measurements indicated that the resistance of the nanowires and nanotubes decreased with increasing temperature, suggesting that these nanostructures behave like semiconductors.

  18. Transport phenomena in nanowires based on bismuth alloys

    International Nuclear Information System (INIS)

    Full text: In this work, we study the conductivity and thermopower of quantum wires (QW) based on bismuth alloys. Calculations are carried out for nanowires with degenerate and nondegenerate gas of carriers at various crystalline orientations taking into account the real band structure of Bi. We find the energy eigenvalues of holes and taking into account the nonparabolicity of the band, the energy eigenvalues for electrons. The conductivity and thermopower determined with the use of the Kubo formulae in the case when the basic mechanism of carrier scattering is assumed to be elastic acoustic-phonon scattering and on a roughness surface of QW. Dependences of kinetic coefficients on temperature, nanowire diameter and crystalline orientation are investigated. The conductivity and thermopower of a QW contains the contributions of electrons and holes. Taking into account values of carrier effective masses and other band parameters of Bi, it is possible to conclude that the contribution of holes to the conductivity of nondegenerate carriers of QWs is more less than that of electrons, which is attributed to smaller effective mass of electrons. For a semiconducting Bi QW the conductivity depends exponentially on a temperature and wire diameter. The thermopower of a semiconducting and of a semimetallic Bi QW at low temperatures can be positive and change sign in more higher temperatures. The theoretical results are close to experiment for Bi wires with diameter of 50-100 nm. (author)

  19. Bismuth alloying properties in GaAs nanowires

    International Nuclear Information System (INIS)

    First-principles calculations have been performed to investigate the structural, electronic and optical properties of bismuth alloying in GaAs nanowires. A typical model of Ga31As31 nanowires is introduced for its reasonable band gap. The band gap of GaAs1−xBix shrinks clearly with the increasing Bi concentration and the band edge shifts when spin–orbit coupling (SOC) is considered. The insertion of Bi atom leads to hybridization of Ga/As/Bi p states which contributes a lot around Fermi level. Scissor effect is involved. The optical properties are presented, including dielectric function, optical absorption spectra and reflectivity, which are also varied with the increasing of Bi concentrations. - Graphical abstract: Top view of Bi-doped GaAs nanowires. Ga, As, and Bi atoms are denoted with grey, purple and red balls, respectively. Display Omitted - Highlights: • A typical model of Ga31As31 nanowires is introduced for its reasonable band gap. • The band gap of GaAs1−xBix shrinks clearly with the increasing Bi concentration. • The band edge shifts when spin–orbit coupling (SOC) is considered. • The insertion of Bi atom leads to hybridization of Ga/As/Bi p states

  20. Antibacterial effect of bismuth subsalicylate nanoparticles synthesized by laser ablation

    Energy Technology Data Exchange (ETDEWEB)

    Flores-Castañeda, Mariela [Instituto Nacional de Investigaciones Nucleares (Mexico); Vega-Jiménez, Alejandro L., E-mail: argelia.almaguer@mac.com; Almaguer-Flores, Argelia [Universidad Nacional Autónoma de México, Facultad de Odontología, DEPeI, I (Mexico); Camps, Enrique; Pérez, Mario [Instituto Nacional de Investigaciones Nucleares (Mexico); Silva-Bermudez, Phaedra [Instituto Nacional de Rehabilitación, Unidad de Ingeniería de Tejidos, Terapia Celular y Medicina Regenerativa (Mexico); Berea, Edgardo [FarmaQuimia SA de CV. (Mexico); Rodil, Sandra E. [Universidad Nacional Autónoma de México, Instituto de Investigaciones en Materiales (Mexico)

    2015-11-15

    The antimicrobial properties of bismuth subsalicylate (BSS) nanoparticles against four opportunistic pathogens; E. coli, P. aeruginosa, S. aureus, and S. epidermidis were determined. BSS nanoparticles were synthesized by pulse laser ablation of a solid target in distilled water under different conditions. The nanoparticles were characterized using high-resolution transmission electron microscopy and absorption spectra and small angle X-ray scattering. The analysis shows that the colloids maintained the BSS structure and presented average particle size between 20 and 60 nm, while the concentration ranges from 95 to 195 mg/L. The antibacterial effect was reported as the inhibition ratio of the bacterial growth after 24 h and the cell viability was measured using the XTT assay. The results showed that the inhibition ratio of E. coli and S. epidermidis was dependant on the NPs size and/or concentration, meanwhile P. aeruginosa and S. aureus were more sensitive to the BSS nanoparticles independently of both the size and the concentration. In general, the BSS colloids with average particle size of 20 nm were the most effective, attaining inhibition ratios >80 %, similar or larger than those obtained with the antibiotic used as control. The results suggest that the BSS colloids could be used as effective antibacterial agents with potential applications in the medical area.

  1. Investigation of solution-processed bismuth-niobium-oxide films

    Energy Technology Data Exchange (ETDEWEB)

    Inoue, Satoshi, E-mail: s-inoue@jaist.ac.jp [Green Device Research Center, Japan Advanced Institute of Science and Technology (JAIST), 2-13 Asahidai, Nomi, Ishikawa 923-1211 (Japan); School of Material Science, Japan Advanced Institute of Science and Technology (JAIST), 1-1 Asahidai, Nomi, Ishikawa 923-1292 (Japan); Ariga, Tomoki [Green Device Research Center, Japan Advanced Institute of Science and Technology (JAIST), 2-13 Asahidai, Nomi, Ishikawa 923-1211 (Japan); ERATO Shimoda Nano-Liquid Process Project, Japan Science and Technology Agency (JST), 2-13 Asahidai, Nomi, Ishikawa 923-1211 (Japan); Matsumoto, Shin [School of Material Science, Japan Advanced Institute of Science and Technology (JAIST), 1-1 Asahidai, Nomi, Ishikawa 923-1292 (Japan); Onoue, Masatoshi; Miyasako, Takaaki [ERATO Shimoda Nano-Liquid Process Project, Japan Science and Technology Agency (JST), 2-13 Asahidai, Nomi, Ishikawa 923-1211 (Japan); Tokumitsu, Eisuke; Shimoda, Tatsuya [Green Device Research Center, Japan Advanced Institute of Science and Technology (JAIST), 2-13 Asahidai, Nomi, Ishikawa 923-1211 (Japan); School of Material Science, Japan Advanced Institute of Science and Technology (JAIST), 1-1 Asahidai, Nomi, Ishikawa 923-1292 (Japan); ERATO Shimoda Nano-Liquid Process Project, Japan Science and Technology Agency (JST), 2-13 Asahidai, Nomi, Ishikawa 923-1211 (Japan); Chinone, Norimichi; Cho, Yasuo [Research Institute of Electrical Communication, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai, Miyagi 980-8577 (Japan)

    2014-10-21

    The characteristics of bismuth-niobium-oxide (BNO) films prepared using a solution process were investigated. The BNO film annealed at 550°C involving three phases: an amorphous phase, Bi₃NbO₇ fluorite microcrystals, and Nb-rich cubic pyrochlore microcrystals. The cubic pyrochlore structure, which was the main phase in this film, has not previously been reported in BNO films. The relative dielectric constant of the BNO film was approximately 140, which is much higher than that of a corresponding film prepared using a conventional vacuum sputtering process. Notably, the cubic pyrochlore microcrystals disappeared with increasing annealing temperature and were replaced with triclinic β-BiNbO₄ crystals at 590°C. The relative dielectric constant also decreased with increasing annealing temperature. Therefore, the high relative dielectric constant of the BNO film annealed at 550°C is thought to result from the BNO cubic pyrochlore structure. In addition, the BNO films annealed at 500°C contained approximately 6.5 atm.% carbon, which was lost at approximately 550°C. This result suggests that the carbon in the BNO film played an important role in the formation of the cubic pyrochlore structure.

  2. Optical bleaching of bismuth implanted silica glass: A threshold effect

    International Nuclear Information System (INIS)

    The near surface regions of high purity silica glass discs, Spectrosil A, were modified by implantation with bismuth ions at 160 keV and room temperature. The glasses implanted with a nominal dose of 6 x 1016 Bi/cm2 at ∼5 μA/cm2 were subsequently bleached with a 5.0 eV KrF pulsed excimer laser. The laser had an average pulse duration of ∼20 ns and repetition rate of 10 Hz, It was found that the bleaching was dependent upon the power density of the laser for a constant total integrated energy. Ion backscattering and optical absorption measurements were made before and after laser irradiation. Large changes in optical density and depth distribution of the implanted ions were observed at power densities of ≥45 mJ/cm2-pulse. On the basis of the experimental results, the onset of the threshold for bleaching of silica glass implanted with 6 x 1016 Bi/cm2 at 160 keV and at room temperature is between 30 and 45 mJ/cm2-pulse

  3. Modular Lead-Bismuth Fast Reactors in Nuclear Power

    Directory of Open Access Journals (Sweden)

    Vladimir Petrochenko

    2012-09-01

    Full Text Available On the basis of the unique experience of operating reactors with heavy liquid metal coolant–eutectic lead-bismuth alloy in nuclear submarines, the concept of modular small fast reactors SVBR-100 for civilian nuclear power has been developed and validated. The features of this innovative technology are as follows: a monoblock (integral design of the reactor with fast neutron spectrum, which can operate using different types of fuel in various fuel cycles including MOX fuel in a self-providing mode. The reactor is distinct in that it has a high level of self-protection and passive safety, it is factory manufactured and the assembled reactor can be transported by railway. Multipurpose application of the reactor is presumed, primarily, it can be used for regional power to produce electricity, heat and for water desalination. The Project is being realized within the framework of state-private partnership with joint venture OJSC “AKME-Engineering” established on a parity basis by the State Atomic Energy Corporation “Rosatom” and the Limited Liability Company “EuroSibEnergo”.

  4. A detailed study of 2223 bismuth superconductor system

    International Nuclear Information System (INIS)

    In an attempt to obtain improved Phase conditions, Critical current density and Tc, in Bismuth based 2223 superconducting, eleven batches of samples of Bi/sub 2-x/, (Pb/sub x-y/ Sb/sub y/) Sr/sub 2/ Ca/sub 2/Cu/sub 3/O delta series, where (x,y) =(0.5,0.4), (0.32, 0), (0.4, 0.2), (o.4, 0.1), (0.3, 0.2), (0.3, 0.1), (0.2, 0.1), (0.1, 0.1) and (0.1, 0) were prepared using solid state reaction method. Electrical resistivity measurements on samples showed normal superconductor behavior with a dominating superconducting phase of 110K as well as a quite improved critical current. However two samples of series showed semiconductor behavior up to LN2 temperature. X-ray diffraction analysis have also been made on samples which showed a multiphase. (author)

  5. Synthesis and characterization of bismuth zinc niobate pyrochlore nanopowders

    Directory of Open Access Journals (Sweden)

    Sonia Maria Zanetti

    2007-09-01

    Full Text Available Bismuth zinc niobate pyrochlores Bi1.5ZnNb1.5O7 (alpha-BZN, and Bi2(Zn1/3Nb2/32O 7 (beta-BZN have been synthesized by chemical method based on the polymeric precursors. The pyrochlore phase was investigated by differential scanning calorimetry, infrared spectroscopy, and X ray diffraction. Powder and sintered pellets morphology was examined by scanning electron microscopy. The study of alpha-BZN phase formation reveals that, at 500 °C, the pyrochlore phase was already present while a single-phased nanopowder was obtained after calcination at 700 °C. The crystallization mechanism of the beta-BZN is quite different, occurring through the crystallization of alpha-BZN and BiNbO4 intermediary phases. Both compositions yielded soft agglomerated powders. alpha-BZN pellets, sintered at 800 °C for 2 hours, presented a relative density of 97.3% while those of beta-BZN, sintered at 900 °C for 2 hours, reached only 91.8%. Dielectric constant and dielectric loss, measured at 1 MHz, were 150 and 4 x/10-4 for a-BZN, and 97 and 8 x 10-4 for beta-BZN.

  6. Energy levels scheme simulation of divalent cobalt doped bismuth germanate

    Energy Technology Data Exchange (ETDEWEB)

    Andreici, Emiliana-Laura, E-mail: andreicilaura@yahoo.com [Department of Physics, West University of Timisoara, Bd. V. Parvan 4,300223 Timisoara (Romania); Petkova, Petya [Shumen University “Konstantin Preslavsky”, 115 Universitetska street, 9712 Shumen (Bulgaria); Avram, Nicolae M. [Department of Physics, West University of Timisoara, Bd. V. Parvan 4,300223 Timisoara (Romania); Academy of Romanian Scientists, Independentei 54, 050094-Bucharest (Romania)

    2015-12-07

    The aim of this paper is to simulate the energy levels scheme for Bismuth Germanate (BGO) doped with divalent cobalt, in order to give a reliable explanation for spectral experimental data. In the semiempirical crystal field theory we first modeled the Crystal Field Parameters (CFPs) of BGO:Cr{sup 2+} system, in the frame of Exchange Charge Model (ECM), with actually site symmetry of the impurity ions after doping. The values of CFPs depend on the geometry of doped host matrix and by parameter G of ECM. First, we optimized the geometry of undoped BGO host matrix and afterwards, that of doped BGO with divalent cobalt. The charges effect of ligands and covalence bonding between cobalt cations and oxygen anions, in the cluster approach, also were taken into account. With the obtained values of the CFPs we simulate the energy levels scheme of cobalt ions, by diagonalizing the matrix of the doped crystal Hamiltonian. Obviously, energy levels and estimated Racah parameters B and C were compared with the experimental spectroscopic data and discussed. Comparison of obtained results with experimental data shows quite satisfactory, which justify the model and simulation schemes used for the title system.

  7. Synthesis and characterization of bismuth doped barium sulphide nanoparticles

    International Nuclear Information System (INIS)

    We have synthesized BaS:Bi nanocrystalline powder of average grain size 35 nm by solid-state diffusion method using sodium thiosulphate as a flux. During this work we have optimized the nature and amount of flux, amount of the dopant and temperature of firing for maximum yield of photoluminescence. The samples were characterized by X-ray powder diffraction (XRD) method, transmission electron microscopy (TEM), photoluminescence (PL) and UV-visible techniques. On excitation by 425 nm, these nanophosphors give one emission peak at 575 nm which corresponds to green color. In the excitation spectra of these particles there are two peaks at 350 nm and 425 nm. The effect of dopant concentration on the photoluminescence of BaS:Bi nanocrystallites has been studied which is in agreement with the principle of concentration quenching. The energy band gap of bismuth doped BaS nanopowder has been calculated to be 4.25 eV and is blue shifted in comparison to their bulk counterparts. The blue shift may be due to the quantum confinement in the particles.

