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Sample records for biodiesel percentage miscele

  1. Bio diesel blends stability. Analytical aspects and test methods; Stabilita' delle miscele gasolio-biodiesel. Aspetti analitici e metodi di prova

    Energy Technology Data Exchange (ETDEWEB)

    Pinelli, G. [Stazione Sperimentale per i Combustibili, San Donato Milanese, Milan (Italy)

    2001-08-01

    Bio diesel blends are receiving increasing attention as an alternative to conventional petroleum fuel for Diesel engines. This interest is based on several valuable properties of bio diesel, which, besides the production from renewable sources and its sufficient compatibility with Diesel engines, could reduce exhaust emissions. From technical point of view the main disadvantage of bio diesel is fuel un stability. As a matter of fact, bio diesel is more subject to oxidative degradation than petroleum diesel oil and this can alter the stability of bio diesel blends. In this connection the greatest controversy stability regards test methods for bio diesel blends. This review presents a synthesis of the studies performed in recent years on bio diesel blends stability. Besides considering the analytical aspects involving both products, the most important test methods for stability of bio diesel blends are discussed. [Italian] Le miscele gasolio-biodiesel stanno riscuotendo una crescente attenzione come alternative ai tradizionali comustibili diesel. Questo interesse e' dovuto ad alcune pregevoli proprieta' del biodiesel, il quale, oltre a essere prodotto da fonti rinnovabili, presenta una soddisfacente compatibilita' con i motori Diesel e potrebbe contribuire a ridurre le emissioni inquinanti. Da un punto di vista tecnico il suo grande svantaggio e' la instabilita'. Il biodiesel, infatti, e' piu' soggetto alla degradazione ossidativa rispetto al gasolio e questo puo' alterare la stabilita' delle miscele tra i due prodotti. A tal proposito l'aspetto piu' controverso riguarda i metodi di prova per la valutazione della stabilita' delle miscele gasolio-biodiesel. In questa rassegna viene presentata una sintesi degli studi condotti negli ultimi anni sulla stabilita' delle miscele gasolio-biodiesel. Oltre a considerare gli aspetti analitici riguardanti i due prodotti, vengono discussi i principali metodi di

  2. 10 CFR 490.706 - Procedure for modifying the biodiesel component percentage.

    Science.gov (United States)

    2010-01-01

    ... 10 Energy 3 2010-01-01 2010-01-01 false Procedure for modifying the biodiesel component percentage... TRANSPORTATION PROGRAM Biodiesel Fuel Use Credit § 490.706 Procedure for modifying the biodiesel component percentage. (a) DOE may, by rule, lower the 20 percent biodiesel volume requirement of this subpart...

  3. Metodologia analítica para quantificar o teor de biodiesel na mistura biodiesel: diesel utilizando espectroscopia na região do infravermelho Determination of biodiesel percentage in biodiesel: diesel mixtures using mid-infrared spectroscopy

    Directory of Open Access Journals (Sweden)

    Lílian Lefol Nani Guarieiro

    2008-01-01

    Full Text Available Considered the best substitute for diesel, biodiesel can be blended with diesel in any ratio, bringing lots of environmental, economic and social advantages. Brazilian law Nº 11097/2005, proposes the introduction of biodiesel in to the Brazilian energy matrix, mixed with diesel at a minimum percentage of 2%. For consumers and sellers to be sure that the commercialized mixture of biodiesel:diesel contains the correct percentage, it is necessary to develop analytical methodologies to quantify the amount of biodiesel added. This work presents a fast, low-cost and simple methodology to determine the biodiesel proportion in mixtures of biodiesel:diesel, based on infrared spectroscopy.

  4. Ahmar, otro hijo de Iblis (el diablo) en el Miscel??neo de Salom??n

    OpenAIRE

    1997-01-01

    Ahmar Ibn Iblis aparece con sus cinco hermanos en el Hadit de Salom??n, relato recogido en el libro manuscrito Miscel??neo de Salom??n. Ahmar es un ser infernal que da??a a `los hijos de Ad??n' produci??ndoles enfermedades mentales. Salom??n le obliga con amenazas a que le cuente la sintomatolog??a de la enfermedad y su remedio. Ahmar obedece y cuenta todo.

  5. Biodiesel Basics

    Energy Technology Data Exchange (ETDEWEB)

    Putzig, Mollie [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-10-04

    This fact sheet (updated for 2017) provides a brief introduction to biodiesel, including a discussion of biodiesel blends, which blends are best for which vehicles, where to buy biodiesel, how biodiesel compares to diesel fuel in terms of performance, the difference between biodiesel and renewable diesel, how biodiesel performs in cold weather, whether biodiesel use will plug vehicle filters, how long-term biodiesel use may affect engines, biodiesel fuel standards, and whether biodiesel burns cleaner than diesel fuel. The fact sheet also dismisses the use of vegetable oil as a motor fuel.

  6. La revista Miscel·lània Zoològica: apunts per a la seva història

    Directory of Open Access Journals (Sweden)

    Uribe, F.

    2003-01-01

    Full Text Available Miscel·lània Zoològica: some remarks for the history of this journal In a little over four decades the journal Miscel·lània Zoològica published some 900 papers. A simple review of the contents of these articles reveals several characteristics: the issues most commonly dealt with were faunistics and taxonomy, with insects making up the most frequently analyzed group. The geographical range was centred on the Iberian peninsula, mainly Catalonia. The intellectual heritage of Miscel·lània Zoològica has been continued since 2001 by the journal Animal Biodiversity and Conservation and by Arxius de Miscel·lània Zoològica as of this current volume. It is now time to start writing the history of Miscel·lània Zoològica.

  7. Biodiesel Basics

    Energy Technology Data Exchange (ETDEWEB)

    None

    2014-07-01

    This fact sheet provides a brief introduction to biodiesel, including a discussion of biodiesel blends and specifications. It also covers how biodiesel compares to diesel fuel in terms of performance (including in cold weather) and whether there are adverse effects on engines or other systems. Finally, it discusses biodiesel fuel quality and standards, and compares biodiesel emissions to those of diesel fuel.

  8. El fútbol español como paradigma. Una miscelánea

    OpenAIRE

    Leguina, Joaquín

    2006-01-01

    Esta miscelánea aborda el fenómeno futbolístico en España, primero desde la óptica del espectáculo: ¿por qué este juego de pelota atrae a las masas?, ¿qué papel juegan los árbitros en la emoción del juego? son algunas de las preguntas que el autor pretende elucidar. A continuación, el autor aborda la relación entre los clubes de fútbol con sus connotaciones ideológicas y políticas y el consiguiente juego identitario de equipos como el Club de Fútbol Barcelona y el Atlethi...

  9. Uso da cromatografia gasosa bidimensional abrangente (GC×GC na caracterização de misturas biodiesel/diesel: aplicação ao biodiesel de sebo bovino

    Directory of Open Access Journals (Sweden)

    Maria Silvana A Moraes

    2011-01-01

    Full Text Available The growth of biodiesel market and the implementation of regulations related to biodiesel production and biodiesel/diesel blending has encouraged the development of appropriate analytical methods to control the composition of this type of mixture. In this study, an evaluation of the potential of GC×GC for the characterization of samples of beef tallow biodiesel and the composition of blends of biodiesel/diesel is presented. The methodology was applied to beef tallow biodiesel and its mixtures with petrodiesel, ranging from B2 to B50. Results allowed not only the identification and quantification of the biodiesel esters, but also the biodiesel percentage in biodiesel/diesel blends.

  10. Varietas Indiana: le cas de la Miscelánea Antártica de Miguel Cabello Valboa

    Directory of Open Access Journals (Sweden)

    2001-01-01

    Full Text Available La notion de varietas est reprise par la culture de l’Humanisme et érigée en principe générateur de formes de pensée et d’écriture. Compte tenu de ceci, il y a lieu de se demander quel fut son rôle dans l’appréhension intellectuelle du Nouveau Monde et dans les divers discours sur celui-ci, aussi bien ceux qui furent élaborés depuis l’Europe que ceux qui le furent depuis les Indes Occidentales. Il s'agit ici de réfléchir sur un cas particulier, celui de la fonction de la varietas dans la Miscelánea Antártica de Miguel Cabello Valboa, pour essayer de démontrer comment l’auteur se sert doublement de ce principe pour insérer le lecteur, aussi bien local que peninsulaire, au sein de la matière américaine et, en même temps, assimiler celle-ci au fonds commun du savoir, rattachant l’histoire indigène à l’Histoire universelle. VARIETAS INDIANA: EL CASO DE LA MISCELÁNEA ANTÁRTICA DE MIGUEL CABELLO VALBOA La noción de varietas se erige como principio generador de formas de pensamiento y de escritura y, en un sentido general, como eje de la cultura del Humanismo. Teniendo en cuenta lo anterior, cabe preguntarse sobre la función que ésta cumplió en la aprensión intelectual de los territorios ultamarinos dentro del imaginario europeo y en la formación de un imaginario local. En el presente artículo hemos examinado esta cuestión en un caso particular, el de la Miscelánea Antártica de Miguel Cabello Valboa, intentando mostrar cómo el autor se sirve doblemente del principio de la varietas para insertar al lector, tanto local como peninsular, en el ámbito de la materia americana y de la historia indígena, pero sobre todo para asimilarlas al fondo común del saber y engarzarlas, en un plano de igualdad, dentro de la historia universal. VARIETAS INDIANA: THE CASE OF MISCELÁNEA ANTÁRTICA DE MIGUEL CABELLO VALBOA The age of Humanism revived the notion of varietas and established it as a generating force of thought and

  11. Biodiesel fuels

    Science.gov (United States)

    The mono-alkyl esters, most commonly the methyl esters, of vegetable oils, animal fats or other materials consisting mainly of triacylglycerols, often referred to as biodiesel, are an alternative to conventional petrodiesel for use in compression-ignition engines. The fatty acid esters that thus com...

  12. WSF Biodiesel Demonstration Project Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Washington State University; University of Idaho; The Glosten Associates, Inc.; Imperium Renewables, Inc.

    2009-04-30

    In 2004, WSF canceled a biodiesel fuel test because of “product quality issues” that caused the fuel purifiers to clog. The cancelation of this test and the poor results negatively impacted the use of biodiesel in marine application in the Pacific Northwest. In 2006, The U.S. Department of Energy awarded the Puget Sound Clean Air Agency a grant to manage a scientific study investigating appropriate fuel specifications for biodiesel, fuel handling procedures and to conduct a fuel test using biodiesel fuels in WSF operations. The Agency put together a project team comprised of experts in fields of biodiesel research and analysis, biodiesel production, marine engineering and WSF personnel. The team reviewed biodiesel technical papers, reviewed the 2004 fuel test results, designed a fuel test plan and provided technical assistance during the test. The research reviewed the available information on the 2004 fuel test and conducted mock laboratory experiments, but was not able to determine why the fuel filters clogged. The team then conducted a literature review and designed a fuel test plan. The team implemented a controlled introduction of biodiesel fuels to the test vessels while monitoring the environmental conditions on the vessels and checking fuel quality throughout the fuel distribution system. The fuel test was conducted on the same three vessels that participated in the canceled 2004 test using the same ferry routes. Each vessel used biodiesel produced from a different feedstock (i.e. soy, canola and yellow grease). The vessels all ran on ultra low sulfur diesel blended with biodiesel. The percentage of biodiesel was incrementally raised form from 5 to 20 percent. Once the vessels reached the 20 percent level, they continued at this blend ratio for the remainder of the test. Fuel samples were taken from the fuel manufacturer, during fueling operations and at several points onboard each vessel. WSF Engineers monitored the performance of the fuel systems and

  13. Application of thermal lens technique to measure the thermal diffusivity of biodiesel blend

    Science.gov (United States)

    Sadrolhosseini, Amir Reza; Noor, A. S. M.; Mehdipour, Lotf Ali; Noura, Amin; Mahdi, Mohd Adzir

    2015-04-01

    Thermal diffusivity of palm biodiesel blends was measured using a thermal lens double beam setup. Palm biodiesel blends were prepared from a mixture of normal palm oil biodiesel and diesel fuel with the percentage of the mixture set in the range of 10-90 %. The thermal diffusivity of the palm biodiesel blends consistently increased by increasing the concentration of palm biodiesel from 0.784 × 10-7 to 1.056 × 10-7 m2/s and average of measurement limitation was 0.629 × 10-7 m2/s. Hence, thermal lens technique is suitable and accurate to assess the thermal diffusivity of palm biodiesel.

  14. The Influence of Non-Esterification Biodiesel in AN Indirect Injection Diesel Engine

    Science.gov (United States)

    Choi, Seung-Hun; Oh, Young-Taig

    Biodiesel as alternative energy source of the traditional petroleum fuels has increased interest, because environmental pollution based exhaust emissions from vehicle became serious. The advantage of biodiesel produced from esterification of vegetable and animal oils can be used without the modification of existing diesel engine, but glycerin is generated by production process. In this study, the usability of non-esterification biodiesel as an alternative fuel was investigated in an indirect injection diesel engine. The non-esterification biodiesel has not generated glycerin in esterification process and reduced the 20 percent of cost because it has not used methanol in the production process. Experiments were conducted by using the 5, 10 and 20 percentage of biodiesel and 4 and 8 percentage of biodiesel with 1 and 2 percentage of WDP in baseline diesel fuel. The smoke emission of biodiesel was reduced in comparison with diesel fuel, but power, torque and brake specific energy consumption was similar to diesel fuel.

  15. Miscelánea

    OpenAIRE

    Luque, C.

    2012-01-01

    1. Contra la tecnocracia En el prólogo de su libro " Cours d' Algèbre  (Hermann) el profesor Roger Godement trae varios comentarios muy interesantes aunque no todos ellos referentes exactamente al algebra abstracta. Presentamos enseguida, en traducción del profesor Manuel Vinent un trozo de dicho prólogo que juzgamos de especial actualidad.

  16. Biodiesel and its properties

    Science.gov (United States)

    Biodiesel is a bio-based alternative to conventional diesel fuel derived from petroleum. It consists mainly of the fatty acid esters of vegetable oils or other triacylglycerol feedstocks. This chapter provides a background on biodiesel as well as an overview of biodiesel production, analysis, and pr...

  17. Market penetration of biodiesel

    Directory of Open Access Journals (Sweden)

    Kenneth R. Szulczyk, Bruce A. McCarl

    2010-01-01

    Full Text Available This research examines in detail the technology and economics of substituting biodiesel for diesel #2. This endeavor examines three areas. First, the benefits of biodiesel are examined, and the technical problems of large-scale implementation. Second, the biodiesel production possibilities are examined for soybean oil, corn oil, tallow, and yellow grease, which are the largest sources of feedstocks for the United States. Examining in detail the production possibilities allows to identity the extent of technological change, production costs, byproducts, and greenhouse gas (GHG emissions. Finally, a U.S. agricultural model, FASOMGHG was used to predict market penetration of biodiesel, given technological progress, variety of technologies and feedstocks, market interactions, energy prices, and carbon dioxide equivalent prices. FASOMGHG has several interesting results. First, diesel fuel prices have an expansionary impact on the biodiesel industry. The higher the diesel fuel prices, the more biodiesel is produced. However, given the most favorable circumstances, the maximum biodiesel market penetration is 9% in 2030 with a wholesale diesel price of $4 per gallon. Second, the two dominant sources of biodiesel are from corn and soybeans. Sources like tallow and yellow grease are more limited, because they are byproducts of other industries. Third, GHG prices have an expansionary impact on the biodiesel prices, because biodiesel is quite GHG efficient. Finally, U.S. government subsidies on biofuels have an expansionary impact on biodiesel production, and increase market penetration at least an additional 3%.

  18. Market penetration of biodiesel

    Energy Technology Data Exchange (ETDEWEB)

    Szulczyk, Kenneth R. [Department of Economics, Orbita 3, Suleyman Demirel University, Almaty, 050043 (Kazakhstan); McCarl, Bruce A. [Department of Agricultural Economics, 2124 TAMU, Texas A& amp; M University, College Station, Texas, 77843 (United States)

    2010-07-01

    This research examines in detail the technology and economics of substituting biodiesel for diesel number 2. This endeavor examines three areas. First, the benefits of biodiesel are examined, and the technical problems of large-scale implementation. Second, the biodiesel production possibilities are examined for soybean oil, corn oil, tallow, and yellow grease, which are the largest sources of feedstocks for the United States. Examining in detail the production possibilities allows to identity the extent of technological change, production costs, byproducts, and greenhouse gas (GHG) emissions. Finally, a U.S. agricultural model, FASOMGHG was used to predict market penetration of biodiesel, given technological progress, variety of technologies and feedstocks, market interactions, energy prices, and carbon dioxide equivalent prices. FASOMGHG has several interesting results. First, diesel fuel prices have an expansionary impact on the biodiesel industry. The higher the diesel fuel prices, the more biodiesel is produced. However, given the most favorable circumstances, the maximum biodiesel market penetration is 9% in 2030 with a wholesale diesel price of $4 per gallon. Second, the two dominant sources of biodiesel are from corn and soybeans. Sources like tallow and yellow grease are more limited, because they are byproducts of other industries. Third, GHG prices have an expansionary impact on the biodiesel prices, because biodiesel is quite GHG efficient. Finally, U.S. government subsidies on biofuels have an expansionary impact on biodiesel production, and increase market penetration at least an additional 3%.

  19. Los libros misceláneos y la emergencia de la escritora profesional: Juana Manuela Gorriti y Clorinda Matto de Turner

    Directory of Open Access Journals (Sweden)

    Beatriz Ferrús Antón

    2013-03-01

    Full Text Available Juana Manuela Gorriti y Clorinda Matto de Turner, dos de las primeras escritoras profesionales de América Latina, publicaron libros misceláneos. Éstos son el síntoma de una época, donde la mujer se incorpora como profesional al mundo de la prensa. El objeto de este artículo es analizar estos libros, que han sido objeto del olvido crítico, prestando atención a tres elementos: los diferentes géneros que los conforman, el modo en que se imagina en ellos la “nación” y las “imágenes de mujer” que producen.

  20. Spectroscopic Analysis of Structural Transformation in Biodiesel Degradation

    Directory of Open Access Journals (Sweden)

    N. Saifuddin

    2014-09-01

    Full Text Available The vegetable oil, fats and their biodiesel suffer with the drawback of deterioration of its quality during long term storage unlike petroleum diesel. The oxidation and thermal stability of two biodiesels of different origins, viz. palm oil derived biodiesel and used cooking oil based biodiesel were analyzed. The structural transformation of Fatty Acid Methyl Ester (FAME of the biodiesels was analyzed by an infrared spectrometer and an ultraviolet absorption spectrometer. The infrared spectra of the samples were recorded by FTIR spectroscopy. The absorbance values of the spectrum bands were observed and it was determined that some of the chemical groups of oxidized oils caused changes in absorbance. The spectroscopic data of degraded biodiesel suggested oxidative polymerization. The results demonstrated that the oxidation behavior of biodiesels of different origins was closely related to the composition and distribution of FAMEs. Higher concentration of unsaturated FAME with multi-double bonds exhibited poorer oxidation resistance. In this study, in order to increase the stability of biodiesel, against oxidation process during the storage and distribution, different percentages (0.02, 0.05, 0.1 and 0.2% (w/v, respectively of caffeic acid, were added as natural antioxidants. The antioxidant effect increased with concentration up to an optimal level. Above the optimal level, the increase in antioxidant effect with its concentration was relatively small.

  1. Biodiesel at TRANSPETRO; Biodiesel na TRANSPETRO

    Energy Technology Data Exchange (ETDEWEB)

    Fonseca, Antonio Carlos C. da; Machado, Tupinamba da Conceicao S. [TRANSPETRO, Rio de Janeiro, RJ (Brazil)

    2008-07-01

    TRANSPETRO took the challenge, in early 2007, to design and install in less than one year, the systems of injection of Biodiesel in its Distribution Bases with loading truck. The basics premises, adopted for the development of the project, were based on the criteria of safety, operational reliability and to complying with legal deadline. These points guided the actions of Coordinating with two goals: Ensure the injection of Biodiesel according to time by law and the future flexibility of the system. Two to three sets were installed in each Distribution Base, respecting the characteristics of the market and the distance from centers producers of Biodiesel. TRANSPETRO was one of the first companies in Brazil using cutting-edge technology in injection of this product through the use of digital valves in the control of flow of the product. Sum up the storage capacity of Biodiesel the first and second phase of the project, TRANSPETRO will provide 8 to 10 days' stock of Biodiesel to its customers based on the injection of 5% to Diesel Oil. The Project Biodiesel at TRANSPETRO was differentiated by working in teams, the strategy for deployment and the modular aspect with focus on future demand. (author)

  2. Supercritical Synthesis of Biodiesel

    Directory of Open Access Journals (Sweden)

    Michel Vaultier

    2012-07-01

    Full Text Available The synthesis of biodiesel fuel from lipids (vegetable oils and animal fats has gained in importance as a possible source of renewable non-fossil energy in an attempt to reduce our dependence on petroleum-based fuels. The catalytic processes commonly used for the production of biodiesel fuel present a series of limitations and drawbacks, among them the high energy consumption required for complex purification operations and undesirable side reactions. Supercritical fluid (SCF technologies offer an interesting alternative to conventional processes for preparing biodiesel. This review highlights the advances, advantages, drawbacks and new tendencies involved in the use of supercritical fluids (SCFs for biodiesel synthesis.

  3. A Comprehensive Review of Effect of Biodiesel Additives on Properties, Performance, and Emission

    Science.gov (United States)

    Madiwale, S.; Karthikeyan, A.; Bhojwani, V.

    2017-05-01

    Objectives:- To presents the literature review on effect of biodiesel additives on properties, performance and on emission. Method:-In the current paper reviews are taken from previous years paper which necessitates the need of addition of additives in the blends of biodiesel and studied the its effect on properties, performance and emissions. Emissions from the diesel powered vehicles mostly damaged the earth’s environment and also increased the overall earth’s temperature. This attracts the need of alternative fuels in the field of transportation sector. Past inventions and research showed that Biodiesel can be used as an alternative fuel for the diesel engine. Biodiesel have good combustion characteristics because of their long chain hydrocarbon structure. However biodiesel possesses few disadvantages such as lower heating value, higher flow ability, much high density and not able to flow at low temperature. Higher rate of fuel consumption is identified and higher level of NOx emissions when biodiesel used in an engine as an alternative fuels. Findings:-Different additives such as antioxidants, improvers for cetane number, cold flow properties improver, etc were investigated by the many researcher and scientists and added in the different feedstock of biodiesel or blends of biodiesel with diesel in different proportions. Directly or indirectly fuel additives can improve the reduction in the emissions, improve the fuel economy, and reduce the dependency of the one’s nation on other. Performances of biodiesel vehicles were drastically improved because of additioninthe blends of biodiesel with diesel fuel in specific percentages to meet the international emission standards. Addition of additives in the biodiesel or in the blends of biodiesel basically changes the high temperature and low temperature flow properties of blends of biodiesel. Current paper finds and compares properties of different additives and its effect on blends of biodiesel properties

  4. Catalysis in biodiesel processing

    Science.gov (United States)

    A substantial industry has grown in recent years to achieve the industrial scale production of biodiesel, a renewable replacement for petroleum-derived diesel fuel. The prevalent technology for biodiesel production at this time involves use of the long known single-use catalysts sodium hydroxide (o...

  5. Biodiesel from conventional feedstocks.

    Science.gov (United States)

    Du, Wei; Liu, De-Hua

    2012-01-01

    At present, traditional fossil fuels are used predominantly in China, presenting the country with challenges that include sustainable energy supply, energy efficiency improvement, and reduction of greenhouse gas emissions. In 2007, China issued The Strategic Plan of the Mid-and-Long Term Development of Renewable Energy, which aims to increase the share of clean energy in the country's energy consumption to 15% by 2020 from only 7.5% in 2005. Biodiesel, an important renewable fuel with significant advantages over fossil diesel, has attracted great attention in the USA and European countries. However, biodiesel is still in its infancy in China, although its future is promising. This chapter reviews biodiesel production from conventional feedstocks in the country, including feedstock supply and state of the art technologies for the transesterification reaction through which biodiesel is made, particularly the enzymatic catalytic process developed by Chinese scientists. Finally, the constraints and perspectives for China's biodiesel development are highlighted.

  6. Effect of first and second generation biodiesel blends on engine performance and emission

    Science.gov (United States)

    Azad, A. K.; Rasul, M. G.; Bhuiya, M. M. K.; Islam, Rubayat

    2016-07-01

    The biodiesel is a potential source of alternative fuel which can be used at different proportions with diesel fuel. This study experimentally investigated the effect of blend percentage on diesel engine performance and emission using first generation (soybean) and second generation (waste cooking) biodiesel. The characterization of the biodiesel was done according to ASTM and EN standards and compared with ultralow sulfur diesel (ULSD) fuel. A multi-cylinder test bed engine coupled with electromagnetic dynamometer and 5 gas analyzer were used for engine performance and emission test. The investigation was made using B5, B10 and B15 blends for both biodiesels. The study found that brake power (BP) and brake torque (BT) slightly decreases and brake specific fuel consumption (BSFC) slightly increases with an increase in biodiesel blends ratio. Besides, a significant reduction in exhaust emissions (except NOx emission) was found for both biodiesels compared to ULSD. Soybean biodiesel showed better engine performance and emissions reduction compared with waste cooking biodiesel. However, NOx emission for B5 waste cooking biodiesel was lower than soybean biodiesel.

  7. Effect of first and second generation biodiesel blends on engine performance and emission

    Energy Technology Data Exchange (ETDEWEB)

    Azad, A. K., E-mail: azad.cqu@gmail.com, E-mail: a.k.azad@cqu.edu.au; Rasul, M. G., E-mail: m.rasul@cqu.edu.au; Bhuiya, M. M. K., E-mail: m.bhuiya@cqu.edu.au [School of Engineering and Technology, Central Queensland University, Rockhampton, QLD 4702 (Australia); Islam, Rubayat, E-mail: rubayat12@yahoo.com [Department of Mechanical Engineering, Bangladesh University of Engineering and Technology, Dhaka-1000 (Bangladesh)

    2016-07-12

    The biodiesel is a potential source of alternative fuel which can be used at different proportions with diesel fuel. This study experimentally investigated the effect of blend percentage on diesel engine performance and emission using first generation (soybean) and second generation (waste cooking) biodiesel. The characterization of the biodiesel was done according to ASTM and EN standards and compared with ultralow sulfur diesel (ULSD) fuel. A multi-cylinder test bed engine coupled with electromagnetic dynamometer and 5 gas analyzer were used for engine performance and emission test. The investigation was made using B5, B10 and B15 blends for both biodiesels. The study found that brake power (BP) and brake torque (BT) slightly decreases and brake specific fuel consumption (BSFC) slightly increases with an increase in biodiesel blends ratio. Besides, a significant reduction in exhaust emissions (except NO{sub x} emission) was found for both biodiesels compared to ULSD. Soybean biodiesel showed better engine performance and emissions reduction compared with waste cooking biodiesel. However, NO{sub x} emission for B5 waste cooking biodiesel was lower than soybean biodiesel.

  8. Analysis of Performance and Emmissions in a Diesel Engine Fueled with Biodiesel and Blends

    Directory of Open Access Journals (Sweden)

    Ahmet Necati ÖZSEZEN

    2009-02-01

    Full Text Available In this study, the performance and emission characteristics of biodiesel based waste palm oil and its blends with petroleum based diesel fuel (PBDF was analyzed by means of three dimensional maps. In order to determine the engine performance and exhaust emission characteristics, the engine was exposed with full load and varied speed tests. In the result of analyze, it was seen that the brake specific fuel consumptions increased with the increase of biodiesel percentage in the fuel blend, but brake torque decreased depending upon biodiesel percentage in the fuel. In the result of emission analyze, it has determined that biodiesel and its blends has provided significant improvements in HC, CO and smoke opacity emissions. However, the stable behaviors in NOx and CO2 emissions of biodiesel and its blends did not seen in terms of the engine speed.

  9. Biodiesel from microalgae

    OpenAIRE

    Aullón Alcaine, Anna

    2010-01-01

    In this project we will travel back in time to the nineteenth century to discover the inventor of the diesel engine, Rudolf Diesel, and his renewable fuel vision that is only now being realized. Biodiesel has received considerable attention in recent years as it is biodegradable, renewable and non-toxic fuel. It emits less gaseous pollutants than conventional diesel fuel, and can work directly in diesel engines with no required modifications. The most common way to produce biodiesel is by tra...

  10. Biodiesel Fuel Quality and the ASTM Biodiesel Standard

    Science.gov (United States)

    Biodiesel is usually produced from vegetable oils, animal fats and used cooking oils with alternative feedstocks such as algae receiving increasing interest. The transesterification reaction which produces biodiesel also produces glycerol and proceeds stepwise via mono- and diacylglycerol intermedi...

  11. Business management for biodiesel producers

    Energy Technology Data Exchange (ETDEWEB)

    Gerpen, Jon Van [Iowa State Univ., Ames, IA (United States)

    2004-07-01

    The material in this book is intended to provide the reader with information about the biodiesel and liquid fuels industry, biodiesel start-up issues, legal and regulatory issues, and operational concerns.

  12. BIODIESELS AS A FUNCTION OF ENVIRONMENTAL PROTECTION

    Directory of Open Access Journals (Sweden)

    Lovro Babić

    2013-04-01

    Full Text Available As of July 1st 2013. the Republic of Croatia will be a member of the European Union, which will primarily bring necessary harmonisation of ecological standards and requirements. Biodiesel, as a renewable source of energy, can be produced from algae, vegetable oil, and animal fats, and thus it is biodegradable. Biodiesel in Croatia is mainly produced from oilseed rape which, as an agricultural plant, has an increasing share in the past three years and records positive trends. This paper analyses the trend of production in the Republic of Croatia, and compares it with the production and consumption of fossil fuels. On the grounds of Croatia’s favourable agriculture-related climatic characteristics, in particular in the region of Slavonija and Baranja, more intense exploitation of farm land under the cultures intended for biodiesel production can be organised aiming at bumper yield and production. Croatia has already harmonised its standards of production of biodiesel, and by 2020 the consumption of biodiesel is bound to reach 20%. The data used in this paper are obtained from the sources available by Croatian Institute of Statistics, Market Information System in Agriculture, as well as Eurostat, and the rest used here are translated from the sources in the English language. The reviewed are the surfaces planted with oilseed rape in the period between 2007. and 2011., an average yield, and overall production. On the grounds of available information, the calculations of the quantity of bio fuel to be consumed in Croatia by 2020. and the percentage of the land surfaces planted with oilseed rape have been made.

  13. Production of Biodiesel from Chicken Frying Oil

    Directory of Open Access Journals (Sweden)

    Emaad T. Bakir

    2011-12-01

    Full Text Available Chicken fried oil was converted into different biodiesels through single step transesterification and two step transesterification, namely acid-base and base–base catalyzed transesterification. Hydrochloric acid and potassium hydroxide with methanol were used for this purpose. The results showed that two step base catalyzed transesterification was better compared to other methods. It resulted in higher yield and better fuel properties. Transesterification of fried chicken oil was monitored by TLC technique and compared with that of the parent oil. Fuel properties of the products have been measured and found markedly enhanced compared to those of the parent oil. Also, the values satisfied the standard limits according to the ASTM standards. Blending of the better biodiesel sample with petro diesel was made using three volume percentages (10, 30 and 50% v/v. The results disclosed that blending had slight effect on the original properties of petro diesel.

  14. Effect of Algae-Derived Biodiesel on Ignition Delay, Combustion Process and Emission

    Science.gov (United States)

    Kumaran, Mahendran; Khalid, Amir; Salleh, Hamidon; Razali, Azahari; Sapit, Azwan; Jaat, Norrizam; Sunar, Norshuhaila

    2016-11-01

    Algae oil methyl esters produced from algae oil were blended with diesel at various volumetric percentages to evaluate the variations in the fuel properties. Microalgae biodiesel production has received much interest in an effort for sustainable development as the microalgae seem to be an attractive way to produce the biodiesel due to their ability to accumulate lipids and their very high actual photosynthetic yields. Correlations between fuel properties, including the calorific heat, density, kinematic viscosity, and oxidation stability of the Algae oil-diesel blends, and the blending ratio of the algae biodiesel have been established. As a result, low blending ratio of the Algae oil with diesel was recommended up to 2vol % in comparison with other type of biodiesel-diesel blends. The objective of this research is to investigate effect of biodiesel blending ratio on ignition delay, combustion process and emission for different type of biodiesel. The combustion tests of the Algae-Derived biodiesel blends were performed in a Rapid Compression Machine (RCM). The combustion tests were carried out at injection pressure of 130 MPa and ambient temperature were varied between 750 K and 1100 K. The result from the experiment is compared with Palm-Oil biodiesel which are varied in biodiesel percentage from 5vol% to 15vol% and jatropha biodiesel. Higher ignition delay period were clearly observed with higher blending ratio. It seems that increasing blending ratio exhibits relatively weakens in fuel ignitibility and therefore prolongs the ignition delay of algae biodiesel. A2 had the lowest ignition delay period when compared with J2, B5, B10 and B15 due to lower density that present in A2 molecules.The concentration of carbon dioxide and nitrogen monoxide in the exhaust gas increased with higher blending ratio while the concentration of carbon monoxide and hydrocarbon decreased.

  15. Particle emissions from microalgae biodiesel combustion and their relative oxidative potential.

    Science.gov (United States)

    Rahman, M M; Stevanovic, S; Islam, M A; Heimann, K; Nabi, M N; Thomas, G; Feng, B; Brown, R J; Ristovski, Z D

    2015-09-01

    Microalgae are considered to be one of the most viable biodiesel feedstocks for the future due to their potential for providing economical, sustainable and cleaner alternatives to petroleum diesel. This study investigated the particle emissions from a commercially cultured microalgae and higher plant biodiesels at different blending ratios. With a high amount of long carbon chain lengths fatty acid methyl esters (C20 to C22), the microalgal biodiesel used had a vastly different average carbon chain length and level of unsaturation to conventional biodiesel, which significantly influenced particle emissions. Smaller blend percentages showed a larger reduction in particle emission than blend percentages of over 20%. This was due to the formation of a significant nucleation mode for the higher blends. In addition measurements of reactive oxygen species (ROS), showed that the oxidative potential of particles emitted from the microalgal biodiesel combustion were lower than that of regular diesel. Biodiesel oxygen content was less effective in suppressing particle emissions for biodiesels containing a high amount of polyunsaturated C20-C22 fatty acid methyl esters and generated significantly increased nucleation mode particle emissions. The observed increase in nucleation mode particle emission is postulated to be caused by very low volatility, high boiling point and high density, viscosity and surface tension of the microalgal biodiesel tested here. Therefore, in order to achieve similar PM (particulate matter) emission benefits for microalgal biodiesel likewise to conventional biodiesel, fatty acid methyl esters (FAMEs) with high amounts of polyunsaturated long-chain fatty acids (≥C20) may not be desirable in microalgal biodiesel composition.

  16. Evaluation of Miscelánea de Estudios Árabes y Hebraicos According to the Criteria of the Spanish National Comisión for the Evaluation of Research Activities

    Directory of Open Access Journals (Sweden)

    Antonio Bernardo Espinosa-Ramírez

    2015-12-01

    Full Text Available

    Scientific journals are nowadays the main way of communication and spread of research activity, but these journals must be also submitted for evaluating their different mechanisms for selecting and publishing in order to consider their scientific impact in their own fields and for being included in the major reference databases. The paper evaluates Miscelánea de Estudios Árabes y Hebraicos. Sección Hebreo according to the requirements for scientific journals by the Spanish National Evaluation of Research Activity (CNEAI.

  17. Biodiesel Handling and Use Guide (Fifth Edition)

    Energy Technology Data Exchange (ETDEWEB)

    Alleman, Teresa L.; McCormick, Robert L.; Christensen, Earl D.; Fioroni, Gina; Moriarty, Kristi; Yanowitz, Janet

    2016-11-08

    This document is a guide for those who blend, distribute, and use biodiesel and biodiesel blends. It provides basic information on the proper and safe use of biodiesel and biodiesel blends in engines and boilers, and is intended to help fleets, individual users, blenders, distributors, and those involved in related activities understand procedures for handling and using biodiesel fuels.

  18. Snohomish County Biodiesel Project

    Energy Technology Data Exchange (ETDEWEB)

    Chang, Terrill; Carveth, Deanna

    2010-02-01

    Snohomish County in western Washington State began converting its vehicle fleet to use a blend of biodiesel and petroleum diesel in 2005. As prices for biodiesel rose due to increased demand for this cleaner-burning fuel, Snohomish County looked to its farmers to grow this fuel locally. Suitable seed crops that can be crushed to extract oil for use as biodiesel feedstock include canola, mustard, and camelina. The residue, or mash, has high value as an animal feed. County farmers began with 52 acres of canola and mustard crops in 2006, increasing to 250 acres and 356 tons in 2008. In 2009, this number decreased to about 150 acres and 300 tons due to increased price for mustard seed.

  19. Emissions characteristics of a diesel engine operating on biodiesel and biodiesel blended with ethanol and methanol.

    Science.gov (United States)

    Zhu, Lei; Cheung, C S; Zhang, W G; Huang, Zhen

    2010-01-15

    Euro V diesel fuel, pure biodiesel and biodiesel blended with 5%, 10% and 15% of ethanol or methanol were tested on a 4-cylinder naturally-aspirated direct-injection diesel engine. Experiments were conducted under five engine loads at a steady speed of 1800 r/min. The study aims to investigate the effects of the blended fuels on reducing NO(x) and particulate. On the whole, compared with Euro V diesel fuel, the blended fuels could lead to reduction of both NO(x) and PM of a diesel engine, with the biodiesel-methanol blends being more effective than the biodiesel-ethanol blends. The effectiveness of NO(x) and particulate reductions is more effective with increase of alcohol in the blends. With high percentage of alcohol in the blends, the HC, CO emissions could increase and the brake thermal efficiency might be slightly reduced but the use of 5% blends could reduce the HC and CO emissions as well. With the diesel oxidation catalyst (DOC), the HC, CO and particulate emissions can be further reduced.

  20. Microwave irradiation biodiesel processing of waste cooking oil

    Science.gov (United States)

    Motasemi, Farough; Ani, Farid Nasir

    2012-06-01

    Major part of the world's total energy output is generated from fossil fuels, consequently its consumption has been continuously increased which accelerates the depletion of fossil fuel reserves and also increases the price of these valuable limited resources. Biodiesel is a renewable, non-toxic and biodegradable diesel fuel which it can be the best environmentally friendly and easily attainable alternative for fossil fuels. The costs of feedstock and production process are two important factors which are particularly against large-scale biodiesel production. This study is intended to optimize three critical reaction parameters including intensity of mixing, microwave exit power and reaction time from the transesterification of waste cooking oil by using microwave irradiation in an attempt to reduce the production cost of biodiesel. To arrest the reaction, similar quantities of methanol/oil molar ratio (6:1) and potassium hydroxide (2% wt) as the catalyst were used. The results showed that the best yield percentage (95%) was obtained using 300W microwave exit power, 300 rpm stirrer speed (intensity of mixing) and 78°C for 5 min. It was observed that increasing the intensity of mixing greatly ameliorates the yield percentage of biodiesel (up to 17%). Moreover, the results demonstrate that increasing the reaction time in the low microwave exit power (100W) improves the yield percentage of biodiesel, while it has a negative effect on the conversion yield in the higher microwave exit power (300W). From the obtained results it was clear that FAME was within the standards of biodiesel fuel.

  1. Enhancement of biodiesel production from different species of algae

    OpenAIRE

    El-Moneim M. R. Afify, Abd; Shalaby, Emad A.; Shanab, Sanaa M. M.

    2010-01-01

    Eight algal species (4 Rhodo, 1 chloro and 1 phaeophycean macroalgae, 1 cyanobacterium and 1 green microalga) were used for the production of biodiesel using two extraction solvent systems (Hexane/ether (1:1, v/v)) and (Chloroform/ methanol (2:1, v/v)). Biochemical evaluations of algal species were carried out by estimating biomass, lipid, biodiesel and sediment (glycerin and pigments) percentages. Hexane/ ether (1:1, v/v) extraction so...

  2. Pyrolytic characteristics of biodiesel prepared from lipids accumulated in diatom cells with growth regulation.

    Science.gov (United States)

    Cheng, Jun; Feng, Jia; Ge, Tingting; Yang, Weijuan; Zhou, Junhu; Cen, Kefa

    2015-08-01

    Dynamic compositions of lipids accumulated in two diatoms Chaetoceros gracilis and Nitzschia closterium cultured with nitrogen and silicon deprivation were studied. It was found that short-chain fatty acids (C14-C16) content was much higher than long-chain fatty acids (C18-C20) content in lipids of two diatoms. The pyrolytic characteristics of biodiesel made from two diatoms and two plant seeds were compared by thermogravimetric analysis. The highest activation energy of 46.68 kJ mol(-1) and the minimum solid residue of 25.18% were obtained in the pyrolysis of biodiesel made from C. gracilis cells, which were cultured with 0.5 mmol L(-1) of nitrogen (no silicon) and accumulated the minimum polyunsaturated fatty acid (C20:5). The pyrolysis residue percentage of C. gracilis biodiesel was lower than that of N. closterium biodiesel and higher than those of plant (Cormus wilsoniana and Pistacia chinensis) biodiesels.

  3. Synthesis, spectroscopic and chromatographic studies of sunflower oil biodiesel using optimized base catalyzed methanolysis.

    Science.gov (United States)

    Naureen, Rizwana; Tariq, Muhammad; Yusoff, Ismail; Chowdhury, Ahmed Jalal Khan; Ashraf, Muhammad Aqeel

    2015-05-01

    Methyl esters from vegetable oils have attracted a great deal of interest as substitute for petrodiesel to reduce dependence on imported petroleum and provide an alternate and sustainable source for fuel with more benign environmental properties. In the present study biodiesel was prepared from sunflower seed oil by transesterification by alkali-catalyzed methanolysis. The fuel properties of sunflower oil biodiesel were determined and discussed in the light of ASTM D6751 standards for biodiesel. The sunflower oil biodiesel was chemically characterized with analytical techniques like FT-IR, and NMR ((1)H and (13)C). The chemical composition of sunflower oil biodiesel was determined by GC-MS. Various fatty acid methyl esters (FAMEs) were identified by retention time data and verified by mass fragmentation patterns. The percentage conversion of triglycerides to the corresponding methyl esters determined by (1)H NMR was 87.33% which was quite in good agreement with the practically observed yield of 85.1%.

  4. Why Teach about Biodiesel?

    Science.gov (United States)

    Lawrence, Richard

    2002-01-01

    Proposes that study of biodiesel as a healthier alternative to petroleum diesel be included in the curriculum. Suggests that teachers will play a critical role during the transition away from fossil fuel technologies. Provides background information and web-based resources. (DLH)

  5. Analysis of biodiesel

    Science.gov (United States)

    Biodiesel is a biogenic alternative to diesel fuel derived from petroleum. It is produced by a transesterification reaction from materials consisting largely of triacylglycerols such as vegetable and other plant oils, animal fats, used cooking oils, and “alternative” feedstocks such as algal oils. T...

  6. A review on biodiesel production using catalyzed transesterification

    Energy Technology Data Exchange (ETDEWEB)

    Leung, Dennis Y.C.; Wu, Xuan; Leung, M.K.H. [Department of Mechanical Engineering, The University of Hong Kong, Pokfulam Road, Hong Kong (China)

    2010-04-15

    Biodiesel is a low-emissions diesel substitute fuel made from renewable resources and waste lipid. The most common way to produce biodiesel is through transesterification, especially alkali-catalyzed transesterification. When the raw materials (oils or fats) have a high percentage of free fatty acids or water, the alkali catalyst will react with the free fatty acids to form soaps. The water can hydrolyze the triglycerides into diglycerides and form more free fatty acids. Both of the above reactions are undesirable and reduce the yield of the biodiesel product. In this situation, the acidic materials should be pre-treated to inhibit the saponification reaction. This paper reviews the different approaches of reducing free fatty acids in the raw oil and refinement of crude biodiesel that are adopted in the industry. The main factors affecting the yield of biodiesel, i.e. alcohol quantity, reaction time, reaction temperature and catalyst concentration, are discussed. This paper also described other new processes of biodiesel production. For instance, the Biox co-solvent process converts triglycerides to esters through the selection of inert co-solvents that generates a one-phase oil-rich system. The non-catalytic supercritical methanol process is advantageous in terms of shorter reaction time and lesser purification steps but requires high temperature and pressure. For the in situ biodiesel process, the oilseeds are treated directly with methanol in which the catalyst has been preciously dissolved at ambient temperatures and pressure to perform the transesterification of oils in the oilseeds. This process, however, cannot handle waste cooking oils and animal fats. (author)

  7. Costilla County Biodiesel Pilot Project

    Energy Technology Data Exchange (ETDEWEB)

    Doon, Ben; Quintana, Dan

    2011-08-25

    The Costilla County Biodiesel Pilot Project has demonstrated the compatibility of biodiesel technology and economics on a local scale. The project has been committed to making homegrown biodiesel a viable form of community economic development. The project has benefited by reducing risks by building the facility gradually and avoiding large initial outlays of money for facilities and technologies. A primary advantage of this type of community-scale biodiesel production is that it allows for a relatively independent, local solution to fuel production. Successfully using locally sourced feedstocks and putting the fuel into local use emphasizes the feasibility of different business models under the biodiesel tent and that there is more than just a one size fits all template for successful biodiesel production.

  8. Biodiesel production using heterogeneous catalysts.

    Science.gov (United States)

    Semwal, Surbhi; Arora, Ajay K; Badoni, Rajendra P; Tuli, Deepak K

    2011-02-01

    The production and use of biodiesel has seen a quantum jump in the recent past due to benefits associated with its ability to mitigate greenhouse gas (GHG). There are large number of commercial plants producing biodiesel by transesterification of vegetable oils and fats based on base catalyzed (caustic) homogeneous transesterification of oils. However, homogeneous process needs steps of glycerol separation, washings, very stringent and extremely low limits of Na, K, glycerides and moisture limits in biodiesel. Heterogeneous catalyzed production of biodiesel has emerged as a preferred route as it is environmentally benign needs no water washing and product separation is much easier. The present report is review of the progress made in development of heterogeneous catalysts suitable for biodiesel production. This review shall help in selection of suitable catalysts and the optimum conditions for biodiesel production.

  9. Obtaining biodiesel from spanish used frying oil: Issues in meeting the EN 14214 biodiesel standard

    Energy Technology Data Exchange (ETDEWEB)

    Berrios, M.; Gutierrez, M.C.; Martin, M.A.; Martin, A. [Departamento de Quimica Inorganica e Ingenieria Quimica, Universidad de Cordoba, Campus Universitario de Rabanales, Edificio Marie Curie, 14071 Cordoba (Spain)

    2010-03-15

    The biodiesel production from Spanish used frying oils has been studied using two operation flow charts: two-step alkaline transesterification and sequential esterification-transesterification, followed by washing in water in both cases, in order to set out the most suitable operational conditions to achieve the highest FAME percentage in the shortest time. Sequential esterification-transesterification reached slightly better results than two-step alkaline transesterification. The resulting product cannot be called biodiesel as the specifications of EN 14214 Standards have not been met. Specifically, FAME content and kinematic viscosity were outside the requirements because of the chemical modifications which took place in the oil during cooking (presence of polar compounds). The influence of polar compounds on the processes has been studied by means of their analysis in the oil and the product. (author)

  10. Sustainable Biocatalytic Biodiesel Production

    DEFF Research Database (Denmark)

    Güzel, Günduz

    and chemical equilibria as part of his main sustainable biodiesel project. The transesterification reaction of vegetable oils or fats with an aliphatic alcohol – in most cases methanol or ethanol – yields biodiesel (long-chain fatty acid alkyl esters – FAAE) as the main product in the presence of alkaline....../acid catalysts or biocatalysts (free or immobilised lipase enzymes). The reaction by-product glycerol is immiscible with the ester products (FAAE and oils/fats) in addition to the partial miscibility problem of methanol or ethanol with oils/fats. The insoluble parts of alcohol feeds or by-products form emulsion...... droplets within the reaction media, where continuous stirring operations are applied to improve mass transfer and thus reaction rates. In all other cases, there is a heterogeneous alcohol phase in equilibrium with the ester phase under equilibrium conditions. The immiscibility and/or miscibility drawbacks...

  11. Production of biodiesel from microalgae

    Directory of Open Access Journals (Sweden)

    Danilović Bojana R.

    2014-01-01

    Full Text Available In recent years, more attention has been paid to the use of third generation feedstocs for the production of biodiesel. One of the most promising sources of oil for biodiesel production are microalgae. They are unicellular or colonial photosynthetic organisms, with permanently increasing industrial application in the production of not only chemicals and nutritional supplements but also biodiesel. Biodiesel productivity per hectare of cultivation area can be up to 100 times higher for microalgae than for oil crops. Also, microalgae can grow in a variety of environments that are often unsuitable for agricultural purposes. Microalgae oil content varies in different species and can reach up to 77% of dry biomass, while the oil productivity by the phototrophic cultivation of microalgae is up to 122 mg/l/d. Variations of the growth conditions and the implementation of the genetic engineering can induce the changes in the composition and productivity of microalgal oil. Biodiesel from microalgae can be produced in two ways: by transesterification of oil extracted from biomass or by direct transesterification of algal biomass (so called in situ transesterification. This paper reviews the curent status of microalgae used for the production of biodiesel including their isolation, cultivation, harvesting and conversion to biodiesel. Because of high oil productivity, microalgae will play a significant role in future biodiesel production. The advantages of using microalgae as a source for biofuel production are increased efficiency and reduced cost of production. Also, microalgae do not require a lot of space for growing and do not have a negative impact on the global food and water supplies. Disadvantages of using microalgae are more difficult separation of biomass and the need for further research to develop standardized methods for microalgae cultivation and biodiesel production. Currently, microalgae are not yet sustainable option for the commercial

  12. Biodiesel Test Plan

    Science.gov (United States)

    2014-07-01

    toxic replacement is most often made from soybean oil through a process called transesterfication, whereby it is mixed with methanol to produce both soy...vegeta b le oils or animal fats , for use in compression-ignition (diesel) engines. This specification is For pure (100%) biodiesel prior to use or...field testing, provided no safety concerns or major issues are discovered. The BUSL engines and fuel system will be prepared and modified to ensure

  13. Particulate emissions from a stationary engine fueled with ultra-low-sulfur diesel and waste-cooking-oil-derived biodiesel.

    Science.gov (United States)

    Betha, Raghu; Balasubramanian, Rajasekhar

    2011-10-01

    Stationary diesel engines, especially diesel generators, are increasingly being used in both developing countries and developed countries because of increased power demand. Emissions from such engines can have adverse effects on the environment and public health. In this study, particulate emissions from a domestic stationary diesel generator running on ultra-low-sulfur diesel (ULSD) and biodiesel derived from waste cooking oil were characterized for different load conditions. Results indicated a reduction in particulate matter (PM) mass and number emissions while switching diesel to biodiesel. With increase in engine load, it was observed that particle mass increased, although total particle counts decreased for all the fuels. The reduction in total number concentration at higher loads was, however, dependent on percentage of biodiesel in the diesel-biodiesel blend. For pure biodiesel (B100), the reduction in PM emissions for full load compared to idle mode was around 9%, whereas for ULSD the reduction was 26%. A large fraction of ultrafine particles (UFPs) was found in the emissions from biodiesel compared to ULSD. Nearly 90% of total particle concentration in biodiesel emissions comprised ultrafine particles. Particle peak diameter shifted from a smaller to a lower diameter with increase in biodiesel percentage in the fuel mixture.

  14. Performance and emission parameters of single cylinder diesel engine using castor oil bio-diesel blended fuels

    Science.gov (United States)

    Rahimi, A.; Ghobadian, B.; Najafi, G.; Jaliliantabar, F.; Mamat, R.

    2015-12-01

    The purpose of this study is to investigate the performance and emission parameters of a CI single cylinder diesel engine operating on biodiesel-diesel blends (B0, B5, B10, B15 and E20: 20% biodiesel and 80% diesel by volume). A reactor was designed, fabricated and evaluated for biodiesel production. The results showed that increasing the biodiesel content in the blend fuel will increase the performance parameters and decrease the emission parameters. Maximum power was detected for B0 at 2650 rpm and maximum torque was belonged to B20 at 1600 rpm. The experimental results revealed that using biodiesel-diesel blended fuels increased the power and torque output of the engine. For biodiesel blends it was found that the specific fuel consumption (sfc) was decreased. B10 had the minimum amount for sfc. The concentration of CO2 and HC emissions in the exhaust pipe were measured and found to be decreased when biodiesel blends were introduced. This was due to the high oxygen percentage in the biodiesel compared to the net diesel fuel. In contrast, the concentration of CO and NOx was found to be increased when biodiesel is introduced.

  15. Predicting various biodiesel fuel properties

    Science.gov (United States)

    Several essential fuel properties of biodiesel are largely determined by the properties of the fatty esters which are its main components. These include cetane number, kinematic viscosity, oxidative stability, and cold flow which are contained in almost all biodiesel standards but also other propert...

  16. The State High Biodiesel Project

    Science.gov (United States)

    Heasley, Paul L.; Van Der Sluys, William G.

    2009-01-01

    Through a collaborative project in Pennsylvania, high school students developed a method for converting batches of their cafeteria's waste fryer oil into biodiesel using a 190 L (50 gal) reactor. While the biodiesel is used to supplement the school district's heating and transportation energy needs, the byproduct--glycerol--is used to make hand…

  17. Biodiesel lubricity and other properties

    Science.gov (United States)

    Biodiesel, defined as the mono-alkyl esters of vegetable oils or animal fats, is an “alternative” diesel fuel that is becoming accepted in a steadily growing number of countries worldwide. Since the source of biodiesel varies with the location, and other sources such as recycled oils are continuousl...

  18. An experimental study on thermal stability of biodiesel fuel

    Science.gov (United States)

    Zhu, Yiying

    adequately describe the experimental data points of the concentrations or the decomposition percentage as a function of time. The forward and reverse rate constants were determined at each temperature for the model. The Arrhenius pre-exponential factors A for k1 and k2 obtained were 1.50 x 109 and 257 min-1, and the energies of activation Ea were 126.0 and 46.0 KJ/mol, respective. The high linearity of the Arrhenius plots (R2 > 98%) further validated the rationality of the assumed reversible first-order kinetics to represent the overall biodiesel decomposition. Moreover, a Van't Hoff plot was established, the reaction enthalpy DeltaHo for biodiesel thermal decomposition is 80.0 KJ/mol, indicating the overall decomposition is an endothermic reaction.

  19. The Effects of Biodiesel and Crude Oil on the Foraging Behavior of Rusty Crayfish, Orconectes rusticus.

    Science.gov (United States)

    Jurcak, Ana M; Gauthier, Steven J; Moore, Paul A

    2015-11-01

    Environmental pollutants, such as crude oil and other petroleum-based fuels, inhibit and limit an organism's ability to perceive a chemical stimulus. Despite the increased use of alternative fuels, such as biodiesel, there have been few studies investigating the impact of these chemicals on the behavior of aquatic organisms. The purpose of this study was to compare the sublethal effects of biodiesel and crude oil exposure on chemically mediated behaviors in a freshwater keystone species. Crayfish (Orconectes rusticus) were tested on their ability to respond appropriately to a positive chemical stimulus within a Y-maze choice paradigm. Behavior was quantified by measuring time spent finding an odor source, duration of time spent at the odor source, percentage of crayfish that found the odor source, and percentage of crayfish that chose the correct arm of the arena. Results indicated negative impacts of both biodiesel and crude oil on the ability of crayfish to locate the food source. However, there were no significant differences between behavioral performances when crayfish were exposed to crude oil compared with biodiesel. Thus, biodiesel and crude oil have equally negative effects on the chemosensory behavior of crayfish. These findings indicate that biodiesel has the potential to have similar negative ecological impacts as other fuel source toxins.

  20. Life cycle energy and CO2 analysis of microalgae-to-biodiesel: preliminary results and comparisons.

    Science.gov (United States)

    Khoo, H H; Sharratt, P N; Das, P; Balasubramanian, R K; Naraharisetti, P K; Shaik, S

    2011-05-01

    Despite claims that microalgal biofuels are environmentally friendlier alternatives to conventional fuels, debate surrounding its ecological benefits or drawbacks still exists. LCA is used to analyze various biofuel production technologies from 'cradle to gate'. Energy and CO(2) balances are carried out for a hypothetical integrated PBR-raceway microalgae-to-biodiesel production in Singapore. Based on a functional unit of 1 MJ biofuel, the total energy demands are 4.44 MJ with 13% from biomass production, 85% from lipid extraction, and 2% from biodiesel production. Sensitivity analysis was carried out for adjustments in energy requirements, percentage lipid contents, and lower/higher heating product value. An 'Optimistic Case' was projected with estimates of: 45% lipid content; reduced energy needs for lipid extraction (1.3 MJ per MJ biodiesel); and heating value of biodiesel (42 MJ/kg). The life cycle energy requirements dropped significantly by about 60%. The results are compared with other published case studies from other countries.

  1. An ultrasound-assisted system for the optimization of biodiesel production from chicken fat oil using a genetic algorithm and response surface methodology.

    Science.gov (United States)

    Fayyazi, E; Ghobadian, B; Najafi, G; Hosseinzadeh, B; Mamat, R; Hosseinzadeh, J

    2015-09-01

    Biodiesel is a green (clean), renewable energy source and is an alternative for diesel fuel. Biodiesel can be produced from vegetable oil, animal fat and waste cooking oil or fat. Fats and oils react with alcohol to produce methyl ester, which is generally known as biodiesel. Because vegetable oil and animal fat wastes are cheaper, the tendency to produce biodiesel from these materials is increasing. In this research, the effect of some parameters such as the alcohol-to-oil molar ratio (4:1, 6:1, 8:1), the catalyst concentration (0.75%, 1% and 1.25% w/w) and the time for the transesterification reaction using ultrasonication on the rate of the fatty acids-to-methyl ester (biodiesel) conversion percentage have been studied (3, 6 and 9 min). In biodiesel production from chicken fat, when increasing the catalyst concentration up to 1%, the oil-to-biodiesel conversion percentage was first increased and then decreased. Upon increasing the molar ratio from 4:1 to 6:1 and then to 8:1, the oil-to-biodiesel conversion percentage increased by 21.9% and then 22.8%, respectively. The optimal point is determined by response surface methodology (RSM) and genetic algorithms (GAs). The biodiesel production from chicken fat by ultrasonic waves with a 1% w/w catalyst percentage, 7:1 alcohol-to-oil molar ratio and 9 min reaction time was equal to 94.8%. For biodiesel that was produced by ultrasonic waves under a similar conversion percentage condition compared to the conventional method, the reaction time was decreased by approximately 87.5%. The time reduction for the ultrasonic method compared to the conventional method makes the ultrasonic method superior.

  2. Er biodiesel en god ide?

    DEFF Research Database (Denmark)

    Schmidt, Jannick

    2007-01-01

    Biodiesel opfattes som en grøn miljøvenlig teknologi. Men har dette 'grønne' alternativ til konventionel diesel en skjult bagside af medaljen? Og kan det være, at man i stedet for at få et bedre miljø, medvirker til øgede miljøpåvirkninger i form af emissioner og naturødelæggelse, når man skifter...... til biodiesel? I artiklen belyses nogle af de mest sejlivede myter omkring biodiesel. Udgivelsesdato: Januar...

  3. Pengaruh Zat Aditif Urea terhadap Kuantitas Biodiesel Pada Reaksi Transesterfikasi

    Directory of Open Access Journals (Sweden)

    Rismawati Rasyid

    2017-03-01

    Full Text Available Abstrak Asam lemak jenuh maupun tak jenuh pada minyak nabati memiliki potensi untuk diubah menjadi bahan kimia penyusun bahan bakar . Komponen asam lemak pada CPO RBD dengan komposisi terbesar adalah asam palmitat (38.2% dan asam oleat (45.89%.  Pembuatan biodiesel dalam penelitian ini menggunakan CPO (Crude Palm Oil yang telah dimurnikan melalui reaksi transesterfikasi dengan pereaksi etanol dan katalisator KOH. Penambahan urea sebagai zat aditif pada reaksi dapat meningkatkan kualitas biodiesel yang diperoleh serta lebih efisien dalam tahapan pemurnian. Persentase kadar FAME (Fatty Acid Metyl Ester setara dengan persen yield biodiesel pada proses reaksi tanpa penambahan urea adalah 90.34% dan mengalami peningkatan setelah penambahan urea sebesar 98%. Densitas yang dihasilkan pada reaksi tanpa zat aditif  0.868 gr/ ml dan reaksi dengan penambahan zat aditif memiliki densitas  0.866 gr/ml,  kedua produk tersebut telah sesuai dengan standar SNI yakni berkisar 0.85–0.89. Kata kunci : biodiesel, CPO, zat aditif Abstract Saturated and unsaturated fatty acids in vegetable oils have potential to be converted into constituent of chemicals fuel. Fatty acids in the RBD palm oil with the largest composition are palmitic acid (38.2% and oleic acid (45.89%. Production of fuel which substitute diesel fuel (biodiesel from CPO (Crude Palm Oil which has been purified by transesterification reaction with ethanol reagent and KOH catalyst. The addition of urea as an additive substancein the reaction to improve  the quality as well as more efficient biodiesel obtained in the purification stages. Percentage value of FAME(Fatty Acid Metyl Esteror yield biodiesel in the reaction without the addition of urea is 90.34% and after the addition of urea increased by 98%. Density of product that produced in the reaction without additives is 0.868 g / ml and for reaction with additives has a density of 0.866 g / ml, both of these products are met the criteria of SNI

  4. Obtention and characterization of biodiesel; Obtencao e caracterizacao do biodiesel

    Energy Technology Data Exchange (ETDEWEB)

    Santos, Leonidas B.O. dos; Caitano, Moises; Aranda, Donato A.G.; Mothe, Cheila G. [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil)

    2004-07-01

    Biodiesel is an ester resulting from the transesterification reaction of an alcohol and an oil obtained from biomass. The products of the transesterification are an ester and the glycerol. The biodiesel and the petroleum commercial diesel have similar properties, and they can be mixed and used in diesel motors. The use of biodiesel will allow a better exploration of the energetic potential of our cultures. The biodiesel has some advantages compared to others combustibles, such as adaptability to usual diesel motors and non-generation of NO{sub x} and SO{sub x} compounds. Many experiments with biodiesel have been made in Brazil since the 70's. This work made samples of biodiesel by transesterification batch reactions to many blends of soybean oil and residual fry oil, at room temperature, using mechanical mixture or magnetic agitation by a magnetic stirrer, using as catalysts sodium methoxide and potassium hydroxide. For each obtained sample tests to determine the Acidity Index (ABNT-MB-74), Saponification Index (ABNT-MB-75), Iodine Wijz Index (ABNT-MB- 77), thermal analysis by DTA and TG (TA Instruments SDT 2960, 30 to 800 deg C, 10 deg C/min at nitrogen atmosphere) and rheological test (Haake RS 150 Rheo Stress rheometer) were done. (author)

  5. Lipases as biocatalyst for biodiesel production.

    Science.gov (United States)

    Fan, Xiaohu; Niehus, Xochitl; Sandoval, Georgina

    2012-01-01

    The global shortages of fossil fuels, significant increase in the price of crude oil, and increased environmental concerns have stimulated the rapid growth in biodiesel production. Biodiesel is generally produced through transesterification reaction catalyzed either chemically or enzymatically. Enzymatic transesterification draws high attention because that process shows certain advantages over the chemical catalysis of transesterification and it is "greener." This paper reviews the current status of biodiesel production with lipase-biocatalysis approach, including sources of lipases, kinetics, and reaction mechanism of biodiesel production using lipases, and lipase immobilization techniques. Factors affecting biodiesel production and economic feasibility of biodiesel production using lipases are also covered.

  6. Verf en biodiesel uit algen

    NARCIS (Netherlands)

    Mooibroek, H.

