WorldWideScience

Sample records for biomass fuel producers

  1. Hydropyrolysis of biomass to produce liquid hydrocarbon fuels. Final report. Biomass Alternative-Fuels Program

    Energy Technology Data Exchange (ETDEWEB)

    Fujita, R K; Bodle, W W; Yuen, P C

    1982-10-01

    The ojective of the study is to provide a process design and cost estimates for a biomass hydropyrolysis plant and to establish its economic viability for commercial applications. A plant site, size, product slate, and the most probable feedstock or combination of feedstocks were determined. A base case design was made by adapting IGT's HYFLEX process to Hawaiian biomass feedstocks. The HYFLEX process was developed by IGT to produce liquid and/or gaseous fuels from carbonaceous materials. The essence of the process is the simultaneous extraction of valuable oil and gaseous products from cellulosic biomass feedstocks without forming a heavy hard-to-handle tar. By controlling rection time and temperature, the product slate can be varied according to feedstock and market demand. An optimum design and a final assessment of the applicability of the HYFLEX process to the conversion of Hawaiian biomass was made. In order to determine what feedstocks could be available in Hawaii to meet the demands of the proposed hydropyrolysis plant, various biomass sources were studied. These included sugarcane and pineapple wastes, indigenous and cultivated trees and indigenous and cultivated shrubs and grasses.

  2. Chemical comparisons of liquid fuel produced by thermochemical liquefaction of various biomass materials

    Energy Technology Data Exchange (ETDEWEB)

    Russell, J.A.; Molton, P.M.; Landsman, S.D.

    1980-12-01

    Liquefaction of biomass in aqueous alkali at temperatures up to 350/sup 0/C is an effective way to convert solid wastes into liquid fuels. The liqefaction oils of several forms of biomass differing in proportions of cellulose, hemi-cellulose, lignin, protein, and minerals were studied and their chemical composition compared. It was that the proportions of chemical components varied considerably depending on the type of biomass liquefied. However, all the oils, even those produced from cellulose, had similar chemical characteristics due to the presence of significant quantities of phenols. These phenols are at least partially responsible for the corrosivity and viscosity commonly associated with biomass oils. The differences in chemical component distribution in the various biomass oils might successfully be exploited if the oil is to be used as a chemical feedstock. If the oil is to be used as a fuel, however, then reaction conditions will be a more important consideration than the source of biomass.

  3. Characterized hydrochar of algal biomass for producing solid fuel through hydrothermal carbonization.

    Science.gov (United States)

    Park, Ki Young; Lee, Kwanyong; Kim, Daegi

    2018-06-01

    The aim of this work was to study the characterized hydrochar of algal biomass to produce solid fuel though hydrothermal carbonization. Hydrothermal carbonization conducted at temperatures ranging from 180 to 270 °C with a 60 min reaction improved the upgrading of the fuel properties and the dewatering of wet-basis biomasses such as algae. The carbon content, carbon recovery, energy recovery, and atomic C/O and C/H ratios in all the hydrochars in this study were improved. These characteristic changes in hydrochar from algal biomass are similar to the coalification reactions due to dehydration and decarboxylation with an increase in the hydrothermal reaction temperature. The results of this study indicate that hydrothermal carbonization can be used as an effective means of generating highly energy-efficient renewable fuel resources using algal biomass. Copyright © 2018 Elsevier Ltd. All rights reserved.

  4. Characterization of biomass producer gas as fuel for stationary gas engines in combined heat and power production

    DEFF Research Database (Denmark)

    Ahrenfeldt, Jesper

    2008-01-01

    The aim of this project has been the characterization of biomass producer gas as a fuel for stationary gas engines in heat and power production. More than 3200 hours of gas engine operation, with producer gas as fuel, has been conducted at the biomass gasification combined heat and power (CHP...... from 50% to 90% load. Biomass producer gas is an excellent lean burn engine fuel: Operation of a natural aspirated engine has been achieved for 1.2...

  5. The market for fuel pellets produced from biomass and waste in the Netherlands

    International Nuclear Information System (INIS)

    Koppejan, J.; Meulman, P.D.M.

    2001-12-01

    Several initiatives are currently being developed in the Netherlands for the production of fuel pellets from waste and biomass. This report presents an overview of the current producers and (potential) users of these pellets in the Netherlands. It also outlines the Dutch and European policies and legislations concerned. Furthermore, important barriers to market development of fuel pellets are defined and future expectations are summarized. The study covers fuel pellets made from different feedstock, varying from clean biomass to waste with traces of contaminants. In each project, pellets are produced that are unique as to their product specifications, as they are usually designed for a single application. It is therefore impossible to generalize characteristics and end use. 27 refs

  6. Experimental investigation of solid oxide fuel cells using biomass gasification producer gases

    Energy Technology Data Exchange (ETDEWEB)

    Norheim, Arnstein

    2005-07-01

    The main objective of this thesis is theoretical and experimental investigations related to utilisation of biomass gasification producer gases as fuel for Solid Oxide Fuel Cells (SOFC). Initial fundamental steps towards a future system of combined heat and power production based on biomass gasification and SOFC are performed and include: 1) Theoretical modeling of the composition of biomass gasification producer gases. 2) Experimental investigation of SOFC performance using biomass gasification producer gas as fuel. 3) Experimental investigation of SOFC performance using biomass gasification producer gas containing high sulphur concentration. The modeling of the composition of gasifier producer gas was performed using the program FactSage. The main objective was to investigate the amount and speciation of trace species in the producer gases as several parameters were varied. Thus, the composition at thermodynamic equilibrium of sulphur, chlorine, potassium, sodium and compounds of these were established. This was done for varying content of the trace species in the biomass material at different temperatures and fuel utilisation i.e. varying oxygen content in the producer gas. The temperature interval investigated was in the range of normal SOFC operation. It was found that sulphur is expected to be found as H2S irrespective of temperature and amount of sulphur. Only at very high fuel utilisation some S02 is formed. Important potassium containing compounds in the gas are gaseous KOH and K. When chlorine is present, the amount of KOH and K will decrease due to the formation of KCI. The level of sodium investigated here was low, but some Na, NaOH and NaCl is expected to be formed. Below a certain temperature, condensation of alkali rich carbonates may occur. The temperature at which condensation begins is mainly depending on the amount of potassium present; the condensation temperature increases with increasing potassium content. In the first experimental work

  7. Biotechnology for producing fuels and chemicals from biomass. Volume II. Fermentation chemicals from biomass

    Energy Technology Data Exchange (ETDEWEB)

    Villet, R. (ed.)

    1981-02-01

    The technological and economic feasibility of producing some selected chemicals by fermentation is discussed: acetone, butanol, acetic acid, citric acid, 2,3-butanediol, and propionic acid. The demand for acetone and butanol has grown considerably. They have not been produced fermentatively for three decades, but instead by the oxo and aldol processes. Improved cost of fermentative production will hinge on improving yields and using cellulosic feedstocks. The market for acetic acid is likely to grow 5% to 7%/yr. A potential process for production is the fermentation of hydrolyzed cellulosic material to ethanol followed by chemical conversion to acetic acid. For about 50 years fermentation has been the chief process for citric acid production. The feedstock cost is 15% to 20% of the overall cost of production. The anticipated 5%/yr growth in demand for citric acid could be enhanced by using it to displace phosphates in detergent manufacture. A number of useful chemicals can be derived from 2,3-butanediol, which has not been produced commercially on a large scale. R and D are needed to establish a viable commercial process. The commercial fermentative production of propionic acid has not yet been developed. Recovery and purification of the product require considerable improvement. Other chemicals such as lactic acid, isopropanol, maleic anhydride, fumarate, and glycerol merit evaluation for commercial fermentative production in the near future.

  8. Producer gas production of Indonesian biomass in fixed-bed downdraft gasifier as an alternative fuels for internal combustion engines

    Science.gov (United States)

    Simanjuntak, J. P.; Lisyanto; Daryanto, E.; Tambunan, B. H.

    2018-03-01

    downdraft biomass gasification reactors, coupled with reciprocating internal combustion engines (ICE) are a viable technology for small scale heat and power generation. The direct use of producer gas as fuel subtitution in an ICE could be of great interest since Indonesia has significant land area in different forest types that could be used to produce bioenergy and convert forest materials to bioenergy for use in energy production and the versatility of this engine. This paper will look into the aspect of biomass energie as a contributor to energy mix in Indonesia. This work also contains information gathered from numerous previews study on the downdraft gasifier based on experimental or simulation study on the ability of producer gas as fuels for internal combustion engines aplication. All data will be used to complement the preliminary work on biomass gasification using downdraft to produce producer gas and its application to engines.

  9. Feasibility of Producing and Using Biomass-Based Diesel and Jet Fuel in the United States

    Energy Technology Data Exchange (ETDEWEB)

    Milbrandt, A. [National Renewable Energy Lab. (NREL), Golden, CO (United States); Kinchin, C. [National Renewable Energy Lab. (NREL), Golden, CO (United States); McCormick, R. [National Renewable Energy Lab. (NREL), Golden, CO (United States)

    2013-12-01

    The study summarizes the best available public data on the production, capacity, cost, market demand, and feedstock availability for the production of biomass-based diesel and jet fuel. It includes an overview of the current conversion processes and current state-of-development for the production of biomass-based jet and diesel fuel, as well as the key companies pursuing this effort. Thediscussion analyzes all this information in the context of meeting the RFS mandate, highlights uncertainties for the future industry development, and key business opportunities.

  10. Syngas suitability for solid oxide fuel cells applications produced via biomass steam gasification process: Experimental and modeling analysis

    Science.gov (United States)

    Pieratti, Elisa; Baratieri, Marco; Ceschini, Sergio; Tognana, Lorenzo; Baggio, Paolo

    The technologies and the processes for the use of biomass as an energy source are not always environmental friendly. It is worth to develop approaches aimed at a more sustainable exploitation of biomass, avoiding whenever possible direct combustion and rather pursuing fuel upgrade paths, also considering direct conversion to electricity through fuel cells. In this context, it is of particular interest the development of the biomass gasification technology for synthesis gas (i.e., syngas) production, and the utilization of the obtained gas in fuel cells systems, in order to generate energy from renewable resources. Among the different kind of fuel cells, SOFCs (solid oxide fuel cells), which can be fed with different type of fuels, seem to be also suitable for this type of gaseous fuel. In this work, the syngas composition produced by means of a continuous biomass steam gasifier (fixed bed) has been characterized. The hydrogen concentration in the syngas is around 60%. The system is equipped with a catalytic filter for syngas purification and some preliminary tests coupling the system with a SOFCs stack are shown. The data on the syngas composition and temperature profile measured during the experimental activity have been used to calibrate a 2-dimensional thermodynamic equilibrium model.

  11. Development of a pressurized fluidized-bed biomass gsifier to produce substitute fuels

    Science.gov (United States)

    Babu, S. P.; Onischak, M.; Kosowski, G.

    The Institute of Gas technology (IGT) is conducting a program to convert forest and crop residues to substitute fuel in a pressurized fluidized-bed biomass gasifier. The process is designed for operation at pressures up to 2.17 MPa (315 psia) and temperatures up to 1255 K (1800 F). Various goals for synthesis or fuel gas processes are being pursued to develop an efficient process. Some of these goals are to maximize the throughput, the amount, and the quality of the gas, while minimizing both the amount of the feedstock preparation needed and the formation of condensible compounds that require by-product disposal and process wastewater treatment. The process development results obtained from fluidization biomass devolatilization, and char gasification studies were used to design a 30/5-cm (12-inch) ID adiabatic fluidized-bed gasification process development unit (PDU), capable of handling up to 455 kg (1000 lb) of biomass per hour.

  12. Combustion Chamber Deposits and PAH Formation in SI Engines Fueled by Producer Gas from Biomass Gasification

    DEFF Research Database (Denmark)

    Ahrenfeldt, Jesper; Henriksen, Ulrik Birk; Schramm, Jesper

    2003-01-01

    Investigations were made concerning the formation of combustion chamber deposits (CCD) in SI gas engines fueled by producer gas. The main objective was to determine and characterise CCD and PAH formation caused by the presence of the light tar compounds phenol and guaiacol in producer gas from...... showed that guaiacol formed significant amount of deposits. The structure observed was a lacquer type of deposit. It was determined that there was no distinct deposit formation due to phenol. Experiments were conducted with a 0.48 litre one-cylinder high compression ratio SI engine fueled by synthetic...... producer gas. Known quantities of tar compounds were added to the fuel gas and the CCD were examined. The experiments showed significant formation of deposits when guaiacol was added to the fuel, whereas for phenol only minor CCD formation was observed. Particulate matter in the exhaust gas was sampled...

  13. Performance evaluation of premixed burner fueled with biomass derived producer gas

    OpenAIRE

    Punnarapong, P.; Sucharitakul, T.; Tippayawong, N.

    2017-01-01

    Energy consumption of liquefied petroleum gas (LPG) in ceramic firing process accounts for about 15–40% of production cost. Biomass derived producer gas may be used to replace LPG. In this work, a premixed burner originally designed for LPG was modified for producer gas. Its thermal performance in terms of axial and radial flame temperature distribution, thermal efficiency and emissions was investigated. The experiment was conducted at various gas production rates with equivalence ratios betw...

  14. Combustion Chamber Deposits and PAH Formation in SI Engines Fueled by Producer Gas from Biomass Gasification

    DEFF Research Database (Denmark)

    Ahrenfeldt, Jesper; Henriksen, Ulrik Birk; Schramm, Jesper

    2003-01-01

    Investigations were made concerning the formation of combustion chamber deposits (CCD) in SI gas engines fueled by producer gas. The main objective was to determine and characterise CCD and PAH formation caused by the presence of the light tar compounds phenol and guaiacol in producer gas from an...

  15. Assesment of the energy quality of the synthesis gas produced from biomass derived fuels conversion: Part I: Liquid Fuels, Ethanol

    International Nuclear Information System (INIS)

    Arteaga Perez, Luis E; Casas, Yannay; Peralta, Luis M; Granda, Daikenel; Prieto, Julio O

    2011-01-01

    The use of biofuels plays an important role to increase the efficiency and energetic safety of the energy processes in the world. The main goal of the present research is to study from the thermodynamics and kinetics the effect of the operational variables on the thermo-conversion processes of biomass derived fuels focused on ethanol reforming. Several models are developed to assess the technological proposals. The minimization of Gibbs free energy is the criterion applied to evaluate the performance of the different alternatives considering the equilibrium constraints. All the models where validated on an experimental data base. The gas composition, HHV and the ratio H2/CO are used as measures for the process efficiency. The operational parameters are studied in a wide range (reactants molar ratio, temperature and oxygen/fuel ratio). (author)

  16. Catalytic hydrotreating of biomass liquefaction products to produce hydrocarbon fuels: Interim report

    Energy Technology Data Exchange (ETDEWEB)

    Elliott, D.C.; Baker, E.G.

    1986-03-01

    Research catalytic hydrotreatment of biomass liquefaction products to a gasoline has been technically demonstrated in a bench-scale continuous processing unit. This report describes the development of the chemistry needed for hydrotreatment of both high pressure and pyrolyzate biomass liquefaction products and outlines the important processing knowledge gained by the research. Catalyst identity is important in hydrotreatment of phenolics. Hydrogenation catalysts such as palladium, copper chromite, cobalt and nickel show activity with nickel being the most active. Major products include benzene, cyclohexane, and cyclohexanone. The hydrotreating catalysts cobalt-molybdenum, nickel-molybdenum and nickel-tungsten exhibit some activity when added to the reactor in the oxide form and show a great specificity for hydrodeoxygenation of phenol without saturation of the benzene product. The sulfide form of these catalysts is much more active than the oxide form and, in the case of the cobalt-molybdenum, much of the specificity for hydrodeoxygenation is retained. Substitution on the phenolic ring has only marginal effects on the hydrotreating reaction. However, the methoxy (OCH/sub 3/) substituent on the phenol ring is thermally unstable relative to other phenolics tested. The pyrolysis products dominate the product distribution when cobalt-molybdenum is used as the hydrotreating catalyst for methoxyphenol. The product from catalytic hydrotreatment of high-pressure biomass liquefaction products confirms the model compounds studies. Catalytic processing at 350 to 400/sup 0/C and 2000 psig with the sulfided cobalt-molybdenum or nickel-molybdenum catalyst produced a gasoline-like product composed of cyclic and aromatic compounds. Oxygen contents in products were in the range of 0 to 0.7 wt % and hydrogen to carbon atomic ratios ranged from 1.5 to 2.0. 46 refs., 10 figs., 21 tabs.

  17. Biotechnology for producing fuels and chemicals from biomass: recommendations for R and D. Volume I. Synopsis and executive summary

    Energy Technology Data Exchange (ETDEWEB)

    Villet, R

    1979-12-01

    Areas of research and development judged to be crucial for establishing a biotechnology of biomass processing are identified. Two general avenues are recommended for R and D: (1) in the near term, revival of the older fermentation technology and improvement of processing efficiencies; and (2) in the longer term, the development of novel biotechnological processes, such as for the conversion of lignocellulosic biomass to fuels and chemicals. Recommended R and D ranges from work in moleular genetics to biochemical engineering aspects of plant design. It is recommended that the R and D strategy be designed as an integration of three disciplines: biochemical engineering, microbial genetics, and biochemistry. Applcations of gene-transfer methodology and developments in continuous fermentation should be pursued. Currently, economic incentive for the use of biological conversion processes for producing fuels and chemical feedstocks from biomass is marginal. But as the imported fraction of US oil supply grows and hydrocarbon costs mount, the market is beginning to motivate a quest for substitutes. The commercial potential for biotechnology for establishing a renewable resources chemicals industry appears similar to the potential of the computer and microelectronics field several decades ago.

  18. Performance evaluation of premixed burner fueled with biomass derived producer gas

    Directory of Open Access Journals (Sweden)

    P. Punnarapong

    2017-03-01

    Full Text Available Energy consumption of liquefied petroleum gas (LPG in ceramic firing process accounts for about 15–40% of production cost. Biomass derived producer gas may be used to replace LPG. In this work, a premixed burner originally designed for LPG was modified for producer gas. Its thermal performance in terms of axial and radial flame temperature distribution, thermal efficiency and emissions was investigated. The experiment was conducted at various gas production rates with equivalence ratios between 0.8 and 1.2. Flame temperatures of over 1200 °C can be achieved, with maximum value of 1260 °C. It was also shown that the burner can be operated at 30.5–39.4 kWth with thermal efficiency in the range of 84 – 91%. The maximum efficiency of this burner was obtained at producer gas flow rate of 24.3 Nm3/h and equivalence ratio of 0.84.

  19. Soybean biomass produced in Argentina

    DEFF Research Database (Denmark)

    Semino, Stella Maris; Paul, Helena; Tomei, Julia

    2009-01-01

    Soybean biomass for biodiesel, produced in Argentina amongst other places, is considered by some to reduce greenhouse gas emissions and mitigate climate change when compared with fossil fuel. To ensure that the production of biofuels is ‘sustainable', EU institutions and national governments are ...... for environmental sustainability. This is exemplified by soy, whose cultivation undermines the climate benefit claimed for soy-based biodiesel. This paper concludes that to certify soy monocultures as sustainable would exacerbate existing climatic and environmental problems....

  20. Evaluation of Biomass Gasification to Produce Reburning Fuel for Coal-Fired Boilers

    Science.gov (United States)

    Gasification and reburning testing with biomass and other wastes is of interest to both the U.S. EPA and the Italian Ministry of the Environment & Territory. Gasification systems that use biofuels or wastes as feedstock can provide a clean, efficient source of synthesis gas and p...

  1. Market dynamics of biomass fuel in California

    International Nuclear Information System (INIS)

    Delaney, W.F.; Zane, G.A.

    1991-01-01

    The California market for biomass fuel purchased by independent power producers has grown substantially since 1980. The PURPA legislation that based power purchase rates upon the 'avoided cost' of public utilities resulted in construction of nearly 900 Megawatts of capacity coming online by 1991. Until 1987, most powerplants were co-sited at sawmills and burned sawmill residue. By 1990 the installed capacity of stand-alone powerplants exceeded the capacity co-sited at wood products industry facilities. The 1991 demand for biomass fuel is estimated as 6,400,000 BDT. The 1991 market value of most biomass fuel delivered to powerplants is from $34 to $47 per BDT. Biomass fuel is now obtained from forest chips, agriculture residue and urban wood waste. The proportion of biomass fuel from the wood products industry is expected to decline and non-traditional fuels are expected to increase in availability

  2. Method for producing bio-fuel that integrates heat from carbon-carbon bond-forming reactions to drive biomass gasification reactions

    Science.gov (United States)

    Cortright, Randy D [Madison, WI; Dumesic, James A [Verona, WI

    2011-01-18

    A low-temperature catalytic process for converting biomass (preferably glycerol recovered from the fabrication of bio-diesel) to synthesis gas (i.e., H.sub.2/CO gas mixture) in an endothermic gasification reaction is described. The synthesis gas is used in exothermic carbon-carbon bond-forming reactions, such as Fischer-Tropsch, methanol, or dimethylether syntheses. The heat from the exothermic carbon-carbon bond-forming reaction is integrated with the endothermic gasification reaction, thus providing an energy-efficient route for producing fuels and chemicals from renewable biomass resources.

  3. Automotive fuels from biomass via gasification

    International Nuclear Information System (INIS)

    Zhang, Wennan

    2010-01-01

    There exists already a market of bio-automotive fuels i.e. bioethanol and biodiesel produced from food crops in many countries. From the viewpoint of economics, environment, land use, water use and chemical fertilizer use, however, there is a strong preference for the use of woody biomass and various forest/agricultural residues as the feedstock. Thus, the production of 2nd generation of bio-automotive fuels i.e. synthetic fuels such as methanol, ethanol, DME, FT-diesel, SNG and hydrogen through biomass gasification seems promising. The technology of producing synthetic fuels is well established based on fossil fuels. For biomass, however, it is fairly new and the technology is under development. Starting from the present market of the 1st generation bio-automotive fuels, this paper is trying to review the technology development of the 2nd generation bio-automotive fuels from syngas platform. The production of syngas is emphasized which suggests appropriate gasifier design for a high quality syngas production. A number of bio-automotive fuel demonstration plant will be presented, which gives the state of the art in the development of BTS (biomass to synthetic fuels) technologies. It can be concluded that the 2nd generation bio-automotive fuels are on the way to a breakthrough in the transport markets of industrial countries especially for those countries with a strong forest industry. (author)

  4. The opportunities for woody biomass fuels in New Zealand produced in association with land disposal of effluent

    International Nuclear Information System (INIS)

    Sims, R.E.H.; Collins, C.

    1993-01-01

    An assessment of the future New Zealand biomass resource has shown exotic forest arisings could supply 970 GWh/year by the year 2002; wood processing residues 280 GWh/year; and fuelwood plantations 2,060 GWh/year with potential to rise to 10,000 GWh/year by 2012. Currently annual electricity demand is around 30,000 GWh 70% of which is generated by hydro power. A further 25% stems from natural gas, a resource with estimated reserves of only approximately 14 years. This paper describes how part replacement of gas by biomass could be a feasible proposition for the future. Life cycle cost analyses showed electricity could be generated from arisings for 4.8--6 c/kWh; from residues for 2.4--4.8 c/kWh; and from plantations for 4.8--7.2 c/kWh. For comparison the current retail electricity price is around 4--5.5 c/kWh and estimates for wind power generation range from 5--10 c/kWh. Future hydro-power schemes will generate power between 4--9 c/kWh depending on site suitability. The link between land disposal of effluent and short rotation coppice production can reduce the biomass costs. A meatworks processing 1.6 million sheep annually has planted 90 ha in trees for flood irrigation of effluent and biomass fuel production for use on site. Similar schemes linking sewage disposal with wood-fired power generation are under evaluation

  5. Biomass as a modern fuel

    International Nuclear Information System (INIS)

    Hall, D.O.; House, J.

    1994-01-01

    Case studies are presented for several developed and developing countries. Constraints involved in modernising biomass energy and the potential for turning them into entrepreneurial opportunities are discussed. It is concluded that the long term impacts of biomass programmes and projects depend mainly on ensuring sustainability, flexibility and replicability while taking account of local conditions and providing multiple benefits. Implementation of biomass projects requires governmental policy initiatives that will internalise the external economic, social and environmental costs of conventional fuel sources so that biomass fuels can become competitive on a ''level playing field''. Policies are also required to encourage R and D and commercialisation of biomass energy programs in close co-ordination with the private sector. (author)

  6. Production of chemicals and fuels from biomass

    Science.gov (United States)

    Qiao, Ming; Woods, Elizabeth; Myren, Paul; Cortright, Randy; Kania, John

    2018-01-23

    Methods, reactor systems, and catalysts are provided for converting in a continuous process biomass to fuels and chemicals, including methods of converting the water insoluble components of biomass, such as hemicellulose, cellulose and lignin, to volatile C.sub.2+O.sub.1-2 oxygenates, such as alcohols, ketones, cyclic ethers, esters, carboxylic acids, aldehydes, and mixtures thereof. In certain applications, the volatile C.sub.2+O.sub.1-2 oxygenates can be collected and used as a final chemical product, or used in downstream processes to produce liquid fuels, chemicals and other products.

  7. A productivity and cost comparison of two systems for producing biomass fuel from roadside forest treatment residues

    Science.gov (United States)

    Nathaniel Anderson; Woodam Chung; Dan Loeffler; John Greg Jones

    2012-01-01

    Forest operations generate large quantities of forest biomass residues that can be used for production of bioenergy and bioproducts. However, a significant portion of recoverable residues are inaccessible to large chip vans, making use financially infeasible. New production systems must be developed to increase productivity and reduce costs to facilitate use of these...

  8. Combining protein extraction and anaerobic digestion to produce feed, fuel and fertilizer from green biomass – An organic biorefinery concept

    DEFF Research Database (Denmark)

    Fernandez, Maria Santamaria; Salces, Beatriz Molinuevo; Lübeck, Mette

    Organically grown green biomass (red clover, clover grass) was investigated as a resource for organic feed and organic fertilizer by combination of proteins extraction and anaerobic digestion of the residues. Extraction of proteins from both crops revealed very favourable amino acid composition...

  9. Agricultural policies and biomass fuels

    Science.gov (United States)

    Flaim, S.; Hertzmark, D.

    The potentials for biomass energy derived from agricultural products are examined. The production of energy feedstocks from grains is discussed for the example of ethanol production from grain, with consideration given to the beverage process and the wet milling process for obtaining fuel ethanol from grains and sugars, the nonfeedstock costs and energy requirements for ethanol production, the potential net energy gain from ethanol fermentation, the effect of ethanol fuel production on supplies of protein, oils and feed and of ethanol coproducts, net ethanol costs, and alternatives to corn as an ethanol feedstock. Biomass fuel production from crop residues is then considered; the constraints of soil fertility on crop residue removal for energy production are reviewed, residue yields with conventional practices and with reduced tillage are determined, technologies for the direct conversion of cellulose to ethanol and methanol are described, and potential markets for the products of these processes are identified. Implications for agricultural policy of ethanol production from grain and fuel and chemical production from crop residues are also discussed.

  10. Biomass conversion processes for energy and fuels

    Science.gov (United States)

    Sofer, S. S.; Zaborsky, O. R.

    The book treats biomass sources, promising processes for the conversion of biomass into energy and fuels, and the technical and economic considerations in biomass conversion. Sources of biomass examined include crop residues and municipal, animal and industrial wastes, agricultural and forestry residues, aquatic biomass, marine biomass and silvicultural energy farms. Processes for biomass energy and fuel conversion by direct combustion (the Andco-Torrax system), thermochemical conversion (flash pyrolysis, carboxylolysis, pyrolysis, Purox process, gasification and syngas recycling) and biochemical conversion (anaerobic digestion, methanogenesis and ethanol fermentation) are discussed, and mass and energy balances are presented for each system.

  11. CO Emissions from Gas Engines Operating on Biomass Producer Gas

    DEFF Research Database (Denmark)

    Ahrenfeldt, Jesper; Jensen, T. K.; Henriksen, Ulrik Birk

    2004-01-01

    the emissions exceed the regulated limit significantly. The high CO emissions are mainly due to the high content of CO in the fuel and can ¿ in origin ¿ be compared with the emission of unburned hydrocarbons (UHC) from natural gas engines, thus CO emissions from producer gas engines are a measure of fuel......High carbon monoxide (CO) emission from gas engines fueled by producer gas is a concerning problem in the struggle to make biomass gasification for heat and power production a success. CO emissions from engines operating on biomass producer gases are high, especially at very lean conditions where...... passing unburned through the combustion. Measurements of the slip of the producer gas fuel components CO and CH4 showed that these are of similar order. When the environmental effect of the emissions is discussed, unburned hydrocarbons in the form of methane is a strong greenhouse gas (21 times higher...

  12. PRODUCTION OF NEW BIOMASS/WASTE-CONTAINING SOLID FUELS

    Energy Technology Data Exchange (ETDEWEB)

    David J. Akers; Glenn A. Shirey; Zalman Zitron; Charles Q. Maney

    2001-04-20

    CQ Inc. and its team members (ALSTOM Power Inc., Bliss Industries, McFadden Machine Company, and industry advisors from coal-burning utilities, equipment manufacturers, and the pellet fuels industry) addressed the objectives of the Department of Energy and industry to produce economical, new solid fuels from coal, biomass, and waste materials that reduce emissions from coal-fired boilers. This project builds on the team's commercial experience in composite fuels for energy production. The electric utility industry is interested in the use of biomass and wastes as fuel to reduce both emissions and fuel costs. In addition to these benefits, utilities also recognize the business advantage of consuming the waste byproducts of customers both to retain customers and to improve the public image of the industry. Unfortunately, biomass and waste byproducts can be troublesome fuels because of low bulk density, high moisture content, variable composition, handling and feeding problems, and inadequate information about combustion and emissions characteristics. Current methods of co-firing biomass and wastes either use a separate fuel receiving, storage, and boiler feed system, or mass burn the biomass by simply mixing it with coal on the storage pile. For biomass or biomass-containing composite fuels to be extensively used in the U.S., especially in the steam market, a lower cost method of producing these fuels must be developed that includes both moisture reduction and pelletization or agglomeration for necessary fuel density and ease of handling. Further, this method of fuel production must be applicable to a variety of combinations of biomass, wastes, and coal; economically competitive with current fuels; and provide environmental benefits compared with coal. Notable accomplishments from the work performed in Phase I of this project include the development of three standard fuel formulations from mixtures of coal fines, biomass, and waste materials that can be used in

  13. Biomass as a fuel: Advantages, limitations and possibilities

    International Nuclear Information System (INIS)

    McBurney, B.

    1997-01-01

    This presentation briefly outlines major issues related to the use of biomass fuels. Advantages and disadvantages of biomass fuels are identified, as well as major factors that may facilitate greater use of biomass fuels. Highlights of the US DOE Biomass Power Program, program activities, and demonstration projects are presented. Some statistical and economic data are provided, including biomass fueled electric capacity, biomass energy consumption by sector, and fuel cost savings and greenhouse gas emissions reductions for four biomass co-fired units

  14. Green energy. Biomass fuels and the environment

    International Nuclear Information System (INIS)

    1991-01-01

    The United Nations Environment Programme has been concerned with energy/environment issues since it was first set up after the United Nations Conference on the Human Environment held in Stockholm in 1972. In the late 1970s, UNEP compiled three comprehensive reports on the the environmental impacts of the production and use of fossil fuels, nuclear energy and renewable energy sources. In 1987 it was decided to update the volume on renewable energy since knowledge of biofuels and their effects on the environment had greatly improved. Among many innovations, Brazil's decision to embark on a major, and now successful, programme to produce ethanol from sugarcane as a substitute vehicle fuel is one of the most significant. At the same time, energy tree crops, agroforestry systems and the use of plantations for environmental improvement have become issues of key importance to sustainable development in developing countries. Biomass fuels, of course, have always been important in terms of the numbers of people who use them; the significant change during the 1980s was that the potential advantages of these fuels took on a new significance in the light of environmental degradation and related issues such as greenhouse warming. The biomass fuels began to be considered as attractive energy sources in their own right - not simply as 'last resort' fuels for developing countries with only limited energy options. While this development may solve some environmental problems, it certainly raises others - the improper utilization of biomass fuels in the past has been responsible for deforestation, desertification and the ill health of many millions of the women in developing countries who use biomass fuels in unventilated huts. These issues currently affect about half of the world population. The new UNEP study was intended to provide an up-to-date evaluation of the environmental issues raised by the use of biomass fuels, and hence to reduce or eliminate their adverse impacts while

  15. Current Challenges in Commercially Producing Biofuels from Lignocellulosic Biomass

    Science.gov (United States)

    Balan, Venkatesh

    2014-01-01

    Biofuels that are produced from biobased materials are a good alternative to petroleum based fuels. They offer several benefits to society and the environment. Producing second generation biofuels is even more challenging than producing first generation biofuels due the complexity of the biomass and issues related to producing, harvesting, and transporting less dense biomass to centralized biorefineries. In addition to this logistic challenge, other challenges with respect to processing steps in converting biomass to liquid transportation fuel like pretreatment, hydrolysis, microbial fermentation, and fuel separation still exist and are discussed in this review. The possible coproducts that could be produced in the biorefinery and their importance to reduce the processing cost of biofuel are discussed. About $1 billion was spent in the year 2012 by the government agencies in US to meet the mandate to replace 30% existing liquid transportation fuels by 2022 which is 36 billion gallons/year. Other countries in the world have set their own targets to replace petroleum fuel by biofuels. Because of the challenges listed in this review and lack of government policies to create the demand for biofuels, it may take more time for the lignocellulosic biofuels to hit the market place than previously projected. PMID:25937989

  16. Direct production of fractionated and upgraded hydrocarbon fuels from biomass

    Science.gov (United States)

    Felix, Larry G.; Linck, Martin B.; Marker, Terry L.; Roberts, Michael J.

    2014-08-26

    Multistage processing of biomass to produce at least two separate fungible fuel streams, one dominated by gasoline boiling-point range liquids and the other by diesel boiling-point range liquids. The processing involves hydrotreating the biomass to produce a hydrotreatment product including a deoxygenated hydrocarbon product of gasoline and diesel boiling materials, followed by separating each of the gasoline and diesel boiling materials from the hydrotreatment product and each other.

  17. Fixed bed gasification of solid biomass fuels

    Energy Technology Data Exchange (ETDEWEB)

    Haavisto, I. [Condens Oy, Haemeenlinna (Finland)

    1996-12-31

    Fixed bed biomass gasifiers are feasible in the effect range of 100 kW -10 MW. Co-current gasification is available only up to 1 MW for technical reasons. Counter-current gasifiers have been used in Finland and Sweden for 10 years in gasification heating plants, which are a combination of a gasifier and an oil boiler. The plants have proved to have a wide control range, flexible and uncomplicated unmanned operation and an excellent reliability. Counter-current gasifiers can be applied for new heating plants or for converting existing oil and natural gas boilers into using solid fuels. There is a new process development underway, aiming at motor use of the producer gas. The development work involves a new, more flexible cocurrent gasifier and a cleaning step for the counter-current producer gas. (orig.)

  18. Biomass gasification for liquid fuel production

    Energy Technology Data Exchange (ETDEWEB)

    Najser, Jan, E-mail: jan.najser@vsb.cz, E-mail: vaclav.peer@vsb.cz; Peer, Václav, E-mail: jan.najser@vsb.cz, E-mail: vaclav.peer@vsb.cz [VSB - Technical university of Ostrava, Energy Research Center, 17. listopadu 15/2172, 708 33 Ostrava-Poruba (Czech Republic); Vantuch, Martin [University of Zilina, Faculty of Mechanical Engineering, Department of Power Engineering, Univerzitna 1, 010 26 Zilina (Slovakia)

    2014-08-06

    In our old fix-bed autothermal gasifier we tested wood chips and wood pellets. We make experiments for Czech company producing agro pellets - pellets made from agricultural waste and fastrenewable natural resources. We tested pellets from wheat and rice straw and hay. These materials can be very perspective, because they dońt compete with food production, they were formed in sufficient quantity and in the place of their treatment. New installation is composed of allothermal biomass fixed bed gasifier with conditioning and using produced syngas for Fischer - Tropsch synthesis. As a gasifying agent will be used steam. Gas purification will have two parts - separation of dust particles using a hot filter and dolomite reactor for decomposition of tars. In next steps, gas will be cooled, compressed and removed of sulphur and chlorine compounds and carbon dioxide. This syngas will be used for liquid fuel synthesis.

  19. Biomass gasification for liquid fuel production

    Science.gov (United States)

    Najser, Jan; Peer, Václav; Vantuch, Martin

    2014-08-01

    In our old fix-bed autothermal gasifier we tested wood chips and wood pellets. We make experiments for Czech company producing agro pellets - pellets made from agricultural waste and fastrenewable natural resources. We tested pellets from wheat and rice straw and hay. These materials can be very perspective, because they dońt compete with food production, they were formed in sufficient quantity and in the place of their treatment. New installation is composed of allothermal biomass fixed bed gasifier with conditioning and using produced syngas for Fischer - Tropsch synthesis. As a gasifying agent will be used steam. Gas purification will have two parts - separation of dust particles using a hot filter and dolomite reactor for decomposition of tars. In next steps, gas will be cooled, compressed and removed of sulphur and chlorine compounds and carbon dioxide. This syngas will be used for liquid fuel synthesis.

  20. Catalytic routes from biomass to fuels

    DEFF Research Database (Denmark)

    Riisager, Anders

    2014-01-01

    The carbon-based chemicals and fuels that are necessary to meet the energy demand for our society originate presently almost exclusively from inexpensive fossil resources – coal, oil and natural gas. The forecast of diminishing and more expensive petroleum reserves has, however, engaged...... the chemical industry to find new feasible chemocatalytic routes to convert the components of lignocellulosic plant biomass (green biomass) as well as aquatic biomass (blue biomass) into potential platform chemicals that can replace the fossil based chemicals in order to leave the chemical supply and value...... chain unaffected. This presentation will survey the status of biofuels production from different sources, and discuss the sustainability of making transportation fuels from biomass. Furthermore, recently developed chemocatalytic technologies that allow efficient conversion of lignocellulosic biomass...

  1. Lignin biomass conversion into chemicals and fuels

    DEFF Research Database (Denmark)

    Melián Rodríguez, Mayra

    Second-generation biomass or lignocellulosic biomass, which is mainly composed of cellulose, hemicellulose and lignin, is a very important and promising feedstock for the renewable production of fuels and chemicals of the future. Lignin is the second most abundant natural polymer, representing 30...

  2. Fuel and fuel blending components from biomass derived pyrolysis oil

    Science.gov (United States)

    McCall, Michael J.; Brandvold, Timothy A.; Elliott, Douglas C.

    2012-12-11

    A process for the conversion of biomass derived pyrolysis oil to liquid fuel components is presented. The process includes the production of diesel, aviation, and naphtha boiling point range fuels or fuel blending components by two-stage deoxygenation of the pyrolysis oil and separation of the products.

  3. Alkali slagging problems with biomass fuels

    Energy Technology Data Exchange (ETDEWEB)

    Miles, T.R.; Miles, T.R. Jr.; Baxter, L.L.; Jenkins, B.M.; Oden, L.L.

    1993-12-31

    Biomass fueled power boilers are unable to burn more than minor percentages of annually generated agricultural fuels. Determining the mechanisms of deposit formation, and developing means of increasing the proportion of these annual biofuels to be fired are the aims of the ongoing Alkali Deposit Investigation sponsored by DOE/NREL with matching funds from industry sponsors, combining Science, Engineering and Industry.

  4. Investigation of Heat Generation from Biomass Fuels

    Directory of Open Access Journals (Sweden)

    Naoharu Murasawa

    2015-06-01

    Full Text Available New biomass fuels are constantly being developed from renewable resources in an effort to counter global warming and to create a sustainable society based on recycling. Among these, biomass fuels manufactured from waste are prone to microbial fermentation, and are likely to cause fires and explosions if safety measures, including sufficient risk assessments and long-term storage, are not considered. In this study, we conducted a series of experiments on several types of newly developed biomass fuels, using combinations of various thermal- and gas-analysers, to identify the risks related to heat- and gas-generation. Since a method for the evaluation of the relative risks of biomass fuels is not yet established in Japan, we also such a method based on our experimental results. The present study found that in cases where safety measures are not thoroughly observed, biomass fuels manufactured from waste materials have a higher possibility of combusting spontaneously at the storage site due to microbial fermentation and heat generation.

  5. Commercialization analysis for fuels from Pinyon-Juniper biomass

    International Nuclear Information System (INIS)

    Morris, G.P.

    1993-01-01

    Pinyon-Juniper (P-J) is a predominant forest type in the Southwestern US, and in many areas it is considered a hinderance to optimal land use management. There is only limited commercial demand for the traditional products that are produced from PJ biomass, like Christmas trees, fence poles, and firewood, and their production does not always promote overall land-management goals. This research effort, which is supported by the DOE through the Western Regional Biomass Energy Program, identifies commercially feasible energy markets to promote sustainable land clearing operations for alternative land uses of P-J woodlands in Eastern Nevada. All of the woodlands under consideration are federal lands managed by the U.S. Bureau of Land Management, which is supportive of our concept. Three possible markets are available or could reasonably be developed to use fuels derived from PJ biomass in Nevada: (1) The existing market for biomass power-plant fuels in California. (2) The emerging market for fuels for residential pellet-burning stoves. (3) The development of a biomass-fired power plant in the Eastern Nevada Area. The study analyzes the cost of harvesting, processing, transporting, and delivering fuels derived from P-J biomass, and identifies commercialization strategies for bringing these fuels to market. The best opportunity for near term commercial conversion of P-J biomass to fuel lies in the area of entering the pellet-stove fuel market, establishing a 10,000 ton per year pelletizing facility in Lincoln County. Such a facility would have excellent access to markets in Las Vegas, Phoenix, Denver, and Salt Lake City

  6. Biomass energy from wood chips: Diesel fuel dependence?

    International Nuclear Information System (INIS)

    Timmons, Dave; Mejia, Cesar Viteri

    2010-01-01

    Most renewable energy sources depend to some extent on use of other, non-renewable sources. In this study we explore use of diesel fuel in producing and transporting woody biomass in the state of New Hampshire, USA. We use two methods to estimate the diesel fuel used in woody biomass production: 1) a calculation based on case studies of diesel consumption in different parts of the wood chip supply chain, and 2) to support extrapolating those results to a regional system, an econometric study of the variation of wood-chip prices with respect to diesel fuel prices. The econometric study relies on an assumption of fixed demand, then assesses variables impacting supply, with a focus on how the price of diesel fuel affects price of biomass supplied. The two methods yield similar results. The econometric study, representing overall regional practices, suggests that a $1.00 per liter increase in diesel fuel price is associated with a $5.59 per Mg increase in the price of wood chips. On an energy basis, the diesel fuel used directly in wood chip production and transportation appears to account for less than 2% of the potential energy in the wood chips. Thus, the dependence of woody biomass energy production on diesel fuel does not appear to be extreme. (author)

  7. Soybean biomass produced in Argentina: Myths and realities

    International Nuclear Information System (INIS)

    Semino, S; Jelsoee, E; Paul, H; Tomei, J; Joensen, L; Monti, M

    2009-01-01

    Soybean biomass for biodiesel, produced in Argentina amongst other places, is considered by some to reduce greenhouse gas emissions and mitigate climate change when compared with fossil fuel alternatives. To ensure that the production of biofuels is 'sustainable', EU institutions and national governments are designing certification schemes for the sustainable production of biomass. In this paper, we question the validity of these proposed environmental standards, using the production of Argentine soybean as a case study. We highlight the negative environmental and social impacts of intensive soybean production, and conclude that certification schemes are unlikely to be able to address the detrimental impacts of increased biofuel production and trade.

  8. Soybean biomass produced in Argentina: Myths and realities

    Energy Technology Data Exchange (ETDEWEB)

    Semino, S; Jelsoee, E [Department of Environment, Social and Spatial Change, Roskilde University Universitetsvej 1, DK-4000, Roskilde (Denmark); Paul, H [ECONEXUS, PO Box 1455, Oxford OX4 9BS (United Kingdom); Tomei, J [UCL Energy Institute, Central House, 14 Upper Woburn Place, London, WC1H 0HY (United Kingdom); Joensen, L [Grupo de Reflexion Rural, Rondeau, 812 Marcos Paz, 1727, Provincia de Buenos Aires (Argentina); Monti, M, E-mail: semino@ruc.d, E-mail: stella.semino@mail.d [Direccion de Extension e Investigacion Agropecuaria, Ministerio de la Produccion, Provincia de Santa Fe, Pte Peron y Garay, 6100, Rufino, Provincia de Santa Fe (Argentina)

    2009-11-01

    Soybean biomass for biodiesel, produced in Argentina amongst other places, is considered by some to reduce greenhouse gas emissions and mitigate climate change when compared with fossil fuel alternatives. To ensure that the production of biofuels is 'sustainable', EU institutions and national governments are designing certification schemes for the sustainable production of biomass. In this paper, we question the validity of these proposed environmental standards, using the production of Argentine soybean as a case study. We highlight the negative environmental and social impacts of intensive soybean production, and conclude that certification schemes are unlikely to be able to address the detrimental impacts of increased biofuel production and trade.

  9. Biofuels for fuel cells: renewable energy from biomass fermentation

    NARCIS (Netherlands)

    Lens, P.N.L.; Westermann, P.; Haberbauer, M.; Moreno, A.

    2005-01-01

    This book has been produced under the auspices of the Network ‘Biomass Fermentation Towards Usage in Fuel Cells’. The Network comprises nine partners from eight European countries and is funded by the European Science Foundation. This volume includes a chapter, from each of the member institutions,

  10. Biomass fuel based on wastes from the paper industry

    Directory of Open Access Journals (Sweden)

    Budzyń Stanisław

    2016-01-01

    Full Text Available Wastes from paper industry are mostly combustible. It is possible to recycle them with energy recovery. These wastes have a high moisture content (up to 60% and thus a small calorific value. An alternative to waste incineration is the production of solid recovered fuel. The benefits are: easy adjustment of the physical and chemical properties of the fuel (via the change of proportions of ingredients, low moisture and high calorific value. The study involved the following types of cellulose wastes: - Belmer - the rejects from recovered paper, Krofta - deinking sludge, sludge - wastewater treatment sludge, bark - the rejects from virgin pulps. The results of investigations of waste produced in one of the biggest Polish paper mill - are shown. Following aspects were investigated: energy properties, content of carbon, hydrogen, sulfur, chlorine and nitrogen, chemical composition of ash. Authors proposed two formulas of the biomass fuel. The properties of the fuel such as the content of carbon, hydrogen, sulfur, chlorine or nitrogen, the chemical composition of the ash were investigated. Due to the fact that the combustion of the biomass fuel is preferred in view of law regulations (zero CO2 emission, green certificates the content of biodegradable fraction was examined. It has been shown that the fuel is a biomass one. Fuel from waste can be a substitute for approx. 25% of primary fuel (coal used by the paper mill.

  11. 77 FR 59458 - Regulation of Fuels and Fuel Additives: 2013 Biomass-Based Diesel Renewable Fuel Volume

    Science.gov (United States)

    2012-09-27

    ... 80 Regulation of Fuels and Fuel Additives: 2013 Biomass-Based Diesel Renewable Fuel Volume; Final...] RIN 2060-AR55 Regulation of Fuels and Fuel Additives: 2013 Biomass-Based Diesel Renewable Fuel Volume... biomass-based diesel to be used in setting annual percentage standards under the renewable fuel standard...

  12. Biomass. A modern and environmentally acceptable fuel

    International Nuclear Information System (INIS)

    Hall, D.O.; House, J.I.

    1995-01-01

    The energy of the sun and carbon dioxide from the atmosphere are captured by plants during photosynthesis. Plant biomass can be used to absorb carbon dioxide emissions from fossil fuels, or it can be converted into modern energy carriers such as electricity, and liquid and gaseous fuels. Biomass supplies 13% of the world's energy consumption (55 EJ, 1990), and in some developing countries it accounts for over 90% of energy use. There is considerable potential for the modernisation of biomass fuels through improved utilisation of existing resources, higher plant productivities and efficient conversion processes using advanced technologies. The interest in bioenergy is increasing rapidly, and it is widely considered as one of the main renewable energy resources of the future due to its large potential, economic viability, and various social and environmental benefits. In particular, biomass energy is among the most favourable options for reducing carbon dioxide emissions. Most of the perceived problems such as land availability, environmental impact, economic viability, and efficiency can be overcome with good management. The constraints to achieving environmentally-acceptable biomass production are not insurmountable, but should rather be seen as scientific and entrepreneurial opportunities which will yield numerous advantages at local, national and international levels in the long term

  13. Income tax credits and incentives available for producing energy from biomass

    International Nuclear Information System (INIS)

    Sanderson, G.A.

    1993-01-01

    In the 1970's the US became interested in the development of energy from biomass and other alternative sources. While this interest was stimulated primarily by the oil embargoes of the 1970's, the need for environmentally friendly alternative fuels was also enhanced by the Clean Water Act and the Clean Air Act, two prominent pieces of environmental legislation. As a result, Congress created several tax benefits and subsidies for the production of energy for biomass. Congress enacted biomass energy incentives in 1978 with the creation of excise tax exemptions for alcohol fuels, in 1980 with the enactment of the IRC section 29 nonconventional fuel credit provisions and the IRC section 40 alcohol fuel credits, and recently with the addition of favorable biomass energy provisions as part of the Comprehensive National energy Policy Act of 1992. This article focuses on the following specific tax credits, tax benefits and subsidies for biomass energy: (1) IRC section 29 credit for producing gas from biomass, (2) IRC section 45 credit for producing electricity from biomass, (3) Incentive payments for electricity produced from biomass, (4) Excise tax exemptions for alcohol fuels, (5) IRC section 40 alcohol fuels credits, and (6) IRC section 179A special deduction for alcohol fuels property

  14. High-grade fuels and biomass farming

    Energy Technology Data Exchange (ETDEWEB)

    Kyle, B.G.

    1980-11-14

    This article analyzes distorted views that Weisz and Marshall have presented on the energetics and economics of ethanol production via biomass fermentation. Their conclusion, that with current technology ethanol production represents a net consumption of fuel, results from use of an unrealistically high processing energy and neglect of energy credit for the distillers' dry grains. Other fallacies were mentioned: failure to use insights available through the second law of thermodynamics; inconsistency of comparing cost of net alcohol fuel production with the market price of other fuels. It was concluded that if allowed to stand unchallenged, they could do serious damage to future research and development. (DP)

  15. Hydrogen assisted catalytic biomass pyrolysis for green fuels

    DEFF Research Database (Denmark)

    Stummann, Magnus Zingler; Høj, Martin; Gabrielsen, Jostein

    2017-01-01

    due to coking of the catalyst is an inhibitive problem for this technology. The objective of the present work is to produce oxygen free gasoline and diesel from biomass by hydrogen assisted catalytic fast pyrolysis. Fast pyrolysis of beech wood has been performed in high-pressure hydrogen atmosphere......Fast pyrolysis of biomass is a well-known technology for producing bio-oil, however in order to use the oil as transportation fuel the oxygen content must be decreased from approximately 30 wt.% to below 1 wt.%. This can be achieved by catalytic hydrodeoxygenation (HDO). Unfortunately, deactivation...

  16. Hydrogen assisted catalytic biomass pyrolysis for green fuels

    DEFF Research Database (Denmark)

    Stummann, Magnus Zingler; Høj, Martin; Schandel, Christian Bækhøj

    Fast pyrolysis of biomass is a well-known technology for producing bio-oil, however in order to use the oil as transportation fuel the oxygen content must be decreased from approximately 30 wt.% to below 1 wt.%. This can be achieved by catalytic hydrodeoxygenation (HDO). Unfortunately, deactivation...... due to coking of the catalyst is an inhibitive problem for this technology. The objective of the present work is to produce oxygen free gasoline and diesel from biomass by hydrogen assisted catalytic fast pyrolysis. Fast pyrolysis of beech wood has been performed in high-pressure hydrogen atmosphere...

  17. Three generation production biotechnology of biomass into bio-fuel

    Science.gov (United States)

    Zheng, Chaocheng

    2017-08-01

    The great change of climate change, depletion of natural resources, and scarcity of fossil fuel in the whole world nowadays have witnessed a sense of urgency home and abroad among scales of researchers, development practitioners, and industrialists to search for completely brand new sustainable solutions in the area of biomass transforming into bio-fuels attributing to our duty-that is, it is our responsibility to take up this challenge to secure our energy in the near future with the help of sustainable approaches and technological advancements to produce greener fuel from nature organic sources or biomass which comes generally from organic natural matters such as trees, woods, manure, sewage sludge, grass cuttings, and timber waste with a source of huge green energy called bio-fuel. Biomass includes most of the biological materials, livings or dead bodies. This energy source is ripely used industrially, or domestically for rather many years, but the recent trend is on the production of green fuel with different advance processing systems in a greener. More sustainable method. Biomass is becoming a booming industry currently on account of its cheaper cost and abundant resources all around, making it fairly more effective for the sustainable use of the bio-energy. In the past few years, the world has witnessed a remarkable development in the bio-fuel production technology, and three generations of bio-fuel have already existed in our society. The combination of membrane technology with the existing process line can play a vital role for the production of green fuel in a sustainable manner. In this paper, the science and technology for sustainable bio-fuel production will be introduced in detail for a cleaner world.

  18. Energetic and economical comparison for biomass fuel

    International Nuclear Information System (INIS)

    Galins, A.; Grundulis, A.; Zihmane, K.

    2003-01-01

    The common agricultural biomass, such as wheat straw, rape straw, wheat small corn, wheat forage, rape oil cakes and other, we can use as fuel for heat production. The biomass application for burning depends on economical situation on agriculture and fuel market. Energetic and economical parameters of agricultural biomass are estimated and compared to wooden grain. As parameters for comparison used the biomass heat value Q (MJ/kg), specific cost per 1 kWh heat production C 0 (Ls/kWh) and the fuel consumption per 1 kWh heat production M 0 (kg/kWh). The rape oil cakes have best heat value (20.82 MJ/kg), but cheapest heat energy we can get from rape straw (0.0046 Ls/kWh). Expenses of heat production for forge wheat corn (0.011 Ls/kWh) are alike to wooden chip (0.0103 Ls/kWh) and wooden grain (0.0122 Ls/kWh) (authors)

  19. Identifying biomass fuel shortages in Sri Lanka

    Energy Technology Data Exchange (ETDEWEB)

    Howes, Michael (Sussex Univ., Brighton (UK). Inst. of Development Studies)

    1989-01-01

    This paper analyses data from the Sri Lankan Forestry Master Plan and other sources, to explore the causes of biomass shortages, and to identify the areas where interventions are likely to have most impact. Five districts, concentrated in the wet lowland and hill country zones, are found to be in overall biomass fuel deficit whilst in a further five, which include dry zone locations, fuelwood consumption exceeds potential supply, Within the area of overall deficit, poorer urban groups and rural families with no home gardens - who together comprise 15% of all households nationally - are affected most severely. Another 10% of households are likely to suffer to a lesser extent. (author).

  20. Production of New Biomass/Waste-Containing Solid Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Glenn A. Shirey; David J. Akers

    2005-09-23

    CQ Inc. and its industry partners--PBS Coals, Inc. (Friedens, Pennsylvania), American Fiber Resources (Fairmont, West Virginia), Allegheny Energy Supply (Williamsport, Maryland), and the Heritage Research Group (Indianapolis, Indiana)--addressed the objectives of the Department of Energy and industry to produce economical, new solid fuels from coal, biomass, and waste materials that reduce emissions from coal-fired boilers. This project builds on the team's commercial experience in composite fuels for energy production. The electric utility industry is interested in the use of biomass and wastes as fuel to reduce both emissions and fuel costs. In addition to these benefits, utilities also recognize the business advantage of consuming the waste byproducts of customers both to retain customers and to improve the public image of the industry. Unfortunately, biomass and waste byproducts can be troublesome fuels because of low bulk density, high moisture content, variable composition, handling and feeding problems, and inadequate information about combustion and emissions characteristics. Current methods of co-firing biomass and wastes either use a separate fuel receiving, storage, and boiler feed system, or mass burn the biomass by simply mixing it with coal on the storage pile. For biomass or biomass-containing composite fuels to be extensively used in the U.S., especially in the steam market, a lower cost method of producing these fuels must be developed that is applicable to a variety of combinations of biomass, wastes, and coal; economically competitive with current fuels; and provides environmental benefits compared with coal. During Phase I of this project (January 1999 to July 2000), several biomass/waste materials were evaluated for potential use in a composite fuel. As a result of that work and the team's commercial experience in composite fuels for energy production, paper mill sludge and coal were selected for further evaluation and demonstration

  1. Distributed renewable power from biomass and other waste fuels

    Science.gov (United States)

    Lyons, Chris

    2012-03-01

    The world population is continually growing and putting a burden on our fossil fuels. These fossil fuels such as coal, oil and natural gas are used for a variety of critical needs such as power production and transportation. While significant environmental improvements have been made, the uses of these fuels are still causing significant ecological impacts. Coal power production efficiency has not improved over the past thirty years and with relatively cheap petroleum cost, transportation mileage has not improved significantly either. With the demand for these fossil fuels increasing, ultimately price will also have to increase. This presentation will evaluate alternative power production methods using localized distributed generation from biomass, municipal solid waste and other waste sources of organic materials. The presentation will review various gasification processes that produce a synthetic gas that can be utilized as a fuel source in combustion turbines for clean and efficient combined heat and power. This fuel source can produce base load renewable power. In addition tail gases from the production of bio-diesel and methanol fuels can be used to produce renewable power. Being localized can reduce the need for long and costly transmission lines making the production of fuels and power from waste a viable alternative energy source for the future.

  2. Commercialization of fuels from Pinyon-Juniper biomass in Nevada

    International Nuclear Information System (INIS)

    Morris, G.P.

    1994-01-01

    This study analyzes and defines energy applications and markets that could stimulate the commercial use of Eastern Nevada's Pinyon-Juniper resources. The commercialization potential for producing energy from Pinyon-Juniper biomass is analyzed by examining the resource base and resource availability for a commercial harvesting and processing operation. The study considered the spectrum of available equipment and technology for carrying out harvesting and processing operations, investigated the markets that might be able to use energy products derived from Pinyon-Juniper biomass, analyzed the costs of harvesting, processing, and transporting Pinyon-Juniper fuels, and set forth a plan for developing the commercial potential of these resources. The emerging residential pellet-fuels market is a promising entry market for the commercialization of an energy from Pinyon-Juniper biomass industry in Eastern Nevada, although there are serious technical issues that may render Pinyon-Juniper biomass an unsuitable feedstock for the manufacture of pellet fuels. These issues could be investigated at a moderate cost in order to determine whether to proceed with development efforts in this direction. In the longer term, one or two biomass-fired power plants in the size range of 5-10 MW could provide a stable and predictable market for the production and utilization of fuels derived from local Pinyon-Juniper biomass resources, and would provide valuable economic and environmental benefits to the region. Municipal utility ownership of such facilities could help to enhance the economic benefits of the investments by qualifying them for federal energy credits and tax-free financing

  3. H2CAP - Hydrogen assisted catalytic biomass pyrolysis for green fuels

    DEFF Research Database (Denmark)

    Stummann, Magnus Zingler; Høj, Martin; Gabrielsen, Jostein

    Fast pyrolysis of biomass produces a high yield of bio-oil through well-established technologies [1]. To utilize this oil as liquid fuel the oxygen content must be reduced from 15-30 wt.% down to ... of 100 to 300 g/h solid biomass, the aim is to provide a proof-of-concept for the continuous conversion of solid biomass to low oxygen, fuel-grade bio-oil....

  4. Biomass Biorefinery for the production of Polymers and Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Dr. Oliver P. Peoples

    2008-05-05

    The conversion of biomass crops to fuel is receiving considerable attention as a means to reduce our dependence on foreign oil imports and to meet future energy needs. Besides their use for fuel, biomass crops are an attractive vehicle for producing value added products such as biopolymers. Metabolix, Inc. of Cambridge proposes to develop methods for producing biodegradable polymers polyhydroxyalkanoates (PHAs) in green tissue plants as well as utilizating residual plant biomass after polymer extraction for fuel generation to offset the energy required for polymer extraction. The primary plant target is switchgrass, and backup targets are alfalfa and tobacco. The combined polymer and fuel production from the transgenic biomass crops establishes a biorefinery that has the potential to reduce the nation’s dependence on foreign oil imports for both the feedstocks and energy needed for plastic production. Concerns about the widespread use of transgenic crops and the grower’s ability to prevent the contamination of the surrounding environment with foreign genes will be addressed by incorporating and expanding on some of the latest plant biotechnology developed by the project partners of this proposal. This proposal also addresses extraction of PHAs from biomass, modification of PHAs so that they have suitable properties for large volume polymer applications, processing of the PHAs using conversion processes now practiced at large scale (e.g., to film, fiber, and molded parts), conversion of PHA polymers to chemical building blocks, and demonstration of the usefulness of PHAs in large volume applications. The biodegradability of PHAs can also help to reduce solid waste in our landfills. If successful, this program will reduce U.S. dependence on imported oil, as well as contribute jobs and revenue to the agricultural economy and reduce the overall emissions of carbon to the atmosphere.

  5. Biomass fuel exposure and respiratory diseases in India.

    Science.gov (United States)

    Prasad, Rajendra; Singh, Abhijeet; Garg, Rajiv; Giridhar, Giridhar B

    2012-10-01

    One half of the world's population relies on biomass fuel as the primary source of domestic energy. Biomass fuel exposure causes a high degree of morbidity and mortality in humans. This is especially true in the context of developing countries, which account for 99% of the world's biomass fuel use. Biomass fuel consists of fire wood, dung cakes, agricultural crop residues such as straw, grass, and shrubs, coal fuels and kerosene. Together, they supply 75% of the domestic energy in India. An estimated three-quarters of Indian households use biomass fuel as the primary means for domestic cooking. Ninety percent of rural households and 32% of urban households cook their meals on a biomass stove. There are wide variations between the rural and urban households regarding the specific type of biomass fuel used. Globally, almost 2 million deaths per year are attributable to solid fuel use, with more than 99% of these occurring in developing countries. Biomass fuel accounts for 5-6% of the national burden of disease. Burning biomass fuels emits toxic fumes into the air that consist of small solid particles, carbon monoxide, polyorganic and polyaromatic hydrocarbons, and formaldehyde. Exposure to biomass fuels has been found to be associated with many respiratory diseases such as acute lower respiratory infections, chronic obstructive pulmonary disease, lung cancer, pulmonary tuberculosis, and asthma. Biomass fuel exposure is closely related to the burden of disease in India. Hopes are that future studies will examine the morbidity associated with biomass exposure and seek to prevent it. Concerted efforts to improve stove design and transition to high-efficiency low-emission fuels may reduce respiratory disease associated with biomass fuel exposure.

  6. Method of producing hydrogen, and rendering a contaminated biomass inert

    Science.gov (United States)

    Bingham, Dennis N [Idaho Falls, ID; Klingler, Kerry M [Idaho Falls, ID; Wilding, Bruce M [Idaho Falls, ID

    2010-02-23

    A method for rendering a contaminated biomass inert includes providing a first composition, providing a second composition, reacting the first and second compositions together to form an alkaline hydroxide, providing a contaminated biomass feedstock and reacting the alkaline hydroxide with the contaminated biomass feedstock to render the contaminated biomass feedstock inert and further producing hydrogen gas, and a byproduct that includes the first composition.

  7. A Hybrid Catalytic Route to Fuels from Biomass Syngas

    Energy Technology Data Exchange (ETDEWEB)

    Harmon, Laurel [LanzaTech, Inc.; Hallen, Richard [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Lilga, Michael [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Heijstra, Bjorn [LanzaTech, Inc.; Palou-Rivera, Ignasi [LanzaTech, Inc.; Handler, Robert [Michigan Technological Univ., Houghton, MI (United States)

    2017-12-31

    LanzaTech partnered with the Pacific Northwest National Laboratory (PNNL), Imperium Aviation Fuels, InEnTec, Orochem Technologies, the University of Delaware, Michigan Technological University, the National Renewable Energy Laboratory, and The Boeing Company, to develop a cost-effective hybrid conversion technology for catalytic upgrading of biomass-derived syngas to sustainable alternative jet fuel (SAJF) meeting the price, quality and environmental requirements of the aviation industry. Alternative “synthetic paraffinic kerosene” (SPK) blendstock produced from syngas via “Fischer-Tropsch” (F-T) or from lipids via “hydroprocessing of esters and fatty acids” (HEFA) are currently being used in commercial jet fuel blends containing at least 50% petroleum-based fuel. This project developed an alternative route to SAJF from ethanol, a type of “alcohol to jet” (ATJ) SPK. The project objective was to demonstrate a pathway that combines syngas fermentation to ethanol with catalytic upgrading of ethanol to sustainable alternative jet fuel and shows attractive overall system economics to drive down the price of biomass-derived jet fuel. The hybrid pathway was to be demonstrated on three biomass feedstocks: corn stover, woody biomass, and third biomass feedstock, cellulosic residues. The objective also included the co-production of chemicals, exemplified by 2,3-Butanediol (2,3-BDO), which can be converted to key chemical intermediates. The team successfully demonstrated that biomass syngas fermentation followed by catalytic conversion is a viable alternative to the Fischer-Tropsch process and produces a fuel with properties comparable to F-T and HEFA SPKs. Plasma gasification and gas fermentation were successfully integrated and demonstrated in continuous fermentations on waste wood, corn stover, and cellulosic bagasse. Gas fermentation was demonstrated to produce ethanol suitable for catalytic upgrading, isolating the upgrading from variations in biomass

  8. Biomass burning fuel consumption rates: a field measurement database

    NARCIS (Netherlands)

    van Leeuwen, T.T.; van der Werf, G.R.; Hoffmann, A.A.; Detmers, R.G.; Ruecker, G.; French, N.H.F.; Archibald, S.; Carvalho Jr., J.A.; Cook, G.D.; de Groot, J.W.; Hely, C.; Kasischke, E.S.; Kloster, S.; McCarty, J.L.; Pettinari, M.L.; Savadogo, P.

    2014-01-01

    Landscape fires show large variability in the amount of biomass or fuel consumed per unit area burned. Fuel consumption (FC) depends on the biomass available to burn and the fraction of the biomass that is actually combusted, and can be combined with estimates of area burned to assess emissions.

  9. Liquid fuels production from biomass. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Levy, P. F.; Sanderson, J. E.; Ashare, E.; Wise, D. L.; Molyneaux, M. S.

    1980-06-30

    The current program to convert biomass into liquid hydrocarbon fuels is an extension of a previous program to ferment marine algae to acetic acid. In that study it was found that marine algae could be converted to higher aliphatic organic acids and that these acids could be readily removed from the fermentation broth by membrane or liquid-liquid extraction. It was then proposed to convert these higher organic acids via Kolbe electrolysis to aliphatic hydrocarbons, which may be used as a diesel fuel. The specific goals for the current porgram are: (1) establish conditions under which substrates other than marine algae may be converted in good yield to organic acids, here the primary task is methane suppression; (2) modify the current 300-liter fixed packed bed batch fermenter to operate in a continuous mode; (3) change from membrane extraction of organic acids to liquid-liquid extraction; (4) optimize the energy balance of the electrolytic oxidation process, the primary task is to reduce the working potential required for the electrolysis while maintaining an adequate current density; (5) scale the entire process up to match the output of the 300 liter fermenter; and (6) design pilot plant and commercial size plant (1000 tons/day) processes for converting biomass to liquid hydrocarbon fuels and perform an economic analysis for the 1000 ton/day design.

  10. Competitiveness of biomass-fueled electrical power plants.

    Science.gov (United States)

    Bruce A. McCarl; Darius M. Adams; Ralph J. Alig; John T. Chmelik

    2000-01-01

    One way countries like the United States can comply with suggested rollbacks in greenhouse gas emissions is by employing power plants fueled with biomass. We examine the competitiveness of biomass-based fuel for electrical power as opposed to coal using a mathematical programming structure. We consider fueling power plants from milling residues, whole trees, logging...

  11. Cost effectiveness of transportation fuels from biomass

    International Nuclear Information System (INIS)

    De Jager, D.; Faaij, A.P.C.; Troelstra, W.P.

    1998-06-01

    The aim of the study on the title subject was to investigate whether stimulation of the production and use of biofuels for transportation is worthwhile compared to the production of electricity from biomass. Several options are compared to each other and with reference technologies on the basis of the consumption or the avoided input of fossil fuels, emissions of greenhouse gases, specific costs and cost effectiveness. For each phase in the biomass conversion process (cultivation, pretreatment, transportation, conversion, distribution and final consumption) indicators were collected from the literature. Next to costs of the bioconversion routes attention is paid to other relevant aspects that are important for the introduction of the technological options in the Netherlands. 41 refs

  12. Methods for producing and using densified biomass products containing pretreated biomass fibers

    Science.gov (United States)

    Dale, Bruce E.; Ritchie, Bryan; Marshall, Derek

    2015-05-26

    A process is provided comprising subjecting a quantity of plant biomass fibers to a pretreatment to cause at least a portion of lignin contained within each fiber to move to an outer surface of said fiber, wherein a quantity of pretreated tacky plant biomass fibers is produced; and densifying the quantity of pretreated tacky plant biomass fibers to produce one or more densified biomass particulates, wherein said biomass fibers are densified without using added binder.

