WorldWideScience

Sample records for biogas reactor performance

  1. Reactor performances and microbial communities of biogas reactors: effects of inoculum sources.

    Science.gov (United States)

    Han, Sheng; Liu, Yafeng; Zhang, Shicheng; Luo, Gang

    2016-01-01

    Anaerobic digestion is a very complex process that is mediated by various microorganisms, and the understanding of the microbial community assembly and its corresponding function is critical in order to better control the anaerobic process. The present study investigated the effect of different inocula on the microbial community assembly in biogas reactors treating cellulose with various inocula, and three parallel biogas reactors with the same inoculum were also operated in order to reveal the reproducibility of both microbial communities and functions of the biogas reactors. The results showed that the biogas production, volatile fatty acid (VFA) concentrations, and pH were different for the biogas reactors with different inocula, and different steady-state microbial community patterns were also obtained in different biogas reactors as reflected by Bray-Curtis similarity matrices and taxonomic classification. It indicated that inoculum played an important role in shaping the microbial communities of biogas reactor in the present study, and the microbial community assembly in biogas reactor did not follow the niche-based ecology theory. Furthermore, it was found that the microbial communities and reactor performances of parallel biogas reactors with the same inoculum were different, which could be explained by the neutral-based ecology theory and stochastic factors should played important roles in the microbial community assembly in the biogas reactors. The Bray-Curtis similarity matrices analysis suggested that inoculum affected more on the microbial community assembly compared to stochastic factors, since the samples with different inocula had lower similarity (10-20 %) compared to the samples from the parallel biogas reactors (30 %).

  2. Effect of post-digestion temperature on serial CSTR biogas reactor performance

    DEFF Research Database (Denmark)

    Boe, Kanokwan; Karakashev, Dimitar Borisov; Trably, Eric

    2009-01-01

    The effect of post-digestion temperature on a lab-scale serial continuous-flow stirred tank reactor (CSTR) system performance was investigated. The system consisted of a main reactor operated at 55 degrees C with hydraulic retention time (HRT) of 15 days followed by post-digestion reactors with HRT...... gave extra biogas production of 11.7%, 8.4% and 1.2%, respectively. The post-digester operated at 55 degrees C had the highest biogas production and was the most stable in terms of low VFA concentrations. The specific methanogenic activity tests revealed that the main reactor and the post...

  3. Effect of post-digestion temperature on serial CSTR biogas reactor performance.

    Science.gov (United States)

    Boe, Kanokwan; Karakashev, Dimitar; Trably, Eric; Angelidaki, Irini

    2009-02-01

    The effect of post-digestion temperature on a lab-scale serial continuous-flow stirred tank reactor (CSTR) system performance was investigated. The system consisted of a main reactor operated at 55 degrees C with hydraulic retention time (HRT) of 15 days followed by post-digestion reactors with HRT of 5.3 days. Three post-digestion temperatures (55 degrees C, 37 degrees C and 15 degrees C) were compared in terms of biogas production, process stability, microbial community and methanogenic activity. The results showed that the post-digesters operated at 55 degrees C, 37 degrees C and 15 degrees C gave extra biogas production of 11.7%, 8.4% and 1.2%, respectively. The post-digester operated at 55 degrees C had the highest biogas production and was the most stable in terms of low VFA concentrations. The specific methanogenic activity tests revealed that the main reactor and the post-digester operated at 55 degrees C and 37 degrees C had very active acidogens and methanogens. In contrast, very low methanogenic activity was observed at 15 degrees C.

  4. Methanogenesis in Thermophilic Biogas Reactors

    DEFF Research Database (Denmark)

    Ahring, Birgitte Kiær

    1995-01-01

    Methanogenesis in thermophilic biogas reactors fed with different wastes is examined. The specific methanogenic activity with acetate or hydrogen as substrate reflected the organic loading of the specific reactor examined. Increasing the loading of thermophilic reactors stabilized the process...... as indicated by a lower concentration of volatile fatty acids in the effluent from the reactors. The specific methanogenic activity in a thermophilic pilot-plant biogas reactor fed with a mixture of cow and pig manure reflected the stability of the reactor. The numbers of methanogens counted by the most...... against Methanothrix soehngenii or Methanothrix CALS-I in any of the thermophilic biogas reactors examined. Studies using 2-14C-labeled acetate showed that at high concentrations (more than approx. 1 mM) acetate was metabolized via the aceticlastic pathway, transforming the methyl-group of acetate...

  5. Performance and microbial community analysis of the anaerobic reactor with coke oven gas biomethanation and in situ biogas upgrading

    DEFF Research Database (Denmark)

    Wang, Wen; Xie, Li; Luo, Gang;

    2013-01-01

    (HFM). With pH control at 8.0, the added H2 and CO were fully consumed and no negative effects on the anaerobic degradation of sewage sludge were observed. The maximum CH4 content in the biogas was 99%. The addition of SCOG resulted in enrichment and dominance of homoacetogenetic genus Treponema......A new method for simultaneous coke oven gas (COG) biomethanation and in situ biogas upgrading in anaerobic reactor was developed in this study. The simulated coke oven gas (SCOG) (92% H2 and 8% CO) was injected directly into the anaerobic reactor treating sewage sludge through hollow fiber membrane...

  6. Effect of biogas sparging on the performance of bio-hydrogen reactor over a long-term operation

    Science.gov (United States)

    Nualsri, Chatchawin; Kongjan, Prawit; Imai, Tsuyoshi

    2017-01-01

    This study aimed to enhance hydrogen production from sugarcane syrup by biogas sparging. Two-stage continuous stirred tank reactor (CSTR) and upflow anaerobic sludge blanket (UASB) reactor were used to produce hydrogen and methane, respectively. Biogas produced from the UASB was used to sparge into the CSTR. Results indicated that sparging with biogas increased the hydrogen production rate (HPR) by 35% (from 17.1 to 23.1 L/L.d) resulted from a reduction in the hydrogen partial pressure. A fluctuation of HPR was observed during a long term monitoring because CO2 in the sparging gas and carbon source in the feedstock were consumed by Enterobacter sp. to produce succinic acid without hydrogen production. Mixed gas released from the CSTR after the sparging can be considered as bio-hythane (H2+CH4). In addition, a continuous sparging biogas into CSTR release a partial pressure in the headspace of the methane reactor. In consequent, the methane production rate is increased. PMID:28207755

  7. Effect of biogas sparging on the performance of bio-hydrogen reactor over a long-term operation.

    Science.gov (United States)

    Nualsri, Chatchawin; Kongjan, Prawit; Reungsang, Alissara; Imai, Tsuyoshi

    2017-01-01

    This study aimed to enhance hydrogen production from sugarcane syrup by biogas sparging. Two-stage continuous stirred tank reactor (CSTR) and upflow anaerobic sludge blanket (UASB) reactor were used to produce hydrogen and methane, respectively. Biogas produced from the UASB was used to sparge into the CSTR. Results indicated that sparging with biogas increased the hydrogen production rate (HPR) by 35% (from 17.1 to 23.1 L/L.d) resulted from a reduction in the hydrogen partial pressure. A fluctuation of HPR was observed during a long term monitoring because CO2 in the sparging gas and carbon source in the feedstock were consumed by Enterobacter sp. to produce succinic acid without hydrogen production. Mixed gas released from the CSTR after the sparging can be considered as bio-hythane (H2+CH4). In addition, a continuous sparging biogas into CSTR release a partial pressure in the headspace of the methane reactor. In consequent, the methane production rate is increased.

  8. Performance evaluation of biogas burners

    Energy Technology Data Exchange (ETDEWEB)

    Chandra, A.; Tiwari, G.N.; Srivastava, V.K.; Yadav, Y.P. (Indian Inst. of Tech., New Delhi (India). Centre of Energy Studies)

    1991-01-01

    The results of testing some biogas burners of various brands are presented. A wide variation is found in their performance under similar conditions of testing. Parametric investigations have also been carried out on a typical biogas burner. These investigations reveal that the burner efficiency is a strong function of biogas flow pressure, pan-size and its position over the burner head. (author).

  9. Impact of the substrate loading regime and phosphoric acid supplementation on performance of biogas reactors and microbial community dynamics during anaerobic digestion of chicken wastes.

    Science.gov (United States)

    Belostotskiy, Dmitry E; Ziganshina, Elvira E; Siniagina, Maria; Boulygina, Eugenia A; Miluykov, Vasili A; Ziganshin, Ayrat M

    2015-10-01

    This study evaluates the effects of increasing organic loading rate (OLR) and decreasing hydraulic retention time (HRT) as well as phosphoric acid addition on mesophilic reactors' performance and biogas production from chicken wastes. Furthermore, microbial community composition in reactors was characterized by a 16S rRNA gene-based pyrosequencing analysis. Each step of increasing OLR impacted on the activity of microorganisms what caused a temporary decrease in biogas production. The addition of phosphoric acid resulted in the increased biogas production with values between 361 and 447 mL g(VS)(-1) from day 61 to day 74 compared to control reactor (309-350 mL g(VS)(-1)). With reactors' operation, Bacteroidetes phylotypes were noticeably replaced with Firmicutes representatives, and significant increase of Clostridium sp. was identified. Within Euryarchaeota, Methanosarcina sp. dominated in all analyzed samples, in which high ammonium levels were detected (3.4-4.9 NH4(+)-N g L(-1)). These results can help in better understanding the anaerobic digestion process of simultaneously ammonium/phosphate-rich substrates.

  10. Performance of a novel two-phase continuously fed leach bed reactor for demand-based biogas production from maize silage.

    Science.gov (United States)

    Linke, Bernd; Rodríguez-Abalde, Ángela; Jost, Carsten; Krieg, Andreas

    2015-02-01

    This study investigated the potential of producing biogas on demand from maize silage using a novel two-phase continuously fed leach bed reactor (LBR) which is connected to an anaerobic filter (AF). Six different feeding patterns, each for 1week, were studied at a weekly average of a volatile solids (VS) loading rate of 4.5 g L(-1) d(-1) and a temperature of 38°C. Methane production from the LBR and AF responded directly proportional to the VS load from the different daily feeding and resulted in an increase up to 50-60% per day, compared to constant feeding each day. The feeding patterns had no impact on VS methane yield which corresponded on average to 330 L kg(-1). In spite of some daily shock loadings, carried out during the different feeding patterns study, the reactor performance was not affected. A robust and reliable biogas production from stalky biomass was demonstrated.

  11. Realtime control of biogas reactors. Technical report

    Energy Technology Data Exchange (ETDEWEB)

    Poulsen, Allan K.

    2010-12-15

    In this project several online methods were connected to a biogas pilot plant designed and built by Xergi A/S (Foulum, Denmark). The pilot plant was composed of two stainless steel tanks used as substrate storage and as digester, respectively. The total volume of the reactor tank was 300 L, the working volume 200 L and the headspace volume 100 L. The process temperature in the biogas reactor was maintained at 52 {+-} 0.5 deg. C during normal operating conditions. The biogas production was measured with a flow meter and a controller was used for automatic control of temperature, effluent removal, feeding and for data logging. A NIRS (near infrared spectrometer) was connected to a recurrent loop measuring on the slurry while a {mu}-GC (micro gas chromatograph) and a MIMS (membrane inlet mass spectrometer) enabled online measurements of the gas phase composition. During the project period three monitoring campaigns were accomplished. The loading rate of the biogas reactor was increased stepwise during the periods while the process was monitored. In the first two campaigns the load was increased by increasing the mass of organic material added to the reactor each day. However, this increasing amount changed the retention time in the reactor and in order to keep the retention time constant an increasing amount of inhibitor of the microbial process was instead added in the third campaign and as such maintaining a constant organic load mass added to the reactor. The effect is similar to an increase in process load, while keeping the load of organic material and hence retention time constant. Methods have been developed for the following online technologies and each technology has been evaluated with regard to future use as a tool for biogas process monitoring: 1) {mu}-GC was able to quantitative monitor important gas phase parameters in a reliable, fast and low-maintenance way. 2) MIMS was able to quantitative monitor gas phase composition in a reliable and fast manner

  12. Biogas production from UASB and polyurethane carrier reactors treating sisal processing wastewater

    Energy Technology Data Exchange (ETDEWEB)

    Rubindamayugi, M.S.T.; Salakana, L.K.P. [Univ. of Dar es Salaam, Faculty of Science, Applied Microbiology Unit (Tanzania, United Republic of)

    1997-12-31

    The fundamental benefits which makes anaerobic digestion technology (ADT) attractive to the poor developing include the low cost and energy production potential of the technology. In this study the potential of using UASB reactor and Polyurethane Carrier Reactor (PCR) as pollution control and energy recovery systems from sisal wastewater were investigated in lab-scale reactors. The PCR demonstrated the shortest startup period, whereas the UASB reactor showed the highest COD removal efficiency 79%, biogas production rate (4.5 l biogas/l/day) and process stability than the PCR under similar HRT of 15 hours and OLR of 8.2 g COD/l/day. Both reactor systems became overloaded at HRT of 6 hours and OLR of 15.7 g COD/l/day, biogas production ceased and reactors acidified to pH levels which are inhibiting to methanogenesis. Based on the combined results on reactor performances, the UASB reactor is recommended as the best reactor for high biogas production and treatment efficiency. It was estimated that a large-scale UASB reactor can be designed under the same loading conditions to produce 2.8 m{sup 3} biogas form 1 m{sup 3} of wastewater of 5.16 kg COD/m{sup 3}. Wastewater from one decortication shift can produce 9,446 m{sup 3} og biogas. The energy equivalent of such fuel energy is indicated. (au)

  13. Thermal pretreatment of the solid fraction of manure: Impact on the biogas reactor performance and microbial community

    DEFF Research Database (Denmark)

    Mladenovska, Z; Hartmann, H.; Kvist, T.

    2006-01-01

    and an improved removal of the volatile solids (VS). The properties of microbial communities of both reactors were analysed. The specific methanogenic activity (SMA) test showed that both biomasses had significant activity towards hydrogen and formate, while the activity with the VFA - acetate, propionate...... of methane yield. The performances of two thermophilic continuously stirred tank reactors (CSTR) treating manure with solid fraction pretreated for 40 minutes at 140 degrees C and non-treated manure were compared. The digester fed with the thermally pretreated manure had a higher methane productivity...

  14. Microbial analysis in biogas reactors suffering by foaming incidents

    DEFF Research Database (Denmark)

    Kougias, Panagiotis; De Francisci, Davide; Treu, Laura

    2014-01-01

    Foam formation can lead to total failure of digestion process in biogas plants. In the present study, possible correlation between foaming and the presence of specific microorganisms in biogas reactors was elucidated. The microbial ecology of continuous fed digesters overloaded with proteins...

  15. Biogas upgrading by injection of hydrogen in a two-stage Continuous Stirred-Tank Reactor system

    DEFF Research Database (Denmark)

    Bassani, Ilaria; Kougias, Panagiotis; Treu, Laura;

    An innovative method for biogas upgrading (i.e. CH4 content more than 90%) combines the coupling of H2, which could be produced by water electrolysis using surplus renewable electricity produced from wind mills, with the CO2 of the biogas. CO2 is biologically converted to CH4 by hydrogenotrophic...... methanogens. In this study, a novel serial biogas reactor system is presented, in which the produced biogas from the first stage reactor was introduced in the second stage, where also H2 was injected. The effects of the H2 addition on the process performance and on the microbial community were investigated...

  16. Anaerobic digestion of manure and mixture of manure with lipids: biogas reactor performance and microbial community analysis

    DEFF Research Database (Denmark)

    Mladenovska, Zuzana; Dabrowski, Slawomir; Ahring, Birgitte Kiær

    2003-01-01

    Anaerobic digestion of cattle manure and a mixture of cattle manure with glycerol trioleate (GTO) was studied in lab-scale, continuously stirred tank reactors (CSTR) operated at 37degreesC. The reactor. codigesting manure and lipids exhibited a significantly higher specific methane yield...... and a higher removal of VS than the reactor treating manure. Microbial population analysis done by cultivation - most probable number (MPN) test and specific methanogenic activity (SMA) measurement, revealed higher MPN and increased SMA of methanogenic populations of biomass from the reactor codigesting manure...... and lipids. Spatial microbial distribution and activity was studied in digested materials fractionated into size of particles > 200 mum, 50-200 mum and 0.45-50 mum. With manure, the main pool of methanogenic activity from propionate, butyrate and hydrogen was associated with the particles > 200 mum, while...

  17. Microbial analysis in biogas reactors suffering by foaming incidents.

    Science.gov (United States)

    Kougias, Panagiotis G; De Francisci, Davide; Treu, Laura; Campanaro, Stefano; Angelidaki, Irini

    2014-09-01

    Foam formation can lead to total failure of digestion process in biogas plants. In the present study, possible correlation between foaming and the presence of specific microorganisms in biogas reactors was elucidated. The microbial ecology of continuous fed digesters overloaded with proteins, lipids and carbohydrates before and after foaming incidents was characterized using 16S rRNA gene sequencing. Moreover, the microbial diversity between the liquid and foaming layer was assessed. A number of genera that are known to produce biosurfactants, contain mycolic acid in their cell wall, or decrease the surface tension of the media, increased their relative abundance after foam formation. Finally, a microorganism similar to widely known foaming bacteria (Nocardia and Desulfotomaculum) was found to increase its relative abundance in all reactors once foam was observed, regardless of the used substrate. These findings suggest that foaming and specific microorganisms might have direct association which requires to be further investigated.

  18. Effect of reactor configuration on biogas production from wheat straw hydrolysate.

    Science.gov (United States)

    Kaparaju, Prasad; Serrano, María; Angelidaki, Irini

    2009-12-01

    The potential of wheat straw hydrolysate for biogas production was investigated in continuous stirred tank reactor (CSTR) and up-flow anaerobic sludge bed (UASB) reactors. The hydrolysate originated as a side stream from a pilot plant pretreating wheat straw hydrothermally (195 degrees C for 10-12 min) for producing 2nd generation bioethanol [Kaparaju, P., Serrano, M., Thomsen, A.B., Kongjan, P., Angelidaki, I., 2009. Bioethanol, biohydrogen and biogas production from wheat straw in a biorefinery concept. Bioresource Technology 100 (9), 2562-2568]. Results from batch assays showed that hydrolysate had a methane potential of 384 ml/g-volatile solids (VS)(added). Process performance in CTSR and UASB reactors was investigated by varying hydrolysate concentration and/or organic loading rate (OLR). In CSTR, methane yields increased with increase in hydrolysate concentration and maximum yield of 297 ml/g-COD was obtained at an OLR of 1.9 g-COD/l d and 100% (v/v) hydrolysate. On the other hand, process performance and methane yields in UASB were affected by OLR and/or substrate concentration. Maximum methane yields of 267 ml/g-COD (COD removal of 72%) was obtained in UASB reactor when operated at an OLR of 2.8 g-COD/l d but with only 10% (v/v) hydrolysate. However, co-digestion of hydrolysate with pig manure (1:3 v/v ratio) improved the process performance and resulted in methane yield of 219 ml/g-COD (COD removal of 72%). Thus, anaerobic digestion of hydrolysate for biogas production was feasible in both CSTR and UASB reactor types. However, biogas process was affected by the reactor type and operating conditions.

  19. Counteracting foaming caused by lipids or proteins in biogas reactors using rapeseed oil or oleic acid as antifoaming agents

    DEFF Research Database (Denmark)

    Kougias, Panagiotis; Boe, Kanokwan; Einarsdottir, E. S.;

    2015-01-01

    Foaming is one of the major operational problems in biogas plants, and dealing with foaming incidents is still based on empirical practices. Various types of antifoams are used arbitrarily to combat foaming in biogas plants, but without any scientific support this action can lead to serious...... deterioration of the methanogenic process. Many commercial antifoams are derivatives of fatty acids or oils. However, it is well known that lipids can induce foaming in manure based biogas plants. This study aimed to elucidate the effect of rapeseed oil and oleic acid on foam reduction and process performance...... in biogas reactors fed with protein or lipid rich substrates. The results showed that both antifoams efficiently suppressed foaming. Moreover rapeseed oil resulted in stimulation of the biogas production. Finally, it was reckoned that the chemical structure of lipids, and more specifically their carboxylic...

  20. Integrated biogas upgrading and hydrogen utilization in an anaerobic reactor containing enriched hydrogenotrophic methanogenic culture

    DEFF Research Database (Denmark)

    Luo, Gang; Angelidaki, Irini

    2012-01-01

    the existing natural gas grid. The current study presents a new biological method for biogas upgrading in a separate biogas reactor, containing enriched hydrogenotrophic methanogens and fed with biogas and hydrogen. Both mesophilic- and thermophilic anaerobic cultures were enriched to convert CO2 to CH4...... by PCR–DGGE. Nonetheless, they all belonged to the order Methanobacteriales, which can mediate hydrogenotrophic methanogenesis. Biogas upgrading was then tested in a thermophilic anaerobic reactor under various operation conditions. By continuous addition of hydrogen in the biogas reactor, high degree......Biogas produced by anaerobic digestion, is mainly used in a gas motor for heat and electricity production. However, after removal of CO2, biogas can be upgraded to natural gas quality, giving more utilization possibilities, such as utilization as autogas, or distant utilization by using...

  1. Hydrogenotrophic methanogens dominate in biogas reactors fed with defined substrates.

    Science.gov (United States)

    Kampmann, K; Ratering, S; Baumann, R; Schmidt, M; Zerr, W; Schnell, S

    2012-09-01

    Methanogenic communities in 200L biogas reactors containing liquid manure were investigated for 33 d. The reactors were consecutively fed with casein, starch and cream. Real-time PCR with primers targeting the gene for methyl coenzyme-M reductase (mcrA) resulted in copy numbers of up to 2.1×10(9) g dry mass(-1). Single strand conformation polymorphism (SSCP) analysis revealed a stable community consisting of few hydrogenotrophic methanogens. One of the two most abundant species was closely related to Methanospirillum hungatei, whereas the other one was only distantly related to other methanogens, with Methanopyrus kandleri being the closest cultivated relative. Most probable number (MPN) cultivations were accomplished with a sample from a 600 m(3) reactor from which all manures used in the experiments originated, and equal cell counts of ca. 10(9) g dry mass(-1) were found for cultivations with acetate, H(2) and methanol. SSCP analysis of these samples and sequencing of the DNA bands identified different hydrogenotrophic methanogens in all samples, and acetoclastic methanogens closely related to Methanosarcina mazei in the samples cultivated with acetate and methanol. As the acetoclastic species were not found in any other SSCP sample, it was supposed that the ammonia values in the manure of the laboratory biogas reactor, which ranged from 2.48 to 3.61 g NH(4)-NL(-1), inhibited the growth of the acetoclastic methanogens.

  2. Microbial dynamics in a glycolate fed biogas reactor influenced by abiotic parameters

    OpenAIRE

    Reinert, Susann

    2015-01-01

    Much research was performed in order to find alternative energy sources. In the new concept presented in this thesis, methane was produced by a microbial consortium which is fed only by glycolate excreted by photosynthetic algae. It was unknown how the biogas production and the process stability are influenced by certain parameter shifts in glycolate feed, pH of the feed, oxygen input and temperature. Therefore, different parameter changes were applied to the reactor...

  3. Bioaugmentation of syntrophic acetate-oxidizing culture in biogas reactors exposed to increasing levels of ammonia.

    Science.gov (United States)

    Westerholm, Maria; Levén, Lotta; Schnürer, Anna

    2012-11-01

    The importance of syntrophic acetate oxidation for process stability in methanogenic systems operating at high ammonia concentrations has previously been emphasized. In this study we investigated bioaugmentation of syntrophic acetate-oxidizing (SAO) cultures as a possible method for decreasing the adaptation period of biogas reactors operating at gradually increased ammonia concentrations (1.5 to 11 g NH(4)(+)-N/liter). Whole stillage and cattle manure were codigested semicontinuously for about 460 days in four mesophilic anaerobic laboratory-scale reactors, and a fixed volume of SAO culture was added daily to two of the reactors. Reactor performance was evaluated in terms of biogas productivity, methane content, pH, alkalinity, and volatile fatty acid (VFA) content. The decomposition pathway of acetate was analyzed by isotopic tracer experiments, and population dynamics were monitored by quantitative PCR analyses. A shift in dominance from aceticlastic methanogenesis to SAO occurred simultaneously in all reactors, indicating no influence by bioaugmentation on the prevailing pathway. Higher abundances of Clostridium ultunense and Tepidanaerobacter acetatoxydans were associated with bioaugmentation, but no influence on Syntrophaceticus schinkii or the methanogenic population was distinguished. Overloading or accumulation of VFA did not cause notable dynamic effects on the population. Instead, the ammonia concentration had a substantial impact on the abundance level of the microorganisms surveyed. The addition of SAO culture did not affect process performance or stability against ammonia inhibition, and all four reactors deteriorated at high ammonia concentrations. Consequently, these findings further demonstrate the strong influence of ammonia on the methane-producing consortia and on the representative methanization pathway in mesophilic biogas reactors.

  4. Biogas and methane production in an aerobic reactor; Produccion de biogas y metano en un reactor anaerobio UASB

    Energy Technology Data Exchange (ETDEWEB)

    Vazquez Borges, E.; Mendez Novelo, R.; Magana Pietra, A.

    1998-06-01

    On the basis of the results obtained during the evaluation of an anaerobic digester in treating pig farm sewage, mathematical models were constructed predicting the system`s efficiency in producing biogas from such waste, and the methane content of this gas, as a function of the influent`s hydraulic retention time(HRT) and chemical oxygen demand (COD). The experimental device consisted of a UASB reactor at the bottom and a high-rate sedimentator at the top with a total operational volume of 534 litres. The results obtained to establish the critical operating parameters are reported. The production of biogas was 259 1/m``3 and methane 217 1/m``3 with an HRT of 1.3 days when a load of 3.1 kg-COD/m``3 day was applied. The mathematical models presented analyses biogas production as a variable response and the influents` HRT and COD as independent variables to assess the efficiency of the system. (Author) 13 refs.

  5. Antifoaming effect of chemical compounds in manure biogas reactors.

    Science.gov (United States)

    Kougias, P G; Tsapekos, P; Boe, K; Angelidaki, I

    2013-10-15

    A precise and efficient antifoaming control strategy in bioprocesses is a challenging task as foaming is a very complex phenomenon. Nevertheless, foam control is necessary, as foam is a major operational problem in biogas reactors. In the present study, the effect of 14 chemical compounds on foam reduction was evaluated at concentration of 0.05%, 0.1% and 0.5% v/v(sample), in raw and digested manure. Moreover, two antifoam injection methods were compared for foam reduction efficiency. Natural oils (rapeseed and sunflower oil), fatty acids (oleic, octanoic and derivative of natural fatty acids), siloxanes (polydimethylsiloxane) and ester (tributylphosphate) were found to be the most efficient compounds to suppress foam. The efficiency of antifoamers was dependant on their physicochemical properties and greatly correlated to their chemical characteristics for dissolving foam. The antifoamers were more efficient in reducing foam when added directly into the liquid phase rather than added in the headspace of the reactor.

  6. Solutions for Foaming Problems in Biogas Reactors Using Natural Oils or Fatty Acids as Defoamers

    DEFF Research Database (Denmark)

    Kougias, Panagiotis; Boe, Kanokwan; Angelidaki, Irini

    2015-01-01

    results from our previous extensive research along with some unpublished data on defoaming by rapeseed oil and oleic acid in manure-based biogas reactors. It was found that both compounds exhibited remarkable defoaming efficiency ranging from 30 to 57% in biogas reactors suffering from foaming problems...... promoted by the addition of protein, lipid, or carbohydrate co-substrates. However, in most cases, the defoaming efficiency of rapeseed oil was greater than that of oleic acid, and therefore, rapeseed oil is recommended to be used in biogas reactors to solve foaming problems....

  7. Foam suppression in overloaded manure-based biogas reactors using antifoaming agents

    DEFF Research Database (Denmark)

    Kougias, Panagiotis; Boe, Kanokwan; Tsapekos, Panagiotis

    2014-01-01

    Foam control is an imperative need in biogas plants, as foaming is a major operational problem. In the present study, the effect of oils (rapeseed oil, oleic acid, and octanoic acid) and tributylphosphate on foam reduction and process performance in batch and continuous manure-based biogas reactors...... was investigated. The compounds were tested in dosages of 0.05%, 0.1% and 0.5% v/vfeed. The results showed that rapeseed oil was most efficient to suppress foam at the dosage of 0.05% and 0.1% v/vfeed, while octanoic acid was most efficient to suppress foam at dosage of 0.5% v/vfeed. Moreover, the addition...

  8. Ex-situ biogas upgrading and enhancement in different reactor systems

    DEFF Research Database (Denmark)

    Kougias, Panagiotis; Treu, Laura; Benavente, Daniela Peñailillo;

    2017-01-01

    Biogas upgrading is envisioned as a key process for clean energy production. The current study evaluates the efficiency of different reactor configurations for ex-situ biogas upgrading and enhancement, in which externally provided hydrogen and carbon dioxide were biologically converted to methane...... and Methanoculleus genera. Methanothermobacter thermautotrophicus was the predominant methanogen in the biofilm formed on top of the diffuser surface in the bubble column reactor....

  9. Simultaneous hydrogen utilization and in situ biogas upgrading in an anaerobic reactor

    DEFF Research Database (Denmark)

    Luo, Gang; Johansson, Sara; Boe, Kanokwan;

    2011-01-01

    . The methane production rate of the reactor with H2 addition was 22% higher, compared to the control reactor only fed with manure. The CO2 content in the produced biogas was only 15%, while it was 38% in the control reactor. However, the addition of hydrogen resulted in increase of pH (from 8.0 to 8.3) due......The possibility of converting hydrogen to methane and simultaneous upgrading of biogas was investigated in both batch tests and fully mixed biogas reactor, simultaneously fed with manure and hydrogen. Batch experiments showed that hydrogen could be converted to methane by hydrogenotrophic...... mixing intensity (shaking speed 300 rpm). Continuous addition of hydrogen (flow rate of 28.6 mL/(L/h)) to an anaerobic reactor fed with manure, showed that more than 80% of the hydrogen was utilized. The propionate and butyrate level in the reactor was not significantly affected by the hydrogen addition...

  10. Influence of the biogas reburning for reducing nitric oxide emissions in an alundum-tube reactor

    Science.gov (United States)

    Zhao, Jie; Wang, Qingcheng; Yu, Lihui; Wu, Liyan

    2016-05-01

    The experimental study on reburning reduction reaction between biogas and NO is very important in de-NOx technology. The reburning experiments by the simulated biogas with different operation variables have been performed in an alundum-tube reactor. Results showed that the uppermost constituent in NO-reduction was CH4, H2 second, and NO-reduction by CO in biogas reburning was negligible at the same conditions. In the condition of oxygen-poor, H2 could promote CH4 oxidation and enhance the concentration of CH3 radicals, thereby increasing the reduction efficiency of NO accordingly. At the same temperature, with the increase of stoichiometric ratio, it would increase O radicals and decrease NO reduction efficiency. With the increase of reaction temperature, the reduction efficiency behaved a trend of first increased then decreased at the same stoichiometric ratio, and obtained the maximum value 51.38% at the condition of 1200 °C and λ = 0.6. Additionally, increasing the NO input concentration also could improve the reduction efficiency under the condition of fuel-rich.

  11. Integrated biogas upgrading and hydrogen utilization in an anaerobic reactor containing enriched hydrogenotrophic methanogenic culture.

    Science.gov (United States)

    Luo, Gang; Angelidaki, Irini

    2012-11-01

    Biogas produced by anaerobic digestion, is mainly used in a gas motor for heat and electricity production. However, after removal of CO(2) , biogas can be upgraded to natural gas quality, giving more utilization possibilities, such as utilization as autogas, or distant utilization by using the existing natural gas grid. The current study presents a new biological method for biogas upgrading in a separate biogas reactor, containing enriched hydrogenotrophic methanogens and fed with biogas and hydrogen. Both mesophilic- and thermophilic anaerobic cultures were enriched to convert CO(2) to CH(4) by addition of H(2) . Enrichment at thermophilic temperature (55°C) resulted in CO(2) and H(2) bioconversion rate of 320 mL CH(4) /(gVSS h), which was more than 60% higher than that under mesophilic temperature (37°C). Different dominant species were found at mesophilic- and thermophilic-enriched cultures, as revealed by PCR-DGGE. Nonetheless, they all belonged to the order Methanobacteriales, which can mediate hydrogenotrophic methanogenesis. Biogas upgrading was then tested in a thermophilic anaerobic reactor under various operation conditions. By continuous addition of hydrogen in the biogas reactor, high degree of biogas upgrading was achieved. The produced biogas had a CH(4) content, around 95% at steady-state, at gas (mixture of biogas and hydrogen) injection rate of 6 L/(L day). The increase of gas injection rate to 12 L/(L day) resulted in the decrease of CH(4) content to around 90%. Further study showed that by decreasing the gas-liquid mass transfer by increasing the stirring speed of the mixture the CH(4) content was increased to around 95%. Finally, the CH(4) content around 90% was achieved in this study with the gas injection rate as high as 24 L/(L day).

  12. Comparative analysis of the microbial diversity in liquid and foaming layer in biogas reactors

    DEFF Research Database (Denmark)

    Campanaro, Stefano; Treu, Laura; Kougias, Panagiotis

    2014-01-01

    Foaming incidents have been recorded in many biogas plants causing severe operational, economical and environmental problems (Kougias et al., 2014). However, the foaming phenomenon in biogas reactors fed with agro-industrial wastes has not been extensively investigated, especially with respect...... stirred tank reactors (CSTR) fed with manure and supplemental amounts of lipids, proteins and carbohydrates. Once foaming was formed in the reactors, samples from the liquid and foaming layer were obtained and screened using 16S rDNA sequencing. The results of these analyses revealed that there are indeed...... on foam formation or stabilization might be enhanced in correlation with other parameters (i.e. presence of specific microorganisms)....

  13. Counteracting foaming caused by lipids or proteins in biogas reactors using rapeseed oil or oleic acid as antifoaming agents.

    Science.gov (United States)

    Kougias, P G; Boe, K; Einarsdottir, E S; Angelidaki, I

    2015-08-01

    Foaming is one of the major operational problems in biogas plants, and dealing with foaming incidents is still based on empirical practices. Various types of antifoams are used arbitrarily to combat foaming in biogas plants, but without any scientific support this action can lead to serious deterioration of the methanogenic process. Many commercial antifoams are derivatives of fatty acids or oils. However, it is well known that lipids can induce foaming in manure based biogas plants. This study aimed to elucidate the effect of rapeseed oil and oleic acid on foam reduction and process performance in biogas reactors fed with protein or lipid rich substrates. The results showed that both antifoams efficiently suppressed foaming. Moreover rapeseed oil resulted in stimulation of the biogas production. Finally, it was reckoned that the chemical structure of lipids, and more specifically their carboxylic ends, is responsible for their foam promoting or foam counteracting behaviour. Thus, it was concluded that the fatty acids and oils could suppress foaming, while salt of fatty acids could generate foam.

  14. Kinetic study on the effect of temperature on biogas production using a lab scale batch reactor.

    Science.gov (United States)

    Deepanraj, B; Sivasubramanian, V; Jayaraj, S

    2015-11-01

    In the present study, biogas production from food waste through anaerobic digestion was carried out in a 2l laboratory-scale batch reactor operating at different temperatures with a hydraulic retention time of 30 days. The reactors were operated with a solid concentration of 7.5% of total solids and pH 7. The food wastes used in this experiment were subjected to characterization studies before and after digestion. Modified Gompertz model and Logistic model were used for kinetic study of biogas production. The kinetic parameters, biogas yield potential of the substrate (B), the maximum biogas production rate (Rb) and the duration of lag phase (λ), coefficient of determination (R(2)) and root mean square error (RMSE) were estimated in each case. The effect of temperature on biogas production was evaluated experimentally and compared with the results of kinetic study. The results demonstrated that the reactor with operating temperature of 50°C achieved maximum cumulative biogas production of 7556ml with better biodegradation efficiency.

  15. biogas

    DEFF Research Database (Denmark)

    2015-01-01

    Functions for working with biogas data. Both low- and high-level functions are included for carrying out common tasks for analysis of biogas and related data. Molar mass and calculated oxygen demand (COD') can be determined from a chemical formula. Measured gas volume can be corrected for water...... vapor and to (possibly user-defined) standard temperature and pressure. Gas composition, cumulative production, or other variables can be interpolated to a specified time. Cumulative biogas and methane production (and rates) can be calculated using volumetric, manometric, or gravimetric methods for any...... be summarized in several different ways (e.g., omitting normalization) using the same function. Lastly, biogas and methane production can be predicted from substrate composition and additional, optional data....

  16. Degradation and detoxification of tar water from a gasification plant in a biogas reactor

    Energy Technology Data Exchange (ETDEWEB)

    Angelidaki, I.; Torry-Smith, M.; Petersen, L.; Ahring, B.K. [Denmarks Technical Univ., Dept. of Environmental Science and Engineering, Lyngby (Denmark)

    1998-08-01

    During gasification of biomass, toxic tar and tar-water (TW) are produced. The produced TW is saturated by soluble phenolic compound. In this project we have attempted detoxification of the produced TW by either wet oxidation where the TW is heated under pressure and addition of excess oxygen, and then subsequent treatment of the formed wet oxidized product in a biogas reactor. Alternatively, we treated the TW directly in a biogas reactor. Reduction in phenolic compounds, which constitute the major toxic compounds in TW, was used as a success parameter evaluating the detoxification of TW. The TW could successfully be degraded in a biogas reactor when co-digested with manure at a concentration up to 5%. Wet oxidized tar water (WOTW) could be degraded when added at a concentration of 30%. A biogas potential of approx. 0.19 L CH/g-VS was achieved for both the TW and WOTW. The biogas production per kg waste was 30 and 10 L CH/kg waste for the TW and the WOTW, respectively. The reason for the much lower methane production of the WOTW was that a large part of the organic content of the TW was converted to carbon dioxide during the wet oxidation process. The effluent concentrations of phenolic were in all cases much lower than the concentrations found in normally in undigested manure, showing that biomethanation of toxic wastes in co-digestion with manure could be an easy and cheap way to detoxify specific toxic wastes. (au)

  17. Ex-situ biogas upgrading and enhancement in different reactor systems.

    Science.gov (United States)

    Kougias, Panagiotis G; Treu, Laura; Benavente, Daniela Peñailillo; Boe, Kanokwan; Campanaro, Stefano; Angelidaki, Irini

    2017-02-01

    Biogas upgrading is envisioned as a key process for clean energy production. The current study evaluates the efficiency of different reactor configurations for ex-situ biogas upgrading and enhancement, in which externally provided hydrogen and carbon dioxide were biologically converted to methane by the action of hydrogenotrophic methanogens. The methane content in the output gas of the most efficient configuration was >98%, allowing its exploitation as substitute to natural gas. Additionally, use of digestate from biogas plants as a cost efficient method to provide all the necessary nutrients for microbial growth was successful. High-throughput 16S rRNA sequencing revealed that the microbial community was resided by novel phylotypes belonging to the uncultured order MBA08 and to Bacteroidales. Moreover, only hydrogenotrophic methanogens were identified belonging to Methanothermobacter and Methanoculleus genera. Methanothermobacter thermautotrophicus was the predominant methanogen in the biofilm formed on top of the diffuser surface in the bubble column reactor.

  18. Analysis of the key enzymes of butyric and acetic acid fermentation in biogas reactors.

    Science.gov (United States)

    Gabris, Christina; Bengelsdorf, Frank R; Dürre, Peter

    2015-09-01

    This study aimed at the investigation of the mechanisms of acidogenesis, which is a key process during anaerobic digestion. To expose possible bottlenecks, specific activities of the key enzymes of acidification, such as acetate kinase (Ack, 0.23-0.99 U mg(-1) protein), butyrate kinase (Buk, < 0.03 U mg(-1) protein) and butyryl-CoA:acetate-CoA transferase (But, 3.24-7.64 U mg(-1) protein), were determined in cell free extracts of biogas reactor content from three different biogas reactors. Furthermore, the detection of Ack was successful via Western blot analysis. Quantification of corresponding functional genes encoding Buk (buk) and But (but) was not feasible, although an amplification was possible. Thus, phylogenetic trees were constructed based on respective gene fragments. Four new clades of possible butyrate-producing bacteria were postulated, as well as bacteria of the genera Roseburia or Clostridium identified. The low Buk activity was in contrast to the high specific But activity in the analysed samples. Butyrate formation via Buk activity does barely occur in the investigated biogas reactor. Specific enzyme activities (Ack, Buk and But) in samples drawn from three different biogas reactors correlated with ammonia and ammonium concentrations (NH₃ and NH₄(+)-N), and a negative dependency can be postulated. Thus, high concentrations of NH₃ and NH₄(+)-N may lead to a bottleneck in acidogenesis due to decreased specific acidogenic enzyme activities.

  19. Effect of organic loading rate and feedstock composition on foaming in manure-based biogas reactors

    DEFF Research Database (Denmark)

    Kougias, Panagiotis; Boe, Kanokwan; Angelidaki, Irini

    2013-01-01

    Foaming is one of the major problems that occasionally occur in biogas plants, affecting negatively the overall digestion process. In the present study, the effect of organic loading rate (OLR) and feedstock composition on foaming was elucidated in continuous reactor experiments. By stepwise...

  20. Strategies for recovering inhibition caused by long chain fatty acids on anaerobic thermophilic biogas reactors

    DEFF Research Database (Denmark)

    Palatsi, J.; Laureni, M.; Andres, M.V.

    2009-01-01

    Long chain fatty acids (LCFA) concentrations over 1.0 g L1 were inhibiting manure thermophilic digestion, in batch and semi-continuous experiments, resulting in a temporary cease of the biogas production. The aim of the work was to test and evaluate several recovery actions, such as reactor feedi...

  1. Simultaneous hydrogen utilization and in situ biogas upgrading in an anaerobic reactor.

    Science.gov (United States)

    Luo, Gang; Johansson, Sara; Boe, Kanokwan; Xie, Li; Zhou, Qi; Angelidaki, Irini

    2012-04-01

    The possibility of converting hydrogen to methane and simultaneous upgrading of biogas was investigated in both batch tests and fully mixed biogas reactor, simultaneously fed with manure and hydrogen. Batch experiments showed that hydrogen could be converted to methane by hydrogenotrophic methanogenesis with conversion of more than 90% of the consumed hydrogen to methane. The hydrogen consumption rates were affected by both P(H₂) (hydrogen partial pressure) and mixing intensity. Inhibition of propionate and butyrate degradation by hydrogen (1 atm) was only observed under high mixing intensity (shaking speed 300 rpm). Continuous addition of hydrogen (flow rate of 28.6 mL/(L/h)) to an anaerobic reactor fed with manure, showed that more than 80% of the hydrogen was utilized. The propionate and butyrate level in the reactor was not significantly affected by the hydrogen addition. The methane production rate of the reactor with H₂ addition was 22% higher, compared to the control reactor only fed with manure. The CO₂ content in the produced biogas was only 15%, while it was 38% in the control reactor. However, the addition of hydrogen resulted in increase of pH (from 8.0 to 8.3) due to the consumption of bicarbonate, which subsequently caused slight inhibition of methanogenesis.

  2. Where does the removal of H₂S from biogas occur in microaerobic reactors?

    Science.gov (United States)

    Ramos, I; Peña, M; Fdz-Polanco, M

    2014-08-01

    In order to maximise the efficiency of biogas desulphurisation and reduce the oxygen cost during microaerobic digestion, it is essential to know how the process occurs. For this purpose, a reactor with a total volume of 266 L, treating 10 L/d of sewage sludge, was operated with 25.0 L and without headspace. Under anaerobic conditions, the H2S concentration in the biogas varied between 0.21 and 0.38%v/v. Next, O2 was supplied from the bottom of the reactor. At 0.25-0.30 NLO₂/Lfed, the biogas was entirely desulphurised, and its O₂ content remained below 1.03%v/v, when the digester had 25.0 L of gas space. However, with almost no headspace, the H2S content in the biogas fluctuated from 0.08 to 0.21%v/v, while the average O2 concentration was 1.66%v/v. The removed H2S accumulated in the outlet pipe of the biogas in the form of S(0) due to the insufficient headspace.

  3. Syntrophic microbial communities on straw as biofilm carrier increase the methane yield of a biowaste-digesting biogas reactor

    Directory of Open Access Journals (Sweden)

    Frank R. Bengelsdorf

    2015-08-01

    Full Text Available Biogas from biowaste can be an important source of renewable energy, but the fermentation process of low-structure waste is often unstable. The present study uses a full-scale biogas reactor to test the hypothesis that straw as an additional biofilm carrier will increase methane yield; and this effect is mirrored in a specific microbial community attached to the straw. Better reactor performance after addition of straw, at simultaneously higher organic loading rate and specific methane yield confirmed the hypothesis. The microbial communities on straw as a biofilm carrier and of the liquid reactor content were investigated using 16S rDNA amplicon sequencing by means of 454 pyrosequencing technology. The results revealed high diversity of the bacterial communities in the liquid reactor content as well as the biofilms on the straw. The most abundant archaea in all samples belonged to the genera Methanoculleus and Methanosarcina. Addition of straw resulted in a significantly different microbial community attached to the biofilm carrier. The bacterium Candidatus Cloacamonas acidaminovorans and methanogenic archaea of the genus Methanoculleus dominated the biofilm on straw. Syntrophic interactions between the hydrogenotrophic Methanoculleus sp. and members of the hydrogen-producing bacterial community within biofilms may explain the improved methane yield. Thus, straw addition can be used to improve and to stabilize the anaerobic process in substrates lacking biofilm-supporting structures.

  4. Effect of organic loading rate and feedstock composition on foaming in manure-based biogas reactors.

    Science.gov (United States)

    Kougias, P G; Boe, K; Angelidaki, I

    2013-09-01

    Foaming is one of the major problems that occasionally occur in biogas plants, affecting negatively the overall digestion process. In the present study, the effect of organic loading rate (OLR) and feedstock composition on foaming was elucidated in continuous reactor experiments. By stepwise increasing the OLR and the concentration of proteins or lipids in the substrate, foaming in biogas reactors was investigated. No foam formation was observed at the OLR of 3.5 g volatile solids/(L-reactor·day). Organic loading was the main factor affecting foam formation in manure digester, while the organic composition, such as content of proteins or lipids were factors that in combination with the organic loading were triggering foaming. More specifically, gelatine could initiate foam formation at a lower OLR than sodium oleate. Moreover, the volume of foam produced by gelatine was relatively stable and was not increased when further increasing either OLR or gelatine concentration in the feed.

  5. Comparative microbial analysis before and after foaming incidents in biogas reactors

    DEFF Research Database (Denmark)

    Kougias, Panagiotis; De Francisci, Davide; Treu, Laura

    2014-01-01

    retention time (HRT) of all reactors was kept constant at 15 days. The whole experiment was divided into two periods. During the first period, the reactors were fed only with cattle manure. Once steady state conditions were reached, liquid sample from all reactors was obtained for DNA extraction...... foam was steady, samples were taken again for DNA extraction and metagenomic analysis. Results from the present study revealed significant variations in the microbiology of the manure-based biogas reactors after foam initiation. A number of genera could be linked to foaming as they produce...... and metagenomic analysis. After sampling, the feedstock composition of each reactor was changed by the addition of gelatine or Na-Oleate or glucose (second experimental period). As a consequence, foam formation was observed in all reactors approximately after one HRT period. Once the daily volume of the formed...

  6. Valorization of biogas into liquid hydrocarbons in plasma-catalyst reactor

    Science.gov (United States)

    Nikravech, Mehrdad; Rahmani, Abdelkader; Labidi, Sana; Saintini, Noiric

    2016-09-01

    Biogas represents an important source of renewable energy issued from biological degradation of biomass. It is planned to produce in Europe the amount of biogas equivalent to 6400 kWh electricity and 4500 kteo (kilo tons equivalent oil) in 2020. Currently the biogas is used in cogeneration engines to produce heat and electricity directly in farms or it is injected in gas networks after purification and odorisation. The aim of this work is to propose a third option that consists of valorization of biogas by transformation into liquid hydrocarbons like acetone, methanol, ethanol, acetic acid etc. These chemicals, among the most important feed materials for chemical industries, retain CO2 molecules participating to reduce the greenhouse gas emissions and have high storage energy capacity. We developed a low temperature atmospheric plasma-catalyst reactor (surface dielectric barrier discharge) to transform biogas into chemicals. The conversion rates of CH4 and CO2 are respectively about 50% and 30% depending on operational conditions. The energetic cost is 25 eV/molecule. The yields of liquid hydrocarbon reaches currently 10% wt. More the 11 liquid chemicals are observed in the liquid fraction. Acknowledgements are due to SPC Programme Energie de demain.

  7. Energy performance and consumption for biogas heat pump air conditioner

    Energy Technology Data Exchange (ETDEWEB)

    Xu, Zhenjun [Architectural Engineering College, Qingdao Agricultural University, 266109 (China); Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101 (China); Tianjin University, Tianjin, 300072 (China); Wu, Huaizhi; Wu, Meiling [Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101 (China); Tianjin University, Tianjin, 300072 (China)

    2010-12-15

    Biogas engine-driven heat pump air conditioner is a new-style system which includes biogas engine-driven heat pump, primary heat exchanger, second heat exchanger, sprayed room and fans, pumps, etc. In summertime, the air can be reheated by the waste heat water from the biogas engine in the system, while the air can be reheated and humidified by the waste heat water in winter. Reducing or displacing electrical heating requirements can achieve the great opportunity for significant energy savings. This paper, therefore, aims to improve the energy performance of the AC system by using the waste heat from the biogas engine. The mathematic model was used to research the BHPAC. Explicitly, we investigated the influence of various factors including the outdoor air temperature and humidity in summer and winter. Results show that the biogas engine-driven heat pump air conditioner can save more energy than the electrical power heat pump. In summer, the minimum for percentage of primary energy saving for BHPAC is over 25%. With the outdoor air dry-bulb temperature and the relative humidity rises, the saving energy percentage rises. In winter, the minimum for percentage of primary energy saving for BHPAC is 37%. The more the outdoor air relative humidity of the outdoor air decreases, the more the BHPAC saves energy. It is proved that the system which is a highly actively fully utilizing energy technology has good partial load characteristic and good effects of energy saving. (author)

  8. In-situ biogas upgrading in thermophilic granular UASB reactor: key factors affecting the hydrogen mass transfer rate.

    Science.gov (United States)

    Bassani, Ilaria; Kougias, Panagiotis G; Angelidaki, Irini

    2016-12-01

    Biological biogas upgrading coupling CO2 with external H2 to form biomethane opens new avenues for sustainable biofuel production. For developing this technology, efficient H2 to liquid transfer is fundamental. This study proposes an innovative setup for in-situ biogas upgrading converting the CO2 in the biogas into CH4, via hydrogenotrophic methanogenesis. The setup consisted of a granular reactor connected to a separate chamber, where H2 was injected. Different packing materials (rashig rings and alumina ceramic sponge) were tested to increase gas-liquid mass transfer. This aspect was optimized by liquid and gas recirculation and chamber configuration. It was shown that by distributing H2 through a metallic diffuser followed by ceramic sponge in a separate chamber, having a volume of 25% of the reactor, and by applying a mild gas recirculation, CO2 content in the biogas dropped from 42 to 10% and the final biogas was upgraded from 58 to 82% CH4 content.

  9. Waste management of tar water from pyrolysis and gasification of biomass in biogas reactors

    Energy Technology Data Exchange (ETDEWEB)

    Mogensen, A.S.; Schmidt, J.E.; Angelidaki, R.; Ahring, B.K.

    1998-08-01

    The digestion and detoxification of pyrolysis condensate and wet oxidised pyrolysis condensate was studied in different reactor systems: combined anaerobic and denitrifying UASB reactors, conventional UASB reactors and CSTR`s. The pyrolysis condensate and the wet oxidised condensate have a biogas potential of 190 m{sup 3}/ton VS, and the low amount of suspended solids is allowing the waste water to be treated in the UASB reactor as well as in the CSTR. The pyrolysis condensate could successfully be degraded in a CSTR in a 5% concentration when co-digested with manure, and the wet oxidised pyrolysis condensate could be degraded when added at a concentration of 30%. The UASB reactor was preferred over the CSTR since the xenobiotic compounds present in the waste water might easily be absorbed in the co-substrate required when using the CSTR technology. Consequently, decreased degradation of xenobiotics would be observed in the CSTR. A combined anaerobic and denitrifying UASB reactor was successfully digesting 5.5% of wet oxidised pyrolysis condensate, but further loading increments deteriorated the anaerobic digestion process. However, when a UASB reactor was fed with pyrolysis condensate (up to 100%) good reactor operation was observed indicating that the waste could be used as substrate in the biogas process, even in very high concentrations. The detoxification of pyrolysis condensate was further studied and the toxicity of pyrolysis condensate was decreased more than 77 times in the UASB reactor that was operating on 100% pyrolysis condensate. Phenol, methyl and dimethyl phenols along with methoxyphenols were shown to be degraded within the rector systems. Degradation rates for phenol and substituted phenols were determined indicating that the biomass was selective towards the substrates. Maximum growth rates and half saturation constants for phenol, 4-Methylphenol and 2-Methoxy-4-methylphenol were determined in batch experiments. A UASB reactor concept was further

  10. In-situ biogas upgrading in thermophilic granular UASB reactor: key factors affecting the hydrogen mass transfer rate

    DEFF Research Database (Denmark)

    Bassani, Ilaria; Kougias, Panagiotis; Angelidaki, Irini

    2016-01-01

    Biological biogas upgrading coupling CO2 with external H2 to form biomethane opens new avenues for sustainable biofuel production. For developing this technology, efficient H2 to liquid transfer is fundamental. This study proposes an innovative setup for in-situ biogas upgrading converting the CO2...... in the biogas into CH4, via hydrogenotrophic methanogenesis. The setup consisted of a granular reactor connected to a separate chamber, where H2 was injected. Different packing materials (rashig rings and alumina ceramic sponge) were tested to increase gas-liquid mass transfer. This aspect was optimized...... by liquid and gas recirculation and chamber configuration. It was shown that by distributing H2 through a metallic diffuser followed by ceramic sponge in a separate chamber, having a volume of 25% of the reactor, and by applying a mild gas recirculation, CO2 content in the biogas dropped from 42 to 10...

  11. Modelling anaerobic digestion in a biogas reactor: ADM1 model development with lactate as an intermediate (Part I).

    Science.gov (United States)

    Satpathy, Preseela; Biernacki, Piotr; Uhlenhut, Frank; Cypionka, Heribert; Steinigeweg, Sven

    2016-12-05

    The Anaerobic Digestion Model No. 1 (ADM1) was extended to include lactate, a crucial metabolic product during sugar fermentation. This study tests the validity of the modified ADM1 model in improving the predictions of a standard biogas reactor. This reactor was prepared in the laboratory with simple organic substrates with an intention to represent an 'average biogas plant'. Kinetic parameters were determined from a lactic acid enriched steady-state reactor. The parameters were adjusted further in order to acquire satisfying simulation results systematically with the batch experiments and then against the standard biogas reactor. Arresting methanogenesis revealed that lactate degradation occurred majorly via acetate followed by propionate, and a non-negligible proportion of butyrate too was found, which were further updated in the model. The modified ADM1 provided a successful correlation with the experimental results for the batch and continuous experiments. We justified that inclusion of lactate in the model resulted in optimized simulation for both biogas and methane content in the standard biogas reactor.

  12. A new degassing membrane coupled upflow anaerobic sludge blanket (UASB) reactor to achieve in-situ biogas upgrading and recovery of dissolved CH4 from the anaerobic effluent

    DEFF Research Database (Denmark)

    Luo, Gang; Wang, Wen; Angelidaki, Irini

    2014-01-01

    A new technology for in-situ biogas upgrading and recovery of CH4 from the effluent of biogas reactors was proposed and demonstrated in this study. A vacuum degassing membrane module was used to desorb CO2 from the liquid phase of a biogas reactor. The degassing membrane was submerged into a dega......A new technology for in-situ biogas upgrading and recovery of CH4 from the effluent of biogas reactors was proposed and demonstrated in this study. A vacuum degassing membrane module was used to desorb CO2 from the liquid phase of a biogas reactor. The degassing membrane was submerged......, the COD removal efficiency and CH4 yield were not obviously affected by the gas desorption....

  13. Different substrates and starter inocula govern microbial community structures in biogas reactors.

    Science.gov (United States)

    Satpathy, Preseela; Steinigeweg, Sven; Cypionka, Heribert; Engelen, Bert

    2016-01-01

    The influence of different starter inocula on the microbial communities in biogas batch reactors fed with fresh maize and maize silage as substrates was investigated. Molecular biological analysis by Denaturing Gradient Gel Electrophoresis (DGGE) of 16S rRNA gene fragments showed that each inoculum bore specific microbial communities with varying predominant phylotypes. Both, bacterial and archaeal DGGE profiles displayed three distinct communities that developed depending on the type of inoculum. Although maize and silage are similar substrates, different communities dominated the lactate-rich silage compared to lactate-free fresh maize. Cluster analysis of DGGE gels showed the communities of the same substrates to be stable with their respective inoculum. Bacteria-specific DGGE analysis revealed a rich diversity with Firmicutes being predominant. The other abundant phylotypes were Bacteroidetes and Synergistetes. Archaea-specific DGGE analysis displayed less diverse community structures, identifying members of the Methanosarcinales as the dominant methanogens present in all the three biogas digesters. In general, the source of inoculum played a significant role in shaping microbial communities. Adaptability of the inoculum to the substrates fed also influenced community compositions which further impacted the rates of biogas production.

  14. Energy potential and alternative usages of biogas and sludge from UASB reactors: case study of the Laboreaux wastewater treatment plant.

    Science.gov (United States)

    Rosa, A P; Conesa, J A; Fullana, A; Melo, G C B; Borges, J M; Chernicharo, C A L

    2016-01-01

    This work assessed the energy potential and alternative usages of biogas and sludge generated in upflow anaerobic sludge blanket reactors at the Laboreaux sewage treatment plant (STP), Brazil. Two scenarios were considered: (i) priority use of biogas for the thermal drying of dehydrated sludge and the use of the excess biogas for electricity generation in an ICE (internal combustion engine); and (ii) priority use of biogas for electricity generation and the use of the heat of the engine exhaust gases for the thermal drying of the sludge. Scenario 1 showed that the electricity generated is able to supply 22.2% of the STP power demand, but the thermal drying process enables a greater reduction or even elimination of the final volume of sludge to be disposed. In Scenario 2, the electricity generated is able to supply 57.6% of the STP power demand; however, the heat in the exhaust gases is not enough to dry the total amount of dehydrated sludge.

  15. Biogas composition and engine performance, including database and biogas property model

    NARCIS (Netherlands)

    Bruijstens, A.J.; Beuman, W.P.H.; Molen, M. van der; Rijke, J. de; Cloudt, R.P.M.; Kadijk, G.; Camp, O.M.G.C. op den; Bleuanus, W.A.J.

    2008-01-01

    In order to enable this evaluation of the current biogas quality situation in the EU; results are presented in a biogas database. Furthermore the key gas parameter Sonic Bievo Index (influence on open loop A/F-ratio) is defined and other key gas parameters like the Methane Number (knock resistance)

  16. Biogas Upgrading via Hydrogenotrophic Methanogenesis in Two-Stage Continuous Stirred Tank Reactors at Mesophilic and Thermophilic Conditions.

    Science.gov (United States)

    Bassani, Ilaria; Kougias, Panagiotis G; Treu, Laura; Angelidaki, Irini

    2015-10-20

    This study proposes an innovative setup composed by two stage reactors to achieve biogas upgrading coupling the CO2 in the biogas with external H2 and subsequent conversion into CH4 by hydrogenotrophic methanogenesis. In this configuration, the biogas produced in the first reactor was transferred to the second one, where H2 was injected. This configuration was tested at both mesophilic and thermophilic conditions. After H2 addition, the produced biogas was upgraded to average CH4 content of 89% in the mesophilic reactor and 85% in the thermophilic. At thermophilic conditions, a higher efficiency of CH4 production and CO2 conversion was recorded. The consequent increase of pH did not inhibit the process indicating adaptation of microorganisms to higher pH levels. The effects of H2 on the microbial community were studied using high-throughput Illumina random sequences and full-length 16S rRNA genes extracted from the total sequences. The relative abundance of archaeal community markedly increased upon H2 addition with Methanoculleus as dominant genus. The increase of hydrogenotrophic methanogens and syntrophic Desulfovibrio and the decrease of aceticlastic methanogens indicate a H2-mediated shift toward the hydrogenotrophic pathway enhancing biogas upgrading. Moreover, Thermoanaerobacteraceae were likely involved in syntrophic acetate oxidation with hydrogenotrophic methanogens in absence of aceticlastic methanogenesis.

  17. Wood ash amendment to biogas reactors as an alternative to landfilling? A preliminary study on changes in process chemistry and biology.

    Science.gov (United States)

    Podmirseg, Sabine M; Seewald, Martin S A; Knapp, Brigitte A; Bouzid, Ourdia; Biderre-Petit, Corinne; Peyret, Pierre; Insam, Heribert

    2013-08-01

    Wood ash addition to biogas plants represents an alternative to commonly used landfilling by improving the reactor performance, raising the pH and alleviating potential limits of trace elements. This study is the first on the effects of wood ash on reactor conditions and microbial communities in cattle slurry-based biogas reactors. General process parameters [temperature, pH, electrical conductivity, ammonia, volatile fatty acids, carbon/nitrogen (C/N), total solids (TS), volatile solids, and gas quantity and quality] were monitored along with molecular analyses of methanogens by polymerase chain reaction- denaturing gradient gel electrophoresis and modern microarrays (archaea and bacteria). A prompt pH rise was observed, as was an increase in C/N ratio and volatile fatty acids. Biogas production was inhibited, but recovered to even higher production rates and methane concentration after single amendment. High sulphur levels in the wood ash generated hydrogen sulphide and potentially hampered methanogenesis. Methanosarcina was the most dominant methanogen in all reactors; however, diversity was higher in ash-amended reactors. Bacterial groups like Firmicutes, Proteobacteria and Acidobacteria were favoured, which could improve the hydrolytic efficiency of the reactors. We recommend constant monitoring of the chemical composition of the used wood ash and suggest that ash amendment is adequate if added to the substrate at a rate low enough to allow adaptation of the microbiota (e.g. 0.25 g g(-1) TS). It could further help to enrich digestate with important nutrients, for example phosphorus, calcium and magnesium, but further experiments are required for the evaluation of wood ash concentrations that are tolerable for anaerobic digestion.

  18. Functionally redundant but dissimilar microbial communities within biogas reactors treating maize silage in co-fermentation with sugar beet silage.

    Science.gov (United States)

    Langer, Susanne G; Ahmed, Sharif; Einfalt, Daniel; Bengelsdorf, Frank R; Kazda, Marian

    2015-09-01

    Numerous observations indicate a high flexibility of microbial communities in different biogas reactors during anaerobic digestion. Here, we describe the functional redundancy and structural changes of involved microbial communities in four lab-scale continuously stirred tank reactors (CSTRs, 39°C, 12 L volume) supplied with different mixtures of maize silage (MS) and sugar beet silage (SBS) over 80 days. Continuously stirred tank reactors were fed with mixtures of MS and SBS in volatile solid ratios of 1:0 (Continuous Fermenter (CF) 1), 6:1 (CF2), 3:1 (CF3), 1:3 (CF4) with equal organic loading rates (OLR 1.25 kgVS m(-3)  d(-1) ) and showed similar biogas production rates in all reactors. The compositions of bacterial and archaeal communities were analysed by 454 amplicon sequencing approach based on 16S rRNA genes. Both bacterial and archaeal communities shifted with increasing amounts of SBS. Especially pronounced were changes in the archaeal composition towards Methanosarcina with increasing proportion of SBS, while Methanosaeta declined simultaneously. Compositional shifts within the microbial communities did not influence the respective biogas production rates indicating that these communities adapted to environmental conditions induced by different feedstock mixtures. The diverse microbial communities optimized their metabolism in a way that ensured efficient biogas production.

  19. Functionally redundant but dissimilar microbial communities within biogas reactors treating maize silage in co-fermentation with sugar beet silage

    Science.gov (United States)

    Langer, Susanne G; Ahmed, Sharif; Einfalt, Daniel; Bengelsdorf, Frank R; Kazda, Marian

    2015-01-01

    Numerous observations indicate a high flexibility of microbial communities in different biogas reactors during anaerobic digestion. Here, we describe the functional redundancy and structural changes of involved microbial communities in four lab-scale continuously stirred tank reactors (CSTRs, 39°C, 12 L volume) supplied with different mixtures of maize silage (MS) and sugar beet silage (SBS) over 80 days. Continuously stirred tank reactors were fed with mixtures of MS and SBS in volatile solid ratios of 1:0 (Continuous Fermenter (CF) 1), 6:1 (CF2), 3:1 (CF3), 1:3 (CF4) with equal organic loading rates (OLR 1.25 kgVS m−3 d−1) and showed similar biogas production rates in all reactors. The compositions of bacterial and archaeal communities were analysed by 454 amplicon sequencing approach based on 16S rRNA genes. Both bacterial and archaeal communities shifted with increasing amounts of SBS. Especially pronounced were changes in the archaeal composition towards Methanosarcina with increasing proportion of SBS, while Methanosaeta declined simultaneously. Compositional shifts within the microbial communities did not influence the respective biogas production rates indicating that these communities adapted to environmental conditions induced by different feedstock mixtures. The diverse microbial communities optimized their metabolism in a way that ensured efficient biogas production. PMID:26200922

  20. Acetate conversion in anaerobic biogas reactors: Traditional and molecular tools for studying this important group of anaerobic microorganisms

    DEFF Research Database (Denmark)

    Schmidt, Jens Ejbye; Mladenovska, Zuzana; Lange, Marianne;

    2000-01-01

    Different methods were applied to study the role of aceticlastic methanogens in biogas reactors treating solid waste and wastewater. We used traditional microbiological methods, immunological and 16S rRNA ribosomal probes for detection of the methanogens. Using this approach we identified the met...

  1. Hollow fiber membrane based H-2 diffusion for efficient in situ biogas upgrading in an anaerobic reactor

    DEFF Research Database (Denmark)

    Luo, Gang; Angelidaki, Irini

    2013-01-01

    Bubbleless gas transfer through a hollow fiber membrane (HFM) module was used to supply H2 to an anaerobic reactor for in situ biogas upgrading, and it creates a novel system that could achieve a CH4 content higher than 90 % in the biogas. The increase of CH4 content and pH, and the decrease of b...... also demonstrated that the biofilm formed on the membrane only contributed 22-36 % to the H2 consumption, while most of the H2 was consumed by the microorganisms in the liquid phase....

  2. Changing Feeding Regimes To Demonstrate Flexible Biogas Production: Effects on Process Performance, Microbial Community Structure, and Methanogenesis Pathways.

    Science.gov (United States)

    Mulat, Daniel Girma; Jacobi, H Fabian; Feilberg, Anders; Adamsen, Anders Peter S; Richnow, Hans-Hermann; Nikolausz, Marcell

    2015-10-23

    Flexible biogas production that adapts biogas output to energy demand can be regulated by changing feeding regimes. In this study, the effect of changes in feeding intervals on process performance, microbial community structure, and the methanogenesis pathway was investigated. Three different feeding regimes (once daily, every second day, and every 2 h) at the same organic loading rate were studied in continuously stirred tank reactors treating distiller's dried grains with solubles. A larger amount of biogas was produced after feeding in the reactors fed less frequently (once per day and every second day), whereas the amount remained constant in the reactor fed more frequently (every 2 h), indicating the suitability of the former for the flexible production of biogas. Compared to the conventional more frequent feeding regimes, a methane yield that was up to 14% higher and an improved stability of the process against organic overloading were achieved by employing less frequent feeding regimes. The community structures of bacteria and methanogenic archaea were monitored by terminal restriction fragment length polymorphism (T-RFLP) analysis of 16S rRNA and mcrA genes, respectively. The results showed that the composition of the bacterial community varied under the different feeding regimes, and the observed T-RFLP patterns were best explained by the differences in the total ammonia nitrogen concentrations, H2 levels, and pH values. However, the methanogenic community remained stable under all feeding regimes, with the dominance of the Methanosarcina genus followed by that of the Methanobacterium genus. Stable isotope analysis showed that the average amount of methane produced during each feeding event by acetoclastic and hydrogenotrophic methanogenesis was not influenced by the three different feeding regimes.

  3. Thermal hygienization of excess anaerobic sludge: a possible self-sustained application of biogas produced in UASB reactors.

    Science.gov (United States)

    Borges, E S M; Godinho, V M; Chernicharo, C A L

    2005-01-01

    The main current trends in final disposal of sludge from Wastewater Treatment Plants (WTP) include: safe use of nutrients and organic matter in agriculture, sludge disinfection and restricted use in landfill. As to sludge hygienization, helminth eggs have been used as a major parameter to determine the effectiveness of such process, and its inactivation can be reached by means of thermal treatment, under varying temperature and other conditions. In such context, the objective of this research was to determine how effectively biogas produced in UASB reactors could be used as a source of calorific energy for the thermal hygienization of excess anaerobic sludge, with Ascaris lumbricoides eggs being used as indicator microorganisms, and whether the system can operate on a self-sustained basis. The experiments were conducted in a pilot-scale plant comprising one UASB reactor, two biogas holders and one thermal reactor. The investigation proved to be of extreme importance to developing countries, since it leads to a simplified and fully self-sustainable solution for sludge hygienization, while making it possible to reuse such material for agricultural purposes. It should be also noted that using biogas from UASB reactors is more than sufficient to accomplish the thermal hygienization of all excess sludge produced by this system, when used for treating domestic sewage.

  4. Autogenerative high pressure digestion: anaerobic digestion and biogas upgrading in a single step reactor system

    NARCIS (Netherlands)

    Lindeboom, R.E.F.; Fermoso, F.G.; Weijma, J.; Zagt, K.; Lier, van J.B.

    2011-01-01

    Conventional anaerobic digestion is a widely applied technology to produce biogas from organic wastes and residues. The biogas calorific value depends on the CH4 content which generally ranges between 55 and 65%. Biogas upgrading to so-called ‘green gas’, with natural gas quality, generally proceeds

  5. Comparative analysis of taxonomic, functional, and metabolic patterns of microbiomes from 14 full-scale biogas reactors by metagenomic sequencing and radioisotopic analysis

    DEFF Research Database (Denmark)

    Luo, Gang; Fotidis, Ioannis; Angelidaki, Irini

    2016-01-01

    Background Biogas production is a very complex process due to the high complexity in diversity and interactions of the microorganisms mediating it, and only limited and diffuse knowledge exists about the variation of taxonomic and functional patterns of microbiomes across different biogas reactors......, and their relationships with the metabolic patterns. The present study used metagenomic sequencing and radioisotopic analysis to assess the taxonomic, functional, and metabolic patterns of microbiomes from 14 full-scale biogas reactors operated under various conditions treating either sludge or manure. Results...

  6. Final report on household and institutional biogas : technical performance & economic potential

    NARCIS (Netherlands)

    Anonymous,

    2010-01-01

    This report gives an overview of the technical performance for the ARTI compact biogas system in Nairobi and of the potential economic savings therein, and provides a preliminary analysis of the “gas for cash” business concept in Kenya.

  7. A fuzzy-logic-based model to predict biogas and methane production rates in a pilot-scale mesophilic UASB reactor treating molasses wastewater.

    Science.gov (United States)

    Turkdogan-Aydinol, F Ilter; Yetilmezsoy, Kaan

    2010-10-15

    A MIMO (multiple inputs and multiple outputs) fuzzy-logic-based model was developed to predict biogas and methane production rates in a pilot-scale 90-L mesophilic up-flow anaerobic sludge blanket (UASB) reactor treating molasses wastewater. Five input variables such as volumetric organic loading rate (OLR), volumetric total chemical oxygen demand (TCOD) removal rate (R(V)), influent alkalinity, influent pH and effluent pH were fuzzified by the use of an artificial intelligence-based approach. Trapezoidal membership functions with eight levels were conducted for the fuzzy subsets, and a Mamdani-type fuzzy inference system was used to implement a total of 134 rules in the IF-THEN format. The product (prod) and the centre of gravity (COG, centroid) methods were employed as the inference operator and defuzzification methods, respectively. Fuzzy-logic predicted results were compared with the outputs of two exponential non-linear regression models derived in this study. The UASB reactor showed a remarkable performance on the treatment of molasses wastewater, with an average TCOD removal efficiency of 93 (+/-3)% and an average volumetric TCOD removal rate of 6.87 (+/-3.93) kg TCOD(removed)/m(3)-day, respectively. Findings of this study clearly indicated that, compared to non-linear regression models, the proposed MIMO fuzzy-logic-based model produced smaller deviations and exhibited a superior predictive performance on forecasting of both biogas and methane production rates with satisfactory determination coefficients over 0.98.