    2009-01-01

    Met algen kun je niet alleen biodiesel en groene coatings produceren, maar ook iets doen aan het mestoverschot en de uitstoot van kooldioxide. In Delfzijl zijn kweekvijvers geopend om de technologie hiervoor te ontwikkelen

  7. Toxicology of Biodiesel Combustion products

    Science.gov (United States)

    1. Introduction The toxicology of combusted biodiesel is an emerging field. Much of the current knowledge about biological responses and health effects stems from studies of exposures to other fuel sources (typically petroleum diesel, gasoline, and wood) incompletely combusted. ...

  8. Methyl biodiesel from Dipteryx lacunifera: preparation, characterization and effect of antioxidant on the oxidation stability; Biodiesel metilico de Dipteryx lacunifera: preparacao, caracterizacao e efeito de antioxidantes na estabilidade a oxidacao

    Energy Technology Data Exchange (ETDEWEB)

    Araujo, Francisca Diana da Silva; Moura, Carla Veronica Rodarte de; Chaves, Mariana H., E-mail: mariana@ufpi.edu.b [Universidade Federal do Piaui (UFPI), Teresina, PI (Brazil). Dept. de Quimica

    2010-07-01

    The objective of this work was to study the potentialities of Dipteryx lacunifera Ducke seeds oil for biodiesel production. The yield in oil was of 46.11 {+-} 0.37%. Methyl biodiesel was prepared by base catalyzed transesterification yielding 88.13% and percentage conversion of triglycerides to corresponding methyl ester of 89.1%. The addition of the tertiary butylhydroquinone (TBHQ, 50 ppm), butylated hydroxytoluene (BHT, 50 ppm) and cashew nut shell liquid (CNSL, 2000 ppm) antioxidants in the biodiesel contributed to the increase of the induction period of 2.97 h for 8.08; 6.06 and 6.02 h, respectively. (author)

  9. Ionic liquid as a promising biobased green solvent in combination with microwave irradiation for direct biodiesel production.

    Science.gov (United States)

    Wahidin, Suzana; Idris, Ani; Shaleh, Sitti Raehanah Muhamad

    2016-04-01

    The wet biomass microalgae of Nannochloropsis sp. was converted to biodiesel using direct transesterification (DT) by microwave technique and ionic liquid (IL) as the green solvent. Three different ionic liquids; 1-butyl-3-metyhlimidazolium chloride ([BMIM][Cl], 1-ethyl-3-methylimmidazolium methyl sulphate [EMIM][MeSO4] and 1-butyl-3-methylimidazolium trifluoromethane sulfonate [BMIM][CF3SO3]) and organic solvents (hexane and methanol) were used as co-solvents under microwave irradiation and their performances in terms of percentage disruption, cell walls ruptured and biodiesel yields were compared at different reaction times (5, 10 and 15 min). [EMIM][MeSO4] showed highest percentage cell disruption (99.73%) and biodiesel yield (36.79% per dried biomass) after 15 min of simultaneous reaction. The results demonstrated that simultaneous extraction-transesterification using ILs and microwave irradiation is a potential alternative method for biodiesel production.

  10. Continuous Production of Lipase-Catalyzed Biodiesel in a Packed-Bed Reactor: Optimization and Enzyme Reuse Study

    OpenAIRE

    Hsiao-Ching Chen; Hen-Yi Ju; Tsung-Ta Wu; Yung-Chuan Liu; Chih-Chen Lee; Cheng Chang; Yi-Lin Chung; Chwen-Jen Shieh

    2010-01-01

    An optimal continuous production of biodiesel by methanolysis of soybean oil in a packed-bed reactor was developed using immobilized lipase (Novozym 435) as a catalyst in a tert-butanol solvent system. Response surface methodology (RSM) and Box-Behnken design were employed to evaluate the effects of reaction temperature, flow rate, and substrate molar ratio on the molar conversion of biodiesel. The results showed that flow rate and temperature have significant effects on the percentage of mol...

  11. Biodiesel Fuel Quality and the ASTM Standard

    Science.gov (United States)

    Biodiesel is usually produced from vegetable oils, animal fats and used cooking oils with alternative feedstocks such as algae receiving increasing interest. The transesterification reaction which produces biodiesel also produces glycerol and proceeds stepwise via mono- and diacylglycerol intermedia...

  12. Performance and emission characteristics of double biodiesel blends with diesel

    OpenAIRE

    Kuthalingam Arun Balasubramanian; Asokan Guruprasath; Marta Vivar; Skryabin Igor; Karuppian Srithar

    2013-01-01

    Recent research on biodiesel focused on performance of single biodiesel and its blends with diesel. The present work aims to investigate the possibilities of the application of mixtures of two biodiesel and its blends with diesel as a fuel for diesel engines. The combinations of Pongamia pinnata biodiesel, Mustard oil biodiesel along with diesel (PMD) and combinations of Cotton seed biodiesel, Pongamia pinnata biodiesel along with diesel (CPD) are taken for the experimental analysis. Ex...

  13. Utilization of biodiesel by-products for mosquito control.

    Science.gov (United States)

    Pant, Megha; Sharma, Satyawati; Dubey, Saurabh; Naik, Satya Narayan; Patanjali, Phool Kumar

    2016-03-01

    The current paper has elaborated the efficient utilization of non-edible oil seed cakes (NEOC), by-products of the bio-diesel extraction process to develop a herbal and novel mosquitocidal composition against the Aedes aegypti larvae. The composition consisted of botanical active ingredients, inerts, burning agents and preservatives; where the botanical active ingredients were karanja (Pongamia glabra) cake powder and jatropha (Jatropha curcas) cake powder, products left after the extraction of oil from karanja and jatropha seed. The percentage mortality value recorded for the combination with concentration, karanja cake powder (20%) and jatropha cake powder (20%), 1:1 was 96%. The coil formulations developed from these biodiesel by-products are of low cost, environmentally friendly and are less toxic than the synthetic active ingredients.

  14. Quality Assessment of Biodiesel Blends Proposed by the New Mexican Policy Framework

    Directory of Open Access Journals (Sweden)

    Marcos A. Coronado

    2017-05-01

    Full Text Available Nowadays, biodiesel is being promoted worldwide as a sustainable and alternative to diesel fuel. However, there is still a lack of a biodiesel market in Mexico. Hence, a new initiative to reform the Mexican biofuels framework by decree includes the production and use of biodiesel. This regulation can ensure and contribute to the development of the biodiesel market in Mexico. The initiative proposes to start from the B5.8 blend by the end of 2017 and reach the B10 by 2020. Therefore, the objective of the present work was the quality assessment of biodiesel blends proposed by the new Mexican policy framework. The techniques applied were Fourier transform infrared (FT-IR spectroscopy, X-ray fluorescence analysis, scanning electron microscopy analysis, viscosity, higher heating value, thermogravimetric analysis, refractive index, acid number, specific gravity, flash point, and copper strip corrosion based on ASTM standards. The results indicate that the biodiesel and its blends B5.8 and B10 fulfilled relevant quality specifications established in the ASTM D6751 and EN14214 standards for fuels. However, the fuel blends presented a higher heating value (HHV diminution. The experimental HHV percentages decrease for the mandatory mixtures compared to diesel were 2.29% (B10, and 0.29% (B5.8.

  15. Análisis Químico de Mezclas Biodiesel de Aceite de Cocina Usado y Diesel por Espectroscopia Infrarroja Chemical Analysis of Mixtures of Biodiesel from Used Cooking Oil and Diesel by Infrared Spectroscopy

    Directory of Open Access Journals (Sweden)

    Jennifer J Lafont

    2011-01-01

    Full Text Available Se propone un método eficiente para determinar los porcentajes óptimos de mezclas biodiesel de aceite usado y diesel, para uso automotor. El procedimiento consiste en recolección del aceite usado, limpieza de residuos, y obtención del biodiesel mediante una reacción de transesterificación, con diferentes proporciones molares metanol/aceite . Las muestras fueron analizadas por espectroscopia infrarroja. Se encontró que una proporción metanol/aceite de 1:8 presentó mayor rendimiento en la obtención de biodiesel. Los espectros de infrarrojo mostraron el incremento del máximo de carbonilo de los esteres metílicos al aumentar las concentraciones de biodiesel en las mezcla biodiesel+diesel. Se concluye que la técnica usada cumple con la ley de Beer-Lambert y es adecuada para cuantificar este tipo de mezclas.An efficient method to determine the optimum percentages of blends biodiesel from used oil and diesel for automotive use, is proposed. The procedure consists of recollection of used frying oil, residue cleaning and synthesis of biodiesel by a transesterification reaction with different molar proportions of methanol/oil. The samples were analyzed by infrared spectroscopy. It was found that a ratio methanol/oil of 1:8 showed higher performance in the production of biodiesel. The infrared spectra showed an increase in the carbonyl peak of the methyl esters with the increase of the concentration of biodiesel in the mixtures biodiesel+diesel. It is concluded that proposed technique complies with the Beer-Lambert law and it is a good method to quantify these types of mixtures.

  16. Biodiesel Production from Spent Coffee Grounds

    Science.gov (United States)

    Blinová, Lenka; Bartošová, Alica; Sirotiak, Maroš

    2017-06-01

    The residue after brewing the spent coffee grounds is an oil-containing waste material having a potential of being used as biodiesel feedstock. Biodiesel production from the waste coffee grounds oil involves collection and transportation of coffee residue, drying, oil extraction, and finally production of biodiesel. Different methods of oil extraction with organic solvents under different conditions show significant differences in the extraction yields. In the manufacturing of biodiesel from coffee oil, the level of reaction completion strongly depends on the quality of the feedstock oil. This paper presents an overview of oil extraction and a method of biodiesel production from spent coffee grounds.

  17. Recent trends in biodiesel production

    Directory of Open Access Journals (Sweden)

    Meisam Tabatabaei

    2015-09-01

    Full Text Available This article fully discusses the recent trends in the production of one the most attractive types of biofuels, i.e., biodiesel.with a focus on the existing obstacles for its large scale production. Moreover, recent innovations/improvements under three categories of upstream, mainstream, and downstream processes are also presented. Upstream strategies are mainly focused on seeking more sustainable oil feedstocks and/or enhancing the quality of waste-oriented ones. The mainstream strategies section highlights the numerous attempts made to enhance agitation efficiency including chemical and/or mechanical strategies. Finally, the innovative downstream strategies basically dealing with 1 separation of biodiesel and glycerin, 2 purification of biodiesel and glycerin, and 3 improving the characteristics of the produced fuel, are comprehensively reviewed.

  18. Biodiesel production : process and characterization

    OpenAIRE

    2010-01-01

    Resumo: O biodiesel (ésteres) é um combustível que pode ser produzido a partir de óleos vegetais, gorduras animais e óleo de origem microbiana (algas, fungos e bactérias). As matérias-primas são convertidas em biodiesel por meio de uma reação química envolvendo álcool e catalisador. Esta reação é chamada de transesterificação ou etanólise, caso o álcool for o etanol. Neste trabalho, foi realizada a produção de biodiesel utilizando os seguintes sistemas: reator em batelada, processo de destila...

  19. Palm biodiesel: performance of a agricultural tractor in function of differents storage periods; Biodiesel de dende: desempenho de trator agricola em funcao de diferentes periodos de armazenamento

    Energy Technology Data Exchange (ETDEWEB)

    Lopes, Afonso; Oliveira, Melina C.J. [Universidade Estadual Paulista Julio de Mesquita Filho (FCAV/UNESP), Jaboticabal, SP (Brazil). Fac. de Ciencias Agrarias e Veterinarias. Dept. de Engenharia Rural], email: fonso@fcav.unesp.br; Lima, Leomar P. [Instituto Federal do Triangulo Mineiro (IFTM), Uberlandia, MG (Brazil); Camara, Felipe P. [Universidade Federal do Ceara (UFC), Cariri, CE (Brazil)

    2011-07-01

    The use of biofuel for replacement of oil in internal combustion engines is an alternative to seek the reduction of harmful effects that the use of these fuels question to the environment. The objective of this work was to evaluate the performance of a tractor in the light of storage time of the biodiesel of palm oil. The experiment was conducted in the Laboratory of machinery and agricultural mechanization of Rural Engineering Department of UNESP, Jaboticabal, SP. In this study, -if a tractor Valtra BM 110 4x2 TDA 74 kW (100 cv) in engine 2.350 rpm. The experimental design was completely randomized, in factorial scheme 5x3, with 3 repetitions. The first factor represents 5 proportions of mixing biodiesel for diesel (B0, B5, B25, B 50 and B100, that the number indicates the percentage of biodiesel for diesel) and three storage times in condition storage environment in a rural property (0, 3 and 6 months). The mixtures were prepared hours before the test. The results showed that the storage time did not influence the performance of the tractor, occurring biodiesel specific increase in consumption from the proportion of 25% (B25) mixture of biodiesel for diesel. (author)

  20. Montana BioDiesel Initiative

    Energy Technology Data Exchange (ETDEWEB)

    Peyton, Brent [Montana State Univ., Bozeman, MT (United States)

    2017-01-29

    This initiative funding helped put Montana State University (MSU) in a position to help lead in the development of biodiesel production strategies. Recent shortages in electrical power and rising gasoline prices have focused much attention on the development of alternative energy sources that will end our dependence on fossil fuels. In addition, as the concern for environmental impact of utilizing fossil fuels increases, effective strategies must be implemented to reduce emissions or the increased regulations imposed on fossil fuel production will cause economic barriers for their use to continue to increase. Biodiesel has been repeatedly promoted as a more environmentally sound and renewable source of fuel and may prove to be a highly viable solution to provide, at the least, a proportion of our energy needs. Currently there are both practical and economic barriers to the implementation of alternative energy however the advent of these technologies is inevitable. Since many of the same strategies for the storage, transport, and utilization of biodiesel are common with that of fossil fuels, the practical barriers for biodiesel are comparatively minimal. Strategies were developed to harness the CO2 as feedstock to support the growth of biodiesel producing algae. The initiative funding led to the successful funding of highly rated projects in competitive national grant programs in the National Science Foundation and the Department of Energy. This funding put MSU in a key position to develop technologies to utilize the CO2 rich emissions produced in fossil fuel utilization and assembled world experts concerning the growth characteristics of photosynthetic microorganisms capable of producing biodiesel.

  1. A review of chromatographic characterization techniques for biodiesel and biodiesel blends.

    Energy Technology Data Exchange (ETDEWEB)

    Pauls, R. E. (Chemical Sciences and Engineering Division)

    2011-05-01

    This review surveys chromatographic technology that has been applied to the characterization of biodiesel and its blends. Typically, biodiesel consists of fatty acid methyl esters produced by transesterification of plant or animal derived triacylglycerols. Primary attention is given to the determination of trace impurities in biodiesel, such as methanol, glycerol, mono-, di-, and triacylglycerols, and sterol glucosides. The determination of the fatty acid methyl esters, trace impurities in biodiesel, and the determination of the biodiesel content of commercial blends of biodiesel in conventional diesel are also addressed.

  2. Biodiesel production with microalgae as feedstock: from strains to biodiesel.

    Science.gov (United States)

    Gong, Yangmin; Jiang, Mulan

    2011-07-01

    Due to negative environmental influence and limited availability, petroleum-derived fuels need to be replaced by renewable biofuels. Biodiesel has attracted intensive attention as an important biofuel. Microalgae have numerous advantages for biodiesel production over many terrestrial plants. There are a series of consecutive processes for biodiesel production with microalgae as feedstock, including selection of adequate microalgal strains, mass culture, cell harvesting, oil extraction and transesterification. To reduce the overall production cost, technology development and process optimization are necessary. Genetic engineering also plays an important role in manipulating lipid biosynthesis in microalgae. Many approaches, such as sequestering carbon dioxide from industrial plants for the carbon source, using wastewater for the nutrient supply, and maximizing the values of by-products, have shown a potential for cost reduction. This review provides a brief overview of the process of biodiesel production with microalgae as feedstock. The methods associated with this process (e.g. lipid determination, mass culture, oil extraction) are also compared and discussed.

  3. Study on Carbonyl Emissions of Diesel Engine Fueled with Biodiesel

    National Research Council Canada - National Science Library

    Ruina Li; Zhong Wang; Guangju Xu

    2017-01-01

      Biodiesel is a kind of high-quality alternative fuel of diesel engine. In this study, biodiesel and biodiesel/diesel blend were used in a single cylinder diesel engine to study the carbonyl emissions...

  4. [Progress and prospect of biodiesel industry in China].

    Science.gov (United States)

    Li, Yang; Zeng, Jing; Du, Wei; Liu, Dehua

    2015-06-01

    The development of biodiesel and production feedstock in China was introduced, and the biodiesel production technologies as well as corresponding representative enterprises were reviewed. In addition, the development prospect of biodiesel industry in China was addressed.

  5. Cultivating Microalgae in Domestic Wastewater for Biodiesel Production

    Directory of Open Access Journals (Sweden)

    Soha S.M. MOSTAFA

    2012-02-01

    Full Text Available The objective of this study was to evaluate the growth of nine species of microalgae (green and blue green microalgae on domestic waste water samples obtained from Zenein Waste Water Treatment Plant (ZWWTP, Giza governorate, Egypt. The species were cultivated in different kind of waste water; before treatment; after sterilization; with nutrients with sterilization and with nutrients without sterilization. The experiment was conducted in triplicate and cultures were incubated at 25�1�C under continuous shaking (150 rpm and illumination (2000 Lux for 15 days. pH, electric conductivity (EC, optical density (OD , dry weight (DW, were done at the time of incubation and at the end of experiment, in addition to determine the percentage of lipid and biodiesel. The data revealed that, domestic waste water with nutrient media (T3 was promising for cultivation of five algal species when compared with conventional media, Moreover, domestic waste water after sterilization (T2 was selected media for cultivation of Oscillatoria sp and Phormedium sp. However, T1 media (waste water without treatment was the promising media for cultivation of Nostoc humifusum. The biodiesel produced from algal species cultivated in waste water media ranged from 3.8 to 11.80% when compared with the conventional method (3.90 to 12.52%. The results of this study suggest that growing algae in nutrient rich media offers a new option of applying algal process in ZWWTP to mange the nutrient load for growth and valuable biodiesel feedstock production.

  6. Cultivating Microalgae in Domestic Wastewater for Biodiesel Production

    Directory of Open Access Journals (Sweden)

    Soha S.M. MOSTAFA

    2012-02-01

    Full Text Available The objective of this study was to evaluate the growth of nine species of microalgae (green and blue green microalgae on domestic waste water samples obtained from Zenein Waste Water Treatment Plant (ZWWTP, Giza governorate, Egypt. The species were cultivated in different kind of waste water; before treatment; after sterilization; with nutrients with sterilization and with nutrients without sterilization. The experiment was conducted in triplicate and cultures were incubated at 251C under continuous shaking (150 rpm and illumination (2000 Lux for 15 days. pH, electric conductivity (EC, optical density (OD , dry weight (DW, were done at the time of incubation and at the end of experiment, in addition to determine the percentage of lipid and biodiesel. The data revealed that, domestic waste water with nutrient media (T3 was promising for cultivation of five algal species when compared with conventional media, Moreover, domestic waste water after sterilization (T2 was selected media for cultivation of Oscillatoria sp and Phormedium sp. However, T1 media (waste water without treatment was the promising media for cultivation of Nostoc humifusum. The biodiesel produced from algal species cultivated in waste water media ranged from 3.8 to 11.80% when compared with the conventional method (3.90 to 12.52%. The results of this study suggest that growing algae in nutrient rich media offers a new option of applying algal process in ZWWTP to mange the nutrient load for growth and valuable biodiesel feedstock production.

  7. Biodiesel via hydrotreating of fat

    DEFF Research Database (Denmark)

    Madsen, Anders Theilgaard; Ahmed, El Hadi; Christensen, Claus Hviid

    Biodiesel production via transesterification to fatty acid alkyl esters is rising rapidly worldwide due to the limited availability of fossil resources and the problems of global warming. Often, however, the use of 2nd-generation feedstock like animal waste fat and trap greases etc. is made...

  8. Biodiesel production using heterogenous catalyst

    Science.gov (United States)

    The current transesterification of triacylglycerides (TAG) to produce biodiesel is based on the homogenous catalyst method using strong base such as hydroxides or methoxides. However, this method results in a number of problems: (1) acid pre-treatment is required of feedstocks high in free fatty ac...

  9. New regulatory landmark for biodiesel use; Novo marco regulatorio para usos de biodiesel

    Energy Technology Data Exchange (ETDEWEB)

    Araujo, Rosangela Moreira de [Agencia Nacional do Petroleo, Gas Natural e Biocombustiveis (ANP), Rio de Janeiro, RJ (Brazil)

    2008-07-01

    The Brazilian Biodiesel Production and Use of Biodiesel - PNPB, made possible the insert of Biodiesel in the Brazilian energy matrix. The National Agency of the Petroleum, Natural Gas and Biofuels - ANP was responsible to create the outline regulatory that established the rules for entrance and commercialization of this new fuel in the country. This work seeks to present the effects of the implantation of the new relative rules to the biodiesel use. (author)

  10. Chemical alternative to the energetic use of biodiesel; Chemische Alternativen zur energetischen Nutzung von Biodiesel

    Energy Technology Data Exchange (ETDEWEB)

    Warwel, S; Ruesch genannt Klaas, M.; Harperscheid, M. [Bundesanstalt fuer Getreide-, Kartoffel- und Fettforschung, Muenster (Germany). Inst. fuer Biochemie und Technologie der Fette - H.P. Kaufmann-Inst.

    1996-12-31

    Biodiesel is environment-friendly, but much more costly to produce than `normal` diesel fuel. Higher economic efficiency can be achieved by using biodiesel as a chemical feedstock instead. Tenside and polymers offer a wide range of applications. (orig) [Deutsch] Biodiesel ist ein umweltfreundlicher Kraftstoff, jedoch in der Herstellung deutlich teurer als Mineraloel-Dieselkraftstoff. Eine signifikant hoehere Wertschoepfung koennte errreicht werden, wenn Biodiesel nicht im Kraftstoffsektor, sondern als chemischer Rohstoff verwendet wird. Tenside und Polymere sind hierbei grossvolumige Einsatzbereiche. (orig)

  11. Spray and combustion visualization of bio-diesel in a direct injection diesel engine

    Directory of Open Access Journals (Sweden)

    Pan Jianfeng

    2013-01-01

    Full Text Available By using the self-developed dynamic visualization photographic setup, this article investigated some major factors affecting the spray and combustion process of diesel engine fueled by biodiesel. The experimental results show: With the increase of biodiesel percentage, fuel injection advances slightly, the ignition delay becomes shorter and the duration of combustion lengthens. Engine speed has little effect on the spray. However, the combustion rate is increased and the burning time becomes shorter with the increase of engine speed, although the duration of combustion in terms of crank angle increases. With the increase of needle opening pressure, both the spray cone angle and the spray penetration of biodiesel increases, the atomization of spray improves, the ignition delay and the duration of combustion becomes shorter, the peak pressure increases.

  12. Percentage Energy from Fat Screener: Overview

    Science.gov (United States)

    A short assessment instrument to estimate an individual's usual intake of percentage energy from fat. The foods asked about on the instrument were selected because they were the most important predictors of variability in percentage energy.

  13. Solving Problems with the Percentage Bar

    Science.gov (United States)

    van Galen, Frans; van Eerde, Dolly

    2013-01-01

    At the end of primary school all children more of less know what a percentage is, but yet they often struggle with percentage problems. This article describes a study in which students of 13 and 14 years old were given a written test with percentage problems and a week later were interviewed about the way they solved some of these problems. In a…

  14. Thermoanalytical characterization of castor oil biodiesel

    Energy Technology Data Exchange (ETDEWEB)

    Conceicao, Marta M.; Fernandes, Valter J. [Universidade Federal do Rio Grande do Norte, Departamento de Quimica, Laboratorio de Combustiveis, Natal, RN, Lagoa Nova, CEP 59072970 (Brazil); Candeia, Roberlucia A.; Bezerra, Aline F.; Souza, Antonio G. [Universidade Federal da Paraiba, Departamento Quimica, Joao Pessoa, PB (Brazil); Silva, Fernando C. [Universidade Federal do Maranhao, Sao Luis, Maranhao (Brazil)

    2007-06-15

    The castor oil seed has 47-49% of oil. Biodiesel obtained from castor oil has a lower cost compared to the ones obtained from other oils, as due its solvability in alcohol transesterification occurs without heating. The use of biodiesel will allow a reduction on the consumption of petroleum-derived fuels minimizing the harmful effects on the environment. This work wants to provide a thermoanalytical and physical-chemistry characterization of castor oil and biodiesel. Biodiesel was obtained with methyl alcohol and characterized through several techniques. Gas chromatography indicated methyl ester content of 97.7%. The volatilization of biodiesel starts and finishes under inferior temperatures than the beginning and final volatilization temperatures of castor oil. Biodiesel data are very close to the volatilization temperatures of conventional diesel. (author)

  15. Genetic engineering of microorganisms for biodiesel production.

    Science.gov (United States)

    Lin, Hui; Wang, Qun; Shen, Qi; Zhan, Jumei; Zhao, Yuhua

    2013-01-01

    Biodiesel, as one type of renewable energy, is an ideal substitute for petroleum-based diesel fuel and is usually made from triacylglycerides by transesterification with alcohols. Biodiesel production based on microbial fermentation aiming to establish more efficient, less-cost and sustainable biodiesel production strategies is under current investigation by various start-up biotechnology companies and research centers. Genetic engineering plays a key role in the transformation of microbes into the desired cell factories with high efficiency of biodiesel production. Here, we present an overview of principal microorganisms used in the microbial biodiesel production and recent advances in metabolic engineering for the modification required. Overexpression or deletion of the related enzymes for de novo synthesis of biodiesel is highlighted with relevant examples.

  16. Biodiesel research progress 1992-1997

    Energy Technology Data Exchange (ETDEWEB)

    Tyson, K.S. [ed.

    1998-04-01

    The US Department of Energy (DOE) Office of Fuels Development began evaluating the potential of various alternative fuels, including biodiesel, as replacement fuels for traditional transportation fuels. Biodiesel is derived from a variety of biological materials from waste vegetable grease to soybean oil. This alkyl ester could be used as a replacement, blend, or additive to diesel fuel. This document is a comprehensive summary of relevant biodiesel and biodiesel-related research, development demonstration, and commercialization projects completed and/or started in the US between 1992 and 1997. It was designed for use as a reference tool to the evaluating biodiesel`s potential as a clean-burning alternative motor fuel. It encompasses, federally, academically, and privately funded projects. Research projects are presented under the following topical sections: Production; Fuel characteristics; Engine data; Regulatory and legislative activities; Commercialization activities; Economics and environment; and Outreach and education.

  17. Correlating Engine NOx Emission with Biodiesel Composition

    Science.gov (United States)

    Jeyaseelan, Thangaraja; Mehta, Pramod Shankar

    2016-06-01

    Biodiesel composition comprising of saturated and unsaturated fatty acid methyl esters has a significant influence on its properties and hence the engine performance and emission characteristics. This paper proposes a comprehensive approach for composition-property-NOx emission analysis for biodiesel fuels and highlights the pathways responsible for such a relationship. Finally, a procedure and a predictor equation are developed for the assessment of biodiesel NOx emission from its composition details.

  18. Solving Problems with The Percentage Bar

    Directory of Open Access Journals (Sweden)

    Frans van Galen

    2013-01-01

    Full Text Available At the end of primary school all children more of less know what apercentage is, but yet they often struggle with percentage problems.This article describes a study in which students of 13 and 14 years old were given a written test with percentage problems and a week later were interviewed about the way they solved some of these problems. In a teaching experiment the students were then taught the use of the percentage bar. Although the teaching experiment was very short - just one lesson - the results confirm that the percentage bar is a powerful model that deserves a central place in the teaching of percentages

  19. Genetic Engineering Strategies for Enhanced Biodiesel Production.

    Science.gov (United States)

    Hegde, Krishnamoorthy; Chandra, Niharika; Sarma, Saurabh Jyoti; Brar, Satinder Kaur; Veeranki, Venkata Dasu

    2015-07-01

    The focus on biodiesel research has shown a tremendous growth over the last few years. Several microbial and plant sources are being explored for the sustainable biodiesel production to replace the petroleum diesel. Conventional methods of biodiesel production have several limitations related to yield and quality, which led to development of new engineering strategies to improve the biodiesel production in plants, and microorganisms. Substantial progress in utilizing algae, yeast, and Escherichia coli for the renewable production of biodiesel feedstock via genetic engineering of fatty acid metabolic pathways has been reported in the past few years. However, in most of the cases, the successful commercialization of such engineering strategies for sustainable biodiesel production is yet to be seen. This paper systematically presents the drawbacks in the conventional methods for biodiesel production and an exhaustive review on the present status of research in genetic engineering strategies for production of biodiesel in plants, and microorganisms. Further, we summarize the technical challenges need to be tackled to make genetic engineering technology economically sustainable. Finally, the need and prospects of genetic engineering technology for the sustainable biodiesel production and the recommendations for the future research are discussed.

  20. Oxidation stability and risk evaluation of biodiesel

    Directory of Open Access Journals (Sweden)

    Hoshino Takashi

    2007-01-01

    Full Text Available This review describes oxidation and thermal stability and hazardous possibility of biodiesel by auto-oxidation. As it can be distributed using today’s infrastructure biodisel production has increased especially in the European Union. Biodiesel has many surpassing properties as an automotive fuel. Biodiesel is considered safer than diesel fuel because of the high flash point, but it has oxygen and double bond(s. Fatty acid methyl esters are more sensitive to oxidative degradation than fossil diesel fuel. The ability of producing peroxides is rather high, therefore we should care of handling of biodiesel.

  1. Solving Problems with The Percentage Bar

    Directory of Open Access Journals (Sweden)

    Frans van Galen

    2013-01-01

    Full Text Available At the end of primary school all children more of less know what a percentage is, but yet they often struggle with percentage problems. This article describes a study in which students of 13 and 14 years old were given a written test with percentage problems and a week later were interviewed about the way they solved some of these problems. In a teaching experiment the students were then taught the use of the percentage bar. Although the teaching experiment was very short - just one lesson  -  the results confirm that the percentage bar is a powerful model that deserves a central place in the teaching of percentages.Keywords: percentage, model, design research DOI: http://dx.doi.org/10.22342/jme.4.1.558.1-8

  2. Purification of crude biodiesel using dry washing and membrane technologies

    Directory of Open Access Journals (Sweden)

    I.M. Atadashi

    2015-12-01

    Full Text Available Purification of crude biodiesel is mandatory for the fuel to meet the strict international standard specifications for biodiesel. Therefore, this paper carefully analyzed recently published literatures which deal with the purification of biodiesel. As such, dry washing technologies and the most recent membrane biodiesel purification process have been thoroughly examined. Although purification of biodiesel using dry washing process involving magnesol and ion exchange resins provides high-quality biodiesel fuel, considerable amount of spent absorbents is recorded, besides the skeletal knowledge on its operating process. Further, recent findings have shown that biodiesel purification using membrane technique could offer high-quality biodiesel fuel with less wastewater discharges. Thus, both researchers and industries are expected to benefit from the development of membrane technique in purifying crude biodiesel. As well biodiesel purification via membranes has been shown to be environmentally friendly. For these reasons, it is important to explore and exploit membrane technology to purify crude biodiesel.

  3. Production and characterization of biodiesel using palm kernel oil; fresh and recovered from spent bleaching earth

    Directory of Open Access Journals (Sweden)

    Abiodun Aladetuyi

    2014-12-01

    Full Text Available Palm kernel oil (PKO was recovered from spent bleaching earth with a yield of 16 %, using n-hexane while the fresh oil was extracted from palm kernel with n-hexane and a yield of 40.23% was obtained. These oils were trans-esterified with methanol under the same reaction conditions: 100 oC, 2 h reaction time, and oil-methanol ratio of 5:1 (w/v. The cocoa pod ash (CPA was compared with potassium hydroxide (KOH as catalyst. The percentage yields of biodiesel obtained from PKO catalysed by CPA and KOH were 94 and 90%, respectively. While the yields achieved using the recovered oil catalysed by CPA and KOH were measured at 86 and 81.20 %. The physico-chemical properties of the biodiesel produced showed that the flash point, viscosity, density, ash content, percentage carbon content, specific gravity and the acid value fell within American Society for Testing and Materials (ASTM specifications for biodiesel. The findings of this study suggest that agricultural residues such as CPA used in this study could be explored as alternatives for KOH catalyst for biodiesel production.

  4. Continuous Low Cost Transesterification Process for the Production of Coconut Biodiesel

    Directory of Open Access Journals (Sweden)

    Chandra P. Singh

    2010-01-01

    Full Text Available Biodiesel, or alkyl ester, is an alternative renewable, biodegradable, and non-toxic diesel fuel produced by the catalytic transesterification of vegetable oil. Here we characterize a system for continuous transesterification of vegetable oil using five continuous stirring tank reactors (5CSTRs. We tested residence times of 16–43min, stirring speeds of 200–800rpm, a catalyst concentration (KOH of 0.25–1 wt% of oil (in gram, different total flow rates of the oil and MeOH, and on the production performance of the 5 stage continuous reactor for transesterification of vegetable oil. Using a molar ratio of oil:methanol of 1:7 and a reaction temperature of 65 °C, we show that a high stirring speed increased the reaction rate, but an excessive stir speed decreased the reaction rate and conversion to biodiesel. Furthermore, a higher catalyst percentage significantly increased the reaction rate and production capacity. A catalyst percentage of 1 wt% of oil gave the best conversion; 99.04 ± 0.05%. The resulting biodiesel esters were characterized for their physical and fuel properties including density, viscosity, iodine volume, acid volume, cloud point, pure point, gross heat of combustion, and volatility. The purity and conversion of the biodiesel was analyzed by HPLC.

  5. Biodiesel/Cummins CRADA Report

    Science.gov (United States)

    2014-07-01

    nitrile rubber , natural rubber ) that are commonly used for hoses, seals and gaskets, and may degrade them to the point where they fail. Failure can...cloud point (33.5°F for the test fuel). Gelling can be prevented through fuel management (e.g., fuel additives, shifting to a diesel/biodiesel blend ...Engineering CG Coast Guard CNG Compressed Natural Gas CO Carbon monoxide CO2 Carbon dioxide COG Course over ground CRADA Cooperative Research and

  6. Mississippi State Biodiesel Production Project

    Energy Technology Data Exchange (ETDEWEB)

    Rafael Hernandez; Todd French; Sandun Fernando; Tingyu Li; Dwane Braasch; Juan Silva; Brian Baldwin

    2008-03-20

    Biodiesel is a renewable fuel conventionally generated from vegetable oils and animal fats that conforms to ASTM D6751. Depending on the free fatty acid content of the feedstock, biodiesel is produced via transesterification, esterification, or a combination of these processes. Currently the cost of the feedstock accounts for more than 80% of biodiesel production cost. The main goal of this project was to evaluate and develop non-conventional feedstocks and novel processes for producing biodiesel. One of the most novel and promising feedstocks evaluated involves the use of readily available microorganisms as a lipid source. Municipal wastewater treatment facilities (MWWTF) in the USA produce (dry basis) of microbial sludge annually. This sludge is composed of a variety of organisms, which consume organic matter in wastewater. The content of phospholipids in these cells have been estimated at 24% to 25% of dry mass. Since phospholipids can be transesterified they could serve as a ready source of biodiesel. Examination of the various transesterification methods shows that in situ conversion of lipids to FAMEs provides the highest overall yield of biodiesel. If one assumes a 7.0% overall yield of FAMEs from dry sewage sludge on a weight basis, the cost per gallon of extracted lipid would be $3.11. Since the lipid is converted to FAMEs, also known as biodiesel, in the in Situ extraction process, the product can be used as is for renewable fuel. As transesterification efficiency increases the cost per gallon drops quickly, hitting $2.01 at 15.0% overall yield. An overall yield of 10.0% is required to obtain biodiesel at $2.50 per gallon, allowing it to compete with soybean oil in the marketplace. Twelve plant species with potential for oil production were tested at Mississippi State, MS. Of the species tested, canola, rapeseed and birdseed rape appear to have potential in Mississippi as winter annual crops because of yield. Two perennial crops were investigated, Chinese

  7. Mississippi State Biodiesel Production Project

    Energy Technology Data Exchange (ETDEWEB)

    Rafael Hernandez; Todd French; Sandun Fernando; Tingyu Li; Dwane Braasch; Juan Silva; Brian Baldwin

    2008-03-20

    Biodiesel is a renewable fuel conventionally generated from vegetable oils and animal fats that conforms to ASTM D6751. Depending on the free fatty acid content of the feedstock, biodiesel is produced via transesterification, esterification, or a combination of these processes. Currently the cost of the feedstock accounts for more than 80% of biodiesel production cost. The main goal of this project was to evaluate and develop non-conventional feedstocks and novel processes for producing biodiesel. One of the most novel and promising feedstocks evaluated involves the use of readily available microorganisms as a lipid source. Municipal wastewater treatment facilities (MWWTF) in the USA produce (dry basis) of microbial sludge annually. This sludge is composed of a variety of organisms, which consume organic matter in wastewater. The content of phospholipids in these cells have been estimated at 24% to 25% of dry mass. Since phospholipids can be transesterified they could serve as a ready source of biodiesel. Examination of the various transesterification methods shows that in situ conversion of lipids to FAMEs provides the highest overall yield of biodiesel. If one assumes a 7.0% overall yield of FAMEs from dry sewage sludge on a weight basis, the cost per gallon of extracted lipid would be $3.11. Since the lipid is converted to FAMEs, also known as biodiesel, in the in Situ extraction process, the product can be used as is for renewable fuel. As transesterification efficiency increases the cost per gallon drops quickly, hitting $2.01 at 15.0% overall yield. An overall yield of 10.0% is required to obtain biodiesel at $2.50 per gallon, allowing it to compete with soybean oil in the marketplace. Twelve plant species with potential for oil production were tested at Mississippi State, MS. Of the species tested, canola, rapeseed and birdseed rape appear to have potential in Mississippi as winter annual crops because of yield. Two perennial crops were investigated, Chinese

  8. Peningkatan Kinerja Mesin Diesel dengan Produksi Biodiesel dari Kelapa (Coconut Nufera dan Unjuk Kinerjanya Berbasis Transesterifikasi dengan Sistim Injeksi Langsung

    Directory of Open Access Journals (Sweden)

    Soni Sisbudi Harsono

    2015-12-01

    Abstract. Use of biodiesel especially from CPO has not been popularly used either for transportation nor for industrial fuel, while in foreign countries, it has been used for transportation fuel even just be blended. As the available of fosil fuel ten to decrease, the use of a renewable fuel biodiesel will be promising. This study aimed to evaluate the performance of amall diesel engine using biodiesel as fuel source. Performance test of small diesel engine using biodiesel was conducted in the laboratory by using engine dynamometer. The results shown that mixing 30% of biodiesel and 70% fosil fuel (petro diesel gave the best performance among other percentage mixture. Mixing 30% of biodiesel and 70% fosil fuel gave maximum power 5.36 HP at 2190 rpm and maximum torque 1.748 Nm. Its lower comparing than pure petro diesel that gave 5.41 HP at 2200 rpm and maximum torque 1.761 Nm. The gas emission was also evaluated simultaneously. The results shown that the mixing 30%: 70% produced low carbon monoxide (CO and low hydrocarbon (HC than petro diesel.

  9. Contribution of state public policies to participation of family agriculture in the national program for production and use of biodiesel: the case of Bahia (Brazil); A contribuicao da politica estadual para viabilizar a participacao da agricultura familiar no programa nacional de producao e uso de biodiesel: o caso da Bahia

    Energy Technology Data Exchange (ETDEWEB)

    Avzaradel, Ana Carolina

    2008-03-15

    The commencement of the National Program for the Production and Use of Biodiesel (PNPB) consolidates the efforts of the Federal Government to stimulate the national production of this biofuel. The program is aimed at the insertion of small family farmers in the productive chain of biodiesel, promoting the social inclusion of this part of the population. PNPB stipulates that 2% of biodiesel must be blended with diesel oil (B2) from 2008 on, a percentage that will reach 5% in 2013. However, the demand for biodiesel created by this program may not be met if the blockages in the production chain are not removed. Since the absence of raw material is highlighted as the main obstacle to production, the main difficulties faced by family farmers were focused on. The study dealt specifically with the case of Bahia, since it already has a structured production chain of vegetable oil seeds and because of its leading position in the national production of biodiesel. Impacts resulting from the adoption of state public policies aimed at family farmers who produce vegetable oil for the production of biodiesel were analyzed. Vegetable oil supply scenarios in Bahia show that state government support for family farming benefits biodiesel production, allowing to estimate the percentage of the participation of family agriculture in Bahia to meet the targets set in the PNPB. (author)

  10. Biodiesel metílico de Dipteryx lacunifera: preparação, caracterização e efeito de antioxidantes na estabilidade à oxidação Methyl biodiesel from Dipteryx lacunifera: preparation, characterization and effect of antioxidant on the oxidation stability

    Directory of Open Access Journals (Sweden)

    Francisca Diana da Silva Araújo

    2010-01-01

    Full Text Available The objective of this work was to study the potentialities of Dipteryx lacunifera Ducke seeds oil for biodiesel production. The yield in oil was of 46.11 ± 0.37%. Methyl biodiesel was prepared by base catalyzed transesterification yielding 88.13% and percentage conversion of triglycerides to corresponding methyl ester of 89.1%. The addition of the tertiary butylhydroquinone (TBHQ, 50 ppm, butylated hydroxytoluene (BHT, 50 ppm and cashew nut shell liquid (CNSL, 2000 ppm antioxidants in the biodiesel contributed to the increase of the induction period of 2.97 h for 8.08; 6.06 and 6.02 h, respectively.

  11. Promoting Scientific and Technological Literacy: Teaching Biodiesel.

    Science.gov (United States)

    Eilks, Ingo

    2000-01-01

    Describes a unit on biodiesel from a socio-critical chemistry teaching approach aimed at improving student participation and decision making. Explores the use of biodiesel (chemically changed vegetable oils), especially in Europe. The unit proved to be successful as students participated enthusiastically and social and scientific goals were…

  12. Comparative toxicity and mutagenicity of biodiesel exhaust

    Science.gov (United States)

    Biodiesel (BD) is commercially made from the transesterification of plant and animal derived oils. The composition of biodiesel exhaust (BE) depends on the type of fuel, the blend ratio and the engine and operating conditions. While numerous studies have characterized the health ...

  13. Comparative toxicity and mutagenicity of biodiesel exhaust

    Science.gov (United States)

    Biodiesel (BD) is commercially made from the transesterification of plant and animal derived oils. The composition of biodiesel exhaust (BE) depends on the type of fuel, the blend ratio and the engine and operating conditions. While numerous studies have characterized the health ...

  14. Algal biodiesel economy and competition among bio-fuels.

    Science.gov (United States)

    Lee, D H

    2011-01-01

    This investigation examines the possible results of policy support in developed and developing economies for developing algal biodiesel through to 2040. This investigation adopts the Taiwan General Equilibrium Model-Energy for Bio-fuels (TAIGEM-EB) to predict competition among the development of algal biodiesel, bioethanol and conventional crop-based biodiesel. Analytical results show that algal biodiesel will not be the major energy source in 2040 without strong support in developed economies. In contrast, bioethanol enjoys a development advantage relative to both forms of biodiesel. Finally, algal biodiesel will almost completely replace conventional biodiesel. CO(2) reduction benefits the development of the bio-fuels industry.

  15. Biodiesel production from municipal secondary sludge.

    Science.gov (United States)

    Kumar, Manish; Ghosh, Pooja; Khosla, Khushboo; Thakur, Indu Shekhar

    2016-09-01

    In the present study, feasibility of biodiesel production from freeze dried sewage sludge was studied and its yield was enhanced by optimization of the in situ transesterification conditions (temperature, catalyst and concentration of sludge solids). Optimized conditions (45°C, 5% catalyst and 0.16g/mL sludge solids) resulted in a 20.76±0.04% biodiesel yield. The purity of biodiesel was ascertained by GC-MS, FT-IR and NMR ((1)H and (13)C) spectroscopy. The biodiesel profile obtained revealed the predominance of methyl esters of fatty acids such as oleic, palmitic, myristic, stearic, lauric, palmitoleic and linoleic acids indicating potential use of sludge as a biodiesel feedstock.

  16. Microbial recycling of glycerol to biodiesel.

    Science.gov (United States)

    Yang, Liu; Zhu, Zhi; Wang, Weihua; Lu, Xuefeng

    2013-12-01

    The sustainable supply of lipids is the bottleneck for current biodiesel production. Here microbial recycling of glycerol, byproduct of biodiesel production to biodiesel in engineered Escherichia coli strains was reported. The KC3 strain with capability of producing fatty acid ethyl esters (FAEEs) from glucose was used as a starting strain to optimize fermentation conditions when using glycerol as sole carbon source. The YL15 strain overexpressing double copies of atfA gene displayed 1.7-fold increase of FAEE productivity compared to the KC3 strain. The titer of FAEE in YL15 strain reached to 813 mg L(-1) in minimum medium using glycerol as sole carbon source under optimized fermentation conditions. The titer of glycerol-based FAEE production can be significantly increased by both genetic modifications and fermentation optimization. Microbial recycling of glycerol to biodiesel expands carbon sources for biodiesel production.

  17. Process development for scum to biodiesel conversion.

    Science.gov (United States)

    Bi, Chong-hao; Min, Min; Nie, Yong; Xie, Qing-long; Lu, Qian; Deng, Xiang-yuan; Anderson, Erik; Li, Dong; Chen, Paul; Ruan, Roger

    2015-06-01

    A novel process was developed for converting scum, a waste material from wastewater treatment facilities, to biodiesel. Scum is an oily waste that was skimmed from the surface of primary and secondary settling tanks in wastewater treatment plants. Currently scum is treated either by anaerobic digestion or landfilling which raised several environmental issues. The newly developed process used a six-step method to convert scum to biodiesel, a higher value product. A combination of acid washing and acid catalyzed esterification was developed to remove soap and impurities while converting free fatty acids to methyl esters. A glycerol washing was used to facilitate the separation of biodiesel and glycerin after base catalyzed transesterification. As a result, 70% of dried and filtered scum was converted to biodiesel which is equivalent to about 134,000 gallon biodiesel per year for the Saint Paul waste water treatment plant in Minnesota.

  18. Impacts of biodiesel production on Croatian economy

    Energy Technology Data Exchange (ETDEWEB)

    Kulisic, Biljana [Energy Institute Hrvoje Pozar, Zagreb (Croatia). Department for Renewable Energy Sources and Energy Efficiency; Mediterranean Agronomic Institute Chania - MAICh, CIHEAM - International Centre for Advanced Mediterranean Agronomic Studies (Greece); Loizou, Efstratios [Technological Education Institute (TEI) of Western Macedonia (Greece). Department of Agricultural Products Marketing and Quality Control; Rozakis, Stelios [Agricultural University of Athens (Greece). Department of Agricultural Economics and Rural Development; Segon, Velimir [Energy Institute Hrvoje Pozar, Zagreb (Croatia). Department for Renewable Energy Sources and Energy Efficiency

    2007-12-15

    The aim of this paper is to assess the direct and indirect impacts on a national economy from biodiesel (rapeseed methyl ester (RME)) production using input-output (I-O) analysis. Biodiesel development in Croatia is used as a case study. For Croatia, as for many other countries in Europe, biodiesel is a new activity not included in the existing I-O sectoral accounts. For this reason the I-O table has to be modified accordingly before being able to quantify the effect of an exogenous demand for biodiesel. Impacts in terms of output, income and employment lead to the conclusion that biodiesel production could have significant positive net impact on the Croatian economy despite the high level of subsidies for rapeseed growing. (author)

  19. 38 CFR 1.703 - Percentage estimate.

    Science.gov (United States)

    2010-07-01

    ... 38 Pensions, Bonuses, and Veterans' Relief 1 2010-07-01 2010-07-01 false Percentage estimate. 1.703 Section 1.703 Pensions, Bonuses, and Veterans' Relief DEPARTMENT OF VETERANS AFFAIRS GENERAL PROVISIONS Use of Official Mail in the Location and Recovery of Missing Children § 1.703 Percentage...

  20. Making Sense of Fractions and Percentages

    Science.gov (United States)

    Whitin, David J.; Whitin, Phyllis

    2012-01-01

    Because fractions and percentages can be difficult for children to grasp, connecting them whenever possible is beneficial. Linking them can foster representational fluency as children simultaneously see the part-whole relationship expressed numerically (as a fraction and as a percentage) and visually (as a pie chart). NCTM advocates these…

  1. Enhancement of biodiesel production from different species of algae

    Directory of Open Access Journals (Sweden)

    El-Moneim M. R. Afify, Abd

    2010-12-01

    Full Text Available Eight algal species (4 Rhodo, 1 chloro and 1 phaeophycean macroalgae, 1 cyanobacterium and 1 green microalga were used for the production of biodiesel using two extraction solvent systems (Hexane/ether (1:1, v/v and (Chloroform/ methanol (2:1, v/v. Biochemical evaluations of algal species were carried out by estimating biomass, lipid, biodiesel and sediment (glycerin and pigments percentages. Hexane/ ether (1:1, v/v extraction solvent system resulted in low lipid recoveries (2.3-3.5% dry weight while; chloroform/methanol (2: 1, v/v extraction solvent system was proved to be more efficient for lipid and biodiesel extraction (2.5 – 12.5% dry weight depending on algal species. The green microalga Dictyochloropsis splendida extract produced the highest lipid and biodiesel yield (12.5 and 8.75% respectively followed by the cyanobacterium Spirulina platensis (9.2 and 7.5 % respectively. On the other hand, the macroalgae (red, brown and green produced the lowest biodiesel yield. The fatty acids of Dictyochloropsis splendida Geitler biodiesel were determined using gas liquid chromatography. Lipids, biodiesel and glycerol production of Dictyochloropsis splendida Geitler (the promising alga were markedly enhanced by either increasing salt concentration or by nitrogen deficiency with maximum production of (26.8, 18.9 and 7.9 % respectively at nitrogen starvation condition.

    Ocho especies de algas (4 Rhodo, 1 cloro y 1 macroalgas phaeophycean, 1 cianobacteria y 1 microalga verde fueron utilizados para la producción de biodiesel utilizando dos sistemas de extracción con disolventes (hexano/éter (1:1, v/v y (Cloroformo / metanol (2:1, v/v. La evaluación bioquímica de las especies de algas se llevó a cabo mediante la estimación de los porcentajes de biomasa, de lípidos, de biodiesel y de sedimento (glicerina y pigmentos. El sistema extracción con el disolvente hexano/éter (1:1, v

  2. Characterization of beef tallow biodiesel and their mixtures with soybean biodiesel and mineral diesel fuel

    Energy Technology Data Exchange (ETDEWEB)

    Teixeira, Leonardo S.G. [Instituto de Quimica, Universidade Federal da Bahia, Campus Universitario de Ondina, 40.170-280, Salvador, Bahia (Brazil); INCT de Energia e Ambiente, Universidade Federal da Bahia, 40.170-280, Salvador, Bahia (Brazil); Couto, Marcelo B.; Filho, Miguel Andrade; Assis, Julio C.R.; Guimaraes, Paulo R.B.; Pontes, Luiz A.M.; Almeida, Selmo Q. [Departamento de Engenharia e Arquitetura, Universidade Salvador - UNIFACS, Av. Cardeal da Silva 132, 40.220-141, Salvador, Bahia (Brazil); Souza, Giancarlos S. [Instituto de Quimica, Universidade Federal da Bahia, Campus Universitario de Ondina, 40.170-280, Salvador, Bahia (Brazil); Teixeira, Josanaide S.R. [Instituto Federal de Educacao Ciencia e Tecnologica da Bahia - IFBAHIA, Rua Emidio de Morais S/N, 40.625-650, Salvador, Bahia (Brazil)

    2010-04-15

    Tallow is a raw material for biodiesel production that, due to their highly centralized generation in slaughter/processing facilities and historically low prices, may have energy, environmental, and economic advantages that could be exploited. However beef tallow biodiesel have unfavorable properties due the presence of high concentration of saturated fatty esters. One way to overcome these inconveniences is using blending procedures. In this way, blends of beef tallow biodiesel with soybean biodiesel and with conventional mineral diesel fuel were prepared and the quality of the mixtures was monitored with the purpose to study ideal proportions of the fuels. By measurement of the viscosity, density, cold filter plugging point, and flash point, it was demonstrated that tallow biodiesel can be blended with both mineral diesel and soybean biodiesel to improve the characteristics of the blend fuels, over that of the tallow. (author)

  3. Determination of the biodiesel content in diesel/biodiesel blends: a method based on fluorescence spectroscopy.

    Science.gov (United States)

    Scherer, Marisa D; Oliveira, Samuel L; Lima, Sandro M; Andrade, Luis H C; Caires, Anderson R L

    2011-05-01

    Blends of biodiesel and diesel are being used increasingly worldwide because of environmental, economic, and social considerations. Several countries use biodiesel blends with different blending limits. Therefore, it is necessary to develop or improve methods to quantify the biodiesel level in a diesel/biodiesel blend, to ensure compliance with legislation. The optical technique based on the absorption of light in the mid-infrared has been successful for this application. However, this method presents some challenges that must be overcome. In this paper, we propose a novel method, based on fluorescence spectroscopy, to determine the biodiesel content in the diesel/biodiesel blend, which allows in loco measurements by using portable systems. The results showed that this method is both practical and more sensitive than the standard optical method. © Springer Science+Business Media, LLC 2011

  4. Development of a biodiesel activity

    Directory of Open Access Journals (Sweden)

    Vermeersch Georges

    2001-01-01

    Full Text Available Nutritional values of fatty acid classes are normally discussed on the basis of their saturated, monounsaturated and polyunsaturated structures with implicit understanding that they are straight-chain. Here we focus on chlorophyll-derived phytanic and pristanic acids that are minor isoprenoid branched-chain lipid constituents in food, but of unknown nutritional value. After describing the enzyme machinery that degrades these nutrient fatty acids in the peroxisome, we show by the criteria of a mouse model and of a human cell culture model that they induce with high potency expression of enzymes responsible for beta-oxidation of straight-chain fatty acids in the peroxisome. We summarize present mechanistic knowledge on fatty acid signaling to the nucleus, which involves protein/protein contacts between peroxisome proliferator activated receptor (PPAR and fatty acid binding protein (FABP. In this signaling event the branched-chain fatty acids are the most effective ones. Finally, on the basis of this nutrient-gene interaction we discuss nutritional opportunities and therapeutic aspects of the chlorophyll-derived fatty acids. The circumstances that led to the significant French biodiesel activity will be examined: the oilseed producers and transformers actions, the partnership with the oil refiners, the government support - regulation and detaxation... The French production units will be described, followed by update scientific results highlighting the advantages of biodiesel: functionality and friendly environmentally impact. The current usage of biodiesel by oil refiners will be described and its future in the oncoming context (fuel specifications, HDI engines and post-treatment discussed.

  5. Development and validation of a generic reduced chemical kinetic mechanism for CFD spray combustion modelling of biodiesel fuels

    DEFF Research Database (Denmark)

    Cheng, Xinwei; Ng, Hoon Kiat; Ho, Jee Hou

    2015-01-01

    In this reported work, a generic reduced biodiesel chemical kinetic mechanism, with components of methyl decanoate (C11H22O2, MD), methyl-9-decenoate (C11H20O2, MD9D) and n-heptane (C7H16) was built to represent the methyl esters of coconut, palm, rapeseed and soybean. The reduced biodiesel...... and detailed mechanism predictions, for each zero-dimensional (0D) auto-ignition and extinction process using CHEMKIN-PRO. Maximum percentage errors of less than 40.0% were recorded when the predicted ignition delay (ID) periods for coconut, palm, rapeseed and soybean methyl esters were compared to those...

  6. KINETIKA TRANSESTERIFIKASI BIODIESEL JARAK PAGAR

    OpenAIRE

    Buchori Luqman; Budi Sasongko Setia

    2012-01-01

    Biodiesel were produced by trans-etherification of castor oil with alcohol in the presence of NaOH catalyst. Thereaction mechanism and model of castor oil trans-etherification isA + 3B C + 3 DA, B, C, and D were castor oil, alcohol, glycerol, and ester. The reaction rate equation was r=-dCA/dt =k1(CA)(CB)3–k2(CC)(CD)3. In this study was used two measurement method of free fat acid as the rest content ofcastor oil with SNI 01-3555-1998 and AOAC (Association of Analytical Chemist). It found tha...

  7. Biodiesel production by transesterification using immobilized lipase.

    Science.gov (United States)

    Narwal, Sunil Kumar; Gupta, Reena

    2013-04-01

    Biodiesel can be produced by transesterification of vegetable or waste oil catalysed by lipases. Biodiesel is an alternative energy source to conventional fuel. It combines environmental friendliness with biodegradability, low toxicity and renewability. Biodiesel transesterification reactions can be broadly classified into two categories: chemical and enzymatic. The production of biodiesel using the enzymatic route eliminates the reactions catalysed under acid or alkali conditions by yielding product of very high purity. The modification of lipases can improve their stability, activity and tolerance to alcohol. The cost of lipases and the relatively slower reaction rate remain the major obstacles for enzymatic production of biodiesel. However, this problem can be solved by immobilizing the enzyme on a suitable matrix or support, which increases the chances of re-usability. The main factors affecting biodiesel production are composition of fatty acids, catalyst, solvents, molar ratio of alcohol and oil, temperature, water content, type of alcohol and reactor configuration. Optimization of these parameters is necessary to reduce the cost of biodiesel production.

  8. Process Simulation of enzymatic biodiesel production -at what cost can biodiesel be made with enzymes?

    DEFF Research Database (Denmark)

    Fjerbæk Søtoft, Lene; Christensen, Knud Villy; Rong, Benguang

    The industrial production of biodiesel has had a very turbulent lifetime due to drastic changes in prices of raw materials and fossil fuels as well as regulatory changes and produced amounts of biodiesel. Biodiesel production is carried out by various forms of catalysts, but industrially only...... as well as environmental impacts of the alternative process must be evaluated towards the conventional process. With process simulation tools, an evaluation will be carried out looking at what it will cost to produce biodiesel with enzymes. Different scenarios will be taken into account with variations...

  9. Element pollution of exhaust aftertreatment systems by using biodiesel; Elementbelastungen von Abgasnachbehandlungssystemen durch Biodiesel

    Energy Technology Data Exchange (ETDEWEB)

    Stein, Hendrik; Wilharm, Thomas [ASG Analytik-Service Gesellschaft mbH, Neusaess (Germany); Winkler, Markus [DEUTZ AG, Koeln (Germany); Knuth, Hans-Walter

    2012-06-15

    Biodiesel is a particularly attractive fuel for agricultural machinery. However, the introduction of new emission standards has made the use of exhaust gas treatment systems in agricultural vehicles essential. The combination of biodiesel and exhaust gas treatment causes problems, because the biodiesel contains traces of inorganic elements. These turn into ash during the combustion process in the engine, which can result in permanent damage to the components of the exhaust gas treatment system. Deutz and ASG have investigated the impact of current grades of biodiesel on the systems in real-life operation. (orig.)

  10. Prediction of cold flow properties of Biodiesel

    Directory of Open Access Journals (Sweden)

    Parag Saxena

    2016-08-01

    Full Text Available Biodiesel being environmentally friendly is fast gaining acceptance in the market as an alternate diesel fuel. But compared to petroleum diesel it has certain limitations and thus it requires further development on economic viability and improvement in its properties to use it as a commercial fuel. The cold flow properties play a major role in the usage of biodiesel commercially as it freezes at cold climatic conditions. In the present study, cold flow properties of various types of biodiesel were estimated by using correlations available in literature. The correlations were evaluated based on the deviation between the predicted value and experimental values of cold flow properties.

  11. Innovative Canadian Process Technology For Biodiesel Production

    Energy Technology Data Exchange (ETDEWEB)

    Johar, Sangat; Norton, Kevin

    2010-09-15

    The need for increasing renewable and alternative energy in the global energy mix has been well recognized by Governments and major scientific forums to reduce climate change impact for this living planet. Biodiesel has very high potential for GHG emission reduction. An innovative process developed in Canada provides solution to mitigate the feedstock, yield and quality issues impacting the industry. The Biox process uses a continuous process which reduces reaction times, provides > 99% yield of high quality biodiesel product. The process is feedstock flexible and can use cheaper higher FFA feedstock providing a sustainable approach for biodiesel production.

  12. Aqueous solubility, dispersibility and toxicity of biodiesels

    Energy Technology Data Exchange (ETDEWEB)

    Hollebone, B.P.; Fieldhouse, B.; Lumley, T.C.; Landriault, M. [Environment Canada, Ottawa, ON (Canada). ; Doe, K.; Jackman, P. [Environment Canada, Moncton, NB (Canada). Toxicology Laboratory, Environmental Science Centre

    2007-07-01

    The renewed interest in the use of biological fuels can be attributed to that fact that feedstocks for fatty-acid ester biodiesels are renewable and can be reclaimed from waste. Although there are significant benefits to using biodiesels, their increased use leaves potential for accidental release to the environment. Therefore, their environmental behaviours and impacts must be evaluated along with the risk associated with their use. Biodiesel fuels may be made from soy oil, canola oil, reclaimed restaurant grease, fish oil and animal fat. The toxicological fate of biofuel depends on the variability of its chemical composition. This study provided an initial assessment of the aqueous fate and effects of biodiesel from a broad range of commonly available feedstocks and their blends with petroleum diesels. The study focused primarily on the fate and impact of these fuels in fresh-water. The use of chemical dispersion as a countermeasure for saltwater was also investigated. The exposure of aquatic ecosystems to biodiesels and petroleum diesel occurs via the transfer of material from the non-aqueous phase liquid (NAPL) into the aqueous phase, as both soluble and dispersed components. The aqueous solubilities of the fuels were determined from the equilibrium water-accommodated fraction concentrations. The acute toxicities of many biodiesels were reported for 3 test species used by Environment Canada for toxicological evaluation, namely rainbow trout, the water flea and a luminescent bacterium. This study also evaluated the natural potential for dispersion of the fuels in the water column in both low and high-energy wave conditions. Chemical dispersion as a potential countermeasure for biodiesel spills was also evaluated using solubility testing, acute toxicity testing, and dispersibility testing. It was shown that biodiesels have much different fates and impacts from petroleum diesels. The compounds partitioning into the water column are also very different for each

  13. Biodiesel and Other Renewable Diesel Fuels

    Energy Technology Data Exchange (ETDEWEB)

    2006-11-01

    Present federal tax incentives apply to certain types of biomass-derived diesel fuels, which in energy policy and tax laws are described either as renewable diesel or biodiesel. To understand the distinctions between these diesel types it is necessary to understand the technologies used to produce them and the properties of the resulting products. This fact sheet contains definitions of renewable and biodiesel and discusses the processes used to convert biomass to diesel fuel and the properties of biodiesel and renewable diesel fuels.

  14. Response Surface Methodology for Biodiesel Production Using Calcium Methoxide Catalyst Assisted with Tetrahydrofuran as Cosolvent

    Directory of Open Access Journals (Sweden)

    Nichaonn Chumuang

    2017-01-01

    Full Text Available The present study was performed to optimize a heterogeneous calcium methoxide (Ca(OCH32 catalyzed transesterification process assisted with tetrahydrofuran (THF as a cosolvent for biodiesel production from waste cooking oil. Response surface methodology (RSM with a 5-level-4-factor central composite design was applied to investigate the effect of experimental factors on the percentage of fatty acid methyl ester (FAME conversion. A quadratic model with an analysis of variance obtained from the RSM is suggested for the prediction of FAME conversion and reveals that 99.43% of the observed variation is explained by the model. The optimum conditions obtained from the RSM were 2.83 wt% of catalyst concentration, 11.6 : 1 methanol-to-oil molar ratio, 100.14 min of reaction time, and 8.65% v/v of THF in methanol concentration. Under these conditions, the properties of the produced biodiesel satisfied the standard requirement. THF as cosolvent successfully decreased the catalyst concentration, methanol-to-oil molar ratio, and reaction time when compared with biodiesel production without cosolvent. The results are encouraging for the application of Ca(OCH32 assisted with THF as a cosolvent for environmentally friendly and sustainable biodiesel production.

  15. The Production of Biodiesel and Bio-kerosene from Coconut Oil Using Microwave Assisted Reaction

    Science.gov (United States)

    SAIFUDDIN, N.; SITI FAZLILI, A.; KUMARAN, P.; PEI-JUA, N.; PRIATHASHINI, P.