  8. Optical bleaching of bismuth implanted silica glass: A threshold effect

    International Nuclear Information System (INIS)

    The near surface regions of high purity silica glass discs, Spectrosil A, were modified by implantation with bismuth ions at 160 key and room temperature. The glasses implanted with a nominal dose of 6x1016 Bi/cm2 at ∼5 μA/cm2 were subsequently bleached with a 5.0 eV KrF pulsed excimer laser. The laser had an average pulse duration of ∼20 ns and repetition rate of 10 Hz. It was found that the bleaching was dependent upon the power density of the laser for a constant total integrated energy. Ion backscattering and optical absorption measurements were made before and after laser irradiation. Large changes in optical density and depth distribution of the implanted ions were observed at power densities of ≥45 mJ/cm2-pulse. Onset of threshold for bleaching of silica glass implanted with 6x1016 Bi/cm2 at 160 key and at room temperature is between 30 and 45 mJ/cm2-pulse

  9. Bismuth nanoparticles integration into heavy metal electrochemical stripping sensor.

    Science.gov (United States)

    Cadevall, Miquel; Ros, Josep; Merkoçi, Arben

    2015-08-01

    Between their many applications bismuth nanoparticles (BiNPs) are showing interest as pre-concentrators in heavy metals detection while being applied as working electrode modifiers used in electrochemical stripping analysis. From the different reported methods to synthesize BiNPs we are focused on the typical polyol method, largely used in these types of metallic and semi-metallic nanoparticles. This study presents the strategy for an easy control of the shape and size of BiNPs including nanocubes, nanosferes and triangular nanostructures. To improve the BiNP size and shape, different reducing agents (ethylene glycol or sodium hypophosphite) and stabilizers (polyvinyl pyrrolidone, PVP, in different amounts) have been studied. The efficiency of BiNPs for heavy metals analysis in terms of detection sensitivity while being used as modifiers of screen-printed carbon electrodes including the applicability of the developed device in real sea water samples is shown. A parallel study between the obtained nanoparticles and their performance in heavy metal sensing has been described in this communication. PMID:25994368

  10. Investigation of solution-processed bismuth-niobium-oxide films

    International Nuclear Information System (INIS)

    The characteristics of bismuth-niobium-oxide (BNO) films prepared using a solution process were investigated. The BNO film annealed at 550 °C involving three phases: an amorphous phase, Bi3NbO7 fluorite microcrystals, and Nb-rich cubic pyrochlore microcrystals. The cubic pyrochlore structure, which was the main phase in this film, has not previously been reported in BNO films. The relative dielectric constant of the BNO film was approximately 140, which is much higher than that of a corresponding film prepared using a conventional vacuum sputtering process. Notably, the cubic pyrochlore microcrystals disappeared with increasing annealing temperature and were replaced with triclinic β-BiNbO4 crystals at 590 °C. The relative dielectric constant also decreased with increasing annealing temperature. Therefore, the high relative dielectric constant of the BNO film annealed at 550 °C is thought to result from the BNO cubic pyrochlore structure. In addition, the BNO films annealed at 500 °C contained approximately 6.5 atm. % carbon, which was lost at approximately 550 °C. This result suggests that the carbon in the BNO film played an important role in the formation of the cubic pyrochlore structure.

  11. CLASH-VLT: Environment-driven evolution of galaxies in the z=0.209 cluster Abell 209

    CERN Document Server

    Annunziatella, M; Biviano, A; Girardi, M; Nonino, M; Balestra, I; Rosati, P; Caminha, G Bartosch; Brescia, M; Gobat, R; Grillo, C; Lombardi, M; Sartoris, B; De Lucia, G; Demarco, R; Frye, B; Fritz, A; Moustakas, J; Scodeggio, M; Kuchner, U; Maier, C; Ziegler, B

    2016-01-01

    The analysis of galaxy properties and the relations among them and the environment, can be used to investigate the physical processes driving galaxy evolution. We study the cluster A209 by using the CLASH-VLT spectroscopic data combined with Subaru photometry, yielding to 1916 cluster members down to a stellar mass of 10^{8.6} Msun. We determine: i) the stellar mass function of star-forming and passive galaxies; ii) the intra-cluster light and its properties; iii) the orbits of low- and high-mass passive galaxies; and iv) the mass-size relation of ETGs. The stellar mass function of the star-forming galaxies does not depend on the environment, while the slope found for passive galaxies becomes flatter in the densest region. The color distribution of the intra-cluster light is consistent with the color of passive members. The analysis of the dynamical orbits shows that low-mass passive galaxies have tangential orbits, avoiding small pericenters around the BCG. The mass-size relation of low-mass passive ETGs is ...

  12. Bessel Beams

    OpenAIRE

    McDonald, Kirk T

    2000-01-01

    Scalar Bessel beams are derived both via the wave equation and via diffraction theory. While such beams have a group velocity that exceeds the speed of light, this is a manifestation of the "scissors paradox" of special relativty. The signal velocity of a modulated Bessel beam is less than the speed of light. Forms of Bessel beams that satisfy Maxwell's equations are also given.

  13. Study of the di-nuclear system $^{A}$Rb + $^{209}$Bi (Z$_{1}$ + Z$_{2}$ = 120)

    CERN Multimedia

    The exact location of the next spherical shell closures beyond Z = 82, N = 126 is still an open question. According to model predictions shell closures are expected at Z = 114 or 120 or 126 and N = 184. Also experimental data cannot yet give a definite answer. Known nuclei with Z = 114 are too neutron‐deficient with respect to the N = 184 shell and nuclei with Z = 120 and beyond are still unknown. An option for studying reactions of super-heavy systems at Z = 120 and neutron numbers up to 184 becomes possible with the use of $^{209}$Bi targets and neutron‐rich beams. By studying quasi-fission and fusion‐fission reactions, which have significantly larger production cross‐sections than the evaporation residues, a possible influence of shell closures at Z = 120, N = 184 can be explored. Well suitable for such studies will be neutron‐rich rubidium beams at energies of about 5 MeV/u delivered by the HIE‐ISOLDE facility.

  14. Chapter 10. On average contents of bismuth, indium and thallium in secondary sediments of depression of Tajikistan

    International Nuclear Information System (INIS)

    In this part of book author made conclusion that background contents of bismuth, indium and thallium in secondary sediments of depression of Tajikistan depend from petrographic composition of layers of drainage area, facial-climatic conditions and lithologic layer type; accumulation of investigated elements pass at coastal phases; clayey sediments more enriched by bismuth, indium and thallium than sandstones

  15. Behavior of decabromodiphenyl ether (BDE-209) in soil: Effects of rhizosphere and mycorrhizal colonization of ryegrass roots

    International Nuclear Information System (INIS)

    A rhizobox experiment was conducted to investigate degradation of decabromodiphenyl ether (BDE-209) in the rhizosphere of ryegrass and the influence of root colonization with an arbuscular mycorrhizal (AM) fungus. BDE-209 dissipation in soil varied with its proximity to the roots and was enhanced by AM inoculation. A negative correlation (P 2 = 0.66) was found between the residual BDE-209 concentration in soil and soil microbial biomass estimated as the total phospholipid fatty acids, suggesting a contribution of microbial degradation to BDE-209 dissipation. Twelve and twenty-four lower brominated PBDEs were detected in soil and plant samples, respectively, with a higher proportion of di- through hepta-BDE congeners in the plant tissues than in the soils, indicating the occurrence of BDE-209 debromination in the soil-plant system. AM inoculation increased the levels of lower brominated PBDEs in ryegrass. These results provide important information about the behavior of BDE-209 in the soil-plant system. - Research highlights: → BDE-209 dissipation in soil was affected by the proximity to the roots. → Microbial degradation contributes greatly to BDE-209 dissipation in the soil. → Twelve and twenty-four lower brominated PBDEs were detected in soil and plant samples. → AM inoculation increased root uptake and accumulation of BDE-209. - BDE-209 dissipation and degradation in soil were affected by both its proximity to ryegrass roots and inoculation with an AM fungus.

  16. Behavior of decabromodiphenyl ether (BDE-209) in soil: Effects of rhizosphere and mycorrhizal colonization of ryegrass roots

    Energy Technology Data Exchange (ETDEWEB)

    Wang Sen [State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, P.O. Box 2871, Beijing 100085 (China); Zhang Shuzhen, E-mail: szzhang@rcees.ac.cn [State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, P.O. Box 2871, Beijing 100085 (China); Huang, Honglin [State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, P.O. Box 2871, Beijing 100085 (China); Christie, Peter [Agri-Environment Branch, Agri-Food and Biosciences Institute, Newforge Lane, Belfast BT9 5PX (United Kingdom)

    2011-03-15

    A rhizobox experiment was conducted to investigate degradation of decabromodiphenyl ether (BDE-209) in the rhizosphere of ryegrass and the influence of root colonization with an arbuscular mycorrhizal (AM) fungus. BDE-209 dissipation in soil varied with its proximity to the roots and was enhanced by AM inoculation. A negative correlation (P < 0.001, R{sup 2} = 0.66) was found between the residual BDE-209 concentration in soil and soil microbial biomass estimated as the total phospholipid fatty acids, suggesting a contribution of microbial degradation to BDE-209 dissipation. Twelve and twenty-four lower brominated PBDEs were detected in soil and plant samples, respectively, with a higher proportion of di- through hepta-BDE congeners in the plant tissues than in the soils, indicating the occurrence of BDE-209 debromination in the soil-plant system. AM inoculation increased the levels of lower brominated PBDEs in ryegrass. These results provide important information about the behavior of BDE-209 in the soil-plant system. - Research highlights: > BDE-209 dissipation in soil was affected by the proximity to the roots. > Microbial degradation contributes greatly to BDE-209 dissipation in the soil. > Twelve and twenty-four lower brominated PBDEs were detected in soil and plant samples. > AM inoculation increased root uptake and accumulation of BDE-209. - BDE-209 dissipation and degradation in soil were affected by both its proximity to ryegrass roots and inoculation with an AM fungus.

  17. Overview of the use of ATHENA for thermal-hydraulic analysis of systems with lead-bismuth coolant

    International Nuclear Information System (INIS)

    The INEEL and MIT are investigating the suitability of lead-bismuth cooled fast reactor for producing low-cost electricity as well as for actinide burning. This paper is concerned with the general area of thermal-hydraulics of lead-bismuth cooled reactors. The ATHENA code is being used in the thermal-hydraulic design and analysis of lead-bismuth cooled reactors. The ATHENA code was reviewed to determine its applicability for simulating lead-bismuth cooled reactors. Two modifications were made to the code as a result of this review. Specifically, a correlation to represent heat transfer from rod bundles to a liquid metal and a void correlation based on data taken in a mixture of lead-bismuth and steam were added the code. The paper also summarizes the analytical work that is being performed with the code and plans for future analytical work

  18. Assessment of the Eye Lens Dose Reduction by Bismuth Shields in Rando Phantom Undergoing CT of the Head

    International Nuclear Information System (INIS)

    The aim of this study is to assess the dose reduction of eye lens and availability of bismuth garments resulting from the use of radioprotective bismuth garments to shield the eyes of patients undergoing head CT. Rando phantom and TLDs were used to determine the amount of dose reduction by bismuth shielding of the eye in the following simulated CT scans : (a) scanning of the head including orbits, (b) scanning of the whole head, and (c) angled scanning of the head excluding orbits. The average dose reduction of eye lens was 43.2%, 36.0% and 1.4% for the three CT scans listed above. Significant reduction in the eye lens dose was achieved by using superficial orbital bismuth shielding during head CT scans. However, bismuth shields should not be used for the patients when their eyes are excluded from the primarily exposed region.

  19. Melting behaviour of lead and bismuth nano-particles in quasicrystalline matrix - The role of interfaces

    Indian Academy of Sciences (India)

    Alok Singh; A P Tsai

    2003-02-01

    Nanomaterials are playing an increasingly important role in modern technologies. Interfaces are crucial in nanotechnology. In this study, we have examined the stability of nanoparticles. Major emphasis is on understanding the effect of interfaces on melting. Melting behaviour of nanocrystalline interfaces, created by embedding lead and bismuth nanoparticles in quasicrystalline matrices, was studied. Sharply faceted and coherent interfaces can be related to sharper melting transitions, while irregularly shaped and incoherent interfaces can be directly correlated with lowering of melting temperatures. It is shown here that solid lead forms a high energy interface with phason strain-free quasicrystal (resulting in a lowering of the melting temperature) while bismuth forms a low energy interface with the quasicrystal (resulting in superheating, unusual for bismuth).

  20. Bismuth subcarbonate as filler particle for an Epoxy-based root canal sealer

    Directory of Open Access Journals (Sweden)

    Eduardo Schwartzer

    2013-01-01

    Full Text Available Introduction: The aim of this study was to evaluate the addition of bismuth subcarbonate with different concentrations regarding the rheological properties of an experimental epoxy-based root canal sealer. Materials and Methods: Endodontic sealers were prepared with epoxy resin-based sealer with bismuth subcarbonate additions of 20%, 40%, 60%, 80%, 100%, and 120%. Flow, film thickness, working time, setting time, dimensional change, sorption, solubility, and cytotoxicity were studied according to the ISO standards. Data were statistically analyzed by one-way ANOVA, and Tukey multiple comparisons were used, with a significance level of 5%. Results: The flow, working time, water sorption, and solubility significantly decreased and the film thickness and dimensional change increased with higher filler particle addition. There were no statistically significant differences for setting time and cytotoxicity between the filler particle proportions. Conclusion: Experimental resin-based sealer with bismuth subcarbonate addition up to 40% can be an alternative for root canal sealer.

  1. Fluorescence Emission Centres and the Corresponding Infrared Fluorescence Saturation in a Bismuth-Doped Silica Fibre

    Institute of Scientific and Technical Information of China (English)

    QIU Yan-Qing; SHEN Yong-Hang

    2008-01-01

    We investigate the fluorescence characteristics of bismuth doped silica fibres with and without Al co-dopant which are fabricated by means of modified chemical vapour deposition (MCVD) technique, and find that the fluorescences in the red region (centred around 750nm) and in the infrared region (centred around 1100nm) may originate from different emission sites in the fibre. Strong upconversion phenomena are observed in both Al-codoped and non Al codoped bismuth fibres when the fibres are excited by an acoustic-optic Q-switched Nd: YVO4 laser. Both the aspects indicate that the upper energy level absorption reported in the work of the bismuth doped silica fibre lasers may result from the fluorescence emission sites that are not responsible for the infrared emission. It is thus expected that optimizing the compositions and the fabrication conditions of the fibre and then transferring more fluorescence emission centres are helpful for the infrared emission.

  2. Sintering characteristics of La/Nd doped Bi4Ti3O12 bismuth titanate ceramics

    Directory of Open Access Journals (Sweden)

    Islam Aminul Md.

    2015-01-01

    Full Text Available A good understanding about the properties of La/Nd doped Bismuth Titanate (BIT ceramics at high temperature is very important as the new materials being developed based on the BIT. Pure BIT, La doped (BLT, Nd doped (BNT and La and Nd co-doped BIT (BLNT powders were synthesized by solid state reaction method. Prepared powders were calcined at different temperatures and structural properties measured by XRD. For pure BIT better crystal quality was obtained at 750 0C and for both BLT and BNT better result obtained at 800 0C. Calcined powders were formed into pellets and sintered at different temperatures and its dielectric properties were characterized. Optimum sintering temperature for both BLT and BNT showed was 850 0C and La and Nd co-doped bismuth titanate (BLNT revealed optimum sintering temperature of 950 0C. Therefore, optimum sintering temperature of bismuth titanate was increased due to La and Nd doping.

  3. Bismuth- and lithium-loaded plastic scintillators for gamma and neutron detection

    International Nuclear Information System (INIS)

    Transparent plastic scintillators based on polyvinyltoluene (PVT) have been fabricated with high loading of bismuth carboxylates for gamma spectroscopy, and with lithium carboxylates for neutron detection. When activated with a combination of standard fluors, 2,5-diphenyloxazole (PPO) and tetraphenylbutadiene (TPB), gamma light yields with 15 wt% bismuth tripivalate of 5000 Ph/MeV are measured. A PVT plastic formulation including 30 wt% lithium pivalate and 30 wt% PPO offers both pulse shape discrimination, and a neutron capture peak at ~400 keVee. In another configuration, a bismuth-loaded PVT plastic is coated with ZnS(6Li) paint, permitting simultaneous gamma and neutron detection via pulse shape discrimination with a figure-of-merit of 3.8, while offering gamma spectroscopy with energy resolution of R(662 keV)=15%

  4. Bismuth- and lithium-loaded plastic scintillators for gamma and neutron detection

    Energy Technology Data Exchange (ETDEWEB)

    Cherepy, Nerine J., E-mail: cherepy1@llnl.gov [Lawrence Livermore National Laboratory, Livermore, CA (United States); Sanner, Robert D.; Beck, Patrick R.; Swanberg, Erik L.; Tillotson, Thomas M.; Payne, Stephen A. [Lawrence Livermore National Laboratory, Livermore, CA (United States); Hurlbut, Charles R. [Eljen Technology, Sweetwater, TX (United States)

    2015-04-01

    Transparent plastic scintillators based on polyvinyltoluene (PVT) have been fabricated with high loading of bismuth carboxylates for gamma spectroscopy, and with lithium carboxylates for neutron detection. When activated with a combination of standard fluors, 2,5-diphenyloxazole (PPO) and tetraphenylbutadiene (TPB), gamma light yields with 15 wt% bismuth tripivalate of 5000 Ph/MeV are measured. A PVT plastic formulation including 30 wt% lithium pivalate and 30 wt% PPO offers both pulse shape discrimination, and a neutron capture peak at ~400 keVee. In another configuration, a bismuth-loaded PVT plastic is coated with ZnS({sup 6}Li) paint, permitting simultaneous gamma and neutron detection via pulse shape discrimination with a figure-of-merit of 3.8, while offering gamma spectroscopy with energy resolution of R(662 keV)=15%.