  13. Compacting biomass waste materials for use as fuel

    Science.gov (United States)

    Zhang, Ou

    Every year, biomass waste materials are produced in large quantity. The combustibles in biomass waste materials make up over 70% of the total waste. How to utilize these waste materials is important to the nation and the world. The purpose of this study is to test optimum processes and conditions of compacting a number of biomass waste materials to form a densified solid fuel for use at coal-fired power plants or ordinary commercial furnaces. Successful use of such fuel as a substitute for or in cofiring with coal not only solves a solid waste disposal problem but also reduces the release of some gases from burning coal which cause health problem, acid rain and global warming. The unique punch-and-die process developed at the Capsule Pipeline Research Center, University of Missouri-Columbia was used for compacting the solid wastes, including waste paper, plastics (both film and hard products), textiles, leaves, and wood. The compaction was performed to produce strong compacts (biomass logs) under room temperature without binder and without preheating. The compaction conditions important to the commercial production of densified biomass fuel logs, including compaction pressure, pressure holding time, back pressure, moisture content, particle size, binder effects, and mold conditions were studied and optimized. The properties of the biomass logs were evaluated in terms of physical, mechanical, and combustion characteristics. It was found that the compaction pressure and the initial moisture content of the biomass material play critical roles in producing high-quality biomass logs. Under optimized compaction conditions, biomass waste materials can be compacted into high-quality logs with a density of 0.8 to 1.2 g/cm3. The logs made from the combustible wastes have a heating value in the range 6,000 to 8,000 Btu/lb which is only slightly (10 to 30%) less than that of subbituminous coal. To evaluate the feasibility of cofiring biomass logs with coal, burn tests were

  14. Processes for converting biomass-derived feedstocks to chemicals and liquid fuels

    Science.gov (United States)

    Held, Andrew; Woods, Elizabeth; Cortright, Randy; Gray, Matthew

    2017-05-23

    The present invention provides processes, methods, and systems for converting biomass-derived feedstocks to liquid fuels and chemicals. The method generally includes the reaction of a hydrolysate from a biomass deconstruction process with hydrogen and a catalyst to produce a reaction product comprising one of more oxygenated compounds. The process also includes reacting the reaction product with a condensation catalyst to produce C.sub.4+ compounds useful as fuels and chemicals.

  15. Is biomass always a renewable fuel as guaranteed?

    International Nuclear Information System (INIS)

    Veski, Rein

    1999-01-01

    Full text: In official EU documents the terms biomass, biofuels, renewable energy resources have not yet been defined unambiguously. In the respective statistical reports peat falls, according to earlier classification traditions, under the subdivision NACE 10 together with coal and lignite (fossil fuels). No NACE classification has been applied in the renewable energy industry. This is probably why no unanimity has been achieved in classifying peat as a renewable fuel. Besides wind, solar, geothermal and water energy, biomass belongs to renewable energy sources as well. The situation is also regrettably equivocal because the terms biomass and biofuel (biological fuel) were used only recently and are continuously used as a wholly dry mass of animal or plant population (kg/m 2 or kg/m 3 ) and as manure or other organic waste as a source of heat delivered in an anaerobic decay in greenhouses, respectively. This uncertainty in using the terms under consideration leads sometimes to a nonsense in official documents. For example, in paragraph 2 of the Energy Act, the provision concerning fuel does not apply to wood, peat and biofuel. According to this statement wood and peat are not classified as biofuels (the correct statement is: wood, peat and other biofuels). Another statement of the Act (paragraph 28 1 The obligation to purchase alternatively produced electric power) declares that an energy trader dominating the market is required to purchase electric power from traders connected to its network and who produce such power from water, wind or solar energy, biomass, waste gases or waste material. According to this statement waste material is not classified as biomass either. As wood and peat are not classified as biofuel in Paragrapg 2 (4) and paragraph 28 1 , an energy trader dominating the market must not purchase electricity produced from wood and peat. By way of a remark: almost 99 % of Estonia's electric energy was produced from oil shale. It means that in Estonia

  16. The regional effects of a biomass fuel industry on US agriculture

    International Nuclear Information System (INIS)

    Gallagher, Paul W.

    2014-01-01

    This study looks at the potential competitiveness of the emerging biomass-based biofuel industry in the current economic environment. A simulation model suggests that a mature biomassbased biofuel industry is potentially competitive with gasoline, and capable of filling a significant fraction of motor fuel supplies. However, the existing land policy has a narrow definition of agricultural land for a biomass-based fuel industry. A broader definition of agricultural land suitable for biomass inputs would reduce biofuel processing costs, relieve the food versus fuel conflict, and increase the net gain to fuel consumers, food consumers, and producers of food and fuel. - Highlights: • We look at the potential competitiveness of a mature biomass fuel (BF) industry in the US. • We model a land policy that allows BF-cattle competition for forage, crop residues, and pasture. • We estimate the cost reductions and welfare gains associated with modifying the land use policy

  17. Production Of Bio fuel Starter From Biomass Waste Using Rocking Kiln Fluidized Bed System

    International Nuclear Information System (INIS)

    Mohamad Azman Che Mat Isa; Muhd Noor Muhd Yunus; Zulkafli Ghazali; Mohd Zaid Mohamed; Phongsakorn, P.T.; Mohamad Puad Abu

    2014-01-01

    The biggest biomass source in Malaysia comes from oil palm industry. According to the statistic in 2010, Malaysia produced 40 million tones per year of biomass of which 30 million tones of biomass originated from the oil palm industries. The biomass waste such as palm kernel shell can be used to produce activated carbon and bio fuel starter. A new type of rotary kiln, called Rocking Kiln Fluidized Bed (RKFB) was developed in Nuclear Malaysia to utilize the large amount of the biomass to produce high value added products. This system is capable to process biomass with complete combustion to produce bio fuel starter. With this system, the produced charcoal has calorific value, 33MJ/ kg that is better than bituminous coal with calorific value, 25-30 MJ/ kg. In this research, the charcoals produced were further used to produce the bio fuel starter. This paper will elaborate the experimental set-up of the Rocking Kiln Fluidized Bed (RKFB) for bio fuel starter production and the quality of the produced bio fuel starter. (author)

  18. Synthesis gas from biomass for fuels and chemicals

    International Nuclear Information System (INIS)

    Van der Drift, A.; Boerrigter, H.

    2006-01-01

    Making H2 and CO (syngas) from biomass is widely recognised as a necessary step in the production of various second generation biofuels. There are two major ways to produce a biosyngas: fluidised bed gasification with catalytic reformer or entrained flow gasification. The latter option requires extensive pre-treatment such as flash pyrolysis, slow pyrolysis, torrefaction, or fluidized bed gasification at a low temperature. Cleaned and conditioned biosyngas can be used to synthesize second generation biofuels such as Fischer-Tropsch fuels, methanol, DME, mixed alcohols, and even pure hydrogen. The report describes the different technical options to produce, clean and condition bio-syngas. Furthermore, issues related to scale and biomass transport are covered shortly

  19. Biomass equipments. The wood-fueled heating plants; Materiels pour la biomasse. Les chaudieres bois

    Energy Technology Data Exchange (ETDEWEB)

    Chieze, B. [SA Compte R, 63 - Arlanc (France)

    1997-12-31

    This paper analyzes the consequences of the classification of biomass fuels in the French 2910 by-law on the classification of biomass-fueled combustion installations. Biomass fuels used in such installations must be only wood wastes without any treatment or coating. The design of biomass combustion systems must follow several specifications relative to the fueling system, the combustion chamber, the heat exchanger and the treatment of exhaust gases. Other technical solutions must be studied for other type of wood wastes in order to respect the environmental pollution laws. (J.S.)

  20. Production of distillate fuels from biomass-derived polyoxygenates

    Science.gov (United States)

    Kania, John; Blommel, Paul; Woods, Elizabeth; Dally, Brice; Lyman, Warren; Cortright, Randy

    2017-03-14

    The present invention provides methods, reactor systems and catalysts for converting biomass and biomass-derived feedstocks to C.sub.8+ hydrocarbons using heterogenous catalysts. The product stream may be separated and further processed for use in chemical applications, or as a neat fuel or a blending component in jet fuel and diesel fuel, or as heavy oils for lubricant and/or fuel oil applications.

  1. Social cost pricing of fossil fuels used in the production of electricity: implications to biomass feasibility

    International Nuclear Information System (INIS)

    Dillivan, K.D.; English, B.C.

    1997-01-01

    The primary objective of this study is to investigate full social pricing for fossil fuels and the subsequent effect on biomass quantities in the state of Tennessee. The first step is to estimate the full social costs and then to estimate the effects of their internalization. Other objectives are (1) investigate whether or not market imperfections exist, (2) if they exist, how should full social cost pricing be estimated, (3) what other barriers help fossil fuels stay economically attractive and prevent biomass from competing, (4) estimating the demand for biomass, and (5) given this demand for biomass, what are the implications for farmers and producers in Tennessee. (author)

  2. Overview of biomass and waste fuel resources for power production

    International Nuclear Information System (INIS)

    Easterly, J.L.; Burnham, M.

    1993-01-01

    This paper provides an overview of issues and opportunities associated with the use of biomass for electric power generation. Important physical characteristics of biomass and waste fuels are summarized, including comparisons with conventional fossil fuels, primarily coal. The paper also provides an overview of the current use of biomass and waste fuels for electric power generation. Biomass and waste fuels are currently used for approximately 9,800 megawatts (MW) of electric generating capacity, including about 6,100 MW of capacity fueled by wood/wood waste and about 2,200 MW of capacity fueled with municipal solid waste. Perspectives on the future availability of biomass fuels (including energy crops) are addressed, as well as projected levels of market penetration for biomass power. By the year 2010, there is a potential for 22,000 MW, to as much as 70,000 MW of biomass-powered electric generating capacity in the U.S. Given the range of benefits offered by biomass, including reduced sulfur emissions, reduced greenhouse gas emissions, job creation, rural revitalization impacts, and new incentives under the Energy Policy Act of 1992, the potential use of biomass for power production could significantly expand in the future

  3. Simulation and Optimization of the logistics of biomass fuel collection.

    NARCIS (Netherlands)

    Mol, de R.M.; Jogems, M.A.H.; Beek, van P.; Gigler, J.K.

    1997-01-01

    Biomass fuel costs depend for a great part on the logistics of biomass fuel collection. The logistics, including pre-treatments, from source locations to energy plant can be modelled by means of a network structure. Nodes correspond to source locations, collection sites, trans-shipment sites,

  4. Biomass fuel characterization for NOx emissions in cofiring applications

    NARCIS (Netherlands)

    Di Nola, G.

    2007-01-01

    This dissertation investigates the impact of various biomass fuels and combustion conditions on the NOx emissions during biomass co-firing. Fossil fuels dominated the energy scenario since the industrial revolution. However, in the last decades, increasing concerns about their availability and

  5. Carbon-Based Nanomaterials in Biomass-Based Fuel-Fed Fuel Cells

    Directory of Open Access Journals (Sweden)

    Le Quynh Hoa

    2017-11-01

    Full Text Available Environmental and sustainable economical concerns are generating a growing interest in biofuels predominantly produced from biomass. It would be ideal if an energy conversion device could directly extract energy from a sustainable energy resource such as biomass. Unfortunately, up to now, such a direct conversion device produces insufficient power to meet the demand of practical applications. To realize the future of biofuel-fed fuel cells as a green energy conversion device, efforts have been devoted to the development of carbon-based nanomaterials with tunable electronic and surface characteristics to act as efficient metal-free electrocatalysts and/or as supporting matrix for metal-based electrocatalysts. We present here a mini review on the recent advances in carbon-based catalysts for each type of biofuel-fed/biofuel cells that directly/indirectly extract energy from biomass resources, and discuss the challenges and perspectives in this developing field.

  6. Carbon-Based Nanomaterials in Biomass-Based Fuel-Fed Fuel Cells

    Science.gov (United States)

    Vestergaard, Mun’delanji C.; Tamiya, Eiichi

    2017-01-01

    Environmental and sustainable economical concerns are generating a growing interest in biofuels predominantly produced from biomass. It would be ideal if an energy conversion device could directly extract energy from a sustainable energy resource such as biomass. Unfortunately, up to now, such a direct conversion device produces insufficient power to meet the demand of practical applications. To realize the future of biofuel-fed fuel cells as a green energy conversion device, efforts have been devoted to the development of carbon-based nanomaterials with tunable electronic and surface characteristics to act as efficient metal-free electrocatalysts and/or as supporting matrix for metal-based electrocatalysts. We present here a mini review on the recent advances in carbon-based catalysts for each type of biofuel-fed/biofuel cells that directly/indirectly extract energy from biomass resources, and discuss the challenges and perspectives in this developing field. PMID:29125564

  7. CO and PAH Emissions from Engines Operating on Biomass Producer Gas

    DEFF Research Database (Denmark)

    Ahrenfeldt, Jesper; Jensen, Torben Kvist; Henriksen, Ulrik Birk

    2003-01-01

    High carbon monoxide (CO) emission from gas engines fueled by producer gas is a concerning problem in the struggle to make biomass gasification for heat and power production a success. The standing regulations concerning CO emissions from producer gas engine based power plants in most EU countrie...

  8. Upgrading Fuel Properties of Biomass by Torrefaction

    DEFF Research Database (Denmark)

    Shang, Lei; Holm, Jens Kai

    , higher heating value, better grindability, and less moisture absorption. However, severe torrefaction conditions were found not necessary in order to save energy during grinding, since strain energy and grinding energy decreased tremendously in the first 5 - 25% anhydrous weight loss. By correlating...... the heating value and mass loss, it was found that wheat straw contained less heating value on mass basis than the other two fuels, but the fraction of energy retained in the torrefied sample as a function of mass loss was very similar for all three biomass. Gas products formed during torrefaction of three...... at 300 ÛC for 1 h were compared, and water was found to be the dominant product during torrefaction. The degradation kinetics of wheat straw was studied in TGA by applying a two-step reaction in series model and taking the mass loss during the initial heating period into account. The model and parameters...

  9. Preliminary analysis of biomass potentially useful for producing biodiesel

    International Nuclear Information System (INIS)

    Cabrera Cifuentes, Gerardo; Burbano Jaramillo, Juan Carlos; Garcia Melo, Jose Isidro

    2011-01-01

    Given that biodiesel is emerging as a viable solution for some energy and environmental problems, research on raw materials appropriate for its production is a matter of growing interest. In this study we present the results of research devoted to preliminary analysis on several vegetable (biomass) species potentially useful for producing biodiesel. The bioprospection zone is a region on the Colombian Pacific coast. The candidate species collected underwent different standardized ASTM tests in order for us to define properties that facilitate their evaluation. Some of the species underwent a transesterification process. Comparisons between the thermo-physical properties of the biofuels obtained and the properties of commercial diesel were carried out. Also, performance tests for these biofuels were conducted in compression ignition engines, particularly evaluating efficiency, fuel consumption, and potency at different RPMs.

  10. Synthesis, Hydrogenation, and Hydrodeoxygenation of Biomass-Derived Furans for Diesel Fuel

    OpenAIRE

    Louie, Ying Lin

    2017-01-01

    Hydrogenation and hydrodeoxygenation (HDO) processes are critical for the chemical conversion of lignocellulosic biomass into liquid transportation fuels such as gasoline, jet, and diesel. Hydro-treatment processes can remove undesired functionalities and reduce the oxygen content in biomass-derived oxygenates to produce candidates suitable for fuel blends. In this study, the liquid phase hydrogenation and hydrogenolysis of several model substrates including, 2,5-dimethylfuran (DMF), 5-methyl...

  11. CO-FIRING COAL: FEEDLOT AND LITTER BIOMASS FUELS

    Energy Technology Data Exchange (ETDEWEB)

    Dr. Kalyan Annamalai; Dr. John Sweeten; Dr. Sayeed Mukhtar

    2000-10-24

    The following are proposed activities for quarter 1 (6/15/00-9/14/00): (1) Finalize the allocation of funds within TAMU to co-principal investigators and the final task lists; (2) Acquire 3 D computer code for coal combustion and modify for cofiring Coal:Feedlot biomass and Coal:Litter biomass fuels; (3) Develop a simple one dimensional model for fixed bed gasifier cofired with coal:biomass fuels; and (4) Prepare the boiler burner for reburn tests with feedlot biomass fuels. The following were achieved During Quarter 5 (6/15/00-9/14/00): (1) Funds are being allocated to co-principal investigators; task list from Prof. Mukhtar has been received (Appendix A); (2) Order has been placed to acquire Pulverized Coal gasification and Combustion 3 D (PCGC-3) computer code for coal combustion and modify for cofiring Coal: Feedlot biomass and Coal: Litter biomass fuels. Reason for selecting this code is the availability of source code for modification to include biomass fuels; (3) A simplified one-dimensional model has been developed; however convergence had not yet been achieved; and (4) The length of the boiler burner has been increased to increase the residence time. A premixed propane burner has been installed to simulate coal combustion gases. First coal, as a reburn fuel will be used to generate base line data followed by methane, feedlot and litter biomass fuels.

  12. A survey of Opportunities for Microbial Conversion of Biomass to Hydrocarbon Compatible Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Jovanovic, Iva; Jones, Susanne B.; Santosa, Daniel M.; Dai, Ziyu; Ramasamy, Karthikeyan K.; Zhu, Yunhua

    2010-09-01

    Biomass is uniquely able to supply renewable and sustainable liquid transportation fuels. In the near term, the Biomass program has a 2012 goal of cost competitive cellulosic ethanol. However, beyond 2012, there will be an increasing need to provide liquid transportation fuels that are more compatible with the existing infrastructure and can supply fuel into all transportation sectors, including aviation and heavy road transport. Microbial organisms are capable of producing a wide variety of fuel and fuel precursors such as higher alcohols, ethers, esters, fatty acids, alkenes and alkanes. This report surveys liquid fuels and fuel precurors that can be produced from microbial processes, but are not yet ready for commercialization using cellulosic feedstocks. Organisms, current research and commercial activities, and economics are addressed. Significant improvements to yields and process intensification are needed to make these routes economic. Specifically, high productivity, titer and efficient conversion are the key factors for success.

  13. Gasification Characteristics of Coal/Biomass Mixed Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Mitchell, Reginald [Stanford Univ., CA (United States). Mechanical Engineering Dept.

    2014-09-01

    A research project was undertaken that had the overall objective of developing the models needed to accurately predict conversion rates of coal/biomass mixtures to synthesis gas under conditions relevant to a commercially-available coal gasification system configured to co-produce electric power as well as chemicals and liquid fuels. In our efforts to accomplish this goal, experiments were performed in an entrained flow reactor in order to produce coal and biomass chars at high heating rates and temperatures, typical of the heating rates and temperatures fuel particles experience in real systems. Mixed chars derived from coal/biomass mixtures containing up to 50% biomass and the chars of the pure coal and biomass components were subjected to a matrix of reactivity tests in a pressurized thermogravimetric analyzer (TGA) in order to obtain data on mass loss rates as functions of gas temperature, pressure and composition as well as to obtain information on the variations in mass specific surface area during char conversion under kinetically-limited conditions. The experimental data were used as targets when determining the unknown parameters in the chemical reactivity and specific surface area models developed. These parameters included rate coefficients for the reactions in the reaction mechanism, enthalpies of formation and absolute entropies of adsorbed species formed on the carbonaceous surfaces, and pore structure coefficients in the model used to describe how the mass specific surface area of the char varies with conversion. So that the reactivity models can be used at high temperatures when mass transport processes impact char conversion rates, Thiele modulus – effectiveness factor relations were also derived for the reaction mechanisms developed. In addition, the reactivity model and a mode of conversion model were combined in a char-particle gasification model that includes the effects of chemical reaction and diffusion of reactive gases through particle

  14. Understory biomass from southern pine forests as a fuel source

    Energy Technology Data Exchange (ETDEWEB)

    Ku, T.T. [Univ. of Arkansas, Monticello, AR (United States); Baker, J.B. [USDA Forest Service, Monticello, AR (United States)

    1993-12-31

    The energy crisis in the US in the late 1970s led to accelerated research on renewable energy resources. The use of woody biomass, harvested from pine forests in the southern US, as a renewable energy source would not only provide an efficient energy alternative to forest industries, but its use would also reduce understory competition and accelerate growth of overstory crop trees. This study was initiated in the early 1980s to investigate the feasibility and applicability of the use of understory vegetation as a possible energy fuel resource. All woody understory vegetation [<14 cm (<5.5 in) in dbh], on 0.2 ha (0.5 ac) plots that represented a range of stand/site conditions of pine stands located in twelve southern Arkansas counties and two northern Louisiana parishes were characterized, quantified, and harvested. Based on the biomass yield from 720 subplots nested within 40 main plots, the top five dominant species in the understory, based on number and size were: Red maple, red oaks, pines, sweetgum, and winged elm. Some other species occurring, but in smaller proportions, were flowering dogwood, beautyberry, white oaks, black gum, wax myrtle, hickories, persimmon, and ashes. Most of these species are deciduous hardwoods that provide high BTU output upon burning. The average yield of chipped understory biomass was 23.5 T/ha with no difference occurring between summer and winter harvests. A predictive model of understory biomass production was developed using a step-wise multivariate regression analysis. In relation to forest type, high density pine stands produced 53% more understory biomass than high density pine-hardwood stands. The average moisture content of biomass was significantly lower when harvested in winter than when harvested in summer.

  15. Pectin-rich biomass as feedstock for fuel ethanol production

    Energy Technology Data Exchange (ETDEWEB)

    Edwards, Meredith C.; Doran-Peterson, Joy [Georgia Univ., Athens, GA (United States). Dept. of Microbiology

    2012-08-15

    The USA has proposed that 30 % of liquid transportation fuel be produced from renewable resources by 2030 (Perlack and Stokes 2011). It will be impossible to reach this goal using corn kernel-based ethanol alone. Pectin-rich biomass, an under-utilized waste product of the sugar and juice industry, can augment US ethanol supplies by capitalizing on this already established feedstock. Currently, pectin-rich biomass is sold (at low value) as animal feed. This review focuses on the three most studied types of pectin-rich biomass: sugar beet pulp, citrus waste and apple pomace. Fermentations of these materials have been conducted with a variety of ethanologens, including yeasts and bacteria. Escherichia coli can ferment a wide range of sugars including galacturonic acid, the primary component of pectin. However, the mixed acid metabolism of E. coli can produce unwanted side products. Saccharomyces cerevisiae cannot naturally ferment galacturonic acid nor pentose sugars but has a homoethanol pathway. Erwinia chrysanthemi is capable of degrading many of the cell wall components of pectin-rich materials, including pectin. Klebsiella oxytoca can metabolize a diverse array of sugars including cellobiose, one degradation product of cellulose. However, both E. chrysanthemi and K. oxytoca produce side products during fermentation, similar to E. coli. Using pectin-rich residues from industrial processes is beneficial because the material is already collected and partially pretreated to facilitate enzymatic deconstruction of the plant cell walls. Using biomass already produced for other purposes is an attractive practice because fewer greenhouse gases (GHG) will be anticipated from land-use changes. (orig.)

  16. CO-FIRING COAL, FEEDLOT, AND LITTER BIOMASS (CFB AND LFB) FUELS IN PULVERIZED FUEL AND FIXED BED BURNERS

    Energy Technology Data Exchange (ETDEWEB)

    Kalyan Annamalai; John Sweeten; Saqib Mukhtar; Ben Thien; Gengsheng Wei; Soyuz Priyadarsan

    2002-01-15

    Intensive animal feeding operations create large amounts of animal waste that must be safely disposed of in order to avoid environmental degradation. Cattle feedlots and chicken houses are two examples. In feedlots, cattle are confined to small pens and fed a high calorie grain diet in preparation for slaughter. In chicken houses, thousands of chickens are kept in close proximity. In both of these operations, millions of tons of manure are produced every year. In this project a co-firing technology is proposed which would use manure that cannot be used for fertilizer, for power generation. Since the animal manure has economic uses as both a fertilizer and as a fuel, it is properly referred to as feedlot biomass (FB) for cow manure, or litter biomass (LB) for chicken manure. The biomass will be used a as a fuel by mixing it with coal in a 90:10 blend and firing it in existing coal fired combustion devices. This technique is known as co-firing, and the high temperatures produced by the coal will allow the biomass to be completely combusted. Therefore, it is the goal of the current research to develop an animal biomass cofiring technology. A cofiring technology is being developed by performing: (1) studies on fundamental fuel characteristics, (2) small scale boiler burner experiments, (3) gasifier experiments, (4) computer simulations, and (5) an economic analysis. The fundamental fuel studies reveal that biomass is not as high a quality fuel as coal. The biomass fuels are higher in ash, higher in moisture, higher in nitrogen and sulfur (which can cause air pollution), and lower in heat content than coal. Additionally, experiments indicate that the biomass fuels have higher gas content, release gases more readily than coal, and less homogeneous. Small-scale boiler experiments revealed that the biomass blends can be successfully fired, and NO{sub x} pollutant emissions produced will be similar to or lower than pollutant emissions when firing coal. This is a surprising

  17. Sustainable Production of Asphalt using Biomass as Primary Process Fuel

    DEFF Research Database (Denmark)

    Bühler, Fabian; Nguyen, Tuong-Van; Elmegaard, Brian

    2016-01-01

    is the heating and drying of aggregate,where natural gas, fuel oil or LPG is burned in a direct-fired rotary dryer. Replacing this energy source with amore sustainable one presents several technical and economic challenges, as high temperatures, short startuptimes and seasonal production variations are required......The production of construction materials is very energy intensive and requires large quantities of fossil fuels.Asphalt is the major road paving material in Europe and is being produced primarily in stationary batch mixasphalt factories. The production process requiring the most energy...... is further evaluated during hours without asphalt production.The challenges of having varying seasonal production can be solved by this integration of the production unitto the utility system. The results show the economic and technical feasibility of using biomass for processheating in the asphalt factory...

  18. Self-deconstructing algae biomass as feedstock for transportation fuels

    Energy Technology Data Exchange (ETDEWEB)

    Davis, Ryan Wesley [Sandia National Lab. (SNL-CA), Livermore, CA (United States). Biomass Science and Conversion Technologies

    2014-09-01

    The potential for producing biofuels from algae has generated much excitement based on projections of large oil yields with relatively little land use. However, numerous technical challenges remain for achieving market parity with conventional non-renewable liquid fuel sources. Among these challenges, the energy intensive requirements of traditional cell rupture, lipid extraction, and residuals fractioning of microalgae biomass have posed significant challenges to the nascent field of algal biotechnology. Our novel approach to address these problems was to employ low cost solution-state methods and biochemical engineering to eliminate the need for extensive hardware and energy intensive methods for cell rupture, carbohydrate and protein solubilization and hydrolysis, and fuel product recovery using consolidated bioprocessing strategies. The outcome of the biochemical deconstruction and conversion process consists of an emulsion of algal lipids and mixed alcohol products from carbohydrate and protein fermentation for co-extraction or in situ transesterification.

  19. Physical Properties of Biomass Fuel Briquette from Oil Palm ...

    African Journals Online (AJOL)

    ADOWIE PERE

    of fuel briquettes in this study in order to supplement the energy mix of the nation. PKS was pulverized and then sieved ... Keywords: Palm kernel shell; Mesocarp fibre; Briquette; Biomass solid fuel; proximate analysis. The major source of energy in most ... Continuous fluctuation in the price of fossil fuel in the world market is ...

  20. Annex 34 : task 1 : analysis of biodiesel options : biomass-derived diesel fuels : final report

    Energy Technology Data Exchange (ETDEWEB)

    McGill, R. [Oak Ridge National Laboratory, TN (United States); Aakko-Saksa, P.; Nylund, N.O. [TransEnergy Consulting Ltd., Helsinki (Finland)

    2009-06-15

    Biofuels are derived from woody biomass, non-woody biomass, and organic wastes. The properties of vegetable oil feedstocks can have profound effects on the properties of the finished biodiesel product. However, all biodiesel fuels have beneficial effects on engine emissions. This report discussed the use of biodiesel fuels as replacements for part of the diesel fuel consumed throughout the world. Biodiesel fuels currently being produced from fatty acid esters today were reviewed, as well as some of the more advanced diesel replacement fuels. The report was produced as part of the International Energy Agency (IEA) Advanced Motor Fuels (AMF) Implementing Agreement Annex 34, and was divided into 14 sections: (1) an introduction, (2) biodiesel and biomass, (3) an explanation of biodiesel, (4) properties of finished biodiesel fuels, (5) exhaust emissions of finished biodiesel fuels and blends, (6) life-cycle emissions and energy, (7) international biodiesel (FAME) technical standards and specifications, (8) growth in production and use of biodiesel fuels, (9) biofuel refineries, (10) process technology, (11) development and status of biorefineries, (12) comparison of options to produce biobased diesel fuels, (13) barriers and gaps in knowledge, and (14) references. 113 refs., 37 tabs., 74 figs.

  1. Estimating externalities of biomass fuel cycles, Report 7

    Energy Technology Data Exchange (ETDEWEB)

    Barnthouse, L.W.; Cada, G.F.; Cheng, M.-D.; Easterly, C.E.; Kroodsma, R.L.; Lee, R.; Shriner, D.S.; Tolbert, V.R.; Turner, R.S.

    1998-01-01

    This report documents the analysis of the biomass fuel cycle, in which biomass is combusted to produce electricity. The major objectives of this study were: (1) to implement the methodological concepts which were developed in the Background Document (ORNL/RFF 1992) as a means of estimating the external costs and benefits of fuel cycles, and by so doing, to demonstrate their application to the biomass fuel cycle; (2) to develop, given the time and resources, a range of estimates of marginal (i.e., the additional or incremental) damages and benefits associated with selected impact-pathways from a new wood-fired power plant, using a representative benchmark technology, at two reference sites in the US; and (3) to assess the state of the information available to support energy decision making and the estimation of externalities, and by so doing, to assist in identifying gaps in knowledge and in setting future research agendas. The demonstration of methods, modeling procedures, and use of scientific information was the most important objective of this study. It provides an illustrative example for those who will, in the future, undertake studies of actual energy options and sites. As in most studies, a more comprehensive analysis could have been completed had budget constraints not been as severe. Particularly affected were the air and water transport modeling, estimation of ecological impacts, and economic valuation. However, the most important objective of the study was to demonstrate methods, as a detailed example for future studies. Thus, having severe budget constraints was appropriate from the standpoint that these studies could also face similar constraints. Consequently, an important result of this study is an indication of what can be done in such studies, rather than the specific numerical estimates themselves.

  2. Experimental setup for combustion characteristics in a diesel engine using derivative fuel from biomass

    International Nuclear Information System (INIS)

    Andi Mulkan; Zainal, Z.A.

    2006-01-01

    Reciprocating engines are normally run on petroleum fuels or diesel fuels. Unfortunately, energy reserves such as gas and oil are decreasing. Today, with renewable energy technologies petroleum or diesel can be reduced and substituted fully or partly by alternative fuels in engine. The objective of this paper is to setup the experimental rig using producer gas from gasification system mix with diesel fuel and fed to a diesel engine. The Yanmar L60AE-DTM single cylinder diesel engine is used in the experiment. A 20 kW downdraft gasifier has been developed to produce gas using cut of furniture wood used as biomass source. Air inlet of the engine has been modified to include the producer gas. An AVL quartz Pressure Transducer P4420 was installed into the engine head to measure pressure inside the cylinder of the engine. Several test were carried out on the downdraft gasifier system and diesel engine. The heating value of the producer gas is about 4 MJ/m 3 and the specific biomass fuel consumption is about 1.5 kg/kWh. Waste cooking oil (WCO) and crude palm oil (CPO) were used as biomass fuel. The pressure versus crank angle diagram for using blend of diesel are presented and compared with using diesel alone. The result shows that the peak pressure is higher. The premixed combustion is lower but have higher mixing controlled combustion. The CO and NO x emission are higher for biomass fuel

  3. Method to produce fuel particles

    International Nuclear Information System (INIS)

    Oizumi, C.H.; Uesugi, J.N.

    1978-01-01

    The invention concerns the manufacture of cladded nuclear fuel particles for HTGR. By adding β-1.4-glucan to Th, U or Pu compounds one obtains a mixture which in the presence of a dispersing agent is kneeded to small spherules, ground and granulated. The spherules are then dried and burnt and later coated. 16 examples explain the details of the manufacture. (UWI) [de

  4. Efficient process for producing saccharides and ethanol from a biomass feedstock

    Science.gov (United States)

    Okeke, Benedict C.; Nanjundaswamy, Ananda K.

    2017-04-11

    Described herein is a process for producing saccharides and ethanol from biomass feedstock that includes (a) producing an enzyme composition by culturing a fungal strain(s) in the presence of a lignocellulosic medium, (b) using the enzyme composition to saccharify the biomass feedstock, and (c) fermenting the saccharified biomass feedstock to produce ethanol. The process is scalable and, in certain aspects, is capable of being deployed on farms, thereby allowing local production of saccharides and ethanol and resulting in a reduction of energy and other costs for farm operators. Optional steps to improve the biomass-to-fuel conversion efficiency are also contemplated, as are uses for byproducts of the process described herein.

  5. Minimally refined biomass fuel. [carbohydrate-water-alcohol mixture

    Energy Technology Data Exchange (ETDEWEB)

    Pearson, R.K.; Hirschfeld, T.B.

    1981-03-26

    A minimally refined fluid composition, suitable as a fuel mixture and derived from biomass material, is comprised of one or more water-soluble carbohydrates such as sucrose, one or more alcohols having less than four carbons, and water. The carbohydrate provides the fuel source; water-solubilizes the carbohydrate; and the alcohol aids in the combustion of the carbohydrate and reduces the viscosity of the carbohydrate/water solution. Because less energy is required to obtain the carbohydrate from the raw biomass than alcohol, an overall energy savings is realized compared to fuels employing alcohol as the primary fuel.

  6. Fuel Pellets from Biomass. Processing, Bonding, Raw Materials

    DEFF Research Database (Denmark)

    Stelte, Wolfgang

    The depletion of fossil fuels and the need to reduce green house gas emissions has resulted in a strong growth of biomass utilization for heat and power production. Attempts to overcome the poor handling properties of biomass, i.e. its low bulk density and inhomogeneous structure, have resulted...

  7. Thermal characteristics of various biomass fuels in a small-scale biomass combustor

    International Nuclear Information System (INIS)

    Al-Shemmeri, T.T.; Yedla, R.; Wardle, D.

    2015-01-01

    Biomass combustion is a mature and reliable technology, which has been used for heating and cooking. In the UK, biomass currently qualifies for financial incentives such as the Renewable Heat Incentive (RHI). Therefore, it is vital to select the right type of fuel for a small-scale combustor to address different types of heat energy needs. In this paper, the authors attempt to investigate the performance of a small-scale biomass combustor for heating, and the impact of burning different biomass fuels on useful output energy from the combustor. The test results of moisture content, calorific value and combustion products of various biomass samples were presented. Results from this study are in general agreement with published data as far as the calorific values and moisture contents are concerned. Six commonly available biomass fuels were tested in a small-scale combustion system, and the factors that affect the performance of the system were analysed. In addition, the study has extended to examine the magnitude and proportion of useful heat, dissipated by convection and radiation while burning different biomass fuels in the small-scale combustor. It is concluded that some crucial factors have to be carefully considered before selecting biomass fuels for any particular heating application. - Highlights: • Six biomass materials combustion performance in a small combustor was examined. • Fuel combustion rate and amount of heat release has varied between materials. • Heat release by radiation, convection and flue gasses varied between materials. • Study helps engineers and users of biomass systems to select right materials

  8. Solid Oxide Fuel Cells coupled with a biomass gasification unit

    Directory of Open Access Journals (Sweden)

    Skrzypkiewicz Marek

    2016-01-01

    Full Text Available A possibility of fuelling a solid oxide fuel cell stack (SOFC with biomass fuels can be realized by coupling a SOFC system with a self-standing gasification unit. Such a solution enables multi-fuel operation, elasticity of the system as well as the increase of the efficiency of small-scale biomass-to-electricity conversion units. A system of this type, consisting of biomass gasification unit, gas purification unit, SOFC stack, anode off-gas afterburner and peripherals was constructed and operated successfully. During the process, biomass fuel (wood chips was gasified with air as gasification agent. The gasifier was capable of converting up to 30 kW of fuel to syngas with efficiencies up to 75%. Syngas leaving the gasification unit is delivered to a medium temperature adsorber for sulphur compounds removal. Steam is added to the purified fuel to maintain steam to carbon ratio higher than 2. The syngas then is passed to a SOFC stack through a fuel preheater. In such a configuration it was possible to operate a commercial 1.3 kW stack within its working regime. Conducted tests confirmed successful operation of a SOFC stack fuelled by biomass-sourced syngas.

  9. A comparison of producer gas, biochar, and activated carbon from two distributed scale thermochemical conversion systems used to process forest biomass

    Science.gov (United States)

    Nathaniel Anderson; J. Greg Jones; Deborah Page-Dumroese; Daniel McCollum; Stephen Baker; Daniel Loeffler; Woodam Chung

    2013-01-01

    Thermochemical biomass conversion systems have the potential to produce heat, power, fuels and other products from forest biomass at distributed scales that meet the needs of some forest industry facilities. However, many of these systems have not been deployed in this sector and the products they produce from forest biomass have not been adequately described or...

  10. Zeolite-catalyzed biomass conversion to fuels and chemicals

    DEFF Research Database (Denmark)

    Taarning, Esben; Osmundsen, Christian Mårup; Yang, Xiaobo

    2011-01-01

    Heterogeneous catalysts have been a central element in the efficient conversion of fossil resources to fuels and chemicals, but their role in biomass utilization is more ambiguous. Zeolites constitute a promising class of heterogeneous catalysts and developments in recent years have demonstrated...... their potential to find broad use in the conversion of biomass. In this perspective we review and discuss the developments that have taken place in the field of biomass conversion using zeolites. Emphasis is put on the conversion of lignocellulosic material to fuels using conventional zeolites as well...

  11. CO-FIRING COAL: FEEDLOT AND LITTER BIOMASS (CFB AND CLB) FUELS IN PULVERIZED FUEL AND FIXED BED BURNERS

    Energy Technology Data Exchange (ETDEWEB)

    Kalyan Annamalai; John Sweeten; Saqib Mukhtar; Ben Thein; Gengsheng Wei; Soyuz Priyadarsan; Senthil Arumugam; Kevin Heflin

    2003-08-28

    Intensive animal feeding operations create large amounts of animal waste that must be safely disposed of in order to avoid environmental degradation. Cattle feedlots and chicken houses are two examples. In feedlots, cattle are confined to small pens and fed a high calorie grain-diet diet in preparation for slaughter. In chicken houses, thousands of chickens are kept in close proximity. In both of these operations, millions of tons of manure are produced every year. The manure could be used as a fuel by mixing it with coal in a 90:10 blend and firing it in an existing coal suspension fired combustion systems. This technique is known as co-firing, and the high temperatures produced by the coal will allow the biomass to be completely combusted. Reburn is a process where a small percentage of fuel called reburn fuel is injected above the NO{sub x} producing, conventional coal fired burners in order to reduce NO{sub x}. The manure could also be used as reburn fuel for reducing NO{sub x} in coal fired plants. An alternate approach of using animal waste is to adopt the gasification process using a fixed bed gasifier and then use the gases for firing in gas turbine combustors. In this report, the cattle manure is referred to as feedlot biomass (FB) and chicken manure as litter biomass (LB). The report generates data on FB and LB fuel characteristics. Co-firing, reburn, and gasification tests of coal, FB, LB, coal: FB blends, and coal: LB blends and modeling on cofiring, reburn systems and economics of use of FB and LB have also been conducted. The biomass fuels are higher in ash, lower in heat content, higher in moisture, and higher in nitrogen and sulfur (which can cause air pollution) compared to coal. Small-scale cofiring experiments revealed that the biomass blends can be successfully fired, and NO{sub x} emissions will be similar to or lower than pollutant emissions when firing coal. Further experiments showed that biomass is twice or more effective than coal when

  12. Will biomass be the environmentally friendly fuel of the future?

    International Nuclear Information System (INIS)

    Hall, D.O.; Scrase, J.I.

    1998-01-01

    Many influential organisations foresee biomass playing a key role in a future, more sustainable, global energy supply matrix. Countries such as Austria, Brazil, Denmark, Finland, Sweden, India, the USA and the UK are actively encouraging the use of biomass for energy, and pushing forward the development of the necessary knowledge and technology for modern biomass energy systems. There is a growing consensus that renewable energy must progressively displace the use of fossil fuels, with fears of global climate change adding urgency to this need. Among the available types of renewable energy biomass is unique in its ability to provide solid, liquid and gaseous fuels which can be stored and transported. The potential resource for bioenergy is large, especially in forest-rich nations, in richer countries where there is a surplus of agricultural land, and in many low latitude countries where high biomass yields are possible. Therefore we expect biomass to be an important fuel of the future, but this cannot be taken for granted. The systems adopted must demonstrate clear environmental and social benefits relative to alternatives if the potential is to be realised. These benefits are not inherent to biomass energy, but depend on site- and fuel cycle-specific factors. Life-cycle analysis and evaluation of external costs are important means for assessing the social and environmental pros and cons of bioenergy systems. (author)

  13. Physical Properties of Biomass Fuel Briquette from Oil Palm Residues

    African Journals Online (AJOL)

    Palm Kernel Shell (PKS) and Mesocarp Fibre (MF) were used for the production of fuel briquettes in this study in order to supplement the energy mix of the nation. PKS was pulverized and then ... and industrial applications. Keywords: Palm kernel shell; Mesocarp fibre; Briquette; Biomass solid fuel; proximate analysis.

  14. 78 FR 49411 - Denial of Petitions for Reconsideration of Regulation of Fuels and Fuel Additives: 2013 Biomass...

    Science.gov (United States)

    2013-08-14

    ...-AR55 Denial of Petitions for Reconsideration of Regulation of Fuels and Fuel Additives: 2013 Biomass... Fuel Additives: 2013 Biomass-Based Diesel Renewable Fuel Volume. DATES: EPA's denials of the petitions... requires that EPA determine the applicable volume of biomass-based diesel to be used in setting annual...

  15. Energy Efficiency of Biogas Produced from Different Biomass Sources

    International Nuclear Information System (INIS)

    Begum, Shahida; Nazri, A H

    2013-01-01

    Malaysia has different sources of biomass like palm oil waste, agricultural waste, cow dung, sewage waste and landfill sites, which can be used to produce biogas and as a source of energy. Depending on the type of biomass, the biogas produced can have different calorific value. At the same time the energy, being used to produce biogas is dependent on transportation distance, means of transportation, conversion techniques and for handling of raw materials and digested residues. An energy systems analysis approach based on literature is applied to calculate the energy efficiency of biogas produced from biomass. Basically, the methodology is comprised of collecting data, proposing locations and estimating the energy input needed to produce biogas and output obtained from the generated biogas. The study showed that palm oil and municipal solid waste is two potential sources of biomass. The energy efficiency of biogas produced from palm oil residues and municipal solid wastes is 1.70 and 3.33 respectively. Municipal solid wastes have the higher energy efficiency due to less transportation distance and electricity consumption. Despite the inherent uncertainties in the calculations, it can be concluded that the energy potential to use biomass for biogas production is a promising alternative.

  16. Catalytic tar removal from biomass producer gas with secondary air

    Energy Technology Data Exchange (ETDEWEB)

    Lammers, G.; Beenackers, A.A.C.M. [University of Groningen (Netherlands). Dept. of Chemical Engineering; Corella, J. [Universidad Complutense, Madrid (Spain)

    1997-12-31

    The effect of air addition on biomass tar conversion in catalytic packed bed crackers was studied using both an isothermal micro reactor and a fluidised bed bench scale biomass gasification set up with down stream tar crackers. The micro reactor was applied for experiments with artificial biomass producer gas containing naphthalene as a model tar compound. Experiments were carried out with inert silica and catalytically active calcined dolomite bed material both with and without air addition. Experimental results with real tar from the fluidised bed bench scale gasification set up were in qualitative agreement with results from the micro reactor experiments. (author)

  17. Biomass pretreatment affects Ustilago maydis in producing itaconic acid

    Directory of Open Access Journals (Sweden)

    Klement Tobias

    2012-04-01

    Full Text Available Abstract Background In the last years, the biotechnological production of platform chemicals for fuel components has become a major focus of interest. Although ligno-cellulosic material is considered as suitable feedstock, the almost inevitable pretreatment of this recalcitrant material may interfere with the subsequent fermentation steps. In this study, the fungus Ustilago maydis was used to produce itaconic acid as platform chemical for the synthesis of potential biofuels such as 3-methyltetrahydrofuran. No studies, however, have investigated how pretreatment of ligno-cellulosic biomass precisely influences the subsequent fermentation by U. maydis. Thus, this current study aims to first characterize U. maydis in shake flasks and then to evaluate the influence of three exemplary pretreatment methods on the cultivation and itaconic acid production of this fungus. Cellulose enzymatically hydrolysed in seawater and salt-assisted organic-acid catalysed cellulose were investigated as substrates. Lastly, hydrolysed hemicellulose from fractionated beech wood was applied as substrate. Results U. maydis was characterized on shake flask level regarding its itaconic acid production on glucose. Nitrogen limitation was shown to be a crucial condition for the production of itaconic acid. For itaconic acid concentrations above 25 g/L, a significant product inhibition was observed. Performing experiments that simulated influences of possible pretreatment methods, U. maydis was only slightly affected by high osmolarities up to 3.5 osmol/L as well as of 0.1 M oxalic acid. The production of itaconic acid was achieved on pretreated cellulose in seawater and on the hydrolysed hemicellulosic fraction of pretreated beech wood. Conclusion The fungus U. maydis is a promising producer of itaconic acid, since it grows as single cells (yeast-like in submerged cultivations and it is extremely robust in high osmotic media and real seawater. Moreover, U. maydis can grow on

  18. A laboratory fuel efficiency and emissions comparison between Tanzanian traditional and improved biomass cooking stoves and alternative fuels

    Science.gov (United States)

    Mitchell, B. R.; Maggio, J. C.; Paterson, K.

    2010-12-01

    Large amounts of aerosols are emitted from domestic biomass burning globally every day. Nearly three billion people cook in their homes using traditional fires and stoves. Biomass is the primary fuel source which results in detrimental levels of indoor air pollution as well as having a strong impact on climate change. Variations in emissions occur depending on the combustion process and stove design as well as the condition and type of fuel used. The three most commonly used fuels for domestic biomass burning are wood, charcoal, and crop residue. In addition to these commonly used fuels and because of the increased difficulty of obtaining charcoal and wood due to a combination of deforestation and new governmental restrictions, alternative fuels are becoming more prevalent. In the Republic of Tanzania a field campaign was executed to test previously adopted and available traditional and improved cooking stoves with various traditional and alternative fuels. The tests were conducted over a two month period and included four styles of improved stoves, two styles of traditional cooking methods, and eight fuel types. The stoves tested include a sawdust stove, ceramic and brick insulated metal stoves, and a mud stove. A traditional three-stone fire was also tested as a benchmark by which to compare the other stoves. Fuel types tested include firewood, charcoal (Acacia), sawdust, pressed briquettes, charcoal dust briquettes, and carbonized crop residue. Water boiling tests were conducted on each stove with associated fuel types during which boiling time, water temperature, CO, CO2, and PM2.5μm emissions were recorded. All tests were conducted on-site in Arusha, Tanzania enabling the use of local materials and fuels under local conditions. It was found that both stove design and fuel type play a critical role in the amount of emissions produced. The most influential design aspect affecting emissions was the size of the combustion chamber in combination with air intake

  19. A study of bonding and failure mechanisms in fuel pellets from different biomass resources

    DEFF Research Database (Denmark)

    Stelte, Wolfgang; Holm, Jens K.; Sanadi, Anand R.

    2011-01-01

    Pelletization of biomass reduces its handling costs, and results in a fuel with a greater structural homogeneity. The aim of the present work was to study the strength and integrity of pellets and relate them to the quality and mechanisms of inter-particular adhesion bonding. The raw materials used...... were: beech, spruce and straw, representing the most common biomass types used for fuel pellet production, i.e. hardwoods, softwoods and grasses, respectively. The results showed that the compression strengths of the pellets were in general higher for pellets produced at higher temperatures, and much...

  20. Handbook for inventorying surface fuels and biomass in the Interior West

    Science.gov (United States)

    James K. Brown; Rick D. Oberheu; Cameron M. Johnston

    1982-01-01

    Presents comprehensive procedures for inventorying weight per unit area of living and dead surface vegetation, to facilitate estimation of biomass and appraisal of fuels. Provides instructions for conducting fieldwork and calculating estimates of downed woody material, forest floor litter and duff, herbaceous vegetation, shrubs, and small conifers. Procedures produce...

  1. Conditions for the sustainability of biomass based fuel use

    International Nuclear Information System (INIS)

    Reijnders, L.

    2006-01-01

    Sustainability of biomass based fuel use requires that in biomass production erosion and water usage do not exceed addition to stocks of soil and water and that levels of nutrients and organic matter in soils do not decrease. Levels of volatile carbon compounds and N 2 O in the atmosphere should remain unaffected. To maintain ecosystems services of nature useful to mankind, restriction of biomass production to degraded and currently fallow land is to be preferred. Also sustainability of biomass-for-energy use requires a high efficiency recycling of nutrients present in ashes and low emissions of persistent organics, acidifying compounds and heavy metals due to biomass combustion. Meeting such conditions requires major efforts

  2. Supercritical Fluids Processing of Biomass to Chemicals and Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Olson, Norman K. [Iowa State Univ., Ames, IA (United States)

    2011-09-28

    The main objective of this project is to develop and/or enhance cost-effective methodologies for converting biomass into a wide variety of chemicals, fuels, and products using supercritical fluids. Supercritical fluids will be used both to perform reactions of biomass to chemicals and products as well as to perform extractions/separations of bio-based chemicals from non-homogeneous mixtures. This work supports the Biomass Program’s Thermochemical Platform Goals. Supercritical fluids are a thermochemical approach to processing biomass that, while aligned with the Biomass Program’s interests in gasification and pyrolysis, offer the potential for more precise and controllable reactions. Indeed, the literature with respect to the use of water as a supercritical fluid frequently refers to “supercritical water gasification” or “supercritical water pyrolysis.”

  3. Pollutants generated by the combustion of solid biomass fuels

    CERN Document Server

    Jones, Jenny M; Ma, Lin; Williams, Alan; Pourkashanian, Mohamed

    2014-01-01

    This book considers the pollutants formed by the combustion of solid biomass fuels. The availability and potential use of solid biofuels is first discussed because this is the key to the development of biomass as a source of energy.This is followed by details of the methods used for characterisation of biomass and their classification.The various steps in the combustion mechanisms are given together with a compilation of the kinetic data. The chemical mechanisms for the formation of the pollutants: NOx, smoke and unburned hydrocarbons, SOx, Cl compounds, and particulate metal aerosols

  4. Synthetic and Biomass Alternate Fueling in Aviation

    Science.gov (United States)

    Hendricks, R. C.; Bushnell, D. M.

    2009-01-01

    While transportation fueling can accommodate a broad range of alternate fuels, aviation fueling needs are specific, such as the fuel not freezing at altitude or become too viscous to flow properly or of low bulk energy density that shortens range. The fuel must also be compatible with legacy aircraft, some of which are more than 50 years old. Worldwide, the aviation industry alone uses some 85-95 billion gallons of hydrocarbon-based fossil fuel each year, which is about 10% of the transportation industry. US civil aviation alone consumes nearly 14 billion gallons. The enormity of the problem becomes overwhelming, and the aviation industry is taking alternate fueling issues very seriously. Biofuels (algae, cyanobacteria, halophytes, weeds that use wastelands, wastewater and seatwater), when properly sourced, have the capacity to be drop-in fuel replacements for petroleum fuels. As such, biojet from such sources solves the aviation CO2 emissions issue without the downsides of 'conventional' biofuels, such as competing with food and fresh water resources. Of the many current fundamental problems, the major biofuel problem is cost. Both research and development and creative engineering are required to reduce these biofuels costs. Research is also ongoing in several 'improvement' areas including refining/processing and biologics with greater disease resistance, greater bio-oil productivity, reduced water/nutrient requirements, etc. The authors' current research is aimed at aiding industry efforts in several areas. They are considering different modeling approaches, growth media and refining approaches, different biologic feedstocks, methods of sequestering carbon in the processes, fuel certification for aviation use and, overall, ensuring that biofuels are feasible from all aspects - operability, capacity, carbon cycle and financial. The authors are also providing common discussion grounds/opportunities for the various parties, disciplines and concerned organization to

  5. Combustion of biomass-derived, low caloric value, fuel gas in a gasturbine combustor

    Energy Technology Data Exchange (ETDEWEB)

    Andries, J.; Hoppesteyn, P.D.J.; Hein, K.R.G. [Technische Univ. Delf (Netherlands)

    1998-09-01

    The use of biomass and biomass/coal mixtures to produce electricity and heat reduces the net emissions of CO{sub 2}, contributes to the restructuring of the agricultural sector, helps to reduce the waste problem and saves finite fossil fuel reserves. Pressurised fluidised bed gasification followed by an adequate gas cleaning system, a gas turbine and a steam turbine, is a potential attractive way to convert biomass and biomass/coal mixtures. To develop and validate mathematical models, which can be used to design and operate Biomass-fired Integrated Gasification Combined Cycle (BIGCC) systems, a Process Development Unit (PPDU) with a maximum thermal capacity of 1.5 MW{sub th}, located at the Laboratory for Thermal Power Engineering of the Delft University of Technology in The Netherlands is being used. The combustor forms an integral part of this facility. Recirculated flue gas is used to cool the wall of the combustor. (orig.)

  6. Biomass - alternative renewable energy source to the fossil fuels

    OpenAIRE

    Koruba Dorota; Piotrowski Jerzy Zbigniew; Latosińska Jolanta

    2017-01-01

    The article presents the fossil fuels combustion effects in terms of the dangers of increasing CO2 concentration in the atmosphere. Based on the bibliography review the negative impact of increased carbon dioxide concentration on the human population is shown in the area of the external environment, particularly in terms of the air pollution and especially the impact on human health. The paper presents biomass as the renewable energy alternative source to fossil fuels which combustion gives a...

  7. Preliminary evaluation of fuel oil produced from pyrolysis of waste ...

    African Journals Online (AJOL)

    It could be refined further to produce domestic kerosene and gasoline. The physical and structural properties of the fuel oil produced compared favorably with that of Aviation fuel JP-4 (a wide-cut US Air force fuel). Presently African countries are importing aviation fuels. The fuel oil produced from the pyrolysis of waste water ...

  8. Transportation Energy Futures Series. Projected Biomass Utilization for Fuels and Power in a Mature Market

    Energy Technology Data Exchange (ETDEWEB)

    Ruth, M. [National Renewable Energy Lab. (NREL), Golden, CO (United States); Mai, T. [National Renewable Energy Lab. (NREL), Golden, CO (United States); Newes, E. [National Renewable Energy Lab. (NREL), Golden, CO (United States); Aden, A. [National Renewable Energy Lab. (NREL), Golden, CO (United States); Warner, E. [National Renewable Energy Lab. (NREL), Golden, CO (United States); Uriarte, C. [National Renewable Energy Lab. (NREL), Golden, CO (United States); Inman, D. [National Renewable Energy Lab. (NREL), Golden, CO (United States); Simpkins, T. [National Renewable Energy Lab. (NREL), Golden, CO (United States); Argo, A. [National Renewable Energy Lab. (NREL), Golden, CO (United States)

    2013-03-01

    The viability of biomass as transportation fuel depends upon the allocation of limited resources for fuel, power, and products. By focusing on mature markets, this report identifies how biomass is projected to be most economically used in the long term and the implications for greenhouse gas (GHG) emissions and petroleum use. In order to better understand competition for biomass between these markets and the potential for biofuel as a market-scale alternative to petroleum-based fuels, this report presents results of a micro-economic analysis conducted using the Biomass Allocation and Supply Equilibrium (BASE) modeling tool. The findings indicate that biofuels can outcompete biopower for feedstocks in mature markets if research and development targets are met. The BASE tool was developed for this project to analyze the impact of multiple biomass demand areas on mature energy markets. The model includes domestic supply curves for lignocellulosic biomass resources, corn for ethanol and butanol production, soybeans for biodiesel, and algae for diesel. This is one of a series of reports produced as a result of the Transportation Energy Futures (TEF) project, a Department of Energy-sponsored multi-agency project initiated to pinpoint underexplored strategies for abating GHGs and reducing petroleum dependence related to transportation.

  9. Waste biomass toward hydrogen fuel supply chain management for electricity: Malaysia perspective

    Science.gov (United States)

    Zakaria, Izatul Husna; Ibrahim, Jafni Azhan; Othman, Abdul Aziz

    2016-08-01

    Green energy is becoming an important aspect of every country in the world toward energy security by reducing dependence on fossil fuel import and enhancing better life quality by living in the healthy environment. This conceptual paper is an approach toward determining physical flow's characteristic of waste wood biomass in high scale plantation toward producing gas fuel for electricity using gasification technique. The scope of this study is supply chain management of syngas fuel from wood waste biomass using direct gasification conversion technology. Literature review on energy security, Malaysia's energy mix, Biomass SCM and technology. This paper uses the theoretical framework of a model of transportation (Lumsden, 2006) and the function of the terminal (Hulten, 1997) for research purpose. To incorporate biomass unique properties, Biomass Element Life Cycle Analysis (BELCA) which is a novel technique develop to understand the behaviour of biomass supply. Theoretical framework used to answer the research questions are Supply Chain Operations Reference (SCOR) framework and Sustainable strategy development in supply chain management framework

  10. Transportation Energy Futures Series: Projected Biomass Utilization for Fuels and Power in a Mature Market

    Energy Technology Data Exchange (ETDEWEB)

    Ruth, M.; Mai, T.; Newes, E.; Aden, A.; Warner, E.; Uriarte, C.; Inman, D.; Simpkins, T.; Argo, A.

    2013-03-01

    The viability of biomass as transportation fuel depends upon the allocation of limited resources for fuel, power, and products. By focusing on mature markets, this report identifies how biomass is projected to be most economically used in the long term and the implications for greenhouse gas (GHG) emissions and petroleum use. In order to better understand competition for biomass between these markets and the potential for biofuel as a market-scale alternative to petroleum-based fuels, this report presents results of a micro-economic analysis conducted using the Biomass Allocation and Supply Equilibrium (BASE) modeling tool. The findings indicate that biofuels can outcompete biopower for feedstocks in mature markets if research and development targets are met. The BASE tool was developed for this project to analyze the impact of multiple biomass demand areas on mature energy markets. The model includes domestic supply curves for lignocellulosic biomass resources, corn for ethanol and butanol production, soybeans for biodiesel, and algae for diesel. This is one of a series of reports produced as a result of the Transportation Energy Futures (TEF) project, a Department of Energy-sponsored multi-agency project initiated to pinpoint underexplored strategies for abating GHGs and reducing petroleum dependence related to transportation.

  11. Electrocatalytic upgrading of biomass pyrolysis oils to chemical and fuel

    Science.gov (United States)

    Lam, Chun Ho

    The present project's aim is to liquefy biomass through fast pyrolysis and then upgrade the resulting "bio-oil" to renewable fuels and chemicals by intensifying its energy content using electricity. This choice reflects three points: (a) Liquid hydrocarbons are and will long be the most practical fuels and chemical feedstocks because of their energy density (both mass and volume basis), their stability and relative ease of handling, and the well-established infrastructure for their processing, distribution and use; (b) In the U.S., the total carbon content of annually harvestable, non-food biomass is significantly less than that in a year's petroleum usage, so retention of plant-captured carbon is a priority; and (c) Modern technologies for conversion of sunlight into usable energy forms---specifically, electrical power---are already an order of magnitude more efficient than plants are at storing solar energy in chemical form. Biomass fast pyrolysis (BFP) generates flammable gases, char, and "bio-oil", a viscous, corrosive, and highly oxygenated liquid consisting of large amounts of acetic acid and water together with hundreds of other organic compounds. With essentially the same energy density as biomass and a tendency to polymerize, this material cannot practically be stored or transported long distances. It must be upgraded by dehydration, deoxygenation, and hydrogenation to make it both chemically and energetically compatible with modern vehicles and fuels. Thus, this project seeks to develop low cost, general, scalable, robust electrocatalytic methods for reduction of bio-oil into fuels and chemicals.

  12. Efficient Fuel Pretreatment: Simultaneous Torrefaction and Grinding of Biomass

    DEFF Research Database (Denmark)

    Saleh, Suriyati Binti; Hansen, Brian Brun; Jensen, Peter Arendt

    2013-01-01

    Combining torrefaction and grinding of biomass in one reactor may be an attractive fuel pretreatment process. A combined laboratory torrefaction and ball mill reactor has been constructed for studies of the influence of temperature and residence time on the product yields and particle size...

  13. Biomass and fuel characteristics of chaparral in southern California

    Science.gov (United States)

    J.C. Regelbrugge; S.G. Conard

    2002-01-01

    Knowledge of biomass components and fuel characteristics of southern California chaparral plant communities is important for planning prescribed fires, suppressing wildfires, managing the fire regime, and understanding the ecological interactions between fire and chaparral community development and succession. To improve our understanding of the relationship between...

  14. Respiratory effects of biomass fuel combustion on rural fish smokers ...

    African Journals Online (AJOL)

    Respiratory effects of biomass fuel combustion on rural fish smokers in a Nigerian fishing settlement: a case control study. Paul Dienye, Alex Akani, Ita Okokon. Abstract. Backgroud: The aim was to study the prevalence of respiratory symptoms and assess the lung function of fish smokers in Nigeria. Methods: A case control ...

  15. Fuels and chemicals from biomass using solar thermal energy

    Science.gov (United States)

    Giori, G.; Leitheiser, R.; Wayman, M.

    1981-01-01

    The significant nearer term opportunities for the application of solar thermal energy to the manufacture of fuels and chemicals from biomass are summarized, with some comments on resource availability, market potential and economics. Consideration is given to the production of furfural from agricultural residues, and the role of furfural and its derivatives as a replacement for petrochemicals in the plastics industry.

  16. Thermodynamic simulation of biomass gas steam reforming for a solid oxide fuel cell (SOFC system

    Directory of Open Access Journals (Sweden)

    A. Sordi

    2009-12-01

    Full Text Available This paper presents a methodology to simulate a small-scale fuel cell system for power generation using biomass gas as fuel. The methodology encompasses the thermodynamic and electrochemical aspects of a solid oxide fuel cell (SOFC, as well as solves the problem of chemical equilibrium in complex systems. In this case the complex system is the internal reforming of biomass gas to produce hydrogen. The fuel cell input variables are: operational voltage, cell power output, composition of the biomass gas reforming, thermodynamic efficiency, electrochemical efficiency, practical efficiency, the First and Second law efficiencies for the whole system. The chemical compositions, molar flows and temperatures are presented to each point of the system as well as the exergetic efficiency. For a molar water/carbon ratio of 2, the thermodynamic simulation of the biomass gas reforming indicates the maximum hydrogen production at a temperature of 1070 K, which can vary as a function of the biomass gas composition. The comparison with the efficiency of simple gas turbine cycle and regenerative gas turbine cycle shows the superiority of SOFC for the considered electrical power range.

  17. Highly selective condensation of biomass-derived methyl ketones as a source of aviation fuel.

    Science.gov (United States)

    Sacia, Eric R; Balakrishnan, Madhesan; Deaner, Matthew H; Goulas, Konstantinos A; Toste, F Dean; Bell, Alexis T

    2015-05-22

    Aviation fuel (i.e., jet fuel) requires a mixture of C9 -C16 hydrocarbons having both a high energy density and a low freezing point. While jet fuel is currently produced from petroleum, increasing concern with the release of CO2 into the atmosphere from the combustion of petroleum-based fuels has led to policy changes mandating the inclusion of biomass-based fuels into the fuel pool. Here we report a novel way to produce a mixture of branched cyclohexane derivatives in very high yield (>94 %) that match or exceed many required properties of jet fuel. As starting materials, we use a mixture of n-alkyl methyl ketones and their derivatives obtained from biomass. These synthons are condensed into trimers via base-catalyzed aldol condensation and Michael addition. Hydrodeoxygenation of these products yields mixtures of C12 -C21 branched, cyclic alkanes. Using models for predicting the carbon number distribution obtained from a mixture of n-alkyl methyl ketones and for predicting the boiling point distribution of the final mixture of cyclic alkanes, we show that it is possible to define the mixture of synthons that will closely reproduce the distillation curve of traditional jet fuel. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  18. Investigation of Continuous Gas Engine CHP Operation on Biomass Producer Gas

    DEFF Research Database (Denmark)

    Ahrenfeldt, Jesper; Henriksen, Ulrik Birk; Jensen, Torben Kvist

    2005-01-01

    investigated. The engine and the plant are equipped with continuously data acquisition that monitors the operation including the composition of the producer gas and the flow. Producer gas properties and contaminations have been investigated. No detectable tar or particle content was observed......More than 2000 hours of gas engine operation with producer gas from biomass as fuel has been conducted on the gasification CHP demonstration and research plant, named “Viking” at the Technical University of Denmark. The gas engine is an integrated part of the entire gasification plant. The excess...

  19. Environmental Life Cycle Implications of Fuel Oxygenate Production from California Biomass

    Energy Technology Data Exchange (ETDEWEB)

    Kadam, K. L. (National Renewable Energy Laboratory); Camobreco, V. J.; Glazebrook, B. E. (Ecobalance Inc.); Forrest, L. H.; Jacobson, W. A. (TSS Consultants); Simeroth, D. C. (California Air Resources Board); Blackburn, W. J. (California Energy Commission); Nehoda, K. C. (California Department of Forestry and Fire Protection)

    1999-05-20

    Historically, more than 90% of the excess agricultural residue produced in California (approximately 10 million dry metric tons per year) has been disposed through open-field burning. Concerns about air quality have prompted federal, state, and local air quality agencies to tighten regulations related to this burning and to look at disposal alternatives. One use of this biomass is as an oxygenated fuel. This report focuses on quantifying and comparing the comprehensive environmental flows over the life cycles of two disposal scenarios: (1) burning the biomass, plus producing and using MTBE; and (2) converting and using ETBE.

  20. Romania, producer and consumer of nuclear fuel

    International Nuclear Information System (INIS)

    Iuhas, Tiberius

    1998-01-01

    A historical sketch of the activity of Romanian Rare Metals Enterprises is presented stressing the valorization of rare metals like: - radioactive metals, uranium and thorium; - dispersed rare metals, molybdenum, monazite; - heavy and refractory metals, titanium and zirconium; rare earths, lanthanides and yttrics. The beginning and developing of research in the nuclear field is in closed relation to the existence on the domestic territory of important uranium ores the mining of which begun early in 1954. The exploitation of Baita-Bihor orebody was followed by that at Ciudanovita, Natra and Dobrei ores in Caras-Severin county. Concomitantly with the ore mining, geological research was developed covering vast areas of country's surface and using advanced investigation tools suitable for increasing depths. The next step in the nuclear fuel program was made by building a uranium concentrate (as ammonium or sodium diuranate) plant. Two purification units for processing the uranium concentrate to sintered uranium dioxide powder were completed and commissioned at Feldioara in 1986. The quality of the uranium dioxide product meets the quality standards requirements for CANDU type nuclear fuel as certified in 1994. Currently, part of the fuel load of Cernavoda reactor is fuel element clusters produced by Nuclear Fuel Plant at Pitesti of sintered powder processed at Feldioara. A list of strategic objectives of the Uranium National Company is presented among which: - maintaining the uranium mining and milling activities in close relation with the fuel requirements of Cernavoda NPP; continuing geological research in promising zones, to find new uranium orebodies, easy to mill cost effectively; decreasing the environmental impact in the geological research areas, in mining and transport affected areas and in the processing plants. The fuel demand of current operation of Cernavoda NPP Unit 1 as well as of future Unit 2 after commissioning are and will be satisfied by the

  1. Evaluation of Various Solid Biomass Fuels Using Thermal Analysis and Gas Emission Tests

    Directory of Open Access Journals (Sweden)

    Hiroshi Koseki

    2011-04-01

    Full Text Available Various recently proposed biomass fuels are reviewed from the point of view of their safety. Many biomass materials are proposed for use as fuels, such as refuse derived fuel (RDF, wood chips, coal-wood mixtures, etc. However, these fuels have high energy potentials and can cause fires and explosions. We have experienced many such incidents. It is very difficult to extinguish fires in huge piles of biomass fuel or storage facilities. Here current studies on heat generation for these materials and proposed evaluation methods for these new developing materials in Japan are introduced, which are consistent with measurements using highly sensitive calorimeters such as C80, or TAM, and gas emission tests. The highly sensitive calorimeters can detect small heat generation between room temperature and 80 °C, due to fermentation or other causes. This heat generation sometimes initiates real fires, and also produces combustible gases which can explode if fuel is stored in silos or indoor storage facilities.

