Process and apparatus for the conversion of biomass

NARCIS (Netherlands)

Bakker, R.R.C.; Hazewinkel, J.H.O.; Groenestijn, van J.W.

2008-01-01

The invention is directed to a process for the conversion of cellulosic biomass, in particular lignocellulose-containing biomass into fermentable sugars. The invention is further directed to apparatus suitable for carrying out such processes. According to the invention biomass is converted into

Thermochemical conversion of microalgal biomass into biofuels: a review.

Science.gov (United States)

Chen, Wei-Hsin; Lin, Bo-Jhih; Huang, Ming-Yueh; Chang, Jo-Shu

2015-05-01

Following first-generation and second-generation biofuels produced from food and non-food crops, respectively, algal biomass has become an important feedstock for the production of third-generation biofuels. Microalgal biomass is characterized by rapid growth and high carbon fixing efficiency when they grow. On account of potential of mass production and greenhouse gas uptake, microalgae are promising feedstocks for biofuels development. Thermochemical conversion is an effective process for biofuel production from biomass. The technology mainly includes torrefaction, liquefaction, pyrolysis, and gasification. Through these conversion technologies, solid, liquid, and gaseous biofuels are produced from microalgae for heat and power generation. The liquid bio-oils can further be upgraded for chemicals, while the synthesis gas can be synthesized into liquid fuels. This paper aims to provide a state-of-the-art review of the thermochemical conversion technologies of microalgal biomass into fuels. Detailed conversion processes and their outcome are also addressed. Copyright © 2014 Elsevier Ltd. All rights reserved.

Process and apparatus for conversion of biomass

NARCIS (Netherlands)

Bakker, R.R.C.; Hazewinkel, J.H.O.; Groenestijn, van J.W.

2006-01-01

The invention is directed to a process for the conversion of biomass, in particular lignocellulose-containing biomass into a product that may be further processes in a fermentation step. The invention is further directed to apparatus suitable for carrying out such processes. According to the

Photon up-conversion increases biomass yield in Chlorella vulgaris.

Science.gov (United States)

Menon, Kavya R; Jose, Steffi; Suraishkumar, Gadi K

2014-12-01

Photon up-conversion, a process whereby lower energy radiations are converted to higher energy levels via the use of appropriate phosphor systems, was employed as a novel strategy for improving microalgal growth and lipid productivity. Photon up-conversion enables the utilization of regions of the solar spectrum, beyond the typical photosynthetically active radiation, that are usually wasted or are damaging to the algae. The effects of up-conversion of red light by two distinct sets of up-conversion phosphors were studied in the model microalgae Chlorella vulgaris. Up-conversion by set 1 phosphors led to a 2.85 fold increase in biomass concentration and a 3.2 fold increase in specific growth rate of the microalgae. While up-conversion by set 2 phosphors resulted in a 30% increase in biomass and 12% increase in specific intracellular neutral lipid, while the specific growth rates were comparable to that of the control. Furthermore, up-conversion resulted in higher levels of specific intracellular reactive oxygen species in C. vulgaris. Up-conversion of red light (654 nm) was shown to improve biomass yields in C. vulgaris. In principle, up-conversion can be used to increase the utilization range of the electromagnetic spectrum for improved cultivation of photosynthetic systems such as plants, algae, and microalgae. Copyright © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

CFD Studies on Biomass Thermochemical Conversion

Directory of Open Access Journals (Sweden)

Lifeng Yan

2008-06-01

Full Text Available Thermochemical conversion of biomass offers an efficient and economically process to provide gaseous, liquid and solid fuels and prepare chemicals derived from biomass. Computational fluid dynamic (CFD modeling applications on biomass thermochemical processes help to optimize the design and operation of thermochemical reactors. Recent progression in numerical techniques and computing efficacy has advanced CFD as a widely used approach to provide efficient design solutions in industry. This paper introduces the fundamentals involved in developing a CFD solution. Mathematical equations governing the fluid flow, heat and mass transfer and chemical reactions in thermochemical systems are described and sub-models for individual processes are presented. It provides a review of various applications of CFD in the biomass thermochemical process field.

Role of Bioreactors in Microbial Biomass and Energy Conversion

Energy Technology Data Exchange (ETDEWEB)

Zhang, Liang [Chongqing University, Chongqing, China; Zhang, Biao [Chongqing University, Chongqing, China; Zhu, Xun [Chongqing University, Chongqing, China; Chang, Haixing [Chongqing University of Technology; Ou, Shawn [ORNL; Wang, HONG [Chongqing University, Chongqing, China

2018-04-01

Bioenergy is the world’s largest contributor to the renewable and sustainable energy sector, and it plays a significant role in various energy industries. A large amount of research has contributed to the rapidly evolving field of bioenergy and one of the most important topics is the use of the bioreactor. Bioreactors play a critical role in the successful development of technologies for microbial biomass cultivation and energy conversion. In this chapter, after a brief introduction to bioreactors (basic concepts, configurations, functions, and influencing factors), the applications of the bioreactor in microbial biomass, microbial biofuel conversion, and microbial electrochemical systems are described. Importantly, the role and significance of the bioreactor in the bioenergy process are discussed to provide a better understanding of the use of bioreactors in managing microbial biomass and energy conversion.

Process Design and Economics for the Conversion of Lignocellulosic Biomass to Hydrocarbons: Dilute-Acid and Enzymatic Deconstruction of Biomass to Sugars and Catalytic Conversion of Sugars to Hydrocarbons

Energy Technology Data Exchange (ETDEWEB)

Davis, R. [National Renewable Energy Lab. (NREL), Golden, CO (United States); Tao, L. [National Renewable Energy Lab. (NREL), Golden, CO (United States); Scarlata, C. [National Renewable Energy Lab. (NREL), Golden, CO (United States); Tan, E. C. D. [National Renewable Energy Lab. (NREL), Golden, CO (United States); Ross, J. [Harris Group Inc., New York, NY (United States); Lukas, J. [Harris Group Inc., New York, NY (United States); Sexton, D. [Harris Group Inc., New York, NY (United States)

2015-03-01

This report describes one potential conversion process to hydrocarbon products by way of catalytic conversion of lignocellulosic-derived hydrolysate. This model leverages expertise established over time in biomass deconstruction and process integration research at NREL, while adding in new technology areas for sugar purification and catalysis. The overarching process design converts biomass to die die diesel- and naphtha-range fuels using dilute-acid pretreatment, enzymatic saccharification, purifications, and catalytic conversion focused on deoxygenating and oligomerizing biomass hydrolysates.

FY 2000 report on the results of the survey on the biomass-derived energy conversion technology. III; 2000 nendo biomass shigen wo genryo to suru energy henkan gijutsu ni kansuru chosa. 3

Energy Technology Data Exchange (ETDEWEB)

NONE

2001-03-01

In relation to the biomass-derived energy conversion technology which was regarded as promising from the results of the survey already made, the survey was made on the present situation and subjects of the technical development, social needs, energy efficiency, economical efficiency and the future. Studies were conducted on the development of technology for effective biomass utilization and the conceptual design and evaluation of a system for effective biomass utilization. As to the effective biomass utilization technology, the survey was made on the biomass combustion power generation technology/gasification power generation technology, gasification methanol synthesis of biomass, biomass gasification dimethyl ether synthesis, technology of ethanol production by alcohol fermentation via saccharification of biomass, methy-esterification of grease biomass, especially palm oil, and diesel oil production via reformation of by-product glycerin, and energy production from biomass using super- (sub- ) critical reaction. As to the system for effective biomass utilization, the survey was carried out of the regional outline, resource amount and sampling amount, selection of the conversion technology, and economical efficiency of Takatsuki city, Osaka, Shimokawa town, Hokkaido, Yufutsu/Hidaka region, Hokkaido, and Aogaki town, Hyogo. (NEDO)

Energy conversion of biomass in coping with global warming

Energy Technology Data Exchange (ETDEWEB)

Yokoyama, Shin-ya; Ogi, Tomoko; Minowa, Tomoaki [National Inst. for Resources and Environment, Tsukuba, Ibaraki (Japan)

1993-12-31

The main purpose of the present paper is to propose energy conversion technologies of biomass in coping with global warming. Among thermochemical conversion, liquid fuel production by high pressure process is mainly introduced. Biomass is a term used to describe materials of biological origin, either purpose-grown or arising as by-products, residues or wastes from forestry, agriculture and food processing. Such biomass is a renewable energy sources dependent on solar energy. Through photosynthesis, plants converts carbon dioxide into organic materials used in their growth. Energy can be recovered from the plant materials by several processes, the simplest way is burning in air. As far as biomass is used in this way, there is no atmospheric accumulation of carbon dioxide making no effect on the Greenhouse Effect, provided that the cycle of regrowth and burning is sustained.

Review of the direct thermochemical conversion of lignocellulosic biomass for liquid fuels

Directory of Open Access Journals (Sweden)

Jianchun JIANG,Junming XU,Zhanqian SONG

2015-03-01

Full Text Available Increased demand for liquid transportation fuels, environmental concerns and depletion of petroleum resources requires the development of efficient conversion technologies for production of second-generation biofuels from non-food resources. Thermochemical approaches hold great potential for conversion of lignocellulosic biomass into liquid fuels. Direct thermochemical processes convert biomass into liquid fuels in one step using heat and catalysts and have many advantages over indirect and biological processes, such as greater feedstock flexibility, integrated conversion of whole biomass, and lower operation costs. Several direct thermochemical processes are employed in the production of liquid biofuels depending on the nature of the feedstock properties: such as fast pyrolysis/liquefaction of lignocellulosic biomass for bio-oil, including upgrading methods, such as catalytic cracking and hydrogenation. Owing to the substantial amount of liquid fuels consumed by vehicular transport, converting biomass into drop-in liquid fuels may reduce the dependence of the fuel market on petroleum-based fuel products. In this review, we also summarize recent progress in technologies for large-scale equipment for direct thermochemical conversion. We focus on the technical aspects critical to commercialization of the technologies for production of liquid fuels from biomass, including feedstock type, cracking catalysts, catalytic cracking mechanisms, catalytic reactors, and biofuel properties. We also discuss future prospects for direct thermochemical conversion in biorefineries for the production of high grade biofuels.

Biomass Feedstock and Conversion Supply System Design and Analysis

Energy Technology Data Exchange (ETDEWEB)

Jacobson, Jacob J. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Roni, Mohammad S. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Lamers, Patrick [Idaho National Lab. (INL), Idaho Falls, ID (United States); Cafferty, Kara G. [Idaho National Lab. (INL), Idaho Falls, ID (United States)

2014-09-01

Idaho National Laboratory (INL) supports the U.S. Department of Energy’s bioenergy research program. As part of the research program INL investigates the feedstock logistics economics and sustainability of these fuels. A series of reports were published between 2000 and 2013 to demonstrate the feedstock logistics cost. Those reports were tailored to specific feedstock and conversion process. Although those reports are different in terms of conversion, some of the process in the feedstock logistic are same for each conversion process. As a result, each report has similar information. A single report can be designed that could bring all commonality occurred in the feedstock logistics process while discussing the feedstock logistics cost for different conversion process. Therefore, this report is designed in such a way that it can capture different feedstock logistics cost while eliminating the need of writing a conversion specific design report. Previous work established the current costs based on conventional equipment and processes. The 2012 programmatic target was to demonstrate a delivered biomass logistics cost of $55/dry ton for woody biomass delivered to fast pyrolysis conversion facility. The goal was achieved by applying field and process demonstration unit-scale data from harvest, collection, storage, preprocessing, handling, and transportation operations into INL’s biomass logistics model. The goal of the 2017 Design Case is to enable expansion of biofuels production beyond highly productive resource areas by breaking the reliance of cost-competitive biofuel production on a single, low-cost feedstock. The 2017 programmatic target is to supply feedstock to the conversion facility that meets the in-feed conversion process quality specifications at a total logistics cost of $80/dry T. The $80/dry T. target encompasses total delivered feedstock cost, including both grower payment and logistics costs, while meeting all conversion in-feed quality targets

Review and analysis of the 1980-1989 biomass thermochemical conversion program

Energy Technology Data Exchange (ETDEWEB)

Stevens, D.J.

1994-09-01

In the period between 1980 and 1989, the U.S. Department of Energy (DOE) sponsored research and development projects through its Biomass Thermochemical Conversion (BTC) Program. Thermochemical conversion technologies use elevated temperatures to convert biomass into more useful forms of energy such as fuel gases or transportation fuels. The BTC Program included a wide range of biomass conversion projects in the areas of gasification, pyrolysis, liquefaction, and combustion. This work formed the basis of the present DOE research and development efforts on advanced liquid fuel and power generation systems. At the beginning of Fiscal Year 1989, the management of the BTC Program was transferred from Pacific Northwest Laboratory (PNL) to National Renewable Energy Laboratory (NREL, formerly Solar Energy Research Institute). This document presents a summary of the research which was performed under the BTC Program during the 1981-1989 time frame. The document consists of an analysis of the research projects which were funded by the BTC Program and a bibliography of published documents. This work will help ensure that information from PNL`s BTC Program is available to those interested in biomass conversion technologies. The background of the BTC Program is discussed in the first chapter of this report. In addition, a brief summary of other related biomass research and development programs funded by the U.S. Department of Energy and others is presented with references where additional information can be found. The remaining chapters of the report present a detailed summary of the research projects which were funded by the BTC Program. The progress which was made on each project is summarized, the overall impact on biomass conversion is discussed, and selected references are provided.

A techno-economic evaluation of a biomass energy conversion park

Energy Technology Data Exchange (ETDEWEB)

Van Dael, M.; Van Passel, S.; Witters, N. [Centre for Environmental Sciences, Hasselt University, Agoralaan Gebouw D, 3590 Diepenbeek (Belgium); Pelkmans, L.; Guisson, R. [VITO, Boeretang 200, 2400 Mol (Belgium); Reumermann, P. [BTG Biomass Technology Group, Josink Esweg 34, 7545 PN Enschede (Netherlands); Marquez Luzardo, N. [School of Life Sciences and Environmental Technology, Avans Hogeschool, Hogeschoollaan 1, 4800 RA Breda (Netherlands); Broeze, J. [Agrotechnology and Food Sciences Group, Wageningen University, Bomenweg 2, 6703 HD Wageningen (Netherlands)

2013-04-15

Biomass as a renewable energy source has many advantages and is therefore recognized as one of the main renewable energy sources to be deployed in order to attain the target of 20% renewable energy use of final energy consumption by 2020 in Europe. In this paper the concept of a biomass Energy Conversion Park (ECP) is introduced. A biomass ECP can be defined as a synergetic, multi-dimensional biomass conversion site with a highly integrated set of conversion technologies in which a multitude of regionally available biomass (residue) sources are converted into energy and materials. A techno-economic assessment is performed on a case study in the Netherlands to illustrate the concept and to comparatively assess the highly integrated system with two mono-dimensional models. The three evaluated models consist of (1) digestion of the organic fraction of municipal solid waste, (2) co-digestion of manure and co-substrates, and (3) integration. From a socio-economic point of view it can be concluded that it is economically and energetically more interesting to invest in the integrated model than in two separate models. The integration is economically feasible and environmental benefits can be realized. For example, the integrated model allows the implementation of a co-digester. Unmanaged manure would otherwise represent a constant pollution risk. However, from an investor's standpoint one should firstly invest in the municipal solid waste digester since the net present value (NPV) of this mono-dimensional model is higher than that of the multi-dimensional model. A sensitivity analysis is performed to identify the most influencing parameters. Our results are of interest for companies involved in the conversion of biomass. The conclusions are useful for policy makers when deciding on policy instruments concerning manure processing or biogas production.

Biomass recalcitrance: a multi-scale, multi-factor, and conversion-specific property.

Science.gov (United States)

McCann, Maureen C; Carpita, Nicholas C

2015-07-01

Recalcitrance of plant biomass to enzymatic hydrolysis for biofuel production is thought to be a property conferred by lignin or lignin-carbohydrate complexes. However, chemical catalytic and thermochemical conversion pathways, either alone or in combination with biochemical and fermentative pathways, now provide avenues to utilize lignin and to expand the product range beyond ethanol or butanol. To capture all of the carbon in renewable biomass, both lignin-derived aromatics and polysaccharide-derived sugars need to be transformed by catalysts to liquid hydrocarbons and high-value co-products. We offer a new definition of recalcitrance as those features of biomass which disproportionately increase energy requirements in conversion processes, increase the cost and complexity of operations in the biorefinery, and/or reduce the recovery of biomass carbon into desired products. The application of novel processing technologies applied to biomass reveal new determinants of recalcitrance that comprise a broad range of molecular, nanoscale, and macroscale factors. Sampling natural genetic diversity within a species, transgenic approaches, and synthetic biology approaches are all strategies that can be used to select biomass for reduced recalcitrance in various pretreatments and conversion pathways. © The Author 2015. Published by Oxford University Press on behalf of the Society for Experimental Biology. All rights reserved. For permissions, please email: journals.permissions@oup.com.

Potential and challenges of zeolite chemistry in the catalytic conversion of biomass.

Science.gov (United States)

Ennaert, Thijs; Van Aelst, Joost; Dijkmans, Jan; De Clercq, Rik; Schutyser, Wouter; Dusselier, Michiel; Verboekend, Danny; Sels, Bert F

2016-02-07

Increasing demand for sustainable chemicals and fuels has pushed academia and industry to search for alternative feedstocks replacing crude oil in traditional refineries. As a result, an immense academic attention has focused on the valorisation of biomass (components) and derived intermediates to generate valuable platform chemicals and fuels. Zeolite catalysis plays a distinct role in many of these biomass conversion routes. This contribution emphasizes the progress and potential in zeolite catalysed biomass conversions and relates these to concepts established in existing petrochemical processes. The application of zeolites, equipped with a variety of active sites, in Brønsted acid, Lewis acid, or multifunctional catalysed reactions is discussed and generalised to provide a comprehensive overview. In addition, the feedstock shift from crude oil to biomass involves new challenges in developing fields, like mesoporosity and pore interconnectivity of zeolites and stability of zeolites in liquid phase. Finally, the future challenges and perspectives of zeolites in the processing of biomass conversion are discussed.

2011 Biomass Program Platform Peer Review: Biochemical Conversion

Energy Technology Data Exchange (ETDEWEB)

Pezzullo, Leslie [Office of Energy Efficiency and Renewable Energy (EERE), Washington, DC (United States)

2012-02-01

This document summarizes the recommendations and evaluations provided by an independent external panel of experts at the 2011 U.S. Department of Energy Biomass Program’s Biochemical Conversion Platform Review meeting.

2011 Biomass Program Platform Peer Review. Thermochemical Conversion

Energy Technology Data Exchange (ETDEWEB)

Grabowski, Paul E. [Office of Energy Efficiency and Renewable Energy (EERE), Washington, DC (United States)

2012-02-01

This document summarizes the recommendations and evaluations provided by an independent external panel of experts at the 2011 U.S. Department of Energy Biomass Program’s Thermochemical Conversion Platform Review meeting.

Recent patents on genetic modification of plants and microbes for biomass conversion to biofuels.

Science.gov (United States)

Lubieniechi, Simona; Peranantham, Thinesh; Levin, David B

2013-04-01

Development of sustainable energy systems based on renewable biomass feedstocks is now a global effort. Lignocellulosic biomass contains polymers of cellulose, hemicellulose, and lignin, bound together in a complex structure. Liquid biofuels, such as ethanol, can be made from biomass via fermentation of sugars derived from the cellulose and hemicellulose within lignocellulosic materials, but pre-treatment of the biomass to release sugars for microbial conversion is a significant barrier to commercial success of lignocellulosic biofuel production. Strategies to reduce the energy and cost inputs required for biomass pre-treatment include genetic modification of plant materials to reduce lignin content. Significant efforts are also underway to create recombinant microorganisms capable of converting sugars derived from lignocellulosic biomass to a variety of biofuels. An alternative strategy to reduce the costs of cellulosic biofuel production is the use of cellulolytic microorganisms capable of direct microbial conversion of ligno-cellulosic biomass to fuels. This paper reviews recent patents on genetic modification of plants and microbes for biomass conversion to biofuels.

Complex thermal energy conversion systems for efficient use of locally available biomass

International Nuclear Information System (INIS)

Kalina, Jacek

2016-01-01

This paper is focused on a theoretical study in search for new technological solutions in the field of electricity generation from biomass in small-scale distributed cogeneration systems. The purpose of this work is to draw readers' attention to possibilities of design complex multi-component hybrid and combined technological structures of energy conversion plants for effective use of locally available biomass resources. As an example, there is presented analysis of cogeneration system that consists of micro-turbine, high temperature fuel cell, inverted Bryton cycle module and biomass gasification island. The project assumes supporting use of natural gas and cooperation of the plant with a low-temperature district heating network. Thermodynamic parameters, energy conversion effectiveness and economic performance are examined. Results show relatively high energy conversion performance and on the other hand weak financial indices of investment projects at the current level of energy prices. It is however possible under certain conditions to define an optimistic business model that leads to a feasible project. - Highlights: • Concept of biomass energy conversion plant is proposed and theoretically analysed. • MCFC type fuel cell is fuelled with biomass gasification gas. • Natural gas fired microturbine is considered as a source of continuous power. • Inverted Bryton Cycle is considered for utilisation of high temperature exhaust gas.

Effect of biomass feedstock chemical and physical properties on energy conversion processes: Volume 1, Overview

Energy Technology Data Exchange (ETDEWEB)

Butner, R.S.; Elliott, D.C.; Sealock, L.J. Jr.; Pyne, J.W.

1988-12-01

Pacific Northwest Laboratory has completed an initial investigation of the effects of physical and chemical properties of biomass feedstocks relative to their performance in biomass energy conversion systems. Both biochemical conversion routes (anaerobic digestion and ethanol fermentation) and thermochemical routes (combustion, pyrolysis, and gasification) were included in the study. Related processes including chemical and physical pretreatment to improve digestibility, and size and density modification processes such as milling and pelletizing were also examined. This overview report provides background and discussion of feedstock and conversion relationships, along with recommendations for future research. The recommendations include (1) coordinate production and conversion research programs; (2) quantify the relationship between feedstock properties and conversion priorities; (3) develop a common framework for evaluating and characterizing biomass feedstocks; (4) include conversion effects as part of the criteria for selecting feedstock breeding programs; and (5) continue emphasis on multiple feedstock/conversion options for biomass energy systems. 9 refs., 3 figs., 2 tabs.

Research and evaluation of biomass resources/conversion/utilization systems. Biomass allocation model. Volume 1: Test and appendices A & B

Science.gov (United States)

Stringer, R. P.; Ahn, Y. K.; Chen, H. T.; Helm, R. W.; Nelson, E. T.; Shields, K. J.

1981-08-01

A biomass allocation model was developed to show the most profitable combination of biomass feedstocks, thermochemical conversion processes, and fuel products to serve the seasonal conditions in a regional market. This optimization model provides a tool for quickly calculating which of a large number of potential biomass missions is the most profitable mission. Other components of the system serve as a convenient storage and retrieval mechanism for biomass marketing and thermochemical conversion processing data. The system can be accessed through the use of a computer terminal, or it could be adapted to a microprocessor. A User's Manual for the system is included. Biomass derived fuels included in the data base are the following: medium Btu gas, low Btu gas, substitute natural gas, ammonia, methanol, electricity, gasoline, and fuel oil.

Communal biomass conversion plants. From idea to reality

International Nuclear Information System (INIS)

1995-11-01

The first Danish biomass conversion plant for the production of methane was built in the nineteen seventies. It was just a little plant based on manure slurries from a local herd of farm animals. It was not until the nineteen eighties that larger plants were established so that enough methane could be produced as part fuels for decentral district heating and/or cogeneration plants. By November 1995 there were 15 communal biomass conversion plants producing methane in Denmark, three more plants were in the course of establishment and a number of similar projects were on the drawing board. The history of this development is narrated and plans for the future are indicated. The document also deals with the technological aspects, operational economics, environmental impacts, resources and re-use, wastes used as fertilizers, household organic wastes and sewage slam, standards of hygiene and reduction of infection risks, exports and commercial development and socio-economic evaluations in addition to areas within this field which need special attention in the very near future. It is concluded that the economics of Danish biomass conversion plants have improved significantly since 1987, and many older plants have been brought right up to date. Improvements in technology and an increase in the supply of industrial wastes have increased production. Details of the basis of many other betterments that have taken place in recent years are also given. (AB) 27 refs

THERMO-MECHANICAL PULPING AS A PRETREATMENT FOR AGRICULTURAL BIOMASS FOR BIOCHEMICAL CONVERSION

Directory of Open Access Journals (Sweden)

Ronalds W. Gonzalez

2011-03-01

Full Text Available The use of thermo-mechanical pulping (TMP, an existing and well known technology in the pulp and paper industry, is proposed as a potential pretreatment pathway of agriculture biomass for monomeric sugar production in preparation for further fermentation into alcohol species. Three agricultural biomass types, corn stover, wheat straw, and sweet sorghum bagasse, were pretreated in a TMP unit under two temperature conditions, 160 ºC and 170 ºC, and hydrolyzed using cellulase at 5, 10, and 20 FPU/g OD biomass. Wheat straw biomass was further pretreated at different conditions including: i soaking with acetic acid, ii longer steaming residence time (15 and 30 min, and iii refined at lower disk gap (0.0508 and 0.1524 mm. Preliminary results showed that carbohydrate conversion increased from 25% to 40% when the TMP temperature was increased from 160 to 170 ºC. Carbohydrate conversion was relatively similar for the three biomasses under the same pretreatment conditions and enzyme loading. Acetic acid soaking and refining at a reduce disk gap increases carbohydrate conversion. Further studies within this technological field to identify optimum process and TMP conditions for pretreatment are suggested.

Fiscal 1998 research report. Research on energy conversion technology using biomass resources; 1998 nendo chosa hokokusho. Biomass shigen wo genryo to suru energy henkan gijutsu ni kansuru chosa

Energy Technology Data Exchange (ETDEWEB)

NONE

1999-03-01

Feasibility study was made on construction of the new energy production system by thermochemical conversion or combination of thermochemical and biological conversions of agricultural, fishery and organic waste system biomass resources. This report first outlines types and characteristics of biomass over the world, proposes the classification method of biomass from the viewpoint of biomass energy use, and shows the introduction scenario of biomass energy. The energy potential is calculated of agricultural waste, forestry waste and animal waste as the most promising biomass energy resources, and the biomass energy potential of energy plantation is estimated. The present and future of biochemical energy conversion technologies are viewed. The present and future of thermochemical energy conversion technologies are also viewed. Through evaluation of every conversion technology, the difference in feature between each conversion technology was clarified, and the major issues for further R and D were showed. (NEDO)

Biomass Conversion in Ionic Liquids - in-situ Investigations

DEFF Research Database (Denmark)

Kunov-Kruse, Andreas Jonas

Due to rising oil prices and global warming caused by CO2 emissions, there is an increased demand for new types of fuels and chemicals derived from biomass. This thesis investigates catalytic conversion of cellulose into sugars in ionic liquids and the important platform chemical 5-hydroxymethylf......Due to rising oil prices and global warming caused by CO2 emissions, there is an increased demand for new types of fuels and chemicals derived from biomass. This thesis investigates catalytic conversion of cellulose into sugars in ionic liquids and the important platform chemical 5......-hydroxymethylfurfural (HMF). The thesis focuses on kinetic and mechanistic investigations using new in-situ FTIR spectroscopic methods based on the ATR-principle. At first the kinetics of cellulose hydrolysis and the simultaneously HMF formation was investigated in the ionic liquid 1-butyl-2,3-dimethylimidazolium...... activation energies suggest that the ionic liquid acts co-catalytic by stabilizing the oxocarbenium transition state. The chromium catalyzed conversion of glucose to HMF in ionic liquid 1-butyl-3-methylimidazolium chloride with CrCl3⋅6H2O and CrCl2 as catalysts was investigated. The CrCl3⋅6H2O catalyst...

Biomass valorisation by staged degasification A new pyrolysis-based thermochemical conversion option to produce value-added chemicals from lignocellulosic biomass

NARCIS (Netherlands)

de Wild, P. J.; den Uil, H.; Reith, J. H.; Kiel, J. H. A.; Heeres, H. J.

Pyrolysis of lignocellulosic biomass leads to an array Of useful solid, liquid and gaseous products. Staged degasification is a pyrolysis-based conversion route to generate value-added chemicals from biomass. Because of different thermal stabilities of the main biomass constituents hemicellulose.

Effect of biomass feedstock chemical and physical properties on energy conversion processes: Volume 2, Appendices

Energy Technology Data Exchange (ETDEWEB)

Butner, R.S.; Elliott, D.C.; Sealock, L.J., Jr.; Pyne, J.W.

1988-12-01

This report presents an exploration of the relationships between biomass feedstocks and the conversion processes that utilize them. Specifically, it discusses the effect of the physical and chemical structure of biomass on conversion yields, rates, and efficiencies in a wide variety of available or experimental conversion processes. A greater understanding of the complex relationships between these conversion systems and the production of biomass for energy uses is required to help optimize the complex network of biomass production, collection, transportation, and conversion to useful energy products. The review of the literature confirmed the scarcity of research aimed specifically at identifying the effect of feedstock properties on conversion. In most cases, any mention of feedstock-related effects was limited to a few brief remarks (usually in qualitative terms) in the conclusions, or as a topic for further research. Attempts to determine the importance of feedstock parameters from published data were further hampered by the lack of consistent feedstock characterization and the difficulty of comparing results between different experimental systems. Further research will be required to establish quantitative relationships between feedstocks and performance criteria in conversion. 127 refs., 4 figs., 7 tabs.

Woody biomass availability for bioethanol conversion in Mississippi

International Nuclear Information System (INIS)

Perez-Verdin, Gustavo; Grebner, Donald L.; Sun, Changyou; Munn, Ian A.; Schultz, Emily B.; Matney, Thomas G.

2009-01-01

This study evaluated woody biomass from logging residues, small-diameter trees, mill residues, and urban waste as a feedstock for cellulosic ethanol conversion in Mississippi. The focus on Mississippi was to assess in-state regional variations and provide specific information of biomass estimates for those facilities interested in locating in Mississippi. Supply and cost of four woody biomass sources were derived from Forest Inventory Analysis (FIA) information, a recent forest inventory conducted by the Mississippi Institute for Forest Inventory, and primary production costs. According to our analysis, about 4.0 million dry tons of woody biomass are available for production of up to 1.2 billion liters of ethanol each year in Mississippi. The feedstock consists of 69% logging residues, 21% small-diameter trees, 7% urban waste, and 3% mill residues. Of the total, 3.1 million dry tons (930 million liters of ethanol) can be produced for $34 dry ton -1 or less. Woody biomass from small-diameter trees is more expensive than other sources of biomass. Transportation costs accounted for the majority of total production costs. A sensitivity analysis indicates that the largest impacts in production costs of ethanol come from stumpage price of woody biomass and technological efficiency. These results provide a valuable decision support tool for resource managers and industries in identifying parameters that affect resource magnitude, type, and location of woody biomass feedstocks in Mississippi. (author)

Conversion of Lignocellulosic Biomass to Nanocellulose: Structure and Chemical Process

Directory of Open Access Journals (Sweden)

H. V. Lee

2014-01-01

Full Text Available Lignocellulosic biomass is a complex biopolymer that is primary composed of cellulose, hemicellulose, and lignin. The presence of cellulose in biomass is able to depolymerise into nanodimension biomaterial, with exceptional mechanical properties for biocomposites, pharmaceutical carriers, and electronic substrate’s application. However, the entangled biomass ultrastructure consists of inherent properties, such as strong lignin layers, low cellulose accessibility to chemicals, and high cellulose crystallinity, which inhibit the digestibility of the biomass for cellulose extraction. This situation offers both challenges and promises for the biomass biorefinery development to utilize the cellulose from lignocellulosic biomass. Thus, multistep biorefinery processes are necessary to ensure the deconstruction of noncellulosic content in lignocellulosic biomass, while maintaining cellulose product for further hydrolysis into nanocellulose material. In this review, we discuss the molecular structure basis for biomass recalcitrance, reengineering process of lignocellulosic biomass into nanocellulose via chemical, and novel catalytic approaches. Furthermore, review on catalyst design to overcome key barriers regarding the natural resistance of biomass will be presented herein.

Conversion of Lignocellulosic Biomass to Nanocellulose: Structure and Chemical Process

Science.gov (United States)

Lee, H. V.; Hamid, S. B. A.; Zain, S. K.

2014-01-01

Lignocellulosic biomass is a complex biopolymer that is primary composed of cellulose, hemicellulose, and lignin. The presence of cellulose in biomass is able to depolymerise into nanodimension biomaterial, with exceptional mechanical properties for biocomposites, pharmaceutical carriers, and electronic substrate's application. However, the entangled biomass ultrastructure consists of inherent properties, such as strong lignin layers, low cellulose accessibility to chemicals, and high cellulose crystallinity, which inhibit the digestibility of the biomass for cellulose extraction. This situation offers both challenges and promises for the biomass biorefinery development to utilize the cellulose from lignocellulosic biomass. Thus, multistep biorefinery processes are necessary to ensure the deconstruction of noncellulosic content in lignocellulosic biomass, while maintaining cellulose product for further hydrolysis into nanocellulose material. In this review, we discuss the molecular structure basis for biomass recalcitrance, reengineering process of lignocellulosic biomass into nanocellulose via chemical, and novel catalytic approaches. Furthermore, review on catalyst design to overcome key barriers regarding the natural resistance of biomass will be presented herein. PMID:25247208

Application of Fischer–Tropsch Synthesis in Biomass to Liquid Conversion

Directory of Open Access Journals (Sweden)

Yongwu Lu

2012-06-01

Full Text Available Fischer–Tropsch synthesis is a set of catalytic processes that can be used to produce fuels and chemicals from synthesis gas (mixture of CO and H2, which can be derived from natural gas, coal, or biomass. Biomass to Liquid via Fischer–Tropsch (BTL-FT synthesis is gaining increasing interests from academia and industry because of its ability to produce carbon neutral and environmentally friendly clean fuels; such kinds of fuels can help to meet the globally increasing energy demand and to meet the stricter environmental regulations in the future. In the BTL-FT process, biomass, such as woodchips and straw stalk, is firstly converted into biomass-derived syngas (bio-syngas by gasification. Then, a cleaning process is applied to remove impurities from the bio-syngas to produce clean bio-syngas which meets the Fischer–Tropsch synthesis requirements. Cleaned bio-syngas is then conducted into a Fischer–Tropsch catalytic reactor to produce green gasoline, diesel and other clean biofuels. This review will analyze the three main steps of BTL-FT process, and discuss the issues related to biomass gasification, bio-syngas cleaning methods and conversion of bio-syngas into liquid hydrocarbons via Fischer–Tropsch synthesis. Some features in regard to increasing carbon utilization, enhancing catalyst activity, maximizing selectivity and avoiding catalyst deactivation in bio-syngas conversion process are also discussed.

Present situation, problems and solutions of China's biomass power generation industry

International Nuclear Information System (INIS)

Liu, Jicheng; Wang, Sijia; Wei, Qiushuang; Yan, Suli

2014-01-01

With the reduction of global oil reserves, developing renewable energy has become an important issue for each country. Biomass power is an important kind of clean energy, as it has abundant resource and is environmental friendly. In the past few years, China biomass power industry has developed rapidly accompanied with some problems. This paper analyzes the current situation of China biomass power generation from several aspects such as power structure, resource distribution, investment strength, and policy environment, etc. We focus on the problems existed in practical operation and analyze the outstanding problems. At last, this paper offers several suggestions for future development on the relevant fields, such as cost, strategic planning and policy. - Highlights: • Review and analyze the internal and external environment of biomass power in China. • Summarize and classify policies of China biomass power according to time sequence. • Describe the distribution of biomass resources in China accurately on the map. • Use data to draw a picture for grasping current situation. • Provide valuable suggestions for practitioners to improve their business strategies

Feedstock Supply System Design and Economics for Conversion of Lignocellulosic Biomass to Hydrocarbon Fuels: Conversion Pathway: Biological Conversion of Sugars to Hydrocarbons The 2017 Design Case

Energy Technology Data Exchange (ETDEWEB)

Kevin Kenney; Kara G. Cafferty; Jacob J. Jacobson; Ian J Bonner; Garold L. Gresham; William A. Smith; David N. Thompson; Vicki S. Thompson; Jaya Shankar Tumuluru; Neal Yancey

2013-09-01

The U.S. Department of Energy promotes the production of a range of liquid fuels and fuel blendstocks from lignocellulosic biomass feedstocks by funding fundamental and applied research that advances the state of technology in biomass collection, conversion, and sustainability. As part of its involvement in this program, the Idaho National Laboratory (INL) investigates the feedstock logistics economics and sustainability of these fuels. Between 2000 and 2012, INL conducted a campaign to quantify the economics and sustainability of moving biomass from standing in the field or stand to the throat of the biomass conversion process. The goal of this program was to establish the current costs based on conventional equipment and processes, design improvements to the current system, and to mark annual improvements based on higher efficiencies or better designs. The 2012 programmatic target was to demonstrate a delivered biomass logistics cost of $35/dry ton. This goal was successfully achieved in 2012 by implementing field and process demonstration unit-scale data from harvest, collection, storage, preprocessing, handling, and transportation operations into INL’s biomass logistics model. Looking forward to 2017, the programmatic target is to supply biomass to the conversion facilities at a total cost of $80/dry ton and on specification with in-feed requirements. The goal of the 2017 Design Case is to enable expansion of biofuels production beyond highly productive resource areas by breaking the reliance of cost-competitive biofuel production on a single, abundant, low-cost feedstock. If this goal is not achieved, biofuel plants are destined to be small and/or clustered in select regions of the country that have a lock on low-cost feedstock. To put the 2017 cost target into perspective of past accomplishments of the cellulosic ethanol pathway, the $80 target encompasses total delivered feedstock cost, including both grower payment and logistics costs, while meeting all

Bioenergy Research Programme. Yearbook 1997. Utilization of bioenergy and biomass conversion

International Nuclear Information System (INIS)

Nikku, P.

1998-01-01

The aim of the research programme is to increase the use of economically profitable and environmentally sound bioenergy, by improving the competitiveness of present peat and wood fuels. Research and development projects will also develop new economically competitive biofuels, new equipment and methods for production, handling and using of biofuels. The total funding for 1997 was 33.5 million FIM, and the number of projects 62. The number of projects concerning bioenergy use was 17 and biomass conversion 4. Results from the projects that were going on in 1997 are presented in this publication. The aim of the bioenergy use is to develop and demonstrate at least 3-4 new equipment or methods for handling and use of biofuels. The equipment and/or methods should provide economically competitive and environmentally sound energy production. The second aim is to demonstrate at least 2-3 large-scale biofuel end-use technologies. Each of these should have a potential of 0.2-0.3 million toe per year till the year 2000. The aims have been achieved in the field of fuel handling technologies and small scale combustion concepts, but the large scale demonstration projects before the year 2000 seem to be a very challenging goal. The aim of the biomass conversion is to produce basic information on biomass conversion, to evaluate the quality of products, their usability, environmental effects of the use as well as the total economy of the production. The objective of the biomass conversion is to develop 2-3 new methods, which could be demonstrated, for the production and utilization of liquefied, gasified and other converted biofuels. The production target is 0.2-0.3 million toe per year by 2005 at a competitive price level. The studies focused on the development of flash pyrolysis technology for biomass, and on the study of the storage stability of imported wood oils and their suitability for use in oil-fired boilers and diesel power plants

Biomass Thermochemical Conversion Program. 1983 Annual report

Energy Technology Data Exchange (ETDEWEB)

Schiefelbein, G.F.; Stevens, D.J.; Gerber, M.A.

1984-08-01

Highlights of progress achieved in the program of thermochemical conversion of biomass into clean fuels during 1983 are summarized. Gasification research projects include: production of a medium-Btu gas without using purified oxygen at Battelle-Columbus Laboratories; high pressure (up to 500 psia) steam-oxygen gasification of biomass in a fluidized bed reactor at IGT; producing synthesis gas via catalytic gasification at PNL; indirect reactor heating methods at the Univ. of Missouri-Rolla and Texas Tech Univ.; improving the reliability, performance, and acceptability of small air-blown gasifiers at Univ. of Florida-Gainesville, Rocky Creek Farm Gasogens, and Cal Recovery Systems. Liquefaction projects include: determination of individual sequential pyrolysis mechanisms at SERI; research at SERI on a unique entrained, ablative fast pyrolysis reactor for supplying the heat fluxes required for fast pyrolysis; work at BNL on rapid pyrolysis of biomass in an atmosphere of methane to increase the yields of olefin and BTX products; research at the Georgia Inst. of Tech. on an entrained rapid pyrolysis reactor to produce higher yields of pyrolysis oil; research on an advanced concept to liquefy very concentrated biomass slurries in an integrated extruder/static mixer reactor at the Univ. of Arizona; and research at PNL on the characterization and upgrading of direct liquefaction oils including research to lower oxygen content and viscosity of the product. Combustion projects include: research on a directly fired wood combustor/gas turbine system at Aerospace Research Corp.; adaptation of Stirling engine external combustion systems to biomass fuels at United Stirling, Inc.; and theoretical modeling and experimental verification of biomass combustion behavior at JPL to increase biomass combustion efficiency and examine the effects of additives on combustion rates. 26 figures, 1 table.

The development situation of biomass gasification power generation in China

International Nuclear Information System (INIS)

Zhou, Zhaoqiu; Yin, Xiuli; Xu, Jie; Ma, Longlong

2012-01-01

This work presents the development situation of biomass gasification power generation technology in China and analyzes the difficulty and challenge in the development process. For China, a large agricultural country with abundant biomass resources, the utilization of biomass gasification power generation technology is of special importance, because it can contribute to the electricity structure diversification under the present coal-dominant electricity structure, ameliorate the environmental impact, provide energy to electricity-scarce regions and solve the problems facing agriculture. Up to now, China has developed biomass gasification power generation plants of different types and scales, including simple gas engine-based power generation systems with capacity from several kW to 3 MW and integrated gasification combined cycle systems with capacity of more than 5 MW. In recent years, due to the rising cost of biomass material, transportation, manpower, etc., the final cost of biomass power generation has increased greatly, resulting in a serious challenge in the Chinese electricity market even under present preferential policy for biomass power price. However, biomass gasification power generation technology is generally in accord with the characteristics of biomass resources in China, has relatively good adaptability and viability, and so has good prospect in China in the future. - Highlights: ► Biomass gasification power generation of 2 kW–2 MW has wide utilization in China. ► 5.5 MW biomass IGCC demonstration plant has maximum power efficiency of up to 30%. ► Biomass power generation is facing a serious challenge due to biomass cost increase.

Biomass Conversion

Energy Technology Data Exchange (ETDEWEB)

Decker, Steve [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Brunecky, Roman [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Lin, Chien-Yuan [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Amore, Antonella [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Wei, Hui [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Chen, Xiaowen [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Tucker, Melvin P [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Czernik, Stefan [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Sluiter, Amie D [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Zhang, Min [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Magrini, Kimberly A [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Himmel, Michael E [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Sheehan, John [Formerly NREL; Dayton, David C. [Formerly NREL; Bozell, Joseph J. [Formerly NREL; Adney, William S. [Formerly NREL; Aden, Andy [Formerly NREL; Hames, Bonnie [Formerly NREL; Thomas, Steven R. [Formerly NREL; Bain, Richard L. [Formerly NREL

2017-08-02

Biomass constitutes all the plant matter found on our planet, and is produced directly by photosynthesis, the fundamental engine of life on earth. It is the photosynthetic capability of plants to utilize carbon dioxide from the atmosphere that leads to its designation as a 'carbon neutral' fuel, meaning that it does not introduce new carbon into the atmosphere. This article discusses the life cycle assessments of biomass use and the magnitude of energy captured by photosynthesis in the form of biomass on the planet to appraise approaches to tap this energy to meet the ever-growing demand for energy.

Communal biomass conversion plants

International Nuclear Information System (INIS)

Holm-Nielsen, J.B.; Huntingford, S.; Halberg, N.

1993-03-01

The aim was to show the agricultural advantages of farmers being in connection with Communal Biogas Plant. Whether a more environmentally protectire distribution of plant nutrients from animal manure takes place through a biogas plants distribution system, whether the nitrogen in the digested slurry is better utilized and whether the connection results in slurry transportation-time reduction, are discussed. The average amount of nitrogen from animal manure used per hectare was reduced. The area of manure distribution was larger. The nitrogen efficiency was increased when using digested slurry and purchase of N mineral fertilizer decreased, resulting in considerable reduction in nitrogen leaching. The amount of slurry delivered to the local storage tanks was approximately 45 per cent of the total amount treated on the biogas plant. Conditions of manure transport improved greatly as this was now the responsibility of the communal biomass conversion plant administrators. (AB) (24 refs.)

An overview of key pretreatment processes for biological conversion of lignocellulosic biomass to bioethanol

OpenAIRE

Maurya, Devendra Prasad; Singla, Ankit; Negi, Sangeeta

2015-01-01

Second-generation bioethanol can be produced from various lignocellulosic biomasses such as wood, agricultural or forest residues. Lignocellulosic biomass is inexpensive, renewable and abundant source for bioethanol production. The conversion of lignocellulosic biomass to bioethanol could be a promising technology though the process has several challenges and limitations such as biomass transport and handling, and efficient pretreatment methods for total delignification of lignocellulosics. P...

Environmental requirements in thermochemical and biochemical conversion of biomass

International Nuclear Information System (INIS)

Frings, R.M.; Mackie, K.L.; Hunter, I.R.

1992-01-01

Many biological and thermochemical processing options exist for the conversion of biomass to fuels. Commercially, these options are assessed in terms of fuel product yield and quality. However, attention must also be paid to the environmental aspects of each technology so that any commercial plant can meet the increasingly stringent environmental legislation in the world today. The environmental aspects of biological conversion (biogasification and bioliquefaction) and thermal conversion (high pressure liquefaction, flash pyrolysis, and gasification) are reviewed. Biological conversion processes are likely to generate waste streams which are more treatable than those from thermal conversion processes but the available data for thermal liquefaction are very limited. Close attention to waste minimisation is recommended and processing options that greatly reduce or eliminate waste streams have been identified. Product upgrading and its effect on wastewater quality also requires attention. Emphasis in further research studies needs to be placed on providing authentic waste streams for environmental assessment. (author)

Outcome of UNIDO symposium on biomass energy

International Nuclear Information System (INIS)

Nazemi, A.H.

1997-01-01

The results of the UNIDO symposium are presented. The symposium covered a variety of subjects, beginning with a comparison of biomass energy production and potential uses in different regions, specific country case studies about the present situation and trends in biomass energy utilisation. Technological aspects discussed included the production of biomass resources, their conversion into energy carriers and technology transfer to developing countries. An analysis of financial resources available and mechanisms for funding biomass projects were given. Environmental effects and some relatively successful biomass projects under development were described. (K.A.)

Process Design and Economics for Biochemical Conversion of Lignocellulosic Biomass to Ethanol

Energy Technology Data Exchange (ETDEWEB)

None

2011-05-02

The U.S. Department of Energy (DOE) promotes the production of ethanol and other liquid fuels from lignocellulosic biomass feedstocks by funding fundamental and applied research that advances the state of technology in biomass collection, conversion, and sustainability. As part of its involvement in the program, the National Renewable Energy Laboratory (NREL) investigates the production economics of these fuels.

Direct conversion of plant biomass to ethanol by engineered Caldicellulosiruptor bescii.

Science.gov (United States)

Chung, Daehwan; Cha, Minseok; Guss, Adam M; Westpheling, Janet

2014-06-17

Ethanol is the most widely used renewable transportation biofuel in the United States, with the production of 13.3 billion gallons in 2012 [John UM (2013) Contribution of the Ethanol Industry to the Economy of the United States]. Despite considerable effort to produce fuels from lignocellulosic biomass, chemical pretreatment and the addition of saccharolytic enzymes before microbial bioconversion remain economic barriers to industrial deployment [Lynd LR, et al. (2008) Nat Biotechnol 26(2):169-172]. We began with the thermophilic, anaerobic, cellulolytic bacterium Caldicellulosiruptor bescii, which efficiently uses unpretreated biomass, and engineered it to produce ethanol. Here we report the direct conversion of switchgrass, a nonfood, renewable feedstock, to ethanol without conventional pretreatment of the biomass. This process was accomplished by deletion of lactate dehydrogenase and heterologous expression of a Clostridium thermocellum bifunctional acetaldehyde/alcohol dehydrogenase. Whereas wild-type C. bescii lacks the ability to make ethanol, 70% of the fermentation products in the engineered strain were ethanol [12.8 mM ethanol directly from 2% (wt/vol) switchgrass, a real-world substrate] with decreased production of acetate by 38% compared with wild-type. Direct conversion of biomass to ethanol represents a new paradigm for consolidated bioprocessing, offering the potential for carbon neutral, cost-effective, sustainable fuel production.

Conversion Efficiency of Photosynthetically Active Radiation Into Acacia mearnsii Biomass

Directory of Open Access Journals (Sweden)

Elder Eloy

2018-02-01

Full Text Available ABSTRACT The objective of this experiment was to determine the conversion efficiency of intercepted photosynthetically active radiation into biomass of Acacia mearnsii De Wild. seedlings. A forest species, plastic tubes (90 cm3, and 11 evaluation periods (up to 180 days after emergence were used in this study. The leaf area index (LAI, total dry biomass (BIO, global solar radiation (GSR, cumulative intercepted photosynthetically active radiation (PARic, and conversion efficiency of radiation (εb were determined using a pyranometer (LI200X, LICOR. The value of εb in BIO seedlings of Acacia mearnsii was 7.76 g MJ-1. LAI was directly related to the efficiency of PARic, and this influenced the development, production potential and accumulation of BIO. The value of GSR flow was 11.81 MJ m-2 day-1, while the value inside the greenhouse was 6.26 MJ m-2 day-1.

Thermo-economic evaluation and optimization of the thermo-chemical conversion of biomass into methanol

International Nuclear Information System (INIS)

Peduzzi, Emanuela; Tock, Laurence; Boissonnet, Guillaume; Maréchal, François

2013-01-01

In a carbon and resources constrained world, thermo-chemical conversion of lignocellulosic biomass into fuels and chemicals is regarded as a promising alternative to fossil resources derived products. Methanol is one potential product which can be used for the synthesis of various chemicals or as a fuel in fuel cells and internal combustion engines. This study focuses on the evaluation and optimization of the thermodynamic and economic performance of methanol production from biomass by applying process integration and optimization techniques. Results reveal the importance of the energy integration and in particular of the cogeneration of electricity for the efficient use of biomass. - Highlights: • A thermo-economic model for biomass conversion into methanol is developed. • Process integration and multi-objective optimization techniques are applied. • Results reveal the importance of energy integration for electricity co-generation

Feedstock Supply System Design and Economics for Conversion of Lignocellulosic Biomass to Hydrocarbon Fuels Conversion Pathway: Fast Pyrolysis and Hydrotreating Bio-Oil Pathway "The 2017 Design Case"

Energy Technology Data Exchange (ETDEWEB)

Kevin L. Kenney; Kara G. Cafferty; Jacob J. Jacobson; Ian J. Bonner; Garold L. Gresham; J. Richard Hess; William A. Smith; David N. Thompson; Vicki S. Thompson; Jaya Shankar Tumuluru; Neal Yancey

2014-01-01

The U.S. Department of Energy promotes the production of liquid fuels from lignocellulosic biomass feedstocks by funding fundamental and applied research that advances the state of technology in biomass sustainable supply, logistics, conversion, and overall system sustainability. As part of its involvement in this program, Idaho National Laboratory (INL) investigates the feedstock logistics economics and sustainability of these fuels. Between 2000 and 2012, INL quantified and the economics and sustainability of moving biomass from the field or stand to the throat of the conversion process using conventional equipment and processes. All previous work to 2012 was designed to improve the efficiency and decrease costs under conventional supply systems. The 2012 programmatic target was to demonstrate a biomass logistics cost of $55/dry Ton for woody biomass delivered to fast pyrolysis conversion facility. The goal was achieved by applying field and process demonstration unit-scale data from harvest, collection, storage, preprocessing, handling, and transportation operations into INL’s biomass logistics model.

Pilot project concerning the establishment of a collective biomass conversion plant on the island of Mors

International Nuclear Information System (INIS)

1993-06-01

This pilot project comprises a feasibility study in connection with plans to establish a biomass conversion plant, on the Danish island of Mors, which would provide methane to be used as fuel, in combination with natural gas, for a cogeneration plant serving six villages. The subjects of location, organization, the transportation of biomass, the design of the biomass conversion plant, economical aspects and conditions of the use of the methane are discussed as a basis for decisions in this respect. Environmental considerations are also dealt with. (AB)

Dissecting variation in biomass conversion factors across China's forests: implications for biomass and carbon accounting.

Science.gov (United States)

Luo, Yunjian; Zhang, Xiaoquan; Wang, Xiaoke; Ren, Yin

2014-01-01

Biomass conversion factors (BCFs, defined as the ratios of tree components (i.e. stem, branch, foliage and root), as well as aboveground and whole biomass of trees to growing stock volume, Mg m-3) are considered as important parameters in large-scale forest biomass carbon estimation. To date, knowledge of possible sources of the variation in BCFs is still limited at large scales. Using our compiled forest biomass dataset of China, we presented forest type-specific values of BCFs, and examined the variation in BCFs in relation to forest type, stand development and environmental factors (climate and soil fertility). BCFs exhibited remarkable variation across forest types, and also were significantly related to stand development (especially growing stock volume). BCFs (except Stem BCF) had significant relationships with mean annual temperature (MAT) and mean annual precipitation (MAP) (Pforest carbon estimates, we should apply values of BCFs for a specified forest type, and also consider climatic and edaphic effects, especially climatic effect, in developing predictive models of BCFs (except Stem BCF).

Process Design and Economics for the Conversion of Algal Biomass to Biofuels: Algal Biomass Fractionation to Lipid-and Carbohydrate-Derived Fuel Products

Energy Technology Data Exchange (ETDEWEB)

None

2014-09-11

The U.S. Department of Energy (DOE) promotes the production of a range of liquid fuels and fuel blendstocks from biomass feedstocks by funding fundamental and applied research that advances the state of technology in biomass production, conversion, and sustainability. As part of its involvement in this program, the National Renewable Energy Laboratory (NREL) investigates the conceptual production economics of these fuels. This includes fuel pathways from lignocellulosic (terrestrial) biomass, as well as from algal (aquatic) biomass systems.

Catalytic Hydrothermal Conversion of Wet Biomass Feedstocks and Upgrading – Process Design and Optimization

DEFF Research Database (Denmark)

Hoffmann, Jessica; Toor, Saqib; Rosendahl, Lasse

Liquid biofuels will play a major role for a more sustainable energy system of the future. The CatLiq® process is a 2nd generation biomass conversion process that is based on hydrothermal liquefaction. Hydrothermal liquefaction offers a very efficient and feedstock flexible way of converting...... biomass to bio-oil. Bio-oils from hydrothermal liquefaction are characterised by their high feedstock flexibility. Upgrading of complete bio-oils derived from hydrothermal conversion has not yet been extensively studied. Purpose of this work is to reduce the oxygen content of the bio-oil to improve...

Establishment of a communal biomass conversion plant in the municipal area of Sydthy

International Nuclear Information System (INIS)

1992-09-01

The report should form the basis for an application to the Danish Energy Agency regarding potentials for a planned biomass conversion plant demonstration project, including effective storage of liquid manures. A survey of the needed resources in the form of organic wastes is given in addition to a description of immediate heat demand and heat production prices. The location of the plant and the supply of manures are discussed and the design of the plant is described in detail. The concentration of the biomass after conversion in order to facilitate storage and the organization and financing of the project are elucidated in addition to agricultural, environmental and administrational aspects. (AB)

Hydrothermal conversion of biomass to liquid energy sources; Hydrothermale Konversion von Biomasse zu fluessigen Energietraegern

Energy Technology Data Exchange (ETDEWEB)

Kroeger, Michael; Peters, Mario; Klemm, Marco; Nelles, Michael [Deutsches Biomasseforschungszentrum (DBFZ) gemeinnuetzige GmbH, Leipzig (Germany)

2013-10-01

Beside thermo-chemical processes like pyrolysis, torrefaction and gasification another process group called hydrothermal conversion of biomass comes into the focus of research and development. Especially for wet biomass this process has several advantages: as the reaction medium is water wet biomass not needs to be dried. Beside the reaction pathways, which are still not completely understood, it is important to investigate reactor concepts. That gives the possibility to continuously process the given biomass to deduce specific process conditions for the production of chemicals and fuels. Experiments were conducted in a newly developed tubular reactor at temperatures from 150 to 270 C and reaction times from 1 to 6 min. By studying the HPLC analysis of the liquid products the formation and degradation of several products which may be utilized as base materials for chemicals and fuels (furfural, 5-HMF etc.) was conducted. The experiments illustrate the possibility to influence product composition to a certain extend only by varying temperature and time of the hydrothermal process. That could result in an economic and feasible way to produce intermediate chemicals from biomass. In a second step these product analysis will be used to develop catalysts and investigate the possibilities of in-situ-hydrogenation and synthesis of further valuable chemicals and fuels. (orig.)