  5. Design of an Actinide Burning, Lead-Bismuth Cooled Reactor That Produces Low Cost Electricity

    Energy Technology Data Exchange (ETDEWEB)

    C. Davis; S. Herring; P. MacDonald; K. McCarthy; V. Shah; K. Weaver (INEEL); J. Buongiorno; R. Ballinger; K. Doyoung; M. Driscoll; P. Hejzler; M. Kazimi; N. Todreas (MIT)

    1999-07-01

    The purpose of this project is to investigate the suitability of lead-bismuth cooled fast reactors for producing low-cost electricity as well as for actinide burning. The goal is to identify and analyze the key technical issues in core neutronics, materials, thermal-hydraulics, fuels, and economics associated with the development of this reactor concept. The choice of lead-bismuth for the reactor coolant is an actinide burning fast reactor offers enhanced safety and reliability. The advantages of lead-bismuth over sodium as a coolant are related to the following material characteristics: chemical inertness with air and water; higher atomic number; lower vapor pressure at operating temperatures; and higher boiling temperature. Given the status of the field, it was agreed that the focus of this investigation in the first two years will be on the assessment of approaches to optimize core and plant arrangements in order to provide maximum safety and economic potential in this type of reactor.

  6. Poisoning effect of bismuth on modification behaviour of strontium in LM25 alloy

    Indian Academy of Sciences (India)

    S Farahany; A Ourdjini; M H Idris; L T Thai

    2011-10-01

    Nucleation and growth, temperature measurements andmicrostructure observations of silicon phase are presented for strontium modified Al–7%Si (LM25) cast alloy treated with bismuth. The results show that addition of bismuth in strontium modified alloys may have a poisoning effect resulting in lost modification of the silicon phase. With increasing Bi/Sr ratio, thermal analysis measurements showed that the eutectic growth temperature increased remarkably to 573°C and recalescence decreased to 0.2°C and the morphology of silicon displayed the same flakelike structure as in the unmodified alloys. Microstructural observation showed that a minimum Bi/Sr ratio of 1.2 which is equivalent to a Sr/Bi ratio of 0.43 is required for effective strontium modification and neutralization of the poisoning effect of bismuth.

  7. Preparation of bismuth-based nanosheets by ultrasound-assisted liquid laser ablation

    Science.gov (United States)

    Escobar-Alarcón, L.; Velarde Granados, E.; Solís-Casados, D. A.; Olea-Mejía, O.; Espinosa-Pesqueira, M.; Haro-Poniatowski, E.

    2016-04-01

    The preparation of bismuth nanosheets ablating a high purity Bi target immersed in water subjected to an ultrasound wave is reported. The effect of the laser fluence used for ablation on the size and shape of the nanostructures synthesized was investigated. The obtained results reveal the formation of nanosheets with square-like shape and sizes from approximately 140-543 nm. In comparison, experiments without the ultrasound field lead to the formation of quasi-spherical nanoparticles. The nanosheets were characterized by means of transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDS), UV-Vis and Raman spectroscopies. The bismuth nanosheets, as deposited, are highly crystalline, and depending on the preparation conditions, the α or β phases of Bi2O3 are obtained. UV-Vis measurements show the typical band absorption characteristic of bismuth with nanometric size. Raman spectra confirm the formation of Bi2O3 nanostructures.

  8. Application of Thermodynamic Calculations to the Pyro-refining Process for Production of High Purity Bismuth

    Science.gov (United States)

    Mezbahul-Islam, Mohammad; Belanger, Frederic; Chartrand, Patrice; Jung, In-Ho; Coursol, Pascal

    2016-04-01

    The present work has been performed with the aim to optimize the existing process for the production of high purity bismuth (99.999 pct). A thermo-chemical database including most of the probable impurities of bismuth (Bi-X, X = Ag, Au, Al, Ca, Cu, Fe, Mg, Mn, Na, Ni, Pb, S, Sb, Sn, Si, Te, Zn) has been constructed to perform different thermodynamic calculations required for the refining process. Thermodynamic description for eight of the selected binaries, Bi-Ca, Cu, Mn, Ni, Pb, S, Sb, and Sn, has been given in the current paper. Using the current database, different thermodynamic calculations have been performed to explain the steps involved in the bismuth refining process.

  9. Radioactive Iodine (I-129) Gas Adsorption by Using Bismuth-Embedded SBA-15

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Jae Hwan; Cho, Yong-Jun; Park, Jang Jin; Ahn, Do-Hee [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of); Yim, Man-Sung [Korea Advanced Institute of Science and Technology, Daejeon (Korea, Republic of)

    2015-05-15

    The efficient capture of the long-lived I-129, released as off-gas from nuclear fuel reprocessing, have been of significant concern in the waste management field. In this study, bismuth-embedded SBA-15 mesoporous silica was firstly applied for iodine capture and storage. SBA-15 was functionalized with thiol (-SH) groups, followed by bismuth adsorption with Bi-S bonding, which was thermally treated to form Bi{sub 2}S{sub 3} within SBA-15. The bismuth-embedded SBA-15s demonstrated high iodine loading capacities with 540 mg-I/g-sorbent maximally, which benefitted from the high surface area and porosity of SBA-15 as well as the formation of thermodynamically stable BiI{sub 3} compound. Iodine physisorption could effectively be suppressed due to the large pores present in SBA-15, resulting in chemisorption as a main mechanism for iodine confinement.

  10. Influence of bismuth on the charging ability of negative plates in lead-acid batteries

    Science.gov (United States)

    Lam, L. T.; Ceylan, H.; Haigh, N. P.; Manders, J. E.

    To examine the influence of bismuth on the charging ability of negative plates in lead-acid batteries, plates are made from three types of oxides: (i) leady oxide of high quality which contains virtually no bismuth (termed 'control oxide'); (ii) control oxide in which bismuth oxide is blended at bismuth levels from 0.01 to 0.12 wt.%; (iii) leady oxide produced from Pasminco VRLA Refined™ lead (0.05-0.06 wt.%Bi). An experimental tool—the 'conversion indicator'—is developed to assess the charging ability of the test negative plates when cycling under either zero percent state-of-charge (SoC)/full-charge or partial state-of-charge (PSoC) duty. Although the conversion indicator is not the true charging efficiency, the two parameters have a close relationship, namely, the higher the conversion indicator, the greater the charging efficiency. Little difference is found in the charging ability, irrespective of bismuth content and discharge rate, when the plates are subjected to zero percent SoC/full-charge duty; the conversion indicator lies in the range 81-84%. By contrast, there is a marked difference when the negative plates are subjected to PSoC duty, i.e. consecutive cycling through 90-60, 70-40, 80-40 and 90-40% SoC windows. Up to 0.06 wt.%Bi improves the charging ability, especially with a low and narrow PSoC window (40-70% SoC) of the type that will be experienced in 42 V powernet automobile and hybrid electric duties. To maximize this beneficial effect, bismuth must be distributed uniformly in the plates. This is best achieved by using VRLA Refined™ lead for oxide production.

  11. Syntheses, crystal structures and characterizations of two new bismuth(III) arsenites

    International Nuclear Information System (INIS)

    Two new bismuth arsenites with two different structural types, namely, Bi2O(AsO3)Cl (1), Bi8O6(AsO3)2(AsO4)2 (2), have been synthesized by the solid-state reactions. Compound 1 exhibits novel 2D bismuth arsenite layers with Bi4O4 rings capped by oxide anions, which are further interconnected by Bi–Cl–Bi bridges into a 3D network. Compound 2 contains both arsenite and arsenate anions, its 3D structures are based on 1D bismuth arsenite and 1D bismuth arsenate chains both along b-axis, which are interconnected by oxide anions via Bi–O–Bi bridges, forming 1D tunnels of Bi4As4 8-membered rings (MRs) along b-axis, the lone pairs of the arsenite groups are orientated toward the centers of the above tunnels. Thermogravimetric analysis indicated that both compounds display high thermal stability. Optical property measurements revealed that they are wide band-gap semiconductors. Both compounds display broad green-light emission bands centered at 506 nm under excitation at 380 and 388 nm. - Graphical abstract: Solid state reactions of Bi2O3 (BiCl3) and As2O3 yielded two new compounds with two different structural types, namely, Bi2O(AsO3)Cl (1), Bi8O6(AsO3)2(AsO4)2 (2). They represent the first examples of bismuth arsenates. Highlights: ► Solid state reactions of Bi2O3 (BiCl3) and As2O3 yielded two new phases. ► They represent the first examples of bismuth arsenites. ► The two compounds exhibit two different structural types.

  12. The effect of bismuth subcitrate in patients with diarrhea predominant irritable bowel syndrome

    Directory of Open Access Journals (Sweden)

    Kalani M

    2010-09-01

    Full Text Available "nBackground: The irritable bowel syndrome (IBS is one of the most common chronic medical conditions. Various mechanisms, including altered gut flora and/or small bowel bacterial overgrowth, have been suggested to play a role in the development of gas-related symptoms aim of study. The clinical evidence of small intestinal bacterial overgrowth as an important etiology of irritable bowel syndrome continues to accumulate. Clinical symptoms of bacterial overgrowth and irritable bowel syndrome are similar; however, a definitive cause-and-effect relationship remains unproven. It is unclear whether motility dysfunction causes bacterial overgrowth or gas products of"nenteric bacteria affect intestinal motility in irritable bowel syndrome."n "nMethods: In a randomized double-blind placebo-controlled trial consisting of treatment with bismuth subcitrate. Primary efficacy variable was subjective symptoms; frequency of abdominal pain, Number of bowel movement & Bloating/distension."n "nResults: 119 patients were enrolled (59 bismuth subcitrate and 60 placebo recipients. At the end of phase 2, all symptom scores dropped significantly both in bismuth subcitrate and placebo group (p<0.001. There was not a significant difference in symptom relief with bismuth subcitrate versus placebo administration."n "nConclusions: There was not a significant difference in symptom relief with bismuth subcitrate versus placebo in IBS patients. Whether antibiotics can improve quality of life in patients with irritable bowel syndrome warrants further research."nInterventions: Participants were randomly assigned to receive 120mg bismuth subcitrate four times daily for 14 days (n=59 or placebo (n=60.

  13. Basic principles of lead and lead-bismuth eutectic application in blanket of fusion reactors

    International Nuclear Information System (INIS)

    High magnetohydrodynamic pressure drop is an important issue for liquid metal blanket concepts. To decrease magnetohydrodynamic resistance authors propose to form insulating coatings on internal surface of blanket ducts at any moment of fusion reactor exploitation. It may be achieved easily if lead or lead-bismuth eutectic is used and technology of oxidative potential handling is applied. A number of experiments carried out in NNSTU show the availability of the proposed technology. It bases on formation of the insulating coatings that consist of the oxides of components of the structural materials and of the coolant components. In-situ value of the insulating coatings characteristics ρδ is ∼ 10-5 Ohm·m2 for steels and 5,0x10-6 - 5,0x10-5 Ohm·m2 for vanadium alloys. Thermal cycling is possible during exploitation of a blanket. The experimental research of the insulating coatings properties during thermal cycling have shown that the coatings formed into the lead and lead-bismuth coolants save there insulating properties. Experience of many years is an undoubted advantage of the lead-bismuth coolant and less of the lead coolant in comparison with lithium. Russian Federation possesses of experience of exploitation of the research and industrial facilities, of experience of creation of the pumps, steamgenerators and equipment with heavy liquid metal coolants. The unique experience of designing, assembling and exploitation of the fission reactors with lead-bismuth coolant is also available. The problem of technology of lead and lead-bismuth coolants for power high temperature radioactive facilities has been solved. Accidents, emergency situations such as leakage of steamgenerators or depressurization of gas system in facilities with lead and lead-bismuth coolants have been explored and suppressed. (author)

  14. Deposition of Visible Light Active Photocatalytic Bismuth Molybdate Thin Films by Reactive Magnetron Sputtering

    OpenAIRE

    Marina Ratova; Kelly, Peter J; Glen T. West; Xiaohong Xia; Yun Gao

    2016-01-01

    Bismuth molybdate thin films were deposited by reactive magnetron co-sputtering from two metallic targets in an argon/oxygen atmosphere, reportedly for the first time. Energy dispersive X-ray spectroscopy (EDX) analysis showed that the ratio of bismuth to molybdenum in the coatings can be effectively controlled by varying the power applied to each target. Deposited coatings were annealed in air at 673 K for 30 min. The crystalline structure was assessed by means of Raman spectroscopy and X-ra...

  15. Equilibrium distribution of lanthanum, neodymium, and thorium between lithium chloride melt and liquid bismuth

    Science.gov (United States)

    Zagnit'ko, A. V.; Ignat'ev, V. V.

    2013-04-01

    The distribution of lanthanum, neodymium, and thorium between a lithium chloride melt and liquid bismuth with additions of lithium as a reducing agent are investigated at 650°C. Equilibrium values of their distribution constants are measured. It is shown that in contrast to neodymium and lanthanum, thorium cannot be extracted from bismuth into lithium chloride. This allows us to propose an efficient scheme for separating lanthanides and thorium in a system for the extraction of fuel salts in molten-salt nuclear reactors.

  16. Basic principles of lead and lead-bismuth eutectic application in blanket of fusion reactors

    International Nuclear Information System (INIS)

    Full text: One of the main requirements of advanced nuclear-power engineering is inherent safety of power installations. It initiates R and D of heavy liquid metals (lead, lead- bismuth eutectic) application in fission reactors as substitute of sodium. The same requirement makes advisable R and D of the lead and lead-bismuth eutectic application in blanket of fusion reactors as substitute of lithium. High magnetohydrodynamic pressure drop is an important issue for liquid metal blanket concepts. To decrease MHD-resistance authors propose to form electro-insulating coatings on internal surface of blanket ducts at any moment of fusion reactor exploitation. It may be achieved easily if lead or lead-bismuth eutectic is used and technology of oxidative potential handling is applied. A number of experiments carried out in NNSTU show the availability of the proposed technology. It bases on formation of the insulating coatings that consist of the oxides of components of the structural materials and of the coolant components. In-situ value of the electro-insulating coatings characteristics rd (r - specific resistance of coatings, d - thickness) is ∼ 10-5Ω·m2 for steels and 5, 0x10-6 - 5, 0x10-5Ω·m2 for vanadium alloys. Thermal cycling is possible during exploitation of a blanket. The experimental research of the insulating coatings properties during thermal cycling have shown that the coatings formed into the lead and lead-bismuth coolants save there electro-insulating properties. Experience of many years is an undoubted advantage of the lead-bismuth coolant and less of the lead coolant in comparison with lithium. Russian Federation possesses of experience of exploitation of the research and industrial facilities, of experience of creation of the pumps, steam generators and another equipment with heavy liquid metal coolants. The unique experience of designing, assembling and exploitation of the fission reactors with lead-bismuth coolant is also available. The problem

  17. Optical properties of thermally reduced bismuth-doped sodium aluminosilicate glasses

    DEFF Research Database (Denmark)

    Nielsen, K.H.; Smedskjær, Morten Mattrup; Yue, Yuanzheng;

    Heat-treatment of multivalent ion containing glasses in a hydrogen atmosphere may cause both reduction of the multivalent ions and ionic inward diffusion, resulting in improved glass properties. Bismuth-doped glasses are also interesting objects not only concerning the reduction induced diffusion......, but also concerning the metal particle formation, and the broadband near infrared luminescence. Both the inward diffusion and the infrared luminescence depend on the bismuth oxidation state. The latter can be varied by adjusting the parameters of the heat-treatment, e.g., time, temperature, and...