  2. From biomass to fuels: Hydrotreating of oxygenated compounds

    Energy Technology Data Exchange (ETDEWEB)

    Gandarias, I.; Barrio, V.L.; Requies, J.; Arias, P.L.; Cambra, J.F.; Gueemez, M.B. [School of Engineering (UPV/EHU), c/ Alameda Urquijo s/n, 48013 Bilbao (Spain)

    2008-07-15

    Biomass is a renewable alternative to fossil raw materials in the production of liquid fuels and chemicals. Pyrolyzed biomass derived liquids contain oxygenated molecules that need to be removed to improve the stability of these liquids. A hydrotreating process, hydrodeoxygenation (HDO), is commonly used for this purpose. Thus, the aim of this work is to examine the role of advanced NiMo and NiW catalysts developed for HDS purposes in a HDO reaction. In addition, product distribution and catalyst stability are studied against changes in the feed composition, the solvent, and the catalyst pretreatment. (author)

  3. Biological production of liquid fuels from biomass

    Energy Technology Data Exchange (ETDEWEB)

    None

    1982-01-01

    A scheme for the production of liquid fuels from renewable resources such as poplar wood and lignocellulosic wastes from a refuse hydropulper was investigated. The particular scheme being studied involves the conversion of a cellulosic residue, resulting from a solvent delignified lignocellulosic feed, into either high concentration sugar syrups or into ethyl and/or butyl alcohol. The construction of a pilot apparatus for solvent delignifying 150 g samples of lignocellulosic feeds was completed. Also, an analysis method for characterizing the delignified product has been selected and tested. This is a method recommended in the Forage Fiber Handbook. Delignified samples are now being prepared and tested for their extent of delignification and susceptibility to enzyme hydrolysis. Work is continuing on characterizing the cellulase and cellobiase enzyme systems derived from the YX strain of Thermomonospora.

  4. A life cycle assessment of options for producing synthetic fuel via pyrolysis.

    Science.gov (United States)

    Vienescu, D N; Wang, J; Le Gresley, A; Nixon, J D

    2018-02-01

    The aim of this study was to investigate the sustainability of producing synthetic fuels from biomass using thermochemical processing and different upgrading pathways. Life cycle assessment (LCA) models consisting of biomass collection, transportation, pre-treatment, pyrolysis and upgrading stages were developed. To reveal the environmental impacts associated with greater post-processing to achieve higher quality fuels, six different bio-oil upgrading scenarios were analysed and included esterification, ketonisation, hydrotreating and hydrocracking. Furthermore, to take into account the possible ranges in LCA inventory data, expected, optimistic and pessimistic values for producing and upgrading pyrolysis oils were evaluated. We found that the expected carbon dioxide equivalent emissions could be as high as 6000 gCO 2e /kg of upgraded fuel, which is greater than the emissions arising from the use of diesel fuel. Other environmental impacts occurring from the fuel production process are outlined, such as resource depletion, acidification and eutrophication. Copyright © 2017 Elsevier Ltd. All rights reserved.

  5. Hydrocarbon bio-jet fuel from bioconversion of poplar biomass: life cycle assessment.

    Science.gov (United States)

    Budsberg, Erik; Crawford, Jordan T; Morgan, Hannah; Chin, Wei Shan; Bura, Renata; Gustafson, Rick

    2016-01-01

    Bio-jet fuels compatible with current aviation infrastructure are needed as an alternative to petroleum-based jet fuel to lower greenhouse gas emissions and reduce dependence on fossil fuels. Cradle to grave life cycle analysis is used to investigate the global warming potential and fossil fuel use of converting poplar biomass to drop-in bio-jet fuel via a novel bioconversion platform. Unique to the biorefinery designs in this research is an acetogen fermentation step. Following dilute acid pretreatment and enzymatic hydrolysis, poplar biomass is fermented to acetic acid and then distilled, hydroprocessed, and oligomerized to jet fuel. Natural gas steam reforming and lignin gasification are proposed to meet hydrogen demands at the biorefineries. Separate well to wake simulations are performed using the hydrogen production processes to obtain life cycle data. Both biorefinery designs are assessed using natural gas and hog fuel to meet excess heat demands. Global warming potential of the natural gas steam reforming and lignin gasification bio-jet fuel scenarios range from CO2 equivalences of 60 to 66 and 32 to 73 g MJ(-1), respectively. Fossil fuel usage of the natural gas steam reforming and lignin gasification bio-jet fuel scenarios range from 0.78 to 0.84 and 0.71 to 1.0 MJ MJ(-1), respectively. Lower values for each impact category result from using hog fuel to meet excess heat/steam demands. Higher values result from using natural gas to meet the excess heat demands. Bio-jet fuels produced from the bioconversion of poplar biomass reduce the global warming potential and fossil fuel use compared with petroleum-based jet fuel. Production of hydrogen is identified as a major source of greenhouse gas emissions and fossil fuel use in both the natural gas steam reforming and lignin gasification bio-jet simulations. Using hog fuel instead of natural gas to meet heat demands can help lower the global warming potential and fossil fuel use at the biorefineries.

  6. Impacts of Particulate Pollution from Fossil Fuel and Biomass Burnings on the Air Quality and Human Health in Southeast Asia

    Science.gov (United States)

    Lee, H. H.; Iraqui, O.; Gu, Y.; Yim, S. H. L.; Wang, C.

    2017-12-01

    Severe haze events in Southeast Asia have attracted the attention of governments and the general public in recent years, due to their impact on local economies, air quality and public health. Widespread biomass burning activities are a major source of severe haze events in Southeast Asia. On the other hand, particulate pollutants from human activities other than biomass burning also play an important role in degrading air quality in Southeast Asia. These pollutants can be locally produced or brought in from neighboring regions by long-range transport. A better understanding of the respective contributions of fossil fuel and biomass burning aerosols to air quality degradation becomes an urgent task in forming effective air pollution mitigation policies in Southeast Asia. In this study, to examine and quantify the contributions of fossil fuel and biomass burning aerosols to air quality and visibility degradation over Southeast Asia, we conducted three numerical simulations using the Weather Research and Forecasting (WRF) model coupled with a chemistry component (WRF-Chem). These simulations were driven by different aerosol emissions from: (a) fossil fuel burning only, (b) biomass burning only, and (c) both fossil fuel and biomass burning. By comparing the simulation results, we examined the corresponding impacts of fossil fuel and biomass burning emissions, separately and combined, on the air quality and visibility of the region. The results also showed that the major contributors to low visibility days (LVDs) among 50 ASEAN cities are fossil fuel burning aerosols (59%), while biomass burning aerosols provided an additional 13% of LVDs in Southeast Asia. In addition, the number of premature mortalities among ASEAN cities has increased from 4110 in 2002 to 6540 in 2008, caused primarily by fossil fuel burning aerosols. This study suggests that reductions in both fossil fuel and biomass burning emissions are necessary to improve the air quality in Southeast Asia.

  7. Life cycle assessment of biomass-to-liquid fuels - Final report

    Energy Technology Data Exchange (ETDEWEB)

    Jungbluth, N.; Buesser, S.; Frischknecht, R.; Tuchschmid, M.

    2008-02-15

    This study elaborates a life cycle assessment of using of BTL-fuels (biomass-to-liquid). This type of fuel is produced in synthesis process from e.g. wood, straw or other biomass. The life cycle inventory data of the fuel provision with different types of conversion concepts are based on the detailed life cycle assessment compiled and published within a European research project. The inventory of the fuel use emissions is based on information published by automobile manufacturers on reductions due to the use of BTL-fuels. Passenger cars fulfilling the EURO3 emission standards are the basis for the comparison. The life cycle inventories of the use of BTL-fuels for driving in passenger cars are investigated from cradle to grave. The full life cycle is investigated with the transportation of one person over one kilometre (pkm) as a functional unit. This includes all stages of the life cycle of a fuel (biomass and fuel production, distribution, combustion) and the necessary infrastructure (e.g. tractors, conversion plant, cars and streets). The use of biofuels is mainly promoted for the reason of reducing the climate change impact and the use of scarce non-renewable resources e.g. crude oil. The possible implementation of BTL-fuel production processes would potentially help to achieve this goal. The emissions of greenhouse gases due to transport services could be reduced by 28% to 69% with the BTL-processes using straw, forest wood or short-rotation wood as a biomass input. The reduction potential concerning non-renewable energy resources varies between 37% und 61%. A previous study showed that many biofuels cause higher environmental impacts than fossil fuels if several types of ecological problems are considered. The study uses two single score impact assessment methods for the evaluation of the overall environmental impacts, namely the Eco-indicator 99 (H,A) and the Swiss ecological scarcity 2006 method. The transportation with the best BTL-fuel from short

  8. Catalytic destruction of tar in biomass derived producer gas

    International Nuclear Information System (INIS)

    Zhang Ruiqin; Brown, Robert C.; Suby, Andrew; Cummer, Keith

    2004-01-01

    The purpose of this study is to investigate catalytic destruction of tar formed during gasification of biomass, with the goal of improving the quality of the producer gas. This work focuses on nickel based catalysts treated with alkali in an effort to promote steam gasification of the coke that deposits on catalyst surfaces. A tar conversion system consisting of a guard bed and catalytic reactor was designed to treat the producer gas from an air blown, fluidized bed biomass gasifier. The guard bed used dolomite to crack the heavy tars. The catalytic reactor was used to evaluate three commercial steam reforming catalysts. These were the ICI46-1 catalyst from Imperial Chemical Industry and Z409 and RZ409 catalysts from Qilu Petrochemical Corp. in China. A 0.5-3 l/min slipstream from a 5 tpd biomass gasifier was used to test the tar conversion system. Gas and tar were sampled before and after the tar conversion system to evaluate the effectiveness of the system. Changes in gas composition as functions of catalytic bed temperature, space velocity and steam/TOC (total organic carbon) ratio are presented. Structural changes in the catalysts during the tests are also described

  9. Compositional and Agronomic Evaluation of Sorghum Biomass as a Potential Feedstock for Renewable Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Dahlberg, J.; Wolfrum, E.; Bean, B.; Rooney, W. L.

    2011-12-01

    One goal of the Biomass Research and Development Technical Advisory Committee was to replace 30% of current U.S. petroleum consumption with biofuels by 2030. This will take mixtures of various feedstocks; an annual biomass feedstock such as sorghum will play an important role in meeting this goal. Commercial forage sorghum samples collected from field trials grown in Bushland, TX in 2007 were evaluated for both agronomic and compositional traits. Biomass compositional analysis of the samples was performed at the National Renewable Energy Lab in Golden, CO following NREL Laboratory Analytical Procedures. Depending on the specific cultivar, several additional years of yield data for this location were considered in establishing agronomic potential. Results confirm that sorghum forages can produce high biomass yields over multiple years and varied growing conditions. In addition, the composition of sorghum shows significant variation, as would be expected for most crops. Using theoretical estimates for ethanol production, the sorghum commercial forages examined in this study could produce an average of 6147 L ha{sup -1} of renewable fuels. Given its genetic variability, a known genomic sequence, a robust seed industry, and biomass composition, sorghum will be an important annual feedstock to meet the alternative fuel production goals legislated by the US Energy Security Act of 2007.

  10. Biomass yield and fuel characteristics of short-rotation coppice (willow, poplar, empress tree)

    Energy Technology Data Exchange (ETDEWEB)

    Maier, J.; Vetter, R. [Institute for Land Management Compatible to Environmental Requirements, Muellheim (Germany)

    2004-07-01

    In two pedo-climatic different regions in the state of Baden-Wuerttemberg three shortrotation coppices willow, poplar and empress tree were tested with regard to their biomass productivity on arable land and to their properties for energetic use. Between 8 and 13 tons of dry matter per hectare and year could be produced under extensive cultivation conditions, over 15 tons with irrigation. Due to their composition, it can be assumed that their use as solid fuel in a biomass combustor is just as unproblematic as with forest timber. (orig.)

  11. High-performance liquid-catalyst fuel cell for direct biomass-into-electricity conversion.

    Science.gov (United States)

    Liu, Wei; Mu, Wei; Deng, Yulin

    2014-12-01

    Herein, we report high-performance fuel cells that are catalyzed solely by polyoxometalate (POM) solution without any solid metal or metal oxide. The novel design of the liquid-catalyst fuel cells (LCFC) changes the traditional gas-solid-surface heterogeneous reactions to liquid-catalysis reactions. With this design, raw biomasses, such as cellulose, starch, and even grass or wood powders can be directly converted into electricity. The power densities of the fuel cell with switchgrass (dry powder) and bush allamanda (freshly collected) are 44 mW cm(-2) and 51 mW cm(-2) respectively. For the cellulose-based biomass fuel cell, the power density is almost 3000 times higher than that of cellulose-based microbial fuel cells. Unlike noble-metal catalysts, POMs are tolerant to most organic and inorganic contaminants. Therefore, almost any raw biomass can be used directly to produce electricity without prior purification. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  12. H2CAP - Hydrogen assisted catalytic biomass pyrolysis for green fuels

    DEFF Research Database (Denmark)

    Stummann, Magnus Zingler; Høj, Martin; Gabrielsen, Jostein

    Fast pyrolysis of biomass produces a high yield of bio-oil through well-established technologies [1]. To utilizethis oil as liquid fuel the oxygen content must be reduced from 15-30 wt.% down to <1 wt.%, which increases heating value and stability and decreases acidity [1]. Upgrading bio-oil by c......Fast pyrolysis of biomass produces a high yield of bio-oil through well-established technologies [1]. To utilizethis oil as liquid fuel the oxygen content must be reduced from 15-30 wt.% down to ...-oil by catalytic hydrodeoxygenation (HDO) is challenged by severe polymerization and coking upon heating the oil. Alternatively, performing fast pyrolysis in high-pressure hydrogen atmosphere in a fluid bed reactor with a HDO catalyst as bed medium, could immediately stabilize reactive pyrolysis vapors [2...

  13. Potentials of Selected Malaysian Biomasses as Co-Gasification Fuels with Oil Palm Fronds in a Fixed-Bed Downdraft Gasifier

    Directory of Open Access Journals (Sweden)

    Moni Mohamad Nazmi Zaidi

    2014-07-01

    Full Text Available Oil palm frond (OPF has been successfully gasified to produce syngas and has since deemed as a potential source of biomass fuel in Malaysia. However, if OPF is to be utilized as a main fuel for industrial-scale firing/gasification plant, interruption in fuel supply may occur due to numerous reasons, for instance inefficient fuel processing and ineffective transportation. A secondary supporting solid fuel is therefore necessary as a partial component to the main fuel in such cases, where the secondary fuel is combusted with the main fuel to adhere to main fuel shortage. Gasification of two fuels together, known as co-gasification, is practiced worldwide, some in industrial scale. However, current practice utilizes biomass fuel as the secondary fuel to coal in co-gasification. This investigation explores into the feasibility of co-gasifying two biomass fuels together to produce syngas. OPF was chosen as the primary fuel and a selection of Malaysian biomasses were studied to discover their compatibility with OPF in co-gasification. Biomass selection was made using score-and-rank method and their selection criteria are concisely discussed.

  14. Fuel substitution - poverty impacts on biomass fuel suppliers (Uganda, Kenya and Ethiopia)

    International Nuclear Information System (INIS)

    2002-01-01

    Many sub Saharan countries view the increasing use of traditional fuels (primarily charcoal and, to a lesser extent, wood) in urban areas as a major cause of environmental degradation. Governments are concerned about the effects of perceived rising costs of traditional fuels on poor households and seek to reduce those costs. Many are also concerned with the health impacts that using traditional fuels may have in households. In response to this, many governments have prompted a shift from traditional fuels for cooking to kerosene, gas and electricity as substitutes, and to energy-efficient charcoal and wood stoves to reduce these impacts. Such interventions can have major impacts on the livelihoods of people engaged in the production, transport and sale of traditional biomass supplies due to the decline in demand for wood-based fuels. This project will quantify the impact that fuel substitution will have on people engaged in traditional fuel supply, distribution and trade and develop a set of recommendations for Kenya, Ethiopia and Uganda that will recommend ways to mitigate the negative effects of fuel substitution on traditional biomass fuel suppliers. At the same time, it will address how this can be accomplished while mitigating the environmental and health impacts of continued use of traditional fuels. (author)

  15. Effects of Fuel Quantity on Soot Formation Process for Biomass-Based Renewable Diesel Fuel Combustion

    KAUST Repository

    Jing, Wei

    2016-12-01

    Soot formation process was investigated for biomass-based renewable diesel fuel, such as biomass to liquid (BTL), and conventional diesel combustion under varied fuel quantities injected into a constant volume combustion chamber. Soot measurement was implemented by two-color pyrometry under quiescent type diesel engine conditions (1000 K and 21% O2 concentration). Different fuel quantities, which correspond to different injection widths from 0.5 ms to 2 ms under constant injection pressure (1000 bar), were used to simulate different loads in engines. For a given fuel, soot temperature and KL factor show a different trend at initial stage for different fuel quantities, where a higher soot temperature can be found in a small fuel quantity case but a higher KL factor is observed in a large fuel quantity case generally. Another difference occurs at the end of combustion due to the termination of fuel injection. Additionally, BTL flame has a lower soot temperature, especially under a larger fuel quantity (2 ms injection width). Meanwhile, average soot level is lower for BTL flame, especially under a lower fuel quantity (0.5 ms injection width). BTL shows an overall low sooting behavior with low soot temperature compared to diesel, however, trade-off between soot level and soot temperature needs to be carefully selected when different loads are used.

  16. METHANOL PRODUCTION FROM BIOMASS AND NATURAL GAS AS TRANSPORTATION FUEL

    Science.gov (United States)

    Two processes are examined for production of methanol. They are assessed against the essential requirements of a future alternative fuel for road transport: that it (i) is producible in amounts comparable to the 19 EJ of motor fuel annually consumed in the U.S., (ii) minimizes em...

  17. Use of lignocellulosic biomass to produce ethanol. Aprovechamiento de la biomasa lignocelulosica para la produccion de etanol

    Energy Technology Data Exchange (ETDEWEB)

    Oliva, J.M.

    1993-01-01

    Gasohol is an automobile fuel with 10% ethanol and 90% gasoline used in USA. A 20/80% mixture is also used in Brasil. Lignocellulosic biomass can be a source to produce ethanol. It is a mixture of cellulose (30%), Memicellulose (32%), lignine (17%) and other (13%). The fundamentals of the ethanol production process are presented. (Author)

  18. Biomass-powered Solid Oxide Fuel Cells : Experimental and Modeling Studies for System Integrations

    NARCIS (Netherlands)

    Liu, M.

    2013-01-01

    Biomass is a sustainable energy source which, through thermo-chemical processes of biomass gasification, is able to be converted from a solid biomass fuel into a gas mixture, known as syngas or biosyngas. A solid oxide fuel cell (SOFC) is a power generation device that directly converts the chemical

  19. Production of Solid Fuel by Torrefaction Using Coconut Leaves As Renewable Biomass

    Directory of Open Access Journals (Sweden)

    Lola Domnina Bote Pestaño

    2016-11-01

    Full Text Available The reserves of non-renewable energy sources such as coal, crude oil and natural gas are not limitless, they gradually get exhausted and their price continually increases. In the last four decades, researchers have been focusing on alternate fuel resources to meet the ever increasing energy demand and to avoid dependence on crude oil. Amongst different sources of renewable energy, biomass residues hold special promise due to their inherent capability to store solar energy and amenability to subsequent conversion to convenient solid, liquid and gaseous fuels. At present, among the coconut farm wastes such as husks, shell, coir dust and coconut leaves, the latter is considered the most grossly under-utilized by in situ burning in the coconut farm as means of disposal. In order to utilize dried coconut leaves and to improve its biomass properties, this research attempts to produce solid fuel by torrefaction using dried coconut leaves for use as alternative source of energy. Torrefaction is a thermal method for the conversion of biomass operating in the low temperature range of 200oC-300oC under atmospheric conditions in absence of oxygen. Dried coconut leaves were torrefied at different feedstock conditions. The key torrefaction products were collected and analyzed. Physical and combustion characteristics of both torrefied and untorrefied biomass were investigated. Torrefaction of dried coconut leaves significantly improved the heating value compared to that of the untreated biomass.  Proximate compositions of the torrefied biomass also improved and were comparable to coal. The distribution of the products of torrefaction depends highly on the process conditions such as torrefaction temperature and residence time. Physical and combustion characteristics of torrefied biomass were superior making it more suitable for fuel applications. Article History: Received June 24th 2016; Received in revised form August 16th 2016; Accepted 27th 2016; Available

  20. Tar Removal from Biomass Producer Gas by Using Biochar

    DEFF Research Database (Denmark)

    Ravenni, Giulia; Henriksen, Ulrik Birk; Ahrenfeldt, Jesper

    2017-01-01

    The biomass-derived char (biochar) produced in the gasifier as a residue, is a potential solution for removing tars from producer gas. This work investigates the interaction between tar compounds and biochar. Residual biochar from a TwoStage gasifier was tested as bed material in a laboratory setup....... Phenol and naphthalene were chosen as model tars, and entrained in a nitrogen flow. The gaseous stream was sampled before and after the biochar bed to evaluate the extent of conversion. The biochar bed (30g) was tested at 250°C, 500°C and 600°C, with for 3 consecutive hours. The compounds concentration...... in the gas phase was quantified by stable isotope dilution analysis, using Gas Chromatography-Mass Spectrometry (GC-MS). Results showed a significant effect of biochar on the removal of phenol, at all temperatures. Naphthalene was removed less efficiently at higher temperature, and this trend was even more...

  1. Energy efficiency analysis: biomass-to-wheel efficiency related with biofuels production, fuel distribution, and powertrain systems.

    Science.gov (United States)

    Huang, Wei-Dong; Zhang, Y-H Percival

    2011-01-01

    Energy efficiency analysis for different biomass-utilization scenarios would help make more informed decisions for developing future biomass-based transportation systems. Diverse biofuels produced from biomass include cellulosic ethanol, butanol, fatty acid ethyl esters, methane, hydrogen, methanol, dimethyether, Fischer-Tropsch diesel, and bioelectricity; the respective powertrain systems include internal combustion engine (ICE) vehicles, hybrid electric vehicles based on gasoline or diesel ICEs, hydrogen fuel cell vehicles, sugar fuel cell vehicles (SFCV), and battery electric vehicles (BEV). We conducted a simple, straightforward, and transparent biomass-to-wheel (BTW) analysis including three separate conversion elements--biomass-to-fuel conversion, fuel transport and distribution, and respective powertrain systems. BTW efficiency is a ratio of the kinetic energy of an automobile's wheels to the chemical energy of delivered biomass just before entering biorefineries. Up to 13 scenarios were analyzed and compared to a base line case--corn ethanol/ICE. This analysis suggests that BEV, whose electricity is generated from stationary fuel cells, and SFCV, based on a hydrogen fuel cell vehicle with an on-board sugar-to-hydrogen bioreformer, would have the highest BTW efficiencies, nearly four times that of ethanol-ICE. In the long term, a small fraction of the annual US biomass (e.g., 7.1%, or 700 million tons of biomass) would be sufficient to meet 100% of light-duty passenger vehicle fuel needs (i.e., 150 billion gallons of gasoline/ethanol per year), through up to four-fold enhanced BTW efficiencies by using SFCV or BEV. SFCV would have several advantages over BEV: much higher energy storage densities, faster refilling rates, better safety, and less environmental burdens.

  2. Energy efficiency analysis: biomass-to-wheel efficiency related with biofuels production, fuel distribution, and powertrain systems.

    Directory of Open Access Journals (Sweden)

    Wei-Dong Huang

    Full Text Available BACKGROUND: Energy efficiency analysis for different biomass-utilization scenarios would help make more informed decisions for developing future biomass-based transportation systems. Diverse biofuels produced from biomass include cellulosic ethanol, butanol, fatty acid ethyl esters, methane, hydrogen, methanol, dimethyether, Fischer-Tropsch diesel, and bioelectricity; the respective powertrain systems include internal combustion engine (ICE vehicles, hybrid electric vehicles based on gasoline or diesel ICEs, hydrogen fuel cell vehicles, sugar fuel cell vehicles (SFCV, and battery electric vehicles (BEV. METHODOLOGY/PRINCIPAL FINDINGS: We conducted a simple, straightforward, and transparent biomass-to-wheel (BTW analysis including three separate conversion elements--biomass-to-fuel conversion, fuel transport and distribution, and respective powertrain systems. BTW efficiency is a ratio of the kinetic energy of an automobile's wheels to the chemical energy of delivered biomass just before entering biorefineries. Up to 13 scenarios were analyzed and compared to a base line case--corn ethanol/ICE. This analysis suggests that BEV, whose electricity is generated from stationary fuel cells, and SFCV, based on a hydrogen fuel cell vehicle with an on-board sugar-to-hydrogen bioreformer, would have the highest BTW efficiencies, nearly four times that of ethanol-ICE. SIGNIFICANCE: In the long term, a small fraction of the annual US biomass (e.g., 7.1%, or 700 million tons of biomass would be sufficient to meet 100% of light-duty passenger vehicle fuel needs (i.e., 150 billion gallons of gasoline/ethanol per year, through up to four-fold enhanced BTW efficiencies by using SFCV or BEV. SFCV would have several advantages over BEV: much higher energy storage densities, faster refilling rates, better safety, and less environmental burdens.

  3. Energy Efficiency Analysis: Biomass-to-Wheel Efficiency Related with Biofuels Production, Fuel Distribution, and Powertrain Systems

    Science.gov (United States)

    Huang, Wei-Dong; Zhang, Y-H Percival

    2011-01-01

    Background Energy efficiency analysis for different biomass-utilization scenarios would help make more informed decisions for developing future biomass-based transportation systems. Diverse biofuels produced from biomass include cellulosic ethanol, butanol, fatty acid ethyl esters, methane, hydrogen, methanol, dimethyether, Fischer-Tropsch diesel, and bioelectricity; the respective powertrain systems include internal combustion engine (ICE) vehicles, hybrid electric vehicles based on gasoline or diesel ICEs, hydrogen fuel cell vehicles, sugar fuel cell vehicles (SFCV), and battery electric vehicles (BEV). Methodology/Principal Findings We conducted a simple, straightforward, and transparent biomass-to-wheel (BTW) analysis including three separate conversion elements -- biomass-to-fuel conversion, fuel transport and distribution, and respective powertrain systems. BTW efficiency is a ratio of the kinetic energy of an automobile's wheels to the chemical energy of delivered biomass just before entering biorefineries. Up to 13 scenarios were analyzed and compared to a base line case – corn ethanol/ICE. This analysis suggests that BEV, whose electricity is generated from stationary fuel cells, and SFCV, based on a hydrogen fuel cell vehicle with an on-board sugar-to-hydrogen bioreformer, would have the highest BTW efficiencies, nearly four times that of ethanol-ICE. Significance In the long term, a small fraction of the annual US biomass (e.g., 7.1%, or 700 million tons of biomass) would be sufficient to meet 100% of light-duty passenger vehicle fuel needs (i.e., 150 billion gallons of gasoline/ethanol per year), through up to four-fold enhanced BTW efficiencies by using SFCV or BEV. SFCV would have several advantages over BEV: much higher energy storage densities, faster refilling rates, better safety, and less environmental burdens. PMID:21765941

  4. Oil from biomass corncob tar as a fuel

    International Nuclear Information System (INIS)

    Zhang, Hongmei; Wang, Jun

    2007-01-01

    In this study, biomass corncob tar oil (B-oil I and B-oil II) was extracted and its characteristics were measured. The characterization data show some similarities and differences among B-oil I, B-oil II and the Diesel: flash point. The densities and viscosities are higher than that of Diesel fuel. The solidifying point for B-oil I and B-oil II were lower than that of Diesel. The heating value of B-oil I and B-oil II were about 85.6% and 87.3% of that ordinary Diesel fuel (OD). The distillation temperatures of B-oil I and B-oil II were lower than that of Diesel fuel, with the 50% evaporation point being as much as 10 o C and 4 o C lower and the 90% evaporation point being 10 o C and 2 o C lower, respectively. These evaporation characteristics implied better cold starting and warm up properties of B-oil I and B-oil II than that of Diesel fuel. B-oil I and B-oil II were blended with Diesel in 10% and 20% by volume. Engine tests have been conducted with the aim of obtaining comparative measures of torque, thermal efficiency, specific fuel consumption and emissions such as CO, smoke density and NO to evaluate and compute the behavior of the Diesel engine running on the above mentioned fuels. The reduction in exhaust emissions, together with the increases in torque and thermal efficiency and the reduction in specific fuel consumption made the blends of B-oil I and B-oil II a suitable alternative fuel for Diesel and could help in controlling air pollution

  5. Biomass - alternative renewable energy source to the fossil fuels

    Directory of Open Access Journals (Sweden)

    Koruba Dorota

    2017-01-01

    Full Text Available The article presents the fossil fuels combustion effects in terms of the dangers of increasing CO2 concentration in the atmosphere. Based on the bibliography review the negative impact of increased carbon dioxide concentration on the human population is shown in the area of the external environment, particularly in terms of the air pollution and especially the impact on human health. The paper presents biomass as the renewable energy alternative source to fossil fuels which combustion gives a neutral CO2 emissions and therefore should be the main carrier of primary energy in Poland. The paper presents the combustion heat results and humidity of selected dry wood pellets (pellets straw, energy-crop willow pellets, sawdust pellets, dried sewage sludge from two sewage treatment plants of the Holly Cross province pointing their energy potential. In connection with the results analysis of these studies the standard requirements were discussed (EN 14918:2010 “Solid bio-fuels-determination of calorific value” regarding the basic parameters determining the biomass energy value (combustion heat, humidity.

  6. Energy consumption analysis of integrated flowsheets for production of fuel ethanol from lignocellulosic biomass

    International Nuclear Information System (INIS)

    Cardona Alzate, C.A.; Sanchez Toro, O.J.

    2006-01-01

    Fuel ethanol is considered one of the most important renewable fuels due to the economic and environmental benefits of its use. Lignocellulosic biomass is the most promising feedstock for producing bioethanol due to its global availability and to the energy gain that can be obtained when non-fermentable materials from biomass are used for cogeneration of heat and power. In this work, several process configurations for fuel ethanol production from lignocellulosic biomass were studied through process simulation using Aspen Plus. Some flowsheets considering the possibilities of reaction-reaction integration were taken into account among the studied process routes. The flowsheet variants were analyzed from the energy point of view utilizing as comparison criterion the energy consumption needed to produce 1 L of anhydrous ethanol. Simultaneous saccharification and cofermentation process with water recycling showed the best results accounting an energy consumption of 41.96 MJ/L EtOH. If pervaporation is used as dehydration method instead of azeotropic distillation, further energy savings can be obtained. In addition, energy balance was estimated using the results from the simulation and literature data. A net energy value of 17.65-18.93 MJ/L EtOH was calculated indicating the energy efficiency of the lignocellulosic ethanol

  7. OxyFuel combustion of Coal and Biomass

    DEFF Research Database (Denmark)

    Toftegaard, Maja Bøg

    of coal and straw at conditions relevant to suspension-fired boilers by clarifying the effect of the change in combustion atmosphere on fuel burnout, flame temperatures, emissions of polluting species (NO, SO2, and CO), fly ash quality, and deposit formation. This work is one of the first to investigate...... and oxyfuel atmospheres. Apart from slightly improved burnout and reduced emissions of NO during oxyfuel combustion these operating conditions yield similar combustion characteristics in both environments. Co-firing coal and biomass or combustion of pure biomass in an oxyfuel power plant could yield...... be adjusted independently. By increasing the concentration of oxygen in the oxidant, i.e. by reducing the flue gas recirculation ratio, it is possible to achieve similar burnout at lower oxygen excess levels. Further work on implications of this strategy are necessary in order to fully clarify its potential...

  8. Comparative study of thermochemical processes for hydrogen production from biomass fuels.

    Science.gov (United States)

    Biagini, Enrico; Masoni, Lorenzo; Tognotti, Leonardo

    2010-08-01

    Different thermochemical configurations (gasification, combustion, electrolysis and syngas separation) are studied for producing hydrogen from biomass fuels. The aim is to provide data for the production unit and the following optimization of the "hydrogen chain" (from energy source selection to hydrogen utilization) in the frame of the Italian project "Filiera Idrogeno". The project focuses on a regional scale (Tuscany, Italy), renewable energies and automotive hydrogen. Decentred and small production plants are required to solve the logistic problems of biomass supply and meet the limited hydrogen infrastructures. Different options (gasification with air, oxygen or steam/oxygen mixtures, combustion, electrolysis) and conditions (varying the ratios of biomass and gas input) are studied by developing process models with uniform hypothesis to compare the results. Results obtained in this work concern the operating parameters, process efficiencies, material and energetic needs and are fundamental to optimize the entire hydrogen chain. Copyright 2010 Elsevier Ltd. All rights reserved.

  9. H2CAP - Hydrogen assisted catalytic biomass pyrolysis for green fuels

    DEFF Research Database (Denmark)

    Arndal, Trine Marie Hartmann; Høj, Martin; Jensen, Peter Arendt

    2014-01-01

    Pyrolysis of biomass produces a high yield of condensable oil at moderate temperature and low pressure.This bio-oil has adverse properties such as high oxygen and water contents, high acidity and immiscibility with fossil hydrocarbons. Catalytic hydrodeoxygenation (HDO) is a promising technology...... that can be used to upgrade the crude bio-oil to fuel-grade oil. The development of the HDO process is challenged by rapid catalyst deactivation, instability of the pyrolysis oil, poorly investigated reaction conditions and a high complexity and variability of the input oil composition. However, continuous...... catalytic hydropyrolysis coupled with downstream HDO of the pyrolysis vapors before condensation shows promise (Figure 1). A bench scale experimental setup will be constructed for the continuous conversion of solid biomass (100g /h) to low oxygen, fuel-grade bio-oil. The aim is to provide a proof...

  10. Biomass co-firing under oxy-fuel conditions

    DEFF Research Database (Denmark)

    Álvarez, L.; Yin, Chungen; Riaza, J.

    2014-01-01

    to have favourable synergy effects in all the cases: it significantly improves the burnout and remarkably lowers NOx emissions. The reduced peak temperatures during co-firing can also help to mitigate deposition formation in real furnaces. Co-firing CO2-neutral biomass with coals under oxy-fuel conditions...... can achieve a below-zero CO2 emission if the released CO2 is captured and sequestered. The model-predicted burnout and gaseous emissions were compared against the experimental results. A very good agreement was observed, the differences in a range of ± 5–10% of the experimental values, which indicates...

  11. Process Design and Economics for the Conversion of Algal Biomass to Biofuels: Algal Biomass Fractionation to Lipid-and Carbohydrate-Derived Fuel Products

    Energy Technology Data Exchange (ETDEWEB)

    None

    2014-09-11

    The U.S. Department of Energy (DOE) promotes the production of a range of liquid fuels and fuel blendstocks from biomass feedstocks by funding fundamental and applied research that advances the state of technology in biomass production, conversion, and sustainability. As part of its involvement in this program, the National Renewable Energy Laboratory (NREL) investigates the conceptual production economics of these fuels. This includes fuel pathways from lignocellulosic (terrestrial) biomass, as well as from algal (aquatic) biomass systems.

  12. Biomass

    International Nuclear Information System (INIS)

    Hernandez, L.A.

    1998-01-01

    Biomass constitutes the energetic form more important and of greater potential after solar energy (source of origin), being consumed in direct form through the combustion, or indirectly through the fossil fuels (those which originates) or by means of different technical of thermochemical and of biochemistry for its conversion and utilization. The current document describes the origin and the energetic characteristics of biomass, its energetic and environmental importance for a developing Country as Colombia, its possibilities of production and the technologies developed for its utilization and transformation, mainly, of the residual biomass

  13. Techno-Economic Analysis of Biomass Fast Pyrolysis to Transportation Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Wright, M. M.; Satrio, J. A.; Brown, R. C.; Daugaard, D. E.; Hsu, D. D.

    2010-11-01

    This study develops techno-economic models for assessment of the conversion of biomass to valuable fuel products via fast pyrolysis and bio-oil upgrading. The upgrading process produces a mixture of naphtha-range (gasoline blend stock) and diesel-range (diesel blend stock) products. This study analyzes the economics of two scenarios: onsite hydrogen production by reforming bio-oil, and hydrogen purchase from an outside source. The study results for an nth plant indicate that petroleum fractions in the naphtha distillation range and in the diesel distillation range are produced from corn stover at a product value of $3.09/gal ($0.82/liter) with onsite hydrogen production or $2.11/gal ($0.56/liter) with hydrogen purchase. These values correspond to a $0.83/gal ($0.21/liter) cost to produce the bio-oil. Based on these nth plant numbers, product value for a pioneer hydrogen-producing plant is about $6.55/gal ($1.73/liter) and for a pioneer hydrogen-purchasing plant is about $3.41/gal ($0.92/liter). Sensitivity analysis identifies fuel yield as a key variable for the hydrogen-production scenario. Biomass cost is important for both scenarios. Changing feedstock cost from $50-$100 per short ton changes the price of fuel in the hydrogen production scenario from $2.57-$3.62/gal ($0.68-$0.96/liter).

  14. Biomass-derived Syngas Utilization for Fuels and Chemicals - Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Dayton, David C

    2010-03-24

    Executive Summary The growing gap between petroleum production and demand, mounting environmental concerns, and increasing fuel prices have stimulated intense interest in research and development (R&D) of alternative fuels, both synthetic and bio-derived. Currently, the most technically defined thermochemical route for producing alternative fuels from lignocellulosic biomass involves gasification/reforming of biomass to produce syngas (carbon monoxide [CO] + hydrogen [H2]), followed by syngas cleaning, Fischer-Tropsch synthesis (FTS) or mixed alcohol synthesis, and some product upgrading via hydroprocessing or separation. A detailed techno-economic analysis of this type of process has recently been published [1] and it highlights the need for technical breakthroughs and technology demonstration for gas cleanup and fuel synthesis. The latter two technical barrier areas contribute 40% of the total thermochemical ethanol cost and 70% of the production cost, if feedstock costs are factored out. Developing and validating technologies that reduce the capital and operating costs of these unit operations will greatly reduce the risk for commercializing integrated biomass gasification/fuel synthesis processes for biofuel production. The objective of this project is to develop and demonstrate new catalysts and catalytic processes that can efficiently convert biomass-derived syngas into diesel fuel and C2-C4 alcohols. The goal is to improve the economics of the processes by improving the catalytic activity and product selectivity, which could lead to commercialization. The project was divided into 4 tasks: Task 1: Reactor Systems: Construction of three reactor systems was a project milestone. Construction of a fixed-bed microreactor (FBR), a continuous stirred tank reactor (CSTR), and a slurry bubble column reactor (SBCR) were completed to meet this milestone. Task 2: Iron Fischer-Tropsch (FT) Catalyst: An attrition resistant iron FT catalyst will be developed and tested

  15. Best Available Techniques (BAT) in solid biomass fuel processing, handling, storage and production of pellets from biomass

    Energy Technology Data Exchange (ETDEWEB)

    Lindberg, J.P.; Tana, J. [AaF-Industri Ab, Stockholm (Sweden)

    2012-09-15

    With the increasing use of biomass fuels the varieties of sources for biomass have expanded to almost all possible combustible matter with biological origin. The increasing scale in solid biomass fuel production and utilization at the combustion plants of the wide variety of biomass fuels have contributed to littering, dust, odor and noise emissions of the production chain. The report aims to provide information for operators, environmental consultants and competent environmental authorities on what is considered BAT, as defined in the IPPC directive (2008/1/EC), in biomass processing and handling as well as the production of pellets from biomass. The project gives a brief description of commonly used solid biomass fuels and the processes, handling and storage of these biomasses in the Nordic countries covering processes from production site to the point of use. Environmental emissions, sources of waste and other relevant environmental aspects from commonly used processes, included raw material and energy use, chemical use and emissions to soil are also included in the report. (Author)

  16. FRACTIONATION OF LIGNOCELLULOSIC BIOMASS FOR FUEL-GRADE ETHANOL PRODUCTION

    Energy Technology Data Exchange (ETDEWEB)

    F.D. Guffey; R.C. Wingerson

    2002-10-01

    PureVision Technology, Inc. (PureVision) of Fort Lupton, Colorado is developing a process for the conversion of lignocellulosic biomass into fuel-grade ethanol and specialty chemicals in order to enhance national energy security, rural economies, and environmental quality. Lignocellulosic-containing plants are those types of biomass that include wood, agricultural residues, and paper wastes. Lignocellulose is composed of the biopolymers cellulose, hemicellulose, and lignin. Cellulose, a polymer of glucose, is the component in lignocellulose that has potential for the production of fuel-grade ethanol by direct fermentation of the glucose. However, enzymatic hydrolysis of lignocellulose and raw cellulose into glucose is hindered by the presence of lignin. The cellulase enzyme, which hydrolyzes cellulose to glucose, becomes irreversibly bound to lignin. This requires using the enzyme in reagent quantities rather than in catalytic concentration. The extensive use of this enzyme is expensive and adversely affects the economics of ethanol production. PureVision has approached this problem by developing a biomass fractionator to pretreat the lignocellulose to yield a highly pure cellulose fraction. The biomass fractionator is based on sequentially treating the biomass with hot water, hot alkaline solutions, and polishing the cellulose fraction with a wet alkaline oxidation step. In September 2001 PureVision and Western Research Institute (WRI) initiated a jointly sponsored research project with the U.S. Department of Energy (DOE) to evaluate their pretreatment technology, develop an understanding of the chemistry, and provide the data required to design and fabricate a one- to two-ton/day pilot-scale unit. The efforts during the first year of this program completed the design, fabrication, and shakedown of a bench-scale reactor system and evaluated the fractionation of corn stover. The results from the evaluation of corn stover have shown that water hydrolysis prior to

  17. Survey of renewable chemicals produced from lignocellulosic biomass during ionic liquid pretreatment

    Directory of Open Access Journals (Sweden)

    Varanasi Patanjali

    2013-01-01

    Full Text Available Abstract Background Lignin is often overlooked in the valorization of lignocellulosic biomass, but lignin-based materials and chemicals represent potential value-added products for biorefineries that could significantly improve the economics of a biorefinery. Fluctuating crude oil prices and changing fuel specifications are some of the driving factors to develop new technologies that could be used to convert polymeric lignin into low molecular weight lignin and or monomeric aromatic feedstocks to assist in the displacement of the current products associated with the conversion of a whole barrel of oil. We present an approach to produce these chemicals based on the selective breakdown of lignin during ionic liquid pretreatment. Results The lignin breakdown products generated are found to be dependent on the starting biomass, and significant levels were generated on dissolution at 160°C for 6 hrs. Guaiacol was produced on dissolution of biomass and technical lignins. Vanillin was produced on dissolution of kraft lignin and eucalytpus. Syringol and allyl guaiacol were the major products observed on dissolution of switchgrass and pine, respectively, whereas syringol and allyl syringol were obtained by dissolution of eucalyptus. Furthermore, it was observed that different lignin-derived products could be generated by tuning the process conditions. Conclusions We have developed an ionic liquid based process that depolymerizes lignin and converts the low molecular weight lignin fractions into a variety of renewable chemicals from biomass. The generated chemicals (phenols, guaiacols, syringols, eugenol, catechols, their oxidized products (vanillin, vanillic acid, syringaldehyde and their easily derivatized hydrocarbons (benzene, toluene, xylene, styrene, biphenyls and cyclohexane already have relatively high market value as commodity and specialty chemicals, green building materials, nylons, and resins.

  18. Emission factors from residential combustion appliances burning Portuguese biomass fuels.

    Science.gov (United States)

    Fernandes, A P; Alves, C A; Gonçalves, C; Tarelho, L; Pio, C; Schimdl, C; Bauer, H

    2011-11-01

    Smoke from residential wood burning has been identified as a major contributor to air pollution, motivating detailed emission measurements under controlled conditions. A series of experiments were performed to compare the emission levels from two types of wood-stoves to those of fireplaces. Eight types of biomass were burned in the laboratory: wood from seven species of trees grown in the Portuguese forest (Pinus pinaster, Eucalyptus globulus, Quercus suber, Acacia longifolia, Quercus faginea, Olea europaea and Quercus ilex rotundifolia) and briquettes produced from forest biomass waste. Average emission factors were in the ranges 27.5-99.2 g CO kg(-1), 552-1660 g CO(2) kg(-1), 0.66-1.34 g NO kg(-1), and 0.82-4.94 g hydrocarbons kg(-1) of biomass burned (dry basis). Average particle emission factors varied between 1.12 and 20.06 g kg(-1) biomass burned (dry basis), with higher burn rates producing significantly less particle mass per kg wood burned than the low burn rates. Particle mass emission factors from wood-stoves were lower than those from the fireplace. The average emission factors for organic and elemental carbon were in the intervals 0.24-10.1 and 0.18-0.68 g kg(-1) biomass burned (dry basis), respectively. The elemental carbon content of particles emitted from the energy-efficient "chimney type" logwood stove was substantially higher than in the conventional cast iron stove and fireplace, whereas the opposite was observed for the organic carbon fraction. Pinus pinaster, the only softwood species among all, was the biofuel with the lowest emissions of particles, CO, NO and hydrocarbons.

  19. Biomass based energy combines with motor fuel production; Biobraenslebaserade energikombinat med tillverkning av drivmedel

    Energy Technology Data Exchange (ETDEWEB)

    Goldschmidt, Barbara

    2005-01-01

    In the report the state of development of production processes for various motor fuels, such as FT diesel, methanol , DME and ethanol, from biomass is reviewed. Biomass and black liquor gasification processes as well as processes for ethanol production from lignocellulosic biomass are discussed. The processes are complicated and still not very well tried in their whole context. The gas cleaning steps, which are necessary to reach acceptable catalyst lifetimes in the motor fuel production processes based on gasification, have been tested in the oil industry and to some extent in coal gasification plants, but not with syngas from biomass or black liquor gasification. For black liquor gasification particularly, also material selection and material lifetime issues remain to be solved. For ethanol production from lignocellulosic biomass process development is needed, to increase the yield in the pre-treatment, hydrolysis and fermentation steps. The energy yields of the processes are dependent on the degree of complexity of the processes, as well as on the integration and balancing of energy demanding steps and steps with energy surplus. This is especially valid for the processes based on gasification, due to high temperatures in the gasifier and some of the catalytic steps, but also for the ethanol process, which benefit from optimal steam integration in the evaporation and distillation steps. Also steam integration with cogeneration plants, or for black liquor gasification with pulp mills, improves the overall energy balance. In addition, the energy yield when motor fuels are produced by gasification is dependent on the usage of the off-gas. The efficiency is improved when the off-gas is burned in a boiler or gas turbine, than when it is flared. In the report examples are given of processes with and without integration.

  20. Electricity and fluid fuels from biomass and coal using advanced technologies: a cost comparison for developing country applications

    International Nuclear Information System (INIS)

    Kartha, S.; Larson, E.D.; Williams, R.H.; Katofsky, R.E.; Chen, J.; Marrison, C.I.

    1995-01-01

    Recent analyses of alternative global energy supply strategies, such as the forthcoming report of the Intergovernmental Panel on Climate Change (IPCC), to be published in 1996, have drawn attention to the possibility that biomass modernized with advanced technologies could play an important role in meeting global energy needs in the next century. This paper discusses two promising classes of advanced technologies that offer the potential for providing modem energy carriers (electricity and fluid fuels) from biomass at competitive costs within one or two decades. These technologies offer significantly more efficient use of land than currently commercial technologies for producing electricity and fluid fuels from biomass, as well as substantially improved energy balances. Electricity is Rely to be the first large market for modernized biomass, but the potential market for fluid fuel production is likely to be much larger. As coal is likely to present a more serious competitive challenge to biomass in the long run, we present an economic comparison with coal-based electricity and fluid fuels. A meaningful economic comparison between coal and biomass is possible because these feedstocks are sufficiently alike in their physical characteristics that similar conversion technologies may well be used for producing electricity and fluid fuels from them. When similar conversion technologies are used for both feedstocks, the relative costs of electricity or fluid fuels will be determined by the distinguishing technical characteristics of the feedstocks (sulphur content, moisture content and reactivity) and by the relative feedstock prices. Electric power generation from biomass and coal are compared here using an advanced integrated gasifier/gas turbine cycle that offers the potential for achieving high efficiency, low unit capital cost and low local pollutant emissions: the steam-injected gas turbine coupled to an air-blown gasifier. For both feedstocks, generation costs are

  1. Techno-Economic Basis for Coproduct Manufacturing To Enable Hydrocarbon Fuel Production from Lignocellulosic Biomass

    Energy Technology Data Exchange (ETDEWEB)

    Biddy, Mary J.; Davis, Ryan; Humbird, David; Tao, Ling; Dowe, Nancy; Guarnieri, Michael T.; Linger, Jeffrey G.; Karp, Eric M.; Salvachua, Davinia; Vardon, Derek R.; Beckham, Gregg T.

    2016-06-06

    Biorefinery process development relies on techno-economic analysis (TEA) to identify primary cost drivers, prioritize research directions, and mitigate technical risk for scale-up through development of detailed process designs. Here, we conduct TEA of a model 2000 dry metric ton-per-day lignocellulosic biorefinery that employs a two-step pretreatment and enzymatic hydrolysis to produce biomass-derived sugars, followed by biological lipid production, lipid recovery, and catalytic hydrotreating to produce renewable diesel blendstock (RDB). On the basis of projected near-term technical feasibility of these steps, we predict that RDB could be produced at a minimum fuel selling price (MFSP) of USD $9.55/gasoline-gallon-equivalent (GGE), predicated on the need for improvements in the lipid productivity and yield beyond current benchmark performance. This cost is significant given the limitations in scale and high costs for aerobic cultivation of oleaginous microbes and subsequent lipid extraction/recovery. In light of this predicted cost, we developed an alternative pathway which demonstrates that RDB costs could be substantially reduced in the near term if upgradeable fractions of biomass, in this case hemicellulose-derived sugars, are diverted to coproducts of sufficient value and market size; here, we use succinic acid as an example coproduct. The coproduction model predicts an MFSP of USD $5.28/GGE when leaving conversion and yield parameters unchanged for the fuel production pathway, leading to a change in biorefinery RDB capacity from 24 to 15 MM GGE/year and 0.13 MM tons of succinic acid per year. Additional analysis demonstrates that beyond the near-term projections assumed in the models here, further reductions in the MFSP toward $2-3/GGE (which would be competitive with fossil-based hydrocarbon fuels) are possible with additional transformational improvements in the fuel and coproduct trains, especially in terms of carbon efficiency to both fuels and

  2. A LOW COST AND HIGH QUALITY SOLID FUEL FROM BIOMASS AND COAL FINES

    Energy Technology Data Exchange (ETDEWEB)

    John T. Kelly; George Miller; Mehdi Namazian

    2001-07-01

    Use of biomass wastes as fuels in existing boilers would reduce greenhouse gas emissions, SO2 and NOx emissions, while beneficially utilizing wastes. However, the use of biomass has been limited by its low energy content and density, high moisture content, inconsistent configuration and decay characteristics. If biomass is upgraded by conventional methods, the cost of the fuel becomes prohibitive. Altex has identified a process, called the Altex Fuel Pellet (AFP) process, that utilizes a mixture of biomass wastes, including municipal biosolids, and some coal fines, to produce a strong, high energy content, good burning and weather resistant fuel pellet, that is lower in cost than coal. This cost benefit is primarily derived from fees that are collected for accepting municipal biosolids. Besides low cost, the process is also flexible and can incorporate several biomass materials of interest The work reported on herein showed the technical and economic feasibility of the AFP process. Low-cost sawdust wood waste and light fractions of municipal wastes were selected as key biomass wastes to be combined with biosolids and coal fines to produce AFP pellets. The process combines steps of dewatering, pellet extrusion, drying and weatherizing. Prior to pilot-scale tests, bench-scale test equipment was used to produce limited quantities of pellets for characterization. These tests showed which pellet formulations had a high potential. Pilot-scale tests then showed that extremely robust pellets could be produced that have high energy content, good density and adequate weatherability. It was concluded that these pellets could be handled, stored and transported using equipment similar to that used for coal. Tests showed that AFP pellets have a high combustion rate when burned in a stoker type systems. While NOx emissions under stoker type firing conditions was high, a simple air staging approach reduced emissions to below that for coal. In pulverized-fuel-fired tests it was

  3. Qualification of UKAEA produced silicide fuel

    International Nuclear Information System (INIS)

    Gibson, J.; Cartwright, P.; Markgraf, J.

    1998-01-01

    As a result of the US RERTR programme, many research reactors have converted their reactor fuel usage from HEU to LEU. The production of LEU fuel provides the fabricator with many new fabrication and inspection challenges. The MTR Fuel Fabrication Plant at Dounreay has extensive experience in alloy fuel fabrication but, to maintain future commercial viability, it has expanded its product base. To become a recognized fabricator of LEU fuel elements requires the production, irradiation and post-irradiation examination of qualification elements. This paper describes the process undertaken in the identification of an irradiation partner, the specification of an element design, the production of two qualification elements and their test irradiation to more than 50% burnup. The two fuel elements completed this irradiation cycle in October 1997 with no unexpected deviations in performance. Post-irradiation examination is currently in progress and the results will be presented at the RRFM conference in March 1998. (author)

  4. A Low-cost, High-yield Process for the Direct Productin of High Energy Density Liquid Fuel from Biomass

    Energy Technology Data Exchange (ETDEWEB)

    Agrawal, Rakesh [Purdue Univ., West Lafayette, IN (United States); Delgass, W. N. [Purdue Univ., West Lafayette, IN (United States); Ribeiro, F. [Purdue Univ., West Lafayette, IN (United States)

    2013-08-31

    The primary objective and outcome of this project was the development and validation of a novel, low-cost, high-pressure fast-hydropyrolysis/hydrodeoxygenation (HDO) process (H2Bioil) using supplementary hydrogen (H2) to produce liquid hydrocarbons from biomass. The research efforts under the various tasks of the project have culminated in the first experimental demonstration of the H2Bioil process, producing 100% deoxygenated >C4+ hydrocarbons containing 36-40% of the carbon in the feed of pyrolysis products from biomass. The demonstrated H{sub 2}Bioil process technology (i.e. reactor, catalyst, and downstream product recovery) is scalable to a commercial level and is estimated to be economically competitive for the cases when supplementary H2 is sourced from coal, natural gas, or nuclear. Additionally, energy systems modeling has revealed several process integration options based on the H2Bioilprocess for energy and carbon efficient liquid fuel production. All project tasks and milestones were completed or exceeded. Novel, commercially-scalable, high-pressure reactors for both fast-hydropyrolysis and hydrodeoxygenation were constructed, completing Task A. These reactors were capable of operation under a wide-range of conditions; enabling process studies that lead to identification of optimum process conditions. Model compounds representing biomass pyrolysis products were studied, completing Task B. These studies were critical in identifying and developing HDO catalysts to target specific oxygen functional groups. These process and model compound catalyst studies enabled identification of catalysts that achieved 100% deoxygenation of the real biomass feedstock, sorghum, to form hydrocarbons in high yields as part of Task C. The work completed during this grant has identified and validated the novel and commercially scalable H2Bioil process for production of hydrocarbon fuels from biomass. Studies on

  5. Pyrolysis kinetics study of three biomass solid wastes for thermochemical conversion into liquid fuels

    Science.gov (United States)

    Tuly, S. S.; Parveen, M.; Islam, M. R.; Rahman, M. S.; Haniu, H.

    2017-06-01

    Pyrolysis has been considered as the most efficient way of producing liquid fuel from biomass and its wastes. In this study the thermal degradation characteristics and pyrolysis kinetics of three selected biomass samples of Jute stick (Corchorus capsularis), Japanese cedar wood (Cryptomeria japonica) and Tamarind seed (Tamarindus indica) have been investigated in a nitrogen atmosphere at heating rates of 10°C/min and 60°C/min over a temperature range of 30°C to 800°C. The weight loss region for the three biomass solid wastes has shifted to a higher temperature range and the weight loss rate has increased with increasing heating rate. In this case, the three biomass samples have represented the similar behavior. The initial reaction temperature has decreased with increasing heating rate but the reaction range and reaction rate have increased. The percentage of total weight loss is higher for cedar wood than jute stick and tamarind seed. For the three biomass wastes, the overall rate equation has been modeled properly by one simplified equation and from here it is possible to determine kinetic parameters of unreacted materials based on Arrhenious form. The calculated rate equation compares thoroughly well with the measured TG and DTG data.

  6. Fuel production from biomass: generation of liquid biofuels

    Directory of Open Access Journals (Sweden)

    Carmen Ghergheleş

    2008-05-01

    Full Text Available Anaerobic fermentation processes mayalso be used to produce liquid fuels frombiological raw materials. An example is theethanol production from glucose, known asstandard yeast fermentation in the beer, wine andliquor industries. It has to take place in steps, suchthat the ethanol is removed (by distillation ordehydrator application whenever itsconcentration approaches a value (around 12%which would impede reproduction of the yeastculture.

  7. Microgasification cookstoves and pellet fuels from waste biomass: A ...

    African Journals Online (AJOL)

    Biochar production averaged 59 and 29% of total fuel in the ND and Philips, respectively. Interviews of 30 ND TLUD stove users showed that 60% abandoned use within one month, 80% stating that they produce too much smoke and 40% stating that controlling the air vent is too much trouble. Seventy five percent said that ...

  8. Fuel production from biomass: generation of liquid biofuels

    OpenAIRE

    Carmen Ghergheleş; V. Ghergheleş

    2008-01-01

    Anaerobic fermentation processes mayalso be used to produce liquid fuels frombiological raw materials. An example is theethanol production from glucose, known asstandard yeast fermentation in the beer, wine andliquor industries. It has to take place in steps, suchthat the ethanol is removed (by distillation ordehydrator application) whenever itsconcentration approaches a value (around 12%)which would impede reproduction of the yeastculture.

  9. Perspectives on gasification systems to produce energy carriers and other chemicals with low CO2 emissions : techno‐economic system analysis on current and advanced flexible thermo‐chemical conversion of fossil fuels and biomass

    NARCIS (Netherlands)

    Meerman, J.C.

    2012-01-01

    To prevent dangerous climate change, the emissions of anthropogenic greenhouse gasses (GHG) need to be reduced. Two key mitigation options to reduce GHG involve a transition from the current fossil-fuel based infrastructure towards one based on renewable and the implementation of CO2 capture,

  10. Concurrent bio-electricity and biomass production in three Plant-Microbial Fuel Cells using Spartina anglica, Arundinella anomala and Arundo donax

    NARCIS (Netherlands)

    Helder, M.; Strik, D.P.B.T.B.; Hamelers, H.V.M.; Kuhn, A.J.; Blok, C.; Buisman, C.J.N.

    2010-01-01

    In a Plant Microbial Fuel Cell (P-MFC) three plants were tested for concurrent biomass and bio-electricity production and maximization of power output. Spartina anglica and Arundinella anomala concurrently produced biomass and bio-electricity for six months consecutively. Average power production of

  11. Hydrogen Through Water Electrolysis and Biomass Gasification for Application in Fuel Cells

    Directory of Open Access Journals (Sweden)

    Y. Kirosa

    2017-03-01

    Full Text Available Hydrogen is considered to be one of the most promising green energy carrier in the energy storage and conversion scenario. Although it is abundant on Earth in the form of compounds, its occurrence in free form is extremely low. Thus, it has to be produced by reforming processes, steam reforming (SR, partial oxidation (POX and auto-thermal reforming (ATR mainly from fossil fuels for high throughput with high energy requirements, pyrolysis of biomass and electrolysis. Electrolysis is brought about by passing electric current though two electrodes to evolve water into its constituent parts, viz. hydrogen and oxygen, respectively. Hydrogen produced by non-noble metal catalysts for both anode and cathode is therefore cost-effective and can be integrated into fuel cells for direct chemical energy conversion into electrical energy electricity, thus meeting the sustainable and renewable use with low carbon footprint.

  12. Evaluation of design and operation of fuel handling systems for 25 MW biomass fueled CFB power plants

    International Nuclear Information System (INIS)

    Precht, D.

    1991-01-01

    Two circulating fluidized bed, biomass fueled, 25MW power plants were placed into operation by Thermo Electron Energy Systems in California during late 1989. This paper discusses the initial fuel and system considerations, system design, actual operating fuel characterisitics, system operation during the first year and modifications. Biomass fuels handled by the system include urban/manufacturing wood wastes and agricultural wastes in the form of orchard prunings, vineyard prunings, pits, shells, rice hulls and straws. Equipment utilized in the fuel handling system are described and costs are evaluated. Lessons learned from the design and operational experience are offered for consideration on future biomass fueled installations where definition of fuel quality and type is subject to change

  13. Preliminary evaluation of fuel oil produced from pyrolysis of low ...

    African Journals Online (AJOL)

    MICHAEL

    *SOURCE: ATSDR-JET FUELS JP-4 AND JP –7[1995]. Conclusion: The pyrolysis of waste polyethylene film to produce fuel oil increases with temperature. High yield is best obtained from above 300oC. The fuel oil formation is also affected by the type of heat source. i.e. reaction time is longer when a 2000W heater was.

  14. Novel Strategies for the Production of Fuels, Lubricants, and Chemicals from Biomass.

    Science.gov (United States)

    Shylesh, Sankaranarayanapillai; Gokhale, Amit A; Ho, Christopher R; Bell, Alexis T

    2017-10-17

    Growing concern with the environmental impact of CO 2 emissions produced by combustion of fuels derived from fossil-based carbon resources has stimulated the search for renewable sources of carbon. Much of this focus has been on the development of methods for producing transportation fuels, the major source of CO 2 emissions today, and to a lesser extent on the production of lubricants and chemicals. First-generation biofuels such as bioethanol, produced by the fermentation of sugar cane- or corn-based sugars, and biodiesel, produced by the transesterification reaction of triglycerides with alcohols to form a mixture of long-chain fatty esters, can be blended with traditional fuels in limited amounts and also arise in food versus fuel debates. Producing molecules that can be drop-in solutions for fossil-derived products used in the transportation sector allows for efficient use of the existing infrastructure and is therefore particularly interesting. In this context, the most viable source of renewable carbon is abundantly available lignocellulosic biomass, a complex mixture of lignin, hemicellulose, and cellulose. Conversion of the carbohydrate portion of biomass (hemicellulose and cellulose) to fuels requires considerable chemical restructuring of the component sugars in order to achieve the energy density and combustion properties required for transportation fuels-gasoline, diesel, and jet. A different set of constraints must be met for the conversion of biomass-sourced sugars to lubricants and chemicals. This Account describes strategies developed by us to utilize aldehydes, ketones, alcohols, furfurals, and carboxylic acids derived from C 5 and C 6 sugars, acetone-butanol-ethanol (ABE) fermentation mixtures, and various biomass-derived carboxylic acids and fatty acids to produce fuels, lubricants, and chemicals. Oxygen removal from these synthons is achieved by dehydration, decarboxylation, hydrogenolysis, and hydrodeoxygenation, whereas reactions such as

  15. Biomass fuel smoke exposure was associated with adverse cardiac remodeling and left ventricular dysfunction in Peru.

    Science.gov (United States)

    Burroughs Peña, M S; Velazquez, E J; Rivera, J D; Alenezi, F; Wong, C; Grigsby, M; Davila-Roman, V G; Gilman, R H; Miranda, J J; Checkley, W

    2017-07-01

    While household air pollution from biomass fuel combustion has been linked to cardiovascular disease, the effects on cardiac structure and function have not been well described. We sought to determine the association between biomass fuel smoke exposure and cardiac structure and function by transthoracic echocardiography. We identified a random sample of urban and rural residents living in the high-altitude region of Puno, Peru. Daily biomass fuel use was self-reported. Participants underwent transthoracic echocardiography. Multivariable linear regression was used to examine the relationship of biomass fuel use with echocardiographic measures of cardiac structure and function, adjusting for age, sex, height, body mass index, diabetes, physical activity, and tobacco use. One hundred and eighty-seven participants (80 biomass fuel users and 107 non-users) were included in this analysis (mean age 59 years, 58% women). After adjustment, daily exposure to biomass fuel smoke was associated with increased left ventricular internal diastolic diameter (P=.004), left atrial diameter (P=.03), left atrial area (four-chamber) (P=.004) and (two-chamber) (P=.03), septal E' (P=.006), and lateral E' (P=.04). Exposure to biomass fuel smoke was also associated with worse global longitudinal strain in the two-chamber view (P=.01). Daily biomass fuel use was associated with increased left ventricular size and decreased left ventricular systolic function by global longitudinal strain. © 2016 John Wiley & Sons A/S. Published by John Wiley & Sons Ltd.

  16. Linking biomass fuel consumption and improve cooking stove: A study from Bangladesh

    Energy Technology Data Exchange (ETDEWEB)

    Sohel, Md. Shawkat Islam; Rana, Md. Parvez; Akhter, Sayma

    2010-09-15

    The study determines the biomass fuel consumption pattern and environmental consequences of biomass fuel usage in the traditional and improve cooking stove. The introduction of improved cooking stove minimizes people's forest dependence by reducing the amount of fuelwood required to meet their household needs. Firewood was the most frequently used biomass fuel. It has been figured out that the incomplete combustion of biomass in the traditional cooking stove poses severe epidemiological consequences to human health and contributes to global warming. While improve cooking stove help to reduce such consequences.

  17. Optimization of biomass-producing conditions of Micrococcus sp. S ...

    African Journals Online (AJOL)

    STORAGESEVER

    2009-04-20

    Apr 20, 2009 ... identify the significant variables from a ten-variables system, and then three significant variables ... the response (biomass) and the three variables were fitted to a predictive quadratic polynomial equation .... (biomass) as a function of three significant variables. A quadratic model was attempted to fit the data ...

  18. Optimization of biomass-producing conditions of Micrococcus sp. S ...

    African Journals Online (AJOL)

    Then these three variables were optimized by Box-behnken experimental design and response surface methodology, and a multinomial equation was constructed to describe the correlation between the biomass production and the three tested variables. By solving to this equation, the predicted maximum biomass was ...

  19. Fuel gas production from animal and agricultural residues and biomass

    Energy Technology Data Exchange (ETDEWEB)

    Wise, D. L; Wentworth, R. L

    1978-05-30

    Progress was reported by all contractors. Topics presented include: solid waste to methane gas; pipeline fuel gas from an environmental cattle feed lot; heat treatment of organics for increasing anaerobic biodegradability; promoting faster anaerobic digestion; permselective membrane control of algae and wood digesters for increased production and chemicals recovery; anaerobic fermentation of agricultural residues; pilot plant demonstration of an anaerobic, fixed-film bioreactor for wastewater treatment; enhancement of methane production in the anaerobic diegestion of sewage; evaluation of agitation concepts for biogasification of sewage sludge; operation of a 50,000 gallon anaerobic digester; biological conversion of biomass to methane; dirt feedlot residue experiments; anaerobic fermentation of livestock and crop residues; current research on methanogenesis in Europe; and summary of EPA programs in digestion technology. (DC)

  20. Methods for producing extracted and digested products from pretreated lignocellulosic biomass

    Science.gov (United States)

    Chundawat, Shishir; Sousa, Leonardo Da Costa; Cheh, Albert M.; Balan; , Venkatesh; Dale, Bruce

    2017-05-16

    Methods for producing extracted and digested products from pretreated lignocellulosic biomass are provided. The methods include converting native cellulose I.sub..beta. to cellulose III.sub.I by pretreating the lignocellulosic biomass with liquid ammonia under certain conditions, and performing extracting or digesting steps on the pretreated/converted lignocellulosic biomass.

  1. Electrocatalytic processing of renewable biomass-derived compounds for production of chemicals, fuels and electricity

    Science.gov (United States)

    Xin, Le

    The dual problems of sustaining the fast growth of human society and preserving the environment for future generations urge us to shift our focus from exploiting fossil oils to researching and developing more affordable, reliable and clean energy sources. Human beings had a long history that depended on meeting our energy demands with plant biomass, and the modern biorefinery technologies realize the effective conversion of biomass to production of transportation fuels, bulk and fine chemicals so to alleviate our reliance on fossil fuel resources of declining supply. With the aim of replacing as much non-renewable carbon from fossil oils with renewable carbon from biomass as possible, innovative R&D activities must strive to enhance the current biorefinery process and secure our energy future. Much of my Ph.D. research effort is centered on the study of electrocatalytic conversion of biomass-derived compounds to produce value-added chemicals, biofuels and electrical energy on model electrocatalysts in AEM/PEM-based continuous flow electrolysis cell and fuel cell reactors. High electricity generation performance was obtained when glycerol or crude glycerol was employed as fuels in AEMFCs. The study on selective electrocatalytic oxidation of glycerol shows an electrode potential-regulated product distribution where tartronate and mesoxalate can be selectively produced with electrode potential switch. This finding then led to the development of AEMFCs with selective production of valuable tartronate or mesoxalate with high selectivity and yield and cogeneration of electricity. Reaction mechanisms of electrocatalytic oxidation of ethylene glycol and 1,2-propanediol were further elucidated by means of an on-line sample collection technique and DFT modeling. Besides electro-oxidation of biorenewable alcohols to chemicals and electricity, electrocatalytic reduction of keto acids (e.g. levulinic acid) was also studied for upgrading biomass-based feedstock to biofuels while

  2. Fine grain separation for the production of biomass fuel from mixed municipal solid waste.

    Science.gov (United States)

    Giani, H; Borchers, B; Kaufeld, S; Feil, A; Pretz, T

    2016-01-01

    The main goal of the project MARSS (Material Advanced Sustainable Systems) is to build a demonstration plant in order to recover a renewable biomass fuel suitable for the use in biomass power plants out of mixed municipal solid waste (MMSW). The demonstration plant was constructed in Mertesdorf (Germany), working alongside an existing mechanical-biological treatment plant, where the MMSW is biological dried under aerobe conditions in rotting boxes. The focus of the presented sorting campaign was set on the processing of fine grain particles minor than 11.5mm which have the highest mass content and biogenic energy potential of the utilized grain size fractions. The objective was to produce a biomass fuel with a high calorific value and a low content of fossil (plastic, synthetic) materials while maximizing the mass recovery. Therefore, the biogenic components of the dried MMSW are separated from inert and fossil components through various classification and sifting processes. In three experimental process setups of different processing depths, the grain size fraction 4-11.5mm was sifted by the use of air sifters and air tables. Copyright © 2015 Elsevier Ltd. All rights reserved.