Thermochemical conversion of biomass storage covers to reduce ammonia emissions from dairy manure Thermochemical conversion of biomass storage covers to reduce ammonia emissions from dairy manure

Science.gov (United States)

Manure storages, and in particular those storing digested manure, are a source of ammonia (NH3) emissions. Permeable manure storage covers can reduce NH3 emissions, however performance can decline as they degrade. Thermochemical conversion of biomass through pyrolysis and steam treatment could incre...

Process Design and Economics for the Conversion of Lignocellulosic Biomass to Hydrocarbons: Dilute-Acid and Enzymatic Deconstruction of Biomass to Sugars and Biological Conversion of Sugars to Hydrocarbons

Energy Technology Data Exchange (ETDEWEB)

Davis, R.; Tao, L.; Tan, E. C. D.; Biddy, M. J.; Beckham, G. T.; Scarlata, C.; Jacobson, J.; Cafferty, K.; Ross, J.; Lukas, J.; Knorr, D.; Schoen, P.

2013-10-01

This report describes one potential conversion process to hydrocarbon products by way of biological conversion of lingnocellulosic-dervied sugars. The process design converts biomass to a hydrocarbon intermediate, a free fatty acid, using dilute-acid pretreatement, enzymatic saccharification, and bioconversion. Ancillary areas--feed handling, hydrolysate conditioning, product recovery and upgrading (hydrotreating) to a final blendstock material, wastewater treatment, lignin combusion, and utilities--are also included in the design.

Fundamental mechanisms for conversion of volatiles in biomass and waste combustion. Final report

Energy Technology Data Exchange (ETDEWEB)

Glarborg, P.; Hindiyarti, L.; Marshall, P.; Livbjerg, H.; Dagaut, P.; Jensen, Anker; Frandsen, Flemming

2007-03-15

This project deals with the volatile oxidation chemistry in biomass and waste fired systems, emphasizing reactions important for pollutants emissions (NO{sub x}, SO{sub 2}, HCl, aerosols). The project aims to extend existing models and databases with a number of chemical subsystems that are presently not well understood, but are particularly important in connection with combustion of biomass and waste. The project is divided into 3 tasks. Task 1: Conversion of chlorine, sulfur and alkali gas phase components in combustion of biomass. Task 2: Formation mechanisms for NO{sub x} in the freeboard of grate combustion of biomass. Task 3: Oxidation mechanisms for oxygenated hydrocarbons in the volatiles from pyrolysis of biomass. (au)

Conversion analysis of a cylindrical biomass particle with a DEM-CFD coupling approach

Directory of Open Access Journals (Sweden)

Mohammad Mohseni

2017-09-01

Full Text Available Biomass as a renewable energy source has attracted more attention nowadays due to ecological and economical benefits. The main objective of this work is studying the biomass conversion with employing a DEM-CFD coupling approach. In this model, the solid particulates are considered as discrete elements coupled via heat, mass and momentum transfer to the surrounding gas as continuous phase. That is, a comprehensive three-dimensional numerical model is developed and applied to investigate the complex phenomena taking place during biomass conversion in a reactor. In this case, the physical and chemical processes as heat-up, drying, pyrolysis, gasification and combustion are taken into account based on the relevant homogeneous and heterogeneous reactions. This platform predicts the motion of discrete particles based on the newton's equations of motion; and the thermodynamic state of each particle is extended according to the related algorithms. The thermodynamic state estimates the temperature and species distributions inside the particle due to external heat sources and chemical reactions. The reaction rates are described with Arrhenius model, and the reactions in the gas phase are modeled using Partially Stirred Reactor (PaSR model with the standard k−ϵ turbulent model. The conductive and radiative heat transfer between particles as well as convective heat transfer between particles and gas phase are also observed. Due to layered behavior of biomass materials, the shape of particle is considered as cylindrical rather than spherical to predict more realistic results. In order to improve the numerical modeling of biomass conversion, a shrinkage model is also developed and validated with experimental data in literature.

Process Design and Economics for the Conversion of Algal Biomass to Biofuels: Algal Biomass Fractionation to Lipid- and Carbohydrate-Derived Fuel Products

Energy Technology Data Exchange (ETDEWEB)

Davis, R.; Kinchin, C.; Markham, J.; Tan, E.; Laurens, L.; Sexton, D.; Knorr, D.; Schoen, P.; Lukas, J.

2014-09-01

Beginning in 2013, NREL began transitioning from the singular focus on ethanol to a broad slate of products and conversion pathways, ultimately to establish similar benchmarking and targeting efforts. One of these pathways is the conversion of algal biomass to fuels via extraction of lipids (and potentially other components), termed the 'algal lipid upgrading' or ALU pathway. This report describes in detail one potential ALU approach based on a biochemical processing strategy to selectively recover and convert select algal biomass components to fuels, namely carbohydrates to ethanol and lipids to a renewable diesel blendstock (RDB) product. The overarching process design converts algal biomass delivered from upstream cultivation and dewatering (outside the present scope) to ethanol, RDB, and minor coproducts, using dilute-acid pretreatment, fermentation, lipid extraction, and hydrotreating.

Exploring the natural fungal biodiversity of tropical and temperate forests toward improvement of biomass conversion.

Science.gov (United States)

Berrin, Jean-Guy; Navarro, David; Couturier, Marie; Olivé, Caroline; Grisel, Sacha; Haon, Mireille; Taussac, Sabine; Lechat, Christian; Courtecuisse, Régis; Favel, Anne; Coutinho, Pedro M; Lesage-Meessen, Laurence

2012-09-01

In this study, natural fungal diversity in wood-decaying species was explored for biomass deconstruction. In 2007 and 2008, fungal isolates were collected in temperate forests mainly from metropolitan France and in tropical forests mainly from French Guiana. We recovered and identified 74 monomorph cultures using morphological and molecular identification tools. Following production of fungal secretomes under inductive conditions, we evaluated the capacity of these fungal strains to potentiate a commercial Trichoderma reesei cellulase cocktail for the release of soluble sugars from biomass. The secretome of 19 isolates led to an improvement in biomass conversion of at least 23%. Of the isolates, the Trametes gibbosa BRFM 952 (Banque de Ressources Fongiques de Marseille) secretome performed best, with 60% improved conversion, a feature that was not universal to the Trametes and related genera. Enzymatic characterization of the T. gibbosa BRFM 952 secretome revealed an unexpected high activity on crystalline cellulose, higher than that of the T. reesei cellulase cocktail. This report highlights the interest in a systematic high-throughput assessment of collected fungal biodiversity to improve the enzymatic conversion of lignocellulosic biomass. It enabled the unbiased identification of new fungal strains issued from biodiversity with high biotechnological potential.

Microfluidic glycosyl hydrolase screening for biomass-to-biofuel conversion.

Science.gov (United States)

Bharadwaj, Rajiv; Chen, Zhiwei; Datta, Supratim; Holmes, Bradley M; Sapra, Rajat; Simmons, Blake A; Adams, Paul D; Singh, Anup K

2010-11-15

The hydrolysis of biomass to fermentable sugars using glycosyl hydrolases such as cellulases and hemicellulases is a limiting and costly step in the conversion of biomass to biofuels. Enhancement in hydrolysis efficiency is necessary and requires improvement in both enzymes and processing strategies. Advances in both areas in turn strongly depend on the progress in developing high-throughput assays to rapidly and quantitatively screen a large number of enzymes and processing conditions. For example, the characterization of various cellodextrins and xylooligomers produced during the time course of saccharification is important in the design of suitable reactors, enzyme cocktail compositions, and biomass pretreatment schemes. We have developed a microfluidic-chip-based assay for rapid and precise characterization of glycans and xylans resulting from biomass hydrolysis. The technique enables multiplexed separation of soluble cellodextrins and xylose oligomers in around 1 min (10-fold faster than HPLC). The microfluidic device was used to elucidate the mode of action of Tm_Cel5A, a novel cellulase from hyperthermophile Thermotoga maritima . The results demonstrate that the cellulase is active at 80 °C and effectively hydrolyzes cellodextrins and ionic-liquid-pretreated switchgrass and Avicel to glucose, cellobiose, and cellotriose. The proposed microscale approach is ideal for quantitative large-scale screening of enzyme libraries for biomass hydrolysis, for development of energy feedstocks, and for polysaccharide sequencing.

Secondary reactions of tar during thermochemical biomass conversion[Dissertation 14341

Energy Technology Data Exchange (ETDEWEB)

Morf, P.O.

2001-07-01

This dissertation submitted to the Swiss Federal Institute of Technology in Zurich presents and discusses the results obtained during the examination of the processes involved in the formation and conversion of tar in biomass gasification plant. Details are given on the laboratory reactor system used to provide separated tar production and conversion for the purposes of the experiments carried out. The results of analyses made of the tar and the gaseous products obtained after its conversion at various temperatures are presented. The development of kinetic models using the results of the experiments that were carried out is described. The results of the experiments and modelling are compared with the corresponding results obtained using a full-scale down-draft, fixed-bed gasifier. The author is of the opinion that the reaction conditions found in full-scale gasifiers can be well simulated using heterogeneous tar conversion experiments using the lab reactor system.

Conversion of Lignocellulosic Bagasse Biomass into Hydrogel

Directory of Open Access Journals (Sweden)

Farzaneh Amiri

2016-11-01

Full Text Available In recent years, the main objective of developing new hydrogel systems has been to convert biomass into environmentally-friendly hydrogels. Hybrid hydrogels are usually prepared by graft copolymerization of acrylic monomers onto natural polymers or biomass. In this study, sugarcane bagasse was used to prepare semi-synthetic hybrid hydrogels without delignification, which is a costly and timeconsuming process. Sugarcane bagasse as a source of polysaccharide was modified using polymer microgels based on acrylic monomers such as acrylic acid, acrylamide and 2-acrylamido-2-methyl propane sulfonic acid which were prepared through inverse emulsion polymerization. By this process, biomass as a low-value by-product was converted into a valuable semi-synthetic hydrogel. In the following, the effect of latex type¸ the aqueous-to-organic phase ratio in the polymer latex, time and temperature of modification reaction on the swelling capacity of the hybrid hydrogel were evaluated. The chemical reaction between sugarcane bagasse and acrylic latex was carried out during heating of the modified bagasse which led to obtain a semisynthetic hydrogel with 60% natural components and 40% synthetic components. Among the latexes with different structures, poly(AA-NaAA-AM-AMPS was the most suitable polymer latex for the conversion of biomass into hydrogel. The bagasse modified with this latex had a water absorption capacity up to 112 g/g, while the water absorption capacity of primary sugarcane bagasse was only equal to 3.6 g/g. The prepared polymer hydrogels were characterized using Fourier transform infrared spectroscopy (FTIR, dynamic-mechanical thermal analysis (DMTA, thermal gravimetric analysis (TGA, scanning electron microscopy (SEM and determination of the amount of swelling capacity.

Biomass-fuelled PEMFC systems: Evaluation of two conversion paths relevant for different raw materials

International Nuclear Information System (INIS)

Guan, Tingting; Chutichai, Bhawasut; Alvfors, Per; Arpornwichanop, Amornchai

2015-01-01

Highlights: • Anaerobic digestion and gasification are viable biomass conversion technologies. • GF-PEMFC system yields a 20% electric efficiency and 57% thermal efficiency. • AD-PEMFC system has a 9% electric efficiency and 13% thermal efficiency. • AD-PEMFC system has an efficient land-use. • GF-PEMFC system has a high CO_2 emissions offset factor. - Abstract: Biomass-fuelled polymer electrolyte membrane fuel cells (PEMFCs) offer a solution for replacing fossil fuel with hydrogen production. This paper uses simulation methods for investigating biomass-fuelled PEMFCs for different raw materials and conversion paths. For liquid and solid biomass, anaerobic digestion (AD) and gasification (GF), respectively, are relatively viable and developed conversion technologies. Therefore, the AD-PEMFC system and the GF-PEMFC system are simulated for residential applications in order to evaluate the performance of the biomass-fuelled PEMFC systems. The results of the evaluation show that renewable hydrogen-rich gas from manure or forest residues is usable for the PEMFCs and makes the fuel cell stack work in a stable manner. For 100 kWe generation, the GF-PEMFC system yields an excellent technical performance with a 20% electric efficiency and 57% thermal efficiency, whereas the AD-PEMFC system only has an 9% electric efficiency and 13% thermal efficiency due to the low efficiency of the anaerobic digester (AD) and the high internal heat consumption of the AD and the steam reformer (SR). Additionally, in this study, the environmental performances of the AD-PEMFC and the GF-PEMFC in terms of CO_2 emission offset and land-use efficiency are discussed.

Chemistry of Furan Conversion into Aromatics and Olefins over HZSM-5: A Model Biomass Conversion Reaction

Energy Technology Data Exchange (ETDEWEB)

Cheng, Yu-Ting; Huber, George W.

2011-06-03

The conversion of furan (a model of cellulosic biomass) over HZSM-5 was investigated in a thermogravimetric analysis–mass spectrometry system, in situ Fourier transform infrared analysis, and in a continuous-flow fixed-bed reactor. Furan adsorbed as oligomers at room temperature with a 1.73 of adsorbed furan/Al ratio. These oligomers were polycyclic aromatic compounds that were converted to CO, CO₂, aromatics, and olefins at temperatures from 400 to 600 °C. Aromatics (e.g., benzene, toluene, and naphthalene), oligomer isomers (e.g., benzofuran, 2,2-methylenebisfuran, and benzodioxane), and heavy oxygenates (C₁₂{sub +} oligomers) were identified as intermediates formed inside HZSM-5 at different reaction temperatures. During furan conversion, graphite-type coke formed on the catalyst surface, which caused the aromatics and olefins formation to deactivate within the first 30 min of time on-stream. We have measured the effects of space velocity and temperature for furan conversion to help us understand the chemistry of biomass conversion inside zeolite catalysts. The major products for furan conversion included CO, CO₂, allene, C₂–C₆ olefins, benzene, toluene, styrene, benzofuran, indene, and naphthalene. The aromatics (benzene and toluene) and olefins (ethylene and propylene) selectivity decreased with increasing space velocity. Unsaturated hydrocarbons such as allene, cyclopentadiene, and aromatics selectivity increased with increasing space velocity. The product distribution was selective to olefins and CO at high temperatures (650 °C) but was selective to aromatics (benzene and toluene) at intermediate temperatures (450–600 °C). At low temperatures (450 °C), benzofuran and coke contributed 60% of the carbon selectivity. Several different reactions were occurring for furan conversion over zeolites. Some important reactions that we have identified in this study include Diels–Alder condensation (e.g., two furans form benzofuran and water

Calculating the share of process energy consumed by biomass conversion plants. Bestimmung der Anteile der Prozessenergie bei einer Biogasanlage

Energy Technology Data Exchange (ETDEWEB)

Goebel, W

1984-06-01

During the winter season the process energy consumption of biomass conversion plants is relatively high. Apart from the quantity and temperature of manures and insulation of the fermentation tank the process energy consumption depends on the efficiency of the heating system. Moreover, heat losses decide on the required quantities of process energy. Compared with the process energy consumption the electric power consumption of the engines supplying the biomass conversion plant is relatively low. Along with calculations tests and measurements in a biomass conversion plant during the winter season of 1981/1982 give access to the interrelation between process energy and electric power consumption.

Bioenergy Research Programme. Yearbook 1994. Utilization of bioenergy and biomass conversion

International Nuclear Information System (INIS)

Alakangas, E.

1995-01-01

BIOENERGIA Research Programme is one of energy technology programmes of the Finnish Ministry of Trade and Industry (in 1995 TEKES, Technology Development Center). The aim of Bioenergy Research Programme is to increase the use of economically profitable and environmentally sound bioenergy by improving the competitiveness of present peat and wood fuels. Research and development projects will also develop new economically competitive biofuels and new equipment and methods for production, handling and using of biofuels. The funding for 1994 was nearly 50 million FIM and project numbered 60. The research area of biomass conversion consisted of 8 projects in 1994, and the research area of bioenergy utilization of 13 projects. The results of these projects carried out in 1994 are presented in this publication. The aim of the biomass conversion research is to produce more bio-oils and electric power as well at wood processing industry as at power plants. The conversion research was pointed at refining of the waste liquors of pulping industry and the extracts of them into fuel oil and liquid engine fuels, on production of wood oil via flash pyrolysis, and on combustion tests. Other conversion studies dealt with production of fuel-grade ethanol. For utilization of agrobiomass in various forms of energy, a system study is introduced where special attention is how to use rapeseed oil unprocessed in heating boilers and diesel engines. Possibilities to produce agrofibre in investigated at a laboratory study

Numerical modelling of biomass combustion: Solid conversion processes in a fixed bed furnace

Science.gov (United States)

Karim, Md. Rezwanul; Naser, Jamal

2017-06-01

Increasing demand for energy and rising concerns over global warming has urged the use of renewable energy sources to carry a sustainable development of the world. Bio mass is a renewable energy which has become an important fuel to produce thermal energy or electricity. It is an eco-friendly source of energy as it reduces carbon dioxide emissions. Combustion of solid biomass is a complex phenomenon due to its large varieties and physical structures. Among various systems, fixed bed combustion is the most commonly used technique for thermal conversion of solid biomass. But inadequate knowledge on complex solid conversion processes has limited the development of such combustion system. Numerical modelling of this combustion system has some advantages over experimental analysis. Many important system parameters (e.g. temperature, density, solid fraction) can be estimated inside the entire domain under different working conditions. In this work, a complete numerical model is used for solid conversion processes of biomass combustion in a fixed bed furnace. The combustion system is divided in to solid and gas phase. This model includes several sub models to characterize the solid phase of the combustion with several variables. User defined subroutines are used to introduce solid phase variables in commercial CFD code. Gas phase of combustion is resolved using built-in module of CFD code. Heat transfer model is modified to predict the temperature of solid and gas phases with special radiation heat transfer solution for considering the high absorptivity of the medium. Considering all solid conversion processes the solid phase variables are evaluated. Results obtained are discussed with reference from an experimental burner.

Integration of deep geothermal energy and woody biomass conversion pathways in urban systems

International Nuclear Information System (INIS)

Moret, Stefano; Peduzzi, Emanuela; Gerber, Léda; Maréchal, François

2016-01-01

Highlights: • Novel optimization-based methodology to integrate renewable energy systems in cities. • Multiperiod model including storage, heat integration and Life Cycle Assessment. • Case study: systematic assessment of deep geothermal and wood conversion pathways. • Identification of novel wood-geothermal hybrid systems leading to higher efficiencies. • Extensive Supplementary Material to ensure full reproducibility of the work. - Abstract: Urban systems account for about two-thirds of global primary energy consumption and energy-related greenhouse gas emissions, with a projected increasing trend. Deep geothermal energy and woody biomass can be used for the production of heat, electricity and biofuels, thus constituting a renewable alternative to fossil fuels for all end-uses in cities: heating, cooling, electricity and mobility. This paper presents a methodology to assess the potential for integrating deep geothermal energy and woody biomass in an urban energy system. The city is modeled in its entirety as a multiperiod optimization problem with the total annual cost as an objective, assessing as well the environmental impact with a Life Cycle Assessment approach. For geothermal energy, deep aquifers and Enhanced Geothermal Systems are considered for stand-alone production of heat and electricity, and for cogeneration. For biomass, besides direct combustion and cogeneration, conversion to biofuels by a set of alternative processes (pyrolysis, Fischer-Tropsch synthesis and synthetic natural gas production) is studied. With a scenario-based approach, all pathways are first individually evaluated. Secondly, all possible combinations between geothermal and biomass options are systematically compared, taking into account the possibility of hybrid systems. Results show that integrating these two resources generates configurations featuring both lower costs and environmental impacts. In particular, synergies are found in innovative hybrid systems using

Thermal conversion of biomass to valuable fuels, chemical feedstocks and chemicals

Science.gov (United States)

Peters, William A [Lexington, MA; Howard, Jack B [Winchester, MA; Modestino, Anthony J [Hanson, MA; Vogel, Fredreric [Villigen PSI, CH; Steffin, Carsten R [Herne, DE

2009-02-24

A continuous process for the conversion of biomass to form a chemical feedstock is described. The biomass and an exogenous metal oxide, preferably calcium oxide, or metal oxide precursor are continuously fed into a reaction chamber that is operated at a temperature of at least 1400.degree. C. to form reaction products including metal carbide. The metal oxide or metal oxide precursor is capable of forming a hydrolizable metal carbide. The reaction products are quenched to a temperature of 800.degree. C. or less. The resulting metal carbide is separated from the reaction products or, alternatively, when quenched with water, hydolyzed to provide a recoverable hydrocarbon gas feedstock.

Efficient conversion of lignocellulosic biomass to levulinic acid using acidic ionic liquids.

Science.gov (United States)

Khan, Amir Sada; Man, Zakaria; Bustam, Mohamad Azmi; Nasrullah, Asma; Ullah, Zahoor; Sarwono, Ariyanti; Shah, Faiz Ullah; Muhammad, Nawshad

2018-02-01

In the present research work, dicationic ionic liquids, containing 1,4-bis(3-methylimidazolium-1-yl) butane ([C 4 (Mim) 2 ]) cation with counter anions [(2HSO 4 )(H 2 SO 4 ) 0 ], [(2HSO 4 )(H 2 SO 4 ) 2 ] and [(2HSO 4 )(H 2 SO 4 ) 4 ] were synthesised. ILs structures were confirmed using 1 H NMR spectroscopy. Thermal stability, Hammett acidity, density and viscosity of ILs were determined. Various types of lignocellulosic biomass such as rubber wood, palm oil frond, bamboo and rice husk were converted into levulinic acid (LA). Among the synthesized ionic liquids, [C 4 (Mim) 2 ][(2HSO 4 )(H 2 SO 4 ) 4 ] showed higher % yield of LA up to 47.52 from bamboo biomass at 110°C for 60min, which is the better yield at low temperature and short time compared to previous reports. Surface morphology, surface functional groups and thermal stability of bamboo before and after conversion into LA were studied using SEM, FTIR and TGA analysis, respectively. This one-pot production of LA from agro-waste will open new opportunity for the conversion of sustainable biomass resources into valuable chemicals. Copyright © 2017 Elsevier Ltd. All rights reserved.

Report on a survey in fiscal 1999. Part 2. Survey on the biomass-derived energy conversion technology; 1999 nendo biomass shigen wo genryo to suru energy henkan gijutsu ni kansuru chosa hokokusho. 2

Energy Technology Data Exchange (ETDEWEB)

NONE

2000-03-01

Biomass energy is positioned as a promising environment harmonizing energy in the 21st century because it does not break down the CO2 balance in the global scale. The present survey has investigated quantity of biomass resources utilizable as energy resources, investigated and analyzed the biomass-derived energy conversion technology, searched for a promising practically usable technology, and discussed the means to achieve the technological introduction. The foreword chapter describes that now is the good time to recognize importance of and introduce the biomass-derived technology. First and second chapters estimate energy potential and utilizable quantity of wastes-based biomass in Indonesia, Malaysia, the Philippines, and Brazil. Chapter 3 investigates feasibility of methane fermentation and ethanol fermentation as a promising bio-chemical conversion process. Chapter 4 has performed feasibility studies on biomass electric power generation, methanol synthesis by gasification, thermal decomposition and gasification as promising thermo-chemical conversion processes. Chapter 5 proposed a biomass electric power generation system, a biomass-gasified methanol synthesizing system, and a dimethyl ether production system. (NEDO)

Development of a fermentation-based process for biomass conversion to hydrogen gas

NARCIS (Netherlands)

Claassen, P.A.M.; Vrije, de G.J.; Urbaniec, K.; Grabarczyk, R.

2010-01-01

The production of hydrogen gas from biomass to meet the foreseen demand arising from the expected introduction of fuel cells is envisaged. Apart from the well-known gasification method, fermentative conversion can also be applied for this purpose. Two options of the latter method, that is,

Conversion of Lignocellulosic Biomass to Ethanol and Butyl Acrylate

Energy Technology Data Exchange (ETDEWEB)

Binder, Thomas [Archer Daniels Midland Company, Decatur, IL (United States); Erpelding, Michael [Archer Daniels Midland Company, Decatur, IL (United States); Schmid, Josef [Archer Daniels Midland Company, Decatur, IL (United States); Chin, Andrew [Archer Daniels Midland Company, Decatur, IL (United States); Sammons, Rhea [Archer Daniels Midland Company, Decatur, IL (United States); Rockafellow, Erin [Archer Daniels Midland Company, Decatur, IL (United States)

2015-04-10

Conversion of Lignocellulosic Biomass to Ethanol and Butyl Acrylate. The purpose of Archer Daniels Midlands Integrated Biorefinery (IBR) was to demonstrate a modified acetosolv process on corn stover. It would show the fractionation of crop residue to distinct fractions of cellulose, hemicellulose, and lignin. The cellulose and hemicellulose fractions would be further converted to ethanol as the primary product and a fraction of the sugars would be catalytically converted to acrylic acid, with butyl acrylate the final product. These primary steps have been demonstrated.

Biomass thermochemical conversion. Overview of results; Biomassan jalostus. Tutkimusalueen katsaus

Energy Technology Data Exchange (ETDEWEB)

Sipilae, K [VTT Energy, Jyvaeskylae (Finland)

1997-12-01

The BIOENERGY Programme comprised two research institute projects, one enterprise project and two demonstration projects in 1996. The studies focused on the development of flash pyrolysis technology for biomass, and on the study of the storage stability of imported wood oils and of their suitability for use in oil-fired boilers and diesel power plants. Development of biomass gasification/gas engine concepts suitable for diesel power plants was also initiated. In addition to techno-economic assessments, experimental work was carried out focusing on the cleaning of gasification gas for engine use. Conversion of by-products from the pulping industry, in particular crude soap, into liquid fuels was studied by laboratory tests. Results obtained within IEA Bioenergy Agreement are also surveyed and a new three-year work plan is presented in the overview. (orig.)

Total Protein Content Determination of Microalgal Biomass by Elemental Nitrogen Analysis and a Dedicated Nitrogen-to-Protein Conversion Factor

Energy Technology Data Exchange (ETDEWEB)

Laurens, Lieve M [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Olstad-Thompson, Jessica L [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Templeton, David W [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

2018-04-02

Accurately determining protein content is important in the valorization of algal biomass in food, feed, and fuel markets, where these values are used for component balance calculations. Conversion of elemental nitrogen to protein is a well-accepted and widely practiced method, but depends on developing an applicable nitrogen-to-protein conversion factor. The methodology reported here covers the quantitative assessment of the total nitrogen content of algal biomass and a description of the methodology that underpins the accurate de novo calculation of a dedicated nitrogen-to-protein conversion factor.

Process Design and Economics for the Conversion of Lignocellulosic Biomass to High Octane Gasoline: Thermochemical Research Pathway with Indirect Gasification and Methanol Intermediate

Energy Technology Data Exchange (ETDEWEB)

Tan, Eric [National Renewable Energy Lab. (NREL), Golden, CO (United States); Talmadge, M. [National Renewable Energy Lab. (NREL), Golden, CO (United States); Dutta, Abhijit [National Renewable Energy Lab. (NREL), Golden, CO (United States); Hensley, Jesse [National Renewable Energy Lab. (NREL), Golden, CO (United States); Schaidle, Josh [National Renewable Energy Lab. (NREL), Golden, CO (United States); Biddy, Mary J. [National Renewable Energy Lab. (NREL), Golden, CO (United States); Humbird, David [DWH Process Consulting, Denver, CO (United States); Snowden-Swan, Lesley J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Ross, Jeff [Harris Group, Inc., Seattle, WA (United States); Sexton, Danielle [Harris Group, Inc., Seattle, WA (United States); Yap, Raymond [Harris Group, Inc., Seattle, WA (United States); Lukas, John [Harris Group, Inc., Seattle, WA (United States)

2015-03-01

The U.S. Department of Energy (DOE) promotes research for enabling cost-competitive liquid fuels production from lignocellulosic biomass feedstocks. The research is geared to advance the state of technology (SOT) of biomass feedstock supply and logistics, conversion, and overall system sustainability. As part of their involvement in this program, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) investigate the economics of conversion pathways through the development of conceptual biorefinery process models. This report describes in detail one potential conversion process for the production of high octane gasoline blendstock via indirect liquefaction (IDL). The steps involve the conversion of biomass to syngas via indirect gasification followed by gas cleanup and catalytic syngas conversion to a methanol intermediate; methanol is then further catalytically converted to high octane hydrocarbons. The conversion process model leverages technologies previously advanced by research funded by the Bioenergy Technologies Office (BETO) and demonstrated in 2012 with the production of mixed alcohols from biomass. Biomass-derived syngas cleanup via tar and hydrocarbons reforming was one of the key technology advancements as part of that research. The process described in this report evaluates a new technology area with downstream utilization of clean biomass-syngas for the production of high octane hydrocarbon products through a methanol intermediate, i.e., dehydration of methanol to dimethyl ether (DME) which subsequently undergoes homologation to high octane hydrocarbon products.

Characterization of second generation biomass under thermal conversion and the fate of nitrogen

NARCIS (Netherlands)

Giuntoli, J.

2010-01-01

This dissertation deals with the characterization of several biomass materials under thermal conversion conditions using small--scale equipment. The fuels are tested under the conditions of slow and fast heating rate pyrolysis and combustion, with the main goal of investigating the chemistry of

Catalytic oxidative conversion of cellulosic biomass to formic acid and acetic acid with exceptionally high yields

KAUST Repository

Zhang, Jizhe

2014-09-01

Direct conversion of raw biomass materials to fine chemicals is of great significance from both economic and ecological perspectives. In this paper, we report that a Keggin-type vanadium-substituted phosphomolybdic acid catalyst, namely H4PVMo11O40, is capable of converting various biomass-derived substrates to formic acid and acetic acid with high selectivity in a water medium and oxygen atmosphere. Under optimized reaction conditions, H4PVMo11O40 gave an exceptionally high yield of formic acid (67.8%) from cellulose, far exceeding the values achieved in previous catalytic systems. Our study demonstrates that heteropoly acids are generally effective catalysts for biomass conversion due to their strong acidities, whereas the composition of metal addenda atoms in the catalysts has crucial influence on the reaction pathway and the product selectivity. © 2013 Elsevier B.V.

Process Design and Economics for the Production of Algal Biomass: Algal Biomass Production in Open Pond Systems and Processing Through Dewatering for Downstream Conversion

Energy Technology Data Exchange (ETDEWEB)

Davis, Ryan [National Renewable Energy Lab. (NREL), Golden, CO (United States); Markham, Jennifer [National Renewable Energy Lab. (NREL), Golden, CO (United States); Kinchin, Christopher [National Renewable Energy Lab. (NREL), Golden, CO (United States); Grundl, Nicholas [National Renewable Energy Lab. (NREL), Golden, CO (United States); Tan, Eric C.D. [National Renewable Energy Lab. (NREL), Golden, CO (United States); Humbird, David [DWH Process Consulting, Denver, CO (United States)

2016-02-17

This report describes in detail a set of aspirational design and process targets to better understand the realistic economic potential for the production of algal biomass for subsequent conversion to biofuels and/or coproducts, based on the use of open pond cultivation systems and a series of dewatering operations to concentrate the biomass up to 20 wt% solids (ash-free dry weight basis).

Multiscale Mathematics for Biomass Conversion to Renewable Hydrogen

Energy Technology Data Exchange (ETDEWEB)

Plechac, Petr [Univ. of Tennessee, Knoxville, TN (United States). Dept. of Mathematics; Univ. of Delaware, Newark, DE (United States). Dept. of Mathematics; Vlachos, Dionisios [Univ. of Delaware, Newark, DE (United States). Dept. of Chemical and Biomolecular Engineering; Katsoulakis, Markos [Univ. of Massachusetts, Amherst, MA (United States). Dept. of Mathematics

2013-09-05

The overall objective of this project is to develop multiscale models for understanding and eventually designing complex processes for renewables. To the best of our knowledge, our work is the first attempt at modeling complex reacting systems, whose performance relies on underlying multiscale mathematics. Our specific application lies at the heart of biofuels initiatives of DOE and entails modeling of catalytic systems, to enable economic, environmentally benign, and efficient conversion of biomass into either hydrogen or valuable chemicals. Specific goals include: (i) Development of rigorous spatio-temporal coarse-grained kinetic Monte Carlo (KMC) mathematics and simulation for microscopic processes encountered in biomass transformation. (ii) Development of hybrid multiscale simulation that links stochastic simulation to a deterministic partial differential equation (PDE) model for an entire reactor. (iii) Development of hybrid multiscale simulation that links KMC simulation with quantum density functional theory (DFT) calculations. (iv) Development of parallelization of models of (i)-(iii) to take advantage of Petaflop computing and enable real world applications of complex, multiscale models. In this NCE period, we continued addressing these objectives and completed the proposed work. Main initiatives, key results, and activities are outlined.

Fractional Multistage Hydrothermal Liquefaction of Biomass and Catalytic Conversion into Hydrocarbons

Energy Technology Data Exchange (ETDEWEB)

Cortright, Randy [Virent, Inc., Madison, WI (United States); Rozmiarek, Robert [Virent, Inc., Madison, WI (United States); Dally, Brice [Virent, Inc., Madison, WI (United States); Holland, Chris [Virent, Inc., Madison, WI (United States)

2017-08-31

The objective of this project was to develop an improved multistage process for the hydrothermal liquefaction (HTL) of biomass to serve as a new front-end, deconstruction process ideally suited to feed Virent’s well-proven catalytic technology, which is already being scaled up. This process produced water soluble, partially de-oxygenated intermediates that are ideally suited for catalytic finishing to fungible distillate hydrocarbons. Through this project, Virent, with its partners, demonstrated the conversion of pine wood chips to drop-in hydrocarbon distillate fuels using a multi-stage fractional conversion system that is integrated with Virent’s BioForming® process. The majority of work was in the liquefaction task and included temperature scoping, solvent optimization, and separations.

Impact of various storage conditions on enzymatic activity, biomass components and conversion to ethanol yields from sorghum biomass used as a bioenergy crop.

Science.gov (United States)

Rigdon, Anne R; Jumpponen, Ari; Vadlani, Praveen V; Maier, Dirk E

2013-03-01

With increased mandates for biofuel production in the US, ethanol production from lignocellulosic substrates is burgeoning, highlighting the need for thorough examination of the biofuel production supply chain. This research focused on the impact storage has on biomass, particularly photoperiod-sensitive sorghum biomass. Biomass quality parameters were monitored and included biomass components, cellulose, hemicellulose and lignin, along with extra-cellular enzymatic activity (EEA) responsible for cellulose and hemicellulose degradation and conversion to ethanol yields. Analyses revealed dramatic decreases in uncovered treatments, specifically reduced dry matter content from 88% to 59.9%, cellulose content from 35.3% to 25%, hemicellulose content from 23.7% to 16.0% and ethanol production of 0.20 to 0.02gL(-1) after 6months storage along with almost double EEA activities. In contrast, biomass components, EEA and ethanol yields remained relatively stable in covered treatments, indicating covering of biomass during storage is essential for optimal substrate retention and ethanol yields. Copyright © 2013 Elsevier Ltd. All rights reserved.

Selection of biomass thermochemical conversion technology in the Netherlands : A best worst method approach

NARCIS (Netherlands)

van de Kaa, G.; Kamp, L.M.; Rezaei, J.

2017-01-01

This paper studies the technology battle for biomass conversion in the Netherlands. Three types of technologies are currently fighting the battle for standard dominance: combustion, pyrolysis, and gasification. Twelve relevant factors for standard dominance were found: ‘financial strength’,

Research and evaluation of biomass resources/conversion/utilization systems (market/experimental analysis for development of a data base for a fuels from biomass model. Volume I. Biomass allocation model. Technical progress report for the period ending September 30, 1980

Energy Technology Data Exchange (ETDEWEB)

Ahn, Y.K.; Chen, H.T.; Helm, R.W.; Nelson, E.T.; Shields K.J.

1980-01-01

A biomass allocation model has been developed to show the most profitable combination of biomass feedstocks thermochemical conversion processes, and fuel products to serve the seasonal conditions in a regional market. This optimization model provides a tool for quickly calculating the most profitable biomass missions from a large number of potential biomass missions. Other components of the system serve as a convenient storage and retrieval mechanism for biomass marketing and thermochemical conversion processing data. The system can be accessed through the use of a computer terminal, or it could be adapted to a portable micro-processor. A User's Manual for the system has been included in Appendix A of the report. The validity of any biomass allocation solution provided by the allocation model is dependent on the accuracy of the data base. The initial data base was constructed from values obtained from the literature, and, consequently, as more current thermochemical conversion processing and manufacturing costs and efficiencies become available, the data base should be revised. Biomass derived fuels included in the data base are the following: medium Btu gas low Btu gas, substitute natural gas, ammonia, methanol, electricity, gasoline, and fuel oil. The market sectors served by the fuels include: residential, electric utility, chemical (industrial), and transportation. Regional/seasonal costs and availabilities and heating values for 61 woody and non-woody biomass species are included. The study has included four regions in the United States which were selected because there was both an availability of biomass and a commercial demand for the derived fuels: Region I: NY, WV, PA; Region II: GA, AL, MS; Region III: IN, IL, IA; and Region IV: OR, WA.

Air pollution reduction with respect to the conversion of biomass into electricity and heat. Emission and cost indexes

International Nuclear Information System (INIS)

Bergsma, G.C.; Croezen, H.C.; De Weerd, G.; Van der Werff, T.

1999-01-01

Although biomass conversion is considered to be a CO2-free method of producing electricity and heat other emissions have to be taken into account: SO2, NOx, HCl, HF, Hg, Cd, dusts, etc. The aim of the study on the title subject is to support the Dutch Ministry of Housing, Planning and Environment (VROM) in the determination of feasible emission standards for bioconversion installations. The Centre for Energy conservation and clean technology (CE) compiled information on the costs for flue gas purification for different degrees of purification. Because of the fact that the composition of flue gases strongly depends on the biomass flow and the applied conversion technique, both biomass flows and conversion techniques must be distinguished. The following biomass conversion techniques were studied: large-scale combustion of wood wastes and sludges, large-scale gasification of wood wastes, cocombustion of wood wastes and sludges, small-scale combustion of wood wastes and chicken manure, small-scale gasification of wood wastes, and fermentation of wastes from vegetables, fruits and gardens. For each combination it is determined what the emissions are in case of a minimal flue gas purification, what the emissions are and how much additional costs are involved in case the regulations in the BLA (decree on air pollution of waste incineration) are taken into account, and what the emissions are and how much additional costs are involved for a number of levels in between the two fore-mentioned cases. refs

Effective conversion of biomass tar into fuel gases in a microwave reactor

Energy Technology Data Exchange (ETDEWEB)

Anis, Samsudin, E-mail: samsudin-anis@yahoo.com [Department of Mechanical Engineering, Universitas Negeri Semarang, Kampus Sekaran, Gunungpati, 50229 Semarang, 8508101 (Indonesia); Zainal, Z. A., E-mail: mezainal@usm.my [School of Mechanical Engineering, Universiti Sains Malaysia, Engineering Campus, 14300 Nibong Tebal, Penang (Malaysia)

2016-06-03

This work deals with conversion of naphthalene (C{sub 10}H{sub 8}) as a biomass tar model compound by means of thermal and catalytic treatments. A modified microwave oven with a maximum output power of 700 W was used as the experimental reactor. Experiments were performed in a wide temperature range of 450-1200°C at a predetermined residence time of 0.24-0.5 s. Dolomite and Y-zeolite were applied to convert naphthalene catalytically into useful gases. Experimental results on naphthalene conversion showed that conversion efficiency and yield of gases increased significantly with the increase of temperature. More than 90% naphthalene conversion efficiency was achieved by thermal treatment at 1200°C and 0.5 s. Nevertheless, this treatment was unfavorable for fuel gases production. The main product of this treatment was soot. Catalytic treatment provided different results with that of thermal treatment in which fuel gases formation was found to be the important product of naphthalene conversion. At a high temperature of 900°C, dolomite had better conversion activity where almost 40 wt.% of naphthalene could be converted into hydrogen, methane and other hydrocarbon gases.

Biomass pre-extraction, hydrolysis and conversion process improvements fro an integrated biorefinery

Energy Technology Data Exchange (ETDEWEB)

Jansen, Robert [Virdia, Inc., Danville, VA (United States)

2014-12-23

In this project, Virdia will show that it can improve the production of sugars suitable for the conversion into advanced biofuels from a range of woods. Several biomass feedstocks (Pine wood chips & Eucalyptus wood chips) will be tested on this new integrated biorefinery platform. The resultant drop-in biodiesel can be a cost-effective petroleum-replacement that can compete with projected market prices

Biomass supply management for advanced energy: applications in developing countries

International Nuclear Information System (INIS)

Ranney, J.W.; Perlack, R.D.

1995-01-01

Advanced biomass energy systems, including new biomass resource enhancement technologies, should be developed only where compelling situations for investors or communities exist to economically do so. These situations, or minimum viable operating conditions, are assessed from a pragmatic perspective. They are determined by specific circumstances and divergent interests that take time to define and integrate. Customized solutions are necessary and can change quickly with geography and market circumstances New technologies offer more options but are not necessarily the best. The example of energy crop technology is used to demonstrate the interdependencies that exist between new resource enhancement technology and biomass energy systems operations. The ability to genetically increase the energy density of energy crops is compared to other enhancement measures such as increasing the number of tonnes grown per hectare-year, reducing costs per tonne and improving other characteristics. Issues that need to be considered include significant knowledge gaps, lack of commitments in R and D, specificity of conversion system requirements, handling capabilities and opportunity costs. Broader biomass procurement strategies, which may be more important than resource enhancement technologies, are discussed. Biomass cost-supply is utilized as a strong analytical feature to evaluate the effectiveness of biomass procurement strategies and new biomass production technologies. Some past experiences are reviewed. Cost-supply is assessed from the perspective of the whole biomass energy system to expose the interdependencies between production operations, conversion scale and technologies, and community markets and service. Investment limits, for example, may be as important a determinant as the cost-efficiency of a new technology, which, in turn, affects biomass cost-supply-quality requirements. The cost of new technologies can then be compared to the changed performance of the overall

Biomass supply management for advanced energy: applications in developing countries

Energy Technology Data Exchange (ETDEWEB)

Ranney, J W [Joint Institute for Energy and Environment, Knoxville, TN (United States); Perlack, R D [Oak Ridge National Laboratory, Oak Ridge, TN (United States)

1995-12-01

Advanced biomass energy systems, including new biomass resource enhancement technologies, should be developed only where compelling situations for investors or communities exist to economically do so. These situations, or minimum viable operating conditions, are assessed from a pragmatic perspective. They are determined by specific circumstances and divergent interests that take time to define and integrate. Customized solutions are necessary and can change quickly with geography and market circumstances New technologies offer more options but are not necessarily the best. The example of energy crop technology is used to demonstrate the interdependencies that exist between new resource enhancement technology and biomass energy systems operations. The ability to genetically increase the energy density of energy crops is compared to other enhancement measures such as increasing the number of tonnes grown per hectare-year, reducing costs per tonne and improving other characteristics. Issues that need to be considered include significant knowledge gaps, lack of commitments in R and D, specificity of conversion system requirements, handling capabilities and opportunity costs. Broader biomass procurement strategies, which may be more important than resource enhancement technologies, are discussed. Biomass cost-supply is utilized as a strong analytical feature to evaluate the effectiveness of biomass procurement strategies and new biomass production technologies. Some past experiences are reviewed. Cost-supply is assessed from the perspective of the whole biomass energy system to expose the interdependencies between production operations, conversion scale and technologies, and community markets and service. Investment limits, for example, may be as important a determinant as the cost-efficiency of a new technology, which, in turn, affects biomass cost-supply-quality requirements. The cost of new technologies can then be compared to the changed performance of the overall

The different forms of biomass. A broad range of thermal and biochemical conversion techniques; Biomassa kan alle gedaantes aannemen. Thermische en biochemische conversietechnieken vormen breed scala

Energy Technology Data Exchange (ETDEWEB)

Van Doorn, J. [ECN Brandstoffen, Conversie en Milieu, Petten (Netherlands)

1997-05-01

Biomass and wastes are considered to be the most important renewable energy source in the Netherlands for the year 2020 (a contribution of 45% is estimated). Dependent on the characteristics of the type of biomass there is a broad range of ready and not yet ready conversion techniques (combustion, gasification, pyrolysis) for every required bio-energy carrier: electricity, heat, oil, gas, or solid fuel. A brief overview is given of the biomass types, the conversion techniques and the activities with respect to biomass conversion in the Netherlands. 3 ills., 1 ref.

A Review of the Role of Amphiphiles in Biomass to Ethanol Conversion

Directory of Open Access Journals (Sweden)

William Gibbons

2013-04-01

Full Text Available One of the concerns for economical production of ethanol from biomass is the large volume and high cost of the cellulolytic enzymes used to convert biomass into fermentable sugars. The presence of acetyl groups in hemicellulose and lignin in plant cell walls reduces accessibility of biomass to the enzymes and makes conversion a slow process. In addition to low enzyme accessibility, a rapid deactivation of cellulases during biomass hydrolysis can be another factor contributing to the low sugar recovery. As of now, the economical reduction in lignin content of the biomass is considered a bottleneck, and raises issues for several reasons. The presence of lignin in biomass reduces the swelling of cellulose fibrils and accessibility of enzyme to carbohydrate polymers. It also causes an irreversible adsorption of the cellulolytic enzymes that prevents effective enzyme activity and recycling. Amphiphiles, such as surfactants and proteins have been found to improve enzyme activity by several mechanisms of action that are not yet fully understood. Reduction in irreversible adsorption of enzyme to non-specific sites, reduction in viscosity of liquid and surface tension and consequently reduced contact of enzyme with air-liquid interface, and modifications in biomass chemical structure are some of the benefits derived from surface active molecules. Application of some of these amphiphiles could potentially reduce the capital and operating costs of bioethanol production by reducing fermentation time and the amount of enzyme used for saccharification of biomass. In this review article, the benefit of applying amphiphiles at various stages of ethanol production (i.e., pretreatment, hydrolysis and hydrolysis-fermentation is reviewed and the proposed mechanisms of actions are described.

Conversion of Levulinic Acid from Various Herbaceous Biomass Species Using Hydrochloric Acid and Effects of Particle Size and Delignification

Directory of Open Access Journals (Sweden)

Indra Neel Pulidindi

2018-03-01

Full Text Available Acid catalyzed hydrothermal conversion of levulinic acid (LA from various herbaceous materials including rice straw (RS, corn stover (CS, sweet sorghum bagasse (SSB, and Miscanthus (MS was evaluated. With 1 M HCl, 150 °C, 5 h, 20 g/L solid loading, the yields of LA from untreated RS, CS, SSB and MS based on the glucan content were 60.2, 75.1, 78.5 and 61.7 wt %, respectively. It was also found that the particle size had no significant effect on LA conversion yield with >3 h reaction time. With delignification using simulated green liquor (Na2CO3-Na2S, 20 wt % total titratable alkali (TTA, 40 wt % sulfidity at 200 °C for 15 min, lignin removal was in the range of 64.8–91.2 wt %. Removal of both lignin and xylan during delignification increased the glucan contents from 33.0–44.3 of untreated biomass to 61.7–68.4 wt % of treated biomass. Delignified biomass resulted in much lower conversion yield (50.4–56.0 wt % compared to 60.2–78.5 wt % of untreated biomass. Nonetheless, the concentration of LA in the product was enhanced by a factor of ~1.5 with delignification.

Proceedings of the Chernobyl phytoremediation and biomass energy conversion workshop

International Nuclear Information System (INIS)

Hartley, J.; Tokarevsky, V.

1998-06-01

Many concepts, systems, technical approaches, technologies, ideas, agreements, and disagreements were vigorously discussed during the course of the 2-day workshop. The workshop was successful in generating intensive discussions on the merits of the proposed concept that includes removal of radionuclides by plants and trees (phytoremediation) to clean up soil in the Chernobyl Exclusion Zone (CEZ), use of the resultant biomass (plants and trees) to generate electrical power, and incorporation of ash in concrete casks to be used as storage containers in a licensed repository for low-level waste. Twelve years after the Chernobyl Nuclear Power Plant (ChNPP) Unit 4 accident, which occurred on April 26, 1986, the primary 4radioactive contamination of concern is from radioactive cesium ( 137 Cs) and strontium ( 90 Sr). The 137 Cs and 90 Sr were widely distributed throughout the CEZ. The attendees from Ukraine, Russia, Belarus, Denmark and the US provided information, discussed and debated the following issues considerably: distribution and characteristics of radionuclides in CEZ; efficacy of using trees and plants to extract radioactive cesium (Cs) and strontium (Sr) from contaminated soil; selection of energy conversion systems and technologies; necessary infrastructure for biomass harvesting, handling, transportation, and energy conversion; radioactive ash and emission management; occupational health and safety concerns for the personnel involved in this work; and economics. The attendees concluded that the overall concept has technical and possibly economic merits. However, many issues (technical, economic, risk) remain to be resolved before a viable commercial-scale implementation could take place

Proceedings of the Chornobyl phytoremediation and biomass energy conversion workshop

Energy Technology Data Exchange (ETDEWEB)

Hartley, J. [Pacific Northwest National Lab., Richland, WA (United States); Tokarevsky, V. [State Co. for Treatment and Disposal of Mixed Hazardous Waste (Ukraine)

1998-06-01

Many concepts, systems, technical approaches, technologies, ideas, agreements, and disagreements were vigorously discussed during the course of the 2-day workshop. The workshop was successful in generating intensive discussions on the merits of the proposed concept that includes removal of radionuclides by plants and trees (phytoremediation) to clean up soil in the Chornobyl Exclusion Zone (CEZ), use of the resultant biomass (plants and trees) to generate electrical power, and incorporation of ash in concrete casks to be used as storage containers in a licensed repository for low-level waste. Twelve years after the Chornobyl Nuclear Power Plant (ChNPP) Unit 4 accident, which occurred on April 26, 1986, the primary 4radioactive contamination of concern is from radioactive cesium ({sup 137}Cs) and strontium ({sup 90}Sr). The {sup 137}Cs and {sup 90}Sr were widely distributed throughout the CEZ. The attendees from Ukraine, Russia, Belarus, Denmark and the US provided information, discussed and debated the following issues considerably: distribution and characteristics of radionuclides in CEZ; efficacy of using trees and plants to extract radioactive cesium (Cs) and strontium (Sr) from contaminated soil; selection of energy conversion systems and technologies; necessary infrastructure for biomass harvesting, handling, transportation, and energy conversion; radioactive ash and emission management; occupational health and safety concerns for the personnel involved in this work; and economics. The attendees concluded that the overall concept has technical and possibly economic merits. However, many issues (technical, economic, risk) remain to be resolved before a viable commercial-scale implementation could take place.

Thermo-Chemical Conversion of Microwave Activated Biomass Mixtures

Science.gov (United States)

Barmina, I.; Kolmickovs, A.; Valdmanis, R.; Vostrikovs, S.; Zake, M.

2018-05-01

Thermo-chemical conversion of microwave activated wheat straw mixtures with wood or peat pellets is studied experimentally with the aim to provide more effective application of wheat straw for heat energy production. Microwave pre-processing of straw pellets is used to provide a partial decomposition of the main constituents of straw and to activate the thermo-chemical conversion of wheat straw mixtures with wood or peat pellets. The experimental study includes complex measurements of the elemental composition of biomass pellets (wheat straw, wood, peat), DTG analysis of their thermal degradation, FTIR analysis of the composition of combustible volatiles entering the combustor, the flame temperature, the heat output of the device and composition of the products by comparing these characteristics for mixtures with unprocessed and mw pre-treated straw pellets. The results of experimental study confirm that mw pre-processing of straw activates the thermal decomposition of mixtures providing enhanced formation of combustible volatiles. This leads to improvement of the combustion conditions in the flame reaction zone, completing thus the combustion of volatiles, increasing the flame temperature, the heat output from the device, the produced heat energy per mass of burned mixture and decreasing at the same time the mass fraction of unburned volatiles in the products.

Biomass Conversion Factsheet

Energy Technology Data Exchange (ETDEWEB)

None

2016-06-05

To efficiently convert algae, diverse types of cellulosic biomass, and emerging feedstocks into renewable fuels, the U.S. Department of Energy (DOE) supports research, development, and demonstration of technologies. This research will help ensure that these renewable fuels are compatible with today’s vehicles and infrastructure.

Ensiling and hydrothermal pretreatment of grass: Consequences for enzymatic biomass conversion and total monosaccharide yields

DEFF Research Database (Denmark)

Ambye-Jensen, Morten; Johansen, Katja Salomon; Didion, Thomas

2014-01-01

Ensiling may act as a pretreatment of fresh grass biomass and increase the enzymatic conversion of structural carbohydrates to fermentable sugars. However, ensiling does not provide sufficient severity to be a standalone pretreatment method. Here, ensiling of grass is combined with hydrothermal...... treatment (HTT) with the aim of improving the enzymatic biomass convertibility and decrease the required temperature of the HTT. Results: Grass silage (Festulolium Hykor) was hydrothermally treated at temperatures of 170, 180, and 190°C for 10 minutes. Relative to HTT treated dry grass, ensiling increased...... convertibility). The effect of ensiling of grass prior to HTT improved the enzymatic conversion of cellulose for HTT at 170 and 180°C, but the increased glucose release did not make up for the loss of water soluble carbohydrates (WSC) during ensiling. Overall, sugar yields (C6 + C5) were similar for HTT of grass...

Biomass conversion and expansion factors are afected by thinning

Directory of Open Access Journals (Sweden)

Teresa Duque Enes

2014-12-01

Full Text Available Aim of the study: The objective of this paper is to investigate the use of Biomass Conversion and Expansion Factors (BCEFs in maritime pine (Pinus pinaster Ait. stands subjected to thinning.Area of the study: The study area refers to different ecosystems of maritime pine stands inNorthern Portugal.Material and methods: The study is supported by time data series and cross sectional data collected in permanent plots established in the North of Portugal. An assessment of BCEF values for the aboveground compartments and for total was completed for each studied stand. Identification of key variables affecting the value of the BCEFs in time and with thinning was conducted using correlation analysis. Predictive models for estimation of the BCEFs values in time and after thinning were developed using nonlinear regression analysis.Research highlights: For periods of undisturbed growth, the results show an allometric relationship between the BCEFs, the dominant height and the mean diameter. Management practices such as thinning also influence the factors. Estimates of the ratio change before and after thinning depend on thinning severity and thinning type. The developed models allow estimating the biomass of the stands, for the aboveground compartments and for total, based on information of stand characteristics and of thinning descriptors. These estimates can be used to assess the forest dry wood stocks to be used for pulp, bioenergy or other purposes, as well as the biomass quantification to support the evaluation of the net primary productivity.Keywords: carbon; softwood; thinning; volume; wood energy; maritime pine.

Boiler conversions for biomass

Energy Technology Data Exchange (ETDEWEB)

Kinni, J [Tampella Power Inc., Tampere (Finland)

1997-12-31

Boiler conversions from grate- and oil-fired boilers to bubbling fluidized bed combustion have been most common in pulp and paper industry. Water treatment sludge combustion, need for additional capacity and tightened emission limits have been the driving forces for the conversion. To accomplish a boiler conversion for biofuel, the lower part of the boiler is replaced with a fluidized bed bottom and new fuel, ash and air systems are added. The Imatran Voima Rauhalahti pulverized-peat-fired boiler was converted to bubbling fluidized bed firing in 1993. In the conversion the boiler capacity was increased by 10 % to 295 MWth and NO{sub x} emissions dropped. In the Kymmene Kuusankoski boiler, the reason for conversion was the combustion of high chlorine content biosludge. The emissions have been under general European limits. During the next years, the emission limits will tighten and the boilers will be designed for most complete combustion and compounds, which can be removed from flue gases, will be taken care of after the boiler. (orig.) 3 refs.

Boiler conversions for biomass

Energy Technology Data Exchange (ETDEWEB)

Kinni, J. [Tampella Power Inc., Tampere (Finland)

1996-12-31

Boiler conversions from grate- and oil-fired boilers to bubbling fluidized bed combustion have been most common in pulp and paper industry. Water treatment sludge combustion, need for additional capacity and tightened emission limits have been the driving forces for the conversion. To accomplish a boiler conversion for biofuel, the lower part of the boiler is replaced with a fluidized bed bottom and new fuel, ash and air systems are added. The Imatran Voima Rauhalahti pulverized-peat-fired boiler was converted to bubbling fluidized bed firing in 1993. In the conversion the boiler capacity was increased by 10 % to 295 MWth and NO{sub x} emissions dropped. In the Kymmene Kuusankoski boiler, the reason for conversion was the combustion of high chlorine content biosludge. The emissions have been under general European limits. During the next years, the emission limits will tighten and the boilers will be designed for most complete combustion and compounds, which can be removed from flue gases, will be taken care of after the boiler. (orig.) 3 refs.