  18. Electrical properties of niobium doped barium bismuth-titanate ceramics

    International Nuclear Information System (INIS)

    Highlights: ► Pure and doped BaBi4Ti4O15 were prepared via the solid-state reaction method. ► The grain size was suppressed in Nb-doped samples. ► The diffuseness of the dielectric peak increased with dopant concentration. ► Niobium affected on relaxor behavior of barium bismuth titanate ceramics. ► The conductivity change was noticed in doped samples. -- Abstract: BaBi4Ti4–5/4xNbxO15 (BBNTx, x = 0, 0.05, 0.15, 0.30) ceramics have been prepared by solid state method. XRD data indicate the formation of single-phase-layered perovskites for all compositions. SEM micrographs suggest that the grain size decreases with Nb doping. The effect of niobium doping on the dielectric and relaxor behavior of BaBi4Ti4O15 ceramics was investigated in a wide range of temperatures (20–777 °C) and frequencies (1.21 kHz to 1 MHz). Nb doping influences Tc decrease as well as the decrease of dielectric permittivity at Curie temperature. At room temperature, undoped BaBi4Ti4O15 exhibits dielectric constant of ∼204 at 100 kHz, that slightly increases with Nb doping. The conductivity of BBNT5 ceramics is found to be lower than that of other investigated compositions. The value of activation energy of σDC was found to be 0.89 eV, 1.01 eV, 0.93 eV and 0.71 eV for BBT, BBNT5, BBNT15 and BBNT30, respectively.

  19. Electrical properties of niobium doped barium bismuth-titanate ceramics

    Energy Technology Data Exchange (ETDEWEB)

    Bobić, J.D., E-mail: jelenabobic@yahoo.com [Institute for Multidisciplinary Researches, Belgrade University, Kneza Viseslava 1, Belgrade (Serbia); Vijatović Petrović, M.M. [Institute for Multidisciplinary Researches, Belgrade University, Kneza Viseslava 1, Belgrade (Serbia); Banys, J. [Faculty of Physics, Vilnius University, 9 Sauletekio Str., Vilnius (Lithuania); Stojanović, B.D. [Institute for Multidisciplinary Researches, Belgrade University, Kneza Viseslava 1, Belgrade (Serbia)

    2012-08-15

    Highlights: ► Pure and doped BaBi{sub 4}Ti{sub 4}O{sub 15} were prepared via the solid-state reaction method. ► The grain size was suppressed in Nb-doped samples. ► The diffuseness of the dielectric peak increased with dopant concentration. ► Niobium affected on relaxor behavior of barium bismuth titanate ceramics. ► The conductivity change was noticed in doped samples. -- Abstract: BaBi{sub 4}Ti{sub 4–5/4x}Nb{sub x}O{sub 15} (BBNTx, x = 0, 0.05, 0.15, 0.30) ceramics have been prepared by solid state method. XRD data indicate the formation of single-phase-layered perovskites for all compositions. SEM micrographs suggest that the grain size decreases with Nb doping. The effect of niobium doping on the dielectric and relaxor behavior of BaBi{sub 4}Ti{sub 4}O{sub 15} ceramics was investigated in a wide range of temperatures (20–777 °C) and frequencies (1.21 kHz to 1 MHz). Nb doping influences T{sub c} decrease as well as the decrease of dielectric permittivity at Curie temperature. At room temperature, undoped BaBi{sub 4}Ti{sub 4}O{sub 15} exhibits dielectric constant of ∼204 at 100 kHz, that slightly increases with Nb doping. The conductivity of BBNT5 ceramics is found to be lower than that of other investigated compositions. The value of activation energy of σ{sub DC} was found to be 0.89 eV, 1.01 eV, 0.93 eV and 0.71 eV for BBT, BBNT5, BBNT15 and BBNT30, respectively.

  20. Formic acid oxidation at platinum-bismuth catalysts

    Directory of Open Access Journals (Sweden)

    Popović Ksenija Đ.

    2015-01-01

    Full Text Available The field of heterogeneous catalysis, specifically catalysis on bimetallic surfaces, has seen many advances over the past few decades. Bimetallic catalysts, which often show electronic and chemical properties that are distinct from those of their parent metals, offer the opportunity to obtain new catalysts with enhanced selectivity, activity, and stability. The oxidation of formic acid is of permanent interest as a model reaction for the mechanistic understanding of the electrooxidation of small organic molecules and because of its technical relevance for fuel cell applications. Platinum is one of the most commonly used catalysts for this reaction, despite the fact that it shows a few significant disadvantages: high cost and extreme susceptibility to poisoning by CO. To solve this problem, several approaches have been used, but generally, they all consist in the modification of platinum with a second element. Especially, bismuth has received significant attention as Pt modifier. According to the results presented in this survey dealing with the effects influencing the formic acid oxidation it was found that two types of Pt-Bi bimetallic catalysts (bulk and low loading deposits on GC showed superior catalytic activity in terms of the lower onset potential and oxidation current density, as well as exceptional stability compared to Pt. The findings in this report are important for the understanding of mechanism of formic acid electrooxidation on a bulk alloy and decorated surface, for the development of advanced anode catalysts for direct formic acid fuel cells, as well as for the synthesis of novel low-loading bimetallic catalysts. The use of bimetallic compounds as the anode catalysts is an effective solution to overcoming the problems of the formic acid oxidation current stability for long term applications. In the future, the tolerance of both CO poisoning and electrochemical leaching should be considered as the key factors in the development

  1. Low level exposure to the flame retardant BDE-209 reduces thyroid hormone levels and disrupts thyroid signaling in fathead minnows

    OpenAIRE

    Noyes, Pamela D.; Lema, Sean C.; Macaulay, Laura J.; Douglas, Nora K.; Stapleton, Heather M.

    2013-01-01

    Polybrominated diphenyl ether (PBDE) flame retardants have been shown to disrupt thyroid hormone regulation, neurodevelopment, and reproduction in some animals. However, effects of the most heavily used PBDE, decabromodiphenyl ether (BDE-209), on thyroid functioning remain unclear. This study examined low-dose effects of BDE-209 on thyroid hormone levels and signaling in fathead minnows. Adult males received dietary exposures of BDE-209 at a low dose (~3 ng/g bw-day) and high dose (~300 ng/g ...

  2. Uranium, thorium and bismuth photofission cross sections at high energies

    International Nuclear Information System (INIS)

    The U238, Th232 and Bi209 photofission using nuclear emulsion technique for fission fragments detection is presented. The photofission cross sections were measured using Bremsstrahlung photon which were produced irradiating thin tungsten radiators with electrons accelerated at the energy range from 1,0 to 5,5 GeV in the ''Deutsches Elektronen Synchrotron'' (Hamburg), and aluminium radiator with electrons accelarated at 16,0 GeV in Stanford Linear Accelerator Center. A special revelation technique for nuclear emulsion pellicles loaded with uranium and thorium, allowed the discrimination between alpha particles tracks and fission fragments tracks. The results show a decrease in the cross sections, which is in good agreement, within experimental errors, with the conclusions of other authors. The estimations from the two-step mechanism for high energy nuclear reactions (intranuclear cascade followed by fission-evaporation competition) show that, the primary interaction according to the photomesonic model and the quasi-deuteron photon interaction are sufficient to explain the general behavior exhibited by photofission cross sections for investigated nuclei. The calculations show a resonant structure around 300 MeV, with a width at half maximum of 200 MeV, and another not so pronounced, near to 700 MeV. (Author)

  3. Nuclear Data and Measurements Series: The energy dependence of the optical-model potential for fast-neutron scattering from bismuth

    International Nuclear Information System (INIS)

    Neutron differential-elastic-scattering cross sections of bismuth were measured at 0.5 MeV intervals from 4.5 to 10.0 MeV. At each incident energy ≥40 differential values were obtained, distributed between 180 and 1600. The measured data were combined with lower-energy results previously reported from this laboratory, and others available in the literature, to provide a detailed data base extending from 1.5 to 10.0 MeV. This data base was interpreted in terms of the conventional optical-statistical model and also a model inclusive of the surface-peaked real potential predicted by the dispersion relation. Particular attention was given to the energy dependence of the volume-integral-per-nucleon of the real potential, J/sub v/, to see if there was evidence of the Fermi Surface Anomaly. In the range 3.0 to 10.0 MeV the present data indicate that dJ/sub v//dE is essentially constant, with a relatively large negative value of -6.0 to -9.0 fm3, depending on the model used in the analysis. Below 3.0 MeV, there is some evidence for a decrease in the magnitude of dJ/dE. However, the effect is very small and it is only when this trend is combined with considerations of the J/sub v/ values needed to give correct bound-state energies that evidence for the Fermi Surface Anomaly emerges. J/sub v/ and the geometry of the optical potentials found for 209Bi become equal to those needed to explain the high-energy 208Pb data at about 10.0 MeV. Since dJ/sub v//dE for the latter is smaller in magnitude than for 209Bi, a change in dJ/sub v//dE is clearly indicated near 10.0 MeV. This may effect the extrapolation of higher-energy and charged-particle potentials into the lower-energy neutron domain. 47 refs., 9 figs

  4. Potentiation of the action of metronidazole on Helicobacter pylori by omeprazole and bismuth subcitrate

    DEFF Research Database (Denmark)

    Andersen, L P; Colding, H; Kristiansen, J E

    2000-01-01

    regimens that include proton pump inhibitors. In the present study, the synergistic effect of subinhibitory concentrations (0.25-0.5 MIC) of either bismuth subcitrate or omeprazole with metronidazole on the susceptibility of 42 H. pylori strains was investigated by agar dilution method and the Epsilometer...

  5. Robust synthesis of bismuth titanate pyrochlore nanorods and their photocatalytic applications.

    Science.gov (United States)

    Murugesan, Sankaran; Subramanian, Vaidyanathan Ravi

    2009-09-14

    A facile and template-free reverse micelle-based method can be employed to synthesize highly crystalline and pure stoichiometric bismuth titanate (Bi(2)Ti(2)O(7)) pyrochlore nanorods 400-500 nm long and 40-50 nm in diameter which demonstrate promising photoactivity. PMID:20448962

  6. Performance of bismuth germanate active shielding on a balloon flight over Antarctica

    Energy Technology Data Exchange (ETDEWEB)

    Rester, A.C.; Coldwell, R.L. (Institute for Astrophysics and Planetary Exploration, Univ. of Florida, Alachua, FL (US)); Trombka, J.I. (National Aeronautics and Space Administration, Greenbelt, MD (USA). Goddard Space Flight Center); Starr, R. (Catholic Univ. of America, Washington, DC (USA). Dept. of Physics); Eichhorn, G. (Steward Observatory, Tucson, AZ (USA)); Lasche, G.P. (Defense Advanced Research Projects Agency, Arlington, VA (USA))(Defense Advanced Research Projects Agency, Arlington, VA (USA))

    1990-04-01

    The GRAD gamma-ray spectrometer was flown on a high-altitude balloon at an altitude of 36.6 km over Antarctica on January 8-10, 1988 where it was used to make observations of Supernova 1987a. The performance of the bismuth germinate active shielding in the near-space environment over Antarctica is examined.

  7. Performance of bismuth germanate active shielding on a balloon flight over Antarctica

    International Nuclear Information System (INIS)

    The GRAD gamma-ray spectrometer was flown on a high-altitude balloon at an altitude of 36.6 km over Antarctica on January 8-10, 1988 where it was used to make observations of Supernova 1987a. The performance of the bismuth germinate active shielding in the near-space environment over Antarctica is examined

  8. Effect of bismuth citrate, lactose, and organic acid on necrotic enteritis in broilers

    Science.gov (United States)

    Clostridium perfringens – associated necrotic enteritis causes significant losses and increased morbidity in poultry. The objective of this study was to evaluate the effect of bismuth citrate and acidifiers on the development of necrotic enteritis in broilers. The first study was a dose response t...

  9. Examination of dielectric dispersion of complex oxides on the basis of bismuth-containing titanates

    International Nuclear Information System (INIS)

    In the present work the samples of complex oxide compounds on the basis of bismuth titanates with chalcolamprite structure type and layered perovskite doped with Cr, Fe and Co were studied at room temperature by the method of dielectric spectroscopy in the frequency range of 30 to 106 Hz

  10. Azo dyes photobleaching and operando FTIR study of acetaldehyde photoinduced decomposition on bismuth doped titania

    Czech Academy of Sciences Publication Activity Database

    Henych, Jiří; Štengl, Václav; Mattsson, A.; Österlund, L.

    Thessaloniki: Aristotle University of Thessaloniki, 2014, 41 PC-2-4. [European Meeting on Solar Chemistry and Photocatalysis: Environmental Applications (SPEA) /8./. Thessaloniki (GR), 25.6.2014-28.6.2014] Institutional support: RVO:61388980 Keywords : bismuth doped titania * photocatalytic Subject RIV: CA - Inorganic Chemistry

  11. Renal pigmentation due to chronic bismuth administration in a rhesus macaque (Macaca mulatta).

    Science.gov (United States)

    Johnson, A L; Blaine, E T; Lewis, A D

    2015-05-01

    Renal pigmentation due to the administration of exogenous compounds is an uncommon finding in most species. This report describes renal pigmentation and intranuclear inclusions of the proximal convoluted tubules due to chronic bismuth administration in a rhesus macaque. An 11-year-old Indian-origin rhesus macaque with a medical history of chronic intermittent vomiting had been treated with bismuth subsalicylate, famotidine, and omeprazole singly or in combination over the course of 8 years. At necropsy, the renal cortices were diffusely dark green to black. Light and electron microscopy revealed intranuclear inclusions within the majority of renal proximal tubular epithelial cells. These inclusions appeared magenta to brown when stained with hematoxylin and eosin and were negative by the Ziehl-Neelsen acid-fast stain. Elemental analysis performed on frozen kidney measured bismuth levels to be markedly elevated at 110.6 ppm, approximately 500 to 1000 times acceptable limits. To our knowledge, this is the first report of renal bismuth deposition in a rhesus macaque resulting in renal pigmentation and intranuclear inclusions. PMID:24990482

  12. Dynamics and coherent control of high-amplitude optical phonons in bismuth

    Science.gov (United States)

    Decamp, M. F.; Reis, D. A.; Bucksbaum, P. H.; Merlin, R.

    2001-09-01

    High-amplitude optical phonons in bismuth are generated through impulsive stimulated Raman scattering and detected through the induced change in the optical reflectivity. Reflectivity changes greater than 1% have been recorded. Phonon dynamics and coherent control in the high-amplitude regime are reported.

  13. Microwave-assisted facile and rapid Friedel-Crafts benzoylation of arenes catalysed by bismuth trifluoromethanesulfonate

    DEFF Research Database (Denmark)

    Tran, Phoung Hoang; Hansen, Poul Erik; Pham, Thuy Than;

    2014-01-01

    The catalytic activity of metal triflates was investigated in Friedel–Crafts benzoylation under microwave irradiation. Friedel–Crafts benzoylation with benzoyl chloride of a variety of arenes containing electron-rich and electron-poor rings using bismuth triflate under microwave irradiation is...

  14. Nanodomains and nanometer-scale disorder in multiferroic bismuth ferrite single crystals

    Czech Academy of Sciences Publication Activity Database

    Jia, C.L.; Jin, L.; Wang, D.; Mi, S.B.; Alexe, M.; Hesse, D.; Reichlová, Helena; Martí, Xavier; Bellaiche, L.; Urban, K.W.

    2015-01-01

    Roč. 82, Jan (2015), s. 356-368. ISSN 1359-6454 Institutional support: RVO:68378271 Keywords : bismuth ferrite * crystal growth * high-resolution electron microscopy * atomic structure * first-principles calculations Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 4.465, year: 2014

  15. Group III-nitride thin films grown using MBE and bismuth

    Science.gov (United States)

    Kisielowski, Christian K.; Rubin, Michael

    2000-01-01

    The present invention comprises growing gallium nitride films in the presence of bismuth using MBE at temperatures of about 1000 K or less. The present invention further comprises the gallium nitride films fabricated using the inventive fabrication method. The inventive films may be doped with magnesium or other dopants. The gallium nitride films were grown on sapphire substrates using a hollow anode Constricted Glow Discharge nitrogen plasma source. When bismuth was used as a surfactant, two-dimensional gallium nitride crystal sizes ranging between 10 .mu.m and 20 .mu.m were observed. This is 20 to 40 times larger than crystal sizes observed when GaN films were grown under similar circumstances but without bismuth. It is thought that the observed increase in crystal size is due bismuth inducing an increased surface diffusion coefficient for gallium. The calculated value of 4.7.times.10.sup.-7 cm.sup.2 /sec. reveals a virtual substrate temperature of 1258 K which is 260 degrees higher than the actual one.