    2016-03-01

    Biofuels including biodiesel, an alternative fuel, is renewable, environmentally friendly, non-toxic and low emissions. The raw material used in this work was coconut oil, which contained saturated fatty acids about 90% with high percentage of medium chain (C8-C12), especially lauric acid and myristic acid. The purpose of this research was to study the effect of power and NaOH catalyst in transesterification assisted by microwave for production of biofuels (biodiesel and bio-kerosene) derived from coconut oil. The reaction was performed with oil and methanol using mole ratio of 1:6, catalyst concentration of 0.6% with microwave power at 100W, 180W, 300W, 450W, 600W, and 850W. The reaction time was set at of 3, 5, 7, 10 and 15 min. The results showed that microwave could accelerate the transesterification process to produce biodiesel and bio-kerosene using NaOH catalyst. The highest yield of biodiesel was 97.17 %, or 99.05 % conversion at 5 min and 100W microwave power. Meanwhile, the bio-kerosene obtained was 65% after distillation.

  16. Biodiesel Production from Spent Fish Frying Oil Through Acid-Base Catalyzed Transesterification

    Directory of Open Access Journals (Sweden)

    Abdalrahman B. Fadhil

    2012-06-01

    Full Text Available Biodiesel fuels were prepared from a special type of frying oil namely spent fish frying oil through two step transesterification viz. acid-base catalyzed transesterification. Hydrochloric acid and potassium hydroxide with methanol were used for this purpose. The oil was pre-treated with (1.0 wt% HCl and methanol to reduce free fatty acids content of the oil. Then, conditions of the base catalyzed step such as base concentration, reaction temperature, methanol to oil molar ratio and reaction time were optimized. The study raveled that, 0.50% KOH w/w of oil; a 6:1 methanol to oil molar ratio; a reaction temperature of 60°C and a duration of 1h were the optimal conditions because they resulted in high biodiesel yield. Fuel properties of the products were assessed and found better than those of the parent oil. Furthermore, they met the specified limits according to the ASTM standards. Thin layer chromatography was used as a simple technique to monitor the transesterification of the oil. Blending of the optimal biodiesel sample with petro diesel using specified volume percentages was done as well. The results indicated that biodiesel had slight effect on the values of the assessed properties.

  17. Statistical optimization for biodiesel production from waste frying oil through two-step catalyzed process

    Energy Technology Data Exchange (ETDEWEB)

    Charoenchaitrakool, Manop [Department of Chemical Engineering, Faculty of Engineering, Kasetsart University, Bangkok (Thailand); Center for Advanced Studies in Nanotechnology and its Applications in Chemical, Food and Agricultural Industries, Kasetsart University, Bangkok (Thailand); Thienmethangkoon, Juthagate [Department of Chemical Engineering, Faculty of Engineering, Kasetsart University, Bangkok (Thailand)

    2011-01-15

    The aim of this work was to investigate the optimum conditions in biodiesel production from waste frying oil using two-step catalyzed process. In the first step, sulfuric acid was used as a catalyst for the esterification reaction of free fatty acid and methanol in order to reduce the free fatty acid content to be approximate 0.5%. In the second step, the product from the first step was further reacted with methanol using potassium hydroxide as a catalyst. The Box-Behnken design of experiment was carried out using the MINITAB RELEASE 14, and the results were analyzed using response surface methodology. The optimum conditions for biodiesel production were obtained when using methanol to oil molar ratio of 6.1:1, 0.68 wt.% of sulfuric acid, at 51 C with a reaction time of 60 min in the first step, followed by using molar ratio of methanol to product from the first step of 9.1:1, 1 wt.% KOH, at 55 C with a reaction time of 60 min in the second step. The percentage of methyl ester in the obtained product was 90.56 {+-} 0.28%. In addition, the fuel properties of the produced biodiesel were in the acceptable ranges according to Thai standard for community biodiesel. (author)

  18. Cocoa pod husk: A new source of CLEA-lipase for preparation of low-cost biodiesel: An optimized process.

    Science.gov (United States)

    Khanahmadi, Soofia; Yusof, Faridah; Chyuan Ong, Hwai; Amid, Azura; Shah, Harmen

    2016-08-10

    Enzymatic reactions involving lipases as catalyst in transesterification can be an excellent alternative to produce environmental-friendly biodiesel. In this study, lipase extracted from Cocoa Pod Husk (CPH) and immobilized through cross linked enzyme aggregate (CLEA) technology catalysed the transesterification of Jatropha curcas oil successfully. Face centered central composite design (FCCCD) under response surface methodology (RSM) was used to get the optimal conditions of 3% (w/w) enzyme loading, 4h reaction time and 1:6 oil/ethanol ratio to achieve the highest conversion of free fatty acid and glycerides into biodiesel (93%). The reusability of CLEA-lipase was tested and after seven cycles, the conversion percentage reduced to 58%. The results revealed that CLEA lipase from CPH is a potential catalyst for biodiesel production.

  19. Fuel spray combustion of waste cooking oil and palm oil biodiesel: Direct photography and detailed chemical kinetics

    KAUST Repository

    Kuti, Olawole

    2013-10-14

    increased. PO has a higher reactivity and this make its chemical ignition delay shorter as compared to WCO. This was attributed to the higher percentage of straight fully saturated chain methyl ester, i.e., methyl palmitate (C16:0) in PO. As injection pressure increases, physical delay, which is the difference between the experimental ignition delay and chemical ignition delay, decreases. As a result of inferior atomization PO biodiesel has longer physical delay compared to WCO. Hence it took longer time for PO biodiesel to achieve mixing prior to chemical ignition delay. Copyright © 2013 SAE International and Copyright © 2013 KSAE.

  20. Biodiesel production with immobilized lipase: A review.

    Science.gov (United States)

    Tan, Tianwei; Lu, Jike; Nie, Kaili; Deng, Li; Wang, Fang

    2010-01-01

    Fatty acid alkyl esters, also called biodiesel, are environmentally friendly and show great potential as an alternative liquid fuel. Biodiesel is produced by transesterification of oils or fats with chemical catalysts or lipase. Immobilized lipase as the biocatalyst draws high attention because that process is "greener". This article reviews the current status of biodiesel production with immobilized lipase, including various lipases, immobilization methods, various feedstocks, lipase inactivation caused by short chain alcohols and large scale industrialization. Adsorption is still the most widely employed method for lipase immobilization. There are two kinds of lipase used most frequently especially for large scale industrialization. One is Candida antartica lipase immobilized on acrylic resin, and the other is Candida sp. 99-125 lipase immobilized on inexpensive textile membranes. However, to further reduce the cost of biodiesel production, new immobilization techniques with higher activity and stability still need to be explored.

  1. Enzymatic biodiesel production: Technical and economical considerations

    DEFF Research Database (Denmark)

    Munk Nielsen, Per; Brask, Jesper; Fjerbæk, Lene

    2008-01-01

    It is well documented in the literature that enzymatic processing of oils and fats for biodiesel is technically feasible. However, with very few exceptions, enzyme technology is not currently used in commercial-scale biodiesel production. This is mainly due to non-optimized process design...... and a lack of available costeffective enzymes. The technology to re-use enzymes has typically proven insufficient for the processes to be competitive. However, literature data documenting the productivity of enzymatic biodiesel together with the development of new immobilization technology indicates...... that enzyme catalysts can become cost effective compared to chemical processing. This work reviews the enzymatic processing of oils and fats into biodiesel with focus on process design and economy....

  2. Sustainable Future for Biodiesel in Brazil

    DEFF Research Database (Denmark)

    Dias, Maria Amélia de Paula

    This thesis aims to study alternatives to biodiesel industry in Brazil, for 2030, taking in account the sustainability dimensions, namely economic, environmental, ecological, social, national and international politics, territorial, cultural, and technological, through the development of scenarios...... for agriculture and pasture. Thus, a simulation, using linear programming models, was made in order to verify the alternatives of feedstock to produce biodiesel. It was observed that it is possible to decentralize the market, reduce land use, and regionalize production, making better use of the availability...... to identify the driving forces to develop the scenario storylines. This proposition was tested in an in-depth interview with the biodiesel market stakeholders. Based on the findings of the two approaches, the simulations and the interviews, it was possible to obtain future alternatives, where the biodiesel...

  3. Current status of biodiesel development in Brazil.

    Science.gov (United States)

    Ramos, Luiz Pereira; Wilhelm, Helena Maria

    2005-01-01

    In recent years, the concept of producing biodiesel from renewable lipid sources has regained international attention. In Brazil, a national program was launched in 2002 to evaluate the technical, economic, and environmental competitiveness of biodiesel in relation to the commercially available diesel oil. Several research projects were initiated nationwide to investigate and/or optimize biodiesel production from renewable lipid sources and ethanol derived from sugarcane (ethyl esters). Once implemented, this program will not only decrease our dependence on petroleum derivatives but also create new market opportunities for agribusiness, opening new jobs in the countryside, improving the sustainability of our energy matrix, and helping the Brazilian government to support important actions against poverty. This article discusses the efforts to develop the Brazilian biodiesel program in the context of technical specifications as well as potential oilseed sources.

  4. ANALYSIS OF COCONUT ETHYL ESTER (BIODIESEL) AND ...

    African Journals Online (AJOL)

    ANALYSIS OF COCONUT ETHYL ESTER (BIODIESEL) AND FOSSIL DIESEL BLENDING: PROPERTIES AND CORROSION CHARACTERISTICS. ... resulting coconut oil ethyl ester (COEE) was blended with fossil diesel (B0). ... Article Metrics.

  5. Survey of alternative feedstocks for biodiesel production

    Science.gov (United States)

    Summarized will be results obtained from the production of biodiesel from several alternative feedstocks with promising agronomic characteristics. Such feedstocks include camelina (Camelina sativa L.), coriander (Coriandrum sativum L.), field pennycress (Thlaspi arvense L.), and meadowfoam (Limnanth...

  6. Obras de Domenico Scarlatti, Antonio Soler y Manuel Blasco [¿de Nebra?] en un manuscrito misceláneo de tecla del Archivo de Música de las Catedrales de Zaragoza

    Directory of Open Access Journals (Sweden)

    Yáñez Navarro, Celestino

    2012-12-01

    Full Text Available The Musical Archive of the Cathedrals of Saragosse (E-Zac keeps a relevant collection of manuscripts of keyboard music of the 18th century. The present study deals, for the fi rst time, with one of these sources, a miscellaneous one (E-Zac, A-1 Ms.1, in which we can find, together with a number of anonymous works, and copies of musical pieces by outstanding local and international composers, musical works by musicians who were developing their careers in the court of Madrid in the last two-thirds of the 18th century. Such were the cases of Domenico Scarlatti, father Antonio Soler, Manuel Blasco (de Nebra?, maybe José de Nebra, Fr. Joaquín Asiaín, (Juan de? Sesé and José Moreno y Polo. The manuscript is particularly interesting not only for compiling three unknown adagios by Manuel Blasco, published here, but also for introducing some sonatas by Scarlatti and Soler, with amazing variants in comparison with the so called “authorized” or reference versions. This gives an added value to this kind of compilations –considered secondary up to now– with no doubt intended to be used by organist working in an ecclesiastical environment.

    El Archivo de Música de las Catedrales de Zaragoza custodia una relevante colección de manuscritos de música de tecla del siglo XVIII. El presente artículo trata por vez primera una de dichas fuentes, miscelánea (E-Zac, A-1 Ms.1, en la que aparecen, junto a numerosas obras anónimas y copias de composiciones de autores destacados del ámbito local e internacional, obras de compositores activos en la corte de Madrid durante los dos últimos tercios del siglo XVIII, tales como Domenico Scarlatti, el padre Antonio Soler, Manuel Blasco [¿de Nebra?], acaso José de Nebra, fray Joaquín Asiaín, [¿Juan de? ] Sesé y José Moreno y Polo. El manuscrito es especialmente interesante no sólo porque compila tres adagios inéditos de Manuel Blasco que hoy se editan

  7. Biodiesel of palm oil in tractor agricultural: opacity of smoke in the light of storage time; Biodiesel de dende em trator agricola: opacidade da fumaca em funcao do tempo de armazenamento

    Energy Technology Data Exchange (ETDEWEB)

    Lima, Leomar P. [Instituto Federal do Triangulo Mineiro (IFTM), Uberlandia, MG (Brazil)], email: leomaragro@yahoo.com.br; Lopes, Afonso; Oliveira, Melina C.J. [Universidade Estadual Paulista Julio de Mesquita Filho (FCAV/UNESP), Jaboticabal, SP (Brazil). Fac. de Ciencias Agrarias e Veterinarias. Dept. de Engenharia Rural; Camara, Felipe T. [Universidade Federal do Ceara (UFC), Cariri, CE (Brazil)

    2011-07-01

    The scenario of atmospheric emissions world characterized-if, in recent years, due to a series of technical factors, economic and political, by the need to reduce the consumption of petroleum. The objective of this work was to evaluate the opacity of smoke of a motor of a tractor agricultural operating with biodiesel of palm oil with different periods of storage. The experiment was conducted in the Laboratory of machinery and agricultural mechanization of Rural Engineering Department of UNESP, Jaboticabal, SP. In this study,-if a tractor Valtra BM 110 4x2 TDA 73,6 kW (100 cv) in engine 2.350 rpm. The experimental design was completely randomized, in factorial scheme 5x3, with 3 repetitions. The combinations of factors were five proportions of mixing biodiesel for diesel (B0, B5, B25, B 50 and B100, that the number indicates the percentage of biodiesel for diesel) and three storage times in condition environment (0, 3 and 6 months). The results showed that in relation to B0, when used biodiesel in the proportion of B100, the opacity of smoke reduced in 50.4% and the time of storage of biodiesel not committed the opacity of smoke from combustion of the engine. (author)

  8. A comparative analysis of in vitro toxicity of diesel exhaust particles from combustion of 1st- and 2nd-generation biodiesel fuels in relation to their physicochemical properties-the FuelHealth project.

    Science.gov (United States)

    Lankoff, Anna; Brzoska, Kamil; Czarnocka, Joanna; Kowalska, Magdalena; Lisowska, Halina; Mruk, Remigiusz; Øvrevik, Johan; Wegierek-Ciuk, Aneta; Zuberek, Mariusz; Kruszewski, Marcin

    2017-07-03

    Biodiesels represent more carbon-neutral fuels and are introduced at an increasing extent to reduce emission of greenhouse gases. However, the potential impact of different types and blend concentrations of biodiesel on the toxicity of diesel engine emissions are still relatively scarce and to some extent contradictory. The objective of the present work was to compare the toxicity of diesel exhaust particles (DEP) from combustion of two 1st-generation fuels: 7% fatty acid methyl esters (FAME; B7) and 20% FAME (B20) and a 2nd-generation 20% FAME/HVO (synthetic hydrocarbon biofuel (SHB)) fuel. Our findings indicate that particulate emissions of each type of biodiesel fuel induce cytotoxic effects in BEAS-2B and A549 cells, manifested as cell death (apoptosis or necrosis), decreased protein concentrations, intracellular ROS production, as well as increased expression of antioxidant genes and genes coding for DNA damage-response proteins. The different biodiesel blend percentages and biodiesel feedstocks led to marked differences in chemical composition of the emitted DEP. The different DEPs also displayed statistically significant differences in cytotoxicity in A549 and BEAS-2B cells, but the magnitude of these variations was limited. Overall, it seems that increasing biodiesel blend concentrations from the current 7 to 20% FAME, or substituting 1st-generation FAME biodiesel with 2nd-generation HVO biodiesel (at least below 20% blends), affects the in vitro toxicity of the emitted DEP to some extent, but the biological significance of this may be moderate.

  9. Production of Biodiesel by Enzymatic Transesterification: Review

    Directory of Open Access Journals (Sweden)

    Abdel E. Ghaly

    2010-01-01

    Full Text Available Problem Statement: The research on the production of biodiesel has increased significantly in recent years because of the need for an alternative fuel which endows with biodegradability, low toxicity and renewability. Plant oils, animal fats, microalgal oils and waste products such as animal rendering, fish processing waste and cooking oils have been employed as feedstocks for biodiesel production. In order to design an economically and environmentally sustainable biodiesel production process, a proper understanding of the factors affecting the process and their relative importance is necessary. Approach: A comprehensive review of the literature on the subject of biodiesel production was carried out. Traditionally biodiesel has been produced using either acid or base catalysts. The multi-step purification of end products, wastewater treatment and energy demand of the conventional process has lead to search for alternative option for production of biodiesel. The use the enzyme lipase as a biocatalyst for the transesterification reaction step in biodiesel production has been extensively investigated. Lipase is produced by all living organisms and can be used intracellularly or extracellularly. Conclusion: To date, the most popular microbes used for their lipases have been filamentous fungi and recombinant bacteria. A summary of lipases used in transesterification and their optimum operating conditions is provided. In addition to the choice of lipase employed, factors which make the transesterification process feasible and ready for commercialization are: enzyme modification, the selection of feedstock and alcohol, use of common solvents, pretreatment of the lipase, alcohol to oil molar ratio, water activity/content and reaction temperature. Optimization of these parameters is necessary in order to reduce the cost of biodiesel production. Use of no/low cost waste materials as feedstocks will have double environmental benefits by reducing the

  10. Microbial degradation of palm (Elaeis guineensis) biodiesel

    OpenAIRE

    Giselle Lutz; Max Chavarría; María Laura Arias; Mata-Segreda, Julio F.

    2014-01-01

    The kinetics of biodegradation of palm-derived fatty methyl and ethyl esters (Elaeis guineensis biodiesel) by a wild-type aerobic bacterial population was measured at 20 °C, as the rate of oxygen uptake by a manometric technique. The methyl and ethyl biodiesels were obtained by potassium-hydroxide catalysed transesterification of palm oil, respectively. The bacterial flora included the genera Bacillus, Proteus, Pseudomonas, Citrobacter and Enterobacter. The rate of oxygen uptake for palm biod...

  11. Physico-Chemical Properties of Bio-diesel from Wild Grape Seeds Oil and Petro-Diesel Blends

    Directory of Open Access Journals (Sweden)

    M. U. Kaisan

    2013-10-01

    Full Text Available The swiftly depleting conventional fossil fuel resources and increasing environmental distress has considerably popped up research curiosity in renewable energy fuel for internal combustion engines. Accordingly, in this research work, biodiesel from wild grape seed (Lannea Microcarpa was blended with petro-diesel in a ratio of 5:95, 10:90, 15:85 and 20:80 and pure fossil diesel designated B5, B10, B15, B20 and B0 respectively. The physico chemical properties of the biodiesel/petro diesel blends were determined. The properties are specific gravity, viscosity, flash point, calorific value, sulphur content, copper strip corrosion, colour, diesel index, cetane number, and cloud point. It was observed that, 9 out of the 10 properties determined conform to ASTM standards except for the colour which was dark brown for the oil and biodiesel, and brown for the automotive gasoline oil. The specific gravity and viscosity increase with percentage increase of biodiesel in the blends. The sulphur content, calorific values, cetane number and diesel index decrease with increase in the percentage biodiesel from the blends. The colour of the samples does not conform to the ASTM standards. All the samples have the best ASTM value for copper strip corrosion and as such, they could be run in any diesel engine without any fear of corrosion tendencies. Whence, Wild Grape seed biodiesel is physically okay, chemically stable, environmentally friendly and economically viable for use in compression ignition engine as a blend to partly replace the automotive gasoline oil.

  12. Production of Bio-Diesel to Neem oil and its performance and emission Analysis in two stroke Diesel Engine.

    Directory of Open Access Journals (Sweden)

    G.Mahesh BABU

    2013-02-01

    Full Text Available In India Neem tree is a widely grown up termed as a divine tree due to its wide relevance in many areas of study. This paper deals with Biodiesel production from neem oil, which is monoester produced usingtransesterification process. Biodiesel is a safe alternative fuel to replace traditional petroleum diesel. It has high lubricity, clean burning fuel and can be a fuel component for use in existing unmodified diesel engine. Neem (Azadirachita Indica is an evergreen tree, which is endemic to the Indian Sub-continent and has beenintroduced to many other areas intropics. The fuel properties of biodiesel including flash point-and fire point were examined. The engine properties and pollutant emissions characteristics under different biodiesel percentages were also studied. The results shows that the biodiesel produced using neem oil could reduce Carbon monoxide and smoke emissions significantly while the Nitrogen oxide emission changed slightly. Thus, the ester of this oil can be used as environment friendly alternative fuel for diesel engine.

  13. Perspectives of microbial oils for biodiesel production.

    Science.gov (United States)

    Li, Qiang; Du, Wei; Liu, Dehua

    2008-10-01

    Biodiesel has become more attractive recently because of its environmental benefits, and the fact that it is made from renewable resources. Generally speaking, biodiesel is prepared through transesterification of vegetable oils or animal fats with short chain alcohols. However, the lack of oil feedstocks limits the large-scale development of biodiesel to some extent. Recently, much attention has been paid to the development of microbial, oils and it has been found that many microorganisms, such as algae, yeast, bacteria, and fungi, have the ability to accumulate oils under some special cultivation conditions. Compared to other plant oils, microbial oils have many advantages, such as short life cycle, less labor required, less affection by venue, season and climate, and easier to scale up. With the rapid expansion of biodiesel, microbial oils might become one of potential oil feedstocks for biodiesel production in the future, though there are many works associated with microorganisms producing oils need to be carried out further. This review is covering the related research about different oleaginous microorganisms producing oils, and the prospects of such microbial oils used for biodiesel production are also discussed.

  14. Butter as a feedstock for biodiesel production.

    Science.gov (United States)

    Haas, Michael J; Adawi, Nadia; Berry, William W; Feldman, Elaine; Kasprzyk, Stephen; Ratigan, Brian; Scott, Karen; Landsburg, Emily Bockian

    2010-07-14

    Fatty acid methyl esters (FAME) were produced from cow's milk (Bostaurus) butter by esterification/transesterification in the presence of methanol. The product was assayed according to the Standard Specification for Biodiesel Fuel Blend Stock (B100) for Middle Distillate Fuels (ASTM D 6751). The preparation failed to meet the specifications for flash point, free and total glycerin contents, total sulfur, and oxidation stability. Failures to meet the flash point and free/total glycerin specifications were determined to be due to interference with standard assays for these parameters by short-chain-length fatty acid esters. The oxidation stability of the butterfat FAME was improved by supplementation with a commercial antioxidant formulation. Approximately 725 ppm of antioxidant was required to meet the ASTM-specified stability value for biodiesel. This work indicates that, without further purification to reduce a slightly excessive sulfur content, fatty acid ester preparations produced from butter are unacceptable as sole components of a biodiesel fuel. However, it is possible that even without further purification a butter-based ester preparation could be mixed with biodiesel from other feedstocks to produce a blend that meets the current quality standards for biodiesel. The results presented here also illustrate some potential weaknesses in the accepted methods for biodiesel characterization when employed in the analysis of FAME preparations containing mid- and short-chain fatty acid esters.

  15. INTEGER PERCENTAGES AS ELECTORAL FALSIFICATION FINGERPRINTS

    NARCIS (Netherlands)

    Kobak, Dmitry; Shpilkin, Sergey; Pshenichnikov, Maxim S.

    2016-01-01

    We hypothesize that if election results are manipulated or forged, then, due to the well-known human attraction to round numbers, the frequency of reported round percentages can be increased. To test this hypothesis, we analyzed raw data from seven federal elections held in the Russian Federation du

  16. The effect of biodiesel policies on world biodiesel and oilseed prices

    NARCIS (Netherlands)

    Drabik, D.; Gorter, de H.; Timilsina, G.R.

    2014-01-01

    A theoretical and empirical model is developed to analyze the effect of a biodiesel mandate, a tax exemption (tax credit) and an exogenous diesel price shock on world soybean and canola markets. The jointness in crushing oil and meal from the oilseed reduces the size of the link between biodiesel

  17. The effect of biodiesel policies on world biodiesel and oilseed prices

    NARCIS (Netherlands)

    Drabik, D.; Gorter, de H.; Timilsina, G.R.

    2014-01-01

    A theoretical and empirical model is developed to analyze the effect of a biodiesel mandate, a tax exemption (tax credit) and an exogenous diesel price shock on world soybean and canola markets. The jointness in crushing oil and meal from the oilseed reduces the size of the link between biodiesel an

  18. Optimisation of integrated biodiesel production. Part I. A study of the biodiesel purity and yield.

    Science.gov (United States)

    Vicente, Gemma; Martínez, Mercedes; Aracil, José

    2007-07-01

    This study consists of the development and optimisation of the potassium hydroxide-catalysed synthesis of fatty acid methyl esters (biodiesel) from sunflower oil. A factorial design of experiments and a central composite design have been used. The variables chosen were temperature, initial catalyst concentration by weight of sunflower oil and the methanol:vegetable oil molar ratio, while the responses were biodiesel purity and yield. The initial catalyst concentration is the most important factor, having a positive influence on biodiesel purity, but a negative one on biodiesel yield. Temperature has a significant positive effect on biodiesel purity and a significant negative influence on biodiesel yield. The methanol:vegetable oil molar ratio is only significant for the biodiesel purity, having a positive influence. Second-order models were obtained to predict biodiesel purity and yield as a function of these variables. The best conditions are 25 degrees C, a 1.3%wt for the catalyst concentration and a 6:1 methanol:sunflower oil molar ratio.

  19. Performance and emission characteristics of double biodiesel blends with diesel

    Directory of Open Access Journals (Sweden)

    Kuthalingam Arun Balasubramanian

    2013-01-01

    Full Text Available Recent research on biodiesel focused on performance of single biodiesel and its blends with diesel. The present work aims to investigate the possibilities of the application of mixtures of two biodiesel and its blends with diesel as a fuel for diesel engines. The combinations of Pongamia pinnata biodiesel, Mustard oil biodiesel along with diesel (PMD and combinations of Cotton seed biodiesel, Pongamia pinnata biodiesel along with diesel (CPD are taken for the experimental analysis. Experiments are conducted using a single cylinder direct-injection diesel engine with different loads at rated 3000 rpm. The engine characteristics of the two sets of double biodiesel blends are compared. For the maximum load, the value of Specific Fuel consumption and thermal efficiency of CPD-1 blend (10:10:80 is close to the diesel values. CPD blends give better engine characteristics than PMD blends. The blends of CPD are suitable alternative fuel for diesel in stationary/agricultural diesel engines.

  20. Evaluation of hydrolysis-esterification biodiesel production from wet microalgae.

    Science.gov (United States)

    Song, Chunfeng; Liu, Qingling; Ji, Na; Deng, Shuai; Zhao, Jun; Li, Shuhong; Kitamura, Yutaka

    2016-08-01

    Wet microalgae hydrolysis-esterification route has the advantage to avoid the energy-intensive units (e.g. drying and lipid extraction) in the biodiesel production process. In this study, techno-economic evaluation of hydrolysis-esterification biodiesel production process was carried out and compared with conventional (usually including drying, lipid extraction, esterification and transesterification) biodiesel production process. Energy and material balance of the conventional and hydrolysis-esterification processes was evaluated by Aspen Plus. The simulation results indicated that drying (2.36MJ/L biodiesel) and triolein transesterification (1.89MJ/L biodiesel) are the dominant energy-intensive stages in the conventional route (5.42MJ/L biodiesel). By contrast, the total energy consumption of hydrolysis-esterification route can be reduced to 1.81MJ/L biodiesel, and approximately 3.61MJ can be saved to produce per liter biodiesel.

  1. Plant latex lipase as biocatalysts for biodiesel production

    African Journals Online (AJOL)

    MAZOU Mouaïmine

    2016-07-13

    Jul 13, 2016 ... Bio-fuel or biodiesel is ... 1998), the European standard EN14214 (FAME, 2003) and the ... biodiesel and industrial detergent industries (Alonso et al., 2005). ...... product, alkaline wastewater requires treatment, and free.

  2. The Language of Comparisons: Communicating about Percentages

    Directory of Open Access Journals (Sweden)

    Jessica Polito

    2014-01-01

    Full Text Available While comparisons between percentages or rates appear frequently in journalism and advertising, and are an essential component of quantitative writing, many students fail to understand precisely what percentages mean, and lack fluency with the language used for comparisons. After reviewing evidence demonstrating this weakness, this experience-based perspective lays out a framework for teaching the language of comparisons in a structured way, and illustrates it with several authentic examples that exemplify mistaken or misleading uses of such numbers. The framework includes three common types of erroneous or misleading quantitative writing: the missing comparison, where a key number is omitted; the apples-to-pineapples comparison, where two subtly incomparable rates are presented; and the implied fallacy, where an invalid quantitative conclusion is left to the reader to infer.

  3. Characteristics of particulate emissions from a diesel generator fueled with varying blends of biodiesel and fossil diesel.

    Science.gov (United States)

    Tsai, Jen-Hsiung; Chen, Shui-Jen; Huang, Kuo-Lin; Lee, Wen-Jhy; Kuo, Wen-Chien; Lin, Wen-Yinn

    2011-01-01

    This study investigated the particulate matter (PM), particle-bound carbons, and polycyclic aromatic hydrocarbons (PAHs) emitted from a diesel-engine generator fuelled with blends of pure fossil diesel oil (D100) and varying percentages of waste-edible-oil biodiesel (W10, 10 vol %; W20, 20 vol %; W30, 30 vol %; and W50, 50 vol %) under generator loads of 0, 1.5, and 3 kW. On average, the PM emission factors of all blends was 30.5 % (range, 13.7-52.3 %) lower than that of D100 under the tested loads. Substituting pure fossil diesel oil with varying percentages of waste-edible-oil biodiesel reduced emissions of particle-bound total carbon (TC) and elemental carbon (EC). The W20 blend had the lowest particle-bound organic carbon (OC) emissions. Notably, W10, W20, and W30 also had lower Total-PAH emissions and lower total equivalent toxicity (Total-BaP(eq)) compared to D100. Additionally, the brake-specific fuel consumption of the generator correlated positively with the ratio of waste-edible-oil biodiesel to pure fossil diesel. However, generator energy efficiency correlated negatively with the ratio of waste-edible-oil biodiesel to pure fossil diesel.

  4. Market penetration of biodiesel and ethanol

    Science.gov (United States)

    Szulczyk, Kenneth Ray

    This dissertation examines the influence that economic and technological factors have on the penetration of biodiesel and ethanol into the transportation fuels market. This dissertation focuses on four aspects. The first involves the influence of fossil fuel prices, because biofuels are substitutes and have to compete in price. The second involves biofuel manufacturing technology, principally the feedstock-to-biofuel conversion rates, and the biofuel manufacturing costs. The third involves prices for greenhouse gas offsets. The fourth involves the agricultural commodity markets for feedstocks, and biofuel byproducts. This dissertation uses the Forest and Agricultural Sector Optimization Model-Greenhouse Gas (FASOM-GHG) to quantitatively examine these issues and calculates equilibrium prices and quantities, given market interactions, fossil fuel prices, carbon dioxide equivalent prices, government biofuel subsidies, technological improvement, and crop yield gains. The results indicate that for the ranges studied, gasoline prices have a major impact on aggregate ethanol production but only at low prices. At higher prices, one runs into a capacity constraint that limits expansion on the capacity of ethanol production. Aggregate biodiesel production is highly responsive to gasoline prices and increases over time. (Diesel fuel price is proportional to the gasoline price). Carbon dioxide equivalent prices expand the biodiesel industry, but have no impact on ethanol aggregate production when gasoline prices are high again because of refinery capacity expansion. Improvement of crop yields shows a similar pattern, expanding ethanol production when the gasoline price is low and expanding biodiesel. Technological improvement, where biorefinery production costs decrease over time, had minimal impact on aggregate ethanol and biodiesel production. Finally, U.S. government subsidies have a large expansionary impact on aggregate biodiesel production. Finally, U.S. government

  5. Production of Biodiesel from Parinari polyandra B. Seed Oil using ...

    African Journals Online (AJOL)

    Akorede

    The acid value of 2.620 mg KOH/g obtained for the crude oil is suitable for biodiesel .... Khalil, A.; Shaikh S.N., and Nudrat Z.R. (2014). Reinforcement of natural ... transesterification of soybean oil into biodiesel: Effects of biodiesel on engine ...

  6. 10 CFR 490.703 - Biodiesel fuel use credit allocation.

    Science.gov (United States)

    2010-01-01

    ... 10 Energy 3 2010-01-01 2010-01-01 false Biodiesel fuel use credit allocation. 490.703 Section 490.703 Energy DEPARTMENT OF ENERGY ENERGY CONSERVATION ALTERNATIVE FUEL TRANSPORTATION PROGRAM Biodiesel Fuel Use Credit § 490.703 Biodiesel fuel use credit allocation. (a) DOE shall allocate to a fleet...

  7. Effects of fractal grid on emissions in burner combustion by using fuel-water-air premix injector derived from biodiesel crude palm oil (CPO base

    Directory of Open Access Journals (Sweden)

    Suardi Mirnah

    2017-01-01

    Full Text Available The alternative fuel is attracted good attention from worldwide especially for renewable and prevention energy such as biodiesel. Biodiesel is one of the hydrocarbon fuels and it has potential for external combustion. As one of the different solutions to these problems, rapid mixing of biodiesel-water-air technique is one of the most significant approaches to improve the combustion and reduce the emissions. The gas emission can be reduced by two methods. First is by improving an injector with fractal and the other is by using a biodiesel-water mixture as an alternative fuel. Mixing of water with fuel in the combustion process is a low cost and effective way. This research used biodiesel Crude Palm Oil (CPO as fuels in which blended with diesel. This study investigated the effects of water content and equivalence ratio on emissions with the rapid mixing injector. Fuels used are diesel, CPO5, CPO10 and CPO15 and the exhausts gaseous tested are CO, CO2, HC and NOX. The gas emissions processes are tested by using the gas analyzer. In this research, water premix of percentage up to 15vol% and blending biodiesel ratio was varied from 5vom% - 15vol%. The result shows that increasing of water content will effected decrement of CO, CO2 and HC emissions but increasing the NOX emissions.

  8. ESTUDO DA VIABILIDADE DA AUTOPRODUÇÃO E USO DE BIODIESEL PARA ABASTECIMENTO DA ESTRADA DE FERRO CARAJÁS

    Directory of Open Access Journals (Sweden)

    AURÉLIO LAMARE SOARES MURTA

    2014-04-01

    Full Text Available Due to the great changes brought about by climate change associated with the effects of global warming and oil shortages, new forms of energy have been investigated aiming to mitigate these impacts. Thus, this work addresses the tests made by different companies and universities that demonstrate the technical feasibility of the biodiesel use in heavy vehicles. Therefore, a methodology was developed to allow the tests to be conducted in a secure and reliable way, following the procedures recommended for larger percentage of mixture of diesel and biodiesel. This work also includes a case study of biodiesel production by the Vale Company for the Carajás Railroad, from where was made a cost of deployment and production of biodiesel from soybean and palm. The final conclusions are that the cost of biodiesel produced in this unit was set up well above the final price of diesel acquired by the company at the distribution, similar to what happens in the market. However, with the expectation that with the development of production processes of biofuel, the fixation of limits of emissions control, as well as the high price of oil, make the price of biodiesel competitive regarding to diesel.

  9. Tratamento de águas contaminadas por diesel/biodiesel utilizando processo Fenton Treatment of water contaminated by diesel/biodiesel using Fenton process

    Directory of Open Access Journals (Sweden)

    Teofani Koslides Mitre

    2012-06-01

    Full Text Available A contaminação de águas por misturas diesel/biodiesel pode causar grandes impactos ambientais, relacionados à presença de compostos orgânicos recalcitrantes e tóxicos, inviabilizando o uso de processos biológicos de tratamento. A avaliação da biodegradabilidade, nas proporções B0, B25, B50, B75 e B100 (os números especificam o percentual em massa de biodiesel na mistura, indicou que a adição de biodiesel em teores acima de 50% aumenta a biodegradabilidade, alcançando 60 e 80% para B50 e B75, respectivamente. Na aplicação do processo Fenton, a remoção da matéria orgânica foi superior a 80% em todas as misturas, exceto para B0, que apresentou remoção máxima de 50%. A oxidação por Fenton se ajustou a um modelo cinético de pseudo-segunda ordem em relação à concentração de matéria orgânica, e resultou em aumento da biodegradabilidade de até 150%.Waters contaminated with diesel/biodiesel and their blends can cause major environmental impacts, due to the presence of toxic and recalcitrant organic compounds, which invalidate the use of biological treatment processes. Evaluation of biodegradability of the blends B0, B25, B50, B75 and B100 (the numbers specify the mass percentage of biodiesel in the blend indicated that the addition of biodiesel at concentrations above 50% increased biodegradation, reaching 60 and 80% for B50 and B75, respectively. When the Fenton process was used, removal of organic matter was greater than 80 % in all blends, except for B0, which showed maximum removal of 60%. Oxidation by Fenton was fitted with a pseudo-second order kinetic model in relation to the concentration of organic matter and resulted in increased biodegradation of up to 150%.

  10. Significance of the structural properties of CaO catalyst in the production of biodiesel: An effect on the reduction of greenhouse gases emission

    Directory of Open Access Journals (Sweden)

    Ljupković Radomir B.

    2014-01-01

    Full Text Available The influence of the physicochemical properties of a series of CaO catalysts activated at different temperatures on the biodiesel production was investigated. These catalysts show dissimilar yields in the transesterification of triglycerides with methanol. We have found significant relationships between structural properties (the type of the pore system, the typical CaO crystal phase and the sizes of crystallites (up to 25 nm, the minimal weight percentage of CaO phase, the total surface basicity and potential existence of two types of basic active sites of CaO prepared and activated by means of thermal treatment at highest temperature and catalytic efficiency. Benefits of this catalyst are short contact time, standard operating temperature and atmospheric conditions, relatively low molar ratios and small catalyst loading. These all together resulted in a very high biodiesel yield of high purity. The properties of different biodiesel (obtained with the use of the prepared CaO catalyst blends with different diesel and biodiesel ratios indicate that the higher the fraction of biodiesel fuel the better the achieved fuel properties according to the EU standards. A significant reduction of CO2 and CO emissions and only a negligible NOx increase occurred when blends with an increased biodiesel portion was used. The use of biodiesel derived blends, and the eventual complete replacement of fossil fuels with biodiesel as a renewable, alternative fuel for diesel engines, would greatly contribute to the reduction of greenhouse gases emissions. [Projekat Ministarstva nauke Republike Srbije, br. ON 172061 i TR 34008

  11. Integral process of obtaining glycerol as a by-product of biodiesel production from castor oil

    Directory of Open Access Journals (Sweden)

    Leonel Romero

    2012-12-01

    Full Text Available The biodiesel is obtained from about 10 years ago in Europe, and now that it has taken hold as fuel for diesel engines, it is expected a clear increase in the production of this class of fuels in a the near future. The biodiesel is derived from the transesterification reaction of castor oil with methanol, which is the main by-product the glycerol with an approximate content of 10%. Besides catalyst residuals, soaps, methanol traces, mono and diglycerides in small percentages are presented. This study proposes the separation, purification and characterization of the glycerol obtained from the transesterificación reaction of the castor oil, in order to be able to market it in the national or international market, so that it fulfills the standards of quality, which means getting a pure glycerol and the appropriate physico-chemical characteristics and techniques. The glycerin-methyl esters separation is carried out by decantation being obtained a percentage of around 70% glycerol. This percentage is subsequently increased through the purification process, using hydrochloric acid. Glycerol characterization was carried out by physicochemical and organoleptic tests. The purification process allowed us to obtain a glycerol with a percentage of purity close to 98%. It was also tested by comparison with theoretical data that remnants influenced in the physiochemical properties

  12. Enzymatisk omestring til produktion af biodiesel

    DEFF Research Database (Denmark)

    Fjerbæk, Lene

    2007-01-01

      Biodiesel er i dag sammen med bioethanol et bud på, hvordan transportsektoren kan nedbringe sin netto CO2-emission til atmosfæren og lagrene af fossilt brændstof kan strækkes. På verdensplan forventes der en produktion af biodiesel på 7,9 mio. tons i 2007. Ved den industrielle fremstilling af...... biodiesel benyttes i dag kemiske katalysatorer såsom H2SO4, NaOH, MeONa eller KOH, der efterfølgende fjernes fra den producerede biodiesel med store mængder vand og derved produceres store mængder spildevand. Ved at benytte enzymer i processen kan man reducere mængden af spildevand, der skal renses. Enzymer...... benyttes ikke i de eksisterende processer, men det forventes, at udviklingen af processerne vil øge deres anvendelse i biodieselproduktion. I artiklen præsenteres fordele og ulemper ved anvendelse af enzymer til biodiesel produktion....

  13. Compatibility of elastomers in palm biodiesel

    Energy Technology Data Exchange (ETDEWEB)

    Haseeb, A.S.M.A.; Masjuki, H.H.; Siang, C.T.; Fazal, M.A. [Department of Mechanical Engineering, University of Malaya, 50603 Kuala Lumpur (Malaysia)

    2010-10-15

    In recent time, environmental awareness and concern over the rapid exhaustion of fossil fuels have led to an increased popularity of biodiesel as an alternative fuel for automobiles. However, there are concerns over enhanced degradation of automotive materials in biodiesel. The present study aims to investigate the impact of palm biodiesel on the degradation behavior of elastomers such as nitrile rubber (NBR), polychloroprene, and fluoro-viton A. Static immersion tests in B0 (diesel), B10 (10% biodiesel in diesel), B100 (biodiesel) were carried out at room temperature (25 C) and at 50 C for 500 h. At the end of immersion test, degradation behavior was investigated by measuring mass, volume, hardness as well as tensile strength and elongation. The exposed elastomer surface was studied by scanning electron microscopy (SEM). Fourier Transform Infrared (FTIR) spectroscopy was carried out to identify the chemical and structural changes. Results showed that the extent of degradation was higher for both polychloroprene and NBR while fluoro-viton exhibited good resistance to degradation and was least attacked. (author)

  14. Some Technical Aspects for Sustainable Biodiesel Production

    Directory of Open Access Journals (Sweden)

    Imam Paryanto

    2013-01-01

    Full Text Available According to Brundtland Commission (1987, sustainability means the ability to meet the needs of the present without compromising the ability of future generations’ abilities to meet their own needs. The term of sustainability has multi-dimensional objectives of social, environmental and economic. Without ignoring the importance of social, environmental, and economical aspects of sustainability, this study will only highlight some technical aspects for sustainable biodiesel production and, of course, the final goal will target the implication of improved social, environmental and economical conditions. Some technical aspects for sustainable biodiesel production cover the multi-discipline activities at the design stage and at the operation stage of biodiesel production plant. The design stage can be divided into conceptual design, basic engineering design and detailed engineering design. At this stage, the design parameters should consider the selection of the type and availability of raw material, biodiesel plant capacity and location, the efficient production process, the availability of utilities and supporting infrastructures, waste (environmental treatment, and raw material and product handling facilities. And during the operation of biodiesel plant, some important technical issues are the production process activities according to the Standard Operating Procedure (SOP, awareness of safety and Hazard and Operability Study (HAZOP, scheduled maintenance activity, waste management, product quality control, and further, if possible, efficiency improvement in the production line through R&D activities and technological advances.

  15. Environmental accounting of biodiesel from soybeans

    Energy Technology Data Exchange (ETDEWEB)

    Romanelli, T.L. [Escola Superior de Agricultura Luiz de Queiroz (ESALQ/USP), Piracicaba, SP (Brazil). Dept. de Engenharia Rural

    2008-07-01

    As nonrenewable energy sources are depleted globally new sources of energy are becoming necessary. One option that has been explored in recent years is biodiesel production using agricultural products such as soybeans. The emergy accounting method gives value to environmental flows of energy and it quantifies the total amount of energy that has gone in to a product. Also, it provides an inventory of inputs and outputs that can be used to analyze what, if any, types of changes can be made to specific processes within the production as well as improvements in the efficiency of the system as a whole in order to increase the viability of biodiesel as a fuel source. This evaluation uses the concept of emergy to quantify the costs and returns of biodiesel production. This study showed that, currently in the typical production system in the US, biodiesel is not competitive to fossil fuel sources regarding energy providing. But, considering the depletion of the latter source it may become part of source for society. For biodiesel from soybean oil to become more energetically competitive the agricultural production has to be improved since it demands more than 80% of the used resources. Within the soybean production, topsoil loss was responsible for more than 40% which also negatively affects the renewability of this energy source. (author)

  16. Processing Coconut Fiber and Shell to Biodiesel

    Directory of Open Access Journals (Sweden)

    Sri Aulia Novita

    2014-01-01

    Full Text Available Based on research conducted, liquid smoke coming from the husk and coconut shell containing 58-70% Methyl Ester as biodiesel-forming compounds. Then conducted research for the manufacture of methyl esters of liquid smoke based on differences in their boiling points. The purpose of this research is the development of tools producing liquid smoke, liquid smoke processing into biodiesel, biodiesel testing with the diesel engine and the determination of the proper blending between biodiesel. The method used in this study is a phase of making tools, raw material preparation, testing tools  for liquid smoke production, purification, separation of methyl esters and methyl esters testing by blending in diesel engines. Obtained from research conducted work capacity device of liquid smoke 1:22 kg / hour with a yield of 32.17%. Performance test  by blending biodiesel B10, B20, B30, B40, B50 and B100 with a 6.5 HP engine capable of running a diesel engine with performance that is not much different, more smoke clear, odorless and lighter engine speed.

  17. Comparative characterization of Jatropha, soybean and commercial biodiesel

    Institute of Scientific and Technical Information of China (English)

    Sylvain-Didier B. Kouame

    2011-01-01

    Oil was extracted from seeds of Jatropha Curcas, in high yields (up to 40% by weight). The extracted Jatropha oil was converted in a laboratory reactor to biodiesel by transesterification. Analysis of Jatropha oil and Jatropha biodiesel by GC/MS and GC/SIMDIS showed that Jatropha oil could be readily converted to a biodiesel product through NaOH catalyzed transesterification.The resulting biodiesel has desirable properties such as high cetane number and low flash point, which are major improvements over the properties of commercial biodiesel fuels.

  18. A fuzzy goal programming model for biodiesel production

    Science.gov (United States)

    Lutero, D. S.; Pangue, EMU; Tubay, J. M.; Lubag, S. P.

    2016-02-01

    A fuzzy goal programming (FGP) model for biodiesel production in the Philippines was formulated with Coconut (Cocos nucifera) and Jatropha (Jatropha curcas) as sources of biodiesel. Objectives were maximization of feedstock production and overall revenue and, minimization of energy used in production and working capital for farming subject to biodiesel and non-biodiesel requirements, and availability of land, labor, water and machine time. All these objectives and constraints were assumed to be fuzzy. Model was tested for different sets of weights. Results for all sets of weights showed the same optimal allocation. Coconut alone can satisfy the biodiesel requirement of 2% per volume.

  19. Perspectives for biotechnological production of biodiesel and impacts

    Energy Technology Data Exchange (ETDEWEB)

    Du Wei; Li Wei; Sun Ting; Chen Xin; Liu Dehua [Tsinghua Univ., Beijing (China). Dept. of Chemical Engineering

    2008-06-15

    In recent years, biological ways for biodiesel production have drawn an increasing attention and compared to chemical approaches, lipase-mediated alcoholysis for biodiesel production has many advantages. Currently, there are extensive reports about enzyme-mediated alcoholysis for biodiesel production, and based on the application forms of biocatalyst, the related research can be classified into immobilized lipase, whole cell catalyst, and liquid lipase-mediated alcoholysis for biodiesel production, respectively. This mini-review is focusing on the study of the aforementioned three forms of biocatalyst for biodiesel production, as well as its impacts and prospects. (orig.)

  20. Biodiesel Basics (Spanish Version); Clean Cities, Energy Efficiency & Renewable Energy (EERE)

    Energy Technology Data Exchange (ETDEWEB)

    None

    2015-08-01

    This Spanish-language fact sheet provides a brief introduction to biodiesel, including a discussion of biodiesel blends, which blends are best for which vehicles, where to buy biodiesel, how biodiesel compares to diesel fuel in terms of performance, how biodiesel performs in cold weather, whether biodiesel use will plug vehicle filters, how long-term biodiesel use may affect engines, biodiesel fuel standards, and whether biodiesel burns cleaner than diesel fuel. The fact sheet also dismisses the use of vegetable oil as a motor fuel.

  1. Uncertainties in pipeline water percentage measurement

    Energy Technology Data Exchange (ETDEWEB)

    Scott, Bentley N.

    2005-07-01

    Measurement of the quantity, density, average temperature and water percentage in petroleum pipelines has been an issue of prime importance. The methods of measurement have been investigated and have seen continued improvement over the years. Questions are being asked as to the reliability of the measurement of water in the oil through sampling systems originally designed and tested for a narrow range of densities. Today most facilities sampling systems handle vastly increased ranges of density and types of crude oils. Issues of pipeline integrity, product loss and production balances are placing further demands on the issues of accurate measurement. Water percentage is one area that has not received the attention necessary to understand the many factors involved in making a reliable measurement. A previous paper1 discussed the issues of uncertainty of the measurement from a statistical perspective. This paper will outline many of the issues of where the errors lie in the manual and automatic methods in use today. A routine to use the data collected by the analyzers in the on line system for validation of the measurements will be described. (author) (tk)

  2. Uncertainties in pipeline water percentage measurement

    Energy Technology Data Exchange (ETDEWEB)

    Scott, Bentley N.

    2005-07-01

    Measurement of the quantity, density, average temperature and water percentage in petroleum pipelines has been an issue of prime importance. The methods of measurement have been investigated and have seen continued improvement over the years. Questions are being asked as to the reliability of the measurement of water in the oil through sampling systems originally designed and tested for a narrow range of densities. Today most facilities sampling systems handle vastly increased ranges of density and types of crude oils. Issues of pipeline integrity, product loss and production balances are placing further demands on the issues of accurate measurement. Water percentage is one area that has not received the attention necessary to understand the many factors involved in making a reliable measurement. A previous paper1 discussed the issues of uncertainty of the measurement from a statistical perspective. This paper will outline many of the issues of where the errors lie in the manual and automatic methods in use today. A routine to use the data collected by the analyzers in the on line system for validation of the measurements will be described. (author) (tk)

  3. Energy aspects of microalgal biodiesel production

    Directory of Open Access Journals (Sweden)

    Edith Martinez-Guerra

    2016-03-01

    Full Text Available Algal biodiesel production will play a significant role in sustaining future transportation fuel supplies. A large number of researchers around the world are investigating into making this process sustainable by increasing the energy gains and by optimizing resource-utilization efficiencies. Although, research is being pursued aggressively in all aspects of algal biodiesel production from microalgal cell cultivation, cell harvesting, and extraction and transesterification steps to the final product separation and purification, there is a large disparity in the data presented in recent reports making it difficult to assess the real potential of microalgae as a future energy source. This article discusses some of the key issues in energy consumption in the process of algal biodiesel production and identifies the areas for improvement to make this process energy-positive and sustainable.

  4. Process for biodiesel production from Cryptococcus curvatus.

    Science.gov (United States)

    Thiru, Meikandhan; Sankh, Santosh; Rangaswamy, Vidhya

    2011-11-01

    The objective of the current report is process optimization for economical production of lipids by the well known oleaginous yeast Cryptococcus curvatus and conversion of the lipids to biodiesel. A high cell density fed-batch cultivation on low cost substrate viz. crude glycerol resulted in a dry biomass and oil yield of up to 69 g/L and 48% (w/w), respectively. The process was scaled up easily to 26 L. The oil extraction process was also optimized using environmentally safe solvents. The oil profile indicated a high oleic acid content followed by palmitic acid, stearic acid and linoleic acid. The oil was trans-esterified to biodiesel and thoroughly characterized. This is the first end to end report on production of biodiesel from the C. curvatus oil.

  5. Operation and Control of Enzymatic Biodiesel Production

    DEFF Research Database (Denmark)

    Price, Jason Anthony; Huusom, Jakob Kjøbsted; Nordblad, Mathias

    -product. Current literature indicates that enzymatic processing of oils and fats to produce biodiesel is technically feasible and developments in immobilization technology indicate that enzyme catalysts can become cost effective compared to chemical processing. However, with very few exceptions, enzyme technology...... is not currently used in commercial-scale biodiesel production. This is mainly due to non-optimized process designs, which do not use the full potential of the catalysts in a cost-efficient way. Furthermore is it unclear what process variables need to be monitored and controlled to ensure optimal economics...... an enzymatic route, batch operation is a straightforward and efficient means for producing BD with its main disadvantage being the downtime between batches. For large-scale production of biodiesel, continuous operation is an attractive alternative as it enables efficient use of manpower and capital assets...

  6. Valorization of crude glycerol from biodiesel production

    Directory of Open Access Journals (Sweden)

    Konstantinović Sandra S.

    2016-01-01

    Full Text Available The increased production of biodiesel as an alternative fuel involves the simultaneous growth in production of crude glycerol as its main by-product. Therefore, the feasibility and sustainability of biodiesel production requires the effective utilization of crude glycerol. This review describes various uses of crude glycerol as a potential green solvent for chemical reactions, a starting raw material for chemical and biochemical conversions into value-added chemicals, a substrate or co-substrate in microbial fermentations for synthesis of valuable chemicals and production of biogas and biohydrogen as well as a feedstuff for animal feed. A special attention is paid to various uses of crude glycerol in biodiesel production. [Projekat Ministarstva nauke Republike Srbije, br. III 45001

  7. Effect of Reaction Temperature on Biodiesel Production from Chlorella vulgaris using CuO/Zeolite as Heterogeneous Catalyst

    Science.gov (United States)

    Dianursanti; Delaamira, M.; Bismo, S.; Muharam, Y.

    2017-02-01

    Human needs for fossil energy increase every year. Biodiesel is the main way to resolve this world problem. Biodiesel produces from vegetable oil. But then, the alternative way came from the uses of microalgae in Chlorella vulgaris type causes by its simplicity of growing. In the other hand, this microalgae known for its high lipid content by considering several parameter such as light intensity, medium nutrition, pH and also salinity. Lipid content will be extracted by using Bligh-Dryer method which will be reacted with methanol along transesterification. Beside, there come another matter which is the utilization of homogeny catalyst. The difficulty of separation is the main matter so then biodiesel need to be washed in case normalizing the pH and this process will decrease the quality of biodiesel. To resolve this problem, we’ll be using a heterogeneous catalyst, zeolite, with ability to catalyst the process. Zeolite is easier to separate from the biodiesel so there will not be needed washing process. Heterogeneous catalyst work as well as homogeneous. Variation implemented on transesterification included reaction temperature of 40°C, 60°C, and 80°C. Reaction time, catalyst percentage and the solvent amount remain steady on 4 hours, 3% and 1:400. Complete best result obtained at 60°C with the yield of 36,78%. Through this, heterogeneous catalyst CuO/Zeolite proved to have a capability for replacing homogeneous catalyst and simplify the production of biodiesel particularly in separation step.

  8. Synthesis And Characterization of Biodiesel From Nigerian Palm Kernel oil.

    Directory of Open Access Journals (Sweden)

    IGBOKWE, J. O.

    2016-07-01

    Full Text Available Biodiesel was produced from Nigerian Palm kernel oil through direct base- catalyzed transesterification process using methanol and sodium hydroxide as alcohol and catalyst respectively. The transesterification process involved 1 liter of Palm kernel oil, 200ml of methanol, 1.0% NaOH, reaction temperature of 65 degree Celsius and reaction time of 90mins and an average biodiesel yield of 87.67% was obtained. The produced biodiesel was blended with diesel fuel at a ratio of 20% biodiesel to 80% diesel fuel (by volume. The neat biodiesel and its blend were characterized using the ASTM methods. The results showed that the properties of the neat palm kernel oil biodiesel and its blend fall within the American Society for Testing and Materials (ASTM specifications for Biodiesel fuels hence confirming their suitability as alternative fuels for modern diesel engines.

  9. Improvement of biodiesel methanol blends

    Directory of Open Access Journals (Sweden)

    Y. Datta Bharadwaz

    2016-06-01

    Full Text Available The main objective of this work was to improve the performance of biodiesel–methanol blends in a VCR engine by using optimized engine parameters. For optimization of the engine, operational parameters such as compression ratio, fuel blend, and load are taken as factors, whereas performance parameters such as brake thermal efficiency (Bth and brake specific fuel consumption (Bsfc and emission parameters such as carbon monoxide (CO, unburnt hydrocarbons (HC, Nitric oxides (NOx and smoke are taken as responses. Experimentation is carried out as per the design of experiments of the response surface methodology. Optimization of engine operational parameters is carried out using Derringers Desirability approach. From the results obtained it is inferred that the VCR engine has maximum performance and minimum emissions at 18 compression ratio, 5% fuel blend and at 9.03 kg of load. At this optimized operating conditions of the engine the responses such as brake thermal efficiency, brake specific fuel consumption, carbon monoxide, unburnt hydrocarbons, nitric oxide, and smoke are found to be 31.95%, 0.37 kg/kW h, 0.036%, 5 ppm, 531.23 ppm and 15.35% respectively. It is finally observed from the mathematical models and experimental data that biodiesel methanol blends have maximum efficiency and minimum emissions at optimized engine parameters.

  10. Microbial degradation of palm (Elaeis guineensis biodiesel

    Directory of Open Access Journals (Sweden)

    Giselle Lutz

    2006-03-01

    Full Text Available The kinetics of biodegradation of palm-derived fatty methyl and ethyl esters (Elaeis guineensis biodiesel by a wild-type aerobic bacterial population was measured at 20 °C, as the rate of oxygen uptake by a manometric technique. The methyl and ethyl biodiesels were obtained by potassium-hydroxide catalysed transesterification of palm oil, respectively. The bacterial flora included the genera Bacillus, Proteus, Pseudomonas, Citrobacter and Enterobacter. The rate of oxygen uptake for palm biodiesel is similar to the quantity observed in the biodegradation of 1.0 mM solutions of simple substrates such as carbohydrates or amino acids.Palm methyl or ethyl biodiesel is subjected to facile aerobic biodegradation by wild-type bacteria commonly present in natural open environments. This result should lessen any environmental concern for its use as alternative fuel, solvent or lubricant. Rev. Biol. Trop. 54(1: 59-63.Epub 2006 Mar 31.La cinética de la biodegradación de los ésteres metílicos y etílicos derivados de palma (biodiesel por una población silvestre de bacterias aeróbicas fue medida a 20 °C, como medición manométrica del consumo de oxígeno. Los ésteres metílicos y etílicos se obtuvieron por transesterificación del aceite de palma con metanol y etanol,respectivamente. La flora bacteriana incluyó a los géneros Bacillus, Proteus, Pseudomonas, Citrobacter y Enterobacter. Las velocidades de consumo de oxígeno para las muestras de biodiesel fueron similares a lo observado en la biodegradación de disoluciones 1.0 mM de sustratos sencillos solubles en agua, tales como carbohidratos, aminoácidos y albúmina de huevo.

  11. Isothermal calorimetry of enzymatic biodiesel reaction

    DEFF Research Database (Denmark)

    Fjerbæk Søtoft, Lene; Westh, Peter; Christensen, Knud Villy

    2010-01-01

      Isothermal calorimetry ITC has been used to investigate enzymatic biodiesel production. The transesterification of rapeseed oil with methanol and ethanol was catalyzed by the immobilized lipase Novozym 435 at 40°C. The ITC-experiments clearly demonstrate the possibilities of investigating complex...... and composition change in the system, the heat of reaction at 40°C for the two systems has been determined to -9.8 ± 0.9 kJ/mole biodiesel formed from rapeseed oil and methanol, and - 9.3 ± 0.7 kJ/mole when rapeseed oil and ethanol is used....

  12. Cetane Number of Biodiesel from Karaya Oil

    KAUST Repository

    Wasfi, Bayan

    2017-04-01

    Biodiesel is a renewable fuel alternative to petroleum Diesel, biodiesel has similar characteristic but with lesser exhaust emission. In this study, transesterification of Karaya oil is examined experimentally using a batch reactor at 100-140°C and 5 bar in subcritical methanol conditions, residence time from 10 to 20 minutes, using a mass ratio 6 methanol-to-vegetable oil. Methanol is used for alcoholysis and sodium hydroxide as a catalyst. Experiments varied the temperature and pressure, observing the effect on the yield and reaction time. In addition, biodiesel from corn oil was created and compared to biodiesel from karaya oil. Kinetic model proposed. The model estimates the concentration of triglycerides, diglycerides, monoglycerides and methyl esters during the reaction. The experiments are carried out at temperatures of 100°C and above. The conversion rate and composition of methyl esters produced from vegetable oils are determined by Gas Chromatography Analysis. It was found that the higher the temperature, the higher reaction rate. Highest yield is 97% at T=140°C achieved in 13 minutes, whereas at T=100°C yield is 68% in the same time interval. Ignition Quality Test (IQT) was utilized for determination of the ignition delay time (IDT) inside a combustion chamber. From the IDT cetane number CN inferred. In case of corn oil biodiesel, the IDT = 3.5 mS, leading to a CN = 58. Whereas karaya oil biodiesel showed IDT = 2.4 mS, leading to a CN = 97. The produced methyl esters were also characterized by measurements of viscosity (υ), density (ρ), flash point (FP) and heat of combustion (HC). The following properties observed: For corn biodiesel, υ = 8.8 mPa-s, ρ = 0.863 g/cm3, FP = 168.8 °C, and HC = 38 MJ/kg. For karaya biodiesel, υ = 10 mPa-s, ρ = 0.877 g/cm3, FP = 158.2 °C, and HC = 39 MJ/kg.

  13. MULTIVARIATE REGRESSION MODELS USING INTERVAL SELECTION FOR QUANTIFICATION OF THE BIODIESEL IN BIODIESEL/DIESEL BLENDS

    Directory of Open Access Journals (Sweden)

    Marco Flôres Ferrão

    2010-11-01

    Full Text Available In the present work multivariate regression models using interval partial least square (iPLS and backward interval partial least square (biPLS had been analyzed and compared. iPLS and biPLS models had been developed to determine the concentration of biodiesel in blends of biodiesel/diesel using infrared spectroscopy signals. 45 samples with concentrations in range 8-30% of biodiesel, and two distinct spectrophotometers were used. Both the techniques (iPLS and biPLS using the data obtained by HATR-FTIR if had shown promising to develop simpler, faster and non-destructive methodologies for the biodiesel determination in commercial blends.

  14. Cottonseed oil for biodiesel production; Oleo de algodao para a producao de biodiesel

    Energy Technology Data Exchange (ETDEWEB)

    Pighinelli, Anna L.M.T.; Park, Kil J. [Universidade Estadual de Campinas (UNICAMP), SP (Brazil)], E-mail: annalets@feagri.unicamp.br; Ferrari, Roseli A.; Miguel, Ana M.R.O. [Instituto de Tecnologia de Alimentos (ITAL), Campinas, SP (Brazil)], Emails: roseliferrari@ital.sp.gov.br, anarauen@ital.sp.gov.br, kil@feagri.unicamp.br

    2009-07-01

    Crude cottonseed oil is an alternative for biodiesel production, mostly in Mato Grosso State, where its production is the biggest of Brazil. Even being an acid oil, esterification reaction, followed by transesterification, could make possible the biodiesel production. In this study, crude cottonseed oil obtained from expelled process was reacted to evaluate molar ration and catalyst concentration effects in biodiesel yield. Molar ratio varied from 3 to 15 moles of ethanol to 1 mol of oil, and catalyst, from 1 to 5% by oil mass. Statistic analysis showed that none of studied variables was significant, for the values range. Biodiesel yield had a maximum of 88%, for molar ratio of 4.7 and 4.42% of catalyst concentration. A combination of oil with high free fatty acid content and ethanol as alcohol, affected the separation between esters and glycerol. (author)

  15. Mont-Tremblant biodiesel project : feasibility study; Projet biodiesel Mont-Tremblant : etude de faisabilite

    Energy Technology Data Exchange (ETDEWEB)

    Lagace, C. [Groupe Sine Nomine, Montreal, PQ (Canada); Lamy, V.; Lapointe, L.; Pilon, B. [CEGEP de Saint-Jerome, Saint-Jerome, PQ (Canada). Inst. du transport avance du Quebec, ITAQ

    2008-08-15

    The growing interest in biodiesel can be attributed to concerns regarding climate change, environmental protection and sustainable development. Biodiesel produced from biomass is a renewable energy source that can replace fossil fuels and help reduce greenhouse gas emissions. The City of Mont-Tremblant commissioned a pilot study to determine the feasibility of integrating 20 per cent biodiesel (B20) in city fleet vehicles and school buses. The study focused on the use of biodiesel fuel under winter conditions. The fleet vehicles were analyzed and various strategies for integrating biodiesel mixtures by type and concentration were proposed. The feasibility study also investigated different types of petrodiesel such as Nordic type, seasonal type and kerosene. The effects of an electrical thermal management system were also investigated along with the use of additives. Various laboratory tests were performed in a controlled climate chamber to validate potential solutions. Finally, the study measured the impacts of likely solutions, and proposed 4 different scenarios for the use of biodiesel for the region of Mont-Tremblant. The study showed that it is possible to use B20 year-round, provided that certain conditions are met. The pilot project will also evaluate changes to storage infrastructure that may be needed for storing B20 in winter. 5 tabs., 10 figs., 2 appendices.