Techno-economic Analysis for the Thermochemical Conversion of Lignocellulosic Biomass to Ethanol via Acetic Acid Synthesis

Energy Technology Data Exchange (ETDEWEB)

Zhu, Yunhua; Jones, Susanne B.

2009-04-01

Biomass is a renewable energy resource that can be converted into liquid fuel suitable for transportation applications. As a widely available biomass form, lignocellulosic biomass can have a major impact on domestic transportation fuel supplies and thus help meet the Energy Independence and Security Act renewable energy goals (U.S. Congress 2007). This study performs a techno-economic analysis of the thermo chemical conversion of biomass to ethanol, through methanol and acetic acid, followed by hydrogenation of acetic acid to ethanol. The conversion of syngas to methanol and methanol to acetic acid are well-proven technologies with high conversions and yields. This study was undertaken to determine if this highly selective route to ethanol could provide an already established economically attractive route to ethanol. The feedstock was assumed to be wood chips at 2000 metric ton/day (dry basis). Two types of gasification technologies were evaluated: an indirectly-heated gasifier and a directly-heated oxygen-blown gasifier. Process models were developed and a cost analysis was performed. The carbon monoxide used for acetic acid synthesis from methanol and the hydrogen used for hydrogenation were assumed to be purchased and not derived from the gasifier. Analysis results show that ethanol selling prices are estimated to be $2.79/gallon and $2.81/gallon for the indirectly-heated gasifier and the directly-heated gasifier systems, respectively (1stQ 2008$, 10% ROI). These costs are above the ethanol market price for during the same time period ($1.50 - $2.50/gal). The co-production of acetic acid greatly improves the process economics as shown in the figure below. Here, 20% of the acetic acid is diverted from ethanol production and assumed to be sold as a co-product at the prevailing market prices ($0.40 - $0.60/lb acetic acid), resulting in competitive ethanol production costs.

A comparison of producer gas, biochar, and activated carbon from two distributed scale thermochemical conversion systems used to process forest biomass

Science.gov (United States)

Nathaniel Anderson; J. Greg Jones; Deborah Page-Dumroese; Daniel McCollum; Stephen Baker; Daniel Loeffler; Woodam Chung

2013-01-01

Thermochemical biomass conversion systems have the potential to produce heat, power, fuels and other products from forest biomass at distributed scales that meet the needs of some forest industry facilities. However, many of these systems have not been deployed in this sector and the products they produce from forest biomass have not been adequately described or...

Catalytic oxidative conversion of cellulosic biomass to formic acid and acetic acid with exceptionally high yields

KAUST Repository

Zhang, Jizhe; Sun, Miao; Liu, Xin; Han, Yu

2014-01-01

Direct conversion of raw biomass materials to fine chemicals is of great significance from both economic and ecological perspectives. In this paper, we report that a Keggin-type vanadium-substituted phosphomolybdic acid catalyst, namely H4PVMo11O40

A review of thermo-chemical conversion of biomass into biofuels-focusing on gas cleaning and up-grading process steps

OpenAIRE

Brandin, Jan; Hulteberg, Christian; Kusar, Henrik

2017-01-01

It is not easy to replace fossil-based fuels in the transport sector, however, an appealing solution is to use biomass and waste for the production of renewable alternatives. Thermochemical conversion of biomass for production of synthetic transport fuels by the use of gasification is a promising way to meet these goals. One of the key challenges in using gasification systems with biomass and waste as feedstock is the upgrading of the raw gas produced in the gasifier. These materials replacin...

Catalytic Conversion of Biomass to Fuels and Chemicals Using Ionic Liquids

Energy Technology Data Exchange (ETDEWEB)

Liu, Wei; Zheng, Richard; Brown, Heather; Li, Joanne; Holladay, John; Cooper, Alan; Rao, Tony

2012-04-13

This project provides critical innovations and fundamental understandings that enable development of an economically-viable process for catalytic conversion of biomass (sugar) to 5-hydroxymethylfurfural (HMF). A low-cost ionic liquid (Cyphos 106) is discovered for fast conversion of fructose into HMF under moderate reaction conditions without any catalyst. HMF yield from fructose is almost 100% on the carbon molar basis. Adsorbent materials and adsorption process are invented and demonstrated for separation of 99% pure HMF product and recovery of the ionic liquid from the reaction mixtures. The adsorbent material appears very stable in repeated adsorption/regeneration cycles. Novel membrane-coated adsorbent particles are made and demonstrated to achieve excellent adsorption separation performances at low pressure drops. This is very important for a practical adsorption process because ionic liquids are known of high viscosity. Nearly 100% conversion (or dissolution) of cellulose in the catalytic ionic liquid into small molecules was observed. It is promising to produce HMF, sugars and other fermentable species directly from cellulose feedstock. However, several gaps were identified and could not be resolved in this project. Reaction and separation tests at larger scales are needed to minimize impacts of incidental errors on the mass balance and to show 99.9% ionic liquid recovery. The cellulose reaction tests were troubled with poor reproducibility. Further studies on cellulose conversion in ionic liquids under better controlled conditions are necessary to delineate reaction products, dissolution kinetics, effects of mass and heat transfer in the reactor on conversion, and separation of final reaction mixtures.

Cell wall targeted in planta iron accumulation enhances biomass conversion and seed iron concentration in Arabidopsis and rice

Energy Technology Data Exchange (ETDEWEB)

Yang, Haibing [Center for Direct Catalytic Conversion Of Biomass to Biofuels (C3Bio), Purdue University, West Lafayette IN USA; Department of Horticulture, Purdue University, West Lafayette IN USA; Department of Biological Sciences, Purdue University, West Lafayette IN USA; Wei, Hui [Biosciences Center, National Renewable Energy Laboratory, Golden CO USA; Ma, Guojie [Center for Direct Catalytic Conversion Of Biomass to Biofuels (C3Bio), Purdue University, West Lafayette IN USA; Department of Horticulture, Purdue University, West Lafayette IN USA; Antunes, Mauricio S. [Center for Direct Catalytic Conversion Of Biomass to Biofuels (C3Bio), Purdue University, West Lafayette IN USA; Department of Biological Sciences, Purdue University, West Lafayette IN USA; Vogt, Stefan [X-ray Science Division, Advanced Photon Source, Argonne National Laboratory, Argonne IL USA; Cox, Joseph [Center for Direct Catalytic Conversion Of Biomass to Biofuels (C3Bio), Purdue University, West Lafayette IN USA; Department of Horticulture, Purdue University, West Lafayette IN USA; Zhang, Xiao [Department of Horticulture, Purdue University, West Lafayette IN USA; Liu, Xiping [Center for Direct Catalytic Conversion Of Biomass to Biofuels (C3Bio), Purdue University, West Lafayette IN USA; Department of Horticulture, Purdue University, West Lafayette IN USA; Bu, Lintao [National Bioenergy Center, National Renewable Energy Laboratory, Golden CO USA; Gleber, S. Charlotte [X-ray Science Division, Advanced Photon Source, Argonne National Laboratory, Argonne IL USA; Carpita, Nicholas C. [Department of Biological Sciences, Purdue University, West Lafayette IN USA; Department of Botany and Plant Pathology, Purdue University, West Lafayette IN USA; Makowski, Lee [Department of Bioengineering, Northeastern University, Boston MA USA; Department of Chemistry and Chemical Biology, Northeastern University, Boston MA USA; Himmel, Michael E. [Biosciences Center, National Renewable Energy Laboratory, Golden CO USA; Tucker, Melvin P. [X-ray Science Division, Advanced Photon Source, Argonne National Laboratory, Argonne IL USA; McCann, Maureen C. [Center for Direct Catalytic Conversion Of Biomass to Biofuels (C3Bio), Purdue University, West Lafayette IN USA; Department of Biological Sciences, Purdue University, West Lafayette IN USA; Murphy, Angus S. [Center for Direct Catalytic Conversion Of Biomass to Biofuels (C3Bio), Purdue University, West Lafayette IN USA; Department of Horticulture, Purdue University, West Lafayette IN USA; Department of Plant Science and Landscape Architecture, University of Maryland, College Park MD USA; Peer, Wendy A. [Center for Direct Catalytic Conversion Of Biomass to Biofuels (C3Bio), Purdue University, West Lafayette IN USA; Department of Horticulture, Purdue University, West Lafayette IN USA; Department of Plant Science and Landscape Architecture, University of Maryland, College Park MD USA; Department of Environmental Science and Technology, University of Maryland, College Park MD USA

2016-04-07

Conversion of nongrain biomass into liquid fuel is a sustainable approach to energy demands as global population increases. Previously, we showed that iron can act as a catalyst to enhance the degradation of lignocellulosic biomass for biofuel production. However, direct addition of iron catalysts to biomass pretreatment is diffusion-limited, would increase the cost and complexity of biorefinery unit operations and may have deleterious environmental impacts. Here, we show a new strategy for in planta accumulation of iron throughout the volume of the cell wall where iron acts as a catalyst in the deconstruction of lignocellulosic biomass. We engineered CBM-IBP fusion polypeptides composed of a carbohydrate-binding module family 11 (CBM11) and an iron-binding peptide (IBP) for secretion into Arabidopsis and rice cell walls. CBM-IBP transformed Arabidopsis and rice plants show significant increases in iron accumulation and biomass conversion compared to respective controls. Further, CBM-IBP rice shows a 35% increase in seed iron concentration and a 40% increase in seed yield in greenhouse experiments. CBM-IBP rice potentially could be used to address iron deficiency, the most common and widespread nutritional disorder according to the World Health Organization.

Quantifying above- and belowground biomass carbon loss with forest conversion in tropical lowlands of Sumatra (Indonesia).

Science.gov (United States)

Kotowska, Martyna M; Leuschner, Christoph; Triadiati, Triadiati; Meriem, Selis; Hertel, Dietrich

2015-10-01

Natural forests in South-East Asia have been extensively converted into other land-use systems in the past decades and still show high deforestation rates. Historically, lowland forests have been converted into rubber forests, but more recently, the dominant conversion is into oil palm plantations. While it is expected that the large-scale conversion has strong effects on the carbon cycle, detailed studies quantifying carbon pools and total net primary production (NPPtotal ) in above- and belowground tree biomass in land-use systems replacing rainforest (incl. oil palm plantations) are rare so far. We measured above- and belowground carbon pools in tree biomass together with NPPtotal in natural old-growth forests, 'jungle rubber' agroforests under natural tree cover, and rubber and oil palm monocultures in Sumatra. In total, 32 stands (eight plot replicates per land-use system) were studied in two different regions. Total tree biomass in the natural forest (mean: 384 Mg ha(-1) ) was more than two times higher than in jungle rubber stands (147 Mg ha(-1) ) and >four times higher than in monoculture rubber and oil palm plantations (78 and 50 Mg ha(-1) ). NPPtotal was higher in the natural forest (24 Mg ha(-1)  yr(-1) ) than in the rubber systems (20 and 15 Mg ha(-1)  yr(-1) ), but was highest in the oil palm system (33 Mg ha(-1)  yr(-1) ) due to very high fruit production (15-20 Mg ha(-1)  yr(-1) ). NPPtotal was dominated in all systems by aboveground production, but belowground productivity was significantly higher in the natural forest and jungle rubber than in plantations. We conclude that conversion of natural lowland forest into different agricultural systems leads to a strong reduction not only in the biomass carbon pool (up to 166 Mg C ha(-1) ) but also in carbon sequestration as carbon residence time (i.e. biomass-C:NPP-C) was 3-10 times higher in the natural forest than in rubber and oil palm plantations. © 2015 John Wiley & Sons Ltd.

Process Design and Economics for the Conversion of Lignocellulosic Biomass to Hydrocarbons via Indirect Liquefaction. Thermochemical Research Pathway to High-Octane Gasoline Blendstock Through Methanol/Dimethyl Ether Intermediates

Energy Technology Data Exchange (ETDEWEB)

Tan, E. C. D.; Talmadge, M.; Dutta, A.; Hensley, J.; Schaidle, J.; Biddy, M.; Humbird, D.; Snowden-Swan, L. J.; Ross, J.; Sexton, D.; Yap, R.; Lukas, J.

2015-03-01

This report was developed as part of the U.S. Department of Energy’s Bioenergy Technologies Office’s (BETO’s) efforts to enable the development of technologies for the production of infrastructure-compatible, cost-competitive liquid hydrocarbon fuels from lignocellulosic biomass feedstocks. The research funded by BETO is designed to advance the state of technology of biomass feedstock supply and logistics, conversion, and overall system sustainability. It is expected that these research improvements will be made within the 2022 timeframe. As part of their involvement in this research and development effort, the National Renewable Energy Laboratory and the Pacific Northwest National Laboratory investigate the economics of conversion pathways through the development of conceptual biorefinery process models and techno-economic analysis models. This report describes in detail one potential conversion process for the production of high-octane gasoline blendstock via indirect liquefaction of biomass. The processing steps of this pathway include the conversion of biomass to synthesis gas or syngas via indirect gasification, gas cleanup, catalytic conversion of syngas to methanol intermediate, methanol dehydration to dimethyl ether (DME), and catalytic conversion of DME to high-octane, gasoline-range hydrocarbon blendstock product. The conversion process configuration leverages technologies previously advanced by research funded by BETO and demonstrated in 2012 with the production of mixed alcohols from biomass. Biomass-derived syngas cleanup via reforming of tars and other hydrocarbons is one of the key technology advancements realized as part of this prior research and 2012 demonstrations. The process described in this report evaluates a new technology area for the downstream utilization of clean biomass-derived syngas for the production of high-octane hydrocarbon products through methanol and DME intermediates. In this process, methanol undergoes dehydration to

Biomass thermochemical conversion - overview of results; Biomassan jalostus - tutkimusalueen katsaus

Energy Technology Data Exchange (ETDEWEB)

Sipilae, K. [VTT Energy, Espoo (Finland). Energy Production Technologies

1995-12-31

In this Bioenergy research program the thermochemical conversion activities are mainly concentrated in three fields (1) flash pyrolysis and the use of wood oil in boilers and engines (2) biomass gasification for gas engine power plants and finally (3) conversion of black liquor and extractives in a pulp mill to various liquid fuels. Parallel to activities in Finland also significant work has been done in EU-Joule and Apas projects and in the IEA Bioenergy Agreement. In the area of flash pyrolysis technology, three new laboratory and PDU-units have been installed to VTT in order to produce various qualities of bio oils from wood and straw. The quality of pyrolysis oils have been characterized by physical and chemical methods supported by EU and IEA networks. Several companies are carrying out pyrolysis activities as well: Neste Oy is testing the wood oil in a 200 kW boiler, Waertsilae Diesel Oy is testing Canadian wood oil in a 1.5 MWe diesel power plant engine and Vapo Oy is carrying out investigations to produce pyrolysis oils in Finland. The biomass gasification coupled to a gas engine is an interesting alternative for small scale power production parallel to existing fluid bed boiler technology. VTT has installed a circulating fluid bed gasifier with advanced gas cleaning system to test various technologies in order to feed the gas to an engine. In order to produce liquid fuels at a pulp mill, the laboratory work has continued using crude soap as a raw material for high pressure liquid phase treatment and atmospheric pyrolysis process. The quality of the oil is like light fuel oil or diesel fuel, possibilities to use it as a lubricant will be investigated

Biomass thermochemical conversion - overview of results; Biomassan jalostus - tutkimusalueen katsaus

Energy Technology Data Exchange (ETDEWEB)

Sipilae, K [VTT Energy, Espoo (Finland). Energy Production Technologies

1996-12-31

In this Bioenergy research program the thermochemical conversion activities are mainly concentrated in three fields (1) flash pyrolysis and the use of wood oil in boilers and engines (2) biomass gasification for gas engine power plants and finally (3) conversion of black liquor and extractives in a pulp mill to various liquid fuels. Parallel to activities in Finland also significant work has been done in EU-Joule and Apas projects and in the IEA Bioenergy Agreement. In the area of flash pyrolysis technology, three new laboratory and PDU-units have been installed to VTT in order to produce various qualities of bio oils from wood and straw. The quality of pyrolysis oils have been characterized by physical and chemical methods supported by EU and IEA networks. Several companies are carrying out pyrolysis activities as well: Neste Oy is testing the wood oil in a 200 kW boiler, Waertsilae Diesel Oy is testing Canadian wood oil in a 1.5 MWe diesel power plant engine and Vapo Oy is carrying out investigations to produce pyrolysis oils in Finland. The biomass gasification coupled to a gas engine is an interesting alternative for small scale power production parallel to existing fluid bed boiler technology. VTT has installed a circulating fluid bed gasifier with advanced gas cleaning system to test various technologies in order to feed the gas to an engine. In order to produce liquid fuels at a pulp mill, the laboratory work has continued using crude soap as a raw material for high pressure liquid phase treatment and atmospheric pyrolysis process. The quality of the oil is like light fuel oil or diesel fuel, possibilities to use it as a lubricant will be investigated

Microbial conversion of biomass into bio-based polymers.

Science.gov (United States)

Kawaguchi, Hideo; Ogino, Chiaki; Kondo, Akihiko

2017-12-01

The worldwide market for plastics is rapidly growing, and plastics polymers are typically produced from petroleum-based chemicals. The overdependence on petroleum-based chemicals for polymer production raises economic and environmental sustainability concerns. Recent progress in metabolic engineering has expanded fermentation products from existing aliphatic acids or alcohols to include aromatic compounds. This diversity provides an opportunity to expand the development and industrial uses of high-performance bio-based polymers. However, most of the biomonomers are produced from edible sugars or starches that compete directly with food and feed uses. The present review focuses on recent progress in the microbial conversion of biomass into bio-based polymers, in which fermentative products from renewable feedstocks serve as biomonomers for the synthesis of bio-based polymers. In particular, the production of biomonomers from inedible lignocellulosic feedstocks by metabolically engineered microorganisms and the synthesis of bio-based engineered plastics from the biological resources are discussed. Copyright © 2017 Elsevier Ltd. All rights reserved.

Interfacing feedstock logistics with bioenergy conversion

Energy Technology Data Exchange (ETDEWEB)

Sokhansanj, S. [British Columbia Univ., Vancouver, BC (Canada). Oak Ridge National Lab

2010-07-01

The interface between biomass production and biomass conversion platforms was investigated. Functional relationships were assembled in a modeling platform to simulate the flow of biomass feedstock from farm and forest to a densification plant. The model considers key properties of biomass for downstream pre-processing and conversion. These properties include moisture content, cellulose, hemicelluloses, lignin, ash, particle size, specific density and bulk density. The model simulates logistical operations such as grinding to convert biomass to pellets that are supplied to a biorefinery for conversion to heat, power, or biofuels. Equations were developed to describe the physical aspects of each unit operation. The effect that each of the process variables has on the efficiency of the conversion processes was described.

One-pot conversion of biomass-derived xylose and furfural into levulinate esters via acid catalysis.

Science.gov (United States)

Hu, Xun; Jiang, Shengjuan; Wu, Liping; Wang, Shuai; Li, Chun-Zhu

2017-03-07

Direct conversion of biomass-derived xylose and furfural into levulinic acid, a platform molecule, via acid-catalysis has been accomplished for the first time in dimethoxymethane/methanol. Dimethoxymethane acted as an electrophile to transform furfural into 5-hydroxymethylfurfural (HMF). Methanol suppressed both the polymerisation of the sugars/furans and the Aldol condensation of levulinic acid/ester.

Biomass [updated

Energy Technology Data Exchange (ETDEWEB)

Turhollow Jr, Anthony F [ORNL

2016-01-01

Biomass resources and conversion technologies are diverse. Substantial biomass resources exist including woody crops, herbaceous perennials and annuals, forest resources, agricultural residues, and algae. Conversion processes available include fermentation, gasification, pyrolysis, anaerobic digestion, combustion, and transesterification. Bioderived products include liquid fuels (e.g. ethanol, biodiesel, and gasoline and diesel substitutes), gases, electricity, biochemical, and wood pellets. At present the major sources of biomass-derived liquid fuels are from first generation biofuels; ethanol from maize and sugar cane (89 billion L in 2013) and biodiesel from vegetable oils and fats (24 billion liters in 2011). For other than traditional uses, policy in the forms of mandates, targets, subsidies, and greenhouse gas emission targets has largely been driving biomass utilization. Second generation biofuels have been slow to take off.

Bioenergy research programme. Yearbook 1996. Utilization of bioenergy and biomass conversion; Bioenergian tutkimusohjelma. Vuosikirja 1996. Bioenergian kaeyttoe ja biomassan jalostus

Energy Technology Data Exchange (ETDEWEB)

Nikku, P [ed.

1997-12-01

The aim of the programme is to increase the use of economically profitable and environmentally sound bioenergy by improving the competitiveness of present peat and wood fuels. Research and development projects will also develop new economically competitive biofuels, new equipment and methods for production, handling and utilisation of biofuels. The total funding for 1996 was 27.3 million FIM and the number of projects 63. The number of projects concerning bioenergy use was 10 and biomass conversion 6. Results of the projects carried out in 1996 are presented in this publication. The aim of the bioenergy use is to develop and demonstrate at least 3-4 new equipment or methods for handling and use of biofuels. The equipment and/or methods should provide economically competitive and environmentally sound energy production. The second aim is to demonstrate 2-3 large-scale biofuel end-use technologies. Each of these should have a potential of 0.2- 0.3 million toe/a till the year 2000. The aims have been achieved in the field of fuel handling technologies and small-scale combustion concepts, but large-scale demonstration projects before the year 2000 seems to be a very challenging aim. The aim of the biomass conversion is to produce basic information on biomass conversion, to evaluate the quality of products, their usability, environmental effects of use as well as the total economy of the production. The objective of biomass conversion is to develop 2-3 new methods, which could be demonstrated, for the production and utilisation of liquefied, gasified and other converted biofuels. The production target is 0.2-0.3 million toe/a by the year 2000 at a competitive price level. The studies focused on the development of flash pyrolysis technology for biomass, and on the study of storage stability of imported wood oils and of their suitability for use in oil-fired boilers and diesel power plants

Biomass Characterization | Bioenergy | NREL

Science.gov (United States)

Characterization Biomass Characterization NREL provides high-quality analytical characterization of biomass feedstocks, intermediates, and products, a critical step in optimizing biomass conversion clear, amber liquid Standard Biomass Laboratory Analytical Procedures We maintain a library of

Low-temperature conversion of high-moisture biomass: Topical report, January 1984--January 1988

Energy Technology Data Exchange (ETDEWEB)

Sealock, L.J. Jr.; Elliott, D.C.; Butner, R.S.; Neuenschwander, G.G.

1988-10-01

Pacific Northwest Laboratory (PNL) is developing a low-temperature, catalytic process that converts high-moisture biomass feedstocks and other wet organic substances to useful gaseous and liquid fuels. The advantage of this process is that it works without the need for drying or dewatering the feedstock. Conventional thermal gasification processes, which require temperatures above 750/degree/C and air or oxygen for combustion to supply reaction heat, generally cannot utilize feedstocks with moisture contents above 50 wt %, as the conversion efficiency is greatly reduced as a result of the drying step. For this reason, anaerobic digestion or other bioconversion processes traditionally have been used for gasification of high-moisture feedstocks. However, these processes suffer from slow reaction rates and incomplete carbon conversion. 50 refs., 21 figs., 22 tabs.

Flow-through biological conversion of lignocellulosic biomass

Science.gov (United States)

Herring, Christopher D.; Liu, Chaogang; Bardsley, John

2014-07-01

The present invention is directed to a process for biologically converting carbohydrates from lignocellulosic biomass comprising the steps of: suspending lignocellulosic biomass in a flow-through reactor, passing a reaction solution into the reactor, wherein the solution is absorbed into the biomass substrate and at least a portion of the solution migrates through said biomass substrate to a liquid reservoir, recirculating the reaction solution in the liquid reservoir at least once to be absorbed into and migrate through the biomass substrate again. The biological converting of the may involve hydrolyzing cellulose, hemicellulose, or a combination thereof to form oligosaccharides, monomelic sugars, or a combination thereof; fermenting oligosaccharides, monomelic sugars, or a combination thereof to produce ethanol, or a combination thereof. The process can further comprise removing the reaction solution and processing the solution to separate the ethanol produced from non-fermented solids.

Potential for thermochemical conversion of biomass residues from the integrated sugar-ethanol process - Fate of ash and ash-forming elements.

Science.gov (United States)

Dirbeba, Meheretu Jaleta; Brink, Anders; DeMartini, Nikolai; Zevenhoven, Maria; Hupa, Mikko

2017-06-01

In this work, potential for thermochemical conversion of biomass residues from an integrated sugar-ethanol process and the fate of ash and ash-forming elements in the process are presented. Ash, ash-forming elements, and energy flows in the process were determined using mass balances and analyses of eight different biomass samples for ash contents, elemental compositions, and heating values. The results show that the ash content increases from the sugarcane to the final residue, vinasse. The cane straw, which is left in the field, contains one-third of the energy and 25% of the K and Cl while the vinasse contains 2% of the energy and 40% of the K and Cl in the cane. K and Cl in biomass fuels cause corrosion and fouling problems in boilers and gasifiers. Over 85% of these elements in the straw are water soluble indicating that water leaching would improve it for utilization in thermochemical conversion. Copyright © 2017 Elsevier Ltd. All rights reserved.

Main routes for the thermo-conversion of biomass into fuels and chemicals. Part 1: Pyrolysis systems

International Nuclear Information System (INIS)

Balat, Mustafa; Balat, Mehmet; Kirtay, Elif; Balat, Havva

2009-01-01

Since the energy crises of the 1970s, many countries have become interest in biomass as a fuel source to expand the development of domestic and renewable energy sources and reduce the environmental impacts of energy production. Biomass is used to meet a variety of energy needs, including generating electricity, heating homes, fueling vehicles and providing process heat for industrial facilities. The methods available for energy production from biomass can be divided into two main categories: thermo-chemical and biological conversion routes. There are several thermo-chemical routes for biomass-based energy production, such as direct combustion, liquefaction, pyrolysis, supercritical water extraction, gasification, air-steam gasification and so on. The pyrolysis is thermal degradation of biomass by heat in the absence of oxygen, which results in the production of charcoal (solid), bio-oil (liquid), and fuel gas products. Pyrolysis liquid is referred to in the literature by terms such as pyrolysis oil, bio-oil, bio-crude oil, bio-fuel oil, wood liquid, wood oil, liquid smoke, wood distillates, pyroligneous tar, and pyroligneous acid. Bio-oil can be used as a fuel in boilers, diesel engines or gas turbines for heat and electricity generation.

A high performance Trichoderma reesei strain that reveals the importance of xylanase III in cellulosic biomass conversion.

Science.gov (United States)

Nakazawa, Hikaru; Kawai, Tetsushi; Ida, Noriko; Shida, Yosuke; Shioya, Kouki; Kobayashi, Yoshinori; Okada, Hirofumi; Tani, Shuji; Sumitani, Jun-Ichi; Kawaguchi, Takashi; Morikawa, Yasushi; Ogasawara, Wataru

2016-01-01

The ability of the Trichoderma reesei X3AB1strain enzyme preparations to convert cellulosic biomass into fermentable sugars is enhanced by the replacement of xyn3 by Aspergillus aculeatus β-glucosidase 1 gene (aabg1), as shown in our previous study. However, subsequent experiments using T. reesei extracts supplemented with the glycoside hydrolase (GH) family 10 xylanase III (XYN III) and GH Family 11 XYN II showed increased conversion of alkaline treated cellulosic biomass, which is rich in xylan, underscoring the importance of XYN III. To attain optimal saccharifying potential in T. reesei, we constructed two new strains, C1AB1 and E1AB1, in which aabg1 was expressed heterologously by means of the cbh1 or egl1 promoters, respectively, so that the endogenous XYN III synthesis remained intact. Due to the presence of wild-type xyn3 in T. reesei E1AB1, enzymes prepared from this strain were 20-30% more effective in the saccharification of alkaline-pretreated rice straw than enzyme extracts from X3AB1, and also outperformed recent commercial cellulase preparations. Our results demonstrate the importance of XYN III in the conversion of alkaline-pretreated cellulosic biomass by T. reesei. Copyright © 2015 Elsevier Inc. All rights reserved.

A survey of Opportunities for Microbial Conversion of Biomass to Hydrocarbon Compatible Fuels

Energy Technology Data Exchange (ETDEWEB)

Jovanovic, Iva; Jones, Susanne B.; Santosa, Daniel M.; Dai, Ziyu; Ramasamy, Karthikeyan K.; Zhu, Yunhua

2010-09-01

Biomass is uniquely able to supply renewable and sustainable liquid transportation fuels. In the near term, the Biomass program has a 2012 goal of cost competitive cellulosic ethanol. However, beyond 2012, there will be an increasing need to provide liquid transportation fuels that are more compatible with the existing infrastructure and can supply fuel into all transportation sectors, including aviation and heavy road transport. Microbial organisms are capable of producing a wide variety of fuel and fuel precursors such as higher alcohols, ethers, esters, fatty acids, alkenes and alkanes. This report surveys liquid fuels and fuel precurors that can be produced from microbial processes, but are not yet ready for commercialization using cellulosic feedstocks. Organisms, current research and commercial activities, and economics are addressed. Significant improvements to yields and process intensification are needed to make these routes economic. Specifically, high productivity, titer and efficient conversion are the key factors for success.

Biomass Feedstocks | Bioenergy | NREL

Science.gov (United States)

Feedstocks Biomass Feedstocks Our mission is to enable the coordinated development of biomass generic biomass thermochemical conversion process (over a screened-back map of the United States) showing U.S. Biomass Resources, represented by photos of timber, corn stover, switchgrass, and poplar. All

Biomass energy

International Nuclear Information System (INIS)

Pasztor, J.; Kristoferson, L.

1992-01-01

Bioenergy systems can provide an energy supply that is environmentally sound and sustainable, although, like all energy systems, they have an environmental impact. The impact often depends more on the way the whole system is managed than on the fuel or on the conversion technology. The authors first describe traditional biomass systems: combustion and deforestation; health impact; charcoal conversion; and agricultural residues. A discussion of modern biomass systems follows: biogas; producer gas; alcohol fuels; modern wood fuel resources; and modern biomass combustion. The issue of bioenergy and the environment (land use; air pollution; water; socioeconomic impacts) and a discussion of sustainable bioenergy use complete the paper. 53 refs., 9 figs., 14 tabs

Solid biomass barometer - EurObserv'ER - December 2015

International Nuclear Information System (INIS)

2015-12-01

The European Reanalysis and Observations for Monitoring (EURO4M) project experts report that the year 2014 was unusually hot on the European continent, with the highest temperatures on record, following on from 2013 whose winter conditions were also exceptionally mild, and ahead of 2015 which is also set to be very warm. This situation led to a fall in solid biomass consumption for heating across the European Union. In 2014 electricity output increased by 4.5% on its 2013 level to 84.8 TWh, as the vagaries of climate have less impact on demand and it was also boosted by the expansion of biomass cogeneration and new coal-fired power plant conversions

Characterization of 2nd generation biomass under thermal conversion and the fate of nitrogen

Energy Technology Data Exchange (ETDEWEB)

Giuntoli, J.

2010-11-17

This dissertation deals with the characterization of several biomass materials under thermal conversion conditions using small-scale equipment. The fuels are tested under the conditions of slow and fast heating rate pyrolysis and combustion, with the main goal of investigating the chemistry of fuel-bound nitrogen. Among renewable sources, biomass materials hold a special position because they can, in the short term, substitute or integrate fossil fuels in all of their applications applying comparatively few changes to the existing equipment. Biomass wastes, from agriculture or other processes, are convenient in more respects since their use would not only substitute fossil fuels but it would also valorize waste streams. These materials, however, present several issues that are highly delaying their deployment on a large scale. Three of the most important problems are dealt with in this thesis: the heterogeneous nature of the materials, high amount of ash forming matter containing troublesome compounds such as K, Cl and P, and finally, high content of nitrogen. First of all, many biomass residues contain a higher amount of nitrogen compared with woody biomass or even coal. This high content of fuel-N could directly translate into high NOx emissions in combustion conditions or into a high content of nitrogen containing gases such as NH3 and HCN in the syngas from gasification. Primary measures, such as air staging, can be applied directly in the reactor in order to promote the reduction of NOx and NOx--precursors to molecular nitrogen. However, in order to apply such measures and optimize the syngas composition or minimize emissions without relying on expensive catalysts, a detailed knowledge of the mechanisms of fuel-N conversion is required. This thesis has as its main purpose to study the release of volatile nitrogen compounds under pyrolysis conditions and the analysis of the emissions of NO under combustion conditions from high-N fuels. Secondly, as explained in

Secondary Forest Age and Tropical Forest Biomass Estimation Using TM

Science.gov (United States)

Nelson, R. F.; Kimes, D. S.; Salas, W. A.; Routhier, M.

1999-01-01

The age of secondary forests in the Amazon will become more critical with respect to the estimation of biomass and carbon budgets as tropical forest conversion continues. Multitemporal Thematic Mapper data were used to develop land cover histories for a 33,000 Square kM area near Ariquemes, Rondonia over a 7 year period from 1989-1995. The age of the secondary forest, a surrogate for the amount of biomass (or carbon) stored above-ground, was found to be unimportant in terms of biomass budget error rates in a forested TM scene which had undergone a 20% conversion to nonforest/agricultural cover types. In such a situation, the 80% of the scene still covered by primary forest accounted for over 98% of the scene biomass. The difference between secondary forest biomass estimates developed with and without age information were inconsequential relative to the estimate of biomass for the entire scene. However, in futuristic scenarios where all of the primary forest has been converted to agriculture and secondary forest (55% and 42% respectively), the ability to age secondary forest becomes critical. Depending on biomass accumulation rate assumptions, scene biomass budget errors on the order of -10% to +30% are likely if the age of the secondary forests are not taken into account. Single-date TM imagery cannot be used to accurately age secondary forests into single-year classes. A neural network utilizing TM band 2 and three TM spectral-texture measures (bands 3 and 5) predicted secondary forest age over a range of 0-7 years with an RMSE of 1.59 years and an R(Squared) (sub actual vs predicted) = 0.37. A proposal is made, based on a literature review, to use satellite imagery to identify general secondary forest age groups which, within group, exhibit relatively constant biomass accumulation rates.

Improving the conversion of biomass in catalytic fast pyrolysis via white-rot fungal pretreatment.

Science.gov (United States)

Yu, Yanqing; Zeng, Yelin; Zuo, Jiane; Ma, Fuying; Yang, Xuewei; Zhang, Xiaoyu; Wang, Yujue

2013-04-01

This study investigated the effect of white-rot fungal pretreatment on corn stover conversion in catalytic fast pyrolysis (CFP). Corn stover pretreated by white-rot fungus Irpex lacteus CD2 was fast pyrolyzed alone (non-CFP) and with ZSM-5 zeolite (CFP) in a semi-batch pyroprobe reactor. The fungal pretreatment considerably increased the volatile product yields (predominantly oxygenated compounds) in non-CFP, indicating that fungal pretreatment enhances the corn stover conversion in fast pyrolysis. In the presence of ZSM-5 zeolite, these oxygenated volatiles were further catalytically converted to aromatic hydrocarbons, whose yield increased from 10.03 wt.% for the untreated corn stover to 11.49 wt.% for the pretreated sample. In contrast, the coke yield decreased from 14.29 to 11.93 wt.% in CFP following the fungal pretreatment. These results indicate that fungal pretreatment can enhance the production of valuable aromatics and decrease the amount of undesired coke, and thus has a beneficial effect on biomass conversion in CFP. Copyright © 2013 Elsevier Ltd. All rights reserved.

Decentralized energy conversion of biomass from Amstelland. The feasibility of decentralized use of energy from green wastes in the municipality Amstelveen and its environs

International Nuclear Information System (INIS)

Brouwer, H.D.

1997-10-01

The aim of the study on the title subject is to determine the enviro-technical and economical feasibility of decentralized biomass conversion as part of the green area and energy infrastructure of the region Amstelland, Netherlands. The parts of the study concern a regional inventory of green wastes in Amstelland, an energy demand analysis of conversion sites in the region, a logistic analysis, an evaluation of technical options (cogeneration, combustion, gasification), business economical analysis of the investments, determining the support and willingness to contribute and cooperate, and drafting a final report. Based on the results of the report decisions can be made whether or not the design and installation of a decentralized biomass conversion system should be elaborated in detail. 16 refs

Expanding the biomass resource: sustainable oil production via fast pyrolysis of low input high diversity biomass and the potential integration of thermochemical and biological conversion routes.

Science.gov (United States)

Corton, J; Donnison, I S; Patel, M; Bühle, L; Hodgson, E; Wachendorf, M; Bridgwater, A; Allison, G; Fraser, M D

2016-09-01

Waste biomass is generated during the conservation management of semi-natural habitats, and represents an unused resource and potential bioenergy feedstock that does not compete with food production. Thermogravimetric analysis was used to characterise a representative range of biomass generated during conservation management in Wales. Of the biomass types assessed, those dominated by rush ( Juncus effuses ) and bracken ( Pteridium aquilinum ) exhibited the highest and lowest volatile compositions respectively and were selected for bench scale conversion via fast pyrolysis. Each biomass type was ensiled and a sub-sample of silage was washed and pressed. Demineralization of conservation biomass through washing and pressing was associated with higher oil yields following fast pyrolysis. The oil yields were within the published range established for the dedicated energy crops miscanthus and willow. In order to examine the potential a multiple output energy system was developed with gross power production estimates following valorisation of the press fluid, char and oil. If used in multi fuel industrial burners the char and oil alone would displace 3.9 × 10 5  tonnes per year of No. 2 light oil using Welsh biomass from conservation management. Bioenergy and product development using these feedstocks could simultaneously support biodiversity management and displace fossil fuels, thereby reducing GHG emissions. Gross power generation predictions show good potential.

Monitoring `Renewable fuels`. Gasification and pyrolysis of biomass. Second situation report; Monitoring ``Nachwachsende Rohstoffe``. Vergasung und Pyrolyse von Biomasse. Zweiter Sachstandsbericht

Energy Technology Data Exchange (ETDEWEB)

Roesch, C; Wintzer, D

1997-04-01

The second situation report deals with gasification and pyrolysis as means of improving the energetic utilisation of wood and strawlike biomass and with various possibilities of utilising the gas produced in these processes. It also presents different gasification techniques, measures for gas purification, and ways of utilising gas for electricity generation. Out of the wide range of possible process combinations for producing energy from biomass the report only deals more closely with a few concepts that appear very promising from today`s viewpoint. Working from the current state and perspectives of technical development and from prospective operating conditions and potential market chances of pyrolysis and gasification the report deliberates on the future orientation of research, development, and demonstration activities. (orig./SR) [Deutsch] Im zweiten Sachstandsbericht werden die Vergasung und Pyrolyse zur besseren energetischen Nutzung von Holz und halmartiger Biomasse und verschiedene Moeglichkeiten zur Verwertung des dabei erzeugten Gases betrachtet. Es werden unterschiedliche Vergasungstechniken, Massnahmen zur Gasreinigung und Arten der Gasnutzung zur Stromgewinnung dargestellt. Aus der Vielzahl an moeglichen Kombinationen werden einige, aus gegenwaertiger Sichtweise besonders vielversprechende Konzepte zur Energieerzeugung ueber die Biomassevergasung naeher ausgefuehrt. Ausgehend vom Stand und von den Perspektiven der technischen Entwicklungen sowie den Einsatzbedingungen und potentiellen Marktchancen werden Schlussfolgerungen fuer die zukuenftige Ausrichtung im Bereich Forschung, Entwicklung und Demonstration Anstrengungen gezogen. (orig./SR)

Energy efficient thermochemical conversion of very wet biomass to biofuels by integration of steam drying, steam electrolysis and gasification

DEFF Research Database (Denmark)

Clausen, Lasse Røngaard

2017-01-01

A novel system concept is presented for the thermochemical conversion of very wet biomasses such as sewage sludge and manure. The system integrates steam drying, solid oxide electrolysis cells (SOEC) and gasification for the production of synthetic natural gas (SNG). The system is analyzed...

Laccases as a Potential Tool for the Efficient Conversion of Lignocellulosic Biomass: A Review

Directory of Open Access Journals (Sweden)

Úrsula Fillat

2017-05-01

Full Text Available The continuous increase in the world energy and chemicals demand requires the development of sustainable alternatives to non-renewable sources of energy. Biomass facilities and biorefineries represent interesting options to gradually replace the present industry based on fossil fuels. Lignocellulose is the most promising feedstock to be used in biorefineries. From a sugar platform perspective, a wide range of fuels and chemicals can be obtained via microbial fermentation processes, being ethanol the most significant lignocellulose-derived fuel. Before fermentation, lignocellulose must be pretreated to overcome its inherent recalcitrant structure and obtain the fermentable sugars. Usually, harsh conditions are required for pretreatment of lignocellulose, producing biomass degradation and releasing different compounds that are inhibitors of the hydrolytic enzymes and fermenting microorganisms. Moreover, the lignin polymer that remains in pretreated materials also affects biomass conversion by limiting the enzymatic hydrolysis. The use of laccases has been considered as a very powerful tool for delignification and detoxification of pretreated lignocellulosic materials, boosting subsequent saccharification and fermentation processes. This review compiles the latest studies about the application of laccases as useful and environmentally friendly delignification and detoxification technology, highlighting the main challenges and possible ways to make possible the integration of these enzymes in future lignocellulose-based industries.

A novel biorefinery integration concept for lignocellulosic biomass

International Nuclear Information System (INIS)

Özdenkçi, Karhan; De Blasio, Cataldo; Muddassar, Hassan R.; Melin, Kristian; Oinas, Pekka; Koskinen, Jukka; Sarwar, Golam; Järvinen, Mika

2017-01-01

Highlights: • Wide review is provided on supply chain and biomass conversion processes. • The requirements for sustainable biorefinery are listed. • An enhanced version distributed-centralized network is proposed. • A novel hydrothermal process is proposed for biomass conversion. - Abstract: The concept of an integrated biorefinery has increasing importance regarding sustainability aspects. However, the typical concepts have techno-economic issues: limited replacement in co-processing with fossil sources and high investment costs in integration to a specific plant. These issues have directed the current investigations to supply-chain network systems. On the other hand, these studies have the scope of a specific product and/or a feedstock type. This paper proposes a novel biorefinery concept for lignocellulosic biomass: sectoral integration network and a new hydrothermal process for biomass conversion. The sectoral integration concept has the potential for sustainable production from biomass: pre-treatment at the biomass sites, regional distributed conversion of biomass from various sectors (e.g. black liquor, sawdust, straw) and centralized upgrading/separation of crude biofuels. On the other hand, the conversion processes compose the vital part of such a concept. The new conversion involves partial wet oxidation - or simultaneous dissolution with partial wet oxidation for solid biomass- followed by lignin recovery with acidification and a reactor that can perform either hydrothermal liquefaction or supercritical water gasification. The process can intake both liquid and solid biomass to produce lignin as biomaterial and syngas or bio-oil. The new concept can contribute social development of rural areas by utilizing waste as valuable raw material for the production of multiple products and reduce the net greenhouse gas emissions by replacing fossil-based production.

Vegetal and animal biomass; Les biomasses vegetales et animales

Energy Technology Data Exchange (ETDEWEB)

Combarnous, M. [Bordeaux-1 Univ., Lab. Energetique et Phenomenes de Transfert, UMR CNRS ENSAM, 33 - Talence (France)

2005-07-01

This presentation concerns all types of biomass of the earth and the seas and the relative implicit consumptions. After an evaluation of the food needs of the human being, the author discusses the solar energy conversion, the energetic flux devoted to the agriculture production, the food chain and the biomass. (A.L.B.)

Biomass CHP Catalog of Technologies

Science.gov (United States)

This report reviews the technical and economic characterization of biomass resources, biomass preparation, energy conversion technologies, power production systems, and complete integrated CHP systems.

Methods for pretreating biomass

Science.gov (United States)

Balan, Venkatesh; Dale, Bruce E; Chundawat, Shishir; Sousa, Leonardo

2017-05-09

A method for pretreating biomass is provided, which includes, in a reactor, allowing gaseous ammonia to condense on the biomass and react with water present in the biomass to produce pretreated biomass, wherein reactivity of polysaccharides in the biomass is increased during subsequent biological conversion as compared to the reactivity of polysaccharides in biomass which has not been pretreated. A method for pretreating biomass with a liquid ammonia and recovering the liquid ammonia is also provided. Related systems which include a biochemical or biofuel production facility are also disclosed.

Hydrothermal liquefaction of biomass

DEFF Research Database (Denmark)

Toor, Saqib; Rosendahl, Lasse; Hoffmann, Jessica

2014-01-01

Biomass is one of the most abundant sources of renewable energy, and will be an important part of a more sustainable future energy system. In addition to direct combustion, there is growing attention on conversion of biomass into liquid en-ergy carriers. These conversion methods are divided...... into biochemical/biotechnical methods and thermochemical methods; such as direct combustion, pyrolysis, gasification, liquefaction etc. This chapter will focus on hydrothermal liquefaction, where high pressures and intermediate temperatures together with the presence of water are used to convert biomass...... into liquid biofuels, with the aim of describing the current status and development challenges of the technology. During the hydrothermal liquefaction process, the biomass macromolecules are first hydrolyzed and/or degraded into smaller molecules. Many of the produced molecules are unstable and reactive...

Isotopic abundance of 13 C and contribution of eucalyptus biomass to soil organic matter conversion

Directory of Open Access Journals (Sweden)

Fabiane Figueiredo Severo

Full Text Available ABSTRACT: It has become possible to evaluate the conversion of soil organic matter (SOM in pastures and arboreal crops due to the difference between the photosynthetic cycles of Eucalyptus (C3 and most grasses (C4. The auto analyzer method coupled to the IRMS (Isotope Ratio Mass Spectrometer in the present study evaluated the 13C content in soil profiles of Eucalyptus plantations of different ages (2, 10 and 21 years, in natural regeneration areas and natural grazing fields, and estimated the SOM conversion of each crop type of. The initial management of all sampled areas was natural pasture. The following profile layers were evaluated: 0-5, 5-10, 10-20, 20-30, 30-40, 40-50, 50-70 and 70-90cm, and the contribution of Eucalyptus biomass over the years of farming was estimated in the SOM conversion process. After 2 years of planting Eucalyptus, the beginning of pasture carbon conversion process occurred in the surface layer (0-5cm. Ten years after planting, the process of converting organic matter by arboreal crops reached the layers up to 20cm. After 21 years of planting and in natural regeneration areas, the entire profile has already been changed by planting Eucalyptus and native tree species.

Synthesis, Characterization and Evaluation of Tin-containing Silicates for Biomass Conversion

DEFF Research Database (Denmark)

Tolborg, Søren

at optimized conditions. The effect of alkali was found to transcend to a variety of sugars, solvents and other stannosilicates such as Sn-MCM-41 or Sn-Beta prepared by a post-synthesis methodology. The latter makes it possible to use industrially relevant tin-containing catalysts to achieved high yields......The transition to renewable carbon sources such as biomass will require entirely new catalytic processes and result in completely new products. An entire industry is built up around the chemicals that are available from fossil resources but will be unfeasible to prepare from other carbon sources....... This dissertation describes the preparation and use of several important stannosilicate materials, known to transform carbohydrates into different valuable products. Several aspects of the tin-containing catalysts are investigated and discussed and new insight into the conversion of sugars is provided. The catalyst...

Biochemical Conversion Processes of Lignocellulosic Biomass to Fuels and Chemicals - A Review.

Science.gov (United States)

Brethauer, Simone; Studer, Michael H

2015-01-01

Lignocellulosic biomass - such as wood, agricultural residues or dedicated energy crops - is a promising renewable feedstock for production of fuels and chemicals that is available at large scale at low cost without direct competition for food usage. Its biochemical conversion in a sugar platform biorefinery includes three main unit operations that are illustrated in this review: the physico-chemical pretreatment of the biomass, the enzymatic hydrolysis of the carbohydrates to a fermentable sugar stream by cellulases and finally the fermentation of the sugars by suitable microorganisms to the target molecules. Special emphasis in this review is put on the technology, commercial status and future prospects of the production of second-generation fuel ethanol, as this process has received most research and development efforts so far. Despite significant advances, high enzyme costs are still a hurdle for large scale competitive lignocellulosic ethanol production. This could be overcome by a strategy termed 'consolidated bioprocessing' (CBP), where enzyme production, enzymatic hydrolysis and fermentation is integrated in one step - either by utilizing one genetically engineered superior microorganism or by creating an artificial co-culture. Insight is provided on both CBP strategies for the production of ethanol as well as of advanced fuels and commodity chemicals.

Value-added Chemicals from Biomass by Heterogeneous Catalysis

DEFF Research Database (Denmark)

Voss, Bodil

feedstock, having retained one C-C bond originating from the biomass precursor, the aspects of utilising heterogeneous catalysis for its conversion to value added chemicals is investigated. Through a simple analysis of known, but not industrialised catalytic routes, the direct conversion of ethanol....... The results of the thesis, taking one example of biomass conversion, show that the utilisation of biomass in the production of chemicals by heterogeneous catalysis is promising from a technical point of view. But risks of market price excursions dominated by fossil based chemicals further set a criterion...... been implemented. The subject on chemical production has received less attention. This thesis describes and evaluates the quest for an alternative conversion route, based on a biomass feedstock and employing a heterogeneous catalyst capable of converting the feedstock, to a value-added chemical...

Contributions at the DGMK conference conversion of biomass. Conferene report; Beitraege zur DGMK-Fachbereichstagung Konversion von Biomassen. Tagungsbericht

Energy Technology Data Exchange (ETDEWEB)

NONE

2010-07-01

Within the DGMK conference on conversion of biomass between 10th and 12th May 2010 in Gelsenkirchen (Federal Republic of Germany) the following lectures were held: (1) How much does carbon need humans? (H. Puetter); (2) Enhanced exergy and energetic efficiency of utilization biomass by mean of bio methane and bio-SNG (E. Oettel); (3) Determination of specified costs and ecologic effects of BTL fuels (R. Stahlschmidt); (4) Conversion of cellulose in sugar alcohols as entry point of a biorefinery concept (R. Palkovits); (5) bio coke as a product of substitution for fossil metallurgical coke (S.H. Freitas Seabra da Rocha); (6) About the development of a thermochemical gasification of biomass for combined heat and power generation in Germany in the years 2008/2009 (D. Braekow); (7) Updraft gasification: A status on the harboore technology (R. Heeb); (8) Hydrogen production from biomass by means of an adsorption supported reformation in a dual circulation fluidised-bed plant (A. Schuster); (9) Flow gasification of high viscous suspension fuels (T. Kolb); (10) Gasification of different raw materials in a staged melt gasification with subsequent hot gas cleaning and CO shift catalysis (M. Kleinhappl); (11) Methanization of biogenic syngas - Influence of operation parameters of gasification on gas quality and catalyst deactivation (Th. Kienberger); (12) Bio-SNG - future regenerative energy source in the gas grid of E.ON (M. Adelt); (13) Heterogeneous degradation of pyrolysis oil at activated carbon (W. Wiest); (14) Ti-based Cu/Ni nanocatalyst for steam reformation of model tars (F. Wiedenmann); (15) Cleaning of fuel gas from the gasification of biomass by means of electro filter (H. Oldenburg); (16) Dedusting of product gas behind biomass gasification reactors with Herding {sup registered} ALPHA filter (W. Duerlich); (17) An investigation of enhancement of performance for the utilization of lean gas and syngas in gas motors (J. Krueger); (18) Amount of pollutants in waste

Routing of biomass for sustainable agricultural development

International Nuclear Information System (INIS)

Suhaimi Masduki; Aini Zakaria

1998-01-01

Photosynthetically derived biomass and residues, including waste products from food processing industries are renewable. They accumulate every year in large quantities, causing deterioration to the environment and loss of potentially valuable resources. The conserved energy is potentially convertible; thermodynamically the energy can be tapped into forms which are more amenable for value added agricultural applications or for other higher value products such as chemicals or their feedstocks. The forms and types in which this biomass has to be modified for the intended use depend on the costs or the respective alternatives. Under current situations, where chemical feedstocks are available in abundance at very competitive prices, biomass is obviously more suitably placed in the agro-industrial sector. Recycling of the biomass or residues into the soil as biofertilizers or for some other uses for agricultural applications requires less intense energy inputs for their improvements. Highly efficient biological processes with microorganisms as the primary movers in the production of the desired end products indeed require less capital costs than in most other industrial entities. In this paper, the various processes, which are potentially valuable and economically feasible in the conversion of biomass and residues for several products important in the agricultural sector, are described. Emphasis is given to the approach and the possible permutations of these processes to arrive at the desired good quality products for sustainable agricultural development. (Author)

Ab initio calculations and kinetic modeling of thermal conversion of methyl chloride: implications for gasification of biomass

DEFF Research Database (Denmark)

Singla, Mallika; Rasmussen, Morten Lund; Hashemi, Hamid

2018-01-01

. In the present work, the thermal conversion of CH3Cl under gasification conditions was investigated. A detailed chemical kinetic model for pyrolysis and oxidation of methyl chloride was developed and validated against selected experimental data from the literature. Key reactions of CH2Cl with O2 and C2H4......Limitations in current hot gas cleaning methods for chlorine species from biomass gasification may be a challenge for end use such as gas turbines, engines, and fuel cells, all requiring very low levels of chlorine. During devolatilization of biomass, chlorine is released partly as methyl chloride...... in low-temperature gasification. The present work illustrates how ab initio theory and chemical kinetic modeling can help to resolve emission issues for thermal processes in industrial scale....

Characterization and comparison of biomass produced from various sources: Suggestions for selection of pretreatment technologies in biomass-to-energy

International Nuclear Information System (INIS)

Chiang, Kung-Yuh; Chien, Kuang-Li; Lu, Cheng-Han

2012-01-01

Highlights: ► Biomass with higher volatile matter content has a higher carbon conversion rate. ► Applying the suitable pretreatment techniques that will enhance the bioenergy yield. ► The ratio of H 2 O/fixed carbon is a critical factor for enhancing the energy conversion. -- Abstract: This study investigated the characteristics of 26 varieties of biomass produced from forestry, agriculture, municipality, and industry in Taiwan to test their applicability in thermal conversion technologies and evaluation of enhanced energy efficiency. Understanding the reactivity of the tested biomass, the cluster analysis was also used in this research to classify into characteristics groups of biomass. This research also evaluated the feasibility of energy application of tested biomass by comparing it to the physicochemical properties of various coals used in Taiwan’s power plants. The experimental results indicated that the volatile matter content of the all tested biomass was 60% and above. It can be concluded that the higher carbon conversion rate will occur in the thermal conversion process of all tested biomass. Based on the results of lower heating value (LHV) of MSW and non-hazardous industrial sludge, the LHV was lower than other tested biomass that was between 1000 and 1800 kcal/kg. This is due to the higher moisture content of MSW and sludge that resulted in the lower LHV. Besides, the LHV of other tested biomass and their derived fuels was similar to the tested coal. However, the energy densities of woody and agricultural waste were smaller than that of the coal because the bulky densities of woody and agricultural wastes were low. That is, the energy utilization efficiency of woody and agricultural waste was relatively low. To improve the energy density of tested biomass, appropriate pre-treatment technologies, such as shredding, pelletizing or torrefied technologies can be applied, that will enhance the energy utilization efficiency of all tested biomass.