  16. Determination of (111) ordered domains on platinum electrodes by irreversible adsorption of bismuth.

    Science.gov (United States)

    Rodríguez, Paramaconi; Solla-Gullón, José; Vidal-Iglesias, Francisco J; Herrero, Enrique; Aldaz, Antonio; Feliu, Juan M

    2005-08-15

    Irreversible adsorbed bismuth can be used to determine the fraction of (111) domains on a given platinum sample. On Pt(111) electrodes, the surface redox process of adsorbed bismuth takes place at 0.63 V in a well-defined peak. The behavior of this redox process on the Pt(111) vicinal surfaces indicates that the bismuth atoms involved in the redox process are only those deposited on the (111) terrace sites and that the charge under the peak at 0.63 V is directly proportional to the number of sites on (111) ordered domains (terraces). The good linear relationship obtained between the charge for the bismuth redox process and the number of (111) terrace sites on the vicinal surfaces allows construction of a calibration curve. This calibration curve has been used to directly estimate the amount of (111) ordered domain terrace sites on polycrystalline platinum samples with different surface ordered domains. The results agree with what we would expect from our knowledge of these surfaces. PMID:16097774

  17. Microwave and magneto-optic properties of bismuth-substituted yttrium iron garnet thin films

    Science.gov (United States)

    Butler, J. C.; Kramer, J. J.; Esman, R. D.; Craig, A. E.; Lee, J. N.; Ryuo, T.

    1990-05-01

    Microwave and magneto-optic measurements have been made on bismuth-substituted yttrium iron garnet (BiYIG) films. Forward-volume (FV) magnetostatic-wave (MSW) attenuation has been measured from ferrimagnetic resonance and from pulse delay data. We report the indirect observation of FV MSW in BiYIG using two independent techniques: a pulse transmission technique and a passband measurement technique. Faraday rotation in the films was also recorded at a wavelength of 1.3 μm. The bismuth-substituted films are grown on carefully cleaned substrates and have yttrium:bismuth ratios of 1:1. The composition of the bismuth substituted films is Y1.5Bi1.5Fe5O12 deduced from lattice parameters and absolute Faraday rotation. These films show particular promise for use in waveguide-type high-speed MSW-optical devices where low MSW attenuation and high Faraday rotation are among the necessary criteria for successful operation.

  18. The antimicrobial effects and metabolomic footprinting of carboxyl-capped bismuth nanoparticles against Helicobacter pylori.

    Science.gov (United States)

    Nazari, P; Dowlatabadi-Bazaz, R; Mofid, M R; Pourmand, M R; Daryani, N E; Faramarzi, M A; Sepehrizadeh, Z; Shahverdi, A R

    2014-01-01

    Organic salts of bismuth are currently used as antimicrobial agents against Helicobacter pylori. This study evaluated the antibacterial effect of elemental bismuth nanoparticles (Bi NPs) using a serial agar dilution method for the first time against different clinical isolates and a standard strain of H. pylori. The Bi NPs were biologically prepared and purified by a recently described method and subjected to further characterization by infrared spectroscopy and anti-H. pylori evaluation. Infrared spectroscopy results showed the presence of carboxyl functional groups on the surface of biogenic Bi NPs. These biogenic nanoparticles showed good antibacterial activity against all tested H. pylori strains. The resulting MICs varied between 60 and 100 μg/ml for clinical isolates of H. pylori and H. pylori (ATCC 26695). The antibacterial effect of bismuth ions was also tested against all test strains. The antimicrobial effect of Bi ions was lower than antimicrobial effect of bismuth in the form of elemental NPs. The effect of Bi NPs on metabolomic footprinting of H. pylori was further evaluated by (1)H NMR spectroscopy. Exposure of H. pylori to an inhibitory concentration of Bi NPs (100 μg/ml) led to release of some metabolites such as acetate, formic acid, glutamate, valine, glycine, and uracil from bacteria into their supernatant. These findings confirm that these nanoparticles interfere with Krebs cycle, nucleotide, and amino acid metabolism and shows anti-H. pylori activity. PMID:24104691

  19. Bio-assisted synthesis and characterization of nanostructured bismuth (III) sulphide using Clostridium acetobutylicum

    International Nuclear Information System (INIS)

    Nanostructured bismuth (III) sulphide is synthesized at room temperature using a hydrogen sulphide producing microorganism namely Clostridium acetobutylicum. On contrary to chemical routes involving both the high and room temperature methods, the present experimental procedure involves a bio-assisted approach. This method is free from the usage of toxic and hazardous chemicals making it an environment friendly route. The synthesized bismuth sulphide is characterized using transmission electron microscope (TEM), powder X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and cyclic voltammetry (CV). From our experiments we find that bismuth sulphide produced using this bio-assisted approach exhibits a hexagonal shaped plate-like structures and is stabilized by the extracellular proteins present in the culture medium. - Graphical abstract: A green chemistry approach towards the synthesis of bismuth (III) sulphide nanostructures at room temperature using a hydrogen sulphide producing microorganism namely, Clostridium acetobutylicum is demonstrated. - Highlights: • Environmentally benign (greener) route towards synthesis of Bi2S3 nanostructures. • Bio-assisted synthesis of Bi2S3 at room temperature using Clostridium acetobutylicum. • Extracellular proteins in H2S producing microorganism as stabilizer for Bi2S3 NPs. • Hexagonal platelets of Bi2S3 possessing an orthorhombic crystalline structure

  20. Electrodeposition of bismuth telluride nanowires with controlled composition in polycarbonate membranes

    International Nuclear Information System (INIS)

    Bismuth telluride nanowires were potentiostatically deposited from a water/DMSO 50%, v/v electrolyte within polycarbonate etched ion-track membranes covered by a platinum substrate. The presence of DMSO shifts the potentials to more negative values and slows down the cation diffusion. Cyclic voltammetries on recessed Pt nanoelectrodes using polycarbonate membranes highlight a complex electrochemical behavior through several cathodic and anodic peaks which are not observed onto platinum discs macroelectrodes. Analytical investigations enabled the determination of appropriate deposition conditions to finely tune the average composition of the nanowires. Calibrated TEM-EDX analyses evidence high aspect ratio nanowires, whose composition is strongly dependent on the deposition potential. In the same manner as for bismuth telluride film electroplating, bismuth enrichment occurs at more cathodic deposition potential whereas tellurium enrichment is observed at low cathodic potentials. Stoichiometric nanowires of 60 nm diameter were obtained at −100 mV vs Ag/AgCl from an electrolyte which contains [Bi3+] = 1.5[HTeO2+] = 15 mM. The composition is homogeneous along the nanowire except at both edges: the cap is rich in bismuth whereas the base is rich in tellurium. The composition at the nanowire base is adjusted by setting a short initial voltage step (Ui = −300 mV vs Ag/AgCl, ti = 2 s). In the case of stoichiometric compounds, the resulting nanostructures were found to be polycrystalline with a preferential orientation along the direction perpendicular to the planes (0 1 5).

  1. Electrodeposition of bismuth telluride thermoelectric films from a nonaqueous electrolyte using ethylene glycol

    NARCIS (Netherlands)

    Nguyen, H.P.; Wu, M.; Su, J.; Vullers, R.J.M.; Vereecken, P.M.; Fransaer, J.

    2012-01-01

    Ethylene glycol was studied as an electrolyte for the electrodeposition of thermoelectric bismuth telluride films by cyclic voltammetry, rotating ring disk electrode and electrochemical quartz crystal microbalance (EQCM). The reduction of both Bi3+ and Te4+ ions proceeds in one step without the form

  2. Structural Engineering of Vacancy Defected Bismuth Tellurides for Thermo-electric Applications

    Directory of Open Access Journals (Sweden)

    Chumakov Y.

    2012-10-01

    Full Text Available Molecular Dynamics and ab-initio simulations are used to find the most stable stoichiometries of Bismuth Tellurides with vacancy defects. The interest is to decrease the thermal conductivity of these compounds a key point to achieve high figure of merits. A reduction of 70% of the thermal conductivity is observed with Te vacancies of only 5%.

  3. Bio-assisted synthesis and characterization of nanostructured bismuth (III) sulphide using Clostridium acetobutylicum

    Energy Technology Data Exchange (ETDEWEB)

    Kamaraj, Sathish Kumar; Venkatachalam, Ganesh; Arumugam, Palaniappan; Berchmans, Sheela, E-mail: sheelaberchmans@yahoo.com

    2014-02-14

    Nanostructured bismuth (III) sulphide is synthesized at room temperature using a hydrogen sulphide producing microorganism namely Clostridium acetobutylicum. On contrary to chemical routes involving both the high and room temperature methods, the present experimental procedure involves a bio-assisted approach. This method is free from the usage of toxic and hazardous chemicals making it an environment friendly route. The synthesized bismuth sulphide is characterized using transmission electron microscope (TEM), powder X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and cyclic voltammetry (CV). From our experiments we find that bismuth sulphide produced using this bio-assisted approach exhibits a hexagonal shaped plate-like structures and is stabilized by the extracellular proteins present in the culture medium. - Graphical abstract: A green chemistry approach towards the synthesis of bismuth (III) sulphide nanostructures at room temperature using a hydrogen sulphide producing microorganism namely, Clostridium acetobutylicum is demonstrated. - Highlights: • Environmentally benign (greener) route towards synthesis of Bi{sub 2}S{sub 3} nanostructures. • Bio-assisted synthesis of Bi{sub 2}S{sub 3} at room temperature using Clostridium acetobutylicum. • Extracellular proteins in H{sub 2}S producing microorganism as stabilizer for Bi{sub 2}S{sub 3} NPs. • Hexagonal platelets of Bi{sub 2}S{sub 3} possessing an orthorhombic crystalline structure.

  4. Fridel-Crafts acylation using bismuth triflate in [BMI][PF6

    DEFF Research Database (Denmark)

    Tran, Phuong Hoang; Duus, Fritz; Le, Thach Ngoc

    2012-01-01

    Bismuth trifluoromethanesulfonate was found to be a good catalyst for the Friedel–Craftsacylation. Bismuthtriflate immobilized in an ionic liquid was the most efficient catalytic system. Bismuthtriflate in [BMI][PF6] catalyzes this reaction under microwave irradiation allowing the rapid synthesis...

  5. Thermodynamics of neptunium in LiCl-KCl eutectic/liquid bismuth systems

    International Nuclear Information System (INIS)

    Thermodynamic properties of neptunium in LiCl-KCl eutectic/liquid bismuth systems in the temperature range 400--500 C have been studied using a galvanic cell method for the pyrometallurgical reprocessing of nuclear spent fuels. The standard potential of the Np/Np(III) couple vs. the Ag/AgCl (1 wt% AgCl) reference electrode in LiCl-KCl eutectic was measured and given by the equation ENp/Np(III)0 = minus2.0667 + 0.0007892 T (σ = 0.0009), where E is in volts, T is in kelvin, and σ is the standard deviation. The potential of neptunium-bismuth alloy, ENp-Bi, was measured as a function of neptunium concentration, XNpinBi. The curves for EBi-Np vs. log XNpinBi indicated the neptunium solubility in liquid bismuth to be 0.34 ± 0.02, 0.61 ± 0.08, and 1.06 ± 0.09 (±σ) atom % at 400, 450, and 500 C, respectively. The excess partial free energy of neptunium in liquid bismuth was represented by the equation, Δbar GNpxs (kcal/g atom) = minus32.5 (±0.7) + 0.0072 (±0.0010) T. The values of the solubility and excess partial free energy for neptunium were closer to those for plutonium rather than uranium

  6. Optimal biliary drainage for inoperable Klatskin's tumor based on Bismuth type

    OpenAIRE

    Lee, Sang Hyub; Park, Joo Kyung; Yoon, Won Jae; Lee, Jun Kyu; Ryu, Ji Kon; Yoon, Yong Bum; Kim, Yong-Tae

    2007-01-01

    AIM: To investigate differences in the effects of biliary drainage procedures in patients with inoperable Klatskin’s tumor based on Bismuth type, considering endoscopic retrograde biliary drainage (ERBD), external percutaneous transhepatic biliary drainage (EPTBD) and internal biliary stenting via the PTBD tract (IPTBD).

  7. Designing of Anti Dengue Drug Molecule against Insilico Modeled Target DC-Sign (CD-209

    Directory of Open Access Journals (Sweden)

    Prashantha C.N

    2013-09-01

    Full Text Available The C-type lectin DC-SIGN (CD209 plays a major role in receptor on human dendritic cells, it binds to several glycoproteins of viruses that facilitate disease progression. In dengue fever, the disease targets of arbovirus infection, show dendritic and reticuloendothelial cells that may affect immune system. The phytochemical extracts of Bosenbergia rotunda (BR have been effectively used as potential small molecular inhibitors to inhibit DC-SIGN (CD209 function. Using rational drug designing the training sets include Panduratin-A and 4-hydroxypanduratin is designed from BR derivatives could be an effective inhibitor of a DC-SIGN (CD209 binding towards the drug discovery/ therapy against dengue fever.

  8. Hall Plateaus at magic angles in ultraquantum Bismuth

    Science.gov (United States)

    Benoît, Fauqué.

    2009-03-01

    The behaviour of a three-dimensional electron gas in the presence of a magnetic field strong enough to put all carriers in the first Landau level (i.e. beyond the quantum limit) is a longstanding question of theoretical condensed matter physics [1]. This issue has been recently explored by two high-field experiments on elemental semi-metal Bismuth. In a first study of transport coefficients (which are dominated by hole-like carriers), the Nernst coefficient presented three unexpected maxima that are concomitant with quasi-plateaux in the Hall coefficient [2]. In a second series of experiments, torque magnetometry (which mainly probes the three Dirac valley electron pockets) detected a field-induced phase transition [3]. The full understanding of the electron and hole behaviours above the quantum limit of pure Bi is therefore still under debate. In this talk, we will present our measurement of the Hall resistivity and torque magnetometry with magnetic field up to 31 T and rotating in the trigonal-bisectrix plane [4]. The Hall response is dominated by the hole pockets according to its sign as well as the period and the angular dependence of its quantum oscillations. In the vicinity of the quantum limit, it presents additional anomalies which are the fingerprints of the electron pockets. We found that for particular orientations of the magnetic field (namely ``magic angles''), the Hall response becomes field-independent within the experimental resolution around 20T. This drastic dependence of the plateaux on the field orientation provides strong constraints for theoretical scenarios. [4pt] [1] Bertrand I. Halperin, Japanese Journal of Applied Physics, 26, Supplement 26-3 (1987).[0pt] [2] Kamran Behnia, Luis Balicas, Yakov Kopelevich, Science, 317, 1729 (2008).[0pt] [3] Lu Li, J. G. Checkelsky, Y. S. Hor, C. Uher, A. F. Hebard, R. J. Cava, and N. P. Ong , Science, 321, 5888 (2008).[0pt] [4] Benoît Fauqu'e, Luis Balicas, Ilya Sheikin, Jean Paul Issi and Kamran Behnia

  9. Improvements to a Flow Sensor for Liquid Bismuth-Fed Hall Thrusters

    Science.gov (United States)

    Bonds, Kevin; Polzin, Kurt A.