  16. Thermodegradation of biodiesel: thermoanalytical and rheological characterization; Degradacao termica de biodiesel: caracterizacao termoanalitica e reologica

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Everson L.; Carvalho, Laura H.; Araujo, Gilmar T.; Gadelha, Tatiana S. [Universidade Federal de Campina Grande (UFCG), PB (Brazil)

    2008-07-01

    Brazil is a country of extensive agricultural land and great oil consumption and these factors favor biodiesel production in this country. In order for diesel/biodiesel mixtures to be effectively employed in diesel engines, a rigid quality control of these mixtures is needed. Biodiesel and mixtures must have their quality monitored with respect to oxidative resistance, thermal stability, fluidity and volatility, properties which can be modified by the adverse transport and stock conditions prior to consumption. Oxidation is the main degradation mechanism of products under transport and stock conditions, which can lead to significant economical losses. In this work sought the thermal degradation of neat biodiesel, synthesized in our laboratories was monitored. Thermal aging was conducted at 210 deg C for up to 1000 h. Virgin and thermally degraded samples were characterized by rheological measurements (in different shear conditions); FTIR; density and by color changes. We concluded that the soy biodiesel was successfully synthesized and that thermal exposure caused thermal-oxidative degradation of the biodiesel sample, significantly changing its properties as a function of thermal exposure times. (author)

  17. Exhaust gas emissions and mutagenic effects of modern diesel fuels, GTL, biodiesel and biodiesel blends

    Energy Technology Data Exchange (ETDEWEB)

    Munack, Axel; Ruschel, Yvonne; Schroeder, Olaf [Federal Research Institute for Rural Areas, Forestry and Fisheries, Braunschweig (Germany)], E-mail: axel.munack@vti.bund.de; Krahl, Juergen [Coburg Univ. of Applied Sciences (Germany); Buenger, Juergen [University of Bochum (Germany)

    2008-07-01

    Biodiesel can be used alone (B100) or blended with petroleum diesel in any proportion. The most popular biodiesel blend in the U.S.A. is B20 (20% biodiesel, 80% diesel fuel), which can be used for Energy Policy Act of 1992 (EPAct) compliance. In the European Union, the use of biofuel blends is recommended and was introduced by federal regulations in several countries. In Germany, biodiesel is currently blended as B5 (5% biodiesel) to common diesel fuel. In 2008, B7 plus three percent hydrotreated vegetable oil (HVO) as well is intended to become mandatory in Germany. To investigate the influence of blends on the emissions and possible health effects, we performed a series of studies with several engines (Euro 0, III and IV) measuring regulated and non-regulated exhaust compounds and determining their mutagenic effects. Emissions of blends showed an approximate linear dependence on the blend composition, in particular when regulated emissions are considered. However, a negative effect of blends was observed with respect to mutagenicity of the exhaust gas emissions. In detail, a maximum of the mutagenic potency was found in the range of B20. From this point of view, B20 must be considered as a critical blend, in case diesel fuel and biodiesel are used as binary mixtures. (author)

  18. Thermodegradation of biodiesel: thermoanalytical and rheological characterization; Degradacao termica de biodiesel: caracterizacao termoanalitica e reologica

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Everson L.; Carvalho, Laura H.; Araujo, Gilmar T.; Gadelha, Tatiana S. [Universidade Federal de Campina Grande (UFCG), PB (Brazil)

    2008-07-01

    Brazil is a country of extensive agricultural land and great oil consumption and these factors favor biodiesel production in this country. In order for diesel/biodiesel mixtures to be effectively employed in diesel engines, a rigid quality control of these mixtures is needed. Biodiesel and mixtures must have their quality monitored with respect to oxidative resistance, thermal stability, fluidity and volatility, properties which can be modified by the adverse transport and stock conditions prior to consumption. Oxidation is the main degradation mechanism of products under transport and stock conditions, which can lead to significant economical losses. In this work sought the thermal degradation of neat biodiesel, synthesized in our laboratories was monitored. Thermal aging was conducted at 210 deg C for up to 1000 h. Virgin and thermally degraded samples were characterized by rheological measurements (in different shear conditions); FTIR; density and by color changes. We concluded that the soy biodiesel was successfully synthesized and that thermal exposure caused thermal-oxidative degradation of the biodiesel sample, significantly changing its properties as a function of thermal exposure times. (author)

  19. KINETIKA TRANSESTERIFIKASI BIODIESEL JARAK PAGAR

    Directory of Open Access Journals (Sweden)

    Buchori Luqman

    2012-07-01

    Full Text Available Biodiesel were produced by trans-etherification of castor oil with alcohol in the presence of NaOH catalyst. Thereaction mechanism and model of castor oil trans-etherification isA + 3B C + 3 DA, B, C, and D were castor oil, alcohol, glycerol, and ester. The reaction rate equation was r=-dCA/dt =k1(CA(CB3–k2(CC(CD3. In this study was used two measurement method of free fat acid as the rest content ofcastor oil with SNI 01-3555-1998 and AOAC (Association of Analytical Chemist. It found that SNI 01-3555-1998 method was the easier and the acurate measurement. The classification of alcohol used was methanol andethanol to compare the action both of them. Methanol produces the higher conversion than ethanol. The reactionin a batch reactor with temperature 40, 50, and 60°C in atmospheric pressure as the operation condition tolooking for kinetics parameter of trans-etherification. Coefficient reaction rate and activation energy were lookinto kinetics study. Reaction rate was a mathematics model as a function of concentration and time which solvedby Runge-Kutta, multivariable optimization and SSE (some square error method using Matlab. The activationenergy (Ea and impact factor (A obtained by linier regression method. The result of study obtained the kineticsparameter of trans-etherification with methanol k1=1.9313x1031exp (-41.940/RT average error 0.0010 andk2=2.7678x1025exp(-37.362/ RT average error 0.0003. While kinetics parameter of trans-etherification withethanol obtained k1=1.168x1019exp(-24.588/ RT average error 0.0306 and k2=4.9966x106exp(-10.328/RTaverage error 0.1589. It means, more reactive alcohol then bigger the value of kinetics parameter.

  20. Experimental study of DI diesel engine performance using biodiesel blends with kerosene

    Energy Technology Data Exchange (ETDEWEB)

    Azad, A.K.; Ameer Uddin, S.M.; Alam, M.M. [Department of Mechanical Engineering, Bangladesh University of Engineering and Technology, Dhaka-1000 (Bangladesh)

    2013-07-01

    The experimental investigation offers a comprehensive study of DI diesel engine performance using bio-diesel from mustard oil blends with kerosene. The vegetable oil without trans-esterification reaction have been blended with kerosene oil by volume in some percentage like 20%, 30%, 40% and 50% which have been named as M20 (20% mustard, 80% kerosene), M30 (30% mustard, 70% kerosene), M40 (40% mustard, 60% kerosene) and M50 (50% mustard, 50% kerosene). The properties of the bio-fuel blended with kerosene have been tested in the laboratories with maintaining different ASTM standards. Then a four stroke, single cylinder, direct injection diesel engine has been mounted on the dynamometer bed for testing the performance of the engine using the bio-diesel blends. Several engine parameters like bsfc, bhp, break mean effective pressure, exhaust gas temperature, lube oil temperature, sound level etc. have been determined. A comparison has been made for engine performance of different bio-diesel blends with kerosene with the engine performance of diesel fuel.

  1. Role of biodiesel with nanoadditives in port owned trucks and other vehicles for emission reduction

    Directory of Open Access Journals (Sweden)

    Misra Atulya

    2017-01-01

    Full Text Available Biodiesel is presently available all over the world and can be produced from several types of biomass. Biodiesel fuels are gaining more and more importance as an attractive alternate fuel in various transport sectors due to their renewable nature and lower pollution impact. However, the ports and the shipping sector are still in the early stage of orientation towards biofuels. In the present work, an experimental investigation on the use of diesterol blend (a mixture of diesel, ethanol with biodiesel with cerium oxide as a nanoadditive (D80JBD15E4S1 + cerium oxide in a compression ignition engine is performed to assess the emission characteristics. The results reveal that the presence of the cerium oxide nanoparticle changes the reaction patterns and heat transfer rate that reduces both the CO and CO2 percentage concentration in the exhaust gas appreciably. Further, the reduction in CO2 emission in the port of Chennai is quantified considering the replacement of neat diesel with those of modified diesel blend in port owned trucks and vehicles.

  2. Recent Strategy of Biodiesel Production from Waste Cooking Oil and Process Influencing Parameters: A Review

    Directory of Open Access Journals (Sweden)

    A. Gnanaprakasam

    2013-01-01

    Full Text Available Cost of biodiesel produced from virgin vegetable oil through transesterification is higher than that of fossil fuel, because of high raw material cost. To minimize the biofuel cost, in recent days waste cooking oil was used as feedstock. Catalysts used in this process are usually acids, base, and lipase. Since lipase catalysts are much expensive, the usage of lipase in biodiesel production is limited. In most cases, NaOH is used as alkaline catalyst, because of its low cost and higher reaction rate. In the case of waste cooking oil containing high percentage of free fatty acid, alkaline catalyst reacts with free fatty acid and forms soap by saponification reaction. Also, it reduces the biodiesel conversions. In order to reduce the level of fatty acid content, waste cooking oil is pretreated with acid catalyst to undergo esterification reaction, which also requires high operating conditions. In this review paper, various parameters influencing the process of biofuel production such as reaction rate, catalyst concentration, temperature, stirrer speed, catalyst type, alcohol used, alcohol to oil ratio, free fatty acid content, and water content have been summarized.

  3. Kinetic studies and thermodynamics of oil extraction and transesterification of Chlorella sp. for biodiesel production.

    Science.gov (United States)

    Ahmad, A L; Yasin, N H Mat; Derek, C J C; Lim, J K

    2014-01-01

    In this work, a mixture of chloroform and methanol (1:1, v/v) was applied to oil extraction from Chlorella sp. at 30, 40, 50 and 60 degrees C for 150 min extraction times. Kinetic studies revealed that the values of n and the rate constants were found to depend strongly on temperature. The activation energy was Ea = 38.893 kJ/mol, and the activation thermodynamic parameters at 60 degrees C were ΔS≠ = -180.190 J/mol , ΔH≠ = 36.124k J/mol and ΔG≠ = 96.128k J/mol. Both ΔH and ΔS yielded positive values, whereas ΔG was negative at 60 degrees C, indicating that this process is endothermic, irreversible and spontaneous. The acidic transesterification process was also investigated by gas chromatographic analysis of the microalgae fatty acid methyl esters (biodiesel) at different temperatures and reaction times. The fatty acid profile indicated that the main components were palmitic, linoleic and linolenic acids. The concentration of linolenic acid increased and oleic acid decreased as the temperature increased. Two-hour transesterification is the best reaction time for biodiesel production because it produces the highest percentage of unsaturated fatty acids (74%). These results indicate the potential of Chlorella sp. to produce biodiesel of good quality.

  4. Experimental investigation on CRDI engine using butanol-biodiesel-diesel blends as fuel

    Science.gov (United States)

    Divakar Shetty, A. S.; Dineshkumar, L.; Koundinya, Sandeep; Mane, Swetha K.

    2017-07-01

    In this research work an experimental investigation of butanol-biodisel-diesel blends on combustion, performance and emission characteristics of a direct injection (DI) diesel engine is carried out. The blends are prepared at different proportions and fuel properties such as calorific value, viscosity, flash point and fire point, cloud point, pour point of butanol (B), biodiesel (B), diesel (D), biodiesel-diesel (BD) blends and butanol-biodiesel-diesel (BBD) blends are determined. The engine test is conducted at different speed and load. From the results obtained for fuel properties we can observe that the flash, fire and pour point, viscosity and density are decreasing by increasing the percentage of butanol in BBD blends. It is also observed that the performance parameters such as brake thermal efficiency (BTE) and exhaust gas temperature increases with increase in the proportion of butanol in BBD blend. However, the brake specific fuel consumption (BFSC) decreases with increase in the proportion of butanol in BBD blend. The increase of butanol in BBD blends also influence to increase on emission characteristic such as carbon monoxide (CO), hydrocarbon (HC) and oxides of nitrogen (NOx).

  5. Performance Evaluation of Palm Oil-Based Biodiesel Combustion in an Oil Burner

    Directory of Open Access Journals (Sweden)

    Abdolsaeid Ganjehkaviri

    2016-02-01

    Full Text Available This paper presents an experimental investigation of the combustion characteristics of palm methyl ester (PME, also known as palm oil-based biodiesel, in an oil burner system. The performance of conventional diesel fuel (CDF and various percentages of diesel blended with palm oil-based biodiesel is also studied to evaluate their performance. The performance of the various fuels is evaluated based on the temperature profile of the combustor’s wall and emissions, such as nitrogen oxides (NOx and carbon monoxide (CO. The combustion experiments were conducted using three different oil burner nozzles (1.25, 1.50 and 1.75 USgal/h under lean (equivalence ratio (Φ = 0.8, stoichiometric (Φ = 1 and rich fuel (Φ = 1.2 ratio conditions. The results show that the rate of emission formation decreases as the volume percent of palm biodiesel in a blend increases. PME combustion tests present a lower temperature inside the chamber compared to CDF combustion. High rates of NOx formation occur under lean mixture conditions with the presence of high nitrogen and sufficient temperature, whereas high CO occurs for rich mixtures with low oxygen presence.

  6. Scum sludge as a potential feedstock for biodiesel production from wastewater treatment plants.

    Science.gov (United States)

    Wang, Yi; Feng, Sha; Bai, Xiaojuan; Zhao, Jingchan; Xia, Siqing

    2016-01-01

    The main goal of this study was to compare the component and yield of biodiesel obtained by different methods from different sludge in a wastewater treatment plant. Biodiesel was produced by ex-situ and in-situ transesterification of scum, primary and secondary sludge respectively. Results showed that scum sludge had a higher calorific value and neutral lipid than that of primary and secondary sludge. The lipid yield accounted for one-third of the dried scum sludge and the maximum yield attained 22.7% under in-situ transesterification. Furthermore the gas chromatography analysis of fatty acid methyl esters (FAMEs) revealed that all sludge contained a significant amount of palmitic acid (C16:0) and oleic acid (C18:1) regardless of extraction solvents and sludge types used. However, the difference lay in that oleic acid methyl ester was the dominant component in FAMEs produced from scum sludge while palmitic acid methyl ester was the dominant component in FAMEs from primary and secondary sludge. In addition, the percentage of unsaturated fatty acid ester in FAMEs from scum sludge accounted for 57.5-64.1% of the total esters, which was higher than the equivalent derived from primary and secondary sludge. In brief, scum sludge is a potential feedstock for the production of biodiesel and more work is needed in the future.

  7. Acute aqueous toxicities of diesel-biodiesel blends

    Energy Technology Data Exchange (ETDEWEB)

    Hollebone, B.P.; Ho, N.; Landriault, M. [Environment Canada, Ottawa, ON (Canada). Emergencies Science and Technology Division, Science and Technology Branch, Environmental Science and Technology Centre; Harrison, S. [Science Applications International Corp., SAIC Canada, Ottawa, ON (Canada); Doe, K.; Jackman, P. [Environment Canada, Moncton, NB (Canada). Toxicology Laboratory, Environmental Science Centre

    2008-07-01

    The renewed interest in biodiesels as a new transportation fuel was discussed. Although there are several advantages to using biodiesels, their environmental behaviours and effects need to be evaluated along with the risks associated with their use, such as accidental releases of these biodiesels to the environment. The wide variability of biodiesels may result in different toxicological impacts, depending on the fuel feedstock. This study evaluated the aqueous effects of biodiesels from several commonly available feedstocks and their blends with petroleum diesel. Since most of the commercial uses of these products are currently focused on road-use, this study focused on the effects of these fuels in fresh-water. Biodiesels derived from soy, canola and waste restaurant oil feedstocks were used in the study. The acute toxicities of these biodiesels and biodiesel/petroleum diesel fuel blends were reported for 3 test species used by Environment Canada for toxicological evaluation, notably rainbow trout, the water flea, and a luminescent bacterium. The correlations between acute toxicity, water accommodated fractions (WAF) concentrations and fuel property data were examined. The study revealed that biodiesel is significantly less acutely toxic than petroleum diesels in potential ecological impacts. However, the biodiesel-diesel blends were found to be more acutely toxic than a linear dilution model predicts. 11 refs., 6 tabs., 3 figs.

  8. Profitability and sustainability of small - medium scale palm biodiesel plant

    Science.gov (United States)

    Solikhah, Maharani Dewi; Kismanto, Agus; Raksodewanto, Agus; Peryoga, Yoga

    2017-06-01

    The mandatory of biodiesel application at 20% blending (B20) has been started since January 2016. It creates huge market for biodiesel industry. To build large-scale biodiesel plant (> 100,000 tons/year) is most favorable for biodiesel producers since it can give lower production cost. This cost becomes a challenge for small - medium scale biodiesel plants. However, current biodiesel plants in Indonesia are located mainly in Java and Sumatra, which then distribute biodiesel around Indonesia so that there is an additional cost for transportation from area to area. This factor becomes an opportunity for the small - medium scale biodiesel plants to compete with the large one. This paper discusses the profitability of small - medium scale biodiesel plants conducted on a capacity of 50 tons/day using CPO and its derivatives. The study was conducted by performing economic analysis between scenarios of biodiesel plant that using raw material of stearin, PFAD, and multi feedstock. Comparison on the feasibility of scenarios was also conducted on the effect of transportation cost and selling price. The economic assessment shows that profitability is highly affected by raw material price so that it is important to secure the source of raw materials and consider a multi-feedstock type for small - medium scale biodiesel plants to become a sustainable plant. It was concluded that the small - medium scale biodiesel plants will be profitable and sustainable if they are connected to palm oil mill, have a captive market, and are located minimally 200 km from other biodiesel plants. The use of multi feedstock could increase IRR from 18.68 % to 56.52 %.

  9. The Current Status of Biodiesel Production Technology: A Review

    Directory of Open Access Journals (Sweden)

    Rizal Alamsyah

    2007-12-01

    Full Text Available Biodiesel is addressed to the name of fuel which consist of mono-alkyl ester that made from renewable and biodegradable resources, such as oils from plants (vegetable oils, waste or used cooking oil, and animal fats. Such oils or fats are chemically reacted with alcohols or methanol In producing chernical compounds called fatty acid methyl ester (FAME and these reactions are called transesterification and esterification. Glycerol, used in the pharmaceutical and cosmetics industry is produced from biodiesel production as a by-product. Researches on biodiesel as an alternative petroleum diesel have been done for more than 20 years. Transesterification reaction can be acid-catalyzed, alkali-catatyzed, or enzyme-catalyzed. Commercially biodiesel is processed by transesterification with alkali catalyst. This process, however, requires refining of products and recovery of catalysts, Such biodiesel production accelerates researches on biodiesel to obtain simpler methods, better quality. and minimum production cost. Besides the catalytic production for biodiesel, there is a method for biodiesel production namely non-catalytic production. Non-catalytic transesterification method was developed since catalytic tranestertfification still has two main problems assoclated With long reaction time and complicated purification. The first problem occurres because of the two phase nature of vegetable oil/methanol mixture, and the last problem is due to purification of catalyst and glycerol. The application of catalytic tranestertfication method leads to condition of high biodiesel production cost and high energy consumption. This paper provides information of biodiesel production progress namely catalytic tranestertfification (acid, alkali, and enzymatic tranesterfification, and non-catalytic tranesterification (at sub-critical­-supercritical temperature under pressurized conditions. It was found that every method of biodiesel production still has advantages and

  10. Production and application of biodiesel from waste cooking oil

    Science.gov (United States)

    Tuly, S. S.; Saha, M.; Mustafi, N. N.; Sarker, M. R. I.

    2017-06-01

    Biodiesel has been identified as an alternative and promising fuel source to reduce the dependency on conventional fossil fuel in particular diesel. In this work, waste cooking oil (WCO) of restaurants is considered to produce biodiesel. A well-established transesterification reaction by sodium hydroxide (NaOH) catalytic and supercritical methanol (CH3OH) methods are applied to obtain biodiesel. In the catalytic transesterification process, biodiesel and glycerine are simultaneously produced. The impact of temperature, methanol/WCO molar ratio and sodium hydroxide concentration on the biodiesel formation were analysed and presented. It was found that the optimum 95% of biodiesel was obtained when methanol/WCO molar ratio was 1:6 under 873 K temperature with the presence of 0.2% NaOH as a catalyst. The waste cooking oil blend proportions were 10%, 15%, 20% and 25% and named as bio-diesel blends B-10, B-15, B-20, and B-25, respectively. Quality of biodiesel was examined according to ASTM 6751: biodiesel standards and testing methods. Important fuel properties of biodiesel, such as heating value, cetane index, viscosity, and others were also investigated. A four-stroke single cylinder naturally aspirated DI diesel engine was operated using in both pure form and as a diesel blend to evaluate the combustion and emission characteristics of biodiesel. Engine performance is examined by measuring brake specific fuel consumption and fuel conversion efficiency. The emission of carbon monoxide (CO), carbon dioxide (CO2), nitrogen oxides (NOx), and others were measured. It was measured that the amount of CO2 increases and CO decreases both for pure diesel and biodiesel blends with increasing engine load. However, for same load, a higher emission of CO2 from biodiesel blends was recorded than pure diesel.

  11. Isothermal calorimetry of enzymatic biodiesel reaction

    DEFF Research Database (Denmark)

    Fjerbæk Søtoft, Lene; Westh, Peter; Christensen, Knud Villy

    2010-01-01

      Isothermal calorimetry ITC has been used to investigate enzymatic biodiesel production. The transesterification of rapeseed oil with methanol and ethanol was catalyzed by the immobilized lipase Novozym 435 at 40°C. The ITC-experiments clearly demonstrate the possibilities of investigating complex...

  12. Environmental Sustainability Analysis of Biodiesel Production

    DEFF Research Database (Denmark)

    Herrmann, Ivan Tengbjerg; Hauschild, Michael Michael Zwicky; Birkved, Morten

    like these require a life cycle perspective on the biofuel - from the cradle (production of the agricultural feedstock) to the grave (use as fuel). An environmental life cycle assessment is performed on biodiesel to compare different production schemes including chemical and enzymatic esterification...

  13. Jatropha bio-diesel production and use

    Energy Technology Data Exchange (ETDEWEB)

    Achten, W.M.J.; Aerts, R.; Muys, B. [Katholieke Universiteit Leuven, Division Forest, Nature and Landscape, Celestijnenlaan 200 E Box 2411, BE-3001 Leuven (Belgium); Verchot, L. [World Agroforestry Centre (ICRAF) Head Quarters, United Nations Avenue, P.O. Box 30677, Nairobi (Kenya); Franken, Y.J. [FACT Foundation, Horsten 1, 5612 AX Eindhoven (Netherlands); Mathijs, E. [Katholieke Universiteit Leuven, Division Agricultural and Food Economics, Willem de Croylaan 42 Box 2424, BE-3001 Leuven (Belgium); Singh, V.P. [World Agroforestry Centre (ICRAF) Regional Office for South Asia, CG Block, 1st Floor, National Agricultural Science Centre, Dev Prakash Shastri Marg, Pusa, New Delhi 110 012 (India)

    2008-12-15

    The interest in using Jatropha curcas L. (JCL) as a feedstock for the production of bio-diesel is rapidly growing. The properties of the crop and its oil have persuaded investors, policy makers and clean development mechanism (CDM) project developers to consider JCL as a substitute for fossil fuels to reduce greenhouse gas emissions. However, JCL is still a wild plant of which basic agronomic properties are not thoroughly understood and the environmental effects have not been investigated yet. Gray literature reports are very optimistic on simultaneous wasteland reclamation capability and oil yields, further fueling the Jatropha bio-diesel hype. In this paper, we give an overview of the currently available information on the different process steps of the production process of bio-diesel from JCL, being cultivation and production of seeds, extraction of the oil, conversion to and the use of the bio-diesel and the by-products. Based on this collection of data and information the best available practice, the shortcomings and the potential environmental risks and benefits are discussed for each production step. The review concludes with a call for general precaution and for science to be applied. (author)

  14. Hydrotreatment of Oils and Fats for Biodiesel

    DEFF Research Database (Denmark)

    Madsen, Anders Theilgaard; Riisager, Anders; Fehrmann, Rasmus

    The use of renewable biofuels in the transport sector represents an important step towards a sustainable society. Biodiesel is currently produced by the transesterification of fats and oils with methanol, but another viable method could be reaction of the feedstock with H2 to produce long...

  15. Uncertainties in the Bidirectional Biodiesel Supply Chain

    NARCIS (Netherlands)

    Bot, Pieter; van Donk, Dirk Pieter; Pennink, Bartjan; Simatupang, Togar M.

    2015-01-01

    For remote areas, small-scale local biodiesel production is particularly attractive if producers and consumers are the same. Such supply chains are labeled as bidirectional. However, little is known on how raw material supply, transportation, logistics, production and operations uncertainties impact

  16. Lipases as biocatalysts for biodiesel production

    Directory of Open Access Journals (Sweden)

    Ognjanović Nevena D.

    2010-01-01

    Full Text Available Lipases can be used for a variety of biotechnological applications: synthesis of fine chemicals, therapeutics, agrochemicals, cosmetics, flavors, biopolymers and biodiesel. Biodiesel is an alternative fuel for diesel engines that is environmentally acceptable. Conventionally, biodiesel is produced by transesterification of triglycerides and short chain alcohols in the presence of an acid or an alkaline catalyst. There are several problems associated with this kind of production that can be resolved by using lipase as the biocatalyst. The usage of lipases has several advantages over the conventional chemical methods. It is considered as less energy intensive and environmentally friendly. However, there are two main obstacles associated with the effective utilization of lipases in the production of biodiesel. The main one is the cost of the enzyme and its poor stability in the presence of excess alcohol. Several strategies are proposed to overcome these drawbacks: immobilization of lipases, stepwise addition of alcohol, and the usage of novel acyl acceptors and the usage of whole cell biocatalysts.

  17. Characterization of residual oils for biodiesel production

    Directory of Open Access Journals (Sweden)

    Edmilson Antonio Canesin

    2014-01-01

    Conclusions: The obtained results suggesting that it is possible to take advantage of these residues for biodiesel production as the obtained products were approved according to the rules established by the National Association of Petroleum (ANP; the bovine samples were the exception regarding moisture and acidity.

  18. WI Biodiesel Blending Progream Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Redmond, Maria E; Levy, Megan M

    2013-04-01

    The Wisconsin State Energy Office's (SEO) primary mission is to implement cost effective, reliable, balanced, and environmentally friendly clean energy projects. To support this mission the Wisconsin Biodiesel Blending Program was created to financially support the installation infrastructure necessary to directly sustain biodiesel blending and distribution at petroleum terminal facilities throughout Wisconsin. The SEO secured a federal directed award of $600,000 over 2.25 years. With these funds, the SEO supported the construction of inline biodiesel blending facilities at two petroleum terminals in Wisconsin. The Federal funding provided through the state provided a little less than half of the necessary investment to construct the terminals, with the balance put forth by the partners. Wisconsin is now home to two new biodiesel blending terminals. Fusion Renewables on Jones Island (in the City of Milwaukee) will offer a B100 blend to both bulk and retail customers. CITGO is currently providing a B5 blend to all customers at their Granville, WI terminal north of the City of Milwaukee.

  19. Influence of Antioxidant Addition in Jatropha Biodiesel on the Performance, Combustion and Emission Characteristics of a DI Diesel Engine

    Science.gov (United States)

    Arockiasamy, Prabu; Ramachandran Bhagavathiammal, Anand

    2017-04-01

    An experimental investigation is conducted on a single-cylinder DI diesel engine, to evaluate the performance, combustion and emission characteristics of Jatropha biodiesel with the addition of antioxidants namely, Succinimide (C4H5NO2), N,N-Dimethyl p-phenylenediamine dihydrochloride (C8H14Cl2N2) and N-Phenyl-p-phenylenediamine (C6H5NHC6H4NH2) at 500, 1000 and 2000 ppm. The performance, combustion and emission characteristic tests are conducted at a constant speed of 1500 rpm, injection pressure of 215 bar, injection timing of 26° before top dead centre for the nine test fuels and the experimental results are compared with neat diesel and neat biodiesel as base fuels. The experimental results show that the addition of antioxidant in biodiesel suppresses the NO emission by quenching the OH radicals that are produced by the reaction of hydrocarbon radicals with molecular nitrogen. The maximum percentage reduction of NO emission by 5, 6 and 7% are observed for N-Phenyl-p-phenylenediamine, N,N-Dimethyl p-phenylenediamine dihydrochloride and Succinimide blended test fuels at 2000 ppm antioxidant addition with biodiesel.

  20. Study on the lubrication properties of biodiesel as fuel lubricity enhancers

    Energy Technology Data Exchange (ETDEWEB)

    Jianbo Hu; Zexue Du; Changxiu Li; Enze Min [Research Institute of Petroleum Processing, SINOPEC, Beijing (China)

    2005-09-01

    Unrefined biodiesels containing small quantities of monoglycerides, diglycerides, and triglycerides, and refined biodiesels not containing these glycerides were added to diesel fuel and the resulting lubricity was measured using the High Frequency Reciprocating Rig (HFRR) method. The unrefined biodiesels showed higher lubricity properties than refined biodiesels. The chemical factors influencing the lubricity properties of biodiesels were investigated. Methyl esters and monoglycerides are the main compositions that determine the lubricity of biodiesels that meet international standards. Free fatty acids and diglycerides can also affect the lubricity of biodiesel, but not so much as monoglycerides. Triglycerides almost have no effects on the lubricity of biodiesel. 18 refs., 3 figs., 5 tabs.

  1. Microtox aquatic toxicity of petrodiesel and biodiesel blends: the role of biodiesel's autoxidation products.

    Science.gov (United States)

    Yassine, Mohamad H; Wu, Shuyun; Suidan, Makram T; Venosa, Albert D

    2012-12-01

    The acute Microtox toxicity of the water accommodated fraction (WAF) of six commercial soybean biodiesel/petrodiesel blends was investigated at different oil loads. We analyzed five fatty acid methyl esters (FAMEs), C10-C24 n-alkanes, four aromatics, methanol, and total organic carbon (TOC) content. At high oil loads, the WAFs' toxicity was significantly higher for blends containing biodiesel. At the lowest load, the WAFs' toxicity decreased almost linearly with decreasing biodiesel in the blend. At intermediate loads, the WAFs of all the blends appeared to have a similar toxicity. Analysis of WAFs confirmed the presence of autoxidation byproducts of FAMEs at high oil loads. Pure unsaturated FAMEs and n-alkanes were nontoxic when present in water at their reported solubility limits. However, 24-h equilibrated WAFs of pure FAMEs were highly toxic for C18:1 and C18:3, but not for C18:2. The authors concluded that at high oil loads, the acute toxicity of the WAFs was caused by FAMEs' autoxidation byproducts, whereas at low oil loads, the toxicity appeared to be caused primarily by the aromatic compounds present in petrodiesel. The addition of a synthetic antioxidant in biodiesel did not appear to affect the concentration of autoxidation byproducts in the WAF but resulted in a slight decrease in its toxicity. The major autoxidation byproducts identified in the WAF of commercial biodiesel were present neither in the WAFs of pure unsaturated FAMEs nor in the WAF of a different soybean biodiesel that was transesterified in our laboratory, which was nontoxic. We concluded that the process of transesterification of biodiesel might be a more critical factor in determining the aquatic toxicity of the fuel than the source of feedstock itself. Copyright © 2012 SETAC.

  2. An updated comprehensive techno-economic analysis of algae biodiesel.

    Science.gov (United States)

    Nagarajan, Sanjay; Chou, Siaw Kiang; Cao, Shenyan; Wu, Chen; Zhou, Zhi

    2013-10-01

    Algae biodiesel is a promising but expensive alternative fuel to petro-diesel. To overcome cost barriers, detailed cost analyses are needed. A decade-old cost analysis by the U.S. National Renewable Energy Laboratory indicated that the costs of algae biodiesel were in the range of $0.53-0.85/L (2012 USD values). However, the cost of land and transesterification were just roughly estimated. In this study, an updated comprehensive techno-economic analysis was conducted with optimized processes and improved cost estimations. Latest process improvement, quotes from vendors, government databases, and other relevant data sources were used to calculate the updated algal biodiesel costs, and the final costs of biodiesel are in the range of $0.42-0.97/L. Additional improvements on cost-effective biodiesel production around the globe to cultivate algae was also recommended. Overall, the calculated costs seem promising, suggesting that a single step biodiesel production process is close to commercial reality.

  3. Biodiesel production with special emphasis on lipase-catalyzed transesterification.

    Science.gov (United States)

    Bisen, Prakash S; Sanodiya, Bhagwan S; Thakur, Gulab S; Baghel, Rakesh K; Prasad, G B K S

    2010-08-01

    The production of biodiesel by transesterification employing acid or base catalyst has been industrially accepted for its high conversion and reaction rates. Downstream processing costs and environmental problems associated with biodiesel production and byproducts recovery have led to the search for alternative production methods. Recently, enzymatic transesterification involving lipases has attracted attention for biodiesel production as it produces high purity product and enables easy separation from the byproduct, glycerol. The use of immobilized lipases and immobilized whole cells may lower the overall cost, while presenting less downstream processing problems, to biodiesel production. The present review gives an overview on biodiesel production technology and analyzes the factors/methods of enzymatic approach reported in the literature and also suggests suitable method on the basis of evidence for industrial production of biodiesel.

  4. Performance characteristics of mix oil biodiesel blends with smoke emissions

    OpenAIRE

    Sanjay Mohite; Sudhir Kumar; Sagar Maji

    2016-01-01

    Fossil fuel resources are being depleted day by day and its use affects the environment adversely. Renewable energy is one of the alternate for sustainable development and biodiesel is one of the suitable alternate which can replace the diesel. The major hurdles in the successful commercialization of biodiesel are high feedstock cost and conversion technology to reduce viscosity. The choice of raw material and biodiesel production method must depend upon techno-economical view. There are some...

  5. Combustion and Performance Characteristics of CI Engine Running with Biodiesel

    OpenAIRE

    Tesfa, Belachew; Mishra, Rakesh; Gu, Fengshou; Ball, Andrew

    2013-01-01

    Biodiesel is one of the alternative fuels which is renewable and environmentally friendly and can be used in diesel engines with little or no modifications. In the present study, experimental investigations were carried out on the effects of biodiesel types, biodiesel fraction and physical properties on the combustion and performance characteristics of a compression ignition (CI) engine. The experimental work was conducted on a four-cylinder, four -stroke, direct injection (DI) and turbocharg...

  6. Potential use of eucalyptus biodiesel in compressed ignition engine

    OpenAIRE

    Puneet Verma; Mahendra Pal Sharma; Gaurav Dwivedi

    2016-01-01

    The increased population has resulted in extra use of conventional sources of fuels due to which there is risk of extinction of fossil fuels’ resources especially petroleum diesel. Biodiesel is emerging as an excellent alternative choice across the world as a direct replacement for diesel fuel in vehicle engines. Biodiesel offers a great choice. It is mainly derived from vegetable oils, animal fats and algae. Hence in this paper effort has been made to find out feasibility of biodiesel obtain...

  7. Pembuatan Biodiesel Dari Minyak Nyamplung Menggunakan Pemanasan Gelombang Mikro

    Directory of Open Access Journals (Sweden)

    Fatih Ridho Muhammad

    2014-09-01

    Full Text Available Energi fosil yang selama ini menjadi tumpuan penduduk seluruh dunia, jumlahnya semakin menipis dari waktu ke waktu. Peran minyak bumi dalam penyediaan energi nasional pun masih dominan. Sekitar 53% kebutuhan energi nasional dipenuhi dari minyak bumi. Oleh karena itu, pencarian energi alternatif pengganti minyak bumi harus dikembangkan, salah satunya biodiesel. Penggunaan microwave sebagai sumber energi pembuatan biodiesel dapat mempercepat waktu reaksi. Sehingga microwave dipandang lebih efisien. Biji nyamplung (Calophyllum inophyllum memiliki kandungan minyak sebesar 60,1% berat. Dengan kandungan minyak sebesar ini maka biji nyamplung memiliki potensi yang besar bila digunakan sebagai bahan baku pembuatan biodiesel. Nyamplung tersebar luas di pantai-pantai Indonesia. Tujuan penelitian ini adalah untuk mensintesa biodiesel dari minyak mentah nyamplung (Callophyluminophyllum dengan proses trans-esterifikasi dengan menggunakan microwave, mempelajari daya optimal dalam pembuatan biodiesel, mempelajari jumlah katalis yang dibutuhkan untuk mendapatkan biodiesel yang paling baik, mempelajari yield biodiesel yang dihasilkan serta mempelajari pengaruh penambahan ratio mol minyak-metanol terhadap kualitas biodiesel yang dihasilkan. Langkah awal pembuatan biodiesel nyamplung adalah proses degumming atau penghilangan impurities seperti getah, kemudian dilanjutkan dengan esterifikasi yang bertujuan untuk mengubah free fatty acid (FFA menjadi metil ester. Setelah esterifikasi, larutan dititrasi dengan NaOH dan indicator pp hingga konsentrasi FFA menjadi < 2%. Kemudian masuk proses trans-esterifikasi yang merubah trigliserida dalam minyak menjadi metil ester dan gliserol. Proses selanjutnya adalah pemisahan biodiesel dan gliserol dan terakhir proses pencucian. Variabel percobaan adalah kadar katalis CaO 2, 3, 4, 5, dan 6% berat minyak. Ratio mol minyak-metanol 1:9 dan 1:12. Variabel terakhir adalah daya microwave sebesar 100W, 264W dan 400W. Dari hasil

  8. Effectiveness of Low Temperature Additives for Biodiesel Blends

    Science.gov (United States)

    2012-06-30

    UNCLASSIFIED EFFECTIVENESS OF LOW TEMPERATURE ADDITIVES FOR BIODIESEL BLENDS INTERIM REPORT TFLRF No. 428 by Steven R...Do not return it to the originator. UNCLASSIFIED UNCLASSIFIED EFFECTIVENESS OF LOW TEMPERATURE ADDITIVES FOR BIODIESEL BLENDS...17-2010 – 06-30-2012 4. TITLE AND SUBTITLE Effectiveness of Low Temperature Additives for Biodiesel Blends 5a. CONTRACT NUMBER W56HZV-09-C-0100

  9. Optimization of emergy sustainability index for biodiesel supply network design

    DEFF Research Database (Denmark)

    Ren, Jingzheng; Tan, Shiyu; Yang, Le

    2015-01-01

    sustainable design. In the proposed model, the emergy sustainability index of the whole biodiesel supply networks in a life cycle perspective is employed as the measure of the sustainability, and multiple feedstocks, multiple transport modes, multiple regions for biodiesel production and multiple distribution...... centers can be considered. After describing the process and mathematic framework of the model, an illustrative case was studied and demonstrated that the proposed methodology is feasible for finding the most sustainable design and planning of biodiesel supply chains....

  10. Biodiesel Production Using Wet and Dry Purification Methods

    OpenAIRE

    DEMIR, Veli Gokhan

    2017-01-01

    Inbiodiesel production via transesterification, after removing glycerol fromcrude biodiesel, purification process must be performed before using biodieselas a fuel that meets the EN 14214 standard. In the literature, variousprocesses are presented for purification of biodiesel however; dry and wetwashing methods are mostly recommended because of their higher efficiencies andeasier applicabilities. In this study, methyl esters (biodiesel) derived fromwaste frying oil (WFO) and sunflower oil we...

  11. Producción de biodiesel asistida por ultrasonidos

    OpenAIRE

    Sáez Bastante, Javier

    2015-01-01

    The continuous increase of fossil fuel prices has raised interest in searching for new forms of energy to power internal combustion engines. Among the most promising options is biodiesel. According to ASTM (American Society for Testing and Materials Standard) specifications, biodiesel is described as monoalkyl esters of long chain fatty acids derived from renewable lipids such as vegetable oils or animal fats used in ignition engines. The process leading to biodiesel is called ...

  12. Messiah College Biodiesel Fuel Generation Project Final Technical Report

    Energy Technology Data Exchange (ETDEWEB)

    Zummo, Michael M; Munson, J; Derr, A; Zemple, T; Bray, S; Studer, B; Miller, J; Beckler, J; Hahn, A; Martinez, P; Herndon, B; Lee, T; Newswanger, T; Wassall, M

    2012-03-30

    Many obvious and significant concerns arise when considering the concept of small-scale biodiesel production. Does the fuel produced meet the stringent requirements set by the commercial biodiesel industry? Is the process safe? How are small-scale producers collecting and transporting waste vegetable oil? How is waste from the biodiesel production process handled by small-scale producers? These concerns and many others were the focus of the research preformed in the Messiah College Biodiesel Fuel Generation project over the last three years. This project was a unique research program in which undergraduate engineering students at Messiah College set out to research the feasibility of small-biodiesel production for application on a campus of approximately 3000 students. This Department of Energy (DOE) funded research program developed out of almost a decade of small-scale biodiesel research and development work performed by students at Messiah College. Over the course of the last three years the research team focused on four key areas related to small-scale biodiesel production: Quality Testing and Assurance, Process and Processor Research, Process and Processor Development, and Community Education. The objectives for the Messiah College Biodiesel Fuel Generation Project included the following: 1. Preparing a laboratory facility for the development and optimization of processors and processes, ASTM quality assurance, and performance testing of biodiesel fuels. 2. Developing scalable processor and process designs suitable for ASTM certifiable small-scale biodiesel production, with the goals of cost reduction and increased quality. 3. Conduct research into biodiesel process improvement and cost optimization using various biodiesel feedstocks and production ingredients.

  13. A First Law Thermodynamic Analysis of Biodiesel Production from Soybean

    Science.gov (United States)

    Patzek, Tad W.

    2009-01-01

    A proper First Law energy balance of the soybean biodiesel cycle shows that the overall efficiency of biodiesel production is 0.18, i.e., only 1 in 5 parts of the solar energy sequestered as soya beans, plus the fossil energy inputs, becomes biodiesel. Soybean meal is produced with an overall energetic efficiency of 0.38, but it is not a fossil…

  14. Assessing the greenhouse gas emissions from poultry fat biodiesel

    DEFF Research Database (Denmark)

    Jørgensen, Andreas; Bikker, Paul; Herrmann, Ivan Tengbjerg

    2012-01-01

    original use. This implies that even though the use of biodiesel is assumed to displace petrochemical diesel, the ‘original user’ of the poultry fat will have to find a substitute, whose production leads to a greenhouse gas emissions comparable to what is saved through driving on poultry fat biodiesel...... rather than petrochemical diesel. Given that it is the production of the substitute for the poultry fat which mainly eliminates the benefit from using poultry fat for biodiesel, it is argued that whenever assessing the greenhouse gas emissions from biodiesel made from by-products (such as rendered animal...

  15. Biodiesel fuel costs and environmental issues when powering railway locomotives

    Energy Technology Data Exchange (ETDEWEB)

    Mirza, Abdul; Ziemer, Norbert; Tatara, Robert; Moraga, Reinaldo; Mirman, Clifford; Vohra, Promod

    2010-09-15

    Issues for adopting biodiesel fuel, instead of petrodiesel, to power railroad locomotives are engine performance and emissions, fuel infrastructure, and fuel cost. These are evaluated for B2 through B100 blends. Biodiesel's solvent action on fuel systems is addressed. With biodiesel, hydrocarbon, carbon monoxide, and particulate emissions are unchanged or reduced. Nitrogen oxides are elevated but it is believed that engine alterations can minimize these emissions. A Transportation Model, using data from a major railway, has demonstrated that refueling depots can be fully supplied with biodiesel at a pricing premium of 1% to 26%, depending on blend and geographical location.

  16. Spectroscopic Analysis of Structural Transformation in Biodiesel Oxidation

    Institute of Scientific and Technical Information of China (English)

    Wu Jiang; Chen Boshui; Fang Jianhua; Wang Jiu

    2013-01-01

    The oxidation behavior of three biodiesels of different origins, viz. rapesee d oil derived biodiesel, soybean oil derived biodiesel and waste oil based biodiesel, were tested on an oxidation tester. The chemical compositions of the biodie-sels were characterized by gas chromatography. Thereafter, the structural transformation of fatty acid methyl ester (FAME) of the biodiesels was analyzed by an infrared spectrometer and an ultraviolet absorption spectrometer. The results demon-strated that the oxidation behavior of biodiesels of different origins was closely related to the composition and distribution of FAMEs. Higher concentration of unsaturated FAME with multi-double bonds exhibited poorer oxidation resistance. Fur-thermore, cis-trans isomerization transformation occurred in the unsaturated FAME molecules and conjugated double-bond produced during the oxidation process of biodiesel. Greater cis-trans variations corresponded to deeper oxidation degree. The higher the content of unsaturated FAME with multi-double bonds in a biodiesel, the more the conjugated double bonds was formed.

  17. Impact of ternary blends of biodiesel on diesel engine performance

    Directory of Open Access Journals (Sweden)

    Prem Kumar

    2016-06-01

    Full Text Available The Pongamia and waste cooking oils are the main non edible oils for biodiesel production in India. The aim of the present work is to evaluate the fuel properties and investigate the impact on engine performance using Pongamia and waste cooking biodiesel and their ternary blend with diesel. The investigation of the fuel properties shows that Pongamia biodiesel and waste cooking biodiesel have poor cold flow property. This will lead to starting problem in the engine operation. To overcome this problem the ternary blends of diesel, waste cooking biodiesel and Pongamia biodiesel are prepared. The cloud and pour point for ternary blend, (WCB20:PB20:D60 were found to be 7 °C and 6.5 °C which are comparable to cloud and pour point of diesel 6 °C and 5 °C, respectively. The result of the test showed that brake specific fuel consumption for Pongamia biodiesel and waste cooking biodiesel is higher than ternary blend, (WCB20:PB20:D60 due to their lower energy content. The brake thermal efficiency of ternary blend and diesel is comparable while the Pongamia and waste cooking biodiesel have low efficiency. The result of investigation showed that ternary blend can be developed as alternate fuel.

  18. Biodiesel from soybean promotes cell proliferation in vitro.

    Science.gov (United States)

    Gioda, Adriana; Rodríguez-Cotto, Rosa I; Amaral, Beatriz Silva; Encarnación-Medina, Jarline; Ortiz-Martínez, Mario G; Jiménez-Vélez, Braulio D

    2016-08-01

    Toxicological responses of exhaust emissions of biodiesel are different due to variation in methods of generation and the tested biological models. A chemical profile was generated using ICP-MS and GC-MS for the biodiesel samples obtained in Brazil. A cytotoxicity assay and cytokine secretion experiments were evaluated in human bronchial epithelial cells (BEAS-2B). Cells were exposed to polar (acetone) and nonpolar (hexane) extracts from particles obtained from fuel exhaust: fossil diesel (B5), pure soybean biodiesel (B100), soybean biodiesel with additive (B100A) and ethanol additive (EtOH). Biodiesel and its additives exhibited higher organic and inorganic constituents on particles when compared to B5. The biodiesel extracts did not exert any toxic effect at concentrations 10, 25, 50, 75, and 100μgmL(-1). In fact quite the opposite, a cell proliferation effect induced by the B100 and B100A extracts is reported. A small increase in concentrations of inflammatory mediators (Interleukin-6, IL-6; and Interleukin-8, IL-8) in the medium of biodiesel-treated cells was observed, however, no statistical difference was found. An interesting finding indicates that the presence of metals in the nonpolar (hexane) fraction of biodiesel fuel (B100) represses cytokine release in lung cells. This was revealed by the use of the metal chelator. Results suggest that metals associated with biodiesel's organic constituents might play a significant role in molecular mechanisms associated to cellular proliferation and immune responses.

  19. Biodiesel production from waste frying oils and its quality control.

    Science.gov (United States)

    Sabudak, T; Yildiz, M

    2010-05-01

    The use of biodiesel as fuel from alternative sources has increased considerably over recent years, affording numerous environmental benefits. Biodiesel an alternative fuel for diesel engines is produced from renewable sources such as vegetable oils or animal fats. However, the high costs implicated in marketing biodiesel constitute a major obstacle. To this regard therefore, the use of waste frying oils (WFO) should produce a marked reduction in the cost of biodiesel due to the ready availability of WFO at a relatively low price. In the present study waste frying oils collected from several McDonald's restaurants in Istanbul, were used to produce biodiesel. Biodiesel from WFO was prepared by means of three different transesterification processes: a one-step base-catalyzed, a two-step base-catalyzed and a two-step acid-catalyzed transesterification followed by base transesterification. No detailed previous studies providing information for a two-step acid-catalyzed transesterification followed by a base (CH(3)ONa) transesterification are present in literature. Each reaction was allowed to take place with and without tetrahydrofuran added as a co-solvent. Following production, three different procedures; washing with distilled water, dry wash with magnesol and using ion-exchange resin were applied to purify biodiesel and the best outcome determined. The biodiesel obtained to verify compliance with the European Standard 14214 (EN 14214), which also corresponds to Turkish Biodiesel Standards.

  20. Purification of biodiesel by choline chloride based deep eutectic solvent

    Science.gov (United States)

    Niawanti, Helda; Zullaikah, Siti; Rachimoellah, M.

    2017-05-01

    Purification is a crucial step in biodiesel production to meet the biodiesel standard. This study purified biodiesel using choline chloride based deep eutectic solvent (DES). DES was used to reduce unreacted oil and unsaponifiable matter in rice bran oil based biodiesel. The objective of this work was to study the effect of extraction time using DES on the content and yield of fatty acid methyl ester (FAME). Rice bran used in this work contains 16.49 % of oil with initial free fatty acids (FFA) of 44.75 %. Acid catalyzed methanolysis was employed to convert rice bran oil (RBO) into biodiesel under following operation conditions: T = 60 °C, t = 8 h, molar ratio of oil to methanol = 1/10, H2SO4 = 1% w/w of oil. Rice bran oil based biodiesel obtained contain 89.05 % of FAME with very low FFA content (0.05 %). DES was made from a mixture of choline chloride and ethylene glycol with molar ratio of 1/2. Molar ratio of crude biodiesel to DES were 1/2 and 1/4. Extraction time was varied from 15 minutes to 240 minutes at 30 °C. The highest FAME content was obtained after purification for 240 min. at molar ratio crude biodiesel to DES 1/4 was 96.60 %. This work shows that DES has potential to purify biodiesel from non-edible raw material, such as RBO.

  1. Utilization of biodiesel alcohol blends in a compression ignition engine

    Energy Technology Data Exchange (ETDEWEB)

    Yilmaz, Nadir; Sanchez, Tomas M. [Department of Mechanical Engineering, New Mexico Institute of Mining and Technology (United States)], e-mail: nadir@nmt.edu, email: tsanchez@omicron.net

    2011-07-01

    There has been a recent revival of interest in the use of ethanol-diesel and methanol-diesel fuel blends in vehicles as a way to reduce vehicle emissions. This article presents combustion tests and comparisons of standard diesel, neat biodiesel, biodiesel (85%)-methanol (15%), and biodiesel (85%)-ethanol (15%) fuels in a diesel engine. Experiments were carried out using a two-cylinder, 4-cycle, direct injected, water-cooled diesel engine as a function of five loads between no-load and full-load operating conditions at constant engine speed. The performance and emission characteristics of the engine fuelled with biodiesel-ethanol and biodiesel-methanol blends are compared to those of obtained using neat biodiesel and standard diesel fuel as the baseline fuels. The ethanol-biodiesel blends were found to be more effective than methanol-biodiesel for emission reduction and overall engine performance. It was also found that while biodiesel-alcohols reduce nitrogen monoxide emissions, they also increase carbon monoxide and hydrocarbons emissions at below 70% loads unless additional treatments are used, such as preheating intake air. Exhaust temperatures showed similar behavior for all of the fuels, with no significant difference being found.

  2. PRELIMINARY DESIGN OF OSCILLATORY FLOW BIODIESEL REACTOR FOR CONTINUOUS BIODIESEL PRODUCTION FROM JATROPHA TRIGLYCERIDES

    Directory of Open Access Journals (Sweden)

    AZHARI T. I. MOHD. GHAZI

    2008-08-01

    Full Text Available The concept of a continuous process in producing biodiesel from jatropha oil by using an Oscillatory Flow Biodiesel Reactor (OFBR is discussed in this paper. It has been recognized that the batch stirred reactor is a primary mode used in the synthesis of biodiesel. However, pulsatile flow has been extensively researcehed and the fundamental principles have been successfully developed upon which its hydrodynamics are based. Oscillatory flow biodiesel reactor offers precise control of mixing by means of the baffle geometry and pulsation which facilitates to continuous operation, giving plug flow residence time distribution with high turbulence and enhanced mass and heat transfer. In conjunction with the concept of reactor design, parameters such as reactor dimensions, the hydrodynamic studies and physical properties of reactants must be considered prior to the design work initiated recently. The OFBR reactor design involves the use of simulation software, ASPEN PLUS and the reactor design fundamentals. Following this, the design parameters shall be applied in fabricating the OFBR for laboratory scale biodiesel production.

  3. Study about the particularities of biodiesel in Brazil; Estudo sobre as particularidades do biodiesel no Brasil

    Energy Technology Data Exchange (ETDEWEB)

    Santos, Marcia Franca Ribeiro Fernandes dos [Instituto Brasileiro de Geografia e Estatistica (IBGE), Brasilia, DF (Brazil); Peixoto, Jose Antonio Assuncao; Souza, Cristina Gomes de [Centro Federal de Educacao Tecnologica Celso Suckow da Fonseca (CEFET/RJ), Rio de Janeiro, RJ (Brazil)

    2008-07-01

    The environmental concern associated with the impending shortage of oil, which is pressing to raise the price of the barrel, has forced governments and society to seek alternatives that will replace the use of fossil fuels. The biodiesel, in particular, has been set up as an alternative energy by it of fuel come from renewable sources, and less polluting the environment. In this context, the objective of this article is to present some features of the production of biodiesel in Brazil, identifying the characteristics of the main oil used, as well as regional motivations for the use of biodiesel in Brazil. The methodology adopted in this study was exploratory in nature based on a literature search and documentary from a survey of information available in literature. The main results, the article points out that: unlike alcohol, which is in sugar cane their ideal raw material, biodiesel is still in a stage of intensive research and development in order to identify the most appropriate its oil production - with emphasis on soybean and castor bean, and the motivations for regional use of biodiesel are different for the Brazilian regions. The study aims to contribute to the discussion on the subject, emphasizing that technological research should be directed taking into consideration the conditions and needs of Brazil. (author)

  4. RSM Based Optimization of Chemical and Enzymatic Transesterification of Palm Oil: Biodiesel Production and Assessment of Exhaust Emission Levels

    Directory of Open Access Journals (Sweden)

    Muhammad Waseem Mumtaz

    2014-01-01

    Full Text Available Current study presents RSM based optimized production of biodiesel from palm oil using chemical and enzymatic transesterification. The emission behavior of biodiesel and its blends, namely, POB-5, POB-20, POB-40, POB-50, POB-80, and POB-100 was examined using diesel engine (equipped with tube well. Optimized palm oil fatty acid methyl esters (POFAMEs yields were depicted to be 47.6±1.5,  92.7±2.5, and 95.4±2.0% for chemical transesterification catalyzed by NaOH, KOH, and NaOCH3, respectively, whereas for enzymatic transesterification reactions catalyzed by NOVOZYME-435 and A. n. lipase optimized biodiesel yields were 94.2±3.1 and 62.8±2.4%, respectively. Distinct decrease in particulate matter (PM and carbon monoxide (CO levels was experienced in exhaust emissions from engine operating on biodiesel blends POB-5, POB-20, POB-40, POB-50, POB-80, and POB-100 comparative to conventional petroleum diesel. Percentage change in CO and PM emissions for different biodiesel blends ranged from −2.1 to −68.7% and −6.2 to −58.4%, respectively, relative to conventional diesel, whereas an irregular trend was observed for NOx emissions. Only POB-5 and POB-20 showed notable reductions, whereas all other blends (POB-40 to POB-100 showed slight increase in NOx emission levels from 2.6 to 5.5% comparative to petroleum diesel.

  5. Biodiesel Reactor Design with Glycerol Separation to Increase Biodiesel Production Yield

    Directory of Open Access Journals (Sweden)

    Budy Rahmat

    2013-09-01

    Full Text Available The study consisted of reactor design used for transesterification process, effect of glycerol separation ontransesterification reaction, determination of biodiesel quality, and mass balance analysis. The reactor was designed byintegrating circulated pump/stirrer, static mixer, and sprayer that intensify the reaction in the outer tank reactor. The objective was to reduce the use of methanol in excess and to shorten the processing time. The results showed that thereactor that applied the glycerol separation was able to compensate for the decreased use of the reactant methanol from 6:1 to 5:1 molar ratio, and changed the mass balance in the product, including: (i the increase of biodiesel productionfrom 42.37% to 49.34%, and (ii the reduction of methanol in excess from 42.37% to 32.89%. The results suggested that the efficiency of biodiesel production could be increased with the glycerol separation engineering.

  6. Alcohol biodiesel from frying oil residues; Biodiesel etilico a partir de oleo de fritura residual

    Energy Technology Data Exchange (ETDEWEB)

    Festa, Brunna Simoes; Marques, Luiz Guilherme da Costa [Universidade Federal do Rio de Janeiro (IVIG/COPPE/UFRJ), RJ (Brazil). Coordenacao dos Programas de Pos-Graduacao de Engenharia. Inst. Virtual Internacional de Mudancas Globais], E-mail: lguilherme@ivig.coppe.ufrj.br

    2010-07-01

    This paper describes the reaction optimization and production of biodiesel through the use of frying residual oil made available by the restaurant placed at the PETROBRAS Research Center (CENPES-RJ), using ethanol, so that to permit the production of sustainable bio diesel. The environmental gains obtained by the utilization of residual oil, avoiding that this oil be released in the nature, and the economic gains coming from the generation and utilization of ethanol allowing the production of biodiesel be an viable alternative. The obtained results during laboratory tests shown that biodiesel produced from the transesterification in alkaline medium, of the frying residual oil collected presented a reaction yield of approximately 80% considering in mass.

  7. Castor oil biodiesel: an economic evaluation; Biodiesel de mamona: uma avaliacao economica

    Energy Technology Data Exchange (ETDEWEB)

    Pires, Monica de Moura; Alves, Jaenes Miranda; Almeida Neto, Jose Adolfo de; Almeida, Cezar Menezes; Sousa, Geovania Silva de; Cruz, Rosenira Serpa da; Monteiro, Renata; Lopes, Beatriz Sampaio; Robra, Sabine [Universidade Estadual de Santa Cruz, Ilheus, BA (Brazil). Grupo Bioenergia e Meio Ambiente]. E-mails: mpires@uesc.br; jaenes@uesc.br; jalmeida@uesc.br; roserpa@uesc.br

    2004-07-01

    The production cost of castor oil biodiesel by methyl way and its economic viability, using as reference the production cost data of castor oil and the implantation of the pilot plant at UESC - state university of Santa Cruz, Bahia State, Brazil was determined. From this information, it was seen that the estimated price of castor oil biodiesel is close to the diesel price in the Itabuna market, Bahia state, Brazil. The indicators show economic viability of the mini-power plant installation. Such information are preliminary estimative for the market and can be modified as function of changes in the main factors used to have the production costs, as well as the sectorial policies that drives the activity as much in levels of raw material production as in biodiesel.

  8. Landfill gas, canola, and biodiesel. Working towards a sustainable system [Snohomish County Biodiesel Project

    Energy Technology Data Exchange (ETDEWEB)

    Chang, Terrill; Carveth, Deanna

    2010-02-01

    Snohomish County in western Washington State began converting its vehicle fleet to use a blend of biodiesel and petroleum diesel in 2005. As prices for biodiesel rose due to increased demand for this cleaner-burning fuel, Snohomish County looked to its farmers to grow this fuel locally. Suitable seed crops that can be crushed to extract oil for use as biodiesel feedstock include canola, mustard, and camelina. The residue, or mash, has high value as an animal feed. County farmers began with 52 acres of canola and mustard crops in 2006, increasing to 250 acres and 356 tons in 2008. In 2009, this number decreased to about 150 acres and 300 tons due to increased price for mustard seed.

  9. Biodiesel: uma energia alternativa e verde

    Directory of Open Access Journals (Sweden)

    Milena Carvalho Teixeira

    2010-12-01

    Full Text Available O presente texto busca expor a importância do uso de energias alternativas. O biodiesel é apontado como uma das soluções para o esgotamento do petróleo e seus derivados e para o problema do aquecimento global, e o Brasil, por apresentar biodiversidade e forte economia agrícola, permitiu que o Governo Federal criasse o Programa Nacional de Produção e Uso de Biodiesel (PNPB com chances de sucesso. O programa explora várias fontes energéticas, de culturas temporárias e perenes ao uso do óleo residual, além de trazer benefícios ao desenvolvimento do país, gerando emprego e renda, e, principalmente, redução nas emissões de gás carbônico.

  10. Fremtidens Biodiesel: Kom fedtaffald i tanken!

    DEFF Research Database (Denmark)

    Madsen, Anders Theilgaard; Taarning, Esben; Christensen, Claus Hviid

    2009-01-01

    Mange tror måske, at det er svært for menigmand at lave biobrændstof. Det er faktisk forkert, fordi biodiesel nemt kan laves af kemikalier, der er ret almindelige i laboratorier og hos købmanden og materialisten. Det kræver blot en såkaldt om-estring af planteolie eller fedt med methanol, samt...

  11. Biodiesel Projects Helpful to Ease Energy Shortage

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    @@ Nearly 7,000 hectares of biodiesel forest will take shape in the northern province of Hebei in 2008, part of a national campaign to fuel the fast growing economy in a green way. In no more than five years, the Pistacia chinensis Bunge, whose seeds have an oil content of up to 40 percent, will yield five tons of fruit and contribute about two tons of high-quality biological diesel oil,according to the provincial forestry administration.

  12. Fremtidens Biodiesel: Kom fedtaffald i tanken!

    DEFF Research Database (Denmark)

    Madsen, Anders Theilgaard; Taarning, Esben; Christensen, Claus Hviid

    2009-01-01

    Mange tror måske, at det er svært for menigmand at lave biobrændstof. Det er faktisk forkert, fordi biodiesel nemt kan laves af kemikalier, der er ret almindelige i laboratorier og hos købmanden og materialisten. Det kræver blot en såkaldt om-estring af planteolie eller fedt med methanol, samt...

  13. Production of Biodiesel from Chicken Frying Oil

    OpenAIRE

    Emaad T. Bakir; Abdelrahman B. Fadhil

    2011-01-01

    Chicken fried oil was converted into different biodiesels through single step transesterification and two step transesterification, namely acid-base and base–base catalyzed transesterification. Hydrochloric acid and potassium hydroxide with methanol were used for this purpose. The results showed that two step base catalyzed transesterification was better compared to other methods. It resulted in higher yield and better fuel properties. Transesterification of fried chicken oil was monitored by...