Technical and economic data biomass-based energy conversion systems for the production of gaseous and/or liquid energy carriers

International Nuclear Information System (INIS)

2000-02-01

The objectives of this study are: (1) to give an indication of the expected development of the currently mainly fossil fuel based Dutch energy supply system to a future CO 2 -emission 'free' energy supply system, and (2) to present main technological, economic, and environmental characteristics of three promising renewable energy based technologies for the production of gaseous and/or liquid secondary energy carriers and/or electricity and/or heat, viz.: (a) biomass hydrogasification for SNG (synthetic natural gas) production; (b) trigeneration of methanol and CHP (combined heat and power) from biomass by integrating a 'once-through' LPMEOH (liquid phase methanol) process into a 'conventional BIG/CC (Biomass-Integrated-Gasifier/Combined Cycle) system; and (c) trigeneration of Fischer-Tropsch derived transportation fuels and CHP from biomass by integrating a 'once-through' FT-process (Fischer-Tropsch) into a 'conventional' BIG/CC-system. Biomass conversion systems, for the production of CHP, transportation fuels, and as biofeedstock for the petrochemical industry, will play a substantial role in meeting the future Dutch renewable energy policy goals. In case fossil fuel prices remain low, additional policies are needed to reach these goals. Biomass will also play a significant role in reaching significant CO 2 emission reduction in Western Europe. In which sector the limited amount of biomass available/contractable can be applied best is still unclear, and therefore needs further research. By biomass hydrogasification it is possible to produce SNG with more or less the same composition as Groningen natural gas. In case relatively cheap hydrogen-rich waste gas streams are used in the short-term, the SNG production costs will he in the same order of magnitude as the market price for Dutch natural gas for small consumers (fl 0.6/Nm 3 ). The calculated minimum production costs for the 'green' fuels (methanol: 15 Euroct/l or 9 Euro/GJ, and FT-fuels: 27 Euroct/l or 9 Euro

Strain selection, biomass to biofuel conversion, and resource colocation have strong impacts on the economic performance of algae cultivation sites

Directory of Open Access Journals (Sweden)

Erik R. Venteris

2014-09-01

Full Text Available Decisions involving strain selection, biomass to biofuel technology, and the location of cultivation facilities can strongly influence the economic viability of an algae-based biofuel enterprise. We summarize our past results in a new analysis to explore the relative economic impact of these design choices. Our growth model is used to predict average biomass production for two saline strains (Nannocloropsis salina, Arthrospira sp., one fresh to brackish strain (Chlorella sp., DOE strain 1412, and one freshwater strain (order Sphaeropleales. Biomass to biofuel conversion is compared between lipid extraction (LE and hydrothermal liquefaction (HTL technologies. National-scale models of water, CO2 (as flue gas, land acquisition, site leveling, construction of connecting roads, and transport of HTL oil to existing refineries are used in conjunction with estimates of fuel value (from HTL to prioritize and select from 88,692 unit farms (UF, 405 ha in pond area, a number sufficient to produce 136E+9 L yr-1 of renewable diesel (36 billion gallons yr-1. Strain selection and choice of conversion technology have large economic impacts, with differences between combinations of strains and biomass to biofuel technologies being up to $10 million dollars yr-1 UF-1. Results based on the most productive strain, HTL-based fuel conversion, and resource costs show that the economic potential between geographic locations within the selection can differ by up to $4 million yr-1 UF-1, with 1.8 BGY of production possible from the most cost-effective sites. The local spatial variability in site rank is extreme, with very high and low sites within 10s of km of each other. Colocation with flue gas sources has a strong influence on rank, but the most costly resource component varies from site to site. The highest rank UFs are located predominantly in Florida and Texas, but most states south of 37°N latitude contain promising locations.

Strain Selection, Biomass to Biofuel Conversion, and Resource Colocation have Strong Impacts on the Economic Performance of Algae Cultivation Sites

Energy Technology Data Exchange (ETDEWEB)

Venteris, Erik R., E-mail: erik.venteris@pnl.gov; Wigmosta, Mark S.; Coleman, Andre M.; Skaggs, Richard L. [Pacific Northwest National Laboratory, Richland, WA (United States)

2014-09-16

Decisions involving strain selection, biomass to biofuel technology, and the location of cultivation facilities can strongly influence the economic viability of an algae-based biofuel enterprise. We summarize our past results in a new analysis to explore the relative economic impact of these design choices. Our growth model is used to predict average biomass production for two saline strains (Nannochloropsis salina and Arthrospira sp.), one fresh to brackish strain (Chlorella sp., DOE strain 1412), and one freshwater strain (order Sphaeropleales). Biomass to biofuel conversion is compared between lipid extraction and hydrothermal liquefaction (HTL) technologies. National-scale models of water, CO{sub 2} (as flue gas), land acquisition, site leveling, construction of connecting roads, and transport of HTL oil to existing refineries are used in conjunction with estimates of fuel value (from HTL) to prioritize and select from 88,692 unit farms (UF, 405 ha in pond area), a number sufficient to produce 136E + 9 L year{sup −1} of renewable diesel [36 billion gallons year{sup −1} (BGY)]. Strain selection and choice of conversion technology have large economic impacts, with differences between combinations of strains and biomass to biofuel technologies being up to $10 million year{sup −1} UF{sup −1}. Results based on the most productive strain, HTL-based fuel conversion, and resource costs show that the economic potential between geographic locations within the selection can differ by up to 4 million year{sup −1} UF{sup −1}, with 1.8 BGY of production possible from the most cost-effective sites. The local spatial variability in site rank is extreme, with very high and low sites within 10 kms of each other. Colocation with flue gas sources has a strong influence on rank, but the most costly resource component varies from site to site. The highest rank UFs are located predominantly in Florida and Texas, but most states south of 37°N latitude contain promising

Thermodynamic efficiency of biomass gasification and biofuels conversion

NARCIS (Netherlands)

Ptasinski, K.J.

2008-01-01

Biomass has great potential as a clean renewable feedstock for producing biofuels such as Fischer-Tropsch biodiesel, methanol, and hydrogen. The use of biomass is accompanied by possible ecological drawbacks, however, such as limitation of land or water and competition with food production. For

Biomass resources in California

Energy Technology Data Exchange (ETDEWEB)

Tiangco, V.M.; Sethi, P.S. [California Energy Commission, Sacramento, CA (United States)

1993-12-31

The biomass resources in California which have potential for energy conversion were assessed and characterized through the project funded by the California Energy Commission and the US Department of Energy`s Western Regional Biomass Energy Program (WRBEP). The results indicate that there is an abundance of biomass resources as yet untouched by the industry due to technical, economic, and environmental problems, and other barriers. These biomass resources include residues from field and seed crops, fruit and nut crops, vegetable crops, and nursery crops; food processing wastes; forest slash; energy crops; lumber mill waste; urban wood waste; urban yard waste; livestock manure; and chaparral. The estimated total potential of these biomass resource is approximately 47 million bone dry tons (BDT), which is equivalent to 780 billion MJ (740 trillion Btu). About 7 million BDT (132 billion MJ or 124 trillion Btu) of biomass residue was used for generating electricity by 66 direct combustion facilities with gross capacity of about 800 MW. This tonnage accounts for only about 15% of the total biomass resource potential identified in this study. The barriers interfering with the biomass utilization both in the on-site harvesting, collection, storage, handling, transportation, and conversion to energy are identified. The question whether these barriers present significant impact to biomass {open_quotes}availability{close_quotes} and {open_quotes}sustainability{close_quotes} remains to be answered.

Techno-economic Analysis for the Conversion of Lignocellulosic Biomass to Gasoline via the Methanol-to-Gasoline (MTG) Process

Energy Technology Data Exchange (ETDEWEB)

Jones, Susanne B.; Zhu, Yunhua

2009-05-01

Biomass is a renewable energy resource that can be converted into liquid fuel suitable for transportation applications. As a widely available biomass form, lignocellulosic biomass can have a major impact on domestic transportation fuel supplies and thus help meet the Energy Independence and Security Act renewable energy goals (U.S. Congress 2007). With gasification technology, biomass can be converted to gasoline via methanol synthesis and methanol-to-gasoline (MTG) technologies. Producing a gasoline product that is infrastructure ready has much potential. Although the MTG technology has been commercially demonstrated with natural gas conversion, combining MTG with biomass gasification has not been shown. Therefore, a techno-economic evaluation for a biomass MTG process based on currently available technology was developed to provide information about benefits and risks of this technology. The economic assumptions used in this report are consistent with previous U.S. Department of Energy Office of Biomass Programs techno-economic assessments. The feedstock is assumed to be wood chips at 2000 metric ton/day (dry basis). Two kinds of gasification technologies were evaluated: an indirectly-heated gasifier and a directly-heated oxygen-blown gasifier. The gasoline selling prices (2008 USD) excluding taxes were estimated to be $3.20/gallon and $3.68/gallon for indirectly-heated gasified and directly-heated. This suggests that a process based on existing technology is economic only when crude prices are above $100/bbl. However, improvements in syngas cleanup combined with consolidated gasoline synthesis can potentially reduce the capital cost. In addition, improved synthesis catalysts and reactor design may allow increased yield.

Thermochemical conversion of biomass in smouldering combustion across scales: The roles of heterogeneous kinetics, oxygen and transport phenomena.

Science.gov (United States)

Huang, Xinyan; Rein, Guillermo

2016-05-01

The thermochemical conversion of biomass in smouldering combustion is investigated here by combining experiments and modeling at two scales: matter (1mg) and bench (100g) scales. Emphasis is put on the effect of oxygen (0-33vol.%) and oxidation reactions because these are poorly studied in the literature in comparison to pyrolysis. The results are obtained for peat as a representative biomass for which there is high-quality experimental data published previously. Three kinetic schemes are explored, including various steps of drying, pyrolysis and oxidation. The kinetic parameters are found using the Kissinger-Genetic Algorithm method, and then implemented in a one-dimensional model of heat and mass transfer. The predictions are validated with thermogravimetric and bench-scale experiments and then analyzed to unravel the role of heterogeneous reaction. This is the first time that the influence of oxygen on biomass smouldering is explained in terms of both chemistry and transport phenomena across scales. Copyright © 2016 The Authors. Published by Elsevier Ltd.. All rights reserved.

Investigation of thermodynamic parameters in the pyrolysis conversion of biomass and manure to biochars using thermogravimetric analysis.

Science.gov (United States)

Xu, Yiliang; Chen, Baoliang

2013-10-01

The thermodynamic parameters of the conversion of two companion pair materials, i.e., rice straw vs dairy manure, and rice bran vs chicken manure, to biochars were characterized by thermogravimetric analysis. The overall changes of activation energy (Ea) were well described by the Flynn-Wall method. The Ea values increased steeply from about 120 to 180 kJ/mol at the mass conversion (α) at 0.2-0.4, followed by a relatively steady change at 0.40.65. The higher contents of minerals in manures resulted in the larger Ea. The individual conversion of hemicellulose, cellulose and lignin in the feedstocks was identified and their thermodynamic parameters (ΔH°, ΔG° and ΔS°) were calculated. The yields of biochars calculated from TG curve were compared with the determined yields of biochars using muffle pyrolysis. Along with Fourier transform infrared spectra data, the distinct decompositions of biomasses and manures were evaluated. Copyright © 2013 Elsevier Ltd. All rights reserved.

Biomass Conversion over Heteropoly Acid Catalysts

KAUST Repository

Zhang, Jizhe

2015-01-01

Biomass is a natural resource that is both abundant and sustainable. Its efficient utilization has long been the focus of research and development efforts with the aim to substitute it for fossil-based feedstock. In addition to the production

Thermodynamic evaluation of biomass-to-biofuels production systems

International Nuclear Information System (INIS)

Piekarczyk, Wodzisław; Czarnowska, Lucyna; Ptasiński, Krzysztof; Stanek, Wojciech

2013-01-01

Biomass is a renewable feedstock for producing modern energy carriers. However, the usage of biomass is accompanied by possible drawbacks, mainly due to limitation of land and water, and competition with food production. In this paper, the analysis concerns so-called second generation biofuels, like Fischer–Tropsch fuels or Substitute Natural Gas which are produced either from wood or from waste biomass. For these biofuels the most promising conversion case is the one which involves production of syngas from biomass gasification, followed by synthesis of biofuels. The thermodynamic efficiency of biofuels production is analyzed and compared using both the direct exergy analysis and the thermo-ecological cost. This analysis leads to the detection of exergy losses in various elements which forms the starting point to the improvement of conversion efficiency. The efficiency of biomass conversion to biofuels is also evaluated for the whole production chain, including biomass cultivation, transportation and conversion. The global effects of natural resources management are investigated using the thermo-ecological cost. The energy carriers' utilities such as electricity and heat are externally generated either from fossil fuels or from renewable biomass. In the former case the production of biofuels not always can be considered as a renewable energy source whereas in the latter case the production of biofuels leads always to the reduction of depletion of non-renewable resources

Product quality optimization in an integrated biorefinery: Conversion of pistachio nutshell biomass to biofuels and activated biochars via pyrolysis

International Nuclear Information System (INIS)

Işıtan, Seçil; Ceylan, Selim; Topcu, Yıldıray; Hintz, Chloe; Tefft, Juliann; Chellappa, Thiago; Guo, Jicheng; Goldfarb, Jillian L.

2016-01-01

Highlights: • Pyrolysis temperature key variable in manipulating biofuel quality. • Pyrolysis temperature does not impact activated biochar surface area. • Activation temperature key variable to optimize surface area of pistachio biochar. • Statistical model accurately predicts surface area of biochar, especially above 600 m"2/g. - Abstract: An economically viable transition to a renewable, sustainable energy future hinges on the ability to simultaneously produce multiple high value products from biomass precursors. Though there is considerable literature on the thermochemical conversion of biomass to biofuels and biochars, there are few holistic examinations that seek to understand trade-offs between biofuel quality and the associated pyrolysis conditions on activated carbons made from the resulting biochars. Using an Ordinary Least Squares regression analysis, this study probes the impact of pyrolysis and activation temperature on surface areas and pore volumes for 28 carbon dioxide-activated carbons. Activation temperature has the largest single impact of any other variable; increasing the temperature from 800 to 900 °C leads to an increase in surface area of more than 300 m"2/g. Contrary to some prior results, pyrolysis temperature has minimal effect on the resulting surface area and pore volume, suggesting that optimizing the temperature at which biofuels are extracted will have little impact on carbon dioxide-activated carbons. Increasing pyrolysis temperature increases methane formation but decreases gaseous hydrocarbons. Bio-oil obtained at lower pyrolysis temperatures shows fewer oxygenated compounds, indicating a greater stability, but higher pyrolysis temperatures maximize production of key biorefinery intermediaries such as furans. By analyzing data in such a holistic manner, it may be possible to optimize the production of biofuels and activated carbons from biomass by minimizing the amount of raw materials and energy necessary to maximize

Improvement of the energy conversion efficiency of Chlorella pyrenoidosa biomass by a three-stage process comprising dark fermentation, photofermentation, and methanogenesis.

Science.gov (United States)

Xia, Ao; Cheng, Jun; Ding, Lingkan; Lin, Richen; Huang, Rui; Zhou, Junhu; Cen, Kefa

2013-10-01

The effects of pre-treatment methods on saccharification and hydrogen fermentation of Chlorella pyrenoidosa biomass were investigated. When raw biomass and biomass pre-treated by steam heating, by microwave heating, and by ultrasonication were used as feedstock, the hydrogen yields were only 8.8-12.7 ml/g total volatile solids (TVS) during dark fermentation. When biomass was pre-treated by steam heating with diluted acid and by microwave heating with diluted acid, the dark hydrogen yields significantly increased to 75.6 ml/g TVS and 83.3 ml/g TVS, respectively. Steam heating with diluted acid is the preferred pre-treatment method of C. pyrenoidosa biomass to improve hydrogen yield during dark fermentation and photofermentation, which is followed by methanogenesis to increase energy conversion efficiency (ECE). A total hydrogen yield of 198.3 ml/g TVS and a methane yield of 186.2 ml/g TVS corresponding to an overall ECE of 34.0% were obtained through the three-stage process (dark fermentation, photofermentation, and methanogenesis). Copyright © 2013 Elsevier Ltd. All rights reserved.

Biomass for electricity

International Nuclear Information System (INIS)

Barbucci, P.; Neri, G.; Trebbi, G.

1995-01-01

This paper describes the activities carried out at ENEL-Thermal research center to develop technologies suitable to convert biomass into power with high conversion efficiency: a demonstration project, Energy Farm, to build an Integrated Gasification Combined Cycle (IGCC) plant fed by wood chips; a demonstration plant for converting wood chips into oil by thermal conversion (pyrolysis oil); combustion tests of different oils produced by thermal conversion. 3 figs., 1 tab

Biomass energy development

International Nuclear Information System (INIS)

Ng'eny-Mengech, A.

1990-01-01

This paper deals more specifically with biomethanation process and non conventional sources of biomass energy such as water hyacinths and vegetable oil hydrocarbon fuels. It highlights socioeconomic issues in biomass energy production and use. The paper also contains greater details on chemical conversion methods and processes of commercial ethanol and methanol production. (author). 291 refs., 6 tabs

The potential of the Malaysian oil palm biomass as a renewable energy source

International Nuclear Information System (INIS)

Loh, Soh Kheang

2017-01-01

Highlights: • An energy resource data for oil palm biomass is generated. • The data encompasses crucial fuel and physicochemical characteristics. • These characteristics guide on biomass behaviors and technology selection. • Oil palm biomass is advantageous in today’s energy competitive markets. • Overall, it is a green alternative for biorefinery establishment. - Abstract: The scarcity of conventional energy such as fossil fuels (which will lead to eventual depletion) and the ever-increasing demand for new energy sources have resulted in the world moving into an era of renewable energy (RE) and energy efficiency. The Malaysian oil palm industry has been one of the largest contributor of lignocellulosic biomass, with more than 90% of the country’s total biomass deriving from 5.4 million ha of oil palms. Recent concerns on accelerating replanting activity, improving oil extraction rate, expanding mill capacity, etc. are expected to further increase the total oil palm biomass availability in Malaysia. This situation has presented a huge opportunity for the utilization of oil palm biomass in various applications including RE. This paper characterizes the various forms of oil palm biomass for their important fuel and other physicochemical properties, and assesses this resource data in totality – concerning energy potential, the related biomass conversion technologies and possible combustion-related problems. Overall, oil palm biomass possesses huge potential as one of the largest alternative energy sources for commercial exploitation.

Recent progress in the development of solid catalysts for biomass conversion into high value-added chemicals

Science.gov (United States)

Hara, Michikazu; Nakajima, Kiyotaka; Kamata, Keigo

2015-06-01

In recent decades, the substitution of non-renewable fossil resources by renewable biomass as a sustainable feedstock has been extensively investigated for the manufacture of high value-added products such as biofuels, commodity chemicals, and new bio-based materials such as bioplastics. Numerous solid catalyst systems for the effective conversion of biomass feedstocks into value-added chemicals and fuels have been developed. Solid catalysts are classified into four main groups with respect to their structures and substrate activation properties: (a) micro- and mesoporous materials, (b) metal oxides, (c) supported metal catalysts, and (d) sulfonated polymers. This review article focuses on the activation of substrates and/or reagents on the basis of groups (a)-(d), and the corresponding reaction mechanisms. In addition, recent progress in chemocatalytic processes for the production of five industrially important products (5-hydroxymethylfurfural, lactic acid, glyceraldehyde, 1,3-dihydroxyacetone, and furan-2,5-dicarboxylic acid) as bio-based plastic monomers and their intermediates is comprehensively summarized.

Recent progress in the development of solid catalysts for biomass conversion into high value-added chemicals

International Nuclear Information System (INIS)

Hara, Michikazu; Nakajima, Kiyotaka; Kamata, Keigo

2015-01-01

In recent decades, the substitution of non-renewable fossil resources by renewable biomass as a sustainable feedstock has been extensively investigated for the manufacture of high value-added products such as biofuels, commodity chemicals, and new bio-based materials such as bioplastics. Numerous solid catalyst systems for the effective conversion of biomass feedstocks into value-added chemicals and fuels have been developed. Solid catalysts are classified into four main groups with respect to their structures and substrate activation properties: (a) micro- and mesoporous materials, (b) metal oxides, (c) supported metal catalysts, and (d) sulfonated polymers. This review article focuses on the activation of substrates and/or reagents on the basis of groups (a)–(d), and the corresponding reaction mechanisms. In addition, recent progress in chemocatalytic processes for the production of five industrially important products (5-hydroxymethylfurfural, lactic acid, glyceraldehyde, 1,3-dihydroxyacetone, and furan-2,5-dicarboxylic acid) as bio-based plastic monomers and their intermediates is comprehensively summarized. (focus issue review)

Recent progress in the development of solid catalysts for biomass conversion into high value-added chemicals

Science.gov (United States)

Hara, Michikazu; Nakajima, Kiyotaka; Kamata, Keigo

2015-01-01

In recent decades, the substitution of non-renewable fossil resources by renewable biomass as a sustainable feedstock has been extensively investigated for the manufacture of high value-added products such as biofuels, commodity chemicals, and new bio-based materials such as bioplastics. Numerous solid catalyst systems for the effective conversion of biomass feedstocks into value-added chemicals and fuels have been developed. Solid catalysts are classified into four main groups with respect to their structures and substrate activation properties: (a) micro- and mesoporous materials, (b) metal oxides, (c) supported metal catalysts, and (d) sulfonated polymers. This review article focuses on the activation of substrates and/or reagents on the basis of groups (a)–(d), and the corresponding reaction mechanisms. In addition, recent progress in chemocatalytic processes for the production of five industrially important products (5-hydroxymethylfurfural, lactic acid, glyceraldehyde, 1,3-dihydroxyacetone, and furan-2,5-dicarboxylic acid) as bio-based plastic monomers and their intermediates is comprehensively summarized. PMID:27877800

BIOETHANOL PRODUCTION BY MISCANTHUS AS A LIGNOCELLULOSIC BIOMASS: FOCUS ON HIGH EFFICIENCY CONVERSION TO GLUCOSE AND ETHANOL

Directory of Open Access Journals (Sweden)

Minhee Han Mail

2011-04-01

Full Text Available Current ethanol production processes using crops such as corn and sugar cane have been well established. However, the utilization of cheaper lignocellulosic biomass could make bioethanol more competitive with fossil fuels while avoiding the ethical concerns associated with using potential food resources. In this study, Miscanthus, a lignocellulosic biomass, was pretreated using NaOH to produce bioethanol. The pretreatment and enzymatic hydrolysis conditions were evaluated by response surface methodology (RSM. The optimal conditions were found to be 145.29 °C, 28.97 min, and 1.49 M for temperature, reaction time, and NaOH concentration, respectively. Enzymatic digestibility of pretreated Miscanthus was examined at various enzyme loadings (10 to 70 FPU/g cellulose of cellulase and 30 CbU/g of β-glucosidase. Regarding enzymatic digestibility, 50 FPU/g cellulose of cellulase and 30 CbU/g of β-glucosidase were selected as the test concentrations, resulting in a total glucose conversion rate of 83.92%. Fermentation of hydrolyzed Miscanthus using Saccharomyces cerevisiae resulted in an ethanol concentration of 59.20 g/L at 20% pretreated biomass loading. The results presented here constitute a significant contribution to the production of bioethanol from Miscanthus.

Thermodynamic data for biomass conversion and waste incineration

Energy Technology Data Exchange (ETDEWEB)

Domalski, E.S.; Jobe, T.L. Jr; Milne, T.A.

1986-09-01

The general purpose of this collection of thermodynamic data of selected materials is to make property information available to the engineering community on chemical mixtures, polymers, composite materials, solid wastes, biomass, and materials not easily identifiable by a single stoichiometric formula. More than 700 materials have been compiled covering properties such as specific heat, gross heat of combustion, heat of fusion, heat of vaporization, and vapor pressure. The information was obtained from the master files of the NBS Chemical Thermodynamics Data Center, the annual issues of the Bulletin of Chemical Thermodynamics, intermittent examinations of the Chemical Abstracts subject indexes, individual articles by various authors, and other general reference sources. The compilation is organized into several broad categories; materials are listed alphabetically within each category. For each material, the physical state, information as to the composition or character of the material, the kind of thermodynamic property reported, the specific property values for the material, and citations to the reference list are given. In addition, appendix A gives an empirical formula that allows heats of combustion of carbonaceous materials to be predicted with surprising accuracy when the elemental composition is known. A spread sheet illustrates this predictability with examples from this report and elsewhere. Appendix B lists some reports containing heats of combustion not included in this publication. Appendix C contains symbols, units, conversion factors, and atomic weights used in evaluating and compiling the thermodynamic data.

Energy from biomass: An overview

International Nuclear Information System (INIS)

Van der Toorn, L.J.; Elliott, T.P.

1992-01-01

Attention is paid to the effect of the use of energy from biomass on the greenhouse effect. An overview is given of the aspects of forest plantation, carbon dioxide fixation and energy from biomass, in particular with regard to the potential impact of the use of biomass energy on the speed of accumulation of carbon in the atmosphere. A simple model of the carbon cycle to illustrate the geochemical, biological and antropogenic characteristics of the cycle is presented and briefly discussed. Biomass, which is appropriate for energy applications, can be subdivided into three categories: polysaccharides, vegetable oils, and lignocellulosis. The costs for the latter are discussed. Three important options to use biomass as a commercial energy source are solid fuels, liquid fuels, and power generation. For each option the value of energy (on a large-scale level) is compared to the costs of several types of biomass. Recent evaluation of new techniques show that small biomass conversion plants can realize an electricity efficiency of 40%, with capitalized costs far below comparable conventional biomass conversion plants. One of the policy instruments to stimulate the use of biomass as an energy source is the carbon levy, in which the assumed external costs to reduce carbon dioxide emission are expressed. Political and administrative feasibility are important factors in the decision making with regard to carbon storage and energy plantations. 6 figs

Catalytic routes from biomass to fuels

DEFF Research Database (Denmark)

Riisager, Anders

2014-01-01

chain unaffected. This presentation will survey the status of biofuels production from different sources, and discuss the sustainability of making transportation fuels from biomass. Furthermore, recently developed chemocatalytic technologies that allow efficient conversion of lignocellulosic biomass...... the chemical industry to find new feasible chemocatalytic routes to convert the components of lignocellulosic plant biomass (green biomass) as well as aquatic biomass (blue biomass) into potential platform chemicals that can replace the fossil based chemicals in order to leave the chemical supply and value...

White Pine Co. Public School System Biomass Conversion Heating Project

Energy Technology Data Exchange (ETDEWEB)

Paul Johnson

2005-11-01

The White Pine County School District and the Nevada Division of Forestry agreed to develop a pilot project for Nevada using wood chips to heat the David E. Norman Elementary School in Ely, Nevada. Consideration of the project was triggered by a ''Fuels for Schools'' grant that was brought to the attention of the School District. The biomass project that was part of a district-wide energy retrofit, called for the installation of a biomass heating system for the school, while the current fuel oil system remained as back-up. Woody biomass from forest fuel reduction programs will be the main source of fuel. The heating system as planned and completed consists of a biomass steam boiler, storage facility, and an area for unloading and handling equipment necessary to deliver and load fuel. This was the first project of it's kind in Nevada. The purpose of the DOE funded project was to accomplish the following goals: (1) Fuel Efficiency: Purchase and install a fuel efficient biomass heating system. (2) Demonstration Project: Demonstrate the project and gather data to assist with further research and development of biomass technology; and (3) Education: Educate the White Pine community and others about biomass and other non-fossil fuels.

Allocation of biomass resources for minimising energy system greenhouse gas emissions

International Nuclear Information System (INIS)

Bentsen, Niclas Scott; Jack, Michael W.; Felby, Claus; Thorsen, Bo Jellesmark

2014-01-01

The European Union (EU) energy policy has three targets: supply security, development of a competitive energy sector and environmental sustainability. The EU countries have issued so-called National Renewable Energy Action Plans (NREAP) for increased renewable energy generation. Biomass is stipulated to account for 56% of renewable energy generation by 2020, corresponding to an increase in bioenergy generation from 2.4 × 10 9  GJ in 2005 to 5.7 × 10 9  GJ in 2020. There is uncertainty about the amounts of biomass available in the EU, and import challenges policy targets on supply security and sustainability. We address issues about how, from a technical point of view, the EU may deploy its biomass resources to reduce greenhouse gas (GHG) emissions from energy consumption. We investigate if deployment patterns depend on resource availability and technological development. In situations with adequate biomass availability the analysis suggests that liquid fuel production should be based on agricultural residues. Electricity production should be based on forest residues and other woody biomass and heat production on forest and agricultural residues. Improved conversion technologies implicitly relax the strain on biomass resources and improve supply security. - Highlights: • Optimal allocation of biomass to energy is analysed conceptually for the EU by 2020. • Allocation is influenced not only by GHG performance, also by resource availability. • Surplus biomass could be allocated to electricity generation to reduce GHG emissions

Bioenergy Research Programme, Yearbook 1995. Utilization of bioenergy and biomass conversion; Bioenergian tutkimusohjelma, vuosikirja 1995. Bioenergian kaeyttoe ja biomassan jalostus

Energy Technology Data Exchange (ETDEWEB)

Alakangas, E. [ed.

1996-12-31

Bioenergy Research Programme is one of the energy technology research programmes of the Technology Development Centre TEKES. The aim of the bioenergy Research Programme is to increase, by using technical research and development, the economically profitable and environmentally sound utilisation of bioenergy, to improve the competitiveness of present peat and wood fuels, and to develop new competitive fuels and equipment related to bioenergy. The funding for 1995 was nearly 52 million FIM and the number of projects 66. The research area of biomass conversion consisted of 8 projects in 1995, and the research area of bioenergy utilization of 14 projects. The results of these projects carried out in 1995 are presented in this publication. The aim of the biomass conversion is to produce more bio-oils and electric power as well as wood processing industry as at power plants than it is possible at present appliances. The conversion research was pointed at refining of the waste liquors of pulping industry and the extracts of them into fuel-oil and liquid engine fuels, on production of wood oil via flash pyrolysis, and on combustion tests. Other conversion studies dealt with production of fuel-grade ethanol. For utilization of agrobiomass in various forms of energy, a system study is introduced where special attention is how to use rapeseed oil unprocessed in heating boilers and diesel engines. The main aim of the research in bioenergy utilization is to create the technological potential for increasing the bioenergy use. The aim is further defined as to get into commercial phase 3-4 new techniques or methods and to start several demonstrations, which will have 0.2-0.3 million toe bioenergy utilization potential

Utilizing hydrogen in aqueous phase conversion of biomass

Energy Technology Data Exchange (ETDEWEB)

Peng, Baoxiang; Zhao, Chen; Li, Xuebing; Lercher, Johannes A. [Technische Univ. Muenchen, Garching (Germany). Technische Chemie II

2010-12-30

Hydrogen generation and selective hydrodeoxygenation of biomass are the key for the successful integration of biogenic carbon resources for energy carriers and intermediates. This includes the generation of hydrogen from biomass in the liquid phase and more importantly, for the direct utilization of the hydrogen generated into the molecules. We will outline this strategy with two groups of oxofunctionalized molecules, i.e., glycerol as example for the aliphatic group and substituted phenols as the aromatic group. (orig.)

Biomass availability and commercialization trend analysis in China. A marketing study

International Nuclear Information System (INIS)

2000-10-01

Among the different energy sources utilized in China, biomass energy takes a very important part. The importance of the biomass energy can be proved particularly in the rural area. In the period 1991 to 1995 the average consumption of bio-energy represented about 40% of the total rural energy consumption and about 70% of rural household energy consumption. The annual bio-energy consumption is more than 220 Mtce. According to prediction, all kinds of biomass fuels produced by new technology will take 40% of the total energy consumption all over the world at the middle of next century. In future decades, R and D for new technologies of producing all kinds of biomass energies as substitute fuels will be extremely important to China. The biomass energy resources in China mainly come from 4 sources: (1)The residues from agriculture and forestry processing such us straw, stalk, wood residues, high concentrated organic effluents from the agriculture products processing, etc.; (2) Firewood; (3) Human and animal excreta; and (4) Urban household solid wastes. The utilization technology of biomass energy can be generally classified as (a) The direct burn technology, which refers the method and equipment using crop straws and firewood as fuels through direct burning; (b) Physical conversion technology, which includes gasification technology by physical method - mainly heating and relevant equipment; (c) Biological conversion technology, which refers technology and equipment converting and gasifying the biomass through biological method - mainly anaerobic biodegradation; (d) Liquefaction technology; and (e) Conversion technology for solid waste. Chinese government has been giving great attention to the development and utilization of biomass energy. However, at present the bio-energy as one of the most important energy resources, its development and commercialized utilization are just at beginning stage. The basic conditions composing a market and commercialization environment

Biomass Processing using Ionic Liquids for Jet Fuel Production

Science.gov (United States)

2014-04-09

either water (W) or ethanol (E) as the nonsolvent and (bottom) enzymatic hydrolysis (cellulose conversion ) of the samples. PILs for Lignin Dissolution...of lignin) with IL dissolution of biomass has been demonstrated to be a highly effective pretreatment method for the conversion of raw cornstover...into glucose—this enables the rapid conversion (hydrolysis) of the biomass , while minimizing the amount of enzyme necessary (also a crucial issue for

Relationships between biomass composition and liquid products formed via pyrolysis

Directory of Open Access Journals (Sweden)

Fan eLin

2015-10-01

Full Text Available Thermal conversion of biomass is a rapid, low-cost way to produce a dense liquid product, known as bio-oil, that can be refined to transportation fuels. However, utilization of bio-oil is challenging due to its chemical complexity, acidity, and instability—all results of the intricate nature of biomass. A clear understanding of how biomass properties impact yield and composition of thermal products will provide guidance to optimize both biomass and conditions for thermal conversion. To aid elucidation of these associations, we first describe biomass polymers, including phenolics, polysaccharides, acetyl groups, and inorganic ions, and the chemical interactions among them. We then discuss evidence for three roles (i.e., models for biomass components in formation of liquid pyrolysis products: (1 as direct sources, (2 as catalysts, and (3 as indirect factors whereby chemical interactions among components and/or cell wall structural features impact thermal conversion products. We highlight associations that might be utilized to optimize biomass content prior to pyrolysis, though a more detailed characterization is required to understand indirect effects. In combination with high-throughput biomass characterization techniques this knowledge will enable identification of biomass particularly suited for biofuel production and can also guide genetic engineering of bioenergy crops to improve biomass features.

Relationships between Biomass Composition and Liquid Products Formed via Pyrolysis

International Nuclear Information System (INIS)

Lin, Fan; Waters, Christopher L.; Mallinson, Richard G.; Lobban, Lance L.; Bartley, Laura E.

2015-01-01

Thermal conversion of biomass is a rapid, low-cost way to produce a dense liquid product, known as bio-oil, that can be refined to transportation fuels. However, utilization of bio-oil is challenging due to its chemical complexity, acidity, and instability – all results of the intricate nature of biomass. A clear understanding of how biomass properties impact yield and composition of thermal products will provide guidance to optimize both biomass and conditions for thermal conversion. To aid elucidation of these associations, we first describe biomass polymers, including phenolics, polysaccharides, acetyl groups, and inorganic ions, and the chemical interactions among them. We then discuss evidence for three roles (i.e., models) for biomass components in the formation of liquid pyrolysis products: (1) as direct sources, (2) as catalysts, and (3) as indirect factors whereby chemical interactions among components and/or cell wall structural features impact thermal conversion products. We highlight associations that might be utilized to optimize biomass content prior to pyrolysis, though a more detailed characterization is required to understand indirect effects. In combination with high-throughput biomass characterization techniques, this knowledge will enable identification of biomass particularly suited for biofuel production and can also guide genetic engineering of bioenergy crops to improve biomass features.

Extremely thermophilic microorganisms for biomass conversion: status and prospects.

Science.gov (United States)

Blumer-Schuette, Sara E; Kataeva, Irina; Westpheling, Janet; Adams, Michael Ww; Kelly, Robert M

2008-06-01

Many microorganisms that grow at elevated temperatures are able to utilize a variety of carbohydrates pertinent to the conversion of lignocellulosic biomass to bioenergy. The range of substrates utilized depends on growth temperature optimum and biotope. Hyperthermophilic marine archaea (T(opt)>or=80 degrees C) utilize alpha- and beta-linked glucans, such as starch, barley glucan, laminarin, and chitin, while hyperthermophilic marine bacteria (T(opt)>or=80 degrees C) utilize the same glucans as well as hemicellulose, such as xylans and mannans. However, none of these organisms are able to efficiently utilize crystalline cellulose. Among the thermophiles, this ability is limited to a few terrestrial bacteria with upper temperature limits for growth near 75 degrees C. Deconstruction of crystalline cellulose by these extreme thermophiles is achieved by 'free' primary cellulases, which are distinct from those typically associated with large multi-enzyme complexes known as cellulosomes. These primary cellulases also differ from the endoglucanases (referred to here as 'secondary cellulases') reported from marine hyperthermophiles that show only weak activity toward cellulose. Many extremely thermophilic enzymes implicated in the deconstruction of lignocellulose can be identified in genome sequences, and many more promising biocatalysts probably remain annotated as 'hypothetical proteins'. Characterization of these enzymes will require intensive effort but is likely to generate new opportunities for the use of renewable resources as biofuels.

Technoeconomic assessment of biomass to energy

International Nuclear Information System (INIS)

Mitchell, C.P.; Watters, M.P.

1995-01-01

A spreadsheet-based decision support system has been developed that allows easy evaluation of integrated biomass to electricity and biomass to ethanol systems. The Bioenergy Assessment Model (BEAM) has been developed to allow the techno-economic assessment of biomass to electricity and biomass to ethanol schemes, including investigation of the interfacing issues. Technical and economic parameters can be assessed for a variety of feedstocks, conversion technologies and generating cycles. Production modules are currently available for biomass supply from short rotation coppice and conventional forestry relevant to conditions and practices in NW Europe. The biomass conversion modules include pre-treatment (reception, storage, handling, comminution, screening and drying); atmospheric gasification (generic gasifier, wet gas scrubbing, dual fuel engine); pressure gasification (generic gasifier, hot gas filtration, gas turbine combined cycle); fast pyrolysis for liquid bio-fuel-oil (pyrolyser, oil storage, pilot-injected diesel engine); combustion (fluid bed combuster steam turbine), conventional acid hydrolysis fermentation and the NREL SSF process to ethanol. In addition there is a further module which can be used to examine the collection, mass burn and generation of electricity from MSW. BEAM has been used, and the results presented in this paper, to determine the costs of generating bio-electricity from short rotation coppice and conventional forestry over a range of power outputs and for each conversion technology. Alternative feedstock supply strategies have been examined and relations drawn between delivered feedstock cost and cost of electricity. (author)

Green technology for conversion of renewable hydrocarbon based on plasma-catalytic approach

Science.gov (United States)

Fedirchyk, Igor; Nedybaliuk, Oleg; Chernyak, Valeriy; Demchina, Valentina

2016-09-01

The ability to convert renewable biomass into fuels and chemicals is one of the most important steps on our path to green technology and sustainable development. However, the complex composition of biomass poses a major problem for established conversion technologies. The high temperature of thermochemical biomass conversion often leads to the appearance of undesirable byproducts and waste. The catalytic conversion has reduced yield and feedstock range. Plasma-catalytic reforming technology opens a new path for biomass conversion by replacing feedstock-specific catalysts with free radicals generated in the plasma. We studied the plasma-catalytic conversion of several renewable hydrocarbons using the air plasma created by rotating gliding discharge. We found that plasma-catalytic hydrocarbon conversion can be conducted at significantly lower temperatures (500 K) than during the thermochemical ( 1000 K) and catalytic (800 K) conversion. By using gas chromatography, we determined conversion products and found that conversion efficiency of plasma-catalytic conversion reaches over 85%. We used obtained data to determine the energy yield of hydrogen in case of plasma-catalytic reforming of ethanol and compared it with other plasma-based hydrogen-generating systems.

Hemicellulose conversion by anaerobic digestion

Energy Technology Data Exchange (ETDEWEB)

Ghosh, S; Honry, M P; Christopher, R W

1985-01-01

This research was undertaken to study the digestibility of the hemicellulose fractions of an aquatic biomass, a land-based biomass and a biomass-waste blend under various fermentation conditions. The conversion of hemicellulose was higher than those of cellulose and protein under the mesophilic condition. Hemicellulose was converted at a much lower efficency than cellulose during thermophilic digestion. In contrast, cellulose conversion was about the same under mesophilic and thermophilic conditions. Cellulose was utilized in preference to hemicellulose during mesophilic fermentation of nitrogen-supplemented Bermuda grass. It was speculated that Bermuda grass cellulose was converted at a higher efficiency than hemicellulose in the pressure of external nitrogen because the metabolism of the breakdown product (glucose) of cellulose required the least investment of enzymes and energy. 4 references.

Strain selection, biomass to biofuel conversion, and resource colocation have strong impacts on the economic performance of algae cultivation sites

Energy Technology Data Exchange (ETDEWEB)

Venteris, Erik R.; Wigmosta, Mark S.; Coleman, Andre M.; Skaggs, Richard

2014-09-16

Decisions involving strain selection, biomass to biofuel technology, and the location of cultivation facilities can strongly influence the economic viability of an algae-based biofuel enterprise. In this contribution we summarize our past results in a new analysis to explore the relative economic impact of these design choices. We present strain-specific growth model results from two saline strains (Nannocloropsis salina, Arthrospira sp.), a fresh to brackish strain (Chlorella sp., DOE strain 1412), and a freshwater strain of the order Sphaeropleales. Biomass to biofuel conversion is compared between lipid extraction (LE) and hydrothermal liquefaction (HTL) technologies. National-scale models of water, CO2 (as flue gas), land acquisition, site leveling, construction of connecting roads, and transport of HTL oil to existing refineries are used in conjunction with estimates of fuel value (from HTL) to prioritize and select from 88,692 unit farms (UF, 405 ha in pond area), a number sufficient to produce 136E+9 L yr-1 of renewable diesel (36 billion gallons yr-1, BGY). Strain selection and choice of conversion technology have large economic impacts, with differences between combinations of strains and biomass to biofuel technologies being up to $10 million dollars yr-1 UF-1. Results based on the most productive species, HTL-based fuel conversion, and resource costs show that the economic potential between geographic locations within the selection can differ by up to $4 million yr-1 UF-1, with 2.0 BGY of production possible from the most cost-effective sites. The local spatial variability in site rank is extreme, with very high and low rank sites within 10s of km of each other. Colocation with flue gas sources has a strong influence on site rank, but the most costly resource component varies from site to site. The highest rank sites are located predominantly in Florida and Texas, but most states south of 37°N latitude contain promising locations. Keywords: algae

Enzymatic conversion of pretreated biomass into fermentable sugars for biorefinery operation

Science.gov (United States)

Gao, Dahai

2011-12-01

Depleting petroleum reserves and potential climate change caused by fossil fuel consumption have attracted significant attention towards the use of alternative renewable resources for production of fuels and chemicals. Lignocellulosic biomass provides a plentiful resource for the sustainable production of biofuels and biochemicals and could serve as an important contributor to the world energy portfolio in the near future. Successful biological conversion of lignocellulosic biomass requires an efficient and economical pretreatment method, high glucose/xylose yields during enzymatic hydrolysis and fermentation of both hexose and pentose to ethanol. High enzyme loading is a major economic bottleneck for the commercial processing of pretreated lignocellulosic biomass to produce fermentable sugars. Optimizing the enzyme cocktail for specific types of pretreated biomass allows for a significant reduction in enzyme loading without sacrificing hydrolysis yield. Core glycosyl hydrolases were isolated and purified from various sources to help rationally optimize an enzyme cocktail to digest ammonia fiber expansion (AFEX) treated corn stover. The four core cellulases were endoglucanase I (EG I), cellobiohydrolase I (CBH I), cellobiohydrolase II (CBH II) and beta-Glucosidase (betaG). The two core hemicellulases were an endoxylanase (EX) and a beta-xylosidase (betaX). A diverse set of accessory hemicellulases from bacterial sources was found necessary to enhance the synergistic action of cellulases hydrolysing AFEX pretreated corn stover. High glucose (around 80%) and xylose (around 70%) yields were achieved with a moderate enzyme loading (˜20 mg protein/g glucan) using an in-house developed enzyme cocktail and this cocktail was compared to commercial enzyme. Studying the binding properties of cellulases to lignocellulosic substrates is critical to achieving a fundamental understanding of plant cell wall saccharification. Lignin auto-fluorescence and degradation products

Environmental impacts of biomass energy resource production and utilization

Energy Technology Data Exchange (ETDEWEB)

Easterly, J L; Dunn, S M [DynCorp, Alexandria, VA (United States)

1995-12-01

The purpose of this paper is to provide a broad overview of the environmental impacts associated with the production, conversion and utilization of biomass energy resources and compare them with the impacts of conventional fuels. The use of sustainable biomass resources can play an important role in helping developing nations meet their rapidly growing energy needs, while providing significant environmental advantages over the use of fossil fuels. Two of the most important environmental benefits biomass energy offers are reduced net emissions of greenhouse gases, particularly CO{sub 2}, and reduced emissions of SO{sub 2}, the primary contributor to acid rain. The paper also addresses the environmental impacts of supplying a range of specific biomass resources, including forest-based resources, numerous types of biomass residues and energy crops. Some of the benefits offered by the various biomass supplies include support for improved forest management, improved waste management, reduced air emissions (by eliminating the need for open-field burning of residues) and reduced soil erosion (for example, where perennial energy crops are planted on degraded or deforested land). The environmental impacts of a range of biomass conversion technologies are also addressed, including those from the thermochemical processing of biomass (including direct combustion in residential wood stoves and industrial-scale boilers, gasification and pyrolysis); biochemical processing (anaerobic digestion and fermentation); and chemical processing (extraction of organic oils). In addition to reducing CO{sub 2} and SO{sub 2}, other environmental benefits of biomass conversion technologies include the distinctly lower toxicity of the ash compared to coal ash, reduced odours and pathogens from manure, reduced vehicle emissions of CO{sub 2}, with the use of ethanol fuel blends, and reduced particulate and hydrocarbon emissions where biodiesel is used as a substitute for diesel fuel. In general

Environmental impacts of biomass energy resource production and utilization

International Nuclear Information System (INIS)

Easterly, J.L.; Dunn, S.M.

1995-01-01

The purpose of this paper is to provide a broad overview of the environmental impacts associated with the production, conversion and utilization of biomass energy resources and compare them with the impacts of conventional fuels. The use of sustainable biomass resources can play an important role in helping developing nations meet their rapidly growing energy needs, while providing significant environmental advantages over the use of fossil fuels. Two of the most important environmental benefits biomass energy offers are reduced net emissions of greenhouse gases, particularly CO 2 , and reduced emissions of SO 2 , the primary contributor to acid rain. The paper also addresses the environmental impacts of supplying a range of specific biomass resources, including forest-based resources, numerous types of biomass residues and energy crops. Some of the benefits offered by the various biomass supplies include support for improved forest management, improved waste management, reduced air emissions (by eliminating the need for open-field burning of residues) and reduced soil erosion (for example, where perennial energy crops are planted on degraded or deforested land). The environmental impacts of a range of biomass conversion technologies are also addressed, including those from the thermochemical processing of biomass (including direct combustion in residential wood stoves and industrial-scale boilers, gasification and pyrolysis); biochemical processing (anaerobic digestion and fermentation); and chemical processing (extraction of organic oils). In addition to reducing CO 2 and SO 2 , other environmental benefits of biomass conversion technologies include the distinctly lower toxicity of the ash compared to coal ash, reduced odours and pathogens from manure, reduced vehicle emissions of CO 2 , with the use of ethanol fuel blends, and reduced particulate and hydrocarbon emissions where biodiesel is used as a substitute for diesel fuel. In general, the key elements for

The Mississippi University Research Consortium for the Utilization of Biomass: Production of Alternative Fuels from Waste Biomass Initiative

Energy Technology Data Exchange (ETDEWEB)

Drs. Mark E. Zapp; Todd French; Lewis Brown; Clifford George; Rafael Hernandez; Marvin Salin (from Mississippie State University); Drs. Huey-Min Hwang, Ken Lee, Yi Zhang; Maria Begonia (from Jackson State University); Drs. Clint Williford; Al Mikell (from the University of Mississippi); Drs. Robert Moore; Roger Hester (from the University of Southern Mississippi).

2009-03-31

The Mississippi Consortium for the Utilization of Biomass was formed via funding from the US Department of Energy's EPSCoR Program, which is administered by the Office of Basic Science. Funding was approved in July of 1999 and received by participating Mississippi institutions by 2000. The project was funded via two 3-year phases of operation (the second phase was awarded based on the high merits observed from the first 3-year phase), with funding ending in 2007. The mission of the Consortium was to promote the utilization of biomass, both cultured and waste derived, for the production of commodity and specialty chemicals. These scientific efforts, although generally basic in nature, are key to the development of future industries within the Southeastern United States. In this proposal, the majority of the efforts performed under the DOE EPSCoR funding were focused primarily toward the production of ethanol from lignocellulosic feedstocks and biogas from waste products. However, some of the individual projects within this program investigated the production of other products from biomass feeds (i.e. acetic acid and biogas) along with materials to facilitate the more efficient production of chemicals from biomass. Mississippi is a leading state in terms of raw biomass production. Its top industries are timber, poultry production, and row crop agriculture. However, for all of its vast amounts of biomass produced on an annual basis, only a small percentage of the biomass is actually industrially produced into products, with the bulk of the biomass being wasted. This situation is actually quite representative of many Southeastern US states. The research and development efforts performed attempted to further develop promising chemical production techniques that use Mississippi biomass feedstocks. The three processes that were the primary areas of interest for ethanol production were syngas fermentation, acid hydrolysis followed by hydrolyzate fermentation, and

FIA's volume-to-biomass conversion method (CRM) generally underestimates biomass in comparison to published equations

Science.gov (United States)

David. C. Chojnacky

2012-01-01

An update of the Jenkins et al. (2003) biomass estimation equations for North American tree species resulted in 35 generalized equations developed from published equations. These 35 equations, which predict aboveground biomass of individual species grouped according to a taxa classification (based on genus or family and sometimes specific gravity), generally predicted...

Lignin biomass conversion into chemicals and fuels

DEFF Research Database (Denmark)

Melián Rodríguez, Mayra

Second-generation biomass or lignocellulosic biomass, which is mainly composed of cellulose, hemicellulose and lignin, is a very important and promising feedstock for the renewable production of fuels and chemicals of the future. Lignin is the second most abundant natural polymer, representing 30...... and show similar, although simplified, characteristics to the natural biopolymer. Among them, the most abundant structural unit is the β-O-4, representing approximately 60% of the bonds in hardwood and 45-50% of those in softwood. Oxidative depolymerization is one of the most viable methods for lignin...... valorization. It involves the cleavage of ether bonds, such as β-O-4 and other linkages present in lignin and its model compounds, giving aldehydes or carboxylic acids as products, depending on the reaction conditions used. In Chapter 2 of this thesis, the preparation, characterization and catalytic...

Incentives and market development to establish sustainable biomass systems

International Nuclear Information System (INIS)

Matteson Gary, C.

2009-01-01

Business-as-usual is not acceptable when it comes to the future for biomass-to-energy/product conversion industry. Incentives and market development need to be applied to guide the owners and operators towards the sustainable practices. Sustainability for biomass is defined to be future energy fuels and bio products that are secure, renewable, and accessible locally, affordable, and pollution free. Intensives are required to convert biomass-to-energy/product conversion systems that are not sustainable into sustainable formats. (Author)

Catalytic Conversion of Carbohydrates

DEFF Research Database (Denmark)

Osmundsen, Christian Mårup

a renewable route to aromatics. The conversion of biomass by high temperature processes is a desirable prospect due to the high volumetric production rates which can be achieved, and the ability of these types of processes to convert a wide range of substrates. Current processes however typically have rather...... with the production of commodity chemicals from the most abundantly available renewable source of carbon, carbohydrates. The production of alkyl lactates by the Lewis acid catalyzed conversion of hexoses is an interesting alternative to current fermentation based processes. A range of stannosilicates were...... to be an efficient initial conversion step in the utilization of biomass for chemicals production. The shift from an oil based chemical industry to one based on renewable resources is bound to happen sooner or later, however the environmental problems associated with the burning of fossil resources means...

Biomass Program 2007 Accomplishments - Full Report

Energy Technology Data Exchange (ETDEWEB)

none,

2009-10-27

The Office of Energy Efficiency and Renewable Energy's (EERE’s) Biomass Program works with industry, academia and its national laboratory partners on a balanced portfolio of research in biomass feedstocks and conversion technologies. This document provides Program accomplishments for 2007.

Entrained Flow Gasification of Biomass

DEFF Research Database (Denmark)

Qin, Ke

The present Ph. D. thesis describes experimental and modeling investigations on entrained flow gasification of biomass and an experimental investigation on entrained flow cogasification of biomass and coal. A review of the current knowledge of biomass entrained flow gasification is presented....... Biomass gasification experiments were performed in a laboratory-scale atmospheric pressure entrained flow reactor with the aim to investigate the effects of operating parameters and biomass types on syngas products. A wide range of operating parameters was involved: reactor temperature, steam/carbon ratio......, excess air ratio, oxygen concentration, feeder gas flow, and residence time. Wood, straw, and lignin were used as biomass fuels. In general, the carbon conversion was higher than 90 % in the biomass gasification experiments conducted at high temperatures (> 1200 °C). The biomass carbon...

Environmental and institutional considerations in the development and implementation of biomass energy technologies

Energy Technology Data Exchange (ETDEWEB)

Schwab, C.

1979-09-01

The photosynthetic energy stored in plant and organic waste materials in the United States amounts to approximately 40% of the nation's total energy consumption. Conversion of this energy to usable power sources is a complex process, involving many possible materials, conversion technologies, and energy products. Near-term biomass technologies are predominantly based on traditional fuel use and have the advantage over other solar technologies of fitting into existing tax and business practices. However, no other solar technology has the potential for such large environmental impacts. Unlike the conversion of sun, wind, and ocean thermal energy, the conversion of the biomass energy source, in the form of biomass residues and wastes, can create problems. Environmental impacts may be significant, and legal responses to these impacts are a key determinant to the widespread adoption of biomass technologies. This paper focuses on the major legal areas which will impact on biomass energy conversion. These include (1) the effect of existing state and federal legislation, (2) the role of regulatory agencies in the development of biomass energy, (3) governmental incentives to biomass development, and (4) legal issues surrounding the functioning of the technologies themselves. Emphasis is placed on the near-term technologies whose environmental impacts and institutional limitations are more readily identified. If biomass energy is to begin to achieve its apparently great potential, these questions must receive immediate attention.

Biomass based energy. A review on raw materials and processing methods; Energie aus Biomasse. Eine Uebersicht ueber Rohstoffe und Verfahren

Energy Technology Data Exchange (ETDEWEB)

Woellauer, P

2007-07-01

The book reviews the variety of biogenic raw materials and the technologically important biomass conversion techniques. The chapter on the different kinds of biomass includes a) wood from forestry, landscape culturing and saw mills, bark and old wood; b) plants (corn, miscanthus, cannabis, wheat, rye, sugar beets, grass, rape, etc.), residuals and wastes (straw, liquid manure, slaughthouse wastes, kitchen wastes, sewage sludge, others). The chapter on biomass conversion processing discusses combustion, oxidation in spercritical water, gasification and reforming, fermentation, extrusion or extraction, and downstream processes. The chapter on biomass based electricity and mechanical energy includes refrigeration engineering, direct utilization: Otto engines, Diesel engines, microgas turbine fuel cells, and heat processing: Striling engine, vapour turbine, ORC turbine, externally fired gas turbine, and the Kalina process.

Global biomass burning: Atmospheric, climatic, and biospheric implications

International Nuclear Information System (INIS)

Levine, J.S.

1991-01-01

As a significant source of atmospheric gases, biomass burning must be addressed as a major environmental problem. Biomass burning includes burning forests and savanna grasslands for land clearing and conversion, burning agricultural stubble and waste after harvesting, and burning biomass fuels. The editor discusses the history of biomass burning and provides an overview of the individual chapters

Feasibility study of a biomass-fired cogeneration plant Groningen, Netherlands

International Nuclear Information System (INIS)

Rijk, P.J.; Van Loo, S.; Webb, R.

1996-06-01

The feasibility of the title plant is determined for district heating and electricity supply of more than 1,000 houses in Groningen, Netherlands. Also attention is paid to the feasibility of such installations in a planned area of the city. Prices and supply of several biomass resources are dealt with: prunings of parks, public and private gardens, clean wood wastes, wood wastes from forests, wood from newly planted forests, specific energy crops (willows in high densities and short cycles). Prices are calculated, including transport to the gate of the premises where the cogeneration installations is situated. For the conversion attention is paid to both the feasibility of the use of a conventional cogeneration installation (by means of a steam turbine) and the use of a new conversion technique: combined cycle of a gasification installation and a cogeneration installation. 5 figs., 5 ills., 22 tabs., 1 appendix, 33 refs

Techno-economic analysis of a biomass depot

Energy Technology Data Exchange (ETDEWEB)

Jacobson, Jacob Jordan [Idaho National Lab. (INL), Idaho Falls, ID (United States); Lamers, Patrick [Idaho National Lab. (INL), Idaho Falls, ID (United States); Roni, Mohammad Sadekuzzaman [Idaho National Lab. (INL), Idaho Falls, ID (United States); Cafferty, Kara Grace [Idaho National Lab. (INL), Idaho Falls, ID (United States); Kenney, Kevin Louis [Idaho National Lab. (INL), Idaho Falls, ID (United States); Heath, Brendi May [Idaho National Lab. (INL), Idaho Falls, ID (United States); Hansen, Jason K [Idaho National Lab. (INL), Idaho Falls, ID (United States)

2014-10-01

The U.S. Department of Energy (DOE) Bioenergy Technologies Office (BETO) promotes the production of an array of liquid fuels and fuel blendstocks from lignocellulosic biomass feedstocks by funding fundamental and applied research that advances the state of technology in biomass collection, conversion, and sustainability. As part of its involvement in this program, the Idaho National Laboratory (INL) investigates the technical, economic, and environmental performance of different feedstock supply systems and their impacts on the downstream conversion processes.