  8. Evaluation of marine algae as a source of biogas in a two-stage anaerobic reactor system

    Energy Technology Data Exchange (ETDEWEB)

    Vergara-Fernandez, Alberto; Vargas, Gisela [Escuela de Ingenieria Ambiental, Facultad de Ingenieria, Universidad Catolica de Temuco, Manuel Montt 56, Casilla 15-D, Temuco (Chile); Alarcon, Nelson [Departamento de Ingenieria Quimica, Facultad de Ingenieria y Ciencias Geologicas, Universidad Catolica del Norte (Chile); Velasco, Antonio [Centro Nacional de Investigacion y Capacitacion Ambiental del Instituto Nacional de Ecologia (CENICA-INE), Av. San Rafael Atlixco 186, Col. Vicentina, Del. Iztapalapa, 09340, Mexico, DF (Mexico)

    2008-04-15

    The marine algae are considered an important biomass source; however, their utilization as energy source is still low around the world. The technical feasibility of marine algae utilization as a source of renewable energy was studied to laboratory scale. The anaerobic digestion of Macrocystis pyrifera, Durvillea antarctica and their blend 1:1 (w/w) was evaluated in a two-phase anaerobic digestion system, which consisted of an anaerobic sequencing batch reactor (ASBR) and an upflow anaerobic filter (UAF). The results show that 70% of the total biogas produced in the system was generated in the UAF, and both algae species have similar biogas productions of 180.4({+-}1.5) mL g{sup -1} dry algae d{sup -1}, with a methane concentration around 65%. The same methane content was observed in biogas yield of algae blend; however, a lower biogas yield was obtained. In conclusion, either algae species or their blend can be utilized to produce methane gas in a two-phase digestion system. (author)

  9. Clostridium bornimense sp. nov., isolated from a mesophilic, two-phase, laboratory-scale biogas reactor.

    Science.gov (United States)

    Hahnke, Sarah; Striesow, Jutta; Elvert, Marcus; Mollar, Xavier Prieto; Klocke, Michael

    2014-08-01

    A novel anaerobic, mesophilic, hydrogen-producing bacterium, designated strain M2/40(T), was isolated from a mesophilic, two-phase, laboratory-scale biogas reactor fed continuously with maize silage supplemented with 5% wheat straw. 16S rRNA gene sequence comparison revealed an affiliation to the genus Clostridium sensu stricto (cluster I of the clostridia), with Clostridium cellulovorans as the closest characterized species, showing 93.8% sequence similarity to the type strain. Cells of strain M2/40(T) were rods to elongated filamentous rods that showed variable Gram staining. Optimal growth occurred at 35 °C and at pH 7. Grown on glucose, the main fermentation products were H2, CO2, formate, lactate and propionate. The DNA G+C content was 29.6 mol%. The major fatty acids (>10 %) were C(16 : 0), summed feature 10 (C(18 : 1)ω11c/ω9t/ω6t and/or unknown ECL 17.834) and C(18 : 1)ω11c dimethylacetal. Based on phenotypic, chemotaxonomic and phylogenetic differences, strain M2/40(T) represents a novel species within the genus Clostridium, for which we propose the name Clostridium bornimense sp. nov. The type strain is M2/40(T) ( = DSM 25664(T) = CECT 8097(T)).

  10. Performance of the biogas project in Ziyang sugar factory

    Energy Technology Data Exchange (ETDEWEB)

    Dezhao He [Chengdu Biogas Research Inst., Chengdu (China)

    2000-07-01

    Located in Houjiaping town, Ziyang county, Ziyang Sugar Factory was installed in 1958 as a state enterprise, which mainly processes sugar cane to produce sugar. Sideline products include alcohol and paper. Nowadays, its daily capacity of sugar cane extraction is 1,000 tons and potable alcohol production is 15 - 20 tons. Its annual output value is 25 million Yuan. This plant is one of the backbones in Sichuan sugar cane processing enterprises. The biogas project of the Ziyang Sugar Factory was one of the large biogas installations in China, completed during the Seventh Five-year Plan. The distillery wastewater (slops) from the alcoholic fermentation process of starch (fresh potato, dry potato, kernel and Chinese sorghum) and sugar molasses as substrates is disposed of. The slop has a low pH, a high organic concentration, a high content of suspended solids, a dark colour and a high temperature. Its daily discharge quantity is 200 tons corresponding to 2/3 of total wastewater in that plant. It is a serious source of water pollution when it is directly discharged into Tuojiang River. Therefore, due to its high concentration of polluting substances, anaerobic treatment of distillery wastewater has been decided. This is the first case of wastewater treatment in Nudging city. The construction of this biogas installation started in July 1987. On November 25, 1988, the digester began to produce biogas. Up to now, the digesters have properly operated for more than one year. Besides its use as daily household fuel for the 810 employees, biogas is also supplied to the plant cafeteria as cooking fuel and to some production purposes within the plant, which has achieved obvious economic benefits. The designed capacity of daily biogas production for this biogas plant is 3,000 - 4,000 m{sup 3}. (orig.)

  11. Changes of the microbial population structure in an overloaded fed-batch biogas reactor digesting maize silage.

    Science.gov (United States)

    Kampmann, Kristina; Ratering, Stefan; Geißler-Plaum, Rita; Schmidt, Michael; Zerr, Walter; Schnell, Sylvia

    2014-12-01

    Two parallel, stable operating biogas reactors were fed with increasing amounts of maize silage to monitor microbial community changes caused by overloading. Changes of microorganisms diversity revealed by SSCP (single strand conformation polymorphism) indicating an acidification before and during the pH-value decrease. The earliest indicator was the appearance of a Methanosarcina thermophila-related species. Diversity of dominant fermenting bacteria within Bacteroidetes, Firmicutes and other Bacteria decreased upon overloading. Some species became dominant directly before and during acidification and thus could be suitable as possible indicator organisms for detection of futurity acidification. Those bacteria were related to Prolixibacter bellariivorans and Streptococcus infantarius subsp. infantarius. An early detection of community shifts will allow better feeding management for optimal biogas production.

  12. Biogas Upgrading via Hydrogenotrophic Methanogenesis in Two-Stage Continuous Stirred Tank Reactors at Mesophilic and Thermophilic Conditions

    DEFF Research Database (Denmark)

    Bassani, Ilaria; Kougias, Panagiotis; Treu, Laura;

    2015-01-01

    to the second one, where H2 was injected. This configuration was tested at both mesophilic and thermophilic conditions. After H2 addition, the produced biogas was upgraded to average CH4 content of 89% in the mesophilic reactor and 85% in the thermophilic. At thermophilic conditions, a higher efficiency of CH4...... production and CO2 conversion was recorded. The consequent increase of pH did not inhibit the process indicating adaptation of microorganisms to higher pH levels. The effects of H2 on the microbial community were studied using high-throughput Illumina random sequences and full-length 16S rRNA genes extracted...

  13. Microbial community composition and dynamics in high-temperature biogas reactors using industrial bioethanol waste as substrate.

    Science.gov (United States)

    Röske, Immo; Sabra, Wael; Nacke, Heiko; Daniel, Rolf; Zeng, An-Ping; Antranikian, Garabed; Sahm, Kerstin

    2014-11-01

    Stillage, which is generated during bioethanol production, constitutes a promising substrate for biogas production within the scope of an integrated biorefinery concept. In this study, a microbial community was grown on thin stillage as mono-substrate in a continuous stirred tank reactor (CSTR) at a constant temperature of 55 °C, at an organic loading rate of 1.5 goTS/L*d and a retention time of 25 days. Using an amplicon-based dataset of 17,400 high-quality sequences of 16S rRNA gene fragments (V2-V3 regions), predominance of Bacteria assigned to the families Thermotogaceae and Elusimicrobiaceae was detected. Dominant members of methane-producing Euryarchaeota within the CSTR belonged to obligate acetoclastic Methanosaetaceae and hydrogenotrophic Methanobacteriaceae. In order to investigate population dynamics during reactor acidification, the organic loading rate was increased abruptly, which resulted in an elevated concentration of volatile fatty acids. Acidification led to a decrease in relative abundance of Bacteria accompanied with stable numbers of Archaea. Nevertheless, the abundance of Methanosaetaceae increased while that of Methanobacteriales decreased successively. These findings demonstrate that a profound intervention to the biogas process may result in persistent community changes and reveals uncommon bacterial families as process-relevant microorganisms.

  14. COD removal and biogas production at the manipueira treatment in anaerobic one-stage reactor with different supporting media; Remocao de DQO e producao de biogas no tratamento de manipueira em reator anaerobico monofasico com diferentes meios de suporte

    Energy Technology Data Exchange (ETDEWEB)

    Torres, Douglas Guedes Batista; Kunzler, Kathia Regina; Gomes, Simone Damasceno; Tavares, Maria Herminia Ferreira; Assis, Tatiane Martins de [Universidade Estadual do Oeste do Parana (UNIOESTE), PR (Brazil)], Emails: simoned@unioeste.br, mhstavar@certto.com.br

    2009-07-01

    This study aims at evaluating the efficiency for organic load removal and biogas production for the manipueira treatment in two anaerobic reactors using as supporting media bamboo rings and polyurethane. The manipueira loads added to the systems were 0.548, 1.156, 1.471 and 3.049 g COD/ L{sub reactorday}, gradually increased. With bamboo as supporting media, the load increasing carried the greatest biogas production, with 3.049 g COD/ L{sub reactorday}. Using polyurethane, the greatest production occurred with the 1.471 g CODL{sub reactorday} {sup -1}load. Therefore, it was shown that the supporting media use allowed greater loads and biogas productions, comparatively to the literature data. (author)

  15. Energy performance and greenhouse gas emissions of kelp cultivation for biogas and fertilizer recovery in Sweden.

    Science.gov (United States)

    Pechsiri, Joseph S; Thomas, Jean-Baptiste E; Risén, Emma; Ribeiro, Mauricio S; Malmström, Maria E; Nylund, Göran M; Jansson, Anette; Welander, Ulrika; Pavia, Henrik; Gröndahl, Fredrik

    2016-12-15

    The cultivation of seaweed as a feedstock for third generation biofuels is gathering interest in Europe, however, many questions remain unanswered in practise, notably regarding scales of operation, energy returns on investment (EROI) and greenhouse gas (GHG) emissions, all of which are crucial to determine commercial viability. This study performed an energy and GHG emissions analysis, using EROI and GHG savings potential respectively, as indicators of commercial viability for two systems: the Swedish Seafarm project's seaweed cultivation (0.5ha), biogas and fertilizer biorefinery, and an estimation of the same system scaled up and adjusted to a cultivation of 10ha. Based on a conservative estimate of biogas yield, neither the 0.5ha case nor the up-scaled 10ha estimates met the (commercial viability) target EROI of 3, nor the European Union Renewable Energy Directive GHG savings target of 60% for biofuels, however the potential for commercial viability was substantially improved by scaling up operations: GHG emissions and energy demand, per unit of biogas, was almost halved by scaling operations up by a factor of twenty, thereby approaching the EROI and GHG savings targets set, under beneficial biogas production conditions. Further analysis identified processes whose optimisations would have a large impact on energy use and emissions (such as anaerobic digestion) as well as others embodying potential for further economies of scale (such as harvesting), both of which would be of interest for future developments of kelp to biogas and fertilizer biorefineries.

  16. Performance of photoperiod and light intensity on biogas upgrade and biogas effluent nutrient reduction by the microalgae Chlorella sp.

    Science.gov (United States)

    Yan, Cheng; Zheng, Zheng

    2013-07-01

    Biogas is an environment-friendly fuel but that must be upgraded before being utilized. The method about removing CO2 from biogas by microalgal culturing using biogas effluent as nutrient medium in this study could effectively upgrade biogas and simultaneously reduce the biogas effluent nutrient. Results showed that the optimum parameters for microalgal growth and biogas effluent nutrient reduction was moderate light intensity with middle photoperiod. While low light intensity with long photoperiod and moderate light intensity with middle photoperiod obtained the best biogas CO2 removal and biogas upgrade effects. Therefore, the optimal parameters were moderate light intensity 350 μmol m(-2)s(-1) with middle photoperiod 14 h light:10h dark. Under this condition, the microalgal dry weight, CH4 concentration, reduction efficiency of chemical oxygen demand, total nitrogen, and total phosphorus was 615.84 ± 33.07 mg L(-1), 92.16 ± 2.83% (v/v), 88.74 ± 3.45%, 83.94 ± 3.51%, and 80.43 ± 4.17%, respectively.

  17. Reviewing the anaerobic digestion and co-digestion process of food waste from the perspectives on biogas production performance and environmental impacts.

    Science.gov (United States)

    Chiu, Sam L H; Lo, Irene M C

    2016-12-01

    In this paper, factors that affect biogas production in the anaerobic digestion (AD) and anaerobic co-digestion (coAD) processes of food waste are reviewed with the aim to improve biogas production performance. These factors include the composition of substrates in food waste coAD as well as pre-treatment methods and anaerobic reactor system designs in both food waste AD and coAD. Due to the characteristics of the substrates used, the biogas production performance varies as different effects are exhibited on nutrient balance, inhibitory substance dilution, and trace metal element supplement. Various types of pre-treatment methods such as mechanical, chemical, thermal, and biological methods are discussed to improve the rate-limiting hydrolytic step in the digestion processes. The operation parameters of a reactor system are also reviewed with consideration of the characteristics of the substrates. Since the environmental awareness and concerns for waste management systems have been increasing, this paper also addresses possible environmental impacts of AD and coAD in food waste treatment and recommends feasible methods to reduce the impacts. In addition, uncertainties in the life cycle assessment (LCA) studies are also discussed.

  18. Performance analysis of upflow anaerobic sludge blanket reactors in the treatment of swine wastewater

    Directory of Open Access Journals (Sweden)

    Luiz A. V. Sarmento

    2007-07-01

    Full Text Available The adoption of confined systems for swine production have been increased the use of water in these installations and, consequently, an each time greater production of wastewater. Diagnostics have been showed a high level of water pollution due the waste material release on lands without criterions and in waters without previous treatment. The utilization of anaerobic process to reduce the liquid residues pollutant power has been detaching because beyond reducing the environmental pollution they allow to recover the energetic potential as fertilizer and biogas. In this work the performance of two real scale upflow anaerobic sludge blanket reactors treating swine wastewater were evaluated through operational system analysis, physical-chemical parameters of pollution and biogas production measurement. The results permitted to verify upflow rate speeds above of the value for which these reactors were designed and hydraulic residence times under of the design value. These factors affected negatively the treatment and had reflected on the law removal of the physical-chemical parameters and biogas production. The maximum removal efficiencies reached for TSS, BOD and COD were 72,5%, 34,7% and 40,0%, respectively. The mean rate of biogas liberation was 0,011 m-³ m-².h-1.

  19. Utilization of high-strength wastewater for the production of biogas as a renewable energy source using hybrid upflow anaerobic sludge blanket (HUASB) reactor

    Energy Technology Data Exchange (ETDEWEB)

    Shivayogimath, C.B.; Ramanujam, T.K.

    1998-07-01

    Anaerobic digestion of distillery spentwash, a high-strength wastewater, was studied using a hybrid upflow anaerobic sludge blanket (HUASB) reactor for 240 days under ambient conditions. The HUASB reactor combined an open volume in the bottom two-thirds of the reactor for sludge blanket and polypropylene pall rings packing in the upper one-third of the reactor. The aim of the study was to achieve optimum biogas production and waste treatment. Using non-granular anaerobic sewage sludge as seed, the start-up of the HUASB reactor was successfully completed, with the production of active bacterial granules of 1--2 mm size, within 90 days. Examination of the bacterial granules under scanning electron microscope (SEM) revealed that Methanothrix like microorganisms were the dominant species besides Methanosarcina. An organic loading of 24 kg COD/m{sup 3}d at a low hydraulic retention time (HRT) of 6 hours was achieved with 82% reduction in COD. Biogas with high methane content (80%) was produced at these loadings. The specific biogas yield was 0.36 m{sup 3} CH{sub 4}/kg COD. Packing in the upper third of the reactor was very efficient as a gas-solid separator (GSS); and in addition it retained the biomass.

  20. Performance of a flameless combustion furnace using biogas and natural gas.

    Science.gov (United States)

    Colorado, A F; Herrera, B A; Amell, A A

    2010-04-01

    Flameless combustion technology has proved to be flexible regarding the utilization of conventional fuels. This flexibility is associated with the main characteristic of the combustion regime, which is the mixing of the reactants above the autoignition temperature of the fuel. Flameless combustion advantages when using conventional fuels are a proven fact. However, it is necessary to assess thermal equipments performance when utilizing bio-fuels, which usually are obtained from biomass gasification and the excreta of animals in bio-digesters. The effect of using biogas on the performance of an experimental furnace equipped with a self-regenerative Flameless burner is reported in this paper. All the results were compared to the performance of the system fueled with natural gas. Results showed that temperature field and uniformity are similar for both fuels; although biogas temperatures were slightly lower due to the larger amount of inert gases (CO(2)) in its composition that cool down the reactions. Species patterns and pollutant emissions showed similar trends and values for both fuels, and the energy balance for biogas showed a minor reduction of the efficiency of the furnace; this confirms that Flameless combustion is highly flexible to burn conventional and diluted fuels. Important modifications on the burner were not necessary to run the system using biogas. Additionally, in order to highlight the advantages of the Flameless combustion regime, some comparisons of the burner performance working in Flameless mode and working in conventional mode are presented.

  1. Anaerobic co-digestion of biodiesel waste glycerin with municipal wastewater sludge: microbial community structure dynamics and reactor performance.

    Science.gov (United States)

    Razaviarani, Vahid; Buchanan, Ian D

    2015-04-01

    Two 10 L completely mixed reactors operating at 37°C and 20 days SRT were used to evaluate the relationships between reactor performance and microbial community dynamics during anaerobic co-digestion of biodiesel waste glycerin (BWG) with municipal wastewater sludge (MWS). The addition of up to 1.35% (v/v) BWG to reactor feeds yielded increased VS and COD removal together with enhanced the biogas production and methane yield. This represented 50% of the MWS feed COD. Pyrosequencing analysis showed Methanosaeta (acetoclastic) and Methanomicrobium (hydrogenotrophic) to be the methanogenic genera present in greatest diversity during stable reactor operation. Methanosaeta sequences predominated at the lowest BWG loading while those of Methanomicrobium were present in greatest abundance at the higher BWG loadings. Genus Candidatus cloacamonas was present in the greatest number of bacterial sequences at all loadings. Alkalinity, pH, biogas production and methane yield declined and VFA concentrations (especially propionate) increased during the highest BWG loading.

  2. High rate biomethanation technology for solid waste management and rapid biogas production: An emphasis on reactor design parameters.

    Science.gov (United States)

    Dahiya, Shikha; Joseph, Johny

    2015-01-01

    A high rate biomethanation digester was designed and fabricated to study its real field treatment efficiency and simultaneous biogas generation. The major design parameters like self mixing, delinking hydraulic retention time and solid retention time etc. were considered for efficient performance. It was operated with an organic loading rate (OLR) of 1.5kg/m(3)d(-1) with composite food waste for about one year. The maximum treatment efficiency achieved with respect to total solid (TS) reduction and volatile solids (VS) reduction was 94.5% and 89.7%, respectively. Annual mean biogas of about 0.16m(3)/kgVSd(-1) was observed with methane content varying from 56% to 60% (v/v). The high competence of high rate digester is attributed to its specific design features and intermittent mixing of the digester contents and also due to the hydrodynamic principles involved in its operation.

  3. Performance of a cycle Otto engine using biogas; Desempenho de um motor ciclo Otto utilizando biogas como combustivel

    Energy Technology Data Exchange (ETDEWEB)

    Souza, Juliano de [Universidade Estadual do Oeste do Parana (UNIOESTE), Cascavel, PR (Brazil). Centro de Ciencias Exatas e Tecnologicas], e-mail: jsouza@unioeste.br; Souza, Samuel N. Melegari de [Universidade Estadual do Oeste do Parana (UNIOESTE), Cascavel, PR (Brazil)], e-mail: ssouza@unioeste.br; Machado, Paulo Romeu M. [Universidade Federal de Santa Maria (UFSM), RS (Brazil). Dept. de Engenharia Mecanica

    2004-07-01

    The rising of the oil prices is increasing the search for alternative fuels. Brazil has a great availability of biogas from anaerobic digestion in the rural area, urban waste in the landfills and treatment of the municipal sewer. In this work were evaluated in dynamometer a cycle Otto engine using biogas, and were obtained the characteristics curves of torque and power. First was done the evidence test with gasoline, biogas and natural gas, using commercial systems for this fuels, using as comparison for other tests. After has been done tests for some combinations of ignition point, mixer of gas and compression tax. By the analysis of the results has been concluded that the better results for power and torque using biogas as fuel were with a tax compression of 12,5:1, gas mixer long and ignition point advanced in 45 deg. (author)

  4. Aerobic desulfurization of biogas by acidic biotrickling filtration in a randomly packed reactor

    Energy Technology Data Exchange (ETDEWEB)

    Montebello, Andrea M.; Mora, Mabel; López, Luis R.; Bezerra, Tercia [Department of Chemical Engineering, School of Engineering, Universitat Autònoma de Barcelona, 08193 Bellaterra, Barcelona (Spain); Gamisans, Xavier [Department of Mining Engineering and Natural Resources, Universitat Politècnica de Catalunya, Bases de Manresa 61-73, 08240 Manresa (Spain); Lafuente, Javier [Department of Chemical Engineering, School of Engineering, Universitat Autònoma de Barcelona, 08193 Bellaterra, Barcelona (Spain); Baeza, Mireia [Department of Chemistry, Universitat Autònoma de Barcelona, 08193 Bellaterra, Barcelona (Spain); Gabriel, David, E-mail: david.gabriel@uab.cat [Department of Chemical Engineering, School of Engineering, Universitat Autònoma de Barcelona, 08193 Bellaterra, Barcelona (Spain)

    2014-09-15

    Highlights: • Desulfurization of high loads of H{sub 2}S is feasible by acidic biotrickling filtration. • Robustness of the process is demonstrated in the long-term (550 d). • Biosulfur to sulfate oxidation under H{sub 2}S starvation was successfully performed. • Lower sulfate production found at acidic pH compared to that at neutral pH. • Plastic material is recommended for long-term acidic biotrickling filtration. - Abstract: Biotrickling filters for biogas desulfurization still must prove their stability and robustness in the long run under extreme conditions. Long-term desulfurization of high loads of H{sub 2}S under acidic pH was studied in a lab-scale aerobic biotrickling filter packed with metallic Pall rings. Reference operating conditions at steady-state corresponded to an empty bed residence time (EBRT) of 130 s, H{sub 2}S loading rate of 52 g S–H{sub 2}S m{sup −3} h{sup −1} and pH 2.50–2.75. The EBRT reduction showed that the critical EBRT was 75 s and the maximum EC 100 g S–H{sub 2}S m{sup −3} h{sup −1}. Stepwise increases of the inlet H{sub 2}S concentration up to 10,000 ppm{sub v} lead to a maximum EC of 220 g S–H{sub 2}S m{sup −3} h{sup −1}. The H{sub 2}S removal profile along the filter bed indicated that the first third of the filter bed was responsible for 70–80% of the total H{sub 2}S removal. The oxidation rate of solid sulfur accumulated inside the bioreactor during periodical H{sub 2}S starvation episodes was verified under acidic operating conditions. The performance under acidic pH was comparable to that under neutral pH in terms of H{sub 2}S removal capacity. However, bioleaching of the metallic packing used as support and chemical precipitation of sulfide/sulfur salts occurred.

  5. Chemical speciation of sulfur and metals in biogas reactors - Implications for cobalt and nickel bio-uptake processes.

    Science.gov (United States)

    Yekta, Sepehr Shakeri; Skyllberg, Ulf; Danielsson, Åsa; Björn, Annika; Svensson, Bo H

    2017-02-15

    This article deals with the interrelationship between overall chemical speciation of S, Fe, Co, and Ni in relation to metals bio-uptake processes in continuous stirred tank biogas reactors (CSTBR). To address this topic, laboratory CSTBRs digesting sulfur(S)-rich stillage, as well as full-scale CSTBRs treating sewage sludge and various combinations of organic wastes, termed co-digestion, were targeted. Sulfur speciation was evaluated using acid volatile sulfide extraction and X-ray absorption spectroscopy. Metal speciation was evaluated by chemical fractionation, kinetic and thermodynamic analyses. Relative Fe to S content is identified as a critical factor for chemical speciation and bio-uptake of metals. In reactors treating sewage sludge, quantity of Fe exceeds that of S, inducing Fe-dominated conditions, while sulfide dominates in laboratory and co-digestion reactors due to an excess of S over Fe. Under sulfide-dominated conditions, metals availability for microorganisms is restricted due to formation of metal-sulfide precipitates. However, aqueous concentrations of different Co and Ni species were shown to be sufficient to support metal acquisition by microorganisms under sulfidic conditions. Concentrations of free metal ions and labile metal complexes in aqueous phase, which directly participate in bio-uptake processes, are higher under Fe-dominated conditions. This in turn enhances metal adsorption on cell surfaces and bio-uptake rates.

  6. Microbial diversity and dynamicity of biogas reactors due to radical changes of feedstock composition

    DEFF Research Database (Denmark)

    De Francisci, Davide; Kougias, Panagiotis; Treu, Laura;

    2015-01-01

    substrate change. The greatest increase in diversity was observed in the reactor supplemented with carbohydrates and the microbial community became dominated by lactobacilli, while the lowest corresponded to the reactor overfed with proteins, where only Desulfotomaculum showed significant increase...

  7. Long-term stability of thermophilic co-digestion submerged anaerobic membrane reactor encountering high organic loading rate, persistent propionate and detectable hydrogen in biogas.

    Science.gov (United States)

    Qiao, Wei; Takayanagi, Kazuyuki; Niu, Qigui; Shofie, Mohammad; Li, Yu You

    2013-12-01

    The performance of thermophilic anaerobic co-digestion of coffee grounds and sludge using membrane reactor was investigated for 148 days, out of a total research duration of 263 days. The OLR was increased from 2.2 to 33.7 kg-COD/m(3)d and HRT was shortened from 70 to 7 days. A significant irreversible drop in pH confirmed the overload of reactor. Under a moderately high OLR of 23.6 kg-COD/m(3)d, and with HRT and influent total solids of 10 days and 150 g/L, respectively, the COD removal efficiency was 44.5%. Hydrogen in biogas was around 100-200 ppm, which resulted in the persistent propionate of 1.0-3.2g/L. The VFA consumed approximately 60% of the total alkalinity. NH4HCO3 was supplemented to maintain alkalinity. The stability of system relied on pH management under steady state. The 16SrDNA results showed that hydrogen-utilizing methanogens dominates the archaeal community. The propionate-oxidizing bacteria in bacterial community was insufficient.

  8. Effects of mixing system and pilot fuel quality on diesel-biogas dual fuel engine performance.

    Science.gov (United States)

    Bedoya, Iván Darío; Arrieta, Andrés Amell; Cadavid, Francisco Javier

    2009-12-01

    This paper describes results obtained from CI engine performance running on dual fuel mode at fixed engine speed and four loads, varying the mixing system and pilot fuel quality, associated with fuel composition and cetane number. The experiments were carried out on a power generation diesel engine at 1500 m above sea level, with simulated biogas (60% CH(4)-40% CO(2)) as primary fuel, and diesel and palm oil biodiesel as pilot fuels. Dual fuel engine performance using a naturally aspirated mixing system and diesel as pilot fuel was compared with engine performance attained with a supercharged mixing system and biodiesel as pilot fuel. For all loads evaluated, was possible to achieve full diesel substitution using biogas and biodiesel as power sources. Using the supercharged mixing system combined with biodiesel as pilot fuel, thermal efficiency and substitution of pilot fuel were increased, whereas methane and carbon monoxide emissions were reduced.

  9. COD biological removal and biogas production in anaerobic reactor treating cassava wastewater industry; Remocao biologica de DQO e producao de biogas em reator anaerobio tratando efluente de fecularia de madioca

    Energy Technology Data Exchange (ETDEWEB)

    Watthier, Elisangela [Universidade Estadual do Oeste do Parana (UNIOESTE), Cascavel, PR (Brazil). Curso de Mestrado em Engenharia Agricola; Andreani, Cristiane Lurdes [Conselho Nacional de Desenvolvimento Cientifico e Tecnologico (CNPq), Brasilia, DF (Brazil); Gomes, Simone Damasceno [Universidade Estadual do Oeste do Parana (PGEAGRI/UNIOESTE), Cascavel, PR (Brazil). Programa de Pos-Graduacao em Engenharia Agricola; Moreschi, Roberson; Rufino, Mauricio de Oliveira [Universidade Estadual do Oeste do Parana (UNIOESTE), Cascavel, PR (Brazil). Curso de Engenharia Agricola

    2010-07-01

    The effluent from the cassava industry cause damage to the environment if released without treatment. One alternative is the implementation of anaerobic reactors, which also add value through the production of biogas. The support means increases the contact surface of micro-organisms and enhance their setting. The purpose of this study was to evaluate the reduction of organic matter (DQO) and biogas production in a reactor of PVC with 90 cm long and 15 cm in diameter, through support rings of bamboo, 10 cm in length and diameter ranged from 1.7 to 2.5 cm, with a volume of 6 L. The organic loading used were 4,357, 4,708, 5,601 and 6,126 g DQO.L-1.day-1, corresponding to hydraulic retention time (TRH) of 3,5, 2,8, 3,25 and 2,7 days, respectively. It was observed that with the increase of organic load was increased production of biogas, the largest observed for a load of 6.126 g DQO.L-1.day-1 with an average of 9.146 L.day-1. Regarding the removal of organic matter were achieved values of 98.35, 99.09, 99.33 and 98.55% respectively for each load applied, with the highest efficiency observed in charge of 5.601 g COD. L-1. day-1, but without significant differences. (author)

  10. Biogas and reduction of organic matter in anaerobic reactor with continuous flow means support; Producao de biogas e reducao de materia organica em reatores anaerobicos de fluxo continuo com meio suporte

    Energy Technology Data Exchange (ETDEWEB)

    Kunzler, Kathia Regina; Gomes, Simone Damasceno; Goncalves, Jefferson Luiz; Kuczman, Osvaldo [Universidade Estadual do Oeste do Parana (PGEAGRI/UNIOESTE), Cascavel, PR (Brazil). Programa de Pos-Graduacao em Engenharia Agricola], Emails: kathiark@yahoo.com.br, simoned@unioeste.br; Piana, Pitagoras Augusto [Universidade Estadual do Oeste do Parana (UNIOESTE), Toledo, PR (Brazil)

    2010-07-01

    Starch processing industries are to obtain cassava starch. Its main residue is the effluent resulting from pressing the roots, Manipueira, high organic load and toxic. In this study, we compared the removal efficiency of organic loading and biogas production in anaerobic reactors, with the support means bamboo in different relations width: height. The first lesion diameter of 15 cm and a length of 90 cm, a ratio 1:6 and the second with a diameter of 20 cm and 60 cm long, ratio of 1:3. The support medium consisted of rings of bamboo with 10 cm length and diameters between 1.7 and 2.5 cm. The loads applied were 0.519, 1.156, 1.471, 3.813, 4.347, 4.708 and 5.601gDQO/L.day. To evaluate the removal efficiency of organic matter, the samples were subjected to analysis of DQO biogas production was assessed in terms of organic load removed. Bamboo as a support allowed the application of higher loads. The higher efficiency in the production of biogas was produced in the reactor with the highest ratio width: height, being more significant for the organic load of 5, 601 gCOD/L.day, showing more stability this. (author)

  11. Ultrasound assisted biogas production from landfill leachate

    Energy Technology Data Exchange (ETDEWEB)

    Oz, Nilgün Ayman, E-mail: nilgunayman@comu.edu.tr; Yarimtepe, Canan Can

    2014-07-15

    Highlights: • Effect of low frequency ultrasound pretreatment on leachate was investigated. • Three different ultrasound energy inputs (200, 400 and 600 W/l) was applied. • Low-frequency ultrasound treatment increased soluble COD in landfill leachate. • Application of ultrasound to leachate increased biogas production about 40%. • Application of ultrasound to leachate increased total methane production rate about 20%. - Abstract: The aim of this study is to increase biogas production and methane yield from landfill leachate in anaerobic batch reactors by using low frequency ultrasound as a pretreatment step. In the first part of the study, optimum conditions for solubilization of organic matter in leachate samples were investigated using various sonication durations at an ultrasound frequency of 20 kHz. The level of organic matter solubilization during ultrasonic pretreatment experiments was determined by calculating the ratio of soluble chemical oxygen demand (sCOD) to total chemical oxygen demand (tCOD). The sCOD/tCOD ratio was increased from 47% in raw leachate to 63% after 45 min sonication at 600 W/l. Non-parametric Friedman’s test indicated that ultrasonic pretreatment has a significant effect on sCOD parameter for leachate (p < 0.05). In the second part of the study, anaerobic batch reactors were operated for both ultrasonically pretreated and untreated landfill leachate samples in order to assess the effect of sonication on biogas and methane production rate. In anaerobic batch reactor feed with ultrasonically pretreated leachate, 40% more biogas was obtained compared to the control reactor. For statistical analysis, Mann–Whitney U test was performed to compare biogas and methane production rates for raw and pretreated leachate samples and it has been found that ultrasonic pretreatment significantly enhanced biogas and methane production rates from leachate (p < 0.05) in anaerobic batch reactors. The overall results showed that low frequency

  12. Birds heater adaptation and performance using biogas as fuel; Avaliacao do desempenho de um aquecedor para aves adaptado para utilizar biogas como combustivel

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2007-09-15

    It was carried out a trial to evaluate the adaptation (injector diameter) and performance (biogas consumption and heating efficiency) of a heating adapted to burn biogas. It was tried a common heater, burning liquefied petroleum gas (LPG), operating with low gas pressure (28 cm water column), with calorific capacity of 5024 kJ/h and recommended for 500 birds. The heater was evaluated with the original fuel (LPG) without any modification in the gas injector and after adapting to biogas burning. Five injectors were evaluated with drillings of 1,0053; 1,5080; 1,5708; 1,7672 and 1,980 mm{sup 2}. It also was varied the biogas pressures in the heater entrance of 10, 12, 15, 17 and 20 cm of water column. Results showed that expressions for theoretical calculation and proposed parameters in the literature can be used for aviaries heaters adaptation. The adaptation is simple, indicating the viability for utilization of existing heaters in farms and in the market. Air temperatures were similar to the obtained with the original fuel (LPG). (author)

  13. Dynamic functional characterization and phylogenetic changes due to Long Chain Fatty Acids pulses in biogas reactors

    DEFF Research Database (Denmark)

    Kougias, Panagiotis; Treu, Laura; Campanaro, Stefano;

    2016-01-01

    The process stability of biogas plants is often deteriorated by the accumulation of Long Chain Fatty Acids (LCFA). The microbial community shifts due to LCFA disturbances have been poorly understood as the molecular techniques used were not able to identify the genome characteristics of uncultured...... microorganisms, and additionally, the presence of limited number of reference genomes in public databases prevented the comprehension of specific functional roles characterizing these microorganisms. The present study is the first research which deciphers by means of high throughput shotgun sequencing...

  14. Effect of operating conditions and reactor configuration on efficiency of full-scale biogas plants

    DEFF Research Database (Denmark)

    Angelidaki, Irini; Boe, Kanokwan; Ellegaard, L.

    2005-01-01

    /l. VFA concentration increase was observed in occasions with dramatic overloading or other disturbances such as operational temperature changes. Ammonia was found to be a significant factor for stability. A correlation between increased residual biogas production and high ammonia was found. When ammonia...... was higher than approx. 4 g-N/l the degradation efficiency of the plant decreased and as a consequence, the residual methane potential was high. Decrease of the residual methane potential with increasing hydraulic retention time was found. Digestion temperature was very important for effective post......-digestion. Post-digestion for recovering the residual methane potential at temperatures below 15 degrees C was very inefficient....

  15. Biogas production from potato-juice, a by-product from potato-starch processing, in upflow anaerobic sludge blanket (UASB) and expanded granular sludge bed (EGSB) reactors

    DEFF Research Database (Denmark)

    Fang, Cheng; Boe, Kanokwan; Angelidaki, Irini

    2011-01-01

    In this study, the utilization of potato-juice, the organic by-product from potato-starch processing, for biogas production was investigated in batch assay and in high rate anaerobic reactors. The maximum methane potential of the potato-juice determined by batch assay was 470mL-CH4/g......VS-added. Anaerobic digestion of potato-juice in an EGSB reactor could obtain a methane yield of 380mL-CH4/gVS-added at the organic loading rate of 3.2gCOD/(L-reactor.d). In a UASB reactor, higher organic loading rate of 5.1gCOD/(L-reactor.d) could be tolerated, however, it resulted in a lower methane yield of 240m...

  16. Performance assessment of natural gas and biogas fueled molten carbonate fuel cells in carbon capture configuration

    Science.gov (United States)

    Barelli, Linda; Bidini, Gianni; Campanari, Stefano; Discepoli, Gabriele; Spinelli, Maurizio

    2016-07-01

    The ability of MCFCs as carbon dioxide concentrator is an alternative solution among the carbon capture and storage (CCS) technologies to reduce the CO2 emission of an existing plant, providing energy instead of implying penalties. Moreover, the fuel flexibility exhibited by MCFCs increases the interest on such a solution. This paper provides the performance characterization of MCFCs operated in CCS configuration and fed with either natural gas or biogas. Experimental results are referred to a base CCS unit constituted by a MCFC stack fed from a reformer and integrated with an oxycombustor. A comparative analysis is carried out to evaluate the effect of fuel composition on energy efficiency and CO2 capture performance. A higher CO2 removal ability is revealed for the natural feeding case, bringing to a significant reduction in MCFC total area (-11.5%) and to an increase in produced net power (+13%). Moreover, the separated CO2 results in 89% (natural gas) and 86.5% (biogas) of the CO2 globally delivered by the CCS base unit. Further investigation will be carried out to provide a comprehensive assessment of the different solutions eco-efficiency considering also the biogas source and availability.

  17. Investigation of factors influencing biogas production in a large-scale thermophilic municipal biogas plant

    Energy Technology Data Exchange (ETDEWEB)

    Weiss, Agnes; Jerome, Valerie; Freitag, Ruth [Bayreuth Univ. (Germany). Chair for Process Biotechnology; Burghardt, Diana; Likke, Likke; Peiffer, Stefan [Bayreuth Univ. (Germany). Dept. of Hydrology; Hofstetter, Eugen M. [RVT Process Equipment GmbH, Steinwiesen (Germany); Gabler, Ralf [BKW Biokraftwerke Fuerstenwalde GmbH, Fuerstenwalde (Germany)

    2009-10-15

    A continuously operated, thermophilic, municipal biogas plant was observed over 26 months (sampling twice per month) in regard to a number of physicochemical parameters and the biogas production. Biogas yields were put in correlation to parameters such as the volatile fatty acid concentration, the pH and the ammonium concentration. When the residing microbiota was classified via analysis of the 16S rRNA genes, most bacterial sequences matched with unidentified or uncultured bacteria from similar habitats. Of the archaeal sequences, 78.4% were identified as belonging to the genus Methanoculleus, which has not previously been reported for biogas plants, but is known to efficiently use H{sub 2} and CO{sub 2} produced by the degradation of fatty acids by syntrophic microorganisms. In order to further investigate the influence of varied amounts of ammonia (2-8 g/L) and volatile fatty acids on biogas production and composition (methane/CO{sub 2}), laboratory scale satellite experiments were performed in parallel to the technical plant. Finally, ammonia stripping of the process water of the technical plant was accomplished, a measure through which the ammonia entering the biogas reactor via the mash could be nearly halved, which increased the energy output of the biogas plant by almost 20%. (orig.)

  18. Ultrasound assisted biogas production from landfill leachate.

    Science.gov (United States)

    Oz, Nilgün Ayman; Yarimtepe, Canan Can

    2014-07-01

    The aim of this study is to increase biogas production and methane yield from landfill leachate in anaerobic batch reactors by using low frequency ultrasound as a pretreatment step. In the first part of the study, optimum conditions for solubilization of organic matter in leachate samples were investigated using various sonication durations at an ultrasound frequency of 20 kHz. The level of organic matter solubilization during ultrasonic pretreatment experiments was determined by calculating the ratio of soluble chemical oxygen demand (sCOD) to total chemical oxygen demand (tCOD). The sCOD/tCOD ratio was increased from 47% in raw leachate to 63% after 45 min sonication at 600 W/l. Non-parametric Friedman's test indicated that ultrasonic pretreatment has a significant effect on sCOD parameter for leachate (pbiogas and methane production rate. In anaerobic batch reactor feed with ultrasonically pretreated leachate, 40% more biogas was obtained compared to the control reactor. For statistical analysis, Mann-Whitney U test was performed to compare biogas and methane production rates for raw and pretreated leachate samples and it has been found that ultrasonic pretreatment significantly enhanced biogas and methane production rates from leachate (p<0.05) in anaerobic batch reactors. The overall results showed that low frequency ultrasound pretreatment can be potentially used for wastewater management especially with integration of anaerobic processes.

  19. Performance evaluation of a completely stirred anaerobic reactor treating pig manure at a low range of mesophilic conditions

    Energy Technology Data Exchange (ETDEWEB)

    Guo, Jianbin, E-mail: jianbinguo@gmail.com [Department of Environmental Engineering, Tsinghua University, Beijing 100084 (China); Dong, Renjie [College of Engineering, China Agricultural University, P.O. Box 184, Beijing 100083 (China); Clemens, Joachim [Institute of Crop Science and Resource Reservation (INRES), University of Bonn, Karlrobert-Kreiten-Strasse 13, 53115 Bonn (Germany); Wang, Wei [Department of Environmental Engineering, Tsinghua University, Beijing 100084 (China)

    2013-11-15

    Highlights: • The biogas process can run stably at 20 °C at extremely low OLR after long-term acclimation of bacteria. • A biogas plant running at 28 °C seems as efficient as that operated at 38 °C at low OLR of 1.3 g ODM L{sup −1} d{sup −1}. • Lower temperature operation is inadvisable for the commercial biogas plant running at rather high OLR. • The estimated sludge yield at 28 °C is higher than that at 38 °C. - Abstract: Many Chinese biogas plants run in the lower range of mesophilic conditions. This study evaluated the performance of a completely stirred anaerobic reactor treating pig manure at different temperatures (20, 28 and 38 °C). The start-up phase of the reactor at 20 °C was very long and extremely poor performance was observed with increasing organic loading rate (OLR). At an OLR of 4.3 g ODM L{sup −1} d{sup −1}, methane production at 28 °C was comparable (3% less) with that at 38 °C, but the risk of acidification was high at 28 °C. At low OLR (1.3 g ODM L{sup −1} d{sup −1}), the biogas process appeared stable at 28 °C and gave same methane yields as compared to the reactor operating at 38 °C. The estimated sludge yield at 28 °C was 0.065 g VSS g{sup −1} COD{sub removed,} which was higher than that at 38 °C (0.016 g VSS g{sup −1} COD{sub removed})

  20. A highly thermoactive and salt-tolerant α-amylase isolated from a pilot-plant biogas reactor.

    Science.gov (United States)

    Jabbour, Dina; Sorger, Anneke; Sahm, Kerstin; Antranikian, Garabed

    2013-04-01

    Aiming at the isolation of novel enzymes from previously uncultured thermophilic microorganisms, a metagenome library was constructed from DNA isolated from a pilot-plant biogas reactor operating at 55 °C. The library was screened for starch-degrading enzymes, and one active clone was found. An open reading frame of 1,461 bp encoding an α-amylase from an uncultured organism was identified. The amy13A gene was cloned in Escherichia coli, resulting in high-level expression of the recombinant amylase. The novel enzyme Amy13A showed the highest sequence identity (75%) to α-amylases from Petrotoga mobilis and Halothermothrix orenii. Amy13A is highly thermoactive, exhibiting optimal activity at 80 °C, and it is also highly salt-tolerant, being active in 25% (w/v) NaCl. Amy13A is one of the few enzymes that tolerate high concentrations of salt and elevated temperatures, making it a potential candidate for starch processing under extreme conditions.

  1. Purification of bioethanol effluent in an UASB reactor system with simultaneous biogas formation

    DEFF Research Database (Denmark)

    Torry-Smith, Mads Peter; Sommer, Peter; Ahring, Birgitte Kiær

    2003-01-01

    acid, 4-hydroxyacetophenone, and acetovanillone as compared to conversion of the inhibitors as sole substrate in synthetic media. Furthermore, experiments were carried out treating BEE in a laboratory-scale UASB reactor. The results showed a Chemical Oxygen Demand (COD) removal of 80% (w...

  2. An innovative bioelectrochemical-anaerobic digestion-coupled system for in-situ ammonia recovery and biogas enhancement: process performance and microbial ecology

    OpenAIRE

    Zhang, Yifeng; Angelidaki, Irini

    2014-01-01

    Ammonia (NH4+/NH3) inhibition during anaerobic digestion process is one of the most frequent problems existing in biogas plants, resulting in unstable process and reduced biogas production. In this study, we developed a novel hybrid system, consisted of a submersed microbial resource recovery cell (SMRC) and a continuous stirred tank reactor (CSTR), to prevent ammonia toxicity during anaerobic digestion by in-situ ammonia recovery and electricity production. In batch experiment, the ammonia c...

  3. Experimental and numerical analysis of the performance and exhaust gas emissions of a biogas/n-heptane fueled HCCI engine

    KAUST Repository

    Kozarac, Darko

    2016-09-12

    The use of highly reactive fuel as an ignition promoter enables operation of biogas fueled homogeneous charge compression ignition (HCCI) engine at low intake temperatures with practical control of combustion phasing. In order to gain some insight into this operation mode the influence of addition of n-heptane on combustion, performance, emissions and control of combustion phasing of a biogas fueled HCCI engine is experimentally researched and presented in this paper. Additionally, the performance analysis of the practical engine solution for such operation is estimated by using the numerical simulation of entire engine. The results showed that the introduction of highly reactive fuel results with a significant change in operating conditions and with a change in optimum combustion phasing. The addition of n-heptane resulted in lower nitrogen oxides and increased carbon monoxide emissions, while the unburned hydrocarbons emissions were strongly influenced by combustion phasing and at optimal conditions are lowered compared to pure biogas operation. The results also showed a practical operation range for strategies that use equivalence ratio as a control of load. Simulation results showed that the difference in performance between pure biogas and n-heptane/biogas operation is even greater when the practical engine solution is taken into account.

  4. Anaerobic digestion technology in livestock manure treatment for biogas production: a review

    Energy Technology Data Exchange (ETDEWEB)

    Nasir, Ismail M. [Department of Chemical and Environmental Engineering, Faculty of Engineering, Universiti Putra Malaysia, Selangor (Malaysia); Mohd Ghazi, Tinia I.; Omar, Rozita

    2012-06-15

    This article reviews the potential of anaerobic digestion (AD) for biogas production from livestock manure wastes and compares the operating and performance data for various anaerobic process configurations. It examines different kinds of manure waste treatment techniques and the influence of several parameters on biogas and methane yield. The comparison indicates that a variety of different operational conditions, various reactor configurations such as batch reactors, continuously stirred tank reactor (CSTR), plug flow reactor (PFR), up-flow anaerobic sludge blanket (UASB), anaerobic sequencing batch reactor (ASBR), temperature phased anaerobic digestion (TPAD), and continuous one- and two-stage systems, present a suitable technology for the AD of livestock manure waste. Main performance indicators are biogas and methane yield, degradation of volatile solids (VS), higher loading, and process stability with a short retention time. (copyright 2012 WILEY-VCH Verlag GmbH 8 Co. KGaA, Weinheim)

  5. Study on the flow characteristics and the wastewater treatment performance in modified internal circulation reactor.

    Science.gov (United States)

    Wang, Jiade; Xu, Weijun; Yan, Jingjia; Yu, Jianming

    2014-12-01

    A modified internal circulation (MIC) reactor with an external circulation system was proposed and the performance of treating dyeing wastewater using both MIC and typical IC reactor were compared. Utilization of the external circulation system in the MIC reactor could dramatically improve the mixing intensity of the biomass with the wastewater and resulted in better performance. The COD removal efficiency, biogas production, volatile fatty acids and effluent color were approximately 87%, 98 L d−1, 180 mg L−1 and 100 times, respectively, in the MIC reactor with a hydraulic retention time of 5 h and organic loading rate of 15 kg COD m−3 d−1. The hydrodynamics of the MIC reactor under different flows rate of external circulation were also analyzed using computational fluid dynamics (CFD) method. The optimal flow rate of external circulation was 12 L min−1, which resulted in a corresponding up-flow velocity of 40 m h−1. The consistency of the result between experiment and simulation validated the scientificity of CFD technique applied to numerical simulation of the MIC reactor.

  6. Performance and characterization of a newly developed self-agitated anaerobic reactor with biological desulfurization.

    Science.gov (United States)

    Kobayashi, Takuro; Li, Yu-You

    2011-05-01

    The continuous operation of a newly developed methane fermentation reactor, which requires no electricity for the agitation of the fermentation liquid was investigated, and the extent of the biological desulfurization was monitored. Inside the reactor, the continual change in the liquid level and the self-agitation, occurring between 5 and 16 times every day, distributed the organic load near the inlet port of the reactor, as well as providing a nutrient supply to the hydrogen sulfide oxidizing bacteria. At different COD(Cr) loading rates (5, 7, 10 kg m(3)d(-1)), the reactor achieved a biogas production yield of 0.72-0.82 m(3)g(-1)-TS, a COD(Cr) reduction of 79.4-85.5% and an average of 99% hydrogen sulfide removal. This investigation demonstrated that the self-agitated reactor is comparable in digestion performance to the completely stirred tank reactor (CSTR) investigated in a previous study, and that the desulfurization performance was significantly enhanced compared to the CSTR.

  7. In-reactor performance of pressure tubes in CANDU reactors

    Science.gov (United States)

    Rodgers, D. K.; Coleman, C. E.; Griffiths, M.; Bickel, G. A.; Theaker, J. R.; Muir, I.; Bahurmuz, A. A.; Lawrence, S. St.; Resta Levi, M.

    2008-12-01

    The pressure tubes in CANDU reactors have been operating for times up to about 25 years. The in-reactor performance of Zr-2.5Nb pressure tubes has been evaluated by sampling and periodic inspection. This paper describes the behaviour and discusses the factors controlling the behaviour of these components in currently operating CANDU reactors. The mechanical properties (such as ultimate tensile strength, UTS, and fracture toughness), and delayed-hydride-cracking properties (crack growth rate Vc, and threshold stress intensity factor, KIH) change with irradiation; the former reach a limiting value at a fluence of Pressure tubes exhibit elongation and diametral expansion. The deformation behaviour is a function of operating conditions and material properties that vary from tube-to-tube and as a function of axial location. Semi-empirical predictive models have been developed to describe the deformation response of average tubes as a function of operating conditions. For corrosion and, more importantly deuterium pickup, semi-empirical predictive models have also been developed to represent the behaviour of an average tube. The effect of material variability on corrosion behaviour is less well defined compared with other properties. Improvements in manufacturing have increased fracture resistance by minimising trace elements, especially H and Cl, and reduced variability by tightening controls on forming parameters, especially hot-working temperatures.

  8. Evaluation biogas production performance and dynamics of the microbial community in different straw.

    Science.gov (United States)

    Li, Xue; Liu, Yan-Hua; Zhang, Xin; Ge, Chang-Ming; Piao, Ren-Zhe; Wang, Wei-Dong; Zong, Jun-Cui; Zhao, Hong-Yan

    2016-11-04

    The development and utilization of crop straw biogas resources can effectively alleviate the shortage of energy, environmental pollution, and other issues. This study performed a continuous batch test at 35°C to assess methane production potential and volatile organic acid contents using the modified Gompertz equation. Illumina MiSeq platform sequencing, which is a sequencing method based on sequencing-by-synthesis, was used to compare archaeal community diversity, and denaturing gradient gel electrophoresis (DGGE) was used to analyze bacterial community diversity in rice straw, dry maize straw, silage maize straw, and tobacco straw. The results show that cumulative gas production values for silage maize straw, rice straw, dry maize straw, and tobacco straw were 4870, 4032.5, 3907.5, and 3628.3 mL/g ·VS , respectively, after 24 days. Maximum daily gas production values of silage maize straw and rice straw were 1025 and 904.17 mL/g middot;VS, respectively, followed by tobacco straw and dry maize straw. The methane content of all four kinds of straws was > 60%, particularly that of silage maize straw, which peaked at 67.3%. Biogas production from the four kinds of straw was in the order silage maize straw > rice straw > dry maize straw > tobacco straw, and the values were 1166.7, 1048.4, 890, and 637.4 mL/g middot;VS, respectively. The microbial community analysis showed that metabolism was mainly carried out by acetate-utilizing methanogens, and that Methanosarcina was the dominant archaeal genus in the four kinds of straw, and the DGGE bands belonged to the phyla Firmicutes, Bacteroidetes, and Chloroflexi. Silage maize is useful for biogas production because it contains four kinds of straw.

  9. Low-temperature upgrading of low-calorific biogas for CO2 mitigation using DBD-catalyst hybrid reactor

    Science.gov (United States)

    Nozaki, Tomohiro; Tsukijihara, Hiroyuki; Fukui, Wataru; Okazaki, Ken

    2006-10-01

    Although huge amounts of biogas, which consists of 20-60% of CH4 in CO2/N2, can be obtained from landfills, coal mines, and agricultural residues, most of them are simply flared and wasted: because global warming potential of biogas is 5-15 times as potent as CO2. Poor combustibility of such biogas makes it difficult to utilize in conventional energy system. The purpose of this project is to promote the profitable recovery of methane from poor biogas via non-thermal plasma technology. We propose low-temperature steam reforming of biogas using DBD generated in catalyst beds. Methane is partially converted into hydrogen, and then fed into internal combustion engines for improved ignition stability as well as efficient operation. Low-temperature steam reforming is beneficial because exhaust gas from an engine can be used to activate catalyst beds. Space velocity (3600-15000 hr-1), reaction temperature (300-650^oC), and energy cost (30-150 kJ per mol CH4) have been investigated with simulated biogas (20-60% CH4 in mixtures of CO2/N2). The DBD enhances reaction rate of CH4 by a factor of ten at given catalyst temperatures, which is a rate-determining step of methane steam reforming, while species concentration of upgraded biogas was governed by thermodynamic equilibrium in the presence of catalyst.

  10. Performance Analysis of a MCFC/MGT Hybrid Power System Bi-Fueled by City Gas and Biogas

    Directory of Open Access Journals (Sweden)

    Hongyu Huang

    2015-06-01

    Full Text Available This study evaluates the performance of a molten carbonate fuel cell and micro gas turbine (MCFC/MGT hybrid power system bi-fueled by city gas and biogas. The performance of the MCFC/MGT hybrid power system and MFCF/MGT hybrid power system response have been investigated experimentally and numerically. Results show that the MCFC, steam reformer, and catalytic combustor models are in agreement with the experimental results of the system fueled by city gas only and the system bi-fueled by city gas and biogas. The MFCF/MGT hybrid power system can have manifest operation with the addition of biogas at a flow rate of up to 150.0 Nm3·h−1, which is about 50% of the overall input heat value. In addition, the MCFC and MGT outputs decrease with the increase in the flow rate of added biogas, with an overall power generation efficiency ranging from 39.0% to 42.0%. Furthermore, the MCFC/MGT hybrid power system can be operated stably both at low amplitude with slow current change and large amplitude with rapid power conditions. Finally, the MCFC/MGT hybrid system bi-fueled by city gas and biogas may be applicable to the energy supply of the micro–grid network.

  11. Performance evaluation of restaurant food waste and biowaste to biogas pilot projects in China and implications for national policy.

    Science.gov (United States)

    De Clercq, Djavan; Wen, Zongguo; Fan, Fei

    2017-03-15

    The objective of this research was to conduct a performance evaluation of three food waste/biowaste-to-biogas pilot projects across 7 scenarios in China based on multi-criteria decision analysis (MCDA) methodology. The projects ranked included a food waste-biogas project in Beijing, a food waste-biogas project in Suzhou and a co-digestion project producing biomethane in Hainan. The projects were ranked from best to worst based on technical, economic and environmental criteria under the MCDA framework. The results demonstrated that some projects are encountering operational problems. Based on these findings, six national policy recommendations were provided: (1) shift away from capital investment subsidies to performance-based subsidies; (2) re-design feed in tariffs; (3) promote bio-methane and project clustering; (4) improve collection efficiency by incentivizing FW producers to direct waste to biogas projects; (5) incentivize biogas projects to produce multiple outputs; (6) incentivize food waste-based projects to co-digest food waste with other substrates for higher gas output.

  12. The kinetics of nitrogen removal and biogas production in an anammox non-woven membrane reactor.

    Science.gov (United States)

    Ni, Shou-Qing; Lee, Po-Heng; Sung, Shihwu

    2010-08-01

    The anammox non-woven membrane reactor (ANMR) is a novel reactor configuration to culture the slowly growing anammox bacteria. Different mathematical models were used to study the process kinetics of the nitrogen removal in the ANMR. The kinetics of nitrogen gas production of anammox process was first evaluated in this paper. For substrate removal kinetics, the modified Stover-Kincannon model and the Grau second-order model were more applicable to the ANMR than the first-order model and the Monod model. For nitrogen gas production kinetics, the Van der Meer and Heertjes model was more appropriate than the modified Stover-Kincannon model. Model evaluation was carried out by comparing experimental data with predicted values calculated from suitable models. Both model kinetics study and model testing showed that the Grau second-order model and the Van der Meer and Heertjes model seemed to be the best models to describe the nitrogen removal and nitrogen gas production in the ANMR, respectively.

  13. Co-digestion of manure and whey for in situ biogas upgrading by the addition of H2: process performance and microbial insights

    DEFF Research Database (Denmark)

    Luo, Gang; Angelidaki, Irini

    2013-01-01

    In situ biogas upgrading was conducted by introducing H2 directly to the anaerobic reactor. As H2 addition is associated with consumption of the CO2 in the biogas reactor, pH increased to higher than 8.0 when manure alone was used as substrate. By co-digestion of manure with acidic whey, the p......H in the anaerobic reactor with the addition of hydrogen could be maintained below 8.0, which did not have inhibition to the anaerobic process. The H2 distribution systems (diffusers with different pore sizes) and liquid mixing intensities were demonstrated to affect the gas-liquid mass transfer of H2 and the biogas...... composition. The best biogas composition (75:6.6:18.4) was obtained at stirring speed 150 rpmand using ceramic diffuser, while the biogas in the control reactor consisted of CH4 and CO2 at a ratio of 55:45. The consumed hydrogen was almost completely converted to CH4, and there was no significant accumulation...

  14. Performance Indicators of Operating Reactors

    Data.gov (United States)

    Nuclear Regulatory Commission — A list of Performance Indicators (PI) that are reported to the NRC by licensees at the end of each quarter in accordance with Inspection Manual Chapters (IMC) 0608,...

  15. BIOGAS PROCTION FROM ANAEROBIC CO-DIGESTION OF COW DUNG AND ORGANIC WASTES (NAPIER PAK CHONG I AND FOOD WASTE IN THAILAND: TEMPERATURE EFFECT ON BIOGAS PRODUCT

    Directory of Open Access Journals (Sweden)

    Lertluck Saitawee

    2014-01-01

    Full Text Available Biogas production has been attracting increasing attention as a biofuel of the future because biogas technology not only constitutes a biofuel source, but also can be applied in the various environmental pollutants. Anaerobic digestion of high solid slurries (such as food waste and cow dung is typically performed in continuously reactor (by force substrate flow to avoid problems with a thick floating layer or large amounts of sediments. Temperature also seems to have profound influence on the biogas production. The objective of the study was to identify the optimum biogas production for anaerobic co-digestion of cow dung and organic wastes (napierpakchong I and food waste. Influence of temperature (psyhrophilic temperature 25°C and thermoplilic temperature 45°C and active biogas process on single substrate (food waste feed and co-digestion of cow dung and organic wastes (napierpakchong I and food waste was used, within the reactor was studies in 1.80 cm high over a 45 day. Results showed that best digestion was achieved when digested of cow dung, napierpakchong I and food waste on 1:1:1 and thermoplilic temperature. Maximum biogas production (R4, biogas yield, methane content and %VS reduction was found that 70 L/day, 70 L/VS feed, 65 and 80%, respectively. The result showed that the biogas production increased progressively withhigher temperature.The increased in biogas production in thermophilic temperature and psyhrophilic temperature could be up 28.01 and 26%, respectively. The biogas yield increased 12.5% of co-digestion system, which compared to thermophilic temperature and psyhrophilic temperature (R4 and R2. This behavior might be due to the higher degradability. Therefore, temperature of digester can be used effectively as an operating strategy to optimize biogas production.

  16. MODIFIKASI KARBON AKTIF SEBAGAI ADSORBEN UNTUK PEMURNIAN BIOGAS

    Directory of Open Access Journals (Sweden)

    Heru Susanto

    2012-08-01

    Full Text Available The use of biogas as an environmentally friendly fuel is limited by the presence of CO2 and water vapor asimpurities. Therefore, biogas purification for CO2 and water vapor removal is very important step during biogasapplication. This paper presents a process for biogas purification by means of adsorption using either modifiedor unmodified activated carbon as an adsorbent. The modification was performed by passing a pure ammoniagas into activated carbon in a quartz reactor. The results showed that the adsorption process using modifiedactivated carbon decreases CO2 content in biogas up to 67.5% whereas for unmodified activated carbon was of43%. Further, the modification increased CO2 adsorption capacity from ~28 to ~38 mg CO2/g adsorbent. Theincrease in feed temperature decreases CO2 adsorption capacity.

  17. Enhanced biogas yield from energy crops with rumen anaerobic fungi

    Energy Technology Data Exchange (ETDEWEB)

    Prochazka, Jindrich; Zabranska, Jana; Dohanyos, Michal [Department of Water Technology and Environmental Engineering, Faculty of Environmental Technology, Institute of Chemical Technology in Prague, Prague (Czech Republic); Mrazek, Jakub; Strosova, Lenka; Fliegerova, Katerina [Laboratory of Anaerobic Microbiology, Institute of Animal Physiology and Genetics, CAS, v.v.i., Prague (Czech Republic)

    2012-06-15

    Anaerobic fungi (AF) are able to degrade crop substrates with higher efficiency than commonly used anaerobic bacteria. The aim of this study was to investigate ways of use of rumen AF to improve biogas production from energy crops under laboratory conditions. In this study, strains of AF isolated from feces or rumen fluid of cows and deer were tested for their ability to integrate into the anaerobic bacterial ecosystem used for biogas production, in order to improve degradation of substrate polysaccharides and consequently the biogas yield. Batch culture, fed batch culture, and semicontinuous experiments have been performed using anaerobic sludge from pig slurry fermentation and different kinds of substrates (celluloses, maize, and grass silage) inoculated by different genera of AF. All experiments showed a positive effect of AF on the biogas yield and quality. AF improved the biogas production by 4-22%, depending on the substrate and AF species used. However, all the cultivation experiments indicated that rumen fungi do not show long-term survival in fermenters with digestate from pig slurry. The best results were achieved during fed batch experiment with fungal culture Anaeromyces (KF8), in which biogas production was enhanced during the whole experimental period of 140 days. This result has not been achieved in semicontinuous experiment, where increment in biogas production in fungal enriched reactor was only 4% after 42 days. (copyright 2012 Wiley-VCH Verlag GmbH and Co. KGaA, Weinheim)

  18. Evaluation of silage-fed biogas process performance using microbiological and kinetic methods

    Energy Technology Data Exchange (ETDEWEB)

    Jarvis, Aa.

    1996-10-01

    In this study, different kinetic and microbiological methods were used to evaluate the growth and activity of key groups of bacteria degrading ley silage in one-phase and two-phase biogas processes. Emphasis was placed on studying the dynamic behaviour of different trophic groups resulting from the initiation of liquid recirculation in the processes. The microbiological methods included microscopy and most probable number (MPN) counts with different substrates. The kinetic methods included measurements of specific methanogenic activity (SMA) with acetate and H{sub 2}/CO{sub 2} as substrates, batch assays with trace element additions and measurement of conversion rates of mannitol and lactate in the digesters. In general, the initiation of liquid recirculation at first promoted the growth and/or activity of several trophic groups of bacteria, such as butyrate and propionate degraders and acetotrophic and hydrogenotrophic methanogens in the liquefaction/acidogenesis reactors of the two-phase processes. This was probably mainly due to the increased pH. However, after some time of liquid recirculation, an inhibition of some bacterial groups occurred, such as propionate degraders and methanogens in the methanogenic reactors of two-phase processes. This was probably due to increased concentrations of salts and free ammonia. The batch assays proved to be valuable tools in process optimization by the addition of trace elements. Here, the addition of cobalt significantly increased methane production from acetate. In this study, a more comprehensive understanding of the process behaviour in response to the initiation of liquid recirculation was achieved which could not have been obtained by only monitoring routine parameters such as pH, methane production and concentrations of organic acids and salts. 120 refs, 4 figs, 1 tab

  19. A novel bioinformatic strategy to characterise microbial communities in biogas reactors

    DEFF Research Database (Denmark)

    Treu, Laura; Campanaro, Stefano; De Francisci, Davide;

    2014-01-01

    , J.J. et al., 2011). For this reason we developed a bioinformatics strategy in order to create a tool to review the generated dataset and to obtain a more strict control on the bacterial composition at the species level, with estimation of its reliability. The program perform local similarity search...

  20. Co-digestion of manure and whey for in situ biogas upgrading by the addition of H(2): process performance and microbial insights.

    Science.gov (United States)

    Luo, Gang; Angelidaki, Irini

    2013-02-01

    In situ biogas upgrading was conducted by introducing H(2) directly to the anaerobic reactor. As H(2) addition is associated with consumption of the CO(2) in the biogas reactor, pH increased to higher than 8.0 when manure alone was used as substrate. By co-digestion of manure with acidic whey, the pH in the anaerobic reactor with the addition of hydrogen could be maintained below 8.0, which did not have inhibition to the anaerobic process. The H(2) distribution systems (diffusers with different pore sizes) and liquid mixing intensities were demonstrated to affect the gas-liquid mass transfer of H(2) and the biogas composition. The best biogas composition (75:6.6:18.4) was obtained at stirring speed 150 rpm and using ceramic diffuser, while the biogas in the control reactor consisted of CH(4) and CO(2) at a ratio of 55:45. The consumed hydrogen was almost completely converted to CH(4), and there was no significant accumulation of VFA in the effluent. The study showed that addition of hydrogen had positive effect on the methanogenesis, but had no obvious effect on the acetogenesis. Both hydrogenotrophic methanogenic activity and the concentration of coenzyme F(420) involved in methanogenesis were increased. The archaeal community was also altered with the addition of hydrogen, and a Methanothermobacter thermautotrophicus related band appeared in a denaturing gradient gel electrophoresis gel from the sample of the reactor with hydrogen addition. Though the addition of hydrogen increased the dissolved hydrogen concentration, the degradation of propionate was still thermodynamically feasible at the reactor conditions.

  1. DEVELOPMENT TRENDS OF BIOGAS

    Directory of Open Access Journals (Sweden)

    Mariana DUMITRU

    2015-04-01

    Full Text Available All over the world, researches are made in order to improve the technologies, the operational and process stability and performance of biogas plants, because the world markets for biogas increased considerably in Europe and all over the world. In this paper we studied the most important parameters related to a biogas plant, starting from the ecologic landfill of Cristian, Sibiu, a landfill which storages industrial and household waste. In this respect, we studied operational parameters, such as organic load and hydraulic retention time, and parameters for evaluation of a biogas plant. Also, we made a case study concerning the evaluation of used waters in the landfill described above under the aspect of pollution sources, way of treatment and evacuation mode of used waters. The existing biomass resources everywhere in the world can give us an idea of the global potential of biogas production, which is not exploited to its capacity, especially in our country.

  2. Progress in biogas II - Biogas production from agricultural biomass and organic residues. Pt. 1. Proceedings; Progress in Biogas II - Biogasproduktion aus landwirtschaftlicher Biomasse und organischen Reststoffen. T. 1. Tagungsband

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2011-08-12

    biogas production - Methabe yield and energy balance (R. Bolduan); (19) Evaluation of a pre-treatment process for improved methane production from grass silage (A. Orozco); (20) Anaerobic fungi and biogas production (J. Prochazka); (21) Preservation of sugar beets for biogas production (A. Wagner); (22) Fibre, biogas and compost from banana agro-residues (leaves, pseudostem and rachis) by anaerobic digestion in plug flow type digester (H. Chanakya); (23) Extraction of biogas from waste products of he sugarcane industry (J. Rietzler); (24) Practical experiences with the digestion of straw in 2-stage AD plants - Extension of the value chain (W. Danner); (25) Improving biogas production on wastewater treatment plants by co-digestion of grass (D. Klein); (26) Generation of algal biomass for biogas production: energetic and environmental from a Life Cycle Assessment (LCA) perspective (F. Romagnoli); (27) Risk reduction in spreading plant pathogens by anaerobic digestion? First results from laboratory experiments (M. Heiermann); (28) Demand-oriented biogas production for the generation of peak load (R. Wallmann); (29) Investigation of mesophilic and thermophilic bioleaching method in a two-phase anaerobic digestion process (M. Schoenberg): (30) Efficient hydrogen fermentation for 2-stage anaerobic digestion processes: Conversion of sucrose containing substrates (S. Noebauer); (31) Process development of two-phase pressure formation - Influence of gas solubilities (A.-M. Wonneberger); (32) Benefits and limitations when treating liquid pig manure in an anaerobic membrane bioreactor (P. Messerl); (33) Experiences with continuous high-rate thermophilic dry anaerobic digestion of energy crops (L. De Baere); (34) The Sauter-biogas-system: spraying instead of stirring (S. Sauter); (35) Biogas production from raw palm oil mill effluent using a pilot-scale anaerobic hybrid reactor (C. Wangnai); (36) Eta max - the biogas power plant with high biological efficiency (M. Niederbacher); (37

  3. Performance and Emissions of a Small Compression Ignition Engine Run on Dual-fuel Mode (Diesel-Raw biogas)

    Science.gov (United States)

    Ambarita, H.; Sinulingga, E. P.; Nasution, M. KM; Kawai, H.

    2017-03-01

    In this work, a compression ignition (CI) engine is tested in dual-fuel mode (Diesel-Raw biogas). The objective is to examine the performance and emission characteristics of the engine when some of the diesel oil is replaced by biogas. The specifications of the CI engine are air cooled single horizontal cylinder, four strokes, and maximum output power of 4.86 kW. It is coupled with a synchronous three phase generator. The load, engine revolution, and biogas flow rate are varied from 600 W to 1500 W, 1000 rpm to 1500 rpm, 0 to 6 L/minute, respectively. The electric power, specific fuel consumption, thermal efficiency, gas emission, and diesel replacement ratio are analyzed. The results show that there is no significant difference of the power resulted by CI run on dual-fuel mode in comparison with pure diesel mode. However, the specific fuel consumption and efficiency decrease significantly as biogas flow rate increases. On the other hand, emission of the engine on dual-fuel mode is better. The main conclusion can be drawn is that CI engine without significant modification can be operated perfectly in dual-fuel mode and diesel oil consumption can be decreased up to 87.5%.

  4. System for obtaining biogas. System zur Gewinnung von Biogas

    Energy Technology Data Exchange (ETDEWEB)

    Anon.

    1985-01-17

    The invention refers to a system for obtaining biogas from organic substances in at least one drum reactor, which is situated in a container accepting a liquid and which is driven so that it rotates preferably around its horizontal drum axis. It is distinguished by the fact that for at least one drum reactor acting as the main reactor there is at least one further reactor ahead of it for the pre-treatment or pre-fermentation of the substances.

  5. Kinetic evaluation and process performance of an upflow anaerobic filter reactor degrading terephthalic acid.

    Science.gov (United States)

    Davutluoglu, Orkun I; Seckin, Galip

    2014-01-01

    The anaerobic degradation of terephthalic acid (TA) as the sole organic carbon source was studied in an upflow anaerobic filter (UAF) reactor. The reactor was seeded with biomass obtained from a full-scale upflow anaerobic sludge bed (UASB) reactor and was used to treat wastewater from a petrochemical facility producing dimethyl terephthalate. The UAF reactor was operated for 252 d with a constant hydraulic retention time of 24 h, and the organic loading rate (OLR) was gradually increased from 1 to 10 g-chemical oxygen demand (COD)/L d. After a lag period of approximately 40 d, the COD removal efficiency increased exponentially and high removal rate values (≈90%) were obtained, except for at highest OLR (10 g-COD/L d). The high removal rates and the robustness of the reactor performance could be attributed to the formation of biofilm as well as granular sludge. The methane production rates (0.22 to 2.15 L/d) correlated well with the removed OLRs (0.3 to 6.8 g-COD/L d) during the various phases of treatment, indicating that the main mechanism of TA degradation occurs via methanogenic reactions. The average methane content of the produced biogas was 70.3%. The modified Stover-Kincannon model was found to be applicable for the anaerobic degradation of TA in UAFs (Umax = 64.5, KB = 69.1 g-COD/L d and Ymax = 0.27 L-CH4/g-CODremoved). These results suggest that UAF reactors are among the most effective reactor configurations for the anaerobic degradation of TA.

  6. Short-term effect of acetate and ethanol on methane formation in biogas sludge.

    Science.gov (United States)

    Refai, Sarah; Wassmann, Kati; Deppenmeier, Uwe

    2014-08-01

    Biochemical processes in biogas plants are still not fully understood. Especially, the identification of possible bottlenecks in the complex fermentation processes during biogas production might provide potential to increase the performance of biogas plants. To shed light on the question which group of organism constitutes the limiting factor in the anaerobic breakdown of organic material, biogas sludge from different mesophilic biogas plants was examined under various conditions. Therefore, biogas sludge was incubated and analyzed in anaerobic serum flasks under an atmosphere of N2/CO2. The batch reactors mirrored the conditions and the performance of the full-scale biogas plants and were suitable test systems for a period of 24 h. Methane production rates were compared after supplementation with substrates for syntrophic bacteria, such as butyrate, propionate, or ethanol, as well as with acetate and H2+CO2 as substrates for methanogenic archaea. Methane formation rates increased significantly by 35 to 126 % when sludge from different biogas plants was supplemented with acetate or ethanol. The stability of important process parameters such as concentration of volatile fatty acids and pH indicate that ethanol and acetate increase biogas formation without affecting normally occurring fermentation processes. In contrast to ethanol or acetate, other fermentation products such as propionate, butyrate, or H2 did not result in increased methane formation rates. These results provide evidence that aceticlastic methanogenesis and ethanol-oxidizing syntrophic bacteria are not the limiting factor during biogas formation, respectively, and that biogas plant optimization is possible with special focus on methanogenesis from acetate.