  14. Biodiesel production from Jatropha curcas oil

    Energy Technology Data Exchange (ETDEWEB)

    Jain, Siddharth; Sharma, M.P. [Alternate Hydro Energy Centre, Indian Institute of Technology Roorkee, Roorkee, Uttarakhand 247667 (India)

    2010-12-15

    In view of the fast depletion of fossil fuel, the search for alternative fuels has become inevitable, looking at huge demand of diesel for transportation sector, captive power generation and agricultural sector, the biodiesel is being viewed a substitute of diesel. The vegetable oils, fats, grease are the source of feedstocks for the production of biodiesel. Significant work has been reported on the kinetics of transesterification of edible vegetable oils but little work is reported on non-edible oils. Out of various non-edible oil resources, Jatropha curcas oil (JCO) is considered as future feedstocks for biodiesel production in India and limited work is reported on the kinetics of transesterification of high FFA containing oil. The present study reports a review of kinetics of biodiesel production. The paper also reveals the results of kinetics study of two-step acid-base catalyzed transesterification process carried out at pre-determined optimum temperature of 65 and 50 C for esterification and transesterification process, respectively, under the optimum condition of methanol to oil ratio of 3:7 (v/v), catalyst concentration 1% (w/w) for H{sub 2}SO{sub 4} and NaOH and 400 rpm of stirring. The yield of methyl ester (ME) has been used to study the effect of different parameters. The maximum yield of 21.2% of ME during esterification and 90.1% from transesterification of pretreated JCO has been obtained. This is the first study of its kind dealing with simplified kinetics of two-step acid-base catalyzed transesterification process carried at optimum temperature of both the steps which took about 6 h for complete conversion of TG to ME. (author)

  15. Use of waste materials for biodiesel production

    Energy Technology Data Exchange (ETDEWEB)

    Vitiello, R.; Tesser, R.; Di Serio, M.; Santacesaria, E. [Napoli Univ. (Italy). Dipt. di Scienze Chimiche; Buonerba, A.; Grassi, A. [Salerno Univ. (Italy). Dipt. di Chimica e Biologia

    2012-07-01

    Waste raw materials obtained by several sources of both food and agro industries could be considered for biofuel production. In the last years, this topic has growing in interest. At this purpose, our research, has been focused on the development of new technologies to obtain biodiesel from the mentioned wastes feedstock. In particular from oleins, that are mixtures of free fatty acids (FFAs) and triglycerides. Therefore, we are studying the way to produce biodiesel in two steps: an esterification reaction of FFAs with glycerol and a transesterification with methanol of the whole mixture. The esterification of FFAs with glycerol has the advantage of using a relatively high temperature favouring the stripping of water formed during the esterification. In this way esterification equilibrium is shifted to the right. Then, the mixture of mono-, di- and triglycerides, obtained by esterification with glycerol, can be submitted to transesterification with methanol, in the usual way, to produce biodiesel Catalysts promoting esterification, normally, are mineral acids or heterogeneous Bronsted acid catalysts. At this purpose, the classical sulphonated polystyrene acid resins cannot be used at temperature greater than 120 C. Therefore, a new class of sulfonated polymers, with enhanced temperature resistance, has been developed by selective and quantitative sulfonation of olefinic butadiene units in multiblock copolymers syndiotactic polystyrene-co-1,4-cis-polybutadiene. This catalytic system has been successfully tested in the above mentioned esterification reaction and compared to classic commercial strong acid catalysts like Amberlyst {sup registered}, Nafion {sup registered} and sulfuric acid. (orig.)

  16. Designing a new MSA biodiesel technology MBT

    Energy Technology Data Exchange (ETDEWEB)

    Ingendoh, Axel [Lanxess Deutschland GmbH, Leverkusen (Germany)

    2013-06-01

    The new MBT Technology was developed at Lanxess and eliminates all these constraints of the alkaline transesterification technology. The acidic transesterification uses Methane sulfonic acid catalysis. Due to the acidic nature of the MBT process formation of soaps is made impossible, sterylglycosides are completely cleaved into soluble product, free fatty acids up to 10% are tolerated, higher alcohols like ethanol and butanol do react equally well and waxes are completely converted into biodiesel. Phase separation of biodiesel and glycerol is dramatically enhanced due to the lack of methanol in this stage. Surprisingly, even water up to 5% does not affect the overall yield and product quality of the MBT Process. Cost savings in biodiesel production may be achieved by using low quality oils with high free fatty acids, use of algae oil, and cost savings at oil raffination due to no need of drying. The Technology is lean and requires less apparatus and less operational steps. The catalyst may be completely recycled by recovering it from the glycerol phase using Lewatit ion exchange technology of Lanxess. (orig.)

  17. Refining of biodiesel by ceramic membrane separation

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Yong; Ou, Shiyi; Tan, Yanlai; Tang, Shuze [Department of Food Science and Engineering, Jinan University, Guangzhou 510632 (China); Wang, Xingguo; Liu, Yuanfa [School of Food Science and Technology, Jiangnan University, Wuxi 214112 (China)

    2009-03-15

    A ceramic membrane separation process for biodiesel refining was developed to reduce the considerable usage of water needed in the conventional water washing process. Crude biodiesel produced by refined palm oil was micro-filtered by ceramic membranes of the pore size of 0.6, 0.2 and 0.1 {mu}m to remove the residual soap and free glycerol, at the transmembrane pressure of 0.15 MPa and temperature of 60 C. The flux through membrane maintained at 300 L m{sup -} {sup 2} h{sup -} {sup 1} when the volumetric concentrated ratio reached 4. The content of potassium, sodium, calcium and magnesium in the whole permeate was 1.40, 1.78, 0.81 and 0.20 mg/kg respectively, as determined by inductively coupled plasma-atomic emission spectroscopy. These values are lower than the EN 14538 specifications. The residual free glycerol in the permeate was estimated by water extraction, its value was 0.0108 wt.%. This ceramic membrane technology was a potential environmental process for the refining of biodiesel. (author)

  18. Kinetic Model of Biodiesel Processing Using Ultrasound

    Directory of Open Access Journals (Sweden)

    Bambang Susilo

    2009-04-01

    Full Text Available Ultrasound is predicted to be able to accelerate the chemical reaction, to increase the conversion of plant oil into biodiesel, and to decrease the need of catalyst and energy input. The application of ultrasound for processing of biodiesel and the mathematical model were conducted in this research. The result of the experiments showed that the ultrasound increased reaction rate and the conversion of palm oil into biodiesel up to 100%. It was better than the process with mechanical stirrer that the conversion was just 96%. The duration to complete the process using ultrasound was 1 minute. It was 30 to 120 times faster than that with mechanical stirrer. Ultrasound transforms mechanical energy into inner energy of the fluids and causes an increasing of temperature. Simultaneously, natural mixing process undergo because of acoustic circulation. Simulation with experiment data showed that the acceleration of transesterification with ultrasound was affected not only by natural mixing and increasing temperature. The cavitation, surface tension of micro bubble, and hot spot accelerate chemical reaction. In fact, transesterification of palm oil with ultrasound still needs catalyst. It needs only about 20% of catalyst compared to the process with mechanical stirrer.

  19. 10 CFR 490.707 - Increasing the qualifying volume of the biodiesel component.

    Science.gov (United States)

    2010-01-01

    ... 10 Energy 3 2010-01-01 2010-01-01 false Increasing the qualifying volume of the biodiesel... TRANSPORTATION PROGRAM Biodiesel Fuel Use Credit § 490.707 Increasing the qualifying volume of the biodiesel component. DOE may increase the qualifying volume of the biodiesel component of fuel for purposes...

  20. Water Consumption Estimates of the Biodiesel Process in the US

    Science.gov (United States)

    As a renewable alternative to petroleum diesel, biodiesel has been widely used in the US and around the world. Along with the rapid development of the biodiesel industry, its potential impact on water resources should also be evaluated. This study investigates water consumption f...

  1. Partitioning Behavior of Petrodiesel/Biodiesel Blends in Water

    Science.gov (United States)

    The partitioning behavior of six petrodiesel/soybean-biodiesel blends (B0, B20, B40, B60, B80, and B100, where B100 is 100% unblended biodiesel) in water was investigated at various oil loads by the 10-fold dilution method. Five fatty acid methyl esters (FAMEs), C10 - C20 n

  2. Moringa oleifera oil: Studies of characterization and biodiesel production

    Energy Technology Data Exchange (ETDEWEB)

    da Silva, Jhosianna P.V.; Serra, Tatiana M.; Meneghetti, Simoni M.P. [Universidade Federal de Alagoas, Instituto de Quimica e Biotecnologia, Laboratorio de Oleoquimica, Maceio, Alagoas, CEP 57072-970 (Brazil); Gossmann, Marcelo; Wolf, Carlos R.; Meneghetti, Mario R. [Universidade Luterana do Brasil, Instituto de Quimica, Canoas, Rio Grande do Sul, CEP 92420-280 (Brazil)

    2010-10-15

    This work describes studies with the seeds of Moringa oleifera (MO), obtained in the northeast of Brazil, evaluating some properties and chemical composition of the oil, as well any potential application in biodiesel production. The studied physicochemical properties of the MO biodiesel, suggest that this material may be used as fuel in diesel engines, mainly as a mixture to petrodiesel. (author)

  3. Biodiesel production--current state of the art and challenges.

    Science.gov (United States)

    Vasudevan, Palligarnai T; Briggs, Michael

    2008-05-01

    Biodiesel is a clean-burning fuel produced from grease, vegetable oils, or animal fats. Biodiesel is produced by transesterification of oils with short-chain alcohols or by the esterification of fatty acids. The transesterification reaction consists of transforming triglycerides into fatty acid alkyl esters, in the presence of an alcohol, such as methanol or ethanol, and a catalyst, such as an alkali or acid, with glycerol as a byproduct. Because of diminishing petroleum reserves and the deleterious environmental consequences of exhaust gases from petroleum diesel, biodiesel has attracted attention during the past few years as a renewable and environmentally friendly fuel. Since biodiesel is made entirely from vegetable oil or animal fats, it is renewable and biodegradable. The majority of biodiesel today is produced by alkali-catalyzed transesterification with methanol, which results in a relatively short reaction time. However, the vegetable oil and alcohol must be substantially anhydrous and have a low free fatty acid content, because the presence of water or free fatty acid or both promotes soap formation. In this article, we examine different biodiesel sources (edible and nonedible), virgin oil versus waste oil, algae-based biodiesel that is gaining increasing importance, role of different catalysts including enzyme catalysts, and the current state-of-the-art in biodiesel production.

  4. Methyl esters (biodiesel) from Pachyrhizus erosus seed oil

    Science.gov (United States)

    The search for additional or alternative feedstocks is one of the major areas of interest regarding biodiesel. In this paper, the fuel properties of Pachyrhizus erosus (commonly known as yam bean or Mexican potato or jicama) seed oil methyl esters were investigated by methods prescribed in biodiesel...

  5. Assessment of Physicochemical Properties of Biodiesel from African ...

    African Journals Online (AJOL)

    The oil was transesterified using alkali hydrolysis to biodiesel. ... point (96 oC), cloud point (+9oC), sulphur content (0.03 wt %), and free glycerol (0.54%). ... followed by sieving to get fine kernel-rich powder and ... require 0.30-1.5% of the oil weight as base catalyst. ... for treating triglycerides to produce (biodiesel) fatty acid.

  6. Pembuatan Biodiesel Secara Batch Dengan Memanfaatkan Gelombang Mikro (Microwave

    Directory of Open Access Journals (Sweden)

    Rhesa Purnama Putra

    2012-09-01

    Full Text Available Biodiesel merupakan bioenergi atau bahan bakar nabati yang dibuat dari minyak nabati, baik minyak baru atau bekas penggorengan melalui proses transesterifikasi, esterifikasi, atau proses esterifikasi-transesterifikasi. Tujuan penelitian ini adalah untuk membuat biodiesel dari minyak goreng secara batch melalui proses transesterifikasi dengan menggunakan radiasi mikrowave serta mempelajari berapa daya dan waktu optimal yang diperlukan untuk proses pembuatan biodiesel dengan radiasi microwave dengan katalis CaO, H2SO4, dan tanpa katalis. Dalam penelitian ini digunakan tiga variabel, yaitu daya (Watt;100,200,300,400, waktu (menit; 5,10,15,20 dan jenis katalis; CaO, H2SO4, dan tanpa katalis. Pada tahap persiapan menghitung volume minyak dan metanol yang akan dicampur. Kemudian mencampurnya didalam reaktor. Lalu mendinginkan campuran hingga terbentuk dua lapisan atas dan bawah dilanjutkan dengan melakukan pemisahan lapisan atas (biodiesel dari lapisan bawah (gliserol. Adapun pada tahap analisis, biodiesel hasil reaksi transesterfikasi dianalisa untuk mendapatkan data yield metil ester, densitas, viskositas, dan flash point. Dari penelitian diketahui bahwa hasil yang didapatkan masih belum dapat memenuhi standar biodiesel yang ditetapkan. Katalis CaO dapat memberikan hasil yang lebih baik dibandingkan dengan katalis H2SO4 dan tanpa katalis. Kondisi operasi untuk menghasilkan kualitas yield biodiesel terbaik yaitu pada daya 200 Watt selama 20 menit dengan menggunakan katalis CaO. Yield biodiesel terbesar didapatkan yield sebesar 60,11 %.

  7. Biodiesel by catalytic reactive distillation powered by metal oxides

    NARCIS (Netherlands)

    Kiss, A.A.; Dimian, A.C.; Rothenberg, G.

    2008-01-01

    The properties and use of biodiesel as a renewable fuel as well as the problems associated with its current production processes are outlined. A novel sustainable esterification process based on catalytic reactive distillation is proposed. The pros and cons of manufacturing biodiesel via fatty acid

  8. An Investigation of Biodiesel Production from Wastes of Seafood Restaurants

    Directory of Open Access Journals (Sweden)

    Nour Sh. El-Gendy

    2014-01-01

    Full Text Available This work illustrates a comparative study on the applicability of the basic heterogeneous calcium oxide catalyst prepared from waste mollusks and crabs shells (MS and CS, resp. in the transesterification of waste cooking oil collected from seafood restaurants with methanol for production of biodiesel. Response surface methodology RSM based on D-optimal deign of experiments was employed to study the significance and interactive effect of methanol to oil M : O molar ratio, catalyst concentration, reaction time, and mixing rate on biodiesel yield. Second-order quadratic model equations were obtained describing the interrelationships between dependent and independent variables to maximize the response variable (biodiesel yield and the validity of the predicted models were confirmed. The activity of the produced green catalysts was better than that of chemical CaO and immobilized enzyme Novozym 435. Fuel properties of the produced biodiesel were measured and compared with those of Egyptian petro-diesel and international biodiesel standards. The biodiesel produced using MS-CaO recorded higher quality than that produced using CS-CaO. The overall biodiesel characteristics were acceptable, encouraging application of CaO prepared from waste MS and CS for production of biodiesel as an efficient, environmentally friendly, sustainable, and low cost heterogeneous catalyst.

  9. Lipids from yeasts and fungi: Tomorrow's source of Biodiesel?

    NARCIS (Netherlands)

    Meeuwse, P.; Sanders, J.P.M.; Tramper, J.; Rinzema, A.

    2013-01-01

    In the search for new transport fuels from renewable resources, biodiesel from microbial lipids comes into view. We have evaluated the lipid yield and energy use of a process for production of biodiesel from agricultural waste using lipid-accumulating yeast and fungi. We included different

  10. Biodiesel: A fuel, a lubricant, and a solvent

    Science.gov (United States)

    Biodiesel is well-known as a biogenic alternative to conventional diesel fuel derived from petroleum. It is produced from feedstocks such as plant oils consisting largely of triacylglycerols through transesterification with an alcohol such as methanol. The properties of biodiesel are largely compet...

  11. Direct transesterification of spent coffee grounds for biodiesel production

    Science.gov (United States)

    Studies of spent coffee grounds (SCGs) as a potential biodiesel feedstock in recent years mostly started from solvent extraction to obtain coffee oil, and then converted it into coffee biodiesel in two steps, acid esterification followed by alkaline transesterification. This paper presents a direct ...

  12. Moringa Oleifera Oil: A Possible Source of Biodiesel

    Science.gov (United States)

    Biodiesel is an alternative to petroleum-based conventional diesel fuel and is defined as the mono-alkyl esters of vegetable oils and animal fats. Biodiesel has been prepared from numerous vegetable oils, such as canola (rapeseed), cottonseed, palm, peanut, soybean and sunflower oils as well as a v...

  13. Preparation of Biodiesel by Methanolysis of Crude Moringa Oleifera Oil

    Science.gov (United States)

    Biodiesel was prepared from the unconventional crude oil of Moringa oleifera by transesterification with methanol and alkali catalyst. Moringa oleifera oil is reported for the first time as potential feedstock for biodiesel. Moringa oleifera oil contains a high amount of oleic acid (>70%) with sat...

  14. The effect of economic variables over a biodiesel production plant

    Energy Technology Data Exchange (ETDEWEB)

    Marchetti, J.M., E-mail: jmarchetti@plapiqui.edu.ar [Planta Piloto de Ingenieria Quimica (UNS-CONICET), Camino La Carrindanga km 7, 8000 Bahia Blanca (Argentina)

    2011-09-15

    Highlights: {yields} Influence of the mayor economic parameters for biodiesel production. {yields} Variations of profitability of a biodiesel plant due to changes in the market scenarios. {yields} Comparison of economic indicators of a biodiesel production facility when market variables are modified. - Abstract: Biodiesel appears as one of the possible alternative renewable fuels to substitute diesel fuel derived from petroleum. Several researches have been done on the technical aspects of biodiesel production in an attempt to develop a better and cleaner alternative to the conventional process. Economic studies have been carried out to have a better understanding of the high costs and benefits of different technologies in the biodiesel industry. In this work it is studied the effect of the most important economic variables of a biodiesel production process over the general economy of a conventional plant which employs sodium methoxide as catalyst. It has been analyzed the effect of the oil price, the amount of free fatty acid, the biodiesel price, the cost of the glycerin, the effect due to the modification on the methanol price, the washing water price, and several others. Small variations on some of the major market variables would produce significant effects over the global economy of the plant, making it non profitable in some cases.

  15. Partitioning Behavior of Petrodiesel/Biodiesel Blends in Water

    Science.gov (United States)

    The partitioning behavior of six petrodiesel/soybean-biodiesel blends (B0, B20, B40, B60, B80, and B100, where B100 is 100% unblended biodiesel) in water was investigated at various oil loads by the 10-fold dilution method. Five fatty acid methyl esters (FAMEs), C10 - C20 n

  16. Study on Carbonyl Emissions of Diesel Engine Fueled with Biodiesel

    Directory of Open Access Journals (Sweden)

    Ruina Li

    2017-01-01

    Full Text Available Biodiesel is a kind of high-quality alternative fuel of diesel engine. In this study, biodiesel and biodiesel/diesel blend were used in a single cylinder diesel engine to study the carbonyl emissions. The result shows that carbonyl pollutants of biodiesel and biodiesel/diesel blend are mainly aldehyde and ketone compounds with 1–3 carbon atoms, and formaldehyde concentration is higher than 80% of the total carbonyl pollutants for biodiesel. The formaldehyde concentration peak is reduced with the increase of intake temperature (T, intake pressure (P, and exhaust gas recirculation (EGR ratio and increased with the increase of compression ratio (ε. When excess air coefficient (λ is lower than 1.7, the formaldehyde concentration is increased with the increase of excess air ratio. When λ is higher than 1.7, the formaldehyde concentration is reduced with the increase of excess air ratio. The dilution of air can reduce formaldehyde concentration in the premixed flame of diesel effectively; however, it has less effect on biodiesel. Among the fuel pretreatment measures of adding hydrogen, CO, and methane, the addition of hydrogen shows the best effect on reducing formaldehyde of biodiesel.

  17. Economic assessment of biodiesel production from waste frying oils.

    Science.gov (United States)

    Araujo, Victor Kraemer Wermelinger Sancho; Hamacher, Silvio; Scavarda, Luiz Felipe

    2010-06-01

    Waste frying oils (WFO) can be a good source for the production of biodiesel because this raw material is not part of the food chain, is low cost and can be used in a way that resolves environmental problems (i.e. WFO is no longer thrown into the sewage network). The goal of this article is to propose a method to evaluate the costs of biodiesel production from WFO to develop an economic assessment of this alternative. This method embraces a logistics perspective, as the cost of collection of oil from commercial producers and its delivery to biodiesel depots or plants can be relevant and is an issue that has been little explored in the academic literature. To determine the logistics cost, a mathematical programming model is proposed to solve the vehicle routing problem (VRP), which was applied in an important urban center in Brazil (Rio de Janeiro), a relevant and potential center for biodiesel production and consumption. Eighty-one biodiesel cost scenarios were compared with information on the commercialization of biodiesel in Brazil. The results obtained demonstrate the economic viability of biodiesel production from WFO in the urban center studied and the relevance of logistics in the total biodiesel production cost. (c) 2010 Elsevier Ltd. All rights reserved.

  18. Modeling the Crystallization Behavior of Biodiesel at Low Temperatures

    Science.gov (United States)

    The most common form of biodiesel is made by transesterification of vegetable oil or animal fat fatty acids with methanol (FAME). Biodiesel from feedstocks such as palm oil (PME), rapeseed oil (RME), soybean oil (SME) or used cooking oil (UCOME) is susceptible to performance issues during cold weat...

  19. Biodiesel by catalytic reactive distillation powered by metal oxides

    NARCIS (Netherlands)

    Kiss, A.A.; Dimian, A.C.; Rothenberg, G.

    2008-01-01

    The properties and use of biodiesel as a renewable fuel as well as the problems associated with its current production processes are outlined. A novel sustainable esterification process based on catalytic reactive distillation is proposed. The pros and cons of manufacturing biodiesel via fatty acid

  20. Water Consumption Estimates of the Biodiesel Process in the US

    Science.gov (United States)

    As a renewable alternative to petroleum diesel, biodiesel has been widely used in the US and around the world. Along with the rapid development of the biodiesel industry, its potential impact on water resources should also be evaluated. This study investigates water consumption f...

  1. Overview on the current trends in biodiesel production

    Energy Technology Data Exchange (ETDEWEB)

    Yusuf, N.N.A.N. [Department of Chemical and Process Engineering, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor (Malaysia); Kamarudin, S.K., E-mail: ctie@eng.ukm.m [Department of Chemical and Process Engineering, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor (Malaysia); Yaakub, Z. [Department of Chemical and Process Engineering, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor (Malaysia)

    2011-07-15

    Research highlights: {yields} Various method for the production of biodiesel from vegetable oil were reviewed. {yields} Such as direct use and blending, microemulsion, pyrolysis and transesterification. {yields} The advantages and disadvantages of the different biodiesel-production methods are also discussed. {yields} Finally, the economics of biodiesel production was discussed using Malaysia as a case study. -- Abstract: The finite nature of fossil fuels necessitates consideration of alternative fuels from renewable sources. The term biofuel refers to liquid, gas and solid fuels predominantly produced from biomass. Biofuels include bioethanol, biomethanol, biodiesel and biohydrogen. Biodiesel, defined as the monoalkyl esters of vegetable oils or animal fats, is an attractive alternative fuel because it is environmentally friendly and can be synthesized from edible and non-edible oils. Here, we review the various methods for the production of biodiesel from vegetable oil, such as direct use and blending, microemulsion, pyrolysis and transesterification. The advantages and disadvantages of the different biodiesel-production methods are also discussed. Finally, we analyze the economics of biodiesel production using Malaysia as a case study.

  2. Progress and Challenges in Microalgal Biodiesel Production

    Science.gov (United States)

    Mallick, Nirupama; Bagchi, Sourav K.; Koley, Shankha; Singh, Akhilesh K.

    2016-01-01

    The last decade has witnessed a tremendous impetus on biofuel research due to the irreversible diminution of fossil fuel reserves for enormous demands of transportation vis-a-vis escalating emissions of green house gasses (GHGs) into the atmosphere. With an imperative need of CO2 reduction and considering the declining status of crude oil, governments in various countries have not only diverted substantial funds for biofuel projects but also have introduced incentives to vendors that produce biofuels. Currently, biodiesel production from microalgal biomass has drawn an immense importance with the potential to exclude high-quality agricultural land use and food safe-keeping issues. Moreover, microalgae can grow in seawater or wastewater and microalgal oil can exceed 50–60% (dry cell weight) as compared with some best agricultural oil crops of only 5–10% oil content. Globally, microalgae are the highest biomass producers and neutral lipid accumulators contending any other terrestrial oil crops. However, there remain many hurdles in each and every step, starting from strain selection and lipid accumulation/yield, algae mass cultivation followed by the downstream processes such as harvesting, drying, oil extraction, and biodiesel conversion (transesterification), and overall, the cost of production. Isolation and screening of oleaginous microalgae is one pivotal important upstream factor which should be addressed according to the need of freshwater or marine algae with a consideration that wild-type indigenous isolate can be the best suited for the laboratory to large scale exploitation. Nowadays, a large number of literature on microalgal biodiesel production are available, but none of those illustrate a detailed step-wise description with the pros and cons of the upstream and downstream processes of biodiesel production from microalgae. Specifically, harvesting and drying constitute more than 50% of the total production costs; however, there are quite a less

  3. Progress and Challenges in Microalgal Biodiesel Production.

    Science.gov (United States)

    Mallick, Nirupama; Bagchi, Sourav K; Koley, Shankha; Singh, Akhilesh K

    2016-01-01

    The last decade has witnessed a tremendous impetus on biofuel research due to the irreversible diminution of fossil fuel reserves for enormous demands of transportation vis-a-vis escalating emissions of green house gasses (GHGs) into the atmosphere. With an imperative need of CO2 reduction and considering the declining status of crude oil, governments in various countries have not only diverted substantial funds for biofuel projects but also have introduced incentives to vendors that produce biofuels. Currently, biodiesel production from microalgal biomass has drawn an immense importance with the potential to exclude high-quality agricultural land use and food safe-keeping issues. Moreover, microalgae can grow in seawater or wastewater and microalgal oil can exceed 50-60% (dry cell weight) as compared with some best agricultural oil crops of only 5-10% oil content. Globally, microalgae are the highest biomass producers and neutral lipid accumulators contending any other terrestrial oil crops. However, there remain many hurdles in each and every step, starting from strain selection and lipid accumulation/yield, algae mass cultivation followed by the downstream processes such as harvesting, drying, oil extraction, and biodiesel conversion (transesterification), and overall, the cost of production. Isolation and screening of oleaginous microalgae is one pivotal important upstream factor which should be addressed according to the need of freshwater or marine algae with a consideration that wild-type indigenous isolate can be the best suited for the laboratory to large scale exploitation. Nowadays, a large number of literature on microalgal biodiesel production are available, but none of those illustrate a detailed step-wise description with the pros and cons of the upstream and downstream processes of biodiesel production from microalgae. Specifically, harvesting and drying constitute more than 50% of the total production costs; however, there are quite a less number

  4. Thermal behavior of diesel/biodiesel blends of biodiesel obtained from buriti oil=Comportamento térmico de blendas de diesel/biodiesel de biodiesel obtido a partir do óleo de buriti

    Directory of Open Access Journals (Sweden)

    Alexandre Gustavo Soares do Prado

    2012-04-01

    Full Text Available Biodiesel has been obtained from methanolysis of buriti oil. This biodiesel was added in fossil diesel in order to obtain diesel/biodiesel blends. Thermal analysis of blends were carried on 30-600oC range at rate of 10oC min.-1. Kinetic parameters such as activation energy (Ea, pre-exponential factor (A, Gibbs energy (≠G, enthalpy (≠H and entropy (≠S of activation were determined by using Coats–Redfern equation. The Ea, ≠H and ≠G values presented a linear increase with biodiesel amount added in blends. The heat of combustion of diesel/biodiesel blends was determined, and it was observed that the heat of combustion decreased with the addition of biodiesel in diesel/biodiesel blends.O biodiesel foi obtido a partir de metanólise de óleo de buriti. O biodiesel foi adicionado ao diesel fóssil a fim de obter misturas de biodiesel/diesel. Análises térmica das misturas foram realizadas entre 30-600°C com uma taxa de aquecimento de 10ºC min.-1. Parâmetros cinéticos como a energia de ativação (Ea, fator pré-exponencial (A, energia livre de Gibbs (≠G, entalpia (≠H e entropia de ativação (≠S foram determinadas usando equação de Coats-Redfern. Os valores de Ea, ≠H and ≠G apresentaram aumento linear com a quantidade de biodiesel adicionado na mistura. O calor de combustão de misturas de biodiesel/diesel foi determinada, e foi observado que o calor de combustão diminuiu com a adição de biodiesel no diesel e nas misturas de biodiesel.

  5. Brown Grease to Biodiesel Demonstration Project Report

    Energy Technology Data Exchange (ETDEWEB)

    San Francisco Public Utilities Commission; URS Corporation; Biofuels, Blackgold; Carollo Engineers

    2013-01-30

    Municipal wastewater treatment facilities have typically been limited to the role of accepting wastewater, treating it to required levels, and disposing of its treatment residuals. However, a new view is emerging which includes wastewater treatment facilities as regional resource recovery centers. This view is a direct result of increasingly stringent regulations, concerns over energy use, carbon footprint, and worldwide depletion of fossil fuel resources. Resources in wastewater include chemical and thermal energy, as well as nutrients, and water. A waste stream such as residual grease, which concentrates in the drainage from restaurants (referred to as Trap Waste), is a good example of a resource with an energy content that can be recovered for beneficial reuse. If left in wastewater, grease accumulates inside of the wastewater collection system and can lead to increased corrosion and pipe blockages that can cause wastewater overflows. Also, grease in wastewater that arrives at the treatment facility can impair the operation of preliminary treatment equipment and is only partly removed in the primary treatment process. In addition, residual grease increases the demand in treatment materials such as oxygen in the secondary treatment process. When disposed of in landfills, grease is likely to undergo anaerobic decay prior to landfill capping, resulting in the atmospheric release of methane, a greenhouse gas (GHG). This research project was therefore conceptualized and implemented by the San Francisco Public Utilities Commission (SFPUC) to test the feasibility of energy recovery from Trap Waste in the form of Biodiesel or Methane gas. The research goals are given below: To validate technology performance; To determine the costs and benefits [including economic, socioeconomic, and GHG emissions reduction] associated with co-locating this type of operation at a municipal wastewater treatment plant (WWTP); To develop a business case or model for replication of the

  6. 7 CFR 981.48 - Increase of salable percentage.

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 8 2010-01-01 2010-01-01 false Increase of salable percentage. 981.48 Section 981.48... Regulating Handling Volume Regulation § 981.48 Increase of salable percentage. Upon request filed prior to... for the crop year, the Secretary may increase the salable percentage. Such findings shall be made in...

  7. 7 CFR 930.15 - Restricted percentage cherries.

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 8 2010-01-01 2010-01-01 false Restricted percentage cherries. 930.15 Section 930.15... Agreements and Orders; Fruits, Vegetables, Nuts), DEPARTMENT OF AGRICULTURE TART CHERRIES GROWN IN THE STATES... Handling Definitions § 930.15 Restricted percentage cherries. Restricted percentage cherries means...

  8. A Comparative Characteristic Study of Jatropha and Cardanol Biodiesel Blends

    Science.gov (United States)

    Pugazhenthi, R.; Chandrasekaran, M.; Muthuraman, R. K.; Vivek, P.; Parthiban, A.

    2017-03-01

    The demand in fuel needs and the depleting fossil fuels raised the need towards bio-fuels. The emerging trend in research field is highly focused on biodiesel production and their characteristic analysis. Since pollution is a major threat to the environment, emission parameter analyses are much important to be concentrated. As the entire world contains plenty of biofuels, it is necessary to explore them for its efficiency and analyze their parameters. In this experimental work jatropha and cashew nut shell biodiesel (Cardanol) was extracted and they were blended with diesel. The characteristics of jatropha and cardanol biodiesel were studied in the DI diesel engine by varying the load at the same speed. In brief, this experimental analysis is carried out to compare the emission characteristics between Jatropha biodiesel at 20% (B20) and 40% (B40) and Cardanol biodiesel blends at 20% (C20) and 40% (C40).

  9. Use of Reactive Distillation for Biodiesel Production: A Literature Survey

    Directory of Open Access Journals (Sweden)

    Muhammad Dani Supardan

    2006-06-01

    Full Text Available Biodiesel has been shown to be the best substitute for fossil-based fuels to its environmental advantages and renewable resource availability. There is a great demand for the commercialization of biodiesel production, which in turn calls for a technically and economically reactor technology. The production of biodiesel in existing batch and continuous-flow processes requires excess alcohol, typically 100%, over the stoichiometric molar requirement in order to drive the chemical reaction to completion. In this study, a novel reactor system using a reactive distillation (RD technique was discussed for biodiesel production. RD is a chemical unit operation in which chemical reactions and separations occur simultaneously in one unit. It is an effective alternative to the classical combination of reactor and separation units especially when involving reversible or consecutive chemical reactions such as transesterication process in biodiesel production.

  10. The feasibility of converting Cannabis sativa L. oil into biodiesel.

    Science.gov (United States)

    Li, Si-Yu; Stuart, James D; Li, Yi; Parnas, Richard S

    2010-11-01

    Cannabis sativa Linn, known as industrial hemp, was utilized for biodiesel production in this study. Oil from hemp seed was converted to biodiesel through base-catalyzed transesterification. The conversion is greater than 99.5% while the product yield is 97%. Several ASTM tests for biodiesel quality were implemented on the biodiesel product, including acid number, sulfur content, flash point, kinematic viscosity, and free and total glycerin content. In addition, the biodiesel has a low cloud point (-5 degrees C) and kinematic viscosity (3.48mm(2)/s). This may be attributed to the high content of poly-unsaturated fatty acid of hemp seed oil and its unique 3:1 ratio of linoleic to alpha-linolenic acid.

  11. Enzymatic biodiesel synthesis. Key factors affecting efficiency of the process

    Energy Technology Data Exchange (ETDEWEB)

    Szczesna Antczak, Miroslawa; Kubiak, Aneta; Antczak, Tadeusz; Bielecki, Stanislaw [Institute of Technical Biochemistry, Faculty of Biotechnology and Food Sciences, Technical University of Lodz, Stefanowskiego 4/10, 90-924 Lodz (Poland)

    2009-05-15

    Chemical processes of biodiesel production are energy-consuming and generate undesirable by-products such as soaps and polymeric pigments that retard separation of pure methyl or ethyl esters of fatty acids from glycerol and di- and monoacylglycerols. Enzymatic, lipase-catalyzed biodiesel synthesis has no such drawbacks. Comprehension of the latter process and an appreciable progress in production of robust preparations of lipases may soon result in the replacement of chemical catalysts with enzymes in biodiesel synthesis. Engineering of enzymatic biodiesel synthesis processes requires optimization of such factors as: molar ratio of substrates (triacylglycerols: alcohol), temperature, type of organic solvent (if any) and water activity. All of them are correlated with properties of lipase preparation. This paper reports on the interplay between the crucial parameters of the lipase-catalyzed reactions carried out in non-aqueous systems and the yield of biodiesel synthesis. (author)

  12. Heterogeneous catalysis afford biodiesel of babassu, castor oil and blends

    Energy Technology Data Exchange (ETDEWEB)

    Carvalho, Lee M.G. de; Abreu, Wiury C. de; Silva, Maria das Gracas de O. e; Matos, Jose Milton E. de; Moura, Carla V.R. de; Moura, Edmilson M. de, E-mail: mmoura@ufpi.edu.br [Universidade Federal do Piaui (UFPI), Teresina, PI (Brazil). Departamento de Quimica; Lima, Jose Renato de O.; Oliveira, Jose Eduardo de [Universidade Estadual Paulista Julio de Mesquita Filho (UNESP/IQ/CEMPEQC), Araraquara, SP (Brazil). Instituto de Quimica. Centro de Monitoramento e Pesquisa da Qualidade de Combustiveis, Biocombustiveis, Petroleo e Derivados

    2013-04-15

    This work describes the preparation of babassu, castor oil biodiesel and mixtures in various proportions of these oils, using alkaline compounds of strontium (SrCO{sub 3} + SrO + Sr (OH){sub 2}) as heterogeneous catalysts. The mixture of oils of these oleaginous sources was used in the production of biodiesel with quality parameters that meet current legislation. The catalyst was characterized by X-ray diffractometry (XDR), physisorption of gas (BET method), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDX) and Fourier transform infrared spectroscopy (FTIR). The viscometric technique was used to monitor the optimization.The transesterification reactions performed using strontium compounds reached conversion rates of 97.2% babassu biodiesel (BB), 96.4% castor oil biodiesel (COB) and 95.3% Babassu/Castor Oil Biodiesel 4:1 (BBCO41). (author)

  13. Process simulation and economical evaluation of enzymatic biodiesel production plant.

    Science.gov (United States)

    Sotoft, Lene Fjerbaek; Rong, Ben-Guang; Christensen, Knud V; Norddahl, Birgir

    2010-07-01

    Process simulation and economical evaluation of an enzymatic biodiesel production plant has been carried out. Enzymatic biodiesel production from high quality rapeseed oil and methanol has been investigated for solvent free and cosolvent production processes. Several scenarios have been investigated with different production scales (8 and 200 mio. kg biodiesel/year) and enzyme price. The cosolvent production process is found to be most expensive and is not a viable choice, while the solvent free process is viable for the larger scale production of 200 mio. kg biodiesel/year with the current enzyme price. With the suggested enzyme price of the future, both the small and large scale solvent free production proved viable. The product price was estimated to be 0.73-1.49 euro/kg biodiesel with the current enzyme price and 0.05-0.75 euro/kg with the enzyme price of the future for solvent free process.

  14. Antioxidant Effect on Oxidation Stability of Blend Fish Oil Biodiesel with Vegetable Oil Biodiesel and Petroleum Diesel Fuel

    Directory of Open Access Journals (Sweden)

    M. Hossain

    2013-06-01

    Full Text Available Two different phenolic synthetic antioxidants were used to improve the oxidation stability of fish oil biodiesel blends with vegetable oil biodiesel and petroleum diesel. Butylhydroxytoluene (BHT most effective for improvement of the oxidation stability of petro diesel, whereas  tert-butylhydroquinone (TBHQ showed good performance in fish oil biodiesel. Fish oil/Rapeseed oil biodiesel mixed showed some acceptable results in higher concentration ofantioxidants. TBHQ showed better oxidation stability than BHT in B100 composition. In fish oil biodiesel/diesel mixed fuel, BHT was more effective antioxidant than TBHQ to increase oxidationstability because BHT is more soluble than TBHQ. The stability behavior of biodiesel/diesel blends with the employment of the modified Rancimat method (EN 15751. The performance ofantioxidants was evaluated for treating fish oil biodiesel/Rapeseed oil biodiesel for B100, and blends with two type diesel fuel (deep sulfurization diesel and automotive ultra-low sulfur or zero sulfur diesels. The examined blends were in proportions of 5, 10, 15, and 20% by volume of fish oilbiodiesel.

  15. Microtox Aquatic Toxcity of Petrodiesel and Biodiesel Blends: The Role of Biodiesel's Autoxidation Products

    Science.gov (United States)

    The acute Microtox toxicity of the water accommodated fraction (WAF) of six commercial soybean biodiesel/petrodiesel blends was investigated at different oil loads. We analyzed five fatty acid methyl esters (FAMEs), C10 - C24 n-alkanes, four aromatics, methanol, and tota...

  16. Microtox Aquatic Toxcity of Petrodiesel and Biodiesel Blends: The Role of Biodiesel's Autoxidation Products

    Science.gov (United States)

    The acute Microtox toxicity of the water accommodated fraction (WAF) of six commercial soybean biodiesel/petrodiesel blends was investigated at different oil loads. We analyzed five fatty acid methyl esters (FAMEs), C10 - C24 n-alkanes, four aromatics, methanol, and tota...

  17. Regulated and unregulated emissions from a diesel engine fueled with biodiesel and biodiesel blended with methanol

    Science.gov (United States)

    Cheung, C. S.; Zhu, Lei; Huang, Zhen

    Experiments were carried out on a diesel engine operating on Euro V diesel fuel, pure biodiesel and biodiesel blended with methanol. The blended fuels contain 5%, 10% and 15% by volume of methanol. Experiments were conducted under five engine loads at a steady speed of 1800 rev min -1 to assess the performance and the emissions of the engine associated with the application of the different fuels. The results indicate an increase of brake specific fuel consumption and brake thermal efficiency when the diesel engine was operated with biodiesel and the blended fuels, compared with the diesel fuel. The blended fuels could lead to higher CO and HC emissions than biodiesel, higher CO emission but lower HC emission than the diesel fuel. There are simultaneous reductions of NO x and PM to a level below those of the diesel fuel. Regarding the unregulated emissions, compared with the diesel fuel, the blended fuels generate higher formaldehyde, acetaldehyde and unburned methanol emissions, lower 1,3-butadiene and benzene emissions, while the toluene and xylene emissions not significantly different.

  18. Process Simulation of enzymatic biodiesel production -at what cost can biodiesel be made with enzymes?

    DEFF Research Database (Denmark)

    Fjerbæk Søtoft, Lene; Christensen, Knud Villy; Rong, Benguang

    as well as environmental impacts of the alternative process must be evaluated towards the conventional process. With process simulation tools, an evaluation will be carried out looking at what it will cost to produce biodiesel with enzymes. Different scenarios will be taken into account with variations...... in raw material prices, process designs and enzyme cost and performance....

  19. Western Kentucky University Research Foundation Biodiesel Project

    Energy Technology Data Exchange (ETDEWEB)

    Pan, Wei-Ping [Principal Investigator; Cao, Yan [Co-Principal Investigator

    2013-03-15

    Petroleum-based liquid hydrocarbons is exclusively major energy source in the transportation sector. Thus, it is the major CO{sub 2} source which is the associated with greenhouse effect. In the United States alone, petroleum consumption in the transportation sector approaches 13.8 million barrels per day (Mbbl/d). It is corresponding to a release of 0.53 gigatons of carbon per year (GtC/yr), which accounts for approximate 7.6 % of the current global release of CO{sub 2} from all of the fossil fuel usage (7 GtC/yr). For the long term, the conventional petroleum production is predicted to peak in as little as the next 10 years to as high as the next 50 years. Negative environmental consequences, the frequently roaring petroleum prices, increasing petroleum utilization and concerns about competitive supplies of petroleum have driven dramatic interest in producing alternative transportation fuels, such as electricity-based, hydrogen-based and bio-based transportation alternative fuels. Use of either of electricity-based or hydrogen-based alternative energy in the transportation sector is currently laden with technical and economical challenges. The current energy density of commercial batteries is 175 Wh/kg of battery. At a storage pressure of 680 atm, the lower heating value (LHV) of H{sub 2} is 1.32 kWh/liter. In contrast, the corresponding energy density for gasoline can reach as high as 8.88 kWh/liter. Furthermore, the convenience of using a liquid hydrocarbon fuel through the existing infrastructures is a big deterrent to replacement by both batteries and hydrogen. Biomass-derived ethanol and bio-diesel (biofuels) can be two promising and predominant U.S. alternative transportation fuels. Both their energy densities and physical properties are comparable to their relatives of petroleum-based gasoline and diesel, however, biofuels are significantly environmental-benign. Ethanol can be made from the sugar-based or starch-based biomass materials, which is easily

  20. Biodiesel II: A new concept of biodiesel production - transesterification with supercritical methanol

    Directory of Open Access Journals (Sweden)

    Skala Dejan U.

    2004-01-01

    Full Text Available Biodiesel is defined as a fuel that might be used as a pure biofuel or at high concentration in mineral oil derivatives, in accordance with specific quality standards for transport applications. The main raw material used for biodiesel production is rapeseed, which contains mono-unsaturated (about 60% and also, in a lower quantity, poly-unsaturated fatty acids (C 18:1 and C 18:3, as well as some amounts of undesired saturated fatty acids (palmitic and stearic acids. Other raw materials have also been used in the research and industrial production of biodiesel (palm-oil, sunflower-oil, soybean-oil, waste plant oil, animal fats, etc. The historical background of the biodiesel production, installed industrial capacities, as well as Directives of the European Parliament and of the Council (May 2003 regarding the promotion of the use of biofuels or other renewable fuels for transport are discussed in the first part of this article (Chem. Ind. 58 (2004. The second part focused on some new concepts and the future development of technology for biodiesel production based on the use of non-catalytic transesterification under supercritical conditions. A literature review, as well as original results based on the transesterification of animal fats, plant oil and used plant oil were discussed. Obtained results were compared with the traditional concept of transesterification based on base or acid catalysis. Experimental investigations of transesterification with supercritical methanol were performed in a 2 dm3 autoclave at 140 bar pressure and at 300°C with molar ratio of methanol to triglycerides of about 41. The degree of esterification strongly depends on the density of supercritical methanol and on the possibility of reaction occurring in one phase.

  1. Isothermal calorimetry on enzymatic biodiesel production

    DEFF Research Database (Denmark)

    Fjerbæk, Lene

    2008-01-01

    conditions can not be elucidated. These effects have been observed with isothermal calorimetry bringing forth new information about the reaction of enzymes catalyzing transesterification. Enzymatic biodiesel production has until now not been investigated with isothermal microcalorimetry, but the results...... and potential of the technique used for investigations of complex and heterogeneous substrates are presented and discussed in the presentation. Reference List 1 Bianconi,M.L. (2007) Calorimetry of enzyme-catalyzed reactions.  Biophysical Chemistry, 126, 59-64. 2 Todd,M.J. and Gomez,J. (2001) Enzyme Kinetics...... Determined Using Calorimetry: A General Assay for Enzyme Activity?  Analytical Biochemistry, 296, 179-187....

  2. A comprehensive review on biodiesel purification and upgrading

    Directory of Open Access Journals (Sweden)

    Hamed Bateni

    2017-09-01

    Full Text Available Serious environmental concerns regarding the use of fossil-based fuels have raised awareness regarding the necessity of alternative clean fuels and energy carriers. Biodiesel is considered a clean, biodegradable, and non-toxic diesel substitute produced via the transesterification of triglycerides with an alcohol in the presence of a proper catalyst. After initial separation of the by-product (glycerol, the crude biodiesel needs to be purified to meet the standard specifications prior to marketing. The presence of impurities in the biodiesel not only significantly affects its engine performance but also complicates its handling and storage. Therefore, biodiesel purification is an essential step prior to marketing. Biodiesel purification methods can be classified based on the nature of the process into equilibrium-based, affinity-based, membrane-based, reaction-based, and solid-liquid separation processes. The main adverse properties of biodiesel – namely moisture absorption, corrosiveness, and high viscosity – primarily arise from the presence of oxygen. To address these issues, several upgrading techniques have been proposed, among which catalytic (hydrodeoxygenation using conventional hydrotreating catalysts, supported metallic materials, and most recently transition metals in various forms appear promising. Nevertheless, catalyst deactivation (via coking and/or inadequacy of product yields necessitate further research. This paper provides a comprehensive overview on the techniques and methods used for biodiesel purification and upgrading.

  3. [Progress on biodiesel production with enzymatic catalysis in China].

    Science.gov (United States)

    Tan, Tianwei; Lu, Jike; Nie, Kaili; Zhang, Haixia; Deng, Li; Wang, Fang

    2010-07-01

    This paper reports the progress of biodiesel production with enzymatic catalysis in Beijing University of Chemical Technology, one of the leaders in biodiesel R & D in China, which includes screening of high-yield lipase production strains, optimization and scale-up of the lipase fermentation process, lipase immobilization, bioreactor development and scale-up, biodiesel separation and purification and the by-product glycerol utilization. Firstly, lipase fermentation was carried out at industrial scale with the 5 m3 stirred tank bioreactor, and the enzyme activity as high as 8 000 IU/mL was achieved by the species Candida sp. 99-125. Then, the lipase was purified and immobilized on textile membranes. Furthermore, biodiesel production was performed in the 5 m3 stirred tank bioreactor with an enzyme dosage as low as 0.42%, and biodiesel that met the German biodiesel standard was produced. And in the meantime, the byproduct glycerol was used for the production of 1,3-propanediol to partly offset the production cost of biodiesel, and 76.1 g/L 1,3-propanediol was obtained in 30 L fermentor with the species Klebsiella pneumoniae.

  4. Methanolysis of Carica papaya Seed Oil for Production of Biodiesel

    Directory of Open Access Journals (Sweden)

    Foluso O. Agunbiade

    2014-01-01

    Full Text Available The future of fossil fuel sources of energy has necessitated the need to search for renewable alternatives. Thus, Carica papaya seed oil (CPSO was employed as feedstock for the production of biodiesel by methanolysis. The seed was obtained locally, dried, and extracted with n-hexane. The CPSO was analyzed for specific gravity, viscosity, iodine value, and saponification value, among others using standard methods. The oil was transesterified by two-stage catalysis with oil to methanol mole ratio of 1 : 9. The biodiesel produced was subjected to standard fuel tests. The seed has an oil yield of 31.2% which is commercially viable. The kinematic viscosity of the oil at 313 K was 27.4 mm2s−1 while that of Carica papaya oil methylester (CPOME was reduced to 3.57 mm2s−1 and the specific gravity was 0.84 comparable with other seed-oil biodiesels and number 2 diesel. Other oil properties were compared favourably with seed oils already documented for biodiesel synthesis. CPOME’s cloud and pour points were 275 K and 274 K, respectively, and relatively higher than other biodiesels and number 2 diesel. CPOME exhibits moderate corrosion of copper strip. The methanolysis improved the fuel properties of the CPOME similar to other biodiesels. CPSO therefore exhibits a potential for biodiesel production.

  5. Prospects of biodiesel production from microalgae in India

    Energy Technology Data Exchange (ETDEWEB)

    Khan, Shakeel A.; Hussain, Mir Z.; Prasad, S. [Division of Environmental Sciences, Indian Agricultural Research Institute, New Delhi 110012 (India); Rashmi; Banerjee, U.C. [Department of Pharmaceutical Technology (Biotechnology), National Institute of Pharmaceutical and Education Research (NIPER), Sector 67, Phase X, S.A.S. Nagar, Mohali 160062, Punjab (India)

    2009-12-15

    Energy is essential and vital for development, and the global economy literally runs on energy. The use of fossil fuels as energy is now widely accepted as unsustainable due to depleting resources and also due to the accumulation of greenhouse gases in the environment. Renewable and carbon neutral biodiesel are necessary for environmental and economic sustainability. Biodiesel demand is constantly increasing as the reservoir of fossil fuel are depleting. Unfortunately biodiesel produced from oil crop, waste cooking oil and animal fats are not able to replace fossil fuel. The viability of the first generation biofuels production is however questionable because of the conflict with food supply. Production of biodiesel using microalgae biomass appears to be a viable alternative. The oil productivity of many microalgae exceeds the best producing oil crops. Microalgae are photosynthetic microorganisms which convert sunlight, water and CO{sub 2} to sugars, from which macromolecules, such as lipids and triacylglycerols (TAGs) can be obtained. These TAGs are the promising and sustainable feedstock for biodiesel production. Microalgal biorefinery approach can be used to reduce the cost of making microalgal biodiesel. Microalgal-based carbon sequestration technologies cover the cost of carbon capture and sequestration. The present paper is an attempt to review the potential of microalgal biodiesel in comparison to the agricultural crops and its prospects in India. (author)

  6. Biodiesel Fuel Production from Algae as Renewable Energy

    Directory of Open Access Journals (Sweden)

    A. B.M. Sharif Hossain

    2008-01-01

    Full Text Available Biodiesel is biodegradable, less CO2 and NOx emissions. Continuous use of petroleum sourced fuels is now widely recognized as unsustainable because of depleting supplies and the contribution of these fuels to the accumulation of carbon dioxide in the environment. Renewable, carbon neutral, transport fuels are necessary for environmental and economic sustainability. Algae have emerged as one of the most promising sources for biodiesel production. It can be inferred that algae grown in CO2-enriched air can be converted to oily substances. Such an approach can contribute to solve major problems of air pollution resulting from CO2 evolution and future crisis due to a shortage of energy sources. This study was undertaken to know the proper transesterification, amount of biodiesel production (ester and physical properties of biodiesel. In this study we used common species Oedogonium and Spirogyra to compare the amount of biodiesel production. Algal oil and biodiesel (ester production was higher in Oedogonium than Spirogyra sp. However, biomass (after oil extraction was higher in Spirogyra than Oedogonium sp. Sediments (glycerine, water and pigments was higher in Spirogyra than Oedogonium sp. There was no difference of pH between Spirogyra and Oedogonium sp. These results indicate that biodiesel can be produced from both species and Oedogonium is better source than Spirogyra sp.

  7. Spontaneous ignition of biodiesel: A potential fire risk

    Directory of Open Access Journals (Sweden)

    Shibata Yasuhito

    2008-01-01

    Full Text Available The spontaneous ignition of biodiesel was for the first time suspected to be the cause of a recent fire in Japan. We herein present experimental evidence implying this potential risk of biodiesel. Thus, three independent biodiesel samples were subjected to a series of experiments, including a thermogravimetry-differential thermal analysis, a differential scanning calorimetry analysis and a modified wire basket test. The results were comparatively evaluated with reference to vegetable oils, of which spontaneous ignition has been well reported as a cause of fires. The heat onset temperature of biodiesel samples was determined to be ~100 °C, which was ~45 °C lower than those of vegetable oils. Furthermore, under the isothermal condition at 100 °C, the inner temperature of biodiesel samples rose rapidly with the generation of smoke after short induction periods owing to their exothermal decomposition, whereas for vegetable oils neither change in the inside temperature nor generation of smoke was observed even after 10 hours. It was therefore concluded that biodiesel possesses the higher risk of spontaneous ignition than vegetable oils. This is very important information to minimize the fire risk in biodiesel production facilities and so on. .

  8. Production of Biodiesel from Vegetable Oil Using Microware Irradiation

    Directory of Open Access Journals (Sweden)

    N. Kapilan

    2012-01-01

    Full Text Available The petroleum oil supply crisis, the increase in demand and the price eruption have led to a search for an alternative fuel of bio-origin in India. Among the alternative fuels, biodiesel is considered as a sustainable renewable alternative fuel to fossil diesel. Non-edible jatropha oil has considerable potential for the production of biodiesel in India. The production of biodiesel from jatropha oil using a conventional heating method takes more than 1h. In this work, microwave irradiation has been used as a source of heat for the transesterification reaction. A domestic microwave oven was modified and used for microwave heating of the reactants. The time taken for biodiesel production using microwave irradiation was 1 min. The fuel property analysis shows that the properties of jatropha oil biodiesel satisfy the biodiesel standards, and are close to the fossil diesel standards. From this work, it is concluded that biodiesel can be produced from vegetable oil using microwave irradiation, with a significant reduction in production time.

  9. Prospects of dedicated biodiesel engine vehicles in Malaysia and Indonesia

    Energy Technology Data Exchange (ETDEWEB)

    Jayed, M.H.; Masjuki, H.H.; Kalam, M.A.; Mahlia, T.M.I.; Liaquat, A.M. [Centre for Energy Sciences, Faculty of Engineering, University of Malaya, 50603 Kuala Lumpur (Malaysia); Husnawan, M. [Centre for Energy Sciences, Faculty of Engineering, University of Malaya, 50603 Kuala Lumpur (Malaysia); Department of Mechanical Engineering University of Syiah Kuala, Jl. S. Abd. Rauf No. 7, Darussalam - Banda Aceh (Indonesia)

    2011-01-15

    Petro diplomacy has played its role in last few decades and that makes energy security a major concern worldwide. Rapid climate change and environmental protection is another vital issue to be addressed in recent energy policies. So an alternative carbon neutral transport fuel is a must in new sustainable energy mix. Biodiesel has immense potentiality to be a part of a sustainable energy mix. In this energy scenario, Brazil's success is a role model in utilizing its agro-industry for reducing poverty, greenhouse gas emission and petro-dependency simultaneously. Brazil commercialized bioethanol in mass scale by introducing flexible fuel vehicles in market. This dedicated engine idea moralizes a new concept of dedicated biodiesel engine vehicles for Malaysia and Indonesia. Southeast Asian countries, i.e. Malaysia and Indonesia is the largest producer as well as exporter of palm oil. Growing at highest yield rate among other biodiesel feedstock, palm based biodiesel is a top exported product for this region. This paper will quantify the prospects of a dedicated biodiesel engine vehicle for Malaysia and Indonesia that will initiate palm based biodiesel in fuel supply chain by leapfrogging the barriers of biodiesel utilization by boosting local automobile industry simultaneously. This article will also review on energy scenario of Malaysia and Indonesia and their renewable energy policies and challenges for coming decades. (author)

  10. Development of Brazilian Biodiesel Sector from the Perspective of Stakeholders

    Directory of Open Access Journals (Sweden)

    Bárbara Françoise Cardoso

    2017-03-01

    Full Text Available In Brazil, the main program with respect to biodiesel is the National Program of Biodiesel Production and Use (NPBP. It is also considered the regulation mark of biodiesel production in Brazil and its directives are social inclusion and regional development. Considering these directives, this paper aims to analyse the perspective of biodiesel sector stakeholders in Brazil to understand whether NPBP directives are in consonance with the reality of the sector for its development. A questionnaire was created with 48 questions in order to understand the importance of 13 variables for the stakeholders, and the responses were treated by factor analysis (FA. The results showed the existence of a trade-off related to technological advances in biodiesel production that confronts NPBP directives, that is, the biodiesel sector tends not to evolve in terms of the use of advanced technologies. If policies change so as to develop the biodiesel sector using advanced technologies, NPBP should change its directives in order to involve family farmers in another way in the Brazilian economy.

  11. Relationship between fatty acid composition and biodiesel quality for nine commercial palm oils

    Directory of Open Access Journals (Sweden)

    Chanida Lamaisri

    2015-08-01

    Full Text Available Biodiesel is an alternative fuel consisting of alkyl esters of fatty acids from vegetable oils or animal fats. The fatty acid compositions in the oils used as feedstock can influence quality of the biodiesel. In the present study, oil content and fatty acid composition of mesocarp and kernel oil were examined from nine commercial oil palm Elaeis guineensis cultivars. Saponification number, iodine value and cetane number were calculated from palm oil fatty acid methyl ester compositions. Fruits of tenera oil palm were collected from a farmer’s plantation in Dan Makham Tia District, Kanchanaburi Province in 2009. Variation between cultivars was observed in oil content and fatty acid profile of mesocarp oil rather than kernel oil. The percentage of oil in dry mesocarp ranged from 63.8% to 74.9%. The mesocarp oil composed of 41.5 - 51.6% palmitic acid, 3.58-7.10% stearic acid, 32.8-42.5% oleic acid and 9.3-13.0% linoleic acid. Likewise saponification number, iodine value and cetane number of mesocarp oil fatty acid methyl ester showed more variation among cultivars, ranging from 196.5-198.9, 45.7-54.6 and 61.8-63.6, respectively. While those of kernel oil fatty acid methyl ester showed no different among cultivars, ranging from 229-242, 13.6-16.4 and 65.3-66.5, respectively. The cetane number of fatty acid methyl ester positively correlated with contents of myristic, palmitic and stearic acids in palm oil and saponification number of biodiesel, but negatively correlated with iodine value

  12. Development of novel alternative biodiesel fuels for reducing PM emissions and PM-related genotoxicity.

    Science.gov (United States)

    Yang, Po-Ming; Wang, Chia-Chi; Lin, Ying-Chi; Jhang, Syu-Ruei; Lin, Li-Jung; Lin, Yuan-Chung

    2017-07-01

    This paper intend to investigate the effects of biodiesel fuel blends comprising of waste-cooking oil and butanol-diesel (B10W10-B10W40) under steady-state conditions. Both particulate organic carbon (OC) and PM including PM2.5 and PM10 significantly decreased with the increasing percentage of biodiesel fuel blends. The fuel blend of B10W40 also demonstrated the most effective function in reducing the emissions of PM10 and PM2.5 in the volume by 59.4% and 57.7%, respectively. Moreover, the emissions of nitrogen oxides decreased with the blending of B10W10-B10W40 (13.9-28.5%), while the brake specific fuel consumption was substantially increased (5.69-13.4%). The overall biological toxicity of PM10 generated from the fuel tested in this study was determined according to Single Cell Gel Electrophoresis assay in human alveolar basal epithelial A549 cells and micronucleus assay in CHO-K1 cells. In addition, the volume of more than 20% waste-cooking oil (B10W20 and B10W40) significantly reduced diesel-induced genotoxicity in lung cells and micronucleus formation in CHO-K1 cells. Collectively, these results indicated that biodiesel fuel blends with the butanol could be a potential alternative fuels for diesel engines because of its substantial property with a significant reduction of the PM-related genotoxicity and the emissions of PM, particulate OC, and NOX. Copyright © 2017 Elsevier Inc. All rights reserved.

  13. AC Own Motion Percentage of Randomly Sampled Cases

    Data.gov (United States)

    Social Security Administration — Longitudinal report detailing the numbers and percentages of Appeals Council (AC) own motion review actions taken on un-appealed favorable hearing level decisions...

  14. Optimisation of biodiesel production by sunflower oil transesterification.

    Science.gov (United States)

    Antolín, G; Tinaut, F V; Briceño, Y; Castaño, V; Pérez, C; Ramírez, A I

    2002-06-01

    In this work the transformation process of sunflower oil in order to obtain biodiesel by means of transesterification was studied. Taguchi's methodology was chosen for the optimisation of the most important variables (temperature conditions, reactants proportion and methods of purification), with the purpose of obtaining a high quality biodiesel that fulfils the European pre-legislation with the maximum process yield. Finally, sunflower methyl esters were characterised to test their properties as fuels in diesel engines, such as viscosity, flash point, cold filter plugging point and acid value. Results showed that biodiesel obtained under the optimum conditions is an excellent substitute for fossil fuels.

  15. Enzymatic reactors for biodiesel synthesis: Present status and future prospects.

    Science.gov (United States)

    Poppe, Jakeline Kathiele; Fernandez-Lafuente, Roberto; Rodrigues, Rafael C; Ayub, Marco Antônio Záchia

    2015-01-01

    Lipases are being extensively researched for the production of biodiesel as a "silver bullet" in order to avoid the drawbacks of the traditional alkaline transesterification. In this review, we analyzed the main factors involved in the enzymatic synthesis of biodiesel, focusing in the choice of the immobilization protocol, and the parameters involved in the choice and configuration of the reactors. An extensive discussion is presented about the advantages and disadvantages of each type of reactor and their mode of operation. The current scenario of the market for enzymatic biodiesel and some future prospects and necessary developments are also briefly presented.

  16. Transesterification of Palm Oil for the Production of Biodiesel

    Directory of Open Access Journals (Sweden)

    Khalizani Khalid

    2011-01-01

    Full Text Available Problem statement: Palm oil is known as an important source of edible oil with significant values of renewable energy. Depletion of petroleum had captured much attention on producing biodiesel from the palm oil. Approach: The most concerning methods for the production of biodiesel were discussed, namely transesterification (alkali and acid, enzymetic approach and supercritical alcohol. Results: The results showed the vis-a-vis of the methods for possible consideration of research. Conclusion: Concerning the importance of this vegetable oil, the contribution of palm oil towards diminution of fossil fuel, possible methods for the production of biodiesel and the opportunity for the futures is very much important.

  17. Continuous production of lipase-catalyzed biodiesel in a packed-bed reactor: optimization and enzyme reuse study.

    Science.gov (United States)

    Chen, Hsiao-Ching; Ju, Hen-Yi; Wu, Tsung-Ta; Liu, Yung-Chuan; Lee, Chih-Chen; Chang, Cheng; Chung, Yi-Lin; Shieh, Chwen-Jen

    2011-01-01

    An optimal continuous production of biodiesel by methanolysis of soybean oil in a packed-bed reactor was developed using immobilized lipase (Novozym 435) as a catalyst in a tert-butanol solvent system. Response surface methodology (RSM) and Box-Behnken design were employed to evaluate the effects of reaction temperature, flow rate, and substrate molar ratio on the molar conversion of biodiesel. The results showed that flow rate and temperature have significant effects on the percentage of molar conversion. On the basis of ridge max analysis, the optimum conditions were as follows: flow rate 0.1 mL/min, temperature 52.1°C, and substrate molar ratio 1 : 4. The predicted and experimental values of molar conversion were 83.31 ± 2.07% and 82.81 ± .98%, respectively. Furthermore, the continuous process over 30 days showed no appreciable decrease in the molar conversion. The paper demonstrates the applicability of using immobilized lipase and a packed-bed reactor for continuous biodiesel synthesis.