Biomass decomposition in near critical water

International Nuclear Information System (INIS)

Sinag, Ali; Guelbay, Selen; Uskan, Burcin; Canel, Muammer

2010-01-01

Conversion of baby food (taken as model biomass for protein and carbohydrate containing biomass) to the valuable chemicals in near critical water (648 K and 24 MPa) in an autoclave is presented in this work. K 2 CO 3 , Nickel on silica and Zeolith (HZSM-5) are selected as catalysts. A detailed characterization of the aqueous phases is performed by High Pressure Liquid Chromatography, UV-Vis Spectroscopy, Total Organic Carbon Analyser. Solid particles recovered by the experiments are also subjected to Scanning Electron Microscopy analysis. This study determines the effect of reaction conditions on the reactivity of the major biomass component. Acetic, formic and glycolic acid, aldehydes (acetaldehyde, formaldehyde), phenol and phenol derivatives, furfural, methyl furfural, hydroxymethyl furfural are the intermediates found in the aqueous phase. Baby food contains mostly carbohydrates, proteins, a variety of salts and minerals, etc. Thus, the results show the effect of these ingredients on the hydrothermal conversion of biomass. It is found that the formation and degradation pathways of the intermediates are influenced by the biomass structure.

Biomass decomposition in near critical water

Energy Technology Data Exchange (ETDEWEB)

Sinag, Ali, E-mail: sinag@science.ankara.edu.t [Department of Chemistry, Science Faculty, Ankara University, 06100 Besevler, Ankara (Turkey); Guelbay, Selen; Uskan, Burcin; Canel, Muammer [Department of Chemistry, Science Faculty, Ankara University, 06100 Besevler, Ankara (Turkey)

2010-03-15

Conversion of baby food (taken as model biomass for protein and carbohydrate containing biomass) to the valuable chemicals in near critical water (648 K and 24 MPa) in an autoclave is presented in this work. K{sub 2}CO{sub 3}, Nickel on silica and Zeolith (HZSM-5) are selected as catalysts. A detailed characterization of the aqueous phases is performed by High Pressure Liquid Chromatography, UV-Vis Spectroscopy, Total Organic Carbon Analyser. Solid particles recovered by the experiments are also subjected to Scanning Electron Microscopy analysis. This study determines the effect of reaction conditions on the reactivity of the major biomass component. Acetic, formic and glycolic acid, aldehydes (acetaldehyde, formaldehyde), phenol and phenol derivatives, furfural, methyl furfural, hydroxymethyl furfural are the intermediates found in the aqueous phase. Baby food contains mostly carbohydrates, proteins, a variety of salts and minerals, etc. Thus, the results show the effect of these ingredients on the hydrothermal conversion of biomass. It is found that the formation and degradation pathways of the intermediates are influenced by the biomass structure.

Catalytic conversion of nonfood woody biomass solids to organic liquids

NARCIS (Netherlands)

Barta, Katalin; Ford, Peter C

CONSPECTUS: This Account outlines recent efforts in our laboratories addressing a fundamental challenge of sustainability chemistry, the effective utilization of biomass for production of chemicals and fuels. Efficient methods for converting renewable biomass solids to chemicals and liquid fuels

Indirect Liquefaction of Biomass to Transportation Fuels Via Mixed Oxygenated Intermediates

Energy Technology Data Exchange (ETDEWEB)

Tan, Eric C.D.

2016-11-14

This paper presents a comparative techno-economic analysis of four emerging conversion pathways from biomass to gasoline-, jet-, and diesel-range hydrocarbons via indirect liquefaction with specific focus on pathways utilizing oxygenated intermediates. The processing steps include: biomass-to-syngas via indirect gasification, gas cleanup, conversion of syngas to alcohols/oxygenates followed by conversion of alcohols/oxygenates to hydrocarbon blendstocks via dehydration, oligomerization, and hydrogenation.

Indoor air pollution and the health of children in biomass- and fossil-fuel users of Bangladesh: situation in two different seasons.

Science.gov (United States)

Khalequzzaman, Md; Kamijima, Michihiro; Sakai, Kiyoshi; Hoque, Bilqis Amin; Nakajima, Tamie

2010-07-01

Indoor air pollution levels are reported to be higher with biomass fuel, and a number of respiratory diseases in children are associated with pollution from burning such fuel. However, little is known about the situation in developing countries. The aim of the study was to compare indoor air pollution levels and prevalence of symptoms in children between biomass- and fossil-fuel-using households in different seasons in Bangladesh. We conducted a cross-sectional study among biomass- (n = 42) and fossil-fuel (n = 66) users having children Moulvibazar and Dhaka, Bangladesh. Health-related information of one child from each family was retrieved once in winter (January 2008) and once in summer (June 2008). The measured pollutants were carbon monoxide (CO), carbon dioxide (CO(2)), dust particles, volatile organic compounds (VOCs), and nitrogen dioxide. Mean concentration of dust particles and geometric mean concentrations of VOCs such as benzene, toluene, and xylene, which were significantly higher in biomass- than fossil-fuel-users' kitchens (p < 0.05), were significantly higher in winter than in summer (p < 0.05). Levels of CO and CO(2), which were significantly higher in biomass than fossil-fuel users (p < 0.05), were significantly higher in summer than winter (p < 0.05). However, no significant difference was found in the occurrence of symptoms between biomass- and fossil-fuel users either in winter or in summer. It was suggested that the measured indoor air pollution did not directly result in symptoms among children. Other factors may be involved.

Development of High Yield Feedstocks and Biomass Conversion Technology for Renewable Energy

Energy Technology Data Exchange (ETDEWEB)

Hashimoto, Andrew G. [Univ. of Hawaii, Honolulu, HI (United States); Crow, Susan [Univ. of Hawaii, Honolulu, HI (United States); DeBeryshe, Barbara [Univ. of Hawaii, Honolulu, HI (United States); Ha, Richard [Hamakua Springs County Farms, Hilo, HI (United States); Jakeway, Lee [Hawaiian Commercial and Sugar Company, Puunene, HI (United States); Khanal, Samir [Univ. of Hawaii, Honolulu, HI (United States); Nakahata, Mae [Hawaiian Commercial and Sugar Company, Puunene, HI (United States); Ogoshi, Richard [Univ. of Hawaii, Honolulu, HI (United States); Shimizu, Erik [Univ. of Hawaii, Honolulu, HI (United States); Stern, Ivette [Univ. of Hawaii, Honolulu, HI (United States); Turano, Brian [Univ. of Hawaii, Honolulu, HI (United States); Turn, Scott [Univ. of Hawaii, Honolulu, HI (United States); Yanagida, John [Univ. of Hawaii, Honolulu, HI (United States)

2015-04-09

This project had two main goals. The first goal was to evaluate several high yielding tropical perennial grasses as feedstock for biofuel production, and to characterize the feedstock for compatible biofuel production systems. The second goal was to assess the integration of renewable energy systems for Hawaii. The project focused on high-yield grasses (napiergrass, energycane, sweet sorghum, and sugarcane). Field plots were established to evaluate the effects of elevation (30, 300 and 900 meters above sea level) and irrigation (50%, 75% and 100% of sugarcane plantation practice) on energy crop yields and input. The test plots were extensive monitored including: hydrologic studies to measure crop water use and losses through seepage and evapotranspiration; changes in soil carbon stock; greenhouse gas flux (CO₂, CH₄, and N₂O) from the soil surface; and root morphology, biomass, and turnover. Results showed significant effects of environment on crop yields. In general, crop yields decrease as the elevation increased, being more pronounced for sweet sorghum and energycane than napiergrass. Also energy crop yields were higher with increased irrigation levels, being most pronounced with energycane and less so with sweet sorghum. Daylight length greatly affected sweet sorghum growth and yields. One of the energy crops (napiergrass) was harvested at different ages (2, 4, 6, and 8 months) to assess the changes in feedstock characteristics with age and potential to generate co-products. Although there was greater potential for co-products from younger feedstock, the increased production was not sufficient to offset the additional cost of harvesting multiple times per year. The feedstocks were also characterized to assess their compatibility with biochemical and thermochemical conversion processes. The project objectives are being continued through additional support from the Office of Naval Research, and the Biomass Research and Development

Biomass pyrolysis liquid to citric acid via 2-step bioconversion.

Science.gov (United States)

Yang, Zhiguang; Bai, Zhihui; Sun, Hongyan; Yu, Zhisheng; Li, Xingxing; Guo, Yifei; Zhang, Hongxun

2014-12-31

The use of fossil carbon sources for fuels and petrochemicals has serious impacts on our environment and is unable to meet the demand in the future. A promising and sustainable alternative is to substitute fossil carbon sources with microbial cell factories converting lignocellulosic biomass into desirable value added products. However, such bioprocesses require tolerance to inhibitory compounds generated during pretreatment of biomass. In this study, the process of sequential two-step bio-conversion of biomass pyrolysis liquid containing levoglucosan (LG) to citric acid without chemical detoxification has been explored, which can greatly improve the utilization efficiency of lignocellulosic biomass. The sequential two-step bio-conversion of corn stover pyrolysis liquid to citric acid has been established. The first step conversion by Phanerochaete chrysosporium (P. chrysosporium) is desirable to decrease the content of other compounds except levoglucosan as a pretreatment for the second conversion. The remaining levoglucosan in solution was further converted into citric acid by Aspergillus niger (A. niger) CBX-209. Thus the conversion of cellulose to citric acid is completed by both pyrolysis and bio-conversion technology. Under experimental conditions, levoglucosan yield is 12% based on the feedstock and the citric acid yield can reach 82.1% based on the levoglucosan content in the pyrolysis liquid (namely 82.1 g of citric acid per 100 g of levoglucosan). The study shows that P. chrysosporium and A. niger have the potential to be used as production platforms for value-added products from pyrolyzed lignocellulosic biomass. Selected P. chrysosporium is able to decrease the content of other compounds except levoglucosan and levoglucosan can be further converted into citric acid in the residual liquids by A. niger. Thus the conversion of cellulose to citric acid is completed by both pyrolysis and bio-conversion technology.

Situated Transgressiveness

DEFF Research Database (Denmark)

Muhr, Sara Louise; Sullivan, Katie Rose; Rich, Craig

2016-01-01

conversations within queer theory, transgender and organization studies by highlighting how situated contexts mediate the political potential of queer bodies at work. By developing the concept ‘situated transgressiveness’, this article challenges notions of transgender as a stable, ideal disruptive category......This study investigates the lived experience of one transwoman, Claire, a public advocate and a manager with client services responsibilities. We examine Claire's story in order to discuss how situated contexts, such as different roles, locales and interactions, shape the way she experiences...

Special involuntary conversion situations involving timberland

Science.gov (United States)

William C. Siegal

2001-01-01

If standing timber is destroyed or stolen, or if forest land is condemned for public use, the owner may be entitled to take a deduction on his or her income tax return. These types of losses are called involuntary conversions. In previous National Woodlands articles I've discussed in detail casualty losses, which represent the major type of timber involuntary...

Biomass Program 2007 Accomplishments - Report Introduction

Energy Technology Data Exchange (ETDEWEB)

none,

2009-10-27

The Office of Energy Efficiency and Renewable Energy's (EERE’s) Biomass Program works with industry, academia and its national laboratory partners on a balanced portfolio of research in biomass feedstocks and conversion technologies. This document provides the introduction to the 2007 Program Accomplishments Report.

Biomass electrochemistry : from cellulose to sorbitol

NARCIS (Netherlands)

Kwon, Youngkook

2013-01-01

The primary goal of this thesis is to study the potential role of electrochemistry in finding new routes for sustainable chemicals from biomass in aqueous-phase solutions. In order to assess the potential of electrochemistry in biomass conversion, we developed an online HPLC system by using a

Homogeneous catalysis for the conversion of biomass and biomass-derived platform chemicals

NARCIS (Netherlands)

Deuss, Peter J.; Barta, Katalin; de Vries, Johannes G.

2014-01-01

The transition from a petroleum-based infrastructure to an industry which utilises renewable resources is one of the key research challenges of the coming years. Biomass, consisting of inedible plant material that does not compete with our food production, is a suitable renewable feedstock. In

EERC Center for Biomass Utilization 2006

Energy Technology Data Exchange (ETDEWEB)

Zygarlicke, Christopher J. [Univ. of North Dakota, Grand Forks, ND (United States). Energy and Environmental Research Center; Hurley, John P. [Univ. of North Dakota, Grand Forks, ND (United States). Energy and Environmental Research Center; Aulich, Ted R. [Univ. of North Dakota, Grand Forks, ND (United States). Energy and Environmental Research Center; Folkedahl, Bruce C. [Univ. of North Dakota, Grand Forks, ND (United States). Energy and Environmental Research Center; Strege, Joshua R. [Univ. of North Dakota, Grand Forks, ND (United States). Energy and Environmental Research Center; Patel, Nikhil [Univ. of North Dakota, Grand Forks, ND (United States). Energy and Environmental Research Center; Shockey, Richard E. [Univ. of North Dakota, Grand Forks, ND (United States). Energy and Environmental Research Center

2009-05-27

The Center for Biomass Utilization® 2006 project at the Energy & Environmental Research Center (EERC) consisted of three tasks related to applied fundamental research focused on converting biomass feedstocks to energy, liquid transportation fuels, and chemicals. Task 1, entitled Thermochemical Conversion of Biomass to Syngas and Chemical Feedstocks, involved three activities. Task 2, entitled Crop Oil Biorefinery Process Development, involved four activities. Task 3, entitled Management, Education, and Outreach, focused on overall project management and providing educational outreach related to biomass technologies through workshops and conferences.

Hydrogen production from biomass by thermochemical recuperative energy conversion

Energy Technology Data Exchange (ETDEWEB)

Fushimi, C.; Araki, K.; Yamaguchi, Y.; Tsutsumi, A. [Tokyo Univ. (Japan). Dept. of Chemical System Engineering

2002-07-01

The authors conducted, using a thermogravimetric reactor, a kinetic study of production of thermochemical recuperative hydrogen from biomass. The four different biomass materials used were: cellulose, lignin, metroxylon stem, and coconut husk. Under both rapid heating and slow heating conditions, the weight changes of the biomass samples during the steam gasification or pyrolysis were measured at 973 Kelvin. Simultaneously, measurements of the evolution rates of low-molecular-weight gas products such as hydrogen, methane, carbon monoxide, and carbon dioxide were taken with the help of a mass spectrometer and a micro gas chromatograph (GC). The steam gasification of char significantly increased the amount of hydrogen and carbon dioxide production. The results also indicated that at higher heating rate, the cold gas efficiency of steam gasification was increased. This can be explained by the suppression of the tar production at lower temperature. 25 refs., 2 tabs., 10 figs.

Utilization of biomass in the U.S. for the production of ethanol fuel as a gasoline replacement. I - Terrestrial resource potential. II - Energy requirements, with emphasis on lignocellulosic conversion

Science.gov (United States)

Ferchak, J. D.; Pye, E. K.

The paper assesses the biomass resource represented by starch derived from feed corn, surplus and distressed grain, and high-yield sugar crops planted on set-aside land in the U.S. It is determined that the quantity of ethanol produced may be sufficient to replace between 5 to 27% of present gasoline requirements. Utilization of novel cellulose conversion technology may in addition provide fermentable sugars from municipal, agricultural and forest wastes, and ultimately from highly productive silvicultural operations. The potential additional yield of ethanol from lignocellulosic biomass appears to be well in excess of liquid fuel requirements of an enhanced-efficiency transport sector at present mileage demands. No conflict with food production would be entailed. A net-energy assessment is made for lignocellulosic biomass feedstocks' conversion to ethanol and an almost 10:1 energy yield/energy cost ratio determined. It is also found that novel cellulose pretreatment and enzymatic conversion methods still under development may significantly improve even that figure, and that both chemical-feedstocks and energy-yielding byproducts such as carbon dioxide, biogas and lignin make ethanol production potentially energy self-sufficient. A final high-efficiency production approach incorporates site-optimized, nonpolluting energy sources such as solar and geothermal.

The Role of Conversation Policy in Carrying Out Agent Conversations

International Nuclear Information System (INIS)

Link, Hamilton E.; Phillips, Laurence R.

1999-01-01

Structured conversation diagrams, or conversation specifications, allow agents to have predictable interactions and achieve predefined information-based goals, but they lack the flexibility needed to function robustly in an unpredictable environment. We propose a mechanism that combines a typical conversation structure with a separately established policy to generate an actual conversation. The word ''policy'' connotes a high-level direction external to a specific planned interaction with the environment. Policies, which describe acceptable procedures and influence decisions, can be applied to broad sets of activity. Based on their observation of issues related to a policy, agents may dynamically adjust their communication patterns. The policy object describes limitations, constraints, and requirements that may affect the conversation in certain circumstances. Using this new mechanism of interaction simplifies the description of individual conversations and allows domain-specific issues to be brought to bear more easily during agent communication. By following the behavior of the conversation specification when possible and deferring to the policy to derive behavior in exceptional circumstances, an agent is able to function predictably under normal situations and still act rationally in abnormal situations. Different conversation policies applied to a given conversation specification can change the nature of the interaction without changing the specification

Biomass: An overview in the United States of America

Energy Technology Data Exchange (ETDEWEB)

Robertson, T. [USDA Soil Conservation Service, Washington, DC (United States); Shapouri, H.

1993-12-31

Concerns about the heavy reliance on foreign sources of fossil fuels, environmental impacts of burning fossil fuels, environmental impacts of agricultural activities, the need to find sustainable renewable sources of energy, and the need for a sustainable agricultural resource base have been driving forces for the development of biomass as a source of energy. The development of biomass conversion technologies, of high-yielding herbaceous and short-rotation woody biomass crops, of high-yielding food, feed, and fiber crops, and of livestock with higher levels of feed conversion efficiencies has made the transition from total reliance on fossil fuels to utilization of renewable sources of energy from biomass a reality. A variety of biomass conversion technologies have been developed and tested. Public utilities, private power companies, and the paper industry are interested in applying this technology. Direct burning of biomass and/or cofiring in existing facilities will reduce emissions of greenhouse and other undesirable gases. Legislation has been passed to promote biomass production and utilization for liquid fuels and electricity. Land is available. The production of short-rotation woody crops and perennial grasses provides alternatives to commodity crops to stabilize income in the agricultural sector. The production of biomass crops can also reduce soil erosion, sediment loadings to surface water, and agricultural chemical loadings to ground and surface water; provide wildlife habitat; increase income and employment opportunities in rural areas; and provide a more sustainable agricultural resource base.

Biomass in Switzerland. Energy production

International Nuclear Information System (INIS)

Guggisberg, B.

2006-01-01

In the long term, biomass could be used for energy production in a three times more intensive way, compared to current figures. A major contribution would be delivered to Switzerland's energy supply. Numerous biomass conversion technologies do exist, for the production of heat, power or vehicle fuel. However, the implementation of such a large-scale utilisation of biomass requires a couple of strategic decisions in order to improve the framework conditions for biomass development and precisely target the supporting measures applicable to both research and pilot plants. In short, a clear and efficient strategy is necessary in what regards biomass, that will be used for the definition of a future catalogue of measures. (author)

Process Design and Economics for Biochemical Conversion of Lignocellulosic Biomass to Ethanol: Dilute-Acid Pretreatment and Enzymatic Hydrolysis of Corn Stover

Energy Technology Data Exchange (ETDEWEB)

Humbird, D.; Davis, R.; Tao, L.; Kinchin, C.; Hsu, D.; Aden, A.; Schoen, P.; Lukas, J.; Olthof, B.; Worley, M.; Sexton, D.; Dudgeon, D.

2011-03-01

This report describes one potential biochemical ethanol conversion process, conceptually based upon core conversion and process integration research at NREL. The overarching process design converts corn stover to ethanol by dilute-acid pretreatment, enzymatic saccharification, and co-fermentation. Building on design reports published in 2002 and 1999, NREL, together with the subcontractor Harris Group Inc., performed a complete review of the process design and economic model for the biomass-to-ethanol process. This update reflects NREL's current vision of the biochemical ethanol process and includes the latest research in the conversion areas (pretreatment, conditioning, saccharification, and fermentation), optimizations in product recovery, and our latest understanding of the ethanol plant's back end (wastewater and utilities). The conceptual design presented here reports ethanol production economics as determined by 2012 conversion targets and 'nth-plant' project costs and financing. For the biorefinery described here, processing 2,205 dry ton/day at 76% theoretical ethanol yield (79 gal/dry ton), the ethanol selling price is $2.15/gal in 2007$.

Ionic Liquids in Biomass Processing

Science.gov (United States)

Tan, Suzie Su Yin; Macfarlane, Douglas R.

Ionic liquids have been studied for their special solvent properties in a wide range of processes, including reactions involving carbohydrates such as cellulose and glucose. Biomass is a widely available and renewable resource that is likely to become an economically viable source of starting materials for chemical and fuel production, especially with the price of petroleum set to increase as supplies are diminished. Biopolymers such as cellulose, hemicellulose and lignin may be converted to useful products, either by direct functionalisation of the polymers or depolymerisation to monomers, followed by microbial or chemical conversion to useful chemicals. Major barriers to the effective conversion of biomass currently include the high crystallinity of cellulose, high reactivity of carbohydrates and lignin, insolubility of cellulose in conventional solvents, as well as heterogeneity in the native lignocellulosic materials and in lignin itself. This combination of factors often results in highly heterogeneous depolymerisation products, which make efficient separation difficult. Thus the extraction, depolymerisation and conversion of biopolymers will require novel reaction systems in order to be both economically attractive and environmentally benign. The solubility of biopolymers in ionic liquids is a major advantage of their use, allowing homogeneous reaction conditions, and this has stimulated a growing research effort in this field. This review examines current research involving the use of ionic liquids in biomass reactions, with perspectives on how it relates to green chemistry, economic viability, and conventional biomass processes.

75 FR 6263 - Biomass Crop Assistance Program

Science.gov (United States)

2010-02-08

... guidelines followed for any harvesting, collecting, storing or transporting of such material from such... for the purposes of transport and delivery to eligible biomass conversion facilities. As specified in... or proposes to convert renewable biomass into heat, power, biobased products, advanced biodiesel, or...

Determination of saccharides and ethanol from biomass conversion using Raman spectroscopy: Effects of pretreatment and enzyme composition

Energy Technology Data Exchange (ETDEWEB)

Shih, Chien-Ju [Iowa State Univ., Ames, IA (United States)

2010-01-01

This dissertation focuses on the development of facile and rapid quantitative Raman spectroscopy measurements for the determination of conversion products in producing bioethanol from corn stover. Raman spectroscopy was chosen to determine glucose, xylose and ethanol in complex hydrolysis and fermentation matrices. Chapter 1 describes the motives and main goals of this work, and includes an introduction to biomass, commonly used pretreatment methods, hydrolysis and fermentation reactions. The principles of Raman spectroscopy, its advantages and applications related to biomass analysis are also illustrated. Chapter 2 and 3 comprise two published or submitted manuscripts, and the thesis concludes with an appendix. In Chapter 2, a Raman spectroscopic protocol is described to study the efficiency of enzymatic hydrolysis of cellulose by measuring the main product in hydrolysate, glucose. Two commonly utilized pretreatment methods were investigated in order to understand their effect on glucose measurements by Raman spectroscopy. Second, a similar method was set up to determine the concentration of ethanol in fermentation broth. Both of these measurements are challenged by the presence of complex matrices. In Chapter 3, a quantitative comparison of pretreatment protocols and the effect of enzyme composition are studied using systematic methods. A multipeak fitting algorithm was developed to analyze spectra of hydrolysate containing two analytes: glucose and xylose. Chapter 4 concludes with a future perspective of this research area. An appendix describes a convenient, rapid spectrophotometric method developed to measure cadmium in water. This method requires relatively low cost instrumentation and can be used in microgravity, such as space shuttles or the International Space Station. This work was performed under the supervision of Professor Marc Porter while at Iowa State University. Research related to producing biofuel from bio-renewable resources, especially

Energy from Dutch biomass. Energie uit Nederlandse biomassa

Energy Technology Data Exchange (ETDEWEB)

Van Doorn, J

1993-12-01

Attention is paid to the options and potential of using biomass wastes in the Netherlands for the production of energy. An overview of the flows of biomass residues is given, next to the biomass properties, and biomass conversion techniques. Data on the contribution of renewable energy sources (1990) and targets for the year 2010 are presented and briefly discussed. It is expected that the contribution of biomass will increase considerably in the next years in the form of cheap biomass residues. 1 fig., 4 tabs.

Process Design and Economics for the Conversion of Lignocellulosic Biomass to Hydrocarbon Fuels: Fast Pyrolysis and Hydrotreating Bio-oil Pathway

Energy Technology Data Exchange (ETDEWEB)

Jones, Susanne [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Meyer, Pimphan [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Snowden-Swan, Lesley [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Padmaperuma, Asanga [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Tan, Eric [National Renewable Energy Lab. (NREL), Golden, CO (United States); Dutta, Abhijit [National Renewable Energy Lab. (NREL), Golden, CO (United States); Jacobson, Jacob [Idaho National Lab. (INL), Idaho Falls, ID (United States); Cafferty, Kara [Idaho National Lab. (INL), Idaho Falls, ID (United States)

2013-11-01

This report describes a proposed thermochemical process for converting biomass into liquid transportation fuels via fast pyrolysis followed by hydroprocessing of the condensed pyrolysis oil. As such, the analysis does not reflect the current state of commercially-available technology but includes advancements that are likely, and targeted to be achieved by 2017. The purpose of this study is to quantify the economic impact of individual conversion targets to allow a focused effort towards achieving cost reductions.

Process Design and Economics for the Conversion of Lignocellulosic Biomass to Hydrocarbon Fuels: Fast Pyrolysis and Hydrotreating Bio-Oil Pathway

Energy Technology Data Exchange (ETDEWEB)

Jones, Susanne B. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Meyer, Pimphan A. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Snowden-Swan, Lesley J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Padmaperuma, Asanga B. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Tan, Eric [National Renewable Energy Lab. (NREL), Golden, CO (United States); Dutta, Abhijit [National Renewable Energy Lab. (NREL), Golden, CO (United States); Jacobson, Jacob [Idaho National Lab. (INL), Idaho Falls, ID (United States); Cafferty, Kara [Idaho National Lab. (INL), Idaho Falls, ID (United States)

2013-11-01

This report describes a proposed thermochemical process for converting biomass into liquid transportation fuels via fast pyrolysis followed by hydroprocessing of the condensed pyrolysis oil. As such, the analysis does not reflect the current state of commercially-available technology but includes advancements that are likely, and targeted to be achieved by 2017. The purpose of this study is to quantify the economic impact of individual conversion targets to allow a focused effort towards achieving cost reductions.

A techno-economic evaluation of a biomass energy conversion park

NARCIS (Netherlands)

Dael, Van M.; Passel, van S.; Pelkmans, L.; Guisson, R.; Reumermann, P.; Luzardo, N.M.; Witters, N.; Broeze, J.

2013-01-01

Biomass as a renewable energy source has many advantages and is therefore recognized as one of the main renewable energy sources to be deployed in order to attain the target of 20% renewable energy use of final energy consumption by 2020 in Europe. In this paper the concept of a biomass Energy

Biomass Program 2007 Program Peer Review - Thermochemical Conversion Platform Summary

Energy Technology Data Exchange (ETDEWEB)

none,

2009-10-27

This document discloses the comments provided by a review panel at the U.S. Department of Energy Office of the Biomass Program Peer Review held on November 15-16, 2007 in Baltimore, MD and the Biomass Program Peer Review for the Thermochemical Platform, held on July 9th and 10th in Golden, Colorado.

Gasification Characteristics of Coal/Biomass Mixed Fuels

Energy Technology Data Exchange (ETDEWEB)

Mitchell, Reginald [Stanford Univ., CA (United States). Mechanical Engineering Dept.

2014-09-01

A research project was undertaken that had the overall objective of developing the models needed to accurately predict conversion rates of coal/biomass mixtures to synthesis gas under conditions relevant to a commercially-available coal gasification system configured to co-produce electric power as well as chemicals and liquid fuels. In our efforts to accomplish this goal, experiments were performed in an entrained flow reactor in order to produce coal and biomass chars at high heating rates and temperatures, typical of the heating rates and temperatures fuel particles experience in real systems. Mixed chars derived from coal/biomass mixtures containing up to 50% biomass and the chars of the pure coal and biomass components were subjected to a matrix of reactivity tests in a pressurized thermogravimetric analyzer (TGA) in order to obtain data on mass loss rates as functions of gas temperature, pressure and composition as well as to obtain information on the variations in mass specific surface area during char conversion under kinetically-limited conditions. The experimental data were used as targets when determining the unknown parameters in the chemical reactivity and specific surface area models developed. These parameters included rate coefficients for the reactions in the reaction mechanism, enthalpies of formation and absolute entropies of adsorbed species formed on the carbonaceous surfaces, and pore structure coefficients in the model used to describe how the mass specific surface area of the char varies with conversion. So that the reactivity models can be used at high temperatures when mass transport processes impact char conversion rates, Thiele modulus – effectiveness factor relations were also derived for the reaction mechanisms developed. In addition, the reactivity model and a mode of conversion model were combined in a char-particle gasification model that includes the effects of chemical reaction and diffusion of reactive gases through particle

Overview of recent advances in thermo-chemical conversion of biomass

International Nuclear Information System (INIS)

Zhang Linghong; Xu Chunbao; Champagne, Pascale

2010-01-01

Energy from biomass, bioenergy, is a perspective source to replace fossil fuels in the future, as it is abundant, clean, and carbon dioxide neutral. Biomass can be combusted directly to generate heat and electricity, and by means of thermo-chemical and bio-chemical processes it can be converted into bio-fuels in the forms of solid (e.g., charcoal), liquid (e.g., bio-oils, methanol and ethanol), and gas (e.g., methane and hydrogen), which can be used further for heat and power generation. This paper provides an overview of the principles, reactions, and applications of four fundamental thermo-chemical processes (combustion, pyrolysis, gasification, and liquefaction) for bioenergy production, as well as recent developments in these technologies. Some advanced thermo-chemical processes, including co-firing/co-combustion of biomass with coal or natural gas, fast pyrolysis, plasma gasification and supercritical water gasification, are introduced. The advantages and disadvantages, potential for future applications and challenges of these processes are discussed. The co-firing of biomass and coal is the easiest and most economical approach for the generation of bioenergy on a large-sale. Fast pyrolysis has attracted attention as it is to date the only industrially available technology for the production of bio-oils. Plasma techniques, due to their high destruction and reduction efficiencies for any form of waste, have great application potential for hazardous waste treatment. Supercritical water gasification is a promising approach for hydrogen generation from biomass feedstocks, especially those with high moisture contents.

Advances in High Throughput Screening of Biomass Recalcitrance (Poster)

Energy Technology Data Exchange (ETDEWEB)

Turner, G. B.; Decker, S. R.; Tucker, M. P.; Law, C.; Doeppke, C.; Sykes, R. W.; Davis, M. F.; Ziebell, A.

2012-06-01

This was a poster displayed at the Symposium. Advances on previous high throughput screening of biomass recalcitrance methods have resulted in improved conversion and replicate precision. Changes in plate reactor metallurgy, improved preparation of control biomass, species-specific pretreatment conditions, and enzymatic hydrolysis parameters have reduced overall coefficients of variation to an average of 6% for sample replicates. These method changes have improved plate-to-plate variation of control biomass recalcitrance and improved confidence in sugar release differences between samples. With smaller errors plant researchers can have a higher degree of assurance more low recalcitrance candidates can be identified. Significant changes in plate reactor, control biomass preparation, pretreatment conditions and enzyme have significantly reduced sample and control replicate variability. Reactor plate metallurgy significantly impacts sugar release aluminum leaching into reaction during pretreatment degrades sugars and inhibits enzyme activity. Removal of starch and extractives significantly decreases control biomass variability. New enzyme formulations give more consistent and higher conversion levels, however required re-optimization for switchgrass. Pretreatment time and temperature (severity) should be adjusted to specific biomass types i.e. woody vs. herbaceous. Desalting of enzyme preps to remove low molecular weight stabilizers and improved conversion levels likely due to water activity impacts on enzyme structure and substrate interactions not attempted here due to need to continually desalt and validate precise enzyme concentration and activity.

Enhancing Cellulase Commercial Performance for the Lignocellulosic Biomass Industry

Energy Technology Data Exchange (ETDEWEB)

Jarnigan, Alisha [Danisco, US Inc., Copenhagen (Denmark)

2016-06-07

Cellulase enzyme loading (Bt-G) for the economic conversion of lignocellulosic biomass to ethanol is on of the key challenges identified in the Biomass Program of DOE/EERE. The goal of Danisco’s project which ran from 2008 to 2012, was to address the technical challenge by creating more efficient enzyme that could be used at lower doses, thus reducing the enzymes’ cost contribution to the conversio process. We took the approach of protein engineering of cellulase enzymes to overcome the enzymati limitations in the system of cellulosic-hydrolyzing enzymes to improve performance in conversion o biomass, thereby creating a more effective enzyme mix.

Artificial Neural Networks for Thermochemical Conversion of Biomass

DEFF Research Database (Denmark)

Puig Arnavat, Maria; Bruno, Joan Carles

2015-01-01

Artificial neural networks (ANNs), extensively used in different fields, have been applied for modeling biomass gasification processes in fluidized bed reactors. Two ANN models are presented, one for circulating fluidized bed gasifiers and another for bubbling fluidized bed gasifiers. Both models...

Systems Based Approaches for Thermochemical Conversion of Biomass to Bioenergy and Bioproducts

Energy Technology Data Exchange (ETDEWEB)

Taylor, Steven [Auburn Univ., AL (United States)

2016-07-11

Auburn’s Center for Bioenergy and Bioproducts conducts research on production of synthesis gas for use in power generation and the production of liquid fuels. The overall goal of our gasification research is to identify optimal processes for producing clean syngas to use in production of fuels and chemicals from underutilized agricultural and forest biomass feedstocks. This project focused on construction and commissioning of a bubbling-bed fluidized-bed gasifier and subsequent shakedown of the gasification and gas cleanup system. The result of this project is a fully commissioned gasification laboratory that is conducting testing on agricultural and forest biomass. Initial tests on forest biomass have served as the foundation for follow-up studies on gasification under a more extensive range of temperatures, pressures, and oxidant conditions. The laboratory gasification system consists of a biomass storage tank capable of holding up to 6 tons of biomass; a biomass feeding system, with loss-in-weight metering system, capable of feeding biomass at pressures up to 650 psig; a bubbling-bed fluidized-bed gasification reactor capable of operating at pressures up to 650 psig and temperatures of 1500oF with biomass flowrates of 80 lb/hr and syngas production rates of 37 scfm; a warm-gas filtration system; fixed bed reactors for gas conditioning; and a final quench cooling system and activated carbon filtration system for gas conditioning prior to routing to Fischer-Tropsch reactors, or storage, or venting. This completed laboratory enables research to help develop economically feasible technologies for production of biomass-derived synthesis gases that will be used for clean, renewable power generation and for production of liquid transportation fuels. Moreover, this research program provides the infrastructure to educate the next generation of engineers and scientists needed to implement these technologies.

Raw materials evaluation and process development studies for conversion of biomass to sugars and ethanol

Energy Technology Data Exchange (ETDEWEB)

Wilke, C.R.; Yang, R.D.; Sciamanna, A.S.; Freitas, R.P.

1978-06-01

A range of cellulosic raw materials in the form of agricultural crop residue was analyzed for chemical composition and assessed for potential yields of sugars through chemical pretreatment and enzymatic hydrolysis of these materials. Corn stover was used as a representative raw material for a preliminary process design and economic assessment of the production of sugars and ethanol. With the process as presently developed, 23 gallons of ethanol can be obtained per ton of corn stover at a processing cost of about $1.80 per gallon exclusive of by-product credits. The analysis shows the cost of ethanol to be highly dependent upon (1) the cost of the biomass, (2) the extent of conversion to glucose, (3) enzyme recovery and production cost and (4) potential utilization of xylose. Significant cost reduction appears possible through further research in these directions.

Development of a catalytic system for gasification of wet biomass

Energy Technology Data Exchange (ETDEWEB)

Elliott, D.C.; Sealock, L.J.; Phelps, M.R.; Neuenschwander, G.G.; Hart, T.R. [Pacific Northwest Lab., Richland, WA (United States)

1993-12-31

A gasification system is under development at Pacific Northwest Laboratory that can be used with high-moisture biomass feedstocks. The system operates at 350{degrees}C and 205 atm using a liquid water phase as the processing medium. Since a pressurized system is used, the wet biomass can be fed as a slurry to the reactor without drying. Through the development of catalysts, a useful processing system has been produced. This paper includes assessment of processing test results of different catalysts. Reactor system results including batch, bench-scale continuous, and engineering-scale processing results are presented to demonstrate the applicability of this catalytic gasification system to biomass. The system has utility both for direct conversion of biomass to fuel gas or as a wastewater cleanup system for treatment of unconverted biomass from bioconversion processes. By the use of this system high conversions of biomass to fuel gas can be achieved. Medium-Btu is the primary product. Potential exists for recovery/recycle of some of the unreacted inorganic components from the biomass in the aqueous byproduct stream.

Technical and economic analysis of using biomass energy

Directory of Open Access Journals (Sweden)

Piaskowska-Silarska Małgorzata

2017-01-01

Full Text Available In the first part of the article were presented the technical possibilities of obtaining solid biomass, biogas, landfill gas, a biogas from wastewater treatment plants, bioethanol and biodiesel. Then processes was described, allowing use of energy from biomass. As first was discussed the incineration which includes drying and degassing of the wood materials, wood gas burning at 1200°C, post-combustion gas and heat transfer in the heat exchanger. Then had been described gasification, or thermochemical conversion process, occurring at high temperature. It is two-stage process. In the first chamber at deficiency of air and at relatively low temperatures (450–800°C, the fuel is being degasified, resulting in creating combustible gas and a mineral residue (charcoal. In the second stage, secondary combustion chamber and at a temperature of about 1000–1200°C and in the presence of excess of oxygen resultant gas is burned. A further process is pyrolysis. It consists of the steps of drying fuel to a moisture level below 10%, milling the biomass into very small particles, the pyrolysis reaction, separation of solid products, cooling and collecting bio-oil. Then discusses co-generation, which is combined production of heat and electricity. In this situation where the biomass contains too much water it can be used for energy purposes through biochemical processes. The alcoholic fermentation results in decomposition of carbohydrates taking place under anaerobic conditions, and the product is bioethanol. Another biochemical process used for the production of liquid biofuels is esterification of vegetable oils. Methane fermentation in turn causes a decomposition of macromolecular organic substances with limited oxygen available. As a result, we obtain alcohols, lower organic acids, methane, carbon dioxide and water. There was analysis of economic increasing of solid biomass energy, biogas and liquid biofuels in the following article.

Sustainable Development Strategies of Biomass Energy in Beijing

Science.gov (United States)

Zhang, H. Z.; Huang, B. R.

2017-10-01

The development of biomass energy industry can effectively improve the rural environment and alleviate the shortage of living energy in rural areas, especially in mountain areas. In order to make clear the current situation of biomass energy industry development in Beijing, this paper analyzed the status of biomass resources and biomass energy utilization and discussed the factors hindering the development of biomass energy industry in Beijing. Based on the analysis, suggestions for promoting sustainable development of Biomass Energy Industry in Beijing are put forward.

Environmental issues related to biomass: An overview

International Nuclear Information System (INIS)

Hughes, M.; Ranney, J.W.

1993-01-01

With public attention increasingly focused on environmentalism and climate change, there is enormous potential for the commercial use of biomass to accelerate. Renewable feedstocks such as biomass can provide more environmentally balanced sources of energy and other non-food products than fossil fuels. Biomass utilization is in a precarious position, however, with public attention increasingly focused on both its potential and the strength of the challenges it faces. The paper is divided into five sections. Section 2 briefly addresses economic environmental issues. The extent to which externalities are accounted for in the market price of fuels plays a significant role in determining both the ultimate size of biofuel markets and the extent of the environmental benefits of feedstock cultivation and conversion processes. Sections 3 through 4 catalogue the main hazards and benefits that are likely to arise in the large scale commercialization of biomass fuel and note where the major uncertainties lay. Environmental issues arise with the cultivation of each feedstock and with each step in the process of its conversion to fuel. Feedstocks are discussed in Section 3 in terms of three main groups; wastes, energy crops, and traditional agricultural crops. In Section 4, conversion processes are also divided into three groups, on the basis of the end energy carrier; gas, liquid, and solid and electricity. Section 5 is devoted to a conclusion and summary

Biomass programme: Overview of the 2006 Swiss research programme; Programm Biomasse. Ueberblicksbericht zum Forschungsprogramm 2006

Energy Technology Data Exchange (ETDEWEB)

Binggeli, D.; Guggisberg, B.

2007-07-01

This report for the Swiss Federal Office of Energy (SFOE) reviews work done within the framework of the Swiss biomass research programme in 2006. The programme concentrates on the efficient conversion of biomass into heat, electrical power and motor fuels. Projects concerned with the optimisation of processes are reported on, including low-particle-emission systems, control systems for bivalent heating installations, use of demanding biomass fuels, combined pellets and solar heating systems and the elimination of ammonia emissions. In the material flow area, measurement campaigns, organic pollutants in compost, the effects of fermented wastes in agriculture and methane losses in biogas conditioning are reported on. New conversion technologies are reviewed, including hydro-thermal gasification, plant-oil fuelled combined heat and power units, flameless burners and catalytic direct liquefaction. In the area of basics, studies and concepts, eco-balances and life-cycle analyses are reported on; the production of synthetic natural gas and the influence of combustion particles are discussed and decentralised power generation from solid biomass is reported on. National and international co-operation is reviewed. The report is concluded with a review of eight pilot and demonstration projects, a review of work to be done in 2007 and a list of research and demonstration projects.

Development of biomass energy lacks a clear direction

International Nuclear Information System (INIS)

1998-01-01

By the year 2020, 4.4% of total energy consumption in the Netherlands must be generated from biomass. That means that biomass will be the most important form of renewable energy for this country. But, with 20 years to go, there is still no generally accepted strategy for the technological and economical development of bio-energy. The most important questions are discussed: is biomass sustainable or not, is it better to burn biomass or to gasify, must one built large-scale or small-scale biomass conversion plants, should the Netherlands import or biomass or cultivate biomass themselves, should biomass wastes be incinerated or recycled, must the emission standard for SO2 be 40 or 200 mg, and, finally, is bio-energy economically feasible?

Application of Fischer–Tropsch Synthesis in Biomass to Liquid Conversion

OpenAIRE

Yongwu Lu; Fei Yu; Jin Hu

2012-01-01

Fischer–Tropsch synthesis is a set of catalytic processes that can be used to produce fuels and chemicals from synthesis gas (mixture of CO and H2), which can be derived from natural gas, coal, or biomass. Biomass to Liquid via Fischer–Tropsch (BTL-FT) synthesis is gaining increasing interests from academia and industry because of its ability to produce carbon neutral and environmentally friendly clean fuels; such kinds of fuels can help to meet the globally increasing energy demand and to me...

Structural evolution of biomass char and its effect on the gasification rate

International Nuclear Information System (INIS)

Fatehi, Hesameddin; Bai, Xue-Song

2017-01-01

Highlights: • A comprehensive model was developed to describe the evolution of biomass char structure. • An effectiveness factor was used to account for the intra-particle chemical and physical processes. • The effect of the structural evolution of the multi-pore structure on biomass char reactivity was analyzed. • The multi-pore model yields results in satisfactory agreement with experiments. - Abstract: The evolution of char porous structure can affect the conversion rate of the char by affecting the intra-particle transport, especially in the zone II conversion regime. A multi-pore model based on the capillary pore theory is developed to take into account different conversion rates for pores with different radii. The model is valid for biomass chars produced under relatively low heating rates, when the original beehive structure of the biomass is not destroyed during the pyrolysis stage. The contribution of different pores with different radius is taken into account using an effectiveness factor presented for each pore radius with respect to different reactions. As the char conversion proceeds, the pore enlargement increases the contribution of micro-pores; consequently the effective surface area will increase. The increase in the effective surface area leads to an increased reactivity of char during the entire conversion process. This model is used to analyze the steam gasification process of biomass char of centimeter sizes. The results from the present multi-pore model are in better agreement with experimental data than those from a corresponding single pore model. Since the multi-pore model accommodates the detailed intra-particle transport, it is a useful basis toward developing a more predictive model for biomass char gasification.

Regional biomass supply: three case studies in the Midwest, US

Energy Technology Data Exchange (ETDEWEB)

English, B.C.; Dillivan, K.D.; Ojo, M.A.; Alexander, R.R.; Graham, R.L. [Tennessee Univ., Knoxville, TN (United States)

1995-06-01

Increased interest in the development and utilization of alternative energy sources has generated research demonstrating that fuels developed from energy crops (biofuels) can be a viable substitute for fossil fuels. A national energy program dedicated to the advancement of fuel derived from lignocellulosic crops could have major impacts on conventional energy supplied in the United States. Sufficient biofuel demand would allow conversion of croplands, as well as some pasture and forest lands, into biomass producing lands and possibly return to production acres formerly idled. A shift from crop, pasture or forest production activities to biomass production would likely require changes in the levels of inputs, outputs, and costs associated with these activities, which would impact producers and ultimately consumers. The conversion of cropland or idled land to biomass production will also have impacts on the physical characteristics of the soil. Soil erosion levels, soil chemical composition, soil structure, and organic matter content are some of the many soil attributes which will be impacted as a result of conversion. Research is needed to estimate the impact conversion activities have on these variables.

Canada's forest biomass resources: deriving estimates from Canada's forest inventory

International Nuclear Information System (INIS)

Penner, M.; Power, K.; Muhairwe, C.; Tellier, R.; Wang, Y.

1997-01-01

A biomass inventory for Canada was undertaken to address the data needs of carbon budget modelers, specifically to provide estimates of above-ground tree components and of non-merchantable trees in Canadian forests. The objective was to produce a national method for converting volume estimates to biomass that was standardized, repeatable across the country, efficient and well documented. Different conversion methods were used for low productivity forests (productivity class 1) and higher productivity forests (productivity class 2). The conversion factors were computed by constructing hypothetical stands for each site, age, species and province combination, and estimating the merchantable volume and all the above-ground biomass components from suitable published equations. This report documents the procedures for deriving the national biomass inventory, and provides illustrative examples of the results. 46 refs., 9 tabs., 5 figs

Biotechnological conversion of waste cooking olive oil into lipid-rich biomass using Aspergillus and Penicillium strains.

Science.gov (United States)

Papanikolaou, S; Dimou, A; Fakas, S; Diamantopoulou, P; Philippoussis, A; Galiotou-Panayotou, M; Aggelis, G

2011-05-01

In this study, we have investigated the biochemical behaviour of Aspergillus sp. (five strains) and Penicillium expansum (one strain) fungi cultivated on waste cooking olive oil. The production of lipid-rich biomass was the main target of the work. In parallel, the biosynthesis of other extracellular metabolites (organic acids) and enzyme (lipase) and the substrate fatty acid specificity of the strains were studied. Carbon-limited cultures were performed on waste oil, added in the growth medium at 15g l(-1) , and high biomass quantities were produced (up to c.18g l(-1) , conversion yield of c. 1·0 g of dry biomass formed per g of fat consumed or higher). Cellular lipids were accumulated in notable quantities in almost all cultures. Aspergillus sp. ATHUM 3482 accumulated lipid up to 64·0% (w/w) in dry fungal mass. In parallel, extracellular lipase activity was quantified, and it was revealed to be strain and fermentation time dependent, with a maximum quantity of 645 U ml(-1) being obtained by Aspergillus niger NRRL 363. Storage lipid content significantly decreased at the stationary growth phase. Some differences in the fatty acid composition of both cellular and residual lipids when compared with the initial substrate fat used were observed; in various cases, cellular lipids more saturated and enriched with arachidic acid were produced. Aspergillus strains produced oxalic acid up to 5·0 g l(-1) . Aspergillus and Penicillium strains are able to convert waste cooking olive oil into high-added-value products.   Increasing fatty wastes amounts are annually produced. The current study provided an alternative way of biovalourization of these materials, by using them as substrates, to produce added-value compounds. © 2011 The Authors. Journal of Applied Microbiology © 2011 The Society for Applied Microbiology.

Macroalgae as a Biomass Feedstock: A Preliminary Analysis

Energy Technology Data Exchange (ETDEWEB)

Roesijadi, Guritno; Jones, Susanne B.; Snowden-Swan, Lesley J.; Zhu, Yunhua

2010-09-26

A thorough of macroalgae analysis as a biofuels feedstock is warranted due to the size of this biomass resource and the need to consider all potential sources of feedstock to meet current biomass production goals. Understanding how to harness this untapped biomass resource will require additional research and development. A detailed assessment of environmental resources, cultivation and harvesting technology, conversion to fuels, connectivity with existing energy supply chains, and the associated economic and life cycle analyses will facilitate evaluation of this potentially important biomass resource.

Conversion and utilisation of biomass from Swedish agriculture; Foeraedling och avsaettning av jordbruksbaserade biobraenslen

Energy Technology Data Exchange (ETDEWEB)

Boerjesson, Paal

2007-05-15

Biomass feedstock from agriculture can be refined and converted into several different energy carriers and utilised for different energy services, such as production of heat, electricity or transportation fuel. The feedstock may be residues and by-products, such as straw and manure, or energy crops cultivated under different conditions depending on variations in regional and local conditions. Similar variations exist in the regional and local conditions for the refining and utilisation of the bioenergy and its by-products. The overall aim of this report is to analyse and describe the technical and physical conditions of different agriculture-based bioenergy systems using the existing infrastructure and potential new systems expected to be developed in the future. To which extent this technical/physical potential will be utilised in the future depends mainly on economic conditions and financial considerations. These aspects are not included in this study. Furthermore, potential possibilities to utilise existing infrastructure within the forest industry are not included. The report starts with an analysis and description of the energy efficiency of different bioenergy systems, from the production of the biomass to the final use of the refined energy carrier, expressed as the amount of heat, electricity or transportation fuel produced per hectare and year. The possibilities to co-produce different energy carries in bio-refineries are also analysed. The next part of the report includes an analysis of the variation in the regional conditions for the conversion and utilisation of the different energy carriers, based on existing infrastructure, for instance, district heating systems, individual heating systems, combined heat and power production, utilisation of by-products as feed in animal production, utilisation of digestion residues as fertilisers, the supply of forest fuels, etc. The report also includes a discussion of the environmental impact of an increased

Molybdenum-containing acidic catalysts to convert cellulosic biomass to glycolic acid

KAUST Repository

Han, Yu

2014-09-30

Embodiments of the present invention include methods and compositions related to catabolic conversion of cellulosic biomass to glycolic acid using molybdenum-containing acidic catalysts. The invention includes the use of heteropoly and isopoly acids and salts as the molybdenum-containing multi-functional catalysts for biomass conversion. In embodiments of the invention, the reactions employ successive hydrolysis, retro-aldol fragmentation, and selective oxidation in a noble metal-free system.

Biomass energy: its important and future trends

International Nuclear Information System (INIS)

Rao, P.S.

1997-01-01

The development of photo-biological energy conversion systems has long-term implication from the energy, wood fibre and chemical points etc. Power generation through biomass combustion and gasification has proved to be very successful venture. The energy needs of the people in the remote, rural and even urban areas of the country can be met economically by the energy from the renewable source such as biomass. The biomass energy is full of opportunities, and future trends are emerging towards renewable energy

Critical success factors for biomass. Identification/specification of critical success factors in the development and market introduction of biomass conversion systems for the production of electricity and/or heat and/or gaseous/liquid secondary energy carriers

International Nuclear Information System (INIS)

Van Ree, R.; Dinkelbach, L.; Van Doorn, J.; Hemmes, K.; Gerlagh, T.; Groenendaal, B.

2000-06-01

The Dutch government has set the policy target that in 2020 10% of the total energy consumption has to be provided by means of renewable energy sources. Biomass is expected to play a major role (25-30%) in this future renewable energy based energy supply system. However, it is still unclear if this biomass-based target will be reached. Although studies showed that success or failure of innovations and projects depend on a multitude of scientific, technical, economic and societal variables, a number of questions still remained unanswered. This information often concentrated exclusively on the cost price aspects. This study is conducted to identify the internal and external barriers or constraints other than cost aspects, which are of vital importance to a successful penetration of biomass in the Dutch energy market. Barriers with a decreasing influence on the market introduction of bioenergy in the Netherlands are: short-term contractability of biomass (organic waste streams) for energy purposes, applicable emission and waste policies, and unfamiliarity of bioenergy by the public and government. Barriers that potentially could play an important role on the market introduction of bioenergy in the Netherlands in the near future are: long-term contractability of biomass (organic waste streams and energy crops) for energy purposes, the 'new' emission constraints and their potential negative influence on the implementation of small-scale biomass-based combined-cycle plants, the rivalry of bioenergy with other renewable energy based technologies in a liberalising energy market, the social acceptance of bioenergy, the future European agriculture policy (energy crops), and the current status and development perspectives of biomass-based energy conversion technologies. 66 refs

Carbon-Based Nanomaterials in Biomass-Based Fuel-Fed Fuel Cells

Directory of Open Access Journals (Sweden)

Le Quynh Hoa

2017-11-01

Full Text Available Environmental and sustainable economical concerns are generating a growing interest in biofuels predominantly produced from biomass. It would be ideal if an energy conversion device could directly extract energy from a sustainable energy resource such as biomass. Unfortunately, up to now, such a direct conversion device produces insufficient power to meet the demand of practical applications. To realize the future of biofuel-fed fuel cells as a green energy conversion device, efforts have been devoted to the development of carbon-based nanomaterials with tunable electronic and surface characteristics to act as efficient metal-free electrocatalysts and/or as supporting matrix for metal-based electrocatalysts. We present here a mini review on the recent advances in carbon-based catalysts for each type of biofuel-fed/biofuel cells that directly/indirectly extract energy from biomass resources, and discuss the challenges and perspectives in this developing field.

Energy from Biomass: technology assessment of small-medium scale biomass conversion systems

OpenAIRE

Cutz Ijchajchal, Luis Leonardo

2016-01-01

Mención Internacional en el título de doctor Bioenergy is a key resource to addressing challenges such as climate change (anthropogenic CO₂ emissions), pollution (suspended particles), energy security and human well-being. Currently, most of the biomass produced worldwide is consumed for cooking and space heating which has raised concerns among governments and policy-makers, especially due to threats to human health. The present thesis focuses on studying the technical and economic feasibi...

Solar Program Assessment: Environmental Factors - Fuels from Biomass.

Science.gov (United States)

Energy Research and Development Administration, Washington, DC. Div. of Solar Energy.

The purpose of this report is to present and prioritize the major environmental issues associated with the further development of biomass production and biomass conversion systems. To provide a background for this environmental analysis, the basic concepts of the technology are reviewed, as are resource requirements. The potential effects of this…

Economic analysis of biomass crop production in Florida

Energy Technology Data Exchange (ETDEWEB)

Rahmani, M.; Hodges, A.W.; Stricker, J.A.; Kiker, C.F. [University of Florida, Gainesville, FL (United States)

1997-07-01

Favorable soil and climate conditions for production of biomass crops in Florida, and a market for their use, provide the essentials for developing a biomass energy system in the State. Recent surveys showed that there is low opportunity cost land available and several high yield herbaceous and woody crops have potential as biomass crops. Comparison of biomass crop yields, farmgate costs, and costs of final products in Florida and other states show that Florida can be considered as one of the best areas for development of biomass energy systems in the United States. This paper presents facts and figures on biomass production and conversion in Florida and addresses issues of concern to the economics of biomass energy in the State. (author)

Economic analysis of biomass crop production in Florida

International Nuclear Information System (INIS)

Rahmani, M.; Hodges, A.W.; Stricker, J.A.; Kiker, C.F.

1997-01-01

Favorable soil and climate conditions for production of biomass crops in Florida, and a market for their use, provide the essentials for developing a biomass energy system in the State. Recent surveys showed that there is low opportunity cost land available and several high yield herbaceous and woody crops have potential as biomass crops. Comparison of biomass crop yields, farmgate costs, and costs of final products in Florida and other states show that Florida can be considered as one of the best areas for development of biomass energy systems in the United States. This paper presents facts and figures on biomass production and conversion in Florida and addresses issues of concern to the economics of biomass energy in the State. (author)

Catalytic biomass conversion methods, catalysts, and methods of making the same

Science.gov (United States)

Delgass, William Nicholas; Agrawal, Rakesh; Ribeiro, Fabio Henrique; Saha, Basudeb; Yohe, Sara Lynn; Abu-Omar, Mahdi M; Parsell, Trenton; Dietrich, Paul James; Klein, Ian Michael

2017-10-10

Described herein are processes for one-step delignification and hydrodeoxygenation of lignin fraction a biomass feedstock. The lignin feedstock is derived from by-products of paper production and biorefineries. Additionally described is a process for converting biomass-derived oxygenates to lower oxygen-content compounds and/or hydrocarbons in the liquid or vapor phase in a reactor system containing hydrogen and a catalyst comprised of a hydrogenation function and/or an oxophilic function and/or an acid function. Finally, also described herein is a process for converting biomass-derived oxygenates to lower oxygen-content compounds and/or hydrocarbons in the liquid or vapor phase in a reactor system containing hydrogen and a catalyst comprised of a hydrogenation function and/or an oxophilic function and/or an acid function.