  3. The Swedish Ash Programme 2002-2008. Biomass, wastes, peat - any solid fuel but coal

    Energy Technology Data Exchange (ETDEWEB)

    Bjurstroem, Henrik; Herbert, Roger

    2009-07-15

    In Sweden, producers of combustion residues have since 2002 implemented a collaborative applied RandD programme aimed at the utilisation of combustion residues (ash). The fuels are biomass, wastes, peat - any solid fuel but coal. In this report, the main lines of the programme are described: Covers for landfills and mine tailings; Civil works, e.g. road-buildings, where both geotechnical and environmental questions have been addressed; Cement and concrete applications; Compensating soils for removing biomass and the mineral nutrients in the biomass. The emphasis of the Programme is on environmental questions, even if technical questions have been treated. The time perspective in this context is much longer than the 3-5 years that are usual in an applied RandD programme, i.e. decades after ash has been placed on a site, e.g. in a road, or spread to forest soil. New test fields have been created in the programme and old test fields have been evaluated in order to gather available information

  4. Liquid transportation fuels via large-scale fluidised-bed gasification of lignocellulosic biomass

    Energy Technology Data Exchange (ETDEWEB)

    Hannula, I.; Kurkela, E.

    2013-04-15

    With the objective of gaining a better understanding of the system design trade-offs and economics that pertain to biomass-to-liquids processes, 20 individual BTL plant designs were evaluated based on their technical and economic performance. The investigation was focused on gasification-based processes that enable the conversion of biomass to methanol, dimethyl ether, Fischer-Tropsch liquids or synthetic gasoline at a large (300 MWth of biomass) scale. The biomass conversion technology was based on pressurised steam/O2-blown fluidised-bed gasification, followed by hot-gas filtration and catalytic conversion of hydrocarbons and tars. This technology has seen extensive development and demonstration activities in Finland during the recent years and newly generated experimental data has also been used in our simulation models. Our study included conceptual design issues, process descriptions, mass and energy balances and production cost estimates. Several studies exist that discuss the overall efficiency and economics of biomass conversion to transportation liquids, but very few studies have presented a detailed comparison between various syntheses using consistent process designs and uniform cost database. In addition, no studies exist that examine and compare BTL plant designs using the same front-end configuration as described in this work. Our analysis shows that it is possible to produce sustainable low-carbon fuels from lignocellulosic biomass with first-law efficiency in the range of 49.6-66.7% depending on the end-product and process conditions. Production cost estimates were calculated assuming Nth plant economics and without public investment support, CO2 credits or tax assumptions. They are 58-65 euro/MWh for methanol, 58-66 euro/MWh for DME, 64-75 euro/MWh for Fischer-Tropsch liquids and 68-78 euro/MWh for synthetic gasoline. (orig.)

  5. The Advanced High-Temperature Reactor (AHTR) for Producing Hydrogen to Manufacture Liquid Fuels

    International Nuclear Information System (INIS)

    Forsberg, C.W.; Peterson, P.F.; Ott, L.

    2004-01-01

    Conventional world oil production is expected to peak within a decade. Shortfalls in production of liquid fuels (gasoline, diesel, and jet fuel) from conventional oil sources are expected to be offset by increased production of fuels from heavy oils and tar sands that are primarily located in the Western Hemisphere (Canada, Venezuela, the United States, and Mexico). Simultaneously, there is a renewed interest in liquid fuels from biomass, such as alcohol; but, biomass production requires fertilizer. Massive quantities of hydrogen (H2) are required (1) to convert heavy oils and tar sands to liquid fuels and (2) to produce fertilizer for production of biomass that can be converted to liquid fuels. If these liquid fuels are to be used while simultaneously minimizing greenhouse emissions, nonfossil methods for the production of H2 are required. Nuclear energy can be used to produce H2. The most efficient methods to produce H2 from nuclear energy involve thermochemical cycles in which high-temperature heat (700 to 850 C) and water are converted to H2 and oxygen. The peak nuclear reactor fuel and coolant temperatures must be significantly higher than the chemical process temperatures to transport heat from the reactor core to an intermediate heat transfer loop and from the intermediate heat transfer loop to the chemical plant. The reactor temperatures required for H2 production are at the limits of practical engineering materials. A new high-temperature reactor concept is being developed for H2 and electricity production: the Advanced High-Temperature Reactor (AHTR). The fuel is a graphite-matrix, coated-particle fuel, the same type that is used in modular high-temperature gas-cooled reactors (MHTGRs). The coolant is a clean molten fluoride salt with a boiling point near 1400 C. The use of a liquid coolant, rather than helium, reduces peak reactor fuel and coolant temperatures 100 to 200 C relative to those of a MHTGR. Liquids are better heat transfer fluids than gases

  6. Biomass Fuel Characterization : Testing and Evaluating the Combustion Characteristics of Selected Biomass Fuels : Final Report May 1, 1988-July, 1989.

    Energy Technology Data Exchange (ETDEWEB)

    Bushnell, Dwight J.; Haluzok, Charles; Dadkhah-Nikoo, Abbas

    1990-04-01

    Results show that two very important measures of combustion efficiency (gas temperature and carbon dioxide based efficiency) varied by only 5.2 and 5.4 percent respectively. This indicates that all nine different wood fuel pellet types behave very similarly under the prescribed range of operating parameters. The overall mean efficiency for all tests was 82.1 percent and the overall mean temperature was 1420 1{degree}F. Particulate (fly ash) ad combustible (in fly ash) data should the greatest variability. There was evidence of a relationship between maximum values for both particulate and combustible and the percentages of ash and chlorine in the pellet fuel. The greater the percentage of ash and chlorine (salt), the greater was the fly ash problem, also, combustion efficiency was decreased by combustible losses (unburned hydrocarbons) in the fly ash. Carbon monoxide and Oxides of Nitrogen showed the next greatest variability, but neither had data values greater than 215.0 parts per million (215.0 ppm is a very small quantity, i.e. 1 ppm = .001 grams/liter = 6.2E-5 1bm/ft{sup 3}). Visual evidence indicates that pellets fuels produced from salt laden material are corrosive, produce the largest quantities of ash, and form the only slag or clinker formations of all nine fuels. The corrosion is directly attributable to salt content (or more specifically, chloride ions and compounds formed during combustion). 45 refs., 23 figs., 19 tabs.

  7. Biomass energy

    International Nuclear Information System (INIS)

    Pasztor, J.; Kristoferson, L.

    1992-01-01

    Bioenergy systems can provide an energy supply that is environmentally sound and sustainable, although, like all energy systems, they have an environmental impact. The impact often depends more on the way the whole system is managed than on the fuel or on the conversion technology. The authors first describe traditional biomass systems: combustion and deforestation; health impact; charcoal conversion; and agricultural residues. A discussion of modern biomass systems follows: biogas; producer gas; alcohol fuels; modern wood fuel resources; and modern biomass combustion. The issue of bioenergy and the environment (land use; air pollution; water; socioeconomic impacts) and a discussion of sustainable bioenergy use complete the paper. 53 refs., 9 figs., 14 tabs

  8. Novel pathways for fuels and lubricants from biomass optimized using life-cycle greenhouse gas assessment.

    Science.gov (United States)

    Balakrishnan, Madhesan; Sacia, Eric R; Sreekumar, Sanil; Gunbas, Gorkem; Gokhale, Amit A; Scown, Corinne D; Toste, F Dean; Bell, Alexis T

    2015-06-23

    Decarbonizing the transportation sector is critical to achieving global climate change mitigation. Although biofuels will play an important role in conventional gasoline and diesel applications, bioderived solutions are particularly important in jet fuels and lubricants, for which no other viable renewable alternatives exist. Producing compounds for jet fuel and lubricant base oil applications often requires upgrading fermentation products, such as alcohols and ketones, to reach the appropriate molecular-weight range. Ketones possess both electrophilic and nucleophilic functionality, which allows them to be used as building blocks similar to alkenes and aromatics in a petroleum refining complex. Here, we develop a method for selectively upgrading biomass-derived alkyl methyl ketones with >95% yields into trimer condensates, which can then be hydrodeoxygenated in near-quantitative yields to give a new class of cycloalkane compounds. The basic chemistry developed here can be tailored for aviation fuels as well as lubricants by changing the production strategy. We also demonstrate that a sugarcane biorefinery could use natural synergies between various routes to produce a mixture of lubricant base oils and jet fuels that achieve net life-cycle greenhouse gas savings of up to 80%.

  9. Reducing life cycle greenhouse gas emissions of corn ethanol by integrating biomass to produce heat and power at ethanol plants

    International Nuclear Information System (INIS)

    Kaliyan, Nalladurai; Morey, R. Vance; Tiffany, Douglas G.

    2011-01-01

    A life-cycle assessment (LCA) of corn ethanol was conducted to determine the reduction in the life-cycle greenhouse gas (GHG) emissions for corn ethanol compared to gasoline by integrating biomass fuels to replace fossil fuels (natural gas and grid electricity) in a U.S. Midwest dry-grind corn ethanol plant producing 0.19 hm 3 y -1 of denatured ethanol. The biomass fuels studied are corn stover and ethanol co-products [dried distillers grains with solubles (DDGS), and syrup (solubles portion of DDGS)]. The biomass conversion technologies/systems considered are process heat (PH) only systems, combined heat and power (CHP) systems, and biomass integrated gasification combined cycle (BIGCC) systems. The life-cycle GHG emission reduction for corn ethanol compared to gasoline is 38.9% for PH with natural gas, 57.7% for PH with corn stover, 79.1% for CHP with corn stover, 78.2% for IGCC with natural gas, 119.0% for BIGCC with corn stover, and 111.4% for BIGCC with syrup and stover. These GHG emission estimates do not include indirect land use change effects. GHG emission reductions for CHP, IGCC, and BIGCC include power sent to the grid which replaces electricity from coal. BIGCC results in greater reductions in GHG emissions than IGCC with natural gas because biomass is substituted for fossil fuels. In addition, underground sequestration of CO 2 gas from the ethanol plant's fermentation tank could further reduce the life-cycle GHG emission for corn ethanol by 32% compared to gasoline.

  10. Conversion of Biomass-Derived Furans into Hydrocarbon Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Moens, L.; Johnson, D. K.

    2013-01-01

    One of the most studied chemical transformations of carbohydrates is their thermocatalytic dehydration to form furans. Cellulose-derived glucose is thereby converted into 5-hydroxymethylfurfuraldehyde (5-HMF), while the hemicellulose-derived pentoses (e.g., xylose, arabinose) form furfuraldehyde. Our objective is to identify new pathways to convert furfuryl alcohol into a mixture of aliphatic hydrocarbons that can be used as drop-in fuels for diesel (C10-20) and jet fuel (C9-16) blends. Furfuryl alcohol is produced commercially through hydrogenation of furfuraldehyde that is derived from hemicellulose-derived pentoses via acid-catalyzed dehydration. The steps that we are currently pursuing to convert furfuryl alcohol into hydrocarbons are 1) oligomerization of furfuryl alcohol to form dimers (C10) and trimers (C15), and 2) hydrotreatment of the dimers and trimers to produce a mixture of linear hydrocarbons with carbon chain lengths in the range of diesel and jet fuels. This presentation will discuss our progress in the development of this pathway.

  11. Wet scrubbing of biomass producer gas tars using vegetable oil

    Science.gov (United States)

    Bhoi, Prakashbhai Ramabhai

    The overall aims of this research study were to generate novel design data and to develop an equilibrium stage-based thermodynamic model of a vegetable oil based wet scrubbing system for the removal of model tar compounds (benzene, toluene and ethylbenzene) found in biomass producer gas. The specific objectives were to design, fabricate and evaluate a vegetable oil based wet scrubbing system and to optimize the design and operating variables; i.e., packed bed height, vegetable oil type, solvent temperature, and solvent flow rate. The experimental wet packed bed scrubbing system includes a liquid distributor specifically designed to distribute a high viscous vegetable oil uniformly and a mixing section, which was designed to generate a desired concentration of tar compounds in a simulated air stream. A method and calibration protocol of gas chromatography/mass spectroscopy was developed to quantify tar compounds. Experimental data were analyzed statistically using analysis of variance (ANOVA) procedure. Statistical analysis showed that both soybean and canola oils are potential solvents, providing comparable removal efficiency of tar compounds. The experimental height equivalent to a theoretical plate (HETP) was determined as 0.11 m for vegetable oil based scrubbing system. Packed bed height and solvent temperature had highly significant effect (p0.05) effect on the removal of model tar compounds. The packing specific constants, Ch and CP,0, for the Billet and Schultes pressure drop correlation were determined as 2.52 and 2.93, respectively. The equilibrium stage based thermodynamic model predicted the removal efficiency of model tar compounds in the range of 1-6%, 1-4% and 1-2% of experimental data for benzene, toluene and ethylbenzene, respectively, for the solvent temperature of 30° C. The NRTL-PR property model and UNIFAC for estimating binary interaction parameters are recommended for modeling absorption of tar compounds in vegetable oils. Bench scale

  12. Matsalu wetland area biomass as a bio fuel

    International Nuclear Information System (INIS)

    Lausmaa, Toenu

    2000-01-01

    To preserve Matsalu as an especially interesting and specific wetland area even on the international scale, the Matsalu Nature Reserve was founded in 1957. The most natural and characteristic bio topes at Matsalu are undoubtedly the reed stands, covering almost 3000 ha. The reed is rather thin and mixed with common hay plants near the land but towards the bay it becomes increasingly abundant and thick. The characterise features of several bio topes at the Nature Reserve (water-meadows, coastal pastures and meadows etc.) can be preserved only by human activity. Without human activity the landscape encompassing coastal pastures and meadows would go through changes and these areas would be soon covered with junipers. The reed harvesting in Matsalu goes back in the Middle Ages and even before that. The reed was harvested mainly in winter and only seldom in summer. The main goal of the reed harvesting was to obtain material for hatched roofs. The reed cutting is economically justified and environmentally benign activity even now, but only less than 1% of the total area of reed stands is cut nowadays. In spite of the fact that reed harvesting is now economical undertaking (export to Germany and Denmark), it could be much more escalated if were possible to use better technical equipment to that end and get low interest loans. Unfortunately, not all the reed in the wetland of Matsalu Nature Reserve is suitable for hatched roofs. Therefore, it is needed to find some other practical usage for reed as well. The most perspective of these new choices is, indeed, to use the reed biomass as a bio fuel for space heating in the local area of Matsalu. According to Matsalu wetland protection regulation, the constant human care of reed stands and meadows is one of the priorities in nature protection for this area. One possible field of use for the cut down biomass is to use it as a bio fuel. It is not only a good chance to run Matsalu Nature Reserve in sustainable way in terms of

  13. Attempt to produce silicide fuel elements in Indonesia

    International Nuclear Information System (INIS)

    Soentono, S.; Suripto, A.

    1991-01-01

    After the successful experiment to produce U 3 Si 2 powder and U 3 Si 2 -Al fuel plates using depleted U and Si of semiconductor quality, silicide fuel was synthesized using x -Al available at the Fuel Element Production Installation (FEPI) at Serpong, Indonesia. Two full-size U 3 Si 2 -Al fuel elements, having similar specifications to the ones of U 3 O 8 -Al for the RSG-GAS (formerly known as MPR-30), have been produced at the FEPI. All quality controls required have been imposed to the feeds, intermediate, as well as final products throughout the production processes of the two fuel elements. The current results show that these fuel elements are qualified from fabrication point of view, therefore it is expected that they will be permitted to be tested in the RSG-GAS, sometime by the end of 1989, for normal (∝50%) and above normal burn-up. (orig.)

  14. Reducing the rate of carbon dioxide buildup with biomass fuel under climate change

    International Nuclear Information System (INIS)

    Peart, R.; Curry, R.; Jones, J.; Boote, K.; Allen, L.

    1993-01-01

    The authors have been working for several years on estimating, through crop simulation and crop growth chamber experiments, the changes in yield and in irrigation demand which would be brought about by a doubling of atmospheric greenhouse gases, given the results of three General Circulation Models (GCM) that simulate the climate change that would be expected. They are now beginning to study the impact this might have in relation to biomass fuels. An important question is the effect of the changed climate on crop production, would the increased carbon dioxide concentration outweigh the negative climate change effects on crop yields? Results are quite variable due to different climate change effects at different locations and the differences in historical weather and in soils in different locations. However, on balance, climate change would result in reduced yields of the crops we studied, soybean, maize and peanut. However, US production of these crops could be maintained or increased by the use of irrigation on more acres. Irrigated crops, in general, would have increased yields under climate change because of the increased photosynthetic efficiency with higher carbon dioxide levels. Results on net remediation of carbon dioxide buildup by the use of biomass fuel rather than fossil fuel are not completed, but previous work has shown that Midwest non-irrigated maize production provides much more equivalent biomass energy than is required for its production. The studies with soybean show a ratio of equivalent energy output in the seed to energy used in producing the crop ranging from 4 to almost 9 under climate change

  15. Hydrocarbon bio-jet fuel from bioconversion of poplar biomass: techno-economic assessment.

    Science.gov (United States)

    Crawford, Jordan T; Shan, Chin Wei; Budsberg, Erik; Morgan, Hannah; Bura, Renata; Gustafson, Rick

    2016-01-01

    Infrastructure compatible hydrocarbon biofuel proposed to qualify as renewable transportation fuel under the U.S. Energy Independence and Security Act of 2007 and Renewable Fuel Standard (RFS2) is evaluated. The process uses a hybrid poplar feedstock, which undergoes dilute acid pretreatment and enzymatic hydrolysis. Sugars are fermented to acetic acid, which undergoes conversion to ethyl acetate, ethanol, ethylene, and finally a saturated hydrocarbon end product. An unfermentable lignin stream may be burned for steam and electricity production, or gasified to produce hydrogen. During biofuel production, hydrogen gas is required and may be obtained by various methods including lignin gasification. Both technical and economic aspects of the biorefinery are analyzed, with different hydrogen sources considered including steam reforming of natural gas and gasification of lignin. Cash operating costs for jet fuel production are estimated to range from 0.67 to 0.86 USD L -1 depending on facility capacity. Minimum fuel selling prices with a 15 % discount rate are estimated to range from 1.14 to 1.79 USD L -1 . Capacities of 76, 190, and 380 million liters of jet fuel per year are investigated. Capital investments range from 356 to 1026 million USD. A unique biorefinery is explored to produce a hydrocarbon biofuel with a high yield from bone dry wood of 330 L t -1 . This yield is achieved chiefly due to the use of acetogenic bacteria that do not produce carbon dioxide as a co-product during fermentation. Capital investment is significant in the biorefinery in part because hydrogen is required to produce a fully de-oxygenated fuel. Minimum selling price to achieve reasonable returns on investment is sensitive to capital financing options because of high capital costs. Various strategies, such as producing alternative, intermediate products, are investigated with the intent to reduce risk in building the proposed facility. It appears that producing and selling these

  16. Low oxygen biomass-derived pyrolysis oils and methods for producing the same

    Science.gov (United States)

    Marinangeli, Richard; Brandvold, Timothy A; Kocal, Joseph A

    2013-08-27

    Low oxygen biomass-derived pyrolysis oils and methods for producing them from carbonaceous biomass feedstock are provided. The carbonaceous biomass feedstock is pyrolyzed in the presence of a catalyst comprising base metal-based catalysts, noble metal-based catalysts, treated zeolitic catalysts, or combinations thereof to produce pyrolysis gases. During pyrolysis, the catalyst catalyzes a deoxygenation reaction whereby at least a portion of the oxygenated hydrocarbons in the pyrolysis gases are converted into hydrocarbons. The oxygen is removed as carbon oxides and water. A condensable portion (the vapors) of the pyrolysis gases is condensed to low oxygen biomass-derived pyrolysis oil.

  17. Sulphur capture by co-firing sulphur containing fuels with biomass fuels - optimization

    International Nuclear Information System (INIS)

    Nordin, A.

    1992-12-01

    Previous results concerning co-firing of high sulphur fuels with biomass fuels have shown that a significant part of the sulphur can be absorbed in the ash by formation of harmless sulphates. The aim of this work has been to (i) determine the maximum reduction that can be obtained in a bench scaled fluidized bed (5 kW); (ii) determine which operating conditions will give maximum reduction; (iii) point out the importance and applicability of experimental designs and multivariate methods when optimizing combustion processes; (iv) determine if the degree of sulphur capture can be correlated to the degree of slagging, fouling or bed sintering; and (v) determine if further studies are desired. The following are some of the more important results obtained: - By co-firing peat with biomass, a total sulphur retention of 70 % can be obtained. By co-firing coal with energy-grass, the total SO 2 emissions can be reduced by 90 %. - Fuel feeding rate, amount of combustion air and the primary air ratio were the most important operating parameters for the reduction. Bed temperature and oxygen level seem to be the crucial physical parameters. - The NO emissions also decreased by the sulphur reducing measures. The CO emissions were relatively high (130 mg/MJ) compared to large scale facilities due to the small reactor and the small fluctuations in the fuel feeding rate. The SO 2 emissions could however be reduced without any increase in CO emissions. - When the reactor was fired with a grass, the bed sintered at a low temperature ( 2 SO 4 and KCl are formed no sintering problems were observed. (27 refs., 41 figs., 9 tabs., 3 appendices)

  18. Hydroliquefaction of green wastes to produce fuels.

    Science.gov (United States)

    Beauchet, R; Pinard, L; Kpogbemabou, D; Laduranty, J; Lemee, L; Lemberton, J L; Bataille, F; Magnoux, P; Ambles, A; Barbier, J

    2011-05-01

    The direct liquefaction of a biomass composed of a mixture of wastes (straw, wood and grass) was studied using Nickel Raney as catalyst and tetralin as a solvent. Tetralin allows to solubilize green waste from 330°C at relatively low hydrogen pressure, and avoids the recondensation of the intermediate products. The green waste deoxygenation results mainly from a decarboxylation reaction. The addition of Raney Ni in the feed, increases the gas yield due to methane formation, without diminishing the yield in solvolysis oil. The catalyst hydrogenolyses the small molecules present in the light fraction. Moreover, it improves the quality of the oil by increasing the hydrogen transfer between the solvent and the solvolysis oil. As a consequence, the oxygen content decreases and the yield of oil soluble in hexane strongly increases. The catalyst allows to obtain straight long chain alkanes (C(13)-C(26)), which result from the hydrogenation of the extractives compounds of the green waste. Copyright © 2011 Elsevier Ltd. All rights reserved.

  19. Ash related behaviour in staged and non-staged combustion of biomass fuels and fuel mixtures

    International Nuclear Information System (INIS)

    Becidan, Michaël; Todorovic, Dusan; Skreiberg, Øyvind; Khalil, Roger A.; Backman, Rainer; Goile, Franziska; Skreiberg, Alexandra; Jovovic, Aleksandar; Sørum, Lars

    2012-01-01

    The fate of selected elements (with focus on the important players in corrosion i.e. Na, K, Pb, Zn, Cl and S) are investigated for three biomasses (wood, demolition wood and coffee waste) and six mixtures of these as pellets both with and without air staging in a laboratory reactor. In order to get a complete overview of the combustion products, both online and offline analytical methods are used. Information is collected about: flue gas composition, particle (fly ash) size distribution and composition, bottom ash composition and melting properties. The main findings are: (1) complex interactions are taking place between the mixed fuels during combustion; (2) the mode of occurrence of an element as well as the overall structure of the fuel are important for speciation; (3) the pelletisation process, by bringing chemical elements into intimate contact, may affect partitioning and speciation; (4) staging and mixing might simultaneously have positive and negative effects on operation; (5) staging affects the governing mechanisms of fly ash (aerosols) formation. -- Highlights: ► Complex interactions are taking place between the mixed fuels during combustion. ► The mode of occurrence of an element as well as the overall structure of the fuel are important for speciation. ► The pelletisation process, by bringing chemical elements into intimate contact, may affect partitioning and speciation. ► Staging and mixing might simultaneously have positive and negative effects on operation. ► Staging affects the governing mechanisms of fly ash (aerosols) formation.

  20. Biomass pyrolysis: use of some agricultural wastes for alternative fuel production

    International Nuclear Information System (INIS)

    Kimura, Lygia Maestri; Santos, Larissa Cardoso; Vieira, Paula Fraga; Parreira, Priciane Martins; Henrique, Humberto Molinar

    2009-01-01

    The use of biomass for energy generation has aroused great attention and interest because of the global climate changes, environmental pollution and reduction of availability of fossil energy. This study deals with pyrolysis of four agricultural wastes (sawdust, sugarcane straw, chicken litter and cashew nut shell) in a fixed bed pyrolytic reactor. The yields of char, liquid and gas were quantified at 300, 400, 500, 600 and 700 deg C and the temperature and pressure effects were investigated. Pyrolytic liquids produced were separated into aqueous and oil phases. XRF spectroscopy was used for qualitative and quantitative elemental analysis of the liquids and solids produced at whole temperature range. Calorific value analysis of liquids and solids were also performed for energy content evaluation. Experimental results showed sawdust, sugarcane straw and cashew nut waste have very good potential for using in pyrolysis process for alternative fuel production. (author)

  1. Subtask 3.11 - Production of CBTL-Based Jet Fuels from Biomass-Based Feedstocks and Montana Coal

    Energy Technology Data Exchange (ETDEWEB)

    Sharma, Ramesh

    2014-06-01

    The Energy & Environmental Research Center (EERC), in partnership with the U.S. Department of Energy (DOE) and Accelergy Corporation, an advanced fuels developer with technologies exclusively licensed from Exxon Mobil, undertook Subtask 3.11 to use a recently installed bench-scale direct coal liquefaction (DCL) system capable of converting 45 pounds/hour of pulverized, dried coal to a liquid suitable for upgrading to fuels and/or chemicals. The process involves liquefaction of Rosebud mine coal (Montana coal) coupled with an upgrading scheme to produce a naphthenic fuel. The upgrading comprises catalytic hydrotreating and saturation to produce naphthenic fuel. A synthetic jet fuel was prepared by blending equal volumes of naphthenic fuel with similar aliphatic fuel derived from biomass and 11 volume % of aromatic hydrocarbons. The synthetic fuel was tested using standard ASTM International techniques to determine compliance with JP-8 fuel. The composite fuel thus produced not only meets but exceeds the military aviation fuel-screening criteria. A 500-milliliter synthetic jet fuel sample which met internal screening criteria was submitted to the Air Force Research Laboratory (AFRL) at Wright–Patterson Air Force Base, Dayton, Ohio, for evaluation. The sample was confirmed by AFRL to be in compliance with U.S. Air Force-prescribed alternative aviation fuel initial screening criteria. The results show that this fuel meets or exceeds the key specification parameters for JP-8, a petroleum-based jet fuel widely used by the U.S. military. JP-8 specifications include parameters such as freeze point, density, flash point, and others; all of which were met by the EERC fuel sample. The fuel also exceeds the thermal stability specification of JP-8 fuel as determined by the quartz crystalline microbalance (QCM) test also performed at an independent laboratory as well as AFRL. This means that the EERC fuel looks and acts identically to petroleum-derived jet fuel and can be used

  2. Raw material and market for biomass fuel; Raastoff og marked for biobrensel

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-12-31

    The report from a conference deals with raw material and market relations for biomass fuel in Norway. The proceedings cover themes like requirements concerning quality and purity, supply of raw materials, supply and production of chips, supply and market for industrial waste and wood waste, supply of raw materials and market relations for pellets, practical experience from a pelletizing plant, use of source selected paper as a biomass fuel, use of bio-carbon in the ferro-alloy industry, biomass fuel and waste in the cement industry - technical requirements and experience of utilization, processed biomass fuel from wastes - possible niches of marketing, and evaluation of a bio-energy project. 9 figs., 12 tabs.

  3. Proposed Renewable Fuel Standards for 2017, and the Biomass-Based Diesel Volume for 2018

    Science.gov (United States)

    EPA is proposing the volume requirements and associated percentage standards that would apply under the RFS program in calendar years 2016, 2017 and 2018 for cellulosic biofuel, biomass-based diesel, advanced biofuel, and total renewable fuel.

  4. Environmental, Economic, and Scalability Considerations and Trends of Selected Fuel Economy-Enhancing Biomass-Derived Blendstocks

    Energy Technology Data Exchange (ETDEWEB)

    Dunn, Jennifer B. [Systems; Biddy, Mary [National; Jones, Susanne [Energy; Cai, Hao [Systems; Benavides, Pahola Thathiana [Systems; Markham, Jennifer [National; Tao, Ling [National; Tan, Eric [National; Kinchin, Christopher [National; Davis, Ryan [National; Dutta, Abhijit [National; Bearden, Mark [Energy; Clayton, Christopher [Energy; Phillips, Steven [Energy; Rappé, Kenneth [Energy; Lamers, Patrick [Bioenergy

    2017-10-30

    24 biomass-derived compounds and mixtures, identified based on their physical properties, that could be blended into fuels to improve spark ignition engine fuel economy were assessed for their economic, technology readiness, and environmental viability. These bio-blendstocks were modeled to be produced biochemically, thermochemically, or through hybrid processes. To carry out the assessment, 17 metrics were developed for which each bio-blendstock was determined to be favorable, neutral, or unfavorable. Cellulosic ethanol was included as a reference case. Overall, bio-blendstock yields in biochemical processes were lower than in thermochemical processes, in which all biomass, including lignin, is converted to a product. Bio-blendstock yields were a key determinant in overall viability. Key knowledge gaps included the degree of purity needed for use as a bio-blendstock as compared to a chemical. Less stringent purification requirements for fuels could cut processing costs and environmental impacts. Additionally, more information is needed on the blendability of many of these bio-blendstocks with gasoline to support the technology readiness evaluation. Overall, the technology to produce many of these blendstocks from biomass is emerging and as it matures, these assessments must be revisited. Importantly, considering economic, environmental, and technology readiness factors in addition to physical properties of blendstocks that could be used to boost fuel economy can help spotlight those most likely to be viable in the near term.

  5. Costs of Producing Biomass from Riparian Buffer Strips

    Energy Technology Data Exchange (ETDEWEB)

    Turhollow, A.

    2000-09-01

    Nutrient runoff from poultry litter applied to agricultural fields in the Delmarva Peninsula contributes to high nutrient loadings in Chesapeake Bay. One potential means of ameliorating this problem is the use of riparian buffer strips. Riparian buffer strips intercept overland flows of water, sediments, nutrients, and pollutants; and ground water flows of nutrients and pollutants. Costs are estimated for three biomass systems grown on buffer strips: willow planted at a density of 15,300 trees/ha (6200 trees/acre); poplar planted at a density of 1345 trees/ha (545 trees/acre); and switchgrass. These costs are estimated for five different scenarios: (1) total economic costs, where everything is costed [cash costs, noncash costs (e.g., depreciation), land rent, labor]; (2) costs with Conservation Reserve Program (CRP) payments (which pays 50% of establishment costs and an annual land rent); (3) costs with enhanced CRP payments (which pays 95% of establishment costs and an annual payment of approximately 170% of land rent for trees and 150% of land rent for grasses); (4) costs when buffer strips are required, but harvest of biomass is not required [costs borne by biomass are for yield enhancing activities (e.g., fertilization), harvest, and transport]; and (5) costs when buffer strips are required. and harvest of biomass is required to remove nutrients (costs borne by biomass are for yield enhancing activities and transport). CRP regulations would have to change to allow harvest. Delivered costs of willow, poplar, and switchgrass [including transportation costs of $0.38/GJ ($0.40/million Btu) for switchgrass and $0.57/GJ ($0.60/million Btu) for willow and poplar] at 11.2 dry Mg/ha-year (5 dry tons/acre-year) for the five cost scenarios listed above are [$/GJ ($million BIN)]: (1) 3.30-5.45 (3.45-5.75); (2) 2.30-3.80 (2.45-4.00); (3) 1.70-2.45 (1.80-2.60); (4) l-85-3.80 (1.95-4.05); and (5) 0.80-1.50 (0.85-1.60). At yields of 15.7 to 17.9 GJ/ha-year (7 to 8 dry tons

  6. Electrocatalytic water splitting to produce fuel hydrogen

    Science.gov (United States)

    Yuan, Hao

    Solar energy is regarded as a promising source for clean and sustainable energy. However, it is not a continuous energy source, thus certain strategies have to be developed to effectively convert and store it. Solar-driven electrocatalytic water splitting, which converts solar energy into chemical energy for storage as fuel hydrogen, can effectively mitigate the intermittence of solar radiation. Water splitting consists of two half reactions: water oxidation and hydrogen evolution. Both reactions rely on highly effective electrocatalysts. This dissertation is an account of four detailed studies on developing highly effective low-cost electrocatalysts for both reactions, and includes a preliminary attempt at system integration to build a functional photoanode for solar-driven water oxidation. For the water oxidation reaction, we have developed an electrochemical method to immobilize a cobalt-based (Co-OXO) water oxidation catalyst on a conductive surface to promote recyclability and reusability without affecting functionality. We have also developed a method to synthesize a manganese-based (MnOx) catalytic film in situ, generating a nanoscale fibrous morphology that provides steady and excellent water oxidation performance. The new method involves two series of cyclic voltammetry (CV) over different potential ranges, followed by calcination to increase crystallinity. The research has the potential to open avenues for synthesizing and optimizing other manganese-based water oxidation catalysts. For the hydrogen evolution reaction, we have developed a new electrodeposition method to synthesize Ni/Ni(OH)2 catalysts in situ on conductive surfaces. The new method involves only two cycles of CV over a single potential range. The resulting catalytic film has a morphology of packed walnut-shaped particles. It has superior catalytic activity and good stability over long periods. We have investigated the feasibility of incorporating manganese-based water oxidation catalysts

  7. Direct Coal -to-Liquids (CTL) for Jet Fuel Using Biomass-Derived Solvents

    Energy Technology Data Exchange (ETDEWEB)

    Chauhan, Satya P. [Battelle, Columbus, OH (United States); Garbark, Daniel B. [Battelle, Columbus, OH (United States); Taha, Rachid [Battelle, Columbus, OH (United States); Peterson, Rick [Battelle, Columbus, OH (United States)

    2017-09-30

    Battelle has demonstrated a novel and potentially breakthrough technology for a direct coal-to-liquids (CTL) process for producing jet fuel using biomass-derived coal solvents (bio-solvents). The Battelle process offers a significant reduction in capital and operating costs and a substantial reduction in greenhouse gas (GHG) emissions, without requiring carbon capture and storage (CCS). The results of the project are the advancement of three steps of the hybrid coal/biomass-to-jet fuel process to the technology readiness level (TRL) of 5. The project objectives were achieved over two phases. In Phase 1, all three major process steps were explored and refined at bench-scale, including: (1) biomass conversion to high hydrogen-donor bio-solvent; (2) coal dissolution in biomass-derived bio-solvent, without requiring molecular H2, to produce a synthetic crude (syncrude); and (3) two-stage catalytic hydrotreating/hydrogenation of syncrude to jet fuel and other distillates. In Phase 2, all three subsystems of the CTL process were scaled up to a pre-pilot scale, and an economic analysis was carried out. A total of over 40 bio-solvents were identified and prepared. The most unique attribute of Battelle’s bio-solvents is their ability to provide much-needed hydrogen to liquefy coal and thus increase its hydrogen content so much that the resulting syncrude is liquid at room temperature. Based on the laboratory-scale testing with bituminous coals from Ohio and West Virginia, a total of 12 novel bio-solvent met the goal of greater than 80% coal solubility, with 8 bio-solvents being as good as or better than a well-known but expensive hydrogen-donor solvent, tetralin. The Battelle CTL process was then scaled up to 1 ton/day (1TPD) at a pre-pilot facility operated in Morgantown, WV. These tests were conducted, in part, to produce enough material for syncrude-upgrading testing. To convert the Battelle-CTL syncrude into a form suitable as a blending stock for jet

  8. Strategic analysis of biomass and waste fuels for electric power generation

    International Nuclear Information System (INIS)

    Wiltsee, G.A. Jr.; Easterly, J.; Vence, T.

    1993-12-01

    In this report, the Electric Power Research Institute (EPRI) intends to help utility companies evaluate biomass and wastes for power generation. These fuels may be alternatives or supplements to fossil fuels in three applications: (1) utility boiler coining; (2) dedicated combustion/energy recovery plants; and 3) dedicated gasification/combined cycle plants. The report summarizes data on biomass and waste properties, and evaluates the cost and performance of fuel preparation and power generation technologies. The primary biomass and waste resources evaluated are: (1) wood wastes (from forests, mills, construction/demolition, and orchards) and short rotation woody crops; (2) agricultural wastes (from fields, animals, and processing) and herbaceous energy crops; and (3) consumer or industrial wastes (e.g., municipal solid waste, scrap tires, sewage sludge, auto shredder waste). The major fuel types studied in detail are wood, municipal solid waste, and scrap tires. The key products of the project include the BIOPOWER model of biomass/waste-fired power plant performance and cost. Key conclusions of the evaluation are: (1) significant biomass and waste fuel resources are available; (2) biomass power technology cannot currently compete with natural gas-fired combined cycle technology; (3) coining biomass and waste fuels with coal in utility and industrial boilers is the most efficient, lowest cost, and lowest risk method of energy recovery from residual materials; (4) better biomass and waste fuel production and conversion technology must be developed, with the help of coordinated government energy and environmental policies and incentives; and (5) community partnerships can enhance the chances for success of a project

  9. Analytical Strategies Involved in the Detailed Componential Characterization of Biooil Produced from Lignocellulosic Biomass

    Directory of Open Access Journals (Sweden)

    Yao Lu

    2017-01-01

    Full Text Available Elucidation of chemical composition of biooil is essentially important to evaluate the process of lignocellulosic biomass (LCBM conversion and its upgrading and suggest proper value-added utilization like producing fuel and feedstock for fine chemicals. Although the main components of LCBM are cellulose, hemicelluloses, and lignin, the chemicals derived from LCBM differ significantly due to the various feedstock and methods used for the decomposition. Biooil, produced from pyrolysis of LCBM, contains hundreds of organic chemicals with various classes. This review covers the methodologies used for the componential analysis of biooil, including pretreatments and instrumental analysis techniques. The use of chromatographic and spectrometric methods was highlighted, covering the conventional techniques such as gas chromatography, high performance liquid chromatography, Fourier transform infrared spectroscopy, nuclear magnetic resonance, and mass spectrometry. The combination of preseparation methods and instrumental technologies is a robust pathway for the detailed componential characterization of biooil. The organic species in biooils can be classified into alkanes, alkenes, alkynes, benzene-ring containing hydrocarbons, ethers, alcohols, phenols, aldehydes, ketones, esters, carboxylic acids, and other heteroatomic organic compounds. The recent development of high resolution mass spectrometry and multidimensional hyphenated chromatographic and spectrometric techniques has considerably elucidated the composition of biooils.

  10. EVALUATION OF A PROCESS TO CONVERT BIOMASS TO METHANOL FUEL

    Science.gov (United States)

    The report gives results of a review of the design of a reactor capable of gasifying approximately 50 lb/hr of biomass for a pilot-scale facility to develop, demonstrate, and evaluate the Hynol Process, a high-temperature, high-pressure method for converting biomass into methanol...

  11. Fuels production by the thermochemical transformation of the biomass

    International Nuclear Information System (INIS)

    Claudet, G.

    2005-01-01

    The biomass is a local and renewable energy source, presenting many advantages. This paper proposes to examine the biomass potential in France, the energy valorization channels (thermochemical chains of thermolysis and gasification) with a special interest for the hydrogen production and the research programs oriented towards the agriculture and the forest. (A.L.B.)

  12. Factors Contributing to Use of Biomass as Domestic Fuel and ...

    African Journals Online (AJOL)

    Biomass energy dominates household cooking energy in developing countries and Nigeria is not exceptional. However, a number of implications such as indoor air pollution, environmental degradation and social burden have been associated with the use of biomass energy. The paper discusses factors that determine the ...

  13. Solar Program Assessment: Environmental Factors - Fuels from Biomass.

    Science.gov (United States)

    Energy Research and Development Administration, Washington, DC. Div. of Solar Energy.

    The purpose of this report is to present and prioritize the major environmental issues associated with the further development of biomass production and biomass conversion systems. To provide a background for this environmental analysis, the basic concepts of the technology are reviewed, as are resource requirements. The potential effects of this…

  14. TRANSPORTATION FUEL FROM CELLULOSIC BIOMASS: A COMPARATIVE ASSESSMENT OF ETHANOL AND METHANOL OPTIONS

    Science.gov (United States)

    Future sources of renewable fuel energy will be needed to supplement or displace petroleum. Biomass can be converted to ethanol or methanol, either having good properties as motor fuel, but distinctly different production technology. Those technologies are compared in terms of ...

  15. Forest biomass and tree planting for fossil fuel offsets in the Colorado Front Range

    Science.gov (United States)

    Mike A. Battaglia; Kellen Nelson; Dan Kashian; Michael G. Ryan

    2010-01-01

    This study estimates the amount of carbon available for removal in fuel reduction and reforestation treatments in montane forests of the Colorado Front Range based on site productivity, pre-treatment basal area, and planting density. Thinning dense stands will yield the greatest offsets for biomass fuel. However, this will also yield the greatest carbon losses, if the...

  16. Development of an efficient catalyst for the pyrolytic conversion of biomass into transport fuel

    NARCIS (Netherlands)

    Nguyen, T.S.

    2014-01-01

    Fast pyrolysis is a promising technique to convert biomass into a liquid fuel/fuel precursor, known as bio-oil. However, compared to conventional crude oil, bio-oil has much higher oxygen content which results in various detrimental properties and limits its application. Thus the first part of this

  17. 77 FR 5755 - Request for Proposals: 2012 Hazardous Fuels Woody Biomass Utilization Grant Program

    Science.gov (United States)

    2012-02-06

    ... program are to: Promote projects that target and help remove economic and market barriers to using woody... target market(s), extent of competition for supply and delivered costs and general characterization of... of biomass fuel available and realistic pricing information based on fuel specifications required by...

  18. 78 FR 11622 - Request for Proposals: 2013 Hazardous Fuels Woody Biomass Utilization Grant Program

    Science.gov (United States)

    2013-02-19

    ... infrastructure from wildfires. Goals of the grant program are to: Promote projects that target and help remove... target market(s), extent of competition for supply and delivered costs and general characterization of... project site; Types of biomass fuel available and realistic pricing information based on fuel...

  19. Bioaugmentation for Electricity Generation from Corn Stover Biomass Using Microbial Fuel Cells

    KAUST Repository

    Wang, Xin

    2009-08-01

    Corn stover is usually treated by an energy-intensive or expensive process to extract sugars for bioenergy production. However, it is possible to directly generate electricity from corn stover in microbial fuel cells (MFCs) through the addition of microbial consortia specifically acclimated for biomass breakdown. A mixed culture that was developed to have a high saccharification rate with corn stover was added to singlechamber, air-cathode MFCs acclimated for power production using glucose. The MFC produced a maximum power of 331 mW/ m 2 with the bioaugmented mixed culture and corn stover, compared to 510 mW/m2 using glucose. Denaturing gradient gel electrophoresis (DGGE) showed the communities continued to evolve on both the anode and corn stover biomass over 60 days, with several bacteria identified including Rhodopseudomonas palustris. The use of residual solids from the steam exploded corn stover produced 8% more power (406 mW/m2) than the raw corn stover. These results show that it is possible to directly generate electricity from waste corn stover in MFCs through bioaugmentation using naturally occurring bacteria. © 2009 American Chemical Society.

  20. A cross-system synthesis of consumer and nutrient resource control on producer biomass.

    Science.gov (United States)

    Gruner, Daniel S; Smith, Jennifer E; Seabloom, Eric W; Sandin, Stuart A; Ngai, Jacqueline T; Hillebrand, Helmut; Harpole, W Stanley; Elser, James J; Cleland, Elsa E; Bracken, Matthew E S; Borer, Elizabeth T; Bolker, Benjamin M

    2008-07-01

    Nutrient availability and herbivory control the biomass of primary producer communities to varying degrees across ecosystems. Ecological theory, individual experiments in many different systems, and system-specific quantitative reviews have suggested that (i) bottom-up control is pervasive but top-down control is more influential in aquatic habitats relative to terrestrial systems and (ii) bottom-up and top-down forces are interdependent, with statistical interactions that synergize or dampen relative influences on producer biomass. We used simple dynamic models to review ecological mechanisms that generate independent vs. interactive responses of community-level biomass. We calibrated these mechanistic predictions with the metrics of factorial meta-analysis and tested their prevalence across freshwater, marine and terrestrial ecosystems with a comprehensive meta-analysis of 191 factorial manipulations of herbivores and nutrients. Our analysis showed that producer community biomass increased with fertilization across all systems, although increases were greatest in freshwater habitats. Herbivore removal generally increased producer biomass in both freshwater and marine systems, but effects were inconsistent on land. With the exception of marine temperate rocky reef systems that showed positive synergism of nutrient enrichment and herbivore removal, experimental studies showed limited support for statistical interactions between nutrient and herbivory treatments on producer biomass. Top-down control of herbivores, compensatory behaviour of multiple herbivore guilds, spatial and temporal heterogeneity of interactions, and herbivore-mediated nutrient recycling may lower the probability of consistent interactive effects on producer biomass. Continuing studies should expand the temporal and spatial scales of experiments, particularly in understudied terrestrial systems; broaden factorial designs to manipulate independently multiple producer resources (e.g. nitrogen

  1. Potential high temperature corrosion problems due to co-firing of biomass and fossil fuels

    DEFF Research Database (Denmark)

    Montgomery, Melanie; Vilhelmsen, T.; Jensen, S.A.

    2007-01-01

    Over the past years, considerable high temperature corrosion problems have been encountered when firing biomass in power plants due to the high content of potassium chloride in the deposits. Therefore to combat chloride corrosion problems co-firing of biomass with a fossil fuel has been undertaken...... significant corrosion attack was due to sulphidation attack at the grain boundaries of 18-8 steel after 3 years exposure. The corrosion mechanisms and corrosion rates are compared with biomass firing and coal firing. Potential corrosion problems due to co-firing biomass and fossil fuels are discussed....... appear such as sulphidation and hot corrosion due to sulphate deposits. At Studstrup power plant Unit 4, based on trials with exposure times of 3000 hours using 0-20% straw co-firing with coal, the plant now runs with a fuel of 10% straw + coal. After three years exposure in this environment...

  2. Potential high temperature corrosion problems due to co-firing of biomass and fossil fuels

    DEFF Research Database (Denmark)

    Montgomery, Melanie; Vilhelmsen, T.; Jensen, S.A.

    2008-01-01

    Over the past few years, considerable high temperature corrosion problems have been encountered when firing biomass in power plants due to the high content of potassium chloride in the deposits. Therefore, to combat chloride corrosion problems cofiring of biomass with a fossil fuel has been....... However, the most significant corrosion attack was sulphidation attack at the grain boundaries of 18-8 steel after 3 years exposure. The corrosion mechanisms and corrosion rates are compared with biomass firing and coal firing. Potential corrosion problems due to co-firing biomass and fossil fuels...... corrosion mechanisms appear such as sulphidation and hot corrosion due to sulphate deposits. At Studstrup power plant Unit 4, based on trials with exposure times of 3000 h using 0–20% straw co-firing with coal, the plant now runs with a fuel mix of 10% strawþcoal. Based on results from a 3 years exposure...

  3. Liquid fuels production from biomass. Progress report No. 7, January 1-March 31, 1979

    Energy Technology Data Exchange (ETDEWEB)

    Sanderson, J.E.; Garcia-Martinez, D.V.; George, G.S.; Dillon, J.J.; Wise, D.L.

    1979-01-01

    The current program to convert biomass into liquid hydrocarbon fuels is an extension of the previous program to ferment marine algae to acetic acid. In that study, it was found that marine algae could be converted to higher aliphatic organic acids and that these acids could be readily removed from the fermentation broth by membrane or liquid-liquid extraction. It was then proposed to convert these higher organic acids to aliphatic hydrocarbons via Kolbe Electrolysis, which may be used as a diesel fuel. The specific goals for the current program are: (1) establish conditions under which substrates other than marine algae may be converted in good yield to organic acids. The primary task in this regard is methane suppression; (2) modify the current 300 liter fixed packed bed batch fermenter to operate in a continuous mode; (3) change from membrane extraction of organic acids to liquid-liquid extraction; (4) optimize the energy balance of the electrolytic oxidation process. The primary task in this regard is to reduce the working potential required for the electrolysis while maintaining an adequate current density; (5) scale the entire process up to match the ouput of the 300 liter fermenter. The accomplishments in this program are on schedule. Experimental results have shown that the electrolysis of organic acids produced by fermentation to liquid hydrocarbon fuels is already operating with a favorable energy balance of 6/1 based on the applied potential and over 10/1 based on the working potential. 2-Bromoethanesulfonic acid, a coenzyme M analogue, has been shown to be an effective methane suppressor, and the program is being rapidly expanded to include biomass substrates other than marine algae. In addition, considerable effort has been directed toward refining the process design and economic analysis presented previously.

  4. LEU fuel element produced by the Egyptian fuel manufacturing pilot plant

    International Nuclear Information System (INIS)

    Zidan, W.I.

    2000-01-01

    The Egyptian Fuel Manufacturing Pilot Plant, FMPP, is a Material Testing Reactor type (MTR) fuel element facility, for producing the specified fuel elements required for the Egyptian Second Research Reactor, ETRR-2. The plant uses uranium hexafluoride (UF 6 , 19.75% U 235 by wt) as a raw material which is processed through a series of the manufacturing, inspection and test plan to produce the final specified fuel elements. Radiological safety aspects during design, construction, operation, and all reasonably accepted steps should be taken to prevent or reduce the chance of accidents occurrence. (author)

  5. Scientific bases of biomass processing into basic component of aviation fuel

    Science.gov (United States)

    Kachalov, V. V.; Lavrenov, V. A.; Lishchiner, I. I.; Malova, O. V.; Tarasov, A. L.; Zaichenko, V. M.

    2016-11-01

    A combination of feedstock pyrolysis and the cracking of the volatile pyrolysis products on the charcoal at 1000 °C allows to obtain a tarless synthesis gas which contains 90 vol% or more of carbon monoxide and hydrogen in approximately equal proportions. Basic component of aviation fuel was synthesized in a two-stage process from gas obtained by pyrolytic processing of biomass. Methanol and dimethyl ether can be efficiently produced in a two-layer loading of methanolic catalyst and γ-Al2O3. The total conversion of CO per pass was 38.2% using for the synthesis of oxygenates a synthesis gas with adverse ratio of H2/CO = 0.96. Conversion of CO to CH3OH was 15.3% and the conversion of CO to dimethyl ether was 20.9%. A high yield of basic component per oxygenates mass (44.6%) was obtained during conversion. The high selectivity of the synthesis process for liquid hydrocarbons was observed. An optimal recipe of aviation fuel B-92 based on a synthesized basic component was developed. The prototype of aviation fuel meets the requirements for B-92 when straight fractions of 50-100 °C (up to 35 wt%), isooctane (up to 10 wt%) and ethyl fluid (2.0 g/kg calculated as tetraethyl lead) is added to the basic component.

  6. Potential of Tropical Fruit Waste Biomass for Production of Bio-Briquette Fuel: Using Indonesia as an Example

    Directory of Open Access Journals (Sweden)

    Anna Brunerová

    2017-12-01

    Full Text Available Within developing countries, there is an appeal to use waste biomass for energy generation in the form of bio-briquettes. This study investigated the potential use of bio-briquettes that are produced from the waste biomass of the following tropical fruits: durian (Durio zibethinus, coconut (Cocos nucifera, coffee (Coffea arabica, cacao (Theobroma cacao, banana (Musa acuminata and rambutan (Nephelium lappaceum. All fruit waste biomass samples exhibited an extremely high level of initial moisture content (78.22% in average. Fruit samples with the highest proportion of fruit waste biomass (of total unprocessed fruit mass were represented by cacao (83.82%, durian (62.56% and coconut (56.83%. Highest energy potentials (calorific value of fruit waste biomass were observed in case of coconut (18.22 MJ∙kg−1, banana (17.79 MJ∙kg−1 and durian (17.60 MJ∙kg−1 fruit samples, whereas fruit waste biomass with the lowest level of ash content originated from the rambutan (3.67%, coconut (4.52%, and durian (5.05% fruit samples. When investigating the energy demands to produce bio-briquettes from such feedstock materials, the best results (lowest amount of required deformation energy in combination with highest level of bio-briquette bulk density were achieved by the rambutan, durian and banana fruit waste biomass samples. Finally, all investigated bio-briquette samples presented satisfactory levels of bulk density (>1050 kg∙m−3. In conclusion, our results indicated the practicability and viability of such bio-briquette fuel production, as well as supporting the fact that bio-briquettes from tropical fruit waste biomass can offer a potentially attractive energy source with many benefits, especially in rural areas.

  7. Laboratory Scale Coal And Biomass To Drop-In Fuels (CBDF) Production And Assessment

    Energy Technology Data Exchange (ETDEWEB)

    Lux, Kenneth [Altex Technologies Corporation, Sunnyvale, CA (United States); Imam, Tahmina [Altex Technologies Corporation, Sunnyvale, CA (United States); Chevanan, Nehru [Altex Technologies Corporation, Sunnyvale, CA (United States); Namazian, Mehdi [Altex Technologies Corporation, Sunnyvale, CA (United States); Wang, Xiaoxing [Pennsylvania State Univ., University Park, PA (United States); Song, Chunshan [Pennsylvania State Univ., University Park, PA (United States)

    2016-06-29

    This Final Technical Report describes the work and accomplishments of the project entitled, “Laboratory Scale Coal and Biomass to Drop-In Fuels (CBDF) Production and Assessment.” The main objective of the project was to fabricate and test a lab-scale liquid-fuel production system using coal containing different percentages of biomass such as corn stover and switchgrass at a rate of 2 liters per day. The system utilizes the patented Altex fuel-production technology, which incorporates advanced catalysts developed by Pennsylvania State University. The system was designed, fabricated, tested, and assessed for economic and environmental feasibility relative to competing technologies.

  8. Global combustion: the connection between fossil fuel and biomass burning emissions (1997–2010)

    Science.gov (United States)

    Balch, Jennifer K.; Nagy, R. Chelsea; Archibald, Sally; Moritz, Max A.; Williamson, Grant J.

    2016-01-01

    Humans use combustion for heating and cooking, managing lands, and, more recently, for fuelling the industrial economy. As a shift to fossil-fuel-based energy occurs, we expect that anthropogenic biomass burning in open landscapes will decline as it becomes less fundamental to energy acquisition and livelihoods. Using global data on both fossil fuel and biomass burning emissions, we tested this relationship over a 14 year period (1997–2010). The global average annual carbon emissions from biomass burning during this time were 2.2 Pg C per year (±0.3 s.d.), approximately one-third of fossil fuel emissions over the same period (7.3 Pg C, ±0.8 s.d.). There was a significant inverse relationship between average annual fossil fuel and biomass burning emissions. Fossil fuel emissions explained 8% of the variation in biomass burning emissions at a global scale, but this varied substantially by land cover. For example, fossil fuel burning explained 31% of the variation in biomass burning in woody savannas, but was a non-significant predictor for evergreen needleleaf forests. In the land covers most dominated by human use, croplands and urban areas, fossil fuel emissions were more than 30- and 500-fold greater than biomass burning emissions. This relationship suggests that combustion practices may be shifting from open landscape burning to contained combustion for industrial purposes, and highlights the need to take into account how humans appropriate combustion in global modelling of contemporary fire. Industrialized combustion is not only an important driver of atmospheric change, but also an important driver of landscape change through companion declines in human-started fires. This article is part of the themed issue ‘The interaction of fire and mankind’. PMID:27216509

  9. Global combustion: the connection between fossil fuel and biomass burning emissions (1997-2010).

    Science.gov (United States)

    Balch, Jennifer K; Nagy, R Chelsea; Archibald, Sally; Bowman, David M J S; Moritz, Max A; Roos, Christopher I; Scott, Andrew C; Williamson, Grant J

    2016-06-05

    Humans use combustion for heating and cooking, managing lands, and, more recently, for fuelling the industrial economy. As a shift to fossil-fuel-based energy occurs, we expect that anthropogenic biomass burning in open landscapes will decline as it becomes less fundamental to energy acquisition and livelihoods. Using global data on both fossil fuel and biomass burning emissions, we tested this relationship over a 14 year period (1997-2010). The global average annual carbon emissions from biomass burning during this time were 2.2 Pg C per year (±0.3 s.d.), approximately one-third of fossil fuel emissions over the same period (7.3 Pg C, ±0.8 s.d.). There was a significant inverse relationship between average annual fossil fuel and biomass burning emissions. Fossil fuel emissions explained 8% of the variation in biomass burning emissions at a global scale, but this varied substantially by land cover. For example, fossil fuel burning explained 31% of the variation in biomass burning in woody savannas, but was a non-significant predictor for evergreen needleleaf forests. In the land covers most dominated by human use, croplands and urban areas, fossil fuel emissions were more than 30- and 500-fold greater than biomass burning emissions. This relationship suggests that combustion practices may be shifting from open landscape burning to contained combustion for industrial purposes, and highlights the need to take into account how humans appropriate combustion in global modelling of contemporary fire. Industrialized combustion is not only an important driver of atmospheric change, but also an important driver of landscape change through companion declines in human-started fires.This article is part of the themed issue 'The interaction of fire and mankind'. © 2016 The Author(s).

  10. Pressurised combustion of biomass-derived, low calorific value, fuel gas

    Energy Technology Data Exchange (ETDEWEB)

    Andries, J.; Hoppesteyn, P.D.J.; Hein, K.R.G. [Lab. for Thermal Power Engineering, Dept. of Mechanical Engineering and Marine Technology, Delft Univ. of Technology (Netherlands)

    1996-12-31

    The Laboratory for Thermal Power Engineering of the Delft University of Technology is participating in an EU-funded, international R + D project which is designed to aid European industry in addressing issues regarding pressurised combustion of biomass-derived, low calorific flue fuel gas. The objects of the project are: To design, manufacture and test a pressurised, high temperature gas turbine combustor for biomass derived LCV fuel gas; to develop a steady-state and dynamic model describing a combustor using biomass-derived, low calorific value fuel gases; to gather reliable experimental data on the steady-state and dynamic characteristics of the combustor; to study the steady-state and dynamic plant behaviour using a plant layout wich incorporates a model of a gas turbine suitable for operation on low calorific value fuel gas. (orig)

  11. Hydrodeoxygenation processes: advances on catalytic transformations of biomass-derived platform chemicals into hydrocarbon fuels.

    Science.gov (United States)

    De, Sudipta; Saha, Basudeb; Luque, Rafael

    2015-02-01

    Lignocellulosic biomass provides an attractive source of renewable carbon that can be sustainably converted into chemicals and fuels. Hydrodeoxygenation (HDO) processes have recently received considerable attention to upgrade biomass-derived feedstocks into liquid transportation fuels. The selection and design of HDO catalysts plays an important role to determine the success of the process. This review has been aimed to emphasize recent developments on HDO catalysts in effective transformations of biomass-derived platform molecules into hydrocarbon fuels with reduced oxygen content and improved H/C ratios. Liquid hydrocarbon fuels can be obtained by combining oxygen removal processes (e.g. dehydration, hydrogenation, hydrogenolysis, decarbonylation etc.) as well as by increasing the molecular weight via C-C coupling reactions (e.g. aldol condensation, ketonization, oligomerization, hydroxyalkylation etc.). Fundamentals and mechanistic aspects of the use of HDO catalysts in deoxygenation reactions will also be discussed. Copyright © 2014 Elsevier Ltd. All rights reserved.

  12. Multi-scale sustainability assessments for biomass-based and coal-based fuels in China.

    Science.gov (United States)

    Man, Yi; Xiao, Honghua; Cai, Wei; Yang, Siyu

    2017-12-01

    Transportation liquid fuels production is heavily depend on oil. In recent years, developing biomass based and coal based fuels are regarded as promising alternatives for non-petroleum based fuels in China. With the rapid growth of constructing and planning b biomass based and coal based fuels production projects, sustainability assessments are needed to simultaneously consider the resource, the economic, and the environmental factors. This paper performs multi-scale analyses on the biomass based and coal based fuels in China. The production cost, life cycle cost, and ecological life cycle cost (ELCC) of these synfuels are investigated to compare their pros to cons and reveal the sustainability. The results show that BTL fuels has high production cost. It lacks of economic attractiveness. However, insignificant resource cost and environmental cost lead to a substantially lower ELCC, which may indicate better ecological sustainability. CTL fuels, on the contrary, is lower in production cost and reliable for economic benefit. But its coal consumption and pollutant emissions are both serious, leading to overwhelming resource cost and environmental cost. A shifting from petroleum to CTL fuels could double the ELCC, posing great threat to the sustainability of the entire fuels industry. Copyright © 2017 Elsevier B.V. All rights reserved.

  13. Improvement of the competitiveness of biomass fuels by developing combustion technologies - new research facilities to Saarijaervi

    Energy Technology Data Exchange (ETDEWEB)

    Orjala, M.; Leino, T.; Kaerki, J.; Haemaelaeinen, J. (VTT Technical Research Centre of Finland, Jyvaeskylae (Finland)), Email: markku.orjala@vtt.fi, Email: timo.leino@vtt.fi, Email: janne.karki@vtt.fi, Email: jouni.hamalainen@vtt.fi

    2009-07-01

    The global use of biomass fuels is increasing significantly which also means that the fuel assortment will be increased strongly in the future. These new fuels, however, are often more challenging from the point of both production and site handling methods, and their combustion properties than the more traditional fuels. The increment of the biomass assortment creates a need for further development of combustion technologies. VTT creates with its collaborators possibilities for new generation multi-fuel boiler research and product development environment that enables the development of efficient solutions for utilisation of new biomass fuels. The research environment will be constructed during 2009 by the side of the new heating plant located at Saarijaervi. 'The future multi-fuel boiler' - research environment offers a unique possibility to develop solutions for the total biomass chain, from production of the fuel to fuel handling, and the combustion process. The research environment offers abilities, e.g. the analysis of the total biomass supply chain and new concept demonstration, as well as training possibilities for both domestic and international customers of Finnish equipment suppliers. Through the research and development abilities VTT and its co-operators want to develop the branch in co-operation with all actors in bioenergy chain. Co-operators in the research are currently Saarijaerven Kaukolaempoe Oy, boiler supplier Putkimaa, University of Jyvaeskylae and JAMK University of Applied Sciences. In the future the objective is to increase both the national and European co-operation with universities, equipment suppliers and energy companies, and hence to improve the competitiveness of Finnish equipment suppliers and energy companies, and hence to improve the competitiveness of Finnish equipment suppliers on the international markets. (orig.)

  14. Biomass fuel exposure and asthma symptoms among rural school children in Nigeria.

    Science.gov (United States)

    Oluwole, Oluwafemi; Arinola, Ganiyu O; Huo, Dezheng; Olopade, Christopher O

    2017-05-01

    Approximately 70% of rural Nigerian households rely on biomass fuels for cooking. The International Study of Asthma and Allergies in Childhood (ISAAC) estimates the prevalence of current wheeze among children in Nigeria to have risen from 10.7% in 1999 to approximately 20% in 2014. To examine the effects of biomass smoke exposure on asthma symptom prevalence in rural children in Nigeria. We conducted a cross-sectional survey in rural communities in Nigeria. Asthma symptoms were defined according to ISAAC definitions. Biomass smoke exposure was determined by the types of fuel used for cooking. Logistic regression was used to explore associations between biomass smoke and asthma symptoms. The study population comprised 1,690 school children, of which 865 lived in households cooking with biomass and 825 lived in households not using biomass. Asthma symptoms were reported in 481 (28.5%) children. Biomass fuel was associated with increased odds of asthma symptoms. Adjusted odds ratios (aORs) were 1.38 (95% CI: 1.05-1.80) for nocturnal cough, 1.26 (95% CI: 1.00-1.61) for current wheeze, and 1.33 (95% CI: 1.05-1.69) for report of any asthma-related symptoms. Sex modified the associations between asthma symptoms with biomass fuel: aORs were stronger and significant for males (nocturnal cough = 1.85, 95% CI: 1.24-2.76; current wheeze = 1.48, 95% CI: 1.03-2.13; report of any asthma-related symptoms = 1.60, 95% CI: 1.12-2.28), but weaker and non-significant for females. The risk of asthma symptoms related to biomass smoke exposure appears to differ by sex.

  15. Air Quality and Acute Respiratory Illness in Biomass Fuel using homes in Bagamoyo, Tanzania

    Directory of Open Access Journals (Sweden)

    Satoshi Nakai

    2007-03-01

    Full Text Available Respiratory Diseases are public health concern worldwide. The diseases have been associated with air pollution especially indoor air pollution from biomass fuel burning in developing countries. However, researches on pollution levels and on association of respiratory diseases with biomass fuel pollution are limited. A study was therefore undertaken to characterize the levels of pollutants in biomass fuel using homes and examine the association between biomass fuel smoke exposure and Acute Respiratory Infection (ARI disease in Nianjema village in Bagamoyo, Tanzania. Pollution was assessed by measuring PM10, NO2, and CO concentrations in kitchen, living room and outdoors. ARI prevalence was assessed by use of questionnaire which gathered health information for all family members under the study. Results showed that PM10, NO2, and CO concentrations were highest in the kitchen and lowest outdoors. Kitchen concentrations were highest in the kitchen located in the living room for all pollutants except CO. Family size didn’t have effect on the levels measured in kitchens. Overall ARI prevalence for cooks and children under age 5 making up the exposed group was 54.67% with odds ratio (OR of 5.5; 95% CI 3.6 to 8.5 when compared with unexposed men and non-regular women cooks. Results of this study suggest an association between respiratory diseases and exposure to domestic biomass fuel smoke, but further studies with improved design are needed to confirm the association.

  16. Exergy analysis and optimization of a biomass gasification, solid oxide fuel cell and micro gas turbine hybrid system

    DEFF Research Database (Denmark)

    Bang-Møller, Christian; Rokni, Masoud; Elmegaard, Brian

    2011-01-01

    A hybrid plant producing combined heat and power (CHP) from biomass by use of a two-stage gasification concept, solid oxide fuel cells (SOFC) and a micro gas turbine was considered for optimization. The hybrid plant represents a sustainable and efficient alternative to conventional decentralized...... and exergy analyses were applied. Focus in this optimization study was heat management, and the optimization efforts resulted in a substantial gain of approximately 6% in the electrical efficiency of the plant. The optimized hybrid plant produced approximately 290 kWe at an electrical efficiency of 58...

  17. Recent standardisation work in Sweden related to measurement of biomass fuel quality

    Energy Technology Data Exchange (ETDEWEB)

    Maansson, Margret [Swedish National Testing and Research Inst., Boraas (Sweden)

    1998-06-01

    Work on Swedish standards for peat and biofuels started close to fifteen years ago. The same technical committee that has the responsibility for peat and solid biofuels is also handling the standardisation work on solid mineral fuels. Its counterpart within the ISO is TC 27 Solid mineral fuels. A number of the Swedish analysis standards are structured such that they define methods for all of the solid fuels in the same standard, with specific requirements for the type of fuel if necessary. By now, twenty Swedish biomass standards have been prepared and adopted, half of them already revised at least once. There are dedicated biofuel standards for terminology, sampling and sample preparation and for determination of parameters such as moisture, ash, size distribution, bulk density and mechanical strength. Solid fuels standards that include biomass and peat in their range of application exist for the determination of volatile matter, sulfur chlorine and calorific value. Solid fuel ash methods have been specifically developed for the determination of unburned material and sulfur content. At the present time, standard methods are being defined for the determination of total amounts of heavy metals in ash, and also methods for measuring the availability (leaching properties) of certain elements in ash, in particular ash from combustion of biomass. Ash methods are of interest because of the focus on the possibilities of returning biomass-origin ash to forest soil as a fertilizer and also to prevent depletion of trace elements caused by the increase in the utilisation of the forest growth

  18. Influence of diligent disintegration on anaerobic biomass and performance of microbial fuel cell.

    Science.gov (United States)

    Divyalakshmi, Palanisamy; Murugan, Devaraj; Rai, Chockalingam Lajapathi

    2017-12-01

    To enhance the performance of microbial fuel cells (MFC) by increasing the surface area of cathode and diligent mechanical disintegration of anaerobic biomass. Tannery effluent and anaerobic biomass were used. The increase in surface area of the cathode resulted in 78% COD removal, with the potential, current density, power density and coulombic efficiency of 675 mV, 147 mA m -2 , 33 mW m -2 and 3.5%, respectively. The work coupled with increased surface area of the cathode with diligent mechanical disintegration of the biomass, led to a further increase in COD removal of 82% with the potential, current density, power density and coulombic efficiency of 748 mV, 229 mA m -2 , 78 mW m -2 and 6% respectively. Mechanical disintegration of the biomass along with increased surface area of cathode enhances power generation in vertical MFC reactors using tannery effluent as fuel.