  7. Performance tests for integral reactor nuclear fuel

    Energy Technology Data Exchange (ETDEWEB)

    Sohn, Dong-Seong; Yim, Jeong-Sik; Lee, Chong-Tak; Kim, Han-Soo; Koo, Yang-Hyun; Lee, Byung-Ho; Cheon, Jin-Sik; Oh, Je-Yong

    2006-02-15

    An integral type reactor SMART plans to utilize metallic Zr-U fuel which is Zr-based alloy with 34{approx}38 wt% U. In order to verify the technologies for the design and manufacturing of the fuel and get a license, performance tests were carried out. Experimental Fuel Assembly (EFA) manufactured in KAERI is being successfully irradiated in the MIR reactor of RIAR from September 4 2004, and it has achieved burnup of 0.21 g/cc as of January 25 2006. Thermal properties of irradiated Zr-U fuel were measured. Up to the phase transformation temperature, thermal diffusivity increased linearly in proportion to temperature. However its dependence on the burnup was not significant. RIA tests with 4 unirradiated Zr-U fuel rods were performed in Kurchatov Institute to establish a safety criterion. In the case of the un-irradiated Zr-U fuel, the energy deposition during the control rod ejection accident should be less than 172 cal/g to prevent the failure accompanying fuel fragmentation and dispersal. Finally the irradiation tests of fuel rods have been performed at HANARO. The HITE-2 test was successfully completed up to a burnup of 0.31 g/cc. The HITE-3 test began in February 2004 and will be continued up to a target burnup of 0.6 g/cc.

  8. Complete genome sequence of the novel Porphyromonadaceae bacterium strain ING2-E5B isolated from a mesophilic lab-scale biogas reactor.

    Science.gov (United States)

    Hahnke, Sarah; Maus, Irena; Wibberg, Daniel; Tomazetto, Geizecler; Pühler, Alfred; Klocke, Michael; Schlüter, Andreas

    2015-01-10

    In this study, the whole genome sequence of the mesophilic, anaerobic Porphyromonadaceae bacterium strain ING2-E5B (LMG 28429, DSM 28696) is reported. The new isolate belongs to the phylum Bacteroidetes and was obtained from a biogas-producing lab-scale completely stirred tank reactor (CSTR) optimized for anaerobic digestion of maize silage in co-fermentation with pig and cattle manure. The genome of strain ING2-E5B contains numerous genes encoding proteins and enzymes involved in the degradation of complex carbohydrates and proteinaceous compounds. Moreover, it possesses genes catalyzing the production of volatile fatty acids. Hence, this bacterium was predicted to be involved in hydrolysis and acidogenesis during anaerobic digestion and biomethanation.

  9. Evaluation of the efficiency of a plug-flow digester to produce biogas from swine waste water; Avaliacao da eficiencia de um biodigestor tubular na producao de biogas a partir de aguas residuarias de suinocultura

    Energy Technology Data Exchange (ETDEWEB)

    Feiden, Armin [Universidade Estadual do Oeste do Parana (UNIOESTE), Marechal Candido Rondon, PR (Brazil). Centro de Ciencias Agrarias], e-mail: armin.feiden@creapr.org.br; Reichl, Johann [Escola de Energia Biolsolar, Quatro Pontes, PR (Brazil); Schwab, Jair; Schwab, Vera [Colegio Estadual Entre Rios do Oeste, PR (Brazil)

    2004-07-01

    The performance of a plug-flow digester, type Reichl, was evaluated with and without mixing. The digester, treating swine wastewater, had a capacity of 800 m{sup 3} and were operated at a loading rate of 0,931 kg and 0,634 kg of total solids and volatile solids per day, respectively. With mixing, the daily average biogas production was 289,50 m{sup 3} day{sup -1}, the specific volume production of 0,362 m{sup 3} biogas m{sup -3} reactor day{sup -1} and a specific biogas production of 0,389 m{sup 3} and 0,571 m{sup 3} biogas kg{sup -1} total solids and volatile solids added, respectively. Without mixing, was observed a reduction of 17,69% on the daily average biogas production, to only 238,30 m{sup 3} day{sup -1}. It correspond to a specific volume production of 0,298 m{sup 3} biogas m{sup -3} reactor day{sup -1} and a specific biogas production of 0,320 m{sup 3} and 0,470 m{sup 3} biogas kg{sup -1} total solids and volatile solids added, respectively. With mixing, a reduction of 68,67% total solids was achieved, compared to 52,11% without mixing. Considering volatile solids, it was achieved 80,16% with mixing, compared to 58,77% without mixing. (author)

  10. Improving the mixing performances of rice straw anaerobic digestion for higher biogas production by computational fluid dynamics (CFD) simulation.

    Science.gov (United States)

    Shen, Fei; Tian, Libin; Yuan, Hairong; Pang, Yunzhi; Chen, Shulin; Zou, Dexun; Zhu, Baoning; Liu, Yanping; Li, Xiujin

    2013-10-01

    As a lignocellulose-based substrate for anaerobic digestion, rice straw is characterized by low density, high water absorbability, and poor fluidity. Its mixing performances in digestion are completely different from traditional substrates such as animal manures. Computational fluid dynamics (CFD) simulation was employed to investigate mixing performances and determine suitable stirring parameters for efficient biogas production from rice straw. The results from CFD simulation were applied in the anaerobic digestion tests to further investigate their reliability. The results indicated that the mixing performances could be improved by triple impellers with pitched blade, and complete mixing was easily achieved at the stirring rate of 80 rpm, as compared to 20-60 rpm. However, mixing could not be significantly improved when the stirring rate was further increased from 80 to 160 rpm. The simulation results agreed well with the experimental results. The determined mixing parameters could achieve the highest biogas yield of 370 mL (g TS)(-1) (729 mL (g TS(digested))(-1)) and 431 mL (g TS)(-1) (632 mL (g TS(digested))(-1)) with the shortest technical digestion time (T 80) of 46 days. The results obtained in this work could provide useful guides for the design and operation of biogas plants using rice straw as substrates.

  11. Biogas utilization

    Energy Technology Data Exchange (ETDEWEB)

    Moser, M.A. [Resource Conservation Management, Inc., Berkeley, CA (United States)

    1996-01-01

    Options for successfully using biogas depend on project scale. Almost all biogas from anaerobic digesters must first go through a gas handling system that pressurizes, meters, and filters the biogas. Additional treatment, including hydrogen sulfide-mercaptan scrubbing, gas drying, and carbon dioxide removal may be necessary for specialized uses, but these are complex and expensive processes. Thus, they can be justified only for large-scale projects that require high-quality biogas. Small-scale projects (less than 65 cfm) generally use biogas (as produced) as a boiler fuel or for fueling internal combustion engine-generators to produce electricity. If engines or boilers are selected properly, there should be no need to remove hydrogen sulfide. Small-scale combustion turbines, steam turbines, and fuel cells are not used because of their technical complexity and high capital cost. Biogas cleanup to pipeline or transportation fuel specifications is very costly, and energy economics preclude this level of treatment.

  12. Performance comparison between mesophilic and thermophilic anaerobic reactors for treatment of palm oil mill effluent.

    Science.gov (United States)

    Jeong, Joo-Young; Son, Sung-Min; Pyon, Jun-Hyeon; Park, Joo-Yang

    2014-08-01

    The anaerobic digestion of palm oil mill effluent (POME) was carried out under mesophilic (37°C) and thermophilic (55°C) conditions without long-time POME storage in order to compare the performance of each condition in the field of Sumatra Island, Indonesia. The anaerobic treatment system was composed of anaerobic hybrid reactor and anaerobic baffled filter. Raw POME was pretreated by screw decanter to reduce suspended solids and residual oil. The total COD removal rate of 90-95% was achieved in both conditions at the OLR of 15kg[COD]/m(3)/d. The COD removal in thermophilic conditions was slightly better, however the biogas production was much higher than that in the mesophilic one at high OLR. The organic contents in pretreated POME were highly biodegradable in mesophilic under the lower OLRs. The biogas production was 13.5-20.0l/d at the 15kg[COD]/m(3)/d OLR, and the average content of carbon dioxide was 5-35% in both conditions.

  13. Performance evaluation of oxygen, air and nitrate for the microaerobic removal of hydrogen sulphide in biogas from sludge digestion.

    Science.gov (United States)

    Díaz, I; Lopes, A C; Pérez, S I; Fdz-Polanco, M

    2010-10-01

    The removal performance of hydrogen sulphide in severely polluted biogas produced during the anaerobic digestion of sludge was studied by employing pure oxygen, air and nitrate as oxidant reactives supplied to the biodigester. Research was performed in a 200-L digester with an hydraulic retention time (HRT) of ∼20 days under mesophilic conditions. The oxygen supply (0.25 N m³/m³ feed) to the bioreactor successfully reduced the hydrogen sulphide content from 15,811 mg/N m³ to less than 400 mg/N m³. The introduction of air (1.27 N m³/m³ feed) removed more than 99% of the hydrogen sulphide content, with a final concentration of ∼55 mg/N m³. COD removal, VS reduction and methane yield were not affected under microaerobic conditions; however, methane concentration in the biogas decreased when air was employed as a result of nitrogen dilution. The nitrate addition was not effective for hydrogen sulphide removal in the biogas.

  14. Improvement of biogas production by bioaugmentation.

    Science.gov (United States)

    Kovács, K L; Ács, N; Kovács, E; Wirth, R; Rákhely, G; Strang, Orsolya; Herbel, Zsófia; Bagi, Z

    2013-01-01

    Biogas production technologies commonly involve the use of natural anaerobic consortia of microbes. The objective of this study was to elucidate the importance of hydrogen in this complex microbial food chain. Novel laboratory biogas reactor prototypes were designed and constructed. The fates of pure hydrogen-producing cultures of Caldicellulosiruptor saccharolyticus and Enterobacter cloacae were followed in time in thermophilic and mesophilic natural biogas-producing communities, respectively. Molecular biological techniques were applied to study the altered ecosystems. A systematic study in 5-litre CSTR digesters revealed that a key fermentation parameter in the maintenance of an altered population balance is the loading rate of total organic solids. Intensification of the biogas production was observed and the results corroborate that the enhanced biogas productivity is associated with the increased abundance of the hydrogen producers. Fermentation parameters did not indicate signs of failure in the biogas production process. Rational construction of more efficient and sustainable biogas-producing microbial consortia is proposed.

  15. Biogas in the natural gas distribution network; Biogas til nettet

    Energy Technology Data Exchange (ETDEWEB)

    Kvist Jensen, T.

    2009-05-15

    With the Danish 'Thorsoe Biogas Plant' as reference case, an assessment of the possibility of using the existing natural gas distribution network for distributing biogas was carried out. Technologies for and cost of upgrading biogas to natural gas quality are presented. Furthermore, a socio-economic analysis has been performed, including the Danish financial conditions, the market models, and the role of the natural gas distribution companies.

  16. 沼气中CO2含量对沼气灶性能的影响及对策%Effects and countermeasures of CO2 content in biogas on performance of biogas stove

    Institute of Scientific and Technical Information of China (English)

    戴万能; 秦朝葵; 杨贤潮; 马飞

    2011-01-01

    采用天然气掺混CO2的方法模拟沼气,在CO2体积分数为30%~50%条件下,测试了典型家用沼气灶的热工性能,研究了应对沼气气质变化的措施.结果表明:随C02含量的降低,沼气灶热流量增大,热效率升高,烟气中CO浓度升高,NOx浓度无显著变化.热流量大于3.26 kW时,现行测试方法不能真实反映热效率与CO2含量的关系.沼气中CO2含量的变化会显著改变沼气灶的热工性能,可能增加用户的抱怨和安全风险.在CO2体积分数小于40%时,根据CO2含量调整供气压力,可使灶具热流量保持稳定,并显著改善CO排放,可能成为沼气组分含量变化的应对措施.%The thermal performance of a typical domestic biogas stove supplied with biogas of different CO2 volume fractions was investigated. Possible technical measures in response to variations in biogas composition were studied as well. Mixed gas of natural gas and CO2 were produced so as to simulate the biogas in which CO2 volume fraction varied from 50% to 30%. With the decrease of CO2 percentage in the mixture, it was found that heat output, heat efficiency and CO emission increased, while NOX emission did not change significantly. When heat output was greater than 3.26 kW, the current testing method could not reflect the relationship between thermal efficiency and CO2 ratio exactly. Variations in the CO2 content in biogas significantly affected the thermal performance of the biogas stove, which maight increase complaints and security risks. When the volume fraction of CO2 was less than 40%, regulating the biogas pressure according to the CO2 content so as to stabilize heat output could significantly improve the CO emission, which may be regarded as a measure to cope with variations of CO2 content in biogas.

  17. Enhancing biogas production from vinasse in sugarcane biorefineries: Effects of urea and trace elements supplementation on process performance and stability.

    Science.gov (United States)

    Janke, Leandro; Leite, Athaydes F; Batista, Karla; Silva, Witan; Nikolausz, Marcell; Nelles, Michael; Stinner, Walter

    2016-10-01

    In this study, the effects of nitrogen, phosphate and trace elements supplementation were investigated in a semi-continuously operated upflow anaerobic sludge blanket system to enhance process stability and biogas production from sugarcane vinasse. Phosphate in form of KH2PO4 induced volatile fatty acids accumulation possibly due to potassium inhibition of the methanogenesis. Although nitrogen in form of urea increased the reactor's alkalinity, the process was overloaded with an organic loading rate of 6.1gCODL(-1)d(-1) and a hydraulic retention time of 3.6days. However, by supplementing urea and trace elements a stable operation even at an organic loading rate of 9.6gCODL(-1)d(-1) and a hydraulic retention time of 2.5days was possible, resulting in 79% higher methane production rate with a stable specific methane production of 239mLgCOD(-1).

  18. Performance of a multipurpose research electrochemical reactor

    Energy Technology Data Exchange (ETDEWEB)

    Henquin, E.R. [Programa de Electroquimica Aplicada e Ingenieria Electroquimica (PRELINE), Facultad de Ingenieria Quimica, Universidad Nacional del Litoral, Santiago del Estero 2829, S3000AOM Santa Fe (Argentina); Bisang, J.M., E-mail: jbisang@fiq.unl.edu.ar [Programa de Electroquimica Aplicada e Ingenieria Electroquimica (PRELINE), Facultad de Ingenieria Quimica, Universidad Nacional del Litoral, Santiago del Estero 2829, S3000AOM Santa Fe (Argentina)

    2011-07-01

    Highlights: > For this reactor configuration the current distribution is uniform. > For this reactor configuration with bipolar connection the leakage current is small. > The mass-transfer conditions are closely uniform along the electrode. > The fluidodynamic behaviour can be represented by the dispersion model. > This reactor represents a suitable device for laboratory trials. - Abstract: This paper reports on a multipurpose research electrochemical reactor with an innovative design feature, which is based on a filter press arrangement with inclined segmented electrodes and under a modular assembly. Under bipolar connection, the fraction of leakage current is lower than 4%, depending on the bipolar Wagner number, and the current distribution is closely uniform. When a turbulence promoter is used, the local mass-transfer coefficient shows a variation of {+-}10% with respect to its mean value. The fluidodynamics of the reactor responds to the dispersion model with a Peclet number higher than 10. It is concluded that this reactor is convenient for laboratory research.

  19. High Performance Photocatalytic Oxidation Reactor System Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Pioneer Astronautics proposes a technology program for the development of an innovative photocatalytic oxidation reactor for the removal and mineralization of...

  20. Optimisation of biogas production from manure through serial digestion: lab-scale and pilot-scale studies.

    Science.gov (United States)

    Kaparaju, Prasad; Ellegaard, Lars; Angelidaki, Irini

    2009-01-01

    In the present study, the possibility of optimizing biogas production from manure by serial digestion was investigated. In the lab-scale experiments, process performance and biogas production of serial digestion, two methanogenic continuously stirred tank reactors (CSTR) connected in series, was compared to a conventional one-step CSTR process. The one-step process was operated at 55 degrees C with 15d HRT and 5l working volume (control). For serial digestion, the total working volume of 5l was distributed as 70/30%, 50/50%, 30/70% or 13/87% between the two methanogenic reactors, respectively. Results showed that serial digestion improved biogas production from manure compared to one-step process. Among the tested reactor configurations, best results were obtained when serial reactors were operated with 70/30% and 50/50% volume distribution. Serial digestion at 70/30% and 50/50% volume distribution produced 13-17.8% more biogas and methane and, contained low VFA and residual methane potential loss in the effluent compared to the one-step CSTR process. At 30/70% volume distribution, an increase in biogas production was also noticed but the process was very unstable with low methane production. At 13/87% volume distribution, no difference in biogas production was noticed and methane production was much lower than the one-step CSTR process. Pilot-scale experiments also showed that serial digestion with 77/23% volume distribution could improve biogas yields by 1.9-6.1% compared to one-step process. The study thus suggests that the biogas production from manure can be optimized through serial digestion with an optimal volume distribution of 70/30% or 50/50% as the operational fluctuations are typically high during full scale application. However, process temperature between the two methanogenic reactors should be as close as possible in order to derive the benefits of serial coupling.

  1. Responses of the biogas process to pulses of oleate in reactors treating mixtures of cattle and pig manure

    DEFF Research Database (Denmark)

    Nielsen, Henrik Bjørn; Ahring, Birgitte Kiær

    2006-01-01

    The effect of oleate on the anaerobic digestion process was investigated. Two thermophilic continuously stirred tank reactors (CSTR) were fed with mixtures of cattle and pig manure with different total solid (TS) and volatile solid (VS) content. The reactors were subjected to increasing pulses...

  2. Sicilian potential biogas production

    Directory of Open Access Journals (Sweden)

    Antonio Comparetti

    2013-09-01

    Full Text Available This study is aimed at predicting the Sicilian potential biogas production, using the Organic Fraction of Municipal Solid Waste (OFMSW, animal manure and food industry by-products, in a region where only one biogas plant using MSW and one co-digestion plant are nowadays available. The statistical data about OFMSW, the number of animals bred in medium and large farms and the amounts of by-products of food processing industries were evaluated, in order to compute the Sicilian potential biogas and energy production. The OFMSW produced in Sicily, that is 0.8 million tons ca. per year (37% of MSW, could be used in a bio-reactor, together with other raw materials, for Anaerobic Digestion (AD process, producing biogas and “digestate”. Moreover, 3.03 million tons ca. of manure, collected in medium and large animal husbandry farms (where cows, pigs and poultry are bred, and 350 thousand tons ca. of by-products, collected in food processing industries (pomace from olive oil mills and grape marc from wineries, might be used for AD process. The Sicilian potential biogas production from the AD of the above raw materials is 170.2 millions of m3, that is equal to 1023.4 GWh of energy per year, of which 484 GWh from animal manure, 303 GWh from OFMSW and 236.4 GWh from food industry by-products. The highest biogas production is in the province of Palermo (35.6 millions of m3, Ragusa (30.8 millions of m3 and Catania (22.8 millions of m3, having a potential energy production of 213.8, 185 and 137 GWh, respectively.

  3. Local biogas producer; Bodenstaendiges Biogas

    Energy Technology Data Exchange (ETDEWEB)

    Wiedemann, Karsten

    2010-02-15

    MT-Energie is a manufacturer of industrial process plants seated in the German state of Niedersachsen. After a period of steep growth, the company is now entering the biogas business and intends to supply biogas into the public gas grid. (orig.)

  4. Harvesting biogas from wastewater sludge and food waste

    Science.gov (United States)

    Chua, K. H.; Cheah, W. L.; Tan, C. F.; Leong, Y. P.

    2013-06-01

    Wastewater sludge and food waste are good source of biogas. Anaerobic treatment of slude and food waste able to produce biogas which is a potential renewable energy source. This study looks into the potential biogas generation and the effects of temperature on biogas generation. A lab scale reactor was used to simulate the biogas generation. The results show that wastewater sludge able to produced upto 44.82 ml biogas/kg of sludge. When mixed with food waste at a ratio of 30:70 (food waste), the biogas generated were 219.07 ml/kg of waste. Anaerobic of food waste alone produced biogas amount to 59.75 ml/kg of food waste. Anaerobic treatment also reduces the volume of waste. The effect of temperature shows that higher temperature produces more biogas than lower temperature.

  5. Oxidation performance of graphite material in reactors

    Institute of Scientific and Technical Information of China (English)

    Xiaowei LUO; Xinli YU; Suyuan YU

    2008-01-01

    Graphite is used as a structural material and moderator for high temperature gas-cooled reactors (HTGR). When a reactor is in operation, graphite oxida-tion influences the safety and operation of the reactor because of the impurities in the coolant and/or the acci-dent conditions, such as water ingress and air ingress. In this paper, the graphite oxidation process is introduced, factors influencing graphite oxidation are analyzed and discussed, and some new directions for further study are pointed out.

  6. Quantification of syntrophic fatty acid-beta-oxidizing bacteria in a mesophilic biogas reactor by oligonucleotide probe hybridization

    DEFF Research Database (Denmark)

    Hansen, K.W.; Ahring, Birgitte Kiær; Raskin, L.

    1999-01-01

    Small-subunit rRNA sequences were obtained for two saturated fatty acid-beta-oxidizing syntrophic bacteria, Syntrophomonas sapovorans and Syntrophomonas wolfei LYE, and sequence analysis confirmed their classification as members of the family Syntrophomonadaceae. S, wolfei LYE was closely related...... to S. wolfei subsp. wolfei, but S. sapovorans did not cluster with the other members of the genus Syntrophomonas, Five oligonucleotide probes targeting the small-subunit rRNA of different groups within the family Syntrophomonadaceae, which contains all currently known saturated fatty acid...... fatty acid-beta-oxidizing syntrophic bacteria in methanogenic environments, the microbial community structure of a sample from a full-scale biogas plant was determined. Hybridization results with probes for syntrophic bacteria-and methanogens were compared to specific methanogenic activities...

  7. Dispersion and treatment performance analysis of an UASB reactor under different hydraulic loading rates.

    Science.gov (United States)

    Peña, M R; Mara, D D; Avella, G P

    2006-02-01

    Mixing and transport phenomena affect the efficiency of all bioreactor configurations. An even mixing pattern at the macro-level is desirable to provide good conditions for substrate transport to, and from, the microbial aggregates. The state of segregation of particulate material in the reactor is also important. The production of biogas in anaerobic reactors is another factor that affects mixing intensity and hence the interactions between the liquid, solid and gaseous phases. The CSTR model with some degree of short-circuiting, dead zones and bypassing flows seems to describe the overall hydrodynamics of UASBs. However, few data are available in the literature for full-scale reactors that relate process performance to mixing characteristics. Dispersion studies using LiCl were done for four hydraulic loading rates on a full-scale UASB treating domestic wastewater in Ginebra, Valle del Cauca, southwest Colombia. COD, TSS, and Settleable Solids were used to evaluate the performance of organic matter removal. The UASB showed a complete mixing pattern for hydraulic loading rates close to the design value (i.e. Q = 10-13l s(-1) and HRT=8-6 h). Gross mixing distortions and localised stagnant zones, short-circuiting and bypass flows were found in the sludge bed and blanket zones for both extreme conditions (underloading and overloading). The liquid volume contained below the gas-liquid-solid separator was found to contribute to the overall stagnant volume, particularly when the reactor was underloaded. The removal of organic matter showed a log-linear correlation with the dispersion number.

  8. Performance of pressure tubes in CANDU reactors

    Energy Technology Data Exchange (ETDEWEB)

    Rodgers, D.; Griffiths, M.; Bickel, G.; Buyers, A.; Coleman, C.; Nordin, H.; St Lawrence, S. [Canadian Nuclear Laboratories, Chalk River, Ontario (Canada)

    2016-06-15

    The pressure tubes in CANDU reactors typically operate for times up to about 30 years prior to refurbishment. The in-reactor performance of Zr-2.5Nb pressure tubes has been evaluated by sampling and periodic inspection. This paper describes the behavior and discusses the factors controlling the behaviour of these components. The Zr–2.5Nb pressure tubes are nominally extruded at 815{sup o}C, cold worked nominally 27%, and stress relieved at 400 {sup o}C for 24 hours, resulting in a structure consisting of elongated grains of hexagonal close-packed alpha-Zr, partially surrounded by a thin network of filaments of body-centred-cubic beta-Zr. These beta-Zr filaments are meta-stable and contain about 20% Nb after extrusion. The stress-relief treatment results in partial decomposition of the beta-Zr filaments with the formation of hexagonal close-packed alpha-phase particles that are low in Nb, surrounded by a Nb-enriched beta-Zr matrix. The material properties of pressure tubes are determined by variations in alpha-phase texture, alpha-phase grain structure, network dislocation density, beta-phase decomposition, and impurity concentration that are a function of manufacturing variables. The pressure tubes operate at temperatures between 250 {sup o}C and 310 {sup o}C with coolant pressures up to about 11 MPa in fast neutron fluxes up to 4 x 10{sup 17} n·m{sup -2}·s{sup -1} (E > 1 MeV) and the properties are modified by these conditions. The properties of the pressure tubes in an operating reactor are therefore a function of both manufacturing and operating condition variables. The ultimate tensile strength, fracture toughness, and delayed hydride-cracking properties (velocity (V) and threshold stress intensity factor (K{sub IH})) change with irradiation, but all reach a nearly limiting value at a fluence of less than 10{sup 25} n·m{sup -2} (E > 1 MeV). At this point the ultimate tensile strength is raised about 200 MPa, toughness is reduced by about 50%, V increases

  9. Process control in biogas plants

    DEFF Research Database (Denmark)

    Holm-Nielsen, Jens Bo; Oleskowicz-Popiel, Piotr

    2013-01-01

    Efficient monitoring and control of anaerobic digestion (AD) processes are necessary in order to enhance biogas plant performance. The aim of monitoring and controlling the biological processes is to stabilise and optimise the production of biogas. The principles of process analytical technology...

  10. Sustainable operation of submerged Anammox membrane bioreactor with recycling biogas sparging for alleviating membrane fouling.

    Science.gov (United States)

    Li, Ziyin; Xu, Xindi; Xu, Xiaochen; Yang, FengLin; Zhang, ShuShen

    2015-12-01

    A submerged anaerobic ammonium oxidizing (Anammox) membrane bioreactor with recycling biogas sparging for alleviating membrane fouling has been successfully operated for 100d. Based on the batch tests, a recycling biogas sparging rate at 0.2m(3)h(-1) was fixed as an ultimate value for the sustainable operation. The mixed liquor volatile suspended solid (VSS) of the inoculum for the long operation was around 3000mgL(-1). With recycling biogas sparging rate increasing stepwise from 0 to 0.2m(3)h(-1), the reactor reached an influent total nitrogen (TN) up to 1.7gL(-1), a stable TN removal efficiency of 83% and a maximum specific Anammox activity (SAA) of 0.56kg TNkg(-1) VSSd(-1). With recycling biogas sparging rate at 0.2 m(3) h(-1) (corresponding to an aeration intensity of 118m(3)m(-2)h(-1)), the membrane operation circle could prolong by around 20 times compared to that without gas sparging. Furthermore, mechanism of membrane fouling was proposed. And with recycling biogas sparging, the VSS and EPS content increasing rate in cake layer were far less than the ones without biogas sparging. The TN removal performance and sustainable membrane operation of this system showed the appealing potential of the submerged Anammox MBR with recycling biogas sparging in treating high-strength nitrogen-containing wastewaters.

  11. Glidarc assisted production of synthesis gas from biogas

    Energy Technology Data Exchange (ETDEWEB)

    Czernichowski, A. [Orleans Univ., Department of Physics, 45 - Orleans (France); Czernichowski, M.; Wesolowska, K. [Etudes Chimiques et Physiques (ECP), 45 - La Ferte Saint Aubin (France)

    2003-09-01

    We present an emerging biogas reformer based on a direct use of high-voltage discharges (called GlidArc) that strike in the flow of such widely available and renewable feedstock without any gas separation or purification. A poor biogas (containing only 35-50 vol.% of methane) is partially converted into hydrogen and carbon monoxide (SynGas). Such upgraded biogas can, for example, be used as fuel in Internal Combustion Engines, be considered as source of Hydrogen for PEM fuel cells or be consumed in other specific fuel cells. Any level of impurities is accepted for our reformer where the discharges provide all necessary energy and catalytic assistance for endothermic process of so-called 'dry' reforming of CH{sub 4}+CO{sub 2} into H{sub 2}+CO. Our tests with biogas are performed in a 1.4-L reactor working at atmospheric pressure at up to 0.6 kW electric power. Such input is fully sufficient to process a flow of a poor biogas presenting up to 7 kW of thermal power. (authors)

  12. Fuel Cycle Performance of Thermal Spectrum Small Modular Reactors

    Energy Technology Data Exchange (ETDEWEB)

    Worrall, Andrew [ORNL; Todosow, Michael [Brookhaven National Laboratory (BNL)

    2016-01-01

    Small modular reactors may offer potential benefits, such as enhanced operational flexibility. However, it is vital to understand the holistic impact of small modular reactors on the nuclear fuel cycle and fuel cycle performance. The focus of this paper is on the fuel cycle impacts of light water small modular reactors in a once-through fuel cycle with low-enriched uranium fuel. A key objective of this paper is to describe preliminary reactor core physics and fuel cycle analyses conducted in support of the U.S. Department of Energy Office of Nuclear Energy Fuel Cycle Options Campaign. Challenges with small modular reactors include: increased neutron leakage, fewer assemblies in the core (and therefore fewer degrees of freedom in the core design), complex enrichment and burnable absorber loadings, full power operation with inserted control rods, the potential for frequent load-following operation, and shortened core height. Each of these will impact the achievable discharge burn-up in the reactor and the fuel cycle performance. This paper summarizes the results of an expert elicitation focused on developing a list of the factors relevant to small modular reactor fuel, core, and operation that will impact fuel cycle performance. Preliminary scoping analyses were performed using a regulatory-grade reactor core simulator. The hypothetical light water small modular reactor considered in these preliminary scoping studies is a cartridge type one-batch core with 4.9% enrichment. Some core parameters, such as the size of the reactor and general assembly layout, are similar to an example small modular reactor concept from industry. The high-level issues identified and preliminary scoping calculations in this paper are intended to inform on potential fuel cycle impacts of one-batch thermal spectrum SMRs. In particular, this paper highlights the impact of increased neutron leakage and reduced number of batches on the achievable burn-up of the reactor. Fuel cycle performance

  13. Biogas recirculation for simultaneous calcium removal and biogas purification within an expanded granular sludge bed system treating leachate.

    Science.gov (United States)

    Luo, Jinghuan; Lu, Xueqin; Liu, Jianyong; Qian, Guangren; Lu, Yongsheng

    2014-12-01

    Biogas, generated from an expanded granular sludge bed (EGSB) reactor treating municipal solid waste (MSW) leachate, was recirculated for calcium removal from the leachate via a carbonation process with simultaneous biogas purification. Batch trials were performed to optimize the solution pH and imported biogas (CO2) for CaCO3 precipitation. With applicable pH of 10-11 obtained, continuous trials achieved final calcium concentrations of 181-375 mg/L (removal efficiencies≈92.8-96.5%) in the leachate and methane contents of 87.1-91.4% (purification efficiencies≈65.4-82.2%) in the biogas. Calcium-balance study indicates that 23-986 mg Ca/d was released from the bio-system under the carbonized condition where CaCO3 precipitating was moved outside the bioreactor, whereas 7918-9517 mg Ca/d was trapped into the system for the controlled one. These findings demonstrate that carbonation removal of calcium by biogas recirculation could be a promising alternative to pretreat calcium-rich MSW leachate and synergistically to improve methane content.

  14. Reactors

    CERN Document Server

    International Electrotechnical Commission. Geneva

    1988-01-01

    This standard applies to the following types of reactors: shunt reactors, current-limiting reactors including neutral-earthing reactors, damping reactors, tuning (filter) reactors, earthing transformers (neutral couplers), arc-suppression reactors, smoothing reactors, with the exception of the following reactors: small reactors with a rating generally less than 2 kvar single-phase and 10 kvar three-phase, reactors for special purposes such as high-frequency line traps or reactors mounted on rolling stock.

  15. Optimizing the performance of a reactor by reducing the retention time and addition of glycerin for anaerobically digesting manure.

    Science.gov (United States)

    Timmerman, Maikel; Schuman, Els; van Eekert, Miriam; van Riel, Johan

    2015-01-01

    Anaerobic digestion of manure is a widely accepted technology for energy production. However, only a minimal portion of the manure production in the EU is anaerobically digested and occurs predominantly in codigestion plants. There is substantial potential for biogas plants that primarily operate on manure (>90%); however, the methane yields of manure are less compared to coproducts, which is one of the reasons for manure-based biogas plants often being economically non-viable. Therefore, it is essential to begin increasing the efficiency of these biogas plants. This study investigated the effect of decreasing retention time and introducing a moderate amount of glycerin on the biogas production as methods to improve efficiency. An experiment has been conducted with two different manure types in four biogas reactors. The results of the study demonstrated that, first, it was possible to decrease the retention time to 10-15 days; however, the effect on biogas production varied per manure type. Secondly, the biogas production almost triples at a retention time of 15.6 days with an addition of 4% glycerin. The relative production-enhancing effect of glycerin did not vary significantly with both manure types. However, the absolute production-enhancing effect of glycerin differed per manure type since the biogas production per gram VS differed per manure type. Thirdly, the positive effect of the glycerin input declines with shorter retention times. Therefore, the effect of glycerin addition depends on the manure type and retention time.

  16. Cooling Performance of Natural Circulation for a Research Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Park, Suki; Chun, J. H.; Yum, S. B. [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2015-10-15

    This paper deals with the core cooling performance by natural circulation during normal operation and a flow channel blockage event in an open tank-in-pool type research reactor. The cooling performance is predicted by using the RELAP5/ MOD3.3 code. The core decay heat is usually removed by natural circulation to the reactor pool water in open tank-in-pool type research reactors with the thermal power less than several megawatts. Therefore, these reactors have generally no active core cooling system against a loss of normal forced flow. In reactors with the thermal power less than around one megawatt, the reactor core can be cooled down by natural circulation even during normal full power operation. The cooling performance of natural circulation in an open tank-in-pool type research reactor has been investigated during the normal natural circulation and a flow channel blockage event. It is found that the maximum powers without void generation at the hot channel are around 1.16 MW and 820 kW, respectively, for the normal natural circulation and the flow channel blockage event.

  17. Effects of octahedral molecular sieve on treatment performance, microbial metabolism, and microbial community in expanded granular sludge bed reactor.

    Science.gov (United States)

    Pan, Fei; Xu, Aihua; Xia, Dongsheng; Yu, Yang; Chen, Guo; Meyer, Melissa; Zhao, Dongye; Huang, Ching-Hua; Wu, Qihang; Fu, Jie

    2015-12-15

    This study evaluated the effects of synthesized octahedral molecular sieve (OMS-2) nanoparticles on the anaerobic microbial community in a model digester, expanded granular sludge bed (EGSB) reactor. The addition of OMS-2 (0.025 g/L) in the EGSB reactors resulted in an enhanced operational performance, i.e., COD removal and biogas production increased by 4% and 11% respectively, and effluent volatile fatty acid (VFA) decreased by 11% relative to the control group. The Biolog EcoPlate™ test was employed to investigate microbial metabolism in the EGSB reactors. Results showed that OMS-2 not only increased the microbial metabolic level but also significantly changed the community level physiological profiling of the microorganisms. The Illumina MiSeq high-throughput sequencing of 16S rRNA gene indicated OMS-2 enhanced the microbial diversity and altered the community structure. The largest bacterial genus Lactococcus, a lactic acid bacterium, reduced from 29.3% to 20.4% by abundance in the presence of 0.25 g/L OMS-2, which may be conducive to decreasing the VFA production and increasing the microbial diversity. OMS-2 also increased the quantities of acetogenic bacteria and Archaea, and promoted the acetogenesis and methanogenesis. The X-ray photoelectron spectroscopy illustrated that Mn(IV)/Mn(III) with high redox potential in OMS-2 were reduced to Mn(II) in the EGSB reactors; this in turn affected the microbial community.

  18. Influence of alkalinity and VFAs on the performance of an UASB reactor with recirculation for the treatment of Tequila vinasses.

    Science.gov (United States)

    López-López, Alberto; León-Becerril, Elizabeth; Rosales-Contreras, María Elena; Villegas-García, Edgardo

    2015-01-01

    The main problem linked to the stability of upflow anaerobic sludge blanket (UASB) reactors during the treatment of Tequila vinasse is the high acidity and the null alkalinity present in this effluent. This research evaluates the effect of alkalinity and volatile fatty acids (VFAs) concentration on the performance of an UASB reactor with recirculation of the effluent for removing organic matter and biogas production from Tequila vinasses. Recirculation of the effluent reduces the impact of VFAs and organic matter concentration present in the influent, inducing the stability of the reactor. The UASB reactor was operated during 235 days at organic loading rates from 2.5 to 20.0 kg m(-3) d(-1), attaining a removal efficiency of COD greater than 75% with a methane yield of 335 ml CH4 g(-1) COD at SPT, maintaining a ratio of VFAs/Alk ≤ 0.5. Therefore, an optimal ratio of VFAs/Alk was established for the system operating in stable conditions for the treatment of Tequila vinasses. Under these conditions, the alkalinity was recuperated by the system itself, without the addition of external alkalinity.

  19. Comparative life cycle assessment of biogas plant configurations for a demand oriented biogas supply for flexible power generation.

    Science.gov (United States)

    Hahn, Henning; Hartmann, Kilian; Bühle, Lutz; Wachendorf, Michael

    2015-03-01

    The environmental performance of biogas plant configurations for a demand - oriented biogas supply for flexible power generation is comparatively assessed in this study. Those configurations indicate an increased energy demand to operate the operational enhancements compared to conventional biogas plants supplying biogas for baseload power generation. However, findings show that in contrast to an alternative supply of power generators with natural gas, biogas supplied on demand by adapted biogas plant configurations saves greenhouse gas emissions by 54-65 g CO(2-eq) MJ(-1) and primary energy by about 1.17 MJ MJ(-1). In this regard, configurations with flexible biogas production profit from reduced biogas storage requirements and achieve higher savings compared to configurations with continuous biogas production. Using thicker biogas storage sheeting material reduces the methane permeability of up to 6m(3) d(-1) which equals a reduction of 8% of the configuration's total methane emissions.

  20. Synthesis, performance and regeneration of carbon membranes for biogas upgrading - a future energy carrier

    Energy Technology Data Exchange (ETDEWEB)

    Lie, Jon Arvid

    2005-07-01

    The focus of the current work was to find a low-cost precursor for carbon molecular sieve (CMS) membranes for biogas upgrading (i.e. CO{sub 2}/CH{sub 4} separation to meet vehicle fuel criteria), and a simple way of producing them. Wood pulp from spruce and pine containing a majority of cellulose resulted in carbons with CO{sub 2}/CH{sub 4} separation performance at the same level as those derived from specialty polymers like polyimides. Pulp has the advantage of being widespread and cheap. Cellulose hydrolysis with trifluoroacetic acid (TFA), that is gentle enough to preserve the monosaccharides, provided an anticipative route to carbon membrane formation. Increasing the hydrolysis time, resulted in reduced weight loss during carbonization, and better separation performance for the gas pair CO{sub 2}/CH{sub 4}. The results indicated that furans are a key intermediate in forming microporosity with high separation performance. For the separation of CO2 from CH{sub 4} the optimum carbon formation temperature seemed to be near 650{sup d}eg C (single gas tests at 30{sup d}eg C and 2 bar feed pressure). In addition, several ways of modifying a carbon material are described. The modification method used in this study was metal doping of carbon. CMS membranes were formed by vacuum carbonization of hydrolyzed cellulose and metal loaded hydrolyzed cellulose. Metal additives include oxides of Ca, Mg, Fe(III) and Si, and nitrates of Ag, Cu and Fe(III). The carbon membrane containing Fe-nitrate has promising separation performance for the gas pairs 02/N2 and CO{sub 2}/CH{sub 4}. The CO{sub 2}/CH{sub 4} selectivity was typically larger than 100, with a CO2 permeability of about 300 Barrer (single gas tests). Carbon containing nitrates of Cu or Ag showed high selectivity, but reduced 02 and CO2 permeability compared to carbon with Fe-nitrate. Element analysis indicated that Cu migrates to the carbon surface, creating an extra layer resistance to gas transport. A silver mirror

  1. Synthesis, performance and regeneration of carbon membranes for biogas upgrading - a future energy carrier

    Energy Technology Data Exchange (ETDEWEB)

    Lie, Jon Arvid

    2005-07-01

    The focus of the current work was to find a low-cost precursor for carbon molecular sieve (CMS) membranes for biogas upgrading (i.e. CO{sub 2}/CH{sub 4} separation to meet vehicle fuel criteria), and a simple way of producing them. Wood pulp from spruce and pine containing a majority of cellulose resulted in carbons with CO{sub 2}/CH{sub 4} separation performance at the same level as those derived from specialty polymers like polyimides. Pulp has the advantage of being widespread and cheap. Cellulose hydrolysis with trifluoroacetic acid (TFA), that is gentle enough to preserve the monosaccharides, provided an anticipative route to carbon membrane formation. Increasing the hydrolysis time, resulted in reduced weight loss during carbonization, and better separation performance for the gas pair CO{sub 2}/CH{sub 4}. The results indicated that furans are a key intermediate in forming microporosity with high separation performance. For the separation of CO2 from CH{sub 4} the optimum carbon formation temperature seemed to be near 650{sup d}eg C (single gas tests at 30{sup d}eg C and 2 bar feed pressure). In addition, several ways of modifying a carbon material are described. The modification method used in this study was metal doping of carbon. CMS membranes were formed by vacuum carbonization of hydrolyzed cellulose and metal loaded hydrolyzed cellulose. Metal additives include oxides of Ca, Mg, Fe(III) and Si, and nitrates of Ag, Cu and Fe(III). The carbon membrane containing Fe-nitrate has promising separation performance for the gas pairs 02/N2 and CO{sub 2}/CH{sub 4}. The CO{sub 2}/CH{sub 4} selectivity was typically larger than 100, with a CO2 permeability of about 300 Barrer (single gas tests). Carbon containing nitrates of Cu or Ag showed high selectivity, but reduced 02 and CO2 permeability compared to carbon with Fe-nitrate. Element analysis indicated that Cu migrates to the carbon surface, creating an extra layer resistance to gas transport. A silver mirror

  2. Enhancing biogas production from recalcitrant lignocellulosic residue

    DEFF Research Database (Denmark)

    Tsapekos, Panagiotis

    and lignocellulosic silage was assessed in continuous stirred tank reactors (CSTR). Addition of mechanically pretreated silage in the feedstock positively affected the methane yield (+16%) and in parallel, reduced the risk of ammonia inhibition compared to mono-digestion of pig manure. Furthermore, metagenomic...... analysis was performed to determine differences among the microbial communities in CSTRs operating under mono- and co-digestion. Species similar to Clostridium thermocellum, with increased cellulolytic activity, were detected to be adherent to the solid fraction of digested feedstock and concluded...... be periodically applied in biogas reactors in order to extract the residual methane from the amassing materials and avoid potential accumulation. Additionally, the facultative anaerobic Melioribacter roseus was inoculated in a replicate CSTR following different bioaugmentation strategies, either strictly...

  3. Thermodynamic Performance Analysis of a Biogas-Fuelled Micro-Gas Turbine with a Bottoming Organic Rankine Cycle for Sewage Sludge and Food Waste Treatment Plants

    Directory of Open Access Journals (Sweden)

    Sunhee Kim

    2017-02-01

    Full Text Available In the Republic of Korea, efficient biogas-fuelled power systems are needed to use the excess biogas that is currently burned due to a lack of suitable power technology. We examined the performance of a biogas-fuelled micro-gas turbine (MGT system and a bottoming organic Rankine cycle (ORC. The MGT provides robust operation with low-grade biogas, and the exhaust can be used for heating the biodigester. Similarly, the bottoming ORC generates additional power output with the exhaust gas. We selected a 1000-kW MGT for four co-digestion plants with 28,000-m3 capacity. A 150-kW ORC system was selected for the MGT exhaust gas. We analysed the effects of the system size, methane concentration, and ORC operating conditions. Based on the system performance, we analysed the annual performance of the MGT with a combined heat and power (CHP system, bottoming ORC, or both a bottoming ORC and CHP system. The annual net power outputs for each system were 7.4, 8.5, and 9.0 MWh per year, respectively.

  4. Biomass storage for further energy use through biogas production

    Energy Technology Data Exchange (ETDEWEB)

    Atem, A.D. [Instituto CEDIAC, Facultad de Ingenieria, Universidad Nacional de Cuyo, Centro Universitario, 5500 Mendoza (Argentina); Instituto de Medio Ambiente, Facultad de Ingenieria, Universidad Nacional de Cuyo, Centro Universitario, 5500 Mendoza (Argentina); Instituto de Energia, Universidad Nacional de Cuyo, Centro Universitario, 5500 Mendoza (Argentina); Consejo Nacional de Investigaciones Cientificas y Tecnicas - CONICET, Mendoza (Argentina); Indiveri, M.E. [Instituto de Medio Ambiente, Facultad de Ingenieria, Universidad Nacional de Cuyo, Centro Universitario, 5500 Mendoza (Argentina); Instituto de Energia, Universidad Nacional de Cuyo, Centro Universitario, 5500 Mendoza (Argentina); Llamas, S. [Instituto de Medio Ambiente, Facultad de Ingenieria, Universidad Nacional de Cuyo, Centro Universitario, 5500 Mendoza (Argentina)

    2010-06-15

    The present work approaches the residual biomass conservation for later digestion in an anaerobic batch reactor. Twenty 4 L capacity PET reactors were used. A measuring device was constructed to quantify the biogas production. As substrate were used tomato wastes from local industry and rumen fluid as inoculum. Digestion start up was able to be controlled by varying the temperature, during a period of 118 days was not verified biogas production. After re-inoculated with rumen fluid stabilized for 34 days, biogas production was verified. They were obtained 0.10 m{sup 3} of biogas per kilogram of volatile solids, with 50% of methane content. (author)

  5. EU Agro Biogas Project

    NARCIS (Netherlands)

    Amon, T.; Mayr, H.; Eder, M.; Hobbs, P.; Rao Ravella, S.; Roth, U.; Niebaum, A.; Doehler, H.; Weiland, P.; Abdoun, E.; Moser, A.; Lyson, M.; Heiermann, M.; Plöchl, M.; Budde, J.; Schattauer, A.; Suarez, T.; Möller, H.; Ward, A.; Hillen, F.; Sulima, P.; Oniszk-Polplawska, A.; Krampe, P.; Pastorek, Z.; Kara, J.; Mazancova, J.; Dooren, van H.J.C.; Wim, C.; Gioelli, F.; Balsari, P.

    2009-01-01

    EU-AGRO-BIOGAS is a European Biogas initiative to improve the yield of agricultural biogas plants in Europe, to optimise biogas technology and processes and to improve the efficiency in all parts of the production chain from feedstock to biogas utilisation. Leading European research institutions and

  6. Thermal Simulation of Biogas Plants Using Mat Lab

    Directory of Open Access Journals (Sweden)

    Shaheen.M.Sain

    2014-10-01

    Full Text Available The major prerequisite for the optimum production of methane from a biogas plant is the sustenance of digester temperature within the narrow limits (300C-350C. It is experimentally investigated that, the MIT biogas plant is not maintaining optimum temperature, this decreases the efficiency and increases the detention time for charge. To maintain the plant in optimum temperature, it is necessary to find out the heat losses from the biogas plant and the external energy inputs need to operate the plant. Rate of gas yield, and the detention time (time necessary to anaerobically digest organic wastes in a biogas reactor, are favorable functions of the temperature in the digester. A thermal simulation for MIT biogas plant has developed using matlab in order to understand the heat transfer from the slurry and the gas holder to the surrounding earth and air respectively. The computation has been performed when the slurry is maintained at 200C and 300C, optimum temperature of anaerobic fermentation. If the slurry is considered to be at 350C, the optimum temperature of anaerobic fermentation, the total heat loss from the plant is higher than the heat loss when the slurry is maintained at 200C. The heat calculations provide an appraisal for the heat which has to be supplied by external means to compensate for the net heat losses which occur if the slurry is to be maintained at 350C. A solar system with auxiliary electric heater is designed for maintaining the slurry at 350C.In conclusion; the results of thermal analysis are used to define a strategy for operating biogas plant at optimum temperatures. .

  7. Whole genome sequence of Clostridium bornimense strain M2/40 isolated from a lab-scale mesophilic two-phase biogas reactor digesting maize silage and wheat straw.

    Science.gov (United States)

    Hahnke, Sarah; Wibberg, Daniel; Tomazetto, Geizecler; Pühler, Alfred; Klocke, Michael; Schlüter, Andreas

    2014-08-20

    The bacterium Clostridium bornimense M2/40 is a mesophilic, anaerobic bacterium isolated from a two-phase biogas reactor continuously fed with maize silage and 5% wheat straw. Grown on glucose, it produced H2, CO2, formiate, lactate and propionate as the main fermentation products, of which some compounds serve as substrates for methanogenic Archaea to form methane. Here, the whole genome sequence of the bacterium consisting of two circular replicons is reported. This genome information provides the basis for further studies addressing metabolic features of the isolate and its role in anaerobic biomass degradation.

  8. Numerical investigation: Performances of a standard biogas in a 100 kWe MGT

    Directory of Open Access Journals (Sweden)

    Vincenza Liguori

    2016-11-01

    For reasons related to the design economies, the preliminary numerical investigations such as that of the work in question on a model of combustor of a 100 kWe MGT are essential. To limit nitrogen oxides production, established lean premixed conditions. It is studied the behavior of a standard biogas M65 starting from the mouth of flame, through the laminar model up to the whole combustor but through the model k-ε, at different adducted flows. It is liked also to submit a hint related to the variation of thermal profiles or of concentrations in the combustor when the supplied natural gases have different composition, as well as at different flows and when adopted simplified kinetic paths of model to understand a sort of acceptable degree of simplification, for studies of first approximation.

  9. BIOGAS TECHNOLOGY

    Directory of Open Access Journals (Sweden)

    D.B. SALUNKHE

    2012-12-01

    Full Text Available Due to scarcity of petroleum and coal it threatens supply of fuel throughout the world also problem of their combustion leads to research in different corners to get access the new sources of energy, like renewable energy resources. Solar energy, wind energy, different thermal and hydro sources of energy, biogas are all renewable energy resources. But, biogas is distinct from other renewable energies because of its characteristics of using, controlling and collecting organic wastes and at the same time producing fertilizer and water for use in agricultural irrigation. Biogas does not have any geographical limitations nor does it require advanced technology for producing energy, also it is very simple to use and apply. Anaerobic digestion is controlled biological degradation process which allows efficient capturing & utilization of biogas (approximately 60% methane and 40% carbon dioxide for energy generation. Anaerobic digestion of food waste is achievable but different types, composition of food waste results in varying degrees of methane yields, and thus the effects of mixing various types of food waste and their proportions should be determined on case by case basis.

  10. A Computer Simulation of the Effect of the Inert Gas Volume Fraction in Low-Caloric Biogas on the Performance of an Engine

    Directory of Open Access Journals (Sweden)

    Choong Hoon Lee

    2015-10-01

    Full Text Available A computer simulation of a gas engine was performed to investigate the effects of the inert gas volume fraction in biogas on engine performance, specifically the engine torque and the brakespecific fuel consumption (BSFC using GT-Power®. The engine speeds used in the simulation were 900 and 1800 rpm, while the simulated engine loads were 25, 50, 75 and 100%. The volume fraction of the inert gas N2 in the biogas was varied from 20 to 80% with an interval of 10%. In a simulation of a naturally aspirated gas engine which is operated with an 80% volume fraction of N2 in biogas, the optimal air-fuel ratio in terms of the fuel economy and brake power generation was 3.5. In a simulation of a turbo intercooler gas engine operated with an 80% volume fraction of N2 in biogas, the optimal air-fuel ratios with regard to the fuel economy and brake power generation were 5.0 and 3.5, respectively.

  11. Biogas production in an anaerobic sequencing batch reactor by using tequila vinasses: effect of pH and temperature.

    Science.gov (United States)

    Arreola-Vargas, J; Jaramillo-Gante, N E; Celis, L B; Corona-González, R I; González-Álvarez, V; Méndez-Acosta, H O

    2016-01-01

    In recent years, anaerobic digestion has been recognized as a suitable alternative for tequila vinasses treatment due to its high energy recovery and chemical oxygen demand (COD) removal efficiency. However, key factors such as the lack of suitable monitoring schemes and the presence of load disturbances, which may induce unstable operating conditions in continuous systems, have limited its application at full scale. Therefore, the aim of this work was to evaluate the anaerobic sequencing batch reactor (AnSBR) configuration in order to provide a low cost and easy operation alternative for the treatment of these complex effluents. In particular, the AnSBR was evaluated under different pH-temperature combinations: 7 and 32 °C; 7 and 38 °C; 8 and 32 °C and 8 and 38 °C. Results showed that the AnSBR configuration was able to achieve high COD removal efficiencies (around 85%) for all the tested conditions, while the highest methane yield was obtained at pH 7 and 38 °C (0.29 L/g COD added). Furthermore, high robustness was found in all the AnSBR experiments. Therefore, the full-scale application of the AnSBR technology for the treatment of tequila vinasses is quite encouraging, in particular for small and medium size tequila industries that operate under seasonal conditions.

  12. Insights into the annotated genome sequence of Methanoculleus bourgensis MS2(T), related to dominant methanogens in biogas-producing plants.

    Science.gov (United States)

    Maus, Irena; Wibberg, Daniel; Stantscheff, Robbin; Stolze, Yvonne; Blom, Jochen; Eikmeyer, Felix-Gregor; Fracowiak, Jochen; König, Helmut; Pühler, Alfred; Schlüter, Andreas

    2015-05-10

    The final step of the biogas production process, the methanogenesis, is frequently dominated by members of the genus Methanoculleus. In particular, the species Methanoculleus bourgensis was identified to play a role in different biogas reactor systems. The genome of the type strain M. bourgensis MS2(T), originally isolated from a sewage sludge digestor, was completely sequenced to analyze putative adaptive genome features conferring competitiveness within biogas reactor environments to the strain. Sequencing and assembly of the M. bourgensis MS2(T) genome yielded a chromosome with a size of 2,789,773 bp. Comparative analysis of M. bourgensis MS2(T) and Methanoculleus marisnigri JR1 revealed significant similarities. The absence of genes for a putative ammonium uptake system may indicate that M. bourgensis MS2(T) is adapted to environments rich in ammonium/ammonia. Specific genes featuring predicted functions in the context of osmolyte production were detected in the genome of M. bourgensis MS2(T). Mapping of metagenome sequences derived from a production-scale biogas plant revealed that M. bourgensis MS2(T) almost completely comprises the genetic information of dominant methanogens present in the biogas reactor analyzed. Hence, availability of the M. bourgensis MS2(T) genome sequence may be valuable regarding further research addressing the performance of Methanoculleus species in agricultural biogas plants.

  13. Optimization of biogas production from coffee production waste.

    Science.gov (United States)

    Battista, Federico; Fino, Debora; Mancini, Giuseppe

    2016-01-01

    This study was conducted to investigate the effects of chemical pretreatments on biogas production from coffee waste. After the preparation of a mixture of coffee waste with a TS concentration of 10%w/w, basic and acid pretreatments were conducted in batch mode and their performances were compared with the biogas produced from a mixture without any pretreatment stage. The basic pretreatment demonstrated a very good action on the hydrolysis of the lignin and cellulose, and permitted a biogas production of about 18NL/L with a methane content of almost 80%v/v. Thus, the basic pretreatment has been used to scale-up the process. The coffee refuse was has been carried out in a 45L anaerobic reactor working in continuous mode and in a mesophilic condition (35°C) with a Hydraulic Retention Time (HRT) of about 40days. A high biogas production of 1.14NL/Ld, with a methane percentage of 65%v/v was obtained, thus permitting a process yield of about 83% to be obtained.

  14. Spark ignition engine performance and emissions in a high compression engine using biogas and methane mixtures without knock occurrence

    Directory of Open Access Journals (Sweden)

    Gómez Montoya Juan Pablo

    2015-01-01

    Full Text Available With the purpose to use biogas in an internal combustion engine with high compression ratio and in order to get a high output thermal efficiency, this investigation used a diesel engine with a maximum output power 8.5 kW, which was converted to spark ignition mode to use it with gaseous fuels. Three fuels were used: Simulated biogas, biogas enriched with 25% and 50% methane by volume. After conversion, the output power of the engine decreased by 17.64% when using only biogas, where 7 kW was the new maximum output power of the engine. The compression ratio was kept at 15.5:1, and knocking did not occur during engine operation. Output thermal efficiency operating the engine in SI mode with biogas enriched with 50% methane was almost the same compared with the engine running in diesel-biogas dual mode at full load and was greater at part loads. The dependence of the diesel pilot was eliminated when biogas was used in the engine converted in SI mode. The optimum condition of experiment for the engine without knocking was using biogas enriched with 50% methane, with 12 degrees of spark timing advance and equivalence ratio of 0.95, larger output powers and higher values of methane concentration lead the engine to knock operation. The presence of CO2 allows operating engines at high compression ratios with normal combustion conditions. Emissions of nitrogen oxides, carbon monoxide and unburnt methane all in g/kWh decreased when the biogas was enriched with 50% methane.

  15. Systematic Quantification of Biogas Potential in Urban Organic Waste

    DEFF Research Database (Denmark)

    Fitamo, Temesgen Mathewos

    of biogas from organic waste rather than incineration and landfilling. The production of biogas from urban organic waste is expected to contribute to reaching the EU target of 20% of overall energy production and 10% of vehicle fuel derived from renewable sources by 2020. The Danish energy strategy...... is for Demark to become a 100% fossil fuel-free nation by 2050. However, existing technical challenges and barriers must be overcome to make the production of biogas more attractive. In this respect, a systematic quantification of the biogas production potential of various urban organic waste sources...... is necessary, in order to analyse and improve processes for biogas production. Conventionally, the potential biogas production of organic waste sources is quantified through biochemical methane potential (BMP) analysis and anaerobic digestion in biogas reactors. However, the determination of BMP in batch...

  16. High-calorific biogas production by selective CO₂ retention at autogenerated biogas pressures up to 20 bar.

    Science.gov (United States)

    Lindeboom, Ralph E F; Weijma, Jan; van Lier, Jules B

    2012-02-07

    Autogenerative high pressure digestion (AHPD) is a novel configuration of anaerobic digestion, in which micro-organisms produce autogenerated biogas pressures up to 90 bar with >90% CH(4)-content in a single step reactor. (1) The less than 10% CO(2)-content was postulated to be resulting from proportionally more CO(2) dissolution relative to CH(4) at increasing pressure. However, at 90 bar of total pressure Henry's law also predicts dissolution of 81% of produced CH(4). Therefore, in the present research we studied whether CO(2) can be selectively retained in solution at moderately high pressures up to 20 bar, aiming to produce high-calorific biogas with >90% methane. Experiments were performed in an 8 L closed fed-batch pressure digester fed with acetate as the substrate. Experimental results confirmed CH(4) distribution over gas and liquid phase according to Henry's law, but the CO(2)-content of the biogas was only 1-2%, at pH 7, that is, much lower than expected. By varying the ratio between acid neutralizing capacity (ANC) and total inorganic carbon (TIC(produced)) of the substrate between 0 and 1, the biogas CO(2)-content could be controlled independently of pressure. However, by decreasing the ANC relative to the TIC(produced) CO(2) accumulation in the aqueous medium caused acidification to pH 5, but remarkably, acetic acid was still converted into CH(4) at a rate comparable to neutral conditions.

  17. Enhancement of biogas production from food waste and sewage sludge - Environmental and economic life cycle performance.

    Science.gov (United States)

    Eriksson, Ola; Bisaillon, Mattias; Haraldsson, Mårten; Sundberg, Johan

    2016-06-15

    Management of municipal solid waste is an efficient method to increase resource efficiency, as well as to replace fossil fuels with renewable energy sources due to that (1) waste to a large extent is renewable as it consists of food waste, paper, wood etc. and (2) when energy and materials are recovered from waste treatment, fossil fuels can be substituted. In this paper results from a comprehensive system study of future biological treatment of readily degradable waste in two Swedish regions are presented. Different collection and separation systems for food waste in households have been applied as well as technical improvements of the biogas process as to reduce environmental impact. The results show that central sorting of a mixed fraction into recyclables, combustibles, biowaste and inert is a competitive option compared to source separation. Use of pellets is beneficial compared to direct spreading as fertiliser. Fuel pellets seem to be the most favourable option, which to a large extent depends on the circumstances in the energy system. Separation and utilisation of nitrogen in the wet part of the digestion residue is made possible with a number of technologies which decreases environmental impact drastically, however to a substantial cost in some cases.

  18. Serial CSTR digester configuration for improving biogas production from manure

    DEFF Research Database (Denmark)

    Boe, Kanokwan; Angelidaki, Irini

    2009-01-01

    A new configuration of manure digesters for improving biogas production has been investigated in laboratory scale. A single thermophilic continuous-flow stirred tank reactor (CSTR) operated with a hydraulic retention time (HRT) of 15 days was compared to a serial CSTR configuration with volume...... distribution ratio of 80/20 and 90/10, and total HRT of 15 days. The results showed that the serial CSTR could obtain 11% higher biogas yield compared to the single CSTR. The increased biogas yield in the serial CSTR was mainly from the second reactor, which accounted for 16% and 12% of total biogas yield...... in the 90/10 and 80/20 configuration, respectively. VFA concentration in the serial CSTR was high in the first reactor but very low in the second reactor. The results from organic pulse load test showed that the second reactor in serial CSTR helped utilizing VFA produced from overloading in the first...

  19. Online monitoring and control of the biogas process

    Energy Technology Data Exchange (ETDEWEB)

    Boe, K.

    2006-07-01

    The demand for online monitoring and control of biogas process is increasing, since better monitoring and control system can improve process stability and enhance process performance for better economy of the biogas plants. A number of parameters in both the liquid and the gas phase have been suggested as process indicators. These include gas production, pH, alkalinity, volatile fatty acids (VFA) and hydrogen. Of these, VFA is the most widely recognised as a direct, relevant measure of stability. The individual, rather than collective VFA concentrations are recognised as providing significantly more information for diagnosis. However, classic on-line measurement is based on filtration, which suffers from fouling, especially in particulate or slurry wastes. In this project, a new online VFA monitoring system has been developed using gas-phase VFA extraction to avoid sample filtration. The liquid sample is pumped into a sampling chamber, acidified, added with salt and heated to extract VFA into the gas phase before analysis by GC-FID. This allows easy application to manure. Sample and analysis time of the system varies from 25-40 min. depending on the washing duration. The sampling frequency is fast enough for the dynamic of a manure digester, which is in the range of several hours. This system has been validated over more than 6 months and had shown good agreement with offline VFA measurement. Response from this sensor was compared with other process parameters such as biogas production, pH and dissolved hydrogen during overload situations in a laboratory-scale digester, to investigate the suitability of each measure as a process indicator. VFA was most reliable for indicating process imbalance, and propionate was most persistent. However, when coupling the online VFA monitoring with a simple control for automatic controlling propionate level in a digester, it was found that propionate decreased so slow that the biogas production fluctuated. Therefore, it is more

  20. The Performance of Structured Packings in Trickle-Bed Reactors

    NARCIS (Netherlands)

    Frank, M.J.W.; Kuipers, J.A.M.; Versteeg, G.F.; Swaaij, W.P.M. van

    1999-01-01

    An experimental study was carried out to investigate whether the use of structured packings might improve the mass transfer characteristics and the catalyst effectiveness of a trickle-bed reactor. Therefore, the performances of a structured packing, consisting of KATAPAK elements, and a dumped packi

  1. The performance of structured packings in trickle-bed reactors.

    NARCIS (Netherlands)

    Frank, M.J.W.; Kuipers, J.A.M.; Versteeg, G.F.; Swaaij, van W.P.M.

    1999-01-01

    An experimental study was carried out to investigate whether the use of structured packings might improve the mass transfer characteristics and the catalyst effectiveness of a trickle-bed reactor. Therefore, the performances of a structured packing, consisting of KATAPAK elements, and a dumped packi

  2. BISON and MARMOT Development for Modeling Fast Reactor Fuel Performance

    Energy Technology Data Exchange (ETDEWEB)

    Gamble, Kyle Allan Lawrence [Idaho National Lab. (INL), Idaho Falls, ID (United States); Williamson, Richard L. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Schwen, Daniel [Idaho National Lab. (INL), Idaho Falls, ID (United States); Zhang, Yongfeng [Idaho National Lab. (INL), Idaho Falls, ID (United States); Novascone, Stephen Rhead [Idaho National Lab. (INL), Idaho Falls, ID (United States); Medvedev, Pavel G. [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2015-09-01

    BISON and MARMOT are two codes under development at the Idaho National Laboratory for engineering scale and lower length scale fuel performance modeling. It is desired to add capabilities for fast reactor applications to these codes. The fast reactor fuel types under consideration are metal (U-Pu-Zr) and oxide (MOX). The cladding types of interest include 316SS, D9, and HT9. The purpose of this report is to outline the proposed plans for code development and provide an overview of the models added to the BISON and MARMOT codes for fast reactor fuel behavior. A brief overview of preliminary discussions on the formation of a bilateral agreement between the Idaho National Laboratory and the National Nuclear Laboratory in the United Kingdom is presented.

  3. Monitoring and controlling the biogas process

    Energy Technology Data Exchange (ETDEWEB)

    Ahring, B.K.; Angelidaki, I. [The Technical Univ. of Denmark, Dept. of Environmental Science and Engineering, Lyngby (Denmark)

    1997-08-01

    Many modern large-scale biogas plants have been constructed recently, increasing the demand for proper monitoring and control of these large reactor systems. For monitoring the biogas process, an easy to measure and reliable indicator is required, which reflects the metabolic state and the activity of the bacterial populations in the reactor. In this paper, we discuss existing indicators as well as indicators under development which can potentially be used to monitor the state of the biogas process in a reactor. Furthermore, data are presented from two large scale thermophilic biogas plants, subjected to temperature changes and where the concentration of volatile fatty acids was monitored. The results clearly demonstrated that significant changes in the concentration of the individual VFA occurred although the biogas production was not significantly changed. Especially the concentrations of butyrate, isobutyrate and isovalerate showed significant changes. Future improvements of process control could therefore be based on monitoring of the concentration of specific VFA`s together with information about the bacterial populations in the reactor. The last information could be supplied by the use of modern molecular techniques. (au) 51 refs.

  4. Performance of an Anaerobic Baffled Filter Reactor in the Treatment of Algae-Laden Water and the Contribution of Granular Sludge

    Directory of Open Access Journals (Sweden)

    Yaqin Yu

    2014-01-01

    Full Text Available This study investigated the performance and stability of an anaerobic baffled filter reactor in the treatment of algae-laden water from Taihu Lake at several organic loading rates. The study also evaluated the capability of soft filler to train granule sludge and improve the anaerobic environment and sludge activity in the anaerobic baffled reactor (ABR, thereby enhancing the treatment efficiency. The ABR consisted of five rectangular compartments, each of which was 120 cm long, 80 cm wide, 80 cm high, and packed with soft filler. The anaerobic baffled filter reactor was found to be an efficient reactor configuration for the treatment of algae-laden water. The reactor was operated at an organic loading rate of 1.5 kg chemical oxygen demand (COD/(m3d and an ambient temperature of 30 °C; under these conditions, the COD removal efficiency was 80% and the biogas production rate was 293 mL/(Ld. Moreover, the soft filler increased the biomass retention time and decreased the rate at which solids were washed out from the reactor, promoting an improved spatial distribution of the microbial communities within the compartments. Methanoregula, Methanobacteriaceae, Methanosaeta, Methanoculleu, and Thermogymnomonas were the dominant archaeal species in each compartment during an operational period of approximately 100 days. The protease activity in the reactor decreased longitudinally down the reactor from Compartments 1 to 5, whereas the activity of coenzyme F420 increased. The soft filler played a key role in successfully treating algae-laden water with the anaerobic baffled filter reactor.

  5. Antibiotic Resistance Genes and Correlations with Microbial Community and Metal Resistance Genes in Full-Scale Biogas Reactors As Revealed by Metagenomic Analysis

    DEFF Research Database (Denmark)

    Luo, Gang; Li, Bing; Li, Li-Guan

    2017-01-01

    Digested residues from biogas plants are often used as biofertilizers for agricultural crops cultivation. The antibiotic resistance genes (ARGs) in digested residues pose a high risk to public health due to their potential spread to the disease-causing microorganisms and thus reduce the susceptib...

  6. Biogas Production Using Anaerobic Biodigester from Cassava Starch Effluent

    OpenAIRE

    Sunarso, S.; B Budiyono; Siswo Sumardiono

    2010-01-01

    IKMs’ factory activity in Margoyoso produces liquid and solid wastes. The possible alternative was to use the liquid effluent as biogas raw material. This study focuses on the used of urea, ruminant, yeast, microalgae, the treatment of gelled and ungelled feed for biogas production, pH control during biogas production using buffer Na2CO3, and feeding management in the semi-continuous process of biogas production that perform at ambient temperature for 30 days. Ruminant bacteria, yeast, urea, ...

  7. Improvement of Biogas Production by Bioaugmentation

    Directory of Open Access Journals (Sweden)

    K. L. Kovács

    2013-01-01

    Full Text Available Biogas production technologies commonly involve the use of natural anaerobic consortia of microbes. The objective of this study was to elucidate the importance of hydrogen in this complex microbial food chain. Novel laboratory biogas reactor prototypes were designed and constructed. The fates of pure hydrogen-producing cultures of Caldicellulosiruptor saccharolyticus and Enterobacter cloacae were followed in time in thermophilic and mesophilic natural biogas-producing communities, respectively. Molecular biological techniques were applied to study the altered ecosystems. A systematic study in 5-litre CSTR digesters revealed that a key fermentation parameter in the maintenance of an altered population balance is the loading rate of total organic solids. Intensification of the biogas production was observed and the results corroborate that the enhanced biogas productivity is associated with the increased abundance of the hydrogen producers. Fermentation parameters did not indicate signs of failure in the biogas production process. Rational construction of more efficient and sustainable biogas-producing microbial consortia is proposed.

  8. Performance of up flow anaerobic sludge fixed film bioreactor for the treatment of high organic load and biogas production of cheese whey wastewater

    Directory of Open Access Journals (Sweden)

    Tehrani Nazila Samimi

    2015-01-01

    Full Text Available Among various wastewater treatment technologies, biological wastewater treatment appears to be the most promising method. A pilot scale of hybrid anaerobic bioreactor was fabricated and used for the whey wastewater treatment. The top and bottom of the hybrid bioreactor known as up flow anaerobic sludge fixed film (UASFF; was a combination of up flow anaerobic sludge blanket (UASB and up flow anaerobic fixed film reactor (UAFF, respectively. The effects of operating parameters such as temperature and hydraulic retention time (HRT on chemical oxygen demand (COD removal and biogas production in the hybrid bioreactor were investigated. Treatability of the samples at various HRTs of 12, 24, 36 and 48 hours was evaluated in the fabricated bioreactor. The desired conditions for COD removal such as HRT of 48 hours and operation temperature of 40 °C were obtained. The maximum COD removal and biogas production were 80% and 2.40 (L/d, respectively. Kinetic models of Riccati, Monod and Verhalst were also evaluated for the living microorganisms in the treatment process. Among the above models, Riccati model was the best growth model fitted with the experimental data with R2 of about 0.99.

  9. Improved biogas production from rice straw by co-digestion with kitchen waste and pig manure

    Energy Technology Data Exchange (ETDEWEB)

    Ye, Jingqing [Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640 (China); School of Environmental Sciences and Engineering, Sun Yat-sen University, Guangzhou 510275 (China); Li, Dong; Sun, Yongming [Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640 (China); Wang, Guohui [School of Environmental Sciences and Engineering, Sun Yat-sen University, Guangzhou 510275 (China); Yuan, Zhenhong, E-mail: yuanzh@ms.giec.ac.cn [Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640 (China); Zhen, Feng; Wang, Yao [Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640 (China)

    2013-12-15

    Highlights: • Biogas production was enhanced by co-digestion of rice straw with other materials. • The optimal ratio of kitchen waste, pig manure and rice straw is 0.4:1.6:1. • The maximum biogas yield of 674.4 L/kg VS was obtained. • VFA inhibition occurred when kitchen waste content was more than 26%. • The dominant VFA were propionate and acetate in successful reactors. - Abstract: In order to investigate the effect of feedstock ratios in biogas production, anaerobic co-digestions of rice straw with kitchen waste and pig manure were carried out. A series of single-stage batch mesophilic (37 ± 1 °C) anaerobic digestions were performed at a substrate concentration of 54 g/L based on volatile solids (VS). The results showed that the optimal ratio of kitchen waste, pig manure, and rice straw was 0.4:1.6:1, for which the C/N ratio was 21.7. The methane content was 45.9–70.0% and rate of VS reduction was 55.8%. The biogas yield of 674.4 L/kg VS was higher than that of the digestion of rice straw or pig manure alone by 71.67% and 10.41%, respectively. Inhibition of biogas production by volatile fatty acids (VFA) occurred when the addition of kitchen waste was greater than 26%. The VFA analysis showed that, in the reactors that successfully produced biogas, the dominant intermediate metabolites were propionate and acetate, while they were lactic acid, acetate, and propionate in the others.