  18. Continuous Production of Lipase-Catalyzed Biodiesel in a Packed-Bed Reactor: Optimization and Enzyme Reuse Study

    Directory of Open Access Journals (Sweden)

    Hsiao-Ching Chen

    2011-01-01

    Full Text Available An optimal continuous production of biodiesel by methanolysis of soybean oil in a packed-bed reactor was developed using immobilized lipase (Novozym 435 as a catalyst in a tert-butanol solvent system. Response surface methodology (RSM and Box-Behnken design were employed to evaluate the effects of reaction temperature, flow rate, and substrate molar ratio on the molar conversion of biodiesel. The results showed that flow rate and temperature have significant effects on the percentage of molar conversion. On the basis of ridge max analysis, the optimum conditions were as follows: flow rate 0.1 mL/min, temperature 52.1∘C, and substrate molar ratio 1 : 4. The predicted and experimental values of molar conversion were 83.31±2.07% and 82.81±.98%, respectively. Furthermore, the continuous process over 30 days showed no appreciable decrease in the molar conversion. The paper demonstrates the applicability of using immobilized lipase and a packed-bed reactor for continuous biodiesel synthesis.

  19. Performance and Emission Characteristics of a Compression Ignition Engine Operating on Blends of Castor Oil Biodiesel-Diesel

    Science.gov (United States)

    Kanwar, Roopesh; Sharma, Pushpendra Kumar; Singh, Aditya Narayan; Agrawal, Yadvendra Kumar

    2016-06-01

    Diesel vehicles are the nerves and veins of transportation, particularly in developing countries. With the rapid rate of modernization, increasing demand of fuel is inevitable. The exponential increase in fuel prices and the scarcity of its supply from the environment have promoted interest in the development of alternative sources of fuel. In this work, genus Ricinus communis L. was studied in order to delimit their potential as a raw material for biodiesel production. Further, castor oil, ethyl ester were prepared by transesterification using potassium hydroxide (KOH) as a catalyst and tested on a four-stroke, single-cylinder compression ignition engine. The test was carried out at a constant speed of 3000 rpm at different loads. The results represent a substantial decrease in carbon monoxide (CO) emission with an increasing biodiesel percentage. The reduction of CO in B05, B10, B15 and B20 averaged 11.75, 22.02, 24.23 and 28.79 %, respectively, compared to mineral diesel. The emission results of the comparative test indicated that CO, oxygen (O2) and smoke density emissions are found to be lower when the engine is filled with B05, B10, B15 and B20 as compared to mineral diesel, while carbon dioxide (CO2) and nitrogen oxide (NOx) with B05, B10, B15 and B20 are found to increase marginally. Brake thermal efficiency and brake specific fuel consumption decrease and increase respectively in biodiesel with different blends in comparison of mineral diesel.

  20. Performance and Emission Characteristics of a Compression Ignition Engine Operating on Blends of Castor Oil Biodiesel-Diesel

    Science.gov (United States)

    Kanwar, Roopesh; Sharma, Pushpendra Kumar; Singh, Aditya Narayan; Agrawal, Yadvendra Kumar

    2017-04-01

    Diesel vehicles are the nerves and veins of transportation, particularly in developing countries. With the rapid rate of modernization, increasing demand of fuel is inevitable. The exponential increase in fuel prices and the scarcity of its supply from the environment have promoted interest in the development of alternative sources of fuel. In this work, genus Ricinus communis L. was studied in order to delimit their potential as a raw material for biodiesel production. Further, castor oil, ethyl ester were prepared by transesterification using potassium hydroxide (KOH) as a catalyst and tested on a four-stroke, single-cylinder compression ignition engine. The test was carried out at a constant speed of 3000 rpm at different loads. The results represent a substantial decrease in carbon monoxide (CO) emission with an increasing biodiesel percentage. The reduction of CO in B05, B10, B15 and B20 averaged 11.75, 22.02, 24.23 and 28.79 %, respectively, compared to mineral diesel. The emission results of the comparative test indicated that CO, oxygen (O2) and smoke density emissions are found to be lower when the engine is filled with B05, B10, B15 and B20 as compared to mineral diesel, while carbon dioxide (CO2) and nitrogen oxide (NOx) with B05, B10, B15 and B20 are found to increase marginally. Brake thermal efficiency and brake specific fuel consumption decrease and increase respectively in biodiesel with different blends in comparison of mineral diesel.

  1. Biomass for biodiesel production on family farms in Brazil: promise or failure? : integrated assessment of biodiesel crops, farms, policies and producer organisations

    NARCIS (Netherlands)

    Belo Leite, Dal J.G.

    2013-01-01

    In Brazil, a biodiesel policy was implemented as a way of reducing poverty among family farms. The objective of this thesis is to perform an integrated assessment of biodiesel crops, farm types, biodiesel policies and producer organisations that reveals opportunities and limitations of family

  2. Calorific value for compositions with biodiesel of fat chicken and diesel oil; Valor calorifico para composicoes com biodiesel da gordura de frango e oleo diesel

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Marcelo Jose da [Universidade de Campinas (FEAGRI/UNICAMP), SP (Brazil). Fac. de Engenharia Agricola], email: marcelo.jose@feagri.unicamp.br; Souza, Samuel N.M. de; Souza, Abel A. de; Martins, Gislaine I. [Universidade Estadual do Oeste do Parana (CCET/UNIOESTE), Cascavel, PR (Brazil). Centro de Ciencias Exatas e Tecnologicas], emails: ssouza@unioeste.br, abel.sza@hotmail.com, iastiaque@yahoo.com.br

    2011-07-01

    The biodiesel fuel is a renewable source of alternative fuel used in diesel cycle engines. The production of biodiesel involves the reaction of methanol with fatty acids of animal or vegetable. The production of biodiesel from chicken fat can be very attractive for some regions from Brazil with high poultry production, as in the Parana West and Santa Catarina West. In this study , the goal was the lower calorific value of the compositions between biodiesel and diesel oil: 100% Diesel oil (B0), 20% biodiesel (B20), 40% biodiesel (B40), 60% biodiesel (B60), 80% biodiesel (B80 ), 100% biodiesel (B100). The biodiesel used was acquired in the Centre for Development and Diffusion of technologies on the Assis Gurgacz College, in Cascavel city. The nominal production capacity of the unit is 900 liters on period of 8 hours. The model of the calorimeter used, was the E2K. The lower calorific value of B100 composition was 35.388 MJ kg-1 and the diesel oil was 41.299 MJ kg-1. With the measuring of the caloric value of six samples mix of diesel oil and biodiesel, was obtained a linear function decrease of the calorific value when increased it the proportion of biodiesel from chicken fat into fuel. (author)

  3. Biomass for biodiesel production on family farms in Brazil: promise or failure? : integrated assessment of biodiesel crops, farms, policies and producer organisations

    NARCIS (Netherlands)

    Belo Leite, Dal J.G.

    2013-01-01

    In Brazil, a biodiesel policy was implemented as a way of reducing poverty among family farms. The objective of this thesis is to perform an integrated assessment of biodiesel crops, farm types, biodiesel policies and producer organisations that reveals opportunities and limitations of family farmer

  4. Bio-Diesel production and Effect of Catalytic Converter on Emission performance with Bio-Diesel Blends

    Directory of Open Access Journals (Sweden)

    R.Murali Manohar

    2010-06-01

    Full Text Available Bio-Diesel the word itself defines almost all the features of the Bio-Diesel literary. In the Era of this Global Warming where the people are making their living more and more comfortable and they are deteriorating the environment also. The uses of the automobiles with the conventional source of fuel leads to the production of the toxic gaseous substances like carbon monoxide, carbon dioxide, oxides of nitrogen, oxide of sulphur, hydro-carbons etc. The limitation comes with the rise in the price of the fuel as well as the produce of the green house gases as the exhaust gas. In the present study, a new method has been employed to produce Bio-Diesel in a homely basis. Theproduction of the Bio-Diesel is done by using Bio-Diesel processor. It requires the used vegetable oil, methanol and the lye with the accurate proportionate. Generally, emissions of regulated compounds changed linearly with the blend level. The objective is to detect any posit ive or negative effects depending on blend levels, because conventional diesel fuel and biodiesel can be blended in every ratio. The known positive and negative effects of biodiesel varied accordingly and investigate the effect of Catalytic Converter on emission performance with Bio- Diesel Blends.

  5. BACTERIAL COMMUNITY DYNAMICS AND ECOTOXICOLOGICAL ASSESSMENT DURING BIOREMEDIATION OF SOILS CONTAMINATED BY BIODIESEL AND DIESEL/BIODIESEL BLENDS.

    Science.gov (United States)

    Matos, G I; Junior, C S; Oliva, T C; Subtil, D F; Matsushita, L Y; Chaves, A L; Lutterbach, M T; Sérvulo, E F; Agathos, S N; Stenuit, B

    2015-01-01

    The gradual introduction of biodiesel in the Brazilian energy landscape has primarily occurred through its blending with conventional petroleum diesel (e.g., B20 (20% biodiesel) and B5 (5% biodiesel) formulations). Because B20 and lower-level blends generally do not require engine modifications, their use as transportation fuel is increasing in the Brazilian distribution networks. However, the environmental fate of low-level biodiesel blends and pure biodiesel (B100) is poorly understood and the ecotoxicological-safety endpoints of biodiesel-contaminated environments are unknown. Using laboratory microcosms consisting of closed reactor columns filled with clay loam soil contaminated with pure biodiesel (EXPB100) and a low-level blend (EXPB5) (10% w/v), this study presents soil ecotoxicity assessement and dynamics of culturable heterotrophic bacteria. Most-probable-number (MPN) procedures for enumeration of bacteria, dehydrogenase assays and soil ecotoxicological tests using Eisenia fetida have been performed at different column depths over the course of incubation. After 60 days of incubation, the ecotoxicity of EXPB100-derived samples showed a decrease from 63% of mortality to 0% while EXPB5-derived samples exhibited a reduction from 100% to 53% and 90% on the top and at the bottom of the reactor column, respectively. The dehydrogenase activity of samples from EXPB100 and EXPB5 increased significantly compared to pristine soil after 60 days of incubation. Growth of aerobic bacterial biomass was only observed on the top of the reactor column while the anaerobic bacteria exhibited significant growth at different column depths in EXPB100 and EXPB5. These preliminary results suggest the involvement of soil indigenous microbiota in the biodegradation of biodiesel and blends. However, GC-FID analyses for quantification of fatty acid methyl esters (FAMEs) and aliphatic hydrocarbons and targeted sequencing of 16S rRNA tags using illumina platforms will provide important

  6. Extended exergy accounting applied to biodiesel production

    Energy Technology Data Exchange (ETDEWEB)

    Talens Peiro, L. [SosteniPrA (UAB-IRTA), Institute of Environmental Science and Technology (ICTA), Edifici Q-ETSE, Room QC 3101, Universitat Autonoma de Barcelona (UAB), E-08193 Bellaterra (Cerdanyola del Valles), Barcelona (Spain); Villalba Mendez, G.; Gabarrell i Durany, X. [SosteniPrA (UAB-IRTA), Institute of Environmental Science and Technology (ICTA), Edifici Q-ETSE, Room QC 3101, Universitat Autonoma de Barcelona (UAB), E-08193 Bellaterra (Cerdanyola del Valles), Barcelona (Spain); Department of Chemical Engineering, Edifici Q, Universitat Autonoma de Barcelona (UAB), E- 08193, Bellaterra (Cerdanyola del Valles), Barcelona (Spain); Sciubba, E. [Department of Mechanical and Aeronautical Engineering, University of Roma 1 ' ' La Sapienza' ' , Via Eudossiana 18, I-00184 Roma (Italy)

    2010-07-15

    When evaluating the production of renewable energies such as biofuels, it is necessary to include in the assessment the resource inputs, capital, labor investment and environmental remediation costs. Extended Exergy Accounting (EEA) is a system analysis method that calculates, on the basis of detailed mass and exergy balances, the total amount of primary exergy resources necessary to obtain a product or service. The conceptual novelty of EEA is represented by the fact that it also includes externalities (capital, labor and environmental impact) measured in homogeneous units (Joules). As an illustration of EEA, we assess and compare the production of 1 ton of biodiesel from used cooking oil (UCOME) and rapeseed crops (RME). The extended exergy ''content'' of UCOME and RME are 51.90 GJ and 77.05 GJ respectively. The production of UCOME uses 25.15 GJ less resources (materials and energy) and requires lower total investments and environmental remediation costs than that of RME. On the other hand, UCOME requires 35% more workhours. In summary, the extended exergy of UCOME is about 1.5 the extended exergy content of RME. Thus, we can conclude that biodiesel production from UCO is less resource use intensive than the production from RME. (author)

  7. Digital image-based classification of biodiesel.

    Science.gov (United States)

    Costa, Gean Bezerra; Fernandes, David Douglas Sousa; Almeida, Valber Elias; Araújo, Thomas Souto Policarpo; Melo, Jessica Priscila; Diniz, Paulo Henrique Gonçalves Dias; Véras, Germano

    2015-07-01

    This work proposes a simple, rapid, inexpensive, and non-destructive methodology based on digital images and pattern recognition techniques for classification of biodiesel according to oil type (cottonseed, sunflower, corn, or soybean). For this, differing color histograms in RGB (extracted from digital images), HSI, Grayscale channels, and their combinations were used as analytical information, which was then statistically evaluated using Soft Independent Modeling by Class Analogy (SIMCA), Partial Least Squares Discriminant Analysis (PLS-DA), and variable selection using the Successive Projections Algorithm associated with Linear Discriminant Analysis (SPA-LDA). Despite good performances by the SIMCA and PLS-DA classification models, SPA-LDA provided better results (up to 95% for all approaches) in terms of accuracy, sensitivity, and specificity for both the training and test sets. The variables selected Successive Projections Algorithm clearly contained the information necessary for biodiesel type classification. This is important since a product may exhibit different properties, depending on the feedstock used. Such variations directly influence the quality, and consequently the price. Moreover, intrinsic advantages such as quick analysis, requiring no reagents, and a noteworthy reduction (the avoidance of chemical characterization) of waste generation, all contribute towards the primary objective of green chemistry.

  8. Oil extraction from microalgae for biodiesel production.

    Science.gov (United States)

    Halim, Ronald; Gladman, Brendan; Danquah, Michael K; Webley, Paul A

    2011-01-01

    This study examines the performance of supercritical carbon dioxide (SCCO(2)) extraction and hexane extraction of lipids from marine Chlorococcum sp. for lab-scale biodiesel production. Even though the strain of Chlorococcum sp. used in this study had a low maximum lipid yield (7.1 wt% to dry biomass), the extracted lipid displayed a suitable fatty acid profile for biodiesel [C18:1 (∼63 wt%), C16:0 (∼19 wt%), C18:2 (∼4 wt%), C16:1 (∼4 wt%), and C18:0 (∼3 wt%)]. For SCCO(2) extraction, decreasing temperature and increasing pressure resulted in increased lipid yields. The mass transfer coefficient (k) for lipid extraction under supercritical conditions was found to increase with fluid dielectric constant as well as fluid density. For hexane extraction, continuous operation with a Soxhlet apparatus and inclusion of isopropanol as a co-solvent enhanced lipid yields. Hexane extraction from either dried microalgal powder or wet microalgal paste obtained comparable lipid yields. Copyright © 2010 Elsevier Ltd. All rights reserved.

  9. Odour Prevention at Biodiesel Fuel Producing Enterprises

    Directory of Open Access Journals (Sweden)

    Kristina Montrimaite

    2012-03-01

    Full Text Available Gaseous, unpleasant, pungent and even harmful odour frequently leads to complaints and appeals to the authorities. For this reason an environmental review was carried out in a certain biodiesel fuel production enterprise, odour pollution sources were identified, their quantities estimated and their impact on the environment assessed. Following the initial environmental review, significant environmental aspects of biodiesel fuel production processes were evaluated. It was found that in technological processes of heating and pressing oil, triglycerides disintegrated in aromas causing discomfort. In order to reduce this impact, the appropriate economic management method and odour removal equipment are to be chosen. When solving this problem it is suggested to install biofilters - activated carbon adsorbers with a stationary adsorber layer and probiotics. In order to choose the adsorber, a calculation method of adsorber technical parameters has been developed in accordance with literature data. The proposed preventive odour reduction means and feasibility of their technical and economical application have been analysed.DOI: http://dx.doi.org/10.5755/j01.erem.59.1.676

  10. Genomic Prospecting for Microbial Biodiesel Production

    Energy Technology Data Exchange (ETDEWEB)

    Lykidis, Athanasios; Lykidis, Athanasios; Ivanova, Natalia

    2008-03-20

    Biodiesel is defined as fatty acid mono-alkylesters and is produced from triacylglycerols. In the current article we provide an overview of the structure, diversity and regulation of the metabolic pathways leading to intracellular fatty acid and triacylglycerol accumulation in three types of organisms (bacteria, algae and fungi) of potential biotechnological interest and discuss possible intervention points to increase the cellular lipid content. The key steps that regulate carbon allocation and distribution in lipids include the formation of malonyl-CoA, the synthesis of fatty acids and their attachment onto the glycerol backbone, and the formation of triacylglycerols. The lipid biosynthetic genes and pathways are largely known for select model organisms. Comparative genomics allows the examination of these pathways in organisms of biotechnological interest and reveals the evolution of divergent and yet uncharacterized regulatory mechanisms. Utilization of microbial systems for triacylglycerol and fatty acid production is in its infancy; however, genomic information and technologies combined with synthetic biology concepts provide the opportunity to further exploit microbes for the competitive production of biodiesel.

  11. Investigation of palm methyl-ester bio-diesel with additive on performance and emission characteristics of a diesel engine under 8-mode testing cycle

    Directory of Open Access Journals (Sweden)

    S. Senthilkumar

    2015-09-01

    Full Text Available Biodiesel is receiving increasing attention each passing day because of its same diesel-like fuel properties and compatibility with petroleum-based diesel fueled engines. Therefore, in this paper the prospects and opportunities of using various blends of methyl esters of palm oil as fuel in an engine with and without the effect of multi-functional fuel additive (MFA, Multi DM 32 are studied to arrive at an optimum blend of bio-diesel best suited for low emissions and minimal power drop. Experimental tests were conducted on a four stroke, three cylinder and naturally aspirated D.I. Diesel engine with diesel and various blend percentages of 20%, 40%, 45%, and 50% under the 8 mode testing cycle. The effect of fuel additive was tested out on the optimum blend ratio of the bio-diesel so as to achieve further reduced emissions. Comparison of results shows that, 73% reduction in hydrocarbon emission, 46% reduction in carbon monoxide emission, and around 1% reduction in carbon dioxide emission characteristics. So it is observed that the blend ratio of 40% bio-diesel with MFA fuel additive creates reduced emission and minimal power drop due to effective combustion even when the calorific value is comparatively lower due to its higher cetane number.

  12. Combined iron and sulfate reduction biostimulation as a novel approach to enhance BTEX and PAH source-zone biodegradation in biodiesel blend-contaminated groundwater.

    Science.gov (United States)

    Müller, Juliana B; Ramos, Débora T; Larose, Catherine; Fernandes, Marilda; Lazzarin, Helen S C; Vogel, Timothy M; Corseuil, Henry X

    2017-03-15

    The use of biodiesel as a transportation fuel and its growing mandatory blending percentage in diesel increase the likelihood of contaminating groundwater with diesel/biodiesel blends. A 100L-field experiment with B20 (20% biodiesel and 80% diesel, v/v) was conducted to assess the potential for the combined biostimulation of iron and sulfate reducing bacteria to enhance BTEX and PAH biodegradation in a diesel/biodiesel blend-contaminated groundwater. A B20 field experiment under monitored natural attenuation (MNA) was used as a baseline control. Ammonium acetate and a low-cost and sustainable product recovered from acid mine drainage treatment were used to stimulate iron and sulfate-reducing conditions. As a result, benzene and naphthalene concentrations (maximum concentrations were 28.1μgL(-1) and 10.0μgL(-1), respectively) remained lower than the MNA experiment (maximum concentrations were 974.7μgL(-1) and 121.3μgL(-1), respectively) over the whole experiment. Geochemical changes were chronologically consistent with the temporal change of the predominance of Geobacter and GOUTA19 which might be the key players responsible for the rapid attenuation of benzene and naphthalene. To the best of our knowledge, this is the first field experiment to demonstrate the potential for the combined iron and sulfate biostimulation to enhance B20 source-zone biodegradation.

  13. Spectroscopic Analysis of Heterogeneous Biocatalysts for Biodiesel Production from Expired Sunflower Cooking Oil

    Directory of Open Access Journals (Sweden)

    Enoch Wembabazi

    2015-01-01

    Full Text Available The study characterized heterogeneous biocatalyst synthesized from sucrose, saw dust, and chicken egg shells using Fourier Transform Infrared (FTIR spectroscopy coupled with Attenuated Total Reflectance (ATR technique. Acidic sulphonate (–SO3H groups were more visible in the spectrum generated for carbonized and sulphonated sucrose than in carbonized and sulphonated saw dust. This was highlighted further by the significantly higher conversion percentage achieved for sulphonated sucrose (62.5% than sulphonated saw dust (46.6% during esterification of expired sunflower oil (p=0.05. The spectra for calcinated egg shells also showed that the most active form of calcium oxide was produced at calcination temperature of 1000°C. This was confirmed in the single-step transesterification reaction in which calcium oxide generated at 1000°C yielded the highest biodiesel (87.8% from expired sunflower oil. The study further demonstrated the versatility of the FTIR technique in qualitative analysis of biodiesel and regular diesel by confirming the presence of specific characteristic peaks of diagnostic importance. These findings therefore highlight the potential of FTIR-ATR as an inexpensive, fast, and accurate diagnostic means for easy identification and characterization of different materials and products.

  14. Extraction of fleshing oil from waste limed fleshings and biodiesel production.

    Science.gov (United States)

    Sandhya, K V; Abinandan, S; Vedaraman, N; Velappan, K C

    2016-02-01

    The aim of the study was focused on extraction of fleshing oil from limed fleshings with different neutralization process by ammonium chloride (NH4Cl) and hydrochloric acid (HCl) followed by solvent extraction. The production of fatty acid methyl esters (FAMEs) from limed fleshing oil by two stage process has also been investigated. The central composite design (CCD) was used to study the effect of process variables viz., amount of flesh, particle size and time of fleshing oil extraction. The maximum yield of fleshing oil from limed fleshings post neutralization by ammonium chloride (NH4Cl) and hydrochloric acid (HCl) was 26.32g and 12.43g obtained at 200g of flesh, with a particle size of 3.90mm in the time period of 2h. Gas chromatography analysis reveals that the biodiesel (FAME) obtained from limed fleshings is rich in oleic and palmitic acids with weight percentages 46.6 and 32.2 respectively. The resulting biodiesel was characterized for its physio-chemical properties of diesel as per international standards (EN14214).

  15. Studying and optimizing the biodiesel production from mastic oil aided by ultrasonic using response surface method

    Directory of Open Access Journals (Sweden)

    B Hosseinzdeh Samani

    2016-09-01

    interface. Increasing the ratio of ultrasonic working time to its idling time caused to an increase in the conversion percent. Because the treating time of the samples by ultrasound in limit time durations is increased, while this increase becomes lower at higher ratios. This is due to the fact that the initial vibrative shock acted on the samples after ultrasonic restarting, finds an identical effect with uniform wave. However, the idling phase of ultrasound caused a decrease in the amount of consumed energy. Similar results have been reported by Chand et al. (2010 for the effect of pulse on conversion percent of methyl ester. Trend of reaction time and molar ratio were different with trend of amplitude and molar ratio on methyl ester content so that they were divided to two sections. It should be mentioned that the increase in biodiesel yield because of molar ratio has some limitations. If the ratio is increased more than a certain extent, biodiesel conversion percent will decrease. The main reason for this result can be related to the amount of methanol increase in the mixture, which leads to more dissolution of glycerin and alcohol in biodiesel which considerably influences its purity. Optimization was carried out based on Response Surface Methodology (RSM using Design Experts software. The obtained results from optimization were as follow: 5.45 molar ratio, 0.89 amplitude, 0.71 pulse and 5.99 minutes of time. The conversion percentage obtained as 94.96. It is worthy to note that the experiment was iterated at suggested point by the optimization software and the conversion percent was 94.02. As well as 34792.37 J at the obtained point to be acceptable (1% difference from the model. Conclusions The increase in the ultrasound amplitude resulted in an increase in the conversion percentage which tends to ascend. Also, the increase of reaction time by 5 to 7 minutes increased the conversion percentage, following which is the descend trend. The obtained results from

  16. 7 CFR 201.61 - Fluorescence percentages in ryegrasses.

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 3 2010-01-01 2010-01-01 false Fluorescence percentages in ryegrasses. 201.61 Section... ACT FEDERAL SEED ACT REGULATIONS Tolerances § 201.61 Fluorescence percentages in ryegrasses. Tolerances for 400-seed fluorescence tests shall be those set forth in the following table plus one-half...

  17. 78 FR 33757 - Rural Determination and Financing Percentage

    Science.gov (United States)

    2013-06-05

    ... finance where the project supplies electricity to an electric utility serving an area that is less than... funds to finance the construction and improvement of electric projects in rural areas, including... Percentage. It has been the Agency's practice to finance only that percentage of a project cost that equates...

  18. 15 CFR 23.4 - Cost and percentage estimates.

    Science.gov (United States)

    2010-01-01

    ... 15 Commerce and Foreign Trade 1 2010-01-01 2010-01-01 false Cost and percentage estimates. 23.4... LOCATION AND RECOVERY OF MISSING CHILDREN § 23.4 Cost and percentage estimates. It is estimated that this... estimate that 9% of its penalty mail will transmit missing children photographs and information when...

  19. 28 CFR 19.4 - Cost and percentage estimates.

    Science.gov (United States)

    2010-07-01

    ... 28 Judicial Administration 1 2010-07-01 2010-07-01 false Cost and percentage estimates. 19.4... RECOVERY OF MISSING CHILDREN § 19.4 Cost and percentage estimates. It is estimated that this program will cost DOJ $78,000 during the initial year. This figure is based on estimates of printing, inserting,...

  20. 7 CFR 930.8 - Free market tonnage percentage cherries.

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 8 2010-01-01 2010-01-01 false Free market tonnage percentage cherries. 930.8 Section... CHERRIES GROWN IN THE STATES OF MICHIGAN, NEW YORK, PENNSYLVANIA, OREGON, UTAH, WASHINGTON, AND WISCONSIN Order Regulating Handling Definitions § 930.8 Free market tonnage percentage cherries. Free...

  1. Room temperature synthesis of biodiesel using sulfonated graphitic carbon nitride

    Science.gov (United States)

    Sulfonation of graphitic carbon nitride (g-CN) affords a polar and strongly acidic catalyst, Sg-CN, which displays unprecedented reactivity and selectivity in biodiesel synthesis and esterification reactions at room temperature.

  2. Effect of temperature on tribological properties of palm biodiesel

    Energy Technology Data Exchange (ETDEWEB)

    Haseeb, A.S.M.A.; Sia, S.Y.; Fazal, M.A.; Masjuki, H.H. [Department of Mechanical Engineering, University of Malaya, 50603 Kuala Lumpur (Malaysia)

    2010-03-15

    Biodiesel, as an alternative fuel is steadily gaining attention to replace petroleum diesel partially or completely. The tribological performance of biodiesel is crucial for its application in automobiles. In the present study, effect of temperature on the tribological performance of palm biodiesel was investigated by using four ball wear machine. Tests were conducted at temperatures 30, 45, 60 and 75 C, under a normal load of 40 kg for 1 h at speed 1200 rpm. For each temperature, the tribological properties of petroleum diesel (B0) and three biodiesel blends like B10, B20, B50 were investigated and compared. During the wear test, frictional torque was recorded on line. Wear scars in tested ball were investigated by optical microscopy. Results show that friction and wear increase with increasing temperature. (author)

  3. Biodiesel production from low cost and renewable feedstock

    Science.gov (United States)

    Gude, Veera; Grant, Georgene; Patil, Prafulla; Deng, Shuguang

    2013-12-01

    Sustainable biodiesel production should: a) utilize low cost renewable feedstock; b) utilize energy-efficient, nonconventional heating and mixing techniques; c) increase net energy benefit of the process; and d) utilize renewable feedstock/energy sources where possible. In this paper, we discuss the merits of biodiesel production following these criteria supported by the experimental results obtained from the process optimization studies. Waste cooking oil, non-edible (low-cost) oils (Jatropha curcas and Camelina Sativa) and algae were used as feedstock for biodiesel process optimization. A comparison between conventional and non-conventional methods such as microwaves and ultrasound was reported. Finally, net energy scenarios for different biodiesel feedstock options and algae are presented.

  4. Life cycle assessment of biodiesel production in China.

    Science.gov (United States)

    Liang, Sai; Xu, Ming; Zhang, Tianzhu

    2013-02-01

    This study aims to evaluate energy, economic, and environmental performances of seven categories of biodiesel feedstocks by using the mixed-unit input-output life cycle assessment method. Various feedstocks have different environmental performances, indicating potential environmental problem-shift. Jatropha seed, castor seed, waste cooking oil, and waste extraction oil are preferred feedstocks for biodiesel production in the short term. Positive net energy yields and positive net economic benefits of biodiesel from these four feedstocks are 2.3-52.0% of their life cycle energy demands and 74.1-448.4% of their economic costs, respectively. Algae are preferred in the long term mainly due to their less arable land demands. Special attention should be paid to potential environmental problems accompanying feedstock choice: freshwater use, ecotoxicity potentials, photochemical oxidation potential, acidification potential and eutrophication potential. Moreover, key processes are identified by sensitivity analysis to direct future technology improvements. Finally, supporting measures are proposed to optimize China's biodiesel development.

  5. Analysis of national Jatropha biodiesel programme in Senegal

    DEFF Research Database (Denmark)

    Dafrallah, Touria; Ackom, Emmanuel

    2016-01-01

    and other biodiesel crop options, based on findings from an agro-environmental mapping exercise have been shown. Findings show that prior policies in agricultural and energy sectors had been instrumental in developing the NJP. It highlights significant challenges in the value chain, the implementation...... of NJP and on the importance of using empirical assessment of evidence to inform on the biodiesel crop type compared to a focus on only one crop, Jatropha. Agro-environmental mapping was identified as useful technique prior to biodiesel cultivation. The work reported here indicates Jatropha having...... on the suitability of areas for Jatropha cultivation and on environmentally, socially and culturally sensitive areas. Policy options have been suggested for environmentally benigned sustained biodiesel activities in Senegal....

  6. Sustainable and Intensified Design of a Biodiesel Production Process

    DEFF Research Database (Denmark)

    Mansouri, Seyed Soheil; Ismail, Muhammad I.; Babi, Deenesh Kavi

    impact and maximum profitability is needed. In this work a computer-aided framework for process synthesis and process intensification is applied for sustainable production of biodiesel from pure/waste palm oil as the feedstock. This approach examines several biodiesel processing routes that were...... collected through available data and current technologies reported in the literature. Using this information, a generic superstructure of processing routes was created that described a network of configurations representing multiple designs for the production of biodiesel. Therefore, based on the currently...... of economic and environmental sustainability was identified. For the case of biodiesel production, the intensified process alternative turned out to be the most economical and more sustainable than other alternatives. The computer-aided methods and tools used in this work are: SustainPro (method and tool...

  7. Polymeric efficiency in remove impurities during cottonseed biodiesel production

    Science.gov (United States)

    Lin, H. L.; Liang, Y. H.; Yan, J.; Lin, H. D.; Espinosa, A. R.

    2016-07-01

    This paper describes a new process for developing biodiesel by polymer from crude cottonseed oil. The study was conducted to examine the effectiveness of the alkali transesterification-flocculation-sedimentation process on fast glycerol and other impurities in the separation from biodiesel by using quaternary polyamine-based cationic polymers SL2700 and polyacylamide cationic polymer SAL1100. The settling velocity of glycerol and other impurities in biodiesel was investigated through settling test experiments; the quality of the biodiesel was investigated by evaluating the viscosity and density. The results revealed that SL2700, SAL1100 and their combination dramatically improved the settling velocity of glycerol and other impurities materials than traditional method. SL 2700 with molecular weight of 0.2 million Da and charge density of 50% then plus SAL1100 with molecular weight of 11 million Da and charge density of 10% induced observable particle aggregation with the best settling performance.

  8. Prospective of biodiesel production utilizing microalgae as the cell ...

    African Journals Online (AJOL)

    STORAGESEVER

    2010-03-08

    Mar 8, 2010 ... light intensity, CO2 concentration, nutritional balance, etc, in closed reactors remain controlled. On the .... High photosynthesis yields, that is, about 3 – 8% of ... transesterification reaction to obtain biodiesel (Figure 3).

  9. Investigating the Production of Biodiesel from Alphonso Mango ...

    African Journals Online (AJOL)

    Investigating the Production of Biodiesel from Alphonso Mango Seed Oil. ... cetane number, kinematic viscosity, Iodine value, density and saponification value ... oil methyl ester could be used as an alternative to/or blended with petrodiesel.

  10. Production of biodiesel using lipase encapsulated in κ-carrageenan

    CERN Document Server

    Ravindra, Pogaku

    2015-01-01

    This book explores a novel technique for processing biodiesel using lipase immobilization by encapsulation and its physical properties, stability characteristics, and application in stirred tank and re-circulated packed bed immobilized reactors for biodiesel production. The enzymatic processing of biodiesel addresses many of the problems associated with chemical processing. It requires only moderate operating conditions and yields a high-quality product with a high level of conversion and the life cycle assessment of enzymatic biodiesel production has more favourable environmental consequences. The chemical processing problems of waste water treatment are lessened and soap formation is not an issue, meaning that waste oil with higher FFA can be used as the feedstock. The by product glycerol does not require any purification and it can be sold at higher price. However, soluble enzymatic processing is not perfect. It is costly, the enzyme cannot be recycled and its removal from the product is difficult. For...

  11. Biodiesel production from Jatropha curcas oil catalyzed by whole ...

    African Journals Online (AJOL)

    my mord

    2013-07-03

    Jul 3, 2013 ... reaction conditions for biodiesel production via transesterification between Jatropha curcas (physic nut) oil and ... to be a potential feedstock for enzyme produced bio- .... The growth rate of A. pullulans var. melanogenum SRY.

  12. Microbiologically Influenced Corrosion of Carbon Steel Exposed to Biodiesel

    Directory of Open Access Journals (Sweden)

    S. Malarvizhi

    2016-01-01

    Full Text Available Environmental concerns over worsening air pollution problems caused by emissions from vehicles and depletion of fossil fuels have forced us to seek fuels such as biodiesel which can supplement petrofuels. Biodiesels have the ability to retain water and provide a conducive environment for microbiologically influenced corrosion (MIC which may cause difficulties during transportation, storage, and their use. This paper analyses the influence of bacteria on the corrosivity of biodiesel obtained from Jatropha curcas on carbon steel using mass loss method. Carbon steel showed the highest corrosion rates in B100 (100% biodiesel both in the presence and in absence of bacteria. The surface analysis of the metal was carried out using SEM.

  13. Room temperature synthesis of biodiesel using sulfonated graphitic carbon nitride

    Science.gov (United States)

    Baig, R. B. Nasir; Verma, Sanny; Nadagouda, Mallikarjuna N.; Varma, Rajender S.

    2016-12-01

    Sulfonation of graphitic carbon nitride (g-CN) affords a polar and strongly acidic catalyst, Sg-CN, which displays unprecedented reactivity and selectivity in biodiesel synthesis and esterification reactions at room temperature.

  14. Biodiesel production from castor oil in Brazil: A difficult reality

    Energy Technology Data Exchange (ETDEWEB)

    Silva Cesar, Aldara da, E-mail: aldara@dep.ufscar.b [Federal University of Sao Carlos, Gepai - Grupo de Estudos e Pesquisas Agroindustriais, Departamento de Engenharia de Producao - UFSCar, Rodovia Washington Luis, km 235 - CEP 13565-905 - Sao Carlos - SP (Brazil); Otavio Batalha, Mario [Federal University of Sao Carlos, Gepai - Grupo de Estudos e Pesquisas Agroindustriais, Departamento de Engenharia de Producao - UFSCar, Rodovia Washington Luis, km 235 - CEP 13565-905 - Sao Carlos - SP (Brazil)

    2010-08-15

    The Brazilian National Program for Production and Use of Biodiesel (PNPB in Portuguese) has created a huge demand for biodiesel in Brazil. The PNPB is strongly based on social development through the inclusion of family farmers in projects integrated with biodiesel power plants. Among the various oilseeds, castor bean (Ricinus communis L.) was identified as the ideal one to promote social development in the semi-arid region. However, although promising, the mechanisms of the federal program are still insufficient to promote the effective participation of family farmers. This research shows that companies are facing huge problems in implementing contracts with family farmers. It describes and analyzes the functioning dynamics of this agro-production chain. This paper addresses the identification and the discussion of these obstacles, in order to increase the competitiveness of the biodiesel agribusiness chain, based on castor oil social projects in Brazil.

  15. Biodiesel production from castor oil in Brazil. A difficult reality

    Energy Technology Data Exchange (ETDEWEB)

    Silva Cesar, Aldara da; Otavio Batalha, Mario [Federal University of Sao Carlos, Gepai - Grupo de Estudos e Pesquisas Agroindustriais, Departamento de Engenharia de Producao - UFSCar, Rodovia Washington Luis, km 235 - CEP 13565-905 - Sao Carlos (Brazil)

    2010-08-15

    The Brazilian National Program for Production and Use of Biodiesel (PNPB in Portuguese) has created a huge demand for biodiesel in Brazil. The PNPB is strongly based on social development through the inclusion of family farmers in projects integrated with biodiesel power plants. Among the various oilseeds, castor bean (Ricinus communis L.) was identified as the ideal one to promote social development in the semi-arid region. However, although promising, the mechanisms of the federal program are still insufficient to promote the effective participation of family farmers. This research shows that companies are facing huge problems in implementing contracts with family farmers. It describes and analyzes the functioning dynamics of this agro-production chain. This paper addresses the identification and the discussion of these obstacles, in order to increase the competitiveness of the biodiesel agribusiness chain, based on castor oil social projects in Brazil. (author)

  16. Biodiesel From Alternative Oilseed Feedstocks: Production and Properties

    Science.gov (United States)

    Fatty acid methyl esters were prepared and evaluated as potential biodiesel fuels from several alternative oilseed feedstocks, which included camelina (Camelina sativa L.), coriander (Coriandrum sativum L.), field mustard (Brassica juncea L.), field pennycress (Thlaspi arvense L.), and meadowfoam (L...

  17. Using wet microalgae for direct biodiesel production via microwave irradiation.

    Science.gov (United States)

    Cheng, Jun; Yu, Tao; Li, Tao; Zhou, Junhu; Cen, Kefa

    2013-03-01

    To address the large energy consumption of microalgae dewatering and to simplify the conventional two-step method (cellular lipid extraction and lipid transesterification) for biodiesel production, a novel process for the direct conversion of wet microalgae biomass into biodiesel by microwave irradiation is proposed. The influences of conventional thermal heating and microwave irradiation on biodiesel production from wet microalgae biomass were investigated. The effects of using the one-step (simultaneous lipid extraction and transesterification) and two-step methods were also studied. Approximately 77.5% of the wet microalgal cell walls were disrupted under microwave irradiation. The biodiesel production rate and yield from wet microalgae biomass obtained through the one-step process using microwave irradiation were 6-fold and 1.3-fold higher than those from wet microalgae obtained through the two-step process using conventional heating.

  18. Biodiesel Production from Rubber Seed Oil via Esterification Process

    Directory of Open Access Journals (Sweden)

    W Widayat

    2012-07-01

    Full Text Available One promise source of alternative energy is biodiesel from rubber seed oil, because the raw materials available in plentiful quantities and can be renewed. In addition, the rubber seed is still lack of utilization, and Indonesia is one of the largest rubbers producing country in the world. The objective of this research is to studied on biodiesel production by esterification process. Parameters used in this study are the ratio of catalyst and temperature and its influence on the characteristics of the resulting biodiesel product. Characterization of rubber seed include acid content number analysis, saponification numbers, density, viscosity, iodine number, type of free fatty acids and triglyceride oils. The results of analysis showed that rubber seed oil content obtained is 50.5%. The results of the GCMS analysis showed that a free fatty acid level in rubber seed is very high. Conversion into bio-diesel oil is obtained by at most 59.91% and lowest 48.24%.

  19. Microreactors - a marvel of modern manufacturing technology: biodiesel case study

    CSIR Research Space (South Africa)

    Buddoo, SR

    2008-11-01

    Full Text Available Microreactors are miniature reactors for carrying out chemical reactions. CSIR Biosciences has been investigating the production of biodiesel using various sources of vegetable oils, for example, soya, sunflower, canada, Jatropha, palm and peanuts...

  20. Ultrasonication: An effective pre-treatment method for extracting lipid from Salvinia molesta for biodiesel production

    Directory of Open Access Journals (Sweden)

    M. Mubarak

    2016-09-01

    Full Text Available Biodiesel is considered as one of the promising alternative fuels for diesel engines due its renewability and environment friendly nature. As the process of lipid extraction from the biomass consumes about 90% of the total energy spent for biodiesel production, an efficient and economic method is very important. The amount of lipid extracted from the biomass could be increased if it is pre-treated before the extraction process. This work was an attempt to compare the various pre-treatment methods before extracting lipids from dried Salvinia molesta (aquatic weed, such as autoclaving, microwaving, ultrasonication, sand, and glass grinding. After each pre-treatment method, Bligh and Dyer's method was used to measure the total lipid content in percentage dry weight (% dwt, which was then compared with the untreated S. molesta. It was found experimentally that the lipid yield was 19.97% dwt for ultrasonication > 16.60% dwt for microwaving > 16.46% dwt for glass grinding >16.26% dwt for sand grindin, > 15.72% dwt for autoclaving > 15.36% dwt for untreated. The one-way ANOVA with Tukey's test was then used to validate the experimental results and showed that ultrasonication method of pre-treatment was the most efficient and had resulted in the highest lipid yield among all the methods used which was followed by the microwaving method. The Taguchi method with L9 orthogonal array was then used for the optimization of ultrasonic assisted pre-treatment method before extracting lipid from S. molesta and showed a maximum lipid of 20.86% using 100% amplitude and sonication time of 15 min. The fatty acid methyl ester (FAME of S. molesta lipid was analyzed using gas chromatography mass spectroscopy (GCMS with flame ionization detector. It showed fatty acids such as C14:0, C14:1, C16:0, C16:1, C18:0, C18:1, C20:1, C20:4, C22:0 which contributed 97.38% weight of the total fatty acids. FAME consisted of 63.59% monounsaturated, 33.18% saturated and 0

  1. An evaluation of marine based biodiesel using GHGenius

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2004-11-25

    A project was conducted to add the commercial harvesting of fish and its reduction to proteins and oils to GHGenius, a model developed to analyze the emissions of contaminants associated with the production and use of traditional and alternative transportation fuels. The project also added the generic production of biodiesel from marine oils to GHGenius to compare results to a specific Canadian operation, Ocean Nutrition, which produces marine oil biodiesel. A biodiesel pathway was added to the model, utilizing marine oils as feedstock. The GHGenius was modified and expanded to allow the use of ethanol rather than methanol in the biodiesel production system. Another objective of the project was to address allocation issues raised by the co-production of biodiesel and the high value Omega-3 oils produced in the Ocean Nutrition process. A new pathway was fully integrated and used to analyze a number of cases including: a generic marine biodiesel case; the ocean nutrition case with system boundary conditions; and a more narrow interpretation of the Ocean Nutrition situation, treating oil from Omega 3 production as a by-product. Results indicated that emission benefits from the specific Ocean Nutrition case were about 65 per cent of the benefits of soy biodiesel because of the reduced co-product credit and the use of ethanol rather than methanol. The narrower view of the system boundary for the Ocean Nutrition process resulted in GHG emission reductions similar to soy biodiesel. Challenges to the development of marine biodiesel include the wide variations in harvesting practices and efficiencies of fisheries; different oil yields; and difficulties in arriving at a case that models the global fishery. It was concluded that governments should be careful about encouraging the development of marine based biodiesel. There was little net gain in the availability of diesel fuel as a result of the production and use of marine based biodiesel. Other considerations were that

  2. Physico-chemical characterization of biodiesel from pests attacked corn oil; Caracterizacao fisico-quimica do biodiesel de oleo de milho danificado por pragas

    Energy Technology Data Exchange (ETDEWEB)

    Carvalho, Fabia M.; Correa, Paulo C.; Martins, Marcio A.; Santos, Silmara B.; Damian, Amanda D. [Universidade Federal de Vicosa (UFV), MG (Brazil)], Emails: copace@ufv.br, aredes@ufv.br, syllmara@vicosa.ufv.br

    2009-07-01

    The biodiesel is a renewable energy source alternative to fossil fuels. The biodiesel synthesis can be made by many types of triglycerides transesterification, it is possible to use this biofuel in vehicles if it has the quality required from Agencia Nacional de Petroleo, Gas Natural e Biocombustiveis (ANP). Searching an application for pests attacked corn, there is feasibility technical for the biodiesel production from this corn oil. The biodiesel synthesis was made through ethyl transesterification process with alkaline catalyst using ethanol. The biodiesel physical-chemical characterization was performed using ANP methods. (author)

  3. Process intensification technologies for biodiesel production reactive separation processes

    CERN Document Server

    Kiss, A A

    2014-01-01

    This book is among the first to address the novel process intensification technologies for biodiesel production, in particular the integrated reactive separations. It provides a comprehensive overview illustrated with many industrially relevant examples of novel reactive separation processes used in the production of biodiesel (e.g. fatty acid alkyl esters): reactive distillation, reactive absorption, reactive extraction, membrane reactors, and centrifugal contact separators. Readers will also learn about the working principles, design and control of integrated processes, while also getting a

  4. Biodiesel de microalgas: avanços e desafios

    Directory of Open Access Journals (Sweden)

    André Luiz Custódio Franco

    2013-01-01

    Full Text Available Microalgae biomass has been described by several authors as the raw material with the greatest potential to meet the goals of replacing petroleum diesel by biodiesel while not competing with arable land suitable for food production. Research groups in different countries are seeking the most appropriate production model for productivity, economic viability and environmental sustainability. This review focused on recent advances and challenges of technology for the production of biodiesel from microalgae, including the procedures used to obtain biomass.

  5. Global sale of green air travel supported using biodiesel

    Energy Technology Data Exchange (ETDEWEB)

    Wardle, D.A. [Auckland (New Zealand)

    2003-02-01

    The technical feasibility of operating commercial aircraft on low concentration biodiesel in kerosene blends is reviewed. Although the analysis is preliminary, it seems plausible that a biodiesel component could be introduced without significant modification to aircraft, airport infrastructure, and flight operations. The use of a biodiesel component, even for only a subset of flight operations, would open the possibility of giving all passengers, the world over, regardless of route, the option to pay a premium to make their journey on 'green' fuel (actually biodiesel). In this way, the airline industry could recover the additional cost of biodiesel in comparison to kerosene. The costs associated with such a scheme are estimated, as is consumer demand. Although the analysis is preliminary, the scheme appears commercially viable. From a humanitarian and/or environmental perspective, marketing flight on biodiesel as 'green air travel' is problematic. On the one hand, the use of biodiesel in aviation would reduce addition of carbon dioxide to the atmosphere and foster development of sustainable technology. On the other hand, it would require that agricultural resources be dedicated to air travel, nominally a luxury, in a world where agricultural resources appear destined to come under increasing strain merely to satisfy humanity's basic food and energy needs. A preliminary discussion of these issues is presented. It is hoped that this can serve as the starting point for further discussion, at an international level, to reach consensus on whether marketing of flight on biodiesel as 'green air travel' should be allowed to proceed, or whether it should be declared unethical. (author)

  6. Thermal properties measurements in biodiesel oils using photothermal techniques

    Science.gov (United States)

    Castro, M. P. P.; Andrade, A. A.; Franco, R. W. A.; Miranda, P. C. M. L.; Sthel, M.; Vargas, H.; Constantino, R.; Baesso, M. L.

    2005-08-01

    In this Letter, thermal lens and open cell photoacoustic techniques are used to measure the thermal properties of biodiesel oils. The absolute values of the thermal effusivity, thermal diffusivity, thermal conductivity and the temperature coefficient of the refractive index were determined for samples obtained from soy, castor bean, sunflower and turnip. The results suggest that the employed techniques may be useful as complementary methods for biodiesel certification.

  7. Biodiesel production by chemical or enzymatic esterification of sunflower oil

    Energy Technology Data Exchange (ETDEWEB)

    Passarinho, Paula C.; Rosa, M. Fernanda; Oliveira, A.C.; Pingarilho, M.S.; Beirao, S.G.; Vieira, Ana Maria Soares

    1998-07-01

    In this work, two processes of sunflower oil transesterification, with methanol or ethanol, were studied for biodiesel production: chemical (catalyst- NaOH) and enzymatic (catalyst - rhizomucor miehei lipase). The chemical catalysis proved to be more efficient, having been obtained higher conversion yields and a better quality biodiesel, mainly in the case where methanol was used. The transesterification product had, in all cases, to be purified in order to be used as a diesel substitute.

  8. Calcium oxide based catalysts for biodiesel production: A review

    OpenAIRE

    Kesić Željka; Lukić Ivana; Zdujić Miodrag; Mojović Ljiljana; Skala Dejan

    2016-01-01

    Vegetable oils are mainly esters of fatty acids and glycerol, which can be converted to fatty acid methyl esters (FAME), also known as biodiesel, by the transesterification reaction with methanol. In order to attain environmental benignity, a large attention has been focused in the last decades on utilizing heterogeneous catalysts for biodiesel production instead the homogenously catalyzed transesterification of vegetable oil. The pure CaO or CaO mixed with...

  9. Biodiesel Fuel Production from Algae as Renewable Energy

    OpenAIRE

    Sharif Hossain, A.B.M.; Aishah Salleh; Amru Nasrulhaq Boyce; Partha chowdhury; Mohd Naqiuddin

    2008-01-01

    Biodiesel is biodegradable, less CO2 and NOx emissions. Continuous use of petroleum sourced fuels is now widely recognized as unsustainable because of depleting supplies and the contribution of these fuels to the accumulation of carbon dioxide in the environment. Renewable, carbon neutral, transport fuels are necessary for environmental and economic sustainability. Algae have emerged as one of the most promising sources for biodiesel production. It can be inferred that algae grown in CO...

  10. Current Status and Prospects of Biodiesel Production from Microalgae

    Directory of Open Access Journals (Sweden)

    Yuhuan Liu

    2012-07-01

    Full Text Available Microalgae represent a sustainable energy source because of their high biomass productivity and ability to remove air and water born pollutants. This paper reviews the current status of production and conversion of microalgae, including the advantages of microalgae biodiesel, high density cultivation of microalgae, high-lipid content microalgae selection and metabolic control, and innovative harvesting and processing technologies. The key barriers to commercial production of microalgae biodiesel and future perspective of the technologies are also discussed.

  11. Brown Grease to Biodiesel Demonstration Project Report

    Energy Technology Data Exchange (ETDEWEB)

    San Francisco Public Utilities Commission; URS Corporation; Biofuels, Blackgold; Carollo Engineers

    2013-01-30

    Municipal wastewater treatment facilities have typically been limited to the role of accepting wastewater, treating it to required levels, and disposing of its treatment residuals. However, a new view is emerging which includes wastewater treatment facilities as regional resource recovery centers. This view is a direct result of increasingly stringent regulations, concerns over energy use, carbon footprint, and worldwide depletion of fossil fuel resources. Resources in wastewater include chemical and thermal energy, as well as nutrients, and water. A waste stream such as residual grease, which concentrates in the drainage from restaurants (referred to as Trap Waste), is a good example of a resource with an energy content that can be recovered for beneficial reuse. If left in wastewater, grease accumulates inside of the wastewater collection system and can lead to increased corrosion and pipe blockages that can cause wastewater overflows. Also, grease in wastewater that arrives at the treatment facility can impair the operation of preliminary treatment equipment and is only partly removed in the primary treatment process. In addition, residual grease increases the demand in treatment materials such as oxygen in the secondary treatment process. When disposed of in landfills, grease is likely to undergo anaerobic decay prior to landfill capping, resulting in the atmospheric release of methane, a greenhouse gas (GHG). This research project was therefore conceptualized and implemented by the San Francisco Public Utilities Commission (SFPUC) to test the feasibility of energy recovery from Trap Waste in the form of Biodiesel or Methane gas. The research goals are given below: To validate technology performance; To determine the costs and benefits [including economic, socioeconomic, and GHG emissions reduction] associated with co-locating this type of operation at a municipal wastewater treatment plant (WWTP); To develop a business case or model for replication of the

  12. Biodiesel exhaust: the need for a systematic approach to health effects research.

    Science.gov (United States)

    Larcombe, Alexander N; Kicic, Anthony; Mullins, Benjamin J; Knothe, Gerhard

    2015-10-01

    Biodiesel is a generic term for fuel that can be made from virtually any plant or animal oil via transesterification of triglycerides with an alcohol (and usually a catalyst). Biodiesel has received considerable scientific attention in recent years, as it is a renewable resource that is directly able to replace mineral diesel in many engines. Additionally, some countries have mandated a minimum biodiesel content in all diesel fuel sold on environmental grounds. When combusted, biodiesel produces exhaust emissions containing particulate matter, adsorbed chemicals and a range of gases. In many cases, absolute amounts of these pollutants are lower in biodiesel exhaust compared with mineral diesel exhaust, leading to speculation that biodiesel exhaust may be less harmful to health. Additionally, engine performance studies show that the concentrations of these pollutants vary significantly depending on the renewable oil used to make the biodiesel and the ratio of biodiesel to mineral diesel in the fuel mix. Given the strategic and legislative push towards the use of biodiesel in many countries, a concerning possibility is that certain biodiesels may produce exhaust emissions that are more harmful to health than others. This variation suggests that a comprehensive, systematic and comparative approach to assessing the potential for a range of different biodiesel exhausts to affect health is urgently required. Such an assessment could inform biodiesel production priorities, drive research and development into new exhaust treatment technologies, and ultimately minimize the health impacts of biodiesel exhaust exposure.

  13. ANÁLISES DE PARÂMETROS FÍSICO-QUÍMICOS DO ÓLEO EXTRAÍDO DE ESPÉCIES VEGETAIS UTILIZADAS PARA A PRODUÇÃO DO BIODIESEL

    Directory of Open Access Journals (Sweden)

    Carla Juliana R. Ferreira

    2015-06-01

    Full Text Available Biodiesel is considered an excellent alternative to diesel derived from fossil sources, due to its renewable nature, which minimizes environmental impacts. In this research, several parameters were analyzed, such as the oil content of seeds, acidity and saponification indexes for oil extracted from different plant species, and qualitative analysis for the verification of free fatty acids in the biodiesel composition by thin layer chromatography (TLC. Four cultivars were evaluated for each specie: canola, sunflower, corn and soybean. Oil samples were submitted to the transesterification process for the production of biodiesel. The data were submitted to ANOVA and Tukey and F significance tests for evaluation of differences between and within species. A significant difference was observed in the percentage of oil between species, sunflower (40.4% to 46.6%, Análises físico-químicas de óleos vegetais para a produção de biodiesel 131 Colloquium Exactarum, v. 7, n.2, Abr-Jun. 2015, p.130 –141. DOI: 10.5747/ce.2015.v07.n2.e121 canola (38.4% to 41.9%, soy (17.1% at 21 , 8% and corn (4.3% to 6.4%. The acidity and the saponification indexes values showed no differences between and within species, indicating the good quality of the oil. The TLC analysis revealed the presence of oleic, linoleic and palmitic acids in the biodiesel synthesized from each specie.

  14. Design and optimisation of purification procedure for biodiesel washing

    Directory of Open Access Journals (Sweden)

    S.B. Glišić

    2009-09-01

    Full Text Available Almost complete methanolysis of triglycerides is usually not enough to fulfil the strict standards of biodiesel quality. A key step in this process is neutralization of alkali (catalyst followed by the washing procedure necessary for removing different impurities such as traces of catalyst and methanol and removal of soaps and glycerol from esters phase. The washing with hot water is still widely used in many industrial units for the biodiesel production. In this study, different procedures of biodiesel washing using hot water were investigated. The orto-phosphoric acid was suggested as the best compound for alkali catalyst (sodium hydroxide neutralization. The main goal of the performed analysis was to minimize the water usage in the washing-neutralization step during the biodiesel production. Such solution would make the process of biodiesel synthesis more economical taking into account the decrease of energy consumed for evaporation of water during the final product purification, as well as more acceptable procedure related to the impact on environment (minimal waste water release. Results of the performed simulation of the washing process supported by original experimental data suggested that neutralization after the optimized washing process of the methyl ester layer could be the best solution. The proposed washing procedure significantly decreases the amount of waste water giving at the same time the desired purity of final products (biodiesel and glycerol. The simulation of the process was performed using ASPEN plus software supported by ELCANTREL and UNIQUAC procedure of required properties calculation

  15. Sustaining Biodiesel Production via Value-Added Applications of Glycerol

    Directory of Open Access Journals (Sweden)

    Omotola Babajide

    2013-01-01

    Full Text Available The production of biofuels worldwide has been significant lately due to the shift from obtaining energy from nonrenewable energy (fossil fuels to renewable sources (biofuels. This energy shift arose as a result of the disturbing crude petroleum price fluctuations, uncertainties about fossil fuel reserves, and greenhouse gas (GHG concerns. With the production of biofuels increasing considerably and the current global biodiesel production from different feedstock, reaching about 6 billion liters per year, biodiesel production costs have been highly dependent on feedstock prices, ranging from 70 to 25; of total production costs, and in comparison with the conventional diesel fuel, the biodiesel is currently noncompetitive. An efficient production process is, therefore, crucial to lowering biodiesel production costs. The question of sustainability, however, arises, taking into account the African diverse conditions and how vital concerns need to be addressed. The major concern about biodiesel production costs can be reduced by finding value-added applications for its glycerol byproduct. This paper, thus, provides an overview of current research trends that could overcome the major hurdles towards profitable commercialization of biodiesel and also proposes areas of opportunity probable to capitalize the surplus glycerol obtained, for numerous applications.

  16. Oil extraction from plant seeds for biodiesel production

    Directory of Open Access Journals (Sweden)

    Yadessa Gonfa Keneni

    2017-04-01

    Full Text Available Energy is basic for development and its demand increases due to rapid population growth, urbanization and improved living standards. Fossil fuels will continue to dominate other sources of energy although it is non-renewable and harm global climate. Problems associated with fossil fuels have driven the search for alternative energy sources of which biodiesel is one option. Biodiesel is renewable, non-toxic, environmental-friendly and an economically feasible options to tackle the depleting fossil fuels and its negative environmental impact. It can be produced from vegetable oils, animal fats, waste oils and algae. However, nowadays, the major feedstocks of biodiesel are edible oils and this has created food vs fuel debate. Therefore, the future prospect is to use non-edible oils, animal fats, waste oils and algae as feedstock for biodiesel. Selection of non-expensive feedstock and the extraction and preparation of oil for biodiesel production is a crucial step due to its relevance on the overall technology. There are three main conventional oil extraction methods: mechanical, chemical/solvent and enzymatic extraction methods. There are also some newly developed oil extraction methods that can be used separately or in combination with the conventional ones, to overcome some disadvantages of the conventional oil extraction methods. This review paper presents, compare and discusses different potential biofuel feedstocks, various oil extraction methods, advantages and disadvantages of different oil extraction methods, and propose future prospective for the improvement of oil extraction methods and sustainability of biodiesel production and utilization.

  17. Biodiesel/Aquatic Species Project report, FY 1992

    Energy Technology Data Exchange (ETDEWEB)

    Brown, L.; Jarvis, E.; Dunahay, T.; Roessler, P.; Zeiler, K. [National Renewable Energy Lab., Golden, CO (United States); Sprague, S. [USDOE, Washington, DC (United States)

    1993-05-01

    The primary goal of the Biodiesel/Aquatic Species Project is to develop the technology for growing microalgae as a renewable biomass feedstock for the production of a diesel fuel substitute (biodiesel), thereby reducing the need for imported petroleum. Microalgae are of interest as a feedstock because of their high growth rates and tolerance to varying environmental conditions, and because the oils (lipids) they produce can be extracted and converted to substitute petroleum fuels such as biodiesel. Microalgae can be grown in arid and semi-arid regions with poor soil quality, and saline water from aquifers or the ocean can be used for growing microalgae. Biodiesel is an extremely attractive candidate to fulfill the need for a diesel fuel substitute. Biodiesel is a cleaner fuel than petroleum diesel; it is virtually free of sulfur, and emissions of hydrocarbons, carbon monoxide, and particulates during combustion are significantly reduced in comparison to emissions from petroleum diesel. Biodiesel provides essentially the same energy content and power output as petroleum-based diesel fuel.

  18. Evaluation of Biodiesel Production, Engine Performance, and Emissions

    Science.gov (United States)

    Gürü, Metin; Keskïn, Ali

    2016-08-01

    Nowadays, to decrease environmental pollution and dependence on fossil-based fuels, research on alternative renewable energy sources has been increasing. One such renewable energy source is biodiesel, which is used as an alternative fuel for diesel engines. Biodiesel is renewable, nontoxic, biodegradable, and environmentally friendly. Biodiesel is domestically produced from vegetable oil (edible or nonedible), animal fat, and used cooking oils. In the biodiesel production process, oil or fat undergoes transesterification reaction through use of simple alcohols such as methanol, ethanol, propanol, butanol, etc. Use of methanol is most feasible because of its low cost, and physical and chemical advantages. Acid catalysis, alkali catalysis, and enzyme catalysis are usually used to improve the reaction rate and yield. Glycerol is a byproduct of the reaction and can be used as an industrial raw material. In this study, biodiesel production methods (direct use, pyrolysis, microemulsion, transesterification, supercritical processes, ultrasound- assisted, and microwave-assisted) and types of catalyst (homogeneous, heterogeneous, and enzyme) have been evaluated and compared. In addition, the effects of biodiesel and its blends on diesel engine performance and exhaust emissions are described and reviewed.

  19. Sustainable Energy Production from Jatropha Bio-Diesel

    Science.gov (United States)

    Yadav, Amit Kumar; Krishna, Vijai

    2012-10-01

    The demand for petroleum has risen rapidly due to increasing industrialization and modernization of the world. This economic development has led to a huge demand for energy, where the major part of that energy is derived from fossil sources such as petroleum, coal and natural gas. Continued use of petroleum sourced fuels is now widely recognized as unsustainable because of depleting supplies. There is a growing interest in using Jatropha curcas L. oil as the feedstock for biodiesel production because it is non-edible and thus does not compromise the edible oils, which are mainly used for food consumption. Further, J. curcas L. seed has a high content of free fatty acids that is converted in to biodiesel by trans esterification with alcohol in the presence of a catalyst. The biodiesel produced has similar properties to that of petroleum-based diesel. Biodiesel fuel has better properties than petro diesel fuel; it is renewable, biodegradable, non-toxic, and essentially free of sulfur and aromatics. Biodiesel seems to be a realistic fuel for future. Biodiesel has the potential to economically, socially, and environmentally benefit communities as well as countries, and to contribute toward their sustainable development.