    2010-01-01

    Recently, there has been significant interest in using bismuth metal as a propellant in Hall Thrusters [1, 2]. Bismuth offers some considerable cost, weight, and space savings over the traditional propellant--xenon. Quantifying the performance of liquid metal-fed Hall thrusters requires a very precise measure of the low propellant flow rates [1, 2]. The low flow rates (10 mg/sec) and the temperature at which free flowing liquid bismuth exists (above 300 C) preclude the use of off-the-shelf flow sensing equipment [3]. Therefore a new type of sensor is required. The hotspot bismuth flow sensor, described in Refs. [1-5] is designed to perform a flow rate measurement by measuring the velocity at which a thermal feature moves through a flow chamber. The mass flow rate can be determined from the time of flight of the thermal peak, [4, 5]. Previous research and testing has been concerned mainly with the generation of the thermal peak and it's subsequent detection. In this paper, we present design improvements to the sensor concept; and the results of testing conducted to verify the functionality of these improvements. A ceramic material is required for the sensor body (see Fig. 1), which must allow for active heating of the bismuth flow channel to keep the propellant in a liquid state. The material must be compatible with bismuth and must be bonded to conductive elements to allow for conduction of current into the liquid metal and measurement of the temperature in the flow. The new sensor requires fabrication techniques that will allow for a very small diameter flow chamber, which is required to produce useful measurements. Testing of various materials has revealed several that are potentially compatible with liquid bismuth. Of primary concern in the fabrication and testing of a robust, working prototype, is the compatibility of the selected materials with one another. Specifically, the thermal expansion rates of the materials relative to the ceramic body cannot expand so

  10. Synthesis and performance of bismuth trioxide nanoparticles for high energy gas generator use

    Energy Technology Data Exchange (ETDEWEB)

    Martirosyan, K S; Wang, L; Vicent, A; Luss, D, E-mail: kmartirossian@uh.ed [Department of Chemical and Biomolecular Engineering, University of Houston, Houston, TX 77204 (United States)

    2009-10-07

    Our experiments showed that the combustion of an Al-Bi{sub 2}O{sub 3} nanoparticle mixture generated the highest pressure pulse among common nanothermite reactions and can potentially be used as a nanoenergetic gas generator. The combustion front propagation velocity and rate of energy release increased by up to three orders of magnitude when the particle size was reduced to a nanosize range for both the aluminum and the oxidizer. We developed a novel one-step (metal nitrate-glycine) combustion synthesis of nanostructured amorphous-like and highly crystalline bismuth trioxide nanoparticles. The combustion synthesis was conducted using a solution of molten bismuth nitrate as an oxidizer and glycine as a fuel. The glycine was completely combusted during the thermal decomposition of the bismuth nitrate pentahydrate and generated a temperature front that propagated through the sample. Increasing the fuel concentration increased the maximum combustion temperature from 280 to 1200 {sup 0}C and the Bi{sub 2}O{sub 3} particle size from 20 to 100 nm. The oxidizer/fuel ratio had a strong impact on the bismuth trioxide particle crystallinity. At low temperature (280 {sup 0}C), amorphous-like bismuth trioxide nanoparticles formed, while at T{>=}370 {sup 0}C the structures were crystalline. A peak pressure of {approx}12 MPa and a thermal front propagating velocity of {approx}2500 m s{sup -1} were achieved during the combustion of an Al-Bi{sub 2}O{sub 3} mixture containing 80 wt% of the synthesized Bi{sub 2}O{sub 3} crystalline nanoparticles (size: 40-50 nm).

  11. Measurement of nuclear cross sections using radioactive beams

    International Nuclear Information System (INIS)

    One of the main applications of the production and use of nuclear radioactive beams is the measurement of nuclear cross sections. In this work is used a 6 He nuclear radioactive beam (β emitting with half life 806.7 ms) for the study of the reaction 6 + 209 Bi which could have several products. This investigation was realized in collaboration with the personnel of the Nuclear Structure laboratory at the University of Notre Dame (U.S.A.) and the National institute of Nuclear Research and CONACyT by Mexico. (Author)

  12. Beam - cavity interaction beam loading

    International Nuclear Information System (INIS)

    The interaction of a beam with a cavity and a generator in cyclic accelerators or storage rings is investigated. Application of Maxwell's equations together with the nonuniform boundary condition allows one to get an equivalent circuit for a beam-loaded cavity. The general equation for beam loading is obtained on the basis of the equivalent circuit, and the beam admittance is calculated. Formulas for power consumption by a beam-loaded cavity are derived, and the optimal tuning and coupling factor are analyzed. (author)

  13. CLASH-VLT: Environment-driven evolution of galaxies in the z = 0.209 cluster Abell 209

    Science.gov (United States)

    Annunziatella, M.; Mercurio, A.; Biviano, A.; Girardi, M.; Nonino, M.; Balestra, I.; Rosati, P.; Bartosch Caminha, G.; Brescia, M.; Gobat, R.; Grillo, C.; Lombardi, M.; Sartoris, B.; De Lucia, G.; Demarco, R.; Frye, B.; Fritz, A.; Moustakas, J.; Scodeggio, M.; Kuchner, U.; Maier, C.; Ziegler, B.

    2016-01-01

    Context. The analysis of galaxy properties, such as stellar masses, colors, sizes and morphologies, and the relations among them and the environment, in which the galaxies reside, can be used to investigate the physical processes driving galaxy evolution. Aims: We conduct a thorough study of the cluster A209 with a new large spectro-photometric dataset to investigate possible environmental effects on galaxy properties that can provide information on galaxy evolution in cluster hostile environments. Methods: We use the dataset obtained as part of the CLASH-VLT spectroscopic survey, supplemented with Subaru/SuprimeCam high-quality imaging in BVRIz-bands, which yields 1916 cluster members (50% of them spectroscopically confirmed) down to a stellar mass M⋆ = 108.6 M⊙. We determine the stellar mass function of these galaxies in different regions of the cluster, by separating the sample into star-forming and passive cluster members. We then determine the intra-cluster light and its properties. We also derive the orbits of low- (M⋆ ≤ 1010.0 M⊙) and high-mass (M⋆ > 1010.0 M⊙) passive galaxies and study the effect of the environment on the mass-size relation of early-type galaxies, selected according to their Sérsic index; the effects are studied separately for the galaxies in each mass range. Finally, we compare the cluster stellar mass density profile with the number density and total-mass density profiles. Results: The stellar mass function of the star-forming cluster galaxies does not depend on the environment. The slope found for passive galaxies becomes flatter in the densest cluster region, which implies that the low-mass component starts to dominate when moving away from the cluster center. The color distribution of the intra-cluster light is consistent with the color of passive cluster members. The analysis of the dynamical orbits of passive galaxies shows that low-mass galaxies have tangential orbits, avoiding small pericenters around the BCG. The

  14. 43 CFR 17.209 - Effect of State or local law or other requirements and effect of employment opportunities.

    Science.gov (United States)

    2010-10-01

    ... requirements and effect of employment opportunities. 17.209 Section 17.209 Public Lands: Interior Office of the... employment opportunities. (a) The obligation to comply with this subpart is not obviated or alleviated by the... alleviated because employment opportunities in any occupation or profession are or may be more limited...

  15. 40 CFR 600.209-08 - Calculation of vehicle-specific 5-cycle fuel economy values for a model type.

    Science.gov (United States)

    2010-07-01

    ...-cycle fuel economy values for a model type. 600.209-08 Section 600.209-08 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) ENERGY POLICY FUEL ECONOMY AND CARBON-RELATED EXHAUST EMISSIONS OF MOTOR VEHICLES Fuel Economy Regulations for 1977 and Later Model Year Automobiles-Procedures...

  16. Impact of co-exposure with lead and decabromodiphenyl ether (BDE-209) on thyroid function in zebrafish larvae

    International Nuclear Information System (INIS)

    Highlights: • PBDEs and metals are the main contaminants at e-waste recycling sites. • Combined effects of Pb/BDE-209 on thyroid function in zebrafish larvae were studied. • Co-exposure of Pb and BDE-209 elicited synergistic effects on T3 and T4 levels. • BDE-209 enhanced Pb uptake, and Pb decreased bioconcentration/metabolism of BDE-209. • Mixtures of Pb and BDE-209 probably result in an increase in toxicological effects. - Abstract: Polybrominated diphenyl ethers (PBDEs) and metals are the main contaminants at waste electrical and electronic equipment (“e-waste”) recycling sites. However, the potential environmental health effects of mixtures of PBDEs and metals are not known. We investigated co-exposure of lead (Pb) with decabromodiphenyl ether (BDE-209) on thyroid function in zebrafish larvae. Seven groups of embryos/larvae of zebrafish were treated with Pb (0, 2, 5, 10, 15, 20, and 30 μg/L), six groups were exposed to BDE-209 (0, 50, 100, 200, 400, and 800 μg/L), and nine groups of zebrafish larvae were treated with Pb and BDE-209 (5, 10, and 20 μg/L Pb; 50, 100, and 200 μg/L BDE-209). Embryos/larvae were exposed from 2 h post-fertilization (hpf) until 144 hpf, and thyroid hormone (TH) content measured. Pb exposure significantly decreased whole-body TH contents (triiodothyroxine (T3) and thyroxine (T4)) but BDE-209 exposure significantly increased T3 and T4 levels. Pb or BDE-209 treatment alone caused a predicted downregulation of TH transport (i.e., expression of the mRNA or proteins of transthyretin). Chemical analyses showed Pb uptake to be increased by BDE-209, but BDE-209 bioconcentration was decreased and the ability to metabolize BDE-209 was reduced in the presence of Pb. We also found that a mixture of the two chemicals had a synergistic effect on TH levels in zebrafish

  17. Impact of co-exposure with lead and decabromodiphenyl ether (BDE-209) on thyroid function in zebrafish larvae

    Energy Technology Data Exchange (ETDEWEB)

    Zhu, Biran; Wang, Qiangwei; Wang, Xianfeng [State Key Laboratory of Freshwater Ecology and Biotechnology, Institute of Hydrobiology, Chinese Academy of Sciences, Wuhan 430072 (China); University of Chinese Academy of Sciences, Beijing 100049 (China); Zhou, Bingsheng, E-mail: bszhou@ihb.ac.cn [State Key Laboratory of Freshwater Ecology and Biotechnology, Institute of Hydrobiology, Chinese Academy of Sciences, Wuhan 430072 (China)

    2014-12-15

    Highlights: • PBDEs and metals are the main contaminants at e-waste recycling sites. • Combined effects of Pb/BDE-209 on thyroid function in zebrafish larvae were studied. • Co-exposure of Pb and BDE-209 elicited synergistic effects on T{sub 3} and T{sub 4} levels. • BDE-209 enhanced Pb uptake, and Pb decreased bioconcentration/metabolism of BDE-209. • Mixtures of Pb and BDE-209 probably result in an increase in toxicological effects. - Abstract: Polybrominated diphenyl ethers (PBDEs) and metals are the main contaminants at waste electrical and electronic equipment (“e-waste”) recycling sites. However, the potential environmental health effects of mixtures of PBDEs and metals are not known. We investigated co-exposure of lead (Pb) with decabromodiphenyl ether (BDE-209) on thyroid function in zebrafish larvae. Seven groups of embryos/larvae of zebrafish were treated with Pb (0, 2, 5, 10, 15, 20, and 30 μg/L), six groups were exposed to BDE-209 (0, 50, 100, 200, 400, and 800 μg/L), and nine groups of zebrafish larvae were treated with Pb and BDE-209 (5, 10, and 20 μg/L Pb; 50, 100, and 200 μg/L BDE-209). Embryos/larvae were exposed from 2 h post-fertilization (hpf) until 144 hpf, and thyroid hormone (TH) content measured. Pb exposure significantly decreased whole-body TH contents (triiodothyroxine (T{sub 3}) and thyroxine (T{sub 4})) but BDE-209 exposure significantly increased T{sub 3} and T{sub 4} levels. Pb or BDE-209 treatment alone caused a predicted downregulation of TH transport (i.e., expression of the mRNA or proteins of transthyretin). Chemical analyses showed Pb uptake to be increased by BDE-209, but BDE-209 bioconcentration was decreased and the ability to metabolize BDE-209 was reduced in the presence of Pb. We also found that a mixture of the two chemicals had a synergistic effect on TH levels in zebrafish.

  18. Frozen Beams

    CERN Document Server

    Okamoto, Hiromi

    2005-01-01

    In general, the temperature of a charged particle beam traveling in an accelerator is very high. Seen from the rest frame of the beam, individual particles randomly oscillate about the reference orbit at high speed. This internal kinetic energy can, however, be removed by introducing dissipative interactions into the system. As a dissipative process advances, the beam becomes denser in phase space or, in other words, the emittance is more diminished. Ideally, it is possible to reach a "zero-emittance" state where the beam is Coulomb crystallized. The space-charge repulsion of a crystalline beam just balances the external restoring force provided by artificial electromagnetic elements. In this talk, general discussion is made of coasting and bunched crystalline beams circulating in a storage ring. Results of molecular dynamics simulations are presented to demonstrate the dynamic nature of various crystalline states. A possible method to approach such an ultimate state of matter is also discussed.

  19. Beam loading

    CERN Document Server

    Gamp, Alexander

    2013-01-01

    We begin by giving a description of the radio-frequency generator-cavity-beam coupled system in terms of basic quantities. Taking beam loading and cavity detuning into account, expressions for the cavity impedance as seen by the generator and as seen by the beam are derived. Subsequently methods of beam-loading compensation by cavity detuning, radio-frequency feedback and feedforward are described. Examples of digital radio-frequency phase and amplitude control for the special case of superconducting cavities are also given. Finally, a dedicated phase loop for damping synchrotron oscillations is discussed.

  20. ELECTRA: A European Lead-bismuth Cooled Training Reactor

    International Nuclear Information System (INIS)

    The lack of low power liquid metal cooled reactors has meant that few engineers within the nuclear power industry and research community are familiar with operational procedures of this family of coolants, expected to be used for Generation IV fast neutron systems. The reasons for this lack may include safety issues related to use of Mercury, NaK or sodium as applied in early low power reactors. Especially in western Europe, no low power liquid metal cooled reactor was ever in operation. Here, we present the design of a 2 MWth lead-bismuth cooled reactor with (Pu,Zr)N fuel, relying on natural convection for full power operation. The combination of low power density with natural convection for heat removal makes the reactor ideal for training purposes. The large thermal expansion of heavy liquid metals makes is possible to design low power fast neutron reactors relying on natural convection. Since at present, there exists no suitable material for pumps operating at high velocity in lead alloy environments, the only possible short term solution for constructing such a reactor is anyway to design for 100% natural circulation of the coolant. For this purpose, a small core height, a large difference between coolant inlet and outlet temperatures and a low coolant velocity is desired. By application of (Pu,Zr)N fuel, criticality can be achieved with a fissile inventory of 100 kg LWR grade plutonium. Monte Carlo simulations show that 19 hexagonal fuel assemblies, each with 91 fuel pins having an outer diameter of 1.1 cm, and an active height of 15 cm is sufficient to obtain a critical core. Including end pellets, gas plenum and end caps, the total core height is limited to 30 cm. Adopting P/D = 1.25 and a heat exchanger elevation of 4 m, it is found that 2 MW of thermal power may be removed by a natural circulation velocity of 0.4 m/s. This corresponds to a linear rating of 8 kW/m and a temperature increase of the coolant equal to 240 degrees. Limiting the clad temperature

  1. 48 CFR 2452.209-70 - Potential organizational conflicts of interest.

    Science.gov (United States)

    2010-10-01

    ... competitive advantage. The offeror may also provide relevant facts that show how its organizational structure... 48 Federal Acquisition Regulations System 6 2010-10-01 2010-10-01 true Potential organizational... Provisions and Clauses 2452.209-70 Potential organizational conflicts of interest. As prescribed in...

  2. 23 CFR 633.209 - Notices to prospective Federal-aid construction contractors.

    Science.gov (United States)

    2010-04-01

    ... 23 Highways 1 2010-04-01 2010-04-01 false Notices to prospective Federal-aid construction...) § 633.209 Notices to prospective Federal-aid construction contractors. The State highway department... Development System and Appalachian local access roads construction contracts....

  3. 22 CFR 209.12 - Effect on other regulations; supervision and coordination.

    Science.gov (United States)

    2010-04-01

    ... 22 Foreign Relations 1 2010-04-01 2010-04-01 false Effect on other regulations; supervision and... OF THE CIVIL RIGHTS ACT OF 1964 § 209.12 Effect on other regulations; supervision and coordination... other ground. (b) Supervision and coordination. The Administrator may from time to time assign...