The road from photon to biomass. Van foton tot biomassa

Energy Technology Data Exchange (ETDEWEB)

Schaafsma, T J [Landbouwuniversiteit Wageningen (Netherlands)

1989-10-01

The photosynthesis of biomass is outlined. Concentration of the lowpower density of sunlight by means of biomass production makes biomasscomparable to fossil fuels with respect to power density. Efficiency ofthe photosynthesis process and use of biomass conversion processestogether with their costs are discussed. Possible future utilization ofbiological solar cells is mentioned. 5 figs., 8 refs., 3 tabs.

The study of reactions influencing the biomass steam gasification process

Energy Technology Data Exchange (ETDEWEB)

C. Franco; F. Pinto; I. Gulyurtlu; I. Cabrita [INETI-DEECA, Lisbon (Portugal)

2003-05-01

Steam gasification studies were carried out in an atmospheric fluidised bed. The gasifier was operated over a temperature range of 700 900{sup o}C whilst varying a steam/biomass ratio from 0.4 to 0.85 w/w. Three types of forestry biomass were studied: Pinus pinaster (softwood), Eucalyptus globulus and holm-oak (hardwood). The energy conversion, gas composition, higher heating value and gas yields were determined and correlated with temperature, steam/biomass ratio, and species of biomass used. The results obtained seemed to suggest that the operating conditions were optimised for a gasification temperature around 830{sup o}C and a steam/biomass ratio of 0.6 0.7 w/w, because a gas richer in hydrogen and poorer in hydrocarbons and tars was produced. These conditions also favoured greater energy and carbon conversions, as well the gas yield. The main objective of the present work was to determine what reactions were dominant within the operation limits of experimental parameters studied and what was the effect of biomass type on the gasification process. As biomass wastes usually have a problem of availability because of seasonal variations, this work analysed the possibility of replacing one biomass species by another, without altering the gas quality obtained. 19 refs., 8 figs. 2 tabs.

Considerations in implementing integrated biomass energy systems in developing countries

International Nuclear Information System (INIS)

Perlack, R.D.; Ranney, J.W.

1993-01-01

Biomass energy is emerging as a real option for satisfying power needs in developing countries. Experience has shown improvements in GDP are directly linked to increased consumption of energy. Biomass energy can also be environmentally and developmentally beneficial where it will be both grown and used. Biomass production can offset deforestation, reduce soil erosion, increase rural employment, and stimulate development. Moreover, when biomass is grown renewably there is no net buildup of atmospheric carbon. Issues and barriers associated with implementing integrated biomass energy systems in developing countries are discussed. An integrated biomass energy system is dependent on sustainably grown and managed energy crops, supportive of rural development, and environmentally beneficial, adapted to local conditions; takes advantage of by- and co-products and uses conversion technologies that have been optimized for biomass. A preliminary evaluation of a biomass to electricity project relying on plantation grown feedstocks in Southwest China indicates that biomass could be grown and converted to electricity at costs lower than alternatives and yield an internal rate of return of about 15%. The IRR based on a social and environmental benefits are substantial and investment in the facility is well-justified. However, assessing biomass energy systems is exceedingly complex. Considerations are grouped into biomass production, biomass logistics and transport, and biomass conversion. Implementation requires considerations of energy and economics, institutional and social issues, and environmental issues. The conclusion that such a project would be viable in rural China is shadowed by many site-specific circumstances and highlights the need for systematic and integrated appraisal

Thermochemical Conversion of Woody Biomass to Fuels and Chemicals Final Report

Energy Technology Data Exchange (ETDEWEB)

Pendse, Hemant P. [Univ. of Maine, Orono, ME (United States)

2015-09-30

Maine and its industries identified more efficient utilization of biomass as a critical economic development issue. In Phase I of this implementation project, a research team was assembled, research equipment was implemented and expertise was demonstrated in pyrolysis, hydrodeoxygenation of pyrolysis oils, catalyst synthesis and characterization, and reaction engineering. Phase II built upon the infrastructure to innovate reaction pathways and process engineering, and integrate new approaches for fuels and chemical production within pulp and paper and other industries within the state. This research cluster brought together chemists, engineers, physicists and students from the University of Maine, Bates College, and Bowdoin College. The project developed collaborations with Oak Ridge National Laboratory and Brookhaven National Laboratory. The specific research projects within this proposal were of critical interest to the DoE - in particular the biomass program within EERE and the catalysis/chemical transformations program within BES. Scientific and Technical Merit highlights of this project included: (1) synthesis and physical characterization of novel size-selective catalyst/supports using engineered mesoporous (1-10 nm diameter pores) materials, (2) advances in fundamental knowledge of novel support/ metal catalyst systems tailored for pyrolysis oil upgrading, (3) a microcalorimetric sensing technique, (4) improved methods for pyrolysis oil characterization, (5) production and characterization of woody biomass-derived pyrolysis oils, (6) development of two new patented bio oil pathways: thermal deoxygenation (TDO) and formate assisted pyrolysis (FASP), and (7) technoeconomics of pyrolysis of Maine forest biomass. This research cluster has provided fundamental knowledge to enable and assess pathways to thermally convert biomass to hydrocarbon fuels and chemicals.

Chemicals from biomass - The U.S. prospects for the turn of the century

Science.gov (United States)

Sarbolouki, M. N.; Moacanin, J.

1980-01-01

Historically, chemicals from biomass have been and are expected to be economical in three major areas: byproducts, specialty items and polymers. Assessments of producing major chemicals from biomass in a processing plant based on the available conversion techniques indicate that they are not economically attractive, with the possible exception of conversion to ammonia and ethanol. The deterrents are the heavy capital investments, dependability of raw material supply and transportation costs for large plants, lack of operation experience, inadaptability of market variations, and competition from petroleum and coal. More importantly, it is also shown that even if chemicals from biomass were economical today, the resultant savings in petroleum would be far less than those achieved through other options available for the utilization of biomass as fuel and structural material. Thus, it is concluded that near-term research and development must be toward improved conversion processes, recovery of valuable products from waste streams at existing plants, more efficient use of biomass of energy and more efficient production of superior material products.

Improved lignocellulose conversion to biofuels with thermophilic bacteria and thermostable enzymes.

Science.gov (United States)

Bhalla, Aditya; Bansal, Namita; Kumar, Sudhir; Bischoff, Kenneth M; Sani, Rajesh K

2013-01-01

Second-generation feedstock, especially nonfood lignocellulosic biomass is a potential source for biofuel production. Cost-intensive physical, chemical, biological pretreatment operations and slow enzymatic hydrolysis make the overall process of lignocellulosic conversion into biofuels less economical than available fossil fuels. Lignocellulose conversions carried out at ≤ 50 °C have several limitations. Therefore, this review focuses on the importance of thermophilic bacteria and thermostable enzymes to overcome the limitations of existing lignocellulosic biomass conversion processes. The influence of high temperatures on various existing lignocellulose conversion processes and those that are under development, including separate hydrolysis and fermentation, simultaneous saccharification and fermentation, and extremophilic consolidated bioprocess are also discussed. Copyright © 2012 Elsevier Ltd. All rights reserved.

Reaction pathways of model compounds of biomass-derived oxygenates on Fe/Ni bimetallic surfaces

Science.gov (United States)

Yu, Weiting; Chen, Jingguang G.

2015-10-01

Controlling the activity and selectivity of converting biomass-derivatives to fuels and valuable chemicals is critical for the utilization of biomass feedstocks. There are primarily three classes of non-food competing biomass, cellulose, hemicellulose and lignin. In the current work, glycolaldehyde, furfural and acetaldehyde are studied as model compounds of the three classes of biomass-derivatives. Monometallic Ni(111) and monolayer (ML) Fe/Ni(111) bimetallic surfaces are studied for the reaction pathways of the three biomass surrogates. The ML Fe/Ni(111) surface is identified as an efficient surface for the conversion of biomass-derivatives from the combined results of density functional theory (DFT) calculations and temperature programmed desorption (TPD) experiments. A correlation is also established between the optimized adsorption geometry and experimental reaction pathways. These results should provide helpful insights in catalyst design for the upgrading and conversion of biomass.

A Comparison of Producer Gas, Biochar, and Activated Carbon from Two Distributed Scale Thermochemical Conversion Systems Used to Process Forest Biomass

Directory of Open Access Journals (Sweden)

Nathaniel Anderson

2013-01-01

Full Text Available Thermochemical biomass conversion systems have the potential to produce heat, power, fuels and other products from forest biomass at distributed scales that meet the needs of some forest industry facilities. However, many of these systems have not been deployed in this sector and the products they produce from forest biomass have not been adequately described or characterized with regards to chemical properties, possible uses, and markets. This paper characterizes the producer gas, biochar, and activated carbon of a 700 kg h−1 prototype gasification system and a 225 kg h−1 pyrolysis system used to process coniferous sawmill and forest residues. Producer gas from sawmill residues processed with the gasifier had higher energy content than gas from forest residues, with averages of 12.4 MJ m−3 and 9.8 MJ m−3, respectively. Gases from the pyrolysis system averaged 1.3 MJ m−3 for mill residues and 2.5 MJ m−3 for forest residues. Biochars produced have similar particle size distributions and bulk density, but vary in pH and carbon content. Biochars from both systems were successfully activated using steam activation, with resulting BET surface area in the range of commercial activated carbon. Results are discussed in the context of co-locating these systems with forest industry operations.

Biochemical conversions of lignocellulosic biomass for sustainable fuel-ethanol production in the upper Midwest

Science.gov (United States)

Brodeur-Campbell, Michael J.

Biofuels are an increasingly important component of worldwide energy supply. This research aims to understand the pathways and impacts of biofuels production, and to improve these processes to make them more efficient. In Chapter 2, a life cycle assessment (LCA) is presented for cellulosic ethanol production from five potential feedstocks of regional importance to the upper Midwest — hybrid poplar, hybrid willow, switchgrass, diverse prairie grasses, and logging residues — according to the requirements of Renewable Fuel Standard (RFS). Direct land use change emissions are included for the conversion of abandoned agricultural land to feedstock production, and computer models of the conversion process are used in order to determine the effect of varying biomass composition on overall life cycle impacts. All scenarios analyzed here result in greater than 60% reduction in greenhouse gas emissions relative to petroleum gasoline. Land use change effects were found to contribute significantly to the overall emissions for the first 20 years after plantation establishment. Chapter 3 is an investigation of the effects of biomass mixtures on overall sugar recovery from the combined processes of dilute acid pretreatment and enzymatic hydrolysis. Biomass mixtures studied were aspen, a hardwood species well suited to biochemical processing; balsam, a high-lignin softwood species, and switchgrass, an herbaceous energy crop with high ash content. A matrix of three different dilute acid pretreatment severities and three different enzyme loading levels was used to characterize interactions between pretreatment and enzymatic hydrolysis. Maximum glucose yield for any species was 70% of theoretical for switchgrass, and maximum xylose yield was 99.7% of theoretical for aspen. Supplemental β-glucosidase increased glucose yield from enzymatic hydrolysis by an average of 15%, and total sugar recoveries for mixtures could be predicted to within 4% by linear interpolation of the pure

Energy from biomass: An overview. Energie uit biomassa: Een overzicht

Energy Technology Data Exchange (ETDEWEB)

Van der Toorn, L J; Elliott, T P [Non-Traditional Business Division, Shell International Petroleum Company, London (United Kingdom)

1992-03-01

Attention is paid to the effect of the use of energy from biomass on the greenhouse effect. An overview is given of the aspects of forest plantation, carbon dioxide fixation and energy from biomass, in particular with regard to the potential impact of the use of biomass energy on the speed of accumulation of carbon in the atmosphere. A simple model of the carbon cycle to illustrate the geochemical, biological and antropogenic characteristics of the cycle is presented and briefly discussed. Biomass, which is appropriate for energy applications, can be subdivided into three categories: polysaccharides, vegetable oils, and lignocellulosis. The costs for the latter are discussed. Three important options to use biomass as a commercial energy source are solid fuels, liquid fuels, and power generation. For each option the value of energy (on a large-scale level) is compared to the costs of several types of biomass. Recent evaluation of new techniques show that small biomass conversion plants can realize an electricity efficiency of 40%, with capitalized costs far below comparable conventional biomass conversion plants. One of the policy instruments to stimulate the use of biomass as an energy source is the carbon levy, in which the assumed external costs to reduce carbon dioxide emission are expressed. Political and administrative feasibility are important factors in the decision making with regard to carbon storage and energy plantations. 6 figs.

Cost effectiveness of transportation fuels from biomass

International Nuclear Information System (INIS)

De Jager, D.; Faaij, A.P.C.; Troelstra, W.P.

1998-06-01

The aim of the study on the title subject was to investigate whether stimulation of the production and use of biofuels for transportation is worthwhile compared to the production of electricity from biomass. Several options are compared to each other and with reference technologies on the basis of the consumption or the avoided input of fossil fuels, emissions of greenhouse gases, specific costs and cost effectiveness. For each phase in the biomass conversion process (cultivation, pretreatment, transportation, conversion, distribution and final consumption) indicators were collected from the literature. Next to costs of the bioconversion routes attention is paid to other relevant aspects that are important for the introduction of the technological options in the Netherlands. 41 refs

Life-Cycle Analysis of Greenhouse Gas Emissions and Water Consumption – Effects of Coal and Biomass Conversion to Liquid Fuels as Analyzed with the GREET Model

Energy Technology Data Exchange (ETDEWEB)

Li, Qianfeng [Argonne National Lab. (ANL), Argonne, IL (United States); Cai, Hao [Argonne National Lab. (ANL), Argonne, IL (United States); Han, Jeongwoo [Argonne National Lab. (ANL), Argonne, IL (United States)

2017-06-01

The vast reserves of coal in the U.S. provide a significant incentive for the development of processes for coal conversion to liquid fuels (CTL). Also, CTL using domestic coal can help move the U.S. toward greater energy independence and security. However, current conversion technologies are less economically competitive and generate greater greenhouse gas (GHG) emissions than production of petroleum fuels. Altex Technologies Corporation (Altex, hereinafter) and Pennsylvania State University have developed a hybrid technology to produce jet fuel from a feedstock blend of coal and biomass. Collaborating with Altex, Argonne National Laboratory has expanded and used the Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET®) model to assess the life-cycle GHG emissions and water consumption of this hybrid technology. Biomass feedstocks include corn stover, switchgrass, and wheat straw. The option of biomass densification (bales to pellets) is also evaluated in this study. The results show that the densification process generates additional GHG emissions as a result of additional biomass process energy demand. This process coproduces a large amount of char, and this study investigates two scenarios to treat char: landfill disposal (Char-LF) and combustion for combined heat and power (CHP). Since the CHP scenarios export excess heat and electricity as coproducts, two coproduct handling methods are used for well-to-wake (WTWa) analysis: displacement (Char-CHP-Disp) and energy allocation (Char-CHP-EnAllo). When the feedstock contains 15 wt% densified wheat straw and 85 wt% lignite coal, WTWa GHG emissions of the coal-and-biomass-to-liquid pathways are 116, 97, and 137 gCO2e per megajoule (MJ) under the Char-LF, Char-CHP-Disp, and Char-CHP-EnAllo scenarios, respectively, as compared to conventional jet fuel production at 84 gCO2e/MJ. WTWa water consumption values are 0.072, -0.046, and 0.044 gal/MJ for Char-LF, Char-CHP-Disp, and Char

Conversion of Abbandoned Military Areas

Directory of Open Access Journals (Sweden)

Daiva Marcinkevičiūtė

2011-03-01

Full Text Available The article analyses the situation of abandoned military sites, their value and significance of their conservation. It also reviews their impact on their environment and their potential in tourism, environmental, economic and social spheres. Further the positive experiences in military sites' conversion are studied. The importance of society's involvement in the conversions is discussed. The situation of XIX-XX age's military object's, the significance of their conservation and their potential in tourism market is separately analysed. The results of two researches are introduced, one of which inquires about the Lithuanian military objects' potential in tourism sphere, another one explores the possibilities of conversion. Article in Lithuanian

Metal Carbides for Biomass Valorization

Directory of Open Access Journals (Sweden)

Carine E. Chan-Thaw

2018-02-01

Full Text Available Transition metal carbides have been utilized as an alternative catalyst to expensive noble metals for the conversion of biomass. Tungsten and molybdenum carbides have been shown to be effective catalysts for hydrogenation, hydrodeoxygenation and isomerization reactions. The satisfactory activities of these metal carbides and their low costs, compared with noble metals, make them appealing alternatives and worthy of further investigation. In this review, we succinctly describe common synthesis techniques, including temperature-programmed reaction and carbothermal hydrogen reduction, utilized to prepare metal carbides used for biomass transformation. Attention will be focused, successively, on the application of transition metal carbide catalysts in the transformation of first-generation (oils and second-generation (lignocellulose biomass to biofuels and fine chemicals.

Biomass will grow as a chemical feedstock

Energy Technology Data Exchange (ETDEWEB)

Coombs, J

1979-11-30

This article discusses the possibility of biomass replacing a large fraction of oil use both as a fuel and a chemical feedstock. Problems arise from the low density, calorific value and diffuse nature of plant material which makes collection and processing expensive on both a financial and an energy cost basis. Two distinct sources of biomass are identified: (a) wastes and residues and (b) purpose grown crops. In the same way it is possible to distinguish thermal and biological conversion technologies. Finally, worldwide biomass energy programmes are reviewed.

Biomass processing over gold catalysts

CERN Document Server

Simakova, Olga A; Murzin, Dmitry Yu

2014-01-01

The book describes the valorization of biomass-derived compounds over gold catalysts. Since biomass is a rich renewable feedstock for diverse platform molecules, including those currently derived from petroleum, the interest in various transformation routes has become intense. Catalytic conversion of biomass is one of the main approaches to improving the economic viability of biorefineries.  In addition, Gold catalysts were found to have outstanding activity and selectivity in many key reactions. This book collects information about transformations of the most promising and important compounds derived from cellulose, hemicelluloses, and woody biomass extractives. Since gold catalysts possess high stability under oxidative conditions, selective oxidation reactions were discussed more thoroughly than other critical reactions such as partial hydrogenation, acetalization, and isomerization. The influence of reaction conditions, the role of the catalyst, and the advantages and disadvantages of using gold are pre...

Synergetic and inhibition effects in carbon dioxide gasification of blends of coals and biomass fuels of Indian origin.

Science.gov (United States)

Satyam Naidu, V; Aghalayam, P; Jayanti, S

2016-06-01

The present study investigates the enhancement of CO2 gasification reactivity of coals due to the presence of catalytic elements in biomass such as K2O, CaO, Na2O and MgO. Co-gasification of three Indian coal chars with two biomass chars has been studied using isothermal thermogravimetric analysis (TGA) in CO2 environment at 900, 1000 and 1100°C. The conversion profiles have been used to establish synergetic or inhibitory effect on coal char reactivity by the presence of catalytic elements in biomass char by comparing the 90% conversion time with and without biomass. It is concluded that both biomasses exhibit synergistic behavior when blended with the three coals with casuarina being more synergetic than empty fruit bunch. Some inhibitory effect has been noted for the high ash coal at the highest temperature with higher 90% conversion time for the blend over pure coal, presumably due to diffusional control of the conversion rate. Copyright © 2016 Elsevier Ltd. All rights reserved.

Retrofit options to enable biomass firing at Irish peat plants: Background report 4.2 for the EU Joule 2+ project: Energy from biomass: An assessment of two promising systems for energy production

International Nuclear Information System (INIS)

Van den Broek, R.; Faaij, A.; Blaney, G.

1995-05-01

An overview is given of the most promising options for retrofitting existing Irish peat plants to accept biomass fuel. It is expected that with low investment costs the existing peat stations can be adapted to enable them to fire biomass. It will also be possible to co-fire peat and biomass, this option will become a way of using biomass in power generation with relatively low risk, both on the field of initial investments and supply security. The objectives of this report are: assessing the different technical options for retrofitting the plants to enable biomass firing; provide investment costs, efficiencies, emissions and expected lifetimes for the different retrofit options. The results from this study are used in the final integration phase of the EU-Joule project 'Energy from biomass'. Chapter 2 deals with methodological considerations which have been made in estimation of the investment costs. In chapter 3 the present situation is described. Both peat harvesting and power plant operation of both sod and milled peat plants are explained. Also some past experiences with wood chips firing in Irish peat stations are discussed. Chapter 4 gives a general view on retrofitting peat plants to enable biomass firing. Some starting points like biomass fuel feeding and emission standards that have to be met are highlighted. The rationale behind four main choices are given. Finally, a technical description is presented of the two boiler adaptations that will be considered among the different retrofit options, namely conversion of milled peat units into bubbling fluidized bed and into a whole tree energy unit. Six retrofit options are described in more detail in chapter 5. Information is given on the present status of the plants, the technical considerations of the retrofit, expected performance and an estimation of a range in which the investment costs can be expected. 4 figs., 10 tabs., 5 appendices

Fiscal 2000 report of investigation. Research on effective use of technology for biomass waste and diffusion scenario of the technology; 2000 nendo biomass kei haikibutsu no yuko riyo gijutsu to sono fukyu scenario no chosa hokokusho

Energy Technology Data Exchange (ETDEWEB)

NONE

2001-03-01

Examination and proposal were made on the effective uses of technologies for biomass wastes and on the diffusion scenarios, with trial calculations done to find the maximum reducible amounts in terms of carbon dioxide. In the examination of the systems, it was focused on five technologies, namely, direct combustion of straw and rice straw/CHP/heat utilization, synthesis of gasified methanol from demolition wood, biogas/CHP from livestock feces and urine, conversion to ethanol through saccharification of used paper, and conversion to biodiesel from vegetable waste oil; the examination also covered each feature, core function, use situation inside and outside Japan, technological system for each energy conversion, etc. Further, solutions were examined and proposed concerning diffusion barriers in each scenario. Consequently, the maximum amount of CO2 reduction effect was found respectively 217 thousand t-C in the straw and rice straw, 500 thousand t-C in the demolition wood, 9.53 million t-C in the livestock feces/urine, 820 thousand t-C in the used paper, and 30 thousand t-C in the vegetable waste oil. (NEDO)

High-throughput microplate technique for enzymatic hydrolysis of lignocellulosic biomass.

Science.gov (United States)

Chundawat, Shishir P S; Balan, Venkatesh; Dale, Bruce E

2008-04-15

Several factors will influence the viability of a biochemical platform for manufacturing lignocellulosic based fuels and chemicals, for example, genetically engineering energy crops, reducing pre-treatment severity, and minimizing enzyme loading. Past research on biomass conversion has focused largely on acid based pre-treatment technologies that fractionate lignin and hemicellulose from cellulose. However, for alkaline based (e.g., AFEX) and other lower severity pre-treatments it becomes critical to co-hydrolyze cellulose and hemicellulose using an optimized enzyme cocktail. Lignocellulosics are appropriate substrates to assess hydrolytic activity of enzyme mixtures compared to conventional unrealistic substrates (e.g., filter paper, chromogenic, and fluorigenic compounds) for studying synergistic hydrolysis. However, there are few, if any, high-throughput lignocellulosic digestibility analytical platforms for optimizing biomass conversion. The 96-well Biomass Conversion Research Lab (BCRL) microplate method is a high-throughput assay to study digestibility of lignocellulosic biomass as a function of biomass composition, pre-treatment severity, and enzyme composition. The most suitable method for delivering milled biomass to the microplate was through multi-pipetting slurry suspensions. A rapid bio-enzymatic, spectrophotometric assay was used to determine fermentable sugars. The entire procedure was automated using a robotic pipetting workstation. Several parameters that affect hydrolysis in the microplate were studied and optimized (i.e., particle size reduction, slurry solids concentration, glucan loading, mass transfer issues, and time period for hydrolysis). The microplate method was optimized for crystalline cellulose (Avicel) and ammonia fiber expansion (AFEX) pre-treated corn stover. Copyright 2008 Wiley Periodicals, Inc.

Engineering a Synthetic Microbial Consortium for Comprehensive Conversion of Algae Biomass into Terpenes for Advanced Biofuels and Bioproducts

Energy Technology Data Exchange (ETDEWEB)

Wu, Weihua [Sandia National Lab. (SNL-CA), Livermore, CA (United States); Wu, Benjamin Chiau-Pin [Sandia National Lab. (SNL-CA), Livermore, CA (United States); Davis, Ryan Wesley [Sandia National Lab. (SNL-CA), Livermore, CA (United States)

2015-10-01

Recent strategies for algae-based biofuels have primarily focused on biodiesel production by exploiting high algal lipid yields under nutrient stress conditions. However, under conditions supporting robust algal biomass accumulation, carbohydrate and proteins typically comprise up to ~80% of the ash-free dry weight of algae biomass. Therefore, comprehensive utilization of algal biomass for production of multipurpose intermediate- to high-value bio-based products will promote scale-up of algae production and processing to commodity volumes. Terpenes are hydrocarbon and hydrocarbon-like (C:O>10:1) compounds with high energy density, and are therefore potentially promising candidates for the next generation of value added bio-based chemicals and “drop-in” replacements for petroleum-based fuels. In this study, we demonstrated the feasibility of bioconversion of proteins into sesquiterpene compounds as well as comprehensive bioconversion of algal carbohydrates and proteins into biofuels. To achieve this, the mevalonate pathway was reconstructed into an E. coli chassis with six different terpene synthases (TSs). Strains containing the various TSs produced a spectrum of sesquiterpene compounds in minimal medium containing amino acids as the sole carbon source. The sesquiterpene production was optimized through three different regulation strategies using chamigrene synthase as an example. The highest total terpene titer reached 166 mg/L, and was achieved by applying a strategy to minimize mevalonate accumulation in vivo. The highest yields of total terpene were produced under reduced IPTG induction levels (0.25 mM), reduced induction temperature (25°C), and elevated substrate concentration (20 g/L amino acid mixture). A synthetic bioconversion consortium consisting of two engineering E. coli strains (DH1-TS and YH40-TS) with reconstructed terpene biosynthetic pathways was designed for comprehensive single-pot conversion of algal carbohydrates and proteins to

Analytical Methods for Biomass Characterization during Pretreatment and Bioconversion

Energy Technology Data Exchange (ETDEWEB)

Pu, Yunqiao [ORNL; Meng, Xianzhi [University of Tennessee, Knoxville (UTK); Yoo, Chang Geun; Li, Mi; Ragauskas, Arthur J [ORNL

2016-01-01

Lignocellulosic biomass has been introduced as a promising resource for alternative fuels and chemicals because of its abundance and complement for petroleum resources. Biomass is a complex biopolymer and its compositional and structural characteristics largely vary depending on its species as well as growth environments. Because of complexity and variety of biomass, understanding its physicochemical characteristics is a key for effective biomass utilization. Characterization of biomass does not only provide critical information of biomass during pretreatment and bioconversion, but also give valuable insights on how to utilize the biomass. For better understanding biomass characteristics, good grasp and proper selection of analytical methods are necessary. This chapter introduces existing analytical approaches that are widely employed for biomass characterization during biomass pretreatment and conversion process. Diverse analytical methods using Fourier transform infrared (FTIR) spectroscopy, gel permeation chromatography (GPC), and nuclear magnetic resonance (NMR) spectroscopy for biomass characterization are reviewed. In addition, biomass accessibility methods by analyzing surface properties of biomass are also summarized in this chapter.

Short-time ultrasonication treatment in enzymatic hydrolysis of biomass

Science.gov (United States)

Zengqian Shi; Zhiyong Cai; Siqun Wang; Qixin Zhong; Joseph J. Bozell

2013-01-01

To improve the conversion of enzymatic hydrolysis of biomass in an energy-efficient manner, two shorttime ultrasonication strategies were applied on six types of biomass with different structures and components. The strategies include pre-sonication before the hydrolysis and intermittent sonication during the ongoing hydrolysis. The microstructures of each type of...

Bibliography of Finnish biomass and peat literature 1986-1987. Biomassa- ja turvebibliografia 1986-1987

Energy Technology Data Exchange (ETDEWEB)

Alakangas, E; Luoma, H

1989-02-15

This bibliography is a collection of citations from Finnish literature dealing with energy use of peat and biomass, collected during 1986 and 1987. The citations have been made in English because they were abstracted for international databases, such as BIOMASS, NEI (Nordic Energy Index) and DOE ENERGY. Collection of citations is a part of information service of International Energy Agency's (IEA) Biomass Conversion Technical Information Service (BCTIS). dissemination of information relating to all aspects of biomass energy including cultivation, harvesting, materials handling, conversion techniques and environmental and economic aspects. The bibliography contain 226 references. The citations contain bibliographic information and abstract. The keyword index is included.

Development of a system for characterizing biomass quality of lignocellulosic feedstocks for biochemical conversion

Science.gov (United States)

Murphy, Patrick Thomas

The purpose of this research was twofold: (i) to develop a system for screening lignocellulosic biomass feedstocks for biochemical conversion to biofuels and (ii) to evaluate brown midrib corn stover as feedstock for ethanol production. In the first study (Chapter 2), we investigated the potential of corn stover from bm1-4 hybrids for increased ethanol production and reduced pretreatment intensity compared to corn stover from the isogenic normal hybrid. Corn stover from hybrid W64A X A619 and respective isogenic bm hybrids was pretreated by aqueous ammonia steeping using ammonium hydroxide concentrations from 0 to 30%, by weight, and the resulting residues underwent simultaneous saccharification and cofermentation (SSCF) to ethanol. Dry matter (DM) digested by SSCF increased with increasing ammonium hydroxide concentration across all genotypes (P>0.0001) from 277 g kg-1 DM in the control to 439 g kg-1 DM in the 30% ammonium hydroxide pretreatment. The bm corn stover materials averaged 373 g kg-1 DM of DM digested by SSCF compared with 335 g kg-1 DM for the normal corn stover (Pdetergent fiber (NDF) as a cell-wall isolation procedure, and (iii) elimination of the fermentation organism in the SSCF procedures used to determine biochemically available carbohydrates. The original and the HTP assay methods were compared using corn cobs, hybrid poplar, kenaf, and switchgrass. Biochemically available carbohydrates increased with the HTP methods in the corn cobs, hybrid poplar, and switchgrass, but remained the same in the kenaf. Total available carbohydrates increased and unavailable carbohydrates decreased with the HTP methods in the corn cobs and switchgrass and remained the same in the hybrid poplar and kenaf. There were no differences in total carbohydrates (CT) between the two methods. The final study evaluated the variability of biomass quality parameters in a set of corn stover samples, and developed calibration equations for determining parameter values using near

Decentralized biomass combustion: State of the art and future development

NARCIS (Netherlands)

Obernberger, I.

1998-01-01

The present amount of biomass used for heat, and to a smaller extent electricity production, is already considerable in several European countries but the potential unused in Europe is even higher. Combustion is the most mature conversion technology utilized for biomass. The systems addressed in

Biomass gasification in a circulating fluidized bed; Vergasung von Biomasse in der zirkulierenden Wirbelschicht

Energy Technology Data Exchange (ETDEWEB)

Ising, M; Hoelder, D; Backhaus, C; Althaus, W [Fraunhofer Inst. fuer Umwelt-, Sicherheits- und Energietechnik UMSICHT, Oberhausen (Germany)

1998-09-01

Biomass gasification in a circulating fluidized bed, in combination with a gas engine or gas burner, is a promising option for energetic use of biomass. Economic efficiency analyses on the basis of the UMSICHT plant show that this technology for combined heat and power generation from biomass is promising also for the range below 10 MW. The economic situation of any plant must be considered for the specific boundary conditions imposed by the power supply industry. The feasibility of the process was tested in a demonstration plant at Oberhausen. The plant was optimized further in extensive test series, and a number of tar reduction processes were investigated and improved on. The authors now intend to prove that gasification in a circulating fluidized bed combined with a gas engine cogeneration plant is feasible in continuous operation. (orig./SR) [Deutsch] Die Vergasung von Biomasse in der zirkulierenden Wirbelschicht ist in Kombination mit einem Gasmotor oder einem Gasbrenner eine vielversprechende Option fuer die energetische Biomassenutzung. Wirtschaftlichkeitsbetrachtungen auf Basis der UMSICHT-Anlage zeigen, dass diese Technologie fuer die gekoppelte Strom- und Waermeerzeugung aus Biomasse auch im Leistungsbereich unter 10 MW grosse Chancen verspricht. Dabei ist die oekonomische Situation einer Anlage im Einzelfall unter Beachtung der energiewirtschaftlichen Randbedingungen zu beurteilen. Durch den Betrieb einer Demonstrationsanlage in Oberhausen konnte die Funktion des Verfahrens nachgewiesen werden. In weiteren umfangreichen Versuchsreihen werden die Anlage weiter optimiert und verschiedene Konzepte zur Teerminderung untersucht und weiterentwickelt. Angestrebt ist der Nachweis des Dauerbetriebs von ZWS-Vergasung zusammen mit dem Gasmotoren-BHKW. (orig./SR)

From waste water treatment to land management: Conversion of aquatic biomass to biochar for soil amelioration and the fortification of crops with essential trace elements.

Science.gov (United States)

Roberts, David A; Paul, Nicholas A; Cole, Andrew J; de Nys, Rocky

2015-07-01

Macroalgae can be grown in industrial waste water to sequester metals and the resulting biomass used for biotechnological applications. We have previously cultivated the freshwater macroalga Oedogonium at a coal-fired power station to treat a metal-contaminated effluent from that facility. We then produced biochar from this biomass and determined the suitability of both the biomass and the biochar for soil amelioration. The dried biomass of Oedogonium cultivated in the waste water contained several elements for which there are terrestrial biosolids criteria (As, Cd, Cr, Cu, Pb, Ni, Se and Zn) and leached significant amounts of these elements into solution. Here, we demonstrate that these biomass leachates impair the germination and growth of radishes as a model crop. However, the biochar produced from this same biomass leaches negligible amounts of metal into solution and the leachates support high germination and growth of radishes. Biochar produced at 750 °C leaches the least metal and has the highest recalcitrant C content. When this biochar is added to a low-quality soil it improves the retention of nutrients (N, P, Ca, Mg, K and Mo) from fertilizer in the soil and the growth of radishes by 35-40%. Radishes grown in the soils amended with the biochar have equal or lower metal contents than radishes grown in soil without biochar, but much higher concentrations of essential trace elements (Mo) and macro nutrients (P, K, Ca and Mg). The cultivation of macroalgae is an effective waste water bioremediation technology that also produces biomass that can be used as a feedstock for conversion to biochar for soil amelioration. Copyright © 2015 Elsevier Ltd. All rights reserved.

Production of renewable phenolic resins by thermochemical conversion of biomass: A review

Energy Technology Data Exchange (ETDEWEB)

Effendi, A.; Gerhauser, H.; Bridgwater, A.V. [Bio-Energy Research Group, Aston University, Birmingham B4 7ET (United Kingdom)

2008-10-15

This review covers the production and utilisation of liquids from the thermal processing of biomass and related materials to substitute for synthetic phenol and formaldehyde in phenol formaldehyde resins. These resins are primarily employed in the manufacture of wood panels such as plywood, MDF, particle-board and OSB. The most important thermal conversion methods for this purpose are fast pyrolysis and vacuum pyrolysis, pressure liquefaction and phenolysis. Many feedstocks have been tested for their suitability as sources of phenolics including hard and softwoods, bark and residual lignins. Resins have been prepared utilising either the whole liquid product, or a phenolics enriched fraction obtained after fractional condensation or further processing, such as solvent extraction. None of the phenolics production and fractionation techniques covered in this review are believed to allow substitution of 100% of the phenol content of the resin without impacting its effectiveness compared to commercial formulations based on petroleum derived phenol. This survey shows that considerable progress has been made towards reaching the goal of a price competitive renewable resin, but that further research is required to meet the twin challenges of low renewable resin cost and satisfactory quality requirements. Particular areas of concern are wood panel press times, variability of renewable resin properties, odour, lack of reactive sites compared to phenol and potential for increased emissions of volatile organic compounds. (author)

Potential and possibilities of supplying energy from biomass and biogas; Potentiale und Moeglichkeiten der Energiebereitstellung durch Biomasse und Biogas

Energy Technology Data Exchange (ETDEWEB)

Sonnenberg, H. [Bundesforschungsanstalt fuer Landwirtschaft, Braunschweig (Germany). Inst. fuer Betriebstechnik; Weiland, P.; Ahlgrimm, H.J. [Bundesforschungsanstalt fuer Landwirtschaft (FAL), Braunschweig (Germany). Inst. fuer Technologie

1998-06-01

Agriculture`s potential contribution to the energy supply of the ``town of the future`` through the conversion of biomass to energy, including biogas production, is a rather modest one. Supposing that the share of total renewable energy in Germany`s primary energy demand rises to approximately 4%, then the proportion of biomass from biotic raw materials especially produced for the purpose will at the most make up an eighth of this amount. Beyond this, biomass is burdened with other drawbacks such as low supply efficiency, limited availability, and weather-dependent reliability. On the other hand, biomass is well suited for conversion to solid, liquid, and gaseous fuels, including inexpensive ones with low energy density (solid fuels), mostly used for stationary heating applications, as well as more expensive ones such as liquid fuels with a high energy density for mobile applications in the automotive sector. Thanks to its capacity to regenerate, biomass is an inexhaustible resource. Moreover, its natural life cycle has a small impact on the environment. [Deutsch] Der Beitrag, den die Landwirtschaft durch energetische Nutzung von Biomasse, z.B. auch mit der Erzeugung von Biogas, zur Energieversorgung der `Stadt der Zukunft` leisten kann, nimmt sich bescheiden aus. Wird erwartet, dass innerhalb des naechsten Jahrzehnts der Anteil regenerativer Energien insgesamt auf etwa 4% des Primaerenergie-Verbrauchs Deutschlands ansteigen koennte, so duerfte Biomasse als speziell zur Energiegewinnung angebaute nachwachsende Rohstoffe mit bestensfalls 0,5 Prozentpunkten daran beteiligt sein. Es beduerfen darueber hinaus auch Nachteile, wie geringe Bereitstellungseffizienz, beschraenkte Verfuegbarkeit und witterungsabhaengige Zuverlaessigkeit, der Beachtung. Die Biomasse kann jedoch mit Erfolg in feste, fluessige und gasfoermige Energietraeger konvertiert werden, sowohl in preiswerte mit geringer Energiedichte (Festbrennstoffe) fuer bevorzugt stationaeren Heizungs-Einsatz als auch

Study on thermochemical liquefaction of biomass feedstocks; Biomass genryo no yuka hanno tokusei ni kansuru kisoteki kenkyu

Energy Technology Data Exchange (ETDEWEB)

NONE

1997-02-10

Liquefaction is applied to various biomass wastes and unused biomass to study characteristics of the liquefaction in each case. The paper described the system of the conversion and use of biomass into energy, conducted the positioning of the liquefaction, and outlined a history of the liquefaction chemistry and the study. To obtain basic data of characteristics of the liquefaction of various biomass raw materials, the liquefaction was conducted changing operational factors for the purpose of clarifying the product distribution of oil and by-products and oil properties. A comprehensive consideration was made of the liquefaction based on basic data and literature reports on the liquefaction of various biomass. From the above-mentioned studies, it was concluded that the energy can be recovered in a form of oil by applying the liquefaction to various biomass materials. A series of the study clarified effects of various operational factors on characteristics of the liquefaction as well as effects of classification of biomass materials and composition of the materials on characteristics of the liquefaction. 141 refs., 78 figs., 56 tabs.

Biomass as an alternative energy source

Energy Technology Data Exchange (ETDEWEB)

De Bruyn, M.; Naveau, H.; Declerck, C.; Vanacker, L.; Mahy, D.; Schepens, G.

The object of this paper is to evaluate the possible production and utilization of biomass as an energy source in Belgium. Four conversion methods are considered - methanation, fermentation, incineration and gasification - from a technological and economic viewpoint.

Pyrolysis of biomass for hydrogen production

International Nuclear Information System (INIS)

Constantinescu, Marius; David, Elena; Bucura, Felicia; Sisu, Claudia; Niculescu, Violeta

2006-01-01

Biomass processing is a new technology within the area of renewable energies. Current energy supplies in the world are dominated by fossil fuels (some 80% of the total use of over 400 EJ per year). Nevertheless, about 10-15% of this demand is covered by biomass resources, making biomass by far the most important renewable energy source used to date. On average, in the industrialized countries biomass contributes some 9-13% to the total energy supplies, but in developing countries the proportion is as high as a fifth to one third. In quite a number of countries biomass covers even over 50 to 90% of the total energy demand. Classic application of biomass combustion is heat production for domestic applications. A key issue for bio-energy is that its use should be modernized to fit into a sustainable development path. Especially promising are the production of electricity via advanced conversion concepts (i.e. gasification and state-of-the-art combustion and co-firing) and modern biomass derived fuels like methanol, hydrogen and ethanol from ligno-cellulosic biomass, which can reach competitive cost levels within 1-2 decades (partly depending on price developments with petroleum). (authors)

Biomass: An Alternative Source of Energy for Eighth or Ninth Grade Science.

Science.gov (United States)

Heyward, Lillie; Murff, Marye

This teaching unit develops the possibility of using biomass as an alternative source of energy. The concept of biomass is explained and the processes associated with its conversion to energy are stated. Suggestions for development of biomass technology in different geographic areas are indicated. Lessons for 6 days are presented for use with…

Engineering Aspergillus oryzae A-4 through the chromosomal insertion of foreign cellulase expression cassette to improve conversion of cellulosic biomass into lipids.

Science.gov (United States)

Lin, Hui; Wang, Qun; Shen, Qi; Ma, Junwei; Fu, Jianrong; Zhao, Yuhua

2014-01-01

A genetic modification scheme was designed for Aspergillus oryzae A-4, a natural cellulosic lipids producer, to enhance its lipid production from biomass by putting the spotlight on improving cellulase secretion. Four cellulase genes were separately expressed in A-4 under the control of hlyA promoter, with the help of the successful development of a chromosomal genetic manipulation system. Comparison of cellulase activities of PCR-positive transformants showed that these transformants integrated with celA gene and with celC gene had significantly (pcellulase gene in A2-2 and D1-B1 was subsequently investigated. It was noted that cellulase expression repressed biomass formation but enhanced lipid accumulation; whereas the inhibitory effect on cell growth would be shielded during cellulosic lipids production owing to the essential role of cellulase in substrate utilization. Different metabolic profiles also existed between A2-2 and D1-B1, which could be attributed to not only different transgene but also biological impacts of different integration. Overall, both simultaneous saccharification and lipid accumulation were enhanced in A2-2 and D1-B1, resulting in efficient conversion of cellulose into lipids. A regulation of cellulase secretion in natural cellulosic lipids producers could be a possible strategy to enhance its lipid production from lignocellulosic biomass.

Swiss Biomass Programme - Overview report on the 2007 research programme; Programm Biomasse: Ueberblicksbericht zum Forschungsprogramm 2007

Energy Technology Data Exchange (ETDEWEB)

Binggeli, D; Guggisberg, B

2008-07-01

This illustrated report for the Swiss Federal Office of Energy (SFOE) presents an overview of the results obtained in 2007 within the framework of the Swiss Biomass research programme. The potential for biomass use in Switzerland is reviewed and the emphases of the national programme are discussed. The results obtained are noted for the following areas: process optimisation, including - amongst others - particle emissions and control aspects as well as combined wood-pellets and solar heating systems. Projects involving non-wood biomass are reported on, including biomass digesters and various biogas systems. Further reports deal with the analysis and optimisation of material flows, organic pollutants and methane losses. New conversion technologies are reported on. Further reports deal with basic strategies and concepts in the area of biomass usage. National and international co-operation is also discussed. A selection of innovative pilot and demonstration projects is also presented and research and development projects are listed.

Assessment of Biomass Resources in Afghanistan

Energy Technology Data Exchange (ETDEWEB)

Milbrandt, A.; Overend, R.

2011-01-01

Afghanistan is facing many challenges on its path of reconstruction and development. Among all its pressing needs, the country would benefit from the development and implementation of an energy strategy. In addition to conventional energy sources, the Afghan government is considering alternative options such as energy derived from renewable resources (wind, solar, biomass, geothermal). Biomass energy is derived from a variety of sources -- plant-based material and residues -- and can be used in various conversion processes to yield power, heat, steam, and fuel. This study provides policymakers and industry developers with information on the biomass resource potential in Afghanistan for power/heat generation and transportation fuels production. To achieve this goal, the study estimates the current biomass resources and evaluates the potential resources that could be used for energy purposes.

Conversion of biomass into energy source

International Nuclear Information System (INIS)

Antonescu, S.; Garjoaba, M.; Antonescu, A.

2005-01-01

This study assists the identification of possible application and markets of the CHP-plants in the NAS states, and forms the first part of a detailed study on economical and ecological prospects of small scale and large heat pipe reformers in NAS. It is well known that the energy strategy of the European Union, foresees the increase of the participation of the renewable energy from the total of the energy resources of the European Union, up to 12% in 2010. This participation is of a great importance for the adequate reduction of green house effect gases. From the energy production point of view it is proven the fact that in 2010 the production of renewable energy will be: electricity - 675 tWh; heat - 80 Mtoe (930 TWh). From the above mentioned energy demand, the biomass will cover: electricity - 230 TWh-34,1%; heat - 75 Mtoe (93,8%)

Conversion of woody biomass into fermentable sugars by cellulase from Agaricus arvensis.

Science.gov (United States)

Jeya, Marimuthu; Nguyen, Ngoc-Phuong-Thao; Moon, Hee-Jung; Kim, Sang-Hwan; Lee, Jung-Kul

2010-11-01

Agaricus arvensis, a newly isolated basidiomycetous fungus, was found to secrete efficient cellulases. The strain produced the highest endoglucanase (EG), cellobiohydrolase (CBH) and beta-glucosidase (BGL) activities of 0.3, 3.2 and 8U/mg-protein, respectively, with rice straw as the carbon source. Saccharification of the woody biomass with A. arvensis cellulase as the enzyme source released a high level of fermentable sugars. Enzymatic hydrolysis of the poplar biomass was optimized using the response surface methodology in order to study the influence of the variables (pH, temperature, cellulases concentration and substrate concentration). The enzyme and substrate concentrations were identified as the limiting factors for the saccharification of poplar wood biomass. A total reducing sugar level of 29g/L (293mg/g-substrate) was obtained at an enzyme concentration of 65FPU/g-substrate after optimization of the hydrolysis parameters. The model validation showed a good agreement between the experimental results and the predicted responses. A. arvensis could be a good candidate for the production of reducing sugars from a cellulosic biomass.

Potentials for forest woody biomass production in Serbia

Directory of Open Access Journals (Sweden)

Vasiljević Aleksandar Lj.

2015-01-01

Full Text Available The paper presents the analysis of possible potentials for the production of forest biomass in Serbia taking into consideration the condition of forests, present organizational and technical capacities as well as the needs and situation on the firewood market. Starting point for the estimation of production potentials for forest biomass is the condition of forests which is analyzed based on the available planning documents on all levels. Potentials for biomass production and use refer to initial periods in the production and use of forest biomass in Serbia.

Engineering bed models for solid fuel conversion process in grate-fired boilers

DEFF Research Database (Denmark)

Costa, M.; Massarotti, N.; Indrizzi, V.

2014-01-01

of the syngas predicted by the two models is equal to about 7%. The application to different types of biomass shows that the difference in the predictions increases as the carbon content grows. The phenomenological model, in fact, generally considers higher conversion rates of this element to volatiles......A comparison between two numerical models describing the thermo-chemical conversion process of a solid fuel bed in a grate-fired boiler is presented. Both models consider the incoming biomass as subjected to drying, pyrolysis, gasification and combustion. In the first approach the biomass bed...... is treated as a 0D system, where the thermo-chemical processes are divided in two successive sections: drying and conversion. Phenomenological laws are written to characterize the syngas release as a function of the main governing parameters. The second model is an empirical 1D approach. Temperature, species...

Directed plant cell-wall accumulation of iron: embedding co-catalyst for efficient biomass conversion

Science.gov (United States)

Chien-Yuan Lin; Joseph E. Jakes; Bryon S. Donohoe; Peter N. Ciesielski; Haibing Yang; Sophie-Charlotte Gleber; Stefan Vogt; Shi-You Ding; Wendy A. Peer; Angus S. Murphy; Maureen C. McCann; Michael E. Himmel; Melvin P. Tucker; Hui Wei

2016-01-01

Background: Plant lignocellulosic biomass is an abundant, renewable feedstock for the production of biobased fuels and chemicals. Previously, we showed that iron can act as a co-catalyst to improve the deconstruction of lignocellulosic biomass. However, directly adding iron catalysts into biomass prior to pretreatment is diffusion limited,...

Biomass, lasting perspective. Biomassa, een duurzaam perspectief

Energy Technology Data Exchange (ETDEWEB)

Knol, M E [Centrum voor Energiebesparing en Schone Technologie,Delft (Netherlands)

1989-10-01

The contribution of biomass in a possible sustainable energy future of the Netherlands is discussed. The different types of biomass, their properties and their most effective energy conversion techniques are summarized. At this moment the energy potential of the available biomass is 110 PJ per year. Net energy: 45 PJ per year (= 2% of the energy consumption in the Netherlands). Estimated net energy in 2000 is 60 PJ per year. Scenario calculations for the late 21st century reveal potential and net energy amounts of 350 PJ and 280 PJ per year, respectively. 2 refs., 4 tabs., 1 ill.

Environmental implications of increased biomass energy use

Energy Technology Data Exchange (ETDEWEB)

Miles, T.R. Sr.; Miles, T.R. Jr. (Miles (Thomas R.), Portland, OR (United States))

1992-03-01

This study reviews the environmental implications of continued and increased use of biomass for energy to determine what concerns have been and need to be addressed and to establish some guidelines for developing future resources and technologies. Although renewable biomass energy is perceived as environmentally desirable compared with fossil fuels, the environmental impact of increased biomass use needs to be identified and recognized. Industries and utilities evaluating the potential to convert biomass to heat, electricity, and transportation fuels must consider whether the resource is reliable and abundant, and whether biomass production and conversion is environmentally preferred. A broad range of studies and events in the United States were reviewed to assess the inventory of forest, agricultural, and urban biomass fuels; characterize biomass fuel types, their occurrence, and their suitability; describe regulatory and environmental effects on the availability and use of biomass for energy; and identify areas for further study. The following sections address resource, environmental, and policy needs. Several specific actions are recommended for utilities, nonutility power generators, and public agencies.

Performance of a pilot-scale, steam-blown, pressurized fluidized bed biomass gasifier

Science.gov (United States)

Sweeney, Daniel Joseph

With the discovery of vast fossil resources, and the subsequent development of the fossil fuel and petrochemical industry, the role of biomass-based products has declined. However, concerns about the finite and decreasing amount of fossil and mineral resources, in addition to health and climate impacts of fossil resource use, have elevated interest in innovative methods for converting renewable biomass resources into products that fit our modern lifestyle. Thermal conversion through gasification is an appealing method for utilizing biomass due to its operability using a wide variety of feedstocks at a wide range of scales, the product has a variety of uses (e.g., transportation fuel production, electricity production, chemicals synthesis), and in many cases, results in significantly lower greenhouse gas emissions. In spite of the advantages of gasification, several technical hurdles have hindered its commercial development. A number of studies have focused on laboratory-scale and atmospheric biomass gasification. However, few studies have reported on pilot-scale, woody biomass gasification under pressurized conditions. The purpose of this research is an assessment of the performance of a pilot-scale, steam-blown, pressurized fluidized bed biomass gasifier. The 200 kWth fluidized bed gasifier is capable of operation using solid feedstocks at feedrates up to 65 lb/hr, bed temperatures up to 1600°F, and pressures up to 8 atm. Gasifier performance was assessed under various temperatures, pressure, and feedstock (untreated woody biomass, dark and medium torrefied biomass) conditions by measuring product gas yield and composition, residue (e.g., tar and char) production, and mass and energy conversion efficiencies. Elevated temperature and pressure, and feedstock pretreatment were shown to have a significant influence on gasifier operability, tar production, carbon conversion, and process efficiency. High-pressure and temperature gasification of dark torrefied biomass

Energy conversion statics

CERN Document Server

Messerle, H K; Declaris, Nicholas

2013-01-01

Energy Conversion Statics deals with equilibrium situations and processes linking equilibrium states. A development of the basic theory of energy conversion statics and its applications is presented. In the applications the emphasis is on processes involving electrical energy. The text commences by introducing the general concept of energy with a survey of primary and secondary energy forms, their availability, and use. The second chapter presents the basic laws of energy conversion. Four postulates defining the overall range of applicability of the general theory are set out, demonstrating th

Catalytic destruction of tar in biomass derived producer gas

International Nuclear Information System (INIS)

Zhang Ruiqin; Brown, Robert C.; Suby, Andrew; Cummer, Keith

2004-01-01

The purpose of this study is to investigate catalytic destruction of tar formed during gasification of biomass, with the goal of improving the quality of the producer gas. This work focuses on nickel based catalysts treated with alkali in an effort to promote steam gasification of the coke that deposits on catalyst surfaces. A tar conversion system consisting of a guard bed and catalytic reactor was designed to treat the producer gas from an air blown, fluidized bed biomass gasifier. The guard bed used dolomite to crack the heavy tars. The catalytic reactor was used to evaluate three commercial steam reforming catalysts. These were the ICI46-1 catalyst from Imperial Chemical Industry and Z409 and RZ409 catalysts from Qilu Petrochemical Corp. in China. A 0.5-3 l/min slipstream from a 5 tpd biomass gasifier was used to test the tar conversion system. Gas and tar were sampled before and after the tar conversion system to evaluate the effectiveness of the system. Changes in gas composition as functions of catalytic bed temperature, space velocity and steam/TOC (total organic carbon) ratio are presented. Structural changes in the catalysts during the tests are also described

Biomass energy - Definitions, resources and transformation processes

International Nuclear Information System (INIS)

Damien, Alain

2013-01-01

Biomass energy is today considered as a new renewable energy source, and thus, has entered a regulatory framework aiming at encouraging its development for CO 2 pollution abatement. This book addresses the constraints, both natural and technological, of the exploitation of the biomass resource, and then the economical and regulatory aspects of this industry. This second edition provides a complement about the plants used and the new R and D progresses made in this domain. Content: 1 - Definitions and general considerations: natural organic products, regulatory and standardized definitions, energy aspects of biomass fuels; 2 - Resources: energy production dedicated crops, biomass by-products, biomass from wastes; 3 - Biomass to energy transformation processes: combustion, gasification, pyrolysis, torrefaction, methanation, alcoholic fermentation, landfill biogas, Fischer-Tropsch synthesis, methanol synthesis, trans-esterification, synthetic natural gas production, bio-hydrogen production; 4 - Biofuels: solid fuels, solid automotive biofuels, gaseous biofuels, liquid biofuels, comparative efficiency; 5 - Situation of biomass energy: regulations, impact on non-energy purpose biomass, advantages and drawbacks

Fates of Chemical Elements in Biomass during Its Pyrolysis.

Science.gov (United States)

Liu, Wu-Jun; Li, Wen-Wei; Jiang, Hong; Yu, Han-Qing

2017-05-10

Biomass is increasingly perceived as a renewable resource rather than as an organic solid waste today, as it can be converted to various chemicals, biofuels, and solid biochar using modern processes. In the past few years, pyrolysis has attracted growing interest as a promising versatile platform to convert biomass into valuable resources. However, an efficient and selective conversion process is still difficult to be realized due to the complex nature of biomass, which usually makes the products complicated. Furthermore, various contaminants and inorganic elements (e.g., heavy metals, nitrogen, phosphorus, sulfur, and chlorine) embodied in biomass may be transferred into pyrolysis products or released into the environment, arousing environmental pollution concerns. Understanding their behaviors in biomass pyrolysis is essential to optimizing the pyrolysis process for efficient resource recovery and less environmental pollution. However, there is no comprehensive review so far about the fates of chemical elements in biomass during its pyrolysis. Here, we provide a critical review about the fates of main chemical elements (C, H, O, N, P, Cl, S, and metals) in biomass during its pyrolysis. We overview the research advances about the emission, transformation, and distribution of elements in biomass pyrolysis, discuss the present challenges for resource-oriented conversion and pollution abatement, highlight the importance and significance of understanding the fate of elements during pyrolysis, and outlook the future development directions for process control. The review provides useful information for developing sustainable biomass pyrolysis processes with an improved efficiency and selectivity as well as minimized environmental impacts, and encourages more research efforts from the scientific communities of chemistry, the environment, and energy.

Assessment of the status and outlook of biomass energy in Jordan

International Nuclear Information System (INIS)

Al-Hamamre, Zayed; Al-Mater, Ali; Sweis, Fawaz; Rawajfeh, Khaled

2014-01-01

Highlights: • The potential of utilizing biomass as an energy source in Jordan is investigated. • The biomass thermal energy represents 10.2% of the total primary energy. • Bioenergy production depends on biomass availability, conversion and recovery efficiency. - Abstract: This work investigates the status and potential of utilizing biomass as an energy source in Jordan. The amount of waste and residue is estimated to be 6.680 million tons for the year 2011. Two scenarios were investigated: biogas production and thermal treatment. The amount of biogas that can be produced from various biomass sources in Jordan is estimated at 428 MCM. The equivalent annual power production is estimated at 698.1 GW h. This is equivalent to about 5.09% of the consumed electricity (13,535 GW h) and 39.65% of the imported electricity in 2011. The alternative scenario of thermal treatment was investigated. The total theoretical thermal energy that can be obtained assuming 70% conversion efficiency is equivalent to 779 thousand toe (5.33 million barrels of crude oil) which amounts to 10.2% of the total primary energy consumed in 2011. Due to biomass collection and recovery challenges, the energy availability factor varies for the different resources. Hence, contribution of the different biomass resources can significantly vary

Opportunities for Small Biomass Power Systems. Final Technical Report

Energy Technology Data Exchange (ETDEWEB)

Schmidt, D. D.; Pinapati, V. S.