  10. Operational limitations of light water reactors relating to fuel performance

    Energy Technology Data Exchange (ETDEWEB)

    Cheng, H S

    1976-07-01

    General aspects of fuel performance for typical Boiling and Pressurized Water Reactors are presented. Emphasis is placed on fuel failures in order to make clear important operational limitations. A discussion of fuel element designs is first given to provide the background information for the subsequent discussion of several fuel failure modes that have been identified. Fuel failure experiences through December 31, 1974, are summarized. The operational limitations that are required to mitigate the effects of fuel failures are discussed.

  11. Biogas Production from Sugarcane Waste: Assessment on Kinetic Challenges for Process Designing.

    Science.gov (United States)

    Janke, Leandro; Leite, Athaydes; Nikolausz, Marcell; Schmidt, Thomas; Liebetrau, Jan; Nelles, Michael; Stinner, Walter

    2015-08-31

    Biogas production from sugarcane waste has large potential for energy generation, however, to enable the optimization of the anaerobic digestion (AD) process each substrate characteristic should be carefully evaluated. In this study, the kinetic challenges for biogas production from different types of sugarcane waste were assessed. Samples of vinasse, filter cake, bagasse, and straw were analyzed in terms of total and volatile solids, chemical oxygen demand, macronutrients, trace elements, and nutritional value. Biochemical methane potential assays were performed to evaluate the energy potential of the substrates according to different types of sugarcane plants. Methane yields varied considerably (5-181 Nm³·tonFM(-1)), mainly due to the different substrate characteristics and sugar and/or ethanol production processes. Therefore, for the optimization of AD on a large-scale, continuous stirred-tank reactor with long hydraulic retention times (>35 days) should be used for biogas production from bagasse and straw, coupled with pre-treatment process to enhance the degradation of the fibrous carbohydrates. Biomass immobilization systems are recommended in case vinasse is used as substrate, due to its low solid content, while filter cake could complement the biogas production from vinasse during the sugarcane offseason, providing a higher utilization of the biogas system during the entire year.

  12. Anaerobic digestion of different organic wastes for biogas production and its operational control performed by the modified ADM1.

    Science.gov (United States)

    Zhou, Haidong; Li, Han; Wang, Fengfei

    2012-01-01

    Anaerobic digestion (AD) of different organic wastes for biogas production under variable operating conditions was simulated with a steady-state implementation of the modified IWA Anaerobic Digestion Model No. 1 (ADM1), and an input-output feedback control system using the model as a test platform was developed. The main aim of this study was to compare the characteristics of organic wastes in the AD processes and manage to keep the processes stable based on the results of simulation. The two important operating factors, solid retention time (SRT) and organic loading rate (OLR) (or the ratio of input flows for co-digestion), were investigated. Anaerobic digestion of biowaste was characterized with lower biogas production and instability of the processes, especially at OLR 2.5 kgCOD/m(3)·d or more, although longer SRT could increase the biogas production. Moreover, the co-substrate composed of biowaste and corn silage would lead to instability of the processes and much lower biogas production. Biowaste was, however, preferable to be co-digested with manures of living stock or sewage sludge. Manure could contribute to the stability of the AD processes, and its co-substrates with organic wastes rich in carbohydrates such as biowaste and corn silage would improve the biogas production and the proportion of methane. Longer SRTs would improve the biogas production from manure as well as its co-substrates except the co-substrate with biowaste as the production was not distinctly raised. The test of the developed input-output feedback control system showed that the control system could reject a realistic set of random disturbances and keep the AD processes stable under the desired operational conditions with a minimal use of measurement facilities.

  13. Performance improvement of direct internal reforming solid oxide fuel cell fuelled by H2S-contaminated biogas with paper-structured catalyst technology

    Science.gov (United States)

    Shiratori, Y.; Sakamoto, M.

    2016-11-01

    Direct internal reforming (DIR) operation of a solid oxide fuel cell (SOFC) is a very attractive concept for downsizing and cost reduction of SOFC systems. This study aimed to develop stable operation of a DIR-SOFC fuelled by biogas. The current-voltage (I-V) curves of 2 × 2 cm2 planar SOFCs (anode- and electrolyte-supported cells, ASC and ESC, respectively.) were measured at 800 °C in the direct feed of a simulated biogas mixture (CH4/CO2 = 1), and the flexible structured catalyst material (paper-structured catalyst (PSC)) was applied on the anode material for performance enhancement. By applying a hydrotalcite (HT)-dispersed PSC (HT-PSC), the sulfur tolerance of the SOFC in the DIR operation was remarkably improved. By the effect of the HT-PSC, for both ASC and ESC, a stable cell voltage higher than 800 mV was obtained over 200 h at 0.2 A cm-2 in the direct feed of simulated biogas under 5 ppm H2S poisoning.

  14. Contrast on Biogas Production Performances of Above Ground and Under Ground Digesters%地上和地下式沼气池产气性能对比

    Institute of Scientific and Technical Information of China (English)

    李金怀; 徐铁纯; 蒋湖波; 赵德钦

    2012-01-01

    Biogas production performances of above ground and under ground digesters were contrasted, based on the characteristics of underground digester with water pressure and above ground movable digest- er and the same fermented concentration of pig murine material. The results showed that the biogas and methane production of underground digester was higher than above ground digester, and there was no difference to methane content in two types of digesters. In addition, temperature had influence on biogas production of two types of digesters%针对广西推广的地下水压式沼气池和地上移动式沼气池的特点,以猪粪为发酵原料,并以相同的发酵浓度投料,进行地上和地下式沼气池产气性能对比试验,结果表明:地下水压式沼气池的产气量和产甲烷量都显著高于地上移动式沼气池,而2种形式的沼气池中甲烷含量相差不大。此外,温度对2种形式沼气池的产气性能有一定影响。

  15. Energy Crop-Based Biogas as Vehicle Fuel—The Impact of Crop Selection on Energy Efficiency and Greenhouse Gas Performance

    Directory of Open Access Journals (Sweden)

    Pål Börjesson

    2015-06-01

    Full Text Available The production of biogas from six agricultural crops was analysed regarding energy efficiency and greenhouse gas (GHG performance for vehicle fuel from a field-to-tank perspective, with focus on critical parameters and on calculation methods. The energy efficiency varied from 35% to 44%, expressed as primary energy input per energy unit vehicle gas produced. The GHG reduction varied from 70% to 120%, compared with fossil liquid fuels, when the GHG credit of the digestate produced was included through system expansion according to the calculation methodology in the ISO 14044 standard of life cycle assessment. Ley crop-based biogas systems led to the highest GHG reduction, due to the significant soil carbon accumulation, followed by maize, wheat, hemp, triticale and sugar beet. Critical parameters are biogenic nitrous oxide emissions from crop cultivation, for which specific emission factors for digestate are missing today, and methane leakage from biogas production. The GHG benefits were reduced and the interrelation between the crops changed, when the GHG calculations were instead based on the methodology stated in the EU Renewable Energy Directive, where crop contribution to soil carbon accumulation is disregarded. All systems could still reach a 60% GHG reduction, due to the improved agricultural management when digestate replaces mineral fertilisers.

  16. Assessment of The Performance of a Small Capacity SI Engine Fuelled with Model Lean Mixture of Biogas

    OpenAIRE

    Przybyla, Grzegorz Kazimierz; Andrzej SZLEK; Ziolkowski, Lukasz

    2013-01-01

    In this paper the results of the experimental study on the SI engine using biogas will be presented. The experiments were carried out on a petrol engine with a low engine displacement. Typical SI engine was selected in order to evaluate the potential application of gaseous fuel (i.e. biogas). These types of engines are available on a wide scale and commonly used in automotive sector because of the low purchase price and operating costs. It is expected that after minor modifications, the engin...

  17. Use of alcohol distillery wastewater for sulfide hydrogen removal with iron chloride; Uso de los mostos de destilerias de alcohol tratados en reactores anaerobios para la desulfuracion del biogas con cloruro ferrico

    Energy Technology Data Exchange (ETDEWEB)

    Obaya, M. C.; Valencia, R.; Eng, F.; Diez, K.; Valdes, E.; Santiesteban Garlobo, C. M.

    2002-07-01

    From the technical point of view, the assayed meted was very good to achieve very high percents of sulfide hydrogen removal in the treated biogas where the concentrations were below to the required. It had been proved to scale of lab, those results were more efficient when we used of tubular reactors and the gas-liquid contact was more effective. There were not significant differences between the experiments with stirring and without it and the light effect on pH over iron sulfide production rate, that do not justified some expense of neutralizing agents. The meted was particularly attractive when it was employed ad liquid medium for depuration, the wastewaters from alcohol distillery treated in the anaerobic digester, which had a high pH and buffer capacity. They allowed keeping a relatively high pH(7.8-8.5) without employing chemical neutralizing agents. (Author) 15 refs.

  18. Biogas Production on Demand Regulated by Butyric Acid Addition

    Science.gov (United States)

    Kasper, K.; Schiffels, J.; Krafft, S.; Kuperjans, I.; Elbers, G.; Selmer, T.

    2016-03-01

    Investigating effects of volatile fatty acids on the biogas process it was observed that butyric acid can be used for transient stimulation of the methane production in biogas plants operating with low energy substrates like cattle manure. Upon addition of butyrate the methane output of the reactors doubled within 24 h and reached almost 3-times higher methane yields within 3-4 days. Butyrate was quantitatively eliminated and the reactors returned to the original productivity state within 3 days when application of butyrate was stopped. The opportunity to use butyrate feeding for increased biogas production on demand is discussed.

  19. High Performance Fuel Desing for Next Generation Pressurized Water Reactors

    Energy Technology Data Exchange (ETDEWEB)

    Mujid S. Kazimi; Pavel Hejzlar

    2006-01-31

    The use of internally and externally cooled annular fule rods for high power density Pressurized Water Reactors is assessed. The assessment included steady state and transient thermal conditions, neutronic and fuel management requirements, mechanical vibration issues, fuel performance issues, fuel fabrication methods and econmic assessment. The investigation was donducted by a team from MIT, Westinghouse, Gamma Engineering, Framatome ANP, and AECL. The analyses led to the conclusion that raising the power density by 50% may be possible with this advanced fuel. Even at the 150% power level, the fuel temperature would be a few hundred degrees lower than the current fuel temperatre. Significant economic and safety advantages can be obtained by using this fuel in new reactors. Switching to this type of fuel for existing reactors would yield safety advantages, but the economic return is dependent on the duration of plant shutdown to accommodate higher power production. The main feasiblity issue for the high power performance appears to be the potential for uneven splitting of heat flux between the inner and outer fuel surfaces due to premature closure of the outer fuel-cladding gap. This could be overcome by using a very narrow gap for the inner fuel surface and/or the spraying of a crushable zirconium oxide film at the fuel pellet outer surface. An alternative fuel manufacturing approach using vobropacking was also investigated but appears to yield lower than desirable fuel density.

  20. Impact of reactor water chemistry on cladding performance

    Energy Technology Data Exchange (ETDEWEB)

    Cox, B. [University of Toronto, Centre for Nuclear Engineering, Toronto, Ontario (Canada)

    1997-07-01

    Water chemistry may have a major impact on fuel cladding performance in PWRs. If the saturation temperature on the surface of fuel cladding is exceeded, either because of the thermal hydraulics of the system, or because of crud deposition, then LiOH concentration can occur within thick porous oxide films on the cladding. This can degrade the protective film and accelerate the corrosion rate of the cladding. If sufficient boric acid is also present in the coolant then these effects may be mitigated. This is normally the case through most of any reactor fuel cycle. Extensive surface boiling may disrupt this equilibrium because of the volatility of boric acid in steam. Under such conditions severe cladding corrosion can ensue. The potential for such effects on high burnup cladding in CANDU reactors, where bone acid is not present in the primary coolant, is discussed. (author)

  1. Overcoming the effects of stress on reactor operator performance

    Energy Technology Data Exchange (ETDEWEB)

    He Xuhong; Wei Li; Zhao Bingquan [Tsinghua Univ., Nuclear Power Plant Simulation Training Center, Beijing (China)

    2003-03-01

    Reactor operators may be exposed to significant levels of stress during plant emergencies and their performance may be affected by the stress. This paper first identified the potential sources of stress in the nuclear power plant, then discussed the ways in which stress is likely to affect the reactor operators, and finally identified several training approaches for reducing or eliminating stress effects. The challenges for effective stress reducing training may seem daunting, yet the challenges are real and must be addressed. This paper reviewed researches in training design, knowledge and skill acquisition, and training transfer point to a number of strategies that can be used to address these challenges and lead to more effective training and development. (author)

  2. Computational Neutronics Methods and Transmutation Performance Analyses for Fast Reactors

    Energy Technology Data Exchange (ETDEWEB)

    R. Ferrer; M. Asgari; S. Bays; B. Forget

    2007-03-01

    The once-through fuel cycle strategy in the United States for the past six decades has resulted in an accumulation of Light Water Reactor (LWR) Spent Nuclear Fuel (SNF). This SNF contains considerable amounts of transuranic (TRU) elements that limit the volumetric capacity of the current planned repository strategy. A possible way of maximizing the volumetric utilization of the repository is to separate the TRU from the LWR SNF through a process such as UREX+1a, and convert it into fuel for a fast-spectrum Advanced Burner Reactor (ABR). The key advantage in this scenario is the assumption that recycling of TRU in the ABR (through pyroprocessing or some other approach), along with a low capture-to-fission probability in the fast reactor’s high-energy neutron spectrum, can effectively decrease the decay heat and toxicity of the waste being sent to the repository. The decay heat and toxicity reduction can thus minimize the need for multiple repositories. This report summarizes the work performed by the fuel cycle analysis group at the Idaho National Laboratory (INL) to establish the specific technical capability for performing fast reactor fuel cycle analysis and its application to a high-priority ABR concept. The high-priority ABR conceptual design selected is a metallic-fueled, 1000 MWth SuperPRISM (S-PRISM)-based ABR with a conversion ratio of 0.5. Results from the analysis showed excellent agreement with reference values. The independent model was subsequently used to study the effects of excluding curium from the transuranic (TRU) external feed coming from the LWR SNF and recycling the curium produced by the fast reactor itself through pyroprocessing. Current studies to be published this year focus on analyzing the effects of different separation strategies as well as heterogeneous TRU target systems.

  3. Effect of Equivalence Ratio on Composition and performance of Biogas and Gasoline Exhaust from Spark Ignition Engine by Mathematical Modeling

    Directory of Open Access Journals (Sweden)

    Juntarakod Paramust

    2016-01-01

    Full Text Available This paper presents the numerical computationnal of pressure, temperature and exhaust characteristics of spark ignition engine with biogas as fuel. The solution of non-linear combustion equation systems have been computed, that based on a quasi-one-dimensional engine model, high order iteration method with the equilibrium constants method. Computer program was used to calculate the mole fractions of 10 combustion products when biogas and gasoline fuel are burnt along with variable equivalence ratios. In cylinder chamber model is based on the classical two-zone approach, wherein parameters like heat transfer from the cylinder, blow by energy loss and heat release rate are also considered and calculated. Biogas is defined as fuel produced from using anaerobic digestion of biodegradable or waste materials and the constituents are C5H7O2N, CH4, CO2 N2 H2O of biogas and C7H17 of gosoline. Which general fuel model is specified by way of its CaHbOcNd values. The curve-fitted coefficients of energy were then employed to simulate air and fuels data along with frozen composition and practical chemical equilibrium routines from Gill data. The calculated data were used to plot the various pressure and temperature with the crank angle of each step of four stroke engine cycle and combustion products versus equivalence ratio. All results were compared with gasoline as reference fuel in the spark ignition engine according to the same numerical method.

  4. Enhancing the hydrolysis process of a two-stage biogas technology for the organic fraction of municipal solid waste

    DEFF Research Database (Denmark)

    Nasir, Zeeshan; Uellendahl, Hinrich

    2015-01-01

    the hydrolytic (1st) stage, which enables pump-free feeding of the waste into the 1st stage (processing module), and eliminates the risk for blocking of pumps and pipes by pumping only the percolate from the 1st stage into the 2nd stage (biogas reactor tank). The biogas yield of the AIKAN® two-stage process...... as lab-scale batch and pilot-scale reactor tests. A lab-scale reactor system to mimic the 2-stage set-up in large-scale is currently set-up and the results will be included in the final conference paper. The first pilot-scale tests were performed at Solum’s pilot-scale modules by adjusting the p...

  5. Optimization of biogas production from manure

    DEFF Research Database (Denmark)

    Kaparaju, Prasad Laxmi-Narasimha; Boe, Kanokwan; Buendia, Inmaculada M.

    The main objective of the project was to improve biogas production from manures. This objective was addressed by investigating 1) the effect of different reactor configurations, 2) operational procedures, aiming to selectively retain/return degradable material in the reactor and 3) different...... process. In the second experiment, the effect of temperature (10 & 55°C) and microbial activity on passive separation of digested cow manure was investigated in vertical columns (100 cm) with an aim to improve solids retention time within the reactor and improve biogas production. Results showed...... improved from 2.5 to 14.6% when the reactor was operated under intermittent mixing compared to continuous mixing. The effect of mixing intensities (minimal, gentle or vigorous) in batch assays at 55°C showed that when the process was overloaded by high substrate to inoculum ratio (40/60), gentle (35 times...

  6. Formation and suppression of foam in biogas plants. Practical experiences; Bildung von Schaum in Biogasanlagen und seine Bekaempfung. Erfahrungen aus der Praxis

    Energy Technology Data Exchange (ETDEWEB)

    Moeller, Lucie; Goersch, Kati; Mueller, Roland A.; Zehnsdorf, Andreas [Helmholtz-Zentrum fuer Umweltforschung - UFZ, Leipzig (Germany). Umwelt- und Biotechnologisches Zentrum

    2012-07-01

    Foam formation during the anaerobic digestion may have negative impact on the economics of a biogas plant. This problem concerns especially those biogas plants, which utilize biogenic waste for biogas production. Eighteen operators of waste treating biogas plants from Saxony, Saxony-Anhalt and Thuringia have been surveyed. The aim of the enquiry was collecting experience about the foam formation in biogas reactors and about the foam fighting tasks in practice. (orig.)

  7. Pengaruh Laju Alir Volumetrik Umpan Static In-Line Mixer Terhadap Performance Bioreaktor Pada Pembuatan Biogas Dari Limbah Cair Kelapa Sawit Skala Pilot Plant

    OpenAIRE

    Sitepu, Juliananta

    2015-01-01

    Indonesia as the second country for production CPO in the world is very potesially in biogas industry. Something make it very potensial is POME (Palm Oil Effulent).POME is the most important in biogas because it can be change to biogas. Production biogas is in thermofilik anaerob with recyle sludge 34% through in four tank. They are pretreatment tank, mixing tank, bioreactor, and gravity thickner.The mixing tank is a tank with motor (machine), impeller and any baffle. For...

  8. Titer-plate formatted continuous flow thermal reactors: Design and performance of a nanoliter reactor.

    Science.gov (United States)

    Chen, Pin-Chuan; Park, Daniel S; You, Byoung-Hee; Kim, Namwon; Park, Taehyun; Soper, Steven A; Nikitopoulos, Dimitris E; Murphy, Michael C

    2010-08-06

    Arrays of continuous flow thermal reactors were designed, configured, and fabricated in a 96-device (12 × 8) titer-plate format with overall dimensions of 120 mm × 96 mm, with each reactor confined to a 8 mm × 8 mm footprint. To demonstrate the potential, individual 20-cycle (740 nL) and 25-cycle (990 nL) reactors were used to perform the continuous flow polymerase chain reaction (CFPCR) for amplification of DNA fragments of different lengths. Since thermal isolation of the required temperature zones was essential for optimal biochemical reactions, three finite element models, executed with ANSYS (v. 11.0, Canonsburg, PA), were used to characterize the thermal performance and guide system design: (1) a single device to determine the dimensions of the thermal management structures; (2) a single CFPCR device within an 8 mm × 8 mm area to evaluate the integrity of the thermostatic zones; and (3) a single, straight microchannel representing a single loop of the spiral CFPCR device, accounting for all of the heat transfer modes, to determine whether the PCR cocktail was exposed to the proper temperature cycling. In prior work on larger footprint devices, simple grooves between temperature zones provided sufficient thermal resistance between zones. For the small footprint reactor array, 0.4 mm wide and 1.2 mm high fins were necessary within the groove to cool the PCR cocktail efficiently, with a temperature gradient of 15.8°C/mm, as it flowed from the denaturation zone to the renaturation zone. With temperature tolerance bands of ±2°C defined about the nominal temperatures, more than 72.5% of the microchannel length was located within the desired temperature bands. The residence time of the PCR cocktail in each temperature zone decreased and the transition times between zones increased at higher PCR cocktail flow velocities, leading to less time for the amplification reactions. Experiments demonstrated the performance of the CFPCR devices as a function of flow

  9. Draft genome sequence of Herbinix hemicellulosilytica T3/55 T, a new thermophilic cellulose degrading bacterium isolated from a thermophilic biogas reactor.

    Science.gov (United States)

    Koeck, Daniela E; Maus, Irena; Wibberg, Daniel; Winkler, Anika; Zverlov, Vladimir V; Liebl, Wolfgang; Pühler, Alfred; Schwarz, Wolfgang H; Schlüter, Andreas

    2015-11-20

    A novel bacterial species was isolated from an industrial-scale biogas plant. The isolate Herbinix hemicellulosilytica T3/55(T) is able to degrade crystalline cellulose. Comparative 16S rRNA gene sequencing demonstrated that the isolate is closely related to environmental samples forming a hitherto unknown sub-cluster within the family Lachnospiraceae. The draft genome sequence of strain T3/55(T) was established and now provides the genetic basis for application of this microorganism in thermophilic degradation of lignocellulosic biomass.

  10. Hybrid Adsorption-Membrane Biological Reactors for Improved Performance and Reliability of Perchlorate Removal Processes

    Science.gov (United States)

    2008-12-01

    carbon supply for the autotrophic perchlorate reducing bacteria. The membrane used in the reactor is a hollow-fiber microfiltration membrane made from...1 HYBRID ADSORPTION- MEMBRANE BIOLOGICAL REACTORS FOR IMPROVED PERFORMANCE AND RELIABILITY OF PERCHLORATE REMOVAL PROCESSES L.C. Schideman...Center Champaign, IL 61826, USA ABSTRACT This study introduces the novel HAMBgR process (Hybrid Adsorption Membrane Biological Reactor) and

  11. Biogas from lignocellulosic biomass

    Energy Technology Data Exchange (ETDEWEB)

    Berglund Odhner, Peter; Schabbauer, Anna [Grontmij AB, Stockholm (Sweden); Sarvari Horvath, Ilona; Mohseni Kabir, Maryam [Hoegskolan i Boraas, Boraas (Sweden)

    2012-01-15

    Grontmij AB has cooperated with the University of Boraas to evaluate the technological and economical possibilities for biogas production from substrates containing lignocellulose, such as forest residues, straw and paper. The state of knowledge regarding biogas production from cellulosic biomass has been summarized. The research in the field has been described, especially focusing on pretreatment methods and their results on increased gas yields. An investigation concerning commercially available pretreatment methods and the cost of these technologies has been performed. An economic evaluation of biogas production from lignocellulosic materials has provided answers to questions regarding the profitability of these processes. Pretreatment with steam explosion was economically evaluated for three feedstocks - wood, straw and paper - and a combination of steam explosion and addition of NaOH for paper. The presented costs pertain to costs for the pretreatment step as it, in this study, was assumed that the pretreatment would be added to an existing plant and the lignocellulosic substrates would be part of a co-digestion process. The results of the investigation indicate that it is difficult to provide a positive net result when comparing the cost of pretreatment versus the gas yield (value) for two of the feedstocks - forest residues and straw. This is mainly due to the high cost of the raw material. For forest residues the steam pretreatment cost exceeded the gas yield by over 50 %, mainly due to the high cost of the raw material. For straw, the production cost was similar to the value of the gas. Paper showed the best economic result. The gas yield (value) for paper exceeded the pretreatment cost by 15 %, which makes it interesting to study paper further.

  12. PERFORMANCE IMPROVEMENT OF A CHEMICAL REACTOR BY NONLINEAR NATURAL OSCILLATIONS

    NARCIS (Netherlands)

    RAY, AK

    1995-01-01

    The dynamic behaviour of two coupled continuous stirred tank reactors in sequence is studied when the first reactor is being operated under limit cycle regimes producing self-sustained natural oscillations. The periodic output from the first reactor is then used as a forced input into the second rea

  13. A highly concentrated diet increases biogas production and the agronomic value of young bull's manure.

    Science.gov (United States)

    Mendonça Costa, Mônica Sarolli Silva de; Lucas, Jorge de; Mendonça Costa, Luiz Antonio de; Orrico, Ana Carolina Amorim

    2016-02-01

    The increasing demand for animal protein has driven significant changes in cattle breeding systems, mainly in feedlots, with the use of young bulls fed on diets richer in concentrate (C) than in forage (F). These changes are likely to affect animal manure, demanding re-evaluation of the biogas production per kg of TS and VS added, as well as of its agronomic value as a biofertilizer, after anaerobic digestion. Here, we determined the biogas production and agronomic value (i.e., the macronutrient concentration in the final biofertilizer) of the manure of young bulls fed on diets with more (80% C+20% F; 'HighC' diet) or less (65% C+35% F; 'LowC' diet) concentrate, evaluating the effects of temperature (25, 35, and 40°C) and the use of an inoculum, during anaerobic digestion. A total of 24 benchtop reactors were used, operating in a semi-continuous system, with a 40-day hydraulic retention time (HRT). The manure from animals given the HighC diet had the greatest potential for biogas production, when digested with the use of an inoculum and at 35 or 40°C (0.6326 and 0.6207m(3)biogas/kg volatile solids, or VS, respectively). We observed the highest levels of the macronutrients N, P, and K in the biofertilizer from the manure of animals given HighC. Our results show that the manure of young bulls achieves its highest potential for biogas production and agronomic value when animals are fed diets richer in concentrate, and that biogas production increases if digestion is performed at higher temperatures, and with the use of an inoculum.

  14. Desempenho de um conjunto motogerador adaptado a biogás Performance of a motogenerator adapted for biogas

    Directory of Open Access Journals (Sweden)

    Rodrigo G. Souza

    2010-02-01

    Full Text Available O presente trabalho foi desenvolvido na Estação de Produção e Uso de Biogás, da Universidade Federal de Lavras. O objetivo foi desenvolver e avaliar um sistema de alimentação de um motor estacionário com biogás. Foi utilizado um motor de 4 tempos com 4077 W de potência nominal à rotação de 4200 rpm acoplado a um gerador de 2400 W com rotação operacional de 3600 rpm. O biogás utilizado foi produzido em um biodigestor modelo indiano a partir de esterco bovino, contendo, em média, 63 % de metano. Os experimentos foram realizados com o motor operando, inicialmente, a gasolina na sua versão original e, posteriormente, com o sistema de alimentação a biogás. Para os ensaios foram medidas as rotações e o consumo energético do motor, além da tensão e corrente gerada para alimentar três potências resistivas iguais a 1000, 1200 e 1500 W. Para o conjunto motogerador alimentado a gasolina na sua versão original, observou-se uma potência média gerada de 840,2 W com tensão de 109 volts e eficiência do conjunto de 12,14 %. Para o conjunto motogerador operando a biogás utilizando o sistema de alimentação desenvolvido, observou-se uma potência média de 934,59 W, tensão 100,90 volts e eficiência de 8,22 %. Foi possível operar estavelmente o conjunto motogerador com combustível alternativo, biogás, utilizando o sistema de alimentação desenvolvido, substituindo em 100% o uso de gasolina.The present work was conducted at the Unity of Production and Use of Biogas of Lavras Federal University. Its objective was to develop and to evaluate the biogas powering system in a stationary motor using biogas. A four-timing stationary motor with 4077 W nominal potency at a 4200 rpm rotation was used coupled to a generator of 2400 W with operational rotation of 3600 rpm. The biogas used in the experiment was produced in an Indian model biodigestor operated with bovine manure, containing an average of 63% methane. The experiments were

  15. Influence of Inoculum Content on Performance of Anaerobic Reactors for Treating Cattle Manure using Rumen Fluid Inoculum

    Directory of Open Access Journals (Sweden)

    Sunarso

    2009-12-01

    Full Text Available Biogas productions of cattle manure using rumen fluid inoculums were determined using batch anaerobic digesters at mesophilic temperatures (room and 38.5 oC. The aim of this paper was to analyze the influence of rumen fluid contents on biogas yield from cattle manure using fluid rumen inoculums. A series of laboratory experiments using 400 ml biodigester were performed in batch operation mode. Given 100 grams of fresh cattle manure (M was fed to each biodigester and mixed with rumen fluid (R and tap water (W in several ratio resulting six different M:W:R ratio contents i.e. 1:1:0; 1:0.75:0.25; 1:0.5:0.5; 1:0.25:0.75; and 1:0:1 (correspond to 0; 12.5; 25, 37.5; 50, and 100 % rumen, respectively. The research showed that, either in room temperature as well as in 38.5 C, the best performance of biogas production was obtained with rumen fluid in the range of 25-50 %. Increasing rumen content will also increase biogas production. This is suggest that, due to the optimum total solid (TS content for biogas production between 7-9 % (or correspond to more and less manure and total liquid 1:1, the rumen fluid content of 50 % will give the best performance for biogas production. However, intensively research need to be carried in further research to study interaction effect of TS and rumen content to biogas production.

  16. Biogas Production: Microbiology and Technology.

    Science.gov (United States)

    Schnürer, Anna

    Biogas, containing energy-rich methane, is produced by microbial decomposition of organic material under anaerobic conditions. Under controlled conditions, this process can be used for the production of energy and a nutrient-rich residue suitable for use as a fertilising agent. The biogas can be used for production of heat, electricity or vehicle fuel. Different substrates can be used in the process and, depending on substrate character, various reactor technologies are available. The microbiological process leading to methane production is complex and involves many different types of microorganisms, often operating in close relationships because of the limited amount of energy available for growth. The microbial community structure is shaped by the incoming material, but also by operating parameters such as process temperature. Factors leading to an imbalance in the microbial community can result in process instability or even complete process failure. To ensure stable operation, different key parameters, such as levels of degradation intermediates and gas quality, are often monitored. Despite the fact that the anaerobic digestion process has long been used for industrial production of biogas, many questions need still to be resolved to achieve optimal management and gas yields and to exploit the great energy and nutrient potential available in waste material. This chapter discusses the different aspects that need to be taken into consideration to achieve optimal degradation and gas production, with particular focus on operation management and microbiology.

  17. Microbial community structure and dynamics during co-digestion of whey permeate and cow manure in continuous stirred tank reactor systems.

    Science.gov (United States)

    Hagen, Live Heldal; Vivekanand, Vivekanand; Linjordet, Roar; Pope, Phillip B; Eijsink, Vincent G H; Horn, Svein J

    2014-11-01

    Microbial community profiles in two parallel CSTR biogas reactors fed with whey permeate and cow manure were investigated. The operating conditions for these two reactors were identical, yet only one of them (R1) showed stable performance, whereas the other (R2) showed a decrease in methane production accompanied by accumulation of propionic acid and, later, acetic acid. This gave a unique opportunity to study the dynamics of the microbial communities in two biogas reactors apparently operating close to the edge of stability. The microbial community was dominated by Bacteroidetes and Firmicutes, and the methanogens Methanobacteriales and Methanomicrobiales in both reactors, but with larger fluctuations in R2. Correlation analyses showed that the depletion of propionic acid in R1 and the late increase of acetic acid in R2 was related to several bacterial groups. The biogas production in R1 shows that stable co-digestion of manure and whey can be achieved with reasonable yields.

  18. GlidArc-assisted production of synthesis gas from biogas

    Energy Technology Data Exchange (ETDEWEB)

    Czernichowski, A.; Czernichowski, M.; Wesolowska, K. [Etudes Chimiques et Physiques, La Ferte Saint Aubin (France)

    2003-07-01

    This paper elaborates on the use of a biogas reformer process based on the direct use of high-voltage discharges (also called GlidArc) which strike in the flow of renewable feedstock without requiring prior gas separation or purification. The paper describes the partial conversion of a poor biogas into hydrogen and carbon monoxide (syngas). The biogas contained only 35 to 50 volume per cent of methane. The reformer accepts any level of impurities. All the energy and catalytic assistance for endothermic process of dry reforming of methane plus carbon dioxide into hydrogen and carbon monoxide is provided by the discharges. A 1.4-litre reactor operating at atmospheric pressure was used to conduct the tests with simulated biogas, at up to 0.6 kilowatt. This input proved sufficient to process a flow of a poor biogas carrying up to 7 kilowatts of thermal power. 13 refs., 2 tabs., 3 figs.

  19. The control of H2S in biogas using iron ores as in situ desulfurizers during anaerobic digestion process.

    Science.gov (United States)

    Zhou, Qiying; Jiang, Xia; Li, Xi; Jiang, Wenju

    2016-09-01

    In this study, five kinds of iron ores, limonite, hematite, manganese ore, magnetite and lava rock, were used as the in situ desulfurizers in the anaerobic digestion reactors to investigate their effects on controlling H2S in biogas. The results show that the addition of the five iron ores could significantly control the content of H2S in biogas, with the best performance for limonite. As limonite dosages increase (10-60 g/L), the contents of H2S in biogas were evidently decreased in the digesters with different initial sulfate concentrations (0-1000 mg/L). After the anaerobic digestion, the removed sulfur was mostly deposited on the surface of limonite. A possible mechanism of H2S control in biogas by limonite was proposed preliminarily, including adsorption, FeS precipitation, and Fe (III) oxidation. The results demonstrated that limonite was a promising in situ desulfurizer for controlling H2S in biogas with low cost and high efficiency.

  20. Research about reactor operator's personability characteristics and performance

    Energy Technology Data Exchange (ETDEWEB)

    Wei Li; He Xuhong; Zhao Bingquan [Tsinghua Univ., Institute of Nuclear Energy Technology, Beijing (China)

    2003-03-01

    To predict and evaluate the reactor operator's performance by personality characteristics is an important part of reactor operator safety assessment. Using related psychological theory combined with the Chinese operator's fact and considering the effect of environmental factors to personality analysis, paper does the research about the about the relationships between reactor operator's performance and personality characteristics, and offers the reference for operator's selection, using and performance in the future. (author)

  1. Improved biogas production from rice straw by co-digestion with kitchen waste and pig manure.

    Science.gov (United States)

    Ye, Jingqing; Li, Dong; Sun, Yongming; Wang, Guohui; Yuan, Zhenhong; Zhen, Feng; Wang, Yao

    2013-12-01

    In order to investigate the effect of feedstock ratios in biogas production, anaerobic co-digestions of rice straw with kitchen waste and pig manure were carried out. A series of single-stage batch mesophilic (37±1 °C) anaerobic digestions were performed at a substrate concentration of 54 g/L based on volatile solids (VS). The results showed that the optimal ratio of kitchen waste, pig manure, and rice straw was 0.4:1.6:1, for which the C/N ratio was 21.7. The methane content was 45.9-70.0% and rate of VS reduction was 55.8%. The biogas yield of 674.4 L/kg VS was higher than that of the digestion of rice straw or pig manure alone by 71.67% and 10.41%, respectively. Inhibition of biogas production by volatile fatty acids (VFA) occurred when the addition of kitchen waste was greater than 26%. The VFA analysis showed that, in the reactors that successfully produced biogas, the dominant intermediate metabolites were propionate and acetate, while they were lactic acid, acetate, and propionate in the others.

  2. MODERN BIOGAS TECHNOLOGIES

    Directory of Open Access Journals (Sweden)

    Yu. I. Sidorov

    2013-02-01

    Full Text Available The modern technical level of biogas technologies is considered, in particular in Ukraine. It is shown that in Ukraine the level of introduction of these technologies remains unsatisfactory. The main reason of such state is absence of the government program of development of sufficiently not profitable biogas industry, which again depends on availability of investment facilities including the state one. On the example of the company’s data Zorg Biogas AG, which is dominant in Ukraine among the foreign ones that offer their products using the technique of the net present value — NPV — it is shown insolvency of functioning of profitable biogas power plants. A conclusion is done about the necessity of orientation on own development in area of biogas technologies, State support and intensive technologies. The world level of modern intensive biogas technologies, in particular the use of the cogeneration plants.

  3. Biogenic hydrogen conversion of de-oiled jatropha waste via anaerobic sequencing batch reactor operation: process performance, microbial insights, and CO2 reduction efficiency.

    Science.gov (United States)

    Kumar, Gopalakrishnan; Lin, Chiu-Yue

    2014-01-01

    We report the semicontinuous, direct (anaerobic sequencing batch reactor operation) hydrogen fermentation of de-oiled jatropha waste (DJW). The effect of hydraulic retention time (HRT) was studied and results show that the stable and peak hydrogen production rate of 1.48 L/L ∗ d and hydrogen yield of 8.7 mL H2/g volatile solid added were attained when the reactor was operated at HRT 2 days (d) with a DJW concentration of 200 g/L, temperature 55 °C, and pH 6.5. Reduced HRT enhanced the production performance until 1.75 d. Further reduction has lowered the process efficiency in terms of biogas production and hydrogen gas content. The effluent from hydrogen fermentor was utilized for methane fermentation in batch reactors using pig slurry and cow dung as seed sources. The results revealed that pig slurry was a feasible seed source for methane generation. Peak methane production rate of 0.43 L CH4/L ∗ d and methane yield of 20.5 mL CH4/g COD were observed at substrate concentration of 10 g COD/L, temperature 30 °C, and pH 7.0. PCR-DGGE analysis revealed that combination of cellulolytic and fermentative bacteria were present in the hydrogen producing ASBR.

  4. Biogenic Hydrogen Conversion of De-Oiled Jatropha Waste via Anaerobic Sequencing Batch Reactor Operation: Process Performance, Microbial Insights, and CO2 Reduction Efficiency

    Directory of Open Access Journals (Sweden)

    Gopalakrishnan Kumar

    2014-01-01

    Full Text Available We report the semicontinuous, direct (anaerobic sequencing batch reactor operation hydrogen fermentation of de-oiled jatropha waste (DJW. The effect of hydraulic retention time (HRT was studied and results show that the stable and peak hydrogen production rate of 1.48 L/L*d and hydrogen yield of 8.7 mL H2/g volatile solid added were attained when the reactor was operated at HRT 2 days (d with a DJW concentration of 200 g/L, temperature 55°C, and pH 6.5. Reduced HRT enhanced the production performance until 1.75 d. Further reduction has lowered the process efficiency in terms of biogas production and hydrogen gas content. The effluent from hydrogen fermentor was utilized for methane fermentation in batch reactors using pig slurry and cow dung as seed sources. The results revealed that pig slurry was a feasible seed source for methane generation. Peak methane production rate of 0.43 L CH4/L*d and methane yield of 20.5 mL CH4/g COD were observed at substrate concentration of 10 g COD/L, temperature 30°C, and pH 7.0. PCR-DGGE analysis revealed that combination of celluloytic and fermentative bacteria were present in the hydrogen producing ASBR.

  5. Polyphasic Analyses of Methanogenic Archaeal Communities in Agricultural Biogas Plants▿

    OpenAIRE

    Nettmann, E.; Bergmann, I.; Pramschüfer, S.; Mundt, K; Plogsties, V.; Herrmann, C.; Klocke, M.

    2010-01-01

    Knowledge of the microbial consortia participating in the generation of biogas, especially in methane formation, is still limited. To overcome this limitation, the methanogenic archaeal communities in six full-scale biogas plants supplied with different liquid manures and renewable raw materials as substrates were analyzed by a polyphasic approach. Fluorescence in situ hybridization (FISH) was carried out to quantify the methanogenic Archaea in the reactor samples. In addition, quantitative r...

  6. Environmental perspectives on using cast seaweed for biogas production

    DEFF Research Database (Denmark)

    Fredenslund, Anders Michael; Møller, Henrik Bjarne; Christensen, Thomas Budde

    Solrød Municipality, Denmark is working towards building a biogas plant utilizing locally available organic wastes including cast seaweed, which is collected each year, since the local inhabitants see this material as a nuisance. A preliminary study suggested favorable conditions for contstructing...... a mixed substrate biogas plant. Continuously fed reactor experiments showed that the intended mix of substrate including cast seaweed could be used as raw material for a biogas plant in thermophilic operation. The environmental analysis suggests existence of several positive benefits of utilizing cast...

  7. Energy from Biomass - Comparision of biogas production at ambient temperature and at mesophilic temperature in semicontenous anaerobic digester using vegetable market waste

    Directory of Open Access Journals (Sweden)

    Dhanalakshmi Sridevi V.

    2014-03-01

    Full Text Available Studies are conducted in semicontinuous anaerobic reactors of 2 L Capacity with effective volume of 1.5 L. Experiments were carried out in the mesophilic temperature range maintained at 35°C in a thermostat, and parallel experiments were performed at ambient temperature on biogas production from the month of Februray to August. The reactors were operated with an organic loading rate of 0.5 gVS/L/d with 25 days HRT. The feed stock used for the study was vegetable market waste obtained from Koyambedu vegetable market. The specific biogas production was found to be 0.530 L gVS add-1 for the reactor operated at mesophilic temperature and in the range of 0.431 to 0.732 L gVSadd -1 for the reactor operated in the ambient temperature condition from the month of February to August. The daily biogas production was found to be similar (approximately 350 mL/d when reactors were operated at mesophilic and ambient temperature except for the period of May and June wherein higher amount of daily biogas production (472 and 529 mL/d was observed in the reactor operated at ambient temperature. The ratio of total VFA and alkalinity and propionic acid to acetic acid (PA/AA was found to be in the range of 0.25 – 0.4 and 0.34 - 1.38 during the operation of the reactor for the entire period, which was within the range reported for digester stability.

  8. Biogas Production from Vinasse

    DEFF Research Database (Denmark)

    de Souza Moraes, Bruna; Triolo, Jin Mi; Pulido Lecona, Vanessa

    2014-01-01

    In many developing countries, simple biogas digesters are used to produce energy for domestic purposes from anaerobic digestion of animal manure. We developed a simple, one-dimensional (1-D), thermal model with easily-available input data for unheated, unstirred, uninsulated, fixed-dome digesters...... buried in the soil to study heat transfer between biogas digester and its surroundings. The predicted temperatures in the dome, biogas and slurry inside the digester and the resulting biogas production are presented and validated. The model was well able to estimate digester temperature (linear slope...

  9. Basic Data on Biogas

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2012-07-01

    Renewable gases such as biogas and biomethane are considered as key energy carrier when the society is replacing fossil fuels with renewable alternatives. In Sweden, almost 80 % of the fossil fuels are used in the transport sector. Therefore, the focus in Sweden has been to use the produced biogas in this sector as vehicle gas. Basic Data on Biogas contains an overview of production, utilisation, climate effects etc. of biogas from a Swedish perspective. The purpose is to give an easy overview of the current situation in Sweden for politicians, decision makers and interested public. 1.4 TWh of biogas is produced annually in Sweden at approximately 230 facilities. The 135 wastewater treatment plants that produce biogas contribute with around half of the production. In order to reduce the sludge volume, biogas has been produced at wastewater treatment plants for decades. New biogas plants are mainly co-digestion plants and farm plants. The land filling of organic waste has been banned since 2005, thus the biogas produced in landfills is decreasing.

  10. Development of mixed inoculum for methane enriched biogas production.

    Science.gov (United States)

    Singh, Ranjeet; Mandal, S K; Jain, V K

    2010-10-01

    Inocula were collected from four different sources such as Jajmau tannery waste treatment plant (ITW), Jajmau municipal waste treatment (IMW), Unnao distillery (IDW) and a batch reactor, in which the sludge of a field scale biogas reactor was added to cow dung slurry to develop inoculum (IBS). A combination of these mixed inocula were used for biogas production at 35°C in laboratory scale reactor (10 L capacity) and the average yield of biogas (0.547 Lg(-1) volatile solid (VS)) and methane (0.323 Lg(-1)VS) in 41 d was higher in case of mixed inoculum IMW (1) (IMW+IBS), with maximum methane content in biogas (68% during 27-30 d), as compared to other mixed inocula as well as control i.e. ITW (1) (ITW+IBS), IDW(1) (IDW+IBS) and IBS. The corresponding yields of gas were biogas (0.505, 0.536 and 0.456 Lg(-1)VS), methane (0.288, 0.305, and 0.245 Lg(-1)VS) where as, the corresponding maximum methane content in biogas was 62% during 29-33d, 64% during 29-33 d and 62% during 27-29 d in ITW(1), IDW(1) and IBS.

  11. The Improvement of Carburater Efficiency Using Biogas-based Venturi

    Directory of Open Access Journals (Sweden)

    Lasmi Ni Ketut

    2016-01-01

    Full Text Available The elimination of the fossil fuel subsidy by the Indonesian government has caused an increase in fuel prices, and a solution to find a relatively cheap and environmentally friendly alternative energy is needed. Biogas is one of the sources of renewable energy that has a potential to be developed, especially in farming area where the abundant animal excrement is not yet optimally used and causes environmental problems. Addressing this issue, we have developed an innovation by making a biogas and air mixer instrument through venturi pipe, using the basic theory of fluid mechanism in order to increase the use of biogas as an electricity source. Usually, biogas-based electric generators use dual fuel system such as fossil fuel and biogas to perform combustion due to the low octane contained in the biogas. By replacing the readily available manufactured venturi with the modified venturi, optimal combustion can be reached with using only single fuel of biogas. The results of the experiments show that the biogas debit on carburetor increases from 13 to 439 watts consuming biogas fuel from 0.22 to 4.96 liter/minute, respectively. The amount of combusted biogas depends on the value of the load power. Within the scope of our results, the maximum voltage reached is about 211.13 – 211.76 volts which is feasible to use for 220 volts electrical appliances

  12. Continuous biogas production from fodder beet silage as sole substrate

    Energy Technology Data Exchange (ETDEWEB)

    Scherer, P.A.; Dobler, S.; Rohardt, S. [University of Applied Sciences, Hamburg (Germany). Research Centre of Environmental Bioengineering and Applied Biotechnology; Loock, R.; Buettner, B.; Noeldeke, P.; Brettschuh, A. [Loock Environmental Technologies, Hamburg (Germany)

    2003-07-01

    Since April 2000 a two-step anaerobic plant with two subsequent 500 m{sup 3} reactors has been producing biogas from fodder beet silage (pH 4.1) as the sole substrate. The plant is located at Kirchlengern near Bielefeld, Germany. Initially the reactors were inoculated with swine manure at 37{sup o}C. After a start-up phase the process was sustained at pH 7.5-8.0 by feeding with the silage as sole substrate twice a day. Parallel to the biogas plant at Kirchlengern four one-step laboratory reactors were continuously driven at temperatures of 37{sup o}C, 45{sup o}C, 60{sup o}C and 65{sup o}C. They were fed with the same silage, but only once per day (one impulse). The organic loading rate (OLR) was adjusted to 3.9 g volatile solids (VS)/(l*d) with a concomitant hydraulic retention time (HRT) of 27 d. There was no problem with starting the reactors, but after 86 days the volumetric gas production of the 65{sup o}C reactor ceased and a high amount of approximately 130 mM propionate could be determined. By decreasing the temperature down to 60{sup o}C a stable reactor performance was recovered for a period of at least 250 further days. During impulse feeding it was observed that the quickest recovery of gas production could be observed at 37{sup o}C or at 45{sup o}C. Recovery of 75% gas volume (related to the value before or after impulse feeding) was obtained after 5.5 and 7.5 h of feeding time point whereas the 60{sup o}C reactor needed 16 h. Slight significant differences were seen in the spectrum of volatile fatty acids (VFA) reaching at 37{sup o} or 45{sup o}C its maximum with 10-30 mM total VFA at 2-3 h after feeding. After this the VFA level declined to nearly zero (except for the 60{sup o}C reactor). Therefore the 37{sup o}C reactor was favoured. A double experiment with a second 37{sup o}C reactor was started by a somewhat different inoculation procedure from the remaining 3 reactors, but revealed similar results. By increasing the temperature no significantly

  13. Polyphasic analyses of methanogenic archaeal communities in agricultural biogas plants.

    Science.gov (United States)

    Nettmann, E; Bergmann, I; Pramschüfer, S; Mundt, K; Plogsties, V; Herrmann, C; Klocke, M

    2010-04-01

    Knowledge of the microbial consortia participating in the generation of biogas, especially in methane formation, is still limited. To overcome this limitation, the methanogenic archaeal communities in six full-scale biogas plants supplied with different liquid manures and renewable raw materials as substrates were analyzed by a polyphasic approach. Fluorescence in situ hybridization (FISH) was carried out to quantify the methanogenic Archaea in the reactor samples. In addition, quantitative real-time PCR (Q-PCR) was used to support and complete the FISH analysis. Five of the six biogas reactors were dominated by hydrogenotrophic Methanomicrobiales. The average values were between 60 to 63% of archaeal cell counts (FISH) and 61 to 99% of archaeal 16S rRNA gene copies (Q-PCR). Within this order, Methanoculleus was found to be the predominant genus as determined by amplified rRNA gene restriction analysis. The aceticlastic family Methanosaetaceae was determined to be the dominant methanogenic group in only one biogas reactor, with average values for Q-PCR and FISH between 64% and 72%. Additionally, in three biogas reactors hitherto uncharacterized but potentially methanogenic species were detected. They showed closest accordance with nucleotide sequences of the hitherto unclassified CA-11 (85%) and ARC-I (98%) clusters. These results point to hydrogenotrophic methanogenesis as a predominant pathway for methane synthesis in five of the six analyzed biogas plants. In addition, a correlation between the absence of Methanosaetaceae in the biogas reactors and high concentrations of total ammonia (sum of NH(3) and NH(4)(+)) was observed.

  14. Dynamic biogas upgrading based on the Sabatier process

    DEFF Research Database (Denmark)

    Jurgensen, Lars; Ehimen, Ehiazesebhor Augustine; Born, Jens;

    2015-01-01

    This study aimed to investigate the feasibility of substitute natural gas (SNG) generation using biogas from anaerobic digestion and hydrogen from renewable energy systems. Using thermodynamic equilibrium analysis, kinetic reactor modeling and transient simulation, an integrated approach...... for the operation of a biogas-based Sabatier process was put forward, which was then verified using a lab scale heterogenous methanation reactor. The process simulation using a kinetic reactor model demonstrated the feasibility of the production of SNG at gas grid standards using a single reactor setup. The Wobbe...... index, CO2 content and calorific value were found to be controllable by the H2/CO2 ratio fed the methanation reactor. An optimal H2/CO2 ratio of 3.45–3.7 was seen to result in a product gas with high calorific value and Wobbe index. The dynamic reactor simulation verified that the process start...

  15. Progress in biogas. Biogas production from agricultural biomass and organic residues. Pt. 1 and 2. Proceedings (oral presentations and poster presentations); Fortschritt beim Biogas. Biogas aus landwirtschaftlicher Biomasse and organischen Reststoffen. T. 1 und 2. Tagungsband. Vortraege and Poster

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2007-07-01

    population social level raising; (20) Production of biogas with grassilage - when is this profitable?; (21) Biogas: Opportunity or threat for the agriculture; (22) Country report Cameroon; (23) Fruit wastes bioconversion for anaerobic co-digestion with pig manure. Process development for the recycling in decentralised farm scale plants; (24) A parameter estimation protocol for anaerobic digestion; (25) BABIU - a new process for production of biomethane from biogas; (26) Dry fermentation of organic wastes; (27) Biological production of hydrogen from agricultural raw materials and residual materials with subsequent methane step; (28) Two phase continuous digestion of solid manure on-farm; (29) Investigation and development of an optimal process of fermenentation of grassilage by a two-phase process operation; (30) Technical weak points at biogas plants - occasions, effects and measures; (31) Plant safety - a substantial component according to permission and availability of biogas plants; (32) Analysis and evaluation of alternative concepts of the energetic use of biogas and other biogenous gases; (33) Gas-side bundling of some biogas plants, gas processing and gas feeding; (34) Technical and economical demands to biogas production for feeding into the HD grid; (35) Thinking about the use of biogas from the view of heat utilization - development of concepts for bioenergy villages; (36) Biogas cogeneration plant in the practice: Behaviour of emission and performance; (37) The future of biogas in Europe: Visions and targets until 2020; (38) Two-stage dry-wet-fermentation - optimization of the hydrolysis for a short space-time-yields; (39) Manure-free fermentation of renewable raw materials; (40) Quantification of different microbial population in termophilic-dry anaerobic digestion; (41) The use of hydrolytic enzymes in agricultural biogas production; (42) A contribution to mobile online gas diagnostics according to the efficiency of biogas plants; (43) Genetic &apos

  16. Farm Biogas Handbook; Gaardsbiogashandbok

    Energy Technology Data Exchange (ETDEWEB)

    Christensson, Kjell; Bjoernsson, Lovisa; Dahlgren, Stefan; Eriksson, Peter; Lantz, Mikael; Lindstroem, Johanna; Mickelaaker, Maria

    2009-04-15

    A very large share of the total raw material potential for biogas production will be found within the agriculture. The raw material potential of manure in Sweden amounts to 4 - 6 TWh. Within the agriculture there is moreover a big potential in the form of residues from plant cultivation and non-food crops (approximately 7 TWh) that can to be used for biogas production. The potential for biogas production from only residues and manure is around 8-10 TWh. An increased biogas production within the agriculture would give significant environmental effects. Among other things manure, that today is leaking methane gas to the atmosphere, can be fermented, and trough this process the methane losses will be reduced. When the produced biogas replaces fossil fuel, an overall environmental effect will be reached, that is highly significant. This manual deals with biogas plants for agriculture and such plants that do not have extensive transports of different raw materials, as manure, wastes etc. One of the starting points for this manual's set-up is a course plan that Biogas Syd made for the courses they give to farmers, advisors and others. The manual illustrates important aspects in planning and construction of biogas plants, from raw material and technology to dimensioning of plant, use of biogas and planning of local gas grids. We also think it is important to illustrate the legislation that encompasses construction work and operation of a biogas plant. Investment costs are also illustrated, but the book does not give any extensive economic calculations, since we believe that such calculations need their own manual in the form of calculation examples, based on various conditions. The final section is called 'Biogas on farm - from idea to reality' where the entire process from analysis and pre-planning to monitoring and control of plant during operation is briefly described

  17. Desempenho de um aquecedor de água a biogás Performance of a water heater by biogas

    Directory of Open Access Journals (Sweden)

    Fabio M. da Silva

    2005-12-01

    Full Text Available Estudos foram desenvolvidos para dimensionar e adaptar o injetor do queimador principal de um aquecedor de água tipo acumulação de 75 L. O diâmetro do injetor foi redimensionado em função da pressão de serviço de 100 mm H2O e poder calorífico inferior do biogás de 21.600 kJ m-3 n, garantindo a manutenção da potência calorífica do equipamento de 20.900 kJ h-1. Os resultados demonstraram que o queimador adaptado operou com biogás adequadamente, com chama estável. A eficiência média do aquecedor foi de 68%, para ganho térmico de 36,7 ºC, correspondendo à temperatura final da água igual a 62,7 ºC, sendo consumido 0,796 m³n de biogás, aquecendo 75 L de água em 72 minutos.Studies had been developed to project and to adapt the injector of the main burner of water heater accumulated type of 75 L. The diameter of the injector was project in function of the pressure of service of 100 mm H2O and inferior calorific power of biogas of 21,600 kJ m-3 n, having guaranteed the maintenance of the calorific power of the equipment of 20,900 of kJ h-1 .The results had demonstrated that the adapted burner to operate with biogas operated adequately with a steady flame. The average efficiency of the heater was of 68%, for a thermal profit of 36.7 ºC, corresponding the final temperature of the water of 62.7 ºC being consumed 0.796 m³ n of biogas, heating 75 L of water in 72 minutes.

  18. Boosting biogas yield of anaerobic digesters by utilizing concentrated molasses from 2nd generation bioethanol plant

    Energy Technology Data Exchange (ETDEWEB)

    Sarker, Shiplu [Department of Renewable Energy, Faculty of Engineering and Science, University of Agder, Grimstad-4879 (Norway); Moeller, Henrik Bjarne [Department of Biosystems Engineering, Faculty of Science and Technology, Aarhus University, Research center Foulum, Blichers Alle, Post Box 50, Tjele-8830 (Denmark)

    2013-07-01

    Concentrated molasses (C5 molasses) from 2nd generation bioethanol plant has been investigated for enhancing productivity of manure based digesters. A batch study at mesophilic condition (35+- 1 deg C) showed the maximum methane yield from molasses as 286 LCH4/kgVS which was approximately 63% of the calculated theoretical yield. In addition to the batch study, co-digestion of molasses with cattle manure in a semi-continuously stirred reactor at thermophilic temperature (50+- 1 deg C) was also performed with a stepwise increase in molasses concentration. The results from this experiment revealed the maximum average biogas yield of 1.89 L/L/day when 23% VSmolasses was co-digested with cattle manure. However, digesters fed with more than 32% VSmolasses and with short adaptation period resulted in VFA accumulation and reduced methane productivity indicating that when using molasses as biogas booster this level should not be exceeded.

  19. Boosting biogas yield of anaerobic digesters by utilizing concentrated molasses from 2nd generation bioethanol plant

    Directory of Open Access Journals (Sweden)

    Shiplu Sarker, Henrik Bjarne Møller

    2013-01-01

    Full Text Available Concentrated molasses (C5 molasses from 2nd generation bioethanol plant has been investigated for enhancing productivity of manure based digesters. A batch study at mesophilic condition (35±1C showed the maximum methane yield from molasses as 286 LCH4/kgVS which was approximately 63% of the calculated theoretical yield. In addition to the batch study, co-digestion of molasses with cattle manure in a semi-continuously stirred reactor at thermophilic temperature (50±1°C was also performed with a stepwise increase in molasses concentration. The results from this experiment revealed the maximum average biogas yield of 1.89 L/L/day when 23% VSmolasses was co-digested with cattle manure. However, digesters fed with more than 32% VSmolasses and with short adaptation period resulted in VFA accumulation and reduced methane productivity indicating that when using molasses as biogas booster this level should not be exceeded.

  20. Horse dung waste utilization as a household energy resource and estimation of biogas production

    Science.gov (United States)

    Umbara, Rian F.; Sumaryatie, Erni D.; Kirom, M. R.; Iskandar, Reza F.

    2013-09-01

    Horses are still used as traditional transportation in Soreang, West Java. About 6-7 horses can produce 25-30 kg of dung every day. Horse dung can produce biogas that can be used as an energy resource. A biogas reactor with capacity of 4 m3 has been built in Soreang. The reactor is filled with a mixture of 50 kg of horse dung and 100 liters of water every two days. This research was conducted to observe the quality of biogas produced from the reactor and to estimate the volume of biogas produced per day. The observation of daily biogas production conducted in 22 days. Laboratory tests showed that the composition of gases contained in the produced biogas consists of 56.53% of CH4, 26.98% of CO2, 12.35% of N2, 4.13% of O2, and 0.007% of H2. Daily biogas production data indicate a stationary trend. A moving average time series model is used to model the data. Using the model, it is estimated that the reactor can produce 0.240112 m3 of biogas per day, which is sufficient to meet the energy needs of a household.

  1. A study on the establishment of component/equipment performance criteria considering Heavy Water Reactor characteristics

    Energy Technology Data Exchange (ETDEWEB)

    Chang, Keun Sun; Kwon, Young Chul; Lee, Min Kyu; Lee, Yun Soo [Sunmoon Univ., Asan (Korea, Republic of); Chang, Seong Hoong; Ryo, Chang Hyun [Korea Advanced Institute of Science and Technology, Taejon (Korea, Republic of); Kim, Soong Pyung; Hwnag, Jung Rye; Chung, Chul Kee [Chosun Univ., Gwangju (Korea, Republic of)

    2002-03-15

    Foreign and domestic technology trends, regulatory requirements, design and researches for heavy water reactors are analyzed. Safety design guides of Canada industry and regulatory documents and consultative documents of Canada regulatory agency are reviewed. Applicability of MOST guidance 16 Revision 'guidance for technical criteria of nuclear reactor facility' is reviewed. Specific performance criteria are established for components and facilities for heavy water reactor.

  2. Serial CSTR digester configuration for improving biogas production from manure.

    Science.gov (United States)

    Boe, Kanokwan; Angelidaki, Irini

    2009-01-01

    A new configuration of manure digesters for improving biogas production has been investigated in laboratory scale. A single thermophilic continuous-flow stirred tank reactor (CSTR) operated with a hydraulic retention time (HRT) of 15 days was compared to a serial CSTR configuration with volume distribution ratio of 80/20 and 90/10, and total HRT of 15 days. The results showed that the serial CSTR could obtain 11% higher biogas yield compared to the single CSTR. The increased biogas yield in the serial CSTR was mainly from the second reactor, which accounted for 16% and 12% of total biogas yield in the 90/10 and 80/20 configuration, respectively. VFA concentration in the serial CSTR was high in the first reactor but very low in the second reactor. The results from organic pulse load test showed that the second reactor in serial CSTR helped utilizing VFA produced from overloading in the first reactor, which improved the effluent quality and conversion efficiency of the serial CSTR.

  3. Upscaling of an electronic nose for completely stirred tank reactor stability monitoring from pilot-scale to real-scale agricultural co-digestion biogas plant.

    Science.gov (United States)

    Adam, Gilles; Lemaigre, Sébastien; Goux, Xavier; Delfosse, Philippe; Romain, Anne-Claude

    2015-02-01

    This study investigated the use of an electronic nose for on-line anaerobic reactor state monitoring at the pilot-scale level and then upscaling to the full-scale level. E-nose indicator was compared to classical state indicators such as pH, alkalinity, volatile fatty acids concentration and to other gas phase compounds. Multivariate statistical process control method, based on principal component analysis and the Hotelling's T(2) statistics was used to derive an indicator representative of the reactor state. At the pilot-scale level, the e-nose indicator was relevant and could distinguish 3 process states: steady-state, transient and collapsing process. At the full-scale level, the e-nose indicator could provide the warning of the major disturbance whereas two slight disturbances were not detected and it gave one major false alarm. This work showed that gas phase relation with anaerobic process should be deeper investigated, as an e-nose could indicate the reactor state, focusing on the gas phase.

  4. Biogas production from Eichhornia crassipes aquatic plant; Producao de biogas a partir da planta aquatica Eichhornia crassipes

    Energy Technology Data Exchange (ETDEWEB)

    Pereira, Roberto Guimaraes; Silva, Jose Goncalves da; Fernandes Filho, Jorge; Pereira, Maria Cristina Duarte Eiras [Universidade Federal Fluminense (UFF), Niteroi, RJ (Brazil). Dept. de Engenharia Mecanica. Programa de Pos-Graduacao em Engenharia Mecanica]. E-mail: temrobe@vm.uff.br; Melo, Ricardo Bichara de [Light Servicos de Eletricidade S.A., Rio de Janeiro, RJ (Brazil)]. E-mail: rbmelo@light.com.br

    2004-07-01

    Virtually all plants and waste plants and animals may in some way be used as an energy source. The anaerobic digestion of these materials is an option, resulting in the biogas. Besides the gas obtained in the process, is produced, inside the biodigester, an excellent fertilizer. The aquatic plant Eichhornia crassipes is found in large quantities in various water bodies, such as reservoirs, lakes and ponds, becoming mostly often a big problem and it is necessary its systematic removal of water. The bench biodigester used in the experiment of biodigestion of aquatic plants is composed of a reactor containing the biomass, where the biogas is produced, and a reservoir to monitor the production of biogas. The reactor is located within a receptacle containing water that can be heated by an electrical resistance, with the purpose of maintaining the temperature inside the reactor around 35 deg C. The results of analysis of gas of the reactor made in a gas chromatograph to CG MASTER of double ionization detector with a flame and thermal conductivity, show a percentage of 50% of methane in the biogas. The process of biodigestion of aquatic plant Eichhornia crassipes shows potential to obtain biogas, with considerable levels of methane in order to make its exploitation. Also, were analyzed the biomass in the biodigester for determination of humid, total organic matter, mineral and organic carbon residue.

  5. Biodigestion of the aquatics plants mixtures and biogas production; Biodigestao de misturas de plantas aquaticas e producao de biogas

    Energy Technology Data Exchange (ETDEWEB)

    Pereira, Roberto Guimaraes; Abreu, Fernando Luiz Barbuda de; Fernandes Filho, Jorge; Pereira, Maria Cristina Duarte Eiras [Universidade Federal Fluminense (UFF), Niteroi, RJ (Brazil). Dept. de Engenharia Mecanica. Programa de Pos-Graduacao em Engenharia Mecanica]. E-mail: temrobe@vm.uff.br; Melo, Ricardo Bichara de [Light Servicos de Eletricidade S.A., Rio de Janeiro, RJ (Brazil). Gerencia de Estudos e Gestao de Geracao]. E-mail: rbmelo@light.com.br

    2004-07-01

    Several systems of generating electricity using water storage reservoirs. One problem that occurs constantly in these reservoirs is the accumulation of aquatic plants, such as Eichhornia crassipes, Eichhornia azurea, Pistia stratiotes and Salvinia that may cause serious problems for the system. Periodically, the biomass must be removed and disposed of appropriate form, so that does not cause contamination of soil, groundwater or allowing the proliferation of vectors. One possible destination is the use of biomass in a process of biodigestion, resulting in biogas. The bench of biodigester used in the experiment of biodigestion of aquatic plants is composed of a reactor containing the biomass, where the biogas is produced and a reservoir for the monitoring the production of biogas. The reactor is located inside a container containing water that can be heated by an electrical resistance, with the aim of maintaining the temperature inside the reactor around 35 deg C. The results of analysis of gas of the reactor was obtained using a gas chromatograph to CG MASTER of double ionization detector with a flame and thermal conductivity. These results show a percentage of 50% of methane in the biogas. Also, were analyzed the biomass in the biodigester for determination of humidity, total organic matter, waste mineral and organic carbon. The process of biodigestion of the mixture of aquatic plants: Eichhornia crassipes, Eichhornia azurea and Pistia stratiotes and Salvinia shows potential for obtaining biogas, with considerable levels of methane, in order to facilitate its recovery.

  6. An immobilized cell reactor with simultaneous product separation. II. Experimental reactor performance.

    Science.gov (United States)

    Dale, M C; Okos, M R; Wankat, P C

    1985-07-01

    The simultaneous separation of volatile fermentation products from product-inhibited fermentations can greatly increase the productivity of a bioreactor by reducing the product concentration in the bioreactor, as well as concentrating the product in an output stream free of cells, substrate, or other feed impurities. The Immobilized Cell Reactor-Separator (ICRS) consists of two column reactors: a cocurrent gas-liquid "enricher" followed by a countercurrent "stripper" The columns are four-phase tubular reactors consisting of (1) an inert gas phase, (2) the liquid fermentation broth, (3) the solid column internal packing, and (4) the immobilized biological catalyst or cells. The application of the ICRS to the ethanol-from-whey-lactose fermentation system has been investigated. Operation in the liquid continuous or bubble flow regime allows a high liquid holdup in the reactor and consequent long and controllable liquid residence time but results in a high gas phase pressure drop over the length of the reactor and low gas flow rates. Operation in the gas continuous regime gives high gas flow rates and low pressure drop but also results in short liquid residence time and incomplete column wetting at low liquid loading rates using conventional gas-liquid column packings. Using cells absorbed to conventional ceramic column packing (0.25-in. Intalox saddles), it was found that a good reaction could be obtained in the liquid continuous mode, but little separation, while in the gas continuous mode there was little reaction but good separation. Using cells sorbed to an absorbant matrix allowed operation in the gas continuous regime with a liquid holdup of up to 30% of the total reactor volume. Good reaction rates and product separation were obtained using this matrix. High reaction rates were obtained due to high density cell loading in the reactor. A dry cell density of up to 92 g/L reactor was obtained in the enricher. The enricher ethanol productivity ranged from 50 to 160

  7. Recent performance experience with US light water reactor self-actuating safety and relief valves

    Energy Technology Data Exchange (ETDEWEB)

    Hammer, C.G.

    1996-12-01

    Over the past several years, there have been a number of operating reactor events involving performance of primary and secondary safety and relief valves in U.S. Light Water Reactors. There are several different types of safety and relief valves installed for overpressure protection of various safety systems throughout a typical nuclear power plant. The following discussion is limited to those valves in the reactor coolant systems (RCS) and main steam systems of pressurized water reactors (PWR) and in the RCS of boiling water reactors (BWR), all of which are self-actuating having a setpoint controlled by a spring-loaded disk acting against system fluid pressure. The following discussion relates some of the significant recent experience involving operating reactor events or various testing data. Some of the more unusual and interesting operating events or test data involving some of these designs are included, in addition to some involving a number of similar events and those which have generic applicability.

  8. Biogas Production Using Anaerobic Biodigester from Cassava Starch Effluent

    Directory of Open Access Journals (Sweden)

    S. Sunarso

    2010-12-01

    Full Text Available IKMs’ factory activity in Margoyoso produces liquid and solid wastes. The possible alternative was to use the liquid effluent as biogas raw material. This study focuses on the used of urea, ruminant, yeast, microalgae, the treatment of gelled and ungelled feed for biogas production, pH control during biogas production using buffer Na2CO3, and feeding management in the semi-continuous process of biogas production that perform at ambient temperature for 30 days. Ruminant bacteria, yeast, urea, and microalgae was added 10% (v/v, 0.08% (w/v, 0.04% (w/v, 50% (v/v of mixing solution volume, respectively. The pH of slurry was adjusted with range 6.8-7.2 and was measured daily and corrected when necessary with Na2CO3. The total biogas production was measured daily by the water displacement technique. Biogas production from the ungelling and gelling mixture of cassava starch effluent, yeast, ruminant bacteria, and urea were 726.43 ml/g total solid and 198 ml/g total solid. Biogas production from ungelling mixture without yeast was 58.6 ml/g total solid. Biogas production from ungelling mixture added by microalgae without yeast was 58.72 ml/g total solid and that with yeast was 189 ml/g total solid. Biogas production from ungelling mixture of cassava starch effluent, yeast, ruminant bacteria, and urea in semi-continuous process was 581.15 ml/g total solid. Adding of microalgae as nitrogen source did not give significant effect to biogas production. But adding of yeast as substrate activator was very helpful to accelerate biogas production. The biogas production increased after cassava starch effluent and yeast was added. Requirement of sodium carbonate (Na2CO3 to increase alkalinity or buffering capacity of fermenting solution depends on pH-value

  9. Progress in biogas II - Biogas production from agricultural biomass and organic residues. Pt. 1. Proceedings; Progress in Biogas II - Biogasproduktion aus landwirtschaftlicher Biomasse und organischen Reststoffen. T. 1. Tagungsband

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2011-08-12

    biogas production - Methabe yield and energy balance (R. Bolduan); (19) Evaluation of a pre-treatment process for improved methane production from grass silage (A. Orozco); (20) Anaerobic fungi and biogas production (J. Prochazka); (21) Preservation of sugar beets for biogas production (A. Wagner); (22) Fibre, biogas and compost from banana agro-residues (leaves, pseudostem and rachis) by anaerobic digestion in plug flow type digester (H. Chanakya); (23) Extraction of biogas from waste products of he sugarcane industry (J. Rietzler); (24) Practical experiences with the digestion of straw in 2-stage AD plants - Extension of the value chain (W. Danner); (25) Improving biogas production on wastewater treatment plants by co-digestion of grass (D. Klein); (26) Generation of algal biomass for biogas production: energetic and environmental from a Life Cycle Assessment (LCA) perspective (F. Romagnoli); (27) Risk reduction in spreading plant pathogens by anaerobic digestion? First results from laboratory experiments (M. Heiermann); (28) Demand-oriented biogas production for the generation of peak load (R. Wallmann); (29) Investigation of mesophilic and thermophilic bioleaching method in a two-phase anaerobic digestion process (M. Schoenberg): (30) Efficient hydrogen fermentation for 2-stage anaerobic digestion processes: Conversion of sucrose containing substrates (S. Noebauer); (31) Process development of two-phase pressure formation - Influence of gas solubilities (A.-M. Wonneberger); (32) Benefits and limitations when treating liquid pig manure in an anaerobic membrane bioreactor (P. Messerl); (33) Experiences with continuous high-rate thermophilic dry anaerobic digestion of energy crops (L. De Baere); (34) The Sauter-biogas-system: spraying instead of stirring (S. Sauter); (35) Biogas production from raw palm oil mill effluent using a pilot-scale anaerobic hybrid reactor (C. Wangnai); (36) Eta max - the biogas power plant with high biological efficiency (M. Niederbacher); (37

  10. Effect of Sulfur Source on the Performance and Metal Retention of Methanol-Fed UASB Reactors

    NARCIS (Netherlands)

    Zandvoort, M.H.; Hullebusch, van E.D.; Gieteling, J.; Lettinga, G.; Lens, P.N.L.