  20. Biodiesel Production from Microalgae by Extraction – Transesterification Method

    Directory of Open Access Journals (Sweden)

    Nguyen Thi Phuong Thao

    2013-11-01

    Full Text Available The environmental impact of using petroleum fuels has led to a quest to find a suitable alternative fuel source. In this study, microalgae were explored as a highly potential feedstock to produce biodiesel fuel. Firstly, algal oil is extracted from algal biomass by using organic solvents (n–hexan.  Lipid is contained in microalgae up to 60% of their weight. Then, Biodiesel is created through a chemical reaction known as transesterification between algal oil and alcohol (methanol with strong acid (such as H2SO4 as the catalyst. The extraction – transesterification method resulted in a high biodiesel yield (10 % of algal biomass and high FAMEs content (5.2 % of algal biomass. Biodiesel production from microalgae was studied through experimental investigation of transesterification conditions such as reaction time, methanol to oil ration and catalyst dosage which are deemed to have main impact on reaction conversion efficiency. All the parameters which were characterized for purified biodiesel such as free glycerin, total glycerin, flash point, sulfur content were analyzed according to ASTM standardDoi: http://dx.doi.org/10.12777/wastech.1.1.6-9Citation:  Thao, N.T.P., Tin, N.T., and Thanh, B.X. 2013. Biodiesel Production from Microalgae by Extraction – Transesterification Method. Waste Technology 1(1:6-9. Doi: http://dx.doi.org/10.12777/wastech.1.1.6-9

  1. Supercritical biodiesel production and power cogeneration: technical and economic feasibilities.

    Science.gov (United States)

    Deshpande, A; Anitescu, G; Rice, P A; Tavlarides, L L

    2010-03-01

    An integrated supercritical fluid technology with power cogeneration to produce biodiesel fuels, with no need for the costly separations involved with the conventional technology, is proposed, documented for technical and economic feasibility, and preliminarily designed. The core of the integrated system consists of the transesterification of various triglyceride sources (e.g., vegetable oils and animal fats) with supercritical methanol/ethanol. Part of the reaction products can be combusted by a diesel power generator integrated in the system which, in turn, provides the power needed to pressurize the system and the heat of the exhaust gases necessary in the transesterification step. The latter energy demand can also be satisfied by a fired heater, especially for higher plant capacities. Different versions of this system can be implemented based on the main target of the technology: biodiesel production or diesel engine applications, including power generation. The process options considered for biodiesel fuel production estimate break-even processing costs of biodiesel as low as $0.26/gal ($0.07/L) with a diesel power generator and $0.35/gal ($0.09/L) with a fired heater for a plant capacity of 15,000 gal/day (56,775 L/day). Both are significantly lower than the current processing costs of approximately $0.51/gal ($0.13/L) of biodiesel produced by conventional catalytic methods. A retail cost of biodiesel produced by the proposed method is likely to be competitive with the prices of diesel fuels.

  2. Study of the drivers of competitiveness of the Brazilian biodiesel; Estudo dos direcionadores de competitividade do biodiesel brasileiro

    Energy Technology Data Exchange (ETDEWEB)

    Cesar, Aldara da Silva; Batalha, Mario Otavio [Universidade Federal de Sao Carlos (UFSCar), SP (Brazil). Dept. de Engenharia de Producao; Monteiro, Marcos Roberto [Universidade Federal de Sao Carlos (UFSCar), SP (Brazil). Centro de Caracterizacao e Desenvolvimento de Materiais

    2008-07-01

    In the increasingly important role that the biofuel market takes in the new dynamic global competition, biodiesel emerges as a real alternative of implantation. In Brazil, this interest is not different. However, despite of biodiesel's enormous potential, there is a number of uncertainties that need to be investigated in order to produce a biodiesel which has its unique specifications and international quality recognized. The aim of this article is twofold: first, the information systematization of the Brazilian biodiesel production chain; and second, the analysis of drivers of competitiveness that affect that same production chain. Through the theory of systemic approach, each driver of competitiveness is described and its competitive environment is analyzed. The range of different raw materials and possible technological routes present numerous challenges for the agents of this chain. What increases the relevance of studies such as this is the notion that investigating the drives of competitiveness is the first step in overcoming these challenges. (author)

  3. Biocatalytic production of biodiesel from cottonseed oil: Standardization of process parameters and comparison of fuel characteristics

    Energy Technology Data Exchange (ETDEWEB)

    Chattopadhyay, Soham; Karemore, Ankush; Das, Sancharini; Sen, Ramkrishna [Department of Biotechnology, Indian Institute of Technology Kharagpur, West Bengal 721302 (India); Deysarkar, Asoke [PfP Technology LLC., 14227 Fern, Houston, TX 77079 (United States)

    2011-04-15

    The enzymatic production of biodiesel by transesterification of cottonseed oil was studied using low cost crude pancreatic lipase as catalyst in a batch system. The effects of the critical process parameters including water percentage, methanol:oil ratio, enzyme concentration, buffer pH and reaction temperature were determined. Maximum conversion of 75-80% was achieved after 4 h at 37 C, pH 7.0 and with 1:15 M ratio of oil to methanol, 0.5% (wt of oil) enzyme and water concentration of 5% (wt of oil). Various organic solvents were tested among which a partially polar solvent (t-butanol) was found to be suitable for the reaction. The major fuel characteristics like specific gravity, kinematic viscosity, flash point and calorific value of the 20:80 blends (B20) of the fatty acid methyl esters with petroleum diesel conformed very closely to those of American Society for Testing Materials (ASTM) standards. (author)

  4. Biodiesel and vegetable oil cogeneration systems: No boom in sight; Biodiesel- und Pflanzenoel-BHKW: Es plaetschert so dahin

    Energy Technology Data Exchange (ETDEWEB)

    Kiessling, K.P. [SenerTec, Schweinfurt (Germany); Wedekind, E. [Technologie fuer die Umwelt, Sachsen (Germany); Kramer, M. [Menag Energie GmbH, Engen (Germany)

    2003-09-29

    The market situation of biodiesel and vegetable oil fuelled cogeneration systems is outlined. There is a tabular survey and producers' statements which provide interesting information on this ecologically favourable but hardly profitable niche market. (orig.) [German] Nicht leicht zu deuten ist die derzeitige Marktsituation der mit Biodiesel bzw. Pflanzenoel betriebenen Blockheizkraftwerke. Die tabellarische Uebersicht auf Seite 84/85 liefert einen guten Ueberblick, die Stellungnahmen der Hersteller einen interessanten Einblick in diesen oekologischen, aber finanziell kaum rentablen Nischenmarkt. (orig.)

  5. Exergy analysis applied to biodiesel production

    Energy Technology Data Exchange (ETDEWEB)

    Talens, Laura; Villalba, Gara [SosteniPra UAB-IRTA. Environmental Science and Technology Institute (ICTA), Edifici Cn, Universitat Autonoma de Barcelona (UAB), 08193 Bellaterra, Cerdanyola del Valles, Barcelona (Spain); Gabarrell, Xavier [SosteniPra UAB-IRTA. Environmental Science and Technology Institute ICTA, Edifici Cn, Universitat Autonoma de Barcelona (UAB), 08193 Bellaterra (Cerdanyola del Valles), Barcelona (Spain); Department of Chemical Engineering, Universitat Autonoma de Barcelona (UAB), 08193 Bellaterra Cerdanyola del Valles, Barcelona (Spain)

    2007-08-15

    In our aim to decrease the consumption of materials and energy and promote the use of renewable resources, such as biofuels, rises the need to measure materials and energy fluxes. This paper suggests the use of Exergy Flow Analysis (ExFA) as an environmental assessment tool to account wastes and emissions, determine the exergetic efficiency, compare substitutes and other types of energy sources: all useful in defining environmental and economical policies for resource use. In order to illustrate how ExFA is used, it is applied to the process of biodiesel production. The results show that the production process has a low exergy loss (492 MJ). The exergy loss is reduced by using potassium hydroxide and sulphuric acid as process catalysts and it can be further minimised by improving the quality of the used cooking oil. (author)

  6. Formulação de biodiesel

    OpenAIRE

    Pinto, Maria Jorge Pratas de Melo

    2012-01-01

    O consumo de energia a nível mundial aumenta a cada dia, de forma inversa aos recursos fósseis que decrescem de dia para dia. O sector dos transportes é o maior consumidor deste recurso. Face ao actual cenário urge encontrar uma solução renovável e sustentável que permita não só, diminuir a nossa dependência de combustíveis fósseis mas fundamentalmente promover a sua substituição por energias de fontes renováveis. O biodiesel apresenta-se na vanguarda das alternativas aos co...

  7. Sustainable Future for Biodiesel in Brazil

    DEFF Research Database (Denmark)

    Dias, Maria Amélia de Paula

    This thesis aims to study alternatives to biodiesel industry in Brazil, for 2030, taking in account the sustainability dimensions, namely economic, environmental, ecological, social, national and international politics, territorial, cultural, and technological, through the development of scenarios...... of existing oil and waste today. A methodological discussion was also necessary to include sustainable dimensions on the scenario methods. Therefore, the environment, economics, technology, social, territorial, national and international institutional, cultural and political aspects were considered....... In order to carry on this work, it was necessary to develop a cross-disciplinary research, since sustainability requires a long run vision and a comprehensive approach. Brazil is a large country (851 Mha), with soil and weather conditions that are suitable to produce oilseeds, and available land...

  8. Characterization of crude glycerol from biodiesel plants.

    Science.gov (United States)

    Hu, Shengjun; Luo, Xiaolan; Wan, Caixia; Li, Yebo

    2012-06-13

    Characterization of crude glycerol is very important to its value-added conversion. In this study, the physical and chemical properties of five biodiesel-derived crude glycerol samples were determined. Three methods, including iodometric-periodic acid method, high performance liquid chromatography (HPLC), and gas chromatography (GC), were shown to be suitable for the determination of glycerol content in crude glycerol. The compositional analysis of crude glycerol was successfully achieved by crude glycerol fractionation and characterization of the obtained fractions (aqueous and organic) using titrimetric, HPLC, and GC analyses. The aqueous fraction consisted mainly of glycerol, methanol, and water, while the organic fraction contained fatty acid methyl esters (FAMEs), free fatty acids (FFAs), and glycerides. Despite the wide variations in the proportion of their components, all raw crude glycerol samples were shown to contain glycerol, soap, methanol, FAMEs, water, glycerides, FFAs, and ash.

  9. Biochemical responses in armored catfish (Pterygoplichthys anisitsi) after short-term exposure to diesel oil, pure biodiesel and biodiesel blends.

    Science.gov (United States)

    Nogueira, Lílian; da Silva, Danilo Grünig Humberto; Oliveira, Thiago Yukio Kikuchi; da Rosa, Joel Maurício Correa; Felício, Andréia Arantes; de Almeida, Eduardo Alves

    2013-09-01

    Biodiesel fuel is gradually replacing petroleum-based diesel oil use. Despite the biodiesel being considered friendlier to the environment, little is known about its effects in aquatic organisms. In this work we evaluated whether biodiesel exposure can affect oxidative stress parameters and biotransformation enzymes in armored catfish (Pterygoplichthys anisitsi, Loricariidae), a South American endemic species. Thus, fish were exposed for 2 and 7d to 0.01mLL(-1) and 0.1mLL(-1) of pure diesel, pure biodiesel (B100) and blends of diesel with 5% (B5) and 20% (B20) biodiesel. Lipid peroxidation (malondialdehyde) levels and the activities of the enzymes glutathione S-transferase, superoxide dismutase, catalase and glutathione peroxidase were measured in liver and gills. Also, DNA damage (8-oxo-7, 8-dihydro-2'-deoxyguanosine) levels in gills and 7-ethoxyresorufin-O-deethylase activity in liver were assessed. Pure diesel, B5 and B20 blends changed most of the enzymes tested and in some cases, B5 and B20 induced a higher enzyme activity than pure diesel. Antioxidant system activation in P. anisitsi was effective to counteract reactive oxygen species effects, since DNA damage and lipid peroxidation levels were maintained at basal levels after all treatments. However, fish gills exposed to B20 and B100 presented increased lipid peroxidation. Despite biodiesel being more biodegradable fuel that emits less greenhouse gases, the increased lipid peroxidation showed that biofuel and its blends also represent hazards to aquatic biota.

  10. Production of biodiesel from vegetable oils

    Directory of Open Access Journals (Sweden)

    Luque, Susana

    2008-03-01

    Full Text Available Biodiesel is produced by transesterification of triglycerides present in animal fat or vegetable oils, by displacing glycerine with a low molar mass alcohol. This resulting ester mixture has physico-chemical properties similar to those of petroleum diesel. This paper reviews the synthetic paths that lead to biodiesel by means of the catalytic transesterification of vegetable oils. Although methyl esters are at present the only ones produced at industrial scale, the use of ethanol, which can also be obtained from renewable resources, has been considered, since it would generate a cleaner and more biocompatible fuel.El biodiésel se produce mediante la transesterificación de triglicéridos, presentes en grasas animales o aceites vegetales, en un proceso en el que un alcohol de bajo peso molecular desplaza a la glicerina. La mezcla de esteres así resultante posee unas propiedades físico-químicas similares a las del diésel procedente de petróleo. En este artículo se revisan las vías de síntesis de biodiésel mediante la transesterificación catalítica de aceites vegetales. Aunque actualmente a escala industrial solo se producen ésteres metílicos, también se ha considerado el uso de etanol, ya que éste se obtiene también de fuentes renovables, generando así un combustible más limpio y biocompatible.

  11. Sustainable biocatalytic biodiesel production : A thermodynamic analysis

    Energy Technology Data Exchange (ETDEWEB)

    Guezel, G.

    2012-09-15

    In the present thesis it was aimed at achieving thermodynamic analysis of reactions involved in enzymatic biodiesel production with specific focus on chemical and phase equilibria of reactive systems. Lipase-catalyzed biodiesel production (biocatalytic ethanolysis) presents significant advantages: Easy recovery of glycerol, no complex down-processing operations for elimination of catalyst and salt, and requires less organic solvent and lower energy consumption compared with conventional chemical methods. In overall, the major aims of this thesis were evaluating and subsequently finding feasible solutions to the questions emerged during the corresponding studies that have been performed worldwide. Some of the questions that were answered as appropriate as possible can be listed as follows: 1) What is the solubility of EtOH in vegetable oils and in FAEE blends and how does it change with temperature? 2) Is it possible to prevent denaturing impact of EtOH on biocatalysts? 3) What are the feedstock content (water and FFA) impacts on glycerol and EtOH miscibility with ester species? 4) Is it necessary removing glycerol by-product simultaneously? 5) Is it feasible providing monophasic or homogeneous reaction media that procure lower external mass transfer resistance? 6) What are the moisture absorption limits of FAAE species? 7) How are the interactions of reactive species in terms of miscibility/immiscibility phenomena? 8) Is it thermodynamically feasible providing monophasic reaction media? 9) How can LLE and VLE phase behaviors help to determine optimum reaction conditions? 10) How can the results of LLE and VLE studies be used so as to determine appropriate refining operations? (LN)

  12. Court Remands as a Percentage of New Court Cases Filed

    Data.gov (United States)

    Social Security Administration — Longitudinal report detailing the numbers and percentages of court remand actions received during each Fiscal Year 2010 - onward as compared to the total number of...

  13. Social Security Administration Percentage of Fast-Track Receipts

    Data.gov (United States)

    Social Security Administration — The dataset provides the percentage of fast-track receipts by state during the reporting fiscal year. Fast-tracked cases consist of those cases identified as Quick...

  14. Calophyllum inophyllum L. as a future feedstock for bio-diesel production

    Energy Technology Data Exchange (ETDEWEB)

    Atabania, A.E. [Department of Mechanical Engineering, University of Khartoum (Sudan)], email: a_atabani2@msn.com, email: ardinsu@yahoo.co.id; Silitonga, A.S.; Mahlia, T.M.I.; Masjukia, H.H.; Badruddin, I.A. [University of Malaya (Malaysia)

    2011-07-01

    Due to the energy crisis and the concerns about climate change, the possibility of using biodiesel as an alternative energy resource has been examined. It has been found that biodiesel could be a solution for the future but the first generation of biodiesel, prepared from edible vegetable oils, has raised important concerns about food and environmental problems. The aim of this study is to assess if Calophyllum inophyllum, a non-edible oil, could be used for biodiesel production. Density, kinematic viscosity, cetane number, flashpoint and iodine value were determined on Calophyllum inophyllum trees from Cilacap, Indonesia and compared in light of ASTM D6751 biodiesel standards. It was found that Calophyllum inophyllum would be a satisfactory feedstock to produce biodiesel in the future. This study demonstrated that Calophyllum inophyllum has the potential to be a biodiesel feedstock and further research should be carried out on engine performance, combustion and emission performance of biodiesel produced from Calophyllum inophyllum.

  15. Effect of biodiesel addition on microbial community structure in a simulated fuel storage system.

    Science.gov (United States)

    Restrepo-Flórez, Juan-Manuel; Bassi, Amarjeet; Rehmann, Lars; Thompson, Michael R

    2013-11-01

    Understanding changes in microbial structure due to biodiesel storage is important both for protecting integrity of storage systems and fuel quality management. In this work a simulated storage system was used to study the effect of biodiesel (0%, 25%, 50%, 75% and 100%) on a microbial population, which was followed by community level physiological profiling (CLPP), 16s rDNA analysis and plating in selective media. Results proved that structure and functionality were affected by biodiesel. CLPP showed at least three populations: one corresponding to diesel, one to biodiesel and one to blends of diesel and biodiesel. Analysis of 16s rDNA revealed that microbial composition was different for populations growing in diesel and biodiesel. Genera identified are known for degradation of hydrocarbons and emulsifier production. Maximum growth was obtained in biodiesel; however, microbial counts in standard media were lower for this samples. Acidification of culture media was observed at high biodiesel concentration.

  16. Influence of Fatty Acid Methyl Esters on Fuel properties of Biodiesel ...

    African Journals Online (AJOL)

    biodiesel standards are exhaust emissions, lubricity ... oils are usually associated with low free fatty acid .... ensure good cold start properties and minimize the .... Blending effects of biodiesels on oxidation stability and low temperature flow ...

  17. Dynamics of control mechanisms in a cost plus percentage contract

    OpenAIRE

    Huang, Wen-Haw; Yin, Samuel Yen-Lian; Tserng, H. Ping

    2012-01-01

    While the control mechanisms of incentive contracts have been widely studied, this study attempts to determine the optimal control over a cost-plus percentage contract of a construction project. Cost-plus percentage contract shifts some risk from the contractor to client, thus offering little incentive for the contractor to control costs. The owner requires additional management over the construction project to ensure that only necessary costs are spent. The data are collected through documen...

  18. Evaluation of natural smile: Golden proportion, RED or Golden percentage

    OpenAIRE

    Murthy, B. V. Sreenivasan; Ramani, Niketa

    2008-01-01

    Creating geometric or mathematical proportion to relate the successive width of maxillary anterior teeth is a critical aspect in Esthetic dentistry. Golden proportion, recurring esthetic dental (RED) proportion and golden percentage are new theories in this field. Aim: To investigate the existence and suitability of Golden proportion, Recurring Esthetic Dental, and Golden percentage between the widths of maxillary anterior teeth in individuals with natural dentition, with the aid of digital p...

  19. PENINGKATAN KUALITAS DAN PROSES PEMBUATAN BIODIESEL DARI BLENDING MINYAK KELAPA SAWIT (PALM OIL DAN MINYAK KELAPA (COCONUT OIL DAN BANTUAN GELOMBANG ULTRASONIK

    Directory of Open Access Journals (Sweden)

    Hantoro Satriadi

    2015-01-01

    the standard of SNI and ASTM. To improve the quality of biodiesel as well as produce maximum yield, then do the blending of raw materials between Palm oil and coconut oil and with the help of ultrasonic waves. This research aims to study the influence of variable ratio of the volume of palm oil and coconut oil, methanol-oil volume ratio, and the percentage of weight of the catalyst to oil to biodiesel results or yield. The main tool used by the reactors are equipped with ultrasonic wave generator temperature 60 oC, pressure 1 atm, 3 liters of volume, and frequency 28 kHz. Process variables in this study is a comparison of the volume of palm oil and coconut 2:1, 3:1 and 4:1, ratio volume of methanol-oil 0.2:1, 0.25:1, and 0,31:1, and the percentage of weight of KOH catalyst to oil 0.3%, 0.5% and 0.7%. Results of the study had the highest conversion achieved at variable volume ratio of palm oil and coconut 3:1, a comparison of the volume of methanol/oil 0.25:1, and the percentage of the weight of oil with the catalyst to yield 97,26%.Copyright (c by Fakultas Teknik, Undip. All right reserved.

  20. Biodiesel forming reactions using heterogeneous catalysis

    Science.gov (United States)

    Liu, Yijun

    Biodiesel synthesis from biomass provides a means for utilizing effectively renewable resources, a way to convert waste vegetable oils and animal fats to a useful product, a way to recycle carbon dioxide for a combustion fuel, and production of a fuel that is biodegradable, non-toxic, and has a lower emission profile than petroleum-diesel. Free fatty acid (FFA) esterification and triglyceride (TG) transesterification with low molecular weight alcohols constitute the synthetic routes to prepare biodiesel from lipid feedstocks. This project was aimed at developing a better understanding of important fundamental issues involved in heterogeneous catalyzed biodiesel forming reactions using mainly model compounds, representing part of on-going efforts to build up a rational base for assay, design, and performance optimization of solid acids/bases in biodiesel synthesis. As FFA esterification proceeds, water is continuously formed as a byproduct and affects reaction rates in a negative manner. Using sulfuric acid (as a catalyst) and acetic acid (as a model compound for FFA), the impact of increasing concentrations of water on acid catalysis was investigated. The order of the water effect on reaction rate was determined to be -0.83. Sulfuric acid lost up to 90% activity as the amount of water present increased. The nature of the negative effect of water on esterification was found to go beyond the scope of reverse hydrolysis and was associated with the diminished acid strength of sulfuric acid as a result of the preferential solvation by water molecules of its catalytic protons. The results indicate that as esterification progresses and byproduct water is produced, deactivation of a Bronsted acid catalyst like H2SO4 occurs. Using a solid composite acid (SAC-13) as an example of heterogeneous catalysts and sulfuric acid as a homogeneous reference, similar reaction inhibition by water was demonstrated for homogeneous and heterogeneous catalysis. This similarity together with

  1. Performance characteristics of mix oil biodiesel blends with smoke emissions

    Directory of Open Access Journals (Sweden)

    Sanjay Mohite

    2016-08-01

    Full Text Available Fossil fuel resources are being depleted day by day and its use affects the environment adversely. Renewable energy is one of the alternate for sustainable development and biodiesel is one of the suitable alternate which can replace the diesel. The major hurdles in the successful commercialization of biodiesel are high feedstock cost and conversion technology to reduce viscosity. The choice of raw material and biodiesel production method must depend upon techno-economical view. There are some specific regions for different types of oil availability. It is therefore required to produce biodiesel from the mixture of oils to fulfill the requirements of energy demand in a particular country according to its suitability and availability of feedstock. Karanja and Linseed crops  are abundantly available in India. Biodiesel was produced from a mixture of Karanja and Linseed oils by alkaline transesterification. In this experimental study, biodiesel blends of 10%, 20% and 30% were used with diesel in a diesel engine at a constant speed of 1500 rpm with varying brake powers (loads from 0.5 kW to 3.5kW to evaluate brake thermal efficiency, brake specific fuel consumption,  brake specific energy consumption, exhaust gas temperature, mechanical efficiency, volumetric efficiency, air fuel ratio and smoke opacity. They were compared with diesel and found satisfactory. BTE was found to be  28.76% for B10 at 3.5kW load.  Smoke opacity was also found to be reduced with all blends. Smoke opacity was found to be reduced up to 10.23% for B10 biodiesel blend as compared to that of diesel at 3.5kW. Experimental investigation  has revealed that  biodiesel produced from a mixture of Karanja and Linseed oils can be successfully used in diesel engines without any engine modification  and B10 was found to be an optimum biodiesel blend in terms of brake thermal efficiency. Article History: Received April 14th 2016; Received in revised form June 25th 2016; Accepted

  2. A Decision Support System (DSS) for Project Management in the Bio-diesel Industry

    OpenAIRE

    Alin Paul OLTEANU

    2011-01-01

    The European biodiesel industry is currently facing several challenges affecting the profitability of investment projects in the industry. Among these challenges are higher prices for oilseeds, which are the main input for biodiesel production, lower fiscal support by national governments for biodiesel producers and high price volatility of oil markets. Thus identifying all opportunities for optimizing the value chain and lower the production cost of biodiesel is a main requirement for an eff...

  3. High-level expression and characterization of a chimeric lipase from Rhizopus oryzae for biodiesel production

    OpenAIRE

    Yu, Xiao-Wei; Sha, Chong; Guo, Yong-Liang; Xiao, Rong; Xu, Yan

    2013-01-01

    Background Production of biodiesel from non-edible oils is receiving increasing attention. Tung oil, called “China wood oil” is one kind of promising non-edible biodiesel oil in China. To our knowledge, tung oil has not been used to produce biodiesel by enzymatic method. The enzymatic production of biodiesel has been investigated extensively by using Rhizopus oryzae lipase as catalyst. However, the high cost of R. oryzae lipase remains a barrier for its industrial applications. Through differ...

  4. Production of Biodiesel from Lipid of Phytoplankton Chaetoceros calcitrans through Ultrasonic Method

    OpenAIRE

    Raymond Kwangdinata; Indah Raya; Muhammad Zakir

    2014-01-01

    A research on production of biodiesel from lipid of phytoplankton Chaetoceros calcitrans through ultrasonic method has been done. In this research, we carried out a series of phytoplankton cultures to determine the optimum time of growth and biodiesel synthesis process from phytoplankton lipids. Process of biodiesel synthesis consists of two steps, that is, isolation of phytoplankton lipids and biodiesel synthesis from those lipids. Oil isolation process was carried out by ultrasonic extracti...

  5. Dynamics of Peroxy and Alkenyl Radicals Undergoing Competing Rearrangements in Biodiesel Combustion

    Energy Technology Data Exchange (ETDEWEB)

    Dibble, Theodore S. [State Univ. of New York (SUNY), Syracuse, NY (United States)

    2016-03-24

    Biodiesel fuel is increasingly being used worldwide. Although we have a fair understanding of the molecular details of the chemistry of peroxy radicals derived from alkanes, biodiesel fuels contain ester and olefin groups which significantly impact the thermodynamics and kinetics of biodiesel ignition. The broader goal of this research is to carry out systematic computational studies of the elementary kinetics of the chemistry of ROO•, QOOH and •OOQOOH compounds that are models for biodiesel ignition.

  6. 生物柴油一柴油混合燃料性能和排放的实验研究%Performance and Emission Tests of Biodiesel-diesel Blends

    Institute of Scientific and Technical Information of China (English)

    宋天一; 雷廷宙; 王志伟; 朱金陵; 何晓峰

    2012-01-01

    实验研究了由地沟油甲酯化得到的生物柴油和柴油的混合燃料在单缸四冲程柴油机中的燃烧性能和尾气排放,生物柴油的添加体积分数分别为10%,20%和30%.结果表明,由于生物柴油热值较低,混合燃料的油耗率比纯柴油高出10%左右;NOx,CO和CO2的排放浓度随柴油机输出功率的增大而升高,随着生物柴油浓度的升高,NOx和CO2的排放浓度呈先上升后下降的趋势,而CO的排放浓度则逐渐降低至纯柴油的排放水平;尾气烟度随生物柴油浓度的增加而明显降低.%Performances and exhaust emissions of biodiesel-diesel blends, with biodiesel (waste cooking oil methyl esters) percentages of 10% ,20% and 30%, were tested and compared with pure diesel in a horizontal single cylinder four stroke diesel engine. Experimental results showed that brake specific fuel consumptions of biodiesel-diesel blends were higher than pure diesel for no more than 10% generally; Nox, CO and CO2 emissions increased with engine power; with increasing of biodiesel percentage. Nox and CO2 emissions increased and followed by decreasing, CO emissions decreased all along to values similar with pure diesel; smoke emissions decreased with the increasing of biodiesel percentage.

  7. Potential use of eucalyptus biodiesel in compressed ignition engine

    Directory of Open Access Journals (Sweden)

    Puneet Verma

    2016-03-01

    Full Text Available The increased population has resulted in extra use of conventional sources of fuels due to which there is risk of extinction of fossil fuels’ resources especially petroleum diesel. Biodiesel is emerging as an excellent alternative choice across the world as a direct replacement for diesel fuel in vehicle engines. Biodiesel offers a great choice. It is mainly derived from vegetable oils, animal fats and algae. Hence in this paper effort has been made to find out feasibility of biodiesel obtained from eucalyptus oil and its impact on diesel engine. Higher viscosity is a major issue while using vegetable oil directly in engine which can be removed by converting it into biodiesel by the process of transesterification. Various fuel properties like calorific value, flash point and cetane value of biodiesel and biodiesel–diesel blends of different proportions were evaluated and found to be comparable with petroleum diesel. The result of investigation shows that Brake Specific Fuel Consumption (BSFC for two different samples of B10 blend of eucalyptus biodiesel is 2.34% and 2.93% lower than that for diesel. Brake Thermal Efficiency (BTE for B10 blends was found to be 0.52% and 0.94% lower than that for diesel. Emission characteristics show that Smoke Opacity improves for both samples, smoke is found to be 64.5% and 62.5% cleaner than that of diesel. Out of all blends B10 was found to be a suitable alternative to conventional diesel fuel to control air pollution without much significant effect on engine performance. On comparing both samples, biodiesel prepared from sample A of eucalyptus oil was found to be superior in all aspects of performance and emission.

  8. Biodiesel production from seed oil of Cleome viscosa L.

    Science.gov (United States)

    Kumari, Rashmi; Jain, Vinod Kumar; Kumar, Sushil

    2012-07-01

    Edible oil seed crops, such as rapeseed, sunflower, soyabean and safflower and non-edible seed oil plantation crops Jatropha and Pongamia have proved to be internationally viable commercial sources of vegetable oils for biodiesel production. Considering the paucity of edible oils and unsustainability of arable land under perennial plantation of Jatropha and Pongamia in countries such as India, the prospects of seed oil producing Cleome viscosa, an annual wild short duration plant species of the Indogangetic plains, were evaluated for it to serve as a resource for biodiesel. The seeds of C. viscosa resourced from its natural populations growing in Rajasthan, Haryana and Delhi areas of Aravali range were solvent extracted to obtain the seed oil. The oil was observed to be similar in fatty acid composition to the non-edible oils of rubber, Jatropha and Pongamia plantation crops and soybean, sunflower, safflower, linseed and rapeseed edible oil plants in richness of unsaturated fatty acids. The Cleome oil shared the properties of viscosity, density, saponification and calorific values with the Jatropha and Pongamia oils, except that it was comparatively acidic. The C. viscosa biodiesel had the properties of standard biodiesel specified by ASTM and Indian Standard Bureau, except that it had low oxidation stability. It proved to be similar to Jatropha biodiesel except in cloud point, pour point, cold filter plugging point and oxidation stability. In view of the annual habit of species and biodiesel quality, it can be concluded that C. viscosa has prospects to be developed into a short-duration biodiesel crop.

  9. Prediction of class membership of biodiesels using chemometrics.

    Science.gov (United States)

    Mustafa, Zylia; Milina, Rumyana; Simeonova, Pavlina A; Tsakovski, Stefan L; Simeonov, Vasil D

    2015-01-01

    Recently, serious scientific and technological attention is paid to creation of alternative energy sources, including biofuels. The assessment of the quality of the biofuels produced and of the raw materials needed for the production technology is an important scientific challenge. One of the major sources for biodiesel production is plant oils material (sunflower, rapeseed, palm, soya etc.). Since plants are complex system from the biota it is not easy to find specific chemical components responsible for their ability to serve as biodiesels. The characterization and classification of plant sources as biofuel material could be reliably estimated only by the use of multivariate statistical approaches (chemometrics). The chemometric expertise makes it possible not only to classify different biofuel sources into similarity classes but also to predict the membership of unknown by origin chemically analyzed samples to already existing classes. The present study deals with the prediction of the class membership of several unknown by origin samples, which are included in a large data set with FAME profiles of biodiesel plant sources. Using a data set from chromatographic analysis of fatty acid methyl esters profiles (FAME) of different plant biodiesel sources and applying the chemometric technique know as partial least squares-discriminant analysis (PLS - DA) a pattern recognition procedure is developed to: I. Model classes of similarity of biodiesel plant sources using their FAME profiles not taking into account the samples with unknown origin; II. Classify correctly the samples with unknown origin to the previously defined classes of biodiesel sources (palm oil, soybean oil, peanut oil, rapeseed oil, sunflower oil and maize oil). The prediction is successfully achieved for all samples with previously unknown origin. This pattern recognition approach is applied for the first time in the field of biodiesel classification and modeling tasks.

  10. Biodiesel from lignocellulosic biomass--prospects and challenges.

    Science.gov (United States)

    Yousuf, Abu

    2012-11-01

    Biodiesel can be a potential alternative to petroleum diesel, but its high production cost has impeded its commercialization in most parts of the world. One of the main drivers for the generation and use of biodiesel is energy security, because this fuel can be produced from locally available resources, thereby reducing the dependence on imported oil. Many countries are now trying to produce biodiesel from plant or vegetable oils. However, the consumption of large amounts of vegetable oils for biodiesel production could result in a shortage in edible oils and cause food prices to soar. Alternatively, the use of animal fat, used frying oils, and waste oils from restaurants as feedstock could be a good strategy to reduce the cost. However, these limited resources might not meet the increasing demand for clean, renewable fuels. Therefore, recent research has been focused the use of residual materials as renewable feedstock in order to lower the cost of producing biodiesel. Microbial oils or single cell oils (SCOs), produced by oleaginous microorganisms have been studied as promising alternatives to vegetable or seed oils. Various types of agro-industrial residues have been suggested as prospective nutritional sources for microbial cultures. Since the most abundant residue from agricultural crops is lignocellulosic biomass (LCB), this byproduct has been given top-priority consideration as a source of biomass for producing biodiesel. But the biological transformation of lignocellulosic materials is complicated due to their crystalline structure. So, pretreatment is required before they can be converted into fermentable sugar. This article compares and scrutinizes the extent to which various microbes can accumulate high levels of lipids as functions of the starting materials and the fermentation conditions. Also, the obstacles associated with the use of LCB are described, along with a potentially viable approach for overcoming the obstacles that currently preclude the

  11. Prospects of biodiesel from Jatropha in India: A review

    Energy Technology Data Exchange (ETDEWEB)

    Jain, Siddharth; Sharma, M.P. [Alternate Hydro Energy Centre, Indian Institute of Technology Roorkee, Roorkee 247667, Uttarakhand (India)

    2010-02-15

    The increasing industrialization and modernization of the world has to a steep rise for the demand of petroleum products. Economic development in developing countries has led to huge increase in the energy demand. In India, the energy demand is increasing at a rate of 6.5% per annum. The crude oil demand of the country is met by import of about 80%. Thus the energy security has become a key issue for the nation as a whole. Petroleum-based fuels are limited. The finite reserves are highly concentrated in certain regions of the world. Therefore, those countries not having these reserves are facing foreign exchange crises, mainly due to the import of crude oil. Hence it is necessary to look forward for alternative fuels, which can be produced from feedstocks available within the country. Biodiesel, an ecofriendly and renewable fuel substitute for diesel has been getting the attention of researchers/scientists of all over the world. The R and D has indicated that up to B20, there is no need of modification and little work is available related to suitability and sustainability of biodiesel production from Jatropha as non-edible oil sources. In addition, the use of vegetable oil as fuel is less polluting than petroleum fuels. The basic problem with biodiesel is that it is more prone to oxidation resulting in the increase in viscosity of biodiesel with respect to time which in turn leads to piston sticking, gum formation and fuel atomization problems. The report is an attempt to present the prevailing fossil fuel scenario with respect to petroleum diesel, fuel properties of biodiesel resources for biodiesel production, processes for its production, purification, etc. Lastly, an introduction of stability of biodiesel will also be presented. (author)

  12. Engineering an Escherichia coli platform to synthesize designer biodiesels.

    Science.gov (United States)

    Wierzbicki, Michael; Niraula, Narayan; Yarrabothula, Akshitha; Layton, Donovan S; Trinh, Cong T

    2016-04-20

    Biodiesels, fatty acid esters (FAEs), can be synthesized by condensation of fatty acid acyl CoAs and alcohols via a wax ester synthase in living cells. Biodiesels have advantageous characteristics over petrodiesels such as biodegradability, a higher flash point, and less emission. Controlling fatty acid and alcohol moieties are critical to produce designer biodiesels with desirable physiochemical properties (e.g., high cetane number, low kinematic viscosity, high oxidative stability, and low cloud point). Here, we developed a flexible framework to engineer Escherichia coli cell factories to synthesize designer biodiesels directly from fermentable sugars. In this framework, we designed each FAE pathway as a biodiesel exchangeable production module consisting of acyl CoA, alcohol, and wax ester synthase submodules. By inserting the FAE modules in an engineered E. coli modular chassis cell, we generated E. coli cell factories to produce targeted biodiesels (e.g., fatty acid ethyl (FAEE) and isobutyl (FAIbE) esters) with tunable and controllable short-chain alcohol moieties. The engineered E. coli chassis carrying the FAIbE production module produced 54mg/L FAIbEs with high specificity, accounting for>90% of the total synthesized FAEs and ∼4.7 fold increase in FAIbE production compared to the wildtype. Fed-batch cultures further improved FAIbE production up to 165mg/L. By mixing ethanol and isobutanol submodules, we demonstrated controllable production of mixed FAEEs and FAIbEs. We envision the developed framework offers a flexible, alternative route to engineer designer biodiesels with tunable and controllable properties using biomass-derived fermentable sugars. Copyright © 2016 Elsevier B.V. All rights reserved.

  13. Cold flow properties of biodiesel: A guide to getting an accurate analysis

    Science.gov (United States)

    Biodiesel has several advantages compared to conventional diesel fuel (petrodiesel). Nevertheless, biodiesel has poor cold flow properties that may restrict its use in moderate climates. It is essential that the cold flow properties of biodiesel and its blends with petrodiesel be measured as accurat...

  14. Aerobic Biodegradation Kinetics And Mineralization Of Six Petrodiesel/Soybean-Biodiesel Blends

    Science.gov (United States)

    The aerobic biodegradation kinetics and mineralization of six petrodiesel/soybean-biodiesel blends (B0, B20, B40, B60, B80, and B100), where B100 is 100% biodiesel, were investigated by acclimated cultures. The fatty acid methyl esters (FAMEs) of biodiesel were found to undergo ...

  15. DNA adducts induced by in vitro activation of extracts of diesel and biodiesel exhaust particles

    Science.gov (United States)

    AbstractContext: Biodiesel and biodiesel-blend fuels offer a renewable alternative to petroleum diesel, but few data are available concerning the carcinogenic potential of biodiesel exhausts. Objectives: We compared the formation of covalent DNA adducts by the in vitro metabol...

  16. Quantitative Investigations of Biodiesel Fuel Using Infrared Spectroscopy: An Instrumental Analysis Experiment for Undergraduate Chemistry Students

    Science.gov (United States)

    Ault, Andrew P.; Pomeroy, Robert

    2012-01-01

    Biodiesel has gained attention in recent years as a renewable fuel source due to its reduced greenhouse gas and particulate emissions, and it can be produced within the United States. A laboratory experiment designed for students in an upper-division undergraduate laboratory is described to study biodiesel production and biodiesel mixing with…

  17. 16 CFR Appendix A to Part 306 - Summary of Labeling Requirements for Biodiesel Fuels

    Science.gov (United States)

    2010-01-01

    ... Biodiesel Fuels A Appendix A to Part 306 Commercial Practices FEDERAL TRADE COMMISSION REGULATIONS UNDER... Part 306—Summary of Labeling Requirements for Biodiesel Fuels (Part 1 of 2) Fuel type Blends of 5 percent or less Blends of more than 5 but not more than 20 percent Header Text Color Biodiesel No...

  18. 76 FR 78290 - Cooperative Research and Development Agreement: Usage of Biodiesel Fuel Blends Within Marine...

    Science.gov (United States)

    2011-12-16

    ... SECURITY Coast Guard Cooperative Research and Development Agreement: Usage of Biodiesel Fuel Blends Within... technology enhancements, performance, costs, and other issues associated with using biodiesel fuel blends in... notice (investigating the use of biodiesel fuel blends in marine inboard engines) must reach the...

  19. [FTIR detection of unregulated emissions from a diesel engine with biodiesel fuel].

    Science.gov (United States)

    Tan, Pi-qiang; Hu, Zhi-yuan; Lou, Di-ming

    2012-02-01

    Biodiesel, as one of the most promising alternative fuels, has received more attention because of limited fossil fuels. A comparison of biodiesel and petroleum diesel fuel is discussed as regards engine unregulated exhaust emissions. A diesel fuel, a pure biodiesel fuel, and fuel with 20% V/V biodiesel blend ratio were tested without engine modification The present study examines six typical unregulated emissions by Fourier transform infrared spectroscopy (FTIR) method: formaldehyde (HCHO), acetaldehyde (C2 H4 O), acetone (C3 H6 O), toluene (C7 H8), sulfur dioxide (SO2), and carbon dioxide (CO2). The results show addition of biodiesel fuel increases the formaldehyde emission, and B20 fuel has little change, but the formaldehyde emission of pure biodiesel shows a clear trend of addition. Compared with the pure diesel fuel, the acetaldehyde of B20 fuel has a distinct decrease, and the acetaldehyde emission of pure biodiesel is lower than that of the pure diesel fuel at low and middle engine loads, but higher at high engine load. The acetone emission is very low, and increases for B20 and pure biodiesel fuels as compared to diesel fuel. Compared with the diesel fuel, the toluene and sulfur dioxide values of the engine show a distinct decrease with biodiesel blend ratio increasing. It is clear that the biodiesel could reduce aromatic compounds and emissions of diesel engines. The carbon dioxide emission of pure biodiesel has a little lower value than diesel, showing that the biodiesel benefits control of greenhouse gas.

  20. DNA adducts induced by in vitro activation of extracts of diesel and biodiesel exhaust particles

    Science.gov (United States)

    AbstractContext: Biodiesel and biodiesel-blend fuels offer a renewable alternative to petroleum diesel, but few data are available concerning the carcinogenic potential of biodiesel exhausts. Objectives: We compared the formation of covalent DNA adducts by the in vitro metabol...

  1. Aerobic Biodegradation Kinetics And Mineralization Of Six Petrodiesel/Soybean-Biodiesel Blends

    Science.gov (United States)

    The aerobic biodegradation kinetics and mineralization of six petrodiesel/soybean-biodiesel blends (B0, B20, B40, B60, B80, and B100), where B100 is 100% biodiesel, were investigated by acclimated cultures. The fatty acid methyl esters (FAMEs) of biodiesel were found to undergo ...

  2. Anaerobic Biodegradation of Soybean Biodiesel and Diesel Blends under Methanogenic Conditions

    Science.gov (United States)

    Biotransformation of soybean biodiesel and the inhibitory effect of petrodiesel were studied under methanogenic conditions. Biodiesel removal efficiency of more than 95% was achieved in a chemostat with influent biodiesel concentrations up to 2.45 g/L. The kinetics of anaerobic...

  3. Quantitative Investigations of Biodiesel Fuel Using Infrared Spectroscopy: An Instrumental Analysis Experiment for Undergraduate Chemistry Students

    Science.gov (United States)

    Ault, Andrew P.; Pomeroy, Robert

    2012-01-01

    Biodiesel has gained attention in recent years as a renewable fuel source due to its reduced greenhouse gas and particulate emissions, and it can be produced within the United States. A laboratory experiment designed for students in an upper-division undergraduate laboratory is described to study biodiesel production and biodiesel mixing with…

  4. Complete utilization of spent coffee grounds to produce biodiesel, bio-oil and biochar

    Science.gov (United States)

    This study presents the complete utilization of spent coffee grounds to produce biodiesel, bio-oil and biochar. Lipids extracted from spent grounds were converted to biodiesel to evaluate neat and blended (B5 and B20) fuel properties against ASTM and EN standards. Although neat biodiesel displayed h...

  5. OPTIMASI SUHU REAKSI TRANSESTERIFIKASI PADA MINYAK JERAMI PADI (ORYZA SATIVA L. MENJADI BIODIESEL DENGAN MENGGUNAKAN KATALIS CAO DARI KULIT TELUR AYAM

    Directory of Open Access Journals (Sweden)

    Tasik Sinta

    2016-11-01

    Full Text Available The research on optimization of transesterification temperature for production of biodiesel from rice straw oil (Oryza sativa L. using CaO catalyst derived from the chicken egg skin has been conducted. Production of biodiesel was conducted at varied temperatures, namely 30oC, 40oC, 50oC, 60oC and 70oC. The fatty acid compositions of the transesterification products were determined by using GC-MS and the physical and chemical characteristics were determined using SNI Methods 04-7182-2006. The AAS result suggested that the chicken egg skin contained 91.41% CaO. The optimum transesterification temperature was 60oC producing 90,8405% methyl ester. The results of GC-MS showed that the highest percentage of fatty acid was methyl oleic (44.56%.

  6. Evaluation of natural smile: Golden proportion, RED or Golden percentage.

    Science.gov (United States)

    Murthy, B V Sreenivasan; Ramani, Niketa

    2008-01-01

    Creating geometric or mathematical proportion to relate the successive width of maxillary anterior teeth is a critical aspect in Esthetic dentistry. Golden proportion, recurring esthetic dental (RED) proportion and golden percentage are new theories in this field. To investigate the existence and suitability of Golden proportion, Recurring Esthetic Dental, and Golden percentage between the widths of maxillary anterior teeth in individuals with natural dentition, with the aid of digital photographs and computer analysis. Standardized frontal images of 56 dental students, 20 male and 36 female, were captured. Each maxillary anterior tooth was digitally measured. Once the measurements were recorded, the three theories were applied and the data was analyzed statistically. The golden proportion was found to exist only in 14-25% of the subjects, between perceived maxillary anterior teeth in natural dentition. The value of RED proportion was not constant, and as one moved distally, this proportion gradually increased. Furthermore, the results revealed that golden percentage was rather constant in terms of relative tooth width. Central incisor represented 22%, lateral incisor 15% and canine 13% of the width of six maxillary anterior teeth, as viewed from the front. Both golden proportion and RED proportion are unsuitable methods to relate the successive width of the maxillary anterior teeth in natural dentition. However, the golden percentage theory can be applied if percentages are adjusted, taking into consideration the ethnicity of the population.

  7. Western Kentucky University Research Foundation Biodiesel Project

    Energy Technology Data Exchange (ETDEWEB)

    Pan, Wei-Ping [Principal Investigator; Cao, Yan [Co-Principal Investigator

    2013-03-15

    Petroleum-based liquid hydrocarbons is exclusively major energy source in the transportation sector. Thus, it is the major CO{sub 2} source which is the associated with greenhouse effect. In the United States alone, petroleum consumption in the transportation sector approaches 13.8 million barrels per day (Mbbl/d). It is corresponding to a release of 0.53 gigatons of carbon per year (GtC/yr), which accounts for approximate 7.6 % of the current global release of CO{sub 2} from all of the fossil fuel usage (7 GtC/yr). For the long term, the conventional petroleum production is predicted to peak in as little as the next 10 years to as high as the next 50 years. Negative environmental consequences, the frequently roaring petroleum prices, increasing petroleum utilization and concerns about competitive supplies of petroleum have driven dramatic interest in producing alternative transportation fuels, such as electricity-based, hydrogen-based and bio-based transportation alternative fuels. Use of either of electricity-based or hydrogen-based alternative energy in the transportation sector is currently laden with technical and economical challenges. The current energy density of commercial batteries is 175 Wh/kg of battery. At a storage pressure of 680 atm, the lower heating value (LHV) of H{sub 2} is 1.32 kWh/liter. In contrast, the corresponding energy density for gasoline can reach as high as 8.88 kWh/liter. Furthermore, the convenience of using a liquid hydrocarbon fuel through the existing infrastructures is a big deterrent to replacement by both batteries and hydrogen. Biomass-derived ethanol and bio-diesel (biofuels) can be two promising and predominant U.S. alternative transportation fuels. Both their energy densities and physical properties are comparable to their relatives of petroleum-based gasoline and diesel, however, biofuels are significantly environmental-benign. Ethanol can be made from the sugar-based or starch-based biomass materials, which is easily

  8. Emissions from a generator fueled by blends of diesel, biodiesel, acetone, and isopropyl alcohol: analyses of emitted PM, particulate carbon, and PAHs.

    Science.gov (United States)

    Tsai, Jen-Hsiung; Chen, Shui-Jen; Huang, Kuo-Lin; Lin, Wen-Yinn; Lee, Wen-Jhy; Lin, Chih-Chung; Hsieh, Lien-Te; Chiu, Juei-Yu; Kuo, Wen-Chien

    2014-01-01

    Biodiesel is one of alternative energies that have been extensively discussed and studied. This research investigates the characteristics of particulate matter (PM), particulate carbon, and polycyclic aromatic hydrocarbons (PAHs) emitted from a generator fueled by waste-edible-oil-biodiesel with acetone and isopropyl alcohol (IPA) addition. The tested biodieselhols consisted of pure diesel oil (D100) with 1-3 vol.% pure acetone (denoted as A), 1-70 vol.% waste-edible-oil-biodiesel (denoted as W), and 1 vol.% pure isopropyl alcohol (the stabilizer, denoted as P). The results show that in comparison to W1D99, W3D97, W5D95, W10D90, and W20D80, the use of biodieselhols achieved additional reduction of PM and particulate organic carbon (OC) emission, and such reduction increased as the addition percentage of pure acetone increased. Regardless of the percentages of added waste-edible-oil-biodiesel, acetone, and isopropyl alcohol, the use of biodieselhol in place of D100 could reduce the emissions of Total-PAHs (by 6.13-42.5% (average = 24.1%)) and Total-BaPeq (by 16.6-74.8% (average = 53.2%)) from the diesel engine generator. Accordingly, the W/D blended fuels (W<20 vol.%) containing acetone (1-3 vol.%) and isopropyl alcohol (1 vol.%) are a potential alternative fuel for diesel engine generators because they substantially reduce emissions of PM, particulate OC, Total-PAHs, and Total-BaPeq. © 2013. Published by Elsevier B.V. All rights reserved.

  9. Use of clays for purification of biodiesel; Utilizacao de argilas para purificacao de biodiesel

    Energy Technology Data Exchange (ETDEWEB)

    Paula, Andreia Juliana Almeida de; Kruegel, Marlus; Miranda, Joao Paulo; Rossi, Luciano Fernando dos Santos; Costa Neto, Pedro Ramos da, E-mail: pedroneto@utfpr.edu.b [Universidade Tecnologica Federal do Parana (UTFPR), Curitiba, PR (Brazil). Depts. de Quimica, Biologia e Mecanica

    2011-07-01

    This work describes the results of the purification of methyl biodiesel, obtained by oxidized soybean oil, using different methods. After the ester separation from the glycerin by decanting, the ester was purified each time with distillation, washing with water and adsorption with bauxite, bentonite and attapulgite. The removal of total contamination, unsaponifiable material, concentrations of free glycerin and soap were analyzed in the purified ester phase. The best result of purification was observed with the use of bentonite and bauxite, in the removal of soap and free glycerin respectively. (author)

  10. Determination of antioxidant content in biodiesel by fluorescence spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Magalhaes, Keurison F.; Caires, Anderson R.L. [Universidade Federal da Grande Dourados, MS (Brazil). Grupo de Optica Aplicada; Oliveira, Samuel L. [Universidade Federal de Mato Grosso do Sul (UFMS), MS (Brazil). Grupo de Optica e Fotonica

    2011-07-01

    Full text. Biodiesel is an alternative fuel composed by mono-alkyl esters obtained from vegetable oils or animal fats. Due to its chemical structure, biodiesel is highly susceptible to oxidation which leads to formation of insoluble gums and sediments that can block the filter system of fuel injection. Biodiesel made from vegetable oils typically has a small amount of natural antioxidants so that it is necessary to add synthetic antioxidants to enhance its stability and retain their properties for a longer period. The main antioxidants are synthetic phenolic compounds such as butylated hydroxyanisole (BHA), butylated hydroxytoluene (BHT) and tert-butyl hydroquinone (TBHQ) as well as natural antioxidants as tocopherols. The fluorescence spectroscopy has been applied for determination of phenolic compounds in oils. Here, a method based on fluorescence is proposed to quantify the BHA and TBHQ antioxidant concentration in biodiesel produced from sunflower and soybean oils. Soybean and sunflower biodiesel were obtained by transesterification of fatty alcohol in the presence of NaOH as catalyst. The reactions were carried out in the molar ratio of 6:1 methanol/oil. After the production and purification, biodiesel samples were stored. Biodiesel samples with BHA and TBHQ concentrations from 1000 to 8000 ppm (m/m) were pre- pared. These samples were diluted in ethanol (95%) in order to measure the fluorescence spectra. Fluorescence and excitation spectra of the solutions were recorded at room temperature using a spectrofluorimeter. The emission spectra were obtained under excitation at about 310nm and fluorescence in the 320-800nm range was evaluated. Biodiesel samples without BHA and TBHQ showed fluorescence band at about 420nm, which can be attributed to tocopherols inherent to the vegetable oils used in the biodiesel production. The addition of BHA and/or TBHQ is responsible for the appearance of a fluorescence band around 330nm. It was verified that the fluorescence

  11. Comparative Analysis of Biodiesels from Calabash and Rubber Seeds Oils

    Directory of Open Access Journals (Sweden)

    J.O. Awulu

    2015-07-01

    Full Text Available Physicochemical properties of biodiesel from vegetable oils depend on the inherent properties of the oil-producing seeds. The purpose of this study is to investigate the physicochemical properties of biodiesels extracted from calabash and rubber seeds oils, as well as their combined oil mixtures with a view to ascertaining the most suitable for biodiesel production. Calabash and rubber seeds oils were separately extracted through the use of a mechanical press with periodic addition of water. Biodiesels were produced from each category of the oils by transesterification of the free fatty acid (FFA with alcohol under the influence of a catalyst in batch process. The physicochemical properties of the biodiesels were investigated and comparatively analysed. The results obtained indicated an average of 1.40 wt% FFA for biodiesel produced from the purified calabash oil, which has a specific gravity of 0.920, pH of 5.93, flash point of 116 0C, fire point of 138 0C, cloud point of 70 0C, pour point of -4 0C, moisture content of 0.82 wt% and specific heat capacity of 5301 J/kgK. Conversely, the results obtained for biodiesel produced from the purified rubber oil showed an average of 33.66 wt% FFA, specific gravity of 0.885, pH of 5.51, flash point of 145 0C, fire point of 170 0C, cloud point of 10 0C, pour point of 4 0C, moisture content of 1.30 wt% and specific heat capacity of 9317 J/kgK. However, results obtained for biodiesel produced from the combined oil mixtures indicated an average of 19.77 wt% FFA content, specific gravity of 0.904, API gravity of 25.036, pH value of 5.73, flash point of 157 0C, Fire point of 180 0C, cloud point of 9 0C, pour point of 5 0C, moisture content of 0.93 wt% and specific heat capacity of 6051 J/kgK. Biodiesel produced from calabash seed oil is superior in quality to rubber seed oil, particularly in terms of its low FFA and moisture contents.

  12. Effects of concentration and temperature on tribological properties of biodiesel

    Directory of Open Access Journals (Sweden)

    De-Xing Peng

    2015-11-01

    Full Text Available For tribologists, continuing challenges in engine design include reduced emissions and increased operating temperatures. Regulating the sulfur content in diesel fuel is expected to reduce the lubricity of these fuels, which may result in increased wear and damage of fuel injection systems in diesel engines. However, the use of biodiesel improves lubricity and cetane number requirements, particularly in ultra-low sulfur petro-diesel. In this study, the effect of temperature on the tribological properties of palm biodiesel was investigated using a wear machine. Palm biodiesel was used as a lubricating additive to petro-diesel at six concentrations of 2%, 5%, 10%, 20%, 50%, and 100%, and these biodiesel blends were named as B2, B5, B10, B20, B50, and B100, respectively. The tribological experiments were performed using the ball-on-ring method. Tests were conducted at 30°C, 60°C, 90°C, and 120°C, under a normal load of 50 N for 2 h and at a speed of 500 r/min. The wear scar diameter and the worn surface of tribopairs were studied and analyzed. According to the wear experimental results, the addition of a small amount of palm biodiesel to petroleum diesel can bring about a considerable reduction in the wear and friction under boundary lubrication. Results show that friction and wear increase with increasing temperature.

  13. Life cycle assessment of palm-derived biodiesel in Taiwan

    KAUST Repository

    Maharjan, Sumit

    2016-10-01

    In Taiwan, due to the limited capacity of waste cooking oil, palm oil has been viewed as the potential low-cost imported feedstock for producing biodiesel, in the way of obtaining oil feedstock in Malaysia and producing biodiesel in Taiwan. This study aims to evaluate the cradle-to-grave life cycle environmental performance of palm biodiesel within two different Asian countries, Malaysia and Taiwan. The phases of the life cycle such as direct land-use-change impact, plantation and milling are investigated based on the Malaysia case and those of refining, and fuel production as well as engine combustion is based on Taiwan case. The greenhouse gas (GHG) emission and energy consumption for the whole life cycle were calculated as −28.29 kg CO2-equiv. and +23.71 MJ/kg of palm-derived biodiesel. We also analyze the impacts of global warming potential (GWP) and the payback time for recovering the GHG emissions when producing and using biodiesel. Various scenarios include (1) clearing rainforest or peat-forest; (2) treating or discharging palm-oil-milling effluent (POME) are further developed to examine the effectiveness of improving the environmental impacts © 2016 Springer-Verlag Berlin Heidelberg

  14. Cultivation of freshwater microalgae in biodiesel wash water.

    Science.gov (United States)

    Sassi, Patrícia Giulianna Petraglia; Calixto, Clediana Dantas; da Silva Santana, Jordana Kaline; Sassi, Roberto; Costa Sassi, Cristiane Francisca; Abrahão, Raphael

    2017-06-21

    Biodiesel wash water is a contaminating industrial effluent that must be treated prior to disposal. The use of this effluent as a low-cost alternative cultivation medium for microalgae could represent a viable supplementary treatment. We cultivated 11 microalgae species with potential use for biodiesel production to assess their growth capacities in biodiesel industrial washing waters. Only Monoraphidium contortum, Ankistrodesmus sp., Chlorococcum sp., and one unidentified Chlorophyceae species grew effectively in that effluent. M. contortum showed the highest growth capacity and had the second highest fatty acid content (267.9 mg g(-1) of DW), predominantly producing palmitic (20.9%), 7,10,13-hexadecatrienoic (14%), oleic (16.2%), linoleic (10.5%), and linolenic acids (23.2%). In the second phase of the experiment, the microalgae were cultivated in biodiesel wash water at 75% of its initial concentration as well as in WC (control) medium. After 21 days of cultivation, 25.8 and 7.2% of the effluent nitrate and phosphate were removed, respectively, and the chemical oxygen demand was diminished by 31.2%. These results suggest the possibility of cultivating biodiesel producing microalgae in industrial wash water effluents.

  15. Conversion of lipid from food waste to biodiesel.

    Science.gov (United States)

    Karmee, Sanjib Kumar; Linardi, Darwin; Lee, Jisoo; Lin, Carol Sze Ki

    2015-07-01

    Depletion of fossil fuels and environmental problems are encouraging research on alternative fuels of renewable sources. Biodiesel is a promising alternative fuel to be used as a substitute to the petroleum based diesel fuels. However, the cost of biodiesel production is high and is attributed mainly to the feedstock used which leads to the investigation of low cost feedstocks that are economically feasible. In this paper, we report on the utilization of lipid obtained from food waste as a low-cost feedstock for biodiesel production. Lipid from food waste was transesterified with methanol using base and lipase as catalysts. The maximum biodiesel yield was 100% for the base (KOH) catalyzed transesterification at 1:10M ratio of lipid to methanol in 2h at 60°C. Novozyme-435 yielded a 90% FAME conversion at 40°C and 1:5 lipid to methanol molar ratio in 24h. Lipid obtained from fungal hydrolysis of food waste is found to be a suitable feedstock for biodiesel production.

  16. Ionic liquid supported acid/base-catalyzed production of biodiesel.

    Science.gov (United States)

    Lapis, Alexandre A M; de Oliveira, Luciane F; Neto, Brenno A D; Dupont, Jairton

    2008-01-01

    The transesterification (alcoholysis) reaction was successfully applied to synthesize biodiesel from vegetable oils using imidazolium-based ionic liquids under multiphase acidic and basic conditions. Under basic conditions, the combination of the ionic liquid 1-n-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (BMINTf2), alcohols, and K2CO3 (40 mol %) results in the production of biodiesel from soybean oil in high yields (>98%) and purity. H2SO4 immobilized in BMINTf2 efficiently promotes the transesterification reaction of soybean oil and various primary and secondary alcohols. In this multiphase process the acid is almost completely retained in the ionic liquid phase, while the biodiesel forms a separate phase. The recovered ionic liquid containing the acid could be reused at least six times without any significant loss in the biodiesel yield or selectivity. In both catalytic processes (acid and base), the reactions proceed as typical multiphasic systems in which the formed biodiesel accumulates as the upper phase and the glycerol by-product is selectively captured by the alcohol-ionic liquid-acid/base phase. Classical ionic liquids such as 1-n-butyl-3-methylimidazolium tetrafluoroborate and hexafluorophosphate are not stable under these acidic or basic conditions and decompose.

  17. Noncatalytic biodiesel fuel production from croton megalocarpus oil

    Energy Technology Data Exchange (ETDEWEB)

    Kafuku, G.; Mbarawa, M. [Department of Mechanical Engineering, Tshwane University of Technology, Pretoria (South Africa); Tan, K.T.; Lee, K.T. [School of Chemical Engineering, Universiti Sains Malaysia, Engineering Campus, Seri Ampangan, Nibong Tebal, Pulau Pinang (Malaysia)

    2011-11-15

    Biodiesel is currently considered as the most promising substitute for diesel fuel because of its similar properties to diesel. This study presents the use of the supercritical methanol method in the production of biodiesel from Croton megalocarpus oil. The reaction parameters such as methanol-to-oil ratio, reaction temperature and reaction time were varied to obtain the optimal reaction conditions by design of experiment, specifically, response surface methodology based on three-variable central composite design with {alpha}=2. It has been shown that it is possible to achieve methyl ester yields as high as 74.91 % with reaction conditions such as 50:1 methanol-to-oil molar ratio, 330 C reaction temperature and a reaction period of 20 min. However, Croton-based biodiesel did not sustain higher temperatures due to decomposition of polyunsaturated methyl linoleate, which is dominant in biodiesel. Lower yields were observed when higher temperatures were used during the optimization process. The supercritical methanol method showed competitive biodiesel yields when compared with catalytic methods. (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  18. Solid Catalysts and theirs Application in Biodiesel Production

    Directory of Open Access Journals (Sweden)

    Ramli Mat

    2012-12-01

    Full Text Available The reduction of oil resources and increasing petroleum price has led to the search for alternative fuel from renewable resources such as biodiesel. Currently biodiesel is produced from vegetable oil using liquid catalysts. Replacement of liquid catalysts with solid catalysts would greatly solve the problems associated with expensive separation methods and corrosion problems, yielding to a cleaner product and greatly decreasing the cost of biodiesel production. In this paper, the development of solid catalysts and its catalytic activity are reviewed. Solid catalysts are able to perform trans-esterification and esterification reactions simultaneously and able to convert low quality oils with high amount of Free Fatty Acids. The parameters that effect the production of biodiesel are discussed in this paper. Copyright © 2012 by BCREC UNDIP. All rights reservedReceived: 6th April 2012, Revised: 24th October 2012, Accepted: 24th October 2012[How to Cite: R. Mat, R.A. Samsudin, M. Mohamed, A. Johari, (2012. Solid Catalysts and Their Application in Biodiesel Production. Bulletin of Chemical Reaction Engineering & Catalysis, 7(2: 142-149. doi:10.9767/bcrec.7.2.3047.142-149] [How to Link / DOI: http://dx.doi.org/10.9767/bcrec.7.2.3047.142-149 ] | View in 

  19. Ultrasound Assisted Esterification of Rubber Seed Oil for Biodiesel Production

    Directory of Open Access Journals (Sweden)

    Berkah Fajar Tamtomo Kiono

    2012-02-01

    Full Text Available roduction of biodiesel is currently shifting from the first to the second generation in which the raw materials are mostly from non-edible type oils and fats. Biodiesel production is commonly conducted under batch operation using mechanical agitation to accelerate mass transfers. The main drawback of oil esterification is the high content of free fatty acids (FFA which may reduce the yield of biodiesel and prolong the production time (2-5 hours. Ultrasonification has been used in many applications such as component extraction due to its ability to produce cavitation under certain frequency. This research is aimed to facilitate ultrasound system for improving biodiesel production process particularly rubber seed oil. An ultrasound unit was used under constant temperature (40oC and frequency of 40 Hz. The result showed that ultrasound can reduces the processing time and increases the biodiesel yield significantly. A model to describe correlation of yield and its independent variables is yield (Y = 43,4894 – 0,6926 X1 + 1,1807 X2 – 7,1042 X3 + 2,6451 X1X2 – 1,6557 X1X3 + 5,7586 X2X3 - 10,5145 X1X2X3, where X1 is mesh sizes, X2 ratio oil: methanol and X3 type of catalyst.