2000-11-15

The purpose of this study was to provide information to key stakeholders and the general public about biomass resource potential for power generation. Ten types of biomass were identified and evaluated. The quantities available for power generation were estimated separately for five U.S. regions and Canada. A method entitled ''competitive resource profile'' was used to rank resources based on economics, utilization, and environmental impact. The results of the analysis may be used to set priorities for utilization of biomass in each U.S. region. A review of current biomass conversion technologies was accomplished, linking technologies to resources.

Spatial Analysis of Depots for Advanced Biomass Processing

Energy Technology Data Exchange (ETDEWEB)

Hilliard, Michael R. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Brandt, Craig C. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Webb, Erin [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Sokhansanj, Shahabaddine [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Eaton, Laurence M. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Martinez Gonzalez, Maria I. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

2014-09-01

The objective of this work was to perform a spatial analysis of the total feedstock cost at the conversion reactor for biomass supplied by a conventional system and an advanced system with depots to densify biomass into pellets. From these cost estimates, the conditions (feedstock cost and availability) for which advanced processing depots make it possible to achieve cost and volume targets can be identified.

Liquid transportation fuels via large-scale fluidised-bed gasification of lignocellulosic biomass

Energy Technology Data Exchange (ETDEWEB)

Hannula, I.; Kurkela, E.

2013-04-15

With the objective of gaining a better understanding of the system design trade-offs and economics that pertain to biomass-to-liquids processes, 20 individual BTL plant designs were evaluated based on their technical and economic performance. The investigation was focused on gasification-based processes that enable the conversion of biomass to methanol, dimethyl ether, Fischer-Tropsch liquids or synthetic gasoline at a large (300 MWth of biomass) scale. The biomass conversion technology was based on pressurised steam/O2-blown fluidised-bed gasification, followed by hot-gas filtration and catalytic conversion of hydrocarbons and tars. This technology has seen extensive development and demonstration activities in Finland during the recent years and newly generated experimental data has also been used in our simulation models. Our study included conceptual design issues, process descriptions, mass and energy balances and production cost estimates. Several studies exist that discuss the overall efficiency and economics of biomass conversion to transportation liquids, but very few studies have presented a detailed comparison between various syntheses using consistent process designs and uniform cost database. In addition, no studies exist that examine and compare BTL plant designs using the same front-end configuration as described in this work. Our analysis shows that it is possible to produce sustainable low-carbon fuels from lignocellulosic biomass with first-law efficiency in the range of 49.6-66.7% depending on the end-product and process conditions. Production cost estimates were calculated assuming Nth plant economics and without public investment support, CO2 credits or tax assumptions. They are 58-65 euro/MWh for methanol, 58-66 euro/MWh for DME, 64-75 euro/MWh for Fischer-Tropsch liquids and 68-78 euro/MWh for synthetic gasoline. (orig.)

Biomass energy systems program summary

Energy Technology Data Exchange (ETDEWEB)

None

1980-07-01

Research programs in biomass which were funded by the US DOE during fiscal year 1978 are listed in this program summary. The conversion technologies and their applications have been grouped into program elements according to the time frame in which they are expected to enter the commercial market. (DMC)

Catalytic conversion of biomass pyrolysis-derived compounds with chemical liquid deposition (CLD) modified ZSM-5.

Science.gov (United States)

Zhang, Huiyan; Luo, Mengmeng; Xiao, Rui; Shao, Shanshan; Jin, Baosheng; Xiao, Guomin; Zhao, Ming; Liang, Junyu

2014-03-01

Chemical liquid deposition (CLD) with KH550, TEOS and methyl silicone oil as the modifiers was used to modify ZSM-5 and deposit its external acid sites. The characteristics of modified catalysts were tested by catalytic conversion of biomass pyrolysis-derived compounds. The effects of different modifying conditions (deposited amount, temperature, and time) on the product yields and selectivities were investigated. The results show KH550 modified ZSM-5 (deposited amount of 4%, temperature of 20°C and time of 6h) produced the maximum yields of aromatics (24.5%) and olefins (16.5%), which are much higher than that obtained with original ZSM-5 catalyst (18.8% aromatics and 9.8% olefins). The coke yield decreased from 44.1% with original ZSM-5 to 26.7% with KH550 modified ZSM-5. The selectivities of low-molecule-weight hydrocarbons (ethylene and benzene) decreased, while that of higher molecule-weight hydrocarbons (propylene, butylene, toluene, and naphthalene) increased comparing with original ZSM-5. Copyright © 2013 Elsevier Ltd. All rights reserved.

Biological Conversion of Sugars to Hydrocarbons Technology Pathway

Energy Technology Data Exchange (ETDEWEB)

Davis, Ryan; Biddy, Mary J.; Tan, Eric; Tao, Ling; Jones, Susanne B.

2013-03-31

In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This technology pathway case investigates the biological conversion of biomass derived sugars to hydrocarbon biofuels, utilizing data from recent literature references and information consistent with recent pilot scale demonstrations at NREL. Technical barriers and key research needs have been identified that should be pursued for the pathway to become competitive with petroleum-derived gasoline, diesel and jet range hydrocarbon blendstocks.

Biomass Energy Data Book: Edition 4

Energy Technology Data Exchange (ETDEWEB)

Boundy, Robert Gary [ORNL; Diegel, Susan W [ORNL; Wright, Lynn L [ORNL; Davis, Stacy Cagle [ORNL

2011-12-01

The Biomass Energy Data Book is a statistical compendium prepared and published by Oak Ridge National Laboratory (ORNL) under contract with the Biomass Program in the Energy Efficiency and Renewable Energy (EERE) program of the Department of Energy (DOE). Designed for use as a convenient reference, the book represents an assembly and display of statistics and information that characterize the biomass industry, from the production of biomass feedstocks to their end use, including discussions on sustainability. This is the fourth edition of the Biomass Energy Data Book which is only available online in electronic format. There are five main sections to this book. The first section is an introduction which provides an overview of biomass resources and consumption. Following the introduction to biomass, is a section on biofuels which covers ethanol, biodiesel and bio-oil. The biopower section focuses on the use of biomass for electrical power generation and heating. The fourth section is on the developing area of biorefineries, and the fifth section covers feedstocks that are produced and used in the biomass industry. The sources used represent the latest available data. There are also two appendices which include frequently needed conversion factors, a table of selected biomass feedstock characteristics, and discussions on sustainability. A glossary of terms and a list of acronyms are also included for the reader's convenience.

Biomass Energy Data Book: Edition 2

Energy Technology Data Exchange (ETDEWEB)

Wright, Lynn L [ORNL; Boundy, Robert Gary [ORNL; Badger, Philip C [ORNL; Perlack, Robert D [ORNL; Davis, Stacy Cagle [ORNL

2009-12-01

The Biomass Energy Data Book is a statistical compendium prepared and published by Oak Ridge National Laboratory (ORNL) under contract with the Biomass Program in the Energy Efficiency and Renewable Energy (EERE) program of the Department of Energy (DOE). Designed for use as a convenient reference, the book represents an assembly and display of statistics and information that characterize the biomass industry, from the production of biomass feedstocks to their end use, including discussions on sustainability. This is the second edition of the Biomass Energy Data Book which is only available online in electronic format. There are five main sections to this book. The first section is an introduction which provides an overview of biomass resources and consumption. Following the introduction to biomass, is a section on biofuels which covers ethanol, biodiesel and bio-oil. The biopower section focuses on the use of biomass for electrical power generation and heating. The fourth section is on the developing area of biorefineries, and the fifth section covers feedstocks that are produced and used in the biomass industry. The sources used represent the latest available data. There are also four appendices which include frequently needed conversion factors, a table of selected biomass feedstock characteristics, assumptions for selected tables and figures, and discussions on sustainability. A glossary of terms and a list of acronyms are also included for the reader's convenience.

Biomass Energy Data Book: Edition 3

Energy Technology Data Exchange (ETDEWEB)

Boundy, Robert Gary [ORNL; Davis, Stacy Cagle [ORNL

2010-12-01

The Biomass Energy Data Book is a statistical compendium prepared and published by Oak Ridge National Laboratory (ORNL) under contract with the Biomass Program in the Energy Efficiency and Renewable Energy (EERE) program of the Department of Energy (DOE). Designed for use as a convenient reference, the book represents an assembly and display of statistics and information that characterize the biomass industry, from the production of biomass feedstocks to their end use, including discussions on sustainability. This is the third edition of the Biomass Energy Data Book which is only available online in electronic format. There are five main sections to this book. The first section is an introduction which provides an overview of biomass resources and consumption. Following the introduction to biomass, is a section on biofuels which covers ethanol, biodiesel and bio-oil. The biopower section focuses on the use of biomass for electrical power generation and heating. The fourth section is on the developing area of biorefineries, and the fifth section covers feedstocks that are produced and used in the biomass industry. The sources used represent the latest available data. There are also four appendices which include frequently needed conversion factors, a table of selected biomass feedstock characteristics, and discussions on sustainability. A glossary of terms and a list of acronyms are also included for the reader's convenience.

Biomass Energy Data Book: Edition 1

Energy Technology Data Exchange (ETDEWEB)

Wright, Lynn L [ORNL; Boundy, Robert Gary [ORNL; Perlack, Robert D [ORNL; Davis, Stacy Cagle [ORNL; Saulsbury, Bo [ORNL

2006-09-01

The Biomass Energy Data Book is a statistical compendium prepared and published by Oak Ridge National Laboratory (ORNL) under contract with the Office of the Biomass Program and the Office of Planning, Budget and Analysis in the Department of Energy's Energy Efficiency and Renewable Energy (EERE) program. Designed for use as a desk-top reference, the book represents an assembly and display of statistics and information that characterize the biomass industry, from the production of biomass feedstocks to their end use. This is the first edition of the Biomass Energy Data Book and is currently only available online in electronic format. There are five main sections to this book. The first section is an introduction which provides an overview of biomass resources and consumption. Following the introduction to biomass is a section on biofuels which covers ethanol, biodiesel and BioOil. The biopower section focuses on the use of biomass for electrical power generation and heating. The fourth section is about the developing area of biorefineries, and the fifth section covers feedstocks that are produced and used in the biomass industry. The sources used represent the latest available data. There are also three appendices which include measures of conversions, biomass characteristics and assumptions for selected tables and figures. A glossary of terms and a list of acronyms are also included for the reader's convenience.

Process Design and Economics for Conversion of Lignocellulosic Biomass to Ethanol: Thermochemical Pathway by Indirect Gasification and Mixed Alcohol Synthesis

Energy Technology Data Exchange (ETDEWEB)

Dutta, A.; Talmadge, M.; Hensley, J.; Worley, M.; Dudgeon, D.; Barton, D.; Groendijk, P.; Ferrari, D.; Stears, B.; Searcy, E. M.; Wright, C. T.; Hess, J. R.

2011-05-01

This design report describes an up-to-date benchmark thermochemical conversion process that incorporates the latest research from NREL and other sources. Building on a design report published in 2007, NREL and its subcontractor Harris Group Inc. performed a complete review of the process design and economic model for a biomass-to-ethanol process via indirect gasification. The conceptual design presented herein considers the economics of ethanol production, assuming the achievement of internal research targets for 2012 and nth-plant costs and financing. The design features a processing capacity of 2,205 U.S. tons (2,000 metric tonnes) of dry biomass per day and an ethanol yield of 83.8 gallons per dry U.S. ton of feedstock. The ethanol selling price corresponding to this design is $2.05 per gallon in 2007 dollars, assuming a 30-year plant life and 40% equity financing with a 10% internal rate of return and the remaining 60% debt financed at 8% interest. This ethanol selling price corresponds to a gasoline equivalent price of $3.11 per gallon based on the relative volumetric energy contents of ethanol and gasoline.

Exergy analysis of thermochemical ethanol production via biomass gasification and catalytic synthesis

NARCIS (Netherlands)

van der Heijden, H.H.J.L.; Ptasinski, K.J.

2012-01-01

In this paper an exergy analysis of thermochemical ethanol production from biomass is presented. This process combines a steam-blown indirect biomass gasification of woody feedstock, with a subsequent conversion of produced syngas into ethanol. The production process involves several process

Switchgrass harvest time management can impact biomass yield and nutrient content

Science.gov (United States)

Switchgrass (Panicum virgatum L.) is a dedicated energy crop native to much of North America. While high-biomass yield is of significant importance for the development of switchgrass as a bioenergy crop, nutrient content in the biomass as it relates to biofuel conversion efficiency is also critical...

Hydropyrolysis of biomass to produce liquid hydrocarbon fuels. Final report. Biomass Alternative-Fuels Program

Energy Technology Data Exchange (ETDEWEB)

Fujita, R K; Bodle, W W; Yuen, P C

1982-10-01

The ojective of the study is to provide a process design and cost estimates for a biomass hydropyrolysis plant and to establish its economic viability for commercial applications. A plant site, size, product slate, and the most probable feedstock or combination of feedstocks were determined. A base case design was made by adapting IGT's HYFLEX process to Hawaiian biomass feedstocks. The HYFLEX process was developed by IGT to produce liquid and/or gaseous fuels from carbonaceous materials. The essence of the process is the simultaneous extraction of valuable oil and gaseous products from cellulosic biomass feedstocks without forming a heavy hard-to-handle tar. By controlling rection time and temperature, the product slate can be varied according to feedstock and market demand. An optimum design and a final assessment of the applicability of the HYFLEX process to the conversion of Hawaiian biomass was made. In order to determine what feedstocks could be available in Hawaii to meet the demands of the proposed hydropyrolysis plant, various biomass sources were studied. These included sugarcane and pineapple wastes, indigenous and cultivated trees and indigenous and cultivated shrubs and grasses.

Engineering Aspergillus oryzae A-4 through the Chromosomal Insertion of Foreign Cellulase Expression Cassette to Improve Conversion of Cellulosic Biomass into Lipids

Science.gov (United States)

Shen, Qi; Ma, Junwei; Fu, Jianrong; Zhao, Yuhua

2014-01-01

A genetic modification scheme was designed for Aspergillus oryzae A-4, a natural cellulosic lipids producer, to enhance its lipid production from biomass by putting the spotlight on improving cellulase secretion. Four cellulase genes were separately expressed in A-4 under the control of hlyA promoter, with the help of the successful development of a chromosomal genetic manipulation system. Comparison of cellulase activities of PCR-positive transformants showed that these transformants integrated with celA gene and with celC gene had significantly (pcellulase gene in A2-2 and D1-B1 was subsequently investigated. It was noted that cellulase expression repressed biomass formation but enhanced lipid accumulation; whereas the inhibitory effect on cell growth would be shielded during cellulosic lipids production owing to the essential role of cellulase in substrate utilization. Different metabolic profiles also existed between A2-2 and D1-B1, which could be attributed to not only different transgene but also biological impacts of different integration. Overall, both simultaneous saccharification and lipid accumulation were enhanced in A2-2 and D1-B1, resulting in efficient conversion of cellulose into lipids. A regulation of cellulase secretion in natural cellulosic lipids producers could be a possible strategy to enhance its lipid production from lignocellulosic biomass. PMID:25251435

Biochemical Conversion: Using Enzymes, Microbes, and Catalysis to Make Fuels and Chemicals

Energy Technology Data Exchange (ETDEWEB)

None

2013-07-26

This fact sheet describes the Bioenergy Technologies Office's biochemical conversion work and processes. BETO conducts collaborative research, development, and demonstration projects to improve several processing routes for the conversion of cellulosic biomass.

Development of an extruder-feeder biomass direct liquefaction process

Energy Technology Data Exchange (ETDEWEB)

White, D.H.; Wolf, D. (Arizona Univ., Tucson, AZ (United States). Dept. of Chemical Engineering)

1991-10-01

As an abundant, renewable, domestic energy resource, biomass could help the United States reduce its dependence on imported oil. Biomass is the only renewable energy technology capable of addressing the national need for liquid transportation fuels. Thus, there is an incentive to develop economic conversion processes for converting biomass, including wood, into liquid fuels. Through research sponsored by the US DOE's Biomass Thermochemical Conversion Program, the University of Arizona has developed a unique biomass direct liquefaction system. The system features a modified single-screw extruder capable of pumping solid slurries containing as high as 60 wt% wood flour in wood oil derived vacuum bottoms at pressures up to 3000 psi. The extruder-feeder has been integrated with a unique reactor by the University to form a system which offers potential for improving high pressure biomass direct liquefaction technology. The extruder-feeder acts simultaneously as both a feed preheater and a pumping device for injecting wood slurries into a high pressure reactor in the biomass liquefaction process. An experimental facility was constructed and following shakedown operations, wood crude oil was produced by mid-1985. By July 1988, a total of 57 experimental continuous biomass liquefaction runs were made using White Birch wood feedstock. Good operability was achieved at slurry feed rates up to 30 lb/hr, reactor pressures from 800 to 3000 psi and temperatures from 350{degree}C to 430{degree}C under conditions covering a range of carbon monoxide feed rates and sodium carbonate catalyst addition. Crude wood oils containing as little as 6--10 wt% residual oxygen were produced. 38 refs., 82 figs., 26 tabs.

Recent trends in ionic liquid (IL) tolerant enzymes and microorganisms for biomass conversion.

Science.gov (United States)

Portillo, Maria Del Carmen; Saadeddin, Anas

2015-01-01

Second generation biofuel production depends on lignocellulosic (LC) biomass transformation into simple sugars and their subsequent fermentation into alcohols. However, the main obstacle in this process is the efficient breakdown of the recalcitrant cellulose to sugar monomers. Hence, efficient feedstock pretreatment and hydrolysis are necessary to produce a cost effective biofuel. Recently, ionic liquids (ILs) have been recognized as a promising solvent able to dissolve different biomass feedstocks, providing higher sugar yields. However, most of the hydrolytic enzymes and microorganisms are inactivated, completely or partially, in the presence of even low concentrations of IL, making necessary the discovery of novel hydrolytic enzymes and fermentative microorganisms that are tolerant to ILs. In this review, the current state and the challenges of using ILs as a pretreatment of LC biomass was evaluated, underlining the advances in the discovery and identification of new IL-tolerant enzymes and microorganisms that could improve the bioprocessing of biomass to fuels and chemicals.

Solid biomass barometer

International Nuclear Information System (INIS)

Anon.

2011-01-01

The primary energy production from solid biomass in the European Union reached 79.3 Mtoe in 2010 which implies a growth rate of 8% between 2009 and 2010. The trend, which was driven deeper by Europe's particularly cold winter of 2009-2010, demonstrates that the economic down-turn failed to weaken the member states' efforts to structure the solid biomass sector. Heat consumption rose sharply: the volume of heat sold by heating networks increased by 18% and reached 6.7 Mtoe and if we consider the total heat consumption (it means with and without recovery via heating networks) the figure is 66 Mtoe in 2010, which amounts to 10.1% growth. The growth of electricity production continued through 2010 (8.3% up on 2009) and rose to 67 TWh but at a slower pace than in 2009 (when it rose by 11.3% on 2008). The situation of the main producer countries: Sweden, Finland, Germany and France is reviewed. It appears that cogeneration unit manufacturers and biomass power plant constructors are the main beneficiaries of the current biomass energy sector boom. There is a trend to replace coal-fired plants that are either obsolete or near their end of life with biomass or multi-fuel plants. These opportunities will enable the industry to develop and further exploit new technologies such as gasification, pyrolysis and torrefaction which will enable biomass to be turned into bio-coal. (A.C.)

Romania biomass energy. Country study

Energy Technology Data Exchange (ETDEWEB)

Burnham, M; Easterly, J L; Mark, P E; Keller, A [DynCorp, Alexandria, VA (United States)

1995-12-01

The present report was prepared under contract to UNIDO to conduct a case study of biomass energy use and potential in Romania. The purpose of the case study is to provide a specific example of biomass energy issues and potential in the context of the economic transition under way in eastern Europe. The transition of Romania to a market economy is proceeding at a somewhat slower pace than in other countries of eastern Europe. Unfortunately, the former regime forced the use of biomass energy with inadequate technology and infrastructure, particularly in rural areas. The resulting poor performance thus severely damaged the reputation of biomass energy in Romania as a viable, reliable resource. Today, efforts to rejuvenate biomass energy and tap into its multiple benefits are proving challenging. Several sound biomass energy development strategies were identified through the case study, on the basis of estimates of availability and current use of biomass resources; suggestions for enhancing potential biomass energy resources; an overview of appropriate conversion technologies and markets for biomass in Romania; and estimates of the economic and environmental impacts of the utilization of biomass energy. Finally, optimal strategies for near-, medium- and long-term biomass energy development, as well as observations and recommendations concerning policy, legislative and institutional issues affecting the development of biomass energy in Romania are presented. The most promising near-term biomass energy options include the use of biomass in district heating systems; cofiring of biomass in existing coal-fired power plants or combined heat and power plants; and using co-generation systems in thriving industries to optimize the efficient use of biomass resources. Mid-term and long-term opportunities include improving the efficiency of wood stoves used for cooking and heating in rural areas; repairing the reputation of biogasification to take advantage of livestock wastes

Romania biomass energy. Country study

International Nuclear Information System (INIS)

Burnham, M.; Easterly, J.L.; Mark, P.E.; Keller, A.

1995-01-01

The present report was prepared under contract to UNIDO to conduct a case study of biomass energy use and potential in Romania. The purpose of the case study is to provide a specific example of biomass energy issues and potential in the context of the economic transition under way in eastern Europe. The transition of Romania to a market economy is proceeding at a somewhat slower pace than in other countries of eastern Europe. Unfortunately, the former regime forced the use of biomass energy with inadequate technology and infrastructure, particularly in rural areas. The resulting poor performance thus severely damaged the reputation of biomass energy in Romania as a viable, reliable resource. Today, efforts to rejuvenate biomass energy and tap into its multiple benefits are proving challenging. Several sound biomass energy development strategies were identified through the case study, on the basis of estimates of availability and current use of biomass resources; suggestions for enhancing potential biomass energy resources; an overview of appropriate conversion technologies and markets for biomass in Romania; and estimates of the economic and environmental impacts of the utilization of biomass energy. Finally, optimal strategies for near-, medium- and long-term biomass energy development, as well as observations and recommendations concerning policy, legislative and institutional issues affecting the development of biomass energy in Romania are presented. The most promising near-term biomass energy options include the use of biomass in district heating systems; cofiring of biomass in existing coal-fired power plants or combined heat and power plants; and using co-generation systems in thriving industries to optimize the efficient use of biomass resources. Mid-term and long-term opportunities include improving the efficiency of wood stoves used for cooking and heating in rural areas; repairing the reputation of biogasification to take advantage of livestock wastes

Direct hydrodeoxygenation of raw woody biomass into liquid alkanes.

Science.gov (United States)

Xia, Qineng; Chen, Zongjia; Shao, Yi; Gong, Xueqing; Wang, Haifeng; Liu, Xiaohui; Parker, Stewart F; Han, Xue; Yang, Sihai; Wang, Yanqin

2016-03-30

Being the only sustainable source of organic carbon, biomass is playing an ever-increasingly important role in our energy landscape. The conversion of renewable lignocellulosic biomass into liquid fuels is particularly attractive but extremely challenging due to the inertness and complexity of lignocellulose. Here we describe the direct hydrodeoxygenation of raw woods into liquid alkanes with mass yields up to 28.1 wt% over a multifunctional Pt/NbOPO4 catalyst in cyclohexane. The superior performance of this catalyst allows simultaneous conversion of cellulose, hemicellulose and, more significantly, lignin fractions in the wood sawdust into hexane, pentane and alkylcyclohexanes, respectively. Investigation on the molecular mechanism reveals that a synergistic effect between Pt, NbOx species and acidic sites promotes this highly efficient hydrodeoxygenation of bulk lignocellulose. No chemical pretreatment of the raw woody biomass or separation is required for this one-pot process, which opens a general and energy-efficient route for converting raw lignocellulose into valuable alkanes.

Identifying the point of departures for the detailed sustainability assessment of biomass feedstocks for biorefinery

DEFF Research Database (Denmark)

Parajuli, Ranjan; Knudsen, Marie Trydeman; Dalgaard, Tommy

for biorefineries and potential impacts to the existing market. This study aims to assist in the sustainability assessment of straw conversion in the biochemical conversion routes to deliver bioethanol and other biobased products. For the comparison, conversion of straw to produce heat and electricity in a Combined......In the light of sustainable development in the energy sector, biomasses have gained increasing attention, which have exacerbated competition among them. Biorefineries are increasing its hold in developed economies, since it facilitates the delivery of multiple products including food, feed...... and fuels. Lignocelluloses (e.g straw) are one of the important biomasses considered in such transition. Meanwhile, it is also relevant to examine how the current utilization of biomasses are taking place and the related environmental and economic burdens. This also allows to compare the sustainability...

2009 Biochemical Conversion Platform Review Report

Energy Technology Data Exchange (ETDEWEB)

Ferrell, John [Office of Energy Efficiency and Renewable Energy (EERE), Washington, DC (United States)

2009-12-01

This document summarizes the recommendations and evaluations provided by an independent external panel of experts at the U.S. Department of Energy Biomass Program’s Biochemical Conversion platform review meeting, held on April 14-16, 2009, at the Sheraton Denver Downtown, Denver, Colorado.

2009 Thermochemical Conversion Platform Review Report

Energy Technology Data Exchange (ETDEWEB)

Ferrell, John [Office of Energy Efficiency and Renewable Energy (EERE), Washington, DC (United States)

2009-12-01

This document summarizes the recommendations and evaluations provided by an independent external panel of experts at the U.S. Department of Energy Biomass Program’s Thermochemical Conversion platform review meeting, held on April 14-16, 2009, at the Sheraton Denver Downtown, Denver, Colorado.

Biomass boiler energy conversion system analysis with the aid of exergy-based methods

International Nuclear Information System (INIS)

Li, Changchun; Gillum, Craig; Toupin, Kevin; Donaldson, Burl

2015-01-01

Highlights: • Conventional exergy analysis and advanced exergy analysis are performed. • The combustion process dominates the exergy destruction. • Increase excess air will decrease the overall boiler exergy efficiency. • Increase the SH temperatures will increase the overall boiler exergy efficiency. • The avoidable exergy destructions in the air heaters are very small. - Abstract: The objective of this paper is to establish a theoretical framework for the exergy analysis and advanced exergy analysis of a real biomass boiler. These analyses can be used for both the diagnosis and optimization of a biomass boiler as well as for the design of a new biomass boiler. Conventional exergy analysis is performed to recognize the source(s) of inefficiency and irreversibility and identify exergy destruction in different components of the biomass boiler. An advanced exergy analysis is performed to provide comprehensive information about the avoidable exergy destruction and real fuel-saving potential for each component, as well as the overall system. Sensitivity studies of several design parameters including the excess air, biomass moisture and steam parameters were evaluated. The results show that the maximum exergy destruction occurs in the combustion process, followed by the Water Walls (WW) & Radiant Superheater (RSH) and the Low Temperature Superheater (LTSH). The fuel-saving and exergy efficiency improvement strategies for different components are discussed in this paper

Electricity from biomass within reach. Elektriciteit uit biomassa binnen handbereik

Energy Technology Data Exchange (ETDEWEB)

Beenackers, A A.C.M. [Univ. Groningen (Netherlands)

1992-11-01

A state of the art is given of the developments in gasifiers and conversion techniques for biomass. Also attention is paid to the production costs of flue gas and electric power from biomass, and the production costs of the transportation fuels bio-ethanol and rapeseed oil, compared with the cost prices of refinery fuels. 2 figs., 3 tabs.

The economics of biomass energy: a case study from Hawaii

International Nuclear Information System (INIS)

Gopalakrishnan, Chennat; Gadepalli, K.S.; Cox, L.J.; Pingsun Leung

1993-01-01

The thesis that the cost-effective conversion of Hawaii's biomass sources to electricity can be best accomplished by a central power plant is developed and empirically tested using a multiperiod linear programming model. The results also suggest that it is cheaper to produce electric power from a biomass-fueld plant than from a fuel oil-based facility. (author)

Experimental comparison of biomass chars with other catalysts for tar reduction

NARCIS (Netherlands)

Abu El-Rub, Ziad; Bramer, Eduard A.; Brem, Gerrit

2008-01-01

In this paper the potential of using biomass char as a catalyst for tar reduction is discussed. Biomass char is compared with other known catalysts used for tar conversion. Model tar compounds, phenol and naphthalene, were used to test char and other catalysts. Tests were carried out in a fixed bed

Biomass furnace: projection and construction

Energy Technology Data Exchange (ETDEWEB)

Melo, Fernanda Augusta de Oliveira; Silva, Juarez Sousa e; Silva, Denise de Freitas; Sampaio, Cristiane Pires; Nascimento Junior, Jose Henrique do [Universidade Federal de Vicosa (DEA/UFV), MG (Brazil). Dept. de Engenharia Agricola

2008-07-01

Of all the ways to convert biomass into thermal energy, direct combustion is the oldest. The thermal-chemical technologies of biomass conversion such as pyrolysis and gasification, are currently not the most important alternatives; combustion is responsible for 97% of the bio-energy produced in the world (Demirbas, 2003). For this work, a small furnace was designed and constructed to use biomass as its main source of fuel, and the combustion chamber was coupled with a helical transporter which linked to the secondary fuel reservoir to continually feed the combustion chamber with fine particles of agro-industrial residues. The design of the stove proved to be technically viable beginning with the balance of mass and energy for the air heating system. The proposed heat generator was easily constructed as it made use of simple and easily acquired materials, demanding no specialized labor. (author)

Factors Influencing the Ignition and Burnout of a Single Biomass Particle

DEFF Research Database (Denmark)

Momenikouchaksaraei, Maryam; Kær, Søren Knudsen; Yin, Chungen

2011-01-01

Ignition and burnout of a single biomass particle were studied numerically. A one-dimensional particle combustion model was developed which is capable to simulate all the intraparticle conversion processes (drying, recondensation, devolatilization, char gasification/oxidation and heat/mass/moment......Ignition and burnout of a single biomass particle were studied numerically. A one-dimensional particle combustion model was developed which is capable to simulate all the intraparticle conversion processes (drying, recondensation, devolatilization, char gasification/oxidation and heat...... concentration were not very significant. The influences of these factors on particle burnout were much more remarkable than ignition behaviour....

Siting Evaluation for Biomass-Ethanol Production in Hawaii

Energy Technology Data Exchange (ETDEWEB)

Kinoshita, C.M.; Zhou, J.

2000-10-15

This report examines four Hawaiian islands, Oahu, Hawaii, Maui, and Kauai, to identify three best combinations of potential sites and crops for producing dedicated supplies of biomass for conversion to ethanol. Key technical and economic factors considered in the siting evaluation include land availability (zoning and use), land suitability (agronomic conditions), potential quantities and costs of producing biomass feedstocks, infrastructure (including water and power supplies), transportation, and potential bioresidues to supplement dedicated energy crops.

Biomass Biorefinery for the production of Polymers and Fuels

Energy Technology Data Exchange (ETDEWEB)

Dr. Oliver P. Peoples

2008-05-05

The conversion of biomass crops to fuel is receiving considerable attention as a means to reduce our dependence on foreign oil imports and to meet future energy needs. Besides their use for fuel, biomass crops are an attractive vehicle for producing value added products such as biopolymers. Metabolix, Inc. of Cambridge proposes to develop methods for producing biodegradable polymers polyhydroxyalkanoates (PHAs) in green tissue plants as well as utilizating residual plant biomass after polymer extraction for fuel generation to offset the energy required for polymer extraction. The primary plant target is switchgrass, and backup targets are alfalfa and tobacco. The combined polymer and fuel production from the transgenic biomass crops establishes a biorefinery that has the potential to reduce the nation’s dependence on foreign oil imports for both the feedstocks and energy needed for plastic production. Concerns about the widespread use of transgenic crops and the grower’s ability to prevent the contamination of the surrounding environment with foreign genes will be addressed by incorporating and expanding on some of the latest plant biotechnology developed by the project partners of this proposal. This proposal also addresses extraction of PHAs from biomass, modification of PHAs so that they have suitable properties for large volume polymer applications, processing of the PHAs using conversion processes now practiced at large scale (e.g., to film, fiber, and molded parts), conversion of PHA polymers to chemical building blocks, and demonstration of the usefulness of PHAs in large volume applications. The biodegradability of PHAs can also help to reduce solid waste in our landfills. If successful, this program will reduce U.S. dependence on imported oil, as well as contribute jobs and revenue to the agricultural economy and reduce the overall emissions of carbon to the atmosphere.

Biomass production and nitrogen dynamics in an integrated aquaculture/agriculture system

Science.gov (United States)

Owens, L. P.; Hall, C. R.

1990-01-01

A combined aquaculture/agriculture system that brings together the three major components of a Controlled Ecological Life Support System (CELSS) - biomass production, biomass processing, and waste recycling - was developed to evaluate ecological processes and hardware requirements necessary to assess the feasibility of and define design criteria for integration into the Kennedy Space Center (KSC) Breadboard Project. The system consists of a 1 square meter plant growth area, a 500 liter fish culture tank, and computerized monitoring and control hardware. Nutrients in the hydrophonic solution were derived from fish metabolites and fish food leachate. In five months of continuous operation, 27.0 kg of lettuce tops, 39.9 kg of roots and biofilm, and 6.6 kg of fish (wet weights) were produced with 12.7 kg of fish food input. Based on dry weights, a biomass conversion index of 0.52 was achieved. A nitrogen budget was derived to determine partitioning of nitrogen within various compartments of the system. Accumulating nitrogen in the hypoponic solution indicated a need to enlarge the plant growth area, potentially increasing the biomass production and improving the biomass conversion index.

The biomass like renewable energy in the future

International Nuclear Information System (INIS)

Perez Peces, J.

1993-01-01

The energetic contribution of biomass in EC and world figures represents a 14% of the whole demand. For developing countries this figure goes up to 35% and can be a source of employment for manpower decreasing in other sectors. At European level the CEC are promoting research areas through JOULE and LEBEN programs. Current European policy with big subsidies for intensive agricultural production has penalized forest and biomass production. Reforestation and biomass energetics crops are going to be a new strategy with 20 million Ha of agricultural soil transformed and between 10 and 20 million ha of marginal soil transformed. Biomass will be promoted keeping in mind environmental benefits like compost production for soil conditioning. A review of the different biomass sources and treatment techniques (bioconversion, thermal conversion and biodigestion), as well as environmental aspects are given

Production of hydrogen from biomass by catalytic steam reforming of fast pyrolysis oil

Energy Technology Data Exchange (ETDEWEB)

Czernik, S.; Wang, D.; Chornet, E. [National Renewable Energy Lab., Golden, CO (United States). Center for Renewable Chemical Technologies and Materials

1998-08-01

Hydrogen is the prototype of the environmentally cleanest fuel of interest for power generation using fuel cells and for transportation. The thermochemical conversion of biomass to hydrogen can be carried out through two distinct strategies: (a) gasification followed by water-gas shift conversion, and (b) catalytic steam reforming of specific fractions derived from fast pyrolysis and aqueous/steam processes of biomass. This paper presents the latter route that begins with fast pyrolysis of biomass to produce bio-oil. This oil (as a whole or its selected fractions) can be converted to hydrogen via catalytic steam reforming followed by a water-gas shift conversion step. Such a process has been demonstrated at the bench scale using model compounds, poplar oil aqueous fraction, and the whole pyrolysis oil with commercial Ni-based steam reforming catalysts. Hydrogen yields as high as 85% have been obtained. Catalyst initial activity can be recovered through regeneration cycles by steam or CO{sub 2} gasification of carbonaceous deposits.

A kinetic study on the conversion of glucose to levulinic acid

NARCIS (Netherlands)

Girisuta, B; Janssen, LPBM; Heeres, HJ

Levulinic acid has been identified as a promising green. biomass derived platform chemical. A kinetic study oil one of the key steps in the conversion of biomass to levulinic acid, i.e., the acid catalysed decomposition of glucose to levulinic acid has been performed. The experiments were Performed

The biomass valorization / the electric power in processes: innovation and challenges; valorisation de la biomasse / l'electricite dans les procedes: innovation et defis

Energy Technology Data Exchange (ETDEWEB)

Dahy, M [Agence de l' Environnement et de la Maitrise de l' Energie, ADEME, 75 - Paris (France); Leclercq, M [Ministere de l' Industrie, des Postes et Telecommunications et du Commerce Exterieur, 75 - Paris (France). Direction Generale de L' Energie et des Matieres Premieres; Gosse, G [Institut National de Recherches Agronomiques (INRA), 75 - Paris (France); Lacour, P A [AFOCEL, 34 - St Clement de Riviere (France); Ballerini, D; Duplan, J L; Monot, F [Institut Francais du Petrole (IFP), 69 - Lyon (France); Seiler, J M [CEA Grenoble, 38 (France); Ancelme, A [Syndicat National des Producteurs d' Alcools Agricoles (SNPAA), 92 - Neuilly (France); Vermeersch, G [Sofiproteol, 75 - Paris (France); Hervouet, V [Total, La Defense, 92 - Courbevoie (France); Rouveirolles, P [Renault, 92 6 Boulogne Billancourt (France); Bellot, M [Electricite de France (EDF), 75 - Paris (France); Pascual, C [ELYO Cylergie, 69 - Ecully (France); Girard, M [PRONOVIAL, 51 - Reims (France); Bernard, D [ARKEMA, 69 - Lyon (France); Dussaud, J; Vrevin, L [Ahlstrom Research and Services, Edinburgh, Midlothian (United Kingdom); Mentink, L [Roquette Freres (Italy)

2005-07-01

In a context of an insufficient offer on processes/technology, this day is devoted to the processes adapted to the biomass conversion in energy, fuels and other products. It provides presentations on the biomass economy and regulations, the different channels, the thermochemical processes to produce synthetic fuels and hydrogen, the ethanol production, refiners, automotive industry, an electric power, producer point of view, the byproducts. (A.L.B.)

Conversing as Metaphor of Human Thinking: Is Mind like a Conversation?

Science.gov (United States)

Sorsana, Christine; Trognon, Alain

2018-06-01

How can researchers shape their ideas so that they understand the mind better? This theoretical paper discusses the merits of the conversation metaphor as a means of analyzing the human mind. We will develop arguments concerning conversation as i) a situated and distributed activity, ii) a "product" in perpetual construction, and iii) the amount of credence and belief we afford it. Finally, we will advocate for metaphorical tools that promote a more dynamic conceptualization of human thinking.

Biomass utilisation for combined heat and power generation: Status and perspectives for rural regions. Guelzow expert discussions; Energetische Nutzung von Biomasse mit Kraft-Waerme-Kopplung: Stand der Technik und Perspektiven fuer den laendlichen Raum. Guelzower Fachgespraeche

Energy Technology Data Exchange (ETDEWEB)

NONE

2000-07-01

Biomass has a high potential but biomass utilisation technologies have not yet reached sufficient maturity for a general breakthrough on the market. Political boundary conditions alone are not sufficient if technical conversion processes are neglected. For the time being, the potential of biomass can not be utilised.

A review of conversion processes for bioethanol production with a focus on syngas fermentation

Directory of Open Access Journals (Sweden)

Mamatha Devarapalli

2015-09-01

Full Text Available Bioethanol production from corn is a well-established technology. However, emphasis on exploring non-food based feedstocks is intensified due to dispute over utilization of food based feedstocks to generate bioethanol. Chemical and biological conversion technologies for non-food based biomass feedstocks to biofuels have been developed. First generation bioethanol was produced from sugar based feedstocks such as corn and sugar cane. Availability of alternative feedstocks such as lignocellulosic and algal biomass and technology advancement led to the development of complex biological conversion processes, such as separate hydrolysis and fermentation (SHF, simultaneous saccharification and fermentation (SSF, simultaneous saccharification and co-fermentation (SSCF, consolidated bioprocessing (CBP, and syngas fermentation. SHF, SSF, SSCF, and CBP are direct fermentation processes in which biomass feedstocks are pretreated, hydrolyzed and then fermented into ethanol. Conversely, ethanol from syngas fermentation is an indirect fermentation that utilizes gaseous substrates (mixture of CO, CO2 and H2 made from industrial flue gases or gasification of biomass, coal or municipal solid waste. This review article provides an overview of the various biological processes for ethanol production from sugar, lignocellulosic, and algal biomass. This paper also provides a detailed insight on process development, bioreactor design, and advances and future directions in syngas fermentation.

IEA Bioenergy Task 42 - Countries report. IEA Bioenergy Task 42 on biorefineries: Co-production of fuels, chemicals, power and materials from biomass. Final report

Energy Technology Data Exchange (ETDEWEB)

Cherubini, F.; Jungmeier, G.; Mandl, M. (Joanneum Research, Graz (Austria)) (and others)

2010-07-01

This report has been developed by the members of IEA Bioenergy Task 42 on Biorefinery: Co-production of Fuels, Chemicals, Power and Materials from Biomass (www.biorefinery.nl/ieabioenergy-task42). IEA Bioenergy is a collaborative network under the auspices of the International Energy Agency (IEA) to improve international cooperation and information exchange between national bioenergy RD and D programs. IEA Bioenergy Task 42 on Biorefinery covers a new and very broad biomass-related field, with a very large application potential, and deals with a variety of market sectors with many interested stakeholders, a large number of biomass conversion technologies, and integrated concepts of both biochemical and thermochemical processes. This report contains an overview of the biomass, bioenergy and biorefinery situation, and activities, in the Task 42 member countries: Austria, Canada, Denmark, France, Germany, Ireland, and the Netherlands. The overview includes: national bioenergy production, non-energetic biomass use, bioenergy related policy goals, national oil refineries, biofuels capacity for transport purposes, existing biorefinery industries, pilot and demo plants, and other activities of research and development (such as main national projects and stakeholders). Data are provided by National Task Leaders (NTLs), whose contact details are listed at the end of the report. (author)

Lignin-blocking treatment of biomass and uses thereof

Science.gov (United States)

Yang, Bin [Hanover, NH; Wyman, Charles E [Norwich, VT

2009-10-20

Disclosed is a method for converting cellulose in a lignocellulosic biomass. The method provides for a lignin-blocking polypeptide and/or protein treatment of high lignin solids. The treatment enhances cellulase availability in cellulose conversion. Cellulase efficiencies are improved by the protein or polypeptide treatment. The treatment may be used in combination with steam explosion and acid prehydrolysis techniques. Hydrolysis yields from lignin containing biomass are enhanced 5-20%, and enzyme utilization is increased from 10% to 50%. Thus, a more efficient and economical method of processing lignin containing biomass materials utilizes a polypeptide/protein treatment step that effectively blocks lignin binding of cellulase.

Algal Energy Conversion and Capture

Science.gov (United States)

Hazendonk, P.

2015-12-01

We address the potential for energy conversions and capture for: energy generation; reduction in energy use; reduction in greenhouse gas emissions; remediation of water and air pollution; protection and enhancement of soil fertility. These processes have the potential to sequester carbon at scales that may have global impact. Energy conversion and capture strategies evaluate energy use and production from agriculture, urban areas and industries, and apply existing and emerging technologies to reduce and recapture energy embedded in waste products. The basis of biocrude production from Micro-algal feedstocks: 1) The nutrients from the liquid fraction of waste streams are concentrated and fed into photo bioreactors (essentially large vessels in which microalgae are grown) along with CO2 from flue gasses from down stream processes. 2) The algae are processed to remove high value products such as proteins and beta-carotenes. The advantage of algae feedstocks is the high biomass productivity is 30-50 times that of land based crops and the remaining biomass contains minimal components that are difficult to convert to biocrude. 3) The remaining biomass undergoes hydrothermal liquefaction to produces biocrude and biochar. The flue gasses of this process can be used to produce electricity (fuel cell) and subsequently fed back into the photobioreactor. The thermal energy required for this process is small, hence readily obtained from solar-thermal sources, and furthermore no drying or preprocessing is required keeping the energy overhead extremely small. 4) The biocrude can be upgraded and refined as conventional crude oil, creating a range of liquid fuels. In principle this process can be applied on the farm scale to the municipal scale. Overall, our primary food production is too dependent on fossil fuels. Energy conversion and capture can make food production sustainable.

The biomass valorization / the electric power in processes: innovation and challenges; valorisation de la biomasse / l'electricite dans les procedes: innovation et defis

Energy Technology Data Exchange (ETDEWEB)

Dahy, M. [Agence de l' Environnement et de la Maitrise de l' Energie, ADEME, 75 - Paris (France); Leclercq, M. [Ministere de l' Industrie, des Postes et Telecommunications et du Commerce Exterieur, 75 - Paris (France). Direction Generale de L' Energie et des Matieres Premieres; Gosse, G. [Institut National de Recherches Agronomiques (INRA), 75 - Paris (France); Lacour, P.A. [AFOCEL, 34 - St Clement de Riviere (France); Ballerini, D.; Duplan, J.L.; Monot, F. [Institut Francais du Petrole (IFP), 69 - Lyon (France); Seiler, J.M. [CEA Grenoble, 38 (France); Ancelme, A. [Syndicat National des Producteurs d' Alcools Agricoles (SNPAA), 92 - Neuilly (France); Vermeersch, G. [Sofiproteol, 75 - Paris (France); Hervouet, V. [Total, La Defense, 92 - Courbevoie (France); Rouveirolles, P. [Renault, 92 6 Boulogne Billancourt (France); Bellot, M. [Electricite de France (EDF), 75 - Paris (France); Pascual, C. [ELYO Cylergie, 69 - Ecully (France); Girard, M. [PRONOVIAL, 51 - Reims (France); Bernard, D. [ARKEMA, 69 - Lyon (France); Dussaud, J.; Vrevin, L. [Ahlstrom Research and Services, Edinburgh, Midlothian (United Kingdom); Mentink, L. [Roquette Freres (Italy)

2005-07-01

In a context of an insufficient offer on processes/technology, this day is devoted to the processes adapted to the biomass conversion in energy, fuels and other products. It provides presentations on the biomass economy and regulations, the different channels, the thermochemical processes to produce synthetic fuels and hydrogen, the ethanol production, refiners, automotive industry, an electric power, producer point of view, the byproducts. (A.L.B.)

Other Polyesters from Biomass Derived Monomers

NARCIS (Netherlands)

Es, van D.S.; Klis, van der F.; Knoop, J.R.I.; Molenveld, K.; Sijtsma, L.; Haveren, van J.

2013-01-01

In the transition from a fossil-based to a bio-based economy the introduction of bio-based chemicals can be achieved via two distinctly different approaches. The first approach is based on the conversion of bio-mass into existing (petro)chemicals; the ‘drop-in’ approach. The main benefit of this

Biomass - Activities and projects in 2002; Biomasse Aktivitaeten und Projekte 2002. Ueberblicksbericht zum Forschungsprogramm 2002

Energy Technology Data Exchange (ETDEWEB)

Binggeli, D.; Guggisberg, B.

2003-07-01

This annual report made for the Swiss Federal Office of Energy reviews the activities carried out under the Biomass Research Programme in 2002 and describes the various projects that were active during the year. The situation concerning energy supply from biomass is discussed and figures are presented on its share in total Swiss energy consumption. Three categories of biomass use are presented - burning, fermentation of wastes and biofuels. >From each of these categories, several pilot and demonstration projects are described that cover a wide range of technologies and research activities, ranging from the pre-processing of biogenic wastes through to the optimisation of biogas-based combined heat and power installations and the operational economics of compact biogas installations. The report is completed with lists of research and development projects and pilot and demonstration projects.

Biomass gasification : The understanding of sulfur, tar, and char reaction in fluidized bed gasifiers

NARCIS (Netherlands)

Meng, X.

2012-01-01

As one of the currently available thermo-chemical conversion technologies, biomass gasification has received considerable interest since it increases options for combining with various power generation systems. The product gas or syngas produced from biomass gasification is environmental friendly

Guideline for safe and eco-friendly biomass gasification

Energy Technology Data Exchange (ETDEWEB)

Vos, J.; Knoef, H. (BTG biomass technology group, Enschede (Netherlands)); Hauth, M. (Graz Univ. of Technology. Institute of Thermal Engineering, Graz (Austria)) (and others)

2009-11-15

The objective of the Gasification Guide project is to accelerate the market penetration of small-scale biomass gasification systems (< 5 MW fuel power) by the development of a Guideline and Software Tool to facilitate risk assessment of HSE aspects. The Guideline may also be applied in retrofitting or converting old thermal plants in the Eastern European countries - with rich biomass recourses - to new gasification plants. The objective of this document is to guide key target groups identifying potential hazards and make a proper risk assessment. The software tool is an additional aid in the risk assessment. This guideline is intended to be a training tool and a resource for workers and employers to safely design, fabricate, construct, operate and maintain small-scale biomass gasification facilities. The Guideline is applicable with the following constraints: 1) The maximum scale of the gasification plant was agreed to be about 1 MW{sub e}. The reason is that large companies do have normally their safety rules in place; 2) This means in principle only fixed bed gasifier designs. However, most parts are also valid to other designs and even other thermal conversion processes; 3) The use of contaminated biomass is beyond the scope of this Guideline. The Guideline contains five major chapters; Chapter 2 briefly describes the gasification technology in general. Chapter 3 gives an overview of major legal framework issues on plant permission and operation. The legal frame is changing and the description is based on the situation by the end of 2007. Chapter 4 explains the theory behind the risk assessment method and risk reduction measures. Chapter 5 is the heart of the Guideline and gives practical examples of good design, operation and maintenance principles. The practical examples and feedback have been received throughout the project and the description is based on mid-2009. Chapter 6 describes the best techniques currently available for emission abatement which are

Renewable energy potential from biomass residues in Egypt

Energy Technology Data Exchange (ETDEWEB)

Said, N.; Zamorano, M. [Civil Engineering Dept., Univ. of Granada, Campus de Fuentenueva, Granada (Spain); El-Shatoury, S.A. [Botany Dept., Faculty of Sciences, Suez Canal Univ., Ismailia (Egypt)

2012-11-01

Egypt has been one of the developing countries following successful programs for the development of renewable energy resources, with special emphasis on solar, wind and biomass. Utilization of biomass as a source of energy is important from energetic as well as environmental viewpoint. Furthermore, Egypt produces millions of biomass waste every year causing pollution and health problems. So, the incorporation of biomass with other renewable energy will increase the impact of solving energy and environmental problem. There is a good potential for the utilization of biomass energy resources in Egypt. Four main types of biomass energy sources are included in this study: agricultural residues, municipal solid wastes, animal wastes and sewage sludge. Analysis of the potential biomass resource quantity and its theoretical energy content has been computed according to literature review. The agriculture crop residue represents the main source of biomass waste with a high considerable amount of the theoretical potential energy in Egypt. Rice straw is considered one of the most important of such residue due to its high amount and its produced energy through different conversion techniques represent a suitable candidate for crop energy production in Egypt.

Picoheterotroph (Bacteria and Archaea biomass distribution in the global ocean

Directory of Open Access Journals (Sweden)

M. R. Landry

2012-09-01

Full Text Available We compiled a database of 39 766 data points consisting of flow cytometric and microscopical measurements of picoheterotroph abundance, including both Bacteria and Archaea. After gridding with 1° spacing, the database covers 1.3% of the ocean surface. There are data covering all ocean basins and depths except the Southern Hemisphere below 350 m or from April until June. The average picoheterotroph biomass is 3.9 ± 3.6 μg C l−1 with a 20-fold decrease between the surface and the deep sea. We estimate a total ocean inventory of about 1.3 × 1029 picoheterotroph cells. Surprisingly, the abundance in the coastal regions is the same as at the same depths in the open ocean. Using an average of published open ocean measurements for the conversion from abundance to carbon biomass of 9.1 fg cell−1, we calculate a picoheterotroph carbon inventory of about 1.2 Pg C. The main source of uncertainty in this inventory is the conversion factor from abundance to biomass. Picoheterotroph biomass is ~2 times higher in the tropics than in the polar oceans. doi:10.1594/PANGAEA.779142

Comparative techno-economic analysis and process design for indirect liquefaction pathways to distillate-range fuels via biomass-derived oxygenated intermediates upgrading: Liquid Transportation Fuel Production via Biomass-derived Oxygenated Intermediates Upgrading

Energy Technology Data Exchange (ETDEWEB)

Tan, Eric C. D. [National Renewable Energy Laboratory, Golden CO USA; Snowden-Swan, Lesley J. [Pacific Northwest National Laboratory, Richland WA USA; Talmadge, Michael [National Renewable Energy Laboratory, Golden CO USA; Dutta, Abhijit [National Renewable Energy Laboratory, Golden CO USA; Jones, Susanne [Pacific Northwest National Laboratory, Richland WA USA; Ramasamy, Karthikeyan K. [Pacific Northwest National Laboratory, Richland WA USA; Gray, Michel [Pacific Northwest National Laboratory, Richland WA USA; Dagle, Robert [Pacific Northwest National Laboratory, Richland WA USA; Padmaperuma, Asanga [Pacific Northwest National Laboratory, Richland WA USA; Gerber, Mark [Pacific Northwest National Laboratory, Richland WA USA; Sahir, Asad H. [National Renewable Energy Laboratory, Golden CO USA; Tao, Ling [National Renewable Energy Laboratory, Golden CO USA; Zhang, Yanan [National Renewable Energy Laboratory, Golden CO USA

2016-09-27

This paper presents a comparative techno-economic analysis (TEA) of five conversion pathways from biomass to gasoline-, jet-, and diesel-range hydrocarbons via indirect liquefaction with specific focus on pathways utilizing oxygenated intermediates. The four emerging pathways of interest are compared with one conventional pathway (Fischer-Tropsch) for the production of the hydrocarbon blendstocks. The processing steps of the four emerging pathways include: biomass to syngas via indirect gasification, gas cleanup, conversion of syngas to alcohols/oxygenates followed by conversion of alcohols/oxygenates to hydrocarbon blendstocks via dehydration, oligomerization, and hydrogenation. Conversion of biomass-derived syngas to oxygenated intermediates occurs via three different pathways, producing: 1) mixed alcohols over a MoS2 catalyst, 2) mixed oxygenates (a mixture of C2+ oxygenated compounds, predominantly ethanol, acetic acid, acetaldehyde, ethyl acetate) using an Rh-based catalyst, and 3) ethanol from syngas fermentation. This is followed by the conversion of oxygenates/alcohols to fuel-range olefins in two approaches: 1) mixed alcohols/ethanol to 1-butanol rich mixture via Guerbet reaction, followed by alcohol dehydration, oligomerization, and hydrogenation, and 2) mixed oxygenates/ethanol to isobutene rich mixture and followed by oligomerization and hydrogenation. The design features a processing capacity of 2,000 tonnes/day (2,205 short tons) of dry biomass. The minimum fuel selling prices (MFSPs) for the four developing pathways range from $3.40 to $5.04 per gasoline-gallon equivalent (GGE), in 2011 US dollars. Sensitivity studies show that MFSPs can be improved with co-product credits and are comparable to the commercial Fischer-Tropsch benchmark ($3.58/GGE). Overall, this comparative TEA study documents potential economics for the developmental biofuel pathways via mixed oxygenates.

A sustainable woody biomass biorefinery.

Science.gov (United States)

Liu, Shijie; Lu, Houfang; Hu, Ruofei; Shupe, Alan; Lin, Lu; Liang, Bin

2012-01-01

Woody biomass is renewable only if sustainable production is imposed. An optimum and sustainable biomass stand production rate is found to be one with the incremental growth rate at harvest equal to the average overall growth rate. Utilization of woody biomass leads to a sustainable economy. Woody biomass is comprised of at least four components: extractives, hemicellulose, lignin and cellulose. While extractives and hemicellulose are least resistant to chemical and thermal degradation, cellulose is most resistant to chemical, thermal, and biological attack. The difference or heterogeneity in reactivity leads to the recalcitrance of woody biomass at conversion. A selection of processes is presented together as a biorefinery based on incremental sequential deconstruction, fractionation/conversion of woody biomass to achieve efficient separation of major components. A preference is given to a biorefinery absent of pretreatment and detoxification process that produce waste byproducts. While numerous biorefinery approaches are known, a focused review on the integrated studies of water-based biorefinery processes is presented. Hot-water extraction is the first process step to extract value from woody biomass while improving the quality of the remaining solid material. This first step removes extractives and hemicellulose fractions from woody biomass. While extractives and hemicellulose are largely removed in the extraction liquor, cellulose and lignin largely remain in the residual woody structure. Xylo-oligomers, aromatics and acetic acid in the hardwood extract are the major components having the greatest potential value for development. Higher temperature and longer residence time lead to higher mass removal. While high temperature (>200°C) can lead to nearly total dissolution, the amount of sugars present in the extraction liquor decreases rapidly with temperature. Dilute acid hydrolysis of concentrated wood extracts renders the wood extract with monomeric sugars

Environmental implications of increased biomass energy use. Final report

Energy Technology Data Exchange (ETDEWEB)

Miles, T.R. Sr.; Miles, T.R. Jr. [Miles (Thomas R.), Portland, OR (United States)

1992-03-01

This study reviews the environmental implications of continued and increased use of biomass for energy to determine what concerns have been and need to be addressed and to establish some guidelines for developing future resources and technologies. Although renewable biomass energy is perceived as environmentally desirable compared with fossil fuels, the environmental impact of increased biomass use needs to be identified and recognized. Industries and utilities evaluating the potential to convert biomass to heat, electricity, and transportation fuels must consider whether the resource is reliable and abundant, and whether biomass production and conversion is environmentally preferred. A broad range of studies and events in the United States were reviewed to assess the inventory of forest, agricultural, and urban biomass fuels; characterize biomass fuel types, their occurrence, and their suitability; describe regulatory and environmental effects on the availability and use of biomass for energy; and identify areas for further study. The following sections address resource, environmental, and policy needs. Several specific actions are recommended for utilities, nonutility power generators, and public agencies.