    2005-01-01

    The effect of a sulfur source on the performance and metal retention of methanol-fed upflow anaerobic sludge bed (UASB) reactors was investigated. For this purpose, two UASB reactors were operated with cobalt preloaded granular sludge (1 mM CoCl2; 30° C; 24 h) at an organic loading rate (OLR) of 5 g

  11. Micro-scale H2-CO2 dynamics in a hydrogenotrophic methanogenic membrane reactor

    DEFF Research Database (Denmark)

    Garcia-Robledo, Emilio; Ottosen, Lars Ditlev Mørck; Voigt, Niels Vinther;

    2016-01-01

    Biogas production is a key factor in a sustainable energy supply. It is possible to get biogas with very high methane content if the biogas reactors are supplied with exogenous hydrogen, and one of the technologies for supplying hydrogen is through gas permeable membranes. In this study the activ......Biogas production is a key factor in a sustainable energy supply. It is possible to get biogas with very high methane content if the biogas reactors are supplied with exogenous hydrogen, and one of the technologies for supplying hydrogen is through gas permeable membranes. In this study...

  12. Biogas in agriculture. Status and prospects. Proceedings; Biogas in der Landwirtschaft. Stand und Perspektiven. Tagungsband

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2011-07-01

    emissions and optimization of the humus balance (Kurt Moeller); (18) Evaluation of greenhouse gases from agricultural biogas plants by means of emission measurements (Jan Liebetrau); (19) Greenhouse gas balances and CO{sub 2}-eq abatement costs of agricultural biogas plants (Ursula Roth); (20) Mixtures of wild plants for production of biogas (Birgit Vollrath); (21) Utilization of straw as a fermentation substrate by means of digestion of straw (Stefan Droege); (22) Biogas from algae, seaweed and seagrass? (Helga Schneider); (23) Common project of farmers and public utilities - Feeding of biogas with amine purification (Johannes Steinhauer); (23) Feeding bio methan from the view of a plant operator (Thomas Balling); (24) Potentials for an optimized and resources carefully delivery of bio methan - Guidelines for a further expansion for biogas utilization (Wolfgang Urban); (25) Repowering of biogas plants (Anton Baumann); (26) Repowering of biogas plants for enhancing the process efficiency (Matthias Effenberger); (27) From troubled kid to star performers - On the repowering of a biogas plant (Hans-Werner Gress). Furthermore, 55 posters were presented.

  13. Improved performance of parallel surface/packed-bed discharge reactor for indoor VOCs decomposition: optimization of the reactor structure

    Science.gov (United States)

    Jiang, Nan; Hui, Chun-Xue; Li, Jie; Lu, Na; Shang, Ke-Feng; Wu, Yan; Mizuno, Akira

    2015-10-01

    The purpose of this paper is to develop a high-efficiency air-cleaning system for volatile organic compounds (VOCs) existing in the workshop of a chemical factory. A novel parallel surface/packed-bed discharge (PSPBD) reactor, which utilized a combination of surface discharge (SD) plasma with packed-bed discharge (PBD) plasma, was designed and employed for VOCs removal in a closed vessel. In order to optimize the structure of the PSPBD reactor, the discharge characteristic, benzene removal efficiency, and energy yield were compared for different discharge lengths, quartz tube diameters, shapes of external high-voltage electrode, packed-bed discharge gaps, and packing pellet sizes, respectively. In the circulation test, 52.8% of benzene was removed and the energy yield achieved 0.79 mg kJ-1 after a 210 min discharge treatment in the PSPBD reactor, which was 10.3% and 0.18 mg kJ-1 higher, respectively, than in the SD reactor, 21.8% and 0.34 mg kJ-1 higher, respectively, than in the PBD reactor at 53 J l-1. The improved performance in benzene removal and energy yield can be attributed to the plasma chemistry effect of the sequential processing in the PSPBD reactor. The VOCs mineralization and organic intermediates generated during discharge treatment were followed by CO x selectivity and FT-IR analyses. The experimental results indicate that the PSPBD plasma process is an effective and energy-efficient approach for VOCs removal in an indoor environment.

  14. Biocatalysis conversion of methanol to methane in an upflow anaerobic sludge blanket (UASB) reactor: Long-term performance and inherent deficiencies.

    Science.gov (United States)

    Lu, Xueqin; Zhen, Guangyin; Chen, Mo; Kubota, Kengo; Li, Yu-You

    2015-12-01

    Long-term performance of methanol biocatalysis conversion in a lab-scale UASB reactor was evaluated. Properties of granules were traced to examine the impact of methanol on granulation. Methanolic wastewater could be stably treated during initial 240d with the highest biogas production rate of 18.6 ± 5.7 L/Ld at OLR 48 g-COD/Ld. However, the reactor subsequently showed severe granule disintegration, inducing granule washout and process upsets. Some steps (e.g. increasing influent Ca(2+) concentration, etc.) were taken to prevent rising dispersion, but no clear improvement was observed. Further characterizations in granules revealed that several biotic/abiotic factors all caused the dispersion: (1) depletion of extracellular polymeric substances (EPS) and imbalance of protein/polysaccharide ratio in EPS; (2) restricted formation of hard core and weak Ca-EPS bridge effect due to insufficient calcium supply; and (3) simplification of species with the methanol acclimation. More efforts are required to solve the technical deficiencies observed in methanolic wastewater treatment.

  15. Biogas in the agriculture. State of the art. Proceedings; Biogas in der Landwirtschaft. Stand und Perspektiven. Tagungsband

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2009-07-01

    Within the meeting of the Association for Technology and Structures in Agriculture (Darmstadt, Federal Republic of Germany) and the Agency for Renewable Resources (Guelzow, Federal Republic of Germany) between 15th and 16th September, 2009, in Weimar the following lectures were held: (1) Results of the actual biogas measurement II (Peter Weiland); (2) Agitators in biogas plants - Technology with central significance (Kay Rostalski); (3) How much energy is needed by a biogas fermenter? (Ludwig Heinloth); (4) The fermentation concept of Rueckert NatUrgas GmbH (Claus Rueckert, Dominique Pfeufer); (5) Experiences from the construction for the practice of the company MT-Energie GmbH (Bodo Drescher); (6) Fermenter/technology concept of Schmack Biogas AG (Thomas Moeeslinger); (7) Transport of biomass - How much does the logistics of Guelle and Co. cost? (Thore Toews); (8) Which factors determine the efficiency of biogas plants? (Gerd Reinhold); (9) Microbial diversity in biogas reactors in the fermentation of renewable raw materials (Michael Klocke et al.); (10) What do additives and ingredients contribute to the optimisation of the production of biogas? (Udo Hoelker); (11) Process optimisation - An interaction between technology and microbiology (Andreas Gronauer et al.); (12) Emissions at the production of biogas - an analysis if the environmental relevance (Joachim Clemens et al.); (13) Support systems for energy plants - Consequences to soil and environment (Matthias Willms et al.); (14) How ecological is biogas? (Sven Gaertner); (15) Biogas plant - Analysis of construction and operation from licensing view (Hans-Walter Schneichel); (16) Biogas plants - Analysis of construction and operation from contractual legal view (Florian Valentin); (17) Biogasplants - Analysis of construction and operation from remuneration legal view (Helmut Loibl); (18) Process and costs of treatment of residues of fermentation (Sebastian Wulf, Helmut Doehler); (19) How do residues of

  16. Anaerobic digestion foaming in full-scale biogas plants: a survey on causes and solutions.

    Science.gov (United States)

    Kougias, P G; Boe, K; O-Thong, S; Kristensen, L A; Angelidaki, I

    2014-01-01

    Anaerobic digestion foaming is a common operation problem in biogas plants with negative impacts on the biogas plants economy and environment. A survey of 16 Danish full-scale biogas plants on foaming problems revealed that most of them had experienced foaming in their processes up to three times per year. Foaming incidents often lasted from one day to three weeks, causing 20-50% biogas production loss. One foaming case at Lemvig biogas plant has been investigated and the results indicated that the combination of feedstock composition and mixing pattern of the reactor was the main cause of foaming in this case. Moreover, no difference in bacterial communities between the foaming and non-foaming reactors was observed, showing that filamentous bacteria were not the main reason for foaming in this case.

  17. Innovative test method for the estimation of the foaming tendency of substrates for biogas plants.

    Science.gov (United States)

    Moeller, Lucie; Eismann, Frank; Wißmann, Daniel; Nägele, Hans-Joachim; Zielonka, Simon; Müller, Roland A; Zehnsdorf, Andreas

    2015-07-01

    Excessive foaming in anaerobic digestion occurs at many biogas plants and can cause problems including plugged gas pipes. Unfortunately, the majority of biogas plant operators are unable to identify the causes of foaming in their biogas reactor. The occurrence of foaming is often related to the chemical composition of substrates fed to the reactor. The consistency of the digestate itself is also a crucial part of the foam formation process. Thus, no specific recommendations concerning substrates can be given in order to prevent foam formation in biogas plants. The safest way to avoid foaming is to test the foaming tendency of substrates on-site. A possible solution is offered by an innovative foaming test. With the help of this tool, biogas plant operators can evaluate the foaming disposition of new substrates prior to use in order to adjust the composition of substrate mixes.

  18. Reactor

    Science.gov (United States)

    Evans, Robert M.

    1976-10-05

    1. A neutronic reactor having a moderator, coolant tubes traversing the moderator from an inlet end to an outlet end, bodies of material fissionable by neutrons of thermal energy disposed within the coolant tubes, and means for circulating water through said coolant tubes characterized by the improved construction wherein the coolant tubes are constructed of aluminum having an outer diameter of 1.729 inches and a wall thickness of 0.059 inch, and the means for circulating a liquid coolant through the tubes includes a source of water at a pressure of approximately 350 pounds per square inch connected to the inlet end of the tubes, and said construction including a pressure reducing orifice disposed at the inlet ends of the tubes reducing the pressure of the water by approximately 150 pounds per square inch.

  19. Anaerobic digestion of Chinese cabbage waste silage with swine manure for biogas production: batch and continuous study.

    Science.gov (United States)

    Kafle, Gopi Krishna; Bhattarai, Sujala; Kim, Sang Hun; Chen, Lide

    2014-01-01

    The aim of this study was to investigate the potential for anaerobic co-digestion of Chinese cabbage waste silage (CCWS) with swine manure (SM). Batch and continuous experiments were carried out under mesophilic anaerobic conditions (36-38°C). The batch test evaluated the effect of CCWS co-digestion with SM (SM: CCWS=100:0; 25:75; 33:67; 0:100, % volatile solids (VS) basis). The continuous test evaluated the performance of a single stage completely stirred tank reactor with SM alone and with a mixture of SM and CCWS. Batch test results showed no significant difference in biogas yield up to 25-33% of CCWS; however, biogas yield was significantly decreased when CCWS contents in feed increased to 67% and 100%. When testing continuous digestion, the biogas yield at organic loading rate (OLR) of 2.0 g VSL⁻¹ d⁻¹ increased by 17% with a mixture of SM and CCWS (SM:CCWS=75:25) (423 mL g⁻¹ VS) than with SM alone (361 mL g⁻¹ VS). The continuous anaerobic digestion process (biogas production, pH, total volatile fatty acids (TVFA) and TVFA/total alkalinity ratios) was stable when co-digesting SM and CCWS (75:25) at OLR of 2.0 g VSL⁻¹ d⁻¹ and hydraulic retention time of 20 days under mesophilic conditions.

  20. The effect of storage conditions on microbial community composition and biomethane potential in a biogas starter culture.

    Science.gov (United States)

    Hagen, Live Heldal; Vivekanand, Vivekanand; Pope, Phillip B; Eijsink, Vincent G H; Horn, Svein J

    2015-07-01

    A new biogas process is initiated by adding a microbial community, typically in the form of a sample collected from a functional biogas plant. This inoculum has considerable impact on the initial performance of a biogas reactor, affecting parameters such as stability, biogas production yields and the overall efficiency of the anaerobic digestion process. In this study, we have analyzed changes in the microbial composition and performance of an inoculum during storage using barcoded pyrosequencing of bacterial and archaeal 16S ribosomal RNA (rRNA) genes, and determination of the biomethane potential, respectively. The inoculum was stored at room temperature, 4 and -20 °C for up to 11 months and cellulose was used as a standard substrate to test the biomethane potential. Storage up to 1 month resulted in similar final methane yields, but the rate of methane production was reduced by storage at -20 °C. Longer storage times resulted in reduced methane yields and slower production kinetics for all storage conditions, with room temperature and frozen samples consistently giving the best and worst performance, respectively. Both storage time and temperature affected the microbial community composition and methanogenic activity. In particular, fluctuations in the relative abundance of Bacteroidetes were observed. Interestingly, a shift from hydrogenotrophic methanogens to methanogens with the capacity to perform acetoclastic methanogensis was observed upon prolonged storage. In conclusion, this study suggests that biogas inocula may be stored up to 1 month with low loss of methanogenic activity, and identifies bacterial and archaeal species that are affected by the storage.

  1. The Jules Horowitz Reactor - A new High Performance European Material Testing Reactor open to International Users Present Status and Objectives

    Energy Technology Data Exchange (ETDEWEB)

    Iracane, Daniel; Bignan, Gilles [CEA Atomic Energy Commission Saclay Batiment 121- 91191 Gif Sur Yvette (France); Lindbaeck, Jan-Erik; Blomgren, Jan [VATTENFALL AB Nuclear Power Jaemtlandsgatan 99 SE-16287 Stockholm (Sweden)

    2010-07-01

    The development of sustainable nuclear energy requires R and D on fuel and material behaviour under irradiation with a high level of performance in order to meet the needs and challenges for the benefit of industry, research and public bodies. These stakes require a sustainable and secured access to an up-to-date high performance Material Testing Reactor. Following a broad survey within the European Research Area, the international community agreed that the need for Material Test Reactors in support of nuclear power plant safety and operation will continue in the context of sustainable nuclear energy. The Jules Horowitz Reactor project (JHR) copes with this context. JHR is designed as a user facility addressing the needs of the international community. This means: - flexibility with irradiation loops able to reproduce a large variation in operation conditions of different power reactor technologies, - high flux capacity to address Generations II, III, and IV needs. JHR is designed, built and operated as an international user facility because: - Given the maturity and globalization of the industry, domestic tools have no more the required level of economic and technical efficiency. Meanwhile, countries with nuclear energy need an access to high performance irradiation experimental capabilities to support technical skill and guarantee the competitiveness and safety of nuclear energy. - Many research items related to safety or public policy (waste management, etc.) require international cooperation to share costs and benefits of resulting consensus. JHR design is optimised for offering high performance material and fuel irradiation capability for the coming decades. This project is driven and funded by an international consortium gathering vendors, utilities and public stakeholders. This consortium has been set up in March 2007 when the construction began. The construction is in progress and the start of operation is scheduled for 2014. The JHR is a research

  2. Eliminating methanogenic activity in hydrogen reactor to improve biogas production in a two-stage anaerobic digestion process co-digesting municipal food waste and sewage sludge.

    Science.gov (United States)

    Zhu, Heguang; Parker, Wayne; Conidi, Daniela; Basnar, Robert; Seto, Peter

    2011-07-01

    Laboratory scale two-stage anaerobic digestion process model was operated for 280 days to investigate the feasibility to produce both hydrogen and methane from a mixture feedstock (1:1 (v/v)) of municipal food waste and sewage sludge. The maximum hydrogen and methane yields obtained in the two stages were 0.93 and 9.5 mL/mL feedstock. To eliminate methanogenic activity and obtain substantial hydrogen production in the hydrogen reactor, both feedstock and mixed liquor required treatment. The heat treatment (100°C, 10 min) for feedstock and a periodical treatment (every 2-5 weeks, either heating, removal of biomass particles or flushing with air) for mixed liquor were effective in different extent. The methane production in the second stage was significantly improved by the hydrogen production in the first stage. The maximum methane production obtained in the period of high hydrogen production was more than 2-fold of that observed in the low hydrogen production period.

  3. Progress in biogas. Biogas production from agricultural biomass and organic residues. Pt. 1 and 2. Proceedings (oral presentations and poster presentations); Fortschritt beim Biogas. Biogas aus landwirtschaftlicher Biomasse and organischen Reststoffen. T. 1 und 2. Tagungsband. Vortraege and Poster

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2007-07-01

    population social level raising; (20) Production of biogas with grassilage - when is this profitable?; (21) Biogas: Opportunity or threat for the agriculture; (22) Country report Cameroon; (23) Fruit wastes bioconversion for anaerobic co-digestion with pig manure. Process development for the recycling in decentralised farm scale plants; (24) A parameter estimation protocol for anaerobic digestion; (25) BABIU - a new process for production of biomethane from biogas; (26) Dry fermentation of organic wastes; (27) Biological production of hydrogen from agricultural raw materials and residual materials with subsequent methane step; (28) Two phase continuous digestion of solid manure on-farm; (29) Investigation and development of an optimal process of fermenentation of grassilage by a two-phase process operation; (30) Technical weak points at biogas plants - occasions, effects and measures; (31) Plant safety - a substantial component according to permission and availability of biogas plants; (32) Analysis and evaluation of alternative concepts of the energetic use of biogas and other biogenous gases; (33) Gas-side bundling of some biogas plants, gas processing and gas feeding; (34) Technical and economical demands to biogas production for feeding into the HD grid; (35) Thinking about the use of biogas from the view of heat utilization - development of concepts for bioenergy villages; (36) Biogas cogeneration plant in the practice: Behaviour of emission and performance; (37) The future of biogas in Europe: Visions and targets until 2020; (38) Two-stage dry-wet-fermentation - optimization of the hydrolysis for a short space-time-yields; (39) Manure-free fermentation of renewable raw materials; (40) Quantification of different microbial population in termophilic-dry anaerobic digestion; (41) The use of hydrolytic enzymes in agricultural biogas production; (42) A contribution to mobile online gas diagnostics according to the efficiency of biogas plants; (43) Genetic &apos

  4. How to best use biogas; Wohin mit dem Biogas?

    Energy Technology Data Exchange (ETDEWEB)

    Wiedemann, Karsten

    2010-02-15

    Biogas has many uses, e.g. in power generation, space heating or as motor fuel, but not all of them are efficient. The biogas industry debates the most useful future strategies. The contribution goes into detail about the German legislation on biogas supply to the public gas grids and about the deregulation of the heat market. (orig.)

  5. Anaerobic Digestion and Biogas Potential: Simulation of Lab and Industrial-Scale Processes

    Directory of Open Access Journals (Sweden)

    Ihsan Hamawand

    2015-01-01

    Full Text Available In this study, a simulation was carried out using BioWin 3.1 to test the capability of the software to predict the biogas potential for two different anaerobic systems. The two scenarios included: (1 a laboratory-scale batch reactor; and (2 an industrial-scale anaerobic continuous lagoon digester. The measured data related to the operating conditions, the reactor design parameters and the chemical properties of influent wastewater were entered into BioWin. A sensitivity analysis was carried out to identify the sensitivity of the most important default parameters in the software’s models. BioWin was then calibrated by matching the predicted data with measured data and used to simulate other parameters that were unmeasured or deemed uncertain. In addition, statistical analyses were carried out using evaluation indices, such as the coefficient of determination (R-squared, the correlation coefficient (r and its significance (p-value, the general standard deviation (SD and the Willmott index of agreement, to evaluate the agreement between the software prediction and the measured data. The results have shown that after calibration, BioWin can be used reliably to simulate both small-scale batch reactors and industrial-scale digesters with a mean absolute percentage error (MAPE of less than 10% and very good values of the indexes. Furthermore, by changing the default parameters in BioWin, which is a way of calibrating the models in the software, as well, this may provide information about the performance of the digester. Furthermore, the results of this study showed there may be an over estimation for biogas generated from industrial-scale digesters. More sophisticated analytical devices may be required for reliable measurements of biogas quality and quantity.

  6. Evaluation of Biogas Production Performance and Archaeal Microbial Dynamics of Corn Straw during Anaerobic Co-Digestion with Cattle Manure Liquid.

    Science.gov (United States)

    Zhang, Benyue; Zhao, Hongyan; Yu, Hairu; Chen, Di; Li, Xue; Wang, Weidong; Piao, Renzhe; Cui, Zongjun

    2016-04-28

    The rational utilization of crop straw as a raw material for natural gas production is of economic significance. In order to increase the efficiency of biogas production from agricultural straw, seasonal restrictions must be overcome. Therefore, the potential for biogas production via anaerobic straw digestion was assessed by exposing fresh, silage, and dry yellow corn straw to cow dung liquid extract as a nitrogen source. The characteristics of anaerobic corn straw digestion were comprehensively evaluated by measuring the pH, gas production, chemical oxygen demand, methane production, and volatile fatty acid content, as well as applying a modified Gompertz model and high-throughput sequencing technology to the resident microbial community. The efficiency of biogas production from fresh straw (433.8 ml/g) was higher than that of production from straw silage and dry yellow straw (46.55 ml/g and 68.75 ml/g, respectively). The cumulative biogas production from fresh straw, silage straw, and dry yellow straw was 365 l(-1) g(-1) VS, 322 l(-1) g-1 VS, and 304 l(-1) g(-1) VS, respectively, whereas cumulative methane production was 1,426.33%, 1,351.35%, and 1,286.14%, respectively, and potential biogas production was 470.06 ml(-1) g(-1) VS, 461.73 ml(-1) g(-1) VS, and 451.76 ml(-1) g(-1) VS, respectively. Microbial community analysis showed that the corn straw was mainly metabolized by acetate-utilizing methanogens, with Methanosaeta as the dominant archaeal community. These findings provide important guidance to the biogas industry and farmers with respect to rational and efficient utilization of crop straw resources as material for biogas production.

  7. Terpenes removal from biogas; Terpenenverwijdering uit biogas

    Energy Technology Data Exchange (ETDEWEB)

    Schulze, P.; Holstein, J.; De Haan, HR.; Vlap, H. [DNV KEMA, Arnhem (Netherlands)

    2013-06-15

    Biogas may contain unwanted and harmful components, including aromatic hydrocarbons such as terpenes. These terpenes (organic oils) are mainly present in citrus peel and plant residues; that is why especially raw biogas from organic waste digestion plants contains high concentrations of terpenes. If terpenes end up in the gas grid (with the injected biomethane) there is a risk that plastics (PE pipes) lose their mechanical properties by absorbing liquids or extracting ethereal plasticizers. This can lead to embrittlement greatly lowering the reliability of the piping. In addition, soft components are als o affected (gaskets and rubber O-rings). Besides the impact on the integrity of the gas grid, terpenes also mask the odor of natural gas odorants such as THT. This impedes the detection of gas leaks which is a significant security risk. Furthermore, the presence of terpenes in biogas leads to fouling of equipment used for the drying of biomethane, as well as contamination of adsorption liquids and membranes used in the upgrading process. Currently, terpenes are removed by activated carbon filters. The tool life of such a filter can be relatively short if terpene concentrations are high in the biogas; this results in a significant increase of the operational costs, due to the replacement of the carbon. This study looked at alternative techniques for removing much of the terpenes from biogas in a simple, efficient and cheap way. In a workshop with stakeholders two techniques were chosen to be tested on laboratory scale in order to demonstrate the proof of principle. These techniques are photo-oxydation and a gas scrubbing. Of all investigated techniques for the removal of limonene the application of UV radiation seems to be the most promising option because of the simplicity of the process, the high efficiency (up to 94%), the comparable operational costs with activated carbon (6.7 to 9.5 euro/kg limonene removed, compared to 10 euro/kg limonene removed for activated

  8. Moving bed biofilm reactor technology: process applications, design, and performance.

    Science.gov (United States)

    McQuarrie, James P; Boltz, Joshua P

    2011-06-01

    The moving bed biofilm reactor (MBBR) can operate as a 2- (anoxic) or 3-(aerobic) phase system with buoyant free-moving plastic biofilm carriers. These systems can be used for municipal and industrial wastewater treatment, aquaculture, potable water denitrification, and, in roughing, secondary, tertiary, and sidestream applications. The system includes a submerged biofilm reactor and liquid-solids separation unit. The MBBR process benefits include the following: (1) capacity to meet treatment objectives similar to activated sludge systems with respect to carbon-oxidation and nitrogen removal, but requires a smaller tank volume than a clarifier-coupled activated sludge system; (2) biomass retention is clarifier-independent and solids loading to the liquid-solids separation unit is reduced significantly when compared with activated sludge systems; (3) the MBBR is a continuous-flow process that does not require a special operational cycle for biofilm thickness, L(F), control (e.g., biologically active filter backwashing); and (4) liquid-solids separation can be achieved with a variety of processes, including conventional and compact high-rate processes. Information related to system design is fragmented and poorly documented. This paper seeks to address this issue by summarizing state-of-the art MBBR design procedures and providing the reader with an overview of some commercially available systems and their components.

  9. 15. Annual Meeting on biogas and bioenergy in agriculture. Proceedings; 15. Jahrestagung Biogas und Bioenergie in der Landwirtschaft. Tagungsband

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2006-07-01

    The volume contains besides the general statements on environmental protection and energy savings in the future and biogas as great potential for the rural development the following contributions in four parts: 1. political enveloping conditions: biogas usage within the frame of the the new EEG; state of biogas usage in Baden-Wuerttemberg; practical experiences end perspectives for the biogas development; renewable raw materials from the view of environmenmental protection; 2. gas utilization: the bioenergy village Mauenheim - model for the rural area; compression ignition gas engines with biogenic ignition oils; realization and economic performance of gas engines with biogas; microgasturbines - engineering and chances, gas processing and feeding into the gas network; 3. substrate: influence of the energy plant agriculture on the regional structures; biogas plants: substrate control by TS sensing; fermentation of fusaria contaminated corn; substrate contracts in the view of revenue and contract legacy; energy plants agriculture in Baden-Wuerttemberg; 4. process biology: comparison of dry and wet fermentation; fundamentals, process stability analytical possibilities; start-up of a biogas plant; biogas process with external hydrolysis; problems in the fermenter - inhibitors and auxiliaries.

  10. A Framework for Human Performance Criteria for Advanced Reactor Operational Concepts

    Energy Technology Data Exchange (ETDEWEB)

    Jacques V Hugo; David I Gertman; Jeffrey C Joe

    2014-08-01

    This report supports the determination of new Operational Concept models needed in support of the operational design of new reactors. The objective of this research is to establish the technical bases for human performance and human performance criteria frameworks, models, and guidance for operational concepts for advanced reactor designs. The report includes a discussion of operating principles for advanced reactors, the human performance issues and requirements for human performance based upon work domain analysis and current regulatory requirements, and a description of general human performance criteria. The major findings and key observations to date are that there is some operating experience that informs operational concepts for baseline designs for SFR and HGTRs, with the Experimental Breeder Reactor-II (EBR-II) as a best-case predecessor design. This report summarizes the theoretical and operational foundations for the development of a framework and model for human performance criteria that will influence the development of future Operational Concepts. The report also highlights issues associated with advanced reactor design and clarifies and codifies the identified aspects of technology and operating scenarios.

  11. Effect of substrate and cation requirement on anaerobic volatile fatty acid conversion rates at elevated biogas pressure

    NARCIS (Netherlands)

    Lindeboom, R.E.F.; Ferrer, I.; Weijma, J.; Lier, van J.B.

    2013-01-01

    This work studied the anaerobic conversion of neutralized volatile fatty acids (VFA) into biogas under Autogenerative High Pressure Digestion (AHPD) conditions. The effects of the operating conditions on the biogas quality, and the substrate utilisation rates were evaluated using 3 AHPD reactors (0.

  12. A pH-based control of ammonia in biogas during anaerobic digestion of artificial pig manure and maize silage

    NARCIS (Netherlands)

    Strik, D.P.B.T.B.; Domnanovich, A.M.; Braun, R.; Holubar, P.

    2006-01-01

    The purposes of this study were to prove that ammonia can be present in biogas from anaerobic digestion and to control this ammonia by reducing the reactor pH. Ammonia containing biogas was produced for a period of more than 100 days, with a maximum of 332 ppm. Especially during periods of high free

  13. A review on optimization production and upgrading biogas through CO2 removal using various techniques.

    Science.gov (United States)

    Andriani, Dian; Wresta, Arini; Atmaja, Tinton Dwi; Saepudin, Aep

    2014-02-01

    Biogas from anaerobic digestion of organic materials is a renewable energy resource that consists mainly of CH4 and CO2. Trace components that are often present in biogas are water vapor, hydrogen sulfide, siloxanes, hydrocarbons, ammonia, oxygen, carbon monoxide, and nitrogen. Considering the biogas is a clean and renewable form of energy that could well substitute the conventional source of energy (fossil fuels), the optimization of this type of energy becomes substantial. Various optimization techniques in biogas production process had been developed, including pretreatment, biotechnological approaches, co-digestion as well as the use of serial digester. For some application, the certain purity degree of biogas is needed. The presence of CO2 and other trace components in biogas could affect engine performance adversely. Reducing CO2 content will significantly upgrade the quality of biogas and enhancing the calorific value. Upgrading is generally performed in order to meet the standards for use as vehicle fuel or for injection in the natural gas grid. Different methods for biogas upgrading are used. They differ in functioning, the necessary quality conditions of the incoming gas, and the efficiency. Biogas can be purified from CO2 using pressure swing adsorption, membrane separation, physical or chemical CO2 absorption. This paper reviews the various techniques, which could be used to optimize the biogas production as well as to upgrade the biogas quality.

  14. Impact of nickel and cobalt on biogas production and process stability during semi-continuous anaerobic fermentation of a model substrate for maize silage.

    Science.gov (United States)

    Pobeheim, Herbert; Munk, Bernhard; Lindorfer, Harald; Guebitz, Georg M

    2011-01-01

    The importance of nickel and cobalt on anaerobic degradation of a defined model substrate for maize was demonstrated. Five semi-continuous reactors were operated for 250 days at 35 °C and a well-defined trace metal solution was added to all reactors. Two reactors each were limited regarding the concentration of Ni(2+) and Co(2+), respectively, for certain time intervals. The required nickel concentration was depending on the organic loading rates (OLR) while, for example, above 2.6 g ODM L(-1) d(-1) nickel concentrations below 0.06 mg kg(-1) FM in the process significantly decreased biogas production by up to 25% compared to a control reactor containing 0.8 mg Ni(2+) kg(-1) FM. Similarly, limitation of cobalt to 0.02 mg kg(-1) FM decreased biogas production by about 10%. Limitations of nickel as well as cobalt lead to process instability. However, after gradual addition of nickel till 0.6 mg and cobalt till 0.05 mg kg(-1) FM the OLR was again increased to 4.3 g ODM L(-1) d(-1) while process stability was recovered and a fast metabolisation of acetic and propionic acid was detected. An increase of nickel to 0.88 mg kg(-1) FM did not enhance biogas performance. Furthermore, the increase of cobalt from 0.05 mg kg(-1) FM up to 0.07 mg kg(-1) FM did not exhibit a change in anaerobic fermentation and biogas production.

  15. Basic data biogas Germany. Solid fuels, biofuels, biogas; Basisdaten Bioenergie Deutschland. Festbrennstoffe, Biokraftstoffe, Biogas

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2011-09-15

    The brochure ''Basic data biogas Germany'' gives statistical information about (a) renewable energies: primary energy consumption, power generation, energy supply, avoidance of greenhouse gases; (b) Solid fuels: energetic utilization, wood pellets, energy consumption, comparison to heating oil; (c) Biofuels: consumption, bioethanol, biodiesel, vegetable oils; (d) Biogas: biogas power plants, energy content, production, legal aspects.

  16. Basic data biogas Germany. Solid fuels, biofuels, biogas; Basisdaten Bioenergie Deutschland. Festbrennstoffe - Biokraftstoffe - Biogas

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2012-08-15

    The brochure ''Basic data biogas Germany'' gives statistical information about (a) renewable energies: primary energy consumption, power generation, energy supply, avoidance of greenhouse gases; (b) Solid fuels: energetic utilization, wood pellets, energy consumption, comparison to heating oil; (c) Biofuels: consumption, bioethanol, biodiesel, vegetable oils; (d) Biogas: biogas power plants, energy content, production, legal aspects.

  17. Comparative review of foam formation in biogas plants and ruminant bloat

    Energy Technology Data Exchange (ETDEWEB)

    Moeller, Lucie; Goersch, Kati; Zehnsdorf, Andreas; Mueller, Roland Arno [UFZ - Helmholtz Centre for Environmental Research, Leipzig (Germany). Environmental and Biotechnology Centre; Neuhaus, Juergen [Leipzig Univ. (Germany). Inst. of Bacteriology and Mycology

    2012-12-15

    This review gives an overview of the current knowledge concerning the problem of foam formation in the process of anaerobic digestion in biogas plants that utilize renewable resources or biogenic waste material for biogas production. Process upsets in biogas production induced by foam formation can have a negative impact on the efficiency of biogas plants. The foam can block gas pipes and cause severe damage to the bioreactor equipment, ranging from a failure of the feeders to a damage of the roof of the biogas plant. The most common foam removal methods - stirring in the foam, adding anti-foaming agents, diminishing substrate feeding, and altering the biogas reactor management - are not always successful. However, the reasons for the excessive foam formation during the biogas production process have not yet been elucidated in detail. In contrast, foam building in the rumen of ruminants as a cause for bloat has been studied thoroughly. In general, the interaction between proteins, polysaccharides (mucilage), and small plant particles is assumed to be the crucial factor. As the fermentation process in the rumen has many similarities with the biogas production process, the current research results on bloat in ruminants are summarized and compared with the process of foaming in biogas plants. (orig.)

  18. A novel application of red mud-iron on granulation and treatment of palm oil mill effluent using upflow anaerobic sludge blanket reactor.

    Science.gov (United States)

    Ahmad, Anwar

    2014-01-01

    The performance of the upflow anaerobic sludge blanket reactor that used red mud-iron (RM-Fe) for methane production for the treatment of palm oil mill effluent (POME) at various hydraulic retention time (HRT) was determined. POME was used as the substrate carbon source. The biogas production rate was 1.7 l biogas/h with a methane yield of 0.78 l CH4/g CODremoved and chemical oxygen demand (COD) removal was 85% at POME concentration of 30 g COD/l at HRT 16 h. The reactor R2 showed average methane content of biogas and COD reduction of 78% and 85% at 400 mg/l RM-Fe. Significant increase in the granule diameter (up to 2900 μm) in R2 was compared to control R1 (up to 86 μm) at end of the experiment.

  19. Implementation of online volatile fatty acids sensor for control and optimization of anaerobic process for low cost biogas production from manure. Project report

    Energy Technology Data Exchange (ETDEWEB)

    Boe, K.; Angelidaki, I.

    2010-10-15

    Proper monitoring and control can improve process stability and enhance process performance for better economy of the biogas plants. Volatile fatty acid (VFA) is the most widely recognized as a direct, relevant measure of stability. Classic on-line measurement of individual VFA is based on filtration, which suffers from fouling when applied with manure slurries. A VFA sensor developed at DTU Environment, based on headspace chromatography technique could avoid the problems from particulate matters. In this work, the sensor had been implemented for online monitoring of the lab-scale and the pilot-scale manure digester. The industrial prototype of the VFA sensor and sample acquisition system has been constructed and implemented at a pilot scale biogas plant, located at Lundtofte, DTU. The VFA sensor has shown very satisfying results in terms of sensitivity and reliability for monitoring the biogas process. Moreover, the online VFA and biogas registration data were used as process indicators for automatic control of the biogas reactor. The results from control experiments confirmed that the combination of biogas production, total VFA concentration and propionate concentration could effectively reflect the dynamic state of the process which was very crucial for automatic control. Due to the standardized analyzing condition (pH<2, temperature>70 deg. C), the sensor responses were not affected by the manure composition (TS, VS or the addition of extra organics), which made these results representative for implementing in the full-scale biogas plant where some industrial organic wastes were added to increase the biogas production. During the project period, the sensor design and construction had been modified and tested several times to improve the robustness. However, the implementation of the sensor in full-scale biogas plant would need some further development such as improvement of mechanical design and further up-scaling depending on the dry solid content in the

  20. Economical and ecological benchmarking of biogas plant configurations for flexible power generation in future power supply systems; Oekonomisches und oekologisches Benchmarking von Biogasanlagenkonfigurationen zur flexiblen Verstromung in zukuenftigen Stromversorgungssystemen

    Energy Technology Data Exchange (ETDEWEB)

    Hahn, Henning [Fraunhofer Institut fuer Windenergie und Energiesystemtechnik (IWES), Kassel (Germany). Bereich Energieverfahrenstechnik

    2016-08-01

    With the share of intermittent renewable energies within the electricity system rising, balancing services from dispatchable power plants are of increasing importance. This study comparatively assesses the environmental and economic performance of biogas plant configurations, supplying biogas on demand for flexible power generation. A cost analysis of five configurations based on biogas storing and flexible biogas production concepts has been carried out. Results show that additional flexibility costs for a biogas supply of 8 hours per day range between 2 Euro to 11 Euro MWh{sup -1} and for a 72 hour period without biogas demand from 9 Euro to 19 Euro MWh{sup -1}. While biogas storage concepts were identified as favorable short-term supply configurations, flexible biogas production concepts profit from reduced storage requirements at plants with large biogas production capacities or for longer periods without biogas demand [1, 2]. Flexible biogas plant configurations indicate an increased energy demand to operate the operational enhancements compared to conventional biogas plants supplying biogas for baseload power generation. However, findings show that in contrast to an alternative supply of power generators with natural gas, biogas supplied on demand by adapted biogas plant configurations saves greenhouse gas emissions by 54 to 65 g CO{sub 2-eq} MJ{sup -1} and primary energy by about 1.17 MJ MJ{sup -1}. In this regard, configurations with flexible biogas production profit from reduced biogas storage requirements and achieve higher savings compared to configurations with continuous biogas production [1, 3].

  1. Experiences with biogas in Denmark

    DEFF Research Database (Denmark)

    Bundgaard, Sirid Sif; Kofoed-Wiuff, Anders

    This report is primarily based on the work of the Danish biogas task force, which was established as a result of the Energy Agreement of 22 March 2012. The purpose of the task force is to examine and support concrete biogas projects in order to facilitate the projected biogas development up to 2020....... The focus of the task force was on the practical integration of the new biogas production in energy system, including the utilization of gas, the necessary infrastructure and contractual relationships. The aim was to ensure effective and appropriate integration of biogas in the Danish energy supply, which...... was consistent with the policy objectives, both in regards to current challenges for specific biogas plants and the role of biogas flexible renewable energy form on longer term. The task force's final report was published in 2014....

  2. Biogas generation in anaerobic wastewater treatment under tetracycline antibiotic pressure

    Science.gov (United States)

    Lu, Meiqing; Niu, Xiaojun; Liu, Wei; Zhang, Jun; Wang, Jie; Yang, Jia; Wang, Wenqi; Yang, Zhiquan

    2016-06-01

    The effect of tetracycline (TC) antibiotic on biogas generation in anaerobic wastewater treatment was studied. A lab-scale Anaerobic Baffled Reactor (ABR) with three compartments was used. The reactor was operated with synthetic wastewater in the absence of TC and in the presence of 250 μg/L TC for 90 days, respectively. The removal rate of TC, volatile fatty acids (VFAs), biogas compositions (hydrogen (H2), methane (CH4), carbon dioxide (CO2)), and total biogas production in each compartment were monitored in the two operational conditions. Results showed that the removal rate of TC was 14.97–67.97% in the reactor. The presence of TC had a large negative effect on CH4 and CO2 generation, but appeared to have a positive effect on H2 production and VFAs accumulation. This response indicated that the methanogenesis process was sensitive to TC presence, but the acidogenesis process was insensitive. This suggested that the presence of TC had less influence on the degradation of organic matter but had a strong influence on biogas generation. Additionally, the decrease of CH4 and CO2 generation and the increase of H2 and VFAs accumulation suggest a promising strategy to help alleviate global warming and improve resource recovery in an environmentally friendly approach.

  3. Effect of Inhibitors on Biogas Laminar Burning Velocity and Flammability Limits in Spark Ignited Premix Combustion

    Directory of Open Access Journals (Sweden)

    Willyanto Anggono

    2014-01-01

    Full Text Available Biogas is the natural byproduct of the decomposition of vegetation or animal manure, of which there are almost in exhaustable supplies in the world, and which does not contribute CO2 or other greenhouse gases to global warming or climate change. Biogas contains 66.4% flammable gas (CH4 and 33.6% inhibitors (CO2 and N2. This study focuses on the effects of inhibitors on biogas laminar burning velocity and flammability limits in spark ignited premix combustion. Spherically expanding laminar premixed flames, freely propagating from spark ignition sources in initially quiescent biogas–air mixtures, are continuously recorded by a high-speed digital camera. Initially, all the experiments in this paper were performed using inhibitorless biogas (biogas without inhibitors at room temperature, at reduced pressure (0.5 atm and at various equivalence ratios (ϕ from the lower flammable limit to the upper flammable limit. The results are compared with those from biogas (containing inhibitors flames at reduced pressure, inhibitorless biogas flames at atmospheric pressure (1 atm, and biogas flames at atmospheric pressure to emphasize the effect of inhibitors on biogas laminar burning velocity and flammability limits. Compared to an inhibitorless biogas-air mixtures, in the biogas-air mixtures, the presence of inhibitors cause a reduction in the laminar burning velocity and the flammable limits become narrower.

  4. Liquid membrane purification of biogas

    Energy Technology Data Exchange (ETDEWEB)

    Majumdar, S.; Guha, A.K.; Lee, Y.T.; Papadopoulos, T.; Khare, S. (Stevens Inst. of Tech., Hoboken, NJ (United States). Dept. of Chemistry and Chemical Engineering)

    1991-03-01

    Conventional gas purification technologies are highly energy intensive. They are not suitable for economic removal of CO{sub 2} from methane obtained in biogas due to the small scale of gas production. Membrane separation techniques on the other hand are ideally suited for low gas production rate applications due to their modular nature. Although liquid membranes possess a high species permeability and selectivity, they have not been used for industrial applications due to the problems of membrane stability, membrane flooding and poor operational flexibility, etc. A new hollow-fiber-contained liquid membrane (HFCLM) technique has been developed recently. This technique overcomes the shortcomings of the traditional immobilized liquid membrane technology. A new technique uses two sets of hydrophobic, microporous hollow fine fibers, packed tightly in a permeator shell. The inter-fiber space is filled with an aqueous liquid acting as the membrane. The feed gas mixture is separated by selective permeation of a species through the liquid from one fiber set to the other. The second fiber set carries a sweep stream, gas or liquid, or simply the permeated gas stream. The objectives (which were met) of the present investigation were as follows. To study the selective removal of CO{sub 2} from a model biogas mixture containing 40% CO{sub 2} (the rest being N{sub 2} or CH{sub 4}) using a HFCLM permeator under various operating modes that include sweep gas, sweep liquid, vacuum and conventional permeation; to develop a mathematical model for each mode of operation; to build a large-scale purification loop and large-scale permeators for model biogas separation and to show stable performance over a period of one month.

  5. Bio-Propane from glycerol for biogas addition

    Energy Technology Data Exchange (ETDEWEB)

    Brandin, Jan; Hulteberg, Christian; Liljegren Nilsson, Andreas (Biofuel-Solution AB, Malmoe (Sweden))

    2008-11-15

    In this report, the technical and economical feasibility to produce higher alkanes from bioglycerol has been investigated. The main purpose of producing this kind of chemicals would be to replace the fossil LPG used in upgraded biogas production. When producing biogas and exporting it to the natural gas grid, the Wobbe index and heating value does not match the existing natural gas. Therefore, the upgraded biogas that is put into the natural gas grid in Sweden today contains 8-10 vol-% of LPG. The experimental work performed in association to this report has shown that it is possible to produce propane from glycerol. However, the production of ethane from glycerol may be even more advantageous. The experimental work has included developing and testing catalysts for several intermediate reactions. The work was performed using different micro-scale reactors with a liquid feed rate of 18 g/h. The first reaction, independent on if propane or ethane is to be produced, is dehydration of glycerol to acrolein. This was showed during 60 h on an acidic catalyst with a yield of 90%. The production of propanol, the second intermediate to producing propane, was shown as well. Propanol was produced both using acrolein as the starting material as well as glycerol (combining the first and second step) with yields of 70-80% in the first case and 65-70% in the second case. The propanol produced was investigated for its dehydration to propene, with a yield of 70-75%. By using a proprietary, purposely developed catalyst the propene was hydrogenated to propane, with a yield of 85% from propanol. The formation of propane from glycerol was finally investigated, with an overall yield of 55%. The second part of the experimental work performed investigated the possibilities of decarbonylating acrolein to form ethane. This was made possible by the development of a proprietary catalyst which combines decarbonylation and water-gas shift functionality. By combining these two functionalities, no

  6. Effect of inoculum and sulfide type on simultaneous hydrogen sulfide removal from biogas and nitrogen removal from swine slurry and microbial mechanism.

    Science.gov (United States)

    Wang, Lan; Wei, Benping; Chen, Ziai; Deng, Liangwei; Song, Li; Wang, Shuang; Zheng, Dan; Liu, Yi; Pu, Xiaodong; Zhang, Yunhong

    2015-12-01

    Four reactors were initiated to study the effect of inoculum and sulfide type on the simultaneous hydrogen sulfide removal from biogas and nitrogen removal from swine slurry (Ssu-Nir) process. Anaerobic sludge, aerobic sludge, and water were used as inocula, and Na2S and biogas were used as a sulfide substrate, respectively. Additionally, 454 pyrosequencing of the 16S rRNA gene was used to explore the bacterial diversity. The results showed that sulfur-oxidizing bacteria (Thiobacillus, 42.2-84.4 %) were dominant in Ssu-Nir process and led to the excellent performance. Aerobic sludge was more suitable for inoculation of the Ssu-Nir process because it is better for rapidly enriching dominant sulfur-oxidizing bacteria (Thiobacillus, 54.4 %), denitrifying sulfur-oxidizing bacteria (40.0 %) and denitrifiers (23.9 %). Lower S(2-) removal efficiency (72.6 %) and NO3 (-) removal efficiency (biogas as a sulfide substrate than when Na2S was used. For the Ssu-Nir process with biogas as the sulfide substrate, limiting H2S absorption caused a high relative abundance of sulfur-oxidizing bacteria, Thiobacillus (84.8 %) and Thiobacillus sayanicus (39.6 %), which in turn led to low relative abundance of denitrifiers (1.6 %) and denitrifying sulfur-oxidizing bacteria (24.4 %), low NO3 (-) removal efficiency, and eventually poor performance.

  7. Biogas document; Dossier Biogaz

    Energy Technology Data Exchange (ETDEWEB)

    Verchin, J.C.; Servais, C. [Club BIOGAZ, 94 - Arcueil (France)

    2002-06-01

    In this document concerning the biogas, the author presents this renewable energy situation in 2001-2002, the concerned actors, the accounting of the industrial methanization installations in France, the three main chains of process for industrial wastes and two examples of methanization implementation in a paper industry and in a dairy. (A.L.B.)

  8. Anaerobic digestion without biogas?

    NARCIS (Netherlands)

    Kleerebezem, R.; Joosse, B.; Rozendaal, R.; Van Loosdrecht, M.C.M.

    2015-01-01

    Anaerobic digestion for the production of methane containing biogas is the classic example of a resource recovery process that combines stabilization of particulate organic matter or wastewater treatment with the production of a valuable end-product. Attractive features of the process include the pr

  9. Environmental systems analysis of biogas systems; Miljoeanalys av biogassystem

    Energy Technology Data Exchange (ETDEWEB)

    Boerjesson, Paal; Berglund, Maria

    2003-05-01

    the fields, from manure when handling and storing it in conventional ways, and from organic waste from municipalities and food industries when composting the organic wastes. The size of the reduction of emission of ammonia and leakage of nitrate could, however, vary due to local conditions. Losses of methane would only have minor impact on eutrophication and acidification through somewhat higher emissions from fossil fuels which are assumed to be used to compensate for the energy losses that methane leakage leads to. Biogas as transportation fuel leads to reduced emissions of compounds that can create photochemical oxidants, especially when gasoline is replaced. The same situation occurs when biogas is used for heat production, with a few exceptions, where the largest reduction is achieved when biogas from straw replaces combustion of straw in smallscale boilers. Biogas-based combined heat and power production in gas turbines may, however, result in an increased contribution when natural gas is replaced. When indirect environmental effects are considered, biogas from manure will give significant benefits, while losses of methane will give significant negative effects. Emissions of particles will be reduced in all analysed cases when biogas is used for heat production. Biogas for combined heat and power production may, however, result in both reduced and increased emissions. When biogas is utilised as transportation fuel, a reduction of emission of particles is almost always achieved, especially when diesel in trucks is replaced. The results from this study clearly show the importance of optimising both the performance and localisation of biogas systems in order to maximise the significant potential environmental benefits they can generate and to minimise the potential negative effects.

  10. Effects of sludge recirculation rate and mixing time on performance of a prototype single-stage anaerobic digester for conversion of food wastes to biogas and energy recovery.

    Science.gov (United States)

    Ratanatamskul, Chavalit; Saleart, Tawinan

    2016-04-01

    Food wastes have been recognized as the largest waste stream and accounts for 39.25 % of total municipal solid waste in Thailand. Chulalongkorn University has participated in the program of in situ energy recovery from food wastes under the Ministry of Energy (MOE), Thailand. This research aims to develop a prototype single-stage anaerobic digestion system for biogas production and energy recovery from food wastes inside Chulalongkorn University. Here, the effects of sludge recirculation rate and mixing time were investigated as the main key parameters for the system design and operation. From the results obtained in this study, it was found that the sludge recirculation rate of 100 % and the mixing time of 60 min per day were the most suitable design parameters to achieve high efficiencies in terms of chemical oxygen demand (COD), total solids (TS), and total volatile solid (TVS) removal and also biogas production by this prototype anaerobic digester. The obtained biogas production was found to be 0.71 m(3)/kg COD and the composition of methane was 61.6 %. Moreover, the efficiencies of COD removal were as high as 82.9 % and TVS removal could reach 83.9 % at the optimal condition. Therefore, the developed prototype single-stage anaerobic digester can be highly promising for university canteen application to recover energy from food wastes via biogas production.

  11. Rancang Bangun Alat Penghasil Biogas dari Plastik Polietilen

    OpenAIRE

    Latif

    2011-01-01

    Biogas is a gas the can be produced from anaerobic fermentation of organic matters such as animal or human’s feces, agricultural wastes, or their combination in a digester. In this research the biogas was produced from mixture of cow dung and paddy hay. The aim of this research was to design of a drift biogas producer which was easy to be assembled, cheap, and had a best performance. The result of this experiment showed that the polyethylene digester had a: capacity of 0,25 m3, wet volume 0,2...

  12. 射流搅拌提高牛粪中温厌氧发酵产沼气性能%Jet mixing improving biogas production performance of mesophilic anaerobic fermentation with cow manure

    Institute of Scientific and Technical Information of China (English)

    熊向峰; 贾丽娟; 宁平; 瞿广飞; 周成

    2015-01-01

    was increased in the bioreactor with the jet mixing. The microbial activity would have contributed to the vigorous degradation of organic matter. VFAs were utilized by methanogens for biogas production, which were unable to accumulate during the anaerobic digestion process with the jet mixing, and thus the product inhibition or substrate inhibition was eliminated. The methanogens in the jet mixing bioreactor grew fast since the 10th day, and the peak value was 2.0×108mL-1. During fermentation process in the jet mixing bioreactor, the amount and the activity of hydrolytic bacteria, acetogenic bacteria and methanogens remained at a high level. Meanwhile, the methane content of the biogas increased drastically from about 20% to over 55% before the 10th day, and it ranged between 55% and 65% from the 10th to the 30th day. The methane content variation was less than 10% in approximately 20 days. Carbon dioxide in biogas could be absorbed by the jet mixing, and therefore it was reused to generate methane with hydrogen as an electron donor. Moreover, the acetate could be formed from hydrogen and carbon dioxide by hydrogen-oxidizing acetogenic bacteria. These reactions should improve the performance of methanogenesis process. To sum up, the jet mixing method had a higher methane content and lower carbon dioxide content. Based on the results presented in this article, the jet mixing system shows a higher efficiency than the mechanical mixer and single slurry recirculation.%现有中温沼气工程的搅拌方式以机械搅拌和沼液回流搅拌为主,存在产气率低、设备难以维护、长期运行不稳定等问题。该研究设计了一种射流搅拌技术,集沼液回流搅拌和沼气搅拌于一体,试验用于牛粪中温厌氧发酵产沼气。通过沼气产率、营养基质消耗、微生物种类和数量的变化等方面分析射流搅拌强化牛粪中温厌氧发酵产气的效果及机理。结果表明:发酵期30 d内,无搅拌、机械

  13. Use of biogas in PEM fuel cells; Einsatz von Biogas in PEM-Brennstoffzellen

    Energy Technology Data Exchange (ETDEWEB)

    Scholz, Volkhard; Schmersahl, Ralf; Ellner, Janine (comps.)

    2009-06-15

    This research project was dedicated to two problems: 1. What demands must biogas meet in order to conform to the specifications of PEM fuel cell systems and permit safe operation? 2. How must a fuel cell system be designed and operated in order to be well-adapted to the special features of biogas as opposed to natural gas? For this purpose biogas samples were taken from laboratory-scale and commercial plants and analysed by gas chromatography using various substrates and methods. By combining this with the use of a mass spectroscopy detector (GC-MS system) it was possible to perform a qualitative and quantitative analysis of sulphurious trace gases in the biogas which might cause damage to the fuel cell system. Investigations were performed on an experimental reformer using either modelled or native biogas of different compositions, the intent being to obtain information for the design of the individual process stages. The two operating parameters steam-methane ratio (or S/C ratio) and reforming temperature were varied to optimise parameter settings in terms of energy efficiency. By linking the reformer to a 500 W fuel cell it was possible confirm the suitability of the reformed biogas for use in fuel cells. [German] In diesm Forschungsvorhaben werden zwei Fragestellungen bearbeitet: 1. Welche Anforderungen ergeben sich an das Biogas, um den Spezifikationen von PEM-Brennstoffzellensystemen zu genuegen und eine sicheren Betrieb zu ermoeglichen? 2. Wie muss das Brennstoffzellensystem ausgelegt und gefuehrt werden, um den Besonderheiten von Biogas im Vergleich zu Erdgas Rechnung zu tragen? Dazu wurden Biogasproben aus Labor- und Praxisanlagen unter Beruecksichtigung unterschiedlicher Substrate und Verfahren gaschromatisch analysiert. Die Kopplung mit einem massenspektroskopischen Detektor (GC-MS System) ermoeglicht dabei die Qualifizierung und Quantifizierung der vorhandenen schwefelhaltigen Spurengase, die eine Schaedigung von Brennstoffzellenanlagen verursachen. Die

  14. Advanced Conversion of Organic Waste into Biogas

    Energy Technology Data Exchange (ETDEWEB)

    Offenbacher, Elmar [BDI-BioEnergy International AG, Grambach/Graz (Austria)

    2012-11-01

    Day by day, every human generates significant amounts of organic waste that most of the time ends on landfills. Disposing of organic residues is not just a waste of energy resources but also a burden to the environment as anthropogenic emissions of greenhouse gases are produced. In contrast to waste combustion that can't generate any energy out of organic waste but the contrary, anaerobic digestion is the most suitable technology for the sustainable and efficient conversion of all kind of organic waste into valuable biogas. Biogas generated from organic waste typically consists of 55-60% methane (CH{sub 4}) and provides an energy content of more than 20 MJ/Nm{sup 3}. The average biogas yield is around 150 Nm{sup 3} per ton of organic waste that can be converted into 350 kW of electricity plus the same amount of process heat. In other words a typical household could recover about one twentieth of its power consumption just out of the organic waste it is producing. Anaerobic digestion significantly reduces the amount of waste going to landfill as well as the uncontrolled emissions of methane. The BDI High Load Hybrid Reactor merges the core concepts of CSTR and UASB fermenters while providing a two phase anaerobic digestion system. The first process step accommodates hydrolysis and acidification to break down the complex organic molecules into simple sugars, amino acids, and fatty acids under acid conditions. In the second stage acetic acids are finally converted into methane (CH{sub 4}), carbon dioxide (CO{sub 2}) and water. This two-phase concept ensures maximum yield of biogas generated, paired with high loading rates and feedstock flexibility.

  15. A Critical Assessment of Microbiological Biogas to Biomethane Upgrading Systems.

    Science.gov (United States)

    Rittmann, Simon K-M R

    2015-01-01

    Microbiological biogas upgrading could become a promising technology for production of methane (CH(4)). This is, storage of irregular generated electricity results in a need to store electricity generated at peak times for use at non-peak times, which could be achieved in an intermediate step by electrolysis of water to molecular hydrogen (H(2)). Microbiological biogas upgrading can be performed by contacting carbon dioxide (CO(2)), H(2) and hydrogenotrophic methanogenic Archaea either in situ in an anaerobic digester, or ex situ in a separate bioreactor. In situ microbiological biogas upgrading is indicated to require thorough bioprocess development, because only low volumetric CH(4) production rates and low CH(4) fermentation offgas content have been achieved. Higher volumetric production rates are shown for the ex situ microbiological biogas upgrading compared to in situ microbiological biogas upgrading. However, the ex situ microbiological biogas upgrading currently suffers from H(2) gas liquid mass transfer limitation, which results in low volumetric CH(4) productivity compared to pure H(2)/CO(2) conversion to CH(4). If waste gas utilization from biological and industrial sources can be shown without reduction in volumetric CH(4) productivity, as well as if the aim of a single stage conversion to a CH(4) fermentation offgas content exceeding 95 vol% can be demonstrated, ex situ microbiological biogas upgrading with pure or enrichment cultures of methanogens could become a promising future technology for almost CO(2)-neutral biomethane production.

  16. Design improvement and performance evaluation of solar photocatalytic reactor for industrial effluent treatment.

    Science.gov (United States)

    Nair, Ranjith G; Bharadwaj, P J; Samdarshi, S K

    2016-12-01

    This work reports the details of the design components and materials used in a linear compound parabolic trough reactor constructed with an aim to use the photocatalyst for solar photocatalytic applications. A compound parabolic trough reactor has been designed and engineered to exploit both UV and visible part of the solar irradiation. The developed compound parabolic trough reactor could receive almost 88% of UV radiation along with a major part of visible radiation. The performance of the reactor has been evaluated in terms of degradation of a probe pollutant using the parameters such as rate constant, residence time and photonic efficiency. An attempt has been made to assess the performance in different ranges of solar spectrum. Finally the developed reactor has been employed for the photocatalytic treatment of a paper mill effluent using Degussa P25 as the photocatalyst. The paper mill effluent collected from Nagaon paper mill, Assam, India has been treated under both batch mode and continuous mode using Degussa P25 photocatalyst under artificial and natural solar radiation, respectively. The photocatalytic degradation kinetics of the paper mill effluent has been determined using the reduction in total organic carbon (TOC) values of the effluent.

  17. Augmented biogas production from protein-rich substrates and associated metagenomic changes.

    Science.gov (United States)

    Kovács, Etelka; Wirth, Roland; Maróti, Gergely; Bagi, Zoltán; Nagy, Katalin; Minárovits, János; Rákhely, Gábor; Kovács, Kornél L

    2015-02-01

    This study demonstrates that appropriate adaptation of the microbial community to protein-rich biomass can lead to sustainable biogas production. The process of acclimation to these unusual mono-substrates was controlled by the protease activity of the microbial community. Meat extract (C/N=3.32) and kitchen waste (C/N=12.43) were used as biogas substrates. Metagenome analysis highlighted several mesophilic strains that displayed a preference for protein degradation. Bacillus coagulans, Bacillus subtilis and Pseudomonas fluorescens were chosen for detailed investigation. Pure cultures were added to biogas reactors fed solely with protein-rich substrates. The bioaugmentation resulted in a 50% increase in CH4 production even without any acclimation. The survival and biological activity of the added bacteria were followed in fed-batch fermenters by qPCR. Stable biogas production was observed for an extended period of time in laboratory CSTR reactors fed with biomass of low C/N.

  18. Continuous dry fermentation of swine manure for biogas production.

    Science.gov (United States)

    Chen, Chuang; Zheng, Dan; Liu, Gang-Jin; Deng, Liang-Wei; Long, Yan; Fan, Zhan-Hui

    2015-04-01

    A down plug-flow anaerobic reactor (DPAR) was designed for the feasibility study on continuous dry fermentation of swine manure without any additional stirring. Using fresh swine manure as the feedstock with TS concentration (w/w) of 20%, 25%, 30%, and 35%, stable volumetric biogas production rates of 2.40, 1.92, 0.911, and 0.644L · (Ld)(-1) and biogas yields of 0.665, 0.532, 0.252, and 0.178 L g(-)(1)VS were obtained respectively, and the TS degradation rates were 46.5%, 45.4%, 53.2%, and 55.6%, respectively. With the increase of feedstock TS concentration, the concentration of ammonia nitrogen grew up to the maximum value of 3500 mg L(-1). Biogas production was obviously inhibited when the concentration of ammonia nitrogen was above 3000 mg L(-1). The maximal volumetric biogas production rate of 2.34 L ·(Ld)(-1) and biogas yield of 0.649 L g(-1)VS were obtained with TS concentration of 25% at 25°C without inhibition. Liquidity experiments showed that TS concentration of digestate could be less than 15.8%, and the flow rate of digestate more than 0.98 m s(-1) when the feedstock TS concentration was less than 35%, which indicated the digestate could be easily discharged from a DPAR. Therefore, it is feasible to conduct a continuous dry fermentation in a DPAR using fresh swine manure as the feedstock with TS concentration less than 35%, whereas the feedstock TS concentration should not exceed 30% to achieve the maximal biogas production rate and biogas yield.

  19. Ultrasound pretreatment for enhanced biogas production from olive mill wastewater.

    Science.gov (United States)

    Oz, Nilgun Ayman; Uzun, Alev Cagla

    2015-01-01

    This study investigates applicability of low frequency ultrasound technology to olive mill wastewaters (OMWs) as a pretreatment step prior to anaerobic batch reactors to improve biogas production and methane yield. OMWs originating from three phase processes are characterized with high organic content and complex nature. The treatment of the wastewater is problematic and alternative treatment options should be investigated. In the first part of the study, OMW samples were subjected to ultrasound at a frequency of 20kHz with applied powers varying between 50 and 100W under temperature controlled conditions for different time periods in order to determine the most effective sonication conditions. The level of organic matter solubilization at ultrasound experiments was assessed by calculating the ratio of soluble chemical oxygen demand/total chemical oxygen demand (SCOD/TCOD). The results revealed that the optimum ultrasonic condition for diluted OMW is 20kHz, 0.4W/mL for 10min. The application of ultrasound to OMW increased SCOD/TCOD ratio from 0.59 to 0.79. Statistical analysis (Friedman's tests) show that ultrasound was significantly effective on diluted OMW (p0.05). For raw OMW, this increase has been found to be limited due to high concentration of suspended solids (SS). In the second part of the study, biogas and methane production rates of anaerobic batch reactor fed with the ultrasound pretreated OMW samples were compared with the results of control reactor fed with untreated OMW in order to determine the effect of sonication. A nonparametric statistical procedure, Mann-Whitney U test, was used to compare biogas and methane production from anaerobic batch reactors for control and ultrasound pretreated samples. Results showed that application of low frequency ultrasound to OMW significantly improved both biogas and methane production in anaerobic batch reactor fed with the wastewater (preactor fed with ultrasound pretreated diluted OMW produced approximately 20

  20. ASSESSMENT OF THE BIODIVERSITY OF SAMPLES USED FOR ISOLATION OF MICROBIAL STRAINS CAPABLE OF CONVERTING STRAW DESTINED AS A SUBSTRATE FOR BIOGAS PLANT

    Directory of Open Access Journals (Sweden)

    Krystyna Cybulska

    2016-01-01

    Full Text Available In biogas plants, almost any type of organic matter can be used as a substrate to produce biogas. To make the process of methane fermentation more effective, these materials are pretreated. This applies in particular to a group of difficult substrates. Straw, due to its hemicellulose structure and saturation, is hardly fermented by biogas reactor microorganisms. The methods of post-harvest residue preparation for anaerobic digestion being applied so far are expensive, while their application has a negative effect on methanoegenic bacteria. Therefore, the microorganisms being able to degrade straw hemicellulose structure, utilisation of which could precede the proper fermentation process, have been searched for. This paper presents the results of microbial biodiversity analysis in the environmental samples being lupin, cereal, rape and maize straw as well as hay and haylage at different degradation stages. The analysis of biodiversity will help at a further stage of study to isolate active microbial strains showing cellulolytic, hemicellulolytic or ligninolytic activity which are desirable in the process of straw biodegradation. Analysis of the microbial count was performed by the method of deep inoculation on different microbiological culture media. The conducted tests include determination of the number of fungi, bacteria and actinomycetes. The results obtained confirm the usefulness of the analysed samples for isolation of microbial strains capable of converting straw preceding the biogas production.

  1. Innovative test method for the estimation of the foaming tendency of substrates for biogas plants

    Energy Technology Data Exchange (ETDEWEB)

    Moeller, Lucie, E-mail: lucie.moeller@ufz.de [UFZ – Helmholtz Centre for Environmental Research, Centre for Environmental Biotechnology, Permoserstrasse 15, 04318 Leipzig (Germany); Eismann, Frank, E-mail: info@antoc.de [Eismann & Stöbe GbR, GeoPark, Geb. A12, Bautzner Strasse 67, 04347 Leipzig (Germany); Wißmann, Daniel, E-mail: d.s.wissmann@gmx.de [University of Hohenheim, State Institute of Agricultural Engineering and Bioenergy (LA740), Garbenstrasse 9, 70599 Stuttgart (Germany); Nägele, Hans-Joachim, E-mail: hajo.naegele@uni-hohenheim.de [University of Hohenheim, State Institute of Agricultural Engineering and Bioenergy (LA740), Garbenstrasse 9, 70599 Stuttgart (Germany); Zielonka, Simon, E-mail: simon.zielonka@uni-hohenheim.de [University of Hohenheim, State Institute of Agricultural Engineering and Bioenergy (LA740), Garbenstrasse 9, 70599 Stuttgart (Germany); Müller, Roland A., E-mail: roland.mueller@ufz.de [UFZ – Helmholtz Centre for Environmental Research, Centre for Environmental Biotechnology, Permoserstrasse 15, 04318 Leipzig (Germany); Zehnsdorf, Andreas, E-mail: andreas.zehnsdorf@ufz.de [UFZ – Helmholtz Centre for Environmental Research, Centre for Environmental Biotechnology, Permoserstrasse 15, 04318 Leipzig (Germany)

    2015-07-15

    Graphical abstract: Display Omitted - Highlights: • Foaming in biogas plants depends on the interactions between substrate and digestate. • Foaming tests enable the evaluation of substrate foaming tendency in biogas plants. • Leipzig foam tester enables foaming tests of substrates prior to use. - Abstract: Excessive foaming in anaerobic digestion occurs at many biogas plants and can cause problems including plugged gas pipes. Unfortunately, the majority of biogas plant operators are unable to identify the causes of foaming in their biogas reactor. The occurrence of foaming is often related to the chemical composition of substrates fed to the reactor. The consistency of the digestate itself is also a crucial part of the foam formation process. Thus, no specific recommendations concerning substrates can be given in order to prevent foam formation in biogas plants. The safest way to avoid foaming is to test the foaming tendency of substrates on-site. A possible solution is offered by an innovative foaming test. With the help of this tool, biogas plant operators can evaluate the foaming disposition of new substrates prior to use in order to adjust the composition of substrate mixes.

  2. Life cycle assessment of flexibly fed biogas processes for an improved demand-oriented biogas supply.

    Science.gov (United States)

    Ertem, Funda Cansu; Martínez-Blanco, Julia; Finkbeiner, Matthias; Neubauer, Peter; Junne, Stefan

    2016-11-01

    This paper analyses concepts to facilitate a demand oriented biogas supply at an agricultural biogas plant of a capacity of 500kWhel, operated with the co-digestion of maize, grass, rye silage and chicken manure. In contrast to previous studies, environmental impacts of flexible and the traditional baseload operation are compared. Life Cycle Assessment (LCA) was performed to detect the environmental impacts of: (i) variety of feedstock co-digestion scenarios by substitution of maize and (ii) loading rate scenarios with a focus on flexible feedstock utilization. Demand-driven biogas production is critical for an overall balanced power supply to the electrical grid. It results in lower amounts of emissions; feedstock loading rate scenarios resulted in 48%, 20%, 11% lower global warming (GWP), acidification (AP) and eutrophication potentials, and a 16% higher cumulative energy demand. Substitution of maize with biogenic-waste regarding to feedstock substitution scenarios could create 10% lower GWP and AP.

  3. Two-Stage Conversion of Land and Marine Biomass for Biogas and Biohydrogen Production

    OpenAIRE

    Nkemka, Valentine

    2012-01-01

    The replacement of fossil fuels by renewable fuels such as biogas and biohydrogen will require efficient and economically competitive process technologies together with new kinds of biomass. A two-stage system for biogas production has several advantages over the widely used one-stage continuous stirred tank reactor (CSTR). However, it has not yet been widely implemented on a large scale. Biohydrogen can be produced in the anaerobic two-stage system. It is considered to be a useful fuel for t...

  4. Effects of cycle-frequency and temperature on the performance of anaerobic sequencing batch reactors (ASBRs) treating swine waste.

    Science.gov (United States)

    Ndegwa, P M; Hamilton, D W; Lalman, J A; Cumba, H J

    2008-04-01

    Anaerobic digestion of animal waste is a technically viable process for the abatement of adverse environmental impacts caused by animal wastes; however, widespread acceptance has been plagued by poor economics. This situation is dismal if the technology is adapted for treating low strength animal slurries because of large digester-volume requirements and a corresponding high energy input. A possible technology to address these constraints is the anaerobic sequencing batch reactor (ASBR). The ASBR technology has demonstrated remarkable potential to improve the economics of treating dilute animal waste effluents. This paper presents preliminary data on the effects of temperature and frequency-cycle on the operation of an ASBR at a fixed hydraulic retention time (HRT). The results suggest that within the parameter range under consideration, temperature did not affect the biogas yield significantly, however, higher cycle-frequency had a negative effect. The biogas quality (%CH(4)) was not significantly affected by temperature nor by the cycle-frequency. The operating principle of the ASBR follows four phases: feed, react, settle, and decant in a cyclic mode. To improve the biogas production in an ASBR, one long react-phase was preferable compared to three shorter react-phases. Treatment of dilute manure slurries in an ASBR at 20 degrees C was more effective than at 35 degrees C; similarly more bio-stable effluents were obtained at low cycle-frequency. The treatment of dilute swine slurries in an ASBR at the lower temperature (20 degrees C) and lower cycle-frequency is, therefore, recommended for the bio-stabilization of dilute swine wastewaters. The results also indicate that significantly higher VFA degradation occurred at 20 degrees C than at 35 degrees C, suggesting that the treatment of dilute swine slurries in ASBRs for odor control might be more favorable at the lower than at the higher temperatures examined in this study. Volatile fatty acid reduction at the two

  5. Reviewing real-time performance of nuclear reactor safety systems

    Energy Technology Data Exchange (ETDEWEB)

    Preckshot, G.G. [Lawrence Livermore National Lab., CA (United States)

    1993-08-01

    The purpose of this paper is to recommend regulatory guidance for reviewers examining real-time performance of computer-based safety systems used in nuclear power plants. Three areas of guidance are covered in this report. The first area covers how to determine if, when, and what prototypes should be required of developers to make a convincing demonstration that specific problems have been solved or that performance goals have been met. The second area has recommendations for timing analyses that will prove that the real-time system will meet its safety-imposed deadlines. The third area has description of means for assessing expected or actual real-time performance before, during, and after development is completed. To ensure that the delivered real-time software product meets performance goals, the paper recommends certain types of code-execution and communications scheduling. Technical background is provided in the appendix on methods of timing analysis, scheduling real-time computations, prototyping, real-time software development approaches, modeling and measurement, and real-time operating systems.

  6. A Comparison of Photocatalytic Oxidation Reactor Performance for Spacecraft Cabin Trace Contaminant Control Applications

    Science.gov (United States)

    Perry, Jay L.; Frederick, Kenneth R.; Scott, Joseph P.; Reinermann, Dana N.

    2011-01-01

    Photocatalytic oxidation (PCO) is a maturing process technology that shows potential for spacecraft life support system application. Incorporating PCO into a spacecraft cabin atmosphere revitalization system requires an understanding of basic performance, particularly with regard to partial oxidation product production. Four PCO reactor design concepts have been evaluated for their effectiveness for mineralizing key trace volatile organic com-pounds (VOC) typically observed in crewed spacecraft cabin atmospheres. Mineralization efficiency and selectivity for partial oxidation products are compared for the reactor design concepts. The role of PCO in a spacecraft s life support system architecture is discussed.

  7. Initial in-reactor performance of the Cornell cold neutron source

    Energy Technology Data Exchange (ETDEWEB)

    Spern, S.A.; Clark, D.D.; Atwood, A.G. [Cornell Univ., Ithaca, NY (United States)

    1996-12-31

    The Cornell Cold Neutron Beam Facility consists of two major subsystems, a cold neutron source (CNS) and a 13-m-long curved neutron guide. This paper describes the initial in-reactor performance tests of the CNS. The results agree closely with predictions from out-of-reactor tests and meet the design criteria for safety and simplicity of operation. This phase of the project has therefore been completed. Three meters of neutron guide were in place during these tests, and a preliminary evaluation of neutronic properties is also presented.

  8. Biogas production from solid pineapple waste

    Energy Technology Data Exchange (ETDEWEB)

    Tanticharoen, M.; Bhumiratana, S.; Tientanacom, S.; Pengsobha, L.

    1984-01-01

    Solid pineapple waste composed of shell and core was used as substrate in anaerobic fermentation producing CH4. The experiments were carried out using four 30-L vessels and no mixing, a 200-L plug-flow reactor, and a 5-cubic m stirred tank. Because of high acidity of the substrate, the loading rate is as low as 2.5 g dry solid added/L-day. The average gas yield is 0.3-0.5 L/g dry substrate. A pretreatment of wet solid with sludge effluent prior loading to the digester resulted in better stability of the biodigester than without pretreatment. These studies showed that loading rate can be much higher than those previously used. The 2-stage process was tested to determine a conversion efficiency of high loading and at much shorter reactor retention times. The results of the entire program indicated that biogas production from cannery pineapple waste is technically feasible.