  20. Thermoeconomic Analysis of Biodiesel Production from Used Cooking Oils

    Directory of Open Access Journals (Sweden)

    Emilio Font de Mora

    2015-05-01

    Full Text Available Biodiesel from used cooking oil (UCO is one of the most sustainable solutions to replace conventional fossil fuels in the transport sector. It can achieve greenhouse gas savings up to 88% and at the same time reducing the disposal of a polluting waste. In addition, it does not provoke potential negative impacts that conventional biofuels may eventually cause linked to the use of arable land. For this reason, most policy frameworks favor its consumption. This is the case of the EU policy that double-counters the use of residue and waste use to achieve the renewable energy target in the transport sector. According to different sources, biodiesel produced from UCO could replace around 1.5%–1.8% of the EU-27 diesel consumption. This paper presents an in-depth thermoeconomic analysis of the UCO biodiesel life cycle to understand its cost formation process. It calculates the ExROI value (exergy return on investment and renewability factor, and it demonstrates that thermoeconomics is a useful tool to assess life cycles of renewable energy systems. It also shows that UCO life cycle biodiesel production is more sustainable than biodiesel produced from vegetable oils.

  1. Biodiesel from Forsythia suspense [(Thunb.) Vahl (Oleaceae)] seed oil.

    Science.gov (United States)

    Jiao, Jiao; Gai, Qing-Yan; Wei, Fu-Yao; Luo, Meng; Wang, Wei; Fu, Yu-Jie; Zu, Yuan-Gang

    2013-09-01

    In the present work, Forsythia suspense seed oil (FSSO) was investigated for the first time as an alternative non-conventional feedstock for the preparation of biodiesel. The FSSO yield is 30.08±2.35% (dry weight of F. suspense seed basis), and the oil has low acid value (1.07 mg KOH/g). The fatty acid composition of FSSO exhibits the predominance of linoleic acid (72.89%) along with oleic acid (18.68%) and palmitic acid (5.65%), which is quite similar to that of sunflower oil. Moreover, microwave-assisted transesterification process of FSSO with methanol in the presence of potassium hydroxide catalyst was optimized and an optimal biodiesel yield (90.74±2.02%) was obtained. Furthermore, the fuel properties of the biodiesel product were evaluated as against ASTM D-6751 biodiesel standards and an acceptable agreement was observed except the cetane number. Overall, this study revealed the possibility of FSSO as a potential resource of biodiesel feedstock.

  2. Integrated biodiesel production: a comparison of different homogeneous catalysts systems

    Energy Technology Data Exchange (ETDEWEB)

    Vicente, Gemma; Martinez, Mercedes; Aracil, Jose [Complutense Univ., Dept. of Chemical Engineering, Madrid (Spain)

    2004-05-01

    The most common catalysts for biodiesel production are homogeneous basic catalysts. In the present paper, a comparison is made of different basic catalysts (sodium methoxide, potassium methoxide, sodium hydroxide and potassium hydroxide) for methanolysis of sunflower oil. All the reactions were carried out under the same experimental conditions in a batch stirred reactor and the subsequent separation and purification stages in a decanter. The analytical methods included gas chromatography and the determination of fat and oil conventional parameters. The biodiesel purity was near 100 wt. % for all catalysts. However, near 100 wt. % biodiesel yields were only obtained with the methoxide catalysts. According to the material balance of the process, yield losses were due to triglyceride saponification and methyl ester dissolution in glycerol. Obtained biodiesel met the measured specifications, except for the iodine value, according to the German and EU draft standards. Although all the transesterification reactions were quite rapid and the biodiesel layers achieved nearly 100% methyl ester concentrations, the reactions using sodium hydroxide turned out the fastest. (Author)

  3. Economic Consequences of DifferentLean Percentage Estimation Methods

    Directory of Open Access Journals (Sweden)

    Zdravko Tolušić

    2003-06-01

    Full Text Available The economic effects of the choice of two different lean percentage estimation methods and terminal sire breed were investigated on 53 pig carcasses divided in two groups. In the 1st group were progeny of Pietrain used as terminal sire (n=25 and in 2nd the progeny of Large White terminal sire. It was found that the breed of terminal sire haven.t had influence on cold carcass weight and fat thickness measured for TP method of lean percentage estimation. Inclusion of Pietrain as terminal sire had influence on MLD thickness measured for TP and INS methods which was significantly higher, while fat thickness measured for instrumental method was significantly lower (p<0.01. Carcasses of the same group had higher lean percentage estimated by TP and INS methods (p<0.05 and p<0.01, resp.. Also, different methods of lean percentage estimation resulted in different classification of the carcasses into SEUROP classes. The choice of the lean percentage estimation method had no significant effect on the price of the carcasses from 2nd group which had Large White as terminal sire, while in pig carcasses from the 1st group (Pietrain as terminal sire, the choice of lean percentage method of estimation determined the price of the carcasses, and by this also economic surplus (or loss of the producers. It is concluded that both methods are equally applicable in the case of Large White crossbreeds, while caution should be taken in the case of pig carcasses originated from Pietrain as terminal sire because carcasses of such pigs reached higher prices when estimated by instrumental method.

  4. Miscelánea de pintura decimonónica

    Directory of Open Access Journals (Sweden)

    Arias Anglés, Enrique

    2003-12-01

    Full Text Available El objeto de estas líneas es el de dar a conocer una serie de obras de diversos pintores del siglo XIX, que nos han ido llegando a lo largo de cierto tiempo y por diferentes conductos, y que, por no prestarse a ser publicadas individualmente, queremos hacerlo ahora en conjunto, ya que hemos reunido las suficientes para conformar un pequeño trabajo que pensamos tendrá, aunque sea al menos, el valor de aportar su existencia y conocimiento. Presentándolas por orden cronológico de sus autores, la primera de ellas, procedente de colección particular, es un hermoso dibujo acuarelado de 0,18 x 0,24 m. del pintor romántico español Jenaro Pérez Villaamil, y que por su asunto podríamos titular Contrabando de tabaco con el norte de África (Fig. 1. Se halla firmada en el ángulo inferior derecho «G. P. de Villaamil», con inconfundible caligrafía del artista; y, en el lateral derecho de la obra…

  5. Enhancing clostridial acetone-butanol-ethanol (ABE) production and improving fuel properties of ABE-enriched biodiesel by extractive fermentation with biodiesel.

    Science.gov (United States)

    Li, Qing; Cai, Hao; Hao, Bo; Zhang, Congling; Yu, Ziniu; Zhou, Shengde; Chenjuan, Liu

    2010-12-01

    The extractive acetone-butanol-ethanol (ABE) fermentations of Clostridium acetobutylicum were evaluated using biodiesel as the in situ extractant. The biodiesel preferentially extracted butanol, minimized product inhibition, and increased production of butanol (from 11.6 to 16.5 g L⁻¹) and total solvents (from 20.0 to 29.9 g L⁻¹) by 42% and 50%, respectively. The fuel properties of the ABE-enriched biodiesel obtained from the extractive fermentations were analyzed. The key quality indicators of diesel fuel, such as the cetane number (increased from 48 to 54) and the cold filter plugging point (decreased from 5.8 to 0.2 °C), were significantly improved for the ABE-enriched biodiesel. Thus, the application of biodiesel as the extractant for ABE fermentation would increase ABE production, bypass the energy intensive butanol recovery process, and result in an ABE-enriched biodiesel with improved fuel properties.

  6. Using near-infrared overtone regions to determine biodiesel content and adulteration of diesel/biodiesel blends with vegetable oils.

    Science.gov (United States)

    de Vasconcelos, Fernanda Vera Cruz; de Souza, Paulo Fernandes Barbosa; Pimentel, Maria Fernanda; Pontes, Márcio José Coelho; Pereira, Claudete Fernandes

    2012-02-24

    This work evaluates the use of near-infrared (NIR) overtone regions to determine biodiesel content, as well potential adulteration with vegetable oil, in diesel/biodiesel blends. For this purpose, NIR spectra (12,000-6300 cm(-1)) were obtained using three different optical path lengths: 10 mm, 20 mm and 50 mm. Two strategies of regression with variable selection were evaluated: partial least squares (PLS) with significant regression coefficients selected by Jack-Knife algorithm (PLS/JK) and multiple linear regression (MLR) with wavenumber selection by successive projections algorithm (MLR/SPA). For comparison, the results obtained by using PLS full-spectrum models are also presented. In addition, the performance of models using NIR (1.0 mm optical path length, 9000-4000 cm(-1)) and MIR (UATR - universal attenuated total reflectance, 4000-650 cm(-1)) spectral regions was also investigated. The results demonstrated the potential of overtone regions with MLR/SPA regression strategy to determine biodiesel content in diesel/biodiesel blends, considering the possible presence of raw oil as a contaminant. This strategy is simple, fast and uses a fewer number of spectral variables. Considering this, the overtone regions can be useful to develop low cost instruments for quality control of diesel/biodiesel blends, considering the lower cost of optical components for this spectral region.

  7. Guidelines for Statistical Analysis of Percentage of Syllables Stuttered Data

    Science.gov (United States)

    Jones, Mark; Onslow, Mark; Packman, Ann; Gebski, Val

    2006-01-01

    Purpose: The purpose of this study was to develop guidelines for the statistical analysis of percentage of syllables stuttered (%SS) data in stuttering research. Method; Data on %SS from various independent sources were used to develop a statistical model to describe this type of data. On the basis of this model, %SS data were simulated with…

  8. 78 FR 48789 - Loan Guaranty: Percentage to Determine Net Value

    Science.gov (United States)

    2013-08-09

    ... AFFAIRS Loan Guaranty: Percentage to Determine Net Value AGENCY: Department of Veterans Affairs (VA... component of this is the ``net value'' of the property to the Government, as defined in 38 CFR 36.4301. Essentially ``net value'' is the fair market value of the property, minus the total costs the...

  9. Combustion, emission and engine performance characteristics of used cooking oil biodiesel - A review

    Energy Technology Data Exchange (ETDEWEB)

    Enweremadu, C.C. [Department of Mechanical Engineering, Vaal University of Technology, Private Bag X021, Vanderbijlpark 1900 (South Africa); Rutto, H.L. [Department of Chemical Engineering, Vaal University of Technology, Private Bag X021, Vanderbijlpark 1900 (South Africa)

    2010-12-15

    As the environment degrades at an alarming rate, there have been steady calls by most governments following international energy policies for the use of biofuels. One of the biofuels whose use is rapidly expanding is biodiesel. One of the economical sources for biodiesel production which doubles in the reduction of liquid waste and the subsequent burden of sewage treatment is used cooking oil (UCO). However, the products formed during frying, such as free fatty acid and some polymerized triglycerides, can affect the transesterification reaction and the biodiesel properties. This paper attempts to collect and analyze published works mainly in scientific journals about the engine performance, combustion and emissions characteristics of UCO biodiesel on diesel engine. Overall, the engine performance of the UCO biodiesel and its blends was only marginally poorer compared to diesel. From the standpoint of emissions, NOx emissions were slightly higher while un-burnt hydrocarbon (UBHC) emissions were lower for UCO biodiesel when compares to diesel fuel. There were no noticeable differences between UCO biodiesel and fresh oil biodiesel as their engine performances, combustion and emissions characteristics bear a close resemblance. This is probably more closely related to the oxygenated nature of biodiesel which is almost constant for every biodiesel (biodiesel has some level of oxygen bound to its chemical structure) and also to its higher viscosity and lower calorific value, which have a major bearing on spray formation and initial combustion. (author)

  10. Biodiesel Production by Reactive Flash: A Numerical Simulation

    Directory of Open Access Journals (Sweden)

    Alejandro Regalado-Méndez

    2016-01-01

    Full Text Available Reactive flash (RF in biodiesel production has been studied in order to investigate steady-state multiplicities, singularities, and effect of biodiesel quality when the RF system approaches to bubble point. The RF was modeled by an index-2 system of differential algebraic equations, the vapor split (ϕ was computed by modified Rachford-Rice equation and modified Raoult’s law computed bubble point, and the continuation analysis was tracked on MATCONT. Results of this study show the existence of turning points, leading to a unique bubble point manifold, (xBiodiesel,T=(0.46,478.41 K, which is a globally stable flashing operation. Also, the results of the simulation in MATLAB® of the dynamic behavior of the RF show that conversion of triglycerides reaches 97% for a residence time of 5.8 minutes and a methanol to triglyceride molar flow ratio of 5 : 1.

  11. Lipase-catalyzed biodiesel synthesis with different acyl acceptors

    Directory of Open Access Journals (Sweden)

    Ognjanović Nevena D.

    2008-01-01

    Full Text Available Biodiesel is an alternative fuel for diesel engine that is environmentally acceptable. Conventionally, biodiesel is produced by transesterification of triglycerides and short alcohols in the presence of an acid or an alkaline catalyst. There are several problems associated with this kind of production that can be resolved by using lipase as the biocatalyst. The aim of the present work was to investigate novel acyl acceptors for biodiesel production. 2-Propanol and n-butanol have a less negative effect on lipase stability, and they also improve low temperature properties of the fuel. However, excess alcohol leads to inactivation of the enzyme, and glycerol, a major byproduct, can block the immobilized enzyme, resulting in low enzymatic activity. This problem was solved by using methyl acetate as acyl acceptor. Triacetylglycerol is produced instead of glycerol, and it has no negative effect on the activity of the lipase.

  12. Whole-cell biocatalysts for biodiesel fuel production.

    Science.gov (United States)

    Fukuda, H; Hama, S; Tamalampudi, S; Noda, H

    2008-12-01

    Biodiesel fuel (BDF), which refers to fatty acid alkyl esters, has attracted considerable attention as an environmentally friendly alternative fuel for diesel engines. Alkali catalysis is widely applied for the commercial production of BDF. However, enzymatic transesterification offers considerable advantages, including reducing process operations in biodiesel fuel production and an easy separation of the glycerol byproduct. The high cost of the lipase enzyme is the main obstacle for a commercially feasible enzymatic production of biodiesel fuels. To reduce enzyme associated process costs, the immobilization of fungal mycelium within biomass support particles (BSPs) as well as expression of the lipase enzyme on the surface of yeast cells has been developed to generate whole-cell biocatalysts for industrial applications.

  13. Sustainable and Intensified Design of a Biodiesel Production Process

    DEFF Research Database (Denmark)

    Mansouri, Seyed Soheil; Ismail, Muhammad I.; Babi, Deenesh Kavi

    for process sustainability analysis), ECON (method and tool for process economic analysis), LCSoft (method and tool for process lifecycle assessment analysis) and process simulation software (e.g. PRO/II, ASPEN Plus, ICAS). They are all used in an integrated framework for process synthesis....... impact and maximum profitability is needed. In this work a computer-aided framework for process synthesis and process intensification is applied for sustainable production of biodiesel from pure/waste palm oil as the feedstock. This approach examines several biodiesel processing routes that were...... collected through available data and current technologies reported in the literature. Using this information, a generic superstructure of processing routes was created that described a network of configurations representing multiple designs for the production of biodiesel. Therefore, based on the currently...

  14. Biodegradation of diesel/biodiesel blends in saturated sand microcosms

    DEFF Research Database (Denmark)

    Lisiecki, Piotr; Chrzanowski, Łukasz; Szulc, Alicja

    2014-01-01

    The aim of the study was to evaluate the biodegradation extent of both aromatic and aliphatic hydrocarbon fractions in saturated sandy microcosm spiked with diesel/biodiesel blends (D, B10, B20, B30, B40, B50, B60, B70, B80, B90 and B100, where D is commercial petroleum diesel fuel and B...... is commercial biodiesel blend) augmented with a bacterial consortium of petroleum degraders. The biodegradation kinetics for blends were evaluated based on measuring the amount of emitted CO2 after 578 days. Subsequently, the residual aromatic and aliphatic fractions were separated and determined by employing...... GC-FID and GC _ GC–TOF-MS. Additionally, the influence of biodiesel-amendment on the community dynamics was assessed based on the results of real-time PCR analyzes. Our results suggest that the biodegradation extents of both aliphatic and aromatic hydrocarbon were uninfluenced by the addition...

  15. Coagulation-flocculation of marine Chlorella sp. for biodiesel production.

    Science.gov (United States)

    Sanyano, Naruetsawan; Chetpattananondh, Pakamas; Chongkhong, Sininart

    2013-11-01

    Harvesting of marine Chlorella sp. by autoflocculation and flocculation by addition of coagulant with pH adjustment was investigated in this study. Autoflocculation provided low efficiency. Response surface methodology was employed to optimize the coagulant dosage and pH for flocculation. Aluminium sulfate and ferric chloride were investigated coagulants. The empirical models from RSM are in a good agreement with the experimental results. The optimum flocculation was achieved at ferric chloride dosage 143 mg/L, pH 8.1 and settling time 40 min. Biomass concentration also presented the significant effect on harvesting efficiency. Lipid extracted from marine Chlorella sp. cultivated in urea fertilizer medium with hexane as a solvent is suitable to produce biodiesel according to it contains high proportion of saturated fatty acids. The crude lipid should be purified to remove some impurities before making biodiesel. As the free fatty acid content was higher than 1% a two-step biodiesel production is recommended.

  16. From Fed-batch to Continuous Enzymatic Biodiesel Production

    DEFF Research Database (Denmark)

    2015-01-01

    In this this paper, we use mechanistic modelling to guide the development of acontinuous enzymatic process that is performed as a fed-batch operation. In this workwe use the enzymatic biodiesel process as a case study. A mechanistic model developedin our previous work was used to determine...... measured components (triglycerides, diglycerides, monoglycerides, free fatty acid and fatty acid methyl esters(biodiesel)) much better than using fed-batch data alone given the smaller residuals. We also observe a reduction in the correlation between the parameters.The model was then used to predict that 5...... reactors are required (with a combined residence time of 30 hours) to reach a final biodiesel concentration within 2 % of the95.6 mass % achieved in a fed-batch operation, for 24 hours....

  17. Lipase-immobilized biocatalytic membranes for biodiesel production.

    Science.gov (United States)

    Kuo, Chia-Hung; Peng, Li-Ting; Kan, Shu-Chen; Liu, Yung-Chuan; Shieh, Chwen-Jen

    2013-10-01

    Microbial lipase from Candida rugosa (Amano AY-30) has good transesterification activity and can be used for biodiesel production. In this study, polyvinylidene fluoride (PVDF) membrane was grafted with 1,4-diaminobutane and activated by glutaraldehyde for C. rugosa lipase immobilization. After immobilization, the biocatalytic membrane was used for producing biodiesel from soybean oil and methanol via transesterification. Response Surface Methodology (RSM) in combination with a 5-level-5-factor central composite rotatable design (CCRD) was employed to evaluate the effects of reaction time, reaction temperature, enzyme amount, substrate molar ratio and water content on the yield of soybean oil methyl ester. By ridge max analysis, the predicted and experimental yields under the optimum synthesis conditions were 97% and 95%, respectively. The lipase-immobilized PVDF membrane showed good reuse ability for biodiesel production, enabling operation for at least 165 h during five reuses of the batch, without significant loss of activity.

  18. Biodiesel production in crude oil contaminated environment using Chlorella vulgaris.

    Science.gov (United States)

    Xaaldi Kalhor, Aadel; Mohammadi Nassab, Adel Dabbagh; Abedi, Ehsan; Bahrami, Ahmad; Movafeghi, Ali

    2016-12-01

    Biodiesel is a valuable alternative to fossil fuels and many countries choose biodiesel as an unconventional energy source. A large number of investigations have been done on microalgae as a source of oil production. In recent years, wastewater pollutions have caused many ecological problems, and therefore, wastewater phycoremediation has attracted the international attention. This paper studied the cultivation of Chlorella vulgaris in a crude oil polluted environment for biodiesel production. Intended concentrations were 10 and 20gperliter (crude oil/water) at two times. The results showed that the growth of C. vulgaris was improved in wastewater and the maximum amount of dry mass and oil was produced at the highest concentration of crude oil (0.41g and 0.15g/l, respectively). In addition, dry mass and oil yield of the microalga were significantly enhanced by increasing the experiment duration.

  19. Biodiesel production from microalgae oil catalyzed by a recombinant lipase.

    Science.gov (United States)

    Huang, Jinjin; Xia, Ji; Jiang, Wei; Li, Ying; Li, Jilun

    2015-03-01

    A recombinant Rhizomucor miehei lipase was constructed and expressed in Pichia pastoris. The target enzyme was termed Lipase GH2 and it can be used as a free enzyme for catalytic conversion of microalgae oil mixed with methanol or ethanol for biodiesel production in an n-hexane solvent system. Conversion rates of two major types of biodiesel, fatty acid methyl ester (FAME) and fatty acid ethyl ester (FAEE), reached maximal values (>90%) after 24h. The process of FAME production is generally more simple and economical than that of FAEE production, even though the two processes show similar conversion rates. In spite of the damaging effect of ethanol on enzyme activity, we successfully obtained ethyl ester by the enzymatic method. Our findings indicate that Lipase GH2 is a useful catalyst for conversion of microalgae oil to FAME or FAEE, and this system provides efficiency and reduced costs in biodiesel production.

  20. Biodiesel Production from Bulk Frying Oil with Ultrasound Assisted

    Directory of Open Access Journals (Sweden)

    Widayat

    2013-07-01

    Full Text Available The objective of this research is to optimize of biodiesel production with ultrasound assisted. Optimization was used central composite design methods. Biodiesel was produced from frying oil with KOH catalyst and ultrasonic assisted. The variables were investigated temperature, catalyst concentration and ratio of methanol to oil. Biodiesel was separated from reactant and impurities with decantation process and distillation process. The results of research obtained optimum conversion 85.95% in operation condition are methanol/oil 5.05:1, catalyst concentration 1.65% and temperature reaction 50°C. Mathematic modeling for describe in this process like expressed; Y = 86.2107 - 7.4287X1 + 1.0661X2 + 0.6289X3 - 2.5319X12 - 2.0603X22 - 1.0618X32.

  1. Performance optimization of Jatropha biodiesel engine model using Taguchi approach

    Energy Technology Data Exchange (ETDEWEB)

    Ganapathy, T.; Murugesan, K.; Gakkhar, R.P. [Mechanical and Industrial Engineering Department, Indian Institute of Technology Roorkee, Roorkee 247 667 (India)

    2009-11-15

    This paper proposes a methodology for thermodynamic model analysis of Jatropha biodiesel engine in combination with Taguchi's optimization approach to determine the optimum engine design and operating parameters. A thermodynamic model based on two-zone Weibe's heat release function has been employed to simulate the Jatropha biodiesel engine performance. Among the important engine design and operating parameters 10 critical parameters were selected assuming interactions between the pair of parameters. Using linear graph theory and Taguchi method an L{sub 16} orthogonal array has been utilized to determine the engine test trials layout. In order to maximize the performance of Jatropha biodiesel engine the signal to noise ratio (SNR) related to higher-the-better (HTB) quality characteristics has been used. The present methodology correctly predicted the compression ratio, Weibe's heat release constants and combustion zone duration as the critical parameters that affect the performance of the engine compared to other parameters. (author)

  2. Extraction of oil from microalgae for biodiesel production: A review.

    Science.gov (United States)

    Halim, Ronald; Danquah, Michael K; Webley, Paul A

    2012-01-01

    The rapid increase of CO(2) concentration in the atmosphere combined with depleted supplies of fossil fuels has led to an increased commercial interest in renewable fuels. Due to their high biomass productivity, rapid lipid accumulation, and ability to survive in saline water, microalgae have been identified as promising feedstocks for industrial-scale production of carbon-neutral biodiesel. This study examines the principles involved in lipid extraction from microalgal cells, a crucial downstream processing step in the production of microalgal biodiesel. We analyze the different technological options currently available for laboratory-scale microalgal lipid extraction, with a primary focus on the prospect of organic solvent and supercritical fluid extraction. The study also provides an assessment of recent breakthroughs in this rapidly developing field and reports on the suitability of microalgal lipid compositions for biodiesel conversion. Copyright © 2012 Elsevier Inc. All rights reserved.

  3. Producing biodiesel from yellow greases with high free fatty acids

    Directory of Open Access Journals (Sweden)

    Amrani Mahacine

    2007-01-01

    Full Text Available Biodiesel is a diesel replacement fuel that is manufactured from vegetable oils recycled cooking greases and oils or animal fats. Biodiesel offers many advantages because it is renewable, nontoxic, biodegradable, and suitable for sensitive environments. It can also be used in most diesel equipments with no or only minor modifications. These yellow greases contain great quantities of free fatty acids which form soaps in the presence of alkaline catalyst. Pretreatments of the raw material with acid catalysts are necessary to avoid the soap formation. The transesterification of yellow greases is supplemented in the presence of an alkaline catalyst. The greatest production of biodiesel corresponds to molar flows of 4.985 kmol.hr-1 of methyl oleate, and 4.658 kmol.hr-1 of methyl butyrate.

  4. Production of Biodiesel from Shea Butter Oil using Homogeneous Catalysts

    Directory of Open Access Journals (Sweden)

    Jude EJEH

    2014-02-01

    Full Text Available An investigation into the production of biodiesel from shea butter oil using homogenous catalyst was carried out. The properties of the oil obtained were first determined, having an FFA value of 2.279 amongst other properties. Thus, the direct base-catalysis method was used, with potassium hydroxide as the catalyst. In a 1 hour batch run, biodiesel was produced with a conversion of 92%, FAME content of 97.1%, cetane number of 46.84 and kinematic viscosity of 4.30mm2/s, conforming to ASTM D6751 and EN 14214 international standards. As such, it was established that shea butter biodiesel could be produced by the direct base catalysis, over a shorter time with low cost chemicals.

  5. Biodiesel for Brazilian development: current situation and challenges for a sustainable future; Biodiesel para o desenvolvimento brasileiro: situacao atual e desafios para um futuro sustentavel

    Energy Technology Data Exchange (ETDEWEB)

    Bartsch, Aleksandra Sliwowska; Antunes, Adelaide Maria de Souza [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Escola de Quimica

    2008-07-01

    This article aims at analyzing the state of art and trends of biodiesel in Brazil, with resort to the Industry Strategic Map, a tool developed by National Industry Federation (CNI). The situation of biodiesel will be analyzed considering : Bases for Development, Processes and Activities, Market and Results for Country. At the beginning is presented the evolution of biodiesel in Brazil e are explained the construction of the Strategic Map by CNI. (author)

  6. Novel process integration for biodiesel blend in membrane reactive divided wall (MRDW column

    Directory of Open Access Journals (Sweden)

    Sakhre Vandana

    2016-03-01

    Full Text Available The paper proposes a novel process integration for biodiesel blend in the Membrane assisted Reactive Divided Wall Distillation (MRDW column. Biodiesel is a green fuel and grade of biodiesel blend is B20 (% which consist of 20% biodiesel and rest 80% commercial diesel. Instead of commercial diesel, Tertiary Amyl Ethyl Ether (TAEE was used as an environment friendly fuel for blending biodiesel. Biodiesel and TAEE were synthesized in a pilot scale reactive distillation column. Dual reactive distillation and MRDW were simulated using aspen plus. B20 (% limit calculation was performed using feed flow rates of both TAEE and biodiesel. MRDW was compared with dual reactive distillation column and it was observed that MRDW is comparatively cost effective and suitable in terms of improved heat integration and flow pattern.

  7. Production of biodiesel from lipid of phytoplankton Chaetoceros calcitrans through ultrasonic method.

    Science.gov (United States)

    Kwangdinata, Raymond; Raya, Indah; Zakir, Muhammad

    2014-01-01

    A research on production of biodiesel from lipid of phytoplankton Chaetoceros calcitrans through ultrasonic method has been done. In this research, we carried out a series of phytoplankton cultures to determine the optimum time of growth and biodiesel synthesis process from phytoplankton lipids. Process of biodiesel synthesis consists of two steps, that is, isolation of phytoplankton lipids and biodiesel synthesis from those lipids. Oil isolation process was carried out by ultrasonic extraction method using ethanol 96%, while biodiesel synthesis was carried out by transesterification reaction using methanol and KOH catalyst under sonication. Weight of biodiesel yield per biomass Chaetoceros calcitrans is 35.35%. Characterization of biodiesel was well carried out in terms of physical properties which are density and viscosity and chemical properties which are FFA content, saponification value, and iodine value. These values meet the American Society for Testing and Materials (ASTM D6751) standard levels, except for the viscosity value which was 1.14 g · cm(-3).

  8. Anaerobic biodegradation of soybean biodiesel and diesel blends under sulfate-reducing conditions.

    Science.gov (United States)

    Wu, Shuyun; Yassine, Mohamad H; Suidan, Makram T; Venosa, Albert D

    2016-10-01

    Biotransformation of soybean biodiesel and its biodiesel/petrodiesel blends were investigated under sulfate-reducing conditions. Three blends of biodiesel, B100, B50, and B0, were treated using microbial cultures pre-acclimated to B100 (biodiesel only) and B80 (80% biodiesel and 20% petrodiesel). Results indicate that the biodiesel could be effectively biodegraded in the presence or absence of petrodiesel, whereas petrodiesel could not be biodegraded at all under sulfate-reducing conditions. The kinetics of biodegradation of individual Fatty Acid Methyl Ester (FAME) compounds and their accompanying sulfate-reduction rates were studied using a serum bottle test. As for the biodegradation of individual FAME compounds, the biodegradation rates for the saturated FAMEs decreased with increasing carbon chain length. For unsaturated FAMEs, biodegradation rates increased with increasing number of double bonds. The presence of petrodiesel had a greater effect on the rate of biodegradation of biodiesel than on the extent of removal.

  9. Study on Emission and Performance of Diesel Engine Using Castor Biodiesel

    Directory of Open Access Journals (Sweden)

    Md. Saiful Islam

    2014-01-01

    performance of diesel engine using the castor biodiesel and its blend with diesel from 0% to 40% by volume. The acid-based catalyzed transesterification system was used to produce castor biodiesel and the highest yield of 82.5% was obtained under the optimized condition. The FTIR spectrum of castor biodiesel indicates the presence of C=O and C–O functional groups, which is due to the ester compound in biodiesel. The smoke emission test revealed that B40 (biodiesel blend with 40% biodiesel and 60% diesel had the least black smoke compared to the conventional diesel. Diesel engine performance test indicated that the specific fuel consumption of biodiesel blend was increased sufficiently when the blending ratio was optimized. Thus, the reduction in exhaust emissions and reduction in brake-specific fuel consumption made the blends of caster seed oil (B20 a suitable alternative fuel for diesel and could help in controlling air pollution.

  10. Technical aspects of production and analysis of biodiesel from used cooking oil. A review

    Energy Technology Data Exchange (ETDEWEB)

    Enweremadu, C.C.; Mbarawa, M.M. [Department of Mechanical Engineering, Tshwane University of Technology, Private Bag X680, Pretoria 001 (South Africa)

    2009-12-15

    The increasing awareness of the depletion of fossil fuel resources and the environmental benefits of biodiesel fuel has made it more attractive in recent times. The cost of biodiesel, however, is the major hurdle to its commercialization in comparison to petroleum-based diesel fuel. The high cost is primarily due to the raw material, mostly neat vegetable oil. Used cooking oil is one of the economical sources for biodiesel production. However, the products formed during frying, can affect the transesterification reaction and the biodiesel properties. This paper attempts to review various technological methods of biodiesel production from used cooking oil. The analytical methods for high quality biodiesel fuel from used cooking oil like GC, TLC, HPLC, GPC and TGA have also been summarized in this paper. In addition, the specifications provided by different countries are presented. The fuel properties of biodiesel fuel from used cooking oil were also reviewed and compared with those of conventional diesel fuel. (author)

  11. IDENTIFICATION OF ADULTERANT AND ALCOHOL ROUTE IN BIODIESEL USING MID-INFRARED ABSORPTION SPECTROSCOPY

    Directory of Open Access Journals (Sweden)

    Maryleide Ventura da Silva

    2014-01-01

    Full Text Available Mid-infrared absorption spectroscopy was used to analyze soybean oil, ethylic and methylic soybean biodiesel, and blends prepared with soybean oil mixed with biodiesel, in order to evaluate this method as an alternative to assess oil as impurities or adulterant in biodiesel. We also aimed to determine whether the biodiesel was prepared by the ethyl or methyl routes, by inspecting the infrared spectra. The C-O functional groups between 1100 and 1200 cm-1 are different for oil and biodiesel, which allows them to be used to distinguish impurities (residual oil in biofuel. The peak C-O-C at 1017 cm-1 is characteristic for methylic biodiesel, and the peak O-C-C at 1035 cm-1 for ethylic biodiesel. These vibrational modes can therefore be used to indicate the route used to prepare the biofuel. Results indicated that infrared spectroscopy is appropriate for monitoring the quality of biofuel for commercial sale.

  12. MODEL FOR THE CORRECTION OF THE SPECIFIC GRAVITY OF BIODIESEL FROM RESIDUAL OIL

    Directory of Open Access Journals (Sweden)

    Tatiana Aparecida Rosa da Silva

    2013-06-01

    Full Text Available Biodiesel is a important fuel with economic benefits, social and environmental. The production cost of the biodiesel can be significantly lowered if the raw material is replaced by a alternative material as residual oil. In this study, the variation of specific gravity with temperature increase for diesel and biodiesel from residual oil obtained by homogeneous basic catalysis. All properties analyzed for biodiesel are within specification Brazil. The determination of the correction algorithm for the specific gravity function of temperature is also presented, and the slope of the line to diesel fuel, methylic biodiesel (BMR and ethylic biodiesel (BER from residual oil were respectively the values -0.7089, -0.7290 and -0.7277. This demonstrates the existence of difference of the model when compared chemically different fuels, like diesel and biodiesel from different sources, indicating the importance of determining the specific algorithm for the operations of conversion of volume to the reference temperature.

  13. Pancreatic Cancer: 80 Years of Surgery—Percentage and Repetitions

    Directory of Open Access Journals (Sweden)

    Birgir Gudjonsson

    2016-01-01

    Full Text Available Objective. The incidence of pancreatic cancer is estimated to be 48,960 in 2015 in the US and projected to become the second and third leading causes of cancer-related deaths by 2030. The mean costs in 2015 may be assumed to be $79,800 per patient and for each resection $164,100. Attempt is made to evaluate the results over the last 80 years, the number of survivors, and the overall survival percentage. Methods. Altogether 1230 papers have been found which deal with resections and reveal survival information. Only 621 of these report 5-year survivors. Reservation about surgery was first expressed in 1964 and five-year survival of nonresected survivors is well documented. Results. The survival percentage depends not only on the number of survivors but also on the subset from which it is calculated. Since the 1980s the papers have mainly reported the number of resections and survival as actuarial percentages, with or without the actual number of survivors being reported. The actuarial percentage is on average 2.75 higher. Detailed information on the original group (TN, number of resections, and actual number of survivors is reported in only 10.6% of the papers. Repetition occurs when the patients from a certain year are reported several times from the same institution or include survivors from many institutions or countries. Each 5-year survivor may be reported several times. Conclusion. Assuming a 10% resection rate and correcting for repetitions and the life table percentage the overall actual survival rate is hardly more than 0.3%.

  14. Characterization of Palm Oil as Biodiesel

    Science.gov (United States)

    Gorey, Neeraj; Ghosh, Shankha; Srivastava, Priyank; Kumar, Vivek

    2017-08-01

    The various sources of energy from which mechanical energy is obtained are non-renewable and are thus considered to be unsustainable. These sources include the various fossil fuels like the petroleum, coal and the natural gas. The burning of fossil fuels led to the production of the greenhouse gases increasing the levels of CO2 in the atmosphere. The adverse effects are the global warming and the ozone layer depletion. In a nation like India, where consumable oils are still transported in, it is advantageous to investigate the likelihood of utilising such non-palatable oils as a part of CI motors which are not by and by used as cooking oil. Palm oil (otherwise called dendê oil, from Portuguese) is a consumable vegetable oil got from the monocarp (ruddy mash) of the product of the oil palms. The major objective is to provide a cheap and effective alternative to diesel. This paper is an exploration of the capability of the palm oil as a practical, modest and effective hotspot for the generation of biodiesel. the paper is based on the characterisation of palm oil compare to diesel.

  15. Biodiesel production by enzyme-catalyzed transesterification

    Directory of Open Access Journals (Sweden)

    Stamenković Olivera S.

    2005-01-01

    Full Text Available The principles and kinetics of biodiesel production from vegetable oils using lipase-catalyzed transesterification are reviewed. The most important operating factors affecting the reaction and the yield of alkyl esters, such as: the type and form of lipase, the type of alcohol, the presence of organic solvents, the content of water in the oil, temperature and the presence of glycerol are discussed. In order to estimate the prospects of lipase-catalyzed transesterification for industrial application, the factors which influence the kinetics of chemically-catalysed transesterification are also considered. The advantages of lipase-catalyzed transesterification compared to the chemically-catalysed reaction, are pointed out. The cost of down-processing and ecological problems are significantly reduced by applying lipases. It was also emphasized that lipase-catalysed transesterification should be greatly improved in order to make it commercially applicable. The further optimization of lipase-catalyzed transesterification should include studies on the development of new reactor systems with immobilized biocatalysts and the addition of alcohol in several portions, and the use of extra cellular lipases tolerant to organic solvents, intracellular lipases (i.e. whole microbial cells and genetically-modified microorganisms ("intelligent" yeasts.

  16. Ultrasound assisted intensification of biodiesel production using enzymatic interesterification.

    Science.gov (United States)

    Subhedar, Preeti B; Gogate, Parag R

    2016-03-01

    Ultrasound assisted intensification of synthesis of biodiesel from waste cooking oil using methyl acetate and immobilized lipase obtained from Thermomyces lanuginosus (Lipozyme TLIM) as a catalyst has been investigated in the present work. The reaction has also been investigated using the conventional approach based on stirring so as to establish the beneficial effects obtained due to the use of ultrasound. Effect of operating conditions such as reactant molar ratio (oil and methyl acetate), temperature and enzyme loading on the yield of biodiesel has been investigated. Optimum conditions for the conventional approach (without ultrasound) were established as reactant molar ratio of 1:12 (oil:methyl acetate), enzyme loading of 6% (w/v), temperature of 40 °C and reaction time of 24 h and under these conditions, 90.1% biodiesel yield was obtained. The optimum conditions for the ultrasound assisted approach were oil to methyl acetate molar ratio of 1:9, enzyme loading of 3% (w/v), and reaction time of 3 h and the biodiesel yield obtained under these conditions was 96.1%. Use of ultrasound resulted in significant reduction in the reaction time with higher yields and lower requirement of the enzyme loading. The obtained results have clearly established that ultrasound assisted interesterification was a fast and efficient approach for biodiesel production giving significant benefits, which can help in reducing the costs of production. Reusability studies for the enzyme were also performed but it was observed that reuse of the catalyst under the optimum experimental condition resulted in reduced enzyme activity and biodiesel yield.

  17. Los Alamos National Laboratory considers the use of biodiesel.

    Energy Technology Data Exchange (ETDEWEB)

    Matlin, M. K. (Marla K.)

    2002-01-01

    A new EPA-approved alternative fuel, called biodiesel, may soon be used at Los Alamos National Laboratory in everything from diesel trucks to laboratory equipment. Biodiesel transforms vegetable oils into a renewable, cleaner energy source that can be used in any machinery that uses diesel fuel. For the past couple years, the Laboratory has been exploring the possibility of switching over to soybean-based biodiesel. This change could lead to many health and environmental benefits, as well as help reduce the nation's dependence on foreign oil. Biodiesel is a clean, renewable diesel fuel substitute made from soybean and other vegetable oil crops, as well as from recycled cooking oils. A chemical process breaks down the vegetable oil into a usable form. Vegetable oil has a chain of about 18 carbons and ordinary diesel has about 12 or 13 carbons. The process breaks the carbon chains of the vegetable oil and separates out the glycerin (a fatty substance used in creams and soaps). The co-product of glycerin can be used by pharmaceutical and cosmetic companies, as well as many other markets. Once the chains are shortened and the glycerin is removed from the oil, the remaining liquid is similar to petroleum diesel fuel. It can be burned in pure form or in a blend of any proportion with petroleum diesel. To be considered an alternative fuel source by the EPA, the blend must be at least 20 percent biodiesel (B20). According to the U.S. Department of Energy (DOE), biodiesel is America's fastest growing alternative fuel.

  18. Tinjauan Penilaian Siklus Hidup Bahan Bakar Biodiesel di Indonesia

    Directory of Open Access Journals (Sweden)

    Kiman Siregar

    2014-10-01

    Review of Life Cycle Assesment of Biodiesel in Indonesia Abstract. Currently, environmental consideration becomes the most important issue in biodiesel production. Eventhough source of energy is considered as carbon neutral, the production path may release various environmentally hazardous gasses. European and American countries claim that production of biodiesel from palm oil contributes carbon emission to the atmosphere along its production path. Furthermore, US EPA-NODA and EU RED stated that palm oil based biodiesel can only reduce emission of GWP by 17 % and 19 % compared to fossil-fuel based. Considering on the minimum requirement is 20 % for US and 35 % for EU, CPO from Indonesia experiences difficulties to enter the global market. Scientific approach should be undertaken by Indonesia to address this issue. Summary of the literature mentions that the sustainability of biodiesel from palm oil is better than Jatropha curcas, compared to other sources of raw materials, such as rapeseed. Summary of the literature mentions that the value of carbon that can be absorbed by primary forest is higher than secondary forest and palm oil plantation. This is the reason why world claims Indonesia on global warming issues although further research is still needed based on the latest data. From the real condition in Indonesia, in which GHG value before stable productivity is 2 575.47 kg-CO2eq./ton-Biodiesel fuel(BDF for oil palm and 3 057.74 kg-CO2eq./ton-BDF for Jatropha curcas. When the productivity has reached stability, the GHG value is  1 511.96 kg-CO2eq./ton-BDF for oil palm and 380.52 kg-CO2eq./ton-BDF for Jatropha curcas. If we compared to diesel fuel, CO2eq. emission is reduced up to 49.27 % and 88.45 % for BDF-CPO and BDF-CJCO, respectively.

  19. Simulation, optimization and analysis of cost of biodiesel plant pot route enzymatic; Simulacao, otimizacao e analise de custo de planta de biodiesel via rota enzimatica

    Energy Technology Data Exchange (ETDEWEB)

    Mendes, Jocelia S.; Ferreira, Andrea L.O. [Universidade Federal do Ceara (UFC), Fortaleza, CE (Brazil); Silva, Giovanilton F. [Tecnologia Bioenergetica - Tecbio, Fortaleza, CE (Brazil)

    2008-07-01

    The aim of this work ware simulation, optimization and to find the biodiesel production cost produced by enzymatic route. Consequently, it was carried out a methodology of economic calculations and sensitivity analyses for this process. It was used a computational software from balance equations for obtaining the biodiesel cost. The economical analysis was obtained by capital cost of biofuel. The whole process was developed according analysis of fixed capital cost, total manufacturing cost, raw material cost, and chemical cost. The results of economic calculations to biodiesel production showed efficient. The model was meant for use in assessing the effects on estimated biodiesel production cost of changes in different types of oils. (author)

  20. Life cycle assessment of palm biodiesel: Revealing facts and benefits for sustainability

    Energy Technology Data Exchange (ETDEWEB)

    Yee, Kian Fei; Tan, Kok Tat; Abdullah, Ahmad Zuhairi; Lee, Keat Teong [School of Chemical Engineering, Universiti Sains Malaysia, Engineering Campus, Seri Ampangan, 14300 Nibong Tebal, Pulau Pinang (Malaysia)

    2009-11-15

    Similarity between the properties of biodiesel and petroleum-derived diesel has made the former one of the most promising alternatives to a renewable and sustainable fuel for the transportation sector. In Malaysia, palm oil can be a suitable feedstock for the production of biodiesel due to its abundant availability and low production cost. However, not many assessments have been carried out regarding the impacts of palm biodiesel on the environment. Hence, in this study, life cycle assessment (LCA) was conducted for palm biodiesel in order to investigate and validate the popular belief that palm biodiesel is a green and sustainable fuel. The LCA study was divided into three main stages, namely agricultural activities, oil milling and transesterification process for the production of biodiesel. For each stage, the energy balance and green house gas assessments were presented and discussed. These are important data for the techno-economical and environmental feasibility evaluation of palm biodiesel. The results obtained for palm biodiesel were then compared with rapeseed biodiesel. From this study, it was found that the utilization of palm biodiesel would generate an energy yield ratio of 3.53 (output energy/input energy), indicating a net positive energy generated and ensuring its sustainability. The energy ratio for palm biodiesel was found to be more than double that of rapeseed biodiesel which was estimated to be only 1.44, thereby indicating that palm oil would be a more sustainable feedstock for biodiesel production as compared to rapeseed oil. Moreover, combustion of palm biodiesel was found to be more environment-friendly than petroleum-derived-diesel as a significant 38% reduction of CO{sub 2} emission can be achieved per liter combusted. (author)

  1. Treatment for purification water of biodiesel using electrofloculation

    Directory of Open Access Journals (Sweden)

    Juliana Ferreira de Brito

    2012-01-01

    Full Text Available Biodiesel was created as a solution for a great economic and enviromental problem of petroleum, a resource with sustainable characteristics. But its production still needs optimization, because it uses a lot of water and generates a large volume of this residue, which appears improper to disposal without correct treatment. This work propose an economic, viable and efficient way to treat the Biodiesel purification water, not only aiming at a proper disposal, but the reuse as input in the process, generating a large industrial economy, and greater environmental progress. For both treatment uses the electrofloculation technique.

  2. Alabama Institute for Deaf and Blind Biodiesel Project Green

    Energy Technology Data Exchange (ETDEWEB)

    Edmiston, Jessica L

    2012-09-28

    Through extensive collaboration, Alabama Institute for Deaf and Blind (AIDB) is Alabama's first educational entity to initiate a biodiesel public education, student training and production program, Project Green. With state and national replication potential, Project Green benefits local businesses and city infrastructures within a 120-mile radius; provides alternative education to Alabama school systems and to schools for the deaf and blind in Appalachian States; trains students with sensory and/or multiple disabilities in the acquisition and production of biodiesel; and educates the external public on alternative fuels benefits.

  3. An Overview of Biodiesel and Petroleum Diesel Life Cycles

    Energy Technology Data Exchange (ETDEWEB)

    Sheehan, John [National Renewable Energy Lab. (NREL), Golden, CO (United States); Camobreco, Vince [National Renewable Energy Lab. (NREL), Golden, CO (United States); Duffield, James [National Renewable Energy Lab. (NREL), Golden, CO (United States); Graboski, Michael [National Renewable Energy Lab. (NREL), Golden, CO (United States); Shapouri, Housein [National Renewable Energy Lab. (NREL), Golden, CO (United States)

    1998-05-01

    This overview is extracted from a detailed, comprehensive report entitled Life Cycle Inventories of Biodiesel and Petroleum Diesel for Use in an Urban Bus. This report presents the findings from a study of the life cycle inventories (LCIs) for petroleum diesel and biodiesel. An LCI comprehensively quantifies all the energy and environmental flows associated with a product from “cradle to grave.” It provides information on raw materials extracted from the environment; energy resources consumed; and air, water, and solid waste emissions generated.

  4. Mechanistic Modelling of Biodiesel Production using a Liquid Lipase Formulation

    DEFF Research Database (Denmark)

    Price, Jason Anthony; Hofmann, Björn; Silva, Vanessa T. L.

    2014-01-01

    , with respect to the industrial production of biodiesel. The developed kinetic model, coupled with a mass balance of the system, was fitted to and validated on experimental results for the fed-batch transesterification of rapeseed oil. The confidence intervals of the parameter estimates, along...... that constrains the amount of methanol in the reactor was computed and the predictions experimentally validated. Monte-Carlo simulations were then used to characterize the effect of the parameter uncertainty on the model outputs, giving a biodiesel yield, based on the mass of oil, of 90.8 ± 0.55 mass %. © 2014...

  5. Optimization of Substrate Feeding for Enzymatic Biodiesel Production

    DEFF Research Database (Denmark)

    Price, Jason Anthony; Huusom, Jakob Kjøbsted; Nordblad, Mathias

    to be effective in mitigating the effects of substrate inhibition. Using enzymatic biodiesel production as a case study, the volumetric productivity of the reactor is increased while minimizing inactivation of the enzyme due to the alcohol. This is done by using a simple optimization routine where the substrate...... (both the vegetable oil and alcohol) feed rate/concentration is manipulated simultaneously. The results of the simulation were tested in the laboratory and are sufficiently positive to suggest the implementation of a feeding strategy for large scale enzymatic biodiesel production....

  6. Model Feed for Hydrotreating of Fat for Biodiesel Production

    DEFF Research Database (Denmark)

    Biodiesel production by the transesterification of oils and fats with an alcohol to fatty acid alkyl esters is rapidly increasing worldwide. Plant oils are usually suited for transesterification, but feedstocks from waste products like trap greases and abattoir wastes are difficult to react due...... resulted in lower conversions and a much higher degree of hydrogenation than with the Pt catalyst. This protocol represents a facile method of studying hydrotreating of waste fats and oils for biodiesel production, which may be a viable alternative to current dominating transesterification technology. 1...

  7. Fed-Batch Feeding Strategies for Enzymatic Biodiesel Production

    DEFF Research Database (Denmark)

    Price, Jason Anthony; Nordblad, Mathias; Woodley, John

    2014-01-01

    of the differences in the interfacial and bulk concentrations of the enzyme. The model is then used to evaluate various feeding strategies to improve the enzymatic biodiesel production. The feeding strategies investigated, gave insight into how the methanol should be fed to potentially mitigate enzyme deactivation...... while improving the biodiesel yield. The best experimental results gave a yield of 703 .76 g FAME L-1 and a reactor productivity of 28.12 g FAME L-1 h-1. In comparison, to reach the same yield, the optimised two step feeding strategy took 6.25 hours less, which equates to an increase the reactor...

  8. Moving towards a Competitive Fully Enzymatic Biodiesel Process

    Directory of Open Access Journals (Sweden)

    Silvia Cesarini

    2015-06-01

    Full Text Available Enzymatic biodiesel synthesis can solve several problems posed by the alkaline-catalyzed transesterification but it has the drawback of being too expensive to be considered competitive. Costs can be reduced by lipase improvement, use of unrefined oils, evaluation of soluble/immobilized lipase preparations, and by combination of phospholipases with a soluble lipase for biodiesel production in a single step. As shown here, convenient natural tools have been developed that allow synthesis of high quality FAMEs (EN14214 from unrefined oils in a completely enzymatic single-step process, making it fully competitive.

  9. Optimization of Substrate Feeding for Enzymatic Biodiesel Production

    DEFF Research Database (Denmark)

    Price, Jason Anthony; Huusom, Jakob Kjøbsted; Nordblad, Mathias

    2013-01-01

    to be effective in mitigating the effects of substrate inhibition. Using enzymatic biodiesel production as a case study, the volumetric productivity of the reactor is increased while minimizing inactivation of the enzyme due to the alcohol. This is done by using a simple optimization routine where the substrate...... (both the vegetable oil and alcohol) feed rate/concentration is manipulated simultaneously. The results of the simulation were tested in the laboratory and are sufficiently positive to suggest the implementation of a feeding strategy for large scale enzymatic biodiesel production...

  10. [Biodiesel-fuel: content, production, producers, contemporary biotechnology (review)].

    Science.gov (United States)

    Feofilova, E P; Sergeeva, Ia E; Ivashechkin, A A

    2010-01-01

    The necessity of expanding studies on producing renewable biofuel is reviewed. Special attention is given to biodiesel, the history of its creation, and its advantages and disadvantages in comparison with diesel-fuel. The main part of the review is devoted to an analysis of diesel biofuel on the basis of bacterial lipids, filamentous fungi, yeasts, plants, photo- and heterotrophic algae. Biodiesel on the basis of filamentous fungi is studied in detail and the possibility of creation of the most perspective biotechnology using these producers is grounded. The contemporary state of biotechnology in Russia is discussed in connection with the development of energetics based on renewable biofuels.

  11. Potency of Microalgae as Biodiesel Source in Indonesia

    Directory of Open Access Journals (Sweden)

    H Hadiyanto

    2012-02-01

    Full Text Available Within 20 years, Indonesia should find another energy alternative to substitute current fossil oil. Current use of renewable energy is only 5% and need to be improved up to 17% of our energy mix program. Even though, most of the area in Indonesia is covered by sea, however the utilization of microalgae as biofuel production is still limited. The biodiesel from current sources (Jatropha, palm oil, and sorghum is still not able to cover all the needs if the fossil oil cannot be explored anymore. In this paper, the potency of microalgae in Indonesia was analysed as the new potential of energy (biodiesel sources.

  12. Potency of Microalgae as Biodiesel Source in Indonesia

    Directory of Open Access Journals (Sweden)

    H Hadiyanto

    2012-04-01

    Full Text Available Within 20 years, Indonesia should find another energy alternative to substitutecurrent fossil oil. Current use of renewable energy is only 5% and need to be improved up to 17%of our energy mix program. Even though, most of the area in Indonesia is covered by sea, howeverthe utilization of microalgae as biofuel production is still limited. The biodiesel from currentsources (Jatropha, palm oil, and sorghum is still not able to cover all the needs if the fossil oilcannot be explored anymore. In this paper, the potency of microalgae in Indonesia was analysed asthe new potential of energy (biodiesel sources.

  13. Percentage of microbeads in pelagic microplastics within Japanese coastal waters.

    Science.gov (United States)

    Isobe, Atsuhiko

    2016-09-15

    To compare the quantity of microbeads with the quantity of pelagic microplastics potentially degraded in the marine environment, samples were collected in coastal waters of Japan using neuston nets. Pelagic spherical microbeads were collected in the size range below 0.8mm at 9 of the 26 stations surveyed. The number of pelagic microbeads smaller than 0.8mm accounted for 9.7% of all microplastics collected at these 9 stations. This relatively large percentage results from a decrease in the abundance of microplastics smaller than 0.8mm in the upper ocean, as well as the regular loading of new microbeads from land areas, in this size range. In general, microbeads in personal care and cosmetic products are not always spherical, but rather are often a variety of irregular shapes. It is thus likely that this percentage is a conservative estimate, because of the irregular shapes of the remaining pelagic microbeads.

  14. Conversion of palm oil sludge to biodiesel using alum and KOH as catalysts

    Directory of Open Access Journals (Sweden)

    Abdullah

    2017-11-01

    Full Text Available Conversion of palm oil sludge was studied by esterification and transesterification which used methanol as a reactant. The esterification of palm oil sludge was performed by variation of molar ratios of methanol to palm oil sludge (5:1, 10:1, 15:1, 20:1, and 25:1 and percentages of alum catalyst (3–7 wt% at 60 °C for 3 h with stirring rate 300 rpm. Transesterification was also carried out by variation of KOH (0.5–2.5 wt% at 60 °C and stirring rate 300 rpm for 1 h. The optimum molar ratio of methanol to palm oil sludge was 20:1 (6% alum catalyst. Meanwhile, the optimum concentration for transesterification was 1.5% of KOH. The yield of biodiesel production was 93%, the density and kinematic viscosity were 0.864 g mL−1 and 12.8 mm2 s−1, respectively. The existence of ester compounds in the product was shown by Fourier Transform Infrared Spectrometry spectrum data of carbonyl group (CO at 1744 cm−1 and CO of ester at 1234; 1119 and 1026 cm−1. Gas Chromatograph-Mass Spectrometry analysis showed the biodiesel product contains palmitic acid methyl ester (23.4%, trans-methyl oleate (75.5%, cis-methyl oleate (< 0.1%, and methyl stearate (1.2%.

  15. Effect of poultry fat oil biodiesel on tractor engine performance

    Directory of Open Access Journals (Sweden)

    M Bavafa

    2016-04-01

    Full Text Available Introduction: Depletion of fossil fuels and environmental degradation are two major problems faced by the world. Today fossil fuels take up to 80% of the primary energy consumed in the world, of which 58% is consumed by the transport sector alone (Mard et al., 2012. The combustion products cause global warming, which is caused of emissions like carbon monoxide (CO, sulfur dioxide (SO2 and nitrogen oxides (NOX. Thus it is essential that low emission alternative fuels to be developed for useing in diesel engines. Many researchers have concluded that biodiesel holds promise as an alternative fuel for diesel engines. Biodiesel is oxygenated, biodegradable, non-toxic, and environmentally friendly (Qi et al., 2010. Materials and Methods: In this study transesterification method was used to produce biodiesel, because of its simplicity in biodiesel production process and holding the highest conversion efficiency. Transesterification of poultry fat oil and the properties of the fuels: Fatty acid methyl ester of poultry fat oil was prepared by transesterification of oil with methanol in the presence of KOH as catalyst. The fuel properties of poultry fat oil methyl ester and diesel fuel were determined. These properties are presented in Table 1. Tests of engine performance and emissions: After securing the qualitative characteristics of produced biodiesel, different biodiesel fuels of 5%, 10%, 15%, and 20% blended with diesel fuel were prepared. A schematic diagram of the engine setup is shown in Fig.1. The MF-399 tractor engine was used in the tests. The basic specifications of the engine are shown in Table 3. The engine was loaded with an electromagnetic dynamometer. The Σ5 model dynamometer manufactured by NJ-FROMENT was used to measure the power and the torque of the tractor engine. The speed range and capacity of this device are shown in Table 2. A FTO Flow Meter, manufactured by American FLOWTECH Company, was used to measure the fuel consumption

  16. Fuel Pellets Production from Biodiesel Waste

    Directory of Open Access Journals (Sweden)

    Kawalin Chaiyaomporn

    2010-01-01

    Full Text Available This research palm fiber and palm shell were used as raw materials to produce pelletised fuel, and waste glycerol were used as adhesive to reduce biodiesel production waste. The aim of this research is to find optimum ratio of raw material (ratio of palm fiber and palm shell, raw material size distribution, adhesive temperature, and ratio of ingredients (ratio of raw material, waste glycerol, and water. The optimum ratio of pelletized fuel made only by palm fiber was 50:10:40; palm fiber, water, and waste glycerol respectively. In the best practice condition; particle size was smaller than 2 mm, adhesive glycerol was heated. From the explained optimum ratio and ingredient, pelletizing ratio was 62.6%, specific density was 982.2 kg/m3, heating value was 22.5 MJ/kg, moisture content was 5.9194%, volatile matter was 88.2573%, fix carbon content was 1.5894%, and ash content was 4.2339% which was higher than the standard. Mixing palm shell into palm fiber raw material reduced ash content of the pellets. The optimum raw material ratio, which minimizes ash content, was 80 to 20 palm fiber and palm shell respectively. Adding palm shell reduced ash content to be 2.5247% which was higher than pelletized fuel standard but followed cubed fuel standard. At this raw material ratio, pelletizing ratio was 70.5%, specific density was 774.8 kg/m3, heating value was 19.71 MJ/kg, moisture content was 9.8137%, volatile matter was 86.2259%, fix carbon content was 1.4356%, and compressive force was 4.83 N. Pelletized fuel cost at optimum condition was 1.14 baht/kg.

  17. Biodiesel: most recent developments in distribution infra-structure; Recentes desenvolvimentos na infra-estrutura do biodiesel: caso pratico apresentando desde a compra do biodiesel ate a mistura automatizada nas bases

    Energy Technology Data Exchange (ETDEWEB)

    Kauer, Luiz Athayde da Silva; Silberman Luis [Petroleo Ipiranga (Grupo ULTRA), Rio Grande, RS (Brazil)

    2008-07-01

    This presentation will show a practical large scale case of, which involves: the purchase, distribution and storage of 80 million liters of Biodiesel that we have bought in the Brazilian market; the way the distribution is being done and the future perspectives in its infra-structure. Moreover, this presentation will approach and detail the most recent developments in: automation of the mix in the terminals of distribution. Specific analysis of our terminal in Rio de Janeiro - Brazil; identification of the best practice and the results already obtained from it; identification of the tie breaker criteria to produce the mix of the Biodiesel in the Diesel oil; what we are doing to development the modals of transportation of Biodiesel; the Biodiesel storage - Best operational practices; the Biodiesel - aspects for the consumer quality control; acquisition of 5 thousand tons of carbon credits. (author)

  18. Direct Biodiesel Production from Wet Microalgae Biomass of Chlorella pyrenoidosa through In Situ Transesterification

    Directory of Open Access Journals (Sweden)

    Hechun Cao

    2013-01-01

    Full Text Available A one-step process was applied to directly converting wet oil-bearing microalgae biomass of Chlorella pyrenoidosa containing about 90% of water into biodiesel. In order to investigate the effects of water content on biodiesel production, distilled water was added to dried microalgae biomass to form wet biomass used to produce biodiesel. The results showed that at lower temperature of 90°C, water had a negative effect on biodiesel production. The biodiesel yield decreased from 91.4% to 10.3% as water content increased from 0% to 90%. Higher temperature could compensate the negative effect. When temperature reached 150°C, there was no negative effect, and biodiesel yield was over 100%. Based on the above research, wet microalgae biomass was directly applied to biodiesel production, and the optimal conditions were investigated. Under the optimal conditions of 100 mg dry weight equivalent wet microalgae biomass, 4 mL methanol, 8 mL n-hexane, 0.5 M H2SO4, 120°C, and 180 min reaction time, the biodiesel yield reached as high as 92.5% and the FAME content was 93.2%. The results suggested that biodiesel could be effectively produced directly from wet microalgae biomass and this effort may offer the benefits of energy requirements for biodiesel production.

  19. Computational fluid dynamics simulation of a single cylinder research engine working with biodiesel

    Directory of Open Access Journals (Sweden)

    Moldovanu Dan

    2013-01-01

    Full Text Available The main objective of the paper is to present the results of the CFD simulation of a DI single cylinder engine using diesel, biodiesel, or different mixture proportions of diesel and biodiesel and compare the results to a test bed measurement in the same functioning point. The engine used for verifying the results of the simulation is a single cylinder research engine from AVL with an open ECU, so that the injection timings and quantities can be controlled and analyzed. In Romania, until the year 2020 all the fuel stations are obliged to have mixtures of at least 10% biodiesel in diesel [14]. The main advantages using mixtures of biofuels in diesel are: the fact that biodiesel is not harmful to the environment; in order to use biodiesel in your engine no modifications are required; the price of biodiesel is smaller than diesel and also if we compare biodiesel production to the classic petroleum based diesel production, it is more energy efficient; biodiesel assures more lubrication to the engine so the life of the engine is increased; biodiesel is a sustainable fuel; using biodiesel helps maintain the environment and it keeps the people more healthy [1-3].

  20. Annex 34 : task 1 : analysis of biodiesel options : biomass-derived diesel fuels : final report

    Energy Technology Data Exchange (ETDEWEB)

    McGill, R. [Oak Ridge National Laboratory, TN (United States); Aakko-Saksa, P.; Nylund, N.O. [TransEnergy Consulting Ltd., Helsinki (Finland)

    2009-06-15

    Biofuels are derived from woody biomass, non-woody biomass, and organic wastes. The properties of vegetable oil feedstocks can have profound effects on the properties of the finished biodiesel product. However, all biodiesel fuels have beneficial effects on engine emissions. This report discussed the use of biodiesel fuels as replacements for part of the diesel fuel consumed throughout the world. Biodiesel fuels currently being produced from fatty acid esters today were reviewed, as well as some of the more advanced diesel replacement fuels. The report was produced as part of the International Energy Agency (IEA) Advanced Motor Fuels (AMF) Implementing Agreement Annex 34, and was divided into 14 sections: (1) an introduction, (2) biodiesel and biomass, (3) an explanation of biodiesel, (4) properties of finished biodiesel fuels, (5) exhaust emissions of finished biodiesel fuels and blends, (6) life-cycle emissions and energy, (7) international biodiesel (FAME) technical standards and specifications, (8) growth in production and use of biodiesel fuels, (9) biofuel refineries, (10) process technology, (11) development and status of biorefineries, (12) comparison of options to produce biobased diesel fuels, (13) barriers and gaps in knowledge, and (14) references. 113 refs., 37 tabs., 74 figs.