  19. Study of the equilibrium of air-blown gasification of biomass to coal evolution fuels

    International Nuclear Information System (INIS)

    Biagini, Enrico

    2016-01-01

    Highlights: • Equilibrium model validated for coals, torrefied/green biomasses, in different gasifiers. • Maps of syngas composition, LHV and CGE for ER = 0–0.6, T = 500–2000 K, EBP = 0.004–0.158. • Effect of unconverted carbon, fuel moisture and overoxidation quantified. • Parameters for the maximum efficiency determined as functions of EBP. • EBP proven to be a good parameter for the quantitative comparison of different fuels. - Abstract: A non-stoichiometric equilibrium model based on the minimization of the Gibbs free energy was used to study the isothermal and adiabatic air-blown gasification of solid fuels on a carbonization curve from fossil (hard/brown coals, peat) to renewable (green biomasses and cellulose) fuels, including torrefied biofuels. The maps of syngas composition, heating value and process efficiency were provided as functions of equivalent ratio (oxygen-to-fuel ratio) in the range 0–0.6, temperature in 500–2000 K, and a fuel parameter, which allowed different cases to be quantitatively compared. The effect of fuel moisture, unconverted carbon and conditions to limit the tar formation was also studied. Cold gas efficiency >0.75 can be achieved for coals at high temperature, using entrained beds (which give low unconverted carbon), and improved by moisture/added steam. The bigger efficiency of green biomasses is only potential, as the practical limits (high temperature required to limit tar formation, moisture content and unconverted carbon in small gasifiers) strongly reduce the gasification performance. Torrefied biomasses (and plastics having an intermediate fuel parameter between coals and green biomasses) can attain high efficiency also in real conditions. The results shown in this work can be useful to evaluate the most promising feedstock (depending on its composition and possible pre-treatment/upgrading), define the operating conditions for maximizing the syngas heating value or the global efficiency, assess the

  20. Converting Biomass and Waste Plastic to Solid Fuel Briquettes

    Directory of Open Access Journals (Sweden)

    F. Zannikos

    2013-01-01

    Full Text Available This work examines the production of briquettes for household use from biomass in combination with plastic materials from different sources. Additionally, the combustion characteristics of the briquettes in a common open fireplace were studied. It is clear that the geometry of the briquettes has no influence on the smoke emissions. When the briquettes have a small amount of polyethylene terephthalate (PET, the behavior in the combustion is steadier because of the increase of oxygen supply. The smoke levels are between the 3rd and 4th grades of the smoke number scale. Measuring the carbon monoxide emission, it was observed that the burning of the plastic in the mixture with biomass increases the carbon monoxide emissions from 10% to 30% as compared to carbon monoxide emission from sawdust biomass emissions which was used as a reference.

  1. Investment appraisal for small CHP technology in biomass-fuel power plant

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-07-01

    The paper is essentially an investment appraisal for small CHP (combined heat and power) technology in biomass-fuel power plant and discusses and presents data on the combustion/steam cycle technologies to demonstrate the economic viability of CHP projects using established market costs for technology and employing energy crops as biomass fuel. The data is based on the UK, where electricity prices are low, but the overseas market (where prices are higher and there is potential for UK exports) is also discussed. The report aims to synthesise up-to-date technical and economic information on biomass-fuel CHP projects of small scale and focuses on technical and financial information on equipment, capital, construction and operating costs, and revenue streams.

  2. Biomass fuel use by the rural households in Chittagong region, Bangladesh

    Energy Technology Data Exchange (ETDEWEB)

    Danesh Miah; Romel Ahmed; Mohammad Belal Uddin [University of Chittagong (Bulgaria). Institute of Forestry and Environmental Sciences

    2003-05-01

    An exploratory survey was carried out to assess biomass fuel use by the rural households in the Chittagong region, Bangladesh. A multistage random sampling technique was adopted to perform the study. Based on the monthly income, respondents were categorized into rich, medium and poor and a total of 45 homesteads, 15 from each category were selected randomly for the study. The study revealed that stems, branches, leaves of trees and agricultural residues were the biomass fuel used by the respondents. Market, homestead, agricultural field, secondary forests/plantation were the sources of biomass fuel identified. Male and female were identified as the major collectors of fuelwood from the nearby forests/plantations and homesteads, respectively. Six fuelwood species were identified as the most preferred in the study area. The study identified the rainy season as the woodfuel shortage period spanning between May and August. (author)

  3. Direct power generation from waste coffee grounds in a biomass fuel cell

    Science.gov (United States)

    Jang, Hansaem; Ocon, Joey D.; Lee, Seunghwa; Lee, Jae Kwang; Lee, Jaeyoung

    2015-11-01

    We demonstrate the possibility of direct power generation from waste coffee grounds (WCG) via high-temperature carbon fuel cell technology. At 900 °C, the WCG-powered fuel cell exhibits a maximum power density that is twice than carbon black. Our results suggest that the heteroatoms and hydrogen contained in WCG are crucial in providing good cell performance due to its in-situ gasification, without any need for pre-reforming. As a first report on the use of coffee as a carbon-neutral fuel, this study shows the potential of waste biomass (e.g. WCG) in sustainable electricity generation in fuel cells.

  4. Lung function impairment in women exposed to biomass fuels during cooking compared to cleaner fuels in Uttar Pradesh, India.

    Science.gov (United States)

    Bihari, Vipin; Iqbal, S M; Srivastava, L P; Kesavachandran, C; Siddique, M J A

    2013-11-01

    A national survey has shown that approximately 75-80% use of fire wood and chips, 10% of dung cake rural women in Uttar Pradesh, India. Considering the respiratory health risk of biomass fuel exposure to women, a cross sectional study was conducted to elucidate the relationship between cooking smoke and lung function impairments. The present study showed significant decline in air flow limitation based on reduced PEFR (3.69 | sec(-1)) and FEV1 (1.34 | sec(-1)) in women cooking with biomass fuels compared to PEFR (4.26 | sec(-1)) and FEV1 (1.73 | sec(-1)) in women cooking with cleaner fuels. The noxious gases and particles generated from biomass fuels during cooking reported in earlier studies may be the reason for the slight decline in airway status PEFR (3.69 | sec(-1)) and lung volumes FEV1 (1.34 | sec(-1)). The higher mean bio-fuels exposure index (52.5 hr-yrs) can attribute to reduced lung function in rural women.

  5. Establishing fuel specifications of non-wood biomass crops

    Energy Technology Data Exchange (ETDEWEB)

    Christian, D.G.; Riche, A.B.

    1999-07-01

    Six grasses were selected for evaluation as biomass energy crops. The species were planted at the same site in the same year so that differences due to soil quality and climate could be eliminated from the comparison. The species planted were Miscanthus, switchgrass, Spartina grass, reed canary-grass and rye. All species except rye are rhizomatous perennials. Rye is an annual. (author)

  6. Upgrading biomass pyrolysis bio-oil to renewable fuels.

    Science.gov (United States)

    2015-01-01

    Fast pyrolysis is a process that can convert woody biomass to a crude bio-oil (pyrolysis oil). However, some of these compounds : contribute to bio-oil shelf life instability and difficulty in refining. Catalytic hydrodeoxygenation (HDO) of the bio-o...

  7. Fuel pellets from biomass - Processing, bonding, raw materials

    Energy Technology Data Exchange (ETDEWEB)

    Stelte, W.

    2011-12-15

    The present study investigates several important aspects of biomass pelletization. Seven individual studies have been conducted and linked together, in order to push forward the research frontier of biomass pelletization processes. The first study was to investigate influence of the different processing parameters on the pressure built up in the press channel of a pellet mill. It showed that the major factor was the press channel length as well as temperature, moisture content, particle size and extractive content. Furthermore, extractive migration to the pellet surface at an elevated temperature played an important role. The second study presented a method of how key processing parameters can be estimated, based on a pellet model and a small number of fast and simple laboratory trials using a single pellet press. The third study investigated the bonding mechanisms within a biomass pellet, which indicate that different mechanisms are involved depending on biomass type and pelletizing conditions. Interpenetration of polymer chains and close intermolecular distance resulting in better secondary bonding were assumed to be the key factors for high mechanical properties of the formed pellets. The outcome of this study resulted in study four and five investigating the role of lignin glass transition for biomass pelletization. It was demonstrated that the softening temperature of lignin was dependent on species and moisture content. In typical processing conditions and at 8% (wt) moisture content, transitions were identified to be at approximately 53-63 deg. C for wheat straw and about 91 deg. C for spruce lignin. Furthermore, the effects of wheat straw extractives on the pelletizing properties and pellet stability were investigated. The sixth and seventh study applied the developed methodology to test the pelletizing properties of thermally pre-treated (torrefied) biomass from spruce and wheat straw. The results indicated that high torrefaction temperatures above 275 deg

  8. Sustainable Transportation Fuels from Natural Gas (H{sub 2}), Coal and Biomass

    Energy Technology Data Exchange (ETDEWEB)

    Huffman, Gerald

    2012-12-31

    This research program is focused primarily on the conversion of coal, natural gas (i.e., methane), and biomass to liquid fuels by Fischer-Tropsch synthesis (FTS), with minimum production of carbon dioxide. A complementary topic also under investigation is the development of novel processes for the production of hydrogen with very low to zero production of CO{sub 2}. This is in response to the nation's urgent need for a secure and environmentally friendly domestic source of liquid fuels. The carbon neutrality of biomass is beneficial in meeting this goal. Several additional novel approaches to limiting carbon dioxide emissions are also being explored.

  9. Techno-economic analysis of biomass to fuel conversion via the MixAlco process.

    Science.gov (United States)

    Pham, Viet; Holtzapple, Mark; El-Halwagi, Mahmoud

    2010-11-01

    MixAlco is a robust process that converts biomass to fuels and chemicals. A key feature of the MixAlco process is the fermentation, which employs a mixed culture of acid-forming microorganisms to convert biomass components (carbohydrates, proteins, and fats) to carboxylate salts. Subsequently, these intermediate salts are chemically converted to hydrocarbon fuels (gasoline, jet fuel, and diesel). This work focuses on process synthesis, simulation, integration, and cost estimation of the MixAlco process. For the base-case capacity of 40 dry tonne feedstock per hour, the total capital investment is US $5.54/annual gallon of hydrocarbon fuels (US $3.79/annual gallon of ethanol equivalent), and the minimum selling price [with 10% return on investment (ROI), internal hydrogen production, and US $60/tonne biomass] is US $2.56/gal hydrocarbon, which is equivalent to US $1.75/gal ethanol. If plant capacity is increased to 400 tph, the minimum selling price of biomass-derived hydrocarbon fuels is US $1.76/gal hydrocarbon (US $1.20/gal ethanol equivalent), which can compete without subsidies with petroleum-derived hydrocarbons when crude oil sells for about US $65/bbl. At 40 tph, using the average tipping fee for municipal solid waste (US $45/dry tonne) and current price of external hydrogen (US $1/kg), the minimum selling price is only US $1.24/gal hydrocarbon (US $0.85/gal ethanol equivalent).

  10. Thermal use of challenging biomass fuels; Thermische Nutzung von anspruchsvollen Biomassebrennstoffen. Versuche Herbst 2006

    Energy Technology Data Exchange (ETDEWEB)

    Buehler, R. [Umwelt und Energie, Maschwanden (Switzerland); Hersener, J.-L. [Ingenieurbuero Hersener, Wiesendangen (Switzerland); Jenni, A. [Ardens GmbH, Liestal (Switzerland); Klippel, N. [Verenum, Zuerich (Switzerland)

    2007-10-15

    This final report for the Swiss Federal Office of Energy (SFOE) reports on experiments made in autumn 2006 on the thermal use of biomass fuels such as agricultural wastes. As a continuation of the tests performed in 2005, further tests were planned for 2006. The authors quote that for various reasons, only part of the planned test program could be carried out. Tests made with the fuel mixtures sedge and chipped wood as well as horse manure, sedge and chipped wood are reported on. The tests showed that, under optimal conditions, these fuel mixtures can be used as biomass fuel, leading to low emissions. Stable combustion conditions were, however, very difficult to achieve. Details on the tests performed and their results are presented and knowledge gained is discussed.

  11. Refuse recovered biomass fuel from municipal solid waste. A life cycle assessment

    International Nuclear Information System (INIS)

    Ripa, M.; Fiorentino, G.; Giani, H.; Clausen, A.; Ulgiati, S.

    2017-01-01

    Highlights: • An innovative waste treatment process is proposed and evaluated by means of LCA. • The MARSS process produces a biomass fuel with a marketable quality for CHP plants. • The recovery of energy and metals generates significant environmental benefits. • Valuable resources can be recovered from waste and be feedback to the urban systems. - Abstract: Waste disposal is a controversial issue in many European countries: concerns about potential health effects and land value loss as well as the fulfillment of the European Landfill Directive and Waste Framework Directive have significantly changed the way waste should be managed. An appropriate management of municipal solid waste (MSW) may allow a significant enhancement of efficiency in resources use, by recovering both energy and materials from waste, otherwise landfilled, thus replacing fossil fuels and virgin materials with renewable sources. Separation and recovery of the biodegradable fraction of municipal solid waste is encouraged as a mean to produce bioenergy. Therefore, if not source segregated, innovative waste refining technologies may provide potential solutions for separation of organic fraction and improved energy and materials recovery. This paper presents a comprehensive system study of a recently developed technology aimed to improve the MSW management in order to decrease the demand for new landfill space and, at the same time, contribute to the urban energy needs. As part of a wider Life Plus Project entitled MARSS (Material Advanced Recovery Sustainable Systems), funded by European Community in 2012, the environmental assessment of an innovative and enhanced mechanical and biological treatment (MBT) demo plant installed in Mertesdorf (Germany) was performed by means of the SimaPro 8.0.5 LCA software, utilizing ReCiPe (H) Midpoint method for the impact assessment. The plant under study is designed to concentrate the biodegradable part of MSW in the <40 mm fraction, through a series

  12. Association between the use of biomass fuels on respiratory health of workers in food catering enterprises in Nairobi Kenya.

    Science.gov (United States)

    Keraka, Margaret; Ochieng, Carolyne; Engelbrecht, Jacobus; Hongoro, Charles

    2013-01-01

    Indoor air pollution from biomass fuel use has been found to be responsible for more than 1.6 million annual deaths and 2.7% of the global burden of disease. This makes it the second biggest environmental contributor to ill health, behind unsafe water and sanitation. The main objective of this study was to investigate if there was any association between use of bio-fuels in food catering enterprises and respiratory health of the workers. A cross-sectional design was employed, and data collected using Qualitative and quantitative techniques. The study found significantly higher prevalence of respiratory health outcomes among respondents in enterprises using biomass fuels compared to those using processed fuels. Biomass fuels are thus a major public health threat to workers in this sub-sector, and urgent intervention is required. The study recommends a switch from biomass fuels to processed fuels to protect the health of the workers.

  13. Household fuels, low birth weight, and neonatal death in India: the separate impacts of biomass, kerosene, and coal.

    Science.gov (United States)

    Epstein, M B; Bates, M N; Arora, N K; Balakrishnan, K; Jack, D W; Smith, K R

    2013-08-01

    We examined the impact of maternal use of different household cooking fuels in India on low birth weight (LBWfuels for cooking - biomass, coal, and kerosene - using low-pollution fuels (gas and biogas) as the comparison "control" group. Taking socioeconomic and child-specific factors into account, we employed logistic regression to examine the impact of fuel use on fetal and infant health. The results indicate that household use of high-pollution fuels is significantly associated with increased odds of LBW and neonatal death. Compared to households using cleaner fuels (in which the mean birth weight is 2901g), the primary use of coal, kerosene, and biomass fuels is associated with significant decreases in mean birth weight (of -110g for coal, -107g for kerosene, and -78g for biomass). Kerosene and biomass fuel use are also associated with increased risk of LBW (pfuels. Copyright © 2012 Elsevier GmbH. All rights reserved.

  14. Canola Oil Fuel Cell Demonstration: Volume 3 - Technical, Commercialization, and Application Issues Associated with Harvested Biomass

    Science.gov (United States)

    2006-08-17

    series of steam- heated drum or stack-type cookers . Cooking serves to thermally rup- ture oil cells that have survived flaking; to reduce oil viscosity...Credit (Federal) The REPC provides a corporate tax credit of 1.5 cents/kWh, adjusted an- nually for inflation, for: solar thermal electric...such as solar energy, wind energy, geothermal energy, conversion of biomass, fuel cells that do not require hydrocarbon fuel, small hydroelectric

  15. An atlas of thermal data for biomass and other fuels

    Energy Technology Data Exchange (ETDEWEB)

    Gaur, S.; Reed, T.B. [Colorado School of Mines, Golden, CO (United States)

    1995-06-01

    Biomass is recognized as a major source of renewable energy. In order to convert biomass energy to more useful forms, it is necessary to have accurate scientific data on the thermal properties of biomass. This Atlas has been written to supply a uniform source of that information. In the last few decades Thermal analysis (TA) tools such as thermogravimetry, differential thermal analysis, thermo mechanical analysis, etc. have become more important. The data obtained from these techniques can provide useful information in terms of reaction mechanism, kinetic parameters, thermal stability, phase transformation, heat of reaction, etc. for gas-solid and gas-liquid systems. Unfortunately, there are no ASTM standards set for the collection of these types of data using TA techniques and therefore, different investigators use different conditions which suit their requirements for measuring this thermal data. As a result, the information obtained from different laboratories is not comparable. This Atlas provides the ability to compare new laboratory results with a wide variety of related data available in the literature and helps ensure consistency in using these data.

  16. Long-term effects of fuel treatments on aboveground biomass accumulation in ponderosa pine forests of the northern Rocky Mountains

    Science.gov (United States)

    Kate A. Clyatt; Christopher R. Keyes; Sharon M. Hood

    2017-01-01

    Fuel treatments in ponderosa pine forests of the northern Rocky Mountains are commonly used to modify fire behavior, but it is unclear how different fuel treatments impact the subsequent production and distribution of aboveground biomass, especially in the long term. This research evaluated aboveground biomass responses 23 years after treatment in two silvicultural...

  17. Liquid fuels production from biomass. Progress report No. 5, July 1-September 30, 1978

    Energy Technology Data Exchange (ETDEWEB)

    Sanderson, J.E.; Wise, D.L.

    1978-01-01

    The current program to convert biomass into liquid hydrocarbon fuels is an extension of the previous program to ferment marine algae to acetic acid. In that study, it was found that marine algae could be converted to higher aliphatic organic acids and that these acids could be readily removed from the fermentation both by membrane or liquid-liquid extraction. It was then proposed to convert these higher organic acids to aliphatic hydrocarbons via Kolbe Electrolysis, which may be used as a diesel fuel. The specific goals for the current program are: (1) Establish conditions under which substrates other than marine algae may be converted in good yield to organic acids. The primary task in this regard is methane suppression. (2) Modify the current 300 liter fixed packed bed batch fermenter to operate in a continuous mode. (3) Change from membrane extraction of organic acids to liquid-liquid extraction. (4) Optimize the energy balance of the electrolytic oxidation process. The primary task in this regard is to reduce the working potential required for the electrolysis while maintaining an adequate current density. (5) Scale the entire process up to match the output of the 300 liter fermenter. The accomplishments in this program are on schedule. Substantial progress has been made on the problem of methane suppression through the use of sulfide addition and the identification of bromoethane-sulfonic acid as a specific inhibitor of methanogenesis. A conceptual design of a continuously fed fixed packed bed fermenter is presented. Experimental results show that the electrolysis of organic acids produced by fermentation to liquid hydrocarbon fuels already have a favorable energy balance of 6/1 based on the applied potential and over 10/1 based on the working potential.

  18. Biomass conversion to hydrocarbon fuels using the MixAlco™ process at a pilot-plant scale

    International Nuclear Information System (INIS)

    Taco Vasquez, Sebastian; Dunkleman, John; Chaudhuri, Swades K.; Bond, Austin; Holtzapple, Mark T.

    2014-01-01

    Texas A and M University has built a MixAlco™ pilot plant that converts biomass to hydrocarbons (i.e., jet fuel, gasoline) using the following steps: fermentation, descumming, dewatering, thermal ketonization, distillation, hydrogenation, and oligomerization. This study describes the pilot plant and reports results from an 11-month production campaign. The focus was to produce sufficient jet fuel to be tested by the U.S. military. Because the scale was relatively small, energy-saving features were not included in the pilot plant. Further, the equipment was operated in a manner to maximize productivity even if yields were low. During the production campaign, a total of 6.015 Mg of shredded paper and 120 kg of chicken manure (dry basis) were fermented to produce 126.5 m 3 of fermentation broth with an average concentration of 12.5 kg m −3 . A total of 1582 kg of carboxylate salts were converted to 587 L of raw ketones, which were distilled and hydrogenated to 470 L of mixed alcohols ranging from C3 to C12. These alcohols, plus 300 L of alcohols made by an industrial partner (Terrabon, Inc.) were shipped to an independent contractor (General Electric) and transformed to jet fuel (∼100 L) and gasoline (∼100 L) byproduct. - Highlights: • We produce hydrocarbons from paper and chicken manure in a pilot-scale production using the MixAlco™ process. • About 100 L of jet fuel were produced for military testing. • High production rates and good product quality were preferred rather than high yields or energy efficiency. • The MixAlco™ process converted successfully lignocellulosic biomass to hydrocarbons and viable for commercial-scale production

  19. Torrefaction study for energy upgrading on Indonesian biomass as low emission solid fuel

    Science.gov (United States)

    Alamsyah, R.; Siregar, N. C.; Hasanah, F.

    2017-05-01

    Torrefaction is a pyrolysis process with low heating rate and temperature lower than 300°C in an inert condition which transforms biomass into a low emission solid fuel with relatively high energy. Through the torrefaction process biomass can be altered so that the end product is easy to grind and simple in the supply chain. The research was aimed at designing torrefaction reactor and upgrading energy content of some Indonesian biomass. The biomass used consist of empty fruit bunches of oil palm (EFB), cassava peel solid waste, and cocopeat (waste of coconut fiber). These biomass were formed into briquette and pellet form and were torrified with 300°C temperature during 1.5 hours without air. The results of terrified biomass and non-torrefied biomass were compared after burning on the stove in term of energy content and air emission quality. The result shows that energy content of biomass have increased by 1.1 up to 1.36 times. Meanwhile emission air resulted from its combustion was met with Indonesian emission regulation.

  20. An integrated process for the extraction of fuel and chemicals from marine macroalgal biomass

    Science.gov (United States)

    Trivedi, Nitin; Baghel, Ravi S.; Bothwell, John; Gupta, Vishal; Reddy, C. R. K.; Lali, Arvind M.; Jha, Bhavanath

    2016-07-01

    We describe an integrated process that can be applied to biomass of the green seaweed, Ulva fasciata, to allow the sequential recovery of four economically important fractions; mineral rich liquid extract (MRLE), lipid, ulvan, and cellulose. The main benefits of our process are: a) its simplicity and b) the consistent yields obtained from the residual biomass after each successive extraction step. For example, dry Ulva biomass yields ~26% of its starting mass as MRLE, ~3% as lipid, ~25% as ulvan, and ~11% as cellulose, with the enzymatic hydrolysis and fermentation of the final cellulose fraction under optimized conditions producing ethanol at a competitive 0.45 g/g reducing sugar. These yields are comparable to those obtained by direct processing of the individual components from primary biomass. We propose that this integration of ethanol production and chemical feedstock recovery from macroalgal biomass could substantially enhance the sustainability of marine biomass use.

  1. A light hydrocarbon fuel processor producing high-purity hydrogen

    Science.gov (United States)

    Löffler, Daniel G.; Taylor, Kyle; Mason, Dylan

    thermal efficiency is better than 67% operating at full load. This fuel processor has been integrated with a 5-kW fuel cell producing electricity and hot water.

  2. Electricity and biomass production in a bacteria-Chlorella based microbial fuel cell treating wastewater

    Science.gov (United States)

    Commault, Audrey S.; Laczka, Olivier; Siboni, Nachshon; Tamburic, Bojan; Crosswell, Joseph R.; Seymour, Justin R.; Ralph, Peter J.

    2017-07-01

    The chlorophyte microalga Chlorella vulgaris has been exploited within bioindustrial settings to treat wastewater and produce oxygen at the cathode of microbial fuel cells (MFCs), thereby accumulating algal biomass and producing electricity. We aimed to couple these capacities by growing C. vulgaris at the cathode of MFCs in wastewater previously treated by anodic bacteria. The bioelectrochemical performance of the MFCs was investigated with different catholytes including phosphate buffer and anode effluent, either in the presence or absence of C. vulgaris. The power output fluctuated diurnally in the presence of the alga. The maximum power when C. vulgaris was present reached 34.2 ± 10.0 mW m-2, double that observed without the alga (15.6 ± 9.7 mW m-2), with a relaxation of 0.19 gL-1 d-1 chemical oxygen demand and 5 mg L-1 d-1 ammonium also removed. The microbial community associated with the algal biofilm included nitrogen-fixing (Rhizobiaceae), denitrifying (Pseudomonas stutzeri and Thauera sp., from Pseudomonadales and Rhodocyclales orders, respectively), and nitrate-reducing bacteria (Rheinheimera sp. from the Alteromonadales), all of which likely contributed to nitrogen cycling processes at the cathode. This paper highlights the importance of coupling microbial community screening to electrochemical and chemical analyses to better understand the processes involved in photo-cathode MFCs.

  3. Preference and consumption pattern of biomass fuel in some disregarded villages of Bangladesh

    Energy Technology Data Exchange (ETDEWEB)

    Jashimuddin, M.; Masum, K.M.; Salam, M.A. [Institute of Forestry and Environmental Sciences, Chittagong University, Chittagong 4331 (Bangladesh)

    2006-05-15

    Consumer's preference and consumption pattern of biomass fuel, fuel types and energy use category has been studied in the disregarded villages of Bangladesh. The study was conducted both in the inland and island areas. Biomass energy in the study area was used in domestic cooking, tea stalls, brickfields, bakeries, paddy parboiling and pottery. Assessment of consumption in domestic cooking was done by means of multistage random sampling and that in the tea stalls, brickfields, bakeries, paddy parboiling and pottery by means of complete enumeration of the sampling unit. Based on the homestead size respondents were categorized into small, medium and large and a total of 60 homesteads (30 from inland and another 30 from island areas), 20 from each category were selected randomly for the study. The study revealed that natural gas was quite absent and stems, branches and twigs, leaves of trees, agricultural residues, shell and coir of coconut, saw dust, brush wood, rhizomes of bamboo, and cowdung were the biomass fuel used by the respondent. Nine fuelwood species were identified as the most preferred in the study area. Consumption pattern was mostly traditional. Each year preceding the rainy season cyclonic action damages a large quantity of biomass energy sources. Though at the initial stage of rainy season (April-May) there remain a more or less good collection of fuelwood to the user as the byproduct of cyclones and storms, the last part of the rainy season (July-August) was identified as the fuel shortage period. (author)

  4. Physical characterization of biomass fuels prepared for suspension firing in utility boilers for CFD modelling

    DEFF Research Database (Denmark)

    Rosendahl, Lasse; Yin, Chungen; Kær, Søren Knudsen

    2007-01-01

    shapes. The sample is subdivided by straw type, and coherent size, type and mass distribution parameters are reported for the entire sample. This type of data is necessary in order to use CFD reliably as a design and retrofit tool for co-firing biomass with fossil fuels, as the combustion processes...

  5. A strategic assessment of forest biomass and fuel reduction treatments in Western States

    Science.gov (United States)

    USDA Forest Service; Bob Rummer; Jeff Prestemon; Dennis May; Pat Miles; John Vissage; Ron McRoberts; Greg Liknes; Wayne D. Shepperd; Dennis Ferguson; William Elliot; Sue Miller; Steve Reutebuch; Jamie Barbour; Jeremy Fried; Bryce Stokes; Edward Bilek; Ken Skog

    2005-01-01

    This assessment characterizes, at a regional scale, forest biomass that can potentially be removed to implement the fuel reduction and ecosystem restoration objectives of the National Fire Plan for the Western United States. The assessment area covers forests on both public and private ownerships in the region and describes all standing tree volume including stems,...

  6. Woody and non-woody biomass utilisation for fuel and implications ...

    African Journals Online (AJOL)

    Plant biomass is a major source of energy for households in eastern Africa. Unfortunately, the heavy reliance on this form of energy is a threat to forest ecosystems and a recipe for accelerated land resource degradation. Due to the increasing scarcity of traditional fuel wood resources, rural communities have shifted to ...

  7. Differential Mutagenicity and Lung Toxicity of Smoldering Versus Flaming Emissions from a Variety of Biomass Fuels

    Science.gov (United States)

    Wildfire smoke properties change with combustion conditions and biomass fuel types. However the specific role of wildfire conditions on the health effects following smoke exposure are uncertain. This study applies a novel combustion and smoke-collection system to examine emission...

  8. Nitrogen compounds in pressurised fluidised bed gasification of biomass and fossil fuels

    NARCIS (Netherlands)

    De Jong, W.

    2005-01-01

    Fossil fuels still dominate the energy supply in modern societies. The resources, however, are depleting. Therefore, other energy sources are to be exploited further within this century. Biomass is one of the practically CO2 neutral, renewable contributors to the future energy production. Nowadays

  9. Association between the use of biomass fuels on respiratory health

    African Journals Online (AJOL)

    abp

    2013-05-06

    May 6, 2013 ... use generates substantial emissions of many health-damaging pollutants, including respirable particulates and carbon monoxide, and results in indoor air pollution exposures often far .... fuels such as liquid petroleum gas and electricity would not be affected due to cost implications. Prevalence of ...

  10. Bioethanol fuel production from rambutan fruit biomass as reducing ...

    African Journals Online (AJOL)

    The depletion of fossil fuels impacts on the increase of petroleum price and has triggered the finding of alternative and renewable energy. Biofuel has attracted the attention of researchers all over the world due to reducing the environmental impacts of elevated carbon monoxide. Abundant of fruits waste can be reused in the ...

  11. Bioethanol fuel production from rambutan fruit biomass as reducing ...

    African Journals Online (AJOL)

    Administrator

    2011-09-05

    Sep 5, 2011 ... The depletion of fossil fuels impacts on the increase of petroleum price and has triggered the finding of alternative and renewable energy. Biofuel has attracted the attention of researchers all over the world due to reducing the environmental impacts of elevated carbon monoxide. Abundant of fruits waste ...

  12. Modeling the emissions of a dual fuel engine coupled with a biomass gasifier-supplementing the Wiebe function.

    Science.gov (United States)

    Vakalis, Stergios; Caligiuri, Carlo; Moustakas, Konstantinos; Malamis, Dimitris; Renzi, Massimiliano; Baratieri, Marco

    2018-03-12

    There is a growing market demand for small-scale biomass gasifiers that is driven by the economic incentives and the legislative framework. Small-scale gasifiers produce a gaseous fuel, commonly referred to as producer gas, with relatively low heating value. Thus, the most common energy conversion systems that are coupled with small-scale gasifiers are internal combustion engines. In order to increase the electrical efficiency, the operators choose dual fuel engines and mix the producer gas with diesel. The Wiebe function has been a valuable tool for assessing the efficiency of dual fuel internal combustion engines. This study introduces a thermodynamic model that works in parallel with the Wiebe function and calculates the emissions of the engines. This "vis-à-vis" approach takes into consideration the actual conditions inside the cylinders-as they are returned by the Wiebe function-and calculates the final thermodynamic equilibrium of the flue gases mixture. This approach aims to enhance the operation of the dual fuel internal combustion engines by identifying the optimal operating conditions and-at the same time-advance pollution control and minimize the environmental impact.

  13. Inhibitors in sorghum biomass during growth and processing into fuel

    Energy Technology Data Exchange (ETDEWEB)

    Waniska, R.D.; Ring, A.S.; Doherty, C.A.; Poe, J.H.; Rooney, L.W.

    1988-01-01

    The presence and inhibitory activity of phenolic compounds in sorghum biomass were determined. Sorghum contains phenolic compounds at all stages of growth, with higher levels in leaves and glumes compared to stalks and caryopses. These phenolic compounds inhibited alpha- and gluco-amylase activity. Storage of sorghum resulted in increased levels of some phenolic acids. Levels of free phenolic compounds in ensiled sorghum leachate were sufficient to inhibit the hydrolysis of carbohydrates. The phenolic compounds from sorghum appeared to be detoxified during anaerobic digestion.

  14. Thermal Plasma Gasification of Biomass for Fuel Gas Production

    Czech Academy of Sciences Publication Activity Database

    Hrabovský, Milan; Hlína, Michal; Konrád, Miloš; Kopecký, Vladimír; Kavka, Tetyana; Chumak, Oleksiy; Mašláni, Alan

    2009-01-01

    Roč. 13, č. 3-4 (2009), s. 299-313 ISSN 1093-3611 R&D Projects: GA ČR GA202/08/1084 Institutional research plan: CEZ:AV0Z20430508 Keywords : Thermal plasma * plasma gasification * syngas * biomass Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 0.333, year: 2009 http://www.begellhouse.com/journals/57d172397126f956,5cbc272245f24168,0ac09d02537962cf.html

  15. Avoided emissions of a fuel-efficient biomass cookstove dwarf embodied emissions

    Directory of Open Access Journals (Sweden)

    D.L. Wilson

    2016-06-01

    Full Text Available Three billion people cook their food on biomass-fueled fires. This practice contributes to the anthropogenic radiative forcing. Fuel-efficient biomass cookstoves have the potential to reduce CO2-equivalent emissions from cooking, however, cookstoves made from modern materials and distributed through energy-intensive supply chains have higher embodied CO2-equivalent than traditional cookstoves. No studies exist examining whether lifetime emissions savings from fuel-efficient biomass cookstoves offset embodied emissions, and if so, by what margin. This paper is a complete life cycle inventory of “The Berkeley–Darfur Stove,” disseminated in Sudan by the non-profit Potential Energy. We estimate the embodied CO2-equivalent in the cookstove associated with materials, manufacturing, transportation, and end-of-life is 17 kg of CO2-equivalent. Assuming a mix of 55% non-renewable biomass and 45% renewable biomass, five years of service, and a conservative 35% reduction in fuel use relative to a three-stone fire, the cookstove will offset 7.5 tonnes of CO2-equivalent. A one-to-one replacement of a three-stone fire with the cookstove will save roughly 440 times more CO2-equivalent than it “costs” to create and distribute. Over its five-year life, we estimate the total use-phase emissions of the cookstove to be 13.5 tonnes CO2-equivalent, and the use-phase accounts for 99.9% of cookstove life cycle emissions. The dominance of use-phase emissions illuminate two important insights: (1 without a rigorous program to monitor use-phase emissions, an accurate estimate of life cycle emissions from biomass cookstoves is not possible, and (2 improving a cookstove's avoided emissions relies almost exclusively on reducing use-phase emissions even if use-phase reductions come at the cost of substantially increased non-use-phase emissions.

  16. NEW SOLID FUELS FROM COAL AND BIOMASS WASTE; FINAL

    International Nuclear Information System (INIS)

    Hamid Farzan

    2001-01-01

    Under DOE sponsorship, McDermott Technology, Inc. (MTI), Babcock and Wilcox Company (B and W), and Minergy Corporation developed and evaluated a sludge derived fuel (SDF) made from sewage sludge. Our approach is to dry and agglomerate the sludge, combine it with a fluxing agent, if necessary, and co-fire the resulting fuel with coal in a cyclone boiler to recover the energy and to vitrify mineral matter into a non-leachable product. This product can then be used in the construction industry. A literature search showed that there is significant variability of the sludge fuel properties from a given wastewater plant (seasonal and/or day-to-day changes) or from different wastewater plants. A large sewage sludge sample (30 tons) from a municipal wastewater treatment facility was collected, dried, pelletized and successfully co-fired with coal in a cyclone-equipped pilot. Several sludge particle size distributions were tested. Finer sludge particle size distributions, similar to the standard B and W size distribution for sub-bituminous coal, showed the best combustion and slagging performance. Up to 74.6% and 78.9% sludge was successfully co-fired with pulverized coal and with natural gas, respectively. An economic evaluation on a 25-MW power plant showed the viability of co-firing the optimum SDF in a power generation application. The return on equity was 22 to 31%, adequate to attract investors and allow a full-scale project to proceed. Additional market research and engineering will be required to verify the economic assumptions. Areas to focus on are: plant detail design and detail capital cost estimates, market research into possible project locations, sludge availability at the proposed project locations, market research into electric energy sales and renewable energy sales opportunities at the proposed project location. As a result of this program, wastes that are currently not being used and considered an environmental problem will be processed into a renewable

  17. NEW SOLID FUELS FROM COAL AND BIOMASS WASTE

    Energy Technology Data Exchange (ETDEWEB)

    Hamid Farzan

    2001-09-24

    Under DOE sponsorship, McDermott Technology, Inc. (MTI), Babcock and Wilcox Company (B and W), and Minergy Corporation developed and evaluated a sludge derived fuel (SDF) made from sewage sludge. Our approach is to dry and agglomerate the sludge, combine it with a fluxing agent, if necessary, and co-fire the resulting fuel with coal in a cyclone boiler to recover the energy and to vitrify mineral matter into a non-leachable product. This product can then be used in the construction industry. A literature search showed that there is significant variability of the sludge fuel properties from a given wastewater plant (seasonal and/or day-to-day changes) or from different wastewater plants. A large sewage sludge sample (30 tons) from a municipal wastewater treatment facility was collected, dried, pelletized and successfully co-fired with coal in a cyclone-equipped pilot. Several sludge particle size distributions were tested. Finer sludge particle size distributions, similar to the standard B and W size distribution for sub-bituminous coal, showed the best combustion and slagging performance. Up to 74.6% and 78.9% sludge was successfully co-fired with pulverized coal and with natural gas, respectively. An economic evaluation on a 25-MW power plant showed the viability of co-firing the optimum SDF in a power generation application. The return on equity was 22 to 31%, adequate to attract investors and allow a full-scale project to proceed. Additional market research and engineering will be required to verify the economic assumptions. Areas to focus on are: plant detail design and detail capital cost estimates, market research into possible project locations, sludge availability at the proposed project locations, market research into electric energy sales and renewable energy sales opportunities at the proposed project location. As a result of this program, wastes that are currently not being used and considered an environmental problem will be processed into a renewable

  18. Biomass Conversion

    Energy Technology Data Exchange (ETDEWEB)

    Decker, Steve [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Brunecky, Roman [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Lin, Chien-Yuan [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Amore, Antonella [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Wei, Hui [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Chen, Xiaowen [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Tucker, Melvin P [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Czernik, Stefan [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Sluiter, Amie D [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Zhang, Min [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Magrini, Kimberly A [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Himmel, Michael E [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Sheehan, John [Formerly NREL; Dayton, David C. [Formerly NREL; Bozell, Joseph J. [Formerly NREL; Adney, William S. [Formerly NREL; Aden, Andy [Formerly NREL; Hames, Bonnie [Formerly NREL; Thomas, Steven R. [Formerly NREL; Bain, Richard L. [Formerly NREL

    2017-08-02

    Biomass constitutes all the plant matter found on our planet, and is produced directly by photosynthesis, the fundamental engine of life on earth. It is the photosynthetic capability of plants to utilize carbon dioxide from the atmosphere that leads to its designation as a 'carbon neutral' fuel, meaning that it does not introduce new carbon into the atmosphere. This article discusses the life cycle assessments of biomass use and the magnitude of energy captured by photosynthesis in the form of biomass on the planet to appraise approaches to tap this energy to meet the ever-growing demand for energy.

  19. Biomass Converting Enzymes as Industrial Biocatalysts for Fuels and Chemicals: Recent Developments

    Directory of Open Access Journals (Sweden)

    Feng Xu

    2012-04-01

    Full Text Available The economic utilization of abundant lignocellulosic biomass as a feedstock for the production of fuel and chemicals would represent a profound shift in industrial carbon utilization, allowing sustainable resources to substitute for, and compete with, petroleum based products. In order to exploit biomass as a source material for production of renewable compounds, it must first be broken down into constituent compounds, such as sugars, that can be more easily converted in chemical and biological processes. Lignocellulose is, unfortunately, a heterogeneous and recalcitrant material which is highly resistant to depolymerization. Many microorganisms have evolved repertoires of enzyme activities which act in tandem to decompose the various components of lignocellulosic biomass. In this review, we discuss recent advances in the understanding of these enzymes, with particular regard to those activities deemed likely to be applicable in commercialized biomass utilization processes.

  20. Process Improvements to Biomass Pretreatment of Fuels and Chemicals

    Energy Technology Data Exchange (ETDEWEB)

    Teymouri, Farzaneh [Michigan Biotechnology Inst., Lansing, MI (United States)

    2015-05-30

    MBI, a 501c(3) company focusing on de-risking and scaling up bio-based technologies, has teamed with Michigan State University and the Idaho National Laboratory to develop and demonstrate process improvements to the ammonia fiber expansion (AFEX) pretreatment process. The logistical hurdles of biomass handling are well known, and the regional depot concept - in which small, distributed bioprocessing operations collect, preprocess, and densify biomass before shipping to a centralized refinery - is a promising alternative to centralized collection. AFEXTM (AFEX is a trademark of MBI) has unique features among pretreatments that would make it desirable as a pretreatment prior to densification at the depot scale. MBI has developed a novel design, using a packed bed reactor for the AFEX process that can be scaled down economically to the depot scale at a lower capital cost as compared to the traditional design (Pandia type reactor). Thus, the purpose of this project was to develop, scale-up, demonstrate, and improve this novel design The key challenges are the recovery of ammonia, consistent and complete pretreatment performance, and the overall throughput of the reactor. In this project an engineering scale packed bed AFEX system with 1-ton per day capacity was installed at MBI’s building. The system has been operational since mid-2013. During that time, MBI has demonstrated the robustness, reliability, and consistency of the process. To date, nearly 500 runs have been performed in the reactors. There have been no incidences of plugging (i.e., inability to remove ammonia from biomass after the treatment), nor has there been any instance of a major ammonia release into the atmosphere. Likewise, the sugar released via enzyme hydrolysis has remained consistent throughout these runs. Our economic model shows a 46% reduction in AFEX capital cost at the 100 ton/day scale compared to the traditional design of AFEX (Pandia type reactor). The key performance factors were

  1. The bio refinery; producing feed and fuel from grain.

    Science.gov (United States)

    Scholey, D V; Burton, E J; Williams, P E V

    2016-04-15

    It is both possible and practicable to produce feed and fuel from grain. Using the value of grain to produce renewable energy for transport, while using the remaining protein content of the grain as a valuable protein source for livestock and for fish, can be seen as a complimentary and optimal use of all the grain constituents. Consideration must be given to maximise the value of the yeast components, as substantial yeast is generated during the fermentation of the grain starch to produce ethanol. Yeast is a nutritionally rich feed ingredient, with potential for use both as feed protein and as a feed supplement with possible immunity and gut health enhancing properties. Bioprocessing, with the consequent economies of scale, is a process whereby the value of grain can be optimised in a way that is traditional, natural and sustainable for primarily producing protein and oil for feed with a co-product ethanol as a renewable fuel. Copyright © 2015 Elsevier Ltd. All rights reserved.

  2. Characteristics of sustainable bio-solid fuel produced from sewage sludge as a conventional fuel substitute

    International Nuclear Information System (INIS)

    Jung, Bongjin; Nam, Wonjun; Lee, Na-Yeon; Kim, Kyung-Hoon

    2010-01-01

    Safely final disposal of sewage sludge which is being increased every year has already become serious problems. As one of the promising technologies to solve this problem, thermal drying method has been attracting wide attention due to energy recovery from sewage sludge. This paper describes several characteristics of sustainable bio-solid fuel, as a conventional fuel substitute, produced from sewage sludge drying and granulation plant having the treatment capacity of 10 ton/ day. This plant has been successfully operated many times and is now designing for scale-up. Average moisture content of twelve kinds of bio-solid fuels produced from the plant normally less than 10 wt% and average shape of them is mainly composed of granular type having a diameter of 2-8 mm for easy handling and transportation to the final market destinations. Average higher heating value, which is one of the important properties to estimate the possibility of available energy, of bio-solid fuels is about 3800 kcal/ kg as dry basis. So they can be utilized to supply energy in the coal power plant and cement kiln etc. as a conventional fuel substitute for a beneficial reuse. Characteristics including proximate analysis, ultimate analysis, contents of heavy metals, wettability etc. of bio-solid fuels have been also analyzed for the environmentally safe re utilization. (author)

  3. Flocculating Zymomonas mobilis is a promising host to be engineered for fuel ethanol production from lignocellulosic biomass.

    Science.gov (United States)

    Zhao, Ning; Bai, Yun; Liu, Chen-Guang; Zhao, Xin-Qing; Xu, Jian-Feng; Bai, Feng-Wu

    2014-03-01

    Whereas Saccharomyces cerevisiae uses the Embden-Meyerhof-Parnas pathway to metabolize glucose, Zymomonas mobilis uses the Entner-Doudoroff (ED) pathway. Employing the ED pathway, 50% less ATP is produced, which could lead to less biomass being accumulated during fermentation and an improved yield of ethanol. Moreover, Z. mobilis cells, which have a high specific surface area, consume glucose faster than S. cerevisiae, which could improve ethanol productivity. We performed ethanol fermentations using these two species under comparable conditions to validate these speculations. Increases of 3.5 and 3.3% in ethanol yield, and 58.1 and 77.8% in ethanol productivity, were observed in ethanol fermentations using Z. mobilis ZM4 in media containing ∼100 and 200 g/L glucose, respectively. Furthermore, ethanol fermentation bythe flocculating Z. mobilis ZM401 was explored. Although no significant difference was observed in ethanol yield and productivity, the flocculation of the bacterial species enabled biomass recovery by cost-effective sedimentation, instead of centrifugation with intensive capital investment and energy consumption. In addition, tolerance to inhibitory byproducts released during biomass pretreatment, particularly acetic acid and vanillin, was improved. These experimental results indicate that Z. mobilis, particularly its flocculating strain, is superior to S. cerevisiae as a host to be engineered for fuel ethanol production from lignocellulosic biomass. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  4. Single-reactor process for producing liquid-phase organic compounds from biomass

    Science.gov (United States)

    Dumesic, James A [Verona, WI; Simonetti, Dante A [Middleton, WI; Kunkes, Edward L [Madison, WI

    2011-12-13

    Disclosed is a method for preparing liquid fuel and chemical intermediates from biomass-derived oxygenated hydrocarbons. The method includes the steps of reacting in a single reactor an aqueous solution of a biomass-derived, water-soluble oxygenated hydrocarbon reactant, in the presence of a catalyst comprising a metal selected from the group consisting of Cr, Mn, Fe, Co, Ni, Cu, Mo, Tc, Ru, Rh, Pd, Ag, W, Re, Os, Ir, Pt, and Au, at a temperature, and a pressure, and for a time sufficient to yield a self-separating, three-phase product stream comprising a vapor phase, an organic phase containing linear and/or cyclic mono-oxygenated hydrocarbons, and an aqueous phase.

  5. Disease burden due to biomass cooking-fuel-related household air pollution among women in India

    Science.gov (United States)

    Sehgal, Meena; Rizwan, Suliankatchi Abdulkader; Krishnan, Anand

    2014-01-01

    Background Household air pollution (HAP) due to biomass cooking fuel use is an important risk factor for a range of diseases, especially among adult women who are primary cooks, in India. About 80% of rural households in India use biomass fuel for cooking. The aim of this study is to estimate the attributable cases (AC) for four major diseases/conditions associated with biomass cooking fuel use among adult Indian women. Methods We used the population attributable fraction (PAF) method to calculate the AC of chronic bronchitis, tuberculosis (TB), cataract, and stillbirths due to exposure to biomass cooking fuel. A number of data sources were accessed to obtain population totals and disease prevalence rates. A meta-analysis was conducted to obtain adjusted pooled odds ratios (ORs) for strength of association. Using this, PAF and AC were calculated using a standard formula. Results were presented as number of AC and 95% confidence intervals (CI). Results The fixed effects pooled OR obtained from the meta-analysis were 2.37 (95% CI: 1.59, 3.54) for chronic bronchitis, 2.33 (1.65, 3.28) for TB, 2.16 (1.42, 3.26) for cataract, and 1.26 (1.12, 1.43) for stillbirths. PAF varied across conditions being maximum (53%) for chronic bronchitis in rural areas and least (1%) for cataract in older age and urban areas. About 2.4 (95% CI: 1.4, 3.1) of 5.6 m cases of chronic bronchitis, 0.3 (0.2, 0.4) of 0.76 m cases of TB, 5.0 (2.8, 6.7) of 51.4 m cases of cataract among adult Indian women and 0.02 (0.01, 0.03) of 0.15 m stillbirths across India are attributable to HAP due to biomass cooking fuel. These estimates should be cautiously interpreted in the light of limitations discussed which relate to exposure assessment, exposure characterization, and age-specific prevalence of disease. Conclusions HAP due to biomass fuel has diverse and major impacts on women’s health in India. Although challenging, incorporating the agenda of universal clean fuel access or cleaner technology within

  6. A fluidized bed furnace fired with biomass waste to supply heat for a spray dryer in a plant producing floortiles

    Energy Technology Data Exchange (ETDEWEB)

    Gulyurtlu, I.; Andre, R.; Mendes, J.; Monteiro, A.; Cabrita, I. [Instituto Nacional de Engenharia e Tecnologia Industrial, Lisboa (Portugal)

    1993-12-31

    This project has been implemented at a factory producing floortiles for domestic use. The project consists of a fluidized bed combustion system burning coal or wood or a mixture of both to produce hot combustion gases to provide heat for spray drying process. The system was designed by INETI for a maximum output of 8 MW thermal energy and all the engineering calculations were carried out to dimension the furnace to provide this amount of heat. Shallow bed concept was used for complete burning of the biomass particles which contained volatiles up to 75% by weight. The sand bed was used as a flame stabilizer for the combustion of volatiles. The combustion of volatiles in the freeboard was mainly controlled by mixing ashes and other impurities. The combustion temperature had to be maintained in the range 700--800{degrees}C to achieve combustion efficiencies of 85% or more. The combustion efficiency (1) did not increase substantially above 90% of excess air although levels of up to 120% were used during combustion and (2) was found to increase through air staging in the order of 20 to 25%, by simply adding 45 to 55% of the air required to the freeboard zone. No SO{sub 2} was observed in flue gases when burning only biomass but there was some NO{sub x} formed and the level of conversion of fuel-N to NO{sub x} was found to be about 25--30%.

  7. Biomass burning fuel consumption rates: a field measurement database

    CSIR Research Space (South Africa)

    Van Leeuwen, TT

    2014-01-01

    Full Text Available are generally not susceptible to fire except during extreme drought periods due to their dense canopy cover keeping humidity high and wind speed low,25 and also because the amount of fuel on the surface is low due to rapid decomposition. However, human... by high temperatures, low humidities, and high offshore Santa Ana winds (Moritz et al., 2010) may lead to large and costly wildfires (Keeley et al., 2009).20 We found 2 studies covering 4 different measurement locations in southwestern US (Table 1, Fig. 1g...

  8. Comparative techno-economic analysis and process design for indirect liquefaction pathways to distillate-range fuels via biomass-derived oxygenated intermediates upgrading: Liquid Transportation Fuel Production via Biomass-derived Oxygenated Intermediates Upgrading

    Energy Technology Data Exchange (ETDEWEB)

    Tan, Eric C. D. [National Renewable Energy Laboratory, Golden CO USA; Snowden-Swan, Lesley J. [Pacific Northwest National Laboratory, Richland WA USA; Talmadge, Michael [National Renewable Energy Laboratory, Golden CO USA; Dutta, Abhijit [National Renewable Energy Laboratory, Golden CO USA; Jones, Susanne [Pacific Northwest National Laboratory, Richland WA USA; Ramasamy, Karthikeyan K. [Pacific Northwest National Laboratory, Richland WA USA; Gray, Michel [Pacific Northwest National Laboratory, Richland WA USA; Dagle, Robert [Pacific Northwest National Laboratory, Richland WA USA; Padmaperuma, Asanga [Pacific Northwest National Laboratory, Richland WA USA; Gerber, Mark [Pacific Northwest National Laboratory, Richland WA USA; Sahir, Asad H. [National Renewable Energy Laboratory, Golden CO USA; Tao, Ling [National Renewable Energy Laboratory, Golden CO USA; Zhang, Yanan [National Renewable Energy Laboratory, Golden CO USA

    2016-09-27

    This paper presents a comparative techno-economic analysis (TEA) of five conversion pathways from biomass to gasoline-, jet-, and diesel-range hydrocarbons via indirect liquefaction with specific focus on pathways utilizing oxygenated intermediates. The four emerging pathways of interest are compared with one conventional pathway (Fischer-Tropsch) for the production of the hydrocarbon blendstocks. The processing steps of the four emerging pathways include: biomass to syngas via indirect gasification, gas cleanup, conversion of syngas to alcohols/oxygenates followed by conversion of alcohols/oxygenates to hydrocarbon blendstocks via dehydration, oligomerization, and hydrogenation. Conversion of biomass-derived syngas to oxygenated intermediates occurs via three different pathways, producing: 1) mixed alcohols over a MoS2 catalyst, 2) mixed oxygenates (a mixture of C2+ oxygenated compounds, predominantly ethanol, acetic acid, acetaldehyde, ethyl acetate) using an Rh-based catalyst, and 3) ethanol from syngas fermentation. This is followed by the conversion of oxygenates/alcohols to fuel-range olefins in two approaches: 1) mixed alcohols/ethanol to 1-butanol rich mixture via Guerbet reaction, followed by alcohol dehydration, oligomerization, and hydrogenation, and 2) mixed oxygenates/ethanol to isobutene rich mixture and followed by oligomerization and hydrogenation. The design features a processing capacity of 2,000 tonnes/day (2,205 short tons) of dry biomass. The minimum fuel selling prices (MFSPs) for the four developing pathways range from $3.40 to $5.04 per gasoline-gallon equivalent (GGE), in 2011 US dollars. Sensitivity studies show that MFSPs can be improved with co-product credits and are comparable to the commercial Fischer-Tropsch benchmark ($3.58/GGE). Overall, this comparative TEA study documents potential economics for the developmental biofuel pathways via mixed oxygenates.

  9. Highly Selective Upgrading of Biomass-Derived Alcohol Mixtures for Jet/Diesel-Fuel Components.

    Science.gov (United States)

    Liu, Qiang; Xu, Guoqiang; Wang, Xicheng; Liu, Xiaoran; Mu, Xindong

    2016-12-20

    In light of the increasing concern about the energy and environmental problems caused by the combustion of petroleum-based fuels (e.g., jet and diesel fuels), the development of new procedures for their sustainable production from renewable biomass-derived platform compounds has attracted tremendous attention recently. Long-chain ketones/alcohols are promising fuel components owing to the fuel properties that closely resemble those of traditional fuels. The focus of this report is the production of long-chain ketones/alcohols by direct upgrading of biomass-derived short-chain alcohol mixtures (e.g., isopropanol-butanol-ethanol mixtures) in pure water. An efficient Pd catalyst system was developed for these highly selective transformations. Long-chain ketones/alcohols (C 8 -C 19 ), which can be used as precursors for renewable jet/diesel fuel, were obtained in good-to-high selectivity (>90 %) by using the developed Pd catalyst. © 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  10. Biomass gasification integrated with a solid oxide fuel cell and Stirling engine

    International Nuclear Information System (INIS)

    Rokni, Masoud

    2014-01-01

    An integrated gasification solid oxide fuel cell (SOFC) and Stirling engine for combined heat and power application is analyzed. The target for electricity production is 120 kW. Woodchips are used as gasification feedstock to produce syngas, which is then used to feed the SOFC stacks for electricity production. Unreacted hydrocarbons remaining after the SOFC are burned in a catalytic burner, and the hot off-gases from the burner are recovered in a Stirling engine for electricity and heat production. Domestic hot water is used as a heat sink for the Stirling engine. A complete balance-of-plant is designed and suggested. Thermodynamic analysis shows that a thermal efficiency of 42.4% based on the lower heating value (LHV) can be achieved if all input parameters are selected conservatively. Different parameter studies are performed to analyze the system behavior under different conditions. The analysis shows that the decreasing number of stacks from a design viewpoint, indicating that plant efficiency decreases but power production remains nearly unchanged. Furthermore, the analysis shows that there is an optimum value for the utilization factor of the SOFC for the suggested plant design with the suggested input parameters. This optimum value is approximately 65%, which is a rather modest value for SOFC. In addition, introducing a methanator increases plant efficiency slightly. If SOFC operating temperature decreases due to new technology then plant efficiency will slightly be increased. Decreasing gasifier temperature, which cannot be controlled, causes the plant efficiency to increase also. - Highlights: • Design of integrated gasification with solid oxide fuel and Stirling engine. • Important plant parameters study. • Plant running on biomass with and without methanator. • Thermodynamics of integrated gasification SOFC-Stirling engine plants

  11. Liquid fuels production from biomass. Progress report No. 8, April 1-June 30, 1979

    Energy Technology Data Exchange (ETDEWEB)

    Sanderson, J.E.; Garcia-Martinez, D.V.; George, G.S.; Dillon, J.J.; Molyneaux, M.S.; Barnard, G.W.; Wise, D.L.

    1979-07-23

    The current program to convert biomass into liquid hydrocarbon fuels is an extension of the previous program to ferment marine algae to acetic acid. In that study, it was found that marine algae could be converted to higher aliphatic organic acids and that these acids could be readily removed from the fermentation both by membrane or liquid-liquid extraction. It was then proposed to convert these higher organic acids to aliphatic hydrocarbons via Kolbe Electrolysis, which may be used as a diesel fuel. The accompishments in this program for the first year of work are as follows: a coenzyme M anologue, 2-bromoethanesulfonic acid has been shown to be an effective suppressor of methane in nonsterile anaerobic fermentation of cellulosic substrates; a tapered auger device has been designed and built which has been demonstrated on the bench to be effective for adding substrate and removing residue in a continuous manner from a fixed packed bed fermenter; a solvent extracter system using kerosene as the nonaqueous phase has been constructed and is currently in operation in series with the 300 liter fixed packed bed fermenter; although additional work is required to optimize the electrolysis process the electrolytic oxidation of organic acids produced in the 300 liter fixed packed bed fermenter is operating with a favorable energy balance of 6/1 based on the applied potential; the liquid-liquid extractor system is operating in line with 300 liter fixed packed bed fermentor; the other components of an integrated continuous system, the continuous feed device and the Kolbe electrolysis cell are operating satisfactorily out of line on a scale compatible with the 300 liter fixed packed bed fermentor; and an economic analysis for a 1000 ton per day plant has been performed and has been improved and updated based on additional experimental results.

  12. Cellulosic Biomass Sugars to Advantaged Jet Fuel – Catalytic Conversion of Corn Stover to Energy Dense, Low Freeze Point Paraffins and Naphthenes

    Energy Technology Data Exchange (ETDEWEB)

    Cortright, Randy [Virent, Inc., Madison, WI (United States)

    2015-07-31

    The purpose of this project was to demonstrate the technical and commercial feasibility of producing liquid fuels, particularly jet fuel, from lignocellulosic materials, such as corn stover. This project was led by Virent, Inc. (Virent) which has developed a novel chemical catalytic process (the BioForming® platform) capable of producing “direct replacement” liquid fuels from biomass-derived feedstocks. Virent has shown it is possible to produce an advantaged jet fuel from biomass that meets or exceeds specifications for commercial and military jet fuel through Fuel Readiness Level (FRL) 5, Process Validation. This project leveraged The National Renewable Energy Lab’s (NREL) expertise in converting corn stover to sugars via dilute acid pretreatment and enzymatic hydrolysis. NREL had previously developed this deconstruction technology for the conversion of corn stover to ethanol. In this project, Virent and NREL worked together to condition the NREL generated hydrolysate for use in Virent’s catalytic process through solids removal, contaminant reduction, and concentration steps. The Idaho National Laboratory (INL) was contracted in this project for the procurement, formatting, storage and analysis of corn stover and Northwestern University developed fundamental knowledge of lignin deconstruction that can help improve overall carbon recovery of the combined technologies. Virent conducted fundamental catalytic studies to improve the performance of the catalytic process and NREL provided catalyst characterization support. A technoeconomic analysis (TEA) was conducted at each stage of the project, with results from these analyses used to inform the direction of the project.

  13. Solid oxide fuel cells powered by biomass gasification for high efficiency power generation

    DEFF Research Database (Denmark)

    Gadsbøll, Rasmus Østergaard; Thomsen, Jesper; Bang-Møller, Christian

    2017-01-01

    efficiencies, flexibility and possibly costs of current biomass power generating systems, a power plant concept combining solid oxide fuel cells (SOFC) and gasification is investigated experimentally. The aim of the study is to examine the commercial operation system potential of these two technologies......Increased use of bioenergy is a very cost-effective and flexible measure to limit changes in the climate and the infrastructure. One of the key technologies toward a higher implementation of biomass is thermal gasification, which enables a wide span of downstream applications. In order to improve...

  14. Carbon deposition in an SOFC fueled by tar-laden biomass gas: a thermodynamic analysis

    Science.gov (United States)

    Singh, Devinder; Hernández-Pacheco, Eduardo; Hutton, Phillip N.; Patel, Nikhil; Mann, Michael D.

    This work presents a thermodynamic analysis of the carbon deposition in a solid oxide fuel cell (SOFC) fueled by a biomass gasifier. Integrated biomass-SOFC units offer considerable benefits in terms of efficiency and fewer emissions. SOFC-based power plants can achieve a system efficiency of 70-80% (including heat utilization) as compared to 30-37% for conventional systems. The fuel from the biomass gasifier can contain considerable amounts of tars depending on the type of gasifier used. These tars can lead to the deposition of carbon at the anode side of SOFCs and affect the performance of the fuel cells. This paper thermodynamically studies the risk of carbon deposition due to the tars present in the feed stream and the effect various parameters like current density, steam, and temperature have on carbon deposition. Since tar is a complex mixture of aromatics, it is represented by a mixture of toluene, naphthalene, phenol, and pyrene. A total of 32 species are considered for the thermodynamic analysis, which is done by the Gibbs energy minimization technique. The carbon deposition is shown to decrease with an increase in current density and becomes zero after a critical current density. Steam in the feed stream also decreases the amount of carbon deposition. With the increase in temperature the amount of carbon first decreases and then increases.

  15. GASEOUS EMISSIONS FROM FOSSIL FUELS AND BIOMASS COMBUSTION IN SMALL HEATING APPLIANCES

    Directory of Open Access Journals (Sweden)

    Daniele Dell'Antonia

    2012-06-01

    Full Text Available The importance of emission control has increased sharply due to the increased need of energy from combustion. However, biomass utilization in energy production is not free from problems because of physical and chemical characteristics which are substantially different from conventional energy sources. In this situation, the quantity and quality of emissions as well as used renewable sources as wood or corn grain are often unknown. To assess this problem the paper addresses the objectives to quantify the amount of greenhouse gases during the combustion of corn as compared to the emissions in fossil combustion (natural gas, LPG and diesel boiler. The test was carried out in Friuli Venezia Giulia in 2006-2008 to determine the air pollution (CO, NO, NO2, NOx, SO2 and CO2 from fuel combustion in family boilers with a power between 20-30 kWt. The flue gas emission was measured with a professional semi-continuous multi-gas analyzer, (Vario plus industrial, MRU air Neckarsulm-Obereisesheim. Data showed a lower emission of fossil fuel compared to corn in family boilers in reference to pollutants in the flue gas (NOx, SO2 and CO. In a particular way the biomass combustion makes a higher concentration of carbon monoxide (for an incomplete combustion because there is not a good mixing between fuel and air and nitrogen oxides (in relation at a higher content of nitrogen in herbaceous biomass in comparison to another fuel.

  16. Forest biomass flow for fuel wood, fodder and timber security among tribal communities of Jharkhand.

    Science.gov (United States)

    Islam, M A; Quli, S M S; Rai, R; Ali, Angrej; Gangoo, S A

    2015-01-01

    The study investigated extraction and consumption pattern of fuel wood, fodder and timber and forest biomass flow for fuel wood, fodder and timber security among tribal communities in Bundu block of Ranchi district in Jharkhand (India). The study is based on personal interviews of the selected respondents through structured interview schedule, personal observations and participatory rural appraisal tools i.e. key informant interviews and focus group discussions carried out in the sample villages, using multi-stage random sampling technique. The study revealed that the total extraction of fuel wood from different sources in villages was 2978.40 tons annum(-1), at the rate of 0.68 tons per capita annum(-1), which was mostly consumed in cooking followed by cottage industries, heating, community functions and others. The average fodder requirement per household was around 47.77 kg day(-1) with a total requirement of 14227.34 tons annum(-1). The average timber requirement per household was computed to be 0.346 m3 annum(-1) accounting for a total timber demand of 282.49 m3 annum(-1), which is mostly utilized in housing, followed by agricultural implements, rural furniture, carts and carriages, fencing, cattle shed/ store house and others. Forest biomass is the major source of fuel wood, fodder and timber for the primitive societies of the area contributing 1533.28 tons annum(-1) (51.48%) of the total fuel wood requirement, 6971.55 tons annum(-1) (49.00%) of the total fodder requirement and 136.36 m3 annum(-1) (48.27%) of the total timber requirement. The forest biomass is exposed to enormous pressure for securing the needs by the aboriginal people, posing great threat to biodiversity and environment of the region. Therefore, forest biomass conservation through intervention of alternative avenues is imperative to keep pace with the current development and future challenges in the area.

  17. Speciated Chemical Composition of Biomass Burning Aerosol from Various Fuels during FIREX

    Science.gov (United States)

    Jen, C.; Hatch, L. E.; Kreisberg, N. M.; Selimovic, V.; Yokelson, R. J.; Barsanti, K.; Goldstein, A. H.

    2017-12-01

    Biomass burning is the largest global source of atmospheric primary carbonaceous aerosols and the second largest global source of non-methane organic compounds, including volatile and semi-volatile organic compounds that are now understood to be major contributors to secondary particle formation in the atmosphere. As wildfires in forested regions such as the western United States become larger and more frequent, understanding the chemical composition of biomass burning organic aerosol is needed to better predict their increasing impact on human health, air quality, and climate. This study presents emission profiles of chemically speciated intermediate and semi-volatile organic compounds present in biomass burning aerosol particles ≤1.0 μm. Biomass burning organic aerosol (BBOA) samples from a variety of fuel types and burning conditions were collected during the FIREX campaign at the USDA Fire Lab (Missoula, MT). Fuels were primarily selected from vegetation commonly found in the western United States, such as ponderosa pine, lodgepole pine, ceanothus, and chaparral. Collected BBOA was thermally desorbed from the filters and analyzed using online derivatization and 2-dimensional gas chromatography with an electron impact (70 eV) and vacuum ultra violet light (10.5 eV) high resolution time of flight mass spectrometer for compound identification. Emission profiles for specific compounds (e.g., levoglucosan) and families of compounds (e.g., sugars and methoxyphenols) show distinct variations between different fuel types, with major differences between fresh and partially decomposed fuels. Results also illustrate the variability in chemical species between burns conducted under similar conditions. Furthermore, chemical fingerprints, representing ratios of normalized emissions for key chemical compounds, were measured for specific fuels/conditions and could be used in future field studies to help identify contributions of various vegetation to total BBOA and in

  18. A Supply-Chain Analysis Framework for Assessing Densified Biomass Solid Fuel Utilization Policies in China

    Directory of Open Access Journals (Sweden)

    Wenyan Wang

    2015-07-01

    Full Text Available Densified Biomass Solid Fuel (DBSF is a typical solid form of biomass, using agricultural and forestry residues as raw materials. DBSF utilization is considered to be an alternative to fossil energy, like coal in China, associated with a reduction of environmental pollution. China has abundant biomass resources and is suitable to develop DBSF. Until now, a number of policies aimed at fostering DBSF industry have been proliferated by policy makers in China. However, considering the seasonality and instability of biomass resources, these inefficiencies could trigger future scarcities of biomass feedstocks, baffling the resilience of biomass supply chains. Therefore, this review paper focuses on DBSF policies and strategies in China, based on the supply chain framework. We analyzed the current developing situation of DBSF industry in China and developed a framework for policy instruments based on the supply chain steps, which can be used to identify and assess the deficiencies of current DBSF industry policies, and we proposed some suggestions. These findings may inform policy development and identify synergies at different steps in the supply chain to enhance the development of DBSF industry.

  19. One-step catalytic conversion of biomass-derived carbohydrates to liquid fuels

    Science.gov (United States)

    Sen, Ayusman; Yang, Weiran

    2014-03-18

    The invention relates to a method for manufacture of hydrocarbon fuels and oxygenated hydrocarbon fuels such as alkyl substituted tetrahydrofurans such as 2,5-dimethyltetrahydrofuran, 2-methyltetrahydrofuran, 5-methylfurfural and mixtures thereof. The method generally entails forming a mixture of reactants that includes carbonaceous material, water, a metal catalyst and an acid reacting that mixture in the presence of hydrogen. The reaction is performed at a temperature and for a time sufficient to produce a furan type hydrocarbon fuel. The process may be adapted to provide continuous manufacture of hydrocarbon fuels such as a furan type fuel.

  20. Techno-economic Analysis for the Thermochemical Conversion of Biomass to Liquid Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Zhu, Yunhua; Tjokro Rahardjo, Sandra A.; Valkenburt, Corinne; Snowden-Swan, Lesley J.; Jones, Susanne B.; Machinal, Michelle A.

    2011-06-01

    ). This study is part of an ongoing effort within the Department of Energy to meet the renewable energy goals for liquid transportation fuels. The objective of this report is to present a techno-economic evaluation of the performance and cost of various biomass based thermochemical fuel production. This report also documents the economics that were originally developed for the report entitled “Biofuels in Oregon and Washington: A Business Case Analysis of Opportunities and Challenges” (Stiles et al. 2008). Although the resource assessments were specific to the Pacific Northwest, the production economics presented in this report are not regionally limited. This study uses a consistent technical and economic analysis approach and assumptions to gasification and liquefaction based fuel production technologies. The end fuels studied are methanol, ethanol, DME, SNG, gasoline and diesel.

  1. Fuel biomass and combustion factors associated with fires in savanna ecosystems of South Africa and Zambia

    Science.gov (United States)

    Shea, Ronald W.; Shea, Barbara W.; Kauffman, J. Boone; Ward, Darold E.; Haskins, Craig I.; Scholes, Mary C.