  9. [Effects of the size of magnetic particles of immobilized enzyme reactors on the digestion performance].

    Science.gov (United States)

    Zhang, Jiao; Zhou, Lianqi; Tian, Fang; Zhang, Yangjun; Qian, Xiaohong

    2013-02-01

    We applied immobilized enzyme reactors prepared with different sizes of magnetic particles into protein and proteome digestion. In addition, the influences of different sizes of the magnetic particles were studied on the reunion, enzyme efficiency and leakage sites. The experimental results showed that in comparison with the submicron magnetic particles, the amount of trypsin immobilized on the magnetic nanoparticles was 3. 5 times more than that of the submicron magnetic particles. However, the enzymatic efficiency was at the same level when the same amount of trypsin was used, and the reunion phenomenon was obviously improved when the size of the magnetic nanoparticles increased. Taking the immobilized enzyme reactor of 20 nm magnetic nanoparticles as an example, the digestion performance was further examined. The experimental results showed that rapid digestion could be achieved within 1 mm when the mass ratio of the trypsin and bovine serum albumin was 1:1. The peptide number of 0 missed cleavage site and the sequence coverage changed little after the protein was digested for 10 mm. It was concluded that the digestion efficiency of the immobilized enzyme reactor was much better than that of the in-solution digestion. When the immobilized enzyme reactors and the free trypsin were used for digestion, little differences of the leakage sites were found. Therefore, the immobilized enzyme reactors prepared with different sizes of magnetic particles can be applied in proteomic research for quick and efficient digestion.

  10. Profile and Perceptions of Biogas as Automobile Fuel : A Study of Svensk Biogas

    OpenAIRE

    Larsson, Anneli

    2008-01-01

    From an environmental- and health perspective, biogas and other biomass-based fuels have several advantages; nevertheless the majority of motorists fill their cars with petroleum-based fuels. This thesis is designed to explore the profile of biogas in relation to its perceptions. It is a study concerning the communication between the biogas producing company Svensk Biogas and their biogas users and non biogas users. To obtain a thorough understanding of the profile and perceptions of biogas a...

  11. Biogas Opportunities Roadmap Progress Report

    Energy Technology Data Exchange (ETDEWEB)

    None, None

    2015-12-01

    In support of the Obama Administration's Climate Action Plan, the U.S. Department of Energy, the U.S. Environmental Protection Agency, and U.S. Department of Agriculture jointly released the Biogas Opportunities Roadmap Progress Report, updating the federal government's progress to reduce methane emissions through biogas systems since the Biogas Opportunities Roadmap was completed by the three agencies in July 2014. The report highlights actions taken, outlines challenges and opportunities, and identifies next steps to the growth of a robust biogas industry.

  12. Bioelectrochemical removal of carbon dioxide (CO2): an innovative method for biogas upgrading.

    Science.gov (United States)

    Xu, Heng; Wang, Kaijun; Holmes, Dawn E

    2014-12-01

    Innovative methods for biogas upgrading based on biological/in-situ concepts have started to arouse considerable interest. Bioelectrochemical removal of CO2 for biogas upgrading was proposed here and demonstrated in both batch and continuous experiments. The in-situ biogas upgrading system seemed to perform better than the ex-situ one, but CO2 content was kept below 10% in both systems. The in-situ system's performance was further enhanced under continuous operation. Hydrogenotrophic methanogenesis and alkali production with CO2 absorption could be major contributors to biogas upgrading. Molecular studies showed that all the biocathodes associated with biogas upgrading were dominated by sequences most similar to the same hydrogenotrophic methanogen species, Methanobacterium petrolearium (97-99% sequence identity). Conclusively, bioelectrochemical removal of CO2 showed great potential for biogas upgrading.

  13. Performance Test of System Identification Methods for a Nuclear Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Yu, Keuk Jong; Kim, Han Gon [KHNP, Daejeon (Korea, Republic of)

    2011-05-15

    An automatic controller that uses the model predictive control (MPC) method is being developed for automatic load follow operation. As described in Ref. a system identification method is important in the MPC method because MPC is based on a system model produced by system identification. There are many models and methods of system identification. In this study, AutoRegressive eXogenous (ARX) model was selected from among them, and the recursive least square (RLS) method and least square (LS) method associated with this model are used in a comparative performance analysis

  14. Effect of Different Structural Materials on Neutronic Performance of a Hybrid Reactor

    Science.gov (United States)

    Übeyli, Mustafa; Tel, Eyyüp

    2003-06-01

    Selection of structural material for a fusion-fission (hybrid) reactor is very important by taking into account of neutronic performance of the blanket. Refractory metals and alloys have much higher operating temperatures and neutron wall load (NWL) capabilities than low activation materials (ferritic/martensitic steels, vanadium alloys and SiC/SiC composites) and austenitic stainless steels. In this study, effect of primary candidate refractory alloys, namely, W-5Re, T111, TZM and Nb-1Zr on neutronic performance of the hybrid reactor was investigated. Neutron transport calculations were conducted with the help of SCALE 4.3 System by solving the Boltzmann transport equation with code XSDRNPM. Among the investigated structural materials, tantalum had the worst performance due to the fact that it has higher neutron absorption cross section than others. And W-5Re and TZM having similar results showed the best performance.

  15. Use of biogas for cogeneration of heat and electricity for local application: performance evaluation of an engine power generator and a sludge thermal dryer.

    Science.gov (United States)

    Lobato, L C S; Chernicharo, C A L; Pujatti, F J P; Martins, O M; Melo, G C B; Recio, A A R

    2013-01-01

    A small unit of cogeneration of energy and heat was tested at the Centre for Research and Training on Sanitation UFMG/COPASA - CePTS, located at the Arrudas Sewage Treatment Plant, in Belo Horizonte, Minas Gerais, Brazil. The unit consisted of an engine power generator adapted to run on biogas, a thermal dryer prototype and other peripherals (compressor, biogas storage tank, air blower, etc.). The heat from engine power generator exhaust gases was directed towards the thermal dryer prototype to dry the sludge and disinfect it. The results showed that the experimental apparatus is self-sufficient in electricity, even producing a surplus, available for other uses. The tests of drying and disinfection of sludge lasted 7 h, leading to an increase in solids content from 4 to 8% (50% reduction in sludge volume). Although the drying of sludge was not possible (only thickening was achieved), the disinfection process proved very effective, enabling the complete inactivation of helminth eggs.

  16. Performance of static var compensator control type thyristor controlled reactor and thyristor switched capacitor

    Energy Technology Data Exchange (ETDEWEB)

    Araujo, Josias M. de; Yung, Chou Shaw; Rose, Eber H.; Pantoja, Antonio L.A. [ELETRONORTE, Belem, PA (Brazil); Fouesnant, Thomas; Boissier, Luc

    1994-12-31

    This paper has the objective of presenting the philosophy of Static Var Compensator (SVC) Control as well the necessary adjustments in the project of control system to guarantee suitable performance under different operating conditions. The verification on the performance of the SVC control has been done by Transient Network Analyzer (TNA/CEPEL) studies, commissioning tests and a factory tests. The SVC is the type of Thyristor Controlled Reactor (TCR) and Thyristor Switched Capacitor (TSC). (author) 3 refs., 12 figs.

  17. PRELIMINARY STUDY ON BIOGAS PRODUCTION OF BIOGAS FROM MUNICIPAL SOLID WASTE (MSW LEACHATE

    Directory of Open Access Journals (Sweden)

    WAN AZLINA WAN AB KARIM GHANI

    2009-12-01

    Full Text Available Laboratory-scale digesters were operated to study the effect of leachate chemical oxygen demand strength on biogas (methane production. Three sets of experiment were performed using municipal solid waste leachate slurry with two different chemical oxygen demand strength strengths namely 3000 and 21000 mg/L (referred as low and high strength, respectively. The experiments were conducted at a controlled temperature of 35°C and pH ranging from 6.8 to 7.3 over 20 days period. The process performance was evaluated based on the biogas production and pollutants removal efficiencies. Results showed that the high and low strength samples performed quite similarly but with different biogas production rate observed. The biochemical oxygen demand in the effluent removed up to 80%, but the performance of other parameters such as chemical oxygen demand, total suspended solid and volatile suspended solid was slightly decreased which contributes 33 to 46%, 21 to 37% and 20 to 35%, respectively. From this study, it can be concluded that this method not only contributed to renewable biogas production but also improved the effluent quality.

  18. Evaluation of Heavy Metals Influence on Biogas Production

    Directory of Open Access Journals (Sweden)

    Ernestas Zaleckas

    2013-01-01

    Full Text Available Heavy metals play a very significant role in the performance and stability of biogas digesters, which are operated with organic fraction of municipal solid wastes or any other type of organic waste. For this reason this paper tries to evaluate the impact of heavy metals on biogas yield and quality. Anaerobic digestion of sewage sludge and rapeseed cake mixture has been carried out for 14 days. The obtained data show that the greatest negative impact on biogas production was made by zinc additive. Meanwhile, methane content in biogas varied from 64.5 to 70%.DOI: http://dx.doi.org/10.5755/j01.erem.62.4.2040

  19. Performance of low smeared density sodium-cooled fast reactor metal fuel

    Science.gov (United States)

    Porter, D. L.; Chichester, H. J. M.; Medvedev, P. G.; Hayes, S. L.; Teague, M. C.

    2015-10-01

    An experiment was performed in the Experimental Breeder Rector-II (EBR-II) in the 1990s to show that metallic fast reactor fuel could be used in reactors with a single, once-through core. To prove the long duration, high burnup, high neutron exposure capability an experiment where the fuel pin was designed with a very large fission gas plenum and very low fuel smeared density (SD). The experiment, X496, operated to only 8.3 at.% burnup because the EBR-II reactor was scheduled for shut-down at that time. Many of the examinations of the fuel pins only funded recently with the resurgence of reactor designs using very high-burnup fuel. The results showed that, despite the low smeared density of 59% the fuel swelled radially to contact the cladding, fission gas release appeared to be slightly higher than demonstrated in conventional 75%SD fuel tests and axial growth was about the same as 75% SD fuel. There were axial positions in some of the fuel pins which showed evidence of fuel restructuring and an absence of fission products with low melting points and gaseous precursors (Cs and Rb). A model to investigate whether these areas may have overheated due to a loss of bond sodium indicates that it is a possible explanation for the fuel restructuring and something to be considered for fuel performance modeling of low SD fuel.

  20. Improvement of Membrane Performances to Enhance the Yield of Vanillin in a Pervaporation Reactor

    Directory of Open Access Journals (Sweden)

    Giovanni Camera-Roda

    2014-02-01

    Full Text Available In membrane reactors, the interaction of reaction and membrane separation can be exploited to achieve a “process intensification”, a key objective of sustainable development. In the present work, the properties that the membrane must have to obtain this result in a pervaporation reactor are analyzed and discussed. Then, the methods to enhance these properties are investigated for the photocatalytic synthesis of vanillin, which represents a case where the recovery from the reactor of vanillin by means of pervaporation while it is produced allows a substantial improvement of the yield, since its further oxidation is thus prevented. To this end, the phenomena that control the permeation of both vanillin and the reactant (ferulic acid are analyzed, since they ultimately affect the performances of the membrane reactor. The results show that diffusion of the aromatic compounds takes place in the presence of low concentration gradients, so that the process is controlled by other phenomena, in particular by the equilibrium with the vapor at the membrane-permeate interface. On this basis, it is demonstrated that the performances are enhanced by increasing the membrane thickness and/or the temperature, whereas the pH begins to limit the process only at values higher than 6.5.

  1. Improvement of membrane performances to enhance the yield of vanillin in a pervaporation reactor.

    Science.gov (United States)

    Camera-Roda, Giovanni; Cardillo, Antonio; Loddo, Vittorio; Palmisano, Leonardo; Parrino, Francesco

    2014-02-28

    In membrane reactors, the interaction of reaction and membrane separation can be exploited to achieve a "process intensification", a key objective of sustainable development. In the present work, the properties that the membrane must have to obtain this result in a pervaporation reactor are analyzed and discussed. Then, the methods to enhance these properties are investigated for the photocatalytic synthesis of vanillin, which represents a case where the recovery from the reactor of vanillin by means of pervaporation while it is produced allows a substantial improvement of the yield, since its further oxidation is thus prevented. To this end, the phenomena that control the permeation of both vanillin and the reactant (ferulic acid) are analyzed, since they ultimately affect the performances of the membrane reactor. The results show that diffusion of the aromatic compounds takes place in the presence of low concentration gradients, so that the process is controlled by other phenomena, in particular by the equilibrium with the vapor at the membrane-permeate interface. On this basis, it is demonstrated that the performances are enhanced by increasing the membrane thickness and/or the temperature, whereas the pH begins to limit the process only at values higher than 6.5.

  2. The Denitrifying Biological Phosphorus Removal Performance in Anaerobic/Anoxic Sequencing Batch Reactor: The Effect of Carbon Source

    OpenAIRE

    Gürtekin, Engin; ŞEKERDAĞ, Nusret

    2015-01-01

    In this study, the effect of carbon source on denitrifying biological phosphorus removal performance in acetate and glucose fed two anaerobic/anoxic sequencinq batch reactor (SBR) was investigated. Glucose and acetate were used as the substrates. In acetate and glucose fed reactors, the COD (Chemical Oxygen Demand) removal efficiencies were 91,90% and PO4-P removal efficiencies were 87,51% respectively. These results shows that the phosphorus removal efficiency is lower in glucose fed reactor.

  3. Biogas - the calculable energy

    Science.gov (United States)

    Kith, Károly; Nagy, Orsolya; Balla, Zoltán; Tamás, András

    2015-04-01

    EU actions against climate change are rising energy prices, both have emphasized the use of renewable energy,increase investments and energy efficiency. A number of objectives formulated in the EC decree no. 29/2009 by 2020. This document is based on the share of renewable energies in energy consumption should be increased to 20% (EC, 2009). The EU average is 20% but the share of renewables vary from one member state to another. In Hungary in 2020, 14.65% renewable energy share is planned to be achieved. According to the latest Eurostat data, the share of renewable energy in energy consumption of the EU average was 14.1%, while in Hungary, this share was 9.6% in 2012. (EUROSTAT, 2014). The use of renewable energy plant level is influenced by several factors. The most important of these is the cost savings and efficiency gains. Hungarian investments in renewable energy production usually have high associated costs and the payback period is substantially more than five years, depending on the support rate. For example, the payback period is also influenced by the green electricity generated feed prices, which is one of the lowest in Hungary compared the Member States of the European Union. Consequently, it is important to increase the production of green energy. Nowadays, predictable biogas energy is an outstanding type of decentralized energy production. It follows directly that agricultural by-products can be used to produce energy and they also create jobs by the construction of a biogas plant. It is important to dispose of and destroy hazardous and noxious substances in energy production. It follows from this that the construction of biogas plants have a positive impact, in addition to green energy which is prepared to reduce the load on the environment. The production of biogas and green electricity is one of the most environment friendly forms of energy production. Biogas production also has other important ecological effects, such as the substitution of

  4. Physicochemical and Microbial Caracteristics Performency in Wastewater Treated Under Aerobic Reactor

    Directory of Open Access Journals (Sweden)

    Asma B. Rajeb

    2011-01-01

    Full Text Available Problem statement: The current work study the efficiency of biological wastewater treatment by an aerobic reactor which could be used in small agglomerations. RBC reduced physicochemical and microbiological load of wastewater but values remain above Tunisian standard. Approach: Experiments were conducted on a sand filled PVC column fed with wastewater treated by Rotating Biological Contactor (RBC at a pulsed rhythm of 8 sequences per day. For performances study process, physicochemical and bacterial analyses effluent at inlet and outlet of column were realized. Results: The results showed that through filter mass (D10 = 0.55 mm, D60 = 1.3 mm and coefficient uniformity = 2.36 96% of suspended solids, 99% of NH4 +-N (during first phase, 92% of COD, 91% of BOD5 and 46% of phosphorus are retained by surface filtration. The microbial abatement results is E. coli. The microbial water quality is slightly higher than Tunisian standards. The removal of microbial indicators in the considered reactor depends on the depth of the filter and negatively correlated with NO3 --N (r = -0.99, with E. coli at 3rd OPD. Conclusion/Recommendation: Results confirmed that the reactor tested is performed as an advanced treatment system for DBO, COD, SS, NH4 +-N and NO3 --N. Despite that 96% of SS efficiency reduction, clogging is not achieved quickly that due to biofilm detachment phenomena. The removal of microbial indicators in the considered reactor depends on the depth of the filter and negatively correlated with NO3 --N. Disinfection performances for the considered reactor reduce microbial load, however chlore, ozone or UV disinfection should be considered.

  5. Application of a real-time qPCR method to measure the methanogen concentration during anaerobic digestion as an indicator of biogas production capacity.

    Science.gov (United States)

    Traversi, Deborah; Villa, Silvia; Lorenzi, Eugenio; Degan, Raffaella; Gilli, Giorgio

    2012-11-30

    Biogas is an energy source that is produced via the anaerobic digestion of various organic materials, including waste-water sludge and organic urban wastes. Among the microorganisms involved in digestion, methanogens are the major microbiological group responsible for methane production. To study the microbiological equilibrium in an anaerobic reactor, we detected the methanogen concentration during wet digestion processes fed with pre-treated urban organic waste and waste-water sludge. Two different pre-treatments were used in successive experimental digestions: pressure-extrusion and turbo-mixing. Chemical parameters were collected to describe the process and its production. The method used is based on real-time quantitative PCR (RT-qPCR) with the functional gene mcrA as target. First, we evaluated the validity of the analyses. Next, we applied this method to 50 digestate samples and then we performed a statistical analysis. A positive and significant correlation between the biogas production rate and methanogen abundance was observed (r = 0.579, p production rate above than of 0.6 m(3) biogas/kg TVS (F = 7.053; p < 0.05). The applied method is suitable to describe microbiome into the anaerobic reactor, moreover methanogen concentration may have potential for use as a digestion optimisation tool.

  6. Two-phase anaerobic digestion of vegetable market waste fraction of municipal solid waste and development of improved technology for phase separation in two-phase reactor.

    Science.gov (United States)

    Majhi, Bijoy Kumar; Jash, Tushar

    2016-12-01

    Biogas production from vegetable market waste (VMW) fraction of municipal solid waste (MSW) by two-phase anaerobic digestion system should be preferred over the single-stage reactors. This is because VMW undergoes rapid acidification leading to accumulation of volatile fatty acids and consequent low pH resulting in frequent failure of digesters. The weakest part in the two-phase anaerobic reactors was the techniques applied for solid-liquid phase separation of digestate in the first reactor where solubilization, hydrolysis and acidogenesis of solid organic waste occur. In this study, a two-phase reactor which consisted of a solid-phase reactor and a methane reactor was designed, built and operated with VMW fraction of Indian MSW. A robust type filter, which is unique in its implementation method, was developed and incorporated in the solid-phase reactor to separate the process liquid produced in the first reactor. Experiments were carried out to assess the long term performance of the two-phase reactor with respect to biogas production, volatile solids reduction, pH and number of occurrence of clogging in the filtering system or choking in the process liquid transfer line. The system performed well and was operated successfully without the occurrence of clogging or any other disruptions throughout. Biogas production of 0.86-0.889m(3)kg(-1)VS, at OLR of 1.11-1.585kgm(-3)d(-1), were obtained from vegetable market waste, which were higher than the results reported for similar substrates digested in two-phase reactors. The VS reduction was 82-86%. The two-phase anaerobic digestion system was demonstrated to be stable and suitable for the treatment of VMW fraction of MSW for energy generation.

  7. Irradiation performance of AGR-1 high temperature reactor fuel

    Energy Technology Data Exchange (ETDEWEB)

    Paul A. Demkowicz; John D. Hunn; Robert N. Morris; Charles A. Baldwin; Philip L. Winston; Jason M. Harp; Scott A. Ploger; Tyler Gerczak; Isabella J. van Rooyen; Fred C. Montgomery; Chinthaka M. Silva

    2014-10-01

    The AGR-1 experiment contained 72 low-enriched uranium oxide/uranium carbide TRISO-coated particle fuel compacts in six capsules irradiated to burnups of 11.2 to 19.5% FIMA, with zero TRISO coating failures detected during the irradiation. The irradiation performance of the fuel–including the extent of fission product release and the evolution of kernel and coating microstructures–was evaluated based on detailed examination of the irradiation capsules, the fuel compacts, and individual particles. Fractional release of 110mAg from the fuel compacts was often significant, with capsule-average values ranging from 0.01 to 0.38. Analysis of silver release from individual compacts indicated that it was primarily dependent on fuel temperature history. Europium and strontium were released in small amounts through intact coatings, but were found to be significantly retained in the outer pyrocrabon and compact matrix. The capsule-average fractional release from the compacts was 1×10 4 to 5×10 4 for 154Eu and 8×10 7 to 3×10 5 for 90Sr. The average 134Cs release from compacts was <3×10 6 when all particles maintained intact SiC. An estimated four particles out of 2.98×105 experienced partial cesium release due to SiC failure during the irradiation, driving 134Cs release in two capsules to approximately 10 5. Identification and characterization of these particles has provided unprecedented insight into the nature and causes of SiC coating failure in high-quality TRISO fuel. In general, changes in coating morphology were found to be dominated by the behavior of the buffer and inner pyrolytic carbon (IPyC), and infrequently observed SiC layer damage was usually related to cracks in the IPyC. Palladium attack of the SiC layer was relatively minor, except for the particles that released cesium during irradiation, where SiC corrosion was found adjacent to IPyC cracks. Palladium, silver, and uranium were found in the SiC layer of irradiated particles, and characterization

  8. Estimation of biogas and methane yields in an UASB treating potato starch processing wastewater with backpropagation artificial neural network.

    Science.gov (United States)

    Antwi, Philip; Li, Jianzheng; Boadi, Portia Opoku; Meng, Jia; Shi, En; Deng, Kaiwen; Bondinuba, Francis Kwesi

    2017-03-01

    Three-layered feedforward backpropagation (BP) artificial neural networks (ANN) and multiple nonlinear regression (MnLR) models were developed to estimate biogas and methane yield in an upflow anaerobic sludge blanket (UASB) reactor treating potato starch processing wastewater (PSPW). Anaerobic process parameters were optimized to identify their importance on methanation. pH, total chemical oxygen demand, ammonium, alkalinity, total Kjeldahl nitrogen, total phosphorus, volatile fatty acids and hydraulic retention time selected based on principal component analysis were used as input variables, whiles biogas and methane yield were employed as target variables. Quasi-Newton method and conjugate gradient backpropagation algorithms were best among eleven training algorithms. Coefficient of determination (R(2)) of the BP-ANN reached 98.72% and 97.93% whiles MnLR model attained 93.9% and 91.08% for biogas and methane yield, respectively. Compared with the MnLR model, BP-ANN model demonstrated significant performance, suggesting possible control of the anaerobic digestion process with the BP-ANN model.

  9. Biogas production and microbial community shift through neutral pH control during the anaerobic digestion of pig manure.

    Science.gov (United States)

    Zhou, Jun; Zhang, Rui; Liu, Fenwu; Yong, Xiaoyu; Wu, Xiayuan; Zheng, Tao; Jiang, Min; Jia, Honghua

    2016-10-01

    Laboratory-scale reactors, in which the pH could be auto-adjusted, were employed to investigate the mesophilic methane fermentation with pig manure (7.8% total solids) at pH 6.0, 7.0, and 8.0. Results showed that the performance of anaerobic digestion was strongly dependent on pH value. Biogas production and methane content at neutral pH 7.0 were significantly higher (16,607mL, 51.81%) than those at pH 6.0 (6916mL, 42.9%) and 8.0 (9739mL, 35.6%). Denaturing gradient gel electrophoresis fingerprinting and Shannon's index indicated that the samples contained highly diverse microbial communities. The major genus at pH 7.0 was Methanocorpusculum, compared with that was Methanosarcina at both pH 6.0 and 8.0. Our research revealed that cultures maintained at pH 7.0 could support increased biogas production, which has significant implications for the scale-up biogas engineering.

  10. Nitrogen and phosphorus removal coupled with carbohydrate production by five microalgae cultures cultivated in biogas slurry.

    Science.gov (United States)

    Tan, Fen; Wang, Zhi; Zhouyang, Siyu; Li, Heng; Xie, Youping; Wang, Yuanpeng; Zheng, Yanmei; Li, Qingbiao

    2016-12-01

    In this study, five microalgae strains were cultured for their ability to survive in biogas slurry, remove nitrogen resources and accumulate carbohydrates. It was proved that five microalgae strains adapted in biogas slurry well without ammonia inhibition. Among them, Chlorella vulgaris ESP-6 showed the best performance on carbohydrate accumulation, giving the highest carbohydrate content of 61.5% in biogas slurry and the highest ammonia removal efficiency and rate of 96.3% and 91.7mg/L/d respectively in biogas slurry with phosphorus and magnesium added. Additionally, the absence of phosphorus and magnesium that can be adverse for biomass accumulation resulted in earlier timing of carbohydrate accumulation and magnesium was firstly recognized and proved as the influence factor for carbohydrate accumulation. Microalgae that cultured in biogas slurry accumulated more carbohydrate in cell, making biogas slurry more suitable medium for the improvement of carbohydrate content, thus can be regarded as a new strategy to accumulate carbohydrate.

  11. Comparative performance of fixed-film biological filters: Application of reactor theory

    Science.gov (United States)

    Watten, B.J.; Sibrell, P.L.

    2006-01-01

    Nitrification is classified as a two-step consecutive reaction where R1 represents the rate of formation of the intermediate product NO2-N and R2 represents the rate of formation of the final product NO3-N. The relative rates of R1 and R2 are influenced by reactor type characterized hydraulically as plug-flow, plug-flow with dispersion and mixed-flow. We develop substrate conversion models for fixed-film biofilters operating in the first-order kinetic regime based on application of chemical reactor theory. Reactor type, inlet conditions and the biofilm kinetic constants Ki (h-1) are used to predict changes in NH4-N, NO2-N, NO3-N and BOD5. The inhibiting effects of the latter on R1 and R2 were established based on the ?? relation, e.g.:{A formula is presented}where BOD5,max is the concentration that causes nitrification to cease and N is a variable relating Ki to increasing BOD5. Conversion models were incorporated in spreadsheet programs that provided steady-state concentrations of nitrogen and BOD5 at several points in a recirculating aquaculture system operating with input values for fish feed rate, reactor volume, microscreen performance, make-up and recirculating flow rates. When rate constants are standardized, spreadsheet use demonstrates plug-flow reactors provide higher rates of R1 and R2 than mixed-flow reactors thereby reducing volume requirements for target concentrations of NH4-N and NO2-N. The benefit provided by the plug-flow reactor varies with hydraulic residence time t as well as the effective vessel dispersion number, D/??L. Both reactor types are capable of providing net increases in NO2-N during treatment but the rate of decrease in the mixed-flow case falls well behind that predicted for plug-flow operation. We show the potential for a positive net change in NO2-N increases with decreases in the dimensionless ratios K2, (R2 )/K1,( R1 ) and [NO2-N]/[NH4-N] and when the product K1, (R1) t provides low to moderate NH4-N conversions. Maintaining

  12. Thermal performance of over-ground household biogas production system heated by solar energy%太阳能加热的地上式户用沼气生产系统热性能分析

    Institute of Scientific and Technical Information of China (English)

    冯荣; 李金平; 李修真; 杨捷媛

    2015-01-01

    Household biogas is widely used in rural areas of China because it is clean, convenient and renewable energy, and the temperature of slurry in biogas digester is one of the most important factors on the biogas production. It has been proved that heating the biogas digester by solar energy is an effective manner to improve the biogas production performance of digester in winter, and many scholars have researched the thermal performance of heating the biogas digester by solar energy. The new type over-ground household biogas digester has been researched and developed successfully by Lanzhou University of Technology, which can be applied in most areas of China. In this paper, the thermal performance of the new type household biogas production system was experimentally studied in order to provide guidance for the design optimization and promotion of this type of system, which mainly included the heat collection efficiency of vacuum-tube solar water heater, the heat loss of digester and the heat transfer coefficient between hot water and slurry. The new type of system had been constructed completely in November, 2014 in a farmer family in a village of Minqin County, Gansu Province, including an vacuum-tube solar water heater with 3.85 m2 heat-collecting area which consisted of 40 vacuum tubes made of glass, an insulating room of 1.9 m × 1.9 m × 2.6 m, a rheid biogas digester of 1.6 m × 1.6 m × 2.5 m, a temperature controller, a circulating pump and other devices. After feeding 1.73 m3 slurry to the digester, the test had been done from December 1st to December 22nd, 2014, and the following parameters were measured: solar radiation on the collection face of solar water heater, hot water temperature in solar water heater’s storage, ambient temperature, slurry temperature in digester, inlet and outlet temperature of heat pipe and hot water flow rate in heat pipe, which were recorded by the computer automatically. Else, in order to avoid reducing the activity of

  13. Technological assumptions for biogas purification.

    Science.gov (United States)

    Makareviciene, Violeta; Sendzikiene, Egle

    2015-01-01

    Biogas can be used in the engines of transport vehicles and blended into natural gas networks, but it also requires the removal of carbon dioxide, hydrogen sulphide, and moisture. Biogas purification process flow diagrams have been developed for a process enabling the use of a dolomite suspension, as well as for solutions obtained by the filtration of the suspension, to obtain biogas free of hydrogen sulphide and with a carbon dioxide content that does not exceed 2%. The cost of biogas purification was evaluated on the basis of data on biogas production capacity and biogas production cost obtained from local water treatment facilities. It has been found that, with the use of dolomite suspension, the cost of biogas purification is approximately six times lower than that in the case of using a chemical sorbent such as monoethanolamine. The results showed travelling costs using biogas purified by dolomite suspension are nearly 1.5 time lower than travelling costs using gasoline and slightly lower than travelling costs using mineral diesel fuel.

  14. Continuous dry fermentation of swine manure for biogas production

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Chuang; Zheng, Dan [Biogas Institute of Ministry of Agriculture, Chengdu 610041 (China); Liu, Gang–Jin [Biogas Institute of Ministry of Agriculture, Chengdu 610041 (China); Bioprocess Control AB, Scheelevägen 22, 223 63 Lund (Sweden); Deng, Liang–Wei, E-mail: dengliangwei@caas.cn [Biogas Institute of Ministry of Agriculture, Chengdu 610041 (China); Laboratory of Development and Application of Rural Renewable Energy, Ministry of Agriculture, Chengdu 610041 (China); Southwest Collaborative Innovation Center of Swine for Quality & Safety, Chengdu 611130 (China); Long, Yan; Fan, Zhan–Hui [Biogas Institute of Ministry of Agriculture, Chengdu 610041 (China)

    2015-04-15

    Highlights: • Continuous dry fermentation of swine manure for biogas production is feasible. • The feedstock TS concentration exerted a significant impact on biogas production. • Influences of ammonia and digestate liquidity were investigated in this study. • The results showed that the feedstock TS of swine manure should not exceed 30%. - Abstract: A down plug-flow anaerobic reactor (DPAR) was designed for the feasibility study on continuous dry fermentation of swine manure without any additional stirring. Using fresh swine manure as the feedstock with TS concentration (w/w) of 20%, 25%, 30%, and 35%, stable volumetric biogas production rates of 2.40, 1.92, 0.911, and 0.644 L·(L d){sup −1} and biogas yields of 0.665, 0.532, 0.252, and 0.178 L g{sup −1}VS were obtained respectively, and the TS degradation rates were 46.5%, 45.4%, 53.2%, and 55.6%, respectively. With the increase of feedstock TS concentration, the concentration of ammonia nitrogen grew up to the maximum value of 3500 mg L{sup −1}. Biogas production was obviously inhibited when the concentration of ammonia nitrogen was above 3000 mg L{sup −1}. The maximal volumetric biogas production rate of 2.34 L·(L d){sup −1} and biogas yield of 0.649 L g{sup −1}VS were obtained with TS concentration of 25% at 25 °C without inhibition. Liquidity experiments showed that TS concentration of digestate could be less than 15.8%, and the flow rate of digestate more than 0.98 m s{sup −1} when the feedstock TS concentration was less than 35%, which indicated the digestate could be easily discharged from a DPAR. Therefore, it is feasible to conduct a continuous dry fermentation in a DPAR using fresh swine manure as the feedstock with TS concentration less than 35%, whereas the feedstock TS concentration should not exceed 30% to achieve the maximal biogas production rate and biogas yield.

  15. Preliminary Assessment of a Debris Bed Cooling Performance for Demonstration Sodium-cooled Fast Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Cho, Chung Ho; Park, Chang Gyu; Song, Hoon; Kim, Young Gyun; Jeong, Hae Yong; Chang, Jin Wook [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2012-05-15

    In the case of the sodium-cooled fast reactor such as KALIMER-600, Hypothetical Core Disruptive Accident (HCDA) attributed from mass nuclear fuel melting is unlikely to occur due to defense in depth concepts to meet requirements of redundancy and diversity. Multiple faults such as loss of flow, loss of heat sink, or transient overpower without scram are to lead rising the power level until cladding failure as reactivity increasing. The fact that metallic fuel melts at a lower temperature than the cladding allows significant in-pin- fuel motion to occur prior to cladding failure. Also, the combination of Doppler and axial expansion feedback and negative feedback associated with the in-pin fuel relocation prevents the reactivity from reaching prompt critical. Finally, the resulting reactivity and power reductions help prevent fuel temperatures from rising more than the fuel melting temperature. It is more difficult to occur HCDA in a metallic fueled core because reactor power and heat removal capability is maintained in balance by inherent safety characteristics However, for the future design of sodium-cooled fast reactor, the evaluation of the safety performance and the determination of containment requirements may be worth considering due to the triple-fault accident sequences of extremely low probability of occurrence that leads to core melting. For any postulated accident sequence which leads to core melting, in-vessel retention of the core debris will be required as a design requirement for the future design of sodium cooled fast reactor. Also, proof of the capacity of the debris bed cooling is an essential condition to solve the problem of in-vessel retention of the core debris. Accordingly, evaluation of a packed debris bed cooling performance with single phase flow for demonstration sodium-cooled fast reactor was carried out for proof of the in-vessel retention of the core debris

  16. Pressure-accelerated azide-alkyne cycloaddition: micro capillary versus autoclave reactor performance.

    Science.gov (United States)

    Borukhova, Svetlana; Seeger, Andreas D; Noël, Timothy; Wang, Qi; Busch, Markus; Hessel, Volker

    2015-02-01

    Pressure effects on regioselectivity and yield of cycloaddition reactions have been shown to exist. Nevertheless, high pressure synthetic applications with subsequent benefits in the production of natural products are limited by the general availability of the equipment. In addition, the virtues and limitations of microflow equipment under standard conditions are well established. Herein, we apply novel-process-window (NPWs) principles, such as intensification of intrinsic kinetics of a reaction using high temperature, pressure, and concentration, on azide-alkyne cycloaddition towards synthesis of Rufinamide precursor. We applied three main activation methods (i.e., uncatalyzed batch, uncatalyzed flow, and catalyzed flow) on uncatalyzed and catalyzed azide-alkyne cycloaddition. We compare the performance of two reactors, a specialized autoclave batch reactor for high-pressure operation up to 1800 bar and a capillary flow reactor (up to 400 bar). A differentiated and comprehensive picture is given for the two reactors and the three methods of activation. Reaction speedup and consequent increases in space-time yields is achieved, while the process window for favorable operation to selectively produce Rufinamide precursor in good yields is widened. The best conditions thus determined are applied to several azide-alkyne cycloadditions to widen the scope of the presented methodology.

  17. Proceedings of the Water Reactor Fuel Performance Meeting - WRFPM / Top Fuel 2009

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2009-06-15

    SFEN, ENS, SNR, ANS, AESJ, CNS KNS, IAEA and NEA are jointly organizing the 2009 International Water Reactor Fuel Performance / TopFuel 2009 Meeting following the 2008 KNS Water Reactor Performance Meeting held during October 19-23, 2008 in Seoul, Korea. This meeting is held annually on a tri-annual rotational basis in Europe, USA and Asia. In 2009, this meeting will be held in Paris, September 6-10, 2009 in coordination with the Global 2009 Conference at the same date and place. That would lead to a common opening session, some common technical presentations, a common exhibition and common social events. The technical scope of the meeting includes all aspects of nuclear fuel from fuel rod to core design as well as manufacturing, performance in commercial and test reactors or on-going and future developments and trends. Emphasis will be placed on fuel reliability in the general context of nuclear 'Renaissance' and recycling perspective. The meeting includes selectively front and/or back end issues that impact fuel designs and performance. In this frame, the conference track devoted to 'Concepts for transportation and interim storage of spent fuels and conditioned waste' will be shared with 'GLOBAL' conference. Technical Tracks: - 1. Fuel Performance, Reliability and Operational Experience: Fuel operating experience and performance; experience with high burn-up fuels; water side corrosion; stress corrosion cracking; MOX fuel performance; post irradiation data on lead fuel assemblies; radiation effects; water chemistry and corrosion counter-measures. - 2. Transient Fuel Behaviour and Safety Related Issues: Transient fuel behavior and criteria (RIA, LOCA, ATWS, Ramp tests..). Fuel safety-related issues such as PCI (pellet cladding interaction), transient fission gas releases and cladding bursting/ballooning during transient events - Advances in fuel performance modeling and core reload methodology, small and large-scale fuel testing

  18. Analysis, evaluation, and optimization of kinetic parameters for performance appraisal and design of UASB reactors.

    Science.gov (United States)

    Bhunia, Puspendu; Ghangrekar, M M

    2008-05-01

    Studies have been undertaken to explore the applicability of different kinetic models for the performance appraisal of upflow anaerobic sludge blanket (UASB) reactors treating wastewater in the range of 300-4000 mg COD/l. Three kinetic models namely, Monod, Grau second-order, and Haldane model are considered for the analysis. Both linear and nonlinear regressions have been performed to examine the best-fit among the kinetic models. In this process, five error analysis methods have been used to analyze the data. Apart from optimization of kinetic coefficients with minimization of associated errors, prediction of effluent COD has also been undertaken to verify the applicability of kinetic models. In both the cases, Grau second-order model is found to be the best class of fit for wide range of data sets in UASB reactor.

  19. Biogas : Animal Waste That Can be Alternative Energy Source

    Directory of Open Access Journals (Sweden)

    Tuti Haryati

    2006-09-01

    Full Text Available Biogas is a renewable energy which can be used as alternative fuel to replace fossil fuel such as oil and natural gas . Recently, diversification on the use of energy has increasingly become an important issue because the oil sources are depleting . Utilization of agricultural wastes for biogas production can minimize the consumption of commercial energy source such as kerosene as well as the use of firewood . Biogas is generated by the process of organic material digestion by certain anaerobe bacteria activity in aerobic digester . Anaerobic digestion process is basically carried out in three steps i.e. hydrolysis, acidogenic and metanogenic . Digestion process needs certain condition such as C : N ratio, temperature, acidity and also digester design . Most anaerobic digestions perform best at 32 - 35°C or at 50 - 55°C, and pH 6 .8 - 8 . At these temperatures, the digestion process essentially converts organic matter in the present of water into gaseous energy . Generally, biogas consists of methane about 60 - 70% and yield about 1,000 British Thermal Unit/ft 3 or 252 Kcal/0.028 m3 when burned . In several developing countries, as well as in Europe and the United States, biogas has been commonly used as a subtitute environmental friendly energy . Meanwhile, potentially Indonesia has abundant potential of biomass waste, however biogas has not been used maximally .

  20. Performance of Aerobic Sequencing Batch reactor (SBR) for Formaldehyde Removal from Synthetic Wastewater

    OpenAIRE

    2013-01-01

    Background and objectives: Formaldehyde is one of the compounds widely used in various industries; hence, its discharge into the effluent is unavoidable. Exposure to formaldehyde has a significant health effects. To prevent these issues, treatment of wastewater containing formaldehyde is necessary. The purpose of this study was to determine the performance of aerobic sequencing batch reactor (SBR) in removing formaldehyde from wastewater. Methods: We used a SBR having a total volume of 6.1...

  1. Analysis of dashpot performance for rotating control drums of a lithium cooled fast reactor concept

    Science.gov (United States)

    Wenzler, C. J.

    1972-01-01

    A dashpot was incorporated in the design of the drive train of the rotating control drum to prevent shock damage to the control drum and drive train at the termination of a scram action. A rotating vane dashpot using reactor coolant lithium as a damping fluid appears to be the best candidate of the various damping devices explored. A performance analysis, results and discussion of vane type dashpots are presented.

  2. 沼液氨氮减压蒸馏分离性能与反应动力学%Ammonia nitrogen separation performance and kinetics from biogas slurry using vacuum distillation method

    Institute of Scientific and Technical Information of China (English)

    贺清尧; 王文超; 刘璐; 余歌; 晏水平

    2016-01-01

    phytotoxicity to plant germination and growth when biogas slurry is put into agricultural or horticultural applications. So ammonia nitrogen in biogas slurry should be removed. Conventional methods for removing ammonia nitrogen are based on gas or thermal stripping. However, these methods have low ammonia nitrogen removal rate and are time-consumed. Due to the higher ammonia mass transfer driving force ascribed to the lower ammonia partial pressure in gas phase, vacuum distillation has the advantages of high ammonia nitrogen removal kinetics constant and short time required. Furthermore, ammonia can also be recovered and enriched to act as the valuable carbon dioxide (CO2) absorbent to upgrade biogas. Therefore, in this study, ammonia nitrogen separation from biogas slurry by using vacuum distillation method was conducted in a rotary evaporator. And the key operating parameters including sodium hydroxide (NaOH) dosage, temperature and pressure were investigated and optimized. The first-order rate constant (k), ammonia nitrogen removal time constant (τ), ammonia nitrogen removal efficiency (η) and ammonia nitrogen separation factor (St) were adopted to evaluate the ammonia nitrogen removal performance. Results showed that when raw biogas slurry without pH adjustment was vacuumed, CO2 loading of biogas slurry reduced from 0.15 to 0.08 mol CO2/L under the conditions of 45 °C and 5 kPa. But the first-order rate constantand ammonia nitrogen separation factor were low and ammonia nitrogen removal time constant was very high. Increasing NaOH dosage to elevate the initial pH value of biogas slurry was positive for enhancing the first-order rate constantandammonia nitrogen separation factor. Additionally, if high first-order rate constantvalue was targeted, high removal temperature and low operating pressure should be required. However, it will lead to the decrease of ammonia nitrogen separation factor value. So, the orthogonal tests were conducted in this study to optimize the

  3. UTILIZATION OF POULTRY, COW AND KITCHEN WASTES FOR BIOGAS PRODUCTION: A COMPARATIVE ANALYSIS

    Directory of Open Access Journals (Sweden)

    K. Animasahun

    2007-09-01

    Full Text Available The amount of solid wastes generated in developing countries such as Nigeria has steadily increased over the last two decades as a result of population explosion and continuous growth of industries and agricultural practices. In agriculture, particularly cattle rearing, large quantities of cow wastes are generated, which could be used as biogas inputs to compliment the fuel usage alternative. In addition, a large number of families generate heavy wastes in the kitchen on a daily basis, which could be converted to economic benefits. In this work, a comparative study of biogas production from poultry droppings, cattle dung, and kitchen wastes was conducted under the same operating conditions. 3kg of each waste was mixed with 9L of water and loaded into the three waste reactors. Biogas production was measured for a period of 40 days and at an average temperature of 30.5oC. Biogas production started on the 7th day, and attained maximum value on the 14th days for reactor 1. Production reached its peak on the 14th day with 85´10-3dm3 of gas produced in reactor 2. For reactor 3, biogas production started on the 8th day and production reached a peak value on the 14th day. The average biogas production from poultry droppings, cow dung and kitchen waste was 0.0318dm3/day, 0.0230dm3/day and 0.0143dm3/day, respectively. It is concluded that the wastes can be managed through conversion into biogas, which is a source of income generation for the society.

  4. Biogas production from wheat straw and manure--impact of pretreatment and process operating parameters.

    Science.gov (United States)

    Risberg, Kajsa; Sun, Li; Levén, Lotta; Horn, Svein Jarle; Schnürer, Anna

    2013-12-01

    Non-treated or steam-exploded straw in co-digestion with cattle manure was evaluated as a substrate for biogas production compared with manure as the sole substrate. All digestions were performed in laboratory-scale CSTR reactors (5L) operating with an organic loading late of approximately 2.8 g VS/L/day, independent of substrate mixture. The hydraulic retention was 25 days and an operating temperature of 37, 44 or 52°C. The co-digestion with steam exploded straw and manure was evaluated with two different mixtures, with different proportion. The results showed stable performance but low methane yields (0.13-0.21 N L CH4/kg VS) for both manure alone and in co-digestion with the straw. Straw appeared to give similar yield as manure and steam-explosion treatment of the straw did not increase gas yields. Furthermore, there were only slight differences at the different operating temperatures.

  5. Treatment of Biogas for Use as Energy

    OpenAIRE

    Koller, J.

    2010-01-01

    The biogas generated in biogas plants offers significant potential for the production of energy from renewable energy sources. The number biogas plants in the Czech Republic is expected to exceed one hundred in the near future. Substrates from agriculture, industry and municipal wastes are used for biogas production. Biogas plants usually use co-generation units to generate electricity and heat. Increased effectiveness can be achieved by using heat as a source of energy for producing renewabl...

  6. Beets for biogas. News from the laboratory and practice; Rueben fuer Biogas. Neues aus Labor und Praxis

    Energy Technology Data Exchange (ETDEWEB)

    Jeche, Ulrike [KWS Saat AG, Einbeck (Germany). Vertrieb Zuckerruebe Deutschland und Oesterreich; Schaffner, Sebastian

    2011-07-01

    Being a multi-talented crop, sugar beets are increasingly convincing biogas plant owners with their positive properties. In a mixture of substrates, they are a perfect partner for biogas production as they can push gas yield. In breeding, the experts mainly focus on increasing dry matter yield. There is a close correlation with sugar yield. The market already offers a multitude of highly performing sugar beet varieties for most diverse cropping conditions. The beets are harvested and transported from the field to the biogas plant with harvesting and transport technology which has proved its efficiency for many years. Other than harvested for other purposes, sugar beet for biogas production are stripped of their leaves instead of being topped. Stocking sugar beet at the biogas plant is a quite demanding issue. Sugar beets may be stocked as ensiled, whole beet, as pulp, or as crushed beet in mixed silage. There is a whole range of most diverse storage and crushing concepts. When used as a substrate for biogas production, sugar beet mostly need to be cleaned and stones need to be discarded before feeding the beets into the digester. In the meanwhile, the market offers a large choice of cleaning technique to pave the ways for sugar beets as a substrate. (orig.)

  7. High-solid Anaerobic Co-digestion of Food Waste and Rice Straw for Biogas Production

    Institute of Scientific and Technical Information of China (English)

    Pei Zhan-jiang; Liu Jie; Shi Feng-mei; Wang Su; GaoYa-bing; Zhang Da-lei

    2014-01-01

    Anaerobic co-digestion of food waste (FW) and rice straw (RS) in continuously stirred tank reactor (CSTR) at high organic loading rate (OLR) was investigated. Co-digestion studies of FW and RS with six different mixing ratios were conducted at an initial volatile solid (VS) concentration of more than 3 gVS•L-1. The biogas production, methane contents, degradation efficiency of VS, chemical oxygen demand (COD) and volatile fatty acids (VFAs) were determined to evaluate the stability and performance of the system. The results showed that the co-digestion process had higher system stability and higher volumetric biogas production than mono-digestions. Increase in FW content in the feedstock could increase the methane yield and shorten retention time. The efficiency of co-digestion systems mainly relied on the mixing ratios of FW and RS to some extent. The highest methane yield was 60.55 mL•gV•S-1•d-1 at a mass ratio (FW/RS) of 3: 1, which was 178% and 70% higher than that of mono-digestions of FW and RS, respectively. Consequently, the anaerobic co-digestion of FW and RS could have superior stability and better performance than mono-digestions in higher organic loading system.

  8. Inducting biogas. Future prospects; Einspeisung von Biogas. Zukunftsperspektiven

    Energy Technology Data Exchange (ETDEWEB)

    Edelmann, W.

    2008-07-01

    Biogas is a very environmentally friendly source of energy as long as it is produced from refuse and sewage. If on the other hand energy plants are added, the ecological balance is unfavourable. Using photovoltaic methods for the same surface area, 100 times more solar energy can be produced than with renewable raw materials. One can therefore assure that in the future, traffic will run on electricity and biogas from natural resources will take on an important role as a supply of raw materials for chemical synthesis. It would appear to be a good idea for this purpose to clean biogas and introduce it into the network, at least for larger plants. (author)

  9. Commercial-Scale Performance Predictions for High-Temperature Electrolysis Plants Coupled to Three Advanced Reactor Types

    Energy Technology Data Exchange (ETDEWEB)

    M. G. McKellar; J. E. O' Brien; J. S. Herring

    2007-09-01

    This report presents results of system analyses that have been developed to assess the hydrogen production performance of commercial-scale high-temperature electrolysis (HTE) plants driven by three different advanced reactor – power-cycle combinations: a high-temperature helium cooled reactor coupled to a direct Brayton power cycle, a supercritical CO2-cooled reactor coupled to a direct recompression cycle, and a sodium-cooled fast reactor coupled to a Rankine cycle. The system analyses were performed using UniSim software. The work described in this report represents a refinement of previous analyses in that the process flow diagrams include realistic representations of the three advanced reactors directly coupled to the power cycles and integrated with the high-temperature electrolysis process loops. In addition, this report includes parametric studies in which the performance of each HTE concept is determined over a wide range of operating conditions. Results of the study indicate that overall thermal-to- hydrogen production efficiencies (based on the low heating value of the produced hydrogen) in the 45 - 50% range can be achieved at reasonable production rates with the high-temperature helium cooled reactor concept, 42 - 44% with the supercritical CO2-cooled reactor and about 33 - 34% with the sodium-cooled reactor.

  10. Efficiency of biogas plants; Effizienz von Biogasanlagen

    Energy Technology Data Exchange (ETDEWEB)

    Haupt, T.; Kraft, E. [Bauhaus-Universitaet Weimar (Germany). Fachbereich Bauingenieurwesen

    2007-02-15

    A stable biological process is a requisite for an efficient operation of biogas plants. Due to increasing flexible conditions, especially in agriculture, higher demands concerning the process performance arising. A sophisticated approach to different procedures seems to be useful. Regarding wet fermentation plants efficient control algorithms on basis of a simple model are of special interest. Analyses to figure the dynamic process behaviour via online measurements represent one possibility. For batch-operated dry fermentation processes, as most suitable application in agriculture, it is more to establish optimal start conditions. The inquiry of master data dealing with the influence of physical parameters of packed beds on the biogas yield has a valueable contingent on that. (orig.)

  11. Bioenergy, protein and fibres from grass - biogas process monitoring; Bioenergie, Protein und Fasern aus Gras - Monitoring des Biogasprozesses

    Energy Technology Data Exchange (ETDEWEB)

    Baier, U.; Delavy, P.

    2003-07-01

    Starting in Summer 2001 the first full scale Swiss Bio-refinery for grass processing took up operation in Schaffhausen. Grass processing covers the production of technical fibres and protein concentrate as well as anaerobic digestion of residual slops for the production of biogas and 'green' electricity. The refinery is operated by the company Bioenergie Schaffhausen as a P+D (pilot + demonstration) project of the Swiss Federal Office of Energy. Under full load it will deliver 2,000 MWh of 'green' electricity (10% own needs) and 3,000 MWh heat (50% own needs). Prior to start up the Swiss technology holder 2B Biorefineries AG mandated the University of Applied Sciences HSW with lab scale testing of the mesophilic biogas potential and anaerobic degradability of residual grass processing slops. Nutrient limitations and possible inhibition risks were evaluated. During the initial 8 months of full scale operation of the refinery in Schaffhausen an intensive monitoring of the anaerobic digester's performance was carried out. Carbon and nitrogen mass balances have been set up and the development of the granular EGSB sludge was characterised. From operational data a set of performance values was elaborated. The first year of operation was characterised by only partial exploitation of the refinery's grass processing capacity. Furthermore the protein separation and production unit has not yet been incorporated. Consequently, the EGSB biogas reactor showed a significant hydraulic underload when compared to dimensioning basics. Raw residuals were characterised by a higher particulate protein fraction. Operational conditions for the EGSB reactor were worked out to allow stable operation at elevated load conditions and with protein separation in operation. (author)

  12. Analysis of biogas production through anaerobics digestion using cow dung and various co-substrates

    Directory of Open Access Journals (Sweden)

    Dhanapal Thamilselvan

    2016-01-01

    Full Text Available Biodegradable waste is a sustainable energy resource. In coming years biogas technology can be very useful worldwide, since biogas can be obtained from biodegradable waste material. This technology is based on waste reduction and also is helpful in the clean-up process of India. In this experiment, we have made single-phase biogas set-ups by using two-liter bottles. The fermentation time of the anaerobic digestion for the efficient use of gas as a fuel is about sixteen days. In our biogas digester set-ups for waste decomposion anaerobic co-digestion process is utilized. The primary feed stock is cow dung, whereas the grass, fruit, and vegetable waste are used as co-subtracts. The pH value was maintained at the range level of 6.5 to 6.9. The output biogas yield was 1.59 ml, 1.28 ml, 1.03 ml, and 0.95 ml, within an approximate period of sixteen days. Biogas obtained from cow dung and grass waste is almost identical as biogas obtained from the experimental set-up 1 (pure cow dung. Main performance characteristics of biogas formation were presented in this paper. In order to analyze a daily biogas formation, the pH value, temperature, and hydraulic retention time were changed in this experiment.

  13. Deeper insight into the structure of the anaerobic digestion microbial community; the biogas microbiome database is expanded with 157 new genomes

    DEFF Research Database (Denmark)

    Treu, Laura; Kougias, Panagiotis; Campanaro, Stefano

    2016-01-01

    This research aimed to better characterize the biogas microbiome by means of high throughput metagenomic sequencing and to elucidate the core microbial consortium existing in biogas reactors independently from the operational conditions. Assembly of shotgun reads followed by an established binning...... strategy resulted in the highest, up to now, extraction of microbial genomes involved in biogas producing systems. From the 236 extracted genome bins, it was remarkably found that the vast majority of them could only be characterized at high taxonomic levels. This result confirms that the biogas microbiome...

  14. Biotechnological intensification of biogas production

    Energy Technology Data Exchange (ETDEWEB)

    Bagi, Z.; Acs, N.; Balint, B.; Horvath, L.; Dobo, K.; Perei, K.R.; Rakhely, G.; Kovacs, K.L. [Szeged Univ. (Hungary). Dept. of Biotechnology; Hungarian Academy of Sciences, Szeged (Hungary). Inst. of Biophysics

    2007-08-15

    The importance of syntrophic relationships among microorganisms participating in biogas formation has been emphasized, and the regulatory role of in situ hydrogen production has been recognized. It was assumed that the availability of hydrogen may be a limiting factor for hydrogenotrophic methanogens. This hypothesis was tested under laboratory and field conditions by adding a mesophilic (Enterobacter cloacae) or thermophilic hydrogen-producing (Caldicellulosyruptor saccharolyticus) strain to natural biogas-producing consortia. The substrates were waste water sludge, dried plant biomass from Jerusalem artichoke, and pig manure. In all cases, a significant intensification of biogas production was observed. The composition of the generated biogas did not noticeably change. In addition to being a good hydrogen producer, C. saccharolyticus has cellulolytic activity; hence, it is particularly suitable when cellulose-containing biomass is fermented. The process was tested in a 5-m{sup 3} thermophilic biogas digester using pig manure slurry as a substrate. Biogas formation increased at least 160-170% upon addition of the hydrogen-producing bacteria as compared to the biogas production of the spontaneously formed microbial consortium. Using the hydrogenase-minus control strain provided evidence that the observed enhancement was due to interspecies hydrogen transfer. The on-going presence of C. saccharolyticus was demonstrated after several months of semicontinuous operation. (orig.)

  15. Stable isotope composition of biogas allows early warning of complete process failure as a result of ammonia inhibition in anaerobic digesters.

    Science.gov (United States)

    Lv, Zuopeng; Hu, Meng; Harms, Hauke; Richnow, Hans Hermann; Liebetrau, Jan; Nikolausz, Marcell

    2014-09-01

    Four 15-L lab-scale continuous stirred tank reactors were operated under mesophilic conditions to investigate the effect of ammonia inhibition. Stable isotope fingerprinting of biogas was applied as a process monitoring tool. Ammonia inhibition was initiated by amendment of chicken manure to maize silage fed reactors. During the accumulation of ammonia, the concentration of volatile fatty acids increased while the biogas production and pH decreased. However, in one reactor, an inhibited steady state with stable gas production even at high ammonia levels was achieved, while the other reactor proceeded to complete process failure. A depletion of the δ(13)CH4 and δ(13)CO2 values preceded the process inhibition. Moreover, the stable isotope composition of biogas also forecasted the complete process failure earlier than other standard parameters. The stable isotope analyses of biogas have a potential for mechanistic insights in anaerobic processes, and may be used to pre-warn process failure under stress conditions.

  16. Influences of iron and calcium carbonate on wastewater treatment performances of algae based reactors.

    Science.gov (United States)

    Zhao, Zhimiao; Song, Xinshan; Wang, Wei; Xiao, Yanping; Gong, Zhijie; Wang, Yuhui; Zhao, Yufeng; Chen, Yu; Mei, Mengyuan

    2016-09-01

    The influences of iron and calcium carbonate (CaCO3) addition in wastewater treatments reactors performance were investigated. Adding different concentrations of Fe(3+) (5, 10, 30 and 50mmol/m(3)), iron and CaCO3 powder led to changes in algal characteristics and physico-chemical and microbiological properties. According to the investigation results, nutrient removal efficiency in algae based reactors was obviously increased by the addition of 10mmol/m(3) Fe(3+), iron (5mmol/m(3)) and CaCO3 powder (0.2gm(-3)) and the removal efficiencies of BOD5, TN, and TP in Stage 2 were respectively increased by 28%, 8.9%, and 22%. The improvements in physico-chemical performances were verified by microbial community tests (bacteria quantity, activity and community measured in most probable number, extracellular enzymes activity, and Biolog Eco Plates). Microbial variations indicated the coexistence of Fe ions and carbonate-bicarbonate, which triggered the synergistic effect of physico-chemical action and microbial factors in algae based reactors.

  17. Neutronic and Thermal-hydraulic Modelling of High Performance Light Water Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Seppaelae, Malla [VTT Technical Research Centre of Finland, P.O.Box 1000, FI02044 VTT (Finland)

    2008-07-01

    High Performance Light Water Reactor (HPLWR), which is studied in EU project 'HPLWR2', uses water at supercritical pressures as coolant and moderator to achieve higher core outlet temperature and thus higher efficiency compared to present reactors. At VTT Technical Research Centre of Finland, functionality of the thermal-hydraulics in the coupled reactor dynamics code TRAB3D/ SMABRE was extended to supercritical pressures for the analyses of HPLWR. Input models for neutronics and thermal-hydraulics were made for TRAB3D/ SMABRE according to the latest HPLWR design. A preliminary analysis was performed in which the capability of SMABRE in the transition from supercritical pressures to subcritical pressures was demonstrated. Parameterized two-group cross sections for TRAB3D neutronics were received from Hungarian Academy of Sciences KFKI Atomic Energy Research Institute together with a subroutine for handling them. PSG, a new Monte Carlo transport code developed at VTT, was also used to generate two-group constants for HPLWR and comparisons were made with the KFKI cross sections and MCNP calculations. (author)

  18. EXPERIMENTAL EVALUATION OF THE THERMAL PERFORMANCE OF A WATER SHIELD FOR A SURFACE POWER REACTOR

    Energy Technology Data Exchange (ETDEWEB)

    REID, ROBERT S. [Los Alamos National Laboratory; PEARSON, J. BOSIE [Los Alamos National Laboratory; STEWART, ERIC T. [Los Alamos National Laboratory

    2007-01-16

    Water based reactor shielding is being investigated for use on initial lunar surface power systems. A water shield may lower overall cost (as compared to development cost for other materials) and simplify operations in the setup and handling. The thermal hydraulic performance of the shield is of significant interest. The mechanism for transferring heat through the shield is natural convection. Natural convection in a 100 kWt lunar surface reactor shield design is evaluated with 2 kW power input to the water in the Water Shield Testbed (WST) at the NASA Marshall Space Flight Center. The experimental data from the WST is used to validate a CFD model. Performance of the water shield on the lunar surface is then predicted with a CFD model anchored to test data. The experiment had a maximum water temperature of 75 C. The CFD model with 1/6-g predicts a maximum water temperature of 88 C with the same heat load and external boundary conditions. This difference in maximum temperature does not greatly affect the structural design of the shield, and demonstrates that it may be possible to use water for a lunar reactor shield.

  19. Treatment of slaughter house wastewater in a sequencing batch reactor: performance evaluation and biodegradation kinetics.

    Science.gov (United States)

    Kundu, Pradyut; Debsarkar, Anupam; Mukherjee, Somnath

    2013-01-01

    Slaughterhouse wastewater contains diluted blood, protein, fat, and suspended solids, as a result the organic and nutrient concentration in this wastewater is vary high and the residues are partially solubilized, leading to a highly contaminating effect in riverbeds and other water bodies if the same is let off untreated. The performance of a laboratory-scale Sequencing Batch Reactor (SBR) has been investigated in aerobic-anoxic sequential mode for simultaneous removal of organic carbon and nitrogen from slaughterhouse wastewater. The reactor was operated under three different variations of aerobic-anoxic sequence, namely, (4+4), (5+3), and (3+5) hr. of total react period with two different sets of influent soluble COD (SCOD) and ammonia nitrogen (NH4(+)-N) level 1000 ± 50 mg/L, and 90 ± 10 mg/L, 1000 ± 50 mg/L and 180 ± 10 mg/L, respectively. It was observed that from 86 to 95% of SCOD removal is accomplished at the end of 8.0 hr of total react period. In case of (4+4) aerobic-anoxic operating cycle, a reasonable degree of nitrification 90.12 and 74.75% corresponding to initial NH4(+)-N value of 96.58 and 176.85 mg/L, respectively, were achieved. The biokinetic coefficients (k, K(s), Y, k(d)) were also determined for performance evaluation of SBR for scaling full-scale reactor in future operation.

  20. Performance of a sequencing batch biofilm reactor for the treatment of pre-oxidized sulfamethoxazole solutions.

    Science.gov (United States)

    González, Oscar; Esplugas, Marc; Sans, Carme; Torres, Alicia; Esplugas, Santiago

    2009-05-01

    A combined strategy of a photo-Fenton pretreatment followed by a Sequencing Batch Biofilm Reactor (SBBR) was evaluated for total C and N removal from a synthetic wastewater containing exclusively 200 mg L(-1) of the antibiotic Sulfamethoxazole (SMX). Photo-Fenton reaction was optimized at the minimum reagent doses in order to improve the biocompatibility of effluents with the subsequent biological reactor. Consequently, the pretreatment was performed with two different initial H(2)O(2) concentrations (300 and 400 mg L(-1)) and 10 mg L(-1) of Fe(2+). The pre-treated effluents with the antibiotic intermediates as sole carbon source were used as feed for the biological reactor. The SBBR was operated under aerobic conditions to mineralize the organic carbon, and the Hydraulic Retention Time (HRT) was optimized down to 8h reaching a removal of 75.7% of the initial Total Organic Carbon (TOC). The total denitrification of the NO(3)(-) generated along the chemical-biological treatment was achieved by means of the inclusion of a 24-h anoxic stage in the SBBR strategy. In addition, the Activated Sludge Model No. 1 (ASM1) was successfully used to complete the N balance determining the N fate in the SBBR. The characterization and the good performance of the SBBR allow presenting the assessed combination as an efficient way for the treatment of wastewaters contaminated with biorecalcitrant pharmaceuticals as the SMX.

  1. Removal performance and microbial communities in a sequencing batch reactor treating hypersaline phenol-laden wastewater.

    Science.gov (United States)

    Jiang, Yu; Wei, Li; Zhang, Huining; Yang, Kai; Wang, Hongyu

    2016-10-01

    Hypersaline phenol-rich wastewater is hard to be treated by traditional biological systems. In this work, a sequencing batch reactor was used to remove phenol from hypersaline wastewater. The removal performance was evaluated in response to the variations of operating parameters and the microbial diversity was investigated by 454 pyrosequencing. The results showed that the bioreactor had high removal efficiency of phenol and was able to keep stable with the increase of initial phenol concentration. DO, pH, and salinity also affected the phenol removal rate. The most abundant bacterial group was phylum Proteobacteria in the two working conditions, and class Gammaproteobacteria as well as Alphaproteobacteria was predominant subgroup. The abundance of bacterial clusters was notably different along with the variation of operation conditions, resulting in changes of phenol degradation rates. The high removal efficiency of phenol suggested that the reactor might be promising in treating phenol-laden industrial wastewater in high-salt condition.

  2. Nuclear Systems Enhanced Performance Program, Maintenance Cycle Extension in Advanced Light Water Reactor Design

    Energy Technology Data Exchange (ETDEWEB)

    Professor Neill Todreas

    2001-10-01

    A renewed interest in new nuclear power generation in the US has spurred interest in developing advanced reactors with features which will address the public's concerns regarding nuclear generation. However, it is economic performance which will dictate whether any new orders for these plants will materialize. Economic performance is, to a great extent, improved by maximizing the time that the plant is on-line generating electricity relative to the time spent off-line conducting maintenance and refueling. Indeed, the strategy for the advanced light water reactor plant IRIS (International Reactor, Innovative and Secure) is to utilize an eight year operating cycle. This report describes a formalized strategy to address, during the design phase, the maintenance-related barriers to an extended operating cycle. The top-level objective of this investigation was to develop a methodology for injecting component and system maintainability issues into the reactor plant design process to overcome these barriers. A primary goal was to demonstrate the applicability and utility of the methodology in the context of the IRIS design. The first step in meeting the top-level objective was to determine the types of operating cycle length barriers that the IRIS design team is likely to face. Evaluation of previously identified regulatory and investment protection surveillance program barriers preventing a candidate operating PWR from achieving an extended (48 month) cycle was conducted in the context of the IRIS design. From this analysis, 54 known IRIS operating cycle length barriers were identified. The resolution methodology was applied to each of these barriers to generate design solution alternatives for consideration in the IRIS design. The methodology developed has been demonstrated to narrow the design space to feasible design solutions which enable a desired operating cycle length, yet is general enough to have broad applicability. Feedback from the IRIS design team

  3. Testing of Passive Safety System Performance for Higher Power Advanced Reactors

    Energy Technology Data Exchange (ETDEWEB)

    brian G. Woods; Jose Reyes, Jr.; John Woods; John Groome; Richard Wright

    2004-12-31

    This report describes the results of NERI research on the testing of advanced passive safety performance for the Westinghouse AP1000 design. The objectives of this research were: (a) to assess the AP1000 passive safety system core cooling performance under high decay power conditions for a spectrum of breaks located at a variety of locations, (b) to compare advanced thermal hydraulic computer code predictions to the APEX high decay power test data and (c) to develop new passive safety system concepts that could be used for Generation IV higher power reactors.

  4. Evaluating the Air Quality, Climate Change, and Economic Impacts of Biogas Management Technologies

    Science.gov (United States)

    This is an abstract for a presentation that describes a project to evaluate economic and environmental performance of several biogas management technologies. It will analyze various criteria air pollutants, greenhouse gas emissions, and costs associated with the use of biogas. Th...

  5. Economic analysis of anaerobic digestion - A case of Green power biogas plant in The Netherlands

    NARCIS (Netherlands)

    Gebrezgabher, S.A.; Meuwissen, M.P.M.; Prins, B.A.M.; Oude Lansink, A.G.J.M.

    2010-01-01

    One of the key concerns of biogas plants is the disposal of comparatively large amounts of digestates in an economically and environmentally sustainable manner. This paper analyses the economic performance of anaerobic digestion of a given biogas plant based on net present value (NPV) and internal r

  6. Performance evaluation of a continuous flow photocatalytic reactor for wastewater treatment.

    Science.gov (United States)

    Rezaei, Mohammad; Rashidi, Fariborz; Royaee, Sayed Javid; Jafarikojour, Morteza

    2014-11-01

    A novel photocatalytic reactor for wastewater treatment was designed and constructed. The main part of the reactor was an aluminum tube in which 12 stainless steel circular baffles and four quartz tube were placed inside of the reactor like shell and tube heat exchangers. Four UV-C lamps were housed within the space of the quartz tubes. Surface of the baffles was coated with TiO2. A simple method was employed for TiO2 immobilization, while the characterization of the supported photocatalyst was based on the results obtained through performing some common analytical methods such as X-ray diffraction (XRD), scanning electron microscope (SEM), and BET. Phenol was selected as a model pollutant. A solution of a known initial concentration (20, 60, and 100 ppmv) was introduced to the reactor. The reactor also has a recycle flow to make turbulent flow inside of the reactor. The selected recycle flow rate was 7 × 10(-5) m(3).s(-1), while the flow rate of feed was 2.53 × 10(-7), 7.56 × 10(-7), and 1.26 × 10(-6) m(3).s(-1), respectively. To evaluate performance of the reactor, response surface methodology was employed. A four-factor three-level Box-Behnken design was developed to evaluate the reactor performance for degradation of phenol. Effects of phenol inlet concentration (20-100 ppmv), pH (3-9), liquid flow rate (2.53 × 10(-7)-1.26 × 10(-6) m(3).s(-1)), and TiO2 loading (8.8-17.6 g.m(-2)) were analyzed with this method. The adjusted R (2) value (0.9936) was in close agreement with that of corresponding R (2) value (0.9961). The maximum predicted degradation of phenol was 75.50 % at the optimum processing conditions (initial phenol concentration of 20 ppmv, pH ∼ 6.41, and flow rate of 2.53 × 10(-7) m(3).s(-1) and catalyst loading of 17.6 g.m(-2)). Experimental degradation of phenol determined at the optimum conditions was 73.7 %. XRD patterns and SEM images at the optimum conditions revealed that crystal size is approximately 25

  7. Biogas production and biogas as vehicle fuel - Swedish experiences

    Energy Technology Data Exchange (ETDEWEB)

    Lindberg, A.E. [VBB Viak AB, Stockholm (Sweden)

    1997-08-01

    In Sweden there are totally about 220 biogas plants in operation. The major part of these plants (134) are represented by sewage sludge treatment facilities at waste water treatment plants. At 60 sites the biogas is generated from landfills or cell digesters at landfills. In 1996, the amount produced had a total energy content of about 1,35 TWh (or 4 900 PJ). (EG)

  8. Formation and suppression of foam in biogas plants; Bildung von Schaum in Biogasanlagen und seine Bekaempfung

    Energy Technology Data Exchange (ETDEWEB)

    Moeller, Lucie [Helmholtz-Zentrum fuer Umweltforschung, Leipzig (Germany); Goersch, Kati; Zehnsdorf, Andreas

    2012-07-01

    Excessive foaming in the process of anaerobic digestion is one of the most common disorders of the biological stage of the biogas production process. Especially biogas plants treating biogenic residues and waste materials are affected. A survey of fifteen operators of waste-utilizing biogas plants in Saxony, Saxony-Anhalt and Thuringia showed that 80 % of the operators have already had problems with excessive foam formation in their biogas reactor. More than half of them complained about regular foam events. The consequences of excessive foam formation may vary depending on the extent of foaming. They range from extra costs for anti-foaming agents to cleaning and repair costs in case of construction defects. Foam in the reactor may have many causes. They involve the careless application of risk substrates, inadequate plant management or technical errors and accidents. Mostly, the direct cause of foaming remains unclear. Although foam formation in the biogas reactor is a very common phenomenon, only little research has been done in this field until now. (orig.)

  9. The influence on biogas production of three slurry-handling systems in dairy farms

    Directory of Open Access Journals (Sweden)

    Damiano Coppolecchia

    2015-04-01

    Full Text Available Handling systems can influence the production of biogas and methane from dairy farm manures. A comparative work performed in three different Italian dairy farms showed how the most common techniques (scraper, slatted floor, flushing can change the characteristics of collected manure. Scraper appears to be the most neutral choice, as it does not significantly affect the original characteristics of manure. Slatted floor produces a manure that has a lower methane potential in comparison with scraper, due to: a lower content of volatile solids caused by the biodegradation occurring in the deep pit, and a lower specific biogas production caused by the change in the characteristics of organic matter. Flushing can produce three different fluxes: diluted flushed manure, solid separated manure and liquid separated manure. The diluted fraction appears to be unsuitable for conventional anaerobic digestion in completely stirred reactors (CSTR, since its content of organic matter is too low to be worthwhile. The liquid separated fraction could represent an interesting material, as it appears to accumulate the most biodegradable organic fraction, but not as primary substrate in CSTR as the organic matter concentration is too low. Finally, the solid-liquid separation process tends to accumulate inert matter in the solid separated fraction and, therefore, its specific methane production is low.