  4. Equal Opportunity in Higher Education: The Past and Future of California's Proposition 209

    Science.gov (United States)

    Grodsky, Eric, Ed.; Kurlaender, Michal, Ed.

    2010-01-01

    This timely book examines issues pertaining to equal opportunity--affirmative action, challenges to it, and alternatives for improving opportunities for underrepresented groups--in higher education today. Its starting point is California's Proposition 209, which ended race-based affirmative action in public education and the workplace in 1996. The…

  5. 48 CFR 1552.209-70 - Organizational conflict of interest notification.

    Science.gov (United States)

    2010-10-01

    ... 48 Federal Acquisition Regulations System 6 2010-10-01 2010-10-01 true Organizational conflict of... Clauses 1552.209-70 Organizational conflict of interest notification. As prescribed in 1509.507-1(b) insert the following solicitation provision in all solicitations. Organizational Conflict of...

  6. 48 CFR 1352.209-70 - Potential organizational conflict of interest.

    Science.gov (United States)

    2010-10-01

    ....209-70 Potential organizational conflict of interest. As prescribed in 48 CFR 1309.507-1(a), insert the following provision, modified appropriately: Potential Organizational Conflict of Interest (APR 2010) (a) There is a potential organizational conflict of interest (see FAR Subpart 9.5,...

  7. 48 CFR 952.209-8 - Organizational conflicts of interest-disclosure.

    Science.gov (United States)

    2010-10-01

    ... Services (JUN 1997) (a) Organizational conflict of interest means that because of other activities or... 48 Federal Acquisition Regulations System 5 2010-10-01 2010-10-01 false Organizational conflicts... Clauses 952.209-8 Organizational conflicts of interest-disclosure. As prescribed in 909.507-1(e),...

  8. 48 CFR 1552.209-72 - Organizational conflict of interest certification.

    Science.gov (United States)

    2010-10-01

    ... 48 Federal Acquisition Regulations System 6 2010-10-01 2010-10-01 true Organizational conflict of... Provisions and Clauses 1552.209-72 Organizational conflict of interest certification. As prescribed in 1509... existence of any potential organizational conflict of interest. If the offeror is aware of...

  9. Pion-Induced Fission of 209Bi and 119Sn:. Measurements, Calculations, Analyses and Comparison

    Science.gov (United States)

    Rana, Mukhtar Ahmed; Sher, Gul; Manzoor, Shahid; Shehzad, M. I.

    Cross-sections for the π--induced fission of 209Bi and 119Sn have been measured using the most sensitive CR-39 solid-state nuclear track detector. In experiments, target-detector stacks were exposed to negative pions of energy 500, 672, 1068, and 1665 MeV at the Brookhaven National Laboratory, USA. An important aspect of the present paper is the comparison of pion-induced fission fragment spectra of above mentioned nuclei with the spontaneous fission fragment spectra of 252Cf. This comparison is made in terms of fission fragment track lengths in the CR-39 detectors. Measurement results are compared with calculations of Monte Carlo and statistical weight functions methods using the computer code CEM95. Agreement between measurements and calculations is fairly good for 209Bi target nuclei whereas it is indigent for the case of 119Sn. The possibilities of the trustworthy calculations, using the computer code CEM95, comparable with measurements of pion-induced fission in intermediate and heavy nuclei are explored by employing various systematics available in the code. Energy dependence of pion-induced fission in 119Sn and 209Bi is analyzed employing a newly defined parameter geometric-size-normalized fission cross-section (χfg). It is found that the collective nuclear excitations, which may lead to fission, become more probable for both 209Bi and 119Sn nuclei with increasing energy of negative pions from 500 to 1665 MeV.

  10. 48 CFR 52.209-4 - First Article Approval-Government Testing.

    Science.gov (United States)

    2010-10-01

    ... 48 Federal Acquisition Regulations System 2 2010-10-01 2010-10-01 false First Article Approval... Clauses 52.209-4 First Article Approval—Government Testing. As prescribed in 9.308-2 (a) and (b), insert the following clause: First Article Approval—Government Testing (SEP 1989) (a) The Contractor...

  11. 48 CFR 52.209-3 - First Article Approval-Contractor Testing.

    Science.gov (United States)

    2010-10-01

    ... 48 Federal Acquisition Regulations System 2 2010-10-01 2010-10-01 false First Article Approval... Clauses 52.209-3 First Article Approval—Contractor Testing. As prescribed in 9.308-1 (a) and (b), insert the following clause: First Article Approval—Contractor Testing (SEP 1989) (a) The Contractor...

  12. 48 CFR 2152.209-70 - Certification regarding debarment, suspension, proposed debarment and other responsibility...

    Science.gov (United States)

    2010-10-01

    ... the contract resulting from this certification for default. (Name of Company) By: (Signature) (Name... 48 Federal Acquisition Regulations System 6 2010-10-01 2010-10-01 true Certification regarding... CONTRACT CLAUSES Text of Provisions and Clauses 2152.209-70 Certification regarding debarment,...

  13. Confirmation of 20% error in the 209Po half-life

    International Nuclear Information System (INIS)

    First results of a half-life measurement of 209Po show 20% discrepancy with the formerly recommended value of 102 (5) years, which was based on a single experiment performed in 1956. After one year of measurement, a statistical uncertainty on T1/2 of 3.5% has been reached and effects of long-term instability are assumed to be less than 5%. The preliminary half-life value obtained in this work, 120 (6) years, supports the newly determined value of 125.2 (33) years by Collé et al. (2014). The 20% error in the half-life has an impact on numerous measurements in which aged 209Po solutions were used as a tracer. - Highlights: • Measured half-life of 209Po is 120 (6) a. • The formerly recommended value was in error by 20%. • Measurement results using 209Po as a tracer are affected. • The error persisted for half a century

  14. 18 CFR 1304.209 - Land-based structures/alterations.

    Science.gov (United States)

    2010-04-01

    ... 18 Conservation of Power and Water Resources 2 2010-04-01 2010-04-01 false Land-based structures... APPROVAL OF CONSTRUCTION IN THE TENNESSEE RIVER SYSTEM AND REGULATION OF STRUCTURES AND OTHER ALTERATIONS TVA-Owned Residential Access Shoreland § 1304.209 Land-based structures/alterations. (a) Except...

  15. 77 FR 16319 - Amtrak's Petition for Determination of PRIIA Section 209 Cost Methodology

    Science.gov (United States)

    2012-03-20

    ... From the Federal Register Online via the Government Publishing Office SURFACE TRANSPORTATION BOARD Amtrak's Petition for Determination of PRIIA Section 209 Cost Methodology AGENCY: Surface Transportation... environment or the conservation of energy resources. Decided: March 13, 2012. By the Board, Chairman...

  16. 49 CFR 238.209 - Forward end structure of locomotives, including cab cars and MU locomotives.

    Science.gov (United States)

    2010-10-01

    ... 49 Transportation 4 2010-10-01 2010-10-01 false Forward end structure of locomotives, including... SAFETY STANDARDS Specific Requirements for Tier I Passenger Equipment § 238.209 Forward end structure of locomotives, including cab cars and MU locomotives. (a)(1) The skin covering the forward-facing end of...

  17. The LEP 2 machine : pushing to the limits 209 GeV! Exhibition LEPFest 2000

    CERN Multimedia

    2000-01-01

    By installing 288 new superconducting accelerating cavities after 1995,and thanks to the excellent work of the CERN teams,energies up to 209 GeV -well beyond LEP 's original design energy -have been achieved.Significant experi- mental data have been collected at energies in excess of 206 GeV.

  18. 20 CFR 209.17 - Use of payroll records as returns of compensation.

    Science.gov (United States)

    2010-04-01

    ... 20 Employees' Benefits 1 2010-04-01 2010-04-01 false Use of payroll records as returns of... RAILROAD RETIREMENT ACT RAILROAD EMPLOYERS' REPORTS AND RESPONSIBILITIES § 209.17 Use of payroll records as returns of compensation. Payroll records of employers which have permanently ceased operations may...

  19. In vitro synergy testing of clarithromycin and 14-hydroxyclarithromycin with amoxicillin or bismuth subsalicylate against Helicobacter pylori.

    OpenAIRE

    Meyer, J.M.; Ryu, S; Pendland, S L; Danziger, L H

    1997-01-01

    The activity of clarithromycin-14-hydroxyclarithromycin (2:1 ratio) and bismuth subsalicylate or amoxicillin against Helicobacter pylori was determined by the checkerboard technique in vitro. Clarithromycin-14-hydroxyclarithromycin and amoxicillin resulted in additive effects in 7 of 22 isolates, compared to 14 of 22 isolates when bismuth subsalicylate was substituted for amoxicillin. Synergy was not demonstrated and is probably not responsible for the clinical success of treatment combinatio...

  20. Electrodes modified with bismuth, antimony and tin precursor compounds for electrochemical stripping analysis of trace metals (a short review)

    OpenAIRE

    Lezi, Nikolitsa; Economou, Anastasios; Barek, Jiří

    2014-01-01

    Over the last decade, intensive research is being carried out towards the development of “green” electrochemical sensors. Bismuth, antimony and tin electrodes have been proposed as potential substitutes of mercury electrodes in electrochemical stripping analysis of trace metals. The main advantage of these metals as electrode materials is their lower toxicity compared to mercury. Among the different configuration of bismuth, antimony and tin electrodes, one of the most attractive inv...

  1. Optical properties of bismuth-doped SiO2- or GeO2-based glass core optical fibers

    OpenAIRE

    Firstova, Elena G.

    2015-01-01

    A detailed study of optical properties of bismuth-doped fibers based on SiO2 and GeO2 glasses containing no other dopants has been carried out. To provide important information about spectroscopic properties of IR bismuth-related active centers (BAC) the excitation-emission fluorescence spectra for a spectral region of 220-2000 nm have been measured. The obtained three-dimensional spectra have been presented for different host glass compositions: silicate, germanate, aluminosilicate and phosp...

  2. Calculation of the two-electron vacuum-polarization corrections to the hyperfine splitting in Li-like bismuth

    International Nuclear Information System (INIS)

    Ab initio calculation of the two-electron vacuum-polarization corrections to the hyperfine splitting in Li-like bismuth is presented. The diagrams with electric and magnetic vacuum-polarization loops are evaluated rigorously to all orders in αZ. The accuracy of the theoretical prediction for the screened quantum electrodynamics contribution to the specific difference of the hyperfine splitting values of H- and Li-like bismuth is improved by a factor of 3. (paper)

  3. CD209L (L-SIGN) is a receptor for severe acute respiratory syndrome coronavirus

    Science.gov (United States)

    Jeffers, Scott A.; Tusell, Sonia M.; Gillim-Ross, Laura; Hemmila, Erin M.; Achenbach, Jenna E.; Babcock, Gregory J.; Thomas, William D.; Thackray, Larissa B.; Young, Mark D.; Mason, Robert J.; Ambrosino, Donna M.; Wentworth, David E.; DeMartini, James C.; Holmes, Kathryn V.

    2004-01-01

    Angiotensin-converting enzyme 2 (ACE2) is a receptor for SARS-CoV, the novel coronavirus that causes severe acute respiratory syndrome [Li, W. Moore, M. J., Vasilieva, N., Sui, J., Wong, S. K., Berne, M. A., Somasundaran, M., Sullivan, J. L., Luzuriaga, K., Greenough, T. C., et al. (2003) Nature 426, 450–454]. We have identified a different human cellular glycoprotein that can serve as an alternative receptor for SARS-CoV. A human lung cDNA library in vesicular stomatitis virus G pseudotyped retrovirus was transduced into Chinese hamster ovary cells, and the cells were sorted for binding of soluble SARS-CoV spike (S) glycoproteins, S590 and S1180. Clones of transduced cells that bound SARS-CoV S glycoprotein were inoculated with SARS-CoV, and increases in subgenomic viral RNA from 1–16 h or more were detected by multiplex RT-PCR in four cloned cell lines. Sequencing of the human lung cDNA inserts showed that each of the cloned cell lines contained cDNA that encoded human CD209L, a C-type lectin (also called L-SIGN). When the cDNA encoding CD209L from clone 2.27 was cloned and transfected into Chinese hamster ovary cells, the cells expressed human CD209L glycoprotein and became susceptible to infection with SARS-CoV. Immunohistochemistry showed that CD209L is expressed in human lung in type II alveolar cells and endothelial cells, both potential targets for SARS-CoV. Several other enveloped viruses including Ebola and Sindbis also use CD209L as a portal of entry, and HIV and hepatitis C virus can bind to CD209L on cell membranes but do not use it to mediate virus entry. Our data suggest that the large S glycoprotein of SARS-CoV may use both ACE2 and CD209L in virus infection and pathogenesis. PMID:15496474

  4. Pharmacokinetics and bioequivalence of ranitidine and bismuth derived from two compound preparations

    Institute of Scientific and Technical Information of China (English)

    Quan Zhou; Zou-Rong Ruan; Hong Yuan; Bo Jiang; Dong-Hang Xu

    2006-01-01

    AIM: To evaluate the bioequivalence of ranitidine and bismuth derived from two compound preparations.METHODS: The bioavailability was measured in 20healthy male Chinese volunteers following a single oral dose (equivalent to 200 mg of ranitidine and 220 mg of bismuth) of the test or reference products in the fasting state. Then blood samples were collected for 24 h.Plasma concentrations of ranitidine and bismuth were analyzed by high-performance liquid chromatography and inductively coupled plasma-mass spectrometry (ICPMS), respectively. The non-compartmental method was used for pharmacokinetic analysis. Log-transformed Cmax,AUC(0-t) and AUC(0-∞) were tested for bioequivalence using ANOVA and Schuirmann two-one sided t-test. Tmax was analyzed by Wilcoxon's test.RESULTS: Various pharmacokinetic parameters of ranitidine derived from the two compound preparations,including Cmax, AUC(0-t), AUC(0-∞), Tmax and T1/2, were nearly consistent with previous observations. These parameters derived from test and reference drug were as follows: Cmax(0.67 ± 0.21 vs 0.68 ± 0.22mg/L), AUC(0-t)(3.1 ± 0.6 vs 3.0 ± 0.7 mg/L per hour),AUC(0-∞)(3.3 ± 0.6 vs 3.2 ± 0.8 mg/L per hour),Tmax (2.3 ± 0.9 vs 2.1 ± 0.9 h) and T1/2 (2.8 ± 0.3 vs 3.1± 0.4 h). In addition, double-peak absorption profiles of ranitidine were found in some Chinese volunteers.For bismuth, those parameters derived from test and reference drug were as follows: Cmax (11.80 ± 7.36 vs 11.40 ± 6.55 μg/L),AUC(0-t) (46.65 ± 16.97 vs 47.03 ±21.49 μg/L per hour), Tmax (0.50 ± 0.20 vs 0.50 ± 0.20 h)and T1/2 (10.2 ± 2.3 vs 13.0 ± 6.9 h). Ninety percent of confidence intervals for the test/reference ratio of Cmax,AUC(0-t) and AUC(0-∞) derived from both ranitidine and bismuth were found within the bioequivalence acceptable range of 80%-125%. No significant difference was found in Tmax derived from both ranitidine and bismuth.CONCLUSION: The two compound preparations are bioequivalent and may be prescribed

  5. Syntheses, crystal structures and characterizations of two new bismuth(III) arsenites

    Energy Technology Data Exchange (ETDEWEB)

    Liu Junhui [State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002 (China); Graduate School of the Chinese Academy of Sciences, Beijing 100039 (China); Kong Fang [State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002 (China); Gai Yanli [State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002 (China); Graduate School of the Chinese Academy of Sciences, Beijing 100039 (China); Mao Jianggao, E-mail: mjg@fjirsm.ac.cn [State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002 (China)

    2013-01-15

    Two new bismuth arsenites with two different structural types, namely, Bi{sub 2}O(AsO{sub 3})Cl (1), Bi{sub 8}O{sub 6}(AsO{sub 3}){sub 2}(AsO{sub 4}){sub 2} (2), have been synthesized by the solid-state reactions. Compound 1 exhibits novel 2D bismuth arsenite layers with Bi{sub 4}O{sub 4} rings capped by oxide anions, which are further interconnected by Bi-Cl-Bi bridges into a 3D network. Compound 2 contains both arsenite and arsenate anions, its 3D structures are based on 1D bismuth arsenite and 1D bismuth arsenate chains both along b-axis, which are interconnected by oxide anions via Bi-O-Bi bridges, forming 1D tunnels of Bi{sub 4}As{sub 4} 8-membered rings (MRs) along b-axis, the lone pairs of the arsenite groups are orientated toward the centers of the above tunnels. Thermogravimetric analysis indicated that both compounds display high thermal stability. Optical property measurements revealed that they are wide band-gap semiconductors. Both compounds display broad green-light emission bands centered at 506 nm under excitation at 380 and 388 nm. - Graphical abstract: Solid state reactions of Bi{sub 2}O{sub 3} (BiCl{sub 3}) and As{sub 2}O{sub 3} yielded two new compounds with two different structural types, namely, Bi{sub 2}O(AsO{sub 3})Cl (1), Bi{sub 8}O{sub 6}(AsO{sub 3}){sub 2}(AsO{sub 4}){sub 2} (2). They represent the first examples of bismuth arsenates. Highlights: Black-Right-Pointing-Pointer Solid state reactions of Bi{sub 2}O{sub 3} (BiCl{sub 3}) and As{sub 2}O{sub 3} yielded two new phases. Black-Right-Pointing-Pointer They represent the first examples of bismuth arsenites. Black-Right-Pointing-Pointer The two compounds exhibit two different structural types.