    1996-10-01

    Fires are dominant factors in shaping the structure and composition of vegetation in African savanna ecosystems. Emissions such as CO2, NOx, CH4, and other compounds originating from these fires are suspected to contribute substantially to changes in global biogeochemical processes. Limited quantitative data exist detailing characteristics of biomass, burning conditions, and the postfire environment in African savannas. Fourteen test sites, differentiated by distinct burn frequency histories and land-use patterns, were established and burned during August and September 1992 in savanna parklands of South Africa and savanna woodlands of Zambia. Vegetation physiognomy, available fuel loads, the levels of biomass consumed by fire, environmental conditions, and fire behavior are described. In the South African sites, total aboveground fuel loads ranged from 2218 to 5492 kg ha-1 where fire return intervals were 1-4 years and exceeded 7000 kg ha-1 at a site subjected to 38 years of fire exclusion. However, fireline intensity was only 1419 kW m-1 at the fire exclusion site, while ranging from 480 to 6130 kW m-1 among the frequent fire sites. In Zambia, total aboveground fuel loads ranged from 3164 kg ha-1 in a hydromorphic grassland to 7343 kg ha-1 in a fallow shifting cultivation site. Dormant grass and litter constituted 70-98% of the total fuel load among all sites. Although downed woody debris was a relatively minor fuel component at most sites, it constituted 43-57% of the total fuel load in the fire exclusion and shifting cultivation sites. Fire line intensity ranged between 1734 and 4061 kW m-1 among all Zambian sites. Mean grass consumption generally exceeded 95%, while downed woody debris consumption ranged from 3 to 73% at all sites. In tropical savannas and savanna woodlands of southern Africa, differences in environmental conditions, land- use patterns, and fire regimes influence vegetation characteristics and thus influence fire behavior and biomass

  2. Development and Test of a new Concept for Biomass Producer Gas Engines

    DEFF Research Database (Denmark)

    Ahrenfeldt, Jesper; Foged, Esben Vendelbo; Strand, Rune

    The technical requirements and the economical assessment of converting commercial diesel engine gen-sets into high compression spark ignition operation on biomass producer gas have been investigated. Assessments showed that for a 200 kWe gen-set there would be a financial benefit of approximately....... The engines were operated with two different compression ratios, one with the original compression ratio for natural gas operation 9.5:1, and the second with a compression ratio of 18.5:1 (converted diesel engine). It was shown that high compression ratio SI engine operation was possible when operating...... on this specific biomass producer gas. The results showed an increase in the electrical efficiency from 30% to 34% when the compression ratio was increased....

  3. Exploring the Perspectives of Alternative Fuels Production. Towards alternative fuels with zero, or negative greenhouse gas emissions, considering coal, biomass and carbon capture and storage

    International Nuclear Information System (INIS)

    Eerhart, A.J.J.E.

    2009-05-01

    In this report it is shown that future improvements in the production process of Fischer-Tropsch fuels can reduce costs and produce CO2 neutral gasoline and diesel. Major benefits lie in the improvement of the overall temperature profile of the plant at higher temperatures and carbon capture and storage. Based on literature studies, it was found that future technologies can operate at higher temperatures, and thus a better integration of heating and cooling. It was found that the future model of a CBTL (Coal and Biomass To Liquids) plant can produce liquids at a break-even oil price (BEOP) of 58.60 USD/barrel at 100% coal, with similar greenhouse gas emissions compared to liquids produced by conventional means today. However, once biomass is introduced at a ratio of 33% - 67% biomass, a CBTL plant becomes neutral in terms of GHG emissions. The BEOP for this neutral scenario is 69.60 USD/barrel. Looking at the 100% biomass scenario, the BEOP becomes 82.77 USD/barrel. The greenhouse gas emissions at this point are negative, meaning that more CO2 is captured during the process than is needed to grow biomass. This in effect makes a CBTL plant a carbon sink. By introducing future technologies and improvements, such as membrane technology for CCS (Carbon dioxide Capture and Storage), higher FTS (Fischer-Tropsch Synthesis) catalyst selectivities and an overall better temperature profile, the BEOP for the 100% coal scenario drops from 58.60 to 45.27 USD/barrel. The BEOP for the neutral scenario drops from 69.60 to 57.99 USD/barrel. The BEOP for the 100% biomass scenario drops from 82.77 to 69.07 USD/barrel. For the neutral scenario, the BEOP drops from 69.60 to 57.99 USD/barrel. If one assumes that a BEOP of 60 USD/barrel is economically reasonable, one can calculate the level of a carbon tax, once a carbon tax regime is imposed. For SOTA (state-of-the-art) 100% coal, FS (Future Scenario) 100%, FS 50% coal and FS 33% coal, there is no need for a carbon tax to reach 60 USD

  4. Possibilities of CO and H2 Contents Change in the Syngas Produced by Biomass Gasification

    Directory of Open Access Journals (Sweden)

    Jan JANŠA

    2015-06-01

    Full Text Available Thermal gasification is an advanced technology to convert purposefully grown or waste ligno-cellulosic biomass into calorific gas. Increasing the content of CO and H2 in the product gas is important for the further use of the gas in technologies for power generation. This article describes the process of gasification and specifies parameters that determine the content of CO and H2 in the produced gas.

  5. Design of an extrusion screw and solid fuel produced from coconut shell

    Directory of Open Access Journals (Sweden)

    Madhiyanon, T

    2006-03-01

    Full Text Available The objectives were to design an extrusion screw to produce biomass solid fuel in a cold extrusion process, and investigate the effects of molasses used as a selected adhesive on the physical properties of extruded products. The material employed consisted of crushed coconut shell char and coconut fiber char mixed at a ratio of 40:60. The ratios of molasses in the mixture were 10:100, 15:100 and 20:100 (by weight and the extrusion die angles were 1.0, 1.1, 1.2, and 1.3 degrees gradation per experiment. The experimental results showed that the newly designed screw could function properly in the output range 0.75-0.90 kg/min, which is close to the design value. Regarding the molasses's effect on solid fuel properties, increasing the share of molasses was positive for both output and strength of the resulting briquettes, whereas the results of increasing die angle showed decreases in both output and strength. The compressive strength varied between 2.49-2.87 MPa in all circumstances, which was considerably higher than acceptable industrial level. Furthermore, the extruded solid fuel showed excellent resistance to impact force. Regarding energy consumption, the amount of electrical energy used in the extrusion process was insignificant, ranging between 0.040-0.079 kWh/kg.

  6. Algal biomass as a global source of transport fuels: Overview and development perspectives

    Directory of Open Access Journals (Sweden)

    Kifayat Ullah

    2014-08-01

    Full Text Available As a result of the global fuel crisis of the early 1970s, coupled with concerns for the environment, the use of biofuel has been on the increase in many regions throughout the world. At present, a total of approximately 30 billion (30×109 liters of biofuel are utilized worldwide annually, although most countries rely hugely on the first generation biofuel. The limitations of the first and second generation biofuel gave rise to current interest in algae as a promising alternative to these conventional biofuel sources. Algal biomass could provide a lion׳s share of the global transport fuel requirements in future. The present review highlights some important developments in, and potentials of algaculture as a major biomass resource of the future. However, the major constraint to commercial-scale algae farming for energy production is the cost factor, which must be addressed adequately before its potentials can be harnessed.

  7. Coming on stream: Financing biomass and alternative-fuel projects in the 1990s

    International Nuclear Information System (INIS)

    Mumford, E.B. Jr.

    1993-01-01

    Biomass-energy and alternative-fuels projects make environmental sense, but do they make economic sense? In the current project-finance environment, moving ideas off the drawing board and transforming them into reality takes more than vision and commitment; it takes the ability to understand and address the financial markets' perception of risk. This paper examines the state of the project-finance market, both as it pertains to biomass and alternative-fuels projects and in more general terms, focusing on what project sponsors and developers need to dot to obtain both early-state and construction/term financing, and the role a financial adviser can play in helping ensure access to funds at all stages

  8. A strategic assessment of forest biomass and fuel reduction treatments in western states

    Science.gov (United States)

    Bob Rummer; Jeff Prestemon; Dennis May; Pat Miles; John Vissage; Ron McRoberts; Greg Liknes; Wayne D. Shepperd; Dennis Ferguson; William Elliot; Sue Miller; Steve Reutebuch; Jamie Barbour; Jeremy Fried; Bryce Stokes; Edward Bilek; Ken Skog

    2003-01-01

    In the 15 western states there are at least 28 million acres of forest that could benefit from some type of mechanical treatment to reduce hazardous fuel loading. It is estimated that about 60 percent of this area could be operationally accessible for treatment with a total biomass treatment volume of 345 million bone dry tons (bdt). Two-thirds of this forest area is...

  9. Improved moulding material for addition to nuclear fuel particles to produce nuclear fuel elements

    International Nuclear Information System (INIS)

    Miertschin, G.N.; Leary, D.F.

    1976-01-01

    A suggestion is made to improve the moulding materials used to produce carbon-contained nuclear fuel particles by a coke-reducing added substance. The nuclear fuel particles are meant for the formation of fuel elements for gas-cooled high-temperature nuclear reactors. The moulding materials are above all for the formation of coated particles which are burnt in situ in nuclear fuel element chambers out of 'green' nuclear fuel bodies. The added substance improves the shape stability of the particles forming and prevents a stiding or bridge formation between the particles or with the surrounding walls. The following are named as added substances: 1) Polystyrene and styrene-butadiene-Co polymers (mol. wt. between 5oo and 1,000,000), 2) aromatic compounds (mol. wt. 75 to 300), 3) saturated hydrocarbon polymers (mol. wt. 5,000 to 1,000,000). Additional release agents further improve the properties in the same direction (e.g. alcohols, fatty acids, amines). (orig.) [de

  10. Analysis of Indirectly Fired Gas Turbine for Wet Biomass Fuels Based on commercial micro gas turbine data

    DEFF Research Database (Denmark)

    Elmegaard, Brian; Qvale, Einar Bjørn

    2002-01-01

    The results of a study of a novel gas turbine configuration is being presented. In this power plant, an Indirectly Fired Gas Turbine (IFGT), is being fueled with very wet biomass. The exhaust gas is being used to dry the biomass, but instead of striving to recover as much as possible of the thermal...... fueled by dry biomass assuming negligible pressure loss in the heat exchanger and the combustion chamber, the IFGT fueled with wet biomass (Wet IFGT) assuming no pressure losses, and finally both the Simple and the Wet IFGT incorporating typical data for pressure losses of commercially available micro...... turbines. The study shows that the novel configuration, in which an IFGT and a drying unit have been combined, has considerable merit, in that its performance exceeds that of the currently available methods converting wet biomass to electric power by a factor of five. The configuration also has clear...

  11. Laboratory Studies of Water Uptake by Biomass Burning Smoke: Role of Fuel Inorganic Content, Combustion Phase and Aging

    Science.gov (United States)

    Dubey, M. K.; Bixler, S. L.; Romonosky, D.; Lam, J.; Carrico, C.; Aiken, A. C.

    2017-12-01

    Biomass burning aerosol emissions have substantially increased with observed warming and drying in the southwestern US. While wildfires are projected to intensify missing knowledge on the aerosols hampers assessments. Observations demonstrate that enhanced light absorption by coated black carbon and brown carbon can offset the cooling effects of organic aerosols in wildfires. However, if mixing processes that enhance this absorption reduce the aerosol lifetime it would lower their atmospheric burden. In order to elucidate mechanisms regulating this tradeoff we performed laboratory studies of smoke from biomass burning. We focus on aerosol optical properties and their hygroscopic response. Fresh emissions from burning 30 fuels under flaming and smoldering conditions were investigated. We measured aerosol absorption, scattering and extinction at multiple wavelengths, water uptake at 85% relative humidity (fRH85%) with a humidity controlled dual nephelometer, and black carbon mass with a SP2. Trace gases and the ionic content of the fuel and smoke were also measured We find that whereas the optical properties of smoke were strongly dictated by the flaming versus smoldering nature of the burn, the observed hygroscopicity was intimately linked to the chemical composition of the fuel. The mean hygroscopicity ranged from nearly hydrophobic (fRH85% = 1) to very hydrophilic (fRH85% = 2.1) values typical of pure deliquescent salts. The k values varied from 0.004 to 0.18 and correlated well with inorganic content. Inorganic fuel content was the key driver of hygroscopicity with combustion phase playing a secondary but important role ( 20%). Flaming combustion promoted hygroscopicity by generating refractory black carbon and ions. Smoldering combustion suppressed hygroscopicity by producing hydrogenated organic species. Wildfire smoke was hydrophobic since the evergreen species with low inorganic content dominated in these fires. We also quantify the mass absorption cross

  12. Leaching of lead by ammonium salts and EDTA from Salvinia minima biomass produced during aquatic phytoremediation

    Energy Technology Data Exchange (ETDEWEB)

    Nunez-Lopez, Roberto Aurelio [Centro de Investigacion y Desarrollo Tecnologico en Electroquimica (CIDETEQ), Parque Tecnologico Queretaro, Sanfandila, Pedro Escobedo Qro., 76700 Mexico (Mexico)], E-mail: ndahi2000@yahoo.com; Meas, Yunny [Centro de Investigacion y Desarrollo Tecnologico en Electroquimica (CIDETEQ), Parque Tecnologico Queretaro, Sanfandila, Pedro Escobedo Qro., 76700 Mexico (Mexico)], E-mail: yunnymeas@cideteq.mx; Citlalli Gama, Silvia; Ortega Borges, Raul [Centro de Investigacion y Desarrollo Tecnologico en Electroquimica (CIDETEQ), Parque Tecnologico Queretaro, Sanfandila, Pedro Escobedo Qro., 76700 Mexico (Mexico); Olguin, Eugenia J. [Instituto de Ecologia (INECOL), Apdo. Postal 63, Xalapa, Veracruz 91000 (Mexico)

    2008-06-15

    Plant biomass harvested after heavy-metal phytoremediation must be considered as a hazardous waste that should be contained or treated appropriately before disposal or reuse. As a potential method to detoxify the biomass and to convert this material to a suitable fertilizer or mulch, leaching of lead (Pb) from Salvinia minima biomass was studied by testing water, several aqueous ammonium salts, and EDTA solution as lead extractants. The research was carried out in two phases: (i) a leaching study to determine the lead-extraction efficiency of the different leachants, and (ii) a thermodynamic analysis to identify the likely reactions and stable Pb(II) species formed in the leaching systems of the most efficient leachants. Experimentally, lead concentrations measured in leached biomass and in leachates were significantly different among the various leachants. It was determined that the extraction strength of the leachants followed the order: EDTA > ammonium oxalate > water {approx} ammonium nitrate > ammonium acetate, achieving Pb extraction efficiencies of 99%, 70%, 7.2%, 6.9% and 1.3%, respectively, in single-stage extractions. The thermodynamic study indicated that the dominant species produced by the leaching process should be the soluble species PbEDTA{sup 2-} for EDTA system, and the insoluble Pb(COO){sub 2S} precipitate for the oxalate system.

  13. Preliminary evaluation of fungicidal and termiticidal activities of filtrates from biomass slurry fuel production

    Energy Technology Data Exchange (ETDEWEB)

    Kartal, S.N. [Istanbul University (Turkey). Forestry Faculty; Imamura, Y. [Kyoto University (Japan). Wood Research Institute; Tsuchiya, F.; Ohsato, K. [JGC Corporation, Yokohama (Japan)

    2004-10-01

    Biomass slurry fuel (BSF) production has recently been developed as a natural energy for the conversion of solid biomass into fuel. In addition to using fuel, filtrates from BSF production may also serve a chemical source with several organic compounds. There is an increasing interest in the research and application of biomass-based filtrates. In this study, fungicidal and termiticidal properties of filtrates from BSF production using sugi (Cryptomeria japonica) and acacia (Acacia mangium) wood were evaluated in laboratory decay and termite resistance tests. Wood blocks treated with the filtrates showed increased resistance against brown-rot fungus, Formitopsis palustris. However the filtrates from sugi wood processed at 270{sup o}C which contained less phenolic compounds than the other filtrates were effective against white-rot fungus, Trametes versicolor. Phenolic compounds of filtrates seemed to play a role in the decay resistance tests however the filtrates did not increase the durability of the wood blocks against subterranean termites Coptotermes formosanus. Despite high acetic and lactic acid content of the filtrates, vanillin content of the filtrates may have served as an additional food source and promoted termite attack. It can be concluded that filtrates with phenolic compounds from lignin degradation during BSF production can be considered for targeted inhibition of brown-rot. (author)

  14. Re-thinking china's densified biomass fuel policies: Large or small scale?

    International Nuclear Information System (INIS)

    Shan, Ming; Li, Dingkai; Jiang, Yi; Yang, Xudong

    2016-01-01

    Current policies and strategies related to the utilization of densified biomass fuel (DBF) in China are mainly focused on medium- or large-scale manufacturing modes, which cannot provide feasible solutions to solve the household energy problems in China's rural areas. To simplify commercial processes related to the collection of DBF feedstock and the production and utilization of fuel, a novel village-scale DBF approach is proposed. Pilot demonstration projects have shown the feasibility and flexibility of this new approach in realizing sustainable development in rural China. Effective utilization of DBF in rural China will lead to gains for global, regional, and local energy savings, environmental protection, sustainable development, and related social benefits. It could also benefit other developing countries for better utilization of biomass as a viable household energy source. This proposal therefore delivers the possibility of reciprocal gains, and as such deserves the attention of policy makers and various stakeholders. - Highlights: •A field survey of Chinese densified biomass fuel (DBF) development is conducted. •The current situation and problems related to China's DBF industry are analyzed. •A novel and viable village-scale DBF utilization mode is proposed. •Further actions are suggested to boost the utilization of DBF in rural China.

  15. Process analysis of a molten carbonate fuel cell power plant fed with a biomass syngas

    Science.gov (United States)

    Tomasi, C.; Baratieri, M.; Bosio, B.; Arato, E.; Baggio, P.

    The coupling of renewable energy sources and innovative power generation technologies is of topical interest to meet demands for increased power generation and cleaner environmental performance. Accordingly, biomass is receiving considerable attention as a partial substitute for fossil fuels, as it is more environmentally friendly and provides a profitable way of disposing of waste. In addition, fuel cells are perceived as most promising electrical power generation systems. Today, many plants combining these two concepts are under study; they differ in terms of biomass type and/or power plant configuration. Even if the general feasibility of such applications has been demonstrated, there are still many associated problems to be resolved. This study examines a plant configuration based on a molten carbonate fuel cell (MCFC) and a recirculated fluidized-bed reactor which has been applied to the thermal conversion of many types of biomass. Process analysis is conducted by simulating the entire plant using a commercial code. In particular, an energy assessment is studied by taking account of the energy requirements of auxiliary equipment and the possibility of utilizing the exhaust gases for cogeneration.

  16. Preliminary evaluation of fungicidal and termiticidal activities of filtrates from biomass slurry fuel production.

    Science.gov (United States)

    Kartal, S N; Imamura, Y; Tsuchiya, F; Ohsato, K

    2004-10-01

    Biomass slurry fuel (BSF) production has recently been developed as a natural energy for the conversion of solid biomass into fuel. In addition to using fuel, filtrates from BSF production may also serve a chemical source with several organic compounds. There is an increasing interest in the research and application of biomass-based filtrates. In this study, fungicidal and termiticidal properties of filtrates from BSF production using sugi (Cryptomeria japonica) and acacia (Acacia mangium) wood were evaluated in laboratory decay and termite resistance tests. Wood blocks treated with the filtrates showed increased resistance against brown-rot fungus, Fomitopsis palustris. However the filtrates from sugi wood processed at 270 degrees C which contained less phenolic compounds than the other filtrates were effective against white-rot fungus, Trametes versicolor. Phenolic compounds of filtrates seemed to play a role in the decay resistance tests however the filtrates did not increase the durability of the wood blocks against subterranean termites Coptotermes formosanus. Despite high acetic and lactic acid content of the filtrates, vanillin content of the filtrates may have served as an additional food source and promoted termite attack. It can be concluded that filtrates with phenolic compounds from lignin degradation during BSF production can be considered for targeted inhibition of brown-rot.

  17. Final Renewable Fuel Standards for 2014, 2015 and 2016, and the Biomass-Based Diesel Volume for 2017

    Science.gov (United States)

    EPA is proposing the volume requirements and associated percentage standards that would apply under the RFS program in calendar years 2014, 2015, and 2016 for cellulosic biofuel, biomass-based diesel, advanced biofuel, and total renewable fuel.

  18. Fossil fuel and biomass burning effect on climate - heating or cooling?

    International Nuclear Information System (INIS)

    Kaufman, Y.J.; Fraser, R.S.; Mahoney, R.L.

    1991-01-01

    Emission from burning of fossil fuels and biomass (associated with deforestation) generates a radiative forcing on the atmosphere and a possible climate change. Emitted trace gases heat the atmosphere through their greenhouse effect, while particulates formed from emitted SO 2 cause cooling by increasing cloud albedos through alteration of droplet size distributions. This paper reviews the characteristics of the cooling effect and applies Twomey's theory to check whether the radiative balance favours heating or cooling for the cases of fossil fuel and biomass burning. It is also shown that although coal and oil emit 120 times as many CO 2 molecules as SO 2 molecules, each SO 2 molecule is 50-1100 times more effective in cooling the atmosphere (through the effect of aerosol particles on cloud albedo) than a CO 2 molecule is in heating it. Note that this ratio accounts for the large difference in the aerosol (3-10 days) and CO 2 (7-100 years) lifetimes. It is concluded, that the cooling effect from coal and oil burning may presently range from 0.4 to 8 times the heating effect. Within this large uncertainty, it is presently more likely that fossil fuel burning causes cooling of the atmosphere rather than heating. Biomass burning associated with deforestation, on the other hand, is more likely to cause heating of the atmosphere than cooling since its aerosol cooling effect is only half that from fossil fuel burning and its heating effect is twice as large. Future increases in coal and oil burning, and the resultant increase in concentration of cloud condensation nuclei, may saturate the cooling effect, allowing the heating effect to dominate. For a doubling in the CO 2 concentration due to fossil fuel burning, the cooling effect is expected to be 0.1 to 0.3 of the heating effect. 75 refs., 8 tabs

  19. The Mississippi University Research Consortium for the Utilization of Biomass: Production of Alternative Fuels from Waste Biomass Initiative

    Energy Technology Data Exchange (ETDEWEB)

    Drs. Mark E. Zapp; Todd French; Lewis Brown; Clifford George; Rafael Hernandez; Marvin Salin (from Mississippie State University); Drs. Huey-Min Hwang, Ken Lee, Yi Zhang; Maria Begonia (from Jackson State University); Drs. Clint Williford; Al Mikell (from the University of Mississippi); Drs. Robert Moore; Roger Hester (from the University of Southern Mississippi).

    2009-03-31

    The Mississippi Consortium for the Utilization of Biomass was formed via funding from the US Department of Energy's EPSCoR Program, which is administered by the Office of Basic Science. Funding was approved in July of 1999 and received by participating Mississippi institutions by 2000. The project was funded via two 3-year phases of operation (the second phase was awarded based on the high merits observed from the first 3-year phase), with funding ending in 2007. The mission of the Consortium was to promote the utilization of biomass, both cultured and waste derived, for the production of commodity and specialty chemicals. These scientific efforts, although generally basic in nature, are key to the development of future industries within the Southeastern United States. In this proposal, the majority of the efforts performed under the DOE EPSCoR funding were focused primarily toward the production of ethanol from lignocellulosic feedstocks and biogas from waste products. However, some of the individual projects within this program investigated the production of other products from biomass feeds (i.e. acetic acid and biogas) along with materials to facilitate the more efficient production of chemicals from biomass. Mississippi is a leading state in terms of raw biomass production. Its top industries are timber, poultry production, and row crop agriculture. However, for all of its vast amounts of biomass produced on an annual basis, only a small percentage of the biomass is actually industrially produced into products, with the bulk of the biomass being wasted. This situation is actually quite representative of many Southeastern US states. The research and development efforts performed attempted to further develop promising chemical production techniques that use Mississippi biomass feedstocks. The three processes that were the primary areas of interest for ethanol production were syngas fermentation, acid hydrolysis followed by hydrolyzate fermentation, and

  20. Solar Reforming of Carbon Dioxide to Produce Diesel Fuel

    Energy Technology Data Exchange (ETDEWEB)

    Dennis Schuetzle; Robert Schuetzle

    2010-12-31

    Measurement Methods for Assessing Contaminant Levels in Captured CO2 Streams; (3) An Assessment of Current Commercial Scale Fisher-Tropsch (F-T) Technologies for the Conversion of Syngas to Fuels; (4) An Overview of CO2 Capture Technologies from Various Industrial Sources; and (5) Lifecycle Analysis for the Capture and Conversion of CO2 to Synthetic Diesel Fuel. Commercial scale Sunexus CO2 Solar Reformer plant designs, proposed in this report, should be able to utilize waste CO2 from a wide variety of industrial sources to produce a directly usable synthetic diesel fuel that replaces petroleum derived fuel, thus improving the United States energy security while also sequestering CO2. Our material balance model shows that every 5.0 lbs of CO2 is transformed using solar energy into 6.26 lbs (1.0 U.S. gallon) of diesel fuel and into by-products, which includes water. Details are provided in the mass and energy model in this report.

  1. Are forestation, bio-char and landfilled biomass adequate offsets for the climate effects of burning fossil fuels?

    NARCIS (Netherlands)

    Reijnders, L.

    2009-01-01

    Forestation and landfilling purpose-grown biomass are not adequate offsets for the CO2 emission from burning fossil fuels. Their permanence is insufficiently guaranteed and landfilling purpose-grown biomass may even be counterproductive. As to permanence, bio-char may do better than forests or

  2. Cofiring biomass and coal for fossil fuel reduction and other benefits–Status of North American facilities in 2010

    Science.gov (United States)

    David Nicholls; John. Zerbe

    2012-01-01

    Cofiring of biomass and coal at electrical generation facilities is gaining in importance as a means of reducing fossil fuel consumption, and more than 40 facilities in the United States have conducted test burns. Given the large size of many coal plants, cofiring at even low rates has the potential to utilize relatively large volumes of biomass. This could have...

  3. Progress in researches on MOX fuel pellet producing technology in China

    International Nuclear Information System (INIS)

    Hu Xiaodan

    2010-01-01

    Being the key section of nuclear-fuel cycle, the producing technology of MOX(UO 2 -PuO 2 ) fuel had driven to maturity in France, England, Russia, Belgium, etc. MOX fuel had been applied in FBR and LWR successfully in those countries. With the rapidly developing of nuclear-generated power, the MOX fuel for FBR and LWR was active demanded in China. However, the producing technology of MOX fuel developed slowly. During the period of 'the seventh five year's project', MOX fuel pellet was produced by mechanically mixed method and oxalate deposited method, respectively. Parts of cool performance of MOX fuel pellet produced by oxalate deposited method reached the qualification of fuel for FBR. During the period of 'the ninth five year's project' and 'the tenth five year's project', the technical route of producing MOX fuel was determined, and the test line of producing MOX fuel was built preliminarily. In the same time, the producing technology and analyzing technology of MOX fuel pellet by mechanically mixed was studied roundly, and the representative analogue pellet(UO 2 -CeO 2 ) was produced. That settled the supporting technology for the commercial process and research of MOX fuel rod and MOX fuel module. (authors)

  4. Using the second law of thermodynamics for enrichment and isolation of microorganisms to produce fuel alcohols or hydrocarbons.

    Science.gov (United States)

    Kohn, Richard A; Kim, Seon-Woo

    2015-10-07

    Fermentation of crops, waste biomass, or gases has been proposed as a means to produce desired chemicals and renewable fuels. The second law of thermodynamics has been shown to determine the net direction of metabolite flow in fermentation processes. In this article, we describe a process to isolate and direct the evolution of microorganisms that convert cellulosic biomass or gaseous CO2 and H2 to biofuels such as ethanol, 1-butanol, butane, or hexane (among others). Mathematical models of fermentation elucidated sets of conditions that thermodynamically favor synthesis of desired products. When these conditions were applied to mixed cultures from the rumen of a cow, bacteria that produced alcohols or alkanes were isolated. The examples demonstrate the first use of thermodynamic analysis to isolate bacteria and control fermentation processes for biofuel production among other uses. Copyright © 2015 Elsevier Ltd. All rights reserved.

  5. Gasoline from biomass through refinery-friendly carbohydrate-based bio-oil produced by ketalization.

    Science.gov (United States)

    Batalha, Nuno; da Silva, Alessandra V; de Souza, Matheus O; da Costa, Bruna M C; Gomes, Elisa S; Silva, Thiago C; Barros, Thalita G; Gonçalves, Maria L A; Caramão, Elina B; dos Santos, Luciana R M; Almeida, Marlon B B; de Souza, Rodrigo O M A; Lam, Yiu L; Carvalho, Nakédia M F; Miranda, Leandro S M; Pereira, Marcelo M

    2014-06-01

    The introduction of biomass-derived compounds as an alternative feed into the refinery structure that already exists can potentially converge energy uses with ecological sustainability. Herein, we present an approach to produce a bio-oil based on carbohydrate-derived isopropylidene ketals obtained by reaction with acetone under acidic conditions directly from second-generation biomass. The obtained bio-oil showed a greater chemical inertness and miscibility with gasoil than typical bio-oil from fast pyrolysis. Catalytic upgrading of the bio-oil over zeolites (USY and Beta) yielded gasoline with a high octane number. Moreover, the co-processing of gasoil and bio-oil improved the gasoline yield and quality compared to pure gasoil and also reduced the amount of oxygenated compounds and coke compared with pure bio-oil, which demonstrates a synergistic effect. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  6. Method to produce water-soluble sugars from biomass using solvents containing lactones

    Science.gov (United States)

    Dumesic, James A.; Luterbacher, Jeremy S.

    2017-08-08

    A process to produce an aqueous solution of carbohydrates that contains C6-sugar-containing oligomers, C6 sugar monomers, C5-sugar-containing oligomers, C5 sugar monomers, or any combination thereof is presented. The process includes the steps of reacting biomass or a biomass-derived reactant with a solvent system including a lactone and water, and an acid catalyst. The reaction yields a product mixture containing water-soluble C6-sugar-containing oligomers, C6-sugar monomers, C5-sugar-containing oligomers, C5-sugar monomers, or any combination thereof. A solute is added to the product mixture to cause partitioning of the product mixture into an aqueous layer containing the carbohydrates and a substantially immiscible organic layer containing the lactone.

  7. Fuel-nitrogen conversion in the combustion of small amines using dimethylamine and ethylamine as biomass-related model fuels

    DEFF Research Database (Denmark)

    Lucassen, Arnas; Zhang, Kuiwen; Warkentin, Julia

    2012-01-01

    Laminar premixed flames of the two smallest isomeric amines, dimethylamine and ethylamine, were investigated under one-dimensional low-pressure (40mbar) conditions with the aim to elucidate pathways that may contribute to fuel-nitrogen conversion in the combustion of biomass. For this, identical...... flames of both fuels diluted with 25% Ar were studied for three different stoichiometries (Φ=0.8, 1.0, and 1.3) using in situ molecular-beam mass spectrometry (MBMS). Quantitative mole fractions of reactants, products and numerous stable and reactive intermediates were determined by electron ionization...... (EI) MBMS with high mass resolution to separate overlapping features from species with different heavy elements by exact mass. Species assignment was assisted by using single-photon vacuum-ultraviolet (VUV) photoionization (PI) MBMS. The results indicate formation of a number of nitrogenated...

  8. Deposit Probe Measurements in Danish Grate and Pulverized Fuel Biomass Power Boilers

    DEFF Research Database (Denmark)

    Hansen, Stine Broholm; Jensen, Peter Arendt; Jappe Frandsen, Flemming

    2012-01-01

    . Corresponding samples of fuels, ash deposits and fly ash have provided information on the transformation of inorganics in the boiler. Generally, grate fired boilers provide a fly ash containing high contents of K, Cl and S compared to the fuel ash, while suspension fired boilers fly ash has a composition nearly...... similar to the fuel ash. Inner most biomass deposits are always salt-rich, while thicker deposit layers also contain some Si and Ca. Deposit probe formation rate measurements have been performed in different ways on several boilers. Grate and suspension fired boilers seems to cause similar deposit...... formation rates. Suspension fired boilers generate more fly ash, while grate boilers form a fly ash with a higher fraction of melt formation (and thereby a higher sticking probability) at similar temperatures. For suspension fired units it is observed that wood with a lower ash content than straw gives rise...

  9. Thermochemical Conversion of Woody Biomass to Fuels and Chemicals Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Pendse, Hemant P. [Univ. of Maine, Orono, ME (United States)

    2015-09-30

    Maine and its industries identified more efficient utilization of biomass as a critical economic development issue. In Phase I of this implementation project, a research team was assembled, research equipment was implemented and expertise was demonstrated in pyrolysis, hydrodeoxygenation of pyrolysis oils, catalyst synthesis and characterization, and reaction engineering. Phase II built upon the infrastructure to innovate reaction pathways and process engineering, and integrate new approaches for fuels and chemical production within pulp and paper and other industries within the state. This research cluster brought together chemists, engineers, physicists and students from the University of Maine, Bates College, and Bowdoin College. The project developed collaborations with Oak Ridge National Laboratory and Brookhaven National Laboratory. The specific research projects within this proposal were of critical interest to the DoE - in particular the biomass program within EERE and the catalysis/chemical transformations program within BES. Scientific and Technical Merit highlights of this project included: (1) synthesis and physical characterization of novel size-selective catalyst/supports using engineered mesoporous (1-10 nm diameter pores) materials, (2) advances in fundamental knowledge of novel support/ metal catalyst systems tailored for pyrolysis oil upgrading, (3) a microcalorimetric sensing technique, (4) improved methods for pyrolysis oil characterization, (5) production and characterization of woody biomass-derived pyrolysis oils, (6) development of two new patented bio oil pathways: thermal deoxygenation (TDO) and formate assisted pyrolysis (FASP), and (7) technoeconomics of pyrolysis of Maine forest biomass. This research cluster has provided fundamental knowledge to enable and assess pathways to thermally convert biomass to hydrocarbon fuels and chemicals.

  10. Biochemical conversions of lignocellulosic biomass for sustainable fuel-ethanol production in the upper Midwest

    Science.gov (United States)

    Brodeur-Campbell, Michael J.

    Biofuels are an increasingly important component of worldwide energy supply. This research aims to understand the pathways and impacts of biofuels production, and to improve these processes to make them more efficient. In Chapter 2, a life cycle assessment (LCA) is presented for cellulosic ethanol production from five potential feedstocks of regional importance to the upper Midwest — hybrid poplar, hybrid willow, switchgrass, diverse prairie grasses, and logging residues — according to the requirements of Renewable Fuel Standard (RFS). Direct land use change emissions are included for the conversion of abandoned agricultural land to feedstock production, and computer models of the conversion process are used in order to determine the effect of varying biomass composition on overall life cycle impacts. All scenarios analyzed here result in greater than 60% reduction in greenhouse gas emissions relative to petroleum gasoline. Land use change effects were found to contribute significantly to the overall emissions for the first 20 years after plantation establishment. Chapter 3 is an investigation of the effects of biomass mixtures on overall sugar recovery from the combined processes of dilute acid pretreatment and enzymatic hydrolysis. Biomass mixtures studied were aspen, a hardwood species well suited to biochemical processing; balsam, a high-lignin softwood species, and switchgrass, an herbaceous energy crop with high ash content. A matrix of three different dilute acid pretreatment severities and three different enzyme loading levels was used to characterize interactions between pretreatment and enzymatic hydrolysis. Maximum glucose yield for any species was 70% of theoretical for switchgrass, and maximum xylose yield was 99.7% of theoretical for aspen. Supplemental β-glucosidase increased glucose yield from enzymatic hydrolysis by an average of 15%, and total sugar recoveries for mixtures could be predicted to within 4% by linear interpolation of the pure

  11. Toxic and hazardous air pollutants from co-firing biomass fuels, fossil fuels, MSW and RDF

    International Nuclear Information System (INIS)

    Junge, D.C.

    1991-01-01

    Toxic and hazardous pollutants are defined and then are considered from the perspective of pollutants which enter the combustion process with the fuel (principally the metals and metallic compounds) and pollutants which are formed as products of incomplete combustion. Control strategies are reviewed through the entire process including fuel preparation and storage, combustion control and the application of air pollution control devices. Measurement techniques for specific toxic and hazardous air pollutants are discussed

  12. Techno-economic assessment of a solar PV, fuel cell, and biomass gasifier hybrid energy system

    Directory of Open Access Journals (Sweden)

    Anand Singh

    2016-11-01

    Full Text Available The interest of power is expanding step by step all through the world. Because of constrained measure of fossil fuel, it is vital to outline some new non-renewable energy frameworks that can diminish the reliance on ordinary energy asset. A hybrid off-grid renewable energy framework might be utilized to reduction reliance on the traditional energy assets. Advancement of crossover framework is a procedure to choose the best mix of part and there cost that can give shabby, solid and successful option energy resource. In this paper sun oriented photovoltaic, fuel cell, biomass gasifier generator set, battery backup and power conditioning unit have been simulated and optimized for educational institute, energy centre, Maulana Azad National Institute of Technology, Bhopal in the Indian state of Madhya Pradesh. The area of the study range on the guide situated of 23°12′N latitude and 77°24′E longitude. In this framework, the essential wellspring of power is sun based solar photovoltaic system and biomass gasifier generator set while fuel cell and batteries are utilized as reinforcement supply. HOMER simulator has been utilized to recreate off the grid and it checks the specialized and financial criteria of this hybrid energy system. The execution of every segment of this framework is dissected lastly delicate examination has been performing to enhance the mixture framework at various conditions. In view of the recreation result, it is found that the cost of energy (COE of a biomass gasifier generator set, solar PV and fuel cell crossover energy system has been found to be 15.064 Rs/kWh and complete net present cost Rs.51,89003. The abundance power in the proposed framework is observed to be 36 kWh/year with zero rates unmet electrical burden.

  13. Are forestation, bio-char and landfilled biomass adequate offsets for the climate effects of burning fossil fuels?

    International Nuclear Information System (INIS)

    Reijnders, L.

    2009-01-01

    Forestation and landfilling purpose-grown biomass are not adequate offsets for the CO 2 emission from burning fossil fuels. Their permanence is insufficiently guaranteed and landfilling purpose-grown biomass may even be counterproductive. As to permanence, bio-char may do better than forests or landfilled biomass, but there are major uncertainties about net greenhouse gas emissions linked to the bio-char life cycle, which necessitate suspension of judgement about the adequacy of bio-char addition to soils as an offset for CO 2 emissions from burning fossil fuels.

  14. Biomass gasification: Produced gas upgrading by in-bed use of dolomite

    Energy Technology Data Exchange (ETDEWEB)

    Olivares, A.; Aznar, M.P.; Caballero, M.A.; Gil, J.; Frances, E. [Univ. of Saragossa (Spain). Chemical and Environmental Engineering Dept.; Corella, J. [Univ. Complutense of Madrid (Spain). Chemical Engineering Dept.

    1997-12-01

    When some calcined dolomite (OCa{center_dot}OMg) is used in the bed of a biomass gasifier of fluidized bed type the raw gas produced is cleaner than when only silica sand is used in it as fluidizing medium. In-bed dolomite changes the product distribution at the gasifier exit because of in-situ catalytic reactions promoted by the calcined dolomite. Gasifying with steam-O{sub 2} mixtures causes the tar content in the exit gas to decrease from 12 to 2--3 g tar/m{sup 3}{sub n}, the H{sub 2} content to increase from 25--28 to 43 vol%, and the CO content to decrease from 45 to 27 vol% when the gas and char yields, heating value of the gas, and other main variables also undergo important changes because of the in-bed dolomite. The experimental work here reported is carried out at small pilot plant scale in a 15 cm i.d. atmospheric and bubbling fluidized bed gasifier fed by 10 kg biomass/h. Dolomite is continuously fed to the gasifier, mixed with the biomass in percentages of 2--3 wt% of the total mass flow fed. A 10 wt% of calcined dolomite in the gasifier bed is enough to significantly improve the product distribution and gas quality.

  15. Thermochemistry: the key to minerals separation from biomass for fuel use in high performance systems

    Energy Technology Data Exchange (ETDEWEB)

    Overend, R.P. [National Renewable Energy Laboratory, Golden, CO (United States)

    1996-12-31

    Biomass use in high efficiency thermal electricity generation is limited not by the properties of the organic component of biomass, but by the behavior of the associated mineral matter at high temperatures. On a moisture and ash free basis biomass, which has an average formula of CH{sub 1.4}O{sub 0.6}N{sub 0.1}, has a relatively low heating value of 18.6 GJ/t. However, this would not limit its use in high efficiency combustion systems because adequate high temperatures could be reached to achieve high carnot cycle efficiencies. These high temperatures cannot be reached because of the fouling and slagging propensities of the minerals in biomass. The mineral composition is a function of soils and the growth habit of the biomass, however, the most important element is potassium, which either alone or in combinating with silica forms the basis of fouling and slagging behaviors. Growing plants selectively concentrate potassium in their cells, which along with nitrogen and phosphorus are the key macronutrients for plant growth. Annual plants tend to have very high potassium contents, although wood biomass exclusive of the living cambial layer (i.e. minus the bark, small branches, and leaves) has minimal potassium content and other nutrients. Under combustion conditions the potassium is mobilized, especially in the presence of chlorine, at relative low temperatures and fouls heat transfer surfaces and corrodes high performance metals used, for example, in the high temperature sections of burners and gas turbines. Recent work has demonstrated the phenomenology of ash fouling, mainly by the potassium component of biomass, as well as identifying the key species such as KOH, KCl, and sulphates that are involved in potassium transport at temperatures <800 deg C. Techniques that separate the mineral matter from the fuel components (carbon and hydrogen) at low temperatures reduce or limit the alkali metal transport phenomena and result in very high efficiency combustion

  16. Enzymatic hydrolysis and characterization of waste lignocellulosic biomass produced after dye bioremediation under solid state fermentation.

    Science.gov (United States)

    Waghmare, Pankajkumar R; Kadam, Avinash A; Saratale, Ganesh D; Govindwar, Sanjay P

    2014-09-01

    Sugarcane bagasse (SCB) adsorbes 60% Reactive Blue172 (RB172). Providensia staurti EbtSPG able to decolorize SCB adsorbed RB172 up to 99% under solid state fermentation (SSF). The enzymatic saccharification efficiency of waste biomass after bioremediation of RB172 process (ddSCB) has been evaluated. The cellulolyitc crude enzyme produced by Phanerochaete chrysosporium used for enzymatic hydrolysis of native SCB and ddSCB which produces 0.08 and 0.3 g/L of reducing sugars respectively after 48 h of incubation. The production of hexose and pentose sugars during hydrolysis was confirmed by HPTLC. The effect of enzymatic hydrolysis on SCB and ddSCB has been evaluated by FTIR, XRD and SEM analysis. Thus, during dye biodegradation under SSF causes biological pretreatment of SCB which significantly enhanced its enzymatic saccharification. Adsorption of dye on SCB, its bioremediation under SSF produces wastes biomass and which further utilized for enzymatic saccharification for biofuel production. Copyright © 2014 Elsevier Ltd. All rights reserved.

  17. Scientific tools for fuel characterization for clean and efficient biomass combustion - SciToBiCom final report

    Energy Technology Data Exchange (ETDEWEB)

    Jappe Frandsen, F. (ed.); Glarborg, P.; Arendt Jensen, Peter [Technical Univ. of Denmark. CHEC Research Centre, Kgs. Lyngby (Denmark)] [and others

    2013-05-15

    Through years the Nordic countries and Austria have been very active in promoting biomass utilization for heat and power production. This project has succeeded in conducting a research plan including main actors in the field of biomass combustion from Denmark, Norway, Finland and Austria. The project has aimed at the development of advanced fuel analysis and characterisation methods concerning the combustion of different biomass fuels in various plant technologies of different size ranges. The goal has been to provide the basis for an improved understanding of the combustion behaviour and to collect the data in an advanced fuel database. Moreover, advanced CFD-based simulation routines considering different phenomena like single particle conversion, solid biomass combustion on the grate, release of ash forming elements, gas phase combustion and NO{sub x} formation has been developed as efficient, future process analysis and plant design tools. (LN)

  18. Chemical composition, pretreatments and saccharification of Senna siamea (Lam.) H.S. Irwin & Barneby: An efficient biomass producing tree legume.

    Science.gov (United States)

    Mund, Nitesh K; Dash, Debabrata; Barik, Chitta R; Goud, Vaibhav V; Sahoo, Lingaraj; Mishra, Prasannajit; Nayak, Nihar R

    2016-05-01

    Protocols were developed for efficient release of glucose from the biomass of Senna siamea, one of the highly efficient biomass producing tree legumes. Composition of mature, 1year and 2years coppice biomass were analysed. For the hydrolysis of the glucan, two pretreatments, cellulose solvent- and organic solvent-based lignocellulose fractionation (COSLIF) and alkali (sodium hydroxide) were used; COSLIF (85% phosphoric acid, 45min incubation at 50°C) pretreated mature biomass exhibited best result in which 88.90% glucose released after 72h of incubation with the use of 5 filter paper units (FPU) of cellulase and 10 international units (IU) of β-glucosidase per gram of glucan. Of the biomass of different particle sizes (40-200mesh) used for saccharification, 40-60mesh shown the maximum glucose release. COSLIF pretreated mature, 1year and 2years coppice biomass showed equivalent glucose release profiles. Copyright © 2016 Elsevier Ltd. All rights reserved.

  19. Biomass Pyrolysis to Hydrocarbon Fuels in the Petroleum Refining Context: Cooperative Research and Development Final Report, CRADA Number CRD-12-500

    Energy Technology Data Exchange (ETDEWEB)

    Chum, Helena L. [National Renewable Energy Lab. (NREL), Golden, CO (United States)

    2018-01-01

    This work focuses on developing a thermochemical route to produce biofuels from agricultural wastes such as sugar cane bagasse, wood chips or corn stover; more specifically it intends to develop the biomass pyrolysis route, which produces bio-oils. Production of bio-oils by pyrolysis is a commercial technology. However, bio-oils are currently not being used for liquid fuels production. Although bio-oils can be produced by high-pressure liquefaction, pyrolysis is a less expensive technology. Nevertheless, bio-oils cannot be used directly as a transportation fuel without upgrading, since they are generally unstable, viscous, and acidic. Thus NREL and Petrobras intend to use their combined expertise to develop a two-step route to biofuels production: in the first step, a stable bio-oil is produced by NREL biomass pyrolysis technology, while in the second step it is upgraded by using two distinct catalytic processes under development by Petrobras. The first process converts bio-oil into gasoline, LPG, and fuel oil using the catalytic cracking process, while the second one, converts bio-oil into synthesis gas. Syngas gasification catalysts provided by both NREL and Petrobras will be tested. The work includes experiments at both sites to produce bio-oil and then biofuels, life-cycle analysis of each route, personnel training and development of analytical methods with a duration time of two years.

  20. Jet-Fuel Range Hydrocarbons from Biomass-Derived Sorbitol over Ni-HZSM-5/SBA-15 Catalyst

    Directory of Open Access Journals (Sweden)

    Yujing Weng

    2015-12-01

    Full Text Available Aromatics and cyclic-hydrocarbons are the significant components of jet fuel with high energy-density. However, conventional technologies for bio-fuel production cannot produce these products without further aromatization and isomerization. In this work, renewable liquid fuel with high content of aromatics and cyclic-hydrocarbons was obtained through aqueous catalytic conversion of biomass sorbitol over Ni-HZSM-5/SBA-15 catalyst. Texture characteristics of the catalyst were determined by physisorption of N2, which indicated its bimodal pore structures were microporous (HZSM-5, pore width: 0.56 nm and mesoporous (SBA-15, pore width: 8 nm. The surface acidity included weak and strong acid sites, predominantly Lewis type, and was further confirmed by the NH3-TPD and Py-IR analysis. The catalytic performances were tested in a fixed-bed reactor under the conditions of 593 K, WHSV of 0.75 h−1, GHSV of 2500 h−1 and 4.0 MPa of hydrogen pressure, whereby oil yield of 40.4 wt. % with aromatics and cyclic-hydrocarbons content of 80.0% was obtained.

  1. Liquid fuels production from biomass. Final report, for period ending June 30, 1980

    Energy Technology Data Exchange (ETDEWEB)

    Levy, P. F.; Sanderson, J. E.; Ashare, E.; Wise, D. L.; Molyneaux, M. S.

    1980-01-01

    The current program to convert biomass into liquid hydrocarbon fuels is an extension of a previous program to ferment marine algae to acetic acid. In that study it was found that marine algae could be converted to higher aliphatic organic acids and that these acids could be readily removed from the fermentation broth by membrane or liquid-liquid extraction. It was then proposed to convert these higher organic acids via Kolbe electrolysis to aliphatic hydrocarbons, which may be used as a diesel fuel. The specific goals for the current program are: (1) establish conditions under which substrates other than marine algae may be converted in good yield to organic acids, here the primary task is methane suppression; (2) modify the current 300-liter fixed packed bed batch fermenter to operate in a continuous mode; (3) change from membrane extraction of organic acids to liquid-liquid extraction; (4) optimize the energy balance of the electrolytic oxidation process, the primary task is to reduce the working potential required for the electrolysis while maintaining an adequate current density; (5) scale the entire process up to match the output of the 300 liter fermenter; and (6) design pilot plant and commercial size plant (1000 tons/day) processes for converting biomass to liquid hydrocarbon fuels and perform an economic analysis for the 1000 ton/day design.

  2. Biochemical Conversion Processes of Lignocellulosic Biomass to Fuels and Chemicals - A Review.

    Science.gov (United States)

    Brethauer, Simone; Studer, Michael H

    2015-01-01

    Lignocellulosic biomass - such as wood, agricultural residues or dedicated energy crops - is a promising renewable feedstock for production of fuels and chemicals that is available at large scale at low cost without direct competition for food usage. Its biochemical conversion in a sugar platform biorefinery includes three main unit operations that are illustrated in this review: the physico-chemical pretreatment of the biomass, the enzymatic hydrolysis of the carbohydrates to a fermentable sugar stream by cellulases and finally the fermentation of the sugars by suitable microorganisms to the target molecules. Special emphasis in this review is put on the technology, commercial status and future prospects of the production of second-generation fuel ethanol, as this process has received most research and development efforts so far. Despite significant advances, high enzyme costs are still a hurdle for large scale competitive lignocellulosic ethanol production. This could be overcome by a strategy termed 'consolidated bioprocessing' (CBP), where enzyme production, enzymatic hydrolysis and fermentation is integrated in one step - either by utilizing one genetically engineered superior microorganism or by creating an artificial co-culture. Insight is provided on both CBP strategies for the production of ethanol as well as of advanced fuels and commodity chemicals.

  3. Process Design and Economics for the Conversion of Algal Biomass to Biofuels: Algal Biomass Fractionation to Lipid- and Carbohydrate-Derived Fuel Products

    Energy Technology Data Exchange (ETDEWEB)

    Davis, R.; Kinchin, C.; Markham, J.; Tan, E.; Laurens, L.; Sexton, D.; Knorr, D.; Schoen, P.; Lukas, J.

    2014-09-01

    Beginning in 2013, NREL began transitioning from the singular focus on ethanol to a broad slate of products and conversion pathways, ultimately to establish similar benchmarking and targeting efforts. One of these pathways is the conversion of algal biomass to fuels via extraction of lipids (and potentially other components), termed the 'algal lipid upgrading' or ALU pathway. This report describes in detail one potential ALU approach based on a biochemical processing strategy to selectively recover and convert select algal biomass components to fuels, namely carbohydrates to ethanol and lipids to a renewable diesel blendstock (RDB) product. The overarching process design converts algal biomass delivered from upstream cultivation and dewatering (outside the present scope) to ethanol, RDB, and minor coproducts, using dilute-acid pretreatment, fermentation, lipid extraction, and hydrotreating.

  4. Biomass Fuel and Combustion Conditions Selection in a Fixed Bed Combustor

    Directory of Open Access Journals (Sweden)

    María E. Arce

    2013-11-01

    Full Text Available The biomass market has experienced an increase in development, leading to research and development efforts that are focused on determining optimal biofuel combustion conditions. Biomass combustion is a complex process that involves divergent parameters and thus requires the use of advanced analysis methods. This study proposes combining grey relational analysis (GRA and error propagation theory (EPT to select a biofuel and its optimal combustion conditions. This research will study three biofuels that are currently used in a region of South Europe (Spain, and the most important variables that affect combustion are the ignition front propagation speed and the highest temperature that is reached at the fixed bed combustor. The results demonstrate that a combination of both theories for the analysis of solid-state thermochemical phenomena enables a fast and simple way of choosing the best configuration for each fuel.

  5. H₂-rich syngas production by fluidized bed gasification of biomass and plastic fuel.

    Science.gov (United States)

    Ruoppolo, G; Ammendola, P; Chirone, R; Miccio, F

    2012-04-01

    This paper reports the results of gasification tests using a catalytic fluidized bed gasifier to obtain a H(2)-rich stream by feeding different pellets made of wood, biomass/plastic and olive husks to the gasifier. The effects of both the steam supply and an in-bed catalyst on gasifier performance have been investigated. In general, pelletization was an effective pre-treatment for improving the homogeneity of the fuel and the reliability of the feeding devices. The use of biomass/plastic pellets in a catalyst bed yielded good results in terms of the hydrogen concentration (up to 32%vol.), even if an increase in tar production and in the fine/carbon elutriation rate was observed in comparison with wood pellets. Copyright © 2011 Elsevier Ltd. All rights reserved.

  6. Thermodynamic Analyses of Biomass Gasification Integrated Externally Fired, Post-Firing and Dual-Fuel Combined Cycles

    Directory of Open Access Journals (Sweden)

    Saeed Soltani

    2015-01-01

    Full Text Available In the present work, the results are reported of the energy and exergy analyses of three biomass-related processes for electricity generation: the biomass gasification integrated externally fired combined cycle, the biomass gasification integrated dual-fuel combined cycle, and the biomass gasification integrated post-firing combined cycle. The energy efficiency for the biomass gasification integrated post-firing combined cycle is 3% to 6% points higher than for the other cycles. Although the efficiency of the externally fired biomass combined cycle is the lowest, it has an advantage in that it only uses biomass. The energy and exergy efficiencies are maximized for the three configurations at particular values of compressor pressure ratios, and increase with gas turbine inlet temperature. As pressure ratio increases, the mass of air per mass of steam decreases for the biomass gasification integrated post-firing combined cycle, but the pressure ratio has little influence on the ratio of mass of air per mass of steam for the other cycles. The gas turbine exergy efficiency is the highest for the three configurations. The combustion chamber for the dual-fuel cycle exhibits the highest exergy efficiency and that for the post-firing cycle the lowest. Another benefit of the biomass gasification integrated externally fired combined cycle is that it exhibits the highest air preheater and heat recovery steam generator exergy efficiencies.

  7. Energy, Environmental, and Economic Analyses of Design Concepts for the Co-Production of Fuels and Chemicals with Electricity via Co-Gasification of Coal and Biomass

    Energy Technology Data Exchange (ETDEWEB)

    Eric Larson; Robert Williams; Thomas Kreutz; Ilkka Hannula; Andrea Lanzini; Guangjian Liu

    2012-03-11

    The overall objective of this project was to quantify the energy, environmental, and economic performance of industrial facilities that would coproduce electricity and transportation fuels or chemicals from a mixture of coal and biomass via co-gasification in a single pressurized, oxygen-blown, entrained-flow gasifier, with capture and storage of CO{sub 2} (CCS). The work sought to identify plant designs with promising (Nth plant) economics, superior environmental footprints, and the potential to be deployed at scale as a means for simultaneously achieving enhanced energy security and deep reductions in U.S. GHG emissions in the coming decades. Designs included systems using primarily already-commercialized component technologies, which may have the potential for near-term deployment at scale, as well as systems incorporating some advanced technologies at various stages of R&D. All of the coproduction designs have the common attribute of producing some electricity and also of capturing CO{sub 2} for storage. For each of the co-product pairs detailed process mass and energy simulations (using Aspen Plus software) were developed for a set of alternative process configurations, on the basis of which lifecycle greenhouse gas emissions, Nth plant economic performance, and other characteristics were evaluated for each configuration. In developing each set of process configurations, focused attention was given to understanding the influence of biomass input fraction and electricity output fraction. Self-consistent evaluations were also carried out for gasification-based reference systems producing only electricity from coal, including integrated gasification combined cycle (IGCC) and integrated gasification solid-oxide fuel cell (IGFC) systems. The reason biomass is considered as a co-feed with coal in cases when gasoline or olefins are co-produced with electricity is to help reduce lifecycle greenhouse gas (GHG) emissions for these systems. Storing biomass-derived CO

  8. TASK 3.4--IMPACTS OF COFIRING BIOMASS WITH FOSSIL FUELS

    Energy Technology Data Exchange (ETDEWEB)

    Christopher J. Zygarlicke; Donald P. McCollor; Kurt E. Eylands; Melanie D. Hetland; Mark A. Musich; Charlene R. Crocker; Jonas Dahl; Stacie Laducer

    2001-08-01

    With a major worldwide effort now ongoing to reduce greenhouse gas emissions, cofiring of renewable biomass fuels at conventional coal-fired utilities is seen as one of the lower-cost options to achieve such reductions. The Energy & Environmental Research Center has undertaken a fundamental study to address the viability of cofiring biomass with coal in a pulverized coal (pc)-fired boiler for power production. Wheat straw, alfalfa stems, and hybrid poplar were selected as candidate biomass materials for blending at a 20 wt% level with an Illinois bituminous coal and an Absaloka subbituminous coal. The biomass materials were found to be easily processed by shredding and pulverizing to a size suitable for cofiring with pc in a bench-scale downfired furnace. A literature investigation was undertaken on mineral uptake and storage by plants considered for biomass cofiring in order to understand the modes of occurrence of inorganic elements in plant matter. Sixteen essential elements, C, H, O, N, P, K, Ca, Mg, S, Zn, Cu, Fe, Mn, B, Mo, and Cl, are found throughout plants. The predominant inorganic elements are K and Ca, which are essential to the function of all plant cells and will, therefore, be evenly distributed throughout the nonreproductive, aerial portions of herbaceous biomass. Some inorganic constituents, e.g., N, P, Ca, and Cl, are organically associated and incorporated into the structure of the plant. Cell vacuoles are the repository for excess ions in the plant. Minerals deposited in these ubiquitous organelles are expected to be most easily leached from dry material. Other elements may not have specific functions within the plant, but are nevertheless absorbed and fill a need, such as silica. Other elements, such as Na, are nonessential, but are deposited throughout the plant. Their concentration will depend entirely on extrinsic factors regulating their availability in the soil solution, i.e., moisture and soil content. Similarly, Cl content is determined

  9. Carbon-Increasing Catalytic Strategies for Upgrading Biomass into Energy-Intensive Fuels and Chemicals

    DEFF Research Database (Denmark)

    Li, Hu; Riisager, Anders; Saravanamurugan, Shunmugavel

    2017-01-01

    Lignocellulosic biomass is the most abundant organic carbon source and has received a great deal of interest as renewable and sustainable feedstock for the production of potential biofuels and value-added chemicals with a wide range of designed catalytic systems. However, those natural polymeric...... materials are composed of short-chain monomers (typically C6 and C5 sugars) and complex lignin molecules containing plenty of oxygen, resulting in products during the downstream processing having low-grade fuel properties or limited applications in organic syntheses. Accordingly, approaches to increase...

  10. Fischer–tropsch diesel production and evaluation as alternative automotive fuel in pilot-scale integrated biomass-to-liquid process

    International Nuclear Information System (INIS)

    Kim, Young-Doo; Yang, Chang-Won; Kim, Beom-Jong; Moon, Ji-Hong; Jeong, Jae-Yong; Jeong, Soo-Hwa; Lee, See-Hoon; Kim, Jae-Ho; Seo, Myung-Won; Lee, Sang-Bong; Kim, Jae-Kon; Lee, Uen-Do

    2016-01-01

    Highlights: • A pilot scale biomass-to-liquid (BTL) process was investigated for Fischer-Tropsch diesel production. • 200 kW th dual fluidized bed gasifier was integrated with 1 bbl/day F-T synthesis reactor. • Purified syngas satisfies minimum requirements of F-T synthesis. • F-T diesel produced successfully (1 L/h) and satisfies the automotive fuel standard. • Fully integrated BTL system was operated successfully more than 500 h. - Abstract: Fischer–Tropsch (F-T) diesel produced from biomass through gasification is a promising alternative fuel. In this study, a biomass-to-liquid (BTL) system involving a dual fluidized bed gasifier (DFBG), a methanol absorption tower, and an F-T synthesis process was investigated for producing clean biodiesel as an automotive fuel. A DFBG, which is an efficient indirect gasifier, can produce syngas with high caloric value while minimizing the amount of nitrogen in the product gas. In order to meet the strict requirements of syngas for F-T synthesis, any contaminants in the syngas must be minimized and its composition must be carefully controlled. In this work, the syngas mainly comprised 35 vol% of H 2 and 21.3 vol% of CO. The concentrations of H 2 S and COS in the syngas were less than 1 ppmV owing to the use of chilled methanol cleaning process. Furthermore, long-term operation of a fully integrated BTL system was successfully conducted for over 500 h. The results showed that the BTL diesel can be used as an alternative automotive diesel fuel.

  11. Life-Cycle Analysis of Greenhouse Gas Emissions and Water Consumption – Effects of Coal and Biomass Conversion to Liquid Fuels as Analyzed with the GREET Model

    Energy Technology Data Exchange (ETDEWEB)

    Li, Qianfeng [Argonne National Lab. (ANL), Argonne, IL (United States); Cai, Hao [Argonne National Lab. (ANL), Argonne, IL (United States); Han, Jeongwoo [Argonne National Lab. (ANL), Argonne, IL (United States)

    2017-06-01

    The vast reserves of coal in the U.S. provide a significant incentive for the development of processes for coal conversion to liquid fuels (CTL). Also, CTL using domestic coal can help move the U.S. toward greater energy independence and security. However, current conversion technologies are less economically competitive and generate greater greenhouse gas (GHG) emissions than production of petroleum fuels. Altex Technologies Corporation (Altex, hereinafter) and Pennsylvania State University have developed a hybrid technology to produce jet fuel from a feedstock blend of coal and biomass. Collaborating with Altex, Argonne National Laboratory has expanded and used the Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET®) model to assess the life-cycle GHG emissions and water consumption of this hybrid technology. Biomass feedstocks include corn stover, switchgrass, and wheat straw. The option of biomass densification (bales to pellets) is also evaluated in this study. The results show that the densification process generates additional GHG emissions as a result of additional biomass process energy demand. This process coproduces a large amount of char, and this study investigates two scenarios to treat char: landfill disposal (Char-LF) and combustion for combined heat and power (CHP). Since the CHP scenarios export excess heat and electricity as coproducts, two coproduct handling methods are used for well-to-wake (WTWa) analysis: displacement (Char-CHP-Disp) and energy allocation (Char-CHP-EnAllo). When the feedstock contains 15 wt% densified wheat straw and 85 wt% lignite coal, WTWa GHG emissions of the coal-and-biomass-to-liquid pathways are 116, 97, and 137 gCO2e per megajoule (MJ) under the Char-LF, Char-CHP-Disp, and Char-CHP-EnAllo scenarios, respectively, as compared to conventional jet fuel production at 84 gCO2e/MJ. WTWa water consumption values are 0.072, -0.046, and 0.044 gal/MJ for Char-LF, Char-CHP-Disp, and Char

  12. Hydrogenation and hydrodeoxygenation of biomass-derived oxygenates to liquid alkanes for transportation fuels

    Directory of Open Access Journals (Sweden)

    Shaohui Sun

    2018-04-01

    Full Text Available An attractive approach for the production of transportation fuels from renewable biomass resources is to convert oxygenates into alkanes. In this paper, C5–C20 alkanes formed via the hydrogenation and hydrodeoxygenation of the oligomers of furfuryl alcohol(FA can be used as gasoline, diesel and jet fuel fraction. The first step of the process is the oligomers of FA convert into hydrogenated products over Raney Ni catalyst in a batch reactor. The second step of the process converts hydrogenated products to alkanes via hydrodeoxygenation over different bi-functional catalysts include hydrogenation and acidic deoxidization active sites. After this process, the oxygen content decreased from 22.1 wt% in the oligomers of FA to 0.58 wt% in the hydrodeoxygenation products.

  13. Panorama 2007: Potential biomass mobilization for bio-fuel production worldwide, in Europe and in France

    International Nuclear Information System (INIS)

    Lorne, D.

    2007-01-01

    One key factor in ensuring the success of bio-fuel technologies, which are expected to see high growth, is the availability of biomass resources. Although the targets set in Europe and France for the replacement of petroleum products in the transport sector by 2010 can be met by converting farm surpluses into biofuels, in order to proceed further, it will be necessary to mobilize a resource that is more abundant and potentially less costly: ligno-cellulosic materials, i.e. wood or straw. The future of biofuels depends on establishing the much-awaited 'second generation' bio-fuel pathways able to convert ligno-cellulosic materials to ethanol, bio-diesel and bio-kerosene. (author)

  14. SPUTUM CYTOLOGY CULTURE HAEMATOLOGICAL CHANGES AND AIR QUALITY IN CHRONIC EXPOSURE TO SMOKE FROM BIOMASS FUEL IN RURAL AREA OF SOUTH INDIA

    OpenAIRE

    Razia Sultana; Raghu B. P; Shashidhar Buggi

    2016-01-01

    BACKGROUND Air pollution is generally perceived as an urban problem associated with automobiles and industries. However, half of the world’s population in rural areas of the developing countries is exposed to some of the highest levels of air pollution due to burning of traditional biomass fuels. In view of this, the health impact of biomass fuel use in rural India has been evaluated in this study. OBJECTIVES To analyse the mass concentration in biomass fuel user and LPG use...

  15. Coupling of anaerobic waste treatment to produce protein- and lipid-rich bacterial biomass

    Science.gov (United States)

    Steinberg, Lisa M.; Kronyak, Rachel E.; House, Christopher H.

    2017-11-01

    Future long-term manned space missions will require effective recycling of water and nutrients as part of a life support system. Biological waste treatment is less energy intensive than physicochemical treatment methods, yet anaerobic methanogenic waste treatment has been largely avoided due to slow treatment rates and safety issues concerning methane production. However, methane is generated during atmosphere regeneration on the ISS. Here we propose waste treatment via anaerobic digestion followed by methanotrophic growth of Methylococcus capsulatus to produce a protein- and lipid-rich biomass that can be directly consumed, or used to produce other high-protein food sources such as fish. To achieve more rapid methanogenic waste treatment, we built and tested a fixed-film, flow-through, anaerobic reactor to treat an ersatz wastewater. During steady-state operation, the reactor achieved a 97% chemical oxygen demand (COD) removal rate with an organic loading rate of 1740 g d-1 m-3 and a hydraulic retention time of 12.25 d. The reactor was also tested on three occasions by feeding ca. 500 g COD in less than 12 h, representing 50x the daily feeding rate, with COD removal rates ranging from 56-70%, demonstrating the ability of the reactor to respond to overfeeding events. While investigating the storage of treated reactor effluent at a pH of 12, we isolated a strain of Halomonas desiderata capable of acetate degradation under high pH conditions. We then tested the nutritional content of the alkaliphilic Halomonas desiderata strain, as well as the thermophile Thermus aquaticus, as supplemental protein and lipid sources that grow in conditions that should preclude pathogens. The M. capsulatus biomass consisted of 52% protein and 36% lipids, the H. desiderata biomass consisted of 15% protein and 7% lipids, and the Thermus aquaticus biomass consisted of 61% protein and 16% lipids. This work demonstrates the feasibility of rapid waste treatment in a compact reactor design

  16. Durability Testing of Biomass Based Oxygenated Fuel Components in a Compression Ignition Engine

    Energy Technology Data Exchange (ETDEWEB)

    Ratcliff, Matthew A [National Renewable Energy Laboratory (NREL), Golden, CO (United States); McCormick, Robert L [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Baumgardner, Marc E. [Gonzaga University; Lakshminarayanan, Arunachalam [Colorado State University; Olsen, Daniel B. [Colorado State University; Marchese, Anthony J. [Colorado State University

    2017-10-18

    Blending cellulosic biofuels with traditional petroleum-derived fuels results in transportation fuels with reduced carbon footprints. Many cellulosic fuels rely on processing methods that produce mixtures of oxygenates which must be upgraded before blending with traditional fuels. Complete oxygenate removal is energy-intensive and it is likely that such biofuel blends will necessarily contain some oxygen content to be economically viable. Previous work by our group indicated that diesel fuel blends with low levels (<4%-vol) of oxygenates resulted in minimal negative effects on short-term engine performance and emissions. However, little is known about the long-term effects of these compounds on engine durability issues such as the impact on fuel injection, in-cylinder carbon buildup, and engine oil degradation. In this study, four of the oxygenated components previously tested were blended at 4%-vol in diesel fuel and tested with a durability protocol devised for this work consisting of 200 hrs of testing in a stationary, single-cylinder, Yanmar diesel engine operating at constant load. Oil samples, injector spray patterns, and carbon buildup from the injector and cylinder surfaces were analyzed. It was found that, at the levels tested, these fuels had minimal impact on the overall engine operation, which is consistent with our previous findings.

  17. 40 CFR 80.1126 - How are RINs generated and assigned to batches of renewable fuel by renewable fuel producers or...

    Science.gov (United States)

    2010-07-01

    ... batches of renewable fuel by renewable fuel producers or importers? 80.1126 Section 80.1126 Protection of... ADDITIVES Renewable Fuel Standard § 80.1126 How are RINs generated and assigned to batches of renewable fuel by renewable fuel producers or importers? (a) Regional applicability. (1) Except as provided in...