  10. Microalgae conversion to biogas: thermal pretreatment contribution on net energy production.

    Science.gov (United States)

    Passos, Fabiana; Ferrer, Ivet

    2014-06-17

    Microalgal biomass harvested from wastewater treatment high rate algal ponds may be valorised through anaerobic digestion producing biogas. However, microalgae anaerobic biodegradability is limited by their complex cell wall structure. Thus, pretreatment techniques are being investigated to improve microalgae methane yield. In the current study, thermal pretreatment at relatively low temperatures of 75-95 °C was effective at enhancing microalgae anaerobic biodegradability; increasing the methane yield by 70% in respect to nonpretreated biomass. Microscopic images showed how the pretreatment damaged microalgae cells, enhancing subsequent anaerobic digestion. Indeed, digestate images showed how after pretreatment only species with resistant cell walls, such as diatoms, continued to be present. Energy balances based on lab-scale reactors performance at 20 days HRT, shifted from neutral to positive (energy gain around 2.7 GJ/d) after thermal pretreatment. In contrast with electricity consuming pretreatment methods, such as microwave irradiation, thermal pretreatment of microalgae seems to be scalable.

  11. Nitrogen availability of biogas residues

    Energy Technology Data Exchange (ETDEWEB)

    El-Sayed Fouda, Sara

    2011-09-07

    The objectives of this study were to characterize biogas residues either unseparated or separated into a liquid and a solid phase from the fermentation of different substrates with respect to their N and C content. In addition, short and long term effects of the application of these biogas residues on the N availability and N utilization by ryegrass was investigated. It is concluded that unseparated or liquid separated biogas residues provide N at least corresponding to their ammonium content and that after the first fertilizer application the C{sub org}:N{sub org} ratio of the biogas residues was a crucial factor for the N availability. After long term application, the organic N accumulated in the soil leads to an increased release of N.

  12. BIOGAS PRODUCTION FROM CATCH CROPS

    DEFF Research Database (Denmark)

    Molinuevo-Salces, Beatriz; Larsen, Søren U.; Ahring, Birgitte Kiær

    2014-01-01

    Catch crop cultivation combined with its use for biogas production would increase renewable energy production in the form of methane, without interfering with the production of food and fodder crops. The low biomass yield of catch crops is the main limiting factor for using these crops as co......-substrate in manure-based biogas plants and the profit obtained from the sale of biogas barely compensates for the harvest costs. A new agricultural strategy to harvest catch crops together with the residual straw of the main crop was investigated to increase the biomass and thereby the methane yield per hectare...... biomass. Leaving the straw on the field until harvest of the catch crop in the autumn could benefit biogas production due to the organic matter degradation of the straw taking place on the field during the autumn months. This new agricultural strategy may be a good alternative to achieve economically...

  13. Monitoring of biogas test plants

    DEFF Research Database (Denmark)

    Holm-Nielsen, Jens Bo; Esbensen, Kim H.

    2011-01-01

    Most studies reported in the literature have investigated near infrared spectroscopy (NIR) in laboratory-scale or minor pilot biogas plants only; practically no other studies have examined the potential for meso-scale/full-scale on-line process monitoring. The focus of this study is on a meso......-scale biogas test plant implementation of process analytical technologies (PAT) to develop multivariate calibration/prediction models for anaerobic digestion (AD) processes. A 150 L bioreactor was fitted with a recurrent loop at which NIR spectroscopy and attendant reference sampling were carried out. In all...... realistic bioreactor scales, it is necessary to obtain a fairly constant level of volatile fatty acid (VFA) concentration, which furthers a stable biogas production. Uncontrolled VFA contents have a significant negative impact on biogas production; VFA concentrations should not exceed 5–6000 mg/L lest...

  14. On the factors influencing the performance of solar reactors for water disinfection with photosensitized singlet oxygen.

    Science.gov (United States)

    Manjón, Francisco; Villén, Laura; García-Fresnadillo, David; Orellana, Guillermo

    2008-01-01

    Two solar reactors based on compound parabolic collectors (CPCs) were optimized for water disinfection by photosensitized singlet oxygen (1O2) production in the heterogeneous phase. Sensitizing materials containing Ru(II) complexes immobilized on porous silicone were produced, photochemically characterized, and successfully tested for the inactivation of up to 10(4) CFU mL(-1) of waterborne Escherichia coli (gram-negative) or Enterococcus faecalis (gram-positive) bacteria. The main factors determining the performance of the solar reactors are the type of photosensitizing material, the sensitizer loading, the CPC collector geometry (fin- vs coaxial-type), the fluid rheology, and the balance between concurrent photothermal--photolytic and 1O2 effects on the microorganisms' inactivation. In this way, at the 40 degrees N latitude of Spain, water can be disinfected on a sunny day (0.6-0.8 MJ m(-2) L(-1) accumulated solar radiation dose in the 360-700 nm range, typically 5-6 h of sunlight) with a fin-type reactor containing 0.6 m2 of photosensitizing material saturated with tris(4,7-diphenyl-1,10-phenanthroline)ruthenium(II) (ca. 2.0 g m(-2)). The optimum rheological conditions require laminar-to-transitional water flow in both prototypes. The fin-type system showed better inactivation efficiency than the coaxial reactor due to a more important photolytic contribution. The durability of the sensitizing materials was tested and the operational lifetime of the photocatalyst is at least three months without any reduction in the bacteria inactivation efficiency. Solar water disinfection with 1O2-generating films is demonstrated to be an effective technique for use in isolated regions of developing countries with high yearly average sunshine.

  15. [Performance and substrate inhibition kinetics model of nitritation process in inverse turbulent bed reactor].

    Science.gov (United States)

    Jin, Ren-Cun; Yang, Guang-Feng; Ma, Chun; Zheng, Ping

    2011-01-01

    The performance of a nitritation inverse turbulent bed (ITB) reactor was tested and the substrate inhibition kinetics characteristics of the reactor were analyzed. The results showed that a rapid reactor startup could be realized within 20 d with a strategy that combined the biofilm attachment method named "precoating carrier treatment" and "rapid suspending sludge discharge", with the feeding strategy named "low strength, high load". When operated at a hydraulic retention time of 3 h and influent NH4(+) -N of 700 mg x L(-1), corresponding to a nitrogen loading rate of 5.60 kg x (m3 x d)(-1), a maximum NH4(+) -N removal rate of 4.25 kg x (m3 x d)(-1) was observed. The maximum NO2(-) -N production rate was as high as 3.70 kg x (m3 x d)(-1). Four inhibition kinetic models (Haldane, Edwards, Aiba and Luong) were analyzed through non-linear regression to represent the inhibitions caused by substrate of nitritation process and the parameters of models were gained, which were r(max) of 1.84 kg x (m3 x d)(-1), K(IH) of 97.4 mg x L(-1) and K(m) of 0.188 mg x L(-1) for Haldane model, and r(max) of 1.83 kg x (m3 x d)(-1) and K(IA) of 114 mg x L(-1) for Aiba model. It was proposed that Haldane and Aiba models well fitted the process data harvested in the ITB reactor.

  16. Anaerobic digestion of corn stovers for methane production in a novel bionic reactor.

    Science.gov (United States)

    Zhang, Meixia; Zhang, Guangming; Zhang, Panyue; Fan, Shiyang; Jin, Shuguang; Wu, Dan; Fang, Wei

    2014-08-01

    To improve the biogas production from corn stovers, a new bionic reactor was designed and constructed. The bionic reactor simulated the rumen digestion of ruminants. The liquid was separated from corn stovers and refluxed into corn stovers again, which simulated the undigested particles separated from completely digested materials and fed back again for further degradation in ruminant stomach. Results showed that the bionic reactor was effective for anaerobic digestion of corn stovers. The liquid amount and its reflux showed an obvious positive correlation with biogas production. The highest biogas production rate was 21.6 ml/gVS-addedd, and the total cumulative biogas production was 256.5 ml/gVS-added. The methane content in biogas ranged from 52.2% to 63.3%. The degradation of corn stovers were greatly enhanced through simulating the animal digestion mechanisms in this bionic reactor.

  17. Slaughterhouse fatty waste saponification to increase biogas yield.

    Science.gov (United States)

    Battimelli, A; Torrijos, M; Moletta, R; Delgenès, J P

    2010-05-01

    A thermochemical pretreatment, i.e. saponification, was optimised in order to improve anaerobic biodegradation of slaughterhouse wastes such as aeroflotation grease and flesh fats from cattle carcass. Anaerobic digestion of raw wastes, as well as of wastes saponified at different temperatures (60 degrees C, 120 degrees C and 150 degrees C) was conducted in fed-batch reactors under mesophilic condition and the effect of different saponification temperatures on anaerobic biodegradation and on the long-chain fatty acids (LCFAs) relative composition was assessed. Even after increasing loads over a long period of time, raw fatty wastes were biodegraded slowly and the biogas potentials were lower than those of theoretical estimations. In contrast, pretreated wastes exhibited improved batch biodegradation, indicating a better initial bio-availability, particularly obvious for carcass wastes. However, LCFA relative composition was not significantly altered by the pretreatment. Consequently, the enhanced biodegradation should be attributed to an increased initial bio-availability of fatty wastes without any modification of their long chain structure which remained slowly biodegradable. Finally, saponification at 120 degrees C achieved best performances during anaerobic digestion of slaughterhouse wastes.

  18. Feasibility of biohydrogen production from cheese whey using a UASB reactor: Links between microbial community and reactor performance

    Energy Technology Data Exchange (ETDEWEB)

    Castello, E.; Garcia y Santos, C.; Borzacconi, L. [Chemical Engineering Institute, School of Engineering, University of the Republic, Herrera y Reissig 565, Montevideo (Uruguay); Iglesias, T.; Paolino, G.; Wenzel, J.; Etchebehere, C. [Microbiology Department, School of Science and School of Chemistry, University of the Republic, General Flores 2124, Montevideo (Uruguay)

    2009-07-15

    The present study examines the feasibility of producing hydrogen by dark fermentation using unsterilised cheese whey in a UASB reactor. A lab-scale UASB reactor was operated for more than 250 days and unsterilised whey was used as the feed. The evolution of the microbial community was studied during reactor operation using molecular biology tools (T-RFLP, 16S rRNA cloning library and FISH) and conventional microbiological techniques. The results showed that hydrogen can be produced but in low amounts. For the highest loading rate tested (20 gCOD/L.d), hydrogen production was 122 mL H{sub 2}/L.d. Maintenance of low pH (mean = 5) was insufficient to control methanogenesis; methane was produced concomitantly with hydrogen, suggesting that the methanogenic biomass adapted to the low pH conditions. Increasing the loading rate to values of 2.5 gCOD/gVSS.d favoured hydrogen production in the reactor. Microbiological studies showed the prevalence of fermentative organisms from the genera Megasphaera, Anaerotruncus, Pectinatus and Lactobacillus, which may be responsible for hydrogen production. However, the persistence of methanogenesis and the presence of other fermenters, not clearly recognised as hydrogen producers indicates that competition for the substrate may explain the low hydrogen production. (author)

  19. Composition and uses of anaerobic digestion derived biogas from wastewater treatment facilities in North America.

    Science.gov (United States)

    Lackey, Jillian C; Peppley, B; Champagne, P; Maier, A

    2015-08-01

    A study was conducted to determine the current knowledge of biogas production and its use at municipal wastewater treatment plants (WWTPs) across North America. Information was provided by municipal WWTPs across Canada and the US. It was determined that hydrogen sulfide (H2S) and silicon (Si) compounds had sufficient variability to be of concern. The only biogas production trend that could be identified was a possible seasonal relationship with sludge input and biogas production. Secondary analysis was performed to observe trends in biogas usage in urban areas larger than 150,000 in the US and 50,000 in Canada; 66% of facilities had anaerobic digestion systems and, of those, only 35% had an energy recovery system. Climatic, population, and socio-political influences on the trends were considered. The primary conclusion was that more data is required to perform significant analyses on biogas production and composition variation.

  20. Increase of anaerobic degradation of particulate organic matter in full-scale biogas plants by mechanical maceration

    DEFF Research Database (Denmark)

    Hartmann, Hinrich; Angelidaki, Irini; Ahring, Birgitte Kiær

    2000-01-01

    Different concepts of implementation of mechanical pretreatment for enhancing the biogas potential from fibers in manure feedstock were evaluated by sampling before and after macerators at different biogas plants and from a fiber separation unit. An increase of the biogas potential of up to 25......% by pretreatment of the whole feed in the macerator before the reactor was observed. implementation concepts with a treatment of the fibers alone after separation from the manure showed to be not efficient due to a low recovery of organic matter in the fibers by the separation unit. The low operational costs...

  1. GAS TURBINE ENGINES CONSUMING BIOGAS

    Directory of Open Access Journals (Sweden)

    Е. Ясиніцький

    2011-04-01

    Full Text Available A problem of implementation of biofuel for power plants of big capacity was considered in thisarticle. Up to date in the world practice a wide implementation of biogas plants of low and medialcapacity are integrated. It is explained by the big amount of enterprises in which relatively smallvolumes of organic sediment excrete in the process of its activity. An emphasis of article is on thatenterprises, which have big volumes of sediments for utilizing of which module system of medialcapacity biogas plants are non-effective. The possibility of using biogas and biomethane as a fuelfor gas turbine engine is described. The basic problems of this technology and ways of its solutionsare indicated. Approximate profitability of biogas due to example of compressor station locatednearby poultry factory was determined also. Such factors as process characteristics of engine withcapacity of 5 MW, approximate commercial price for natural gas and equipment costs due toofficial sources of “Zorg Ukraine” company was taken into consideration. The necessity forproviding researches on influence of biogas on the process characteristics of gas turbine engine andits reliability, constructing modern domestic purification system for biogas was shown.

  2. Biogas Production from Citrus Waste by Membrane Bioreactor

    Science.gov (United States)

    Wikandari, Rachma; Millati, Ria; Cahyanto, Muhammad Nur; Taherzadeh, Mohammad J.

    2014-01-01

    Rapid acidification and inhibition by d-limonene are major challenges of biogas production from citrus waste. As limonene is a hydrophobic chemical, this challenge was encountered using hydrophilic polyvinylidine difluoride (PVDF) membranes in a biogas reactor. The more sensitive methane-producing archaea were encapsulated in the membranes, while freely suspended digesting bacteria were present in the culture as well. In this membrane bioreactor (MBR), the free digesting bacteria digested the citrus wastes and produced soluble compounds, which could pass through the membrane and converted to biogas by the encapsulated cell. As a control experiment, similar digestions were carried out in bioreactors containing the identical amount of just free cells. The experiments were carried out in thermophilic conditions at 55 °C, and hydraulic retention time of 30 days. The organic loading rate (OLR) was started with 0.3 kg VS/m3/day and gradually increased to 3 kg VS/m3/day. The results show that at the highest OLR, MBR was successful to produce methane at 0.33 Nm3/kg VS, while the traditional free cell reactor reduced its methane production to 0.05 Nm3/kg VS. Approximately 73% of the theoretical methane yield was achieved using the membrane bioreactor. PMID:25167328

  3. Biogas Production from Citrus Waste by Membrane Bioreactor

    Directory of Open Access Journals (Sweden)

    Rachma Wikandari

    2014-08-01

    Full Text Available Rapid acidification and inhibition by d-limonene are major challenges of biogas production from citrus waste. As limonene is a hydrophobic chemical, this challenge was encountered using hydrophilic polyvinylidine difluoride (PVDF membranes in a biogas reactor. The more sensitive methane-producing archaea were encapsulated in the membranes, while freely suspended digesting bacteria were present in the culture as well. In this membrane bioreactor (MBR, the free digesting bacteria digested the citrus wastes and produced soluble compounds, which could pass through the membrane and converted to biogas by the encapsulated cell. As a control experiment, similar digestions were carried out in bioreactors containing the identical amount of just free cells. The experiments were carried out in thermophilic conditions at 55 °C, and hydraulic retention time of 30 days. The organic loading rate (OLR was started with 0.3 kg VS/m3/day and gradually increased to 3 kg VS/m3/day. The results show that at the highest OLR, MBR was successful to produce methane at 0.33 Nm3/kg VS, while the traditional free cell reactor reduced its methane production to 0.05 Nm3/kg VS. Approximately 73% of the theoretical methane yield was achieved using the membrane bioreactor.

  4. Performance comparison of a continuous-flow stirred-tank reactor and an anaerobic sequencing batch reactor for fermentative hydrogen production depending on substrate concentration.

    Science.gov (United States)

    Kim, S-H; Han, S-K; Shin, H-S

    2005-01-01

    This study was conducted to compare the performance of a continuous-flow stirred-tank reactor (CSTR) and an anaerobic sequencing batch reactor (ASBR) for fermentative hydrogen production at various substrate concentrations. Heat-treated anaerobic sludge was utilized as an inoculum, and hydraulic retention time (HRT) for each reactor was maintained at 12 h. At the influent sucrose concentration of 5 g COD/L, start-up was not successful in both reactors. The CSTR, which was started-up at 10 g COD/L, showed stable hydrogen production at the influent sucrose concentrations of 10-60 g COD/L during 203 days. Hydrogen production was dependent on substrate concentration, resulting in the highest performance at 30 g COD/L. At the lower substrate concentration, the hydrogen yield (based on hexose consumed) decreased with biomass reduction and changes in fermentation products. At the higher substrate concentration, substrate inhibition on biomass growth caused the decrease of carbohydrate degradation and hydrogen yield (based on hexose added). The ASBR showed higher biomass concentration and carbohydrate degradation efficiency than the CSTR, but hydrogen production in the ASBR was less effective than that in the CSTR at all the substrate concentrations.

  5. Performance evaluation of cigarette filter rods as a biofilm carrier in an anaerobic moving bed biofilm reactor.

    Science.gov (United States)

    Sabzali, Ahmad; Nikaeen, Mahnaz; Bina, Bijan

    2012-01-01

    Biocarriers are an important component of anaerobic moving bed biofilm reactors (AMBBRs). In this study, the capability of cigarette filter rods (CFRs) as a biocarrier in an anaerobic moving bed biofilm reactor was evaluated. Two similar lab-scale anaerobic moving bed biofilm reactors were undertaken using Kaldnes-K3 plastic media and cigarette filter rods (wasted filters from tobacco factories) as biofilm attachment media for wastewater treatment. Organic substance and total posphours (TP) removal was investigated over 100 days. Synthetic wastewater was prepared with ordinary water and glucose as the main sources of carbon and energy, plus balanced macro- and micro-nutrients. Process performance was studied by increasing the organic loading rate (OLR) in the range of 1.6-4.5 kg COD/m3 x d. The COD average removal efficiency were 61.3% and 64.5% for AMBBR with cigarette filter rods (Reactor A) and AMBBR with Kaldnes plastic media (Reactor B), respectively. The results demonstrate that the performance of the AMBBR containing 0.25 litres of cigarette filters was comparable with a similar reactor containing 1.5 litres of Kaldnes plastic media. An average phosphorus removal of 67.7% and 72.9% was achieved by Reactors A and B, respectively.

  6. Integrated application of upflow anaerobic sludge blanket reactor for the treatment of wastewaters.

    Science.gov (United States)

    Latif, Muhammad Asif; Ghufran, Rumana; Wahid, Zularisam Abdul; Ahmad, Anwar

    2011-10-15

    The UASB process among other treatment methods has been recognized as a core method of an advanced technology for environmental protection. This paper highlights the treatment of seven types of wastewaters i.e. palm oil mill effluent (POME), distillery wastewater, slaughterhouse wastewater, piggery wastewater, dairy wastewater, fishery wastewater and municipal wastewater (black and gray) by UASB process. The purpose of this study is to explore the pollution load of these wastewaters and their treatment potential use in upflow anaerobic sludge blanket process. The general characterization of wastewater, treatment in UASB reactor with operational parameters and reactor performance in terms of COD removal and biogas production are thoroughly discussed in the paper. The concrete data illustrates the reactor configuration, thus giving maximum awareness about upflow anaerobic sludge blanket reactor for further research. The future aspects for research needs are also outlined.

  7. Biogas from renewable resources through dry anaerobic digestion; Biogas aus NaWaRos durch Trockenfermentation

    Energy Technology Data Exchange (ETDEWEB)

    Heiermann, M. [ATB, Potsdam (Germany). Abt. Technikbewertung und Stoffkreislaeufe; Linke, B. [ATB, Potsdam (Germany). Abt. Bioverfahrenstechnik; Kessler, U. [Agrargenossenschaft Pirow e.G. (Germany). Biogasanlage; Loock, R. [Ingenieurbuero Loock Consultants, Hamburg (Germany)

    2007-07-01

    The functionality, performance and operational safety of anaerobic digestion using the dry-wet simultaneous technique of Loock Consultants were investigated at the biogas pilot plant in Pirow (State Brandenburg). In addition to determining process parameters and the input and output balance of the digester, chemical characterisation of the substrates and their biogas production potential were determined in the laboratory. The results reveal that a substrate mixture of 60% maize silage, 13% poultry manure and 27% digested material on a mass basis deliver a methane yield of 90 m{sup 3}t{sup -1} fresh matter, if conducted as a three-week batch process. A specific methane yield performance of 0.34 m{sup 3}kg{sup -1} VS is attained, as with dry anaerobic digestion of maize silage, with the standard wet process. (orig.)

  8. Effect of auxotrophies on yeast performance in aerated fed-batch reactor

    Energy Technology Data Exchange (ETDEWEB)

    Landi, Carmine; Paciello, Lucia [Dept. Ingegneria Industriale, Universita di Salerno, Via Ponte Don Melillo, 84084 Fisciano, Salerno (Italy); Alteriis, Elisabetta de [Dept. Biologia Strutturale e Funzionale, Universita degli Studi di Napoli ' Federico II' , Via Cinthia, 80100 Napoli (Italy); Brambilla, Luca [Dept. Biotecnologie e Bioscienze, Universita Milano-Bicocca, Piazza della Scienza, 20126 Milano (Italy); Parascandola, Palma, E-mail: pparascandola@unisa.it [Dept. Ingegneria Industriale, Universita di Salerno, Via Ponte Don Melillo, 84084 Fisciano, Salerno (Italy)

    2011-10-28

    Highlights: Black-Right-Pointing-Pointer The paper contributes to fill the gap existing between the basic and applied research. Black-Right-Pointing-Pointer Mathematical model sheds light on the physiology of auxotrophic yeast strains. Black-Right-Pointing-Pointer Yeast behavior in fed-batch is influenced by biological and environmental determinants. Black-Right-Pointing-Pointer Process optimization would make possible the production of heterologous proteins which are not yet on the market. -- Abstract: A systematic investigation on the effects of auxotrophies on the performance of yeast in aerated fed-batch reactor was carried out. Six isogenic strains from the CEN.PK family of Saccharomyces cerevisiae, one prototroph and five auxotrophs, were grown in aerated fed-batch reactor using the same operative conditions and a proper nutritional supplementation. The performance of the strains, in terms of final biomass decreased with increasing the number of auxotrophies. Auxotrophy for leucine exerted a profound negative effect on the performance of the strains. Accumulation of reactive oxygen species (ROS) in the cells of the strain carrying four auxotrophies and its significant viability loss, were indicative of an oxidative stress response induced by exposure of cells to the environmental conditions. The mathematical model was fundamental to highlight how the carbon flux, depending on the number and type of auxotrophies, was diverted towards the production of increasingly large quantities of energy for maintenance.

  9. Aqueous processing of U-10Mo scrap for high performance research reactor fuel

    Science.gov (United States)

    Youker, Amanda J.; Stepinski, Dominique C.; Maggos, Laura E.; Bakel, Allen J.; Vandegrift, George F.

    2012-08-01

    The Global Threat Reduction Initiative (GTRI) Conversion program, which is part of the US government's National Nuclear Security Administration (NNSA), supports the conversion of civilian use of highly enriched uranium (HEU) to low enriched uranium (LEU) for reactor fuel and targets. The reason for conversion is to eliminate the use of any material that may pose a threat to the United States or other foreign countries. High performance research reactors (HPRRs) cannot make the conversion to a standard LEU fuel because they require a more dense fuel to meet their performance requirements. As a result, a more dense fuel consisting of a monolithic uranium-molybdenum alloy containing 10% (w/w) Mo with Al cladding and a Zr bonding-layer is being considered. Significant losses are expected in the fabrication of this fuel, so a means to recycle the scrap pieces is needed. Argonne National Laboratory has developed an aqueous-processing flowsheet for scrap recovery in the fuel fabrication process for high-density LEU-monolithic fuel based on data found in the literature. Experiments have been performed to investigate dissolution conditions for solutions containing approximately 20 g-U/L and 50 g-U/L with and without Fe(NO3)3. HNO3 and HF concentrations have been optimized for timely dissolution of the fuel scrap and prevention of the formation of the U-Zr2 intermetallic, explosive complex, while meeting the requirements needed for further processing.

  10. Investigation of Discharge Performance of SOFC Using Biogas and Its Off-gas%生物气及其电池尾气 SOFC 放电性能研究

    Institute of Scientific and Technical Information of China (English)

    王德震; 左薇; 张军; 吴晓燕; 孔晓伟

    2015-01-01

    To investigate the discharge performance of Ni-YSZ anode solid oxide fuel cell using various biogas and evaluate the valve of reusing its off-gas, electrochemical performance and gas properties were studied when two SOFC operated in tandem using diverse ratio of CH4/CO2 at 750 ℃. Compared with the cell performance using H2, two SOFC both operated at high power density with the first stage SOFC using various CH4/CO2 biogas and the second stage using the off-gas of the first stage. Both of two SOFC worked mostly steadily at constant current density for short time with little carbon deposition. The analysis of the gas properties at 566 mA•cm-2 indicated that the dry reforming rate was the highest when the ratio of CH4/CO2 was 2. The research results show that power generation of SOFC using biogas and its off-gas is feasible. This research can be useful for designing gas circuit of SOFC piles using biogas.%为探究以不同浓度生物气为燃料的固体氧化物燃料电池(SOFC)发电性能及该类电池尾气的再发电价值,通过模拟含不同比例甲烷和二氧化碳的生物气,在750℃下对气路串联 Ni/YSZ 阳极支撑 SOFC 进行放电性能测试和气体特性分析。放电结果显示燃料气经第一级 SOFC 利用后通入第二级 SOFC,同氢气经过两级 SOFC 相比,不同浓度下生物气均获得了较高的功率密度,且短时间恒流时,两级电池均能稳定运行;两级电池均以566 mA· cm-2电流密度恒流放电时的气体分析表明,当 CO2/CH4为2时,电池内甲烷的干重整率最高。研究结果表明两级 SOFC 使用生物气及其电池尾气发电是可行的,可为以生物气为燃料 SOFC 电堆气路设计提供依据。

  11. Efficient Heat Use from Biogas CHP Plants. Case Studies from Biogas Plants in Latvia

    OpenAIRE

    Dzene, Ilze; Slotiņa, Lāsma

    2013-01-01

    This paper is focusing on efficient heat use from biogas plants. It gives an overview about various biogas heat use options and specifically addresses biogas heat use market in Latvia. In the end three examples from typical agricultural biogas plants in Latvia and their heat use plans are described.

  12. Environmental and economic analysis of application of water hyacinth for eutrophic water treatment coupled with biogas production.

    Science.gov (United States)

    Wang, Zanxin; Calderon, Margaret M

    2012-11-15

    The proliferation of water hyacinth is currently controlled by removing it from a water body and disposing it by landfill in China. Using water hyacinth to remove nutrients from water bodies and to produce biogas is another technically feasible option for the control of water hyacinth, but its environmental and economic performances are not well understood. This study collected data from an experimental biogas plant to develop a lifecycle analysis and a cost benefit analysis for the control of water hyacinth proliferation in a eutrophic lake in China. Comparison was made between the alternative option of using water hyacinth for biogas production and the current practice of disposing it in landfills. The results reveal that the biogas option is economically feasible with a positive energy balance. The removal of water hyacinth to produce biogas can contribute to water quality improvement and GHG emission reduction whose values, however, depend on the processing scale of the biogas plant. Since both the current approach and the biogas option can remove nutrients from water bodies, the additional value of water quality improvement resulting from the biogas option is only possible when the processing scale of the biogas plant is greater than the amount of water hyacinth disposed by landfill. The emission of methane deserves attention when water hyacinth is disposed by landfill. The biogas option can respond to China's policies on water pollution control, renewable energy development, and energy saving and emission reduction.

  13. Advanced Fuels Campaign Light Water Reactor Accident Tolerant Fuel Performance Metrics

    Energy Technology Data Exchange (ETDEWEB)

    Brad Merrill; Melissa Teague; Robert Youngblood; Larry Ott; Kevin Robb; Michael Todosow; Chris Stanek; Mitchell Farmer; Michael Billone; Robert Montgomery; Nicholas Brown; Shannon Bragg-Sitton

    2014-02-01

    The safe, reliable and economic operation of the nation’s nuclear power reactor fleet has always been a top priority for the United States’ nuclear industry. As a result, continual improvement of technology, including advanced materials and nuclear fuels, remains central to industry’s success. Decades of research combined with continual operation have produced steady advancements in technology and yielded an extensive base of data, experience, and knowledge on light water reactor (LWR) fuel performance under both normal and accident conditions. In 2011, following the Great East Japan Earthquake, resulting tsunami, and subsequent damage to the Fukushima Daiichi nuclear power plant complex, enhancing the accident tolerance of LWRs became a topic of serious discussion. As a result of direction from the U.S. Congress, the U.S. Department of Energy Office of Nuclear Energy (DOE-NE) initiated an Accident Tolerant Fuel (ATF) Development program. The complex multiphysics behavior of LWR nuclear fuel makes defining specific material or design improvements difficult; as such, establishing qualitative attributes is critical to guide the design and development of fuels and cladding with enhanced accident tolerance. This report summarizes a common set of technical evaluation metrics to aid in the optimization and down selection of candidate designs. As used herein, “metrics” describe a set of technical bases by which multiple concepts can be fairly evaluated against a common baseline and against one another. Furthermore, this report describes a proposed technical evaluation methodology that can be applied to assess the ability of each concept to meet performance and safety goals relative to the current UO2 – zirconium alloy system and relative to one another. The resultant ranked evaluation can then inform concept down-selection, such that the most promising accident tolerant fuel design option(s) can continue to be developed for lead test rod or lead test assembly

  14. Effect of different salinity adaptation on the performance and microbial community in a sequencing batch reactor.

    Science.gov (United States)

    Zhao, Yuanyuan; Park, Hee-Deung; Park, Jeong-Hoon; Zhang, Fushuang; Chen, Chen; Li, Xiangkun; Zhao, Dan; Zhao, Fangbo

    2016-09-01

    The performance and microbial community profiles in a sequencing batch reactor (SBR) treating saline wastewater were studied over 300days from 0wt% to 3.0wt% salinity. The experimental results indicated that the activated sludge had high sensitivity to salinity variations in terms of pollutants removal and sedimentation. At 2.0wt% salinity, the system retained a good performance, and 95% removal rate of chemical oxygen demand (COD), biochemical oxygen demand (BOD), NH4(+)-N and total phosphorus (TP) could be achieved. Operation before addition salinity revealed the optimal performance and the most microbial diversity indicated by 16S rRNA gene clone library. Sequence analyses illustrated that Candidate_division_TM7 (TM7) was predominant at 2.0 wt% salinity; however, Actinobacteria was more abundant at 3.0wt% salinity.

  15. Mechanical Pretreatment to Increase the Bioenergy Yield for Full-scale Biogas Plants

    DEFF Research Database (Denmark)

    Tsapekos, Panagiotis; Kougias, Panagiotis; Angelidaki, Irini

    % compared to the untreated one. The digestion of meadow grass as an alternative co-substrate had positive impact on the energy yield of full-scale biogas reactors operating with cattle manure, pig manure or mixture of both. A preliminary analysis showed that the addition of meadow grass in a manure based...

  16. Monitoring and control of the biogas process based on propionate concentration using online VFA measurement

    DEFF Research Database (Denmark)

    Boe, Kanokwan; Steyer, J.P.; Angelidaki, Irini

    2008-01-01

    Simple logic control algorithms were tested for automatic control of a lab-scale CSTR manure digester. Using an online VFA monitoring system, propionate concentration in the reactor was used as parameter for control of the biogas process. The propionate concentration was kept below a threshold...

  17. Impact of inner-wall reflection on UV reactor performance as evaluated by using computational fluid dynamics: The role of diffuse reflection.

    Science.gov (United States)

    Li, Wentao; Li, Mengkai; Bolton, James R; Qu, Jiuhui; Qiang, Zhimin

    2017-02-01

    Making use of the reflected ultraviolet (UV) radiation with a reflective inner wall is a promising way to improve UV reactor performance. In this study, the impact of inner-wall reflection on UV reactor performance was evaluated in annular single-lamp UV reactors by using computational fluid dynamics, with an emphasis on the role of diffuse reflection. The UV radiation inside the reactor chamber was simulated using a calibrated discrete ordinates radiation model, which has been proven to be a reliable tool for modeling fluence rate (FR) distributions in UV reactors with a reflective inner wall. The results show that UV reactors with a highly reflective inner wall (Reflectivity = 0.80) had obviously higher FRs and reduction equivalent fluences (REFs) than those with an ordinary inner wall (Reflectivity = 0.26). The inner-wall diffuse reflection further increased the reactor REF, as a result of the elevated volume-averaged FR. The FR distribution uniformity had conditioned contributions to UV reactor performance. Specifically, in UV reactors with a plug-like flow the FR distribution uniformity contributed to the REF to some extent, while in UV reactors with a mixed flow it had little influence on the REF. This study has evaluated, for the first time, the impact of inner-wall diffuse reflection on UV reactor performance and has renewed the understanding about the contribution of FR distribution uniformity to UV reactor performance.

  18. Computational Neutronics Methods and Transmutation Performance Analyses for Light Water Reactors

    Energy Technology Data Exchange (ETDEWEB)

    M. Asgari; B. Forget; S. Piet; R. Ferrer; S. Bays

    2007-03-01

    The urgency for addressing repository impacts has grown in the past few years as a result of Spent Nuclear Fuel (SNF) accumulation from commercial nuclear power plants. One obvious path that has been explored by many is to eliminate the transuranic (TRU) inventory from the SNF thus reducing the need for additional long term repository storage sites. One strategy for achieving this is to burn the separated TRU elements in the currently operating U.S. Light Water Reactor (LWR) fleet. Many studies have explored the viability of this strategy by loading a percentage of LWR cores with TRU in the form of either Mixed Oxide (MOX) fuels or Inert Matrix Fuels (IMF). A task was undertaken at INL to establish specific technical capabilities to perform neutronics analyses in order to further assess several key issues related to the viability of thermal recycling. The initial computational study reported here is focused on direct thermal recycling of IMF fuels in a heterogeneous Pressurized Water Reactor (PWR) bundle design containing Plutonium, Neptunium, Americium, and Curium (IMF-PuNpAmCm) in a multi-pass strategy using legacy 5 year cooled LWR SNF. In addition to this initial high-priority analysis, three other alternate analyses with different TRU vectors in IMF pins were performed. These analyses provide comparison of direct thermal recycling of PuNpAmCm, PuNpAm, PuNp, and Pu.

  19. Study on the Use of Hydride Fuel in High-Performance Light Water Reactor Concept

    Directory of Open Access Journals (Sweden)

    Haileyesus Tsige-Tamirat

    2015-01-01

    Full Text Available Hydride fuels have features which could make their use attractive in future advanced power reactors. The potential benefit of use of hydride fuel in HPLWR without introducing significant modification in the current core design concept of the high-performance light water reactor (HPLWR has been evaluated. Neutronics and thermal hydraulic analyses were performed for a single assembly model of HPLWR with oxide and hydride fuels. The hydride assembly shows higher moderation with softer neutron spectrum and slightly more uniform axial power distribution. It achieves a cycle length of 18 months with sufficient excess reactivity. At Beginning of Cycle the fuel temperature coefficient of the hydride assembly is higher whereas the moderator and void coefficients are lower. The thermal hydraulic results show that the achievable fuel temperature in the hydride assembly is well below the design limits. The potential benefits of the use of hydride fuel in the current design of the HPLWR with the achieved improvements in the core neutronics characteristics are not sufficient to justify the replacement of the oxide fuel. Therefore for a final evaluation of the use of hydride fuels in HPLWR concepts additional studies which include modification of subassembly and core layout designs are required.

  20. Improved catalytic performance of Ni catalysts for steam methane reforming in a micro-channel reactor

    Institute of Scientific and Technical Information of China (English)

    Bozhao Chu; Nian Zhang; Xuli Zhai; Xin Chen; Yi Cheng

    2014-01-01

    Milliseconds process to produce hydrogen by steam methane reforming (SMR) reaction, based on Ni catalyst rather than noble catalyst such as Pd, Rh or Ru, in micro-channel reactors has been paid more and more attentions in recent years. This work aimed to further improve the catalytic performance of nickel-based catalyst by the introduction of additives, i.e., MgO and FeO, prepared by impregnation method on the micro-channels made of metal-ceramic complex substrate. The prepared catalysts were tested in the same micro-channel reactor by switching the catalyst plates. The results showed that among the tested catalysts Ni-Mg catalyst had the highest activity, especially under harsh conditions, i.e., at high space velocity and/or low reaction temperature. Moreover, the catalyst activity and selectivity were stable during the 12 h on stream test even when the ratio of steam to carbon (S/C) was as low as 1.0. The addition of MgO promoted the active Ni species to have a good dispersion on the substrate, leading to a better catalytic performance for SMR reaction.

  1. PREDICTION OF COMBUSTION CHARACTERISTICS OF A TYPICAL BIOGAS BURNER USING CFD

    Directory of Open Access Journals (Sweden)

    K. MADHUSOODAN PILLAI

    2012-07-01

    Full Text Available Biogas is obtained from anaerobic digestion of biodegradable materials such as agricultural waste, animal waste, and othertype of household solid waste and its main constituents are CH4 and CO2. Effects of the concentration of each species are very important in the biogas combustion. The present study focuses on the effect of inlet velocities of methane and air on the flame temperature in a biogas burner lamp. The model of biogas burner lamp is constructed by using the CFD software GAMBIT and the simulation process was performed by using Fluent Software. The flame temperature obtained is 2172 k when the inlet velocities of methane and air are 0.2m/s and 0.8 m/s respectively. Results of this study will provide valuable data for biogas burner lamp manufacturers.

  2. Anaerobic fermentation of biogas liquid pretreated maize straw by rumen microorganisms in vitro.

    Science.gov (United States)

    Jin, Wenyao; Xu, Xiaochen; Gao, Yang; Yang, Fenglin; Wang, Gang

    2014-02-01

    This study intended to investigate the effect of pretreatment of maize straw with biogas liquid on followed fermentation by rumen microorganisms in vitro. The multiple effects including treated time, temperature and dosage of biogas liquid in pretreatment on the followed fermentation performance were analyzed by orthogonal array. The optimum conditions of pretreatment were 9days, 25°C and 50% (v/w) dosage of biogas liquid, which were indicated by the corresponding crystallinity index, dry matter digestibility (DMD) and acetate limiting-step concentration were 57.5%, 73.76% and 1756mg/L, respectively. The ordering sequence of the influential factors for pretreatment was treated time > temperature > dosage of biogas liquid. The results of fermentation showed that the maize straw pretreated by biogas liquid was an efficient and economic pretreatment method of maize straw.

  3. A study on improving the performance of a research reactor's equilibrium core

    Directory of Open Access Journals (Sweden)

    Muhammad Atta

    2013-01-01

    Full Text Available Utilizing low enriched uranium silicide fuel (U3Si2-Al of existing uranium density (3.285 g/cm3, different core configurations have been studied in search of an equilibrium core with an improved performance for the Pakistan Research Reactor-1. Furthermore, we have extended our analysis to the performance of higher density silicide fuels with a uranium density of 4.0 and 4.8 U g/cm3. The criterion used in selecting the best performing core was that of “unit flux time cycle length per 235U mass per cycle”. In order to analyze core performance by improving neutron moderation, utilizing higher-density fuel, the effect of the coolant channel width was also studied by reducing the number of plates in the standard/control fuel element. Calculations employing computer codes WIMSD/4 and CITATION were performed. A ten energy group structure for fission neutrons was used for the generation of microscopic cross-sections through WIMSD/4. To search the equilibrium core, two-dimensional core modelling was performed in CITATION. Performance indicators have shown that the higher-density uranium silicide-fuelled core (U density 4.8 g/cm3 without any changes in standard/control fuel elements, comprising of 15 standard and 4 control fuel elements, is the best performing of all analyzed cores.

  4. The influence of leachates on the extraction of biogas in solid refuse tips; Lixiviados en los vertederos de residuos solidos, su incidencia en la extraccion de biogas

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-08-01

    The presence of leachates not far below the surface in solid refuse tips interferes with biogas generation irrespective of the recovery system employed (vertical or horizontal collectors). Biogas management can be optimised by monitoring the level of leachates, which tem have to be eliminated. The results are given of analytical tests on leachates in urban, urban/industrial and industrial waste dumps. Finally, the system used at the Can Mata dump, in which the leachate is pumped out, is described, Controlling the amount extracted has made it possible to optimise the biogas recovery facility and obtain the best energy performance. (Author)

  5. Energy from whey - comparison of the biogas and bioethanol processes; Energie a partir de petit-lait : comparaison des filieres biogaz et bioethanol

    Energy Technology Data Exchange (ETDEWEB)

    Fruteau de Laclos, H.; Membrez, Y. [Erep SA, Aclens (Switzerland)

    2004-07-01

    This final report for the Swiss Federal Office of Energy (SFOE) presents the results of a project which investigated how energy could be generated from the whey produced in the cheese-making process. The first part of the project aimed to validate a concept for on-site production and use of biogas at a medium-sized cheese factory. The results of the first step, an experimental study carried out using a down-flow fixed-film bio-reactor, are discussed. This allowed the determination of the optimal working parameters as well as providing an estimate of the performance of the process. The second part of the project aimed to compare the bio-ethanol and biogas production processes. It was carried out in collaboration with AlcoSuisse and the Energy Systems Laboratory at the Swiss Federal Institute of Technology (EPFL) in Lausanne. The results of a life-cycle assessment (LCA) are discussed, which compared the two processes from an environmental point of view. Here, two impacts were considered: fossil fuel consumption and greenhouse effect. The replacement of fuel-oil with biogas for heat production and the replacement of conventional petrol with mixture including 5% bio-ethanol were examined. The results are presented that show that there was no significant difference between the two processes. According to the authors, the treatment of one cubic meter of cheese-whey allows savings of more than 20 litres of oil equivalent and 60 kg of CO{sub 2} emissions.

  6. Avaliação do desempenho de um aquecedor para aves adaptado para utilizar biogás como combustível Birds heater adaptation and performance using biogas as fuel

    Directory of Open Access Journals (Sweden)

    Tânia M. B. Santos

    2007-12-01

    Full Text Available Desenvolveu-se ensaio para avaliar a adaptação (diâmetro do injetor e o desempenho (consumo e eficiência de aquecimento de um aquecedor tipo campânula, adaptado para queimar biogás. Foi testado um aquecedor comum que, queimando gás liquefeito de petróleo (GLP, opera à baixa pressão (28 cm.c.a., com capacidade calorífica de 5.024 kJ h-1 e recomendado para 500 aves. O aquecedor foi avaliado com o combustível original (GLP, sem qualquer modificação no injetor de gás, e após adaptação para o funcionamento a biogás. Na adaptação, foi mantida a mesma grelha do queimador principal, aumentando-se a perfuração do injetor para permitir o funcionamento e a avaliação. Foram avaliados cinco injetores com perfurações de 1,0053; 1,5080; 1,5708; 1,7672 e 1,980 mm². Também se variaram as pressões do biogás na entrada do aquecedor de 10; 12; 15; 17 e 20 cm de coluna d'água (cm.c.a.. Os resultados indicaram que as expressões de cálculo teórico e parâmetros propostos na bibliografia podem ser utilizados com segurança na adaptação de aquecedores do tipo campânula utilizados em aviários; que a adaptação é de simples execução, indicando a viabilidade da utilização dos aquecedores já existentes em granjas e no mercado, e que as temperaturas do ar foram semelhantes às obtidas com o combustível original (GLP.It was carried out a trial to evaluate the adaptation (injector diameter and performance (biogas consumption and heating efficiency of a heating adapted to burn biogas. It was tried a common heater, burning liquefied petroleum gas (LPG, operating with low gas pressure (28 cm water column, with calorific capacity of 5024 kJ/h and recommended for 500 birds. The heater was evaluated with the original fuel (LPG without any modification in the gas injector and after adapting to biogas burning. Five injectors were evaluated with drillings of 1,0053; 1,5080; 1,5708; 1,7672 and 1,980 mm2. It also was varied the biogas

  7. Biogas and Hydrogen Systems Market Assessment

    Energy Technology Data Exchange (ETDEWEB)

    Milbrandt, Anelia [National Renewable Energy Lab. (NREL), Golden, CO (United States); Bush, Brian [National Renewable Energy Lab. (NREL), Golden, CO (United States); Melaina, Marc [National Renewable Energy Lab. (NREL), Golden, CO (United States)

    2016-03-31

    This analysis provides an overview of the market for biogas-derived hydrogen and its use in transportation applications. It examines the current hydrogen production technologies from biogas, capacity and production, infrastructure, potential and demand, as well as key market areas. It also estimates the production cost of hydrogen from biogas and provides supply curves at a national level and at point source.

  8. Bounded Biofuels? Sustainability of Global Biogas Developments

    NARCIS (Netherlands)

    Mol, A.P.J.

    2014-01-01

    Compared to liquid biofuels biogas has hardly drawn any attention from social sciences researchers lately. Although the share of biogas and liquid biofuels in the energy portfolio of many countries are comparable, biogas systems are strongly place-based and are non-controversial in terms of sustaina

  9. Characterization of the performances of an innovative heat-exchanger/reactor

    OpenAIRE

    Théron, Felicie; Anxionnaz-Minvielle, Zoé; Cabassud, Michel; Gourdon, Christophe; Tochon, Patrice

    2014-01-01

    International audience; The use of heat exchanger/reactors (HEX/reactors) is a promising way to overcome the barrier of poor heat transfer in batch reactors. However to reach residence time long enough to complete the chemistry,low Reynolds number has to be combined with both a plug flow behaviour and the intensification of heat and mass transfers. This work concerns the experimental approach used to characterize an innovative HEX/reactor. The pilot is made of three process plates sandwiched ...

  10. Performance of the solid deuterium ultra-cold neutron source at the pulsed reactor TRIGA Mainz

    CERN Document Server

    Karch, J; Beck, M; Eberhardt, K; Hampel, G; Heil, W; Kieser, R; Reich, T; Trautmann, N; Ziegner, M

    2013-01-01

    The performance of the solid deuterium ultra-cold neutron source at the pulsed reactor TRIGA Mainz with a maximum peak energy of 10 MJ is described. The solid deuterium converter with a volume of V=160 cm3 (8 mol), which is exposed to a thermal neutron fluence of 4.5x10^13 n/cm2, delivers up to 550 000 UCN per pulse outside of the biological shield at the experimental area. UCN densities of ~ 10/cm3 are obtained in stainless steel bottles of V ~ 10 L resulting in a storage efficiency of ~20%. The measured UCN yields compare well with the predictions from a Monte Carlo simulation developed to model the source and to optimize its performance for the upcoming upgrade of the TRIGA Mainz into a user facility for UCN physics.

  11. Biogas Production from Cow Manure

    Directory of Open Access Journals (Sweden)

    Dewi Artanti Putri

    2012-07-01

    Full Text Available The production of biogas from livestock waste manure in particular is one of the alternative utilization of organic wastes that can be implemented in Indonesia since there is a huge potential of bio-energy in Indonesia. This study utilizes cow manure as the raw material for making biogas and it is coupled with a cow rumen fluid and water. The objective of this study is to determine the effect of manure, rumen, and water composition in biogas production. The research was conducted in anaerobic for 60 days. The composition of manure, water, and the rumen were vary following the variable and ratio; variable A (manure and water; variable B (manure and rumen. The results indicate that the variable A (manure and water with a 1:3 ratio, and the variable B (manure and rumen with a 1:2 ratio produced the highest volume of biogas compared to other ratios. The highest biogas production occurred on average at day 23.

  12. The Effect of Duct Level on the Performance of Reactor Vault Cooling System in the PGSFR

    Energy Technology Data Exchange (ETDEWEB)

    Yeom, Sujin; Ryu, Seung Ho; Kim, Dehee; Lee, Tae-Ho [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2015-10-15

    Development of the prototype gen-Ⅵ sodium-cooled fast reactor (PGSFR) has been ongoing in Korea Atomic Energy Research Institute (KAERI). A reactor vault cooling system (RVCS), one of passive decay heat removal systems (PDHRS), passively removes core decay heat by chimney effect when severe accidents occur. The air cooling path is located around containment vessel (CV). An air separator which divides the downstream air and the upstream air is installed between CV and the concrete wall. To design the RVCS, key design parameters such as stack height, gap size between the concrete wall and the air separator, gap size between the air separator and the CV, thickness and layer composition of the air separator have to be determined. A duct level is one of these design parameters. It denotes the height of the upstream air path and related to the heat transfer length from CV to air. The duct level should be optimized with considering structural reliability and heat removal performance. Thus, in this paper, the heat removal performance of RVCS is evaluated depends on the duct level using 1D system design code, that is developed by KAERI autonomously, and commercial CFD program for optimum design of RVCS In this paper, the heat removal performance of RVCS is evaluated depends on the duct level using PARS2- LMR code and commercial CFD program for optimum design of RVCS to satisfy both conflicting needs, structural reliability and cooling performance. As a result of PARS2-LMR code analysis, it was observed that the heat removal rate increases as increase of duct level and the geometrical conditions, that satisfy the design limitations, were obtained. To qualitatively observe the trends of local temperature distribution, CFD simulations were conducted and hotspots were observed at the upper region of ducts for the low duct level case.

  13. Aqueous processing of U-10Mo scrap for high performance research reactor fuel

    Energy Technology Data Exchange (ETDEWEB)

    Youker, Amanda J., E-mail: youker@anl.gov [Chemical Sciences and Engineering Division, Argonne National Laboratory, 9700 S. Cass Avenue, Argonne, IL 60439 (United States); Stepinski, Dominique C.; Maggos, Laura E.; Bakel, Allen J.; Vandegrift, George F. [Chemical Sciences and Engineering Division, Argonne National Laboratory, 9700 S. Cass Avenue, Argonne, IL 60439 (United States)

    2012-08-15

    Highlights: Black-Right-Pointing-Pointer GTRI program supports conversion from HEU to LEU. Black-Right-Pointing-Pointer High performance research reactors require a dense LEU fuel such as U-10Mo foils. Black-Right-Pointing-Pointer Dissolution conditions for U-10Mo foils in acidic media have been optimized. Black-Right-Pointing-Pointer Solvent-extraction processing can be used to recover U lost in fuel fabrication. Black-Right-Pointing-Pointer Flowsheets were developed using Argonne-design contactors but other contactors can be used as well. - Abstract: The Global Threat Reduction Initiative (GTRI) Conversion program, which is part of the US government's National Nuclear Security Administration (NNSA), supports the conversion of civilian use of highly enriched uranium (HEU) to low enriched uranium (LEU) for reactor fuel and targets. The reason for conversion is to eliminate the use of any material that may pose a threat to the United States or other foreign countries. High performance research reactors (HPRRs) cannot make the conversion to a standard LEU fuel because they require a more dense fuel to meet their performance requirements. As a result, a more dense fuel consisting of a monolithic uranium-molybdenum alloy containing 10% (w/w) Mo with Al cladding and a Zr bonding-layer is being considered. Significant losses are expected in the fabrication of this fuel, so a means to recycle the scrap pieces is needed. Argonne National Laboratory has developed an aqueous-processing flowsheet for scrap recovery in the fuel fabrication process for high-density LEU-monolithic fuel based on data found in the literature. Experiments have been performed to investigate dissolution conditions for solutions containing approximately 20 g-U/L and 50 g-U/L with and without Fe(NO{sub 3}){sub 3}. HNO{sub 3} and HF concentrations have been optimized for timely dissolution of the fuel scrap and prevention of the formation of the U-Zr{sub 2} intermetallic, explosive complex, while

  14. Advanced Concepts for Pressure-Channel Reactors: Modularity, Performance and Safety

    Science.gov (United States)

    Duffey, Romney B.; Pioro, Igor L.; Kuran, Sermet

    Based on an analysis of the development of advanced concepts for pressure-tube reactor technology, we adapt and adopt the pressure-tube reactor advantage of modularity, so that the subdivided core has the potential for optimization of the core, safety, fuel cycle and thermal performance independently, while retaining passive safety features. In addition, by adopting supercritical water-cooling, the logical developments from existing supercritical turbine technology and “steam” systems can be utilized. Supercritical and ultra-supercritical boilers and turbines have been operating for some time in coal-fired power plants. Using coolant outlet temperatures of about 625°C achieves operating plant thermal efficiencies in the order of 45-48%, using a direct turbine cycle. In addition, by using reheat channels, the plant has the potential to produce low-cost process heat, in amounts that are customer and market dependent. The use of reheat systems further increases the overall thermal efficiency to 55% and beyond. With the flexibility of a range of plant sizes suitable for both small (400 MWe) and large (1400 MWe) electric grids, and the ability for co-generation of electric power, process heat, and hydrogen, the concept is competitive. The choice of core power, reheat channel number and exit temperature are all set by customer and materials requirements. The pressure channel is a key technology that is needed to make use of supercritical water (SCW) in CANDU®1 reactors feasible. By optimizing the fuel bundle and fuel channel, convection and conduction assure heat removal using passive-moderator cooling. Potential for severe core damage can be almost eliminated, even without the necessity of activating the emergency-cooling systems. The small size of containment structure lends itself to a small footprint, impacts economics and building techniques. Design features related to Canadian concepts are discussed in this paper. The main conclusion is that development of

  15. Performance and microbial ecology of a nitritation sequencing batch reactor treating high-strength ammonia wastewater

    Science.gov (United States)

    Chen, Wenjing; Dai, Xiaohu; Cao, Dawen; Wang, Sha; Hu, Xiaona; Liu, Wenru; Yang, Dianhai

    2016-01-01

    The partial nitrification (PN) performance and the microbial community variations were evaluated in a sequencing batch reactor (SBR) for 172 days, with the stepwise elevation of ammonium concentration. Free ammonia (FA) and low dissolved oxygen inhibition of nitrite-oxidized bacteria (NOB) were used to achieve nitritation in the SBR. During the 172 days operation, the nitrogen loading rate of the SBR was finally raised to 3.6 kg N/m3/d corresponding the influent ammonium of 1500 mg/L, with the ammonium removal efficiency and nitrite accumulation rate were 94.12% and 83.54%, respectively, indicating that the syntrophic inhibition of FA and low dissolved oxygen contributed substantially to the stable nitrite accumulation. The results of the 16S rRNA high-throughput sequencing revealed that Nitrospira, the only nitrite-oxidizing bacteria in the system, were successively inhibited and eliminated, and the SBR reactor was dominated finally by Nitrosomonas, the ammonium-oxidizing bacteria, which had a relative abundance of 83%, indicating that the Nitrosomonas played the primary roles on the establishment and maintaining of nitritation. Followed by Nitrosomonas, Anaerolineae (7.02%) and Saprospira (1.86%) were the other mainly genera in the biomass. PMID:27762325

  16. Microbial community structure and performance of an anaerobic reactor digesting cassava pulp and pig manure.

    Science.gov (United States)

    Panichnumsin, P; Ahring, B; Nopharatana, A; Chaiprasert, P

    2012-01-01

    Microbial community dynamics in response to changes in substrate types (i.e. pig manure (PM), cassava pulp (CP) and mixtures of PM and CP) were investigated in an anaerobic continuously stirred tank reactor (CSTR). Molecular identification of bacterial and archaeal domains were performed, using a 16S rDNA clone library with polymerase chain reaction-denaturing gradient gel electrophoresis (PCR-DGGE) screening and phylogenetic analysis. Analysis of bacterial clone libraries revealed that the differences in the community structure corresponded to the substrate types. However, the Bacteroidetes were the most abundant group in all substrates, followed by the Clostridia. With pure PM, the dominant bacterial groups were Bacteroidales, Clostridia and Paludibacter. With a co-substrate, at CP to PM (CP:PM) ratio of 50:50, the sequences analysis revealed the greatest diversity of bacterial communities at class level, and the sequences affiliated with Cytophaga sp. became an exclusive predominant. With CP alone, Bacteroides sp. was the dominant species and this reactor had the lowest diversity of bacteria. Archaea observed in the CSTR fed with all substrate types were Methanosaeta sp., Methanosaeta concilii and Methanospirillum hungatei. Among the Archaea, Methanosaeta sp. was the exclusive predominant. The relative distribution of Archaea also changed regarding to the substrate types.

  17. Feasibility study of fuel cladding performance for application in ultra-long cycle fast reactor

    Science.gov (United States)

    Jung, Ju Ang; Kim, Seung Hyun; Shin, Sang Hun; Bang, In Cheol; Kim, Ji Hyun

    2013-09-01

    As a part of the research and development activities for long-life core sodium-cooled fast reactors, the cladding performance of the ultra-long cycle fast reactor (UCFR) is evaluated with two design power levels (1000 MWe and 100 MWe) and cladding peak temperatures (873 K and 923 K). The key design concept of the UCFR is that it is non-refueling during its 30-60 years of operation. This concept may require a maximum peak cladding temperature of 923 K and a cladding radiation damage of over 200 dpa (displacements per atom). Therefore, for the design of the UCFR, deformation due to thermal creep, irradiation creep, and swelling must be taken into consideration through quantitative evaluations. As candidate cladding materials for use in UCFRs, ferritic-martensitic (FM) steels, oxide dispersion strengthened (ODS) steels, and SiC-based composite materials are studied using deformation behavior modeling for a feasibility evaluation. The results of this study indicate that SiC is a potential UCFR cladding material, with the exception of irradiation creep due to high neutron fluence stemming from its long operating time of about 30-60 years.

  18. Performance of a fixed-bed biofilm reactor with microbubble aeration in aerobic wastewater treatment.

    Science.gov (United States)

    Zhang, Lei; Liu, Junliang; Liu, Chun; Zhang, Jing; Yang, Jingliang

    2016-01-01

    Microbubble aeration is supposed to be highly efficient for oxygen supply in aerobic wastewater treatment. In the present study, the performance of a fixed-bed biofilm reactor microbubble-aerated using a Shirasu porous glass (SPG) membrane system was investigated when treating synthetic municipal wastewater. The biofilm formation on the carriers was enhanced with microbubble aeration due to the strong adhesion of microbubbles to the solid surface. The dissolved oxygen concentration, the removals of chemical oxygen demand (COD) and nitrogen, and the oxygen utilization efficiency were influenced by the organic loading rate at a certain oxygen supply capacity. The relatively optimal organic loading rate was determined as 0.82 kgCOD/(m(3)d) when the oxygen supply capacity was 0.93 kgO(2)/(m(3)d), where COD and ammonia removal efficiencies were 91.7% and 53.9%, respectively. The corresponding SPG membrane area-based COD removal capacity was 6.88 kgCOD/(m(2)d). The oxygen utilization efficiency of microbubble aeration was obviously higher compared to conventional bubble aeration. The simultaneous nitrification and denitrification occurred in the biofilm reactor and the total nitrogen removal efficiency of 50.4% was achieved under these conditions. In addition, the increase in air supply capacity of the SPG membrane system was suggested to improve its energy utilization efficiency.

  19. Treatment of slaughterhouse wastewater in anaerobic sequencing batch reactors

    Energy Technology Data Exchange (ETDEWEB)

    Masse, D. I.; Masse, L. [Agriculture and Agri-Food Canada, Lennoxville, PQ (Canada)

    2000-09-01

    Slaughterhouse waste water was treated in anaerobic sequencing batch reactors operated at 30 degrees C. Two of the batch reactors were seeded with anaerobic granular sludge from a milk processing plant reactor; two others received anaerobic non-granulated sludge from a municipal waste water treatment plant. Influent total chemical oxygen demand was reduced by 90 to 96 per cent at organic loading rates ranging from 2.07 kg to 4.93 kg per cubic meter. Reactors seeded with municipal sludge performed slightly better than those containing sludge from the milk processing plant. The difference was particularly noticeable during start-up, but the differences between the two sludges were reduced with time. The reactors produced a biogas containing 75 per cent methane. About 90.5 per cent of the chemical oxygen demand removed was methanized; volatile suspended solids accumulation was determined at 0.068 kg per kg of chemical oxygen demand removed. The high degree of methanization suggests that most of the soluble and suspended organic material in slaughterhouse waste water was degraded during the treatment in the anaerobic sequencing batch reactors. 30 refs., 1 tab., 6 figs.

  20. Biogas production from catch crops

    DEFF Research Database (Denmark)

    Molinuevo-Salces, Beatriz; Larsen, Søren U.; Ahring, Birgitte Kiær

    2013-01-01

    Manure-based biogas plants in Denmark are dependent on high yielding biomass feedstock in order to secure economically feasible operation. The aim of this study was to investigate the potential of ten different catch crop species or mixtures as feedstock for biogas production in co......, being in the ranges of 1.4–3.0 t ha−1 and 0.3–1.7 t ha−1 for Holstebro and Aabenraa, respectively. Specific methane yields were in the range of 229–450 m3 t−1 of VS. Methane yields per hectare of up to 800 m3 ha−1 were obtained, making catch crops a promising source of feedstock for manure-based biogas...

  1. Anaerobic digestion of different feedstocks: impact on energetic and environmental balances of biogas process.

    Science.gov (United States)

    Bacenetti, Jacopo; Negri, Marco; Fiala, Marco; González-García, Sara

    2013-10-01

    The possibility of limiting the global warming is strictly linked to the reduction of GHG emissions. Renewable energy both allows reducing emissions and permits to delay fossil fuel depletion. The anaerobic digestion of animal manure and energy crops is a promising way of reducing GHG emissions. In Italy agricultural biogas production was considerably increased; nowadays there are about 520 agricultural biogas plants. The increasing number of biogas plants, especially of those larger than 500 kW(e) (electrical power), involves a high consumption of energy crops, large transport distances of biomass and digestate and difficulties on thermal energy valorization. In this study the energetic (CED) and environmental (GHG emissions) profiles associated with the production of electricity derived from biogas have been identified. Three biogas plants located in Northern Italy have been analyzed. The study has been carried out considering a cradle-to-grave perspective and thus, special attention has been paid on the feedstock production and biogas production process. The influences on the results taking into account different plant sizes and feeding rate has been assessed in detail. Energy analysis was performed using the Cumulative Energy Demand method (CED). The climate change was calculated for a 100-year time frame based on GHG emissions indicated as CO2 equivalents (eq) and defined by the IPCC (2006). In comparison to the fossil reference system, the electricity production using biogas saves GHG emissions from 0.188 to 1.193 kg CO2eq per kWh(e). Electricity supply from biogas can also contribute to a considerable reduction of the use of fossil energy carriers (from -3.97 to 10.08 MJ(fossil) per kWh(e)). The electricity production from biogas has a big potential for energy savings and reduction of GHG emissions. Efficient utilization of the cogenerated heat can substantially improve the GHG balance of electricity production from biogas.

  2. Performance of co-immobilized yeast and glucoamylase in a fluidized bed reactor for fuel ethanol production

    Energy Technology Data Exchange (ETDEWEB)

    Sun, M.Y.; Bienkowski, P.R.; Davison, B.H. [Oak Ridge National Lab., TN (United States)]|[Univ. of Tennessee, Knoxville, TN (United States); Spurrier, M.A.; Webb, O.F. [Univ. of Tennessee, Knoxville, TN (United States)

    1996-07-01

    The performance of co-immobilized Saccharomyces cerevisiae and glucoamylase was evaluated in a fluidized bed reactor. Soluble starch and yeast extract were used as feed stocks. The biocatalyst performed well and demonstrated no significant loss of activity or physical integrity during 10 weeks of continuous operation. The reactor was easily operated and required no pH control. No operational problems were encountered from bacterial contaminants even though the reactor was operated under non-sterile conditions over the entire course of experiments. Productivities ranged between 25 to 44 g ethanol L{sup -1} h{sup -1}. The experiments demonstrated that ethanol inhibition and bed loading had significant effects on bed performance.

  3. Performance characterization of geopolymer composites for hot sodium exposed sacrificial layer in fast breeder reactors

    Energy Technology Data Exchange (ETDEWEB)

    Haneefa, K. Mohammed, E-mail: mhkolakkadan@gmail.com [Department of Civil Engineering, IIT Madras, Chennai (India); Santhanam, Manu [Department of Civil Engineering, IIT Madras, Chennai (India); Parida, F.C. [Radiological Safety Division, Indira Gandhi Centre for Atomic Research, Kalpakkam (India)

    2013-12-15

    Highlights: • Performance evaluation of geopolymers subjected to hot liquid sodium is performed. • Apart from mechanical properties, micro-analytical techniques are used for material characterization. • The geopolymer composite showed comparatively lesser damage than conventional cement composites. • Geopolymer technology can emerge as a new choice for sacrificial layer in SCFBRs. - Abstract: A sacrificial layer of concrete is used in sodium cooled fast breeder reactors (SCFBRs) to mitigate thermo-chemical effect of accidentally spilled sodium at and above 550 °C on structural concrete. Performance of this layer is governed by thermo-chemical stability of the ingredients of sacrificial layer concrete. Concrete with limestone aggregate is generally used as a sacrificial layer. Conventional cement based systems exhibit instability in hot liquid sodium environment. Geo-polymer composites are well known to perform excellently at elevated temperatures compared to conventional cement systems. This paper discusses performance of such composites subjected to exposure of hot liquid sodium in air. The investigation includes comprehensive evaluation of various geo-polymer composites before any exposure, after heating to 550 °C in air, and after immersing in hot liquid sodium initially heated to 550 °C in air. Results from the current study indicate that hot liquid sodium produces less damage to geopolymer composites than to the existing conventional cement based system. Hence, the geopolymer technology has potential application in mitigating the degrading effects of sodium fires and can emerge as a new choice for sodium exposed sacrificial layer in SCFBRs.

  4. Effect of Fuelling Depth on the Fusion Performance and Particle Confinement of a Fusion Reactor

    Science.gov (United States)

    Wang, Shijia; Wang, Shaojie

    2016-12-01

    The fusion performance and particle confinement of an international thermonuclear experimental reactor (ITER)-like fusion device have been modeled by numerically solving the energy transport equation and the particle transport equation. The effect of fuelling depth has been investigated. The plasma is primarily heated by the fusion produced alpha particles and the loss process of particles and energy in the scrape-off layer has been taken into account. To study the effect of fuelling depth on fusion performance, the ITERH-98P(y,2) scaling law has been used to evaluate the transport coefficients. It is shown that the particle confinement and fusion performance are significantly dependent on the fuelling depth. Deviation of 10% of the minor radius on fuelling depth can make the particle confinement change by ∼ 61% and the fusion performance change by ∼ 108%. The enhancement of fusion performance is due to the better particle confinement induced by deeper particle fuelling. supported by National Natural Science Foundation of China (Nos. 11175178 and 11375196) and the National Magnetic Confinement Fusion Science Program of China (No. 2014GB113000)

  5. Stability of an anaerobic reactor with support means in the treatment of cassava through the monitoring of relationship AV/AT specific and production of biogas; Estabilidade de um reator anaerobio com meio suporte no tratamento da manipueira atraves do monitoramento da relacao AV/AT e producao especifica de biogas

    Energy Technology Data Exchange (ETDEWEB)

    Kunzleri, Kathia; Watthier, Elisangela; Gomes, Simone D.; Miguel, Joao F.A. [Universidade Estadual do Oeste do Parana (UNIOESTE), Cascavel, PR (Brazil); Andreani, Cristina Lurdes [Conselho Nacional de Desenvolvimento Cientifico e Tecnologico (CNPq), Brasilia, DF (Brazil)

    2010-07-01

    This study aimed to evaluate the removal of different organic loading in an anaerobic reactor for treatment of cassava wastewater, and as a medium bamboo rings. Cassava wastewater study is derived from a starch industry. The wastewater was characterized following the method described in Standard Methods for Examination of Water and Wastewater. The reactor was constructed of PVC, with a volume of 6.8 liters. The results were evaluated by variance analysis (parametric ANOVA) using the software Statistica 7.0. We observed a higher yield for the charge of 5, 601 (4) gDQO / L day, the ratio av/at was below 0.5 thus ensuring system stability. (author)

  6. Performance of continuous stirred tank reactor (CSTR) on fermentative biohydrogen production from melon waste

    Science.gov (United States)

    Cahyari, K.; Sarto; Syamsiah, S.; Prasetya, A.

    2016-11-01

    This research was meant to investigate performance of continuous stirred tank reactor (CSTR) as bioreactor for producing biohydrogen from melon waste through dark fermentation method. Melon waste are commonly generated from agricultural processing stages i.e. cultivation, post-harvesting, industrial processing, and transportation. It accounted for more than 50% of total harvested fruit. Feedstock of melon waste was fed regularly to CSTR according to organic loading rate at value 1.2 - 3.6 g VS/ (l.d). Optimum condition was achieved at OLR 2.4 g VS/ (l.d) with the highest total gas volume 196 ml STP. Implication of higher OLR value is reduction of total gas volume due to accumulation of acids (pH 4.0), and lower substrate volatile solid removal. In summary, application of this method might valorize melon waste and generates renewable energy sources.

  7. Enzyme hydrolysis of plasma proteins in a CSTR ultrafiltration reactor: Performances and modeling.

    Science.gov (United States)

    Bressollier, P; Petit, J M; Julien, R

    1988-05-01

    By investigating the effects of four operating variables-volume (V), Ultrafiltration flux (J), enzyme concentration (E), and substrate concentration (S)-on capacity (K) and conversion rate (epsilon) of a hollow fiber CSTR, the performances of the CSTR and the kinetic constants of the reaction were determined. A model which takes into account the course of fractional conversion (X) according to the modified space-time parameter, tau (integrated form of V, J, S, and E), was devised by employing the relationship to integrate the equation for the reaction rate of the CSTR and the expression of the modified space time. Correlation of this model and the experimentally obtained results demonstrates that the characteristics for an ultrafiltration membrane reactor for enzymatic hydrolysis by alcalase of plasma proteins are close to those of an ideal CSTR. Optimal scaling up, however, remains dependent on the compromise which may be obtained between capacity and the conversion rate.

  8. Anaerobic digestion performance of vinegar residue in continuously stirred tank reactor.

    Science.gov (United States)

    Li, Lin; Feng, Lu; Zhang, Ruihong; He, Yanfeng; Wang, Wen; Chen, Chang; Liu, Guangqing

    2015-06-01

    Anaerobic digestion (AD) of vinegar residue was investigated in continuously stirred tank reactor (CSTR). The influence of organic loading rate (OLR) and effluent recirculation on AD performance of vinegar residue was tested. Five OLRs, 1.0, 1.5, 2.0, 2.5, and 3.0 g(vs) L(-1) d(-1), were used. The highest volumetric methane productivity of 581.88 mL L(-1) was achieved at OLR of 2.5 g(vs) L(-1) d(-1). Effluent reflux ratio was set as 50%, the results showed that effluent recirculation could effectively neutralize the acidity of vinegar residue, raise the pH of the feedstock, and enhance the buffering capacity of the AD system. Anaerobic digestion of vinegar residue could be a promising way not only for converting this waste into gas energy but also alleviating environmental pollution which might be useful for future industrial application.

  9. Study on the effect of the impeller and diffuser blade number on reactor coolant pump performances

    Science.gov (United States)

    Long, Y.; Yin, J. L.; Wang, D. Z.; Li, T. B.

    2016-05-01

    In this paper, CFD approach was employed to study how the blade number of impeller and diffuser influences reactor coolant pump performances. The three-dimensional pump internal flow channel was modelled by pro/E software, Reynolds-averaged Naiver-Stokes equations with the k-ε turbulence model were solved by the computational fluid dynamics software CFX. By post-processing on the numerical results, the performance curves of reactor coolant pump were obtained. The results are as follows, with the blade number of the impeller increasing, the head of the pump with different diffuser universally increases in the 8Q n∼1.2Q n conditions, and at different blade number of the diffuser, the head increases with the blade number of the impeller increasing. In 1.0Q n condition, when the blades number combination of impeller and diffuser chooses 4+16, 7+14 and 6+18, the head curves exist singular points. In 1.2Q n condition, the head curve still exists singular point in 6+18. With the blade number of the impeller increasing, the efficiency of the pump with different diffuser universally decreases in the 0.8Q n and 1.0Q n conditions, but in 1.2Q n condition, the efficiency of the pump with different diffuser universally increases. In 1.0Q n condition, the impellers of 4 and 5 blades are better. When the blade number combination of impeller and diffuser choose 4+11, 4+17, 4+18, 5+12, 5+17 and 5+18, the efficiencies relatively have higher values. With the blade number of the impeller increasing, the hydraulic shaft power of the pump with different diffuser universally increases in the 0.8Q n∼1.2Q n conditions, and with the blade number of the diffuser increasing, the power of different impeller overall has small fluctuation, but tends to be uniform. This means the increase of the diffuser blade number has less influence on shaft power.The influence on the head and flow by the matching relationship of the blades number between impeller and diffuser is very complicated, which

  10. Main technical options of the Jules Horowitz reactor project to achieve high flux performances and high safety level

    Energy Technology Data Exchange (ETDEWEB)

    Ballagny, A.; Bergamaschi, Y.; Bouilloux, Y.; Bravo, X.; Guigon, B.; Rommens, M.; Tremodeux, P. [CEA Cadarache, Dir. de l' Energie Nucleaire DEN, 13 - Saint-Paul-lez-Durance (France)]|[CEA Saclay Dir. de l' Energie Nucleaire DEN, 91 - Gif sur Yvette (France)

    2003-07-01

    Since the shutdown of the SILOE reactor in 1997, the OSIRIS reactor has ensured the needs regarding technological irradiation at CEA including those of its industrial partners and customers. The Jules Horowitz Reactor will replace it and will offer a quite larger experimental field. It has the ambition to provide the necessary nuclear data and to maintain a fission research capability in Europe after 2010. The Jules Horowitz Reactor will represent a significant step in terms of performances and experimental capabilities. This paper will present the main design option resulting from the preliminary studies. The choice of the specific power around 600 kW/I for the reference core configuration is a key decision to ensure the required flux level. Consequently many choices have to be made regarding the materials used in the core and the fuel element design. These involve many specific qualifications including codes validation. The main safety options are based on: - A safety approach based upon the defence-in-depth principle. - A strategy of generic approaches to assess experimental risks in the facility. - Internal events analysis taking into account risks linked to reactor and experiments (e.g., radioactive source-term). - Systematic consideration of external hazards (e.g., earthquake, airplane crash) and internal hazards. - Design of containment to manage and mitigate a severe reactor accident (consideration of 'BORAX' accident, according to french safety practice for MTRs, beyond design basis reactivity insertion accident, involving core melting and core destruction phenomena). (authors)

  11. Steady performance of a zero valent iron packed anaerobic reactor for azo dye wastewater treatment under variable influent quality

    Institute of Scientific and Technical Information of China (English)

    Yaobin Zhang; Yiwen Liu; Yanwen Jing; Zhiqiang Zhao; Xie Quan

    2012-01-01

    Zero valent iron (ZVI) is expected to help create an enhanced anaerobic environment that might improve the performance of anaerobic treatment.Based on this idea,a novel ZVI packed upflow anaerobic sludge blanket (ZVI-UASB) reactor was developed to treat azo dye wastewater with variable influent quality.The results showed that the reactor was less influenced by increases of Reactive Brilliant Red X-3B concentration from 50 to 1000 mg/L and chemical oxygen demand (COD) from 1000 to 7000 mg/L in the feed than a reference UASB reactor without the ZVI.The ZVI decreased oxidation-reduction potential in the reactor by about 80 mV.Iron ion dissolution from the ZVI could buffer acidity in the reactor,the amount of which was related to the COD concentration.Fluorescence in situ hybridization test showed the abundance of methanogens in the sludge of the ZVI-UASB reactor was significantly greater than that of the reference one.Denaturing gradient gel electrophoresis showed that the ZVI increased the diversity of microbial strains responsible for high efficiency.