  6. Measurements of Neutron-Induced Fission Cross Sections of 205Tl, 204, 206, 207, 208Pb, and 209Bi using Quasi-Monoenergetic Neutrons in the Energy Range 35 - 174 MeV

    Science.gov (United States)

    Tutin, Gennady A.; Ryzhov, Igor V.; Eismont, Vilen P.; Mitryukhin, Andrey G.; Oplavin, Valery S.; Soloviev, Sergey M.; Blomgren, Jan; Condè, Henri; Olsson, Nils; Renberg, Per-Ulf

    2005-05-01

    Cross sections for neutron-induced fission of 205Tl, 204, 206, 207, 208Pb, and 209Bi were measured in the energy range from 35 MeV to 174 MeV. The experiments were done at the neutron beam facility of The Svedberg Laboratory, using a multi-section Frisch-gridded ionization chamber for detection of the fission fragments. The neutron-induced fission cross section of 238U was employed as a reference. The results of the measurements are compared with existing experimental data.

  7. Measurements of neutron-induced fission cross-sections of 205Tl, 204,206,207,208Pb and 209Bi with a multi-section Frisch-gridded ionization chamber

    Science.gov (United States)

    Ryzhov, I. V.; Tutin, G. A.; Mitryukhin, A. G.; Oplavin, V. S.; Soloviev, S. M.; Blomgren, J.; Renberg, P.-U.; Meulders, J. P.; El Masri, Y.; Keutgen, Th.; Prieels, R.; Nolte, R.

    2006-06-01

    Neutron-induced fission cross-sections of 205Tl, 204,206,207,208Pb and 209Bi have been measured in the energy range from 30 to 180 MeV. The measurements were performed with quasi-monoenergetic neutron beams using a multi-section Frisch-gridded ionization chamber. The neutron-induced fission cross-sections of 238U were used as reference data. The experimental techniques are described in detail as well as the data processing. The results are compared with existing experimental data.

  8. Measurements of neutron-induced fission cross-sections of 205Tl, 204,206,207,208Pb and 209Bi with a multi-section Frisch-gridded ionization chamber

    International Nuclear Information System (INIS)

    Neutron-induced fission cross-sections of 205Tl, 204,206,207,208Pb and 209Bi have been measured in the energy range from 30 to 180 MeV. The measurements were performed with quasi-monoenergetic neutron beams using a multi-section Frisch-gridded ionization chamber. The neutron-induced fission cross-sections of 238U were used as reference data. The experimental techniques are described in detail as well as the data processing. The results are compared with existing experimental data

  9. Synthesis and characterization of Bismuth ferrite (BiFeO{sub 3}) nanoparticles by solution evaporation method

    Energy Technology Data Exchange (ETDEWEB)

    Manzoor, A., E-mail: alinamanzoor@hotmail.com; Afzal, A.M., E-mail: amirafzal461@gmail.com; Umair, M., E-mail: umairranwerr@gmail.com; Ali, Adnan, E-mail: adnnan_1982@yahoo.com; Rizwan, M., E-mail: h.rizwan70@gmail.com; Yaqoob, M.Z., E-mail: zeeshaan32@yahoo.com

    2015-11-01

    Single phase Bismuth ferrite (BiFeO{sub 3}) with high magnetization and polarization was synthesized by solution evaporation method (SEM) at room temperature. The influence of temperature and size of nanoparticles on magnetic properties was studied. The prepared Bismuth ferrite (BiFeO{sub 3}) was characterized by X-ray diffraction (XRD) to investigate the structure and size of crystal. The average crystallite size of nanoparticles (NPs) as calculated by X-ray diffraction (XRD) falls in the range of 22–31 nm. The crystallite size of Bismuth ferrite increased as the temperature varied from 450 °C to 650 °C. Magnetic properties were studied by using physical properties measurement system (PPMS). It was also observed that the magnetic properties were directly related to the size and temperature of Bismuth ferrite nanoparticles. It has been investigated that the magnetization was decreased as the temperature and crystallite size increased. - Highlights: • Bismuth ferrite magnetic material was synthesized by solution evaporation method. • Bismuth ferrite shows ferromagnetic properties at room temperature. • Influence of temperature and crystallite size on magnetic properties was observed. • The magnetization was decreased as the temperature and crystallite size increased. • The magnetic moments were found larger in the smaller crystalline size.

  10. Characterization, Leaching, and Filtration Testing for Bismuth Phosphate Sludge (Group 1) and Bismuth Phosphate Saltcake (Group 2) Actual Waste Sample Composites

    Energy Technology Data Exchange (ETDEWEB)

    Lumetta, Gregg J.; Buck, Edgar C.; Daniel, Richard C.; Draper, Kathryn; Edwards, Matthew K.; Fiskum, Sandra K.; Hallen, Richard T.; Jagoda, Lynette K.; Jenson, Evan D.; Kozelisky, Anne E.; MacFarlan, Paul J.; Peterson, Reid A.; Shimskey, Rick W.; Sinkov, Sergey I.; Snow, Lanee A.

    2009-02-19

    A testing program evaluating actual tank waste was developed in response to Task 4 from the M-12 External Flowsheet Review Team (EFRT) issue response plan.() The test program was subdivided into logical increments. The bulk water-insoluble solid wastes that are anticipated to be delivered to the Waste Treatment and Immobilization Plant (WTP) were identified according to type such that the actual waste testing could be targeted to the relevant categories. Eight broad waste groupings were defined. Samples available from the 222S archive were identified and obtained for testing. The actual waste-testing program included homogenizing the samples by group, characterizing the solids and aqueous phases, and performing parametric leaching tests. Two of the eight defined groups—bismuth phosphate sludge (Group 1) and bismuth phosphate saltcake (Group 2)—are the subjects of this report. The Group 1 waste was anticipated to be high in phosphorus and was implicitly assumed to be present as BiPO4 (however, results presented here indicate that the phosphate in Group 1 is actually present as amorphous iron(III) phosphate). The Group 2 waste was also anticipated to be high in phosphorus, but because of the relatively low bismuth content and higher aluminum content, it was anticipated that the Group 2 waste would contain a mixture of gibbsite, sodium phosphate, and aluminum phosphate. Thus, the focus of the Group 1 testing was on determining the behavior of P removal during caustic leaching, and the focus of the Group 2 testing was on the removal of both P and Al. The waste-type definition, archived sample conditions, homogenization activities, characterization (physical, chemical, radioisotope, and crystal habit), and caustic leaching behavior as functions of time, temperature, and hydroxide concentration are discussed in this report. Testing was conducted according to TP-RPP-WTP-467.

  11. 25 CFR 20.209 - Can a tribe operating under a tribal redesign plan go back to operating under this part?

    Science.gov (United States)

    2010-04-01

    ... 25 Indians 1 2010-04-01 2010-04-01 false Can a tribe operating under a tribal redesign plan go back to operating under this part? 20.209 Section 20.209 Indians BUREAU OF INDIAN AFFAIRS, DEPARTMENT....209 Can a tribe operating under a tribal redesign plan go back to operating under this part? Yes,...

  12. Beam Instabilities

    CERN Document Server

    Rumolo, G

    2014-01-01

    When a beam propagates in an accelerator, it interacts with both the external fields and the self-generated electromagnetic fields. If the latter are strong enough, the interplay between them and a perturbation in the beam distribution function can lead to an enhancement of the initial perturbation, resulting in what we call a beam instability. This unstable motion can be controlled with a feedback system, if available, or it grows, causing beam degradation and loss. Beam instabilities in particle accelerators have been studied and analysed in detail since the late 1950s. The subject owes its relevance to the fact that the onset of instabilities usually determines the performance of an accelerator. Understanding and suppressing the underlying sources and mechanisms is therefore the key to overcoming intensity limitations, thereby pushing forward the performance reach of a machine.

  13. Synthesis of α-Bismuth oxide using solution combustion method and its photocatalytic properties

    Science.gov (United States)

    Astuti, Y.; Fauziyah, A.; Nurhayati, S.; Wulansari, A. D.; Andianingrum, R.; Hakim, A. R.; Bhaduri, G.

    2016-02-01

    The monoclinic bismuth oxide was prepared by the solution combustion method using bismuthyl nitrate as the raw material and citric acid as fuel. The synthesis process consisted of the formation of a clear transparent solution and the formation of white powder after heating the mixture at 250 °C for 2 hours. The yellow pale crystalline materials were obtained after calcination of the white powder at 600 °C for 80 minutes. Furthermore, the photocatalytic activity of the product was also studied using methyl orange as a model pollutant. The result showed that the coral reef-like bismuth oxide was able to degrade 50 mL methyl orange (5 ppm) by 37.8% within 12 hours irradiation using 75-watt tungsten lamp.

  14. Designing and operating experience on solid electrolyte activity meters for oxygen in lead-bismuth coolant

    International Nuclear Information System (INIS)

    The device for measuring the oxygen activity in the lead and bismuth meets within the range of 1-10-7 with the inertia up to 5 s is developed and tested on the basis of applying the ZrO2-Y2O3 solid-electrolytes in combination with the liquid-metal reference electrodes (Bi, In, Pb). The range of the working temperatures of the activity meter constitutes 280-600 deg C; the stability by thermoshocks up to 50 deg C/s is guaranteed. The device is recommended for application in the circulating systems with the lead and bismuth meets at the coolant pressures up to 60 atm

  15. Compatibility tests on steels in molten lead and lead-bismuth

    International Nuclear Information System (INIS)

    The compatibility of steels with liquid lead and liquid lead-bismuth is a critical issue for the development of accelerator-driven system (ADS). In this work the results of a set of preliminary tests carried out in stagnant molten lead at 737 K and in lead-bismuth at 573, 673 and 749 K are summarised. The tests were conducted for 700, 1200, 1500 and 5000 h. Three steels were tested: two martensitic steels (mod. F82H and MANET II) and one austenitic steel (AISI 316L). The martensitic steels underwent oxidation phenomena at the higher testing temperature, due to oxygen dissolved in the melts. At a lower test temperature (573 K) and higher exposure time (5000 h) the oxidation rate of the martensitic steel seems to be lower and the developed oxide layer protective against liquid metal corrosion. The austenitic steel, in turn, exhibited an acceptable resistance to corrosion-oxidation under the test conditions

  16. Elastic properties of bismuth layer-structure perovskite single crystals studied by brillouin scattering

    International Nuclear Information System (INIS)

    Elastic properties of bismuth layered perovskite compounds, LaxBi4-xTi3O12 (LBT-x) and SrBi2Ta2O9 (SBT), were examined at room temperature by Brillouin scattering. Elastic stiffness coefficients, c33 and c44, defined in the pseudotetragonal symmetry, were obtained. The longitudinal sound velocities propagating along the c axis, were 3985 m/s and 3118 m/s for the pure bismuth titanate (BTO) and SBT, respectively. The sound velocity of SBT is very slow and is believed to be related with the weak interlayer bonding of this layer-structure compound. A simple linear chain model showed that the difference in the sound velocity between BTO and SBT is mainly due to the difference in the c axis lattice constant. The sound velocity of LBT-x increased slightly with the increase of x, while c33 seems to be insensitive to x

  17. Recovery of IR luminescence in photobleached bismuth-doped fibers by thermal annealing

    Science.gov (United States)

    Firstov, S. V.; Firstova, E. G.; Alyshev, S. V.; Khopin, V. F.; Riumkin, K. E.; Melkumov, M. A.; Guryanov, A. N.; Dianov, E. M.

    2016-08-01

    The effect of annealing temperature on the luminescent properties of bismuth-doped fibers bleached by 532 nm laser radiation was investigated. The photoluminescence (PL) measurements were performed in pristine and photobleached samples which were thermally annealed at various temperatures ranging from 100 to 900 °C and slowly cooled. We observed that the intensity of the PL band at 1700 nm in the photobleached fibers recovered its pre-bleached level. Moreover, it was shown that a significant increase of the PL level could be achieved using the special annealing regime. Thereby, we obtained the experimental evidence of a thermally activated recovery process of the PL intensity showing that photoinduced changes of PL in bismuth-doped fibers are completely reversible. The mechanism of the thermal recovery of the PL is discussed.

  18. MYRRHA ADS DATABASE: Part I. Thermophysical properties of molten lead-bismuth eutectic. Version 1

    International Nuclear Information System (INIS)

    This report is an update of the internal SCK-CEN report IR-18 'Database of thermal properties for the melted lead-bismuth eutectic' issued in 2002. This compilation takes into account larger amount of original sources and, partially, the work performed in the framework of the preparation of a 'zero' version of the HLMC Handbook by the OECD/NEA Working Group on LBE Technology. An analysis is performed of the previous recommendations using some general physical laws and referencing to the properties of lead and bismuth. The updated and extended version of the molten LBE thermal properties database is developed and the correlations are proposed for the design calculations of ADS MYRRHA. (author)

  19. Graphite felt modified with bismuth nanoparticles as negative electrode in a vanadium redox flow battery.

    Science.gov (United States)

    Suárez, David J; González, Zoraida; Blanco, Clara; Granda, Marcos; Menéndez, Rosa; Santamaría, Ricardo

    2014-03-01

    A graphite felt decorated with bismuth nanoparticles was studied as negative electrode in a vanadium redox flow battery (VRFB). The results confirm the excellent electrochemical performance of the bismuth modified electrode in terms of the reversibility of the V(3+) /V(2+) redox reactions and its long-term cycling performance. Moreover a mechanism that explains the role that Bi nanoparticles play in the redox reactions in this negative half-cell is proposed. Bi nanoparticles favor the formation of BiHx , an intermediate that reduces V(3+) to V(2+) and, therefore, inhibits the competitive irreversible reaction of hydrogen formation (responsible for the commonly observed loss of Coulombic efficiency of VRFBs). Thus, the total charge consumed during the cathodic sweep in this electrode is used to reduce V(3+) to V(2+) , resulting in a highly reversible and efficient process. PMID:24520000

  20. Intercalation of pyridine and its derivatives into crystalline bismuth molybdenum hydrous oxide

    International Nuclear Information System (INIS)

    Bismuth molybdenum hydrous oxide was prepared by water-thermally direct precipitation in relatively concentrated solutions. The composition of the resulting product was Bi2Mo3O12 x 3.86 H2O determined by thermal analysis and ICP. The X-ray powder diffraction patterns of the crystal synthesized was identical with that of Bi2Mo3O12 x 4.75 H2O. Pyridine, 2,5-dimethylpyridine and 4-benzylpiridine were intercalated into inorganic crystal, significantly expanding interlayer distance along b axis in the monoclinic cell unit of bismuth molybdenum hydrous oxide. The organic molecules were intercalated by solvent exchange mechanism which mainly devoted to the expansion of interlayer spacing. (author)