  18. Hydrothermal Conversion in Near-Critical Water – A Sustainable Way of Producing Renewable Fuels

    DEFF Research Database (Denmark)

    Hoffmann, Jessica; Pedersen, Thomas Helmer; Rosendahl, Lasse

    2014-01-01

    Liquid fuels from biomass will form an essential part of meeting the grand challenges within energy. The need for renewable and sustainable energy sources is triggered by a number of factors; like increase in global energy demand, depletion of conventional resources, climate issues and the desire...

  19. Enhancing the properties of Fischer-Tropsch fuel produced from syngas over Co/SiO2 catalyst: Lubricity and Calorific Value

    Science.gov (United States)

    Doustdar, O.; Wyszynski, M. L.; Mahmoudi, H.; Tsolakis, A.

    2016-09-01

    Bio-fuel produced from renewable sources is considered the most viable alternatives for the replacement of mineral diesel fuel in compression ignition engines. There are several options for biomass derived fuels production involving chemical, biological and thermochemical processes. One of the best options is Fischer Tropsch Synthesis, which has an extensive history of gasoline and diesel production from coal and natural gas. FTS fuel could be one of the best solutions to the fuel emission due to its high quality. FTS experiments were carried out in 16 different operation conditions. Mini structured vertical downdraft fixed bed reactor was used for the FTS. Instead of Biomass gasification, a simulated N2 -rich syngas cylinder of, 33% H2 and 50% N2 was used. FT fuels products were analyzed in GCMS to find the hydrocarbon distributions of FT fuel. Calorific value and lubricity of liquid FT product were measured and compared with commercial diesel fuel. Lubricity has become an important quality, particularly for biodiesel, due to higher pressures in new diesel fuel injection (DFI) technology which demands better lubrication from the fuel and calorific value which is amount of energy released in combustion paly very important role in CI engines. Results show that prepared FT fuel has desirable properties and it complies with standard values. FT samples lubricities as measured by ASTM D6079 standard vary from 286μm (HFRR scar diameter) to 417μm which are less than limit of 520μm. Net Calorific value for FT fuels vary from 9.89 MJ/kg to 43.29 MJ/kg, with six of the samples less than EN 14213 limit of 35MJ/kg. Effect of reaction condition on FT fuel properties was investigated which illustrates that in higher pressure Fischer-Tropsch reaction condition liquid product has better properties.

  20. Regionalized Techno-Economic Assessment and Policy Analysis for Biomass Molded Fuel in China

    Directory of Open Access Journals (Sweden)

    Jie Xu

    2015-12-01

    Full Text Available As a relatively mature technology, biomass molded fuel (BMF is widely used in distributed and centralized heating in China and has received considerable government attention. Although many BFM incentive policies have been developed, decreased domestic traditional fuel prices in China have caused BMF to lose its economic viability and new policy recommendations are needed to stimulate this industry. The present study built a regionalized net present value (NPV model based on real production process simulation to test the impacts of each policy factor. The calculations showed that BMF production costs vary remarkably between regions, with the cost of agricultural briquette fuel (ABF ranging from 86 US dollar per metric ton (USD/t to 110 (USD/t, while that of woody pellet fuel (WPF varies from 122 USD/t to 154 USD/t. The largest part of BMF’s cost composition is feedstock, which accounts for up 50%–60% of the total; accordingly a feedstock subsidy is the most effective policy factor, but in consideration of policy implementation, it would be better to use a production subsidy. For ABF, the optimal product subsidy varies from 26 USD/t to 57 USD/t among different regions of China, while for WPF, the range is 36 USD/t to 75 USD/t. Based on the data, a regional BMF development strategy is also proposed in this study.

  1. Process integration and optimization of a solid oxide fuel cell – Gas turbine hybrid cycle fueled with hydrothermally gasified waste biomass

    International Nuclear Information System (INIS)

    Facchinetti, Emanuele; Gassner, Martin; D’Amelio, Matilde; Marechal, François; Favrat, Daniel

    2012-01-01

    Due to its suitability for using wet biomass, hydrothermal gasification is a promising process for the valorization of otherwise unused waste biomass to synthesis gas and biofuels. Solid oxide fuel cell (SOFC) based hybrid cycles are considered as the best candidate for a more efficient and clean conversion of (bio) fuels. A significant potential for the integration of the two technologies is expected since hydrothermal gasification requires heat at 673–773 K, whereas SOFC is characterized by heat excess at high temperature due to the limited electrochemical fuel conversion. This work presents a systematic process integration and optimization of a SOFC-gas turbine (GT) hybrid cycle fueled with hydrothermally gasified waste biomass. Several design options are systematically developed and compared through a thermodynamic optimization approach based on First Law and exergy analysis. The work demonstrates the considerable potential of the system that allows for converting wet waste biomass into electricity at a First Law efficiency of up to 63%, while simultaneously enabling the separation of biogenic carbon dioxide for further use or sequestration. -- Highlights: ► Hydrothermal gasification is a promising process for the valorization of waste wet biomass. ► Solid Oxide Fuel Cell – Gas Turbine hybrid cycle emerges as the best candidates for conversion of biofuels. ► A systematic process integration and optimization of a SOFC-GT hybrid cycle fuelled with hydrothermally gasified biomass is presented. ► The system may convert wet waste biomass to electricity at a First Law efficiency of 63% while separating the biogenic carbon dioxide. ► The process integration enables to improve the First Law efficiency of around 4% with respect to a non-integrated system.

  2. Transportation fuel production from gasified biomass integrated with a pulp and paper mill – Part A: Heat integration and system performance

    International Nuclear Information System (INIS)

    Isaksson, Johan; Jansson, Mikael; Åsblad, Anders; Berntsson, Thore

    2016-01-01

    Production of transportation fuels from biorefineries via biomass gasification has been suggested as a way of introducing renewable alternatives in the transportation system with an aim to reduce greenhouse gas emissions to the atmosphere. By co-locating gasification-based processes within heat demanding industries, excess heat from the gasification process can replace fossil or renewable fuels. The objective of this study was to compare the heat integration potential of four different gasification-based biorefinery concepts with a chemical pulp and paper mill. The results showed that the choice of end-product which was either methanol, Fischer-Tropsch crude, synthetic natural gas or electricity, can have significant impact on the heat integration potential with a pulp and paper mill and that the heat saving measures implemented in the mill in connection to integration of a gasification process can increase the biomass resource efficiency by up to 3%-points. Heat saving measures can reduce the necessary biomass input to the biorefinery by 50% if the sizing constraint is to replace the bark boiler with excess heat from the biorefinery. A large integrated gasification process with excess steam utilisation in a condensing turbine was beneficial only if grid electricity is produced at below 30% electrical efficiency. - Highlights: • Biomass gasification integrated with a pulp and paper mill. • Different sizing constraints of integrated biofuel production. • The biofuel product largely influence the heat integration potential. • An oversized gasifier for increased power production could be favourable.

  3. Progress and challenges in utilization of palm oil biomass as fuel for decentralized electricity generation

    Energy Technology Data Exchange (ETDEWEB)

    Bazmi, Aqeel Ahmed [Process Systems Engineering Centre (PROSPECT), Department of Chemical Engineering, Faculty of Chemical and Natural Resources Engineering, University Technology Malaysia, Skudai 81310, Johor Bahru, JB (Malaysia); Biomass Conversion Research Center (BCRC), Department of Chemical Engineering, COMSATS Institute of Information Technology, Lahore (Pakistan); Zahedi, Gholamreza; Hashim, Haslenda [Process Systems Engineering Centre (PROSPECT), Department of Chemical Engineering, Faculty of Chemical and Natural Resources Engineering, University Technology Malaysia, Skudai 81310, Johor Bahru, JB (Malaysia)

    2011-01-15

    It has been broadly accepted worldwide that global warming, indeed, is the greatest threat of the time to the environment. Renewable energy (RE) is expected as a perfect solution to reduce global warming and to endorse sustainable development. Progressive release of greenhouse gases (GHG) from increasing energy-intensive industries has eventually caused human civilization to suffer. Realizing the exigency of reducing emissions and simultaneously catering to needs of industries, researchers foresee the RE as the perfect entrant to overcome these challenges. RE provides an effective option for the provision of energy services from the technical point of view while biomass, a major source of energy in the world until before industrialization when fossil fuels become dominant, appears an important renewable source of energy and researches have proven from time to time its viability for large-scale production. Being a widely spread source, biomass offers the execution of decentralized electricity generation gaining importance in liberalized electricity markets. The decentralized power is characterized by generation of electricity nearer to the demand centers, meeting the local energy needs. Researchers envisaged an increasing decentralization of power supply, expected to make a particular contribution to climate protection. This article investigates the progress and challenges for decentralized electricity generation by palm oil biomass according to the overall concept of sustainable development. (author)

  4. Biomass production from electricity using ammonia as an electron carrier in a reverse microbial fuel cell.

    Directory of Open Access Journals (Sweden)

    Wendell O Khunjar

    Full Text Available The storage of renewable electrical energy within chemical bonds of biofuels and other chemicals is a route to decreasing petroleum usage. A critical challenge is the efficient transfer of electrons into a biological host that can covert this energy into high energy organic compounds. In this paper, we describe an approach whereby biomass is grown using energy obtained from a soluble mediator that is regenerated electrochemically. The net result is a separate-stage reverse microbial fuel cell (rMFC that fixes CO₂ into biomass using electrical energy. We selected ammonia as a low cost, abundant, safe, and soluble redox mediator that facilitated energy transfer to biomass. Nitrosomonas europaea, a chemolithoautotroph, was used as the biocatalyst due to its inherent capability to utilize ammonia as its sole energy source for growth. An electrochemical reactor was designed for the regeneration of ammonia from nitrite, and current efficiencies of 100% were achieved. Calculations indicated that overall bioproduction efficiency could approach 2.7±0.2% under optimal electrolysis conditions. The application of chemolithoautotrophy for industrial bioproduction has been largely unexplored, and results suggest that this and related rMFC platforms may enable biofuel and related biochemical production.

  5. Biomass production from electricity using ammonia as an electron carrier in a reverse microbial fuel cell.

    Science.gov (United States)

    Khunjar, Wendell O; Sahin, Asli; West, Alan C; Chandran, Kartik; Banta, Scott

    2012-01-01

    The storage of renewable electrical energy within chemical bonds of biofuels and other chemicals is a route to decreasing petroleum usage. A critical challenge is the efficient transfer of electrons into a biological host that can covert this energy into high energy organic compounds. In this paper, we describe an approach whereby biomass is grown using energy obtained from a soluble mediator that is regenerated electrochemically. The net result is a separate-stage reverse microbial fuel cell (rMFC) that fixes CO₂ into biomass using electrical energy. We selected ammonia as a low cost, abundant, safe, and soluble redox mediator that facilitated energy transfer to biomass. Nitrosomonas europaea, a chemolithoautotroph, was used as the biocatalyst due to its inherent capability to utilize ammonia as its sole energy source for growth. An electrochemical reactor was designed for the regeneration of ammonia from nitrite, and current efficiencies of 100% were achieved. Calculations indicated that overall bioproduction efficiency could approach 2.7±0.2% under optimal electrolysis conditions. The application of chemolithoautotrophy for industrial bioproduction has been largely unexplored, and results suggest that this and related rMFC platforms may enable biofuel and related biochemical production.

  6. Progress and challenges in utilization of palm oil biomass as fuel for decentralized electricity generation

    International Nuclear Information System (INIS)

    Bazmi, Aqeel Ahmed; Zahedi, Gholamreza; Hashim, Haslenda

    2011-01-01

    It has been broadly accepted worldwide that global warming, indeed, is the greatest threat of the time to the environment. Renewable energy (RE) is expected as a perfect solution to reduce global warming and to endorse sustainable development. Progressive release of greenhouse gases (GHG) from increasing energy-intensive industries has eventually caused human civilization to suffer. Realizing the exigency of reducing emissions and simultaneously catering to needs of industries, researchers foresee the RE as the perfect entrant to overcome these challenges. RE provides an effective option for the provision of energy services from the technical point of view while biomass, a major source of energy in the world until before industrialization when fossil fuels become dominant, appears an important renewable source of energy and researches have proven from time to time its viability for large-scale production. Being a widely spread source, biomass offers the execution of decentralized electricity generation gaining importance in liberalized electricity markets. The decentralized power is characterized by generation of electricity nearer to the demand centers, meeting the local energy needs. Researchers envisaged an increasing decentralization of power supply, expected to make a particular contribution to climate protection. This article investigates the progress and challenges for decentralized electricity generation by palm oil biomass according to the overall concept of sustainable development. (author)

  7. Biomass as a fuel and a profitable investment: the Euro-ASEAN COGEN program

    International Nuclear Information System (INIS)

    Menu, J.-F.; Schenkel, Y.; Guillaume, M.

    1997-01-01

    The COGEN Program (''Cogen'') is an economic cooperation program between the European Commission and ASEAN (Association of Southeast Asian Nations). A pioneering initiative in the field of biomass energy. Cogen is coordinated by and from AIT (Asian Institute of Technology, Bangkok, Thailand). Its main objective is to accelerate the implementation of proven technologies generating heat and/or power from wood and agro-residues through partnerships between European and ASEAN companies. ASEAN now offers the biggest potential for energy solutions, including waste-based fuels. Within Cogen, a number of demonstration projects have been implemented in different ASEAN industries. These projects have generated over 100 million US dollars in direct investment and represent showcases of proven technology in biomass energy equipment around the region. Some biomass energy projects have been highly profitable. The success of Cogen can also be explained by an emphasis on market intelligence, i.e., information sources, channels and business opportunities rarely achieved in public-private initiatives. (author)

  8. Cardboard/sawdust briquettes as biomass fuel: Physical-mechanical and thermal characteristics.

    Science.gov (United States)

    Lela, B; Barišić, M; Nižetić, S

    2016-01-01

    This paper elaborates experimental analysis of cardboard/sawdust briquettes as a viable option for biomass fuel. Physical-mechanical and thermal characteristics of cardboard/sawdust briquettes were investigated. The influence of the main parameters on heating content was also examined through an ANOVA and regression analysis, i.e. pressure influence (that was applied in a punch-and-die process), cardboard/sawdust ratio influence and finally drying temperature influence. In order to find the maximum heating value, minimum ash content and maximum compressive strength optimization were done. The optimal values obtained for the studied briquetting process parameters are a compression force of 588.6 kN, a sawdust mass of 46.66% and a drying temperature of 22°C. According to the mathematical model obtained, these optimal values give a maximum higher heating value of 17.41 MJ/kg, a minimum ash content of 6.62% and a maximum compressive strength of 149.54 N/mm. Finally, Cardboard/sawdust briquettes showed potential for application as viable biomass fuel. Copyright © 2015 Elsevier Ltd. All rights reserved.

  9. Methanol from biomass and hydrogen

    International Nuclear Information System (INIS)

    Anon.

    1989-01-01

    For Hawaii in the near term, the only liquid fuels indigenous sources will be those that can be made from biomass, and of these, methanol is the most promising. In addition, hydrogen produced by electrolysis can be used to markedly increase the yield of biomass methanol. This paper calculates cost of producing methanol by an integrated system including a geothermal electricity facility plus a plant producing methanol by gasifying biomass and adding hydrogen produced by electrolysis. Other studies cover methanol from biomass without added hydrogen and methanol from biomass by steam and carbon dioxide reforming. Methanol is made in a two-step process: the first is the gasification of biomass by partial oxidation with pure oxygen to produce carbon oxides and hydrogen, and the second is the reaction of gases to form methanol. Geothermal steam is used to generate the electricity used for the electrolysis to produce the added hydrogen

  10. EXPERIMENTAL STUDY OF PALM OIL MILL EFFLUENT AND OIL PALM FROND WASTE MIXTURE AS AN ALTERNATIVE BIOMASS FUEL

    Directory of Open Access Journals (Sweden)

    S. HASSAN, L. S. KEE

    2013-12-01

    Full Text Available Palm oil mill effluent (POME sludge generated from palm oil mill industry and oil palm frond (OPF from oil palm plantation are considered biomass wastes that can be fully utilized as a renewable energy sources. In this study, an attempt has been made to convert these residues into solid biomass fuel. The study was conducted by developing experimental testing on the POME and OPF mixture. The performance of each sample with different weight percentage was investigated using standard tests. The biomass mixture was converted into compressed form of briquette through a simple process. The properties of the briquettes were observed and compared at different weight percentage following standard testing methods included ultimate and proximate analyses, burning characteristics, dimensional stability and crack analysis. Experimental results showed that POME sludge and OPF mixture is feasible as an alternative biomass fuel, with briquette of 90:10 POME sludge to OPF ratio has a good combination of properties as an overall.

  11. Ambient measurements and source apportionment of fossil fuel and biomass burning black carbon in Ontario

    Science.gov (United States)

    Healy, R. M.; Sofowote, U.; Su, Y.; Debosz, J.; Noble, M.; Jeong, C.-H.; Wang, J. M.; Hilker, N.; Evans, G. J.; Doerksen, G.; Jones, K.; Munoz, A.

    2017-07-01

    Black carbon (BC) is of significant interest from a human exposure perspective but also due to its impacts as a short-lived climate pollutant. In this study, sources of BC influencing air quality in Ontario, Canada were investigated using nine concurrent Aethalometer datasets collected between June 2015 and May 2016. The sampling sites represent a mix of background and near-road locations. An optical model was used to estimate the relative contributions of fossil fuel combustion and biomass burning to ambient concentrations of BC at every site. The highest annual mean BC concentration was observed at a Toronto highway site, where vehicular traffic was found to be the dominant source. Fossil fuel combustion was the dominant contributor to ambient BC at all sites in every season, while the highest seasonal biomass burning mass contribution (35%) was observed in the winter at a background site with minimal traffic contributions. The mass absorption cross-section of BC was also investigated at two sites, where concurrent thermal/optical elemental carbon data were available, and was found to be similar at both locations. These results are expected to be useful for comparing the optical properties of BC at other near-road environments globally. A strong seasonal dependence was observed for fossil fuel BC at every Ontario site, with mean summer mass concentrations higher than their respective mean winter mass concentrations by up to a factor of two. An increased influence from transboundary fossil fuel BC emissions originating in Michigan, Ohio, Pennsylvania and New York was identified for the summer months. The findings reported here indicate that BC should not be considered as an exclusively local pollutant in future air quality policy decisions. The highest seasonal difference was observed at the highway site, however, suggesting that changes in fuel composition may also play an important role in the seasonality of BC mass concentrations in the near-road environment

  12. Integration of heterogeneous and biochemical catalysis for production of fuels and chemicals from biomass.

    Science.gov (United States)

    Wheeldon, Ian; Christopher, Phillip; Blanch, Harvey

    2017-06-01

    The past decade has seen significant government and private investment in fundamental research and process development for the production of biofuels and chemicals from lignocellulosic biomass-derived sugars. This investment has helped create new metabolic engineering and synthetic biology approaches, novel homogeneous and heterogeneous catalysts, and chemical and biological routes that convert sugars, lignin, and waste products such as glycerol into hydrocarbon fuels and valuable chemicals. With the exception of ethanol, economical biofuels processes have yet to be realized. A potentially viable way forward is the integration of biological and chemical catalysis into processes that exploit the inherent advantages of each technology while circumventing their disadvantages. Microbial fermentation excels at converting sugars from low-cost raw materials streams into simple alcohols, acids, and other reactive intermediates that can be condensed into highly reduced, long and branched chain hydrocarbons and other industrially useful compounds. Chemical catalysis most often requires clean feed streams to avoid catalyst deactivation, but the chemical and petroleum industries have developed large scale processes for C-C coupling, hydrogenation, and deoxygenation that are driven by low grade heat and low-cost feeds such as hydrogen derived from natural gas. In this context, we suggest that there is a reasonably clear route to the high yield synthesis of biofuels from biomass- or otherwise derived-fermentable sugars: the microbial production of reactive intermediates that can be extracted or separated into clean feed stream for upgrading by chemical catalysis. When coupled with new metabolic engineering strategies that maximize carbon and energy yields during fermentation, biomass-to-fuels processes may yet be realized. Copyright © 2017 Elsevier Ltd. All rights reserved.

  13. SPUTUM CYTOLOGY CULTURE HAEMATOLOGICAL CHANGES AND AIR QUALITY IN CHRONIC EXPOSURE TO SMOKE FROM BIOMASS FUEL IN RURAL AREA OF SOUTH INDIA

    Directory of Open Access Journals (Sweden)

    Razia Sultana

    2016-08-01

    Full Text Available BACKGROUND Air pollution is generally perceived as an urban problem associated with automobiles and industries. However, half of the world’s population in rural areas of the developing countries is exposed to some of the highest levels of air pollution due to burning of traditional biomass fuels. In view of this, the health impact of biomass fuel use in rural India has been evaluated in this study. OBJECTIVES To analyse the mass concentration in biomass fuel user and LPG user household and to investigate the effects of biomass smoke exposure in a group of rural women who cook regularly with biomass fuels and compare the results obtained from control group women who cook relatively cleaner fuel, liquefied petroleum gas (LPG. METHODS Respiratory health was evaluated from Questionnaire survey, Clinical examination, haematology, sputum cytology culture and serum C-reactive protein (CRP levels are investigated in biomass and control users. RESULTS A total of 150 women were approached, of which only 70 non-smoking women without any history of any major chronic illness in the past were selected for this study. CRP levels differ significantly in biomass exposure than control users. CONCLUSION From our study it is clear that with increasing duration of exposure to biomass fuel combustion. Women who used to cook with traditional biomass fuels had low haemoglobin & Red Blood Cells values, increased neutrophil and allergic manifestations. Sputum cytology of majority biomass users revealed bacterial infections & chronic inflammation.

  14. Enzymatic hydrolysis of lignocellulosic biomass by Kitasatospora sp. to produce xylo-oligosaccharides (XOS)

    Science.gov (United States)

    Rahmani, Nanik; Jannah, Alifah Mafatikhul; Lisdiyanti, Puspita; Prasetya, Bambang; Yopi

    2017-11-01

    The optimizations of enzymatic hydrolysis to produce of xylo-oligosaccharides (XOs) from three different lignocellulosic biomasses were investigated. Sugarcane bagasse, oil palm empty fruit bunch, and rice straw contain rich hemicelluloses especially hetero-xylan which can be hydrolyzes by endo-xylanase enzyme. Enzymatic hydrolysis of sugarcane bagasse by endo-xylanase from Kitasatospora sp. was optimum at temperature hydrolysis 30 °C using 16 U of enzyme concentrations and 4 % substrate concentrations, while oil palm empty fruit bunchwas optimum at temperature hydrolysis 30 °C using 16 U of enzyme concentrations and 5 % substrate concentrations, and rice straw was optimum at 40 °C temperature hydrolysis using 16 U of enzyme concentrations and 4 % substrate concentrations. The hydrolysis products were analyzed by TLC and HPLC. The main product hydrolysis for sugarcane bagasse, oil palm empty fruit bunch and rice straw are xylobiose.

  15. Olivine, dolomite and ceramic filters in one vessel to produce clean gas from biomass.

    Science.gov (United States)

    Rapagnà, Sergio; Gallucci, Katia; Foscolo, Pier Ugo

    2018-01-01

    Heavy organic compounds produced during almond shells gasification in a steam and/or air atmosphere, usually called tar, are drastically reduced in the product gas by using simultaneously in one vessel a ceramic filter placed in the freeboard and a mixture of olivine and dolomite particles in the fluidized bed of the gasifier. The content of tar in the product gas during a reference gasification test with air, in presence of fresh olivine particles only, was 8600mg/Nm 3 of dry gas. By gasifying biomass with steam at the same temperature level of 820°C in a bed of olivine and dolomite (20% by weight), and in the presence of a catalytic ceramic filter inserted in the freeboard of the fluidized bed gasifier, the level of tar was brought down to 57mg/Nm 3 of dry producct gas, with a decrease of more than two orders of magnitude. Copyright © 2017 Elsevier Ltd. All rights reserved.

  16. Internal curing with lightweight aggregate produced from biomass-derived waste

    International Nuclear Information System (INIS)

    Lura, Pietro; Wyrzykowski, Mateusz; Tang, Clarence; Lehmann, Eberhard

    2014-01-01

    Shrinkage of concrete may lead to cracking and ultimately to a reduction of the service life of concrete structures. Among known methods for shrinkage mitigation, internal curing with porous aggregates was successfully utilized in the last couple of decades for decreasing autogenous and drying shrinkage. In this paper, the internal curing performance of pre-saturated lightweight aggregates produced from biomass-derived waste (bio-LWA) was studied. In the first part of this paper, the microstructure of the bio-LWA is investigated, with special focus on their pore structure and on their water absorption and desorption behavior. The bio-LWA has large porosity and coarse pore structure, which allows them to release the entrained water at early age and counteract self-desiccation and autogenous shrinkage. In the second part, the efficiency of internal curing in mortars incorporating the bio-LWA is examined by neutron tomography, internal relative humidity and autogenous deformation measurements

  17. Foliage and Grass as Fuel Pellets–Small Scale Combustion of Washed and Mechanically Leached Biomass

    Directory of Open Access Journals (Sweden)

    Jan Hari Arti Khalsa

    2016-05-01

    Full Text Available The high contents of disadvantageous elements contained in non-woody biomass are known to cause problems during small and large scale combustion, typically resulting in a higher risk of slagging, corrosion, and increased emissions. Mechanically leaching the respective elements from the biomass through a sequence of process steps has proven to be a promising solution.The florafuel process used here is comprised of size reduction followed by washing and subsequent mechanical dewatering of the biomass. Densification of the upgraded biomass into standardized pellets (Ø 6mm enables an application in existing small-scale boilers. The presented combustion trials investigated the performance of pellets made from leached grass, foliage and a mixture of both in two small-scale boilers (<100 kWth with slightly different technology (moving grate versus water-cooled burner tube during a 4-h measurement period. Emissions were in accordance with German emissions standards except for NOx (threshold is 0.50 g/m3 in the case of pure grass pellets (0.51 g/m3 and particulate matter (PM in all but one case (foliage, 13–16 mg/m3. An electrostatic precipitator (ESP unit installed with one of the boilers successfully reduced PM emission of both the grass and mixture fuel below the threshold of 20 mg/m3 (all emission values refer to 13 vol.% O2, at standard temperature and pressure (STP. Bottom ash composition and grate temperature profiles were analyzed and discussed for one of the boilers.

  18. Low Emissions Burner Technology for Metal Processing Industry using Byproducts and Biomass Derived Liquid Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Agrawal, Ajay; Taylor, Robert

    2013-09-30

    This research and development efforts produced low-emission burner technology capable of operating on natural gas as well as crude glycerin and/or fatty acids generated in biodiesel plants. The research was conducted in three stages (1) Concept definition leading to the design and development of a small laboratory scale burner, (2) Scale-up to prototype burner design and development, and (3) Technology demonstration with field vefiication. The burner design relies upon the Flow Blurring (FB) fuel injection based on aerodynamically creating two-phase flow near the injector exit. The fuel tube and discharge orifice both of inside diameter D are separated by gap H. For H < 0.25D, the atomizing air bubbles into liquid fuel to create a two-phase flow near the tip of the fuel tube. Pressurized two-phase fuel-air mixture exits through the discharge orifice, which results in expansion and breakup of air bubbles yielding a spray with fine droplets. First, low-emission combustion of diesel, biodiesel and straight VO (soybean oil) was achieved by utilizing FB injector to yield fine sprays for these fuels with significantly different physical properties. Visual images for these baseline experiments conducted with heat release rate (HRR) of about 8 kW illustrate clean blue flames indicating premixed combustion for all three fuels. Radial profiles of the product gas temperature at the combustor exit overlap each other signifying that the combustion efficiency is independent of the fuel. At the combustor exit, the NOx emissions are within the measurement uncertainties, while CO emissions are slightly higher for straight VO as compared to diesel and biodiesel. Considering the large variations in physical and chemical properties of fuels considered, the small differences observed in CO and NOx emissions show promise for fuel-flexible, clean combustion systems. FB injector has proven to be very effective in atomizing fuels with very different physical properties, and it offers a

  19. Investigation of Acute Pulmonary Deficits Associated with Biomass Fuel Cookstove Emissions in Rural Bangladesh

    Directory of Open Access Journals (Sweden)

    Danielle N. Medgyesi

    2017-06-01

    Full Text Available The use of solid biomass fuels in cookstoves has been associated with chronic health impacts that disproportionately affect women worldwide. Solid fuel stoves that use wood, plant matter, and cow dung are commonly used for household cooking in rural Bangladesh. This study investigates the immediate effects of acute elevated cookstove emission exposures on pulmonary function. Pulmonary function was measured with spirometry before and during cooking to assess changes in respiratory function during exposure to cookstove emissions for 15 females ages 18–65. Cookstove emissions were characterized using continuous measurements of particulate matter (PM2.5—aerodynamic diameter <2.5 μm concentrations at a 1 s time resolution for each household. Several case studies were observed where women ≥40 years who had been cooking for ≥25 years suffered from severe pulmonary impairment. Forced expiratory volume in one second over forced vital capacity (FEV1/FVC was found to moderately decline (p = 0.06 during cooking versus non-cooking in the study cohort. The study found a significant (α < 0.05 negative association between 3- and 10-min maximum PM2.5 emissions during cooking and lung function measurements of forced vital capacity (FVC, forced expiratory volume in one second (FEV1, and FEV1/FVC obtained during cooking intervals. This study found that exposure to biomass burning emissions from solid fuel stoves- associated with acute elevated PM2.5 concentrations- leads to a decrease in pulmonary function, although further research is needed to ascertain the prolonged (e.g., daily, for multiple years impacts of acute PM2.5 exposure on immediate and sustained respiratory impairment.

  20. Method for producing ethanol and co-products from cellulosic biomass

    Science.gov (United States)

    Nguyen, Quang A

    2013-10-01

    The present invention generally relates to processes for production of ethanol from cellulosic biomass. The present invention also relates to production of various co-products of preparation of ethanol from cellulosic biomass. The present invention further relates to improvements in one or more aspects of preparation of ethanol from cellulosic biomass including, for example, improved methods for cleaning biomass feedstocks, improved acid impregnation, and improved steam treatment, or "steam explosion."

  1. Thermochemical production of liquid fuels from biomass: Thermo-economic modeling, process design and process integration analysis

    International Nuclear Information System (INIS)

    Tock, Laurence; Gassner, Martin; Marechal, Francois

    2010-01-01

    A detailed thermo-economic model combining thermodynamics with economic analysis and considering different technological alternatives for the thermochemical production of liquid fuels from lignocellulosic biomass is presented. Energetic and economic models for the production of Fischer-Tropsch fuel (FT), methanol (MeOH) and dimethyl ether (DME) by means of biomass drying with steam or flue gas, directly or indirectly heated fluidized bed or entrained flow gasification, hot or cold gas cleaning, fuel synthesis and upgrading are reviewed and developed. The process is integrated and the optimal utility system is computed. The competitiveness of the different process options is compared systematically with regard to energetic, economic and environmental considerations. At several examples, it is highlighted that process integration is a key element that allows for considerably increasing the performance by optimal utility integration and energy conversion. The performance computations of some exemplary technology scenarios of integrated plants yield overall energy efficiencies of 59.8% (crude FT-fuel), 52.5% (MeOH) and 53.5% (DME), and production costs of 89, 128 and 113 Euro MWh -1 on fuel basis. The applied process design approach allows to evaluate the economic competitiveness compared to fossil fuels, to study the influence of the biomass and electricity price and to project for different plant capacities. Process integration reveals in particular potential energy savings and waste heat valorization. Based on this work, the most promising options for the polygeneration of fuel, power and heat will be determined in a future thermo-economic optimization.

  2. A FEASIBILITY STUDY FOR THE COPROCESSING OF FOSSIL FUELS WITH BIOMASS BY THE HYDROCARB PROCESS

    Science.gov (United States)

    The report describes and gives results of an assessment of a new process concept for the production of carbon and methanol from fossil fuels. The Hydrocarb Process consists of the hydrogasification of carbonaceous material to produce methane, which is subsequently thermally decom...

  3. Study of the biomass potential that can be used for producing biogas in Burkina Faso

    International Nuclear Information System (INIS)

    1998-10-01

    The introduction of biogas to Burkina Faso was done in 1976 through program of research and development. Agricultural and Animal waste is the principal substrates and the produced gas is useful principally to satisfy the domestic energy needs. The technological outputs go from 200 has 300 liters per m 3 of tank whereas the biological outputs are of 100 has 300 liters per kilogram of dry matter. The cost of the installations vary from 12000 to 100000 Fcfa per m 3 of tank according to the type of digester. In August 1998, only the installation of biogas of the School of Water and Drill of Dinderesso (Bobo-Dioulasso) produced biogas. According to the estimates, Burkina Faso respectively has an annual average potential of production theoretical and accessible about 4694 million and 2790 million m 3 of biogas coming by order from importance from livestock wastes, farming, human and urban. By taking a coefficient of 60% to take account of the imperfections of technology and implementation, 1674 million m 3 of biogas (accessible) could have been produced from the biomass over the period 1990-1996. For the same period, this quantity of biogas could have generated annually 2000 to 2344 GWh of electricity (cogeneration) against 218 GWh for the SONABEL [fr

  4. Holistic analysis of thermochemical processes by using solid biomass for fuel production in Germany

    International Nuclear Information System (INIS)

    Henssler, Martin

    2015-01-01

    According to the German act ''Biokraftstoff-Nachhaltigkeitsverordnung'', biofuels must show a CO 2eq -reduction compared to the fossil reference fuel (83.8 g CO 2eq /MJ fuel /Richtlinie 98/70/EG/) of 35 % beginning with 2011. In new plants, which go into operation after the 31.12.2016 the CO 2eq -savings must be higher than 50 % in 2017 and higher than 60 % in 2018 /Biokraft-NachV/. The biofuels (methyl ester of rapeseed, bioethanol and biomethane) considered in this study do not meet these requirements for new plants. To comply with these rules new processes must be deployed. Alternative thermochemical generated fuels could be an option. The aim of this work is to evaluate through a technical, ecological and economic analysis (Well-to-Wheel) whether and under what conditions the thermochemical production of Fischer-Tropsch-diesel or -gasoline, hydrogen (H 2 ) and Substitute Natural Gas (SNG) complies with the targets. Four different processes are considered (fast pyrolysis and torrefaction with entrained flow gasifier, CHOREN Carbo-V registered -gasifier, Absorption Enhanced Reforming (AER-) gasifier). Beside residues such as winter wheat straw and residual forest wood, wood from short-rotation plantations is taken into account. The technical analysis showed that at present status (2010) two and in 2050 six plants can be operated energy-self-sufficient. The overall efficiency of the processes is in the range of 41.5 (Fischer-Tropsch-diesel or -gasoline) and 59.4 % (H 2 ). Furthermore, it was found that for 2010, all thermochemical produced fuels except the H 2 -production from wood from short-rotation plantations in decentralised or central fast pyrolysis and in decentralised torrefactions with entrained flow gasifier keep the required CO 2eq -saving of 60 %. In 2050, all thermochemical produced fuels will reach these limits. The CO 2eq -saving is between 72 (H 2 ) and 95 % (Fischer-Tropsch-diesel or -gasoline). When the production costs of the

  5. Effect of indoor air pollution from biomass and solid fuel combustion on symptoms of preeclampsia/eclampsia in Indian women.

    Science.gov (United States)

    Agrawal, S; Yamamoto, S

    2015-06-01

    Available evidence concerning the association between indoor air pollution (IAP) from biomass and solid fuel combustion and preeclampsia/eclampsia is not available in developing countries. We investigated the association between exposure to IAP from biomass and solid fuel combustion and symptoms of preeclampsia/eclampsia in Indian women by analyzing cross-sectional data from India's third National Family Health Survey (NFHS-3, 2005-2006). Self-reported symptoms of preeclampsia/eclampsia during pregnancy such as convulsions (not from fever), swelling of legs, body or face, excessive fatigue or vision difficulty during daylight, were obtained from 39,657 women aged 15-49 years who had a live birth in the previous 5 years. Effects of exposure to cooking smoke, ascertained by type of fuel used for cooking on preeclampsia/eclampsia risk, were estimated using logistic regression after adjusting for various confounders. Results indicate that women living in households using biomass and solid fuels have two times higher likelihood of reporting preeclampsia/eclampsia symptoms than do those living in households using cleaner fuels (OR = 2.21; 95%: 1.26-3.87; P = 0.006), even after controlling for the effects of a number of potentially confounding factors. This study is the first to empirically estimate the associations of IAP from biomass and solid fuel combustion and reported symptoms suggestive of preeclampsia/eclampsia in a large nationally representative sample of Indian women and we observed increased risk. These findings have important program and policy implications for countries such as India, where large proportions of the population rely on polluting biomass fuels for cooking and space heating. More epidemiological research with detailed exposure assessments and clinical measures of preeclampsia/eclampsia is needed in a developing country setting to validate these findings. © 2014 The Authors. Indoor Air published by John Wiley & Sons Ltd.

  6. Impact assessment of biomass-based district heating systems in densely populated communities. Part II: Would the replacement of fossil fuels improve ambient air quality and human health?

    Science.gov (United States)

    Petrov, Olga; Bi, Xiaotao; Lau, Anthony

    2017-07-01

    To determine if replacing fossil fuel combustion with biomass gasification would impact air quality, we evaluated the impact of a small-scale biomass gasification plant (BRDF) at a university campus over 5 scenarios. The overall incremental contribution of fine particles (PM2.5) is found to be at least one order of magnitude lower than the provincial air quality objectives. The maximum PM2.5 emission from the natural gas fueled power house (PH) could adversely add to the already high background concentration levels. Nitrogen dioxide (NO2) emissions from the BRDF with no engineered pollution controls for NOx in place exceeded the provincial objective in all seasons except during summer. The impact score, IS, was the highest for NO2 (677 Disability Adjusted Life Years, DALY) when biomass entirely replaced fossil fuels, and the highest for PM2.5 (64 DALY) and CO (3 DALY) if all energy was produced by natural gas at PH. Complete replacement of fossil fuels by one biomass plant can result in almost 28% higher health impacts (708 DALY) compared to 513 DALY when both the current BRDF and the PH are operational mostly due to uncontrolled NO2 emissions. Observations from this study inform academic community, city planners, policy makers and technology developers on the impacts of community district heating systems and possible mitigation strategies: a) community energy demand could be met either by splitting emissions into more than one source at different locations and different fuel types or by a single source with the least-impact-based location selection criteria with biomass as a fuel; b) advanced high-efficiency pollution control devices are essential to lower emissions for emission sources located in a densely populated community; c) a spatial and temporal impact assessment should be performed in developing bioenergy-based district heating systems, in which the capital and operational costs should be balanced with not only the benefit to greenhouse gas emission

  7. Natural Gas and Cellulosic Biomass: A Clean Fuel Combination? Determining the Natural Gas Blending Wall in Biofuel Production.

    Science.gov (United States)

    M Wright, Mark; Seifkar, Navid; Green, William H; Román-Leshkov, Yuriy

    2015-07-07

    Natural gas has the potential to increase the biofuel production output by combining gas- and biomass-to-liquids (GBTL) processes followed by naphtha and diesel fuel synthesis via Fischer-Tropsch (FT). This study reflects on the use of commercial-ready configurations of GBTL technologies and the environmental impact of enhancing biofuels with natural gas. The autothermal and steam-methane reforming processes for natural gas conversion and the gasification of biomass for FT fuel synthesis are modeled to estimate system well-to-wheel emissions and compare them to limits established by U.S. renewable fuel mandates. We show that natural gas can enhance FT biofuel production by reducing the need for water-gas shift (WGS) of biomass-derived syngas to achieve appropriate H2/CO ratios. Specifically, fuel yields are increased from less than 60 gallons per ton to over 100 gallons per ton with increasing natural gas input. However, GBTL facilities would need to limit natural gas use to less than 19.1% on a LHV energy basis (7.83 wt %) to avoid exceeding the emissions limits established by the Renewable Fuels Standard (RFS2) for clean, advanced biofuels. This effectively constitutes a blending limit that constrains the use of natural gas for enhancing the biomass-to-liquids (BTL) process.

  8. Fuels production by the thermochemical transformation of the biomass; La production de carburants par transformation thermochimique de la biomasse

    Energy Technology Data Exchange (ETDEWEB)

    Claudet, G. [CEA, 75 - Paris (France)

    2005-07-01

    The biomass is a local and renewable energy source, presenting many advantages. This paper proposes to examine the biomass potential in France, the energy valorization channels (thermochemical chains of thermolysis and gasification) with a special interest for the hydrogen production and the research programs oriented towards the agriculture and the forest. (A.L.B.)

  9. Hydrogen from biomass gas steam reforming for low temperature fuel cell: energy and exergy analysis

    Directory of Open Access Journals (Sweden)

    A. Sordi

    2009-03-01

    Full Text Available This work presents a method to analyze hydrogen production by biomass gasification, as well as electric power generation in small scale fuel cells. The proposed methodology is the thermodynamic modeling of a reaction system for the conversion of methane and carbon monoxide (steam reforming, as well as the energy balance of gaseous flow purification in PSA (Pressure Swing Adsorption is used with eight types of gasification gases in this study. The electric power is generated by electrochemical hydrogen conversion in fuel cell type PEMFC (Proton Exchange Membrane Fuel Cell. Energy and exergy analyses are applied to evaluate the performance of the system model. The simulation demonstrates that hydrogen production varies with the operation temperature of the reforming reactor and with the composition of the gas mixture. The maximum H2 mole fraction (0.6-0.64 mol.mol-1 and exergetic efficiency of 91- 92.5% for the reforming reactor are achieved when gas mixtures of higher quality such as: GGAS2, GGAS4 and GGAS5 are used. The use of those gas mixtures for electric power generation results in lower irreversibility and higher exergetic efficiency of 30-30.5%.

  10. Characterization and Production of Fuel Briquettes Made from Biomass and Plastic Wastes

    Directory of Open Access Journals (Sweden)

    Maria Angeles Garrido

    2017-06-01

    Full Text Available In this study, the physical properties of briquettes produced from two different biomass feedstocks (sawdust and date palm trunk and different plastic wastes, without using any external binding agent, were investigated. The biomass feedstocks were blended with different ratios of two waste from electrical and electronic equipment (WEEE plastics (halogen-free wire and printed circuit boards (PCBs and automotive shredder residues (ASR. The briquettes production is studied at different waste proportions (10–30%, pressures (22–67 MPa and temperatures (room–130 °C. Physical properties as density and durability rating were measured, usually increasing with temperature. Palm trunk gave better results than sawdust in most cases, due to its moisture content and the extremely fine particles that are easily obtained.

  11. Integrating Wind And Solar With Hydrogen Producing Fuel Cells

    NARCIS (Netherlands)

    Hemmes, K.

    2007-01-01

    The often proposed solution for the fluctuating wind energy supply is the conversion of the surplus of wind energy into hydrogen by means of electrolysis. In this paper a patented alternative is proposed consisting of the integration of wind turbines with internal reforming fuel-cells, capable of

  12. Energy Characterization and Gasification of Biomass Derived by Hazelnut Cultivation: Analysis of Produced Syngas by Gas Chromatography

    OpenAIRE

    D. Monarca; A. Colantoni; M. Cecchini; L. Longo; L. Vecchione; M. Carlini; A. Manzo

    2012-01-01

    Modern agriculture is an extremely energy intensive process. However, high agricultural productivities and the growth of green revolution has been possible only by large amount of energy inputs, especially those coming from fossil fuels. These energy resources have not been able to provide an economically viable solution for agricultural applications. Biomass energy-based systems had been extensively used for transportation and on farm systems during World War II: the most common and reliable...

  13. Comparison of PM emissions from a commercial jet engine burning conventional, biomass, and Fischer-Tropsch fuels.

    Science.gov (United States)

    Lobo, Prem; Hagen, Donald E; Whitefield, Philip D

    2011-12-15

    Rising fuel costs, an increasing desire to enhance security of energy supply, and potential environmental benefits have driven research into alternative renewable fuels for commercial aviation applications. This paper reports the results of the first measurements of particulate matter (PM) emissions from a CFM56-7B commercial jet engine burning conventional and alternative biomass- and, Fischer-Tropsch (F-T)-based fuels. PM emissions reductions are observed with all fuels and blends when compared to the emissions from a reference conventional fuel, Jet A1, and are attributed to fuel properties associated with the fuels and blends studied. Although the alternative fuel candidates studied in this campaign offer the potential for large PM emissions reductions, with the exception of the 50% blend of F-T fuel, they do not meet current standards for aviation fuel and thus cannot be considered as certified replacement fuels. Over the ICAO Landing Takeoff Cycle, which is intended to simulate aircraft engine operations that affect local air quality, the overall PM number-based emissions for the 50% blend of F-T fuel were reduced by 34 ± 7%, and the mass-based emissions were reduced by 39 ± 7%.

  14. Energy and climate impacts of producing synthetic hydrocarbon fuels from CO(2).

    Science.gov (United States)

    van der Giesen, Coen; Kleijn, René; Kramer, Gert Jan

    2014-06-17

    Within the context of carbon dioxide (CO2) utilization there is an increasing interest in using CO2 as a resource to produce sustainable liquid hydrocarbon fuels. When these fuels are produced by solely using solar energy they are labeled as solar fuels. In the recent discourse on solar fuels intuitive arguments are used to support the prospects of these fuels. This paper takes a quantitative approach to investigate some of the claims made in this discussion. We analyze the life cycle performance of various classes of solar fuel processes using different primary energy and CO2 sources. We compare their efficacy with respect to carbon mitigation with ubiquitous fossil-based fuels and conclude that producing liquid hydrocarbon fuels starting from CO2 by using existing technologies requires much more energy than existing fuels. An improvement in life cycle CO2 emissions is only found when solar energy and atmospheric CO2 are used. Producing fuels from CO2 is a very long-term niche at best, not the panacea suggested in the recent public discourse.

  15. Refining Bio-Gas Produced from Biomass: An Alternative to Cooking Gas

    Directory of Open Access Journals (Sweden)

    A. S. ABDULKAREEM

    2005-06-01

    Full Text Available Our life is completely dependent on a reliable and adequate supply of energy. In other to reduce dependence on fossil fuels, the use of animal dung in producing a renewable alternative source of energy has been proved using cow dung. This work is aimed at produced and refined bio - gas from animal dung by reduces the H2S and CO2 content of bio - gas in other to improved the quality of the bio - gas to be used as an alternative to the petroleum based produces in use now. The sample of gas produced was passed through the gas chromatography to determine the percentage composition (mol % dry basis of the bio - gas contents. The results of the bio - gas before refinement were 54.09% mole dry CH4, 40.02mole % dry CO2 and 0.80mole % dry H2S which conformed with the literature values of 50 - 65 % mole dry CH4, 35 - 50 % mole dry CO2 and 0.1 - 1.0 % mole dry H2S. After refining, the composition of bio - gas on dry basis were 54.09% mole dry CH4, 4.01% mole dry CO2, 0.02% mole dry O2, 0.05% mole dry NH3, 0.01% mole dry H2S, 0.5% mole dry H2 and 2.54% mole dry N2. Analysis of the remnant indicated that it could be used for plant nutrient.

  16. Psychrophilic Biomass Producers in the Trophic Chain of the Microbial Community of Lake Untersee, Antarctica

    Science.gov (United States)

    Pikuta, Elena V.; Hoover, Richard B.

    2010-01-01

    The study of photosynthetic microorganisms from the Lake Untersee samples showed dispersed distribution of phototrophs within 80 m water column. Lake Untersee represents a unique ecosystem that experienced complete isolation: sealed by the Anuchin Glacier for many millennia. Consequently, its biocenosis has evolved over a significant period of time without exchange or external interaction with species from other environments. The major producers of organic matter in Lake Untersee are represented by phototrophic and chemolithotrophic microorganisms. This is the traditional trophic scheme for lacustrine ecosystems on Earth. Among the phototrophs, diatoms were not found, which differentiates this lake from other known ecosystems. The dominant species among phototrophs was Chlamydomonas sp. with typical morphostructure: green chloroplasts, bright red round spot, and two polar flagella near the opening. As expected, the physiology of studied phototrophs was limited by low temperature, which defined them as obligate psychrophilic microorganisms. By the quantity estimation of methanogenesis in this lake, the litho-autotrophic production of organic matter is competitive with phototrophic production. However, pure cultures of methanogens have not yet been obtained. We discuss the primary producers of organic matter and the participation of our novel psychrophilic homoacetogen into the litho-autotrophic link of biomass production in Lake Untersee.

  17. Hydrogen Fuel Cell Vehicles

    OpenAIRE

    Delucchi, Mark

    1992-01-01

    Hydrogen is an especially attractive transportation fuel. It is the least polluting fuel available, and can be produced anywhere there is water and a clean source of electricity. A fuel cycle in which hydrogen is produced by solar-electrolysis of water, or by gasification of renewably grown biomass, and then used in a fuel-cell powered electric-motor vehicle (FCEV), would produce little or no local, regional, or global pollution. Hydrogen FCEVs would combine the best features of bat...

  18. Evaluation of the potential of pelletized biomass from different municipal solid wastes for use as solid fuel.

    Science.gov (United States)

    Wang, Ting; Li, Yuening; Zhang, Jing; Zhao, Jingbo; Liu, Yan; Sun, Luna; Liu, Boyang; Mao, Hongjun; Lin, Yingchao; Li, Weizun; Ju, Meiting; Zhu, Fudong

    2018-04-01

    Four different municipal solid wastes (dog manure, horse manure, apple pomace waste and tea waste) and an industrial by-product (NovoGro) were used to produce solid fuel pellets. The mixtures followed a raw material to NovoGro ratio of 50:1. The pellets diameters varied between 4 and 5 mm, and the average length was 20 mm. The dog manure, horse manure, apple pomace waste and tea waste pellets were denoted as DN, HN, AN and TN, respectively. The combustion characteristics of the pelletized fuels were investigated, such as total moisture, ash content, calorific value and ash fusion point, etc. The physicochemical properties were analyzed by using a number of analytical techniques including X-ray fluorescence spectrometry (XRF), X-ray diffraction spectrometry (XRD), scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR). The results of the mechanical, thermal and morphological properties show that the raw materials were effectively combined with the NovoGro binder; furthermore, the DN, HN and TN pellets exhibited excellent mechanical and thermal properties, including high calorific values (>16.30 MJ/kg), high resistance to mechanical shock (>99%), high volatile matter contents, optimal softening temperatures and optimal ash contents. However, the high K, Ca, and Si contents of the AN can form low-melting-point eutectics, which can cause slagging. Moreover, the AN materials had large particle sizes, and high cellulose and hemicellulose contents led to high total moistures, low softening temperatures and low calorific values. The AN was not suitable for use as a fuel. The results suggested that NG is an effective binder for pelletization of biomass and showed the feasibility of using municipal solid wastes for energy production. Copyright © 2017 Elsevier Ltd. All rights reserved.

  19. Environmental profile of ethanol from poplar biomass as transport fuel in Southern Europe

    International Nuclear Information System (INIS)

    Gonzalez-Garcia, Sara; Moreira, M. Teresa; Feijoo, Gumersindo; Gasol, Carles M.; Gabarrell, Xavier; Rieradevall, Joan

    2010-01-01

    Liquid biofuels provide one of the few options for fossil fuel substitution in the short to medium-term and they are strongly being promoted by the European Union as transport fuel (such as ethanol) since they have the potential to offer both greenhouse gas (GHG) savings and energy security. A ''well to wheel'' analysis has been conducted for poplar based ethanol by means of the Life Cycle Assessment (LCA) approach. The aim of the analysis is to assess the environmental performance of three ethanol applications (E10, E85 and E100) in comparison with conventional gasoline. To compare the environmental profiles, the study addressed the impact potentials per kilometre driven by a middle size passenger car, taking into account the performance difference between ethanol blends and gasoline. According to the results of this study, fuel ethanol derived from poplar biomass may help to reduce the contributions to global warming, abiotic resources depletion and ozone layer depletion up to 62%, 72% and 36% respectively. Reductions of fossil fuel extraction of up to 80% could be achieved when pure ethanol is used. On the contrary, contributions to other impact categories would be increased, specifically to acidification and eutrophication. In both categories, ethanol based blends are less environmentally friendly than conventional gasoline due to the higher impact from the upstream activities. Research focussed on the reduction of the environmental impacts should be pointed forward poplar cultivation as well as ethanol conversion plant (enzyme manufacturing, energy production and distillation). In this study poplar cultivation was really intensive in order to obtain a high yield. Strategic planning according to the location of the crops and its requirements should help to reduce these impacts from its cultivation. (author)

  20. Design Concepts for Co-Production of Power, Fuels & Chemicals Via Coal/Biomass Mixtures

    Energy Technology Data Exchange (ETDEWEB)

    Rao, A. D.; Chen, Q.; Samuelsen, G. S.

    2012-09-30

    The overall goal of the program is to develop design concepts, incorporating advanced technologies in areas such as oxygen production, feed systems, gas cleanup, component separations and gas turbines, for integrated and economically viable coal and biomass fed gasification facilities equipped with carbon capture and storage for the following scenarios: (i) coproduction of power along with hydrogen, (ii) coproduction of power along with fuels, (iii) coproduction of power along with petrochemicals, and (iv) coproduction of power along with agricultural chemicals. To achieve this goal, specifically the following objectives are met in this proposed project: (i) identify advanced technology options and innovative preliminary design concepts that synergistically integrate plant subsections, (ii) develop steady state system simulations to predict plant efficiency and environmental signature, (iii) develop plant cost estimates by capacity factoring major subsystems or by major equipment items where required, and then capital, operating and maintenance cost estimates, and (iv) perform techno- economic analyses for the above described coproduction facilities. Thermal efficiencies for the electricity only cases with 90% carbon capture are 38.26% and 36.76% (HHV basis) with the bituminous and the lignite feedstocks respectively. For the coproduction cases (where 50% of the energy exported is in the form of electricity), the electrical efficiency, as expected, is highest for the hydrogen coproduction cases while lowest for the higher alcohols (ethanol) coproduction cases. The electrical efficiencies for Fischer-Tropsch coproduction cases are slightly higher than those for the methanol coproduction cases but it should be noted that the methanol (as well as the higher alcohol) coproduction cases produce the finished coproduct while the Fischer-Tropsch coproduction cases produce a coproduct that requires further processing in a refinery. The cross comparison of the thermal

  1. Process to convert biomass and refuse derived fuel to ethers and/or alcohols

    Science.gov (United States)

    Diebold, James P.; Scahill, John W.; Chum, Helena L.; Evans, Robert J.; Rejai, Bahman; Bain, Richard L.; Overend, Ralph P.

    1996-01-01

    A process for conversion of a feedstock selected from the group consisting of biomass and refuse derived fuel (RDF) to provide reformulated gasoline components comprising a substantial amount of materials selected from the group consisting of ethers, alcohols, or mixtures thereof, comprising: drying said feedstock; subjecting said dried feedstock to fast pyrolysis using a vortex reactor or other means; catalytically cracking vapors resulting from said pyrolysis using a zeolite catalyst; condensing any aromatic byproduct fraction; catalytically alkylating any benzene present in said vapors after condensation; catalytically oligomerizing any remaining ethylene and propylene to higher olefins; isomerizing said olefins to reactive iso-olefins; and catalytically reacting said iso-olefins with an alcohol to form ethers or with water to form alcohols.

  2. Method to produce biomass-derived compounds using a co-solvent system containing gamma-valerolactone

    Science.gov (United States)

    Dumesic, James A.; Motagamwala, Ali Hussain

    2017-06-27

    A method to produce an aqueous solution of carbohydrates containing C5- and/or C6-sugar-containing oligomers and/or C5- and/or C6-sugar monomers in which biomass or a biomass-derived reactant is reacted with a solvent system having an organic solvent, and organic co-solvent, and water, in the presence of an acid. The method produces the desired product, while a substantial portion of any lignin present in the reactant appears as a precipitate in the product mixture.

  3. Method to produce carbon-cladded nuclear fuel particles

    International Nuclear Information System (INIS)

    Sturge, D.W.; Meaden, G.W.

    1978-01-01

    In the method charges of micro-spherules of fuel element are designed to have two carbon layers, whereby a one aims to achieve a uniform granulation (standard measurement). Two drums are used for this purpose connected behind one another. The micro-spherules coated with the first layer (phenolformaldehyde resin coated graphite particles) leave the first drum and enter the second one. Following the coating with a second layer, the micro-spherules are introduced into a grain size separator. The spherules that are too small are directly recycled into the second drum and those ones that are too large are recycled into the first drum after removing the graphite layers. The method may also be applied to metal cladded particles to manufacture cermet fuels. (RW) [de

  4. Energy Characterization and Gasification of Biomass Derived by Hazelnut Cultivation: Analysis of Produced Syngas by Gas Chromatography

    Directory of Open Access Journals (Sweden)

    D. Monarca

    2012-01-01

    Full Text Available Modern agriculture is an extremely energy intensive process. However, high agricultural productivities and the growth of green revolution has been possible only by large amount of energy inputs, especially those coming from fossil fuels. These energy resources have not been able to provide an economically viable solution for agricultural applications. Biomass energy-based systems had been extensively used for transportation and on farm systems during World War II: the most common and reliable solution was wood or biomass gasification. The latter means incomplete combustion of biomass resulting in production of combustible gases which mostly consist of carbon monoxide (CO, hydrogen (H2 and traces of methane (CH4. This mixture is called syngas, which can be successfully used to run internal combustion engines (both compression and spark ignition or as substitute for furnace oil in direct heat applications. The aim of the present paper is to help the experimentation of innovative plants for electric power production using agro-forest biomass derived by hazelnut cultivations. An additional purpose is to point out a connection among the chemical and physical properties of the outgoing syngas by biomass characterization and gas-chromatography analysis.

  5. TECHNOLOGY ASSESSMENT IN ENGINEERING PRACTICE. THE CASE OF BIOLIQ® – FUEL PRODUCTION FROM BIOMASS

    Directory of Open Access Journals (Sweden)

    Armin GRUNWALD

    2013-04-01

    Full Text Available This paper includes a brief overview of the basic motivations and objectives of TA, followed by a description of the three main operating fields of TA: providing scientific advice for decision‐making in the political system, contributing to public debate, and enriching technology development and engineering practice. These issues will then be considered in more detail by referring to various approaches to the relationship between TA and technology development and by presenting a specific case study of an accompanying TA process over various development stages of the bioliq® process for converting dry biomass into fuel (Biomass to Liquid and chemicals. The accompanying TA work on the bioliq® process can, as a result of more than ten years of experience, be considered a successful technology assessment as it has opened up a new research field with a highly precautionary aspect on the one hand, and helped to win over technology‐oriented research institutes to reorienting their research work, on the other. The results of the TA studies allowed to assess e.g. the competitiveness of the bioliq® process at a very early stage. The mutual trust built up in the course of the historical development between the parties involved has always been essential for this ongoing accompanying TA process. TA has been proven, in this way, a useful tool to uncover new chances for engineering research and development, and to accompany the research process.

  6. A survey of processes for producing hydrogen fuel from different sources for automotive-propulsion fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Brown, L.F.

    1996-03-01

    Seven common fuels are compared for their utility as hydrogen sources for proton-exchange-membrane fuel cells used in automotive propulsion. Methanol, natural gas, gasoline, diesel fuel, aviation jet fuel, ethanol, and hydrogen are the fuels considered. Except for the steam reforming of methanol and using pure hydrogen, all processes for generating hydrogen from these fuels require temperatures over 1000 K at some point. With the same two exceptions, all processes require water-gas shift reactors of significant size. All processes require low-sulfur or zero-sulfur fuels, and this may add cost to some of them. Fuels produced by steam reforming contain {approximately}70-80% hydrogen, those by partial oxidation {approximately}35-45%. The lower percentages may adversely affect cell performance. Theoretical input energies do not differ markedly among the various processes for generating hydrogen from organic-chemical fuels. Pure hydrogen has severe distribution and storage problems. As a result, the steam reforming of methanol is the leading candidate process for on-board generation of hydrogen for automotive propulsion. If methanol unavailability or a high price demands an alternative process, steam reforming appears preferable to partial oxidation for this purpose.

  7. Chemical biorefinery perspectives : the valorisation of functionalised chemicals from biomass resources compared to the conventional fossil fuel production route

    NARCIS (Netherlands)

    Brehmer, B.

    2008-01-01

    In response to the impending problems related to fossil fuels (continued supply, price, and
    regional and global pollution) alternative feedstocks are gaining interest as possible solutions.
    Biomass, considered sustainable and renewable, is an option with the potential to replace a wide

  8. Investigation of black and brown carbon multiple-wavelength-dependent light absorption from biomass and fossil fuel combustion source emissions

    Science.gov (United States)

    Michael R. Olson; Mercedes Victoria Garcia; Michael A. Robinson; Paul Van Rooy; Mark A. Dietenberger; Michael Bergin; James Jay Schauer

    2015-01-01

    Quantification of the black carbon (BC) and brown carbon (BrC) components of source emissions is critical to understanding the impact combustion aerosols have on atmospheric light absorption. Multiple-wavelength absorption was measured from fuels including wood, agricultural biomass, coals, plant matter, and petroleum distillates in controlled combustion settings....

  9. Environmental and Sustainable Technology Evaluations (ESTE): Verification of Fuel Characteristics and Emissions from Biomass-fired Boilers 09/2008

    Science.gov (United States)

    This is an ESTE project summary brief. With increasing concern about climate change and fossil fuel energy supplies, there continues to be an interest in biomass as a renewable and sustainable energy source. EPA’s Office of Air Quality Planning and Standards has expressed an int...

  10. Chemical biorefinery perspectives : the valorisation of functionalised chemicals from biomass resources compared to the conventional fossil fuel production route

    NARCIS (Netherlands)

    Brehmer, B.

    2008-01-01

    In response to the impending problems related to fossil fuels (continued supply, price, and regional and global pollution) alternative feedstocks are gaining interest as possible solutions. Biomass, considered sustainable and renewable, is an option with the potential to replace a wide diversity

  11. Renewing Rock-Tenn: A Biomass Fuels Assessment for Rock-Tenn's St. Paul Recycled Paper Mill.

    Energy Technology Data Exchange (ETDEWEB)

    Nelson, Carl

    2007-03-31

    In the summer of 2006 the Green Institute started the study for the RockTenn paper mill that would evaluate the economics and supply chain reliability of wood waste and other clean biomass as a fuel for the facility. The Green Institute obtained sponsorship from a broad coalition representing the community and the project team included other consultants and university researchers specializing in biomass issues. The final product from the project was a report to: 1) assess the availability of clean biomass fuel for use at the Rock-Tenn site; 2) roughly estimate costs at various annual usage quantities; and 3) develop the building blocks for a supply chain procurement plan. The initial report was completed and public presentations on the results were completed in spring of 2007.

  12. The importance of the wood biomass in environment protection

    Science.gov (United States)

    Spîrchez, Cosmin; Lunguleasa, Aurel; Croitoru, Cǎtǎlin

    2017-12-01

    Biomass is a natural vegetal component. As a form of storing energy is chemical form sun, biomass is one of the most popular and universal resource on Earth. Today biomass fuel can be used for various purposes from room heating to produce electricity and fuel for cars. Biomass is presented in various form for energy, including biodegradable fraction of products, remains and waste from agricultural, forestry and industrial wood processing residues from factories paste stationery and paper, remnants of industrial.

  13. Gasification of Woody Biomass.

    Science.gov (United States)

    Dai, Jianjun; Saayman, Jean; Grace, John R; Ellis, Naoko

    2015-01-01

    Interest in biomass to produce heat, power, liquid fuels, hydrogen, and value-added chemicals with reduced greenhouse gas emissions is increasing worldwide. Gasification is becoming a promising technology for biomass utilization with a positive environmental impact. This review focuses specifically on woody biomass gasification and recent advances in the field. The physical properties, chemical structure, and composition of biomass greatly affect gasification performance, pretreatment, and handling. Primary and secondary catalysts are of key importance to improve the conversion and cracking of tars, and lime-enhanced gasification advantageously combines CO2 capture with gasification. These topics are covered here, including the reaction mechanisms and biomass characterization. Experimental research and industrial experience are investigated to elucidate concepts, processes, and characteristics of woody biomass gasification and to identify challenges.

  14. Process Design and Economics for the Conversion of Lignocellulosic Biomass to Hydrocarbon Fuels. Thermochemical Research Pathways with In Situ and Ex Situ Upgrading of Fast Pyrolysis Vapors

    Energy Technology Data Exchange (ETDEWEB)

    Dutta, A.; Sahir, A.; Tan, E.; Humbird, D.; Snowden-Swan, L. J.; Meyer, P.; Ross, J.; Sexton, D.; Yap, R.; Lukas, J.

    2015-03-01

    This report was developed as part of the U.S. Department of Energy’s Bioenergy Technologies Office’s efforts to enable the development of technologies for the production of infrastructurecompatible, cost-competitive liquid hydrocarbon fuels from biomass. Specifically, this report details two conceptual designs based on projected product yields and quality improvements via catalyst development and process integration. It is expected that these research improvements will be made within the 2022 timeframe. The two conversion pathways detailed are (1) in situ and (2) ex situ upgrading of vapors produced from the fast pyrolysis of biomass. While the base case conceptual designs and underlying assumptions outline performance metrics for feasibility, it should be noted that these are only two of many other possibilities in this area of research. Other promising process design options emerging from the research will be considered for future techno-economic analysis.

  15. Technical and environmental performance of 10 kW understocker boiler during combustion of biomass and conventional fuels

    OpenAIRE

    Junga Robert; Wzorek Małgorzata; Kaszubska Mirosława

    2017-01-01

    This paper treats about the impact fuels from biomass wastes and coal combustion on a small boiler operation and the emission of pollutants in this process. Tests were performed in laboratory conditions on a water boiler with retort furnace and the capacity of 10 kW. Fuels from sewage sludge and agriculture wastes (PBZ fuel) and a blend of coal with laying hens mature (CLHM) were taken into account. The results in emission changes of NOx, CO2, CO and SO2 and operating parameters of the tested...

  16. Biomass gasification integrated with a solid oxide fuel cell and Stirling engine

    DEFF Research Database (Denmark)

    Rokni, Masoud

    2014-01-01

    An integrated gasification solid oxide fuel cell (SOFC) and Stirling engine for combined heat and power application is analyzed. The target for electricity production is 120 kW. Woodchips are used as gasification feedstock to produce syngas, which is then used to feed the SOFC stacks for electric......An integrated gasification solid oxide fuel cell (SOFC) and Stirling engine for combined heat and power application is analyzed. The target for electricity production is 120 kW. Woodchips are used as gasification feedstock to produce syngas, which is then used to feed the SOFC stacks......-of-plant is designed and suggested. Thermodynamic analysis shows that a thermal efficiency of 42.4% based on the lower heating value (LHV) can be achieved if all input parameters are selected conservatively. Different parameter studies are performed to analyze the system behavior under different conditions...

  17. Effective conversion of biomass tar into fuel gases in a microwave reactor

    Energy Technology Data Exchange (ETDEWEB)

    Anis, Samsudin, E-mail: samsudin-anis@yahoo.com [Department of Mechanical Engineering, Universitas Negeri Semarang, Kampus Sekaran, Gunungpati, 50229 Semarang, 8508101 (Indonesia); Zainal, Z. A., E-mail: mezainal@usm.my [School of Mechanical Engineering, Universiti Sains Malaysia, Engineering Campus, 14300 Nibong Tebal, Penang (Malaysia)

    2016-06-03

    This work deals with conversion of naphthalene (C{sub 10}H{sub 8}) as a biomass tar model compound by means of thermal and catalytic treatments. A modified microwave oven with a maximum output power of 700 W was used as the experimental reactor. Experiments were performed in a wide temperature range of 450-1200°C at a predetermined residence time of 0.24-0.5 s. Dolomite and Y-zeolite were applied to convert naphthalene catalytically into useful gases. Experimental results on naphthalene conversion showed that conversion efficiency and yield of gases increased significantly with the increase of temperature. More than 90% naphthalene conversion efficiency was achieved by thermal treatment at 1200°C and 0.5 s. Nevertheless, this treatment was unfavorable for fuel gases production. The main product of this treatment was soot. Catalytic treatment provided different results with that of thermal treatment in which fuel gases formation was found to be the important product of naphthalene conversion. At a high temperature of 900°C, dolomite had better conversion activity where almost 40 wt.% of naphthalene could be converted into hydrogen, methane and other hydrocarbon gases.

  18. Thermodynamic Performance Study of Biomass Gasification, Solid Oxide Fuel Cell and Micro Gas Turbine Hybrid Systems

    DEFF Research Database (Denmark)

    Bang-Møller, Christian; Rokni, Masoud

    2010-01-01

    University of Denmark. The SOFC converts the syngas more efficiently than the MGT, which is reflected by the energetic electrical efficiency of the gasifier and MGT system in opposition to the gasifier and SOFC configuration – η_el = 28.1% versus η_el = 36.4%. By combining the SOFC and MGT, the unconverted......A system level modelling study of three combined heat and power systems based on biomass gasification is presented. Product gas is converted in a micro gas turbine (MGT) in the first system, in a solid oxide fuel cell (SOFC) in the second system and in a combined SOFC–MGT arrangement in the third...... system. An electrochemical model of the SOFC has been developed and calibrated against published data from Topsoe Fuel Cells A/S and the Risø National Laboratory. The modelled gasifier is based on an up scaled version (~500 kW_th) of the demonstrated low tar gasifier, Viking, situated at the Technical...