  12. Steady performance of a zero valent iron packed anaerobic reactor for azo dye wastewater treatment under variable influent quality.

    Science.gov (United States)

    Zhang, Yaobin; Liu, Yiwen; Jing, Yanwen; Zhao, Zhiqiang; Quan, Xie

    2012-01-01

    Zero valent iron (ZVI) is expected to help create an enhanced anaerobic environment that might improve the performance of anaerobic treatment. Based on this idea, a novel ZVI packed upflow anaerobic sludge blanket (ZVI-UASB) reactor was developed to treat azo dye wastewater with variable influent quality. The results showed that the reactor was less influenced by increases of Reactive Brilliant Red X-3B concentration from 50 to 1000 mg/L and chemical oxygen demand (COD) from 1000 to 7000 mg/L in the feed than a reference UASB reactor without the ZVI. The ZVI decreased oxidation-reduction potential in the reactor by about 80 mV. Iron ion dissolution from the ZVI could buffer acidity in the reactor, the amount of which was related to the COD concentration. Fluorescence in situ hybridization test showed the abundance of methanogens in the sludge of the ZVI-UASB reactor was significantly greater than that of the reference one. Denaturing gradient gel electrophoresis showed that the ZVI increased the diversity of microbial strains responsible for high efficiency.

  13. Study of a sequencing batch reactor performance in soft drink wastewater treatment

    Directory of Open Access Journals (Sweden)

    Francisco Javier Cuba Terán

    2009-08-01

    Full Text Available A sequencing batch aerobic reactor in pilot scale was constructed and operated with intermittent aeration in Wastewater Treatment Lab of Faculdade de Ciências e Tecnologia de Unesp at Presidente Prudente city. Research was conducted in order to improve reactor’s performance in organic matter and nitrogen removal by means of the application of different aeration times. In 12 and 14 hours long batch tests, with 6 and 8 hours of aeration, more than 96% of organic matter was removed by the third hour in both cases, in the other hand, nitrification showed 50 and 55% of removal at the end of every cycle. Tough showing nitrate removal, denitrification requires more research to be done in order to obtain more accurate data related with best cycle time for both pollutants removal.Key-words: sequencing batchs, aerobic treatment, industrial wastewater.A sequencing batch aerobic reactor in pilot scale was constructed and operated with intermittent aeration in Wastewater Treatment Lab of Faculdade de Ciências e Tecnologia de Unesp at Presidente Prudente city. Research was conducted in order to improve reactor’s performance in organic matter and nitrogen removal by means of the application of different aeration times. In 12 and 14 hours long batch tests, with 6 and 8 hours of aeration, more than 96% of organic matter was removed by the third hour in both cases, in the other hand, nitrification showed 50 and 55% of removal at the end of every cycle. Tough showing nitrate removal, denitrification requires more research to be done in order to obtain more accurate data related with best cycle time for both pollutants removal.Key-words: sequencing batchs, aerobic treatment, industrial wastewater.

  14. Biological sulphide removal from anaerobically treated domestic sewage: reactor performance and microbial community dynamics.

    Science.gov (United States)

    Garcia, Graziella Patrício Pereira; Diniz, Renata Côrtes Oliveira; Bicalho, Sarah Kinaip; Franco, Vitor Araujo de Souza; Gontijo, Eider Max de Oliveira; Toscano, Rodrigo Argolo; Canhestro, Kenia Oliveira; Santos, Merly Rita Dos; Carmo, Ana Luiza Rodrigues Dias; Lobato, Livia Cristina S; Brandt, Emanuel Manfred F; Chernicharo, Carlos A L; Calabria de Araujo, Juliana

    2015-01-01

    We developed a biological sulphide oxidation system and evaluated two reactors (shaped similar to the settler compartment of an up-flow anaerobic sludge blanket [UASB] reactor) with different support materials for biomass retention: polypropylene rings and polyurethane foam. The start-up reaction was achieved using microorganisms naturally occurring on the open surface of UASB reactors treating domestic wastewater. Sulphide removal efficiencies of 65% and 90% were achieved with hydraulic retention times (HRTs) of 24 and 12 h, respectively, in both reactors. However, a higher amount of elemental sulphur was formed and accumulated in the biomass from reactor 1 (20 mg S(0) g(-1) VTS) than in that from reactor 2 (2.9 mg S(0) g(-1) VTS) with an HRT of 24 h. Denaturing gradient gel electrophoresis (DGGE) results revealed that the the pink and green biomass that developed in both reactors comprised a diverse bacterial community and had sequences related to phototrophic green and purple-sulphur bacteria such as Chlorobium sp., Chloronema giganteum, and Chromatiaceae. DGGE band patterns also demonstrated that bacterial community was dynamic over time within the same reactor and that different support materials selected for distinct bacterial communities. Taken together, these results indicated that sulphide concentrations of 1-6 mg L(-1) could be efficiently removed from the effluent of a pilot-scale UASB reactor in two sulphide biological oxidation reactors at HRTs of 12 and 24 h, showing the potential for sulphur recovery from anaerobically treated domestic wastewater.

  15. Performance of up flow anaerobic sludge fixed film bioreactor for the treatment of high organic load and biogas production of cheese whey wastewater

    OpenAIRE

    Tehrani Nazila Samimi; Najafpour Ghasem D.; Rahimnejad Mostafa; Attar Hossein

    2015-01-01

    Among various wastewater treatment technologies, biological wastewater treatment appears to be the most promising method. A pilot scale of hybrid anaerobic bioreactor was fabricated and used for the whey wastewater treatment. The top and bottom of the hybrid bioreactor known as up flow anaerobic sludge fixed film (UASFF); was a combination of up flow anaerobic sludge blanket (UASB) and up flow anaerobic fixed film reactor (UAFF), respectively. The effects o...

  16. Treatment of a chocolate industry wastewater in a pilot-scale low-temperature UASB reactor operated at short hydraulic and sludge retention time.

    Science.gov (United States)

    Esparza-Soto, M; Arzate-Archundia, O; Solís-Morelos, C; Fall, C

    2013-01-01

    The aim of this work was to evaluate the performance of a 244-L pilot-scale upflow anaerobic sludge blanket (UASB) reactor during the treatment of chocolate-processing industry wastewater under low-temperature conditions (18 ± 0.6 °C) for approximately 250 d. The applied organic loading rate (OLR) was varied between 4 and 7 kg/m(3)/d by varying the influent soluble chemical oxygen demand (CODsol), while keeping the hydraulic retention time constant (6.4 ± 0.3 h). The CODsol removal efficiency was low (59-78%). The measured biogas production increased from 240 ± 54 to 431 ± 61 L/d during the experiments. A significant linear correlation between the measured biogas production and removed OLR indicated that 81.69 L of biogas were produced per kg/m(3) of CODsol removed. Low average reactor volatile suspended solids (VSS) (2,700-4,800 mg/L) and high effluent VSS (177-313 mg/L) were derived in a short sludge retention time (SRT) (4.9 d). The calculated SRT was shorter than those reported in the literature, but did not affect the reactor's performance. Average sludge yield was 0.20 kg-VSS/kg-CODsol. The low-temperature anaerobic treatment was a good option for the pre-treatment of chocolate-processing industry wastewater.

  17. A built-in zero valent iron anaerobic reactor to enhance treatment of azo dye wastewater.

    Science.gov (United States)

    Zhang, Yaobin; Jing, Yanwen; Quan, Xie; Liu, Yiwen; Onu, Pascal

    2011-01-01

    Waste scrap iron was packed into an upflow anaerobic sludge blanket (UASB) reactor to form a zero valent iron (ZVI) - UASB reactor system for treatment of azo dye wastewater. The ZVI acted as a reductant to decrease ORP in the reactor by more than 40 mv and functioned as an acid buffer to increase the pH in the reactor from 5.44 to 6.29, both of which improved the performance of the anaerobic reactor. As a result, the removal of color and COD in this reactor was 91.7% and 53%, respectively, which was significantly higher than that of a reference UASB reactor without ZVI. The UV-visible spectrum demonstrated that absorption bands of the azo dye from the ZVI-UASB reactor were substantially reduced. The ZVI promoted methanogenesis, which was confirmed by an increase in CH(4) content in the biogas from 47.9% to 64.8%. The ZVI bed was protected well from rusting, which allowed it to function stably. The effluent could be further purified only by pH adjustment because the Fe(2+) released from ZVI served as a flocculent.

  18. Biogas production: This is how the Swedes do it

    Energy Technology Data Exchange (ETDEWEB)

    1982-01-01

    In Sweden, biogas is produced according to the Abetong-Sabema process. Thermophilic microorganisms are employed for anaerobic digestion. At 55/sup 0/C, residence time is 3 to 5 days. In contrast to other facilities in application, this means a reduction of the digestion space by a factor of six or seven and, thus, reduced investments. Desinfection of the manure takes place under these high temperatures. With a facility operating since 1978, liquid manure is pumped directly from the stable into a 20 cbm prechamber located in the interior of the gas reactor. The liquid manure is heated to 55/sup 0/C and then discharged into the 240 cbm main chamber where the liquid manure is constantly stirred in order to avoid float layers and deposits. The biogas is compressed, stored and combusted in a Fiat ''Totem'' engine producing electricity and hot water. The facility produces 210,000 cbm of biogas. 310,000 kWh of electricity and 590 kWh of heat are available as useful energy. App. 60% of the total energy can be utilized under Swedish conditions. A 40 cbm facility employs a horizontal cylindric main chamber and a separate prechamber. This facility will work without stirring.

  19. Intensification of biogas production using pretreatment based on hydrodynamic cavitation.

    Science.gov (United States)

    Patil, Pankaj N; Gogate, Parag R; Csoka, Levente; Dregelyi-Kiss, Agota; Horvath, Miklos

    2016-05-01

    The present work investigates the application of hydrodynamic cavitation (HC) for the pretreatment of wheat straw with an objective of enhancing the biogas production. The hydrodynamic cavitation reactor is based on a stator and rotor assembly. The effect of three different speeds of rotor (2300, 2500, 2700 rpm), wheat straw to water ratios (0.5%, 1% and 1.5% wt/wt) and also treatment times as 2, 4 and 6 min have been investigated in the work using the design of experiments (DOE) approach. It was observed that the methane yield of 31.8 ml was obtained with untreated wheat straw whereas 77.9 ml was obtained with HC pre-treated wheat straw confirming the favourable changes during the pre-treatment. The combined pre-treatment using KOH and HC gave maximum yield of biogas as 172.3 ml. Overall, it has been established that significant enhancement in the biogas production can be obtained due to the pretreatment using HC which can also be further intensified by combination with chemical treatment.

  20. Performance of evaluation of methanogenic microbial inoculant and its effect of biogas production in pilot scale test%产甲烷复合菌剂的性能评价及中试试验产气效果

    Institute of Scientific and Technical Information of China (English)

    王渝昆; 袁月祥; 李东; 胡亚东; 黄显波; 昊深; 刘晓风; 彭绪亚; 闫志英

    2014-01-01

    constructed based on the physiological, biochemical characteristics and antagonisms of strain RY3, SH4, G1, G2 and G3. The performances of the inoculant under different pH values, temperatures and application rates of the methanogenic microbial inoculant were evaluated. It showed that the 5 strains had different physiological and biochemical characteristics as well as complementary roles. There were no antagonisms among 5 strains. The methanogenic microbial inoculant grew at pH value 5.5-10.5. Methane productions were 1 706.7-2 026.7μmols at pH value 5.5-9.5 after 3 days’ culture, that of different pH values showed no significant difference respectively. The results indicated that the methanogenic microbial inoculant is resistant to acid and alkali changes. The inoculant grew at 15-70℃ and methane productions were 1 906.9-2 028 μmols at 30-60℃ after 3 days’ culture, that of different temperatures treatment showed no significant difference respectively. The results indicated that the methanogenic microbial inoculant is adapted to a wide temperature range. At 20℃, total biogas yield of treatments 2%, 5%, 10% before 14 day were 234, 422 and 950 mL, and the methane concentration of treatments 2%, 5%, 10% on the 14th day were 46.9%, 51.2% and 58.9%respectively corresponding the treatments with 2%, 5%and 10%inoculation dosages of the methanogenic microbial inoculant. At 50℃, total biogas yield before 14 d were 2728, 3291 and 3 832 mL and the methane concentration on 14th day were 62.7%, 63.1%and 63.8%respectively corresponding the treatments with 2%, 5%and 10%inoculation dosages of the methanogenic microbial inoculant. The results indicated that the inoculation could shorten the starting time for methane production compared to the controls without inoculant at 20 and 50℃. Pilot tests by kinetic analysis indicated that inoculant could still shorten the starting time for methane production compared to the control using anaerobic active sludge as inoculant. At 20

  1. Degradation of household biowaste in reactors.

    Science.gov (United States)

    Krzystek, L; Ledakowicz, S; Kahle, H J; Kaczorek, K

    2001-12-28

    Household derived biowaste was degraded by biological methods. The system involves the combined method of low-solids (up to 10% w/v of total solids (TS)) anaerobic digestion and aerobic degradation for the recovery of energy (biogas) and the production of fine humus-like material which can be used as a soil amender or a substrate for further thermal treatment (pyrolysis, gasification). The performance of batch and continuous processes carried out in bioreactors (stirred tank reactor, air-lift) of working volume 6 and 18 dm(3), at different temperatures (25-42 degrees C) was monitored by reduction of TS, volatile solids, chemical oxygen demand, total organic carbon, C/N in time. The application of continuous process with recirculation (33%) caused that for residence time of 8-16 h the obtained degree of organic load reduction was similar to that obtained after 72-96 h of the batch process. The experimental data of batch aerobic degradation was also subjected to kinetic analysis. The sequence of the two processes: aerobic and anaerobic or anaerobic and aerobic showed that the degree of organic load reduction was similar in both cases, while the amount of produced biogas was four times higher when the first stage was anaerobic. The final product after dewatering was subjected to pyrolysis and gasification. The gases obtained were characterised by a high heat of combustion of about 11-15 MJ Nm(-3).

  2. Defluoridation of drinking water by electrocoagulation/electroflotation in a stirred tank reactor with a comparative performance to an external-loop airlift reactor

    OpenAIRE

    Essadki, Abdel Hafid; Gourich, Bouchaib; Vial, Christophe; Delmas, Henri; Bennajah, Mounir

    2009-01-01

    Defluoridation using batch electrocoagulation/electroflotation (EC/EF) was carried out in two reactors for comparison purpose: a stirred tank reactor (STR) close to a conventional EC cell and an external-loop airlift reactor (ELAR) that was recently described as an innovative reactor for EC. The respective influences of current density, initial concentration and initial pH on the efficiency of defluoridation were investigated. The same trends were observed in both reactors, but the efficiency...

  3. Deeper insight into the structure of the anaerobic digestion microbial community; the biogas microbiome database is expanded with 157 new genomes.

    Science.gov (United States)

    Treu, Laura; Kougias, Panagiotis G; Campanaro, Stefano; Bassani, Ilaria; Angelidaki, Irini

    2016-09-01

    This research aimed to better characterize the biogas microbiome by means of high throughput metagenomic sequencing and to elucidate the core microbial consortium existing in biogas reactors independently from the operational conditions. Assembly of shotgun reads followed by an established binning strategy resulted in the highest, up to now, extraction of microbial genomes involved in biogas producing systems. From the 236 extracted genome bins, it was remarkably found that the vast majority of them could only be characterized at high taxonomic levels. This result confirms that the biogas microbiome is comprised by a consortium of unknown species. A comparative analysis between the genome bins of the current study and those extracted from a previous metagenomic assembly demonstrated a similar phylogenetic distribution of the main taxa. Finally, this analysis led to the identification of a subset of common microbes that could be considered as the core essential group in biogas production.

  4. Pemurnian Biogas untuk meningkatkan Nilai Kalor melalui Adsorpsi Dua Tahap Susunan Seri dengan Media Karbon Aktif

    Directory of Open Access Journals (Sweden)

    YANTI SUPRIANTI

    2016-08-01

    that CH4 content can be upgraded above 78.73%. The optimum performance of serial adsorption column obtained at 2.4 lpm of biogas flow in 10 minutes adsorption time, able to purify biogas to 91.60% of CH4 content. In optimum condition, serial adsorption column effectiveness was 98.31%. Keywords: biogas, purification, activated carbon, adsorption time, serial adsorption column effectiveness.

  5. Performance Analysis of Micro Gas Turbine Using Different Kinds of Biogas Fuel%使用不同生物质气的微型燃气轮机性能分析

    Institute of Scientific and Technical Information of China (English)

    吴旺松; 翁一武

    2012-01-01

    The gas composition and calorific value have great impacts on the gas turbine performance.Usually gas turbine can only use the designed fuel,but in fact the fuel composition often changes.Some typical gas compositions and low caloric values after biomass gasification are introduced.Then by calculation and simulation,this paper analyzes the influence rule of biogas calorific value on micro gas turbine performance,and explores the feasibility of using off-designed fuel in micro gas turbine.%指出燃气的成分和热值对燃气轮机性能的影响很大,一般情况下燃气轮机只能使用设计指定的燃料,但实际上常常会有燃料成分发生变化的情况。介绍了几种典型的生物质气化后的燃气成份与低位热值。通过模拟计算分析生物质气的热值变化对微型燃气轮机性能的影响规律,分析微型燃气轮机使用非设计燃料的可行性。

  6. COMPARISON OF TWO CHEMICAL PRETREATMENTS OF RICE STRAW FOR BIOGAS PRODUCTION BY ANAEROBIC DIGESTION

    Directory of Open Access Journals (Sweden)

    Zilin Song,

    2012-06-01

    Full Text Available Lignocellulosic biomass is considered the most abundant renewable resource that has the potential to contribute remarkably in the supply of biofuel. Previous studies have shown that chemical pretreatment prior to anaerobic digestion (AD can increase the digestibility of lignocellulosic biomass and methane yield. In the present study, the effect of rice straw pretreatment using ammonium hydroxide (NH3•H2O and hydrogen peroxide (H2O2 on the biogasification performance through AD was investigated. A self-designed, laboratory-scale, and continuous anaerobic biogas digester was used for the evaluation. Results showed that the contents of the rice straw, i.e. the lignin, cellulose, and hemicellulose were degraded significantly after the NH3•H2O and H2O2 treatments, and that biogas production from all pretreated rice straw increased. In addition, the optimal treatments for biogas production were the 4% and 3% H2O2 treatments (w/w, which yielded 327.5 and 319.7 mL/gVS, biogas, respectively, higher than the untreated sample. Biogas production from H2O2 pretreated rice straw was more favorable than rice straw pretreated with same concentration of ammonia, ranking in the order of 4% ≈ 3% > 2% > 1%. The optimal amount of H2O2 treatment for rice straw biogas digestion is 3% when economics and biogas yields are considered.

  7. An integrated metagenome and -proteome analysis of the microbial community residing in a biogas production plant.

    Science.gov (United States)

    Ortseifen, Vera; Stolze, Yvonne; Maus, Irena; Sczyrba, Alexander; Bremges, Andreas; Albaum, Stefan P; Jaenicke, Sebastian; Fracowiak, Jochen; Pühler, Alfred; Schlüter, Andreas

    2016-08-10

    To study the metaproteome of a biogas-producing microbial community, fermentation samples were taken from an agricultural biogas plant for microbial cell and protein extraction and corresponding metagenome analyses. Based on metagenome sequence data, taxonomic community profiling was performed to elucidate the composition of bacterial and archaeal sub-communities. The community's cytosolic metaproteome was represented in a 2D-PAGE approach. Metaproteome databases for protein identification were compiled based on the assembled metagenome sequence dataset for the biogas plant analyzed and non-corresponding biogas metagenomes. Protein identification results revealed that the corresponding biogas protein database facilitated the highest identification rate followed by other biogas-specific databases, whereas common public databases yielded insufficient identification rates. Proteins of the biogas microbiome identified as highly abundant were assigned to the pathways involved in methanogenesis, transport and carbon metabolism. Moreover, the integrated metagenome/-proteome approach enabled the examination of genetic-context information for genes encoding identified proteins by studying neighboring genes on the corresponding contig. Exemplarily, this approach led to the identification of a Methanoculleus sp. contig encoding 16 methanogenesis-related gene products, three of which were also detected as abundant proteins within the community's metaproteome. Thus, metagenome contigs provide additional information on the genetic environment of identified abundant proteins.

  8. Extremum-seeking with variable gain control for intensifying biogas production in anaerobic fermentation.

    Science.gov (United States)

    Liu, J; Olsson, G; Mattiasson, B

    2006-01-01

    A state-dependent variable-gain control system is implemented to follow the characteristics of a laboratory-scale up-flow anaerobic fixed-bed reactor dynamically. The transition from one state to another is determined on an hourly basis, depending on difference between the setpoint of the reactor pH and its true value. Considerable improvement of the process stability--reduction of oscillation in both the reactor pH and biogas production rate during high-rate operation, has been achieved, although the control structure is simple and intuitive.

  9. Biogas production from brewery spent grain enhanced by bioaugmentation with hydrolytic anaerobic bacteria.

    Science.gov (United States)

    Čater, Maša; Fanedl, Lijana; Malovrh, Špela; Logar, Romana Marinšek

    2015-06-01

    Lignocellulosic substrates are widely available but not easily applied in biogas production due to their poor anaerobic degradation. The effect of bioaugmentation by anaerobic hydrolytic bacteria on biogas production was determined by the biochemical methane potential assay. Microbial biomass from full scale upflow anaerobic sludge blanket reactor treating brewery wastewater was a source of active microorganisms and brewery spent grain a model lignocellulosic substrate. Ruminococcus flavefaciens 007C, Pseudobutyrivibrio xylanivorans Mz5(T), Fibrobacter succinogenes S85 and Clostridium cellulovorans as pure and mixed cultures were used to enhance the lignocellulose degradation and elevate the biogas production. P. xylanivorans Mz5(T) was the most successful in elevating methane production (+17.8%), followed by the coculture of P. xylanivorans Mz5(T) and F. succinogenes S85 (+6.9%) and the coculture of C. cellulovorans and F. succinogenes S85 (+4.9%). Changes in microbial community structure were detected by fingerprinting techniques.

  10. Factors influencing the degradation of garbage in methanogenic bioreactors and impacts on biogas formation

    Energy Technology Data Exchange (ETDEWEB)

    Morita, Masahiko [Central Research Institute of Electric Power Industry, Chiba (Japan). Biotechnology Sector; Sasaki, Kengo [Tokyo Univ. (Japan). Dept. of Biotechnology

    2012-05-15

    Anaerobic digestion of garbage is attracting much attention because of its application in waste volume reduction and the recovery of biogas for use as an energy source. In this review, various factors influencing the degradation of garbage and the production of biogas are discussed. The surface hydrophobicity and porosity of supporting materials are important factors in retaining microorganisms such as aceticlastic methanogens and in attaining a higher degradation of garbage and a higher production of biogas. Ammonia concentration, changes in environmental parameters such as temperature and pH, and adaptation of microbial community to ammonia have been related to ammonia inhibition. The effects of drawing electrons from the methanogenic community and donating electrons into the methanogenic community on methane production have been shown in microbial fuel cells and bioelectrochemical reactors. The influences of trace elements, phase separation, and co-digestion are also summarized in this review. (orig.)

  11. Anaerobic digestion of cassava wastewater in fixed bed reactor using bamboo medium support; Digestao anaerobica de agua residuaria de fecularia em reator de leito fixo utilizando meio suporte de aneis de bambu

    Energy Technology Data Exchange (ETDEWEB)

    Watthier, Elisangela; Andreani, Cristiane L.; Silva, Jefferson L.G. [Universidade Estadual do Oeste do Parana (UNIOESTE), Cascavel, PR (Brazil)], E-mail: eliswa@hotmail.com; Gomes, Simone D. [Universidade Estadual do Oeste do Parana (UNIOESTE), Cascavel, PR (Brazil). Dept. de Recursos Hidricos e Saneamento Ambiental

    2012-11-01

    Cassava wastewater causes damage to the environment due to high organic loads and presence of cyanide and hydrocyanic acid. An alternative treatment anaerobic which add value for biogas production. To allow use of higher load sand reducing the TDH support means are used. This study aimed to evaluate the performance of the anaerobic treatment of liquid effluent of cassava industry, using bamboo as support media. The wastewater used was derived from starch factory located in Toledo. Was used PVC reactor with a diameter of 15 cm and length 90 cm. Were used as support means 52 bamboo rings and useful reactor volume 61. A total of 13 load increasing, from 1,675 to 15.158 g.L{sup -1}.d{sup -1}, until reaching the maximum load bearable. For each load data was collected for 15 days by daily samples at entrance and exit of the reactors. The samples were analyzed: DQO, alkalinity, volatile acidity and biogas production. There was a system instability in 12,394 g.L{sup -1}.d{sup -1}, with values of AV/AT above 0.5, but the system began to show signs of stability in the next load. The reactor showed biogas production up 1.57 L.L{sup -1}.d{sup -1}. (author)

  12. Innovative fusion reactor design analysis: Annual performance report, May 15, 1988--January 31, 1989

    Energy Technology Data Exchange (ETDEWEB)

    Klein, A.C.

    1989-01-31

    This report discusses the following topics on fusion reactor component design: FLiBe intermediate heat exchanger design analysis; FLiBe properties; design methodology; FLiBe system steam generator freezeup; FLiBe reactor systems studies; tritium breeding ratio control; analysis of original objectives; and budget analysis. 15 refs., 13 figs., 3 tabs. (LSP)

  13. Evolution of the construction and performances in accordance to the applications of non-thermal plasma reactors

    Science.gov (United States)

    Hnatiuc, B.; Brisset, J. L.; Astanei, D.; Ursache, M.; Mares, M.; Hnatiuc, E.; Felea, C.

    2016-12-01

    This paper aims to present the evolution of the construction and performances of non-thermal plasma reactors, identifying specific requirements for various known applications, setting out quality indicators that would allow on the one hand comparing devices that use different kinds of electrical discharges but also their rigorous classification by identification of criteria in order to choose the correct cold plasma reactors for a specific application. It briefly comments the post-discharge effect but also the current dilemma on non-thermal plasma direct treatments versus indirect treatments, using plasma activated water (PAW) or plasma activated medium (PAM), promising in cancer treatment.

  14. Effect of corrosion of steel elements on the treatment of dairy wastewater in a UASB reactor.

    Science.gov (United States)

    Jędrzejewska Cicińska, M; Krzemieniewski, M

    2010-05-01

    Experiments were performed in parallel using two laboratory upflow anaerobic sludge blanket (UASB) reactors. One of the two reactors was packed with spiral elements made of steel wire with 48% iron content in order to examine the influence of the steel elements on the chemical oxygen demand (COD) and efficiency of phosphorus removal from synthetically prepared dairy wastewater. A strong relationship was found between anaerobic corrosion and efficiency of phosphorus removal. Phosphorus removal in the reactor packed with steel elements was between 16.4% and 64.4% higher than without the steel elements present. The anaerobic corrosion process improved COD removal efficiency by 1.0-3.1%, which was statistically significant. When steel elements were present the methane content of the biogas was increased by 6.7%. Increasing the organic loading rate had a strong effect on the anaerobic efficiency of the dairy wastewater treatment.

  15. Experimental Evaluation of the Thermal Performance of a Water Shield for a Surface Power Reactor

    Science.gov (United States)

    Pearson, J. Boise; Stewart, Eric T.; Reid, Robert S.

    2007-01-01

    A water based shielding system is being investigated for use on initial lunar surface power systems. The use of water may lower overall cost (as compared to development cost for other materials) and simplify operations in the setup and handling. The thermal hydraulic performance of the shield is of significant interest. The mechanism for transferring heat through the shield is natural convection. Natural convection in a representative lunar surface reactor shield design is evaluated at various power levels in the Water Shield Testbed (WST) at the NASA Marshall Space Flight Center. The experimental data from the WST is used to anchor a CFD model. Performance of a water shield on the lunar surface is then predicted by CFD models anchored to test data. The accompanying viewgraph presentation includes the following topics: 1) Testbed Configuration; 2) Core Heater Placement and Instrumentation; 3) Thermocouple Placement; 4) Core Thermocouple Placement; 5) Outer Tank Thermocouple Placement; 6) Integrated Testbed; 7) Methodology; 8) Experimental Results: Core Temperatures; 9) Experimental Results; Outer Tank Temperatures; 10) CFD Modeling; 11) CFD Model: Anchored to Experimental Results (1-g); 12) CFD MOdel: Prediction for 1/6-g; and 13) CFD Model: Comparison of 1-g to 1/6-g.

  16. Performance improvement of artificial neural networks designed for safety key parameters prediction in nuclear research reactors

    Energy Technology Data Exchange (ETDEWEB)

    Mazrou, Hakim [Division de Physique Radiologique, Centre de Recherche Nucleaire d' Alger (CRNA), 02 Boulevard Frantz, Fanon, B.P. 399, 16000 Alger (Algeria)], E-mail: mazrou_h@crna.dz

    2009-10-15

    The present work explores, through a comprehensive sensitivity study, a new methodology to find a suitable artificial neural network architecture which improves its performances capabilities in predicting two significant parameters in safety assessment i.e. the multiplication factor k{sub eff} and the fuel powers peaks P{sub max} of the benchmark 10 MW IAEA LEU core research reactor. The performances under consideration were the improvement of network predictions during the validation process and the speed up of computational time during the training phase. To reach this objective, we took benefit from Neural Network MATLAB Toolbox to carry out a widespread sensitivity study. Consequently, the speed up of several popular algorithms has been assessed during the training process. The comprehensive neural system was subsequently trained on different transfer functions, number of hidden neurons, levels of error and size of generalization corpus. Thus, using a personal computer with data created from preceding work, the final results obtained for the treated benchmark were improved in both network generalization phase and much more in computational time during the training process in comparison to the results obtained previously.

  17. Evaluating the biogas potential of the dry fraction from pretreatment of food waste from households.

    Science.gov (United States)

    Murto, Marika; Björnsson, Lovisa; Rosqvist, Håkan; Bohn, Irene

    2013-05-01

    At the waste handling company NSR, Helsingborg, Sweden, the food waste fraction of source separated municipal solid waste is pretreated to obtain a liquid fraction, which is used for biogas production, and a dry fraction, which is at present incinerated. This pretreatment and separation is performed to remove impurities, however also some of the organic material is removed. The possibility of realising the methane potential of the dry fraction through batch-wise dry anaerobic digestion was investigated. The anaerobic digestion technique used was a two-stage process consisting of a static leach bed reactor and a methane reactor. Treatment of the dry fraction alone and in a mixture with structural material was tested to investigate the effect on the porosity of the leach bed. A tracer experiment was carried out to investigate the liquid flow through the leach beds, and this method proved useful in demonstrating a more homogenous flow through the leach bed when structural material was added. Addition of structural material to the dry fraction was needed to achieve a functional digestion process. A methane yield of 98 m3/ton was obtained from the dry fraction mixed with structural material after 76 days of digestion. This was in the same range as obtained in the laboratory scale biochemical methane potential test, showing that it was possible to extract the organic content in the dry fraction in this type of dry digestion system for the production of methane.

  18. Performance and kinetic process analysis of an Anammox reactor in view of application for landfill leachate treatment.

    Science.gov (United States)

    Gao, Junling; Chys, Michael; Audenaert, Wim; He, Yanling; Van Hulle, Stijn W H

    2014-01-01

    Anammox has shown its promise and low cost for removing nitrogen from high strength wastewater such as landfill leachate. A reactor was inoculated with nitrification-denitrification sludge originating from a landfill leachate treating waste water treatment plant. During the operation, the sludge gradually converted into red Anammox granular sludge with high and stable Anammox activity. At a maximal nitrogen loading rate of 0.6 g N l(-1) d(-1), the reactor presented ammonium and nitrite removal efficiencies of above 90%. In addition, a modified Stover-Kincannon model was applied to simulate and assess the performance of the Anammox reactor. The Stover-Kincannon model was appropriate for the description of the nitrogen removal in the reactor with the high regression coefficient values (R2 = 0.946) and low Theil's inequality coefficient (TIC) values (TIC < 0.3). The model results showed that the maximal N loading rate of the reactor should be 3.69 g N l(-1) d(-).

  19. Comparison of the performance of MBBR and SBR systems for the treatment of anaerobic reactor biowaste effluent.

    Science.gov (United States)

    Comett-Ambriz, I; Gonzalez-Martinez, S; Wilderer, P

    2003-01-01

    Anaerobic reactor biowaste effluent was treated with biofilm and activated sludge sequencing batch reactors to compare the performance of both systems. The treatment targets were organic carbon removal and nitrification. The pilot plant was operated in two phases. During the first phase, it was operated like a Moving Bed Biofilm Reactor (MBBR) with the Natrix media, with a specific surface area of 210 m2/m3. The MBBR was operated under Sequencing Batch Reactor (SBR) modality with three 8-hour cycles per day over 70 days. During the second phase of the experiment, the pilot plant was operated over 79 days as a SBR. In both phases the influent was fed to the reactor at a flow rate corresponding to a Hydraulic Retention Time (HRT) of 4 days. Both systems presented a good carbon removal for this specific wastewater. The Chemical Oxygen Demand (COD) total removal was 53% for MBBR and 55% for SBR. MBBR offered a higher dissolved COD removal (40%) than SBR (30%). The limited COD removal achieved is in agreement with the high COD to BOD5 ratio (1/3) of the influent wastewater. In both systems a complete nitrification was obtained. The different efficiencies in both systems are related to the different biomass concentrations.

  20. Prediction of moving bed biofilm reactor (MBBR) performance for the treatment of aniline using artificial neural networks (ANN).

    Science.gov (United States)

    Delnavaz, M; Ayati, B; Ganjidoust, H

    2010-07-15

    In this study, the results of 1-year efficiency forecasting using artificial neural networks (ANN) models of a moving bed biofilm reactor (MBBR) for a toxic and hard biodegradable aniline removal were investigated. The reactor was operated in an aerobic batch and continuous condition with 50% by volume which was filled with light expanded clay aggregate (LECA) as carrier. Efficiency evaluation of the reactors was obtained at different retention time (RT) of 8, 24, 48 and 72 h with an influent COD from 100 to 4000 mg/L. Exploratory data analysis was used to detect relationships between the data and dependent evaluated one. The appropriate architecture of the neural network models was determined using several steps of training and testing of the models. The ANN-based models were found to provide an efficient and a robust tool in predicting MBBR performance for treating aromatic amine compounds.

  1. Prediction of moving bed biofilm reactor (MBBR) performance for the treatment of aniline using artificial neural networks (ANN)

    Energy Technology Data Exchange (ETDEWEB)

    Delnavaz, M. [Tarbiat Modares University, Civil Engineering Department, Environmental Engineering Division, Tehran (Iran, Islamic Republic of); Ayati, B., E-mail: ayati_bi@modares.ac.ir [Tarbiat Modares University, Civil Engineering Department, Environmental Engineering Division, Tehran (Iran, Islamic Republic of); Ganjidoust, H. [Tarbiat Modares University, Civil Engineering Department, Environmental Engineering Division, Tehran (Iran, Islamic Republic of)

    2010-07-15

    In this study, the results of 1-year efficiency forecasting using artificial neural networks (ANN) models of a moving bed biofilm reactor (MBBR) for a toxic and hard biodegradable aniline removal were investigated. The reactor was operated in an aerobic batch and continuous condition with 50% by volume which was filled with light expanded clay aggregate (LECA) as carrier. Efficiency evaluation of the reactors was obtained at different retention time (RT) of 8, 24, 48 and 72 h with an influent COD from 100 to 4000 mg/L. Exploratory data analysis was used to detect relationships between the data and dependent evaluated one. The appropriate architecture of the neural network models was determined using several steps of training and testing of the models. The ANN-based models were found to provide an efficient and a robust tool in predicting MBBR performance for treating aromatic amine compounds.

  2. Biogas yield from Sicilian kitchen waste and cheese whey

    Directory of Open Access Journals (Sweden)

    Antonio Comparetti

    2013-09-01

    Full Text Available The aim of this study is to determine the chemical composition of kitchen waste and cheese whey, as well as the biogas yield obtained from the Anaerobic Digestion (AD tests of these two raw materials. Since the separated waste collection is performed in the town of Marineo (Palermo, a sample of kitchen waste, different from food industry one and included in the Organic Fraction of Municipal Solid Waste (OFMSW, was collected from the mass stored at the households of this town. Moreover, a sample of cheese whey was collected in a Sicilian mini dairy plant, where sheep milk is processed. This investigation was carried out inside laboratory digesters of Aleksandras Stulginskis University (Lithuania. Total Solids (TS resulted 15.6% in kitchen waste and 6% in cheese whey, while both the raw materials showed a high content of organic matter, 91.1% and 79.1%, respectively. The biogas yield resulted 104.6 l kg–1 from kitchen waste and 30.6 l kg–1 from cheese whey. The biogas yield from TS resulted 672.6 l kg–1 using kitchen waste and 384.7 l kg–1 using cheese whey. The biogas yield from Volatile Solids (VS resulted 738.9 l kg–1 using kitchen waste and 410.3 l kg–1 using cheese whey.

  3. Reactor performance of a 750 m(3) anaerobic digestion plant: varied substrate input conditions impacting methanogenic community.

    Science.gov (United States)

    Wagner, Andreas Otto; Malin, Cornelia; Lins, Philipp; Gstraunthaler, Gudrun; Illmer, Paul

    2014-10-01

    A 750 m(3) anaerobic digester was studied over a half year period including a shift from good reactor performance to a reduced one. Various abiotic parameters like volatile fatty acids (VFA) (formic-, acetic-, propionic-, (iso-)butyric-, (iso-)valeric-, lactic acid), total C, total N, NH4 -N, and total proteins, as well as the organic matter content and dry mass were determined. In addition several process parameters such as temperature, pH, retention time and input of substrate and the concentrations of CH4, H2, CO2 and H2S within the reactor were monitored continuously. The present study aimed at the investigation of the abundance of acetogens and total cell numbers and the microbial methanogenic community as derived from PCR-dHPLC analysis in order to put it into context with the determined abiotic parameters. An influence of substrate quantity on the efficiency of the anaerobic digestion process was found as well as a shift from a hydrogenotrophic in times of good reactor performance towards an acetoclastic dominated methanogenic community in times of reduced reactor performance. After the change in substrate conditions it took the methano-archaeal community about 5-6 weeks to be affected but then changes occurred quickly.

  4. CONVERSION OF ORGANIC MANURE INTO BIOGAS

    Directory of Open Access Journals (Sweden)

    Dario Brdarić

    2009-12-01

    Full Text Available Production of biogas with anaerobic degradation from organic waste is one of the pledge alternative energetic solutions, especially from organic manure made from animal farming and other residuals of agricultural production. According to 2005 livestock manufacture data daily quantity of animal excrements in Croatia, based on LSU number, is 784 015.26 m3. The aim of this paper is to determine the possibility of production of biogas from the most common types of domestic animals in Croatia. Anaerobic fermentation period of 40 days in mesophilic conditions produced from 1 kg of beef, 31 litres of biogas slurry and from pig slurry 14.83 litres of biogas. From our study it follows that the Republic of Croatia (based on the number of UG could produce 426,995,250.00 Nm3 biogas annually. Exploitation of biogas can decrease import of the referred energents, especially electric energy.

  5. Planning for Biogas Plant in Denmark

    DEFF Research Database (Denmark)

    Landt, Cristina C.; Gaarsmand, Regin; Palsberg, Aske

    2016-01-01

    This article is about establishing biogas in Denmark in the region of Zealand, the challenges that are related to this establishment and how to overcome this challenges. The article highlights three reasons for these challenges: 1) Regulation, 2) The municipal planning and 3) Involved various...... stakeholders. It investigates how these challenges affected the process and were overcome in the establishment of Solrod Biogas. In terms of ownership and biomass input, this biogas plant is unique compared to other Danish biogas plants. The biogas plant is based on organic by-products from local industries...... and seaweed. The plant solves an essential environmental issue for the municipality and citizens who were affected by the smell of rotten seaweed washed up in Koge Bay. The seaweed is used as input; this solves several problems at the same time. The method used to establish Solrod Biogas was an integrated...

  6. Small-scale household biogas digesters

    DEFF Research Database (Denmark)

    Bruun, Sander; Jensen, Lars Stoumann; Khanh Vu, Van Thi

    2014-01-01

    There are a number of advantages to small-scale biogas production on farms, including savings on firewood or fossil fuels and reductions in odour and greenhouse gas emissions. For these reasons, governments and development aid agencies have supported the installation of biogas digesters. However......, biogas digesters are often poorly managed and there is a lack of proper distribution systems for biogas. This results in methane being released inadvertently through leaks in digesters and tubing, and intentionally when production exceeds demand. As methane has a global warming potential 25 times greater......% of the produced biogas is released, depending on the type of fuel that has been replaced. The limited information available as regards methane leaking from small-scale biogas digesters in developing countries indicates that emissions may be as high as 40%. With the best estimates of global numbers of small...

  7. The economics of biogas in Denmark

    DEFF Research Database (Denmark)

    Jacobsen, Brian H.; Laugesen, Frederik Møller; Dubgaard, Alex

    2013-01-01

    Denmark has been one of the leading European Countries in using Biogas for Combined Heat and Power (CHP), since the 1980’ties. However, in the last two decades, the increase has been limited. A new energy policy aimed at increasing the profitability of Biogas was introduced in the spring of 2012....... The analysis here shows that the new agreement will improve the profitability of biogas plants and increase the biogas production although the political ambition of an increase from 4 PJ to 14 PJ by 2020 seems unlikely. The analysis shows that biogas plants can be profitable even if the input is a mix....... Even without an investment subsidy of 30%, the case 2012, is profitable. Financing the biogas plants is a challenge. The interest used of 4.25% requires bank guaranties which in practice can be hard to get. Using a more likely interest of 7-8% reduces the yearly profit to 400.000 €. The socioeconomic...

  8. [Progress on biogas technology and engineering].

    Science.gov (United States)

    Liu, Xiaofeng; Yuan, Yuexiang; Yan, Zhiying

    2010-07-01

    Dwindling supplies of conventional energy sources and the demand to increase the share of renewable energy for sustainability have increased the significance of biogas, the product of synergistic fermentation of biodegrable organic wastes from municipal, agricultural and industrial activities by microbial populations under anaerobic conditions. With extensive research and engineering practice, many technologies and modes have been developed for biogas production and application. Currently, the most widely used mode is the complete-mixing mesophilic fermentation. Europe, especially Germany, is leading the world in the combined heat and power production (CHP) from biogas. In this paper, updated progress in biogas technologies is reviewed, with focuses on anaerobic microorganisms, bioreactor configurations and process development, biogas production and applications, in which perspectives of biogas as a clean and renewable energy are projected.

  9. Biogas infrastructures from farm to regional scale, prospects of biogas transport grids

    NARCIS (Netherlands)

    Hengeveld, E.J.; Bekkering, J.; Gemert, W.J.T. van; Broekhuis, A.A.

    2016-01-01

    The volume of biogas produced in agricultural areas is expected to increase in coming years. An increasing number of local and regional initiatives show a growing interest in decentralized energy production, wherein biogas can play a role. Biogas transport from production sites to user, i.e. a CHP,

  10. Influence of DNA isolation method on the investigation of archaeal diversity and abundance in biogas plants.

    Science.gov (United States)

    Theiss, Juliane; Rother, Michael; Röske, Kerstin

    2016-09-01

    Various methods are available for DNA isolation from environmental samples. Because the chemical and biological composition of samples such as soil, sludge, or plant material is different, the effectiveness of DNA isolation can vary depending on the method applied and thus, have a substantial effect on the results of downstream analysis of the microbial community. Although the process of biogas formation is being intensely investigated, a systematic evaluation of kits for DNA isolation from material of biogas plants is still lacking. Since no DNA isolation kit specifically tailored for DNA isolation from sludge of biogas plants is available, this study compares five commercially available kits regarding their influence on downstream analyses such denaturing gradient gel electrophoresis (DGGE) and quantitative real-time PCR (qPCR). The results show that not all kits are equally suited for the DNA isolation from samples of different biogas plants, but highly reproducible DGGE fingerprints as well as qPCR results across the tested samples from biogas reactors using different substrate compositions could be produced using selected kits.

  11. Biogas in Romanian Agriculture, Present and Perspectives

    Directory of Open Access Journals (Sweden)

    Teodor Vintila

    2011-05-01

    Full Text Available In this work we have made a review of data available concerning the potential and technologies available to be applied in Romania to produce biogas in agricultural sector. Biogas application is especially interesting for medium and large farms, concentrated on specific surfaces, where a proper substrate collection can be organized. Reviewing data presenting the theoretical potential for livestock manure in Romania, we found that over 17 mil. MWh of energy from biogas can be provided in one year. It is estimated that only half of the theoretical energy potential is technically usable by biogas investments. As for the crops residues, has been shown that the theoretical biogas potential is 76,7 mil. MWh/year. However, there is a long way to be done in Romania to reach this potential, as in the present, the entire production of biogas is from industrial and municipal landfill and slurries - there are no operational on-farm biogas plants. Despite the high potential in terms of biogas production from agricultural sources, Romania has among the lowest biogas production in Europe. Although currently there are several biogas plants (not in agricultural sector totaling an installed capacity of only 4 MW, and producing in 2010 only 19 GWh electric power, the target for 2020 in Romania is 195 MWel. installed power, with an output of 950 GW electric power. The main cause of the actual situation is the lack of economic incentives similar to those offered by countries as Germany. Without a review of relevant legislation, the progress of the biogas sector in Romania will be limited. Furthermore, the development of low-cost technologies available to Romanian farmers will contribute to the development of production of renewable energy from biogas and other biofuels.

  12. ORGANIC WASTE USED IN AGRICULTURAL BIOGAS PLANTS

    Directory of Open Access Journals (Sweden)

    Joanna Kazimierowicz

    2014-04-01

    Full Text Available Treatment of organic waste is an ecological and economical problem. Searching method for disposal of these wastes, interest is methane fermentation. The use of this process in agricultural biogas plants allows disposal of hazardous waste, obtaining valuable fertilizer, while the production of ecologically clean fuel – biogas. The article presents the characteristics of organic waste from various industries, which make them suitable for use as substrates in agricultural biogas plants.

  13. ORGANIC WASTE USED IN AGRICULTURAL BIOGAS PLANTS

    OpenAIRE

    Joanna Kazimierowicz

    2014-01-01

    Treatment of organic waste is an ecological and economical problem. Searching method for disposal of these wastes, interest is methane fermentation. The use of this process in agricultural biogas plants allows disposal of hazardous waste, obtaining valuable fertilizer, while the production of ecologically clean fuel – biogas. The article presents the characteristics of organic waste from various industries, which make them suitable for use as substrates in agricultural biogas plants.

  14. Biogas potential atlas. Potential for the sustainable generation of biogas in Germany; Biogaspotenzialatlas. Potenzial zur nachhaltigen Erzeugung von Biogas in Deutschland

    Energy Technology Data Exchange (ETDEWEB)

    Erler, Ronny [DBI - Gastechnologisches Institut gGmbH, Freiberg (Germany); Krause, Hartmut

    2012-10-15

    Biogas can be produced from various agricultural, municipal or industrial accruing substrates. Different biogas potentials result depending on the substrate. As part of a research project, different potentials are recorded in a biogas potential atlas. This atlas can ultimately be helpful in selecting appropriate biogas plant locations.

  15. An innovative bioelectrochemical-anaerobic digestion-coupled system for in-situ ammonia recovery and biogas enhancement: process performance and microbial ecology

    DEFF Research Database (Denmark)

    Zhang, Yifeng; Angelidaki, Irini

    (SMRC) and a continuous stirred tank reactor (CSTR), to prevent ammonia toxicity during anaerobic digestion by in-situ ammonia recovery and electricity production. In batch experiment, the ammonia concentration in the CSTR decreased from 6 to 0.7 g-N/L with an average recovery rate of 0.18 g......-N/L(CSTR)/d. Meanwhile, a maximum power density of 0.71±0.5 W/m2 was produced (10 Ω). Both current driven NH4+ migration and free NH3 diffusion were identified as the mechanisms responsible for the ammonia transportation. With an increase in initial ammonia concentration and a decrease in external resistance, the SMRC...

  16. Effect of the organic loading rate on biogas composition in continuous fermentative hydrogen production.

    Science.gov (United States)

    Spagni, Alessandro; Casu, Stefania; Farina, Roberto

    2010-10-01

    Some systems did not select for hydrogen-producing microorganisms and an unexpected growth of hydrogenotrophic methanogens was observed, although the reactors were operated under well-defined operating conditions that could result in biohydrogen production. The aim of this study was to evaluate the effect of the organic loading rate (OLR) on the hydrogen and methane composition of the biogas produced in dark fermentative processes. The study was carried out using an upflow anaerobic sludge blanket (UASB) reactor in order to evaluate the OLR effect in systems with sludge retention. During continuous operation, the UASB reactor showed the slow development of methanogenic activity, related to the applied OLR. The results demonstrate that operating an UASB reactor at pH 5.5 is not enough to prevent the acclimation of methanogens to the acidic pH and therefore long-term biohydrogen production cannot be achieved. Moreover, this study demonstrates that OLR also has an effect on the biogas composition, where the higher the OLR the greater the biogas H2 content.

  17. Decentralized power generation from biogas; Production d'energie decentralisee a partir de biogaz

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2008-07-01

    Areva Bioenergies proposes ready-to-use biogas production and valorization units that use industrial effluents (liquid effluents, spent water, solid wastes). Biogas valorization is performed through cogeneration plants with an output power of 500 kW to 10 MW. This brochure presents Areva's global offer in methanation projects (support, engineering, optimization). Areva Bioenergies counts 20 dual-purpose power plants in operation or under construction in the world which represent an installed power of 220 MW.

  18. Gel-sphere-pac fuel for thermal reactors: assessment of fabrication technology and irradiation performance

    Energy Technology Data Exchange (ETDEWEB)

    Beatty, R.L. Norman, R.E.; Notz, K.J. (comps.)

    1979-11-01

    Recent interest in proliferation-resistant fuel cycles for light-water reactors has focused attention on spiked plutonium and /sup 233/U-Th fuels, requiring remote refabrication. The gel-sphere-pac process for fabricating metal-clad fuel elements has drawn special attention because it involves fewer steps. Gel-sphere-pac fabrication technology involves two major areas: the preparation of fuel spheres of high density and loading these spheres into rods in an efficiently packed geometry. Gel sphere preparation involves three major steps: preparation of a sol or of a special solution (broth), gelation of droplets of sol or broth to give semirigid spheres of controlled size, and drying and sintering these spheres to a high density. Gelation may be accomplished by water extraction (suitable only for sols) or ammonia gelation (suitable for both sols and broths but used almost exclusively with broths). Ammonia gelation can be accomplished either externally, via ammonia gas and ammonium hydroxide, or internally via an added ammonia generator such as hexamethylenetetramine. Sphere-pac fuel rod fabrication involves controlled blending and metering of three sizes of spheres into the rod and packing by low- to medium-energy vibration to achieve about 88% smear density; these sizes have diametral ratios of about 40:10:1 and are blended in size fraction amounts of about 60% coarse, 18% medium, and 22% fine. Irradiation test results indicate that sphere-pac fuel performs at least as well as pellet fuel, and may in fact offer an advantage in significantly reducing mechanical and chemical interaction between the fuel and cladding. The normal feed for gel sphere preparation, heavy metal nitrate solution, is the usual product of fuel reprocessing, so that fabrication of gel spheres performs all the functions performed by both conversion and pellet fabrication in the case of pellet technology.

  19. Viability of various weed seeds in anaerobic conditions (biogas plant)

    Energy Technology Data Exchange (ETDEWEB)

    Hansen, S.; Hansen, J.

    1983-04-01

    Seeds from different weeds, Urtica urens L. (nettle), Solanum nigrum L. (nightshade), Avena fatua L. (wild oat-grass), Brassica napus L. (rape), Chenopodium album L. (goose-foot), were put into small polyester net bags, which were placed in biogas reactors containing cattle manure. These ''biogas reactors'' were placed at different temperatures . Net bags were taken out after 4.5, 10.5, 21.5, 38 and 53 days, and the seeds were tested for their viability by germination tests and the tetrazolium method. Concerning all seeds it was manifested that the viability decreased very steeply at 35degC. Most of the seeds had a T/sub 50/ at 2-5 days; Chenopodium album L seeds had a T/sub 50/ at 16 days. After 4.5 days it was not possible to find living Avena fatua L seeds. The decrease in viability was less steep at 20degC and even less steep at 2degC.

  20. Neural Network Modeling and Prediction of Methane Fraction in Biogas from Landfill Bioreactors

    Directory of Open Access Journals (Sweden)

    A Ghavidel

    2009-09-01

    Full Text Available "n "nBackgrounds and Objectives:A number of different technologies have recently been studied todetermine the best use of biogas, however, to choose optimize technologies of using biogas for energy recovery it is necessary to monitor and predict the methane percentage of biogas. In this study, a method is proposed for predicting the methane fraction in landfill gas originating from Labscalelandfill bioreactors, based on neural network."nMaterials and Methods: In this study, two different systems were applied, to predict the methane fraction in landfill gas as a final product of anaerobic digestion, we used the leachate specifications as input parameters. In system I (C1, the leachate generated from a fresh-waste reactor was drained to recirculation tank, and recycled. In System II (C2, the leachate generated from a fresh waste landfill reactor was fed through a well-decomposed refuse landfill reactor, and at the same time, the leachate generated from a well-decomposed refuse landfill reactor recycled to a fresh waste landfill reactor."nResults: There is very good agreement in the trends between forecasted and measured data. R valuesare 0.999 and 0.997, and the obtained Root mean square error values are 1.098 and 2.387 for training and test data, respectively"nConclusion: The proposed method can significantly predict the methane fraction in landfill gasoriginating and, consequently, neural network can be use to optimize the dimensions of a plant using biogas for energy (i.e. heat and/or electricity recovery and monitoring system.

  1. Distributed power generation using biogas fuelled microturbines

    Energy Technology Data Exchange (ETDEWEB)

    Pointon, K.; Langan, M.

    2002-07-01

    This research sought to analyse the market for small scale biogas fuelled distributed power generation, to demonstrate the concept of a biogas fuelled microturbine using the Capstone microturbine in conjunction with an anaerobic digester, and undertake a technico-economic evaluation of the biogas fuelled microturbine concept. Details are given of the experimental trials using continuous and batch digesters, and feedstocks ranging from cow and pig slurries to vegetable wastes and municipal solid waste. The yields of methane are discussed along with the successful operation of the microturbine with biogas fuels, and anaerobic digestion projects.

  2. Effects of hexavalent chromium on performance and microbial community of an aerobic granular sequencing batch reactor.

    Science.gov (United States)

    Wang, Zichao; Gao, Mengchun; She, Zonglian; Jin, Chunji; Zhao, Yangguo; Yang, Shiying; Guo, Liang; Wang, Sen

    2015-03-01

    The performance and microbial community of an aerobic granular sequencing batch reactor (GSBR) were investigated at different hexavalent chromium (Cr(VI)) concentrations. The COD and NH4 (+)-N removal efficiencies decreased with the increase in Cr(VI) concentration from 0 to 30 mg/L. The specific oxygen utilization rate (SOUR) decreased from 34.86 to 12.18 mg/(g mixed liquor suspended sludge (MLSS)·h) with the increase in Cr(VI) concentration from 0 to 30 mg/L. The specific ammonium oxidation rate (SAOR), specific nitrite oxidation rate (SNOR), and specific nitrate reduction rate (SNRR) decreased with the increase in Cr(VI) concentration, whereas the SNRR was always higher than the sum of SAOR and SNOR at 0-30 mg/L Cr(VI). The scanning electron micrographs (SEM) showed some undefined particles on the surface of filamentous bacteria that might be the chelation of chromium and macromolecular organics at 30 mg/L Cr(VI). The denaturing gradient gel electrophoresis (DGGE) profiles revealed that some microorganisms adapting to high Cr(VI) concentration gradually became the predominant bacteria, while others without Cr(VI)-tolerance capacity tended to deplete or weaken. Some bacteria could tolerate the toxicity of high Cr(VI) concentration in the aerobic GSBR, such as Propionibacteriaceae bacterium, Ochrobactrum anthropi, and Micropruina glycogenica.

  3. MODELING OF MIXED LIQUOR VOLATILE SUSPENDED SOLIDS AND PERFORMANCE EVALUATION FOR A SEQUENCING BATCH REACTOR

    Directory of Open Access Journals (Sweden)

    S.A. Mirbagheri

    2015-01-01

    Full Text Available This study examined carbon, nitrogen and phosphorous removal from municipal wastewater in a sequencing batch reactor and biokinetic coefficients were evaluated according to results of BOD and COD. Furthermore, the MLVSS in the aeration reactor was modeled by using multilayer perceptron and radial basis function artificial neural networks (MLPANN and RBFANN. The experiments were performed so that the cell retention time, filling time and intensity of aeration were (5, 10 and 15 d, (1, 2 and 3 h and (weak, medium and strong respectively. The result indicated that with cell retention time of 15 d, filling time of 1 h, aeration time of 6 h and settling time of 3 h the HRT is optimized at 10 h. The BOD5, COD, TP, TN and NH4  N removal efficiencies were 97.13%, 94.58%, 94.27%, 89.7% and 92.75% respectively. The yield coefficient (Y, decay coefficient (Kd, maximum specific growth rate (K and saturation constant (Ks were 6.22 mgVSS/mgCOD, 0.002 1/d, 0.029 1/d and 20 mg COD/L according to COD experimental data. The values of the biokinetic coefficients were found to be as follows: Y = 10.45 mgVSS/mgBOD, Kd = 0.01 1/d, 0.014 1/d and 3.38 mgBOD/L according to BOD5 experimental data. The training procedures for simulation of MLVSS were highly collaborated for both RBFANN and MLPANN. The train and test models for both MLPANN and RBFANN demonstrated perfectly matched results between the experimental and the simulated values of MLVSS. The values of RMSE for train and test (verification models obtained by MLPANN were 31.82 and 40.25 mg/L respectively, and the value of R2 was 0.99 for both models. The values of RMSE for train and test models obtained by RBFANN were 69.04 and 43.87 mg/L respectively, and the value of R2 was 0.99 for both models. It was observed that the MLPANN has stronger approximation and generalization ability than the RBFANN with regard to our experimental data for MLVSS.

  4. Biogas upgrading - Review of commercial technologies; Biogasuppgradering - Granskning av kommersiella tekniker

    Energy Technology Data Exchange (ETDEWEB)

    Bauer, Fredric; Hulteberg, Christian; Persson, Tobias; Tamm, Daniel

    2013-04-01

    Biogas production is growing and there is an increasing demand for upgraded biogas, to be used as vehicle fuel or injected to the natural gas grid. To enable the efficient use of biogas in these applications the gas must be upgraded, i.e. the carbon dioxide, which constitutes a large part of the raw biogas from the digester, must be separated from the methane. This report aims to evaluate the biogas upgrading technologies that are commercially available and in operation today: amine scrubbers, water scrubbers, PSA units, organic scrubbers and membrane units. The technologies are described in detail by presenting the theory behind the separation mechanism, the upgrading process as a complete system, operational issues and how these are solved, and finally the most important financial data. Furthermore, the best developed cryogenic technologies, which today are being used to purify landfill gas and biogas from some specific components and to liquefy biogas, are presented. Cryogenic upgrading is an interesting possibility, but as this report shows, the technology still has some important operational issues to resolve. Technologies which are especially focused on small-scale applications are finally presented, however not in as much detail as the other, more common technologies. The report shows that for mid-scale applications, the most common options are all viable. The scrubbing technologies all perform well and have similar costs of investment and operation. The simplicity and reliability of the water scrubber has made this the preferred choice in many applications, but the high purity and very low methane slip from amine scrubbers are important characteristics. Regarding PSA and membrane units, the investment cost for these are about the same as for scrubbers. Furthermore, recent developments of the membrane units have also made it possible to reach low methane slips with this technology. Biogas production is increasing, in Sweden and globally, and the interest for

  5. Study of impact of the AP1000{sup Registered-Sign} reactor vessel upper internals design on fuel performance

    Energy Technology Data Exchange (ETDEWEB)

    Xu Yiban; Conner, Michael; Yuan Kun; Dzodzo, Milorad B.; Karoutas, Zeses; Beltz, Steven A.; Ray, Sumit; Bissett, Teresa A. [Westinghouse Electric Company, Cranberry Township, PA 16066 (United States); Chieng, Ching-Chang, E-mail: cchieng@ess.nthu.edu.tw [National Tsing Hua University, Hsinchu 30043, Taiwan (China); Kao, Min-Tsung; Wu, Chung-Yun [National Tsing Hua University, Hsinchu 30043, Taiwan (China)

    2012-11-15

    One aspect of the AP1000{sup Registered-Sign} reactor design is the reduction in the number of major components and simplification in manufacturing. One design change relative to current Westinghouse reactors of similar size is the reduction in the number of reactor vessel outlet nozzles/hot legs leaving the upper plenum from three to two. With regard to fuel performance, this design difference creates a different flow field in the AP1000 reactor vessel upper plenum (the region above the core). The flow exiting core and entering the upper plenum must turn 90 Degree-Sign , flow laterally through the upper plenum around support structures, and exit through one of the two outlet nozzles. While the flow in the top of the core is mostly axial, there is some lateral flow component as the core flow reacts to the flow field and pressure distribution in the upper plenum. The pressure distribution in the upper plenum varies laterally depending upon various factors including the proximity to the outlet nozzles. To determine how the lateral flow in the top of the AP1000 core compares to current Westinghouse reactors, a computational fluid dynamics (CFD) model of the flow in the upper portion of the AP1000 reactor vessel including the top region of the core, the upper plenum, the reactor vessel outlet nozzles, and a portion of the hot legs was created. Due to geometric symmetry, the computational domain was reduced to a quarter (from the top view) that includes Vulgar-Fraction-One-Quarter of the top of the core, Vulgar-Fraction-One-Quarter of the upper plenum, and Vulgar-Fraction-One-Half of an outlet nozzle. Results from this model include predicted velocity fields and pressure distributions throughout the model domain. The flow patterns inside and around guide tubes clearly demonstrate the influence of lateral flow due to the presence of the outlet nozzles. From these results, comparisons of AP1000 flow versus current Westinghouse plants were performed. Field performance

  6. Use of a Ceramic Membrane to Improve the Performance of Two-Separate-Phase Biocatalytic Membrane Reactor.

    Science.gov (United States)

    Ranieri, Giuseppe; Mazzei, Rosalinda; Wu, Zhentao; Li, Kang; Giorno, Lidietta

    2016-03-14

    Biocatalytic membrane reactors (BMR) combining reaction and separation within the same unit have many advantages over conventional reactor designs. Ceramic membranes are an attractive alternative to polymeric membranes in membrane biotechnology due to their high chemical, thermal and mechanical resistance. Another important use is their potential application in a biphasic membrane system, where support solvent resistance is highly needed. In this work, the preparation of asymmetric ceramic hollow fibre membranes and their use in a two-separate-phase biocatalytic membrane reactor will be described. The asymmetric ceramic hollow fibre membranes were prepared using a combined phase inversion and sintering technique. The prepared fibres were then used as support for lipase covalent immobilization in order to develop a two-separate-phase biocatalytic membrane reactor. A functionalization method was proposed in order to increase the density of the reactive hydroxyl groups on the surface of ceramic membranes, which were then amino-activated and treated with a crosslinker. The performance and the stability of the immobilized lipase were investigated as a function of the amount of the immobilized biocatalytst. Results showed that it is possible to immobilize lipase on a ceramic membrane without altering its catalytic performance (initial residual specific activity 93%), which remains constant after 6 reaction cycles.

  7. Use of a Ceramic Membrane to Improve the Performance of Two-Separate-Phase Biocatalytic Membrane Reactor

    Directory of Open Access Journals (Sweden)

    Giuseppe Ranieri

    2016-03-01

    Full Text Available Biocatalytic membrane reactors (BMR combining reaction and separation within the same unit have many advantages over conventional reactor designs. Ceramic membranes are an attractive alternative to polymeric membranes in membrane biotechnology due to their high chemical, thermal and mechanical resistance. Another important use is their potential application in a biphasic membrane system, where support solvent resistance is highly needed. In this work, the preparation of asymmetric ceramic hollow fibre membranes and their use in a two-separate-phase biocatalytic membrane reactor will be described. The asymmetric ceramic hollow fibre membranes were prepared using a combined phase inversion and sintering technique. The prepared fibres were then used as support for lipase covalent immobilization in order to develop a two-separate-phase biocatalytic membrane reactor. A functionalization method was proposed in order to increase the density of the reactive hydroxyl groups on the surface of ceramic membranes, which were then amino-activated and treated with a crosslinker. The performance and the stability of the immobilized lipase were investigated as a function of the amount of the immobilized biocatalytst. Results showed that it is possible to immobilize lipase on a ceramic membrane without altering its catalytic performance (initial residual specific activity 93%, which remains constant after 6 reaction cycles.

  8. Quantitative calculation of reaction performance in sonochemical reactor by bubble dynamics

    Science.gov (United States)

    Xu, Zheng; Yasuda, Keiji; Liu, Xiao-Jun

    2015-10-01

    In order to design a sonochemical reactor with high reaction efficiency, it is important to clarify the size and intensity of the sonochemical reaction field. In this study, the reaction field in a sonochemical reactor is estimated from the distribution of pressure above the threshold for cavitation. The quantitation of hydroxide radical in a sonochemical reactor is obtained from the calculation of bubble dynamics and reaction equations. The distribution of the reaction field of the numerical simulation is consistent with that of the sonochemical luminescence. The sound absorption coefficient of liquid in the sonochemical reactor is much larger than that attributed to classical contributions which are heat conduction and shear viscosity. Under the dual irradiation, the reaction field becomes extensive and intensive because the acoustic pressure amplitude is intensified by the interference of two ultrasonic waves. Project supported by the National Natural Science Foundation of China (Grant Nos. 11404245, 11204129, and 11211140039).

  9. Quantitative calculation of reaction performance in sonochemical reactor by bubble dynamics

    Institute of Scientific and Technical Information of China (English)

    徐峥; 安田启司; 刘晓峻

    2015-01-01

    In order to design a sonochemical reactor with high reaction efficiency, it is important to clarify the size and intensity of the sonochemical reaction field. In this study, the reaction field in a sonochemical reactor is estimated from the distribution of pressure above the threshold for cavitation. The quantitation of hydroxide radical in a sonochemical reactor is obtained from the calculation of bubble dynamics and reaction equations. The distribution of the reaction field of the numerical simulation is consistent with that of the sonochemical luminescence. The sound absorption coefficient of liquid in the sonochemical reactor is much larger than that attributed to classical contributions which are heat conduction and shear viscosity. Under the dual irradiation, the reaction field becomes extensive and intensive because the acoustic pressure amplitude is intensified by the interference of two ultrasonic waves.

  10. Nuclear Reactors

    Energy Technology Data Exchange (ETDEWEB)

    Hogerton, John

    1964-01-01

    This pamphlet describes how reactors work; discusses reactor design; describes research, teaching, and materials testing reactors; production reactors; reactors for electric power generation; reactors for supply heat; reactors for propulsion; reactors for space; reactor safety; and reactors of tomorrow. The appendix discusses characteristics of U.S. civilian power reactor concepts and lists some of the U.S. reactor power projects, with location, type, capacity, owner, and startup date.

  11. Response of aerobic granular sludge to the long-term presence to nanosilver in sequencing batch reactors: reactor performance, sludge property, microbial activity and community.

    Science.gov (United States)

    Quan, Xiangchun; Cen, Yan; Lu, Fang; Gu, Lingyun; Ma, Jingyun

    2015-02-15

    The increasing use of silver nanoparticles (Ag NPs) raises concerns about their potential toxic effects on the environment. Granular shape sludge is a special type of microbial aggregate. The response of aerobic granular sludge (AGS) to the long-term presence of Ag NPs has not been well studied. In this study, AGS was exposed to 5 and 50mg/L Ag NPs in sequence batch reactors (SBRs) for 69 days, and its response was evaluated based on the sludge properties, microbial activity and community, and reactor performance. The results showed that Ag NPs caused inhibition to microbial activities of AGS from Day 35. At the end of 69 days of Ag NPs exposure, the microbial activity of AGS was significantly inhibited in terms of inhibitions of the ammonia oxidizing rate (33.0%), respiration rate (17.7% and 45.6%) and denitrification rate (6.8%), as well as decreases in the ammonia mono-oxygenase and nitrate reductase activities. During the long-term exposure, the AGS maintained its granular shape and large granule size (approximately 900 μm); the microbial community of AGS slightly changed, but the dominant microbial population remained. Overall, the AGS tolerated the toxicity of Ag NPs well, but a long-term exposure may produce chronic toxicity to the AGS, which is concerning.

  12. PREMOR: a point reactor exposure model computer code for survey analysis of power plant performance

    Energy Technology Data Exchange (ETDEWEB)

    Vondy, D.R.

    1979-10-01

    The PREMOR computer code was written to exploit a simple, two-group point nuclear reactor power plant model for survey analysis. Up to thirteen actinides, fourteen fission products, and one lumped absorber nuclide density are followed over a reactor history. Successive feed batches are accounted for with provision for from one to twenty batches resident. The effect of exposure of each of the batches to the same neutron flux is determined.

  13. Production of bio-gas from maize cobs

    Directory of Open Access Journals (Sweden)

    Luter Leke, Anne Ada Ogbanje, Dekaa Henry Terfa, Tyoalumun Ikyaagba

    2013-01-01

    Full Text Available Anaerobic digestion of energy crop residues and wastes is of increasing interest in order to reduce greenhouse gas emissions and to facilitate a sustainable development of energy supply. Production of biogas provides a versatile carrier of renewable energy, as methane can be used for replacement of fossil fuels in both heat and power generation as vehicle fuel. Biogas fuel production from blends of biological wastes such as Cow rumen liquor (CL, Poultry droppings (PD, and Goat Faeces (GF with Maize cobs (M were studied. 20 g of each inoculum was mixed with 100g of degraded maize cobs in the first three digesters while the fourth contained CL 10g, PD 10 g, and M 100 g. 100 g of M alone in the fifth digester served as the control. The blends were subjected to anaerobic digestion for 10 days on the prevailing atmospheric ambient temperature and pressure conditions. Physiochemical properties of the blends such as moisture content, crude protein, ash, fat, crude fibre, carbohydrate content, C/N ratio, and pH were also determined. Results of the daily performances of each system showed that maize cobs (M alone had cumulative biogas yield of 1.50 cm3 while those of the blends (MCL, MPD, MGF and MCLPD were 6.11 cm3, 3.05 cm3, 2.50 cm3, and 63.00 cm3 respectively, pH and C/N ratio affected the biogas yield of the systems significantly. These results indicate that the low biogas production from maize cobs can be enhanced significantly by blending with cow rumen liquor and poultry droppings.

  14. Production of bio-gas from maize cobs

    Energy Technology Data Exchange (ETDEWEB)

    Leke, Luter [College of Physical Sciences, University of Aberdeen, AB24 3UE, Aberdeen (United Kingdom); Department of Chemistry, Benue State University, P M B 102119, Makurdi (Nigeria); Ogbanje, Anne Ada [Department of Chemistry, Benue State University, P M B 102119, Makurdi (Nigeria); Department of Renewable Energy, Energy Commission of Nigeria, Garki-Abuja (Nigeria); Terfa, Dekaa Henry [Department of Chemistry, Benue State University, P M B