From research plots to prototype biomass plantations

Energy Technology Data Exchange (ETDEWEB)

Kenney, W.A.; Vanstone, B.J.; Gambles, R.L.; Zsuffa, L. [Univ. of Toronto, Ontario (Canada)

1993-12-31

The development of biomass energy plantations is now expanding from the research plot phase into the next level of development at larger scale plantings. This is necessary to provide: more accurate information on biomass yields, realistic production cost figures, venues to test harvesting equipment, demonstration sites for potential producers, and a supply of feedstock for prototype conversion facilities. The paper will discuss some of these objectives and some of the challenges encountered in the scale-up process associated with a willow prototype plantation project currently under development in Eastern Canada.

Fundamental Study of Single Biomass Particle Combustion

DEFF Research Database (Denmark)

Momenikouchaksaraei, Maryam

This thesis is a comprehensive study of single biomass particle combustion. The effect of particle shape and size and operating conditions on biomass conversion characteristics were investigated experimentally and theoretically. The experimental samples were divided in two groups: particles...... well-defined conditions, and the complete combustion processes were recorded as video sequences by a CCD camera installed in the set-up. One of the project objectives is to simulate conditions reasonably close to the conditions in a power plant boiler, i.e., reasonably high temperatures (up to 1600°C...

Characterization of Various Biomass Feedstocks for Energy Production

DEFF Research Database (Denmark)

Toor, Saqib; Rosendahl, Lasse; Hoffmann, Jessica

2013-01-01

Biomass represents the renewable energy source and their use reduces the consumption of fossil fuels and limits the emission of CO2. In this work, various biomass feedstocks were assessed for assessing their suitability as energy production sources using thermochemical conversion routes especially...... hydrothermal liquefaction (HTL) process. The methods used to analyze involved performing proximate, ultimate and thermogravimetry analysis. On the basis of proximate, ultimate, and thermogravimetry analysis, the dried distiller grains with solubles (DDGS), corn silage, chlorella vulgaris, spirulina platensis...

Energy-efficient biomass processing with pulsed electric fields for bioeconomy and sustainable development.

Science.gov (United States)

Golberg, Alexander; Sack, Martin; Teissie, Justin; Pataro, Gianpiero; Pliquett, Uwe; Saulis, Gintautas; Stefan, Töpfl; Miklavcic, Damijan; Vorobiev, Eugene; Frey, Wolfgang

2016-01-01

Fossil resources-free sustainable development can be achieved through a transition to bioeconomy, an economy based on sustainable biomass-derived food, feed, chemicals, materials, and fuels. However, the transition to bioeconomy requires development of new energy-efficient technologies and processes to manipulate biomass feed stocks and their conversion into useful products, a collective term for which is biorefinery. One of the technological platforms that will enable various pathways of biomass conversion is based on pulsed electric fields applications (PEF). Energy efficiency of PEF treatment is achieved by specific increase of cell membrane permeability, a phenomenon known as membrane electroporation. Here, we review the opportunities that PEF and electroporation provide for the development of sustainable biorefineries. We describe the use of PEF treatment in biomass engineering, drying, deconstruction, extraction of phytochemicals, improvement of fermentations, and biogas production. These applications show the potential of PEF and consequent membrane electroporation to enable the bioeconomy and sustainable development.

Economical analyses of construction of a biomass boiler house

International Nuclear Information System (INIS)

Normak, A.

2002-01-01

To reduce the energy costs we can use cheaper fuel to fire our boiler. One of the cheapest fuels is wood biomass. It is very actual issue how to use cheaper wood biomass in heat generation to decrease energy costs and to increase biomass share in our energy balance. Before we decide to build biomass boiler house it is recommendable to analyse the economical situation and work out most profitable, efficient, reliable and ecological boiler plant design on particular conditions. The best way to perform the analyses is to use the economical model presented. It saves our time and gives objective evaluation to the project. (author)

[Effects of situational and individual variables on critical thinking expression].

Science.gov (United States)

Tanaka, Yuko; Kusumi, Takashi

2016-04-01

The present study examined when people decide to choose an expression that is based on critical thinking, and how situational and individual variables affect such a decision process. Given a conversation scenario including overgeneralization with two friends, participants decided whether to follow the conversation by a critical-thinking expression or not. The authors controlled purpose and topic as situational variables, and measured critical-thinking ability, critical-thinking disposition, and self-monitoring as individual variables. We conducted an experiment in which the situational variables were counterbalanced in a within-subject design with 60 university students. The results of logistic regression analysis showed differences within individuals in the decision process whether to choose a critical-thinking expression, and that some situational factors and some subscales of the individual measurements were related to the differences.

Study on new biomass energy systems

Science.gov (United States)

1992-03-01

A biomass energy total system is proposed, and its feasibility is studied. It is the system in which liquid fuel is produced from eucalyptuses planted in the desert area in Australia for production of biomass resource. Eucalyptus tree planting aims at a growth amount of 40 cu m/ha. per year and a practical application area of 45,000ha. CO2 fixation in the biomass plantation becomes 540,000 tons at a 12 ton/ha. rate. Assuming that 0.55 ton of liquid fuel is produced from 1 ton of biomass, a petrochemical plant having a production of 2.5 million bbl/year per unit (equivalent to the fuel used in the 100,000kW class power plant) is needed. Moreover, survey is made on practicality of diesel substitution fuel by esterification of palm oil, and a marked effect of reduction in soot/smoke and particulates in exhaust gas is confirmed. The biomass conversion process technology and the technology for afforestation at the arid land and irrigation are important as future subjects, and the technology development using a bench plant and a pilot plant is needed.

BioBoost. Biomass based energy intermediates boosting bio-fuel production

Energy Technology Data Exchange (ETDEWEB)

Niebel, Andreas [Karlsruher Institut fuer Technologie (KIT), Karlsruhe (Germany). Institut fuer Katalyseforschung und -technologie (IKFT)

2013-10-01

To increase the share of biomass for renewable energy in Europe conversion pathways which are economic, flexible in feedstock and energy efficient are needed. The BioBoost project concentrates on dry and wet residual biomass and wastes as feedstock for de-central conversion by fast pyrolysis, catalytic pyrolysis and hydrothermal carbonization to the intermediate energy carriers oil, coal or slurry. Based on straw the energy density increases from 2 to 20-30 GJ/m{sup 3}, enabling central GW scale gasification plants for bio-fuel production. A logistic model for feedstock supply and connection of de-central with central conversion is set up and validated allowing the determination of costs, the number and location of de-central and central sites. Techno/economic and environmental assessment of the value chain supports the optimization of products and processes. The utilization of energy carriers is investigated in existing and coming applications of heat and power production and synthetic fuels and chemicals. (orig.)

Assesment of the energy quality of the synthesis gas produced from biomass derived fuels conversion: Part I: Liquid Fuels, Ethanol

International Nuclear Information System (INIS)

Arteaga Perez, Luis E; Casas, Yannay; Peralta, Luis M; Granda, Daikenel; Prieto, Julio O

2011-01-01

The use of biofuels plays an important role to increase the efficiency and energetic safety of the energy processes in the world. The main goal of the present research is to study from the thermodynamics and kinetics the effect of the operational variables on the thermo-conversion processes of biomass derived fuels focused on ethanol reforming. Several models are developed to assess the technological proposals. The minimization of Gibbs free energy is the criterion applied to evaluate the performance of the different alternatives considering the equilibrium constraints. All the models where validated on an experimental data base. The gas composition, HHV and the ratio H2/CO are used as measures for the process efficiency. The operational parameters are studied in a wide range (reactants molar ratio, temperature and oxygen/fuel ratio). (author)

Conversation and research

NARCIS (Netherlands)

Schuurman, Jan Gerrit; Veermans, K.H.

2001-01-01

Gordon Pask’s conversation theory was created in the 1970s. The theory encompasses a high-level framework for studying interactions between actors in artificial situations where people co-operate, have conflicts, follow rules, negotiate outcomes, invent new rules together, etc. Sadly, the theory is

Preprocessing Moist Lignocellulosic Biomass for Biorefinery Feedstocks

Energy Technology Data Exchange (ETDEWEB)

Neal Yancey; Christopher T. Wright; Craig Conner; J. Richard Hess

2009-06-01

Biomass preprocessing is one of the primary operations in the feedstock assembly system of a lignocellulosic biorefinery. Preprocessing is generally accomplished using industrial grinders to format biomass materials into a suitable biorefinery feedstock for conversion to ethanol and other bioproducts. Many factors affect machine efficiency and the physical characteristics of preprocessed biomass. For example, moisture content of the biomass as received from the point of production has a significant impact on overall system efficiency and can significantly affect the characteristics (particle size distribution, flowability, storability, etc.) of the size-reduced biomass. Many different grinder configurations are available on the market, each with advantages under specific conditions. Ultimately, the capacity and/or efficiency of the grinding process can be enhanced by selecting the grinder configuration that optimizes grinder performance based on moisture content and screen size. This paper discusses the relationships of biomass moisture with respect to preprocessing system performance and product physical characteristics and compares data obtained on corn stover, switchgrass, and wheat straw as model feedstocks during Vermeer HG 200 grinder testing. During the tests, grinder screen configuration and biomass moisture content were varied and tested to provide a better understanding of their relative impact on machine performance and the resulting feedstock physical characteristics and uniformity relative to each crop tested.

Empowerment model of biomass in west java

Science.gov (United States)

Mulyana, C.; Fitriani, N. I.; Saad, A.; Yuliah, Y.

2017-06-01

Scarcity of fossil energy accelerates the search of renewable energy sources as the substitution. In West Java, biomass has potential to be developed into bio-briquette because the resources are abundant. The objectives of this research are mapping the potency of biomass as bio-briquette in West Java, and making the model of the empowerment biomass potential involving five fundamental step which are raw material, pre-processing process, conversion mechanism, products, and end user. The main object of this model focused on 3 forms which are solid, liquid, and gas which was made by involving the community component as the owner biomass, district government, academics and researcher communities, related industries as users of biomass, and the central government as the policy holders and investors as a funder. In the model was described their respective roles and mutual relationship one with another so that the bio-briquette as a substitute of fossil fuels can be realized. Application of this model will provide the benefits in renewability energy sources, environmental, socio economical and energy security.

Nitrogen-to-Protein Conversion Factors for Crop Residues and Animal Manure Common in China.

Science.gov (United States)

Chen, Xueli; Zhao, Guanglu; Zhang, Yang; Han, Lujia; Xiao, Weihua

2017-10-25

Accurately determining protein content is essential in exploiting biomass as feed and fuel. A survey of biomass samples in China indicated protein contents from 2.65 to 3.98% for crop residues and from 6.07 to 10.24% for animal manure of dry basis. Conversion factors based on amino acid nitrogen (k A ) ranged from 5.42 to 6.00 for the former and from 4.78 to 5.36 for the latter, indicating that the traditional factor of 6.25 is not suitable for biomass samples. On the other hand, conversion factors from Kjeldahl nitrogen (k P ) ranged from 3.97 to 4.57 and from 2.76 to 4.31 for crop residues and animal manure, respectively. Of note, conversion factors were strongly affected by amino acid composition and levels of nonprotein nitrogen. Thus, k P values of 4.23 for crop residues, 4.11 for livestock manure, and 3.11 for poultry manure are recommended to better estimate protein content from total nitrogen.

Liquid fuels from biomass in Europe

Energy Technology Data Exchange (ETDEWEB)

Coombs, J.

1984-03-01

The incorporation of solar energy into plant material through photosynthesis has the advantage that the energy is stored in a fixed form which is relatively stable, but the disadvantage is that plant biomass is not immediately compatible with the use in internal combustion engines to provide motive power. However, by choice of suitable crops, conversion technologies and engine modification it is possible to produce biomassderived liquid transport fuels; either substitutes for petroleum in the form of alcohols or replacements for diesel fuel in the form of vegetable oils or their esters. Using more complex conversion technologies it is also possible to produce hydrocarbon mixtures similar to petroleum. Some of these methodologies are available on a farm or commercial scale now; some are still at the research and development or demonstration stage, whereas others remain speculative. The purpose of this paper is to consider the present state of the art in respect of the production of liquid transport fuels from biomass and to indicate how the various possibilities might fit with present and future energy needs in the European Community.

Energy Efficiency and Air Quality Repairs at Lyonsdale Biomass

Energy Technology Data Exchange (ETDEWEB)

Brower, Michael R; Morrison, James A; Spomer, Eric; Thimot, Carol A

2012-07-31

This project enabled Lyonsdale Biomass, LLC to effect analyses, repairs and upgrades for its biomass cogeneration facility located in Lewis County, New York and close by the Adirondack Park to reduce air emissions by improving combustion technique and through the overall reduction of biomass throughput by increasing the system's thermodynamic efficiency for its steam-electrical generating cycle. Project outcomes result in significant local, New York State, Northeast U.S. and national benefits including improved renewable energy operational surety, enhanced renewable energy efficiency and more freedom from foreign fossil fuel source dependence. Specifically, the reliability of the Lyonsdale Biomass 20MWe woody biomass combined-heat and power (CHP) was and is now directly enhanced. The New York State and Lewis County benefits are equally substantial since the facility sustains 26 full-time equivalency (FTE) jobs at the facility and as many as 125 FTE jobs in the biomass logistics supply chain. Additionally, the project sustains essential local and state payment in lieu of taxes revenues. This project helps meet several USDOE milestones and contributes directly to the following sustainability goals:  Climate: Reduces greenhouse gas emissions associated with bio-power production, conversion and use, in comparison to fossil fuels. Efficiency and Productivity: Enhances efficient use of renewable resources and maximizes conversion efficiency and productivity. Profitability: Lowers production costs. Rural Development: Enhances economic welfare and rural development through job creation and income generation. Standards: Develop standards and corresponding metrics for ensuring sustainable biopower production. Energy Diversification and Security: Reduces dependence on foreign oil and increases energy supply diversity. Net Energy Balance: Ensures positive net energy balance for all alternatives to fossil fuels.

Electrifying biomass

International Nuclear Information System (INIS)

Kusnierczyk, D.

2005-01-01

British Columbia's (BC) energy plan was outlined in this PowerPoint presentation. BC Hydro is the third largest electric utility in Canada with a generating capacity of 11,000 MW, 90 per cent of which is hydro generation. Various independent power project (IPP) biomass technologies were outlined, including details of biogas, wood residue and municipal solid waste facilities. An outline of BC Hydro's overall supply mix was presented, along with details of the IPP supply mix. It was suggested that the cancellation of the Duke Point power project has driven growth in the renewable energy sector. A chart of potential energy contribution by resource type was presented, as well as unit energy cost ranges. Resources included small and large hydro; demand side management; resource smart natural gas; natural gas; coal; wind; geothermal; biomass; wave; and tidal. The acquisition process was reviewed. Details of calls for tenders were presented, and issues concerning bidder responsibility and self-selection were examined. It was observed that wood residue presents a firm source of electricity that is generally local, and has support from the public. In addition, permits for wood residue energy conversion are readily available. However, size limitations, fuel risks, and issues concerning site control may prove to be significant challenges. It was concluded that the success of biomass energy development will depend on adequate access and competitive pricing. tabs., figs

Pyrolysis based bio-refinery for the production of bioethanol from demineralized ligno-cellulosic biomass

NARCIS (Netherlands)

Luque, L.; Westerhof, Roel Johannes Maria; van Rossum, G.; Oudenhoven, Stijn; Kersten, Sascha R.A.; Berruti, F.; Rehmann, L.

2014-01-01

This paper evaluates a novel biorefinery approach for the conversion of lignocellulosic biomass from pinewood. A combination of thermochemical and biochemical conversion was chosen with the main product being ethanol. Fast pyrolysis of lignocellulosic biomasss with fractional condensation of the

Environmental impacts of thermochemical biomass conversion. Final report

Energy Technology Data Exchange (ETDEWEB)

Elliott, D.C.; Hart, T.R.; Neuenschwander, G.G.; McKinney, M.D.; Norton, M.V.; Abrams, C.W. [Pacific Northwest Lab., Richland, WA (United States)

1995-06-01

Thermochemical conversion in this study is limited to fast pyrolysis, upgrading of fast pyrolysis oils, and gasification. Environmental impacts of all types were considered within the project, but primary emphasis was on discharges to the land, air, and water during and after the conversion processes. The project discussed here is divided into five task areas: (1) pyrolysis oil analysis; (2) hydrotreating of pyrolysis oil; (3) gas treatment systems for effluent minimization; (4) strategic analysis of regulatory requirements; and (5) support of the IEA Environmental Systems Activity. The pyrolysis oil task was aimed at understanding the oil contaminants and potential means for their removal. The hydrotreating task was undertaken to better define one potential means for both improving the quality of the oil but also removing contaminants from the oil. Within Task 3, analyses were done to evaluate the results of gasification product treatment systems. Task 4 was a review and collection of regulatory requirements which would be applicable to the subject processes. The IEA support task included input to and participation in the IEA Bioenergy activity which directly relates to the project subject. Each of these tasks is described along with the results. Conclusions and recommendations from the overall project are given.

Environmental impacts of thermochemical biomass conversion. Final report

International Nuclear Information System (INIS)

Elliott, D.C.; Hart, T.R.; Neuenschwander, G.G.; McKinney, M.D.; Norton, M.V.; Abrams, C.W.

1995-06-01

Thermochemical conversion in this study is limited to fast pyrolysis, upgrading of fast pyrolysis oils, and gasification. Environmental impacts of all types were considered within the project, but primary emphasis was on discharges to the land, air, and water during and after the conversion processes. The project discussed here is divided into five task areas: (1) pyrolysis oil analysis; (2) hydrotreating of pyrolysis oil; (3) gas treatment systems for effluent minimization; (4) strategic analysis of regulatory requirements; and (5) support of the IEA Environmental Systems Activity. The pyrolysis oil task was aimed at understanding the oil contaminants and potential means for their removal. The hydrotreating task was undertaken to better define one potential means for both improving the quality of the oil but also removing contaminants from the oil. Within Task 3, analyses were done to evaluate the results of gasification product treatment systems. Task 4 was a review and collection of regulatory requirements which would be applicable to the subject processes. The IEA support task included input to and participation in the IEA Bioenergy activity which directly relates to the project subject. Each of these tasks is described along with the results. Conclusions and recommendations from the overall project are given

Biomass gasification for electricity generation with internal combustion engines. Process efficiency

International Nuclear Information System (INIS)

Lesme-Jaén, René; Garcia Faure, Luis; Recio Recio, Angel; Oliva Ruiz, Luis; Pajarín Rodríguez, Juan; Revilla Suarez, Dennis

2015-01-01

Biomass is a renewable source of energy worldwide increased prospects for its potential and its lower environmental impact compared to fossil fuels. By processes and energy conversion technologies it is possible to obtain fuels in solid, liquid and gaseous form from any biomass. The biomass gasification is the thermal conversion thereof into a gas, which can be used for electricity production with the use of internal combustion engines with a certain level of efficiency, which depends on the characteristics of biomass and engines used. In this work the evaluation of thermal and overall efficiency of the gasification in Integrated Forestry Enterprise of Santiago de Cuba, designed to generate electricity from waste from the forest industry is presented. Is a downdraft gasifier reactor, COMBO-80 model and engine manufacturing Hindu (diesel) model Leyland modified to work with producer gas. The evaluation was carried out for different loads (electric power generated) engine from experimental measurements of flow and composition of the gas supplied to the engine. The results show that the motor operates with a thermal efficiency in the range of 20-32% with an overall efficiency between 12-25%. (full text)

Report on technical measurements concerning measurement of the suction of tanks at Fangel biomass conversion plant

International Nuclear Information System (INIS)

1992-05-01

The inconveniences caused by the odours emerging from the biomass conversion plant in Fangel, Denmark, and the actions taken in an attempt to reduce them, are described. The plant has on several occasions been threatened with being closed down because of the smell. Airtight coverings have been fixed on all the open tanks, and the suction element has been tested to see if it is airtight. Ozone has been added in order to help get rid of the smell. Measurements have shown that it is possible to attain a small vacuum in the storage tank under normal operation, if there is a surfeit of pumping there will be too high pressure. In relation to pumping-in the pressure can be too high in the first and medium tank. Flow, pressure, hydrogen sulphide and methane concentration changes significantly in relation to the various pumping frequences. The level of hydrogen sulphide removal in the biofilter was 70-85%. The flow of hydrogen sulphide becomes less after the addition of ozone. Measurements implied that the tanks were airtight. Larger vacuums can be achieved by changing the shape of the pipe system and increasing the flow. (AB)

Green chemicals : A Kinetic Study on the Conversion of Glucose to Levulinic Acid

NARCIS (Netherlands)

Girisuta, B.; Janssen, L.P.B.M.; Heeres, H.J.

2006-01-01

Levulinic acid has been identified as a promising green, biomass derived platform chemical. A kinetic study on one of the key steps in the conversion of biomass to levulinic acid, i.e., the acid catalysed decomposition of glucose to levulinic acid has been performed. The experiments were performed

Co-gasification of biomass and coal in a pressurised fluidised bed gasifier

Energy Technology Data Exchange (ETDEWEB)

Andries, L; Hein, K R.G. [Lab. for Thermal Power Engineering, Dept. of Mechanical Engineering and Marine Technology, Delft Univ. of Technology (Netherlands)

1997-12-31

The Laboratory for Thermal Power Engineering of the Delft University of Technology is participating in an EU funded, international, R + D project which is designed to aid European industry in addressing issues regarding co-utilisation of biomass and/or waste in advanced coal conversion processes. The project comprises three main programmes, each of which includes a number of smaller subprogrammes. The three main programmes are: Coal-biomass systems component development and design; Coal-biomass environmental studies; Techno-economic assessment studies. (orig)

Co-gasification of biomass and coal in a pressurised fluidised bed gasifier

Energy Technology Data Exchange (ETDEWEB)

Andries, L.; Hein, K.R.G. [Lab. for Thermal Power Engineering, Dept. of Mechanical Engineering and Marine Technology, Delft Univ. of Technology (Netherlands)

1996-12-31

The Laboratory for Thermal Power Engineering of the Delft University of Technology is participating in an EU funded, international, R + D project which is designed to aid European industry in addressing issues regarding co-utilisation of biomass and/or waste in advanced coal conversion processes. The project comprises three main programmes, each of which includes a number of smaller subprogrammes. The three main programmes are: Coal-biomass systems component development and design; Coal-biomass environmental studies; Techno-economic assessment studies. (orig)

Energy from biomass and wastes: 1979 update

Energy Technology Data Exchange (ETDEWEB)

Klass, D.L.

1979-01-01

The R and D activities in progress in the United States on the development of biomass and wastes as renewable energy sources have reached the point where all phases of the technology are under active investigation. Highlights of this effort are briefly reviewed from the standpoint of energy impact, funding, carbon dioxide build-up in the atmosphere, and biomass production and its conversion to energy and synthetic fuels. Special attention is given to alcohols because of the current interest in gasohol. Significant accomplishments were reported in 1979, and it is expected that commercial utilization of this information will begin to gather more momentum.

Production of chemicals and fuels from biomass

Energy Technology Data Exchange (ETDEWEB)

Woods, Elizabeth; Qiao, Ming; Myren, Paul; Cortright, Randy D.; Kania, John

2015-12-15

Described are methods, reactor systems, and catalysts for converting biomass to fuels and chemicals in a batch and/or continuous process. The process generally involves the conversion of water insoluble components of biomass, such as hemicellulose, cellulose and lignin, to volatile C.sub.2+O.sub.1-2 oxygenates, such as alcohols, ketones, cyclic ethers, esters, carboxylic acids, aldehydes, and mixtures thereof. In certain applications, the volatile C.sub.2+O.sub.1-2 oxygenates can be collected and used as a final chemical product, or used in downstream processes to produce liquid fuels, chemicals and other products.

High yielding tropical energy crops for bioenergy production: Effects of plant components, harvest years and locations on biomass composition.

Science.gov (United States)

Surendra, K C; Ogoshi, Richard; Zaleski, Halina M; Hashimoto, Andrew G; Khanal, Samir Kumar

2018-03-01

The composition of lignocellulosic feedstock, which depends on crop type, crop management, locations and plant parts, significantly affects the conversion efficiency of biomass into biofuels and biobased products. Thus, this study examined the composition of different parts of two high yielding tropical energy crops, Energycane and Napier grass, collected across three locations and years. Significantly higher fiber content was found in the leaves of Energycane than stems, while fiber content was significantly higher in the stems than the leaves of Napier grass. Similarly, fiber content was higher in Napier grass than Energycane. Due to significant differences in biomass composition between the plant parts within a crop type, neither biological conversion, including anaerobic digestion, nor thermochemical pretreatment alone is likely to efficiently convert biomass components into biofuels and biobased products. However, combination of anaerobic digestion with thermochemical conversion technologies could efficiently utilize biomass components in generating biofuels and biobased products. Copyright © 2017 Elsevier Ltd. All rights reserved.

Conversion and assimilation of furfural and 5-(hydroxymethyl)furfural by Pseudomonas putida KT2440.

Science.gov (United States)

Guarnieri, Michael T; Ann Franden, Mary; Johnson, Christopher W; Beckham, Gregg T

2017-06-01

The sugar dehydration products, furfural and 5-(hydroxymethyl)furfural (HMF), are commonly formed during high-temperature processing of lignocellulose, most often in thermochemical pretreatment, liquefaction, or pyrolysis. Typically, these two aldehydes are considered major inhibitors in microbial conversion processes. Many microbes can convert these compounds to their less toxic, dead-end alcohol counterparts, furfuryl alcohol and 5-(hydroxymethyl)furfuryl alcohol. Recently, the genes responsible for aerobic catabolism of furfural and HMF were discovered in Cupriavidus basilensis HMF14 to enable complete conversion of these compounds to the TCA cycle intermediate, 2-oxo-glutarate. In this work, we engineer the robust soil microbe, Pseudomonas putida KT2440, to utilize furfural and HMF as sole carbon and energy sources via complete genomic integration of the 12 kB hmf gene cluster previously reported from Burkholderia phytofirmans . The common intermediate, 2-furoic acid, is shown to be a bottleneck for both furfural and HMF metabolism. When cultured on biomass hydrolysate containing representative amounts of furfural and HMF from dilute-acid pretreatment, the engineered strain outperforms the wild type microbe in terms of reduced lag time and enhanced growth rates due to catabolism of furfural and HMF. Overall, this study demonstrates that an approach for biological conversion of furfural and HMF, relative to the typical production of dead-end alcohols, enables both enhanced carbon conversion and substantially improves tolerance to hydrolysate inhibitors. This approach should find general utility both in emerging aerobic processes for the production of fuels and chemicals from biomass-derived sugars and in the biological conversion of high-temperature biomass streams from liquefaction or pyrolysis where furfural and HMF are much more abundant than in biomass hydrolysates from pretreatment.

Conversion and assimilation of furfural and 5-(hydroxymethylfurfural by Pseudomonas putida KT2440

Directory of Open Access Journals (Sweden)

Michael T. Guarnieri

2017-06-01

Full Text Available The sugar dehydration products, furfural and 5-(hydroxymethylfurfural (HMF, are commonly formed during high-temperature processing of lignocellulose, most often in thermochemical pretreatment, liquefaction, or pyrolysis. Typically, these two aldehydes are considered major inhibitors in microbial conversion processes. Many microbes can convert these compounds to their less toxic, dead-end alcohol counterparts, furfuryl alcohol and 5-(hydroxymethylfurfuryl alcohol. Recently, the genes responsible for aerobic catabolism of furfural and HMF were discovered in Cupriavidus basilensis HMF14 to enable complete conversion of these compounds to the TCA cycle intermediate, 2-oxo-glutarate. In this work, we engineer the robust soil microbe, Pseudomonas putida KT2440, to utilize furfural and HMF as sole carbon and energy sources via complete genomic integration of the 12 kB hmf gene cluster previously reported from Burkholderia phytofirmans. The common intermediate, 2-furoic acid, is shown to be a bottleneck for both furfural and HMF metabolism. When cultured on biomass hydrolysate containing representative amounts of furfural and HMF from dilute-acid pretreatment, the engineered strain outperforms the wild type microbe in terms of reduced lag time and enhanced growth rates due to catabolism of furfural and HMF. Overall, this study demonstrates that an approach for biological conversion of furfural and HMF, relative to the typical production of dead-end alcohols, enables both enhanced carbon conversion and substantially improves tolerance to hydrolysate inhibitors. This approach should find general utility both in emerging aerobic processes for the production of fuels and chemicals from biomass-derived sugars and in the biological conversion of high-temperature biomass streams from liquefaction or pyrolysis where furfural and HMF are much more abundant than in biomass hydrolysates from pretreatment.

Sustainable Strategy Utilizing Biomass: Visible-Light-Mediated Synthesis of gamma-Valerolactone

Data.gov (United States)

U.S. Environmental Protection Agency — A novel sustainable approach to valued g-valerolactone was investigated. This approach exploits the visible-light-mediated conversion of biomass-derived levulinic...

Green Polymer Precursors from Biomass-Based Levulinic Acid

NARCIS (Netherlands)

Chalid, M.; Heeres, H.J.; Broekhuis, A.A.

2012-01-01

Levulinic acid (LA) has been identified as a suitable chemical feedstock that can be isolated from biomass. Its conversion into γ-valerolactone (GVL) via hydrogenation and ringclosure to the lactone has been studied as a versatile route to the manufacture of biodegradable polyesters. For

Direct conversion of wet algae to crude biodiesel under supercritical ethanol conditions

Energy Technology Data Exchange (ETDEWEB)

Reddy, Harvind K. [New Mexico State Univ., Las Cruces, NM (United States). Chemical Engineering Dept.; Muppaneni, Tapaswy [New Mexico State Univ., Las Cruces, NM (United States). Chemical Engineering Dept.; Patil, Prafulla D. [American Refining Group, Inc., Bradford, PA (United States); Ponnusamy, Sundaravadivelnathan [New Mexico State Univ., Las Cruces, NM (United States). Chemical Engineering Dept.; Cooke, Peter [New Mexico State Univ., Las Cruces, NM (United States). Core University Research Resource Lab.; Schaub, Tanner [New Mexico State Univ., Las Cruces, NM (United States). Bio Security and Food Safety Center; Deng, Shuguang [New Mexico State Univ., Las Cruces, NM (United States). Chemical Engineering Dept.

2013-08-06

This paper presents a single-step, environmentally friendly approach for the direct conversion of wet algae to crude biodiesel under supercritical ethanol conditions. Ethanol was used for the simultaneous extraction and transesterification of lipids in algae to produce fatty acid ethyl esters at supercritical conditions. In this work the effects of process parameters dry algae to ethanol (wt./vol.) ratio (1:6-1:15), reaction temperature (245-270 C), and reaction time (2-30 min.) on the yield of fatty acid ethyl esters (FAEE) were studied. 67% conversion was achieved at 265 C and 20 min of reaction time. The calorific value of a purified biodiesel sample produced at optimum conditions was measured to be 43 MJ/kg, which is higher than that of fatty acid methyl esters produced from the same biomass. The purified fatty acid ethyl esters were analyzed using GC-MS and FTIR. TGA analysis of algal biomass and purified FAEE was presented along with TEM images of the biomass captured before and after supercritical ethanol transesterification. This green conversion process has the potential to provide an energy-efficient and economical route for the production of renewable biodiesel production.

Process Design and Economics for the Conversion of Lignocellulosic Biomass to Hydrocarbon Fuels. Thermochemical Research Pathways with In Situ and Ex Situ Upgrading of Fast Pyrolysis Vapors

Energy Technology Data Exchange (ETDEWEB)

Dutta, A.; Sahir, A.; Tan, E.; Humbird, D.; Snowden-Swan, L. J.; Meyer, P.; Ross, J.; Sexton, D.; Yap, R.; Lukas, J.

2015-03-01

This report was developed as part of the U.S. Department of Energy’s Bioenergy Technologies Office’s efforts to enable the development of technologies for the production of infrastructurecompatible, cost-competitive liquid hydrocarbon fuels from biomass. Specifically, this report details two conceptual designs based on projected product yields and quality improvements via catalyst development and process integration. It is expected that these research improvements will be made within the 2022 timeframe. The two conversion pathways detailed are (1) in situ and (2) ex situ upgrading of vapors produced from the fast pyrolysis of biomass. While the base case conceptual designs and underlying assumptions outline performance metrics for feasibility, it should be noted that these are only two of many other possibilities in this area of research. Other promising process design options emerging from the research will be considered for future techno-economic analysis.

Critical Exchange: Religion and Schooling in Conversation

Science.gov (United States)

Stern, Julian

2017-01-01

Given the complex and messy contexts of schooling, conversations between religion and schooling can be "admitted" as examples of the sort of situated conversation that goes beyond the "false necessity" of universal state-controlled school-based education. There are distinct claims to be made about religion and schooling in…

Electricity production by advanced biomass power systems

Energy Technology Data Exchange (ETDEWEB)

Solantausta, Y [VTT Energy, Espoo (Finland). Energy Production Technologies; Bridgwater, T [Aston Univ. Birmingham (United Kingdom); Beckman, D [Zeton Inc., Burlington, Ontario (Canada)

1996-11-01

This report gives the results of the Pyrolysis Collaborative Project organized by the International Energy Agency (IEA) under Biomass Agreement. The participating countries or organizations were Canada, European Community (EC), Finland, United States of America, and the United Kingdom. The overall objective of the project was to establish baseline assessments for the performance and economics of power production from biomass. Information concerning the performance of biomass-fuelled power plants based on gasification is rather limited, and even less data is available of on pyrolysis based power applications. In order to gain further insight into the potential for these technologies, this study undertook the following tasks: (1) Prepare process models to evaluate the cost and performance of new advanced biomass power production concepts, (2) Assess the technical and economic uncertainties of different biomass power concepts, (3) Compare the concepts in small scale and in medium scale production (5 - 50 MW{sub e}) to conventional alternatives. Processes considered for this assessment were biomass power production technologies based on gasification and pyrolysis. Direct combustion technologies were employed as a reference for comparison to the processes assessed in this study. Wood was used a feedstock, since the most data was available for wood conversion

Synergistic combination of biomass torrefaction and co-gasification: Reactivity studies.

Science.gov (United States)

Zhang, Yan; Geng, Ping; Liu, Rui

2017-12-01

Two typical biomass feedstocks obtained from woody wastes and agricultural residues were torrefied or mildly pyrolized in a fixed-bed reactor. Effects of the torrefaction conditions on product distributions, compositional and energetic properties of the solid products, char gasification reactivity, and co-gasification behavior between coal and torrefied solids were systematically investigated. Torrefaction pretreatment produced high quality bio-solids with not only increased energy density, but also concentrated alkali and alkaline earth metals (AAEM). As a consequence of greater retention of catalytic elements in the solid products, the chars derived from torrefied biomass exhibited a faster conversion than those derived from raw biomass during CO 2 gasification. Furthermore, co-gasification of coal/torrefied biomass blends exhibited stronger synergy compared to the coal/raw biomass blends. The results and insights provided by this study filled a gap in understanding synergy during co-gasification of coal and torrefied biomass. Copyright © 2017 Elsevier Ltd. All rights reserved.

Benefits of Allothermal Biomass Gasification for Co-Firing

Energy Technology Data Exchange (ETDEWEB)

Van der Meijden, C.M.; Van der Drift, A.; Vreugdenhil, B.J. [ECN Biomass and Energy Efficiency, Petten (Netherlands)

2012-04-15

Many countries have set obligations to reduce the CO2 emissions from coal fired boilers. Co-firing of biomass in existing coal fired power plants is an attractive solution to reduce CO2 emissions. Co-firing can be done by direct mixing of biomass with coal (direct co-firing) or by converting the biomass into a gas or liquid which is fired in a separate burner (indirect co-firing). Direct co-firing is a rather simple solution, but requires a high quality and expensive biomass fuel (e.g. wood pellets). Indirect co-firing requires an additional installation that converts the solid biomass into a gas or liquid, but has the advantage that it can handle a wide range of cheap biomass fuels (e.g. demolition wood) and most of the biomass ash components are separated from the gas before it enters the boiler. Separation of biomass ash can prevent fouling issues in the boiler. Indirect co-firing, using biomass gasification technology, is already common practice. In Geertruidenberg (the Netherlands) a 80 MWth Lurgi CFB gasifier produces gas from demolition wood which is co-fired in the Amer PC boiler. In Ruien (Belgium) a 50 MWth Foster Wheeler fluidized bed gasifier is in operation. The Energy research Centre of the Netherlands (ECN) developed a 'second generation' allothermal gasifier called the MILENA gasifier. This gasifier has some major advantages over conventional fluidized bed gasifiers. The heating value of the produced gas is approximately 2.5 times higher than of gas produced by conventional bubbling / circulating fluidized bed gasifiers. This results in smaller adaptations to the membrane wall of the boiler for the gas injection, thus lower costs. A major disadvantage of most fluidized bed gasifiers is the incomplete conversion of the fuel. Typical fuel conversions vary between 90 and 95%. The remaining combustible material, also containing most of the biomass ash components, is blown out of the gasifier and removed from the gas stream by a cyclone to

Biomass a fast growing energy resource

International Nuclear Information System (INIS)

Hansen, Ulf

2003-01-01

Biomass as an energy resource is as versatile as the biodiversity suggests. The global net primary production, NPP, describes the annual growth of biomass on land and in the seas. This paper focuses on biomass grown on land. A recent estimate for the NPP on land is 120 billion tons of dry matter. How much of this biomass are available for energy purposes? The potential contribution of wood fuel and energy plants from sustainable production is limited to some 5% of NPP, i.e. 6 Bt. One third of the potential is energy forests and energy plantations which at present are not economic. One third is used in rural areas as traditional fuel. The remaining third would be available for modern biomass energy conversion. Biomass is assigned an expanding role as a new resource in the world's energy balance. The EU has set a target of doubling the share of renewable energy sources by 2010. For biomass the target is even more ambitious. The challenge for biomass utilization lies in improving the technology for traditional usage and expanding the role into other areas like power production and transportation fuel. Various technologies for biomass utilization are available among those are combustion, gasification, and liquefaction. Researchers have a grand vision in which the chemical elements in the hydrocarbon molecules of biomass are separated and reformed to yield new tailored fuels and form the basis for a new world economy. The vision of a new energy system based on fresh and fossilized biomass to be engineered into an environmentally friendly and sustainable fuel is a conceivable technical reality. One reason for replacing exhaustible fossil fuels with biomass is to reduce carbon emissions. The most efficient carbon dioxide emission reduction comes from replacing brown coal in a steam-electric unit, due to the efficiency of the thermal cycle and the high carbon intensity of the coal. The smallest emission reduction comes from substituting natural gas. (BA)

Potential contribution of biomass to the sustainable energy development

International Nuclear Information System (INIS)

Demirbas, M. Fatih; Balat, Mustafa; Balat, Havva

2009-01-01

Biomass is a renewable energy source and its importance will increase as national energy policy and strategy focuses more heavily on renewable sources and conservation. Biomass is considered the renewable energy source with the highest potential to contribute to the energy needs of modern society for both the industrialized and developing countries worldwide. The most important biomass energy sources are wood and wood wastes, agricultural crops and their waste byproducts, municipal solid waste, animal wastes, waste from food processing, and aquatic plants and algae. Biomass is one potential source of renewable energy and the conversion of plant material into a suitable form of energy, usually electricity or as a fuel for an internal combustion engine, can be achieved using a number of different routes, each with specific pros and cons. Currently, much research has been focused on sustainable and environmental friendly energy from biomass to replace conventional fossil fuels. The main objective of the present study is to investigate global potential and use of biomass energy and its contribution to the sustainable energy development by presenting its historical development.

Technical, economic and environmental potential of co-firing of biomass in coal and natural gas fired power plants in the Netherlands

International Nuclear Information System (INIS)

Van Ree, R.; Korbee, R.; Eenkhoorn, S.; De Lange, T.; Groenendaal, B.

2000-01-01

In this paper the technical, economic, and environmental potential of co-firing of biomass in existing Dutch coal and natural gas fired power plants, and industrial combined-cycles (CC), is addressed. Main criteria that are considered are: the availability and contractibility of biomass for energy purposes; the (technical) operation of the conventional fossil fuel based processes may not be disturbed; the gaseous and liquid plant emissions have to comply to those applicable for power plants/CCs, the commercial applicability of the solid residues may not be negatively influenced; applicable additional biomass conversion technologies must be commercially available; the necessary additional investment costs must be acceptable from an economic point of view, and the co-firing option must result in a substantial CO 2 -emission reduction. The main result of the study described in the paper is the presentation of a clear and founded indication of the total co-firing potential of biomass in existing power plants and industrial CCs in the Netherlands. This potential is determined by considering both technical, economic, and environmental criteria. In spite of the fact that the co-firing potential for the specific Dutch situation is presented, the results of the criteria considered are more generally applicable, and therefore are also very interesting for potential co-firing initiatives outside of the Netherlands

Catalytic Deoxygenation of Biomass Pyrolysis Vapors to Improve Bio-oil Stability

Energy Technology Data Exchange (ETDEWEB)

Dayton, David C. [RTI International, Research Triangle Park, NC (United States)

2016-12-22

The President’s Advanced Energy Initiative called for a change in the way Americans fuel their vehicles to promote improved energy security. Increasing biofuels production from domestic lignocellulosic resources requires advanced technology development to achieve the aggressive targets set forth to reduce motor gasoline consumption by 20% in ten years (by 2017). The U.S. Department of Energy (USDOE) Office of the Biomass Program (currently Bioenergy Technologies Office) is actively funding research and development in both biochemical and thermochemical conversion technologies to accelerate the deployment of biofuels technologies in the near future to meet the goals of the Advanced Energy Initiative. Thermochemical conversion technology options include both gasification and pyrolysis to enable the developing lignocellulosic biorefineries and maximize biomass resource utilization for production of biofuels.

Biodiesel production by direct transesterification of microalgal biomass with co-solvent.

Science.gov (United States)

Zhang, Yan; Li, Ya; Zhang, Xu; Tan, Tianwei

2015-11-01

In this study, a direct transesterification process using 75% ethanol and co-solvent was studied to reduce the energy consumption of lipid extraction process and improve the conversion yield of the microalgae biodiesel. The addition of a certain amount of co-solvent (n-hexane is most preferable) was required for the direct transesterification of microalgae biomass. With the optimal reaction condition of n-hexane to 75% ethanol volume ratio 1:2, mixed solvent dosage 6.0mL, reaction temperature 90°C, reaction time 2.0h and catalyst volume 0.6mL, the direct transesterification process of microalgal biomass resulted in a high conversion yield up to 90.02±0.55wt.%. Copyright © 2015 Elsevier Ltd. All rights reserved.

Unravelling biocomplexity of electroactive biofilms for producing hydrogen from biomass

Energy Technology Data Exchange (ETDEWEB)

Lewis, Alex J. [Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Biosciences Division; Univ. of Tennessee, Knoxville, TN (United States). Bredesen Center for Interdisciplinary Research and Education; Campa, Maria F. [Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Biosciences Division; Univ. of Tennessee, Knoxville, TN (United States). Bredesen Center for Interdisciplinary Research and Education; Univ. of Tennessee, Knoxville, TN (United States). Inst. for Secure and Sustainable Environments; Hazen, Terry C. [Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Biosciences Division; Univ. of Tennessee, Knoxville, TN (United States). Bredesen Center for Interdisciplinary Research and Education; Univ. of Tennessee, Knoxville, TN (United States). Inst. for Secure and Sustainable Environments; Borole, Abhijeet P. [Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Biosciences Division; Univ. of Tennessee, Knoxville, TN (United States). Bredesen Center for Interdisciplinary Research and Education; Univ. of Tennessee, Knoxville, TN (United States). Inst. for Secure and Sustainable Environments

2017-07-11

Nature recruits various types of microbes to transform its waste products into reusable building blocks. In order to develop engineered systems to enable humans to generate useful products from complex sources such as biomass, a better understanding of the synergy between microbial species is necessary. Here we investigate a bioelectrochemical system for conversion of a complex biomass-derived pyrolysis stream into hydrogen via microbial electrolysis. Interaction between the exoelectrogens and fermentative organisms is key in this process. Comparing bioelectroconversion of a switchgrass-derived bio-oil aqueous phase (BOAP) with a model exoelectrogenic substrate, acetic acid, we demonstrate that fermentative breakdown of BOAP to acetate is the limiting step in the syntophic conversion process. The anode microbial community displayed simultaneous conversion of sugar derivatives, phenolic compounds, carboxylic acids, etc. present in BOAP, but at differing rates through division of labor and syntrophic exchange. Maximum removal for BOAP reached 43 mg COD/h vs. 59 mg COD/h for pure acetic acid. Furthermore, maximum hydrogen production for BOAP reached 11 L/L-d vs. 35 L/L-day for pure acetic acid. Coulombic efficiency for both substrates was >80%. Unpoising of the anode haulted exoelectrogenesis and allowed fermentative processes to proceed resulting in acetic acid accumulation at the rate of 8.4 mg/h. Coupled to the simultaneous conversion of compounds present within BOAP, these results support the division of labor and syntrophic interactions suggested here. The hydrogen productivity is the highest achieved to date for a biomass-derived stream. The exoelectrogenic rates achieved signify that commercial feasibility can be achieved if fermentative rates can be improved.

Ethanol from lignocellulosic biomasses

International Nuclear Information System (INIS)

Ricci, E.; Viola, E.; Zimbardi, F.; Braccio, G.; Cuna, D.

2001-01-01

In this report are presented results achieved on the process optimisation of bioethanol production from wheat straw, carried out within the ENEA's project of biomass exploitation for renewable energy. The process consists of three main steps: 1) biomass pretreatment by means of steam explosion; 2) enzymatic hydrolysis of the cellulose fraction; 3) fermentation of glucose. To perform the hydrolysis step, two commercial enzymatic mixtures have been employed, mainly composed by β-glucosidase (cellobiase), endo-glucanase and exo-glucanase. The ethanologenic yeast Saccharomyces cerevisiae has been used to ferment the glucose in he hydrolyzates. Hydrolysis yield of 97% has been obtained with steam exploded wheat straw treated at 220 0 C for 3 minutes and an enzyme to substrate ratio of 4%. It has been pointed out the necessity of washing with water the pretreated what straw, in order to remove the biomass degradation products, which have shown an inhibition effect on the yeast. At the best process conditions, a fermentation yield of 95% has been achieved. In the Simultaneous Saccharification and Fermentation process, a global conversion of 92% has been obtained, which corresponds to the production of about 170 grams of ethanol per kilogram of exploded straw [it

Biomass markets. Growth strategy and challenges for French actors

International Nuclear Information System (INIS)

2015-01-01

This study comprises three reports. The first one is an executive summary which focuses on the main aspects of the evolution of the activity in the biomass sector, and highlights factors of change and their strategic consequences. The second one proposes an overview of the situation of biomass French markets, analyses growth strategies adopted by actors of the biomass sector (development of new production capacities, international growth, development of strategies based on several energies, diversification of prospects, innovation and improvement of installation efficiency), and discusses the main strategic challenges on the medium term. The third report proposes a presentation of the context of French biomass markets (political, regulatory and energetic framework, energetic assessment and assessment of the waste-based sector, economic context, housing stock, and other contextual factors), a presentation of the biomass French market (data for 2005-2013, dynamics of three specific segments: solid biomass, renewable urban wastes, and biogas), and a description of the competitive landscape (economic structure, actors) and of the 15 main actors

LIGNOCELLULOSIC BIOMASS AFTER EXPLOSIVE AUTOHYDROLYSIS AS SUBSTRATE TO BUTANOL OBTAINING

Directory of Open Access Journals (Sweden)

Tigunova

2016-08-01

Full Text Available The aim of the work was investigation of the effect of the explosive autohydrolysis on lignocellulosic biomass (saving, switchgrass biomass for consequent use as a substrate to produce biofuels such as butanol. Butanol-producing strains, switchgrass Panicum virgatum L. biomass and its components after autohydrolysis were used in study. The thermobaric pressure pretreatment of lignocellulosic biomass was carried out using specially designed equipment. The effect of explosive autohydrolysis on lignocellulosic biomass for further use in producing biofuels using microbial conversion was studied. Components of lignocellulosic biomass were fractionated after undergoing thermobaric treatment. The possibility of using different raw material components after using explosive autohydrolysis processing to produce biobutanol was found. Products of switchgrass biomass autohydrolysis were shown to need further purification before fermentation from furfural formed by thermobaric pretreatment and inhibiting the growth of microorganisms. The ability of strains of the genus Clostridium to use cellulose as a substrate for fermentation was proved. It was found that using explosive autohydrolysis pretreatment to savings allowed boosting the butanol accumulation by 2 times.

Chemical coal conversion yesterday, today, and tomorrow; Der Chemierohstoff Kohle: gestern, heute und morgen

Energy Technology Data Exchange (ETDEWEB)

Talbiersky, J. [UCP Chemicals AG, Wien (Austria)

2007-01-15

Shortage in mineral oil and gas as well as a high price level have caused a renaissance in coal conversion technologies, at the end of the 70's. Today we have a similar situation. Now coal coversion technologies will be in the focus again but hopefully as a longterm strategy. The most important coal conversion technologies as liquefaction, gasification, coking and calcium carbide synthesis are discussed regarding their use for the production of chemicals. The most important source for aromatic chemicals from coal is till now coal tar with an availability of 22 Mio. t/a. The manufacturing of coal tar is discussed as an example for making aromatic products from a complex feed stock that you get by the fixed bed gasification, coal liquefaction and coking. Also the special marketing strategy that is necessary to be competitive against products from the petroindustry. It can be expected, that coal gasification as a source for synthesis gas will become more and more important. Synthesis gas is the access to aliphatic hydrocarbons by Fischer Tropsch synthesis and to methanol, a chemical with a high synthetic potential. Also the new hydrothermal carbonization of biomass to synthetic coal is mentioned. (orig.)

Sulfur Tolerant Magnesium Nickel Silicate Catalyst for Reforming of Biomass Gasification Products to Syngas

Directory of Open Access Journals (Sweden)

Scott L. Swartz

2012-04-01

Full Text Available Magnesium nickel silicate (MNS has been investigated as a catalyst to convert tars and light hydrocarbons to syngas (CO and H2 by steam reforming and CO2 reforming in the presence of H2S for biomass gasification process at NexTech Materials. It was observed that complete CH4 conversion could be achieved on MNS catalyst granules at 800–900 °C and a space velocity of 24,000 mL/g/h in a simulated biomass gasification stream. Addition of 10–20 ppm H2S to the feed had no apparent impact on CH4 conversion. The MNS-washcoated monolith also showed high activities in converting methane, light hydrocarbons and tar to syngas. A 1200 h test without deactivation was achieved on the MNS washcoated monolith in the presence of H2S and/or NH3, two common impurities in gasified biomass. The results indicate that the MNS material is a promising catalyst for removal of tar and light hydrocarbons from biomass gasified gases, enabling efficient use of biomass to produce power, liquid fuels and valuable chemicals.

Renewable energy from corn residues by thermochemical conversion

Science.gov (United States)

Yu, Fei

Declining fossil oil reserve, skyrocket price, unsecured supplies, and environment pollution are among the many energy problems we are facing today. It is our conviction that renewable energy is a solution to these problems. The long term goal of the proposed research is to develop commercially practical technologies to produce energy from renewable resources. The overall objective of my research is to study and develop thermochemical processes for converting bulky and low-energy-density biomass materials into bio-fuels and value-added bio-products. The rationale for the proposed research is that, once such processes are developed, processing facility can be set up on or near biomass product sites, reducing the costs associated with transport of bulky biomass which is a key technical barrier to biomass conversion. In my preliminary research, several conversion technologies including atmospheric pressure liquefaction, high pressure liquefaction, and microwave pyrolysis have been evaluated. Our data indicated that microwave pyrolysis had the potential to become a simple and economically viable biomass conversion technology. Microwave pyrolysis is an innovative process that provides efficient and uniform heating, and are robust to type, size and uniformity of feedstock and therefore suitable for almost any waste materials without needing to reduce the particle size. The proposed thesis focused on in-depth investigations of microwave pyrolysis of corn residues. My first specific aim was to examine the effects of processing parameters on product yields. The second specific research aim was to characterize the products (gases, bio-oils, and solid residues), which was critical to process optimization and product developments. Other research tasks included conducting kinetic modeling and preliminary mass and energy balance. This study demonstrated that microwave pyrolysis could be optimized to produce high value syngas, liquid fuels and pyrolytic carbons, and had a great

The carbon dioxide gasification characteristics of biomass char samples and their effect on coal gasification reactivity during co-gasification.

Science.gov (United States)

Mafu, Lihle D; Neomagus, Hein W J P; Everson, Raymond C; Okolo, Gregory N; Strydom, Christien A; Bunt, John R

2018-06-01

The carbon dioxide gasification characteristics of three biomass char samples and bituminous coal char were investigated in a thermogravimetric analyser in the temperature range of 850-950 °C. Char SB exhibited higher reactivities (R i , R s , R f ) than chars SW and HW. Coal char gasification reactivities were observed to be lower than those of the three biomass chars. Correlations between the char reactivities and char characteristics were highlighted. The addition of 10% biomass had no significant impact on the coal char gasification reactivity. However, 20 and 30% biomass additions resulted in increased coal char gasification rate. During co-gasification, chars HW and SW caused increased coal char gasification reactivity at lower conversions, while char SB resulted in increased gasification rates throughout the entire conversion range. Experimental data from biomass char gasification and biomass-coal char co-gasification were well described by the MRPM, while coal char gasification was better described by the RPM. Copyright © 2018 Elsevier Ltd. All rights reserved.

Content and context in conversations : the role of social and situational signals in conversation structure

OpenAIRE

Bonin, Francesca

2016-01-01

The increasing growth of multimodal material creates, nowadays, a renewed interest in innovative approaches to information extraction from meetings and multiparty conversations; those approaches make use of various multimodal sources such as video, audio and resulting transcripts from which information can be derived to produce a richer semantic analysis of the social interaction. Social interactions are co-constructed by a combination of contextual and linguistic aspects. However, while the ...

Maize feedstocks with improved digestibility reduce the costs and environmental impacts of biomass pretreatment and saccharification

NARCIS (Netherlands)

Torres Salvador, A.F.; Slegers, Ellen; Noordam-Boot, C.M.M.; Dolstra, O.; Vlaswinkel, L.; Boxtel, van A.J.B.; Visser, R.G.F.; Trindade, L.M.

2016-01-01

Background - Despite the recognition that feedstock composition influences biomass conversion efficiency, limited information exists as to how bioenergy crops with reduced recalcitrance can improve the economics and sustainability of cellulosic fuel conversion platforms. We have compared the

Wood-energy in Normandy: situation and objectives for 2013, situation and objectives for 2020

International Nuclear Information System (INIS)

Cousin, Stephane; Defaye, Serge; Fleury, Mathieu; Plumail, Dominique

2008-12-01

In the 2013 issue, this publication gives an assessment of quantity of wood used to produce energy, and comments its origin, gives an assessment of annually available biomass in Normandy, outlines growth perspectives due to the exploitation of new resources. The second one, published in 2008, analyses perspectives by 2020. It analyses wood and forest resources, the present and future situation regarding uses of wood in the region, discusses how to mobilise new wood resources and which organisation could guarantee this mobilisation

A comprehensive review of biomass resources and biofuels potential in Ghana

Energy Technology Data Exchange (ETDEWEB)

Duku, Moses Hensley [School of Engineering Sciences, University of Southampton, Southampton, S017 1BJ (United Kingdom); Institute of Industrial Research, Council for Scientific and Industrial Research, P. Box LG 576, Legon (Ghana); Gu, Sai [School of Engineering Sciences, University of Southampton, Southampton, S017 1BJ (United Kingdom); Hagan, Essel Ben [Institute of Industrial Research, Council for Scientific and Industrial Research, P. Box LG 576, Legon (Ghana)