  19. Solutions for biomass fuel market barriers and raw material availability. WP2 - Biomass fuel trade in Europe – Country report: The Netherlands

    NARCIS (Netherlands)

    Junginger, H.M.|info:eu-repo/dai/nl/202130703

    2009-01-01

    The aims of this country report are: (1) To identify new industries in the Netherlands where biomass is used as an energy carrier, or has the potential to be used in the future, and to describe which drivers, bottlenecks and opportunities these sectors see for the (increased) use of biomass; (2) To

  20. New Experimental Characterisation Methods for Solid Biomass Fuels to be used in Combined Heat and Power Generation

    Energy Technology Data Exchange (ETDEWEB)

    Gunnar Eriksson, (Energy Engineering Div., Luleaa Univ. of Technology, S-971 87 Luleaa (Sweden)); Nordgren, Daniel; Berg, Magnus (Vattenfall Research and Development AB, S-814 26 Aelvkarleby (Sweden))

    2008-10-15

    The replacement of fossil fuels will lead to an increasing demand for unconventional biofuels. Fuel characterisation to predict combustion properties and facilitate the choice of combustion applications is important to avoid costly and time-consuming mistakes. Traditional methods are developed mainly for coal. Therefore procedures adapted specifically for solid biomass fuels are needed. This work is a survey on approaches for combustion characterisation of biomass developed during the last ten years. Innovative characterisation methods of interest concern: 1) Fuel handling behaviour: grindablility, erosion and abrasion properties. 2) Combustion characterisation: devolatilisation properties (important for ignition and flame stability), char burnout time. 3) Slagging and fouling properties of ash: ash particle formation, ash particle size distribution, ash composition, melting and gasification temperatures, slagging of bottom ash, reducing the risk by mixing with other fuels or using fuel additives and choice of suitable combustion applications for specific fuels. The main conclusions are: 1) a method to measure grindability which takes electric power consumption into account is needed as the Hardgrove Grindability Index used for coal grinding is pointless for biofuels, 2) there is a need to develop convenient low-cost methods to measure slagging and fouling tendencies, devolatilisation kinetics and char burnout for high heating rates found in fluidised beds and powder burners

  1. Effect of fuel origin on synergy during co-gasification of biomass and coal in CO2.

    Science.gov (United States)

    Zhang, Yan; Zheng, Yan; Yang, Mingjun; Song, Yongchen

    2016-01-01

    The effect of fuel origin on synergy in coal/biomass blends during co-gasification has been assessed using a congruent-mass thermogravimetry analysis (TGA) method. Results revealed that synergy occurs when ash residuals are formed, followed by an almost complete gasification of biomass. Potassium species in biomass ash play a catalytic role in promoting gasification reactivity of coal char, which is a direct consequence of synergy during co-gasification. The SEM-EDS spectra provided conclusive evidence that the transfer of potassium from biomass to the surface of coal char occurs during co-pyrolysis/gasification. Biomass ash rich in silica eliminated synergy in coal/biomass blends but not to the extent of inhibiting the reaction rate of the blended chars to make it slower than that of separated ones. The best result in terms of synergy was concluded to be the combination of low-ash coal and K-rich biomass. Copyright © 2015 Elsevier Ltd. All rights reserved.

  2. Relation of fuel rod service parameters and design requirements to produced fuel rod and their components

    International Nuclear Information System (INIS)

    Bibilashvili, Yu.K.

    1999-01-01

    Based on the presented material it is possible to state that there is a very close link between the fuel operational parameters and the requirements for its design and production process. The required performance and life-time of a fuel rod can be only assured by the correctly selected design and process solutions. The economical aspect of this problem is significantly depend on the commercial feasibility of a particular selected solution with the provision of an automated and comparative by inexpensive production of a fuel rod and its components. The operational conditions are also important for the life time of the fuel rods. If there are no special measures for the mitigation of the certain operation conditions the leakage of fuel elements can take place before the planned time. (authors)

  3. Guidance on Biogas used to Produce CNG or LNG under the Renewable Fuel Standard Program

    Science.gov (United States)

    Provides EPA’s interpretation of biogas quality and RIN generation requirements that apply to renewable fuel production pathways involving the injection into a commercial pipeline of biogas for use in producing renewable CNG or renewable LNG.

  4. Emissions from small-scale combustion of biomass fuels - extensive quantification and characterization

    Energy Technology Data Exchange (ETDEWEB)

    Boman, Christoffer; Nordin, Anders; Oehman, Marcus; Bostroem, Dan [Umeaa Univ. (Sweden). Energy Technology and Thermal Process Chemistry; Westerholm, Roger [Stockholm Univ., Arrhenius Laboratory (Sweden). Analytical Chemistry

    2005-02-01

    This work was a part of the Swedish national research program concerning emissions and air quality with the sub-programme concerning biomass, health and environment - BHM. The main objective of the work was to systematically determine the quantities and characteristics of gaseous and particulate emissions from combustion in residential wood log and biomass fuel pellet appliances and report emission factors for the most important emission components. The specific focus was on present commercial wood and pellet stoves as well as to illustrate the potentials for future technology development. The work was divided in different subprojects; 1) a literature review of health effects of ambient wood smoke, 2) design and evaluation of an emission dilution sampling set-up, 3) a study of the effects of combustion conditions on the emission formation and characteristics and illustrate the potential for emission minimization during pellets combustion, 4) a study of the inorganic characteristics of particulate matter during combustion of different pelletized woody raw materials and finally 5) an extensive experimental characterization and quantification of gaseous and particulate emissions from residential wood log and pellet stoves. From the initial literature search, nine relevant health studies were identified, all focused on effects of short-term exposure. Substantial quantitative information was only found for acute asthma in relation to PM10. In comparison with the general estimations for ambient PM and adverse health effects, the relative risks were even stronger in the studies where residential wood combustion was considered as a major PM source. However, the importance of other particle properties than mass concentration, like chemical composition, particle size and number concentration remain to be elucidated. A whole flow dilution sampling set-up for residential biomass fired appliances was designed, constructed and evaluated concerning the effects of sampling

  5. Experience in producing LEU fuel elements for the RSG-GAS

    International Nuclear Information System (INIS)

    Suripto, A.; Soentono, S.

    1991-01-01

    To achieve a self-reliance in the operation of the 30 MW Multipurpose Research Reactor at Serpong (the RSG-GAS), a fuel element production facility has been constructed nearby. The main task of the facility is to produce MTR type fuel and control elements containing U 3 O 8 -Al dispersion LEU fuel for the RSG-GAS. The hot commissioning activity has started in early 1988 after completion of the cold commissioning using depleted uranium in 1987, marking the beginning of the real production activity. This paper briefly describes the main features of the fuel production facility, the production experience gained so far, and its current production activity. (orig.)

  6. Engine performance, combustion, and emissions study of biomass to liquid fuel in a compression-ignition engine

    International Nuclear Information System (INIS)

    Ogunkoya, Dolanimi; Fang, Tiegang

    2015-01-01

    Highlights: • Renewable biomass to liquid (BTL) fuel was tested in a direct injection diesel engine. • Engine performance, in-cylinder pressure, and exhaust emissions were measured. • BTL fuel reduces pollutant emission for most conditions compared with diesel and biodiesel. • BTL fuel leads to high thermal efficiency and lower fuel consumption compared with diesel and biodiesel. - Abstract: In this work, the effects of diesel, biodiesel and biomass to liquid (BTL) fuels are investigated in a single-cylinder diesel engine at a fixed speed (2000 rpm) and three engine loads corresponding to 0 bar, 1.26 bar and 3.77 bar brake mean effective pressure (BMEP). The engine performance, in-cylinder combustion, and exhaust emissions were measured. Results show an increase in indicated work for BTL and biodiesel at 1.26 bar and 3.77 bar BMEP when compared to diesel but a decrease at 0 bar. Lower mechanical efficiency was observed for BTL and biodiesel at 1.26 bar BMEP but all three fuels had roughly the same mechanical efficiency at 3.77 bar BMEP. BTL was found to have the lowest brake specific fuel consumption (BSFC) and the highest brake thermal efficiency (BTE) among the three fuels tested. Combustion profiles for the three fuels were observed to vary depending on the engine load. Biodiesel was seen to have the shortest ignition delay among the three fuels regardless of engine loads. Diesel had the longest ignition delay at 0 bar and 3.77 bar BMEP but had the same ignition delay as BTL at 1.26 bar BMEP. At 1.26 bar and 3.77 bar BMEP, BTL had the lowest HC emissions but highest HC emissions at no load conditions when compared to biodiesel and diesel. When compared to diesel and biodiesel BTL had lower CO and CO 2 emissions. At 0 bar and 1.26 bar BMEP, BTL had higher NOx emissions than diesel fuel but lower NOx than biodiesel at no load conditions. At the highest engine load tested, NOx emissions were observed to be highest for diesel fuel but lowest for BTL. At 1

  7. Biomass-derived heteroatoms-doped mesoporous carbon for efficient oxygen reduction in microbial fuel cells.

    Science.gov (United States)

    Lu, Yu; Zhu, Nengwu; Yin, Fuhua; Yang, Tingting; Wu, Pingxiao; Dang, Zhi; Liu, Meilin; Wei, Xiaorong

    2017-12-15

    Currently, the development of less expensive, more active and more stable catalysts like heteroatom-doped carbon based non-precious metal materials are highly desired for the cathodic oxygen reduction reaction (ORR) in microbial fuel cells (MFCs). Comparing with heteroatom sources from chemical reagents, biomass is notably inexpensive and abundant, containing more elements which contribute to ORR activity. Herein, we demonstrate an easy operating one-step and low-cost way to synthesize egg-derived heteroatoms-doped mesoporous carbon (EGC) catalysts utilizing egg as the biomass carbon and other elements source (sulphur, phosphorus, boron and iron), and porous g-C 3 N 4 as both template and nitrogen source. After carbonized, such hybrid materials possess an outstanding electrocatalytic activity towards ORR comparable to the commercial Pt/C catalyst in neutral media. Electrochemical detections as cyclic voltammogram and rotating ring-disk electrode tests show that the potential of oxygen reduction peak of EGC1-10-2 is at + 0.10V, onset potential is at + 0.257V (vs. Ag/AgCl) and electron transfer number of that is 3.84-3.92, which indicate that EGC1-10-2 via a four-electron pathway. Reactor operation shows that the maximum power density of MFC-EGC1-10-2 (737.1mWm -2 ), which is slightly higher than MFC-Pt/C (20%) (704mWm -2 ). The low cost (0.049 $g -1 ), high yield (20.26%) and high performance of EGC1-10-2 provide a promising alternative to noble metal catalysts by using abundant natural biological resources, which contribute a lot to expansion and commercialization of MFCs. Copyright © 2017 Elsevier B.V. All rights reserved.

  8. Emerging Technologies for the Production of Renewable Liquid Transport Fuels from Biomass Sources Enriched in Plant Cell Walls.

    Science.gov (United States)

    Tan, Hwei-Ting; Corbin, Kendall R; Fincher, Geoffrey B

    2016-01-01

    Plant cell walls are composed predominantly of cellulose, a range of non-cellulosic polysaccharides and lignin. The walls account for a large proportion not only of crop residues such as wheat straw and sugarcane bagasse, but also of residues of the timber industry and specialist grasses and other plants being grown specifically for biofuel production. The polysaccharide components of plant cell walls have long been recognized as an extraordinarily large source of fermentable sugars that might be used for the production of bioethanol and other renewable liquid transport fuels. Estimates place annual plant cellulose production from captured light energy in the order of hundreds of billions of tons. Lignin is synthesized in the same order of magnitude and, as a very large polymer of phenylpropanoid residues, lignin is also an abundant, high energy macromolecule. However, one of the major functions of these cell wall constituents in plants is to provide the extreme tensile and compressive strengths that enable plants to resist the forces of gravity and a broad range of other mechanical forces. Over millions of years these wall constituents have evolved under natural selection to generate extremely tough and resilient biomaterials. The rapid degradation of these tough cell wall composites to fermentable sugars is therefore a difficult task and has significantly slowed the development of a viable lignocellulose-based biofuels industry. However, good progress has been made in overcoming this so-called recalcitrance of lignocellulosic feedstocks for the biofuels industry, through modifications to the lignocellulose itself, innovative pre-treatments of the biomass, improved enzymes and the development of superior yeasts and other microorganisms for the fermentation process. Nevertheless, it has been argued that bioethanol might not be the best or only biofuel that can be generated from lignocellulosic biomass sources and that hydrocarbons with intrinsically higher energy

  9. Emerging Technologies for the Production of Renewable Liquid Transport Fuels from Biomass Sources Enriched in Plant Cell Walls

    Directory of Open Access Journals (Sweden)

    Hwei-Ting Tan

    2016-12-01

    Full Text Available Plant cell walls are composed predominantly of cellulose, a range of non-cellulosic polysaccharides and lignin. The walls account for a large proportion not only of crop residues such as wheat straw and sugarcane bagasse, but also of residues of the timber industry and specialist grasses and other plants being grown specifically for biofuel production. The polysaccharide components of plant cell walls have long been recognized as an extraordinarily large source of fermentable sugars that might be used for the production of bioethanol and other renewable liquid transport fuels. Estimates place annual plant cellulose production from captured light energy in the order of hundreds of billions of tonnes. Lignin is synthesised in the same order of magnitude and, as a very large polymer of phenylpropanoid residues, lignin is also an abundant, high energy macromolecule. However, one of the major functions of these cell wall constituents in plants is to provide the extreme tensile and compressive strengths that enable plants to resist the forces of gravity and a broad range of other mechanical forces. Over millions of years these wall constituents have evolved under natural selection to generate extremely tough and resilient biomaterials. The rapid degradation of these tough cell wall composites to fermentable sugars is therefore a difficult task and has significantly slowed the development of a viable lignocellulose-based biofuels industry. However, good progress has been made in overcoming this so-called recalcitrance of lignocellulosic feedstocks for the biofuels industry, through modifications to the lignocellulose itself, innovative pre-treatments of the biomass, improved enzymes and the development of superior yeasts and other microorganisms for the fermentation process. Nevertheless, it has been argued that bioethanol might not be the best or only biofuel that can be generated from lignocellulosic biomass sources and that hydrocarbons with

  10. Feasibility of producing jet fuel from GPGP (Great Plains Gasification Plant) by-products

    Energy Technology Data Exchange (ETDEWEB)

    Willson, W.G.; Knudson, C.L.; Rindt, J.R.

    1987-01-01

    The Great Plains Gasification Plant (GPGP) in Beulah, North Dakota, is in close proximity to several Air Force bases along our northern tier. This plant is producing over 137 million cubic feet per day of high-Btu Natural Gas from North Dakota lignite. In addition, the plant generates three liquid streams, naphtha, crude phenol, and tar oil. The naphtha may be directly marketable because of its low boiling point and high aromatic content. The other two streams, totalling about 4300 barrels per day, are available as potential sources of aviation fuel jet fuel for the Air Force. The overall objective of this project is to assess the technical and economic feasibility of producing aviation turbine fuel from the by-product streams of GPGP. These streams, as well as fractions, thereof, will be characterized and subsequently processed over a wide range of process conditions. The resulting turbine fuel products will be analyzed to determine their chemical and physical characteristics as compared to petroleum-based fuels to meet the military specification requirements. A second objective is to assess the conversion of the by-product streams into a new, higher-density aviation fuel. Since no performance specifications currently exist for a high-density jet fuel, reaction products and intermediates will only be characterized to indicate the feasibility of producing such a fuel. This report discusses the suitability of the tar oil stream. 5 refs., 20 figs., 15 tabs.

  11. Fossil fuel savings, carbon emission reduction and economic attractiveness of medium-scale integrated biomass gasification combined cycle cogeneration plants

    Directory of Open Access Journals (Sweden)

    Kalina Jacek

    2012-01-01

    Full Text Available The paper theoretically investigates the system made up of fluidized bed gasifier, SGT-100 gas turbine and bottoming steam cycle. Different configurations of the combined cycle plant are examined. A comparison is made between systems with producer gas (PG and natural gas (NG fired turbine. Supplementary firing of the PG in a heat recovery steam generator is also taken into account. The performance of the gas turbine is investigated using in-house built Engineering Equation Solver model. Steam cycle is modeled using GateCycleTM simulation software. The results are compared in terms of electric energy generation efficiency, CO2 emission and fossil fuel energy savings. Finally there is performed an economic analysis of a sample project. The results show relatively good performance in the both alternative configurations at different rates of supplementary firing. Furthermore, positive values of economic indices were obtained. [Acknowledgements. This work was carried out within the frame of research project no. N N513 004036, titled: Analysis and optimization of distributed energy conversion plants integrated with gasification of biomass. The project is financed by the Polish Ministry of Science.

  12. CHARACTERIZATION QUALITATIVE OF SOEL FOR A VALORIZATION BEST OF THE BIOMASS PRODUCED

    Directory of Open Access Journals (Sweden)

    Y. M’Sadak

    2015-03-01

    Full Text Available The main objective of this study was to qualitatively characterize biomass of Solanum elaeagnifolium Cav. (or SOEL to highlight the essential alternatives its valorization. At first, we studied the potential of composting biomass of this plant. The physico-chemical characterization of biomass silverleaf nightshade has detected a wealth in organic carbon, which highlighted the potential value of this plant in the Co-composting with other biodegradable waste. In a second step, we assessed the possibility to develop this plant in the area of treatment in textile effluents by biosorption of dyes on fibers from the biomass of this plant, especially after the discovery of high levels of cellulose in its different organs.

  13. CHARACTERIZATION QUALITATIVE OF SOEL FOR A VALORIZATION BEST OF THE BIOMASS PRODUCED

    Directory of Open Access Journals (Sweden)

    Y. M’Sadak

    2015-01-01

    Full Text Available The main objective of this study was to qualitatively characterize biomass of Solanum elaeagnifolium Cav. (or SOEL to highlight the essential alternatives its valorization. At first, we studied the potential of composting biomass of this plant. The physico-chemical characterization of biomass silverleaf nightshade has detected a wealth in organic carbon, which highlighted the potential value of this plant in the Co-composting with other biodegradable waste. In a second step, we assessed the possibility to develop this plant in the area of treatment in textile effluents by biosorption of dyes on fibers from the biomass of this plant, especially after the discovery of high levels of cellulose in its different organs.

  14. Safety - a Neglected Issue When Introducing Solid Biomass Fuel in Thermal Power Plants? Some Evidence of an Emerging Risk

    DEFF Research Database (Denmark)

    Hedlund, Frank Huess; Astad, John

    2013-01-01

    attention paid to safety and points to evidence of media-shifting-that the 'resolution' of a problem within the environmental domain creates a new problem in the workplace safety domain. The paper argues that biomass pellets qualify as an emerging risk for which proper control strategies have yet......The paper examines recent evidence from Denmark and abroad with climate change projects that aim to reduce global carbon dioxide emissions by converting coal fired thermal power plants to solid biomass fuel. The paper argues that projects appear to be pursued narrow-mindedly with insufficient...

  15. Experimental investigations of a four-stroke single cylinder direct injection diesel engine operated on dual fuel mode with producer gas as inducted fuel and Honge oil and its methyl ester (HOME) as injected fuels

    Energy Technology Data Exchange (ETDEWEB)

    Banapurmath, N.R.; Tewari, P.G. [Department of Mechanical Engineering, B.V.B. College of Engineering and Technology, Hubli 580031, Karnataka (India); Hosmath, R.S. [Department of Mechanical Engineering, K.L.E Society' s College of Engineering and Technology, Belgaum, Karnataka (India)

    2008-09-15

    diesel engines. Int J Renew Energy 2000;21:433-44.; Nwafor OMI. The effect of elevated fuel inlet temperature on performance of diesel engine running on neat vegetable oil at constant speed conditions. Renew Energy 2003;28:171-81. ]. In view of this, Honge oil (Pongamia Pinnata Linn) being non-edible oil could be regarded as an alternative fuel for CI engine applications. The viscosity of Honge oil is reduced by transesterification process to obtain Honge oil methyl ester (HOME). Gasification is a process in which solid biomass is converted into a mixture of combustible gases, which complete their combustion in an IC engine. Hence, producer gas can act as a promising alternative fuel, especially for diesel engines by substituting considerable amount of diesel fuels. Downdraft moving bed gasifiers coupled with IC engine are a good choice for moderate quantities of available biomass, up to 500 kW of electric power. Hence, bioderived gas and vegetable liquids appear more attractive in view of their friendly environmental nature. Since vegetable oils produce higher smoke emissions, dual fuel operation could be adopted for improving their performance. (author)

  16. Production of hydrogen driven from biomass waste to power Remote areas away from the electric grid utilizing fuel cells and internal combustion engines vehicles

    Energy Technology Data Exchange (ETDEWEB)

    Tawfik, Hazem [Farmingdale State College, NY (United States)

    2017-03-10

    Recent concerns over the security and reliability of the world’s energy supply has caused a flux towards the research and development of renewable sources. A leading renewable source has been found in the biomass gasification of biological materials derived from organic matters such as wood chips, forest debris, and farm waste that are found in abundance in the USA. Accordingly, there is a very strong interest worldwide in the development of new technologies that provide an in-depth understanding of this economically viable energy source. This work aims to allow the coupling of biomass gasification and fuel cell systems as well as Internal Combustion Engines (ICE) to produce high-energy efficiency, clean environmental performance and near-zero greenhouse gas emissions. Biomass gasification is a process, which produces synthesis gas (syngas) that contains 19% hydrogen and 20% carbon monoxide from inexpensive organic matter waste. This project main goal is to provide cost effective energy to the public utilizing remote farms’ waste and landfill recycling area.

  17. Concurrent bio-electricity and biomass production in three Plant-Microbial Fuel Cells using Spartina anglica, Arundinella anomala and Arundo donax.

    Science.gov (United States)

    Helder, M; Strik, D P B T B; Hamelers, H V M; Kuhn, A J; Blok, C; Buisman, C J N

    2010-05-01

    In a Plant Microbial Fuel Cell (P-MFC) three plants were tested for concurrent biomass and bio-electricity production and maximization of power output. Spartina anglica and Arundinella anomala concurrently produced biomass and bio-electricity for six months consecutively. Average power production of the P-MFC with S. anglica during 13weeks was 16% of the theoretical maximum power and 8% during 7weeks for A. anomala. The P-MFC with Arundo donax, did not produce electricity with a stable output, due to break down of the system. The highest obtained power density in a P-MFC was 222mW/m(2) membrane surface area with S. anglica, over twice as high as the highest reported power density in a P-MFC. High biomass yields were obtained in all P-MFC's, with a high root:shoot ratio, probably caused nutrient availability and anaerobia in the soil. Power output maximization via adjusting load on the system lead to unstable performance of the P-MFC. Copyright 2010 Elsevier Ltd. All rights reserved.

  18. Source apportionment of air pollution exposures of rural Chinese women cooking with biomass fuels

    Science.gov (United States)

    Huang, Wei; Baumgartner, Jill; Zhang, Yuanxun; Wang, Yuqin; Schauer, James J.

    2015-03-01

    Particulate matter (PM) from different sources may differentially affect human health. Few studies have assessed the main sources of personal exposure to PM and their contributions among residents of developing countries, where pollution sources differ from those in higher-income settings. 116 daily (24-h) personal PM2.5 exposure samples were collected among 81 women cooking with biomass fuels in two villages in rural Yunnan, China. The PM samples were analyzed for mass and chemical composition, including water-soluble organic carbon (WSOC), black carbon (BC), and molecular markers. We found black carbon, n-alkanes and levoglucosan dominated the most abundant fractions of the total measured species and average personal PM2.5 exposure was higher in winter than that in summer in both villages. The composition data were then analyzed using a positive matrix factorization (PMF) receptor model to identify the main PM emission sources contributing to women's exposures and to assess their spatial (between villages) and seasonal variation in our study setting. The 6-factor solution provided reasonably stable profiles and was selected for further analysis. Our results show that rural Chinese women cooking with biomass fuels are exposed to a variety of sources. The identified factors include wood combustion (41.1%), a cooking source (35.6%), a mobile source (12.6%), plant waxes (6.7%), pyrolysis combustion (3.0%), and secondary organic aerosols (SOA; 1.0%). The mean source contributions of the mobile source, cooking source, and wood combustion factor to PM2.5 exposure were significantly different between women living in the two study villages, whereas the mean SOA, wood combustion, and plant waxes factors differed seasonally. There was no relationship between source contributions and questionnaire-based measurements of source-specific exposures, implying that the impacts of source contributions on exposure are affected by complex spatial, temporal and behavioral patterns

  19. The influence of a Renewable Energy Feed in Tariff on the decision to produce biomass crops in Ireland

    International Nuclear Information System (INIS)

    Clancy, D.; Breen, J.P.; Thorne, F.; Wallace, M.

    2012-01-01

    A target of 30 per cent substitution of biomass for peat in the three peat fired power stations from 2015 has been set by the Irish Government. However, a knowledge gap exists on the extent to which Irish farmers would actually choose to grow these crops. An extension of the Renewable Energy Feed in Tariff (REFIT) scheme to include the co-firing of biomass with peat in electricity generation would enable the power stations to enter into Power Purchase Agreements (PPAs). These offer a fixed price to farmers for biomass feedstock. The decision to adopt biomass is represented as a constrained problem under certainty with the objective of profit maximisation. The results showed that the price offered under a PPA has a large effect on the economic returns from biomass crops. The price that the power stations previously estimated they would be able to pay, at €46 and €48 per tonne for willow and miscanthus, respectively, was used as a starting point. At this price the number of farmers who would choose to adopt biomass production is insufficient to achieve the national co-firing target. The target could be achieved at €70 and €65 per tonne for willow and miscanthus, respectively. - Highlights: ► We model the decision of Irish farmers to produce biomass crops. ► Current prices will lead to insufficient adoption to achieve policy targets. ► REFIT mechanism can succeed in meeting policy goals. ► Willow prices need to increase by approximately 27 per cent. ► Miscanthus prices need to increase by approximately 8 per cent.

  20. Experimental investigation on combustion and heat transfer characteristics in a furnace fueled with unconventional biomass fuels (date stones and palm stalks)

    International Nuclear Information System (INIS)

    Al-Omari, S.-A.B.

    2006-01-01

    The combustion of date stones and palm stalks in a small scale furnace with a conical solid fuel bed is investigated experimentally. This investigation (to the best of the knowledge of the author) is the first addressing date stones as a new renewable energy source. Different experimental conditions are investigated where different fuel feed conditions and different combustion air flow rates are considered. The major results are given in terms of the fuel reduction rates and the heat transferred to the cooling water flowing in a water jacket around the furnace as functions of time. Combustion of the biomass fuels considered here in the investigated furnace is initiated by using LPG fuel as a starter. The hot products of LPG combustion, which is taking place in a burner built prior to the investigated solid fuel furnace, are allowed to penetrate the conical fuel bed for 2-3 min from its bottom base in the upward direction, causing effective heating and gasification and pyrolysis of the solid fuel in the bed to take place. The resulting combustible gases mix with the combustion air and subsequently are ignited by an external ignition source. The results of the present study highlight date stones as a renewable energy source with a good potential

  1. A review of catalytic microwave pyrolysis of lignocellulosic biomass for value-added fuel and chemicals.

    Science.gov (United States)

    Morgan, Hervan Marion; Bu, Quan; Liang, Jianghui; Liu, Yujing; Mao, Hanping; Shi, Aiping; Lei, Hanwu; Ruan, Roger

    2017-04-01

    Lignocellulosic biomass is an abundant renewable resource and can be efficiently converted into bio-energy by a bio-refinery. From the various techniques available for biomass thermo-chemical conversion; microwave assisted pyrolysis (MAP) seems to be the very promising. The principles of microwave technology were reviewed and the parameters for the efficient production of bio-oil using microwave technology were summarized. Microwave technology by itself cannot efficiently produce high quality bio-oil products, catalysts are used to improve the reaction conditions and selectivity for valued products during MAP. The catalysts used to optimize MAP are revised in the development of this article. The origins for bio-oils that are phenol rich or hydrocarbon rich are reviewed and their experimental results were summarized. The kinetics of MAP is discussed briefly in the development of the article. Future prospects and scientific development of MAP are also considered in the development of this article. Copyright © 2017 Elsevier Ltd. All rights reserved.

  2. Isolation and characterization of Bacillus subtilis strain BY-3, a thermophilic and efficient cellulase-producing bacterium on untreated plant biomass.

    Science.gov (United States)

    Meng, F; Ma, L; Ji, S; Yang, W; Cao, B

    2014-09-01

    Bioconversion of biomass, particularly crop wastes, into biofuels is being developed as an alternative approach in meeting the high energy demand. In this study, a thermophilic bacterial strain BY-3 that exhibits cellulolytic potential was isolated from faecal samples of Tibetan pigs; this strain was identified as Bacillus subtilis. The strain can produce cellulase when grown on various substrates, including carboxymethyl cellulose, rice straw, corn stover, soluble starch and wheat bran. The maximum cellulase activity of the strain was up to 4·323 ± 0·065 U ml(-1) when cultivated in the medium containing corn stover (30 g l(-1) ) for 24 h. The results demonstrated that corn stover is the most suitable substrate for cellulase production by the strain BY-3. The crude cellulase of strain BY-3 was most active at pH 5·5 and 60°C, and the enzyme in acetate buffer (50 mmol l(-1) ) demonstrated a good stability at 60°C for at least 1 h. The crude cellulase exhibited a strong antibacterial activity against Staphylococcus aureus. The strain can be used in cost-efficient cellulase production for bioconversion of agricultural residual biomass into biofuels. The increased consumption of fossil fuels has caused serious energy crisis and environmental problem. Thus, an alternative energy source is necessary. Bioconversion of biomass, particularly agricultural residuals, into value-added bioproducts, such as biofuels and chemical solvents, has received considerable attention. In this study, the newly isolated thermophilic Bacillus subtilis strain BY-3 produces cellulase efficiently with the use of untreated corn stover as a sole carbon source. This strain possesses the thermostable cellulase that is active with diverse crop wastes with a broad pH range and is a highly promising candidate for agricultural waste management. © 2014 The Society for Applied Microbiology.

  3. Highly efficient conversion of terpenoid biomass to jet-fuel range cycloalkanes in a biphasic tandem catalytic process

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Xiaokun [Univ. of Nevada, Reno, NV (United States); Li, Teng [Washington State Univ., Pullman, WA (United States); Tang, Kan [Washington State Univ., Pullman, WA (United States); Zhou, Xinpei [Univ. of Nevada, Reno, NV (United States); Lu, Mi [Univ. of Nevada, Reno, NV (United States); Ounkham, Whalmany L. [Univ. of Nevada, Reno, NV (United States); Spain, Stephen M. [Univ. of Nevada, Reno, NV (United States); Frost, Brian J. [Univ. of Nevada, Reno, NV (United States); Lin, Hongfei [Washington State Univ., Pullman, WA (United States)

    2017-06-12

    The demand for bio-jet fuels to reduce carbon emissions is increasing substantially in the aviation sector, while the scarcity of high-density jet fuel components limits the use of bio-jet fuels in high-performance aircrafts compared with conventional jet fuels. In this paper, we report a novel biphasic tandem catalytic process (biTCP) for synthesizing cycloalkanes from renewable terpenoid biomass, such as 1,8-cineole. Multistep tandem reactions, including C–O ring opening by hydrolysis, dehydration, and hydrogenation, were carried out in the “one-pot” biTCP. 1,8-Cineole was efficiently converted to p-menthane at high yields (>99%) in the biTCP under mild reaction conditions. Finally, the catalytic reaction mechanism is discussed.

  4. Compressed hydrogen-rich fuel gas (CHFG) from wet biomass by reforming in supercritical water

    Energy Technology Data Exchange (ETDEWEB)

    Penninger, Johannes M.L.; Maass, Georg J.J. [SPARQLE International B.V., Hasebroekstraat 1, 7552 VX Hengelo (Netherlands); Rep, Marco [BTG Biomass Technology Group B.V., Pantheon 12, 7521 PR Enschede (Netherlands)

    2007-07-15

    Aqueous condensate produced from biomass by flash pyrolysis is a clean feedstock for gas production by reforming at supercritical water conditions of 600-650 {sup circle} C and 28-30 MPa. Low concentrations of soda ash in the condensate reduce the CO content of the reformer gas to about 2% and proportionally increase the hydrogen content. This lean-CO gas appears as a primary candidate for upgrading to CHFG quality. Desk studies, reported in this paper, concern the design of a conceptual gas conditioning process and reveal interesting potential for production of CHFG, free of CO and CO{sub 2}, a hydrogen content of 50% with a pressure of 30 MPa, without the need for gas compression. The high processing pressure provides for small equipment size and low energy consumption. (author)

  5. Rotary kiln and batch pyrolysis of waste tire to produce gasoline and diesel like fuels

    International Nuclear Information System (INIS)

    Ayanoğlu, Abdulkadir; Yumrutaş, Recep

    2016-01-01

    Highlights: • Waste Tire Oil (WTO) is produced from waste tire at rotary kiln reactor. • Physical and chemical properties of WTO and fuel samples are analyzed. • Gasoline like fuel (GLF) and diesel like fuel (DLF) are produced from the WTO-10 wt% CaO mixture at fixed bed reactor. • Physical and chemical properties of the GLF and DLF are compared with the standard fuels. - Abstract: In this study, waste tire is pyrolyzed in a rotary kiln reactor to obtain more gas, light liquid, heavy liquid, wax products, and less carbon black at their maximum yields as, 20%, 12%, 25%, 8% and 35% of the total weight (4 tones), respectively. Then, the heavy and light oils are reacted with additives such as natural zeolite (NZ) and lime (CaO) at different mass ratio as 2, 6, and 10 wt%, respectively, in the batch reactor to produce liquids similar to standard petroleum fuels. The heavy and light oils mixture samples are distillated to observe their optimum graphics which are similar to gasoline and diesel like fuel. Consequently, the best results are obtained from the CaO sample with 10 wt% in comparison to the ones from the gasoline and diesel fuels. The 10 wt% CaO light liquid mixture resembles to gasoline named as gasoline like fuel (GLF) and the 10 wt% CaO heavy liquid mixture is similar to diesel called as diesel like fuel (DLF). The chemical and physical features of the waste tire, light oil, heavy oil, GLF, and DLF are analyzed by TG (thermogravimetric)/dTG (derivative thermogravimetric), proximate, ultimate, higher heating value (HHV), fourier transform-infrared spectroscopy (FT-IR), Brunauer–Emmett–Teller (BET), sulfur, density, viscosity, gas chromatography–mass spectroscopy (GC–MS), flash point, moisture, and distillation tests. The test results are turned out to be very close to the standard petroleum fuel.

  6. Advanced Systems for Preprocessing and Characterizing Coal-Biomass Mixtures as Next-Generation Fuels and Feedstocks

    Energy Technology Data Exchange (ETDEWEB)

    Karmis, Michael [Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States); Luttrell, Gerald [Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States); Ripepi, Nino [Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States); Bratton, Robert [Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States); Dohm, Erich [Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States)

    2014-09-30

    The research activities presented in this report are intended to address the most critical technical challenges pertaining to coal-biomass briquette feedstocks. Several detailed investigations were conducted using a variety of coal and biomass feedstocks on the topics of (1) coal-biomass briquette production and characterization, (2) gasification of coal-biomass mixtures and briquettes, (3) combustion of coal-biomass mixtures and briquettes, and (4) conceptual engineering design and economic feasibility of briquette production. The briquette production studies indicate that strong and durable co-firing feedstocks can be produced by co-briquetting coal and biomass resources commonly available in the United States. It is demonstrated that binderless coal-biomass briquettes produced at optimized conditions exhibit very high strength and durability, which indicates that such briquettes would remain competent in the presence of forces encountered in handling, storage and transportation. The gasification studies conducted demonstrate that coal-biomass mixtures and briquettes are exceptional gasification feedstocks, particularly with regard to the synergistic effects realized during devolatilization of the blended materials. The mixture combustion studies indicate that coal-biomass mixtures are exceptional combustion feedstocks, while the briquette combustion study indicates that the use of blended briquettes reduces NOx, CO2, and CO emissions, and requires the least amount of changes in the operating conditions of an existing coal-fired power plant. Similar results were obtained for the physical durability of the pilot-scale briquettes compared to the bench-scale tests. Finally, the conceptual engineering and feasibility analysis study for a commercial-scale briquetting production facility provides preliminary flowsheet and cost simulations to evaluate the various feedstocks, equipment selection and operating parameters.

  7. Uncertainty in the availability of natural resources: Fossil fuels, critical metals and biomass

    International Nuclear Information System (INIS)

    Speirs, Jamie; McGlade, Christophe; Slade, Raphael

    2015-01-01

    Energy policies are strongly influenced by resource availability and recoverability estimates. Yet these estimates are often highly uncertain, frequently incommensurable, and regularly contested. This paper explores how the uncertainties surrounding estimates of the availability of fossil fuels, biomass and critical metals are conceptualised and communicated. The contention is that a better understanding of the uncertainties surrounding resource estimates for both conventional and renewable energy resources can contribute to more effective policy decision making in the long term. Two complementary approaches for framing uncertainty are considered in detail: a descriptive typology of uncertainties and a framework that conceptualises uncertainty as alternative states of incomplete knowledge. Both have the potential to be useful analytical and communication tools. For the three resource types considered here we find that data limitations, inconsistent definitions and the use of incommensurable methodologies present a pervasive problem that impedes comparison. Many aspects of resource uncertainty are also not commonly captured in the conventional resource classification schemes. This highlights the need for considerable care when developing and comparing aggregate resource estimates and when using these to inform strategic energy policy decisions. - Highlights: • Resource estimates are highly uncertain, frequently incommensurable, and regularly contested. • Data limitations need to be overcome, and methodologies harmonised and improved. • Sustainability and socio-political uncertainties are frequently neglected. • Uncertainties are dynamic, but reducing uncertainties inevitably involves trade-offs.

  8. Assessment of PM10 concentrations from domestic biomass fuel combustion in two rural Bolivian highland villages

    International Nuclear Information System (INIS)

    Albalak, R.; Haber, M.

    1999-01-01

    PM 10 concentrations were measured in two contrasting rural Bolivian villages that cook with biomass fuels. In one of the villages, cooking was done exclusively indoors, and in the other, it was done primarily outdoors. Concentrations in all potential microenvironments of exposure (i.e., home, kitchen, and outdoors) were measured for a total of 621 samples. Geometric mean kitchen PM 10 concentrations were 1830 and 280 microg/m 3 and geometric mean home concentrations were 280 and 440 microg/m 3 for the indoor and outdoor cooking villages, respectively. An analysis of pollutant concentrations using generalized estimating equation techniques showed significant effects of village location, and interaction of village and location on log-transformed PM 10 concentrations. Pollutant concentrations and activity pattern data were used to estimate total exposure using the indirect method of exposure assessment. Daily exposure for women during the nonwork season was 15 120 and 6240 microg h -1 m -3 for the indoor and outdoor cooking villages, respectively. Differences in exposure to pollution between the villages were not as great as might be expected based on kitchen concentration alone. This study underscores the importance of measuring pollutant concentrations in all microenvironments where people spend time and of shifting the focus of air pollution studies to include rural populations in developing countries

  9. Predicting gaseous emissions from small-scale combustion of agricultural biomass fuels.

    Science.gov (United States)

    Fournel, S; Marcos, B; Godbout, S; Heitz, M

    2015-03-01

    A prediction model of gaseous emissions (CO, CO2, NOx, SO2 and HCl) from small-scale combustion of agricultural biomass fuels was developed in order to rapidly assess their potential to be burned in accordance to current environmental threshold values. The model was established based on calculation of thermodynamic equilibrium of reactive multicomponent systems using Gibbs free energy minimization. Since this method has been widely used to estimate the composition of the syngas from wood gasification, the model was first validated by comparing its prediction results with those of similar models from the literature. The model was then used to evaluate the main gas emissions from the combustion of four dedicated energy crops (short-rotation willow, reed canary grass, switchgrass and miscanthus) previously burned in a 29-kW boiler. The prediction values revealed good agreement with the experimental results. The model was particularly effective in estimating the influence of harvest season on SO2 emissions. Copyright © 2014 Elsevier Ltd. All rights reserved.

  10. Method for producing hydrocarbon fuels and fuel gas from heavy polynuclear hydrocarbons by the use of molten metal halide catalysts

    Science.gov (United States)

    Gorin, Everett

    1979-01-01

    In a process for hydrocracking heavy polynuclear carbonaceous feedstocks to produce lighter hydrocarbon fuels by contacting the heavy feedstocks with hydrogen in the presence of a molten metal halide catalyst in a hydrocracking zone, thereafter separating at least a major portion of the lighter hydrocarbon fuels from the spent molten metal halide and thereafter regenerating the spent molten metal halide by incinerating the spent molten metal halide by combustion of carbon and sulfur compounds in the spent molten metal halide in an incineration zone, the improvement comprising: (a) contacting the heavy feedstocks and hydrogen in the presence of the molten metal halide in the hydrocracking zone at reaction conditions effective to convert from about 60 to about 90 weight percent of the feedstock to lighter hydrocarbon fuels; (b) separating at least a major portion of the lighter hydrocarbon fuels from the spent molten metal halide; (c) contacting the spent molten metal halide with oxygen in a liquid phase gasification zone at a temperature and pressure sufficient to vaporize from about 25 to about 75 weight percent of the spent metal halide, the oxygen being introduced in an amount sufficient to remove from about 60 to about 90 weight percent of the carbon contained in the spent molten metal halide to produce a fuel gas and regenerated metal halide; and (d) incinerating the spent molten metal halide by combusting carbon and sulfur compounds contained therein.

  11. Thermodynamic modelling of an onsite methanation reactor for upgrading producer gas from commercial small scale biomass gasifiers.

    Science.gov (United States)

    Vakalis, S; Malamis, D; Moustakas, K

    2017-06-26

    Small scale biomass gasifiers have the advantage of having higher electrical efficiency in comparison to other conventional small scale energy systems. Nonetheless, a major drawback of small scale biomass gasifiers is the relatively poor quality of the producer gas. In addition, several EU Member States are seeking ways to store the excess energy that is produced from renewables like wind power and hydropower. A recent development is the storage of energy by electrolysis of water and the production of hydrogen in a process that is commonly known as "power-to-gas". The present manuscript proposes an onsite secondary reactor for upgrading producer gas by mixing it with hydrogen in order to initiate methanation reactions. A thermodynamic model has been developed for assessing the potential of the proposed methanation process. The model utilized input parameters from a representative small scale biomass gasifier and molar ratios of hydrogen from 1:0 to 1:4.1. The Villar-Cruise-Smith algorithm was used for minimizing the Gibbs free energy. The model returned the molar fractions of the permanent gases, the heating values and the Wobbe Index. For mixtures of hydrogen and producer gas on a 1:0.9 ratio the increase of the heating value is maximized with an increase of 78%. For ratios higher than 1:3, the Wobbe index increases significantly and surpasses the value of 30 MJ/Nm 3 . Copyright © 2017 Elsevier Ltd. All rights reserved.

  12. Modelling of a Biomass Gasification Plant Feeding a Hybrid Solid Oxide Fuel Cell and Micro Gas Turbine System

    DEFF Research Database (Denmark)

    Bang-Møller, Christian; Rokni, Masoud

    2009-01-01

    A system level modelling study on two combined heat and power (CHP) systems both based on biomass gasification. One system converts the product gas in a solid oxide fuel cell (SOFC) and the other in a combined SOFC and micro gas turbine (MGT) arrangement. An electrochemical model of the SOFC has...... been developed and calibrated against published data from Topsoe Fuel Cells A/S (TOFC) and Risø National Laboratory. The modelled gasifier is based on an up scaled version of the demonstrated low tar gasifier, Viking, situated at the Technical University of Denmark. The MGT utilizes the unconverted...

  13. Technical and Economic Forecast in Selection of Optimum Biomass and Local Fossil Fuel Application Technology for Thermal Electric Energy Generation

    Directory of Open Access Journals (Sweden)

    I. A. Bokun

    2010-01-01

    Full Text Available The paper provides a technical and economic analysis pertaining to selection of optimum biomass and local fossil fuel application technology for thermal electric energy generation while using a matrix of costs and a method of minimum value. Calculation results give grounds to assert that it is expedient to burn in the boiling layer – 69 % and 31 % of wood pellets and wastes, respectively and 54 % of peat and 46 % of slate stones. A steam and gas unit (SGU can fully operate on peat. Taking into account reorientation on decentralized power supply and increase of small power plants up to 3–5 MW the paper specifies variants of the most efficient technologies for burning biomass and local fossil fuels

  14. Analysis of Indirectly Fired Gas Turbine for Wet Biomass Fuels Based on commercial micro gas turbine data

    DEFF Research Database (Denmark)

    Elmegaard, Brian; Qvale, Einar Bjørn

    2002-01-01

    energy, which has been the practice up to now, the low temperature exhaust gases after having served as drying agent, are lead out into the environment; a simple change of process integration that has a profound effect on the performance. Four different cycles have been studied. These are the Simple IFGT...... fueled by dry biomass assuming negligible pressure loss in the heat exchanger and the combustion chamber, the IFGT fueled with wet biomass (Wet IFGT) assuming no pressure losses, and finally both the Simple and the Wet IFGT incorporating typical data for pressure losses of commercially available micro...... advantages with respect to corrosion and to the environmental friendliness and the quantity of the waste products and their usefulness....

  15. Optimization of radial systems with biomass fueled gas engine from a metaheuristic and probabilistic point of view

    International Nuclear Information System (INIS)

    Ruiz-Rodriguez, F.J.; Gomez-Gonzalez, M.; Jurado, F.

    2013-01-01

    Highlights: ► Loads and distributed generation production are modeled as random variables. ► Distribution system with biomass fueled gas engines. ► Random nature of lower heat value of biomass and load. ► The Cornish–Fisher expansion is used for approximating quantiles of a random variable. ► Computational cost is low enough than that required for Monte Carlo simulation. - Abstract: This paper shows that the technical constraints must be considered in radial distribution networks, where the voltage regulation is one of the primary problems to be dealt in distributed generation systems based on biomass fueled engine. Loads and distributed generation production are modeled as random variables. Results prove that the proposed method can be applied for the keeping of voltages within desired limits at all load buses of a distribution system with biomass fueled gas engines. To evaluate the performance of this distribution system, this paper has developed a probabilistic model that takes into account the random nature of lower heat value of biomass and load. The Cornish–Fisher expansion is used for approximating quantiles of a random variable. This work introduces a hybrid method that utilizes a new optimization method based on swarm intelligence and probabilistic radial load flow. It is demonstrated the reduction in computation time achieved by the more efficient probabilistic load flow in comparison to Monte Carlo simulation. Acceptable solutions are reached in a smaller number of iterations. Therefore, convergence is more rapidly attained and computational cost is significantly lower than that required for Monte Carlo methods.

  16. Federal Financial Incentives to Induce Early Experience Producing Unconventional Liquid Fuels

    Science.gov (United States)

    2008-01-01

    to Induce Early Experience Producing Unconventional Liquid Fuels Frank Camm, James T. Bartis, Charles J. Bushman Prepared for the United States Air... Frank Camm (Frank_Camm@rand.org). v Contents Preface...common in agreements between oil producers and governments outside the United States (Kretzschmar and Kirchner , 2007; see also Metcalf, 2006). These

  17. A stochastic analysis of the decision to produce biomass crops in Ireland

    International Nuclear Information System (INIS)

    Clancy, Daragh; Breen, James P.; Thorne, Fiona; Wallace, Michael

    2012-01-01

    There is increasing interest in biomass crops as an alternative farm activity. However farmer concerns about the production and financial risks associated with growing these crops may be impeding the actual rates of adoption. The uncertainty surrounding risky variables such as the costs of production, yield level, price per tonne and opportunity cost of land make it difficult to accurately calculate the returns to biomass crops. Their lengthy production lifespan may only serve to heighten the level of risk that affects key variables. A stochastic budgeting model is used to estimate distributions of returns from willow and miscanthus in Ireland. The opportunity cost of land is accounted for through the inclusion of the foregone returns from selected conventional agricultural activities. The impact on biomass returns of bioremediation is also examined. The Net Present Values (NPVs) of various biomass investment options are simulated to ascertain the full distribution of possible returns. The results of these simulations are then compared using their respective Cumulative Distribution Functions (CDFs) and the investments are ranked using Stochastic Efficiency with Respect to a Function (SERF). While the distributions of investment returns for miscanthus are wider than those of willow, implying greater risk, the distribution of willow returns is predominantly to the left of zero indicating that such an investment has an extremely high probability of generating a negative return. The results from the SERF analysis show that miscanthus generally has higher certainty equivalents (CEs), and therefore farmers would be more likely to invest in miscanthus rather than willow. -- Highlights: ► We develop a stochastic budgeting model to capture uncertainty in key variables. ► Farmers with higher levels of risk aversion would be unwilling to invest in biomass crops. ► Miscanthus has a greater probability of making a profit than willow. ► Bioremediation can help to offset

  18. Effects of environmental biomass-producing factors on Cd uptake in two Swedish ecotypes of Pinus sylvestris

    International Nuclear Information System (INIS)

    Ekvall, Lars; Greger, Maria

    2003-01-01

    Cadmium uptake in Scots pine seedlings was mainly regulated by biomass production. - A factorial design was used to study direct effects of external biomass-producing factors such as light, temperature and photoperiod on cadmium (Cd) uptake and indirect effects, via change in biomass production in two ecotypes of Scots pine (Pinus silvestris). The aim was to find out if the external factors affect the Cd uptake directly or via change in biomass production, and if the effect differs between ecotypes. Seedlings were grown under 10 combinations of external factors, i.e. temperature (15 and 20 deg. C), light intensity (50 and 200 μmol photons m -2 s -1 ), photoperiod (18 h light/8 h darkness and continuous light) and external Cd concentration (totally 1.88 and 7.50 μmol). The treatment lasted for 18 days and Cd concentrations in roots and shoots were determined by AAS. The results showed that an increased biomass production increased the total Cd uptake but had a dilution effect on the Cd concentration, especially in the root tissues. The external factors tested did not have any direct effects on the Cd uptake, only in the case of Cd translocation to the shoot did the higher temperature show a direct increase, but only in the southern ecotype. The two ecotypes reacted differently in Cd uptake and translocation to the external factors studied. The relative Cd uptake increased with increasing photoperiod in the northern but not in the southern ecotype. The southern ecotype decreased the Cd concentration in the shoot with increased light intensity caused by a dilution effect due to extensive shoot growth of this ecotype. The conclusion is that the uptake in pine seedlings is mainly regulated via biomass production, and not directly by light and temperature and that resulting plant Cd contents to a certain extent depend on plant origin

  19. Research on the combustion, energy and emission parameters of diesel fuel and a biomass-to-liquid (BTL) fuel blend in a compression-ignition engine

    International Nuclear Information System (INIS)

    Rimkus, Alfredas; Žaglinskis, Justas; Rapalis, Paulius; Skačkauskas, Paulius

    2015-01-01

    Highlights: • Researched physical–chemical and performance properties of diesel fuel and BTL blend (85/15 V/V). • BTL additive reduced Brake Specific Fuel Consumption, improved engine efficiency. • Simpler BTL molecular chains and lower C/H ratio reduced CO 2 emission and smokiness. • Higher cetane number of BTL reduced heat release in beginning of combustion and NO x emission. • Advanced start of fuel injection caused reduced fuel consumption and smokiness, increased NO x emission. - Abstract: This paper presents the comparable research results of the physical–chemical and direct injection (DI) diesel engine properties of diesel fuel and BTL (biomass-to-liquid) blend (85/15 V/V). The energy, ecological and in-cylinder parameters were analysed under medium engine speed and brake torque load regimes; the start of fuel injection was also adjusted. After analysis of the engine bench tests and simulation with AVL BOOST software, it was observed that the BTL additive shortened the fuel ignition delay phase, reduced the heat release in the pre-mixed intensive combustion phase, reduced the nitrogen oxide (NO x ) concentration in the engine exhaust gases and reduced the thermal and mechanical load of the crankshaft mechanism. BTL additive reduced the rates of carbon dioxide (CO 2 ), incompletely burned hydrocarbons (HC) emission and smokiness due to its chemical composition and combustion features. BTL also reduced Brake Specific Fuel Consumption (BSFC, g/kW h) and improved engine efficiency (η e ); however, the volumetric fuel consumption changed due to the lower density of BTL. The start of fuel injection was adjusted for maximum engine efficiency; concomitantly, reductions in the CO 2 concentration, HC concentration and smokiness were achieved. However, the NO x and thermo-mechanical engine load increased.

  20. Updraft biomass gasification reactor evaluation of fuel; Reator de gaseificacao de biomassa em fluxo contra corrente para aquecimento de ar de secagem

    Energy Technology Data Exchange (ETDEWEB)

    Santos, Ivanildo da S. dos; Silva, Jadir N. da; Martins, Marcio A. [Universidade Federal de Vicosa (UFV), MG (Brazil)], Emails: ivanildomt@gmail.com, jadir@ufv.br, aredes@ufv.br

    2010-07-01

    Searching for a clean hot air from biomass for on farm applications, a gasification/combustion system was designed, built and evaluated. The system consisted of a countercurrent gasifier, coupled with a combustion chamber that burns the producer gas, and eucalyptus firewood was used as a fuel. Willing to reduce heat losses from the unit as well as to prevent thermal hazardous the unit was totally covered with brick's wall. Initial unit thermal efficiency was of about 56% and it reaches up to 71% at recharge. It was concluded that this system attended the proposed objectives, producing clean hot air that can be used for drying purposes as well as ambient space heating. (author)

  1. Biomass in a sustainable energy system

    International Nuclear Information System (INIS)

    Boerjesson, Paal

    1998-04-01

    In this thesis, aspects of an increase in the utilization of biomass in the Swedish energy system are treated. Modern bioenergy systems should be based on high energy and land use efficiency since biomass resources and productive land are limited. The energy input, including transportation, per unit biomass produced is about 4-5% for logging residues, straw and short rotation forest (Salix). Salix has the highest net energy yield per hectare among the various energy crops cultivated in Sweden. The CO 2 emissions from the production and transportation of logging residues, straw and Salix, are equivalent to 2-3% of those from a complete fuel-cycle for coal. Substituting biomass for fossil fuels in electricity and heat production is, in general, less costly and leads to a greater CO 2 reduction per unit biomass than substituting biomass derived transportation fuels for petrol or diesel. Transportation fuels produced from cellulosic biomass provide larger and less expensive CO 2 emission reductions than transportation fuels from annual crops. Swedish CO 2 emissions could be reduced by about 50% from the present level if fossil fuels are replaced and the energy demand is unchanged. There is a good balance between potential regional production and utilization of biomass in Sweden. Future biomass transportation distances need not be longer than, on average, about 40 km. About 22 TWh electricity could be produced annually from biomass in large district heating systems by cogeneration. Cultivation of Salix and energy grass could be utilized to reduce the negative environmental impact of current agricultural practices, such as the emission of greenhouse gases, nutrient leaching, decreased soil fertility and erosion, and for the treatment of municipal waste and sludge, leading to increased recirculation of nutrients. About 20 TWh biomass could theoretically be produced per year at an average cost of less than 50% of current production cost, if the economic value of these

  2. Biomass in a sustainable energy system

    Energy Technology Data Exchange (ETDEWEB)

    Boerjesson, Paal

    1998-04-01

    In this thesis, aspects of an increase in the utilization of biomass in the Swedish energy system are treated. Modern bioenergy systems should be based on high energy and land use efficiency since biomass resources and productive land are limited. The energy input, including transportation, per unit biomass produced is about 4-5% for logging residues, straw and short rotation forest (Salix). Salix has the highest net energy yield per hectare among the various energy crops cultivated in Sweden. The CO{sub 2} emissions from the production and transportation of logging residues, straw and Salix, are equivalent to 2-3% of those from a complete fuel-cycle for coal. Substituting biomass for fossil fuels in electricity and heat production is, in general, less costly and leads to a greater CO{sub 2} reduction per unit biomass than substituting biomass derived transportation fuels for petrol or diesel. Transportation fuels produced from cellulosic biomass provide larger and less expensive CO{sub 2} emission reductions than transportation fuels from annual crops. Swedish CO{sub 2} emissions could be reduced by about 50% from the present level if fossil fuels are replaced and the energy demand is unchanged. There is a good balance between potential regional production and utilization of biomass in Sweden. Future biomass transportation distances need not be longer than, on average, about 40 km. About 22 TWh electricity could be produced annually from biomass in large district heating systems by cogeneration. Cultivation of Salix and energy grass could be utilized to reduce the negative environmental impact of current agricultural practices, such as the emission of greenhouse gases, nutrient leaching, decreased soil fertility and erosion, and for the treatment of municipal waste and sludge, leading to increased recirculation of nutrients. About 20 TWh biomass could theoretically be produced per year at an average cost of less than 50% of current production cost, if the economic

  3. Influence of carbon-bearing raw material on microfungus Blakeslea Trispora biomass producing

    Directory of Open Access Journals (Sweden)

    L. Myronenko

    2015-05-01

    Full Text Available Introduction. This paper investigates influence of hydrated fullerenes on degree of accumulation bioactive substances of microfungus Blakeslea trispora. Materials and methods. In this research effort detection of fatty-acid composition in amino acids, carotenoids and sterols biomass by means of using methods of high-performance liquid chromatography, adsorption and disjunctive chromatography in thin-layer sorbent and spectrophotometric; gravimetric method; method of direct spectrophotometration in benzene took place. Results and discussion. It has been induced that application of hydrated fullerenes in microfungus Blakeslea trispora nutrient medium promotes increasing accumulation in biomass quantity of carotene on 32,3 %; asparaginic, glutamic acids and leucine. Reproportion carbon to nitrogen by means of adding to microfungus Blakeslea trispora nutrient culture medium hydrated fullerenes did not influence on the biomass amino acid structure any. Obtained data of fatty-acid composition in microfungus Blakeslea trispora lipoid fraction indicate about significant predominance unsaturated fatty acids and, as a result of this, we have advance of use microfungus Blakeslea trispora biomass as a source of biologically active substances for establishing a new kind of prophylactic action goods.

  4. Life-cycle GHG emissions of electricity from syngas produced by pyrolyzing woody biomass

    Science.gov (United States)

    Hongmei Gu; Richard Bergman

    2015-01-01

    Low-value residues from forest restoration activities in the western United States intended to mitigate effects from wildfire, climate change, and pests and disease need a sustainable market to improve the economic viability of treatment. Converting biomass into bioenergy is a potential solution. Life-cycle assessment (LCA) as a sustainable metric tool can assess the...

  5. Mutagenicity and Lung Toxicity of Smoldering vs. Flaming Emissions from Various Biomass Fuels: Implications for Health Effects from Wildland Fires.

    Science.gov (United States)

    Kim, Yong Ho; Warren, Sarah H; Krantz, Q Todd; King, Charly; Jaskot, Richard; Preston, William T; George, Barbara J; Hays, Michael D; Landis, Matthew S; Higuchi, Mark; DeMarini, David M; Gilmour, M Ian

    2018-01-24

    The increasing size and frequency of wildland fires are leading to greater potential for cardiopulmonary disease and cancer in exposed populations; however, little is known about how the types of fuel and combustion phases affect these adverse outcomes. We evaluated the mutagenicity and lung toxicity of particulate matter (PM) from flaming vs. smoldering phases of five biomass fuels, and compared results by equal mass or emission factors (EFs) derived from amount of fuel consumed. A quartz-tube furnace coupled to a multistage cryotrap was employed to collect smoke condensate from flaming and smoldering combustion of red oak, peat, pine needles, pine, and eucalyptus. Samples were analyzed chemically and assessed for acute lung toxicity in mice and mutagenicity in Salmonella . The average combustion efficiency was 73 and 98% for the smoldering and flaming phases, respectively. On an equal mass basis, PM from eucalyptus and peat burned under flaming conditions induced significant lung toxicity potencies (neutrophil/mass of PM) compared to smoldering PM, whereas high levels of mutagenicity potencies were observed for flaming pine and peat PM compared to smoldering PM. When effects were adjusted for EF, the smoldering eucalyptus PM had the highest lung toxicity EF (neutrophil/mass of fuel burned), whereas smoldering pine and pine needles had the highest mutagenicity EF. These latter values were approximately 5, 10, and 30 times greater than those reported for open burning of agricultural plastic, woodburning cookstoves, and some municipal waste combustors, respectively. PM from different fuels and combustion phases have appreciable differences in lung toxic and mutagenic potency, and on a mass basis, flaming samples are more active, whereas smoldering samples have greater effect when EFs are taken into account. Knowledge of the differential toxicity of biomass emissions will contribute to more accurate hazard assessment of biomass smoke exposures. https://doi.org/10

  6. Generation of Electricity and Analysis of Microbial Communities in Wheat Straw Biomass-Powered Microbial Fuel Cells

    DEFF Research Database (Denmark)

    Zhang, Yifeng; Min, Booki; Huang, L.

    2009-01-01

    Electricity generation from wheat straw hydrolysate and the microbial ecology of electricity producing microbial communities developed in two chamber microbial fuel cells (MFCs) were investigated. Power density reached 123 mW/m2 with an initial hydrolysate concentration of 1000 mg-COD/L while...... to improve understanding and optimizing the electricity generation in microbial fuel cells....

  7. Conceptual evaluation of hybrid energy system comprising wind-biomass-nuclear plants for load balancing and for production of renewable synthetic transport fuels

    International Nuclear Information System (INIS)

    Carlsson, Johan; Purvins, Arturs; Papaioannou, Ioulia T.; Shropshire, David; Cherry, Robert S.

    2014-01-01

    Future energy systems will increasingly need to integrate variable renewable energy in order to reduce greenhouse gas emissions from power production. Addressing this trend the present paper studies how a hybrid energy systems comprising aggregated wind farms, a biomass processing plant, and a nuclear cogeneration plant could support high renewable energy penetration. The hybrid energy system operates so that its electrical output tends to meet demand. This is achieved mainly through altering the heat-to-power ratio of the nuclear reactor and by using excess electricity for hydrogen production through electrolysis. Hybrid energy systems with biomass treatment processes, i.e. drying, torrefaction, pyrolysis and synthetic fuel production were evaluated. It was shown that the studied hybrid energy system comprising a 1 GWe wind farm and a 347 MWe nuclear reactor could closely follow the power demand profile with a standard deviation of 34 MWe. In addition, on average 600 m 3 of bio-gasoline and 750 m 3 bio-diesel are produced daily. The reduction of greenhouse gas emissions of up to 4.4 MtCO 2 eq annually compared to power generation and transport using conventional fossil fuel sources. (author)

  8. The feasibility of synthetic fuels in renewable energy systems

    DEFF Research Database (Denmark)

    Ridjan, Iva; Mathiesen, Brian Vad; Connolly, David

    2012-01-01

    . Nowadays, biofuels along with electricity are proposed as one of the main options for replacing fossil fuels in the transport sector. The main reasons for avoiding the direct usage of biomass, i.e. producing biomass derived fuels, are land use shortage, limited biomass availability, interference with food...

  9. The feasibility of synthetic fuels in renewable energy systems

    DEFF Research Database (Denmark)

    Ridjan, Iva; Mathiesen, Brian Vad; Connolly, D.

    2013-01-01

    , biofuels along with electricity are proposed as one of the main options for replacing fossil fuels in the transport sector. The main reasons for avoiding the direct usage of biomass, i.e. producing biomass derived fuels, are land use shortages, limited biomass availability, interference with food supplies...

  10. Feasibility of synthetic fuels in renewable energy systems

    DEFF Research Database (Denmark)

    Ridjan, Iva; Mathiesen, Brian Vad; Connolly, David

    . Nowadays, biofuels are proposed as one of the main options for replacing fossil fuels in the transport sector, along with electricity. The main reasons for avoiding the direct usage of biomass in the transport sector, i.e. producing biomass derived fuels, are land use shortage, limited biomass availability...

  11. Chemicals Derived from Biomass Thermolysis and Gasification

    Energy Technology Data Exchange (ETDEWEB)

    Schaidle, Joshua A [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Talmadge, Michael S [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Biddy, Mary J [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Nimlos, Mark R [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Bratis, Adam D [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-07-14

    The United States has the potential to sustainably produce over 1 billion dry tons of nonfood biomass per year by 2030. While conversion of this biomass into fuels has garnished significant attention, these renewable feedstocks can also be converted into valuable chemicals. Analogous to petroleum refining, the coproduction of fuels and chemicals from biomass enables more complete utilization of the feedstock and supports the growth of a bio-economy by improving biorefinery economics. This chapter provides an overview of biomass thermolysis and gasification technologies, highlights existing and future chemical production opportunities, and elaborates on specific challenges associated with product separation and purification.

  12. Pulmonary Tuberculosis Is Associated With Biomass Fuel Use Among Rural Women in Pakistan: An Age- and Residence-Matched Case-Control Study.

    Science.gov (United States)

    Rabbani, Unaib; Sahito, Ambreen; Nafees, Asaad Ahmed; Kazi, Ambreen; Fatmi, Zafar

    2017-04-01

    Facility-based, age- and residential area-matched case-control study was conducted in Sindh, Pakistan to determine association between biomass fuel use for cooking and pulmonary tuberculosis (TB). Cases were women with pulmonary TB, and controls were those suffering from other diseases. Current users of biomass fuel were at higher risk of pulmonary TB (adjusted matched odds ratio [mOR] = 3.0; 95% CI = 1.1-4.9) compared with nonusers. In comparison with former biomass users (women not using biomass for >10 years), recent biomass users (women who switched from biomass to nonbiomass ≤10 years ago), and current (lifetime) users were at a higher risk in a dose-response manner (adjusted mOR = 2.8, 95% CI = 0.9-8.2 and adjusted mOR = 3.9, 95% CI = 1.4-10.7, respectively). Population attributable fraction for TB related to biomass fuel use was 40.6% (95% CI = 35.5%-45.7%). This study strengthens the evidence that biomass fuel use for cooking is associated with pulmonary TB and risk increases with duration of exposure.

  13. Renewable liquid fuels from catalytic reforming of biomass-derived oxygenated hydrocarbons

    Science.gov (United States)

    Barrett, Christopher J.

    Diminishing fossil fuel reserves and growing concerns about global warming require the development of sustainable sources of energy. Fuels for use in the transportation sector must have specific physical properties that allow for efficient distribution, storage, and combustion; these requirements are currently fulfilled by petroleum-derived liquid fuels. The focus of this work has been the development of two new biofuels that have the potential to become widely used transportation fuels from carbohydrate intermediates. Our first biofuel has cetane numbers ranging from 63 to 97 and is comprised of C7 to C15 straight chain alkanes. These alkanes can be blended with diesel like fuels or with P-series biofuel. Production involves a solid base catalyzed aldol condensation with mixed Mg-Al-oxide between furfural or 5-hydroxymethylfurfural (HMF) and acetone, followed by hydrogenation over Pd/Al2O3, and finally hydrogenation/dehydration over Pt/SiO2-Al2O3. Water was the solvent for all process steps, except for the hydrogenation/dehydration stage where hexadecane was co-fed to spontaneously separate out all alkane products and eliminate the need for energy intensive distillation. A later optimization identified Pd/MgO-ZrO2 as a hydrothermally stable bifunctional catalyst to replace Pd/Al2O3 and the hydrothermally unstable Mg-Al-oxide catalysts along with optimizing process parameters, such as temperature and molar ratios of reactants to maximize yields to heavier alkanes. Our second biofuel involved creating an improved process to produce HMF through the acid-catalyzed dehydration of fructose in a biphasic reactor. Additionally, we developed a technique to further convert HMF into 2,5-dimethylfuran (DMF) by hydrogenolysis of C-O bonds over a copper-ruthenium catalyst. DMF has many properties that make it a superior blending agent to ethanol: it has a high research octane number at 119, a 40% higher energy density than ethanol, 20 K higher boiling point, and is insoluble in

  14. Marker-Trait Association for Biomass Yield of Potential Bio-fuel Feedstock Miscanthus sinensis from Southwest China.

    Science.gov (United States)

    Nie, Gang; Huang, Linkai; Zhang, Xinquan; Taylor, Megan; Jiang, Yiwei; Yu, Xiaoqing; Liu, Xinchun; Wang, Xinyu; Zhang, Yajie

    2016-01-01

    As a great potential bio-fuel feedstock, the genus Miscanthus has been widely studied around the world, especially Miscanthus × giganteus owing to its high biomass yield in Europe and North America. However, the narrow genetic basis and sterile characteristics of M. × giganteus have become a limitation for utilization and adaptation to extreme climate conditions. In this study, we focused on one of the progenitors of M. × giganteus, Miscanthus sinensis, which was originally distributed in East Asia with abundant genetic resources and comparable biomass yield potential to M. × giganteus in some areas. A collection of 138 individuals was selected for conducting a 3-year trial of biomass production and analyzed by using 104 pairs of SRAP, ISAP, and SSR primers for genetic diversity as well as marker-trait association. Significant differences in biomass yield and related traits were observed among individuals. Tiller number, fresh biomass yield per plant and dry biomass yield per plant had a high level of phenotypic variation among individuals and the coefficient of variation were all above 40% in 2011, 2012, and 2013. The majority of the traits had a significant correlation with the biomass yield except for the length and width of flag leaves. Plant height was a highly stable trait correlated with biomass yield. A total of 1059 discernible loci were detected by markers across individuals. The population structure (Q) and cluster analyses identified three subpopulations in the collection and family relative kinship (K) represented high gene flow among M. sinensis populations from Southwest China. Model testing identified that Q+K was the best model for describing the associations between the markers and traits, compared to the simple linear, Q or K model. Using the Q+K model, 12 significant associations (P < 0.001) were identified including four markers with plant height and one with biomass yield. Such associations would ser